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1

Multicomponent Geothermometers | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 -Energieprojekte3 ClimateSpurr GeothermalCarmel PublicMulticomponent Geothermometers

2

A new illite geothermometer  

SciTech Connect (OSTI)

Sericite, either as illite or illite/smectite, is ubiquitous in geothermal systems. Theoretical Ca- and Na-smectite contents of non-expanding geothermal sericites have been calculated from published electron microprobe analyses. Geothermal sericites can be modeled as solid solutions of muscovite and smectite. For those sericites that fit the model, the amount of smectite in solid solution is related to temperature by the expression TºC = 1000/(0.45LogX{sub smectite} + 2.38) – 273. The temperature dependence of illite interlayer chemistry suggests a related temperature dependence of the K, Na and Ca content of geothermal fluids. The original data used by Fournier and Truesdell (1973) to derive the empirical Na-K-Ca geothermometer for geothermal fluids can be modeled equally well by an equation incorporating the equilibrium constant for the reaction of smectite to illite: T ºC = 1.145*10{sup 3}/([0.35LogNa + 0.175LogCa – 0.75LogK] + 1.51) – 273, where the concentration units are molalities. This supports the hypothesis that illite and illite/smectite are important controls on the concentrations of Na, K and Ca in geothermal fluids.

Ballantyne, Judith M.; Moore, Joseph N.

1988-01-01T23:59:59.000Z

3

Evaluation Of Chemical Geothermometers For Calculating Reservoir...  

Open Energy Info (EERE)

Geothermometers For Calculating Reservoir Temperatures At Nevada Geothermal Power Plants Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper:...

4

Silica Geothermometers | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revisionEnvReviewNonInvasiveExplorationUT-g Grant ofRichardton AbbeyARaftPadomaSierra Leone)Sikes Act JumpSilica

5

Cation Geothermometers | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin:Energy Information on PV Economics By BuildingCategory: Wind,000Cation

6

Category:Silica Geothermometers | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin: EnergyBostonFacilityCascadeJump to:ListsGeothermalpower.jpg

7

Evaluation Of Chemical Geothermometers For Calculating Reservoir  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address:011-DNA Jump37. It isInformationexplains a4 ClimateEtrionPower Pvt LtdA

8

Cation Geothermometers At Lightning Dock Geothermal Area (Witcher, 2006) |  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin:Energy Information on PV Economics By BuildingCategory: Wind,000

9

Chemical Geothermometers And Mixing Models For Geothermal Systems | Open  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160Benin:Energy Information on PV2009Information17.3180919°,Faults In Utah

10

New Improved Equations For Na-K, Na-Li And Sio2 Geothermometers...  

Open Energy Info (EERE)

errors (2-3%) than for the original equation (5-29%). Authors Surendra P. Verma and Edgar Santoyo Published Journal Journal of Volcanology and Geothermal Research, 1997 DOI Not...

11

Application Of An Artificial Neural Network Model To A Na-K Geothermometer  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160 East 300Algoil JumpAltergyExperimentsInformationAnuvuCommissionArea, Japan |Of||

12

New Improved Equations For Na-K, Na-Li And Sio2 Geothermometers By Outlier  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revision hasInformation Earth's HeatMexico: EnergyMithunCenter Jump to:2Harvest Jump to: navigation,Detection

13

A New Improved Na-K Geothermometer By Artificial Neural Networks | Open  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160 East 300 SouthWater Rights, Substantive(Sichuan, Sw China)|EnergyApproach ToMap

14

An Empirical Na-K-Ca Geothermometer For Natural Waters | Open Energy  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address: 160 East 300Algoil JumpAltergy SystemsAmericanAmphenolInformation Embarrassment

15

Multicomponent Equilibrium Models for Testing Geothermometry Approaches  

SciTech Connect (OSTI)

Geothermometry is an important tool for estimating deep reservoir temperature from the geochemical composition of shallower and cooler waters. The underlying assumption of geothermometry is that the waters collected from shallow wells and seeps maintain a chemical signature that reflects equilibrium in the deeper reservoir. Many of the geothermometers used in practice are based on correlation between water temperatures and composition or using thermodynamic calculations based a subset (typically silica, cations or cation ratios) of the dissolved constituents. An alternative approach is to use complete water compositions and equilibrium geochemical modeling to calculate the degree of disequilibrium (saturation index) for large number of potential reservoir minerals as a function of temperature. We have constructed several “forward” geochemical models using The Geochemist’s Workbench to simulate the change in chemical composition of reservoir fluids as they migrate toward the surface. These models explicitly account for the formation (mass and composition) of a steam phase and equilibrium partitioning of volatile components (e.g., CO2, H2S, and H2) into the steam as a result of pressure decreases associated with upward fluid migration from depth. We use the synthetic data generated from these simulations to determine the advantages and limitations of various geothermometry and optimization approaches for estimating the likely conditions (e.g., temperature, pCO2) to which the water was exposed in the deep subsurface. We demonstrate the magnitude of errors that can result from boiling, loss of volatiles, and analytical error from sampling and instrumental analysis. The estimated reservoir temperatures for these scenarios are also compared to conventional geothermometers. These results can help improve estimation of geothermal resource temperature during exploration and early development.

Cooper, D. Craig; Carl D. Palmer; Robert W. Smith; Travis L. McLing

2013-02-01T23:59:59.000Z

16

Multicomponent membranes  

DOE Patents [OSTI]

A multicomponent membrane which may be used for separating various components which are present in a fluid feed mixture comprises a mixture of a plasticizer such as a glycol and an organic polymer cast upon a porous organic polymer support. The membrane may be prepared by casting an emulsion or a solution of the plasticizer and polymer on the porous support, evaporating the solvent and recovering the membrane after curing.

Kulprathipanja, Santi (Hoffman Estates, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL); Funk, Edward W. (Highland Park, IL)

1988-01-01T23:59:59.000Z

17

Exploring the reactivity of bacterial multicomponent monooxygenases  

E-Print Network [OSTI]

Chapter 1. Introduction: The Reactivity of Bacterial Multicomponent Monooxygenases Bacterial multicomponent monooxygenases constitute a remarkable family of enzymes that oxidize small, inert hydrocarbon substrates using ...

Tinberg, Christine Elaine

2010-01-01T23:59:59.000Z

18

CRYSTALLIZATION IN MULTICOMPONENT GLASSES  

SciTech Connect (OSTI)

In glass processing situations involving glass crystallization, various crystalline forms nucleate, grow, and dissolve, typically in a nonuniform temperature field of molten glass subjected to convection. Nuclear waste glasses are remarkable examples of multicomponent vitrified mixtures involving partial crystallization. In the glass melter, crystals form and dissolve during batch-to-glass conversion, melter processing, and product cooling. Crystals often agglomerate and sink, and they may settle at the melter bottom. Within the body of cooling glass, multiple phases crystallize in a non-uniform time-dependent temperature field. Self-organizing periodic distribution (the Liesegnang effect) is common. Various crystallization phenomena that occur in glass making are reviewed.

KRUGER AA; HRMA PR

2009-10-08T23:59:59.000Z

19

New Design Methods and Algorithms for Multi-component Distillation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

New Design Methods and Algorithms for Multi-component Distillation Processes New Design Methods and Algorithms for Multi-component Distillation Processes multicomponent.pdf More...

20

Geothermal reservoir temperatures estimated from the oxygen isotope...  

Open Energy Info (EERE)

drillholes have been tested as a geothermometer in three areas of the western United States. Limited analyses of spring and borehole fluids and existing experimental rate...

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Geothermal Reservoir Temperatures Estimated from the Oxygen Isotope...  

Open Energy Info (EERE)

drillholes have been tested as a geothermometer in three areas of the western United States. Limited analyses of spring and borehole fluids and existing experimental rate...

22

Improvements in geothermometry. Final technical report  

SciTech Connect (OSTI)

The following are covered: the basis of the Na-K-Ca geothermometer, geothermometry via model calculations, non ideality and complexing, and experimental calibration.

Potter, J.; Dibble, W.; Parks, G.; Nur, A.

1982-07-01T23:59:59.000Z

23

THERMODYNAMICS Unified Model for Nonideal Multicomponent  

E-Print Network [OSTI]

THERMODYNAMICS Unified Model for Nonideal Multicomponent Molecular Diffusion Coefficients Alana and a rigorous descrip- tion of mixture nonideality in the framework of irreversible thermodynamics. Molecular

Firoozabadi, Abbas

24

GROUND STATES AND DYNAMICS OF MULTICOMPONENT BOSEEINSTEIN CONDENSATES  

E-Print Network [OSTI]

GROUND STATES AND DYNAMICS OF MULTICOMPONENT BOSE­EINSTEIN CONDENSATES WEIZHU BAO MULTISCALE MODEL a multicomponent Bose­Einstein condensate (BEC) at zero or a very low temperature. In preparation for the numerics of multicomponent BEC. Key words. multicomponent, Bose­Einstein condensate, vector Gross­Pitaevskii equations

Bao, Weizhu

25

aniline dioxygenase-related multicomponent: Topics by E-print...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and cleared with chloral hydrate to allow high Haseloff, Jim 4 Multi-Component Dark Matter HEP - Phenomenology (arXiv) Summary: We explore multi-component dark matter models...

26

On rational solutions of multicomponent and matrix KP hierarchies  

E-Print Network [OSTI]

We derive some rational solutions for the multicomponent and matrix KP hierarchies generalising an approach by Wilson. Connections with the multicomponent version of the KP/CM correspondence are discussed.

Alberto Tacchella

2010-11-05T23:59:59.000Z

27

Thermodynamics and Mass Transport in Multicomponent,  

E-Print Network [OSTI]

Thermodynamics and Mass Transport in Multicomponent, Multiphase H2O Systems of Planetary Interest, cryogenic systems, thermodynamics, fluid dynamics, clathrates, Mars, Enceladus, sound speed Abstract Heat of the noncondensible components can greatly alter the thermodynamic properties of the phases and their flow properties

Jellinek, Mark

28

THERMODYNAMICS Molecular Simulation of Multicomponent Reaction  

E-Print Network [OSTI]

THERMODYNAMICS Molecular Simulation of Multicomponent Reaction and Phase Equilibria in MTBE Ternary System Martin Lisal´ E. Hala Laboratory of Thermodynamics, Institute of Chemical Process Fundamentals N1G 2W1, Canada Ivo Nezbeda E. Hala Laboratory of Thermodynamics, Institute of Chemical Process

Lisal, Martin

29

Multicomponent interfacial transport as described by  

E-Print Network [OSTI]

at the surface Distillation column Fuel cells Biological membranes Spinodal decomposition #12;5 Multicomponent R1q 100 % Rq2-R2q R2 q 100% R12-R21 R21 100 % Measure of the error: =210-4 -- optimal perturbation

Kjelstrup, Signe

30

ADVANCES IN HYDROGEOCHEMICAL INDICATORS FOR THE DISCOVERY OF NEW GEOTHERMAL RESOURCES IN THE GREAT BASIN, USA  

SciTech Connect (OSTI)

This report summarizes the results of Phase I work for a go/no go decision on Phase II funding. In the first objective, we assessed the extent to which fluid-mineral equilibria controlled deep water compositions in geothermal systems across the Great Basin. Six systems were evaluated: Beowawe; Desert Peak; Dixie Valley; Mammoth; Raft River; Roosevelt. These represent a geographic spread of geothermal resources, in different geological settings and with a wide range of fluid compositions. The results were used for calibration/reformulation of chemical geothermometers that reflect the reservoir temperatures in producing reservoirs. In the second objective, we developed a reactive -transport model of the Desert Peak hydrothermal system to evaluate the processes that affect reservoir fluid geochemistry and its effect on solute geothermometry. This included testing geothermometry on “reacted” thermal water originating from different lithologies and from near-surface locations where the temperature is known from the simulation. The integrated multi-component geothermometer (GeoT, relying on computed mineral saturation indices) was tested against the model results and also on the systems studied in the first objective.

Simmons, Stuart F [Colorado School of Mines; Spycher, Nicolas [Lawrence Berkeley National Laboratory; Sonnenthal, Eric [Lawrence Berkeley National Laboratory; Dobson, Patrick [Lawrence Berkeley National Laboratory

2013-05-20T23:59:59.000Z

31

Multicomponent Gas Diffusion in Porous Electrodes  

E-Print Network [OSTI]

Multicomponent gas transport is investigated with unprecedented precision by AC impedance analysis of porous YSZ anode-supported solid oxide fuel cells. A fuel gas mixture of H2-H2O-N2 is fed to the anode, and impedance data are measured across the range of hydrogen partial pressure (10-100%) for open circuit conditions at three temperatures (800C, 850C and 900C) and for 300mA applied current at 800C. For the first time, analytical formulae for the diffusion resistance (Rb) of three standard models of multicomponent gas transport (Fick, Stefan-Maxwell, and Dusty Gas) are derived and tested against the impedance data. The tortuosity is the only fitting parameter since all the diffusion coefficients are known. Only the Dusty Gas model leads to a remarkable data collapse for over twenty experimental conditions, using a constant tortuosity consistent with permeability measurements and the Bruggeman relation. These results establish the accuracy of the Dusty Gas model for multicomponent gas diffusion in porous med...

Fu, Yeqing; Dutta, Abhijit; Mohanram, Aravind; Pietras, John D; Bazant, Martin Z

2014-01-01T23:59:59.000Z

32

Multi-component Nanoparticle Based Lubricant Additive to Improve...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Nanoparticle Based Lubricant Additive to Improve Efficiency and Durability in Engines Multi-component Nanoparticle Based Lubricant Additive to Improve Efficiency and...

33

Curvature Dependency of Surface Tension in Multicomponent Systems  

E-Print Network [OSTI]

Curvature Dependency of Surface Tension in Multicomponent Systems Erik Santiso Dept. of Chemical InterScience (www.interscience.wiley.com). The effect of curvature on the surface tension of droplets for multicomponent systems, the relation between the surface tension at the surface of tension and the distance

Firoozabadi, Abbas

34

J/$?$ absorption in a multicomponent hadron gas  

E-Print Network [OSTI]

A model for anomalous $J/\\Psi$ suppression in high energy heavy ion collisions is presented. As the additional suppression mechanism beyond standard nuclear absorption inelastic $J/\\Psi$ scattering with hadronic matter is considered. Hadronic matter is modeled as an evolving multi-component gas of point-like non-interacting particles (MCHG). Estimates for the sound velocity of the MCHG are given and the equation of state is compared with Lattice QCD data in the vicinity of the deconfinement phase transition. The approximate cooling pattern caused by longitudinal expansion is presented. It is shown that under these conditions the resulting $J/\\Psi$ suppression pattern agrees well with NA38 and NA50 data.

Dariusz Prorok; Ludwik Turko; David Blaschke

2008-08-04T23:59:59.000Z

35

6 Multicomponent Density-Functional Theory R. van Leeuwen and E.K.U. Gross  

E-Print Network [OSTI]

6 Multicomponent Density-Functional Theory R. van Leeuwen and E.K.U. Gross 6.1 Introduction fields. Our goal is to set up a time-dependent multicomponent density-functional theory (TDMCDFT.K.U. Gross: Multicomponent Density-Functional Theory, Lect. Notes Phys. 706, 93­106 (2006) DOI 10

Gross, E.K.U.

36

Ground states and dynamics of multi-component Bose-Einstein condensates  

E-Print Network [OSTI]

Ground states and dynamics of multi-component Bose-Einstein condensates Weizhu Bao #3; Department) an external driven #12;eld for dynamics describing a multi-component Bose- Einstein condensate (BEC) at zero-component Bose-Einstein condensates. Key Words. Multi-component, Bose-Einstein condensate (BEC), Vector Gross

Markowich, Peter A.

37

The Single Pass Multi-component Harvester  

SciTech Connect (OSTI)

The authors are solely responsible for the content of this technical presentation. The technical presentation does not necessarily reflect the official position of the American Society of Agricultural Engineers (ASAE), and its printing and distribution does not constitute an endorsement of views which may be expressed. Technical presentations are not subject to the formal peer review process by ASAE editorial committees; therefore, they are not to be presented as refereed publications. Citation of this work should state that it is from an ASAE meeting paper. EXAMPLE: Author's Last Name, Initials. 2004. Title of Presentation. ASAE Paper No. 04xxxx. St. Joseph, Mich.: ASAE. For information about securing permission to reprint or reproduce a technical presentation, please contact ASAE at hq@asae.org or 269-429-0300 (2950 Niles Road, St. Joseph, MI 49085-9659 USA). Abstract. In order to meet the U. S. government’s goal of supplementing the energy available from petroleum by increasing the production of energy from renewable resources, increased production of bioenergy has become one of the new goals of the United States government and our society. U.S. Executive Orders and new Federal Legislation have mandated changes in government procedures and caused reorganizations within the government to support these goals. The Biomass Research and Development Initiative is a multi-agency effort to coordinate and accelerate all U.S. Federal biobased products and bioenergy research and development. The Initiative is managed by the National Biomass Coordination Office, which is staffed by both the DOE and the USDA. One of the most readily available sources of biomass from which to produce bioenergy is an agricultural crop residue, of which straw from small grains is the most feasible residue with which to start. For the straw residue to be used its collection must be energy efficient and its removal must not impact the sustainability of the growing environment. In addition, its collection must be economically advantageous to the producer. To do all that, a single pass multi-component harvester system is most desirable. Results from our first prototype suggest that current combines probably do adequate threshing and that a separate chassis can be developed that does additional separation and that is economically feasible.

Reed Hoskinson; John R. Hess

2004-08-01T23:59:59.000Z

38

Nonequilibrium and Rarefaction Effects in Hypersonic Multicomponent Viscous Shock  

E-Print Network [OSTI]

Nonequilibrium and Rarefaction Effects in Hypersonic Multicomponent Viscous Shock Layers V.V. Riabov1 1 Introduction Planetary exploration programs [1] stimulate new studies in hypersonic aerother- modynamics. The design of hypersonic vehicles has brought renewed interests in the heat protecting methods [2

Riabov, Vladimir V.

39

Modelling precipitation of niobium carbide in austenite: multicomponent diffusion, capillarity,  

E-Print Network [OSTI]

Modelling precipitation of niobium carbide in austenite: multicomponent diffusion, capillarity, and coarsening N. Fujita and H. K. D. H. Bhadeshia The growth of niobium carbide in austenite involves for the overall transformation kinetics of niobium carbide precipitation in austenite that takes into account

Cambridge, University of

40

FUNCTIONAL ESTIMATION FOR A MULTICOMPONENT AGE REPLACEMENT MODEL  

E-Print Network [OSTI]

1 FUNCTIONAL ESTIMATION FOR A MULTICOMPONENT AGE REPLACEMENT MODEL Pierre L'Ecuyer, Benoit Martin, controlled by a replacement rule based on age thresholds. We show how to estimate the expected cost­ generative simulation, maintenance models, age replacement policies. #12; 2 L'ECUYER, MARTIN, AND V ' AZQUEZ

L'Ecuyer, Pierre

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

FUNCTIONAL ESTIMATION FOR A MULTICOMPONENT AGE REPLACEMENT MODEL  

E-Print Network [OSTI]

FUNCTIONAL ESTIMATION FOR A MULTICOMPONENT AGE REPLACEMENT MODEL Pierre L'Ecuyer, Benoit Martin, controlled by a replacement rule based on age thresholds. We show how to estimate the expected cost­ generative simulation, maintenance models, age replacement policies. #12; L'ECUYER, MARTIN, AND V ' AZQUEZ

Vázquez-Abad, Felisa J.

42

Computation of liquid-liquid equilibrium in multicomponent electrolyte systems  

SciTech Connect (OSTI)

A computational algorithm for predicting liquid-liquid equilibrium (LLE) data, based on a generalization of the maximum likelihood method applied to implicit constraints, is presented. The algorithm accepts multicomponent data and binary interaction parameters. A comparative study of the models NRTL and electrolyte-NRTL, used for estimating activity coefficients in a quaternary electrolyte system, is presented and discussed. Results show that both models give accurate predictions and the algorithm presents a good performance without convergence or initialization problems. This suggests that the basic NRTL model can be used for describing phase behavior in weak electrolyte systems and the procedure can be of great use for design and optimization of processes involving multicomponent electrolyte systems. 9 refs., 1 fig., 1 tab.

Vianna, R.F.; d`Avila, S.G. [Universidade Estadual de Campinas (Brazil)

1996-12-31T23:59:59.000Z

43

Method for producing nanocrystalline multicomponent and multiphase materials  

DOE Patents [OSTI]

A process for producing multi-component and multiphase nanophase materials is provided wherein a plurality of elements are vaporized in a controlled atmosphere, so as to facilitate thorough mixing, and then condensing and consolidating the elements. The invention also provides for a multicomponent and multiphase nanocrystalline material of specified elemental and phase composition having component grain sizes of between approximately 1 nm and 100 nm. This material is a single element in combination with a binary compound. In more specific embodiments, the single element in this material can be a transition metal element, a non-transition metal element, a semiconductor, or a semi-metal, and the binary compound in this material can be an intermetallic, an oxide, a nitride, a hydride, a chloride, or other compound. 6 figs.

Eastman, J.A.; Rittner, M.N.; Youngdahl, C.J.; Weertman, J.R.

1998-03-17T23:59:59.000Z

44

Method for producing nanocrystalline multicomponent and multiphase materials  

DOE Patents [OSTI]

A process for producing multi-component and multiphase nanophase materials is provided wherein a plurality of elements are vaporized in a controlled atmosphere, so as to facilitate thorough mixing, and then condensing and consolidating the elements. The invention also provides for a multicomponent and multiphase nanocrystalline material of specified elemental and phase composition having component grain sizes of between approximately 1 nm and 100 nm. This material is a single element in combination with a binary compound. In more specific embodiments, the single element in this material can be a transition metal element, a non-transition metal element, a semiconductor, or a semi-metal, and the binary compound in this material can be an intermetallic, an oxide, a nitride, a hydride, a chloride, or other compound.

Eastman, Jeffrey A. (Woodridge, IL); Rittner, Mindy N. (Des Plaines, IL); Youngdahl, Carl J. (Westmont, IL); Weertman, Julia R. (Evanston, IL)

1998-01-01T23:59:59.000Z

45

Multicomponent 3-D characterization of a coalbed methane reservoir  

SciTech Connect (OSTI)

Methane is produced from fractured coalbed reservoirs at Cedar Hill Field in the San Juan Basin. Fracturing and local stress are critical to production because of the absence of matrix permeability in the coals. Knowledge of the direction of open fractures, the degree of fracturing, reservoir pressure, and compartmentalization is required to understand the flow of fluids through the reservoir. A multicomponent 3-D seismic survey was acquired to aid in coalbed methane reservoir characterization. Coalbed reservoir heterogeneities, including isolated pressure cells, zones of increased fracture density, and variable fracture directions, have been interpreted through the analysis of the multicomponent data and integration with petrophysical and reservoir engineering studies. Strike-slip faults, which compartmentalize the reservoir, have been identified by structural interpretation of the 3-D P-wave seismic data. These faults form boundaries for pressure cells that have been identified by P-wave reflection amplitude anomalies.

Shuck, E.L. [Advance Geophysical Corp., Englewood, CO (United States)] [Advance Geophysical Corp., Englewood, CO (United States); Davis, T.L.; Benson, R.D. [Colorado School of Mines, Golden, CO (United States). Geophysics Dept.] [Colorado School of Mines, Golden, CO (United States). Geophysics Dept.

1996-03-01T23:59:59.000Z

46

Minimum Energy Consumption in Multicomponent Distillation. 1. Vmin Diagram for a Two-Product Column  

E-Print Network [OSTI]

Minimum Energy Consumption in Multicomponent Distillation. 1. Vmin Diagram for a Two-Product Column how the minimum energy consumption is related to the feed-component distribution for all possible operating points in a two-product distillation column with a multicomponent feed. The classical Underwood

Skogestad, Sigurd

47

Minimum Energy Consumption in Multicomponent Distillation. 3. More Than Three Products and Generalized Petlyuk Arrangements  

E-Print Network [OSTI]

Minimum Energy Consumption in Multicomponent Distillation. 3. More Than Three Products-component feed into M products has been derived. Interestingly, the minimum-energy solution in a complex solution of minimum energy for distillation of a multicomponent feed into multiple products has not been

Skogestad, Sigurd

48

Multicomponent density-functional theory for electrons and nuclei Thomas Kreibich  

E-Print Network [OSTI]

Multicomponent density-functional theory for electrons and nuclei Thomas Kreibich Institut für a general multicomponent density-functional theory in which electrons and nuclei are treated completely , 71.10. w I. INTRODUCTION Density-functional theory DFT is among the most suc- cessful approaches

Gross, E.K.U.

49

ON THE LINEAR GROWTH OF THE SPLITANDMERGE SIMULATION TREE FOR A MULTICOMPONENT AGE REPLACEMENT MODEL  

E-Print Network [OSTI]

ON THE LINEAR GROWTH OF THE SPLIT­AND­MERGE SIMULATION TREE FOR A MULTICOMPONENT AGE REPLACEMENT Functional estimation, split­and­merge tree, opti­ mization, maintenance models, age replacement poli­ cies Abstract We a consider a replacement policy based on age thresholds, for a multicomponent system. We want

Vázquez-Abad, Felisa J.

50

Fluid description of multi-component solar partially ionized plasma  

SciTech Connect (OSTI)

We derive self-consistent formalism for the description of multi-component partially ionized solar plasma, by means of the coupled equations for the charged and neutral components for an arbitrary number of chemical species, and the radiation field. All approximations and assumptions are carefully considered. Generalized Ohm's law is derived for the single-fluid and two-fluid formalism. Our approach is analytical with some order-of-magnitude support calculations. After general equations are developed, we particularize to some frequently considered cases as for the interaction of matter and radiation.

Khomenko, E., E-mail: khomenko@iac.es; Collados, M.; Vitas, N. [Instituto de Astrofísica de Canarias, 38205 La Laguna, Tenerife (Spain); Departamento de Astrofísica, Universidad de La Laguna, 38205 La Laguna, Tenerife (Spain); Díaz, A. [Departament de Física, Universitat de les Illes Balears, E-07122 Palma de Mallorca (Spain)

2014-09-15T23:59:59.000Z

51

Equilibrium adsorption of multicomponent gas mixtures at elevated pressures  

SciTech Connect (OSTI)

Equilibrium adsorption of H/sub 2/, CO, CH/sub 4/, CO/sub 2/, and H/sub 2/S (single and mixed gases-two to five species) was measured on activated carbon at pressures up to 400 psia. Temperature-dependent parameters, regressed from single-gas data, were applied to four theoretical models which predict adsorption from gas mixtures. Deviations between theory (IAS) and experiment increased with pressure and with the number of components in the mixture. None of the theories employing only single-gas data could consistently predict multicomponent adsorption. It was found that multicomponent adsorption could be predicted from the extended Langmuir equation by including an interaction parameter calculated from only single and binary data. In the application of mixture adsorption theories, it was shown that from the same model significantly different results can be obtained depending on the selection of the independent set, /T, P, X/sub i// or /T, P, Y/sub i//.

Ritter, J.A.; Yang, R.T.

1987-08-01T23:59:59.000Z

52

Phase transition in multicomponent field theory at finite temperature  

E-Print Network [OSTI]

Nuclear matter at finite temperature and barion density exhibits several phase transitions that could happen at the early stages of the Universe evolution and could be realized in heavy-ion or hadron-hadron collisions. Microscopic description of phase transitions is notoriously difficult because of the absence of small parameters. Here we present a general approach allowing to treat situations, when there are no small parameters. The approach is based on optimized perturbation theory and self-similar approximation theory. It allows, starting with divergent perturbation series in powers of an asymptotically small parameter, to construct expressions extrapolating asymptotic series to arbitrary values of the parameter, including its infinite limit. Examples of such approximants are: right root approximants, left root approximants, continued root approximants, exponential approximants, and factor approximants. The approach is illustrated by the phase transition of gauge symmetry breaking in a multicomponent field...

Yukalov, V I

2015-01-01T23:59:59.000Z

53

Phase conversion dissipation in multi-component compact stars  

E-Print Network [OSTI]

We propose a mechanism for the damping of density oscillations in multi-component compact stars. The mechanism is the periodic conversion between different phases, i.e. the movement of the interface between them, induced by pressure oscillations in the star. The damping grows nonlinearly with the amplitude of the oscillation. We study in detail the case of r-modes in a hybrid star with a sharp interface, and we find that this mechanism is powerful enough to saturate the r-mode at very low saturation amplitude, of order $10^{-10}$, and is therefore likely to be the dominant r-mode saturation mechanism in hybrid stars with a sharp interface.

Mark G. Alford; Sophia Han; Kai Schwenzer

2015-01-15T23:59:59.000Z

54

Structural investigations of hydroxylase proteins and complexes in bacterial multicomponent monooxygenase systems  

E-Print Network [OSTI]

Bacterial multicomponent monooxgenases (BMMs) such as toluene/o-xylene monooxygenase (ToMO), phenol hydroxylase (PH), and soluble methane monooxygenase (sMMO) catalyze hydrocarbon oxidation reactions at a carboxylatebridged ...

McCormick, Michael S. (Michael Scott)

2008-01-01T23:59:59.000Z

55

Analytical Solutions for Multicomponent, Two-Phase Flow in Porous Media with Double Contact Discontinuities  

E-Print Network [OSTI]

This paper presents the first instance of a double contact discontinuity in analytical solutions for multicomponent, two-phase flow in porous media. We use a three-component system with constant equilibrium ratios and fixed ...

Orr, F. M. Jr

56

Multicomponent fluid flow by discontinuous Galerkin and mixed methods in unfractured and fractured media  

E-Print Network [OSTI]

. Numerical examples in unfractured and fractured media illustrate the efficiency and robustness in gas-condensate reservoirs), hydrology and geochemical engineering (contamination of groundwater field, sharp variations in the rock properties, and high nonlinearity of the multicomponent system due

Firoozabadi, Abbas

57

Analysis of seismic fractures using multicomponent VSP in the Bartlett Flat area, Utah  

E-Print Network [OSTI]

tool in oil recovery. In homogeneous anisotropic media the fracture orientation can be correctly computed by the transformation method using multicomponent S-wave VSP data. However,, random noise, interference with reflected waves, and unequal source...

Yuh, Sung Hwan

2012-06-07T23:59:59.000Z

58

Modeling of multicomponent radiatively driven stellar winds using a Newton-Raphson method  

E-Print Network [OSTI]

We present a simple method for the solution of one-component and multicomponent hydrodynamic equations based on the Newton-Raphson method. We show that this method can be used for the solution of stationary hydrodynamic equations. This method has been used for the calculation of the low density stellar wind models for which the multicomponent nature of the wind influences the overall wind structure.

J. Krticka

2003-03-03T23:59:59.000Z

59

Universal Whitham hierarchy, dispersionless Hirota equations and multi-component KP hierarchy  

E-Print Network [OSTI]

The goal of this paper is to identify the universal Whitham hierarchy of genus zero with a dispersionless limit of the multi-component KP hierarchy. To this end, the multi-component KP hierarchy is (re)formulated to depend on several discrete variables called ``charges''. These discrete variables play the role of lattice coordinates in underlying Toda field equations. A multi-component version of the so called differential Fay identity are derived from the Hirota equations of the $\\tau$-function of this ``charged'' multi-component KP hierarchy. These multi-component differential Fay identities have a well-defined dispersionless limit (the dispersionless Hirota equations). The dispersionless Hirota equations turn out to be equivalent to the Hamilton-Jacobi equations for the $S$-functions of the universal Whitham hierarchy. The differential Fay identities themselves are shown to be a generating functional expression of auxiliary linear equations for scalar-valued wave functions of the multi-component KP hierarchy.

Kanehisa Takasaki; Takashi Takebe

2007-08-31T23:59:59.000Z

60

PROCEEDINGS, Twenty-Seventh Workshop on Geothermal Reservoir Engineering Stanford University, Stanford, California, January 28-30, 2002  

E-Print Network [OSTI]

probably by the drilling fluid. When applied on all these fluids, numerous chemical geothermometers yield. On the three bore-holes drilled by CFG in this area, only the bore-hole located more at north (Californie bore-hole) and near the old LA-101 bore- hole, indicated the presence of inflows of hot fluid close to 90°C starting

Boyer, Edmond

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Geothermometry At Lassen Volcanic National Park Area (Janik ...  

Open Energy Info (EERE)

sample taken had a pH of 8.35 and contained 2100 ppm Cl and 0.55 ppm NH3. Ratios of Na+K+ and Na+Cl remained nearly constant throughout the flow test. Cation geothermometers...

62

Compound and Elemental Analysis At Lassen Volcanic National Park...  

Open Energy Info (EERE)

sample taken had a pH of 8.35 and contained 2100 ppm Cl and 0.55 ppm NH3. Ratios of Na+K+ and Na+Cl remained nearly constant throughout the flow test. Cation geothermometers...

63

Proceedings World Geothermal Congress 2005 Antalya, Turkey, 24-29 April 2005  

E-Print Network [OSTI]

Proceedings World Geothermal Congress 2005 Antalya, Turkey, 24-29 April 2005 1 Geothermal: Martinique, geothermal exploration, thermal springs, soil gas profiles, chemical geothermometers ABSTRACT in starting again geothermal research on the Martinique island, in the Lesser Antilles. The first works, which

Paris-Sud XI, Université de

64

The solubility of natural quartz sand at 100?C, and 150?C, 345 bars: an experimental investigation in a flow-through hydrothermal system  

E-Print Network [OSTI]

geothermometers and mixing for geothermal systems. Geothermi cs 5, 41-50. Foumier R. O. and Potter R. W. II (1982) An equation correlating the solubility of quartz in water from 25' to 900' C at pressures up to 10, 000 bars, Geochim. Cosrnochim. Acta 46, 1969...

Burns, Gregory Lee

2012-06-07T23:59:59.000Z

65

Sputter deposition for multi-component thin films  

DOE Patents [OSTI]

Ion beam sputter-induced deposition using a single ion beam and a multicomponent target is capable of reproducibly producing thin films of arbitrary composition, including those which are close to stoichiometry. Using a quartz crystal deposition monitor and a computer controlled, well-focused ion beam, this sputter-deposition approach is capable of producing metal oxide superconductors and semiconductors of the superlattice type such as GaAs-AlGaAs as well as layered metal/oxide/semiconductor/superconductor structures. By programming the dwell time for each target according to the known sputtering yield and desired layer thickness for each material, it is possible to deposit composite films from a well-controlled sub-monolayer up to thicknesses determined only by the available deposition time. In one embodiment, an ion beam is sequentially directed via a set of X-Y electrostatic deflection plates onto three or more different element or compound targets which are constituents of the desired film. In another embodiment, the ion beam is directed through an aperture in the deposition plate and is displaced under computer control to provide a high degree of control over the deposited layer. In yet another embodiment, a single fixed ion beam is directed onto a plurality of sputter targets in a sequential manner where the targets are each moved in alignment with the beam under computer control in forming a multilayer thin film. This controlled sputter-deposition approach may also be used with laser and electron beams.

Krauss, Alan R. (Plainfield, IL); Auciello, Orlando (Cary, NC)

1990-01-01T23:59:59.000Z

66

Sputter deposition for multi-component thin films  

DOE Patents [OSTI]

Ion beam sputter-induced deposition using a single ion beam and a multicomponent target is capable of reproducibly producing thin films of arbitrary composition, including those which are close to stoichiometry. Using a quartz crystal deposition monitor and a computer controlled, well-focused ion beam, this sputter-deposition approach is capable of producing metal oxide superconductors and semiconductors of the superlattice type such as GaAs-AlGaAs as well as layered metal/oxide/semiconductor/superconductor structures. By programming the dwell time for each target according to the known sputtering yield and desired layer thickness for each material, it is possible to deposit composite films from a well-controlled sub-monolayer up to thicknesses determined only by the available deposition time. In one embodiment, an ion beam is sequentially directed via a set of X-Y electrostatic deflection plates onto three or more different element or compound targets which are constituents of the desired film. In another embodiment, the ion beam is directed through an aperture in the deposition plate and is displaced under computer control to provide a high degree of control over the deposited layer. In yet another embodiment, a single fixed ion beam is directed onto a plurality of sputter targets in a sequential manner where the targets are each moved in alignment with the beam under computer control in forming a multilayer thin film. This controlled sputter-deposition approach may also be used with laser and electron beams. 10 figs.

Krauss, A.R.; Auciello, O.

1990-05-08T23:59:59.000Z

67

Interpreting multicomponent seismic data in the Gulf of Mexico for shallow sedimentary properties: methodology and case history  

E-Print Network [OSTI]

OTC 15118 Interpreting multicomponent seismic data in the Gulf of Mexico for shallow sedimentary of multicomponent data analysis for the detection of gas hydrate prospects in the northern Gulf of Mexico. Methane and pressure conditions in the region. In many regions of North America, including the southern Gulf of Mexico

Texas at Austin, University of

68

Computational Modeling of Plasmon-Enhanced Light Absorption in a Multicomponent Dye Sensitized Solar Cell  

E-Print Network [OSTI]

can be mitigated by using dye-sensitized solar cells (DSSCs),4 which use organic dye molecules coated by nearly an order of magnitude through plasmon enhanced absorption by the dye.10 This particular solar cellComputational Modeling of Plasmon-Enhanced Light Absorption in a Multicomponent Dye Sensitized

69

Multicomponent reactive transport modeling at the Ratones uranium mine, Cceres (Spain)  

E-Print Network [OSTI]

Multicomponent reactive transport modeling at the Ratones uranium mine, Cáceres (Spain) Modelación management. The Ratones uranium mine was abandoned and flooded in 1974. Due to its reducing underground water, uranium, reactive transport, granite hydrochemistry, Ratones mine. Resumen La inundación de minas

Politècnica de Catalunya, Universitat

70

A multicomponent coupled model of glacier hydrology 1. Theory and synthetic examples  

E-Print Network [OSTI]

A multicomponent coupled model of glacier hydrology 1. Theory and synthetic examples Gwenn E; published 12 November 2002. [1] Basal hydrology is acknowledged as a fundamental control on glacier dynamics of existing basal hydrology models is the treatment of the glacier bed as an isolated system. We present

Flowers, Gwenn

71

Multicomponent Transport of Sulfate in a Goethite-Silica Sand System  

E-Print Network [OSTI]

Multicomponent Transport of Sulfate in a Goethite-Silica Sand System at Variable pH and Ionic of protons and sulfate on goethite and silica were used in combination with a one-dimensional mass-transport model to predict the transport of sulfate at variable pH and ionic strength in a goethite-silica system

Sparks, Donald L.

72

Integrated Simulations for Multi-Component Analysis of Gas Turbines : RANS Boundary Conditions  

E-Print Network [OSTI]

More recently the coupling method has also been applied to a Pratt & Whitney gas turbine.7 The RANSIntegrated Simulations for Multi-Component Analysis of Gas Turbines : RANS Boundary Conditions 94305, U.S.A The aero-thermal computation of the flow path of an entire gas turbine engine can

Kim, Sangho

73

Application of the Cell Potential Method To Predict Phase Equilibria of Multicomponent Gas Hydrate Systems  

E-Print Network [OSTI]

Application of the Cell Potential Method To Predict Phase Equilibria of Multicomponent Gas Hydrate the first documentation nearly two centuries ago,2 natural gas clathrate-hydrates, called clathrates, have at understanding and avoiding clathrate formation. More recently, natural gas hydrates have been proposed

Bazant, Martin Z.

74

PHYSICAL REVIEW B 85, 155101 (2012) Electronic properties of layered multicomponent wide-band-gap oxides: A combinatorial approach  

E-Print Network [OSTI]

devices including solar cells, smart windows, and flat panel displays, and they also find application as heating, antistatic, and optical coatings (for select reviews, see Refs. 1­7). Multicomponent TCOs

Medvedeva, Julia E.

75

Head-on collision of ion-acoustic solitary waves in multicomponent plasmas with positrons  

SciTech Connect (OSTI)

The head-on collision between two ion-acoustic solitary waves in an unmagnetized multicomponent plasma consisting of hot ions, hot positrons, and two-electron temperature distributions is investigated using the extended Poincare-Lighthill-Kuo method. The Kortwege-de Vries equations and the analytical phase shifts after the head-on collision of two solitary waves in this multicomponent plasma are obtained. The effects of two different types of isothermal electrons, the ratio of the hot ion temperature to the effective temperature, the ratio of the effective temperature to the positron temperature, the ratio of the number density of positrons to that of electrons species, and the physical processes (either isothermal or adiabatic) on the phase shifts are studied. It is found that these parameters can significantly influence the phase shifts of the solitons. The relevance of this investigation to space and laboratory plasmas is pointed out.

El-Shamy, E. F.; Sabry, R. [Department of Physics, Theoretical Physics Group, Faculty of Science, Mansoura University, Damietta-Branch, New Damietta 34517, Damietta (Egypt); Moslem, W. M. [Department of Physics, Faculty of Science, Port Said University, Port Said (Egypt); Shukla, P. K. [Institut fuer Theoretische Physik IV, Fakultaet fuer Physik und Astronomie, Ruhr-Universitaet Bochum, D-44780 Bochum (Germany)

2010-08-15T23:59:59.000Z

76

Transport properties of multicomponent thermal plasmas: Grad method versus Chapman-Enskog method  

SciTech Connect (OSTI)

Transport properties (thermal conductivity, viscosity, and electrical conductivity) for multicomponent Ar-Fe thermal plasmas at atmospheric pressure have been determined by means of two different methods. The transport coefficients set based on Grad's method is compared with the data obtained when using the Chapman-Enskog's method. Results from both applied methods are in good agreement. It is shown that the Grad method is suitable for the determination of transport properties of the thermal plasmas.

Porytsky, P. [Institute for Nuclear Research, 03680 Kyiv (Ukraine); Krivtsun, I.; Demchenko, V. [Paton Welding Institute, 03680 Kyiv (Ukraine); Reisgen, U.; Mokrov, O.; Zabirov, A. [RWTH Aachen University, ISF-Welding and Joining Institute, 52062 Aachen (Germany); Gorchakov, S.; Timofeev, A.; Uhrlandt, D. [Leibniz Institute for Plasma Science and Technology (INP Greifswald), 17489 Greifswald (Germany)

2013-02-15T23:59:59.000Z

77

A non-equilibrium model for fixed-bed multi-component adiabatic adsorption  

E-Print Network [OSTI]

to enter the bed. Solutions along a z ~ constant char- acteristic are the history of the. volumn element of the bed located a s constant, This physical interpretat1on is a physical approximation of the real world where adsorber discontinuities... 1 3. 3. 2 3e3e3 3. 3. 4 3. 3. 5 Solution of the multi-component adiabatic adsorption equation, . ~ ~ ~ Fluid phase equations. Fixed-bed solid phase equations. , ~ Construction of the solution surface by stepwise integra- tion...

Harwell, Jeffrey Harry

1979-01-01T23:59:59.000Z

78

Mechanism reduction for multicomponent surrogates: A case study using toluene reference fuels  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Strategies and recommendations for performing skeletal reductions of multicomponent surrogate fuels are presented, through the generation and validation of skeletal mechanisms for a three-component toluene reference fuel. Using the directed relation graph with error propagation and sensitivity analysis method followed by a further unimportant reaction elimination stage, skeletal mechanisms valid over comprehensive and high-temperature ranges of conditions were developed at varying levels of detail. These skeletal mechanisms were generated based on autoignition simulations, and validation using ignition delay predictions showed good agreement with the detailed mechanism in the target range of conditions. When validated using phenomena other than autoignition, such as perfectly stirred reactor and laminar flame propagation, tight error control or more restrictions on the reduction during the sensitivity analysis stage were needed to ensure good agreement. In addition, tight error limits were needed for close prediction of ignition delay when varying the mixture composition away from that used for the reduction. In homogeneous compression-ignition engine simulations, the skeletal mechanisms closely matched the point of ignition and accurately predicted species profiles for lean to stoichiometric conditions. Furthermore, the efficacy of generating a multicomponent skeletal mechanism was compared to combining skeletal mechanisms produced separately for neat fuel components; using the same error limits, the latter resulted in a larger skeletal mechanism size that also lacked important cross reactions between fuel components. Based on the present results, general guidelines for reducing detailed mechanisms for multicomponent fuels are discussed.

Niemeyer, Kyle E.; Sung, Chih-Jen

2014-11-01T23:59:59.000Z

79

A combustion model for IC engine combustion simulations with multi-component fuels  

SciTech Connect (OSTI)

Reduced chemical kinetic mechanisms for the oxidation of representative surrogate components of a typical multi-component automotive fuel have been developed and applied to model internal combustion engines. Starting from an existing reduced mechanism for primary reference fuel (PRF) oxidation, further improvement was made by including additional reactions and by optimizing reaction rate constants of selected reactions. Using a similar approach to that used to develop the reduced PRF mechanism, reduced mechanisms for the oxidation of n-tetradecane, toluene, cyclohexane, dimethyl ether (DME), ethanol, and methyl butanoate (MB) were built and combined with the PRF mechanism to form a multi-surrogate fuel chemistry (MultiChem) mechanism. The final version of the MultiChem mechanism consists of 113 species and 487 reactions. Validation of the present MultiChem mechanism was performed with ignition delay time measurements from shock tube tests and predictions by comprehensive mechanisms available in the literature. A combustion model was developed to simulate engine combustion with multi-component fuels using the present MultiChem mechanism, and the model was applied to simulate HCCI and DI engine combustion. The results show that the present multi-component combustion model gives reliable performance for combustion predictions, as well as computational efficiency improvements through the use of reduced mechanism for multi-dimensional CFD simulations. (author)

Ra, Youngchul; Reitz, Rolf D. [Engine Research Center, University of Wisconsin-Madison (United States)

2011-01-15T23:59:59.000Z

80

Thermal extraction analysis of five Los Azufres production wells  

SciTech Connect (OSTI)

Thermal energy extraction from five wells supplying 5-MWe wellhead generators in three zones of the Los Azufres geothermal field has been examined from production and chemical data compiled over 14-years of operation. The data, as annual means, are useful in observing small-scale changes in reservoir performance with continuous production. The chemical components are chloride for quality control and the geothermometer elements for reservoir temperatures. The flowrate and fluid enthalpy data are used to calculate the thermal extraction rates. Integration of these data provides an estimate of the total energy extracted from the zone surrounding the well. The combined production and chemical geothermometer data are used to model the produced fluid as coming from just-penetrating wells for which the annual produced mass originates from a series of concentric hemispheric shells moving out into the reservoir. Estimates are made of the drawdown distance into the reservoir and the far-field conditions.

Kruger, Paul; Quijano, Luis

1995-01-26T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

A Symmetric Free Energy Based Multi-Component Lattice Boltzmann Method  

E-Print Network [OSTI]

We present a lattice Boltzmann algorithm based on an underlying free energy that allows the simulation of the dynamics of a multicomponent system with an arbitrary number of components. The thermodynamic properties, such as the chemical potential of each component and the pressure of the overall system, are incorporated in the model. We derived a symmetrical convection diffusion equation for each component as well as the Navier Stokes equation and continuity equation for the overall system. The algorithm was verified through simulations of binary and ternary systems. The equilibrium concentrations of components of binary and ternary systems simulated with our algorithm agree well with theoretical expectations.

Qun Li; A. J. Wagner

2007-04-26T23:59:59.000Z

82

Arbitrary amplitude ion-acoustic waves in a multicomponent plasma with superthermal species  

SciTech Connect (OSTI)

Properties of fully nonlinear ion-acoustic waves in a multicomponent plasma consisting of warm positive ions, superthermal electrons, as well as positrons, and dust impurities have been investigated. By using the hydrodynamic model for ions and superthermal electron/positron distribution, a Sagdeev potential has been derived. Existence conditions for large amplitude solitary and shock waves are presented. In order to show that the characteristics of the solitary and shock waves are influenced by the plasma parameters, the relevant numerical analysis of the Sagdeev potential is presented. The nonlinear structures, as predicted here, may be associated with the electrostatic perturbations in interstellar medium.

El-Tantawy, S. A. [Department of Physics, Faculty of Science, Port Said University, Port Said 42521 (Egypt); Moslem, W. M. [Department of Physics, Faculty of Science, Port Said University, Port Said 42521 (Egypt); International Center for Advanced Studies in Physical Sciences, Faculty of Physics and Astronomy, Ruhr University Bochum, D-44780 Bochum (Germany)

2011-11-15T23:59:59.000Z

83

Generalization of internal Density Functional Theory and Kohn-Sham scheme to multicomponent systems, and link with traditional DFT  

E-Print Network [OSTI]

We generalize the recently developped "internal" Density Functional Theory (DFT) and Kohn-Sham scheme to multicomponent systems. We obtain a general formalism, applicable for the description of multicomponent self-bound systems (as molecules where the nuclei are treated explicitely, atomic nuclei and mix of 3He and 4He droplets), where the fundamental translational symmetry has been treated correctly. The main difference with traditional DFT is the explicit inclusion of center-of-mass correlations in the functional. A large part of the paper is dedicated to the application to molecules, which permits among other to clarify the approximations that underly traditional DFT.

Jeremie Messud

2011-11-21T23:59:59.000Z

84

Calculation of multicomponent ionic diffusion from zero to high concentration: II. Inclusion of associated ion species  

SciTech Connect (OSTI)

This paper presents a theoretical model of multicomponent ionic diffusion which is valid to high concentration for systems which show ion association. The results of the authors' formulations are contrasted with those of more simplified models for systems containing Na{sub 2}SO{sub 4} and MgSO{sub 4}, as well as for multicomponent natural seawater. The differences between their model and simplified models are significant, especially at high concentration. Inconsistencies which may develop with the use of the simplified approaches are demonstrated. The authors' approach requires considerable data which are not available at temperatures other than 25{degree}C. Therefore, other approaches which are based only on data at infinite dilution are of great interest. They show here that, if chemical potential derivatives are included in the infinite dilution model of Nernst and Hartley which uses only infinite dilution mobilities, the model can be extended to slightly concentrated solutions. This extended Nernst-Hartley model gives good agreement with all of the existing experimental mutual diffusion coefficient data at concentrations below about 0.2 M in the six component system Na-K-Ca-Mg-Cl-SO{sub 4}-H{sub 2}O. This may be the most reliable way to extend infinite dilution data into more concentrated regions. In the systems they have studied, the inclusion of ion-association species for weakly interacting species does not appear to provide significant improvement over the generalized Nernst-Hartley model.

Felmy, A.R.; Weare, J.H. (Univ. of California, San Diego, La Jolla (USA))

1991-01-01T23:59:59.000Z

85

Monte Carlo methods and their analysis for Coulomb collisions in multicomponent plasmas  

SciTech Connect (OSTI)

Highlights: •A general approach to Monte Carlo methods for multicomponent plasmas is proposed. •We show numerical tests for the two-component (electrons and ions) case. •An optimal choice of parameters for speeding up the computations is discussed. •A rigorous estimate of the error of approximation is proved. -- Abstract: A general approach to Monte Carlo methods for Coulomb collisions is proposed. Its key idea is an approximation of Landau–Fokker–Planck equations by Boltzmann equations of quasi-Maxwellian kind. It means that the total collision frequency for the corresponding Boltzmann equation does not depend on the velocities. This allows to make the simulation process very simple since the collision pairs can be chosen arbitrarily, without restriction. It is shown that this approach includes the well-known methods of Takizuka and Abe (1977) [12] and Nanbu (1997) as particular cases, and generalizes the approach of Bobylev and Nanbu (2000). The numerical scheme of this paper is simpler than the schemes by Takizuka and Abe [12] and by Nanbu. We derive it for the general case of multicomponent plasmas and show some numerical tests for the two-component (electrons and ions) case. An optimal choice of parameters for speeding up the computations is also discussed. It is also proved that the order of approximation is not worse than O(?(?)), where ? is a parameter of approximation being equivalent to the time step ?t in earlier methods. A similar estimate is obtained for the methods of Takizuka and Abe and Nanbu.

Bobylev, A.V., E-mail: alexander.bobylev@kau.se [Department of Mathematics, Karlstad University, SE-65188 Karlstad (Sweden); Potapenko, I.F., E-mail: firena@yandex.ru [Keldysh Institute for Applied Mathematics, RAS, 125047 Moscow (Russian Federation)

2013-08-01T23:59:59.000Z

86

A Robust MEMS Based Multi-Component Sensor for 3D Borehole Seismic Arrays  

SciTech Connect (OSTI)

The objective of this project was to develop, prototype and test a robust multi-component sensor that combines both Fiber Optic and MEMS technology for use in a borehole seismic array. The use such FOMEMS based sensors allows a dramatic increase in the number of sensors that can be deployed simultaneously in a borehole seismic array. Therefore, denser sampling of the seismic wave field can be afforded, which in turn allows us to efficiently and adequately sample P-wave as well as S-wave for high-resolution imaging purposes. Design, packaging and integration of the multi-component sensors and deployment system will target maximum operating temperature of 350-400 F and a maximum pressure of 15000-25000 psi, thus allowing operation under conditions encountered in deep gas reservoirs. This project aimed at using existing pieces of deployment technology as well as MEMS and fiber-optic technology. A sensor design and analysis study has been carried out and a laboratory prototype of an interrogator for a robust borehole seismic array system has been assembled and validated.

Paulsson Geophysical Services

2008-03-31T23:59:59.000Z

87

Low-temperature geothermal assessment of the Santa Clara and Virgin River Valleys, Washington County, Utah  

SciTech Connect (OSTI)

Exploration techniques included the following: (1) a temperature survey of springs, (2) chemical analyses and calculated geothermometer temperatures of water samples collected from selected springs and wells, (3) chemical analyses and calculated geothermometer temperatures of spring and well water samples in the literature, (4) thermal gradients measured in accessible wells, and (5) geology. The highest water temperature recorded in the St. George basin is 42/sup 0/C at Pah Tempe Hot Springs. Additional spring temperatures higher than 20/sup 0/C are at Veyo Hot Spring, Washington hot pot, and Green Spring. The warmest well water in the study area is 40/sup 0/C in Middleton Wash. Additional warm well water (higher than 24.5/sup 0/C) is present north of St. George, north of Washington, southeast of St. George, and in Dameron Valley. The majority of the Na-K-Ca calculated reservoir temperatures range between 30/sup 0/ and 50/sup 0/C. Anomalous geothermometer temperatures were calculated for water from Pah Tempe and a number of locations in St. George and vicinity. In addition to the known thermal areas of Pah Tempe and Veyo Hot Spring, an area north of Washington and St. George is delineated in this study to have possible low-temperature geothermal potential.

Budding, K.E.; Sommer, S.N.

1986-01-01T23:59:59.000Z

88

Improvements in geothermometry. Final technical report. Rev  

SciTech Connect (OSTI)

Alkali and alkaline earth geothermometers are useful for estimating geothermal reservoir temperatures, though a general theoretical basis has yet to be established and experimental calibration needs improvement. Equilibrium cation exchange between feldspars provided the original basis for the Na-K and Na-K-Ca geothermometers (Fournier and Truesdell, 1973), but theoretical, field and experimental evidence prove that neither equilibrium nor feldspars are necessary. Here, evidence is summarized in support of these observations, concluding that these geothermometers can be expected to have a surprisingly wide range of applicability, but that the reasons behind such broad applicability are not yet understood. Early experimental work proved that water-rock interactions are slow at low temperatures, so experimental calibration at temperatures below 150/sup 0/ is impractical. Theoretical methods and field data were used instead for all work at low temperatures. Experimental methods were emphasized for temperatures above 150/sup 0/C, and the simplest possible solid and solution compositions were used to permit investigation of one process or question at a time. Unexpected results in experimental work prevented complete integration of the various portions of the investigation.

Potter, J.; Dibble, W.; Parks, G.; Nur, A.

1982-08-01T23:59:59.000Z

89

Cation geothermometry in oil field waters  

SciTech Connect (OSTI)

The assumptions used in the development of cation ratio geothermometers are: (1) the ratios of the cations are controlled by cation exchange between solid silicate phases, (2) aluminum is conserved in the solid phases, and (3) neither hydrogen ions nor CO[sub 2] enter into the net reactions. These assumptions do not apply to oilfield waters where organic species are present and commonly abundant. Nine different published cation geothermometers of Na/K, Na-K-Ca, Na-K-Ca-Mg, and Mg/Li were applied to 309 water samples from both oilfield and geothermal wells. None of the cation geothermometers predicted consistent or accurate temperatures for the oilfield waters. Plots of measured v. predicted temperature for oilfield water samples gave correlation coefficients of less than 0.35. In contrast, those same plots for geothermal water samples within the same temperature range gave correlation coefficients between 0.45 and 0.95. This analysis suggests that the presence of organic species exerts a strong control on the cation ratios. Organic species form complexes of varying stability with the cations. This, in turn, changes the relative concentrations of the cations in solution over that which is expected when cation exchange between silicate phases controls the ratios. Organic complexes also strongly affect pH and P[sub CO[sub 2

Smith, L.K.; Dunn, T.L.; Surdam, R.C. (Univ. of Wyoming, Laramie, WY (United States))

1992-01-01T23:59:59.000Z

90

Final report on LDRD project: A phenomenological model for multicomponent transport with simultaneous electrochemical reactions in concentrated solutions  

SciTech Connect (OSTI)

A phenomenological model was developed for multicomponent transport of charged species with simultaneous electrochemical reactions in concentrated solutions, and was applied to model processes in a thermal battery cell. A new general framework was formulated and implemented in GOMA (a multidimensional, multiphysics, finite-element computer code developed and being enhanced at Sandia) for modeling multidimensional, multicomponent transport of neutral and charged species in concentrated solutions. The new framework utilizes the Stefan-Maxwell equations that describe multicomponent diffusion of interacting species using composition-insensitive binary diffusion coefficients. The new GOMA capability for modeling multicomponent transport of neutral species was verified and validated using the model problem of ternary gaseous diffusion in a Stefan tube. The new GOMA-based thermal battery computer model was verified using an idealized battery cell in which concentration gradients are absent; the full model was verified by comparing with that of Bernardi and Newman (1987) and validated using limited thermal battery discharge-performance data from the open literature (Dunning 1981) and from Sandia (Guidotti 1996). Moreover, a new Liquid Chemkin Software Package was developed, which allows the user to handle manly aspects of liquid-phase kinetics, thermodynamics, and transport (particularly in terms of computing properties). Lastly, a Lattice-Boltzmann-based capability was developed for modeling pore- or micro-scale phenomena involving convection, diffusion, and simplified chemistry; this capability was demonstrated by modeling phenomena in the cathode region of a thermal battery cell.

CHEN,KEN S.; EVANS,GREGORY H.; LARSON,RICHARD S.; NOBLE,DAVID R.; HOUF,WILLIAM G.

2000-01-01T23:59:59.000Z

91

Effects of liquid conductivity differences on multi-component sample injection, pumping and stacking in microfluidic chips  

E-Print Network [OSTI]

Effects of liquid conductivity differences on multi-component sample injection, pumping-chip processing, or by design. The two situations studied here are sample pumping (where bulk transport in a straight-cross channel configuration is applied here to both pumping and stacking cases. A key

Le Roy, Robert J.

92

Advanced Modeling of Multicomponent Vaporization/Condensation Phenomena for a Reactor Safety Analysis Code SIMMER-III  

SciTech Connect (OSTI)

It is believed that the numerical simulation of thermal-hydraulic phenomena of multiphase, multicomponent flows in a reactor core is essential to investigate core disruptive accidents (CDAs) of liquid-metal fast reactors. A new multicomponent vaporization/condensation (V/C) model was developed to provide a generalized model for a fast reactor safety analysis code SIMMER-III, which analyzes relatively short-time-scale phenomena relevant to accident sequences of CDAs. The model characterizes the V/C process associated with phase transition through heat-transfer and mass-diffusion limited models to follow the time evolution of the rector core under CDA conditions. The heat-transfer limited model describes the nonequilibrium phase-transition processes occurring at interfaces, while the mass-diffusion limited model is employed to represent effects of noncondensable gases and multicomponent mixture on V/C processes. Verification of the model and method employed in the multicomponent V/C model of SIMMER-III was performed successfully by analyzing two series of condensation experiments. (authors)

Koji Morita; Tatsuya Matsumoto; Ryo Akasaka; Kenji Fukuda [Kyushu University, 6-10-1, Hakozaki, Higashi-ku, Fukuoka 812-81 (Japan); Tohru Suzuki; Yoshiharu Tobita; Hidemasa Yamano; Satoru Kondo [Japan Nuclear Cycle Development Institute 4002, Narita, O-arai, Ibaraki 311-1393 (Japan)

2002-07-01T23:59:59.000Z

93

Henn-Lecordier -AVS 99 -MS -WeM10 1 Reaction Sensing in Multicomponent CVD Processes  

E-Print Network [OSTI]

: average specific heat ratio Mavg: average molecular weight · Multicomponent systems ­ F = f ( Average · Remote downstream sampling ­ poor repeatability · Sampling at reactor outlet ­ minimize wall reaction in acoustic sensor for real-time sensing requires 2.5 L.Torr/s throughput 0.5 Torr Remote sampling300 Torr 20

Rubloff, Gary W.

94

Coupling Multi-Component Models with MPH on Distributed MemoryComputer Architectures  

SciTech Connect (OSTI)

A growing trend in developing large and complex applications on today's Teraflop scale computers is to integrate stand-alone and/or semi-independent program components into a comprehensive simulation package. One example is the Community Climate System Model which consists of atmosphere, ocean, land-surface and sea-ice components. Each component is semi-independent and has been developed at a different institution. We study how this multi-component, multi-executable application can run effectively on distributed memory architectures. For the first time, we clearly identify five effective execution modes and develop the MPH library to support application development utilizing these modes. MPH performs component-name registration, resource allocation and initial component handshaking in a flexible way.

He, Yun; Ding, Chris

2005-03-24T23:59:59.000Z

95

Technical status report on the prediction of amorphous phase separation in multicomponent borosilicate glasses. Revision 0  

SciTech Connect (OSTI)

This status report describes the current status for predicting of amorphous phase separation in multicomponent borosilicate glasses and the two major development criteria (composition and thermal history). The goal of this subtask is to perform targeted research activities to define and, where applicable, extend the boundaries of existing phase stability models that restrict HLW glass waste loading. Specifically, the focus will be on delimiting boundaries for immiscible phase separation. The development of data, understanding, and quantitative description for composition and kinetic effects on the development of amorphous phase separation will continue in FY98. This effort will provide insight into the compositional effects on phase stability and will lead to a better understanding of the methods used to predict the development of amorphous phase separation in HLW glasses.

Peeler, D.K.

1998-12-31T23:59:59.000Z

96

Analysis of Substrate Access to Active Sites in Bacterial Multicomponent Monooxygenase Hydroxylases: X-Ray Crystal Structure of Xenon-Pressurized Phenol Hydroxylase from Pseudomonas Sp Ox1  

E-Print Network [OSTI]

In all structurally characterized bacterial multicomponent monooxygenase (BMM) hydroxylase proteins, a series of hydrophobic cavities in the ?-subunit trace a conserved path from the protein exterior to the carboxylate-bridged ...

McCormick, Michael S.

97

Three-dimensional stability of dust-ion acoustic solitary waves in a magnetized multicomponent dusty plasma with negative ions  

SciTech Connect (OSTI)

Using the small-k expansion perturbation method, the three-dimensional stability of dust-ion acoustic solitary waves (DIASWs) in a magnetized multicomponent dusty plasma containing negative heavy ions and stationary variable-charge dust particles is analyzed. A nonlinear Zakharov-Kuznetsov equation adequate for describing these solitary structures is derived. Moreover, the basic features of the DIASWs are studied. The determination of the stability region leads to two different cases depending on the oblique propagation angle. In addition, the growth rate of the produced waves is estimated. The increase of either the negative ion number density or their temperatures or even the number density of the dust grains results in reducing the wave growth rate. Finally, the present results should elucidate the properties of DIASWs in a multicomponent plasma with negative ions, particularly in laboratory experiment and plasma process.

El-Taibany, W. F.; El-Shamy, E. F. [Department of Physics, Faculty of Science, Mansoura University, Damietta Branch, P.O. 34517, Damietta El-Gedida (Egypt); El-Bedwehy, N. A. [Department of Mathematics, Faculty of Science, Mansoura University, Damietta Branch, P.O. 34517, Damietta El-Gedida (Egypt)

2011-03-15T23:59:59.000Z

98

HYDROGEOCHEM: A coupled model of HYDROlogic transport and GEOCHEMical equilibria in reactive multicomponent systems  

SciTech Connect (OSTI)

This report presents the development of a hydrogeochemical transport model for multicomponent systems. The model is designed for applications to proper hydrological setting, accommodation of complete suite of geochemical equilibrium processes, easy extension to deal with chemical kinetics, and least constraints of computer resources. The hydrological environment to which the model can be applied is the heterogeneous, anisotropic, saturated-unsaturated subsurface media under either transient or steady state flow conditions. The geochemical equilibrium processes included in the model are aqueous complexation, adsorption-desorption, ion exchange, precipitation-dissolution, redox, and acid-base reactions. To achieve the inclusion of the full complement of these geochemical processes, total analytical concentrations of all chemical components are chosen as the primary dependent variables in the hydrological transport equations. Attendant benefits of this choice are to make the extension of the model to deal with kinetics of adsorption-desorption, ion exchange, precipitation-dissolution, and redox relatively easy. To make the negative concentrations during the iteration between the hydrological transport and geochemical equilibrium least likely, an implicit form of transport equations are proposed. To alleviate severe constraints of computer resources in terms of central processing unit (CPU) time and CPU memory, various optional numerical schemes are incorporated in the model. The model consists of a hydrological transport module and geochemical equilibrium module. Both modules were thoroughly tested in code consistency and were found to yield plausible results. The model is verified with ten examples. 79 refs., 21 figs., 17 tabs.

Yeh, G.T.; Tripathi, V.S.

1990-11-01T23:59:59.000Z

99

Multiphase flow and multicomponent reactive transport model of the ventilation experiment in Opalinus clay  

SciTech Connect (OSTI)

During the construction and operational phases of a high-level radioactive waste (HLW) repository constructed in a clay formation, ventilation of underground drifts will cause desaturation and oxidation of the rock. The Ventilation Experiment (VE) was performed in a 1.3 m diameter unlined horizontal microtunnel on Opalinus clay at Mont Terri underground research laboratory in Switzerland to evaluate the impact of desaturation on rock properties. A multiphase flow and reactive transport model of VE is presented here. The model accounts for liquid, vapor and air flow, evaporation/condensation and multicomponent reactive solute transport with kinetic dissolution of pyrite and siderite and local-equilibrium dissolution/precipitation of calcite, ferrihydrite, dolomite, gypsum and quartz. Model results reproduce measured vapor flow, liquid pressure and hydrochemical data and capture the trends of measured relative humidities, although such data are slightly overestimated near the rock interface due to uncertainties in the turbulence factor. Rock desaturation allows oxygen to diffuse into the rock and triggers pyrite oxidation, dissolution of calcite and siderite, precipitation of ferrihydrite, dolomite and gypsum and cation exchange. pH in the unsaturated rock varies from 7.8 to 8 and is buffered by calcite. Computed changes in the porosity and the permeability of Opalinus clay in the unsaturated zone caused by oxidation and mineral dissolution/precipitation are smaller than 5%. Therefore, rock properties are not expected to be affected significantly by ventilation of underground drifts during construction and operational phases of a HLW repository in clay.

Zheng, L.; Samper, J.; Montenegro, L.; Major, J.C.

2008-10-15T23:59:59.000Z

100

Effects of multi-component diffusion and heat release on laminar diffusion flame liftoff  

SciTech Connect (OSTI)

Numerical simulations were conducted of the liftoff and stabilization phenomena of laminar jet diffusion flames of inert-diluted C{sub 3}H{sub 8} and CH{sub 4} fuels. Both non-reacting and reacting jets were investigated, including multi-component diffusivities and heat release effects (buoyancy and gas expansion). The role of Schmidt number for non-reacting jets was investigated, with no conclusive Schmidt number criterion for liftoff previously arrived at in similarity solutions. The cold-flow simulation for He-diluted CH{sub 4} fuel does not predict flame liftoff; however, adding heat release reaction lead to the prediction of liftoff, which is consistent with experimental observations. Including reaction was also found to improve liftoff height prediction for C{sub 3}H{sub 8} flames, with the flame base location differing from that in the similarity solution - the intersection of the stoichiometric and iso-velocity (equal to 1-D flame speed) is not necessary for flame stabilization (and thus liftoff). Possible mechanisms other than that proposed for similarity solution may better help to explain the stabilization and liftoff phenomena. (author)

Li, Zhiliang; Chen, Ruey-Hung [Department of Mechanical, Materials and Aerospace Engineering, University of Central Florida, Orlando, FL 32816-2450 (United States); Phuoc, Tran X. [National Energy Technology Laboratory, Department of Energy, P.O. Box 10940, MS 84-340, Pittsburgh, PA 15261 (United States)

2010-08-15T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Vaporization modeling of petroleum-biofuel drops using a hybrid multi-component approach  

SciTech Connect (OSTI)

Numerical modeling of the vaporization characteristics of multi-component fuel mixtures is performed in this study. The fuel mixtures studied include those of binary components, biodiesel, diesel-biodiesel, and gasoline-ethanol. The use of biofuels has become increasingly important for reasons of environmental sustainability. Biofuels are often blended with petroleum fuels, and the detailed understanding of the vaporization process is essential to designing a clean and efficient combustion system. In this study, a hybrid vaporization model is developed that uses continuous thermodynamics to describe petroleum fuels and discrete components to represent biofuels. The model is validated using the experimental data of n-heptane, n-heptane-n-decane mixture, and biodiesel. Since biodiesel properties are not universal due to the variation in feedstock, methods for predicting biodiesel properties based on the five dominant fatty acid components are introduced. Good levels of agreement in the predicted and measured drop size histories are obtained. Furthermore, in modeling the diesel-biodiesel drop, results show that the drop lifetime increases with the biodiesel concentration in the blend. During vaporization, only the lighter components of diesel fuel vaporize at the beginning. Biodiesel components do not vaporize until some time during the vaporization process. On the other hand, results of gasoline-ethanol drops indicate that both fuels start to vaporize once the process begins. At the beginning, the lighter components of gasoline have a slightly higher vaporization rate than ethanol. After a certain time, ethanol vaporizes faster than the remaining gasoline components. At the end, the drop reduces to a regular gasoline drop with heavier components. Overall, the drop lifetime increases as the concentration of ethanol increases in the drop due to the higher latent heat. (author)

Zhang, Lei; Kong, Song-Charng [Department of Mechanical Engineering, Iowa State University, 2025 Black Engineering Building, Ames, IA 50011 (United States)

2010-11-15T23:59:59.000Z

102

Well-posedness, global existence and blow-up phenomena for an integrable multi-component Camassa-Holm system  

E-Print Network [OSTI]

This paper is concerned with a multi-component Camassa-Holm system, which has been proven to be integrable and has peakon solutions. This system includes many one-component and two-component Camassa-Holm type systems as special cases. In this paper, we first establish the local well-posedness and a continuation criterion for the system, then we present several global existence or blow-up results for two important integrable two-component subsystems. Our obtained results cover and improve recent results in \\cite{Gui,yan}.

Zeng Zhang; Zhaoyang Yin

2014-11-24T23:59:59.000Z

103

Multicomponent aerosol dynamic of the Pb-O[sub 2] system in a bench scale flame incinerator  

SciTech Connect (OSTI)

The article gives results of a study to understand the formation and growth of lead particles in a flame incinerator. A bench scale flame incinerator was used to perform controlled experiments with lead acetate as a test compound. A dilution probe (in conjunction with real-time aerosol instruments) was used to measure the evolution of the particle size distribution at different locations in the flame region. A multicomponent lognormal aerosol model was developed accounting for the chemistry of the lead-oxygen system, and for such aerosol dynamic phenomena as nucleation, coagulation, and condensation. Reasonable agreement was obtained between the predictions of the model using appropriate kinetic parameters and the experimental results.

Lin, W.Y.; Sethi, V.; Biswas, P.

1992-01-01T23:59:59.000Z

104

Second-order perturbations of cosmological fluids: Relativistic effects of pressure, multi-component, curvature, and rotation  

E-Print Network [OSTI]

We present general relativistic correction terms appearing in Newton's gravity to the second-order perturbations of cosmological fluids. In our previous work we have shown that to the second-order perturbations, the density and velocity perturbation equations of general relativistic zero-pressure, irrotational, single-component fluid in a flat background coincide exactly with the ones known in Newton's theory. Here, we present the general relativistic second-order correction terms arising due to (i) pressure, (ii) multi-component, (iii) background curvature, and (iv) rotation. In case of multi-component zero-pressure, irrotational fluids under the flat background, we effectively do not have relativistic correction terms, thus the relativistic result again coincides with the Newtonian ones. In the other three cases we generally have pure general relativistic correction terms. In case of pressure, the relativistic corrections appear even in the level of background and linear perturbation equations. In the presence of background curvature, or rotation, pure relativistic correction terms directly appear in the Newtonian equations of motion of density and velocity perturbations to the second order. In the small-scale limit (far inside the horizon), relativistic equations including the rotation coincide with the ones in Newton's gravity.

J. Hwang; H. Noh

2007-04-16T23:59:59.000Z

105

Cooling rate and size effects on the medium-range structure of multicomponent oxide glasses simulated by molecular dynamics  

SciTech Connect (OSTI)

A set of molecular dynamics simulations were performed to investigate the effect of cooling rate and system size on the medium-range structure of melt-derived multicomponent silicate glasses, represented by the quaternary 45S5 Bioglass composition. Given the significant impact of the glass degradation on applications of these materials in biomedicine and nuclear waste disposal, bulk structural features which directly affect the glass dissolution process are of particular interest. Connectivity of the silicate matrix, ion clustering and nanosegregation, distribution of ring and chain structural patterns represent critical features in this context, which can be directly extracted from the models. A key issue is represented by the effect of the computational approach on the corresponding glass models, especially in light of recent indications questioning the suitability of conventional MD approaches (that is, involving melt-and-quench of systems containing ?10{sup 3} atoms at cooling rates of 5-10 K/ps) when applied to model these glasses. The analysis presented here compares MD models obtained with conventional and nonconventional cooling rates and system sizes, highlighting the trend and range of convergence of specific structural features in the medium range. The present results show that time-consuming computational approaches involving much lower cooling rates and/or significantly larger system sizes are in most cases not necessary in order to obtain a reliable description of the medium-range structure of multicomponent glasses. We identify the convergence range for specific properties and use them to discuss models of several glass compositions for which a possible influence of cooling-rate or size effects had been previously hypothesized. The trends highlighted here represent an important reference to obtain reliable models of multicomponent glasses and extract converged medium-range structural features which affect the glass degradation and thus their application in different fields. In addition, as a first application of the present findings, the fully converged structure of the 45S5 glass was further analyzed to shed new light on several dissolution-related features whose interpretation has been rather controversial in the past.

Tilocca, Antonio [Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ (United Kingdom)] [Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ (United Kingdom)

2013-09-21T23:59:59.000Z

106

Modeling of metallic aerosol formation in a multicomponent system at high temperatures using a discrete-sectional model. Appendix 7  

SciTech Connect (OSTI)

A multicomponent discrete-sectional model was used to simulate the fate of lead in a high temperature system. The results show the ability of the developed model to simulate metallic aerosol systems at high temperatures. The PbO reaction and nucleation rate can be determined by comparing the simulations and the experimental data. Condensation on SiO{sub 2} particle surfaces is found important for removing the PbO vapor. The value of the accommodation factor that is applied to account for nonidealities in the condensation process are determined. The differences between the nanosized particles and the bulk particles are elucidated. The use of such a model helped to understand the effects of various mechanisms in determining the metal oxide vapor concentration profile and in establishing the ultimate particle size distribution.

NONE

1997-02-01T23:59:59.000Z

107

An experimental investigation into the effects of fluid composition on certain geothermometry methods  

E-Print Network [OSTI]

at the lower temperatures, and 5) thermal waters do not mix with shallower, cooler ground water. Silica geothermometer The dissolved silica content of geothermal water is used in geothermometry because silica is present in most geologic settings... that the time required to attain equilibrium was 100 hours at 200 C and from four to sixteen hours at 0 360 C. Work at lower temperatures (25 C, 60 -100 C) was done by van Lier, de Bruyn, and Overbeek (1960) using finely ground quartz particles...

Pope, Leslie Anne

1985-01-01T23:59:59.000Z

108

DESIGN, SYNTHESIS AND STUDY OF MULTI-COMPONENT AND INTEGRATED SYSTEMS FOR LIGHT-DRIVEN HYDROGEN GENERATION  

SciTech Connect (OSTI)

The research focussed on fundamental problems in the conversion of light to stored chemical energy. Specifically, work was completed on the design, synthesis and study of multi-component super- and supramolecular systems for photoinduced charge separation, one of the key steps in artificial photosynthesis, and on the use of these and related systems for the photochemical generation of H2 from water. At the center of these systems are chromophores comprised of square planar coordinated Pt(II) ions with arylacetylide and either diimine or terpyridyl ligands. Previous work had shown that the chromophores are photoluminescent in fluid solution with long-lived metal-to-ligand charge transfer (3MLCT) excited states that are necessarily directional. An advance which set the stage for a number of proposed studies was the light-driven production of hydrogen from water using a Pt(terpyridyl)(arylacetylide)+ chromophore and a sacrificial electron donor. The reaction is catalytic and appears to rival previously reported ruthenium bipyridyl systems in terms of H2 production. Variation of system components and mechanistic studies were conducted to understand better the individual steps in the overall process and how to improve its efficiency. Success with light driven H2 generation was employed as a key probe as new systems were constructed consisting of triads for photoinduced charge separation placed in close proximity to the H2 generating catalyst - a Pt colloid - through direct linkage or supramolecular interactions with the polymer used to stabilize the colloid. In order to prepare new donor-chromophore-acceptor (D-C-A) triads and associated D-C and C-A dyads, new ligands were synthesized having functional groups for different coupling reactions such as simple amide formation and Pd-catalyzed coupling. In these systems, the donor was attached to the arylacetylide ligands and the acceptor was linked to the diimine or terpyridyl chelate. Research under the contract proved successful in the development of synthetic methodologies to make multi-component systems designed so as to maintain electronic communication between components held in a defined spatial arrangement. Systems effective for light driven H2 generation were examined by photophysical methods including transient absorption spectroscopy to observe charge-separated states and chart their dynamics. Quantum yields for hydrogen production were also measured. Additional studies examined the effectiveness of these systems for H2 generation and involved the development of new catalysts and systems based thereon. From these studies, a better understanding of initial steps in the light driven generation of hydrogen were obtained.

Professor Richard Eisenberg

2012-07-18T23:59:59.000Z

109

Improved Predictions of Carbon Tetrachloride Contaminant Flow and Transport: Implementation of Kinetic Volatilization and Multicomponent NAPL Behavior  

SciTech Connect (OSTI)

Carbon tetrachloride (CT) was discharged to waste sites that are included in the 200-PW-1 Operable Unit in Hanford 200 West Area. Fluor Hanford, Inc. is conducting a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) remedial investigation/feasibility study (RI/FS) for the 200-PW-1 Operable Unit. The RI/FS process and remedial investigations for the 200-PW-1, 200 PW-3, and 200-PW-6 Operable Units are described in the Plutonium/Organic-Rich Process Condensate/Process Waste Groups Operable Unit RI/FS Work Plan. As part of this overall effort, Pacific Northwest National Laboratory (PNNL) was contracted to improve the STOMP simulator (White and Oostrom, 2006) by incorporating kinetic volatilization of nonaqueous phase liquids (NAPL) and multicomponent flow and transport. This work supports the U.S. Department of Energy's (DOE's) efforts to characterize the nature and distribution of CT in the 200 West Area and subsequently select an appropriate final remedy. Previous numerical simulation results with the STOMP simulator have overestimated the effect of soil vapor extraction (SVE) on subsurface CT, showing rapid removal of considerably more CT than has actually been recovered so far. These previous multiphase simulations modeled CT mass transfer between phases based on equilibrium partitioning. Equilibrium volatilization can overestimate volatilization because mass transfer limitations present in the field are not considered. Previous simulations were also conducted by modeling the NAPL as a single component, CT. In reality, however, the NAPL mixture disposed of at the Hanford site contained several non-volatile and nearly insoluble organic components, resulting in time-variant fluid properties as the CT component volatilized or dissolved over time. Simulation of CT removal from a DNAPL mixture using single-component DNAPL properties typically leads to an overestimation of CT removal. Other possible reasons for the discrepancy between observed and simulated CT mass removal during SVE are differences between the actual and simulated (1) SVE flow rates, (2) fluid-media properties, and (3) disposal history (volumes, rates, and timing). In this report, numerical implementation of kinetic volatilization and multicomponent DNAPL flow and transport into the STOMP simulator (White and Oostrom, 2006) is described. The results of several test cases are presented and explained. The addition of these two major code enhancements increases the ability of the STOMP simulator to model complex subsurface flow and transport processes involving CT at the Hanford site.

Oostrom, Martinus; Zhang, Z. F.; Freedman, Vicky L.; Tartakovsky, Guzel D.

2008-09-29T23:59:59.000Z

110

Mean-field approach in the multi-component gas of interacting particles applied to relativistic heavy-ion collisions  

E-Print Network [OSTI]

Generalized mean-field approach for thermodynamic description of relativistic single- and multi-component gas in the grand canonical ensemble is formulated. In the framework of the proposed approach different phenomenological excluded-volume procedures are presented and compared to the existing ones. The mean-field approach is then used to effectively include hard-core repulsion in hadron-resonance gas model for description of chemical freeze-out in heavy-ion collisions. We calculate the collision energy dependence of several quantities for different values of hard-core hadron radius and for different excluded-volume procedures such as van der Waals and Carnahan-Starling models. It is shown that a choice of the excluded-volume model becomes important for large particle densities, and for large enough values of hadron radii ($r\\gtrsim0.9$ fm) there can be a sizable difference between different excluded-volume procedures used to describe the chemical freeze-out in heavy-ion collisions. For the smaller and more commonly used values of hard-core hadron radii ($r\\lesssim0.5$ fm) the van der Waals excluded-volume procedure is shown to be sufficient.

D. Anchishkin; V. Vovchenko

2015-01-23T23:59:59.000Z

111

A one-dimensional sectional model to simulate multicomponent aerosol dynamics in the marine boundary layer 1. Model description  

SciTech Connect (OSTI)

A one-dimensional, multicomponent sectional model has been developed to simulate the temporal and vertical variations of the aerosol size distribution and composition in the marine boundary layer (MBL). An important aspect of the model is its ability to handle the transport of aerosols in an atmosphere with humidity gradients with no numerical diffusion caused by the swelling and shrinking of the particles as they move through the humidity gradients. This is achieved by rewriting the aerosol general dynamical equation (GDE) in terms of dry radius thus transferring all variations in radius caused by temporal and spatial humidity variations to the rate coefficients appearing in the equations. The model then solves the new GDE in fixed dry size sections, with the humidity dependence of the processes now included in variable coefficients. This procedure also results in correct gradient transport. A limiting assumption is that the particles equilibrate instantaneously with the ambient water vapor. This assumption limits the maximum particle size which can be treated in the model to ambient (wet) radii less than about 30 {mu}m. All processes currently believed to be important in shaping the MBL size distribution are included in the current version of the model. These include generation of sea-salt aerosol at the ocean surface, nucleation of new particles, coagulation, growth due to condensation of gas-phase reaction products, growth due to sulfate formation during cloud processing, precipitation scavenging, surface deposition, turbulent mixing, gravitational settling, and exchange with the free troposphere. Simple gas-phase chemistry which includes the oxidation of dimethylsulfide and SO{sub 2} to sulfate is incorporated in the current version of the model. {copyright} 1998 American Geophysical Union

Fitzgerald, J.W.; Hoppel, W.A. [Remote Sensing Division, Naval Research Laboratory, Washington, District of Columbia (United States)] [Remote Sensing Division, Naval Research Laboratory, Washington, District of Columbia (United States); Gelbard, F. [Modeling and Analysis Department, Sandia National Laboratories, Albuquerque, New Mexico (United States)] [Modeling and Analysis Department, Sandia National Laboratories, Albuquerque, New Mexico (United States)

1998-07-01T23:59:59.000Z

112

Nonaqueous Phase Liquid Dissolution in Porous Media: Multi-Scale Effects of Multi-Component Dissolution Kinetics on Cleanup Time  

SciTech Connect (OSTI)

Industrial organic solvents such as trichloroethylene (TCE) and tetrachloroethylene (PCE) constitute a principal class of groundwater contaminants. Cleanup of groundwater plume source areas associated with these compounds is problematic, in part, because the compounds often exist in the subsurface as dense nonaqueous phase liquids (DNAPLs). Ganglia (or 'blobs') of DNAPL serve as persistent sources of contaminants that are difficult to locate and remediate (e.g. Fenwick and Blunt, 1998). Current understanding of the physical and chemical processes associated with dissolution of DNAPLs in the subsurface is incomplete and yet is critical for evaluating long-term behavior of contaminant migration, groundwater cleanup, and the efficacy of source area cleanup technologies. As such, a goal of this project has been to contribute to this critical understanding by investigating the multi-phase, multi-component physics of DNAPL dissolution using state-of-the-art experimental and computational techniques. Through this research, we have explored efficient and accurate conceptual and numerical models for source area contaminant transport that can be used to better inform the modeling of source area contaminants, including those at the LLNL Superfund sites, to re-evaluate existing remediation technologies, and to inspire or develop new remediation strategies. The problem of DNAPL dissolution in natural porous media must be viewed in the context of several scales (Khachikian and Harmon, 2000), including the microscopic level at which capillary forces, viscous forces, and gravity/buoyancy forces are manifested at the scale of individual pores (Wilson and Conrad, 1984; Chatzis et al., 1988), the mesoscale where dissolution rates are strongly influenced by the local hydrodynamics, and the field-scale. Historically, the physico-chemical processes associated with DNAPL dissolution have been addressed through the use of lumped mass transfer coefficients which attempt to quantify the dissolution rate in response to local dissolved-phase concentrations distributed across the source area using a volume-averaging approach (Figure 1). The fundamental problem with the lumped mass transfer parameter is that its value is typically derived empirically through column-scale experiments that combine the effects of pore-scale flow, diffusion, and pore-scale geometry in a manner that does not provide a robust theoretical basis for upscaling. In our view, upscaling processes from the pore-scale to the field-scale requires new computational approaches (Held and Celia, 2001) that are directly linked to experimental studies of dissolution at the pore scale. As such, our investigation has been multi-pronged, combining theory, experiments, numerical modeling, new data analysis approaches, and a synthesis of previous studies (e.g. Glass et al, 2001; Keller et al., 2002) aimed at quantifying how the mechanisms controlling dissolution at the pore-scale control the long-term dissolution of source areas at larger scales.

McNab, W; Ezzedine, S; Detwiler, R

2007-02-26T23:59:59.000Z

113

Notes on Well-Posed, Ensemble Averaged Conservation Equations for Multiphase, Multi-Component, and Multi-Material Flows  

SciTech Connect (OSTI)

At the INL researchers and engineers routinely encounter multiphase, multi-component, and/or multi-material flows. Some examples include: Reactor coolant flows Molten corium flows Dynamic compaction of metal powders Spray forming and thermal plasma spraying Plasma quench reactor Subsurface flows, particularly in the vadose zone Internal flows within fuel cells Black liquor atomization and combustion Wheat-chaff classification in combine harvesters Generation IV pebble bed, high temperature gas reactor The complexity of these flows dictates that they be examined in an averaged sense. Typically one would begin with known (or at least postulated) microscopic flow relations that hold on the “small” scale. These include continuum level conservation of mass, balance of species mass and momentum, conservation of energy, and a statement of the second law of thermodynamics often in the form of an entropy inequality (such as the Clausius-Duhem inequality). The averaged or macroscopic conservation equations and entropy inequalities are then obtained from the microscopic equations through suitable averaging procedures. At this stage a stronger form of the second law may also be postulated for the mixture of phases or materials. To render the evolutionary material flow balance system unique, constitutive equations and phase or material interaction relations are introduced from experimental observation, or by postulation, through strict enforcement of the constraints or restrictions resulting from the averaged entropy inequalities. These averaged equations form the governing equation system for the dynamic evolution of these mixture flows. Most commonly, the averaging technique utilized is either volume or time averaging or a combination of the two. The flow restrictions required for volume and time averaging to be valid can be severe, and violations of these restrictions are often found. A more general, less restrictive (and far less commonly used) type of averaging known as ensemble averaging can also be used to produce the governing equation systems. In fact volume and time averaging can be viewed as special cases of ensemble averaging. Ensemble averaging is beginning to gain some notice, for example the general-purpose multi-material flow simulation code CFDLib under continuing developed at the Los Alamos National Laboratory [Kashiwa and Rauenzahn 1994] is based on an ensemble averaged formulation. The purpose of this short note is to give an introduction to the ensemble averaging methodology and to show how ensemble averaged balance equations and entropy inequality can be obtained from the microscopic balances. It then details some seven-equation, two-pressure, two-velocity hyperbolic, well-posed models for two-phase flows. Lastly, a simple example is presented of a model in which the flow consists of two barotropic fluids with no phase change in which an equilibrium pressure equation is obtained in the spirit of pressure-based methods of computational fluid dynamics.

Ray A. Berry

2005-07-01T23:59:59.000Z

114

A near-infrared census of the multi-component stellar structure of early-type dwarf galaxies in the Virgo cluster  

E-Print Network [OSTI]

The fraction of star-forming to quiescent dwarf galaxies varies from almost infinity in the field to zero in the centers of rich galaxy clusters. What is causing this pronounced morphology-density relation? What do quiescent dwarf galaxies look like when studied in detail, and what conclusions can be drawn about their formation mechanism? Here we study a nearly magnitude-complete sample (-19 deep near-infrared images from the SMAKCED project. We fit two-dimensional models with optional inner and outer components, as well as bar and lens components (in ~15% of the galaxies), to the galaxy images. While a single S\\'ersic function may approximate the overall galaxy structure, it does not entirely capture the light distribution of two-thirds of our galaxies, for which multi-component models provide a better fit. This fraction of complex galaxies shows a strong dependence on luminosity, being larger for brighter objects. We analyze the global and compone...

Janz, J; Lisker, T; Salo, H; Peletier, R F; Niemi, S -M; Toloba, E; Hensler, G; Falcón-Barroso, J; Boselli, A; Brok, M den; Hansson, K S A; Meyer, H T; Ry?, A; Paudel, S

2013-01-01T23:59:59.000Z

115

Development of multicomponent hybrid density functional theory with polarizable continuum model for the analysis of nuclear quantum effect and solvent effect on NMR chemical shift  

SciTech Connect (OSTI)

We have developed the multicomponent hybrid density functional theory [MC-(HF+DFT)] method with polarizable continuum model (PCM) for the analysis of molecular properties including both nuclear quantum effect and solvent effect. The chemical shifts and H/D isotope shifts of the picolinic acid N-oxide (PANO) molecule in chloroform and acetonitrile solvents are applied by B3LYP electron exchange-correlation functional for our MC-(HF+DFT) method with PCM (MC-B3LYP/PCM). Our MC-B3LYP/PCM results for PANO are in reasonable agreement with the corresponding experimental chemical shifts and isotope shifts. We further investigated the applicability of our method for acetylacetone in several solvents.

Kanematsu, Yusuke; Tachikawa, Masanori [Quantum Chemistry Division, Yokohama City University, Seto 22-2, Kanazawa-ku, Yokohama 236-0027 (Japan)] [Quantum Chemistry Division, Yokohama City University, Seto 22-2, Kanazawa-ku, Yokohama 236-0027 (Japan)

2014-04-28T23:59:59.000Z

116

Investigation of warm-cloud microphysics using a multi-component cloud model: Interactive effects of the aerosol spectrum. Master's thesis  

SciTech Connect (OSTI)

Clouds, especially low, warm, boundary-layer clouds, play an important role in regulating the earth's climate due to their significant contribution to the global albedo. The radiative effects of individual clouds are controlled largely by cloud microstructure, which is itself sensitive to the concentration and spectral distribution of the atmospheric aerosol. Increases in aerosol particle concentrations from anthropogenic activity could result in increased cloud albedo and global cloudiness, increasing the amount of reflected solar radiation. However, the effects of increased aerosol particle concentrations could be offset by the presence of giant or ultragiant aerosol particles. A one-dimensional, multi-component microphysical cloud model has been used to demonstrate the effects of aerosol particle spectral variations on the microstructure of warm clouds. Simulations performed with this model demonstrate that the introduction of increased concentrations of giant aerosol particles has a destabilizing effect on the cloud microstructure. Also, it is shown that warm-cloud microphysical processes modify the aerosol particle spectrum, favoring the generation of the largest sized particles via the collision-coalescence process. These simulations provide further evidence that the effect of aerosol particles on cloud microstructure must be addressed when considering global climate forecasts.

Zahn, S.G.

1993-12-01T23:59:59.000Z

117

Multicomponent Seismic Analysis and Calibration to Improve Recovery from Algal Mounds: Application to the Roadrunner/Towaoc area of the Paradox Basin, UTE Mountain UTE Reservation, Colorado  

SciTech Connect (OSTI)

The goals of this project were: (1) To enhance recovery of oil contained within algal mounds on the Ute Mountain Ute tribal lands. (2) To promote the use of advanced technology and expand the technical capability of the Native American Oil production corporations by direct assistance in the current project and dissemination of technology to other Tribes. (3) To develop an understanding of multicomponent seismic data as it relates to the variations in permeability and porosity of algal mounds, as well as lateral facies variations, for use in both reservoir development and exploration. (4) To identify any undiscovered algal mounds for field-extension within the area of seismic coverage. (5) To evaluate the potential for applying CO{sub 2} floods, steam floods, water floods or other secondary or tertiary recovery processes to increase production. The technical work scope was carried out by: (1) Acquiring multicomponent seismic data over the project area; (2) Processing and reprocessing the multicomponent data to extract as much geological and engineering data as possible within the budget and time-frame of the project; (3) Preparing maps and data volumes of geological and engineering data based on the multicomponent seismic and well data; (4) Selecting drilling targets if warranted by the seismic interpretation; (5) Constructing a static reservoir model of the project area; and (6) Constructing a dynamic history-matched simulation model from the static model. The original project scope covered a 6 mi{sup 2} (15.6 km{sup 2}) area encompassing two algal mound fields (Towaoc and Roadrunner). 3D3C seismic data was to acquired over this area to delineate mound complexes and image internal reservoir properties such as porosity and fluid saturations. After the project began, the Red Willow Production Company, a project partner and fully-owned company of the Southern Ute Tribe, contributed additional money to upgrade the survey to a nine-component (3D9C) survey. The purpose of this upgrade to nine components was to provide additional shear wave component data that might prove useful in delineating internal mound reservoir attributes. Also, Red Willow extended the P-wave portion of the survey to the northwest of the original 6 mi{sup 2} (15.6 km{sup 2}) 3D9C area in order to extend coverage further to the northwest to the Marble Wash area. In order to accomplish this scope of work, 3D9C seismic data set covering two known reservoirs was acquired and processed. Three-dimensional, zero-offset vertical seismic profile (VSP) data was acquired to determine the shear wave velocities for processing the sh3Dseismic data. Anisotropic velocity, and azimuthal AVO processing was carried out in addition to the conventional 3D P-wave data processing. All P-, PS- and S-wave volumes of the seismic data were interpreted to map the seismic response. The interpretation consisted of conventional cross-plots of seismic attributes vs. geological and reservoir engineering data, as well as multivariate and neural net analyses to assess whether additional resolution on exploration and engineering parameters could be achieved through the combined use of several seismic variables. Engineering data in the two reservoirs was used to develop a combined lithology, structure and permeability map. On the basis of the seismic data, a well was drilled into the northern mound trend in the project area. This well, Roadrunner No.9-2, was brought into production in late April 2006 and continues to produce modest amounts of oil and gas. As of the end of August 2007, the well has produced approximately 12,000 barrels of oil and 32,000 mcf of gas. A static reservoir model was created from the seismic data interpretations and well data. The seismic data was tied to various markers identified in the well logs, which in turn were related to lithostratigraphy. The tops and thicknesses of the various units were extrapolated from well control based upon the seismic data that was calibrated to the well picks. The reservoir engineering properties were available from a number of wel

Joe Hachey

2007-09-30T23:59:59.000Z

118

Improving the Monitoring, Verification, and Accounting of CO{sub 2} Sequestered in Geologic Systems with Multicomponent Seismic Technology and Rock Physics Modeling  

SciTech Connect (OSTI)

Research done in this study showed that P-SV seismic data provide better spatial resolution of geologic targets at our Appalachian Basin study area than do P-P data. This finding is important because the latter data (P-P) are the principal seismic data used to evaluate rock systems considered for CO{sub 2} sequestration. The increase in P-SV{sub 1} resolution over P-P resolution was particularly significant, with P-SV{sub 1} wavelengths being approximately 40-percent shorter than P-P wavelengths. CO{sub 2} sequestration projects across the Appalachian Basin should take advantage of the increased resolution provided by converted-shear seismic modes relative to P-wave seismic data. In addition to S-wave data providing better resolution of geologic targets, we found S-wave images described reservoir heterogeneities that P-P data could not see. Specifically, a channel-like anomaly was imaged in a key porous sandstone interval by P-SV{sub 1} data, and no indication of the feature existed in P-P data. If any stratigraphic unit is considered for CO{sub 2} storage purposes, it is important to know all heterogeneities internal to the unit to understand reservoir compartmentalization. We conclude it is essential that multicomponent seismic data be used to evaluate all potential reservoir targets whenever a CO{sub 2} storage effort is considered, particularly when sequestration efforts are initiated in the Appalachian Basin. Significant differences were observed between P-wave sequences and S- wave sequences in data windows corresponding to the Oriskany Sandstone, a popular unit considered for CO{sub 2} sequestration. This example demonstrates that S-wave sequences and facies often differ from P-wave sequences and facies and is a principle we have observed in every multicomponent seismic interpretation our research laboratory has done. As a result, we now emphasis elastic wavefield seismic stratigraphy in our reservoir characterization studies, which is a science based on the concept that the same weight must be given to S-wave sequences and facies as is given to P-wave sequences and facies. This philosophy differs from the standard practice of depending on only conventional P-wave seismic stratigraphy to characterize reservoir units. The fundamental physics of elastic wavefield seismic stratigraphy is that S- wave modes sense different sequences and facies across some intervals than does a P-wave mode because S-wave displacement vectors are orthogonal to P- wave displacement vectors and thus react to a different rock fabric than do P waves. Although P and S images are different, both images can still be correct in terms of the rock fabric information they reveal.

Alkan, Engin; DeAngelo, Michael; Hardage, Bob; Sava, Diana; Sullivan, Charlotte; Wagner, Donald

2012-12-31T23:59:59.000Z

119

An evaluation of the geothermal potential of the Tecuamburro Volcano area of Guatemala  

SciTech Connect (OSTI)

Radiometric ages indicate that the Tecuamburro Volcano and three adjacent lava domes grew during the last 38,300 years, and that a 360-m-wide phreatic crater, Laguna Ixpaco, was formed near the base of these domes about 2900 years ago. Laguna Ixpaco is located within the Chupadero crater, from which pyroxene pumice deposits were erupted 38,300 years ago. Thus, the likelihood is great for a partly molten or solid-but-still-hot near-surface intrusion beneath the area. Fumaroles and hot springs issue locally from the Tecuamburro volcanic complex and near Laguna Ixpaco. Analyses of gas and fluid samples from these and other nearby thermal manifestations yield chemical-geothermometer temperatures of about 150{degree} to 300{degree}C, with the highest temperatures at Ixpaco. The existence of a commercial-grade geothermal reservoir beneath the Ixpaco area seems likely. 84 refs., 70 figs., 12 tabs.

Heiken, G.; Duffield, W. (eds.)

1990-09-01T23:59:59.000Z

120

Multicomponent Seismic Technology Assessment of  

E-Print Network [OSTI]

, and R. Boswell, eds., Natural gas hydrates--Energy resource potential and associated geologic hazards) in the Green Canyon area of the northern Gulf of Mexico were analyzed in this study. These expulsion features

Texas at Austin, University of

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121

Precision measurements of binary and multicomponent diffusion coefficients in protein solutions relevant to crystal growth: Lysozyme chloride in water and aqueous NaCl at pH 4.5 and 25{degree}C  

SciTech Connect (OSTI)

Accurate models of protein diffusion are important in a number of applications, including liquid-liquid phase separation and growth of protein crystals for X-ray diffraction studies. In concentrated multicomponent protein systems, significant deviations from pseudobinary behavior can be expected. Rayleigh interferometry is used to measure the four elements (D{sub if}){sub v} of the ternary diffusion coefficient matrix for the extensively investigated protein, hen egg-white lysozyme (component 1) in aqueous NaCl (component 2) at pH 4.5 and 25 C. These are the first multicomponent diffusion coefficients measured for any protein system at concentrations high enough to be relevant to modeling and prediction of crystal growth or other phase transitions, and the first for a system involving lysozyme at any concentration. The four ternary diffusion coefficients for the system lysozyme chloride/NaCl/water are reported for lysozyme chloride at 0.60 mM (8.6 mg/mL) and NaCl at concentrations of 0.25, 0.50, 0.65, 0.90, and 1.30 M (1.4, 2.8, 3.7, 5.1, and 7.2 wt %), with the latter two compositions being supersaturated. One cross-term, (D{sub 21}){sub v}, is 80--259 times larger than the main term (D{sub 11}){sub v} and 7--18 times larger than (D{sub 22}){sub v}. Standard interferometric diagnostic tests indicate that aggregation is unimportant in the experiments. The authors also present binary diffusion coefficients D{sub v} for lysozyme chloride/water at concentrations from 0.43 to 3.08 mM (6.2--44.1 mg/mL), at the same pH and temperature. The precision of the results is about 0.1% for the binary diffusion coefficients and diagonal ternary diffusion coefficients, and about 1--2% for the cross-terms. For the ternary systems investigated, they show that a single pseudobinary diffusion coefficient does not accurately describe diffusive transport, and predictions by simple models such as the Nernst-Hartley equations are inaccurate at the higher concentrations considered here. Finally, dynamic light-scattering diffusion coefficients, differing form both the interferometrically measured (D{sub ij}){sub v} and a theoretical prediction of light-scattering diffusion coefficients in multicomponent systems, are reported for the same solutions used for the ternary experiments at 1.30 M.

Albright, J.G.; Annunziata, O. [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.] [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.; Miller, D.G. [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.] [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.; [Lawrence Livermore National Lab., CA (United States); Paduano, L. [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.] [Texas Christian Univ., Fort Worth, TX (United States). Chemistry Dept.; [Univ. di Napoli, Naples (Italy). Dipt. di Chimica; Pearlstein, A.J. [Univ. of Illinois, Urbana, IL (United States). Dept. of Mechanical and Industrial Engineering] [Univ. of Illinois, Urbana, IL (United States). Dept. of Mechanical and Industrial Engineering

1999-04-14T23:59:59.000Z

122

MULTICOMPONENT SEISMIC ANALYSIS AND CALIBRATION TO IMPROVE RECOVERY FROM ALGAL MOUNDS: APPLICATION TO THE ROADRUNNER/TOWAOC AREA OF THE PARADOX BASIN, UTE MOUNTAIN UTE RESERVATION, COLORADO  

SciTech Connect (OSTI)

This report describes the results made in fulfillment of contract DE-FG26-02NT15451, ''Multicomponent Seismic Analysis and Calibration to Improve Recovery from Algal Mounds: Application to the Roadrunner/Towaoc Area of the Paradox Basin, Ute Mountain Ute Reservation, Colorado''. Optimizing development of highly heterogeneous reservoirs where porosity and permeability vary in unpredictable ways due to facies variations can be challenging. An important example of this is in the algal mounds of the Lower and Upper Ismay reservoirs of the Paradox Basin in Utah and Colorado. It is nearly impossible to develop a forward predictive model to delineate regions of better reservoir development, and so enhanced recovery processes must be selected and designed based upon data that can quantitatively or qualitatively distinguish regions of good or bad reservoir permeability and porosity between existing well control. Recent advances in seismic acquisition and processing offer new ways to see smaller features with more confidence, and to characterize the internal structure of reservoirs such as algal mounds. However, these methods have not been tested. This project will acquire cutting edge, three-dimensional, nine-component (3D9C) seismic data and utilize recently-developed processing algorithms, including the mapping of azimuthal velocity changes in amplitude variation with offset, to extract attributes that relate to variations in reservoir permeability and porosity. In order to apply advanced seismic methods a detailed reservoir study is needed to calibrate the seismic data to reservoir permeability, porosity and lithofacies. This will be done by developing a petrological and geological characterization of the mounds from well data; acquiring and processing the 3D9C data; and comparing the two using advanced pattern recognition tools such as neural nets. In addition, should the correlation prove successful, the resulting data will be evaluated from the perspective of selecting alternative enhanced recovery processes, and their possible implementation. The work is being carried out on the Roadrunner/Towaoc Fields of the Ute Mountain Ute Tribe, located in the southwestern corner of Colorado. Although this project is focused on development of existing resources, the calibration established between the reservoir properties and the 3D9C seismic data can also enhance exploration success. During the time period covered by this report, the majority of the project effort has gone into the permitting, planning and design of the 3D seismic survey, and to select a well for the VSP acquisition. The business decision in October, 2002 by WesternGeco, the projects' seismic acquisition contractor, to leave North America, has delayed the acquisition until late summer, 2003. The project has contracted Solid State, a division of Grant Geophysical, to carry out the acquisition. Moreover, the survey has been upgraded to a 3D9C from the originally planned 3D3C survey, which should provide even greater resolution of mounds and internal mound structure.

Paul La Pointe; Claudia Rebne; Steve Dobbs

2003-07-10T23:59:59.000Z

123

Exploration of the Upper Hot Creek Ranch Geothermal Resource, Nye County, Nevada  

SciTech Connect (OSTI)

The Upper Hot Creek Ranch (UHCR) geothermal system had seen no significant exploration activity prior to initiation of this GRED III project. Geochemical geothermometers calculated from previously available but questionable quality analyses of the UHCR hot spring waters indicated possible subsurface temperatures of +320 oF. A complex Quaternary and Holocene faulting pattern associated with a six mile step over of the Hot Creek Range near the UHCR also indicated that this area was worthy of some exploration activity. Permitting activities began in Dec. 2004 for the temperature-gradient holes but took much longer than expected with all drilling permits finally being received in early August 2005. The drilling and geochemical sampling occurred in August 2005. Ten temperature gradient holes up to 500’ deep were initially planned but higher than anticipated drilling and permitting costs within a fixed budget reduced the number of holes to five. Four of the five holes drilled to depths of 300 to 400’ encountered temperatures close to the expected regional thermal background conditions. These four holes failed to find any evidence of a large thermal anomaly surrounding the UHCR hot springs. The fifth hole, located within a narrow part of Hot Creek Canyon, encountered a maximum temperature of 81 oF at a depth of 105’ but had cooler temperatures at greater depth. Temperature data from this hole can not be extrapolated to greater depths. Any thermal anomaly associated with the UHCR geothermal system is apparently confined to the immediate vicinity of Hot Creek Canyon where challenges such as topography, a wilderness study area, and wetlands issues will make further exploration time consuming and costly. Ten water samples were collected for chemical analysis and interpretation. Analyses of three samples of the UHCR thermal give predicted subsurface temperatures ranging from 317 to 334 oF from the Na-K-Ca, silica (quartz), and Na-Li geothermometers. The fact that all three thermometers closely agree gives the predictions added credibility. Unfortunately, the final result of this exploration is that a moderate temperature geothermal resource has been clearly identified but it appears to be restricted to a relatively small area that would be difficult to develop.

Dick Benoit; David Blackwell

2006-01-01T23:59:59.000Z

124

Combining Multicomponent Seismic Attributes, New Rock Physics Models, and In Situ Data to Estimate Gas-Hydrate Concentrations in Deep-Water, Near-Seafloor Strata of the Gulf of Mexico  

SciTech Connect (OSTI)

The Bureau of Economic Geology was contracted to develop technologies that demonstrate the value of multicomponent seismic technology for evaluating deep-water hydrates across the Green Canyon area of the Gulf of Mexico. This report describes the methodologies that were developed to create compressional (P-P) and converted-shear (P-SV) images of near-seafloor geology from four-component ocean-bottom-cable (4C OBC) seismic data and the procedures used to integrate P-P and P-SV seismic attributes with borehole calibration data to estimate hydrate concentration across two study areas spanning 16 and 25 lease blocks (or 144 and 225 square miles), respectively. Approximately 200 km of two-dimensional 4C OBC profiles were processed and analyzed over the course of the 3-year project. The strategies we developed to image near-seafloor geology with 4C OBC data are unique, and the paper describing our methodology was peer-recognized with a Best Paper Award by the Society of Exploration Geophysicists in the first year of the project (2006). Among the valuable research findings demonstrated in this report, the demonstrated ability to image deep-water near-seafloor geology with sub-meter resolution using a standard-frequency (10-200 Hz) air gun array on the sea surface and 4C sensors on the seafloor has been the accomplishment that has received the most accolades from professional peers. Our study found that hydrate is pervasive across the two study areas that were analyzed but exists at low concentrations. Although our joint inversion technique showed that in some limited areas, and in some geologic units across those small areas, hydrates occupied up to 40-percent of the sediment pore space, we found that when hydrate was present, hydrate concentration tended to occupy only 10-percent to 20-percent of the pore volume. We also found that hydrate concentration tended to be greater near the base of the hydrate stability zone than it was within the central part of the stability zone.

Bureau of Economic Geology

2009-04-30T23:59:59.000Z

125

Variably Saturated Flow and Multicomponent Biogeochemical Reactive...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of a Uranium Bioremediation Field Abstract: Field experiments at a former uranium mill tailings site have identified the potential for stimulating indigenous bacteria to...

126

Phase Stability of Multicomponent NAPLs Containing PAHs  

E-Print Network [OSTI]

to produce complex synthetic NAPLs which can be used as surrogate materials to simulate the behavior of a contaminant is dependent on its phase state. For solid phase contaminants in contact with water, the maximum assessment, predicting remediation effectiveness, and experimental research. In this paper, we discuss NAPL

Peters, Catherine A.

127

Advancements in isocyanide based multicomponent reactions  

E-Print Network [OSTI]

Wiley: New York, London, Ugi, I. ; Dömling, A. Angew. Chem.Chem. Ital. 1921, 51, 181-189. Ugi, I. Angew. Chem. Int. Ed.c) Hanusch-Kompa, C. ; Ugi, I. Tetrahedron Lett. 1998, 39,

Isaacson, Jerry Calhoun

2009-01-01T23:59:59.000Z

128

Multicomponent Reactions in Total Synthesis Kevin Allan  

E-Print Network [OSTI]

· Ugi Reaction · Cycloadditions · Povarov Reaction · Knoevenagel / Hetero-Diels-Alder Cycloaddition · 1-VCH; Weinheim, 2005. Orru, R. V. A.; de Greef, M. Synthesis 2003, 10, 1471-1499. Ugi, I. Pure Appl. Chem. 2001, 73, 187-191. Bienaymé, H.; Hulme, C.; Oddon, G.; Schmitt, P. Chem. Eur. J. 2000, 6, 3321-3329. Ugi, I

Stoltz, Brian M.

129

Multi-component hydrogen storage material  

DOE Patents [OSTI]

A reversible hydrogen storage composition having an empirical formula of: Li.sub.(x+z)N.sub.xMg.sub.yB.sub.zH.sub.w where 0.4.ltoreq.x.ltoreq.0.8; 0.2.ltoreq.y.ltoreq.0.6; 0

Faheem, Syed A. (Huntley, IL); Lewis, Gregory J. (Santa Cruz, CA); Sachtler, J.W. Adriaan (Des Plaines, IL); Low, John J. (Schaumburg, IL); Lesch, David A. (Hoffman Estates, IL); Dosek, Paul M. (Joliet, IL); Wolverton, Christopher M. (Evanston, IL); Siegel, Donald J. (Ann Arbor, MI); Sudik, Andrea C. (Canton, MI); Yang, Jun (Canton, MI)

2010-09-07T23:59:59.000Z

130

Use of computers for multicomponent distillation calculations  

E-Print Network [OSTI]

The corrected values for the b 's are best cal- i culated by multiplying (b. /d ) by (d. ) The compositions for each component in the vapor and liquid streams leaving plate j are calculated by use of the following equations. ('i/ i)ca ( i)co y. ji c Z (v... . . /b. ) (b. ) ji i ca i co i=1 , f a j x N+1 C (47-b) A temperature profile may be calculated by making either bubble or dew point calculations based on the compositions obtained by use of Equations (46) and (47). The specified distillate rate must...

Sullivan, Samuel Lane

1959-01-01T23:59:59.000Z

131

Variably Saturated Flow and Multicomponent Biogeochemical Reactive  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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132

I I I . Isotherm al Multicomponent Systems  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinementEtching. | EMSL Bubblesstructure eind ExcBAECC: -

133

Advancements in isocyanide based multicomponent reactions  

E-Print Network [OSTI]

3916. (a) Newman, M. S. ; Beal, P. F. , III. J. Am. Chem.Chem. 1999, Newman, M. S. ; Beal, P. F. , III. J. Am. Chem.

Isaacson, Jerry Calhoun

2009-01-01T23:59:59.000Z

134

Results of investigation at the Miravalles geothermal field, Costa Rica. Resultados de las investigaciones en el campo geotermico de Miravalles, Costa Rica; Parte 2, Muestreo de fluidos pozo abajo  

SciTech Connect (OSTI)

Samples of the geothermal fluids in the Miravalles, Costa Rica, geothermal system were collected from production wellbores using downhole fluid samplers, from flowing wellheads using miniseparators, and from hot springs that discharge in the area. The reservoir fluid at Miravalles is a neutral-chloride-type water, but fumaroles and acid-sulfate springs are present within the main thermal area, and there are bicarbonate-rich hot springs that are clearly related to the neutral-chloride reservoir fluids. Dissolved gases are primarily a mixture of CO{sub 2} with air, but samples collected in the fumarolic areas also contain H{sub 2}S. Water-stable isotope analyses suggest local meteoric recharge, and the reservoir fluid shows oxygen isotopic shifts of about 2.5% due to high-temperature oxygen exchange between water and rock. Chemical geothermometer temperatures are consistent with the measured downhole temperature of 220{degrees} to 255{degrees}C. This pattern of neutral-chloride reservoir fluids with acid-sulfate springs near the source region and bicarbonate-rich chloride hot springs at the periphery of the system suggests a lateral outflow type of hydrothermal system. In addition to the geochemical evidence, temperature profiles from several of the wells show temperature reversals that are characteristic of lateral outflow plumes. We find no evidence for the underlying, higher temperature (300{degrees}C) system, which has been suggested by other investigators. 24 refs., 14 figs., 6 tabs.

Grigsby, C.O.; Goff, F.; Trujillo, P.E. Jr.; Counce, D.A.; Dennis, B.; Kolar, J.; Corrales, R. (Los Alamos National Lab., NM (USA); Instituto Costarricense de Electricidad, San Jose (Costa Rica))

1989-10-01T23:59:59.000Z

135

Water information bulletin No. 30 geothermal investigations in Idaho  

SciTech Connect (OSTI)

There are 899 thermal water occurrences known in Idaho, including 258 springs and 641 wells having temperatures ranging from 20 to 93/sup 0/C. Fifty-one cities or towns in Idaho containing 30% of the state's population are within 5 km of known geothermal springs or wells. These include several of Idaho's major cities such as Lewiston, Caldwell, Nampa, Boise, Twin Falls, Pocatello, and Idaho Falls. Fourteen sites appear to have subsurface temperatures of 140/sup 0/C or higher according to the several chemical geothermometers applied to thermal water discharges. These include Weiser, Big Creek, White Licks, Vulcan, Roystone, Bonneville, Crane Creek, Cove Creek, Indian Creek, and Deer Creek hot springs, and Raft River, Preston, and Magic Reservoir areas. These sites could be industrial sites, but several are in remote areas away from major transportation and, therefore, would probably be best utilized for electrical power generation using the binary cycle or Magma Max process. Present uses range from space heating to power generation. Six areas are known where commercial greenhouse operations are conducted for growing cut and potted flowers and vegetables. Space heating is substantial in only two places (Boise and Ketchum) although numerous individuals scattered throughout the state make use of thermal water for space heating and private swimming facilities. There are 22 operating resorts using thermal water and two commercial warm-water fish-rearing operations.

Mitchell, J.C.; Johnson, L.L.; Anderson, J.E.; Spencer, S.G.; Sullivan, J.F.

1980-06-01T23:59:59.000Z

136

Thermal springs in the Payette River basin, west-central Idaho  

SciTech Connect (OSTI)

The Payette River basin, characterized by steep, rugged mountains and narrow river valleys, occupies an area of about 3300 square miles in west-central Idaho. Predominant rock types in the basin include granitic rocks of the Idaho batholith and basalt flows of the Columbia River Basalt Group. Waters from thermal springs in the basin, temperatures of which range from 34/sup 0/ to 86/sup 0/ Celsius, are sodium bicarbonate type and are slightly alkaline. Dissolved-solids concentrations range from 173 to 470 milligrams per liter. Reservoir temperatures determined from the sodium-potassium-calcium, silicic acid-corrected silica, and sulfate-water isotope geothermometers range from 53/sup 0/ to 143/sup 0/ Celsius. Tritium, present in concentrations between 0 and 2 tritium units, indicate that sampled thermal waters are at least 100 years and possibly more than 1000 years old. Stable-isotope data indicate it is unlikely any of the nonthermal waters sampled are representative of precipitation that recharges the thermal springs in the basin. Thermal springs discharged about 5700 acre-feet of water in 1979. Associated convective heat flux is 1.1 x 10/sup 7/ calories per second.

Lewis, R.E.; Young, H.W.

1980-10-01T23:59:59.000Z

137

BACA Project: geothermal demonstration power plant. Final report  

SciTech Connect (OSTI)

The various activities that have been conducted by Union in the Redondo Creek area while attempting to develop the resource for a 50 MW power plant are described. The results of the geologic work, drilling activities and reservoir studies are summarized. In addition, sections discussing the historical costs for Union's involvement with the project, production engineering (for anticipated surface equipment), and environmental work are included. Nineteen geothermal wells have been drilled in the Redondo Creek area of the Valles Caldera: a prominent geologic feature of the Jemez mountains consisting of Pliocene and Pleistocene age volcanics. The Redondo Creek area is within a complex longitudinal graben on the northwest flank of the resurgent structural dome of Redondo Peak and Redondo Border. The major graben faults, with associated fracturing, are geologically plausible candidates for permeable and productive zones in the reservoir. The distribution of such permeable zones is too erratic and the locations too imprecisely known to offer an attractive drilling target. Log analysis indicates there is a preferred mean fracture strike of N31W in the upper portion of Redondo Creek wells. This is approximately perpendicular to the major structure in the area, the northeast-striking Redondo Creek graben. The geothermal fluid found in the Redondo Creek reservoir is relatively benign with low brine concentrations and moderate H/sub 2/S concentrations. Geothermometer calculations indicate that the reservoir temperature generally lies between 500/sup 0/F and 600/sup 0/F, with near wellbore flashing occurring during the majority of the wells' production.

Not Available

1982-12-01T23:59:59.000Z

138

Favorable Geochemistry from Springs and Wells in COlorado  

SciTech Connect (OSTI)

Citation Information: Originator: Geothermal Development Associates, Reno Nevada Originator: United States Geological Survey (USGS) Originator: Colorado Geological Survey Publication Date: 2012 Title: Favorable Geochemistry Edition: First Publication Information: Publication Place: Reno Nevada Publisher: Geothermal Development Associates, Reno, Nevada Description: This layer contains favorable geochemistry for high-temperature geothermal systems, as interpreted by Richard "Rick" Zehner. The data is compiled from the data obtained from the USGS. The original data set combines 15,622 samples collected in the State of Colorado from several sources including 1) the original Geotherm geochemical database, 2) USGS NWIS (National Water Information System), 3) Colorado Geological Survey geothermal sample data, and 4) original samples collected by R. Zehner at various sites during the 2011 field season. These samples are also available in a separate shapefile FlintWaterSamples.shp. Data from all samples were reportedly collected using standard water sampling protocols (filtering through 0.45 micron filter, etc.) Sample information was standardized to ppm (micrograms/liter) in spreadsheet columns. Commonly-used cation and silica geothermometer temperature estimates are included. Spatial Domain: Extent: Top: 4515595.841032 m Left: 149699.513964 m Right: 757959.309388 m Bottom: 4104156.435530 m Contact Information: Contact Organization: Geothermal Development Associates, Reno, Nevada Contact Person: Richard “Rick” Zehner Address: 3740 Barron Way City: Reno State: NV Postal Code: 89511 Country: USA Contact Telephone: 775-737-7806 Spatial Reference Information: Coordinate System: Universal Transverse Mercator (UTM) WGS’1984 Zone 13N False Easting: 500000.00000000 False Northing: 0.00000000 Central Meridian: -105.00000000 Scale Factor: 0.99960000 Latitude of Origin: 0.00000000 Linear Unit: Meter Datum: World Geodetic System 1984 (WGS ’1984) Prime Meridian: Greenwich Angular Unit: Degree Digital Form: Format Name: Shape file

Zehner, Richard E.

2012-02-01T23:59:59.000Z

139

Baryonic Bound State of Vortices in Multicomponent Superconductors  

E-Print Network [OSTI]

We construct a bound state of three 1/3-quantized Josephson coupled vortices in three-component superconductors with intrinsic Josephson couplings, which may be relevant with regard to iron-based superconductors. We find a Y-shaped junction of three domain walls connecting the three vortices, resembling the baryonic bound state of three quarks in QCD. The appearance of the Y-junction (but not a Delta-junction) implies that in both cases of superconductors and QCD, the bound state is described by a genuine three-body interaction (but not by the sum of two-body interactions). We also discuss a confinement/deconfinement phase transition.

Muneto Nitta; Minoru Eto; Toshiaki Fujimori; Keisuke Ohashi

2012-07-30T23:59:59.000Z

140

Multicomponent reactive transport modeling of uranium bioremediation field experiments  

SciTech Connect (OSTI)

Biostimulation field experiments with acetate amendment are being performed at a former uranium mill tailings site in Rifle, Colorado, to investigate subsurface processes controlling in situ bioremediation of uranium-contaminated groundwater. An important part of the research is identifying and quantifying field-scale models of the principal terminal electron-accepting processes (TEAPs) during biostimulation and the consequent biogeochemical impacts to the subsurface receiving environment. Integrating abiotic chemistry with the microbially mediated TEAPs in the reaction network brings into play geochemical observations (e.g., pH, alkalinity, redox potential, major ions, and secondary minerals) that the reactive transport model must recognize. These additional constraints provide for a more systematic and mechanistic interpretation of the field behaviors during biostimulation. The reaction network specification developed for the 2002 biostimulation field experiment was successfully applied without additional calibration to the 2003 and 2007 field experiments. The robustness of the model specification is significant in that 1) the 2003 biostimulation field experiment was performed with 3 times higher acetate concentrations than the previous biostimulation in the same field plot (i.e., the 2002 experiment), and 2) the 2007 field experiment was performed in a new unperturbed plot on the same site. The biogeochemical reactive transport simulations accounted for four TEAPs, two distinct functional microbial populations, two pools of bioavailable Fe(III) minerals (iron oxides and phyllosilicate iron), uranium aqueous and surface complexation, mineral precipitation, and dissolution. The conceptual model for bioavailable iron reflects recent laboratory studies with sediments from the Old Rifle Uranium Mill Tailings Remedial Action (UMTRA) site that demonstrated that the bulk (~90%) of Fe(III) bioreduction is associated with the phyllosilicates rather than the iron oxides. The uranium reaction network includes a U(VI) surface complexation model based on laboratory studies with Old Rifle UMTRA sediments and aqueous complexation reactions that include ternary complexes (e.g., calcium-uranyl-carbonate). The bioreduced U(IV), Fe(II), and sulfide components produced during the experiments are strongly associated with the solid phases and may play an important role in long-term uranium immobilization.

Fang, Yilin; Yabusaki, Steven B.; Morrison, Stan J.; Amonette, James E.; Long, Philip E.

2009-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Towards breaking temperature equilibrium in multi-component Eulerian schemes  

SciTech Connect (OSTI)

We investigate the effects ofthermal equilibrium on hydrodynamic flows and describe models for breaking the assumption ofa single temperature for a mixture of components in a cell. A computational study comparing pressure-temperature equilibrium simulations of two dimensional implosions with explicit front tracking is described as well as implementation and J-D calculations for non-equilibrium temperature methods.

Grove, John W [Los Alamos National Laboratory; Masser, Thomas [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

142

Simulation of multicomponent evaporation in electron beam melting and refining  

SciTech Connect (OSTI)

Experimental results and a mathematical model are presented to describe differential evaporation rates in electron beam melting of titanium alloys containing aluminum and vanadium. Experiments characterized the evaporation rate of commercially pure titanium, and vapor composition over titanium with up to 6% Al and 4.5% V content as a function of beam power, scan frequency and background pressure. The model is made up of a steady-state heat and mass transport model of a melting hearth and a model of transient thermal and flow behavior near the surface. Activity coefficients for aluminum and vanadium in titanium are roughly estimated by fitting model parameters to experimental results. Based on the ability to vary evaporation rate by 10-15% using scan frequency alone, we discuss the possibility of on-line composition control by means of intelligent manipulation of the electron beam.

Powell, A.; Szekely, J. [Massachusetts Inst. of Tech., Cambridge, MA (United States); Van Den Avyle, J.; Damkroger, B. [Sandia National Labs., Albuquerque, NM (United States)

1996-06-01T23:59:59.000Z

143

Composition at the interface between multicomponent nonequilibrium fluid phases  

E-Print Network [OSTI]

. These secondary recovery mechanisms are particularly important in fractured hydrocar- bon reservoirs.4 An accurate, gas has been in- jected into oil reservoirs to maintain the pressure and thus, improve oil recovery.3 is already developed. Moreover, CO2-injection is a hot candidate for improved oil recovery projects. Thus, CO

Firoozabadi, Abbas

144

Controlling morphology of multi-component block copolymer based materials  

E-Print Network [OSTI]

The ability of block copolymers to self-assemble into ordered microstructures has attracted much interest both from a pure scientific perspective and for their potential in numerous industrial applications. The microphase ...

Mickiewicz, Rafal Adam, 1974-

2009-01-01T23:59:59.000Z

145

Multi-component removal in flue gas by aqua ammonia  

DOE Patents [OSTI]

A new method for the removal of environmental compounds from gaseous streams, in particular, flue gas streams. The new method involves first oxidizing some or all of the acid anhydrides contained in the gas stream such as sulfur dioxide (SO.sub.2) and nitric oxide (NO) and nitrous oxide (N.sub.2O) to sulfur trioxide (SO.sub.3) and nitrogen dioxide (NO.sub.2). The gas stream is subsequently treated with aqua ammonia or ammonium hydroxide which captures the compounds via chemical absorption through acid-base or neutralization reactions. The products of the reactions can be collected as slurries, dewatered, and dried for use as fertilizers, or once the slurries have been dewatered, used directly as fertilizers. The ammonium hydroxide can be regenerated and recycled for use via thermal decomposition of ammonium bicarbonate, one of the products formed. There are alternative embodiments which entail stoichiometric scrubbing of nitrogen oxides and sulfur oxides with subsequent separate scrubbing of carbon dioxide.

Yeh, James T. (Bethel Park, PA); Pennline, Henry W. (Bethel Park, PA)

2007-08-14T23:59:59.000Z

146

Parallel Simulation of Bioreactive Multicomponent Transport Processes in  

E-Print Network [OSTI]

fuels (gasoline, diesel), petroleum byproducts (coal tar, creosote), and chlorinated solvents. In many in many non-aqueous phase liquids (NAPLs) or due to co-disposal/co-spillage (e.g., land#12;ll leachates

Kraeutle, Serge

147

Low-density instability of multicomponent matter with trapped neutrinos  

SciTech Connect (OSTI)

The effect of neutrino trapping on the longitudinal dielectric function at low densities has been investigated by using different relativistic mean-field models. Parameter sets G2 of Furnstahl-Serot-Tang and Z271 of Horowitz-Piekarewicz, along with the adjusted parameter sets of both models, have been used in this study. The role of the isovector adjustment and the effect of the Coulomb interaction have also been studied. The effect of the isovector adjustment is found to be more significant in the Horowitz-Piekarewicz model, not only in neutrinoless matter but also in matter with neutrino trapping. Although almost independent to the variation of the leptonic fraction, the instability region of matter with neutrino trapping is found to be larger. The presence of more protons and electrons compared to the neutrinoless case is the reason behind this finding. For parameter sets with soft equations of state at low density, the appearance of a large and negative {epsilon}{sub L}(q,q{sub 0}=0) in some parts of the edge of the instability region in matter with neutrino trapping is understood as a consequence of the fact that the Coulomb interaction produced by electron and proton interaction is larger than the repulsive isovector interaction created by the asymmetry between the proton and neutron numbers.

Mart, T.; Sulaksono, A. [Departemen Fisika, FMIPA, Universitas Indonesia, Depok 16424 (Indonesia)

2008-08-15T23:59:59.000Z

148

The Multicomponent KP Hierarchy: Differential Fay Identities and Lax Equations  

E-Print Network [OSTI]

In this article, we show that four sets of differential Fay identities of an $N$-component KP hierarchy derived from the bilinear relation satisfied by the tau function of the hierarchy are sufficient to derive the auxiliary linear equations for the wave functions. From this, we derive the Lax representation for the $N$-component KP hierarchy, which are equations satisfied by some pseudodifferential operators with matrix coefficients. Besides the Lax equations with respect to the time variables proposed in \\cite{2}, we also obtain a set of equations relating different charge sectors, which can be considered as a generalization of the modified KP hierarchy proposed in \\cite{3}.

Lee-Peng Teo

2010-10-28T23:59:59.000Z

149

Wetting problem for multi-component fluid mixtures  

E-Print Network [OSTI]

In this paper we propose an extension of the Cahn method to binary mixtures and study the problem of wetting near a two-phase critical point without any assumption on the form of intermolecular potentials. A comparison between Cahn's method and later works by Sullivan, Evans et al is made. By using an expression of the energy of interaction between solid surface and liquids proposed recently by Gouin, we obtain the equations of density profiles and the boundary conditions on a solid surface. In the case of a convex free energy, a one-dimensional solution of a linear problem is proposed for the density profiles between a bulk and on a solid wall. A non-linear model of binary mixtures extending Cahn's results for simple fluids is also studied. For the case of a purely attractive wall we have established a criterion of a first order transition in terms of the structure of the level set of the homogeneous part of the free energy. Additively, explicit expressions of density profiles near the wall are proposed. They allow one to consider the adsorption of mixture components by a solid wall.

Henri Gouin; Sergey Gavrilyuk

2008-03-03T23:59:59.000Z

150

The semismooth Newton method for multicomponent reactive transport with minerals  

E-Print Network [OSTI]

is that problems containing CCs (so-called complementarity problems, CPs) are well known in the field of optimization theory. In this field, it is a well known strategy to solve CPs with the semismooth Newton method essential. The article is structured as follows. In Sec. 2.1 we introduce the mineral precipitation

Kraeutle, Serge

151

New Design Methods and Algorithms for Multi-component Distillation  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergy HealthCommentsAugustNationalMarkets with Wind PowerProcesses | Department of

152

Multi-component Nanoparticle Based Lubricant Additive to Improve Efficiency  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F S i DOEToward a Peaceful Nuclear FutureSlide 1 DOEand Durability

153

Multi-component single-substrate conducting polymer actuation systems and fabrication techniques  

E-Print Network [OSTI]

Conducting polymer materials can be employed as actuation elements, length sensors, force sensors, energy storage devices, and electrical components. Combining the various functionalities of conducting polymers to create ...

Paster, Eli Travis

154

A sequential partly iterative approach for multicomponent reactive transport with CORE2D  

E-Print Network [OSTI]

Juncosa R. , Delgado J. and Montenegro L. (2000) CORE 2D : App. Samper, J. , Yang, C. , Montenegro, L. , 2003. CORE 2DSamper, J. , Zhang, G. , Montenegro, L. , 2006a. Coupled

Samper, J.

2009-01-01T23:59:59.000Z

155

Multiphase flow and multicomponent reactive transport model of the ventilation experiment in Opalinus clay  

E-Print Network [OSTI]

Samper, J. , Zheng, L. , Montenegro, L. , 2006c. CoupledSamper, J. , Zheng, L. , Montenegro, L. , Fernández, A.M. ,A.M. Fernández and L. Montenegro, 2008b, Inverse modeling of

Zheng, L.

2010-01-01T23:59:59.000Z

156

Multicomponent Transport through Realistic Zeolite Membranes: Characterization & Transport in Nanoporous Networks  

SciTech Connect (OSTI)

These research studies focused on the characterization and transport for porous solids which comprise both microporosity and mesoporosity. Such materials represent membranes made from zeolites as well as for many new nanoporous solids. Several analytical sorption techniques were developed and evaluated by which these multi-dimensional porous solids could be quantitatively characterized. Notably an approach by which intact membranes could be studied was developed and applied to plate-like and tubular supported zeolitic membranes. Transport processes were studied experimentally and theoretically based on the characterization studies.

William C. Conner

2007-08-02T23:59:59.000Z

157

A comparison of various calculational methods for constant volatility ratio, constant reflux multicomponent distillation  

E-Print Network [OSTI]

for Figures 17, 18, nd 19. . . 83 XIV. Tabulation of Empirical Correlation (Equation 48). 85 ZIQUR S Page l. Operating Data for the Depropanization of a Light Naphtha. 26 2. Composition of Vapor Rising from Plates in a Column Containi. ng an Infinite... for lg constant- doublet separation systems in which the molal liquid and vapor flows remain constant within each section of the column. An empirical correlation (Equation 48) relating the error of the "apcroximate" method to process variables...

Hurst, James William

1952-01-01T23:59:59.000Z

158

Benchmarking a Visual-Basic based multi-component one-dimensional reactive transport modeling tool  

E-Print Network [OSTI]

is an important source of water supply used by populations all around the world (Todd, 1980). In the United States, groundwater accounts for approximately twenty one percent of the annual water supply budget and hence., 2002). In addition to heavy metal and chlorinated solvent issues, contamination of aquifers

Clement, Prabhakar

159

Multicomponent dynamics of coupled quantum subspaces and field-induced molecular ionizations  

SciTech Connect (OSTI)

To describe successive ionization steps of a many-electron atom or molecule driven by an ultrashort, intense laser pulse, we introduce a hierarchy of successive two-subspace Feshbach partitions of the N-electron Hilbert space, and solve the partitioned time-dependent Schrödinger equation by a short-time unitary algorithm. The partitioning scheme allows one to use different level of theory to treat the many-electron dynamics in different subspaces. We illustrate the procedure on a simple two-active-electron model molecular system subjected to a few-cycle extreme Ultra-Violet (XUV) pulse to study channel-resolved photoelectron spectra as a function of the pulse's central frequency and duration. We observe how the momentum and kinetic-energy distributions of photoelectrons accompanying the formation of the molecular cation in a given electronic state (channel) change as the XUV few-cycle pulse's width is varied, from a form characteristic of an impulsive ionization regime, corresponding to the limit of a delta-function pulse, to a form characteristic of multiphoton above-threshold ionization, often associated with continuous-wave infinitely long pulse.

Nguyen-Dang, Thanh-Tung; Viau-Trudel, Jérémy [Département de Chimie, Université Laval, Québec, Québec G1K 7P4 (Canada)] [Département de Chimie, Université Laval, Québec, Québec G1K 7P4 (Canada)

2013-12-28T23:59:59.000Z

160

Identification of material parameters for continuum modeling of phase transformations in multicomponent systems  

E-Print Network [OSTI]

Identification of material parameters for continuum modeling of phase transformations called order pa- rameters, which take on specified values in the bulk phases. If the transformation

Umantsev, Alexander

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Formulation of substrate removal kinetics in multi-component aqueous systems  

E-Print Network [OSTI]

are refractory to the biological culture, A refractory compound ls a chemical compound possessing a structure incapable of being broken by ensymes secreted by microorganisms. Additionally? knowledge of the kinetics of tha individual components could be used...-butanol, a refractory compound, was 0. 0322 as shown in Table 3. The exponential constant for the removal of 1-pentanol was 0, 0330 during the first ten hours, essentially the same as that for 2-methyl-2-butanol. however, the constant increased to 0...

Chaney, Ernest William

1967-01-01T23:59:59.000Z

162

Structural studies of bacterial multicomponent monooxygenases : insights into substrate specificity, diiron center tuning and component interactions  

E-Print Network [OSTI]

(cont.) ?-subunit cavities. The presence of 6-bromohexan-l-ol induces one of the active site helices to adopt a [pi] conformation. Together, these findings suggest modes by which molecules may move through the MMOH cavities ...

Sazinsky, Matthew H. (Matthew Howard), 1976-

2004-01-01T23:59:59.000Z

163

Variably Saturated Flow and Multicomponent Biogeochemical Reactive Transport Modeling of a Uranium Bioremediation Field Experiment  

SciTech Connect (OSTI)

Field experiments at a former uranium mill tailings site have identified the potential for stimulating indigenous bacteria to catalyze the conversion of aqueous uranium in the +6 oxidation state to immobile solid-associated uranium in the +4 oxidation state. This effectively removes uranium from solution resulting in groundwater concentrations below actionable standards. Three-dimensional, coupled variably-saturated flow and biogeochemical reactive transport modeling of a 2008 in situ uranium bioremediation field experiment is used to better understand the interplay of transport rates and biogeochemical reaction rates that determine the location and magnitude of key reaction products. A comprehensive reaction network, developed largely through previous 1-D modeling studies, was used to simulate the impacts on uranium behavior of pulsed acetate amendment, seasonal water table variation, spatially-variable physical (hydraulic conductivity, porosity) and geochemical (reactive surface area) material properties. A principal challenge is the mechanistic representation of biologically-mediated terminal electron acceptor process (TEAP) reactions whose products significantly alter geochemical controls on uranium mobility through increases in pH, alkalinity, exchangeable cations, and highly reactive reduction products. In general, these simulations of the 2008 Big Rusty acetate biostimulation field experiment in Rifle, Colorado confirmed previously identified behaviors including (1) initial dominance by iron reducing bacteria that concomitantly reduce aqueous U(VI), (2) sulfate reducing bacteria that become dominant after {approx}30 days and outcompete iron reducers for the acetate electron donor, (3) continuing iron-reducer activity and U(VI) bioreduction during dominantly sulfate reducing conditions, and (4) lower apparent U(VI) removal from groundwater during dominantly sulfate reducing conditions. New knowledge on simultaneously active metal and sulfate reducers has been incorporated into the modeling. In this case, an initially small population of slow growing sulfate reducers is active from the initiation of biostimulation. Three-dimensional, variably saturated flow modeling was used to address impacts of a falling water table during acetate injection. These impacts included a significant reduction in aquifer saturated thickness and isolation of residual reactants and products, as well as unmitigated uranium, in the newly unsaturated vadose zone. High permeability sandy gravel structures resulted in locally high flow rates in the vicinity of injection wells that increased acetate dilution. In downgradient locations, these structures created preferential flow paths for acetate delivery that enhanced local zones of TEAP reactivity and subsidiary reactions. Conversely, smaller transport rates associated with the lower permeability lithofacies (e.g., fine) and vadose zone were shown to limit acetate access and reaction. Once accessed by acetate, however, these same zones limited subsequent acetate dilution and provided longer residence times that resulted in higher concentrations of TEAP products when terminal electron donors and acceptors were not limiting. Finally, facies-based porosity and reactive surface area variations were shown to affect aqueous uranium concentration distributions; however, the ranges were sufficiently small to preserve general trends. Large computer memory and high computational performance were required to simulate the detailed coupled process models for multiple biogeochemical components in highly resolved heterogeneous materials for the 110-day field experiment and 50 days of post-biostimulation behavior. In this case, a highly-scalable subsurface simulator operating on 128 processor cores for 12 hours was used to simulate each realization. An equivalent simulation without parallel processing would have taken 60 days, assuming sufficient memory was available.

Yabusaki, Steven B.; Fang, Yilin; Williams, Kenneth H.; Murray, Christopher J.; Ward, Anderson L.; Dayvault, Richard; Waichler, Scott R.; Newcomer, Darrell R.; Spane, Frank A.; Long, Philip E.

2011-11-01T23:59:59.000Z

164

Miscible, multi-component, diesel fuels and methods of bio-oil transformation  

DOE Patents [OSTI]

Briefly described, embodiments of this disclosure include methods of recovering bio-oil products, fuels, diesel fuels, and the like are disclosed.

Adams, Thomas (Athens, GA); Garcia, Manuel (Quebec, CA); Geller, Dan (Athens, GA); Goodrum, John W. (Athens, GA); Pendergrass, Joshua T. (Jefferson, GA)

2010-10-26T23:59:59.000Z

165

Integrated Column Designs for Minimum Energy and Entropy Requirements in Multicomponent Distillation  

E-Print Network [OSTI]

prefer a process where the energy may be supplied at a low temperature and cooling may be supplied law). This leads us to the reversible Petlyuk arrangement. However the total required heat supply). A characteristic of the reversible distillation column is that some of the heat is supplied continuously along

Skogestad, Sigurd

166

System and method to determine thermophysical properties of a multi-component gas  

DOE Patents [OSTI]

A system and method to characterize natural gas hydrocarbons using a single inferential property, such as standard sound speed, when the concentrations of the diluent gases (e.g., carbon dioxide and nitrogen) are known. The system to determine a thermophysical property of a gas having a first plurality of components comprises a sound velocity measurement device, a concentration measurement device, and a processor to determine a thermophysical property as a function of a correlation between the thermophysical property, the speed of sound, and the concentration measurements, wherein the number of concentration measurements is less than the number of components in the gas. The method includes the steps of determining the speed of sound in the gas, determining a plurality of gas component concentrations in the gas, and determining the thermophysical property as a function of a correlation between the thermophysical property, the speed of sound, and the plurality of concentrations.

Morrow, Thomas B.; Behring II, Kendricks A.

2003-08-05T23:59:59.000Z

167

Indirect measurement of diluents in a multi-component natural gas  

DOE Patents [OSTI]

A method of indirectly measuring the diluent (nitrogen and carbon dioxide) concentrations in a natural gas mixture. The molecular weight of the gas is modeled as a function of the speed of sound in the gas, the diluent concentrations in the gas, and constant values, resulting in a model equation. A set of reference gas mixtures with known molecular weights and diluent concentrations is used to calculate the constant values. For the gas in question, if the speed of sound in the gas is measured at three states, the three resulting expressions of molecular weight can be solved for the nitrogen and carbon dioxide concentrations in the gas mixture.

Morrow, Thomas B.; Owen, Thomas E.

2006-03-07T23:59:59.000Z

168

Analysis of multicomponent evaporation in electron beam melting and refining of titanium alloys  

SciTech Connect (OSTI)

Experimental evidence and a mathematical model are presented to evaluate the effect of beam-scan frequency on composition change in electron-beam melting of titanium alloys. Experiments characterized the evaporation rate of commercially pure (CP) titanium and vapor composition over titanium alloy with up to 6 wt pct aluminum and 4.5 wt pct vanadium, as a function of beam power, scan frequency, and background pressure. These data and thermal mapping of the hearth melt surface are used to estimate activity coefficients of aluminum and vanadium in the hearth. The model describes transient heat transfer in the surface of the melt and provides a means of estimating enhancement of pure titanium evaporation and change in final aluminum composition due to local heating at moderate beam-scan frequencies.

Powell, A.; Szekely, J.; Pal, U. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Materials Science and Engineering; Avyle, J. van den; Damkroger, B. [Sandia National Labs., Albuquerque, NM (United States). Materials Processing Dept.

1997-12-01T23:59:59.000Z

169

Simulation of multicomponent losses in electron beam melting and refining at varying scan frequencies  

SciTech Connect (OSTI)

A two-stage model is presented to describe alloy element evaporation rates from molten metal due to transient local heating by an electron beam. The first stage is a simulation of transient phenomena near the melt surface due to periodic heating by a scanning beam, the output of which is the relationship between operating parameters, surface temperature, and evaporation rate. At high scan rates, this can be done using a simple one-dimensional heat transfer model of the surface layer; at lower scan rates, a more complex three-dimensional model with fluid flow and periodic boundary conditions is necessary. The second stage couples this evaporation-surface temperature relationship with a larger steady state heat transfer and fluid flow model of an entire melting hearth or mold, in order to calculate local and total evaporation rates. Predictions are compared with experimental results from Sandia`s 310-kW electron beam melting furnace, in which evaporation rates and vapor compositions were studied in pure titanium and Ti-6%Al-4%V alloy. Evaporation rates were estimated from rate of condensation on a substrate held over the hearth, and were characterized as a function of beam power (10{sup {minus}3}, 10{sup {minus}4} and 10{sup {minus}5} torr).

Powell, A.; Szekely, J. [Massachusetts Institute of Technology, Cambridge, MA (United States); Avyle, J.V.D.; Damkroger, B. [Sandia National Laboratories, Albuquerque, NM (United States)

1995-12-31T23:59:59.000Z

170

Simulation of multicomponent losses in electron beam melting and refining at varying scan frequencies  

SciTech Connect (OSTI)

A two-stage model is presented to describe alloy element evaporation rates from molten metal due to transient local heating by an electron beam. The first stage is a simulation of transient phenomena near the melt surface due to periodic heating by a scanning beam, the output of which is the relationship between operating parameters, surface temperature, and evaporation rate. At high scan rates, this can be done using a simple one-dimensional heat transfer model of the surface layer; at lower scan rates, a more complex three-dimensional model with fluid flow and periodic boundary conditions is necessary. The second stage couples this evaporation-surface temperature relationship with a larger steady state heat transfer and fluid flow model of an entire melting hearth or mold, in order to calculate local and total evaporation rates. Predictions are compared with experimental results from Sandia`s 310-kW electron beam melting furnace, in which evaporation rates and vapor compositions were studied in pure titanium and Ti-6%Al-4%V alloy. Evaporation rates were estimated from rate of condensation on a substrate held over the hearth, and were characterized as a function of beam power (150 and 225 kW), scan frequency (30, 115 and 450 Hz) and background pressure (10{sup {minus}3}, 10{sup {minus}4} and 10{sup {minus}5} torr).

Powell, A.; Szekely, J. [Massachusetts Inst. of Tech., Cambridge, MA (United States); Van Den Avyle, J.; Damkroger, B. [Sandia National Labs., Albuquerque, NM (United States)

1995-10-12T23:59:59.000Z

171

Metrological characteristics of the multiparameter method of analysis of multicomponent solutions  

SciTech Connect (OSTI)

On the basis of previously obtained results of the study of nitrate solutions and the parameters of chloride solutions in the homogenous region for acid-salt-water systems, the authors have investigated the conditions and possibilities of the multiparameter method. The authors, having studied the density, viscosity, and electrical conductivity of three acid-salt-water chloride systems as a function of the composition of the solution, obtained equations relative to the measured values of the density, viscosity, and electrical conductivity for determination of the acid and salt contents for solutions of nitrate and chloride systems. The authors estimated the detection limits, the ranges of measurable contents, the standard deviations of the analysis results, the allowable contents of other components, and the requirements imposed on the accuracy in the measurement of the density, viscosity, electrical conductivity and temperature.

Mikhailov, V.A.

1986-02-01T23:59:59.000Z

172

Thin-layer chromatography and colorimetric analysis of multi-component explosive mixtures  

DOE Patents [OSTI]

A thin-layer chromatography method for detection and identification of common military and peroxide explosives in samples includes the steps of provide a reverse-phase thin-layer chromatography plate; prepare the plate by marking spots on which to deposit the samples by touching the plate with a marker; spot one micro liter of a first standard onto one of the spots, spot one micro liter of a second standard onto another of the spots, and spot samples onto other of spots producing a spotted plate; add eluent to a developing chamber; add the spotted plate to the developing chamber; remove the spotted plate from the developing chamber producing a developed plate; place the developed plate in an ultraviolet light box; add a visualization agent to a dip tank; dip the developed plate in the dip tank and remove the developed plate quickly; and detect explosives by viewing said developed plate.

Pagoria, Philip F.; Mitchell, Alexander R.; Whipple, Richard E.; Carman, M. Leslie

2014-08-26T23:59:59.000Z

173

Final Report for: "Bis-pi-allylpalladium Complexes in Catalysis of Multicomponent Reactions"  

SciTech Connect (OSTI)

The research project involved the development of new and functionally improved Pd(II) catalyst for a three-component reaction of boronic acids, allenes and imines to afford homoallylic amines that are useful in synthesis of biologically active heterocycles. Furthermore, insights into the reaction mechanism and the structure and reactivity of the catalytically active intermediates involved in this process were sought. As a result of this work, a new type of Pd-catalysts possessing an auxiliary ligand attached to the Pd center via a C-Pd and N-Pd bonds were identified, and found to be more active than the traditional catalysts derived from Pd(OAc)2. The new catalysts provided an access to a broader range of homoallylic amine products. Although the final unequivocal evidence regarding the structure of the Pd(II) complex involved in the nucleophilic transfer of the allyl fragment from the palladium center to the imine could not be obtained, mechanistic insights into the events that are detrimental to the activity of the originally reported Pd(OAc)2-based catalytic systems were uncovered.

Malinakova, H. C.; Shiota, Atsushi

2012-06-29T23:59:59.000Z

174

Driving force and composition for multicomponent gas hydrate nucleation from supersaturated aqueous solutions  

E-Print Network [OSTI]

formation in storage. Other interests include deep ocean carbon sequestration, use of hydrate deposits

Firoozabadi, Abbas

175

Multi-component modeling of quasielastic neutron scattering from phospholipid membranes  

SciTech Connect (OSTI)

We investigated molecular motions in the 0.3–350 ps time range of D{sub 2}O-hydrated bilayers of 1-palmitoyl-oleoyl-sn-glycero-phosphocholine and 1,2-dimyristoyl-sn-glycero-phosphocholine in the liquid phase by quasielastic neutron scattering. Model analysis of sets of spectra covering scale lengths from 4.8 to 30 Å revealed the presence of three types of motion taking place on well-separated time scales: (i) slow diffusion of the whole phospholipid molecules in a confined cylindrical region; (ii) conformational motion of the phospholipid chains; and (iii) fast uniaxial rotation of the hydrogen atoms around their carbon atoms. Based on theoretical models for the hydrogen dynamics in phospholipids, the spatial extent of these motions was analysed in detail and the results were compared with existing literature data. The complex dynamics of protons was described in terms of elemental dynamical processes involving different parts of the phospholipid chain on whose motions the hydrogen atoms ride.

Wanderlingh, U., E-mail: uwanderlingh@unime.it; D’Angelo, G.; Branca, C.; Trimarchi, A.; Rifici, S.; Finocchiaro, D. [Dipartimento di Fisica e Scienze della Terra, University of Messina, I-98166 Messina (Italy)] [Dipartimento di Fisica e Scienze della Terra, University of Messina, I-98166 Messina (Italy); Conti Nibali, V. [Institute for Physical Chemistry II, Ruhr-University Bochum, Bochum (Germany)] [Institute for Physical Chemistry II, Ruhr-University Bochum, Bochum (Germany); Crupi, C. [IPCF-V.le F. Stagno D’Alcontres, n. 37, Messina 98158 (Italy)] [IPCF-V.le F. Stagno D’Alcontres, n. 37, Messina 98158 (Italy); Ollivier, J. [Institut Laue-Langevin, 6 rue J. Horowitz, BP 156, F-38042 Grenoble (France)] [Institut Laue-Langevin, 6 rue J. Horowitz, BP 156, F-38042 Grenoble (France); Middendorf, H. D. [Clarendon Laboratory, University of Oxford, Oxford (United Kingdom)] [Clarendon Laboratory, University of Oxford, Oxford (United Kingdom)

2014-05-07T23:59:59.000Z

176

An analysis of the regenerative expansion cycle in multi-component hydrocarbon separation systems  

E-Print Network [OSTI]

absolute zero if the equip- ment is perfectly insulated and the amount of heat transfer surface is infinitely large. 5~~~%IIIIN(@Ni5@RAI)5@$5 IWW&~ 55SRINKa'RNSQRINSF)WJL%fOE& IMMMm y&~'~8?NMi&lKSSIKSAINF~ ILRRRF' ', IflF+RF)ISNi%IFkKAF4%:. , NJ NN&NRF... T X (d+g) T + T?(~ ~g) T dTm~zdl (TxTz) dT ~ dl [(Ot +Q) T i Y?- (Ol Jg) 7 - T] z dl % L y ln c z dT 1) Tz t Tx " (4++) T 1 1 [(al tg- 1) 7 + T? xl (aL )g) T 3 when L = 0 T = T 1 Tz = Tz 1 0 = ln (~t g- 1) T t T?- (4++) T zl xl zl c...

Horton, John Leroy

1966-01-01T23:59:59.000Z

177

Device For Determining Therophysical Properties Of A Multi-Component Gas At Arbitrary Temperature And Pressure  

DOE Patents [OSTI]

A computer product for determining thermodynamic properties of a natural gas hydrocarbon, when the speed of sound in the gas is known at an arbitrary temperature and pressure. Thus, the known parameters are the sound speed, temperature, pressure, and concentrations of any dilute components of the gas. The method uses a set of reference gases and their calculated density and speed of sound values to estimate the density of the subject gas. Additional calculations can be made to estimate the molecular weight of the subject gas, which can then be used as the basis for mass flow calculations, to determine the speed of sound at standard pressure and temperature, and to determine various thermophysical characteristics of the gas.

Morrow, Thomas B. (San Antonio, TX); Behring, II, Kendricks A. (Gilbert, AZ)

2005-02-01T23:59:59.000Z

178

Deep Geothermal Reservoir Temperatures in the Eastern Snake River Plain, Idaho using Multicomponent Geothermometry  

SciTech Connect (OSTI)

The U.S. Geological survey has estimated that there are up to 4,900 MWe of undiscovered geothermal resources and 92,000 MWe of enhanced geothermal potential within the state of Idaho. Of particular interest are the resources of the Eastern Snake River Plain (ESRP) which was formed by volcanic activity associated with the relative movement of the Yellowstone Hot Spot across the state of Idaho. This region is characterized by a high geothermal gradient and thermal springs occurring along the margins of the ESRP. Masking much of the deep thermal potential of the ESRP is a regionally extensive and productive cold-water aquifer. We have undertaken a study to infer the temperature of the geothermal system hidden beneath the cold-water aquifer of the ESRP. Our approach is to estimate reservoir temperatures from measured water compositions using an inverse modeling technique (RTEst) that calculates the temperature at which multiple minerals are simultaneously at equilibrium while explicitly accounting for the possible loss of volatile constituents (e.g., CO2), boiling and/or water mixing. In the initial stages of this study, we apply the RTEst model to water compositions measured from a limited number of wells and thermal springs to estimate the regionally extensive geothermal system in the ESRP.

Ghanashyam Neupane; Earl D. Mattson; Travis L. McLing; Carl D. Palmer; Robert W. Smith; Thomas R. Wood

2014-02-01T23:59:59.000Z

179

Modelin combustion of multicomponent fuel droplets: formulation and application to transportation fuels  

E-Print Network [OSTI]

rate constant was obtained as 0.344mm2/sec which compared well with the unsteady results of Reitz et al. The total evaporation time of the droplet at an ambience of 1000K was estimated to be around 0.63 seconds. Next, the results of evaporation...

Vittilapuram Subramanian, Kannan

2006-04-12T23:59:59.000Z

180

Gas Hydrate Equilibrium Measurements for Multi-Component Gas Mixtures and Effect of Ionic Liquid Inhibitors  

E-Print Network [OSTI]

hydrate inhibition data from a newly commissioned micro bench top reactor, a high-pressure autoclave and a rocking cell. The conditions for hydrate formation for pure methane and carbon dioxide were also measured, for validation purposes. The measured data...

Othman, Enas Azhar

2014-04-07T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Rigorous Separation Design. 1. Multicomponent Mixtures, Nonideal Mixtures, and Prefractionating Column Networks  

E-Print Network [OSTI]

the systematic design of energy-efficient separation networks. The methodology is ready to address currently unresolved design problems such as the computer-aided design of energy-efficient separations, the design for discovering energy-efficient configurations systematically. Until recently, however, there were no rigorous

Linninger, Andreas A.

182

Direct gas chromatography for the study of substrate removal kinetics in multi-component aqueous systems  

E-Print Network [OSTI]

component analyses of the aqueous solutions were performed by gas chromatography. The instrumentation consisted of' an Aero- graph Hy-Fi Model 550 gas chromatograph oven utilizing a hydrogen flame ionization detector. The detector was con- trolled... BY GAS CHROMATOGRAPHY, CHEMICAL OXYGEN DEMAND AND BIOCHEMICAL OXYGEN DEMAND Time Total Expected Measured R COD BOD Organics COD COD rrMn nEn mg. /1. nE'r mg. /1. nMn mg. /1. mg. /1. mg. /1. Control Hr 280 604- 225. 6 536 633 +29- 278 543 + 7 1...

Langley, William Douglas

1966-01-01T23:59:59.000Z

183

Dynamics, self-assembly, and function of multicomponent coordination supramolecular systems.  

E-Print Network [OSTI]

??Self-assembly allows for the preparation of highly complex molecular and supramolecular systems from relatively simple starting materials. Self-assembled supramolecules are typically constructed by combining complementary… (more)

Zheng, Yaorong

2011-01-01T23:59:59.000Z

184

The Effects of a Multicomponent Intervention on Treatment Integrity of Counterconditioning for Aggression in Dogs  

E-Print Network [OSTI]

The purpose of this study was to examine the effects of consumer management procedures on dog owner treatment integrity. A within subjects comparison was made. The primary dependent variable was treatment integrity. Errors ...

Savage, Kristyn Echterling

2011-12-31T23:59:59.000Z

185

The breakthrough time and permeation rate of multi-component solvents for selected glove materials  

E-Print Network [OSTI]

required to move molecules through the membrane (cal/mol) gas constant (2. 0 cal/mol ~ K) temperature ( K) Fick's Law states that the chemical permeation rate through a glove material is a function of: 1) diffusion coefficient of the permeation...: 1) Design of permeant collection test cell 2) Area of glove exposed to test chemical 3) Temperature of test chemical and glove material 4) Pressure of the permeation test cell when membrane is clamped in the two holding tephlon gaskets 5...

Brown, Bruce Gustav

1987-01-01T23:59:59.000Z

186

Analysis of seismic anisotropy in 3D multi-component seismic data   

E-Print Network [OSTI]

The importance of seismic anisotropy has been recognized by the oil industry since its first observation in hydrocarbon reservoirs in 1986, and the application of seismic anisotropy to solve geophysical problems has been ...

Qian, Zhongping

2010-01-01T23:59:59.000Z

187

Development of an automated diode-laser-based multicomponent gas sensor  

E-Print Network [OSTI]

-IR spectral region, room-temperature operation of cw single or multisection distributed feedback InGaAsP diode to the mid-IR spectro- scopic fingerprint region 3.3­4.4 m . A continuous absorption spectrum of CH4 and H2CO, and portable sensing device capable of high sensitiv- ity and rapid response time. Characteristic absorption

188

Rational design of self-assembly pathways for complex multicomponent structures  

E-Print Network [OSTI]

The field of complex self-assembly is moving toward the design of multi-particle structures consisting of thousands of distinct building blocks. To exploit the potential benefits of structures with such `addressable complexity,' we need to understand the factors that optimize the yield and the kinetics of self-assembly. Here we use a simple theoretical method to explain the key features responsible for the unexpected success of DNA-brick experiments, which are currently the only demonstration of reliable self-assembly with such a large number of components. Simulations confirm that our theory accurately predicts the narrow temperature window in which error-free assembly can occur. Even more strikingly, our theory predicts that correct assembly of the complete structure may require a time-dependent experimental protocol. Furthermore, we predict that low coordination numbers result in non-classical nucleation behavior, which we find to be essential for achieving optimal nucleation kinetics under mild growth conditions. We also show that, rather surprisingly, the use of heterogeneous bond energies improves the nucleation kinetics and in fact appears to be necessary for assembling certain intricate three-dimensional structures. This observation makes it possible to sculpt nucleation pathways by tuning the distribution of interaction strengths. These insights not only suggest how to improve the design of structures based on DNA bricks, but also point the way toward the creation of a much wider class of chemical or colloidal structures with addressable complexity.

William M. Jacobs; Aleks Reinhardt; Daan Frenkel

2015-02-04T23:59:59.000Z

189

A multi-component partitioning model to predict organic leaching from stabilized/solidified oily wastes  

E-Print Network [OSTI]

42 44 44 Figure 12. 3 Pseudo-Component Model using Modified K values, j = 1 Figure 13. TOC Leaching Rate from a Solidified Oily Waste, . ????, 46 50 LIST OF TABLES Table 1. Composition of Ordinary Portland Cement Table 2. Basic Hydration.... Ordinary Portland Cement (OPC) and flyash are common binders of choice as they are inexpensive, stable against damage and fire, and methods of mixing and processing them are well understood. Poor treatment efficiencies have been found when solidifying...

O'Cleirigh, Declan Ronan

1997-01-01T23:59:59.000Z

190

Freckle suppression in directional solidification of binary and multicomponent alloys using magnetic fields  

E-Print Network [OSTI]

a Lorentz force that opposes the thermosolutal buoyancy force and can be used to control or suppress melt coupling the electromagnetic and fluid flow phenomena. The induced electric potential depends on the fluid heating effect is neglected in the energy equation because of the high electrical conductivity of most

Zabaras, Nicholas J.

191

Use of computers for making multicomponent distillation calculations for reboiler-absorbers  

E-Print Network [OSTI]

/vli are those which are in material balance and in agreement with the specifications. The relationship may be stated as follows. (20) In a similar manner, the quantity 01 is used to express the relationship between the calculated and corrected values of wli... calculation and the minimum rate to I/1. 2 times the value used to make the calculation. At the end of the twentieth trial, p was further reduced to 0. 025 and at the end of the thirtieth trial, p was reduced to 0. 01. For other problems presented herein...

Canik, Leebert J

1961-01-01T23:59:59.000Z

192

Calculational procedure for multicomponent distillation columns with side-stream-strippers  

E-Print Network [OSTI]

, Based u ion tne Ji composition calculated by direct-iter;ition, the coi i icte. . te. . i, erature , irofilo ives ca' culated using iiewton's nethod. The above c. . lcul itio ial procedure w. - found to diver "e if the calcul. i ed i iate c&m csitions...M point calculations based on these oalculatcd cccqxositions, iXthsr Hex&ton&s mthod ca' ths . uxthcxx of interpolation ~ ~) ~ as dsscnibed by Sorolnikof' (27)& may be employed, Thc difference either in the m3culctod tempera5xres frcm trial to trix...

Dickey, Billy Ray

1962-01-01T23:59:59.000Z

193

Effective super Tonks-Girardeau gases as ground states of strongly attractive multicomponent fermions  

SciTech Connect (OSTI)

In the strong interaction limit, attractive fermions with N-component hyperfine states in a one-dimensional waveguide form unbreakable bound cluster states. We demonstrate that the ground state of strongly attractive SU(N) Fermi gases can be effectively described by a super Tonks-Girardeau gaslike state composed of bosonic cluster states with strongly attractive cluster-cluster interaction for even N and a Fermi duality of a super Tonks-Girardeau gaslike state composed of fermionic cluster states with weakly interacting cluster-cluster p-wave interaction for odd N.

Yin Xiangguo; Chen Shu [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Guan Xiwen [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Batchelor, M. T. [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Mathematical Sciences Institute, Australian National University, Canberra ACT 0200 (Australia)

2011-01-15T23:59:59.000Z

194

Coupling Multi-Component Models with MPH on Distributed Memory Computer Architectures  

E-Print Network [OSTI]

Among these, NASA’s Earth System Models Framework (ESMF) [to facilitate coupling earth system model components and to

He, Yun; Ding, Chris

2005-01-01T23:59:59.000Z

195

Study of multi-component fuel premixed combustion using direct numerical simulation  

E-Print Network [OSTI]

Fossil fuel reserves are projected to be decreasing, and emission regulations are becoming more stringent due to increasing atmospheric pollution. Alternative fuels for power generation in industrial gas turbines are thus required able to meet...

Nikolaou, Zacharias M.

2014-04-29T23:59:59.000Z

196

Method for FractMethod for Fracture Detection Using Multicomponent Seismic  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces andMapping theEnergy

197

New Design Methods and Algorithms for Multi-component Distillation Processes  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F S i DOETowardExecutiveRate principlesPierpontNewNewWellsDesign

198

Metabolic patterns of substrate removal in multi-component aqueous systems  

E-Print Network [OSTI]

. 25 8. 35 8. 45 8. 4o 8. 45 8. 50 8. 5o 8. 50 8. 45 8. 5o 86 Bo 84 86 50 FIGURE 3 'S I CRGANIC CONPONENT ANALYSES SI 0-STR! PPI NG ip ethyl ethanoate ethanol In Ph 30 L C3 CC 20 C) 7 ' 5 7. 0 IO 0 I 2 3 4 5 6 7 8 9 10 I] 12.... 5 W 8. 0 7 ' 5 7. 0 10 6. 5 0 I 2 3 4 5 6 8 9 10 11 12 13 14 TIME (hours) TABLE TEST 6 ANALYSIS DATA SUHNARY T ime hrs. -min. ethyl ethanoate mg/I A B propyl etnanoate mg/I A B butyl ethanoate mg/I A B pentyl ethanoate hexyl...

Richards, Paul Allen

1967-01-01T23:59:59.000Z

199

Numerical models of caldera deformation: Effects of multiphase and multicomponent hydrothermal fluid flow  

E-Print Network [OSTI]

in space and in time [e.g., Battaglia and Segall, 2004; Chang et al., 2007; Kwoun et al., 2006; Wicks et al/or gas pres- sures and GSD in volcanoes [e.g., Battaglia et al., 2006; Chiodini et al., 2003; Dzurisin et

200

The Multi-phase Optimization Strategy: A New Way to Develop Multi-component Interventions  

E-Print Network [OSTI]

statistical power - More economy 2 #12;The Classical Approach · Set of candidate components combined components - Refining of screened components to optimize intervention - Confirming effectiveness of optimized

Murphy, Susan A.

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

A Numerical Model for Miscible Displacement of Multi-Component Reactive Species  

E-Print Network [OSTI]

. Azarouala a Water Department/Groundwater and Geochemistry Modeling, BRGM (French Geological Survey) 3 of our approach. Therefore, the model may prove useful for many practical applications. 1. INTRODUCTION Demands to undertake modeling analysis of coupled groundwater ow, solute transport, and reactive water

Paris-Sud XI, Université de

202

Magnetism and magnetocaloric effect in multicomponent Laves-phase compounds: Study and comparative analysis  

SciTech Connect (OSTI)

This paper presents a review and results of comparative study of the influence of Gd on some physical properties of (R{sub 0.9}R?{sub 0.1}){sub 1?x}Gd{sub x}Co{sub 2} solid solutions with R=Dy, Ho and R?=Er, Ho and x varied from 0.05 to 0.15. Powder X-ray diffraction analysis performed at room temperature revealed that all studied solid solutions solidify with the formation of a Laves-phase MgCu{sub 2}-type structure (space group Fd?3m). The magnetization behavior and the magnetic transition are analyzed in terms of the Landau theory. The studies of magnetic properties and heat capacity showed that a relatively small Gd addition significantly increases T{sub C} of the compounds. The maximum percentage increase in T{sub C}, namely, ?43% was observed for (Ho{sub 0.9}Er{sub 0.1}){sub 1?x}Gd{sub x}Co{sub 2}. However, the highest temperature was noted for the (Dy{sub 0.9}Ho{sub 0.1}){sub 0.85}Gd{sub 0.15}Co{sub 2} solid solution; it is T{sub C}=183.4 K. Below the ordering temperature, all samples are ferrimagnetically ordered; at high temperatures, they are Curie–Weiss paramagnets. Moreover, a small Gd addition eliminates the field-induced magnetic transition near T{sub C} and, as consequence, transforms the nature of magnetic transition from the first- to second-order. The magnetocaloric effect has been estimated in terms of both isothermal magnetic entropy and adiabatic temperature changes. The highest adiabatic temperature change ?T{sub ad}=3 K and highest isothermal entropy change ?S{sub mag}=12.1 J/kg K were observed for (Ho{sub 0.9}Er{sub 0.1}){sub 0.95}Gd{sub 0.05}Co{sub 2} at ?90 K in magnetic fields of 2 T and 3 T, respectively. A decrease in the entropy change has been observed with increasing Gd content in all studied samples. The smallest values of ?S{sub mag} were observed for the (Dy{sub 0.9}Ho{sub 0.1}){sub 1?x}Gd{sub x}Co{sub 2} solid solutions. Under an external field change of from 0 to 3 T, the maximum entropy change for (Dy{sub 0.9}Ho{sub 0.1}){sub 1?x}Gd{sub x}Co{sub 2} compounds decreases from 6.9 at x=0.05–4.3 J/kg K at x=0.15. The refrigerant capacity for all solid solutions (with 0.05?x?0.15) is reported. The effect of increasing Gd content in the solid solutions on their magnetic and magnetocaloric properties is discussed. - Graphical abstract: Temperature dependencies of ?T{sub ad} induced by µ{sub 0}H=1 and 2 T in (a) (Ho{sub 0.9}Er{sub 0.1}){sub 1?x}Gd{sub x}Co{sub 2} and (b) (Dy{sub 0.9}Er{sub 0.1}){sub 1?x}Gd{sub x}Co{sub 2} solid solutions. Display Omitted.

?wik, J., E-mail: cwikjac@ml.pan.wroc.pl

2014-01-15T23:59:59.000Z

203

Multicomponent seismic data registration for subsurface characterization in the shallow Gulf of Mexico  

E-Print Network [OSTI]

Gulf of Mexico Sergey Fomel, Milo M. Backus, Michael V. DeAngelo, Paul E. Murray, Bob A. Hardage with application to subsurface characterization in the shallow Gulf of Mexico. In this study, we extend-S images. Application of this technique to data from the Gulf of Mexico reveals the structure of sediments

Texas at Austin, University of

204

Phase 2 and 3 Slim Hole Drilling and Testing at the Lake City, California Geothermal Field  

SciTech Connect (OSTI)

During Phases 2 and 3 of the Lake City GRED II project two slim holes were cored to depths of 1728 and 4727 ft. Injection and production tests with temperature and pressure logging were performed on the OH-1 and LCSH-5 core holes. OH-1 was permanently modified by cementing an NQ tubing string in place below a depth of 947 ft. The LCSH-1a hole was drilled in Quaternary blue clay to a depth of 1727 ft and reached a temperature of 193 oF at a depth of 1649 ft. This hole failed to find evidence of a shallow geothermal system east of the Mud Volcano but the conductive temperature profile indicates temperatures near 325 oF could be present below depth of 4000 ft. The LCSH-5 hole was drilled to a depth of 4727 ft and encountered a significant shallow permeability between depths of 1443 and 1923 ft and below 3955 ft. LCSH-5 drilled impermeable Quaternary fanglomerate to a depth of 1270 ft. Below 1270 ft the rocks consist primarily of Tertiary sedimentary rocks. The most significant formation deep in LCSH-5 appears to be a series of poikoilitic mafic lava flows below a depth of 4244 ft that host the major deep permeable fracture encountered. The maximum static temperature deep in LCSH-5 is 323 oF and the maximum flowing temperature is 329 oF. This hole extended the known length of the geothermal system by ¾ of a mile toward the north and is located over ½ mile north of the northernmost hot spring. The OH-1 hole was briefly flow tested prior to cementing the NQ rods in place. This flow test confirmed the zone at 947 ft is the dominant permeability in the hole. The waters produced during testing of OH-1 and LCSH-5 are generally intermediate in character between the deep geothermal water produced by the Phipps #2 well and the thermal springs. Geothermometers applied to deeper fluids tend to predict higher subsurface temperatures with the maximum being 382 oF from the Phipps #2 well. The Lake City geothermal system can be viewed as having shallow (elevation > 4000 ft and temperatures of 270 to 310 oF), intermediate (elevation 2800 to 3700 ft and temperatures 270 to 320 oF ) and deep (elevations < 1000 ft and temperatures 323 to 337 oF) components. In the south part of the field, near Phipps #2 the shallow and deep components are present. In the central part of the field, near OH-1 the shallow and intermediate components are present and presumably the deep component is also present. In the north part of the field, the intermediate and deep components are present. Most or all of the fractures in the core have dips between 45 degrees and vertical and no strong stratigraphic control on the resource has yet been demonstrated. Conceptually, the Lake City geothermal resource seems to be located along the north-south trending range front in a relatively wide zone of fractured rock. The individual fractures do not seem to be associated with any readily identifiable fault. In fact, no major hydraulically conductive faults were identified by the core drilling.

Dick Benoit; David Blackwell; Joe Moore; Colin Goranson

2005-10-27T23:59:59.000Z

205

Multi-Component Copper Catalyzed Methods to Access Highly-Substituted Amine-Bearing Carbon Centers from Simple Starting Materials  

E-Print Network [OSTI]

Modern physical organic chemistry; University Science Books:Modern physical organic chemistry; University Science Books:

Pierce, Conor John

2013-01-01T23:59:59.000Z

206

Multi-Component Copper Catalyzed Methods to Access Highly-Substituted Amine-Bearing Carbon Centers from Simple Starting Materials  

E-Print Network [OSTI]

2929, 2857, 2808, 1741, 1603, cm -1 . 1 H NMR (400 MHz, CDClcolumn. IR (film) 2929, 2857, 1603, 1507, 1245, 1221, 1036,film) 2927, 2854, 1715, 1603, 1496, 1453, 1121, 907, 733,

Pierce, Conor John

2013-01-01T23:59:59.000Z

207

Apparatus and method for maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling  

DOE Patents [OSTI]

A dilution apparatus for diluting a gas sample. The apparatus includes a sample gas conduit having a sample gas inlet end and a diluted sample gas outlet end, and a sample gas flow restricting orifice disposed proximate the sample gas inlet end connected with the sample gas conduit and providing fluid communication between the exterior and the interior of the sample gas conduit. A diluted sample gas conduit is provided within the sample gas conduit having a mixing end with a mixing space inlet opening disposed proximate the sample gas inlet end, thereby forming an annular space between the sample gas conduit and the diluted sample gas conduit. The mixing end of the diluted sample gas conduit is disposed at a distance from the sample gas flow restricting orifice. A dilution gas source connected with the sample gas inlet end of the sample gas conduit is provided for introducing a dilution gas into the annular space, and a filter is provided for filtering the sample gas. The apparatus is particularly suited for diluting heated sample gases containing one or more condensable components.

Felix, Larry Gordon; Farthing, William Earl; Irvin, James Hodges; Snyder, Todd Robert

2010-05-11T23:59:59.000Z

208

Development and anlysis of fast, approximate 3D Algorithms for interpretation of multi-component induction logging data  

SciTech Connect (OSTI)

This report addresses the effects of electrical anisotropy on the 3D inversion of single-well induction logging data when anisotropy is not considered. Of concern are possible artifacts that may lead to an incorrect interpretation of the formation about the borehole. Comparison is made of 3D isotropic inversion on a suite of model data, with and without anisotropy, consisting of an infinite layer and layer terminated at the borehole. In both cases, the layer dip (or well deviation) is varied. Inversion of the anisotropic data result in an overestimate of the layer conductivity, and the lateral extent of the layer about the borehole.

David L. Alumbaugh

2006-07-03T23:59:59.000Z

209

Phosphine-Mediated Multi-Component ?-Umpolung/Aldol/Wittig Cascade Reaction for the Synthesis of Functionalized Naphthalenes  

E-Print Network [OSTI]

developed for the synthesis of pyrroles, 11 furans, 12 andWittig reactions for the synthesis of pyrroles. Scheme 11.

Zhang, Kui

2013-01-01T23:59:59.000Z

210

Metal-free Michael addition initiated multicomponent oxidative cyclodehydration route to polysubstituted pyridines from 1,3-dicarbonylsw  

E-Print Network [OSTI]

applicability is clearly seen from the results reported in Table 1. Acrolein (2a) (entries 1, 4, 8, 10

Paris-Sud XI, Université de

211

Semiautomatic segmentation and follow-up of multicomponent low-grade tumors in longitudinal brain MRI studies  

SciTech Connect (OSTI)

Purpose: Tracking the progression of low grade tumors (LGTs) is a challenging task, due to their slow growth rate and associated complex internal tumor components, such as heterogeneous enhancement, hemorrhage, and cysts. In this paper, the authors show a semiautomatic method to reliably track the volume of LGTs and the evolution of their internal components in longitudinal MRI scans. Methods: The authors' method utilizes a spatiotemporal evolution modeling of the tumor and its internal components. Tumor components gray level parameters are estimated from the follow-up scan itself, obviating temporal normalization of gray levels. The tumor delineation procedure effectively incorporates internal classification of the baseline scan in the time-series as prior data to segment and classify a series of follow-up scans. The authors applied their method to 40 MRI scans of ten patients, acquired at two different institutions. Two types of LGTs were included: Optic pathway gliomas and thalamic astrocytomas. For each scan, a “gold standard” was obtained manually by experienced radiologists. The method is evaluated versus the gold standard with three measures: gross total volume error, total surface distance, and reliability of tracking tumor components evolution. Results: Compared to the gold standard the authors' method exhibits a mean Dice similarity volumetric measure of 86.58% and a mean surface distance error of 0.25 mm. In terms of its reliability in tracking the evolution of the internal components, the method exhibits strong positive correlation with the gold standard. Conclusions: The authors' method provides accurate and repeatable delineation of the tumor and its internal components, which is essential for therapy assessment of LGTs. Reliable tracking of internal tumor components over time is novel and potentially will be useful to streamline and improve follow-up of brain tumors, with indolent growth and behavior.

Weizman, Lior, E-mail: weizmanl@gmail.com [School of Engineering and Computer Science, The Hebrew University of Jerusalem, Jerusalem 91904 (Israel)] [School of Engineering and Computer Science, The Hebrew University of Jerusalem, Jerusalem 91904 (Israel); Sira, Liat Ben [Department of Radiology, Tel Aviv Medical Center, Tel Aviv University, Tel Aviv 64239 (Israel)] [Department of Radiology, Tel Aviv Medical Center, Tel Aviv University, Tel Aviv 64239 (Israel); Joskowicz, Leo [School of Engineering and Computer Science and The Edmond and Lily Safra Center for Brain Sciences (ELSC), The Hebrew University of Jerusalem, Jerusalem 91904 (Israel)] [School of Engineering and Computer Science and The Edmond and Lily Safra Center for Brain Sciences (ELSC), The Hebrew University of Jerusalem, Jerusalem 91904 (Israel); Rubin, Daniel L.; Yeom, Kristen W. [Department of Radiology, Stanford University, Stanford, California 94305 (United States)] [Department of Radiology, Stanford University, Stanford, California 94305 (United States); Constantini, Shlomi; Shofty, Ben [Tel Aviv Medical Center, Dana Children's Hospital, Tel Aviv University, Tel Aviv 64239 (Israel)] [Tel Aviv Medical Center, Dana Children's Hospital, Tel Aviv University, Tel Aviv 64239 (Israel); Bashat, Dafna Ben [Tel Aviv Medical Center, Functional Brain Center, Tel Aviv University, Tel Aviv 64239 (Israel)] [Tel Aviv Medical Center, Functional Brain Center, Tel Aviv University, Tel Aviv 64239 (Israel)

2014-05-15T23:59:59.000Z

212

A System And Method To Determine Thermophysical Properties Of A Multi-Component Gas At Arbitrary Temperature And Pressure  

DOE Patents [OSTI]

A method to determine thermodynamic properties of a natural gas hydrocarbon, when the speed of sound in the gas is known at an arbitrary temperature and pressure. Thus, the known parameters are the sound speed, temperature, pressure, and concentrations of any dilute components of the gas. The method uses a set of reference gases and their calculated density and speed of sound values to estimate the density of the subject gas. Additional calculations can be made to estimate the molecular weight of the subject gas, which can then be used as the basis for mass flow calculations, to determine the speed of sound at standard pressure and temperature, and to determine various thermophysical characteristics of the gas.

Morrow, Thomas E. (San Antonio, TX); Behring, II, Kendricks A. (Gilbert, AZ)

2004-03-09T23:59:59.000Z

213

Method and apparatus for maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling  

DOE Patents [OSTI]

An apparatus and method for diluting and cooling that is extracted from high temperature and/or high pressure industrial processes. Through a feedback process, a specialized, CFD-modeled dilution cooler is employed along with real-time estimations of the point at which condensation will occur within the dilution cooler to define a level of dilution and diluted gas temperature that results in a gas that can be conveyed to standard gas analyzers that contains no condensed hydrocarbon compounds or condensed moisture.

Farthing, William Earl (Pinson, AL) [Pinson, AL; Felix, Larry Gordon (Pelham, AL) [Pelham, AL; Snyder, Todd Robert (Birmingham, AL) [Birmingham, AL

2008-02-12T23:59:59.000Z

214

Method and apparatus maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling  

DOE Patents [OSTI]

An apparatus and method for diluting and cooling that is extracted from high temperature and/or high pressure industrial processes. Through a feedback process, a specialized, CFD-modeled dilution cooler is employed along with real-time estimations of the point at which condensation will occur within the dilution cooler to define a level of dilution and diluted gas temperature that results in a gas that can be conveyed to standard gas analyzers that contains no condensed hydrocarbon compounds or condensed moisture.

Farthing, William Earl (Pinson, AL); Felix, Larry Gordon (Pelham, AL); Snyder, Todd Robert (Birmingham, AL)

2009-12-15T23:59:59.000Z

215

Phosphine-Mediated Multi-Component ?-Umpolung/Aldol/Wittig Cascade Reaction for the Synthesis of Functionalized Naphthalenes  

E-Print Network [OSTI]

Ital. 1921, 53, 331. (7) Ugi, I; Meyr, R. ; Fetzer, U. ;Passerini reaction. Scheme 6. Ugi reaction. The phosphine-4 Mannich, 5 Passerini, 6 and Ugi 7 reactions (Schemes 1–6).

Zhang, Kui

2013-01-01T23:59:59.000Z

216

A multicomponent, two-phase-flow model for CO{sub 2} storage and enhanced coalbed-methane recovery  

SciTech Connect (OSTI)

Injection of CO{sub 2} into deep unminable coal seams is an option for geological storage of CO{sub 2} and may enhance the recovery of CH{sub 4} in these systems, making coal reservoirs interesting candidates for sequestration. New analytical solutions are presented for two-phase, three- and four-component flow with volume change on mixing in adsorbing systems. We analyze the simultaneous flow of water and gas containing multiple adsorbing components. The displacement problem is solved by the method of characteristics. Mixtures of N{sub 2}, CH{sub 4}, CO{sub 2}, and H{sub 2}O are used to represent enhanced coalbed-methane (ECBM) recovery processes. The displacement behavior is demonstrated to be strongly dependent on the relative adsorption strength of the gas components. In ternary systems, two types of solutions result. When a gas rich in CO{sub 2} displaces a less strongly adsorbing gas (such as CH{sub 4}), a shock solution is obtained. As the injected gas propagates through the system, CO{sub 2} is removed from the mobile phase by adsorption, while desorbed gas propagates ahead of the CO{sub 2} front. The adsorption of CO{sub 2} reduces the flow velocity of the injected gas, delaying breakthrough and allowing for more CO{sub 2} to be sequestered per volume of CH{sub 4} produced. For injection gases rich in N{sub 2}, a decrease in partial pressure is required to displace the preferentially adsorbed CH{sub 4} and a rarefaction solution results. In quaternary displacements with injection-gas mixtures of CO{sub 2} and N{sub 2}, the relative adsorption strength of the components results in solutions that exhibit features of both the N{sub 2}-rich and CO{sub 2}-rich ternary displacements. Analytical solutions for ECBM recovery processes provide insight into the complex interplay of adsorption, phase behavior, and convection.

Seto, C.J.; Jessen, K.; Orr, F.M. [University of Southern California, Los Angeles, CA (United States)

2009-03-15T23:59:59.000Z

217

CO2 gas/oil ratio prediction in a multi-component reservoir bycombined seismic and electromagnetic imaging  

SciTech Connect (OSTI)

Crosswell seismic and electromagnetic data sets taken before and during CO2 flooding of an oil reservoir are inverted to produce crosswell images of the change in compressional velocity, shear velocity and electrical conductivity during a CO2 injection pilot study. A rock properties model is developed using measured log porosity, fluid saturations, pressure, temperature, bulk density, sonic velocity and electrical conductivity. The parameters of the rock properties model are found by an L1-norm simplex minimization of predicted and observed compressional velocity and density. A separate minimization using Archie's law provides parameters for modeling the relations between water saturation, porosity and the electrical conductivity. The rock properties model is used to generate relationships between changes in geophysical parameters and changes in reservoir parameters. The electrical conductivity changes are directly mapped to changes in water saturation. The estimated changes in water saturation are used with the observed changes in shear wave velocity to predict changes in reservoir pressure. The estimation of the spatial extent and amount of CO2 relies on first removing the effects of the water saturation and pressure changes from the observed compressional velocity changes, producing a residual compressional velocity change. The residual compressional velocity change is then interpreted in terms of increases in the CO2 /oil ratio. Resulting images of CO2/oil ratio show CO2 rich zones that are well correlated with the location of injection perforations with the size of these zones also correlating to the amount of injected CO2. The images produced by this process are better correlated to the location and amount of injected CO2 than are any of the individual images of change in geophysical parameters.

Hoversten, G.M.; Gritto, Roland; Washbourne, John; Daley, Tom

2002-08-28T23:59:59.000Z

218

Final Technical Report DE-FG02-99ER14933 Inversion of multicomponent seismic data and rock physics interpretation  

SciTech Connect (OSTI)

An important accomplishment was to understand the seismic velocity anisotropy resulting from the combined roles of depositional stratification and stress in unconsolidated sands. The report presents an experimental study of velocity anisotropy in unconsolidated sands at measured compressive stresses up to 40 bars, which correspond to the first hundred meters of the subsurface. Two types of velocity anisotropy are considered, that due to intrinsic textural anisotropy, and that due to stress anisotropy. We found that sand samples display a bi-linear dependence of velocity anisotropy with stress anisotropy. There exists a transition stress beyond which the stress-induced anisotropy outweighs the intrinsic anisotropy for three different sands.

Mavko, G.

2006-03-15T23:59:59.000Z

219

Multi-Component Copper Catalyzed Methods to Access Highly-Substituted Amine-Bearing Carbon Centers from Simple Starting Materials  

E-Print Network [OSTI]

123 Chapter 3: Copper/Titanium Catalysis Forms Fully-187 vi Chapter 4: Copper-Catalyzed Tandem Markovnikov237 III. Copper(II) Triflate in Dual-Catalytic Role is

Pierce, Conor John

2013-01-01T23:59:59.000Z

220

Ab initio Based Modeling of Radiation Effects in Multi-Component Alloys: Final Scientific/Technical Report  

SciTech Connect (OSTI)

The project began March 13, 2006, allocated for three years, and received a one year extension from March 13, 2009 to March 12, 2010. It has now completed 48 of 48 total months. The project was focused on using ab initio methods to gain insights into radiation induced segregation (RIS) in Ni-Fe-Cr alloys. The project had the following key accomplishments • Development of a large database of ab initio energetics that can be used by many researchers in the future for increased understanding of this system. For example, we have the first calculations showing a dramatic stabilization effect of Cr-Cr interstitial dumbbells in Ni. • Prediction of both vacancy and interstitial diffusion constants for Ni-Cr and Ni-Fe for dilute Cr and Fe. This work included generalization of widely used multifrequency models to make use of ab initio derived energetics and thermodynamics. • Prediction of qualitative trends of RIS from vacancy and interstitial mechanisms, suggesting the two types of defect fluxes drive Cr RIS in opposite directions. • Detailed kinetic Monte Carlo modeling of diffusion by vacancy mechanism in Ni-Cr as a function of Cr concentration. The results demonstrate that Cr content can have a significant effect on RIS. • Development of a quantitative RIS transport model, including models for thermodynamic factors and boundary conditions.

Dane Morgan

2010-06-10T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

PHYSICAL REVIEW B 86, 085123 (2012) Composition-dependent oxygen vacancy formation in multicomponent wide-band-gap oxides  

E-Print Network [OSTI]

PHYSICAL REVIEW B 86, 085123 (2012) Composition-dependent oxygen vacancy formation University of Science and Technology, Rolla, Missouri 65409, USA (Received 17 April 2012; revised manuscript received 19 July 2012; published 16 August 2012) The formation and distribution of oxygen vacancy

Medvedeva, Julia E.

222

CO2 gas/oil ratio prediction in a multi-component reservoir by combined seismic and electromagnetic imaging  

E-Print Network [OSTI]

CO 2 flooding of an oil reservoir are inverted to producein a complex reservoir containing oil, water, hydrocarbonincluding oil, water and gas) and reservoir pressure. The

Hoversten, G.M.; Gritto, Roland; Washbourne, John; Daley, Tom

2002-01-01T23:59:59.000Z

223

Rencontres Gosynthtiques -9-11 avril 2013, Dijon MESURE DU FLUX DANS LES GOFILMS BENTONITIQUES  

E-Print Network [OSTI]

BENTONITIQUES FLOW RATE MEASUREMENT IN MULTICOMPONENT GEOSYNTHETIC CLAY LINERS Camille BARRAL1 , Nathalie TOUZE /d. Keywords: geosynthetics, geomembrane, multicomponent geosynthetic clay liner, flow rate. 1

Boyer, Edmond

224

New Prospects for High Performance SONAR, Chemical Sensor, and Communication Device Materials  

E-Print Network [OSTI]

), such as the cathode material lanthanum strontium cobalt ferrite (LSCF). The complexity of these multicomponent systems

Rappe, Andrew M.

225

PETER WIPF, PHD BIOGRAPHICAL SKETCH  

E-Print Network [OSTI]

synthesis: Fluorous protocols for the Biginelli and Ugi multi-component condensations." J. Org. Chem. 1997

226

Indirect Measurement Of Nitrogen In A Multi-Component Gas By Measuring The Speed Of Sound At Two States Of The Gas.  

DOE Patents [OSTI]

A methods of indirectly measuring the nitrogen concentration in a gas mixture. The molecular weight of the gas is modeled as a function of the speed of sound in the gas, the diluent concentrations in the gas, and constant values, resulting in a model equation. Regression analysis is used to calculate the constant values, which can then be substituted into the model equation. If the speed of sound in the gas is measured at two states and diluent concentrations other than nitrogen (typically carbon dioxide) are known, two equations for molecular weight can be equated and solved for the nitrogen concentration in the gas mixture.

Morrow, Thomas B. (San Antonio, TX); Behring, II, Kendricks A. (Torrance, CA)

2004-10-12T23:59:59.000Z

227

From research to practice: the effect of multi-component vocabulary instruction on fourth grade students' social studies vocabulary and comprehension performance  

E-Print Network [OSTI]

in learning tasks, vocabulary maps, connections webs, and semantic feature analysis. The focus was on using direct, explicit instruction of vocabulary strategies and the resulting outcomes. Curriculum was designed for a six-week period using the district...

Graham, Lori Dear

2009-05-15T23:59:59.000Z

228

REAL-TIME CHEMICAL SENSING IN THIN FILM MULTICOMPONENT Theodosia Gougousi, Department of Materials and Nuclear Engineering and Institute for Systems  

E-Print Network [OSTI]

with two cold wall CVD reactors, a load lock, and a buffer chamber. Heating lamps positioned outside and above the reactor provide heating to the wafer. The gas supply system is designed so that H2

Gougousi, Theodosia

229

WATER RESOURCES RESEARCH, VOL. 29, NO. 11, PAGES 3727-3740, NOVEMBER 1993 Modeling of Multiphase Transport of Multicomponent Organic Contaminants  

E-Print Network [OSTI]

WATER RESOURCES RESEARCH, VOL. 29, NO. 11, PAGES 3727-3740, NOVEMBER 1993 Modeling of Multiphase. Although these organic liquids are designatedas "nonaque- ous," i.e., immiscible with water, their solubilities in water are, in fact, sufficientto render large quantities of ground- water unfit for human use

Patzek, Tadeusz W.

230

Multi component Nanoparticle Based Lubricant Additive to Improve...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Multi-component Nanoparticle Based Lubricant Additive to Improve Efficiency and Durability in Engines ITP Nanomanufacturing:...

231

Integrated Chemical Geothermometry System for Geothermal Exploration  

Broader source: Energy.gov (indexed) [DOE]

interpretations) * Reduce exploration and development costs Innovation * Numerical optimization of multicomponent chemical geothermometry at multiple locations * Integration with...

232

Environmental Toxicology and Chemistry, Vol. 18, No. 3, pp. 426429, 1999 Printed in the USA  

E-Print Network [OSTI]

--Nonaqueous phase liquid Polycyclic aromatic hydrocarbons Coal tar UNIFAC Multicomponent INTRODUCTION Many in the USA 0730-7268/99 $9.00 .00 UNIFAC MODELING OF MULTICOMPONENT NONAQUEOUS PHASE LIQUIDS CONTAINING-2125, USA (Received 12 March 1998; Accepted 17 June 1998) Abstract--Multicomponent nonaqueous phase liquid

Peters, Catherine A.

233

VOLUME 81, NUMBER 1 P H Y S I C A L R E V I E W L E T T E R S 6 JULY 1998 Bobylev-Krook-Wu Modes for Multicomponent Gas Mixtures  

E-Print Network [OSTI]

-Krook-Wu (BKW) mode. The BKW mode is of physical interest for ex- plicit modeling of some nonequilibrium] that the conditions of the BKW mode exis- tence formulated in [3] could be weakened. As a matter of fact, the BKW modes were not considered in [4]. Re- cently, in [5] the BKW modes were obtained for a binary gas

Meleshko, Sergey V.

234

Additivity of detector responses of a portable direct-reading 10. 2 eV photoionization detector and a flame ionization gas chromatograph for atmospheres of multicomponent organics: use of PID/FID ratios  

SciTech Connect (OSTI)

The H-Nu PI-101 with a photoionization detector (PID) of 10.2 eV and Century OVA-128 equipped with a flame ionization detector (FID) were evaluated for the additivity of their responses to a defined mixtures of dissimilar organic vapors at a 0 and 90% relative humidity (RH). The responses of both instruments were additive as long as the effect of RH was accounted for the PID. The PI-101 was not as precise as the Century OVA-128 for 90% RH atmospheres. PID/FID ratios did not change in the presence of 90% RH as long as the effect of RH also was accounted for in the PID reading. The compounds investigated included: toluene, benzaldehyde; 1,2,4-trichlorobenzene, methyl chloroform, methylene dichloride, methyl ethyl ketone, ethanol and acetonitrile.

Lee, I.N.; Hee, S.S.Q.; Clark, C.S.

1987-05-01T23:59:59.000Z

235

Synthesis and Evaluation of Novel Iminosugars as Potential Male Contraceptive Agents; and the Chemistry of 2,3-Dihydropyridin-4-(1H)-ones and Related Enaminones in Multicomponent Reactions  

E-Print Network [OSTI]

.2 Preliminary studies concerning the C5 nucleophilicity 2.2.1 Instalation of alkyl groups at the C5 position 2.2.2 Aminomethylation at the C5 position and the utilization of LiClO 4 2.3 LiClO 4 -assisted Synthesis of 3-functionalized-4...,6,7,8-tetrahydro- quinoline-2,5-diones 2.3.1 LiClO 4 -assisted formation of enaminone methylmalonates 2.3.2 Mechanistic studies 63 68 68 69 69 74 74 75 7 78 80 83 83 8 92 93 96 ? 8 2.3.3 Anulation...

Gu, Xingxian

2010-04-26T23:59:59.000Z

236

februari 2008 MassMass transfer & separation technology 424302 2008transfer & separation technology 424302 2008 --APPENDIXAPPENDIX  

E-Print Network [OSTI]

Multicomponent mixturesmixtures"" by J.A.by J.A. WesselinghWesselingh & R. Krishna,& R. Krishna, DelftDelft University Press (2000Transfer in MulticomponentMulticomponent mixturesmixtures"" by J.A.by J.A. WesselinghWesselingh & R. Krishna,& R. Krishna"" by J.A.by J.A. WesselinghWesselingh & R. Krishna,& R. Krishna, DelftDelft University Press (2000

Zevenhoven, Ron

237

E-Print Network 3.0 - antipsycotic drug chlorpromazine Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

discovery of multicomponent therapeutics Alexis A. Borisy, Peter J. Elliott, Nicole W. Hurst, Margaret S. Lee, Joseph Lehar, E. Roydon Price, George Serbedzija, Summary:...

238

Seismic Technology Adapted to Analyzing and Developing Geothermal...  

Open Energy Info (EERE)

GEDCO, RARE Technology, and Sercel, Inc. to combine multicomponent seismic technology and rock physics modeling that will lead to the ability to image and analyze geothermal...

239

CX-002608: Categorical Exclusion Determination | Department of...  

Broader source: Energy.gov (indexed) [DOE]

Sequestered in Geologic Systems with Multicomponent Seismic Technology and Rock Physics Modeling CX(s) Applied: A9 Date: 12112009 Location(s): Austin, Texas Office(s):...

240

Geothermal: Sponsored by OSTI -- GeoT User's Guide: A Computer...  

Office of Scientific and Technical Information (OSTI)

Program for Multicomponent Geothermometry and Geochemical Speciation, Version 1.4 Geothermal Technologies Legacy Collection HelpFAQ | Site Map | Contact Us HomeBasic Search...

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

E-Print Network 3.0 - asymmetric aza-michael reactions Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: Multicomponent Reactions DOI: 10.1002anie.201103567 A Bioinspired UgiMichaelAza-Michael Cascade... reaction had occurred as the first reaction in the Ugi...

242

E-Print Network 3.0 - advanced reservoir characterization Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

<< < 1 2 3 4 5 > >> 1 TEXAS A&M UNIVERSITY Reservoir Geophysics Program Summary: and fracture analysis, multi-component seismic reservoir characterization, quantitative reservoir...

243

E-Print Network 3.0 - americium alloys Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

University of California, Davis Collection: Physics 34 Freckle suppression in directional solidification of binary and multicomponent alloys using magnetic fields Summary:...

244

U.S. DEPARTMENT OF ENERGY - NETL CATEGORICAL EXCLUSION (CX) DESIGNATIO...  

Broader source: Energy.gov (indexed) [DOE]

and Accounting of CO2 Sequestered in Geologic Systems with Multicomponent Seismic Technology and Rock Physics Modeling Please see SOPO attached. This NEPA action is to...

245

Resolving Conformational and Rotameric Exchange in Spin-Labeled Proteins Using Saturation Recovery EPR  

E-Print Network [OSTI]

Using Saturation Recovery EPR Michael D. Bridges • Ka lma nparamagnetic resonance (EPR) spectra can arise either fromgive rise to multicomponent EPR spectra; rota- mer exchange

Bridges, Michael D.; Hideg, Kálmán; Hubbell, Wayne L.

2010-01-01T23:59:59.000Z

246

Transport of Injected Isobutane by Thermal Groundwater in Long...  

Open Energy Info (EERE)

uses of isotopes have led to novel interpretations of the evolution of fluid and rock chemistry over time. New modelling techniques have allowed elucidation of multi-component...

247

An Explicit Runge-Kutta Iteration for Diffusion in the Low Mach Number Combustion Code  

E-Print Network [OSTI]

usion in the Low Mach Number Combustion Code Joseph F. Grcarthe low Mach number combustion code. Contents 1 Introductionthe low Mach number combustion code, LMC. The multicomponent

Grcar, Joseph F.

2007-01-01T23:59:59.000Z

248

Attractive electrostatic self-assembly of ordered and disordered heterogeneous colloids  

E-Print Network [OSTI]

Ionic colloidal crystals are here defined as multicomponent ordered colloidal structures stabilized by attractive electrostatic interactions. These crystals are colloidal analogues to ionic materials including zincblende, ...

Maskaly, Garry R. (Garry Russell), 1978-

2005-01-01T23:59:59.000Z

249

E-Print Network 3.0 - area iberian pyrite Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Geosciences 23 Multicomponent reactive transport modeling at the Ratones uranium mine, Cceres (Spain) Summary: : 1698-6180 www.ucm.esinfoestratigjournal.htm...

250

OPTIMAL CONTROL OF PARTIALLY MISCIBLE TWO-PHASE FLOW WITH APPLICATIONS TO SUBSURFACE CO2 SEQUESTRATION  

E-Print Network [OSTI]

control problems that are governed by multiphase multicomponent flow in porous media. The concrete in porous media. The objective is, e.g., to maximize the amount of trapped CO2 in an underground reservoir/FV methods for multiphase multicomponent flows in porous media we refer to [11] and references therein

Ulbrich, Michael

251

Molecules 2011, 16, 9261-9273; doi:10.3390/molecules16119261 ISSN 1420-3049  

E-Print Network [OSTI]

of pyrrolidino- pyridines and pyrimidines illustrates the potential of combining Ugi-Smiles couplings with radical tin-free processes. Keywords: Ugi-Smiles coupling; xanthates; multicomponent reactions; radical processes; isocyanides 1. Introduction Among multi-component reactions (MCRs), the Ugi reaction has

Paris-Sud XI, Université de

252

Mechanistic Modelling of Water Vapour Condensation in Presence of  

E-Print Network [OSTI]

analysis of the water vapour condensation from the multicomponent mixture of condensable and noncondensable attention has been paid to the influence of the light gas and induced buoyancy forces on the condensation the multicomponent gas distribution and condensation heat transfer degradation are directly related

Haviland, David

253

Method of joining ITM materials using a partially or fully-transient liquid phase  

DOE Patents [OSTI]

A method of forming a composite structure includes: (1) providing first and second sintered bodies containing first and second multicomponent metallic oxides having first and second identical crystal structures that are perovskitic or fluoritic; (2) providing a joint material containing at least one metal oxide: (a) containing (i) at least one metal of an identical IUPAC Group as at least one sintered body metal in one of the multicomponent metallic oxides, (ii) a first row D-Block transition metal not contained in the multicomponent metallic oxides, and/or (iii) a lanthanide not contained in the multicomponent metallic oxides; (b) free of metals contained in the multicomponent metallic oxides; (c) free of cations of boron, silicon, germanium, tin, lead, arsenic, antimony, phosphorus and tellurium; and (d) having a melting point below the sintering temperatures of the sintered bodies; and (3) heating to a joining temperature above the melting point and below the sintering temperatures.

Butt, Darryl Paul; Cutler, Raymond Ashton; Rynders, Steven Walton; Carolan, Michael Francis

2006-03-14T23:59:59.000Z

254

ChemFeeds -The targeted delivery of multicomponent cargos to cancer cells by nanoporous particle-supported lipid bilayers http://www.chemfeeds.com/comments.php?doi=10.1038/nmat2992[4/21/2011 11:45:43 AM  

E-Print Network [OSTI]

-supported lipid bilayers http://www.chemfeeds.com/comments.php?doi=10.1038/nmat2992[4/21/2011 11:45:43 AM] New by nanoporous particle-supported lipid bilayers http://www.chemfeeds.com/comments.php?doi=10.1038/nmat2992 to cancer cells by nanoporous particle-supported lipid bilayers http://www.chemfeeds.com/comments.php?doi=10

Brinker, C. Jeffrey

255

Computational upscaled modeling of heterogeneous porous media flow utilizing finite volume method  

E-Print Network [OSTI]

. Finally we will present several applications of the multiscale method in the ?ow in porous media. Problems that we will consider are multiphase immiscible ?ow, multicomponent miscible ?ow, and soil in?ltration in saturated/unsaturated...

Ginting, Victor Eralingga

2005-08-29T23:59:59.000Z

256

Design and Synthesis of a Novel Triptycene-Based Ligand for Modeling Carboxylate-Bridged Diiron Enzyme Active Sites  

E-Print Network [OSTI]

A novel triptycene-based ligand with a preorganized framework was designed to model carboxylate-bridged diiron active sites in bacterial multicomponent monooxygenase (BMM) hydroxylase enzymes. The synthesis of the ...

Li, Yang

257

Dioxygen activation and substrate hydroxylation by the hydroxylase component of toluene/O-xylene monooxygenase from pseudomonas sporium OX1  

E-Print Network [OSTI]

Non-heme carboxylate-bridged diiron centers in the hydroxylase components of the bacterial multicomponent monooxygenases activate dioxygen at structurally homologous active sites. Catalysis requires the management of four ...

Murray, Leslie Justin

2007-01-01T23:59:59.000Z

258

Analytical modelling of hydrogen transport in reactor containments  

E-Print Network [OSTI]

There are two diffusion processes, molecular and turbulent, which should be modelled in different ways. Molecular diffusion is modelled by Wilke's formula for the multi-component gas diffusion, where the diffusion constants ...

Manno, V.

1983-01-01T23:59:59.000Z

259

A method for tradespace exploration of systems of systems  

E-Print Network [OSTI]

Systems of Systems (SoS) are a current focus of many organizations interested in integrating assets and utilizing new technology to create multi-component systems that deliver value over time. The dynamic composition of ...

Chattopadhyay, Debarati

2009-01-01T23:59:59.000Z

260

Why perform time-lapse seismic monitoring? Is it to ver-ify the reservoir model? No! We should conduct time-lapse  

E-Print Network [OSTI]

the Teal South time-lapse multicomponent (4-D/4-C) study, in Eugene Island Block 354 in the Gulf of Mexico by Texaco, has been continued through a consortium organized by the Energy Research Clearing House. Some

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Mutoru, Jane Wambui Curriculum Vitae  

E-Print Network [OSTI]

and multicomponent mixtures with carbon dioxide for applications in CO2 sequestration and enhanced oil recovery coefficients in mixtures of carbon dioxide, water, brine, and hydrocarbons Yale University, New Haven, CT Jan

Firoozabadi, Abbas

262

The Microbial Opsin Family of Optogenetic Tools  

E-Print Network [OSTI]

The capture and utilization of light is an exquisitely evolved process. The single-component microbial opsins, although more limited than multicomponent cascades in processing, display unparalleled compactness and speed. ...

Zhang, Feng

263

Investigations into the biosynthesis of salinosporamide A : new insights on PKS extender units and the origin of a nonproteinogenic amino acid  

E-Print Network [OSTI]

J. J Am Chem Soc 2004, 126, Ugi, I. Angew Chem 1962, 74, 9-R. Multicompon React 2005, 1- (10) Ugi, I. ; Offermann, K. ;Ann Chem 1967, 709, 1-10. Ugi, I. ; Kaufhold, G. Justus

Liu, Yuan

2010-01-01T23:59:59.000Z

264

A Biophysical Approach to Investigate the Human Fe-S Cluster Assembly Pathway  

E-Print Network [OSTI]

Iron sulfur (Fe-S) clusters are essential cofactors that function in electron transport, catalyzing substrate turnover, environmental sensing, and initiating radical chemistry. Elaborate multi-component systems have evolved to protect organisms from...

Fox, Nicholas G

2014-06-02T23:59:59.000Z

265

A comparison of iterative methods to solve complex valued linear algebraic systems  

E-Print Network [OSTI]

, electromagnetism, structural dynamics, electrical power system models, wave propagation, magnetized multicomponent.axelsson@it.uu.se Department of Information Technology, Uppsala University, Sweden, maya.neytcheva@it.uu.se King Abdulaziz

Flener, Pierre

266

Long-Term Composition Dynamics of PAH-Containing NAPLs and  

E-Print Network [OSTI]

08544 Subsurface contaminants such as coal tar, creosote, diesel fuel, and other petroleum the factors governing human health risk assessment for multicomponent nonaqueous phase liquids (NAPLs of environmental pollution involving PAHs is subsurface contamination from nonaque- ous phase liquid (NAPL

Peters, Catherine A.

267

Light Duty Combustion Research: Advanced Light-Duty Combustion...  

Broader source: Energy.gov (indexed) [DOE]

Developed multi-component vaporization models 6 Facility and operating conditions The optical engine matches a metal test engine at UW The optical piston retains the same bowl and...

268

Blind benchmark predictions of the NACOK air ingress tests using the CFD code FLUENT  

E-Print Network [OSTI]

The JAERI and NACOK experiments examine the combined effects of natural convection during an air ingress event: diffusion, onset of natural circulation, graphite oxidation and multicomponent chemical reactions. MIT has ...

Brudieu, Marie-Anne V

2007-01-01T23:59:59.000Z

269

Mutations in the Caenorhabditis elegans U2AF Large Subunit UAF-1 Al= of a 3' Splice Site In Vivo  

E-Print Network [OSTI]

The removal of introns from eukaryotic RNA transcripts requires the activities of five multi-component ribonucleoprotein complexes and numerous associated proteins. The lack of mutations affecting splicing factors essential ...

Ma, Long

270

Mutations in the Caenorhabditis elegans U2AF Large Subunit UAF-1 Alter the Choice of a 3' Splice Site In Vivo  

E-Print Network [OSTI]

The removal of introns from eukaryotic RNA transcripts requires the activities of five multi-component ribonucleoprotein complexes and numerous associated proteins. The lack of mutations affecting splicing factors essential ...

Ma, Long

271

The role of mammalian target of rapamycin complex 1 in hepatic physiology and disease  

E-Print Network [OSTI]

The multi-component kinase mTOR complex 1 (mTORC 1) coordinates nutrient and growth factor inputs with numerous downstream processes including protein translation, autophagy, metabolism and cell growth. We have found that ...

Sengupta, Shomit

2010-01-01T23:59:59.000Z

272

FUSION- A Knowledge Management System for Fuel Cell Optimization  

E-Print Network [OSTI]

Fuel cells are highly complex multi-component systems. Their efficiency depends on their internal nanostructure and the complex chemical and physical processes occurring across their internal interfaces. Significant

Jane Hunter; Kwok Cheung; Suzanne Little; John Drennan

273

Lattice Boltzmann equation simulations of turbulence, mixing, and combustion  

E-Print Network [OSTI]

We explore the capability of lattice Boltzmann equation (LBE) method for complex fluid flows involving turbulence, mixing, and reaction. In the first study, LBE schemes for binary scalar mixing and multi-component reacting flow with reactions...

Yu, Huidan

2006-04-12T23:59:59.000Z

274

Studies of the analyte-carrier interface in flow injection analysis  

SciTech Connect (OSTI)

Chemical analysis in flowing solution is popular for automation of classical methods. However, most of the classical methods are not specific enough for direct multicomponent analysis of simple mixtures. This research project has the goals of study of rapid multicomponent analysis of transient species in flowing media, and investigations of chemical reactions at interfaces and of effects of competition on distribution of products from interfacial reaction. This report summarizes work done over the past 4.5 years; support has been terminated.

Brown, S.D.

1992-01-01T23:59:59.000Z

275

Studies of the analyte-carrier interface in flow injection analysis. Final report, June 1, 1987--January 31, 1992  

SciTech Connect (OSTI)

Chemical analysis in flowing solution is popular for automation of classical methods. However, most of the classical methods are not specific enough for direct multicomponent analysis of simple mixtures. This research project has the goals of study of rapid multicomponent analysis of transient species in flowing media, and investigations of chemical reactions at interfaces and of effects of competition on distribution of products from interfacial reaction. This report summarizes work done over the past 4.5 years; support has been terminated.

Brown, S.D.

1992-12-31T23:59:59.000Z

276

Removal of residual uranium in simulated radwaste solution by TBP extraction  

SciTech Connect (OSTI)

The extraction behavior of uranium in a multicomponent system simulated on the basis of high-level liquid waste was examined in order to find effective conditions for the removal of residual uranium in a simulated radwaste solution by the TBP solvent extraction method. While the conventional semiempirical equation for the distribution coefficient of uranium could be used in a system composed of only uranium and nitric acid, it was found to be unsuitable for a multicomponent system where the concentration of uranium is not dominant. Uranium extractability by TBP was found to be limited in multicomponents systems regardless of high TBP concentration, phase ratio, and extraction times because of the presence of neodymium and iron together with uranium in the systems.

Kim, Kwang-Wook; Lee, Eil-Hee; Shin, Young-Joon [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)] [and others

1995-10-01T23:59:59.000Z

277

Universal Tomonaga-Luttinger liquid phases in one-dimensional strongly attractive SU(N) fermionic cold atoms  

SciTech Connect (OSTI)

A simple set of algebraic equations is derived for the exact low-temperature thermodynamics of one-dimensional multicomponent strongly attractive fermionic atoms with enlarged SU(N) spin symmetry and Zeeman splitting. Universal multicomponent Tomonaga-Luttinger liquid (TLL) phases are thus determined. For linear Zeeman splitting, the physics of the gapless phase at low temperatures belongs to the universality class of a two-component asymmetric TLL corresponding to spin-neutral N-atom composites and spin-(N-1)/2 single atoms. The equation of state which we obtained provides a precise description of multicomponent composite fermions and opens up the study of quantum criticality in one-dimensional systems of N-component Fermi gases with population imbalance.

Guan, X. W.; Lee, J.-Y. [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Batchelor, M. T. [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Mathematical Sciences Institute, Australian National University, Canberra ACT 0200 (Australia); Yin, X.-G.; Chen Shu [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

2010-08-15T23:59:59.000Z

278

Planar ceramic membrane assembly and oxidation reactor system  

DOE Patents [OSTI]

Planar ceramic membrane assembly comprising a dense layer of mixed-conducting multi-component metal oxide material, wherein the dense layer has a first side and a second side, a porous layer of mixed-conducting multi-component metal oxide material in contact with the first side of the dense layer, and a ceramic channeled support layer in contact with the second side of the dense layer. The planar ceramic membrane assembly can be used in a ceramic wafer assembly comprising a planar ceramic channeled support layer having a first side and a second side; a first dense layer of mixed-conducting multi-component metal oxide material having an inner side and an outer side, wherein the inner side is in contact with the first side of the ceramic channeled support layer; a first outer support layer comprising porous mixed-conducting multi-component metal oxide material and having an inner side and an outer side, wherein the inner side is in contact with the outer side of the first dense layer; a second dense layer of mixed-conducting multi-component metal oxide material having an inner side and an outer side, wherein the inner side is in contact with the second side of the ceramic channeled layer; and a second outer support layer comprising porous mixed-conducting multi-component metal oxide material and having an inner side and an outer side, wherein the inner side is in contact with the outer side of the second dense layer.

Carolan, Michael Francis (Allentown, PA); Dyer, legal representative, Kathryn Beverly (Allentown, PA); Wilson, Merrill Anderson (West Jordan, UT); Ohm, Ted R. (Alliance, OH); Kneidel, Kurt E. (Alliance, OH); Peterson, David (Uniontown, OH); Chen, Christopher M. (Allentown, PA); Rackers, Keith Gerard (Louisville, OH); Dyer, deceased, Paul Nigel (Allentown, PA)

2007-10-09T23:59:59.000Z

279

Planar ceramic membrane assembly and oxidation reactor system  

DOE Patents [OSTI]

Planar ceramic membrane assembly comprising a dense layer of mixed-conducting multi-component metal oxide material, wherein the dense layer has a first side and a second side, a porous layer of mixed-conducting multi-component metal oxide material in contact with the first side of the dense layer, and a ceramic channeled support layer in contact with the second side of the dense layer. The planar ceramic membrane assembly can be used in a ceramic wafer assembly comprising a planar ceramic channeled support layer having a first side and a second side; a first dense layer of mixed-conducting multi-component metal oxide material having an inner side and an outer side, wherein the inner side is in contact with the first side of the ceramic channeled support layer; a first outer support layer comprising porous mixed-conducting multi-component metal oxide material and having an inner side and an outer side, wherein the inner side is in contact with the outer side of the first dense layer; a second dense layer of mixed-conducting multi-component metal oxide material having an inner side and an outer side, wherein the inner side is in contact with the second side of the ceramic channeled layer; and a second outer support layer comprising porous mixed-conducting multi-component metal oxide material and having an inner side and an outer side, wherein the inner side is in contact with the outer side of the second dense layer.

Carolan, Michael Francis (Allentown, PA); Dyer, legal representative, Kathryn Beverly (Allentown, PA); Wilson, Merrill Anderson (West Jordan, UT); Ohrn, Ted R. (Alliance, OH); Kneidel, Kurt E. (Alliance, OH); Peterson, David (Uniontown, OH); Chen, Christopher M. (Allentown, PA); Rackers, Keith Gerard (Louisville, OH); Dyer, Paul Nigel (Allentown, PA)

2009-04-07T23:59:59.000Z

280

Separation of polar gases from nonpolar gases  

DOE Patents [OSTI]

Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

Kulprathipanja, S.; Kulkarni, S.S.

1986-08-26T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Separation of polar gases from nonpolar gases  

DOE Patents [OSTI]

Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

Kulprathipanja, Santi (Hoffman Estates, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL)

1986-01-01T23:59:59.000Z

282

Separation of polar gases from nonpolar gases  

DOE Patents [OSTI]

The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

Kulprathipanja, S.

1986-08-19T23:59:59.000Z

283

Separation of polar gases from nonpolar gases  

DOE Patents [OSTI]

The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

Kulprathipanja, Santi (Hoffman Estates, IL)

1986-01-01T23:59:59.000Z

284

High performance electrical, magnetic, electromagnetic and electrooptical devices enabled by three dimensionally ordered nanodots and nanorods  

DOE Patents [OSTI]

Novel articles and methods to fabricate same with self-assembled nanodots and/or nanorods of a single or multicomponent material within another single or multicomponent material for use in electrical, electronic, magnetic, electromagnetic and electrooptical devices is disclosed. Self-assembled nanodots and/or nanorods are ordered arrays wherein ordering occurs due to strain minimization during growth of the materials. A simple method to accomplish this when depositing in-situ films is also disclosed. Device applications of resulting materials are in areas of superconductivity, photovoltaics, ferroelectrics, magnetoresistance, high density storage, solid state lighting, non-volatile memory, photoluminescence, thermoelectrics and in quantum dot lasers.

Goyal, Amit (Knoxville, TN), Kang; Sukill (Knoxville, TN)

2012-02-21T23:59:59.000Z

285

High performance devices enabled by epitaxial, preferentially oriented, nanodots and/or nanorods  

DOE Patents [OSTI]

Novel articles and methods to fabricate same with self-assembled nanodots and/or nanorods of a single or multicomponent material within another single or multicomponent material for use in electrical, electronic, magnetic, electromagnetic, superconducting and electrooptical devices is disclosed. Self-assembled nanodots and/or nanorods are ordered arrays wherein ordering occurs due to strain minimization during growth of the materials. A simple method to accomplish this when depositing in-situ films is also disclosed. Device applications of resulting materials are in areas of superconductivity, photovoltaics, ferroelectrics, magnetoresistance, high density storage, solid state lighting, non-volatile memory, photoluminescence, thermoelectrics and in quantum dot lasers.

Goyal, Amit (Knoxville, TN)

2011-10-11T23:59:59.000Z

286

High performance superconducting devices enabled by three dimensionally ordered nanodots and/or nanorods  

DOE Patents [OSTI]

Novel articles and methods to fabricate same with self-assembled nanodots and/or nanorods of a single or multicomponent material within another single or multicomponent material for use in electrical, electronic, magnetic, electromagnetic and electrooptical devices is disclosed. Self-assembled nanodots and/or nanorods are ordered arrays wherein ordering occurs due to strain minimization during growth of the materials. A simple method to accomplish this when depositing in-situ films is also disclosed. Device applications of resulting materials are in areas of superconductivity, photovoltaics, ferroelectrics, magnetoresistance, high density storage, solid state lighting, non-volatile memory, photoluminescence, thermoelectrics and in quantum dot lasers.

Goyal, Amit

2013-09-17T23:59:59.000Z

287

Combined catalysts for the combustion of fuel in gas turbines  

DOE Patents [OSTI]

A catalytic oxidation module for a catalytic combustor of a gas turbine engine is provided. The catalytic oxidation module comprises a plurality of spaced apart catalytic elements for receiving a fuel-air mixture over a surface of the catalytic elements. The plurality of catalytic elements includes at least one primary catalytic element comprising a monometallic catalyst and secondary catalytic elements adjacent the primary catalytic element comprising a multi-component catalyst. Ignition of the monometallic catalyst of the primary catalytic element is effective to rapidly increase a temperature within the catalytic oxidation module to a degree sufficient to ignite the multi-component catalyst.

Anoshkina, Elvira V.; Laster, Walter R.

2012-11-13T23:59:59.000Z

288

The Evolution Towards Grids: Ten Years of High-Speed, Wide Area, Data Intensive Computing  

E-Print Network [OSTI]

systems (e.g., multi-component turbomachine simulation); · Management of very large parameter space / Boeing Remote Help Desk that will provide aircraft field maintenance personnel use of coupled video1 The Evolution Towards Grids: Ten Years of High-Speed, Wide Area, Data Intensive Computing William

289

Collocation method for the modeling of membrane gas permeation systems A. Feichtingera  

E-Print Network [OSTI]

) or hydrogen recovery from biomass gasification gases (Mayer et al., 2010; Makaruk et al., 2012). CorrespondingCollocation method for the modeling of membrane gas permeation systems A. Feichtingera , A simulation, collocation method, error estimate, grid adaptation, multicomponent separation 1. Introduction

Weinmüller, Ewa B.

290

Interaction of Turbomachinery Components in Large-scale Unsteady Computations of Jet Engines  

E-Print Network [OSTI]

Interaction of Turbomachinery Components in Large-scale Unsteady Computations of Jet Engines Georgi on the turbomachinery compu- tation and, in particular, on the physics of interaction of different turbomachinery will be discussed for these multi-component turbomachinery simulations. The compressor and turbine of a modern

Alonso, Juan J.

291

Grouping maintenance strategy with availability constraint under limited  

E-Print Network [OSTI]

with significant assumptions: maintenance durations are neglected and only one preventive maintenance for eachGrouping maintenance strategy with availability constraint under limited repairmen Phuc Do Van Hai maintenance strategies of multi-component systems by integrating two efficient optimization algorithms

Paris-Sud XI, Université de

292

1 Copyright 2004 by ASME DECOMPOSITION-BASED ASSEMBLY SYNTHESIS FOR  

E-Print Network [OSTI]

author ABSTRACT A method for optimally synthesizing multi-component structural assemblies of an aluminum Many modern mechanical products, such as ships hulls, airplanes and automotive bodies, are fairly by decomposing the entire product geometry. In the automotive industry, for example, a handful of basic

Saitou, Kazuhiro "Kazu"

293

Air Ingress Benchmarking with Computational Fluid Dynamics Analysis  

E-Print Network [OSTI]

1 Air Ingress Benchmarking with Computational Fluid Dynamics Analysis Tieliang Zhai Professor by the US Nuclear Regulatory Commission #12;2 Air Ingress Accident Objectives and Overall Strategy: Depresurization Pure Diffusion Natural Convection Challenging: Natural convection Multi-component Diffusion (air

294

Effect of Composition on the Solidification Behavior of Several Ni-Cr-Mo and Fe-Ni-Cr-Mo Alloys  

E-Print Network [OSTI]

simulate the solidifi- cation behavior of dissimilar welds made between AL-6XN and Ni-base filler metals.[3 differential thermal analysis (DTA) samples and welded specimens. This explains the in- variance of the amount of eutectic constituent observed in the microstructure in the welded and DTA conditions. Multicomponent

DuPont, John N.

295

Published: April 26, 2011 r 2011 American Chemical Society 1457 dx.doi.org/10.1021/am200016v |ACS Appl. Mater. Interfaces 2011, 3, 14571462  

E-Print Network [OSTI]

expended toward developing new and simple synthetic ap- proaches to produce multicomponent nanoparticles areas, especially environmental remediation because of its chalcophilic nature and reducing capability. The objective of our work is to produce Fe/FeS nanoparticles via a facile chemical conversion route by simply

Azad, Abdul-Majeed

296

Asymmetric Framework for Predicting Liquid-Liquid Equilibrium of Ionic Liquid-Mixed Solvent Systems  

E-Print Network [OSTI]

of multicomponent (ternary) LLE data with conventional excess Gibbs free energy models such as NRTL.6-14 Previously, we have studied15 the capability of such models, specifically NRTL, UNIQUAC and electrolyte-NRTL (eNRTL is the NRTL-SAC (NRTL Segm

Stadtherr, Mark A.

297

Anomalous Phase Inversion in Polymer Blends Prepared by Cryogenic Mechanical  

E-Print Network [OSTI]

, as well as interpenetrating and bicontinu- ous networks.7,8 Phase inversion occurs when the mi- norityAnomalous Phase Inversion in Polymer Blends Prepared by Cryogenic Mechanical Alloying Archie P strategies for producing highly dis- persed multicomponent polymer blends. By their very nature

298

Motional resonance coupling in cold multispecies Coulomb crystals B. Roth, P. Blythe, and S. Schiller  

E-Print Network [OSTI]

with results from molecular dynamics simulations and allow for a precise identification of sympathetically 10­12 . We have used excitation of motional resonances to iden- tify the molecular species embedded molecular dynamics MD simu- lations. We consider multicomponent ion crystals containing up to several

Schiller, Stephan

299

Macromolecular hydration compared with preferential hydration and their role on macromolecule-osmolyte coupled diffusionwz  

E-Print Network [OSTI]

to solute hydration and size ratio and is not complicated by other factors such as ionic interactions should not be neglected in multicomponent-diffusion theoretical models even when ionic interactions quantities that shape the thermodynamic and diffusion behavior of macromolecule­additive­water solutions.1

Annunziata, Onofrio

300

Simulation of Convection and Macrosegregation in a Large Steel Ingot  

E-Print Network [OSTI]

Simulation of Convection and Macrosegregation in a Large Steel Ingot J.P. GU and C. BECKERMANN Melt convection and macrosegregation in casting of a large steel ingot are numerically simulated. The simulation is based on a previously developed model for multicomponent steel solidification with melt convection

Beckermann, Christoph

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Interfacial systems for photochemical energy conversion: Progress report  

SciTech Connect (OSTI)

The following research areas are briefly discussed: excited state electron transfer in multi-component redox molecules; pH-dependent rectification in viologen-quinone polymers; selective modifications of II-IV semiconductors; and electrocatalysis of redox processes with biological molecules. 13 refs. (CBS)

Wrighton, M.S.

1988-01-01T23:59:59.000Z

302

The mathematical structure of multiphase thermal models of flow in porous media  

E-Print Network [OSTI]

The mathematical structure of multiphase thermal models of flow in porous media By Daniel E.A. van with the formulation and numerical solution of equations for modelling multicomponent, two-phase, thermal fluid flow typical flow behaviour that occurs during fluid injection into a reservoir. Keywords: porous media flow

303

A Study of Austenite Precipitate Growth in Duplex Stainless Steel A Research Performance Evaluation  

E-Print Network [OSTI]

A Study of Austenite Precipitate Growth in Duplex Stainless Steel A Research Performance Evaluation-based metals handbooks. Due the multi-component nature of the duplex stainless steels which are the basis stainless steel. Current State of Knowledge The velocity of an interface during a phase transformation can

McGaughey, Alan

304

Process for the production of superconductor containing filaments  

DOE Patents [OSTI]

Superconductor containing filaments having embedments of superconducting material surrounded by a rayon matrix are formed by preparing a liquid suspension which contains at least 10 weight percent superconducting material; forming a multicomponent filament having a core of the suspension and a viscose sheath which contains cellulose xanthate; and thereafter, regenerating cellulose from the cellulose xanthate to form a rayon matrix.

Tuominen, Olli P. (Candler, NC); Hoyt, Matthew B. (Arden, NC); Mitchell, David F. (Asheville, NC); Morgan, Carol W. (Asheville, NC); Roberts, Clyde Gordon (Asheville, NC); Tyler, Robert A. (Canton, NC)

2002-01-01T23:59:59.000Z

305

Numerical Simulation of Compositional Fluid Flow in Porous Media  

E-Print Network [OSTI]

variables is developed for modeling the enhanced oil recovery pro- cesses. A mixed #12;nite element method to predict the reservoir performance under various exploita- tion schemes. In many enhanced oil recovery. Computational results for two- and three-phase multi-component uid ow occurring in enhanced oil re- covery

Ewing, Richard E.

306

Seismic signals are crucial for male mating success in a visual specialist jumping spider (Araneae: Salticidae)  

E-Print Network [OSTI]

Seismic signals are crucial for male mating success in a visual specialist jumping spider (Araneae of multicomponent seismic courtship signals in addition to and produced in concert with its multiple visual ornaments and movement displays. Here, we demonstrate the importance of these seismic signals

Hoy, Ronald R.

307

Multiphase Turbulent Flow Ken Kiger -UMCP  

E-Print Network [OSTI]

interacting ­ Distinguish multiphase and/or multicomponent · Liquid/Gas or Gas/Liquid · Gas/Solid · Liquid/Liquid ­ Technically, two immiscible liquids are "multi-fluid", but are often referred to as a "multiphase" flow due emulsions Multi-phase Steam bubble in H20 Ice slurry Coal particles in air Sand particle in H20 #12

Gruner, Daniel S.

308

Application of Energy Saving Concepts to LPG Recovery Plants  

E-Print Network [OSTI]

inefficient compared to current standards. This paper deals with energy savings that may be effected for one such plant. Three basic ideas are evaluated:- o Use of Multi-Component Chilling (MCC). o Addition of an Expander. o Heat Recovery from Gas Turbine...

Carpenter, M. J.; Barnwell, J.

1982-01-01T23:59:59.000Z

309

Coupled Effects of Mechanics, Geometry, and Chemistry on Bio-membrane Behavior  

E-Print Network [OSTI]

build and analyze complete models to understand the behavior of multi-component membranes. We proposeCoupled Effects of Mechanics, Geometry, and Chemistry on Bio-membrane Behavior Thesis by Ha Giang, and encouragement. #12;iv Abstract Lipid bilayer membranes are models for cell membranes­the structure that helps

Winfree, Erik

310

"Distillation, Absorption and Extraction" April 5-6, 2001 in Bamberg,, Halvorsen NTNU Department of Chemical Engineering  

E-Print Network [OSTI]

distillation · Underwood (1946, 1948a,b), Fractional distillation of multicomponent mixtures · Shiras (1950"Distillation, Absorption and Extraction" April 5-6, 2001 in Bamberg,, Halvorsen NTNU Department Distillation Arrangements by Ivar J. Halvorsen and Sigurd Skogestad Norwegian University of Science

Skogestad, Sigurd

311

Composite hydrogen separation element and module  

DOE Patents [OSTI]

There are disclosed improvements in multicomponent composite metal membranes useful for the separation of hydrogen, the improvements comprising the provision of a flexible porous intermediate layer between a support layer and a nonporous hydrogen-permeable coating metal layer, and the provision of a textured coating metal layer. 15 figs.

Edlund, D.J.

1996-03-12T23:59:59.000Z

312

Flow and transport simulations using T2CG1, a package of conjugate gradient solvers for the TOUGH2 family of codes  

SciTech Connect (OSTI)

This report discusses the details of modifications made to the TOUGH2 family of codes to complement its direct solver which significantly increases the size of problems solved by the TOUGH2 code. With this modification, the TOUGH2 system is being tested in multiphase, multicomponent fluid and heat flow problems related to vadose zone hydrology, nuclear waste disposal, and environmental remediation.

Moridis, G.; Pruess, K.

1995-04-01T23:59:59.000Z

313

Aerosol Science 35 (2004) 577598 www.elsevier.com/locate/jaerosci  

E-Print Network [OSTI]

-dependence of the covariance matrix of a multicomponent particle population evolving under a size-independent coagulation rate as the particle population evolves to an internally mixed, self-preserving size distribution state. Published and physical properties of aerosols are determined by particle number density, composition, shape, and size

314

IEEE TRANSACTIONS ON PLASMA SCIENCE, VOL. 34, NO. 3, JUNE 2006 867 Experimental and Theoretical Study of RF Plasma  

E-Print Network [OSTI]

is required even for fast PIC Monte Carlo (MC) models of the reactor processes in complex multicomponent gas reactors are carried out at specific input power more than W/cm . At these power conditions, the influence of secondary electron emission ( electrons) and gas heating on discharge self-organization should be studied

Kaganovich, Igor

315

JOURNAL DE PHYSIQUE Colloque C5, supplbment au n05, Tome 50, mai 1989  

E-Print Network [OSTI]

-B- diketonate starting compounds in an ArIO, gas mixture [l,21 have been investigated. The plasma was realized as cathode in a quartz reactor. The aim of these activities is to optimize e.g. ThO, doped W layer structures for multicomponent PCVD. If this has to be avoided, the remedy is a fast plasma movement together with a thermal

Paris-Sud XI, Université de

316

Process diagnostics and thickness metrology using in situ mass spectrometry for the chemical vapor deposition of W from H2 WF6  

E-Print Network [OSTI]

response time 4 s sensor system sampled gas directly from a commercial Ulvac ERA-1000 reactor in order wafers, at 67 Pa 0.5 Torr total pressure, and for wafer temperatures around 400 °C. A relatively fast An ideal real-time chemical sensor for monitoring pro- cesses involving multicomponent gas mixtures would

Gougousi, Theodosia

317

Activation of the C-H Bond of Methane by Intermediate Q of Methane Monooxygenase: A  

E-Print Network [OSTI]

Activation of the C-H Bond of Methane by Intermediate Q of Methane Monooxygenase: A Theoretical component (MMOH) of the multicomponent soluble methane monooxygenase (MMO) system catalyzes the oxidation of methane by dioxygen to form methanol and water at non-heme, dinuclear iron active sites. The catalytic

Gherman, Benjamin F.

318

S. K. Aggarwal Department of Mechanical Engineering,  

E-Print Network [OSTI]

on Droplet Vaporization This paper deals with the multicomponent nature of gas turbine fuels under high employed in spray codes for predicting gas turbine combustor flows do not adequately incorporate with those of a surrogate single-component fuel droplet over a range of parameters relevant to gas turbine

Aggarwal, Suresh K.

319

Optical absorption and ionization of silicate glasses Leonid B. Glebov  

E-Print Network [OSTI]

Optical absorption and ionization of silicate glasses Leonid B. Glebov School of Optics and hydroxyl), and induced (color centers) absorption of multicomponent silicate glasses in UV, visible-photon ionization was detected in alkaline-silicate glasses exposed to high-power laser radiation in nano

Glebov, Leon

320

Alex Y. Sun Professional Summary  

E-Print Network [OSTI]

characterization, and CO2 sequestration. Professional Work Experience A. Present Position: Research Scientist theoretical and analytical tools for predicting CO2 leakage into groundwater aquifers; conducting performance Areas of Expertise A. Modeling of multiphase flow and multicomponent transport in porous media. B

Yang, Zong-Liang

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

PARALLEL PROCESSING OF THREE-DIMENSIONAL FIELD-SCALE REACTIVE TRANSPORT APPLICATIONS  

E-Print Network [OSTI]

BRGM (French Geological Survey), Water Department, Groundwater and Geochemistry Modeling 3, Avenue C for the mixed hybrid finite element kernel. Com- putations of the reaction step are performed using a newly- tions. 1. INTRODUCTION The shape and scope of multi-component reactive transport models changed dramati

Boyer, Edmond

322

Metal-organic frameworks for Xe/Kr separation  

DOE Patents [OSTI]

Metal-organic framework (MOF) materials are provided and are selectively adsorbent to xenon (Xe) over another noble gas such as krypton (Kr) and/or argon (Ar) as a result of having framework voids (pores) sized to this end. MOF materials having pores that are capable of accommodating a Xe atom but have a small enough pore size to receive no more than one Xe atom are desired to preferentially adsorb Xe over Kr in a multi-component (Xe--Kr mixture) adsorption method. The MOF material has 20% or more, preferably 40% or more, of the total pore volume in a pore size range of 0.45-0.75 nm which can selectively adsorb Xe over Kr in a multi-component Xe--Kr mixture over a pressure range of 0.01 to 1.0 MPa.

Ryan, Patrick J.; Farha, Omar K.; Broadbelt, Linda J.; Snurr, Randall Q.; Bae, Youn-Sang

2013-08-27T23:59:59.000Z

323

Conditions for extreme sensitivity of protein diffusion in membranes to cell environments  

E-Print Network [OSTI]

We study protein diffusion in multicomponent lipid membranes close to a rigid substrate separated by a layer of viscous fluid. The large-distance, long-time asymptotics for Brownian motion are calculated using a nonlinear stochastic Navier-Stokes equation including the effect of friction with the substrate. The advective nonlinearity, neglected in previous treatments, gives only a small correction to the renormalized viscosity and diffusion coefficient at room temperature. We find, however, that in realistic multicomponent lipid mixtures, close to a critical point for phase separation, protein diffusion acquires a strong power-law dependence on temperature and the distance to the substrate $H$, making it much more sensitive to cell environment, unlike the logarithmic dependence on $H$ and very small thermal correction away from the critical point.

Yaroslav Tserkovnyak; David R. Nelson

2006-09-29T23:59:59.000Z

324

Metal-organic frameworks for Xe/Kr separation  

DOE Patents [OSTI]

Metal-organic framework (MOF) materials are provided and are selectively adsorbent to xenon (Xe) over another noble gas such as krypton (Kr) and/or argon (Ar) as a result of having framework voids (pores) sized to this end. MOF materials having pores that are capable of accommodating a Xe atom but have a small enough pore size to receive no more than one Xe atom are desired to preferentially adsorb Xe over Kr in a multi-component (Xe--Kr mixture) adsorption method. The MOF material has 20% or more, preferably 40% or more, of the total pore volume in a pore size range of 0.45-0.75 nm which can selectively adsorb Xe over Kr in a multi-component Xe--Kr mixture over a pressure range of 0.01 to 1.0 MPa.

Ryan, Patrick J.; Farha, Omar K.; Broadbelt, Linda J.; Snurr, Randall Q.; Bae, Youn-Sang

2014-07-22T23:59:59.000Z

325

Electron-beam scull melting with electromagnetic stirring of melt in crucible  

SciTech Connect (OSTI)

The technologies and equipment have been developed for electron-beam scull melting with electromagnetic stirring of melt for some Ni-based superalloys as well as for multi-component Ti-, Zr-, Nb-, and Mo-based alloys. Two types of scull crucible sets with electromagnetic stirring systems have been constructed, with the metal pouring by the crucible tilting or through the hole in the crucible bottom. In the second case slag does not fall into a mold, and the electron beam may be used for metal heating in the costing head, thus improving the quality of castings. The technologies developed allow to utilize scrap, cost part reverts, chips etc. thus saving virgin alloys. The electromagnetic stirring application permits to product multi-component alloys, to increase the mass of the metal poured, and to reduce the specific energy expenditure and metal loss through evaporation.

Ladokhin, S.V. [Institute for Casting Problems, Kiev (Ukraine)

1994-12-31T23:59:59.000Z

326

Kinetics and modeling of mixture effects during complete catalytic oxidation of benzene and methyl tert-butyl ether  

SciTech Connect (OSTI)

The performance of a catalytic incinerator depends on the nature of the compounds being oxidized and cannot be predicted simply by knowing the performance of the incinerator with pure-component model compounds. Considering the importance of mixture effects, an attempt was made to develop a combined model to predict the conversion when benzene and methyl tert-butyl ether (MTBE) are simultaneously oxidized. Complete catalytic oxidation of benzene and MTBE, singly and in mixtures, was investigated over a platinum catalyst. No inhibition effects were seen with benzene, but MTBE conversion was distinctly inhibited by benzene. A Mars-van Krevelen rate model was used to explain the results. Model parameters were obtained from pure-component experiments and then incorporated into a multicomponent model without any adjustment or additional rate parameters. The multicomponent model was able to predict the conversion of benzene and MTBE oxidation in the binary mixture using the pure-component data without adjustable parameters.

Dangi, S.; Abraham, M.A. [Univ. of Tulsa, OK (United States). Dept. of Chemical Engineering] [Univ. of Tulsa, OK (United States). Dept. of Chemical Engineering

1997-06-01T23:59:59.000Z

327

Low velocity ion stopping in binary ionic mixtures  

SciTech Connect (OSTI)

Attention is focused on the low ion velocity stopping mechanisms in multicomponent and dense target plasmas built of quasiclassical electron fluids neutralizing binary ionic mixtures, such as, deuterium-tritium of current fusion interest, proton-heliumlike iron in the solar interior or proton-helium ions considered in planetology, as well as other mixtures of fiducial concern in the heavy ion beam production of warm dense matter at Bragg peak conditions. The target plasma is taken in a multicomponent dielectric formulation a la Fried-Conte. The occurrence of projectile ion velocities (so-called critical) for which target electron slowing down equals that of given target ion components is also considered. The corresponding multiquadrature computations, albeit rather heavy, can be monitored analytical through a very compact code operating a PC cluster. Slowing down results are systematically scanned with respect to target temperature and electron density, as well as ion composition.

Tashev, Bekbolat; Baimbetov, Fazylkhan [Department of Physics, Kazakh National University, Tole Bi 96, Almaty 480012 (Kazakhstan); Deutsch, Claude [LPGP (UMR-CNRS 8578), Universite Paris XI, 91405 Orsay (France); Fromy, Patrice [Direction de l'Informatique, Universite Paris XI, 91405 Orsay (France)

2008-10-15T23:59:59.000Z

328

Thermomechanics of hydrogen storage in metallic hydrides: modeling and analysis  

E-Print Network [OSTI]

A thermodynamically consistent mathematical model for hydrogen adsorption in metal hydrides is proposed. Beside hydrogen diffusion, the model accounts for phase transformation accompanied by hysteresis, swelling, temperature and heat transfer, strain, and stress. We prove existence of solutions of the ensuing system of partial differential equations by a carefully-designed, semi-implicit approximation scheme. A generalization for a drift-diffusion of multi-component ionized "gas" is outlined, too.

Tomas Roubicek; Giuseppe Tomassetti

2013-09-12T23:59:59.000Z

329

A three-phase K-value study for pure hydrocarbons/water and crude oil/water systems  

E-Print Network [OSTI]

Steam distillation, or vaporization of crude oil in porous media is on of the major mechanisms responsible for high oil recovery by steamflooding from heavy oil as well as light oil reservoir systems. Several authors have reported steam dsitillation...-phase equilibrium data for hydrocarbon/water systems ranging from light to heavy crude oil fractions. ! Experimental data describing the phase behavior and the hydrocarbon/water separation process for multi-component hydrocarbon/water and crude oil...

Lanclos, Ritchie Paul

1990-01-01T23:59:59.000Z

330

Upscaling of Long-Term U(VI) Desorption from Pore Scale Kinetics to Field-Scale Reactive Transport Models  

SciTech Connect (OSTI)

The focus of the project is the development of scientifically defensible approaches for upscaling reactive transport models (RTM) through a detailed understanding of U(VI) desorption across several spatial scales: bench-, intermediate-, and field-scales. The central hypothesis of the project is that the development of this methodology will lead to a scientifically defensible approach for conceptual model development for multicomponent RTM at contaminated DOE sites, leading to predictive transport simulations with reduced uncertainty.

Steefel, Carl I.; Li Li; Davis, J.A.; Curtis, G.P.; Honeyman, B.D.; Kent, D.B.; Kohler, M.; Rodriguez, D.R.; Johnson, K.J.; Miller, A.

2006-06-01T23:59:59.000Z

331

Speed selection for coupled wave equations  

E-Print Network [OSTI]

We discuss models for coupled wave equations describing interacting fields, focusing on the speed of travelling wave solutions. In particular, we propose a general mechanism for selecting and tuning the speed of the corresponding (multi-component) travelling wave solutions under certain physical conditions. A number of physical models (molecular chains, coupled Josephson junctions, propagation of kinks in chains of adsorbed atoms and domain walls) are considered as examples.

Mariano Cadoni; Giuseppe Gaeta

2015-01-13T23:59:59.000Z

332

Evaluation of improved techniques for the removal of fission products from process wastewater and groundwater: FY 1996 status  

SciTech Connect (OSTI)

This report describes laboratory results acquired in the course of evaluating new sorbents for the treatment of radiologically contaminated groundwater and process wastewater. During FY 1996, the evaluation of resorcinol-formaldehyde (R-F) resin for the removal of cesium and strontium from wastewaters was completed. Additionally, strontium sorption on sodium nonatitanate powder was characterized in a series of multicomponent batch studies. Both of these materials were evaluated in reference to a baseline sorbent, natural chabazite zeolite.

Bostick, D.T. [Oak Ridge National Lab., TN (United States); Guo, B. [Oak Ridge Research Inst., TN (United States)

1997-07-01T23:59:59.000Z

333

Reflux for multifeed distillation  

SciTech Connect (OSTI)

Prior investigations have shown ways to determine minimum reflux for multicomponent distillation. This work extends earlier concepts in order to handle multifeeds. Reflux calculations for each feed, as though it were the only feed, are factored with the reflux effects of the other feeds to give an overall minimum reflux. Each factor has a finite value depending on the composition and thermal quality of the feed it represents.

Chou, S.M.; Yaws, C.L.

1986-12-01T23:59:59.000Z

334

The impact of the Self-Determined Learning Model of Instruction on student self-determination  

E-Print Network [OSTI]

multifaceted construct and interventions that achieve the best outcomes are multicomponent interventions. The SDLMI (Wehmeyer et al., 2000) is a model of teaching (i.e., intended for teachers as end users to guide and direct instruction) that supports teachers... the impact of the SDLMI (Wehmeyer et al., 2000) on self-determination. Project personnel contacted school districts, and districts that agreed to participate (« < 20) identi- fied high school campuses {n < 39) to participate. Next, the primary district...

Wehmeyer, Michael L.; Shogren, Karrie A.; Palmer, Susan B.; Williams-Diehm, Kendra; Little, Todd D.; Boulton, Aaron Jacob

2012-01-01T23:59:59.000Z

335

Nested off-diagonal Bethe ansatz and exact solutions of the su(n) spin chain with generic integrable boundaries  

E-Print Network [OSTI]

The nested off-diagonal Bethe ansatz method is proposed to diagonalize multi-component integrable models with generic integrable boundaries. As an example, the exact solutions of the su(n)-invariant spin chain model with both periodic and non-diagonal boundaries are derived by constructing the nested T-Q relations based on the operator product identities among the fused transfer matrices and the asymptotic behavior of the transfer matrices.

Junpeng Cao; Wen-Li Yang; Kangjie Shi; Yupeng Wang

2014-05-11T23:59:59.000Z

336

Ternary liquid scintillator for optical fiber applications  

DOE Patents [OSTI]

A multicomponent liquid scintillator solution for use as a radiation-to-light converter in conjunction with a fiber optic transmission system. The scintillator includes a quantity of 5-amino-9-diethylaminobenz (a) phenoxazonium nitrate (Nile Blue Nitrate) as a solute in a fluor solvent such as benzyl alcohol. The use of PPD as an additional solute is also disclosed. The system is controllable by addition of a suitable quenching agent, such as phenol.

Franks, Larry A. (Santa Barbara, CA); Lutz, Stephen S. (Santa Barbara, CA)

1982-01-01T23:59:59.000Z

337

Functional Differential Equations for the Free Energy and the Effective Energy in the Broken-Symmetry Phase of phi^4-Theory and Their Recursive Graphical Solution  

E-Print Network [OSTI]

Extending recent work on QED and the symmetric phase of the euclidean multicomponent scalar \\phi^4-theory, we construct the vacuum diagrams of the free energy and the effective energy in the ordered phase of \\phi^4-theory. By regarding them as functionals of the free correlation function and the interaction vertices, we graphically solve nonlinear functional differential equations, obtaining loop by loop all connected and one-particle irreducible vacuum diagrams with their proper weights.

A. Pelster; H. Kleinert

2000-06-20T23:59:59.000Z

338

Multiparameter Fiber Optic Sensing System for Monitoring Enhanced  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 -Energieprojekte3 ClimateSpurr GeothermalCarmel PublicMulticomponent

339

Multispectral Imaging (Laney, 2005) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 -Energieprojekte3 ClimateSpurr GeothermalCarmel PublicMulticomponentLaney, 2005)

340

Multispectral Imaging (Lewicki & Oldenburg, 2004) | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 -Energieprojekte3 ClimateSpurr GeothermalCarmel PublicMulticomponentLaney,

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Aerosol chemical vapor deposition of metal oxide films  

DOE Patents [OSTI]

A process of preparing a film of a multicomponent metal oxide including: forming an aerosol from a solution comprised of a suitable solvent and at least two precursor compounds capable of volatilizing at temperatures lower than the decomposition temperature of said precursor compounds; passing said aerosol in combination with a suitable oxygen-containing carrier gas into a heated zone, said heated zone having a temperature sufficient to evaporate the solvent and volatilize said precursor compounds; and passing said volatilized precursor compounds against the surface of a substrate, said substrate having a sufficient temperature to decompose said volatilized precursor compounds whereby metal atoms contained within said volatilized precursor compounds are deposited as a metal oxide film upon the substrate is disclosed. In addition, a coated article comprising a multicomponent metal oxide film conforming to the surface of a substrate selected from the group consisting of silicon, magnesium oxide, yttrium-stabilized zirconium oxide, sapphire, or lanthanum gallate, said multicomponent metal oxide film characterized as having a substantially uniform thickness upon said substrate.

Ott, K.C.; Kodas, T.T.

1994-01-11T23:59:59.000Z

342

New Design Methods And Algorithms For High Energy-Efficient And Low-cost Distillation Processes  

SciTech Connect (OSTI)

This project sought and successfully answered two big challenges facing the creation of low-energy, cost-effective, zeotropic multi-component distillation processes: first, identification of an efficient search space that includes all the useful distillation configurations and no undesired configurations; second, development of an algorithm to search the space efficiently and generate an array of low-energy options for industrial multi-component mixtures. Such mixtures are found in large-scale chemical and petroleum plants. Commercialization of our results was addressed by building a user interface allowing practical application of our methods for industrial problems by anyone with basic knowledge of distillation for a given problem. We also provided our algorithm to a major U.S. Chemical Company for use by the practitioners. The successful execution of this program has provided methods and algorithms at the disposal of process engineers to readily generate low-energy solutions for a large class of multicomponent distillation problems in a typical chemical and petrochemical plant. In a petrochemical complex, the distillation trains within crude oil processing, hydrotreating units containing alkylation, isomerization, reformer, LPG (liquefied petroleum gas) and NGL (natural gas liquids) processing units can benefit from our results. Effluents from naphtha crackers and ethane-propane crackers typically contain mixtures of methane, ethylene, ethane, propylene, propane, butane and heavier hydrocarbons. We have shown that our systematic search method with a more complete search space, along with the optimization algorithm, has a potential to yield low-energy distillation configurations for all such applications with energy savings up to 50%.

Agrawal, Rakesh

2013-11-21T23:59:59.000Z

343

Feasibility of Geophysical Monitoring of Carbon-Sequestrated Deep Saline Aquifers  

SciTech Connect (OSTI)

As carbon dioxide (CO{sub 2}) is sequestered from the bottom of a brine reservoir and allowed to migrate upward, the effects of the relative permeability hysteresis due to capillary trapping and buoyancy driven migration tend to make the reservoir patchy saturated with different fluid phases over time. Seismically, such a patchy saturated reservoir induces an effective anisotropic behavior whose properties are primarily dictated by the nature of the saturation of different fluid phases in the pores and the elastic properties of the rock matrix. By combining reservoir flow simulation and modeling with seismic modeling, it is possible to derive these effective anisotropic properties, which, in turn, could be related to the saturation of CO{sub 2} within the reservoir volume any time during the post-injection scenario. Therefore, if time-lapse seismic data are available and could be inverted for the effective anisotropic properties of the reservoir, they, in combination with reservoir simulation could potentially predict the CO{sub 2} saturation directly from the time-lapse seismic data. It is therefore concluded that the time-lapse seismic data could be used to monitor the carbon sequestrated saline reservoirs. But for its successful implementation, seismic modeling and inversion methods must be integrated with the reservoir simulations. In addition, because CO{sub 2} sequestration induces an effective anisotropy in the sequestered reservoir and anisotropy is best detected using multicomponent seismic data compared to single component (P-wave) data, acquisition, processing, and analysis is multicomponent seismic data is recommended for these time-lapse studies. Finally, a successful implementation of using time-lapse seismic data for monitoring the carbon sequestrated saline reservoirs will require development of a robust methodology for inverting multicomponent seismic data for subsurface anisotropic properties.

Mallick, Subhashis; Alvarado, Vladimir

2013-09-30T23:59:59.000Z

344

Geologic Sequestration of CO2 in Deep, Unmineable Coalbeds: An Integrated Researdh and Commercial-Scale Field Demonstration Project  

SciTech Connect (OSTI)

The Coal-Seq consortium is a government-industry collaborative consortium with the objective of advancing industry's understanding of complex coalbed methane and gas shale reservoir behavior in the presence of multi-component gases via laboratory experiments, theoretical model development and field validation studies. This will allow primary recovery, enhanced recovery and CO{sub 2} sequestration operations to be commercially enhanced and/or economically deployed. The project was initially launched in 2000 as a U.S. Department of Energy sponsored investigation into CO{sub 2} sequestration in deep, unmineable coalseams. The initial project accomplished a number of important objectives, which mainly revolved around performing baseline experimental studies, documenting and analyzing existing field projects, and establishing a global network for technology exchange. The results from that Phase have been documented in a series of reports which are publicly available. An important outcome of the initial phase was that serious limitations were uncovered in our knowledge of reservoir behavior when CO{sub 2} is injected into coal. To address these limitations, the project was extended in 2005 as a government-industry collaborative consortium. Selected accomplishments from this phase have included the identification and/or development of new models for multi-component sorption and diffusion, laboratory studies of coal geomechanical and permeability behavior with CO{sub 2} injection, additional field validation studies, and continued global technology exchange. Further continuation of the consortium is currently being considered. Some of the topics that have been identified for investigation include further model development/refinement related to multicomponent equations-of-state, sorption and diffusion behavior, geomechanical and permeability studies, technical and economic feasibility studies for major international coal basins, the extension of the work to gas shale reservoirs, and continued global technology exchange.

Scott Reeves; George Koperna

2008-09-30T23:59:59.000Z

345

Chemical structure of vanadium-based contact formation on n-AlN  

SciTech Connect (OSTI)

We have investigated the chemical interaction between a Au/V/Al/V layer structure and n-type AlN epilayers using soft x-ray photoemission, x-ray emission spectroscopy, and atomic force microscopy. To understand the complex processes involved in this multicomponent system, we have studied the interface before and after a rapid thermal annealing step. We find the formation of a number of chemical phases at the interface, including VN, metallic vanadium, aluminum oxide, and metallic gold. An interaction mechanism for metal contact formation on the entire n-(Al,Ga)N system is proposed.

Pookpanratana, S.; France, R.; Blum, M.; Bell, A.; Bar, M.; Weinhardt, L.; Zhang, Y.; Hofmann, T.; Fuchs, O.; Yang, W.; Denlinger, J. D.; Mulcahy, S.; Moustakas, T. D.; Heske, Clemens

2010-05-17T23:59:59.000Z

346

Triple-material stress-strain resistivity gage  

DOE Patents [OSTI]

A triple material piezoresistive gage provides multi-component elastic stress measurements is disclosed. Thin foils of three piezoresistive materials, e.g. ytterbium, manganin, and constantan, are configured in a nested serpentine rectilinear grid or other grid arrangement and embedded in a medium, preferably normal to the direction of shock wave propagation. The output of the gage is a resistivity change history for each material of the gage. Each resistivity change is independent of the others so that three diagonal components of the elastic stress or strain tensor can be calculated from the resistivity measurements. 4 figs.

Stout, R.B.

1988-05-17T23:59:59.000Z

347

Mathematical Modeling of Cation Contamination in a Proton-exchange Membrane  

SciTech Connect (OSTI)

Transport phenomena in an ion-exchange membrane containing both H+ and K+ are described using multicomponent diffusion equations (Stefan-Maxwell). A model is developed for transport through a Nafion 112 membrane in a hydrogen-pump setup. The model results are analyzed to quantify the impact of cation contamination on cell potential. It is shown that limiting current densities can result due to a decrease in proton concentration caused by the build-up of contaminant ions. An average cation concentration of 30 to 40 percent is required for appreciable effects to be noticed under typical steady-state operating conditions.

Weber, Adam; Delacourt, Charles

2008-09-11T23:59:59.000Z

348

Generic process for preparing a crystalline oxide upon a group IV semiconductor substrate  

DOE Patents [OSTI]

A process for growing a crystalline oxide epitaxially upon the surface of a Group IV semiconductor, as well as a structure constructed by the process, is described. The semiconductor can be germanium or silicon, and the crystalline oxide can generally be represented by the formula (AO).sub.n (A'BO.sub.3).sub.m in which "n" and "m" are non-negative integer repeats of planes of the alkaline earth oxides or the alkaline earth-containing perovskite oxides. With atomic level control of interfacial thermodynamics in a multicomponent semiconductor/oxide system, a highly perfect interface between a semiconductor and a crystalline oxide can be obtained.

McKee, Rodney A. (Kingston, TN); Walker, Frederick J. (Oak Ridge, TN); Chisholm, Matthew F. (Oak Ridge, TN)

2000-01-01T23:59:59.000Z

349

High resolution x-ray and gamma ray imaging using diffraction lenses with mechanically bent crystals  

DOE Patents [OSTI]

A method for high spatial resolution imaging of a plurality of sources of x-ray and gamma-ray radiation is provided. High quality mechanically bent diffracting crystals of 0.1 mm radial width are used for focusing the radiation and directing the radiation to an array of detectors which is used for analyzing their addition to collect data as to the location of the source of radiation. A computer is used for converting the data to an image. The invention also provides for the use of a multi-component high resolution detector array and for narrow source and detector apertures.

Smither, Robert K. (Hinsdale, IL)

2008-12-23T23:59:59.000Z

350

Controlling the properties of bulk metal oxides at a molecular level: Alkoxides vs carboxylates-alkoxides routes  

SciTech Connect (OSTI)

The reactions between alkoxides and/or alkoxides and anhydrous acetates have been investigated for access to advanced multicomponent niobates or titanates and with the aim to get insight into relationships between the nature of the initial precursors single or mixed metal derivatives, ligands (OAc or OR, R = Et, iPr),...- and the properties of the final material. Data are based on a variety of techniques: FT-IR, multinuclear NMR ({sup 1}H, {sup 13}C, {sup 207}Pb, {sup 113}Cd), X-ray investigations on single crystals. Powders have been analyzed by TGA, SEM-EDX, light scattering and XRD.

Hubert-Pfalzgraf, L.G.; Daniele, S.; Boulmaaz, S.; Papiernik, R. [Univ. de Nice Sophia-Antipolis, Nice (France)

1994-12-31T23:59:59.000Z

351

A feasibility study of the determination of mass transfer rates from perturbation gas chromatography  

E-Print Network [OSTI]

and be given as ** ? '". , "-- **. * ? '". . "--( ? '". - *, :, ? ". , 'I. i=1, 2, . . . , (n-l) (4) where " indicates steady-state value and ~y-y-y* 1 i i AX = X ? X * 1 1 1 Por the local equilibrium case, if the flowing phase rate is slow.... (6) into Eq. (4), a set of linearized chro- matographic relations for the multicomponent case including the sorption effects will be obtained. This is well de- monstz'ated in Glover and Lau (19$3). For the non-equilibrium case, finite mass...

Huang, Wei-Yih

1984-01-01T23:59:59.000Z

352

Electron beam casting technology in the former Soviet Union  

SciTech Connect (OSTI)

In this report the results of the investigation of metals and alloys melting and casting in the EB skull installations in the former USSR are given. The technological equipment used for these purposes is described. The long term prospects for the technological and engineering developments for multicomponent alloy melting and casting, including those containing volatile elements are shown. The significant technological advantages of the electro-magnetic stirring used in the course of the EB melting are demonstrated. The important advantage of the technology described is the efficient processing of metals and alloys metals.

Ladokhin, S.V. [Inst. of Foundry Problems, Kiev (Ukraine)

1995-12-31T23:59:59.000Z

353

A model for oxygen reduction in a gas-fed porous electrode in caustic electrolyte  

E-Print Network [OSTI]

-Maxwell equations for multicomponent diffusion (11) m (X. N, ? X. N. ) VX, = P j=l CD t, j where m is set equal to two for oxygen and mtrogen (see appendix A for a treatment of the water vapor that is present). To simplify Eq. [1], it is assumed... that the diffusion of oxygen in the porous backing occurs only in the Z' direction, see Fig, 2. To further simplify Eq. [1], the variables X. and C are redefined in terms of partial pressures and the ideal gas i law respectively. phase diffusion The binary...

Wolfe, Don James

2012-06-07T23:59:59.000Z

354

Fuel Conditioning Facility Electrorefiner Model Predictions versus Measurements  

SciTech Connect (OSTI)

Electrometallurgical treatment of spent nuclear fuel is performed in the Fuel Conditioning Facility (FCF) at the Idaho National Laboratory (INL) by electrochemically separating uranium from the fission products and structural materials in a vessel called an electrorefiner (ER). To continue processing without waiting for sample analyses to assess process conditions, an ER process model predicts the composition of the ER inventory and effluent streams via multicomponent, multi-phase chemical equilibrium for chemical reactions and a numerical solution to differential equations for electro-chemical transport. The results of the process model were compared to the electrorefiner measured data.

D Vaden

2007-10-01T23:59:59.000Z

355

A new model for solvent extraction in columns  

SciTech Connect (OSTI)

A new model was developed for analyzing solvent extraction processes carried out in columns. Each column is treated as a series of well-defined equilibrium stages where the backmixing (other-phase carryover) between stages can be large. By including all mass transfer effects in the backmixing value, the same number of stages can be used for all extracted components no matter what their distribution coefficients. This greatly simplifies the calculations required when modeling multicomponent solvent extraction processes. Initial testing shows the new model to be better than either the Height of an Equivalent Theoretical Plate (HETP) or the Height of a Transfer Unit (HTU) method.

Leonard, R.A.; Regalbuto, M.C.; Chamberlain, D.B.; Vandegrift, G.F.

1989-12-08T23:59:59.000Z

356

Hardware-efficient autonomous quantum error correction  

E-Print Network [OSTI]

We propose a new method to autonomously correct for errors of a logical qubit induced by energy relaxation. This scheme encodes the logical qubit as a multi-component superposition of coherent states in a harmonic oscillator, more specifically a cavity mode. The sequences of encoding, decoding and correction operations employ the non-linearity provided by a single physical qubit coupled to the cavity. We layout in detail how to implement these operations in a practical system. This proposal directly addresses the task of building a hardware-efficient and technically realizable quantum memory.

Zaki Leghtas; Gerhard Kirchmair; Brian Vlastakis; Robert Schoelkopf; Michel Devoret; Mazyar Mirrahimi

2013-01-16T23:59:59.000Z

357

Triple-material stress-strain resistivity gage  

DOE Patents [OSTI]

A triple material piezoresistive gage provides multi-component elastic stress or strain measurements. Thin foils of three piezoresistive materials, e.g., ytterbium, manganin, and constantan, are configured in a nested serpentine rectilinear grind or other grind arrangement and embedded in a medium, preferably normal to the direction of shock wave propagation. The output of the gage is a resistivity change history for each material of gage. Each resistivity change is independent of the others so that three diagonal components of the elastic stress or strain tensor can be calculated form the resistivity measurements. 4 figs.

Stout, R.B.

1987-05-19T23:59:59.000Z

358

Scattering of radiation in collisionless dusty plasmas  

SciTech Connect (OSTI)

Scattering of electromagnetic waves in collisionless dusty plasmas is studied in the framework of a multi-component kinetic model. The investigation focuses on the spectral distribution of the scattered radiation. Pronounced dust signatures are identified in the coherent spectrum due to scattering from the shielding cloud around the dust grains, dust acoustic waves, and dust-ion acoustic waves. The magnitude and shape of the scattered signal near these spectral regions are determined with the aid of analytical expressions and its dependence on the dust parameters is investigated. The use of radiation scattering as a potential diagnostic tool for dust detection is discussed.

Tolias, P.; Ratynskaia, S. [Space and Plasma Physics, Royal Institute of Technology, Stockholm SE-100 44 (Sweden)

2013-04-15T23:59:59.000Z

359

Conservation and Renewable Energy Program: Bibliography, 1988 edition  

SciTech Connect (OSTI)

The 831 references covering the period 1980 through Feb. 1988, are arranged under the following: analysis and evaluation, building equipment, building thermal envelope systems and materials, community systems and cogeneration, residential conservation service, retrofit, advanced heat engine ceramics, alternative fuels, microemulsion fuels, industrial chemical heat pumps, materials for waste heat utilization, energy conversion and utilization materials, tribology, emergency energy conservation,inventions, electric energy systems, thermal storage, biofuels production, biotechnology, solar technology, geothermal, and continuous chromatography in multicomponent separations. An author index is included.

Vaughan, K.H. (comp.)

1988-04-01T23:59:59.000Z

360

Dark matter conversion as a source of boost factor for explaining the cosmic ray positron and electron excesses  

E-Print Network [OSTI]

In interacting multi-component dark matter (DM) models, if the DM components are nearly degenerate in mass and the interactions between them are strong enough, the relatively heavy DM components can be converted into lighter ones at late time after the thermal decoupling. Consequently, the relic density of the lightest DM component can be considerably enhanced at late time. This may contribute to an alternative source of boost factor required to explain the positron and electron excesses reported by the recent DM indirect search experiments such as PAMELA, Fermi-LAT and HESS etc..

Ze-Peng Liu; Yue-Liang Wu; Yu-Feng Zhou

2011-12-17T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

An investigation of gas separation membranes for reduction of thermal treatment emissions  

SciTech Connect (OSTI)

Gas permeable membranes were evaluated for possible use as air pollution control devices on a fluidized bed catalytic incineration unit. The unit is a candidate technology for treatment of certain mixed hazardous and radioactive wastes at the Rocky Flats Plant. Cellulose acetate and polyimide membranes were tested to determine the permeance of typical off-gas components such as carbon dioxide, nitrogen, and oxygen. Multi-component permeation studies included gas mixtures containing light hydrocarbons. Experiments were also conducted to discover information about potential membrane degradation in the presence of organic compounds.

Stull, D.M.; Logsdon, B.W. [EG and G Rocky Flats, Inc., Golden, CO (United States). Rocky Flats Plant; Pellegrino, J.J. [National Inst. of Standards and Technology, Gaithersburg, MD (United States)

1994-05-16T23:59:59.000Z

362

Shell-Filling Effect in the Entanglement Entropies of Spinful Fermions  

E-Print Network [OSTI]

We consider the von Neumann and R\\'enyi entropies of the one dimensional quarter-filled Hubbard model. We observe that for periodic boundary conditions the entropies exhibit an unexpected dependence on system size: for L=4 mod 8 the results are in agreement with expectations based on conformal field theory, while for L=0 mod 8 additional contributions arise. We explain this observation in terms of a shell-filling effect, and develop a conformal field theory approach to calculate the extra term in the entropies. Similar shell filling effects in entanglement entropies are expected to be present in higher dimensions and for other multicomponent systems.

Fabian H. L. Essler; Andreas M. Läuchli; Pasquale Calabrese

2012-11-11T23:59:59.000Z

363

Slow light microfluidics: a proposal  

E-Print Network [OSTI]

The resonant slow light structures created along a thin-walled optical capillary by nanoscale deformation of its surface can perform comprehensive simultaneous detection and manipulation of microfluidic components. This concept is illustrated with a model of a 0.5 millimeter long 5 nm high triangular bottle resonator created at a 50 micron radius silica capillary containing floating microparticles. The developed theory shows that the microparticle positions can be determined from the bottle resonator spectrum. In addition, the microparticles can be driven and simultaneously positioned at predetermined locations by the localized electromagnetic field created by the optimized superposition of eigenstates of this resonator, thus, exhibiting a multicomponent near field optical tweezers.

Sumetsky, M

2014-01-01T23:59:59.000Z

364

Varying Faces of Photospheric Emission in Gamma-Ray Bursts  

E-Print Network [OSTI]

Among the more than 1000 gamma-ray bursts observed by the Fermi Gamma-ray Space Telescope, a large fraction show narrow and hard spectra inconsistent with non-thermal emission, signifying optically thick emission from the photosphere. However, only a few of these bursts have spectra consistent with a pure Planck function. We will discuss the observational features of photospheric emission in these GRBs as well as in the ones showing multi-component spectra. We interpret the observations in light of models of subphotospheric dissipation, geometrical broadening and multi-zone emission, and show what we can learn about the dissipation mechanism and properties of GRB jets.

Axelsson, M

2015-01-01T23:59:59.000Z

365

Evaluation of a reduced mechanism for turbulent premixed combustion  

E-Print Network [OSTI]

as alternative fuels for power generation using indus- trial gas-turbines [1]. These are typically multi-component fuels, involving CO; H2; H2O; CH4; CO2; O2 and N2, with their composi- reaction set usually involves more than hundreds of reactions and tens... ]. The supplementary material of this arti- cle provides a CHEMKIN compatible subroutine to calculate these reaction rates. 2.3. Flow configuration and boundary conditions A sketch of the computational domain is given in Fig. 1. The computational domain is discretized...

Nikolaou, Zacharias M.; Swaminathan, Nedunchezhian; Chen, Jyh-Yuan

2014-07-21T23:59:59.000Z

366

Quantum plasma effects in the classical regime  

E-Print Network [OSTI]

For quantum effects to be significant in plasmas it is often assumed that the temperature over density ratio must be small. In this paper we challenge this assumption by considering the contribution to the dynamics from the electron spin properties. As a starting point we consider a multicomponent plasma model, where electrons with spin up and spin down are regarded as different fluids. By studying the propagation of Alfv\\'{e}n wave solitons we demonstrate that quantum effects can survive in a relatively high-temperature plasma. The consequences of our results are discussed.

G. Brodin; M. Marklund; G. Manfredi

2008-02-01T23:59:59.000Z

367

The Function of the acr Genes in Phenazine Regulation and Transport in the Biological Control Strain Pseudomonas Chlororaphis 30-84  

E-Print Network [OSTI]

to the RND type of efflux system (13). RND efflux systems are referred to as “proton antiporters,” which means they generate and se a proton gra ie nt across the membrane “to power effl x” by “exchanging one H+ ion for one r g molec l e” (25). RND type... in P. aeruginosa) respectively (25). Pseudomonas aeruginosa is an important opportunistic pathogen that can become resistant to antimicrobials during antibiotic therapy (13). In P. aeruginosa, four multi-component, multi-drug resistant RNDs have been...

Yang, Yan

2014-05-03T23:59:59.000Z

368

A new nonlinear solution method for phase-change problems  

SciTech Connect (OSTI)

Numerical simulation is playing an increasingly important role in support of industrial casting processes. The goal of simulations is to capture accurately the solidification dynamics in pure materials, and in multicomponent alloys. To achieve this goal a numerical algorithm must evolve accurately the latent heat in an isothermal solidification process, and it must also couple accurately the temperature and concentration fields in the nonisothermal solidification of multicomponent alloys. The authors present a new nonlinear algorithm for the efficient and accurate solution of isothermal and nonisothermal phase-change problems. The method correctly evolves latent heat release in isothermal and nonisothermal phase change, and more important, it provides a means for the efficient and accurate coupling between temperature and concentration fields in multispecies nonisothermal phase change. Newton-like superlinear convergence is achieved in the global nonlinear iteration, without the complexity of forming or inverting the Jacobian matrix. This Jacobian-free method is a combination of an outer Newton-based iteration and an inner conjugate gradient-like (krylov) iteration. The effects of the Jacobian are probed only through approximate matrix-vector products required in the conjugate gradient-like iteration.

Knoll, D.A.; Kothe, D.B.; Lally, B. [Los Alamos National Lab., NM (United States)

1999-06-01T23:59:59.000Z

369

Cryomagmatism in the outer solar system  

SciTech Connect (OSTI)

Assemblages of cryovolcanic, tectonic, and impact structures form varied landscapes quite alien in their collective expression. Many variables can affect the cryovolcanic style of a satellite but none more so than cryolava composition. The compositional variable is examined in considerable detail. Existing knowledge of phase equilibria and physical properties of cosmochemically relevant unary, binary, and multi-component chemical systems are summarized. Where published knowledge was found lacking, measurements of the physical chemistry of volatile mixtures are presented. Cryovolcanic landscapes are briefly toured, and knowledge of the physical chemistry of volatile mixtures is applied to problems of cryovolcanological interest. Aqueous cryolavas may range in composition from salt-water brines to cryogenic ammonia-water-rich multi-components solutions possibly involving methanol, ammonium sulfide, alkali chlorides, and many other potential components. Cryomagmatic distillation can greatly accentuate the importance of trace and minor constituents of icy satellites. The viscosities, densities, and other physical properties of these liquids vary considerably and depend sensitively on their exact compositions. These properties affect everything from cryovolcanic eruptive styles and landforms, to the way cryovolcanic crusts respond to tectonic stress. It is believed that the compositional variable is directly or indirectly implicated in a wide varity of geomorphic aspects of contrast among the icy satellites. Thus, even though as yet any specific morphology can be attributed to a specific composition, there appears to be a powerful link between composition of the ices originally accreted by a satellite and its subsequent interior evolution and exterior geomorphic appearance.

Kargel, J.S.

1990-01-01T23:59:59.000Z

370

Global molecular structure and interfaces : refining an RNA : RNA complex structure using solution x-ray scattering data.  

SciTech Connect (OSTI)

Determining the global architecture of multicomponent systems is a central problem in understanding biomacromolecular machines. Defining interfaces among components and the global structure of multicomponent systems is a central problem in understanding the biological interactions on a molecular level. We demonstrate that solution X-ray scattering data can be used to precisely determine intermolecular interfaces from just the subunit structures, in the complete absence of intermolecular NMR restraints using an example of a 30 kDa RNA-RNA complex. The backbone root-mean-square deviation (rmsd) between structures that are determined using the scattering data and using intermolecular distance restraints is about 0.4 {angstrom}. Further, we refined the global structure of the complex using scattering data as a global restraint. The rmsd in backbone structures that are determined with and without the scattering data refinement is about 3.2 {angstrom}, suggesting the impact of the refinement to the overall structure. Information about the 'global correctness' of solution RNA structures could not be practically obtained otherwise, due to the molecular nature of the RNA molecules, but could only be defined by the scattering data together by residual dipolar couplings. This method provides a powerful new approach for refining global structures of macromolecular complexes whose subunits are elongated.

Zuo, X.; Wang, J.; Foster, T. R.; Schwieters, C. D.; Tiede, D. M.; Butcher, S. E.; Wang, Y.-X.; Chemical Sciences and Engineering Division; NCI-Frederick; Univ. of Wisconin at Madison; NIH

2008-03-19T23:59:59.000Z

371

Elucidating the mysteries of wetting.  

SciTech Connect (OSTI)

Nearly every manufacturing and many technologies central to Sandia's business involve physical processes controlled by interfacial wetting. Interfacial forces, e.g. conjoining/disjoining pressure, electrostatics, and capillary condensation, are ubiquitous and can surpass and even dominate bulk inertial or viscous effects on a continuum level. Moreover, the statics and dynamics of three-phase contact lines exhibit a wide range of complex behavior, such as contact angle hysteresis due to surface roughness, surface reaction, or compositional heterogeneities. These thermodynamically and kinetically driven interactions are essential to the development of new materials and processes. A detailed understanding was developed for the factors controlling wettability in multicomponent systems from computational modeling tools, and experimental diagnostics for systems, and processes dominated by interfacial effects. Wettability probed by dynamic advancing and receding contact angle measurements, ellipsometry, and direct determination of the capillary and disjoining forces. Molecular scale experiments determined the relationships between the fundamental interactions between molecular species and with the substrate. Atomistic simulations studied the equilibrium concentration profiles near the solid and vapor interfaces and tested the basic assumptions used in the continuum approaches. These simulations provide guidance in developing constitutive equations, which more accurately take into account the effects of surface induced phase separation and concentration gradients near the three-phase contact line. The development of these accurate models for dynamic multicomponent wetting allows improvement in science based engineering of manufacturing processes previously developed through costly trial and error by varying material formulation and geometry modification.

Webb, Edmund Blackburn, III (,; ); Bourdon, Christopher Jay; Grillet, Anne Mary; Sackinger, Philip A.; Grest, Gary Stephen; Emerson, John Allen; Ash, Benjamin Jesse; Heine, David R.; Brooks, Carlton, F.; Gorby, Allen D.

2005-11-01T23:59:59.000Z

372

Phase Behavior of Aqueous NA-K-MG-CA-CI-NO3 Mixtures: Isopiestic Measurements and Thermodynamic Modeling  

SciTech Connect (OSTI)

A comprehensive model has been established for calculating thermodynamic properties of multicomponent aqueous systems containing the Na{sup +}, K{sup +}, Mg{sup 2+}, Ca{sup 2+}, Cl{sup -}, and NO{sub 3}{sup -} ions. The thermodynamic framework is based on a previously developed model for mixed-solvent electrolyte solutions. The framework has been designed to reproduce the properties of salt solutions at temperatures ranging from the freezing point to 300 C and concentrations ranging from infinite dilution to the fused salt limit. The model has been parameterized using a combination of an extensive literature database and new isopiestic measurements for thirteen salt mixtures at 140 C. The measurements have been performed using Oak Ridge National Laboratory's (ORNL) previously designed gravimetric isopiestic apparatus, which makes it possible to detect solid phase precipitation. Water activities are reported for mixtures with a fixed ratio of salts as a function of the total apparent salt mole fraction. The isopiestic measurements reported here simultaneously reflect two fundamental properties of the system, i.e., the activity of water as a function of solution concentration and the occurrence of solid-liquid transitions. The thermodynamic model accurately reproduces the new isopiestic data as well as literature data for binary, ternary and higher-order subsystems. Because of its high accuracy in calculating vapor-liquid and solid-liquid equilibria, the model is suitable for studying deliquescence behavior of multicomponent salt systems.

M.S. Gruszkiewiez; D.A. Palmer; R.D. Springer; P. Wang; A. Anderko

2006-09-14T23:59:59.000Z

373

EXPLORING FOR SUBTLE MISSION CANYON STRATIGRAPHIC TRAPS WITH ELASTIC WAVEFIELD SEISMIC TECHNOLOGY  

SciTech Connect (OSTI)

A source-receiver geometry was designed for a 9C3D seismic survey in Montrail County, North Dakota, that will involve the largest number of active 3-component stations (1,800 to 2,100) ever attempted in an onshore U.S. multicomponent seismic survey. To achieve the data-acquisition objectives, 3-component geophone strings will be provided by the Bureau of Economic Geology, Dawson Geophysical, and Vecta Technology. Data acquisition will commence in late October 2003. The general objective of this study is to demonstrate the value of multicomponent seismic technology for exploring for subtle oolitic-bank reservoirs in the Mission Canyon Formation of the Williston Basin. The work tasks done during this report period concentrated on developing an optimal design for the seismic survey. This first semiannual report defines the geographical location and geometrical shape of the survey and documents the key acquisition parameters that will be implemented to yield high-fold, high-resolution 9-component seismic data.

John Beecherl

2003-10-01T23:59:59.000Z

374

TMVOC, simulator for multiple volatile organic chemicals  

SciTech Connect (OSTI)

TMVOC is a numerical simulator for three-phase non-isothermal flow of water, soil gas, and a multicomponent mixture of volatile organic chemicals (VOCs) in multidimensional heterogeneous porous media. It is an extension of the TOUGH2 general-purpose simulation program developed at the Lawrence Berkeley National Laboratory. TMVOC is designed for applications to contamination problems that involve hydrocarbon fuel or organic solvent spills in saturated and unsaturated zones. It can model contaminant behavior under ''natural'' environmental conditions, as well as for engineered systems, such as soil vapor extraction, groundwater pumping, or steam-assisted source remediation. TMVOC is upwards compatible with T2VOC (Falta et al., 1995) and can be initialized from T2VOC-style initial conditions. The main enhancements in TMVOC relative to T2VOC are as follows: a multicomponent mixture of volatile organic chemicals can be modeled; any and all combinations of the three phases water-oil-gas are treated; several non-condensible gases may be present; diffusion is treated in all phases in a manner that is fully coupled with phase partitioning. This paper gives a brief summary of the methodology used in TMVOC as well as highlighting some implementation issues. Simulation of a NAPL spill and subsequent remediation is discussed for a 2-D vertical section of a saturated-unsaturated flow problem.

Pruess, Karsten; Battistelli, Alfredo

2003-03-25T23:59:59.000Z

375

Modelling Mixed Bed Ion Exchange Kinetics for Removal of Trace Levels of Divalent Cations in Ultrapure Water  

SciTech Connect (OSTI)

Ion exchanger resin fluid film mass transfer coefficients and the ionic diffusivities from which they are derived are often measured by use of ion exchange resin columns. Such tests, usually run dynamically using short resin beds, are often performed using relatively high (ppm) concentrations of ions to accurately measure output concentrations as a function of flow rate. The testing described herein was performed to determine fluid film ionic diffusivities for cationic concentrations typical of ultrapure water ({le}ppb levels) containing ppm levels of ammonia. Effective ionic diffusivities at these low ionic concentrations and high pHs were needed to complete a computer model (SIMIX) to be used in ion exchange simulations. SIMIX is a generalized multicomponent ion exchange model designed to simulate the removal of divalent cations from ultrapure water.

B. Widman

2003-01-01T23:59:59.000Z

376

Energy Efficiency and Renewable Energy Program. Bibliography, 1993 edition  

SciTech Connect (OSTI)

The Bibliography contains listings of publicly available reports, journal articles, and published conference papers sponsored by the DOE Office of Energy Efficiency and Renewable Energy and published between 1987 and mid-1993. The topics of Bibliography include: analysis and evaluation; building equipment research; building thermal envelope systems and materials; district heating; residential and commercial conservation program; weatherization assistance program; existing buildings research program; ceramic technology project; alternative fuels and propulsion technology; microemulsion fuels; industrial chemical heat pumps; materials for advanced industrial heat exchangers; advanced industrial materials; tribology; energy-related inventions program; electric energy systems; superconducting technology program for electric energy systems; thermal energy storage; biofuels feedstock development; biotechnology; continuous chromatography in multicomponent separations; sensors for electrolytic cells; hydropower environmental mitigation; environmental control technology; continuous fiber ceramic composite technology.

Vaughan, K.H.

1993-06-01T23:59:59.000Z

377

First-principles path-integral renormalization-group method for Coulombic many-body systems  

SciTech Connect (OSTI)

An approach for obtaining the ground state of Coulombic many-body systems is presented. This approach is based on the path-integral renormalization-group method with nonorthogonal Slater determinants, is free of the negative sign problem, and can handle higher dimensional systems with consideration of the correlation effect. Furthermore, it can be easily extended to the multicomponent quantum systems that contain more than two kinds of quantum particles. According to our results obtained with the present approach, it achieves the same accuracy as the variational Monte Carlo method with a few Slater determinants and enables us to study the entire ground state consisting of electrons and nuclei without the need to use the Born-Oppenheimer approximation.

Kojo, Masashi; Hirose, Kikuji [Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan)

2009-10-15T23:59:59.000Z

378

Fabrication of catalyzed ion transport membrane systems  

DOE Patents [OSTI]

Process for fabricating a catalyzed ion transport membrane (ITM). In one embodiment, an uncatalyzed ITM is (a) contacted with a non-reducing gaseous stream while heating to a temperature and for a time period sufficient to provide an ITM possessing anion mobility; (b) contacted with a reducing gaseous stream for a time period sufficient to provide an ITM having anion mobility and essentially constant oxygen stoichiometry; (c) cooled while contacting the ITM with the reducing gaseous stream to provide an ITM having essentially constant oxygen stoichiometry and no anion mobility; and (d) treated by applying catalyst to at least one of (1) a porous mixed conducting multicomponent metallic oxide (MCMO) layer contiguous with a first side of a dense layer of MCMO and (2) a second side of the dense MCMO layer. In another embodiment, these steps are carried out in the alternative order of (a), (d), (b), and (c).

Carolan, Michael Francis; Kibby, Charles Leonard

2013-06-04T23:59:59.000Z

379

Mixed conducting membranes for syngas production  

DOE Patents [OSTI]

This invention presents a new class of multicomponent metallic oxides which are particularly suited toward use in fabricating components used in processes for producing syngas. The non-stoichiometric, A-site rich compositions of the present invention are represented by the formula (Ln.sub.x Ca.sub.1-x).sub.y FeO.sub.3-.delta. wherein Ln is La or a mixture of lanthanides comprising La, and wherein 1.0>x>0.5, 1.1.gtoreq.y>1.0 and .delta. is a number which renders the composition of matter charge neutral. Solid-state membranes formed from these compositions provide a favorable balance of oxygen permeance and resistance to degradation when employed in processes for producing syngas. This invention also presents a process for making syngas which utilizes such membranes.

Dyer, Paul Nigel (Allentown, PA); Carolan, Michael Francis (Allentown, PA); Butt, Darryl (Gainesville, FL); Van Doorn, Rene Hendrick Elias (Neckarsulm, DE); Cutler, Raymond Ashton (Bountiful, UT)

2002-01-01T23:59:59.000Z

380

Vacancy solution theory of adsorption from gas mixtures  

SciTech Connect (OSTI)

The new correlation based on vacancy-solution theory, reports Pennsylvania State University, improves predictions of gas-mixture adsorption equilibria from single-component adsorption isotherm data. The new method is more general, simpler to apply, and more accurate than other available models. For an adsorption system, the binary parameters - adsorbate and vacancy - are obtained from regression of the pure-gas adsorption data with the vacancy-solution isotherm equation. These parameters are then used to predict multicomponent adsorption equilibrium, assuming that the adsorbate-adsorbate interactions are negligible. Penn State has verified the new correlation on two different kinds of binary adsorption systems: mixtures of O/sub 2/, N/sub 2/, and CO on zeolite 10X and mixtures of light hydrocarbons on Nuxit-AL activated carbon.

Suwanayuen, S.; Danner, R.P.

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

1059-9630/$19.00 Ó ASM International Effective Parameters in Axial Injection Suspension Plasma Spray Process  

E-Print Network [OSTI]

Suspension plasma spray (SPS) is a novel process for producing nano-structured coatings with metastable phases using significantly smaller particles as compared to conventional thermal spraying. Considering the complexity of the system there is an extensive need to better understand the relationship between plasma spray conditions and resulting coating microstructure and defects. In this study, an alumina/ 8 wt. % yttria-stabilized zirconia was deposited by axial injection SPS process. The effects of principal deposition parameters on the microstructural features are evaluated using the Taguchi design of experiment. The microstructural features include microcracks, porosities, and deposition rate. To better understand the role of the spray parameters, in-flight particle characteristics, i.e., temperature and velocity were also measured. The role of the porosity in this multicomponent structure is studied as well. The results indicate that thermal diffusivity of the coatings, an important property for potential thermal barrier applications, is barely affected by the changes in porosity content.

Of Alumina-zirconia Ceramics; F. Tarasi; M. Medraj; A. Dolatabadi; J. Oberste-berghaus; C. Moreau; Peer Reviewed

2008-01-01T23:59:59.000Z

382

Hypersonic hydrogen combustion in the thin viscous shock layer  

SciTech Connect (OSTI)

Different models of hypersonic diffusive hydrogen combustion in a thin viscous shock layer (TVSL) at moderate Reynolds numbers have been developed. The study is based on computations of nonequilibrium multicomponent flowfield parameters of air-hydrogen mixture in the TVSL near the blunt probe. The structure of computed combustion zones is analyzed. Under conditions of slot and uniform injections the zone structures are essentially different. Hydrogen injection conditions are discovered at which the nonreacting hydrogen zone and the zone enriched with the hydrogen combustion products appear near the body surface. Hydrogen, water, and OH concentrations identify these zones. More effective cooling of the probe surface occurs at moderate injections compared to strong ones. Under the blowing conditions at moderate Reynolds numbers the most effective cooling of the body surface occurs at moderate uniform hydrogen injection. The results can be helpful for predicting the degree of supersonic hydrogen combustion in hypersonic vehicle engines. 21 refs.

Riabov, V.V.; Botin, A.V. [Worcester Polytechnic Inst, Worcester, MA (United States)

1995-04-01T23:59:59.000Z

383

Method of forming biaxially textured alloy substrates and devices thereon  

DOE Patents [OSTI]

Specific alloys, in particular Ni-based alloys, that can be biaxially textured, with a well-developed, single component texture are disclosed. These alloys have a significantly reduced Curie point, which is very desirable from the point of view of superconductivity applications. The biaxially textured alloy substrates also possess greatly enhanced mechanical properties (yield strength, ultimate tensile strength) which are essential for most applications, in particular, superconductors. A method is disclosed for producing complex multicomponent alloys which have the ideal physical properties for specific applications, such as lattice parameter, degree of magnetism and mechanical strength, and which cannot be fabricated in textured form. In addition, a method for making ultra thin biaxially textured substrates with complex compositions is disclosed.

Goyal, Amit (Knoxville, TN); Specht, Eliot D. (Knoxville, TN); Kroeger, Donald M. (Knoxville, TN); Paranthaman, Mariappan (Knoxville, TN)

1999-01-01T23:59:59.000Z

384

Method of forming biaxially textured alloy substrates and devices thereon  

DOE Patents [OSTI]

Specific alloys, in particular Ni-based alloys, that can be biaxially textured, with a well-developed, single component texture are disclosed. These alloys have a significantly reduced Curie point, which is very desirable from the point of view of superconductivity applications. The biaxially textured alloy substrates also possess greatly enhanced mechanical properties (yield strength, ultimate tensile strength) which are essential for most applications, in particular, superconductors. A method is disclosed for producing complex multicomponent alloys which have the ideal physical properties for specific applications, such as lattice parameter, degree of magnetism and mechanical strength, and which cannot be in textured form. In addition, a method for making ultra thin biaxially textured substrates with complex compositions is disclosed.

Goyal, Amit (300 Walker Springs Rd., #19E, Knoxville, TN 37923); Specht, Eliot D. (10639 Rivermist La., Knoxville, TN 37922); Kroeger, Donald M. (716 Villa Crest Dr., Knoxville, TN 37923); Paranthaman, Mariappan (1117 Oak Haven Rd., Knoxville, TN 37923)

2000-01-01T23:59:59.000Z

385

Computer control and data acquisition system for the R. F. Test Facility  

SciTech Connect (OSTI)

The Radio Frequency Test Facility (RFTF) at Oak Ridge National Laboratory, used to test and evaluate high-power ion cyclotron resonance heating (ICRH) systems and components, is monitored and controlled by a multicomponent computer system. This data acquisition and control system consists of three major hardware elements: (1) an Allen-Bradley PLC-3 programmable controller; (2) a VAX 11/780 computer; and (3) a CAMAC serial highway interface. Operating in LOCAL as well as REMOTE mode, the programmable logic controller (PLC) performs all the control functions of the test facility. The VAX computer acts as the operator's interface to the test facility by providing color mimic panel displays and allowing input via a trackball device. The VAX also provides archiving of trend data acquired by the PLC. Communications between the PLC and the VAX are via the CAMAC serial highway. Details of the hardware, software, and the operation of the system are presented in this paper.

Stewart, K.A.; Burris, R.D.; Mankin, J.B.; Thompson, D.H.

1986-01-01T23:59:59.000Z

386

Computer control and data-acquisition system for the rf test facility  

SciTech Connect (OSTI)

The radio frequency test facility (RFTF) at Oak Ridge National Laboratory, used to test and evaluate high-power ion cyclotron resonance heating (ICRH) systems and components, is monitored and controlled by a multicomponent computer system. This data-acquisition and control system consists of three major hardware elements: (1) an Allen-Bradley PLC-3 programmable controller, (2) a VAX 11/780 computer, and (3) a CAMAC serial highway interface. Operating in LOCAL as well as REMOTE mode, the programmable logic controller (PLC) performs all the control functions of the test facility. The VAX computer acts as the operator's interface to the test facility by providing color mimic panel displays and allowing input via a trackball device. The VAX also provides archiving of trend data acquired by the PLC. Communications between the PLC and the VAX are via the CAMAC serial highway. Details of the hardware, software, and the operation of the system are presented in this paper.

Stewart, K.A.; Burris, R.D.; Mankin, J.B.; Thompson, D.H.

1986-08-01T23:59:59.000Z

387

MadDM v.1.0: Computation of Dark Matter Relic Abundance Using MadGraph5  

E-Print Network [OSTI]

We present MadDM v.1.0, a numerical tool to compute dark matter relic abundance in a generic model. The code is based on the existing MadGraph 5 architecture and as such is easily integrable into any MadGraph collider study. A simple Python interface offers a level of user-friendliness characteristic of MadGraph 5 without sacrificing functionality. MadDM is able to calculate the dark matter relic abundance in models which include a multi-component dark sector, resonance annihilation channels and co-annihilations. We validate the code in a wide range of dark matter models by comparing the relic density results from MadDM to the existing tools and literature.

Mihailo Backovic; Kyoungchul Kong; Mathew McCaskey

2014-04-24T23:59:59.000Z

388

Optical characteristics of a HgBr excilamp  

SciTech Connect (OSTI)

Optical characteristics of a coaxial HgBr excilamp on multicomponent mercury dibromide vapour mixtures with helium, nitrogen and sulfur hexafluoride are investigated under pumping by a pulse-periodic barrier discharge. Stable excilamp operation was demonstrated at a pump pulse repetition rate of 3 – 9 kHz. The component composition of the working system was determined, which provides a maximal average and pulsed specific radiation power of 48.8 mW cm{sup -3} and 40.6 W cm{sup -3}, respectively, at the efficiency of 7.3 % in the blue-green spectral range with the maximal radiation intensity at the wavelength of 502 nm. The reduction in the radiation power after 2.5 × 10{sup 6} shots is 5 %. Interpretation is given for the results of optimisation of excilamp characteristics. (optical radiation sources)

Malinina, A A; Malinin, A N; Shuaibov, A K [Uzhgorod National University, Uzhgorod (Ukraine)

2013-08-31T23:59:59.000Z

389

Salt Effect Model for Aqueous Solubility of TBP in a 5 to 100% TBP/n-Dodecane-Nitric Acid-Water Biphasic System at 298.2 K  

SciTech Connect (OSTI)

The solubilities of nonelectrolytes in aqueous electrolyte solutions have traditionally been modeled by using the Setschenow equation for salt effect. The aqueous solubility of tri-n-butyl phosphate (TBP) during operating conditions of the Purex process is an important parameter for safety considerations. Use of the Setschenow equation for aqueous solubility of TBP under limited conditions has been reported in the literature. However, there is no general model available to account for the presence of the diluent and for the case of multicomponent electrolyte solutions in which only some electrolytes are solvated and extracted by TBP. An extended salt effect model is proposed for predicting the aqueous solubility of TBP in a 5 to 100% TBP/n-dodecane-nitric acid-water biphasic system at 298.2 K. The literature data on TBP solubility were correlated to aqueous acid concentration, diluent concentration in the solvents, and an interaction parameter for electrolytic solutes (extracted or not extracted by TBP)

Kumar, Shekhar; Koganti, Sudhir Babu [Indira Gandhi Centre for Atomic Research (India)

2000-02-15T23:59:59.000Z

390

An Energy Savings Model for the Heat Treatment of Castings  

SciTech Connect (OSTI)

An integrated system of software, databases, and design rules have been developed, verified, and to be marketed to enable quantitative prediction and optimization of the heat treatment of aluminum castings to increase quality, increase productivity, reduce heat treatment cycle times and reduce energy consumption. The software predicts the thermal cycle in critical locations of individual components in a furnace, the evolution of microstructure, and the attainment of properties in heat treatable aluminum alloy castings. The model takes into account the prior casting process and the specific composition of the component. The heat treatment simulation modules can be used in conjunction with software packages for simulation of the casting process. The system is built upon a quantitative understanding of the kinetics of microstructure evolution in complex multicomponent alloys, on a quantitative understanding of the interdependence of microstructure and properties, on validated kinetic and thermodynamic databases, and validated quantitative models.

Y. Rong; R. Sisson; J. Morral; H. Brody

2006-12-31T23:59:59.000Z

391

Recent advances in the COMMIX and BODYFIT codes  

SciTech Connect (OSTI)

Two general-purpose computer programs for thermal-hydraulic analysis have been developed. One is the COMMIX (COMponent MIXing code. The other one is the BODYFIT (BOunDary FITted Coordinate Transformation) code. Solution procedures based on both elliptical and parabolic systems of partial differential equations are provided in these two codes. The COMMIX code is designed to provide global analysis of thermal-hydraulic behavior of a component or multicomponent of engineering problems. The BODYFIT code is capable of treating irregular boundaries and gives more detailed local information on a subcomponent or component. These two codes are complementary to each other and represent the state-of-the-art of thermal-hydraulic analysis. Effort will continue to make further improvements and include additional capabilities in these codes.

Sha, W.T.; Chen, B.C.J.; Domanus, H.M.; Wood, P.M.

1983-01-01T23:59:59.000Z

392

Wavelength- and thickness-independent optical coatings for integrated circuit metallization layers  

SciTech Connect (OSTI)

Detailed measurements have been made of the optical properties of sputtered tantalum silicide films on aluminum layers used in integrated circuit fabrication. This new multicomponent conductor (TaSi/sub x/ on aluminum), which is currently in use because of its exceptional electrical, physical, and chemical properties, was also found to have superior optical properties compared to aluminum alone. The addition of the thin silicide layers reduces both the total hemispherical and diffuse reflectance properties by up to 45% over the 265--800-nm wavelength range with almost no dependence on film thickness. Unlike other optical coatings used on metal layers in integrated circuit manufacturing, the silicide films do not need to be removed after photolithography and pattern transfer processes are completed: aluminum wire bonding from the completed circuit (with silicide coating) to the package is highly reliable and reproducible.

Draper, B.L.; Mahoney, A.R.; Bailey, G.A.

1987-12-01T23:59:59.000Z

393

Chemical kinetic modeling of component mixtures relevant to gasoline  

SciTech Connect (OSTI)

Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, a recently revised version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multi-component gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines. Simulation results are discussed focusing attention on the mixing effects of the fuel components.

Mehl, M; Curran, H J; Pitz, W J; Westbrook, C K

2009-02-13T23:59:59.000Z

394

Kinetic Modeling of Gasoline Surrogate Components and Mixtures under Engine Conditions  

SciTech Connect (OSTI)

Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, an improved version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multicomponent gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines (3-50 atm, 650-1200K, stoichiometric fuel/air mixtures). Simulation results are discussed focusing attention on the mixing effects of the fuel components.

Mehl, M; Pitz, W J; Westbrook, C K; Curran, H J

2010-01-11T23:59:59.000Z

395

Detailed Kinetic Modeling of Gasoline Surrogate Mixtures  

SciTech Connect (OSTI)

Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, a recently revised version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multi-component gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines. Simulation results are discussed focusing attention on the mixing effects of the fuel components.

Mehl, M; Curran, H J; Pitz, W J; Westbrook, C K

2009-03-09T23:59:59.000Z

396

Alpha phase precipitation from phase-separated beta phase in a model Ti-Mo-Al alloy studied by direct coupling of transmission electron microscopy and atom probe tomography  

SciTech Connect (OSTI)

The benefit of direct coupling of APT with TEM dark field imaging to investigate early stages of phase transformation in multicomponent alloys is demonstrated by analyzing alpha phase precipitated in a model Ti-10 at% Mo-10 at% Al alloy during annealing at 400oC. Through such a direct coupling approach a thermodynamically unexpected solute partitioning trend between beta matrix and alpha precipitate is observed in the early stages of precipitation, which is explained based on possible nucleation of alpha phase in the Ti rich (Mo and Al depleted regions) created as a result of phase separation in beta matrix. On further higher temperature annealing at 600oC for 1 hour, the alpha precipitates were shown to grow and get enriched in Al and further depleted in Mo reaching the thermodynamic equilibrium.

Devaraj, Arun; Nag, Soumya; Banerjee, Rajarshi

2013-10-19T23:59:59.000Z

397

Three-dimensional nonlinear Schroedinger equation in electron-positron-ion magnetoplasmas  

SciTech Connect (OSTI)

Three-dimensional ion-acoustic envelope soliton excitations in electron-positron-ion magnetoplasmas are interpreted. This is accomplished through the derivation of three-dimensional nonlinear Schroedinger equation, where the nonlinearity is balancing with the dispersive terms. The latter contains both an external magnetic field besides the usual plasma parameter effects. Based on the balance between the nonlinearity and the dispersion terms, the regions for possible envelope solitons are investigated indicating that new regimes for modulational instability of envelope ion-acoustic waves could be obtained, which cannot exist in the unmagnetized case. This will allow us to establish additional new regimes, different from the usual unmagnetized plasma, for envelope ion-acoustic waves to propagate in multicomponent plasma that may be observed in space or astrophysics.

Sabry, R. [Department of Physics, College of Science and Humanitarian Studies, Alkharj University, Alkharj 11942 (Saudi Arabia); Department of Physics, Theoretical Physics Group, Faculty of Science, Mansoura University, Damietta-Branch, New Damietta, 34517 Damietta (Egypt); Moslem, W. M. [Department of Physics, Faculty of Science, Port Said University, Port Said (Egypt); El-Shamy, E. F. [Department of Physics, Theoretical Physics Group, Faculty of Science, Mansoura University, Damietta-Branch, New Damietta, 34517 Damietta (Egypt); Shukla, P. K. [RUB International Chair, Faculty of Physics and Astronomy, International Centre for Advanced Studies in Physical Sciences, Ruhr-Universitaet Bochum, D-44780 Bochum (Germany)

2011-03-15T23:59:59.000Z

398

Ternary liquid mixture viscosities and densities  

SciTech Connect (OSTI)

Liquid mixture viscosities and densities have been measured at 298.15 K and ambient pressure for 20 ternary systems. Twelve ternary compositions, encompassing the entire composition range, have been chosen for each system in an effort to test a newly proposed predictive equation based on local compositions. Viscosities calculated by using the local composition model agreed with the experimental data within an average absolute deviation of 6.4%. No adjustable parameters were used and only binary interactions in the form of NRTL constants were input. The results of these studies indicate that the local composition model predictions are generally as good for multicomponent systems as they are for the corresponding binaries. 24 references, 3 tables.

Wei, I.C.; Rowley, R.L.

1984-01-01T23:59:59.000Z

399

Reliable computation of homogeneous azeotropes  

SciTech Connect (OSTI)

It is important to determine the existence and composition of homogeneous azeotropes in the analysis of phase behavior and in the synthesis and design of separation systems, from both theoretical and practical standpoints. A new method for reliably locating any and all homogeneous azeotropes for multicomponent mixtures is presented. The method also verifies the nonexistence of homogeneous azeotropes if none are present. The method is based on interval analysis, in particular an interval-Newton/generalized-bisection-algorithm providing a mathematical and computational guarantee that all azeotropes are located. This general-purpose technique can be applied in connection with any thermodynamic models. The technique is illustrated in several example problems using the Wilson, NRTL, and UNIQUAC activity-coefficient models.

Maier, R.W.; Brennecke, J.F.; Stadtherr, M.A. [Univ. of Notre Dame, IN (United States). Dept. of Chemical Engineering] [Univ. of Notre Dame, IN (United States). Dept. of Chemical Engineering

1998-08-01T23:59:59.000Z

400

Thermochemistry of high-temperature corrosion  

SciTech Connect (OSTI)

Multicomponent gas environments are prevalent in a number of energy systems, especially in those that utilize fossil fuels. The gas environments in these processes contain sulfur-bearing components in addition to oxidants. These complex environments, coupled with the elevated temperatures present in these systems, generally cause significant corrosion of engineering materials. Thermodynamic aspects of high-temperature corrosion processes occuring in complex gas mixtures are discussed, with emphasis on the role of thermochemical diagrams. The interrelationships between the corrosion behavior of materials and gas composition, alloy chemistry, and temperatures are examined. A number of examples from studies on materials behavior in coal-gasification environments are used to elucidate the role of thermochemistry in the understanding of corrosion processes that occur in complex gas mixtures. 11 figures.

Natesan, K.

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

ITOUGH2 user`s guide version 2.2  

SciTech Connect (OSTI)

ITOUGH2 is a program to estimate hydrogeologic model parameters for the numerical simulator TOUGH2. TOUGH2 was developed by Karsten Pruess at Lawrence Berkeley Laboratory for simulating non-isothermal flows of multicomponent, multiphase fluids in porous and fractured media. ITOUGH2 solves the inverse problem by automatic model calibration based on an indirect approach, in which some function of the difference between observed and model-predicted system response and appropriately weighted prior information about the parameters is minimized using standard optimization techniques. ITOUGH2 also provides a detailed error analysis of the estimated parameter set, and employs some procedures to study error propagation for prediction runs. This report includes a review of the inverse modeling theory, and a detailed description of the program architecture, input language, and the various user features provided by ITOUGH2. A sample problem is given to illustrate code application.

Finsterle, S.

1993-08-01T23:59:59.000Z

402

Tuning the external optical feedback-sensitivity of a passively mode-locked quantum dot laser  

SciTech Connect (OSTI)

The external optical feedback-sensitivity of a two-section, passively mode-locked quantum dot laser operating at elevated temperature is experimentally investigated as a function of absorber bias voltage. Results show that the reverse-bias voltage on the absorber has a direct impact on the damping rate of the free-running relaxation oscillations of the optical signal output, thereby enabling interactive external control over the feedback-response of the device, even under the nearly resonant cavity configuration. The combination of high temperature operation and tunable feedback-sensitivity is highly promising from a technological standpoint, in particular, for applications requiring monolithic integration of multi-component architectures on a single chip in order to accomplish, for instance, the dual-objectives of stable pulse quality and isolation from parasitic reflections.

Raghunathan, R., E-mail: raghunat@vt.edu; Kovanis, V.; Lester, L. F. [Bradley Department of Electrical and Computer Engineering, Virginia Polytechnic Institute and State University, 302 Whittemore Hall, Blacksburg, Virginia 24061 (United States); Grillot, F. [Télécom ParisTech, Ecole Nationale Supérieure des Télécommunications, CNRS LTCI, 46 rue Barrault, 75634 Paris Cedex 13 (France); Mee, J. K.; Murrell, D. [Center for High Technology Materials, University of New Mexico, 1313 Goddard SE, Albuquerque, New Mexico 87106 (United States)

2014-07-28T23:59:59.000Z

403

Nanostructured composite reinforced material  

DOE Patents [OSTI]

A family of materials wherein nanostructures and/or nanotubes are incorporated into a multi-component material arrangement, such as a metallic or ceramic alloy or composite/aggregate, producing a new material or metallic/ceramic alloy. The new material has significantly increased strength, up to several thousands of times normal and perhaps substantially more, as well as significantly decreased weight. The new materials may be manufactured into a component where the nanostructure or nanostructure reinforcement is incorporated into the bulk and/or matrix material, or as a coating where the nanostructure or nanostructure reinforcement is incorporated into the coating or surface of a "normal" substrate material. The nanostructures are incorporated into the material structure either randomly or aligned, within grains, or along or across grain boundaries.

Seals, Roland D. (Oak Ridge, TN); Ripley, Edward B. (Knoxville, TN); Ludtka, Gerard M. (Oak Ridge, TN)

2012-07-31T23:59:59.000Z

404

Signal for the Quark-Hadron Phase Transition in Rotating Hybrid Stars  

E-Print Network [OSTI]

For the past 20 years it had been thought that the coexistence phase of the confined hadronic and quark matter phases, assumed to be a first order transition, was strictly excluded from neutron stars. This, however, was due to a seemingly innocuous idealization which has approximated away important physics. The reason is that neutron stars constitute multi-component bodies rather than single-component ones formerly (and incorrectly) used to describe the deconfinement phase transition in neutron stars. So, contrary to earlier claims, `neutron' stars may very well contain quark matter in their cores surrounded by a mixed-phase region of quark and hadronic matter. Such objects are called hybrid stars. The structure of such stars as well as an observable signature that could signal the existence of quark matter in their cores are discussed in this paper.

Fridolin Weber; Norman K. Glendenning; Shouyong Pei

1997-05-25T23:59:59.000Z

405

Nonequilibrium transport through quantum-wire junctions and boundary defects for free massless bosonic fields  

E-Print Network [OSTI]

We consider a model of quantum-wire junctions where the latter are described by conformal-invariant boundary conditions of the simplest type in the multicomponent compactified massless scalar free field theory representing the bosonized Luttinger liquids in the bulk of wires. The boundary conditions result in the scattering of charges across the junction with nontrivial reflection and transmission amplitudes. The equilibrium state of such a system, corresponding to inverse temperature $\\beta$ and electric potential $V$, is explicitly constructed both for finite and for semi-infinite wires. In the latter case, a stationary nonequilibrium state describing the wires kept at different temperatures and potentials may be also constructed. The main result of the present paper is the calculation of the full counting statistics (FCS) of the charge and energy transfers through the junction in a nonequilibrium situation. Explicit expressions are worked out for the generating function of FCS and its large-deviations asym...

Gaw?dzki, Krzysztof

2015-01-01T23:59:59.000Z

406

Dose factor entry and display tool for BNCT radiotherapy  

DOE Patents [OSTI]

A system for use in Boron Neutron Capture Therapy (BNCT) radiotherapy planning where a biological distribution is calculated using a combination of conversion factors and a previously calculated physical distribution. Conversion factors are presented in a graphical spreadsheet so that a planner can easily view and modify the conversion factors. For radiotherapy in multi-component modalities, such as Fast-Neutron and BNCT, it is necessary to combine each conversion factor component to form an effective dose which is used in radiotherapy planning and evaluation. The Dose Factor Entry and Display System is designed to facilitate planner entry of appropriate conversion factors in a straightforward manner for each component. The effective isodose is then immediately computed and displayed over the appropriate background (e.g. digitized image).

Wessol, Daniel E. (Bozeman, MT); Wheeler, Floyd J. (Idaho Falls, ID); Cook, Jeremy L. (Greeley, CO)

1999-01-01T23:59:59.000Z

407

A C/sup +//sub 7/ characterization method for bitumen mixture phase behavior predictions  

SciTech Connect (OSTI)

A procedure was developed to characterize the C/sub 7+/ fraction of bitumen for the Peng-Robinson (PR) equation-of-state (EOS) and to predict multicomponent diluent/bitumen mixture phase behavior. The results showed that the procedure can predict accurately not only the bubble-point pressures but also the atmospheric flash compositions at surface facilities and reservoir conditions. In this procedure, new correlations for the acentric factor and the PR EOS interaction coefficients for high molecular weight components were developed. The sensitivities of the EOS predictions to the number of pseudocomponents and the corresponding critical properties and acentric factors were analyzed. The results also indicated that the critical temperature and the acentric factor of the C/sub 7+/ fraction have a strong influence on the bubble-point pressure predictions. As for the prediction of the flash compositions, the number of pseudocomponents and the interaction coefficients have the strongest influence.

Yu, J.M.; Wu, R.S.; Batycky, J.P. (Research Dept., Esso Resources Canada Ltd. (CA))

1988-01-01T23:59:59.000Z

408

ESM of Ionic and Electrochemical Phenomena on the Nanoscale  

SciTech Connect (OSTI)

Operation of energy storage and conversion devices is ultimately controlled by series of intertwined ionic and electronic transport processes and electrochemical reactions at surfaces and interfaces, strongly mediated by strain and mechanical processes [1-4]. In a typical fuel cell, these include chemical species transport in porous cathode and anode materials, gas-solid electrochemical reactions at grains and triple-phase boundaries (TPBs), ionic and electronic flows in multicomponent electrodes, and chemical and electronic potential drops at internal interfaces in electrodes and electrolytes. All these phenomena are sensitively affected by the microstructure of materials from device level to the atomic scales as illustrated in Fig. 1. Similar spectrum of length scales and phenomena underpin operation of other energy systems including primary and secondary batteries, as well as hybrid systems such flow and metal-air/water batteries.

Kalinin, Sergei V [ORNL; Kumar, Amit [Pennsylvania State University; Balke, Nina [ORNL; McCorkle, Morgan L [ORNL; Guo, Senli [ORNL; Arruda, Thomas M [ORNL; Jesse, Stephen [ORNL

2011-01-01T23:59:59.000Z

409

TOUGH2: A general-purpose numerical simulator for multiphase fluid and heat flow  

SciTech Connect (OSTI)

TOUGH2 is a numerical simulation program for nonisothermal flows of multicomponent, multiphase fluids in porous and fractured media. The chief applications for which TOUGH2 is designed are in geothermal reservoir engineering, nuclear waste disposal, and unsaturated zone hydrology. A successor to the TOUGH program, TOUGH2 offers added capabilities and user features, including the flexibility to handle different fluid mixtures, facilities for processing of geometric data (computational grids), and an internal version control system to ensure referenceability of code applications. This report includes a detailed description of governing equations, program architecture, and user features. Enhancements in data inputs relative to TOUGH are described, and a number of sample problems are given to illustrate code applications. 46 refs., 29 figs., 12 tabs.

Pruess, K.

1991-05-01T23:59:59.000Z

410

Structure of Bright 2MASS Galaxies: 2D Fits to the Ks-band Surface Brightness Profiles  

E-Print Network [OSTI]

The unprecedented sky coverage and photometric uniformity of the Two Micron All Sky Survey (2MASS) provides a rich resource for obtaining a detailed understanding of the galaxies populating our local (z<0.1) Universe. A full characterization of the physical structure of nearby galaxies is essential for theoretical and observational studies of galaxy evolution and structure formation. We have begun a quantified description of the internal structure and morphology of 10,000 bright (10multi-component model fits to the 2D surface brightness profiles using GIM2D. From our initial Monte Carlo tests on 77 galaxies drawn at random from the RC3, we find that the model derived structural parameter errors due to sky uncertainies are typically less than 10%.

Daniel H. McIntosh; Ari H. Maller; Neal Katz; Martin D. Weinberg

2002-09-01T23:59:59.000Z

411

Fundamentals of high pressure adsorption  

SciTech Connect (OSTI)

High-pressure adsorption attracts research interests following the world's attention to alternative fuels, and it exerts essential effect on the study of hydrogen/methane storage and the development of novel materials addressing to the storage. However, theoretical puzzles in high-pressure adsorption hindered the progress of application studies. Therefore, the present paper addresses the major theoretical problems that challenged researchers: i.e., how to model the isotherms with maximum observed in high-pressure adsorption; what is the adsorption mechanism at high pressures; how do we determine the quantity of absolute adsorption based on experimental data. Ideology and methods to tackle these problems are elucidated, which lead to new insights into the nature of high-pressure adsorption and progress in application studies, for example, in modeling multicomponent adsorption, hydrogen storage, natural gas storage, and coalbed methane enrichment, was achieved.

Zhou, Y.P.; Zhou, L. [Tianjin University, Tianjin (China). High Pressure Adsorption Laboratory

2009-12-15T23:59:59.000Z

412

Apparatus and method for pulsed laser deposition of materials on wires and pipes  

DOE Patents [OSTI]

Methods and apparatuses are disclosed which allow uniform coatings to be applied by pulsed laser deposition (PLD) on inner and outer surfaces of cylindrical objects, such as rods, pipes, tubes, and wires. The use of PLD makes this technique particularly suitable for complex multicomponent materials, such as superconducting ceramics. Rigid objects of any length, i.e., pipes up to a few meters, and with diameters from less than 1 centimeter to over 10 centimeters can be coated using this technique. Further, deposition is effected simultaneously onto an annular region of the pipe wall. This particular arrangement simplifies the apparatus, reduces film uniformity control difficulties, and can result in faster operation cycles. In addition, flexible wires of any length can be continuously coated using the disclosed invention.

Fernandez, Felix E. (Mayaguez, PR)

2003-01-01T23:59:59.000Z

413

Autoignition of gasoline surrogates mixtures at intermediate temperatures and high pressures  

SciTech Connect (OSTI)

Ignition times were determined in high-pressure shock-tube experiments for various stoichiometric mixtures of two multicomponent model fuels in air for the validation of ignition delay simulations based on chemical kinetic models. The fuel blends were n-heptane (18%)/isooctane (62%)/ethanol (20%) by liquid volume (14.5%/44.5%/41% by mole fraction) and n-heptane (20%)/toluene (45%)/isooctane (25%)/diisobutylene (10%) by liquid volume (17.5%/55%/19.5%/8.0% by mole fraction). These fuels have octane numbers comparable to a standard European gasoline of 95 RON and 85 MON. The experimental conditions cover temperatures from 690 to 1200 K and pressures at 10, 30, and 50 bar. The obtained ignition time data are scaled with respect to pressure and compared to previous results reported in the literature. (author)

Fikri, M.; Herzler, J.; Starke, R.; Schulz, C.; Roth, P. [IVG, Universitaet Duisburg-Essen, D-47048 Duisburg (Germany); Kalghatgi, G.T. [Shell Global Solutions U.K., P.O. Box 1, Chester CH1 3SH (United Kingdom)

2008-01-15T23:59:59.000Z

414

Fluozirconate glass with low improper scattering on the phase microimpurities  

SciTech Connect (OSTI)

Multicomponent fluozirconate glass is transparent in the 0.5-5.5 {mu}m range, the transparency maximum being at 2.55 {mu}m. It is used as an active medium of solid state lasers, fiber lasers, and amplifiers in the visible and IR region of transformers of IR-radiation into visible radiation (green, red, etc.). The Faraday rotation was found in fluoride glasses containing rare-earth elements, lead, manganese, etc.. Fluoride light guides are used in devices for medical diagnostics, in surgery, anesthesia, etc.. A fluozirconate glass of the 52ZrF{sub 4}{center_dot}20BaF{sub 2}{center_dot}4LaF{sub 3}{center_dot}4AlF{sub 3}{center_dot}20NaF (mole %) composition with a calculated improper scattering of 5{center_dot}10{sup -6} dB/km at 2.6 {mu}m was synthesized.

Grishin, I.A.; Mityugova, V.N.; Tyutyaev, I.N.; Tseloval`nova, T.V.

1995-10-10T23:59:59.000Z

415

Neutron reactions in accreting neutron stars: a new pathway to efficient crust heating  

E-Print Network [OSTI]

In our calculation of neutron star crust heating we include several key new model features. In earlier work electron capture (EC) only allowed neutron emission from the daughter ground-state; here we calculate, in a deformed QRPA model, EC decay rates to all states in the daughter that are allowed by Gamow-Teller selection rules and energetics. The subsequent branching ratios between the 1n,...,xn channels and the competing $\\gamma$-decay are calculated in a Hauser-Feshbach model. Since EC accesses excited states, many more neutrons are emitted in our calculation than in previous work, leading to accelerated reaction flows. In our multi-component plasma model a single (EC,xn) reaction step can produce several neutron-deficient nuclei, each of which can further decay by (EC,xn). Hence, the neutron emission occurs more continuously with increasing depth as compared to that in a one-component plasma model.

Sanjib S. Gupta; Toshihiko Kawano; Peter Möller

2008-11-11T23:59:59.000Z

416

IUPAC-NIST Solubility Data Series. 100. Rare Earth Metal Fluorides in Water and Aqueous Systems. Part 1. Scandium Group (Sc, Y, La)  

SciTech Connect (OSTI)

This work presents an assessment of solubility data for rare earth metal fluorides (generally of trivalent metals and of CeF{sub 4}) in water and in aqueous ternary systems. Compilations of all available experimental data are introduced for each rare earth metal fluoride with a corresponding critical evaluation. Every such evaluation contains a collection of all solubility results in water, a selection of suggested solubility data, and a brief discussion of the multicomponent systems. Because the ternary systems were seldom studied more than once, no critical evaluations of such data were possible. Only simple fluorides (no complexes or binary salts) are treated as the input substances in this report. The literature has been covered through the end of 2013.

Mioduski, Tomasz [Institute of Nuclear Chemistry and Technology, 03195 Warsaw (Poland); Gumi?ski, Cezary, E-mail: cegie@chem.uw.edu.pl [Department of Chemistry, University of Warsaw, 02093 Warsaw (Poland); Zeng, Dewen, E-mail: dewen-zeng@hotmail.com [College of Chemistry and Chemical Engineering, Central South University, 410083 Changsha (China)

2014-03-15T23:59:59.000Z

417

Functional Wigner representation of quantum dynamics of Bose-Einstein condensate  

SciTech Connect (OSTI)

We develop a method of simulating the full quantum field dynamics of multi-mode multi-component Bose-Einstein condensates in a trap. We use the truncated Wigner representation to obtain a probabilistic theory that can be sampled. This method produces c-number stochastic equations which may be solved using conventional stochastic methods. The technique is valid for large mode occupation numbers. We give a detailed derivation of methods of functional Wigner representation appropriate for quantum fields. Our approach describes spatial evolution of spinor components and properly accounts for nonlinear losses. Such techniques are applicable to calculating the leading quantum corrections, including effects such as quantum squeezing, entanglement, EPR correlations, and interactions with engineered nonlinear reservoirs. By using a consistent expansion in the inverse density, we are able to explain an inconsistency in the nonlinear loss equations found by earlier authors.

Opanchuk, B.; Drummond, P. D. [Centre for Atom Optics and Ultrafast Spectroscopy, Swinburne University of Technology, Hawthorn VIC 3122 (Australia)] [Centre for Atom Optics and Ultrafast Spectroscopy, Swinburne University of Technology, Hawthorn VIC 3122 (Australia)

2013-04-15T23:59:59.000Z

418

Progress toward bridging from atomistic to continuum modeling to predict nuclear waste glass dissolution.  

SciTech Connect (OSTI)

This report summarizes research performed for the Nuclear Energy Advanced Modeling and Simulation (NEAMS) Subcontinuum and Upscaling Task. The work conducted focused on developing a roadmap to include molecular scale, mechanistic information in continuum-scale models of nuclear waste glass dissolution. This information is derived from molecular-scale modeling efforts that are validated through comparison with experimental data. In addition to developing a master plan to incorporate a subcontinuum mechanistic understanding of glass dissolution into continuum models, methods were developed to generate constitutive dissolution rate expressions from quantum calculations, force field models were selected to generate multicomponent glass structures and gel layers, classical molecular modeling was used to study diffusion through nanopores analogous to those in the interfacial gel layer, and a micro-continuum model (K{mu}C) was developed to study coupled diffusion and reaction at the glass-gel-solution interface.

Zapol, Peter (Argonne National Laboratory, Argonne, IL); Bourg, Ian (Lawrence Berkeley National Laboratories, Berkeley, CA); Criscenti, Louise Jacqueline; Steefel, Carl I. (Lawrence Berkeley National Laboratories, Berkeley, CA); Schultz, Peter Andrew

2011-10-01T23:59:59.000Z

419

FTIR microspectroscopy of polymeric systems  

E-Print Network [OSTI]

Fourier transform infrared (FTIR) spectroscopy is a mature analytical technique employed to examine polymeric materials. With the coupling of an infrared interferometer to a microscope equipped with specialized detectors, FTIR spectroscopy has been employed widely to examine microscopic areas in polymers for the last twenty years. Following the emergence of instrumentation techniques that employ focal plane array (FPA) detectors, FTIR microspectroscopy has experienced a recent renaissance in terms of the capability of instru-mentation and visualization afforded for examining multicomponent polymer systems. We present an overview of the principles of instrumental configurations used to achieve spatially resolved spectral information, their relative advantages and limitations. Illustrative examples are presented that demonstrate the capabilities of FTIR microspectroscopy and the insight this technique provides into the composition, formation, and behavior of polymeric materials. Fi-nally, some emerging techniques that may permit microspectroscopic analyses on a different

Rohit Bhargava; Shi-qing Wang; Jack L. Koenig

420

Improved recovery demonstration for Williston basin carbonates. Quarterly technical progress report, October 1, 1995--December 31, 1995  

SciTech Connect (OSTI)

The purpose of this project is to demonstrate targeted infill and extension drilling opportunities, better determinations of oil-in-place, methods for improved completion efficiency and the suitability of waterflooding in certain shallow-shelf carbonate reservoirs in the Williston Basin, Montana, North Dakota and South Dakota. Improved reservoir characterization utilizing 3-dimensional and multi-component seismic area is being investigated for identification of structural and stratigraphic reservoir compartments. These seismic characterization tools are integrated with geological and engineering studies. Improved completion efficiency is being tested with extended-reach jetting lance and other ultra-short radius lateral technologies. Improved completion efficiency, additional wells at closer spacing and better estimates of oil-in-place will result in additional oil production by primary and enhanced recovery processes.

NONE

1996-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Improved recovery demonstration for Williston basin carbonates. Annual report, June 10, 1994--June 9, 1995  

SciTech Connect (OSTI)

The purpose of this project is to demonstrate targeted infill and extension drilling opportunities, better determinations of oil-in-place, methods for improved completion efficiency and the suitability of waterflooding in Red River and Ratcliffe shallow-shelf carbonate reservoirs in the Williston Basin, Montana, North Dakota and South Dakota. Improved reservoir characterization utilizing three-dimensional and multi-component seismic are being investigated for identification of structural and stratigraphic reservoir compartments. These seismic characterization tools are integrated with geological and engineering studies. Improved completion efficiency is being tested with extended-reach jetting lance and other ultra-short-radius lateral technologies. Improved completion efficiency, additional wells at closer spacing and better estimates of oil in place will result in additional oil recovery by primary and enhanced recovery processes.

Sippel, M.; Zinke, S.; Magruder, G.; Eby, D.

1995-09-01T23:59:59.000Z

422

Improved recovery demonstration for Williston Basin carbonates. Quarterly report, July 1 - September 30, 1996  

SciTech Connect (OSTI)

The purpose of this project is to demonstrate targeted infill and extension drilling opportunities, better determinations of oil-in- place, methods for improved completion efficiency and the suitability of waterflooding in certain shallow-shelf carbonate reservoirs in the Williston Basin, Montana, North Dakota and South Dakota. Improved reservoir characterization utilizing 3-dimensional (3D) and multi-component seismic are being investigated for identification of structural and stratigraphic reservoir compartments. Field demonstrations are in progress to collect data for evaluation of horizontal completions in both the Red River and Ratcliffe. A vertical well in the Red River will test attribute analysis of 3D seismic data for prediction of porosity development. Additional seismic acquisitions and interpretation are in progress for both the Ratcliffe and Red River. A water-injectivity test in a new horizontal completion in the Red Rive B zone at Buffalo Field is scheduled for next quarter.

Carrell, L.A.

1996-12-31T23:59:59.000Z

423

Improved Recovery Demonstration for Williston Basin Carbonates.  

SciTech Connect (OSTI)

The purpose of this project is to demonstrate targeted infill and extension drilling opportunities, better determinations of oil-in- place, methods for improved completion efficiency and the suitability of waterflooding in certain shallow-shelf carbonate reservoirs in the Williston Basin, Montana, North Dakota and South Dakota. Improved reservoir characterization utilizing 3-dimensional (3-D) and multi-component seismic are being investigated for identification of structural and stratigraphic reservoir compartments. These seismic characterization tools are integrated with geological and engineering studies. Improved completion efficiency is being tested with short-lateral and horizontal drilling technologies. Improved completion efficiency, additional wells at closer spacing and better estimate of oil-in-place will result in additional oil production by primary and enhanced recovery processes.

NONE

1997-12-31T23:59:59.000Z

424

Improved recovery demonstration for Williston Basin carbonates. Quarterly report, January 1, 1996--March 31, 1996  

SciTech Connect (OSTI)

The purpose of this project is to demonstrate targeted infill and extension drilling opportunities, better determinations of oil-in- place, methods for improved completion efficiency and the suitability of waterflooding in certain shallow-shelf carbonate reservoirs in the Williston Basin, Montana, North Dakota and South Dakota. Improved reservoir characterization utilizing 3-dimensional and multi-component seismic area is being investigated for identification of structural and stratigraphic reservoir compartments. These seismic characterization tools are integrated with geological and engineering studies. Improved completion efficiency is being tested with extended- reach jetting lance and other ultra-short radius lateral technologies. Improved completion efficiency, additional wells at closer spacings better estimates of oil-in-place will result in additional oil production by primary and enhanced recovery processes. Technical progress is described for field demonstrations at the Ratcliffe and Buffalo fields and geophysical evaluations at Ratcliffe and Red River.

NONE

1996-07-01T23:59:59.000Z

425

Improved recovery demonstration for Williston Basin carbonates. Quarterly technical progress report, October--December 1996  

SciTech Connect (OSTI)

The purpose of this project is to demonstrate targeted infill and extension drilling opportunities, better determinations of oil-in-place, methods for improved completion efficiency and the suitability of waterflooding in certain shallow-shelf carbonate reservoirs in the Williston Basin, Montana, North Dakota and South Dakota. Improved reservoir characterization utilizing 3-dimensional (3D) and multi-component seismic are being investigated for identification of structural and stratigraphic reservoir compartments. These seismic characterization tools are integrated with geological and engineering studies. Improved completion efficiency is being tested with short-lateral and horizontal drilling technologies. Improved completion efficiency, additional wells at closer spacing and better estimates of oil-in-place will result in additional oil production by primary and enhanced recovery processes.

Sippel, M.A.; Carrell, L.A.

1997-04-01T23:59:59.000Z

426

Improved recovery demonstration for Williston Basin carbonates. Annual report, June 10, 1995--June 9, 1996  

SciTech Connect (OSTI)

The purpose of this project is to demonstrate targeted infill and extension drilling opportunities, better determinations of oil-in-place, methods for improved completion efficiency and the suitability of waterflooding in Red River and Ratcliffe shallow-shelf carbonate reservoirs in the Williston Basin, Montana, North Dakota and South Dakota. Improved reservoir characterization utilizing three-dimensional and multi-component seismic are being investigated for identification of structural and stratigraphic reservoir compartments. These seismic characterization tools are integrated with geological and engineering studies. Improved completion efficiency is being tested with extended-reach jetting lance and other ultra-short-radius lateral technologies. Improved completion efficiency, additional wells at closer spacing and better estimates of oil in place will result in additional oil recovery by primary and enhanced recovery processes.

Carrell, L.A.; Sippel, M.A.

1996-09-01T23:59:59.000Z

427

Scale-up of miscible flood processes for heterogeneous reservoirs. Quarterly report, April 1--June 30, 1995  

SciTech Connect (OSTI)

The current project is a systematic research effort aimed at quantifying relationships between process mechanisms that can lead to improved recovery from gas injection processes performed in heterogeneous Class 1 and Class 2 reservoirs. It will provide a rational basis for the design of displacement processes that take advantage of crossflow due to capillary, gravity and viscous forces to offset partially the adverse effects of heterogeneity. In effect, the high permeability zones are used to deliver fluid by crossflow to zones that would otherwise be flooded only very slowly. Thus, the research effort is divided into five areas: Development of miscibility in multicomponent systems; Design estimates for nearly miscible displacements; Design of miscible floods for fractured reservoirs; Compositional flow visualization experiments; Simulation of near-miscible flow in heterogeneous systems The status of the research effort in each area is reviewed briefly in the following section.

Orr, F.M. Jr.

1995-06-01T23:59:59.000Z

428

Scale-up of miscible flood processes for heterogeneous reservoirs. Quarterly report, July 1, 1995--September 30, 1995  

SciTech Connect (OSTI)

The current project is a systematic research effort aimed at quantifying relationships between process mechanisms that can lead to improved recovery from gas injection processes performed in heterogeneous Class 1 and Class 2 reservoirs. It will provide a rational basis for the design of displacement processes that take advantage of crossflow due to capillary, gravity and viscous forces to offset partially the adverse effects of heterogeneity. In effect, the high permeability zones are used to deliver fluid by crossflow to zones that would otherwise be flooded only very slowly. Thus, the research effort is divided into five areas: Development of miscibility in multicomponent systems; Design estimates for nearly miscible displacements; Design of miscible floods for fractured reservoirs; Compositional flow visualization experiments; and Simulation of near-miscible flow in heterogeneous systems. The status of the research effort in each area is reviewed briefly in the following section.

Orr, F.M. Jr.

1995-10-01T23:59:59.000Z

429

Two Component Model of Dark Energy  

E-Print Network [OSTI]

We consider the possibility that the dark energy is made up of two or more independent components, each having a different equation of state. We fit the model with supernova and gamma-ray burst (GRB) data from resent observations, and use the Markov Chain Monte Carlo (MCMC) technique to estimate the allowed parameter regions. We also use various model selection criteria to compare the two component model with the LCDM, one component dark energy model with static or variable w(XCDM), and with other multi-component models. We find that the two component models can give reasonably good fit to the current data. For some data sets, and depending somewhat on the model selection criteria, the two component model can give better fit to the data than XCDM with static w and XCDM with variable w parameterized by w = w_0 + w_az/(1+z).

Yan Gong; Xuelei Chen

2007-10-18T23:59:59.000Z

430

Astrophysics Simulations from the ASC/Alliances Center for Astrophysical Thermonuclear Flashes  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

The "Flash Center" works to solve the long-standing problem of thermonuclear flashes on the surfaces of compact stars such as neutron stars and white dwarfs, and in the interior of white dwarfs (i.e., Type I supernovae). The physical conditions, and many of the physical phenomena, are similar to those confronted by the Department of Energy Stockpile Stewardship program. The (fully ionized) plasmas are at very high temperatures and densities; and the physical problems of nuclear ignition, deflagration or detonation, turbulent mixing, and interface dynamics for complex multicomponent fluids are common to the weapons program. Because virtually every aspect of this problem represents a computational Grand Challenge, large-scale numerical simulations are at the heart of its resolution (Taken from Executive Summary page). More than 35 simulations and computer animations developed through research at the "Flash Center" are available here. Each .avi or .mov file also references the related research paper or presentation and provides a link.

431

Alternative barrier layers for surface covers in dry climates  

SciTech Connect (OSTI)

Surface covers are one of the most widespread remediation and waste management options in all climates. Barrier layers to limit percolation through cover systems are principal features of engineered, multi-component cover designs. Conventional barrier layer components developed for humid climates have limitations in dry climates. One alternative barrier layer is a capillary barrier, which consists of a fine-over-coarse soil arrangement. The capacity of capillary barrier to laterally divert downward moving water is the key to their success. Another alternative is a dry barrier, in which atmospheric air is circulated through a coarse layer within the cover to remove water vapor. Incorporating a coarse layer which stores water for subsequent removal by air flow reduces the requirements for the air flow velocity and increases the applicability of the dry barrier.

Stormont, J.C.

1994-09-01T23:59:59.000Z

432

Sailfish: a flexible multi-GPU implementation of the lattice Boltzmann method  

E-Print Network [OSTI]

We present Sailfish, an open source fluid simulation package implementing the lattice Boltzmann method (LBM) on modern Graphics Processing Units (GPUs) using CUDA/OpenCL. We take a novel approach to GPU code implementation and use run-time code generation techniques and a high level programming language (Python) to achieve state of the art performance, while allowing easy experimentation with different LBM models and tuning for various types of hardware. We discuss the general design principles of the code, scaling to multiple GPUs in a distributed environment, as well as the GPU implementation and optimization of many different LBM models, both single component (BGK, MRT, ELBM) and multicomponent (Shan-Chen, free energy). The paper also presents results of performance benchmarks spanning the last three NVIDIA GPU generations (Tesla, Fermi, Kepler), which we hope will be useful for researchers working with this type of hardware and similar codes.

Januszewski, Michal

2013-01-01T23:59:59.000Z

433

Recent Results of the Hadron Resonance Gas Model and the Chemical Freeze-out of Strange Hadrons  

E-Print Network [OSTI]

A detailed discussion of recent results obtained within the hadron resonance gas model with the multi-component hard core repulsion is presented. Among them there are the adiabatic chemical freeze-out criterion, the concept of separate chemical freeze-out of strange particles and the effects of enhancement and sharpening of wide resonances and quark gluon bags occurring in a thermal medium. These findings are discussed in order to strengthen the planned heavy-ion collision experimental programs at low collision energies. We argue, that due to found effects, at the center of mass collision energy 4-8 GeV the quark gluon bags may appear directly or in decays as new heavy resonances with the narrow width of about 50-150 MeV and with the mass above 2.5 GeV.

Bugaev, K A; Oliinychenko, D R; Nikonov, E G; Sagun, V V; Zinovjev, G M

2014-01-01T23:59:59.000Z

434

Handbook of gas hydrate properties and occurrence  

SciTech Connect (OSTI)

This handbook provides data on the resource potential of naturally occurring hydrates, the properties that are needed to evaluate their recovery, and their production potential. The first two chapters give data on the naturally occurring hydrate potential by reviewing published resource estimates and the known and inferred occurrences. The third and fourth chapters review the physical and thermodynamic properties of hydrates, respectively. The thermodynamic properties of hydrates that are discussed include dissociation energies and a simplified method to calculate them; phase diagrams for simple and multi-component gases; the thermal conductivity; and the kinetics of hydrate dissociation. The final chapter evaluates the net energy balance of recovering hydrates and shows that a substantial positive energy balance can theoretically be achieved. The Appendices of the Handbook summarize physical and thermodynamic properties of gases, liquids and solids that can be used in designing and evaluating recovery processes of hydrates. 158 references, 67 figures, 47 tables.

Kuustraa, V.A.; Hammershaimb, E.C.

1983-12-01T23:59:59.000Z

435

Gaseous insulators for high voltage electrical equipment  

DOE Patents [OSTI]

Gaseous insulators comprise compounds having high attachment cross sections for electrons having energies in the 0-1.3 electron volt range. Multi-component gaseous insulators comprise compounds and mixtures having overall high electron attachment cross sections in the 0-1.3 electron volt range and moderating gases having high cross sections for inelastic interactions with electrons of energies 1-4 electron volts. Suitable electron attachment components include hexafluorobutyne, perfluorobutene-2, perfluorocyclobutane, perfluorodimethylcyclobutane, perfluorocyclohexene, perfluoromethylcyclohexane, hexafluorobutadiene, perfluoroheptene-1 and hexafluoroazomethane. Suitable moderating gases include N.sub.2, CO, CO.sub.2 and H.sub.2. The gaseous insulating mixture can also contain SF.sub.6, perfluoropropane and perfluorobenzene.

Christophorou, Loucas G. (Oak Ridge, TN); James, David R. (Knoxville, TN); Pace, Marshall O. (Knoxville, TN); Pai, Robert Y. (Concord, TN)

1981-01-01T23:59:59.000Z

436

Theoretical investigation of the effect of hydrogen addition on the formation and properties of soliton in direct current argon plasma  

SciTech Connect (OSTI)

In this study the effect of hydrogen addition on the formation and properties of soliton in direct-current (DC) argon plasma is theoretically investigated. By coupling fluid equations with Poisons equation for such multi-component plasma, the Mach number and amplitude of the soliton are determined following pseudo potential method. Addition of hydrogen in argon discharge leads to the decrease of electron, Ar{sup +} ion density while a reverse trend was observed for ArH{sup +} and hydrogen like ions. It was found that presence of hydrogen like ions in argon plasma affects the formation of soliton with its amplitude significantly decreases as concentration of hydrogen increases. On the other hand, increase in ion to electron temperature ratios of the lighter ions in the discharge also has a significant influence on the amplitude and formation of soliton. The inverse relation between solitons width and amplitude is found to be consistent for the entire range of study.

Saikia, P., E-mail: partha.008@gmail.com; Goswami, K. S.; Saikia, B. K. [Centre of Plasma Physics, Institute for Plasma Research, Nazirakhat, Sonapur, Kamrup, Assam-782 402 (India)] [Centre of Plasma Physics, Institute for Plasma Research, Nazirakhat, Sonapur, Kamrup, Assam-782 402 (India)

2014-03-15T23:59:59.000Z

437

The positive ion temperature effect in magnetized electronegative plasma sheath with two species of positive ions  

SciTech Connect (OSTI)

The properties of a magnetized multi-component (two species of positive ions, negative ions and electrons) plasma sheath with finite positive ion temperature are studied. By using three fluid hydrodynamic model and some dimensionless variables, the ion (both lighter and heavier positive ions, and negative ions) densities, the ion (only for positive ions) velocities, and electric potential inside the sheath are investigated. In addition, the absence and presence of magnetic field and the orientation of magnetic field are considered. It is noticed that, with increase of positive ion temperature, the lighter positive ion density peaks increase only at the sheath edge and shift towards the sheath edge for both absence and presence of magnetic field. For heavier positive ions, in the absence of magnetic field, the density peaks increase at the sheath edge. But in the presence of magnetic field, the density fluctuations increase at the sheath edge. For both the cases, the density peaks shift towards the sheath edge.

Shaw, A. K. [Centre of Plasma Physics, Institute for Plasma Research, Sonapur-782 402, Guwahati, Assam (India); Institute for Plasma Research, Bhat, Gandhinagar-382 428, Gujarat (India); Kar, S. [Institute for Plasma Research, Bhat, Gandhinagar-382 428, Gujarat (India); Goswami, K. S. [Centre of Plasma Physics, Institute for Plasma Research, Sonapur-782 402, Guwahati, Assam (India)

2012-10-15T23:59:59.000Z

438

Coulomb crystal mass spectrometry in a digital ion trap  

E-Print Network [OSTI]

We present a mass spectrometric technique for identifying the masses and relative abundances of Coulomb-crystallized ions held in a linear Paul trap. A digital radiofrequency waveform is employed to generate the trapping potential, as this can be cleanly switched off, and static dipolar fields subsequently applied to the trap electrodes for ion ejection. Excellent detection efficiency is demonstrated for Ca+ and CaF+ ions from bi-component Ca+/CaF+ Coulomb crystals prepared by reaction of Ca+ with CH3F. A quantitative linear relationship is observed between ion number and the corresponding integrated TOF peak, independent of the ionic species. The technique is applicable to a diverse range of multi-component Coulomb crystals - demonstrated here for Ca+/NH3+/NH4+ and Ca+/CaOH+/CaOD+ crystals - and will facilitate the measurement of ion-molecule reaction rates and branching ratios in complicated reaction systems.

Deb, Nabanita; Smith, Alexander D; Keller, Matthias; Rennick, Christopher J; Heazlewood, Brianna R; Softley, Timothy P

2015-01-01T23:59:59.000Z

439

Optical computing with soliton trains in Bose-Einstein condensates  

E-Print Network [OSTI]

Optical computing devices can be implemented based on controlled generation of soliton trains in single and multicomponent Bose-Einstein condensates (BEC). Our concepts utilize the phenomenon that the frequency of soliton trains in BEC can be governed by changing interactions within the atom cloud. We use this property to store numbers in terms of those frequencies for a short time until observation. The properties of soliton trains can be changed in an intended way by other components of BEC occupying comparable states or via phase engineering. We elucidate in which sense such an additional degree of freedom can be regarded as a tool for controlled manipulation of data. Finally the outcome of any manipulation made is read out by observing the signature within the density profile.

Florian Pinsker

2014-11-18T23:59:59.000Z

440

Solubilities of p-quinone and 9,10-anthraquinone in supercritical carbon dioxide  

SciTech Connect (OSTI)

Equilibrium solubilities of p-quinone (1,4-benzoquinone) and 9,10-anthraquinone at 35 C and 45 C in supercritical carbon dioxide over a pressure range of about (85--300) bar have been measured using a supercritical fluid extractor coupled with a high-pressure liquid chromatography apparatus. The solubility results, along with those reported in the literature for 1,4-naphthoquinone, are correlated with a modified Peng-Robinson equation of state. The ability of a supercritical fluid to separate a multicomponent mixture is unique, since it utilizes the salient features of both distillation and liquid extraction. The solubility of a solute in a supercritical fluid is the most important thermophysical property that has to be determined and modeled for an efficient design of any extraction based on supercritical solvents.

Coutsikos, P.; Magoulas, K.; Tassios, D. [National Technical Univ. of Athens (Greece)] [National Technical Univ. of Athens (Greece)

1997-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Synergetic effects of II-VI sensitization upon TiO{sub 2} for photoelectrochemical water splitting; a tri-layered structured scheme  

SciTech Connect (OSTI)

World's energy demands are growing on a higher scale increasing the need of more reliable and long term renewable energy resources. Efficient photo-electrochemical (PEC) devices based on novel nano-structured designs for solar-hydrogen generation need to be developed. This study provides an insight of the tri-layered-TiO2 based nanostructures. Observing the mechanism of hydrogen production, the comparison of the structural order during the synthesis is pronounced. The sequence in the tri-layered structure affects the photogenerated electron (e{sup ?}) and hole (h{sup +}) pair transfer and separation. It is also discussed that not only the semiconductors band gaps alignment is important with respect to the water redox potential but also the interfacial regions. Quasi-Fermi-level adjustment at the interfacial regions plays a key role in deciding the solar to hydrogen efficiency. More efficient multicomponent semiconductor nano-design (MCSN) could be developed with the approach given in this study.

Mumtaz, Asad, E-mail: asad-032@yahoo.com [Department of Fundamental and Applied Sciences, University Teknologi PETRONAS (Malaysia); Mohamed, Norani Muti, E-mail: noranimuti-mohamed@petronas.com.my [Centre of Innovative Nanostructures and Nanodevices (COINN), Universiti Teknologi PETRONAS (Malaysia)

2014-10-24T23:59:59.000Z

442

TOUGH2: A general-purpose numerical simulator for multiphase nonisothermal flows  

SciTech Connect (OSTI)

Numerical simulators for multiphase fluid and heat flows in permeable media have been under development at Lawrence Berkeley Laboratory for more than 10 yr. Real geofluids contain noncondensible gases and dissolved solids in addition to water, and the desire to model such `compositional` systems led to the development of a flexible multicomponent, multiphase simulation architecture known as MULKOM. The design of MULKOM was based on the recognition that the mass-and energy-balance equations for multiphase fluid and heat flows in multicomponent systems have the same mathematical form, regardless of the number and nature of fluid components and phases present. Application of MULKOM to different fluid mixtures, such as water and air, or water, oil, and gas, is possible by means of appropriate `equation-of-state` (EOS) modules, which provide all thermophysical and transport parameters of the fluid mixture and the permeable medium as a function of a suitable set of primary thermodynamic variables. Investigations of thermal and hydrologic effects from emplacement of heat-generating nuclear wastes into partially water-saturated formations prompted the development and release of a specialized version of MULKOM for nonisothermal flow of water and air, named TOUGH. TOUGH is an acronym for `transport of unsaturated groundwater and heat` and is also an allusion to the tuff formations at Yucca Mountain, Nevada. The TOUGH2 code is intended to supersede TOUGH. It offers all the capabilities of TOUGH and includes a considerably more general subset of MULKOM modules with added capabilities. The paper briefly describes the simulation methodology and user features.

Pruess, K. [Lawrence Berkeley Lab., CA (United States)

1991-06-01T23:59:59.000Z

443

TRANSPORT AND PHASE EQUILIBRIA PROPERITIES FOR STEAM FLOODING OF HEAVY OILS  

SciTech Connect (OSTI)

Hydrocarbon/water and CO{sub 2} systems are frequently found in petroleum recovery processes, petroleum refining, and gasification of coals, lignites and tar sands. Techniques to estimate the phase volume and phase composition are indispensable to design and improve oil recovery processes such as steam, hot water, or CO{sub 2}/steam combinations of flooding techniques typically used for heavy oils. An interdisciplinary research program to quantify transport, PVT, and equilibrium properties of selected oil/CO{sub 2}/water mixtures at pressures up to 10,000 psia and at temperatures up to 500 F has been put in place. The objectives of this research include experimental determination and rigorous modeling and computation of phase equilibrium diagrams, and volumetric properties of hydrocarbon/CO{sub 2}/water mixtures at pressures and temperatures typical of steam injection processes for thermal recovery of heavy oils. Highlighting the importance of phase behavior, researchers ([1], and [2]) insist on obtaining truly representative reservoir fluids samples for experimental analysis. The prevailing sampling techniques used for compositional analysis of the fluids have potential for a large source of error. These techniques bring the sample to atmospheric conditions and collect the liquid and vapor portion of the samples for further analysis. We developed a new experimental technique to determine phase volumes, compositions and equilibrium K-values at reservoir conditions. The new methodology is able to measure phase volume and composition at reservoir like temperatures and pressures. We use a mercury free PVT system in conjunction with a Hewlett Packard gas chromatograph capable of measuring compositions on line at high pressures and temperatures. This is made possible by an essentially negligible disturbance of the temperature and pressure equilibrium during phase volume and composition measurements. In addition, not many samples are withdrawn for compositional analysis because a negligible volume (0.1 {micro}l to 0.5 {micro}l) is sent directly to the gas chromatograph through sampling valves. These amounts are less than 1 x 10{sup -5} % of total volume and do not affect the overall composition or equilibrium of the system. A new method to compute multi-component phase equilibrium diagrams based on an improved version of the Peng-Robinson equation has been developed [3]. This new version of the Peng-Robinson equation uses a new volume translation scheme and new mixing rules to improve the accuracy of the calculations. Calculations involving multicomponent mixtures of CO{sub 2}/water and hydrocarbons have been completed. A scheme to lump multi-component materials such as, oils into a small set of ''pseudo-components'' according to the technique outlined by Whitson [4] has been implemented. This final report presents the results of our experimental and predicted phase behavior diagrams and calculations for mixtures of CO{sub 2}/water and real oils at high pressures and temperatures.

Jorge Gabitto; Maria Barrufet

2002-09-01T23:59:59.000Z

444

SHEAR WAVE SEISMIC STUDY COMPARING 9C3D SV AND SH IMAGES WITH 3C3D C-WAVE IMAGES  

SciTech Connect (OSTI)

The objective of this study was to compare the relative merits of shear-wave (S-wave) seismic data acquired with nine-component (9-C) technology and with three-component (3-C) technology. The original proposal was written as if the investigation would be restricted to a single 9-C seismic survey in southwest Kansas (the Ashland survey), on the basis of the assumption that both 9-C and 3-C S-wave images could be created from that one data set. The Ashland survey was designed as a 9-C seismic program. We found that although the acquisition geometry was adequate for 9-C data analysis, the source-receiver geometry did not allow 3-C data to be extracted on an equitable and competitive basis with 9-C data. To do a fair assessment of the relative value of 9-C and 3-C seismic S-wave data, we expanded the study beyond the Ashland survey and included multicomponent seismic data from surveys done in a variety of basins. These additional data were made available through the Bureau of Economic Geology, our research subcontractor. Bureau scientists have added theoretical analyses to this report that provide valuable insights into several key distinctions between 9-C and 3-C seismic data. These theoretical considerations about distinctions between 3-C and 9-C S-wave data are presented first, followed by a discussion of differences between processing 9-C common-midpoint data and 3-C common-conversion-point data. Examples of 9-C and 3-C data are illustrated and discussed in the last part of the report. The key findings of this study are that each S-wave mode (SH-SH, SV-SV, or PSV) involves a different subsurface illumination pattern and a different reflectivity behavior and that each mode senses a different Earth fabric along its propagation path because of the unique orientation of its particle-displacement vector. As a result of the distinct orientation of each mode's particle-displacement vector, one mode may react to a critical geologic condition in a more optimal way than do the other modes. A conclusion of the study is that 9-C seismic data contain more rock and fluid information and more sequence and facies information than do 3-C seismic data; 9-C data should therefore be acquired in multicomponent seismic programs whenever possible.

John Beecherl; Bob A. Hardage

2004-07-01T23:59:59.000Z

445

Recent Progress in the Development of Diesel Surrogate Fuels  

SciTech Connect (OSTI)

There has been much recent progress in the area of surrogate fuels for diesel. In the last few years, experiments and modeling have been performed on higher molecular weight components of relevance to diesel fuel such as n-hexadecane (n-cetane) and 2,2,4,4,6,8,8-heptamethylnonane (iso-cetane). Chemical kinetic models have been developed for all the n-alkanes up to 16 carbon atoms. Also, there has been much experimental and modeling work on lower molecular weight surrogate components such as n-decane and do-decane which are most relevant to jet fuel surrogates, but are also relevant to diesel surrogates where simulation of the full boiling point range is desired. For the cycloalkanes, experimental work on decalin and tetralin recently has been published. For multi-component surrogate fuel mixtures, recent work on modeling of these mixtures and comparisons to real diesel fuel is reviewed. Detailed chemical kinetic models for surrogate fuels are very large in size. Significant progress also has been made in improving the mechanism reduction tools that are needed to make these large models practicable in multidimensional reacting flow simulations of diesel combustion. Nevertheless, major research gaps remain. In the case of iso-alkanes, there are experiments and modeling work on only one of relevance to diesel: iso-cetane. Also, the iso-alkanes in diesel are lightly branched and no detailed chemical kinetic models or experimental investigations are available for such compounds. More components are needed to fill out the iso-alkane boiling point range. For the aromatic class of compounds, there has been no new work for compounds in the boiling point range of diesel. Most of the new work has been on alkyl aromatics that are of the range C7 to C8, below the C10 to C20 range that is needed. For the chemical class of cycloalkanes, experiments and modeling on higher molecular weight components are warranted. Finally for multi-component surrogates needed to treat real diesel, the inclusion of higher molecular weight components is needed in models and experimental investigations.

Pitz, W J

2009-09-04T23:59:59.000Z

446

Recent Progress in the Development of Diesel Surrogate Fuels  

SciTech Connect (OSTI)

There has been much recent progress in the area of surrogate fuels for diesel. In the last few years, experiments and modeling have been performed on higher molecular weight components of relevance to diesel fuel such as n-hexadecane (n-cetane) and 2,2,4,4,6,8,8-heptamethylnonane (iso-cetane). Chemical kinetic models have been developed for all the n-alkanes up to 16 carbon atoms. Also, there has been much experimental and modeling work on lower molecular weight surrogate components such as n-decane and n-dodecane that are most relevant to jet fuel surrogates, but are also relevant to diesel surrogates where simulation of the full boiling point range is desired. For two-ring compounds, experimental work on decalin and tetralin recently has been published. For multi-component surrogate fuel mixtures, recent work on modeling of these mixtures and comparisons to real diesel fuel is reviewed. Detailed chemical kinetic models for surrogate fuels are very large in size. Significant progress also has been made in improving the mechanism reduction tools that are needed to make these large models practicable in multi-dimensional reacting flow simulations of diesel combustion. Nevertheless, major research gaps remain. In the case of iso-alkanes, there are experiments and modeling work on only one of relevance to diesel: iso-cetane. Also, the iso-alkanes in diesel are lightly branched and no detailed chemical kinetic models or experimental investigations are available for such compounds. More components are needed to fill out the iso-alkane boiling point range. For the aromatic class of compounds, there has been no new work for compounds in the boiling point range of diesel. Most of the new work has been on alkyl aromatics that are of the range C7 to C8, below the C10 to C20 range that is needed. For the chemical class of cycloalkanes, experiments and modeling on higher molecular weight components are warranted. Finally for multi-component surrogates needed to treat real diesel, the inclusion of higher molecular weight components is needed in models and experimental investigations.

Pitz, W J; Mueller, C J

2009-12-09T23:59:59.000Z

447

Training toward Advanced 3D Seismic Methods for CO2 Monitoring, Verification, and Accounting  

SciTech Connect (OSTI)

The objective of our work is graduate and undergraduate student training related to improved 3D seismic technology that addresses key challenges related to monitoring movement and containment of CO{sub 2}, specifically better quantification and sensitivity for mapping of caprock integrity, fractures, and other potential leakage pathways. We utilize data and results developed through previous DOE-funded CO{sub 2} characterization project (DE-FG26-06NT42734) at the Dickman Field of Ness County, KS. Dickman is a type locality for the geology that will be encountered for CO{sub 2} sequestration projects from northern Oklahoma across the U.S. midcontinent to Indiana and Illinois. Since its discovery in 1962, the Dickman Field has produced about 1.7 million barrels of oil from porous Mississippian carbonates with a small structural closure at about 4400 ft drilling depth. Project data includes 3.3 square miles of 3D seismic data, 142 wells, with log, some core, and oil/water production data available. Only two wells penetrate the deep saline aquifer. In a previous DOE-funded project, geological and seismic data were integrated to create a geological property model and a flow simulation grid. We believe that sequestration of CO{sub 2} will largely occur in areas of relatively flat geology and simple near surface, similar to Dickman. The challenge is not complex geology, but development of improved, lower-cost methods for detecting natural fractures and subtle faults. Our project used numerical simulation to test methods of gathering multicomponent, full azimuth data ideal for this purpose. Our specific objectives were to apply advanced seismic methods to aide in quantifying reservoir properties and lateral continuity of CO{sub 2} sequestration targets. The purpose of the current project is graduate and undergraduate student training related to improved 3D seismic technology that addresses key challenges related to monitoring movement and containment of CO{sub 2}, specifically better quantification and sensitivity for mapping of caprock integrity, fractures, and other potential leakage pathways. Specifically, our focus is fundamental research on (1) innovative narrow-band seismic data decomposition and interpretation, and (2) numerical simulation of advanced seismic data (multi-component, high density, full azimuth data) ideal for mapping of cap rock integrity and potential leakage pathways.

Christopher Liner

2012-05-31T23:59:59.000Z

448

Numerical Simulations of Leakage from Underground LPG Storage Caverns  

SciTech Connect (OSTI)

To secure a stable supply of petroleum gas, underground storage caverns for liquified petroleum gas (LPG) are commonly used in many countries worldwide. Storing LPG in underground caverns requires that the surrounding rock mass remain saturated with groundwater and that the water pressure be higher than the liquid pressure inside the cavern. In previous studies, gas containment criteria for underground gas storage based on hydraulic gradient and pressure have been discussed, but these studies do not consider the physicochemical characteristics and behavior of LPG such as vaporization and dissolution in groundwater. Therefore, while these studies are very useful for designing storage caverns, they do not provide better understanding of the either the environmental effects of gas contamination or the behavior of vaporized LPG. In this study, we have performed three-phase fluid flow simulations of gas leakage from underground LPG storage caverns, using the multiphase multicomponent nonisothermal simulator TMVOC (Pruess and Battistelli, 2002), which is capable of solving the three-phase nonisothermal flow of water, gas, and a multicomponent mixture of volatile organic chemicals (VOCs) in multidimensional heterogeneous porous media. A two-dimensional cross-sectional model resembling an actual underground LPG facility in Japan was developed, and gas leakage phenomena were simulated for three different permeability models: (1) a homogeneous model, (2) a single-fault model, and (3) a heterogeneous model. In addition, the behavior of stored LPG was studied for the special case of a water curtain suddenly losing its function because of operational problems, or because of long-term effects such as clogging of boreholes. The results of the study indicate the following: (1) The water curtain system is a very powerful means for preventing gas leakage from underground storage facilities. By operating with appropriate pressure and layout, gas containment can be ensured. (2) However , in highly heterogeneous media such as fractured rock and fault zones, local flow paths within which the gas containment criterion is not satisfied could be formed. To eliminate such zones, treatments such as pre/post grouting or an additional installment of water-curtain boreholes are essential. (3) Along highly conductive features such as faults, even partially saturated zones possess certain effects that can retard or prevent gas leakage, while a fully unsaturated fault connected to the storage cavern can quickly cause a gas blowout. This possibility strongly suggests that ensuring water saturation of the rock surrounding the cavern is a very important requirement. (4) Even if an accident should suddenly impair the water curtain, the gas plume does not quickly penetrate the ground surface. In these simulations, the plume takes several months to reach the ground surface.

Yamamoto, Hajime; Pruess, Karsten

2004-09-01T23:59:59.000Z

449

Nanoimaging to Prevent and Treat Alzheimer’s and Parkinson’s Diseases. Scientific/Technical report  

SciTech Connect (OSTI)

This project will develop innovative approaches to characterization of the very early stages of protein aggregation that eventually can be translated to the development of early diagnostic tools and efficient treatments for Alzheimer’s, Parkinson’s and Huntington’s diseases. Funding will be used to acquire nanoimaging technology for nanoscale imaging, manipulation and analysis of biomedical materials to develop treatments that will repair disabled proteins and cure diseases that result from protein malfunction, specifically Alzheimer’s and Parkinson’s diseases. Expected outcomes include tests for early diagnosis and therapeutic treatments for these devastating neurological diseases. To elucidate the mechanisms of protein misfolding, we will establish an extensive program of experimental studies using a broad arsenal of advanced nanoscale and traditional techniques that will be integrated with molecular-scale modeling of protein misfolding and the nucleation of aggregate structures. To identify intracellular machinery or/and multicomponent complexes critically involved in protein misfolding, we will characterize interactions between targeted proteins and specific intracellular components or metabolites that impact on protein conformational pathways leading to protein misfolding accompanied by formation of toxic aggregated morphologies. To design innovative nanotechnology tools for the control of intracellular protein misfolding and aggregation processes, we will develop a predictive molecular scale model for intracellular protein misfolding and the formation of toxic aggregates. Verified through experimental studies, the objective is to establish an enabling foundation for the engineering of novel molecular diagnostics and therapeutics for various cellular pathologies.

Yuri L. Lyubchenko, PhD, DSc

2012-12-20T23:59:59.000Z

450

Electro-diffusion in a plasma with two ion species  

SciTech Connect (OSTI)

Electric field is a thermodynamic force that can drive collisional inter-ion-species transport in a multicomponent plasma. In an inertial confinement fusion capsule, such transport causes fuel ion separation even with a target initially prepared to have equal number densities for the two fuel ion species. Unlike the baro-diffusion driven by ion pressure gradient and the thermo-diffusion driven by ion and electron temperature gradients, electro-diffusion has a critical dependence on the charge-to-mass ratio of the ion species. Specifically, it is shown here that electro-diffusion vanishes if the ion species have the same charge-to-mass ratio. An explicit expression for the electro-diffusion ratio is obtained and used to investigate the relative importance of electro- and baro-diffusion mechanisms. In particular, it is found that electro-diffusion reinforces baro-diffusion in the deuterium and tritium mix, but tends to cancel it in the deuterium and helium-3 mix.

Kagan, Grigory; Tang Xianzhu [Theoretical Division Los Alamos National Laboratory Los Alamos, New Mexico 87545 (United States)

2012-08-15T23:59:59.000Z

451

Three-particle cumulant Study of Conical Emission  

E-Print Network [OSTI]

We discuss the sensitivity of the three-particle azimuthal cumulant method for a search and study of conical emission in central relativistic $A+A $ collisions. Our study is based on a multi-component Monte Carlo model which include flow background, Gaussian mono-jets, jet-flow, and Gaussian conical signals. We find the observation of conical emission is hindered by the presence of flow harmonics of fourth order ($v_4 $) but remains feasible even in the presence of a substantial background. We consider the use of probability cumulants for the suppression of 2$^{nd}$ order flow harmonics. We find that while probability cumulant significantly reduce $v_2^2$ contributions, they also complicate the cumulant of jets, and conical emission. The use of probability cumulants is therefore not particularly advantageous in searches for conical emission. We find the sensitivity of the (density) cumulant method depends inextricably on strengths of $v_2 $, $v_4 $, background and non-Poisson character of particle production. It thus cannot be expressed in a simple form, and without specific assumptions about the values of these parameters.

Claude Pruneau

2009-01-07T23:59:59.000Z

452

Topological and AIM analyses beyond the Born-Oppenheimer paradigm: New opportunities  

E-Print Network [OSTI]

The multi-component quantum theory of atoms in molecules (MC-QTAIM) analysis is done on methane, ethylene, acetylene and benzene as selected basic hydrocarbons. This is the first report on applying the MC-QTAIM analysis on polyatomic species. In order to perform the MC-QTAIM analysis, at first step the nuclear-electronic orbital method at Hartree-Fock level (NEO-HF) is used as a non-Born-Oppenheimer (nBO) ab initio computational procedure assuming both electrons and protons as quantum waves while carbon nuclei as point charges in these systems. The ab initio calculations proceed substituting all the protons of each species first with deuterons and then tritons. At the next step, the derived nBO wavefunctions are used for the "atoms in molecules" (AIM) analysis. The results of topological analysis and integration of atomic properties demonstrate that the MC-QTAIM is capable of deciphering the underlying AIM structure of all the considered species. Also, the results of the analysis for each isotopic composition...

Goli, Mohammad

2014-01-01T23:59:59.000Z

453

Estimation of tracer diffusion coefficients of ions in aqueous solution  

SciTech Connect (OSTI)

Equations are given for estimating tracer diffusion coefficients D/sub i//sup 0/ of ions at infinite dilution in terms of limiting ionic conductances ..lambda../sub i//sup 0/. Also given are generalized Nernst-Hartley equations for binary and multicomponent diffusion coefficients D/sup 0/ and D/sub ij//sup 0/, respectively, at infinite dilution. Data, estimates, and correlations for ..lambda../sub i//sup 0/ at 25/sup 0/C and other temperatures are discussed. Estimated values of ..lambda../sub i//sup 0/ are tabulated from 0-300/sup 0/C for ions of waste isolation interest and for ions of economic interest in geothermal brines. Estimates of their tracer diffusion coefficients at infinite dilution are tabulated. A rule of thumb, good to a factor of 2, is presented. Very limited data (available only at 25/sup 0/C) indicate that D/sub i//D/sub i//sup 0/ generally declines as the concentration of salt or supporting electrolyte increases. 6 figures, 2 tables.

Miller, D.G.

1982-09-07T23:59:59.000Z

454

CALIBRATING C-IV-BASED BLACK HOLE MASS ESTIMATORS  

SciTech Connect (OSTI)

We present the single-epoch black hole mass estimators based on the C IV {lambda}1549 broad emission line, using the updated sample of the reverberation-mapped active galactic nuclei and high-quality UV spectra. By performing multi-component spectral fitting analysis, we measure the C IV line widths (FWHM{sub C{sub IV}} and line dispersion, {sigma}{sub C{sub IV}}) and the continuum luminosity at 1350 A (L{sub 1350}) to calibrate the C-IV-based mass estimators. By comparing with the H{beta} reverberation-based masses, we provide new mass estimators with the best-fit relationships, i.e., M{sub BH}{proportional_to}L{sub 1350}{sup 0.50{+-}0.07}{sigma}{sub C{sub IV}{sup 2}} and M{sub BH}{proportional_to}L{sub 1350}{sup 0.52{+-}0.09} FWHM{sub C{sub IV}{sup 0.56{+-}0.48}}. The new C-IV-based mass estimators show significant mass-dependent systematic difference compared to the estimators commonly used in the literature. Using the published Sloan Digital Sky Survey QSO catalog, we show that the black hole mass of high-redshift QSOs decreases on average by {approx}0.25 dex if our recipe is adopted.

Park, Daeseong; Woo, Jong-Hak; Shin, Jaejin [Astronomy Program, Department of Physics and Astronomy, Seoul National University, Seoul 151-742 (Korea, Republic of); Denney, Kelly D., E-mail: pds2001@astro.snu.ac.kr, E-mail: woo@astro.snu.ac.kr, E-mail: jjshin@astro.snu.ac.kr, E-mail: kelly@dark-cosmology.dk [Dark Cosmology Centre, Niels Bohr Institute, Juliane Maries Vej 30, DK-2100 Copenhagen O (Denmark)

2013-06-20T23:59:59.000Z

455

Gas adsorption isotherm equation based on vacancy solution theory  

SciTech Connect (OSTI)

Pennsylvania State University's new isotherm equation for pure gas adsorption treats the adsorption equilbrium as an osmotic equilibrium between two ''vacancy'' solutions having different compositions. One solution represents the gas phase and the other the adsorbed phase. The vacancy solution is composed of adsorbates and vacancies (imaginary entities defined as the vacuum space that acts as the solvent for the system). Penn State evaluated the developed correlation against published adsorption-isotherm data for O/sub 2/, N/sub 2/, and CO on zeolite 10X and for light hydrocarbons (CH/sub 4/ to nC/sub 4/H/sub 10/) and CO/sub 2/ on Nuxit-AL activated carbon. For both adsorbents, the correlations were closer than those obtained by any other adsorption model that has been extended to gas mixtures. The new method can also represent multicomponent systems because the activity coefficient governing the nonideality of adsorbed mixtures can be readily calculated from binary parameters. These are obtained from single-component adsorption data by a procedure analogous to a bulk solution.

Suwanayuen, S.; Danner, R.P.

1980-01-01T23:59:59.000Z

456

Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption  

SciTech Connect (OSTI)

Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon, zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high parity hydrogen from gaseous products of coal gasification and as an acid gas scrubber.

Ghate, Madhav R. (Morgantown, WV); Yang, Ralph T. (Williamsville, NY)

1987-01-01T23:59:59.000Z

457

Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption  

SciTech Connect (OSTI)

Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high purity hydrogen from gaseous products of coal gasification and as an acid gas scrubber. 2 figs., 2 tabs.

Ghate, M.R.; Yang, R.T.

1985-10-03T23:59:59.000Z

458

Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption  

SciTech Connect (OSTI)

This patent describes the method for bulk separation of multi-component gases generated in a coal gasification process wherein coal is gasified in a gasifier to produce gasification products including a mixture of gases comprising hydrogen, carbon monoxide, methane, and acid gas components carbon dioxide and hydrogen sulfide. It consists of the steps of conveying a stream comprising the mixture of gases into one end of an elongated column containing a solid adsorbent for each of the gases forming the mixture of gases and pressurizing the charge of gases within the column to a pressure within a range sufficient to effect the adsorption by the adsorbent of the conveyed gases including the hydrogen defining the least absorbable gas in the mixture of gases. Then, decreasing the partial pressure of the charge of gases in the column to effect the sequential desorption of the gases hydrogen, carbon monoxide, and methane from the adsorbent in the column, and conveying the adsorbed gases from the column upon desorption thereof from the adsorbent.

Ghate, M.H.; Yang, R.T.

1987-09-29T23:59:59.000Z

459

Development of cost-effective surfactant flooding technology. Final report  

SciTech Connect (OSTI)

Task 1 of this research was the development of a high-resolution, fully implicit, finite-difference, multiphase, multicomponent, compositional simulator for chemical flooding. The major physical phenomena modeled in this simulator are dispersion, heterogeneous permeability and porosity, adsorption, interfacial tension, relative permeability and capillary desaturation, compositional phase viscosity, compositional phase density and gravity effects, capillary pressure, and aqueous-oleic-microemulsion phase behavior. Polymer and its non-Newtonian rheology properties include shear-thinning viscosity, permeability reduction, inaccessible pore volume, and adsorption. Options of constant or variable space grids and time steps, constant-pressure or constant-rate well conditions, horizontal and vertical wells, and multiple slug injections are also available in the simulator. The solution scheme used in this simulator is fully implicit. The pressure equation and the mass-conservation equations are solved simultaneously for the aqueous-phase pressure and the total concentrations of each component. A third-order-in-space, second-order-in-time finite-difference method and a new total-variation-diminishing (TVD) third-order flux limiter are used that greatly reduce numerical dispersion effects. Task 2 was the optimization of surfactant flooding. The code UTCHEM was used to simulate surfactant polymer flooding.

Pope, G.A.; Sepehrnoori, K.

1996-11-01T23:59:59.000Z

460

Ab Initio Enhanced calphad Modeling of Actinide-Rich Nuclear Fuels  

SciTech Connect (OSTI)

The process of fuel recycling is central to the Advanced Fuel Cycle Initiative (AFCI), where plutonium and the minor actinides (MA) Am, Np, and Cm are extracted from spent fuel and fabricated into new fuel for a fast reactor. Metallic alloys of U-Pu-Zr-MA are leading candidates for fast reactor fuels and are the current basis for fast spectrum metal fuels in a fully recycled closed fuel cycle. Safe and optimal use of these fuels will require knowledge of their multicomponent phase stability and thermodynamics (Gibbs free energies). In additional to their use as nuclear fuels, U-Pu-Zr-MA contain elements and alloy phases that pose fundamental questions about electronic structure and energetics at the forefront of modern many-body electron theory. This project will validate state-of-the-art electronic structure approaches for these alloys and use the resulting energetics to model U-Pu-Zr-MA phase stability. In order to keep the work scope practical, researchers will focus on only U-Pu-Zr-{Np,Am}, leaving Cm for later study. The overall objectives of this project are to: Provide a thermodynamic model for U-Pu-Zr-MA for improving and controlling reactor fuels; and, Develop and validate an ab initio approach for predicting actinide alloy energetics for thermodynamic modeling.

Morgan, Dane [Univ. of Wisconsin, Madison, WI (United States); Yang, Yong Austin [Univ. of Wisconsin, Madison, WI (United States)

2013-10-28T23:59:59.000Z

Note: This page contains sample records for the topic "geothermometers multicomponent geothermometers" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
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461

Flux-difference split parabolized Navier-Stokes algorithm for non-equilibrium chemically reacting flows  

SciTech Connect (OSTI)

A flux-difference split explicit finite-difference algorithm is presented for solving the parabolized form of the equations governing three-dimensional nonequilibrium chemically reacting flows. The algorithm is based on an explicit noniterative, upwind space-marching scheme developed by Korte, but differs in that the unsteady Riemann problem, rather than the steady Riemann problem, is solved. The algorithm allows either a second or an approximately third-order accurate upwind treatment of the convection terms by employing the unsteady approximate Riemann solver of Roe. The source terms of the species transport equations are treated in either an explicit or implicit manner, and the species diffusion terms are modeled with either a Fickian or a multicomponent model. A validation of the algorithm is performed by comparing computational results with the 2-D Mach 14, 15 degree compression-corner data of Holden. The three-dimensional capability of the algorithm is demonstrated by computing Mach 2.7 flow over a swept wedge scramjet fuel injector, and three-dimensional reacting flow capability is demonstrated by a computing a shock-jet interaction concept for mixing and combustion enhancement. 34 refs.

White, J.A.; Korte, J.J.; Gaffney, R.L. Jr. (Analytical Services and Materials, Inc., Hampton, VA (United States) NASA, Langley Research Center, Hampton, VA (United States))

1993-01-01T23:59:59.000Z

462

Finite temperature effects on the X-ray absorption spectra of lithium compounds: First-principles interpretation of X-ray Raman measurements  

SciTech Connect (OSTI)

We elucidate the role of room-temperature-induced instantaneous structural distortions in the Li K-edge X-ray absorption spectra (XAS) of crystalline LiF, Li{sub 2}SO{sub 4}, Li{sub 2}O, Li{sub 3}N, and Li{sub 2}CO{sub 3} using high resolution X-ray Raman spectroscopy (XRS) measurements and first-principles density functional theory calculations within the eXcited electron and Core Hole approach. Based on thermodynamic sampling via ab initio molecular dynamics simulations, we find calculated XAS in much better agreement with experiment than those computed using the rigid crystal structure alone. We show that local instantaneous distortion of the atomic lattice perturbs the symmetry of the Li 1s core-excited-state electronic structure, broadening spectral line-shapes and, in some cases, producing additional spectral features. The excellent agreement with high-resolution XRS measurements validates the accuracy of our first-principles approach to simulating XAS, and provides both accurate benchmarks for model compounds and a predictive theoretical capability for identification and characterization of multi-component systems, such as lithium-ion batteries, under working conditions.

Pascal, Tod A.; Prendergast, David, E-mail: dgprendergast@lbl.gov [The Molecular Foundry, Materials Science Division, Lawrence Berkeley National Laboratory (LBNL), Berkeley, California 94720 (United States)] [The Molecular Foundry, Materials Science Division, Lawrence Berkeley National Laboratory (LBNL), Berkeley, California 94720 (United States); Boesenberg, Ulrike; Kostecki, Robert; Richardson, Thomas J. [Environmental Energy Technologies Division, LBNL, Berkeley, California 94720 (United States)] [Environmental Energy Technologies Division, LBNL, Berkeley, California 94720 (United States); Weng, Tsu-Chien; Sokaras, Dimosthenis; Nordlund, Dennis [Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford, California 94720 (United States)] [Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Stanford, California 94720 (United States); McDermott, Eamon; Moewes, Alexander [University of Saskatchewan, Department of Physics and Engineering Physics, Saskatoon, Saskatchewan S7N 5E2 (Canada)] [University of Saskatchewan, Department of Physics and Engineering Physics, Saskatoon, Saskatchewan S7N 5E2 (Canada); Cabana, Jordi [Environmental Energy Technologies Division, LBNL, Berkeley, California 94720 (United States) [Environmental Energy Technologies Division, LBNL, Berkeley, California 94720 (United States); Department of Chemistry, University of Illinois at Chicago, Chicago, Illinois 60605 (United States)

2014-01-21T23:59:59.000Z

463

SANE's Measurement of the Proton's Virtual Photon Spin Asymmetry, A^p_1, at Large Bjorken x  

SciTech Connect (OSTI)

The experiment SANE (Spin Asymmetries of the Nucleon Experiment) measured inclusive double polarization electron asymmetries on a proton target at the Continuous Electron Beam Accelerator Facility at the Thomas Jefferson National Laboratory in Newport News Virgina. Polarized electrons were scattered from a solid {sup 14}NH{sub 3} polarized target provided by the University of Virginia target group. Measurements were taken with the target polarization oriented at 80 degrees and 180 degrees relative to the beam direction, and beam energies of 4.7 and 5.9 GeV were used. Scattered electrons were detected by a multi-component novel non-magnetic detector package constructed for this experiment. Asymmetries measured at the two target orientations allow for the extraction of the virtual Compton asymmetries A{sub 1}{sup p} and A{sub 2}{sup p} as well as the spin structure functions g{sub 1}{sup p} and g{sub 2}{sup p}. This work addresses the extraction of the virtual Compton asymmetry A{sub 1}{sup p} in the deep inelastic regime. The analysis uses data in the kinematic range from Bjorken x of 0.30 to 0.55, separated into four Q{sup 2} bins from 1.9 to 4.7 GeV{sup 2}.

Jonathan Mulholland

2012-05-01T23:59:59.000Z

464

Self-Consistent Fokker-Planck Treatment Of Particle Distributions in Astrophysical Plasmas  

E-Print Network [OSTI]

High-energy, multi-component plasmas in which pair creation and annihilation, lepton-lepton scattering, lepton-proton scattering, and Comptonization all contribute to establishing the particle and photon distributions, are present in a broad range of compact astrophysical objects. Earlier work has included much of the microphysics needed to account for electron-photon and electron-proton interactions, but little has been done to handle the redistribution of the particles as a result of their Coulomb interaction with themselves in an arbitrary case. Our goal here is to use a Fokker-Planck approach in order to develop a fully self-consistent theory for the interaction of arbitrarily distributed particles and radiation to arrive at an accurate representation of the high-energy plasma in these sources. We conduct several tests representative of two dominant segments of parameter space and discuss physical implications of the non-Maxwellian distribution function. Approximate analytical forms for the electron distribution in the case of strongly non-Maxwellian plasmas are given.

Sergei Nayakshin; Fulvio Melia

1997-05-03T23:59:59.000Z

465

Solids flow control and measurement in the PEATGAS pilot-plant program  

SciTech Connect (OSTI)

In a pilot plant gasification program, the measurement and control of major process variables such as flow, temperature, pressure, density and level are essential to develop accurate material balance and reliable scale-up data. Of these, solids mass flow metering and control usually present the most difficult application. Problems are encountered because of (a) solids characteristics, which can cause erosion and plugging; (b) measurement requirements, which are often at elevated pressures and temperatures; and (c) changes in stream characteristics, such as density, viscosity and solids concentration. This paper reviews the approaches used to measure and control solid-liquid and solid-gas mixtures and elaborates on the design, installation and operating experiences of a lockhopper dry feed system commissioned to control solids feed to the gasifier. Accurate and reliable solids flow measurement and control was achieved during the operation of the PEATGAS pilot plant. Standard instrumentation, modified to meet process requirements, was used to measure multi-component flows of solid-gas and solid-liquid mixtures. In addition, a lockhopper feed system using an innovative solids rate control and measurement technique was installed, commissioned and operated. IGT as a process developer will continue to look for new or improved instrumentation that might be better suited to measure important process variables such as the solids mass flow applications discussed herein.

Wohadlo, S.J.; Biljetina, R.; Laurens, R.M.; Bachta, R.

1982-01-01T23:59:59.000Z

466

Diffuse-Charge Dynamics in Electrochemical Systems  

E-Print Network [OSTI]

The response of a model micro-electrochemical system to a time-dependent applied voltage is analyzed. The article begins with a fresh historical review including electrochemistry, colloidal science, and microfluidics. The model problem consists of a symmetric binary electrolyte between parallel-plate, blocking electrodes which suddenly apply a voltage. Compact Stern layers on the electrodes are also taken into account. The Nernst-Planck-Poisson equations are first linearized and solved by Laplace transforms for small voltages, and numerical solutions are obtained for large voltages. The ``weakly nonlinear'' limit of thin double layers is then analyzed by matched asymptotic expansions in the small parameter $\\epsilon = \\lambda_D/L$, where $\\lambda_D$ is the screening length and $L$ the electrode separation. At leading order, the system initially behaves like an RC circuit with a response time of $\\lambda_D L / D$ (not $\\lambda_D^2/D$), where $D$ is the ionic diffusivity, but nonlinearity violates this common picture and introduce multiple time scales. The charging process slows down, and neutral-salt adsorption by the diffuse part of the double layer couples to bulk diffusion at the time scale, $L^2/D$. In the ``strongly nonlinear'' regime (controlled by a dimensionless parameter resembling the Dukhin number), this effect produces bulk concentration gradients, and, at very large voltages, transient space charge. The article concludes with an overview of more general situations involving surface conduction, multi-component electrolytes, and Faradaic processes.

Martin Z. Bazant; Katsuyo Thornton; Armand Ajdari

2004-01-08T23:59:59.000Z

467

Novel nanomaterials based on 5,10,15,20-tetrakis(3,4-dimethoxyphenyl)-21H,23H-porphyrin entrapped in silica matrices  

SciTech Connect (OSTI)

The present study is dealing with the obtaining of transparent hybrid silica materials encapsulating 5,10,15,20-tetrakis(3,4-dimethoxyphenyl)-21H,23H-porphyrin designated for advanced optoelectronic devices. The porphyrin was synthesized by three methods: an Adler-type reaction between pyrrole and 3,4-dimethoxybenzaldehyde in propionic acid medium; by Lindsey condensation of pyrrole with 3,4-dimethoxybenzaldehyde in the presence of BF{sub 3}.OEt{sub 2} and by a multicomponent reaction by simultaneously using of pyrrole and two different aldehydes: 3,4-dimethoxybenzaldehyde and 3-hydroxybenzaldehyde. The 3,4-dimethoxyphenyl substituted porphyrin was characterized by HPLC, TLC, UV-vis, FT-IR, {sup 1}H NMR and {sup 13}C NMR analysis. Excitation and emission spectra were also discussed in terms of pH conditions. The hybrid materials, consisting in the porphyrin encapsulated in silica matrices, have been prepared successfully via the two steps acid-base catalyzed hydrolysis and condensation of tetraethylorthosilicate using different approaches of the sol-gel process: in situ, by impregnation and by sonication. The synthetic conditions and the compositions were monitored and characterized by using spectroscopic methods such as FT-IR, fluorescence and UV-vis. Atomic force microscopy (AFM) has been applied to observe the columnar or pyramidal nanostructures which are formed by the immobilization of porphyrin on the silica matrices.

Fagadar-Cosma, Eugenia, E-mail: efagadar@yahoo.com [Institute of Chemistry Timisoara of Romanian Academy, M. Viteazu Ave, No. 24, 300223 Timisoara (Romania)] [Institute of Chemistry Timisoara of Romanian Academy, M. Viteazu Ave, No. 24, 300223 Timisoara (Romania); Enache, Corina [Institute of Chemistry Timisoara of Romanian Academy, M. Viteazu Ave, No. 24, 300223 Timisoara (Romania)] [Institute of Chemistry Timisoara of Romanian Academy, M. Viteazu Ave, No. 24, 300223 Timisoara (Romania); Vlascici, Dana [West University of Timisoara, Pestalozzi Street, No. 16, 300115 Timisoara (Romania)] [West University of Timisoara, Pestalozzi Street, No. 16, 300115 Timisoara (Romania); Fagadar-Cosma, Gheorghe ['Politehnica' University, T. Lalescu Street, No. 2, 300223 Timisoara (Romania)] ['Politehnica' University, T. Lalescu Street, No. 2, 300223 Timisoara (Romania); Vasile, Mihaela [National Institute for Research and Development in Electrochemistry and Condensed Matter, P. Andronescu Street, No. 1, 300224 Timisoara (Romania)] [National Institute for Research and Development in Electrochemistry and Condensed Matter, P. Andronescu Street, No. 1, 300224 Timisoara (Romania); Bazylak, Grzegorz [Collegium Medicum, Nicolaus Copernicus University, Department of Pharmaco-Bromatology and Molecular Nutrition, Jagiellonska, No. 13, PL-85-067 Bydgoszcz (Poland)] [Collegium Medicum, Nicolaus Copernicus University, Department of Pharmaco-Bromatology and Molecular Nutrition, Jagiellonska, No. 13, PL-85-067 Bydgoszcz (Poland)

2009-12-15T23:59:59.000Z

468

Methods for preparation of catalytic materials  

SciTech Connect (OSTI)

To establish guidelines for the development of a scientific basis for catalyst preparation is perhaps a very ambitious goal. One would re required first to answer the following rhetorical questions: what are the properties which determine the performance of a catalytic material; how can these properties be introduced, developed, and/or improved during preparation? The answer to these questions involves a comprehensive discussion of the theories of catalysis, which is beyond the scope of this review. The authors will attempt, instead, to provide a rationale for each reader to answer these questions on the basis of his/her own interests. They start the discussion by describing the fundamental steps in producing bulk catalysts and/or catalyst supports. The fundamental processes involved are those derived from traditional three-dimensional chemistry. The topic areas will include single-component and multicomponent metal oxides. Unsupported metallic catalysts are formed by transformations involving physical or chemical processes, and the preparation methods for this class of materials will be discussed next. Attention will then turn to the preparation of supported catalytic materials. The main topics to be discussed will be those related to the interaction between the support and the active phase when they are put together to generate the catalyst. In this approach, the authors exploit the virtually unexplored field of surface, or two-dimensional, physical chemistry. The materials considered include dispersed metals and alloys and composite oxides. 366 refs.

Schwarz, J.A. [Syracuse Univ., NY (United States). Dept. of Chemical Engineering and Materials Science; Contescu, C.; Contescu, A. [Romanian Academy, Bucharest (Romania). Inst. of Physical Chemistry

1995-05-01T23:59:59.000Z

469

Interfacial Complex Formation in Uranyl Extraction by Tributyl-Phosphate in Dodecane Diluent: A Molecular Dynamics Study  

SciTech Connect (OSTI)

Atomistic simulations have been carried out in a multicomponent two-phase system (aqueous and organic phases in direct contact) to investigate the interfacial molecular mechanisms leading to uranyl extractionfrom the aqueous to organic phase. The aqueous phase consists of the dissolved ions UO2^2+ and nitrate NO3-,with or without H3O+, in water to describe acidic or neutral condition; the organic phase consists of tributyl phosphate, the extractant, in dodecane as the diluent. We find that the interface facilitates the formation of various uranyl complexes, with a general formula UO2^2+(NO3-)n mTBP kH2O, with n + m + k ) 5, suggesting a 5-fold coordination. The coordination for all three molecular entities has the common feature that they all bind to the uranyl at the uranium atom with an oxygen atom in the equatorial plane perpendicular to the molecular axis of the uranyl, forming a 5-fold symmetry plane. Nitric acid has a strong effect in enhancing the formation of extractable species, which is consistent with experimental findings.

de Almeida, Valmor F [ORNL; Cui, Shengting [ORNL; Ye, Xianggui [ORNL; Khomami, Bamin [ORNL

2009-01-01T23:59:59.000Z

470

Automated Vacuum Ion-Plasma Setup “TRIO” for Making Nanostructure Coatings  

E-Print Network [OSTI]

Abstract – Principle of operation, construction and main parameters of new vacuum ion-plasma setup for arc nitriding and plasma-assisted deposition of such nanostructure coatings as TiAlN, TiCuN on metal substrate are considered. The new setup is assigned for scientific researches with multicom-ponent composite cathode for generation of strain-hardening and protective coatings on tools. The setup is fully automated for high repeatability of complex technological processes. The operating program has planning sheet which contains up to 300 steps in common technological process. The plasma source with heated cathode (PINK) and switch-mode power supply for high-voltage bias on substrate give the opportunity to carry out ion cleaning, etching and activation of substrate sur-face, arc nitriding of tools. There is the opportunity to operate by the inleakage of 2 different gases in necessary proportions. Switch-mode power sup-plies provide stable values of composite cathode currents and automatic discharge initiation in case of arc starvation. The setup main parameters, technical characteristics and supposed application fields are presented. 1.

unknown authors

471

Uranium Removal from Groundwater via In Situ Biostimulation: Field-Scale Modeling of Transport and Biological Processes  

SciTech Connect (OSTI)

During 2002 and 2003, bioremediation experiments in the unconfined aquifer of the Old Rifle UMTRA field site in western Colorado provided evidence for the immobilization of hexavalent uranium in groundwater by iron-reducing Geobacter sp. stimulated by acetate amendment. As the bioavailable Fe(III) terminal electron acceptor was depleted in the zone just downgradient of the acetate injection gallery, sulfate-reducing organisms came to dominate the microbial community. In the present study, we use multicomponent reactive transport modeling to analyze data from the 2002 field experiment to 1) identify the dominant transport and biological processes controlling uranium mobility during biostimulation, 2) determine field-scale parameters for these modeled processes, and 3) apply the calibrated process models to history match observations during the 2003 field experiment. In spite of temporally and spatially variable observations during the field-scale biostimulation experiments, the coupled process simulation approach was able to establish a quantitative characterization of the principal flow, transport, and reaction processes that could be applied without modification to describe the 2003 field experiment. Insights gained from this analysis include field-scale estimates of bioavailable Fe(III) mineral, and the magnitude of uranium bioreduction during biostimulated growth of the iron-reducing and sulfate-reducing microorganisms.

Yabusaki, Steven B.; Fang, Yilin; Long, Philip E.; Resch, Charles T.; Peacock, Aaron D.; Komlos, John; Jaffe, Peter R.; Morrison, Stan J.; Dayvault, Richard; White, David C.; Anderson, Robert T.

2007-03-12T23:59:59.000Z

472

ON MOLECULAR HYDROGEN FORMATION AND THE MAGNETOHYDROSTATIC EQUILIBRIUM OF SUNSPOTS  

SciTech Connect (OSTI)

We have investigated the problem of sunspot magnetohydrostatic equilibrium with comprehensive IR sunspot magnetic field survey observations of the highly sensitive Fe I lines at 15650 A and nearby OH lines. We have found that some sunspots show isothermal increases in umbral magnetic field strength which cannot be explained by the simplified sunspot model with a single-component ideal gas atmosphere assumed in previous investigations. Large sunspots universally display nonlinear increases in magnetic pressure over temperature, while small sunspots and pores display linear behavior. The formation of molecules provides a mechanism for isothermal concentration of the umbral magnetic field, and we propose that this may explain the observed rapid increase in umbral magnetic field strength relative to temperature. Existing multi-component sunspot atmospheric models predict that a significant amount of molecular hydrogen (H{sub 2}) exists in the sunspot umbra. The formation of H{sub 2} can significantly alter the thermodynamic properties of the sunspot atmosphere and may play a significant role in sunspot evolution. In addition to the survey observations, we have performed detailed chemical equilibrium calculations with full consideration of radiative transfer effects to establish OH as a proxy for H{sub 2}, and demonstrate that a significant population of H{sub 2} exists in the coolest regions of large sunspots.

Jaeggli, S. A.; Lin, H. [Institute for Astronomy, University of Hawai'i, 2680 Woodlawn Drive, Honolulu, HI 96822 (United States); Uitenbroek, H. [National Solar Observatory, Sacramento Peak, P.O. Box 62, Sunspot, NM 88349 (United States)

2012-02-01T23:59:59.000Z

473

Map Matching and Real World Integrated Sensor Data Warehousing (Presentation)  

SciTech Connect (OSTI)

The inclusion of interlinked temporal and spatial elements within integrated sensor data enables a tremendous degree of flexibility when analyzing multi-component datasets. The presentation illustrates how to warehouse, process, and analyze high-resolution integrated sensor datasets to support complex system analysis at the entity and system levels. The example cases presented utilizes in-vehicle sensor system data to assess vehicle performance, while integrating a map matching algorithm to link vehicle data to roads to demonstrate the enhanced analysis possible via interlinking data elements. Furthermore, in addition to the flexibility provided, the examples presented illustrate concepts of maintaining proprietary operational information (Fleet DNA) and privacy of study participants (Transportation Secure Data Center) while producing widely distributed data products. Should real-time operational data be logged at high resolution across multiple infrastructure types, map matched to their associated infrastructure, and distributed employing a similar approach; dependencies between urban environment infrastructures components could be better understood. This understanding is especially crucial for the cities of the future where transportation will rely more on grid infrastructure to support its energy demands.

Burton, E.

2014-02-01T23:59:59.000Z

474

REACTIVE TRANSPORT MODELING USING A PARALLEL FULLY-COUPLED SIMULATOR BASED ON PRECONDITIONED JACOBIAN-FREE NEWTON-KRYLOV  

SciTech Connect (OSTI)

Systems of multicomponent reactive transport in porous media that are large, highly nonlinear, and tightly coupled due to complex nonlinear reactions and strong solution-media interactions are often described by a system of coupled nonlinear partial differential algebraic equations (PDAEs). A preconditioned Jacobian-Free Newton-Krylov (JFNK) solution approach is applied to solve the PDAEs in a fully coupled, fully implicit manner. The advantage of the JFNK method is that it avoids explicitly computing and storing the Jacobian matrix during Newton nonlinear iterations for computational efficiency considerations. This solution approach is also enhanced by physics-based blocking preconditioning and multigrid algorithm for efficient inversion of preconditioners. Based on the solution approach, we have developed a reactive transport simulator named RAT. Numerical results are presented to demonstrate the efficiency and massive scalability of the simulator for reactive transport problems involving strong solution-mineral interactions and fast kinetics. It has been applied to study the highly nonlinearly coupled reactive transport system of a promising in situ environmental remediation that involves urea hydrolysis and calcium carbonate precipitation.

Luanjing Guo; Chuan Lu; Hai Huang; Derek R. Gaston

2012-06-01T23:59:59.000Z

475

Final Technical Report, DOE/ER/64323  

SciTech Connect (OSTI)

The DOE SciDAC program funded a team that developed PFLOTRAN, the next-generation (�peta-scale�) massively parallel, multiphase, multicomponent reactive flow and transport code. These codes are required to improve understanding and risk management of subsurface contaminant migration and geological sequestration of carbon dioxide. The important fate and transport processes occurring in the subsurface span a wide range of spatial and temporal scales, and involve nonlinear interactions among many different chemical constituents. Due to the complexity of this problem, modeling subsurface processes normally requires simplifying assumptions. However, tools of advanced scientific computing that have been used in other areas such as energy and materials research can also help address challenging problems in the environmental and geoscience fields. The overall project was led by Los Alamos National Laboratory and included Argonne, Oak Ridge and Pacific Northwest National Laboratories, in addition to the University of Illinois. This report summarizes the results of the research done at the University of Illinois, which focused on improvements to the underlying physical and computational modeling of certain transport and mixing processes.

Valocchi, Albert J. [University of Illinois, Dept of Civil & Environ Engr] University of Illinois, Dept of Civil & Environ Engr

2013-06-05T23:59:59.000Z

476

Tailored ramp-loading via shock release of stepped-density reservoirs  

SciTech Connect (OSTI)

The concept of a gradient piston drive has been extended from that of a single component reservoir, such as a high explosive, to that of a multi-component reservoir that utilizes low density foams and large shocks to achieve high pressures ({approx}3.5 mbar) and controlled pressure vs. time profiles on a driven sample. Simulated and experimental drives shaped through the use of multiple component (including carbonized resorcinol formaldehyde and SiO{sub 2} foam) reservoirs are compared. Individual density layers in a multiple component reservoir are shown to correlate with velocity features in the measured drive which enables the ability to tune a pressure drive by adjusting the components of the reservoir. Pre-shot simulations are shown to be in rough agreement with the data, but post-shot simulations involving the use of simulated plasma drives were needed to achieve an exact match. Results from a multiple component reservoir shot ({approx}3.5 mbar) at the National Ignition Facility are shown.

Prisbrey, Shon T.; Park, Hye-Sook; Remington, Bruce A.; Cavallo, Robert; May, Mark; Pollaine, Stephen M.; Rudd, Robert; Maddox, Brian; Comley, Andrew; Fried, Larry; Blobaum, Kerri; Wallace, Russ; Wilson, Mike; Swift, David; Satcher, Joe; Kalantar, Dan; Perry, Ted [Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, California 94550 (United States); Giraldez, Emilio; Farrell, Michael; Nikroo, Abbas [General Atomics, San Diego, California 92186 (United States)

2012-05-15T23:59:59.000Z

477

Diagnostic Implications of the Reactivity of Fluorescence Tracers  

SciTech Connect (OSTI)

Measurements of fuel concentration distributions with planar laser induced fluorescence of tracer molecules that are added to a base fuel are commonly used in combustion research and development. It usually is assumed that the tracer concentration follows the parent fuel concentration if physical properties such as those determining evaporation are matched. As an example to address this general issue a computational study of combustion of biacetyl/iso-octane mixtures was performed to investigate how well the concentration of biacetyl represents the concentration of iso-octane. For premixed mixture conditions with flame propagation the spatial concentration profiles of the two species in the flame front are separated by 110 {micro}m at 1 bar and by 11 {micro}m at 10 bar. For practical applications this spatial separation is insignificantly small. However, for conditions that mimic ignition and combustion in diesel and HCCI-like operation the differences in tracer and fuel concentration can be significant, exceeding hundreds of percent. At low initial temperature biacetyl was found to be more stable whereas at higher temperature (>1000K) iso-octane is more stable. Similar findings were obtained for a multi-component fuel comprised of iso-octane, n-heptane, methylcyclohexane, and toluene. It may be assumed that similar differences can exist for other tracer/fuel combinations. Caution has therefore to be applied when interpreting PLIF measurements in homogeneous reaction conditions such as in HCCI engine studies.

Sick, V; Westbrook, C

2008-07-14T23:59:59.000Z

478

The origin of steep vertical stellar distribution in the Galactic disk  

E-Print Network [OSTI]

Over the past two decades observations have revealed that the vertical density distribution of stars in galaxies near the mid-plane is substantially steeper than the sech^2 function that is expected from an isothermal approximation. However, the physical origin for this has not been explained so far. Here we show that such steep profiles result naturally even within the isothermal regime, on taking into account the gravitational force due to the gas. Due to its low velocity dispersion the gas is concentrated closer to the galactic mid-plane than the stars, and hence it strongly affects the vertical stellar distribution even though its contribution to the total surface density is small. We apply a three-component galactic disk model consisting of gravitationally coupled stars and the HI and H_2 gas, embedded in the dark matter halo, and calculate the vertical density distribution of stars for the Galaxy. The resulting vertical density distribution of stars is shown to be steeper than the sech^2 function, and lies between the sech and an exponential function, in good agreement with observations of galaxies. We also show that a multi-component stellar disk consisting of coupled dwarfs and two populations of giants does not explain the observed steep stellar profiles.

Arunima Banerjee; Chanda J. Jog

2007-03-08T23:59:59.000Z

479

The origin of the UV excess in powerful radio galaxies: spectroscopy and polarimetry of a complete sample of intermediate redshift radio galaxies  

E-Print Network [OSTI]

We present spectroscopic and polarimetric observations of a complete, optically unbiased sample of 2Jy radio galaxies at intermediate redshifts (0.15 10% level. Careful measurement and modelling of our spectra have allowed us to quantify the contributions of other components to the UV excess. We show that nebular continuum (present in all objects at the 3 -- 40% level), direct AGN light (significant in 40% of objects), and young stellar populations (significant in 15 -- 50% of objects) all make important contributions to the UV continuum in the population of powerful radio galaxies. These results serve to emphasise the multi-component nature of the UV continuum in radio galaxies. The results also point to an interesting link betweeen the optical/UV and far-IR properties of our sample objects, in the sense that the objects with the clearest evidence for optical/UV starburst activity are also the most luminous at far-IR wavelengths. This supports the idea that the cooler dust components in radio galaxies are heated by starbursts rather than by AGN.

C. Tadhunter; R. Dickson; R. Morganti; T. G. Robinson; K. Wills; M. Villar-Martin; M. Hughes

2002-01-23T23:59:59.000Z

480

A novel proportional--integral-derivative control configuration with application to the control of batch distillation  

SciTech Connect (OSTI)

The aim of this paper is to propose a novel proportional-integral-derivative (PID) control configuration based on an observer structure. Batch distillation is used as the base case study where the regulated output is the distillate composition. The proposed PID control law is derived in the framework of robust nonlinear control with modeling error compensation techniques. A reduced-order observer is proposed to estimate both the derivative of the regulated output and the underlying modeling error. These observations are subsequently used in a control loop to feedback variations of distillate composition (derivative feedback) and to counteract the effects of modeling errors. It is shown that, under certain conditions, the resulting control law is equivalent to a classical PID controller with an antireset windup scheme. Moreover, the tuning of the controller is performed very easily in terms of a prescribed closed-loop time constant and an estimation time constant. Numerical results are provided for binary and multicomponent separations. Sampled/delayed measurements and several sources of uncertainties are considered in order to provide a realistic test scenario for the proposed control design procedure.

Alvarez-Ramirez, J.; Monroy-Loperena, R.; Cervantes, I.; Morales, A.

2000-02-01T23:59:59.000Z

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481

Nonlinear dust acoustic waves in inhomogeneous four-component dusty plasma with opposite charge polarity dust grains  

SciTech Connect (OSTI)

The reductive perturbation technique is employed to investigate the propagation properties of nonlinear dust acoustic (DA) waves in a four-component inhomogeneous dusty plasma (4CIDP). The 4CIDP consists of both positive- and negative-charge dust grains, characterized by different mass, temperature, and density, in addition to a background of Maxwellian electrons and ions. The inhomogeneity caused by nonuniform equilibrium values of particle densities, fluid velocities, and electrostatic potential leads to a significant modification to the nature of nonlinear DA solitary waves. It is found that this model reveals two DA wave velocities, one slow, ?{sub s}, and the other is fast, ?{sub f}. The nonlinear wave evolution is governed by a modified Kortweg-de Vries equation, whose coefficients are space dependent. Both the two soliton types; compressive and rarefactive are allowed corresponding to ?{sub s}. However, only compressive soliton is created corresponding to ?{sub f}. The numerical investigations illustrate the dependence of the soliton amplitude, width, and velocity on the plasma inhomogeneities in each case. The relevance of these theoretical results with 4CIDPs observed in a multi-component plasma configurations in the polar mesosphere is discussed.

El-Taibany, W. F. [Department of Physics, Faculty of Science, Damietta University, New Damietta P. O. 34517 (Egypt)] [Department of Physics, Faculty of Science, Damietta University, New Damietta P. O. 34517 (Egypt)

2013-09-15T23:59:59.000Z

482

Life Extension Program for the Modular Caustic Side Solvent Extraction Unit at Savannah River Site - 13179  

SciTech Connect (OSTI)

Caustic Side Solvent Extraction (CSSX) is currently used at the U.S. Department of Energy (DOE) Savannah River Site (SRS) for removal of cesium from the high-level salt-wastes stored in underground tanks. Currently, the Actinide Removal Process (ARP) and the CSSX process are deployed in the (ARP)/Modular CSSX Unit (MCU), to process salt waste for permanent disposition. The CSSX technology utilizes a multi-component organic solvent and annular centrifugal contactors to extract cesium from alkaline salt waste. The original plant was permitted for a three year design life; however, given the successful operation of the plant, a life extension program was completed to continue operations. The program included detailed engineering analyses of the life-expectancy of passive and active components, resulting in component replacement and/or maintenance and monitoring program improvements. The program also included a review of the operations and resulted in a series of operational improvements. Since the improvements have been made, an accelerated processing rate has been demonstrated. In addition, plans for instituting a next-generation solvent are in place and will enhance the decontamination factors. (author)

Samadi, Azadeh [Savannah River Remediation, Aiken, SC 29808 (United States)] [Savannah River Remediation, Aiken, SC 29808 (United States)

2013-07-01T23:59:59.000Z

483

Dynamic density functional theory of protein adsorption on polymer-coated nanoparticles  

E-Print Network [OSTI]

We present a theoretical model for the description of the adsorption kinetics of globular proteins onto charged core-shell microgel particles based on Dynamic Density Functional Theory (DDFT). This model builds on a previous description of protein adsorption thermodynamics [Yigit \\textit{et al}, Langmuir 28 (2012)], shown to well interpret the available calorimetric experimental data of binding isotherms. In practice, a spatially-dependent free-energy functional including the same physical interactions is built, and used to study the kinetics via a generalised diffusion equation. To test this model, we apply it to the case study of Lysozyme adsorption on PNIPAM coated nanoparticles, and show that the dynamics obtained within DDFT is consistent with that extrapolated from experiments. We also perform a systematic study of the effect of various parameters in our model, and investigate the loading dynamics as a function of proteins' valence and hydrophobic adsorption energy, as well as their concentration and that of the nanoparticles. Although we concentrated here on the case of adsorption for a single protein type, the model's generality allows to study multi-component system, providing a reliable instrument for future studies of competitive and cooperative adsorption effects often encountered in protein adsorption experiments.

Stefano Angioletti-Uberti; Matthias Ballauff; Joachim Dzubiella

2014-07-30T23:59:59.000Z

484

Nanocrystallization in spark plasma sintered Fe{sub 48}Cr{sub 15}Mo{sub 14}Y{sub 2}C{sub 15}B{sub 6} bulk amorphous alloy  

SciTech Connect (OSTI)

Spark plasma sintering (SPS) is evolving as an attractive process for the processing of multi-component Fe-based bulk amorphous alloys and their in-situ nanocomposites with controlled primary nanocrystallization. Extended Q-range small angle neutron scattering (EQ-SANS) analysis, complemented by x-ray diffraction and transmission electron microscopy, was performed to characterize nanocrystallization behavior of SPS sintered Fe-based bulk amorphous alloys. The SANS experiments show significant scattering for the samples sintered in the supercooled region indicating local structural/compositional changes associated with the profuse nucleation of nanoclusters (?4 nm). For the samples spark plasma sintered near and above crystallization temperature (>653 °C), the SANS data show the formation of interference maximum indicating the formation and growth of (Fe,Cr){sub 23}C{sub 6} crystallites. The SANS data also indicate the evolution of bimodal crystallite distribution at higher sintering temperatures (above T{sub x1}). The growth of primary nanocrystallites results in impingement of concentration gradient fields (soft impingement effect), leading to non-random nucleation of crystallites near the primary crystallization.

Singh, Ashish; Harimkar, Sandip P. [School of Mechanical and Aerospace Engineering, Oklahoma State University, Stillwater, Oklahoma 74078 (United States)] [School of Mechanical and Aerospace Engineering, Oklahoma State University, Stillwater, Oklahoma 74078 (United States); Katakam, Shravana; Dahotre, Narendra B. [Department of Materials Science and Engineering, University of North Texas, Denton, Texas 76203 (United States)] [Department of Materials Science and Engineering, University of North Texas, Denton, Texas 76203 (United States); Ilavsky, Jan [Advanced Photon Source, Argonne National Laboratory, Chicago, Illinois 60439 (United States)] [Advanced Photon Source, Argonne National Laboratory, Chicago, Illinois 60439 (United States)

2013-08-07T23:59:59.000Z

485

Combined heat and mass transfer device for improving separation process  

DOE Patents [OSTI]

A two-phase small channel heat exchange matrix simultaneously provides for heat transfer and mass transfer between the liquid and vapor phases of a multi-component mixture at a single, predetermined location within a separation column, significantly improving the thermodynamic efficiency of the separation process. The small channel heat exchange matrix is composed of a series of channels having a hydraulic diameter no greater than 5.0 millimeters for conducting a two-phase coolant. In operation, the matrix provides the liquid-vapor contacting surfaces within the separation column, such that heat and mass are transferred simultaneously between the liquid and vapor phases. The two-phase coolant allows for a uniform heat transfer coefficient to be maintained along the length of the channels and across the surface of the matrix. Preferably, a perforated, concave sheet connects each channel to an adjacent channel to facilitate the flow of the liquid and vapor phases within the column and to increase the liquid-vapor contacting surface area.

Tran, Thanh Nhon (Flossmoor, IL)

1999-01-01T23:59:59.000Z