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Sample records for geosynthetic clay liner

  1. Geosynthetic clay liners - slope stability field study

    SciTech Connect (OSTI)

    Carson, D.A.; Daniel, D.E.; Koerner, R.M.; Bonaparte, R.

    1997-12-31

    A field research project was developed to examine the internal shear performance of geosynthetic clay liners (GCLs). Several combinations of cross sections were assembled using GCL materials that were available at the time of project initiation. The cross sections utilized were intended to simulate landfill cover applications. Thirteen (13) resulting test plots were constructed on two different slope angles, and each plot is instrumented for physical displacement and soil moisture characteristics. Test plots were constructed in a manner that dictated the shear plane in the clay portion of the GCL product. The project purpose is to assess field performance and to verify design parameters associated with the application of GCLs in waste containment applications. Interim research data shows that test slopes on 2H:1V show global deformation, but little internal shear evidence, and the 3H:1V slopes show little deformation at approximately 650 days. The research is ongoing, and this paper presents the most recent information available from the project.

  2. In-situ studies on the performance of landfill caps (compacted soil liners, geomembranes, geosynthetic clay liners, capillary barriers)

    SciTech Connect (OSTI)

    Melchior, S.

    1997-12-31

    Since 1986 different types of landfill covers have been studied in-situ on the Georgswerder landfill in Hamburg, Germany. Water balance data are available for eight years. The performance of different carriers has been measured by collecting the leakage on areas ranging from 100 m{sup 2} to 500 m{sup 2}. Composite liners with geomembranes performed best, showing no leakage. An extended capillary barrier also performed well. The performance of compacted soil liners, however, decreased severely within five years due to desiccation, shrinkage and plant root penetration (liner leakage now ranging from 150 mm/a to 200 mm/a). About 50 % of the water that reaches the surface of the liner is leaking through it. The maximum leakage rates have increased from 2 x 10{sup -10} m{sup 3} m{sup -2} s{sup -1} to 4 x 10{sup -8} m{sup 3} m{sup -2} s{sup -1}. Two types of geosynthetic clay liners (GCL) have been tested for two years now with disappointing results. The GCL desiccated during the first dry summer of the study. High percolation rates through the GCL were measured during the following winter (45 mm resp. 63 mm in four months). Wetting of the GCL did not significantly reduce the percolation rates.

  3. Laboratory measurements of contaminant attenuation of uranium mill tailings leachates by sediments and clay liners

    SciTech Connect (OSTI)

    Serne, R.J.; Peterson, S.R.; Gee, G.W.

    1983-04-01

    We discuss FY82 progress on the development of laboratory tools to aid in the prediction of migration potential of contaminants present in acidic uranium mill tailings leachate. Further, empirical data on trace metal and radionuclide migration through a clay liner are presented. Acidic uranium mill tailings solution from a Wyoming mill was percolated through a composite sediment called Morton Ranch Clay liner. These laboratory columns and subsequent sediment extraction data show: (1) As, Cr, Pb, Ag, Th and V migrate very slowly; (2) U, Cd, Ni, Zn, Fe, Mn and similar transition metals are initially immobilized during acid neutralization but later are remobilized as the tailings solution exhausts the clay liner's acid buffering capacity. Such metals remain immobilized as long as the effluent pH remains above a pH value of 4 to 4.5, but they become mobile once the effluent pH drops below this range; and (3) fractions of the Se and Mo present in the influent tailings solution are very mobile. Possible controlling mechanisms for the pH-dependent immobilization-mobilization of the trace metals are discussed. More study is required to understand the controlling mechanisms for Se and Mo and Ra for which data were not successfully collected. Using several column lengths (from 4.5 to 65 cm) and pore volume residence times (from 0.8 to 40 days) we found no significant differences in contaminant migration rates or types and extent of controlling processes. Thus, we conclude that the laboratory results may be capable of extrapolation to actual disposal site conditions.

  4. Modeling of geosynthetic reinforced capping systems

    SciTech Connect (OSTI)

    Viswanadham, B.V.S.; Koenig, D.; Jessberger, H.L.

    1997-12-31

    The investigation deals with the influence of a geosynthetic reinforcement on the deformation behavior and sealing efficiency of the reinforced mineral sealing layer at the onset of non-uniform settlements. The research program is mainly concentrated in studying the influence of reinforcement inclusion in restraining cracks and crack propagation due to soil-geosynthetic bond efficiency. Centrifuge model tests are conducted in the 500 gt capacity balanced beam Bochum geotechnical Centrifuge (Z1) simulating a differential deformation of a mineral sealing layer of a landfill with the help of trap-door arrangement. By comparing the performance of the deformed mineral sealing layer with and without geogrid, the reinforcement ability of the geogrid in controlling the crack propagation and permeability of the mineral swing layer is evaluated.

  5. Emerging and future developments of selected geosynthetic applications

    SciTech Connect (OSTI)

    Koerner, R.M.

    2000-04-01

    This paper presents 17 separate applications within the current technology of geosynthetics. They were selected as being illustrative of the wide range of applications that can utilize geosynthetics in geotechnical, transportation, hydraulics, and geoenvironmental engineering. All are permanent and/or critical applications wherein design by function is required, thereby necessitating the calculation of a product-specific test result versus a site-specific design requirement. This calculation results in a factor of safety, which must be assessed accordingly. In this regard, geosynthetics are no different from any other engineering material. This paper, however, does not go into calculation details, which are available in the literature. References are provided in this regard. The various applications presented were selected to illustrate that both emerging developments and future possibilities are ongoing. This approach illustrates the dynamic nature of the field of geosynthetics, which is both exciting and stimulating, and speaks well for future endeavors.

  6. Application and analysis of anchored geosynthetic systems for stabilization of abandoned mine land slopes

    SciTech Connect (OSTI)

    Vitton, S.J.; Whitman, F.; Liang, R.Y.; Harris, W.W.

    1996-12-31

    An anchored geosynthetic system (AGS) was used in the remediation of a landslide associated with an abandoned coal mine located near Hindman, Kentucky. In concept, AGS is a system that provides in-situ stabilization of soil slopes by combining a surface-deployed geosynthetic with an anchoring system of driven reinforcing rods similar to soil nailing. Installation of the system of driven reinforcing rods similar to soil nailing. Installation of the system involves tensioning a geosynthetic over a slope`s surface by driving anchors through the geosynthetic at a given spacing and distance. By tensioning the geosynthetic over the slope`s surface, a compressive load is applied to the slope. Benefits of AGS are described to include the following: (1) increase soil strength due to soil compression including increased compressive loading on potential failure surfaces, (2) soil reinforcement through soil nailing, (3), halt of soil creep, (4) erosion control, and (5) long term soil consolidation. Following installation of the AGS and one year of monitoring, it was found that the anchored geosynthetic system only provided some of the reported benefits and in general did not function as an active stabilization system. This was due in part to the inability of the system to provide and maintain loading on the geosynthetic. The geosynthetic, however, did tension when slope movement occurred and prevented the slope from failing. Thus, the system functioned more as a passive restraint system and appeared to function well over the monitoring period.

  7. Combustor liner cooling system

    DOE Patents [OSTI]

    Lacy, Benjamin Paul; Berkman, Mert Enis

    2013-08-06

    A combustor liner is disclosed. The combustor liner includes an upstream portion, a downstream end portion extending from the upstream portion along a generally longitudinal axis, and a cover layer associated with an inner surface of the downstream end portion. The downstream end portion includes the inner surface and an outer surface, the inner surface defining a plurality of microchannels. The downstream end portion further defines a plurality of passages extending between the inner surface and the outer surface. The plurality of microchannels are fluidly connected to the plurality of passages, and are configured to flow a cooling medium therethrough, cooling the combustor liner.

  8. Microsoft Word - LL-WM08 Paper 8351.doc

    Broader source: Energy.gov (indexed) [DOE]

    Tests on Geosynthetic Clay Liners Subjected to Differential Settlement," MS Thesis, Univ. of Texas, Austin, TX (1992). 25. W.J. WAUGH, G.M. SMITH, D.BERGMAN-TABBERT, and...

  9. Microsoft Word - LL-White Paper Prac_Improve_Perform.doc

    Broader source: Energy.gov (indexed) [DOE]

    tests on geosynthetic clay liners subjected to differential settlement. MS Thesis, Univ. of Texas, Austin, TX. Lapham, S.C., J.B. Millard, and J.M. Samet, 1989. "Health...

  10. Clay Minerals

    SciTech Connect (OSTI)

    Mueller, Karl T.; Sanders, Rebecca L.; Washton, Nancy M.

    2014-03-14

    Clay minerals are important components of the environment and are involved or implicated in processes such as the uptake of pollutants and the release of nutrients and as potential platforms for a number of chemical reactions. Owing to their small particle sizes (typically, on the order of microns or smaller) and mixing with a variety of other minerals and soil components, advanced characterization methods are needed to study their structures, dynamics, and reactivities. In this article, we describe the use of solid-state NMR methods to characterize the structures and chemistries of clay minerals. Early one-pulse magic-angle spinning (MAS) NMR studies of 27Al and 29Si have now been enhanced and extended with new studies utilizing advanced methodologies (such as Multiple Quantum MAS) as well as studies of less-sensitive nuclei. In additional work, the issue of reactivity of clay minerals has been addressed, including studies of reactive surface area in the environment. Utilizations of NMR-sensitive nuclides within the clay minerals themselves, and in molecules that react with speci?c sites on the clay mineral surfaces, have aided in understanding the reactivity of these complex aluminosilicate systems.

  11. Method for forming or bonding a liner

    DOE Patents [OSTI]

    Prevender, Thomas S.

    1980-01-01

    A process and means for forming or bonding a liner to a shell or element wherein the liner is filled with or immersed in water and a portion of the water is frozen.

  12. Computational fluid dynamics improves liner cementing operation

    SciTech Connect (OSTI)

    Barton, N.A.; Archer, G.L. ); Seymour, D.A. )

    1994-09-26

    The use of computational fluid dynamics (CFD), an analytical tool for studying fluid mechanics, helped plan the successful cementing of a critical liner in a North Sea extended reach well. The results from CFD analysis increased the confidence in the primary cementing of the liner. CFD modeling was used to quantify the effects of increasing the displacement rate and of rotating the liner on the mud flow distribution in the annulus around the liner.

  13. Segmented ceramic liner for induction furnaces

    DOE Patents [OSTI]

    Gorin, A.H.; Holcombe, C.E.

    1994-07-26

    A non-fibrous ceramic liner for induction furnaces is provided by vertically stackable ring-shaped liner segments made of ceramic material in a light-weight cellular form. The liner segments can each be fabricated as a single unit or from a plurality of arcuate segments joined together by an interlocking mechanism. Also, the liner segments can be formed of a single ceramic material or can be constructed of multiple concentric layers with the layers being of different ceramic materials and/or cellular forms. Thermomechanically damaged liner segments are selectively replaceable in the furnace. 5 figs.

  14. Segmented ceramic liner for induction furnaces

    DOE Patents [OSTI]

    Gorin, Andrew H.; Holcombe, Cressie E.

    1994-01-01

    A non-fibrous ceramic liner for induction furnaces is provided by vertically stackable ring-shaped liner segments made of ceramic material in a light-weight cellular form. The liner segments can each be fabricated as a single unit or from a plurality of arcuate segments joined together by an interlocking mechanism. Also, the liner segments can be formed of a single ceramic material or can be constructed of multiple concentric layers with the layers being of different ceramic materials and/or cellular forms. Thermomechanically damaged liner segments are selectively replaceable in the furnace.

  15. An Evaluation of Long-Term Performance of Liner Systems for Low-Level Waste Disposal Facilities

    SciTech Connect (OSTI)

    Arthur S. Rood; Annette L. Schafer; A. Jeffrey Sondrup

    2011-03-01

    Traditional liner systems consisting of a geosynthetic membrane underlying a waste disposal facility coupled with a leachate collection system have been proposed as a means of containing releases of low-level radioactive waste within the confines of the disposal facility and thereby eliminating migration of radionuclides into the vadose zone and groundwater. However, this type of hydraulic containment liner system is only effective as long as the leachate collection system remains functional or an overlying cover limits the total infiltration to the volumetric pore space of the disposal system. If either the leachate collection system fails, or the overlying cover becomes less effective during the 1,000s of years of facility lifetime, the liner may fill with water and release contaminated water in a preferential or focused manner. If the height of the liner extends above the waste, the waste will become submerged which could increase the release rate and concentration of the leachate. If the liner extends near land surface, there is the potential for contamination reaching land surface creating a direct exposure pathway. Alternative protective liner systems can be engineered that eliminate radionuclide releases to the vadose zone during operations and minimizing long term migration of radionuclides from the disposal facility into the vadose zone and aquifer. Non-traditional systems include waste containerization in steel or composite materials. This type of system would promote drainage of clean infiltrating water through the facility without contacting the waste. Other alternatives include geochemical barriers designed to transmit water while adsorbing radionuclides beneath the facility. Facility performance for a hypothetical disposal facility has been compared for the hydraulic and steel containerization liner alternatives. Results were compared in terms of meeting the DOE Order 435.1 low-level waste performance objective of 25 mrem/yr all-pathways dose during

  16. Elastomer liners for geothermal tubulars Y267 EPDM Liner Program:

    SciTech Connect (OSTI)

    Hirasuna, A.R.; Davis, D.L.; Flickinger, J.E.; Stephens, C.A.

    1987-12-01

    The elastomer, Y267 EPDM, has been identified as a hydrothermally stable material which can operate at temperatures in excess of 320/sup 0/C. The goal of the Y267 Liner Program was to demonstrate the feasibility of using this material as a liner for mild steel tubulars to prevent or mitigate corrosion. If successful, the usage of EPDM lined pipe by the geothermal community may have a significant impact on operating costs and serve as a viable alternative to the use of alloyed tubulars. Tooling procedures were developed under this program to mold a 0.64 cm (0.25'') thick Y267 EPDM liner into a tubular test section 61 cm (2') in length and 19.1 cm (7.5'') in diameter (ID). A successful effort was made to identify a potential coupling agent to be used to bond the elastomer to the steel tubular wall. This agent was found to withstand the processing conditions associated with curing the elastomer at 288/sup 0/C and to retain a significant level of adhesive strength following hydrothermal testing in a synthetic brine at 260/sup 0/C for a period of 166 hours. Bonding tests were conducted on specimens of mild carbon steel and several alloys including Hastelloy C-276. An objective of the program was to field test the lined section of pipe mentioned above at a geothermal facility in the Imperial Valley. Though a test was conducted, problems encountered during the lining operation precluded an encouraging outcome. The results of the field demonstration were inconclusive. 6 refs., 13 figs., 13 tabs

  17. Shock wave absorber having a deformable liner

    DOE Patents [OSTI]

    Youngdahl, C.K.; Wiedermann, A.H.; Shin, Y.W.; Kot, C.A.; Ockert, C.E.

    1983-08-26

    This invention discloses a shock wave absorber for a piping system carrying liquid. The absorber has a plastically deformable liner defining the normal flow boundary for an axial segment of the piping system, and a nondeformable housing is spaced outwardly from the liner so as to define a gas-tight space therebetween. The flow capacity of the liner generally corresponds to the flow capacity of the piping system line, but the liner has a noncircular cross section and extends axially of the piping system line a distance between one and twenty times the diameter thereof. Gas pressurizes the gas-tight space equal to the normal liquid pressure in the piping system. The liner has sufficient structural capacity to withstand between one and one-half and two times this normal liquid pressures; but at greater pressures it begins to plastically deform initially with respect to shape to a more circular cross section, and then with respect to material extension by circumferentially stretching the wall of the liner. A high energy shock wave passing through the liner thus plastically deforms the liner radially into the gas space and progressively also as needed in the axial direction of the shock wave to minimize transmission of the shock wave beyond the absorber.

  18. Drapery assembly including insulated drapery liner

    DOE Patents [OSTI]

    Cukierski, Gwendolyn (Ithaca, NY)

    1983-01-01

    A drapery assembly is disclosed for covering a framed wall opening, the assembly including drapery panels hung on a horizontal traverse rod, the rod having a pair of master slides and means for displacing the master slides between open and closed positions. A pair of insulating liner panels are positioned behind the drapery, the remote side edges of the liner panels being connected with the side portions of the opening frame, and the adjacent side edges of the liner panels being connected with a pair of vertically arranged center support members adapted for sliding movement longitudinally of a horizontal track member secured to the upper horizontal portion of the opening frame. Pivotally arranged brackets connect the center support members with the master slides of the traverse rod whereby movement of the master slides to effect opening and closing of the drapery panels effects simultaneous opening and closing of the liner panels.

  19. Modified clay sorbents

    DOE Patents [OSTI]

    Fogler, H. Scott; Srinivasan, Keeran R.

    1990-01-01

    A novel modified clay sorbent and method of treating industrial effluents to remove trace pollutants, such as dioxins, biphenyls, and polyaromatics such as benzo(a)pyrene and pentachlorophenol. The novel clay sorbent has a composite structure in which the interlayer space of an expandable clay, such as smectite, is filled with polyvalent or multivalent inorganic cations which forces weaker surfactant cations to locate on the surface of the clay in such an orientation that the resulting composite is hydrophilic in nature. A specific example is cetylpyridinium-hydroxy aluminum-montmorillonite. In certain embodiments, a non-expanding clay, such as kaolinite, is used and surfactant cations are necessarily located on an external surface of the clay. A specific example is cetylpyridinium-kaolinite.

  20. Engineered clay-shredded tyre mixtures as barrier materials

    SciTech Connect (OSTI)

    Al-Tabbaa, A.; Aravinthan, T.

    1997-12-31

    An engineered clay consisting of kaolin and bentonite was mixed with shredded tyre in various weight percentages and examined for use as a constituent in a landfill liner. The clay-tyre mixtures properties in terms of compaction, unconfined compressive strength, permeability to water and paraffin, leachability, stress-strain behaviour, free swell behaviour and swelling pressure were investigated. The results show that the dry density and strength reduced with the addition of tyre and also with increased tyre content but that good interaction was developed between the clay and tyre. The strain at failure increased showing reinforcing effect of the tyre. The permeability to paraffin was considerably reduced compared to that to water due to the presence of the tyre which caused high swelling pressures to develop. The leachability results indicate initial high concentrations leaching out of the soil-tyre mixtures which will be subjected to dilution in the environment. This work adds evidence to the potential advantages of using soil-tyre mixtures as a landfill liner material.

  1. Lifecycle Verification of Tank Liner Polymers

    SciTech Connect (OSTI)

    Anovitz, Lawrence {Larry} M; Smith, Barton

    2014-03-01

    This report describes a method that was developed for the purpose of assessing the durability of thermoplastic liners used in a Type IV hydrogen storage tank during the tank s expected service life. In the method, a thermoplastic liner specimen is cycled between the maximum and minimum expected working temperatures while it is differentially pressurized with high-pressure hydrogen gas. The number of thermal cycling intervals corresponds to those expected within the tank s design lifetime. At prescribed intervals, hydrogen permeation measurements are done in situ to assess the ability of the liner specimen to maintain its hydrogen barrier properties and to model its permeability over the tank lifetime. Finally, the model is used to assess whether the steady-state leakage rate in the tank could potentially exceed the leakage specification for hydrogen fuel cell passenger vehicles. A durability assessment was performed on a specimen of high-density polyethylene (HDPE) that is in current use as a tank liner. Hydrogen permeation measurements were performed on several additional tank liner polymers as well as novel polymers proposed for use as storage tank liners and hydrogen barrier materials. The following technical barriers from the Fuel Cell Technologies Program MYRDD were addressed by the project: D. Durability of on-board storage systems lifetime of at least 1500 cycles G. Materials of construction vessel containment that is resistant to hydrogen permeation M. Lack of Tank Performance Data and Understanding of Failure Mechanisms And the following technical targets1 for on-board hydrogen storage systems R&D were likewise addressed: Operational cycle life (1/4 tank to full) FY 2017: 1500 cycles; Ultimate: 1500 cycles Environmental health & safety Permeation and leakage: Meets or exceeds applicable standards Loss of useable H2: FY 2017: 0.05 g/h/kg H2; Ultimate: 0.05 g/h/kg H2

  2. Clay slurry and engineered soils as containment technologies for remediation of contaminated sites

    SciTech Connect (OSTI)

    Williams, J.R.; Dudka, S.; Miller, W.P.; Johnson, D.O.

    1997-12-31

    Clay Slurry and Engineered Soils are containment technologies for remediation of waste disposal sites where leaching, groundwater plumes and surface runoff of contaminants are serious ecological hazards to adjacent environments. This technology is a patent-pending process which involves the use of conditioned clay materials mixed with sand and water to form a readily pourable suspension, a clay slurry, which is either placed into a trench barrier system or allowed to de-water to create Engineered Soils. The Engineered Soil forms a layer impervious to water and air, therefore by inhibiting both water and oxygen from penetrating through the soil the material. This material can be installed in layers and as a vertical barrier to create a surface barrier containment system. The clay percentage in the clay slurry and Engineered Soils varies depending on site characteristics and desired performance standards. For example Engineered Soils with 1-2% of clay (dry wt.) had a hydraulic conductivity (K) of 10{sup -8} to 10{sup -1} cm/sec. Tests of tailing materials from a kyanite and pyrite mine showed that the clay slurry was effective not only in reducing the permeability of the treated tailings, but also in decreasing their acidity due to the inherent alkalinity of the clay. The untreated tailings had pH values in the range of 2.4 - 3.1; whereas, the effluent from clay and tailings mixtures had pH values in a slightly alkaline range (7.7-7.9). Pug-mills and high volume slurry pumps can be readily adapted for use in constructing and placing caps and creating Engineered Soils. Moreover, material on site or from a local sand supply can be used to create clay slurries and engineered soils. Clay materials used in cap construction are likewise readily available commercially. As a result, the clay slurry system is very cost effective compared to other capping systems, including the commonly used High Density Polyethylene (HDPE) liner systems.

  3. Accelerated aging tests of liners for uranium mill tailings disposal

    SciTech Connect (OSTI)

    Barnes, S.M.; Buelt, J.L.; Hale, V.Q.

    1981-11-01

    This document describes the results of accelerated aging tests to determine the long-term effectiveness of selected impoundment liner materials in a uranium mill tailings environment. The study was sponsored by the US Department of Energy under the Uranium Mill Tailings Remedial Action Project. The study was designed to evaluate the need for, and the performance of, several candidate liners for isolating mill tailings leachate in conformance with proposed Environmental Protection Agency and Nuclear Regulatory Commission requirements. The liners were subjected to conditions known to accelerate the degradation mechanisms of the various liners. Also, a test environment was maintained that modeled the expected conditions at a mill tailings impoundment, including ground subsidence and the weight loading of tailings on the liners. A comparison of installation costs was also performed for the candidate liners. The laboratory testing and cost information prompted the selection of a catalytic airblown asphalt membrane and a sodium bentonite-amended soil for fiscal year 1981 field testing.

  4. LIQUID BUTANE FILLED LOAD FOR A LINER DRIVEN PEGASUS EXPERIMENT

    SciTech Connect (OSTI)

    M.A. SALAZAR; W. ANDERSON; ET AL

    2001-06-01

    A hydrogen rich, low density liquid, contained within the internal volume of a cylindrical liner, was requested of the Polymers and Coatings Group (MST-7) of the Los Alamos Materials Science Division for one of the last liner driven experiments conducted on the Los Alamos Pegasus facility. The experiment was a continuation of the Raleigh-Taylor hydrodynamics series of experiments and associated liners that have been described previously [1,2].

  5. Liquid butane filled load for a liner driven Pegasus experiment.

    SciTech Connect (OSTI)

    Salazar, M. A.; Armijo, E. V.; Anderson, W. E.; Atchison, W. L.; Bartos, J. J.; Garcia, F.; Randolph, B.; Sheppard, M. G.; Stokes, J. L.

    2001-01-01

    A hydrogen rich, low density liquid, contained within the internal volume of a cylindrical liner, was requested of the Polymers and Coatings Group (MST-7) of the Los Alamos Materials Science Division for one of the last liner driven experiments conducted on the Los Alamos Pegasus facility. The experiment (Fig.1) was a continuation of the Raleigh-Taylor hydrodynamics series of experiments and associated liners that have been described previously.

  6. Magnetized liner inertial fusion (MagLIF)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Magnetized liner inertial fusion (MagLIF) [1] is an inertial confinement fusion (ICF) scheme using cylindrical compression of magnetized, preheated DT gas. A 10 - 30 T axial magnetic field reduces electron thermal conductivity allowing near-adiabatic compression at implosion velocities of order 100 km/s, much lower than the 300 km/s or more required for conventional ICF. Preheating to at least 100 eV ensures that keV temperatures are reached with a convergence ratio no greater than 30. The

  7. CANMET Gasifier Liner Coupon Material Test Plan

    SciTech Connect (OSTI)

    Mark Fitzsimmons; Alan Darby; Fred Widman

    2005-10-30

    The test plan detailed in this topical report supports Task 1 of the project titled ''Development of Technologies and Capabilities for Coal Energy Resources - Advanced Gasification Systems Development (AGSD)''. The purpose of these tests is to verify that materials planned for use in an advanced gasifier pilot plant will withstand the environments in a commercial gasifier. Pratt & Whitney Rocketdyne (PWR) has developed and designed the cooled liner test assembly article that will be tested at CANMET Energy Technology Centre (CETC-O) in Ottawa, Ontario, Canada (CETC-O). The Test Plan TP-00364 is duplicated in its entirety, with formatting changes to comply with the format required for this Topical Report. The table of contents has been modified to include the additional material required by this topical report. Test Request example and drawings of non-proprietary nature are also included as appendices.

  8. Liners for ion transport membrane systems

    DOE Patents [OSTI]

    Carolan, Michael Francis; Miller, Christopher Francis

    2010-08-10

    Ion transport membrane system comprising (a) a pressure vessel comprising an interior, an exterior, an inlet, an inlet conduit, an outlet, and an outlet conduit; (b) a plurality of planar ion transport membrane modules disposed in the interior of the pressure vessel and arranged in series, each membrane module comprising mixed metal oxide ceramic material and having an interior region and an exterior region, wherein the inlet and the outlet of the pressure vessel are in flow communication with exterior regions of the membrane modules; (c) a gas manifold having an interior surface wherein the gas manifold is in flow communication with the interior region of each of the planar ion transport membrane modules and with the exterior of the pressure vessel; and (d) a liner disposed within any of the inlet conduit, the outlet conduit, and the interior surface of the gas manifold.

  9. Re-Use of Clean Coal Technology By-Products in the Construction of Low Permeability Liners. Final report

    SciTech Connect (OSTI)

    Wolfe, William E.; Butalia, Tarunjit S.; Walker, Harold; Mitsch, William

    2005-07-15

    This final project report presents the results of a research program conducted at The Ohio State University from January 3, 2000 to June 30, 2005 to investigate the long-term use of stabilized flue gas desulfurization (FGD) materials in the construction of low permeability liners for ponds and wetlands. The objective of the research program was to establish long-term field-verified time-dependent relationships for the performance of liners constructed from stabilized FGD byproducts generated in Ohio. The project objective was accomplished with a coordinated program of testing and analyzing small-scale laboratory specimens under controlled conditions, mediumscale wetland experiments, and monitoring of a full-scale FGD-lined pond facility. Although the specific uses directly addressed by this report include liners for surface impoundments, the results presented in this study are also useful in other applications especially in the design of daily covers and liners for landfills, seepage cutoff walls and trenches, and for nutrient retention and pollution mitigation wetlands. The small-scale laboratory tests and monitoring of the full-scale FGD lined facility (capacity of one million gallons) shows that stabilized FGD materials can be used as low permeability liners in the construction of water and manure holding ponds. Actual long-term permeability coefficients in the range of 10-7 cm/sec (3 x 10-9 ft/sec) can be obtained in the field by compacting lime and fly ash enriched stabilized FGD materials. Leachate from the FGD material meets Ohios non-toxic criteria for coal combustion by-products, and for most potential contaminants the national primary and secondary drinking water standards are also met. The low permeability non-toxic FGD material investigated in this study poses very minimal risks, if any, for groundwater contamination. The FGD wetland experiments indicated no significant differences in phosphorus retention between the clay and FGD

  10. On Performance of Covers and Liners In Performance Assessments...

    Office of Environmental Management (EM)

    December 11 and 12, 2014 To view all the P&RA CoP 2014 Technical Exchange Meeting videos click here. Video Presentation PDF icon On Performance of Covers and Liners In...

  11. Re-Use of Clean Coal Technology By-Products in the Construction of Low Permeability Liners. Final report, 10/1/96 3/31/00

    SciTech Connect (OSTI)

    Wolfe, William E.; Butalia, Tarunjit S.; Whitlach, Jr., E. Earl; Mitsch, William

    2000-12-31

    giving rise to the potential use of these materials as a liners for wastewater treatment wetlands. While plant growth was observed to be less vigorous for FGD lined wetland mesocosms compared to the control, the above and below ground biomass were not significantly different. Cost estimates for FGD liners compared favorably with clay liners for varying haul distances.

  12. Expandable Metal Liner For Downhole Components

    DOE Patents [OSTI]

    Hall, David R.; Fox, Joe R.

    2004-10-05

    A liner for an annular downhole component is comprised of an expandable metal tube having indentations along its surface. The indentations are formed in the wall of the tube either by drawing the tube through a die, by hydroforming, by stamping, or roll forming and may extend axially, radially, or spirally along its wall. The indentations accommodate radial and axial expansion of the tube within the downhole component. The tube is inserted into the annular component and deformed to match an inside surface of the component. The tube may be expanded using a hydroforming process or by drawing a mandrel through the tube. The tube may be expanded in such a manner so as to place it in compression against the inside wall of the component. The tube is useful for improving component hydraulics, shielding components from contamination, inhibiting corrosion, and preventing wear to the downhole component during use. It may also be useful for positioning conduit and insulated conductors within the component. An insulating material may be disposed between the tube and the component in order to prevent galvanic corrosion of the downhole component.

  13. Metal liner-driven quasi-isentropic compression of deuterium

    SciTech Connect (OSTI)

    Weinwurm, Marcus; Bland, Simon N.; Chittenden, Jeremy P.

    2013-09-15

    Properties of degenerate hydrogen and deuterium (D) at pressures of the order of terapascals are of key interest to Planetary Science and Inertial Confinement Fusion. In order to recreate these conditions in the laboratory, we present a scheme, where a metal liner drives a cylindrically convergent quasi-isentropic compression in a D fill. We first determined an external pressure history for driving a self-similar implosion of a D shell from a fictitious flow simulation [D. S. Clark and M. Tabak, Nucl. Fusion 47, 1147 (2007)]. Then, it is shown that this D implosion can be recreated inside a beryllium liner by shaping the current pulse. For a peak current of 10.8 MA cold and nearly isochoric D is assembled at around 12 500 kg/m{sup 3}. Finally, our two-dimensional Gorgon simulations show the robustness of the implosion method to the magneto-Rayleigh-Taylor instability when using a sufficiently thick liner.

  14. Diagnosing magnetized liner inertial fusion experiments on Z

    SciTech Connect (OSTI)

    Hansen, Stephanie B.; Gomez, Matthew R.; Sefkow, Adam B.; Slutz, Stephen A.; Sinars, Daniel Brian; Hahn, Kelly; Harding, Eric; Knapp, Patrick; Schmit, Paul; Awe, Thomas James; McBride, Ryan D.; Jennings, Christopher; Geissel, Matthias; Harvey-Thompson, Adam James; Peterson, K. J.; Rovang, Dean C.; Chandler, Gordon A.; Cooper, Gary Wayne; Cuneo, Michael Edward; Herrmann, Mark C.; Mark Harry Hess; Johns, Owen; Lamppa, Derek C.; Martin, Matthew; Porter, J. L.; Robertson, G. K.; Rochau, G. A.; Ruiz, C. L.; Savage, M. E.; Smith, I. C.; Stygar, W. A.; Vesey, R. A.; Blue, B. E.; Ryutov, D.; Schroen, Diana; Tomlinson, K.

    2015-05-14

    The Magnetized Liner Inertial Fusion experiments performed at Sandia's Z facility have demonstrated significant thermonuclear fusion neutron yields (~1012 DD neutrons) from multi-keV deuterium plasmasinertially confined by slow (~10 cm/μs), stable, cylindrical implosions. Moreover, effective magnetic confinement of charged fusion reactants and products is signaled by high secondary DT neutron yields above 1010. Further analysis of extensive power, imaging, and spectroscopicx-ray measurements provides a detailed picture of ~3 keV temperatures, 0.3 g/cm3 densities, gradients, and mix in the fuel and liner over the 1–2 ns stagnation duration.

  15. Diagnosing magnetized liner inertial fusion experiments on Z

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hansen, Stephanie B.; Gomez, Matthew R.; Sefkow, Adam B.; Slutz, Stephen A.; Sinars, Daniel Brian; Hahn, Kelly; Harding, Eric; Knapp, Patrick; Schmit, Paul; Awe, Thomas James; et al

    2015-05-14

    The Magnetized Liner Inertial Fusion experiments performed at Sandia's Z facility have demonstrated significant thermonuclear fusion neutron yields (~1012 DD neutrons) from multi-keV deuterium plasmasinertially confined by slow (~10 cm/μs), stable, cylindrical implosions. Moreover, effective magnetic confinement of charged fusion reactants and products is signaled by high secondary DT neutron yields above 1010. Further analysis of extensive power, imaging, and spectroscopicx-ray measurements provides a detailed picture of ~3 keV temperatures, 0.3 g/cm3 densities, gradients, and mix in the fuel and liner over the 1–2 ns stagnation duration.

  16. Diagnosing magnetized liner inertial fusion experiments on Z

    SciTech Connect (OSTI)

    Hansen, S. B. Gomez, M. R.; Sefkow, A. B.; Slutz, S. A.; Sinars, D. B.; Hahn, K. D.; Harding, E. C.; Knapp, P. F.; Schmit, P. F.; Awe, T. J.; McBride, R. D.; Jennings, C. A.; Geissel, M.; Harvey-Thompson, A. J.; Peterson, K. J.; Rovang, D. C.; Chandler, G. A.; Cooper, G. W.; Cuneo, M. E.; Hess, M. H.; and others

    2015-05-15

    Magnetized Liner Inertial Fusion experiments performed at Sandia's Z facility have demonstrated significant thermonuclear fusion neutron yields (∼10{sup 12} DD neutrons) from multi-keV deuterium plasmas inertially confined by slow (∼10 cm/μs), stable, cylindrical implosions. Effective magnetic confinement of charged fusion reactants and products is signaled by high secondary DT neutron yields above 10{sup 10}. Analysis of extensive power, imaging, and spectroscopic x-ray measurements provides a detailed picture of ∼3 keV temperatures, 0.3 g/cm{sup 3} densities, gradients, and mix in the fuel and liner over the 1–2 ns stagnation duration.

  17. Diagnosing magnetized liner inertial fusion experiments on Z

    SciTech Connect (OSTI)

    Hansen, Stephanie B.; Gomez, Matthew R.; Sefkow, Adam B.; Slutz, Stephen A.; Sinars, Daniel Brian; Hahn, Kelly; Harding, Eric; Knapp, Patrick; Schmit, Paul; Awe, Thomas James; McBride, Ryan D.; Jennings, Christopher; Geissel, Matthias; Harvey-Thompson, Adam James; Peterson, K. J.; Rovang, Dean C.; Chandler, Gordon A.; Cooper, Gary Wayne; Cuneo, Michael Edward; Herrmann, Mark C.; Mark Harry Hess; Johns, Owen; Lamppa, Derek C.; Martin, Matthew; Porter, J. L.; Robertson, G. K.; Rochau, G. A.; Ruiz, C. L.; Savage, M. E.; Smith, I. C.; Stygar, W. A.; Vesey, R. A.; Blue, B. E.; Ryutov, D.; Schroen, Diana; Tomlinson, K.

    2015-05-14

    The Magnetized Liner Inertial Fusion experiments performed at Sandia's Z facility have demonstrated significant thermonuclear fusion neutron yields (~1012 DD neutrons) from multi-keV deuterium plasmasinertially confined by slow (~10 cm/?s), stable, cylindrical implosions. Moreover, effective magnetic confinement of charged fusion reactants and products is signaled by high secondary DT neutron yields above 1010. Further analysis of extensive power, imaging, and spectroscopicx-ray measurements provides a detailed picture of ~3 keV temperatures, 0.3 g/cm3 densities, gradients, and mix in the fuel and liner over the 12 ns stagnation duration.

  18. Evaluation of a stack: A concrete chimney with brick liner

    SciTech Connect (OSTI)

    Joshi, J.R.; Amin, J.A. [Westinghouse Savannah River Co., Aiken, SC (United States); Porthouse, R.A. [Chimney Consultants, West Lebanon, NH (United States)

    1995-12-31

    A 200 ft. tall stack, consisting of a concrete chimney with an independent acid proof brick liner built in the 1950`s, serving the Separations facility at the Savannah River Site (SRS), was evaluated for the performance category 3 (PC3) level of Natural Phenomena Hazards (NPH) effects. The inelastic energy absorption capacity of the concrete chimney was considered in the evaluation of the earthquake resistance, in particular, to compute the F{sub {mu}} factor. The calculated value of F{sub {mu}} exceeded 3.0, while the seismic demand for the PC3 level, using an F{sub {mu}} value of 1.5, was found to be less than the capacity of the concrete chimney. The capacity formulation of ACI 307 was modified to incorporate the effect of an after design opening on the tension side. There are considerable uncertainties in determining the earthquake resistance of the independent brick liner. The critical liner section, located at the bottom of the breeching opening, does not meet the current recommendations. A discussion is provided for the possible acceptable values for the ``Moment Reduction Factor``, R{sub w} or F{sub {mu}} for the liner. Comments are provided on the comparison of stack demands using response spectra (RS) versus time history (TH) analysis, with and without soil structure interaction (SSI) effects.

  19. Quantum Chemistry of CO2 Interaction with Swelling Clays | netl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of CO2 Interaction with Swelling Clays Quantum Chemistry of CO2 Interaction with Swelling Clays Ubiquitous clay minerals can play an important role in assessing the ...

  20. Consideration of liners and covers in performance assessments

    SciTech Connect (OSTI)

    Phifer, Mark A.; Seitz, Robert R.; Suttora, Linda C.

    2014-09-18

    On-site disposal cells are in use and being considered at several United States Department of Energy (USDOE) sites as the final disposition for large amounts of waste associated with cleanup of contaminated areas and facilities. These disposal cells are typically regulated by States and/or the U.S. Environmental Protection Agency under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) in addition to having to comply with requirements in DOE Order 435.1, Radioactive Waste Management due to the radioactive waste. The USDOE-Environmental Management Office of Site Restoration formed a working group to foster improved communication and sharing of information for personnel associated with these CERCLA disposal cells and work towards more consistent assumptions, as appropriate, for technical and policy considerations related to CERCLA risk assessments and DOE Order 435.1 performance assessments in support of a Record of Decision and Disposal Authorization Statement, respectively. One of the issues considered by the working group, which is addressed in this report, was how to appropriately consider the performance of covers and liners/leachate collections systems in the context of a DOE Order 435.1 performance assessment (PA). This same information may be appropriate for consideration within CERCLA risk assessments for these facilities. These OSDCs are generally developed to meet hazardous waste (HW) disposal design standards under the Resource Conservation and Recovery Act (RCRA) as well as the DOE Order 435.1 performance based standards for disposal of radioactive waste. To meet the standards for HW, the facilities typically include engineered covers and liner/leachate collection systems. Thus, when considering such facilities in the context of a DOE Order 435.1 PA, there is a need to address the evolution of performance of covers and liner/leachate collection systems in the context of meeting a performance standard considering time

  1. Potassium hydroxide clay stabilization process

    SciTech Connect (OSTI)

    Sydansk, R.

    1981-07-28

    An aqueous solution having potassium hydroxide dissolved therein is injected into a subterranean sandstone formation containing water-sensitive fine particles, including clays. Potassium hydroxide stabilizes the fine particles for a substantial period of time thereby substantially preventing formation permeability damage caused by encroachment of aqueous solutions having a distinct ionic makeup into the treated formation.

  2. Clay Electric Coop Inc | Open Energy Information

    Open Energy Info (EERE)

    Clay Electric Coop Inc Jump to: navigation, search Name: Clay Electric Coop Inc Place: Illinois Phone Number: 1-800-582-9012 Website: www.clayelectric.com Facebook: https:...

  3. Clay complexes support HDS catalyst.

    SciTech Connect (OSTI)

    Marshall, C. L.; Carrado, K.; Chemical Engineering

    2000-01-01

    Hydroprocessing represents a crucial component of petroleum refining operations both in terms of environmental and economic considerations. Regulations concerning maximum amount of sulfur content of gasoline and emissions of sulfur-oxide compounds upon combustion are becoming more and more stringent. One 1994-2000 focus of Argonne National Laboratory (ANL) has been the development of catalysts for hydrodesulfurization (HDS). Typical HDS catalysts are comprised of Co-Mo sulfides or Ni-Mo sulfides on an alumina support. Modification of the pore structure of the support has generated great attention among researchers. Most desulfurization test reactions have used dibenzothiophene (DBT) as the model compound to test various configurations of support material with Co-Mo-S and Ni-Mo-S catalysts. In this testing, the desired product would be biphenyl and hydrogen sulfide (H{sub 2}S). A competing reaction creates cyclohexylbenzene by saturating one aromatic ring prior to desulfurization. Ring saturation requires more costly hydrogen and is not desirable. Fortunately, a more effective catalyst for adding hydrogen at the sulfur site with hydrogenating the aromatic rings has been found. However, this has only been tested on DBT. HDS uses various types of catalysts to add hydrogen to reduce unwanted sulfur compounds. Typically this requires expensive, high-pressure, high-temperature equipment to produce the environmentally friendly low-sulfur fuels. ANL scientists identified several new desulfurization catalysts with improved HDS activity and selectivity. From these new catalysts, it may be possible to achieve HDS processing at lower temperature and pressure. The catalysts used for HDS at ANL are various clay complexes. Natural clays have a history of use in the hydroprocessing industry since they are abundant and inexpensive. ANL's approach is to create synthetic organo-clay complexes (SOCC). An advantage of SOCCs is that the pore size and distribution can be controlled by

  4. A comparison of portable and permanent landfill liner leak detection systems

    SciTech Connect (OSTI)

    Taylor, S.B.; White, C.C.; Barker, R.D.

    1999-07-01

    Monitoring of the integrity of electrically non-conductive geomembrane liners installed at waste sites using electrical geophysical techniques has been carried out for a number of years using above-liner leak location surveys and, more recently, below-liner monitoring systems. The authors compare the theoretical response of both types of survey to a hole in a liner and then compare with measurements made in the field. The theoretical leak response indicates that above-liner surveys are sensitive to leaks over a greater area, though both responses result in comparable leak detectability. However, field data suggest that in practice, measurements made on a sparse grid below the liner have the greater sensitivity to certain leaks. This may be due to the differing leak geometries and background conditions present above and below the liner. The results indicate that a sparse below-liner monitoring grid, with its long-term monitoring capabilities, combined with above-liner surveys to pinpoint leaks accurately offer a successful approach to ensuring liner integrity throughout the lifetime of a lined waste site.

  5. Micro-beam friction liner and method of transferring energy

    DOE Patents [OSTI]

    Mentesana, Charles

    2007-07-17

    A micro-beam friction liner adapted to increase performance and efficiency and reduce wear in a piezoelectric motor or actuator or other device using a traveling or standing wave to transfer energy in the form of torque and momentum. The micro-beam friction liner comprises a dense array of micro-beam projections having first ends fixed relative to a rotor and second ends projecting substantially toward a plurality of teeth of a stator, wherein the micro-beam projections are compressed and bent during piezoelectric movement of the stator teeth, thereby storing the energy, and then react against the stator teeth to convert the stored energy stored to rotational energy in the rotor.

  6. Reliability-based condition assessment of steel containment and liners

    SciTech Connect (OSTI)

    Ellingwood, B.; Bhattacharya, B.; Zheng, R.

    1996-11-01

    Steel containments and liners in nuclear power plants may be exposed to aggressive environments that may cause their strength and stiffness to decrease during the plant service life. Among the factors recognized as having the potential to cause structural deterioration are uniform, pitting or crevice corrosion; fatigue, including crack initiation and propagation to fracture; elevated temperature; and irradiation. The evaluation of steel containments and liners for continued service must provide assurance that they are able to withstand future extreme loads during the service period with a level of reliability that is sufficient for public safety. Rational methodologies to provide such assurances can be developed using modern structural reliability analysis principles that take uncertainties in loading, strength, and degradation resulting from environmental factors into account. The research described in this report is in support of the Steel Containments and Liners Program being conducted for the US Nuclear Regulatory Commission by the Oak Ridge National Laboratory. The research demonstrates the feasibility of using reliability analysis as a tool for performing condition assessments and service life predictions of steel containments and liners. Mathematical models that describe time-dependent changes in steel due to aggressive environmental factors are identified, and statistical data supporting the use of these models in time-dependent reliability analysis are summarized. The analysis of steel containment fragility is described, and simple illustrations of the impact on reliability of structural degradation are provided. The role of nondestructive evaluation in time-dependent reliability analysis, both in terms of defect detection and sizing, is examined. A Markov model provides a tool for accounting for time-dependent changes in damage condition of a structural component or system. 151 refs.

  7. Large Eddy Simulations of Combustor Liner Flows | Argonne Leadership

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computing Facility droplets. Large Eddy Simulations of a GE CFM combustor, temperature distribution and liquid fuel droplets. Anne Dord, GE Global Research Large Eddy Simulations of Combustor Liner Flows PI Name: Anne Dord PI Email: anne.dord@ge.com Institution: GE Global Research Allocation Program: INCITE Allocation Hours at ALCF: 75 Million Year: 2014 Research Domain: Engineering Aviation gas turbine engines are an essential part of the transportation industry. In 2012, the commercial

  8. Large Eddy Simulations of Combustor Liner Flows | Argonne Leadership

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computing Facility droplets Large Eddy Simulations of a GE CFM combustor, temperature distribution and liquid fuel droplets. Credit: Anne Dord, GE Global Research Large Eddy Simulations of Combustor Liner Flows PI Name: Anne Dord PI Email: anne.dord@ge.com Institution: GE Global Research Allocation Program: INCITE Allocation Hours at ALCF: 89 Million Year: 2015 Research Domain: Engineering In 2012, the commercial aviation industry spent an estimated $207 billion on fuel, or about 33 percent

  9. Large Eddy Simulations of Combustor Liner Flows | Argonne Leadership

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computing Facility Turbulent flow going through a multi-hole coupon geometry Turbulent flow going through a multi-hole coupon geometry. Density iso surface colored by velocity magnitude. Joseph Insley, Argonne National Laboratory; Lee Shunn, Cascade Technologies; Anne Dord, GE Aviation; and Yonduck Sung, GE Global Research Large Eddy Simulations of Combustor Liner Flows PI Name: Anne Dord PI Email: anne.dord@ge.com Institution: GE Aviation Allocation Program: INCITE Allocation Hours at ALCF:

  10. A semi-analytic model of magnetized liner inertial fusion

    SciTech Connect (OSTI)

    McBride, Ryan D.; Slutz, Stephen A.

    2015-05-15

    Presented is a semi-analytic model of magnetized liner inertial fusion (MagLIF). This model accounts for several key aspects of MagLIF, including: (1) preheat of the fuel (optionally via laser absorption); (2) pulsed-power-driven liner implosion; (3) liner compressibility with an analytic equation of state, artificial viscosity, internal magnetic pressure, and ohmic heating; (4) adiabatic compression and heating of the fuel; (5) radiative losses and fuel opacity; (6) magnetic flux compression with Nernst thermoelectric losses; (7) magnetized electron and ion thermal conduction losses; (8) end losses; (9) enhanced losses due to prescribed dopant concentrations and contaminant mix; (10) deuterium-deuterium and deuterium-tritium primary fusion reactions for arbitrary deuterium to tritium fuel ratios; and (11) magnetized α-particle fuel heating. We show that this simplified model, with its transparent and accessible physics, can be used to reproduce the general 1D behavior presented throughout the original MagLIF paper [S. A. Slutz et al., Phys. Plasmas 17, 056303 (2010)]. We also discuss some important physics insights gained as a result of developing this model, such as the dependence of radiative loss rates on the radial fraction of the fuel that is preheated.

  11. Contact micromechanics in granular media with clay

    SciTech Connect (OSTI)

    Ita, S.L.

    1994-08-01

    Many granular materials, including sedimentary rocks and soils, contain clay particles in the pores, grain contacts, or matrix. The amount and location of the clays and fluids can influence the mechanical and hydraulic properties of the granular material. This research investigated the mechanical effects of clay at grain-to-grain contacts in the presence of different fluids. Laboratory seismic wave propagation tests were conducted at ultrasonic frequencies using spherical glass beads coated with Montmorillonite clay (SWy-1) onto which different fluids were adsorbed. For all bead samples, seismic velocity increased and attenuation decreased as the contact stiffnesses increased with increasing stress demonstrating that grain contacts control seismic transmission in poorly consolidated and unconsolidated granular material. Coating the beads with clay added stiffness and introduced viscosity to the mechanical contact properties that increased the velocity and attenuation of the propagating seismic wave. Clay-fluid interactions were studied by allowing the clay coating to absorb water, ethyl alcohol, and hexadecane. Increasing water amounts initially increased seismic attenuation due to clay swelling at the contacts. Attenuation decreased for higher water amounts where the clay exceeded the plastic limit and was forced from the contact areas into the surrounding open pore space during sample consolidation. This work investigates how clay located at grain contacts affects the micromechanical, particularly seismic, behavior of granular materials. The need for this work is shown by a review of the effects of clays on seismic wave propagation, laboratory measurements of attenuation in granular media, and proposed mechanisms for attenuation in granular media.

  12. Gas-puff liner implosion in the configuration with helical current return rods

    SciTech Connect (OSTI)

    Sorokin, S. A.

    2013-02-15

    Results of experiments with double-shell gas-puff liners carried out on a high-current MIG generator (2 MA, 80 ns) are presented. To stabilize the process of liner implosion and increase the efficiency of energy transfer from the generator to the liner plasma, a current return in the form of a multifilar helix was used. The effect of the configuration of the current return on the parameters of the generated pulses of argon and neon K-shell radiation (with photon energies of 3-5 and 0.9-1.5 keV, respectively) and the neutron yield from a deuterium liner were studied.

  13. Liner/target/CMU cassette design and fabrication

    SciTech Connect (OSTI)

    Griego, Jeffrey Randall

    2011-01-07

    As part of an ongoing collaboration in pulsed power technology and condensed matter shock physics with RFNCNNIIEF, the initial design for the target and central measuring unit (CMU) for a high-pressure, high-precision ({approx}1 %), Hugoniot, equation of state (EOS) experiment is shown. VNIIEF would design and construct the disk explosive magnetic generator (DEMG) with peak currents {approx}100 MA, and cylindrical liner system with peak velocity {approx}10-20 km/s. LANL would design and construct the target and velocimetry diagnostic system. The initial mechanical design features a 2 cm diameter target system and a 1 cm diameter CMU with 32 lines of sight for PDV.

  14. Clay Electric Cooperative, Inc- Solar Thermal Loans

    Broader source: Energy.gov [DOE]

    Clay Electric Cooperative (CEC), a Touchstone Energy Cooperative, covers 14 counties in northern Florida, including Gainesville, Keystone Heights, Lake City, Orange Park, Palatka, and Salt Springs....

  15. Clay Electric Cooperative, Inc- Energy Conservation Loans

    Office of Energy Efficiency and Renewable Energy (EERE)

    Clay Electric Cooperative (CEC), a Touchstone Energy Cooperative, covers 14 North Florida counties, including Gainesville, Keystone Heights, Lake City, Orange Park, Palatka, and Salt Springs. It...

  16. In situ clay formation : evaluation of a proposed new technology for stable containment barriers.

    SciTech Connect (OSTI)

    Nagy, Kathryn L.; DiGiovanni, Anthony Albert; Fredrich, Joanne T.

    2004-03-01

    Containment of chemical wastes in near-surface and repository environments is accomplished by designing engineered barriers to fluid flow. Containment barrier technologies such as clay liners, soil/bentonite slurry walls, soil/plastic walls, artificially grouted sediments and soils, and colloidal gelling materials are intended to stop fluid transport and prevent plume migration. However, despite their effectiveness in the short-term, all of these barriers exhibit geochemical or geomechanical instability over the long-term resulting in degradation of the barrier and its ability to contain waste. No technologically practical or economically affordable technologies or methods exist at present for accomplishing total remediation, contaminant removal, or destruction-degradation in situ. A new type of containment barrier with a potentially broad range of environmental stability and longevity could result in significant cost-savings. This report documents a research program designed to establish the viability of a proposed new type of containment barrier derived from in situ precipitation of clays in the pore space of contaminated soils or sediments. The concept builds upon technologies that exist for colloidal or gel stabilization. Clays have the advantages of being geologically compatible with the near-surface environment and naturally sorptive for a range of contaminants, and further, the precipitation of clays could result in reduced permeability and hydraulic conductivity, and increased mechanical stability through cementation of soil particles. While limited success was achieved under certain controlled laboratory conditions, the results did not warrant continuation to the field stage for multiple reasons, and the research program was thus concluded with Phase 2.

  17. Tank 241-AY-102 Secondary Liner Corrosion Evaluation - 14191

    SciTech Connect (OSTI)

    Boomer, Kayle D.; Washenfelder, Dennis J.; Johnson, Jeremy M.

    2014-01-07

    In October 2012, Washington River Protection Solutions, LLC (WRPS) determined that the primary tank of 241-AY-102 (AY-102) was leaking. A number of evaluations were performed after discovery of the leak which identified corrosion from storage of waste at the high waste temperatures as one of the major contributing factors in the failure of the tank. The propensity for corrosion of the waste on the annulus floor will be investigated to determine if it is corrosive and must be promptly removed or if it is benign and may remain in the annulus. The chemical composition of waste, the temperature and the character of the steel are important factors in assessing the propensity for corrosion. Unfortunately, the temperatures of the wastes in contact with the secondary steel liner are not known; they are estimated to range from 45 deg C to 60 deg C. It is also notable that most corrosion tests have been carried out with un-welded, stress-relieved steels, but the secondary liner in tank AY-102 was not stress-relieved. In addition, the cold weather fabrication and welding led to many problems, which required repeated softening of the metal to flatten secondary bottom during its construction. This flame treatment may have altered the microstructure of the steel.

  18. FIREBALL: Fusion Ignition Rocket Engine with Ballistic Ablative Lithium Liner

    SciTech Connect (OSTI)

    Martin, Adam K.; Eskridge, Richard H.; Lee, Michael H.; Fimognari, Peter J.

    2006-01-20

    Thermo-nuclear fusion may be the key to a high Isp, high specific power propulsion system. In a fusion system energy is liberated within, and imparted directly to, the propellant. In principle, this can overcome the performance limitations inherent in systems that require thermal power transfer across a material boundary, and/or multiple power conversion stages (NTR, NEP). A thermo-nuclear propulsion system, which attempts to overcome some of the problems inherent in the Orion concept, is described. A dense FRC plasmoid is accelerated to high velocity (in excess of 500 km/s) and is compressed into a detached liner (pulse unit). The kinetic energy of the FRC is converted into thermal and magnetic-field energy, igniting a fusion burn in the magnetically confined plasma. The fusion reaction serves as an ignition source for the liner, which is made out of detonable materials. The energy liberated in this process is converted to thrust by a pusher-plate, as in the classic Orion concept. However with this concept, the vehicle does not carry a magazine of autonomous pulse-units. By accelerating a second, heavier FRC, which acts as a piston, right behind the first one, the velocity required to initiate the fusion burn is greatly reduced.

  19. Liner evaluation for uranium mill tailings. Final report

    SciTech Connect (OSTI)

    Buelt, J.L. (comp.)

    1983-09-01

    The Liner Evaluation for Uranium Mill Tailings Program was conducted to evaluate the need for and performance of prospective lining materials for the long-term management of inactive uranium mill tailings piles. On the basis of program results, two materials have been identified: natural foundation soil amended with 10% sodium bentonite; catalytic airblown asphalt membrane. The study showed that, for most situations, calcareous soils typical of Western US sites adequately buffer tailings leachates and prevent groundwater contamination without additional liner materials or amendments. Although mathematical modeling of disposal sites is recommended on a site-specific basis, there appears to be no reason to expect significant infiltration through the cover for most Western sites. The major water source through the tailings would be groundwater movement at sites with shallow groundwater tables. Even so column leaching studies showed that contaminant source terms were reduced to near maximum contaminant levels (MCL's) for drinking water within one or two pore volumes; thus, a limited source term for groundwater contamination exists. At sites where significant groundwater movement or infiltration is expected and the tailings leachates are alkaline, however, the sodium bentonite or asphalt membrane may be necessary.

  20. Formation of imploding plasma liners for fundamental HEDP studies and MIF Standoff Driver Concept

    SciTech Connect (OSTI)

    Cassibry, Jason; Hatcher, Richard; Stanic, Milos

    2013-08-17

    The disciplines of High Energy Density Physics (HEDP) and Inertial Confinement Fusion (ICF) are characterized by hypervelocity implosions and strong shocks. The Plasma Liner Experiment (PLX) is focused on reaching HEDP and/or ICF relevant regimes in excess of 1 Mbar peak pressure by the merging and implosion of discrete plasma jets, as a potentially efficient path towards these extreme conditions in a laboratory. In this work we have presented the first 3D simulations of plasma liner, formation, and implosion by the merging of discrete plasma jets in which ionization, thermal conduction, and radiation are all included in the physics model. The study was conducted by utilizing a smoothed particle hydrodynamics code (SPHC) and was a part of the plasma liner experiment (PLX). The salient physics processes of liner formation and implosion are studied, namely vacuum propagation of plasma jets, merging of the jets (liner forming), implosion (liner collapsing), stagnation (peak pressure), and expansion (rarefaction wave disassembling the target). Radiative transport was found to significantly reduce the temperature of the liner during implosion, thus reducing the thermal leaving more pronounced gradients in the plasma liner during the implosion compared with ideal hydrodynamic simulations. These pronounced gradients lead to a greater sensitivity of initial jet geometry and symmetry on peak pressures obtained. Accounting for ionization and transport, many cases gave higher peak pressures than the ideal hydrodynamic simulations. Scaling laws were developed accordingly, creating a non-dimensional parameter space in which performance of an imploding plasma jet liner can be estimated. It is shown that HEDP regimes could be reached with ~ 5 MJ of liner energy, which would translate to roughly 10 to 20 MJ of stored (capacitor) energy. This is a potentially significant improvement over the currently available means via ICF of achieving HEDP and nuclear fusion relevant parameters.

  1. Active containment systems incorporating modified pillared clays

    SciTech Connect (OSTI)

    Lundie, P. |; McLeod, N.

    1997-12-31

    The application of treatment technologies in active containment systems provides a more advanced and effective method for the remediation of contaminated sites. These treatment technologies can be applied in permeable reactive walls and/or funnel and gate systems. The application of modified pillared clays in active containment systems provides a mechanism for producing permeable reactive walls with versatile properties. These pillared clays are suitably modified to incorporate reactive intercalatants capable of reacting with both a broad range of organic pollutants of varying molecular size, polarity and reactivity. Heavy metals can be removed from contaminated water by conventional ion-exchange and other reactive processes within the clay structure. Complex contamination problems can be addressed by the application of more than one modified clay on a site specific basis. This paper briefly describes the active containment system and the structure/chemistry of the modified pillared clay technology, illustrating potential applications of the in-situ treatment process for contaminated site remediation.

  2. Energy transfer through a multi-layer liner for shaped charges

    DOE Patents [OSTI]

    Skolnick, Saul; Goodman, Albert

    1985-01-01

    This invention relates to the determination of parameters for selecting materials for use as liners in shaped charges to transfer the greatest amount of energy to the explosive jet. Multi-layer liners constructed of metal in shaped charges for oil well perforators or other applications are selected in accordance with the invention to maximize the penetrating effect of the explosive jet by reference to four parameters: (1) Adjusting the explosive charge to liner mass ratio to achieve a balance between the amount of explosive used in a shaped charge and the areal density of the liner material; (2) Adjusting the ductility of each layer of a multi-layer liner to enhance the formation of a longer energy jet; (3) Buffering the intermediate layers of a multi-layer liner by varying the properties of each layer, e.g., composition, thickness, ductility, acoustic impedance and areal density, to protect the final inside layer of high density material from shattering upon impact of the explosive force and, instead, flow smoothly into a jet; and (4) Adjusting the impedance of the layers in a liner to enhance the transmission and reduce the reflection of explosive energy across the interface between layers.

  3. Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide, Brine, and Clay ...

  4. Clay County, Missouri: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Registered Energy Companies in Clay County, Missouri Alternative Energy Sources Inc Smith Electric Vehicles US SEV US Registered Financial Organizations in Clay County,...

  5. Nonlinear Laser-Plasma Interaction in Magnetized Liner Inertial Fusion

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Geissel, Matthias; Awe, Thomas James; Bliss, David E.; Campbell, Edward Michael; Gomez, Matthew R.; Harding, Eric; Harvey-Thompson, Adam James; Hansen, Stephanie B.; Jennings, Christopher Ashley; Kimmel, Mark W.; et al

    2016-03-04

    Sandia National Laboratories is pursuing a variation of Magneto-Inertial Fusion called Magnetized Liner Inertial Fusion, or MagLIF. The MagLIF approach requires magnetization of the deuterium fuel, which is accomplished by an initial external B-Field and laser-driven pre-heat. Although magnetization is crucial to the concept, it is challenging to couple sufficient energy to the fuel, since laser-plasma instabilities exist, and a compromise between laser spot size, laser entrance window thickness, and fuel density must be found. Ultimately, nonlinear processes in laser plasma interaction, or laser-plasma instabilities (LPI), complicate the deposition of laser energy by enhanced absorption, backscatter, filamentation and beam-spray. Wemore » determine and discuss key LPI processes and mitigation methods. Results with and without improvement measures are presented.« less

  6. Method and apparatus for monitoring the integrity of a geomembrane liner using time domain reflectometry

    DOE Patents [OSTI]

    Morrison, John L.

    2001-04-24

    Leaks are detected in a multi-layered geomembrane liner by a two-dimensional time domain reflectometry (TDR) technique. The TDR geomembrane liner is constructed with an electrically conductive detection layer positioned between two electrically non-conductive dielectric layers, which are each positioned between the detection layer and an electrically conductive reference layer. The integrity of the TDR geomembrane liner is determined by generating electrical pulses within the detection layer and measuring the time delay for any reflected electrical energy caused by absorption of moisture by a dielectric layer.

  7. Formation of Imploding Plasma Liners for HEDP and MIF Application

    SciTech Connect (OSTI)

    Witherspoon, F. Douglas; Case, Andrew; Brockington, Samuel; Messer, Sarah; Bomgardner, Richard; Phillips, Mike; Wu, Linchun; Elton, Ray

    2014-11-11

    Plasma jets with high density and velocity have a number of important applications in fusion energy and elsewhere, including plasma refueling, disruption mitigation in tokamaks, magnetized target fusion, injection of momentum into centrifugally confined mirrors, plasma thrusters, and high energy density plasmas (HEDP). In Magneto-Inertial Fusion (MIF), for example, an imploding material liner is used to compress a magnetized plasma to fusion conditions and to confine the resulting burning plasma inertially to obtain the necessary energy gain. The imploding shell may be solid, liquid, gaseous, or a combination of these states. The presence of the magnetic field in the target plasma suppresses thermal transport to the plasma shell, thus lowering the imploding power needed to compress the target to fusion conditions. This allows the required imploding momentum flux to be generated electromagnetically using off-the-shelf pulsed power technology. Practical schemes for standoff delivery of the imploding momentum flux are required and are open topics for research. One approach for accomplishing this, called plasma jet driven magneto-inertial fusion (PJMIF), uses a spherical array of pulsed plasma guns to create a spherically imploding shell of very high velocity, high momentum flux plasma. This approach requires development of plasma jet accelerators capable of achieving velocities of 50-200 km/s with very precise timing and density profiles, and with high total mass and density. Low-Z plasma jets would require the higher velocities, whereas very dense high-Z plasma shells could achieve the goal at velocities of only 50-100 km/s. In this report, we describe our work to develop the pulsed plasma gun technology needed for an experimental scientific exploration of the PJMIF concept, and also for the other applications mentioned earlier. The initial goal of a few hundred of hydrogen at 200 km/s was eventually replaced with accelerating 8000 μg of argon or xenon to 50 km

  8. Clay Electric Cooperative, Inc | Open Energy Information

    Open Energy Info (EERE)

    Inc Place: Florida Phone Number: 1-888-434-9844 Website: www.clayelectric.com Facebook: https:www.facebook.comClayElectric Outage Hotline: 1-888-434-9844 Outage Map:...

  9. Experimental demonstration of the stabilizing effect of dielectric coatings on magnetically accelerated imploding metallic liners

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Awe, Thomas James; Peterson, Kyle J.; Yu, Edmund P.; McBride, Ryan D.; Sinars, Daniel B.; Gomez, Matthew R.; Jennings, Christopher Ashley; Martin, Matthew R.; Rosenthal, Stephen E.; Sefkow, Adam B.; et al

    2016-02-10

    Enhanced implosion stability has been experimentally demonstrated for magnetically accelerated liners that are coated with 70 μm of dielectric. The dielectric tamps liner-mass redistribution from electrothermal instabilities and also buffers coupling of the drive magnetic field to the magneto-Rayleigh-Taylor instability. A dielectric-coated and axially premagnetized beryllium liner was radiographed at a convergence ratio [CR=Rin,0/Rin(z,t)] of 20, which is the highest CR ever directly observed for a strengthless magnetically driven liner. Lastly, the inner-wall radius Rin(z,t) displayed unprecedented uniformity, varying from 95 to 130 μm over the 4.0 mm axial height captured by the radiograph.

  10. On the efficacy of imploding plasma liners for magnetized fusion target compression

    SciTech Connect (OSTI)

    Parks, P. B.

    2008-06-15

    A new theoretical model is formulated to study the idea of merging a spherical array of converging plasma jets to form a 'plasma liner' that further converges to compress a magnetized plasma target to fusion conditions [Y. C. F. Thio et al., 'Magnetized target fusion in a spheroidal geometry with standoff drivers', Current Trends in International Fusion Research II, edited by E. Panarella (National Research Council Canada, Ottawa, Canada, 1999)]. For a spherically imploding plasma liner shell with high initial Mach number (M=liner speed/sound speed) the rise in liner density with decreasing radius r goes as {rho}{approx}1/r{sup 2}, for any constant adiabatic index {gamma}=d ln p/d ln {rho}. Accordingly, spherical convergence amplifies the ram pressure of the liner on target by the factor A{approx}C{sup 2}, indicating strong coupling to its radial convergence C=r{sub m}/R, where r{sub m}(R)=jet merging radius (compressed target radius), and A=compressed target pressure/initial liner ram pressure. Deuterium-tritium (DT) plasma liners with initial velocity {approx}100 km/s and {gamma}=5/3, need to be hypersonic M{approx}60 and thus cold in order to realize values of A{approx}10{sup 4} necessary for target ignition. For optically thick DT liners, T<2 eV, n>10{sup 19}-10{sup 20} cm{sup -3}, blackbody radiative cooling is appreciable and may counteract compressional heating during the later stages of the implosion. The fluid then behaves as if the adiabatic index were depressed below 5/3, which in turn means that the same amplification A=1.6x10{sup 4} can be accomplished with a reduced initial Mach number M{approx_equal}12.7({gamma}-0.3){sup 4.86}, valid in the range (10liners assembled by current and anticipated plasma jets is <4%. A new similarity model for fusion {alpha}-particle heating of the collapsed liner indicates that 'spark' ignition of the DT liner fuel does not appear to be

  11. Testing of hollow clay tile masonry prisms

    SciTech Connect (OSTI)

    Jones, W.D.; Butala, M.B.

    1993-10-15

    This paper presents test results of 610-mm wide (24-in.) by 1219-mm high (48-in.) by 203-or 330-mm (8- or 13-in.) thick prisms constructed of hollow clay tiles. Three prisms were extracted fro existing hollow clay title walls and 69 were constructed in laboratories at The University of Tennessee and the National Institute of Standards and Technology (NIST) in Gaithersburg, Maryland. Modulus of Elasticity, E, and compressive strength f{prime}{sub m} were calculated from the results.

  12. Nuclear containment steel liner corrosion workshop : final summary and recommendation report.

    SciTech Connect (OSTI)

    Erler, Bryan A.; Weyers, Richard E.; Sagues, Alberto; Petti, Jason P.; Berke, Neal Steven; Naus, Dan J.

    2011-07-01

    This report documents the proceedings of an expert panel workshop conducted to evaluate the mechanisms of corrosion for the steel liner in nuclear containment buildings. The U.S. Nuclear Regulatory Commission (NRC) sponsored this work which was conducted by Sandia National Laboratories. A workshop was conducted at the NRC Headquarters in Rockville, Maryland on September 2 and 3, 2010. Due to the safety function performed by the liner, the expert panel was assembled in order to address the full range of issues that may contribute to liner corrosion. This report is focused on corrosion that initiates from the outer surface of the liner, the surface that is in contact with the concrete containment building wall. Liner corrosion initiating on the outer diameter (OD) surface has been identified at several nuclear power plants, always associated with foreign material left embedded in the concrete. The potential contributing factors to liner corrosion were broken into five areas for discussion during the workshop. Those include nuclear power plant design and operation, corrosion of steel in contact with concrete, concrete aging and degradation, concrete/steel non-destructive examination (NDE), and concrete repair and corrosion mitigation. This report also includes the expert panel member's recommendations for future research.

  13. Enchanted Clays: 44th Annual Meeting of the Clay Minerals Society (June 2007)

    SciTech Connect (OSTI)

    Randall T. Cygan

    2007-06-01

    “Enchanted Clays: 44th Annual Meeting of the Clay Minerals Society” was held in early June 2007 in beautiful and historic Santa Fe, New Mexico, USA. Santa Fe provided an idyllic location in the southwestern United States for the attendees to enjoy technical and social sessions while soaking up the diverse culture and wonderful climate of New Mexico—The Land of Enchantment. The meeting included a large and varied group of scientists, sharing knowledge and ideas, benefitting from technical interactions, and enjoying the wonderful historic and enchanted environs of Santa Fe. Including significant number of international scientists, the meeting was attended by approximately two hundred participants. The meeting included three days of technical sessions (oral and poster presentations), three days of field trips to clay and geological sites of northern New Mexico, and a full day workshop on the stabilization of carbon by clays. Details can be found at the meeting web site: www.sandia.gov/clay.

  14. Organic or organometallic template mediated clay synthesis

    DOE Patents [OSTI]

    Gregar, Kathleen C.; Winans, Randall E.; Botto, Robert E.

    1994-01-01

    A method for incorporating diverse Varieties of intercalants or templates directly during hydrothermal synthesis of clays such as hectorite or montmorillonite-type layer-silicate clays. For a hectorite layer-silicate clay, refluxing a gel of silica sol, magnesium hydroxide sol and lithium fluoride for two days in the presence of an organic or organometallic intercalant or template results in crystalline products containing either (a) organic dye molecules such as ethyl violet and methyl green, (b) dye molecules such as alcian blue that are based on a Cu(II)-phthalocyannine complex, or (c) transition metal complexes such as Ru(II)phenanthroline and Co(III)sepulchrate or (d) water-soluble porphyrins and metalloporphyrins. Montmorillonite-type clays are made by the method taught by U.S. Pat. No. 3,887,454 issued to Hickson, Jun. 13, 1975; however, a variety of intercalants or templates may be introduced. The intercalants or templates should have (i) water-solubility, (ii) positive charge, and (iii) thermal stability under moderately basic (pH 9-10) aqueous reflux conditions or hydrothermal pressurized conditions for the montmorillonite-type clays.

  15. Organic or organometallic template mediated clay synthesis

    DOE Patents [OSTI]

    Gregar, K.C.; Winans, R.E.; Botto, R.E.

    1994-05-03

    A method is described for incorporating diverse varieties of intercalates or templates directly during hydrothermal synthesis of clays such as hectorite or montmorillonite-type layer-silicate clays. For a hectorite layer-silicate clay, refluxing a gel of silica sol, magnesium hydroxide sol and lithium fluoride for two days in the presence of an organic or organometallic intercalate or template results in crystalline products containing either (a) organic dye molecules such as ethyl violet and methyl green, (b) dye molecules such as alcian blue that are based on a Cu(II)-phthalocyannine complex, or (c) transition metal complexes such as Ru(II)phenanthroline and Co(III)sepulchrate or (d) water-soluble porphyrins and metalloporphyrins. Montmorillonite-type clays are made by the method taught by U.S. Pat. No. 3,887,454 issued to Hickson, Jun. 13, 1975; however, a variety of intercalates or templates may be introduced. The intercalates or templates should have (i) water-solubility, (ii) positive charge, and (iii) thermal stability under moderately basic (pH 9-10) aqueous reflux conditions or hydrothermal pressurized conditions for the montmorillonite-type clays. 22 figures.

  16. Study of Plasma Liner Driven Magnetized Target Fusion Via Advanced Simulations

    SciTech Connect (OSTI)

    Samulyak, Roman V.; Parks, Paul

    2013-08-31

    The feasibility of the plasma liner driven Magnetized Target Fusion (MTF) via terascale numerical simulations will be assessed. In the MTF concept, a plasma liner, formed by merging of a number (60 or more) of radial, highly supersonic plasma jets, implodes on the target in the form of two compact plasma toroids, and compresses it to conditions of the fusion ignition. By avoiding major difficulties associated with both the traditional laser driven inertial confinement fusion and solid liner driven MTF, the plasma liner driven MTF potentially provides a low-cost and fast R&D path towards the demonstration of practical fusion energy. High fidelity numerical simulations of full nonlinear models associated with the plasma liner MTF using state-of-art numerical algorithms and terascale computing are necessary in order to resolve uncertainties and provide guidance for future experiments. At Stony Brook University, we have developed unique computational capabilities that ideally suite the MTF problem. The FronTier code, developed in collaboration with BNL and LANL under DOE funding including SciDAC for the simulation of 3D multi-material hydro and MHD flows, has beenbenchmarked and used for fundamental and engineering problems in energy science applications. We have performed 3D simulations of converging supersonic plasma jets, their merger and the formation of the plasma liner, and a study of the corresponding oblique shock problem. We have studied the implosion of the plasma liner on the magnetized plasma target by resolving Rayleigh-Taylor instabilities in 2D and 3D and other relevant physics and estimate thermodynamic conditions of the target at the moment of maximum compression and the hydrodynamic efficiency of the method.

  17. Demonstration of thermonuclear conditions in magnetized liner inertial fusion experiments

    SciTech Connect (OSTI)

    Gomez, Matthew R.; Slutz, Stephen A.; Sefkow, Adam B.; Hahn, Kelly D.; Hansen, Stephanie B.; Knapp, Patrick F.; Schmit, Paul F.; Ruiz, Carlos L.; Sinars, Daniel Brian; Harding, Eric C.; Jennings, Christopher A.; Awe, Thomas James; Geissel, Matthias; Rovang, Dean C.; Smith, Ian C.; Chandler, Gordon A.; Cooper, Gary Wayne; Cuneo, Michael Edward; Harvey-Thompson, Adam James; Herrmann, Mark C.; Hess, Mark Harry; Lamppa, Derek C.; Martin, Matthew R.; McBride, Ryan D.; Peterson, Kyle J.; Porter, John L.; Rochau, Gregory A.; Savage, Mark E.; Schroen, Diana G.; Stygar, William A.; Vesey, Roger Alan

    2015-04-29

    In this study, the magnetized liner inertial fusion concept [S. A. Slutz et al., Phys. Plasmas17, 056303 (2010)] utilizes a magnetic field and laser heating to relax the pressure requirements of inertial confinement fusion. The first experiments to test the concept [M. R. Gomez et al., Phys. Rev. Lett. 113, 155003 (2014)] were conducted utilizing the 19 MA, 100 ns Z machine, the 2.5 kJ, 1 TW Z Beamlet laser, and the 10 T Applied B-field on Z system. Despite an estimated implosion velocity of only 70 km/s in these experiments, electron and ion temperatures at stagnation were as high as 3 keV, and thermonuclear deuterium-deuterium neutron yields up to 2 1012 have been produced. X-ray emission from the fuel at stagnation had widths ranging from 50 to 110 ?m over a roughly 80% of the axial extent of the target (68 mm) and lasted approximately 2 ns. X-ray yields from these experiments are consistent with a stagnation density of the hot fuel equal to 0.20.4 g/cm3. In these experiments, up to 5 1010 secondary deuterium-tritium neutrons were produced. Given that the areal density of the plasma was approximately 12 mg/cm2, this indicates the stagnation plasma was significantly magnetized, which is consistent with the anisotropy observed in the deuterium-tritium neutron spectra. Control experiments where the laser and/or magnetic field were not utilized failed to produce stagnation temperatures greater than 1 keV and primary deuterium-deuterium yields greater than 1010. An additional control experiment where the fuel contained a sufficient dopant fraction to substantially increase radiative losses also failed to produce a relevant stagnation temperature. The results of these experiments are consistent with a thermonuclear neutron source.

  18. Demonstration of thermonuclear conditions in magnetized liner inertial fusion experiments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gomez, Matthew R.; Slutz, Stephen A.; Sefkow, Adam B.; Hahn, Kelly D.; Hansen, Stephanie B.; Knapp, Patrick F.; Schmit, Paul F.; Ruiz, Carlos L.; Sinars, Daniel Brian; Harding, Eric C.; et al

    2015-04-29

    In this study, the magnetized liner inertial fusion concept [S. A. Slutz et al., Phys. Plasmas17, 056303 (2010)] utilizes a magnetic field and laser heating to relax the pressure requirements of inertial confinement fusion. The first experiments to test the concept [M. R. Gomez et al., Phys. Rev. Lett. 113, 155003 (2014)] were conducted utilizing the 19 MA, 100 ns Z machine, the 2.5 kJ, 1 TW Z Beamlet laser, and the 10 T Applied B-field on Z system. Despite an estimated implosion velocity of only 70 km/s in these experiments, electron and ion temperatures at stagnation were as highmore » as 3 keV, and thermonuclear deuterium-deuterium neutron yields up to 2 × 1012 have been produced. X-ray emission from the fuel at stagnation had widths ranging from 50 to 110 μm over a roughly 80% of the axial extent of the target (6–8 mm) and lasted approximately 2 ns. X-ray yields from these experiments are consistent with a stagnation density of the hot fuel equal to 0.2–0.4 g/cm3. In these experiments, up to 5 ×1010 secondary deuterium-tritium neutrons were produced. Given that the areal density of the plasma was approximately 1–2 mg/cm2, this indicates the stagnation plasma was significantly magnetized, which is consistent with the anisotropy observed in the deuterium-tritium neutron spectra. Control experiments where the laser and/or magnetic field were not utilized failed to produce stagnation temperatures greater than 1 keV and primary deuterium-deuterium yields greater than 1010. An additional control experiment where the fuel contained a sufficient dopant fraction to substantially increase radiative losses also failed to produce a relevant stagnation temperature. The results of these experiments are consistent with a thermonuclear neutron source.« less

  19. Microsoft Word - Clay Memo PMC Coburn Obama 11_9_06.doc | Department...

    Office of Environmental Management (EM)

    Clay Memo PMC Coburn Obama 11906.doc Microsoft Word - Clay Memo PMC Coburn Obama 11906.doc Microsoft Word - Clay Memo PMC Coburn Obama 11906.doc More Documents & Publications...

  20. Inductively Driven, 3D Liner Compression of a Magnetized Plasma to Megabar Energy Densities

    SciTech Connect (OSTI)

    Slough, John

    2015-02-01

    To take advantage of the smaller scale, higher density regime of fusion an efficient method for achieving the compressional heating required to reach fusion gain conditions must be found. What is proposed is a more flexible metallic liner compression scheme that minimizes the kinetic energy required to reach fusion. It is believed that it is possible to accomplish this at sub-megajoule energies. This however will require operation at very small scale. To have a realistic hope of inexpensive, repetitive operation, it is essential to have the liner kinetic energy under a megajoule which allows for the survivability of the vacuum and power systems. At small scale the implosion speed must be reasonably fast to maintain the magnetized plasma (FRC) equilibrium during compression. For limited liner kinetic energy, it becomes clear that the thinnest liner imploded to the smallest radius consistent with the requirements for FRC equilibrium lifetime is desired. The proposed work is directed toward accomplishing this goal. Typically an axial (Z) current is employed for liner compression. There are however several advantages to using a θ-pinch coil. With the θ-pinch the liner currents are inductively driven which greatly simplifies the apparatus and vacuum system, and avoids difficulties with the post implosion vacuum integrity. With fractional flux leakage, the foil liner automatically provides for the seed axial compression field. To achieve it with optimal switching techniques, and at an accelerated pace however will require additional funding. This extra expense is well justified as the compression technique that will be enabled by this funding is unique in the ability to implode individual segments of the liner at different times. This is highly advantageous as the liner can be imploded in a manner that maximizes the energy transfer to the FRC. Production of shaped liner implosions for additional axial compression can thus be readily accomplished with the modified power

  1. Early time studies of cylindrical liner implosions at 1 MA on COBRA

    SciTech Connect (OSTI)

    Atoyan, L. Byvank, T. Cahill, A. D. Hoyt, C. L. Grouchy, P. W. L. de Potter, W. M. Kusse, B. R. Hammer, D. A.

    2014-12-15

    Tests of the magnetized liner inertial fusion (MagLIF) concept will make use of the 27 MA Z machine at Sandia National Laboratories, Albuquerque, to implode a cylindrical metal liner to compress and heat preheated, magnetized plasma contained within it. While most pulsed power machines produce much lower currents than the Z-machine, there are issues that can still be addressed on smaller scale facilities. Recent work on the Cornell Beam Research Accelerator (COBRA) has made use of 10 mm long and 4 mm diameter metal liners having different wall thicknesses to study the initiation of plasma on the liner’s surface as well as axial magnetic field compression [P.-A. Gourdain et al., Nucl. Fusion 53, 083006 (2013)]. This report presents experimental results with non-imploding liners, investigating the impact the liner’s surface structure has on initiation and ablation. Extreme ultraviolet (XUV) imaging and optical 12 frame camera imaging were used to observe and assess emission non-uniformities as they developed. Axial and side-on interferometry was used to determine the distribution of plasma near the liner surface, including the impact of non-uniformities during the plasma initiation and ablation phases of the experiments.

  2. Clay-Union Electric Coop | Open Energy Information

    Open Energy Info (EERE)

    Clay-Union Electric Coop Jump to: navigation, search Name: Clay-Union Electric Coop Place: South Dakota Phone Number: 605-624-2673 Website: www.clayunionelectric.coop Facebook:...

  3. Platte-Clay Electric Coop, Inc | Open Energy Information

    Open Energy Info (EERE)

    Platte-Clay Electric Coop, Inc Jump to: navigation, search Name: Platte-Clay Electric Coop, Inc Place: Missouri Phone Number: 816-628-3121 Website: www.pcec.coop Twitter:...

  4. Demonstration of thermonuclear conditions in magnetized liner inertial fusion experiments

    SciTech Connect (OSTI)

    Gomez, Matthew R.; Slutz, Stephen A.; Sefkow, Adam B.; Hahn, Kelly D.; Hansen, Stephanie B.; Knapp, Patrick F.; Schmit, Paul F.; Ruiz, Carlos L.; Sinars, Daniel Brian; Harding, Eric C.; Jennings, Christopher A.; Awe, Thomas James; Geissel, Matthias; Rovang, Dean C.; Smith, Ian C.; Chandler, Gordon A.; Cooper, Gary Wayne; Cuneo, Michael Edward; Harvey-Thompson, Adam James; Herrmann, Mark C.; Mark Harry Hess; Lamppa, Derek C.; Martin, Matthew R.; McBride, Ryan D.; Peterson, Kyle J.; Porter, John L.; Rochau, Gregory A.; Savage, Mark E.; Schroen, Diana G.; Stygar, William A.; Vesey, Roger Alan

    2015-04-29

    In this study, the magnetized liner inertial fusion concept [S. A. Slutz et al., Phys. Plasmas17, 056303 (2010)] utilizes a magnetic field and laser heating to relax the pressure requirements of inertial confinement fusion. The first experiments to test the concept [M. R. Gomez et al., Phys. Rev. Lett. 113, 155003 (2014)] were conducted utilizing the 19 MA, 100 ns Z machine, the 2.5 kJ, 1 TW Z Beamlet laser, and the 10 T Applied B-field on Z system. Despite an estimated implosion velocity of only 70 km/s in these experiments, electron and ion temperatures at stagnation were as high as 3 keV, and thermonuclear deuterium-deuterium neutron yields up to 2 × 1012 have been produced. X-ray emission from the fuel at stagnation had widths ranging from 50 to 110 μm over a roughly 80% of the axial extent of the target (6–8 mm) and lasted approximately 2 ns. X-ray yields from these experiments are consistent with a stagnation density of the hot fuel equal to 0.2–0.4 g/cm3. In these experiments, up to 5 ×1010 secondary deuterium-tritium neutrons were produced. Given that the areal density of the plasma was approximately 1–2 mg/cm2, this indicates the stagnation plasma was significantly magnetized, which is consistent with the anisotropy observed in the deuterium-tritium neutron spectra. Control experiments where the laser and/or magnetic field were not utilized failed to produce stagnation temperatures greater than 1 keV and primary deuterium-deuterium yields greater than 1010. An additional control experiment where the fuel contained a sufficient dopant fraction to substantially increase radiative losses also failed to produce a relevant stagnation temperature. The results of these experiments are consistent with a thermonuclear neutron source.

  5. Demonstration of thermonuclear conditions in magnetized liner inertial fusion experiments

    SciTech Connect (OSTI)

    Gomez, M. R.; Slutz, S. A.; Sefkow, A. B.; Hahn, K. D.; Hansen, S. B.; Knapp, P. F.; Schmit, P. F.; Ruiz, C. L.; Sinars, D. B.; Harding, E. C.; Jennings, C. A.; Awe, T. J.; Geissel, M.; Rovang, D. C.; Smith, I. C.; Chandler, G. A.; Cooper, G. W.; Cuneo, M. E.; Harvey-Thompson, A. J.; Hess, M. H.; and others

    2015-05-15

    The magnetized liner inertial fusion concept [S. A. Slutz et al., Phys. Plasmas 17, 056303 (2010)] utilizes a magnetic field and laser heating to relax the pressure requirements of inertial confinement fusion. The first experiments to test the concept [M. R. Gomez et al., Phys. Rev. Lett. 113, 155003 (2014)] were conducted utilizing the 19 MA, 100 ns Z machine, the 2.5 kJ, 1 TW Z Beamlet laser, and the 10 T Applied B-field on Z system. Despite an estimated implosion velocity of only 70 km/s in these experiments, electron and ion temperatures at stagnation were as high as 3 keV, and thermonuclear deuterium-deuterium neutron yields up to 2 × 10{sup 12} have been produced. X-ray emission from the fuel at stagnation had widths ranging from 50 to 110 μm over a roughly 80% of the axial extent of the target (6–8 mm) and lasted approximately 2 ns. X-ray yields from these experiments are consistent with a stagnation density of the hot fuel equal to 0.2–0.4 g/cm{sup 3}. In these experiments, up to 5 × 10{sup 10} secondary deuterium-tritium neutrons were produced. Given that the areal density of the plasma was approximately 1–2 mg/cm{sup 2}, this indicates the stagnation plasma was significantly magnetized, which is consistent with the anisotropy observed in the deuterium-tritium neutron spectra. Control experiments where the laser and/or magnetic field were not utilized failed to produce stagnation temperatures greater than 1 keV and primary deuterium-deuterium yields greater than 10{sup 10}. An additional control experiment where the fuel contained a sufficient dopant fraction to substantially increase radiative losses also failed to produce a relevant stagnation temperature. The results of these experiments are consistent with a thermonuclear neutron source.

  6. Prospects for x-ray polarimetry measurements of magnetic fields in magnetized liner inertial fusion plasmas

    SciTech Connect (OSTI)

    Lynn, Alan G. Gilmore, Mark

    2014-11-15

    Magnetized Liner Inertial Fusion (MagLIF) experiments, where a metal liner is imploded to compress a magnetized seed plasma may generate peak magnetic fields ∼10{sup 4} T (100 Megagauss) over small volumes (∼10{sup −10}m{sup 3}) at high plasma densities (∼10{sup 28}m{sup −3}) on 100 ns time scales. Such conditions are extremely challenging to diagnose. We discuss the possibility of, and issues involved in, using polarimetry techniques at x-ray wavelengths to measure magnetic fields under these extreme conditions.

  7. Technique for fabrication of ultrathin foils in cylindrical geometry for liner-plasma implosion experiments with sub-megaampere currents

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yager-Elorriaga, D. A.; Steiner, A. M.; Patel, S. G.; Jordan, N. M.; Lau, Y. Y.; Gilgenbach, R. M.

    2015-11-19

    In this study, we describe a technique for fabricating ultrathin foils in cylindrical geometry for liner-plasma implosion experiments using sub-MA currents. Liners are formed by wrapping a 400 nm, rectangular strip of aluminum foil around a dumbbell-shaped support structure with a non-conducting center rod, so that the liner dimensions are 1 cm in height, 6.55 mm in diameter, and 400 nm in thickness. The liner-plasmas are imploded by discharging ~600 kA with ~200 ns rise time using a 1 MA linear transformer driver, and the resulting implosions are imaged four times per shot using laser-shadowgraphy at 532 nm. As amore » result, this technique enables the study of plasma implosion physics, including the magneto Rayleigh-Taylor, sausage, and kink instabilities on initially solid, imploding metallic liners with university-scale pulsed power machines.« less

  8. Technique for fabrication of ultrathin foils in cylindrical geometry for liner-plasma implosion experiments with sub-megaampere currents

    SciTech Connect (OSTI)

    Yager-Elorriaga, D. A.; Steiner, A. M.; Patel, S. G.; Jordan, N. M.; Lau, Y. Y.; Gilgenbach, R. M.

    2015-11-19

    In this study, we describe a technique for fabricating ultrathin foils in cylindrical geometry for liner-plasma implosion experiments using sub-MA currents. Liners are formed by wrapping a 400 nm, rectangular strip of aluminum foil around a dumbbell-shaped support structure with a non-conducting center rod, so that the liner dimensions are 1 cm in height, 6.55 mm in diameter, and 400 nm in thickness. The liner-plasmas are imploded by discharging ~600 kA with ~200 ns rise time using a 1 MA linear transformer driver, and the resulting implosions are imaged four times per shot using laser-shadowgraphy at 532 nm. As a result, this technique enables the study of plasma implosion physics, including the magneto Rayleigh-Taylor, sausage, and kink instabilities on initially solid, imploding metallic liners with university-scale pulsed power machines.

  9. Coatings and films derived from clay/wax nanocomposites

    DOE Patents [OSTI]

    Chaiko, David J.; Leyva, Argentina A.

    2006-11-14

    The invention provides methods for making clay/wax nanocomposites and coatings and films of same with improved chemical resistance and gas barrier properties. The invention further provides methods for making and using emulsions of such clay/wax nanocomposites. Typically, an organophillic clay is combined with a wax or wax/polymer blend such that the cohesion energy of the clay matches that of the wax or wax/polymer blend. Suitable organophilic clays include mica and phyllosilicates that have been surface-treated with edge or edge and surface modifying agents. The resulting nanocomposites have applications as industrial coatings and in protective packaging.

  10. Clay-based geothermal drilling fluids

    SciTech Connect (OSTI)

    Guven, N.; Carney, L.L.; Lee, L.J.; Bernhard, R.P.

    1982-11-01

    The rheological properties of fluids based on fibrous clays such as sepiolite and attapulgite have been systematically examined under conditions similar to those of geothermal wells, i.e. at elevated temperatures and pressures in environments with concentrated brines. Attapulgite- and sepiolite-based fluids have been autoclaved at temperatures in the range from 70 to 800/sup 0/F with the addition of chlorides and hydroxides of Na, K, Ca, and Mg. The rheological properties (apparent and plastic viscosity, fluid loss, gel strength, yield point, and cake thickness) of the autoclaved fluids have been studied and correlated with the chemical and physical changes that occur in the clay minerals during the autoclaving process.

  11. Approaches to consider covers and liners in a low-level waste disposal facility performance assessment

    SciTech Connect (OSTI)

    Seitz, Roger; Phifer, Mark; Suttora, Linda

    2015-03-17

    On-site disposal cells are in use and being considered at several USDOE sites as the final disposition for large amounts of waste associated with cleanup of contaminated areas and facilities. These disposal cells are typically regulated by States and/or the USEPA in addition to having to comply with requirements in DOE Order 435.1, Radioactive Waste Management. The USDOE-EM Office of Site Restoration formed a working group to foster improved communication and sharing of information for personnel associated with these Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) disposal cells and work towards more consistent assumptions, as appropriate, for technical and policy considerations related to performance and risk assessments in support of a Record of Decision and Disposal Authorization Statement. One task completed by the working group addressed approaches for considering the performance of covers and liners/leachate collection systems in the context of a performance assessment (PA). A document has been prepared which provides recommendations for a general approach to address covers and liners/leachate collection systems in a PA and how to integrate assessments with defense-in-depth considerations such as design, operations and waste acceptance criteria to address uncertainties. Specific information and references are provided for details needed to address the evolution of individual components of cover and liner/leachate collection systems. This information is then synthesized into recommendations for best practices for cover and liner system design and examples of approaches to address the performance of covers and liners as part of a performance assessment of the disposal system.

  12. Inferred performance of surface hydraulic barriers from landfill operational data

    SciTech Connect (OSTI)

    Gross, B.A.; Bonaparte, R.; Othman, M.A.

    1997-12-31

    There are few published data on the field performance of surface hydraulic barriers (SHBs) used in waste containment or remediation applications. In contrast, operational data for liner systems used beneath landfills are widely available. These data are frequently collected and reported as a facility permit condition. This paper uses leachate collection system (LCS) and leak detection system (LDS) liquid flow rate and chemical quality data collected from modem landfill double-liner systems to infer the likely hydraulic performance of SHBs. Operational data for over 200 waste management unit liner systems are currently being collected and evaluated by the authors as part of an ongoing research investigation for the United States Environmental Protection Agency (USEPA). The top liner of the double-liner system for the units is either a geomembrane (GMB) alone, geomembrane overlying a geosynthetic clay liner (GMB/GCL), or geomembrane overlying a compacted clay liner (GMB/CCL). In this paper, select data from the USEPA study are used to: (i) infer the likely efficiencies of SHBs incorporating GMBs and overlain by drainage layers; and (ii) evaluate the effectiveness of SHBs in reducing water infiltration into, and drainage from, the underlying waste (i.e., source control). SHB efficiencies are inferred from calculated landfill liner efficiencies and then used to estimate average water percolation rates through SHBs as a function of site average annual rainfall. The effectiveness of SHBs for source control is investigated by comparing LCS liquid flow rates for open and closed landfill cells. The LCS flow rates for closed cells are also compared to the estimated average water percolation rates through SHBs presented in the paper.

  13. Preparation of Clay Brick Using Coal Waste

    SciTech Connect (OSTI)

    Yoo, Jung W.; Jung, Jin H.; Kim, Jae M.; Lee, Sung M.; Kim, Hyung T.

    2004-03-31

    A great deal of coal waste produced during the development of a mine was accumulated around the mine, which caused many problems such as traffic, acid mine drainage and damage of forest and scenery. Carbon in the coal waste helps calcination of the brick even at low temperature. Considering the reuse of natural waste and energy saving, clay brick was prepared using coal waste under various conditions, including particle size, amount of coal waste mixed, calcination temperature and pressing pressure. The specimens were characterized by XRD, SEM and TG-DTA and interpreted in terms of water absorption and compressive strength.

  14. Deputy Secretary Clay Sell Touts Georgian Efforts to Advance Regional

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Cooperation and Non-Proliferation | Department of Energy Clay Sell Touts Georgian Efforts to Advance Regional Energy Cooperation and Non-Proliferation Deputy Secretary Clay Sell Touts Georgian Efforts to Advance Regional Energy Cooperation and Non-Proliferation March 16, 2007 - 10:55am Addthis Visits National Nuclear Waste Repository in Mtskheta, Georgia TBILISI, Georgia - U.S. Deputy Secretary of Energy Clay Sell today visited the National Radioactive Waste Repository in Mtskheta,

  15. Clay Central Everly School Dist Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Everly School District Energy Purchaser Clay CentralEverly School District Location IA Coordinates 43.1392, -95.2644 Show Map Loading map... "minzoom":false,"mappingservi...

  16. Molecular Simulation of Carbon Dioxide Brine and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    of Carbon Dioxide Brine and Clay Mineral Interactions and Determination of Contact Angles. Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide ...

  17. Molecular Simulation of Carbon Dioxide Nanodroplets on Clay in...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide Nanodroplets on Clay in Deep Saline Aquifers. Authors: Tenney, Craig M. Publication Date: ...

  18. Molecular Simulation of Carbon Dioxide Nanodroplets on Clay Surfaces...

    Office of Scientific and Technical Information (OSTI)

    Surfaces in Deep Saline Aquifers. Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide Nanodroplets on Clay Surfaces in Deep Saline Aquifers. Authors: ...

  19. Clay Electric Cooperative, Inc- Energy Smart Energy Efficiency Rebate Program

    Broader source: Energy.gov [DOE]

    Rebates are available only to Clay Electric Cooperative (CEC) residential members who are making efficiency upgrades to primary residence served by CEC. Rebates are available for residential...

  20. Clay County, Florida: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Clay County, Florida: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 29.9943564, -81.7787021 Show Map Loading map... "minzoom":false,"mappings...

  1. Deputy Secretary Clay Sell Touts Georgian Efforts to Advance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to Advance Regional Energy Cooperation and Non-Proliferation Deputy Secretary Clay Sell Touts Georgian Efforts to Advance Regional Energy Cooperation and Non-Proliferation March ...

  2. Optimization of the parameters of plasma liners with zero-dimensional models

    SciTech Connect (OSTI)

    Oreshkin, V. I.

    2013-11-15

    The efficiency of conversion of the energy stored in the capacitor bank of a high-current pulse generator into the kinetic energy of an imploding plasma liner is analyzed. The analysis is performed by using a model consisting of LC circuit equations and equations of motion of a cylindrical shell. It is shown that efficient energy conversion can be attained only with a low-inductance generator. The mode of an 'ideal' load is considered where the load current at the final stage of implosion is close to zero. The advantages of this mode are, first, high efficiency of energy conversion (80%) and, second, improved stability of the shell implosion. In addition, for inertial confinement fusion realized by the scheme of a Z pinch dynamic hohlraum, not one but several fusion targets can be placed in the cavity on the pinch axis due to the large length of the liner.

  3. Nondestructive characterization of ceramic composites used as combustor liners in advanced gas turbines

    SciTech Connect (OSTI)

    Ellingson, W.A.; Rothermel, S.A.; Simpson, J.F.

    1996-07-01

    Nondestructive characterization (NDC) methods, which can provide full-field information about components prior to and during use, are critical to the reliable application of continuous fiber ceramic matrix composites in high-firing-temperature (>1,350 C) gas turbines. [For combustor liners, although they are nonmechanical load-bearing components, both thermal characteristics and mechanical integrity are vitally important.] NDC methods being developed to provide necessary information include x-ray computed tomography (mainly for through-wall density and delamination detection), infrared-based thermal diffusivity imaging, and single-wall through-transmission x-ray imaging (mainly for fiber content and alignment detection). Correlation of the data obtained from NDC methods with subscale combustor liner tests have shown positive results at thermal cycling temperatures from 700 C to 1,177 C.

  4. The washability of lignites for clay removal

    SciTech Connect (OSTI)

    Oteyaka, B.; Yamik, A.; Ucar, A.; Sahbaz, O.; Demir, U.

    2008-07-01

    In the washability research of the Seyitomer Lignites (Kutahya-Turkey), with lower calorific value (1,863 kcal/kg) and high ash content (51.91%), by heavy medium separation, it was found out that middling clay in the coal had an effect to change the medium density. To prevent this problem, a trommel sieve with 18 and 5 mm aperture diameter was designed, and the clay in the coal was tried to be removed using it before the coal was released to heavy medium. Following that, the obtained coal in -100 + 18 mm and -18 + 5 mm fractions was subjected to sink and float test having 1.4 gcm{sup -3} and 1.7 gcm{sup -3} medium densities (-5 mm fraction will be evaluated in a separate work). Depending on the raw coal, with the floating of -100 + 18 mm and -18 + 5 mm size fraction in 1.4 gcm{sup -3} medium density, clean coal with 60.10% combustible matter recovery, 19.12% ash, and 3,150 kcal/kg was obtained. Also floating of the samples sinking in 1.4 gcm{sup -3} in the medium density (1.7 gcm{sup -3}), middling with 18.70% combustible matter recovery, 41.93% ash, 2,150 kcal/kg, and tailing having 78.31% ash were obtained.

  5. Device and method for imploding a microsphere with a fast liner

    DOE Patents [OSTI]

    Thode, Lester E.

    1981-01-01

    A device and method for relativistic electron beam heating of a high-density plasma in a small localized region. A relativistic electron beam generator or accelerator produces a high-voltage electron beam which propagates along a vacuum drift tube and is modulated to initiate electron bunching within the beam. The beam is then directed through a low-density gas chamber which provides isolation between the vacuum modulator and the relativistic electron beam target. The relativistic beam is then applied to a high-density target plasma which typically comprises DT, DD, hydrogen boron or similar thermonuclear gas at a density of 10.sup.17 to 10.sup.20 electrons per cubic centimeter. The target gas is ionized prior to application of the electron beam by means of a laser or other preionization source to form a plasma. Utilizing a relativistic electron beam with an individual particle energy exceeding 3 MeV, classical scattering by relativistic electrons passing through isolation foils is negligible. As a result, relativistic streaming instabilities are initiated within the high-density target plasma causing the relativistic electron beam to efficiently deposit its energy and momentum into a small localized region of the high-density plasma target. Fast liners disposed in the high-density target plasma are explosively or ablatively driven to implosion by a heated annular plasma surrounding the fast liner generated by an annular relativistic electron beam. An azimuthal magnetic field produced by axial current flow in the annular plasma, causes the energy in the heated annular plasma to converge on the fast liner to drive the fast liner to implode a microsphere.

  6. Melt Infiltrated Ceramic Matrix Composites for Shrouds and Combustor Liners of Advanced Industrial Gas Turbines

    SciTech Connect (OSTI)

    Gregory Corman; Krishan Luthra; Jill Jonkowski; Joseph Mavec; Paul Bakke; Debbie Haught; Merrill Smith

    2011-01-07

    This report covers work performed under the Advanced Materials for Advanced Industrial Gas Turbines (AMAIGT) program by GE Global Research and its collaborators from 2000 through 2010. A first stage shroud for a 7FA-class gas turbine engine utilizing HiPerComp{reg_sign}* ceramic matrix composite (CMC) material was developed. The design, fabrication, rig testing and engine testing of this shroud system are described. Through two field engine tests, the latter of which is still in progress at a Jacksonville Electric Authority generating station, the robustness of the CMC material and the shroud system in general were demonstrated, with shrouds having accumulated nearly 7,000 hours of field engine testing at the conclusion of the program. During the latter test the engine performance benefits from utilizing CMC shrouds were verified. Similar development of a CMC combustor liner design for a 7FA-class engine is also described. The feasibility of using the HiPerComp{reg_sign} CMC material for combustor liner applications was demonstrated in a Solar Turbines Ceramic Stationary Gas Turbine (CSGT) engine test where the liner performed without incident for 12,822 hours. The deposition processes for applying environmental barrier coatings to the CMC components were also developed, and the performance of the coatings in the rig and engine tests is described.

  7. Flexible stainless steel hose liner used to rehab drain pipe for seal gates and outlet tubes

    SciTech Connect (OSTI)

    Sauer, S.J.; Monsanto, R. )

    1993-08-01

    Not unlike other dams, the Bureau of Reclamation's 6,500-MW Grand Coulee Dam in Washington State has a large amount of embedded piping, conduits, and drains. Typically, these features were constructed of ductile iron, cast iron, or carbon steel materials. Over the years, excessive internal corrosion of the drains for 102-inch ring seal gates and outlet tubes created leaks that required attention. Reclamation performed a number of temporary repairs before it became evident that the drain system must be rehabilitated. After considering several alternatives for rehabilitation, Reclamation selected stainless steel flexible hose liners for the job. Reclamation is satisfied with the performance of the stainless steel flexible hose liner. The total cost for installing the liners for nine drain lines (for three outlet tubes) was $15,000. Of that, materials cost $7,500, and labor and overhead cost $7,500. The inserts themselves cost from $640 for an 18-foot by 6-inch section. While this was not the least expensive option, it was the best choice for this job. The procedure will be repeated for other outlet tubes at Grand Coulee. Information used in this rehabilitation is being made available to other Reclamation projects.

  8. Performance characteristics of a self-sealing/self-healing barrier

    SciTech Connect (OSTI)

    McGregor, R.G. |; Stegemann, J.A.

    1997-12-31

    Environment Canada and the Netherlands Energy Research Foundation are co-developers of a patented Self-Sealing/Self-Healing (SS/SH) Barrier system for containment of wastes which is licensed to Water Technology International Corporation. The SS/SH Barrier is intended for use as either a liner or cover for landfills, contaminated sites, secondary containment areas, etc., in the industrial, chemical, mining and municipal sectors, and also as a barrier to hydraulic flow for the transportation and construction industry. The SS/SH Barrier`s most significant feature is its capability for self-repair in the event of a breach. By contrast, conventional barrier systems, such as clay, geomembrane, or geosynthetic clay liners can not be repaired without laborious excavation and reconstruction. Laboratory investigations have shown that the SS/SH Barrier concept will function with a variety of reactive materials. Self-Sealing/Self-Healing Barriers are cost competitive and consistently exhibit hydraulic conductivities ranging from 10{sup -9} to 10{sup -13} m/s, which decrease with time. These measurements meet or exceed the recommended hydraulic conductivity required by EPA for clay liners (<1x10{sup -9} m/s) used in landfills and hazardous waste sites. Results of mineralogical examination of the seal, diffusion testing, hydraulic conductivity measurement, and durability testing, including wet/dry, freeze/thaw cycling and leachate compatibility are also presented.

  9. Gypsum treated fly ash as a liner for waste disposal facilities

    SciTech Connect (OSTI)

    Sivapullaiah, Puvvadi V.; Baig, M. Arif Ali

    2011-02-15

    Fly ash has potential application in the construction of base liners for waste containment facilities. While most of the fly ashes improve in the strength with curing, the ranges of permeabilities they attain may often not meet the basic requirement of a liner material. An attempt has been made in the present context to reduce the hydraulic conductivity by adding lime content up to 10% to two selected samples of class F fly ashes. The use of gypsum, which is known to accelerate the unconfined compressive strength by increasing the lime reactivity, has been investigated in further improving the hydraulic conductivity. Hydraulic conductivities of the compacted specimens have been determined in the laboratory using the falling head method. It has been observed that the addition of gypsum reduces the hydraulic conductivity of the lime treated fly ashes. The reduction in the hydraulic conductivity of the samples containing gypsum is significantly more for samples with high amounts of lime contents (as high as 1000 times) than those fly ashes with lower amounts of lime. However there is a relatively more increase in the strengths of the samples with the inclusion of gypsum to the fly ashes at lower lime contents. This is due to the fact that excess lime added to fly ash is not effectively converted into pozzolanic compounds. Even the presence of gypsum is observed not to activate these reactions with excess lime. On the other hand the higher amount of lime in the presence of sulphate is observed to produce more cementitious compounds which block the pores in the fly ash. The consequent reduction in the hydraulic conductivity of fly ash would be beneficial in reducing the leachability of trace elements present in the fly ash when used as a base liner.

  10. Case histories portraying different methods of installing liners for verticle barriers

    SciTech Connect (OSTI)

    Burke, G.K.; Crockford, R.M.; Achhorner, F.N.

    1997-12-31

    The installation of liners for vertical barriers is difficult and has been a learning experience for every contractor making the attempt. Soil stratigraphy and hydrogeologic conditions can vary over short distances, creating a variety of problems. This is particularly so when working near landfills and documentation of the as-built condition is poor. Successful installation requires detailed planning and knowledge of what to expect, as well as alternate plans for potential problems. Several successful methods of panel connection will be presented as well as a variety of installation techniques. Project case histories will be reviewed, highlighting the challenges associated with specific construction techniques.

  11. Probing off-Hugoniot states in Ta, Cu, and Al to 1000 GPa compression with magnetically driven liner implosions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lemke, R. W.; Dolan, D. H.; Dalton, D. G.; Brown, J. L.; Tomlinson, K.; Robertson, G. R.; Knudson, M. D.; Harding, E.; Mattsson, A. E.; Carpenter, J. H.; et al

    2016-01-07

    We report on a new technique for obtaining off-Hugoniot pressure vs. density data for solid metals compressed to extreme pressure by a magnetically driven liner implosion on the Z-machine (Z) at Sandia National Laboratories. In our experiments, the liner comprises inner and outer metal tubes. The inner tube is composed of a sample material (e.g., Ta and Cu) whose compressed state is to be inferred. The outer tube is composed of Al and serves as the current carrying cathode. Another aluminum liner at much larger radius serves as the anode. A shaped current pulse quasi-isentropically compresses the sample as itmore » implodes. The iterative method used to infer pressure vs. density requires two velocity measurements. Photonic Doppler velocimetry probes measure the implosion velocity of the free (inner) surface of the sample material and the explosion velocity of the anode free (outer) surface. These two velocities are used in conjunction with magnetohydrodynamic simulation and mathematical optimization to obtain the current driving the liner implosion, and to infer pressure and density in the sample through maximum compression. This new equation of state calibration technique is illustrated using a simulated experiment with a Cu sample. Monte Carlo uncertainty quantification of synthetic data establishes convergence criteria for experiments. Results are presented from experiments with Al/Ta, Al/Cu, and Al liners. Symmetric liner implosion with quasi-isentropic compression to peak pressure ~1000 GPa is achieved in all cases. Lastly, these experiments exhibit unexpectedly softer behavior above 200 GPa, which we conjecture is related to differences in the actual and modeled properties of aluminum.« less

  12. City of Clay Center, Kansas (Utility Company) | Open Energy Informatio...

    Open Energy Info (EERE)

    commu Facebook: https:www.facebook.compagesCity-of-Clay-Center172525069449548?refbrrs Outage Hotline: 785-632-2139 or (785) 632-5454 References: EIA Form EIA-861 Final...

  13. Modeling Coupled Processes in Clay Formations for Radioactive Waste Disposal

    SciTech Connect (OSTI)

    Liu, Hui-Hai; Rutqvist, Jonny; Zheng, Liange; Sonnenthal, Eric; Houseworth, Jim; Birkholzer, Jens

    2010-08-31

    As a result of the termination of the Yucca Mountain Project, the United States Department of Energy (DOE) has started to explore various alternative avenues for the disposition of used nuclear fuel and nuclear waste. The overall scope of the investigation includes temporary storage, transportation issues, permanent disposal, various nuclear fuel types, processing alternatives, and resulting waste streams. Although geologic disposal is not the only alternative, it is still the leading candidate for permanent disposal. The realm of geologic disposal also offers a range of geologic environments that may be considered, among those clay shale formations. Figure 1-1 presents the distribution of clay/shale formations within the USA. Clay rock/shale has been considered as potential host rock for geological disposal of high-level nuclear waste throughout the world, because of its low permeability, low diffusion coefficient, high retention capacity for radionuclides, and capability to self-seal fractures induced by tunnel excavation. For example, Callovo-Oxfordian argillites at the Bure site, France (Fouche et al., 2004), Toarcian argillites at the Tournemire site, France (Patriarche et al., 2004), Opalinus clay at the Mont Terri site, Switzerland (Meier et al., 2000), and Boom clay at Mol site, Belgium (Barnichon et al., 2005) have all been under intensive scientific investigations (at both field and laboratory scales) for understanding a variety of rock properties and their relations with flow and transport processes associated with geological disposal of nuclear waste. Clay/shale formations may be generally classified as indurated and plastic clays (Tsang et al., 2005). The latter (including Boom clay) is a softer material without high cohesion; its deformation is dominantly plastic. For both clay rocks, coupled thermal, hydrological, mechanical and chemical (THMC) processes are expected to have a significant impact on the long-term safety of a clay repository. For

  14. Clay County Electric Coop Corp | Open Energy Information

    Open Energy Info (EERE)

    Corp Jump to: navigation, search Name: Clay County Electric Coop Corp Place: Arkansas Service Territory: Arkansas, Missouri Phone Number: 870.857.3521 or 870.892.5251 or...

  15. Value engineering: An alternative liner system at the La Paz County Regional Landfill

    SciTech Connect (OSTI)

    Shafer, A.L.; Purdy, S.; Tempelis, D.

    1997-11-01

    The La Paz County Regional Landfill is a 65 hectare (160 acre) municipal waste site located near the western border of Arizona between the cities of Parker and Quartzsite. The site is operated under a public/private partnership between the County of La Paz and Browning-Ferris Industries, Inc. (BFI). The County owns the landfill and infrastructure and BFI is responsible for facility improvements, environmental compliance, and daily operations. Following the initial permitting and construction of the first landfill cell, a value engineering review was conducted on the site design and permit requirements. Based on this review, substantial cost saving opportunities were identified. In order to implement the value engineering ideas, the site permit was modified and a new Solid Waste Facilities Plan was Submitted to the Arizona Department of Environmental Quality. This paper discusses the value engineering modifications that were conducted, the revisions to the permits, and the relative cost savings that were realized. The areas addressed include the liner system design, closure design, disposal capacity, and operations plan. Through the use of alternative liners a cost savings of well over 50 percent (as compared to the original permit) will be realized over the life of the landfill.

  16. Fusion-neutron measurements for magnetized liner inertial fusion experiments on the Z accelerator

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hahn, K. D.; Chandler, G. A.; Ruiz, C. L.; Cooper, G. W.; Gomez, M. R.; Slutz, S.; Sefkow, A. B.; Sinars, D. B.; Hansen, S. B.; Knapp, P. F.; et al

    2016-05-01

    Several magnetized liner inertial fusion (MagLIF) experiments have been conducted on the Z accelerator at Sandia National Laboratories since late 2013. Measurements of the primary DD (2.45 MeV) neutrons for these experiments suggest that the neutron production is thermonuclear. Primary DD yields up to 3e12 with ion temperatures ~2-3 keV have been achieved. Measurements of the secondary DT (14 MeV) neutrons indicate that the fuel is significantly magnetized. Measurements of down-scattered neutrons from the beryllium liner suggest ρRliner ~ 1g/cm2. Neutron bang times, estimated from neutron time-of-flight (nTOF) measurements, coincide with peak x-ray production. Furthermore, plans to improve and expandmore » the Z neutron diagnostic suite include neutron burn-history diagnostics, increased sensitivity and higher precision nTOF detectors, and neutron recoil-based yield and spectral measurements.« less

  17. Macron Formed Liner Compression as a Practical Method for Enabling Magneto-Inertial Fusion

    SciTech Connect (OSTI)

    Slough, John

    2011-12-10

    The entry of fusion as a viable, competitive source of power has been stymied by the challenge of finding an economical way to provide for the confinement and heating of the plasma fuel. The main impediment for current nuclear fusion concepts is the complexity and large mass associated with the confinement systems. To take advantage of the smaller scale, higher density regime of magnetic fusion, an efficient method for achieving the compressional heating required to reach fusion gain conditions must be found. The very compact, high energy density plasmoid commonly referred to as a Field Reversed Configuration (FRC) provides for an ideal target for this purpose. To make fusion with the FRC practical, an efficient method for repetitively compressing the FRC to fusion gain conditions is required. A novel approach to be explored in this endeavor is to remotely launch a converging array of small macro-particles (macrons) that merge and form a more massive liner inside the reactor which then radially compresses and heats the FRC plasmoid to fusion conditions. The closed magnetic field in the target FRC plasmoid suppresses the thermal transport to the confining liner significantly lowering the imploding power needed to compress the target. With the momentum flux being delivered by an assemblage of low mass, but high velocity macrons, many of the difficulties encountered with the liner implosion power technology are eliminated. The undertaking to be described in this proposal is to evaluate the feasibility achieving fusion conditions from this simple and low cost approach to fusion. During phase I the design and testing of the key components for the creation of the macron formed liner have been successfully carried out. Detailed numerical calculations of the merging, formation and radial implosion of the Macron Formed Liner (MFL) were also performed. The phase II effort will focus on an experimental demonstration of the macron launcher at full power, and the demonstration

  18. Hollow clay tile wall program summary report

    SciTech Connect (OSTI)

    Henderson, R.C.; Jones, W.D.

    1995-07-30

    Many of the Y-12 Plant buildings, constructed during the 1940s and 1950s, consist of steel ed concrete framing infilled with hollow clay tile (HCT). The infill was intended to provide for building enclosure and was not designed to have vertical or lateral load-carrying capacity. During the late 1970s and early 1980s, seismic and wind evaluations were performed on many of these buildings in conjunction with the preparation of a site-wide safety analysis report. This analytical work, based on the best available methodology, considered lateral load-carrying capacity of the HCT infill on the basis of building code allowable shear values. In parallel with the analysis effort, DOE initiated a program to develop natural phenomena capacity and performance criteria for existing buildings, but these criteria did not specify guidelines for determining the lateral force capacity of frames infilled with HCT. The evaluation of infills was, therefore, based on the provisions for the design of unreinforced masonry as outlined in standard masonry codes. When the results of the seismic and wind evaluations were compared with the new criteria, the projected building capacities fell short of the requirements. Apparently, if the buildings were to meet the new criteria, many millions of dollars would be required for building upgrades. Because the upgrade costs were significant, the assumptions and approaches used in the analyses were reevaluated. Four issues were identified: (1) Once the infilled walls cracked, what capacity (nonlinear response), if any, would the walls have to resist earthquake or wind loads applied in the plane of the infill (in-plane)? (2) Would the infilled walls remain within the steel or reinforced concrete framing when subjected to earthquake or high wind loads applied perpendicular to the infill (out-of-plane)? (3) What was the actual shear capacity of the HCT infill? (4) Was modeling the HCT infill as a shear wall the best approach?

  19. Constitutive relationships for elastic deformation of clay rock: Data Analysis

    SciTech Connect (OSTI)

    Liu, H.H.; Rutqvist, J.; Birkholzer, J.T.

    2011-04-15

    Geological repositories have been considered a feasible option worldwide for storing high-level nuclear waste. Clay rock is one of the rock types under consideration for such purposes, because of its favorable features to prevent radionuclide transport from the repository. Coupled hydromechanical processes have an important impact on the performance of a clay repository, and establishing constitutive relationships for modeling such processes are essential. In this study, we propose several constitutive relationships for elastic deformation in indurated clay rocks based on three recently developed concepts. First, when applying Hooke's law in clay rocks, true strain (rock volume change divided by the current rock volume), rather than engineering strain (rock volume change divided by unstressed rock volume), should be used, except when the degree of deformation is very small. In the latter case, the two strains will be practically identical. Second, because of its inherent heterogeneity, clay rock can be divided into two parts, a hard part and a soft part, with the hard part subject to a relatively small degree of deformation compared with the soft part. Third, for swelling rock like clay, effective stress needs to be generalized to include an additional term resulting from the swelling process. To evaluate our theoretical development, we analyze uniaxial test data for core samples of Opalinus clay and laboratory measurements of single fractures within macro-cracked Callovo-Oxfordian argillite samples subject to both confinement and water reduced swelling. The results from this evaluation indicate that our constitutive relationships can adequately represent the data and explain the related observations.

  20. Modification of clay-based waste containment materials

    SciTech Connect (OSTI)

    Adu-Wusu, K.; Whang, J.M.; McDevitt, M.F.

    1997-12-31

    Bentonite clays are used extensively for waste containment barriers to help impede the flow of water in the subsurface because of their low permeability characteristics. However, they do little to prevent diffusion of contaminants, which is the major transport mechanism at low water flows. A more effective way of minimizing contaminant migration in the subsurface is to modify the bentonite clay with highly sorptive materials. Batch sorption studies were conducted to evaluate the sorptive capabilities of organo-clays and humic- and iron-based materials. These materials proved to be effective sorbents for the organic contaminants 1,2,4-trichlorobenzene, nitrobenzene, and aniline in water, humic acid, and methanol solution media. The sorption capacities were several orders of magnitude greater than that of unmodified bentonite clay. Modeling results indicate that with small amounts of these materials used as additives in clay barriers, contaminant flux through walls could be kept very small for 100 years or more. The cost of such levels of additives can be small compared to overall construction costs.

  1. Nondestructive laboratory measurement of geotechnical and geoacoustic properties through intact core-liner

    SciTech Connect (OSTI)

    Kayen, R.E.; Edwards, B.D.; Lee, H.J.

    1999-07-01

    High-resolution automated measurement of the geotechnical and geoacoustic properties of soil at the US geological Survey (USGS) is performed with a state-of-the-art multi-sensor whole-core logging device. The device takes measurements, directly through intact sample-tube wall, of p-wave acoustic velocity, of soil wet bulk density, and magnetic susceptibility. This paper summarizes the authors methodology for determining soil-sound speed and wet-bulk density for material encased in an unsplit liner. The authors methodology for nondestructive measurement allows for rapid, accurate, and high-resolution (1 cm-spaced) mapping of the mass physical properties of soil prior to sample extrusion.

  2. Exploring magnetized liner inertial fusion with a semi-analytic model

    SciTech Connect (OSTI)

    McBride, Ryan D.; Slutz, Stephen A.; Vesey, Roger A.; Gomez, Matthew R.; Sefkow, Adam B.; Hansen, Stephanie B.; Knapp, Patrick F.; Schmit, Paul F.; Geissel, Matthias; Harvey-Thompson, Adam James; Jennings, Christopher Ashley; Harding, Eric C.; Awe, Thomas James; Rovang, Dean C.; Hahn, Kelly D.; Martin, Matthew R.; Cochrane, Kyle R.; Peterson, Kyle J.; Rochau, Gregory A.; Porter, John L.; Stygar, William A.; Campbell, Edward Michael; Nakhleh, Charles W.; Herrmann, Mark C.; Cuneo, Michael E.; Sinars, Daniel B.

    2016-01-01

    In this study, we explore magnetized liner inertial fusion (MagLIF) [S. A. Slutz et al., Phys. Plasmas 17, 056303 (2010)] using a semi-analytic model [R. D. McBride and S. A. Slutz, Phys. Plasmas 22, 052708 (2015)]. Specifically, we present simulation results from this model that: (a) illustrate the parameter space, energetics, and overall system efficiencies of MagLIF; (b) demonstrate the dependence of radiative loss rates on the radial fraction of the fuel that is preheated; (c) explore some of the recent experimental results of the MagLIF program at Sandia National Laboratories [M. R. Gomez et al., Phys. Rev. Lett. 113, 155003 (2014)]; (d) highlight the experimental challenges presently facing the MagLIF program; and (e) demonstrate how increases to the preheat energy, fuel density, axial magnetic field, and drive current could affect future MagLIF performance.

  3. Exploring magnetized liner inertial fusion with a semi-analytic model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McBride, Ryan D.; Slutz, Stephen A.; Vesey, Roger A.; Gomez, Matthew R.; Sefkow, Adam B.; Hansen, Stephanie B.; Knapp, Patrick F.; Schmit, Paul F.; Geissel, Matthias; Harvey-Thompson, Adam James; et al

    2016-01-01

    In this study, we explore magnetized liner inertial fusion (MagLIF) [S. A. Slutz et al., Phys. Plasmas 17, 056303 (2010)] using a semi-analytic model [R. D. McBride and S. A. Slutz, Phys. Plasmas 22, 052708 (2015)]. Specifically, we present simulation results from this model that: (a) illustrate the parameter space, energetics, and overall system efficiencies of MagLIF; (b) demonstrate the dependence of radiative loss rates on the radial fraction of the fuel that is preheated; (c) explore some of the recent experimental results of the MagLIF program at Sandia National Laboratories [M. R. Gomez et al., Phys. Rev. Lett. 113,more » 155003 (2014)]; (d) highlight the experimental challenges presently facing the MagLIF program; and (e) demonstrate how increases to the preheat energy, fuel density, axial magnetic field, and drive current could affect future MagLIF performance.« less

  4. Diagnosing laser-preheated magnetized plasmas relevant to magnetized liner inertial fusion

    SciTech Connect (OSTI)

    Harvey-Thompson, Adam James; Sefkow, Adam B.; Nagayama, Taisuke N.; Wei, Mingsheng; Campbell, Edward Michael; Fiksel, Gennady; Chang, Po -Yu; Davies, Jonathan R.; Barnak, Daniel H.; Glebov, Vladimir Y.; Fitzsimmons, Paul; Fooks, Julie; Blue, Brent E.

    2015-12-22

    In this paper, we present a platform on the OMEGA EP Laser Facility that creates and diagnoses the conditions present during the preheat stage of the MAGnetized Liner Inertial Fusion (MagLIF) concept. Experiments were conducted using 9 kJ of 3ω (355 nm) light to heat an underdense deuterium gas (electron density: 2.5 × 1020 cm-3 = 0.025 of critical density) magnetized with a 10 T axial field. Results show that the deuterium plasma reached a peak electron temperature of 670 ± 140 eV, diagnosed using streaked spectroscopy of an argon dopant. The results demonstrate that plasmas relevant to the preheat stage of MagLIF can be produced at multiple laser facilities, thereby enabling more rapid progress in understanding magnetized preheat. Results are compared with magneto-radiation-hydrodynamics simulations, and plans for future experiments are described.

  5. Diagnosing laser-preheated magnetized plasmas relevant to magnetized liner inertial fusion

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Harvey-Thompson, Adam James; Sefkow, Adam B.; Nagayama, Taisuke N.; Wei, Mingsheng; Campbell, Edward Michael; Fiksel, Gennady; Chang, Po -Yu; Davies, Jonathan R.; Barnak, Daniel H.; Glebov, Vladimir Y.; et al

    2015-12-22

    In this paper, we present a platform on the OMEGA EP Laser Facility that creates and diagnoses the conditions present during the preheat stage of the MAGnetized Liner Inertial Fusion (MagLIF) concept. Experiments were conducted using 9 kJ of 3ω (355 nm) light to heat an underdense deuterium gas (electron density: 2.5 × 1020 cm-3 = 0.025 of critical density) magnetized with a 10 T axial field. Results show that the deuterium plasma reached a peak electron temperature of 670 ± 140 eV, diagnosed using streaked spectroscopy of an argon dopant. The results demonstrate that plasmas relevant to the preheatmore » stage of MagLIF can be produced at multiple laser facilities, thereby enabling more rapid progress in understanding magnetized preheat. Results are compared with magneto-radiation-hydrodynamics simulations, and plans for future experiments are described.« less

  6. LITERATURE REVIEW ON THE SORPTION OF PLUTONIUM, URANIUM, NEPTUNIUM, AMERICIUM AND TECHNETIUM TO CORROSION PRODUCTS ON WASTE TANK LINERS

    SciTech Connect (OSTI)

    Li, D.; Kaplan, D.

    2012-02-29

    The Savannah River Site (SRS) has conducted performance assessment (PA) calculations to determine the risk associated with closing liquid waste tanks. The PA estimates the risk associated with a number of scenarios, making various assumptions. Throughout all of these scenarios, it is assumed that the carbon-steel tank liners holding the liquid waste do not sorb the radionuclides. Tank liners have been shown to form corrosion products, such as Fe-oxyhydroxides (Wiersma and Subramanian 2002). Many corrosion products, including Fe-oxyhydroxides, at the high pH values of tank effluent, take on a very strong negative charge. Given that many radionuclides may have net positive charges, either as free ions or complexed species, it is expected that many radionuclides will sorb to corrosion products associated with tank liners. The objective of this report was to conduct a literature review to investigate whether Pu, U, Np, Am and Tc would sorb to corrosion products on tank liners after they were filled with reducing grout (cementitious material containing slag to promote reducing conditions). The approach was to evaluate radionuclides sorption literature with iron oxyhydroxide phases, such as hematite ({alpha}-Fe{sub 2}O{sub 3}), magnetite (Fe{sub 3}O{sub 4}), goethite ({alpha}-FeOOH) and ferrihydrite (Fe{sub 2}O{sub 3} {center_dot} 0.5H{sub 2}O). The primary interest was the sorption behavior under tank closure conditions where the tanks will be filled with reducing cementitious materials. Because there were no laboratory studies conducted using site specific experimental conditions, (e.g., high pH and HLW tank aqueous and solid phase chemical conditions), it was necessary to extend the literature review to lower pH studies and noncementitious conditions. Consequently, this report relied on existing lower pH trends, existing geochemical modeling, and experimental spectroscopic evidence conducted at lower pH levels. The scope did not include evaluating the appropriateness

  7. Application of hard X-ray microprobe methods to clay-rich materials...

    Office of Scientific and Technical Information (OSTI)

    Application of hard X-ray microprobe methods to clay-rich materials Citation Details In-Document Search Title: Application of hard X-ray microprobe methods to clay-rich materials ...

  8. Enhanced shear strength of sodium bentonite using frictional additives

    SciTech Connect (OSTI)

    Schmitt, K.E.; Bowders, J.J.; Gilbert, R.B.; Daniel, D.E.

    1997-12-31

    One of the most important obstacles to using geosynthetic clay liners (GCLs) in landfill cover systems is the low shear strength provided by the bentonitic portion of the GCL. In this study, the authors propose that granular, frictional materials might be added to the bentonite to form an admixture that would have greater shear strength than the bentonite alone while still raining low hydraulic conductivity. Bentonite was mixed with two separate granular additives, expanded shale and recycled to form mixtures consisting of 20-70% bentonite by weight. In direct shear tests at normal stresses of 34.5-103.5 kPa, effective friction angles were measured as 45{degrees} for the expanded 36{degrees} for the recycled glass, and 7{degrees} for the hydrated granular bentonite. The strength of the expanded shale mixtures increased nearly linearly as the percentage shale in the mixture increased, to 44{degrees} for a bentonite mixture with 80% shale. The addition of recycled glass showed little effect on the shear strength of the mixtures of glass and bentonite. Hydraulic conductivity measurements for both types of mixtures indicated a linear increase with log(k) as the amount of granular additive increased. For applications involving geosynthetic clay liners for cover systems, a mixture of 40% expanded shale and 60% bentonite is recommended, although further testing must be done. The 40/60 mixture satisfies the hydraulic equivalency requirement, with k = 5.1X10{sup -9} cm/sec, while increasing the shear strength parameters of the bentonitic mixture to {phi}{prime} = 17{degrees} and c{prime} = 0.

  9. Quantum Chemistry of CO2 Interaction with Swelling Clays | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of CO2 Interaction with Swelling Clays Quantum Chemistry of CO2 Interaction with Swelling Clays Ubiquitous clay minerals can play an important role in assessing the suitability of geologic formations for secure storage of carbon dioxide (CO2). The minerals may affect the reservoir storage capacity as well as the integrity of its natural seals such as caprock formations. CO2 interaction with swelling clays such as smectites is a complex process involving physisorption in micropores and

  10. Open apex shaped charge-type explosive device having special disc means with slide surface thereon to influence movement of open apex shaped charge liner during collapse of same during detonation

    SciTech Connect (OSTI)

    Murphy, M.J.

    1992-12-31

    An open apex shape charge explosive device is disclosed having an inner liner defining a truncated cone, an explosive charge surrounding the truncated inner liner, a primer charge, and a disc located between the inner liner and the primer charge for directing the detonation of the primer charge around the end edge of the disc means to the explosive materials surrounding the inner liner. The disc comprises a material having one or more of: a higher compressive strength, a higher hardness, and/or a higher density than the material comprising the inner liner, thereby enabling the disc to resist deformation until the liner collapses. The disc has a slide surface thereon on which the end edge of the inner liner slides inwardly toward the vertical axis of the device during detonation of the main explosive surrounding the inner liner, to thereby facilitate the inward collapse of the inner liner. In a preferred embodiment, the geometry of the slide surface is adjusted to further control the collapse or {beta} angle of the inner liner.

  11. Open apex shaped charge-type explosive device having special disc means with slide surface thereon to influence movement of open apex shaped charge liner during collapse of same during detonation

    DOE Patents [OSTI]

    Murphy, M.J.

    1993-10-12

    An open apex shape charge explosive device is disclosed having an inner liner defining a truncated cone, an explosive charge surrounding the truncated inner liner, a primer charge, and a disc located between the inner liner and the primer charge for directing the detonation of the primer charge around the end edge of the disc means to the explosive materials surrounding the inner liner. The disc comprises a material having one or more of: a higher compressive strength, a higher hardness, and/or a higher density than the material comprising the inner liner, thereby enabling the disc to resist deformation until the liner collapses. The disc has a slide surface thereon on which the end edge of the inner liner slides inwardly toward the vertical axis of the device during detonation of the main explosive surrounding the inner liner, to thereby facilitate the inward collapse of the inner liner. In a preferred embodiment, the geometry of the slide surface is adjusted to further control the collapse or [beta] angle of the inner liner. 12 figures.

  12. Open apex shaped charge-type explosive device having special disc means with slide surface thereon to influence movement of open apex shaped charge liner during collapse of same during detonation

    DOE Patents [OSTI]

    Murphy, Michael J.

    1993-01-01

    An open apex shape charge explosive device is disclosed having an inner liner defining a truncated cone, an explosive charge surrounding the truncated inner liner, a primer charge, and a disc located between the inner liner and the primer charge for directing the detonation of the primer charge around the end edge of the disc means to the explosive materials surrounding the inner liner. The disc comprises a material having one or more of: a higher compressive strength, a higher hardness, and/or a higher density than the material comprising the inner liner, thereby enabling the disc to resist deformation until the liner collapses. The disc has a slide surface thereon on which the end edge of the inner liner slides inwardly toward the vertical axis of the device during detonation of the main explosive surrounding the inner liner, to thereby facilitate the inward collapse of the inner liner. In a preferred embodiment, the geometry of the slide surface is adjusted to further control the collapse or .beta. angle of the inner liner.

  13. Instability growth for magnetized liner inertial fusion seeded by electro-thermal, electro-choric, and material strength effects

    SciTech Connect (OSTI)

    Pecover, J. D.; Chittenden, J. P.

    2015-10-15

    A critical limitation of magnetically imploded systems such as magnetized liner inertial fusion (MagLIF) [Slutz et al., Phys. Plasmas 17, 056303 (2010)] is the magneto-Rayleigh-Taylor (MRT) instability which primarily disrupts the outer surface of the liner. MagLIF-relevant experiments have showed large amplitude multi-mode MRT instability growth growing from surface roughness [McBride et al., Phys. Rev. Lett. 109, 135004 (2012)], which is only reproduced by 3D simulations using our MHD code Gorgon when an artificially azimuthally correlated initialisation is added. We have shown that the missing azimuthal correlation could be provided by a combination of the electro-thermal instability (ETI) and an “electro-choric” instability (ECI); describing, respectively, the tendency of current to correlate azimuthally early in time due to temperature dependent Ohmic heating; and an amplification of the ETI driven by density dependent resistivity around vapourisation. We developed and implemented a material strength model in Gorgon to improve simulation of the solid phase of liner implosions which, when applied to simulations exhibiting the ETI and ECI, gave a significant increase in wavelength and amplitude. Full circumference simulations of the MRT instability provided a significant improvement on previous randomly initialised results and approached agreement with experiment.

  14. Hot Cell Liners Category of Transuranic Waste Stored Below Ground within Area G

    SciTech Connect (OSTI)

    Jones, Robert Wesley; Hargis, Kenneth Marshall

    2014-09-01

    A large wildfire called the Las Conchas Fire burned large areas near Los Alamos National Laboratory (LANL) in 2011 and heightened public concern and news media attention over transuranic (TRU) waste stored at LANL’s Technical Area 54 (TA-54) Area G waste management facility. The removal of TRU waste from Area G had been placed at a lower priority in budget decisions for environmental cleanup at LANL because TRU waste removal is not included in the March 2005 Compliance Order on Consent (Reference 1) that is the primary regulatory driver for environmental cleanup at LANL. The Consent Order is an agreement between LANL and the New Mexico Environment Department (NMED) that contains specific requirements and schedules for cleaning up historical contamination at the LANL site. After the Las Conchas Fire, discussions were held by the U.S. Department of Energy (DOE) with the NMED on accelerating TRU waste removal from LANL and disposing it at the Waste Isolation Pilot Plant (WIPP). This report summarizes available information on the origin, configuration, and composition of the waste containers within the Hot Cell Liners category; their physical and radiological characteristics; the results of the radioassays; and the justification to reclassify the five containers as LLW rather than TRU waste.

  15. Experimental demonstration of fusion-relevant conditions in magnetized liner inertial fusion

    SciTech Connect (OSTI)

    Gomez, Matthew R.; Slutz, Stephen A..; Sefkow, Adam B.; Sinars, Daniel B.; Hahn, Kelly D.; Hansen, Stephanie B.; Harding, Eric C.; Knapp, Patrick F.; Schmit, Paul F.; Jennings, Christopher A.; Awe, Thomas James; Geissel, Matthias; Rovang, Dean C.; Chandler, Gordon A.; Cooper, Gary Wayne; Cuneo, Michael Edward; Harvey-Thompson, Adam James; Herrmann, Mark; Hess, M. H.; Johns, Owen; Lamppa, Derek C.; Martin, Matthew R.; McBride, Ryan D.; Peterson, Kyle J.; Porter, John L.; Robertson, Grafton Kincannon; Rochau, Gregory A.; Ruiz, Carlos L.; Savage, Mark E.; Smith, Ian C.; Stygar, William A.; Vesey, Roger A.

    2014-10-06

    This Letter presents results from the first fully integrated experiments testing the magnetized liner inertial fusion concept [S.A. Slutz et al., Phys. Plasmas 17, 056303 (2010)], in which a cylinder of deuterium gas with a preimposed axial magnetic field of 10 T is heated by Z beamlet, a 2.5 kJ, 1 TW laser, and magnetically imploded by a 19 MA current with 100 ns rise time on the Z facility. Despite a predicted peak implosion velocity of only 70 km/s, the fuel reaches a stagnation temperature of approximately 3 keV, with Te ≈ Ti, and produces up to 2e12 thermonuclear DD neutrons. In this study, X-ray emission indicates a hot fuel region with full width at half maximum ranging from 60 to 120 μm over a 6 mm height and lasting approximately 2 ns. The number of secondary deuterium-tritium neutrons observed was greater than 1010, indicating significant fuel magnetization given that the estimated radial areal density of the plasma is only 2 mg/cm2.

  16. Experimental demonstration of fusion-relevant conditions in magnetized liner inertial fusion

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gomez, Matthew R.; Slutz, Stephen A..; Sefkow, Adam B.; Sinars, Daniel B.; Hahn, Kelly D.; Hansen, Stephanie B.; Harding, Eric C.; Knapp, Patrick F.; Schmit, Paul F.; Jennings, Christopher A.; et al

    2014-10-06

    This Letter presents results from the first fully integrated experiments testing the magnetized liner inertial fusion concept [S.A. Slutz et al., Phys. Plasmas 17, 056303 (2010)], in which a cylinder of deuterium gas with a preimposed axial magnetic field of 10 T is heated by Z beamlet, a 2.5 kJ, 1 TW laser, and magnetically imploded by a 19 MA current with 100 ns rise time on the Z facility. Despite a predicted peak implosion velocity of only 70 km/s, the fuel reaches a stagnation temperature of approximately 3 keV, with Te ≈ Ti, and produces up to 2e12 thermonuclearmore » DD neutrons. In this study, X-ray emission indicates a hot fuel region with full width at half maximum ranging from 60 to 120 μm over a 6 mm height and lasting approximately 2 ns. The number of secondary deuterium-tritium neutrons observed was greater than 1010, indicating significant fuel magnetization given that the estimated radial areal density of the plasma is only 2 mg/cm2.« less

  17. OIL WELL REMEDIATION IN CLAY AND WAYNE COUNTIES, IL

    SciTech Connect (OSTI)

    Peter L. Dakuras; Larry Stieber; Dick Young

    2003-02-01

    This is the first technical progress report of the remediation of two wells and a water injection well in Clay County, Illinois. The location is identified as the Routt lease and the wells will be identified as the Routt No.3 and Routt No.4 respectively throughout this report. The Clay County portion of this project has met all legal, financial, and environmental requirements to drill and /or pump oil at this lease. We have also obtained all available information about this site and have taken the necessary steps to improve access roads, dig the necessary pits and build the necessary firewalls. Both wells have been drilled to the Salem formation. Gas gun technology was used to stimulate the reservoir of the Routt No.3. This report will address the technical aspects of the remediation.

  18. On sorption and swelling of CO2 in clays

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Busch, A.; Bertier, P.; Gensterblum, Y.; Rother, G.; Spiers, C. J.; Zhang, M.; Wentinck, H. M.

    2016-03-23

    One well-studied technology is the geological storage of carbon dioxide (CO2), and a number of demonstration projects around the world have proven its feasibility and challenges. Storage conformance and seal integrity are among the most important aspects, as they determine risk of leakage as well as limits for storage capacity and injectivity. By providing evidence for safe storage is critical for improving public acceptance. Most caprocks are composed of clays as dominant mineral type which can typically be illite, kaolinite, chlorite or smectite. A number of recent studies addressed the interaction between CO2 and these different clays and it wasmore » shown that clay minerals adsorb considerable quantities of CO2. For smectite this uptake can lead to volumetric expansion followed by the generation of swelling pressures. On the one hand CO2 adsorption traps CO2, on the other hand swelling pressures can potentially change local stress regimes and in unfavourable situations shear-type failure is assumed to occur. Moreover, for storage in a reservoir having high clay contents the CO2 uptake can add to storage capacity which is widely underestimated so far. Smectite-rich seals in direct contact with a dry CO2 plume at the interface to the reservoir might dehydrate leading to dehydration cracks. Such dehydration cracks can provide pathways for CO2 ingress and further accelerate dewatering and penetration of the seal by supercritical CO2. At the same time, swelling may also lead to the closure of fractures or the reduction of fracture apertures, thereby improving seal integrity. Finally, the goal of this communication is to theoretically evaluate and discuss these scenarios in greater detail in terms of phenomenological mechanisms, but also in terms of potential risks or benefits for carbon storage.« less

  19. Photocatalytic properties of titania pillared clays by different drying methods

    SciTech Connect (OSTI)

    Ding, Z.; Zhu, H.Y.; Lu, G.Q.; Greenfield, P.F.

    1999-01-01

    Photocatalysts based on titania pillared clays (TiO{sub 2} PILCs) have been prepared through a sol-gel method. Different drying methods, air drying (AD), air drying after ethanol extraction (EAD), and supercritical drying (SCD) have been employed and found to have significant effects on the photocatalytic efficiency of the resultant catalysts for the oxidation of phenol in water. Titania pillared clay (TiO{sub 2} PILC) obtained by SCD has the highest external and micropore surface area, largest amount and smallest crystallite size of anatase, and exhibited the highest photocatalytic activity. Furthermore, silica titania pillared clay (SiO{sub 2}-TiO{sub 2} PILC) after SCD, titania coated TiO{sub 2} PILC (SCD) and SiO{sub 2}-TiO{sub 2} PILC (SCD) were synthesized to study the key factors controlling the photocatalytic activity. It is concluded that the dispersion of nanometer-sized anatase on the surface of the PILC particles and the suspensibility of the particles are the most important factors for high photocatalytic efficiency.

  20. Device and method for relativistic electron beam heating of a high-density plasma to drive fast liners

    DOE Patents [OSTI]

    Thode, Lester E.

    1981-01-01

    A device and method for relativistic electron beam heating of a high-density plasma in a small localized region. A relativistic electron beam generator or accelerator produces a high-voltage electron beam which propagates along a vacuum drift tube and is modulated to initiate electron bunching within the beam. The beam is then directed through a low-density gas chamber which provides isolation between the vacuum modulator and the relativistic electron beam target. The relativistic beam is then applied to a high-density target plasma which typically comprises DT, DD, hydrogen boron or similar thermonuclear gas at a density of 10.sup.17 to 10.sup.20 electrons per cubic centimeter. The target gas is ionized prior to application of the electron beam by means of a laser or other preionization source to form a plasma. Utilizing a relativistic electron beam with an individual particle energy exceeding 3 MeV, classical scattering by relativistic electrons passing through isolation foils is negligible. As a result, relativistic streaming instabilities are initiated within the high-density target plasma causing the relativistic electron beam to efficiently deposit its energy and momentum into a small localized region of the high-density plasma target. Fast liners disposed in the high-density target plasma are explosively or ablatively driven to implosion by a heated annular plasma surrounding the fast liner which is generated by an annular relativistic electron beam. An azimuthal magnetic field produced by axial current flow in the annular plasma, causes the energy in the heated annular plasma to converge on the fast liner.

  1. Epoxy-borax-coal tar composition for a radiation protective, burn resistant drum liner and centrifugal casting method

    DOE Patents [OSTI]

    Taylor, Robert S.; Boyer, Norman W.

    1980-01-01

    A boron containing burn resistant, low level radiation protection material useful, for example, as a liner for radioactive waste disposal and storage, a component for neutron absorber, and a shield for a neutron source. The material is basically composed of Borax in the range of 25-50%, coal tar in the range of 25-37.5%, with the remainder being an epoxy resin mix. A preferred composition is 50% Borax, 25% coal tar and 25% epoxy resin. The material is not susceptible to burning and is about 1/5 the cost of existing radiation protection material utilized in similar applications.

  2. Evaluation of Used Fuel Disposition in Clay-Bearing Rock

    SciTech Connect (OSTI)

    Jové Colón, Carlos F.; Weck, Philippe F.; Sassani, David H.; Zheng, Liange; Rutqvist, Jonny; Steefel, Carl I.; Kim, Kunhwi; Nakagawa, Seiji; Houseworth, James; Birkholzer, Jens; Caporuscio, Florie A.; Cheshire, Michael; Rearick, Michael S.; McCarney, Mary K.; Zavarin, Mavrik; Benedicto, Ana; Kersting, Annie B.; Sutton, Mark; Jerden, James; Frey, Kurt E.; Copple, Jacqueline M.; Ebert, William

    2014-08-01

    Radioactive waste disposal in shale/argillite rock formations has been widely considered given its desirable isolation properties (low permeability), geochemically reduced conditions, anomalous groundwater pressures, and widespread geologic occurrence. Clay/shale rock formations are characterized by their high content of clay minerals such as smectites and illites where diffusive transport and chemisorption phenomena predominate. These, in addition to low permeability, are key attributes of shale to impede radionuclide mobility. Shale host-media has been comprehensively studied in international nuclear waste repository programs as part of underground research laboratories (URLs) programs in Switzerland, France, Belgium, and Japan. These investigations, in some cases a decade or more long, have produced a large but fundamental body of information spanning from site characterization data (geological, hydrogeological, geochemical, geomechanical) to controlled experiments on the engineered barrier system (EBS) (barrier clay and seals materials). Evaluation of nuclear waste disposal in shale formations in the USA was conducted in the late 70’s and mid 80’s. Most of these studies evaluated the potential for shale to host a nuclear waste repository but not at the programmatic level of URLs in international repository programs. This report covers various R&D work and capabilities relevant to disposal of heat-generating nuclear waste in shale/argillite media. Integration and cross-fertilization of these capabilities will be utilized in the development and implementation of the shale/argillite reference case planned for FY15. Disposal R&D activities under the UFDC in the past few years have produced state-of-the-art modeling capabilities for coupled Thermal-Hydrological-Mechanical-Chemical (THMC), used fuel degradation (source term), and thermodynamic modeling and database development to evaluate generic disposal concepts. The THMC models have been developed for shale

  3. Evaluation of Used Fuel Disposition in Clay-Bearing Rock (Technical...

    Office of Scientific and Technical Information (OSTI)

    ... and Thermodynamic Database Development: Evaluation Strategy, Modeling Tools, First-Principles Modeling of Clay, and Sorption Database Assessment;ANL Mixed Potential Model For Used Fuel ...

  4. Kathryn Clay, Ph.D. Vice President of Policy Strategy American...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Remarks of Kathryn Clay, Ph.D. Vice President of Policy Strategy American Gas Association PUBLIC MEETING ON ENERGY INFRASTRUCTURE SITING DEPARTMENT OF ENERGY QUADRENNIAL ENERGY ...

  5. Clay Sell Sworn in as Deputy Secretary of Energy | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Clay Sell Sworn in as Deputy Secretary of Energy Clay Sell Sworn in as Deputy Secretary of Energy March 21, 2005 - 10:53am Addthis WASHINGTON, DC - Jeffrey Clay Sell was sworn in today as Deputy Secretary of Energy at a small ceremony held at the Department of Energy headquarters in Washington, DC. Mr. Sell was sworn in by Energy Secretary Samuel W. Bodman after being unanimously confirmed by the United States Senate on Thursday, March 17, 2005. "Clay brings a tremendous amount of knowledge

  6. Note: Effect of hot liner in producing {sup 40,48}Ca beam from RIKEN 18-GHz electron cyclotron resonance ion source

    SciTech Connect (OSTI)

    Ozeki, K. Higurashi, Y.; Kidera, M.; Nakagawa, T.

    2015-01-15

    In order to produce a high-intensity and stable {sup 48}Ca beam from the RIKEN 18-GHz electron cyclotron resonance ion source, we have begun testing the production of a calcium beam using a micro-oven. To minimize the consumption rate of the material ({sup 48}Ca), we introduced the hot liner method and investigated the effect of the liner on the material consumption rate. The micro-oven was first used to produce the {sup 48}Ca beam for experiments in the RIKEN radioisotope beam factory, and a stable beam could be supplied for a long time with low consumption rate.

  7. Ideal hydrodynamic scaling relations for a stagnated imploding spherical plasma liner formed by an array of merging plasma jets

    SciTech Connect (OSTI)

    Cassibry, J. T.; Stanic, M.; Hsu, S. C.

    2013-03-15

    This work presents scaling relations for the peak thermal pressure and stagnation time (over which peak pressure is sustained) for an imploding spherical plasma liner formed by an array of merging plasma jets. Results were derived from three-dimensional (3D) ideal hydrodynamic simulation results obtained using the smoothed particle hydrodynamics code SPHC. The 3D results were compared to equivalent one-dimensional (1D) simulation results. It is found that peak thermal pressure scales linearly with the number of jets and initial jet density and Mach number, quadratically with initial jet radius and velocity, and inversely with the initial jet length and the square of the chamber wall radius. The stagnation time scales approximately as the initial jet length divided by the initial jet velocity. Differences between the 3D and 1D results are attributed to the inclusion of thermal transport, ionization, and perfect symmetry in the 1D simulations. A subset of the results reported here formed the initial design basis for the Plasma Liner Experiment [S. C. Hsu et al., Phys. Plasmas 19, 123514 (2012)].

  8. DEVELOPMENT OF ASME SECTION X CODE RULES FOR HIGH PRESSURE COMPOSITE HYDROGEN PRESSURE VESSELS WITH NON-LOAD SHARING LINERS

    SciTech Connect (OSTI)

    Rawls, G.; Newhouse, N.; Rana, M.; Shelley, B.; Gorman, M.

    2010-04-13

    The Boiler and Pressure Vessel Project Team on Hydrogen Tanks was formed in 2004 to develop Code rules to address the various needs that had been identified for the design and construction of up to 15000 psi hydrogen storage vessel. One of these needs was the development of Code rules for high pressure composite vessels with non-load sharing liners for stationary applications. In 2009, ASME approved new Appendix 8, for Section X Code which contains the rules for these vessels. These vessels are designated as Class III vessels with design pressure ranging from 20.7 MPa (3,000 ps)i to 103.4 MPa (15,000 psi) and maximum allowable outside liner diameter of 2.54 m (100 inches). The maximum design life of these vessels is limited to 20 years. Design, fabrication, and examination requirements have been specified, included Acoustic Emission testing at time of manufacture. The Code rules include the design qualification testing of prototype vessels. Qualification includes proof, expansion, burst, cyclic fatigue, creep, flaw, permeability, torque, penetration, and environmental testing.

  9. Diagenesis and clay mineral formation at Gale Crater, Mars

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bridges, J. C.; Schwenzer, S. P.; Leveille, R.; Westall, F.; Wiens, R. C.; Mangold, N.; Bristow, T.; Edwards, P.; Berger, G.

    2015-01-18

    The Mars Science Laboratory rover Curiosity found host rocks of basaltic composition and alteration assemblages containing clay minerals at Yellowknife Bay, Gale Crater. On the basis of the observed host rock and alteration minerals, we present results of equilibrium thermochemical modeling of the Sheepbed mudstones of Yellowknife Bay in order to constrain the formation conditions of its secondary mineral assemblage. Building on conclusions from sedimentary observations by the Mars Science Laboratory team, we assume diagenetic, in situ alteration. The modeling shows that the mineral assemblage formed by the reaction of a CO₂-poor and oxidizing, dilute aqueous solution (Gale Portage Water)more » in an open system with the Fe-rich basaltic-composition sedimentary rocks at 10–50°C and water/rock ratio (mass of rock reacted with the starting fluid) of 100–1000, pH of ~7.5–12. Model alteration assemblages predominantly contain phyllosilicates (Fe-smectite, chlorite), the bulk composition of a mixture of which is close to that of saponite inferred from Chemistry and Mineralogy data and to that of saponite observed in the nakhlite Martian meteorites and terrestrial analogues. To match the observed clay mineral chemistry, inhomogeneous dissolution dominated by the amorphous phase and olivine is required. We therefore deduce a dissolving composition of approximately 70% amorphous material, with 20% olivine, and 10% whole rock component.« less

  10. Radiolysis of alanine adsorbed in a clay mineral

    SciTech Connect (OSTI)

    Aguilar-Ovando, Ellen Y.; Negron-Mendoza, Alicia

    2013-07-03

    Optical activity in molecules is a chemical characteristic of living beings. In this work, we examine the hypothesis of the influence of different mineral surfaces on the development of a specific chirality in organic molecules when subjected to conditions simulating the primitive Earth during the period of chemical evolution. By using X-ray diffraction techniques and HPLC/ELSD to analyze aqueous suspensions of amino acids adsorbed on minerals irradiated in different doses with a cobalt-60 gamma source, the experiments attempt to prove the hypothesis that some solid surfaces (like clays and meteorite rocks) may have a concentration capacity and protective role against external sources of ionizing radiation (specifically {gamma}-ray) for some organic compounds (like some amino acids) adsorbed on them. Preliminary results show a slight difference in the adsorption and radiolysis of the D-and L-alanine.

  11. Formulation of cracking catalyst based on zeolite and natural clays

    SciTech Connect (OSTI)

    Aliev, R.R.; Lupina, M.I.

    1995-11-01

    Domestically manufactured cracking catalysts are based on a synthetic amorphous aluminosilicate matrix and Y zeolite. A multistage {open_quotes}gel{close_quotes} technology is used in manufacturing the catalysts. The process includes mixing solutions of sodium silicate and acidic aluminum sulfate, forming, syneresis, and activation of the beaded gel. In the manufacture of bead catalysts, the next steps in the process are washing, drying, and calcining; in the manufacture of microbead catalysts, the next steps are dispersion and formation of a hydrogel slurry, spray-drying, and calcining. The Y zeolite is either introduced into the alumina-silica sol in the stage of forming the beads, or introduced in the dispersion stage. With the aim of developing an active and selective cracking catalyst based on Y zeolite and natural clays, with improved physicomechanical properties, the authors carried out a series of studies, obtaining results that are set forth in the present article.

  12. Lanthanides-clay nanocomposites: Synthesis, characterization and optical properties

    SciTech Connect (OSTI)

    Celedon, Salvador; Quiroz, Carolina; Gonzalez, Guillermo; Sotomayor Torres, Clivia M.; Benavente, Eglantina

    2009-05-06

    Complexes of Europium(III) and Terbium(III) with 2,2-bipyridine and 1,10-phenanthroline were inserted into Na-bentonite by ion exchange reactions at room temperature. The products display interlaminar distances and stoichiometries in agreement with the ion exchange capacity and the interlayer space available in the clay. The optical properties of the intercalates, being qualitatively similar to those of the free complexes, are additionally improved with respect to exchange processes with the medium, especially in a moist environment. The protection again hydrolysis, together with the intensity of the optical transition {sup 5}D{sub 0}-{sup 5}F{sub 2} observed in the nanocomposite, makes these products promising for the development of novel optical materials.

  13. MgAl2O4 spinel refractory as containment liner for high-temperature alkali salt containing environments

    DOE Patents [OSTI]

    Peascoe-Meisner, Roberta A [Knoxville, TN; Keiser, James R [Oak Ridge, TN; Hemric, James G [Knoxville, TN; Hubbard, Camden R [Oak Ridge, TN; Gorog, J Peter [Kent, WA; Gupta, Amul [Jamestown, NY

    2008-10-21

    A method includes containing a high-temperature alkali salt containing environment using a refractory containment liner containing MgAl.sub.2O.sub.4 spinel. A method, includes forming a refractory brick containing MgAl.sub.2O.sub.4 spinel having an exterior chill zone defined by substantially columnar crystallization and an interior zone defined by substantially equiaxed crystallization; and removing at least a portion of the exterior chill zone from the refractory brick containing MgAl.sub.2O.sub.4 spinel by scalping the refractory brick containing MgAl.sub.2O.sub.4 spinel to define at least one outer surface having an area of substantially equiaxed crystallization. A product of manufacture includes a refractory brick containing MgAl.sub.2O.sub.4 spinel including an interior zone defined by substantially equiaxed crystallization; and at least one outer surface having an area of substantially equiaxed crystallization.

  14. Characterization of Interlayer Cs+ in Clay Samples Using Secondary Ion Mass Spectrometry with Laser Sample Modification

    SciTech Connect (OSTI)

    G. S. Groenewold; R. Avci; C. Karahan; K. Lefebre; R. V. Fox; M. M. Cortez; A. K. Gianotto; J. Sunner; W. L. Manner

    2004-04-01

    Ultraviolet laser irradiation was used to greatly enhance the secondary ion mass spectrometry (SIMS) detection of Cs+ adsorbed to soil consisting of clay and quartz. Imaging SIMS showed that the enhancement of the Cs+ signal was spatially heterogeneous: the intensity of the Cs+ peak was increased by factors up to 100 for some particles but not at all for others. Analysis of standard clay samples exposed to Cs+ showed a variable response to laser irradiation depending on the type of clay analyzed. The Cs+ abundance was significantly enhanced when Cs+-exposed montmorillonite was irradiated and then analyzed using SIMS, which contrasted with the behavior of Cs+-exposed kaolinite, which displayed no Cs+ enhancement. Exposed illitic clays displayed modest enhancement of Cs+ upon laser irradiation, intermediate between that of kaolinite and montmorillonite. The results for Cs+ were rationalized in terms of adsorption to interlayer sites within the montmorillonite, which is an expandable phyllosilicate. In these locations, Cs+ was not initially detectable using SIMS. Upon irradiation, Cs+ was thermally redistributed, which enabled detection using SIMS. Since neither the illite nor the kaolinite is an expandable clay, adsorption to inner-layer sites does not occur, and either modest or no laser enhancement of the Cs+ signal is observed. Laser irradiation also produced unexpected enhancement of Ti+ from illite and kaolinite clays that contained small quantities of Ti, which indicates the presence of microscopic titanium oxide phases in the clay materials.

  15. Mineralogical evaluation and industrial applications of the Triassic clay deposits, Southern Tunisia

    SciTech Connect (OSTI)

    Baccour, H. Medhioub, M.; Jamoussi, F.; Mhiri, T.; Daoud, A.

    2008-11-15

    This study deals with the mineralogical and thermal analysis of Triassic clays in the south-Eastern Tunisia (Medenine area) in order to use them in the faience ceramic. That is why the study had recourse to several quantitative and qualitative research instruments: chemical analysis, mineralogical study, thermal analyses and analyses of geotechnical traits. The data collected from these techniques show that illite and kaolinite are the major clay phases. The accessory minerals detected in powdered rock are; quartz, dolomite and hematite. Geotechnical characterization was carried out on the three representative mixtures of Triassic clay samples. Each mixture is fired at three different temperatures 850,900 and 950 deg. C. Firing characteristics (shrinkage, water absorption, and mechanical resistance to the inflection) were measured and the neomineralization processes were investigated principally by X-ray diffraction. At the end of this study, one can affirm that these clays have qualities necessary for the manufacture of faience ceramic and earthenware production.

  16. Clay Electric Cooperative, Inc- Energy Smart Solar Water Heater Rebate Program

    Office of Energy Efficiency and Renewable Energy (EERE)

    Clay Electric Cooperative (CEC) provides a rebate of $0.01 per BTU output to its residential members when they purchase qualified solar water heaters. This rebate is capped at 60,000 BTUs per...

  17. Rotating Liner Engine: Improving Efficiency of Heavy Duty Diesels by Significant Friction Reduction, and Extending the Life of Heavy Duty Engines.

    SciTech Connect (OSTI)

    Dardalis, Dimitrios

    2013-12-31

    This report describes the work on converting a 4 cylinder Cummins ISB engine into a single cylinder Rotating Liner Engine functioning prototype that can be used to measure the friction benefits of rotating the cylinder liner in a high pressure compression ignition engine. A similar baseline engine was also prepared, and preliminary testing was done. Even though the fabrication of the single cylinder prototype was behind schedule due to machine shop delays, the fundamental soundness of the design elements are proven, and the engine has successfully functioned. However, the testing approach of the two engines, as envisioned by the original proposal, proved impossible due to torsional vibration resonance caused by the single active piston. A new approach for proper testing has been proposed,

  18. Spherules from the Cretaceous/Tertiary boundary clay at Gubbio, Italy: the problem of outcrop contamination

    SciTech Connect (OSTI)

    Montanari, A.

    1986-12-01

    Surficial outcrop contamination has occurred in some well-known stratigraphic sections of carbonate rocks in the northern Apennines. A critical case involves several contaminated clay partings, including the Cretaceous/Tertiary boundary clay in the classic Bottaccione section near Gubbio, Italy. These clay layers contain shiny spherules which, in several recent studies, have been said to consist of volcanic glass and have been used to support the hypothesis that the terminal Cretaceous mass extinction was caused by widespread volcanism. Laboratory tests, however, indicate that these shiny spherules are made of HF-insoluble and combustible material and are therefore of recent biological origin. These objects were introduced into the Cretaceous/Tertiary boundary clay and other clay layers from the surrounding soil along with abundant detrital contaminants derived from erosion of the middle Miocene flysch exposed at the head of the Bottaccione Gorge. They are completely different from the altered and flattened microtektitelike spheroids that are found only in the iridium-rich Cretaceous/Tertiary boundary clay and that provide strong evidence for a large impact.

  19. Formation of hydrocarbons from acid-Clay suspensions by gamma irradiation

    SciTech Connect (OSTI)

    Cruz-Castaneda, J.; Negron-Mendoza, A.; Ramos-Bernal, S.

    2013-07-03

    The adsorption of certain organic compounds by clays gives rise to the transformation of the adsorbate through the action of the clays. This phenomenon can be enhanced using ionizing radiation. In this context, these kinds of reactions play an important role in many natural and industrial processes. For example, in oil and gas exploration, the source and trap of petroleum hydrocarbons is frequently clay-rich rocks. Clay-water-based muds are also seen as environmentally friendly alternatives to toxic oil-based fluids. The principal processes that occur in sediments are usually held to be of bacterial action and thermal transformation, which may include thermally induced catalytic alteration of the organic debris. On the other hand, radioactive materials are widely distributed throughout Earth. They were more abundant in the past, but are present in petroleum reservoirs. Their presence induced radioactive bombardment, which may have altered these sediments. This important subject has not been extensively studied. The aim of this work is to study the behavior of fatty acids-like behenic acid-and dicarboxylic acids-like fumaric acid-as model compounds, which are adsorbed in a clay mineral (Na-montmorillonite) and exposed to gamma radiation. The results show that the radiation-induced decomposition of the clay-acid system goes along a definitive path (oxidation), rather than following several modes of simultaneous decomposition, as happens in radiolysis without clay or by heating the system. The main radiolytic products for fatty acids are their corresponding hydrocarbons, with one C-atom less than the original acid.

  20. Materials derived from synthetic organo-clay complexes as novel hydrodesulfurization catalyst supports.

    SciTech Connect (OSTI)

    Carrado, K. A.; Marshall, C. L.; Brenner, J. R.; Song, K.; Chemistry

    1998-01-01

    A series of mesoporous synthetic organo-clay complexes has been prepared by hydrothermal crystallization of gels containing silica, magnesium hydroxide, lithium fluoride, and an organic of choice, followed by calcination to remove the organics. The organic serves to impart structural order to the inorganic network that does not disappear upon its removal. The choice of organic modifier can be used to control the pore structure of the resulting mesoporous materials. Pore size distributions appear in some cases to be related to the type of polymer packing upon clay formation in situ. These materials are being explored as Co Mo hydrodesulfurization (HDS) catalyst supports. Preliminary HDS results show performance commensurate with commercial catalysis for the mesoporous materials when a model heavy oil feed is used (1 wt% S as dibenzothiophene in hexadecane). Temperature programmed reduction experiments of used catalysts suggest a relationship between HDS activity and ease of reduction of the CoMo/clay catalysts. Reactivity of the CoMo clay also correlates with the percentage of mesopore volume remaining after reaction. Losses in mesopore volume are largely recouped by recalcination, suggesting that reversible coke is formed inside the pore structure of clays faster than inside conventional alumina.

  1. Report on Modeling Coupled Processes in the Near Field of a Clay Repository

    Broader source: Energy.gov [DOE]

    Clay/shale has been considered as potential host rock for geological disposal of high-level radioactive waste throughout the world. Coupled thermal, hydrological, mechanical, and chemical (THMC) processes have a significant impact on the long-term safety of a clay repository. This report documents results from three R&D activities: (1) implementation and validation of constitutive relationships, (2) development of a discrete fracture network (DFN) model for investigating coupled processes in the excavation damaged zone, and (3) development of a THM model for the Full-Scale Emplacement Experiment tests at Mont Terri, Switzerland, for the purpose of model validation. One major goal is to provide a better understanding of the evolution of the excavation damage zone in clay repositories.

  2. In situ synthesis of polymer-clay nanocomposites from silicate gels.

    SciTech Connect (OSTI)

    Carrado, K. A.; Xu, L.; Chemistry

    1998-01-01

    Polymer-containing silicate gels were hydrothermally crystallized to form layered magnesium silicate hectorite clays containing polymers that are incorporated in situ. Gels consist of silica sol, magnesium hydroxide sol, lithium fluoride, and the polymer of choice. Dilute solutions of gel in water are refluxed for various lengths of time and then isolated via centrifugation, washed, and air-dried. Polymer loadings up to 86% were attained by adding more polymer to the solutions after 2-day reaction times, reacting for another 24 h, and continuing this process prior to isolation. Polyaniline (PANI)- and polyacrylonitrile (PACN)-clay samples contain up to 57% and 76% polymer, respectively, after just one sequential addition at high polymer loading. Series of PANI-, PACN-, poly(vinylpyrrolidone) (PVP)-, and hydroxypropylmethylcellulose (HPMC)-clays also were prepared by several sequential additions of lower polymer loading to the silicate gel during crystallization. Final polymer loadings were determined by thermal analysis. Basal spacings between clay interlayers were measured by X-ray powder diffraction for all samples. Increases in polymer loadings and basal spacings were observed for all the neutral polymers studied, until or unless delamination occurred. Delamination was evident for PACN- and PANI-clay nanocomposites. The highest loadings were observed for the PACN-clays, up to 86%. For the cationic polymer polydimethyldiallylammonium chloride, however, the loading could not be increased beyond about 20%. This is due to electrostatic interactions that balance the negatively charged sites on the silicate lattice with those on the cationic polymer chain. Beyond charge compensation, there is no driving force for further incorporation. Charge compensation in the case of the neutral polymers is attained by interlayer lithium(I) cations.

  3. Dynamics of confined reactive water in smectite clay-zeolite composites

    SciTech Connect (OSTI)

    Pitman, Michael C.; Van Duin, Adri C. T.

    2012-01-01

    The dynamics of water confined to mesoporous regions in minerals such as swelling clays and zeolites is fundamental to a wide range of resource management issues impacting many processes on a global scale, including radioactive waste containment, desalination, and enhanced oil recovery. Large-scale atomic models of freely diffusing multilayer smectite particles at low hydration confined in a silicalite cage are used to investigate water dynamics in the composite environment with the ReaxFF reactive force field over a temperature range of 300 647 K. The reactive capability of the force field enabled a range of relevant surface chemistry to emerge, including acid/base equilibria in the interlayer calcium hydrates and silanol formation on the edges of the clay and inner surface of the zeolite housing. After annealing, the resulting clay models exhibit both mono- and bilayer hydration structures. Clay surface hydration redistributed markedly and yielded to silicalite water loading. We find that the absolute rates and temperature dependence of water dynamics compare well to neutron scattering data and pulse field gradient measures from relevant samples of Ca-montmorillonite and silicalite, respectively. Within an atomistic, reactive context, our results distinguish water dynamics in the interlayer Ca(OH)2 nH2O environment from water flowing over the clay surface, and from water diffusing within silicalite. We find that the diffusion of water when complexed to Ca hydrates is considerably slower than freely diffusing water over the clay surface, and the reduced mobility is well described by a difference in the Arrhenius pre-exponential factor rather than a change in activation energy.

  4. Dynamics of confined reactive water in Smectic clay-zeolite composites.

    SciTech Connect (OSTI)

    Pitman, Michael C.; Van Duin, Adri C. T.

    2012-01-01

    The dynamics of water confined to mesoporous regions in minerals such as swelling clays and zeolites is fundamental to a wide range of resource management issues impacting many processes on a global scale, including radioactive waste containment, desalination, and enhanced oil recovery. Large-scale atomic models of freely diffusing multilayer smectite particles at low hydration confined in a silicalite cage are used to investigate water dynamics in the composite environment with the ReaxFF reactive force field over a temperature range of 300 647 K. The reactive capability of the force field enabled a range of relevant surface chemistry to emerge, including acid/base equilibria in the interlayer calcium hydrates and silanol formation on the edges of the clay and inner surface of the zeolite housing. After annealing, the resulting clay models exhibit both mono- and bilayer hydration structures. Clay surface hydration redistributed markedly and yielded to silicalite water loading. We find that the absolute rates and temperature dependence of water dynamics compare well to neutron scattering data and pulse field gradient measures from relevant samples of Ca-montmorillonite and silicalite, respectively. Within an atomistic, reactive context, our results distinguish water dynamics in the interlayer Ca(OH)2 nH2O environment from water flowing over the clay surface, and from water diffusing within silicalite. We find that the diffusion of water when complexed to Ca hydrates is considerably slower than freely diffusing water over the clay surface, and the reduced mobility is well described by a difference in the Arrhenius pre-exponential factor rather than a change in activation energy.

  5. Report on THMC Modeling of the Near Field Evolution of a Generic Clay Repository: Model Validation and Demonstration Rev 2

    Broader source: Energy.gov [DOE]

    Shale and clay-rich rock formations have been considered as potential host rocks for geological disposal of high-level radioactive waste throughout the world: modeling thermal, hydrological, mechanical, and chemical (THMC) of the near field of generic clay repository is discussed.

  6. Unearthing the Antibacterial Mechanism of Medicinal Clay: A Geochemical Approach to Combating Antibiotic Resistance

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Morrison, Keith D.; Misra, Rajeev; Williams, Lynda B.

    2016-01-08

    Natural antibacterial clays, when hydrated and applied topically, kill human pathogens including antibiotic resistant strains proliferating worldwide. Only certain clays are bactericidal; those containing soluble reduced metals and expandable clay minerals that absorb cations, providing a capacity for extended metal release and production of toxic hydroxyl radicals. Here we show the critical antibacterial components are soluble Fe2+ and Al3+ that synergistically attack multiple cellular systems in pathogens normally growth-limited by Fe supply. This geochemical process is more effective than metal solutions alone and provides an alternative antibacterial strategy to traditional antibiotics. Advanced bioimaging methods and genetic show that Al3+ misfoldsmore » cell membrane proteins, while Fe2+ evokes membrane oxidation and enters the cytoplasm inflicting hydroxyl radical attack on intracellular proteins and DNA. The lethal reaction precipitates Fe3+-oxides as biomolecular damage proceeds. In conclusion, discovery of this bactericidal mechanism demonstrated by natural clays should guide designs of new mineral-based antibacterial agents.« less

  7. Status of LANL investigations of temperature constraints on clay in repository environments

    SciTech Connect (OSTI)

    Caporuscio, Florie A; Cheshire, Michael C; Newell, Dennis L; McCarney, Mary Kate

    2012-08-22

    The Used Fuel Disposition (UFD) Campaign is presently evaluating various generic options for disposal of used fuel. The focus of this experimental work is to characterize and bound Engineered Barrier Systems (EBS) conditions in high heat load repositories. The UFD now has the ability to evaluate multiple EBS materials, waste containers, and rock types at higher heat loads and pressures (including deep boreholes). The geologic conditions now available to the U.S.A. and the international community for repositories include saturated and reduced water conditions, along with higher pressure and temperature (P, T) regimes. Chemical and structural changes to the clays, in either backfill/buffer or clay-rich host rock, may have significant effects on repository evolution. Reduction of smectite expansion capacity and rehydration potential due to heating could affect the isolation provided by EBS. Processes such as cementation by silica precipitation and authigenic illite could change the hydraulic and mechanical properties of clay-rich materials. Experimental studies of these repository conditions at high P,T have not been performed in the U.S. for decades and little has been done by the international community at high P,T. The experiments to be performed by LANL will focus on the importance of repository chemical and mineralogical conditions at elevated P,T conditions. This will provide input to the assessment of scientific basis for elevating the temperature limits in clay barriers.

  8. Clay mineralogy of Lower Cretaceous deep-sea fan sediments, western North Atlantic basin

    SciTech Connect (OSTI)

    Holmes, M.A.

    1986-05-01

    The Lower Cretaceous of the eastern North American continent was a time of extensive deltaic progradation. The effects of deltaic deposition on sedimentation in the western North Atlantic were unknown until May 1982, when, at Deep Sea Drilling Project Site 603 off Cape Hatteras, over 260 m of micaceous, muddy turbidites were recovered that correlate with deltaic progradation on eastern North America. The results of clay mineral studies from onshore and offshore equivalents indicate that during the Cretaceous, some sorting of clay minerals by transport processes occurred. Kaolinite tends to accumulate in continental environments, illite in transitional to marine environments, and smectite in deep sea sediments as pelagic clay. In the sediments from the western North Atlantic, illite tended to be more abundant in thick bedded sandy muds, whereas kaolinite tended to be more abundant in thin bedded muddy sands. Although the occurrence of illite and kaolinite in pelagic sediments indicates a general increased terrigenous influence, the results of this study indicate that these two clays behave independently in these sediments. The presence of large amounts of kaolinite at certain levels in these sediments corresponds to phases of maximum deep-sea fan development, and so indicates a more direct input of continental material, with less sorting of sediments by continental and shelf processes (pericontinental fractionation) prior to redeposition.

  9. Multiphase flow and multicomponent reactive transport model of the ventilation experiment in Opalinus clay

    SciTech Connect (OSTI)

    Zheng, L.; Samper, J.; Montenegro, L.; Major, J.C.

    2008-10-15

    During the construction and operational phases of a high-level radioactive waste (HLW) repository constructed in a clay formation, ventilation of underground drifts will cause desaturation and oxidation of the rock. The Ventilation Experiment (VE) was performed in a 1.3 m diameter unlined horizontal microtunnel on Opalinus clay at Mont Terri underground research laboratory in Switzerland to evaluate the impact of desaturation on rock properties. A multiphase flow and reactive transport model of VE is presented here. The model accounts for liquid, vapor and air flow, evaporation/condensation and multicomponent reactive solute transport with kinetic dissolution of pyrite and siderite and local-equilibrium dissolution/precipitation of calcite, ferrihydrite, dolomite, gypsum and quartz. Model results reproduce measured vapor flow, liquid pressure and hydrochemical data and capture the trends of measured relative humidities, although such data are slightly overestimated near the rock interface due to uncertainties in the turbulence factor. Rock desaturation allows oxygen to diffuse into the rock and triggers pyrite oxidation, dissolution of calcite and siderite, precipitation of ferrihydrite, dolomite and gypsum and cation exchange. pH in the unsaturated rock varies from 7.8 to 8 and is buffered by calcite. Computed changes in the porosity and the permeability of Opalinus clay in the unsaturated zone caused by oxidation and mineral dissolution/precipitation are smaller than 5%. Therefore, rock properties are not expected to be affected significantly by ventilation of underground drifts during construction and operational phases of a HLW repository in clay.

  10. Ceramics Technology Project database: September 1991 summary report. [Materials for piston ring-cylinder liner for advanced heat/diesel engines

    SciTech Connect (OSTI)

    Keyes, B.L.P.

    1992-06-01

    The piston ring-cylinder liner area of the internal combustion engine must withstand very-high-temperature gradients, highly-corrosive environments, and constant friction. Improving the efficiency in the engine requires ring and cylinder liner materials that can survive this abusive environment and lubricants that resist decomposition at elevated temperatures. Wear and friction tests have been done on many material combinations in environments similar to actual use to find the right materials for the situation. This report covers tribology information produced from 1986 through July 1991 by Battelle columbus Laboratories, Caterpillar Inc., and Cummins Engine Company, Inc. for the Ceramic Technology Project (CTP). All data in this report were taken from the project's semiannual and bimonthly progress reports and cover base materials, coatings, and lubricants. The data, including test rig descriptions and material characterizations, are stored in the CTP database and are available to all project participants on request. Objective of this report is to make available the test results from these studies, but not to draw conclusions from these data.

  11. Mesoporous materials derived from synthetic organo-clays as novel hydrodesulfurization catalysts

    SciTech Connect (OSTI)

    Carrado, K.A.; Marshall, C.L.; Brenner, J.R.

    1996-12-31

    Various pore size distributions are found for synthetic organo-clay complexes from which the organic portion has been removed via calcination. The clays are prepared by hydrothermal crystallization of gels containing silica, magnesium hydroxide, lithium fluoride, and an organic of choice. The organic serves to impart long-range structural order to the inorganic network that does not disappear upon its removal. Mesoporous materials are prepared from a host of organic modifiers. For example, pore diameters of 40-50{Angstrom} result from tetraethyl ammonium and celluloses, and polydimethyl diallyl ammonium imparts diameters of about 110{Angstrom} on average. These materials have begun to be explored as hydrodesulfurization (HDS) catalyst supports. Preliminary results show performance commensurate with commercial catalysts for the mesoporous materials when a model oil feed is used (1% dibenzothiophene in hexadecane). The target application is HDS of an actual heavy crude oil from California.

  12. Stereo soft x-ray microscopy and elemental mapping of hematite and clay suspensions

    SciTech Connect (OSTI)

    Gleber, S.-C.; Thieme, J.; Chao, W.; Fischer, P.

    2008-09-01

    The spatial arrangements of hematite particles within aqueous soil and clay samples are investigated with soft X-ray microscopy, taking advantage of the elemental contrast at the Fe-L edge around E = 707 eV. In combination with stereo microscopy, information about spatial arrangements are revealed and correlated to electrostatic interactions of the different mixtures. Manipulation of a sample mounted to the microscope is possible and particles added while imaging can be detected.

  13. Effect of pH on the heavy metal-clay mineral interaction

    SciTech Connect (OSTI)

    Altyn, O.; Oezbelge, H.O.; Dogu, T.; Oezbelge, T.A.

    1997-12-31

    Adsorption and ion exchange of Pb and Cd on the surface of kaolinite and montmorillonite were studied with a strong emphasis on the pH values of solutions containing heavy metal ions. The pH range studied was 2.5 - 9. For kaolinite at a clay/solution ratio of 1/10 (w/w), Pb removal changes from 20 to 30% for an initial Pb concentration of 1640 ppm, and Cd removal changes from 10 to 20% for an initial Cd concentration of 1809 ppm. Due to its high exchange capacity, montmorillonite can remove more heavy metal than kaolinite. Removal rates for montmorillonite can reach up to 90% for both Pb and Cd. In the pH range of 3-6, there is a plateau for the removal rates. At pH values higher than 6, removal seems to increase artificially due to the precipitation of heavy metals. Under similar conditions for both clays, the rate of removal of Pb is always higher than that of Cd. As the pH value decreases for montmorillonite, there is a strong tendency for decreased surface area and swelling, as indicated by BET surface area measurements, adsorbed layer thickness and pore size distribution data. In the range of pH values studied, X-ray diffraction analysis showed the appearance of a characteristic (001) peak for montmorillonite, indicating that the crystalline structure of the clay was intact during the experiments.

  14. Investigations of Near-Field Thermal-Hydrologic-Mechanical-Chemical Models for Radioactive Waste Disposal in Clay/Shale Rock

    SciTech Connect (OSTI)

    Liu, H.H.; Li, L.; Zheng, L.; Houseworth, J.E.; Rutqvist, J.

    2011-06-20

    Clay/shale has been considered as potential host rock for geological disposal of high-level radioactive waste throughout the world, because of its low permeability, low diffusion coefficient, high retention capacity for radionuclides, and capability to self-seal fractures. For example, Callovo-Oxfordian argillites at the Bure site, France (Fouche et al., 2004), Toarcian argillites at the Tournemire site, France (Patriarche et al., 2004), Opalinus Clay at the Mont Terri site, Switzerland (Meier et al., 2000), and Boom clay at the Mol site, Belgium (Barnichon and Volckaert, 2003) have all been under intensive scientific investigation (at both field and laboratory scales) for understanding a variety of rock properties and their relationships to flow and transport processes associated with geological disposal of radioactive waste. Figure 1-1 presents the distribution of clay/shale formations within the USA.

  15. Variations in clay mineralogy and sediment texture of salt marsh soils on the Eastern Shore of Virginia

    SciTech Connect (OSTI)

    Robinson, S.E.; Furman, T. . Dept. of Environmental Sciences)

    1993-03-01

    On the Eastern Shore of VA, relative sea level rise has resulted in encroachment of marsh onto upland areas. The amount and type of sediment determines the morphologic environment of the system: lagoon, mudflat, low marsh, high marsh or upland. This research is part of a study to examine the relationship between marsh soil characteristics and the production of Spartina alterniflora. The productivity of marsh vegetation depends on the import and entrapment of sediments that maintain marsh elevation and control water and nutrient availability. This work focused on distribution patterns of sediment texture and mineralogy. One meter deep cores were taken at marsh sites with 10 cm intervals homogenized for analysis. In order to distinguish potential sediment sources, samples were also taken from upland soil pits on the mainland and dredged one-half mile seaward of the barrier islands. Samples have undergone size analysis with a hydrometer and the clay fraction has been analyzed by XRD. Results from the marsh surface indicate large variations in sediment texture, but only slight differences in clay mineralogy between marshes. Barrier island marshes contain a higher average sand content than mainland marshes because of their closer proximity to barrier island beaches and inputs from overwash deposits. The clay minerals found in all marsh surface deposits are illite and chlorite, indicative of oceanic clays. The clay mineralogy of upland soils (kaolinite, chlorite, illite, vermiculite mixed-layer clay) differs from marsh surface clays, indicating that recent sediment deposited on the marsh surface is no upland soil but rather material brought in through tidal inlets. The sediment texture and clay mineralogy at different depths varies as a function of the past geomorphic and depositional history of the site. These data will be used to determine the timing of marsh development on flooded upland sites and to determine the pre-Holocene source of inorganic sediment inputs.

  16. Molecular Simulation of Structure and Diffusion at Smectite-Water Interfaces: Using Expanded Clay Interlayers as Model Nanopores

    SciTech Connect (OSTI)

    Greathouse, Jeffery A.; Hart, David; Bowers, Geoffrey M.; Kirkpatrick, R. James; Cygan, Randall Timothy

    2015-07-20

    In geologic settings relevant to a number of extraction and potential sequestration processes, nanopores bounded by clay mineral surfaces play a critical role in the transport of aqueous species. Solution structure and dynamics at claywater interfaces are quite different from their bulk values, and the spatial extent of this disruption remains a topic of current interest. We have used molecular dynamics simulations to investigate the structure and diffusion of aqueous solutions in clay nanopores approximately 6 nm thick, comparing the effect of clay composition with model Na-hectorite and Na-montmorillonite surfaces. In addition to structural properties at the interface, water and ion diffusion coefficients were calculated within each aqueous layer at the interface, as well as in the central bulk-like region of the nanopore. The results show similar solution structure and diffusion properties at each surface, with subtle differences in sodium adsorption complexes and water structure in the first adsorbed layer due to different arrangements of layer hydroxyl groups in the two clay models. Interestingly, the extent of surface disruption on bulk-like solution structure and diffusion extends to only a few water layers. Additionally, a comparison of sodium ion residence times confirms similar behavior of inner-sphere and outer-sphere surface complexes at each clay surface, but ~1% of sodium ions adsorb in ditrigonal cavities on the hectorite surface. Thus, the presence of these anhydrous ions is consistent with highly immobile anhydrous ions seen in previous nuclear magnetic resonance spectroscopic measurements of hectorite pastes.

  17. 488-4D ASH LANDFILL CLOSURE CAP HELP MODELING

    SciTech Connect (OSTI)

    Phifer, M.

    2014-11-17

    At the request of Area Completion Projects (ACP) in support of the 488-4D Landfill closure, the Savannah River National Laboratory (SRNL) has performed Hydrologic Evaluation of Landfill Performance (HELP) modeling of the planned 488-4D Ash Landfill closure cap to ensure that the South Carolina Department of Health and Environmental Control (SCDHEC) limit of no more than 12 inches of head on top of the barrier layer (saturated hydraulic conductivity of no more than 1.0E-05 cm/s) in association with a 25-year, 24-hour storm event is not projected to be exceeded. Based upon Weber 1998 a 25-year, 24-hour storm event at the Savannah River Site (SRS) is 6.1 inches. The results of the HELP modeling indicate that the greatest peak daily head on top of the barrier layer (i.e. geosynthetic clay liner (GCL) or high density polyethylene (HDPE) geomembrane) for any of the runs made was 0.079 inches associated with a peak daily precipitation of 6.16 inches. This is well below the SCDHEC limit of 12 inches.

  18. Synthesis and characterization of a PbO{sub 2}-clay nanocomposite: Removal of lead from water using montmorillonite

    SciTech Connect (OSTI)

    Aroui, L.; Zerroual, L.; Boutahala, M.

    2012-02-15

    Graphical abstract: The replacement of Na by Pb in the interlayer space of the smectite leads to a decrease in the intensity of the the (0 0 1) reflection as the concentration of lead nitrate increases. A significant restructuring at the particle scale is observed leading probably to the exfoliation of the caly. In addition, the thermal behaviour of the montmorillonite samples with regard to their dehydration and dehydroxilation capacities is significantly influenced. This leads to a lowering of the water content and a decrease in the ionic conductivity of the clay. Highlights: Black-Right-Pointing-Pointer In the clay, Pb replaces Na ions and a significant restructuring at the particle scale is observed. Black-Right-Pointing-Pointer Pb influenced significantly the thermal behaviour of the clay with regard to its dehydration. Black-Right-Pointing-Pointer In the interlayer space, the exchange of Na by Pb leads to a decrease in the protonic conductivity. Black-Right-Pointing-Pointer A PbO{sub 2}-clay nanocomposite material with good conductivity is synthesized. -- Abstract: The aim of this paper is to present the results obtained with Pb(II) sorption on an Algerian Clay. The experiments were carried out using a batch process. Powder X-rays diffraction patterns (PXRD) prove that in the montmorillonite Pb replaces Na ions. A significant restructuring at the particle scale is observed leading to the disappearance of the d{sub 001} reflection of the clay at high concentrations of lead. The replacement of hydrated Na with Pb ions influenced significantly the thermal behaviour of the montmorillonite samples with regard to their dehydration and dehydroxilation capacities with a lowering of the water content. A PbO{sub 2}-clay composite material with good electrical conductivity is synthesized.

  19. Clay-sewage sludge co-pyrolysis. A TG-MS and Py-GC study on potential advantages afforded by the presence of clay in the pyrolysis of wastewater sewage sludge

    SciTech Connect (OSTI)

    Ischia, Marco; Maschio, Roberto Dal; Grigiante, Maurizio; Baratieri, Marco

    2011-01-15

    Wastewater sewage sludge was co-pyrolyzed with a well characterized clay sample, in order to evaluate possible advantages in the thermal disposal process of solid waste. Characterization of the co-pyrolysis process was carried out both by thermogravimetric-mass spectrometric (TG-MS) analysis, and by reactor tests, using a lab-scale batch reactor equipped with a gas chromatograph for analysis of the evolved gas phase (Py-GC). Due to the presence of clay, two main effects were observed in the instrumental characterization of the process. Firstly, the clay surface catalyzed the pyrolysis reaction of the sludge, and secondly, the release of water from the clay, at temperatures of approx. 450-500 deg. C, enhanced gasification of part of carbon residue of the organic component of sludge following pyrolysis. Moreover, the solid residue remaining after pyrolysis process, composed of the inorganic component of sludge blended with clay, is characterized by good features for possible disposal by vitrification, yielding a vitreous matrix that immobilizes the hazardous heavy metals present in the sludge.

  20. Effects of biogenic silica on acoustic and physical properties of clay-rich marine sediments

    SciTech Connect (OSTI)

    Tribble, J.S.; Mackenzie, F.T.; Urmos, J.; O'Brien, D.K.; Manghnani, M.H. )

    1992-06-01

    The physical properties of marine sediments are influenced by compaction and diagenesis during burial. Changes in mineralogy, chemistry, density, porosity, and microfabric all affect a sediment's acoustic and electrical properties. Sediments from the Japan Trench illustrate the dependence of physical properties on biogenic silica content. Increased opal-A content is correlated with increased porosity and decreased grain density and compressional velocity. Variations with depth in opal-A concentration are therefore reflected in highly variable and, at times, inverse velocity-depth gradients. The diagenetic conversion of opal-A to opal-CT and finally to quartz was investigated at a site in the San Miguel Gap, California. Distinct changes in microfabric, particularly in the porosity distribution, accompany the diagenetic reactions and contribute to a sharp velocity discontinuity at the depth of the opal-A to opal-CT conversion. Evaluation of this reaction at several sites indicates a systematic dependence on temperature and age in clay-rich and moderately siliceous sediments. In ocean margin regions, sediments are buried rapidly, and opal-A may be converted to opal-CT in less than 10 m.y. Temperatures of conversion range from 30{degree} to 50{degree}C. Much longer times (>40 m.y.) are required to complete the conversion in open ocean deposits which are exposed to temperatures less than 15{degree}C. In the absence of silica diagenesis, velocity-depth gradients of most clay-rich and moderately siliceous sediments fall in the narrow range of 0.15 to 0.25 km/s/km which brackets the gradient (0.18 km/s/km) determined for a type pelagic clay section. Relationships such as these can be useful in unraveling the history of a sediment sequence, including the evolution with time of reservoir properties and seismic signatures.

  1. Inelastic neutron scattering and molecular simulation of the dynamics of interlayer water in smectite clay minerals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cygan, Randall T.; Daemen, Luke L.; Ilgen, Anastasia G.; Krumhansl, James L.; Nenoff, Tina M.

    2015-11-16

    The study of mineral–water interfaces is of great importance to a variety of applications including oil and gas extraction, gas subsurface storage, environmental contaminant treatment, and nuclear waste repositories. Understanding the fundamentals of that interface is key to the success of those applications. Confinement of water in the interlayer of smectite clay minerals provides a unique environment to examine the interactions among water molecules, interlayer cations, and clay mineral surfaces. Smectite minerals are characterized by a relatively low layer charge that allows the clay to swell with increasing water content. Montmorillonite and beidellite varieties of smectite were investigated to comparemore » the impact of the location of layer charge on the interlayer structure and dynamics. Inelastic neutron scattering of hydrated and dehydrated cation-exchanged smectites was used to probe the dynamics of the interlayer water (200–900 cm–1 spectral region) and identify the shift in the librational edge as a function of the interlayer cation. Molecular dynamics simulations of equivalent phases and power spectra, derived from the resulting molecular trajectories, indicate a general shift in the librational behavior with interlayer cation that is generally consistent with the neutron scattering results for the monolayer hydrates. Both neutron scattering and power spectra exhibit librational structures affected by the location of layer charge and by the charge of the interlayer cation. Furthermore, divalent cations (Ba2+ and Mg2+) characterized by large hydration enthalpies typically exhibit multiple broad librational peaks compared to monovalent cations (Cs+ and Na+), which have relatively small hydration enthalpies.« less

  2. Inelastic neutron scattering and molecular simulation of the dynamics of interlayer water in smectite clay minerals

    SciTech Connect (OSTI)

    Cygan, Randall T.; Daemen, Luke L.; Ilgen, Anastasia G.; Krumhansl, James L.; Nenoff, Tina M.

    2015-11-16

    The study of mineral–water interfaces is of great importance to a variety of applications including oil and gas extraction, gas subsurface storage, environmental contaminant treatment, and nuclear waste repositories. Understanding the fundamentals of that interface is key to the success of those applications. Confinement of water in the interlayer of smectite clay minerals provides a unique environment to examine the interactions among water molecules, interlayer cations, and clay mineral surfaces. Smectite minerals are characterized by a relatively low layer charge that allows the clay to swell with increasing water content. Montmorillonite and beidellite varieties of smectite were investigated to compare the impact of the location of layer charge on the interlayer structure and dynamics. Inelastic neutron scattering of hydrated and dehydrated cation-exchanged smectites was used to probe the dynamics of the interlayer water (200–900 cm–1 spectral region) and identify the shift in the librational edge as a function of the interlayer cation. Molecular dynamics simulations of equivalent phases and power spectra, derived from the resulting molecular trajectories, indicate a general shift in the librational behavior with interlayer cation that is generally consistent with the neutron scattering results for the monolayer hydrates. Both neutron scattering and power spectra exhibit librational structures affected by the location of layer charge and by the charge of the interlayer cation. Furthermore, divalent cations (Ba2+ and Mg2+) characterized by large hydration enthalpies typically exhibit multiple broad librational peaks compared to monovalent cations (Cs+ and Na+), which have relatively small hydration enthalpies.

  3. GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY

    U.S. Energy Information Administration (EIA) Indexed Site

    GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY GLENVILLE N MINNORA JARVISVILLE FAR MINGTON PH ILIPPI BELIN GT ON WAYN ESBUR G PR UNT Y GLENVILLE S CAVE RUN TAYLOR DRAIN ROSEDALE ST MPT-N RMNT-SHK WESTON-JAN E LEW SWN DL-WID EN VADIS STANL EY DEKALB UNION TALLM AN SVILL E ASPINALL-FIN ST ER ZOLLARSVILLE WILBU R RAMSEY HEATER S BR IDGEPORT-PRUNT YTOWN ALEXAND ER LILLY FORK SH ERMAN HIRAM ST FK-BLST N CK BU RNS CH APEL S BR WN -LUM BER PORT CON INGS PR ATT BOSWELL REVEL ELK C REEK

  4. Molecular simulation of structure and diffusion at smectite-water interfaces: Using expanded clay interlayers as model nanopores

    SciTech Connect (OSTI)

    Greathouse, Jeffery A.; Hart, David; Bowers, Geoffrey M.; Kirkpatrick, R. James; Cygan, Randall Timothy

    2015-07-20

    In geologic settings relevant to a number of extraction and potential sequestration processes, nanopores bounded by clay mineral surfaces play a critical role in the transport of aqueous species. Solution structure and dynamics at clay–water interfaces are quite different from their bulk values, and the spatial extent of this disruption remains a topic of current interest. We have used molecular dynamics simulations to investigate the structure and diffusion of aqueous solutions in clay nanopores approximately 6 nm thick, comparing the effect of clay composition with model Na-hectorite and Na-montmorillonite surfaces. In addition to structural properties at the interface, water and ion diffusion coefficients were calculated within each aqueous layer at the interface, as well as in the central bulk-like region of the nanopore. The results show similar solution structure and diffusion properties at each surface, with subtle differences in sodium adsorption complexes and water structure in the first adsorbed layer due to different arrangements of layer hydroxyl groups in the two clay models. Interestingly, the extent of surface disruption on bulk-like solution structure and diffusion extends to only a few water layers. Additionally, a comparison of sodium ion residence times confirms similar behavior of inner-sphere and outer-sphere surface complexes at each clay surface, but ~1% of sodium ions adsorb in ditrigonal cavities on the hectorite surface. Thus, the presence of these anhydrous ions is consistent with highly immobile anhydrous ions seen in previous nuclear magnetic resonance spectroscopic measurements of hectorite pastes.

  5. Steep-Slope Assembly Testing of Clay and Concrete Tile With and Without Cool Pigmented Colors

    SciTech Connect (OSTI)

    Miller, William A

    2005-11-01

    Cool color pigments and sub-tile venting of clay and concrete tile roofs significantly impact the heat flow crossing the roof deck of a steep-slope roof. Field measures for the tile roofs revealed a 70% drop in the peak heat flow crossing the deck as compared to a direct-nailed asphalt shingle roof. The Tile Roofing Institute (TRI) and its affiliate members are keenly interested in documenting the magnitude of the drop for obtaining solar reflectance credits with state and federal "cool roof" building efficiency standards. Tile roofs are direct-nailed or are attached to a deck with batten or batten and counter-batten construction. S-Misson clay and concrete tile roofs, a medium-profile concrete tile roof, and a flat slate tile roof were installed on fully nstrumented attic test assemblies. Temperature measures of the roof, deck, attic, and ceiling, heat flows, solar reflectance, thermal emittance, and the ambient weather were recorded for each of the tile roofs and also on an adjacent attic cavity covered with a conventional pigmented and directnailed asphalt shingle roof. ORNL measured the tile's underside temperature and the bulk air temperature and heat flows just underneath the tile for batten and counter-batten tile systems and compared the results to the conventional asphalt shingle.

  6. Characterization of Two Different Clay Materials by Thermogravimetry (TG), Differential Scanning Calorimetry (DSC), Dilatometry (DIL) and Mass Spectrometry (MS) - 12215

    SciTech Connect (OSTI)

    Post, Ekkehard; Henderson, Jack B.

    2012-07-01

    An illitic clay containing higher amounts of organic materials was investigated by dilatometry, thermogravimetry and differential scanning calorimetric. The evolved gases were studied during simultaneous TG-DSC (STA) and dilatometer measurements with simultaneous mass spectrometry in inert gas and oxidizing atmosphere. The dilatometer results were compared with the STA-MS results which confirmed and explained the reactions found during heating of the clay, like dehydration, dehydroxylation, shrinkage, sintering, quartz phase transition, combustion or pyrolysis of organics and the solid state reactions forming meta-kaolinite and mullite. The high amount of organic material effects in inert gas atmosphere most probably a reduction of the oxides which leads to a higher mass loss than in oxidizing atmosphere. Due to this reduction an additional CO{sub 2} emission at around 1000 deg. C was detected which did not occur in oxidizing atmosphere. Furthermore TG-MS results of a clay containing alkali nitrates show that during heating, in addition to water and CO{sub 2}, NO and NO{sub 2} are also evolved, leading to additional mass loss steps. These types of clays showed water loss starting around 100 deg. C or even earlier. This relative small mass loss affects only less shrinkage during the expansion of the sample. The dehydroxylation and the high crystalline quartz content result in considerable shrinkage and expansion of the clay. During the usual solid state reaction where the clay structure collapses, the remaining material finally shrinks down to a so-called clinker. With the help of MS the TG steps can be better interpreted as the evolved gases are identified. With the help of the MS it is possible to distinguish between CO{sub 2} and water (carbonate decomposition, oxidation of organics or dehydration/dehydroxylation). The MS also clearly shows that mass number 44 is found during the TG step of the illitic clay at about 900 deg. C in inert gas, which was interpreted

  7. CO2 Storage by Sorption on Organic Matter and Clay in Gas Shale

    SciTech Connect (OSTI)

    Bacon, Diana H.; Yonkofski, Catherine MR; Schaef, Herbert T.; White, Mark D.; McGrail, B. Peter

    2015-10-10

    Simulations of methane production and supercritical carbon dioxide injection were developed that consider competitive adsorption of CH4 and CO2 on both organic matter and montmorillonite. The results were used to assess the potential for storage of CO2 in a hydraulically fractured shale gas reservoir and for enhanced recovery of CH4. Assuming equal volume fractions of organic matter and montmorillonite, amounts of CO2 adsorbed on both materials were comparable, while methane desorption was from clays was two times greater than desorption from organic material. The most successful strategy considered CO2 injection from a separate well and enhanced methane recovery by 73%, while storing 240 kmt of CO2.

  8. Molecular simulation of structure and diffusion at smectite-water interfaces: Using expanded clay interlayers as model nanopores

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Greathouse, Jeffery A.; Hart, David; Bowers, Geoffrey M.; Kirkpatrick, R. James; Cygan, Randall Timothy

    2015-07-20

    In geologic settings relevant to a number of extraction and potential sequestration processes, nanopores bounded by clay mineral surfaces play a critical role in the transport of aqueous species. Solution structure and dynamics at clay–water interfaces are quite different from their bulk values, and the spatial extent of this disruption remains a topic of current interest. We have used molecular dynamics simulations to investigate the structure and diffusion of aqueous solutions in clay nanopores approximately 6 nm thick, comparing the effect of clay composition with model Na-hectorite and Na-montmorillonite surfaces. In addition to structural properties at the interface, water andmore » ion diffusion coefficients were calculated within each aqueous layer at the interface, as well as in the central bulk-like region of the nanopore. The results show similar solution structure and diffusion properties at each surface, with subtle differences in sodium adsorption complexes and water structure in the first adsorbed layer due to different arrangements of layer hydroxyl groups in the two clay models. Interestingly, the extent of surface disruption on bulk-like solution structure and diffusion extends to only a few water layers. Additionally, a comparison of sodium ion residence times confirms similar behavior of inner-sphere and outer-sphere surface complexes at each clay surface, but ~1% of sodium ions adsorb in ditrigonal cavities on the hectorite surface. Thus, the presence of these anhydrous ions is consistent with highly immobile anhydrous ions seen in previous nuclear magnetic resonance spectroscopic measurements of hectorite pastes.« less

  9. Confinement analyses of the high-density field-reversed configuration plasma in the field-reversed configuration experiment with a liner

    SciTech Connect (OSTI)

    Zhang Shouyin; Intrator, T.P.; Wurden, G.A.; Waganaar, W.J.; Taccetti, J.M.; Renneke, R.; Grabowski, C.; Ruden, E.L.

    2005-05-15

    The focus of the field-reversed configuration (FRC) experiment with a liner (FRX-L) is the formation of a target FRC plasma for magnetized target fusion experiments. An FRC plasma with density of 10{sup 23} m{sup -3}, total temperature in the range of 150-300 eV, and a lifetime of {approx_equal}20 {mu}s is desired. Field-reversed {theta}-pinch technology is used with programed cusp fields at {theta}-coil ends to achieve non-tearing field line reconnections during FRC formation. Well-formed FRCs with density between (2-4)x10{sup 22} m{sup -3}, lifetime in the range of 15-20 {mu}s, and total temperature between 300-500 eV are reproducibly created. Key FRC parameters have standard deviation in the mean of 10% during consecutive shots. The FRCs are formed at 50 mTorr deuterium static fill using 2 kG net reversed bias field inside the {theta}-coil confinement region, with external main field unexpectedly ranging between 15-30 kG. The high-density FRCs confinement properties are approximately in agreement with empirical scaling laws obtained from previous experiments with fill pressure mostly less than 20 mTorr. Analyses in this paper reveal that reducing the external main field modulation and/or extending the {theta}-coil length in the FRX-L device are critical in achieving higher FRC parameters for application in magnetized target fusion.

  10. Replacemernt of thermally produced calcined clay with chemically structured pigments and methods for the same, quarterly report, January 1, 1995-April 1, 1995

    SciTech Connect (OSTI)

    Whalen-Shaw, M.

    1995-04-25

    The business objective is to manufacture an economically viable chemically structured clay to replace thermally structured calcined clay. The technology will provide substantial benefit in paper coating. The structured pigment containing 90% clay and 10% TiO2 vs the loose blend of these materials as a filler for paper was evaluated. A plan to improve the permanence of the structured pigment using dual functional dispersed pigments is in place. The cationic dispersant for TiO2 will also be a binder. Spray drying will be use to fix the structure of the internally bound structured pigment.

  11. borrow_area.cdr

    Office of Legacy Management (LM)

    Howell High School across Highway 94. The excavated clay soil was used for foundation backfill, clay liners, clean-fill perimeter dikes, and the radon barrier in the disposal cell. ...

  12. Capillary suction-time tests on selected clays and shales. Master's thesis

    SciTech Connect (OSTI)

    Hart, K.M.

    1989-05-01

    Shale stability has been an ongoing problem in the drilling of oil wells. The Capillary Suction Time test is simple and easy to use, allowing operators to conduct the test at the rigsite. However because of difficulty in reproducing results, the test should be used only qualitatively. The CST, along with the Methylene Blue, Specific Surface Area and Ensilin tests, accurately predicts shale swelling and dispersion. The tests have the added advantage of being able to be conducted relatively quickly. These tests could be carried out at the rigsite while the drilling is taking place. The experiments conducted also demonstrated the usefulness of KCL as an inhibitor of shale swelling and dispersion. From the CST data, it can be seen that KCL concentrations as low as 0.5% are effective in controlling the swelling of Phillips Ekofisk, Phillips Andrews County, Texaco Mississippi Canyon and Pierre Texaco. However a greater concentration of KCL is required to inhibit the swelling of Gold Seal Bentonite, Standard Arizona, Standard Wyoming and Standard Texas. It is recommended that more concentrations of KCL be tested of the high swelling clays to determine the minimum concentration required to inhibit swelling and dispersion.

  13. Swelling properties of montmorillonite and beidellite clay minerals from molecular simulation: Comparison of temperature interlayer cation, and charge location effects

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Teich-McGoldrick, Stephanie L.; Greathouse, Jeffery A.; Jove-Colon, Carlos F.; Cygan, Randall Timothy

    2015-08-27

    In this study, the swelling properties of smectite clay minerals are relevant to many engineering applications including environmental remediation, repository design for nuclear waste disposal, borehole stability in drilling operations, and additives for numerous industrial processes and commercial products. We used molecular dynamics and grand canonical Monte Carlo simulations to study the effects of layer charge location, interlayer cation, and temperature on intracrystalline swelling of montmorillonite and beidellite clay minerals. For a beidellite model with layer charge exclusively in the tetrahedral sheet, strong ion–surface interactions shift the onset of the two-layer hydrate to higher water contents. In contrast, for amore » montmorillonite model with layer charge exclusively in the octahedral sheet, weaker ion–surface interactions result in the formation of fully hydrated ions (two-layer hydrate) at much lower water contents. Clay hydration enthalpies and interlayer atomic density profiles are consistent with the swelling results. Water adsorption isotherms from grand canonical Monte Carlo simulations are used to relate interlayer hydration states to relative humidity, in good agreement with experimental findings.« less

  14. Swelling properties of montmorillonite and beidellite clay minerals from molecular simulation: Comparison of temperature interlayer cation, and charge location effects

    SciTech Connect (OSTI)

    Teich-McGoldrick, Stephanie L.; Greathouse, Jeffery A.; Jove-Colon, Carlos F.; Cygan, Randall Timothy

    2015-08-27

    In this study, the swelling properties of smectite clay minerals are relevant to many engineering applications including environmental remediation, repository design for nuclear waste disposal, borehole stability in drilling operations, and additives for numerous industrial processes and commercial products. We used molecular dynamics and grand canonical Monte Carlo simulations to study the effects of layer charge location, interlayer cation, and temperature on intracrystalline swelling of montmorillonite and beidellite clay minerals. For a beidellite model with layer charge exclusively in the tetrahedral sheet, strong ion–surface interactions shift the onset of the two-layer hydrate to higher water contents. In contrast, for a montmorillonite model with layer charge exclusively in the octahedral sheet, weaker ion–surface interactions result in the formation of fully hydrated ions (two-layer hydrate) at much lower water contents. Clay hydration enthalpies and interlayer atomic density profiles are consistent with the swelling results. Water adsorption isotherms from grand canonical Monte Carlo simulations are used to relate interlayer hydration states to relative humidity, in good agreement with experimental findings.

  15. Petrographic report on clay-rich samples from Permian Unit 4 salt, G. Friemel No. 1 well, Palo Duro Basin, Deaf Smith County, Texas: unanalyzed data

    SciTech Connect (OSTI)

    Fukui, L M

    1983-09-01

    This report presents the results of mineralogic and petrographic analyses performed on five samples of clay-rich rock from salt-bearing Permian strata sampled by drill core from G. Friemel No. 1 Well, Deaf Smith County, Texas. Five samples of clay-rich rock from depths of about 2457, 2458, 2521, 2548, and 2568 feet were analyzed to determine the amounts of soluble phase (halite) and the amounts and mineralogy of the insoluble phases. The amounts of halite found were 59, 79, 47, 40, and 4 weight percent, respectively, for the samples. The insoluble minerals are predominately clay (20 to 60 volume percent) and anhydrite (up to 17 volume percent), with minor (about 1.0%) and trace amounts of quartz, dolomite, muscovite, and gypsum. The clays include illite, chlorite, and interstratified chlorite-smectite. The results presented in this petrographic report are descriptive, uninterpreted data. 2 references, 7 tables.

  16. Design of the Long-term Waste Management Facility for Historic LLRW Port Hope Project - 13322

    SciTech Connect (OSTI)

    Campbell, Don; Barton, David; Case, Glenn

    2013-07-01

    The Municipality of Port Hope is located on the northern shores of Lake Ontario approximately 100 km east of Toronto, Ontario, Canada. Starting in the 1930's, radium and later uranium processing by Eldorado Gold Mines Limited (subsequently Eldorado Nuclear Limited) (Eldorado) at their refinery in Port Hope resulted in the generation of process residues and wastes that were disposed of indiscriminately throughout the Municipality until about the mid-1950's. These process residues contained radium (Ra- 226), uranium, arsenic and other contaminants. Between 1944 and 1988, Eldorado was a Federal Crown Corporation, and as such, the Canadian Federal Government has assumed responsibility for the clean-up and long-term management of the historic waste produced by Eldorado during this period. The Port Hope Project involves the construction and development of a new long-term waste management facility (LTWMF), and the remediation and transfer of the historic wastes located within the Municipality of Port Hope to the new LTWMF. The new LTWMF will consist of an engineered above-ground containment mound designed to contain and isolate the wastes from the surrounding environment for the next several hundred years. The design of the engineered containment mound consists of a primary and secondary composite base liner system and composite final cover system, made up of both natural materials (e.g., compacted clay, granular materials) and synthetic materials (e.g., geo-synthetic clay liner, geo-membrane, geo-textiles). The engineered containment mound will cover an area of approximately 13 hectares and will contain the estimated 1.2 million cubic metres of waste that will be generated from the remedial activities within Port Hope. The LTWMF will also include infrastructure and support facilities such as access roads, administrative offices, laboratory, equipment and personnel decontamination facilities, waste water treatment plant and other ancillary facilities. Preliminary

  17. Field test of plutonium and thorium contaminated clay soils from the Mound Site using the ACT*DE*CON Process

    SciTech Connect (OSTI)

    Johnson, J.O.; Swift, N.A.; Church, R.H.; Neff, R.A.

    1998-12-31

    A treatability test was run during the summer and fall of 1997 to demonstrate the effectiveness of ACT*DE*CON for removing plutonium and thorium from the clay soils around Mound. ACT*DE*CON is a proprietary solution patented by Selentec. The process utilized a highly selective dissolution of the contaminants by the use of a chemical wash. The pilot scale process involved pretreatment of the soil in an attrition scrubber with ACT*DE*CON solution. This blended solution was then passed through a counter-current extraction chamber where additional contact with ACT*DE*CON solution occurred, followed by a rinse cycle. During this process sand was added to aid contact of the solution with the soil particles. The sand is removed during the rinse step and reused. The chelating agent is separated from the contaminant and recycled back into the process, along with the reverse osmosis permeate. The resulting solution can be further treated to concentrate the contaminant. Three different types of environmental soils were tested -- plutonium and thorium contaminated soils with the natural clay content, and plutonium contaminated soils with a high percentage of fine clay particles. The goal of these tests was to reduce the plutonium levels from several hundreds of pCi/g to between 25 and 75 pCi/g and the thorium from a couple hundred pCi/g to less than 5 pCi/g. The results of these four tests are presented along with a discussion of the operating parameters and the lessons learned relating to full scale implementation at Mound as well as other potential applications of this process.

  18. Corrective Action Plan for Corrective Action Unit 417: Central Nevada Test Area Surface, Nevada

    SciTech Connect (OSTI)

    K. Campbell

    2000-04-01

    This Corrective Action Plan provides methods for implementing the approved corrective action alternative as provided in the Corrective Action Decision Document for the Central Nevada Test Area (CNTA), Corrective Action Unit (CAU) 417 (DOE/NV, 1999). The CNTA is located in the Hot Creek Valley in Nye County, Nevada, approximately 137 kilometers (85 miles) northeast of Tonopah, Nevada. The CNTA consists of three separate land withdrawal areas commonly referred to as UC-1, UC-3, and UC-4, all of which are accessible to the public. CAU 417 consists of 34 Corrective Action Sites (CASs). Results of the investigation activities completed in 1998 are presented in Appendix D of the Corrective Action Decision Document (DOE/NV, 1999). According to the results, the only Constituent of Concern at the CNTA is total petroleum hydrocarbons (TPH). Of the 34 CASs, corrective action was proposed for 16 sites in 13 CASs. In fiscal year 1999, a Phase I Work Plan was prepared for the construction of a cover on the UC-4 Mud Pit C to gather information on cover constructibility and to perform site management activities. With Nevada Division of Environmental Protection concurrence, the Phase I field activities began in August 1999. A multi-layered cover using a Geosynthetic Clay Liner as an infiltration barrier was constructed over the UC-4 Mud Pit. Some TPH impacted material was relocated, concrete monuments were installed at nine sites, signs warning of site conditions were posted at seven sites, and subsidence markers were installed on the UC-4 Mud Pit C cover. Results from the field activities indicated that the UC-4 Mud Pit C cover design was constructable and could be used at the UC-1 Central Mud Pit (CMP). However, because of the size of the UC-1 CMP this design would be extremely costly. An alternative cover design, a vegetated cover, is proposed for the UC-1 CMP.

  19. Multiaxial deformation of polyethylene and polyethylene/clay nanocomposites: In situ synchrotron small angle and wide angle X-ray scattering study

    SciTech Connect (OSTI)

    Gurun, Bilge; Bucknall, David G.; Thio, Yonathan S.; Teoh, Chin Ching; Harkin-Jones, Eileen

    2013-01-10

    A unique in situ multiaxial deformation device has been designed and built specifically for simultaneous synchrotron small angle X-ray scattering (SAXS) and wide angle X-ray scattering (WAXS) measurements. SAXS and WAXS patterns of high-density polyethylene (HDPE) and HDPE/clay nanocomposites were measured in real time during in situ multiaxial deformation at room temperature and at 55 C. It was observed that the morphological evolution of polyethylene is affected by the existence of clay platelets as well as the deformation temperature and strain rate. Martensitic transformation of orthorhombic into monoclinic crystal phases was observed under strain in HDPE, which is delayed and hindered in the presence of clay nanoplatelets. From the SAXS measurements, it was observed that the thickness of the interlamellar amorphous region increased with increasing strain, which is due to elongation of the amorphous chains. The increase in amorphous layer thickness is slightly higher for the nanocomposites compared to the neat polymer.

  20. Relationship between crystal structure and thermo-mechanical properties of kaolinite clay: Beyond standard density functional theory

    SciTech Connect (OSTI)

    Weck, Philippe F.; Kim, Eunja; Jove-Colon, Carlos F.

    2015-03-04

    In this study, the structural, mechanical and thermodynamic properties of 1 : 1 layered dioctahedral kaolinite clay, with ideal Al2Si2O5(OH)4 stoichiometry, were investigated using density functional theory corrected for dispersion interactions (DFT-D2). The bulk moduli of 56.2 and 56.0 GPa predicted at 298 K using the Vinet and BirchMurnaghan equations of state, respectively, are in good agreement with the recent experimental value of 59.7 GPa reported for well-crystallized samples. The isobaric heat capacity computed for uniaxial deformation of kaolinite along the stacking direction reproduces calorimetric data within 0.73.0% from room temperature up to its thermal stability limit.

  1. Relationship between crystal structure and thermo-mechanical properties of kaolinite clay: Beyond standard density functional theory

    SciTech Connect (OSTI)

    Weck, Philippe F.; Kim, Eunja; Jove-Colon, Carlos F.

    2015-03-04

    In this study, the structural, mechanical and thermodynamic properties of 1 : 1 layered dioctahedral kaolinite clay, with ideal Al2Si2O5(OH)4 stoichiometry, were investigated using density functional theory corrected for dispersion interactions (DFT-D2). The bulk moduli of 56.2 and 56.0 GPa predicted at 298 K using the Vinet and Birch–Murnaghan equations of state, respectively, are in good agreement with the recent experimental value of 59.7 GPa reported for well-crystallized samples. The isobaric heat capacity computed for uniaxial deformation of kaolinite along the stacking direction reproduces calorimetric data within 0.7–3.0% from room temperature up to its thermal stability limit.

  2. Relationship between crystal structure and thermo-mechanical properties of kaolinite clay: Beyond standard density functional theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Weck, Philippe F.; Kim, Eunja; Jove-Colon, Carlos F.

    2015-03-04

    In this study, the structural, mechanical and thermodynamic properties of 1 : 1 layered dioctahedral kaolinite clay, with ideal Al2Si2O5(OH)4 stoichiometry, were investigated using density functional theory corrected for dispersion interactions (DFT-D2). The bulk moduli of 56.2 and 56.0 GPa predicted at 298 K using the Vinet and Birch–Murnaghan equations of state, respectively, are in good agreement with the recent experimental value of 59.7 GPa reported for well-crystallized samples. The isobaric heat capacity computed for uniaxial deformation of kaolinite along the stacking direction reproduces calorimetric data within 0.7–3.0% from room temperature up to its thermal stability limit.

  3. Origin and diagenesis of clay minerals in relation to sandstone paragenesis: An example in eolian dune reservoirs and associated rocks, Permian upper part of the Minnelusa Formation, Powder River basin, Wyoming

    SciTech Connect (OSTI)

    Pollastro, R.M.; Schenk, C.J. )

    1991-06-01

    Eolian dune sandstones are the principal reservoir rocks in the Permian upper part of the Minnelusa Formation, Powder River basin, Wyoming. These sandstones formed as shorelines retreated and dunes migrated across siliciclastic sabkhas. Sandstones are mainly quartzarenites; on average, clay minerals constitute about 5 wt.% the whole rock. Although present in minor amounts, clay minerals play an important role in the diagenetic evolution of these sandstones. Allogenic clay minerals are present in shaly rock fragments and laminae. Early infiltration of clays into porous sabkha sands commonly form characteristic menisei or bridges between framework grains or, when more extensive, form coatings or rims on grain surfaces. Authigenic clays include nearly pure smectite, mixed-layer illite/smectite (I/S), and late diagenetic illite and corrensite; these clay minerals are present as pore-lining cements. In addition to the deposition and neoformation of clay minerals throughout sandstone paragenesis, the conversion of smectite to illite occurred as temperatures increased with progressive burial. A temperature of 103C is calculated at a present depth of 3,200 m using a geothermal gradient of 30C/km and a mean annual surface temperature of 7C. After correction for uplift and erosion (250 m), the maximum calculated temperature for the conversion of all random I/S to ordered I/S is 100C. This calculated temperature is in excellent agreement with temperatures of 100-110C implied from I/S geothermometry.

  4. Efficiency of clay-TiO2 nanocomposites on the photocatalytic eliminationof a model hydrophobic air pollutant

    SciTech Connect (OSTI)

    Kibanova, Daria; Cervini-Silva, Javiera; Destaillats, Hugo

    2009-01-01

    Clay-supported TiO2 photocatalysts can potentially improve the performance of air treatment technologies via enhanced adsorption and reactivity of target volatile organic compounds (VOCs). In this study, a bench-top photocatalytic flow reactor was used to evaluate the efficiency of hectorite-TiO2 and kaolinite-TiO2, two novel composite materials synthesized in our laboratory. Toluene, a model hydrophobic VOC and a common indoor air pollutant, was introduced in the air stream at realistic concentrations, and reacted under UVA (gamma max = 365 nm) or UVC (gamma max = 254 nm) irradiation. The UVC lamp generated secondary emission at 185 nm, leading to the formation of ozone and other short-lived reactive species. Performance of clay-TiO2 composites was compared with that of pure TiO2 (Degussa P25), and with UV irradiation in the absence of photocatalyst under identical conditions. Films of clay-TiO2 composites and of P25 were prepared by a dip-coating method on the surface of Raschig rings, which were placed inside the flow reactor. An upstream toluene concentration of ~;;170 ppbv was generated by diluting a constant flow of toluene vapor from a diffusion source with dry air, or with humid air at 10, 33 and 66percent relative humidity (RH). Toluene concentrations were determined by collecting Tenax-TA (R) sorbent tubes downstream of the reactor, with subsequent thermal desorption -- GC/MS analysis. The fraction of toluene removed, percentR, and the reaction rate, Tr, were calculated for each experimental condition from the concentration changes measured with and without UV irradiation. Use of UVC light (UV/TiO2/O3) led to overall higher reactivity, which can be partially attributed to the contribution of gas phase reactions by short-lived radical species. When the reaction rate was normalized to the light irradiance, Tr/I gamma, the UV/TiO2 reaction under UVA irradiation was more efficient for samples with a higher content of TiO2 (P25 and Hecto-TiO2), but not for Kao

  5. Thermal and mechanical properties of palm oil-based polyurethane acrylate/clay nanocomposites prepared by in-situ intercalative method and electron beam radiation

    SciTech Connect (OSTI)

    Salih, A. M.; Ahmad, Mansor Bin; Ibrahim, Nor Azowa; Dahlan, Khairul Zaman Hj Mohd; Tajau, Rida; Mahmood, Mohd Hilmi; Yunus, Wan Md. Zin Wan

    2014-02-12

    Palm oil based-polyurethane acrylate (POBUA)/clay nanocomposites were prepared via in-situ intercalative polymerization using epoxidized palm oil acrylate (EPOLA) and 4,4' methylene diphenyl diisocyante (MDI). Organically modified Montmorillonite (ODA-MMT) was incorporated in EPOLA (1, 3 and 5%wt), and then subjected to polycondensation reaction with MDI. Nanocomposites solid films were obtained successfully by electron beam radiation induced free radical polymerization (curing). FTIR results reveal that the prepolymer was obtained successfully, with nanoclay dispersed in the matrix. The intercalation of the clay in the polymer matrix was investigated by XRD and the interlayer spacing of clay was found to be increased up to 37 , while the structure morphology of the nanocomposites was investigated by TEM and SEM. The nanocomposites were found to be a mixture of exfoliated and intercalated morphologies. The thermal stability of the nanocomposites was significantly increased by incorporation of nanoclay into the polymer matrix. DSC results reveal that the Tg was shifted to higher values, gradually with increasing the amount of filler in the nanocomposites. Tensile strength and Young's modulus of the nanocomposites showed remarkable improvement compared to the neat POBUA.

  6. {sup 31}P NMR study of the complexation of TBP with lanthanides and actinides in solution and in a clay matrix

    SciTech Connect (OSTI)

    Hartzell, C.J.

    1994-07-24

    Goal was to use NMR to study TBP/lanthanide complexes in the interlayer or on edge sites of clays. Work in this laboratory yielded details of the complexation of Eu(NO{sub 3}){sub 3} and Pr(NO{sub 3}){sub 3} with TBP in hexane solution; this information is crucial to interpretation of results of NMR studies of the complexes exchanged into clays. The solution {sup 31}P-chemical shift values were improved by repeating the studies on the lanthanide salts dissolved directly into neat TBP. NMR studies of these neat solutions of the Eu(NO{sub 3}){sub 3}{lg_bullet}3TBP-complex and the Pr(NO{sub 3}){sub 3}{lg_bullet}3TBP-complex show that the {sup 31}P chemical shift remains relatively constant for TBP: lanthanide ratios below 3: 1. At higher ratios, the chemical shift approaches that of free TBP, indicating rapid exchange of TBP between the free and complexed state. Exchange of these complexes into the clay hectorite yielded discrete {sup 31}P-NMR signals for the Eu{lg_bullet}TBP complex at -190 ppm and free TBP at -6 ppm. Adsorption of the Pr{lg_bullet}TBP complex yielded broad signals at 76 ppm for the complex and -6 ppm for free TBP. There was no evidence of exchange between the incorporated complex and the free TBP.

  7. The effect of clay catalyst on the chemical composition of bio-oil obtained by co-pyrolysis of cellulose and polyethylene

    SciTech Connect (OSTI)

    Solak, Agnieszka; Rutkowski, Piotr

    2014-02-15

    Highlights: • Non-catalytic and catalytic fast pyrolysis of cellulose/polyethylene blend was carried out in a laboratory scale reactor. • Optimization of process temperature was done. • Optimization of clay catalyst type and amount for co-pyrolysis of cellulose and polyethylene was done. • The product yields and the chemical composition of bio-oil was investigated. - Abstract: Cellulose/polyethylene (CPE) mixture 3:1, w/w with and without three clay catalysts (K10 – montmorillonite K10, KSF – montmorillonite KSF, B – Bentonite) addition were subjected to pyrolysis at temperatures 400, 450 and 500 °C with heating rate of 100 °C/s to produce bio-oil with high yield. The pyrolytic oil yield was in the range of 41.3–79.5 wt% depending on the temperature, the type and the amount of catalyst. The non-catalytic fast pyrolysis at 500 °C gives the highest yield of bio-oil (79.5 wt%). The higher temperature of catalytic pyrolysis of cellulose/polyethylene mixture the higher yield of bio-oil is. Contrarily, increasing amount of montmorillonite results in significant, almost linear decrease in bio-oil yield followed by a significant increase of gas yield. The addition of clay catalysts to CPE mixture has a various influence on the distribution of bio-oil components. The addition of montmorillonite K10 to cellulose/polyethylene mixture promotes the deepest conversion of polyethylene and cellulose. Additionally, more saturated than unsaturated hydrocarbons are present in resultant bio-oils. The proportion of liquid hydrocarbons is the highest when a montmorillonite K10 is acting as a catalyst.

  8. Organic liner for thermoset composite tank

    DOE Patents [OSTI]

    Garvey, Raymond E.

    1991-01-01

    A cryogenic tank that is made leak-proof under cryogenic conditions by successive layers of epoxy lining the interior of the tank.

  9. Heat dissipating nuclear reactor with metal liner

    DOE Patents [OSTI]

    Gluekler, Emil L.; Hunsbedt, Anstein; Lazarus, Jonathan D.

    1987-01-01

    Disclosed is a nuclear reactor containment including a reactor vessel disposed within a cavity with capability for complete inherent decay heat removal in the earth and surrounded by a cast steel containment member which surrounds the vessel. The member has a thick basemat in contact with metal pilings. The basemat rests on a bed of porous particulate material, into which water is fed to produce steam which is vented to the atmosphere. There is a gap between the reactor vessel and the steel containment member. The containment member holds any sodium or core debris escaping from the reactor vessel if the core melts and breaches the vessel.

  10. Heat dissipating nuclear reactor with metal liner

    DOE Patents [OSTI]

    Gluekler, E.L.; Hunsbedt, A.; Lazarus, J.D.

    1985-11-21

    A nuclear reactor containment including a reactor vessel disposed within a cavity with capability for complete inherent decay heat removal in the earth and surrounded by a cast steel containment member which surrounds the vessel is described in this disclosure. The member has a thick basemat in contact with metal pilings. The basemat rests on a bed of porous particulate material, into which water is fed to produce steam which is vented to the atmosphere. There is a gap between the reactor vessel and the steel containment member. The containment member holds any sodium or core debris escaping from the reactor vessel if the core melts and breaches the vessel.

  11. Demonstration of thermonuclear conditions in magnetized liner...

    Office of Scientific and Technical Information (OSTI)

    ... A. 1 ; Cooper, Gary Wayne 1 ; Cuneo, Michael Edward 1 ; Harvey-Thompson, Adam James ... Ryan D. 1 ; Peterson, Kyle J. 1 ; Porter, John L. 1 ; Rochau, Gregory A. 1 ; ...

  12. Demonstration of thermonuclear conditions in magnetized liner...

    Office of Scientific and Technical Information (OSTI)

    A. 1 ; Cooper, Gary Wayne 1 ; Cuneo, Michael Edward 1 ; Harvey-Thompson, Adam James ... Ryan D. 1 ; Peterson, Kyle J. 1 ; Porter, John L. 1 ; Rochau, Gregory A. 1 ; ...

  13. Geomembrane barriers using integral fiber optics to monitor barrier integrity

    DOE Patents [OSTI]

    Staller, G.E.; Wemple, R.P.

    1996-10-22

    This invention provides a geomembrane or geotextile with embedded optical sensors that are used to monitor the status of containment site barriers. Fiber optic strands are used to form the sensors that can detect and monitor conditions at the sites such as breaches, slope creep, subsidence, leachate levels, fires, and types of materials present or leaking from the site. The strands are integral to the membrane or textile materials. The geosynthetic membrane is deployed at the site in a fashion similar to carpet laying. Edges of the membrane or textile are joined to form a liner and the ends of the membrane or textile become the connection zones for obtaining signals from the sensors. A connection interface with a control system to generate Optical Time Delay Response or other light signals for transmission to the optic fiber strands or sensors and also to receive reflected signals from the sensors is included in the system. Software to interpret the sensor signals can be used in the geosynthetic monitoring system. 6 figs.

  14. PNNL STC Workshop Getter/Liner Tube Properties and Manufacturing...

    Office of Environmental Management (EM)

    Secondary Tracking of Tritium 4 He in Pellets - by Tritium Assay Method 3 He in ... X-ray Photoelectron Spectroscopy pellets Secondary Ion Mass Spectrometry All ...

  15. High efficiency proportional neutron detector with solid liner internal structures

    DOE Patents [OSTI]

    Kisner, Roger Allen; Holcomb, David Eugene; Brown, Gilbert M.

    2014-08-05

    A tube-style neutron detector, a panel-style neutron detector incorporating a plurality of tube-style neutron detectors, and a panel-style neutron detector including a plurality of anode wires are provided. A plurality of channels is provided in a neutron detector such that each channel has an inner surface of a coating layer including a neutron-absorbing material. A wire anode is provided at end of each channel so that electrons generated by a charged daughter particle generated by a neutron are collected to detect a neutron-matter interaction. Moderator units can be incorporated into a neutron detector to provide improved detection efficiencies and/or to determine neutron energy spectrum. Gas-based proportional response from the neutron detectors can be employed for special nuclear material (SNM) detection. This neutron detector can provide similar performance to .sup.3He-based detectors without requiring .sup.3He and without containing toxic, flammable, or high-pressure materials.

  16. Liners and Covers: Field Performance & Life Expectancy | Department...

    Office of Environmental Management (EM)

    Meeting 11-12 December 2014 Las Vegas, Nevada, USA To view all the P&RA CoP 2014 ... an Alternative Landfill Cover at the Monticello, Utah, Uranium Mill Tailings Disposal Site

  17. Exploring magnetized liner inertial fusion with a semi-analytic...

    Office of Scientific and Technical Information (OSTI)

    ; Peterson, Kyle J. 1 ; Rochau, Gregory A. 1 ; Porter, John L. 1 more ; Stygar, William A. 1 ; Campbell, Edward Michael 2 ; Nakhleh, Charles W. 3 ; Herrmann, Mark C. ...

  18. Diagnosing magnetized liner inertial fusion experiments on Z...

    Office of Scientific and Technical Information (OSTI)

    Wayne 1 ; Cuneo, Michael Edward 1 ; Herrmann, Mark C. 2 more ; Mark Harry Hess ; Johns, Owen 1 ; Lamppa, Derek C. 1 ; Martin, Matthew 1 ; Porter, J. L. 1 ; ...

  19. Nonlinear Laser-Plasma Interaction in Magnetized Liner Inertial...

    Office of Scientific and Technical Information (OSTI)

    ; Bliss, David E. 1 ; Campbell, Edward Michael 2 ; Gomez, Matthew R. 1 ; Harding, ... Christopher 1 ; Vesey, Roger A. 1 ; Porter, John L. 1 less + Show Author ...

  20. Carbon Emissions: Stone, Clay, and Glass Industry

    U.S. Energy Information Administration (EIA) Indexed Site

    Contact: Stephanie Battles Stephanie.Battles@eia.doe.gov (Phone: (202) 586-7237) FAX: 202-586-0018 Contact Us URL: http:www.eia.govemeuefficiencycarbonemissionsstone...

  1. Material characterization of the clay bonded silicon carbide candle filters and ash formations in the W-APF system after 500 hours of hot gas filtration at AEP. Appendix to Advanced Particle Filter: Technical progress report No. 11, January--March 1993

    SciTech Connect (OSTI)

    Alvin, M.A.

    1993-04-05

    (1) After 500 hours of operation in the pressurized fluidized-bed combustion gas environment, the fibrous outer membrane along the clay bonded silicon carbide Schumacher Dia Schumalith candles remained intact. The fibrous outer membrane did not permit penetration of fines through the filter wall. (2) An approximate 10-15% loss of material strength occurred within the intact candle clay bonded silicon carbide matrix after 500 hours of exposure to the PFBC gas environment. A relatively uniform strength change resulted within the intact candles throughout the vessel (i.e., top to bottom plenums), as well as within the various cluster ring positions (i.e., outer versus inner ring candle filters). A somewhat higher loss of material strength, i.e., 25% was detected in fractured candle segments removed from the W-APF ash hopper. (3) Sulfur which is present in the pressurized fluidized-bed combustion gas system induced phase changes along the surface of the binder which coats the silicon carbide grains in the Schumacher Dia Schumalith candle filter matrix.

  2. Effectiveness of interim remedial actions at a radioactive waste facility

    SciTech Connect (OSTI)

    Devgun, J.S.; Beskid, N.J.; Peterson, J.M.; Seay, W.M.; McNamee, E.; USDOE Oak Ridge Operations Office, TN; Bechtel National, Inc., Oak Ridge, TN )

    1989-01-01

    Over the past eight years, several interim remedial actions have been taken at the Niagara Falls Storage Site (NFSS), primarily to reduce radon and gamma radiation exposures and to consolidate radioactive waste into a waste containment facility. Interim remedial actions have included capping of vents, sealing of pipes, relocation of the perimeter fence (to limit radon risk), transfer and consolidation of waste, upgrading of storage buildings, construction of a clay cutoff wall (to limit the potential groundwater transport of contaminants), treatment and release of contaminated water, interim use of a synthetic liner, and emplacement of an interim clay cap. An interim waste containment facility was completed in 1986. 6 refs., 3 figs.

  3. Magnetic design calculation and FRC formation modeling for the field reversed experiment liner

    SciTech Connect (OSTI)

    Dorf, L. A.; Intrator, T. P.; Renneke, R.; Hsu, S. C.; Wurden, G. A.; Awe, T.; Siemon, R.; Semenov, V. E.

    2008-10-01

    Integrated magnetic modeling and design are important to meet the requirements for (1) formation, (2) translation, and (3) compression of a field reversed configuration (FRC) for magnetized target fusion. Off-the-shelf solutions do not exist for many generic design issues. A predictive capability for time-dependent magnetic diffusion in realistically complicated geometry is essential in designing the experiment. An eddy-current code was developed and used to compute the mutual inductances between driven magnetic coils and passive magnetic shields (flux excluder plates) to calculate the self-consistent axisymmetric magnetic fields during the first two stages. The plasma in the formation stage was modeled as an immobile solid cylinder with selectable constant resistivity and magnetic flux that was free to readjust itself. It was concluded that (1) use of experimentally obtained anomalously large plasma resistivity in magnetic diffusion simulations is sufficient to predict magnetic reconnection and FRC formation, (2) comparison of predicted and experimentally observed timescales for FRC Ohmic decay shows good agreement, and (3) for the typical range of resistivities, the magnetic null radius decay rate scales linearly with resistivity. The last result can be used to predict the rate of change in magnetic flux outside of the separatrix (equal to the back-emf loop voltage), and thus estimate a minimum {theta}-coil loop voltage required to form an FRC.

  4. Possible energy gain for a plasma-liner-driven magneto-inertial fusion concept

    SciTech Connect (OSTI)

    Knapp, C. E.; Kirkpatrick, R. C.

    2014-07-15

    A one-dimensional parameter study of a Magneto-Inertial Fusion (MIF) concept indicates that significant gain may be achievable. This concept uses a dynamically formed plasma shell with inwardly directed momentum to drive a magnetized fuel to ignition, which in turn partially burns an intermediate layer of unmagnetized fuel. The concept is referred to as Plasma Jet MIF or PJMIF. The results of an adaptive mesh refinement Eulerian code (Crestone) are compared to those of a Lagrangian code (LASNEX). These are the first published results using the Crestone and LASNEX codes on the PJMIF concept.

  5. POST CLOSURE INSPECTION AND MONITORING REPORT FOR CORRECTIVE ACTION UNIT 417: CENTRAL NEVADA TEST AREA - SURFACE, HOT CREEK VALLEY, NEVADA; FOR CALENDAR YEAR 2005

    SciTech Connect (OSTI)

    2006-04-01

    bentonite during the first quarter of 2006 and monitored during subsequent inspections. The cover vegetation was healthy and well established. No issues were identified with the CMP fence, gate, or subsidence monuments. No issues were identified with the warning signs and monuments at the other two UC-1 locations. The inspections at UC-3 indicated that the sites are in excellent condition. All monuments and signs showed no displacement, damage, or removal. A small erosion gully from spring rain runoff was observed during the June inspection, but it did not grow to an actionable level during 2005. No other issues or concerns were identified. Inspections performed at UC-4 Mud Pit C cover revealed that erosion rills were formed during March and September exposing the geosynthetic clay liner. Both erosion rills were repaired within 90 days of reporting. Sparse vegetation is present on the cover. The overall condition of the monuments, fence, and gate are in good condition. No issues were identified with the warning signs and monuments at the other four UC-4 locations. Subsidence surveys were conducted at UC-1 CMP and UC-4 Mud Pit C in March and September of 2005. The results of the subsidence surveys indicate that the covers are performing as expected, and no unusual subsidence was observed. The June vegetation survey of the UC-1 CMP cover and adjacent areas indicated that the revegetation has been very successful. The vegetation should continue to be monitored to document any changes in the plant community and identify conditions that could potentially require remedial action in order to maintain a viable vegetative cover on the site. Vegetation surveys should be conducted only as required. Precipitation during 2005 was above average, with an annual rainfall total of 21.79 centimeters (8.58 inches). Soil moisture content data show that the UC-1 CMP cover is performing as designed, with evapotranspiration effectively removing water from the cover. It is recommended to continue

  6. Deputy Secretary of Energy Clay Sell to Depart | Department of...

    Energy Savers [EERE]

    WASHINGTON, DC - U.S. Secretary of Energy Samuel W. Bodman today released the following ... Sell previously worked at the White House as a Special Assistant to President George W. ...

  7. Evaluation Of Used Fuel Disposition In Clay-Bearing Rock

    Office of Energy Efficiency and Renewable Energy (EERE)

    Radioactive waste disposal in shale/argillite rock formations has been widely considered given its desirable isolation properties, e.g., low permeability, potential geochemically reduced conditions...

  8. Use of Reinforced Lightweight Clay Aggregates for Landslide Stabilisation

    SciTech Connect (OSTI)

    Herle, Vitezslav

    2008-07-08

    In spring 2006 a large landslide combined with rock fall closed a highway tunnel near Svitavy in NE part of Czech Republic and cut the main highway connecting Bohemia with Moravia regions. Stabilisation work was complicated by steep mountainous terrain and large inflow of surface and underground water. The solution was based on formation of a stabilisation fill made of reinforced free draining aggregates at the toe of the slope with overlying lightweight fill up to 10 m high reinforced with PET geogrid and steel mesh protecting soft easily degrading sandstone against weathering. Extensive monitoring made possible to compare the FEM analysis with real values. The finished work fits very well in the environment and was awarded a special prize in the 2007 transport structures contest.

  9. Modeling Coupled Processes in Clay Formations for Radioactive...

    Office of Scientific and Technical Information (OSTI)

    ... To understand and model the coupled processes and their impact on repository performance ... of Nuclear Energy, LBNL's research activities have focused on understanding and ...

  10. Diagenesis and clay mineral formation at Gale Crater, Mars

    Office of Scientific and Technical Information (OSTI)

    dilute aqueous solution (Gale Portage Water) in an open system with the Fe-rich basaltic-composition sedimentary rocks at 10-50C and waterrock ratio (mass of rock reacted with ...

  11. Tensile strengths of problem shales and clays. Master's thesis

    SciTech Connect (OSTI)

    Rechner, F.J.

    1990-01-01

    The greatest single expense faced by oil companies involved in the exploration for crude oil is that of drilling wells. The most abundant rock drilled is shale. Some of these shales cause wellbore stability problems during the drilling process. These can range from slow rate of penetration and high torque up to stuck pipe and hole abandonment. The mechanical integrity of the shale must be known when the shalers are subjected to drilling fluids to develop an effective drilling plan.

  12. Clay County, Kentucky: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Kentucky: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 37.1738044, -83.7199136 Show Map Loading map... "minzoom":false,"mappingservice":"goo...

  13. Clay County, Arkansas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Arkansas: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 36.3492244, -90.3748354 Show Map Loading map... "minzoom":false,"mappingservice":"goo...

  14. Clay County, Indiana: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Indiana: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 39.368622, -87.1422895 Show Map Loading map... "minzoom":false,"mappingservice":"googl...

  15. Clay County, North Carolina: Energy Resources | Open Energy Informatio...

    Open Energy Info (EERE)

    North Carolina: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 35.0964003, -83.7199136 Show Map Loading map... "minzoom":false,"mappingservice...

  16. Clay County, Tennessee: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Tennessee: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 36.5701766, -85.56121 Show Map Loading map... "minzoom":false,"mappingservice":"goog...

  17. Clay County, South Dakota: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    South Dakota: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 42.8829344, -97.0068393 Show Map Loading map... "minzoom":false,"mappingservice":...

  18. Clay County, Kansas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Kansas: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 39.34792, -97.179026 Show Map Loading map... "minzoom":false,"mappingservice":"googlema...

  19. Clay County, West Virginia: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    West Virginia: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 38.4417717, -81.1196075 Show Map Loading map... "minzoom":false,"mappingservice"...

  20. Clay County, Alabama: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Alabama: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 33.279527, -85.8486236 Show Map Loading map... "minzoom":false,"mappingservice":"googl...

  1. Clay Center, Ohio: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Ohio: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 41.5633831, -83.3618725 Show Map Loading map... "minzoom":false,"mappingservice":"googlem...

  2. Clay County, Iowa: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Iowa: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 43.1368038, -95.1432068 Show Map Loading map... "minzoom":false,"mappingservice":"googlem...

  3. Clay County, Texas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Texas: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 33.7900416, -98.2212979 Show Map Loading map... "minzoom":false,"mappingservice":"google...

  4. Clay Minerals Related To The Hydrothermal Activity Of The Bouillante...

    Open Energy Info (EERE)

    Minerals Related To The Hydrothermal Activity Of The Bouillante Geothermal Field (Guadeloupe) Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  5. Clay County, Nebraska: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Nebraska: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 40.5975479, -98.0465185 Show Map Loading map... "minzoom":false,"mappingservice":"goo...

  6. Clay County, Illinois: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Illinois: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 38.7279431, -88.556531 Show Map Loading map... "minzoom":false,"mappingservice":"goog...

  7. Clay County, Minnesota: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Minnesota: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 46.878186, -96.4257589 Show Map Loading map... "minzoom":false,"mappingservice":"goo...

  8. Clay County, Georgia: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Georgia: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 31.6447931, -85.0025539 Show Map Loading map... "minzoom":false,"mappingservice":"goog...

  9. Clay County, Mississippi: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Mississippi: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 33.6567838, -88.8263006 Show Map Loading map... "minzoom":false,"mappingservice":"...

  10. Diagenesis and clay mineral formation at Gale Crater, Mars (Journal...

    Office of Scientific and Technical Information (OSTI)

    On the basis of the observed host rock and alteration minerals, we present results of equilibrium thermochemical modeling of the Sheepbed mudstones of Yellowknife Bay in order to ...

  11. Definitive design report: Design report project W-025, Radioactive Mixed Waste (RMW) Land Disposal Facility NON-DRAG-OFF. Revision 1, Volume 1 and 2

    SciTech Connect (OSTI)

    Roscha, V.

    1994-11-29

    The purpose of this report is to describe the definitive design of the Radioactive Mixed Waste (RMW) Non-Drag-Off disposal facility, Project W-025. This report presents a n of the major landfill design features and a discussion of how each of the criteria is addressed in the design. The appendices include laboratory test results, design drawings, and individual analyses that were conducted in support of the design. Revision 1 of this document incorporates design changes resulting from an increase in the required operating life of the W-025 landfill from 2 to 20 years. The rationale for these design changes is described in Golder Associates Inc. 1991a. These changes include (1) adding a 1.5-foot-thick layer of compacted admix directory-under the primary FML on the floor of the landfill to mitigate the effects of possible stress cracking in the primary flexible membrane liner (FML), and (2) increasing the operations layer thickness from two to three feet over the entire landfill area, to provide additional protection for the secondary admix layer against mechanical damage and the effects of freezing and desiccation. The design of the W-025 Landfill has also been modified in response to the results of the EPA Method 9090 chemical compatibility testing program (Golder Associates Inc. 1991b and 1991c), which was completed after the original design was prepared. This program consisted of testing geosynthetic materials and soil/bentonite admix with synthetic leachate having the composition expected during the life of the W-025 Landfill., The results of this program indicated that the polyester geotextile originally specified for the landfill might be susceptible to deterioration. On this basis, polypropylene geotextiles were substituted as a more chemically-resistant alternative. In addition, the percentage of bentonite in the admix was increased to provide sufficiently low permeability to the expected leachate.

  12. Compression of a spherically symmetric deuterium-tritium plasma liner onto a magnetized deuterium-tritium target

    SciTech Connect (OSTI)

    Santarius, J. F.

    2012-07-15

    Converging plasma jets may be able to reach the regime of high energy density plasmas (HEDP). The successful application of plasma jets to magneto-inertial fusion (MIF) would heat the plasma by fusion products and should increase the plasma energy density. This paper reports the results of using the University of Wisconsin's 1-D Lagrangian, radiation-hydrodynamics, fusion code BUCKY to investigate two MIF converging plasma jet test cases originally analyzed by Samulyak et al.[Physics of Plasmas 17, 092702 (2010)]. In these cases, 15 cm or 5 cm radially thick deuterium-tritium (DT) plasma jets merge at 60 cm from the origin and converge radially onto a DT target magnetized to 2 T and of radius 5 cm. The BUCKY calculations reported here model these cases, starting from the time of initial contact of the jets and target. Compared to the one-temperature Samulyak et al. calculations, the one-temperature BUCKY results show similar behavior, except that the plasma radius remains about twice as long near maximum compression. One-temperature and two-temperature BUCKY results differ, reflecting the sensitivity of the calculations to timing and plasma parameter details, with the two-temperature case giving a more sustained compression.

  13. Development of NZP ceramic based {open_quotes}cast-in-place{close_quotes} diesel engine port liners

    SciTech Connect (OSTI)

    Nagaswaran, R.; Limaye, S.Y.

    1996-02-01

    BSX (Ba{sub 1+x}Zr{sub 4}P{sub 6-2x}Si{sub 2x}O{sub 24}) and CSX (Ca{sub l-x}Sr{sub x}Zr{sub 4}P{sub 6}O{sub 24}) type NZP ceramics were fabricated and characterized for: (i) thermal properties viz., thermal conductivity, thermal expansion, thermal stability and thermal shock resistance; (ii) mechanical properties viz., flexure strength and elastic modulus; and (iii) microstructures. Results of these tests and analysis indicated that the BS-25 (x=0.25 in BSX) and CS-50 (x=0.50 in CSX) ceramics had the most desirable properties for casting metal with ceramic in place. Finite element analysis (FEA) of metal casting (with ceramic in place) was conducted to analyze thermomechanical stresses generated and determine material property requirements. Actual metal casting trials were also conducted to verify the results of finite element analysis. In initial trials, the ceramic cracked because of the large thermal expansion mismatch (hoop) stresses (predicted by FEA also). A process for introduction of a compliant layer between the metal and ceramic to alleviate such destructive stresses was developed. The compliant layer was successful in preventing cracking of either the ceramic or the metal. In addition to these achievements, pressure slip casting and gel-casting processes for fabrication of NZP components; and acoustic emission and ultrasonics-based NDE techniques for detection of microcracks and internal flaws, respectively, were successfully developed.

  14. Small Business Awarded Contract for Recovery Act Work at DOE Waste Facility

    Broader source: Energy.gov [DOE]

    Louisiana small business to provide geosynthetic materials and installation services for expansion of the Department of Energy’s Environmental Management Waste Management Facility (EMWMF) on the Oak Ridge Reservation.

  15. Improved Lining Material for Gasifiers Could Lead to WiderCommerciali...

    Broader source: Energy.gov (indexed) [DOE]

    ... in field trials versus conventional liner materials) by reducing slag penetration and structural spalling at the refractory hot face, one of the primary causes of liner failure. ...

  16. Sandia Energy - Fusion Instabilities Lessened by Unexpected Effect

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    dramatically in mere nanoseconds, eating through the liner wall like decay through a tooth. Eventually, they may collapse portions of the inner wall of the liner, releasing...

  17. Sandia National Laboratories: News: Publications: Lab News

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a liner aimed at helping prosthetic limbs fit better. Sandia's Intelligent Systems, Robotics, and Cybernetics group is developing a liner with sensors that tell what's going on...

  18. Microsoft PowerPoint - 4B Mark Phifer

    Office of Environmental Management (EM)

    - Consideration of Liners and Covers in Performance Assessments SRNL-STI-2014-00409 - Approaches to Consider Covers and Liners in a Low-Level Waste Disposal Facility...

  19. Strong-Sludge Gas Retention and Release Mechanisms in Clay Simulants

    SciTech Connect (OSTI)

    Gauglitz, Phillip A.; Buchmiller, William C.; Probert, Samuel G.; Owen, Antionette T.; Brockman, Fred J.

    2012-02-24

    The Hanford Site has 28 double-shell tanks (DSTs) and 149 single-shell tanks (SSTs) containing radioactive wastes that are complex mixes of radioactive and chemical products. The mission of the Department of Energy's River Protection Project is to retrieve and treat the Hanford tank waste for disposal and close the tank farms. A key aspect of the mission is to retrieve and transfer waste from the SSTs, which are at greater risk for leaking, into DSTs for interim storage until the waste is transferred to and treated in the Waste Treatment and Immobilization Plant. There is, however, limited space in the existing DSTs to accept waste transfers from the SSTs, and approaches to overcoming the limited DST space will benefit the overall mission. The purpose of this study is to summarize and analyze the key previous experiment that forms the basis for the relaxed controls and to summarize progress and results on new experiments focused on understanding the conditions that result in low gas retention. The previous large-scale test used about 50 m3 of sediment, which would be unwieldy for doing multiple parametric experiments. Accordingly, experiments began with smaller-scale tests to determine whether the desired mechanisms can be studied without the difficulty of conducting very large experiments. The most significant results from the current experiments are that progressively lower gas retention occurs in tests with progressively deeper sediment layers and that the method of gas generation also affects the maximum retention. Based on the results of this study, it is plausible that relatively low gas retention could occur in sufficiently deep tank waste in DSTs. The current studies and previous work, however, have not explored how gas retention and release will behave when two or more layers with different properties are present.

  20. Permeameter studies of water flow through cement and clay borehole seals in granite, basalt and tuff

    SciTech Connect (OSTI)

    South, D.L.; Daemen, J.J.K.

    1986-10-01

    Boreholes near a repository must be sealed to prevent rapid migration of radionuclide-contaminated water to the accessible environment. The objective of this research is to assess the performance of borehole seals under laboratory conditions, particularly with regard to varying stress fields. Flow through a sealed borehole is compared with flow through intact rock. Cement or bentonite seals have been tested in granite, basalt, and welded tuff. The main conclusion is that under laboratory conditions, existing commercial materials can form high quality seals. Triaxial stress changes about a borehole do not significantly affect seal performance if the rock is stiffer than the seal. Temperature but especially moisture variations (drying) significantly degrade the quality of cement seals. Performance partially recovers upon resaturation. A skillfully sealed borehole may be as impermeable as the host rock. Analysis of the influence of relative seal-rock permeabilities shows that a plug with permeability one order of magnitude greater than that of the rock results in a flow increase through the hole and surrounding rock of only 1-1/2 times compared to the undisturbed rock. Since a borehole is only a small part of the total rock mass, the total effect is even less pronounced. The simplest and most effective way to decrease flow through a rock-seal system is to increase the seal length, assuming it can be guaranteed that no dominant by-pass flowpath through the rock exists.

  1. Predicting Porosity in Clean and Clay-Ricj Sediments Using Resistivity...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Office of Environmental Management (EM) (US) Country of Publication: United States Language: English Subject: 54 ENVIRONMENTAL SCIENCES; 58 GEOSCIENCES; ...

  2. Clay enhancement of methane, low molecular weight hydrocarbon and halocarbon conversion by methanotrophic bacteria

    DOE Patents [OSTI]

    Apel, William A.; Dugan, Patrick R.

    1995-01-01

    An apparatus and method for increasing the rate of oxidation of toxic vapors by methanotrophic bacteria. The toxic vapors of interest are methane and trichloroethylene. The apparatus includes a gas phase bioreactor within a closed loop pumping system or a single pass system. The methanotrophic bacteria include Methylomonas methanica, Methylosinus trichosporium, and uncharacterized environmental enrichments.

  3. K-Ar Dates Of Hydrothermal Clays From Core Hole Vc-2B, Valles...

    Open Energy Info (EERE)

    (765 m) gives an age of 6.74 Ma. Two dates on illite from sandstones in Permian red beds (1008 and 1187 m) are 4.33 and 4.07 Ma, respectively. Surprisingly, three dates on...

  4. Clay enhancement of methane, low molecular weight hydrocarbon and halocarbon conversion by methanotrophic bacteria

    DOE Patents [OSTI]

    Apel, William A.; Dugan, Patrick R.

    1995-04-04

    An apparatus and method for increasing the rate of oxidation of toxic vapors by methanotrophic bacteria. The toxic vapors of interest are methane and trichloroethylene. The apparatus includes a gas phase bioreactor within a closed loop pumping system or a single pass system. The methanotrophic bacteria include Methylomonas methanica, Methylosinus trichosporium, and uncharacterized environmental enrichments.

  5. GLADY CASSIT Y VANDALIA MURPHY CR EEK BU CKHN-CENT URY CLAY

    U.S. Energy Information Administration (EIA) Indexed Site

    WAYN ESBUR G PR UNT Y GLENVILLE S CAVE RUN TAYLOR DRAIN ROSEDALE ST MPT-N RMNT-SHK ... Authors: Sam Limerick (1), Lucy Luo (1), Gary Long (2), David Morehouse (2), Jack Perrin ...

  6. Statement by Deputy Secretary of Energy Clay Sell on NRG’s License Application

    Broader source: Energy.gov [DOE]

    "Today marks the most significant and tangible step to date, towards the construction of the first new nuclear power plant in the United States in over 30 years.

  7. Cost savings associated with landfilling wastes containing very low levels of uranium

    SciTech Connect (OSTI)

    Boggs, C.J.; Shaddoan, W.T.

    1996-03-01

    The Paducah Gaseous Diffusion Plant (PGDP) has operated captive landfills (both residential and construction/demolition debris) in accordance with the Commonwealth of Kentucky regulations since the early 1980s. Typical waste streams allowed in these landfills include nonhazardous industrial and municipal solid waste (such as paper, plastic, cardboard, cafeteria waste, clothing, wood, asbestos, fly ash, metals, and construction debris). In July 1992, the U.S. Environmental Protection Agency issued new requirements for the disposal of sanitary wastes in a {open_quotes}contained landfill.{close_quotes} These requirements were promulgated in the 401 Kentucky Administrative Record Chapters 47 and 48 that became effective 30 June 1995. The requirements for a new contained landfill include a synthetic liner made of high-density polyethylene in addition to the traditional 1-meter (3-foot) clay liner and a leachate collection system. A new landfill at Paducah would accept waste streams similar to those that have been accepted in the past. The permit for the previously existing landfills did not include radioactivity limits; instead, these levels were administratively controlled. Typically, if radioactivity was detected above background levels, the waste was classified as low-level waste (LLW), which would be sent off-site for disposal.

  8. Deep patch technique for landslide repair. Final report

    SciTech Connect (OSTI)

    Helwany, B.M.

    1994-10-01

    The report describes the laboratory testing of the `USFS deep patch` technique and a CTI modification of this technique for repairing landslides with geosynthetic reinforcement. The technique involves replacing sections of roadway lost due to landslides on top of a geosynthetically-reinforced embankment. The CTI modification involves replacing the reinforced slope with a geosynthetically-reinforced retaining wall with a truncated base. Both techniques rely on the cantilevering ability of the reinforced mass to limit the load on the foundation with a high slide potential. The tests with road base showed that (1) both the USFS and CTI repair reduced effectively the adverse effects of local landsliding on the highway pavement by preventing crack propagation; (2) the USFS repair increased the stability of the repaired slope, which was in progressive failure, by reducing the stresses exerted on it; and (3) the CTI repair produced substantially greater stresses on its foundation due to the truncated base of the reinforced mass.

  9. International Collaborations on Engineered Barrier Systems: Experiment...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and clay barrier performance; 2) EBS Experiment -thermo-hydro-mechanical-chemical ... DR-A (diffusion and retention) borehole experiment in Opalinus Clay, and cement-clay ...

  10. Sandia Energy - Study Could Help Improve Nuclear Waste Repositories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    underground clay formations for nuclear waste disposal, because clay offers low permeability and high radionuclide retention. Even when a repository isn't sited in clay,...

  11. Lined sampling vessel including a filter to separate solids from liquids on exit

    DOE Patents [OSTI]

    Shurtliff, Rodney M.; Klingler, Kerry M.; Turner, Terry D.

    2001-01-01

    A filtering apparatus has an open canister with an inlet port. A canister lid is provided which includes an outlet port for the passage of fluids from the canister. Liners are also provided which are shaped to fit the interiors of the canister and the lid, with at least the canister liner preferably being flexible. The sample to be filtered is positioned inside the canister liner, with the lid and lid liner being put in place thereafter. A filter element is located between the sample and the outlet port. Seals are formed between the canister liner and lid liner, and around the outlet port to prevent fluid leakage. A pressure differential is created between the canister and the canister liner so that the fluid in the sample is ejected from the outlet port and the canister liner collapses around the retained solids.

  12. Commercial Light Water Production of Tritium Update and Path...

    Office of Environmental Management (EM)

    ... SOLID BOTTOM END PLUG LOWER CRUCIFORM SPACER A B CROSS SECTION Nom 1" PELLETS A A INNER LINER PELLET STACKS with - Nominal 1" Pellets - Inner Liner Nom 1" PELLETS UPPER CRUCIFORM ...

  13. Stockpile Stewardship Q

    National Nuclear Security Administration (NNSA)

    ... concepts exist, all must bring the fusion fuel to an extreme high-energy-density state. ... liners imploded on the Z Facility. Green and red dashed lines indicate the liner's ...

  14. An Improved Method of Manufacturing Corrugated Boxes: Lateral...

    Office of Scientific and Technical Information (OSTI)

    and crush resistance (per unit of fiber weight) than the conventional box construction. ... AND UTILIZATION; COMMERCIALIZATION; CONSTRUCTION; FIBERS; FLEXIBILITY; LINERS; ...

  15. High pressure storage vessel

    DOE Patents [OSTI]

    Liu, Qiang

    2013-08-27

    Disclosed herein is a composite pressure vessel with a liner having a polar boss and a blind boss a shell is formed around the liner via one or more filament wrappings continuously disposed around at least a substantial portion of the liner assembly combined the liner and filament wrapping have a support profile. To reduce susceptible to rupture a locally disposed filament fiber is added.

  16. Perforating devices for use in wells

    DOE Patents [OSTI]

    Jacoby, Jerome J.; Brooks, James E.; Aseltine, Clifford L.

    2002-01-01

    The perforating device for use in completing a well includes a case, an explosive charge contained in the case, and a generally bowl-shaped liner. The liner is positioned adjacent the explosive charge and has non-uniforrn thickness along its length. The liner further includes a protruding portion near its tip. In another configuration, the liner includes a hole near its tip to expose a portion of the explosive charge.

  17. CALUTRON

    DOE Patents [OSTI]

    Brobeck, W.M.; Lofgren, E.J.; Thornton, R.L.

    1959-06-01

    A calutron improved in liner and capacity is offered. The liner is a hollow insulated structure at high negative potential with respect to the vessel. The liner has delimiting vanes to prevent ions from one beam scattering into the receiver from another beam. The double beam-double receiver feature is thus made possible, increasing the capacity of the calutron. (T.R.H.)

  18. Central Facilities Area Sewage Lagoon Evaluation

    SciTech Connect (OSTI)

    Mark R. Cole

    2013-12-01

    The Central Facilities Area (CFA), located in Butte County, Idaho, at the Idaho National Laboratory has an existing wastewater system to collect and treat sanitary wastewater and non-contact cooling water from the facility. The existing treatment facility consists of three cells: Cell #1 has a surface area of 1.7 acres, Cell #2 has a surface area of 10.3 acres, and Cell #3 has a surface area of 0.5 acres. If flows exceed the evaporative capacity of the cells, wastewater is discharged to a 73.5-acre land application site that uses a center-pivot irrigation sprinkler system. As flows at CFA have decreased in recent years, the amount of wastewater discharged to the land application site has decreased from 13.64 million gallons in 2004 to no discharge in 2012 and 2013. In addition to the decreasing need for land application, approximately 7.7 MG of supplemental water was added to the system in 2013 to maintain a water level and prevent the clay soil liners in the cells from drying out and “cracking.” The Idaho National Laboratory is concerned that the sewage lagoons and land application site may be oversized for current and future flows. A further concern is the sustainability of the large volumes of supplemental water that are added to the system according to current operational practices. Therefore, this study was initiated to evaluate the system capacity, operational practices, and potential improvement alternatives, as warranted.

  19. Enhanced cover methods for surface coal refuse reclamation

    SciTech Connect (OSTI)

    Gentile, L.F.; Cargill, K.W.; McGarvie, S.D.

    1997-12-31

    Controlling acid rock drainage (ARD) can be a major component of surface mining reclamation. An enhanced reclamation cover system is being constructed to control infiltration of rain water and generation of ARD from coal-refuse disposal areas at a closed mine in southern Illinois. Development of the mine reclamation plan required consideration of ARD generation in coal refuse disposal areas located adjacent to an alluvial aquifer used for public water supply. An integrated site characterization was performed at the mine to provide information to develop and support the enhanced reclamation plan. The enhanced cover system is similar to covers required for municipal solid waste landfills by the Resource Conversation and Recovery Act (RCRA), Subtitle D regulations. The system comprises a graded and compacted gob layer, overlain by a compacted clay liner, and a protective soil cover. The results of infiltration modeling and analyses showed that the standard reclamation cover is effective in reducing infiltration by about 18 percent compared to an unreclaimed coal-refuse surface. The modeling results showed that the inhanced cover system should reduce infiltration by about 84 percent. The geochemical modeling results showed that the reduction in infiltration would help minimize ARD generation and contribute to an earlier reclamation of the mine site.

  20. Nuclear waste package fabricated from concrete

    SciTech Connect (OSTI)

    Pfeiffer, P.A.; Kennedy, J.M.

    1987-03-01

    After the United States enacted the Nuclear Waste Policy Act in 1983, the Department of Energy must design, site, build and operate permanent geologic repositories for high-level nuclear waste. The Department of Energy has recently selected three sites, one being the Hanford Site in the state of Washington. At this particular site, the repository will be located in basalt at a depth of approximately 3000 feet deep. The main concern of this site, is contamination of the groundwater by release of radionuclides from the waste package. The waste package basically has three components: the containment barrier (metal or concrete container, in this study concrete will be considered), the waste form, and other materials (such as packing material, emplacement hole liners, etc.). The containment barriers are the primary waste container structural materials and are intended to provide containment of the nuclear waste up to a thousand years after emplacement. After the containment barriers are breached by groundwater, the packing material (expanding sodium bentonite clay) is expected to provide the primary control of release of radionuclide into the immediate repository environment. The loading conditions on the concrete container (from emplacement to approximately 1000 years), will be twofold; (1) internal heat of the high-level waste which could be up to 400/sup 0/C; (2) external hydrostatic pressure up to 1300 psi after the seepage of groundwater has occurred in the emplacement tunnel. A suggested container is a hollow plain concrete cylinder with both ends capped. 7 refs.

  1. Final closure cover for a Hanford radioactive mixed waste disposal facility

    SciTech Connect (OSTI)

    Johnson, K.D.

    1996-02-06

    This study provides a preliminary design for a RCRA mixed waste landfill final closure cover. The cover design was developed by a senior class design team from Seattle University. The design incorporates a layered design of indigenous soils and geosynthetics in a layered system to meet final closure cover requirements for a landfill as imposed by the Washington Administrative Code WAC-173-303 implementation of the Resource Conservation and Recovery Act.

  2. Bottom head assembly

    DOE Patents [OSTI]

    Fife, Alex Blair

    1998-01-01

    A bottom head dome assembly which includes, in one embodiment, a bottom head dome and a liner configured to be positioned proximate the bottom head dome is described. The bottom head dome has a plurality of openings extending therethrough. The liner also has a plurality of openings extending therethrough, and each liner opening aligns with a respective bottom head dome opening. A seal is formed, such as by welding, between the liner and the bottom head dome to resist entry of water between the liner and the bottom head dome at the edge of the liner. In the one embodiment, a plurality of stub tubes are secured to the liner. Each stub tube has a bore extending therethrough, and each stub tube bore is coaxially aligned with a respective liner opening. A seat portion is formed by each liner opening for receiving a portion of the respective stub tube. The assembly also includes a plurality of support shims positioned between the bottom head dome and the liner for supporting the liner. In one embodiment, each support shim includes a support stub having a bore therethrough, and each support stub bore aligns with a respective bottom head dome opening.

  3. Bottom head assembly

    DOE Patents [OSTI]

    Fife, A.B.

    1998-09-01

    A bottom head dome assembly is described which includes, in one embodiment, a bottom head dome and a liner configured to be positioned proximate the bottom head dome. The bottom head dome has a plurality of openings extending there through. The liner also has a plurality of openings extending there through, and each liner opening aligns with a respective bottom head dome opening. A seal is formed, such as by welding, between the liner and the bottom head dome to resist entry of water between the liner and the bottom head dome at the edge of the liner. In the one embodiment, a plurality of stub tubes are secured to the liner. Each stub tube has a bore extending there through, and each stub tube bore is coaxially aligned with a respective liner opening. A seat portion is formed by each liner opening for receiving a portion of the respective stub tube. The assembly also includes a plurality of support shims positioned between the bottom head dome and the liner for supporting the liner. In one embodiment, each support shim includes a support stub having a bore there through, and each support stub bore aligns with a respective bottom head dome opening. 2 figs.

  4. Hydrothermal Alteration of Glass from Underground Nuclear Tests: Formation and Transport of Pu-clay Colloids at the Nevada National Security Site

    SciTech Connect (OSTI)

    Zavarin, M.; Zhao, P.; Joseph, C.; Begg, J.; Boggs, M.; Dai, Z.; Kersting, A. B.

    2015-05-27

    The testing of nuclear weapons at the Nevada National Security Site (NNSS), formerly the Nevada Test Site (NTS), has led to the deposition of substantial quantities of plutonium into the environment. Approximately 2.8 metric tons (3.1×104 TBq) of Pu were deposited in the NNSS subsurface as a result of underground nuclear testing. While 3H is the most abundant anthropogenic radionuclide deposited in the NNSS subsurface (4.7×106 TBq), plutonium is the most abundant from a molar standpoint. The only radioactive elements in greater molar abundance are the naturally occurring K, Th, and U isotopes. 239Pu and 240Pu represent the majority of alpha-emitting Pu isotopes. The extreme temperatures associated with underground nuclear tests and the refractory nature of Pu results in most of the Pu (98%) being sequestered in melted rock, referred to as nuclear melt glass (Iaea, 1998). As a result, Pu release to groundwater is controlled, in large part, by the leaching (or dissolution) of nuclear melt glass over time. The factors affecting glass dissolution rates have been studied extensively. The dissolution of Pu-containing borosilicate nuclear waste glasses at 90ºC has been shown to lead to the formation of dioctahedral smectite colloids. Colloid-facilitated transport of Pu at the NNSS has been observed. Recent groundwater samples collected from a number of contaminated wells have yielded a wide range of Pu concentrations from 0.00022 to 2.0 Bq/L. While Pu concentrations tend to fall below the Maximum Contaminant Level (MCL) established by the Environmental Protection Agency (EPA) for drinking water (0.56 Bq/L), we do not yet understand what factors limit the Pu concentration or its transport behavior. To quantify the upper limit of Pu concentrations produced as a result of melt glass dissolution and determine the nature of colloids and Pu associations, we performed a 3 year nuclear melt glass dissolution experiment across a range of temperatures (25-200 °C) that represent hydrothermal conditions representative of the underground nuclear test cavities (when groundwater has re-saturated the nuclear melt glass and glass dissolution occurs). Colloid loads and Pu concentrations were monitored along with the mineralogy of both the colloids and the secondary mineral phases. The intent was to establish an upper limit for Pu concentrations at the NNSS, provide context regarding the Pu concentrations observed at the NNSS to date and the Pu concentrations that may be observed in the future. The results provide a conceptual model for the risks posed by Pu migration at the NNSS.

  5. Combustor for a low-emissions gas turbine engine

    DOE Patents [OSTI]

    Glezer, Boris; Greenwood, Stuart A.; Dutta, Partha; Moon, Hee-Koo

    2000-01-01

    Many government entities regulated emission from gas turbine engines including CO. CO production is generally reduced when CO reacts with excess oxygen at elevated temperatures to form CO2. Many manufactures use film cooling of a combustor liner adjacent to a combustion zone to increase durability of the combustion liner. Film cooling quenches reactions of CO with excess oxygen to form CO2. Cooling the combustor liner on a cold side (backside) away from the combustion zone reduces quenching. Furthermore, placing a plurality of concavities on the cold side enhances the cooling of the combustor liner. Concavities result in very little pressure reduction such that air used to cool the combustor liner may also be used in the combustion zone. An expandable combustor housing maintains a predetermined distance between the combustor housing and combustor liner.

  6. Tokamak with liquid metal toroidal field coil

    DOE Patents [OSTI]

    Ohkawa, Tihiro; Schaffer, Michael J.

    1981-01-01

    Tokamak apparatus includes a pressure vessel for defining a reservoir and confining liquid therein. A toroidal liner disposed within the pressure vessel defines a toroidal space within the liner. Liquid metal fills the reservoir outside said liner. Electric current is passed through the liquid metal over a conductive path linking the toroidal space to produce a toroidal magnetic field within the toroidal space about the major axis thereof. Toroidal plasma is developed within the toroidal space about the major axis thereof.

  7. In situ reactor

    DOE Patents [OSTI]

    Radtke, Corey William; Blackwelder, David Bradley

    2004-01-27

    An in situ reactor for use in a geological strata, is described and which includes a liner defining a centrally disposed passageway and which is placed in a borehole formed in the geological strata; and a sampling conduit is received within the passageway defined by the liner and which receives a geological specimen which is derived from the geological strata, and wherein the sampling conduit is in fluid communication with the passageway defined by the liner.

  8. Tokamak with mechanical compression of toroidal magnetic field

    DOE Patents [OSTI]

    Ohkawa, Tihiro

    1981-01-01

    A tokamak apparatus includes a pressure vessel for defining a reservoir and confining liquid therein. A collapsible toroidal liner disposed within the pressure vessel defines a toroidal space within the liner. Liquid metal fills the reservoir outside said liner. A toroidal magnetic field is developed within the toroidal space about the major axis thereof. A toroidal plasma is developed within the toroidal space about the major axis thereof. Pressure is applied to the liquid metal to collapse the liner and reduce the volume of the toroidal space, thereby increasing the toroidal magnetic flux density therein.

  9. Sandia National Laboratories: News: Publications: Lab News

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    crush the cylinder, called a liner, fusing the deuterium and releasing neutrons and other energies associated with nuclear fusion. Anything hindering that "pinch" or "Z-pinch,"...

  10. December 11-12, 2014 - Technical Exchange Meeting - Las Vegas...

    Broader source: Energy.gov (indexed) [DOE]

    and Liners In Performance Assessments Interstate Technology & Regulatory Council (ITRC) Remediation Management of Complex Sites: Case Studies and Guidance Risk Analysis and ...

  11. Agenda - Interagency Steering Committee on Performance and Risk...

    Office of Environmental Management (EM)

    Craig Benson On Performance of Covers and Liners in Performance Assessments - Mr. Mark Phifer 1:45 - 2:45 pm Interstate Technology & Regulatory Council (ITRC) Remediation ...

  12. Microsoft PowerPoint - xxDraft SEIS PUBLIC MEETING PRESENTATION...

    National Nuclear Security Administration (NNSA)

    Zircaloy Tritium Getter Nickel Plate Lithium Aluminate Pellets Zircaloy Liner Lithium Aluminate Pellets Ceramic material containing Lithium-6, the active ingredient that transmutes ...

  13. RussiaLANLV3-web.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Modified for the Web Both laboratories (LANL and VNIIEF) seek to understand the technological issues of high-current magnetically- driven high velocity liners. This project ...

  14. SANDIA REPORT SAND96-2031 UC-742 Unlimited Release

    Office of Scientific and Technical Information (OSTI)

    ......... 51 Penetration and Fracture of Aluminum ... The length that can be extruded varies with the area or size of cavity between the liner ...

  15. DOE-Idaho Operations Summary For September 10 to October 1, 2012

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The report is broken down by contractor: Advanced Mixed Waste Treatment Project (AMWTP), Idaho ... the liner of a waste container at the Radioactive Waste Storage Facility. ...

  16. Final Meeting Summary Page 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Report considers the Hanford Site as a whole, and it does not distinguish between the ... hazardous materials. A 324 Building black cell liner leaked cesium-137 and ...

  17. TEAM0.5DL.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Instrument preparation Show how to check basic vacuum functionality and target pressure values (Gun: 1, Liner: 18-20 and Octagon: < 10) Check Gun operate "ON" and ...

  18. Moab Mill Tailings Removal Project Plans to Resume Train Shipments...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tons of Mill Tailings Removed From DOE Moab Project Site Laborers place a disposable liner in a tailings container. Moab Project Continues Progress on Tailings Removal with...

  19. Interface ring for gas turbine fuel nozzle assemblies

    DOE Patents [OSTI]

    Fox, Timothy A.; Schilp, Reinhard

    2016-03-22

    A gas turbine combustor assembly including a combustor liner and a plurality of fuel nozzle assemblies arranged in an annular array extending within the combustor liner. The fuel nozzle assemblies each include fuel nozzle body integral with a swirler assembly, and the swirler assemblies each include a bellmouth structure to turn air radially inwardly for passage into the swirler assemblies. A radially outer removed portion of each of the bellmouth structures defines a periphery diameter spaced from an inner surface of the combustor liner, and an interface ring is provided extending between the combustor liner and the removed portions of the bellmouth structures at the periphery diameter.

  20. Legacy Fleet Improvements

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    package, barrier film liner, and low hysteresis tire profile - Goodyear * Developed design process and prototype manufacturing method, proved pumping theory, refined material...

  1. Magnetotelluric Techniques | Open Energy Information

    Open Energy Info (EERE)

    cap, and also in determining the boundary between the alteration zone and the geothermal reservoir. The clay cap composition typically consists of a conductive clay from the...

  2. Remote Sensing For Geothermal Exploration Over Buffalo Valley...

    Open Energy Info (EERE)

    and spectral resolution of the data allows for the identification of carbonate, sulfate, silica and clay minerals. Quartz- and clay-rich regions of Buffalo Valley were...

  3. Introduction to computed microtomography and applications in...

    Office of Scientific and Technical Information (OSTI)

    Resource Relation: Related Information: CMS Workshop Lectures, Advanced Applications of Synchrotron Radiation in Clay Science Publisher: 2014; Tha Clay Minerals Society ;Urbana, IL ...

  4. Experimental and Modeling Investigation of Radionuclide Interaction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    interactions with clay minerals with results suggesting that iodide may directly interact with clays by forming ion-pairs which may concentrate within the interlayer space as...

  5. Tax Credits, Rebates & Savings | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Clay Electric Cooperative, Inc- Energy Conservation Loans Clay Electric Cooperative (CEC), a Touchstone Energy Cooperative, covers 14 North Florida counties, including Gainesville,...

  6. Ultrasonic search wheel probe

    DOE Patents [OSTI]

    Mikesell, Charles R.

    1978-01-01

    A device is provided for reducing internal reflections from the tire of an ultrasonic search wheel probe or from within the material being examined. The device includes a liner with an anechoic chamber within which is an ultrasonic transducer. The liner is positioned within the wheel and includes an aperture through which the ultrasonic sound from the transducer is directed.

  7. HEATING AND COOLING SYSTEM FOR CALUTRON

    DOE Patents [OSTI]

    Starr, A.M.

    1960-06-28

    An apparatus is invented for heating or cooling the electrostatic liner conventionally disposed in a calutron tank. The apparatus is additionally arranged to mount the liner in its intended position in a readily detachable manner so as to facilitate disassembly of the calutron.

  8. Test and evaluate the TRI-GAS low-Btu coal gasification process. Quarterly report, January-March 1980

    SciTech Connect (OSTI)

    Not Available

    1980-04-01

    New silicon carbide liners were cast for all three reactor vessels. The new liners will facilitate installation of the new reactor heaters and make possible a better seal between the heaters and vessel internals. Globar heating elements were received, cut to length, and installed on the new silicon carbide vessel liners in States 2 and 3. The heater for Stage 1 was reassembled on the new silicon carbide liner and installed in the vessel. Preliminary tests were made following the installation of the silicon carbide liners and heaters. The Stage 2 heater failed open, due to poor contact, after a few hours of testing. This problem was solved by nickel plating the ends of the Globars and using graphite packing to cushion the connector set screws.

  9. Combustor assembly in a gas turbine engine

    DOE Patents [OSTI]

    Wiebe, David J; Fox, Timothy A

    2013-02-19

    A combustor assembly in a gas turbine engine. The combustor assembly includes a combustor device coupled to a main engine casing, a first fuel injection system, a transition duct, and an intermediate duct. The combustor device includes a flow sleeve for receiving pressurized air and a liner disposed radially inwardly from the flow sleeve. The first fuel injection system provides fuel that is ignited with the pressurized air creating first working gases. The intermediate duct is disposed between the liner and the transition duct and defines a path for the first working gases to flow from the liner to the transition duct. An intermediate duct inlet portion is associated with a liner outlet and allows movement between the intermediate duct and the liner. An intermediate duct outlet portion is associated with a transition duct inlet section and allows movement between the intermediate duct and the transition duct.

  10. Combustor assembly in a gas turbine engine

    SciTech Connect (OSTI)

    Wiebe, David J; Fox, Timothy A

    2015-04-28

    A combustor assembly in a gas turbine engine includes a combustor device, a fuel injection system, a transition duct, and an intermediate duct. The combustor device includes a flow sleeve for receiving pressurized air and a liner surrounded by the flow sleeve. The fuel injection system provides fuel to be mixed with the pressurized air and ignited in the liner to create combustion products. The intermediate duct is disposed between the liner and the transition duct so as to define a path for the combustion products to flow from the liner to the transition duct. The intermediate duct is associated with the liner such that movement may occur therebetween, and the intermediate duct is associated with the transition duct such that movement may occur therebetween. The flow sleeve includes structure that defines an axial stop for limiting axial movement of the intermediate duct.

  11. Fuel System Compatibility Issues for Prometheus-1

    SciTech Connect (OSTI)

    DC Noe; KB Gibbard; MH Krohn

    2006-01-20

    Compatibility issues for the Prometheus-1 fuel system have been reviewed based upon the selection of UO{sub 2} as the reference fuel material. In particular, the potential for limiting effects due to fuel- or fission product-component (cladding, liner, spring, etc) chemical interactions and clad-liner interactions have been evaluated. For UO{sub 2}-based fuels, fuel-component interactions are not expected to significantly limit performance. However, based upon the selection of component materials, there is a potential for degradation due to fission products. In particular, a chemical liner may be necessary for niobium, tantalum, zirconium, or silicon carbide-based systems. Multiple choices exist for the configuration of a chemical liner within the cladding; there is no clear solution that eliminates all concerns over the mechanical performance of a clad/liner system. A series of tests to evaluate the performance of candidate materials in contact with real and simulated fission products is outlined.

  12. INTERNAL REPAIR OF PIPELINES REVIEW & EVALUATION OF INTERNAL PIPELINE REPAIR TRIALS REPORT

    SciTech Connect (OSTI)

    Robin Gordon; Bill Bruce; Ian Harris; Dennis Harwig; George Ritter; Bill Mohr; Matt Boring; Nancy Porter; Mike Sullivan; Chris Neary

    2004-09-01

    The two broad categories of fiber-reinforced composite liner repair and deposited weld metal repair technologies were reviewed and evaluated for potential application for internal repair of gas transmission pipelines. Both are used to some extent for other applications and could be further developed for internal, local, structural repair of gas transmission pipelines. Evaluation trials were conducted on pipe sections with simulated corrosion damage repaired with glass fiber-reinforced composite liners, carbon fiber-reinforced composite liners, and weld deposition. Additional un-repaired pipe sections were evaluated in the virgin condition and with simulated damage. Hydrostatic failure pressures for pipe sections repaired with glass fiber-reinforced composite liner were only marginally greater than that of pipe sections without liners, indicating that this type of liner is generally ineffective at restoring the pressure containing capabilities of pipelines. Failure pressure for pipe repaired with carbon fiber-reinforced composite liner was greater than that of the un-repaired pipe section with damage, indicating that this type of liner is effective at restoring the pressure containing capability of pipe. Pipe repaired with weld deposition failed at pressures lower than that of un-repaired pipe in both the virgin and damaged conditions, indicating that this repair technology is less effective at restoring the pressure containing capability of pipe than a carbon fiber-reinforced liner repair. Physical testing indicates that carbon fiber-reinforced liner repair is the most promising technology evaluated to-date. Development of a comprehensive test plan for this process is recommended for use in the next phase of this project.

  13. EA-1083: Finding of No Significant Impact

    Broader source: Energy.gov [DOE]

    New Silt/Clay Source Development and Use at the Idaho National Engineering and Environmental Laboratory

  14. EA-1083: Final Environmental Assessment

    Broader source: Energy.gov [DOE]

    New Silt/Clay Source Development and Use at the Idaho National Engineering and Environmental Laboratory

  15. Process for the preparation of organoclays

    DOE Patents [OSTI]

    Chaiko, David J.

    2004-11-23

    A method for preparing organoclays for use as rheological control agents and in the preparation of nanocomposites. Typically, the clay is dispersed in water, and a specific amount of polymeric hydrotrope, ranging from 0.1 to 15 weight percent relative to the weight of the clay, is adsorbed onto the clay surface. Quaternary amine exchange is also performed on the clay to modify the surface hydrophilic/lipophilic balance (HLB) of the clay.

  16. Method of lining a vertical mine shaft with concrete

    DOE Patents [OSTI]

    Eklund, James D.; Halter, Joseph M.; Rasmussen, Donald E.; Sullivan, Robert G.; Moffat, Robert B.

    1981-01-01

    The apparatus includes a cylindrical retainer form spaced inwardly of the wall of the shaft by the desired thickness of the liner to be poured and having overlapping edges which seal against concrete flow but permit the form to be contracted to a smaller circumference after the liner has hardened and is self-supporting. A curb ring extends downwardly and outwardly toward the shaft wall from the bottom of the retainer form to define the bottom surface of each poured liner section. An inflatable toroid forms a seal between the curb ring and the shaft wall. A form support gripper ring having gripper shoes laterally extendable under hydraulic power to engage the shaft wall supports the retainer form, curb ring and liner until the newly poured liner section becomes self-supporting. Adjusting hydraulic cylinders permit the curb ring and retainer form to be properly aligned relative to the form support gripper ring. After a liner section is self-supporting, an advancing system advances the retainer form, curb ring and form support gripper ring toward a shaft boring machine above which the liner is being formed. The advancing system also provides correct horizontal alignment of the form support gripper ring.

  17. High temperature lined conduits, elbows and tees

    DOE Patents [OSTI]

    De Feo, Angelo (Passaic, NJ); Drewniany, Edward (Bergen, NJ)

    1982-01-01

    A high temperature lined conduit comprising, a liner, a flexible insulating refractory blanket around and in contact with the liner, a pipe member around the blanket and spaced therefrom, and castable rigid refractory material between the pipe member and the blanket. Anchors are connected to the inside diameter of the pipe and extend into the castable material. The liner includes male and female slip joint ends for permitting thermal expansion of the liner with respect to the castable material and the pipe member. Elbows and tees of the lined conduit comprise an elbow liner wrapped with insulating refractory blanket material around which is disposed a spaced elbow pipe member with castable refractory material between the blanket material and the elbow pipe member. A reinforcing band is connected to the elbow liner at an intermediate location thereon from which extend a plurality of hollow tubes or pins which extend into the castable material to anchor the lined elbow and permit thermal expansion. A method of fabricating the high temperature lined conduit, elbows and tees is also disclosed which utilizes a polyethylene layer over the refractory blanket after it has been compressed to maintain the refractory blanket in a compressed condition until the castable material is in place. Hot gases are then directed through the interior of the liner for evaporating the polyethylene and setting the castable material which permits the compressed blanket to come into close contact with the castable material.

  18. Proposed generation and compression of a target plasma for MTF

    SciTech Connect (OSTI)

    Kirkpatrick, R.C.; Thurston, R.S.; Chrien, R.E.

    1995-09-01

    Magnetized target fusion (MTF), in which a magnetothermally insulated plasma is hydrodynamically compressed to fusion conditions, represents an approach to controlled fusion which avoids difficulties of both traditional inertial confinement and magnetic confinement approaches. The authors are proposing to demonstrate the feasibility of magnetized target fusion by: (1) creating a suitable magnetized target plasma, (2) performing preliminary liner compression experiments using existing pulsed power facilities and demonstrated liner performance. Once the target plasma and the means for its generation have been optimized, the authors plan to conduct preliminary liner compression experiments aimed at demonstrating the near-adiabatic compression of the target plasma desired for MTF. Relevant liner compression experiments have been performed at Los Alamos in the Scyllac Fast Liner Program and, more recently, in the Pegasus facility and the Procyon explosive pulsed power program. In a series of liner experiments they plan to map out the dependence of temperature and neutron production as functions of the initial plasma conditions and the liner compression achieved. With the above research program, they intend to demonstrate most of the key principles involved in magnetized target fusion, and develop the experimental and theoretical tools needed to design and execute fully integrated MTF ignition experiments.

  19. Tokamak with liquid metal for inducing toroidal electrical field

    DOE Patents [OSTI]

    Ohkawa, Tihiro

    1981-01-01

    A tokamak apparatus includes a vessel for defining a reservoir and confining liquid therein. A toroidal liner disposed within said vessel defines a toroidal space within the liner confines gas therein. Liquid metal fills the reservoir outside the liner. A magnetic field is established in the liquid metal to develop magnetic flux linking the toroidal space. The gas is ionized. The liquid metal and the toroidal space are moved relative to one another transversely of the space to generate electric current in the ionized gas in the toroidal space about its major axis and thereby heat plasma developed in the toroidal space.

  20. Heat exchanger for a Stirling engine

    SciTech Connect (OSTI)

    Fujiwara, M.; Nomaguchi, T.; Kazumoto, Y.; Tsuchino, K.; Kawajiri, K.; Hisamori, Y.

    1987-05-05

    A heat exchanger is described for a Stirling engine comprising: a domed cylinder having a domed portion and a cylindrical portion. The domed cylinder serves as a high-temperature cylinder and a regenerator housing of the Stirling engine; a cylindrical inner liner which is coaxially disposed inside the domed cylinder and which divides the inside of the domed cylinder into an expansion space inside of the inner liner and a regenerator space between the outer surface of the inner liner and the inner surface of the cylindrical portion of the domed cylinder.

  1. Methods and apparatus for radially compliant component mounting

    DOE Patents [OSTI]

    Bulman, David Edward (Cincinnati, OH); Darkins, Jr., Toby George (Loveland, OH); Stumpf, James Anthony (Columbus, IN); Schroder, Mark S. (Greenville, SC); Lipinski, John Joseph (Simpsonville, SC)

    2012-03-27

    Methods and apparatus for a mounting assembly for a liner of a gas turbine engine combustor are provided. The combustor includes a combustor liner and a radially outer annular flow sleeve. The mounting assembly includes an inner ring surrounding a radially outer surface of the liner and including a plurality of axially extending fingers. The mounting assembly also includes a radially outer ring coupled to the inner ring through a plurality of spacers that extend radially from a radially outer surface of the inner ring to the outer ring.

  2. Flow through in situ reactors with suction lysimeter sampling capability and methods of using

    DOE Patents [OSTI]

    Radtke, Corey W. (Idaho Falls, ID) [Idaho Falls, ID; Blackwelder, D. Brad (Blackfoot, ID) [Blackfoot, ID; Hubbell, Joel M. (Idaho Falls, ID) [Idaho Falls, ID

    2009-11-17

    An in situ reactor for use in a geological strata includes a liner defining a centrally disposed passageway and a sampling conduit received within the passageway. The sampling conduit may be used to receive a geological speciment derived from geological strata therein and a lysimeter is disposed within the sampling conduit in communication with the geological specimen. Fluid may be added to the geological specimen through the passageway defined by the liner, between an inside surface of the liner and an outside surface of the sampling conduit. A distal portion of the sampling conduit may be in fluid communication with the passageway.

  3. Methods and systems to facilitate reducing NO.sub.x emissions in combustion systems

    DOE Patents [OSTI]

    Lacy, Benjamin Paul; Kraemer, Gilbert Otto; Varatharajan, Balachandar; Yilmaz, Ertan; Lipinski, John Joseph; Ziminsky, Willy Steve

    2011-02-15

    A method for assembling a gas turbine combustor system is provided. The method includes providing a combustion liner including a center axis, an outer wall, a first end, and a second end. The outer wall is orientated substantially parallel to the center axis. The method also includes coupling a transition piece to the liner second end. The transition piece includes an outer wall. The method further includes coupling a plurality of lean-direct injectors along at least one of the liner outer wall and the transition piece outer wall such that the injectors are spaced axially apart along the wall.

  4. RADIOLOGICAL DATA FOR ALARA PLANNING PURPOSES Rev. 1 Contact

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RADIOLOGICAL DATA FOR ALARA PLANNING PURPOSES Rev. 1 Contact 1 ft 3 ft 10 ft 25 ft 50 ft 125 ft 100 mR/hr line 5 mR/hr line (R/hr) (R/hr) (R/hr) (R/hr) (R/hr) (R/hr) (R/hr) (feet) (feet) Outside of Cask (max) *Unshielded Liner (max) Top of *Unshielded Liner after the cask lid is removed *Unshielded Liner Inside of Cask/Lid Outside of Cask Lifting rig or any other support equipment Does the cask have fixed contamination that may "leach out" during transport (Yes/No)? If yes, please list

  5. Free form hemispherical shaped charge

    DOE Patents [OSTI]

    Haselman, L.C. Jr.

    1996-06-04

    A hemispherical shaped charge has been modified such that one side of the hemisphere is spherical and the other is aspherical allowing a wall thickness variation in the liner. A further modification is to use an elongated hemispherical shape. The liner has a thick wall at its pole and a thin wall at the equator with a continually decreasing wall thickness from the pole to the equator. The ratio of the wall thickness from the pole to the equator varies depending on liner material and HE shape. Hemispherical shaped charges have previously been limited to spherical shapes with no variations in wall thicknesses. By redesign of the basic liner thicknesses, the jet properties of coherence, stability, and mass distribution have been significantly improved. 8 figs.

  6. Free form hemispherical shaped charge

    DOE Patents [OSTI]

    Haselman, Jr., Leonard C.

    1996-01-01

    A hemispherical shaped charge has been modified such that one side of the hemisphere is spherical and the other is aspherical allowing a wall thickness variation in the liner. A further modification is to use an elongated hemispherical shape. The liner has a thick wall at its pole and a thin wall at the equator with a continually decreasing wall thickness from the pole to the equator. The ratio of the wall thickness from the pole to the equator varies depending on liner material and HE shape. Hemispherical shaped charges have previously been limited to spherical shapes with no variations in wall thicknesses. By redesign of the basic liner thicknesses, the jet properties of coherence, stability, and mass distribution have been significantly improved.

  7. Melt Infiltrated Ceramic Composites (Hipercomp) for Gas Turbine...

    Office of Scientific and Technical Information (OSTI)

    ... via combustion rig testing of turbine shrouds and combustor liners, and through field engine tests of shrouds in a 2MW engine for >1000 hours. A unique combustion test ...

  8. First Draft Performance Assessment for the H-Area Tank Farm at...

    Office of Environmental Management (EM)

    ... H-Area Tank Farm at the Revision 0 Savannah River Site March 2011 Page xxx of 864 Figure 5.6-83: CZ (No Liner) Hydraulic Degradation - Type II Tank ...

  9. RussiaLANLV3-web.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dynamic radiographs of stable and unstable liner experiments compared with 2D MHD calculations. Modifi ed for the Web Modified for the Web experiments" conducted in FY02, the ...

  10. RussiaLANLV3-web.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    C U R R E N T 0 50 100 150 200 250 300 Modifi ed for the Web Project Description ... Liner CMU Current Diagnostics Modified for the Web showed that the inner surface of the ...

  11. CX-007514: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion for Big Hill Anhydrite Pond Liner Replacement CX(s) Applied: B1.3 Date: 12/20/2011 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  12. Epitaxial CoSi2 on MOS devices

    DOE Patents [OSTI]

    Lim, Chong Wee; Shin, Chan Soo; Petrov, Ivan Georgiev; Greene, Joseph E.

    2005-01-25

    An Si.sub.x N.sub.y or SiO.sub.x N.sub.y liner is formed on a MOS device. Cobalt is then deposited and reacts to form an epitaxial CoSi.sub.2 layer underneath the liner. The CoSi.sub.2 layer may be formed through a solid phase epitaxy or reactive deposition epitaxy salicide process. In addition to high quality epitaxial CoSi.sub.2 layers, the liner formed during the invention can protect device portions during etching processes used to form device contacts. The liner can act as an etch stop layer to prevent excessive removal of the shallow trench isolation, and protect against excessive loss of the CoSi.sub.2 layer.

  13. CX-007968: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Retention Basin Cover & Liner System Removal From Service CX(s) Applied: B1.28 Date: 02/07/2012 Location(s): South Carolina Offices(s): Savannah River Operations Office

  14. Tecnai

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Know location of Titan documentation. Show how to check basic vacuum functionality (Gun 1, Liner 19-21, Octagon <20). Show how to read extraction voltage, gun lens, microscope ...

  15. CX-001003: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    West Hackberry Tank (WHT)-1 and WHT-10 Liner Removal/RelineCX(s) Applied: B1.3Date: 03/01/2010Location(s): West Hackberry, LouisianaOffice(s): Fossil Energy, Strategic Petroleum Reserve Field Office

  16. Search for: All records | DOE Patents

    Office of Scientific and Technical Information (OSTI)

    A combustion chamber surrounded by an annular combustor liner disposed in supply flow communication with the pre-mixer. An annular trapped dual vortex cavity located at an upstream ...

  17. SPRU Removes High-Risk Radioactive Waste | Department of Energy

    Office of Environmental Management (EM)

    SPRU Removes High-Risk Radioactive Waste SPRU Removes High-Risk Radioactive Waste December 23, 2014 - 12:00pm Addthis A truck carrying the last two solidified liners from the SPRU ...

  18. CX-006729: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Liner DrillingCX(s) Applied: B1.3, B3.7, B5.12Date: 04/27/2010Location(s): Casper, WyomingOffice(s): RMOTC

  19. Off-Board Considerations

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Type-3 Containment Vessel * 2.25 safety factor * 5,500 P and T cycles * Toray 2550 MPa CF * Al 6061-T6 alloy liner Heat Transfer System * 1.5 kgmin H 2 refueling rate * 1.6 ...

  20. DOE Tour of Zero: The Pronghorn Ranch by Mandalay Homes | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The foundation water barrier system includes a heavy-duty plastic liner installed under and around the slab-on-grade foundation. An energy-saving slab edge with R-10 rigid foam ...

  1. DOE Tour of Zero: Pronghorn Ranch by Mandalay Homes | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The foundation water barrier system includes a heavy-duty plastic liner installed under and around the slab-on-grade foundation. An energy-saving slab edge with R-10 rigid foam ...

  2. Method of melting metals to reduce contamination from crucibles

    DOE Patents [OSTI]

    Banker, John G.; Wigginton, Hubert L.

    1977-01-01

    Contamination of metals from crucible materials during melting operations is reduced by coating the interior surface of the crucible with a ceramic non-reactive with the metallic charge and disposing a metal liner formed from a portion of the metallic charge within the coated crucible. The liner protects the ceramic coating during loading of the remainder of the charge and expands against the ceramic coating during heat-up to aid in sintering the coating.

  3. Linearization of scan velocity of resonant vibrating-mirror beam deflectors

    DOE Patents [OSTI]

    Yeung, Edward S.; Chen, Shun-Le

    1991-01-15

    A means and method for producing linerization of scan velocity of resonant vibrating-mirror beam deflectors in laser scanning system including presenting an elliptical convex surface to the scanning beam to reflect the scanning beam to the focal plane of the scanning line. The elliptical surface is shaped to produce linear velocity of the reflective scanning beam at the focal plane. Maximization of linerization is accomplished by considering sets of criteria for different scanning applications.

  4. RAP - Transcribed Flipcharts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    March 15, 2016 Environmental Restoration and Disposal Facility (ERDF) Vertical Expansion  Questions should be framed as questions, not comments or assumptions  Revisit / update on liner  Understand relationship to ERDF ROD and performance assessment o ARARs  Additional questions, per Jean: o Landslides o Cultural resources; tribal consultation o Cap construction o Removing existing soil/liner  Request for workshop, presentation  Opportunity to involve public, HAB  Potential

  5. Moab Project Continues Progress on Tailings Removal with Contract

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transition | Department of Energy Progress on Tailings Removal with Contract Transition Moab Project Continues Progress on Tailings Removal with Contract Transition December 27, 2012 - 12:00pm Addthis Laborers place a disposable liner in a tailings container. Laborers place a disposable liner in a tailings container. MOAB, Utah - The Moab mill tailings removal project in Utah ended the year having shipped more than 35 percent of the total 16 million tons of uranium mill tailings off-site.

  6. Aluminum low temperature smelting cell metal collection

    DOE Patents [OSTI]

    Beck, Theodore R.; Brown, Craig W.

    2002-07-16

    A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte. The method comprises the steps of providing a molten salt electrolyte in an electrolytic cell having an anodic liner for containing the electrolyte, the liner having an anodic bottom and walls including at least one end wall extending upwardly from the anodic bottom, the anodic liner being substantially inert with respect to the molten electrolyte. A plurality of non-consumable anodes is provided and disposed vertically in the electrolyte. A plurality of cathodes is disposed vertically in the electrolyte in alternating relationship with the anodes. The anodes are electrically connected to the anodic liner. An electric current is passed through the anodic liner to the anodes, through the electrolyte to the cathodes, and aluminum is deposited on said cathodes. Oxygen bubbles are generated at the anodes and the anodic liner, the bubbles stirring the electrolyte. Molten aluminum is collected from the cathodes into a tubular member positioned underneath the cathodes. The tubular member is in liquid communication with each cathode to collect the molten aluminum therefrom while excluding electrolyte. Molten aluminum is delivered through the tubular member to a molten aluminum reservoir located substantially opposite the anodes and cathodes. The molten aluminum is collected from the cathodes and delivered to the reservoir while avoiding contact of the molten aluminum with the anodic bottom.

  7. SEISMIC AND ROCK PHYSICS DIAGNOSTICS OF MULTISCALE RESERVOIR TEXTURES

    SciTech Connect (OSTI)

    Gary Mavko

    2003-06-01

    As part of our study on ''Relationships between seismic properties and rock microstructure'', we have studied (1) Elastic properties of clay minerals using Pulse Transmission experiments. We show measurements of elastic moduli and strain in clay minerals.

  8. Disposal Systems Evaluations and Tool Development - Engineered...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    conditions, thermodynamic database development for cement and clay phases, ... and potential variants according to waste form and disposal environment characteristics. ...

  9. On the structural stability and catalytic properties of smectities pillared with RE-Al, Al-Ga polyoxications

    SciTech Connect (OSTI)

    Caballero, L.; Dominguez, J.M.; De los Santos, J.L.

    1995-12-01

    Pillaring of Smectite type clays offers the possibility to develop highly porous catalytic materials with surface acid properties, (1) their me in hydrotreating and FCC hydrocarbon processes has been extensively discussed (2) and still some research on the stabilization of the clays structure is being carried out. Therefore, the aim of the present work was to investigate thermal stability of Montmorillonite type clays, by means of pillaring with distinct polyoxications and by ion-exchanging and treating the clays under several conditions.

  10. Large-Scale Condensed Matter and Fluid Dynamics Simulations in Three

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Diverse Areas: Part II: Molecular Dynamics Study of Clay-Polymer Nanocomposites | Argonne Leadership Computing Facility Snapshot from a molecular dynamics simulation of a system containing 16 isolated clay sheets immersed in a polymer melt. , Snapshot from a molecular dynamics simulation of an isolated clay platelet (consisting of two sheets) immersed in water. Top image: Snapshot from a molecular dynamics simulation of a system containing 16 isolated clay sheets immersed in a polymer melt.

  11. Tax Credits, Rebates & Savings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    approval, Wind (Small), Anaerobic Digestion, Fuel Cells using Renewable Fuels, Other Distributed Generation Technologies Clay Electric Cooperative, Inc- Energy Conservation...

  12. Process for the preparation of organoclays

    DOE Patents [OSTI]

    Chaiko, David J.

    2003-01-01

    A method for preparing organoclays from smectites for use as rheological control agents and in the preparation of nanocomposites. Typically, the clay is dispersed in water, and a substantially monomolecular layer of a water soluble polymer is applied to the surfaces of the clay. A surfactant is also applied to the clay to modify the surface hydrophilic/hydrophobic balance of the clay, and the organoclay is separated out for subsequent use.

  13. Geotechnical practice in dam rehabilitation

    SciTech Connect (OSTI)

    Anderson, L.R.

    1993-01-01

    This proceedings, Geotechnical Practice in Dam Rehabilitation, consists of papers presented at the Specialty Conference sponsored by the Geotechnical Engineering Division of the American Society of Civil Engineers held in Raleigh, North Carolina, April 25-28, 1993. The conference provided a forum for the discussion of the rehabilitation of dams, including case histories and current geotechnical practice. The topics covered by this proceeding include: (1) inspection and monitoring of dams; (2) investigation and evaluation of dams and foundations; (3) risk and reliability assessment; (4) increasing reservoir capacity, spillway modifications and overtopping; (5) seepage control; (6) improving stability of dams, foundations and reservoir slopes; (7) rehabilitation for seismic stability; and (8) geosynthetics and ground improvement techniques.

  14. Seismic behavior of geogrid reinforced slag wall

    SciTech Connect (OSTI)

    Edincliler, Ayse; Baykal, Gokhan; Saygili, Altug

    2008-07-08

    Flexible retaining structures are known with their high performance under earthquake loads. In geogrid reinforced walls the performance of the fill material and the interface of the fill and geogrid controls the performance. Geosynthetic reinforced walls in seismic regions must be safe against not only static forces but also seismic forces. The objective of this study is to determine the behavior of a geogrid reinforced slag wall during earthquake by using shaking table experiments. This study is composed of three stages. In the first stage the physical properties of the material to be used were determined. In the second part, a case history involving the use of slag from steel industry in the construction of geogrid reinforced wall is presented. In the third stage, the results of shaking table tests conducted using model geogrid wall with slag are given. From the results, it is seen that slag can be used as fill material for geogrid reinforced walls subjected to earthquake loads.

  15. Anisotropic capillary barrier for waste site surface covers

    DOE Patents [OSTI]

    Stormont, John C. (Sandia Park, NM)

    1996-01-01

    Waste sites are capped or covered upon closure. The cover structure incorporates a number of different layers each having a contributory function. One such layer is the barrier layer. Traditionally the barriers have been compacted soil and geosynthetics. These types of barriers have not been successfully implemented in unsaturated ground conditions like those found in dry climates. Capillary barriers have been proposed as barrier layers in dry environments, but the divergence length of these barriers has been found to be inadequate. An alternative to the capillary barrier is a anisotropic capillary barrier. An anisotropic capillary barrier has an increased divergence length which results in more water being diverted laterally preventing the majority of water from percolating in a downward direction through the barrier.

  16. Case studies in alternative landfill design

    SciTech Connect (OSTI)

    Barbagallo, J.C.; Druback, G.W.

    1995-12-31

    In the past, landfills or {open_quotes}dumps{close_quotes} were not highly regulated and typically did not require a detailed engineering design. However, landfills are no longer just holes in the ground, and landfill closures entail more than just spreading some dirt on top of piles of garbage. Today landfill design is a highly regulated, complex design effort that integrates soils and geosynthetics into systems aimed at providing long-term protection for the environment and surrounding communities. Integrating these complex design systems into the available landscape and exising landfill configuration often requires the designer go beyond the {open_quotes}typical{close_quotes} landfill and landfill closure design to satisfy regulations and provide cost-effective solutions.

  17. INTERNAL REPAIR OF PIPELINES

    SciTech Connect (OSTI)

    Bill Bruce; Nancy Porter; George Ritter; Matt Boring; Mark Lozev; Ian Harris; Bill Mohr; Dennis Harwig; Robin Gordon; Chris Neary; Mike Sullivan

    2005-07-20

    The two broad categories of fiber-reinforced composite liner repair and deposited weld metal repair technologies were reviewed and evaluated for potential application for internal repair of gas transmission pipelines. Both are used to some extent for other applications and could be further developed for internal, local, structural repair of gas transmission pipelines. Principal conclusions from a survey of natural gas transmission industry pipeline operators can be summarized in terms of the following performance requirements for internal repair: (1) Use of internal repair is most attractive for river crossings, under other bodies of water, in difficult soil conditions, under highways, under congested intersections, and under railway crossings. (2) Internal pipe repair offers a strong potential advantage to the high cost of horizontal direct drilling when a new bore must be created to solve a leak or other problem. (3) Typical travel distances can be divided into three distinct groups: up to 305 m (1,000 ft.); between 305 m and 610 m (1,000 ft. and 2,000 ft.); and beyond 914 m (3,000 ft.). All three groups require pig-based systems. A despooled umbilical system would suffice for the first two groups which represents 81% of survey respondents. The third group would require an onboard self-contained power unit for propulsion and welding/liner repair energy needs. (4) The most common size range for 80% to 90% of operators surveyed is 508 mm (20 in.) to 762 mm (30 in.), with 95% using 558.8 mm (22 in.) pipe. Evaluation trials were conducted on pipe sections with simulated corrosion damage repaired with glass fiber-reinforced composite liners, carbon fiber-reinforced composite liners, and weld deposition. Additional un-repaired pipe sections were evaluated in the virgin condition and with simulated damage. Hydrostatic failure pressures for pipe sections repaired with glass fiber-reinforced composite liner were only marginally greater than that of pipe sections without

  18. Nuclear reactor

    DOE Patents [OSTI]

    Pennell, William E.; Rowan, William J.

    1977-01-01

    A nuclear reactor in which the core components, including fuel-rod assemblies, control-rod assemblies, fertile rod-assemblies, and removable shielding assemblies, are supported by a plurality of separate inlet modular units. These units are referred to as inlet module units to distinguish them from the modules of the upper internals of the reactor. The modular units are supported, each removable independently of the others, in liners in the supporting structure for the lower internals of the reactor. The core assemblies are removably supported in integral receptacles or sockets of the modular units. The liners, units, sockets and assmblies have inlet openings for entry of the fluid. The modular units are each removably mounted in the liners with fluid seals interposed between the opening in the liner and inlet module into which the fluid enters and the upper and lower portion of the liner. Each assembly is similarly mounted in a corresponding receptacle with fluid seals interposed between the openings where the fluid enters and the lower portion of the receptacle or fitting closely in these regions. As fluid flows along each core assembly a pressure drop is produced along the fluid so that the fluid which emerges from each core assembly is at a lower pressure than the fluid which enters the core assembly. However because of the seals interposed in the mountings of the units and assemblies the pressures above and below the units and assemblies are balanced and the units are held in the liners and the assemblies are held in the receptacles by their weights as they have a higher specific gravity than the fluid. The low-pressure spaces between each module and its liner and between each core assembly and its module is vented to the low-pressure regions of the vessel to assure that fluid which leaks through the seals does not accumulate and destroy the hydraulic balance.

  19. Modular assembly for supporting, straining, and directing flow to a core in a nuclear reactor

    DOE Patents [OSTI]

    Pennell, William E.

    1977-01-01

    A reactor core support arrangement for supporting, straining, and providing fluid flow to the core and periphery of a nuclear reactor during normal operation. A plurality of removable inlet modular units are contained within permanent liners in the lower supporting plate of the reactor vessel lower internals. During normal operation (1) each inlet modular unit directs main coolant flow to a plurality of core assemblies, the latter being removably supported in receptacles in the upper portion of the modular unit and (2) each inlet modular unit may direct bypass flow to a low pressure annular region of the reactor vessel. Each inlet modular unit may include special fluid seals interposed between mating surfaces of the inlet modular units and the core assemblies and between the inlet modular units and the liners, to minimize leakage and achieve an hydraulic balance. Utilizing the hydraulic balance, the modular units are held in the liners and the assemblies are held in the modular unit receptacles by their own respective weight. Included as part of the permanent liners below the horizontal support plate are generally hexagonal axial debris barriers. The axial debris barriers collectively form a bottom boundary of a secondary high pressure plenum, the upper boundary of which is the bottom surface of the horizontal support plate. Peripheral liners include radial debris barriers which collectively form a barrier against debris entry radially. During normal operation primary coolant inlet openings in the liner, below the axial debris barriers, pass a large amount of coolant into the inlet modular units, and secondary coolant inlet openings in the portion of the liners within the secondary plenum pass a small amount of coolant into the inlet modular units. The secondary coolant inlet openings also provide alternative coolant inlet flow paths in the unlikely event of blockage of the primary inlet openings. The primary inlet openings have characteristics which limit the

  20. Method of preparation of a CO.sub.2 removal sorbent with high chemical stability during multiple cycles

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.; Rosencwaig, Shira

    2015-07-14

    Method for the production of a clay-alkali-amine CO.sub.2 sorbent prepared by integrating a clay substrate, basic alkali salt, and amine liquid. The basic alkali salt is present relative to the clay substrate in a weight ratio of from about 1 part to about 50 parts per 100 parts of the clay substrate. The amine liquid is present relative to a clay-alkali combination in a weight ratio of from about 1 part to about 10 parts per 10 parts of the clay-alkali combination. The clay substrate and basic alkali salt may be combined in a solid-solid heterogeneous mixture and followed by introduction of the amine liquid. Alternatively, an alkaline solution may be blended with the amine solution prior to contacting the clay substrate. The clay-alkali-amine CO.sub.2 sorbent is particularly advantageous for low temperature CO.sub.2 removal cycles in a gas stream having a CO.sub.2 concentration less than around 2000 ppm and an oxygen concentration around 21%, such as air. Results are presented illustrating the performance of the clay-alkali-amine CO.sub.2 sorbent compared to a clay-amine sorbent lacking the alkali inclusion.

  1. CO.sub.2 removal sorbent composition with high chemical stability during multiple cycles

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.; Rosencwaig, Shira

    2015-09-22

    Disclosed herein is a clay-alkali-amine CO.sub.2 sorbent composition prepared by integrating a clay substrate, basic alkali salt, and amine liquid. The basic alkali salt is present relative to the clay substrate in a weight ratio of from about 1 part to about 50 parts per 100 parts of the clay substrate. The amine liquid is present relative to a clay-alkali combination in a weight ratio of from about 1 part to about 10 parts per 10 parts of the clay-alkali combination. The clay-alkali-amine C02 sorbent is particularly advantageous for low temperature CO.sub.2 removal cycles in a gas stream having a C02 concentration less than around 2000 ppm and an oxygen concentration around 21%, such as air.

  2. INTERNAL REPAIR OF PIPELINES

    SciTech Connect (OSTI)

    Robin Gordon; Bill Bruce; Ian Harris; Dennis Harwig; George Ritter; Bill Mohr; Matt Boring; Nancy Porter; Mike Sullivan; Chris Neary

    2004-12-31

    The two broad categories of fiber-reinforced composite liner repair and deposited weld metal repair technologies were reviewed and evaluated for potential application for internal repair of gas transmission pipelines. Both are used to some extent for other applications and could be further developed for internal, local, structural repair of gas transmission pipelines. Principal conclusions from a survey of natural gas transmission industry pipeline operators can be summarized in terms of the following performance requirements for internal repair: (1) Use of internal repair is most attractive for river crossings, under other bodies of water, in difficult soil conditions, under highways, under congested intersections, and under railway crossings. (2) Internal pipe repair offers a strong potential advantage to the high cost of horizontal direct drilling when a new bore must be created to solve a leak or other problem. (3) Typical travel distances can be divided into three distinct groups: up to 305 m (1,000 ft.); between 305 m and 610 m (1,000 ft. and 2,000 ft.); and beyond 914 m (3,000 ft.). All three groups require pig-based systems. A despooled umbilical system would suffice for the first two groups which represents 81% of survey respondents. The third group would require an onboard self-contained power unit for propulsion and welding/liner repair energy needs. (4) The most common size range for 80% to 90% of operators surveyed is 508 mm (20 in.) to 762 mm (30 in.), with 95% using 558.8 mm (22 in.) pipe. Evaluation trials were conducted on pipe sections with simulated corrosion damage repaired with glass fiber-reinforced composite liners, carbon fiber-reinforced composite liners, and weld deposition. Additional un-repaired pipe sections were evaluated in the virgin condition and with simulated damage. Hydrostatic failure pressures for pipe sections repaired with glass fiber-reinforced composite liner were only marginally greater than that of pipe sections without

  3. INTERNAL REPAIR OF PIPELINES

    SciTech Connect (OSTI)

    Robin Gordon; Bill Bruce; Ian Harris; Dennis Harwig; George Ritter; Bill Mohr; Matt Boring; Nancy Porter; Mike Sullivan; Chris Neary

    2004-08-17

    The two broad categories of fiber-reinforced composite liner repair and deposited weld metal repair technologies were reviewed and evaluated for potential application for internal repair of gas transmission pipelines. Both are used to some extent for other applications and could be further developed for internal, local, structural repair of gas transmission pipelines. Principal conclusions from a survey of natural gas transmission industry pipeline operators can be summarized in terms of the following performance requirements for internal repair: (1) Use of internal repair is most attractive for river crossings, under other bodies of water, in difficult soil conditions, under highways, under congested intersections, and under railway. (2) Internal pipe repair offers a strong potential advantage to the high cost of horizontal direct drilling when a new bore must be created to solve a leak or other problem. (3) Typical travel distances can be divided into three distinct groups: up to 305 m (1,000 ft.); between 305 m and 610 m (1,000 ft. and 2,000 ft.); and beyond 914 m (3,000 ft.). All three groups require pig-based systems. A despooled umbilical system would suffice for the first two groups which represents 81% of survey respondents. The third group would require an onboard self-contained power unit for propulsion and welding/liner repair energy needs. (4) The most common size range for 80% to 90% of operators surveyed is 508 mm (20 in.) to 762 mm (30 in.), with 95% using 558.8 mm (22 in.) pipe. Evaluation trials were conducted on pipe sections with simulated corrosion damage repaired with glass fiber-reinforced composite liners, carbon fiber-reinforced composite liners, and weld deposition. Additional un-repaired pipe sections were evaluated in the virgin condition and with simulated damage. Hydrostatic failure pressures for pipe sections repaired with glass fiber-reinforced composite liner were only marginally greater than that of pipe sections without liners

  4. Methods for detecting and locating leaks in containment facilities using electrical potential data and electrical resistance tomographic imaging techniques

    DOE Patents [OSTI]

    Daily, William D.; Laine, Daren L.; Laine, Edwin F.

    1997-01-01

    Methods are provided for detecting and locating leaks in liners used as barriers in the construction of landfills, surface impoundments, water reservoirs, tanks, and the like. Electrodes are placed in the ground around the periphery of the facility, in the leak detection zone located between two liners if present, and/or within the containment facility. Electrical resistivity data is collected using these electrodes. This data is used to map the electrical resistivity distribution beneath the containment liner between two liners in a double-lined facility. In an alternative embodiment, an electrode placed within the lined facility is driven to an electrical potential with respect to another electrode placed at a distance from the lined facility (mise-a-la-masse). Voltage differences are then measured between various combinations of additional electrodes placed in the soil on the periphery of the facility, the leak detection zone, or within the facility. A leak of liquid though the liner material will result in an electrical potential distribution that can be measured at the electrodes. The leak position is located by determining the coordinates of an electrical current source pole that best fits the measured potentials with the constraints of the known or assumed resistivity distribution.

  5. Methods for detecting and locating leaks in containment facilities using electrical potential data and electrical resistance tomographic imaging techniques

    DOE Patents [OSTI]

    Daily, W.D.; Laine, D.L.; Laine, E.F.

    1997-08-26

    Methods are provided for detecting and locating leaks in liners used as barriers in the construction of landfills, surface impoundments, water reservoirs, tanks, and the like. Electrodes are placed in the ground around the periphery of the facility, in the leak detection zone located between two liners if present, and/or within the containment facility. Electrical resistivity data is collected using these electrodes. This data is used to map the electrical resistivity distribution beneath the containment liner between two liners in a double-lined facility. In an alternative embodiment, an electrode placed within the lined facility is driven to an electrical potential with respect to another electrode placed at a distance from the lined facility (mise-a-la-masse). Voltage differences are then measured between various combinations of additional electrodes placed in the soil on the periphery of the facility, the leak detection zone, or within the facility. A leak of liquid though the liner material will result in an electrical potential distribution that can be measured at the electrodes. The leak position is located by determining the coordinates of an electrical current source pole that best fits the measured potentials with the constraints of the known or assumed resistivity distribution. 6 figs.

  6. Methods for detecting and locating leaks in containment facilities using electrical potential data and electrical resistance tomographic imaging techniques

    DOE Patents [OSTI]

    Daily, William D.; Laine, Daren L.; Laine, Edwin F.

    2001-01-01

    Methods are provided for detecting and locating leaks in liners used as barriers in the construction of landfills, surface impoundments, water reservoirs, tanks, and the like. Electrodes are placed in the ground around the periphery of the facility, in the leak detection zone located between two liners if present, and/or within the containment facility. Electrical resistivity data is collected using these electrodes. This data is used to map the electrical resistivity distribution beneath the containment liner or between two liners in a double-lined facility. In an alternative embodiment, an electrode placed within the lined facility is driven to an electrical potential with respect to another electrode placed at a distance from the lined facility (mise-a-la-masse). Voltage differences are then measured between various combinations of additional electrodes placed in the soil on the periphery of the facility, the leak detection zone, or within the facility. A leak of liquid through the liner material will result in an electrical potential distribution that can be measured at the electrodes. The leak position is located by determining the coordinates of an electrical current source pole that best fits the measured potentials with the constraints of the known or assumed resistivity distribution.

  7. Gas turbine igniter with ball-joint support

    SciTech Connect (OSTI)

    Steber, C.E.; Travis, R.J.; Rizzo, J.A.

    1990-02-27

    This patent describes a support for an igniter for a combustor of a gas turbine, the combustor being of a type including a casing and a liner within the casing. It comprises: a ball joint; means for supporting the ball joint disposed a substantial distance outward from the casing; a body section of the igniter affixed in the ball joint; means for permitting the ball joint, and the body section to rotate through a substantial range; an igniter tip on the body section; and a hole in the liner. The igniter tip entering through the hole and into an interior of the liner. The hole being a tight fit to the igniter tip, whereby leakage past the igniter tip through the hole is limited. The substantial range being sufficient to permit fitting the igniter tip in the hole in the presence of manufacturing tolerances, and to permit the igniter tip to track the hole in the presence of differential thermal expansion during operation.

  8. Irradiation subassembly

    DOE Patents [OSTI]

    Seim, O.S.; Filewicz, E.C.; Hutter, E.

    1973-10-23

    An irradiation subassembly for use in a nuclear reactor is described which includes a bundle of slender elongated irradiation -capsules or fuel elements enclosed by a coolant tube and having yieldable retaining liner between the irradiation capsules and the coolant tube. For a hexagonal bundle surrounded by a hexagonal tube the yieldable retaining liner may consist either of six segments corresponding to the six sides of the tube or three angular segments each corresponding in two adjacent sides of the tube. The sides of adjacent segments abut and are so cut that metal-tometal contact is retained when the volume enclosed by the retaining liner is varied and Springs are provided for urging the segments toward the center of the tube to hold the capsules in a closely packed configuration. (Official Gazette)

  9. Three-phase hypervelocity projectile launcher

    DOE Patents [OSTI]

    Fugelso, L. Erik; Langner, Gerald C.; Burns, Kerry L.; Albright, James N.

    1994-01-01

    A hypervelocity projectile launcher for use in perforating borehole casings provides improved penetration into the surrounding rock structure. The launcher includes a first cylinder of explosive material that defines an axial air-filled cavity, a second cylinder of explosive material defining an axial frustum-shaped cavity abutting and axially aligned with the first cylinder. A pliant washer is located between and axially aligned with the first and second cylinders. The frustum shaped cavity is lined with a metal liner effective to form a projectile when the first and second cylinders are detonated. The washer forms a unique intermediate projectile in advance of the liner projectile and enables the liner projectile to further penetrate into and fracture the adjacent rock structure.

  10. Method for processing aluminum spent potliner in a graphite electrode arc furnace

    DOE Patents [OSTI]

    O'Connor, William K.; Turner, Paul C.; Addison, G.W.

    2002-12-24

    A method of processing spent aluminum pot liner containing carbon, cyanide compositions, fluorides and inorganic oxides. The spend aluminum pot liner is crushed, iron oxide is added to form an agglomerated material. The agglomerated material is melted in an electric arc furnace having the electrodes submerged in the molten material to provide a reducing environment during the furnace operation. In the reducing environment, pot liner is oxidized while the iron oxides are reduced to produce iron and a slag substantially free of cyanide compositions and fluorides. An off-gas including carbon oxides and fluorine is treated in an air pollution control system with an afterburner and a scrubber to produce NaF, water and a gas vented to the atmosphere free of cyanide compositions, fluorine, and CO.

  11. Cavity closure arrangement for high pressure vessels

    DOE Patents [OSTI]

    Amtmann, Hans H.

    1981-01-01

    A closure arrangement for a pressure vessel such as the pressure vessel of a high temperature gas-cooled reactor wherein a liner is disposed within a cavity penetration in the reactor vessel and defines an access opening therein. A closure is adapted for sealing relation with an annular mounting flange formed on the penetration liner and has a plurality of radially movable locking blocks thereon having outer serrations adapted for releasable interlocking engagement with serrations formed internally of the upper end of the penetration liner so as to effect high strength closure hold-down. In one embodiment, ramping surfaces are formed on the locking block serrations to bias the closure into sealed relation with the mounting flange when the locking blocks are actuated to locking positions.

  12. APPARATUS FOR CONDENSATION AND SUBLIMATION

    DOE Patents [OSTI]

    Schmidt, R.J.; Fuis, F. Jr.

    1958-10-01

    An apparatus is presented for the sublimation and condensation of uranium compounds in order to obtain an improved crystalline structure of this material. The apparatus comprises a vaporizing chamber and condensing structure connected thereto. There condenser is fitted with a removable liner having a demountable baffle attached to the liner by means of brackets and a removable pin. The baffle is of spiral cross-section and is provided with cooling coils disposed between the surfaces of the baffle for circulation of a temperature controlling liquid within the baffle. The cooling coll provides for controlllng the temperature of the baffle to insure formatlon of a satisfactory condensate, and the removable liner facilitates the removal of condensate formed during tbe sublimation process.

  13. Method for processing aluminum spent potliner in a graphite electrode ARC furnace

    DOE Patents [OSTI]

    O'Connor, William K.; Turner, Paul C.; Addison, Gerald W.

    2002-12-24

    A method of processing spent aluminum pot liner containing carbon, cyanide compositions, fluorides and inorganic oxides. The spent aluminum pot liner is crushed iron oxide is added to form an agglomerated material. The agglomerated material is melted in an electric arc furnace having the electrodes submerged in the molten material to provide a reducing environment during the furnace operation. In the reducing environment, pot liner is oxidized while the iron oxides are reduced to produce iron and a slag substantially free of cyanide compositions and fluorides. An off-gas including carbon oxides and fluorine is treated in an air pollution control system with an afterburner and a scrubber to produce NaF, water and a gas vented to the atmosphere free of cyanide compositions, fluorine and CO.

  14. Apparatus and method for sealing perforated well casing

    DOE Patents [OSTI]

    Blount, C.G.; Benham, R.A.; Brock, J.L.; Emerson, J.A.; Ferguson, K.R.; Scheve, D.F.; Schmidt, J.H.; Schuler, K.W.; Stanton, P.L.

    1997-03-25

    Perforations and other openings in well casings, liners and other conduits may be substantially blocked or sealed to prevent fluid flow between the casing or liner interior and an earth formation by placing a radially expansible sleeve adjacent the perforations or openings and urging the sleeve into forcible engagement with the casing or inner wall using an explosive charge. An apparatus including a radially contracted sleeve formed by a coiled plate member or a tubular member having flutes defined by external and internal folds, may be deployed into a well casing or liner through a production or injection tubing string and on the end of a flexible cable or coilable tubing. An explosive charge disposed on the apparatus and within the sleeve may be detonated to urge the sleeve into forcible engagement with the casing inner wall. 17 figs.

  15. Apparatus and method for sealing perforated well casing

    DOE Patents [OSTI]

    Blount, Curtis G.; Benham, Robert A.; Brock, Jerry L.; Emerson, John A.; Ferguson, Keith R.; Scheve, Donald F.; Schmidt, Joseph H.; Schuler, Karl W.; Stanton, Philip L.

    1997-01-01

    Perforations and other openings in well casings, liners and other conduits may be substantially blocked or sealed to prevent fluid flow between the casing or liner interior and an earth formation by placing a radially expansible sleeve adjacent the perforations or openings and urging the sleeve into forcible engagement with the casing or inner wall using an explosive charge. An apparatus including a radially contracted sleeve formed by a coiled plate member or a tubular member having flutes defined by external and internal folds, may be deployed into a well casing or liner through a production or injection tubing string and on the end of a flexible cable or coilable tubing. An explosive charge disposed on the apparatus and within the sleeve may be detonated to urge the sleeve into forcible engagement with the casing inner wall.

  16. Apparatus for controlling coolant level in a liquid-metal-cooled nuclear reactor

    DOE Patents [OSTI]

    Jones, Robert D.

    1978-01-01

    A liquid-metal-cooled fast-breeder reactor which has a thermal liner spaced inwardly of the pressure vessel and includes means for passing bypass coolant through the annulus between the thermal liner and the pressure vessel to insulate the pressure vessel from hot outlet coolant includes control ports in the thermal liner a short distance below the normal operating coolant level in the reactor and an overflow nozzle in the pressure vessel below the control ports connected to an overflow line including a portion at an elevation such that overflow coolant flow is established when the coolant level in the reactor is above the top of the coolant ports. When no makeup coolant is added, bypass flow is inwardly through the control ports and there is no overflow; when makeup coolant is being added, coolant flow through the overflow line will maintain the coolant level.

  17. Methods of use of calcium hexa aluminate refractory linings and/or chemical barriers in high alkali or alkaline environments

    DOE Patents [OSTI]

    McGowan, Kenneth A; Cullen, Robert M; Keiser, James R; Hemrick, James G; Meisner, Roberta A

    2013-10-22

    A method for improving the insulating character/and or penetration resistance of a liner in contact with at least one of an alkali and/or alkaline environments is provided. The method comprises lining a surface that is subject to wear by an alkali environment and/or an alkaline environment with a refractory composition comprising a refractory aggregate consisting essentially of a calcium hexa aluminate clinker having the formula CA.sub.6, wherein C is equal to calcium oxide, wherein A is equal to aluminum oxide, and wherein the hexa aluminate clinker has from zero to less than about fifty weight percent C.sub.12A.sub.7, and wherein greater than 98 weight percent of the calcium hexa aluminate clinker having a particle size ranging from -20 microns to +3 millimeters, for forming a liner of the surface. This method improves the insulating character/and or penetration resistance of the liner.

  18. Tokamak with in situ magnetohydrodynamic generation of toroidal magnetic field

    DOE Patents [OSTI]

    Schaffer, Michael J.

    1986-01-01

    A tokamak apparatus includes an electrically conductive metal pressure vessel for defining a chamber and confining liquid therein. A liner disposed within said chamber defines a toroidal space within the liner and confines gas therein. The metal vessel provides an electrically conductive path linking the toroidal space. Liquid metal is forced outwardly through the chamber outside of the toroidal space to generate electric current in the conductive path and thereby generate a toroidal magnetic field within the toroidal space. Toroidal plasma is developed within the toroidal space about the major axis thereof.

  19. Generator modification and characterization of the Ranchero explosive generator

    SciTech Connect (OSTI)

    Oona, Henn; Goforth, James H; Tasker, Douglas G

    2008-01-01

    Magnetic Flux Compression Generators (FCG) have been used as a power source for plasma and metal liner implosions over several decades. We have used the cost effective Ranchero generator to study hydrodynamic effects and instability growth in aluminium liners. Sometimes it is useful to tailor the shape of the current and voltage pulse. Modifications to the geometry can facilitate this task. Changes in the geometrical features of the generator can be used to allow the desired current waveform to be delivered to the load region.

  20. Pressure enhanced penetration with shaped charge perforators

    DOE Patents [OSTI]

    Glenn, Lewis A.

    2001-01-01

    A downhole tool, adapted to retain a shaped charge surrounded by a superatmospherically pressurized light gas, is employed in a method for perforating a casing and penetrating reservoir rock around a wellbore. Penetration of a shaped charge jet can be enhanced by at least 40% by imploding a liner in the high pressure, light gas atmosphere. The gas pressure helps confine the jet on the axis of penetration in the latter stages of formation. The light gas, such as helium or hydrogen, is employed to keep the gas density low enough so as not to inhibit liner collapse.

  1. Coolant mass flow equalizer for nuclear fuel

    DOE Patents [OSTI]

    Betten, Paul R.

    1978-01-01

    The coolant mass flow distribution in a liquid metal cooled reactor is enhanced by restricting flow in sub-channels defined in part by the peripheral fuel elements of a fuel assembly. This flow restriction, which results in more coolant flow in interior sub-channels, is achieved through the use of a corrugated liner positioned between the bundle of fuel elements and the inner wall of the fuel assembly coolant duct. The corrugated liner is expandable to accommodate irradiation induced growth of fuel assembly components.

  2. Source terms released into the environment for a station blackout severe accident at the Peach Bottom Atomic Power Station

    SciTech Connect (OSTI)

    Carbajo, J.J.

    1995-07-01

    This study calculates source terms released into the environment at the Peach Bottom Atomic Power Station after containment failure during a postulated low-pressure, short-term station blackout severe accident. The severe accident analysis code MELCOR, version 1.8.1, was used in these calculations. Source terms were calculated for three different containment failure modes. The largest environmental releases occur for early containment failure at the drywell liner in contact with the cavity by liner melt-through. This containment failure mode is very likely to occur when the cavity is dry during this postulated severe accident sequence.

  3. ALT-3 Target & CMU Version 4

    SciTech Connect (OSTI)

    Griego, Jeffrey R; Atchison, Walter L.; Holtkamp, David; Oro, David M.; Reinovsky, Robert E.; Rousculp, Christopher L.; Tabaka, Leonard J.

    2012-06-11

    The third Advance Liner Technology (ALT-3) experiment is the next in a long tradition of collaborations between LANL and RFNC/VNIIEF in high-explosive pulsed-power. Here a VNIIEF provided Disk Explosive Magnetic Generator (DEMG) will drive a LANL provided experimental load and diagnostic package. The objective of the experiment is to explore the use of a cylindrical liner-ontarget in tera-Pascal equation of state measurement. This presentation will discuss version 4 of the experimental target and central measuring unit (CMU) along with R & D already performed in fabrication of the target.

  4. Method of making a sodium sulfur battery

    DOE Patents [OSTI]

    Elkins, P. E.

    1981-09-22

    A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another. 3 figs.

  5. Method of making a sodium sulfur battery

    DOE Patents [OSTI]

    Elkins, Perry E.

    1981-01-01

    A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another.

  6. Polyolefin nanocomposites

    DOE Patents [OSTI]

    Chaiko, David J.

    2007-01-02

    The present invention relates to methods for the preparation of clay/polymer nanocomposites. The methods include combining an organophilic clay and a polymer to form a nanocomposite, wherein the organophilic clay and the polymer each have a peak recrystallization temperature, and wherein the organophilic clay peak recrystallization temperature sufficiently matches the polymer peak recrystallization temperature such that the nanocomposite formed has less permeability to a gas than the polymer. Such nanocomposites exhibit 2, 5, 10, or even 100 fold or greater reductions in permeability to, e.g., oxygen, carbon dioxide, or both compared to the polymer. The invention also provides a method of preparing a nanocomposite that includes combining an amorphous organophilic clay and an amorphous polymer, each having a glass transition temperature, wherein the organophilic clay glass transition temperature sufficiently matches the polymer glass transition temperature such that the nanocomposite formed has less permeability to a gas than the polymer.

  7. Carbons for lithium batteries prepared using sepiolite as an inorganic template

    DOE Patents [OSTI]

    Sandi, Giselle (Wheaton, IL); Winans, Randall E. (Downers Grove, IL); Gregar, K. Carrado (Naperville, IL)

    2000-01-01

    A method of preparing an anode material using sepiolite clay having channel-like interstices in its lattice structure. Carbonaceous material is deposited in the channel-like interstices of the sepiolite clay and then the sepiolite clay is removed leaving the carbonaceous material. The carbonaceous material is formed into an anode. The anode is combined with suitable cathode and electrolyte materials to form a battery of the lithium-ion type.

  8. Detroit Street Lighting Report | Department of Energy

    Energy Savers [EERE]

    Energy Cooperation and Non-Proliferation | Department of Energy Clay Sell Touts Georgian Efforts to Advance Regional Energy Cooperation and Non-Proliferation Deputy Secretary Clay Sell Touts Georgian Efforts to Advance Regional Energy Cooperation and Non-Proliferation March 16, 2007 - 10:55am Addthis Visits National Nuclear Waste Repository in Mtskheta, Georgia TBILISI, Georgia - U.S. Deputy Secretary of Energy Clay Sell today visited the National Radioactive Waste Repository in Mtskheta,

  9. Property:CapRockLithology | Open Energy Information

    Open Energy Info (EERE)

    + Hydrothermal alteration layer + Bouillante Geothermal Area + Illite-Smectite Clay + Brady Hot Springs Geothermal Area + Hydrothermally altered volcanics + C Cerro Prieto...

  10. Coupled hydro-mechanical processes in crytalline rock and inindurateda...

    Office of Scientific and Technical Information (OSTI)

    rock and ininduratedand plastic clays: A comparative discussion Citation Details In-Document Search Title: Coupled hydro-mechanical processes in crytalline rock and ...

  11. Moeck-Beardsmore Play Types | Open Energy Information

    Open Energy Info (EERE)

    Magmatic-hydrothermal Circulation --- Extensive Low Permeability Clay-rich Layers Java CV-1b: Intrusive Magmatic Arcs, Mid Oceanic Ridges, Hot Spots Active Volcanism, Shallow...

  12. Evidence for immunoglobulin Fc receptor-mediated prostaglandin2...

    Office of Scientific and Technical Information (OSTI)

    Authors: Neuwirth, R. ; Singhal, P. ; Diamond, B. ; Hays, R.M. ; Lobmeyer, L. ; Clay, K. ; ... Language: English Subject: 59 BASIC BIOLOGICAL SCIENCES; BLOOD COAGULATION FACTORS; ...

  13. Los Alamos National Laboratory The

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Highly accurate 3D computing is a critical part of this journey, but not its destination. Clay Dillingham Norris Bradbury, who became the Laboratory's second director, stands ...

  14. Independent Data Validation of an in Vitro Method for the Prediction...

    Office of Scientific and Technical Information (OSTI)

    Authors: Bradham, Karen D. ; Nelson, Clay ; Juhasz, Albert L. ; Smith, Euan ; Scheckel, Kirk ; Obenour, Daniel R. ; Miller, Bradley W. ; Thomas, David J. 1 ; NCSU) 2 ; EPA) 2 ...

  15. Letter report to Pete Sanders, DOE:

    Office of Legacy Management (LM)

    from the Rulison Underground Nuclear Test prepared by Clay Cooper Division of ... The hydraulically fractured, perforated interval at the nuclear test horizon is assumed to ...

  16. Update On Geothermal Exploration At Fort Bidwell, Surprise Valley...

    Open Energy Info (EERE)

    awaits clean-out and testing activities. Authors Joe LaFleur, Anna Carter, Karen Moore, Ben Barker, Paul Atkinson, Clay Jones, Joseph Moore and Bernold Pollard Published...

  17. Petrography Analysis At Raft River Geothermal Area (2011) | Open...

    Open Energy Info (EERE)

    flows, tuffaceous siltstone, greywacke, and sandstone. References Clay Jones, Joseph Moore, William Teplow, Seth Craig (2011) Geology and Hydrothermal Alteration of the Raft...

  18. Thermal Gradient Holes At Fort Bidwell Area (Lafleur, Et Al....

    Open Energy Info (EERE)

    continue exploration when funding allows." References Joe LaFleur, Anna Carter, Karen Moore, Ben Barker, Paul Atkinson, Clay Jones, Joseph Moore, Bernold Pollard (2010) Update On...

  19. Memorandum To: United States Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The following individuals were present: * Judith Greenwald, DOE * Jenah Zweig, DOE * John Cymbalsky, DOE * Eric Stas, DOE * Johanna Jochum, DOE * Kathryn Clay, AGA * Robin Roy, ...

  20. Model Evaluation of the Thermo-Hydrological Response in Argillaceous...

    Office of Scientific and Technical Information (OSTI)

    of Publication: United States Language: English Subject: 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS Dual-purpose canister, dispoal, clay Word Cloud More Like This Full Text...

  1. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Clay ; Ramanathan, Kannan November 2015 , IEEE Microphotonic Spectrum-Splitting and ... of Electrical and Electronics Engineers (IEEE) Spatially Resolved Chemical and ...

  2. DOE-STD-1090-2004; Hoisting and Rigging (Formerly Hoisting and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Brick, common Cement, Portland (packed) Cement, Portland (loose) Cement, slag (packed) Cement, slag (loose) Chalk Charcoal Cinder concrete Clay, ordinary Coal, hard, solid ...

  3. New hydrogen-isotope measurements refine the picture of water on Mars

    SciTech Connect (OSTI)

    Wilson, R. Mark

    2015-05-15

    Atmospheric maps and in situ spectrometry of clay minerals constrain climate models and the prevalence of water in the planet’s ancient past.

  4. Microsoft Word - FFATA Memo 30 March 2007.doc

    Broader source: Energy.gov (indexed) [DOE]

    MEMORANDUM FOR THE PRESIDENT'S MANAGEMENT COUNCIL From: Clay Johnson Deputy Director for Management Subject: Reporting of Data Elements Required by the Federal Funding...

  5. Agassiz Beach Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Scale Wind Facility Status In Service Owner NAEEnel North America Developer Northern Alternative Energy Energy Purchaser Xcel Energy Location Clay County MN Coordinates...

  6. Microsoft Word - LBNL-55113 Xu, T.doc

    Office of Scientific and Technical Information (OSTI)

    manipulations considered here include pH modification and dilution with fresh water. ... the injection water chemistry can enhance mineral dissolution and reduce clay swelling. ...

  7. 3.27 Why Dinosaurs Are Extinct

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Walter Alvarez discovered a layer of red clay between fossil- containing limestone deposits in Italy. His father, Nobel laureate Luis Alvarez, suggested how to analyze it. ...

  8. Modeling Fluid Flow in Natural Systems, Model Validation and...

    Energy Savers [EERE]

    Modeling Fluid Flow in Natural Systems, Model Validation and Demonstration Modeling Fluid Flow in Natural Systems, Model Validation and Demonstration Clay and granitic units are ...

  9. Bi-Con Services Inc | Open Energy Information

    Open Energy Info (EERE)

    Services Inc Jump to: navigation, search Name: Bi-Con Services Inc Address: 10901 Clay Pike Road Place: Derwent, Ohio Zip: 43733 Sector: Buildings, Efficiency, Services Product:...

  10. Tax Credits, Rebates & Savings | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electric Cooperative, Inc- Energy Conservation Loans Clay Electric Cooperative (CEC), a Touchstone Energy Cooperative, covers 14 North Florida counties, including Gainesville,...

  11. Controls on Fault-Hosted Fluid Flow: Preliminary Results from...

    Open Energy Info (EERE)

    Flow: Preliminary Results from the Coso Geothermal Field, CA Abstract cap rock, permeability, fault, fracture, clay, Coso Authors Davatzes, N.C.; Hickman and S.H. Published...

  12. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Filter Results Filter by Subject engineering (11) design ... In clay and deep borehole media, the peak temperature is ... simplified by eliminating water rods and partial length ...

  13. Los Alamos, Sandia National labs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    taught by Carrie Quade, Squlptures' president and artist, who had developed a unique method of using pigmented clay to produce monoprints. Sandia's Materials Characterization...

  14. Microsoft Word - LLNL 2011 SA_8_1.docx

    National Nuclear Security Administration (NNSA)

    ... any known aggregate, clay, coal, or mineral resources. ... sites, including the Waste Isolation Pilot Plant (WIPP). ... from boilers (natural gas fired), internal combustion ...

  15. Microsoft Word - PhycalAlgaePilotProject_NEPAFinalEA_October2011...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... of dirt, when windy or dry conditions promote problematic fugitive dust emissions. ... refining plant flue gas using in-duct scrubber, then coupled with alkaline clay ...

  16. ch1_General_Info

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... of dirt, when windy or dry conditions promote problematic fugitive dust emissions. ... refining plant flue gas using in-duct scrubber, then coupled with alkaline clay ...

  17. Sectoral combustor for burning low-BTU fuel gas

    DOE Patents [OSTI]

    Vogt, Robert L.

    1980-01-01

    A high-temperature combustor for burning low-BTU coal gas in a gas turbine is disclosed. The combustor includes several separately removable combustion chambers each having an annular sectoral cross section and a double-walled construction permitting separation of stresses due to pressure forces and stresses due to thermal effects. Arrangements are described for air-cooling each combustion chamber using countercurrent convective cooling flow between an outer shell wall and an inner liner wall and using film cooling flow through liner panel grooves and along the inner liner wall surface, and for admitting all coolant flow to the gas path within the inner liner wall. Also described are systems for supplying coal gas, combustion air, and dilution air to the combustion zone, and a liquid fuel nozzle for use during low-load operation. The disclosed combustor is fully air-cooled, requires no transition section to interface with a turbine nozzle, and is operable at firing temperatures of up to 3000.degree. F. or within approximately 300.degree. F. of the adiabatic stoichiometric limit of the coal gas used as fuel.

  18. Issues Impacting Refractory Service Life in Biomass/Waste Gasification

    SciTech Connect (OSTI)

    Bennett, J.P.; Kwong, K.-S.; Powell, C.A.

    2007-03-01

    Different carbon sources are used, or are being considered, as feedstock for gasifiers; including natural gas, coal, petroleum coke, and biomass. Biomass has been used with limited success because of issues such as ash impurity interactions with the refractory liner, which will be discussed in this paper.

  19. CX-100540 Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Low Cost Hydrogen Storage at 875 bar by using steel liner and steel wire wrap Award Number: DE-EE0006668 CX(s) Applied: A9, B3.6 Fuel Cells Technology Office Date: 07/29/2014 Location(s): VA Office(s): Golden Field Office

  20. HTGR Gas Turbine Program. Semiannual progress report for the period ending September 30, 1979

    SciTech Connect (OSTI)

    Not Available

    1980-05-01

    Information on the HTGR-GT program is presented concerning systems design methods; systems dynamics methods; alternate design; miscellaneous controls and auxiliary systems; structural mechanics; shielding analysis; licensing; safety; availability; reactor turbine system integration with plant; PCRV liners, penetrations, and closures; PCRV structures; thermal barrier; reactor internals; turbomachinery; turbomachine remote maintenance; control valve; heat exchangers; plant protection system; and plant control system.

  1. RussiaLANLV3-web.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    B-dot (6 probes* 60) TL2-1...TL2-6 B-dot (6 probes* 60) TL3-1...TL3-6 PU CMU Liner Modified for the Web multi-year effort planned in eight phases continuing into FY09 ...

  2. Serial cooling of a combustor for a gas turbine engine

    DOE Patents [OSTI]

    Abreu, Mario E.; Kielczyk, Janusz J.

    2001-01-01

    A combustor for a gas turbine engine uses compressed air to cool a combustor liner and uses at least a portion of the same compressed air for combustion air. A flow diverting mechanism regulates compressed air flow entering a combustion air plenum feeding combustion air to a plurality of fuel nozzles. The flow diverting mechanism adjusts combustion air according to engine loading.

  3. Development of a model for predicting transient hydrogen venting in 55-gallon drums

    SciTech Connect (OSTI)

    Apperson, Jason W; Clemmons, James S; Garcia, Michael D; Sur, John C; Zhang, Duan Z; Romero, Michael J

    2008-01-01

    Remote drum venting was performed on a population of unvented high activity drums (HAD) in the range of 63 to 435 plutonium equivalent Curies (PEC). These 55-gallon Transuranic (TRU) drums will eventually be shipped to the Waste Isolation Pilot Plant (WIPP). As a part of this process, the development of a calculational model was required to predict the transient hydrogen concentration response of the head space and polyethylene liner (if present) within the 55-gallon drum. The drum and liner were vented using a Remote Drum Venting System (RDVS) that provided a vent sampling path for measuring flammable hydrogen vapor concentrations and allow hydrogen to diffuse below lower flammability limit (LFL) concentrations. One key application of the model was to determine the transient behavior of hydrogen in the head space, within the liner, and the sensitivity to the number of holes made in the liner or number of filters. First-order differential mass transport equations were solved using Laplace transformations and numerically to verify the results. the Mathematica 6.0 computing tool was also used as a validation tool and for examining larger than two chamber systems. Results will be shown for a variety of configurations, including 85-gallon and 110-gallon overpack drums. The model was also validated against hydrogen vapor concentration assay measurements.

  4. Disc valve for sampling erosive process streams

    DOE Patents [OSTI]

    Mrochek, J.E.; Dinsmore, S.R.; Chandler, E.W.

    1984-08-16

    This is a patent for a disc-type, four-port sampling valve for service with erosive high temperature process streams. Inserts and liners of ..cap alpha..-silicon carbide respectively, in the faceplates and in the sampling cavities, limit erosion while providing lubricity for a smooth and precise operation. 1 fig.

  5. Lightweight bladder lined pressure vessels

    DOE Patents [OSTI]

    Mitlitsky, F.; Myers, B.; Magnotta, F.

    1998-08-25

    A lightweight, low permeability liner is described for graphite epoxy composite compressed gas storage vessels. The liner is composed of polymers that may or may not be coated with a thin layer of a low permeability material, such as silver, gold, or aluminum, deposited on a thin polymeric layer or substrate which is formed into a closed bladder using tori spherical or near tori spherical end caps, with or without bosses therein, about which a high strength to weight material, such as graphite epoxy composite shell, is formed to withstand the storage pressure forces. The polymeric substrate may be laminated on one or both sides with additional layers of polymeric film. The liner may be formed to a desired configuration using a dissolvable mandrel or by inflation techniques and the edges of the film sealed by heat sealing. The liner may be utilized in most any type of gas storage system, and is particularly applicable for hydrogen, gas mixtures, and oxygen used for vehicles, fuel cells or regenerative fuel cell applications, high altitude solar powered aircraft, hybrid energy storage/propulsion systems, and lunar/Mars space applications, and other applications requiring high cycle life. 19 figs.

  6. Method for forming a bladder for fluid storage vessels

    DOE Patents [OSTI]

    Mitlitsky, Fred; Myers, Blake; Magnotta, Frank

    2000-01-01

    A lightweight, low permeability liner for graphite epoxy composite compressed gas storage vessels. The liner is composed of polymers that may or may not be coated with a thin layer of a low permeability material, such as silver, gold, or aluminum, deposited on a thin polymeric layer or substrate which is formed into a closed bladder using torispherical or near torispherical end caps, with or without bosses therein, about which a high strength to weight material, such as graphite epoxy composite shell, is formed to withstand the storage pressure forces. The polymeric substrate may be laminated on one or both sides with additional layers of polymeric film. The liner may be formed to a desired configuration using a dissolvable mandrel or by inflation techniques and the edges of the film seamed by heat sealing. The liner may be utilized in most any type of gas storage system, and is particularly applicable for hydrogen, gas mixtures, and oxygen used for vehicles, fuel cells or regenerative fuel cell applications, high altitude solar powered aircraft, hybrid energy storage/propulsion systems, and lunar/Mars space applications, and other applications requiring high cycle life.

  7. Lightweight bladder lined pressure vessels

    DOE Patents [OSTI]

    Mitlitsky, Fred; Myers, Blake; Magnotta, Frank

    1998-01-01

    A lightweight, low permeability liner for graphite epoxy composite compressed gas storage vessels. The liner is composed of polymers that may or may not be coated with a thin layer of a low permeability material, such as silver, gold, or aluminum, deposited on a thin polymeric layer or substrate which is formed into a closed bladder using torispherical or near torispherical end caps, with or without bosses therein, about which a high strength to weight material, such as graphite epoxy composite shell, is formed to withstand the storage pressure forces. The polymeric substrate may be laminated on one or both sides with additional layers of polymeric film. The liner may be formed to a desired configuration using a dissolvable mandrel or by inflation techniques and the edges of the film seamed by heat sealing. The liner may be utilized in most any type of gas storage system, and is particularly applicable for hydrogen, gas mixtures, and oxygen used for vehicles, fuel cells or regenerative fuel cell applications, high altitude solar powered aircraft, hybrid energy storage/propulsion systems, and lunar/Mars space applications, and other applications requiring high cycle life.

  8. Rapid-quench axially staged combustor

    DOE Patents [OSTI]

    Feitelberg, Alan S.; Schmidt, Mark Christopher; Goebel, Steven George

    1999-01-01

    A combustor cooperating with a compressor in driving a gas turbine includes a cylindrical outer combustor casing. A combustion liner, having an upstream rich section, a quench section and a downstream lean section, is disposed within the outer combustor casing defining a combustion chamber having at least a core quench region and an outer quench region. A first plurality of quench holes are disposed within the liner at the quench section having a first diameter to provide cooling jet penetration to the core region of the quench section of the combustion chamber. A second plurality of quench holes are disposed within the liner at the quench section having a second diameter to provide cooling jet penetration to the outer region of the quench section of the combustion chamber. In an alternative embodiment, the combustion chamber quench section further includes at least one middle region and at least a third plurality of quench holes disposed within the liner at the quench section having a third diameter to provide cooling jet penetration to at least one middle region of the quench section of the combustion chamber.

  9. MSG MONTICELLO PROJECTS FEDERAL FACILITY AGREEMENT REPORT

    Office of Legacy Management (LM)

    ... ViBiblt Piping Visible Liner Lifo S*vor Station Bvidoli.C<) of erosion of: Top ofl'ond 4 ... FRX:4355872780 1.gs l'"' ND* IJO . : ,. . ** JO f)D" ND ID: SM STOLLER PRGE:003 R95%

  10. MSG MONTICELLO PROJECTS FEDERAL FACILITY AGREEMENT REPORT March...

    Office of Legacy Management (LM)

    ... macroinvertebrate samples l'tojected iiID,ill.l es1lb:i@ o6IB41Q5 d6Z7"2.8p5 ... Condition of: Fence Roads Signs Visible Piping Visible Liner Lire Saver Station Evidence ...

  11. OFF A

    Office of Legacy Management (LM)

    ... a n g e m e n t s x i t h t h e Ato1ni.c Energy Corrmission, f u r n i s h e d t h e p e ... Milled up 5-12" liner from 5874' to 6517'. Ran Sperry-Sun Multi- Shot Log in interval ...

  12. A sensitivity analysis of hazardous waste disposal site climatic and soil design parameters using HELP3

    SciTech Connect (OSTI)

    Adelman, D.D.; Stansbury, J.

    1997-12-31

    The Resource Conservation and Recovery Act (RCRA) Subtitle C, Comprehensive Environmental Response, Compensation, And Liability Act (CERCLA), and subsequent amendments have formed a comprehensive framework to deal with hazardous wastes on the national level. Key to this waste management is guidance on design (e.g., cover and bottom leachate control systems) of hazardous waste landfills. The objective of this research was to investigate the sensitivity of leachate volume at hazardous waste disposal sites to climatic, soil cover, and vegetative cover (Leaf Area Index) conditions. The computer model HELP3 which has the capability to simulate double bottom liner systems as called for in hazardous waste disposal sites was used in the analysis. HELP3 was used to model 54 combinations of climatic conditions, disposal site soil surface curve numbers, and leaf area index values to investigate how sensitive disposal site leachate volume was to these three variables. Results showed that leachate volume from the bottom double liner system was not sensitive to these parameters. However, the cover liner system leachate volume was quite sensitive to climatic conditions and less sensitive to Leaf Area Index and curve number values. Since humid locations had considerably more cover liner system leachate volume than and locations, different design standards may be appropriate for humid conditions than for and conditions.

  13. PHELIX for flux compression studies

    SciTech Connect (OSTI)

    Turchi, Peter J; Rousculp, Christopher L; Reinovsky, Robert E; Reass, William A; Griego, Jeffrey R; Oro, David M; Merrill, Frank E

    2010-06-28

    PHELIX (Precision High Energy-density Liner Implosion eXperiment) is a concept for studying electromagnetic implosions using proton radiography. This approach requires a portable pulsed power and liner implosion apparatus that can be operated in conjunction with an 800 MeV proton beam at the Los Alamos Neutron Science Center. The high resolution (< 100 micron) provided by proton radiography combined with similar precision of liner implosions driven electromagnetically can permit close comparisons of multi-frame experimental data and numerical simulations within a single dynamic event. To achieve a portable implosion system for use at high energy-density in a proton laboratory area requires sub-megajoule energies applied to implosions only a few cms in radial and axial dimension. The associated inductance changes are therefore relatively modest, so a current step-up transformer arrangement is employed to avoid excessive loss to parasitic inductances that are relatively large for low-energy banks comprising only several capacitors and switches. We describe the design, construction and operation of the PHELIX system and discuss application to liner-driven, magnetic flux compression experiments. For the latter, the ability of strong magnetic fields to deflect the proton beam may offer a novel technique for measurement of field distributions near perturbed surfaces.

  14. Method of fabricating a prestressed cast iron vessel

    DOE Patents [OSTI]

    Lampe, Robert F.

    1982-01-01

    A method of fabricating a prestressed cast iron vessel wherein double wall cast iron body segments each have an arcuate inner wall and a spaced apart substantially parallel outer wall with a plurality of radially extending webs interconnecting the inner wall and the outer wall, the bottom surface and the two exposed radial side surfaces of each body segment are machined and eight body segments are formed into a ring. The top surfaces and outer surfaces of the outer walls are machined and keyways are provided across the juncture of adjacent end walls of the body segments. A liner segment complementary in shape to a selected inner wall of one of the body segments is mounted to each of the body segments and again formed into a ring. The liner segments of each ring are welded to form unitary liner rings and thereafter the cast iron body segments are prestressed to complete the ring assembly. Ring assemblies are stacked to form the vessel and adjacent unitary liner rings are welded. A top head covers the top ring assembly to close the vessel and axially extending tendons retain the top and bottom heads in place under pressure.

  15. Intense Magnetized Plasma-Wall Interaction

    SciTech Connect (OSTI)

    Bauer, Bruno S.; Fuelling, Stephan

    2013-11-30

    This research project studied wall-plasma interactions relevant to fusion science. Such interactions are a critical aspect of Magneto-Inertial Fusion (MIF) because flux compression by a pusher material, in particular the metal for the liner approach to MIF, involves strong eddy current heating on the surface of the pusher, and probably interactions and mixing of the pusher with the interior fuel during the time when fusion fuel is being burned. When the pusher material is a metal liner, high-energy-density conditions result in fascinating behavior. For example, "warm dense matter" is produced, for which material properties such as resistivity and opacity are not well known. In this project, the transformation into plasma of metal walls subjected to pulsed megagauss magnetic fields was studied with an experiment driven by the UNR 1 MA Zebra generator. The experiment was numerically simulated with using the MHRDR code. This simple, fundamental high-energy-density physics experiment, in a regime appropriate to MIF, has stimulated an important and fascinating comparison of numerical modeling codes and tables with experiment. In addition, we participated in developing the FRCHX experiment to compress a field-reversed-configuration (FRC) plasma with a liner, in collaboration with researchers from Air Force Research Laboratory and Los Alamos National Lab, and we helped develop diagnostics for the Plasma Liner Experiment (PLX) at LANL. Last, but not least, this project served to train students in high-energy-density physics.

  16. CX-003826: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Project 1712 Repair OF002 Cured-in-Place Pipe Liner Near AICO InletCX(s) Applied: B6.1Date: 09/02/2010Location(s): KansasOffice(s): Kansas City Site Office, NNSA-Headquarters

  17. Permit application modifications

    SciTech Connect (OSTI)

    1995-11-01

    This document contains the Permit Application Modifications for the Y-12 Industrial Landfill V site on the Oak Ridge Reservation. These modifications include the assessment of stability of the proposed Landfill V under static and loading conditions. Analyses performed include the general slope stability, veneer stability of the bottom liner and cover system, and a liquefaction potential assessment of the foundation soils.

  18. Investigation of Radiation and Chemical Resistance of Flexible HLW Transfer Hose

    SciTech Connect (OSTI)

    E. Skidmore; Billings, K.; Hubbard, M.

    2010-03-24

    A chemical transfer hose constructed of an EPDM (ethylene-propylene diene monomer) outer covering with a modified cross-linked polyethylene (XLPE) lining was evaluated for use in high level radioactive waste transfer applications. Laboratory analysis involved characterization of the hose liner after irradiation to doses of 50 to 300 Mrad and subsequent exposure to 25% NaOH solution at 93 C for 30 days, simulating 6 months intermittent service. The XLPE liner mechanical and structural properties were characterized at varying dose levels. Burst testing of irradiated hose assemblies was also performed. Literature review and test results suggest that radiation effects below doses of 100 kGy are minimal, with acceptable property changes to 500 kGy. Higher doses may be feasible. At a bounding dose of 2.5 MGy, the burst pressure is reduced to the working pressure (1.38 MPa) at room temperature. Radiation exposure slightly reduces liner tensile strength, with more significant decrease in liner elongation. Subsequent exposure to caustic solutions at elevated temperature slightly increases elongation, suggesting an immersion/hydrolytic effect or possible thermal annealing of radiation damage. This paper summarizes the laboratory results and recommendations for field deployment.

  19. Investigation and evaluation of geopressured-geothermal wells. Final report, Tenneco Fee N No. 1 Well Terrebonne Paris, Louisiana

    SciTech Connect (OSTI)

    Dobson, R.J.; Hartsock, J.H.; McCoy, R.L.; Rodgers, J.A.

    1980-09-01

    The reservoir conditions that led to the choice of this well as the fifth well of opportunity are described as well as the attempts to complete the well for high-volume brine production. Individual opinions concerning underlying and conributing causes for the liner failure which aborted the completion attempt are included. (MHR)

  20. Optically initiated silicon carbide high voltage switch

    DOE Patents [OSTI]

    Caporaso, George J.; Sampayan, Stephen E.; Sullivan, James S.; Sanders; David M.

    2011-02-22

    An improved photoconductive switch having a SiC or other wide band gap substrate material, such as GaAs and field-grading liners composed of preferably SiN formed on the substrate adjacent the electrode perimeters or adjacent the substrate perimeters for grading the electric fields.

  1. Optically-initiated silicon carbide high voltage switch

    DOE Patents [OSTI]

    Caporaso, George J.; Sampayan, Stephen E.; Sullivan, James S.; Sanders, David M.

    2012-02-28

    An improved photoconductive switch having a SIC or other wide band gap substrate material, such as GaAs and field-grading liners composed of preferably SiN formed on the substrate adjacent the electrode perimeters or adjacent the substrate perimeters for grading the electric fields.

  2. Spent fuel dry storage technology development: fuel temperature measurements under imposed dry storage conditions (I kW PWR spent fuel assembly)

    SciTech Connect (OSTI)

    Unterzuber, R.; Wright, J.B.

    1980-09-01

    A spent fuel assembly temperature test under imposed dry storage conditions was conducted at the Engine Maintenance Assembly and Disassembly (E-MAD) facility on the Nevada Test Site in support of spent fuel dry storage technology development. This document presents the test data and results obtained from an approximately 1.0 kW decay heat level PWR spent fuel assembly. A spent fuel test apparatus was designed to utilize a representative stainless steel spent fuel canister, a canister lid containing internal temperature instrumentation to measure fuel cladding temperatures, and a carbon steel liner that encloses the canister and lid. Electrical heaters along the liner length, on the lid, and below the canister are used to impose dry storage canister temperature profiles. Temperature instrumentation is provided on the liner and canister. The liner and canister are supported by a test stand in one of the large hot cells (West Process Cell) inside E-MAD. Fuel temperature measurements have been performed using imposed canister temperature profiles from the electrically heated and spent fuel drywell tests being conducted at E-MAD as well as for four constant canister temperature profiles, each with a vacuum, helium and air backfill. Computer models have been utilized in conjunction with the test to predict the thermal response of the fuel cladding. Computer predictions are presented, and they show good agreement with the test data.

  3. Spent fuel dry storage technology development: fuel temperature measurements under imposed dry storage conditions (1.4 kW PWR spent fuel assembly)

    SciTech Connect (OSTI)

    Unterzuber, R.

    1981-09-01

    A spent fuel assembly temperature test under imposed dry storage conditions was conducted at the Engine Maintenance Assembly and Disassembly (E-MAD) facility on the Nevada Test Site in support of spent fuel dry storage technology development. This document presents the test data and results obtained from an approximately 1.4 kW decay heat level PWR spent fuel assembly. A spent fuel test apparatus was designed to utilize a stainless steel canister representative of actual fuel canisters, a canister lid containing internal temperature instrumentation to measure fuel cladding temperatures, and a carbon steel liner that encloses the canister and lid. Electrical heaters along the liner length, on the lid, and below the canister are used to impose dry storage canister temperature profiles. Temperature instrumentation is provided on the liner and canister. The liner and canister are supported by a test stand in one of the large hot cells (West Process Cell) inside E-MAD. Fuel temperature measurements have been performed using imposed canister temperature profiles from the electrically heated and spent fuel near-surface drywell tests being conducted at E-MAD, the spent fuel deep geologic storage test being conducted in Climax granite on the Nevada Test Site, and for five constant canister temperature profiles, each with a vacuum, helium and air backfill. Computer models have been utilized in conjunction with the test to predict the thermal response of the fuel cladding. Computer predictions are presented, and they show good agreement with the test data.

  4. Surface decontamination compositions and methods

    DOE Patents [OSTI]

    Wright; Karen E.; Cooper, David C.; Peterman, Dean R.; Demmer, Ricky L.; Tripp, Julia L.; Hull, Laurence C.

    2011-03-29

    Clay-based compositions capable of absorbing contaminants from surfaces or objects having surface faces may be applied to a surface and later removed, the removed clay-based compositions absorbing at least a portion of the contaminant from the surface or object to which it was applied.

  5. Preparation of sorbent pellets with high integrity for sorption of CO.sub.2 from gas streams

    DOE Patents [OSTI]

    Siriwardane, Ranjani V.

    2016-05-10

    Method for the production of a CO.sub.2 sorbent prepared by integrating a clay substrate, basic alkali salt, amine liquid, hydraulic binder, and a liquid binder. The basic alkali salt is present relative to the clay substrate in a weight ratio of from about 1 part to about 50 parts per 100 parts of the clay substrate. The amine liquid is present relative to a clay-alkali combination in a weight ratio of from about 1 part to about 10 parts per 10 parts of the clay-alkali combination. The clay substrate and basic alkali salt may be combined in a solid-solid heterogeneous mixture and followed by introduction of the amine liquid. Alternatively, an alkaline solution may be blended with the amine solution prior to contacting the clay substrate. The clay-alkali-amine CO.sub.2 sorbent is particularly advantageous for low temperature CO.sub.2 removal cycles in a gas stream having a CO.sub.2 concentration less than around 2000 ppm and an oxygen concentration around 21%, such as air.

  6. Seismic Velocities Contain Information About Depth, Lithology, Fluid Content, and Microstructure

    SciTech Connect (OSTI)

    Berge, P A; Bonner, B P

    2002-01-03

    Recent advances in field and laboratory methods for measuring elastic wave velocities provide incentive and opportunity for improving interpretation of geophysical data for engineering and environmental applications. Advancing the state-of-the-art of seismic imaging requires developing petrophysical relationships between measured velocities and the hydrogeology parameters and lithology. Our approach uses laboratory data and rock physics methods. Compressional (Vp) and shear (Vs) wave velocities, Vp/Vs ratios, and relative wave amplitudes show systematic changes related to composition, saturation, applied stress (analogous to depth), and distribution of clay for laboratory ultrasonic measurements on soils. The artificial soils were mixtures of Ottawa sand and a second phase, either Wyoming bentonite or peat moss used to represent clay or organic components found in natural soils. Compressional and shear wave velocities were measured for dry, saturated, and partially-saturated conditions, for applied stresses between about 7 and 100 kPa, representing approximately the top 5 m of the subsurface. Analysis of the results using rock physics methods shows the link between microstructure and wave propagation, and implications for future advances in seismic data interpretation. For example, we found that Vp in dry sand-clay mixtures initially increases as clay cements the sand grains and fills porosity, but then Vp decreases when the clay content is high enough that the clay matrix controls the elastic response of the material. Vs decreases monotonically with increasing clay content. This provides a method for using Vp/Vs ratios to estimate clay content in a dry soil.

  7. University of Alaska Fairbanks | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Alaska Fairbanks University of Alaska Fairbanks Team roster: Clay Allen, Mechanical Engineering; Elisha Dalbec, Mechanical Engineering; Jessica Garvin, Mechanical Engineering; Matthew Pacheco, Mechanical Engineering; Adam Becia, Mechanical Engineering; Daniel Poesy, Mechanical Engineering; Taylor Roth, Mechanical Engineering; Alex Mitchell, Mechanical Engineering; Isaac Lammers, Mechanical Engineering; Dalton Newbrough, Mechanical Engineering Team roster: Clay Allen, Mechanical Engineering;

  8. Natural materials for carbon capture.

    SciTech Connect (OSTI)

    Myshakin, Evgeniy M.; Romanov, Vyacheslav N.; Cygan, Randall Timothy

    2010-11-01

    Naturally occurring clay minerals provide a distinctive material for carbon capture and carbon dioxide sequestration. Swelling clay minerals, such as the smectite variety, possess an aluminosilicate structure that is controlled by low-charge layers that readily expand to accommodate water molecules and, potentially, carbon dioxide. Recent experimental studies have demonstrated the efficacy of intercalating carbon dioxide in the interlayer of layered clays but little is known about the molecular mechanisms of the process and the extent of carbon capture as a function of clay charge and structure. A series of molecular dynamics simulations and vibrational analyses have been completed to assess the molecular interactions associated with incorporation of CO2 in the interlayer of montmorillonite clay and to help validate the models with experimental observation.

  9. Process for preparing organoclays for aqueous and polar-organic systems

    DOE Patents [OSTI]

    Chaiko, David J.

    2001-01-01

    A process for preparing organoclays as thixotropic agents to control the rheology of water-based paints and other aqueous and polar-organic systems. The process relates to treating low-grade clay ores to achieve highly purified organoclays and/or to incorporate surface modifying agents onto the clay by adsorption and/or to produce highly dispersed organoclays without excessive grinding or high shear dispersion. The process involves the treatment of impure, or run-of-mine, clay using an aqueous biphasic extraction system to produce a highly dispersed clay, free of mineral impurities and with modified surface properties brought about by adsorption of the water-soluble polymers used in generating the aqueous biphasic extraction system. This invention purifies the clay to greater than 95%.

  10. Natural-analog studies for partial validation of conceptual models of radionuclide retardation at the Waste Isolation Pilot Plant (WIPP)

    SciTech Connect (OSTI)

    Ward, D.B.; Brookins, D.G. . Dept. of Geology); Siegel, M.D.; Lambert, S.J. )

    1990-01-01

    Transport by groundwater within the Culebra Dolomite, an aquifer above the Waste Isolation Pilot Plant (WIPP), is the most probable mechanism for long-term release of radionuclides to the accessible environment. Radionuclides could be retarded by sorption if the groundwater is exposed to sufficient amounts of fracture-lining clays. In this natural-analog study, distributions of U and trace metals have been examined to constrain the strength of clay/solute interactions within the Culebra. Uranium solid/liquid distribution ratios, calculated from U concentrations of groundwaters and consanguineous fracture-filling clays, range from {approximately}80 to 800 m{ell}/g and imply retardation factors of 60 to 500 using a fracture-flow model. Retardation factors inferred from uranium-series disequilibria and {sup 14}C ages in Culebra groundwaters alone are much lower ({approximately}10), implying that clays may contain a significant unreactive component of U. Such a possibility is corroborated by Rb/Sr ages; these imply long-term stability of the clays,with resetting occurring more than 250 Ma ago. Factor analysis and mass-balance calculations suggest, however, that Mg-rich clays are dissolving in Pleistocene-age groundwaters and/or are converting to Na-rich smectites, and that B and Li are taken up from the water by the clays. Apparently, the solution chemistry reflects gradual equilibration of clays with groundwater, but thus far the bulk of the clays remain structurally intact. Measurements of the distribution of U in the Culebra will be more meaningful if the inert and exchangeable components of the U content of the clays can be quantified. 26 refs., 3 figs., 2 tabs.

  11. INTERNAL REPAIR OF PIPELINES

    SciTech Connect (OSTI)

    Robin Gordon; Bill Bruce; Ian Harris; Dennis Harwig; Nancy Porter; Mike Sullivan; Chris Neary

    2004-04-12

    The two broad categories of deposited weld metal repair and fiber-reinforced composite liner repair technologies were reviewed for potential application for internal repair of gas transmission pipelines. Both are used to some extent for other applications and could be further developed for internal, local, structural repair of gas transmission pipelines. Preliminary test programs were developed for both deposited weld metal repair and for fiber-reinforced composite liner repair. Evaluation trials have been conducted using a modified fiber-reinforced composite liner provided by RolaTube and pipe sections without liners. All pipe section specimens failed in areas of simulated damage. Pipe sections containing fiber-reinforced composite liners failed at pressures marginally greater than the pipe sections without liners. The next step is to evaluate a liner material with a modulus of elasticity approximately 95% of the modulus of elasticity for steel. Preliminary welding parameters were developed for deposited weld metal repair in preparation of the receipt of Pacific Gas & Electric's internal pipeline welding repair system (that was designed specifically for 559 mm (22 in.) diameter pipe) and the receipt of 559 mm (22 in.) pipe sections from Panhandle Eastern. The next steps are to transfer welding parameters to the PG&E system and to pressure test repaired pipe sections to failure. A survey of pipeline operators was conducted to better understand the needs and performance requirements of the natural gas transmission industry regarding internal repair. Completed surveys contained the following principal conclusions: (1) Use of internal weld repair is most attractive for river crossings, under other bodies of water, in difficult soil conditions, under highways, under congested intersections, and under railway crossings. (2) Internal pipe repair offers a strong potential advantage to the high cost of horizontal direct drilling (HDD) when a new bore must be created to

  12. Kaolinization in examples of Carboniferous and Cretaceous tonsteins

    SciTech Connect (OSTI)

    McCuistion, J.T.; Ambers, C.P. . Dept. of Geological Science)

    1993-03-01

    Optical and electron petrography were used to test if differences of mineral textures in tonsteins offer any evidence of the alteration history of their volcanic precursors. A suspect tonstein from the Mississippian Sample fm. In Crawford County, IN, and true tonsteins from the Pennsylvanian Breathitt Fm. in Leslie County, KY; Cretaceous Adaville Fm. in Lincoln County, WY; and the Cretaceous Williams Fork Fm. in Moffat and Routt Counties, CO were studied. Optical petrography showed lack of silt or sand in the Indiana clay, minor silt/fine-sand in the Kentucky clay, and lack of mica in both. The Indiana clay is very fine grained and has a strong preferred orientation, whereas the Kentucky clay matrix is also very fine grained but is isotropic. Abundant, angular, quartzofeldspathic, medium sand abounds in the western clays. Very large kaolinite verms up to 0.5 mm in length dominate the western clays. Each large kaolinite contains evenly spaced interlayers of relict biotite extending exactly the width of each verm. Kaolinite in the western clays shows strong compactional strain including undulose extinction, kink bands, and shearing along the basal plane. Compactional fabrics show all of the samples to have altered from their parent material before significant burial.

  13. Brick manufacture with fly ash from Illinois coals. Quarterly technical report, September 1, 1994--November 30, 1994

    SciTech Connect (OSTI)

    Hughes, R.E.; Dreher, G.; Frost, J.; Moore, D.; Rostam-Abadi, M.; Fiocchi, T.; Swartz, D.

    1995-03-01

    This investigation seeks to utilize fly ash in fired-clay products such as building and patio bricks, ceramic blocks, field and sewer tile, and flower pots. This goal is accomplished by (1) one or more plant-scale, 5000-brick tests with fly ash mixed with brick clays at the 20% or higher level; (2) a laboratory-scale study to measure the firing reactions of a range of compositions of clay and fly ash mixtures; (3) a technical and economic study to evaluate the potential environmental and economic benefits of brick manufacture with fly ash. Bricks and feed materials will be tested for compliance with market specifications and for leachability of pollutants derived from fly ash. The laboratory study will combine ISGS databases, ICCI-supported characterization methods, and published information to improve predictions of the firing characteristics of Illinois fly ash and brick clay mixtures. Because identical methods are used to test clay firing and coal ash fusion, and because melting mechanisms are the same, improved coal ash fusion predictions are an expected result of this research. If successful, this project should convert an environmental problem (fly ash) into valuable products - bricks. During this quarter, the authors set up the manufacturing run at Colonial Brick Co., provided an expanded NEPA questionnaire for DOE, made preliminary arrangements for a larger brick manufacturing run at Marseilles Brick Co., revised laboratory procedures for selective dissolution analysis, and began characterization of brick clays that could be mixed with fly ash for fired-clay products.

  14. Brick manufacture with fly ash from Illinois coals. Technical report, March 1, 1995--May 31, 1995

    SciTech Connect (OSTI)

    Hughes, R.E.; Dreher, G.; Moore, D.; Rostam-Abadi, M.; Fiocchi, T.; Swartz, D.

    1995-12-31

    This investigation seeks to utilize fly ash in fired-clay products such as building and patio bricks, ceramic blocks, field and sewer tile, and flower pots. This goal is accomplished by 1) one or more plant-scale, 5000-brick tests of fly ash mixed with brick clays at the 20% or higher level; 2) a laboratory-scale study to measure the firing reactions of a range of compositions of clay and fly ash mixtures; 3) a preliminary study to evaluate the potential environmental and economic benefits of brick manufacture with fly ash. Bricks and feed materials will be tested for compliance with market specifications and for leachability of pollutants derived from fly ash. The laboratory study will combine ISGS databases, ICCI-supported characterization methods, and published information to improve predictions of the firing characteristics of Illinois fly ash and brick clay mixtures. Because identical methods are used to test clay firing and coal ash fusion, and because melting mechanisms are the same, improved coal ash fusion predictions are and additional expected result of this research. During this quarter we completed a manufacturing run at Colonial Brick Co. and began laboratory testing of samples from that run: clays, fly ash (from Illinois Power Company`s Wood River plant), and green and fired bricks, with and without fly ash. Bricks with 20% fly ash ``scummed`` during firing, and the fly ash failed to increase oxidation rate or water absorption, which were both expected. We obtained chemical and mineralogical analyses of the fireclays and shales at Colonial and Marseilles Brick Companies and began a series of selective dissolution analyses to more accurately determine the composition of the principal clay minerals in brick clays and the components in fly ash. We began related work of calculating normative mineralogical analyses for all clays and fly ashes that we sample.

  15. Studying methane migration mechanisms at Walker Ridge, Gulf of Mexico, via 3D methane hydrate reservoir modeling

    SciTech Connect (OSTI)

    Nole, Michael; Daigle, Hugh; Mohanty, Kishore; Cook, Ann; Hillman, Jess

    2015-12-15

    We have developed a 3D methane hydrate reservoir simulator to model marine methane hydrate systems. Our simulator couples highly nonlinear heat and mass transport equations and includes heterogeneous sedimentation, in-situ microbial methanogenesis, the influence of pore size contrast on solubility gradients, and the impact of salt exclusion from the hydrate phase on dissolved methane equilibrium in pore water. Using environmental parameters from Walker Ridge in the Gulf of Mexico, we first simulate hydrate formation in and around a thin, dipping, planar sand stratum surrounded by clay lithology as it is buried to 295mbsf. We find that with sufficient methane being supplied by organic methanogenesis in the clays, a 200x pore size contrast between clays and sands allows for a strong enough concentration gradient to significantly drop the concentration of methane hydrate in clays immediately surrounding a thin sand layer, a phenomenon that is observed in well log data. Building upon previous work, our simulations account for the increase in sand-clay solubility contrast with depth from about 1.6% near the top of the sediment column to 8.6% at depth, which leads to a progressive strengthening of the diffusive flux of methane with time. By including an exponentially decaying organic methanogenesis input to the clay lithology with depth, we see a decrease in the aqueous methane supplied to the clays surrounding the sand layer with time, which works to further enhance the contrast in hydrate saturation between the sand and surrounding clays. Significant diffusive methane transport is observed in a clay interval of about 11m above the sand layer and about 4m below it, which matches well log observations. The clay-sand pore size contrast alone is not enough to completely eliminate hydrate (as observed in logs), because the diffusive flux of aqueous methane due to a contrast in pore size occurs slower than the rate at which methane is supplied via organic methanogenesis

  16. MODELING UNDERGROUND STRUCTURE VULNERABILITY IN JOINTED ROCK

    SciTech Connect (OSTI)

    R. SWIFT; D. STEEDMAN

    2001-02-01

    The vulnerability of underground structures and openings in deep jointed rock to ground shock attack is of chief concern to military planning and security. Damage and/or loss of stability to a structure in jointed rock, often manifested as brittle failure and accompanied with block movement, can depend significantly on jointed properties, such as spacing, orientation, strength, and block character. We apply a hybrid Discrete Element Method combined with the Smooth Particle Hydrodynamics approach to simulate the MIGHTY NORTH event, a definitive high-explosive test performed on an aluminum lined cylindrical opening in jointed Salem limestone. Representing limestone with discrete elements having elastic-equivalence and explicit brittle tensile behavior and the liner as an elastic-plastic continuum provides good agreement with the experiment and damage obtained with finite-element simulations. Extending the approach to parameter variations shows damage is substantially altered by differences in joint geometry and liner properties.

  17. Development of value-added products from alumina industry mineral wastes using low-temperature-setting phosphate ceramics

    SciTech Connect (OSTI)

    Wagh, A.S.; Jeong, Seung-Young; Singh, D.

    1996-01-01

    A room-temperature process for stabilizing mineral waste streams has been developed, based on acid-base reaction between MgO and H3PO4 or acid phosphate solution. The resulting waste form sets into a hard ceramic in a few hours. In this way, various alumina industry wastes, such as red mud and treated potliner waste, can be solidified into ceramics which can be used as structural materials in waste management and construction industry. Red mud ceramics made by this process were low-porosity materials ({approx}2 vol%) with a compression strength equal to portland cement concrete (4944 psi). Bonding mechanism appears to be result of reactions of boehmite, goethite, and bayerite with the acid solution, and also encapsulation of red mud particles in Mg phosphate matrix. Possible applications include liners for ponds and thickned tailings disposal, dikes for waste ponds, and grouts. Compatability problems arising at the interface of the liner and the waste are avoided.

  18. Fall Protection Procedures for Sealing Bulk Waste Shipments by Rail Cars at Formerly Utilized Sites Remedial Action Program (FUSRAP) Sites - 13509

    SciTech Connect (OSTI)

    Boyle, J.D.; Fort, E. Joseph; Lorenz, William; Mills, Andy

    2013-07-01

    Rail-cars loaded with radioactive materials must be closed and fastened to comply with United States Department of Transportation (DOT) requirements before they shipped. Securing waste shipments in a manner that meets these regulations typically results in the use of a sealable rail-car liner. Workers accessing the tops of the 2.74 m high rail-cars to seal and inspect liners for compliance prior to shipment may be exposed to a fall hazard. Relatively recent revisions to the Fall Protection requirements in the Safety and Health Requirements Manual (EM385-1-1, U.S. Army Corps of Engineers) have necessitated modifications to the fall protection systems previously employed for rail-car loading at Formerly Utilized Sites Remedial Action Program (FUSRAP) sites. In response these projects have developed site-specific procedures to protect workers and maintain compliance with the improved fall protection regulations. (authors)

  19. Analysis of ``soft`` recovered shaped charge jet particles

    SciTech Connect (OSTI)

    Lassila, D.H.; Nikkel, D.J. Jr.; Kershaw, R.P.; Walters, W.P.

    1996-04-01

    A shaped charge with an 81 mm diameter, 42{degree} apex angle oxygen-free high-conductivity (OFHC) copper conical liner was fired into a ``soft`` recovery bunker to allow metallurgical examination of recovered jet particles and the slug. The initial weight of the copper liner was 245 g, of which 184 g was recovered. The number of jet particles recovered was 37 (approximately 63% of the particles formed by the charge). Extensive metallurgical analyses were performed on the recovered slug and jet particles. The microstructural features associated with voids, e.g., dendritic grain growth, clearly indicate that the regions in the vicinity of the centerline of the slug and jet particles were melted. In this work the authors present calculations of jet temperature as a function of constitutive behavior. In order to predict melt in the center region of the jet they find it necessary to scale flow stress with a pressure dependent shear modulus.

  20. Insulation assembly for electric machine

    DOE Patents [OSTI]

    Rhoads, Frederick W.; Titmuss, David F.; Parish, Harold; Campbell, John D.

    2013-10-15

    An insulation assembly is provided that includes a generally annularly-shaped main body and at least two spaced-apart fingers extending radially inwards from the main body. The spaced-apart fingers define a gap between the fingers. A slot liner may be inserted within the gap. The main body may include a plurality of circumferentially distributed segments. Each one of the plurality of segments may be operatively connected to another of the plurality of segments to form the continuous main body. The slot liner may be formed as a single extruded piece defining a plurality of cavities. A plurality of conductors (extendable from the stator assembly) may be axially inserted within a respective one of the plurality of cavities. The insulation assembly electrically isolates the conductors in the electric motor from the stator stack and from other conductors.

  1. Cladding material, tube including such cladding material and methods of forming the same

    DOE Patents [OSTI]

    Garnier, John E.; Griffith, George W.

    2016-03-01

    A multi-layered cladding material including a ceramic matrix composite and a metallic material, and a tube formed from the cladding material. The metallic material forms an inner liner of the tube and enables hermetic sealing of thereof. The metallic material at ends of the tube may be exposed and have an increased thickness enabling end cap welding. The metallic material may, optionally, be formed to infiltrate voids in the ceramic matrix composite, the ceramic matrix composite encapsulated by the metallic material. The ceramic matrix composite includes a fiber reinforcement and provides increased mechanical strength, stiffness, thermal shock resistance and high temperature load capacity to the metallic material of the inner liner. The tube may be used as a containment vessel for nuclear fuel used in a nuclear power plant or other reactor. Methods for forming the tube comprising the ceramic matrix composite and the metallic material are also disclosed.

  2. Merging of high speed argon plasma jets

    SciTech Connect (OSTI)

    Case, A.; Messer, S.; Brockington, S.; Wu, L.; Witherspoon, F. D.; Elton, R.

    2013-01-15

    Formation of an imploding plasma liner for the plasma liner experiment (PLX) requires individual plasma jets to merge into a quasi-spherical shell of plasma converging on the origin. Understanding dynamics of the merging process requires knowledge of the plasma phenomena involved. We present results from the study of the merging of three plasma jets in three dimensional geometry. The experiments were performed using HyperV Technologies Corp. 1 cm Minirailguns with a preionized argon plasma armature. The vacuum chamber partially reproduces the port geometry of the PLX chamber. Diagnostics include fast imaging, spectroscopy, interferometry, fast pressure probes, B-dot probes, and high speed spatially resolved photodiodes, permitting measurements of plasma density, temperature, velocity, stagnation pressure, magnetic field, and density gradients. These experimental results are compared with simulation results from the LSP 3D hybrid PIC code.

  3. High-density FRC formation studies on FRX-L.

    SciTech Connect (OSTI)

    Taccetti, J. M.; Intrator, Thomas; Zhang, S.; Wurden, G. A.; Begay, D. W.; Mignardot, E. R.; Waganaar, W. J.; Siemon, R. E.; Tuszewski, M. G.; Sanchez, P. G.; Degnan, J. H.; Sommars, W.

    2002-01-01

    FRX-L (Field Reversed configuration experiment - Liner) is a magnetized-target injector for magnetized target fusion (MTF) experiments. It was designed with the goal of producing high-density n-1017 cm3 field reversed configurations (FRCs) and translating them into an aluminum liner (1-mm thick, 10-cm diameter cylindrical shell) for further compression to fusion conditions. Although operation at these high densities leads to shorter FRC lifetimes, our application requires thlat the plasma live only long enough to be translated and compressed, or on the order of 10-20 ps. Careful study of FRC formation in situ will be done in the present experiment to differentiate between effects introduced in future experiments by translation, trapping, and compression of the FRC. We present current results on the optimization of the FRC formation process on RX-L and compare the results with those from past experiments.

  4. Installation of the Monitoring Site at the Los Alamos Canyon Low-Head Weir

    SciTech Connect (OSTI)

    W.J.Stone; D.L.Newell

    2002-08-01

    The Cerro Grande fire of 2000 had an enormously adverse impact on and around Los Alamos National Laboratory (LANL). Immediately there were concerns about the potential for enhanced runoff/offsite transport of contaminant-laden sediments because of watershed damage. In response to this concern, the U.S. Army Corps of Engineers installed a low-head weir in Los Alamos Canyon near the White Rock ''Y.'' However, the occurrence of fractured basalt at the surface and ponding of runoff behind the weir enhance the possibility of downward migration of contaminants. Therefore, three boreholes were drilled on the south bank of the channel by LANL to provide a means of monitoring the impact of the Cerro Grande fire and of the weir on water quality beneath the canyon. The boreholes and associated instrumentation are referred to as the Los Alamos Weir Site (LAWS). The three boreholes include a vertical hole and two angled holes (one at approximately 45{sup o} and one at approximately 30{sup o}). Since the basalt is highly fractured, the holes would not stay open. Plans called for inserting flexible liners into all holes. However, using liners in such unstable ground was problematic and, in the angled holes, required deployment through scalloped or perforated polyvinyl chloride (PVC) shield. The vertical hole (LAWS-01), drilled to a total depth of 281.5 ft below ground surface (bgs), was completed as a 278-ft deep monitoring well with four screens: one targeting shallow perched water encountered at 80 ft, two in what may correspond to the upper perched zone at regional groundwater characterization well R-9i (1/4 mi. to the west), and one in what may correspond to the lower perched zone at R-9i. A Water FLUTe{trademark} system deployed in the well isolates the screened intervals; associated transducers and sampling ports permit monitoring head and water quality in the screened intervals. The second hole (LAWS-02), drilled at an angle of 43{sup o} from horizontal, is 156 ft long and

  5. Hanford Double-Shell Tank AY-102 Radioactive Waste Leak Investigation Update - 15302

    SciTech Connect (OSTI)

    Washenfelder, D. J.; Johnson, J. M.

    2014-12-22

    Tank AY-102 was the first of 28 double-shell radioactive waste storage tanks constructed at the U. S. Department of Energy’s Hanford Site, near Richland, WA. The tank was completed in 1970, and entered service in 1971. In August, 2012, an accumulation of material was discovered at two sites on the floor of the annulus that separates the primary tank from the secondary liner. The material was sampled and determined to originate from the primary tank. This paper summarizes the changes in leak behavior that have occurred during the past two years, inspections to determine the capability of the secondary liner to continue safely containing the leakage, and the initial results of testing to determine the leak mechanism.

  6. Particle Control and Plasma Performance in the Lithium Tokamak Experiment (LTX)

    SciTech Connect (OSTI)

    Richard Majeski, et. al.

    2013-02-21

    The Lithium Tokamak eXperiment (LTX) is a small, low aspect ratio tokamak, which is fitted with a stainless steel-clad copper liner, conformal to the last closed flux surface. The liner can be heated to 350{degree}C. Several gas fueling systems, including supersonic gas injection, and molecular cluster injection have been studied, and produce fueling efficiencies up to 35%. Discharges are strongly affected by wall conditioning. Discharges without lithium wall coatings are limited to plasma currents of order 10 kA, and discharge durations of order 5 msec. With solid lithium coatings discharge currents exceed 70 kA, and discharge durations exceed 30 msec. Heating the lithium wall coating, however, results in a prompt degradation of the discharge, at the melting point of lithium. These results suggest that the simplest approach to implementing liquid lithium walls in a tokamak - thin, evaporated, liquefied coatings of lithium - does not produce an adequately clean surface.

  7. CHARACTERIZATION AND TRIBOLOGICAL EVALUATION OF 1-BENZYL-3-METHYLIMIDAZOLIUM BIS(TRIFLUOROMETHYLSULFONYL)IMIDE AS NEAT LUBRICANT AND OIL ADDITIVE

    SciTech Connect (OSTI)

    Bansal, Dinesh G; Qu, Jun; Yu, Bo; Luo, Huimin; Dai, Sheng; Bunting, Bruce G; Blau, Peter Julian; Mordukhovich, Gregory; Smolenski, Donald

    2011-01-01

    Selected physical and chemical properties and tribological data for a newly-developed, imidazolium-based ionic liquid (IL) are presented. The IL is soluble in the SAE 5W-30 oil up to a certain weight percentage, and is as a promising candidate for use in lubrication applications, either in its neat version or as an oil additive. Characterization of the IL included dynamic viscosity at different temperatures, corrosion effects on cast iron cylinder liners, and thermal stability analysis. The tribological performance was evaluated using a reciprocating ring-on-liner test arrangement. When used in neat version this IL demonstrated friction coefficient comparable to a fully formulated engine oil, and when used as an oil additive it produced less wear.

  8. Cu--Ni--Fe anode for use in aluminum producing electrolytic cell

    DOE Patents [OSTI]

    Bergsma, S. Craig; Brown, Craig W.; Bradford, Donald R; Barnett, Robert J.; Mezner, Michael B.

    2006-07-18

    A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte, the method comprising the steps of providing a molten salt electrolyte at a temperature of less than 900.degree. C. having alumina dissolved therein in an electrolytic cell having a liner for containing the electrolyte, the liner having a bottom and walls extending upwardly from said bottom. A plurality of non-consumable Cu--Ni--Fe anodes and cathodes are disposed in a vertical direction in the electrolyte, the cathodes having a plate configuration and the anodes having a flat configuration to compliment the cathodes. The anodes contain apertures therethrough to permit flow of electrolyte through the apertures to provide alumina-enriched electrolyte between the anodes and the cathodes. Electrical current is passed through the anodes and through the electrolyte to the cathodes, depositing aluminum at the cathodes and producing gas at the anodes.

  9. CRUCIBLE LINING METHOD

    DOE Patents [OSTI]

    Bone, W.H.; Schmidt, W.W.

    1958-11-01

    A method is presented for forming refractory liners in cylindrical reaction vessels used for the reductlon of uranium tetrafluoride to metallic uranium. A preliminary form, having positioning lugs attached thereto, is inserted into the reaction vessel and the refractory powder, usually CaO, is put in the annular space between the form and the inner wall of the reaction vessel. A jolting table is used to compact this charge of liner material ln place, and after thls has been done, the preliminary form is removed and the flnal form or plug is lnserted without disturbing the partially completed lining. The remainder of the lining charge is then introduced and compacted by jolting, after which the form is removed.

  10. Instability Control in a Staged Z-pinch

    SciTech Connect (OSTI)

    Frank J. WESSEL

    2011-04-22

    A \\Staged Z-Pinch” is a fusion-energy concept in which stored-electric energy is first converted into plasma-liner-kinetic energy, and then transferred to a coaxialtarget plasma [H. U. Rahman, F. J. Wessel, and N. Rostoker, Phys. Rev. Lett. 74, p. 714(1996)]. Proper choice of the liner and target materials, and their initial radii and mass densities, leads to dynamic stabilization, current amplification, and shock heating of the target. Simulations suggest that this configuration has merit as a alternative inertial-confinement-fusion concept, and may provide an energy release exceeding thermonuclear break-even, if tested on one of many newer pulsed power systems, for example those located at Sandia National Laboratories.

  11. Oxidation of zirconium alloys in 2.5 kPa water vapor for tritium readiness.

    SciTech Connect (OSTI)

    Mills, Bernice E.

    2007-11-01

    A more reactive liner material is needed for use as liner and cruciform material in tritium producing burnable absorber rods (TPBAR) in commercial light water nuclear reactors (CLWR). The function of these components is to convert any water that is released from the Li-6 enriched lithium aluminate breeder material to oxide and hydrogen that can be gettered, thus minimizing the permeation of tritium into the reactor coolant. Fourteen zirconium alloys were exposed to 2.5 kPa water vapor in a helium stream at 300 C over a period of up to 35 days. Experimental alloys with aluminum, yttrium, vanadium, titanium, and scandium, some of which also included ternaries with nickel, were included along with a high nitrogen impurity alloy and the commercial alloy Zircaloy-2. They displayed a reactivity range of almost 500, with Zircaloy-2 being the least reactive.

  12. Gas turbine engine combustor can with trapped vortex cavity

    DOE Patents [OSTI]

    Burrus, David Louis; Joshi, Narendra Digamber; Haynes, Joel Meier; Feitelberg, Alan S.

    2005-10-04

    A gas turbine engine combustor can downstream of a pre-mixer has a pre-mixer flowpath therein and circumferentially spaced apart swirling vanes disposed across the pre-mixer flowpath. A primary fuel injector is positioned for injecting fuel into the pre-mixer flowpath. A combustion chamber surrounded by an annular combustor liner disposed in supply flow communication with the pre-mixer. An annular trapped dual vortex cavity located at an upstream end of the combustor liner is defined between an annular aft wall, an annular forward wall, and a circular radially outer wall formed therebetween. A cavity opening at a radially inner end of the cavity is spaced apart from the radially outer wall. Air injection first holes are disposed through the forward wall and air injection second holes are disposed through the aft wall. Fuel injection holes are disposed through at least one of the forward and aft walls.

  13. FINAL_News_Release_ERDF_20th_Anniversary.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This month marks 20 successful years of environmental cleanup at one of the U.S. Department of Energy (DOE)'s largest disposal facilities--the Environmental Restoration Disposal Facility (ERDF) on the Hanford Site in southeastern Washington state. Since disposal operations began in 1996, 18 million tons of contaminated soil, debris and solid wastes from cleanup activities at the Hanford site have been placed in the disposal facility, which is specially engineered with a liner and leachate

  14. Gas-cooled nuclear reactor

    DOE Patents [OSTI]

    Peinado, Charles O.; Koutz, Stanley L.

    1985-01-01

    A gas-cooled nuclear reactor includes a central core located in the lower portion of a prestressed concrete reactor vessel. Primary coolant gas flows upward through the core and into four overlying heat-exchangers wherein stream is generated. During normal operation, the return flow of coolant is between the core and the vessel sidewall to a pair of motor-driven circulators located at about the bottom of the concrete pressure vessel. The circulators repressurize the gas coolant and return it back to the core through passageways in the underlying core structure. If during emergency conditions the primary circulators are no longer functioning, the decay heat is effectively removed from the core by means of natural convection circulation. The hot gas rising through the core exits the top of the shroud of the heat-exchangers and flows radially outward to the sidewall of the concrete pressure vessel. A metal liner covers the entire inside concrete surfaces of the concrete pressure vessel, and cooling tubes are welded to the exterior or concrete side of the metal liner. The gas coolant is in direct contact with the interior surface of the metal liner and transfers its heat through the metal liner to the liquid coolant flowing through the cooling tubes. The cooler gas is more dense and creates a downward convection flow in the region between the core and the sidewall until it reaches the bottom of the concrete pressure vessel when it flows radially inward and up into the core for another pass. Water is forced to flow through the cooling tubes to absorb heat from the core at a sufficient rate to remove enough of the decay heat created in the core to prevent overheating of the core or the vessel.

  15. Women & the Department of Ecology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    September 4, 2014 Agency Update Hanford Advisory Board Nuclear Waste Program News * TPA Public Involvement Calendar updated & posted on Ecology's website * State/DOE discussing path forward on AY-102 * Negotiations on possible amendments to the Consent Decree continuing Comment periods in progress  325 HWTU* Class 3 permit mod to add capacity to the Radiochemical Processing Lab (RPL or 325 building)  Comment period: August 18-October 17  LERF-ETF Class 2 mod to revise liner repair

  16. Method for cutting steam heat losses during cyclic steam injection of wells. Fourth quarterly report

    SciTech Connect (OSTI)

    1995-02-01

    Effective Gravel-packing of horizontal wells is difficult to achieve, using conventional pre-slotted liners, yet it is generally required in the soft Heavy Oil reservoir rocks of California, where cyclic steam injection has been proven to be the most cost-effective oil recovery method. The proposed method of gravel placement behind a non-perforated liner, which is later perforated {open_quotes}in situ{close_quotes} with a new tool operated by coiled-tubing, is expected to greatly reduce costs resulting from sand production in horizontal wells operated under cyclic steam injection. The detailed configuration of the prototype tool is described. It includes two pairs of cutting wheels at the ends of spring-loaded pivoting arms, which are periodically pressed through the liner wall and shortly thereafter retracted, while the coiled tubing is being pulled-out. For each operating cycle of the hydraulically-operated tool, this results in a set of four narrow slots parallel to the liner axis, in two perpendicular diametral planes. The shape of the edges of each slot facilitates bridging by the gravel particles, for a more effective and compacted gravel-packing. The tool includes a few easily-assembled parts machined from surface-hardened alloy steel presenting great toughness, selected from those used in die making. The operation of the system and potential future improvements are outlined. The method of fabrication, detailed drawings and specifications are given. They will serve as a basis for negotiating subcontracts with qualified machine shops.

  17. Document Details Document Number

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Document Details Document Number Date of Document Document Title/Description [Links below to each document] D195066340 Not listed. N/A REVISIONS IN STRATIGRAPHIC NOMENCLATURE OF COLUMBIA RIVER BASALT GROUP D196000240 Not listed. N/A EPA DENIAL OF LINER LEACHATE COLLECTION SYSTEM REQUIREMENTS D196005916 Not listed. N/A LATE CENOZOIC STRATIGRAPHY AND TECTONIC EVOLUTION WITHIN SUBSIDING BASIN SOUTH CENTRAL WASHINGTON D196025993 RHO-BWI-ST-14 N/A SUPRABASALT SEDIMENTS OF COLD CREEK SYNCLINE AREA

  18. ARM - Publications: Science Team Meeting Documents

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Ship-Based Facility for Cloud and Radiation Measurements on the Cruise Liner the "Explorer of the Seas" Albrecht, B., Minnett, P. J., and Brown, O., University of Miami, Rosenstiel School of Marine and Atmospheric Sciences Eleventh Atmospheric Radiation Measurement (ARM) Science Team Meeting Atmospheric and oceanic laboratories have been constructed on Royal Caribbean Cruise Lines (RCCL) "Explorer of the Seas". A suite of instruments on this 140,000-ton ship was

  19. U.S. DEPARTMENT OF ENERGY * SAVANNAH RIVER SITE * AIKEN * SC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SILDA (Stepped Integral Liner Drum Assembly) Researchers at the Savannah River National Laboratory (SRNL) have developed a new concept for a shipping package which meets new government regulations while remaining cost-efficient. Background Government regulations from DOT and NRC for shipping hazardous materials have recently changed. As part of these changes, there has developed a need for shipping containers to replace existing shipping containers no longer allowed by the government

  20. Microsoft PowerPoint - 4A Craig Benson

    Office of Environmental Management (EM)

    Liners and Covers: Field Performance & Life Expectancy Craig H. Benson, PhD, PE, NAE Wisconsin Distinguished Professor University of Wisconsin-Madison Interagency Steering Committee on Performance and Risk Assessment Community of Practice Annual Technical Exchange Meeting 11-12 December 2014 Las Vegas, Nevada, USA Covers & Waste Containment Waste Groundwater Native soil Leachate storage pond Groundwater monitoring well Rainwater retention pond Gas vent or collection well Leachate

  1. Preshot Predictions for LA-43S-1 using the Eulerian AMR Code Roxane

    SciTech Connect (OSTI)

    Watt, Robert Gregory

    2015-11-23

    The Ranchero Magnetic Flux Compression Generator (FCG) has been used to create current pulses in the 10-100 MA range for driving both static low inductance (0.5 nH) loads1 for generator demonstration purposes and high inductance (10-20 nH) imploding liner loads for ultimate use in physics experiments at very high energy density. This report offers a description of these efforts.

  2. Microsoft PowerPoint - Benson EM Webinar Engr Barrier Perf

    Office of Environmental Management (EM)

    of Engineered Barriers: Lessons Learned Lessons Learned Craig H. Benson, PhD, PE, NAE Wisconsin Distinguished Professor University of Wisconsin-Madison/CRESP 1415 Engineering Drive Madison, Wisconsin 53706 USA (608) 262-7242 chbenson@wisc.edu Barrier Systems for Waste Containment Groundwater Gas collection Cover system monitoring well Waste G d t Native soil Groundwater Leachate collection system Liner system Challenges - Predicting the Future g g erty ? ng Prope As Built ACAP ? ngineerin

  3. Polymer/Elastomer and Composite Material Science

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    / Elastomer and Composite Material Science KEVIN L. SIMMONS Pacific Northwest National Laboratory, Richland, WA DOE Headquarters, Forrestal Bldg. October 17-18, 2012 January 17, 2013 Kevin.simmons@pnnl.gov 1 Outline Hydrogen production, transmission, distribution, delivery system Common themes in the hydrogen system Automotive vs infrastructure Hydrogen use conditions Polymer/elastomer and composites compatibility? Common materials in BOP components, hoses, and liners Common materials in

  4. For Immediate Release:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This month marks 20 successful years of environmental cleanup at one of the U.S. Department of Energy (DOE)'s largest disposal facilities--the Environmental Restoration Disposal Facility (ERDF) on the Hanford Site in southeastern Washington state. Since disposal operations began in 1996, 18 million tons of contaminated soil, debris and solid wastes from cleanup activities at the Hanford site have been placed in the disposal facility, which is specially engineered with a liner and leachate

  5. Elan4/SPARC V9 Cross Loader and Dynamic Linker

    Energy Science and Technology Software Center (OSTI)

    2004-10-25

    The Elan4/Sparc V9 Croos Loader and Liner is a part of the Linux system software that allows the dynamic loading and linking of user code in the network interface Quadrics QsNETII, also called as Elan4 Quadrics. Elan44 uses a thread processor that is based on the assembly instruction set of the Sparc V9. All this software is integrated as a Linux kernel module in the Linux 2.6.5 release.

  6. Disc valve for sampling erosive process streams

    DOE Patents [OSTI]

    Mrochek, John E.; Dinsmore, Stanley R.; Chandler, Edward W.

    1986-01-01

    A four-port disc valve for sampling erosive, high temperature process streams. A rotatable disc defining opposed first and second sampling cavities rotates between fired faceplates defining flow passageways positioned to be alternatively in axial alignment with the first and second cavities. Silicon carbide inserts and liners composed of .alpha. silicon carbide are provided in the faceplates and in the sampling cavities to limit erosion while providing lubricity for a smooth and precise operation when used under harsh process conditions.

  7. In other news

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In other news Community Connections: Your link to news and opportunities from Los Alamos National Laboratory Latest Issue: September 1, 2016 all issues All Issues » submit In other news Call for Venture Acceleration Fund applications, including information sessions March 5 and 11; opportunity to own a Habitat for Humanity home; Luján and Fleischmann to lead House Nuclear Cleanup Caucus March 1, 2015 FLUTe, a flexible liner manufacturer located in Alcalde, New Mexico, was one of the Venture

  8. Control of reactor coolant flow path during reactor decay heat removal

    DOE Patents [OSTI]

    Hunsbedt, Anstein N.

    1988-01-01

    An improved reactor vessel auxiliary cooling system for a sodium cooled nuclear reactor is disclosed. The sodium cooled nuclear reactor is of the type having a reactor vessel liner separating the reactor hot pool on the upstream side of an intermediate heat exchanger and the reactor cold pool on the downstream side of the intermediate heat exchanger. The improvement includes a flow path across the reactor vessel liner flow gap which dissipates core heat across the reactor vessel and containment vessel responsive to a casualty including the loss of normal heat removal paths and associated shutdown of the main coolant liquid sodium pumps. In normal operation, the reactor vessel cold pool is inlet to the suction side of coolant liquid sodium pumps, these pumps being of the electromagnetic variety. The pumps discharge through the core into the reactor hot pool and then through an intermediate heat exchanger where the heat generated in the reactor core is discharged. Upon outlet from the heat exchanger, the sodium is returned to the reactor cold pool. The improvement includes placing a jet pump across the reactor vessel liner flow gap, pumping a small flow of liquid sodium from the lower pressure cold pool into the hot pool. The jet pump has a small high pressure driving stream diverted from the high pressure side of the reactor pumps. During normal operation, the jet pumps supplement the normal reactor pressure differential from the lower pressure cold pool to the hot pool. Upon the occurrence of a casualty involving loss of coolant pump pressure, and immediate cooling circuit is established by the back flow of sodium through the jet pumps from the reactor vessel hot pool to the reactor vessel cold pool. The cooling circuit includes flow into the reactor vessel liner flow gap immediate the reactor vessel wall and containment vessel where optimum and immediate discharge of residual reactor heat occurs.

  9. Squeezing silica reveals meteorite secrets

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Squeezing silica reveals meteorite secrets Squeezing silica reveals meteorite secrets Scientists at Los Alamos National Laboratory are gaining insights into one of the effects of meteorite collisions with earth. September 27, 2015 Arianna Gleason is seen making final adjustments to detector positions inside the Matter in Extreme Conditions (MEC) target chamber at the Stanford Liner Accelerator facility (SLAC) in California. Arianna Gleason is seen making final adjustments to detector positions

  10. Categorical Exclusion Determinations: B1.6 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6 Categorical Exclusion Determinations: B1.6 Existing Regulations B1.6: Tanks and equipment to control runoff and spills Installation or modification of retention tanks or small (normally under one acre) basins and associated piping and pumps for existing operations to control runoff or spills (such as under 40 CFR part 112). Modifications include, but are not limited to, installing liners or covers. (See also B1.33 of this appendix.) Previous Regulations Categorical Exclusion Determinations

  11. Nuclear waste management. Quarterly progress report, July-September 1980

    SciTech Connect (OSTI)

    Chikalla, T.D.

    1980-11-01

    Research is reported on: high-level waste immobilization, alternative waste forms, TRU waste immobilization and decontamination, krypton solidification, thermal outgassing, /sup 129/I fixation, unsaturated zone transport, well-logging instrumentation, waste management system and safety studies, effectiveness of geologic isolation systems, waste/rock interactions, engineered barriers, backfill material, spent fuel storage (criticality), barrier sealing and liners for U mill tailings, and revegetation of inactive U tailings sites. (DLC)

  12. Significance of water fluxes in a deep arid-region vadose zone to waste disposal strategies

    SciTech Connect (OSTI)

    Johnejack, K.R.; Blout, D.O.; Sully, M.J.; Emer, D.F.; Hammermeister, D.P. [Reynolds Electrical and Engineering Co., Inc., Las Vegas, NV (United States); Dever, L.G.; O`Neill, L.J. [DOE Nevada Operations Office, Las Vegas, NV (United States). Waste Management Div.; Tyler, S.W. [Desert Research Institute, Reno, NV (United States). Water Resources Center; Chapman, J. [Desert Research Institute, Las Vegas, NV (United States). Water Resources Center

    1994-03-01

    Recently collected subsurface site characterization data have led to the development of a conceptual model of water movement beneath the Area 5 Radioactive Waste Management Site (RWMS) at the Nevada Test Site (NTS) that differs significantly from the conceptual model of water movement inherent in Resource Conservation and Recovery Act (RCRA) regulations. At the Area 5 RWMS, water fluxes in approximately the upper 75 m (250 ft) of the vadose zone point in the upward direction (rather than downward) which effectively isolates this region from the deep (approximately 250 m (820 ft)) uppermost aquifer. Standard RCRA approaches for detection and containment (groundwater monitoring and double liners/leachate collection/leak detection systems) are not able to fulfill their intended function in this rather unique hydrogeologic environment. In order to better fulfill the waste detection and containment intentions of RCRA for mixed waste disposal at the Area 5 RWMS, the Department of Energy, Nevada Operations Office (DOE/NV) is preparing a single petition for both a waiver from groundwater monitoring and an exemption from double liners with leachate collection/leak detection. DOE/NV proposes in this petition that the containment function of liners and leachate collection is better accomplished by the natural hydrogeologic processes operating in the upper vadose zone; and the detection function of groundwater monitoring and the leak detection system in liners is better fulfilled by an alternative vadose zone monitoring system. In addition, an alternative point of compliance is proposed that will aid in early detection, as well as limit the extent of potential contamination before detection. Finally, special cell design features and operation practices will be implemented to limit leachate formation, especially while the cell is open to the atmosphere during waste emplacement.

  13. Designing tomorrow's warheads -- today

    SciTech Connect (OSTI)

    Schneider, D.P.

    1988-03-15

    Until recently, new weapons' warheads were most often an incremental improvement on a previous warhead design. The tools available to the munition designer today, however, allow for a more comprehensive methodology to be employed. The focus of this paper will be a portion of the process of design of an explosively formed projectile (EFP) which uses tantalum as its liner material. Several questions surrounding tantalum's behavior under high strains require answers before such an EFP can be properly designed. The base-technology issues of different material properties will be explored using a three-dimensional finite element code (DYNA3D) and then compared to experiments. State-of-the-art diagnostics are an integral part of this methodology. Predetermined ''flasher block'' contours will provide specific position/time data which will assist in improving and understanding the high explosive equation of state as well as determining the energy imparted to the liner. In turn, this will lead to improved modeling of the liner as it translates along the line of flight. Flash X-ray Radiograph (FXR) will provide clues to axial symmetry, density, and overall time/distance information. This data will also provide answers to the strain rate depencence of the tantalum. Integration of the data from the experiment with the material response models allows post-experiment normalization of the code. This ''normalized'' tool is, finally used in the point design of the warhead.

  14. Wear mechanism and wear prevention in coal-fueled diesel engines

    SciTech Connect (OSTI)

    Schwalb, J.A.; Ryan, T.W.

    1991-10-01

    Coal fueled diesel engines present unique wear problems in the piston ring/cylinder liner area because of their tendency to contaminate the lube-oil with high concentrations of highly abrasive particles. This program involved a series of bench-scale wear tests and engine tests designed to investigate various aspects of the ring/liner wear problem and to make specific recommendations to engine manufacturers as to how to alleviate these problems. The program was organized into tasks, designed to accomplish the following objectives: (1) define the predominant wear mechanisms causing accelerated wear in the ring/liner area; (2) investigate the effectiveness of traditional approaches to wear prevention to prevent wear in coal-fueled engines; (3) further refine information on the most promising approaches to wear prevention; (4) present detailed information and recommendations to engine manufacturers on the most promising approach to wear prevention; (5) present a final report covering the entire program; (6)complete engine tests with a coal-derived liquid fuel, and investigate the effects of the fuel on engine wear and emissions.

  15. Magnetic flux and heat losses by diffusive, advective, and Nernst effects in MagLIF-like plasma

    SciTech Connect (OSTI)

    Velikovich, A. L. Giuliani, J. L.; Zalesak, S. T.

    2014-12-15

    The MagLIF approach to inertial confinement fusion involves subsonic/isobaric compression and heating of a DT plasma with frozen-in magnetic flux by a heavy cylindrical liner. The losses of heat and magnetic flux from the plasma to the liner are thereby determined by plasma advection and gradient-driven transport processes, such as thermal conductivity, magnetic field diffusion and thermomagnetic effects. Theoretical analysis based on obtaining exact self-similar solutions of the classical collisional Braginskii's plasma transport equations in one dimension demonstrates that the heat loss from the hot plasma to the cold liner is dominated by the transverse heat conduction and advection, and the corresponding loss of magnetic flux is dominated by advection and the Nernst effect. For a large electron Hall parameter ω{sub e}τ{sub e} effective diffusion coefficients determining the losses of heat and magnetic flux are both shown to decrease with ω{sub e}τ{sub e} as does the Bohm diffusion coefficient, which is commonly associated with low collisionality and two-dimensional transport. This family of exact solutions can be used for verification of codes that model the MagLIF plasma dynamics.

  16. Ceramic combustor mounting

    DOE Patents [OSTI]

    Hoffman, Melvin G.; Janneck, Frank W.

    1982-01-01

    A combustor for a gas turbine engine includes a metal engine block including a wall portion defining a housing for a combustor having ceramic liner components. A ceramic outlet duct is supported by a compliant seal on the metal block and a reaction chamber liner is stacked thereon and partly closed at one end by a ceramic bypass swirl plate which is spring loaded by a plurality of circumferentially spaced, spring loaded guide rods and wherein each of the guide rods has one end thereof directed exteriorly of a metal cover plate on the engine block to react against externally located biasing springs cooled by ambient air and wherein the rod spring support arrangement maintains the stacked ceramic components together so that a normal force is maintained on the seal between the outlet duct and the engine block under all operating conditions. The support arrangement also is operative to accommodate a substantial difference in thermal expansion between the ceramic liner components of the combustor and the metal material of the engine block.

  17. State-of-the-Art of Non-Destructive Testing Methods and Technologies for Application to Nuclear Power Plant Safety-Related Concrete Structures

    SciTech Connect (OSTI)

    Wiggenhauser, Dr. Herbert; Naus, Dan J

    2014-01-01

    The inspection of nuclear power plant concrete structures presents challenges different from conventional civil engineering structures. Wall thicknesses can be in excess of one meter and the structures often have increased steel reinforcement density with more complex detailing. The accessibility for any testing method may be limited due to the presence of liners and other components and there can be a number of penetrations or cast-in-place items present. The objective of the report is to present the state-of-the art of non-destructive testing methods and technologies for the inspection of thick, heavily-reinforced nuclear power plant concrete cross-sections with particular respect to: locating steel reinforcement and identification of its cover depth locating tendon ducts and identification of the condition of the grout materials detection of cracking, voids, delamination, and honeycombing in concrete structures detection of inclusions of different materials or voids adjacent to the concrete side of the containment liner methods capable of identification of corrosion occurrence on the concrete side of the containment liner

  18. State-of-the-art of non-destructive testing methods and technologies for application to nuclear power plant safety-related concrete structures

    SciTech Connect (OSTI)

    Wiggenhauser, Herbert; Naus, Dan J.

    2014-02-18

    The inspection of nuclear power plant concrete structures presents challenges different from conventional civil engineering structures. Wall thicknesses can be in excess of one meter and the structures often have increased steel reinforcement density with more complex detailing. The accessibility for any testing method may be limited due to the presence of liners and other components and there can be a number of penetrations or cast-in-place items present. The objective of the report is to present the state-of-the art of non-destructive testing methods and technologies for the inspection of thick, heavily-reinforced nuclear power plant concrete cross-sections with particular respect to: •locating steel reinforcement and identification of its cover depth •locating tendon ducts and identification of the condition of the grout materials •detection of cracking, voids, delamination, and honeycombing in concrete structures •detection of inclusions of different materials or voids adjacent to the concrete side of the containment liner •methods capable of identification of corrosion occurrence on the concrete side of the containment liner.

  19. Dynamic gas flow during plasma operation in TMX-U

    SciTech Connect (OSTI)

    Pickles, W.L.; Carter, M.R.; Clower, C.A.; Drake, R.P.; Hunt, A.L.; Simonen, T.C.; Turner, W.C.

    1982-11-12

    Control of the neutral density outside of the plasma radius is essential for proper operation of the various plasma configurations in TMX-U. TMX-U excess-beam, stream-gun, gas-box, and beam-reflux gases are pumped internally in regions defined by 73/sup 0/ Ti-gettered liners and warm Ti-gettered plasma liners. The array of fast and slow ion gauges - a large TMX-U diagnostic - has been used to measure the dynamic pressure in many of the liner-defined regions on three time scales. The natural divertor action, or plasma pump effect, of mirror plasmas has been measured using the ion gauge diagnostics on a fast time scale during operation of TMX-U with ECRH start-up. Routine operation of TMX-U is enhanced by the ability to verify the effectiveness of gettering and to locate leaks using pressure data collected on the two slow time scales. A computer code, DYNAVAC 6, which treats TMX-U as a set of conductance-coupled regions with pumping and sources in each region, has been used to successfully model the overall gas dynamics during all phases of TMX-U operation.

  20. Weathering of Roofing Materials-An Overview (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    of wood, acceleration of corrosion of metals, staining of clay, and freeze-thaw damage. ... Report Number(s): LBNL--59724 Journal ID: CBUMEZ; R&D Project: EK264L; TRN: US200813%%207 ...