National Library of Energy BETA

Sample records for geopressurized brine devonian

  1. Gas evolution from geopressured brines

    SciTech Connect (OSTI)

    Matthews, C.S.

    1980-06-01

    The process of gas evolution from geopressured brine is examined using as a basis the many past studies of gas evolution from liquids in porous media. A discussion of a number of speculations that have been made concerning gas evolution from geopressured brines is provided. According to one, rapid pressure reduction will cause methane gas to evolve as when one opens a champagne bottle. It has been further speculated that evolved methane gas would migrate up to form an easily producible cap. As a result of detailed analyses, it can be concluded that methane gas evolution from geopressured brines is far too small to ever form a connected gas saturation except very near to the producing well. Thus, no significant gas cap could ever form. Because of the very low solubility of methaned in brine, the process of methane gas evolution is not at all analogous to evolution of carbon dioxide from champagne. A number of other speculations and questions on gas evolution are analyzed, and procedures for completing wells and testing geopressured brine reservoirs are discussed, with the conclusion that presently used procedures will provide adequate data to enable a good evaluation of this resource.

  2. Hydrocarbon content of geopressured brines. Final report

    SciTech Connect (OSTI)

    Osif, T.L.

    1985-08-01

    Design Well data (bottomhole pressure minus wellhead pressure, GWR, and hydrocarbon composition) is presented as a function of producing conditions. These are examined in conjunction with the following models to attempt to deduce the reservoir brine saturation level: (1) reservoir contains gas dispersed in the pores and the gas saturation is greater than critical; (2) reservoir brine is gas-saturated; (3) bubble point below hydrostatic pressure; and (4) bubble point between hydrostatic pressure and reservoir pressure. 24 figs., 10 tabs. (ACR)

  3. Fluid sampling and chemical modeling of geopressured brines containing methane. Final report, March 1980-February 1981

    SciTech Connect (OSTI)

    Dudak, B.; Galbraith, R.; Hansen, L.; Sverjensky, D.; Weres, O.

    1982-07-01

    The development of a flowthrough sampler capable of obtaining fluid samples from geopressured wells at temperatures up to 400/sup 0/F and pressures up to 20,000 psi is described. The sampler has been designed, fabricated from MP35N alloy, laboratory tested, and used to obtain fluid samples from a geothermal well at The Geysers, California. However, it has not yet been used in a geopressured well. The design features, test results, and operation of this device are described. Alternative sampler designs are also discussed. Another activity was to review the chemistry and geochemistry of geopressured brines and reservoirs, and to evaluate the utility of available computer codes for modeling the chemistry of geopressured brines. The thermodynamic data bases for such codes are usually the limiting factor in their application to geopressured systems, but it was concluded that existing codes can be updated with reasonable effort and can usefully explain and predict the chemical characteristics of geopressured systems, given suitable input data.

  4. H. R. 1476: A bill to amend the Internal Revenue Code of 1986 to clarify the application of the credit for producing fuel from a nonconventional source with respect to gas produced from a tight formation and to make such credit permanent with respect to such gas and gas produced from Devonian shale. Introduced in the House of Representatives, One Hundredth First Congress, First Session, March 16, 1989

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    The determination of whether gas is produced from geopressured brines, Devonian shales, coal seams, or a tight formation is made from section 503 of the Natural Gas Policy Act of 1978. Permanent credit is for gas produced from a tight formation or Devonian shale only and applies to gas sold after July 1, 1987. The credit allowed for any taxable year shall not exceed the sum of the regular tax reduced by the sum of other credits allowable under other subsections of the Internal Revenue Code.

  5. Session: Geopressured-Geothermal

    SciTech Connect (OSTI)

    Jelacic, Allan J.; Eaton, Ben A.; Shook, G. Michael; Birkinshaw, Kelly; Negus-de Wys, Jane

    1992-01-01

    This session at the Geothermal Energy Program Review X: Geothermal Energy and the Utility Market consisted of five presentations: ''Overview of Geopressured-Geothermal'' by Allan J. Jelacic; ''Geothermal Well Operations and Automation in a Competitive Market'' by Ben A. Eaton; ''Reservoir Modeling and Prediction at Pleasant Bayou Geopressured-Geothermal Reservoir'' by G. Michael Shook; ''Survey of California Geopressured-Geothermal'' by Kelly Birkinshaw; and ''Technology Transfer, Reaching the Market for Geopressured-Geothermal Resources'' by Jane Negus-de Wys.

  6. Geopressured geothermal bibliography. Volume III. (Geopressure thesaurus). Second edition

    SciTech Connect (OSTI)

    Sepehrnoori, K.; Carter, F.; Schneider, R.; Street, S.; McGill, K.

    1985-05-01

    This thesaurus of terminology associated with the geopressured geothermal energy field has been developed as a part of the Geopressured Geothermal Information System data base. The subject scope includes: (1) geopressure resource assessment; (2) geology, hydrology, and geochemistry of geopressured systems; (3) geopressure exploration and exploration technology; (4) geopressured reservoir engineering and drilling technology; (5) economic aspects; (6) environmental aspects; (7) legal, institutional, and sociological aspects; (8) electrical and nonelectrical utilization; and (9) other energy sources, especially methane and other fossil fuel reserves, associated with geopressured reservoirs.

  7. Use of data obtained from core tests in the design and operation of spent brine injection wells in geopressured or geothermal systems

    SciTech Connect (OSTI)

    Jorda, R.M.

    1980-03-01

    The effects of formation characteristics on injection well performance are reviewed. Use of data acquired from cores taken from injection horizons to predict injectivity is described. And methods for utilizing data from bench scale testing of brine and core samples to optimize injection well design are presented. Currently available methods and equipment provide data which enable the optimum design of injection wells through analysis of cores taken from injection zones. These methods also provide a means of identifying and correcting well injection problems. Methods described in this report are: bulk density measurement; porosity measurement; pore size distribution analysis; permeability measurement; formation grain size distribution analysis; core description (lithology) and composition; amount, type and distribution of clays and shales; connate water analysis; consolidatability of friable reservoir rocks; grain and pore characterization by scanning electron microscopy; grain and pore characterization by thin section analysis; permeability damage and enhancement tests; distribution of water-borne particles in porous media; and reservoir matrix acidizing effectiveness. The precise methods of obtaining this information are described, and their use in the engineering of injection wells is illustrated by examples, where applicable. (MHR)

  8. Materials for geopressure energy extraction

    SciTech Connect (OSTI)

    Raman, A.

    1982-01-01

    The status of efforts in methane and energy extraction from the geopressured aquifer sources of the North Gulf of Mexico region is outlined. Three different schemes for energy extraction are considered, and the anticipated materials and corrosion problems are defined. Suitable materials are suggested for use in the production well and surface equipment. J-55 steel can be used for production well casing. Monel clad carbon steel or high chromium ferritic stainless steels, such as E-Brite or AL 29-4 can be used in the cyclone gas separator. Polymer-concrete coated steel pipings are suitable for brine piping. The hydraulic turbine as well as the power turbine in the thermal energy converter can be made of a titanium alloy such as Ticode-12. Monel or Hastelloy-C276 clad steel is recommended for steam processing areas and monel piping is recommended for the heat exchangers. 20 references.

  9. Recoverable Resource Estimate of Identified Onshore Geopressured Geothermal Energy in Texas and Louisiana (Presentation)

    SciTech Connect (OSTI)

    Esposito, A.; Augustine, C.

    2012-04-01

    Geopressured geothermal reservoirs are characterized by high temperatures and high pressures with correspondingly large quantities of dissolved methane. Due to these characteristics, the reservoirs provide two sources of energy: chemical energy from the recovered methane, and thermal energy from the recovered fluid at temperatures high enough to operate a binary power plant for electricity production. Formations with the greatest potential for recoverable energy are located in the gulf coastal region of Texas and Louisiana where significantly overpressured and hot formations are abundant. This study estimates the total recoverable onshore geopressured geothermal resource for identified sites in Texas and Louisiana. In this study a geopressured geothermal resource is defined as a brine reservoir with fluid temperature greater than 212 degrees F and a pressure gradient greater than 0.7 psi/ft.

  10. Geothermal energy geopressure subprogram

    SciTech Connect (OSTI)

    Not Available

    1981-02-01

    The proposed action will consist of drilling one geopressured-geothermal resource fluid well for intermittent production testing over the first year of the test. During the next two years, long-term testing of 40,000 BPD will be flowed. A number of scenarios may be implemented, but it is felt that the total fluid production will approximate 50 million barrels. The test well will be drilled with a 22 cm (8.75 in.) borehole to a total depth of approximately 5185 m (17,000 ft). Up to four disposal wells will provide disposal of the fluid from the designated 40,000 BPD test rate. The following are included in this assessment: the existing environment; probable environmental impacts-direct and indirect; probable cumulative and long-term environmental impacts; accidents; coordination with federal, state, regional, and local agencies; and alternative actions. (MHR)

  11. Geopressured geothermal drilling and completions technology development needs

    SciTech Connect (OSTI)

    Maish, A.B.

    1981-03-01

    Geopressured geothermal formations found in the Texas and Louisiana gulf coast region and elsewhere have the potential to supply large quantities of energy in the form of natural gas and warm brine (200 to 300/sup 0/F). Advances are needed, however, in hardware technology, well design technology, and drilling and completion practices to enable production and testing of exploratory wells and to enable economic production of the resource should further development be warranted. This report identifies needed technology for drilling and completing geopressured geothermal source and reinjection wells to reduce the cost and to accelerate commercial recovery of this resource. A comprehensive prioritized list of tasks to develop necessary technology has been prepared. Tasks listed in this report address a wide range of technology needs including new diagnostic techniques, control technologies, hardware, instrumentation, operational procedure guidelines and further research to define failure modes and control techniques. Tasks are organized into the functional areas of well design, drilling, casing installation, cementing, completions, logging, brine reinjection and workovers.

  12. Roadmap Finalized for Low-Temperature, Coproduced, and Geopressured...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Roadmap Finalized for Low-Temperature, Coproduced, and Geopressured Technologies Roadmap Finalized for Low-Temperature, Coproduced, and Geopressured Technologies March 23, 2011 -...

  13. Low-Temperature, Coproduced, and Geopressured Geothermal Power...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Temperature, Coproduced, and Geopressured Geothermal Power Low-Temperature, Coproduced, and Geopressured Geothermal Power The Geothermal Technology Program (GTP) ...

  14. Geothermal Energy Production with Co-produced and Geopressured...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Production with Co-produced and Geopressured Resources (Fact Sheet), Geothermal Technologies Program (GTP) Geothermal Energy Production with Co-produced and Geopressured ...

  15. Recoverable Resource Estimate of Identified Onshore Geopressured...

    Office of Scientific and Technical Information (OSTI)

    AAPG 2012 Annual Convention and Exhibition Ariel Esposito and Chad Augustine April 24, 2012 NRELPR-6A20-54999 2 * Geopressured Geothermal o Reservoirs characterized by pore...

  16. Low Temperature/Coproduced/Geopressured Subprogram Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Demonstrating the Commercial Feasibility of Geopressured - Geothermal Power Development at Sweet Lake Field Cameron Parish, Louisiana Louisiana Tank, Inc. will demonstrate the ...

  17. Parcperdue geopressure-geothermal project. Study a geopressured reservoir by drilling and producing a well in a limited geopressured water sand. Final technical report, September 28, 1979-December 31, 1983

    SciTech Connect (OSTI)

    Hamilton, J.R.; Stanley, J.G.

    1984-01-15

    The behavior of geopressured reservoirs was investigated by drilling and producing a well in small, well defined, geopressured reservoir; and performing detailed pressure transient analysis together with geological, geophysical, chemical, and physical studies. The Dow-DOE L. R. Sweezy No. 1 well was drilled to a depth of 13,600 feet in Parcperdue field, just south of Lafayette, Louisiana, and began production in April, 1982. The production zone was a poorly consolidated sandstone which constantly produced sand into the well stream, causing damage to equipment and causing other problems. The amount of sand production was kept manageable by limiting the flow rate to below 10,000 barrels per day. Reservoir properties of size, thickness, depth, temperature, pressure, salinity, porosity, and permeability were close to predicted values. The reservoir brine was undersaturated with respect to gas, containing approximately 20 standard cubic feet of gas per barrel of brine. Shale dewatering either did not occur or was insignificant as a drive mechanism. Production terminated when the gravel-pack completion failed and the production well totally sanded in, February, 1983. Total production up to the sanding incident was 1.94 million barrels brine and 31.5 million standard cubic feet gas.

  18. Geopressured energy availability. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-07-01

    Near- and long-term prospects that geopressured/geothermal energy sources could become a viable alternative fuel for electric power generation were investigated. Technical questions of producibility and power generation were included, as well as economic and environmental considerations. The investigators relied heavily on the existing body of information, particularly in geotechnical areas. Statistical methods were used where possible to establish probable production values. Potentially productive geopressured sediments have been identified in twenty specific on-shore fairways in Louisiana and Texas. A total of 232 trillion cubic feet (TCF) of dissolved methane and 367 x 10/sup 15/ Btu (367 quads) of thermal energy may be contained in the water within the sandstone in these formations. Reasonable predictions of the significant reservoir parameters indicate that a maximum of 7.6 TCF methane and 12.6 quads of thermal energy may be producible from these potential reservoirs.

  19. Computer simulation of production from geothermal-geopressured aquifers. Final report, October 1, 1978-January 31, 1983

    SciTech Connect (OSTI)

    Doherty, M.G.; Poonawala, N.A.

    1983-07-01

    This is the final report on research conducted to improve the technical and scientific understanding of geopressured and geothermal resources. The effort utilized a computer to interpret the results of well tests and compile data on gas solubility in brine and the viscosity of brine. A detailed computer reservoir study of a geopressured test well that had been abandoned as a dry hole but became a commercial producer of hydrocarbons is presented. A number of special topical reports pertaining to test activities performed on Department of Energy test wells (MG-T/DOE Amoco Fee No. 1 Well, Leroy Sweezy No. 1 Well, and Pleasant Bayou No. 2 Well) are appended to the report. A referenced article written under this study that appeared in the Journal of Petroleum Technology is also reproduced.

  20. Computer simulation of production from geothermal-geopressured aquifers. Final report, October 1, 1978 through January 31, 1983

    SciTech Connect (OSTI)

    Doherty, M.G.; Poonawala, N.A.

    1983-07-01

    The effort utilized a computer to interpret the results of well tests and compile data on gas solubility in brine and the viscosity of brine. A detailed computer reservoir study of a geopressured test well that had been abandoned as a dry hole but became a commercial producer of hydrocarbons is presented. A number of special topical reports pertaining to test activities performed on Department of Energy test wells (MG-T/DOE Amoco Fee No. 1 Well, Leroy Sweezy No. 1 Well, and Pleasant Bayou No. 2 Well) are appended. A referenced article written under this study that appeared in the Journal of Petroleum Technology is also reproduced.

  1. Geopressured habitat: A literature review

    SciTech Connect (OSTI)

    Negus-de Wys, Jane

    1992-09-01

    A literature review of the geopressured-geothermal habitat is summarized. Findings are presented and discussed with respect to the principal topics: Casual agents are both geological and geochemical; they include disequilibrium compaction of sediments, clay diagenesis, aquathermal pressuring, hydrocarbon generation, and lateral tectonic compression. The overall physical and chemical characteristics of the habitats are dictated by varying combinations of sedimentation rates, alteration mineralogy, permeability, porosity and pressure, temperature, fluid content and chemistry, and hydrodynamic flow. Habitat pressure seals are considered in terms of their formation processes, geologic characteristics, and physical behavior, including pressure release and reservoir pressure recharge on a geologic time scale. World-wide occurrence of geopressured-geothermal habitats is noted. The main thrust of this topic concerns the U.S.A. and Canada; in addition, reference is made to occurrences in China and indications from deep-sea vents, as well as the contribution of paleo-overpressure to habitat initiation and maintenance. Identification and assessment of the habitat is addressed in relation to use of hydrogeologic, geophysical, geochemical, and geothermic techniques, as well as well-logging and drill-stem-test data. Conclusions concerning the adequacy of the current state of knowledge and its applicability to resource exploration and development are set forth, together with recommendations for the thrust of future work.

  2. Low Temperature/Coproduced/Geopressured Subprogram Overview | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Low Temperature/Coproduced/Geopressured Subprogram Overview Low Temperature/Coproduced/Geopressured Subprogram Overview This overview of GTP's Low Temperature/Coproduced/Geopressured subprogram was given at GTP's Program Peer Review on May 18, 2010. overview_lowtemp.pdf (387.96 KB) More Documents & Publications AAPG Low-Temperature Webinar SMU Geothermal Conference 2011 - Geothermal Technologies Program Geothermal Energy Production with Co-produced and Geopressured Resources (Fact

  3. Geopressured geothermal bibliography. Volume 1 (citation extracts)

    SciTech Connect (OSTI)

    Hill, T.R.; Sepehrnoori, K.

    1981-08-01

    This bibliography was compiled by the Center for Energy Studies at The University of Texas at Austin to serve as a tool for researchers in the field of geopressured geothermal energy resources. The bibliography represents citations of papers on geopressured geothermal energy resources over the past eighteen years. Topics covered in the bibliography range from the technical aspects of geopressured geothermal reservoirs to social, environmental, and legal aspects of tapping those reservoirs for their energy resources. The bibliography currently contains more than 750 entries. For quick reference to a given topic, the citations are indexed into five divisions: author, category, conference title, descriptor, and sponsor. These indexes are arranged alphabetically and cross-referenced by page number.

  4. Geopressured-geothermal well activities in Louisiana

    SciTech Connect (OSTI)

    John, C.J.

    1992-10-01

    Since September 1978, microseismic networks have operated continuously around US Department of Energy (DOE) geopressured-geothermal well sites to monitor any microearthquake activity in the well vicinity. Microseismic monitoring is necessary before flow testing at a well site to establish the level of local background seismicity. Once flow testing has begun, well development may affect ground elevations and/or may activate growth faults, which are characteristic of the coastal region of southern Louisiana and southeastern Texas where these geopressured-geothermal wells are located. The microseismic networks are designed to detest small-scale local earthquakes indicative of such fault activation. Even after flow testing has ceased, monitoring continues to assess any microearthquake activity delayed by the time dependence of stress migration within the earth. Current monitoring shows no microseismicity in the geopressured-geothermal prospect areas before, during, or after flow testing.

  5. Environmental impact of geopressure - geothermal cogeneration facility on wetland resources and socioeconomic characteristics in Louisiana Gulf Coast region. Final report, October 10, 1983-September 31, 1984

    SciTech Connect (OSTI)

    Smalley, A.M.; Saleh, F.M.S.; Fontenot, M.

    1984-08-01

    Baseline data relevant to air quality are presented. The following are also included: geology and resource assessment, design well prospects in southwestern Louisiana, water quality monitoring, chemical analysis subsidence, microseismicity, geopressure-geothermal subsidence modeling, models of compaction and subsidence, sampling handling and preparation, brine chemistry, wetland resources, socioeconomic characteristics, impacts on wetlands, salinity, toxic metals, non-metal toxicants, temperature, subsidence, and socioeconomic impacts. (MHR)

  6. Geothermal Energy Production with Co-produced and Geopressured Resources

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (Fact Sheet), Geothermal Technologies Program (GTP) | Department of Energy Energy Production with Co-produced and Geopressured Resources (Fact Sheet), Geothermal Technologies Program (GTP) Geothermal Energy Production with Co-produced and Geopressured Resources (Fact Sheet), Geothermal Technologies Program (GTP) This fact sheet provides an overview of geothermal energy production using co-produced and geopressured resources. low_temp_copro_fs.pdf (587.5 KB) More Documents & Publications

  7. Geopressure geothermal energy conversion: the supercritical propane cycle for power generation

    SciTech Connect (OSTI)

    Goldsberry, F.L.; Bebout, D.G.; Bachman, A.L.

    1981-01-01

    The development of the geopressure geothermal unconventional gas resource has been the object of a drilling and reservoir testing program. One aspect of the assessment has been to look at the geothermal component of the energy base as a source of power generation. The basic production unit for the resource has been estimated to be a well capable of producing fluid at a rate of 15,000 to 40,000 BPD at temperatures of 240 to 360/sup 0/F (.0276 to .0736 M/sup 3//sec at 338 to 455/sup 0/K). The spacing of these wells will be approximately 2 to 4 km for effective reservoir drainage. This limits the generation capacity, per well from 700 to 3000 kW per site. It is assumed that interconnecting pipelines to carry brine from each well to a central location and then return it to salt water disposal wells will be impractical. Single well power plants with electrical gathering systems are considered to be the probable mode of development. The thermodynamic envelope within which the plant must operate is defined by the linear cooling curve of the brine and the ambient air temperature. The low resource temperature calls for a Rankine cycle. A supercritical propane cycle was selected. The only component of the thermal power system subject to uncertainty is the brine/propane heater. At the present time a scale/corrosion pilot plant is being operated on a number of geopressure test wells to determine inexpensive scale and corrosion inhibitors that may be used to reduce fouling of the exchanger tubes.

  8. Recovery Act: Demonstrating The Commercial Feasibility OfGeopressured...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lake Field, Cameron Parish, Louisiana Recovery Act: Demonstrating The Commercial Feasibility Of Geopressured-Geothermal Power Generation At Sweet Lake Field, Cameron Parish, ...

  9. FINAL TECHNICAL REPORT, U.S. Department of Energy: Award No. DE-EE0002855 "Demonstrating the Commercial Feasibility of Geopressured-Geothermal Power Development at Sweet Lake Field - Cameron Parish, Louisiana"

    SciTech Connect (OSTI)

    Gayle, Phillip A., Jr.

    2012-01-13

    The goal of the project was to demonstrate the commercial feasibility of geopressured-geothermal power development by exploiting the extraordinarily high pressured hot brines know to exist at depth near the Sweet Lake oil and gas field in Cameron Parish, Louisiana. The existence of a geopressured-geothermal system at Sweet Lake was confirmed in the 1970's and 1980's as part of DOE's Geopressured-Geothermal Program. That program showed that the energy prices at the time could not support commercial production of the resource. Increased electricity prices and technological advancements over the last two decades, combined with the current national support for developing clean, renewable energy and the job creation it would entail, provided the justification necessary to reevaluate the commercial feasibility of power generation from this vast resource.

  10. Evaluation of potential geopressure geothermal test sites in southern Louisiana

    SciTech Connect (OSTI)

    Bassiouni, Z.

    1980-04-01

    Six geopressured-geothermal prospects in southern Louisiana were studied in detail to assess their potential use as test sites for the production of geopressure-geothermal energy. Each of the six sites contains substantial quantities of energy. Three of these prospects, Grand Lake, Lake Theriot, and Bayou Hebert, appear to be suitable for a test site. A summary of the findings is presented.

  11. Geopressured Geothermal Resource and Recoverable Energy Estimate for the Wilcox and Frio Formations, Texas (Presentation)

    SciTech Connect (OSTI)

    Esposito, A.; Augustine, C.

    2011-10-01

    An estimate of the total and recoverable geopressured geothermal resource of the fairways in the Wilcox and Frio formations is made using the current data available. The flow rate of water and methane for wells located in the geopressured geothermal fairways is simulated over a 20-year period utilizing the TOUGH2 Reservoir Simulator and research data. The model incorporates relative permeability, capillary pressure, rock compressibility, and leakage from the bounding shale layers. The simulations show that permeability, porosity, pressure, sandstone thickness, well spacing, and gas saturation in the sandstone have a significant impact on the percent of energy recovered. The results also predict lower average well production flow rates and a significantly higher production of natural gas relative to water than in previous studies done from 1975 to 1980. Previous studies underestimate the amount of methane produced with hot brine. Based on the work completed in this study, multiphase flow processes and reservoir boundary conditions greatly influence the total quantity of the fluid produced as well as the ratio of gas and water in the produced fluid.

  12. The feasibility of recovering medium to heavy oil using geopressured- geothermal fluids

    SciTech Connect (OSTI)

    Negus-de Wys, J.; Kimmell, C.E.; Hart, G.F.; Plum, M.M.

    1991-09-01

    The feasibility, economics and environmental concerns of producing more domestic oil using thermal enhanced oil recovery (TEOR) are reviewed and the unique nature of geopressured-geothermal (GPGT) fluids for thermal recovery are outlined. Current methods of TEOR are briefly discussed and it is noted that these methods are presently under scrutiny by both federal and state air quality agencies; and moreover, they often involve costly operational and mechanical problems associated with heating water on the surface for injection into the target reservoir. The characteristics of the GPGT resources as seen through previous Department of Energy (DOE) studies from sites in Louisiana and Texas are discussed. These studies indicate sufficient quantities of GPGT fluids can be produced to sustain a TEOR project. The Alworth Field in the south Texas Mirando Trend is proposed as a TEOR pilot site. The target reservoirs for injection of the GPGT fluids are the Jackson and Yegua sandstones of the upper Eocene Epoch. The reservoirs contain an estimated 4 MMbbls of heavy oil in place (OIP) (18.6{degree}API) of which it is estimated that at least 1 MMbbls could be recovered by TEOR. The problems associated with using the GPGT fluids for TEOR include those normally associated with hot water flooding but in addition the reaction of the brine from the geopressured-geothermal reservoir with the target reservoir is uncertain. Under the elevated temperatures associated with GPGT TEOR, actual increased porosity and permeability are possible. 120 refs., 40 figs., 13 tabs.

  13. Survey of potential geopressured resource areas in California. Final report

    SciTech Connect (OSTI)

    Sanyal, S.K.; Robertson-Tait, A.; Kraemer, M.; Buening, N.

    1993-03-01

    This paper presents the initial results of a survey of the occurrence and characteristics of geopressured fluid resources in California using the publicly- available database involving more than 150,000 oil and gas wells drilled in the State. Of the 975 documented on-shore oil and gas pools studied, about 42% were identified as potentially geopressured. Geothermal gradients in California oil and gas fields lie within the normal range of 1 F to 2 F per 100 feet. Except for the Los Angeles Basin, there was no evidence of higher temperatures or temperature gradients in geopressured pools.

  14. Testing geopressured geothermal reservoirs in existing wells: Detailed completion prognosis for geopressured-geothermal well of opportunity, prospect #2

    SciTech Connect (OSTI)

    1981-03-01

    A geopressured-geothermal test of Martin Exploration Company's Crown Zellerbach Well No. 2 will be conducted in the Tuscaloosa Trend. The Crown Zellerbach Well No. 1 will be converted to a saltwater disposal well for disposal of produced brine. The well is located in the Satsuma Area, Livingston parish, Louisiana. Eaton proposes to test the Tuscaloosa by perforating the 7 inch casing from 16,718 feet to 16,754 feet. The reservoir pressure at an intermediate formation depth of 16,736 feet is anticipated to be 12,010 psi and the temperature is anticipated to be 297 F. Calculated water salinity is 16,000 ppm. The well is expected to produce a maximum of 16,000 barrels of water a day with a gas content of 51 SCF/bbl. Eaton will re-enter the test well, clean out to 17,000 feet, run production casing and complete the well. The disposal well will be re-entered and completed in the 9-5/8 inch casing for disposal of produced brine. Testing will be conducted similar to previous Eaton annular flow WOO tests. An optional test from 16,462 feet to 16,490 feet may be performed after the original test and will require a workover with a rig on location to perform the plugback. The surface production equipment utilized on previous tests will be utilized on this test. The equipment has worked satisfactorily and all parties involved in the testing are familiar with its operation. Weatherly Engineering will operate the test equipment. The Institute of Gas Technology (IGT) and Mr. Don Clark will handle sampling, testing and reservoir engineering evaluation, respectively. wireline work required will be awarded on basis of bid evaluation. At the conclusion of the test period, the D.O.E. owned test equipment will be removed from the test site, the test and disposal wells plugged and abandoned and the sites restored to the satisfaction of all parties.

  15. Low-Temperature, Coproduced, and Geopressured Geothermal Power | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Low-Temperature, Coproduced, and Geopressured Geothermal Power Low-Temperature, Coproduced, and Geopressured Geothermal Power The Geothermal Technology Program (GTP) low-temperature subprogram aims to provide the global geothermal community with the means to achieve development and widespread deployment of economically viable, innovative, and scalable technologies-including those involving coproducts-that will capture a significant portion of the low-temperature geothermal resource

  16. Environmental Assessment: Geothermal Energy Geopressure Subprogram. Gulf Coast Well Drilling and Testing Activity (Frio, Wilcox, and Tuscaloosa Formations, Texas and Louisiana)

    SciTech Connect (OSTI)

    1981-09-01

    The Department of Energy (DOE) has initiated a program to evaluate the feasibility of developing the geothermal-geopressured energy resources of the Louisiana-Texas Gulf Coast. As part of this effort, DOE is contracting for the drilling of design wells to define the nature and extent of the geopressure resource. At each of several sites, one deep well (4000-6400 m) will be drilled and flow tested. One or more shallow wells will also be drilled to dispose of geopressured brines. Each site will require about 2 ha (5 acres) of land. Construction and initial flow testing will take approximately one year. If initial flow testing is successful, a continuous one-year duration flow test will take place at a rate of up to 6400 m{sup 3} (40,000 bbl) per day. Extensive tests will be conducted on the physical and chemical composition of the fluids, on their temperature and flow rate, on fluid disposal techniques, and on the reliability and performance of equipment. Each project will require a maximum of three years to complete drilling, testing, and site restoration.

  17. Parcperdue Geopressure -- Geothermal Project: Appendix E

    SciTech Connect (OSTI)

    Sweezy, L.R.

    1981-10-05

    The mechanical and transport properties and characteristics of rock samples obtained from DOW-DOE L.R. SWEEZY NO. 1 TEST WELL at the Parcperdue Geopressure/Geothermal Site have been investigated in the laboratory. Elastic moduli, compressibility, uniaxial compaction coefficient, strength, creep parameters, permeability, acoustic velocities (all at reservoir conditions) and changes in these quantities induced by simulated reservoir production have been obtained from tests on several sandstone and shale samples from different depths. Most important results are that the compaction coefficients are approximately an order of magnitude lower than those generally accepted for the reservoir sand in the Gulf Coast area and that the creep behavior is significant. Geologic characterization includes lithological description, SEM micrographs and mercury intrusion tests to obtain pore distributions. Petrographic analysis shows that approximately half of the total sand interval has excellent reservoir potential and that most of the effective porosity in the Cib Jeff Sand is formed by secondary porosity development.

  18. Viscous heavy brines

    SciTech Connect (OSTI)

    House, R.F.; Hoover, L.D.

    1984-07-10

    Hydroxyethyl cellulose and a sequestrant are added to a heavy brine containing one or more salts selected from calcium chloride, calcium bromide, and zinc bromide to increase the viscosity of the brine. Preferably the brine contains zinc bromide, has a density in the range from about 14.2-19.2 pounds per gallon, and the sequestrant is a polyphosphonic acid or water soluble salt thereof.

  19. Laboratory development and field application of a novel water-based drill-in fluid for geopressured horizontal wells

    SciTech Connect (OSTI)

    Dobson, J.W.; Harrison, J.C.; Hale, A.H.

    1996-12-31

    Research has identified a novel water-based drill-in fluid for drilling and completing geopressured horizontal wells. This fluid has a unique combination of properties which make it especially suitable for geopressured applications. They include the use of calcium and/or zinc bromide as a base brine, minimal concentration of calcium carbonate as bridging material, low plastic viscosity, tight fluid loss control, good filter cake properties, and excellent return permeability. This drill-in fluid has been used successfully to drill a 1,200 foot production interval, 4.75 inch diameter wellbore in the Gulf of Mexico with a system weight of 13.2 lbm/gal, bottom hole temperature of 185{degrees} F., and a 1400 to 1700 psi overbalance. The system functioned very well in both the drilling and completion operations. Fluid rheology was easily maintainable and the hole conditions were excellent without torque or drag problems. Initial production data suggests that the well is producing at expected rates with low drawdown pressure.

  20. Thickened heavy brines

    SciTech Connect (OSTI)

    House, R.F.; Hoover, L.D.

    1983-12-13

    A thickened brine solution useful as a well servicing fluid is prepared, said solution consisting essentially of water, at least 20% by weight zinc bromide, calcium bromide, and a viscosifying amount of hydroxyethyl cellulose.

  1. Analysis of Sweet Lake geopressured-geothermal aquifer

    SciTech Connect (OSTI)

    Andrade, M.; Rago, F.M.; Ohkuma, H.; Sepehrnoori, K.; Peters, E.; Dorfman, M.

    1983-01-01

    The Sweet Lake geopressured-geothermal aquifer, located southeast of Lake Charles, Louisiana, is an aquifer modeled by a two-dimensional geopressured-geothermal simulator. This aquifer is a sandstone within the Frio formation at depths between 15,000 to 15,640 ft with a net porous thickness of 250 ft, a calculated in-situ permeability (from drawdown data) of 17 md, an estimated porosity of 24 percent, a uniaxial compaction coefficient of 4.5 x 10/sup -7/ psi/sup -1/ and a solution gas-water ratio of 11 SCF/STB all at the initial reservoir pressure of 12,060 psi. These parameters are typically pressure sensitive in geopressured-geothermal aquifers and are critically important to aquifer performance. Several simulation experiments are conducted which investigate the effects of varying initial values for these parameters with the experimentally determined values as means. The simulations give both optimistic and pessimistic expectations for aquifer performance. The expected life of the geopressured-geothermal well is reported for each simulation.

  2. Analysis of Sweet Lake geopressured-geothermal aquifer

    SciTech Connect (OSTI)

    Andrade, M.; Rago, F.; Ohkuma, H.; Sepehrnoori, K.; Peters, E.; Dorfman, M.

    1982-01-01

    The Sweet Lake geopressured-geothermal aquifer, located southeast of Lake Charles, Louisiana, is modeled by a two-dimensional geopressured-geothermal simulator. This aquifer is a sandstone within the Frio formation at depths between 15,000 to 15,640 ft with a net porous thickness of 250 ft, a calculated in-situ permeability (from drawdown data) of 17 md, an estimated porosity of 24%, a uniaxial compaction coefficient of 4.5 x 10/sup -7/ psi/sup -1/ and a solution gas-water ratio of 11 SCF/STB all at the initial reservoir pressure of 12,060 psi. These parameters are typically pressure sensitive in geopressured-geothermal aquifers and are critically important to aquifer performance. Several simulation experiments are conducted which investigate the effects of varying initial values for these parameters with the experimentally determined values as means. The simulations give both optimistic and pessimistic expectations for aquifer performance. The expected life of the geopressured-geothermal well is reported for each simulation.

  3. Geopressured geothermal bibliography. Volume I. Citation extracts. Second edition

    SciTech Connect (OSTI)

    Sepehrnoori, K.; Carter, F.; Schneider, R.; Street, S.; McGill, K.

    1983-05-01

    This annoted bibliography contains 1131 citations. It represents reports, papers, and articles appearing over the past eighteen years covering topics from the scientific and technical aspects of geopressured geothermal reservoirs to the social, environmental, and legal considerations of exploiting those reservoirs for their energy resources. Six indexes include: author, conference title, descriptor, journal title, report number, and sponsor. (MHR)

  4. T-F and S/DOE Gladys McCall No. 1 well, Cameron Parish, Louisiana. Geopressured-geothermal well report, Volume II. Well workover and production testing, February 1982-October 1985. Final report. Part 1

    SciTech Connect (OSTI)

    Not Available

    1985-01-01

    The T-F and S/DOE Gladys McCall No. 1 well was the fourth in a series of wells in the DOE Design Wells Program that were drilled into deep, large geopressured-geothermal brine aquifers in order to provide basic data with which to determine the technological and economic viability of producing energy from these unconventional resources. This brine production well was spudded on May 27, 1981 and drilling operations were completed on November 2, 1981 after using 160 days of rig time. The well was drilled to a total depth of 16,510 feet. The target sands lie at a depth of 14,412 to 15,860 feet in the Fleming Formation of the lower Miocene. This report covers well production testing operations and necessary well workover operations during the February 1982 to October 1985 period. The primary goals of the well testing program were: (1) to determine reservoir size, shape, volume, drive mechanisms, and other reservoir parameters, (2) to determine and demonstrate the technological and economic viability of producing energy from a geopressured-geothermal brine aquifer through long-term production testing, and (3) to determine problem areas associated with such long-term production, and to develop solutions therefor.

  5. Evaluation of land ownership, lease status, and surface features in five geopressured geothermal prospects

    SciTech Connect (OSTI)

    Hackenbracht, W.N.

    1981-05-01

    This study was accomplished for the purpose of gathering information pertaining to land and lease ownership, surface features and use and relevant environmental factors in the Lake Theriot (West and East), Kaplan, Bayou Hebert and Freshwater Bayou geopressured geothermal prospects in Louisiana, and the Blessing geopressured geothermal prospect in Texas. This information and recommendations predicated upon it will then be used to augment engineering and geological data utilized to select geopressured geothermal test well sites within the prospects. The five geopressured geothermal prospects are briefly described and recommendations given.

  6. Technical support for geopressured-geothermal well activities in Louisiana

    SciTech Connect (OSTI)

    Not Available

    1991-07-01

    Continuous recording microearthquake monitoring networks have been established around US Department of Energy (DOE) geopressured-geothermal design wells in southwestern Louisiana and southeastern Texas since summer 1980 to assess the effects well development may have had on subsidence and growth-fault activation. This monitoring has shown several unusual characteristics of Gulf Coast seismic activity. The observed activity is classified into two dominant types, one with identifiable body phases (type 1) and the other with only surface-wave signatures (type 2). During this reporting period no type 1 or body-wave events were reported. A total of 230 type 2 or surface-wave events were recorded. Origins of the type 2 events are still not positively understood; however, little or no evidence is available to connect them with geopressured-geothermal well activity. We continue to suspect sonic booms from military aircraft or some other human-induced source. 37 refs., 16 figs., 6 tabs.

  7. Brine stability study

    SciTech Connect (OSTI)

    Gary Garland

    2015-04-15

    This is a study of the brine formulations that we were using in our testing were stable over time. The data includes charts, as well as, all of the original data from the ICP-MS runs to complete this study.

  8. Gulf Coast geopressured-geothermal program summary report compilation. Volume 2-B: Resource description, program history, wells tested, university and company based research, site restoration

    SciTech Connect (OSTI)

    John, C.J.; Maciasz, G.; Harder, B.J.

    1998-06-01

    The US Department of Energy established a geopressured-geothermal energy program in the mid 1970`s as one response to America`s need to develop alternate energy resources in view of the increasing dependence on imported fossil fuel energy. This program continued for 17 years and approximately two hundred million dollars were expended for various types of research and well testing to thoroughly investigate this alternative energy source. This volume describes the following studies: Design well program; LaFourche Crossing; MG-T/DOE Amoco Fee No. 1 (Sweet Lake); Environmental monitoring at Sweet Lake; Air quality; Water quality; Microseismic monitoring; Subsidence; Dow/DOE L.R. Sweezy No. 1 well; Reservoir testing; Environmental monitoring at Parcperdue; Air monitoring; Water runoff; Groundwater; Microseismic events; Subsidence; Environmental consideration at site; Gladys McCall No. 1 well; Test results of Gladys McCall; Hydrocarbons in production gas and brine; Environmental monitoring at the Gladys McCall site; Pleasant Bayou No. 2 well; Pleasant Bayou hybrid power system; Environmental monitoring at Pleasant Bayou; and Plug abandonment and well site restoration of three geopressured-geothermal test sites. 197 figs., 64 tabs.

  9. Comparison of estimated and background subsidence rates in Texas-Louisiana geopressured geothermal areas

    SciTech Connect (OSTI)

    Lee, L.M.; Clayton, M.; Everingham, J.; Harding, R.C.; Massa, A.

    1982-06-01

    A comparison of background and potential geopressured geothermal development-related subsidence rates is given. Estimated potential geopressured-related rates at six prospects are presented. The effect of subsidence on the Texas-Louisiana Gulf Coast is examined including the various associated ground movements and the possible effects of these ground movements on surficial processes. The relationships between ecosystems and subsidence, including the capability of geologic and biologic systems to adapt to subsidence, are analyzed. The actual potential for environmental impact caused by potential geopressured-related subsidence at each of four prospects is addressed. (MHR)

  10. Operational testing of geopressure geothermal wells on the Gulf Coast

    SciTech Connect (OSTI)

    Goldsberry, F.L.

    1983-01-01

    A combined-cycle electric-power and pipeline-gas production process is proposed for the exploitation of the geopressured geothermal resource. It allows the operator to shift a portion of the production between the electric grid and the gas pipeline markets. On-site equipment and operating labor requirements are minimized. Thermal efficiencies are based upon sound application of thermodynamic principles and are competitive with large-scale plant operations. The economics presented are based upon 1983 avoided power costs and NGPA Section 102 gas prices.

  11. Geologic analysis of Devonian Shale cores

    SciTech Connect (OSTI)

    1982-02-01

    Cleveland Cliffs Iron Company was awarded a DOE contract in December 1977 for field retrieval and laboratory analysis of cores from the Devonian shales of the following eleven states: Michigan, Illinois, Indiana, Ohio, New York, Pennsylvania, West Virginia, Maryland, Kentucky, Tennessee and Virginia. The purpose of this project is to explore these areas to determine the amount of natural gas being produced from the Devonian shales. The physical properties testing of the rock specimens were performed under subcontract at Michigan Technological University (MTU). The study also included LANDSAT information, geochemical research, structural sedimentary and tectonic data. Following the introduction, and background of the project this report covers the following: field retrieval procedures; laboratory procedures; geologic analysis (by state); references and appendices. (ATT)

  12. Water Resource Assessment of Geothermal Resources and Water Use in Geopressured Geothermal Systems

    SciTech Connect (OSTI)

    Clark, C. E.; Harto, C. B.; Troppe, W. A.

    2011-09-01

    This technical report from Argonne National Laboratory presents an assessment of fresh water demand for future growth in utility-scale geothermal power generation and an analysis of fresh water use in low-temperature geopressured geothermal power generation systems.

  13. Gulf Coast geopressured-geothermal program summary report compilation. Volume 4: Bibliography (annotated only for all major reports)

    SciTech Connect (OSTI)

    John, C.J.; Maciasz, G.; Harder, B.J.

    1998-06-01

    This bibliography contains US Department of Energy sponsored Geopressured-Geothermal reports published after 1984. Reports published prior to 1984 are documented in the Geopressured Geothermal bibliography Volumes 1, 2, and 3 that the Center for Energy Studies at the University of Texas at Austin compiled in May 1985. It represents reports, papers and articles covering topics from the scientific and technical aspects of geopressured geothermal reservoirs to the social, environmental, and legal considerations of exploiting those reservoirs for their energy resources.

  14. Testing geopressured geothermal reservoirs in existing wells: Detailed completions prognosis for geopressured-geothermal well of opportunity, prospect #1

    SciTech Connect (OSTI)

    Kennedy, Clovis A.

    1980-04-03

    This prospective well of opportunity was originally drilled and completed as a gas producer by Wrightsman Investment Company in early 1973. The original and present producing interval was from 15,216 to 15,238 feet. IMC Exploration Company, Inc. acquired the property from Wrightsman and is the present owner operator. The well is presently shut in s a non-economic producer and IMC proposed to perform plug and abandonment operations in April, 1980. This well has a good geopressured-geothermal water sand behind the 5-1/2 inch casing that has 94 feet of net sand thickness. Pursuant to DOE/NVO authorization of March 11,1980, Eaton negotiated an option agreement with IMC whereby IMC would delay their abandonment operations for a period of 90 days to permit DOE to evaluate the well for geopressure-geothermal testing. The IMC-Eaton option agreements provide that IMG will delay plugging the well until June 15, 1980. If Eaton exercises its option to acquire the well, IMC will sell the well bore, and an adjacent salt water disposal well, to Eaton for the sole consideration of Eaton assuming the obligation to plug and abandon the wells in accordance with lease and regulatory requirements. If Eaton does not exercise its option, then Eaton will pay IMC $95,000 cash and IMC will proceed with plugging and abandonment at the termination of the option period.

  15. THIRD GEOPRESSURED-GEOTHERMAL ENERGY CONFERENCE University of...

    Office of Scientific and Technical Information (OSTI)

    ... increasing depth (Fig. 15) (De Sitter, 1947; Bredehoeft et al, 1963; Dickey, 1966; ... Geology: v . 2, p. 195-197. De Sitter, L. U . , 1947, Diagenesis of oil-field brines: Am. ...

  16. Hydraulic accumulator-compressor for geopressured enhanced oil recovery

    DOE Patents [OSTI]

    Goldsberry, Fred L.

    1988-01-01

    A hydraulic accumulator-compressor vessel using geothermal brine under pressure as a piston to compress waste (CO.sub.2 rich) gas is used in a system having a plurality of gas separators in tandem to recover pipeline quality gas from geothermal brine. A first high pressure separator feeds gas to a membrance separator which separates low pressure waste gas from high pressure quality gas. A second separator produces low pressure waste gas. Waste gas from both separators is combined and fed into the vessel through a port at the top as the vessel is drained for another compression cycle. High pressure brine is then admitted into the vessel through a port at the bottom of the vessel. Check valves control the flow of low pressure waste gas into the vessel and high pressure waste gas out of the vessel.

  17. Identification of geopressured occurrences outside of the Gulf Coast. Final report, Phase I

    SciTech Connect (OSTI)

    Strongin, O.

    1980-09-30

    As an extension of its efforts in the development of the geopressured resources of the Gulf Coast, the Division of Geothermal Energy of the US Department of Energy is interested in determining the extent and characteristics of geopressured occurrences in areas outside the Gulf Coast. The work undertaken involved a literature search of available information documenting such occurrences. Geopressured reservoirs have been reported from various types of sedimentary lithologies representing virtually all geologic ages and in a host of geologic environments, many of which are unlike those of the Gulf Coast. These include many Rocky Mountain basins (Green River, Big Horn, Powder River, Wind River, Uinta, Piceance, Denver, San Juan), Mid-Continent basins (Delaware, Anadorko, Interior Salt, Williston, Appalachian), California basins (Sacramento, San Joaquin, Los Angeles, Ventura, Coast Ranges), Alaskan onshore and offshore basins, Pacific Coast offshore basins, and other isolated occurrences, both onshore and offshore.

  18. Geopressured-geothermal well activities in Louisiana. Annual report, 1 January 1991--31 December 1991

    SciTech Connect (OSTI)

    John, C.J.

    1992-10-01

    Since September 1978, microseismic networks have operated continuously around US Department of Energy (DOE) geopressured-geothermal well sites to monitor any microearthquake activity in the well vicinity. Microseismic monitoring is necessary before flow testing at a well site to establish the level of local background seismicity. Once flow testing has begun, well development may affect ground elevations and/or may activate growth faults, which are characteristic of the coastal region of southern Louisiana and southeastern Texas where these geopressured-geothermal wells are located. The microseismic networks are designed to detest small-scale local earthquakes indicative of such fault activation. Even after flow testing has ceased, monitoring continues to assess any microearthquake activity delayed by the time dependence of stress migration within the earth. Current monitoring shows no microseismicity in the geopressured-geothermal prospect areas before, during, or after flow testing.

  19. The feasibility of applying geopressured-geothermal resources to direct uses

    SciTech Connect (OSTI)

    Lunis, B.C.; Negus-de Wys, J.; Plum, M.M. ); Lienau, P.J. . Geo-Heat Center); Spencer, F.J. ); Nitschke, G.F. )

    1991-09-01

    This study concludes that direct use technologies, especially desalinated water production, can contribute significantly to the value added process and the overall economic viability in developing a geopressured resource. Although agriculture and aquaculture applications are marginal projects when they are the only use of a geopressured well, the small margin of profitability can contribute to improving the overall economics of the direct use development. The added complexity from a technical and management aspect may add to the overall risk and unpredictability of the project. Six combination of direct uses received economic evaluation that resulted in 15% discounted payback periods ranging from 4 to over 10 years. Many other combinations are possible depending on the resource and market variables. Selection of appropriate technologies and sizes of applications will be established by the developer that engages in geopressured resource utilization. Currently, many areas of the country where geopressured resources are located also have surplus electrical capacity and generation, thus power utilities have been selling power for less than 2 cents per kWH, well below a reasonable breakeven value for geopressured produced electricity. However, when the energy demand of the integrated geopressured facility is large enough to install power generation equipment, operating expenses can be reduced by not paying the 10 to 12 cents per kWH utility rate. The study includes an analysis of a geothermal turbine unit installed with a desalination and an agriculture/aquaculture facility, taking advantage of the cascading energy values. Results suggest that this scenario becomes profitable only where the market price for electricity exceeds five cents per kWH.

  20. Brine Sampling and Evaluation Program, 1991 report

    SciTech Connect (OSTI)

    Deal, D.E.; Abitz, R.J.; Myers, J.; Martin, M.L.; Milligan, D.J.; Sobocinski, R.W.; Lipponer, P.P.J.; Belski, D.S.

    1993-09-01

    The data presented in this report are the result of Brine Sampling and Evaluation Program (BSEP) activities at the Waste Isolation Pilot Plan (WIPP) during 1991. These BSEP activities document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation and seepage of that brine into the excavations at the WIPP. When excavations began at the WIPP in 1982, small brine seepages (weeps) were observed on the walls. Brine studies began as part of the Site Validation Program and were formalized as a program in its own right in 1985. During nine years of observations (1982--1991), evidence has mounted that the amount of brine seeping into the WIPP excavations is limited, local, and only a small fraction of that required to produce hydrogen gas by corroding the metal in the waste drums and waste inventory. The data through 1990 is discussed in detail and summarized by Deal and others (1991). The data presented in this report describes progress made during the calendar year 1991 and focuses on four major areas: (1) quantification of the amount of brine seeping across vertical surfaces in the WIPP excavations (brine ``weeps); (2) monitoring of brine inflow, e.g., measuring brines recovered from holes drilled downward from the underground drifts (downholes), upward from the underground drifts (upholes), and from subhorizontal holes; (3) further characterization of brine geochemistry; and (4) preliminary quantification of the amount of brine that might be released by squeezing the underconsolidated clays present in the Salado Formation.

  1. Viscous heavy brine completion fluids. [Oil wells

    SciTech Connect (OSTI)

    Darlington, R.K.; Hunter, D.V.

    1982-01-01

    An activated hydroxyethyl cellulose (HEC) has been developed which will viscosify brines of any density up to 19.2 lb/gal containing calcium chloride, calcium bromide and/or zinc bromide. The use of activated hydroxyethyl cellulose allows preparation of viscosified brines at ambient emperature and without undissolved polymer solids. The time required to prepare a viscosified brine is greatly reduced. In addition, the rheology of brines viscosified with activated HEC can be accurately predicted allowing brines with equivalent solution rheology properties to be prepared batch after batch. 29 refs.

  2. Improved Water Flooding through Injection Brine Modification

    SciTech Connect (OSTI)

    Robertson, Eric Partridge; Thomas, Charles Phillip; Morrow, Norman

    2003-01-01

    Crude oil/brine/rock interactions can lead to large variations in the displacement efficiency of waterflooding, by far the most widely applied method of improved oil recovery. Laboratory waterflood tests show that injection of dilute brine can increase oil recovery. Numerous fields in the Powder River basin have been waterflooded using low salinity brine (about 500 ppm) from the Madison limestone or Fox Hills sandstone. Although many uncertainties arise in the interpretation and comparison of field production data, injection of low salinity brine appears to give higher recovery compared to brine of moderate salinity (about 7,000 ppm). Laboratory studies of the effect of brine composition on oil recovery cover a wide range of rock types and crude oils. Oil recovery increases using low salinity brine as the injection water ranged from a low of no notable increase to as much as 37.0% depending on the system being studied. Recovery increases using low salinity brine after establishing residual oil saturation (tertiary mode) ranged from no significant increase to 6.0%. Tests with two sets of reservoir cores and crude oil indicated slight improvement in recovery for low salinity brine. Crude oil type and rock type (particularly the presence and distribution of kaolinite) both play a dominant role in the effect that brine composition has on waterflood oil recovery.

  3. Subsurface geology and potential for geopressured-geothermal energy in the Turtle Bayou field-Kent Bayou field area, Terrebonne Parish, Louisiana

    SciTech Connect (OSTI)

    Moore, D.R.

    1982-09-01

    A 216 square mile area approximately 65 miles southwest of New Orleans, Louisiana, has been geologically evaluated to determine its potential for geopressured-geothermal energy production. The structural and stratigraphic analyses were made with emphasis upon the Early and Middle Miocene age sediments which lie close to and within the geopressured section. Three geopressured sands, the Robulus (43) sand, Cibicides opima sand, and Cristellaria (I) sand, are evaluated for their potential of producing geothermal energy. Two of these sands, the Robulus (43) sand and the Cibicides opima sand, meet several of the United States Department of Energy's suggested minimum requirements for a prospective geopressured-geothermal energy reservoir.

  4. Brine disposal process for Morcinek coal mine

    SciTech Connect (OSTI)

    Tait, J.H.

    1995-04-01

    This paper describes the work to develop a commercial brine disposal process for the Morcinek mine, located 45 km south of the city of Katowice in Poland. Currently, brine is discharged into the Odra river and methane from the mine is released into the atmosphere. The process would use the released methane and convert a large percentage of the brine into potable water for commercial use. Thus, the proposed process has two environmental benefits. The brine salinity is about 31,100 ppm. Major brine components are Na (10,300 ppm), Ca (1,170 ppm), Mg (460 ppm), Cl (18,500 ppm) and SO{sub 4}{sup 2-} (252 ppm). Present in smaller amounts are K, S, Sr, B, Ba and NO{sub 3}. The process integrates a reverse osmosis (RO) unit and a submerged combustion evaporator. Extensive studies made at the Lawrence Livermore National Laboratory established the pretreatment method of the brine before it enters the RO unit. Without adequate pretreatment, mineral phases in the brine would become super-saturated and would precipitate in the RO unit. The pretreatment consists of first adding sodium carbonate to increase both the pH and the carbonate concentration of the brine. This addition causes precipitation of carbonate solids containing Ca, Mg, Sr, and Ba. After filtration of these precipitates, the fluid is acidified with HCl to prevent precipitation in the RO unit as the brine increases in salinity.

  5. Brine Migration Experimental Studies for Salt Repositories

    Broader source: Energy.gov [DOE]

    Experiments were used to examine water content in Permian salt samples including impact of variation in thermal regime on water content of evaporites and other mineral species, behavior of brine inclusions in salt, and evolution of the gas/liquid brine/salt system.

  6. Summary Results for Brine Migration Modeling Performed by LANL...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Results for Brine Migration Modeling Performed by LANL, LBNL and SNL for the Used Fuel Disposition Program Summary Results for Brine Migration Modeling Performed by LANL, LBNL and ...

  7. Modeling acid-gas generation from boiling chloride brines (Journal...

    Office of Scientific and Technical Information (OSTI)

    Modeling acid-gas generation from boiling chloride brines Citation Details In-Document Search Title: Modeling acid-gas generation from boiling chloride brines This study ...

  8. Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Molecular Simulation of Carbon Dioxide, Brine, and Clay Mineral Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide, Brine, and Clay ...

  9. TOUGHREACT Testing in High Ionic Strength Brine Sandstone Systems...

    Office of Scientific and Technical Information (OSTI)

    Title: TOUGHREACT Testing in High Ionic Strength Brine Sandstone Systems Deep saline formations and oil and gas reservoirs often contain concentrated brine solutions of ionic ...

  10. Raft River Geothermal Field Well Head Brine Sample

    SciTech Connect (OSTI)

    Tim Lanyk

    2015-12-18

    Raw data and data workup of assay for real-world brine sample. Brine sample was taken at the well head.

  11. Assessment of the geothermal/geopressure potential of the Gulf Coastal Plan of Alabama. Final report

    SciTech Connect (OSTI)

    Wilson, G.V.; Wang, G.C.; Mancini, E.A.; Benson, D.J.

    1980-01-01

    Geothermal and geopressure as well as geologic and geophysical data were studied to evaluate the potential for future development of geothermal resources underlying the Alabama Coastal Plain. Wire-line log data compiled and interpreted from more than 1300 oil and gas test wells included maximum recorded temperatures, mud weights, rock resistivities as related to geopressure, formation tops, fault locations, and depths to basement rock. The Alabama Coastal Plain area is underlain by a conduction dominated, deep sedimentary basin where geothermal gradients are low to moderate (1.0 to 1.8/sup 0/F/100 feet). In some areas of southwest Alabama, abnormally high temperatures are found in association with geopressured zones within the Haynesville Formation of Jurassic age; however, rocks of poor reservoir quality dominate this formation, with the exception of a 200-square-mile area centered in southernmost Clarke County where a porous and permeable sand unit is encased within massive salt deposits of the lower Haynesville. The results of a petrograhic study of the Smackover Formation, which underlies the Haynesville, indicate that this carbonate rock unit has sufficient porosity in some areas to be considered a potential geothermal reservoir. Future development of geothermal resources in south Alabama will be restricted to low or moderate temperature, non-electric applications, which constitute a significant potential energy source for applications in space heating and cooling and certain agricultural and industrial processes.

  12. Industrial Consortium for the Utilization of the Geopressured-Geothermal Resource. Volume 2

    SciTech Connect (OSTI)

    Negus-deWys, J.

    1990-03-01

    The Geopressured-Geothermal Program, now in its fifteenth year, is entering the transition period to commercial use. The industry cost-shared proposals to the consortium, represented in the presentations included in these proceedings, attest to the interest developing in the industrial community in utilizing the geopressured-geothermal resource. Sixty-five participants attended these sessions, two-thirds of whom represented industry. The areas represented by cost-shared proposals include (1) thermal enhanced oil recovery, (2) direct process use of thermal energy, e.g., aquaculture and agriculture, (3) conversion of thermal energy to electricity, (4) environment related technologies, e.g., use of supercritical processes, and (5) operational proposals, e.g., a field manual for scale inhibitors. It is hoped that from this array of potential use projects, some will persist and be successful in proving the viability of using the geopressured-geothermal resource. Such industrial use of an alternative and relatively clean energy resource will benefit our nation and its people.

  13. Industrial Consortium for the Utilization of the Geopressured-Geothermal Resource. Volume 1

    SciTech Connect (OSTI)

    Negus-deWys, J.

    1990-03-01

    The Geopressured-Geothermal Program, now in its fifteenth year, is entering the transition period to commercial use. The industry cost-shared proposals to the consortium, represented in the presentations included in these proceedings, attest to the interest developing in the industrial community in utilizing the geopressured-geothermal resource. Sixty-five participants attended these sessions, two-thirds of whom represented industry. The areas represented by cost-shared proposals include (1) thermal enhanced oil recovery, (2) direct process use of thermal energy, e.g., aquaculture and agriculture, (3) conversion of thermal energy to electricity, (4) environment related technologies, e.g., use of supercritical processes, and (5) operational proposals, e.g., a field manual for scale inhibitors. It is hoped that from this array of potential use projects, some will persist and be successful in proving the viability of using the geopressured-geothermal resource. Such industrial use of an alternative and relatively clean energy resource will benefit our nation and its people.

  14. Geopressured-Geothermal Drilling and Testing Plan, Volume II, Testing Plan; Dow Chemical Co. - Dept. of Energy Dow-DOE Sweezy No. 1 Well, Vermilion Parish, Louisiana

    SciTech Connect (OSTI)

    1982-02-01

    The Dow/D.O.E. L. R. Sweezy No. 1 geopressured geothermal production well was completed in August of 1981. The well was perforated and gravel packed in approximately 50 feet of sand from 13,344 feet to 13,395 feet. Permeabilities of 6 to 914 millidarcies were measured with porosity of 25 to 36%. Static surface pressure after well clean-up was 5000 psi. At 1000 B/D flow rate the drawdown was 50 psi. The water produced in clean-up contained 100,000 ppm TDS. This report details the plan for testing this well with the goal of obtaining sufficient data to define the total production curve of the small, 939 acre, reservoir. A production time of six to nine months is anticipated. The salt water disposal well is expected to be completed and surface equipment installed such that production testing will begin by April 1, 1982. The program should be finished and reports written by February 28, 1983. The brine will be produced from the No.1 well, passed through a separator where the gas is removed, then reinjected into the No.2 (SWD) well under separator pressure. Flow rates of up to 25,000 B/D are expected. The tests are divided into a two-week short-term test and six to nine-month long-term tests with periodic downhole measurement of drawdown and buildup rates. Data obtained in the testing will be relayed by phoneline computer hookup to Otis Engineering in Dallas, Texas, where the reservoir calculations and modeling will be done. At the point where sufficient data has been obtained to reach the objectives of the program, production will be ended, the wells plugged and abandoned, and a final report will be issued.

  15. Geopressured-geothermal well report. Volume I. Drilling and completion

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    Gladys McCall site activities are covered through the completion of the test well and salt water disposal well. The test well was drilled to a total depth of 16,510 feet, then plugged back to 15,831 feet. Three 4'' diameter diamond cores were taken for analysis. An existing well on site, the Getty-Butts Gladys McCall No. 1, was reentered and completed to a depth of 3514 feet as a salt water disposal well. The geologic interpretation of the Gladys McCall site indicated target sands for testing at 15,080 feet through 15, 831 feet. Reservoir fluid temperature at this depth is estimated to be approximately 313/sup 0/F and pressure is estimated to be +-12,800 psi. The preliminary reservoir volume estimate is 3.6 billion barrels of brine. The design wells program includes environmental monitoring of the Gladys McCall site by Louisiana State University. Field stations are set up to monitor surface and ground water quality, subsidence, land loss and shoreline erosion, and seismicity. As of December 31, 1981 the study shows no significant impact on the environment by site operations.

  16. Evaluation of Devonian-shale potential in Ohio

    SciTech Connect (OSTI)

    Komar, C. A.

    1981-01-01

    The purpose of this report is to inform interested oil and gas operators about EGSP results as they pertain to the Devonian gas shales of the Appalachian basin in eastern Ohio. Geologic data and interpretations are summarized, and areas where the accumulation of gas may be large enough to justify commercial production are outlined. Because the data presented in this report are generalized and not suitable for evaluation of specific sites for exploration, the reader should consult the various reports cited for more detail and discussion of the data, concepts, and interpretations presented. A complete list of EGSP sponsored work pertinent to the Devonian shales in Ohio is contained as an appendix to this report. Radioactive shale zones are also mapped.

  17. Property:BrineConstituents | Open Energy Information

    Open Energy Info (EERE)

    Chloride type brine, "The content of potassium and calcium are high, while that of lithium, boron and sulfate is very low", See table 1 of Izquierdo et al. (2006). + Chena...

  18. How temperature and pressure affect clear brines

    SciTech Connect (OSTI)

    Hubbard, J.T.

    1984-04-01

    The correct application of the expansivity and compressibility of brine fluids under the influence of temperature and pressure is needed to calculate the actual hydrostatic pressure in a well. Well operations can benefit by reducing unintentional overbalance, lessening fluid losses, and lowering recommended fluid densities, hence reducing fluid costs. Since the early 1970s, the effects of temperature and pressure on the density of clear brine fluids have been questioned. As early as 1973, studies were started to define density loss with increased temperature in zinc bromide brines. This article describes a continuing study, begun in 1978, which has characterized the expansivity and compressibility of single salt brine solutions, such as are used in workover and completion fluids.

  19. Integrated process for coalbed brine disposal

    SciTech Connect (OSTI)

    Brandt, H. |; Bourcier, W.L.; Jackson, K.J.

    1994-03-01

    A brine disposal process is described that converts the brine stream of a coalbed gas producing site into clean water for agricultural use, combustion products and water vapor that can be released into the atmosphere and dry solids that can be recycled for industrial consumption. The process uses a reverse osmosis unit, a submerged combustion evaporator and a pulse combustion dryer. Pretreatment of the brine feedstream is necessary to prevent fouling of the membranes of the reverse osmosis unit and to separate from the brine stream hazardous metal and other constituents that may make the permeate from the reverse osmosis unit unsuitable for agricultural or other use. A chemical modeling code is used to calculate the saturation states of solids that may precipitate and foul the reverse osmosis membranes. Sodium carbonate is added to the brine to precipitate carbonates of Ba, Ca, Mg and Sr prior to filtration, acidification, and passage into the reverse osmosis unit. Optimization of the process in terms of types and amounts of additives is possible with analysis using the modeling code. The minimum amounts of additives to prevent scaling are calculated. In a typical operation, a brine feedstream of 1,000 m{sup 3}/day (6,290 bpd) that may have a total dissolved salt concentration (TDS) of 7,000 ppm will be separated into a permeate stream of 750 m{sup 3}/day (4,718 bpd) with a TDS of 400 ppm and a concentrated brine stream of 250 m{sup 3}/day (1,573 bpd) with a TDS of 26,800 ppm. The submerged combustion evaporator will concentrate this latter stream to a concentration of 268,000 ppm and reduce the volume to 25 m{sup 3}/day (158 bpd). The pulse combustion dryer can dry the concentrated brine mixture to a low moisture salt. Energy costs to operate the reverse osmosis unit are primarily the pumping costs.

  20. Geologic, geophysical, and geochemical aspects of site-specific studies of the geopressured-geothermal energy resource of southern Louisiana. Final report

    SciTech Connect (OSTI)

    Pilger, R.H. Jr.

    1985-01-01

    The report consists of four sections dealing with progress in evaluating geologic, geochemical, and geophysical aspects of geopressured-geothermal energy resources in Louisiana. Separate abstracts have been prepared for the individual sections. (ACR)

  1. Investigation and evaluation of geopressured-geothermal wells. Summary of Gruy Federal's Well-of-Opportunity Program to January 31, 1980

    SciTech Connect (OSTI)

    Not Available

    1980-03-01

    Scouting and monitoring techniques peculiar to geopressured-geothermal wells and legal problems are presented. The following are tabulated: priority wells actively monitored, industry contacts, and the summary of industry responses to well-or-opportunity solicitation. (MHR)

  2. Contractor for geopressured-geothermal sites: Final contract report, Volume 1, fiscal years 1986--1990 (5 years), testing of wells through October 1990

    SciTech Connect (OSTI)

    Not Available

    1992-09-01

    Field tests and studies were conducted to determine the production behavior of geopressured-geothermal reservoirs and their potential as future energy sources. Results are presented for Gladys McCall Site, Pleasant Bayou Site, and Hulin Site.

  3. Brine flow in heated geologic salt.

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L.; Malama, Bwalya

    2013-03-01

    This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes' governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

  4. Portable brine evaporator unit, process, and system

    DOE Patents [OSTI]

    Hart, Paul John; Miller, Bruce G.; Wincek, Ronald T.; Decker, Glenn E.; Johnson, David K.

    2009-04-07

    The present invention discloses a comprehensive, efficient, and cost effective portable evaporator unit, method, and system for the treatment of brine. The evaporator unit, method, and system require a pretreatment process that removes heavy metals, crude oil, and other contaminates in preparation for the evaporator unit. The pretreatment and the evaporator unit, method, and system process metals and brine at the site where they are generated (the well site). Thus, saving significant money to producers who can avoid present and future increases in transportation costs.

  5. Method of removing benzene from petroleum desalter brine

    SciTech Connect (OSTI)

    Hart, P.R.

    1993-08-17

    A method is described for removing benzene from petroleum refinery desalter effluent brine containing dispersed oil, solids, oily solids and benzene comprising contacting the brine with a sufficient amount for the purpose of flocculating oily solids of a combination of a aluminum chlorohydrate and a water soluble cationic polymer selected from the group consisting of polyamines and dialkyldiallylammonium polymers, in a ratio of from 1:10 to 100:1 at a temperature of about 250 F, separating the resulting floc from the brine; and thereafter contacting the brine with a sufficient amount for the purpose of reducing benzene levels in the brine of an oil solvent in combination with a demulsifier.

  6. Expected brine movement at potential nuclear waste repository salt sites

    SciTech Connect (OSTI)

    McCauley, V.S.; Raines, G.E.

    1987-08-01

    The BRINEMIG brine migration code predicts rates and quantities of brine migration to a waste package emplaced in a high-level nuclear waste repository in salt. The BRINEMIG code is an explicit time-marching finite-difference code that solves a mass balance equation and uses the Jenks equation to predict velocities of brine migration. Predictions were made for the seven potentially acceptable salt sites under consideration as locations for the first US high-level nuclear waste repository. Predicted total quantities of accumulated brine were on the order of 1 m/sup 3/ brine per waste package or less. Less brine accumulation is expected at domal salt sites because of the lower initial moisture contents relative to bedded salt sites. Less total accumulation of brine is predicted for spent fuel than for commercial high-level waste because of the lower temperatures generated by spent fuel. 11 refs., 36 figs., 29 tabs.

  7. Laboratory determination of mechanical properties of rocks from the Parcperdue geopressured/geothermal site

    SciTech Connect (OSTI)

    Sinha, K.P.; Borschel, T.F.; Holland, M.T.; Schatz, J.F.; Bebout, D.G.; Bachman, A.L.

    1981-01-01

    The deformational behavior and fluid flow characteristics of rock samples obtained from DOW/DOE L.R. Sweezy No. 1 Test Well at the Parcperdue Geopressured/Geothermal Site have been investigated in the laboratory. Elastic moduli, compressibility, uniaxial compaction coefficient, strength, creep parameters, permeability, acoustic velocites (all at reservoir conditions) and changes in these quantities induced by simulated reservoir production have been obtained from tests on several sandstone and shale samples from different depths. Tests consisting of several hydrostatic and triaxial loading phases and pore pressure reduction were designed to provide measurements to be used for calculating several of the above mentioned parameters in a single test. Pore volume changes were measured during some phases of the tests.

  8. Variable pressure supercritical Rankine cycle for integrated natural gas and power production from the geopressured geothermal resource

    SciTech Connect (OSTI)

    Goldsberry, F.L.

    1982-03-01

    A small-scale power plant cycle that utilizes both a variable pressure vaporizer (heater) and a floating pressure (and temperature) air-cooled condenser is described. Further, it defends this choice on the basis of classical thermodynamics and minimum capital cost by supporting these conclusions with actual comparative examples. The application suggested is for the geopressured geothermal resource. The arguments cited in this application apply to any process (petrochemical, nuclear, etc.) involving waste heat recovery.

  9. Environmental analysis of geopressured-geothermal prospect areas, De Witt and Colorado counties, Texas. Final report, March 1 - August 31, 1979

    SciTech Connect (OSTI)

    Gustavson, T.C.; Reeder, F.S.; Badger, E.A.

    1980-02-01

    Information collected and analyzed for a preliminary environmental analysis of geopressured geothermal prospect areas in Colorado and DeWitt Counties, Texas is presented. Specific environmental concerns for each geopressured geothermal prospect area are identified and discussed. Approximately 218 km/sup 2/(85 mi/sup 2/) were studied in the vicinity of each prospect area to: (1) conduct an environmental analysis to identify more and less suited areas for geopressured test wells; and (2) provide an environmental data base for future development of geopressured geothermal energy resources. A series of maps and tables are included to illustrate environmental characteristics including: geology, water resources, soils, current land use, vegetation, wildlife, and meteorological characteristics, and additional relevant information on cultural resources, power- and pipelines, and regulatory agencies. A series of transparent overlays at the scale of the original mapping has also been produced for the purposes of identifying and ranking areas of potential conflict between geopressured geothermal development and environmental characteristics. The methodology for ranking suitability of areas within the two prospect areas is discussed in the appendix. (MHR)

  10. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and...

    Office of Scientific and Technical Information (OSTI)

    Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer Citation Details In-Document Search Title: Geochemical Impacts of Carbon ...

  11. Molecular Simulation of Carbon Dioxide Brine and Clay Mineral...

    Office of Scientific and Technical Information (OSTI)

    of Carbon Dioxide Brine and Clay Mineral Interactions and Determination of Contact Angles. Citation Details In-Document Search Title: Molecular Simulation of Carbon Dioxide ...

  12. Fate of Magnesium Chloride Brine Applied to Suppress Dust from...

    Office of Scientific and Technical Information (OSTI)

    Within the deep vadose zone, which consists of interlayered basalt lava flows and sedimentary interbeds, brine has moved up to 110 m laterally. This lateral migration suggests ...

  13. Origin, distribution, and movement of brine in the Permian Basin (U. S. A. ). A model for displacement of connate brine

    SciTech Connect (OSTI)

    Bein, A.; Dutton, A.R. )

    1993-06-01

    Na-Cl, halite Ca-Cl, and gypsum Ca-Cl brines with salinities from 45 to >300 g/L are identified and mapped in four hydrostratigraphic units in the Permian Basin area beneath western Texas and Oklahoma and eastern New Mexico, providing spatial and lithologic constraints on the interpretation of the origin and movement of brine. Na-Cl brine is derived from meteoric water as young as 5-10 Ma that dissolved anhydrite and halite, whereas Ca-Cl brine is interpreted to be ancient, modified-connate Permian brine that now is mixing with, and being displaced by, the Na-Cl brine. Displacement fronts appear as broad mixing zones with no significant salinity gradients. Evolution of Ca-Cl brine composition from ideal evaporated sea water is attributed to dolomitization and syndepositional recycling of halite and bittern salts by intermittent influx of fresh water and sea water. Halite Ca-Cl brine in the evaporite section in the northern part of the basin differs from gypsum Ca-Cl brine in the south-central part in salinity and Na/Cl ratio and reflects segregation between halite- and gypsum-precipitating lagoons during the Permian. Ca-Cl brine moved downward through the evaporite section into the underlying Lower Permian and Pennsylvanian marine section that is now the deep-basin brine aquifer, mixing there with pre-existing sea water. Buoyancy-driven convection of brine dominated local flow for most of basin history, with regional advection governed by topographically related forces dominant only for the past 5 to 10 Ma. 71 refs., 11 figs.

  14. Reduce completion fluid costs with on-site brine tests

    SciTech Connect (OSTI)

    Thomas, D.C.; Darlington, R.K.; Kinney, W.R.; Lowell, J.L.

    1982-09-01

    A newly developed field kit makes on-site brine completion fluid testing practical. Simple titration procedures are used to analyze brine for calcium, zinc, chloride and bromide with an accuracy and repeatability that compares favorably with expensive laboratory techniques. This article describes the field testing theory and details analytical procedures used.

  15. Evaluation of EL836 explosive stimulation of Devonian gas shale

    SciTech Connect (OSTI)

    Barbour, T G

    1980-07-01

    This report presents an evaluation of EL836, an explosive developed at E.I. duPont de Nemours and Company Laboratories, in stimulating gas shale. EL836 is a water gel type explosive with a high aluminum content. The computational evaluation of EL836 involved four one-dimensional cyclindrical geometry calculations to assess the influence of two equation-of-state descriptios of EL836, the effect or rock yielding and the effect of internal crack pressurization. Results of a computational evaluation of the EL836 explosive in stimulating Devonian gas shale suggest the following: Extensive plastic yielding will occur in a region immediate to the borehole. Extensive tensile fracture will occur in a region that begins at the outer boundary of plastic deformation and terminates at more than 100 borehole radii. Without a mechanism of ;near-wellbore fracture, such as crushing or pre-cracking during drilling or intentional borehole grooving, the plastic flow that occurs adjacent to the wellbore causes stress redistributions which prohibit early-time (less than a millisecond) tensile fracture immediate to the wellbore and thus prohibits gas penetration from the wellbore into the crack system. The barrier that the near-wellbore plastic zone presents to gas flow from the wellbore is reduced in radial dimension as time increases. Natural fractures in the wellbore wall or cataclysmic deformation and fracture adjacent to the wellbore, as a result of the explosive detonation, will likely assist in breaking down the barrier to gas flow. Very significatn enhancement is achieved in the EL836 stimulation treatment when gases penetrate the stress-wave induced radial cracks. Only minor differences were observed in the EL836 stimulation effects when comparison is made between two different explosive equations-of-state. 33 figures, 2 tables.

  16. Controls on reservoir development in Devonian Chert: Permian Basin, Texas

    SciTech Connect (OSTI)

    Ruppel, S.C.; Hovorka, S.D.

    1995-12-01

    Chert reservoirs of the Lower Devonian Thirtyone Formation contain a significant portion of the hydrocarbon resource in the Permian basin. More than 700 million bbl of oil have been produced from these rocks, and an equivalent amount of mobile oil remains. Effective exploitation of this sizable remaining resource, however, demands a comprehensive appreciation of the complex factors that have contributed to reservoir development. Analysis of Thirtyone Formation chert deposits in Three Bar field and elsewhere in the Permian basin indicates that reservoirs display substantial heterogeneity resulting from depositional, diagenetic, and structural processes. Large-scale reservoir geometries and finer scale, intra-reservoir heterogeneity are primarily attributable to original depositional processes. Despite facies variations, porosity development in these cherts is principally a result of variations in rates and products of early silica diagenesis. Because this diagenesis was in part a function of depositional facies architecture, porosity development follows original depositional patterns. In reservoirs such as Three Bar field, where the Thirtyone Formation has been unroofed by Pennsylvanian deformation, meteoric diagenesis has created additional heterogeneity by causing dissolution of chert and carbonate, especially in areas of higher density fracturing and faulting and along truncated reservoir margins. Structural deformation also has exerted direct controls on heterogeneity that are particularly noteworthy in reservoirs under waterflood. High-density fracture zones create preferred flow paths that result in nonuniform sweep through the reservoir. Faulting locally creates compartments by offsetting reservoir flow units. As such, the processes and models defined here improve understanding of the causes of heterogeneity in all Thirtyone chert reservoirs in the Permian basin and aid recovery of the sizable hydrocarbon resource remaining in these rocks.

  17. Radionuclide transport in sandstones with WIPP brine

    SciTech Connect (OSTI)

    Weed, H.C.; Bazan, F.; Fontanilla, J.; Garrison, J.; Rego, J.; Winslow, A.M.

    1981-02-01

    Retardation factors (R) have been measured for the transport of /sup 3/H, /sup 95m/Tc, and /sup 85/Sr in WIPP brine using St. Peter, Berea, Kayenta, and San Felipe sandstone cores. If tritium is assumed to have R=1, /sup 95m/Tc has R=1.0 to 1.3 and therefore is essentially not retarded. Strontium-85 has R = 1.0 to 1.3 on St. Peter, Berea, and Kayenta, but R=3 on San Felipe. This is attributed to sorption on the matrix material of San Felipe, which has 45 volume % matrix compared with 1 to 10 volume % for the others. Retardation factors (R/sub s/) for /sup 85/Sr calculated from static sorption measurements are unity for all the sandstones. Therefore, the static and transport results for /sup 85/Sr disagree in the case of San Felipe, but agree for St. Peter, Berea, and Kayenta.

  18. Technique for thermodynamic crystallization temperature of brine fluids

    SciTech Connect (OSTI)

    Clark, D.E.; Hubbard, J.T.

    1983-03-01

    The application of high density solids free brine fluids has proven to be technically and economically successful in hydrocarbon completion and workover operations. The use of inorganic salts such as calcium chloride, calcium bromide, zinc bromide, and sodium bromide has contributed to the development of complex salt systems. As the density and complexity of these systems becomes more detailed, the requirement for proper fluid design becomes increasingly important. When a brine solution is cooled sufficiently, a temperature is reached where the solution will be saturated. A further decrease in temperature will result in the precipitation of salt from the solution. The temperature at which this transpires, provided no super-cooling occurs, is the crystallization point of the solution. A correctly formulated solids free brine should have the optimum crystallization point for the temperature conditions it will encounter. A recently developed semiautomatic procedure constructs a cooling curve plot of each brine tested. This cooling curve plot allows the determination of the super-cooling potential, the Thermodynamic Crystallization Temperature, and the Last Crystal To Dissolve Temperature. The device provides a permanent record of the cooling curve with repeatable accuracy, which assists in the development of error free brine formulation tables, brine density, and/or crystallization point adjustments, and brine analysis.

  19. Formate brines -- New fluids for drilling and completions

    SciTech Connect (OSTI)

    Ramsey, M.S.; Shipp, J.A.

    1996-01-01

    The term ``formate brines`` refers broadly to three primary compounds dissolved in water -- sodium formate (NaCOOH), potassium formate (KCOOH) and cesium formate (CsCOOH). Each is chemically classified as an alkali-metal salt of formic acid. They offer properties that in many respects are superior to their predecessors, halide brines such as zinc bromide and calcium bromide, without the undesirable side effects of those more common halide brine systems. This article introduces the technology and provides an overview of published work to date regarding formates.

  20. An integrated approach to reservoir engineering at Pleasant Bayou Geopressured-Geothermal reservoir

    SciTech Connect (OSTI)

    Shook, G.M.

    1992-12-01

    A numerical model has been developed for the Pleasant Bayou Geothermal-Geopressured reservoir. This reservoir description is the result of integration of a variety of data, including geological and geophysical interpretations, pressure transient test analyses, and well operations. Transient test analyses suggested several enhancements to the geologic description provided by University of Texas Bureau of Economic Geology (BEG), including the presence of an internal fault not previously identified. The transient tests also suggested water influx from an adjacent aquifer during the long-term testing of Pleasant Bayou; comparisons between transient test analyses and the reservoir description from BEG suggests that this fault exhibits pressure-dependent behavior. Below some pressure difference across the fault, it remains a no-flow barrier; above this threshold pressure drop the barrier fails, and fluid moves across the fault. A history match exercise is presented, using the hypothesized {open_quotes}leaky fault.{close_quotes} Successful match of 4 years of production rates and estimates of average reservoir pressure supports the reservoir description developed herein. Sensitivity studies indicate that the degree of communication between the perforated interval and the upper and lower sands in the reservoir (termed {open_quotes}distal volume{close_quotes} by BEG) impact simulation results very little, whereas results are quite sensitive to storage and transport properties of this distal volume. The prediction phase of the study indicates that Pleasant Bayou is capable of producing 20,000 STB/d through 1997, with the final bottomhole pressure approximately 1600 psi above abandonment pressure.

  1. Strontium isotope quantification of siderite, brine and acid mine drainage contributions to abandoned gas well discharges in the Appalachian Plateau

    SciTech Connect (OSTI)

    Chapman, Elizabeth C.; Capo, Rosemary C.; Stewart, Brian W.; Hedin, Robert S.; Weaver, Theodore J.; Edenborn, Harry M.

    2013-04-01

    Unplugged abandoned oil and gas wells in the Appalachian region can serve as conduits for the movement of waters impacted by fossil fuel extraction. Strontium isotope and geochemical analysis indicate that artesian discharges of water with high total dissolved solids (TDS) from a series of gas wells in western Pennsylvania result from the infiltration of acidic, low Fe (Fe < 10 mg/L) coal mine drainage (AMD) into shallow, siderite (iron carbonate)-cemented sandstone aquifers. The acidity from the AMD promotes dissolution of the carbonate, and metal- and sulfate-contaminated waters rise to the surface through compromised abandoned gas well casings. Strontium isotope mixing models suggest that neither upward migration of oil and gas brines from Devonian reservoirs associated with the wells nor dissolution of abundant nodular siderite present in the mine spoil through which recharge water percolates contribute significantly to the artesian gas well discharges. Natural Sr isotope composition can be a sensitive tool in the characterization of complex groundwater interactions and can be used to distinguish between inputs from deep and shallow contamination sources, as well as between groundwater and mineralogically similar but stratigraphically distinct rock units. This is of particular relevance to regions such as the Appalachian Basin, where a legacy of coal, oil and gas exploration is coupled with ongoing and future natural gas drilling into deep reservoirs.

  2. Intergrated study of the Devonian-age black shales in eastern Ohio. Final report

    SciTech Connect (OSTI)

    Gray, J.D.; Struble, R.A.; Carlton, R.W.; Hodges, D.A.; Honeycutt, F.M.; Kingsbury, R.H.; Knapp, N.F.; Majchszak, F.L.; Stith, D.A.

    1982-09-01

    This integrated study of the Devonian-age shales in eastern Ohio by the Ohio Department of Natural Resources, Division of Geological Survey is part of the Eastern Gas Shales Project sponsored by the US Department of Energy. The six areas of research included in the study are: (1) detailed stratigraphic mapping, (2) detailed structure mapping, (3) mineralogic and petrographic characterization, (4) geochemical characterization, (5) fracture trace and lineament analysis, and (6) a gas-show monitoring program. The data generated by the study provide a basis for assessing the most promising stratigraphic horizons for occurrences of natural gas within the Devonian shale sequence and the most favorable geographic areas of the state for natural gas exploration and should be useful in the planning and design of production-stimulation techniques. Four major radioactive units in the Devonian shale sequence are believed to be important source rocks and reservoir beds for natural gas. In order of potential for development as an unconventional gas resource, they are (1) lower and upper radioactive facies of the Huron Shale Member of the Ohio Shale, (2) upper Olentangy Shale (Rhinestreet facies equivalent), (3) Cleveland Shale Member of the Ohio Shale, and (4) lower Olentangy Shale (Marcellus facies equivalent). These primary exploration targets are recommended on the basis of areal distribution, net thickness of radioactive shale, shows of natural gas, and drilling depth to the radioactive unit. Fracture trends indicate prospective areas for Devonian shale reservoirs. Good geological prospects in the Devonian shales should be located where the fracture trends coincide with thick sequences of organic-rich highly radioactive shale.

  3. Testing geopressured geothermal reservoirs in existing wells. Wells of Opportunity Program final contract report, 1980-1981

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    The geopressured-geothermal candidates for the Wells of Opportunity program were located by the screening of published information on oil industry activity and through direct contact with the oil and gas operators. This process resulted in the recommendation to the DOE of 33 candidate wells for the program. Seven of the 33 recommended wells were accepted for testing. Of these seven wells, six were actually tested. The first well, the No. 1 Kennedy, was acquired but not tested. The seventh well, the No. 1 Godchaux, was abandoned due to mechanical problems during re-entry. The well search activities, which culminated in the acceptance by the DOE of 7 recommended wells, were substantial. A total of 90,270 well reports were reviewed, leading to 1990 wells selected for thorough geological analysis. All of the reservoirs tested in this program have been restricted by one or more faults or permeability barriers. A comprehensive discussion of test results is presented.

  4. Operations research and systems analysis of geopressured-geothermal energy in Louisiana. Final report for the period June 1, 1978-August 31, 1979

    SciTech Connect (OSTI)

    Johnson, A.E. Jr.

    1980-11-01

    The primary purpose was to provide a projection of the probable future contribution of the geopressured-geothermal energy resource in Louisiana to the overall energy requirements of the nation. A number of associated objectives were emphasized: namely, development of the tools and methodology for performing economic analyses, application of these tools to specific prospects about which adequate resource assessments have been made, identification of the impediments to resource development, and socio-economic analysis of the impact of development of the resource on these specific prospects. An overview of the geopressured-geothermal resource activities in Louisiana is provided first, followed by a detailed discussion and review of the achievements of this project. Finally the major conclusions and findings of this project with respect to commercial viability, impediments, and social and economic impact are presented, and recommendations are made for future systems analysis work.

  5. World class Devonian potential seen in eastern Madre de Dios basin

    SciTech Connect (OSTI)

    Peters, K.E.; Wagner, J.B.; Carpenter, D.G.; Conrad, K.T.

    1997-02-17

    The Madre de Dios basin in northern Bolivia contains thick, laterally extensive, organic-rich Upper Devonian source rocks that reached the oil-generative stage of thermal maturity after trap and seal formation. Despite these facts, less than one dozen exploration wells have been drilled in the Madre de Dios basin, and no significant reserves have been discovered. Mobil geoscientists conducted a regional geological, geophysical, and geochemical study of the Madre de Dios basin. The work reported here was designed to assess the distribution, richness, depositional environment, and thermal maturity of Devonian source rocks. It is supported by data from over 3,000 m of continuous slimhole core in two of the five Mobil wells in the basin. Source potential also exists in Cretaceous, Mississippian, and Permian intervals. The results of this study have important implications for future exploration in Bolivia and Peru.

  6. The use of Devonian oil shales in the production of portland cement

    SciTech Connect (OSTI)

    Schultz, C.W.; Lamont, W.E.; Daniel, J.

    1991-12-31

    The Lafarge Corporation operates a cement plant at Alpena, Michigan in which Antrim shale, a Devonian oil shale, is used as part of the raw material mix. Using this precedent the authors examine the conditions and extent to which spent shale might be utilized in cement production. They conclude that the potential is limited in size and location but could provide substantial benefit to an oil shale operation meeting these criteria.

  7. The use of Devonian oil shales in the production of portland cement

    SciTech Connect (OSTI)

    Schultz, C.W.; Lamont, W.E. ); Daniel, J. )

    1991-01-01

    The Lafarge Corporation operates a cement plant at Alpena, Michigan in which Antrim shale, a Devonian oil shale, is used as part of the raw material mix. Using this precedent the authors examine the conditions and extent to which spent shale might be utilized in cement production. They conclude that the potential is limited in size and location but could provide substantial benefit to an oil shale operation meeting these criteria.

  8. Actinide (III) solubility in WIPP Brine: data summary and recommendations

    SciTech Connect (OSTI)

    Borkowski, Marian; Lucchini, Jean-Francois; Richmann, Michael K.; Reed, Donald T.

    2009-09-01

    The solubility of actinides in the +3 oxidation state is an important input into the Waste Isolation Pilot Plant (WIPP) performance assessment (PA) models that calculate potential actinide release from the WIPP repository. In this context, the solubility of neodymium(III) was determined as a function of pH, carbonate concentration, and WIPP brine composition. Additionally, we conducted a literature review on the solubility of +3 actinides under WIPP-related conditions. Neodymium(III) was used as a redox-invariant analog for the +3 oxidation state of americium and plutonium, which is the oxidation state that accounts for over 90% of the potential release from the WIPP through the dissolved brine release (DBR) mechanism, based on current WIPP performance assessment assumptions. These solubility data extend past studies to brine compositions that are more WIPP-relevant and cover a broader range of experimental conditions than past studies.

  9. Brine pH Modification Scale Control Technology. 2. A Review.pdf...

    Open Energy Info (EERE)

    Brine pH Modification Scale Control Technology. 2. A Review.pdf Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Brine pH Modification Scale...

  10. Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential...

    Office of Environmental Management (EM)

    Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential August 21, 2013 - 12:00am Addthis Utilizing a 1...

  11. Uranium (VI) solubility in carbonate-free ERDA-6 brine

    SciTech Connect (OSTI)

    Lucchini, Jean-francois; Khaing, Hnin; Reed, Donald T

    2010-01-01

    When present, uranium is usually an element of importance in a nuclear waste repository. In the Waste Isolation Pilot Plant (WIPP), uranium is the most prevalent actinide component by mass, with about 647 metric tons to be placed in the repository. Therefore, the chemistry of uranium, and especially its solubility in the WIPP conditions, needs to be well determined. Long-term experiments were performed to measure the solubility of uranium (VI) in carbonate-free ERDA-6 brine, a simulated WIPP brine, at pC{sub H+} values between 8 and 12.5. These data, obtained from the over-saturation approach, were the first repository-relevant data for the VI actinide oxidation state. The solubility trends observed pointed towards low uranium solubility in WIPP brines and a lack of amphotericity. At the expected pC{sub H+} in the WIPP ({approx} 9.5), measured uranium solubility approached 10{sup -7} M. The objective of these experiments was to establish a baseline solubility to further investigate the effects of carbonate complexation on uranium solubility in WIPP brines.

  12. Durability of concrete materials in high-magnesium brine

    SciTech Connect (OSTI)

    Wakeley, L.D.; Poole, T.S.; Burkes, J.P.

    1994-03-01

    Cement pastes and mortars representing 11 combinations of candidate concrete materials were cast in the laboratory and monitored for susceptibility to chemical deterioration in high-magnesium brine. Mixtures were selected to include materials included in the current leading candidate concrete for seals at the Waste Isolation Pilot Plant (WIPP). Some materials were included in the experimental matrix to answer questions that had arisen during study of the concrete used for construction of the liner of the WIPP waste-handling shaft. Mixture combinations compared Class C and Class F fly ashes, presence or absence of an expansive component, and presence or absence of salt as a mixture component. Experimental conditions exposed the pastes and mortars to extreme conditions, those being very high levels of Mg ion and an effectively unlimited supply of brine. All pastes and mortars showed deterioration with brine exposure. In general, mortars deteriorated more extensively than the corresponding pastes. Two-inch cube specimens of mortar were not uniformly deteriorated, but showed obvious zoning even after a year in the brine, with a relatively unreacted zone remaining at the center of each cube. Loss of calcium from the calcium hydroxide of paste/aggregate interfaces caused measurable strength loss in the reacted zone comprising the outer portion of every mortar specimen. The current candidate mass concrete for WIPP seals includes salt as an initial component, and has a relatively closed initial microstructure. Both of these features contribute to its suitability for use in large placements within the Salado Formation.

  13. Investigation and evaluation of geopressured-geothermal wells. Final report, Tenneco Fee N No. 1 Well Terrebonne Paris, Louisiana

    SciTech Connect (OSTI)

    Dobson, R.J.; Hartsock, J.H.; McCoy, R.L.; Rodgers, J.A.

    1980-09-01

    The reservoir conditions that led to the choice of this well as the fifth well of opportunity are described as well as the attempts to complete the well for high-volume brine production. Individual opinions concerning underlying and conributing causes for the liner failure which aborted the completion attempt are included. (MHR)

  14. Progress on radiometric dating of Wolfcamp brines using /sup 4/He and /sup 40/Ar

    SciTech Connect (OSTI)

    Zaikowski, A.; Kosanke, B.J.; Hubbard, N.

    1984-01-01

    Ground water samples (brines) from deep wells in the Palo Duro Basin, Texas are being analyzed for noble gases in an attempt to obtain radiometric ages for these brines. The brines contain radiogenic /sup 4/He and /sup 40/Ar produced from the radioactive decay of U, Th, and K. Consideration of hydrochemical data for the brines, various isotopic, chemical, and mineralogical data for the aquifer rocks and noble gas production rates allow estimating the age of the brines to be about 130 million years at two wells. At a third well interaquifer mixing has occurred and the age is presently indeterminate. 9 references, 3 figures, 1 table.

  15. Conodonts of Bakken Formation (Devonian and Mississippian), Williston basin, North Dakota

    SciTech Connect (OSTI)

    Hayes, M.D.; Holland, F.D. Jr.

    1983-08-01

    The Bakken Formation is a thin (maximum 145 ft, 45 m), clastic unit in the subsurface of Williston basin in the United States and Canada. The Bakken is similar in lithologic character and stratigraphic position to other black shale units deposited on the North American craton during the Late Devonian and Early Mississippian. The Bakken was initially considered entirely Mississippian in age. Paleontologic study of regional physical equivalents and analysis of the macrofauna in Saskatchewan has suggested that the Bakken is actually both Devonian and Mississippian. Conodonts were obtained from cores of the Bakken in an effort to determine the age of the formation in North Dakota and to assess the oil generation potential. Nearly 700 conodonts have been recovered, but are unevenly distributed within the Bakken Formation. A majority was obtained from thin (approximately 0.5 cm), fossil-rich beds within the upper shale. Conodonts from the top of the upper shale reveal a Mississippian (Kinderhookian) age and are here assigned to the Lower Siphonodella crenulata Zone. Only rare, fragmentary conodonts have been found in the middle member. Conodont evidence from the middle of the lower shale suggests a late Devonian (Famennian) age (Upper Polygnathus styriacus Zone) for this member. Conodont color has been established as a geothermometer in carbonate rocks. Color alteration indices of conodonts from the Bakken range from 1.5 to approximately 2.5 and indicate a pattern of increasing temperature with depth. These results suggest possible hydrocarbon generation from shallower depths than has been reported previously for the Bakken. The lack of agreement in interpreted hydrocarbon generation depths may be due to, among other things, the clastic nature of the Bakken Formation.

  16. Industry participation in DOE-sponsored geopressured geothermal research development. Final report, May 1, 1979-April 30, 1982

    SciTech Connect (OSTI)

    Coffer, H.F.

    1982-07-01

    Nine DOE/Industry Forum meetings where the progress of DOE's resource development program was outlined and discussed were planned, organized, conducted, and reported. These nine forum meetings included three meetings of the Drilling and Testing group, two Site Selection meetings, one meeting each of the Legal and Environmental groups and two Overview meetings where the entire DOE program was discussed. Summaries of each of these meetings are included and the progress of DOE's geopressured geothermal resource evaluation program from its early beginnings to demonstration of the tremendous size and widespread availability of this supplementary energy resource are shown. Attendees at the meetings represented a broad cross section of state and federal agencies and potential users and developers of this large energy source. Attendance at meetings averages 50 to 80 with the most interest shown at meetings where reservoir testing results were discussed. In addition to the forums 16 newsletters were prepared and distributed to all participants. These were instituted to keep industry apprised of the latest developments in this DOE resource evaluation program. Three additional studies were carried out for DOE under this contract: a reservoir continuity study, a survey of gas stripping operations, and the development of a lease agreement for design well prospects.

  17. Subsidence in geopressured geothermal resource test sites: Monitoring assessment combining geodetic leveling and tidal control stations in southwestern Louisiana

    SciTech Connect (OSTI)

    Ramsey, K.E.; John, C.J. ); Trahan, D.B. )

    1989-09-01

    The Louisiana Geological Survey has an ongoing environmental monitoring program, sponsored by the US Department of Energy, at geopressured geothermal prospect well sites in southwestern Louisiana. This paper presents the results from monitoring subsidence at some of these reservoir sites. Over 1,000 km of first-order surveys and data from several NOAA and US Army Corps of Engineers tidal control stations were examined to determine regional trends. Tidal records were used to examine the history of sea level with respect to the land surface. Relative rates of land subsidence can be determined by comparing rates of water level rise over time with rates of rise from a stable craton. Regional subsidence ranges from 3 to 5 mm/year. First-order bench-mark networks established at Parcperdue, Sweet Lake, and Gladys McCall prospects were used to determine local trends of subsidence. Repeated leveling surveys before, during, and after fluid withdrawal from Parcperdue and Gladys McCall indicate that an increase in subsidence was observed during the drilling of the wells. Data suggest subsidence was possibly due to surface loading by heavy drilling equipment. Historical leveling in the Sweet Lake region indicates differential compaction between sediments as a possible cause for subsidence. However, in all cases, virtually no increase in subsidence was observed during and after times of fluid withdrawal.

  18. Shut-off of a geopressured water channel behind casing via coiled tubing utilizing a dual slurry cement system: A case history

    SciTech Connect (OSTI)

    Nowak, T.W.; Lange, K.J.; Grant, W.H.; Patout, T.S.

    1995-12-31

    This paper presents a case history involving a unique dual cement system to shut off a geopressured water channel behind casing utilizing coiled tubing. The channeling problem was identified and documented using water flow logging techniques. Logging indicated the lower gravel packed selective could produce salt water if perforated without eliminating the suspected water channel. Reserves did not warrant a major rig workover, making a non-rig workover via coiled tubing the only viable option to repair the well. A unique dual cement system tested on a hesitation squeeze schedule pumped through coiled tubing with extremely limited thickening time was necessary to repair the primary cement job.

  19. Modeling acid-gas generation from boiling chloride brines

    SciTech Connect (OSTI)

    Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

    2009-11-16

    This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent

  20. Sequence stratigraphy and depositional facies of the Silurian-Devonian interval of the northern Permian basin

    SciTech Connect (OSTI)

    Canter, K.L.; Geesaman, R.C. ); Wheeler, D. )

    1992-04-01

    The Silurian and Devonian intervals of the northern Central Basin platform area of west Texas and southeastern New Mexico include the Fusselman, Wristen, and Thirtyone formations and the Woodford Shale. The carbonate-rich Fusselman, Wristen, and Thirtyone formations record a transition from ramp to platform deposition. Oolite grainstones of the lower Fusselman Formation were deposited in a ramp setting during an Upper Ordovician/Lower Silurian transgression. The overlying crinoid packstones and grainstones represent shoals that developed along a break in slope separating the evolving platform from a southward-dipping starved basin. By the close of Fusselman deposition, the platform was well developed, with shallow peridtidal mudstones and wackestones, and high-energy grainstones deposited as near-parallel facies tracts over the platform area. The platform system became fully developed during the deposition of the Wristen Formation. Porous dolomitic peridtidal and platform margin facies grade downdip into nonporous, limy and argillaceous open-shelf facies. Platform facies are typified by numerous shallowing-upward parasequences that terminated at subaerial exposure surfaces. The rocks of the Lower Devonian Thirtyone Formation were deposited as a wedge that onlaps the exposed Silurian platform margin. This formation contains a porous, chert-rich, lowstand deposit; a transgressive disconformity; and variably porous, grain-rich highstand deposits representing an overall sea level rise. A major unconformity marks the contact between the karsted upper surface of the Thirtyone Formation and the overlying organic-rich, anoxic Woodford Shale.

  1. Pre-injection brine production for managing pressure in compartmentalized CO₂ storage reservoirs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Buscheck, Thomas A.; White, Joshua A.; Chen, Mingjie; Sun, Yunwei; Hao, Yue; Aines, Roger D.; Bourcier, William L.; Bielicki, Jeffrey M.

    2014-12-31

    We present a reservoir management approach for geologic CO₂ storage that combines CO₂ injection with brine extraction. In our approach,dual-mode wells are initially used to extract formation brine and subsequently used to inject CO₂. These wells can also be used to monitor the subsurface during pre-injection brine extraction so that key data is acquired and analyzed prior to CO₂ injection. The relationship between pressure drawdown during pre-injection brine extraction and pressure buildup during CO₂ injection directly informs reservoir managers about CO₂ storage capacity. These data facilitate proactive reservoir management, and thus reduce costs and risks. The brine may be usedmore » directly as make-up brine for nearby reservoir operations; it can also be desalinated and/or treated for a variety of beneficial uses.« less

  2. Pre-injection brine production for managing pressure in compartmentalized CO₂ storage reservoirs

    SciTech Connect (OSTI)

    Buscheck, Thomas A.; White, Joshua A.; Chen, Mingjie; Sun, Yunwei; Hao, Yue; Aines, Roger D.; Bourcier, William L.; Bielicki, Jeffrey M.

    2014-12-31

    We present a reservoir management approach for geologic CO₂ storage that combines CO₂ injection with brine extraction. In our approach,dual-mode wells are initially used to extract formation brine and subsequently used to inject CO₂. These wells can also be used to monitor the subsurface during pre-injection brine extraction so that key data is acquired and analyzed prior to CO₂ injection. The relationship between pressure drawdown during pre-injection brine extraction and pressure buildup during CO₂ injection directly informs reservoir managers about CO₂ storage capacity. These data facilitate proactive reservoir management, and thus reduce costs and risks. The brine may be used directly as make-up brine for nearby reservoir operations; it can also be desalinated and/or treated for a variety of beneficial uses.

  3. Gulf Coast geopressured-geothermal program summary report compilation. Volume 2-A: Resource description, program history, wells tested, university and company based research, site restoration

    SciTech Connect (OSTI)

    John, C.J.; Maciasz, G.; Harder, B.J.

    1998-06-01

    The US Department of Energy established a geopressured-geothermal energy program in the mid 1970`s as one response to America`s need to develop alternate energy resources in view of the increasing dependence on imported fossil fuel energy. This program continued for 17 years and approximately two hundred million dollars were expended for various types of research and well testing to thoroughly investigate this alternative energy source. This volume describes the following studies: Geopressured-geothermal resource description; Resource origin and sediment type; Gulf Coast resource extent; Resource estimates; Project history; Authorizing legislation; Program objectives; Perceived constraints; Program activities and structure; Well testing; Program management; Program cost summary; Funding history; Resource characterization; Wells of opportunity; Edna Delcambre No. 1 well; Edna Delcambre well recompletion; Fairfax Foster Sutter No. 2 well; Beulah Simon No. 2 well; P.E. Girouard No. 1 well; Prairie Canal No. 1 well; Crown Zellerbach No. 2 well; Alice C. Plantation No. 2 well; Tenneco Fee N No. 1 well; Pauline Kraft No. 1 well; Saldana well No. 2; G.M. Koelemay well No. 1; Willis Hulin No. 1 well; Investigations of other wells of opportunity; Clovis A. Kennedy No. 1 well; Watkins-Miller No. 1 well; Lucien J. Richard et al No. 1 well; and the C and K-Frank A. Godchaux, III, well No. 1.

  4. Simulation and economic evaluation of a solar evaporation system for concentrating sodium chloride brines

    SciTech Connect (OSTI)

    Smith, M.K.; Newell, T.A. )

    1991-01-01

    An hourly simulation program has been developed for detailed modelin of an evaporation surface (ES) and an evaporation pond (EP) for reconcentration of a solar pond's (SP's) surface brine. The results are relavant to other systems in which it is desirable to concentrate a brine. The simulation results are used in three ways: first, for general comparison of brine reconcentration performance for a variety of locations; second, development of an ES design method based on long term monthly averaged weather data; and third, an economic comparison between ESs and EPs. The results show that regions with moderate to high precipitation favor ESs over EPs. Dry climates will generally favor EPs for brine reconcentration.

  5. High-pressure mechanical and sonic properties of a Devonian shale from West Virginia

    SciTech Connect (OSTI)

    Heard, H.C.; Lin, W.

    1986-01-01

    Static mechanical properties and sonic velocities were determined on each of four members of the Devonian shale from Columbia Gas Transmission's well 20403, Huntington, West Virginia. They were: Pressure - volume data to 4.0 GPa; Compressive strength at confining pressures up to 300 MPa, both parallel and perpendicular to bedding. Extensile strength at 100 to 700 MPa confining pressure, both parallel and perpendicular to bedding. Loading and unloading path in uniaxial strain at 20 to 500 MPa confining pressure, both parallel and perpendicular to bedding. Tensile strength at ambient pressure, parallel and perpendicular to bedding. Shear and compressional wave velocities at confining pressures up to 1000 MPa parallel, at 45/sup 0/, and perpendicular to bedding. Results are presented and discussed. 32 refs., 10 figs., 10 tabs.

  6. Community Geothermal Technology Program: Electrodeposition of minerals in geothermal brine

    SciTech Connect (OSTI)

    Not Available

    1990-12-31

    Objective was to study the materials electrodeposited from geothermal brine, from the HGP-A well in Puna, Hawaii. Due to limitations, only one good set of electrodeposited material was obtained; crystallography indicates that vaterite forms first, followed by calcite and then perhaps aragonite as current density is increased. While the cost to weight ratio is reasonable, the deposition rate is very slow. More research is needed, such as reducing the brittleness. The electrodeposited material possibly could be used as building blocks, tables, benches, etc. 49 figs, 4 tabs, 7 refs.

  7. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2003-02-11

    Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, strategy is to inject CO{sub 2} into organic-rich shales of Devonian age. Devonian black shales underlie approximately two-thirds of Kentucky and are generally thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to the way methane is stored in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane at a ratio of two to one. Black shales may similarly desorb methane in the presence of CO{sub 2}. If black shales similarly desorb methane in the presence of CO{sub 2}, the shales may be an excellent sink for CO{sub 2} with the added benefit of serving to enhance natural gas production. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject this research. To accomplish this investigation, drill cuttings and cores will be selected from the Kentucky Geological Survey Well Sample and Core Library. CO{sub 2} adsorption analyses will be performed in order to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, new drill cuttings and sidewall core samples will be acquired to investigate specific black-shale facies, their uptake of CO{sub 2}, and the resultant displacement of methane. Advanced logging techniques (elemental capture spectroscopy) will be used to investigate possible correlations between adsorption capacity and geophysical log measurements.

  8. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2003-04-28

    Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, strategy is to inject CO{sub 2} into organic-rich shales of Devonian age. Devonian black shales underlie approximately two-thirds of Kentucky and are generally thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to the way methane is stored in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane at a ratio of two to one. Black shales may similarly desorb methane in the presence of CO{sub 2}. If black shales similarly desorb methane in the presence of CO{sub 2}, the shales may be an excellent sink for CO{sub 2} with the added benefit of serving to enhance natural gas production. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject this research. To accomplish this investigation, drill cuttings and cores will be selected from the Kentucky Geological Survey Well Sample and Core Library. CO{sub 2} adsorption analyses will be performed in order to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, new drill cuttings and sidewall core samples will be acquired to investigate specific black-shale facies, their uptake of CO{sub 2}, and the resultant displacement of methane. Advanced logging techniques (elemental capture spectroscopy) will be used to investigate possible correlations between adsorption capacity and geophysical log measurements.

  9. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2003-02-10

    Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, strategy is to inject CO{sub 2} into organic-rich shales of Devonian age. Devonian black shales underlie approximately two-thirds of Kentucky and are generally thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to the way methane is stored in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane at a ratio of two to one. Black shales may similarly desorb methane in the presence of CO{sub 2}. If black shales similarly desorb methane in the presence of CO{sub 2}, the shales may be an excellent sink for CO{sub 2} with the added benefit of serving to enhance natural gas production. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject this research. To accomplish this investigation, drill cuttings and cores will be selected from the Kentucky Geological Survey Well Sample and Core Library. CO{sub 2} adsorption analyses will be performed in order to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, new drill cuttings and sidewall core samples will be acquired to investigate specific black-shale facies, their uptake of CO{sub 2}, and the resultant displacement of methane. Advanced logging techniques (elemental capture spectroscopy) will be used to investigate possible correlations between adsorption capacity and geophysical log measurements.

  10. Computer program for predicting surface subsidence resulting from pressure depletion in geopressured wells: subsidence prediction for the DOW test well No. 1, Parcperdue, Louisiana

    SciTech Connect (OSTI)

    Janssen, J.C.; Carver, D.R.; Bebout, D.G.; Bachman, A.L.

    1981-01-01

    The nucleus-of-strain concept is used to construct a computer program for predicting surface subsidence due to pressure reduction in geopressured reservoirs. Numerical integration allows one to compute the vertical displacement of the ground surface directly above and beyond the aquifer boundaries which results from the pressure reduction in each of the small finite volumes into which the aquifer is partitioned. The program treats depth (measured from the surface to the mean thickness of the aquifer) as a constant. Variation in aquifer thickness is accounted for by linear interpolation from one boundary to its opposite. In this simple model, subsidence is proportional to the pressure reduction (considered constant in this presentation) and to but one physical parameter, Cm(1-..nu..), in which Cm is its coefficient of uniaxial compaction, and ..nu.. is Poisson's ratio.

  11. Technical support for geopressured-geothermal well activities in Louisiana: Annual report for the period 1 November 1984 to 31 December 1986

    SciTech Connect (OSTI)

    Groat, C.G.

    1987-09-01

    This report describes environmental monitoring activities carried out by Louisiana State University (LSU) under US Department of Energy Contract FC07-85NV10425 for the period 1 November 1984 through 31 December 1986. Other aspects of the LSU technical support program completed under prior contracts were covered in final form in reports preceding this one. During the contract period, the Louisiana Geological Survey, aided by subcontractors, monitored microseismic activity, land-surface subsidence, and surface and ground-water quality at three designed geopressured-geothermal test well sites in Louisiana and Texas. Don Stevenson supervised microseismic monitoring activities, and Drukell Trahan coordinated water quality and land-surface subsidence studies. This is a progress report in the sense that it discusses program components, provides raw data, and presents preliminary interpretations. The environmental monitoring program continues and will be the subject of subsequent annual reports.

  12. Chemical-equilibrium calculations for aqueous geothermal brines

    SciTech Connect (OSTI)

    Kerrisk, J.F.

    1981-05-01

    Results from four chemical-equilibrium computer programs, REDEQL.EPAK, GEOCHEM, WATEQF, and SENECA2, have been compared with experimental solubility data for some simple systems of interest with geothermal brines. Seven test cases involving solubilities of CaCO/sub 3/, amorphous SiO/sub 2/, CaSO/sub 4/, and BaSO/sub 4/ at various temperatures from 25 to 300/sup 0/C and in NaCl or HCl solutions of 0 to 4 molal have been examined. Significant differences between calculated results and experimental data occurred in some cases. These differences were traced to inaccuracies in free-energy or equilibrium-constant data and in activity coefficients used by the programs. Although currently available chemical-equilibrium programs can give reasonable results for these calculations, considerable care must be taken in the selection of free-energy data and methods of calculating activity coefficients.

  13. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2003-10-29

    CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. For the Devonian shale, average total organic carbon is 3.71 (as received) and mean random vitrinite reflectance is 1.16. Measured adsorption isotherm data range from 37.5 to 2,077.6 standard cubic feet of CO{sub 2} per ton (scf/ton) of

  14. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2004-01-01

    CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. For the Devonian shale, average total organic carbon is 3.71 (as received) and mean random vitrinite reflectance is 1.16. Measured adsorption isotherm data range from 37.5 to 2,077.6 standard cubic feet of CO{sub 2} per ton (scf/ton) of

  15. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2004-04-01

    CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. For the Devonian shale, average total organic carbon is 3.71 percent (as received) and mean random vitrinite reflectance is 1.16. Measured adsorption isotherm data range from 37.5 to 2,077.6 standard cubic feet of CO{sub 2} per ton (scf

  16. Inorganic geochemistry of Devonian shales in southern West Virginia: geographic and stratigraphic trends

    SciTech Connect (OSTI)

    Hohn, M.E.; Neal, D.W.; Renton, J.J.

    1980-04-01

    Samples of cuttings from twenty-one wells and a core from a single well in southern West Virginia were analyzed for major and minor elements: silicon, aluminum, iron, magnesium, calcium, sodium, titanium, phosphorus, manganese, sulfur, zinc, and strontium. Stratigraphic and geographic controls on elemental abundances were studied through canonical correlations, factor analyses, and trend surface analyses. The most abundant elements, silicon and aluminum, show gradual trends through the stratigraphic column of most wells, with silicon increasing and aluminum decreasing up-section. Other elements such as calcium, sulfur, and titanium change abruptly in abundance at certain stratigraphic boundaries. Important geographic trends run east-west: for instance, one can see an increase in sulfur and a decrease in titanium to the west; and a decrease in silicon from the east to the central part of the study area, then an increase further west. Although observed vertical trends in detrital minerals and geographic patterns in elemental abundances agree with the accepted view of a prograding delta complex during Late Devonian time, geographically-local, time restricted depositional processes influenced elemental percentages in subsets of the wells and the stratigraphic intervals studied. The black shales of lower Huron age do not represent simply a return of depositional conditions present in the earlier Rhinestreet time; nor do the gray shales of the Ohio Shale represent the same environmental conditions as the Big White Slate.

  17. Macrofossils of Bakken Formation (Devonian and Mississippian), Williston Basin, North Dakota

    SciTech Connect (OSTI)

    Thrasher, L.; Holland, F.D. Jr.

    1983-08-01

    Results of this study of the macrofossils of the Bakken Formation in North Dakota have reinforced the suggestion, based on previous paleontological work in Saskatchewan, that the Bakken is of both Devonian and Mississippian age, rather than being entirely of Lower Mississippian age as originally considered. Increased drilling and coring activity in the North Dakota part of the Williston Basin has provided the opportunity for acquiring a larger fauna that was previously available. Based on lithologic character, the Bakken has been divided into three informal members. These consist of a calcareous siltstone unit between two lithologically similar units of carbonaceous shale. These black shales contain similar faunas distinct from that of the middle member. The black shales contain inarticulate brachiopods, conchostracans, and rare cephalopods and fish remains as well as more abundant conodonts, ostracods, and palynomorphs. The middle siltstone unit contains a more abundant and diverse fauna consisting of inarticulate and articulate brachiopods together with corals, gastropods, cephalopods, ostracods, echinoderm remains, and trace fossils. This is the first report of cephalopods, conchostracans, ostracods, corals, trace fossils, and some of the brachiopods in the Bakken, although all, except the gastropods, have been reported from stratigraphic equivalents (Exshaw Formation of south-central Montana, the Leatham Formation of northeastern Utah, and the middle member of the Pilot Shale in western Utah and eastern Nevada).

  18. Calculation of brine properties. [Above 80/sup 0/F and for salt...

    Office of Scientific and Technical Information (OSTI)

    Brine saturation pressure is calculated as a percentage of the pure water saturation ... temperature and pressure and are obtained from the ASME equation-of-state for pure water. ...

  19. Study of thermal-gradient-induced migration of brine inclusions in salt. Final report

    SciTech Connect (OSTI)

    Olander, D.R.

    1984-08-01

    Natural salt deposits, which are being considered for high-level waste disposal, contain a small volume fraction of water in the form of brine inclusions distributed throughout the salt. Radioactive decay heating of the nuclear wastes will impose a temperature gradient on the surrounding salt which mobilizes the brine inclusions. Inclusions filled completely with brine (the all-liquid inclusions) migrate up the temperature gradient and eventually accumulate brine near the buried waste forms. The brine may slowly corrode or degrade the waste forms, which is undesirable. Therefore it is important to consider the migration of brine inclusions in salt under imposed temperature gradients to properly evaluate the performance of a future salt repository for nuclear wastes. The migration velocities of the inclusions were found to be dependent on temperature, temperature gradient, and inclusion shape and size. The velocities were also dictated by the interfacial mass transfer resistance at brine/solid interface. This interfacial resistance depends on the dislocation density in the crystal, which in turn, depends on the axial compressive loading of the crystal. At low axial loads, the dependence between the velocity and temperature gradient is nonlinear. At high axial loads, the interfacial resistance is reduced and the migration velocity depends linearly on the temperature gradient. All-liquid inclusions filled with mixed brines were also studied. For gas-liquid inclusions, helium, air and argon were compared. Migration studies were also conducted on single crystallites of natural salt as well as in polycrystalline natural salt samples. The behavior of the inclusions at large-ange grain boundaries was observed.

  20. Recovery of energy from geothermal brine and other hot water sources

    DOE Patents [OSTI]

    Wahl, III, Edward F.; Boucher, Frederic B.

    1981-01-01

    Process and system for recovery of energy from geothermal brines and other hot water sources, by direct contact heat exchange between the brine or hot water, and an immiscible working fluid, e.g. a hydrocarbon such as isobutane, in a heat exchange column, the brine or hot water therein flowing countercurrent to the flow of the working fluid. The column can be operated at subcritical, critical or above the critical pressure of the working fluid. Preferably, the column is provided with a plurality of sieve plates, and the heat exchange process and column, e.g. with respect to the design of such plates, number of plates employed, spacing between plates, area thereof, column diameter, and the like, are designed to achieve maximum throughput of brine or hot water and reduction in temperature differential at the respective stages or plates between the brine or hot water and the working fluid, and so minimize lost work and maximize efficiency, and minimize scale deposition from hot water containing fluid including salts, such as brine. Maximum throughput approximates minimum cost of electricity which can be produced by conversion of the recovered thermal energy to electrical energy.

  1. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2003-07-28

    CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. Initial estimates indicate a sequestration capacity of 5.3 billion tons CO{sub 2} in the Lower Huron Member of the Ohio shale in parts of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker portions of the

  2. Analysis of the structural parameters that influence gas production from the Devonian shale. Annual progress report, 1979-1980. Volume III. Data repository and reports published during fiscal year 1979-1980: production, unsponsored research

    SciTech Connect (OSTI)

    Negus-De Wys, J.; Dixon, J. M.; Evans, M. A.; Lee, K. D.; Ruotsala, J. E.; Wilson, T. H.; Williams, R. T.

    1980-10-01

    This document consists of the following papers: inorganic geochemistry studies of the Eastern Kentucky Gas Field; lithology studies of upper Devonian well cuttings in the Eastern Kentucky Gas Field; possible effects of plate tectonics on the Appalachian Devonian black shale production in eastern Kentucky; preliminary depositional model for upper Devonian Huron age organic black shale in the Eastern Kentucky Gas Field; the anatomy of a large Devonian black shale gas field; the Cottageville (Mount Alto) Gas Field, Jackson County, West Virginia: a case study of Devonian shale gas production; the Eastern Kentucky Gas Field: a geological study of the relationships of Ohio Shale gas occurrences to structure, stratigraphy, lithology, and inorganic geochemical parameters; and a statistical analysis of geochemical data for the Eastern Kentucky Gas Field.

  3. Bakken and other Devonian-Mississippian petroleum source rocks, northern Rocky Mtns.-Williston basin: Depositional and burial history and maturity estimations

    SciTech Connect (OSTI)

    Peterson, J.A.

    1996-06-01

    The three-member Devonian-Mississippian Bakken-Exshaw organic-rich shaly facies is widely distributed in the northern U.S. and southern Canadian Cordillera. Equivalent facies are also present as far south as Utah and Nevada. Paleogeographically, these rocks thin markedly or pinchout to the west approximately along the Devonian-Mississippian carbonate reef-mound belt of the Cordilleran shelf margin. Although these rocks reach maximum organic richness approximately at the Devonian-Carboniferous transition, similar but somewhat less organic-rich Bakken-like beds are also present in underlying Upper Devonian and overlying Lower Carboniferous carbonate depositional cycles. At least ten cycles are identified in the underlying Duperow and Jefferson Formations, characterized by basal organic-rich Bakken-like shale or shaly carbonate that grades upward into carbonate mound or reefal beds, overlain by evaporite or solution breccia. Cycles in the overlying Lodgepole and Mission Canyon Formations, as many as 10-12 in number, are similar except that the carbonates are composed of algal-oolith, crinoid, or mixed skeletal beds, and end-cycle evaporitic units are less prevalent in the lower cycles. These dark shaly beds are the most important source of hydrocarbon reserves in Montana and the Williston basin. Maximum net thickness of the Devonian-Mississippian organic-rich facies is in the Williston basin. However, variable thicknesses of these potential source rocks is present in parts of Montana as far west as the thrust belt. Burial history studies suggest that in some areas these rocks are probably thermally immature. However, in much of the area original burial depths are sufficient for them to reach the thermally mature stage, and therefore are of importance to further exploration efforts in the Devonian-Mississippian Madison-Duperow-Jefferson Formations.

  4. West Hackberry Strategic Petroleum Reserve site brine-disposal monitoring, Year I report. Volume III. Biological oceanography. Final report

    SciTech Connect (OSTI)

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J.

    1983-02-01

    The Department of Energy's Strategic Petroleum Reserve Program began discharging brine into the Gulf of Mexico from its West Hackberry site near Cameron, Louisiana in May 1981. The brine originates from underground salt domes being leached with water from the Intracoastal Waterway, making available vast underground storage caverns for crude oil. The effects of brine discharge on aquatic organisms are presented in this volume. The topics covered are: benthos; nekton; phytoplankton; zooplankton; and data management.

  5. Assessment of environmental health and safety issues associated with the commercialization of unconventional gas recovery: Devonian shale

    SciTech Connect (OSTI)

    Not Available

    1981-09-01

    The purpose of this study is to identify and examine potential public health and safety issues and the potential environmental impacts from recovery of natural gas from Devonian age shale. This document will serve as background data and information for planners within the government to assist in development of our new energy technologies in a timely and environmentally sound manner. This report describes the resource and the DOE eastern gas shales project in Section 2. Section 3 describes the new and developing recovery technologies associated with Devonian shale. An assessment of the environment, health and safety impacts associated with a typical fields is presented in Section 4. The typical field for this assessment occupies ten square miles and is developed on a 40-acre spacing (that is, there is a well in each 40-acre grid). This field thus has a total of 160 wells. Finally, Section 5 presents the conclusions and recommendations. A reference list is provided to give a greater plant. Based on the estimated plant cost and the various cases of operating income, an economic analysis was performed employing a profitability index criterion of discounted cash flow to determine an interest rate of return on the plant investment.

  6. Bibliography of the paleontology and paleoecology of the Devonian-Mississippian black-shale sequence in North America

    SciTech Connect (OSTI)

    Barron, L.S.; Ettensohn, F.R.

    1980-06-01

    The Devonian-Mississippian black-shale sequence is one of the most prominent and well-known stratigraphic horizons in the Paleozoic of the United States, yet the paleontology and its paleoecologic and paleoenvironmental implications are poorly known. This is in larger part related to the scarcity of fossils preserved in the shale - in terms of both diversity and abundance. Nonetheless, that biota which is preserved is well-known and much described, but there is little synthesis of this data. The first step in such a synthesis is the compilation of an inclusive bibliography such as this one. This bibliography contains 1193 entries covering all the major works dealing with Devonian-Mississippian black-shale paleontology and paleoecology in North America. Articles dealing with areas of peripheral interest, such as paleogeography, paleoclimatology, ocean circulation and chemistry, and modern analogues, are also cited. In the index, the various genera, taxonomic groups, and other general topics are cross-referenced to the cited articles. It is hoped that this compilation will aid in the synthesis of paleontologic and paleoecologic data toward a better understanding of these unique rocks and their role as a source of energy.

  7. Behavior of natural uranium, thorium, and radium isotopes in the Wolfcamp brine aquifers, Palo Duro Basin, Texas

    SciTech Connect (OSTI)

    Laul, J.C.; Smith, M.R.; Hubbard, N.

    1984-10-01

    Previously reported results for Palo Duro deep brines show that Ra is highly soluble and not retarded. Relative to Ra, U and Th are highly sorbed. Uranium, like thorium, is in the +4 valence state, indicating a reducing environment. Additional data reported here support these results. However, one Wolfcamp brine sample gives somewhat different results. Radium appears to be somewhat sorbed. Uranium is largely in the +6 valence state, indicating a less reducing condition. In all brines, kinetics for sorption (/sup 228/Th) and desorption (/sup 224/Ra) are rapid. This Wolfcamp brine was tested for the effects of colloids for Ra, U, and Th concentrations. No effects were found.

  8. Summary Results for Brine Migration Modeling Performed by LANL, LBNL and SNL for the Used Fuel Disposition Program

    Office of Energy Efficiency and Renewable Energy (EERE)

    The report summarizes laboratory and field observations and numerical modeling related to coupledprocesses involving brine and vapor migration in geologic salt, focusing on recent developments and...

  9. Factors controlling reservoir quality in tertiary sandstones and their significance to geopressured geothermal production. Annual report, May 1, 1979-May 31, 1980

    SciTech Connect (OSTI)

    Loucks, R.G.; Richmann, D.L.; Milliken, K.L.

    1980-07-01

    Differing extents of diagenetic modification is the factor primarily responsible for contrasting regional reservoir quality of Tertiary sandstones from the Upper and Lower Texas Gulf Coast. Detailed comparison of Frio sandstones from the Chocolate Bayou/Danbury Dome area, Brazoria County, and Vicksburg sandstones from the McAllen Ranch Field area, Hidalgo County, reveals that extent of diagenetic modification is most strongly influenced by (1) detrital mineralogy and (2) regional geothermal gradients. Vicksburg sandstones from the McAllen Ranch Field area are less stable, chemically and mechanically, than Frio sandstones from the Chocolate Bayou/Danbury dome area. Vicksburg sandstones are mineralogically immature and contain greater proportions of feldspars and rock fragments than do Frio sandstones. Thr reactive detrital assemblage of Vicksubrg sandstones is highly susceptible to diagenetic modification. Susceptibility is enhanced by higher than normal geothermal gradients in the McAllen Ranch Field area. Thus, consolidation of Vicksburg sandstones began at shallower depth of burial and precipitation of authigenic phases (especially calcite) was more pervasive than in Frio sandstones. Moreover, the late-stage episode of ferroan calcite precipitation that occluded most secondary porosity in Vicksburg sandstones did not occur significantly in Frio sandstones. Therefore, regional reservoir quality of Frio sandstones from Brazoria County is far better than that characterizing Vicksburg sandstones from Hidalgo County, especially at depths suitable for geopressured geothermal energy production.

  10. Testing geopressured geothermal reservoirs in existing wells. Final report P. R. Girouard Well No. 1, Lafayette Parish, Louisiana. Volume I. Completion and testing

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    The P.R. Girouard No. 1 Well, located approximately 10 miles southeast of Lafayette, Louisiana, was the fourth successful test of a geopressured-geothermal aquifer under the Wells of Opportunity program. The well was tested through 3-1/2 inch tubing set on a packer at 14,570 feet without major problems. The geological section tested was the Oligocene Marginulina Texana No. 1 sand of upper Frio age. The interval tested was from 14,744 to 14,819 feet. Produced water was piped down a disposal well perforated from 2870 to 3000 feet in a Miocene saltwater sand. Four flow tests were conducted for sustained production rates of approximately 4000 BWPD to approximately 15,000 BWPD. The highest achieved, during a fifth short test, was 18,460 BWPD. The test equipment was capable of handling higher rates. The gas-to-water ratio was relatively uniform at approximately 40 SCF/bbl. The heating value of the gas is 970 Btu/SCF. The reservoir tests show that is is doubtful that this well would sustain production rates over 10,000 BWPD for any lengthy period from the sand zone in which it was completed. This limited flow capacity is due to the well's poor location in the reservoir and is not a result of any production deficiencies of the Marginulina Texana sand.

  11. Silica separation from reinjection brines at Monte Amiata geothermal plants, Italy

    SciTech Connect (OSTI)

    Vitolo, S.; Cialdella, M.L. . Dipartimento di Ingegneria Chimica)

    1994-06-01

    A process for the separation of silica from geothermal reinjection brines is reported, in which the phases of coagulation, sedimentation and filtration of silica are involved. The effectiveness of lime and calcium chloride as coagulating agents has been investigated and the separating operations have been set out. Attention has been focused on Monte Amiata reinjection geothermal brines, whose scaling effect causes serious problems in the operation and maintenance of reinjection facilities. The study has been conducted using different amounts of added coagulants and at different temperatures, to determine optimal operating conditions. Though calcium chloride was revealed to be effective as a coagulant of the polymeric silica fraction, lime has also proved capable of removing monomeric dissolved silica at high dosages. Investigation on the behavior of coagulated brine has revealed the feasibility of separating the coagulated silica by sedimentation and filtration.

  12. ASSESSMENT OF TECHNETIUM LEACHABILITY IN CEMENT STABILIZED BASIN 43 GROUNDWATER BRINE

    SciTech Connect (OSTI)

    COOKE GA; DUNCAN JB; LOCKREM LL

    2008-09-30

    This report is an initial report on the laboratory effort executed under RPP-PLAN-33338, Test Plan for the Assessment of Technetium Leachability in Cement-Stabilized Basin 43 Groundwater Brine. This report delineates preliminary data obtained under subcontract 21065, release 30, from the RJ Lee Group, Inc., Center for Laboratory Sciences. The report is predicated on CLS RPT-816, Draft Report: Assessment of Technetium Leachability in Cement Stabilized Basin 43 Groundwater Brine. This document will be revised on receipt of the final RJ Lee Group, Inc., Center for Laboratory Sciences report, which will contain data subjected to quality control and quality assurance criteria.

  13. Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Blanco-Martin, Laura; Molins, Sergi; Trebotich, David; Birkholzer, Jens

    2015-09-01

    In this report, we present FY2015 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. This is a combined milestone report related to milestone Salt R&D Milestone “Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures” (M3FT-15LB0818012) and the Salt Field Testing Milestone (M3FT-15LB0819022) to support the overall objectives of the salt field test planning.

  14. Brine flow up a borehole caused by pressure perturbation from CO2 storage: Static and dynamic evaluations

    SciTech Connect (OSTI)

    Birkholzer, J.T.; Nicot, J.-P.; Oldenburg, C.M.; Zhou, Q.; Kraemer, S.; Bandilla, K.W.

    2011-05-01

    Industrial-scale storage of CO{sub 2} in saline sedimentary basins will cause zones of elevated pressure, larger than the CO{sub 2} plume itself. If permeable conduits (e.g., leaking wells) exist between the injection reservoir and overlying shallow aquifers, brine could be pushed upwards along these conduits and mix with groundwater resources. This paper discusses the potential for such brine leakage to occur in temperature- and salinity-stratified systems. Using static mass-balance calculations as well as dynamic well flow simulations, we evaluate the minimum reservoir pressure that would generate continuous migration of brine up a leaking wellbore into a freshwater aquifer. Since the brine invading the well is denser than the initial fluid in the wellbore, continuous flow only occurs if the pressure perturbation in the reservoir is large enough to overcome the increased fluid column weight after full invasion of brine into the well. If the threshold pressure is exceeded, brine flow rates are dependent on various hydraulic (and other) properties, in particular the effective permeability of the wellbore and the magnitude of pressure increase. If brine flow occurs outside of the well casing, e.g., in a permeable fracture zone between the well cement and the formation, the fluid/solute transfer between the migrating fluid and the surrounding rock units can strongly retard brine flow. At the same time, the threshold pressure for continuous flow to occur decreases compared to a case with no fluid/solute transfer.

  15. RESERVOIR CHARACTERIZATION OF UPPER DEVONIAN GORDON SANDSTONE, JACKSONBURG STRINGTOWN OIL FIELD, NORTHWESTERN WEST VIRGINIA

    SciTech Connect (OSTI)

    S. Ameri; K. Aminian; K.L. Avary; H.I. Bilgesu; M.E. Hohn; R.R. McDowell; D.L. Matchen

    2001-07-01

    The Jacksonburg-Stringtown oil field contained an estimated 88,500,000 barrels of oil in place, of which approximately 20,000,000 barrels were produced during primary recovery operations. A gas injection project, initiated in 1934, and a pilot waterflood, begun in 1981, yielded additional production from limited portions of the field. The pilot was successful enough to warrant development of a full-scale waterflood in 1990, involving approximately 8,900 acres in three units, with a target of 1,500 barrels of oil per acre recovery. Historical patterns of drilling and development within the field suggests that the Gordon reservoir is heterogeneous, and that detailed reservoir characterization is necessary for understanding well performance and addressing problems observed by the operators. The purpose of this work is to establish relationships among permeability, geophysical and other data by integrating geologic, geophysical and engineering data into an interdisciplinary quantification of reservoir heterogeneity as it relates to production. Conventional stratigraphic correlation and core description shows that the Gordon sandstone is composed of three parasequences, formed along the Late Devonian shoreline of the Appalachian Basin. The parasequences comprise five lithofacies, of which one includes reservoir sandstones. Pay sandstones were found to have permeabilities in core ranging from 10 to 200 mD, whereas non-pay sandstones have permeabilities ranging from below the level of instrumental detection to 5 mD; Conglomeratic zones could take on the permeability characteristics of enclosing materials, or could exhibit extremely low values in pay sandstone and high values in non-pay or low permeability pay sandstone. Four electrofacies based on a linear combination of density and scaled gamma ray best matched correlations made independently based on visual comparison of geophysical logs. Electrofacies 4 with relatively high permeability (mean value > 45 mD) was

  16. Performance of CRA in concentrated brines at 130 to 180 C -- Effect of H{sub 2}S, elemental sulfur and brine composition

    SciTech Connect (OSTI)

    Schmitt, G.; Pankoke, U.; Klemp, G.; Bruckhoff, W.; Siegmund, G.

    1997-08-01

    Failure analysis of localized corrosion at 28Cr32Ni (Alloy 28) tubing in a sour gas well prompted systematic investigations on the performance of relevant corrosion resistant alloys (CRA) in synthetic high salinity brines at high H{sub 2}S partial pressures in the absence and presence of elemental sulfur at 130 to 180 C. The CRAs included superaustenitic steels, nickel and nickel-cobalt base alloys and titanium alloys. CRAs with pitting resistance equivalents (PRE) of 39 and lower (including 28Cr32Ni) suffered in unbuffered brines from pitting and crevice corrosion already at 130 C. Alloy C276 and Ti Beta-C alloys proved complete resistance in all media tested up to 180 C. The effect of medium composition on CRA performance was studied at 130 C with respect to the presence of elemental sulfur, H{sub 2}S, iron sulfide, and CaCo{sub 3} in NaCl/CaCl{sub 2} brines with a total of 160 g/l chloride.

  17. Exploration for deep gas in the Devonian Chaco Basin of Southern Bolivia: Sequence stratigraphy, predictions, and well results

    SciTech Connect (OSTI)

    Williams, K.E.; Radovich, B.J.; Brett, J.W.

    1995-12-31

    In mid 1991, a team was assembled in Texaco`s Frontier Exploration Department (FED) to define the hydrocarbon potential of the Chaco Basin of Southern Bolivia. The Miraflores No. 1 was drilled in the fall of 1992, for stratigraphic objectives. The well confirmed the predicted stratigraphic trap in the Mid-Devonian, with gas discovered in two highstand and transgressive sands. They are low contrast and low resistivity sands that are found in a deep basin `tight gas` setting. Testing of the gas sands was complicated by drilling fluid interactions at the well bore. Subsequent analysis indicated that the existing porosity and permeability were reduced, such that a realistic test of reservoir capabilities was prevented.

  18. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2005-04-26

    Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples were acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton. There is a direct correlation between measured total organic carbon content and the adsorptive capacity of the shale; CO{sub 2} adsorption capacity increases with increasing organic carbon content. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

  19. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2005-01-01

    Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples were acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

  20. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2004-08-01

    Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library are being sampled to collect CO{sub 2} adsorption isotherms. Sidewall core samples have been acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log has been acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 4.62 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 19 scf/ton in less organic-rich zones to more than 86 scf/ton in the Lower Huron Member of the shale. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

  1. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2005-07-29

    Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples were acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton. There is a direct correlation between measured total organic carbon content and the adsorptive capacity of the shale; CO{sub 2} adsorption capacity increases with increasing organic carbon content. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

  2. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2005-01-28

    Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples were acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton. There is a direct correlation between measured total organic carbon content and the adsorptive capacity of the shale; CO{sub 2} adsorption capacity increases with increasing organic carbon content. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

  3. Geochemistry, palynology, and regional geology of worldclass Upper Devonian source rocks in the Madre de Dios basin, Bolivia

    SciTech Connect (OSTI)

    Peters, K.E.; Conrad, K.T.; Carpenter, D.G.; Wagner, J.B.

    1996-08-01

    Recent exploration drilling indicates the existence of world-class source rock in the Madre de Dios basin, Bolivia. In the Pando-1 X and -2X wells, over 200 m of poorly bioturbated, organic-rich (TOC = 3-16 wt.%) prodelta to shelf mudstones in the Frasnian-Famennian Tomachi Formation contain oil-prone organic matter (hydrogen index = 400-600 mg HC/g TOC). Our calculated source prolificity indices for this interval in these wells (SPI = 15-18 tons of hydrocarbons per square meter of source rock) exceed that for the Upper Jurassic in Central Saudi Arabia. The Tomachi interval is lithologically equivalent to the Colpacucho Formation in the northern Altiplano, the Iquiri Formation in the Cordillera Oriental, and is coeval with other excellent source rocks in North America, Africa, and Eurasia. All of these rocks were deposited under conditions favorable for accumulation of organic matter, including a global highstand and high productivity. However, the Madre de Dios basin was situated at high latitude during the Late Devonian and some of the deposits are interpreted to be of glacial origin, indicating conditions not generally associated with organic-rich deposition. A biomarker and palynological study of Upper Devonian rocks in the Pando-1X well suggests deposition under conditions similar to certain modern fjords. High productivity resulted in preservation of abundant organic matter in the bottom sediments despite a cold, toxic water column. Low-sulfur crude oil produced from the Pando-1X well is geochemically similar to, but more mature than, extracts from associated organic-rich Tomachi samples, and was generated from deeper equivalents of these rocks.

  4. Shaker Table Experiments with Rare Earth Elements Sorption from Geothermal Brine

    SciTech Connect (OSTI)

    Gary Garland

    2015-07-21

    This dataset described shaker table experiments ran with sieved -50 +100 mesh media #1 in brine #1 that have 2ppm each of the 7 REE metals at different starting pH's of 3.5, 4.5, and 5.5. The experimental conditions are 2g media to 150mL of REE solution, at 70C.

  5. RealGasBrine v1.0 option of TOUGH+ v1.5

    SciTech Connect (OSTI)

    Moridis, George

    2015-02-27

    RealGasBrine v1.0 is a numerical code that for the simulation of the behavior of gas-bearing porous and/fractured geologic media. It is an option of TOUGH+ v1.5 [Moridis, 2014], a successor to the TOUGH2 [Pruess et al., 1999; 2012] family of codes for multi-component, multiphase ?uid and heat ?ow developed at the Lawrence Berkeley National Laboratory. RealGasBrine v1.0 needs the TOUGH+ v1.5 core code in order to compile and execute. It is written in standard FORTRAN 95/2003, and can be run on any computational platform (workstation, PC, Macintosh) for which such compilers are available. RealGasBrine v1.0 describes the non-isothermal two- (for pure water) or three-phase (for brine) flow of an aqueous phase and a real gas mixture in a gas-bearing medium, with a particular focus in ultra-tight (such as tight-sand and shale gas) systems. Up to 12 individual real gases can be tracked, and salt can precipitate as solid halite. The capabilities of the code include coupled flow and thermal effects, real gas behavior, Darcy and non-Darcy flow, several isotherm options of gas sorption onto the grains of the porous media, complex fracture descriptions, gas solubility into water, and geomechanical effects on flow properties. RealGasBrine v1.0 allows the study of flow and transport of fluids and heat over a wide range of time frames and spatial scales not only in gas reservoirs, but also in any problem involving the flow of gases in geologic media, including the geologic storage of greenhouse gas mixtures, the behavior of geothermal reservoirs with multi-component condensable (H2O and CO2) and non-condensable gas mixtures, the transport of water and released H2 in nuclear waste storage applications, etc.

  6. Disposal/recovery options for brine waters from oil and gas production in New York State. Final report

    SciTech Connect (OSTI)

    Matsumoto, M.R.; Atkinson, J.F.; Bunn, M.D.; Hodge, D.S.

    1996-03-01

    Produced water from oil and gas operations, or brine as it is typically referred, may be characterized as being highly saline, with total dissolved solids greater than 100 g/L. If these bribes are disposed improperly there may be severe adverse environmental effects. Thus, it is important that brine be disposed using environmentally sound methods. Unfortunately, costs for the disposal of brine water are a significant burden to oil and gas producers in New York State. These costs and the relatively low market price of oil and natural gas have contributed to the decline in gas and oil production in New York State during the past 10 years. The objectives of this study were to evaluate new and existing options for brine disposal in New York State, examine the technical and economic merits of these options, and assess environmental impacts associated with each option. Two new disposal options investigated for New York State oil and gas producers included construction of a regional brine treatment facility to treat brine prior to discharge into a receiving water and a salt production facility that utilizes produced water as a feed stock. Both options are technically feasible; however, their economic viability depends on facility size and volume of brine treated.

  7. Analysis of Devonian Black Shales in Kentucky for Potential Carbon Dioxide Sequestration and Enhanced Natural Gas Production

    SciTech Connect (OSTI)

    Brandon C. Nuttall; Cortland F. Eble; James A. Drahovzal; R. Marc Bustin

    2005-09-30

    Carbonaceous (black) Devonian gas shales underlie approximately two-thirds of Kentucky. In these shales, natural gas occurs in the intergranular and fracture porosity and is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO2 is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO2. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine both CO2 and CH4 adsorption isotherms. Sidewall core samples were acquired to investigate CO2 displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO2 adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton in the more organic-rich zones. There is a direct linear correlation between measured total organic carbon content and the adsorptive capacity of the shale; CO2 adsorption capacity increases with increasing organic carbon content. Initial volumetric estimates based on these data indicate a CO2 sequestration capacity of as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. In the Big Sandy Gas Field area of eastern Kentucky, calculations using the net thickness of shale with 4 percent or greater total organic carbon, indicate that 6.8 billion tonnes of CO2 could be sequestered in the five county area. Discounting the uncertainties in reservoir volume and injection efficiency, these results indicate that the black shales of Kentucky are a potentially large geologic sink for CO2. Moreover, the extensive occurrence of gas shales in Paleozoic and Mesozoic

  8. Recovery Act: Molecular Simulation of Dissolved Inorganic Carbons for Underground Brine CO2 Sequestration

    SciTech Connect (OSTI)

    Goddard, William

    2012-11-30

    To further our understanding and develop the method for measuring the DICs under geological sequestration conditions, we studied the infrared spectra of DICs under high pressure and temperature conditions. First principles simulations of DICs in brine conditions were performed using a highly optimized ReaxFF-DIC forcefield. The thermodynamics stability of each species were determined using the 2PT method, and shown to be consistent with the Reax simulations. More importantly, we have presented the IR spectra of DIC in real brine conditions as a function of temperature and pressure. At near earth conditions, we find a breaking of the O-C-O bending modes into asymmetric and symmetric modes, separated by 100cm{sup -1} at 400K and 5 GPa. These results can now be used to calibrate FTIR laser measurements.

  9. West Hackberry Brine Disposal Project pre-discharge characterization. Final report

    SciTech Connect (OSTI)

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.

    1982-01-01

    The physical, chemical and biological attributes are described for: (1) a coastal marine environment centered about a Department of Energy Strategic Petroleum Reserve (SPR) brine disposal site 11.4 km off the southwest coast of Louisiana; and (2) the lower Calcasieu and Sabine estuarine systems that provide leach waters for the SPR project. A three month sampling effort, February through April 1981, and previous investigations from the study area are integrated to establish baseline information for evaluation of impacts from brine disposal in the nearshore marine waters and from freshwater withdrawal from the coastal marsh of the Chenier Plain. January data are included for some tasks that sampled while testing and mobilizing their instruments prior to the February field effort. The study addresses the areas of physical oceanography, estuarine hydrology and hydrography, water and sediment quality, benthos, nekton, phytoplankton, zooplankton, and data management.

  10. Comparison of selected oil-field brines from fields in the Permian basin, West Texas-southeast New Mexico

    SciTech Connect (OSTI)

    White, H.G. III

    1992-04-01

    Stiff diagrams of oil-field brines from the west Texas Permian basin are identifiable within the geological framework. Plotted from a simple analysis of three cations and three anions, older Paleozoic waters can be categorized as either 'pristine' or modified, usually by a later influx of Permian or early Pennsylvanian water. These different plots can be segregated by geologic province. The Permian brines differ by age and also by environment (shelf, basin, etc.).

  11. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOE Patents [OSTI]

    Premuzic, Eugene T.; Lin, Mow S.

    1994-11-22

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed, The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts, For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates.

  12. Targeted Pressure Management During CO2 Sequestration: Optimization of Well Placement and Brine Extraction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cihan, Abdullah; Birkholzer, Jens; Bianchi, Marco

    2014-12-31

    Large-scale pressure increases resulting from carbon dioxide (CO2) injection in the subsurface can potentially impact caprock integrity, induce reactivation of critically stressed faults, and drive CO2 or brine through conductive features into shallow groundwater. Pressure management involving the extraction of native fluids from storage formations can be used to minimize pressure increases while maximizing CO2 storage. However, brine extraction requires pumping, transportation, possibly treatment, and disposal of substantial volumes of extracted brackish or saline water, all of which can be technically challenging and expensive. This paper describes a constrained differential evolution (CDE) algorithm for optimal well placement and injection/ extractionmore » control with the goal of minimizing brine extraction while achieving predefined pressure contraints. The CDE methodology was tested for a simple optimization problem whose solution can be partially obtained with a gradient-based optimization methodology. The CDE successfully estimated the true global optimum for both extraction well location and extraction rate, needed for the test problem. A more complex example application of the developed strategy was also presented for a hypothetical CO2 storage scenario in a heterogeneous reservoir consisting of a critically stressed fault nearby an injection zone. Through the CDE optimization algorithm coupled to a numerical vertically-averaged reservoir model, we successfully estimated optimal rates and locations for CO2 injection and brine extraction wells while simultaneously satisfying multiple pressure buildup constraints to avoid fault activation and caprock fracturing. The study shows that the CDE methodology is a very promising tool to solve also other optimization problems related to GCS, such as reducing ‘Area of Review’, monitoring design, reducing risk of leakage and increasing storage capacity and trapping.« less

  13. Biochemical solubilization of toxic salts from residual geothermal brines and waste waters

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.S.

    1994-11-22

    A method of solubilizing metal salts such as metal sulfides in a geothermal sludge using mutant Thiobacilli selected for their ability to metabolize metal salts at high temperature is disclosed. The method includes the introduction of mutated Thiobacillus ferrooxidans and Thiobacillus thiooxidans to a geothermal sludge or brine. The microorganisms catalyze the solubilization of metal salts. For instance, in the case of metal sulfides, the microorganisms catalyze the solubilization to form soluble metal sulfates. 54 figs.

  14. Stratigraphy and organic petrography of Mississippian and Devonian oil shale at the Means Project, East-Central Kentucky

    SciTech Connect (OSTI)

    Solomon, B.J.; Hutton, A.C.; Henstridge, D.A.; Ivanac, J.F.

    1985-02-01

    The Means Oil Shale Project is under consideration for financial assistance by the US Synthetic Fuels Corporation. The project site is located in southern Montgomery County, about 45 miles east of Lexington, Kentucky. In the site area the Devonian Ohio Shale and the Mississippian Sunbury Shale are under study; these oil shales were deposited in the Appalachian Basin. The objective of the Means Project is to mine, using open pit methods, an ore zone which includes the Sunbury and upper Cleveland and which excludes the Bedford interburden. The thick lower grade oil shale below this ore zone renders the higher grade shale at the base of the Huron commercially unattractive. The oil shale at Means has been classified as a marinite, an oil shale containing abundant alginite of marine origin. Lamalginite is the dominant liptinite and comprises small, unicellular alginite with weak to moderate fluorescence at low rank and a distinctive lamellar form. Telalginite, derived from large colonial or thick-walled, unicellular algae, is common in several stratigraphic intervals.

  15. Ground-water hydraulics of the deep-basin brine aquifer, Palo Duro Basin, Texas panhandle

    SciTech Connect (OSTI)

    Smith, D.A.

    1985-01-01

    The Deep-Basin Brine aquifer of the Palo Duro Basin (Texas Panhandle) underlies thick Permian bedded evaporites that are being evaluated as a potential high-level nuclear waste isolation repository. Potentiometric surface maps of 5 units of the Deep-Basin Brine aquifer were drawn using drill-stem test (DST) pressure data, which were analyzed by a geostatistical technique (kriging) to smooth the large variation in the data. The potentiometric surface maps indicate that the Deep-Basin Brine aquifer could be conceptually modeled as 5 aquifer units; a Lower Permian (Wolfcamp) aquifer, upper and lower Pennsylvanian aquifers, a pre-Pennsylvanian aquifer, and a Pennsylvanian to Wolfcampian granite-wash aquifer. The hydraulic head maps indicate that ground-water flow in each of the units is west to east with a minor northerly component near the Amarillo Uplift, the northern structural boundary of the basin. The Wolfcamp potentiometric surface indicates the strongest component of northerly flow. Inferred flow direction in Pennsylvanian aquifers is easterly, and in the pre-Pennsylvanian aquifer near its pinch-out in the basin center, flow is inferred to be to the north. In the granite-wash aquifer the inferred flow direction is east across the northern edge of the basin and southeast along the Amarillo Uplift.

  16. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    SciTech Connect (OSTI)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO₂-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at a proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO₂. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO₂ will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO₂ driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ

  17. Utilizing rare earth elements as tracers in high TDS reservoir brines in CCS applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLing, Travis; Smith, William; Smith, Robert

    2014-12-31

    In this paper we report the result of research associated with the testing of a procedures necessary for utilizing natural occurring trace elements, specifically the Rare Earth Elements (REE) as geochemical tracers in Carbon Capture and Storage (CCS) applications. Trace elements, particularly REE may be well suited to serve as in situ tracers for monitoring geochemical conditions and the migration of CO₂-charged waters within CCS storage systems. We have been conducting studies to determine the efficacy of using REE as a tracer and characterization tool in the laboratory, at a CCS analogue site in Soda Springs, Idaho, and at amore » proposed CCS reservoir at the Rock Springs Uplift, Wyoming. Results from field and laboratory studies have been encouraging and show that REE may be an effective tracer in CCS systems and overlying aquifers. In recent years, a series of studies using REE as a natural groundwater tracer have been conducted successfully at various locations around the globe. Additionally, REE and other trace elements have been successfully used as in situ tracers to describe the evolution of deep sedimentary Basins. Our goal has been to establish naturally occurring REE as a useful monitoring measuring and verification (MMV) tool in CCS research because formation brine chemistry will be particularly sensitive to changes in local equilibrium caused by the addition of large volumes of CO₂. Because brine within CCS target formations will have been in chemical equilibrium with the host rocks for millions of years, the addition of large volumes of CO₂ will cause reactions in the formation that will drive changes to the brine chemistry due to the pH change caused by the formation of carbonic acid. This CO₂ driven change in formation fluid chemistry will have a major impact on water rock reaction equilibrium in the formation, which will impart a change in the REE fingerprint of the brine that can measured and be used to monitor in situ reservoir

  18. Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine

    SciTech Connect (OSTI)

    David B. Burnett

    2005-09-29

    This study is developing a comprehensive study of what is involved in the desalination of oil field produced brine and the technical developments and regulatory changes needed to make the concept a commercial reality. It was originally based on ''conventional'' produced water treatment and reviewed (1) the basics of produced water management, (2) the potential for desalination of produced brine in order to make the resource more useful and available in areas of limited fresh water availability, and (3) the potential beneficial uses of produced water for other than oil production operations. Since we have begun however, a new area of interest has appeared that of brine water treatment at the well site. Details are discussed in this technical progress report. One way to reduce the impact of O&G operations is to treat produced brine by desalination. The main body of the report contains information showing where oil field brine is produced, its composition, and the volume available for treatment and desalination. This collection of information all relates to what the oil and gas industry refers to as ''produced water management''. It is a critical issue for the industry as produced water accounts for more than 80% of all the byproducts produced in oil and gas exploration and production. The expense of handling unwanted waste fluids draws scarce capital away for the development of new petroleum resources, decreases the economic lifetimes of existing oil and gas reservoirs, and makes environmental compliance more expensive to achieve. More than 200 million barrels of produced water are generated worldwide each day; this adds up to more than 75 billion barrels per year. For the United States, the American Petroleum Institute estimated about 18 billion barrels per year were generated from onshore wells in 1995, and similar volumes are generated today. Offshore wells in the United States generate several hundred million barrels of produced water per year. Internationally

  19. RealGasBrine v1.0 option of TOUGH+ v1.5

    Energy Science and Technology Software Center (OSTI)

    2015-02-27

    RealGasBrine v1.0 is a numerical code that for the simulation of the behavior of gas-bearing porous and/fractured geologic media. It is an option of TOUGH+ v1.5 [Moridis, 2014], a successor to the TOUGH2 [Pruess et al., 1999; 2012] family of codes for multi-component, multiphase ?uid and heat ?ow developed at the Lawrence Berkeley National Laboratory. RealGasBrine v1.0 needs the TOUGH+ v1.5 core code in order to compile and execute. It is written in standard FORTRANmore » 95/2003, and can be run on any computational platform (workstation, PC, Macintosh) for which such compilers are available. RealGasBrine v1.0 describes the non-isothermal two- (for pure water) or three-phase (for brine) flow of an aqueous phase and a real gas mixture in a gas-bearing medium, with a particular focus in ultra-tight (such as tight-sand and shale gas) systems. Up to 12 individual real gases can be tracked, and salt can precipitate as solid halite. The capabilities of the code include coupled flow and thermal effects, real gas behavior, Darcy and non-Darcy flow, several isotherm options of gas sorption onto the grains of the porous media, complex fracture descriptions, gas solubility into water, and geomechanical effects on flow properties. RealGasBrine v1.0 allows the study of flow and transport of fluids and heat over a wide range of time frames and spatial scales not only in gas reservoirs, but also in any problem involving the flow of gases in geologic media, including the geologic storage of greenhouse gas mixtures, the behavior of geothermal reservoirs with multi-component condensable (H2O and CO2) and non-condensable gas mixtures, the transport of water and released H2 in nuclear waste storage applications, etc.« less

  20. Devonian oil in Mississippian and Mesozoic reservoirs-unconformity controls on migration and accumulation, Sweetgrass Arch, Montana

    SciTech Connect (OSTI)

    Dolson, J.; Piombino, J. ); Franklin, M. ); Harwood, R. )

    1993-10-01

    Lower Cretaceous and Mississippian strata of the Sweetgrass Arch of western Montana have produced over 300 MMBO, primarily from three large combination traps. Gas chromatography-mass spectrometry (GC-MS) data suggest a Devonian/Mississippian Bakken Formation oil source. Most thermally mature Bakken strata are located at least 60 mi (90 km) to the west in the footwall to the thrust belt. Hydrocarbons have migrated vertically through fractures in the Mississippian Madison Group to regional seals in Jurassic shales. Lateral migration occurs predominately within the Jurassic subcrop of the Mississippian Sun River Dolomite. Permeability barriers, paleohills, subtle structures and possible hydrodynamic modification along the migration pathway account for most of the Sun River production. A lack of effective bottom seals generally prevents these subtle traps from developing large accumulations in areas of steep structural dip. The pre-Cretaceous unconformity, which underlies the Lower Cretaceous Cutbank sandstone, bevels across this Mississippian migration route downplunge in Canada, diverting oils southward to the giant Cutbank field accumulation. Alluvial plain and fan sandstones west of the field have sheet-like geometries and appear to have poor lateral seals. Most of the Cutbank accumulation occurs where valley incisement of a north-south trending paleodrainage system juxtaposes these sheet sandstones updip against Jurassic Rierdon and Sawtooth shales, forming a valley wall trap. Additional minor Jurassic and Lower Cretaceous production occurs updip from leak points created by poor lateral seals adjacent the pre-Cretaceous unconformity. These interpretations provide new insight into field distributions throughout the Sweetgrass Arch. 37 refs., 26 figs., 1 tab.

  1. Paleoecology of the Devonian-Mississippian black-shale sequence in eastern Kentucky with an atlas of some common fossils

    SciTech Connect (OSTI)

    Barron, L.S.; Ettensohn, F.R.

    1981-04-01

    The Devonian-Mississippian black-shale sequence of eastern North America is a distinctive stratigraphic interval generally characterized by low clastic influx, high organic production in the water column, anaerobic bottom conditions, and the relative absence of fossil evidence for biologic activity. The laminated black shales which constitute most of the black-shale sequence are broken by two major sequences of interbedded greenish-gray, clayey shales which contain bioturbation and pyritized micromorph invertebrates. The black shales contain abundant evidence of life from upper parts of the water column such as fish fossils, conodonts, algae and other phytoplankton; however, there is a lack of evidence of benthic life. The rare brachiopods, crinoids, and molluscs that occur in the black shales were probably epiplanktic. A significant physical distinction between the environment in which the black sediments were deposited and that in which the greenish-gray sediments were deposited was the level of dissolved oxygen. The laminated black shales point to anaerobic conditions and the bioturbated greenish-gray shales suggest dysaerobic to marginally aerobic-dysaerobic conditions. A paleoenvironmental model in which quasi-estuarine circulation compliments and enhances the effect of a stratified water column can account for both depletion of dissolved oxygen in the bottom environments and the absence of oxygen replenishment during black-shale deposition. Periods of abundant clastic influx from fluvial environments to the east probably account for the abundance of clays in the greenish-gray shale as well as the small amounts of oxygen necessary to support the depauparate, opportunistic, benthic faunas found there. These pulses of greenish-gray clastics were short-lived and eventually were replaced by anaerobic conditions and low rates of clastic sedimentation which characterized most of black-shale deposition.

  2. Pyrolysis and hydrocarbon source bed potential of the Upper Devonian Woodford Shale, Hovey Channel, southern Permian basin, west Texas

    SciTech Connect (OSTI)

    Hussain, M.; Bloom, M.A. )

    1991-03-01

    The Upper Devonian Woodford Shale in the Hovey Channel area, southern Permian basin, is 50 m thick and composed largely of brown to black, pyritic, spore-bearing, organic-rich, fissile shale an chert. Total organic carbon, distillable hydrocarbons, genetic potential, organic carbon index, hydrogen index, temperature of maximum hydrocarbon generation, and kerogen transformation index of the Woodford Shale suggest a matured to overmatured, gas-generating source bed. The total organic carbon content of the formation ranged from a low of 0.77% in the cherty samples to a high of 4.59% in a shaley sample, averaging 2.18%. Distillable hydrocarbon content of the samples is fairly high (averaging 1.72 mg HC/gm{degree} rock), varying from 0.90 mg HC/gm{degree} rock to 3.22 mg HC/gm{degree} rock. Genetic potential evaluated in terms of both residual and total generative potential showed above average potential, averaging 3.25 mg HC/gm{degree} rock for the residual and 4.90 mg HC/gm{degree} rock for the total, respectively. Live organic carbon index values ranged from 11-28%, characterizing the formation as a moderate to good source bed. Hydrogen index values ranged from 73 mg HC/gm{degree} C org to 155 mg HC/gm{degree} C org, suggesting overmaturity and gas-generation potential of the source bed. Temperature of maximum hydrocarbon generation values and kerogen transformation ratio values (averaging 0.34) also indicate overmatured nature of the Woodford Shale.

  3. PILOT TESTING: PRETREATMENT OPTIONS TO ALLOW RE-USE OF FRAC FLOWBACK AND PRODUCED BRINE FOR GAS SHALE RESOURCE DEVELOPMENT

    SciTech Connect (OSTI)

    Burnett, David

    2012-12-31

    The goal of the A&M DOE NETL Project No. DE-FE0000847 was to develop a mobile, multifunctional water treatment capability designed specifically for “pre-treatment” of field waste brine. The project consisted of constructing s mobile “field laboratory” incorporating new technology for treating high salinity produced water and using the lab to conduct a side-by-side comparison between this new technology and that already existing in field operations. A series of four field trials were performed utilizing the mobile unit to demonstrate the effectiveness of different technology suitable for use with high salinity flow back brines and produced water. The design of the mobile unit was based on previous and current work at the Texas A&M Separation Sciences Pilot Plant. The several treatment techniques which have been found to be successful in both pilot plant and field tests had been tested to incorporate into a single multifunctional process train. Eight different components were evaluated during the trials, two types of oil and grease removal, one BTEX removal step, three micro-filters, and two different nanofilters. The performance of each technique was measured by its separation efficiency, power consumption, and ability to withstand fouling. The field trials were a success. Four different field brines were evaluated in the first trial in New York. Over 16,000 gallons of brine were processed. Using a power cost of $.10 per kWh, media pretreatment power use averaged $0.004 per barrel, solids removal $.04 per barrel and brine “softening” $.84 per barrel. Total power cost was approximately $1.00 per barrel of fluid treated. In Pennsylvania, brines collected from frac ponds were tested in two additional trials. Each of the brines was converted to an oil-free, solids-free brine with no biological activity. Brines were stable over time and would be good candidates for use as a make-up fluid in a subsequent fracturing fluid design. Reports on all of the field

  4. Geochemistry of Ca, Sr, Ba and Ra sulfates in some deep brines from the Palo Duro basin, Texas

    SciTech Connect (OSTI)

    Langmuir, D.; Melchior, D.

    1985-11-01

    The geochemistry of Ca, Sr, Ba and Ra sulfates in some deep brines from the Palo Duro Basin of north Texas, was studied to define geochemical controls on radionuclides such as /sup 90/Sr and /sup 226/Ra. Published solubility data for gypsum, anhydrite, celestite, barite and RaSO/sub 4/ were first reevaluated, in most cases using the ion interaction approach of Pitzer, to determine solubility products of the sulfates as a function of temperature and pressure. Ionic strengths of the brines were from 2.9 to 4.8 m, their temperatures and pressures up to 40/sup 0/C and 130 bars. Saturation indices of the sulfates were computed with the ion-interaction approach in one brine from the arkosic granite wash facies and four from the carbonate Wolfcamp Formation. All five brines are saturated with respect to gypsum, anhydrite and celestite, and three of the five with respect to barite. All are undersaturated by from 5 to 6 orders of magnitude with respect to pure RaSO/sub 4/. /sup 226/Ra concentrations in the brines, which ranged from 10/sup -11.3/ to 10/sup -12.7/ m, are not controlled by RaSO/sub 4/ solubility or adsorption, but possibly by the solubility of trace Ra solid solutions in sulfates including celestite and barite.

  5. The sup 36 Cl ages of the brines in the Magadi-Natron basin, east Africa

    SciTech Connect (OSTI)

    Kaufman, A.; Margaritz, M.A.; Hollos, G. ); Paul, M.; Boaretto, E. ); Hillaire-Marcel, C. ); Taieb, M. )

    1990-10-01

    The depression in the East African Rift which includes both Lake Magadi and Lake Natron forms a closed basin within which almost all the dissolved chloride originates in precipitation, since there is no important source of very ancient sedimentary chloride. This provides an ideal setting for the evaluation of the {sup 36}Cl methodology as a geochemical and hydrological tracer. The main source of recent water, as represented by the most dilute samples measured, is characterized by a {sup 36}Cl/Cl ratio of 2.5 {times} 10{sup {minus}14}, in agreement with the calculated value expected in precipitation. Surface evaporation increases the chlorinity of the local freshwater inflow by about a factor of 110 without changing the isotopic ratio, indicating that little chloride enters the system in the form of sediment leachate. A second type of brine found in the basin occurs in a hot deep groundwater reservoir and is characterized by lower {sup 36}Cl/Cl ratios (<1.2 {times} 10{sup {minus}14}). By comparing this value with the 2.5 {times} 10{sup {minus}14} in recent recharge, one obtains an approximate salt accumulation age of 760 Ka which is consistent with thee time of the first appearance of the lake. These older brines also have lower {sup 18}O and {sup 2}H values which indicate that they were recharged during a climatically different era. The {sup 36}Cl/Cl ratios in the inflowing waters and in the accumulated brine, together with the known age of the Lake Magadi basin, may be used to estimate the importance of the hypogene and epigene, as opposed to the meteoric, mode of {sup 36}Cl production. Such a calculation shows that the hypogene and epigene processes together contribute less than 6% of the total {sup 36}Cl present in the lake.

  6. Brine migration test for Asse Mine, Federal Republic of Germany: final test plan

    SciTech Connect (OSTI)

    Not Available

    1983-07-01

    The United States and the Federal Republic of Germany (FRG) will conduct a brine migration test in the Asse Salt Mine in the FRG as part of the US/FRG Cooperative Radioactive Waste Management Agreement. Two sets of two tests each will be conducted to study both liquid inclusion migration and vapor migration in the two salt types chosen for the experiments: (1) pure salt, for its characteristics similar to the salt that might occur in potential US repositories, and (2) transitional salt, for its similarity to the salt that might occur in potential repositories in Germany.

  7. Advanced biochemical processes for geothermal brines FY 1998 annual operating plan

    SciTech Connect (OSTI)

    1997-10-01

    As part of the overall Geothermal Energy Research which is aimed at the development of economical geothermal resources production systems, the aim of the Advanced Biochemical Processes for Geothermal Brines (ABPGB) effort is the development of economic and environmentally acceptable methods for disposal of geothermal wastes and conversion of by-products to useful forms. Methods are being developed for dissolution, separation and immobilization of geothermal wastes suitable for disposal, usable in inert construction materials, suitable for reinjection into the reservoir formation, or used for recovery of valuable metals.

  8. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bacon, Diana H.; Dai, Zhenxue; Zheng, Liange

    2014-12-31

    An important risk at CO2 storage sites is the potential for groundwater quality impacts. As part of a system to assess the potential for these impacts a geochemical scaling function has been developed, based on a detailed reactive transport model of CO2 and brine leakage into an unconfined, oxidizing carbonate aquifer. Stochastic simulations varying a number of geochemical parameters were used to generate a response surface predicting the volume of aquifer that would be impacted with respect to regulated contaminants. The brine was assumed to contain several trace metals and organic contaminants. Aquifer pH and TDS were influenced by CO2more » leakage, while trace metal concentrations were most influenced by the brine concentrations rather than adsorption or desorption on calcite. Organic plume sizes were found to be strongly influenced by biodegradation.« less

  9. Sensitivity study of CO2 storage capacity in brine aquifers withclosed boundaries: Dependence on hydrogeologic properties

    SciTech Connect (OSTI)

    Zhou, Q.; Birkholzer, J.; Rutqvist, J.; Tsang, C-F.

    2007-02-07

    In large-scale geologic storage projects, the injected volumes of CO{sub 2} will displace huge volumes of native brine. If the designated storage formation is a closed system, e.g., a geologic unit that is compartmentalized by (almost) impermeable sealing units and/or sealing faults, the native brine cannot (easily) escape from the target reservoir. Thus the amount of supercritical CO{sub 2} that can be stored in such a system depends ultimately on how much pore space can be made available for the added fluid owing to the compressibility of the pore structure and the fluids. To evaluate storage capacity in such closed systems, we have conducted a modeling study simulating CO{sub 2} injection into idealized deep saline aquifers that have no (or limited) interaction with overlying, underlying, and/or adjacent units. Our focus is to evaluate the storage capacity of closed systems as a function of various reservoir parameters, hydraulic properties, compressibilities, depth, boundaries, etc. Accounting for multi-phase flow effects including dissolution of CO{sub 2} in numerical simulations, the goal is to develop simple analytical expressions that provide estimates for storage capacity and pressure buildup in such closed systems.

  10. Advanced Membrane Filtration Technology for Cost Effective Recovery of Fresh Water from Oil & Gas Produced Brine

    SciTech Connect (OSTI)

    David B. Burnett

    2004-09-29

    Produced water is a major waste generated at the oil and natural gas wells in the state of Texas. This water could be a possible source of new fresh water to meet the growing demands of the state after treatment and purification. Treatment of brine generated in oil fields or produced water with an ultrafiltration membranes were the subject of this thesis. The characterization of ultrafiltration membranes for oil and suspended solids removal of produced water, coupled with the reverse osmosis (RO) desalination of brine were studied on lab size membrane testing equipment and a field size testing unit to test whether a viable membrane system could be used to treat produced water. Oil and suspended solids were evaluated using turbidity and oil in water measurements taken periodically. The research considered the effect of pressure and flow rate on membrane performance of produced water treatment of three commercially available membranes for oily water. The study also analyzed the flux through the membrane and any effect it had on membrane performance. The research showed that an ultrafiltration membrane provided turbidity removal of over 99% and oil removal of 78% for the produced water samples. The results indicated that the ultrafiltration membranes would be asset as one of the first steps in purifying the water. Further results on selected RO membranes showed that salt rejection of greater than 97% could be achieved with satisfactory flux and at reasonable operating cost.

  11. Summary Results for Brine Migration Modeling Performed by LANL LBNL and SNL for the UFD Program.

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L

    2014-09-01

    This report summarizes laboratory and field observations and numerical modeling related to coupled processes involving brine and vapor migration in geologic salt, focusing on recent developments and studies conducted at Sandia, Los Alamos, and Berkeley National Laboratories. Interest into the disposal of heat-generating waste in salt has led to interest into water distribution and migration in both run-of-mine crushed and intact geologic salt. Ideally a fully coupled thermal-hydraulic-mechanical-chemical simulation is performed using numerical models with validated constitutive models and parameters. When mechanical coupling is not available, mechanical effects are prescribed in hydraulic models as source, boundary, or initial conditions. This report presents material associated with developing appropriate initial conditions for a non-mechanical hydrologic simulation of brine migration in salt. Due to the strong coupling between the mechanical and hydrologic problems, the initial saturation will be low for the excavation disturbed zone surrounding the excavation. Although most of the material in this report is not new, the author hopes it is presented in a format making it useful to other salt researchers.

  12. Brine migration test report: Asse Salt Mine, Federal Republic of Germany: Technical report

    SciTech Connect (OSTI)

    Coyle, A.J.; Eckert, J.; Kalia, H.

    1987-01-01

    This report presents a summary of Brine Migration Tests which were undertaken at the Asse mine of the Federal Republic of Germany (FRG) under a bilateral US/FRG agreement. This experiment simulates a nuclear waste repository at the 800-m (2624-ft) level of the Asse salt mine in the Federal Republic of Germany. This report describes the Asse salt mine, the test equipment, and the pretest properties of the salt in the mine and in the vicinity of the test area. Also included are selected test data (for the first 28 months of operation) on the following: brine migration rates, thermomechaical behavior of the salt (including room closure, stress reading, and thermal profiles), borehole gas pressures, and borehole gas analyses. In addition to field data, laboratory analyses of pretest salt properties are included in this report. The operational phase of these experiments was completed on October 4, 1985, with the commencement of cooldown and the start of posttest activities. 7 refs., 68 figs., 48 tabs.

  13. Modeling Coupled THMC Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Blanco Martin, Laura; Mukhopadhyay, Sumit; Houseworth, Jim; Birkholzer, Jens

    2014-08-14

    In this report, we present FY2014 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. LBNL’s work on the modeling of coupled THMC processes in salt was initiated in FY2012, focusing on exploring and demonstrating the capabilities of an existing LBNL modeling tool (TOUGH-FLAC) for simulating temperature-driven coupled flow and geomechanical processes in salt. This work includes development related to, and implementation of, essential capabilities, as well as testing the model against relevant information and published experimental data related to the fate and transport of water. we provide more details on the FY2014 work, first presenting updated tools and improvements made to the TOUGH-FLAC simulator, and the use of this updated tool in a new model simulation of long-term THM behavior within a generic repository in a salt formation. This is followed by the description of current benchmarking and validations efforts, including the TSDE experiment. We then present the current status in the development of constitutive relationships and the dual-continuum model for brine migration. We conclude with an outlook for FY2015, which will be much focused on model validation against field experiments and on the use of the model for the design studies related to a proposed heater experiment.

  14. Analysis of the structural parameters that influence gas production from the Devonian shale. Annual progress report, 1979-1980. Volume II. Data repository and reports published during fiscal year 1979-1980: regional structure, surface structure, surface fractures, hydrology

    SciTech Connect (OSTI)

    Negus-De Wys, J.; Dixon, J. M.; Evans, M. A.; Lee, K. D.; Ruotsala, J. E.; Wilson, T. H.; Williams, R. T.

    1980-10-01

    This volume comprises appendices giving regional structure data, surface structure data, surface fracture data, and hydrology data. The fracture data covers oriented Devonian shale cores from West Virginia, Ohio, Virginia, Pennsylvania, and Kentucky. The subsurface structure of the Eastern Kentucky gas field is also covered. (DLC)

  15. Brine-in-crude-oil emulsions at the Strategic Petroleum Reserve.

    SciTech Connect (OSTI)

    Nemer, Martin B.; Lord, David L.; MacDonald, Terry L.

    2013-10-01

    Metastable water-in-crude-oil emulsion formation could occur in a Strategic Petroleum Reserve (SPR) cavern if water were to flow into the crude-oil layer at a sufficient rate. Such a situation could arise during a drawdown from a cavern with a broken-hanging brine string. A high asphaltene content (> 1.5 wt %) of the crude oil provides the strongest predictor of whether a metastable water-in-crude-oil emulsion will form. However there are many crude oils with an asphaltene content > 1.5 wt % that don't form stable emulsions, but few with a low asphaltene content that do form stable emulsions. Most of the oils that form stable emulsions are %E2%80%9Csour%E2%80%9D by SPR standards indicating they contain total sulfur > 0.50 wt %.

  16. Evaluation of materials for systems using cooled, treated geothermal or high-saline brines

    SciTech Connect (OSTI)

    Suciu, D.F.; Wikoff, P.M.

    1982-09-01

    Lack of adequate quantities of clean surface water for use in wet (evaporative) cooling systems indicates the use of high-salinity waste waters, or cooled geothermal brines, for makeup purposes. High-chloride, aerated water represents an extremely corrosive environment. In order to determine metals suitable for use in such an environment, metal coupons were exposed to aerated, treated geothermal brine salted to a chloride concentration of 10,000 and 50,000 ppM (mg/L) for periods of up to 30 days. The exposed coupons were evaluated to determine the general, pitting, and crevice corrosion characteristics of the metals. The metals exhibiting corrosion resistance at 50,000 ppM chloride were then evaluated at 100,000 and 200,000 ppM chloride. Since these were screening tests to select materials for components to be used in a cooling system, with primary emphasis on condenser tubing, several materials were exposed for 4 to 10 months in pilot cooling tower test units with heat transfer for further corrosion evaluation. The results of the screening tests indicate that ferritic stainless steels (29-4-2 and SEA-CURE) exhibit excellent corrosion resistance at all levels of chloride concentration. Copper-nickel alloys (70/30 and Monel 400) exhibited excellent corrosion resistance in the high-saline water. The 70/30 copper-nickel alloy, which showed excellent resistance to general corrosion, exhibited mild pitting in the 30-day tests. This pitting was not apparent, however, after 6 months of exposure in the pilot cooling tower tests. The nickel-base alloys exhibited excellent corrosion resistance, but their high cost prevents their use unless no other material is found feasible. Other materials tested, although unsuitable for condenser tubing material, would be suitable as tube sheet material.

  17. Reduced order models for prediction of groundwater quality impacts from CO₂ and brine leakage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Liange; Carroll, Susan; Bianchi, Marco; Mansoor, Kayyum; Sun, Yunwei; Birkholzer, Jens

    2014-12-31

    A careful assessment of the risk associated with geologic CO₂ storage is critical to the deployment of large-scale storage projects. A potential risk is the deterioration of groundwater quality caused by the leakage of CO₂ and brine leakage from deep subsurface reservoirs. In probabilistic risk assessment studies, numerical modeling is the primary tool employed to assess risk. However, the application of traditional numerical models to fully evaluate the impact of CO₂ leakage on groundwater can be computationally complex, demanding large processing times and resources, and involving large uncertainties. As an alternative, reduced order models (ROMs) can be used as highlymore » efficient surrogates for the complex process-based numerical models. In this study, we represent the complex hydrogeological and geochemical conditions in a heterogeneous aquifer and subsequent risk by developing and using two separate ROMs. The first ROM is derived from a model that accounts for the heterogeneous flow and transport conditions in the presence of complex leakage functions for CO₂ and brine. The second ROM is obtained from models that feature similar, but simplified flow and transport conditions, and allow for a more complex representation of all relevant geochemical reactions. To quantify possible impacts to groundwater aquifers, the basic risk metric is taken as the aquifer volume in which the water quality of the aquifer may be affected by an underlying CO₂ storage project. The integration of the two ROMs provides an estimate of the impacted aquifer volume taking into account uncertainties in flow, transport and chemical conditions. These two ROMs can be linked in a comprehensive system level model for quantitative risk assessment of the deep storage reservoir, wellbore leakage, and shallow aquifer impacts to assess the collective risk of CO₂ storage projects.« less

  18. Reduced order models for prediction of groundwater quality impacts from CO? and brine leakage

    SciTech Connect (OSTI)

    Zheng, Liange; Carroll, Susan; Bianchi, Marco; Mansoor, Kayyum; Sun, Yunwei; Birkholzer, Jens

    2014-12-31

    A careful assessment of the risk associated with geologic CO? storage is critical to the deployment of large-scale storage projects. A potential risk is the deterioration of groundwater quality caused by the leakage of CO? and brine leakage from deep subsurface reservoirs. In probabilistic risk assessment studies, numerical modeling is the primary tool employed to assess risk. However, the application of traditional numerical models to fully evaluate the impact of CO? leakage on groundwater can be computationally complex, demanding large processing times and resources, and involving large uncertainties. As an alternative, reduced order models (ROMs) can be used as highly efficient surrogates for the complex process-based numerical models. In this study, we represent the complex hydrogeological and geochemical conditions in a heterogeneous aquifer and subsequent risk by developing and using two separate ROMs. The first ROM is derived from a model that accounts for the heterogeneous flow and transport conditions in the presence of complex leakage functions for CO? and brine. The second ROM is obtained from models that feature similar, but simplified flow and transport conditions, and allow for a more complex representation of all relevant geochemical reactions. To quantify possible impacts to groundwater aquifers, the basic risk metric is taken as the aquifer volume in which the water quality of the aquifer may be affected by an underlying CO? storage project. The integration of the two ROMs provides an estimate of the impacted aquifer volume taking into account uncertainties in flow, transport and chemical conditions. These two ROMs can be linked in a comprehensive system level model for quantitative risk assessment of the deep storage reservoir, wellbore leakage, and shallow aquifer impacts to assess the collective risk of CO? storage projects.

  19. Using presence of calcite cap rock in shales to predict occurrence of reservoirs composed of leached secondary porosity in the geopressured zone. Annual report, June 1, 1980-October 31, 1980

    SciTech Connect (OSTI)

    Kaiser, W.R.; Magara, K.; Milliken, K.L.; Richmann, D.L.

    1981-01-01

    The distribution of high-resistivity shale in the Frio Formation between hydropressured and geopressured strata has been mapped along the Texas Gulf Coast. Two high-resistivity intervals more than 1000 ft thick have been mapped, one in Brazoria and Galveston Counties and the other in Kenedy County. They coincide with Frio delta systems and may be related to extraordinary quantities of CO/sub 2/ produced by deltaic sediments rich in woody and herbaceous matter. Beyond being calcareous, the nature of the high-resistivity interval is enigmatic and its relationship to deep secondary porosity problematic. Most of the contained carbonate is microscopically and isotopically skeletal in origin, revealing no evidence of diagenetic modification. Minor rhombs of iron-bearing carbonate tens of microns in size were identified. Detrital feldspar compositions are being established to test subsequent changes in feldspar composition resulting from progressive burial and albitization. Hydrolysis reactions for authigenic minerals and reactions between key pairs of minerals have been written. Thermodynamic functions for complex phyllosilicates at temperatures up to 200/sup 0/C have been calculated. From thermodynamic calculations it was predicted that ferroan calcite would be the favored authigenic carbonate in shales.

  20. A resource evaluation of the Bakken Formation (Upper Devonian and Lower Mississippian) continuous oil accumulation, Williston Basin, North Dakota and Montana

    SciTech Connect (OSTI)

    Schmoker, J.W.

    1996-01-01

    The Upper Devonian and Lower Mississippian Bakken Formation in the United States portion of the Williston Basin is both the source and the reservoir for a continuous oil accumulation -- in effect a single very large field -- underlying approximately 17,800 mi{sup 2} (46,100 km{sup 2}) of North Dakota and Montana. Within this area, the Bakken Formation continuous oil accumulation is not significantly influenced by the water column and cannot be analyzed in terms of conventional, discrete fields. Rather, the continuous accumulation can be envisioned as a collection of oil-charged cells, virtually all of which are capable of producing some oil, but which vary significantly in their production characteristics. Better well-performance statistics are linked regionally to higher levels of thermal maturity and to lower levels of reservoir heterogeneity. Although portions of the Bakken Formation continuous oil accumulation have reached a mature stage of development, the accumulation as a whole is far from depleted.

  1. Regional geological assessment of the Devonian-Mississippian shale sequence of the Appalachian, Illinois, and Michigan basins relative to potential storage/disposal of radioactive wastes

    SciTech Connect (OSTI)

    Lomenick, T.F.; Gonzales, S.; Johnson, K.S.; Byerly, D.

    1983-01-01

    The thick and regionally extensive sequence of shales and associated clastic sedimentary rocks of Late Devonian and Early Mississippian age has been considered among the nonsalt geologies for deep subsurface containment of high-level radioactive wastes. This report examines some of the regional and basin-specific characteristics of the black and associated nonblack shales of this sequence within the Appalachian, Illinois, and Michigan basins of the north-central and eastern United States. Principal areas where the thickness and depth of this shale sequence are sufficient to warrant further evaluation are identified, but no attempt is made to identify specific storage/disposal sites. Also identified are other areas with less promise for further study because of known potential conflicts such as geologic-hydrologic factors, competing subsurface priorities involving mineral resources and groundwater, or other parameters. Data have been compiled for each basin in an effort to indicate thickness, distribution, and depth relationships for the entire shale sequence as well as individual shale units in the sequence. Included as parts of this geologic assessment are isopach, depth information, structure contour, tectonic elements, and energy-resource maps covering the three basins. Summary evaluations are given for each basin as well as an overall general evaluation of the waste storage/disposal potential of the Devonian-Mississippian shale sequence,including recommendations for future studies to more fully characterize the shale sequence for that purpose. Based on data compiled in this cursory investigation, certain rock units have reasonable promise for radioactive waste storage/disposal and do warrant additional study.

  2. REE Sorption Study on sieved -50 +100 mesh fraction of Media #1 in Brine #1 with Different Starting pH's at 70C

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gary Garland

    2015-09-29

    This is a continuation of the REE sorption study for shaker bath tests on 2g media #1 in 150mL brine #1 with different starting pH's at 70C. In a previous submission we reported data for shaker bath tests for brine #1 with starting pH's of 3.5, 4.5 and 5.5. In this submission we these pH's compared to starting brine #1 pH's of 6, and 7.

  3. Radioactive waste isolation in salt: geochemistry of brine in rock salt in temperature gradients and gamma-radiation fields - a selective annotated bibliography

    SciTech Connect (OSTI)

    Hull, A.B.; Williams, L.B.

    1985-07-01

    Evaluation of the extensive research concerning brine geochemistry and transport is critically important to successful exploitation of a salt formation for isolating high-level radioactive waste. This annotated bibliography has been compiled from documents considered to provide classic background material on the interactions between brine and rock salt, as well as the most important results from more recent research. Each summary elucidates the information or data most pertinent to situations encountered in siting, constructing, and operating a mined repository in salt for high-level radioactive waste. The research topics covered include the basic geology, depositional environment, mineralogy, and structure of evaporite and domal salts, as well as fluid inclusions, brine chemistry, thermal and gamma-radiation effects, radionuclide migration, and thermodynamic properties of salts and brines. 4 figs., 6 tabs.

  4. Benefits and Costs of Brine Extraction for Increasing Injection Efficiency In geologic CO2 Sequestration

    SciTech Connect (OSTI)

    Davidson, Casie L.; Watson, David J.; Dooley, James J.; Dahowski, Robert T.

    2014-12-31

    Pressure increases attendant with CO2 injection into the subsurface drive many of the risk factors associated with commercial-scale CCS projects, impacting project costs and liabilities in a number of ways. The area of elevated pressure defines the area that must be characterized and monitored; pressure drives fluid flow out of the storage reservoir along higher-permeability pathways that might exist through the caprock into overlying aquifers or hydrocarbon reservoirs; and pressure drives geomechanical changes that could potentially impact subsurface infrastructure or the integrity of the storage system itself. Pressure also limits injectivity, which can increase capital costs associated with installing additional wells to meet a given target injection rate. The ability to mitigate pressure increases in storage reservoirs could have significant value to a CCS project, but these benefits are offset by the costs of the pressure mitigation technique itself. Of particular interest for CO2 storage operators is the lifetime cost of implementing brine extraction at a CCS project site, and the relative value of benefits derived from the extraction process. This is expected to vary from site to site and from one implementation scenario to the next. Indeed, quantifying benefits against costs could allow operators to optimize their return on project investment by calculating the most effective scenario for pressure mitigation. This work builds on research recently submitted for publication by the authors examining the costs and benefits of brine extraction across operational scenarios to evaluate the effects of fluid extraction on injection rate to assess the cost effectiveness of several options for reducing the number of injection wells required. Modeling suggests that extracting at 90% of the volumetric equivalent of injection rate resulted in a 1.8% improvement in rate over a non-extraction base case; a four-fold increase in extraction rate results in a 7.6% increase in

  5. Benefits and Costs of Brine Extraction for Increasing Injection Efficiency In geologic CO2 Sequestration

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Davidson, Casie L.; Watson, David J.; Dooley, James J.; Dahowski, Robert T.

    2014-12-31

    Pressure increases attendant with CO2 injection into the subsurface drive many of the risk factors associated with commercial-scale CCS projects, impacting project costs and liabilities in a number of ways. The area of elevated pressure defines the area that must be characterized and monitored; pressure drives fluid flow out of the storage reservoir along higher-permeability pathways that might exist through the caprock into overlying aquifers or hydrocarbon reservoirs; and pressure drives geomechanical changes that could potentially impact subsurface infrastructure or the integrity of the storage system itself. Pressure also limits injectivity, which can increase capital costs associated with installing additionalmore » wells to meet a given target injection rate. The ability to mitigate pressure increases in storage reservoirs could have significant value to a CCS project, but these benefits are offset by the costs of the pressure mitigation technique itself. Of particular interest for CO2 storage operators is the lifetime cost of implementing brine extraction at a CCS project site, and the relative value of benefits derived from the extraction process. This is expected to vary from site to site and from one implementation scenario to the next. Indeed, quantifying benefits against costs could allow operators to optimize their return on project investment by calculating the most effective scenario for pressure mitigation. This work builds on research recently submitted for publication by the authors examining the costs and benefits of brine extraction across operational scenarios to evaluate the effects of fluid extraction on injection rate to assess the cost effectiveness of several options for reducing the number of injection wells required. Modeling suggests that extracting at 90% of the volumetric equivalent of injection rate resulted in a 1.8% improvement in rate over a non-extraction base case; a four-fold increase in extraction rate results in a 7

  6. Targeted Pressure Management During CO2 Sequestration: Optimization of Well Placement and Brine Extraction

    SciTech Connect (OSTI)

    Cihan, Abdullah; Birkholzer, Jens; Bianchi, Marco

    2014-12-31

    Large-scale pressure increases resulting from carbon dioxide (CO2) injection in the subsurface can potentially impact caprock integrity, induce reactivation of critically stressed faults, and drive CO2 or brine through conductive features into shallow groundwater. Pressure management involving the extraction of native fluids from storage formations can be used to minimize pressure increases while maximizing CO2 storage. However, brine extraction requires pumping, transportation, possibly treatment, and disposal of substantial volumes of extracted brackish or saline water, all of which can be technically challenging and expensive. This paper describes a constrained differential evolution (CDE) algorithm for optimal well placement and injection/ extraction control with the goal of minimizing brine extraction while achieving predefined pressure contraints. The CDE methodology was tested for a simple optimization problem whose solution can be partially obtained with a gradient-based optimization methodology. The CDE successfully estimated the true global optimum for both extraction well location and extraction rate, needed for the test problem. A more complex example application of the developed strategy was also presented for a hypothetical CO2 storage scenario in a heterogeneous reservoir consisting of a critically stressed fault nearby an injection zone. Through the CDE optimization algorithm coupled to a numerical vertically-averaged reservoir model, we successfully estimated optimal rates and locations for CO2 injection and brine extraction wells while simultaneously satisfying multiple pressure buildup constraints to avoid fault activation and caprock fracturing. The study shows that the CDE methodology is a very promising tool to solve also other optimization problems related to GCS, such as reducing Area of Review, monitoring design, reducing risk of leakage and increasing storage capacity and trapping.

  7. Understanding Long-Term Solute Transport in Sedimentary Basins: Simulating Brine Migration in the Alberta Basin. Final Report

    SciTech Connect (OSTI)

    Alicia M. Wilson

    2009-11-30

    Mass transport in deep sedimentary basins places important controls on ore formation, petroleum migration, CO2 sequestration, and geochemical reactions that affect petroleum reservoir quality, but large-scale transport in this type of setting remains poorly understood. This lack of knowledge is highlighted in the resource-rich Alberta Basin, where geochemical and hydrogeologic studies have suggested residence times ranging from hundreds of millions of years to less than 5 My, respectively. Here we developed new hydrogeologic models that were constrained by geochemical observations to reconcile these two very different estimates. The models account for variable-density fluid flow, heat transport, solute transport, sediment deposition and erosion, sediment compressibility, and dissolution of salt deposits, including Cl/Br systematics. Prior interpretations of Cl/Br ratios in the Alberta Basin concluded that the brines were derived from evaporatively-concentrated brines that were subsequently diluted by seawater and freshwater; models presented here show that halite dissolution must have contributed strongly as well, which implies significantly greater rates of mass transport. This result confirms that Cl/Br ratios are subject to significant non-uniqueness and thus do not provide good independent indicators of the origin of brines. Salinity and Cl/Br ratios provided valuable new constraints for basin-scale models, however. Sensitivity studies revealed that permeabilities obtained from core- and field-scale tests were appropriate for basin-scale models, despite the differences in scale between the tests and the models. Simulations of groundwater age show that the residence time of porefluids in much of the basin is less than 100 My. Groundwater age increases with depth and approaches 200 My in the deepest part of the basin, but brines are significantly younger than their host rocks throughout the basin.

  8. Evaluation of brine disposal from the Bryan Mound site of the strategic petroleum reserve program. Final report

    SciTech Connect (OSTI)

    Case, Robert J.; Chittenden, Jr, Mark E.; Harper, Jr, Donald E.; Kelly, Jr, Francis J.; Loeblich, Laurel A.; McKinney, Larry D.; Minello, Thomas J.; Park, E. Taisoo; Randall, Robert E.; Slowey, J. Frank

    1981-01-01

    On March 10, 1980, the Department of Energy's Strategic Petroleum Reserve Program began leaching the Bryan Mound salt dome and discharging the resulting brine into the coastal waters off Freeport, Texas. During the months of March and April, a team of scientists and engineers from Texas A and M University conducted an intensive environmental study of the area surrounding the diffuser site. A pipeline has been laid from the Bryan Mound site to a location 12.5 statute miles (20 km) offshore. The last 3060 ft (933 m) of this pipeline is a 52-port diffuser through which brine can be discharged at a maximum rate of 680,000 barrels per day. Initially, 16 ports were open which permitted a maximum discharge rate of 350,000 barrels per day and a continuous brine discharge was achieved on March 13, 1980. The purpose of this report is to describe the findings of the project team during the intensive postdisposal study period of March and April, 1980. The major areas of investigation are physical oceanography, analysis of the discharge plume, water and sediment quality, nekton, benthos, phytoplankton, zooplankton, and data management.

  9. Experiments and modeling of variably permeable carbonate reservoir samples in contact with CO₂-acidified brines

    SciTech Connect (OSTI)

    Smith, Megan M.; Hao, Yue; Mason, Harris E.; Carroll, Susan A.

    2014-12-31

    Reactive experiments were performed to expose sample cores from the Arbuckle carbonate reservoir to CO₂-acidified brine under reservoir temperature and pressure conditions. The samples consisted of dolomite with varying quantities of calcite and silica/chert. The timescales of monitored pressure decline across each sample in response to CO₂ exposure, as well as the amount of and nature of dissolution features, varied widely among these three experiments. For all samples cores, the experimentally measured initial permeability was at least one order of magnitude or more lower than the values estimated from downhole methods. Nondestructive X-ray computed tomography (XRCT) imaging revealed dissolution features including “wormholes,” removal of fracture-filling crystals, and widening of pre-existing pore spaces. In the injection zone sample, multiple fractures may have contributed to the high initial permeability of this core and restricted the distribution of CO₂-induced mineral dissolution. In contrast, the pre-existing porosity of the baffle zone sample was much lower and less connected, leading to a lower initial permeability and contributing to the development of a single dissolution channel. While calcite may make up only a small percentage of the overall sample composition, its location and the effects of its dissolution have an outsized effect on permeability responses to CO₂ exposure. The XRCT data presented here are informative for building the model domain for numerical simulations of these experiments but require calibration by higher resolution means to confidently evaluate different porosity-permeability relationships.

  10. Recovery of Fresh Water Resources from Desalination of Brine Produced During Oil and Gas Production Operations

    SciTech Connect (OSTI)

    David B. Burnett; Mustafa Siddiqui

    2006-12-29

    Management and disposal of produced water is one of the most important problems associated with oil and gas (O&G) production. O&G production operations generate large volumes of brine water along with the petroleum resource. Currently, produced water is treated as a waste and is not available for any beneficial purposes for the communities where oil and gas is produced. Produced water contains different contaminants that must be removed before it can be used for any beneficial surface applications. Arid areas like west Texas produce large amount of oil, but, at the same time, have a shortage of potable water. A multidisciplinary team headed by researchers from Texas A&M University has spent more than six years is developing advanced membrane filtration processes for treating oil field produced brines The government-industry cooperative joint venture has been managed by the Global Petroleum Research Institute (GPRI). The goal of the project has been to demonstrate that treatment of oil field waste water for re-use will reduce water handling costs by 50% or greater. Our work has included (1) integrating advanced materials into existing prototype units and (2) operating short and long-term field testing with full size process trains. Testing at A&M has allowed us to upgrade our existing units with improved pre-treatment oil removal techniques and new oil tolerant RO membranes. We have also been able to perform extended testing in 'field laboratories' to gather much needed extended run time data on filter salt rejection efficiency and plugging characteristics of the process train. The Program Report describes work to evaluate the technical and economical feasibility of treating produced water with a combination of different separation processes to obtain water of agricultural water quality standards. Experiments were done for the pretreatment of produced water using a new liquid-liquid centrifuge, organoclay and microfiltration and ultrafiltration membranes for the

  11. Experiments and modeling of variably permeable carbonate reservoir samples in contact with CO₂-acidified brines

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Megan M.; Hao, Yue; Mason, Harris E.; Carroll, Susan A.

    2014-12-31

    Reactive experiments were performed to expose sample cores from the Arbuckle carbonate reservoir to CO₂-acidified brine under reservoir temperature and pressure conditions. The samples consisted of dolomite with varying quantities of calcite and silica/chert. The timescales of monitored pressure decline across each sample in response to CO₂ exposure, as well as the amount of and nature of dissolution features, varied widely among these three experiments. For all samples cores, the experimentally measured initial permeability was at least one order of magnitude or more lower than the values estimated from downhole methods. Nondestructive X-ray computed tomography (XRCT) imaging revealed dissolution featuresmore » including “wormholes,” removal of fracture-filling crystals, and widening of pre-existing pore spaces. In the injection zone sample, multiple fractures may have contributed to the high initial permeability of this core and restricted the distribution of CO₂-induced mineral dissolution. In contrast, the pre-existing porosity of the baffle zone sample was much lower and less connected, leading to a lower initial permeability and contributing to the development of a single dissolution channel. While calcite may make up only a small percentage of the overall sample composition, its location and the effects of its dissolution have an outsized effect on permeability responses to CO₂ exposure. The XRCT data presented here are informative for building the model domain for numerical simulations of these experiments but require calibration by higher resolution means to confidently evaluate different porosity-permeability relationships.« less

  12. Evaluation of brine disposal from the Bryan Mound site of the Strategic Petroleum Reserve Program. Final report

    SciTech Connect (OSTI)

    Hann, R.W. Jr.; Randall, R.E.

    1980-12-01

    The purpose of this report is to describe the environmental conditions found by the principal investigators during the predisposal study conducted from September 1977 through February 1980 prior to the start of brine discharge in March 1980. The major areas of investigation are physical oceanography, analysis of the discharge plume, water and sediment quality, nekton, benthos, phytoplankton, zooplankton, and data management. Volume 1 describes the results of the predisposal study, and it is divided into eight chapters entitled: Physical Oceanography, Analysis of the Discharge Plume, Water and Sediment Quality, Nekton, Benthos, Zooplankton, Phytoplankton, and Data Management. Volume 2 consists of appendices which contain additional supporting data in the form of figures and tables.

  13. The implications of UIC and NPDES regulations on selection of disposal options for spent geothermal brine

    SciTech Connect (OSTI)

    1982-07-01

    This document reviews and evaluates the various options for the disposal of geothermal wastewater with respect to the promulgated regulations for the protection of surface and groundwaters. The Clean Water Act of 1977 and the Safe Drinking Water Act Amendments are especially important when designing disposal systems for geothermal fluids. The former promulgates regulations concerning the discharge of wastewater into surface waters, while the latter is concerned with the protection of ground water aquifers through the establishment of underground injection control (UIC) programs. There is a specific category for geothermal fluid discharge if injection is to be used as a method of disposal. Prior to February 1982, the UIC regulations required geothermal power plant to use Class III wells and direct use plants to use Class V wells. More stringent regulatory requirements, including construction specification and monitoring, are imposed on the Class III wells. On February 3, 1982, the classification of geothermal injection wells was changed from a Class III to Class V on the basis that geothermal wells do not inject for the extraction of minerals or energy, but rather they are used to inject brines, from which heat has been extracted, into formations from which they were originally taken. This reclassification implies that a substantial cost reduction will be realized for geothermal fluid injection primarily because well monitoring is no longer mandatory. The Clean Water Act of 1977 provides the legal basis for regulating the discharge of liquid effluent into the nation's surface waters, through a permitting system called the National Pollution Discharge Elimination System (NPDES) Discharge quantities, rates, concentrations and temperatures are regulated by the NPDES permits. These permits systems are based upon effluent guidelines developed by EPA on an industry by industry basis. For geothermal energy industry, effluent guidelines have not been formulated and are not

  14. Modifications of Carbonate Fracture Hydrodynamic Properties by CO{sub 2}-Acidified Brine Flow

    SciTech Connect (OSTI)

    Deng, Hang; Ellis, Brian R.; Peters, Catherine A.; Fitts, Jeffrey P.; Crandall, Dustin; Bromhal, Grant S.

    2013-08-01

    Acidic reactive flow in fractures is relevant in subsurface activities such as CO{sub 2} geological storage and hydraulic fracturing. Understanding reaction-induced changes in fracture hydrodynamic properties is essential for predicting subsurface flows such as leakage, injectability, and fluid production. In this study, x-ray computed tomography scans of a fractured carbonate caprock were used to create three dimensional reconstructions of the fracture before and after reaction with CO{sub 2}-acidified brine (Ellis et al., 2011, Greenhouse Gases: Sci. Technol., 1:248-260). As expected, mechanical apertures were found to increase substantially, doubling and even tripling in some places. However, the surface geometry evolved in complex ways including ‘comb-tooth’ structures created from preferential dissolution of calcite in transverse sedimentary bands, and the creation of degraded zones, i.e. porous calcite-depleted areas on reacted fracture surfaces. These geometric alterations resulted in increased fracture roughness, as measured by surface Z{sub 2} parameters and fractal dimensions D{sub f}. Computational fluid dynamics (CFD) simulations were conducted to quantify the changes in hydraulic aperture, fracture transmissivity and permeability. The results show that the effective hydraulic apertures are smaller than the mechanical apertures, and the changes in hydraulic apertures are nonlinear. Overestimation of flow rate by a factor of two or more would be introduced if fracture hydrodynamic properties were based on mechanical apertures, or if hydraulic aperture is assumed to change proportionally with mechanical aperture. The differences can be attributed, in part, to the increase in roughness after reaction, and is likely affected by contiguous transverse sedimentary features. Hydraulic apertures estimated by the 1D statistical model and 2D local cubic law (LCL) model are consistently larger than those calculated from the CFD simulations. In addition, a novel

  15. GEOCHEMICAL INVESTIGATIONS OF CO₂-BRINE-ROCK INTERACTIONS OF THE KNOX GROUP IN THE ILLINOIS BASIN

    SciTech Connect (OSTI)

    Yoksoulian, Lois; Berger, Peter; Freiburg, Jared; Butler, Shane; Leetaru, Hannes

    2014-09-30

    study suggests only limited potential for the release of United States Environmental Protection Agency regulated inorganic contaminants into potable water sources. Short-term core flood experiments further verify that the carbonate reactions occurring in Knox Group reservoir samples reach equilibrium rapidly. The core flood experiments also lend insight to pressure changes that may occur during CO₂ injection. The Maquoketa Shale experiments reveal that this rock is initially chemically reactive when in contact with CO₂ and brine. However, due to the conservative nature of silicate and clay reaction kinetics and the rapid equilibration of carbonate reactions that occur in the shale, these reactions would not present a significant risk to the competency of the shale as an effective seal rock.

  16. Evaporite Caprock Integrity. An experimental study of reactive mineralogy and pore-scale heterogeneity during brine-CO2 exposure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Megan M.; Sholokhova, Yelena; Hao, Yue; Carroll, Susan A.

    2012-07-25

    Characterization and geochemical data are presented from a core-flooding experiment on a sample from the Three Fingers evaporite unit forming the lower extent of caprock at the Weyburn-Midale reservoir, Canada. This low-permeability sample was characterized in detail using X-ray computed microtomography before and after exposure to CO 2-acidified brine, allowing mineral phase and voidspace distributions to be quantified in three dimensions. Solution chemistry indicated that CO 2-acidified brine preferentially dissolved dolomite until saturation was attained, while anhydrite remained unreactive. Dolomite dissolution contributed to increases in bulk permeability through the formation of a localized channel, guided by microfractures as well asmore » porosity and reactive phase distributions aligned with depositional bedding. An indirect effect of carbonate mineral reactivity with CO 2-acidified solution is voidspace generation through physical transport of anhydrite freed from the rock matrix following dissolution of dolomite. The development of high permeability fast pathways in this experiment highlights the role of carbonate content and potential fracture orientations in evaporite caprock formations considered for both geologic carbon sequestration and CO 2-enhanced oil recovery operations.« less

  17. Wetting behavior of selected crude oil/brine/rock systems. Topical report, March 1, 1995--March 31, 1996

    SciTech Connect (OSTI)

    Zhou, X.; Morrow, N.R.; Ma, S.

    1996-12-31

    Previous studies of crude oil/brine/rock (COBR) and related ensembles showed that wettability and its effect on oil recovery depend on numerous complex interactions. In the present work, the wettability of COBR ensembles prepared using Prudhoe Bay crude oil, a synthetic formation brine, and Berea Sandstone was varied by systematic change in initial water saturation and length of aging time at reservoir temperature (88 C). All displacement tests were run at ambient temperature. Various degrees of water wetness were achieved and quantified by a modified Amott wettability index to water, the relative pseudo work of imbibition, and a newly defined apparent advancing dynamic contact angle. Pairs of spontaneous imbibition (oil recovery by spontaneous imbibition of water) and waterflood (oil recovery vs. pore volumes of water injected) curves were measured for each of the induced wetting states. Several trends were observed. Imbibition rate, and hence water wetness, decreased with increase in aging time and with decrease in initial water saturation. Breakthrough recoveries and final oil recovery by waterflooding increased with decrease in water wetness. Correlations between water wetness and oil recovery by waterflooding and spontaneous imbibition are presented.

  18. Environmental assessment of the brine pipeline replacement for the Strategic Petroleum Reserve Bryan Mound Facility in Brazoria County, Texas

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    The Department of Energy (DOE) has prepared an environmental assessment (EA), DOE/EA-0804, for the proposed replacement of a deteriorated brine disposal pipeline from the Strategic Petroleum Reserve (SPR) Bryan Mound storage facility in Brazoria County, Texas, into the Gulf of Mexico. In addition, the ocean discharge outfall would be moved shoreward by locating the brine diffuser at the end of the pipeline 3.5 miles offshore at a minimum depth of 30 feet. The action would occur in a floodplain and wetlands; therefore, a floodplain/wetlands assessment has been prepared in conjunction with this EA. Based on the analyses in the EA, DOE has determined that the proposed action is not a major Federal action significantly affecting the quality of the human environment within the meaning of the National Environmental Policy Act (NEPA) of 1969 (42 USC. 4321, et seg.). Therefore, the preparation of an Environmental Impact Statement (EIS) is not required, and the Department is issuing this Finding of No Significant Impact (FONSI). This FONSI also includes a Floodplain Statement of Findings in accordance with 10 CFR Part 1022.

  19. REE Sorption Study for Media #1 and Media #2 in Brine #1 and #2 at different Liquid to Solid Ratio's at Ambient Temperature

    SciTech Connect (OSTI)

    Gary Garland

    2015-03-27

    This data set shows the different loading capacities of Media #1 and Media #2 in a high and low salt content brine matrix at different liquid to solid ratio's. These data sets are shaker bath tests on media #1 and media #2 in brine's #1 and #2 at 500mL-.5g(1000-1 ratio), 150mL-.75g(200-1 ratio), and 150mL-2.5g(60-1 ratio) at ambient temperature.

  20. REE Sorption Study of Sieved -50 +100 mesh Media #1 in Brine #1 with Different Starting pH's at 70C

    SciTech Connect (OSTI)

    Gary Garland

    2015-07-21

    This dataset described shaker table experiments ran with sieved -50 +100 mesh media #1 in brine #1 that have 2ppm each of the 7 REE metals at different starting pH's of 3.5, 4.5, and 5.5. The experimental conditions are 2g media to 150mL of REE solution, at 70C.

  1. Rare-earth elements in hot brines (165 to 190 degree C) from the Salton Sea geothermal field

    SciTech Connect (OSTI)

    Lepel, E.A.; Laul, J.C.; Smith, M.R.

    1988-01-01

    Rare-earth element (REE) concentrations are important indicators for revealing various chemical fractionation processes (water/rock interactions) and source region geochemistry. Since the REE patterns are characteristic of geologic materials (basalt, granite, shale, sediments, etc.) and minerals (K-feldspar, calcite, illite, epidote, etc.), their study in geothermal fluids may serve as a geothermometer. The REE study may also enable us to address the issue of groundwater mixing. In addition, the behavior of the REE can serve as analogs of the actinides in radioactive waste (e.g., neodymium is an analog of americium and curium). In this paper, the authors port the REE data for a Salton Sea Geothermal Field (SSGF) brine (two aliquots: port 4 at 165{degree}C and port 5 at 190{degree}C) and six associated core samples.

  2. Reactive transport modeling to study changes in water chemistry induced by CO2 injection at the Frio-I brine pilot

    SciTech Connect (OSTI)

    Kharaka, Y.K; Doughty, C.; Freifeld, B.M.; Daley, T.M.; Xu, T.

    2009-11-01

    To demonstrate the potential for geologic storage of CO{sub 2} in saline aquifers, the Frio-I Brine Pilot was conducted, during which 1600 tons of CO{sub 2} were injected into a high-permeability sandstone and the resulting subsurface plume of CO{sub 2} was monitored using a variety of hydrogeological, geophysical, and geochemical techniques. Fluid samples were obtained before CO{sub 2} injection for baseline geochemical characterization, during the CO{sub 2} injection to track its breakthrough at a nearby observation well, and after injection to investigate changes in fluid composition and potential leakage into an overlying zone. Following CO{sub 2} breakthrough at the observation well, brine samples showed sharp drops in pH, pronounced increases in HCO{sub 3}{sup -} and aqueous Fe, and significant shifts in the isotopic compositions of H{sub 2}O and dissolved inorganic carbon. Based on a calibrated 1-D radial flow model, reactive transport modeling was performed for the Frio-I Brine Pilot. A simple kinetic model of Fe release from the solid to aqueous phase was developed, which can reproduce the observed increases in aqueous Fe concentration. Brine samples collected after half a year had lower Fe concentrations due to carbonate precipitation, and this trend can be also captured by our modeling. The paper provides a method for estimating potential mobile Fe inventory, and its bounding concentration in the storage formation from limited observation data. Long-term simulations show that the CO{sub 2} plume gradually spreads outward due to capillary forces, and the gas saturation gradually decreases due to its dissolution and precipitation of carbonates. The gas phase is predicted to disappear after 500 years. Elevated aqueous CO{sub 2} concentrations remain for a longer time, but eventually decrease due to carbonate precipitation. For the Frio-I Brine Pilot, all injected CO{sub 2} could ultimately be sequestered as carbonate minerals.

  3. Interpretation of brine-permeability tests of the Salado Formation at the Waste Isolation Pilot Plant site: First interim report

    SciTech Connect (OSTI)

    Beauheim, R.L. ); Saulnier, G.J. Jr.; Avis, J.D. )

    1991-08-01

    Pressure-pulse tests have been performed in bedded evaporites of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) site to evaluate the hydraulic properties controlling brine flow through the Salado. Hydraulic conductivities ranging from about 10{sup {minus}14} to 10{sup {minus}11} m/s (permeabilities of about 10{sup {minus}21} to 10{sup {minus}18} m{sup 2}) have been interpreted from nine tests conducted on five stratigraphic intervals within eleven meters of the WIPP underground excavations. Tests of a pure halite layer showed no measurable permeability. Pore pressures in the stratigraphic intervals range from about 0.5 to 9.3 MPa. An anhydrite interbed (Marker Bed 139) appears to be one or more orders of magnitude more permeable than the surrounding halite. Hydraulic conductivities appear to increase, and pore pressures decrease, with increasing proximity to the excavations. These effects are particularly evident within two to three meters of the excavations. Two tests indicated the presence of apparent zero-flow boundaries about two to three meters from the boreholes. The other tests revealed no apparent boundaries within the radii of influence of the tests, which were calculated to range from about four to thirty-five meters from the test holes. The data are insufficient to determine if brine flow through evaporites results from Darcy-like flow driven by pressure gradients within naturally interconnected porosity or from shear deformation around excavations connecting previously isolated pores, thereby providing pathways for fluids at or near lithostatic pressure to be driven towards the low-pressure excavations. Future testing will be performed at greater distances from the excavations to evaluate hydraulic properties and processes beyond the range of excavation effects.

  4. Effect of Oxygen Co-Injected with Carbon Dioxide on Gothic Shale Caprock-CO2-Brine Interaction during Geologic Carbon Sequestration

    SciTech Connect (OSTI)

    Jung, Hun Bok; Um, Wooyong; Cantrell, Kirk J.

    2013-09-16

    Co-injection of oxygen, a significant component in CO2 streams produced by the oxyfuel combustion process, can cause a significant alteration of the redox state in deep geologic formations during geologic carbon sequestration. The potential impact of co-injected oxygen on the interaction between synthetic CO2-brine (0.1 M NaCl) and shale caprock (Gothic shale from the Aneth Unit in Utah) and mobilization of trace metals was investigated at ~10 MPa and ~75 °C. A range of relative volume percentages of O2 to CO2 (0, 1, 4 and 8%) were used in these experiments to address the effect of oxygen on shale-CO2-brine interaction under various conditions. Major mineral phases in Gothic shale are quartz, calcite, dolomite, montmorillonite, and pyrite. During Gothic shale-CO2-brine interaction in the presence of oxygen, pyrite oxidation occurred extensively and caused enhanced dissolution of calcite and dolomite. Pyrite oxidation and calcite dissolution subsequently resulted in the precipitation of Fe(III) oxides and gypsum (CaSO4•2H2O). In the presence of oxygen, dissolved Mn and Ni were elevated because of oxidative dissolution of pyrite. The mobility of dissolved Ba was controlled by barite (BaSO4) precipitation in the presence of oxygen. Dissolved U in the experimental brines increased to ~8–14 g/L, with concentrations being slightly higher in the absence of oxygen than in the presence of oxygen. Experimental and modeling results indicate the interaction between shale caprock and oxygen co-injected with CO2 during geologic carbon sequestration can exert significant impacts on brine pH, solubility of carbonate minerals, stability of sulfide minerals, and mobility of trace metals. The major impact of oxygen is most likely to occur in the zone near CO2 injection wells where impurity gases can accumulate. Oxygen in CO2-brine migrating away from the injection well will be continually consumed through the reactions with sulfide minerals in deep geologic formations.

  5. Low Temperature/Coproduced/Geopressured Subprogram Overview ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications AAPG Low-Temperature Webinar SMU Geothermal Conference 2011 - Geothermal Technologies Program Geothermal Energy Production with Co-produced and ...

  6. Geopressured-geothermal energy, US Gulf Coast

    SciTech Connect (OSTI)

    Bebout, D.G.; Bachman, A.L.

    1981-01-01

    Sixty-five papers are included. Eleven papers were entered into the data base previously. Separate abstracts were prepared for fifty-four. (MHR)

  7. REE Sorption Study of Seived -50 +100 Mesh Fraction of Media #1 in Brine #1 at Different Concentrations of REE at 70C

    SciTech Connect (OSTI)

    Gary Garland

    2015-06-29

    This dataset shows the sorption capacities of smaller grain size (-50 +100 mesh) of media #1 in brine #1 at different starting concentrations of REE's at elevated temperature of 70C. The experimental conditions are 2g of -50 +100 mesh media #1 to 150mL of REE solution at concentartions of .2ppm each, 2ppm each, and 20ppm each. The pH of the solution is 5.5, and the temperature was at 70C.

  8. Evaluation of experimentally measured and model-calculated pH for rock-brine-CO2 systems under geologic CO2 sequestration conditions

    SciTech Connect (OSTI)

    Shao, Hongbo; Thompson, Christopher J.; Cantrell, Kirk J.

    2013-11-14

    pH is an essential parameter for understanding the geochemical reactions that occur in rock-brine-CO2 systems when CO2 is injected into deep geologic formations for long-term storage. Due to a lack of reliable experimental methods, most laboratory studies conducted under geological CO2 sequestration (GCS) conditions have relied on thermodynamic modeling to estimate pH. The accuracy of these model predictions is typically uncertain. In our previous work, we have developed a method for pH determination by in-situ spectrophotometry. In the present work, we expanded the applicable pH range for this method and measured the pH of several rock-brine-CO2 systems at GCS conditions for five rock samples collected from ongoing GCS demonstration projects. Experimental measurements were compared with pH values calculated using several geochemical modeling approaches. The effect of different thermodynamic databases on the accuracy of model prediction was evaluated. Results indicate that the accuracy of model calculations is rock-dependent. For rocks comprised of carbonate and sandstone, model results generally agreed well with experimentally measured pH; however, for basalt, significant differences were observed. These discrepancies may be due to the models’ failure to fully account for certain reaction occurring between the basalt minerals the CO2-saturated brine solutions.

  9. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation “C”. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthitemore » component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation “C” sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.« less

  10. Accident Investigation of the February 7, 2013, Scissor Lift Accident in the West Hackberry Brine Tank-14 Resulting in Injury, Strategic Petroleum Reserve West Hackberry, LA

    Broader source: Energy.gov [DOE]

    On February 15, 2013, an Accident Investigation Board (the Board) was appointed to investigate an accident that resulted in serious injuries caused when a scissor lift tipped over in Brine Tank-14 (WHT-14) at the Strategic Petroleum Reserve, West Hackberry, Louisiana, site on February 7, 2013. The Board’s responsibilities have been completed with respect to this investigation. The analysis and the identification of the direct cause, root causes, contributing causes, and judgments of need resulting from this investigation were performed in accordance with the Department of Energy (DOE) Order 225.1B, Accident Investigations.

  11. Batteries from Brine

    Broader source: Energy.gov [DOE]

    Low-temp geothermal technologies are meeting a growing demand for strategic materials in clean manufacturing.

  12. Estimates of the solubilities of waste element radionuclides in waste isolation pilot plant brines: A report by the expert panel on the source term

    SciTech Connect (OSTI)

    Hobart, D.E.; Bruton, C.J.; Millero, F.J.; Chou, I.M.; Trauth, K.M.; Anderson, D.R.

    1996-05-01

    Evaluation of the long-term performance of the WIPP includes estimation of the cumulative releases of radionuclide elements to the accessible environment. Nonradioactive lead is added because of the large quantity expected in WIPP wastes. To estimate the solubilities of these elements in WIPP brines, the Panel used the following approach. Existing thermodynamic data were used to identify the most likely aqueous species in solution through the construction of aqueous speciation diagrams. Existing thermodynamic data and expert judgment were used to identify potential solubility-limiting solid phases. Thermodynamic data were used to calculate the activities of the radionuclide aqueous species in equilibrium with each solid. Activity coefficients of the radionuclide-bearing aqueous species were estimated using Pitzer`s equations. These activity coefficients were then used to calculate the concentration of each radionuclide at the 0.1 and 0.9 fractiles. The 0.5 fractile was chosen to represent experimental data with activity coefficient corrections as described above. Expert judgment was used to develop the 0.0, 0.25, 0.75, and 1.0 fractiles by considering the sensitivity of solubility to the potential variability in the composition of brine and gas, and the extent of waste contaminants, and extending the probability distributions accordingly. The results were used in the 1991 and 1992 performance assessment calculations. 68 refs.

  13. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1

    SciTech Connect (OSTI)

    Bacon, Diana H.

    2013-03-31

    The National Risk Assessment Partnership (NRAP) consists of 5 U.S DOE national laboratories collaborating to develop a framework for predicting the risks associated with carbon sequestration. The approach taken by NRAP is to divide the system into components, including injection target reservoirs, wellbores, natural pathways including faults and fractures, groundwater and the atmosphere. Next, develop a detailed, physics and chemistry-based model of each component. Using the results of the detailed models, develop efficient, simplified models, termed reduced order models (ROM) for each component. Finally, integrate the component ROMs into a system model that calculates risk profiles for the site. This report details the development of the Groundwater Geochemistry ROM for the Edwards Aquifer at PNNL. The Groundwater Geochemistry ROM for the Edwards Aquifer uses a Wellbore Leakage ROM developed at LANL as input. The detailed model, using the STOMP simulator, covers a 5x8 km area of the Edwards Aquifer near San Antonio, Texas. The model includes heterogeneous hydraulic properties, and equilibrium, kinetic and sorption reactions between groundwater, leaked CO2 gas, brine, and the aquifer carbonate and clay minerals. Latin Hypercube sampling was used to generate 1024 samples of input parameters. For each of these input samples, the STOMP simulator was used to predict the flux of CO2 to the atmosphere, and the volume, length and width of the aquifer where pH was less than the MCL standard, and TDS, arsenic, cadmium and lead exceeded MCL standards. In order to decouple the Wellbore Leakage ROM from the Groundwater Geochemistry ROM, the response surface was transformed to replace Wellbore Leakage ROM input parameters with instantaneous and cumulative CO2 and brine leakage rates. The most sensitive parameters proved to be the CO2 and brine leakage rates from the well, with equilibrium coefficients for calcite and dolomite, as well as the number of illite and kaolinite

  14. Numerical modeling of regional ground-water flow in the deep-basin brine aquifer of the Palo Duro Basin, Texas Panhandle

    SciTech Connect (OSTI)

    Wirojanagud, P.; Kreitler, C.W.; Smith, D.A.

    1986-01-01

    Bedded Permian-age evaporite sequences in the Palo Duro Basin are being considered for a permanent nuclear waste repository by the U.S. Department of Energy. The purpose of this modeling study is to provide an understanding of regional ground-water flow in the formations beneath the Permian evaporite section. From this understanding, more detailed, smaller scale studies can be designed. This study is also intended to provide a better understanding of the boundary conditions and permeabilities of the aquifer and aquitard system as well as provide estimates of ground-water travel times across the basin. Numerical simulations were made of the Wolfcamp aquifer modeled as a single layer and of the entire Deep-Basin Brine aquifer system, including the Wolfcamp aquifer, modeled as a single layer.

  15. An objective rapid screening tool for surfactants used in foam-like dispersions of CO{sub 2} into Permian Basin brines

    SciTech Connect (OSTI)

    Horton, R.L.; Wicks, J.P.; Prieditis, J.; Turbeville, J.B.

    1995-11-01

    Foam-like dispersions of CO{sub 2} into brines can reduce the mobility of drive fluids in CO{sub 2} floods. To evaluate the effectiveness of such foam-like dispersions, time-consuming laboratory coreflood tests are routinely used. Because of the costliness of such coreflood tests, simple qualitative tests have long been employed to screen potential surfactants. Then only a few of the better candidates are subsequently evaluated in coreflood tests. There are a number of disadvantages of such qualitative tests; therefore the authors developed, instead, a quantitative screening process. Their quantitative process is based on two simple, quick laboratory tests and a neural network interpretation of the test data. The neural network predicted CO{sub 2} mobility reduction values which correlated well with the mobility reductions seen in coreflood tests.

  16. Preliminary performance assessment for the Waste Isolation Pilot Plant, December 1992. Volume 5, Uncertainty and sensitivity analyses of gas and brine migration for undisturbed performance

    SciTech Connect (OSTI)

    Not Available

    1993-08-01

    Before disposing of transuranic radioactive waste in the Waste Isolation Pilot Plant (WIPP), the United States Department of Energy (DOE) must evaluate compliance with applicable long-term regulations of the United States Environmental Protection Agency (EPA). Sandia National Laboratories is conducting iterative performance assessments (PAs) of the WIPP for the DOE to provide interim guidance while preparing for a final compliance evaluation. This volume of the 1992 PA contains results of uncertainty and sensitivity analyses with respect to migration of gas and brine from the undisturbed repository. Additional information about the 1992 PA is provided in other volumes. Volume 1 contains an overview of WIPP PA and results of a preliminary comparison with 40 CFR 191, Subpart B. Volume 2 describes the technical basis for the performance assessment, including descriptions of the linked computational models used in the Monte Carlo analyses. Volume 3 contains the reference data base and values for input parameters used in consequence and probability modeling. Volume 4 contains uncertainty and sensitivity analyses with respect to the EPA`s Environmental Standards for the Management and Disposal of Spent Nuclear Fuel, High-Level and Transuranic Radioactive Wastes (40 CFR 191, Subpart B). Finally, guidance derived from the entire 1992 PA is presented in Volume 6. Results of the 1992 uncertainty and sensitivity analyses indicate that, conditional on the modeling assumptions and the assigned parameter-value distributions, the most important parameters for which uncertainty has the potential to affect gas and brine migration from the undisturbed repository are: initial liquid saturation in the waste, anhydrite permeability, biodegradation-reaction stoichiometry, gas-generation rates for both corrosion and biodegradation under inundated conditions, and the permeability of the long-term shaft seal.

  17. The CPA Equation of State and an Activity Coefficient Model for Accurate Molar Enthalpy Calculations of Mixtures with Carbon Dioxide and Water/Brine

    SciTech Connect (OSTI)

    Myint, P. C.; Hao, Y.; Firoozabadi, A.

    2015-03-27

    Thermodynamic property calculations of mixtures containing carbon dioxide (CO2) and water, including brines, are essential in theoretical models of many natural and industrial processes. The properties of greatest practical interest are density, solubility, and enthalpy. Many models for density and solubility calculations have been presented in the literature, but there exists only one study, by Spycher and Pruess, that has compared theoretical molar enthalpy predictions with experimental data [1]. In this report, we recommend two different models for enthalpy calculations: the CPA equation of state by Li and Firoozabadi [2], and the CO2 activity coefficient model by Duan and Sun [3]. We show that the CPA equation of state, which has been demonstrated to provide good agreement with density and solubility data, also accurately calculates molar enthalpies of pure CO2, pure water, and both CO2-rich and aqueous (H2O-rich) mixtures of the two species. It is applicable to a wider range of conditions than the Spycher and Pruess model. In aqueous sodium chloride (NaCl) mixtures, we show that Duan and Suns model yields accurate results for the partial molar enthalpy of CO2. It can be combined with another model for the brine enthalpy to calculate the molar enthalpy of H2O-CO2-NaCl mixtures. We conclude by explaining how the CPA equation of state may be modified to further improve agreement with experiments. This generalized CPA is the basis of our future work on this topic.

  18. West Hackberry Strategic Petroleum Reserve site brine disposal monitoring, Year I report. Volume V. Supporting data for estuarine hydrology, discharge plume analysis, chemical oceanography, biological oceanography, and data management. Final report

    SciTech Connect (OSTI)

    DeRouen, L.R.; Hann, R.W.; Casserly, D.M.; Giammona, C.; Lascara, V.J.

    1983-02-01

    This project centers around the Strategic Petroleum Site (SPR) known as the West Hackberry salt dome which located in southwestern Louisiana, and which is designed to store 241 million barrels of crude oil. Oil storage caverns are formed by injecting water into salt deposits, and pumping out the resulting brine. Studies described in this report were designed as follow-on studies to three months of pre-discharge characterization work, and include data collected during the first year of brine leaching operations. The objectives were to: (1) characterize the environment in terms of physical, chemical and biological attributes; (2) determine if significant adverse changes in ecosystem productivity and stability of the biological community are occurring as a result of brine discharge; and (3) determine the magnitude of any change observed. Volume V contains appendices for the following: supporting data for estuarine hydrology and hydrography; supporting data analysis of discharge plume; supporting data for water and sediment chemistry; CTD/DO and pH profiles during biological monitoring; supporting data for nekton; and supporting data for data management.

  19. The deep hydrogeologic flow system underlying the Oak Ridge Reservation -- Assessing the potential for active groundwater flow and origin of the brine

    SciTech Connect (OSTI)

    Nativ, R.; Halleran, A.; Hunley, A.

    1997-08-01

    The deep hydrogeologic system underlying the Oak Ridge Reservation (ORR) contains contaminants such as radionuclides, heavy metals, nitrates, and organic compounds. The groundwater in the deep system is saline and has been considered to be stagnant in previous studies. This study was designed to address the following questions: is groundwater in the deep system stagnant; is contaminant migration controlled by diffusion only or is advection a viable mechanism; where are the potential outlet points? On the basis of existing and newly collected data, the nature of saline groundwater flow and potential discharge into shallow, freshwater systems was assessed. Data used for this purpose included (1) spatial and temporal pressures and hydraulic heads measured in the deep system, (2) hydraulic parameters of the formations in question, (3) spatial and temporal temperature variations at depth, and (4) spatial and temporal chemical and isotopic composition of the saline groundwater. The observations suggest that the saline water contained at depth is old but not isolated (in terms of recharge and discharge) from the overlying active, freshwater-bearing units. Influx of recent water does occur. Groundwater volumes involved in this flow are likely to be small. The origin of the saline groundwater was assessed by using existing and newly acquired chemical and isotopic data. The proposed model that best fits the data is modification of residual brine from which halite has been precipitated. Other models, such as ultrafiltration and halite dissolution, were also evaluated.

  20. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    SciTech Connect (OSTI)

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation “C”. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthite component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation “C” sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.

  1. {gamma}-Radiolysis of NaCl Brine in the Presence of UO{sub 2}(s): Effects of Hydrogen and Bromide

    SciTech Connect (OSTI)

    Metz, Volker; Bohnert, Elke; Kelm, Manfred; Schild, Dieter; Kienzler, Bernhard

    2007-07-01

    A concentrated NaCl solution was {gamma}-irradiated in autoclaves under a pressure of 25 MPa. A set of experiments were conducted in 6 mol (kg H{sub 2}O){sup -1} NaCl solution in the presence of UO{sub 2}(s) pellets; in a second set of experiments, {gamma}-radiolysis of the NaCl brine was studied without UO{sub 2}(s). Hydrogen, oxygen and chlorate were formed as long-lived radiolysis products. Due to the high external pressure, all radiolysis products remained dissolved. H{sub 2} and O{sub 2} reached steady state concentrations in the range of 5.10{sup -3} to 6.10{sup -2} mol (kg H{sub 2}O){sup -1} corresponding to a partial gas pressure of {approx}2 to {approx}20 MPa. Radiolytic formation of hydrogen and oxygen increased with the concentration of bromide added to solution. Both, in the presence of bromide, resulting in a relatively high radiolytic yield, and in the absence of bromide surfaces of the UO{sub 2}(s) samples were oxidized, and concentration of dissolved uranium reached the solubility limit of the schoepite / NaUO{sub 2}O(OH)(cr) transition. At the end of the experiments, the pellets were covered by a surface layer of a secondary solid phase having a composition close to Na{sub 2}U{sub 2}O{sub 7}. The experimental results demonstrate that bromide counteracts an H{sub 2} inhibition effect on radiolysis gas production, even at a concentration ratio of [H{sub 2}] / [Br{sup -}] > 100. The present observations are related to the competitive reactions of OH radicals with H{sub 2}, Br{sup -} and Cl{sup -}. A similar competition of hydrogen and bromide, controlling the yield of {gamma}-radiolysis products, is expected for solutions of lower Cl{sup -} concentration. (authors)

  2. HIGH-PRESSURE SOLVENT EXTRACTION OF METHANE FROM GEOPRESSURED...

    Office of Scientific and Technical Information (OSTI)

    ... by conventional 4 pumping (electric motor drive) consumes the largest amount of ... Costs 100,000 1 50,000 3 i ; 26 Electric motor drive to supply at least 35% o f power ...

  3. Recovery Act: Demonstrating The Commercial Feasibility Of Geopressured...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A. Founded in 1974 B. Oilfield service company specializing in the transportation and disposal of non-hazardous E&P waste C. Operate state-of-the-art Class II commercial disposal ...

  4. HIGH-PRESSURE SOLVENT EXTRACTION OF METHANE FROM GEOPRESSURED...

    Office of Scientific and Technical Information (OSTI)

    ... If we assume a 25 year 6 1 6 J straight 1 ine depreciation, 10% royalty, 15% depletion ... the rate begins to decline and finally drop below an economic level of production. ...

  5. High-pressure solvent extraction of methane from geopressured...

    Office of Scientific and Technical Information (OSTI)

    followed by conventional mechanical pumping. The contributions of hydraulic (pressure) energy recovery and geothermal power production are also assessed. For deep injection into...

  6. Demonstrating the Commercial Feasibility of Geopressured-Geothermal...

    Open Energy Info (EERE)

    1 Recovery Act: Geothermal Technologies Program Project Type Topic 2 Geothermal Energy Production from Low Temperature Resources, Coproduced Fluids from Oil and Gas Wells, and...

  7. Review of Geopressured-Geothermal and Co-Production Research

    SciTech Connect (OSTI)

    Not Available

    1987-01-16

    This report is the minutes of the DOE/GRI/Industry meeting. They include a transcript of the questions and answers following each presentation and copies of slides and/or summaries prepared by each of the speakers.

  8. Low-Temperature, Coproduced, and Geopressured Geothermal Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Learn more about the program's new funding initiative in Mineral Recovery. PDF icon ltcgstrategicactionplan.pdf More Documents & Publications Low-Temperature, Coproduced, and ...

  9. Investigation and evaluation of geopressured-geothermal wells

    SciTech Connect (OSTI)

    Hartsock, J.H.; Rodgers, J.A.

    1980-09-01

    Over the life of the project, 1143 wildcat wells were screened for possible use. Although many did not meet the program's requirement for sand development, a surprisingly large number were abandoned because of downhole mechanical problems. Only 94 of these wells were completed as commercial hydrocarbon producers. Five wells of opportunity were funded for testing. Of these, two were evaluated for their hydraulic energy, thermal energy, and recoverable methane, and three were abandoned because of mechanical problems. (MHR)

  10. Geothermal Energy Production with Co-produced and Geopressured...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... power development at the Sweet Lake Oil and Gas Field in Cameron Parish, Louisiana. ... It's expected that the power plant(s) at the Sweet Lake Field site will create electricity ...

  11. Enhanced oil recovery system

    DOE Patents [OSTI]

    Goldsberry, Fred L.

    1989-01-01

    All energy resources available from a geopressured geothermal reservoir are used for the production of pipeline quality gas using a high pressure separator/heat exchanger and a membrane separator, and recovering waste gas from both the membrane separator and a low pressure separator in tandem with the high pressure separator for use in enhanced oil recovery, or in powering a gas engine and turbine set. Liquid hydrocarbons are skimmed off the top of geothermal brine in the low pressure separator. High pressure brine from the geothermal well is used to drive a turbine/generator set before recovering waste gas in the first separator. Another turbine/generator set is provided in a supercritical binary power plant that uses propane as a working fluid in a closed cycle, and uses exhaust heat from the combustion engine and geothermal energy of the brine in the separator/heat exchanger to heat the propane.

  12. Paleoecology of the Devonian-Mississippian black-shale sequence...

    Office of Scientific and Technical Information (OSTI)

    shales contain abundant evidence of life from upper parts of the water column such as fish fossils, conodonts, algae and other phytoplankton; however, there is a lack of evidence...

  13. Paleoecology of the Devonian-Mississippian black-shale sequence...

    Office of Scientific and Technical Information (OSTI)

    The black shales contain abundant evidence of life from upper parts of the water column such as fish fossils, conodonts, algae and other phytoplankton; however, there is a lack of ...

  14. Flow tests of the Gladys McCall well. Appendix A, Gladys McCall Site (Cameron Parish, LA): Final report, October 1985--October 1990

    SciTech Connect (OSTI)

    Randolph, P.L.; Hayden, C.G.; Rogers, L.A.

    1992-04-01

    This report pulls together the data from all of the geopressured-geothermal field research conducted at the Gladys McCall well. The well produced geopressured brine containing dissolved natural gas from the Lower Miocene sands at a depth of 15,150 to 16,650 feet. More than 25 million barrels of brine and 727 million standard cubic feet of natural gas were produced in a series of flow tests between December 1982 and October 1987 at various brine flow rates up to 28,000 barrels per day. Initial short-term flow tests for the Number 9 Sand found the permeability to be 67 to 85 md (millidarcies) for a brine volume of 85 to 170 million barrels. Initial short-term flow tests for the Number 8 Sand found a permeability of 113 to 132 md for a reservoir volume of 430 to 550 million barrels of brine. The long-term flow and buildup test of the Number 8 Sand found that the high-permeability reservoir connected to the wellbore (measured by the short-term flow test) was connected to a much larger, low-permeability reservoir. Numerical simulation of the flow and buildup tests required this large connected reservoir to have a volume of about 8 billion barrels (two cubic miles of reservoir rock) with effective permeabilities in the range of 0.2 to 20 md. Calcium carbonate scale formation in the well tubing and separator equipment was a problem. During the first 2 years of production, scale formation was prevented in the surface equipment by injection of an inhibitor upstream of the choke. Starting in 1985, scale formation in the production tubing was successfully prevented by injecting inhibitor ``pills`` directly into the reservoir. Corrosion and/or erosion of surface piping and equipment, as well as disposal well tubing, was also significant.

  15. Flow tests of the Gladys McCall well

    SciTech Connect (OSTI)

    Randolph, P.L.; Hayden, C.G.; Rogers, L.A. )

    1992-04-01

    This report pulls together the data from all of the geopressured-geothermal field research conducted at the Gladys McCall well. The well produced geopressured brine containing dissolved natural gas from the Lower Miocene sands at a depth of 15,150 to 16,650 feet. More than 25 million barrels of brine and 727 million standard cubic feet of natural gas were produced in a series of flow tests between December 1982 and October 1987 at various brine flow rates up to 28,000 barrels per day. Initial short-term flow tests for the Number 9 Sand found the permeability to be 67 to 85 md (millidarcies) for a brine volume of 85 to 170 million barrels. Initial short-term flow tests for the Number 8 Sand found a permeability of 113 to 132 md for a reservoir volume of 430 to 550 million barrels of brine. The long-term flow and buildup test of the Number 8 Sand found that the high-permeability reservoir connected to the wellbore (measured by the short-term flow test) was connected to a much larger, low-permeability reservoir. Numerical simulation of the flow and buildup tests required this large connected reservoir to have a volume of about 8 billion barrels (two cubic miles of reservoir rock) with effective permeabilities in the range of 0.2 to 20 md. Calcium carbonate scale formation in the well tubing and separator equipment was a problem. During the first 2 years of production, scale formation was prevented in the surface equipment by injection of an inhibitor upstream of the choke. Starting in 1985, scale formation in the production tubing was successfully prevented by injecting inhibitor pills'' directly into the reservoir. Corrosion and/or erosion of surface piping and equipment, as well as disposal well tubing, was also significant.

  16. Rock-brine chemical interactions. Final report

    SciTech Connect (OSTI)

    Not Available

    1982-02-01

    The results of experimental interaction of powdered volcanic rock with aqueous solutions are presented at temperatures from 200 to 400/sup 0/C, 500 to 1000 bars fluid pressure, with reaction durations of approximately 30 days under controlled laboratory conditions. The aim of this research is to develop data on the kinetics and equilibria of rock solution interactions that will provide insight into the complex geochemical processes attending geothermal reservoir development, stimulation, and reinjection. The research was done in the Stanford Hydrothermal Lab using gold cell equipment of the Dickson design. This equipment inverts the solution rock mixture several times a minute to ensure thorough mixing. Solution samples were periodically withdrawn without interruption of the experimental conditions. The data from these experiments suggests a path dependent series of reactions by which geothermal fluids might evolve from meteoric or magmatic sources.

  17. Development Operations Hypersaline Geothermal Brine Utilization...

    Open Energy Info (EERE)

    Abstract NA Authors Whitescarver and Olin D. Published U.S. Department of Energy, 1984 Report Number NA DOI Not Provided Check for DOI availability: http:crossref.org...

  18. Low-Temperature, Coproduced, and Geopressured Geothermal Technologies Strategic Action Plan, September 2010

    Office of Energy Efficiency and Renewable Energy (EERE)

    This action plan presents an agenda for GTO's Low-Temperature and Coproduced Resources Program to efficiently and effectively leverage its resources in support of the geothermal communitys goals and priorities.

  19. Systems for low frequency seismic and infrasound detection of geo-pressure transition zones

    DOE Patents [OSTI]

    Shook, G. Michael; LeRoy, Samuel D.; Benzing, William M.

    2007-10-16

    Methods for determining the existence and characteristics of a gradational pressurized zone within a subterranean formation are disclosed. One embodiment involves employing an attenuation relationship between a seismic response signal and increasing wavelet wavelength, which relationship may be used to detect a gradational pressurized zone and/or determine characteristics thereof. In another embodiment, a method for analyzing data contained within a response signal for signal characteristics that may change in relation to the distance between an input signal source and the gradational pressurized zone is disclosed. In a further embodiment, the relationship between response signal wavelet frequency and comparative amplitude may be used to estimate an optimal wavelet wavelength or range of wavelengths used for data processing or input signal selection. Systems for seismic exploration and data analysis for practicing the above-mentioned method embodiments are also disclosed.

  20. Methods and systems for low frequency seismic and infrasound detection of geo-pressure transition zones

    DOE Patents [OSTI]

    Shook, G. Michael; LeRoy, Samuel D.; Benzing, William M.

    2006-07-18

    Methods for determining the existence and characteristics of a gradational pressurized zone within a subterranean formation are disclosed. One embodiment involves employing an attenuation relationship between a seismic response signal and increasing wavelet wavelength, which relationship may be used to detect a gradational pressurized zone and/or determine characteristics thereof. In another embodiment, a method for analyzing data contained within a response signal for signal characteristics that may change in relation to the distance between an input signal source and the gradational pressurized zone is disclosed. In a further embodiment, the relationship between response signal wavelet frequency and comparative amplitude may be used to estimate an optimal wavelet wavelength or range of wavelengths used for data processing or input signal selection. Systems for seismic exploration and data analysis for practicing the above-mentioned method embodiments are also disclosed.

  1. Environmental assessment: geothermal energy geopressure subprogram. DOE Sweet Lake No. 1, Cameron Parish, Louisiana

    SciTech Connect (OSTI)

    Not Available

    1980-02-01

    The following are described: the proposed action; existing environment; probable impacts, direct and indirect; probable cumulative and long-term environmental impacts; accidents; coordination with federal, state, and local agencies; and alternatives. (MHR)

  2. Low-Temperature, Coproduced, and Geopressured Geothermal Technologies Strategic Action Plan, September 2010

    Broader source: Energy.gov (indexed) [DOE]

    of Energy The Geothermal Technology Program (GTP) low-temperature subprogram aims to provide the global geothermal community with the means to achieve development and widespread deployment of economically viable, innovative, and scalable technologies-including those involving coproducts-that will capture a significant portion of the low-temperature geothermal resource base over the next two decades. To that end, GTP held a Technology Roadmapping Workshop on July 13-14, 2010 in Golden,

  3. Geopressure industrial forums, newsletter and lease support. Final report, April 7, 1981-December 31, 1983

    SciTech Connect (OSTI)

    Knutson, C.F.

    1983-12-01

    In the course of this contract C. K. GeoEnergy: (1) planned, organized, conducted, and reported on six DOE/Industry Forum meetings where the progress of DOE's resource development program was outlined and discussed (these six forum meetings included three meetings of the Drilling and Testing Subgroup and three meetings of the Overview Group), (2) prepared and distributed 15 newsletters, and (3) prepared three reports for DOE lease support. This final report includes summaries of each of the forum meetings as well as the three lease support meetings and the newsletter program.

  4. Unconventional gas recovery: state of knowledge document

    SciTech Connect (OSTI)

    Geffen, C.A.

    1982-01-01

    This report is a synthesis of environmental data and information relevant to the four areas of unconventional gas recovery (UGR) resource recovery: methane from coal, tight western sands, Devonian shales and geopressurized aquifers. Where appropriate, it provides details of work reviewed; while in other cases, it refers the reader to relevant sources of information. This report consists of three main sections, 2, 3, and 4. Section 2 describes the energy resource base involved and characteristics of the technology and introduces the environmental concerns of implementing the technology. Section 3 reviews the concerns related to unconventional gas recovery systems which are of significance to the environment. The potential health and safety concerns of the recovery of natural gas from these resources are outlined in Section 4.

  5. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    properties of Gulf Coast sandstones and their implications for geopressured fluid production Morton R A Ewing T E Tyler N GEOTHERMAL ENERGY GEOPRESSURED SYSTEMS...

  6. Continuity and internal properties of Gulf Coast sandstones and...

    Office of Scientific and Technical Information (OSTI)

    properties of Gulf Coast sandstones and their implications for geopressured fluid production Morton, R.A.; Ewing, T.E.; Tyler, N. 15 GEOTHERMAL ENERGY; GEOPRESSURED...

  7. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and...

    Office of Scientific and Technical Information (OSTI)

    Peer-review under responsibility of the Organizing Committee of GHGT-12 doi: 10.1016j.egy... + ajkXjXj + ai>i,kXi2, where i 1,22 and jl,22 and k 1,37 The goodness-of-fit (R2) ...

  8. GEOTHERMAL ENERGY; 59 BASIC BIOLOGICAL SCIENCES; BRINES; DETOXIFICATIO...

    Office of Scientific and Technical Information (OSTI)

    PROCESSING; BACTERIA; BIOCHEMISTRY; BIOREACTORS; BIOTECHNOLOGY; GEOCHEMISTRY; GEOTHERMAL ENERGY; METALS; SLUDGES; TOXIC MATERIALS; CHEMISTRY; ELEMENTS; ENERGY; ENERGY SOURCES;...

  9. Volume and accessibility of entrained (solution) methane in deep geopressured reservoirs - tertiary formations of the Texas Gulf Coast. Final report

    SciTech Connect (OSTI)

    Gregory, A.R.; Dodge, M.M.; Posey, J.S.; Morton, R.A.

    1980-10-01

    The objective of this project was to appraise the total volume of in-place methane dissolved in formation waters of deep sandstone reservoirs of the onshore Texas Gulf Coast within the stratigraphic section extending from the base of significant hydrocarbon production (8000 ft)* to the deepest significant sandstone occurrence. The area of investigation is about 50,000 mi/sup 2/. Factors that determine the total methane resource are reservoir bulk volume, porosity, and methane solubility; the latter is controlled by the temperature, pressure, and salinity of formation waters. Regional assessment of the volume and the distribution of potential sandstone reservoirs was made from a data base of 880 electrical well logs, from which a grid of 24 dip cross sections and 4 strike cross sections was constructed. Solution methane content in each of nine formations or divisions of formations was determined for each subdivision. The distribution of solution methane in the Gulf Coast was described on the basis of five reservoir models. Each model was characterized by depositional environment, reservoir continuity, porosity, permeability, and methane solubility.

  10. Frio sandstone reservoirs in the deep subsurface along the Texas Gulf Coast: their potential for production of geopressured geothermal energy

    SciTech Connect (OSTI)

    Bebout, D.G.; Loucks, R.G.; Gregory, A.R.

    1983-01-01

    Detailed geological, geophysical, and engineering studies conducted on the Frio Formation have delineated a geothermal test well site in the Austin Bayou Prospect which extends over an area of 60 square miles. A total of 800 to 900 feet of sandstone will occur between the depths of 13,500 and 16,500 feet. At leat 30 percent of the sand will have core permeabilities of 20 to 60 millidarcys. Temperature at the top of the sandstone section will be 300/sup 0/F. Water, produced at a rate of 20,000 to 40,000 barrels per day, will probably have to be disposed of by injection into shallower sandstone reservoirs. More than 10 billion barrels of water are in place in these sandstone reservoirs of the Austin Bayou Prospect; there should be approximately 400 billion cubic feet of methane in solution in this water. Only 10 percent of the water and methane (1 billion barrels of water and 40 billion cubic feet of methane) will be produced without reinjection of the waste water into the producing formation. Reservoir simulation studies indicate that 90 percent of the methane can be produced with reinjection. 106 figures.

  11. Recovery Act: Demonstrating The Commercial Feasibility Of Geopressured-Geothermal Power Generation At Sweet Lake Field, Cameron Parish, Louisiana

    Office of Energy Efficiency and Renewable Energy (EERE)

    Project objective: Extensive conceptual and numerical modeling of the reservoir to quantify the reservoir characteristics; using a wealth of information from oil & gas wells in the area; including log; core; PVT and flow test data.

  12. Recoverable Resource Estimate of Identified Onshore Geopressured Geothermal Energy in Texas and Louisiana (Presentation), NREL (National Renewable Energy Laboratory)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Records Management Handbook Records Management Handbook These records pertain to the sales by agencies of real and personal property surplus to the needs of the Government. Records Management Handbook (628.31 KB) More Documents & Publications Records Management Handbook PROCEDURE FOR CONDUCTING A RECORDS INVENTORY Information and Records Management Transition Guidance

    Records Management Records Management 80 Seconds Around the LMBC In 2009, Legacy Management constructed a state-of-the-art

  13. Testing geopressured geothermal reservoirs in existing wells: Pauline Kraft Well No. 1, Nueces County, Texas. Final report

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    The Pauline Kraft Well No. 1 was originally drilled to a depth of 13,001 feet and abandoned as a dry hole. The well was re-entered in an effort to obtain a source of GEO/sup 2/ energy for a proposed gasohol manufacturing plant. The well was tested through a 5-inch by 2-3/8 inch annulus. The geological section tested was the Frio-Anderson sand of Mid-Oligocene age. The interval tested was from 12,750 to 12,860 feet. A saltwater disposal well was drilled on the site and completed in a Micocene sand section. The disposal interval was perforated from 4710 to 4770 feet and from 4500 to 4542 feet. The test well failed to produce water at substantial rates. Initial production was 34 BWPD. A large acid stimulation treatment increased productivity to 132 BWPD, which was still far from an acceptable rate. During the acid treatment, a failure of the 5-inch production casing occurred. The poor production rates are attributed to a reservoir with very low permeability and possible formation damage. The casing failure is related to increased tensile strain resulting from cooling of the casing by acid and from the high surface injection pressure. The location of the casing failure is now known at this time, but it is not at the surface. Failure as a result of a defect in a crossover joint at 723 feet is suspected.

  14. Geopressurized/geothermal project, Pleasant Bayou well no. 2, Brazoria County, Texas: Workover summary, February 15, 1986-April 3, 1986

    SciTech Connect (OSTI)

    Not Available

    1986-01-01

    A workover of the Pleasant Bayou well No. 2 to clear debris from the well and replace leaking 5.5'' production tubing is described. (ACR)

  15. Reservoir Characterization of Upper Devonian Gordon Sandstone, Jacksonburg, Stringtown Oil Field, Northwestern West Virginia

    SciTech Connect (OSTI)

    Ameri, S.; Aminian, K.; Avary, K.L.; Bilgesu, H.I.; Hohn, M.E.; McDowell, R.R.; Patchen, D.L.

    2002-05-21

    This report gives results of efforts to determine electrofacies from logs; measure permeability in outcrop to study very fine-scale trends; find the correlation between permeability measured by the minipermeameter and in core plugs, define porosity-permeability flow units; and run the BOAST III reservoir simulator using the flow units defined for the Gordon reservoir.

  16. Physical and chemical characterization of Devonian gas shale. Quarterly status report, January 1-March 31, 1980

    SciTech Connect (OSTI)

    Zielinski, R.E.; Nance, S.W.

    1980-01-01

    A change in the format of the Mound Facility EGSP reports begins with this issue. The geochemical characterization data is reported by well instead of by the type of analysis. For most well sections stratigraphic intervals are identified. The stratigraphic zones were picked from borehole logs. The logs and sample datums are discussed in the text. No concentrated effort was made to develop a rigid system of formation and member names. The well logs were generally tied to the nearest available USGS or state generated cross-sections, therefore, the interval names should only be used as a guide for determining stratigraphic position. The general location of wells and corresponding well data used by Mound Facility in its EGSP study is indicated in tables and figures.

  17. Geochemical and Strontium Isotope Characterization of Produced Waters from Marcellus Shale Natural Gas Extraction

    SciTech Connect (OSTI)

    Chapman, Elizabeth C; Capo, Rosemary C.; Stewart, Brian W.; Kirby, Carl S.; Hammack, Richard W.; Schroeder, Karl T.; Edenborn, Harry M.

    2012-03-20

    Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of 375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (ε{sub Sr}{sup SW} = +13.8 to +41.6, where ε{sub Sr}{sup SW} is the deviation of the {sup 87}Sr/{sup 86}Sr ratio from that of seawater in parts per 10{sup 4}); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters.

  18. Geochemical and Strontium Isotope Characterization of Produced Waters from Marcellus Shale Natural Gas Extraction

    SciTech Connect (OSTI)

    Elizabeth C. Chapman,† Rosemary C. Capo,† Brian W. Stewart,*,† Carl S. Kirby,‡ Richard W. Hammack,§ Karl T. Schroeder,§ and Harry M. Edenborn

    2012-02-24

    Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of ∼375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (εSr SW = +13.8 to +41.6, where εSr SW is the deviation of the 87Sr/86Sr ratio from that of seawater in parts per 104); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters.

  19. GEOTHERMAL A N D HEAVY-OIL RESOURCES I N TEXAS TOPICAL REPORT

    Office of Scientific and Technical Information (OSTI)

    ... test well and structure of T5 marker ...... 12 Location of geopressured-geothermal corridors and test wells ...

  20. Preparation of environmental analyses for synfuel and unconventional gas technologies

    SciTech Connect (OSTI)

    Reed, R.M.

    1982-09-01

    Government agencies that offer financial incentives to stimulate the commercialization of synfuel and unconventional gas technologies usually require an analysis of environmental impacts resulting from proposed projects. This report reviews potentially significant environmental issues associated with a selection of these technologies and presents guidance for developing information and preparing analyses to address these issues. The technologies considered are western oil shale, tar sand, coal liquefaction and gasification, peat, unconventional gas (western tight gas sands, eastern Devonian gas shales, methane from coal seams, and methane from geopressured aquifers), and fuel ethanol. Potentially significant issues are discussed under the general categories of land use, air quality, water use, water quality, biota, solid waste disposal, socioeconomics, and health and safety. The guidance provided in this report can be applied to preparation and/or review of proposals, environmental reports, environmental assessments, environmental impact statements, and other types of environmental analyses. The amount of detail required for any issue discussed must, by necessity, be determined on a case-by-case basis.

  1. Geopressured-geothermal drilling and testing plan: Magma Gulf/Technadril-Dept. of Energy MGT-DOE AMOCO Fee No. 1 well, Cameron Parish, Lousiana

    SciTech Connect (OSTI)

    Not Available

    1980-07-01

    The following topics are covered: generalized site activities, occupational health and safety, drilling operations, production testing, environmental assessment and monitoring plan, permits, program management, reporting, and schedule. (MHR)

  2. Sweet Lake geopressured-geothermal project, Magma Gulf-Technadril/DOE Amoco fee. Volume III. Final report. Annual report, February 1982-March 1985

    SciTech Connect (OSTI)

    Durham, C.O. Jr.; O'Brien, F.D.; Rodgers, R.W.

    1985-01-01

    This report presents the results of the testing of Sand 3 (15,245 to 15,280 feet in depth) which occurred from November 1983 to March 1984 and evaluates these new data in comparison to results from the testing of Sand 5 (15,385 to 15,415 feet in depth) which occurred from June 1981 to February 1982. It also describes the reworking of the production and salt water disposal wells preparatory to the Sand 3 testing as well as the plug and abandon procedures requested to terminate the project. The volume contains two parts: Part 1 includes the text and accompanying plates, figures and tables; Part 2 consists of the appendixes including auxiliary reports and tabulations.

  3. Sweet Lake Geopressured-geothermal Project, Magma Gulf-Technadril/DOE Amoco Fee. Volume II. Surface installations reservoir testing. Annual report, February 28, 1981-February 10, 1982

    SciTech Connect (OSTI)

    Hoffman, K.S.

    1984-01-01

    The Magma Gulf-Technadril/Department of Energy Amoco Fee No. 1 (production) and salt water disposal wells were drilled in the period from August, 1980 to February 1981. Surface facilities were designed and constructed during March-June 1981. Flow testing began in June 1981 and continued until February, 1982. The Miogypsinoides interval contains seven discrete sands in the test well. These sands have been numbered 1 to 7, beginning at the top of the sequence. Data from wireline logs and core samples suggested that the first zone to be perforated should be Sand 5. Because of its high porosity and permeability, Sand 5 was thought to contain almost 50% of the total hydraulic capacity of the well. Flow testing of Sand 5 was performed in three stages, each of which is fully described in this report. Phase I was designed as an initial clean-up flow and a reservoir confirmation test. Phase II consisted of the reservoir limit determination test and lasted 17 days. Boundaries were confirmed which suggest that the Sweet Lake reservoir is fairly narrow, with boundaries on three sides, but is open in one direction with no closure for at least 4-1/4 miles. These boundaries approximate the shape of the graben in which the test well was drilled, but may or may not be directly related to the major faults forming the graben. Phase III testing was planned to be a long-term test at commercial design rates. Although Sand 5 alone would not support such rates, long-term production was demonstrated. Additional research not supported by DOE funding was also performed during the period covered by this report. This research, consisting of mud logging, micropaleontology, organic geochemistry, core analysis, and rock mechanics, is summarized in this report.

  4. GTP energy production from low-temperature resources, coproduced fluids,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and geopressured resources. | Department of Energy GTP energy production from low-temperature resources, coproduced fluids, and geopressured resources. GTP energy production from low-temperature resources, coproduced fluids, and geopressured resources. This document provides and overview of how to respond to a funding opportunity announcement. go_foa_overview.pdf (94.71 KB) More Documents & Publications Microsoft Word - fDE-FOA-0000109.rtf Microsoft Word - FOA cover sheet.doc DISCLAIMER:

  5. EERE Success Story—Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential

    Broader source: Energy.gov [DOE]

    Utilizing EERE funds, ElectraTherm developed a geothermal technology that will generate electricity for less than $0.06 per kilowatt hour.

  6. ASSESSMENT OF TECHNETIUM LEACHABILITY IN CEMENT-STABILIZED BASIN 43 GROUNDWATER BRINE

    SciTech Connect (OSTI)

    DUNCAN JB; COOKE GA; LOCKREM LL

    2009-07-20

    This report documents the effort to sequester technetium by the use of getters, reductants (tin(II) apatite and ferrous sulfate), sorbents (A530E and A532E ion exchange resins), and cementitious waste form. The pertechnetate form of technetium is highly soluble and mobile in aerobic (oxidizing) environments.

  7. The role of wellbore remediation on the evolution of groundwater quality from CO₂ and brine leakage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mansoor, Kayyum; Carroll, Susan A.; Sun, Yunwei

    2014-12-31

    Long-term storage of CO₂ in underground reservoirs requires a careful assessment to evaluate risk to groundwater sources. The focus of this study is to assess time-frames required to restore water quality to pre-injection levels based on output from complex reactive transport simulations that exhibit plume retraction within a 200-year simulation period. We examined the relationship between plume volume, cumulative injected CO₂ mass, and permeability. The role of mitigation was assessed by projecting falloffs in plume volumes from their maximum peak levels with a Gaussian function to estimate plume recovery times to reach post-injection groundwater compositions. The results show a strongmore » correlation between cumulative injected CO₂ mass and maximum plume pH volumes and a positive correlation between CO₂ flux, cumulative injected CO₂, and plume recovery times, with secondary dependence on permeability.« less

  8. Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential

    Broader source: Energy.gov [DOE]

    Utilizing EERE funds, ElectraTherm developed a geothermal technology that will generate electricity for less than $0.06 per kilowatt hour.

  9. APPLIED PHYTO-REMEDIATION TECHNIQUES USING HALOPHYTES FOR OIL AND BRINE SPILL SCARS

    SciTech Connect (OSTI)

    M.L. Korphage; Bruce G. Langhus; Scott Campbell

    2003-03-01

    Produced salt water from historical oil and gas production was often managed with inadequate care and unfortunate consequences. In Kansas, the production practices in the 1930's and 1940's--before statewide anti-pollution laws--were such that fluids were often produced to surface impoundments where the oil would segregate from the salt water. The oil was pumped off the pits and the salt water was able to infiltrate into the subsurface soil zones and underlying bedrock. Over the years, oil producing practices were changed so that segregation of fluids was accomplished in steel tanks and salt water was isolated from the natural environment. But before that could happen, significant areas of the state were scarred by salt water. These areas are now in need of economical remediation. Remediation of salt scarred land can be facilitated with soil amendments, land management, and selection of appropriate salt tolerant plants. Current research on the salt scars around the old Leon Waterflood, in Butler County, Kansas show the relative efficiency of remediation options. Based upon these research findings, it is possible to recommend cost efficient remediation techniques for slight, medium, and heavy salt water damaged soil. Slight salt damage includes soils with Electrical Conductivity (EC) values of 4.0 mS/cm or less. Operators can treat these soils with sufficient amounts of gypsum, install irrigation systems, and till the soil. Appropriate plants can be introduced via transplants or seeded. Medium salt damage includes soils with EC values between 4.0 and 16 mS/cm. Operators will add amendments of gypsum, till the soil, and arrange for irrigation. Some particularly salt tolerant plants can be added but most planting ought to be reserved until the second season of remediation. Severe salt damage includes soil with EC values in excess of 16 mS/cm. Operators will add at least part of the gypsum required, till the soil, and arrange for irrigation. The following seasons more gypsum will be added and as the soil EC is reduced, plants can be introduced. If rapid remediation is required, a sufficient volume of topsoil, or sand, or manure can be added to dilute the local salinity, the bulk amendments tilled into the surface with added gypsum, and appropriate plants added. In this case, irrigation will be particularly important. The expense of the more rapid remediation will be much higher.

  10. Molecular dynamics study of interfacial confinement effects of aqueous NaCl brines in nanoporous carbon

    SciTech Connect (OSTI)

    Wander, M. C. F.; Shuford, K. L.

    2010-12-09

    In this paper, studies of aqueous electrolyte solutions in contact with a family of porous carbon geometries using classical molecular dynamics simulations are presented. These simulations provide an atomic scale depiction of ion transport dynamics in different environments to elucidate power of aqueous electrolyte supercapacitors. The electrolyte contains alkali metal and halide ions, which allow for the examination of size trends within specific geometries as well as trends in concentration. The electrode pores are modeled as planar graphite sheets and carbon nanotubes with interstices ranging from one to four nanometers. Ordered layers form parallel to the carbon surface, which facilitates focused ion motion under slightly confining conditions. As a result, the ions diffusivities are enhanced in the direction of the slit or pore. Further confining the system leads to decreased ion diffusivities. The ions are fully hydrated in all but the smallest slits and pores with those sizes showing increased ion pairing. There is strong evidence of charge separation perpendicular to the surface at all size scales, concentrations, and ion types, providing a useful baseline for examining differential capacitance behavior and future studies on energy storage. These systems show promise as high-power electrical energy storage devices.

  11. EERE Success Story-Nevada: Geothermal Brine Brings Low-Cost Power...

    Broader source: Energy.gov (indexed) [DOE]

    Utilizing a 1 million EERE investment, heat from geothermal fluids-a byproduct of gold mining-will be generating electricity this year for less than 0.06 per kilowatt hour with ...

  12. Geothermal Brine Brings Low-Cost Power with Big Potential | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thanks to a 1 million Geothermal Technologies Office investment, heat from geothermal fluids--a byproduct of gold mining--is generating electricity this year for less than 6 a ...

  13. Repetitive Regeneration of Media #1 after REE Sorption from Brine #1 at 70C

    SciTech Connect (OSTI)

    Gary Garland

    2015-07-23

    This dataset shows the ability of media #1 to be loaded with REE's, stripped of the REE's sequestered, regenerated, and reused over many cycles.

  14. Galvanic corrosion of a copper alloy in lithium bromide heavy brine environments

    SciTech Connect (OSTI)

    Itzhak, D.; Greenberg, T.

    1999-08-01

    Galvanic corrosion of the copper alloy 84% Cu-15% Zn-1% Ni was studied in 55 wt% lithium bromide (LiBr) environments. The galvanic couples studied were: 84% Cu-15% Zn-1% Ni-Ti2, 84% Cu-15% Zn-1% Ni-Ti7, 84% Cu-15% Zn-1% Ni-30% Cu-70% Ni, 84% Cu-15% Zn-1% Ni-Pb, 84% Cu-15% Zn-1% Ni-Ag, and 84% Cu-15% Zn-1% Ni-Sn. Potentiodynamic polarization measurements, open-circuit potential (OCP), and weight change measurements were carried out to evaluate the galvanic effect. Results indicated that Ti alloys and 30% Cu-70% Ni were the most passive alloys tested, and they behaved as cathodes. Although galvanic corrosion was expected, a negligible effect was measured because of an effective passivation layer on the surface of Ti alloys and 30% Cu-70% Ni. Pb, Ag, and Sn showed anodic behavior as compared to 84% Cu-15% Zn-1% Ni. As a result of the galvanic coupling, significant weight loss of these metals was measured. Sn was the most effective anode as compared to the other tested alloys; it acted as a sacrificial anode. Sn provided effective cathodic protection to 84% Cu-15% Zn-1% Ni in 55 wt% LiBr environments at 140 C.

  15. Draft Test Plan for Brine Migration Experimental Studies in Run-of-Mine Salt Backfill

    SciTech Connect (OSTI)

    Jordan, Amy B.; Stauffer, Philip H.; Reed, Donald T.; Boukhalfa, Hakim; Caporuscio, Florie Andre; Robinson, Bruce Alan

    2015-02-02

    The primary objective of the experimental effort described here is to aid in understanding the complex nature of liquid, vapor, and solid transport occurring around heated nuclear waste in bedded salt. In order to gain confidence in the predictive capability of numerical models, experimental validation must be performed to ensure that (a) hydrological and physiochemical parameters and (b) processes are correctly simulated. The experiments proposed here are designed to study aspects of the system that have not been satisfactorily quantified in prior work. In addition to exploring the complex coupled physical processes in support of numerical model validation, lessons learned from these experiments will facilitate preparations for larger-scale experiments that may utilize similar instrumentation techniques.

  16. Gas content of Gladys McCall reservoir brine (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    ... However, observed small transients in EthaneMethane and PropaneMethane ratios indicate that some free gas was produced from the near wellbore region. These results suggest that ...

  17. Geochemistry of Bolivian salars, Lipez, southern Altiplano: Origin of solutes and brine evolution

    SciTech Connect (OSTI)

    Risacher, F. ); Fritz, B. )

    1991-03-01

    This paper focuses on poorly understood processes related to saline lakes, or salars, of the southern Bolivian Altiplano. A morphologic classification system is described, and the origin of solutes in the inflow waters is discussed. Next, the actual chemical evolution of these inflow waters is compared with their theoretical evolution based on thermodynamic equilibria. The water chemistry of a specific sequence of evaporating waters is then scrutinized to determine which processes are responsible for a significant discrepancy which is apparent between the measured and the calculated evolution.

  18. Gas Content of Gladys McCall Reservoir Brine A Topical Report

    Office of Scientific and Technical Information (OSTI)

    Produced Gas Composition 2.4 The IGT Bubble Test 2.4.1 Physical Phenomena That Cause the Bubble 2.4.2 The Febuary 1 I , 1986 Bubble Test 2.4.3 The April 14, 1987 Bubble Test 2.4.4 ...

  19. Experimental investigation of brine-CO2 flow through a natural...

    Office of Scientific and Technical Information (OSTI)

    ... A paper copy of this document is also available for sale to the public from the National Technical Information Service, Springfield, VA at www.ntis.gov. Authors: Smith, M M ; ...

  20. The role of wellbore remediation on the evolution of groundwater quality from CO? and brine leakage

    SciTech Connect (OSTI)

    Mansoor, Kayyum; Carroll, Susan A.; Sun, Yunwei

    2014-12-31

    Long-term storage of CO? in underground reservoirs requires a careful assessment to evaluate risk to groundwater sources. The focus of this study is to assess time-frames required to restore water quality to pre-injection levels based on output from complex reactive transport simulations that exhibit plume retraction within a 200-year simulation period. We examined the relationship between plume volume, cumulative injected CO? mass, and permeability. The role of mitigation was assessed by projecting falloffs in plume volumes from their maximum peak levels with a Gaussian function to estimate plume recovery times to reach post-injection groundwater compositions. The results show a strong correlation between cumulative injected CO? mass and maximum plume pH volumes and a positive correlation between CO? flux, cumulative injected CO?, and plume recovery times, with secondary dependence on permeability.

  1. Hydrogen chloride in superheated steam and chloride in deep brine at The Geysers geothermal field, California

    SciTech Connect (OSTI)

    Haizlip, J.R.; Truesdell, A.H.

    1988-01-01

    Chloride (Cl) concentrations of 10-120 ppm{sub w} have been measured in superheated steam produced by wells at The Geysers, a vapor-dominated geothermal field in northern California. Corrosion of the well casing and steam-gathering system has been recognized in some parts of The Geysers, and is apparently related to the presence of Cl. Cl in the steam is in a volatile form, generated with the steam at reservoir temperatures, and probably travels to the wellhead as HCl gas. Published experimental data for partial pressures of HCl in steam over aqueous HCl solutions and for dissociation constants of HCl were used to calculate distribution coefficients for HCl. Reservoir liquid Cl concentrations capable of generating steam with the observed Cl concentrations were then calculated as a function of pH and temperatures from 250 to 350 C. Equilibrium mineral/liquid reactions with the K-mica and K-feldspar assemblage found in the wells limit the reservoir liquid pH values at various Cl concentrations to about 5 to 6 (near neutral at 250 to 350 C). Within this pH range, liquid at 250 C could not produce steam containing the high Cl concentrations observed. However, liquid at higher temperatures (300 to 350 C) with chloride concentrations greater than 10,000 ppm{sub w} could generate steam with 10 to over 200 ppm{sub w} Cl. There is a positive correlation between pH and the chloride concentrations required to generate a given Cl concentration in steam. The concentration of Cl in superheated steam constrains not only the reservoir liquid composition, but the temperature at which the steam last equilibrated with liquid.

  2. Repetitive Regeneration of Media #1 in a Dynamic Column Extraction using Brine #1

    SciTech Connect (OSTI)

    Gary Garland

    2015-10-14

    This data is from a regeneration study from a dynamic column extraction experiment where we ran a solution of REE's through a column of media #1 then stripped the REE's off the media using 2M HNO3 solution. We then re-equilibrated the media and repeated the process of running a REE solution through the column and stripping the REE's off the media and comparing the two runs.

  3. Semi-annual report for the unconventional gas recovery program, period ending March 31, 1980

    SciTech Connect (OSTI)

    Manilla, R.D.

    1980-06-01

    Four subprograms are reported on: methane recovery from coalbeds, Eastern gas shales, Western gas sands, and methane from geopressured aquifers. (DLC)

  4. AAPG Low-Temperature Webinar: Transcript | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    ... demonstration and R&D sections to help capture some of this vast potentialenergy source. ... Geopressured systems are economic sources of geothermal power plus gas, if ...

  5. NREL's New Directions in Geothermal R&D

    Broader source: Energy.gov [DOE]

    Presented at the Technology Planning Workshop for Low-Temperature, Coproduced, and Geopressured Geothermal Energy, July 13-14, 2010, Golden, Colorado

  6. GTP energy production from low-temperature resources, coproduced...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GTP energy production from low-temperature resources, coproduced fluids, and geopressured resources. GTP energy production from low-temperature resources, coproduced fluids, and ...

  7. Regulatory Impacts to Geothermal Development

    Broader source: Energy.gov [DOE]

    Presented at the Technology Planning Workshop for Low-Temperature, Coproduced, and Geopressured Geothermal Energy, July 13-14, 2010, Golden, Colorado

  8. AAPG Low-Temperature Webinar

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Demonstrating the Commercial Feasibility of Geopressured - Geothermal Power Development at Sweet Lake Field Cameron Parish, Louisiana Louisiana Tank, Inc. will demonstrate the ...

  9. Geothermal Energy Production from Low Temperature Resources,...

    Open Energy Info (EERE)

    Geothermal Energy Production from Low Temperature Resources, Coproduced Fluids from Oil and Gas Wells, and Geopressured Resources Jump to: navigation, search Geothermal ARRA Funded...

  10. Innovative Exploration Technologies Subprogram Overview | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Innovative Exploration Technologies Subprogram Overview Geothermal Technologies Program Peer Review Program June 6 - 10, 2011 Low TemperatureCoproducedGeopressured Subprogram...

  11. A Geothermal District-Heating System and Alternative Energy Research...

    Open Energy Info (EERE)

    2 Geothermal Energy Production from Low Temperature Resources, Coproduced Fluids from Oil and Gas Wells, and Geopressured Resources Project Type Topic 3 Low Temperature...

  12. T-F and S/DOE Gladys McCall No. 1 well, Cameron Parish, Louisiana. Geopressured-geothermal well report, Volume II. Well workover and production testing, February 1982-October 1985. Final report. Appendices 1-7

    SciTech Connect (OSTI)

    Not Available

    1985-01-01

    These appendices contain the following reports: (1) investigation of coupling failure from the Gladys McCall No. 1 well; (2) failure analysis - oil well casing coupling; (3) technical remedial requirements for 5-inch production tubing string; (4) reservoir limit test data for sand zone No. 9; (5) reservoir fluid study - sand zone No. 9; (6) engineering interpretation of exploration drawdown tests; and (7) reservoir analysis. (ACR)

  13. Sweet lake geopressured-geothermal project, Magma Gulf-Technadril/DOE Amoco Fee. Annual report, December 1, 1979-February 27, 1981. Volume I. Drilling and completion test well and disposal well

    SciTech Connect (OSTI)

    Rodgers, R.W.

    1982-06-01

    The Sweet lake site is located approximately 15 miles southeast of Lake Charles in Cameron Parish, Louisiana. A geological study showed that the major structure in this area is a graben. The dip of the beds is northwesterly into the basin. A well drilled into the deep basin would find the target sand below 18,000', at high pressures and temperatures. However, since there is no well control in the basin, the specific site was chosen on the 15,000' contour of the target sand in the eastern, more narrow part of the garben. Those key control wells are present within one mile of the test well. The information acquired by drilling the test well confirmed the earlier geologic study. The target sand was reached at 15,065', had a porosity of over 20% and a permeability to water of 300 md. The original reservoir pressure was 12,060 psi and the bottom hole temperature 299{sup 0}F. There are approximately 250 net feet of sand available for the perforation. The disposal well was drilled to a total depth of 7440'.

  14. Alteration Behavior of High Burnup Spent Fuel in Salt Brine Under Hydrogen Overpressure and in Presence of Bromide

    SciTech Connect (OSTI)

    Loida, Andreas; Metz, Volker; Kienzler, Bernhard

    2007-07-01

    Recent studies have shown that in the presence of H2 overpressure, which forms due to the corrosion of the Fe based container, the dissolution rate of the spent fuel matrix is slowed down by a factor of about 10, associated with a distinct decrease of concentrations of important radionuclides. However, in a natural salt environment as well as in geological formations with chloride rich groundwater the presence of radiation chemically active impurities such as bromide must be taken in consideration. Bromide is known to react with {beta}/{gamma} radiolysis products, thus counteracting the protective H{sub 2} effect. In the present experiments using high burnup spent fuel, it is observed that during 212 days the matrix dissolution rate was enhanced by a factor of about 10 in the presence of up to 10{sup -3} M bromide and 3.2 bar H{sub 2} overpressure. However, concentrations of matrix bound actinides were found at the same level or below as found under identical conditions, but in the absence of bromide. In the long-term it is expected that the effect of bromide becomes less important, because the decrease of {beta}/{gamma}-activity results in a decrease of oxidative radicals, which react with bromide, while a-activity will dominate the radiation field. (authors)

  15. RealGasBrine v1.0 option of TOUGH+ v1.5 () | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Guide; Sample Problem Input Data; 1 CD-ROM Software CPU: MLTPL Open Source: No Source Code Available: Yes Research Org: Lawrence Berkeley National Laboratory Sponsoring Org: ...

  16. Reservoir performance in viscoelastic porous media

    SciTech Connect (OSTI)

    Rago, F.M.; Ohkuma, H.; Sepehrnoori, K.; Thompson, T.W.

    1982-01-01

    The mass balance equations for a two-phase two-component fluid system are written for viscoelastic porous media. The resulting equations are approximated by finite differences and the resulting numerical simulator is used to conduct a sensitivity study on the effects of uniaxial viscoelastic deformation in geopressured aquifers. Results of this study indicate that viscoelastic deformation may have considerable influence on the pressure maintenance of these aquifers. A numerical model of the geopressured aquifer in Brazoria County, Texas, is constructed and the numerical simulator is used to predict the ultimate recovery of solution gas from this viscoelastic geopressured aquifer.

  17. 2OC | Open Energy Information

    Open Energy Info (EERE)

    OC Jump to: navigation, search Name: 2OC Place: Bath, England, United Kingdom Zip: BA1 7AB Product: Bath-based, geo-pressure energy company. 2OC helps organisations in the UK and...

  18. Low Temperature Geothermal Energy | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Geothermal Energy Low Temperature Geothermal Energy Presented at the Technology Planning Workshop for Low-Temperature, Coproduced, and Geopressured Geothermal Energy, July 13-14, 2010, Golden, Colorado 20100713_lowtemp_blackwell.pdf (4.32 MB) More Documents & Publications Geothermal Energy Production with Co-produced and Geopressured Resources (Fact Sheet), Geothermal Technologies Program (GTP) AAPG Low-Temperature Webinar Power Plays: Geothermal Energy In Oil and Gas Field

  19. Puna Geothermal Venture 8MW Expantion | Open Energy Information

    Open Energy Info (EERE)

    potential brine in a state-of-the-art binary plant, development of highly reliable brine pH monitoring and control system, and brine injection management in a high energy resource....

  20. EFFECT OF QUARTZ/MULLITE BLEND CERAMIC ADDITIVE ON IMPROVING RESISTANCE TO ACID OF SODIUM SILICATE-ACTIVATED SLAG CEMENT. CELCIUS BRINE.

    SciTech Connect (OSTI)

    SUGAMA, T.; BROTHERS, L.E.; VAN DE PUTTE, T.R.

    2006-06-01

    We evaluated the usefulness of manufactured quartz/mullite blend (MQMB) ceramic powder in increasing the resistance to acid of sodium silicate-activated slag (SSAS) cementitious material for geothermal wells. A 15-day exposure to 90{sup o} CO{sub 2}-laden H{sub 2}SO{sub 4} revealed that the MQMB had high potential as an acid-resistant additive for SSAS cement. Two factors, the appropriate ratio of slag/MQMB and the autoclave temperature, contributed to better performance of MQMB-modified SSAS cement in abating its acid erosion. The most effective slag/MQMB ratio in minimizing the loss in weight by acid erosion was 70/30 by weight. For autoclave temperature, the loss in weight of 100 C autoclaved cement was a less than 2%, but at 300 C it was even lower. Before exposure to acid, the cement autoclaved at 100 C was essentially amorphous; increasing the temperature to 200 C led to the formation of crystalline analcime in the zeolitic mineral family during reactions between the mullite in MQMB and the Na from sodium silicate. In addition, at 300 C, crystal of calcium silicate hydrate (1) (CSH) was generated in reactions between the quartz in MQMB and the activated slag. These two crystalline phases (CSH and analcime) were responsible for densifying the autoclaved cement, conveying improved compressive strength and minimizing water permeability. The CSH was susceptible to reactions with H{sub 2}SO{sub 4}, forming two corrosion products, bassanite and ionized monosilicic acid. However, the uptake of ionized monosilicic acid by Mg dissociated from the activated slag resulted in the formation of lizardite as magnesium silicate hydrate. On the other hand, the analcime was barely susceptible to acid if at all. Thus, the excellent acid resistance of MQMB-modified SSAS cement was due to the combined phases of lizardite and analcime.

  1. Modeling CO{sub 2}-Brine-Rock Interaction Including Mercury and H{sub 2}S Impurities in the Context of CO{sub 2} Geologic Storage

    SciTech Connect (OSTI)

    Spycher, N.; Oldenburg, C.M.

    2014-01-01

    This study uses modeling and simulation approaches to investigate the impacts on injectivity of trace amounts of mercury (Hg) in a carbon dioxide (CO{sub 2}) stream injected for geologic carbon sequestration in a sandstone reservoir at ~2.5 km depth. At the range of Hg concentrations expected (7-190 ppbV, or ~ 0.06-1.6 mg/std.m{sup 3}CO{sub 2}), the total volumetric plugging that could occur due to complete condensation of Hg, or due to complete precipitation of Hg as cinnabar, results in a very small porosity change. In addition, Hg concentration much higher than the concentrations considered here would be required for Hg condensation to even occur. Concentration of aqueous Hg by water evaporation into CO{sub 2} is also unlikely because the higher volatility of Hg relative to H{sub 2}O at reservoir conditions prevents the Hg concentration from increasing in groundwater as dry CO{sub 2} sweeps through, volatilizing both H{sub 2}O and Hg. Using a model-derived aqueous solution to represent the formation water, batch reactive geochemical modeling show that the reaction of the formation water with the CO{sub 2}-Hg mixture causes the pH to drop to about 4.7 and then become buffered near 5.2 upon reaction with the sediments, with a negligible net volume change from mineral dissolution and precipitation. Cinnabar (HgS(s)) is found to be thermodynamically stable as soon as the Hg-bearing CO{sub 2} reacts with the formation water which contains small amounts of dissolved sulfide. Liquid mercury (Hg(l)) is not found to be thermodynamically stable at any point during the simulation. Two-dimensional radial reactive transport simulations of CO{sub 2} injection at a rate of 14.8 kg/s into a 400 m-thick formation at isothermal conditions of 106°C and average pressure near 215 bar, with varying amounts of Hg and H{sub 2}S trace gases, show generally that porosity changes only by about ±0.05% (absolute, i.e., new porosity = initial porosity ±0.0005) with Hg predicted to readily precipitate from the CO{sub 2} as cinnabar in a zone mostly matching the single-phase CO{sub 2} plume. The precipitation of minerals other than cinnabar, however, dominates the evolution of porosity. Main reactions include the replacement of primarily Fe-chlorite by siderite, of calcite by dolomite, and of K-feldspar by muscovite. Chalcedony is also predicted to precipitate from the dissolution of feldspars and quartz. Although the range of predicted porosity change is quite small, the amount of dissolution and precipitation predicted for these individual minerals is not negligible. These reactive transport simulations assume that Hg gas behaves ideally. To examine effects of non-ideality on these simulations, approximate calculations of the fugacity coefficient of Hg in CO{sub 2} were made. Results suggest that Hg condensation could be significantly overestimated when assuming ideal gas behavior, making our simulation results conservative with respect to impacts on injectivity. The effect of pressure on Henry’s constant for Hg is estimated to yield Hg solubilities about 10% lower than when this effect is not considered, a change that is considered too small to affect the conclusions of this report. Although all results in this study are based on relatively mature data and modeling approaches, in the absence of experimental data and more detailed site-specific information, it is not possible to fully validate the results and conclusions.

  2. EERE Success Story-California: Geothermal Plant to Help Meet...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Geothermal Plant to Help Meet High Lithium Demand EERE Success Story-California: ... Here, lithium is extracted from geothermal brines in California. Batteries from Brine ...

  3. Passive injection: A strategy for mitigating reservoir pressurization...

    Office of Scientific and Technical Information (OSTI)

    induced seismicity and brine migration in geologic CO2 storage Citation Details ... induced seismicity and brine migration in geologic CO2 storage Authors: ...

  4. Coupled Model for Heat and Water Transport in a High Level Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and dissolutionprecipitation of the salt in the brine inclusion are simulated; effects of initial inclusion size and temperature gradient on the brine behavior are investigated. ...

  5. [Dynamic enhanced recovery technologies]. Quarterly technical report, August 1992--October 1993

    SciTech Connect (OSTI)

    Anderson, R.N.

    1993-10-15

    This paper has presented the investigation of the mechanism of geopressure occurrence, the transition of elastic properties from the hydrostatic pressured formation to the geopressured formation, and finally, a novel seismic amplitude analysis technique to map the top-of-geopresure surface. The successful application of our new technique to the Pleistocene, offshore Louisiana, Gulf of Mexico has again demonstrated that seismic attributes analyses are of importantance in the hydrocarbon exploration. There are three parts in this paper corresponding to the above discussed topics: Part I discusses mechanisms of geopressuring, and the effects of changing porosity, pressure, and fluid saturation on the elastic properties; Part II investigates the controlling factors in the geopressure transition zone, their seismic responses, and theoretical derivations of our new prediction method; and Part III demonstrates the application of the proposed method to the Pleistocene, Offshore Louisiana, Gulf of Mexico, the prediction discrpepancy between the seismic predicted top-of-geopressure and that dericed from 145 well logs, and finally, the importance of this hydrodynamic surface.

  6. Ordovician carbonate formation waters in the Illinois Basin: Chemical and isotopic evolution beneath a regional aquitard

    SciTech Connect (OSTI)

    Stueber, A.M. ); Walter, L.M. . Dept. of Geological Sciences)

    1992-01-01

    Formation waters from carbonate reservoirs in the upper Ordovician Galena Group of the Illinois Basin have been analyzed geochemically to study origin of salinity, chemical and isotopic evolution, and relation to paleohydrologic flow systems. These carbonate reservoirs underlie the Maquoketa Shale Group of Cincinnatian age, which forms a regional aquitard. Cl-Br relations and Na/Br-Cl/Br systematics indicate that initial brine salinity resulted from subaerial evaporation of seawater to a point not significantly beyond halite saturation. Subsequent dilution in the subsurface by meteoric waters is supported by delta D-delta O-18 covariance. Systematic relations between Sr-87/Sr-86 and 1/Sr suggest two distinct mixing events: introduction of a Sr-87 enriched fluid from a siliciclastic source, and a later event which only affected reservoir waters from the western shelf of the basin. The second mixing event is supported by covariance between Sr-87/Sr-86 and concentrations of cations and anions; covariance between Sr and O-D isotopes suggests that the event is related to meteoric water influx. Systematic geochemical relations in ordovician Galena Group formation waters have been preserved by the overlying Maquoketa shale aquitard. Comparison with results from previous studies indicates that waters from Silurian-Devonian carbonate strata evolved in a manner similar to yet distinct from that of the Ordovician carbonate waters, whereas waters from Mississippian-Pennsylvanian strata that overlie the New Albany Shale Group regional aquitard are marked by fundamentally different Cl-Br-Na and Sr isotope systematics. Evolution of these geochemical formation-water regimes apparently has been influenced significantly by paleohydrologic flow systems.

  7. Geothermal energy technology: issues, R and D needs, and cooperative arrangements

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    In 1986, the National Research Council, through its Energy Engineering Board, formed the Committee on Geothermal Energy Technology. The committee's study addressed major issues in geothermal energy technology, made recommendations for research and development, and considered cooperative arrangements among government, industry, and universities to facilitate RandD under current severe budget constraints. The report addresses four types of geothermal energy: hydrothermal, geopressured, hot dry rock, and magma systems. Hydrothermal systems are the only type that are now economically competitive commercially. Further technology development by the Department of Energy could make the uneconomical hydrothermal resources commercially attractive to the industry. The economics are more uncertain for the longer-term technologies for extracting energy from geopressured, hot dry rock, and magma systems. For some sites, the cost of energy derived from geopressured and hot dry rock systems is projected within a commercially competitive range. The use of magma energy is too far in the future to make reasonable economic calculations.

  8. Zero Discharge Water Management for Horizontal Shale Gas Well...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (fracking), coupled with horizontal drilling, has facilitated exploitation of huge natural gas (gas) reserves in the Devonian-age Marcellus Shale Formation (Marcellus) of...

  9. Semi-annual report for the unconventional gas recovery program, period ending September 30, 1980

    SciTech Connect (OSTI)

    Manilla, R.D.

    1980-11-01

    Progress is reported in research on methane recovery from coalbeds, eastern gas shales, western gas sands, and geopressured aquifers. In the methane from coalbeds project, data on information evaluation and management, resource and site assessment and characterization, model development, instrumentation, basic research, and production technology development are reported. In the methane from eastern gas shales project, data on resource characterization and inventory, extraction technology, and technology testing and verification are presented. In the western gas sands project, data on resource assessments, field tests and demonstrations and project management are reported. In the methane from geopressured aquifers project, data on resource assessment, supporting research, field tests and demonstrations, and technology transfer are reported.

  10. Analysis of preliminary testing of Willis Hulin Well No. 1 (Draft)

    SciTech Connect (OSTI)

    Riney, T.D.

    1991-09-01

    The U.S. Department of Energy (DOE) has both drilled and tested four deep research wells in the Texas-Louisiana Gulf Coast region as part of its program to define the magnitude and recoverability of the geopressured-geothermal energy resource. DOE also took over nine wells from industry (before being abandoned) and tested them for short periods to determine fluid properties. The Willis Hulin Well No. 1, located about 7.5 miles south of the town of Erath, Louisiana, is the first well taken over from industry for possible long-term testing. This well penetrates the deepest known Gulf Coast geopressured-geothermal reservoir.

  11. Geothermal Energy Program Summary Document, FY 1982

    SciTech Connect (OSTI)

    1981-01-01

    Geothermal energy is derived from the internal heat of the earth. Much of it is recoverable with current or near current technology. Geothermal energy can be used for electric power production, residential and commercial space heating and cooling, industrial process heat, and agricultural applications. Three principal types of geothermal resources are exploitable through the year 2000. In order of technology readiness, these resources are: hydrothermal; geopressured (including dissolved natural gas); and hot dry rock. In hydrothermal systems, natural water circulation moves heat from deep internal sources toward the earth's surface. Geothermal fluids (water and steam) tapped by drilling can be used to generate electricity or provide direct heat. Geopressured resources, located primarily in sedimentary basins along the Gulf Coast of Texas and of Louisiana, consist of water and dissolved methane at high pressure and at moderately high temperature. In addition to recoverable methane, geopressured resources provide thermal energy and mechanical energy derived from high fluid pressures, although methane offers the greatest immediate value. Commercial development of geopressured energy may begin in the mid-1980s. Economic feasibility depends on the amount of methane that a given well can produce, a highly uncertain factor at present.

  12. Office of Renewable Energy Technology Geothermal and Hydropower Technologies Division, FY 1983 Annual Operating Plan

    SciTech Connect (OSTI)

    1983-01-01

    There are between 700 and 3400 guads of recoverable geothermal energy in the US. Hydrothermal, geopressure and hot dry rock are the three principal types of geothermal resources (in order of technological readiness) which can supply large amounts of energy for electric power production and direct heat applications. Hydrothermal resources include water and steam trapped in fractured or porous rocks. A hydrothermal system is classified as either hot-water or vapor-dominated (steam), according to the principal physical state of the fluid. Geopressured resources consist of water at moderately high temperatures at pressures higher than normal hydrostatic pressure. This water contains dissolved methane. Geopressured sources in sedimentary formations along the Texas and Louisiana Gulf Coast are believed to be quite large. Geopressured formations also exist in sedimentary basins elsewhere in the US. Hot dry rock resources consist of relatively unfractured and unusually hot rocks at accessible depths that contain little or no water. To extract usable power from hot dry rock, the rock must be fractured and a confined fluid circulation system created. A heat transfer fluid is introduced, circulated, and withdrawn. The overall goal of the Geothermal Program is to build a technology base that will be used by the private sector to exploit geothermal resources which can supply large amounts of energy for electric power production and direct-heat applications.

  13. Unconventional gas recovery program. Semi-annual report for the period ending September 30, 1979

    SciTech Connect (OSTI)

    Manilla, R.D.

    1980-04-01

    This document is the third semi-annual report describing the technical progress of the US DOE projects directed at gas recovery from unconventional sources. Currently the program includes Methane Recovery from Coalbeds Project, Eastern Gas Shales Project, Western Gas Sands Project, and Geopressured Aquifers Project.

  14. CX-001544: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Recovery Act: Demonstrating the Commercial Feasibility of Geopressured-Geothermal Power Development at the Sweet Lake Field, Cameron Parish, LouisianaCX(s) Applied: B3.1, A9Date: 04/01/2010Location(s): Cameron Parish, LouisianaOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  15. Corrosion Resistances of Iron-Based Amorphous Metals with Yttrium and Tungsten Additions in Hot Calcium Chloride Brine & Natural Seawater: Fe48Mo14Cr15Y2C15B6 and W-Containing Variants

    SciTech Connect (OSTI)

    Farmer, J C; Haslam, J; Day, S; Lian, T; Saw, C; Hailey, P; Choi, J; Yang, N; Blue, C; Peter, W; Payer, J; Branagan, D J

    2006-10-20

    Yttrium-containing SAM1651 (Fe{sub 48.0}Cr{sub 15.0}Mo{sub 14.0}B{sub 6.0}C{sub 15.0}Y{sub 2.0}), has a critical cooling rate (CCR) of approximately 80 Kelvin per second, while SAM2X5 (Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4}) with no yttrium has a higher critical cooling rate of approximately 600 Kelvin per second. SAM1651's low CCR enables it to be rendered as a completely amorphous material in practical materials processes. Chromium (Cr), molybdenum (Mo) and tungsten (W) provide corrosion resistance; boron (B) enables glass formation; and rare earths such as yttrium (Y) lower critical cooling rate (CCR). The passive film stability of these Fe-based amorphous metal formulations have been found to be superior to that of conventional stainless steels, and comparable to that of Ni-based alloys, based on electrochemical measurements of the passive film breakdown potential and general corrosion rates.

  16. Operating Experience Summary, 2014-04

    Broader source: Energy.gov (indexed) [DOE]

    that store brine used to displace stored crude oil when the oil is withdrawn from underground caverns. The brine tanks must be repaired and repainted every 3 to 5 years to...

  17. Geochemical engineering reference manual

    SciTech Connect (OSTI)

    Owen, L.B.; Michels, D.E.

    1984-01-01

    The following topics are included in this manual: physical and chemical properties of geothermal brine and steam, scale and solids control, processing spent brine for reinjection, control of noncondensable gas emissions, and goethermal mineral recovery. (MHR)

  18. CX-010404: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace Brine Disposal System Header to West Hackberry Brine Tanks, Government Furnished Equipment CX(s) Applied: B1.3 Date: 04/22/2013 Location(s): Louisiana Offices(s): Strategic Petroleum Reserve Field Office

  19. CX-010401: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace Brine Disposal System Header to West Hackberry Brine Tanks CX(s) Applied: B1.3 Date: 04/22/2013 Location(s): Louisiana Offices(s): Strategic Petroleum Reserve Field Office

  20. CX-009718: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace Brine Disposal System Header to Bryan Mound Brine Tank, GFE CX(s) Applied: B1.3 Date: 12/11/2012 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  1. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    fuel cycle and fuel materials (2) radioactive wastes (2) sensitivity (2) simulation (2) water (2) arsenic (1) bentonite (1) boom clay (1) brine leakage (1) brines (1) buffers (1)...

  2. Column Sorption Uptake and Regeneration Study; Rare Earth Element Sorbent Uptake and Sorbent Stripping

    SciTech Connect (OSTI)

    Tim Lanyk

    2015-12-18

    Study of rare earth element (REE) uptake from geothermal brine simulant by column loading, metal recovery through stripping, and regeneration of column for re-loading. Simulated brine testing.

  3. EERE PowerPoint 97-2004 Template: Green Version

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reaction with CO 2 -brine at 200C (Smith et al, 2013) 2 | US DOE Geothermal Office ... reaction with CO 2 -brine at 200C (Smith et al, 2013) Increased fracture ...

  4. The Viability of Sustainable, Self-Propping Shear Zones in Ehanced...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reaction with CO 2 -brine at 200C (Smith et al, 2013) 2 | US DOE Geothermal Office ... reaction with CO 2 -brine at 200C (Smith et al, 2013) 7 | US DOE Geothermal Office ...

  5. EA-1482: Finding of No Significant Impact

    Broader source: Energy.gov [DOE]

    Pilot Experiment for Geological Sequestration of Carbon Dioxide in Saline Aquifer Brine Formations, Frio Formation, Liberty County, Texas

  6. Demonstration of a Variable Phase Turbine Power System for Low Temperature Geothermal Resources

    Broader source: Energy.gov [DOE]

    Project objectives: Demonstrate a 1 megawatt Variable Phase Turbine and Variable Phase Cycle with low temperature brine.

  7. New interpretations of Paleozoic stratigraphy and history in the northern Laramie Range and vicinity, Southeast Wyoming

    SciTech Connect (OSTI)

    Sando, W.J.; Sandberg, C.A.

    1987-01-01

    Biostratigraphic and lithostratigraphic studies of the Paleozoic sequence in Southeast Wyoming indicate the need for revision of the ages and nomenclature of Devonian, Mississippian, and Pennsylvanian formations. The Paleozoic sequence begins with a quartzarenite of Devonian age referred to the newly named Fremont Canyon Sandstone, which is overlain by the Englewood Formation of Late Devonian and Early Mississippian age. The Englewood is succeeded by the Madison Limestone of Early and Late Mississippian age, which is overlain disconformably by the Darwin Sandstone Member (Pennsylvanian) of the Casper and Hartville formations. This sequence represents predominantly marine deposition in near-shore environments marginal to the ancient Transcontinental Arch.

  8. Norm removal from frac water

    DOE Patents [OSTI]

    Silva, James Manio; Matis, Hope; Kostedt, IV, William Leonard

    2014-11-18

    A method for treating low barium frac water includes contacting a frac water stream with a radium selective complexing resin to produce a low radium stream, passing the low radium stream through a thermal brine concentrator to produce a concentrated brine; and passing the concentrated brine through a thermal crystallizer to yield road salt.

  9. Experimental and theoretical investigation of the production of HCl and some metal chlorides in magmatic/hydrothermal systems

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The theoretical analysis is given for calculating the composition of the aqueous vapor and the saline brine (hydrosaline liquid) present at run pressure and temperature in the experiment. The mixture of aqueous vapor and brine is homogenized upon quench. The method for calculating the concentration of HCl and NaCl in the coexisting aqueous vapor and brine is shown.

  10. Microsoft Word - NETL-TRS-6-2014_Imaging Techniques Applied to...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Pores within shale are generally only on the scale of nanometers, for example: Bakken Shale, 5 nm; Monterey Shale, 10-16 nm; Anadarko Basin, 50 nm; and Appalachian Devonian ...

  11. Technically Recoverable Shale Oil and Shale Gas Resources:

    Gasoline and Diesel Fuel Update (EIA)

    ... of the Paran Basin, although Amerisur Energy has discussed the shale potential of the ... Showing Flat-lying but Moderately Faulted Devonian Shale (Green) at Depths of 2 to 3 km. ...

  12. Evaluation of the corrosivity of dust deposited on waste packages at Yucca Mountain, Nevada.

    SciTech Connect (OSTI)

    Wolery, Thomas J.; Bryan, Charles R.; Barr, Deborah; Jarek, Russell L.; Hardin, Ernest L.; Shields, David R.; Sutton, Mark A.

    2005-08-01

    Potentially corrosive brines can form during post-closure by deliquescence of salt minerals in dust deposited on the surface of waste packages at Yucca Mountain during operations and the pre-closure ventilation period. Although thermodynamic modeling and experimental studies of brine deliquescence indicates that brines are likely to form, they will be nitrate-rich and noncorrosive. Processes that modify the brines following deliquescence are beneficial with respect to inhibition of corrosion. For example, acid degassing (HCl, HNO{sub 3}) could dry out brines, but kinetic limitations are likely to limit the effect to increasing their passivity by raising the pH and increasing the NO{sub 3}/Cl ratio. Predicted dust quantities and maximum brine volumes on the waste package surface are small, and physical isolation of salt minerals in the dust may inhibit formation of eutectic brines and decrease brine volumes. If brines do contact the WP surface, small droplet volumes and layer thicknesses do not support development of diffusive gradients necessary for formation on separate anodic-cathodic zones required for localized corrosion. Finally, should localized corrosion initiate, corrosion product buildup will stifle corrosion, by limiting oxygen access to the metal surface, by capillary retention of brine in corrosion product porosity, or by consumption of brine components (Cl{sup -}).

  13. Direct contact, binary fluid geothermal boiler

    DOE Patents [OSTI]

    Rapier, Pascal M.

    1982-01-01

    Energy is extracted from geothermal brines by direct contact with a working fluid such as isobutane which is immiscible with the brine in a geothermal boiler. The geothermal boiler provides a distributor arrangement which efficiently contacts geothermal brine with the isobutane in order to prevent the entrainment of geothermal brine in the isobutane vapor which is directed to a turbine. Accordingly the problem of brine carry-over through the turbine causes corrosion and scaling thereof is eliminated. Additionally the heat exchanger includes straightening vanes for preventing startup and other temporary fluctuations in the transitional zone of the boiler from causing brine carryover into the turbine. Also a screen is provided in the heat exchanger to coalesce the working fluid and to assist in defining the location of the transitional zone where the geothermal brine and the isobutane are initially mixed.

  14. Direct contact, binary fluid geothermal boiler

    DOE Patents [OSTI]

    Rapier, P.M.

    1979-12-27

    Energy is extracted from geothermal brines by direct contact with a working fluid such as isobutane which is immiscible with the brine in a geothermal boiler. The geothermal boiler provides a distributor arrangement which efficiently contacts geothermal brine with the isobutane in order to prevent the entrainment of geothermal brine in the isobutane vapor which is directed to a turbine. Accordingly the problem of brine carryover through the turbine causing corrosion and scaling thereof is eliminated. Additionally the heat exchanger includes straightening vanes for preventing startup and other temporary fluctuations in the transitional zone of the boiler from causing brine carryover into the turbine. Also a screen is provided in the heat exchanger to coalesce the working fluid and to assist in defining the location of the transitional zone where the geothermal brine and the isobutane are initially mixed.

  15. Geothermal Technologies Program Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Jay Nathwani Acting Program Manager Geothermal Technologies Program Office of Energy Efficiency and Renewable Energy The Geothermal Technologies Program Overview May 18 2010 Energy Efficiency & Renewable Energy eere.energy.gov Geothermal Technologies Program (GTP) Program Topic Areas *Low Temperature, Geopressured and Coproduced Resources *Innovative Exploration Technologies National Goals *Economy Putting people to work in the near- term, and in the future *Security Developing and expanding

  16. SMU Geothermal Conference 2011 - Geothermal Technologies Program |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy SMU Geothermal Conference 2011 - Geothermal Technologies Program SMU Geothermal Conference 2011 - Geothermal Technologies Program DOE Geothermal Technologies Program presentation at the SMU Geothermal Conference in June 2011. gtp_smu_conference_reinhardt_2011.pdf (1.4 MB) More Documents & Publications Low Temperature/Coproduced/Geopressured Subprogram Overview AAPG Low-Temperature Webinar Geothermal Technologies Program Peer Review Program June 6 - 10, 2011

  17. Geothermal Technologies Program Peer Review Program June 6 - 10, 2011

    Broader source: Energy.gov (indexed) [DOE]

    This overview of the Geothermal Technologies Program was given at the GTP Program Peer Review on May 18, 2010. overview_gtp.pdf (539.21 KB) More Documents & Publications AAPG Low-Temperature Webinar Low Temperature/Coproduced/Geopressured Subprogram Overview Geothermal Technologies Program Peer Review Program June 6 - 10, 2011

    Energy eere.energy.gov eere.energy.gov WELCOME Office of Energy Efficiency and Renewable Energy U.S. Department of Energy Geothermal Technologies Program Peer

  18. DOE OIG SemiAnn RPT 10-07.qxd

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Semiannual Report to Congress April 1, 2007 - September 30, 2007 U.S. DEPARTMENT OF ENERGY OFFICE OF INSPECTOR GENERAL DOE/IG-0053 Front Cover Photographs (Clockwise) Heliostats and Solar Two's tower collect and store enough thermal energy to produce electricity to power 10,000 homes. Construction of turbine/generator for hydroelectric plant. Drilling rig used in Department's Geothermal Geopressured Extraction Project to extract heated pressurized water and natural gas trapped below ground. The

  19. Effect of temperature, salinity and oil composition on wetting behavior and oil recovery by waterflooding

    SciTech Connect (OSTI)

    Tang, G.Q.; Morrow, N.R.

    1996-12-31

    The effect of aging and displacement temperatures, and brine and oil composition on wettability and the recovery of crude oil by spontaneous imbibition and waterflooding has been investigated. This study is based on displacement tests in Berea Sandstone using three distinctly different crude oils and three reservoir brines. Brine concentration was varied by changing the concentration of total dissolved solids of the synthetic brine in proportion to give brine of twice, one tenth, and one hundredth of the reservoir brine concentration. Aging and displacement temperatures were varied independently. For all crude oils, water-wetness and oil recovery increased with increase in displacement temperature. Tests on the effect of brine concentration showed that salinity of the connate and invading brines can have a major influence on wettability and oil recovery at reservoir temperature. Oil recovery increased over that for the reservoir brine with dilution of both the initial (connate) and invading brine or dilution of either. Removal of light components from the crude oil resulted in increased water-wetness. Addition of alkanes to the crude oil reduced the water-wetness, and increased oil recovery. Relationships between waterflood recovery and wettability are summarized.

  20. Preliminary evidence for fractionation of stable chlorine isotopes in ore-forming hydrothermal systems

    SciTech Connect (OSTI)

    Eastoe, C.J.; Guilbert, J.M. ); Kaufmann, R.S. )

    1989-03-01

    Chloride from fluid inclusions in hydrothermal minerals is found to have variable and distinctive {delta}{sup 37}Cl values spanning the range -1.1 0/{per thousand} to +0.8 {per thousand}. In Mississippi Valley-type deposits of Tennessee, brines of high (>0{per thousand}) and low (near -1{per thousand}) {delta}{sup 37}Cl are present. High {delta}{sup 37}Cl brines may be saline formation waters, but low {delta}{sup 37}Cl brines remain unexplained. In porphyry copper deposits, both high {delta}{sup 37}Cl (0.8{per thousand}, 0.3{per thousand}) and low {delta}{sup 37}Cl (-1.1{per thousand}, 0.7{per thousand}) hypersaline brines of probable magmatic origin occur. High-salinity magmatic brines with low {delta}{sup 37}Cl values contrast isotopically with high {delta}{sup 37}Cl, less concentrated brines responsible for quartz-sericite-pyrite assemblages.

  1. Request for Information explores mineral recovery from geothermal fluids

    Broader source: Energy.gov [DOE]

    The DOE Geothermal Technologies Office (GTO) is seeking input on ideas that encourage geothermal development by exploring innovations in extracting critical materials found in geothermal brines....

  2. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Julianna Eileen An integrated framework for CO2 accounting and risk analysis ... Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an ...

  3. EIS-0444-SA-01: Draft Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and additional information gathered from an exploratory well and nearby production wells to support planning for the TCEP's deep well injection option for brine disposal has ...

  4. NETL F 451.1/1-1, Categorical Exclusion Designation Form

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TX; Trimeric Corporation: Champaign, IL and Buda, TX. FESCCStorage Division Bruce Brown Brine Extraction and Treatment Strategies to Enhance Pressure Management... Project...

  5. Categorical Exclusion Determination Forn1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    * Modification (not expansion)abandonment of oil storage access brine injectiongasgeothermal wells; no site closure OBS.4 - Repairreplacement of pipeline sections within...

  6. Dixie Valley Bottoming Binary Cycle

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ScientificTechnical Approach Brine Injection Pipeline 6 | US DOE Geothermal Program ... level - Makeup water requirements - Permit Impacts - Space requirements * Phase 1 ...

  7. Beowawe Binary Bottoming Cycle

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ScientificTechnical Approach Brine Injection Pipeline 6 | US DOE Geothermal Program ... level - Makeup water requirements - Permit Impacts - Space requirements * Phase 1 ...

  8. Accident Investigation of the February 7, 2013, Scissor Lift...

    Energy Savers [EERE]

    February 7, 2013, Scissor Lift Accident in the West Hackberry Brine Tank-14 Resulting in Injury, Strategic Petroleum Reserve West Hackberry, LA Accident Investigation of the ...

  9. TITLE AUTHORS SUBJECT SUBJECT RELATED DESCRIPTION PUBLISHER AVAILABILI...

    Office of Scientific and Technical Information (OSTI)

    Reduced Order Model for the Geochemical Impacts of Carbon Dioxide Brine and Trace Metal Leakage into an Unconfined Oxidizing Carbonate Aquifer Version Bacon Diana H carbon...

  10. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1 Citation Details...

  11. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1","Bacon, Diana...

  12. Simbol Mining Corp | Open Energy Information

    Open Energy Info (EERE)

    company commercialising zero waste, zero carbon footprint production processes for lithium, EMD, and zinc battery chemicals produced from geothermal brines. Coordinates:...

  13. DOE-EA-1116 | Open Energy Information

    Open Energy Info (EERE)

    storage tanks and transferring geothermal brine at the power plant. imposed Dames & Moore completed a detailed risk assessment to evaluate potential impacts from an accidental...

  14. Probabilistic evaluation of shallow groundwater resources at...

    Office of Scientific and Technical Information (OSTI)

    atmosphere. This study first develops an integrated Monte Carlo method for simulating CO2 and brine leakage from carbon sequestration and subsequent geochemical interactions in...

  15. Demonstration of a Variable Phase Turbine Power System for Low...

    Broader source: Energy.gov (indexed) [DOE]

    Project objectives: Demonstrate a 1 megawatt Variable Phase Turbine and Variable Phase Cycle with low temperature brine. lowhaysvariablephaseturbine.pdf (732.28 KB) More ...

  16. Li and Mn uptake data from initial set of imprinted polymers

    SciTech Connect (OSTI)

    Susanna Ventura

    2015-03-27

    Batch tests of crosslinked lithium and manganese imprinted polymers of variable composition to assess their ability to extract lithium and manganese from synthetic brines at T=45C .

  17. C R O S S C U T T I N G R E S E A R C H

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... High Temperature Applications Peter Liaw, University of Tennessee * Low-Energy Water Recovery from Subsurface Brines Zachary Hendren, Research Triangle Institute * Treatment of ...

  18. 2016 CROSSCUTTING RESEARCH & RARE EARTH ELEMENTS PORTFOLIOS REVIEW

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    University of Maine System * Low-Cost Efficient and Durable High Temperature Wireless Sensors by Direct ... High Salinity Produced Brine Treatment via Direct Waste Heat ...

  19. Ohio Department of Natural Resources | Open Energy Information

    Open Energy Info (EERE)

    division's responsibilities include regulation of Ohio's oil and gas drilling operations oil and gas production operations brine disposal operations solution mining operations...

  20. EERE PowerPoint 97-2004 Template: Green Version

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    * Geothermal fluids have a complex chemical composition determined by the ... RelevanceImpact of Research x Green and Nix, NRELTP-840-40665 (2006) Brine ...

  1. State Oil and Gas Boards | Open Energy Information

    Open Energy Info (EERE)

    and protect the correlative rights of ownership associated with the production of oil, natural gas and brine, while protecting the environment during the production process,...

  2. EERE PowerPoint 97-2004 Template: Green Version

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Magnetic Partitioning Nanofluid for Rare Earth Extraction from Geothermal Fluids 2 | US DOE ... them suitable to extract rare earth elements (REE) from geothermal brines. ...

  3. Geothermal Technologies Office March

    Broader source: Energy.gov (indexed) [DOE]

    ... supplying new applications for geothermal power, some geothermal brines are turning up relatively high concentrations of rare earth elements (REEs) and other valu- able materials. ...

  4. Geothermal Energy News | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lakes, California. August 21, 2013 Nevada: Geothermal Brine Brings Low-Cost Power with Big Potential Utilizing EERE funds, ElectraTherm developed a geothermal technology that...

  5. CO2-H2O Mixtures in the Geological Sequestration of CO2. II....

    Office of Scientific and Technical Information (OSTI)

    and Duan and Sun (2003), which can be extended to chloride solutions other than NaCl. ... BRINES; CHLORIDES; MIXTURES; REACTION KINETICS; SOLUBILITY; SUN; THERMODYNAMIC ACTIVITY

  6. Section 33: Consideration of Drilling Events in Performance Assessment...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... of the WIPP, brinefluid removal, and circulation of brine within the panels. ... and Disposal of Spent Nuclear Fuel, High-Level and Transuranic Radioactive Wastes; Final Rule." ...

  7. Document

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Disposal of Spent Nuclear Fuel, High-Level and Transuranic (TRU) Radioactive Waste.'' ... to block brine flow between waste panels in WIPP. In the CCA, DOE presented ...

  8. Li and Mn uptake data from initial set of imprinted polymers

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Susanna Ventura

    Batch tests of crosslinked lithium and manganese imprinted polymers of variable composition to assess their ability to extract lithium and manganese from synthetic brines at T=45C .

  9. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Center Office of Groundwater and Soil Remediation Office of Nonproliferation and ... (2) water (2) aqueous solutions (1) bacteria (1) bioremediation (1) brines (1) ...

  10. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    ... Filter Results Filter by Subject ammonia (1) battery separators (1) brines (1) cathodes ... Channel flow cathode assembly and electrolyzer Larson, E. H. ; Fitch, R. H. ; Kurtz, B. E. ...

  11. Lithium uptake data of lithium imprinted polymers

    SciTech Connect (OSTI)

    Susanna Ventura

    2015-12-04

    Batch tests of lithium imprinted polymers of variable composition to assess their ability to extract lithium from synthetic brines at T=45C. Initial selectivity data are included

  12. Evaluation Project 4492

    National Nuclear Security Administration (NNSA)

    Fossil, and Renewable Energy Activities B5.1 - Actions ...abandonment of oil storage access brine injection... - Environmental control system improvements in existing ...

  13. Computer Modeling of Chemical and Geochemical Processes in High...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computer modeling of chemical and geochemical processes in high ionic strength solutions ... in brine Computer modeling of chemical and geochemical processes in high ionic ...

  14. EIS-0385: Draft Environmental Impact Statement | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at two or three existing sites. Storage capacity would be developed by solution mining of salt domes and disposing of the resulting salt brine by ocean discharge or...

  15. EIS-0385: Final Environmental Impact Statement | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at two or three existing sites. Storage capacity would be developed by solution mining of salt domes and disposing of the resulting salt brine by ocean discharge or...

  16. Microsoft PowerPoint - 4 Chris Camphouse [Compatibility Mode...

    Office of Environmental Management (EM)

    Direct Releases Dominate Total Releases Waste Panel Borehole Cuttings (Solids from Drilling) Cavings (Solids from Drilling) Spallings (Solids from Pressure Release) Direct Brine ...

  17. Hydrogen generation by metal corrosion in simulated Waste Isolation Pilot Plant environments. Progress report for the period November 1989 through December 1992

    SciTech Connect (OSTI)

    Telander, M.R.; Westerman, R.E.

    1993-09-01

    The corrosion and gas-generation characteristics of three material types: low-carbon steel (the current waste packaging material for the Waste Isolation Pilot Plant), Cu-base materials, and Ti-base materials were determined in both the liquid and vapor phase of Brine A, a brine representative of an intergranular Salado Formation brine. Test environments included anoxic brine and anoxic brine with overpressures of CO{sub 2}, H{sub 2}S, and H{sub 2}. Low-carbon steel reacted at a slow, measurable rate with anoxic brine, liberating H{sub 2} on an equimolar basis with Fe reacted. Presence of CO{sub 2} caused the initial reaction to proceed more rapidly, but CO{sub 2}-induced passivation stopped the reaction if the CO{sub 2} were present in sufficient quantities. Low-carbon steel immersed in brine with H{sub 2}S showed no reaction, apparently because of passivation of the steel by formation of a protective iron sulfide reaction product. Cu- and Ti-base materials showed essentially no corrosion when exposed to brine and overpressures of N{sub 2}, CO{sub 2}, and H{sub 2}S except for the rapid and complete reaction between Cu-base materials and H{sub 2}S. No significant reaction took place on any material in any environment in the vapor-phase exposures.

  18. Heber geothermal coupon analytical report: (Final technical report)

    SciTech Connect (OSTI)

    Not Available

    1986-10-20

    The objectives of this paper are: to determine the cause of accelerated metal loss from the loading edges (as relates to brine flow) of carbon steel coupons in the low temperature portion of the Heber brine loop; and to clarify the reason for the distinctly different morphology of attack on the A53B pipe steel compared to the sheet 1018 steel. 6 figs.

  19. CX-010712: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace West Hackberry Brine Disposal System Header from MOV-51’s to WHT-14/15 Brine Tanks with HDPE Pipe CX(s) Applied: B5.2 Date: 07/03/2013 Location(s): Louisiana Offices(s): Strategic Petroleum Reserve Field Office

  20. Climate Change Reference Book

    SciTech Connect (OSTI)

    1988-01-01

    This report was prepared for DOE Deputy Assistant Secretary for Renewable Energy, in 1988, by Meridian Corporation, Alexandria, Va. It set the environmental impacts of geothermal power in the context of those of other renewables, coal, and nuclear. While this is a compendium from largely secondary sources, it gives estimates for CO2 per GWh for the three phases of resource extraction, facility construction, and facility operation. Tons of concrete and steel used are estimated. System include hydrothermal (dry steam, flashed, binary), geopressured, hot dry rock, and magma. (DJE 2005)

  1. Geothermal well log interpretation state of the art. Final report

    SciTech Connect (OSTI)

    Sanyal, S.K.; Wells, L.E.; Bickham, R.E.

    1980-01-01

    An in-depth study of the state of the art in Geothermal Well Log Interpretation has been made encompassing case histories, technical papers, computerized literature searches, and actual processing of geothermal wells from New Mexico, Idaho, and California. A classification scheme of geothermal reservoir types was defined which distinguishes fluid phase and temperature, lithology, geologic province, pore geometry, salinity, and fluid chemistry. Major deficiencies of Geothermal Well Log Interpretation are defined and discussed with recommendations of possible solutions or research for solutions. The Geothermal Well Log Interpretation study and report has concentrated primarily on Western US reservoirs. Geopressured geothermal reservoirs are not considered.

  2. Geothermal Energy R&D Program Annual Progress Report for Fiscal Year 1992

    SciTech Connect (OSTI)

    1993-07-01

    Geothermal budget actual amounts are shown for FY 1989 -1992, broken down by about 15 categories. Here, the main Program categories are: Exploration Technology, Drilling Technology, Reservoir Technology, Conversion Technology (power plants and materials), Industry-Coupled Drilling, Drilling Applications, Reservoir Engineering Applications, Direct Heat, Geopressured Wells Operation, and Hot Dry Rock Research. Here the title--Industry-Coupled Drilling--covered case studies of the Coso, CA, and Dixie Valley, NV, fields, and the Long Valley Exploratory Well (which had started as a magma energy exploration project, but reported here as a hydrothermal prospect evaluation well). (DJE 2005)

  3. The National Energy Strategy - The role of geothermal technology development: Proceedings

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    Each year the Geothermal Division of the US Department of Energy conducts an in-depth review of its entire geothermal R D program. The conference serves several purposes: a status report on current R D activities, an assessment of progress and problems, a review of management issues, and a technology transfer opportunity between DOE and the US geothermal industry. Topics in this year's conference included Hydrothermal Energy Conversion Technology, Hydrothermal Reservoir Technology, Hydrothermal Hard Rock Penetration Technology, Hot Dry Rock Technology, Geopressured-Geothermal Technology and Magma Energy Technology. Each individual paper has been cataloged separately.

  4. Geothermal -- The Energy Under Our Feet: Geothermal Resource Estimates for the United States

    SciTech Connect (OSTI)

    Green, B. D.; Nix, R. G.

    2006-11-01

    On May 16, 2006, the National Renewable Energy Laboratory (NREL) in Golden, Colorado hosted a geothermal resources workshop with experts from the geothermal community. The purpose of the workshop was to re-examine domestic geothermal resource estimates. The participating experts were organized into five working groups based on their primary area of expertise in the following types of geothermal resource or application: (1) Hydrothermal, (2) Deep Geothermal Systems, (3) Direct Use, (4) Geothermal Heat Pumps (GHPs), and (5) Co-Produced and Geopressured. The workshop found that the domestic geothermal resource is very large, with significant benefits.

  5. Countercurrent direct contact heat exchange process and system

    DOE Patents [OSTI]

    Wahl, III, Edward F.; Boucher, Frederic B.

    1979-01-01

    Recovery of energy from geothermal brines and other hot water sources by direct contact heat exchange with a working fluid, such as a hydrocarbon working fluid, e.g. isobutane. The process and system consists of a plurality of stages, each stage including mixing and settling units. In the first stage, hot brine and arm working fluid are intimately mixed and passed into a settler wherein the brine settles to the bottom of the settler and the hot working fluid rises to the top. The hot working fluid is passed to a heat engine or turbine to produce work and the working fluid is then recycled back into the system. The system is comprised of a series of stages each containing a settler and mixer, and wherein the working fluid and the brine flow in a countercurrent manner through the stages to recover the heat from the brine in increments and raise the temperature of the working fluid in increments.

  6. Natural radionuclides in groundwaters

    SciTech Connect (OSTI)

    Laul, J.C.

    1990-01-01

    The U-234 and Th-230 radionuclides are highly retarded by factors of 10{sup 4} to 10{sup 5} in basalt groundwater (Hanford) and briny groundwaters from Texas and geothermal brine from the Salton Sea Geothermal Field (SSGF). In basalt groundwaters (low ionic strength), Ra is highly sorbed, while in brines (high ionic strength), Ra is soluble. This is probably because the sorption sites are saturated with Na{sup +} and Cl{sup {minus}} ions and RaCl{sub 2} is soluble in brines. Pb-210 is soluble in SSGF brine, probably as a chloride complex. The U-234/Th-230 ratios in basalt groundwaters and brines from Texas and SSGF are nearly unity, indicating that U is in the +4 state, suggesting a reducing environment for these aquifers. 19 refs., 3 figs.

  7. Hummingbird structure in southeastern Saskatchewan

    SciTech Connect (OSTI)

    Smith, D.D.

    1985-05-01

    Saskatchewan's first Devonian oil pool was discovered September 1966, at Hummingbird, 45 mi (72 km) southwest of Weyburn, Saskatchewan. The Hummingbird structure, located on the northwest flank of the Williston basin, is domal is nature and covers approximately 1 mi/sup 2/ (2.6 km/sup 2/). Oil production is from two zones. The Ratcliffe Member of the Mississippian Charles Formation produces from an algal and bioclastic limestone averaging 49 ft (15 m) thick. The Devonian Birdbear Formation produces from a finely crystalline vuggy dolomite averaging 56 ft (17 m) thick. The Hummingbird structure is a sedimentary structure resulting from multiple-stage salt solution and collapse. Recurring local solution of Middle Devonian Prairie Evaporite during Late Devonian and Early Mississippian time resulted in collapse of overlying strata and deposition of compensating thicknesses of Souris River, Duperow, and Bakken sediments. Between Mississippian and Cretaceous time, solution of Prairie Evaporite in the surrounding area caused collapse of all super-Prairie evaporite beds. The extra Souris River, Duperow, and Bakken strata at Hummingbird created the structure. Vertical migration of formation waters along a high-angle fault is suggested as the cause of the local salt solution at Hummingbird.

  8. Study of hydrocarbon: shale interaction. Progress report No. 16, October 1-December 31, 1979 and January 1-March 31, 1980

    SciTech Connect (OSTI)

    Schettler, P.D. Jr.; Wampler, D.L.

    1980-01-01

    Data and interpretations relating the physical chemistry of Devonian shale to the productivity of natural gas wells are presented in this report. Specifically, methane isotherms, helium porosity, BET, and permeability and diffusion data are presented at pressures ranging up to 1000 psi. Use of the data in productivity calculations and resource estimation has been the subject of other reports in this series.

  9. Exploration within the Sub-Andean Thrust Belt of Southern Bolivia

    SciTech Connect (OSTI)

    Nelson, K.J. )

    1993-02-01

    The Sub-Andean thrust belt of Southern Bolivia is a proven hydrocarbon province. Chevron began a regional study of the area in 1988 and chose the Caipipendi block due to its high potential for significant new oil reserves. A regional work program designed to acquire and integrate seismic data, geologic field data, geochemistry, and gravity data was used to generated structural models, evaluate regional risk components and to detail leads. The structural style within the Caipipendi block is interpreted as being an in sequence, thin skinned thrust belt with eastward verging folds and thrust faults. Tight surface anticlines associated with a Middle Devonian detachment have been later folded by deeper fault bend folds associated with the Silurian detachment. While the tight surface folds are presently producing oil, the deeper broader structures associated with the Silurian detachement have not been tested. Seismic data, utilized for the first time in this part of the Sub-Andean thrust belt, integrated with balanced structural cross sections, is the key to evaluating this new play. Geochemical analysis, including oil biomarker work, indicate that the oils are sourced from the Silurian-Devonian sequence. A generative oil system model formulated by integrating the geochemical analysis with maturation modeling indicates that the Devonian Los Monos formation is the primary oil source. Anticipated reservoirs for the new play are Carboniferous and Devonian sandstones which are also productive elsewhere in the basin.

  10. Laboratory measurements of large-scale carbon sequestration flows in saline reservoirs

    SciTech Connect (OSTI)

    Backhaus, Scott N

    2010-01-01

    Brine saturated with CO{sub 2} is slightly denser than the original brine causing it to sink to the bottom of a saline reservoir where the CO{sub 2} is safely sequestered. However, the buoyancy of pure CO{sub 2} relative to brine drives it to the top of the reservoir where it collects underneath the cap rock as a separate phase of supercritical fluid. Without additional processes to mix the brine and CO{sub 2}, diffusion in this geometry is slow and would require an unacceptably long time to consume the pure CO{sub 2}. However, gravity and diffusion-driven convective instabilities have been hypothesized that generate enhanced CO{sub 2}-brine mixing promoting dissolution of CO{sub 2} into the brine on time scale of a hundred years. These flows involve a class of hydrodynamic problems that are notoriously difficult to simulate; the simultaneous flow of mUltiple fluids (CO{sub 2} and brine) in porous media (rock or sediment). The hope for direct experimental confirmation of simulations is dim due to the difficulty of obtaining high resolution data from the subsurface and the high pressures ({approx}100 bar), long length scales ({approx}100 meters), and long time scales ({approx}100 years) that are characteristic of these flows. We have performed imaging and mass transfer measurements in similitude-scaled laboratory experiments that provide benchmarks to test reservoir simulation codes and enhance their predictive power.

  11. A Systems Approach to Identifying Exploration and Development Opportunities in the Illinois Basin: Digital Portifolio of Plays in Underexplored Lower Paleozoic Rocks

    SciTech Connect (OSTI)

    Beverly Seyler; David Harris; Brian Keith; Bryan Huff; Yaghoob Lasemi

    2008-06-30

    This study examined petroleum occurrence in Ordovician, Silurian and Devonian reservoirs in the Illinois Basin. Results from this project show that there is excellent potential for additional discovery of petroleum reservoirs in these formations. Numerous exploration targets and exploration strategies were identified that can be used to increase production from these underexplored strata. Some of the challenges to exploration of deeper strata include the lack of subsurface data, lack of understanding of regional facies changes, lack of understanding the role of diagenetic alteration in developing reservoir porosity and permeability, the shifting of structural closures with depth, overlooking potential producing horizons, and under utilization of 3D seismic techniques. This study has shown many areas are prospective for additional discoveries in lower Paleozoic strata in the Illinois Basin. This project implemented a systematic basin analysis approach that is expected to encourage exploration for petroleum in lower Paleozoic rocks of the Illinois Basin. The study has compiled and presented a broad base of information and knowledge needed by independent oil companies to pursue the development of exploration prospects in overlooked, deeper play horizons in the Illinois Basin. Available geologic data relevant for the exploration and development of petroleum reservoirs in the Illinois Basin was analyzed and assimilated into a coherent, easily accessible digital play portfolio. The primary focus of this project was on case studies of existing reservoirs in Devonian, Silurian, and Ordovician strata and the application of knowledge gained to future exploration and development in these underexplored strata of the Illinois Basin. In addition, a review of published reports and exploration in the New Albany Shale Group, a Devonian black shale source rock, in Illinois was completed due to the recent increased interest in Devonian black shales across the United States. The New

  12. Overview of fundamental geochemistry basic research at the Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Anovitz, L.M.; Benezeth, P.; Blencoe, J.G.

    1996-01-01

    Researchers in ORNL`s Geochemistry and High Temperature Aqueous Chemistry groups are conducting detailed experimental studies of physicochemical properties of the granite-melt-brine system; sorption of water on rocks from steam-dominated reservoirs; partitioning of salts and acid volatiles between brines and steam; effects of salinity on H and O isotope partitioning between brines, minerals, and steam; and aqueous geochemistry of Al. These studies contribute in many ways to cost reductions and improved efficiency in the discovery, characterization, and production of energy from geothermal resources.

  13. EIS-0165: Strategic Petroleum Reserve Alabama, Louisiana, Mississippi, and Texas

    Broader source: Energy.gov [DOE]

    This EIS assesses the impacts of construction and operation for the range of alternatives being considered and focuses on oil and brine spill risk and impacts of brine disposal. The proposed action entails the development of a plan for 250 million barrels of new crude oil storage capacity in two Gulf Coast salt domes to expand the Strategic Petroleum Reserve pursuant to Congressional directive (PL I 01-383 and PL 101-512). Storage capacity would be developed by solution-mining the salt which would require about two billion barrels of surface water and would generate about two billion barrels of salt brine.

  14. Geothermal research at the Puna Facility

    SciTech Connect (OSTI)

    Chen, B.

    1986-05-01

    Chemical analyses were conducted on the flocculated silica samples obtained during previous field experiments at HGP-A on both flashed and unflashed brines to determine the composition of the recovered silica for specific constituents of the brine which seem to often be entrapped in the silica during the flocculation process. Metals added as flocculants to the brine were also analyzed in order to evaluate the ease or difficulty with which these can be removed from the precipitated silica under varying conditions. Conditions employed included simple distilled water and acid washing (HCl of varying concentration).

  15. Tuba City, Arizona, Disposal Site Fact Sheet

    Office of Legacy Management (LM)

    This site is managed by the U.S. Department of Energy Office of Legacy Management under ... A lined solar evaporation pond receives the waste liquid (brine) and the softener ...

  16. CX-013488: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace 24" West Hackberry Brine Disposal Pipeline (GFE) (WH-MM-826A) CX(s) Applied: B1.3Date: 03/09/2015 Location(s): LouisianaOffices(s): Strategic Petroleum Reserve Field Office

  17. CX-013485: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Re-coat WHT-15 Brine Tank (WH-MM-819D) CX(s) Applied: B1.3Date: 03/24/2015Location(s): LouisianaOffices(s): Strategic Petroleum Reserve Field Office

  18. DOE-Sponsored Project Tests Novel Method to Increase Oil Recovery

    Office of Energy Efficiency and Renewable Energy (EERE)

    Successful laboratory tests at the Energy Department’s National Energy Technology Laboratory (NETL) have verified that the use of a brine-soluble ionic surfactant could improve the efficiency of carbon dioxide enhanced oil recovery (CO2-EOR).

  19. CX-013851: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Advanced Analytical Methods for Air and Stray Gas Emissions and Produced Brine Characterization CX(s) Applied: B3.1Date: 06/23/2015 Location(s): TexasOffices(s): National Energy Technology Laboratory

  20. Microsoft Word - Appendix C_DisposalCellContents.doc

    Office of Legacy Management (LM)

    ... Total occupied volume is below 50 cy. Use 50 cy. 50.00 Brine tanks from SWTP Mixed with soil. Est. conversion factor is 0.430. 25.80 Contaminated Jersey barriers 27 each at 0.5 cy. ...

  1. CX-011223: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Bryan Mound Brine Disposal Pump Replacement (Install) CX(s) Applied: B5.2 Date: 10/28/2013 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  2. CX-010711: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Bryan Mound Brine Disposal Pump Replacement CX(s) Applied: B5.2 Date: 07/03/2013 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  3. CX-100008: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Selective Recovery of Metals from Geothermal Brines Award Number: DE-EE0006747 CX(s) Applied: A9, B3.6 Geothermal Technologies Date: 08/28/2014 Location(s): California Office(s): Golden Field Office

  4. Energy Department Selects Five Projects in First Step to Produce...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and the flow of CO2 - also known as a plume steering- brine can be extracted from the formation at specific points, where fresh water can be separated in a process known as...

  5. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1 Bacon, Diana H. carbon...

  6. CX-013764: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Repair Bayou Choctaw Brine Disposal Road (LANG and Subcontractor) CX(s) Applied: B1.3Date: 05/27/2015 Location(s): LouisianaOffices(s): Strategic Petroleum Reserve Field Office

  7. CX-007505: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Record of Categorical Exclusion for Big Hill Raw Water Brine header Piping Inspection CX(s) Applied: B1.3 Date: 11/28/2011 Location(s): Texas Offices(s): Strategic Petroleum Reserve Field Office

  8. CX-005610: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Soil Amendment Product for Oilfield Brine Contaminated Soil ? Field Testing Part IICX(s) Applied: B3.7Date: 04/12/2011Location(s): Rosalia, KansasOffice(s): Fossil Energy, National Energy Technology Laboratory

  9. CX-004719: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Upgrade Communication/Control Systems to BC Brine Disposal Well (Government Furnished Equipment and Install)CX(s) Applied: B1.7Date: 11/23/2010Location(s): LouisianaOffice(s): Strategic Petroleum Reserve Field Office

  10. CX-004274: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Soil Amendment Product for Oilfield Brine Contaminated Soil ? Field Testing Part IICX(s) Applied: B3.7Date: 10/19/2010Location(s): Blackwell, OklahomaOffice(s): Fossil Energy, National Energy Technology Laboratory

  11. DOE Partner Begins Carbon Storage Test | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of 6-8 months into an existing brine-water injection well at depths of about 1,900 feet. ... Following injection, the oil, gas, and water produced will be measured to evaluate the ...

  12. Most Viewed Documents for Renewable Energy Sources: September...

    Office of Scientific and Technical Information (OSTI)

    (2000) 62 Calculation of brine properties. Above 80sup 0F and for salt content between 5 and 25% Dittman, G.L. (1977) 54 Development of the helical reaction hydraulic turbine. ...

  13. EERE Success Story-Geothermal Technology Breakthrough in Alaska...

    Broader source: Energy.gov (indexed) [DOE]

    A binary process mixes geothermal brine with a working fluid that has a lower boiling point than water. This fluid is compressed into steam to turn a turbine and generate ...

  14. Laboratory testing and modeling to evaluate perfluorocarbon compounds...

    Office of Scientific and Technical Information (OSTI)

    Two sets of duplicate tests were conducted in batch mode in gold-bag reactors, with one pair of reactors charged with a synthetic geothermal brine containing the PFTs and a second ...

  15. CX-010606: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Development of Subsurface Brine Disposal Framework in the Northern Appalachian Basin CX(s) Applied: B3.1 Date: 07/25/2013 Location(s): Kentucky Offices(s): National Energy Technology Laboratory

  16. CX-011437: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Advanced Analytical Methods for Air and Stray Gas Emissions and Produced Brine Characterization CX(s) Applied: A9 Date: 11/21/2013 Location(s): New York Offices(s): National Energy Technology Laboratory

  17. Manganese uptake of imprinted polymers

    SciTech Connect (OSTI)

    Susanna Ventura

    2015-09-30

    Batch tests of manganese imprinted polymers of variable composition to assess their ability to extract lithium and manganese from synthetic brines at T=45C . Data on manganese uptake for two consecutive cycles are included.

  18. CX-006250: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Blast and Paint Bayou Choctaw Brine Pump Pad and Associate PipingCX(s) Applied: B1.3Date: 06/20/2011Location(s): Iberville Parish, LouisianaOffice(s): Strategic Petroleum Reserve Field Office

  19. Microsoft Word - NRAP-TRS-III-005-2012_ROMDevelopment_20121018...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carlo simulation with 1000 samples, using (a) HFM and (b) ROM. Suggested Citation: Zhang, Y.; Pau, G. Reduced-Order Model Development for CO 2 Storage in Brine Reservoirs; ...

  20. CX-005370: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Clean and Inspect West Hackberry (WHT-14) Brine TankCX(s) Applied: B1.3Date: 02/22/2011Location(s): West Hackberry, LouisianaOffice(s): Strategic Petroleum Reserve Field Office

  1. CX-013882: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace Bayou Choctaw Brine Disposal/Recycle Piping in Pump/Pond Area CX(s) Applied: B1.3Date: 07/17/2015 Location(s): None ProvidedOffices(s): Strategic Petroleum Reserve Field Office

  2. Beowawe Binary Bottoming Cycle

    Broader source: Energy.gov [DOE]

    Project objectives: Demonstrate the technical and economic feasibility of electricity generation from the nonconventional geothermal resources of 205°F by extracting waste heat from the brine to power a binary power plant.

  3. Dixie Valley Bottoming Binary Cycle

    Broader source: Energy.gov [DOE]

    Project objective: Prove the technical and economic feasibility of utilizing the available unused heat to generate additional electric power from a binary power plant from low-temperature brine at the Dixie Valley Geothermal Power Plant.

  4. Research News January 2015, Issue 4

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experiments and Models Help Predict CO2 Solubility in Brines page 2 the ENERGY lab NATIONAL ENERGY TECHNOLOGY LABORATORY From NETL's Office of Research & Development Researchnews June 2015, Issue 9 2 Contents June 2015, Issue 9 2 Feature Story: Experiments and Models Help Predict CO2 Solubility in Brines 4 Novel Techniques for Field Measurement of CO2 in Groundwater 5 New Tool Predicts Behavior of Materials Used in CO2 Capture Processes 6 New Capability Takes Sensor Fabrication to a New

  5. Nevada manufacturer installing geothermal power plant | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Nevada manufacturer installing geothermal power plant Nevada manufacturer installing geothermal power plant August 26, 2010 - 4:45pm Addthis Chemetall extracts lithium carbonate, a powder, from brine, a salty solution from within the earth. | Photo courtesy Chemetall Chemetall extracts lithium carbonate, a powder, from brine, a salty solution from within the earth. | Photo courtesy Chemetall Joshua DeLung Chemetall supplies materials for lithium-ion batteries for electric vehicles

  6. Disequilibrium study of natural radionuclides of uranium and thorium series in cores and briny groundwaters from Palo Duro Basin, Texas

    SciTech Connect (OSTI)

    Laul, J.C.; Smith, M.R.

    1988-05-01

    The concentrations of natural radionuclides of the /sup 238/U and /232/Th series are reported in several cores and in ten deep and five shallow briny groundwaters from various formations in the Palo Duro Basin. The formations include Granite Wash, Pennsylvanian Granite Wash, Wolfcamp Carbonate, Pennsylvanian Carbonate, Seven River, Queen Grayburg, San Andres, Yates and Salado. The natural radionuclide data in cores suggest that the radionuclides have not migrated or been leached for at least a period of about 1 million years. Relative to the U and Th concentrations in cores, the brines are depleted by a factor of 10/sup 4/ to 10/sup 5/, indicating extremely low solubility of U and Th in brines. The natural radionuclide data in brines suggest that radium is not sorbed significantly and thus not retarded in nine deep brines. Radium is somewhat sorbed in one deep brine of Wolfcamp Carbonate and significantly sorbed in shallow brines. Relative to radium, the U, Th, Pb, Bi, and Po radionuclides are highly retarded by sorption. The retardation factors for /sup 228/Th range from 10/sup 2/ to 10/sup 3/, whereas those for /sup 230/Th and /sup 234/U range from 10/sup 3/ to 10/sup 5/, depending on the formation. The /sup 234/U//sup 238/U ratios in these brines are constant at about 1.5. The magnitude of the /sup 234/U//sup 230/Th ratio appears to reflect the degree of redox state of the aquifer's environment. The /sup 234/U//sup 230/Th ratio in nine deep brines is about unity, suggesting that U, like Th/sup +4/, is in the +4 state, which in turn suggests a reduced environment. 49 refs., 23 figs., 18 tabs.

  7. Water purification using organic salts

    DOE Patents [OSTI]

    Currier, Robert P.

    2004-11-23

    Water purification using organic salts. Feed water is mixed with at least one organic salt at a temperature sufficiently low to form organic salt hydrate crystals and brine. The crystals are separated from the brine, rinsed, and melted to form an aqueous solution of organic salt. Some of the water is removed from the aqueous organic salt solution. The purified water is collected, and the remaining more concentrated aqueous organic salt solution is reused.

  8. An integrated experimental and numerical study: Developing a reaction

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    transport model that couples chemical reactions of mineral dissolution/precipitation with spatial and temporal flow variations in CO2/brine/rock systems | Department of Energy An integrated experimental and numerical study: Developing a reaction transport model that couples chemical reactions of mineral dissolution/precipitation with spatial and temporal flow variations in CO2/brine/rock systems An integrated experimental and numerical study: Developing a reaction transport model that

  9. Sequestration of CO2 in Mixtures of Bauxite Residue and Saline Wastewater

    SciTech Connect (OSTI)

    Dilmore, R.M.; Lu, Peng; Allen, D.E.; Soong, Yee; Hedges, S.W.; Fu, J.K.; Dobbs, C.L.; DeGalbo, A.D.; Zhu, Chen

    2008-01-01

    Experiments were conducted to explore the concept of beneficially utilizing mixtures of caustic bauxite residue slurry (pH 13) and produced oil-field brine to sequester carbon dioxide from flue gas generated from industrial point sources. Data presented herein provide a preliminary assessment of the overall feasibility of this treatment concept. The Carbonation capacity of bauxite residue/brine mixtures was considered over the full range of reactant mixture combinations in 10% increments by volume. A bauxite residue/brine mixture of 90/10 by volume exhibited a CO2 sequestration capacity of greater than 9.5 g/L when exposed to pure CO2 at 20 °C and 0.689 MPa (100 psig). Dawsonite and calcite formation were predicted to be the dominant products of bauxite/brine mixture carbonation. It is demonstrated that CO2 sequestration is augmented by adding bauxite residue as a caustic agent to acidic brine solutions and that trapping is accomplished through both mineralization and solubilization. The product mixture solution was, in nearly all mixtures, neutralized following carbonation. However, in samples (bauxite residue/brine mixture of 90/10 by volume) containing bauxite residue solids, the pH was observed to gradually increase to as high as 9.7 after aging for 33 days, suggesting that the CO2 sequestration capacity of the samples increases with aging. Our geochemical models generally predicted the experimental results of carbon sequestration capacities and solution pH.

  10. Fresh Water Generation from Aquifer-Pressured Carbon Storage: Interim Progress Report

    SciTech Connect (OSTI)

    Aines, R D; Wolery, T J; Hao, Y; Bourcier, W L

    2009-07-22

    This project is establishing the potential for using brine pressurized by Carbon Capture and Storage (CCS) operations in saline formations as the feedstock for desalination and water treatment technologies including nanofiltration (NF) and reverse osmosis (RO). The aquifer pressure resulting from the energy required to inject the carbon dioxide provides all or part of the inlet pressure for the desalination system. Residual brine would be reinjected into the formation at net volume reduction. This process provides additional storage space (capacity) in the aquifer, reduces operational risks by relieving overpressure in the aquifer, and provides a source of low-cost fresh water to offset costs or operational water needs. Computer modeling and laboratory-scale experimentation are being used to examine mineral scaling and osmotic pressure limitations for brines typical of CCS sites. Computer modeling is being used to evaluate processes in the aquifer, including the evolution of the pressure field. This progress report deals mainly with our geochemical modeling of high-salinity brines and covers the first six months of project execution (September, 2008 to March, 2009). Costs and implementation results will be presented in the annual report. The brines typical of sequestration sites can be several times more concentrated than seawater, requiring specialized modeling codes typical of those developed for nuclear waste disposal calculations. The osmotic pressure developed as the brines are concentrated is of particular concern, as are precipitates that can cause fouling of reverse osmosis membranes and other types of membranes (e.g., NF). We have now completed the development associated with tasks (1) and (2) of the work plan. We now have a contract with Perlorica, Inc., to provide support to the cost analysis and nanofiltration evaluation. We have also conducted several preliminary analyses of the pressure effect in the reservoir in order to confirm that reservoir

  11. The composition of Permian seawater

    SciTech Connect (OSTI)

    Horita, J.; Friedman, T.J.; Lazar, B.; Holland, H.D. )

    1991-02-01

    Forty-nine brine inclusions in marine halite from the Ochoan Salado Formation in the Delaware Basin and fifteen inclusions in halite from the Leonardian Wellington Formation in the Kansas Basin were extracted, and their chemical compositions were determined. The brines are of the Na-K-Mg-Cl-SO{sub 4} type; their compositions resemble those of evaporated modern seawater. The values of (m{sub Cl{sup {minus}}} - m{sub Na{sup +}})/m{sub Br{sup {minus}}} and (m{sub Mg{sup 2+}} + ,{sub Ca{sup 2+}} {minus} m{sub SO{sub 4}{sup 2{minus}}} {minus} {1/2}m{sub HCO{sub 3}{sup {minus}}})/m{sub Br{sup {minus}}} of the inclusion brine from the two formations are equal to or slightly higher than those of modern seawater. The original m{sub Na{sup +}}/m{sub Br{sup {minus}}} and m{sub Cl{sup {minus}}}/m{sub Br{sup {minus}}} ratios of the inclusion brines were probably equal to or slightly larger than those of modern seawater. The values of m{sub Mg{sup 2+}}/m{sub Br{sup {minus}}} of the inclusion brines from the Salado Formation are very close to that of modern seawater; the ratios of inclusion brines from the Wellington Formation are very close to that of modern seawater; the ratios of inclusion brines from the Wellington Formation are slightly lower, probably due to the formation of dolomite/magnesite. The m{sub Mg{sup 2+}}/m{sub Br{sup {minus}}} ratio in the initial seawater was probably close to the parent seawater of the Salado brines. The values of (m{sub SO{sub 4}{sup 2{minus}}} {minus} m{sub Ca{sup 2+}} + {1/2}m{sub HCO{sub 3}{sup {minus}}})/m{sub Br{sup {minus}}} of the inclusion brines appear to be reduced by the formation of dolomite/magnesite, and the value of this ratio in Permian seawater was probably similar to that of modern seawater. The m{sub K{sup +}}/m{sub Br{sup -}} ratios of the inclusion brines are variable, but the original ratios are probably close to or slightly larger than that of modern seawater.

  12. Geothermal Progress Monitor 12

    SciTech Connect (OSTI)

    1990-12-01

    Some of the more interesting articles in this GPM are: DOE supporting research on problems at The Geysers; Long-term flow test of Hot Dry Rock system (at Fenton Hill, NM) to begin in Fiscal Year 1992; Significant milestones reached in prediction of behavior of injected fluids; Geopressured power generation experiment yields good results. A number of industry-oriented events and successes are reported, and in that regard it is noteworthy that this report comes near the end of the most active decade of geothermal power development in the U.S. There is a table of all operating U.S. geothermal power projects. The bibliography of research reports at the end of this GPM is useful. (DJE 2005)

  13. Compaction measurements on cores from the Pleasant Bayou wells

    SciTech Connect (OSTI)

    Jogi, P.N.; Gray, K.E.; Ashman, T.R.; Thompson, T.W.; Bebout, D.G.; Bachman, A.L.

    1981-01-01

    Additional measurements of compressibility, compaction coefficients, porosities, permeabilities, and resistivities have been conducted on cores from Pleasant Bayou wells No. 1 and No. 2. All rock parameters show non-linear behavior with changing reservoir or pore pressure, which is of interest in modelling reservoir performance and subsidence. Compressibilities and uniaxial compaction coefficients decline by a factor of 2 to 3 as reservoir pressure declines from geopressured to normal hydrostatic conditions. Porosity reductions are 6 to 8% while permeability reductions are on the order of 10 to 30% over that reservoir pressure range. Measured formation factors were 2 to 4 times log derived values for F. Matrix compressibilities were not insignificant relative to bulk compressibilities.

  14. Environmental impact assessment of abnormal events: a follow-up study

    SciTech Connect (OSTI)

    Hunsaker, D.B. Jr.; Lee, D.W.

    1985-01-01

    Impact analyses included in environmental assessments for a selected nuclear power plant, petroleum storage facility, crude oil pipeline, and geopressure well that have experienced operational, abnormal events are compared with the data quantifying the environmental impacts of the events. Comparisons of predicted vs actual impacts suggests that prediction of the types of events and associated impacts could be improved; in some instances, impacts have been underestimated. Analysis of abnormal events is especially important in environmental assessment documents addressing a technology that is novel or unique to a particular area. Incorporation of abnormal event impact analysis into project environmental monitoring and emergency response plans can help improve these plans and can help reduce the magnitude of environmental impacts resulting from said events.

  15. Five year research plan, 1988--1992: Energy from the earth: Geothermal energy program

    SciTech Connect (OSTI)

    Not Available

    1988-10-01

    Consistent with national energy policy guidance, the plan concentrates on research and development (R and D) and limits system experiments to only those necessary to stimulate industrial confidence in the validity of research findings. A key strategy element is the continuation of the government/industry partnership which is critical to successful development of geothermal technology. The primary near-term research emphasis is the extension of hydrothermal technology options for reservoir identification, reservoir analysis, hard rock penetration, and flash and binary electric plants. The advanced geothermal resources--geopressured, hot dry rock, and magma--are longer-term and higher-risk focal points, and research in these areas centers on establishing a technology base that will allow industry to make prudent and timely investment decisions with respect to the use of these resources. 13 figs.

  16. Geothermal Power and Interconnection: The Economics of Getting to Market

    SciTech Connect (OSTI)

    Hurlbut, D.

    2012-04-01

    This report provides a baseline description of the transmission issues affecting geothermal technologies. The report begins with a comprehensive overview of the grid, how it is planned, how it is used, and how it is paid for. The report then overlays onto this 'big picture' three types of geothermal technologies: conventional hydrothermal systems; emerging technologies such as enhanced engineered geothermal systems (EGS) and geopressured geothermal; and geothermal co-production with existing oil and gas wells. Each category of geothermal technology has its own set of interconnection issues, and these are examined separately for each. The report draws conclusions about each technology's market affinities as defined by factors related to transmission and distribution infrastructure. It finishes with an assessment of selected markets with known geothermal potential, identifying those that offer the best prospects for near-term commercial development and for demonstration projects.

  17. Geochemistry of oil from Santa Cruz basin, Bolivia: case study of migration-fractionation

    SciTech Connect (OSTI)

    Illich, H.A.; Haney, F.R.; Mendoza, M.

    1981-11-01

    Geochemical studies provide important data relevant to the origin of the oils in the Santa Cruz basin, Bolivia. Production from this basin occurs from rocks of Devonian, Carboniferous, Cretaceous, and Tertiary ages. The productive structures are usually undisturbed by major faulting. The Devonian sediments are composed of sandstones and dark marine shales. The post-Devonian rocks are generally oxidized and probably nonmarine. The Tertiary and Cretaceous reservoirs usually contain the highest API/sup 0/ gravity oils. Comparison of geochemical data (N/sub 5/-N/sub 10/ molecular weight range) shows that the oils are very similar; however, systematic compositional trends occur as a function of API/sup 0/ gravity. These trends are interpreted from gross structural group data. Isoparaffins and cycloparaffins increase in relative abundance, while normal paraffins and aromatics decrease with increasing API/sup 0/ gravity. A model is proposed that rationalizes these compositional trends by a mechanism of accommodation in water. The model requires enrichment of hydrocarbons of intermediate solubility, partial exclusion of hydrocarbons of low solubility, and retention in solution of the more soluble hydrocarbons. Processes such as thermal fractionation and biodegradation fail to account satisfactorily for the observed compositional trends. The compositional interrelationships of the oils coupled with the geologic framework suggest that these oils have a common source, most probably the Devonian. Differences between the oils are attributed to fractionation occurring during migration. Exploration risk for areas such as the Santa Cruz basin can be substantially reduced by use of the knowledge derived from petroleum geochemistry.

  18. NATURAL GAS FROM SHALE: Questions and Answers Shale Gas Glossary

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Glossary Acquifer - A single underground geological formation, or group of formations, containing water. Antrim Shale - A shale deposit located in the northern Michigan basin that is a Devonian age rock formation lying at a relatively shallow depth of 1,000 feet. Gas has been produced from this formation for several decades primarily via vertical, rather than horizontal, wells. The Energy Information Administration (EIA) estimates the technically recoverable Antrim shale resource at 20 trillion

  19. Aquifer Characteristics Data Report for the Weldon Spring Site chemical plant/raffinate pits and vicinity properties for the Weldon Spring Site Remedial Action Project, Weldon Spring, Missouri

    SciTech Connect (OSTI)

    Not Available

    1990-11-01

    This report describes the procedures and methods used, and presents the results of physical testing performed, to characterize the hydraulic properties of the shallow Mississippian-Devonian aquifer beneath the Weldon Spring chemical plant, raffinate pits, and vicinity properties. The aquifer of concern is composed of saturated rocks of the Burlington-Keokuk Limestone which constitutes the upper portion of the Mississippian-Devonian aquifer. This aquifer is a heterogeneous anisotropic medium which can be described in terms of diffuse Darcian flow overlain by high porosity discrete flow zones and conduits. Average hydraulic conductivity for all wells tested is 9.6E-02 meters/day (3.1E-01 feet/day). High hydraulic conductivity values are representative of discrete flow in the fractured and weathered zones in the upper Burlington-Keokuk Limestone. They indicate heterogeneities within the Mississippian-Devonian aquifer. Aquifer heterogeneity in the horizontal plane is believed to be randomly distributed and is a function of fracture spacing, solution voids, and preglacial weathering phenomena. Relatively high hydraulic conductivities in deeper portions of the aquifer are though to be due to the presence of widely spaced fractures. 44 refs., 27 figs., 9 tabs.

  20. The oil and gas potential of southern Bolivia: Contributions from a dual source rock system

    SciTech Connect (OSTI)

    Hartshorn, K.G.

    1996-08-01

    The southern Sub-Andean and Chaco basins of Bolivia produce oil, gas and condensate from reservoirs ranging from Devonian to Tertiary in age. Geochemical evidence points to contributions from two Paleozoic source rocks: the Devonian Los Monos Formation and the Silurian Kirusillas Formation. Rock-Eval pyrolysis, biomarker data, microscopic kerogen analysis, and burial history modeling are used to assess the quality, distribution, and maturity of both source rock systems. The geochemical results are then integrated with the structural model for the area in order to determine the most likely pathways for migration of oil and gas in the thrust belt and its foreland. Geochemical analysis and modeling show that the primary source rock, shales of the Devonian Los Monos Formation, entered the oil window during the initial phase of thrusting in the sub-Andean belt. This provides ideal timing for oil accumulation in younger reservoirs of the thrust belt. The secondary source rock, although richer, consumed most of its oil generating capacity prior to the development of the thrust related structures. Depending on burial depth and location, however, the Silurian source still contributes gas, and some oil, to traps in the region.

  1. Two-phase convective CO2 dissolution in saline aquifers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Martinez, Mario J.; Hesse, Marc A.

    2016-01-01

    Geologic carbon storage in deep saline aquifers is a promising technology for reducing anthropogenic emissions into the atmosphere. Dissolution of injected CO2 into resident brines is one of the primary trapping mechanisms generally considered necessary to provide long-term storage security. Given that diffusion of CO2 in brine is woefully slow, convective dissolution, driven by a small increase in brine density with CO2 saturation, is considered to be the primary mechanism of dissolution trapping. Previous studies of convective dissolution have typically only considered the convective process in the single-phase region below the capillary transition zone and have either ignored the overlyingmore » two-phase region where dissolution actually takes place or replaced it with a virtual region with reduced or enhanced constant permeability. Our objective is to improve estimates of the long-term dissolution flux of CO2 into brine by including the capillary transition zone in two-phase model simulations. In the fully two-phase model, there is a capillary transition zone above the brine-saturated region over which the brine saturation decreases with increasing elevation. Our two-phase simulations show that the dissolution flux obtained by assuming a brine-saturated, single-phase porous region with a closed upper boundary is recovered in the limit of vanishing entry pressure and capillary transition zone. For typical finite entry pressures and capillary transition zone, however, convection currents penetrate into the two-phase region. As a result, this removes the mass transfer limitation of the diffusive boundary layer and enhances the convective dissolution flux of CO2 more than 3 times above the rate assuming single-phase conditions.« less

  2. Two-phase convective CO2 dissolution in saline aquifers

    SciTech Connect (OSTI)

    Martinez, Mario J.; Hesse, Marc A.

    2016-01-01

    Geologic carbon storage in deep saline aquifers is a promising technology for reducing anthropogenic emissions into the atmosphere. Dissolution of injected CO2 into resident brines is one of the primary trapping mechanisms generally considered necessary to provide long-term storage security. Given that diffusion of CO2 in brine is woefully slow, convective dissolution, driven by a small increase in brine density with CO2 saturation, is considered to be the primary mechanism of dissolution trapping. Previous studies of convective dissolution have typically only considered the convective process in the single-phase region below the capillary transition zone and have either ignored the overlying two-phase region where dissolution actually takes place or replaced it with a virtual region with reduced or enhanced constant permeability. Our objective is to improve estimates of the long-term dissolution flux of CO2 into brine by including the capillary transition zone in two-phase model simulations. In the fully two-phase model, there is a capillary transition zone above the brine-saturated region over which the brine saturation decreases with increasing elevation. Our two-phase simulations show that the dissolution flux obtained by assuming a brine-saturated, single-phase porous region with a closed upper boundary is recovered in the limit of vanishing entry pressure and capillary transition zone. For typical finite entry pressures and capillary transition zone, however, convection currents penetrate into the two-phase region. As a result, this removes the mass transfer limitation of the diffusive boundary layer and enhances the convective dissolution flux of CO2 more than 3 times above the rate assuming single-phase conditions.

  3. The geochemistry of formation waters in the Molasse basin of upper Austria

    SciTech Connect (OSTI)

    Andrews, J.N.; Youngman, M.J. ); Goldbrunner, J.E. ); Darling, W.G. )

    1987-01-01

    The geochemistry of formation waters in the Molasse basin of Upper Austria has been investigated to ascertain the extent of meteoric water replacement of the connate interstitial fluids in these sediments. The chemistry, isotopic composition, and dissolved gas contents of the groundwaters and of oil and gas associated brines have been determined. The most superficial sediments of the basin, the Innviertel (Miocene), have been completely flushed by meteoric waters within the last 200 ka. The underlying Hall and Puchkirchen formations (Miocene/Oligocene) form gas reservoirs for biogenic methane, and the associated formation water are chemically and isotopically modified connate brines of the original marine deposition. In the northeastern part of the basin, the connate brines of the deeper sediments (Cretaceous/Jurassic) have been partially or completely replaced by meteoric waters, whereas in the south of the basin these sediments contain high salinity fluids which are substantially of connate origin. These conclusions are supported by the stable isotope composition of the various brines. Oil-associated brines from the Eocene sediments contain large amounts of dissolved radiogenic {sup 40}Ar, which suggests that the oils have migrated from high-temperature environments. The overall geochemical situation confirms the existence of separate hydraulic systems with little interconnection in the several overlying geological horizons.

  4. Effect of water in salt repositories. Final report

    SciTech Connect (OSTI)

    Baes, C.F. Jr.; Gilpatrick, L.O.; Kitts, F.G.; Bronstein, H.R.; Shor, A.J.

    1983-09-01

    Additional results confirm that during most of the consolidation of polycrystalline salt in brine, the previously proposed rate expression applies. The final consolidation, however, proceeds at a lower rate than predicted. The presence of clay hastens the consolidation process but does not greatly affect the previously observed relationship between permeability and void fraction. Studies of the migration of brine within polycrystalline salt specimens under stress indicate that the principal effect is the exclusion of brine as a result of consolidation, a process that evidently can proceed to completion. No clear effect of a temperature gradient could be identified. A previously reported linear increase with time of the reciprocal permeability of salt-crystal interfaces to brine was confirmed, though the rate of increase appears more nearly proportional to the product of sigma ..delta..P rather than sigma ..delta..P/sup 2/ (sigma is the uniaxial stress normal to the interface and ..delta..P is the hydraulic pressure drop). The new results suggest that a limiting permeability may be reached. A model for the permeability of salt-crystal interfaces to brine is developed that is reasonably consistent with the present results and may be used to predict the permeability of bedded salt. More measurements are needed, however, to choose between two limiting forms of the model.

  5. Cerro Prieto cold water injection: effects on nearby production wells

    SciTech Connect (OSTI)

    Truesdell, A.H.; Lippmann, M.J.; De Leon, J.; Rodriguez, M.H.

    1999-07-01

    The liquid-dominated Cerro Prieto geothermal field of northern Baja California, Mexico has been under commercial exploitation since 1973. During the early years of operation, all waste brines were sent to an evaporation pond built west of the production area. In 1989, cooled pond brines began to be successfully injected into the reservoir along the western boundary of the geothermal system. The injection rate varied over the years, and is at present about 20% of the total fluid extracted. As expected under the continental desert conditions prevailing in the area, the temperature and salinity of the pond brines change with the seasons, being higher during the summer and lower during the winter. The chemistry of pond brines is also affected by precipitation of silica, oxidation of H{sub 2}S and reaction with airborne clays. Several production wells in the western part of the field (CP-I area) showed beneficial effects from injection. The chemical (chloride, isotopic) and physical (enthalpy, flow rate) changes observed in producers close to the injectors are reviewed. Some wells showed steam flow increases, in others steam flow decline rates flattened. Because of their higher density, injected brines migrated downward in the reservoir and showed up in deep wells.

  6. Salinity, temperature, oil composition, and oil recovery by waterflooding

    SciTech Connect (OSTI)

    Tang, G.Q.; Morrow, N.R.

    1997-11-01

    The effect of aging and displacement temperatures and brine and oil composition on wettability and the recovery of crude oil by spontaneous imbibition and waterflooding has been investigated. This study is based on displacement tests in Berea sandstone with three crude oils and three reservoir brines (RB`s). Salinity was varied by changing the concentration of total dissolved solids (TDS`s) of the synthetic brine in proportion. Salinity of the connate and invading brines can have a major influence on wettability and oil recovery at reservoir temperature. Oil recovery increased over that for the RB with dilution of both the initial (connate) and invading brine or dilution of either. Aging and displacement temperatures were varied independently. For all crude oils, water wetness and oil recovery increased with increase in displacement temperature. Removal of light components from the crude oil resulted in increased water wetness. Addition of alkanes to the crude oil reduced the water wetness, and increased oil recovery. Relationships between waterflood recovery and rate and extent of oil recovery by spontaneous imbibition are summarized.

  7. Overfilling of cavern blamed for LPG blasts

    SciTech Connect (OSTI)

    Not Available

    1992-07-06

    Three explosions and a fire Apr. 7 at an LPG salt dome storage cavern near Brenham, Tex., were triggered when the cavern was overfilled, the Texas Railroad Commission (TRC) has reported. This paper reports that a TRC investigation found that LPG escaped to the surface at the Brenham site through brine injection tubing after excessive fill from an LPG line forced the cavern's water level below the brine tubing's bottom. At the surface, LPG was released into a brine storage pit where it turned into a dense, explosive vapor. At 7:08 a.m., the vapor was ignited by an unknown source. The resulting blast killed three persons and injured 19 and brought operations at the site to a halt.

  8. Research project on CO2 geological storage and groundwaterresources: Large-scale hydrological evaluation and modeling of impact ongroundwater systems

    SciTech Connect (OSTI)

    Birkholzer, Jens; Zhou, Quanlin; Rutqvist, Jonny; Jordan,Preston; Zhang,K.; Tsang, Chin-Fu

    2007-10-24

    If carbon dioxide capture and storage (CCS) technologies areimplemented on a large scale, the amounts of CO2 injected and sequesteredunderground could be extremely large. The stored CO2 then replaces largevolumes of native brine, which can cause considerable pressureperturbation and brine migration in the deep saline formations. Ifhydraulically communicating, either directly via updipping formations orthrough interlayer pathways such as faults or imperfect seals, theseperturbations may impact shallow groundwater or even surface waterresources used for domestic or commercial water supply. Possibleenvironmental concerns include changes in pressure and water table,changes in discharge and recharge zones, as well as changes in waterquality. In compartmentalized formations, issues related to large-scalepressure buildup and brine displacement may also cause storage capacityproblems, because significant pressure buildup can be produced. Toaddress these issues, a three-year research project was initiated inOctober 2006, the first part of which is summarized in this annualreport.

  9. Electrodialysis technology for salt recovery from aluminum salt cake

    SciTech Connect (OSTI)

    Hryn, J. N.; Krumdick, G.; Graziano, D.; Sreenivasarao, K.

    2000-02-02

    Electrodialysis technology for recovering salt from aluminum salt cake is being developed at Argonne National Laboratory. Salt cake, a slag-like aluminum-industry waste stream, contains aluminum metal, salt (NaCl and KCl), and nonmetallics (primarily aluminum oxide). Salt cake can be recycled by digesting with water and filtering to recover the metal and oxide values. A major obstacle to widespread salt cake recycling is the cost of recovering salt from the process brine. Electrodialysis technology developed at Argonne appears to be a cost-effective approach to handling the salt brines, compared to evaporation or disposal. In Argonne's technology, the salt brine is concentrated until salt crystals are precipitated in the electrodialysis stack; the crystals are recovered downstream. The technology is being evaluated on the pilot scale using Eurodia's EUR 40-76-5 stack.

  10. Sensitivity of CO2 migration estimation on reservoir temperature and pressure uncertainty

    SciTech Connect (OSTI)

    Jordan, Preston; Doughty, Christine

    2008-11-01

    The density and viscosity of supercritical CO{sub 2} are sensitive to pressure and temperature (PT) while the viscosity of brine is sensitive primarily to temperature. Oil field PT data in the vicinity of WESTCARB's Phase III injection pilot test site in the southern San Joaquin Valley, California, show a range of PT values, indicating either PT uncertainty or variability. Numerical simulation results across the range of likely PT indicate brine viscosity variation causes virtually no difference in plume evolution and final size, but CO{sub 2} density variation causes a large difference. Relative ultimate plume size is almost directly proportional to the relative difference in brine and CO{sub 2} density (buoyancy flow). The majority of the difference in plume size occurs during and shortly after the cessation of injection.

  11. Sequestration of CO2 in Mixtures of Bauxite Residue and Saline Wastewater

    SciTech Connect (OSTI)

    Dilmore, Robert; Lu, Peng; Allen, Douglas; Soong, Yee; Hedges, Sheila; Fu, Jaw K.; Dobbs, Charles L.; Degalbo, Angelo; Zhu, Chen

    2008-01-01

    Experiments were conducted to explore the concept of beneficially utilizing mixtures of caustic bauxite residue slurry (pH 13) and produced oil-field brine to sequester carbon dioxide from flue gas generated from industrial point sources. Data presented herein provide a preliminary assessment of the overall feasibility of this treatment concept. The Carbonation capacity of bauxite residue/brine mixtures was considered over the full range of reactant mixture combinations in 10% increments by volume. A bauxite residue/brine mixture of 90/10 by volume exhibited a CO2 sequestration capacity of greater than 9.5 g/L when exposed to pure CO2 at 20 C and 0.689 MPa (100 psig). Dawsonite and calcite formation were predicted to be the dominant products of bauxite/brine mixture carbonation. It is demonstrated that CO2 sequestration is augmented by adding bauxite residue as a caustic agent to acidic brine solutions and that trapping is accomplished through both mineralization and solubilization. The product mixture solution was, in nearly all mixtures, neutralized following carbonation. However, in samples (bauxite residue/brine mixture of 90/10 by volume) containing bauxite residue solids, the pH was observed to gradually increase to as high as 9.7 after aging for 33 days, suggesting that the CO2 sequestration capacity of the samples increases with aging. Our geochemical models generally predicted the experimental results of carbon sequestration capacities and solution pH.

  12. A method for quick assessment of CO2 storage capacity in closedand semi-closed saline formations

    SciTech Connect (OSTI)

    Zhou, Q.; Birkholzer, J.; Tsang, C.F.; Rutqvist, J.

    2008-02-10

    Saline aquifers of high permeability bounded by overlying/underlying seals may be surrounded laterally by low-permeability zones, possibly caused by natural heterogeneity and/or faulting. Carbon dioxide (CO{sub 2}) injection into and storage in such 'closed' systems with impervious seals, or 'semi-closed' systems with nonideal (low-permeability) seals, is different from that in 'open' systems, from which the displaced brine can easily escape laterally. In closed or semi-closed systems, the pressure buildup caused by continuous industrial-scale CO{sub 2} injection may have a limiting effect on CO{sub 2} storage capacity, because geomechanical damage caused by overpressure needs to be avoided. In this research, a simple analytical method was developed for the quick assessment of the CO{sub 2} storage capacity in such closed and semi-closed systems. This quick-assessment method is based on the fact that native brine (of an equivalent volume) displaced by the cumulative injected CO{sub 2} occupies additional pore volume within the storage formation and the seals, provided by pore and brine compressibility in response to pressure buildup. With nonideal seals, brine may also leak through the seals into overlying/underlying formations. The quick-assessment method calculates these brine displacement contributions in response to an estimated average pressure buildup in the storage reservoir. The CO{sub 2} storage capacity and the transient domain-averaged pressure buildup estimated through the quick-assessment method were compared with the 'true' values obtained using detailed numerical simulations of CO{sub 2} and brine transport in a two-dimensional radial system. The good agreement indicates that the proposed method can produce reasonable approximations for storage-formation-seal systems of various geometric and hydrogeological properties.

  13. Two-Stage, Integrated, Geothermal-CO2 Storage Reservoirs: An Approach for Sustainable Energy Production, CO2-Sequestration Security, and Reduced Environmental Risk

    SciTech Connect (OSTI)

    Buscheck, T A; Chen, M; Sun, Y; Hao, Y; Elliot, T R

    2012-02-02

    We introduce a hybrid two-stage energy-recovery approach to sequester CO{sub 2} and produce geothermal energy at low environmental risk and low cost by integrating geothermal production with CO{sub 2} capture and sequestration (CCS) in saline, sedimentary formations. Our approach combines the benefits of the approach proposed by Buscheck et al. (2011b), which uses brine as the working fluid, with those of the approach first suggested by Brown (2000) and analyzed by Pruess (2006), using CO{sub 2} as the working fluid, and then extended to saline-formation CCS by Randolph and Saar (2011a). During stage one of our hybrid approach, formation brine, which is extracted to provide pressure relief for CO{sub 2} injection, is the working fluid for energy recovery. Produced brine is applied to a consumptive beneficial use: feedstock for fresh water production through desalination, saline cooling water, or make-up water to be injected into a neighboring reservoir operation, such as in Enhanced Geothermal Systems (EGS), where there is often a shortage of a working fluid. For stage one, it is important to find economically feasible disposition options to reduce the volume of brine requiring reinjection in the integrated geothermal-CCS reservoir (Buscheck et al. 2012a). During stage two, which begins as CO{sub 2} reaches the production wells; coproduced brine and CO{sub 2} are the working fluids. We present preliminary reservoir engineering analyses of this approach, using a simple conceptual model of a homogeneous, permeable CO{sub 2} storage formation/geothermal reservoir, bounded by relatively impermeable sealing units. We assess both the CO{sub 2} sequestration capacity and geothermal energy production potential as a function of well spacing between CO{sub 2} injectors and brine/CO{sub 2} producers for various well patterns and for a range of subsurface conditions.

  14. Final report on Weeks Island Monitoring Phase : 1999 through 2004.

    SciTech Connect (OSTI)

    Ehgartner, Brian L.; Munson, Darrell Eugene

    2005-05-01

    This Final Report on the Monitoring Phase of the former Weeks Island Strategic Petroleum Reserve crude oil storage facility details the results of five years of monitoring of various surface accessible quantities at the decommissioned facility. The Weeks Island mine was authorized by the State of Louisiana as a Strategic Petroleum Reserve oil storage facility from 1979 until decommissioning of the facility in 1999. Discovery of a sinkhole over the facility in 1992 with freshwater inflow to the facility threatened the integrity of the oil storage and led to the decision to remove the oil, fill the chambers with brine, and decommission the facility. Thereafter, a monitoring phase, by agreement between the Department of Energy and the State, addressed facility stability and environmental concerns. Monitoring of the surface ground water and the brine of the underground chambers from the East Fill Hole produced no evidence of hydrocarbon contamination, which suggests that any unrecovered oil remaining in the underground chambers has been contained. Ever diminishing progression of the initial major sinkhole, and a subsequent minor sinkhole, with time was verification of the response of sinkholes to filling of the facility with brine. Brine filling of the facility ostensively eliminates any further growth or new formation from freshwater inflow. Continued monitoring of sinkhole response, together with continued surface surveillance for environmental problems, confirmed the intended results of brine pressurization. Surface subsidence measurements over the mine continued throughout the monitoring phase. And finally, the outward flow of brine was monitored as a measure of the creep closure of the mine chambers. Results of each of these monitoring activities are presented, with their correlation toward assuring the stability and environmental security of the decommissioned facility. The results suggest that the decommissioning was successful and no contamination of the

  15. Origin of fluids and the evolution of the Atlantis II deep hydrothermal system, Red Sea: Strontium isotope study

    SciTech Connect (OSTI)

    Anschutz, P.; Blanc, G.; Stille, P.

    1995-12-31

    Atlantis II is the largest and most mineralized of the deeps along the axis of the Red Sea spreading center. Its basaltic substratum is covered by recent layered metalliferous sediments, which precipitated from an overlying brine pool. The {sup 87}Sr/{sup 86}Sr ratio and the strontium concentration of interstitial waters within these sediments range between 0.70708 and 0.70725 and between 43 and 53 ppm, respectively. They are close to what is found for the present-day deep brine pool (0.707105, 45.10 ppm). The strontium concentration and the {sup 87}Sr/{sup 86}Sr ratio of the Atlantis II Deep brines can be derived from those of the interstitial waters of the surrounding Miocene evaporite by hydrothermal interaction with oceanic basaltic rocks at a maximal water/rock ratio 2-3. This water/rock ratio is similar to that calculated for oceanic hydrothermal systems on sediment-free ridges. Interstitial waters show a linear trend on plot of {sup 87}Sr/{sup 86}Sr vs. 1/Sr. The highest strontium concentration and the most radiogenic interstitial waters correspond to sediment samples enriched in iron and manganese oxide minerals. These waters reflect the diagenetic release of strontium by oxide minerals and initially precipitated at the interface between the brine pool and more radiogenic seawater. The solid fraction of the sediment has {sup 87}sr{sup 86}Sr isotopic compositions intermediate to those of the brines and seawater. The solid fraction of the sediment has {sup 87}Sr/{sup 86}Sr isotopic compositions intermediate to those of the brines and seawater. The most radiogenic strontium values were observed in samples strongly enriched in marine microbiota. The gradual isotopic evolution in the lowest part of the western basin sediments testifies to the gradual influence of the hydrothermal activity in the deep in the beginning of the Atlantis II Deep sedimentary history. 62 refs., 6 figs., 2 tabs.

  16. Sequestration of CO2 in Mixtures of Bauxite Residue and Saline Wastewater

    SciTech Connect (OSTI)

    Dilmore, Robert; Lu, Peng; Allen, Douglas; Soong, Yee; Hedges, Sheila; Fu, Jaw K.; Dobbs, Charles L.; Degalbo, Angelo; Zhu, Chen

    2008-01-01

    Experiments were conducted to explore the concept of beneficially utilizing mixtures of caustic bauxite residue slurry (pH 13) and produced oil-field brine to sequester carbon dioxide from flue gas generated from industrial point sources. Data presented herein provide a preliminary assessment of the overall feasibility of this treatment concept. The Carbonation capacity of bauxite residue/brine mixtures was considered over the full range of reactant mixture combinations in 10% increments by volume. A bauxite residue/brine mixture of 90/10 by volume exhibited a CO2 sequestration capacity of greater than 9.5 g/L when exposed to pure CO2 at 20º C and 0.689 MPa (100 psig). Dawsonite and calcite formation were predicted to be the dominant products of bauxite/brine mixture carbonation. It is demonstrated that CO2 sequestration is augmented by adding bauxite residue as a caustic agent to acidic brine solutions and that trapping is accomplished through both mineralization and solubilization. The product mixture solution was, in nearly all mixtures, neutralized following carbonation. However, in samples (bauxite residue/brine mixture of 90/10 by volume) containing bauxite residue solids, the pH was observed to gradually increase to as high as 9.7 after aging for 33 days, suggesting that the CO2 sequestration capacity of the samples increases with aging. Our geochemical models generally predicted the experimental results of carbon sequestration capacities and solution pH.

  17. Gravity monitoring of CO2 movement during sequestration: Model studies

    SciTech Connect (OSTI)

    Gasperikova, E.; Hoversten, G.M.

    2008-07-15

    We examine the relative merits of gravity measurements as a monitoring tool for geological CO{sub 2} sequestration in three different modeling scenarios. The first is a combined CO{sub 2} enhanced oil recovery (EOR) and sequestration in a producing oil field, the second is sequestration in a brine formation, and the third is for a coalbed methane formation. EOR/sequestration petroleum reservoirs have relatively thin injection intervals with multiple fluid components (oil, hydrocarbon gas, brine, and CO{sub 2}), whereas brine formations usually have much thicker injection intervals and only two components (brine and CO{sub 2}). Coal formations undergoing methane extraction tend to be thin (3-10 m), but shallow compared to either EOR or brine formations. The injection of CO{sub 2} into the oil reservoir produced a bulk density decrease in the reservoir. The spatial pattern of the change in the vertical component of gravity (G{sub z}) is directly correlated with the net change in reservoir density. Furthermore, time-lapse changes in the borehole G{sub z} clearly identified the vertical section of the reservoir where fluid saturations are changing. The CO{sub 2}-brine front, on the order of 1 km within a 20 m thick brine formation at 1900 m depth, with 30% CO{sub 2} and 70% brine saturations, respectively, produced a -10 Gal surface gravity anomaly. Such anomaly would be detectable in the field. The amount of CO{sub 2} in a coalbed methane test scenario did not produce a large enough surface gravity response; however, we would expect that for an industrial size injection, the surface gravity response would be measurable. Gravity inversions in all three scenarios illustrated that the general position of density changes caused by CO{sub 2} can be recovered, but not the absolute value of the change. Analysis of the spatial resolution and detectability limits shows that gravity measurements could, under certain circumstances, be used as a lower-cost alternative to seismic

  18. Scale Resistant Heat Exchanger for Low Temperature Geothermal Binary Cycle Power Plant

    SciTech Connect (OSTI)

    Hays, Lance G.

    2014-11-18

    Phase 1 of the investigation of improvements to low temperature geothermal power systems was completed. The improvements considered were reduction of scaling in heat exchangers and a hermetic turbine generator (eliminating seals, seal system, gearbox, and lube oil system). A scaling test system with several experiments was designed and operated at Coso geothermal resource with brine having a high scaling potential. Several methods were investigated at the brine temperature of 235 ºF. One method, circulation of abradable balls through the brine passages, was found to substantially reduce scale deposits. The test heat exchanger was operated with brine outlet temperatures as low as 125 ºF, which enables increased heat input available to power conversion systems. For advanced low temperature cycles, such as the Variable Phase Cycle (VPC) or Kalina Cycle, the lower brine temperature will result in a 20-30% increase in power production from low temperature resources. A preliminary design of an abradable ball system (ABS) was done for the heat exchanger of the 1 megawatt VPC system at Coso resource. The ABS will be installed and demonstrated in Phase 2 of this project, increasing the power production above that possible with the present 175 ºF brine outlet limit. A hermetic turbine generator (TGH) was designed and manufacturing drawings produced. This unit will use the working fluid (R134a) to lubricate the bearings and cool the generator. The 200 kW turbine directly drives the generator, eliminating a gearbox and lube oil system. Elimination of external seals eliminates the potential of leakage of the refrigerant or hydrocarbon working fluids, resulting in environmental improvement. A similar design has been demonstrated by Energent in an ORC waste heat recovery system. The existing VPC power plant at Coso was modified to enable the “piggyback” demonstration of the TGH. The existing heat exchanger, pumps, and condenser will be operated to provide the required

  19. Removal of Radionuclides from Waste Water at Fukushima Daiichi Nuclear Power Plant: Desalination and Adsorption Methods - 13126

    SciTech Connect (OSTI)

    Kani, Yuko; Kamosida, Mamoru; Watanabe, Daisuke; Asano, Takashi; Tamata, Shin

    2013-07-01

    Waste water containing high levels of radionuclides due to the Fukushima Daiichi Nuclear Power Plant accident, has been treated by the adsorption removal and reverse-osmosis (RO) desalination to allow water re-use for cooling the reactors. Radionuclides in the waste water are collected in the adsorbent medium and the RO concentrate (RO brine) in the water treatment system currently operated at the Fukushima Daiichi site. In this paper, we have studied the behavior of radionuclides in the presently applied RO desalination system and the removal of radionuclides in possible additional adsorption systems for the Fukushima Daiichi waste water treatment. Regarding the RO desalination system, decontamination factors (DFs) of the elements present in the waste water were obtained by lab-scale testing using an RO unit and simulated waste water with non-radioactive elements. The results of the lab-scale testing using representative elements showed that the DF for each element depended on its hydrated ionic radius: the larger the hydrated ionic radius of the element, the higher its DF is. Thus, the DF of each element in the waste water could be estimated based on its hydrated ionic radius. For the adsorption system to remove radionuclides more effectively, we studied adsorption behavior of typical elements, such as radioactive cesium and strontium, by various kinds of adsorbents using batch and column testing. We used batch testing to measure distribution coefficients (K{sub d}s) for cesium and strontium onto adsorbents under different brine concentrations that simulated waste water conditions at the Fukushima Daiichi site. For cesium adsorbents, K{sub d}s with different dependency on the brine concentration were observed based on the mechanism of cesium adsorption. As for strontium, K{sub d}s decreased as the brine concentration increased for any adsorbents which adsorbed strontium by intercalation and by ion exchange. The adsorbent titanium oxide had higher K{sub d}s and it

  20. Colloid formation study of U, Th, Ra, Pb, Po, Sr, Rb, and Cs in briny (high ionic strength) groundwaters

    SciTech Connect (OSTI)

    Maiti, T.C.; Smith, M.R.; Laul, J.C.

    1989-01-01

    Colloid formation of uranium, thorium, radium, lead, polonium, strontium, rubidium, and cesium in briny (high ionic strength) groundwaters is studied to predict their capability as vectors for transporting radionuclides. This knowledge is essential in developing models to infer the transport of radionuclides from the source region to the surrounding environment. Except polonium, based on the experimental results, colloid formation of uranium, thorium, radium, lead, strontium, rubidium, and cesium is unlikely in brines with compositions similar to the synthetic Palo Duro Basin brine. This observation of no colloid formation is explained by electrokinetic theory and inorganic solution chemistry.

  1. Episodic potassic alteration of Ordovician tuffs in the Upper Mississippi Valley

    SciTech Connect (OSTI)

    Lee, M.; Hay, R.L.; Kolata, D.R.

    1985-01-01

    Tuffs of middle and late Ordovician age are altered to mixed-layer illite-smectite (I/S) and to K-feldspar in the Upper Mississippi Valley in northeast Iowa, southeast Minnesota, and southwest Wisconsin. Some and perhaps much of the I/S replaces previously feldspathized tuff, as shown by field and petrographic relationships. Samples for K-Ar dating were collected over a 200 km southeast-northwest traverse. Dates from authigenic K-feldspar are early Devonian and range from 397 +/- 13 to 406 +/- 18, averaging 400 m.y. in three samples, including a middle Ordovician tuff in Iowa and Minnesota and a late Ordovician tuff in Minnesota. Ages of illite layers in I/S are late Devonian and early Mississippian and range from 356 +/- 16 to 371 +/- 17, averaging 366 m.y. in 5 samples including 4 from two middle Ordovician tuffs in Minnesota and Iowa and the late Ordovician tuff in Minnesota. Oxygen-isotopic composition of the K-feldspar and I/S shows that the two minerals crystallized under different conditions and probably reflect introduction of waters of varying chemistry and temperature. K-feldspar very likely crystallized under higher temperatures and possibly lower salinity than the I/S. Introduction of these pore waters may have been caused by groundwater movements resulting from recharge in distal areas undergoing tectonic uplift. K-feldspar alteration was concurrent with early Devonian uplift on the Northeast Missouri Arch and possibly the Transcontinental Arch. Age of the illite layers corresponds to movements on the Sangamon Arch and possibly the Wisconsin Arch.

  2. Petroleum potential of lower and middle Paleozoic rocks in Nebraska portion of Mid-Continent

    SciTech Connect (OSTI)

    Carlson, M.P. )

    1989-08-01

    Central North America during the Paleozoic was characterized by northern (Williston) and southern (Anadarko) depositional regimes separated by a stable Transcontinental arch. Nebraska lies on the southern flank of this arch and contains the northern zero edges of the lower and middle Paleozoic rocks of the southern regime. Most of these rocks are secondary dolomites with zones of excellent intercrystalline porosity. The Reagan-LaMotte Sandstones and the overlying Arbuckle dolomites are overlapped by Middle Ordovician rocks toward the Transcontinental arch. Rocks equivalent to the Simpson consist of a basal sand (St. Peter) and overlying interbedded gray-green shales and dolomitic limestones. An uppermost shale facies is present in the Upper Ordovician (Viola-Maquoketa) eastward and southward across Nebraska. The dolomite facies extends northward into the Williston basin. The Silurian dolomites, originally more widely deposited, are overlapped by Devonian dolomites in southeastern Nebraska. Upper Devonian rocks exhibit a regional facies change from carbonate to green-gray shale to black shale southeastward across the Mid-Continent. Mississippian carbonates overlap the Devonian westward and northward across the Transcontinental arch. Pennsylvanian uplift and erosion were widespread, producing numerous stratigraphic traps. Sands related to the basal Pennsylvanian unconformity produce along the Cambridge arch. Arbuckle, Simpson, Viola, and Hunton production is present in the Forest City basin and along the Central Kansas uplift. Although source rocks are scarce and the maturation is marginal, current theories of long-distance oil migration encourage exploration in the extensive lower and middle Paleozoic reservoirs in this portion of the Mid-Continent.

  3. High-energy gas-fracturing development. Quarterly report, October-December 1982

    SciTech Connect (OSTI)

    Cuderman, J.F.

    1983-02-01

    The purpose of this study is to develop and optimize the High Energy Gas Fracturing (HEGF) technique to produce multiple fractures around a wellbore in order to stimulate natural-gas production in Devonian shale. The HEGF technique uses a wellbore charge of a propellant tailored to produce pressure loading in the borehole that avoids crushing yet produces multiple fractures radiating from the wellbore. The multiple-fracture regime has been characterized and releated to parameters such as borehole size, pressure risetime, and surface-wave velocity. Pressure risetimes and peak pressures, measured for different propellants in boreholes to specify a propellant for a desired peak pressure and pressure risetime. Semiempirical models, using results from previous experiments, successfully relate stress, acceleration, and fracture radii in surrounding rock to peak pressure and pressure risetime. A finite-element model also has been developed which predicts fracture type and direction of fractures as a function of pressure loading, in situ stress, and material properties. A full-scale HEGF system has been developed for application in gas-well-stimulation experiments in Devonian shale. During this quarter, a proof test of the full-scale HEGF was conducted at the Nevada Test Site (NTS). The designed pressure pulse of 0.5 ms risetime was achieved, and the tamp remained in place during the test. The borehole was successfully cleared posttest. Multiple fracturing was verified with a downhole TV camera. The test of the full-scale hardware and its operational capability was successful. As a result, the HEGF system is ready for application in gas-well-stimulation experiments in Devonian shale. Tests were conducted to determine worst-case accident scenarios to establish sensitivity to shock and fire. There appears to be no risk of initiation resulting from shock or breakage of the propellant-canister segments.

  4. Eastern Gas Shales Project: Pennsylvania No. 4 well, Indiana County. Phase III report, summary of laboratory analyses and mechanical characterization results

    SciTech Connect (OSTI)

    1981-10-01

    This summary presents a detailed characterization of the Devonian Shale occurrence in the EGSP-Pennsylvania No. 4 well. Information provided includes a stratigraphic summary and lithology and fracture analyses resulting from detailed core examinations and geophysical log interpretations at the EGSP Core Laboratory. Plane of weakness orientations stemming from a program of physical properties testing at Michigan Technological University are also summarized; the results of physical properties testing are dealt with in detail in the accompanying report. The data presented was obtained from the study of approximately 891 feet of core retrieved from a well drilled in Indiana County of west-central Pennsylvania.

  5. Eastern Gas Shales Project: Pennsylvania No. 1 well, McKean County. Phase III report, summary of laboratory analyses and mechanical characterization results

    SciTech Connect (OSTI)

    1981-10-01

    This summary presents a detailed characterization of the Devonian Shale occurrence in the EGSP-Pennsylvania No. 1 well. Information provided includes a stratigraphic summary and lithology and fracture analyses resulting from detailed core examinations and geophysical log interpretations at the EGSP Core Laboratory. Plane of weakness orientations stemming from a program of physical properties testing at Michigan Technological University are also summarized; the results of physical properties testing are dealt with in detail in the accompanying report. The data presented was obtained from the study of approximately 741 feet of core retrieved from a well drilled in MeKean County of north-central Pennsylvania.

  6. Cliff Minerals, Inc. Eastern Gas Shales Project, Ohio No. 6 wells - Gallia County. Phase III report. Summary of laboratory analyses and mechanical characterization results

    SciTech Connect (OSTI)

    1981-07-01

    This summary presents a detailed characterization of the Devonian Shale occurrence in the EGSP-Ohio No. 6 wells. Information provided includes a stratigraphic summary and lithology and fracture analyses resulting from detailed core examinations and geophysical log interpretations at the EGSP Core Laboratory. Plane of weakness orientations stemming from a program of physical properties testing at Michigan Technological University are also summarized; the results of physical properties testing are dealt with in detail in the accompanying report. This data presented were obtained from a study of approximately 1522 feet of core retrieved from five wells drilled in Gallia County in southeastern Ohio.

  7. Eastern Gas Shales Project: Michigan No. 2 well, Otsego County. Phase III report, summary of laboratory analyses and mechanical characterization results

    SciTech Connect (OSTI)

    1981-11-01

    This summary presents a detailed characterization of the Devonian Shale occurrence in the EGSP-Michigan No. 2 well. Information provided includes a stratigraphic summary and lithology and fracture analyses resulting from detailed core examinations and geophysical log interpretations at the EGSP Core Laboratory. Plane of weakness orientations stemming from a program of physical properties testing at Michigan Technological University are also summarized; the results of physical properties testing are dealt with in detail in the accompanying report. The data was obtained from the study of approximately 249 feet of core retrived from a well drilled in Otsego County of north-central Michigan (lower peninsula).

  8. Eastern Gas Shales Project: West Virginia No. 7 well, Wetzel County. Phase III report, summary of laboratory analyses and mechanical characterization results

    SciTech Connect (OSTI)

    1981-12-01

    This summary presents a detailed characterization of the Devonian Shale occurrence in the EGSP-West Virginia No. 7 well. Information provided includes a stratigraphic summary and lithiology and fracture analyses resulting from detailed core examinations and geophysical log interpretations at the EGSP Core Laboratory. Plane of weakness orientations stemming from a program of physical properties testing at Michigan Technological University are also summarized; the results of physical properties testing are dealt with in detail in the accompanying report. The data presented was obtained from the study of approximately 533 feet of core retrieved from a well drilled in Wetzel county of north-central West Virginia.

  9. Hunton Group core workshop and field trip

    SciTech Connect (OSTI)

    Johnson, K.S.

    1993-12-31

    The Late Ordovician-Silurian-Devonian Hunton Group is a moderately thick sequence of shallow-marine carbonates deposited on the south edge of the North American craton. This rock unit is a major target for petroleum exploration and reservoir development in the southern Midcontinent. The workshop described here was held to display cores, outcrop samples, and other reservoir-characterization studies of the Hunton Group and equivalent strata throughout the region. A field trip was organized to complement the workshop by allowing examination of excellent outcrops of the Hunton Group of the Arbuckle Mountains.

  10. CX-001190: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    An Integrated Experimental and Numerical Study: Developing a Reaction Transport Model that Couples Chemical Reactions of Mineral Dissolution/Precipitation with Spatial and Temporal Flow Variations in Carbon Dioxide/Brine/Rock SystemsCX(s) Applied: A9, B3.6Date: 03/21/2010Location(s): Minneapolis, MinnesotaOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  11. CX-000459: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Molecular Simulation of Dissolved Inorganic Carbons for Underground Brine Carbon Dioxide SequestrationCX(s) Applied: A9, B3.6Date: 12/07/2009Location(s): Pasadena, CaliforniaOffice(s): Fossil Energy, National Energy Technology Laboratory

  12. SImbol Materials Lithium Extraction Operating Data From Elmore and Featherstone Geothermal Plants

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Stephen Harrison

    2015-07-08

    The data provided in this upload is summary data from its Demonstration Plant operation at the geothermal power production plants in the Imperial Valley. The data provided is averaged data for the Elmore Plant and the Featherstone Plant. Included is both temperature and analytical data (ICP_OES). Provide is the feed to the Simbol Process, post brine treatment and post lithium extraction.

  13. Dixie Valley Binary Cycle Production Data 2013 YTD

    SciTech Connect (OSTI)

    Lee, Vitaly

    2013-10-18

    Proving the technical and economic feasibility of utilizing the available unused heat to generate additional electric power from a binary power plant from the low-temperature brine at the Dixie Valley Geothermal Power Plant. Monthly data for Jan 2013-September 2013

  14. Process for separating dissolved solids from a liquid using an anti-solvent and multiple effect evaporators

    DOE Patents [OSTI]

    Daniels, Edward J.; Jody, Bassam J.; Bonsignore, Patrick V.

    1994-01-01

    A process and system for treating aluminum salt cake containing water soluble halide salts by contacting the salt cake with water to dissolve water soluble halide salts forming a saturated brine solution. Transporting a portion of about 25% of the saturated brine solution to a reactor and introducing into the saturated brine solution at least an equal volume of a water-miscible low-boiling organic material such as acetone to precipitate a portion of the dissolved halide salts forming a three-phase mixture of an aqueous-organic-salt solution phase and a precipitated salt phase and an organic rich phase. The precipitated salt phase is separated from the other phases and the organic rich phase is recycled to the reactor. The remainder of the saturated brine solution is sent to a multiple effect evaporator having a plurality of stages with the last stage thereof producing low grade steam which is used to boil off the organic portion of the solution which is recycled.

  15. Process for separating dissolved solids from a liquid using an anti-solvent and multiple effect evaporators

    DOE Patents [OSTI]

    Daniels, E.J.; Jody, B.J.; Bonsignore, P.V.

    1994-07-19

    A process and system are disclosed for treating aluminum salt cake containing water soluble halide salts by contacting the salt cake with water to dissolve water soluble halide salts forming a saturated brine solution. Transporting a portion of about 25% of the saturated brine solution to a reactor and introducing into the saturated brine solution at least an equal volume of a water-miscible low-boiling organic material such as acetone to precipitate a portion of the dissolved halide salts forming a three-phase mixture of an aqueous-organic-salt solution phase and a precipitated salt phase and an organic rich phase. The precipitated salt phase is separated from the other phases and the organic rich phase is recycled to the reactor. The remainder of the saturated brine solution is sent to a multiple effect evaporator having a plurality of stages with the last stage thereof producing low grade steam which is used to boil off the organic portion of the solution which is recycled. 3 figs.

  16. Extent of water-rock interactions in Lower Permian Wolfcamp carbonates, Palo Duro Basin, Texas

    SciTech Connect (OSTI)

    Fisher, R.S.; Posey, H.H.

    1985-01-01

    A laterally-extensive permeable zone in upper Wolfcampian carbonate strata constitutes the first important transmissive unit below a thick evaporite sequence that is being considered for nuclear waste isolation. The extent of water-rock interaction was evaluated by comparing the chemical and isotopic composition of formation water and core collected at four DOE test wells. Wolfcamp mineralogy is dominantly calcite and dolomite with minor anhydrite at each of the four sites despite minor variations in depositional environment, diagenetic alteration, and abundance of clastic material. Isotopic compositions of calcite and dolomite and of anhydrite are within the ranges expected for Permian marine sediments altered by early diagenesis. Wolfcamp formation water compositions are more variable than host rock compositions, and are not completely controlled by local water-rock equilibria. Wolfcamp brines from two wells in the western part of the basin have depleted isotopic compositions relative to the two eastern wells and have not equilibrated with Wolfcamp carbonates, whereas the eastern fluids have. Strontium in the western samples is more radiogenic than that of the eastern samples, indicating a greater influence of clays or feldspars on the western fluids. Comparison of water and rock compositions suggests: (1) the western brines have interacted less with the carbonate host than the eastern brines due to shorter residence times or greater water: rock ratios, and (2) the minerals encountered along flow paths prior to entering the Wolfcamp are different for the western and eastern Wolfcamp brines.

  17. Code System to Calculate Waste-Isolation Flow and Transport.

    Energy Science and Technology Software Center (OSTI)

    1999-10-18

    Version 00 SWIFT solves the coupled or individual equations governing fluid flow, heat transport, brine displacement, and radionuclide displacement in geologic media. Fluid flow may be transient or steady state. One, two, or three dimensions are available, and transport of radionuclides chains is possible.

  18. An analysis of weep holes as a product detection device for underground compensated LPG storage systems

    SciTech Connect (OSTI)

    Sarica, C.; Demir, H.M.; Brill, J.P.

    1996-09-01

    Weep holes have been used widely to detect the presence of Liquefied Petroleum Gases (LPG) in brine for underground compensated storage systems. When the brine level drops below the weep hole, LPG product enters the brine production system causing an increase in both tubing head pressure and flow rate. To prevent cavern overfill, a cavern shutdown is initiated upon detection of LPG in the surface brine system by pressure or flow instruments at the tubing head. In this study, we have investigated the multiphase flow characteristics of weep hole LPG detection systems to correctly estimate the operating limits. A simple and easy to use model has been developed to predict the tubing head pressure and flow rate increases. The model can be used to implement safer and more efficient operation procedures for underground compensated LPG storage systems. The model predictions for a typical field case are presented. An analysis of weep holes as product detection devices for LPG storage reservoirs has been carried out. It was found that the increases in pressure and flow rates at the tubing head change as a function of injection flow rate of the product. Therefore, a thorough consideration of cavern operating parameters is necessary to evaluate the use constant pressure and flow rate values to initiate emergency shut down of the cavern.

  19. Thermoelectric Materials Development for Low Temperature Geothermal Power Generation

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Tim Hansen

    2016-01-29

    Data includes characterization results for novel thermoelectric materials developed specifically for power generation from low temperature geothermal brines. Materials characterization data includes material density, thickness, resistance, Seebeck coefficient. This research was carried out by Novus Energy Partners in Cooperation with Southern Research Institute for a Department of Energy Sponsored Project.

  20. Geothermal injection treatment: process chemistry, field experiences, and design options

    SciTech Connect (OSTI)

    Kindle, C.H.; Mercer, B.W.; Elmore, R.P.; Blair, S.C.; Myers, D.A.

    1984-09-01

    The successful development of geothermal reservoirs to generate electric power will require the injection disposal of approximately 700,000 gal/h (2.6 x 10/sup 6/ 1/h) of heat-depleted brine for every 50,000 kW of generating capacity. To maintain injectability, the spent brine must be compatible with the receiving formation. The factors that influence this brine/formation compatibility and tests to quantify them are discussed in this report. Some form of treatment will be necessary prior to injection for most situations; the process chemistry involved to avoid and/or accelerate the formation of precipitate particles is also discussed. The treatment processes, either avoidance or controlled precipitation approaches, are described in terms of their principles and demonstrated applications in the geothermal field and, when such experience is limited, in other industrial use. Monitoring techniques for tracking particulate growth, the effect of process parameters on corrosion and well injectability are presented. Examples of brine injection, preinjection treatment, and recovery from injectivity loss are examined and related to the aspects listed above.