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  1. Geology, hydrology, chemistry, and microbiology of the in situ bioremediation demonstration site

    SciTech Connect (OSTI)

    Newcomer, D.R.; Doremus, L.A.; Hall, S.H.; Truex, M.J.; Vermeul, V.R.; Engelman, R.E.

    1995-03-01

    This report summarizes characterization information on the geology, hydrology, microbiology, contaminant distribution, and ground-water chemistry to support demonstration of in situ bioremediation at the Hanford Site. The purpose of this information is to provide baseline conditions, including a conceptual model of the aquifer being utilized for in situ bioremediation. Data were collected from sampling and other characterization activities associated with three wells drilled in the upper part of the suprabasalt aquifer. Results of point-dilution tracer tests, conducted in the upper 9 m (30 ft) of the aquifer, showed that most ground-water flow occurs in the upper part of this zone, which is consistent with hydraulic test results and geologic and geophysical data. Other tracer test results indicated that natural ground-water flow velocity is equal to or less than about 0.03 m/d (0.1 ft/d). Laboratory hydraulic conductivity measurements, which represent the local distribution of vertical hydraulic conductivity, varied up to three orders of magnitude. Based on concentration data from both the vadose and saturated zone, it is suggested that most, if not all, of the carbon tetrachloride detected is representative of the aqueous phase. Concentrations of carbon tetrachloride, associated with a contaminant plume in the 200-West Area, ranged from approximately 500 to 3,800 {mu}g/L in the aqueous phase and from approximately 10 to 290 {mu}g/L in the solid phase at the demonstration site. Carbon tetrachloride gas was detected in the vadose zone, suggesting volatilization and subsequent upward migration from the saturated zone.

  2. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Chemistry Print Chemical science at the ALS encompasses a broad range of approaches and specializations, including surfaces/interfaces, catalysis, chemical dynamics (gas-phase chemistry), crystallography, and physical chemistry. By one estimate, nearly 80% of all chemical reactions in nature and in human technology take place at boundaries between phases, i.e., at surfaces or interfaces. Atomic- and molecular-scale studies are needed to develop a thorough understanding of the

  3. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Chemistry Chemical science for a dynamic world 3D printer is ideal tool to make cones of explosive material with finely controlled internal microstructure Explosiv3Design READ MORE Isotopes for cancer and cardiac care Isotopes for cancer and cardiac care READ MORE Contact Us Division Leader David Morris Deputy Division Leader Mark McCleskey Division Office (505) 667-4457 Email Chemical science in support of Los Alamos mission The Chemistry Division serves the Laboratory's mission with

  4. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Chemistry Top Journals Journal of the American Chemical Society Angewandte Chemie & Angewandte Chemie, international edition in English Chemical Communications Chemical...

  5. Aluminum forms in stream sediment: Relation to bedrock geology and water chemistry

    SciTech Connect (OSTI)

    Turner, R.R.; Bogle, M.A.; Zeiler, M.A.; Mulholland, P.J.; Elwood, J.W.; Cook, R.B.

    1987-01-01

    Longitudinal gradients in sediment and water chemistry were characterized in a high elevation stream in the southern Appalachian Mountains, USA, to elucidate the geochemical behavior of aluminum across gradients in pH (4.5 to 6.5) and elevation (1120 to 1895 m). Observed gradients are driven in part by the presence of pyritic bedrock, which occurs at higher elevations and yields acidity when exposed to oxidation by landslide activity. Exchangeable Al in sediment (estimated using potassium chloride) varied in response to monomeric Al in streamwater and thus decreased downstream. Organic Al in sediment (estimated using sodium pyrophosphate) did not vary in proportion to the organic carbon content of sediment. Amorphous Al in sediment (estimated as the difference between oxalate- and pyrophosphate-extractable Al) and Al extractable with acidified streamwater (pH 4.5) was lowest at the more acidic sites. These results suggest that increases in soluble Al in downstream reaches during episodic pH depressions could be due in part to the release of adsorbed and/or precipitated Al in sediment.

  6. Atmospheric Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chemistry Atmospheric Chemistry Atmospheric Chemistry is the study of the composition of the atmosphere, the sources and fates of gases and particles in air, and changes induced by ...

  7. Actinide Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Actinide Chemistry Actinide chemistry serves a critical role in addressing global threats Project Description At Los Alamos, scientists are using actinide analytical chemistry to ...

  8. Beamline 5.3.2.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    size at sample (FWHM) 25 nm (theoretical), 31 nm actual Scientific applications Photovoltaics, thin films, macromolecular chemistry, geology, cosmological chemistry,...

  9. Emergent cosmology revisited

    SciTech Connect (OSTI)

    Bag, Satadru; Sahni, Varun; Shtanov, Yuri; Unnikrishnan, Sanil E-mail: varun@iucaa.ernet.in E-mail: sanil@lnmiit.ac.in

    2014-07-01

    We explore the possibility of emergent cosmology using the effective potential formalism. We discover new models of emergent cosmology which satisfy the constraints posed by the cosmic microwave background (CMB). We demonstrate that, within the framework of modified gravity, the emergent scenario can arise in a universe which is spatially open/closed. By contrast, in general relativity (GR) emergent cosmology arises from a spatially closed past-eternal Einstein Static Universe (ESU). In GR the ESU is unstable, which creates fine tuning problems for emergent cosmology. However, modified gravity models including Braneworld models, Loop Quantum Cosmology (LQC) and Asymptotically Free Gravity result in a stable ESU. Consequently, in these models emergent cosmology arises from a larger class of initial conditions including those in which the universe eternally oscillates about the ESU fixed point. We demonstrate that such an oscillating universe is necessarily accompanied by graviton production. For a large region in parameter space graviton production is enhanced through a parametric resonance, casting serious doubts as to whether this emergent scenario can be past-eternal.

  10. Actinide Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Actinide Chemistry Actinide Chemistry Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise David Gallimore Actinide Analytical Chemistry Email Rebecca Chamberlin Actinide Analytical Chemistry Email Josh Smith Chemistry Communications Email Along with the lanthanides, they are often called "the f-elements" because they have valence electrons in the f shell. Actinide chemistry serves a

  11. Topics in inflationary cosmologies

    SciTech Connect (OSTI)

    Mahajan, S.

    1986-04-01

    Several aspects of inflationary cosmologies are discussed. An introduction to the standard hot big bang cosmological model is reviewed, and some of the problems associated with it are presented. A short review of the proposals for solving the cosmological conundrums of the big bang model is presented. Old and the new inflationary scenarios are discussed and shown to be unacceptable. Some alternative scenarios especially those using supersymmetry are reviewed briefly. A study is given of inflationary models where the same set of fields that breaks supersymmetry is also responsible for inflation. In these models, the scale of supersymmetry breaking is related to the slope of the potential near the origin and can thus be kept low. It is found that a supersymmetry breaking scale of the order of the weak breaking scale. The cosmology obtained from the simplest of such models is discussed in detail and it is shown that there are no particular problems except a low reheating temperature and a violation of the thermal constraint. A possible solution to the thermal constraint problem is given by introducing a second field, and the role played by this second field in the scenario is discussed. An alternative mechanism for the generation of baryon number within the framework of supergravity inflationary models is studied using the gravitational couplings of the heavy fields with the hidden sector (the sector which breaks supersymmetry). This mechanism is applied to two specific models - one with and one without supersymmetry breaking. The baryon to entropy ratio is found to be dependent on parameters which are model dependent. Finally, the effect of direct coupling between the two sectors on results is related, 88 refs., 6 figs.

  12. Nuclear & Particle Physics, Astrophysics, Cosmology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nuclear & Particle Physics Nuclear & Particle Physics, Astrophysics, Cosmology National security depends on science and technology. The United States relies on Los Alamos National ...

  13. Improving Data Mobility & Management for International Cosmology...

    Office of Scientific and Technical Information (OSTI)

    Improving Data Mobility & Management for International Cosmology Citation Details In-Document Search Title: Improving Data Mobility & Management for International Cosmology In February ...

  14. Cosmology with Mimetic Matter

    SciTech Connect (OSTI)

    Chamseddine, Ali H.; Mukhanov, Viatcheslav; Vikman, Alexander E-mail: viatcheslav.Mukhanov@lmu.de

    2014-06-01

    We consider minimal extensions of the recently proposed Mimetic Dark Matter and show that by introducing a potential for the mimetic non-dynamical scalar field we can mimic nearly any gravitational properties of the normal matter. In particular, the mimetic matter can provide us with inflaton, quintessence and even can lead to a bouncing nonsingular universe. We also investigate the behaviour of cosmological perturbations due to a mimetic matter. We demonstrate that simple mimetic inflation can produce red-tilted scalar perturbations which are largely enhanced over gravity waves.

  15. Inflationary Axion Cosmology

    DOE R&D Accomplishments [OSTI]

    Wilczek, Frank; Turner, Michael S.

    1990-09-01

    If Peccei-Quinn (PQ) symmetry is broken after inflation, the initial axion angle is a random variable on cosmological scales; based on this fact, estimates of the relic-axion mass density give too large a value if the axion mass is less than about 10-6 eV. This bound can be evaded if the Universe underwent inflation after PQ symmetry breaking and if the observable Universe happens to be a region where the initial axion angle was atypically small, .1 . (ma/10-6eV)0.59. We show consideration of fluctuations induced during inflation severely constrains the latter alternative.

  16. Particle physics and cosmology

    SciTech Connect (OSTI)

    Kolb, E.W.

    1986-10-01

    This series of lectures is about the role of particle physics in physical processes that occurred in the very early stages of the bug gang. Of particular interest is the role of particle physics in determining the evolution of the early Universe, and the effect of particle physics on the present structure of the Universe. The use of the big bang as a laboratory for placing limits on new particle physics theories will also be discussed. Section 1 reviews the standard cosmology, including primordial nucleosynthesis. Section 2 reviews the decoupling of weakly interacting particles in the early Universe, and discusses neutrino cosmology and the resulting limits that may be placed on the mass and lifetime of massive neutrinos. Section 3 discusses the evolution of the vacuum through phase transitions in the early Universe and the formation of topological defects in the transitions. Section 4 covers recent work on the generation of the baryon asymmetry by baryon-number violating reactions in Grand Unified Theories, and mentions some recent work on baryon number violation effects at the electroweak transition. Section 5 is devoted to theories of cosmic inflation. Finally, Section 6 is a discussion of the role of extra spatial dimensions in the evolution of the early Universe. 78 refs., 32 figs., 6 tabs.

  17. Cosmology with matter diffusion

    SciTech Connect (OSTI)

    Calogero, Simone; Velten, Hermano E-mail: velten@cce.ufes.br

    2013-11-01

    We construct a viable cosmological model based on velocity diffusion of matter particles. In order to ensure the conservation of the total energy-momentum tensor in the presence of diffusion, we include a cosmological scalar field ? which we identify with the dark energy component of the universe. The model is characterized by only one new degree of freedom, the diffusion parameter ?. The standard ?CDM model can be recovered by setting ? = 0. If diffusion takes place (? > 0) the dynamics of the matter and of the dark energy fields are coupled. We argue that the existence of a diffusion mechanism in the universe may serve as a theoretical motivation for interacting models. We constrain the background dynamics of the diffusion model with Supernovae, H(z) and BAO data. We also perform a perturbative analysis of this model in order to understand structure formation in the universe. We calculate the impact of diffusion both on the CMB spectrum, with particular attention to the integrated Sachs-Wolfe signal, and on the matter power spectrum P(k). The latter analysis places strong constraints on the magnitude of the diffusion mechanism but does not rule out the model.

  18. Chemistry Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Chemistry Applications Gaussian 09 Gaussian 09 is a connected series of programs for performing semi-empirical, density functional theory and ab initio molecular orbital calculations. Read More » GAMESS GAMESS (General Atomic and Molecular Electronic Structure System) is a general ab initio quantum chemistry package. Read More » AMBER AMBER (Assisted Model Building with Energy Refinement) is the collective name for a suite of programs designed to carry out molecular dynamics

  19. Cosmological and supernova neutrinos

    SciTech Connect (OSTI)

    Kajino, T. [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588, Japan Department of Astronomy, University of Tokyo, Hongo 7-3-1, Bunkyo-ku, Tokyo 113-0033 (Japan); Aoki, W. [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan); Balantekin, A. B. [Department of Physics, University of Wisconsin - Madison, Wisconsin 53706 (United States); Cheoun, M.-K. [Department of Physics, Soongsil University, Seoul 156-743 (Korea, Republic of); Hayakawa, T. [Japan Atomic Energy Agency, Shirakara-Shirane 2-4, Tokai-mura, Ibaraki 319-1195 (Japan); Hidaka, J. [National Astronomical Observatory, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan); Hirai, Y.; Shibagaki, S. [National Astronomical Observatory, 2-21-1 Osawa, Mitaka, Tokyo 181-8588, Japan and Department of Astronomy, University of Tokyo, Hongo 7-3-1, Bunkyo-ku, Tokyo 113-0033 (Japan); Kusakabe, M. [School of Liberal Arts and Science, Korea Aerospace University, Goyang 412-791 (Korea, Republic of); Mathews, G. J. [Department of Physics, University of Notre Dame, IN 46556 (United States); Nakamura, K. [Waseda University, Ohkubo 3-4-1, Shinjuku, Tokyo 169-8555 (Japan); Pehlivan, Y. [Mimar Sinan GS, Department of Physics, ?i?li, ?stanbul 34380 (Turkey); Suzuki, T. [Nihon University, Sakurajosui 3-25-40, Setagaya-ku, Tokyo 156-8550 (Japan)

    2014-06-24

    The Big Bang nucleosynthesis (BBN) and the cosmic microwave background (CMB) anisotropies are the pillars of modern cosmology. It has recently been suggested that axion which is a dark matter candidate in the framework of the standard model could condensate in the early universe and induce photon cooling before the epoch of the photon last scattering. Although this may render a solution to the overproduction problem of primordial {sup 7}Li abundance, there arises another serious difficulty of overproducing D abundance. We propose a hybrid dark matter model with both axions and relic supersymmetric (SUSY) particles to solve both overproduction problems of the primordial D and {sup 7}Li abundances simultaneously. The BBN also serves to constrain the nature of neutrinos. Considering non-thermal photons produced in the decay of the heavy sterile neutrinos due to the magnetic moment, we explore the cosmological constraint on the strength of neutrino magnetic moment consistent with the observed light element abundances. Core-collapse supernovae eject huge flux of energetic neutrinos which affect explosive nucleosynthesis of rare isotopes like {sup 7}Li, {sup 11}B, {sup 92}Nb, {sup 138}La and {sup 180}Ta and r-process elements. Several isotopes depend strongly on the neutrino flavor oscillation due to the Mikheyev-Smirnov-Wolfenstein (MSW) effect. Combining the recent experimental constraints on ?{sub 13} with predicted and observed supernova-produced abundance ratio {sup 11}B/{sup 7}Li encapsulated in the presolar grains from the Murchison meteorite, we show a marginal preference for an inverted neutrino mass hierarchy. We also discuss supernova relic neutrinos (SRN) that may indicate the softness of the equation of state (EoS) of nuclear matter and adiabatic conditions of the neutrino oscillation.

  20. Beamline 8.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION Operational Yes Source...

  1. Beamline 8.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION...

  2. Computational Cosmology | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computational Cosmology Computational Cosmology To study the mysterious dark sector we use powerful simulations on state-of-the-art high-performance computers, run at Argonne and elsewhere. By developing specialized codes for these supercomputers, and by comparing their results to observations from deep surveys of the sky, we aim to answer some of the most fundamental questions in physics: What is dark matter made of? What is the nature of dark energy? Does general relativity need to be

  3. Particle Theory & Cosmology

    SciTech Connect (OSTI)

    Shafi, Qaisar; Barr, Steven; Gaisser, Thomas; Stanev, Todor

    2015-03-31

    1. Executive Summary (April 1, 2012 - March 31, 2015) Title: Particle Theory, Particle Astrophysics and Cosmology Qaisar Shafi University of Delaware (Principal Investigator) Stephen M. Barr, University of Delaware (Co-Principal Investigator) Thomas K. Gaisser, University of Delaware (Co-Principal Investigator) Todor Stanev, University of Delaware (Co-Principal Investigator) The proposed research was carried out at the Bartol Research included Professors Qaisar Shafi Stephen Barr, Thomas K. Gaisser, and Todor Stanev, two postdoctoral fellows (Ilia Gogoladze and Liucheng Wang), and several graduate students. Five students of Qaisar Shafi completed their PhD during the period August 2011 - August 2014. Measures of the group’s high caliber performance during the 2012-2015 funding cycle included pub- lications in excellent refereed journals, contributions to working groups as well as white papers, and conference activities, which together provide an exceptional record of both individual performance as well as overall strength. Another important indicator of success is the outstanding quality of the past and current cohort of graduate students. The PhD students under our supervision regularly win the top departmental and university awards, and their publications records show excellence both in terms of quality and quantity. The topics covered under this grant cover the frontline research areas in today’s High Energy Theory & Phenomenology. For Professors Shafi and Barr they include LHC related topics including supersymmetry, collider physics, fl vor physics, dark matter physics, Higgs boson and seesaw physics, grand unifi and neutrino physics. The LHC two years ago discovered the Standard Model Higgs boson, thereby at least partially unlocking the secrets behind electroweak symmetry breaking. We remain optimistic that new and exciting physics will be found at LHC 14, which explain our focus on physics beyond the Standard Model. Professors Shafi continued his

  4. Regional Geologic Map

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Lane, Michael

    Shaded relief base with Hot Pot project area, generalized geology, selected mines, and major topographic features

  5. Regional Geologic Map

    SciTech Connect (OSTI)

    Lane, Michael

    2013-06-28

    Shaded relief base with Hot Pot project area, generalized geology, selected mines, and major topographic features

  6. Double field theory inspired cosmology

    SciTech Connect (OSTI)

    Wu, Houwen; Yang, Haitang E-mail: hyanga@scu.edu.cn

    2014-07-01

    Double field theory proposes a generalized spacetime action possessing manifest T-duality on the level of component fields. We calculate the cosmological solutions of double field theory with vanishing Kalb-Ramond field. It turns out that double field theory provides a more consistent way to construct cosmological solutions than the standard string cosmology. We construct solutions for vanishing and non-vanishing symmetry preserving dilaton potentials. The solutions assemble the pre- and post-big bang evolutions in one single line element. Our results show a smooth evolution from an anisotropic early stage to an isotropic phase without any special initial conditions in contrast to previous models. In addition, we demonstrate that the contraction of the dual space automatically leads to both an inflation phase and a decelerated expansion of the ordinary space during different evolution stages.

  7. Constraining Lorentz Violation with Cosmology

    SciTech Connect (OSTI)

    Zuntz, J. A.; Ferreira, P. G.; Zlosnik, T. G

    2008-12-31

    The Einstein-aether theory provides a simple, dynamical mechanism for breaking Lorentz invariance. It does so within a generally covariant context and may emerge from quantum effects in more fundamental theories. The theory leads to a preferred frame and can have distinct experimental signatures. In this Letter, we perform a comprehensive study of the cosmological effects of the Einstein-aether theory and use observational data to constrain it. Allied to previously determined consistency and experimental constraints, we find that an Einstein-aether universe can fit experimental data over a wide range of its parameter space, but requires a specific rescaling of the other cosmological densities.

  8. Dark D-brane cosmology

    SciTech Connect (OSTI)

    Koivisto, Tomi; Wills, Danielle; Zavala, Ivonne E-mail: d.e.wills@durham.ac.uk

    2014-06-01

    Disformally coupled cosmologies arise from Dirac-Born-Infeld actions in Type II string theories, when matter resides on a moving hidden sector D-brane. Since such matter interacts only very weakly with the standard model particles, this scenario can provide a natural origin for the dark sector of the universe with a clear geometrical interpretation: dark energy is identified with the scalar field associated to the D-brane's position as it moves in the internal space, acting as quintessence, while dark matter is identified with the matter living on the D-brane, which can be modelled by a perfect fluid. The coupling functions are determined by the (warped) extra-dimensional geometry, and are thus constrained by the theory. The resulting cosmologies are studied using both dynamical system analysis and numerics. From the dynamical system point of view, one free parameter controls the cosmological dynamics, given by the ratio of the warp factor and the potential energy scales. The disformal coupling allows for new scaling solutions that can describe accelerating cosmologies alleviating the coincidence problem of dark energy. In addition, this scenario may ameliorate the fine-tuning problem of dark energy, whose small value may be attained dynamically, without requiring the mass of the dark energy field to be unnaturally low.

  9. How does pressure gravitate? Cosmological constant problem confronts observational cosmology

    SciTech Connect (OSTI)

    Narimani, Ali; Scott, Douglas; Afshordi, Niayesh E-mail: nafshordi@pitp.ca

    2014-08-01

    An important and long-standing puzzle in the history of modern physics is the gross inconsistency between theoretical expectations and cosmological observations of the vacuum energy density, by at least 60 orders of magnitude, otherwise known as the cosmological constant problem. A characteristic feature of vacuum energy is that it has a pressure with the same amplitude, but opposite sign to its energy density, while all the precision tests of General Relativity are either in vacuum, or for media with negligible pressure. Therefore, one may wonder whether an anomalous coupling to pressure might be responsible for decoupling vacuum from gravity. We test this possibility in the context of the Gravitational Aether proposal, using current cosmological observations, which probe the gravity of relativistic pressure in the radiation era. Interestingly, we find that the best fit for anomalous pressure coupling is about half-way between General Relativity (GR), and Gravitational Aether (GA), if we include Planck together with WMAP and BICEP2 polarization cosmic microwave background (CMB) observations. Taken at face value, this data combination excludes both GR and GA at around the 3 σ level. However, including higher resolution CMB observations (''highL'') or baryonic acoustic oscillations (BAO) pushes the best fit closer to GR, excluding the Gravitational Aether solution to the cosmological constant problem at the 4- 5 σ level. This constraint effectively places a limit on the anomalous coupling to pressure in the parametrized post-Newtonian (PPN) expansion, ζ{sub 4} = 0.105 ± 0.049 (+highL CMB), or ζ{sub 4} = 0.066 ± 0.039 (+BAO). These represent the most precise measurement of this parameter to date, indicating a mild tension with GR (for ΛCDM including tensors, with 0ζ{sub 4}=), and also among different data sets.

  10. Flame Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear Energy

  11. Materials Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear Energy

  12. Cosmological perturbations in unimodular gravity

    SciTech Connect (OSTI)

    Gao, Caixia; Brandenberger, Robert H.; Cai, Yifu; Chen, Pisin E-mail: rhb@hep.physics.mcgill.ca E-mail: chen@slac.stanford.edu

    2014-09-01

    We study cosmological perturbation theory within the framework of unimodular gravity. We show that the Lagrangian constraint on the determinant of the metric required by unimodular gravity leads to an extra constraint on the gauge freedom of the metric perturbations. Although the main equation of motion for the gravitational potential remains the same, the shift variable, which is gauge artifact in General Relativity, cannot be set to zero in unimodular gravity. This non-vanishing shift variable affects the propagation of photons throughout the cosmological evolution and therefore modifies the Sachs-Wolfe relation between the relativistic gravitational potential and the microwave temperature anisotropies. However, for adiabatic fluctuations the difference between the result in General Relativity and unimodular gravity is suppressed on large angular scales. Thus, no strong constraints on the theory can be derived.

  13. Effective perfect fluids in cosmology

    SciTech Connect (OSTI)

    Ballesteros, Guillermo; Bellazzini, Brando E-mail: brando.bellazzini@pd.infn.it

    2013-04-01

    We describe the cosmological dynamics of perfect fluids within the framework of effective field theories. The effective action is a derivative expansion whose terms are selected by the symmetry requirements on the relevant long-distance degrees of freedom, which are identified with comoving coordinates. The perfect fluid is defined by requiring invariance of the action under internal volume-preserving diffeomorphisms and general covariance. At lowest order in derivatives, the dynamics is encoded in a single function of the entropy density that characterizes the properties of the fluid, such as the equation of state and the speed of sound. This framework allows a neat simultaneous description of fluid and metric perturbations. Longitudinal fluid perturbations are closely related to the adiabatic modes, while the transverse modes mix with vector metric perturbations as a consequence of vorticity conservation. This formalism features a large flexibility which can be of practical use for higher order perturbation theory and cosmological parameter estimation.

  14. Cosmological solution moduli of bigravity

    SciTech Connect (OSTI)

    Yılmaz, Nejat Tevfik

    2015-09-29

    We construct the complete set of metric-configuration solutions of the ghost-free massive bigravity for the scenario in which the g−metric is the Friedmann-Lemaitre-Robertson-Walker (FLRW) one, and the interaction Lagrangian between the two metrics contributes an effective ideal fluid energy-momentum tensor to the g-metric equations. This set corresponds to the exact background cosmological solution space of the theory.

  15. Emergent cosmological constant from colliding electromagnetic waves

    SciTech Connect (OSTI)

    Halilsoy, M.; Mazharimousavi, S. Habib; Gurtug, O. E-mail: habib.mazhari@emu.edu.tr

    2014-11-01

    In this study we advocate the view that the cosmological constant is of electromagnetic (em) origin, which can be generated from the collision of em shock waves coupled with gravitational shock waves. The wave profiles that participate in the collision have different amplitudes. It is shown that, circular polarization with equal amplitude waves does not generate cosmological constant. We also prove that the generation of the cosmological constant is related to the linear polarization. The addition of cross polarization generates no cosmological constant. Depending on the value of the wave amplitudes, the generated cosmological constant can be positive or negative. We show additionally that, the collision of nonlinear em waves in a particular class of Born-Infeld theory also yields a cosmological constant.

  16. Cosmology & Astrophysics | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cosmology & Astrophysics Cosmology & Astrophysics For centuries, scientists have tried to fully describe the formation and evolution of our universe, as well as its composition. At Argonne, scientists study the cosmic background radiation that formed as a result of the big bang as well as the mysterious dark matter and dark energy which combine to form more than 90 percent of our universe. Cosmology, the study of the origins and working of our universe, not only gives us answers that

  17. Nuclear and Particle Physics, Astrophysics, and Cosmology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nuclear and Particle Physics, Astrophysics, and Cosmology Providing scientific and technical leadership in fundamental and applied theoretical research on nuclear, particle, ...

  18. The Effective Field Theory of Cosmological Large Scale Structures...

    Office of Scientific and Technical Information (OSTI)

    The Effective Field Theory of Cosmological Large Scale Structures Citation Details In-Document Search Title: The Effective Field Theory of Cosmological Large Scale Structures...

  19. Cosmological singularities in Born-Infeld determinantal gravity...

    Office of Scientific and Technical Information (OSTI)

    Cosmological singularities in Born-Infeld determinantal gravity Citation Details In-Document Search Title: Cosmological singularities in Born-Infeld determinantal gravity Authors: ...

  20. Combustion chemistry

    SciTech Connect (OSTI)

    Brown, N.J.

    1993-12-01

    This research is concerned with the development and use of sensitivity analysis tools to probe the response of dependent variables to model input variables. Sensitivity analysis is important at all levels of combustion modeling. This group`s research continues to be focused on elucidating the interrelationship between features in the underlying potential energy surface (obtained from ab initio quantum chemistry calculations) and their responses in the quantum dynamics, e.g., reactive transition probabilities, cross sections, and thermal rate coefficients. The goals of this research are: (i) to provide feedback information to quantum chemists in their potential surface refinement efforts, and (ii) to gain a better understanding of how various regions in the potential influence the dynamics. These investigations are carried out with the methodology of quantum functional sensitivity analysis (QFSA).

  1. Flame Chemistry and Diagnostics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flame Conditions Flame Chemistry Insights (n-butanol flame) Experiment vs. ... Molecular beam sampling "freezes" chemistry Time-of-flight mass spectrometry ...

  2. COSMOLOGICAL ADAPTIVE MESH REFINEMENT MAGNETOHYDRODYNAMICS WITH ENZO

    SciTech Connect (OSTI)

    Collins, David C.; Xu Hao; Norman, Michael L.; Li Hui; Li Shengtai

    2010-02-01

    In this work, we present EnzoMHD, the extension of the cosmological code Enzo to include the effects of magnetic fields through the ideal magnetohydrodynamics approximation. We use a higher order Godunov method for the computation of interface fluxes. We use two constrained transport methods to compute the electric field from those interface fluxes, which simultaneously advances the induction equation and maintains the divergence of the magnetic field. A second-order divergence-free reconstruction technique is used to interpolate the magnetic fields in the block-structured adaptive mesh refinement framework already extant in Enzo. This reconstruction also preserves the divergence of the magnetic field to machine precision. We use operator splitting to include gravity and cosmological expansion. We then present a series of cosmological and non-cosmological test problems to demonstrate the quality of solution resulting from this combination of solvers.

  3. Primordial nucleosynthesis: A cosmological point of view

    SciTech Connect (OSTI)

    Mathews, G. J.; Kusakabe, M.; Cheoun, M.-K.

    2014-05-09

    Primordial nucleosynthesis remains as one of the pillars of modern cosmology. It is the test-ing ground upon which all cosmological models must ultimately rest. It is our only probe of the universe during the first few minutes of cosmic expansion and in particular during the important radiation-dominated epoch. These lectures review the basic equations of space-time, cosmology, and big bang nucleosynthesis. We will then review the current state of observational constraints on primordial abundances along with the key nuclear reactions and their uncertainties. We summarize which nuclear measure-ments are most crucial during the big bang. We also review various cosmological models and their constraints. In particular, we summarize the constraints that big bang nucleosynthesis places upon the possible time variation of fundamental constants, along with constraints on the nature and origin of dark matter and dark energy, long-lived supersymmetric particles, gravity waves, and the primordial magnetic field.

  4. Cosmology on the Beach: Kendrick Smith

    ScienceCinema (OSTI)

    George Smoot

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.

  5. Cosmology on the Beach - George Smoot

    ScienceCinema (OSTI)

    George Smoot

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.

  6. Cosmology at the Beach Lecture: David Hughes

    ScienceCinema (OSTI)

    David Hughes

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.

  7. Cosmology at the Beach Lecture: Anne Green

    ScienceCinema (OSTI)

    Ann Green

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.  

  8. Cosmology at the Beach Lecture: Simon White

    ScienceCinema (OSTI)

    Simon White

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.

  9. Nuclear and Particle Physics, Astrophysics, and Cosmology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | (NNSA) Weapons Testing Resumes Nuclear Weapons Testing Resumes Washington, DC The Soviet Union breaks the nuclear test moratorium and the United States resumes testing

    2 Nuclear and Particle Physics, Astrophysics, and Cosmology Providing scientific and technical leadership in fundamental and applied theoretical research on nuclear, particle, astrophysics, and cosmology theory and simulations Leadership Group Leader Joe Carlson Email Deputy Group Leader Gerry Hale Email Contact Us

  10. Improving Data Mobility & Management for International Cosmology

    SciTech Connect (OSTI)

    Borrill, Julian; Dart, Eli; Gore, Brooklin; Habib, Salman; Myers, Steven T.; Nugent, Peter; Petravick, Don; Thomas, Rollin

    2015-10-02

    In February 2015 the third workshop in the CrossConnects series, with a focus on Improving Data Mobility & Management for International Cosmology, was held at Lawrence Berkeley National Laboratory. Scientists from fields including astrophysics, cosmology, and astronomy collaborated with experts in computing and networking to outline strategic opportunities for enhancing scientific productivity and effectively managing the ever-increasing scale of scientific data.

  11. First trillion particle cosmological simulation completed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    First trillion particle cosmological simulation completed First trillion particle cosmological simulation completed A team of astrophysicists and computer scientists has created high-resolution cyber images of our cosmos. January 8, 2015 Simulation of the cosmic web of the dark matter mass distribution. This region represents about 1/10,000 of the total simulation volume. Simulation of the cosmic web of the dark matter mass distribution. This region represents about 1/10,000 of the total

  12. SOPAC marine geology atlases

    SciTech Connect (OSTI)

    Chase, T.E.; Seekins, B.A.; Young, J.D.; Wahler, J.A.

    1986-07-01

    The US Geological Survey conducted a series of marine geologic and geophysical cruises in the southwest Pacific Ocean in 1982 and 1984 as part of a program with participation by Australia and New Zealand. These two SOPAC expeditions obtained various data, which have been compiled into a series of charts and thematic products for the offshore areas of Tonga, Fiji, Vanuatu, the Solomon Islands, and Papua New Guinea. The maps and charts presently being compiled or revised combine previously collected data with information from the SOPAC expeditions. Regional charts at a scale of approximately 1:3 million are included, and more detailed coverage is available at 1:1 million. Additional geologic information-such as gravity, magnetics, and possibly sediment isopachs-is provided on overlays to the topographic base charts. Reproductions of the seismic reflection data are also included, and tracklines with both time marks and shotpoints will permit correlation with the analog and digital seismic records.

  13. Synthetic and Mechanistic Chemistry publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthetic and Mechanistic Chemistry Synthetic and Mechanistic Synthetic and Mechanistic ... Get Expertise Dave Thorn Chemistry Program Manager Email Josh Smith Chemistry ...

  14. Actinide Analytical Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AAC Actinide Analytical Chemistry We do analyses that range from assay of the major and ... Group Office (505) 667-4087 The Actinide Analytical Chemistry (C-AAC) Group at Los Alamos ...

  15. Synthetic and Mechanistic Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Mechanistic Chemistry Security at center of chemical and mechanistic chemistry research at Lab Project Description Los Alamos scientists are using synthetic and mechanistic chemistry to address energy security and other emerging challenges, including global security and core weapons missions. Synthetic chemistry includes work in ligands for catalysts, fission-products separations for isotope delivery, and labeled substrates for reaction mechanisms. Other research addresses materials

  16. Synthetic and Mechanistic Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthetic and Mechanistic Chemistry Synthetic and Mechanistic Chemistry Synthetic and mechanistic chemical sciences play an important role in Lab missions dedicated to energy security, emerging challenges, global security, and core weapons missions. Get Expertise Dave Thorn Chemistry Program Manager Email Josh Smith Chemistry Communications Email "Research into alternative forms of energy, of which biofuels is a key component, is one of the major national security imperatives of this

  17. ALS Chemistry Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Chemistry Lab Print ALS Chemistry Labs The ALS Chemistry Labs are located in the User Support Building (15-130) and in Building 6 (6-2233)*. These spaces are dedicated for chemistry work that involves higher quantities, higher toxicity or reactivity, and/or more complex work activity than is allowed on the ALS experiment floor. In addition, the great majority of hazardous chemicals at the ALS are stored in these facilities. Standard chemical safety engineering, administrative and PPE

  18. ALS Chemistry Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALS Chemistry Lab Print ALS Chemistry Labs The ALS Chemistry Labs are located in the User Support Building (15-130) and in Building 6 (6-2233)*. These spaces are dedicated for chemistry work that involves higher quantities, higher toxicity or reactivity, and/or more complex work activity than is allowed on the ALS experiment floor. In addition, the great majority of hazardous chemicals at the ALS are stored in these facilities. Standard chemical safety engineering, administrative and PPE

  19. ALS Chemistry Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Lab Print ALS Chemistry Labs The ALS Chemistry Labs are located in the User Support Building (15-130) and in Building 6 (6-2233)*. These spaces are dedicated for chemistry work that involves higher quantities, higher toxicity or reactivity, and/or more complex work activity than is allowed on the ALS experiment floor. In addition, the great majority of hazardous chemicals at the ALS are stored in these facilities. Standard chemical safety engineering, administrative and PPE controls

  20. Inflation after COBE: Lectures on inflationary cosmology

    SciTech Connect (OSTI)

    Turner, M.S. [Chicago Univ., IL (United States). Enrico Fermi Inst.]|[Fermi National Accelerator Lab., Batavia, IL (United States)

    1992-12-31

    In these lectures I review the standard hot big-bang cosmology, emphasizing its successes, its shortcomings, and its major challenge-a detailed understanding of the formation of structure in the Universe. I then discuss the motivations for and the fundamentals of inflationary cosmology, particularly emphasizing the quantum origin of metric (density and gravity-wave) perturbations. Inflation addresses the shortcomings of the standard cosmology and provides the ``initial data`` for structure formation. I conclude by addressing the implications of inflation for structure formation, evaluating the various cold dark matter models in the light of the recent detection of temperature anisotropies in the cosmic background radiation by COBE. In the near term, the study of structure formation offers a powerful probe of inflation, as well as specific inflationary models.

  1. CosmoSIS: Modular cosmological parameter estimation

    SciTech Connect (OSTI)

    Zuntz, J.; Paterno, M.; Jennings, E.; Rudd, D.; Manzotti, A.; Dodelson, S.; Bridle, S.; Sehrish, S.; Kowalkowski, J.

    2015-06-09

    Cosmological parameter estimation is entering a new era. Large collaborations need to coordinate high-stakes analyses using multiple methods; furthermore such analyses have grown in complexity due to sophisticated models of cosmology and systematic uncertainties. In this paper we argue that modularity is the key to addressing these challenges: calculations should be broken up into interchangeable modular units with inputs and outputs clearly defined. Here we present a new framework for cosmological parameter estimation, CosmoSIS, designed to connect together, share, and advance development of inference tools across the community. We describe the modules already available in CosmoSIS, including CAMB, Planck, cosmic shear calculations, and a suite of samplers. Lastly, we illustrate it using demonstration code that you can run out-of-the-box with the installer available at http://bitbucket.org/joezuntz/cosmosis

  2. CosmoSIS: Modular cosmological parameter estimation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zuntz, J.; Paterno, M.; Jennings, E.; Rudd, D.; Manzotti, A.; Dodelson, S.; Bridle, S.; Sehrish, S.; Kowalkowski, J.

    2015-06-09

    Cosmological parameter estimation is entering a new era. Large collaborations need to coordinate high-stakes analyses using multiple methods; furthermore such analyses have grown in complexity due to sophisticated models of cosmology and systematic uncertainties. In this paper we argue that modularity is the key to addressing these challenges: calculations should be broken up into interchangeable modular units with inputs and outputs clearly defined. Here we present a new framework for cosmological parameter estimation, CosmoSIS, designed to connect together, share, and advance development of inference tools across the community. We describe the modules already available in CosmoSIS, including CAMB, Planck, cosmicmore » shear calculations, and a suite of samplers. Lastly, we illustrate it using demonstration code that you can run out-of-the-box with the installer available at http://bitbucket.org/joezuntz/cosmosis« less

  3. Gravitational collapse and the cosmological constant

    SciTech Connect (OSTI)

    Deshingkar, S. S.; Jhingan, S.; Chamorro, A.; Joshi, P. S.

    2001-06-15

    We consider here the effects of a nonvanishing cosmological term on the final fate of a spherical inhomogeneous collapsing dust cloud. It is shown that, depending on the nature of the initial data from which the collapse evolves, and for a positive value of the cosmological constant, we can have a globally regular evolution where a bounce develops within the cloud. We characterize precisely the initial data causing such a bounce in terms of the initial density and velocity profiles for the collapsing cloud. In the cases otherwise, the result of collapse is either the formation of a black hole or a naked singularity resulting as the end state of collapse. We also show here that a positive cosmological term can cover a part of the singularity spectrum which is visible in the corresponding dust collapse models for the same initial data.

  4. The new cosmology (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    The new cosmology Citation Details In-Document Search Title: The new cosmology You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a ...

  5. The new cosmology (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    The new cosmology Citation Details In-Document Search Title: The new cosmology Over the past three years we have determined the basic features of our Universe. It is spatially ...

  6. Cosmological Behavior of a Parity and Charge-Parity Violating...

    Office of Scientific and Technical Information (OSTI)

    Cosmological Behavior of a Parity and Charge-Parity Violating Varying Alpha Theory Citation Details In-Document Search Title: Cosmological Behavior of a Parity and Charge-Parity ...

  7. Cosmological Simulations for Large-Scale Sky Surveys | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The focus of cosmology today is on its two mysterious pillars, dark matter and dark energy. Large-scale sky surveys are the current drivers of precision cosmology and have been ...

  8. Cosmological Simulations for Large-Scale Sky Surveys | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The focus of cosmology today revolves around two mysterious pillars, dark matter and dark energy. Large-scale sky surveys are the current drivers of precision cosmology and have ...

  9. Cosmological behavior of a parity and charge-parity violating...

    Office of Scientific and Technical Information (OSTI)

    Cosmological behavior of a parity and charge-parity violating varying alpha theory Citation Details In-Document Search Title: Cosmological behavior of a parity and charge-parity ...

  10. Beamline 8.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3.2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE INFORMATION...

  11. Beamline 8.3.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8.3.2 Print Tomography Scientific disciplines: Applied science, biology, earth sciences, energy, environmental sciences, geology, cosmological chemistry GENERAL BEAMLINE...

  12. Our Universe from the cosmological constant

    SciTech Connect (OSTI)

    Barrau, Aurlien; Linsefors, Linda E-mail: linda.linsefors@lpsc.in2p3.fr

    2014-12-01

    The issue of the origin of the Universe and of its contents is addressed in the framework of bouncing cosmologies, as described for example by loop quantum gravity. If the current acceleration is due to a true cosmological constant, this constant is naturally conserved through the bounce and the Universe should also be in a (contracting) de Sitter phase in the remote past. We investigate here the possibility that the de Sitter temperature in the contracting branch fills the Universe with radiation that causes the bounce and the subsequent inflation and reheating. We also consider the possibility that this gives rise to a cyclic model of the Universe and suggest some possible tests.

  13. Cosmology as Science?: From Inflation to Eternity

    ScienceCinema (OSTI)

    None

    2011-10-06

    The last decade or two have represented the golden age of observational cosmology, producing a revolution in our picture of the Universe on its largest scales, and perhaps also its smallest ones. I will argue that these recent development bring to the forefront some vexing questions about whether various fundamental assumptions about the universe are in fact falsifiable. I will focus on 3 issues: (1) "Proving" Inflation, (2) Dark Energy and Anthropic Arguments, and (3) Cosmology of the far future.Interview with Lawrence M. Krauss

  14. Testing the copernican principle via cosmological observations

    SciTech Connect (OSTI)

    Bolejko, Krzysztof; Wyithe, J. Stuart B. E-mail: swyithe@unimelb.edu.au

    2009-02-15

    Observations of distances to Type-Ia supernovae can be explained by cosmological models that include either a gigaparsec-scale void, or a cosmic flow, without the need for Dark Energy. Instead of invoking dark energy, these inhomogeneous models instead violate the Copernican Principle. we show that current cosmological observations (Supernovae, Baryon Acoustic Oscillations and estimates of the Hubble parameters based on the age of the oldest stars) are not able to rule out inhomogeneous anti-Copernican models. The next generation of surveys for baryonic acoustic oscillations will be sufficiently precise to either validate the Copernican Principle or determine the existence of a local Gpc scale inhomogeneity.

  15. New Cosmologies on the Horizon. Cosmology and Holography in bigravity and massive gravity

    SciTech Connect (OSTI)

    Tolley, Andrew James

    2013-03-31

    The goal of this research program is to explore the cosmological dynamics, the nature of cosmological and black hole horizons, and the role of holography in a new class of infrared modified theories of gravity. This will capitalize of the considerable recent progress in our understanding of the dynamics of massive spin two fields on curved spacetimes, culminating in the formulation of the first fully consistent theories of massive gravity and bigravity/bimetric theories.

  16. Primordial magnetic field limits from cosmological data

    SciTech Connect (OSTI)

    Kahniashvili, Tina [McWilliams Center for Cosmology and Department of Physics, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213 (United States); Department of Physics, Laurentian University, Ramsey Lake Road, Sudbury, Ontario P3E 2C (Canada); Abastumani Astrophysical Observatory, Ilia State University, 2A Kazbegi Ave, Tbilisi, GE-0160 (Georgia); Tevzadze, Alexander G. [Abastumani Astrophysical Observatory, Ilia State University, 2A Kazbegi Ave, Tbilisi, GE-0160 (Georgia); Faculty of Exact and Natural Sciences, Tbilisi State University, 1 Chavchavadze Avenue, Tbilisi, GE-0128 (Georgia); Sethi, Shiv K. [McWilliams Center for Cosmology and Department of Physics, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213 (United States); Raman Research Institute, Sadashivanagar, Bangalore 560080 (India); Pandey, Kanhaiya [Raman Research Institute, Sadashivanagar, Bangalore 560080 (India); Ratra, Bharat [Department of Physics, Kansas State University, 116 Cardwell Hall, Manhattan, Kansas 66506 (United States)

    2010-10-15

    We study limits on a primordial magnetic field arising from cosmological data, including that from big bang nucleosynthesis, cosmic microwave background polarization plane Faraday rotation limits, and large-scale structure formation. We show that the physically relevant quantity is the value of the effective magnetic field, and limits on it are independent of how the magnetic field was generated.

  17. Cosmology at the Beach Lecture: Wayne Hu

    ScienceCinema (OSTI)

    Wayne Hu

    2010-01-08

    Wayne Hu lectures on Secondary Anisotropy in the CMB. The lecture is the first in a series of 3 he delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.

  18. Cosmology and astrophysics with galaxy clusters

    SciTech Connect (OSTI)

    Nagai, Daisuke

    2014-11-20

    Galaxy clusters are the largest gravitationally bound objects in the universe, whose formation is driven by dark energy and dark matter. The majority of the baryonic mass in clusters resides in the hot X-ray emitting plasma, which also leaves imprints in the cosmic microwave background radiation. Recent X-ray and microwave observations have revealed detailed thermodynamic structure of the hot X-ray emitting plasma from their cores to the virial radii, making comparisons of baryonic component in simulations to observations a strong cosmological probe. However, the statistical power of these future surveys can only be exploited for cosmology if and only if we are able to measure the cluster mass with a very high precision. I will discuss recent progress and future challenges for the use of galaxy clusters as precise cosmological probes, with highlights on (1) the importance of understanding thermodynamics and plasma physics in the outskirts of galaxy clusters and (2) prospects for improving the power of cluster-based cosmological measurements using numerical simulations and multi-wavelength observations.

  19. Establishing MICHCARB, a geological carbon sequestration research...

    Office of Scientific and Technical Information (OSTI)

    Western Michigan University 58 GEOSCIENCES Geological carbon sequestration Enhanced oil recovery Characterization of oil, gas and saline reservoirs Geological carbon...

  20. Chemistry of Materials

    Office of Scientific and Technical Information (OSTI)

    Engineering and Materials Science, Dept. of Chemistry, The Smalley Institute for Nanoscale ... University, R.E. Smalley Institute for Nanoscale Science and Tech., Ajayan, Pulickel; ...

  1. DOE fundamentals handbook: Chemistry

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    This handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. This volume contains the following modules: reactor water chemistry (effects of radiation on water chemistry, chemistry parameters), principles of water treatment (purpose; treatment processes [ion exchange]; dissolved gases, suspended solids, and pH control; water purity), and hazards of chemicals and gases (corrosives [acids, alkalies], toxic compounds, compressed gases, flammable/combustible liquids).

  2. Synthetic and Mechanistic Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Performing weapons chemistry of targets for cross-section measurements, energetic ligands, and composites. Conducting separations for (1) medical isotope purification and (2) ...

  3. Neutrinos and cosmology: a lifetime relationship

    SciTech Connect (OSTI)

    Serpico, Pasquale D.; /Fermilab

    2008-06-01

    We consider the example of neutrino decays to illustrate the profound relation between laboratory neutrino physics and cosmology. Two case studies are presented: In the first one, we show how the high precision cosmic microwave background spectral data collected by the FIRAS instrument on board of COBE, when combined with Lab data, have greatly changed bounds on the radiative neutrino lifetime. In the second case, we speculate on the consequence for neutrino physics of the cosmological detection of neutrino masses even as small as {approx}0.06 eV, the lower limit guaranteed by neutrino oscillation experiments. We show that a detection at that level would improve by many orders of magnitude the existing limits on neutrino lifetime, and as a consequence on some models of neutrino secret interactions.

  4. Conformal symmetries of adiabatic modes in cosmology

    SciTech Connect (OSTI)

    Hinterbichler, Kurt; Khoury, Justin; Hui, Lam E-mail: lhui@astro.columbia.edu

    2012-08-01

    We remark on the existence of non-linearly realized conformal symmetries for scalar adiabatic perturbations in cosmology. These conformal symmetries are present for any cosmological background, beyond any slow-roll or quasi-de Sitter approximation. The dilatation transformation shifts the curvature perturbation by a constant, and corresponds to the well-known symmetry under spatial rescaling. We argue that the scalar sector is also invariant under special conformal transformations, which shift the curvature perturbation by a term linear in the spatial coordinates. We discuss whether these conformal symmetries can be extended to include tensor perturbations. Tensor modes introduce their own set of non-linearly realized symmetries. We identify an infinite set of large gauge transformations which maintain the transverse, traceless gauge condition, while shifting the tensor mode non-trivially.

  5. A cosmological study in massive gravity theory

    SciTech Connect (OSTI)

    Pan, Supriya Chakraborty, Subenoy

    2015-09-15

    A detailed study of the various cosmological aspects in massive gravity theory has been presented in the present work. For the homogeneous and isotropic FLRW model, the deceleration parameter has been evaluated, and, it has been examined whether there is any transition from deceleration to acceleration in recent past, or not. With the proper choice of the free parameters, it has been shown that the massive gravity theory is equivalent to Einstein gravity with a modified Newtonian gravitational constant together with a negative cosmological constant. Also, in this context, it has been examined whether the emergent scenario is possible, or not, in massive gravity theory. Finally, we have done a cosmographic analysis in massive gravity theory.

  6. Spacetime Average Density (SAD) cosmological measures

    SciTech Connect (OSTI)

    Page, Don N.

    2014-11-01

    The measure problem of cosmology is how to obtain normalized probabilities of observations from the quantum state of the universe. This is particularly a problem when eternal inflation leads to a universe of unbounded size so that there are apparently infinitely many realizations or occurrences of observations of each of many different kinds or types, making the ratios ambiguous. There is also the danger of domination by Boltzmann Brains. Here two new Spacetime Average Density (SAD) measures are proposed, Maximal Average Density (MAD) and Biased Average Density (BAD), for getting a finite number of observation occurrences by using properties of the Spacetime Average Density (SAD) of observation occurrences to restrict to finite regions of spacetimes that have a preferred beginning or bounce hypersurface. These measures avoid Boltzmann brain domination and appear to give results consistent with other observations that are problematic for other widely used measures, such as the observation of a positive cosmological constant.

  7. Numerical Cosmology: Building a Dynamical Universe

    SciTech Connect (OSTI)

    Garrison, David

    2010-10-11

    In this talk I discuss an often over-looked aspect of most cosmological models, dynamical interactions caused by gravitational waves. I begin by reviewing our current state of cosmological knowledge and gravitational waves. Then, I review work done to understand the nature of primordial magnetic fields. Finally, I combine the ideas of gravitational wave theory and plasma turbulence to develop a new theory of cosmic structure formation. Eventually, this work could help to explain the distribution of mass-energy in the observable universe as well as the anisotropies in the Cosmic Microwave Background without a heavy dependence on dark matter. This work seeks to explain how the dense, hot, turbulent plasma of protons, neutrons, electrons and neutrinos cooled in the presence of gravitational waves to form into structures and develop a statistical mechanics to describe this dynamical system.

  8. Stability analysis in tachyonic potential chameleon cosmology

    SciTech Connect (OSTI)

    Farajollahi, H.; Salehi, A.; Tayebi, F.; Ravanpak, A. E-mail: a.salehi@guilan.ac.ir E-mail: aravanpak@guilan.ac.ir

    2011-05-01

    We study general properties of attractors for tachyonic potential chameleon scalar-field model which possess cosmological scaling solutions. An analytic formulation is given to obtain fixed points with a discussion on their stability. The model predicts a dynamical equation of state parameter with phantom crossing behavior for an accelerating universe. We constrain the parameters of the model by best fitting with the recent data-sets from supernovae and simulated data points for redshift drift experiment generated by Monte Carlo simulations.

  9. Moderator Chemistry Program

    SciTech Connect (OSTI)

    Dewitt, L.V.; Gibbs, A.; Lambert, D.P.; Bohrer, S.R.; Fanning, R.L.; Houston, M.W.; Stinson, S.L.; Deible, R.W.; Abdel-Khalik, S.I.

    1990-11-01

    Over the past fifteen months, the Systems Chemistry Group of the Reactor Engineering Department has undertaken a comprehensive study of the Department`s moderator chemistry program at Savannah River Site (SRS). An internal review was developed to formalize and document this program. Objectives were as outlined in a mission statement and action plan. In addition to the mission statement and action plan, nine separate task reports have been issued during the course of this study. Each of these task reports is included in this document as a chapter. This document is an organized compilation of the individual reports issued by the Systems Chemistry Group in assessment of SRS moderator chemistry to determine if there were significant gaps in the program as ft existed in October, 1989. While these reviews found no significant gaps in that mode of operation, or any items that adversely affected safety, items were identified that could be improved. Many of the items have already been dear with or are in the process of completion under this Moderator Chemistry Program and other Reactor Restart programs. A complete list of the items of improvement found under this assessment is found in Chapter 9, along with a proposed time table for correcting remaining items that can be improved for the chemistry program of SRS reactors. An additional external review of the moderator chemistry processes, recommendations, and responses to/from the Reactor Corrosion Mitigation Committee is included as Appendix to this compilation.

  10. Moderator Chemistry Program

    SciTech Connect (OSTI)

    Dewitt, L.V.; Gibbs, A.; Lambert, D.P.; Bohrer, S.R.; Fanning, R.L.; Houston, M.W.; Stinson, S.L.; Deible, R.W.; Abdel-Khalik, S.I.

    1990-11-01

    Over the past fifteen months, the Systems Chemistry Group of the Reactor Engineering Department has undertaken a comprehensive study of the Department's moderator chemistry program at Savannah River Site (SRS). An internal review was developed to formalize and document this program. Objectives were as outlined in a mission statement and action plan. In addition to the mission statement and action plan, nine separate task reports have been issued during the course of this study. Each of these task reports is included in this document as a chapter. This document is an organized compilation of the individual reports issued by the Systems Chemistry Group in assessment of SRS moderator chemistry to determine if there were significant gaps in the program as ft existed in October, 1989. While these reviews found no significant gaps in that mode of operation, or any items that adversely affected safety, items were identified that could be improved. Many of the items have already been dear with or are in the process of completion under this Moderator Chemistry Program and other Reactor Restart programs. A complete list of the items of improvement found under this assessment is found in Chapter 9, along with a proposed time table for correcting remaining items that can be improved for the chemistry program of SRS reactors. An additional external review of the moderator chemistry processes, recommendations, and responses to/from the Reactor Corrosion Mitigation Committee is included as Appendix to this compilation.

  11. Detecting bioterrorism: Is chemistry enough?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Detecting bioterrorism: Is chemistry enough? Detecting bioterrorism: Is chemistry enough? In an online webinar, Kristin Omberg will offer discussion on the possibilities and ...

  12. SC e-journals, Chemistry

    Office of Scientific and Technical Information (OSTI)

    ... Acta Glass and Ceramics Global Biogeochemical Cycles Green Chemistry Helvetica Chimica Acta High Energy Chemistry High Temperature Hyle: International Journal for ...

  13. Seawater Chemistry Package

    Energy Science and Technology Software Center (OSTI)

    2005-11-23

    SeaChem Seawater Chemistry package provides routines to calculate pH, carbonate chemistry, density, and other quantities for seawater, based on the latest community standards. The chemistry is adapted from fortran routines provided by the OCMIP3/NOCES project, details of which are available at http://www.ipsl.jussieu.fr/OCMIP/. The SeaChem package can generate Fortran subroutines as well as Python wrappers for those routines. Thus the same code can be used by Python or Fortran analysis packages and Fortran ocean models alike.

  14. DOE fundamentals handbook: Chemistry

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Chemistry Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. The handbook includes information on the atomic structure of matter; chemical bonding; chemical equations; chemical interactions involved with corrosion processes; water chemistry control, including the principles of water treatment; the hazards of chemicals and gases, and basic gaseous diffusion processes. This information will provide personnel with a foundation for understanding the chemical properties of materials and the way these properties can impose limitations on the operation of equipment and systems.

  15. PDACS - A Portal for Data Analysis Services for Cosmological...

    Office of Scientific and Technical Information (OSTI)

    Conference: PDACS - A Portal for Data Analysis Services for Cosmological Simulations Citation Details In-Document Search Title: PDACS - A Portal for Data Analysis Services for ...

  16. Astrophysics and Cosmology with TeV Gamma Rays

    SciTech Connect (OSTI)

    Aharonian, Felix

    2005-07-13

    I will discuss the astrophysical and cosmological implications of recent exciting discoveries of TeV gamma-rays from objects representing several Galactic and Extragalactic source populations.

  17. Verification of the Time Evolution of Cosmological Simulations...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; ACCURACY; ALGORITHMS; COSMOLOGY; SIMULATION; VERIFICATION Word ...

  18. Multi-Scale Initial Conditions For Cosmological Simulations ...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Multi-Scale Initial Conditions For Cosmological Simulations Citation ... OSTI Identifier: 1028674 Report Number(s): SLAC-PUB-14463 Journal ID: ISSN 0035-8711; ...

  19. Cosmological Behavior of a Parity and Charge-Parity Violating...

    Office of Scientific and Technical Information (OSTI)

    Violating Varying Alpha Theory Citation Details In-Document Search Title: Cosmological Behavior of a Parity and Charge-Parity Violating Varying Alpha Theory Authors: Maity, ...

  20. Verification of the Time Evolution of Cosmological Simulations...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Verification of the Time Evolution of Cosmological Simulations via Hypothesis-Driven Comparative and Quantitative Visualization Citation Details In-Document Search...

  1. PARALLEL HOP: A SCALABLE HALO FINDER FOR MASSIVE COSMOLOGICAL...

    Office of Scientific and Technical Information (OSTI)

    Center for Astrophysics and Space Sciences, University of California, San Diego, CA 92093 ... Subject: 79 ASTROPHYSICS, COSMOLOGY AND ASTRONOMY; DATA ANALYSIS; DISTRIBUTION; GALAXIES; ...

  2. Cosmology at the frontier of neutrino physics (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Cosmology at the frontier of neutrino ... OSTI Identifier: 22068967 Resource Type: Journal Article Resource Relation: Journal Name: ...

  3. Formation of Compact Clusters from High Resolution Hybrid Cosmological...

    Office of Scientific and Technical Information (OSTI)

    Formation of Compact Clusters from High Resolution Hybrid Cosmological Simulations Citation Details In-Document Search Title: Formation of Compact Clusters from High Resolution ...

  4. CRYSTAL CHEMISTRY OF HYDROUS MINERALS

    SciTech Connect (OSTI)

    Y. ZHAO; ET AL

    2001-02-01

    Hydrogen has long been appreciated for its role in geological processes of the Earth's crust. However, its role in Earth's deep interior has been neglected in most geophysical thinking. Yet it is now believed that most of our planet's hydrogen may be locked up in high pressure phases of hydrous silicate minerals within the Earth's mantle. This rocky interior (approximately 7/8 of Earth's volume) is conjectured to contain 1-2 orders of magnitude more water than the more obvious oceans (the ''hydrosphere'') and atmosphere. This project is aimed at using the capability of neutron scattering from hydrogen to study the crystal chemistry and stability of hydrogen-bearing minerals at high pressures and temperatures. At the most basic level this is a study of the atomic position and hydrogen bond itself. We have conducted experimental runs on hydrous minerals under high pressure and high temperature conditions. The crystallographic structure of hydrous minerals at extreme conditions and its structural stability, and hydrogen bond at high P-T conditions are the fundamental questions to be addressed. The behavior of the hydrous minerals in the deep interior of the Earth has been discussed.

  5. Idaho Geological Survey | Open Energy Information

    Open Energy Info (EERE)

    The Idaho Geological Survey is located in Boise, Idaho. About Information on past oil and gas exploration wells in Idaho was transferred to the Idaho Geological Survey in...

  6. Chinese Geological Survey | Open Energy Information

    Open Energy Info (EERE)

    Chinese Geological Survey Jump to: navigation, search Name: Chinese Geological Survey Place: China Sector: Geothermal energy Product: Chinese body which is involved in surveys of...

  7. Vector fields and Loop Quantum Cosmology

    SciTech Connect (OSTI)

    Artymowski, Michał; Lalak, Zygmunt E-mail: Zygmunt.Lalak@fuw.edu.pl

    2011-09-01

    In the context of the Loop Quantum Cosmology we have analysed the holonomy correction to the classical evolution of the simplified Bianchi I model in the presence of vector fields. For the Universe dominated by a massive vector field or by a combination of a scalar field and a vector field a smooth transition between Kasner-like and Kasner-unlike solutions for a Bianchi I model has been demonstrated. In this case a lack of initial curvature singularity and a finite maximal energy density appear already at the level of General Relativity, which simulates a classical Big Bounce.

  8. Some cosmological consequences of Weyl invariance

    SciTech Connect (OSTI)

    Alvarez, Enrique; González-Martín, Sergio; Herrero-Valea, Mario

    2015-03-19

    We examine some Weyl invariant cosmological models in the framework of generalized dilaton gravity, in which the action is made of a set of N conformally coupled scalar fields. It will be shown that when the FRW ansatz for the spacetime metric is assumed, the Ward identity for conformal invariance guarantees that the gravitational equations hold whenever the scalar fields EM do so. It follows that any scale factor can solve the theory provided a non-trivial profile for a dilaton field. In particular, accelerated expansion is a natural solution to the full set of equations.

  9. Uniqueness of measures in loop quantum cosmology

    SciTech Connect (OSTI)

    Hanusch, Maximilian

    2015-09-15

    In Ashtekar and Campiglia [Classical Quantum Gravity 29, 242001 (2012)], residual diffeomorphisms have been used to single out the standard representation of the reduced holonomy-flux algebra in homogeneous loop quantum cosmology (LQC). We show that, in the homogeneous isotropic case, unitarity of the translations with respect to the extended ℝ-action (exponentiated reduced fluxes in the standard approach) singles out the Bohr measure on both the standard quantum configuration space ℝ{sub Bohr} as well as on the Fleischhack one (ℝ⊔ℝ{sub Bohr}). Thus, in both situations, the same condition singles out the standard kinematical Hilbert space of LQC.

  10. Geologic interpretation of gravity anomalies

    SciTech Connect (OSTI)

    Andreyev, B.A.; Klushin, I.G.

    1990-04-19

    This Russian textbook provides a sufficiently complete and systematic illumination of physico-geologic and mathematical aspect of complex problem of interpretation of gravity anomalies. The rational methods of localization of anomalies are examined in detail. All methods of interpreting gravity anomalies are described which have found successful application in practice. Also given are ideas of some new methods of the interpretation of gravity anomalies, the prospects for further development and industrial testing. Numerous practical examples to interpretation are given. Partial Contents: Bases of gravitational field theory; Physico-geologic bases of gravitational prospecting; Principles of geologic interpretation of gravity anomalies; Conversions and calculations of anomalies; Interpretation of gravity anomalies for bodies of correct geometric form and for bodies of arbitrary form; Geologic interpretation of the results of regional gravitational photographing; Searches and prospecting of oil- and gas-bearing structures and of deposits of ore and nonmetalliferous useful minerals.

  11. A note on entropic force and brane cosmology

    SciTech Connect (OSTI)

    Ling, Yi; Wu, Jian-Pin E-mail: jianpinwu@yahoo.com.cn

    2010-08-01

    Recently Verlinde proposed that gravity is an entropic force caused by information changes when a material body moves away from the holographic screen. In this note we apply this argument to brane cosmology, and show that the cosmological equation can be derived from this holographic scenario.

  12. Cosmology as Science: From Inflation to the Future

    ScienceCinema (OSTI)

    Krass, Lawrence [Case Western Reserve

    2010-01-08

    Recent developments in cosmology bring to the forefront fundamental questions about our ability to falsify various fundamental assumptions about the universe.  I will discuss three issues that reflect different aspects of these questions:  (1) "Proving" Inflation (2) Anthropic "Explanations" (3) Cosmology of the far future.

  13. Evolution of density perturbations in decaying vacuum cosmology

    SciTech Connect (OSTI)

    Borges, H. A.; Pigozzo, C.; Carneiro, S.; Fabris, J. C.

    2008-02-15

    We study cosmological perturbations in the context of an interacting dark energy model, in which the cosmological term decays linearly with the Hubble parameter, with concomitant matter production. A previous joint analysis of the redshift-distance relation for type Ia supernovas, barionic acoustic oscillations, and the position of the first peak in the anisotropy spectrum of the cosmic microwave background has led to acceptable values for the cosmological parameters. Here we present our analysis of small perturbations, under the assumption that the cosmological term, and therefore the matter production, are strictly homogeneous. Such a homogeneous production tends to dilute the matter contrast, leading to a late-time suppression in the power spectrum. Nevertheless, an excellent agreement with the observational data can be achieved by using a higher matter density as compared to the concordance value previously obtained. This may indicate that our hypothesis of homogeneous matter production must be relaxed by allowing perturbations in the interacting cosmological term.

  14. f(T,T) gravity and cosmology

    SciTech Connect (OSTI)

    Harko, Tiberiu; Lobo, Francisco S.N.; Otalora, G.; Saridakis, Emmanuel N. E-mail: flobo@cii.fc.ul.pt

    2014-12-01

    We present an extension of f(T) gravity, allowing for a general coupling of the torsion scalar T with the trace of the matter energy-momentum tensor T. The resulting f(T,T) theory is a new modified gravity, since it is different from all the existing torsion or curvature based constructions. Applied to a cosmological framework, it leads to interesting phenomenology. In particular, one can obtain a unified description of the initial inflationary phase, the subsequent non-accelerating, matter-dominated expansion, and then the transition to a late-time accelerating phase. Additionally, the effective dark energy sector can be quintessence or phantom-like, or exhibit the phantom-divide crossing during the evolution. Moreover, in the far future the universe results either to a de Sitter exponential expansion, or to eternal power-law accelerated expansions. Finally, a detailed study of the scalar perturbations at the linear level reveals that f(T,T) cosmology can be free of ghosts and instabilities for a wide class of ansatzes and model parameters.

  15. Quantum Chemistry of CO2 Interaction with Swelling Clays | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of CO2 Interaction with Swelling Clays Quantum Chemistry of CO2 Interaction with Swelling Clays Ubiquitous clay minerals can play an important role in assessing the suitability of geologic formations for secure storage of carbon dioxide (CO2). The minerals may affect the reservoir storage capacity as well as the integrity of its natural seals such as caprock formations. CO2 interaction with swelling clays such as smectites is a complex process involving physisorption in micropores and

  16. Reaction chemistry of cerium

    SciTech Connect (OSTI)

    1997-01-01

    It is truly ironic that a synthetic organic chemist likely has far greater knowledge of the reaction chemistry of cerium(IV) than an inorganic colleague. Cerium(IV) reagents have long since been employed as oxidants in effecting a wide variety of organic transformations. Conversely, prior to the late 1980s, the number of well characterized cerium(IV) complexes did not extend past a handful of known species. Though in many other areas, interest in the molecular chemistry of the 4f-elements has undergone an explosive growth over the last twenty years, the chemistry of cerium(IV) has for the most part been overlooked. This report describes reactions of cerium complexes and structure.

  17. CMR: Chemistry and Metallurgy Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CMR: Chemistry and Metallurgy Research Facility CMR: Chemistry and Metallurgy Research Facility The Los Alamos National Laboratory (LANL) Chemistry and Metallurgy Research (CMR) ...

  18. Analytical Chemistry Laboratory | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Laboratory provides a broad range of analytical chemistry support services to the scientific and engineering programs. AnalyticalChemistryLaboratoryfactsheet...

  19. The Raychaudhuri equation in homogeneous cosmologies

    SciTech Connect (OSTI)

    Albareti, F.D.; Cembranos, J.A.R.; Cruz-Dombriz, A. de la; Dobado, A. E-mail: cembra@fis.ucm.es E-mail: dobado@fis.ucm.es

    2014-03-01

    In this work we address the issue of studying the conditions required to guarantee the Focusing Theorem for both null and timelike geodesic congruences by using the Raychaudhuri equation. In particular we study the case of Friedmann-Robertson-Walker as well as more general Bianchi Type I spacetimes. The fulfillment of the Focusing Theorem is mandatory in small scales since it accounts for the attractive character of gravity. However, the Focusing Theorem is not satisfied at cosmological scales due to the measured negative deceleration parameter. The study of the conditions needed for congruences convergence is not only relevant at the fundamental level but also to derive the viability conditions to be imposed on extended theories of gravity describing the different expansion regimes of the universe. We illustrate this idea for f(R) gravity theories.

  20. Emergent universe in spatially flat cosmological model

    SciTech Connect (OSTI)

    Zhang, Kaituo; Yu, Hongwei; Wu, Puxun E-mail: wpx0227@gmail.com

    2014-01-01

    The scenario of an emergent universe provides a promising resolution to the big bang singularity in universes with positive or negative spatial curvature. It however remains unclear whether the scenario can be successfully implemented in a spatially flat universe which seems to be favored by present cosmological observations. In this paper, we study the stability of Einstein static state solutions in a spatially flat Shtanov-Sahni braneworld scenario. With a negative dark radiation term included and assuming a scalar field as the only matter energy component, we find that the universe can stay at an Einstein static state past eternally and then evolve to an inflation phase naturally as the scalar field climbs up its potential slowly. In addition, we also propose a concrete potential of the scalar field that realizes this scenario.

  1. Cosmology of bigravity with doubly coupled matter

    SciTech Connect (OSTI)

    Comelli, D.; Crisostomi, M.; Koyama, K.; Pilo, L.; Tasinato, G.

    2015-04-20

    We study cosmology in the bigravity formulation of the dRGT model where matter couples to both metrics. At linear order in perturbation theory two mass scales emerge: an hard one from the dRGT potential, and an environmental dependent one from the coupling of bigravity with matter. At early time, the dynamics is dictated by the second mass scale which is of order of the Hubble scale. The set of gauge invariant perturbations that couples to matter follow closely the same behaviour as in GR. The remaining perturbations show no issue in the scalar sector, while problems arise in the tensor and vector sectors. During radiation domination, a tensor mode grows power-like at super-horizon scales. More dangerously, the only propagating vector mode features an exponential instability on sub-horizon scales. We discuss the consequences of such instabilities and speculate on possible ways to deal with them.

  2. LA-2271 CHEMISTRY-GENERAL

    Office of Scientific and Technical Information (OSTI)

    2271 CHEMISTRY-GENERAL TID-4500, 14th Ed. LOS ALAMOS SCIENTIFIC LABORATORY OF THE ... U in Vol. n of A Treatise on Physical Chemistry, edited by H. S. Taylor and S. ...

  3. Cosmology on the Beach - Carlos Frenk: Lecture 1

    ScienceCinema (OSTI)

    Carlos Frenk

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.

  4. Cosmology on the Beach - Chung-Pei Ma: Lecture 2

    ScienceCinema (OSTI)

    Chung-Pei Ma

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009

  5. Constraints on Cosmology from the Cosmic Microwave Background...

    Office of Scientific and Technical Information (OSTI)

    from the Cosmic Microwave Background Power Spectrum of the 2500-square degree SPT-SZ Survey Citation Details In-Document Search Title: Constraints on Cosmology from the Cosmic...

  6. Constraints on Cosmology from the Cosmic Microwave Background...

    Office of Scientific and Technical Information (OSTI)

    Power Spectrum of the 2500-square degree SPT-SZ Survey Citation Details In-Document Search Title: Constraints on Cosmology from the Cosmic Microwave Background Power Spectrum of ...

  7. Observational constraints on late-time {lambda}(t) cosmology

    SciTech Connect (OSTI)

    Carneiro, S.; Pigozzo, C.; Dantas, M. A.; Alcaniz, J. S.

    2008-04-15

    The cosmological constant {lambda}, i.e., the energy density stored in the true vacuum state of all existing fields in the Universe, is the simplest and the most natural possibility to describe the current cosmic acceleration. However, despite its observational successes, such a possibility exacerbates the well-known {lambda} problem, requiring a natural explanation for its small, but nonzero, value. In this paper we study cosmological consequences of a scenario driven by a varying cosmological term, in which the vacuum energy density decays linearly with the Hubble parameter, {lambda}{proportional_to}H. We test the viability of this scenario and study a possible way to distinguish it from the current standard cosmological model by using recent observations of type Ia supernova (Supernova Legacy Survey Collaboration), measurements of the baryonic acoustic oscillation from the Sloan Digital Sky Survey, and the position of the first peak of the cosmic microwave background angular spectrum from the three-year Wilkinson Microwave Anisotropy Probe.

  8. Cosmology on the Beach - Eric Linder, Lecture 2

    ScienceCinema (OSTI)

    Eric Linder

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.  

  9. Cosmology on the Beach - Wayne Hu: Lecture 2

    ScienceCinema (OSTI)

    Wayne Hu

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.

  10. Cosmology on the Beach: Eric Linder, lecture 3

    ScienceCinema (OSTI)

    Eric Linder

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.

  11. Cosmology on the Beach - Eric Linder: Lecture 1

    ScienceCinema (OSTI)

    Eric Linder

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.

  12. Cosmology at the Beach Lecture: Chung-Pei Ma

    ScienceCinema (OSTI)

    Chung-Pei Ma

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.

  13. COSMOLOGICAL PARAMETERS FROM SUPERNOVAE ASSOCIATED WITH GAMMA-RAY BURSTS

    SciTech Connect (OSTI)

    Li, Xue; Hjorth, Jens; Wojtak, Rados?aw, E-mail: lixue@dark-cosmology.dk [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, DK-2100 Copenhagen (Denmark)

    2014-11-20

    We report estimates of the cosmological parameters ? {sub m} and ?{sub ?} obtained using supernovae (SNe) associated with gamma-ray bursts (GRBs) at redshifts up to 0.606. Eight high-fidelity GRB-SNe with well-sampled light curves across the peak are used. We correct their peak magnitudes for a luminosity-decline rate relation to turn them into accurate standard candles with dispersion ? = 0.18mag. We also estimate the peculiar velocity of the low-redshift host galaxy of SN 1998bw using constrained cosmological simulations. In a flat universe, the resulting Hubble diagram leads to best-fit cosmological parameters of (?{sub m},?{sub ?})=(0.58{sub ?0.25}{sup +0.22},0.42{sub ?0.22}{sup +0.25}). This exploratory study suggests that GRB-SNe can potentially be used as standardizable candles to high redshifts to measure distances in the universe and constrain cosmological parameters.

  14. Cosmology on the Beach - Carlos Frenk, Lecture 3

    ScienceCinema (OSTI)

    Carlos Frenk

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.

  15. Cosmology on the Beach - Carlos Frenk, Lecture 2

    ScienceCinema (OSTI)

    Carlos Frenk

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.

  16. Cosmology on the Beach - Chung-Pei Ma, Lecture 3

    ScienceCinema (OSTI)

    Chung-Pei Ma

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.

  17. Cosmology on the Beach - Simon White, Lecture 3

    ScienceCinema (OSTI)

    Simon White

    2010-01-08

    The lecture was delivered as part of the "Cosmology at the Beach" winter school organized by Berkeley Lab's George Smoot in Los Cabos, Mexico from Jan. 12-16, 2009.

  18. High Pressure Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pressure Chemistry - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear

  19. Chemistry of Autoignition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Autoignition - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced

  20. RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; NUCLEAR MEDICINE; HISTORICAL

    Office of Scientific and Technical Information (OSTI)

    The early days Richards, P. 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; NUCLEAR MEDICINE; HISTORICAL ASPECTS; TECHNETIUM 99; COLLOIDS; MOLYBDENUM...

  1. Extensible Computational Chemistry Environment

    Energy Science and Technology Software Center (OSTI)

    2012-08-09

    ECCE provides a sophisticated graphical user interface, scientific visualization tools, and the underlying data management framework enabling scientists to efficiently set up calculations and store, retrieve, and analyze the rapidly growing volumes of data produced by computational chemistry studies. ECCE was conceived as part of the Environmental Molecular Sciences Laboratory construction to solve the problem of researchers being able to effectively utilize complex computational chemistry codes and massively parallel high performance compute resources. Bringing themore » power of these codes and resources to the desktops of researcher and thus enabling world class research without users needing a detailed understanding of the inner workings of either the theoretical codes or the supercomputers needed to run them was a grand challenge problem in the original version of the EMSL. ECCE allows collaboration among researchers using a web-based data repository where the inputs and results for all calculations done within ECCE are organized. ECCE is a first of kind end-to-end problem solving environment for all phases of computational chemistry research: setting up calculations with sophisticated GUI and direct manipulation visualization tools, submitting and monitoring calculations on remote high performance supercomputers without having to be familiar with the details of using these compute resources, and performing results visualization and analysis including creating publication quality images. ECCE is a suite of tightly integrated applications that are employed as the user moves through the modeling process.« less

  2. Next-Generation Cosmology Simulations with HACC: Challenges from Baryons |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility Simulated cluster strong lensing image based on a large halo extracted from the Outer Rim simulation Simulated cluster strong lensing image based on a large halo extracted from the Outer Rim simulation. The Outer Rim simulation was carried out on Mira and is one of the largest cosmological simulations worldwide. Lindsey Bleem, Nan Li, and the HACC team, Argonne National Laboratory; Mike Gladders, University of Chicago Next-Generation Cosmology

  3. Quantum Newtonian cosmology and the biconfluent Heun functions

    SciTech Connect (OSTI)

    Vieira, H. S.; Bezerra, V. B.

    2015-09-15

    We obtain the exact solution of the Schrödinger equation for a particle (galaxy) moving in a Newtonian universe with a cosmological constant, which is given in terms of the biconfluent Heun functions. The first six Heun polynomials of the biconfluent function are written explicitly. The energy spectrum which resembles the one corresponding to the isotropic harmonic oscillator is also obtained. The wave functions as well as the energy levels codify the role played by the cosmological constant.

  4. Future singularities and teleparallelism in loop quantum cosmology

    SciTech Connect (OSTI)

    Bamba, Kazuharu; Haro, Jaume de; Odintsov, Sergei D. E-mail: jaime.haro@upc.edu

    2013-02-01

    We demonstrate how holonomy corrections in loop quantum cosmology (LQC) prevent the Big Rip singularity by introducing a quadratic modification in terms of the energy density ? in the Friedmann equation in the Friedmann-Lematre-Robertson-Walker (FLRW) space-time in a consistent and useful way. In addition, we investigate whether other kind of singularities like Type II,III and IV singularities survive or are avoided in LQC when the universe is filled by a barotropic fluid with the state equation P = ???f(?), where P is the pressure and f(?) a function of ?. It is shown that the Little Rip cosmology does not happen in LQC. Nevertheless, the occurrence of the Pseudo-Rip cosmology, in which the phantom universe approaches the de Sitter one asymptotically, is established, and the corresponding example is presented. It is interesting that the disintegration of bound structures in the Pseudo-Rip cosmology in LQC always takes more time than that in Einstein cosmology. Our investigation on future singularities is generalized to that in modified teleparallel gravity, where LQC and Brane Cosmology in the Randall-Sundrum scenario are the best examples. It is remarkable that F(T) gravity may lead to all the kinds of future singularities including Little Rip.

  5. Hawaii geologic map data | Open Energy Information

    Open Energy Info (EERE)

    geologic map data Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Hawaii geologic map data Published USGS, Date Not Provided DOI Not Provided Check for...

  6. Utah Geological Survey | Open Energy Information

    Open Energy Info (EERE)

    Logo: Utah Geological Survey Name: Utah Geological Survey Address: 1594 W. North Temple Place: Salt Lake City, Utah Zip: 84114-6100 Phone Number: 801.537.3300 Website:...

  7. AASG State Geological Survey | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AASG State Geological Survey AASG State Geological Survey presentation at the April 2013 peer review meeting held in Denver, Colorado.Contributions to the NGDSAASG State Geological Survey aasg__geo_survey_peer2013.pdf (2.44 MB) More Documents & Publications State Geological Survey Contributions to the National Geothermal Data System National Geothermal Data System Architecture Design, Testing and Maintenance National Geothermal Data Systems Data Acquisition and Access

  8. Hanford Borehole Geologic Information System (HBGIS)

    SciTech Connect (OSTI)

    Last, George V.; Mackley, Rob D.; Saripalli, Ratna R.

    2005-09-26

    This is a user's guide for viewing and downloading borehold geologic data through a web-based interface.

  9. Cosmology in general massive gravity theories

    SciTech Connect (OSTI)

    Comelli, D.; Nesti, F.; Pilo, L. E-mail: fabrizio.nesti@aquila.infn.it

    2014-05-01

    We study the cosmological FRW flat solutions generated in general massive gravity theories. Such a model are obtained adding to the Einstein General Relativity action a peculiar non derivative potentials, function of the metric components, that induce the propagation of five gravitational degrees of freedom. This large class of theories includes both the case with a residual Lorentz invariance as well as the case with rotational invariance only. It turns out that the Lorentz-breaking case is selected as the only possibility. Moreover it turns out that that perturbations around strict Minkowski or dS space are strongly coupled. The upshot is that even though dark energy can be simply accounted by massive gravity modifications, its equation of state w{sub eff} has to deviate from -1. Indeed, there is an explicit relation between the strong coupling scale of perturbations and the deviation of w{sub eff} from -1. Taking into account current limits on w{sub eff} and submillimiter tests of the Newton's law as a limit on the possible strong coupling scale, we find that it is still possible to have a weakly coupled theory in a quasi dS background. Future experimental improvements on short distance tests of the Newton's law may be used to tighten the deviation of w{sub eff} form -1 in a weakly coupled massive gravity theory.

  10. Baryonic matter perturbations in decaying vacuum cosmology

    SciTech Connect (OSTI)

    Marttens, R.F. vom; Zimdahl, W.; Hiplito-Ricaldi, W.S. E-mail: wiliam.ricaldi@ufes.br

    2014-08-01

    We consider the perturbation dynamics for the cosmic baryon fluid and determine the corresponding power spectrum for a ?(t)CDM model in which a cosmological term decays into dark matter linearly with the Hubble rate. The model is tested by a joint analysis of data from supernovae of type Ia (SNIa) (Constitution and Union 2.1), baryonic acoustic oscillations (BAO), the position of the first peak of the anisotropy spectrum of the cosmic microwave background (CMB) and large-scale-structure (LSS) data (SDSS DR7). While the homogeneous and isotropic background dynamics is only marginally influenced by the baryons, there are modifications on the perturbative level if a separately conserved baryon fluid is included. Considering the present baryon fraction as a free parameter, we reproduce the observed abundance of the order of 5% independently of the dark-matter abundance which is of the order of 32% for this model. Generally, the concordance between background and perturbation dynamics is improved if baryons are explicitly taken into account.

  11. Finite Cosmology and a CMB Cold Spot

    SciTech Connect (OSTI)

    Adler, R.J.; Bjorken, J.D.; Overduin, J.M.; /Stanford U., HEPL

    2006-03-20

    The standard cosmological model posits a spatially flat universe of infinite extent. However, no observation, even in principle, could verify that the matter extends to infinity. In this work we model the universe as a finite spherical ball of dust and dark energy, and obtain a lower limit estimate of its mass and present size: the mass is at least 5 x 10{sup 23}M{sub {circle_dot}} and the present radius is at least 50 Gly. If we are not too far from the dust-ball edge we might expect to see a cold spot in the cosmic microwave background, and there might be suppression of the low multipoles in the angular power spectrum. Thus the model may be testable, at least in principle. We also obtain and discuss the geometry exterior to the dust ball; it is Schwarzschild-de Sitter with a naked singularity, and provides an interesting picture of cosmogenesis. Finally we briefly sketch how radiation and inflation eras may be incorporated into the model.

  12. Observational tests for ?(t)CDM cosmology

    SciTech Connect (OSTI)

    Pigozzo, C.; Carneiro, S.; Dantas, M.A.; Alcaniz, J.S. E-mail: aldinez@on.br E-mail: alcaniz@on.br

    2011-08-01

    We investigate the observational viability of a class of cosmological models in which the vacuum energy density decays linearly with the Hubble parameter, resulting in a production of cold dark matter particles at late times. Similarly to the flat ?CDM case, there is only one free parameter to be adjusted by the data in this class of ?(t)CDM scenarios, namely, the matter density parameter. To perform our analysis we use three of the most recent SNe Ia compilation sets (Union2, SDSS and Constitution) along with the current measurements of distance to the BAO peaks at z = 0.2 and z = 0.35 and the position of the first acoustic peak of the CMB power spectrum. We show that in terms of ?{sup 2} statistics both models provide good fits to the data and similar results. A quantitative analysis discussing the differences in parameter estimation due to SNe light-curve fitting methods (SALT2 and MLCS2k2) is studied using the current SDSS and Constitution SNe Ia compilations. A matter power spectrum analysis using the 2dFGRS is also performed, providing a very good concordance with the constraints from the SDSS and Constitution MLCS2k2 data.

  13. Cosmological data and indications for new physics

    SciTech Connect (OSTI)

    Benetti, Micol; Gerbino, Martina; Melchiorri, Alessandro; Pagano, Luca; Kinney, William H.; Kolb, Edward W.; Lattanzi, Massimiliano; Riotto, Antonio E-mail: martina.gerbino@roma1.infn.it E-mail: Rocky.Kolb@uchicago.edu E-mail: alessandro.melchiorri@roma1.infn.it E-mail: antonio.riotto@unige.ch

    2013-10-01

    Data from the Atacama Cosmology Telescope (ACT) and the South Pole Telescope (SPT), combined with the nine-year data release from the WMAP satellite, provide very precise measurements of the cosmic microwave background (CMB) angular anisotropies down to very small angular scales. Augmented with measurements from Baryonic Acoustic Oscillations surveys and determinations of the Hubble constant, we investigate whether there are indications for new physics beyond a Harrison-Zel'dovich model for primordial perturbations and the standard number of relativistic degrees of freedom at primordial recombination. All combinations of datasets point to physics beyond the minimal Harrison-Zel'dovich model in the form of either a scalar spectral index different from unity or additional relativistic degrees of freedom at recombination (e.g., additional light neutrinos). Beyond that, the extended datasets including either ACT or SPT provide very different indications: while the extended-ACT (eACT) dataset is perfectly consistent with the predictions of standard slow-roll inflation, the extended-SPT (eSPT) dataset prefers a non-power-law scalar spectral index with a very large variation with scale of the spectral index. Both eACT and eSPT favor additional light degrees of freedom on top of the Harrison-Zel'dovich model. eACT is consistent with zero neutrino masses, while eSPT favors nonzero neutrino masses at more than 95% confidence.

  14. Cosmological constraints on extended Galileon models

    SciTech Connect (OSTI)

    Felice, Antonio De; Tsujikawa, Shinji E-mail: shinji@rs.kagu.tus.ac.jp

    2012-03-01

    The extended Galileon models possess tracker solutions with de Sitter attractors along which the dark energy equation of state is constant during the matter-dominated epoch, i.e. w{sub DE} = ?1?s, where s is a positive constant. Even with this phantom equation of state there are viable parameter spaces in which the ghosts and Laplacian instabilities are absent. Using the observational data of the supernovae type Ia, the cosmic microwave background (CMB), and baryon acoustic oscillations, we place constraints on the tracker solutions at the background level and find that the parameter s is constrained to be s = 0.034{sub ?0.034}{sup +0.327} (95 % CL) in the flat Universe. In order to break the degeneracy between the models we also study the evolution of cosmological density perturbations relevant to the large-scale structure (LSS) and the Integrated-Sachs-Wolfe (ISW) effect in CMB. We show that, depending on the model parameters, the LSS and the ISW effect is either positively or negatively correlated. It is then possible to constrain viable parameter spaces further from the observational data of the ISW-LSS cross-correlation as well as from the matter power spectrum.

  15. Montana Bureau of Mines and Geology Website | Open Energy Information

    Open Energy Info (EERE)

    Web Site: Montana Bureau of Mines and Geology Website Abstract Provides access to digital information on Montana's geology. Author Montana Bureau of Mines and Geology...

  16. CMI Education Course Inventory: Geology Engineering/Geochemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Course Inventory: Geology EngineeringGeochemistry Geology EngineeringGeochemistry Of the six CMI Team members that are educational institutions, five offer courses in Geology....

  17. Database for Regional Geology, Phase 1- A Tool for informing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Database for Regional Geology, Phase 1- A Tool for informing Regional Evaluations of Alternative Geologic Media and Decision Making Database for Regional Geology, Phase 1- A Tool ...

  18. Oregon Department of Geology and Mineral Industries | Open Energy...

    Open Energy Info (EERE)

    Geology and Mineral Industries Jump to: navigation, search Logo: Oregon Department of Geology and Mineral Industries Name: Oregon Department of Geology and Mineral Industries...

  19. Challenges of tomorrow. chemistry

    SciTech Connect (OSTI)

    Steindler, M.J. )

    1989-11-01

    According to the author, nuclear materials are going to play an increasing role in concerns regarding proliferation and international affair, with an increased demand for clean electric power, and in environmental and health and safety issues. Challenges range from detecting a single species in a sea of others at molar ratios of 10-{sup 12}, or smaller, to a knowledge of the fundamental physical chemistry (e.g., thermodynamics, activity coefficients, etc., of a two phase system, containing about 40 materials, at 500{sup 0}C) for the lanthanide and actinide elements produced during reactor operation. Other concerns are identified and discussed.

  20. Synthetic and Mechanistic Chemistry publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthetic and Mechanistic Chemistry » Synthetic and Mechanistic Synthetic and Mechanistic publications Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Dave Thorn Chemistry Program Manager Email Josh Smith Chemistry Communications Email "Research into alternative forms of energy, of which biofuels is a key component, is one of the major national security imperatives of this century.

  1. Henry Taube and Coordination Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Henry Taube and Coordination Chemistry Resources with Additional Information Henry Taube Chuck Painter/Stanford News Service Henry Taube, a Marguerite Blake Wilbur Professor of Chemistry, Emeritus, at Stanford University, received the 1983 Nobel Prize in Chemistry "for his work on the mechanisms of electron transfer reactions, especially in metal complexes" Taube 'received a doctorate from the University of California-Berkeley in 1940 and was an instructor there from 1940-41. "I

  2. Preliminary Geologic Characterization of West Coast States for Geologic Sequestration

    SciTech Connect (OSTI)

    Larry Myer

    2005-09-29

    Characterization of geological sinks for sequestration of CO{sub 2} in California, Nevada, Oregon, and Washington was carried out as part of Phase I of the West Coast Regional Carbon Sequestration Partnership (WESTCARB) project. Results show that there are geologic storage opportunities in the region within each of the following major technology areas: saline formations, oil and gas reservoirs, and coal beds. The work focused on sedimentary basins as the initial most-promising targets for geologic sequestration. Geographical Information System (GIS) layers showing sedimentary basins and oil, gas, and coal fields in those basins were developed. The GIS layers were attributed with information on the subsurface, including sediment thickness, presence and depth of porous and permeable sandstones, and, where available, reservoir properties. California offers outstanding sequestration opportunities because of its large capacity and the potential of value-added benefits from enhanced oil recovery (EOR) and enhanced gas recovery (EGR). The estimate for storage capacity of saline formations in the ten largest basins in California ranges from about 150 to about 500 Gt of CO{sub 2}, depending on assumptions about the fraction of the formations used and the fraction of the pore volume filled with separate-phase CO{sub 2}. Potential CO{sub 2}-EOR storage was estimated to be 3.4 Gt, based on a screening of reservoirs using depth, an API gravity cutoff, and cumulative oil produced. The cumulative production from gas reservoirs (screened by depth) suggests a CO{sub 2} storage capacity of 1.7 Gt. In Oregon and Washington, sedimentary basins along the coast also offer sequestration opportunities. Of particular interest is the Puget Trough Basin, which contains up to 1,130 m (3,700 ft) of unconsolidated sediments overlying up to 3,050 m (10,000 ft) of Tertiary sedimentary rocks. The Puget Trough Basin also contains deep coal formations, which are sequestration targets and may have

  3. The Atacama Cosmology Telescope: cosmological parameters from three seasons of data

    SciTech Connect (OSTI)

    Sievers, Jonathan L.; Appel, John William; Hlozek, Renée A.; Nolta, Michael R.; Battaglia, Nick; Bond, J. Richard; Acquaviva, Viviana; Addison, Graeme E.; Amiri, Mandana; Battistelli, Elia S.; Burger, Bryce; Ade, Peter A. R.; Aguirre, Paula; Barrientos, L. Felipe; Brown, Ben; Calabrese, Erminia; Chervenak, Jay; Das, Sudeep; Devlin, Mark J.; and others

    2013-10-01

    We present constraints on cosmological and astrophysical parameters from high-resolution microwave background maps at 148 GHz and 218 GHz made by the Atacama Cosmology Telescope (ACT) in three seasons of observations from 2008 to 2010. A model of primary cosmological and secondary foreground parameters is fit to the map power spectra and lensing deflection power spectrum, including contributions from both the thermal Sunyaev-Zeldovich (tSZ) effect and the kinematic Sunyaev-Zeldovich (kSZ) effect, Poisson and correlated anisotropy from unresolved infrared sources, radio sources, and the correlation between the tSZ effect and infrared sources. The power ℓ{sup 2}C{sub ℓ}/2π of the thermal SZ power spectrum at 148 GHz is measured to be 3.4±1.4  μK{sup 2} at ℓ = 3000, while the corresponding amplitude of the kinematic SZ power spectrum has a 95% confidence level upper limit of 8.6  μK{sup 2}. Combining ACT power spectra with the WMAP 7-year temperature and polarization power spectra, we find excellent consistency with the LCDM model. We constrain the number of effective relativistic degrees of freedom in the early universe to be N{sub eff} = 2.79±0.56, in agreement with the canonical value of N{sub eff} = 3.046 for three massless neutrinos. We constrain the sum of the neutrino masses to be Σm{sub ν} < 0.39 eV at 95% confidence when combining ACT and WMAP 7-year data with BAO and Hubble constant measurements. We constrain the amount of primordial helium to be Y{sub p} = 0.225±0.034, and measure no variation in the fine structure constant α since recombination, with α/α{sub 0} = 1.004±0.005. We also find no evidence for any running of the scalar spectral index, dn{sub s}/dln k = −0.004±0.012.

  4. Department of Chemistry | Center for Catalytic HydrocarbonFunctionali...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Faculty & Research Outreach Programs Graduate Studies Events & Seminars ... electrochemistry, bioinorganic chemistry, materials chemistry and quantum mechanics. ...

  5. Parallel halo finding in N-body cosmology simulations

    SciTech Connect (OSTI)

    Pfitzner, D.W.; Salmon, J.K.

    1996-12-31

    Cosmological N-body simulations on parallel computers produce large datasets - about five hundred Megabytes at a single output time, or tens of Gigabytes over the course of a simulation. These large datasets require further analysis before they can be compared to astronomical observations. We have implemented two methods for performing halo finding, a key part of the knowledge discovery process, on parallel machines. One of these is a parallel implementation of the friends of friends (FOF) algorithm, widely used in the field of N-body cosmology. The new isodensity (ID) method has been developed to overcome some of the shortcomings of FOR Both have been implemented on a variety of computer systems, and successfully used to extract halos from simulations with up to 256{sup 3} (or about 16.8 million) particles, which axe among the largest N-body cosmology simulations in existence.

  6. Theoretical Research in Cosmology, High-Energy Physics and String Theory

    SciTech Connect (OSTI)

    Ng, Y Jack; Dolan, Louise; Mersini-Houghton, Laura; Frampton, Paul

    2013-07-29

    The research was in the area of Theoretical Physics: Cosmology, High-Energy Physics and String Theory

  7. Cosmological neutrino mass detection: The Best probe of neutrino lifetime

    SciTech Connect (OSTI)

    Serpico, Pasquale D.; /Fermilab

    2007-01-01

    Future cosmological data may be sensitive to the effects of a finite sum of neutrino masses even as small as {approx}0.06 eV, the lower limit guaranteed by neutrino oscillation experiments. We show that a cosmological detection of neutrino mass at that level would improve by many orders of magnitude the existing limits on neutrino lifetime, and as a consequence on neutrino secret interactions with (quasi-)massless particles as in majoron models. On the other hand, neutrino decay may provide a way-out to explain a discrepancy {approx}< 0.1 eV between cosmic neutrino bounds and Lab data.

  8. Duality linking standard and tachyon scalar field cosmologies

    SciTech Connect (OSTI)

    Avelino, P. P.; Bazeia, D.; Losano, L.; Oliveira, J. C. R. E.; Pavan, A. B.

    2010-09-15

    In this work we investigate the duality linking standard and tachyon scalar field homogeneous and isotropic cosmologies in N+1 dimensions. We determine the transformation between standard and tachyon scalar fields and between their associated potentials, corresponding to the same background evolution. We show that, in general, the duality is broken at a perturbative level, when deviations from a homogeneous and isotropic background are taken into account. However, we find that for slow-rolling fields the duality is still preserved at a linear level. We illustrate our results with specific examples of cosmological relevance, where the correspondence between scalar and tachyon scalar field models can be calculated explicitly.

  9. Implementing the DC Mode in Cosmological Simulations with Supercomoving Variables

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gnedin, Nickolay Y; Kravtsov, Andrey V; Rudd, Douglas H

    2011-06-02

    As emphasized by previous studies, proper treatment of the density fluctuation on the fundamental scale of a cosmological simulation volume - the 'DC mode' - is critical for accurate modeling of spatial correlations on scales ~> 10% of simulation box size. We provide further illustration of the effects of the DC mode on the abundance of halos in small boxes and show that it is straightforward to incorporate this mode in cosmological codes that use the 'supercomoving' variables. The equations governing evolution of dark matter and baryons recast with these variables are particularly simple and include the expansion factor, andmorehence the effect of the DC mode, explicitly only in the Poisson equation.less

  10. Classical and quantum aspects of brane-world cosmology

    SciTech Connect (OSTI)

    Cordero, Ruben; Rojas, Efrain

    2011-10-14

    We give a brief overview of several models in brane-world cosmology. In particular, we focus on the asymmetric DGP and Regge-Teiltelboim models. We present the associated equations of motion governing the dynamics of the brane and their corresponding Friedmann-like equations. In order to develop the quantum Regge-Teiltelboim type cosmology we construct its Ostrogradski Hamiltonian formalism which naturally leads to the corresponding Wheeler-DeWitt equation. In addition, we comment on possible generalizations for these models including second order derivative geometrical terms.

  11. Evolution of density perturbations in decaying vacuum cosmology: The case of nonzero perturbations in the cosmological term

    SciTech Connect (OSTI)

    Borges, H. A.; Carneiro, S.; Fabris, J. C.

    2008-12-15

    We extend the results of a previous paper where a model of interacting dark energy, with a cosmological term decaying linearly with the Hubble parameter, is tested against the observed mass power spectrum. In spite of the agreement with observations of type Ia supernovas, baryonic acoustic oscillations, and the cosmic microwave background, we had shown previously that no good concordance is achieved if we include the mass power spectrum. However, our analysis was based on the ad hoc assumption that the interacting cosmological term is strictly homogeneous. Now we perform a more complete analysis, by perturbing such a term. Although our conclusions are still based on a particular, scale-invariant choice of the primordial spectrum of dark energy perturbations, we show that a cosmological term decaying linearly with the Hubble parameter is indeed disfavored as compared to the standard model.

  12. Chemistry for Measurement and Detection Science publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry for Measurement and Detection Science » Chemistry for Measurement and Detection Science publications Chemistry for Measurement and Detection Science publications Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Randy Drake Actinide Analytical Chemistry Email Kirk Rector Physical Chemistry & Applied Spectroscopy Email Josh Smith Chemistry Communications Email Los Alamos is one of

  13. Regional geophysics, Cenozoic tectonics and geologic resources...

    Open Energy Info (EERE)

    and geologic resources of the Basin and Range Province and adjoining regions Author G.P. Eaton Conference Basin and Range Symposium and Great Basin Field Conference; Denver,...

  14. Wyoming State Geological Survey | Open Energy Information

    Open Energy Info (EERE)

    navigation, search Name: Wyoming State Geological Survey Abbreviation: WSGS Address: P.O. Box 1347 Place: Laramie, Wyoming Zip: 82073 Year Founded: 1933 Phone Number:...

  15. Geological and Anthropogenic Factors Influencing Mercury Speciation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... or greater, although a few samples with Hg concentrations below 100 ppm were also successfully analyzed using EXAFS spectroscopy. Effect of Geological Background on Hg Speciation ...

  16. Gable named Geological Society of America Fellow

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gable was a member of a large team that received a Laboratory Distinguished Performance Award for the Yucca Mountain Project. About the Geological Society of America Established in ...

  17. Exhaust Phosphorous Chemistry and Catalyst Poisoning | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chemistry and Catalyst Poisoning Exhaust Phosphorous Chemistry and Catalyst Poisoning 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: Oak Ridge National ...

  18. NREL: Transportation Research - Fuel Chemistry Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Research Photo of a hand holding a beaker containing a clear yellow liquid. NREL ... Photo by Dennis Schroeder, NREL NREL's fuel chemistry research explores how biofuels, ...

  19. Martin Karplus Wins Nobel Prize in Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Home News & Publications News Center News Martin Karplus Wins Nobel Prize in Chemistry Martin Karplus Wins Nobel Prize in Chemistry October 9, 2013 Contact: Linda Vu, ...

  20. Computational Actinide Chemistry: Reliable Predictions and New...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computational Actinide Chemistry: Reliable Predictions and New Concepts PI Name: David ... 100 Million Year: 2014 Research Domain: Chemistry The project will obtain some of the ...

  1. Redox Chemistry of Anthraquinone Derivatives Via Simulations...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    August 27, 2014, Research Highlights Redox Chemistry of Anthraquinone Derivatives Via ... S. Assary, Investigation of the Redox Chemistry of Anthraquinone Derivatives Using ...

  2. Understanding and Manipulating Solution Chemistry of Polysulfides...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Understanding and Manipulating Solution Chemistry of Polysulfides for Lithium Sulfur Batteries (Top)Fundamental details regarding the solution chemistry of polysulfides in organic ...

  3. Chemistry and Material Sciences Codes at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry and Material Sciences Codes Chemistry and Material Sciences Codes at NERSC April 6, 2011 Last edited: 2016-04-29 11:35:1

  4. Disformal theories of gravity: from the solar system to cosmology

    SciTech Connect (OSTI)

    Sakstein, Jeremy

    2014-12-01

    This paper is concerned with theories of gravity that contain a scalar coupled both conformally and disformally to matter through the metric. By systematically deriving the non-relativistic limit, it is shown that no new non-linear screening mechanisms are present beyond the Vainshtein mechanism and chameleon-like screening. If one includes the cosmological expansion of the universe, disformal effects that are usually taken to be absent can be present in the solar system. When the conformal factor is absent, fifth-forces can be screened on all scales when the cosmological field is slowly-rolling. We investigate the cosmology of these models and use local tests of gravity to place new constraints on the disformal coupling and find M?>O(eV), which is not competitive with laboratory tests. Finally, we discuss the future prospects for testing these theories and the implications for other theories of modified gravity. In particular, the Vainshtein radius of solar system objects can be altered from the static prediction when cosmological time-derivatives are non-negligible.

  5. Bimetric gravity doubly coupled to matter: theory and cosmological implications

    SciTech Connect (OSTI)

    Akrami, Yashar; Koivisto, Tomi S.; Mota, David F.; Sandstad, Marit E-mail: t.s.koivisto@astro.uio.no E-mail: marit.sandstad@astro.uio.no

    2013-10-01

    A ghost-free theory of gravity with two dynamical metrics both coupled to matter is shown to be consistent and viable. Its cosmological implications are studied, and the models, in particular in the context of partially massless gravity, are found to explain the cosmic acceleration without resorting to dark energy.

  6. Detecting a Lorentz-violating field in cosmology

    SciTech Connect (OSTI)

    Li Baojiu; Barrow, John D.; Mota, David F.

    2008-01-15

    We consider cosmology in the Einstein-Aether theory (the generally covariant theory of gravitation coupled to a dynamical timelike Lorentz-violating vector field) with a linear Ae-Lagrangian. The 3+1 spacetime splitting approach is used to derive covariant and gauge invariant perturbation equations which are valid for a general class of Lagrangians. Restricting attention to the parameter space of these theories which is consistent with local gravity experiments, we show that there are tracking behaviors for the Ae field, both in the background cosmology and at the linear perturbation level. The primordial power spectrum of scalar perturbations in this model is shown to be the same as that predicted by standard general relativity. However, the power spectrum of tensor perturbation is different from that in general relativity, but has a smaller amplitude and so cannot be detected at present. We also study the implications for late-time cosmology and find that the evolution of photon and neutrino anisotropic stresses can source the Ae field perturbation during the radiation and matter dominated epochs, and as a result the CMB and matter power spectra are modified. However, these effects are degenerate with respect to other cosmological parameters, such as neutrino masses and the bias parameter in the observed galaxy spectrum.

  7. FRW quantum cosmology with a generalized Chaplygin gas

    SciTech Connect (OSTI)

    Bouhmadi-Lopez, Mariam; Moniz, Paulo Vargas

    2005-03-15

    Cosmologies with a Chaplygin gas have recently been explored with the objective of explaining the transition from a dust dominated epoch towards an accelerating expansion stage. In this context, we consider the hypothesis that this transition involves a quantum mechanical process. Our analysis is entirely analytical, with the objective of finding explicit mathematical expressions for the different quantum mechanical states and their cosmological implications. We employ a Friedmann-Robertson-Walker (FRW) minisuperspace model, characterized by two Lorentzian sectors, separated by a classically forbidden region. This is the configuration associated with the evolution of a generalized Chaplygin gas in a FRW universe. The Hartle-Hawking and Vilenkin wave functions are then computed, together with the transition amplitudes towards the accelerating epoch. Furthermore, for specific initial conditions we found that the generalized Chaplygin gas parameters become related through an expression involving an integer n. We also introduce a phenomenological association between some brane-world scenarios and a FRW minisuperspace cosmology with a generalized Chaplygin gas. The aim is to promote a discussion and subsequent research on the quantum creation of brane cosmologies from such a perspective. Additional results in this paper suggest that the brane tension would become related with the generalized Chaplygin gas parameters through another expression involving an integer.

  8. Hot atom chemistry and radiopharmaceuticals

    SciTech Connect (OSTI)

    Krohn, Kenneth A.; Moerlein, Stephen M.; Link, Jeanne M.; Welch, Michael J.

    2012-12-19

    The chemical products made in a cyclotron target are a combined result of the chemical effects of the nuclear transformation that made the radioactive atom and the bulk radiolysis in the target. This review uses some well-known examples to understand how hot atom chemistry explains the primary products from a nuclear reaction and then how radiation chemistry is exploited to set up the optimal product for radiosynthesis. It also addresses the chemical effects of nuclear decay. There are important principles that are common to hot atom chemistry and radiopharmaceutical chemistry. Both emphasize short-lived radionuclides and manipulation of high specific activity nuclides. Furthermore, they both rely on radiochromatographic separation for identification of no-carrieradded products.

  9. Henry Taube and Coordination Chemistry

    Office of Scientific and Technical Information (OSTI)

    Taube 'received a doctorate from the University of California-Berkeley in 1940 and was an instructor there from 1940-41. "I became deeply interested in chemistry soon after I came ...

  10. National Nuclear Chemistry Summer School

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Division of Nuclear Chemistry and Technology of the American Chemical Society (ACS) is sponsoring two INTENSIVE six-week Summer Schools in Nuclear and Radiochemistry for undergraduates. Funding is provided by the US Department of Energy.

  11. National Nuclear Chemistry Summer School

    Office of Energy Efficiency and Renewable Energy (EERE)

    he Division of Nuclear Chemistry and Technology of the American Chemical Society (ACS) is sponsoring two INTENSIVE six-week Summer Schools in Nuclear and Radiochemistry for undergraduates. Funding...

  12. Nuclear Science/Nuclear Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nuclear science nuclear chemistry Nuclear Science/Nuclear Chemistry Nuclear Physics The 10-MV tandem accelerator at CAMS provides a platform for conducting nuclear physics experiment both for basic science and lab mission-related programs. For example, we performed a new cross section measurement of the astrophysically important reaction 40Ca(a,g)44Ti in which high purity CaO targets were irradiated with helium ions at several different discrete energies. The reaction rate was measured on-line

  13. Chemistry, Life, and Earth Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ADCLES Chemistry, Life, and Earth Sciences The CLES Directorate is home to world class capabilities in chemistry, bioscience, and earth and environmental sciences. Structural protein research Structural protein research A wide range of protein folding research Field Instrument Deployments and Operations (FIDO) Field Instrument Deployments and Operations (FIDO) Atmospheric science research Quantum Dots Quantum Dots Quantum dot research for energy and light Contact Us Associate Director Nan Sauer

  14. Generic Deep Geologic Disposal Safety Case

    Broader source: Energy.gov [DOE]

    The Generic Deep Geologic Disposal Safety Case presents generic information that is of use in understanding potential deep geologic disposal options (e.g., salt, shale, granite, deep borehole) in the U.S. for used nuclear fuel (UNF) from reactors and high-level radioactive waste (HLW).

  15. SRS Geology/Hydrogeology Environmental Information Document

    SciTech Connect (OSTI)

    Denham, M.E.

    1999-08-31

    The purpose of the Savannah River Site Geology and Hydrogeology Environmental Information Document (EID) is to provide geologic and hydrogeologic information to serve as a baseline to evaluate potential environmental impacts. This EID is based on a summary of knowledge accumulated from research conducted at the Savannah River Site (SRS) and surrounding areas.

  16. Global Warming in Geologic Time

    SciTech Connect (OSTI)

    Archer, David

    2008-02-27

    The notion is pervasive in the climate science community and in the public at large that the climate impacts of fossil fuel CO2 release will only persist for a few centuries. This conclusion has no basis in theory or models of the atmosphere/ ocean carbon cycle, which we review here. The largest fraction of the CO2 recovery will take place on time scales of centuries, as CO2 invades the ocean, but a significant fraction of the fossil fuel CO2, ranging in published models in the literature from 20-60%, remains airborne for a thousand years or longer. Ultimate recovery takes place on time scales of hundreds of thousands of years, a geologic longevity typically associated in public perceptions with nuclear waste. The glacial/interglacial climate cycles demonstrate that ice sheets and sea level respond dramatically to millennial-timescale changes in climate forcing. There are also potential positive feedbacks in the carbon cycle, including methane hydrates in the ocean, and peat frozen in permafrost, that are most sensitive to the long tail of the fossil fuel CO2 in the atmosphere.

  17. Global Warming in Geologic Time

    SciTech Connect (OSTI)

    David Archer

    2008-02-27

    The notion is pervasive in the climate science community and in the public at large that the climate impacts of fossil fuel CO2 release will only persist for a few centuries. This conclusion has no basis in theory or models of the atmosphere / ocean carbon cycle, which we review here. The largest fraction of the CO2 recovery will take place on time scales of centuries, as CO2 invades the ocean, but a significant fraction of the fossil fuel CO2, ranging in published models in the literature from 20-60%, remains airborne for a thousand years or longer. Ultimate recovery takes place on time scales of hundreds of thousands of years, a geologic longevity typically associated in public perceptions with nuclear waste. The glacial / interglacial climate cycles demonstrate that ice sheets and sea level respond dramatically to millennial-timescale changes in climate forcing. There are also potential positive feedbacks in the carbon cycle, including methane hydrates in the ocean, and peat frozen in permafrost, that are most sensitive to the long tail of the fossil fuel CO2 in the atmosphere.

  18. Global Warming in Geologic Time

    ScienceCinema (OSTI)

    David Archer

    2010-01-08

    The notion is pervasive in the climate science community and in the public at large that the climate impacts of fossil fuel CO2 release will only persist for a few centuries. This conclusion has no basis in theory or models of the atmosphere / ocean carbon cycle, which we review here. The largest fraction of the CO2 recovery will take place on time scales of centuries, as CO2 invades the ocean, but a significant fraction of the fossil fuel CO2, ranging in published models in the literature from 20-60%, remains airborne for a thousand years or longer. Ultimate recovery takes place on time scales of hundreds of thousands of years, a geologic longevity typically associated in public perceptions with nuclear waste. The glacial / interglacial climate cycles demonstrate that ice sheets and sea level respond dramatically to millennial-timescale changes in climate forcing. There are also potential positive feedbacks in the carbon cycle, including methane hydrates in the ocean, and peat frozen in permafrost, that are most sensitive to the long tail of the fossil fuel CO2 in the atmosphere.

  19. Chemistry for Measurement and Detection Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry for Measurement and Detection Science Chemistry for Measurement and Detection Science Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Randy Drake Actinide Analytical Chemistry Email Kirk Rector Physical Chemistry & Applied Spectroscopy Email Josh Smith Chemistry Communications Email Los Alamos is one of two FBI "hub" laboratories for analyzing bulk special nuclear

  20. Cosmological and astrophysical constraints on superconducting cosmic strings

    SciTech Connect (OSTI)

    Miyamoto, Koichi; Nakayama, Kazunori E-mail: kazunori@hep-th.phys.s.u-tokyo.ac.jp

    2013-07-01

    We investigate the cosmological and astrophysical constraints on superconducting cosmic strings (SCSs). SCS loops emit strong bursts of electromagnetic waves, which might affect various cosmological and astrophysical observations. We take into account the effect on the CMB anisotropy, CMB blackbody spectrum, BBN, observational implications on radio wave burst and X-ray or ?-ray events, and stochastic gravitational wave background measured by pulsar timing experiments. We then derive constraints on the parameters of SCS from current observations and estimate prospects for detecting SCS signatures in on-going observations. As a result, we find that these constraints exclude broad parameter regions, and also that on-going radio wave observations can probe large parameter space.

  1. The adhesion model as a field theory for cosmological clustering

    SciTech Connect (OSTI)

    Rigopoulos, Gerasimos

    2015-01-01

    The adhesion model has been proposed in the past as an improvement of the Zel'dovich approximation, providing a good description of the formation of the cosmic web. We recast the model as a field theory for cosmological large scale structure, adding a stochastic force to account for power generated from very short, highly non-linear scales that is uncorrelated with the initial power spectrum. The dynamics of this Stochastic Adhesion Model (SAM) is reminiscent of the well known Kardar-Parisi-Zhang equation with the difference that the viscosity and the noise spectrum are time dependent. Choosing the viscosity proportional to the growth factor D restricts the form of noise spectrum through a 1-loop renormalization argument. For this choice, the SAM field theory is renormalizable to one loop. We comment on the suitability of this model for describing the non-linear regime of the CDM power spectrum and its utility as a relatively simple approach to cosmological clustering.

  2. Cosmological viability conditions for f(T) dark energy models

    SciTech Connect (OSTI)

    Setare, M.R.; Mohammadipour, N. E-mail: N.Mohammadipour@uok.ac.ir

    2012-11-01

    Recently f(T) modified teleparallel gravity where T is the torsion scalar has been proposed as the natural gravitational alternative for dark energy. We perform a detailed dynamical analysis of these models and find conditions for the cosmological viability of f(T) dark energy models as geometrical constraints on the derivatives of these models. We show that in the phase space exists two cosmologically viable trajectory which (i) The universe would start from an unstable radiation point, then pass a saddle standard matter point which is followed by accelerated expansion de sitter point. (ii) The universe starts from a saddle radiation epoch, then falls onto the stable matter era and the system can not evolve to the dark energy dominated epoch. Finally, for a number of f(T) dark energy models were proposed in the more literature, the viability conditions are investigated.

  3. Horava-Lifshitz Theory and Applications to Cosmology and Astrophysics

    SciTech Connect (OSTI)

    Wang, Anzhong

    2014-08-14

    This final report describes the activities of the Baylor University Gravity, Cosmology and Astroparticle Physics (GCAP) group on the project: Horava-Lifshitz Theory and Applications to Cosmology and Astrophysics, during the time, August 15, 2010 - August 14, 2014. We are grateful for the financial support provided by the U.S. Department of Energy for this research, which leads to our exceptional success. We are very proud to say that we have achieved all the goals set up in our project and made significant contributions to the understanding of the field. In particular, with this DOE support, we have published 38 articles in the prestigious national/international journals, which have already received about 1000 citations so far.

  4. Cosmological moduli problem in large volume scenario and thermal inflation

    SciTech Connect (OSTI)

    Choi, Kiwoon; Park, Wan-Il; Shin, Chang Sub E-mail: wipark@kias.re.kr

    2013-03-01

    We show that in a large volume scenario of type IIB string or F-theory compactifications, single thermal inflation provides only a partial solution to the cosmological problem of the light volume modulus. We then clarify the conditions for double thermal inflation, being a simple extension of the usual single thermal inflation scenario, to solve the cosmological moduli problem in the case of relatively light moduli masses. Using a specific example, we demonstrate that double thermal inflation can be realized in large volume scenario in a natural manner, and the problem of the light volume modulus can be solved for the whole relevant mass range. We also find that right amount of baryon asymmetry and dark matter can be obtained via a late-time Affleck-Dine mechanism and the decays of the visible sector NLSP to flatino LSP.

  5. Nuclear and particle physics, astrophysics and cosmology (NPAC) capability review

    SciTech Connect (OSTI)

    Redondo, Antonio

    2010-01-01

    The present document represents a summary self-assessment of the status of the Nuclear and Particle Physics, Astrophysics and Cosmology (NPAC) capability across Los Alamos National Laboratory (LANL). For the purpose of this review, we have divided the capability into four theme areas: Nuclear Physics, Particle Physics, Astrophysics and Cosmology, and Applied Physics. For each theme area we have given a general but brief description of the activities under the area, a list of the Laboratory divisions involved in the work, connections to the goals and mission of the Laboratory, a brief description of progress over the last three years, our opinion of the overall status of the theme area, and challenges and issues.

  6. Cosmological Ohm's law and dynamics of non-minimal electromagnetism

    SciTech Connect (OSTI)

    Hollenstein, Lukas; Jain, Rajeev Kumar; Urban, Federico R. E-mail: jain@cp3.dias.sdu.dk

    2013-01-01

    The origin of large-scale magnetic fields in cosmic structures and the intergalactic medium is still poorly understood. We explore the effects of non-minimal couplings of electromagnetism on the cosmological evolution of currents and magnetic fields. In this context, we revisit the mildly non-linear plasma dynamics around recombination that are known to generate weak magnetic fields. We use the covariant approach to obtain a fully general and non-linear evolution equation for the plasma currents and derive a generalised Ohm law valid on large scales as well as in the presence of non-minimal couplings to cosmological (pseudo-)scalar fields. Due to the sizeable conductivity of the plasma and the stringent observational bounds on such couplings, we conclude that modifications of the standard (adiabatic) evolution of magnetic fields are severely limited in these scenarios. Even at scales well beyond a Mpc, any departure from flux freezing behaviour is inhibited.

  7. Self-Consistent Cosmological Simulations of DGP Braneworld Gravity

    SciTech Connect (OSTI)

    Schmidt, Fabian; /Chicago U., Astron. Astrophys. Ctr. /KICP, Chicago

    2009-09-01

    We perform cosmological N-body simulations of the Dvali-Gabadadze-Porrati braneworld model, by solving the full non-linear equations of motion for the scalar degree of freedom in this model, the brane bending mode. While coupling universally to matter, the brane-bending mode has self-interactions that become important as soon as the density field becomes non-linear. These self-interactions lead to a suppression of the field in high-density environments, and restore gravity to General Relativity. The code uses a multi-grid relaxation scheme to solve the non-linear field equation in the quasi-static approximation. We perform simulations of a flat self-accelerating DGP model without cosmological constant. However, the type of non-linear interactions of the brane-bending mode, which are the focus of this study, are generic to a wide class of braneworld cosmologies. The results of the DGP simulations are compared with standard gravity simulations assuming the same expansion history, and with DGP simulations using the linearized equation for the brane bending mode. This allows us to isolate the effects of the non-linear self-couplings of the field which are noticeable already on quasi-linear scales. We present results on the matter power spectrum and the halo mass function, and discuss the behavior of the brane bending mode within cosmological structure formation. We find that, independently of CMB constraints, the self-accelerating DGP model is strongly constrained by current weak lensing and cluster abundance measurements.

  8. Cosmological Simulations for Large-Scale Sky Surveys | Argonne Leadership

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computing Facility Cosmological Simulations for Large-Scale Sky Surveys PI Name: Salman Habib PI Email: habib@anl.gov Institution: Argonne National Laboratory Allocation Program: INCITE Allocation Hours at ALCF: 100 Million Year: 2014 Research Domain: Physics The next generation of large-scale sky surveys aims to establish a new regime of cosmic discovery through fundamental measurements of the universe's geometry and the growth of structure. The aim of this project is to accurately

  9. Power-law cosmology, SN Ia, and BAO

    SciTech Connect (OSTI)

    Dolgov, Aleksander; Halenka, Vitali; Tkachev, Igor E-mail: vithal@umich.edu

    2014-10-01

    We revise observational constraints on the class of models of modified gravity which at low redshifts lead to a power-law cosmology. To this end we use available public data on Supernova Ia and on baryon acoustic oscillations. We show that the expansion regime a(t)?t{sup ?} with ? close to 3/2 in a spatially flat universe is a good fit to these data.

  10. Inflation in Kaluza-Klein cosmology. 2; Freidmann models

    SciTech Connect (OSTI)

    Bleyer, U. ); Schmidt, H.J. )

    1990-12-20

    The conformal relation between scale- invariant fourth-order gravity and Kaluza-Klein models as derived is applied to Friedmann cosmological models. Especially, the results that power-law inflation is an attractor solution can be carried over, but the conformal transformation brings power-law inflation to de Sitter-like exponential inflation, or power-law inflation a {approx} t. This paper reports that results depend essentially on the dimension of the internal space.

  11. Radioactive Waste Management: Study of Spent Fuel Dissolution Rates in Geological Storage Using Dosimetry Modeling and Experimental Verification

    SciTech Connect (OSTI)

    Hansen, Brady; Miller, William

    2011-10-28

    This research will provide improved predictions into the mechanisms and effects of radiolysis on spent nuclear fuel dissolution in a geological respository through accurate dosimetry modeling of the dose to water, mechanistic chemistry modeling of the resulting radiolytic reactions and confirmatory experimental measurements. This work will combine effort by the Nuclear Science and Engineering Institute (NSEI) and the Missouri University Research Reactor (MURR) at the University of Missouri-Columbia, and the expertise and facilities at the Pacific Northwest National Laboratory (PNNL).

  12. Atmospheric Chemistry and Air Pollution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gaffney, Jeffrey S.; Marley, Nancy A.

    2003-01-01

    Atmospheric chemistry is an important discipline for understanding air pollution and its impacts. This mini-review gives a brief history of air pollution and presents an overview of some of the basic photochemistry involved in the production of ozone and other oxidants in the atmosphere. Urban air quality issues are reviewed with a specific focus on ozone and other oxidants, primary and secondary aerosols, alternative fuels, and the potential for chlorine releases to amplify oxidant chemistry in industrial areas. Regional air pollution issues such as acid rain, long-range transport of aerosols and visibility loss, and the connections of aerosols to ozonemore » and peroxyacetyl nitrate chemistry are examined. Finally, the potential impacts of air pollutants on the global-scale radiative balances of gases and aerosols are discussed briefly.« less

  13. Cosmological stability bound in massive gravity and bigravity

    SciTech Connect (OSTI)

    Fasiello, Matteo; Tolley, Andrew J. E-mail: andrew.j.tolley@case.edu

    2013-12-01

    We give a simple derivation of a cosmological bound on the graviton mass for spatially flat FRW solutions in massive gravity with an FRW reference metric and for bigravity theories. This bound comes from the requirement that the kinetic term of the helicity zero mode of the graviton is positive definite. The bound is dependent only on the parameters in the massive gravity potential and the Hubble expansion rate for the two metrics. We derive the decoupling limit of bigravity and FRW massive gravity, and use this to give an independent derivation of the cosmological bound. We recover our previous results that the tension between satisfying the Friedmann equation and the cosmological bound is sufficient to rule out all observationally relevant FRW solutions for massive gravity with an FRW reference metric. In contrast, in bigravity this tension is resolved due to different nature of the Vainshtein mechanism. We find that in bigravity theories there exists an FRW solution with late-time self-acceleration for which the kinetic terms for the helicity-2, helicity-1 and helicity-0 are generically nonzero and positive making this a compelling candidate for a model of cosmic acceleration. We confirm that the generalized bound is saturated for the candidate partially massless (bi)gravity theories but the existence of helicity-1/helicity-0 interactions implies the absence of the conjectured partially massless symmetry for both massive gravity and bigravity.

  14. Non-minimal Higgs inflation and frame dependence in cosmology

    SciTech Connect (OSTI)

    Steinwachs, Christian F.; Kamenshchik, Alexander Yu.

    2013-02-21

    We investigate a very general class of cosmological models with scalar fields non-minimally coupled to gravity. A particular representative in this class is given by the non-minimal Higgs inflation model in which the Standard Model Higgs boson and the inflaton are described by one and the same scalar particle. While the predictions of the non-minimal Higgs inflation scenario come numerically remarkably close to the recently discovered mass of the Higgs boson, there remains a conceptual problem in this model that is associated with the choice of the cosmological frame. While the classical theory is independent of this choice, we find by an explicit calculation that already the first quantum corrections induce a frame dependence. We give a geometrical explanation of this frame dependence by embedding it into a more general field theoretical context. From this analysis, some conceptional points in the long lasting cosmological debate: 'Jordan frame vs. Einstein frame' become more transparent and in principle can be resolved in a natural way.

  15. Cosmology from Cosmic Shear with DES Science Verification Data

    SciTech Connect (OSTI)

    Abbott, T.

    2015-07-20

    We present the first constraints on cosmology from the Dark Energy Survey (DES), using weak lensing measurements from the preliminary Science Verification (SV) data. We use 139 square degrees of SV data, which is less than 3% of the full DES survey area. Using cosmic shear 2-point measurements over three redshift bins we find ?8(m=0.3)0.5 = 0:81 0:06 (68% confidence), after marginalising over 7 systematics parameters and 3 other cosmological parameters. Furthermore, we examine the robustness of our results to the choice of data vector and systematics assumed, and find them to be stable. About 20% of our error bar comes from marginalising over shear and photometric redshift calibration uncertainties. The current state-of-the-art cosmic shear measurements from CFHTLenS are mildly discrepant with the cosmological constraints from Planck CMB data. Our results are consistent with both datasets. Our uncertainties are ~30% larger than those from CFHTLenS when we carry out a comparable analysis of the two datasets, which we attribute largely to the lower number density of our shear catalogue. We investigate constraints on dark energy and find that, with this small fraction of the full survey, the DES SV constraints make negligible impact on the Planck constraints. The moderate disagreement between the CFHTLenS and Planck values of ?8(?m=0.3)0.5 is present regardless of the value of w.

  16. Geological Society of America selects Los Alamos scientist Claudia...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    whose research spans the traditional fields of geology, soil science and climate science. ... whose research spans the traditional fields of geology, soil science and climate science. ...

  17. Rock Physics of Geologic Carbon Sequestration/Storage (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Rock Physics of Geologic Carbon SequestrationStorage Citation Details In-Document Search Title: Rock Physics of Geologic Carbon SequestrationStorage This report ...

  18. Idaho Geological Survey and University of Idaho Explore for Geothermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Idaho Geological Survey and University of Idaho Explore for Geothermal Energy Idaho Geological Survey and University of Idaho Explore for Geothermal Energy January 11, 2013 -...

  19. Summary of geology of Colorado related to geothermal potential...

    Open Energy Info (EERE)

    Journal Article: Summary of geology of Colorado related to geothermal potential Author L.T. Grose Published Journal Colorado Geological Survey Bulletin, 1974 DOI Not Provided...

  20. Geologic Sequestration Training and Research Projects

    Office of Energy Efficiency and Renewable Energy (EERE)

    In September 2009, the U.S. Department of Energy announced more than $12.7 million in funding for geologic sequestration training and research projects. The 43 projects will offer training...

  1. North Carolina Geological Survey | Open Energy Information

    Open Energy Info (EERE)

    Address: 1612 Mail Service Center Place: North Carolina Zip: 27699-1612 Website: www.geology.enr.state.nc.us Coordinates: 35.67, -78.66 Show Map Loading map......

  2. Family Chemistry | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Family Chemistry Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) Click to share on LinkedIn (Opens in new window) Click to share on Tumblr (Opens in new window) Family Chemistry Family gathers at the dinner table and, sometimes, the conference table or the science lab. Paul and Mark Buckley both work at the Global Research Center in Niskayuna, New York and, collectively, have more than 45 years of experience

  3. Panel 2, Geologic Storage of Hydrogen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. SAND2014-3954P Geologic Storage of Hydrogen Anna S. Lord Geologist Geotechnology & Engineering Department & Peter H. Kobos Principal Staff Economist, Ph.D. Earth Systems Department 2 Geologic Storage Why underground storage?

  4. Consequences of CCD imperfections for cosmology determined by weak lensing surveys: from laboratory measurements to cosmological parameter bias

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Okura, Yuki; Petri, Andrea; May, Morgan; Plazas, Andrés A.; Tamagawa, Toru

    2016-06-27

    Weak gravitational lensing causes subtle changes in the apparent shapes of galaxies due to the bending of light by the gravity of foreground masses. By measuring the shapes of large numbers of galaxies (millions in recent surveys, up to tens of billions in future surveys) we can infer the parameters that determine cosmology. Imperfections in the detectors used to record images of the sky can introduce changes in the apparent shape of galaxies, which in turn can bias the inferred cosmological parameters. Here in this paper we consider the effect of two widely discussed sensor imperfections: tree-rings, due to impuritymore » gradients which cause transverse electric fields in the Charge-Coupled Devices (CCD), and pixel-size variation, due to periodic CCD fabrication errors. These imperfections can be observed when the detectors are subject to uniform illumination (flat field images). We develop methods to determine the spurious shear and convergence (due to the imperfections) from the flat-field images. We calculate how the spurious shear when added to the lensing shear will bias the determination of cosmological parameters. We apply our methods to candidate sensors of the Large Synoptic Survey Telescope (LSST) as a timely and important example, analyzing flat field images recorded with LSST prototype CCDs in the laboratory. In conclusion, we find that tree-rings and periodic pixel-size variation present in the LSST CCDs will introduce negligible bias to cosmological parameters determined from the lensing power spectrum, specifically w,Ωm and σ8.« less

  5. Exact analytical solution of the linear structure growth rate in {Lambda}CDM cosmology and its cosmological applications

    SciTech Connect (OSTI)

    Zhang Pengjie [Key Laboratory for Research in Galaxies and Cosmology, Shanghai Astronomical Observatory, Chinese Academy of Science, 80 Nandan Road, Shanghai, China, 200030 (China)

    2011-03-15

    We derive the exact analytical solution of the linear structure growth rate in {Lambda}CDM cosmology with flat or curved geometry, under the Newtonian gauge. Unlike the well known solution under the Newtonian limit [D. J. Heath, Mon. Not. R. Astron. Soc. 179, 351 (1977)], our solution takes all general relativistic corrections into account and is hence valid at both the sub- and superhorizon scales. With this exact solution, we evaluate cosmological impacts induced by these relativistic corrections. (1) General relativistic corrections alter the density growth from z=100 to z=0 by 10% at k=0.01 h/Mpc and the impact becomes stronger toward larger scales. We caution the readers that the overdensity is not gauge invariant and the above statement is restrained to the Newtonian gauge. (2) Relativistic corrections introduce a k{sup -2} scale dependence in the density fluctuation. It mimics a primordial non-Gaussianity of the local type with f{sub NL}{sup local{approx}}1. This systematical error may become non-negligible for future all sky deep galaxy surveys. (3) Cosmological simulations with box size greater than 1 Gpc are also affected by these relativistic corrections. We provide a postprocessing recipe to correct for these effects. (4) These relativistic corrections affect the redshift distortion. However, at redshifts and scales relevant to redshift distortion measurements, such effect is negligible.

  6. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Role of inorganic chemistry on nuclear energy examined Role of inorganic chemistry on nuclear energy examined Inorganic chemistry can provide insight and improve technical issues ...

  7. Environmental geological input into urban construction planning

    SciTech Connect (OSTI)

    Berry, W.B.N. . Dept. of Geology and Geophysics)

    1992-01-01

    Environmental issues resulting from planning new construction in urban areas requires understanding of geological processes at many steps in project development. Steps include: assessments of geological characteristics of the proposed construction site, building design features in light of the geological characteristics, development of the geology component of the EIR as well as any mitigations required, and writing special environmental geological concerns into specifications required of the contractor. The latter step may be exemplified in planning a new underground library being constructed in the center of the Berkeley Campus. The site is within 50 yards of a creek that has been restored such that fish now live in it whereas none could three years ago. Runoff from paved parking lots and walkways around existing buildings goes into storm drains that empty directly into the creek. Because they do, creek water is monitored for chemical and solid wastes as well as turbidity. Based on geological input, special project procedures were written to which the contractor must adhere during site preparation and construction. These include: all liquid wastes must be contained in impermeable containers, all hazardous wastes must be removed under state waste removal guidelines, dewatering procedures were developed to remove groundwater that flows through permeable sands and gravels from the creek bed into the construction site and must be followed, and soil flux into the creek must be prevented. Mitigation of soil flux includes watering areas of the site as soil is excavated. Watering must be monitored because the contractor tends to overwater which flushes soil down nearby storm drains into the creek. As well, soil control monitoring includes preventing the contractor from sweeping soil into the storm drains and flushing it into the creek. Geological input has proven valuable in addressing different environmental concerns.

  8. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Chemistry of Cobalt-Platinum Nanocatalysts Print Monday, 25 February 2013 15:59 Bimetallic cobalt-platinum (CoPt) nanoparticles are ...

  9. George A. Olah, Carbocation and Hydrocarbon Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    George A. Olah, Carbocation and Hydrocarbon Chemistry Resources with Additional Information * Patents George A. Olah Courtesy Rand Larson, Morningstar Productions George Olah received the 1994 Nobel Prize in Chemistry "for his contribution to carbocation chemistry" and his 'role in the chemistry of hydrocarbons. In particular, he developed superacids ... that are much stronger than ordinary acids, are non-nucleophilic, and are fluid at low temperatures. In such media ... carbocations

  10. Eleventh international symposium on radiopharmaceutical chemistry

    SciTech Connect (OSTI)

    1995-12-31

    This document contains abstracts of papers which were presented at the Eleventh International Symposium on Radiopharmaceutical Chemistry. Sessions included: radiopharmaceuticals for the dopaminergic system, strategies for the production and use of labelled reactive small molecules, radiopharmaceuticals for measuring metabolism, radiopharmaceuticals for the serotonin and sigma receptor systems, labelled probes for molecular biology applications, radiopharmaceuticals for receptor systems, radiopharmaceuticals utilizing coordination chemistry, radiolabelled antibodies, radiolabelling methods for small molecules, analytical techniques in radiopharmaceutical chemistry, and analytical techniques in radiopharmaceutical chemistry.

  11. Interfacial Chemistry and Engineering Annual Report 2000

    SciTech Connect (OSTI)

    Grate, Jay W.

    2001-08-01

    This annual report describes the research and staff accomplishments in 2000 for the EMSL Interfacial Chemistry and Engineering Directorate.

  12. Martin Karplus Wins Nobel Prize in Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Home » News & Publications » News » Center News » Martin Karplus Wins Nobel Prize in Chemistry Martin Karplus Wins Nobel Prize in Chemistry October 9, 2013 Contact: Linda Vu, +1 510 495 2402, lvu@lbl.gov Karplus605v1.jpg Martin Karplus On Wednesday, the Nobel Prize in Chemistry was awarded to three scientists for pioneering methods in computational chemistry that have brought a deeper understanding of complex chemical structure and reactions in biochemical systems. These methods can

  13. CMR: Chemistry and Metallurgy Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CMR: Chemistry and Metallurgy Research Facility CMR: Chemistry and Metallurgy Research Facility The Los Alamos National Laboratory (LANL) Chemistry and Metallurgy Research (CMR) building supports research and experimental activities for plutonium and uranium analytical chemistry and metallurgy. CMR capabilities support a number of national security programs, such as non-proliferation and nuclear safeguards. The CMR Facility In 1952, the first LANL CMR facility was completed. At that time, the

  14. The halo model in a massive neutrino cosmology

    SciTech Connect (OSTI)

    Massara, Elena; Villaescusa-Navarro, Francisco; Viel, Matteo E-mail: villaescusa@oats.inaf.it

    2014-12-01

    We provide a quantitative analysis of the halo model in the context of massive neutrino cosmologies. We discuss all the ingredients necessary to model the non-linear matter and cold dark matter power spectra and compare with the results of N-body simulations that incorporate massive neutrinos. Our neutrino halo model is able to capture the non-linear behavior of matter clustering with a ?20% accuracy up to very non-linear scales of k=10 h/Mpc (which would be affected by baryon physics). The largest discrepancies arise in the range k=0.51 h/Mpc where the 1-halo and 2-halo terms are comparable and are present also in a massless neutrino cosmology. However, at scales k<0.2 h/Mpc our neutrino halo model agrees with the results of N-body simulations at the level of 8% for total neutrino masses of <0.3 eV. We also model the neutrino non-linear density field as a sum of a linear and clustered component and predict the neutrino power spectrum and the cold dark matter-neutrino cross-power spectrum up to k=1 h/Mpc with ?30% accuracy. For masses below 0.15 eV the neutrino halo model captures the neutrino induced suppression, casted in terms of matter power ratios between massive and massless scenarios, with a 2% agreement with the results of N-body/neutrino simulations. Finally, we provide a simple application of the halo model: the computation of the clustering of galaxies, in massless and massive neutrinos cosmologies, using a simple Halo Occupation Distribution scheme and our halo model extension.

  15. Statefinder hierarchy of bimetric and galileon models for concordance cosmology

    SciTech Connect (OSTI)

    Myrzakulov, R.; Shahalam, M. E-mail: mdshahalam@ctp-jamia.res.in

    2013-10-01

    In this paper, we use Statefinder hierarchy method to distinguish between bimetric theory of massive gravity, galileon modified gravity and DGP models applied to late time expansion of the universe. We also carry out comparison between bimetric and DGP models using Statefinder pairs (r,s) and (r,q). We show that statefinder diagnostic can differentiate between ?CDM and above mentioned cosmological models of dark energy, and finally show that Statefinder S{sub 2} is an excellent discriminant of ?CDM and modified gravity models.

  16. Viscous gravitational aether and the cosmological constant problem

    SciTech Connect (OSTI)

    Kuang, Xiaomei; Ling, Yi E-mail: yling@ncu.edu.cn

    2009-10-01

    Recently a notion of gravitational aether is advocated to solve the cosmological constant problem. Through the modification of the source of gravity one finds that the effective Newton's constant is source dependent so as to provide a simple but consistent way to decouple gravity from the vacuum energy. However, in the original paper the ratio of the effective Newton's constants for pressureless dust and radiation has an upper bound which is 0.75. In this paper we propose a scheme to loose this bound by introducing a bulk viscosity for the gravitational aether, and expect this improvement will provide more space for matching predictions from this theoretical programm with observational constraints.

  17. Can mirror matter solve the the cosmological lithium problem?

    SciTech Connect (OSTI)

    Coc, Alain [Centre de Sciences Nuclaires et de Sciences de la Matire (CSNSM), CNRS/IN2P3, Universit Paris Sud 11, UMR 8609, Btiment 104, 91405 Orsay Campus (France); Uzan, Jean-Philippe; Vangioni, Elisabeth [Institut d'Astrophysique de Paris, UMR-7095 du CNRS, Universit Pierre et Marie Curie, 98 bis bd Arago, 75014 Paris, France and Sorbonne Universits, Institut Lagrange de Paris, 98 bis bd Arago, 75014 Paris (France)

    2014-05-02

    The abundance of lithium-7 confronts cosmology with a long lasting inconsistency between the predictions of standard Big Bang Nucleosynthesis with the baryonic density determined from the Cosmic Microwave Background observations on the one hand, and the spectroscopic determination of the lithium-7 abundance on the other hand. We investigated the influence of the existence of a mirror world, focusing on models in which mirror neutrons can oscillate into ordinary neutrons. Such a mechanism allows for an effective late time neutron injection, which induces an increase of the destruction of beryllium-7and thus a lower final lithium-7 abundance.

  18. Entropy mode loops and cosmological correlations during perturbative reheating

    SciTech Connect (OSTI)

    Kaya, Ali; Kutluk, Emine Seyma E-mail: seymakutluk@gmail.com

    2015-01-01

    Recently, it has been shown that during preheating the entropy modes circulating in the loops, which correspond to the inflaton decay products, meaningfully modify the cosmological correlation functions at superhorizon scales. In this paper, we determine the significance of the same effect when reheating occurs in the perturbative regime. In a typical two scalar field model, the magnitude of the loop corrections are shown to depend on several parameters like the background inflaton amplitude in the beginning of reheating, the inflaton decay rate and the inflaton mass. Although the loop contributions turn out to be small as compared to the preheating case, they still come out larger than the loop effects during inflation.

  19. Brine flow in heated geologic salt.

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L.; Malama, Bwalya

    2013-03-01

    This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes' governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

  20. Exploration and mining geology. Second edition

    SciTech Connect (OSTI)

    Peters, W.C.

    1987-01-01

    Using the concepts and practices of applied geology as its central theme, here is a balanced and comprehensive treatment of the geological, geochemical, geophysical, and economic elements of exploration and mining. The author offers an overview of the methods and aims in mineral exploration and production and gives coverage of the geologic principles of ore deposits and the geomorphic environment. The text deals with ''hard'' minerals and the nonfluid sources of materials and energy in the continental masses and in ocean basins. This edition has been expanded to include recent advances in applications of satellite imagery, lithogeochemical surveys, isotope geochemistry, and other developments in the field. It also covers current uses of computers in mineral exploration programs and features case histories, a current references section, and financial data.

  1. (Chemistry of the global atmosphere)

    SciTech Connect (OSTI)

    Marland, G.

    1990-09-27

    The traveler attended the conference The Chemistry of the Global Atmosphere,'' and presented a paper on the anthropogenic emission of carbon dioxide (CO{sub 2}) to the atmosphere. The conference included meetings of the International Global Atmospheric Chemistry (IGAC) programme, a core project of the International Geosphere/Biosphere Programme (IGBP) and the traveler participated in meetings on the IGAC project Development of Global Emissions Inventories'' and agreed to coordinate the working group on CO{sub 2}. Papers presented at the conference focused on the latest developments in analytical methods, modeling and understanding of atmospheric CO{sub 2}, CO, CH{sub 4}, N{sub 2}O, SO{sub 2}, NO{sub x}, NMHCs, CFCs, and aerosols.

  2. Chemistry-nuclear chemistry division. Progress report, October 1979-September 1980

    SciTech Connect (OSTI)

    Ryan, R.R. (comp.)

    1981-05-01

    This report presents the research and development programs pursued by the Chemistry-Nuclear Chemistry Division of the Los Alamos National Laboratory. Topics covered include advanced analytical methods, atmospheric chemistry and transport, biochemistry, biomedical research, element migration and fixation, inorganic chemistry, isotope separation and analysis, atomic and molecular collisions, molecular spectroscopy, muonic x rays, nuclear cosmochemistry, nuclear structure and reactions, radiochemical separations, theoretical chemistry, and unclassified weapons research.

  3. Physical Chemistry and Applied Spectroscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PCS Physical Chemistry and Applied Spectroscopy We perform basic and applied research in support of the Laboratory's national security mission and serve a wide range of customers. Contact Us Group Leader Kirk Rector Deputy Group Leader Jeff Pietryga Group Office (505) 667-7121 Postdoctoral researcher Young-Shin Park characterizing emission spectra of LEDs in the Los Alamos National Laboratory optical laboratory. Postdoctoral researcher Young-Shin Park characterizing emission spectra of LEDs in

  4. Physics and Chemistry of Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Physics and Chemistry of Materials Developing new science and technologies needed for the national security of the United States by understanding how basic forces operating at the atomic level manifest themselves in the properties of matter at the macroscopic level. Molecular docking simulations The influence of small organic molecules on the operation and mechanism of electron transfer in enzymatic anodes. Molecular docking simulations The influence of small organic molecules on the operation

  5. IN-PACKAGE CHEMISTRY ABSTRACTION

    SciTech Connect (OSTI)

    E. Thomas

    2005-07-14

    This report was developed in accordance with the requirements in ''Technical Work Plan for Postclosure Waste Form Modeling'' (BSC 2005 [DIRS 173246]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as a function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA). The scope of this report is to describe the development and validation of the in-package chemistry model. The in-package model is a combination of two models, a batch reactor model, which uses the EQ3/6 geochemistry-modeling tool, and a surface complexation model, which is applied to the results of the batch reactor model. The batch reactor model considers chemical interactions of water with the waste package materials, and the waste form for commercial spent nuclear fuel (CSNF) waste packages and codisposed (CDSP) waste packages containing high-level waste glass (HLWG) and DOE spent fuel. The surface complexation model includes the impact of fluid-surface interactions (i.e., surface complexation) on the resulting fluid composition. The model examines two types of water influx: (1) the condensation of water vapor diffusing into the waste package, and (2) seepage water entering the waste package as a liquid from the drift. (1) Vapor-Influx Case: The condensation of vapor onto the waste package internals is simulated as pure H{sub 2}O and enters at a rate determined by the water vapor pressure for representative temperature and relative humidity conditions. (2) Liquid-Influx Case: The water entering a waste package from the drift is simulated as typical groundwater and enters at a rate determined by the amount of seepage available to flow through openings in a breached waste package.

  6. Principles of isotope geology. Second edition

    SciTech Connect (OSTI)

    Faure, G.

    1986-01-01

    This is a text in isotope geology/geoscience that integrates material taught in various courses into a unified picture of the earth sciences. It presents an exposition of the principles used in the interpretation of isotopic data and shows how such interpretations apply to the solution of geological problems. References up to 1985 are included with chapters in this edition. New chapters on Sm-Nd, Lu-Hf Re-Os, and K-Ca decay schemes and cosmogenic radionuclides have been added. Data summaries and references have been expanded.

  7. Method of fracturing a geological formation

    DOE Patents [OSTI]

    Johnson, James O.

    1990-01-01

    An improved method of fracturing a geological formation surrounding a well bore is disclosed. A relatively small explosive charge is emplaced in a well bore and the bore is subsequently hydraulically pressurized to a pressure less than the formation breakdown pressure and preferably greater than the fracture propagation pressure of the formation. The charge is denoted while the bore is so pressurized, resulting in the formation of multiple fractures in the surrounding formation with little or no accompanying formation damage. Subsequent hydraulic pressurization can be used to propagate and extend the fractures in a conventional manner. The method is useful for stimulating production of oil, gas and possibly water from suitable geologic formations.

  8. Some Cosmological Models for Poincare Gauge Gravity and Accelerated Expansion of the Universe

    SciTech Connect (OSTI)

    Mebarki, N.

    2010-10-31

    Two cosmological Models for the Poincare Gauge Gravity theory with a non vanishing torsion are proposed. It is shown that the torsion plays an important role in explaining the accelerated expansion of the universe. Some of the cosmological parameters are also expressed in terms of the redshift and the dark energy scenarios are discussed.

  9. The Geometrization of Matter Proposal in the Barrett-Crane Model and Resolution of Cosmological Problems

    SciTech Connect (OSTI)

    Alexander, Stephon

    2003-07-15

    We give an overview of the current issues in early universe cosmology and consider the potential resolution of these issues in an as yet nascent spin foam cosmology. The model is the Barrett-Crane Model for quantum gravity along with a generalization of manifold complexes to complexes including conical singularities.

  10. EINSTEIN'S SIGNATURE IN COSMOLOGICAL LARGE-SCALE STRUCTURE

    SciTech Connect (OSTI)

    Bruni, Marco; Hidalgo, Juan Carlos; Wands, David

    2014-10-10

    We show how the nonlinearity of general relativity generates a characteristic nonGaussian signal in cosmological large-scale structure that we calculate at all perturbative orders in a large-scale limit. Newtonian gravity and general relativity provide complementary theoretical frameworks for modeling large-scale structure in ?CDM cosmology; a relativistic approach is essential to determine initial conditions, which can then be used in Newtonian simulations studying the nonlinear evolution of the matter density. Most inflationary models in the very early universe predict an almost Gaussian distribution for the primordial metric perturbation, ?. However, we argue that it is the Ricci curvature of comoving-orthogonal spatial hypersurfaces, R, that drives structure formation at large scales. We show how the nonlinear relation between the spatial curvature, R, and the metric perturbation, ?, translates into a specific nonGaussian contribution to the initial comoving matter density that we calculate for the simple case of an initially Gaussian ?. Our analysis shows the nonlinear signature of Einstein's gravity in large-scale structure.