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Sample records for geological research geochemical

  1. A Geological and Hydro-Geochemical Study of the Animas Geothermal...

    Open Energy Info (EERE)

    Hydro-Geochemical Study of the Animas Geothermal Area, Hidalgo County, New Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Geological...

  2. GIS Regional Spatial Data from the Great Basin Center for Geothermal Energy: Geochemical, Geodesic, Geologic, Geophysical, Geothermal, and Groundwater Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Great Basin Center for Geothermal Energy, part of the University of Nevada, Reno, conducts research towards the establishment of geothermal energy as an economically viable energy source within the Great Basin. The Center specializes in collecting and synthesizing geologic, geochemical, geodetic, geophysical, and tectonic data, and using Geographic Information System (GIS) technology to view and analyze this data and to produce favorability maps of geothermal potential. The center also makes its collections of spatial data available for direct download to the public. Data are in Lambert Conformable Conic Projection.

  3. Geologic Sequestration Training and Research Projects

    Broader source: Energy.gov [DOE]

    In September 2009, the U.S. Department of Energy announced more than $12.7 million in funding for geologic sequestration training and research projects. The 43 projects will offer training...

  4. Geochemical Implications of CO2 Leakage Associated with Geologic Storage: A Review

    SciTech Connect (OSTI)

    Harvey, Omar R.; Qafoku, Nikolla; Cantrell, Kirk J.; Brown, Christopher F.

    2012-07-09

    Leakage from deep storage reservoirs is a major risk factor associated with geologic sequestration of carbon dioxide (CO2). Different scientific theories exist concerning the potential implications of such leakage for near-surface environments. The authors of this report reviewed the current literature on how CO2 leakage (from storage reservoirs) would likely impact the geochemistry of near surface environments such as potable water aquifers and the vadose zone. Experimental and modeling studies highlighted the potential for both beneficial (e.g., CO2 re sequestration or contaminant immobilization) and deleterious (e.g., contaminant mobilization) consequences of CO2 intrusion in these systems. Current knowledge gaps, including the role of CO2-induced changes in redox conditions, the influence of CO2 influx rate, gas composition, organic matter content and microorganisms are discussed in terms of their potential influence on pertinent geochemical processes and the potential for beneficial or deleterious outcomes. Geochemical modeling was used to systematically highlight why closing these knowledge gaps are pivotal. A framework for studying and assessing consequences associated with each factor is also presented in Section 5.6.

  5. Geological, geochemical, and geophysical survey of the geothermal resources at Hot Springs Bay Valley, Akutan Island, Alaska

    SciTech Connect (OSTI)

    Motyka, R.J.; Wescott, E.M.; Turner, D.L.; Swanson, S.E.; Romick, J.D.; Moorman, M.A.; Poreda, R.J.; Witte, W.; Petzinger, B.; Allely, R.D.

    1985-01-01

    An extensive survey was conducted of the geothermal resource potential of Hot Springs Bay Valley on Akutan Island. A topographic base map was constructed, geologic mapping, geophysical and geochemical surveys were conducted, and the thermal waters and fumarolic gases were analyzed for major and minor element species and stable isotope composition. (ACR)

  6. Recovery Act: Geologic Sequestration Training and Research (Technical...

    Office of Scientific and Technical Information (OSTI)

    Recovery Act: Geologic Sequestration Training and Research Citation Details In-Document Search Title: Recovery Act: Geologic Sequestration Training and Research Work under the ...

  7. TOUGHREACT: A Simulation Program for Non-isothermal Multiphase Reactive Geochemical Transport in Variably Saturated Geologic M

    Office of Scientific and Technical Information (OSTI)

    TOUGHREACT: A Simulation Program for Non-isothermal Multiphase Reactive Geochemical Transport in Variably Saturated Geologic Media Tianfu Xu, Eric Sonnenthal, Nicolas Spycher , and Karsten Pruess Earth Sciences Division, Lawrence Berkeley National Laboratory University of California, Berkeley, CA 94720, USA Abstract. TOUGHREACT is a numerical simulation program for chemically reactive non-isothermal flows of multiphase fluids in porous and fractured media. The program was written in Fortran 77

  8. Establishing MICHCARB, a geological carbon sequestration research...

    Office of Scientific and Technical Information (OSTI)

    Western Michigan University 58 GEOSCIENCES Geological carbon sequestration Enhanced oil recovery Characterization of oil, gas and saline reservoirs Geological carbon...

  9. Map of Geologic Sequestration Training and Research Projects

    Broader source: Energy.gov [DOE]

    A larger map of FE's Geologic Sequestration Training and Research Projects awarded as part of the Recovery Act.

  10. Deep Borehole Disposal Research: Geological Data Evaluation Alternativ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Deep Borehole Disposal Research: Geological Data Evaluation Alternative Waste Forms and Borehole Seals Citation Details In-Document Search Title: Deep Borehole Disposal Research:...

  11. Deep Borehole Disposal Research: Geological Data Evaluation Alternativ...

    Office of Scientific and Technical Information (OSTI)

    Research: Geological Data Evaluation Alternative Waste Forms and Borehole Seals Arnold, Bill W.; Brady, Patrick; Sutton, Mark; Travis, Karl; MacKinnon, Robert; Gibb, Fergus;...

  12. Geological and geochemical aspects of uranium deposits. A selected, annotated bibliography

    SciTech Connect (OSTI)

    Garland, P.A.; Thomas, J.M.; Brock, M.L.; Daniel, E.W.

    1980-06-01

    A bibliography of 479 references encompassing the fields of uranium and thorium geochemistry and mineralogy, geology of uranium deposits, uranium mining, and uranium exploration techniques has been compiled by the Ecological Sciences Information Center of Oak Ridge National Laboratory. The bibliography was produced for the National Uranium Resource Evaluation Program, which is funded by the Grand Junction Office of the Department of Energy. The references contained in the bibliography have been divided into the following eight subject categories: (1) geology of deposits, (2) geochemistry, (3) genesis O deposits, (4) exploration, (5) mineralogy, (6) uranium industry, (7) reserves and resources, and (8) geology of potential uranium-bearing areas. All categories specifically refer to uranium and thorium; the last category contains basic geologic information concerning areas which the Grand Junction Office feels are particularly favorable for uranium deposition. The references are indexed by author, geographic location, quadrangle name, geoformational feature, taxonomic name, and keyword.

  13. Research Portfolio Report Ultra-Deepwater: Geologic Uncertainty

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geologic Uncertainty Cover Image: 3D visualization of directionally drilled boreholes in the Gulf of Mexico, field MC109, showing NETL's interpretation of two reservoir sand intervals. Research Portfolio Report Ultra-Deepwater: Geologic Uncertainty DOE/NETL-2015/1694 Prepared by: Mari Nichols-Haining, Jennifer Funk, Kathy Bruner, John Oelfke, and Christine Rueter KeyLogic Systems, Inc. National Energy Technology Laboratory (NETL) Contact: James Ammer james.ammer@netl.doe.gov Contract

  14. Geological hazards programs and research in the U. S. A

    SciTech Connect (OSTI)

    Filson, J.R. )

    1988-01-01

    Geological hazards have been studied for centuries, but government support of research to lessen their effects is relatively new. This article briefly describes government programs and research underway in the U.S.A. that are directed towards reducing losses of life and property from earthquakes, volcanic eruptions and landslides. The National Earthquake program is described, including four basic research areas: plate tectonics; estimation of the earthquakes; and effects and hazards assessment. The Volcano Studies Program has three areas of research: fundamentals of volcanoes; hazards assessments; and volcano monitoring. Three research areas are included in landslide studies: land slide processes; prediction; inventory and susceptibility studies.

  15. Drill-hole data, drill-site geology, and geochemical data from the study of Precambrian uraniferous conglomerates of the Medicine Bow Mountains and Sierra Madre of southeastern Wyoming

    SciTech Connect (OSTI)

    Karlstrom, K.E.; Houston, R.S.; Schmidt, T.G.; Inlow, D.; Flurkey, A.J.; Kratochvil, A.L.; Coolidge, C.M.; Sever, C.K.; Quimby, W.F.

    1981-02-01

    This volume is presented as a companion to Volume 1: The Geology and Uranium Potential of Precambrian Conglomerates in the Medicine Bow Mountains and Sierra Madre of Southeastern Wyoming; and to Volume 3: Uranium Assessment for Precambrian Pebble Conglomerates in Southeastern Wyoming. Volume 1 summarized the geologic setting and geologic and geochemical characteristics of uranium-bearing conglomerates in Precambrian metasedimentary rocks of southeastern Wyoming. Volume 3 is a geostatistical resource estimate of U and Th in quartz-pebble conglomerates. This volume contains supporting geochemical data, lithologic logs from 48 drill holes in Precambrian rocks of the Medicine Bow Mountains and Sierra Madre, and drill site geologic maps and cross-sections from most of the holes.

  16. Novel Concepts Research in Geologic Storage of CO2

    SciTech Connect (OSTI)

    Neeraj Gupta

    2007-03-31

    As part of the Department of Energy's (DOE) initiative on developing new technologies for the storage of carbon dioxide (CO{sub 2}) in geologic reservoirs, Battelle has been investigating the feasibility of CO{sub 2} sequestration in the deep saline reservoirs of the Ohio River Valley region. In addition to the DOE, the project is being sponsored by American Electric Power (AEP), BP, Ohio Coal Development Office (OCDO) of the Ohio Air Quality Development Authority, Schlumberger, and Battelle. The main objective of the project is to demonstrate that CO{sub 2} sequestration in deep formations is feasible from engineering and economic perspectives, as well as being an inherently safe practice and one that will be acceptable to the public. In addition, the project is designed to evaluate the geology of deep formations in the Ohio River Valley region in general and in the vicinity of AEP's Mountaineer Power Plant, in order to determine their potential use for conducting a long-term test of CO{sub 2} disposal in deep saline formations. The current technical progress report summarizes activities completed for the January-March 2007 period of the project. As discussed in the report, the main accomplishment was an announcement by AEP to move forward with a {approx}100,000 metric tons CO{sub 2}/year capture and sequestration project at the Mountaineer site. This decision was the outcome of last several years of research under the current DOE funded project involving the technology, site-specific characterization, modeling, risk assessment, etc. This news marks a significant accomplishment for DOE's research program to translate the theoretical potential for carbon sequestration into tangible measures and approaches for the region. The program includes a 30-megawatt thermal product validation at the Mountaineer Plant where up to 100,000 metric tons CO{sub 2}/year will be captured and sequestered in deep rock formations identified in this work. Plans include further steps at Mountaineer with capture and storage at a very expedited pace. Work continued on the design and feasibility support tasks such as development of injection well design options, engineering assessment of CO{sub 2} capture systems, permitting, and assessment of monitoring technologies as they apply to the project site. Overall, the current design feasibility phase of the project has reached a major milestone. Plans to facilitate the next steps of the project will be the main work remaining in this portion of the project as the program moves toward the proposed capture and sequestration system.

  17. Geothermal/Geochemical Database | Open Energy Information

    Open Energy Info (EERE)

    to library Chart: GeothermalGeochemical DatabaseInfo GraphicMapChart Author Nevada Bureau of Mines and Geology Published Nevada Bureau of Mines and Geology, 2012 DOI Not...

  18. Novel Concepts Research in Geologic Storage of CO2

    SciTech Connect (OSTI)

    Neeraj Gupta

    2006-09-30

    As part of the Department of Energy's (DOE) initiative on developing new technologies for the storage of carbon dioxide (CO{sub 2}) in geologic reservoirs, Battelle has been investigating the feasibility of CO{sub 2} sequestration in the deep saline reservoirs of the Ohio River Valley region. In addition to the DOE, the project is being sponsored by American Electric Power (AEP), BP, Ohio Coal Development Office (OCDO) of the Ohio Air Quality Development Authority, Schlumberger, and Battelle. The main objective of the project is to demonstrate that CO{sub 2} sequestration in deep formations is feasible from engineering and economic perspectives, as well as being an inherently safe practice and one that will be acceptable to the public. In addition, the project is designed to evaluate the geology of deep formations in the Ohio River Valley region in general and in the vicinity of AEP's Mountaineer Power Plant, in order to determine their potential use for conducting a long-term test of CO{sub 2} disposal in deep saline formations. The current technical progress report summarizes activities completed for the July-September 2006 period of the project. As discussed in the following report, the main accomplishments were reservoir modeling for the Copper Ridge ''B-zone'' and design and feasibility support tasks. Work continued on the development of injection well design options, engineering assessment of CO2 capture systems, permitting, and assessment of monitoring technologies as they apply to the project site. In addition, an integrated risk analysis of the proposed system was completed. Finally, slipstream capture construction issues were evaluated with AEP to move the project toward an integrated carbon capture and storage system at the Mountaineer site. Overall, the current design feasibility phase project is proceeding according to plans.

  19. Novel Concepts Research in Geologic Storage of CO2

    SciTech Connect (OSTI)

    Neeraj Gupta

    2007-06-30

    As part of the Department of Energy's (DOE) initiative on developing new technologies for the storage of carbon dioxide (CO{sub 2}) in geologic reservoirs, Battelle has been investigating the feasibility of CO{sub 2} sequestration in the deep saline reservoirs of the Ohio River Valley region. In addition to the DOE, the project is being sponsored by American Electric Power (AEP), BP, Ohio Coal Development Office (OCDO) of the Ohio Air Quality Development Authority, Schlumberger, and Battelle. The main objective of the project is to demonstrate that CO{sub 2} sequestration in deep formations is feasible from engineering and economic perspectives, as well as being an inherently safe practice and one that will be acceptable to the public. In addition, the project is designed to evaluate the geology of deep formations in the Ohio River Valley region in general and in the vicinity of AEP's Mountaineer Power Plant, in order to determine their potential use for conducting a long-term test of CO{sub 2} disposal in deep saline formations. The current technical progress report summarizes activities completed for the April-June 2007 period of the project. As discussed in the report, the main accomplishments related to preparation to move forward with a 100,000-300,000 metric tons CO{sub 2}/year capture and sequestration project at the Mountaineer site. The program includes a 10 to 30-megawatt thermal product validation at the Mountaineer Plant where up to 300,000 metric tons CO{sub 2}/year will be captured and sequestered in deep rock formations identified in this work. Design and feasibility support tasks such as development of injection well design options, engineering assessment of CO{sub 2} capture systems, permitting, reservoir storage simulations, and assessment of monitoring technologies as they apply to the project site were developed for the project. Plans to facilitate the next steps of the project will be the main work remaining in this portion of the project as the program moves toward the proposed capture and sequestration system.

  20. Recovery Act: Geologic Sequestration Training and Research (Technical...

    Office of Scientific and Technical Information (OSTI)

    through seal layers, (5) education and training of students through independent research on rock properties and ... Country of Publication: United States Language: English ...

  1. Aging and the geochemical environment

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    This report describes and assesses the aging process and related environmental aspects that may provide useful insights toward postponing some of the inevitable effects of aging. Although the Panel on Aging and the Geochemical Environment is convinced that the geochemical environment is associated with aging, it of course recognizes that other factors may also be significant or, perhaps, more important. Accordingly, the report is intended to enhance the awareness of biomedical and geochemical research scientists, decision makers in related areas, and the lay public interested in an understanding of the relation of the geochemical environment to senescence.

  2. HBH-GEOCHEM-GEOPHY

    Energy Science and Technology Software Center (OSTI)

    003015WKSTN00 Hiereachical Bayesian Model for Combining Geochemical and Geophysical Data for Environmental Applications Software

  3. Nanogeochemistry: Geochemical reactions and mass transfers in nanopores

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Journal Article: Nanogeochemistry: Geochemical reactions and mass transfers in nanopores Citation Details In-Document Search Title: Nanogeochemistry: Geochemical reactions and mass transfers in nanopores Nanopores are ubiquitous in porous geologic media and may account for >90% of total mineral surface areas. Surface chemistry, ion sorption, and the related geochemical reactions within nanopores can be significantly modified by a nanometer-scale space

  4. DOE Research Projects to Examine Promising Geologic Formations for CO2 Storage

    Broader source: Energy.gov [DOE]

    The Department of Energy today announced 11 projects valued at $75.5 million aimed at increasing scientific understanding about the potential of promising geologic formations to safely and permanently store carbon dioxide (CO2).

  5. Geochemical Speciation Mass Transfer

    Energy Science and Technology Software Center (OSTI)

    1985-12-01

    PHREEQC is designed to model geochemical reactions. Based on an ion association aqueous model, PHREEQC can calculate pH, redox potential, and mass transfer as a function of reaction progress. It can be used to describe geochemical processes for both far-field and near-field performance assessment and to evaluate data acquisition needs and test data. It can also calculate the composition of solutions in equilibrium with multiple phases. The data base, including elements, aqueous species, and mineralmore » phases, is independent of the program and is completely user-definable. PHREEQC requires thermodynamic data for each solid, gaseous, or dissolved chemical species being modeled. The two data bases, PREPHR and DEQPAK7, supplied with PHREEQC are for testing purposes only and should not be applied to real problems without first being carefully examined. The conceptual model embodied in PHREEQC is the ion-association model of Pearson and Noronha. In this model a set of mass action equations are established for each ion pair (and controlling solid phases when making mass transfer calculations) along with a set of mass balance equations for each element considered. These sets of equations are coupled using activity coefficient values for each aqueous species and solved using a continued fraction approach for the mass balances combined with a modified Newton-Raphson technique for all other equations. The activity coefficient expressions in PHREEQC include the extended Debye-Huckel, WATEQ Debye-Huckel, and Davies equations from the original United States Geological Survey version of the program. The auxiliary preprocessor program PHTL, which is derived from EQTL, converts EQ3/6 thermodynamic data to PHREEQC format so that the two programs can be compared. PHREEQC can be used to determine solubility limits on the radionuclides present in the waste form. These solubility constraints may be input to the WAPPA leach model.« less

  6. The Modular Borehole Monitoring Program. A research program to optimize well-based monitoring for geologic carbon sequestration

    SciTech Connect (OSTI)

    Freifeld, Barry; Daley, Tom; Cook, Paul; Trautz, Robert; Dodds, Kevin

    2014-12-31

    Understanding the impacts caused by injection of large volumes of CO2 in the deep subsurface necessitates a comprehensive monitoring strategy. While surface-based and other remote geophysical methods can provide information on the general morphology of a CO2 plume, verification of the geochemical conditions and validation of the remote sensing data requires measurements from boreholes that penetrate the storage formation. Unfortunately, the high cost of drilling deep wellbores and deploying instrumentation systems constrains the number of dedicated monitoring borings as well as limits the technologies that can be incorporated in a borehole completion. The objective of the Modular Borehole Monitoring (MBM) Program was to develop a robust suite of well-based tools optimized for subsurface monitoring of CO2 that could meet the needs of a comprehensive well-based monitoring program. It should have enough flexibility to be easily reconfigured for various reservoir geometries and geologies. The MBM Program sought to provide storage operators with a turn-key fully engineered design that incorporated key technologies, function over the decades long time-span necessary for post-closure reservoir monitoring, and meet industry acceptable risk profiles for deep-well installations. While still within the conceptual design phase of the MBM program, the SECARB Anthropogenic Test in Citronelle, Alabama, USA was identified as a deployment site for our engineered monitoring systems. The initial step in designing the Citronelle MBM system was to down-select from the various monitoring tools available to include technologies that we considered essential to any program. Monitoring methods selected included U-tube geochemical sampling, discrete quartz pressure and temperature gauges, an integrated fibre-optic bundle consisting of distributed temperature and heat-pulse sensing, and a sparse string of conventional 3C-geophones. While not originally planned within the initial MBM work scope, the fibre-optic cable was able to also be used for the emergent technology of distributed acoustic sensing. The MBM monitoring string was installed in March, 2012. To date, the Citronelle MBM instruments continue to operate reliably. Results and lessons learned from the Citronelle MBM deployment are addressed along with examples of data being collected.

  7. The Modular Borehole Monitoring Program. A research program to optimize well-based monitoring for geologic carbon sequestration

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Freifeld, Barry; Daley, Tom; Cook, Paul; Trautz, Robert; Dodds, Kevin

    2014-12-31

    Understanding the impacts caused by injection of large volumes of CO2 in the deep subsurface necessitates a comprehensive monitoring strategy. While surface-based and other remote geophysical methods can provide information on the general morphology of a CO2 plume, verification of the geochemical conditions and validation of the remote sensing data requires measurements from boreholes that penetrate the storage formation. Unfortunately, the high cost of drilling deep wellbores and deploying instrumentation systems constrains the number of dedicated monitoring borings as well as limits the technologies that can be incorporated in a borehole completion. The objective of the Modular Borehole Monitoring (MBM)more » Program was to develop a robust suite of well-based tools optimized for subsurface monitoring of CO2 that could meet the needs of a comprehensive well-based monitoring program. It should have enough flexibility to be easily reconfigured for various reservoir geometries and geologies. The MBM Program sought to provide storage operators with a turn-key fully engineered design that incorporated key technologies, function over the decades long time-span necessary for post-closure reservoir monitoring, and meet industry acceptable risk profiles for deep-well installations. While still within the conceptual design phase of the MBM program, the SECARB Anthropogenic Test in Citronelle, Alabama, USA was identified as a deployment site for our engineered monitoring systems. The initial step in designing the Citronelle MBM system was to down-select from the various monitoring tools available to include technologies that we considered essential to any program. Monitoring methods selected included U-tube geochemical sampling, discrete quartz pressure and temperature gauges, an integrated fibre-optic bundle consisting of distributed temperature and heat-pulse sensing, and a sparse string of conventional 3C-geophones. While not originally planned within the initial MBM work scope, the fibre-optic cable was able to also be used for the emergent technology of distributed acoustic sensing. The MBM monitoring string was installed in March, 2012. To date, the Citronelle MBM instruments continue to operate reliably. Results and lessons learned from the Citronelle MBM deployment are addressed along with examples of data being collected.« less

  8. NOVEL CONCEPTS RESEARCH IN GEOLOGIC STORAGE OF CO{sub 2}

    SciTech Connect (OSTI)

    Neeraj Gupta

    2005-02-02

    As part of the Department of Energy's (DOE) initiative on developing new technologies for storage of carbon dioxide in geologic reservoirs, Battelle has been awarded a project to investigate the feasibility of CO{sub 2} sequestration in the deep saline reservoirs in the Ohio River Valley region. This project is the Phase III of Battelle's work under the Novel Concepts in Greenhouse Gas Management grant. In addition to the DOE, the project is being sponsored by American Electric Power (AEP), BP, The Ohio Coal Development Office (OCDO) of the Ohio Department of Development, and Schlumberger. The main objective of the project is to evaluate the geology of deep formations in the Ohio River Valley region in general and in the vicinity of AEP's Mountaineer Power Plant in particular, in order to determine their potential use for conducting a long-term test of CO{sub 2} disposal in deep saline formations and potentially in nearby deep coal seams. This work supports the overall project objective of demonstrating that CO{sub 2} sequestration in deep formations is feasible from engineering and economic perspectives, as well as being an inherently safe practice and one that will be acceptable to the public. The current technical progress report summarizes activities completed for the October through December 2004 period of the project. As discussed in the report, the technical activities focused on initial injection well design, completion of the site characterization report, assessment of monitoring technologies, shipment of coal samples for testing the capture system to Mitsubishi Heavy Industry, and presentation of project progress at several venues. In addition, proposals to DOE for continued funding of the project activities under the current contract and potentially a new contract for development of regional framework were being evaluated and processed.

  9. NOVEL CONCEPTS RESEARCH IN GEOLOGIC STORAGE OF CO2 PHASE III

    SciTech Connect (OSTI)

    Neeraj Gupta

    2006-05-18

    As part of the Department of Energy's (DOE) initiative on developing new technologies for storage of carbon dioxide in geologic reservoirs, Battelle has been investigating the feasibility of CO{sub 2} sequestration in the deep saline reservoirs in the Ohio River Valley region. In addition to the DOE, the project is being sponsored by American Electric Power (AEP), BP, The Ohio Coal Development Office (OCDO) of the Ohio Air Quality Development Authority, Schlumberger, and Battelle. The main objective of the project is to demonstrate that CO{sub 2} sequestration in deep formations is feasible from engineering and economic perspectives, as well as being an inherently safe practice and one that will be acceptable to the public. In addition, the project is designed to evaluate the geology of deep formations in the Ohio River Valley region in general and in the vicinity of AEP's Mountaineer Power Plant in particular, in order to determine their potential use for conducting a long-term test of CO{sub 2} disposal in deep saline formations. The current technical progress report summarizes activities completed for the January-March 2006 period of the project. As discussed in the following report, the main accomplishments were analysis of Copper Ridge ''B-zone'' reservoir test results from the AEP No.1 well and design and feasibility support tasks. Reservoir test results indicate injection potential in the Copper Ridge ''B-zone'' may be significantly higher than anticipated for the Mountaineer site. Work continued on development of injection well design options, engineering assessment of CO{sub 2} capture systems, permitting, and assessment of monitoring technologies as they apply to the project site. In addition, organizational and scheduling issues were addressed to move the project toward an integrated carbon capture and storage system at the Mountaineer site. Overall, the current design feasibility phase project is proceeding according to plans.

  10. NOVEL CONCEPTS RESEARCH IN GEOLOGIC STORAGE OF CO2 PHASE III

    SciTech Connect (OSTI)

    Neeraj Gupta

    2006-01-23

    As part of the Department of Energy's (DOE) initiative on developing new technologies for storage of carbon dioxide in geologic reservoirs, Battelle has been investigating the feasibility of CO{sub 2} sequestration in the deep saline reservoirs in the Ohio River Valley region. In addition to the DOE, the project is being sponsored by American Electric Power (AEP), BP, The Ohio Coal Development Office (OCDO) of the Ohio Air Quality Development Authority, Schlumberger, and Battelle. The main objective of the project is to demonstrate that CO{sub 2} sequestration in deep formations is feasible from engineering and economic perspectives, as well as being an inherently safe practice and one that will be acceptable to the public. In addition, the project is designed to evaluate the geology of deep formations in the Ohio River Valley region in general and in the vicinity of AEP's Mountaineer Power Plant in particular, in order to determine their potential use for conducting a long-term test of CO{sub 2} disposal in deep saline formations. The current technical progress report summarizes activities completed for the October through December 2005 period of the project. As discussed in the following report, the main field activity was reservoir testing in the Copper Ridge ''B-zone'' in the AEP No.1 well. In addition reservoir simulations were completed to assess feasibility of CO{sub 2} injection for the Mountaineer site. These reservoir testing and computer simulation results suggest that injection potential may be substantially more than anticipated for the Mountaineer site. Work also continued on development of injection well design options, engineering assessment of CO{sub 2} capture systems, permitting, and assessment of monitoring technologies as they apply to the project site. Overall, the current design feasibility phase project is proceeding according to plans.

  11. NOVEL CONCEPTS RESEARCH IN GEOLOGIC STORAGE OF CO2 PHASE III

    SciTech Connect (OSTI)

    Neeraj Gupta

    2005-11-04

    As part of the Department of Energy's (DOE) initiative on developing new technologies for storage of carbon dioxide in geologic reservoirs, Battelle has been investigating the feasibility of CO{sub 2} sequestration in the deep saline reservoirs in the Ohio River Valley region. In addition to the DOE, the project is being sponsored by American Electric Power (AEP), BP, The Ohio Coal Development Office (OCDO) of the Ohio Air Quality Development Authority, and Schlumberger. The main objective of the project is to demonstrate that CO{sub 2} sequestration in deep formations is feasible from engineering and economic perspectives, as well as being an inherently safe practice and one that will be acceptable to the public. In addition, the project is designed to evaluate the geology of deep formations in the Ohio River Valley region in general and in the vicinity of AEP's Mountaineer Power Plant in particular, in order to determine their potential use for conducting a long-term test of CO{sub 2} disposal in deep saline formations. The current technical progress report summarizes activities completed for the July through September 2005 period of the project. As discussed in the report, the field activities focused on preparations for reservoir testing in the Copper Ridge ''B-zone'' in the AEP No.1 well. In addition work continued on development of injection well design options, engineering assessment of CO{sub 2} capture systems, reservoir simulations, work on a Class V Underground Injection Control permit, and assessment of monitoring technologies as they apply to the project site. Overall, the current design feasibility phase project is proceeding according to plans.

  12. Geologic development and characteristics of the continental margins, Gulf of Mexico. Research report, 1983-1986

    SciTech Connect (OSTI)

    Coleman, J.M.; Prior, D.B.; Roberts, H.H.

    1986-01-01

    The continental slope of the Gulf Basin covers more than 500,000 sq km and consists of smooth and gently sloping surfaces, prominent escarpments, knolls, intraslope basins, and submarine canyons and channels. It is an area of extremely diverse topographic and sedimentologic conditions. The slope extends from the shelf break, roughly at the 200 m isobath, to the upper limit of the continental rise, at a depth of 2800 m. The most-complex province in the basin, and the one of most interest to the petroleum industry, is the Texas-Louisiana slope, occupying 120,000 sq km and in which bottom slopes range from < 1 deg to > 20 deg around the knolls and basins. The near-surface geology and topography of the slope are functions of the interplay between episodes of rapid shelf-edge and slope progradation and contemporaneous modification of the depositional sequence by diapirism. Development of discrete depo-centers throughout the Neogene results in rapid shelf-edge progradation, often in excess of 15-20 km/my. This rapid progradation of the shelf edge leads to development of thick wedges of sediment accumulation on the continental slope. Oversteeping, high pore pressures in rapidly deposited soft sediments and changes in eustatic sea level cause subaqueous slope instabilities such as landsliding and debris flows. Large scale features such as shelf edge separation scars and landslide related canyons often results from such processes.

  13. Research Project on CO2 Geological Storage and Groundwater Resources: Water Quality Effects Caused by CO2 Intrusion into Shallow Groundwater

    SciTech Connect (OSTI)

    Birkholzer, Jens; Apps, John; Zheng, Liange; Zhang, Yingqi; Xu, Tianfu; Tsang, Chin-Fu

    2008-10-01

    One promising approach to reduce greenhouse gas emissions is injecting CO{sub 2} into suitable geologic formations, typically depleted oil/gas reservoirs or saline formations at depth larger than 800 m. Proper site selection and management of CO{sub 2} storage projects will ensure that the risks to human health and the environment are low. However, a risk remains that CO{sub 2} could migrate from a deep storage formation, e.g. via local high-permeability pathways such as permeable faults or degraded wells, and arrive in shallow groundwater resources. The ingress of CO{sub 2} is by itself not typically a concern to the water quality of an underground source of drinking water (USDW), but it will change the geochemical conditions in the aquifer and will cause secondary effects mainly induced by changes in pH, in particular the mobilization of hazardous inorganic constituents present in the aquifer minerals. Identification and assessment of these potential effects is necessary to analyze risks associated with geologic sequestration of CO{sub 2}. This report describes a systematic evaluation of the possible water quality changes in response to CO{sub 2} intrusion into aquifers currently used as sources of potable water in the United States. Our goal was to develop a general understanding of the potential vulnerability of United States potable groundwater resources in the event of CO{sub 2} leakage. This goal was achieved in two main tasks, the first to develop a comprehensive geochemical model representing typical conditions in many freshwater aquifers (Section 3), the second to conduct a systematic reactive-transport modeling study to quantify the effect of CO{sub 2} intrusion into shallow aquifers (Section 4). Via reactive-transport modeling, the amount of hazardous constituents potentially mobilized by the ingress of CO{sub 2} was determined, the fate and migration of these constituents in the groundwater was predicted, and the likelihood that drinking water standards might be exceeded was evaluated. A variety of scenarios and aquifer conditions was considered in a sensitivity evaluation. The scenarios and conditions simulated in Section 4, in particular those describing the geochemistry and mineralogy of potable aquifers, were selected based on the comprehensive geochemical model developed in Section 3.

  14. NOVEL CONCEPTS RESEARCH IN GEOLOGIC STORAGE OF CO2 PHASE III THE OHIO RIVER VALLEY CO2 STORAGE PROJECT

    SciTech Connect (OSTI)

    Neeraj Gupta

    2005-05-26

    As part of the Department of Energy's (DOE) initiation on developing new technologies for storage of carbon dioxide in geologic reservoir, Battelle has been awarded a project to investigate the feasibility of CO{sub 2} sequestration in the deep saline reservoirs in the Ohio River Valley region. This project is the Phase III of Battelle's work under the Novel Concepts in Greenhouse Gas Management grant. The main objective of the project is to demonstrate that CO{sub 2} sequestration in deep formations is feasible from engineering and economic perspectives, as well as being an inherently safe practice and one that will be acceptable to the public. In addition, the project is designed to evaluate the geology of deep formations in the Ohio River Valley region in general and in the vicinity of AEP's Mountaineer Power Plant in particular, in order to determine their potential use for conducting a long-term test of CO{sub 2} disposal in deep saline formations and potentially in nearby deep coal seams. The current technical progress report summarizes activities completed for the January through March 2005 period of the project. As discussed in the report, the technical activities focused on development of injection well design, preparing a Class V Underground Injection Control permit, assessment of monitoring technologies, analysis of coal samples for testing the capture system by Mitsubishi Heavy Industry, and presentation of project progress at several venues. In addition, related work has progressed on a collaborative risk assessment project with Japan research institute CREIPI and technical application for the Midwest Regional Carbon Sequestration Partnership.

  15. Geologic analysis of Devonian Shale cores

    SciTech Connect (OSTI)

    1982-02-01

    Cleveland Cliffs Iron Company was awarded a DOE contract in December 1977 for field retrieval and laboratory analysis of cores from the Devonian shales of the following eleven states: Michigan, Illinois, Indiana, Ohio, New York, Pennsylvania, West Virginia, Maryland, Kentucky, Tennessee and Virginia. The purpose of this project is to explore these areas to determine the amount of natural gas being produced from the Devonian shales. The physical properties testing of the rock specimens were performed under subcontract at Michigan Technological University (MTU). The study also included LANDSAT information, geochemical research, structural sedimentary and tectonic data. Following the introduction, and background of the project this report covers the following: field retrieval procedures; laboratory procedures; geologic analysis (by state); references and appendices. (ATT)

  16. Study of the isolation system for geologic disposal of radioactive wastes

    SciTech Connect (OSTI)

    Not Available

    1983-01-01

    This study was conducted for the US Department of Energy by a Waste Isolation System Panel of the Board on Radioactive Waste Management under the National Research Council's Commission on Physical Sciences, Mathematics, and Resources. The panel was charged to review the alternative technologies available for the isolation of radioactive waste in mined geologic repositories, evaluate the need for and possible performance benefits from these technologies as potential elements of the isolation system, and identify appropriate technical criteria for choosing among them to achieve satisfactory overall performance of a geologic repository. Information has been acquired through examination of a large body of technical literature, briefings by representatives of government agencies and their industrial and university contractors, in-depth discussions with individual experts in the field, site visits, and calculations by panel members and staff, with deliberations extending over a period of approximately two years. The panel's principal findings are given. Chapters are devoted to: the geologic waste-disposal system; waste characteristics; waste package; conceptual design of repositories; geologic hydrologic, and geochemical properties of geologic waste-disposal systems; overall performance criterion for geologic waste disposal; performance analysis of the geologic waste-disposal system; and natural analogs relevant to geologic disposal. 336 references.

  17. Remote sensing data exploiration for geologic characterization of difficult targets : Laboratory Directed Research and Development project 38703 final report.

    SciTech Connect (OSTI)

    Costin, Laurence S.; Walker, Charles A.; Lappin, Allen R.; Hayat, Majeed M. (University of New Mexico, Albuquerque, NM); Ford, Bridget K.; Paskaleva, Biliana (University of New Mexico, Albuquerque, NM); Moya, Mary M.; Mercier, Jeffrey Alan; Stormont, John C.; Smith, Jody Lynn

    2003-09-01

    Characterizing the geology, geotechnical aspects, and rock properties of deep underground facility sites can enhance targeting strategies for both nuclear and conventional weapons. This report describes the results of a study to investigate the utility of remote spectral sensing for augmenting the geological and geotechnical information provided by traditional methods. The project primarily considered novel exploitation methods for space-based sensors, which allow clandestine collection of data from denied sites. The investigation focused on developing and applying novel data analysis methods to estimate geologic and geotechnical characteristics in the vicinity of deep underground facilities. Two such methods, one for measuring thermal rock properties and one for classifying rock types, were explored in detail. Several other data exploitation techniques, developed under other projects, were also examined for their potential utility in geologic characterization.

  18. GaMin’11 – an international inter-laboratory comparison for geochemical CO₂ - saline fluid - mineral interaction experiments

    SciTech Connect (OSTI)

    Ostertag-Henning, C.; Risse, A.; Thomas, B.; Rosenbauer, R.; Rochelle, C.; Purser, G.; Kilpatrick, A.; Rosenqvist, J.; Yardley, B.; Karamalidis, A.; Griffith, C.; Hedges, S.; Dilmore, R.; Goodman, A.; Black, J.; Haese, R.; Deusner, C.; Bigalke, N.; Haeckel, M.; Fischer, S.; Liebscher, A.; Icenhower, J. P.; Daval, D.; Saldi, G. D.; Knauss, K. G.; Schmidt, M.; Mito, S.; Sorai, M.; Truche, L.

    2014-12-31

    Due to the strong interest in geochemical CO₂-fluid-rock interaction in the context of geological storage of CO₂ a growing number of research groups have used a variety of different experimental ways to identify important geochemical dissolution or precipitation reactions and – if possible – quantify the rates and extent of mineral or rock alteration. In this inter-laboratory comparison the gas-fluid-mineral reactions of three samples of rock-forming minerals have been investigated by 11 experimental labs. The reported results point to robust identification of the major processes in the experiments by most groups. The dissolution rates derived from the changes in composition of the aqueous phase are consistent overall, but the variation could be reduced by using similar corrections for changing parameters in the reaction cells over time. The comparison of experimental setups and procedures as well as of data corrections identified potential improvements for future gas-fluid-rock studies.

  19. Geologic and hydrologic research at the Western New York Nuclear Service Center, West Valley, New York. Final report, August 1982-December 1983

    SciTech Connect (OSTI)

    Albanese, J.R.; Anderson, S.L.; Fakundiny, R.H.; Potter, S.M.; Rogers, W.B.; Whitbeck, L.F.; LaFleur, R.G.; Boothroyd, J.C.; Timson, B.S.

    1984-06-01

    This report is the last in a series by the New York State Geological Survey on studies funded by the US Nuclear Regulatory Commission. The report covers five important aspects of the geology and hydrology of the Western New York Nuclear Service Center, near West Valley, New York: geomorphology, stratigraphy, sedimentology, surface water, and radionuclide analyses. We reviewed past research on these subjects and present new data obtained in the final phase of NYSGS research at the site. Also presented are up-to-date summaries of the present knowledge of geomorphology and stratigraphy. The report contains a significant bibliography of previous West Valley studies. Appendices include a report on the Fall 1983 Drilling Project and the procedures used, history and prognosis of Cattaraugus Creek and tributaries down cutting, and bar modification and landslide processes of Buttermilk Valley. 100 references, 7 figures, 7 tables.

  20. Geochemical Monitoring Considerations for the FutureGen 2.0 Project

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Amonette, James E.; Johnson, Timothy A.; Spencer, Clayton F.; Zhong, Lirong; Szecsody, James E.; Vermeul, Vince R.

    2014-12-31

    Geochemical monitoring is an essential component of a suite of monitoring technologies designed to evaluate CO2 mass balance and detect possible loss of containment at the FutureGen 2.0 geologic sequestration site near Jacksonville, IL. This presentation gives an overview of the potential geochemical approaches and tracer technologies that were considered, and describes the evaluation process by which the most cost-effective and robust of these were selected for implementation

  1. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to Unconfined and Confined Aquifers

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Brown, Christopher F.; Wang, Guohui; Sullivan, E. C.; Lawter, Amanda R.; Harvey, Omar R.; Bowden, Mark

    2013-04-15

    Experimental research work has been conducted and is undergoing at Pacific Northwest National Laboratory (PNNL) to address a variety of scientific issues related with the potential leaks of the carbon dioxide (CO2) gas from deep storage reservoirs. The main objectives of this work are as follows: • Develop a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption and redox reactions) in the aquifer sediments. • Identify prevailing environmental conditions that would dictate one geochemical outcome over another. • Gather useful information to support site selection, risk assessment, policy-making, and public education efforts associated with geological carbon sequestration. In this report, we present results from experiments conducted at PNNL to address research issues related to the main objectives of this effort. A series of batch and column experiments and solid phase characterization studies (quantitative x-ray diffraction and wet chemical extractions with a concentrated acid) were conducted with representative rocks and sediments from an unconfined, oxidizing carbonate aquifer, i.e., Edwards aquifer in Texas, and a confined aquifer, i.e., the High Plains aquifer in Kansas. These materials were exposed to a CO2 gas stream simulating CO2 gas leaking scenarios, and changes in aqueous phase pH and chemical composition were measured in liquid and effluent samples collected at pre-determined experimental times. Additional research to be conducted during the current fiscal year will further validate these results and will address other important remaining issues. Results from these experimental efforts will provide valuable insights for the development of site-specific, generation III reduced order models. In addition, results will initially serve as input parameters during model calibration runs and, ultimately, will be used to test model predictive capability and competency. The results from these investigations will provide useful information to support site selection, risk assessment, and public education efforts associated with geological, deep subsurface CO2 storage and sequestration.

  2. Self-Organized Pattern Formation in Sedimentary Geochemical Systems. (Book)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Book: Self-Organized Pattern Formation in Sedimentary Geochemical Systems. Citation Details In-Document Search Title: Self-Organized Pattern Formation in Sedimentary Geochemical Systems. Abstract not provided. Authors: Wang, Yifeng Publication Date: 2015-09-01 OSTI Identifier: 1228821 Report Number(s): SAND2015-7601B 603562 DOE Contract Number: AC04-94AL85000 Resource Type: Book Publisher: SPEM Publications Research Org: Sandia National Laboratories (SNL-NM), Albuquerque,

  3. Category:Geochemical Techniques | Open Energy Information

    Open Energy Info (EERE)

    Techniques Technique Subcategories This category has only the following subcategory. G + Geochemical Data Analysis (2 categories) 4 pages Pages in category "Geochemical...

  4. Novel Coupled Thermochronometric and Geochemical Investigation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Novel Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners Novel Coupled Thermochronometric and Geochemical ...

  5. INEEL Subregional Conceptual Model Report Volume 2: Summary of Existing Knowledge of Geochemical Influences on the Fate and Transport of Contaminants in the Subsurface at the INEEL

    SciTech Connect (OSTI)

    Paul L. Wichlacz; Robert C. Starr; Brennon Orr

    2003-09-01

    This document summarizes previous descriptions of geochemical system conceptual models for the vadose zone and groundwater zone (aquifer) beneath the Idaho National Engineering and Environmental Laboratory (INEEL). The primary focus is on groundwater because contaminants derived from wastes disposed at INEEL are present in groundwater, groundwater provides a pathway for potential migration to receptors, and because geochemical characteristics in and processes in the aquifer can substantially affect the movement, attenuation, and toxicity of contaminants. The secondary emphasis is perched water bodies in the vadose zone. Perched water eventually reaches the regional groundwater system, and thus processes that affect contaminants in the perched water bodies are important relative to the migration of contaminants into groundwater. Similarly, processes that affect solutes during transport from nearsurface disposal facilities downward through the vadose zone to the aquifer are relevant. Sediments in the vadose zone can affect both water and solute transport by restricting the downward migration of water sufficiently that a perched water body forms, and by retarding solute migration via ion exchange. Geochemical conceptual models have been prepared by a variety of researchers for different purposes. They have been published in documents prepared by INEEL contractors, the United States Geological Survey (USGS), academic researchers, and others. The documents themselves are INEEL and USGS reports, and articles in technical journals. The documents reviewed were selected from citation lists generated by searching the INEEL Technical Library, the INEEL Environmental Restoration Optical Imaging System, and the ISI Web of Science databases. The citation lists were generated using the keywords ground water, groundwater, chemistry, geochemistry, contaminant, INEL, INEEL, and Idaho. In addition, a list of USGS documents that pertain to the INEEL was obtained and manually searched. The documents that appeared to be the most pertinent were selected from further review. These documents are tabulated in the citation list. This report summarizes existing geochemical conceptual models, but does not attempt to generate a new conceptual model or select the ''right'' model. This document is organized as follows. Geochemical models are described in general in Section 2. Geochemical processes that control the transport and fate of contaminants introduced into groundwater are described in Section 3. The natural geochemistry of the Eastern Snake River Plain Aquifer (SRPA) is described in Section 4. The effect of waste disposal on the INEEL subsurface is described in Section 5. The geochemical behavior of the major contaminants is described in Section 6. Section 7 describes the site-specific geochemical models developed for various INEEL facilities.

  6. Microbiological, Geochemical and Hydrologic Processes Controlling Uranium Mobility: An Integrated Field-Scale Subsurface Research Challenge Site at Rifle, Colorado, Quality Assurance Project Plan

    SciTech Connect (OSTI)

    Fix, N. J.

    2008-01-07

    The U.S. Department of Energy (DOE) is cleaning up and/or monitoring large, dilute plumes contaminated by metals, such as uranium and chromium, whose mobility and solubility change with redox status. Field-scale experiments with acetate as the electron donor have stimulated metal-reducing bacteria to effectively remove uranium [U(VI)] from groundwater at the Uranium Mill Tailings Site in Rifle, Colorado. The Pacific Northwest National Laboratory and a multidisciplinary team of national laboratory and academic collaborators has embarked on a research proposed for the Rifle site, the object of which is to gain a comprehensive and mechanistic understanding of the microbial factors and associated geochemistry controlling uranium mobility so that DOE can confidently remediate uranium plumes as well as support stewardship of uranium-contaminated sites. This Quality Assurance Project Plan provides the quality assurance requirements and processes that will be followed by the Rifle Integrated Field-Scale Subsurface Research Challenge Project.

  7. Research project on CO2 geological storage and groundwaterresources: Large-scale hydrological evaluation and modeling of impact ongroundwater systems

    SciTech Connect (OSTI)

    Birkholzer, Jens; Zhou, Quanlin; Rutqvist, Jonny; Jordan,Preston; Zhang,K.; Tsang, Chin-Fu

    2007-10-24

    If carbon dioxide capture and storage (CCS) technologies areimplemented on a large scale, the amounts of CO2 injected and sequesteredunderground could be extremely large. The stored CO2 then replaces largevolumes of native brine, which can cause considerable pressureperturbation and brine migration in the deep saline formations. Ifhydraulically communicating, either directly via updipping formations orthrough interlayer pathways such as faults or imperfect seals, theseperturbations may impact shallow groundwater or even surface waterresources used for domestic or commercial water supply. Possibleenvironmental concerns include changes in pressure and water table,changes in discharge and recharge zones, as well as changes in waterquality. In compartmentalized formations, issues related to large-scalepressure buildup and brine displacement may also cause storage capacityproblems, because significant pressure buildup can be produced. Toaddress these issues, a three-year research project was initiated inOctober 2006, the first part of which is summarized in this annualreport.

  8. International Collaboration Activities in Different Geologic Disposal

    Energy Savers [EERE]

    Environments | Department of Energy Collaboration Activities in Different Geologic Disposal Environments International Collaboration Activities in Different Geologic Disposal Environments This report describes the current status of international collaboration regarding geologic disposal research in the Used Fuel Disposition (UFD) Campaign. To date, UFD's International Disposal R&D Program has established formal collaboration agreements with five international initiatives and several

  9. Aging and the geochemical environment

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    The report describes and assesses the aging process and related environmental aspects. Specific geographic areas of increased and decreased longevity were identified and geochemically characterized in terms of surface rocks, drinking water quality, soils, and abnormal absorption of trace elements by plants. Environmental factors that may be related to increased longevity are discussed. 11 references, 32 figures, 8 tables. (ACR)

  10. Exploration and mining geology. Second edition

    SciTech Connect (OSTI)

    Peters, W.C.

    1987-01-01

    Using the concepts and practices of applied geology as its central theme, here is a balanced and comprehensive treatment of the geological, geochemical, geophysical, and economic elements of exploration and mining. The author offers an overview of the methods and aims in mineral exploration and production and gives coverage of the geologic principles of ore deposits and the geomorphic environment. The text deals with ''hard'' minerals and the nonfluid sources of materials and energy in the continental masses and in ocean basins. This edition has been expanded to include recent advances in applications of satellite imagery, lithogeochemical surveys, isotope geochemistry, and other developments in the field. It also covers current uses of computers in mineral exploration programs and features case histories, a current references section, and financial data.

  11. Interplay between microorganisms and geochemistry in geological carbon storage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Altman, Susan J.; Kirk, Matthew Fletcher; Santillan, Eugenio-Felipe U.; Bennett, Philip C.

    2016-02-28

    Researchers at the Center for Frontiers of Subsurface Energy Security (CFSES) have conducted laboratory and modeling studies to better understand the interplay between microorganisms and geochemistry for geological carbon storage (GCS). We provide evidence of microorganisms adapting to high pressure CO2 conditions and identify factors that may influence survival of cells to CO2 stress. Factors that influenced the ability of cells to survive exposure to high-pressure CO2 in our experiments include mineralogy, the permeability of cell walls and/or membranes, intracellular buffering capacity, and whether cells live planktonically or within biofilm. Column experiments show that, following exposure to acidic water, biomassmore » can remain intact in porous media and continue to alter hydraulic conductivity. Our research also shows that geochemical changes triggered by CO2 injection can alter energy available to populations of subsurface anaerobes and that microbial feedbacks on this effect can influence carbon storage. Our research documents the impact of CO2 on microorganisms and in turn, how subsurface microorganisms can influence GCS. Furthermore, we conclude that microbial presence and activities can have important implications for carbon storage and that microorganisms should not be overlooked in further GCS research.« less

  12. GaMin’11 – an international inter-laboratory comparison for geochemical CO₂ - saline fluid - mineral interaction experiments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ostertag-Henning, C.; Risse, A.; Thomas, B.; Rosenbauer, R.; Rochelle, C.; Purser, G.; Kilpatrick, A.; Rosenqvist, J.; Yardley, B.; Karamalidis, A.; et al

    2014-12-31

    Due to the strong interest in geochemical CO₂-fluid-rock interaction in the context of geological storage of CO₂ a growing number of research groups have used a variety of different experimental ways to identify important geochemical dissolution or precipitation reactions and – if possible – quantify the rates and extent of mineral or rock alteration. In this inter-laboratory comparison the gas-fluid-mineral reactions of three samples of rock-forming minerals have been investigated by 11 experimental labs. The reported results point to robust identification of the major processes in the experiments by most groups. The dissolution rates derived from the changes in compositionmore » of the aqueous phase are consistent overall, but the variation could be reduced by using similar corrections for changing parameters in the reaction cells over time. The comparison of experimental setups and procedures as well as of data corrections identified potential improvements for future gas-fluid-rock studies.« less

  13. Interface Induced Carbonate Mineralization: A Fundamental Geochemical

    Office of Scientific and Technical Information (OSTI)

    Process Relevant to Carbon Sequestration (Technical Report) | SciTech Connect Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Citation Details In-Document Search Title: Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration We have approached the long-standing geochemical question why anhydrous high-Mg carbonate minerals (i.e., magnesite and dolomite) cannot be formed at

  14. Regional Geologic Map

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Lane, Michael

    Shaded relief base with Hot Pot project area, generalized geology, selected mines, and major topographic features

  15. Regional Geologic Map

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Lane, Michael

    2013-06-28

    Shaded relief base with Hot Pot project area, generalized geology, selected mines, and major topographic features

  16. Geochemical Data Analysis | Open Energy Information

    Open Energy Info (EERE)

    Information Provided by Technique Lithology: StratigraphicStructural: Hydrological: Thermal: Dictionary.png Geochemical Data Analysis: No definition has been provided for...

  17. Interface Induced Carbonate Mineralization: A Fundamental Geochemical

    Office of Scientific and Technical Information (OSTI)

    Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Teng, H. Henry PI, The George Washington University PI, The George...

  18. Interface Induced Carbonate Mineralization: A Fundamental Geochemical...

    Office of Scientific and Technical Information (OSTI)

    Sequestration We have approached the long-standing geochemical question why ... prevents Mgsup 2+ and COsub 3sup 2- ions from forming long-range ordered structures. ...

  19. Interface Induced Carbonate Mineralization: A Fundamental Geochemical

    Office of Scientific and Technical Information (OSTI)

    Process Relevant to Carbon Sequestration (Technical Report) | SciTech Connect Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Citation Details In-Document Search Title: Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Mica, biotite, muscovite, diopside, tremolite, ultramafic rock, hematite, Ca-Mg-carbonate, calcite, aragonite, dolomite, crystal nucleation,

  20. Application Of Geochemical Methods In The Search For Geothermal...

    Open Energy Info (EERE)

    Geochemical Methods In The Search For Geothermal Fields Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Application Of Geochemical Methods In...

  1. Book Review - Geochemical Exploration 1982 | Open Energy Information

    Open Energy Info (EERE)

    Book Review - Geochemical Exploration 1982 Jump to: navigation, search OpenEI Reference LibraryAdd to library Book Review: Book Review - Geochemical Exploration 1982 Author R. A....

  2. SRS Geology/Hydrogeology Environmental Information Document

    SciTech Connect (OSTI)

    Denham, M.E.

    1999-08-31

    The purpose of the Savannah River Site Geology and Hydrogeology Environmental Information Document (EID) is to provide geologic and hydrogeologic information to serve as a baseline to evaluate potential environmental impacts. This EID is based on a summary of knowledge accumulated from research conducted at the Savannah River Site (SRS) and surrounding areas.

  3. AASG State Geological Survey

    Broader source: Energy.gov [DOE]

    presentation at the April 2013 peer review meeting held in Denver, Colorado.Contributions to the NGDSAASG State Geological Survey

  4. Geochemical Modeling Of Aqueous Systems

    Energy Science and Technology Software Center (OSTI)

    1995-09-07

    EQ3/6 is a software package for geochemical modeling of aqueous systems. This description pertains to version 7.2b. It addresses aqueous speciation, thermodynamic equilibrium, disequilibrium, and chemical kinetics. The major components of the package are EQ3NR, a speciation-solubility code, and EQ6 a reaction path code. EQ3NR is useful for analyzing groundwater chemistry data, calculating solubility limits, and determining whether certain reactions are in states of equilibrium or disequilibrium. It also initializes EQ6 calculations. EQ6 models themore » consequences of reacting an aqueous solution with a specified set of reactants (e.g., minerals or waste forms). It can also model fluid mixing and the effects of changes in temperature. Each of five supporting data files contain both standard state and activity coefficient-related data. Three support the use of the Davies or B-dot equations for the activity coefficients; the other two support the use of Pitzer''s equations. The temperature range of the thermodynamic data on the data files varies from 25 degrees C only to 0-300 degrees C.« less

  5. Nanogeochemistry: Geochemical reactions and mass transfers in...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Nanogeochemistry: Geochemical reactions and mass transfers in nanopores ... OSTI Identifier: 913493 Report Number(s): SAND2003-0369J Journal ID: ISSN 0091-7613; TRN: ...

  6. Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting

    SciTech Connect (OSTI)

    Mani, Devleena; Kumar, T. Satish; Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V.

    2011-03-15

    The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana-Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r{sup 2} < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

  7. Comparison of methods for geologic storage of carbon dioxide...

    Office of Scientific and Technical Information (OSTI)

    United States Geological Survey (Brennan et al., 2010); ... generated by multiple methods revealed that assessments ... Research Org: National Energy Technology Laboratory - ...

  8. State Geological Survey Contributions to NGDS Data Development...

    Open Energy Info (EERE)

    Arizona Geological Survey Awardee Website http:www.azgs.az.gov Partner 1 Microsoft Research Partner 2 Energy Industry Metadata Standards Working Group Partner 4 String...

  9. Carbon Dioxide Geological Sequestration in Fractured Porous Rocks

    Office of Scientific and Technical Information (OSTI)

    Training and Research on Probabilistic Hydro-Thermo-Mechanical Modeling of Carbon Dioxide Geological Sequestration in Fractured Porous Rocks Gutierrez, Marte 54 ENVIRONMENTAL...

  10. Summary outline of DOE geoscience and geoscience - related research

    SciTech Connect (OSTI)

    Not Available

    1982-02-01

    The Office of Basic Energy Sciences (OBES) supports long-range, basic research in those areas of the geosciences which are relevant to the nation's energy needs. The objective of the Geoscience program is to develop a quantitative and predictive understanding of geological, geophysical and geochemical structures and processes in the solid earth and in solar-terrestrial relationships. This understanding is to assure an effective knowledge base for energy resource recognition, evaluation and utilization in an environmentally acceptable manner. The work is carried out primarily in DOE laboratories and in universities, although some is conducted by other federal agencies and by the National Academy of Sciences. Principal areas of interest include: Geology, Geophysics, and Earth Dynamics; Geochemistry; Energy Resource Recognition, Evaluation and Utilization; Hydrologic and Marine Sciences; and Solar-Terrestrial/Atmospheric Interactions.

  11. Geologic Map of the Neal Hot Springs Geothermal Area - GIS Data

    SciTech Connect (OSTI)

    Faulds, James E.

    2013-03-31

    Neal Hot Springs—ESRI Geodatabase (ArcGeology v1.3): - Contains all the geologic map data, including faults, contacts, folds, unit polygons, and attitudes of strata and faults. - List of stratigraphic units and stratigraphic correlation diagram. - Three cross‐sections. - Locations of production, injection, and exploration wells. - Locations of 40Ar/39Ar samples. - Location of XRF geochemical samples. - 3D model constructed with EarthVision using geologic map data, cross‐sections, drill‐hole data, and geophysics (model not in the ESRI geodatabase).

  12. Geochemical and Geomechanical Effects on Wellbore Cement Fractures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Um, Wooyong; Jung, Hun Bok; Kabilan, Senthil; Fernandez, Carlos A.; Brown, Christopher F.

    2014-12-31

    Experimental studies were conducted using batch reactors, X-ray microtomograpy (XMT), and computational fluid dynamics (CFD) simulation to determine changes in cement fracture surfaces, fluid flow pathways, and permeability with geochemical and geomechanical processes. Composite Portland cement-basalt caprock core with artificial fractures was prepared and reacted with CO2-saturated groundwater at 50°C and 10 MPa for 3 to 3.5 months under static conditions to understand the geochemical and geomechanical effects on the integrity of wellbores containing defects. Cement-basalt interface samples were subjected to mechanical stress at 2.7 MPa before the CO2 reaction. XMT provided three-dimensional (3-D) visualization of the opening and interconnectionmore » of cement fractures due to mechanical stress. After the CO2 reaction, XMT images revealed that calcium carbonate precipitation occurred extensively within the fractures in the cement matrix, but only partially along fractures located at the cement-basalt interface. The permeability calculated based on CFD simulation was in agreement with the experimentally measured permeability. The experimental results imply that the wellbore cement with fractures is likely to be healed during exposure to CO2-saturated groundwater under static conditions, whereas fractures along the cement-caprock interface are still likely to remain vulnerable to the leakage of CO2. CFD simulation for the flow of different fluids (CO2-saturated brine and supercritical CO2) using a pressure difference of 20 kPa and 200 kPa along ~2 cm-long cement fractures showed that a pressure gradient increase resulted in an increase of CO2 fluids flux by a factor of only ~3-9 because the friction of CO2 fluids on cement fracture surfaces increased with higher flow rate as well. At the same pressure gradient, the simulated flow rate was higher for supercritical CO2 than CO2-saturated brine by a factor of only ~2-3, because the viscosity of supercritical CO2 is much lower than that of CO2-saturated brine. The study suggests that in deep geological reservoirs the geochemical and geomechanical processes have coupled effects on the wellbore cement fracture evolution and fluid flow along the fracture surfaces.« less

  13. Geochemical and Geomechanical Effects on Wellbore Cement Fractures

    SciTech Connect (OSTI)

    Um, Wooyong; Jung, Hun Bok; Kabilan, Senthil; Fernandez, Carlos A.; Brown, Christopher F.

    2014-12-31

    Experimental studies were conducted using batch reactors, X-ray microtomograpy (XMT), and computational fluid dynamics (CFD) simulation to determine changes in cement fracture surfaces, fluid flow pathways, and permeability with geochemical and geomechanical processes. Composite Portland cement-basalt caprock core with artificial fractures was prepared and reacted with CO2-saturated groundwater at 50°C and 10 MPa for 3 to 3.5 months under static conditions to understand the geochemical and geomechanical effects on the integrity of wellbores containing defects. Cement-basalt interface samples were subjected to mechanical stress at 2.7 MPa before the CO2 reaction. XMT provided three-dimensional (3-D) visualization of the opening and interconnection of cement fractures due to mechanical stress. After the CO2 reaction, XMT images revealed that calcium carbonate precipitation occurred extensively within the fractures in the cement matrix, but only partially along fractures located at the cement-basalt interface. The permeability calculated based on CFD simulation was in agreement with the experimentally measured permeability. The experimental results imply that the wellbore cement with fractures is likely to be healed during exposure to CO2-saturated groundwater under static conditions, whereas fractures along the cement-caprock interface are still likely to remain vulnerable to the leakage of CO2. CFD simulation for the flow of different fluids (CO2-saturated brine and supercritical CO2) using a pressure difference of 20 kPa and 200 kPa along ~2 cm-long cement fractures showed that a pressure gradient increase resulted in an increase of CO2 fluids flux by a factor of only ~3-9 because the friction of CO2 fluids on cement fracture surfaces increased with higher flow rate as well. At the same pressure gradient, the simulated flow rate was higher for supercritical CO2 than CO2-saturated brine by a factor of only ~2-3, because the viscosity of supercritical CO2 is much lower than that of CO2-saturated brine. The study suggests that in deep geological reservoirs the geochemical and geomechanical processes have coupled effects on the wellbore cement fracture evolution and fluid flow along the fracture surfaces.

  14. Geochemical Behaviour of S, Cl and Fe in Silicate Melts/Glasses Simulating

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Magmas | Stanford Synchrotron Radiation Lightsource Geochemical Behaviour of S, Cl and Fe in Silicate Melts/Glasses Simulating Natural Magmas Monday, March 26, 2012 - 11:00am SSRL Conference Room 137-322 G. Giuli, R. Alonso-Mori, E. Paris, P. Glatzel, S. Eeckhout, M. Carroll, School of Science and Technology, Geology Division, University of Camerino, Via G. III da Varano, 62032 Camerino; e-mail: The solubility behaviour of S and Cl in silicate magmas is a key to understand the

  15. Geochemical Reaction Mechanism Discovery from Molecular Simulation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stack, Andrew G.; Kent, Paul R. C.

    2014-11-10

    Methods to explore reactions using computer simulation are becoming increasingly quantitative, versatile, and robust. In this review, a rationale for how molecular simulation can help build better geochemical kinetics models is first given. We summarize some common methods that geochemists use to simulate reaction mechanisms, specifically classical molecular dynamics and quantum chemical methods and discuss their strengths and weaknesses. Useful tools such as umbrella sampling and metadynamics that enable one to explore reactions are discussed. Several case studies wherein geochemists have used these tools to understand reaction mechanisms are presented, including water exchange and sorption on aqueous species and mineralmore » surfaces, surface charging, crystal growth and dissolution, and electron transfer. The impact that molecular simulation has had on our understanding of geochemical reactivity are highlighted in each case. In the future, it is anticipated that molecular simulation of geochemical reaction mechanisms will become more commonplace as a tool to validate and interpret experimental data, and provide a check on the plausibility of geochemical kinetic models.« less

  16. Coupled Geochemical Impacts of Leaking CO2 and Contaminants from Subsurface Storage Reservoirs on Groundwater Quality

    SciTech Connect (OSTI)

    Shao, Hongbo; Qafoku, Nikolla; Lawter, Amanda R.; Bowden, Mark E.; Brown, Christopher F.

    2015-07-07

    The leakage of CO2 and the concomitant saline solutions from deep storage reservoirs to overlying groundwater aquifers is considered one of the major potential risks associated with geologic CO2 sequestration (GCS). Batch and column experiments were conducted to determine the fate of trace metals in groundwater in the scenarios of CO2 and metal contaminated brine leakage. The sediments used in this work were collected from an unconsolidated sand and gravel aquifer in Kansas, and contained 0-4 wt% carbonates. Cd and As were spiked into the reaction system to represent potential contaminants from the reservoir brine that could intrude into groundwater aquifers with leaking CO2 at initial concentrations of 114 and 40 ppb, respectively. Through this research we demonstrated that Cd and As were adsorbed on the sediments, in spite of the lowered pH due to CO2 dissolution in the groundwater. Cd concentrations were well below its MCL in both batch and column studies, even for sediment samples without detectable carbonate to buffer the pH. Arsenic concentrations in the effluent were also significantly lower than influent concentration, suggesting that the sediments tested have the capacity to mitigate the coupled adverse effects of CO2 leakage and brine intrusion. However, the mitigation capacity of sediment is a function of its geochemical properties [e.g., the calcite content; the presence of adsorbed As(III); and the presence of P in the natural sediment]. The competitive adsorption between phosphate and arsenate may result in higher concentrations of As in the aqueous phase.

  17. Twenty-First Water Reactor Safety Information Meeting. Volume 3, Primary system integrity; Aging research, products and applications; Structural and seismic engineering; Seismology and geology: Proceedings

    SciTech Connect (OSTI)

    Monteleone, S.

    1994-04-01

    This three-volume report contains 90 papers out of the 102 that were presented at the Twenty-First Water Reactor Safety Information Meeting held at the Bethesda Marriott Hotel, Bethesda, Maryland, during the week of October 25-27, 1993. The papers are printed in the order of their presentation in each session and describe progress and results of programs in nuclear safety research conducted in this country and abroad. Foreign participation in the meeting included papers presented by researchers from France, Germany, Japan, Russia, Switzerland, Taiwan, and United Kingdom. The titles of the papers and the names of the authors have been updated and may differ from those that appeared in the final program of the meeting. Selected papers were indexed separately for inclusion in the Energy Science and Technology Database.

  18. Collaborative Research. Damage and Burst Dynamics in Failure of Complex Geomaterials. A Statistical Physics Approach to Understanding the Complex Emergent Dynamics in Near Mean-Field Geological Materials

    SciTech Connect (OSTI)

    Rundle, John B.; Klein, William

    2015-09-29

    We have carried out research to determine the dynamics of failure in complex geomaterials, specifically focusing on the role of defects, damage and asperities in the catastrophic failure processes (now popularly termed “Black Swan events”). We have examined fracture branching and flow processes using models for invasion percolation, focusing particularly on the dynamics of bursts in the branching process. We have achieved a fundamental understanding of the dynamics of nucleation in complex geomaterials, specifically in the presence of inhomogeneous structures.

  19. Geological Sequestration Training and Research Program in Capture and Transport: Development of the Most Economical Separation Method for CO2 Capture

    SciTech Connect (OSTI)

    Vahdat, Nader

    2013-09-30

    The project provided hands-on training and networking opportunities to undergraduate students in the area of carbon dioxide (CO2) capture and transport, through fundamental research study focused on advanced separation methods that can be applied to the capture of CO2 resulting from the combustion of fossil-fuels for power generation . The project teams approach to achieve its objectives was to leverage existing Carbon Capture and Storage (CCS) course materials and teaching methods to create and implement an annual CCS short course for the Tuskegee University community; conduct a survey of CO2 separation and capture methods; utilize data to verify and develop computer models for CO2 capture and build CCS networks and hands-on training experiences. The objectives accomplished as a result of this project were: (1) A comprehensive survey of CO2 capture methods was conducted and mathematical models were developed to compare the potential economics of the different methods based on the total cost per year per unit of CO2 avoidance; and (2) Training was provided to introduce the latest CO2 capture technologies and deployment issues to the university community.

  20. Current developments in laser ablation-inductively coupled plasma-mass spectrometry for use in geology, forensics, and nuclear nonproliferation research

    SciTech Connect (OSTI)

    Messerly, Joshua D.

    2008-08-26

    This dissertation focused on new applications of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). The diverse fields that were investigated show the versatility of the technique. In Chapter 2, LA-ICP-MS was used to investigate the rare earth element (REE) profiles of garnets from the Broken Hill Deposit in New South Wales, Australia. The normalized REE profiles helped to shed new light on the formation of deposits of sulfide ores. This information may be helpful in identifying the location of sulfide ore deposits in other locations. New sources of metals such as Pg, Zn, and Ag, produced from these ores, are needed to sustain our current technological society. The application of LA-ICP-MS presented in Chapter 3 is the forensics analysis of automotive putty and caulking. The elemental analysis of these materials was combined with the use of Principal Components Analysis (PCA). The PCA comparison was able to differentiate the automotive putty samples by manufacturer and lot number. The analysis of caulk was able to show a differentiation based on manufacturer, but no clear differentiation was shown by lot number. This differentiation may allow matching of evidence in the future. This will require many more analyses and the construction of a database made up of many different samples. The 4th chapter was a study of the capabilities of LA-ICP-MS for fast and precise analysis of particle ensembles for nuclear nonproliferation applications. Laser ablation has the ability to spatially resolve particle ensembles which may contain uranium or other actinides from other particles present in a sample. This is of importance in samples obtained from air on filter media. The particle ensembles of interest may be mixed in amongst dust and other particulates. A problem arises when ablating these particle ensembles directly from the filter media. Dust particles other than ones of interest may be accidentally entrained in the aerosol of the ablated particle ensemble. This would cause the analysis to be skewed. The use of a gelatin substrate allows the ablation a particle ensemble without disturbing other particles or the gelatin surface. A method to trap and ablate particles on filter paper using collodion was also investigated. The laser was used to dig through the collodion layer and into the particle ensemble. Both of these methods fix particles to allow spatial resolution of the particle ensembles. The use of vanillic acid as a possible enhancement to ablation was also studied. A vanillic acid coating of the particles fixed on top of the gelatin substrate was not found to have any positive effect on either signal intensity or precision. The mixing of vanillic acid in the collodion solution used to coat the filter paper increased ablation signal intensity by a factor of 4 to 5. There was little effect on precision, though. The collodion on filter paper method and the gelatin method of resolving particles have shown themselves to be possible tools in fighting proliferation of nuclear weapons and material. Future applications of LA-ICP-MS are only limited by the imagination of the investigator. Any material that can be ablated and aerosolized is a potential material for analysis by LA-ICP-MS. Improvements in aerosol transport, ablation chamber design, and laser focusing can make possible the ablation and analysis of very small amounts of material. This may perhaps lead to more possible uses in forensics. A similar method to the one used in Chapter 3 could perhaps be used to match drug residue to the place of origin. Perhaps a link could be made based on the elements leached from the soil by plants used to make drugs. This may have a specific pattern based on where the plant was grown. Synthetic drugs are produced in clandestine laboratories that are often times very dirty. The dust, debris, and unique materials in the lab environment could create enough variance to perhaps match drugs produced there to samples obtained off the street. Even if the match was not strong enough to be evidence, the knowledge that many samples of a drug are being produced from a similar location could help law enforcement find and shut down the lab. Future nuclear nonproliferation research would also be helped by the ability to get more analyte signal from smaller and smaller amounts of material. One possible future line of research would be to find a way to make the collodion layer as thin as possible so less laser shots are needed to get to the particle of interest. Collodion and gelatin analysis could also be used for environmental applications where spatial resolution of particles is needed. Individual particles could give information about the contaminants present in a given location. The wide versatility of LA-ICP-MS makes it a useful tool for nearly nondestructive analysis of a variety of samples and matrices.

  1. Petroleum potential of the Upper Ordovician Maquoketa Group in Illinois: A coordinated geological and geochemical study

    SciTech Connect (OSTI)

    Crockett, J.E.; Oltz, D.F. ); Kruge, M.A. )

    1990-05-01

    The Ordovician Maquoketa Group in Illinois, predominantly composed of shale, calcareous shale, and carbonates, has long been considered a potential source for Illinois basin hydrocarbons. Methods used to better define the petroleum potential of the Maquoketa in the Illinois basin were lithostratigraphic study, Rock-Eval (pyrolysis) analyses, comparison of molecular markers from whole-rock extracts and produced oil, and construction of burial history models. Organic-rich submature Maquoketa potential source rocks are present in western Illinois at shallow depths on the basin flank. Deeper in the basin in southern Illinois, Rock-Eval analyses indicate that the Maquoketa shale is within the oil window. Solvent extracts of the Maquoketa from western Illinois closely resemble the Devonian New Albany Shale, suggesting that past studies may have erroneously attributed Maquoketa-generated petroleum to a New Albany source or failed to identify mixed source oils. Subtle differences between Maquoketa and New Albany solvent extracts include differences in pristane/phytane ratios, proportions of steroids, and distribution of dimethyldibenzothiophene isomers. Maquoketa solvent extracts show little resemblance to Middle Ordovician oils from the Illinois or Michigan basins. Lithostratigraphic studies identified localized thick carbonate facies in the Maquoketa, suggesting depositional response to upper Ordovician paleostructures. Sandstone facies in the Maquoketa in southwestern Illinois offer a potential source/trap play, as well as serving as potential carrier beds for hydrocarbon migration. Maquoketa source and carrier beds may feed older Ordovician rocks in faulted areas along and south of the Cottage Grove fault system in southern Illinois.

  2. Hydrological/Geological Studies

    Office of Legacy Management (LM)

    .\ .8.2 Hydrological/Geological Studies Book 1. Radiochemical Analyses of Water Samples from SelectedT" Streams Wells, Springs and Precipitation Collected During Re-Entry Drilling, Project Rulison-7, 197 1 HGS 8 This page intentionally left blank . . . ... . . . . . . . . , : . . . . . . . . . ' . r - . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ... . . . . . ..... . - x ..:; . , ' , . . ' . . . . . . !' r:.::. _. . : _ . . : . . . . \ . . ' - \ , : , . . . . . . . . . . .

  3. RECOVERY ACT: Geologic Sequestration Training and Research

    Office of Scientific and Technical Information (OSTI)

    ... through seal layers, (5) education and training of students ... to use, for its ease of changing samples and obtaining ... C., and H. J. Fraser, "Systematic Packing of Spheres with ...

  4. Establishing MICHCARB, a geological carbon sequestration research...

    Office of Scientific and Technical Information (OSTI)

    ... Authors: Barnes, David A. 1 ; Harrison, William B. 1 + Show Author Affiliations Western Michigan University Western Michigan University Publication Date: 2014-01-28 OSTI ...

  5. A Geochemical Speciation Program Based on PHREEQE

    Energy Science and Technology Software Center (OSTI)

    1992-02-18

    HARPHRQ is a program based on the code PHREEQE and is designed to model geochemical reactions. Like PHREEQE, it can calculate the pH, redox potential and mass transfer as a function of reaction progress and the composition of solution in equilibrium with multiple phases. In addition, HARPHRQ includes options to allow the composition of a solution at a fixed pH to be calculated and to automatically add or remove mineral phases as they become saturatedmore » or exhausted. A separate module can also be interfaced to give a choice of sorption models including the triple-layer model.« less

  6. DNA-based methods of geochemical prospecting

    DOE Patents [OSTI]

    Ashby, Matthew

    2011-12-06

    The present invention relates to methods for performing surveys of the genetic diversity of a population. The invention also relates to methods for performing genetic analyses of a population. The invention further relates to methods for the creation of databases comprising the survey information and the databases created by these methods. The invention also relates to methods for analyzing the information to correlate the presence of nucleic acid markers with desired parameters in a sample. These methods have application in the fields of geochemical exploration, agriculture, bioremediation, environmental analysis, clinical microbiology, forensic science and medicine.

  7. Geochemical Modeling of the Near-Surface Hydrothermal System...

    Open Energy Info (EERE)

    with non-thermal groundwater. Our conceptual model is based on hypotheses in the literature and published geochemical and petrologic data. Mixing of thermal and non-thermal...

  8. Merging high resolution geophysical and geochemical surveys to...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    combine a suite of high resolution geophysical and geochemical techniques to reduce exploration risk by characterizing hydrothermal alteration, fault geometries and relationships. ...

  9. Category:Geochemical Data Analysis | Open Energy Information

    Open Energy Info (EERE)

    category, out of 4 total. G Geochemical Data Analysis Geothermometry T Thermal Ion Dispersion Thermochronometry Retrieved from "http:en.openei.orgwindex.php?titleCategory:Ge...

  10. geologic-sequestration | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Geological Sequestration Training and Research Program in Capture and Transport: Development of the Most Economical Separation Method for CO2 Capture Project No.: DE-FE0001953 NETL has partnered with Tuskegee University (TU) to provide fundamental research and hands-on training and networking opportunities to undergraduate students at TU in the area of CO2 capture and transport with a focus on the development of the most economical separation methods for pre-combustion CO2 capture. The bulk of

  11. Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Research thorium test foil A thorium test foil ...

  12. Estimating the spatio-temporal distribution of geochemical parameters

    Office of Scientific and Technical Information (OSTI)

    associated with biostimulation using spectral induced polarization data and hierarchical Bayesian models (Journal Article) | SciTech Connect Estimating the spatio-temporal distribution of geochemical parameters associated with biostimulation using spectral induced polarization data and hierarchical Bayesian models Citation Details In-Document Search Title: Estimating the spatio-temporal distribution of geochemical parameters associated with biostimulation using spectral induced polarization

  13. Geological Society of America selects Los Alamos scientist Claudia...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is a stable-isotope geochemist whose research spans the traditional fields of geology, soil science and climate science. July 9, 2015 Claudia Mora Claudia Mora Contact Los Alamos...

  14. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to an Unconfined Oxidizing Carbonate Aquifer

    SciTech Connect (OSTI)

    Wang, Guohui; Qafoku, Nikolla; Lawter, Amanda R.; Bowden, Mark E.; Harvey, Omar; Sullivan, E. C.; Brown, Christopher F.

    2015-07-15

    A series of batch and column experiments combined with solid phase characterization studies (i.e., quantitative x-ray diffraction and wet chemical extractions) were conducted to address a variety of scientific issues and evaluate the impacts of the potential leakage of carbon dioxide (CO2) from deep subsurface storage reservoirs. The main objective was to gain an understanding of how CO2 gas influences: 1) the aqueous phase pH; and 2) mobilization of major, minor, and trace elements from minerals present in an aquifer overlying potential CO2 sequestration subsurface repositories. Rocks and slightly weathered rocks representative of an unconfined, oxidizing carbonate aquifer within the continental US, i.e., the Edwards aquifer in Texas, were used in these studies. These materials were exposed to a CO2 gas stream or were leached with a CO2-saturated influent solution to simulate different CO2 gas leakage scenarios, and changes in aqueous phase pH and chemical composition were measured in the liquid samples collected at pre-determined experimental times (batch experiments) or continuously (column experiments). The results from the strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the Edward aquifer samples contain As, Cd, Pb, Cu, and occasionally Zn, which may potentially be mobilized from the solid to the aqueous phase during or after exposure to CO2. The results from the batch and column experiments confirmed the release of major chemical elements into the contacting aqueous phase (such as Ca, Mg, Ba, Sr, Si, Na, and K); the mobilization and possible rapid immobilization of minor elements (such as Fe, Al, and Mn), which are able to form highly reactive secondary phases; and sporadic mobilization of only low concentrations of trace elements (such as As, Cd, Pb, Cu, Zn, Mo, etc.). The results from this experimental research effort will help in developing a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption) in the aquifer sediments and will support site selection, risk assessment, policy-making, and public education efforts associated with geologic carbon sequestration.

  15. Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Research Isotopes produced at Los Alamos National Laboratory are saving lives, advancing cutting-edge research and keeping the U.S. safe. Research thorium test foil A thorium test foil target for proof-of-concept actinium-225 production In addition to our routine isotope products, the LANL Isotope Program is focused on developing the next suite of isotopes and services to meet the Nation's emerging needs. The LANL Isotope Program's R&D strategy is focused on four main areas (see

  16. Predictive Modeling of Terrestrial Radiation Exposure from Geologic Materials

    SciTech Connect (OSTI)

    Malchow, Russell L.; Haber, Daniel University of Nevada, Las Vegas; Burnley, Pamela; Marsac, Kara; Hausrath, Elisabeth; Adcock, Christopher

    2015-01-01

    Aerial gamma ray surveys are important for those working in nuclear security and industry for determining locations of both anthropogenic radiological sources and natural occurrences of radionuclides. During an aerial gamma ray survey, a low flying aircraft, such as a helicopter, flies in a linear pattern across the survey area while measuring the gamma emissions with a sodium iodide (NaI) detector. Currently, if a gamma ray survey is being flown in an area, the only way to correct for geologic sources of gamma rays is to have flown the area previously. This is prohibitively expensive and would require complete national coverage. This project’s goal is to model the geologic contribution to radiological backgrounds using published geochemical data, GIS software, remote sensing, calculations, and modeling software. K, U and Th are the three major gamma emitters in geologic material. U and Th are assumed to be in secular equilibrium with their daughter isotopes. If K, U, and Th abundance values are known for a given geologic unit the expected gamma ray exposure rate can be calculated using the Grasty equation or by modeling software. Monte Carlo N-Particle Transport software (MCNP), developed by Los Alamos National Laboratory, is modeling software designed to simulate particles and their interactions with matter. Using this software, models have been created that represent various lithologies. These simulations randomly generate gamma ray photons at energy levels expected from natural radiologic sources. The photons take a random path through the simulated geologic media and deposit their energy at the end of their track. A series of nested spheres have been created and filled with simulated atmosphere to record energy deposition. Energies deposited are binned in the same manner as the NaI detectors used during an aerial survey. These models are used in place of the simplistic Grasty equation as they take into account absorption properties of the lithology which the simplistic equation ignores.

  17. Research

    SciTech Connect (OSTI)

    1999-10-01

    Subjects covered in this section are: (1) PCAST panel promotes energy research cooperation; (2) Letter issued by ANS urges funding balance in FFTF restart consideration and (3) FESAC panel releases report on priorities and balance.

  18. Modeling Background Radiation in our Environment Using Geochemical Data

    SciTech Connect (OSTI)

    Malchow, Russell L.; Marsac, Kara; Burnley, Pamela; Hausrath, Elisabeth; Haber, Daniel; Adcock, Christopher

    2015-02-01

    Radiation occurs naturally in bedrock and soil. Gamma rays are released from the decay of the radioactive isotopes K, U, and Th. Gamma rays observed at the surface come from the first 30 cm of rock and soil. The energy of gamma rays is specific to each isotope, allowing identification. For this research, data was collected from national databases, private companies, scientific literature, and field work. Data points were then evaluated for self-consistency. A model was created by converting concentrations of U, K, and Th for each rock and soil unit into a ground exposure rate using the following equation: D=1.32 K+ 0.548 U+ 0.272 Th. The first objective of this research was to compare the original Aerial Measurement System gamma ray survey to results produced by the model. The second objective was to improve the method and learn the constraints of the model. Future work will include sample data analysis from field work with a goal of improving the geochemical model.

  19. Remote Raman - laser induced breakdown spectroscopy (LIBS) geochemical investigation under Venus atmospheric conditions

    SciTech Connect (OSTI)

    Clegg, Sanuel M; Barefield, James E; Humphries, Seth D; Wiens, Roger C; Vaniman, D. T.; Sharma, S. K.; Misra, A. K.; Dyar, M. D.; Smrekar, S. E.

    2010-12-13

    The extreme Venus surface temperatures ({approx}740 K) and atmospheric pressures ({approx}93 atm) create a challenging environment for surface missions. Scientific investigations capable of Venus geochemical observations must be completed within hours of landing before the lander will be overcome by the harsh atmosphere. A combined remote Raman - LIBS (Laser Induced Breakdown Spectroscopy) instrument is capable of accomplishing the geochemical science goals without the risks associated with collecting samples and bringing them into the lander. Wiens et al. and Sharma et al. demonstrated that both analytical techniques can be integrated into a single instrument capable of planetary missions. The focus of this paper is to explore the capability to probe geologic samples with Raman - LIBS and demonstrate quantitative analysis under Venus surface conditions. Raman and LIBS are highly complementary analytical techniques capable of detecting both the mineralogical and geochemical composition of Venus surface materials. These techniques have the potential to profoundly increase our knowledge of the Venus surface composition, which is currently limited to geochemical data from Soviet Venera and VEGA landers that collectively suggest a surface composition that is primarily tholeiitic basaltic with some potentially more evolved compositions and, in some locations, K-rich trachyandesite. These landers were not equipped to probe the surface mineralogy as can be accomplished with Raman spectroscopy. Based on the observed compositional differences and recognizing the imprecise nature of the existing data, 15 samples were chosen to constitute a Venus-analog suite for this study, including five basalts, two each of andesites, dacites, and sulfates, and single samples of a foidite, trachyandesite, rhyolite, and basaltic trachyandesite under Venus conditions. LIBS data reduction involved generating a partial least squares (PLS) model with a subset of the rock powder standards to quantitatively determine the major elemental abundance of the remaining samples. PLS analysis suggests that the major element compositions can be determined with root mean square errors ca. 5% (absolute) for SiO{sub 2}, Al{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}(total), MgO, and CaO, and ca. 2% or less for TiO{sub 2}, Cr{sub 2}O{sub 3}, MnO, K{sub 2}O, and Na{sub 2}O. Finally, the Raman experiments have been conducted under supercritical CO{sub 2} involving single-mineral and mixed-mineral samples containing talc, olivine, pyroxenes, feldspars, anhydrite, barite, and siderite. The Raman data have shown that the individual minerals can easily be identified individually or in mixtures.

  20. A Mineralogical Petrographic And Geochemical Study Of Samples...

    Open Energy Info (EERE)

    Mineralogical Petrographic And Geochemical Study Of Samples From Wells In The Geothermal Field Of Milos Island (Greece) Jump to: navigation, search OpenEI Reference LibraryAdd to...

  1. Geochemical Data on Waters, Gases, Scales, and Rocks from the...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999)...

  2. Geology and geochemistry of crude oils, Bolivar coastal fields, Venezuela

    SciTech Connect (OSTI)

    Bockmeulen, H.; Barker, C.; Dickey, P.A.

    1983-02-01

    The Bolivar Coastal Fields (BCF) are located on the eastern margin of Lake Maracaibo, Venezuela. They form the largest oil field outside of the Middle East and contain mostly heavy oil with a gravity less than 22/sup 0/ API. Thirty crude oils from the BCF were collected along two parallel and generally southwest-northeast trends. These oils were characterized by their API gravity, percent saturates, aromatics, NSO and asphalitic compounds, gas chromatograms for whole oils, C/sub 4/-C/sub 7/ fractions, and aromatics. Also, 24 associated waters were sampled and analyzed for Ca/sup + +/, Mg/sup + +/, Na/sup +/, HCO/sub 3//sup -/, CO/sub 3//sup - -/, SO/sub 4//sup - -/, pH, and total dissolved solids (TDS). The geological and geochemical significances of these analyses are discussed with particular emphasis on the genesis of the petroleum.

  3. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic

    Office of Scientific and Technical Information (OSTI)

    Leakage into an Unconfined, Oxidizing Limestone Aquifer (Journal Article) | SciTech Connect Journal Article: Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer Citation Details In-Document Search Title: Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer An important risk at CO2 storage sites is the potential for groundwater quality impacts. As

  4. Monitoring CO2 intrusion and associated geochemical transformations in a

    Office of Scientific and Technical Information (OSTI)

    shallow groundwater system using complex electrical methods (Journal Article) | SciTech Connect Monitoring CO2 intrusion and associated geochemical transformations in a shallow groundwater system using complex electrical methods Citation Details In-Document Search Title: Monitoring CO2 intrusion and associated geochemical transformations in a shallow groundwater system using complex electrical methods Authors: Dafflon, B. ; Wu, Y. ; Hubbard, S. S. ; Birkholzer, J. T. ; Daley, T. M. ; Pugh,

  5. Monitoring CO2 intrusion and associated geochemical transformations in a

    Office of Scientific and Technical Information (OSTI)

    shallow groundwater system using complex electrical methods (Journal Article) | SciTech Connect Monitoring CO2 intrusion and associated geochemical transformations in a shallow groundwater system using complex electrical methods Citation Details In-Document Search Title: Monitoring CO2 intrusion and associated geochemical transformations in a shallow groundwater system using complex electrical methods × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This

  6. Coffinitization of Uraninite: SEM/AEM Investigation and Geochemical

    Office of Scientific and Technical Information (OSTI)

    Modeling (Conference) | SciTech Connect Coffinitization of Uraninite: SEM/AEM Investigation and Geochemical Modeling Citation Details In-Document Search Title: Coffinitization of Uraninite: SEM/AEM Investigation and Geochemical Modeling Coffinite (USiO{sub 4}) has been found in numerous sedimentary and hydrothermal environments including those considered as natural analogues of nuclear waste repositories. Scanning electron microscopy (SEM) and analytical electron microscopy (AEM) studies

  7. Developing a robust geochemical and reactive transport model to evaluate

    Office of Scientific and Technical Information (OSTI)

    possible sources of arsenic at the CO[subscript 2] sequestration natural analog site in Chimayo, New Mexico (Journal Article) | SciTech Connect Journal Article: Developing a robust geochemical and reactive transport model to evaluate possible sources of arsenic at the CO[subscript 2] sequestration natural analog site in Chimayo, New Mexico Citation Details In-Document Search Title: Developing a robust geochemical and reactive transport model to evaluate possible sources of arsenic at the

  8. SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Signals in the Subsurface | Department of Energy SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical Signals in the Subsurface SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical Signals in the Subsurface PDF icon Grand Challenge Workshop -Imaging Subsurface.pdf More Documents & Publications AGU SubTER Town Hall Presentation 2015 SubTER Fact Sheet SubTER Presentation at Town Hall - American Geophysical Union

  9. Geochemical Mud Logging of geothermal drilling

    SciTech Connect (OSTI)

    Tonani, F.B.; Guidi, M.; Johnson, S.D.

    1988-01-01

    The experience and results described in the present paper were developed over nearly two decades, with a major R&D project around 1980. The expression Geochemical Mud Logging (GML) has ill defined meaning in the geothermal industry, and ought to be specified. We refer here to GML as featuring mud and formation fluid tracer(s) and temperature as the bare essentials and with specified accuracies. Air and water logging are expected to be less demanding with regard to analysis accuracy, but are not discussed in this report. During application of GML to several drill holes with low formation permeabilities and under conditions of high temperature and high mud weight, GML as specified, revealed unexpected influx of formation brine. Such influx was a recurring feature that has been referenced to individual fractures and reflects both fracture size and permeability. As a consequence, continuous or subcontinuous sampling of mud systems appears more cost effective than trying to keep up with cumulative changes of bulk mud composition; although, the latter approach is more sensitive to extremely low rate, steady, inflow of formation fluid into the mud system. It appears, that based on this influx of formation fluid, permeability can be estimated well before mud losses are detected and/or drill strings are stuck. The main advantages of GML are: (1) the capability to assess formation temperature and permeability in nearly real time, resulting in (a) assessments of undisturbed formation and (b) having data in hand for holes lost during drilling operations and (2) being effective under conditions of very high temperatures where electrical logs are very costly and less reliable. Estimated cost for GML is $1500 per day (1982) based on assessments of R&D operations. However, extrapolating to larger scale services and to different operating conditions is indeed difficult. GML cost is probably the only significant point of controversy with regard to GML being a viable evaluation tool.

  10. Environmental Responses to Carbon Mitigation through Geological Storage

    SciTech Connect (OSTI)

    Cunningham, Alfred; Bromenshenk, Jerry

    2013-08-30

    In summary, this DOE EPSCoR project is contributing to the study of carbon mitigation through geological storage. Both deep and shallow subsurface research needs are being addressed through research directed at improved understanding of environmental responses associated with large scale injection of CO{sub 2} into geologic formations. The research plan has two interrelated research objectives.  Objective 1: Determine the influence of CO{sub 2}-related injection of fluids on pore structure, material properties, and microbial activity in rock cores from potential geological carbon sequestration sites.  Objective 2: Determine the Effects of CO{sub 2} leakage on shallow subsurface ecosystems (microbial and plant) using field experiments from an outdoor field testing facility.

  11. Chinese Geological Survey | Open Energy Information

    Open Energy Info (EERE)

    Chinese Geological Survey Jump to: navigation, search Name: Chinese Geological Survey Place: China Sector: Geothermal energy Product: Chinese body which is involved in surveys of...

  12. Idaho Geological Survey | Open Energy Information

    Open Energy Info (EERE)

    The Idaho Geological Survey is located in Boise, Idaho. About Information on past oil and gas exploration wells in Idaho was transferred to the Idaho Geological Survey in...

  13. Geologic interpretation of gravity anomalies

    SciTech Connect (OSTI)

    Andreyev, B.A.; Klushin, I.G.

    1990-04-19

    This Russian textbook provides a sufficiently complete and systematic illumination of physico-geologic and mathematical aspect of complex problem of interpretation of gravity anomalies. The rational methods of localization of anomalies are examined in detail. All methods of interpreting gravity anomalies are described which have found successful application in practice. Also given are ideas of some new methods of the interpretation of gravity anomalies, the prospects for further development and industrial testing. Numerous practical examples to interpretation are given. Partial Contents: Bases of gravitational field theory; Physico-geologic bases of gravitational prospecting; Principles of geologic interpretation of gravity anomalies; Conversions and calculations of anomalies; Interpretation of gravity anomalies for bodies of correct geometric form and for bodies of arbitrary form; Geologic interpretation of the results of regional gravitational photographing; Searches and prospecting of oil- and gas-bearing structures and of deposits of ore and nonmetalliferous useful minerals.

  14. Cigeo, the French Geological Repository Project - 13022

    SciTech Connect (OSTI)

    Labalette, Thibaud; Harman, Alain; Dupuis, Marie-Claude; Ouzounian, Gerald

    2013-07-01

    The Cigeo industrial-scale geological disposal centre is designed for the disposal of the most highly-radioactive French waste. It will be built in an argillite formation of the Callovo-Oxfordian dating back 160 million years. The Cigeo project is located near the Bure village in the Paris Basin. The argillite formation was studied since 1974, and from the Meuse/Haute-Marne underground research laboratory since end of 1999. Most of the waste to be disposed of in the Cigeo repository comes from nuclear power plants and from reprocessing of their spent fuel. (authors)

  15. Geochemical Modeling of ILAW Lysimeter Water Extracts

    SciTech Connect (OSTI)

    Cantrell, Kirk J.

    2014-12-22

    Geochemical modeling results of water extracts from simulated immobilized low-activity waste (ILAW) glasses, placed in lysimeters for eight years suggest that the secondary phase reaction network developed using product consistency test (PCT) results at 90°C may need to be modified for field conditions. For sediment samples that had been collected from near the glass samples, the impact of glass corrosion could be readily observed based upon the pH of their water extracts. For unimpacted sediments the pH ranged from 7.88 to 8.11 with an average of 8.04. Sediments that had observable impacts from glass corrosion exhibited elevated pH values (as high as 9.97). For lysimeter sediment samples that appear to have been impacted by glass corrosion to the greatest extent, saturation indices determined for analcime, calcite, and chalcedony in the 1:1 water extracts were near equilibrium and were consistent with the secondary phase reaction network developed using PCT results at 90°C. Fe(OH)3(s) also appears to be essentially at equilibrium in extracts impacted by glass corrosion, but with a solubility product (log Ksp) that is approximately 2.13 units lower than that used in the secondary phase reaction network developed using PCT results at 90°C. The solubilities of TiO2(am) and ZrO2(am) also appear to be much lower than that assumed in the secondary phase reaction network developed using PCT results at 90°C. The extent that the solubility of TiO2(am) and ZrO2(am) were reduced relative to that assumed in the secondary phase reaction network developed using PCT results at 90°C could not be quantified because the concentrations of Ti and Zr in the extracts were below the estimated quantification limit. Gibbsite was consistently highly oversaturated in the extract while dawsonite was at or near equilibrium. This suggests that dawsonite might be a more suitable phase for the secondary phase reaction network than gibbsite under field conditions. This may be due to the availability of carbonate that exists in the Hanford sediments as calcite. A significant source of carbonate was not available in the PCTs and this may account for why this phase did not appear in the PCTs. Sepiolite was consistently highly undersaturated, suggesting that another phase controls the solubility of magnesium. For samples that were most impacted by the effects of glass corrosion, magnesite appears to control glass corrosion. For samples that show less impacts from glass corrosion, clinochlore-7A or saponite-Mg appears to control the magnesium concentrations. For zinc, it appears that zincite is a better candidate than Zn(OH)2-γ for controlling zinc concentrations in the extracts; however, in some samples all zinc phases considered were highly oversaturated. As a result the phase that controls zinc concentrations in the lysimeter extracts remains uncertain.

  16. Geochemical Enhancement Of Enhanced Geothermal System Reservoirs: An Integrated Field And Geochemical Approach

    SciTech Connect (OSTI)

    Joseph N. Moore

    2007-12-31

    The geochemical effects of injecting fluids into geothermal reservoirs are poorly understood and may be significantly underestimated. Decreased performance of injection wells has been observed in several geothermal fields after only a few years of service, but the reasons for these declines has not been established. This study had three primary objectives: 1) determine the cause(s) of the loss of injectivity; 2) utilize these observations to constrain numerical models of water-rock interactions; and 3) develop injection strategies for mitigating and reversing the potential effects of these interactions. In this study rock samples from original and redrilled injection wells at Coso and the Salton Sea geothermal fields, CA, were used to characterize the mineral and geochemical changes that occurred as a result of injection. The study documented the presence of mineral scales and at both fields in the reservoir rocks adjacent to the injection wells. At the Salton Sea, the scales consist of alternating layers of fluorite and barite, accompanied by minor anhydrite, amorphous silica and copper arsenic sulfides. Amorphous silica and traces of calcite were deposited at Coso. The formation of silica scale at Coso provides an example of the effects of untreated (unacidified) injectate on the reservoir rocks. Scanning electron microscopy and X-ray diffractometry were used to characterize the scale deposits. The silica scale in the reservoir rocks at Coso was initially deposited as spheres of opal-A 1-2 micrometers in diameter. As the deposits matured, the spheres coalesced to form larger spheres up to 10 micrometer in diameter. Further maturation and infilling of the spaces between spheres resulted in the formation of plates and sheets that substantially reduce the original porosity and permeability of the fractures. Peripheral to the silica deposits, fluid inclusions with high water/gas ratios provide a subtle record of interactions between the injectate and reservoir rocks. In contrast, fluid inclusions trapped prior to injection are relatively gas rich. These results suggest that the rocks undergo extensive microfracturing during injection and that the composition of the fluid inclusions will be biased toward the youngest event. Interactions between the reservoir rocks and injectate were modeled using the non-isothermal reactive geochemical transport code TOUGHREACT. Changes in fluid pH, fracture porosity, fracture permeability, fluid temperature, and mineral abundances were monitored. The simulations predict that amorphous silica will precipitate primarily within a few meters of the injection well and that mineral deposition will lead to rapid declines in fracture porosity and permeability, consistent with field observations. In support of Enhanced Geothermal System development, petrologic studies of Coso well 46A-19RD were conducted to determine the regions that are most likely to fail when stimulated. These studies indicate that the most intensely brecciated and altered rocks in the zone targeted for stimulation (below 10,000 ft (3048 m)) occur between 11,200 and 11,350 ft (3414 and 3459 m). This zone is interpreted as a shear zone that initially juxtaposed quartz diorite against granodiorite. Strong pervasive alteration and veining within the brecciated quartz diorite and granodiorite suggest this shear zone was permeable in the past. This zone of weakness was subsequently exploited by a granophyre dike whose top occurs at 11,350 ft (3459 m). The dike is unaltered. We anticipate, based on analysis of the well samples that failure during stimulation will most likely occur on this shear zone.

  17. Up-Scaling Geochemical Reaction Rates for Carbon Dioxide (CO2) in Deep Saline Aquifers

    SciTech Connect (OSTI)

    Peters, Catherine A

    2013-02-28

    Geochemical reactions in deep subsurface environments are complicated by the consolidated nature and mineralogical complexity of sedimentary rocks. Understanding the kinetics of these reactions is critical to our ability to make long-term predictions about subsurface processes such as pH buffering, alteration in rock structure, permeability changes, and formation of secondary precipitates. In this project, we used a combination of experiments and numerical simulation to bridge the gap between our knowledge of these reactions at the lab scale and rates that are meaningful for modeling reactive transport at core scales. The focus is on acid-driven mineral dissolution, which is specifically relevant in the context of CO2-water-rock interactions in geological sequestration of carbon dioxide. The project led to major findings in three areas. First, we modeled reactive transport in pore-network systems to investigate scaling effects in geochemical reaction rates. We found significant scaling effects when CO2 concentrations are high and reaction rates are fast. These findings indicate that the increased acidity associated with geological sequestration can generate conditions for which proper scaling tools are yet to be developed. Second, we used mathematical modeling to investigate the extent to which SO2, if co-injected with CO2, would acidify formation brines. We found that there exist realistic conditions in which the impact on brine acidity will be limited due to diffusion rate-limited SO2 dissolution from the CO2 phase, and the subsequent pH shift may also be limited by the lack of availability of oxidants to produce sulfuric acid. Third, for three Viking sandstones (Alberta sedimentary basin, Canada), we employed backscattered electron microscopy and energy dispersive X-ray spectroscopy to statistically characterize mineral contact with pore space. We determined that for reactive minerals in sedimentary consolidated rocks, abundance alone is not a good predictor of mineral accessible surface area, and should not be used in reactive transport modeling. Our work showed that reaction rates would be overestimated by three to five times.

  18. Geological Society of America selects Los Alamos scientist Claudia Mora as

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    president elect Geological Society of America selects Mora as president elect Geological Society of America selects Los Alamos scientist Claudia Mora as president elect Mora is a stable-isotope geochemist whose research spans the traditional fields of geology, soil science and climate science. July 9, 2015 Claudia Mora Claudia Mora Contact Los Alamos National Laboratory Nancy Ambrosiano Communications Office (505) 667-0471 Email "This is a really great testament to Claudia's impact and

  19. Hg Anomalies In Soils- A Geochemical Exploration Method For Geothermal...

    Open Energy Info (EERE)

    is not possible. Hg anomaly patterns yield information on the presence as well as the geometry of shallow geothermal circulation patterns. In conjunction with structural geologic...

  20. Geochemical Processes Data Package for the Vadose Zone in the Single-Shell Tank Waste Management Areas at the Hanford Site

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Zachara, John M.; Dresel, P. Evan; Krupka, Kenneth M.; Serne, R. Jeffrey

    2007-09-28

    This data package discusses the geochemistry of vadose zone sediments beneath the single-shell tank farms at the U.S. Department of Energy’s (DOE’s) Hanford Site. The purpose of the report is to provide a review of the most recent and relevant geochemical process information available for the vadose zone beneath the single-shell tank farms and the Integrated Disposal Facility. Two companion reports to this one were recently published which discuss the geology of the farms (Reidel and Chamness 2007) and groundwater flow and contamination beneath the farms (Horton 2007).

  1. Research Portfolio Map

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Portfolio Map Welcome to the Strategic Center for Coal Project Portfolio Web Map assembled by NETL. The web map includes projects across all Coal & Power Systems technologies including Advanced Energy Systems, Carbon Capture, Carbon Storage, Cross-Cutting Research, Futuregen 2.0, Industrial Carbon Capture and Storage (ICCS), Clean Coal Power Initiative (CCPI), Geologic Sequestration Training and Research (GSTR), Geologic Sequestration Site Characterization (GSSC), and ICCS

  2. Validation of the WATEQ4 geochemical model for uranium

    SciTech Connect (OSTI)

    Krupka, K.M.; Jenne, E.A.; Deutsch, W.J.

    1983-09-01

    As part of the Geochemical Modeling and Nuclide/Rock/Groundwater Interactions Studies Program, a study was conducted to partially validate the WATEQ4 aqueous speciation-solubility geochemical model for uranium. The solubility controls determined with the WATEQ4 geochemical model were in excellent agreement with those laboratory studies in which the solids schoepite (UO/sub 2/(OH)/sub 2/ . H/sub 2/O), UO/sub 2/(OH)/sub 2/, and rutherfordine ((UO/sub 2/CO/sub 3/) were identified as actual solubility controls for uranium. The results of modeling solution analyses from laboratory studies of uranyl phosphate solids, however, identified possible errors in the characterization of solids in the original solubility experiments. As part of this study, significant deficiencies in the WATEQ4 thermodynamic data base for uranium solutes and solids were corrected. Revisions included recalculation of selected uranium reactions. Additionally, thermodynamic data for the hydroxyl complexes of U(VI), including anionic (VI) species, were evaluated (to the extent permitted by the available data). Vanadium reactions were also added to the thermodynamic data base because uranium-vanadium solids can exist in natural ground-water systems. This study is only a partial validation of the WATEQ4 geochemical model because the available laboratory solubility studies do not cover the range of solid phases, alkaline pH values, and concentrations of inorganic complexing ligands needed to evaluate the potential solubility of uranium in ground waters associated with various proposed nuclear waste repositories. Further validation of this or other geochemical models for uranium will require careful determinations of uraninite solubility over the pH range of 7 to 10 under highly reducing conditions and of uranyl hydroxide and phosphate solubilities over the pH range of 7 to 10 under oxygenated conditions.

  3. Structural Analysis for Gold Mineralization Using Remote Sensing and Geochemical Techniques in a GIS Environment: Island of Lesvos, Hellas

    SciTech Connect (OSTI)

    Rokos, D. Argialas, D. Mavrantza, R. St Seymour, K.; Vamvoukakis, C.; Kouli, M.; Lamera, S.; Paraskevas, H.; Karfakis, I.; Denes, G

    2000-12-15

    Exploration for epithermal Au has been active lately in the Aegean Sea of the eastern Mediterranean Basin, both in the islands of the Quaternary arc and in those of the back-arc region. The purpose of this study was the structural mapping and analysis for a preliminary investigation of possible epithermal gold mineralization, using remotely sensed data and techniques, structural and field data, and geochemical information, for a specific area on the Island of Lesvos. Therefore, Landsat-TM and SPOT-Pan satellite images and the Digital Elevation Model (DEM) of the study area were processed digitally using spatial filtering techniques for the enhancement and recognition of the geologically significant lineaments, as well as algebraic operations with band ratios and Principal Component Analysis (PCA), for the identification of alteration zones. Statistical rose diagrams and a SCHMIDT projection Stereo Net were generated from the lineament maps and the collected field data (dip and strike measurements of faults, joints, and veins), respectively. The derived lineament map and the band ratio images were manipulated in a GIS environment, in order to study the relation of the tectonic pattern to both the alteration zoning and the geomorphology of the volcanic field of the study area. Target areas of high interest for possible mineralization also were specified using geochemical techniques, such as X-Ray Diffraction (XRD) analysis, trace-element, and fluid-inclusion analysis. Finally, preliminary conclusions were derived about possible mineralization, the type (high or low sulfidation), and the extent of mineralization, by combining the structural information with geochemical information.

  4. Actualistic and Geochemical Modeling of Reservoir Rock, CO2 and Formation Fluid Interaction, Citronelle Oil Field, Alabama

    SciTech Connect (OSTI)

    Weislogel, Amy

    2014-01-31

    This report includes description of the Citronelle field study area and the work carried out in the project to characterize the geology and composition of reservoir rock material and to collect an analyze the geochemical composition of produced fluid waters from the Citronelle field. Reservoir rock samples collected from well bore core were made into thin-sections and assessed for textural properties, including pore types and porosity distribution. Compositional framework grain modal data were collected via point-counting, and grain and cement mineralogy was assessed using SEM-EDS. Geochemistry of fluid samples is described and modeled using PHREEQC. Composition of rock and produced fluids were used as inputs for TOUGHREACT reactive transport modeling, which determined the rock-fluid system was in disequilibrium.

  5. Hawaii geologic map data | Open Energy Information

    Open Energy Info (EERE)

    geologic map data Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Hawaii geologic map data Published USGS, Date Not Provided DOI Not Provided Check for...

  6. Utah Geological Survey | Open Energy Information

    Open Energy Info (EERE)

    Logo: Utah Geological Survey Name: Utah Geological Survey Address: 1594 W. North Temple Place: Salt Lake City, Utah Zip: 84114-6100 Phone Number: 801.537.3300 Website:...

  7. Application of micro-PIXE method to ore geology

    SciTech Connect (OSTI)

    Murao, S.; Hamasaki, S.; Sie, S. H.; Maglambayan, V. B.; Hu, X.

    1999-06-10

    Specific examples of ore mineral analysis by micro-PIXE are presented in this paper. For mineralogical usage it is essential to construct a specimen chamber which is designed exclusively for mineral analysis. In most of the analysis of natural minerals, selection of absorbers is essential in order to obtain optimum results. Trace element data reflect the crystallographic characteristics of each mineral and also geologic settings of sampling locality, and can be exploited in research spanning mineral exploration to beneficiation. Micro-PIXE thus serves as a bridge between small-scale mineralogical experiments and understanding of large-scale geological phenomenon on the globe.

  8. Merging high resolution geophysical and geochemical surveys to reduce exploration risk at glass buttes, Oregon

    SciTech Connect (OSTI)

    Walsh, Patrick; Fercho, Steven; Perkin, Doug; Martini, Brigette; Boshmann, Darrick

    2015-06-01

    The engineering and studies phase of the Glass Buttes project was aimed at reducing risk during the early stages of geothermal project development. The project’s inclusion of high resolution geophysical and geochemical surveys allowed Ormat to evaluate the value of these surveys both independently and in combination to quantify the most valuable course of action for exploration in an area where structure, permeability, and temperature are the most pressing questions. The sizes of the thermal anomalies at Glass Buttes are unusually large. Over the course of Phase I Ormat acquired high resolution LIDAR data to accurately map fault manifestations at the surface and collected detailed gravity and aeromagnetic surveys to map subsurface structural features. In addition, Ormat collected airborne hyperspectral data to assist with mapping the rock petrology and mineral alteration assemblages along Glass Buttes faults and magnetotelluric (MT) survey to try to better constrain the structures at depth. Direct and indirect identification of alteration assemblages reveal not only the geochemical character and temperature of the causative hydrothermal fluids but can also constrain areas of upflow along specific fault segments. All five datasets were merged along with subsurface lithologies and temperatures to predict the most likely locations for high permeability and hot fluids. The Glass Buttes temperature anomalies include 2 areas, totaling 60 km2 (23 mi2) of measured temperature gradients over 165° C/km (10° F/100ft). The Midnight Point temperature anomaly includes the Strat-1 well with 90°C (194 °F) at 603 m (1981 ft) with a 164 °C/km (10°F/100ft) temperature gradient at bottom hole and the GB-18 well with 71°C (160 °F) at 396 m (1300 ft) with a 182°C/km (11°F/100ft) gradient. The primary area of alteration and elevated temperature occurs near major fault intersections associated with Brothers Fault Zone and Basin and Range systems. Evidence for faulting is observed in each data set as follows. Field observations include fault plane orientations, complicated fault intersections, and hydrothermal alteration apparently pre-dating basalt flows. Geophysical anomalies include large, linear gradients in gravity and aeromagnetic data with magnetic lows possibly associated with alteration. Resistivity low anomalies also appear to have offsets associated with faulting. Hyperspectral and XRF identified alteration and individual volcanic flow units, respectively. When incorporated into a 3D geologic model, the fault intersections near the highest proven temperature and geophysical anomalies provide the first priority targets at Midnight Point. Ormat geologists selected the Midnight Point 52-33 drilling target based on a combination of pre-existing drilling data, geologic field work, geophysical interpretation, and geochemical analysis. Deep temperatures of well 52-33 was lower than anticipated. Temperature gradients in the well mirrored those found in historical drilling, but they decreased below 1500 ft and were isothermal below 2000 ft.

  9. Hanford Borehole Geologic Information System (HBGIS)

    SciTech Connect (OSTI)

    Last, George V.; Mackley, Rob D.; Saripalli, Ratna R.

    2005-09-26

    This is a user's guide for viewing and downloading borehold geologic data through a web-based interface.

  10. Montana Bureau of Mines and Geology Website | Open Energy Information

    Open Energy Info (EERE)

    Web Site: Montana Bureau of Mines and Geology Website Abstract Provides access to digital information on Montana's geology. Author Montana Bureau of Mines and Geology...

  11. CMI Education Course Inventory: Geology Engineering/Geochemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Course Inventory: Geology EngineeringGeochemistry Geology EngineeringGeochemistry Of the six CMI Team members that are educational institutions, five offer courses in Geology....

  12. Oregon Department of Geology and Mineral Industries | Open Energy...

    Open Energy Info (EERE)

    Geology and Mineral Industries Jump to: navigation, search Logo: Oregon Department of Geology and Mineral Industries Name: Oregon Department of Geology and Mineral Industries...

  13. Nanogeochemistry: Geochemical reactions and mass transfers in nanopores

    Office of Scientific and Technical Information (OSTI)

    Frontiers in Geoscience SAND2015-3647C Nanogeochemistry: Nanostructures, emergent properties and their control on geochemical reactions and mass transfers Yifeng Wang Sandia National Laboratories Albuquerque, New Mexico 87185 May 11, 2015, Los Alamos National Laboratory Sandia National Laboratories Nanoscales Angstrom (10-10m) Nanometer Micron Millimeter Meter Kilometer 1000 kilometers (10-9m) (10-6m) (10-3 m) (m) (103 m) (103 m) Why so important? * Emergent properties * Key linkage between

  14. Argonne Geothermal Geochemical Database v2.0

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Harto, Christopher

    2013-05-22

    A database of geochemical data from potential geothermal sources aggregated from multiple sources as of March 2010. The database contains fields for the location, depth, temperature, pH, total dissolved solids concentration, chemical composition, and date of sampling. A separate tab contains data on non-condensible gas compositions. The database contains records for over 50,000 wells, although many entries are incomplete. Current versions of source documentation are listed in the dataset.

  15. Geochemical Triggers of Arsenic Mobilization during Managed Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recharge | Stanford Synchrotron Radiation Lightsource Geochemical Triggers of Arsenic Mobilization during Managed Aquifer Recharge Monday, February 29, 2016 Managed aquifer recharge (MAR) is an increasingly used water enhancement strategy, which involves subsurface storage of water supplies in groundwater aquifers. While MAR projects have the potential to alleviate water deficits, they can also adversely impact groundwater quality by altering the native geochemistry of the aquifer and

  16. Argonne Geothermal Geochemical Database v2.0

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Harto, Christopher

    A database of geochemical data from potential geothermal sources aggregated from multiple sources as of March 2010. The database contains fields for the location, depth, temperature, pH, total dissolved solids concentration, chemical composition, and date of sampling. A separate tab contains data on non-condensible gas compositions. The database contains records for over 50,000 wells, although many entries are incomplete. Current versions of source documentation are listed in the dataset.

  17. Preliminary Geologic Characterization of West Coast States for Geologic Sequestration

    SciTech Connect (OSTI)

    Larry Myer

    2005-09-29

    Characterization of geological sinks for sequestration of CO{sub 2} in California, Nevada, Oregon, and Washington was carried out as part of Phase I of the West Coast Regional Carbon Sequestration Partnership (WESTCARB) project. Results show that there are geologic storage opportunities in the region within each of the following major technology areas: saline formations, oil and gas reservoirs, and coal beds. The work focused on sedimentary basins as the initial most-promising targets for geologic sequestration. Geographical Information System (GIS) layers showing sedimentary basins and oil, gas, and coal fields in those basins were developed. The GIS layers were attributed with information on the subsurface, including sediment thickness, presence and depth of porous and permeable sandstones, and, where available, reservoir properties. California offers outstanding sequestration opportunities because of its large capacity and the potential of value-added benefits from enhanced oil recovery (EOR) and enhanced gas recovery (EGR). The estimate for storage capacity of saline formations in the ten largest basins in California ranges from about 150 to about 500 Gt of CO{sub 2}, depending on assumptions about the fraction of the formations used and the fraction of the pore volume filled with separate-phase CO{sub 2}. Potential CO{sub 2}-EOR storage was estimated to be 3.4 Gt, based on a screening of reservoirs using depth, an API gravity cutoff, and cumulative oil produced. The cumulative production from gas reservoirs (screened by depth) suggests a CO{sub 2} storage capacity of 1.7 Gt. In Oregon and Washington, sedimentary basins along the coast also offer sequestration opportunities. Of particular interest is the Puget Trough Basin, which contains up to 1,130 m (3,700 ft) of unconsolidated sediments overlying up to 3,050 m (10,000 ft) of Tertiary sedimentary rocks. The Puget Trough Basin also contains deep coal formations, which are sequestration targets and may have potential for enhanced coal bed methane recovery (ECBM).

  18. International Collaboration Activities in Different Geologic Disposal Environments

    SciTech Connect (OSTI)

    Birkholzer, Jens

    2015-09-01

    This report describes the current status of international collaboration regarding geologic disposal research in the Used Fuel Disposition (UFD) Campaign. Since 2012, in an effort coordinated by Lawrence Berkeley National Laboratory, UFD has advanced active collaboration with several international geologic disposal programs in Europe and Asia. Such collaboration allows the UFD Campaign to benefit from a deep knowledge base with regards to alternative repository environments developed over decades, and to utilize international investments in research facilities (such as underground research laboratories), saving millions of R&D dollars that have been and are being provided by other countries. To date, UFD’s International Disposal R&D Program has established formal collaboration agreements with five international initiatives and several international partners, and national lab scientists associated with UFD have conducted specific collaborative R&D activities that align well with its R&D priorities.

  19. National Uranium Resource Evaluation. Volume 1. Summary of the geology and uranium potential of Precambrian conglomerates in southeastern Wyoming

    SciTech Connect (OSTI)

    Karlstrom, K.E.; Houston, R.S.; Flurkey, A.J.; Coolidge, C.M.; Kratochvil, A.L.; Sever, C.K.

    1981-02-01

    A series of uranium-, thorium-, and gold-bearing conglomerates in Late Archean and Early Proterozoic metasedimentary rocks have been discovered in southern Wyoming. The mineral deposits were found by applying the time and strata bound model for the origin of uranium-bearing quartz-pebble conglomerates to favorable rock types within a geologic terrane known from prior regional mapping. No mineral deposits have been discovered that are of current (1981) economic interest, but preliminary resource estimates indicate that over 3418 tons of uranium and over 1996 tons of thorium are present in the Medicine Bow Mountains and that over 440 tons of uranium and 6350 tons of thorium are present in Sierra Madre. Sampling has been inadequate to determine gold resources. High grade uranium deposits have not been detected by work to date but local beds of uranium-bearing conglomerate contain as much as 1380 ppM uranium over a thickness of 0.65 meters. This project has involved geologic mapping at scales from 1/6000 to 1/50,000 detailed sampling, and the evaluation of 48 diamond drill holes, but the area is too large to fully establish the economic potential with the present information. This first volume summarizes the geologic setting and geologic and geochemical characteristics of the uranium-bearing conglomerates. Volume 2 contains supporting geochemical data, lithologic logs from 48 drill holes in Precambrian rocks, and drill site geologic maps and cross-sections from most of the holes. Volume 3 is a geostatistical resource estimate of uranium and thorium in quartz-pebble conglomerates.

  20. US Geological Survey publications on western tight gas reservoirs

    SciTech Connect (OSTI)

    Krupa, M.P.; Spencer, C.W.

    1989-02-01

    This bibliography includes reports published from 1977 through August 1988. In 1977 the US Geological Survey (USGS), in cooperation with the US Department of Energy's, (DOE), Western Gas Sands Research program, initiated a geological program to identify and characterize natural gas resources in low-permeability (tight) reservoirs in the Rocky Mountain region. These reservoirs are present at depths of less than 2,000 ft (610 m) to greater than 20,000 ft (6,100 m). Only published reports readily available to the public are included in this report. Where appropriate, USGS researchers have incorporated administrative report information into later published studies. These studies cover a broad range of research from basic research on gas origin and migration to applied studies of production potential of reservoirs in individual wells. The early research included construction of regional well-log cross sections. These sections provide a basic stratigraphic framework for individual areas and basins. Most of these sections include drill-stem test and other well-test data so that the gas-bearing reservoirs can be seen in vertical and areal dimensions. For the convenience of the reader, the publications listed in this report have been indexed by general categories of (1) authors, (2) states, (3) geologic basins, (4) cross sections, (5) maps (6) studies of gas origin and migration, (7) reservoir or mineralogic studies, and (8) other reports of a regional or specific topical nature.

  1. Center for Nanoscale Controls on Geologic CO2 (NCGC) | U.S. DOE Office of

    Office of Science (SC) Website

    Science (SC) Center for Nanoscale Controls on Geologic CO2 (NCGC) Energy Frontier Research Centers (EFRCs) EFRCs Home Centers EFRC External Websites Research Science Highlights News & Events Publications History Contact BES Home Centers Center for Nanoscale Controls on Geologic CO2 (NCGC) Print Text Size: A A A FeedbackShare Page NCGC Header Director Donald DePaolo Lead Institution Lawrence Berkeley National Laboratory Year Established 2009 Mission To enhance the performance and

  2. Research | Savannah River Ecology Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Gene Odum forest sampling marked tortoise geochemical sampling quantifying radionuclide absorption collcting microbes microsatellite development R E S E A R C H A R E A S * Aquatic and terrestrial ecology * Biogeochemistry & soil science * Environmental microbiology * Herpetology * Hydrology * Molecular genetics * Physiological ecology * Conservation biology * Radiation ecology * Ecotoxicology and risk assessment * Remediation and restoration SREL scientists pursue a wide variety of

  3. Geochemical drivers of organic matter decomposition in Arctic tundra soils

    SciTech Connect (OSTI)

    Herndon, Elizabeth M.; Yang, Ziming; Graham, David E.; Wullschleger, Stan D.; Gu, Baohua; Liang, Liyuan; Bargar, John; Janot, Noemie; Regier, Tom Z.

    2015-12-07

    Climate change is warming tundra ecosystems in the Arctic, resulting in the decomposition of previously-frozen soil organic matter (SOM) and release of carbon (C) to the atmosphere; however, the processes that control SOM decomposition and C emissions remain highly uncertain. In this study, we evaluate geochemical factors that influence anaerobic production of carbon dioxide (CO2) and methane (CH4) in the active layers of four ice-wedge polygons. Surface and soil pore waters were collected during the annual thaw season over a two-year period in an area containing waterlogged, low-centered polygons and well-drained, high-centered polygons. We report spatial and seasonal patterns of dissolved gases in relation to the geochemical properties of Fe and organic C as determined using spectroscopic and chromatographic techniques. Iron was present as Fe(II) in soil solution near the permafrost boundary but enriched as Fe(III) in the middle of the active layer, similar to dissolved aromatic-C and organic acids. Dissolved CH4 increased relative to dissolved CO2 with depth and varied with soil moisture in the middle of the active layer in patterns that were positively correlated with the proportion of dissolved Fe(III) in transitional and low-centered polygon soils but negatively correlated in the drier flat- and high-centered polygons. These results suggest that microbial-mediated Fe oxidation and reduction influence respiration/fermentation of SOM and production of substrates (e.g., low-molecular-weight organic acids) for methanogenesis. As a result, we infer that geochemical differences induced by water saturation dictate microbial products of SOM decomposition, and Fe geochemistry is an important factor regulating methanogenesis in anoxic tundra soils.

  4. Geochemical drivers of organic matter decomposition in Arctic tundra soils

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Herndon, Elizabeth M.; Yang, Ziming; Graham, David E.; Wullschleger, Stan D.; Gu, Baohua; Liang, Liyuan; Bargar, John; Janot, Noemie; Regier, Tom Z.

    2015-12-07

    Climate change is warming tundra ecosystems in the Arctic, resulting in the decomposition of previously-frozen soil organic matter (SOM) and release of carbon (C) to the atmosphere; however, the processes that control SOM decomposition and C emissions remain highly uncertain. In this study, we evaluate geochemical factors that influence anaerobic production of carbon dioxide (CO2) and methane (CH4) in the active layers of four ice-wedge polygons. Surface and soil pore waters were collected during the annual thaw season over a two-year period in an area containing waterlogged, low-centered polygons and well-drained, high-centered polygons. We report spatial and seasonal patterns ofmore » dissolved gases in relation to the geochemical properties of Fe and organic C as determined using spectroscopic and chromatographic techniques. Iron was present as Fe(II) in soil solution near the permafrost boundary but enriched as Fe(III) in the middle of the active layer, similar to dissolved aromatic-C and organic acids. Dissolved CH4 increased relative to dissolved CO2 with depth and varied with soil moisture in the middle of the active layer in patterns that were positively correlated with the proportion of dissolved Fe(III) in transitional and low-centered polygon soils but negatively correlated in the drier flat- and high-centered polygons. These results suggest that microbial-mediated Fe oxidation and reduction influence respiration/fermentation of SOM and production of substrates (e.g., low-molecular-weight organic acids) for methanogenesis. As a result, we infer that geochemical differences induced by water saturation dictate microbial products of SOM decomposition, and Fe geochemistry is an important factor regulating methanogenesis in anoxic tundra soils.« less

  5. Research News July 2015, Issue 10

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of injecting and maintaining CO 2 in geological formations, it can also be permanently ... laboratory's research has characterized REEs in Marcellus Shale outcrops and core samples. ...

  6. EQ3/6 A Software Package for Geochemical Modeling

    Energy Science and Technology Software Center (OSTI)

    2010-12-13

    EQ3/6 is a software package for modeling geochemical interactions between aqueous solution, solids, and gases, following principles of chemical thermodynamics and chemical kinetics. It is useful for interpreting aqueiou solution chemical compositions and for calculating the consequences of reaction of such solutions with minerals, other solids, and gases. It is designed to run in a command line environment. EQPT is a thermodynamic data file preprocessor. EQ3NR is a speciation-solubility code. EQ6 is a reaction pathmore » code.« less

  7. Regional geophysics, Cenozoic tectonics and geologic resources...

    Open Energy Info (EERE)

    and geologic resources of the Basin and Range Province and adjoining regions Author G.P. Eaton Conference Basin and Range Symposium and Great Basin Field Conference; Denver,...

  8. Wyoming State Geological Survey | Open Energy Information

    Open Energy Info (EERE)

    navigation, search Name: Wyoming State Geological Survey Abbreviation: WSGS Address: P.O. Box 1347 Place: Laramie, Wyoming Zip: 82073 Year Founded: 1933 Phone Number:...

  9. Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal systems

    Broader source: Energy.gov [DOE]

    Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal systems presentation at the April 2013 peer review meeting held in Denver, Colorado.

  10. Novel Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners

    Broader source: Energy.gov [DOE]

    Novel Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners presentation at the April 2013 peer review meeting held in Denver, Colorado.

  11. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1 Citation Details...

  12. Energy Department Lab Researcher Wins HENAAC Award for Outstanding...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hakala's separate, ongoing research is in geologic CO2 storage. Results from this research can be implemented into water quality prediction models to protect groundwater in areas ...

  13. Geologic Controls of Hydrocarbon Occurrence in the Appalachian Basin in Eastern Tennessee, Southwestern Virginia, Eastern Kentucky, and Southern West Virginia

    SciTech Connect (OSTI)

    Hatcher, Robert D

    2005-11-30

    This report summarizes the accomplishments of a three-year program to investigate the geologic controls of hydrocarbon occurrence in the southern Appalachian basin in eastern Tennessee, southwestern Virginia, eastern Kentucky, and southern West Virginia. The project: (1) employed the petroleum system approach to understand the geologic controls of hydrocarbons; (2) attempted to characterize the P-T parameters driving petroleum evolution; (3) attempted to obtain more quantitative definitions of reservoir architecture and identify new traps; (4) is worked with USGS and industry partners to develop new play concepts and geophysical log standards for subsurface correlation; and (5) geochemically characterized the hydrocarbons (cooperatively with USGS). Third-year results include: All project milestones have been met and addressed. We also have disseminated this research and related information through presentations at professional meetings, convening a major workshop in August 2003, and the publication of results. Our work in geophysical log correlation in the Middle Ordovician units is bearing fruit in recognition that the criteria developed locally in Tennessee and southern Kentucky are more extendible than anticipated earlier. We have identified a major 60 mi-long structure in the western part of the Valley and Ridge thrust belt that has been successfully tested by a local independent and is now producing commercial amounts of hydrocarbons. If this structure is productive along strike, it will be one of the largest producing structures in the Appalachians. We are completing a more quantitative structural reconstruction of the Valley and Ridge and Cumberland Plateau than has been made before. This should yield major dividends in future exploration in the southern Appalachian basin. Our work in mapping, retrodeformation, and modeling of the Sevier basin is a major component of the understanding of the Ordovician petroleum system in this region. Prior to our undertaking this project, this system was the least understood in the Appalachian basin. This project, in contrast to many if not most programs undertaken in DOE laboratories, has a major educational component wherein three Ph.D. students have been partially supported by this grant, one M.S. student partially supported, and another M.S. student fully supported by the project. These students will be well prepared for professional careers in the oil and gas industry.

  14. GEOCHEMICAL INVESTIGATIONS OF CO₂-BRINE-ROCK INTERACTIONS OF THE KNOX GROUP IN THE ILLINOIS BASIN

    SciTech Connect (OSTI)

    Yoksoulian, Lois; Berger, Peter; Freiburg, Jared; Butler, Shane; Leetaru, Hannes

    2014-09-30

    Increased output of greenhouse gases, particularly carbon dioxide (CO₂), into the atmosphere from anthropogenic sources is of great concern. A potential technology to reduce CO₂ emissions is geologic carbon sequestration. This technology is currently being evaluated in the United States and throughout the world. The geology of the Illinois Basin exhibits outstanding potential as a carbon sequestration target, as demonstrated by the ongoing Illinois Basin – Decatur Project that is using the Mt. Simon Sandstone reservoir and Eau Claire Shale seal system to store and contain 1 million tonnes of CO₂. The Knox Group-Maquoketa Shale reservoir and seal system, located stratigraphically above the Mt. Simon Sandstone-Eau Claire Shale reservoir and seal system, has little economic value as a resource for fossil fuels or as a potable water source, making it ideal as a potential carbon sequestration target. In order for a reservoir-seal system to be effective, it must be able to contain the injected CO₂ without the potential for the release of harmful contaminants liberated by the reaction between CO₂-formation fluids and reservoir and seal rocks. This study examines portions of the Knox Group (Potosi Dolomite, Gunter Sandstone, New Richmond Sandstone) and St. Peter Sandstone, and Maquoketa Shale from various locations around the Illinois Basin. A total of 14 rock and fluid samples were exposed to simulated sequestration conditions (9101–9860 kPa [1320–1430 psi] and 32°–42°C [90°– 108°F]) for varying amounts of time (6 hours to 4 months). Knox Group reservoir rocks exhibited dissolution of dolomite in the presence of CO₂ as indicated by petrographic examination, X-ray diffraction analysis, and fluid chemistry analysis. These reactions equilibrated rapidly, and geochemical modeling confirmed that these reactions reached equilibrium within the time frames of the experiments. Pre-reaction sample mineralogy and postreaction fluid geochemistry from this study suggests only limited potential for the release of United States Environmental Protection Agency regulated inorganic contaminants into potable water sources. Short-term core flood experiments further verify that the carbonate reactions occurring in Knox Group reservoir samples reach equilibrium rapidly. The core flood experiments also lend insight to pressure changes that may occur during CO₂ injection. The Maquoketa Shale experiments reveal that this rock is initially chemically reactive when in contact with CO₂ and brine. However, due to the conservative nature of silicate and clay reaction kinetics and the rapid equilibration of carbonate reactions that occur in the shale, these reactions would not present a significant risk to the competency of the shale as an effective seal rock.

  15. FY12 ARRA-NRAP Report Studies to Support Risk Assessment of Geologic Carbon Sequestration

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Shao, Hongbo; Thompson, C. J.; Zhong, Lirong; Jung, Hun Bok; Um, Wooyong

    2011-09-27

    This report summarizes results of research conducted during FY2012 to support the assessment of environmental risks associated with geologic carbon dioxide (CO2) sequestration and storage. Several research focus areas are ongoing as part of this project. This includes the quantification of the leachability of metals and organic compounds from representative CO2 storage reservoir and caprock materials, the fate of metals and organic compounds after release, and the development of a method to measure pH in situ under supercritical CO2 (scCO2) conditions. Metal leachability experiments were completed on 6 different rock samples in brine in equilibrium with scCO2 at representative geologic reservoir conditions. In general, the leaching of RCRA metals and other metals of concern was found to be limited and not likely to be a significant issue (at least, for the rocks tested). Metals leaching experiments were also completed on 1 rock sample with scCO2 containing oxygen at concentrations of 0, 1, 5, and 10% to simulate injection of CO2 originating from the oxy-fuel combustion process. Significant differences in the leaching behavior of certain metals were observed when oxygen is present in the CO2. These differences resulted from oxidation of sulfides, release of sulfate, ferric iron and other metals, and subsequent precipitation of iron oxides and some sulfates such as barite. Experiments to evaluate the potential for mobilization of organic compounds from representative reservoir materials and cap rock and their fate in porous media (quartz sand) have been conducted. Results with Fruitland coal and Gothic shale indicate that lighter organic compounds were more susceptible to mobilization by scCO2 compared to heavier compounds. Alkanes demonstrated very low extractability by scCO2. No significant differences were observed between the extractability of organic compounds by dry or water saturated scCO2. Reaction equilibrium appears to have been reached by 96 hours. When the scCO2 was released from the reactor, less than 60% of the injected lighter compounds (benzene, toluene) were transported through dry sand column by the CO2, while more than 90% of the heavier organics were trapped in the sand column. For wet sand columns, most (80% to 100%) of the organic compounds injected into the sand column passed through, except for naphthalene which was substantial removed from the CO2 within the column. A spectrophotometric method was developed to measure pH in brines in contact with scCO2. This method provides an alternative to fragile glass pH electrodes and thermodynamic modeling approaches for estimating pH. The method was tested in simulated reservoir fluids (CO2NaClH2O) at different temperatures, pressures, and ionic strength, and the results were compared with other experimental studies and geochemical models. Measured pH values were generally in agreement with the models, but inconsistencies were present between some of the models.

  16. Generic Deep Geologic Disposal Safety Case

    Broader source: Energy.gov [DOE]

    The Generic Deep Geologic Disposal Safety Case presents generic information that is of use in understanding potential deep geologic disposal options (e.g., salt, shale, granite, deep borehole) in the U.S. for used nuclear fuel (UNF) from reactors and high-level radioactive waste (HLW).

  17. Geochemical and Isotopic Interpretations of Groundwater Flow in the Oasis Valley Flow System, Southern Nevada

    SciTech Connect (OSTI)

    J.M. Thomas; F.C. Benedict, Jr.; T.P. Rose; R.L. Hershey; J.B. Paces; Z.E. Peterman; I.M. Farnham; K.H. Johannesson; A.K. Singh; K.J. Stetzenbach; G.B. Hudson; J.M. Kenneally; G.F. Eaton; D.K. Smith

    2003-01-08

    This report summarizes the findings of a geochemical investigation of the Pahute Mesa-Oasis Valley groundwater flow system in southwestern Nevada. It is intended to provide geochemical data and interpretations in support of flow and contaminant transport modeling for the Western and Central Pahute Mesa Corrective Action Units.

  18. Global Warming in Geologic Time

    SciTech Connect (OSTI)

    David Archer

    2008-02-27

    The notion is pervasive in the climate science community and in the public at large that the climate impacts of fossil fuel CO2 release will only persist for a few centuries. This conclusion has no basis in theory or models of the atmosphere / ocean carbon cycle, which we review here. The largest fraction of the CO2 recovery will take place on time scales of centuries, as CO2 invades the ocean, but a significant fraction of the fossil fuel CO2, ranging in published models in the literature from 20-60%, remains airborne for a thousand years or longer. Ultimate recovery takes place on time scales of hundreds of thousands of years, a geologic longevity typically associated in public perceptions with nuclear waste. The glacial / interglacial climate cycles demonstrate that ice sheets and sea level respond dramatically to millennial-timescale changes in climate forcing. There are also potential positive feedbacks in the carbon cycle, including methane hydrates in the ocean, and peat frozen in permafrost, that are most sensitive to the long tail of the fossil fuel CO2 in the atmosphere.

  19. Global Warming in Geologic Time

    SciTech Connect (OSTI)

    Archer, David

    2008-02-27

    The notion is pervasive in the climate science community and in the public at large that the climate impacts of fossil fuel CO2 release will only persist for a few centuries. This conclusion has no basis in theory or models of the atmosphere/ ocean carbon cycle, which we review here. The largest fraction of the CO2 recovery will take place on time scales of centuries, as CO2 invades the ocean, but a significant fraction of the fossil fuel CO2, ranging in published models in the literature from 20-60%, remains airborne for a thousand years or longer. Ultimate recovery takes place on time scales of hundreds of thousands of years, a geologic longevity typically associated in public perceptions with nuclear waste. The glacial/interglacial climate cycles demonstrate that ice sheets and sea level respond dramatically to millennial-timescale changes in climate forcing. There are also potential positive feedbacks in the carbon cycle, including methane hydrates in the ocean, and peat frozen in permafrost, that are most sensitive to the long tail of the fossil fuel CO2 in the atmosphere.

  20. Global Warming in Geologic Time

    ScienceCinema (OSTI)

    David Archer

    2010-01-08

    The notion is pervasive in the climate science community and in the public at large that the climate impacts of fossil fuel CO2 release will only persist for a few centuries. This conclusion has no basis in theory or models of the atmosphere / ocean carbon cycle, which we review here. The largest fraction of the CO2 recovery will take place on time scales of centuries, as CO2 invades the ocean, but a significant fraction of the fossil fuel CO2, ranging in published models in the literature from 20-60%, remains airborne for a thousand years or longer. Ultimate recovery takes place on time scales of hundreds of thousands of years, a geologic longevity typically associated in public perceptions with nuclear waste. The glacial / interglacial climate cycles demonstrate that ice sheets and sea level respond dramatically to millennial-timescale changes in climate forcing. There are also potential positive feedbacks in the carbon cycle, including methane hydrates in the ocean, and peat frozen in permafrost, that are most sensitive to the long tail of the fossil fuel CO2 in the atmosphere.

  1. Recovery Act: Geologic Sequestration Training and Research Walsh...

    Office of Scientific and Technical Information (OSTI)

    simulation, and (6) development of an advanced undergraduategraduate level course on coal combustion and gasification, climate change, and carbon sequestration. Four graduate...

  2. Deep Borehole Disposal Research: Geological Data Evaluation Alternativ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    much of the enhanced geothermal focus on stimulating fracture development (e.g., fracking) at depth is not directly relevant to deep borehole disposal. For deep borehole...

  3. Deep Borehole Disposal Research: Geological Data Evaluation Alternativ...

    Office of Scientific and Technical Information (OSTI)

    Content: Close Send 0 pages in this document matching the terms "" Search For Terms: Enter terms in the toolbar above to search the full text of this document for pages...

  4. STOMP-ECKEChem: An Engineering Perspective on Reactive Transport in Geologic Media

    SciTech Connect (OSTI)

    White, Mark D.; Fang, Yilin

    2012-04-04

    ECKEChem (Equilibrium, Conservation, Kinetic Equation Chemistry) is a reactive transport module for the STOMP suite of multifluid subsurface flow and transport simulators that was developed from an engineering perspective. STOMP comprises a suite of operational modes that are distinguished by the solved coupled conservation equations with capabilities for a variety of subsurface applications (e.g., environmental remediation and stewardship, geologic sequestration of greenhouse gases, gas hydrate production, and oil shale production). The ECKEChem module was designed to provide integrated reactive transport capabilities across the suite of STOMP simulator operational modes. The initial application for the ECKEChem module was in the simulation of the mineralization reactions that occurred with the injection of supercritical carbon dioxide into deep Columbia River basalt formations, where it was implemented in the STOMP-CO2 simulator. The STOMP-ECKEChem solution approach to modeling reactive transport in multifluid geologic media is founded on an engineering perspective: (1) sequential non-iterative coupling between the flow and reactive transport is sufficient, (2) reactive transport can be modeled by operator splitting with local geochemistry and global transport, (3) geochemistry can be expressed as a system of coupled nonlinear equilibrium, conservation and kinetic equations, (4) a limited number of kinetic equation forms are used in geochemical practice. This chapter describes the conceptual approach to converting a geochemical reaction network into a series of equilibrium, conservation and kinetic equations, the implementation of ECKEChem in STOMP, the numerical solution approach, and a demonstration of the simulator on a complex application involving desorption of uranium from contaminated field-textured sediments.

  5. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground (LBNL Summer Lecture Series)

    ScienceCinema (OSTI)

    Oldenburg, Curtis M [LBNL Earth Sciences Division

    2011-04-28

    Summer Lecture Series 2009: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  6. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground (LBNL Summer Lecture Series)

    SciTech Connect (OSTI)

    Oldenburg, Curtis M

    2009-07-21

    Summer Lecture Series 2009: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  7. Constructing Hydraulic Barriers in Deep Geologic Formations

    SciTech Connect (OSTI)

    Carter, E.E.; Carter, P.E. [Technologies Co, Texas (United States); Cooper, D.C. [Ph.D. Idaho National Laboratory, Idaho Falls, ID (United States)

    2008-07-01

    Many construction methods have been developed to create hydraulic barriers to depths of 30 to 50 meters, but few have been proposed for depths on the order of 500 meters. For these deep hydraulic barriers, most methods are potentially feasible for soil but not for hard rock. In the course of researching methods of isolating large subterranean blocks of oil shale, the authors have developed a wax thermal permeation method for constructing hydraulic barriers in rock to depths of over 500 meters in competent or even fractured rock as well as soil. The technology is similar to freeze wall methods, but produces a permanent barrier; and is potentially applicable in both dry and water saturated formations. Like freeze wall barriers, the wax thermal permeation method utilizes a large number of vertical or horizontal boreholes around the perimeter to be contained. However, instead of cooling the boreholes, they are heated. After heating these boreholes, a specially formulated molten wax based grout is pumped into the boreholes where it seals fractures and also permeates radially outward to form a series of columns of wax-impregnated rock. Rows of overlapping columns can then form a durable hydraulic barrier. These barriers can also be angled above a geologic repository to help prevent influx of water due to atypical rainfall events. Applications of the technique to constructing containment structures around existing shallow waste burial sites and water shutoff for mining are also described. (authors)

  8. Borehole Imaging of In Situ Stress Tests at Mirror Lake Research...

    Open Energy Info (EERE)

    at Mirror Lake Research Site Citation U.S. Geological Survey. Borehole Imaging of In Situ Stress Tests at Mirror Lake Research Site Internet. 2013. U.S. Geological Survey. cited...

  9. The hydrogeologic-geochemical model of Cerro Prieto revisited

    SciTech Connect (OSTI)

    Lippmann, M.J.; Halfman, S.E.; Truesdell, A.H.; Manon M., A.

    1989-01-01

    As the exploitation of the Cerro Prieto, Mexico, geothermal field continues, there is increasing evidence that the hydrogeologic model developed by Halfman et al. (1984, 1986) presents the basic features controlling the movement of geothermal fluids in the system. At the present time the total installed capacity at Cerro Prieto is 620 MWe requiring the production of more than 10,500 tonnes/hr of a brine-steam mixture. This significant rate of fluid production has resulted in changes in reservoir thermodynamic conditions and in the chemistry of the produced fluids. After reviewing the hydrogeologic-geochemical model of Cerro Prieto, some of the changes observed in the field due to its exploitation are discussed and interpreted on the basis of the model. 21 refs., 11 figs., 1 tab.

  10. Evaluation of the geologic relations and seismotectonic stability of the Yucca Mountain area, Nevada Nuclear Waste Site Investigation (NNWSI); Final report, January 1, 1987--June 30, 1988: Volume 1

    SciTech Connect (OSTI)

    1988-10-01

    This report provides a summary of progress for the project ``Evaluation of the Geologic Relations and Seismotectonic Stability of the Yucca Mountain Area, Nevada Nuclear Waste Site Investigation (NNWSI)`` for the eighteen month period of January 1, 1987 to June 10, 1988. This final report was preceded by the final report for the initial six month period, July 1, 1986 to December 31, 1986 (submitted on January 25, 1987, and revised in June 1987.) Quaternary Tectonics, Geochemical, Mineral Deposits, Vulcanic Geology, Seismology, Tectonics, Neotectonics, Remote Sensing, Geotechnical Assessments, Geotechnical Rock Mass Assessments, Basinal Studies, and Strong Ground Motion.

  11. WATEQ3 geochemical model: thermodynamic data for several additional solids

    SciTech Connect (OSTI)

    Krupka, K.M.; Jenne, E.A.

    1982-09-01

    Geochemical models such as WATEQ3 can be used to model the concentrations of water-soluble pollutants that may result from the disposal of nuclear waste and retorted oil shale. However, for a model to competently deal with these water-soluble pollutants, an adequate thermodynamic data base must be provided that includes elements identified as important in modeling these pollutants. To this end, several minerals and related solid phases were identified that were absent from the thermodynamic data base of WATEQ3. In this study, the thermodynamic data for the identified solids were compiled and selected from several published tabulations of thermodynamic data. For these solids, an accepted Gibbs free energy of formation, ..delta..G/sup 0//sub f,298/, was selected for each solid phase based on the recentness of the tabulated data and on considerations of internal consistency with respect to both the published tabulations and the existing data in WATEQ3. For those solids not included in these published tabulations, Gibbs free energies of formation were calculated from published solubility data (e.g., lepidocrocite), or were estimated (e.g., nontronite) using a free-energy summation method described by Mattigod and Sposito (1978). The accepted or estimated free energies were then combined with internally consistent, ancillary thermodynamic data to calculate equilibrium constants for the hydrolysis reactions of these minerals and related solid phases. Including these values in the WATEQ3 data base increased the competency of this geochemical model in applications associated with the disposal of nuclear waste and retorted oil shale. Additional minerals and related solid phases that need to be added to the solubility submodel will be identified as modeling applications continue in these two programs.

  12. Idaho Geological Survey and University of Idaho Explore for Geothermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Idaho Geological Survey and University of Idaho Explore for Geothermal Energy Idaho Geological Survey and University of Idaho Explore for Geothermal Energy January 11, 2013 -...

  13. Summary of geology of Colorado related to geothermal potential...

    Open Energy Info (EERE)

    Journal Article: Summary of geology of Colorado related to geothermal potential Author L.T. Grose Published Journal Colorado Geological Survey Bulletin, 1974 DOI Not Provided...

  14. Rock Physics of Geologic Carbon Sequestration/Storage (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Rock Physics of Geologic Carbon SequestrationStorage Citation Details In-Document Search Title: Rock Physics of Geologic Carbon SequestrationStorage This report ...

  15. Rock Physics of Geologic Carbon Sequestration/Storage (Technical...

    Office of Scientific and Technical Information (OSTI)

    Rock Physics of Geologic Carbon SequestrationStorage Citation Details In-Document Search Title: Rock Physics of Geologic Carbon SequestrationStorage This report covers the ...

  16. Rock Physics of Geologic Carbon Sequestration/Storage (Technical...

    Office of Scientific and Technical Information (OSTI)

    Rock Physics of Geologic Carbon SequestrationStorage Citation Details In-Document Search Title: Rock Physics of Geologic Carbon SequestrationStorage You are accessing a ...

  17. North Carolina Geological Survey | Open Energy Information

    Open Energy Info (EERE)

    Address: 1612 Mail Service Center Place: North Carolina Zip: 27699-1612 Website: www.geology.enr.state.nc.us Coordinates: 35.67, -78.66 Show Map Loading map......

  18. Panel 2, Geologic Storage of Hydrogen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    under contract DE-AC04-94AL85000. SAND2014-3954P Geologic Storage of Hydrogen Anna S. Lord Geologist Geotechnology & Engineering Department & Peter H. Kobos Principal ...

  19. Elucidating geochemical response of shallow heterogeneous aquifers to CO2 leakage using high-performance computing: Implications for monitoring of CO2 sequestration

    SciTech Connect (OSTI)

    Navarre-Sitchler, Alexis K.; Maxwell, Reed M.; Siirila, Erica R.; Hammond, Glenn E.; Lichtner, Peter C.

    2013-03-01

    Predicting and quantifying impacts of potential carbon dioxide (CO2) leakage into shallow aquifers that overlie geologic CO2 storage formations is an important part of developing reliable carbon storage techniques. Leakage of CO2 through fractures, faults or faulty wellbores can reduce groundwater pH, inducing geochemical reactions that release solutes into the groundwater and pose a risk of degrading groundwater quality. In order to help quantify this risk, predictions of metal concentrations are needed during geologic storage of CO2. Here, we present regional-scale reactive transport simulations, at relatively fine-scale, of CO2 leakage into shallow aquifers run on the PFLOTRAN platform using high-performance computing. Multiple realizations of heterogeneous permeability distributions were generated using standard geostatistical methods. Increased statistical anisotropy of the permeability field resulted in more lateral and vertical spreading of the plume of impacted water, leading to increased Pb2+ (lead) concentrations and lower pH at a well down gradient of the CO2 leak. Pb2+ concentrations were higher in simulations where calcite was the source of Pb2+ compared to galena. The low solubility of galena effectively buffered the Pb2+ concentrations as galena reached saturation under reducing conditions along the flow path. In all cases, Pb2+ concentrations remained below the maximum contaminant level set by the EPA. Results from this study, compared to natural variability observed in aquifers, suggest that bicarbonate (HCO3) concentrations may be a better geochemical indicator of a CO2 leak under the conditions simulated here.

  20. The French Geological Repository Project Cigeo - 12023

    SciTech Connect (OSTI)

    Harman, Alain; Labalette, Thibaud; Dupuis, Marie-Claude; Ouzounian, Gerald [ANDRA, Chatenay-Malabry (France)

    2012-07-01

    The French Agency for Radioactive Waste Management, ANDRA, was launched by law in 1991 to perform and develop the research programme for managing high level and intermediate level long-lived radioactive waste generated by the French nuclear fleet. After a 15-year intensive research programme, including the study of alternative solutions, an overall review and assessment of the results was organized, including a national public debate. As a result, the Parliament passed a Planning Act on radioactive waste management in 2006. Commissioning of a geological repository by 2025 was one of the most important decisions taken at that time. To reach this goal, a license application must be submitted and reviewed by the competent authorities by 2015. A detailed review and consultation process is, as well, defined in the Planning Act. Beside the legal framework the project needs to progress on two fronts. The first one is on siting. A significant milestone was reached in 2009 with the definition of a defined area to locate the underground repository facilities. This area was approved in March 2010 by the Government, after having collected the opinions and positions of all the interested parties, at both National and local levels. A new phase of dialogue with local players began to refine the implementation scenarios of surface facilities. The final site selection will be approved after a public debate planned for 2013. The second one is the industrial organization, planning and costing. The industrial project of this geological repository was called Cigeo (Centre Industriel de Stockage Geologique). Given the amount of work to be done to comply with the given time framework, a detailed organization with well-defined milestones must be set-up. Cigeo will be a specific nuclear facility, built and operated underground for over a hundred years. The consequence of this long duration is that the development of the repository facilities will take place in successive operational phases. The characteristics of the first waste packages received will determine the work and the corresponding investments by 2025 on the repository site. One of the main challenges will be to accommodate both activities of mining and nuclear operations at the same time and at the same location. From the technical standpoint, ventilation and fire risk cannot be managed through a simple transposition from current nuclear industry practices. The reversibility demand also leads to concrete proposals with regard to repository management flexibility and waste package retrievability. These proposals contribute to the dialogue with stakeholders to prepare for the public debate and a future law which will determine the reversibility conditions. New design developments are expected to be introduced in the application from the current studies conducted until 2014. The possibility of optimization beyond 2015 will be kept open taking into account the one hundred years operating time as well as the capability to integrate feedback gained from the first construction and operation works. The industrial committed work aims to reach the application stage by 2015. The license application procedure was defined by the 2006 Act. Subject to authorization, the construction might begin in 2017. (authors)

  1. Biogeochemical Changes at Early Stage After the Closure of Radioactive Waste Geological Repository in South Korea

    SciTech Connect (OSTI)

    Choung, Sungwook; Um, Wooyong; Choi, Seho; Francis, Arokiasamy J.; Kim, Sungpyo; Park, Jin beak; Kim, Suk-Hoon

    2014-09-01

    Permanent disposal of low- and intermediate-level radioactive wastes in the subterranean environment has been the preferred method of many countries, including Korea. A safety issue after the closure of a geological repository is that biodegradation of organic materials due to microbial activities generates gases that lead to overpressure of the waste containers in the repository and its disintegration with the release of radionuclides. As part of an ongoing large-scale in situ experiment using organic wastes and groundwater to simulate geological radioactive waste repository conditions, we investigated the geochemical alteration and microbial activities at an early stage (~63 days) intended to be representative of the initial period after repository closure. The increased numbers of both aerobes and facultative anaerobes in waste effluents indicate that oxygen content could be the most significant parameter to control biogeochemical conditions at very early periods of reaction (<35 days). Accordingly, the values of dissolved oxygen and redox potential were decreased. The activation of anaerobes after 35 days was supported by the increased concentration to ~50 mg L-1 of ethanol. These results suggest that the biogeochemical conditions were rapidly altered to more reducing and anaerobic conditions within the initial 2 months after repository closure. Although no gases were detected during the study, activated anaerobic microbes will play more important role in gas generation over the long term.

  2. U

    U.S. Energy Information Administration (EIA) Indexed Site

    ... The government may bring a civil action to prohibit reporting violations, which may result ... Exploration - all expenditures for assessment work on geological research; geochemical and ...

  3. CREATING A GEOLOGIC PLAY BOOK FOR TRENTON-BLACK RIVER APPALACHIAN BASIN EXPLORATION

    SciTech Connect (OSTI)

    Douglas G. Patchen; Katharine Lee Avary; John M. Bocan; Michael Hohn; John B. Hickman; Paul D. Lake; James A. Drahovzal; Christopher D. Laughrey; Jaime Kostelnik; Taury Smith; Ron Riley; Mark Baranoski

    2005-04-01

    The Trenton-Black River Appalachian Basin Research Consortium has made significant progress toward their goal of producing a geologic play book for the Trenton-Black River gas play. The final product will include a resource assessment model of Trenton-Black River reservoirs; possible fairways within which to concentrate further studies and seismic programs; and a model for the origin of Trenton-Black River hydrothermal dolomite reservoirs. All seismic data available to the consortium have been examined. Synthetic seismograms constructed for specific wells have enabled researchers to correlate the tops of 15 stratigraphic units determined from well logs to seismic profiles in New York, Pennsylvania, Ohio, West Virginia and Kentucky. In addition, three surfaces for the area have been depth converted, gridded and mapped. A 16-layer velocity model has been developed to help constrain time-to-depth conversions. Considerable progress was made in fault trend delineation and seismic-stratigraphic correlation within the project area. Isopach maps and a network of gamma-ray cross sections supplemented with core descriptions allowed researchers to more clearly define the architecture of the basin during Middle and Late Ordovician time, the control of basin architecture on carbonate and shale deposition and eventually, the location of reservoirs in Trenton Limestone and Black River Group carbonates. The basin architecture itself may be structurally controlled, and this fault-related structural control along platform margins influenced the formation of hydrothermal dolomite reservoirs in original limestone facies deposited in high energy environments. This resulted in productive trends along the northwest margin of the Trenton platform in Ohio. The continuation of this platform margin into New York should provide further areas with good exploration potential. The focus of the petrographic study shifted from cataloging a broad spectrum of carbonate rocks that occur in the Trenton-Black River interval to delineation of regional limestone diagenesis in the basin. A consistent basin-wide pattern of marine and burial diagenesis that resulted in relatively low porosity and permeability in the subtidal facies of these rocks has been documented across the study area. Six diagenetic stages have been recognized: four marine diagenesis stages and two burial diagenesis stages. This dominance of extensive marine and burial diagenesis yielded rocks with low reservoir potential, with the exception of fractured limestone and dolostone reservoirs. Commercial amounts of porosity, permeability and petroleum accumulation appear to be restricted to areas where secondary porosity developed in association with hydrothermal fluid flow along faults and fractures related to basement tectonics. A broad range of geochemical and fluid inclusion analyses have aided in a better understanding of the origin of the dolomites in the Trenton and Black River Groups over the study area. The results of these analyses support a hydrothermal origin for all of the various dolomite types found to date. The fluid inclusion data suggest that all of the dolomite types analyzed formed from hot saline brines. The dolomite is enriched in iron and manganese, which supports a subsurface origin for the dolomitizing brine. Strontium isotope data suggest that the fluids passed through basement rocks or immature siliciclastic rocks prior to forming the dolomites. All of these data suggest a hot, subsurface origin for the dolomites. The project database continued to be redesigned, developed and deployed. Production data are being reformatted for standard relational database management system requirements. Use of the project intranet by industry partners essentially doubled during the reporting period.

  4. Merging high resolution geophysical and geochemical surveys to reduce exploration risk at Glass Buttes, Oregon

    Broader source: Energy.gov [DOE]

    DOE Geothermal Technologies Peer Review - 2010. The primary objective of this project is to combine a suite of high resolution geophysical and geochemical techniques to reduce exploration risk by characterizing hydrothermal alteration, fault geometries and relationships.

  5. 31 TAC, part 1, chapter 9, rule 9.11 Geophysical and Geochemical...

    Open Energy Info (EERE)

    9, rule 9.11 Geophysical and Geochemical Exploration Permits Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: 31 TAC, part...

  6. A geochemical model of the Kilauea east rift zone | Open Energy...

    Open Energy Info (EERE)

    rift zone Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A geochemical model of the Kilauea east rift zone Abstract NA Author Donald Thomas...

  7. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1 Bacon, Diana H. carbon...

  8. Center for Geologic Storage of CO2 (GSCO2) | U.S. DOE Office of Science

    Office of Science (SC) Website

    (SC) Center for Geologic Storage of CO2 (GSCO2) Energy Frontier Research Centers (EFRCs) EFRCs Home Centers EFRC External Websites Research Science Highlights News & Events Publications History Contact BES Home Centers Center for Geologic Storage of CO2 (GSCO2) Print Text Size: A A A FeedbackShare Page GSCO<sub>2</sub> Director Scott M. Frailey Lead Institution University of Illinois at Urbana-Champaign Year Established 2014 Mission To generate new conceptual, mathematical,

  9. Estimating the spatio-temporal distribution of geochemical parameters...

    Office of Scientific and Technical Information (OSTI)

    Resource Relation: Journal Name: Water Resources Research; Journal Volume: 48; Journal Issue: 5; Related Information: Journal Publication Date: 2012 Research Org: Ernest Orlando ...

  10. Brine flow in heated geologic salt.

    SciTech Connect (OSTI)

    Kuhlman, Kristopher L.; Malama, Bwalya

    2013-03-01

    This report is a summary of the physical processes, primary governing equations, solution approaches, and historic testing related to brine migration in geologic salt. Although most information presented in this report is not new, we synthesize a large amount of material scattered across dozens of laboratory reports, journal papers, conference proceedings, and textbooks. We present a mathematical description of the governing brine flow mechanisms in geologic salt. We outline the general coupled thermal, multi-phase hydrologic, and mechanical processes. We derive these processes' governing equations, which can be used to predict brine flow. These equations are valid under a wide variety of conditions applicable to radioactive waste disposal in rooms and boreholes excavated into geologic salt.

  11. Wellbore cement fracture evolution at the cementbasalt caprock interface during geologic carbon sequestration

    SciTech Connect (OSTI)

    Jung, Hun Bok; Kabilan, Senthil; Carson, James P.; Kuprat, Andrew P.; Um, Wooyong; Martin, Paul F.; Dahl, Michael E.; Kafentzis, Tyler A.; Varga, Tamas; Stephens, Sean A.; Arey, Bruce W.; Carroll, KC; Bonneville, Alain; Fernandez, Carlos A.

    2014-08-01

    Composite Portland cement-basalt caprock cores with fractures, as well as neat Portland cement columns, were prepared to understand the geochemical and geomechanical effects on the integrity of wellbores with defects during geologic carbon sequestration. The samples were reacted with CO2-saturated groundwater at 50 C and 10 MPa for 3 months under static conditions, while one cement-basalt core was subjected to mechanical stress at 2.7 MPa before the CO2 reaction. Micro-XRD and SEM-EDS data collected along the cement-basalt interface after 3-month reaction with CO2-saturated groundwater indicate that carbonation of cement matrix was extensive with the precipitation of calcite, aragonite, and vaterite, whereas the alteration of basalt caprock was minor. X-ray microtomography (XMT) provided three-dimensional (3-D) visualization of the opening and interconnection of cement fractures due to mechanical stress. Computational fluid dynamics (CFD) modeling further revealed that this stress led to the increase in fluid flow and hence permeability. After the CO2-reaction, XMT images displayed that calcium carbonate precipitation occurred extensively within the fractures in the cement matrix, but only partially along the fracture located at the cement-basalt interface. The 3-D visualization and CFD modeling also showed that the precipitation of calcium carbonate within the cement fractures after the CO2-reaction resulted in the disconnection of cement fractures and permeability decrease. The permeability calculated based on CFD modeling was in agreement with the experimentally determined permeability. This study demonstrates that XMT imaging coupled with CFD modeling represent a powerful tool to visualize and quantify fracture evolution and permeability change in geologic materials and to predict their behavior during geologic carbon sequestration or hydraulic fracturing for shale gas production and enhanced geothermal systems.

  12. Quantification of Hydrological, Geochemical, and Mineralogical Processes Governing the Fate and Transport of Uranium over Multiple Scales in Hanford Sediments

    SciTech Connect (OSTI)

    Mayes, Melanie A.; Perfect, Edmund; van den Berg, Elmer; Parker, Jack C.; Jardine, Philip M.; Tang, Guoping; Fendorf, Scott

    2006-11-15

    A long-term measure of the DOE Environmental Remediation Sciences Division is to provide sufficient scientific understanding to allow a significant fraction of DOE sites to incorporate coupled biological, chemical, and physical processes into decision making for environmental remediation and long-term stewardship by 2015. Our research targets two related, major obstacles to understanding and predicting contaminant transport at DOE sites: the heterogeneity of subsurface geologic media, and the scale dependence of experimental and modeled results.

  13. Method of fracturing a geological formation

    DOE Patents [OSTI]

    Johnson, James O.

    1990-01-01

    An improved method of fracturing a geological formation surrounding a well bore is disclosed. A relatively small explosive charge is emplaced in a well bore and the bore is subsequently hydraulically pressurized to a pressure less than the formation breakdown pressure and preferably greater than the fracture propagation pressure of the formation. The charge is denoted while the bore is so pressurized, resulting in the formation of multiple fractures in the surrounding formation with little or no accompanying formation damage. Subsequent hydraulic pressurization can be used to propagate and extend the fractures in a conventional manner. The method is useful for stimulating production of oil, gas and possibly water from suitable geologic formations.

  14. Principles of isotope geology. Second edition

    SciTech Connect (OSTI)

    Faure, G.

    1986-01-01

    This is a text in isotope geology/geoscience that integrates material taught in various courses into a unified picture of the earth sciences. It presents an exposition of the principles used in the interpretation of isotopic data and shows how such interpretations apply to the solution of geological problems. References up to 1985 are included with chapters in this edition. New chapters on Sm-Nd, Lu-Hf Re-Os, and K-Ca decay schemes and cosmogenic radionuclides have been added. Data summaries and references have been expanded.

  15. In This Issue Advanced Research Projects Agency Electricity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Researchers can arrange samples in different ways around the source depending on the... ... PNNL-developed software in the evaluation of permits for geological sequestration. ...

  16. Training and Research on Probabilistic Hydro-Thermo-Mechanical...

    Office of Scientific and Technical Information (OSTI)

    Mines conducted research and training in the development and validation of an advanced COsub 2 GS (Geological Sequestration) probabilistic simulation and risk assessment model. ...

  17. Basin-Scale Leakage Risks from Geologic Carbon Sequestration: Impact on Carbon Capture and Storage Energy Market Competitiveness

    SciTech Connect (OSTI)

    Peters, Catherine; Fitts, Jeffrey; Wilson, Elizabeth; Pollak, Melisa; Bielicki, Jeffrey; Bhatt, Vatsal

    2013-03-13

    This three-year project, performed by Princeton University in partnership with the University of Minnesota and Brookhaven National Laboratory, examined geologic carbon sequestration in regard to CO{sub 2} leakage and potential subsurface liabilities. The research resulted in basin-scale analyses of CO{sub 2} and brine leakage in light of uncertainties in the characteristics of leakage processes, and generated frameworks to monetize the risks of leakage interference with competing subsurface resources. The geographic focus was the Michigan sedimentary basin, for which a 3D topographical model was constructed to represent the hydrostratigraphy. Specifically for Ottawa County, a statistical analysis of the hydraulic properties of underlying sedimentary formations was conducted. For plausible scenarios of injection into the Mt. Simon sandstone, leakage rates were estimated and fluxes into shallow drinking-water aquifers were found to be less than natural analogs of CO{sub 2} fluxes. We developed the Leakage Impact Valuation (LIV) model in which we identified stakeholders and estimated costs associated with leakage events. It was found that costs could be incurred even in the absence of legal action or other subsurface interference because there are substantial costs of finding and fixing the leak and from injection interruption. We developed a model framework called RISCS, which can be used to predict monetized risk of interference with subsurface resources by combining basin-scale leakage predictions with the LIV method. The project has also developed a cost calculator called the Economic and Policy Drivers Module (EPDM), which comprehensively calculates the costs of carbon sequestration and leakage, and can be used to examine major drivers for subsurface leakage liabilities in relation to specific injection scenarios and leakage events. Finally, we examined the competiveness of CCS in the energy market. This analysis, though qualitative, shows that financial incentives, such as a carbon tax, are needed for coal combustion with CCS to gain market share. In another part of the project we studied the role of geochemical reactions in affecting the probability of CO{sub 2} leakage. A basin-scale simulation tool was modified to account for changes in leakage rates due to permeability alterations, based on simplified mathematical rules for the important geochemical reactions between acidified brines and caprock minerals. In studies of reactive flows in fractured caprocks, we examined the potential for permeability increases, and the extent to which existing reactive transport models would or would not be able to predict it. Using caprock specimens from the Eau Claire and Amherstburg, we found that substantial increases in permeability are possible for caprocks that have significant carbonate content, but minimal alteration is expected otherwise. We also found that while the permeability increase may be substantial, it is much less than what would be predicted from hydrodynamic models based on mechanical aperture alone because the roughness that is generated tends to inhibit flow.

  18. Natural bacterial communities serve as quantitative geochemical biosensors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Mark B.; Rocha, Andrea M.; Smillie, Chris S.; Olesen, Scott W.; Paradis, Charles; Wu, Liyou; Campbell, James H.; Fortney, Julian L.; Mehlhorn, Tonia L.; Lowe, Kenneth A.; et al

    2015-05-12

    Biological sensors can be engineered to measure a wide range of environmental conditions. Here we show that statistical analysis of DNA from natural microbial communities can be used to accurately identify environmental contaminants, including uranium and nitrate at a nuclear waste site. In addition to contamination, sequence data from the 16S rRNA gene alone can quantitatively predict a rich catalogue of 26 geochemical features collected from 93 wells with highly differing geochemistry characteristics. We extend this approach to identify sites contaminated with hydrocarbons from the Deepwater Horizon oil spill, finding that altered bacterial communities encode a memory of prior contamination,more » even after the contaminants themselves have been fully degraded. We show that the bacterial strains that are most useful for detecting oil and uranium are known to interact with these substrates, indicating that this statistical approach uncovers ecologically meaningful interactions consistent with previous experimental observations. Future efforts should focus on evaluating the geographical generalizability of these associations. Taken as a whole, these results indicate that ubiquitous, natural bacterial communities can be used as in situ environmental sensors that respond to and capture perturbations caused by human impacts. These in situ biosensors rely on environmental selection rather than directed engineering, and so this approach could be rapidly deployed and scaled as sequencing technology continues to become faster, simpler, and less expensive. Here we show that DNA from natural bacterial communities can be used as a quantitative biosensor to accurately distinguish unpolluted sites from those contaminated with uranium, nitrate, or oil. These results indicate that bacterial communities can be used as environmental sensors that respond to and capture perturbations caused by human impacts.« less

  19. Natural bacterial communities serve as quantitative geochemical biosensors

    SciTech Connect (OSTI)

    Smith, Mark B.; Rocha, Andrea M.; Smillie, Chris S.; Olesen, Scott W.; Paradis, Charles; Wu, Liyou; Campbell, James H.; Fortney, Julian L.; Mehlhorn, Tonia L.; Lowe, Kenneth A.; Earles, Jennifer E.; Phillips, Jana; Techtmann, Steve M.; Joyner, Dominique C.; Elias, Dwayne A.; Bailey, Kathryn L.; Hurt, Richard A.; Preheim, Sarah P.; Sanders, Matthew C.; Yang, Joy; Mueller, Marcella A.; Brooks, Scott; Watson, David B.; Zhang, Ping; He, Zhili; Dubinsky, Eric A.; Adams, Paul D.; Arkin, Adam P.; Fields, Matthew W.; Zhou, Jizhong; Alm, Eric J.; Hazen, Terry C.

    2015-05-12

    Biological sensors can be engineered to measure a wide range of environmental conditions. Here we show that statistical analysis of DNA from natural microbial communities can be used to accurately identify environmental contaminants, including uranium and nitrate at a nuclear waste site. In addition to contamination, sequence data from the 16S rRNA gene alone can quantitatively predict a rich catalogue of 26 geochemical features collected from 93 wells with highly differing geochemistry characteristics. We extend this approach to identify sites contaminated with hydrocarbons from the Deepwater Horizon oil spill, finding that altered bacterial communities encode a memory of prior contamination, even after the contaminants themselves have been fully degraded. We show that the bacterial strains that are most useful for detecting oil and uranium are known to interact with these substrates, indicating that this statistical approach uncovers ecologically meaningful interactions consistent with previous experimental observations. Future efforts should focus on evaluating the geographical generalizability of these associations. Taken as a whole, these results indicate that ubiquitous, natural bacterial communities can be used as in situ environmental sensors that respond to and capture perturbations caused by human impacts. These in situ biosensors rely on environmental selection rather than directed engineering, and so this approach could be rapidly deployed and scaled as sequencing technology continues to become faster, simpler, and less expensive. Here we show that DNA from natural bacterial communities can be used as a quantitative biosensor to accurately distinguish unpolluted sites from those contaminated with uranium, nitrate, or oil. These results indicate that bacterial communities can be used as environmental sensors that respond to and capture perturbations caused by human impacts.

  20. Geochemical characteristics of bitumens and seeps from Tanzania

    SciTech Connect (OSTI)

    Mpanju, F. ); Philp, P. )

    1991-03-01

    A number of bitumen extracts from prospective source rocks and oil seeps of potential oil-producing areas in Tanzania have been characterized by a variety of geochemical techniques. The data obtained from this study have provided additional insight into the source rock potential of these areas. However, in this paper it is proposed to discuss in detail the results from two of the more unusual samples in this region, namely Wingayongo and Pemba. The Wingayongo bitumens isolated from an exposed Neocomian-aged sandstone, possibly a paleoreservoir, are almost totally devoid of n-alkanes and steranes and dominated by hopane-type biomarkers with the so-called immature {beta}{beta}-stereochemistry at the C{sub 17} and C{sub 21} positions. There is no typical evidence of biodegradation having occurred leading to the proposal of an unusual source material or maturity history for this sample. The Pemba seep samples were also characterized by relatively high concentrations of hopanes with the immature stereochemistry at the C{sub 17} and C{sub 21} positions and a virtual absence of n-alkanes and steranes. The aromatic fractions contained relatively high concentrations of hopanic acids, with the immature stereochemistry at C{sub 17} and C{sub 21} positions and a virtual absence of n-alkanes and steranes. The aromatic fractions contained relatively high concentrations of hopanic acids, with the immature stereochemistry at C{sub 17} and C{sub 21}. On the basis of these data, it is proposed that the seeps in the Pemba region are not true oil seeps. Rather they are formed as a result of extremely high levels of bacterial activity with the bacteria utilizing natural gas in the region as the substrate. The net result is a material referred to in other areas of the world as paraffin dirt whose occurrence results from extensive microbial activity in the region and not directly from seepage of products having a thermal origin.

  1. National Environmental Research Parks

    SciTech Connect (OSTI)

    Not Available

    1994-07-01

    The National Environmental Research Parks are outdoor laboratories that provide opportunities for environmental studies on protected lands that act as buffers around Department of Energy (DOE) facilities. The research parks are used to evaluate the environmental consequences of energy use and development as well as the strategies to mitigate these effects. They are also used to demonstrate possible environmental and land-use options. The seven parks are: Fermilab National Environmental Research Park; Hanford National Environmental Research Park; Idaho National Environmental Research Park; Los Alamos National Environmental Research Park; Nevada National Environmental Research Park; Oak Ridge National Environmental Research Park; and Savannah River National Environmental Research Park. This document gives an overview of the events that led to the creation of the research parks. Its main purpose is to summarize key points about each park, including ecological research, geological characteristics, facilities, and available databases.

  2. Investigating the Fundamental Scientific Issues Affecting the Long-term Geologic Storage of Carbon Dioxide

    SciTech Connect (OSTI)

    Spangler, Lee; Cunningham, Alfred; Barnhart, Elliot; Lageson, David; Nall, Anita; Dobeck, Laura; Repasky, Kevin; Shaw, Joseph; Nugent, Paul; Johnson, Jennifer; Hogan, Justin; Codd, Sarah; Bray, Joshua; Prather, Cody; McGrail, B.; Oldenburg, Curtis; Wagoner, Jeff; Pawar, Rajesh

    2014-12-19

    The Zero Emissions Research and Technology (ZERT) collaborative was formed to address basic science and engineering knowledge gaps relevant to geologic carbon sequestration. The original funding round of ZERT (ZERT I) identified and addressed many of these gaps. ZERT II has focused on specific science and technology areas identified in ZERT I that showed strong promise and needed greater effort to fully develop.

  3. Hiereachical Bayesian Model for Combining Geochemical and Geophysical Data for Environmental Applications Software

    Energy Science and Technology Software Center (OSTI)

    2013-05-01

    Development of a hierarchical Bayesian model to estimate the spatiotemporal distribution of aqueous geochemical parameters associated with in-situ bioremediation using surface spectral induced polarization (SIP) data and borehole geochemical measurements collected during a bioremediation experiment at a uranium-contaminated site near Rifle, Colorado. The SIP data are first inverted for Cole-Cole parameters including chargeability, time constant, resistivity at the DC frequency and dependence factor, at each pixel of two-dimensional grids using a previously developed stochastic method.more » Correlations between the inverted Cole-Cole parameters and the wellbore-based groundwater chemistry measurements indicative of key metabolic processes within the aquifer (e.g. ferrous iron, sulfate, uranium) were established and used as a basis for petrophysical model development. The developed Bayesian model consists of three levels of statistical sub-models: 1) data model, providing links between geochemical and geophysical attributes, 2) process model, describing the spatial and temporal variability of geochemical properties in the subsurface system, and 3) parameter model, describing prior distributions of various parameters and initial conditions. The unknown parameters are estimated using Markov chain Monte Carlo methods. By combining the temporally distributed geochemical data with the spatially distributed geophysical data, we obtain the spatio-temporal distribution of ferrous iron, sulfate and sulfide, and their associated uncertainity information. The obtained results can be used to assess the efficacy of the bioremediation treatment over space and time and to constrain reactive transport models.« less

  4. Evaluation of experimentally measured and model-calculated pH for rock-brine-CO2 systems under geologic CO2 sequestration conditions

    SciTech Connect (OSTI)

    Shao, Hongbo; Thompson, Christopher J.; Cantrell, Kirk J.

    2013-11-14

    pH is an essential parameter for understanding the geochemical reactions that occur in rock-brine-CO2 systems when CO2 is injected into deep geologic formations for long-term storage. Due to a lack of reliable experimental methods, most laboratory studies conducted under geological CO2 sequestration (GCS) conditions have relied on thermodynamic modeling to estimate pH. The accuracy of these model predictions is typically uncertain. In our previous work, we have developed a method for pH determination by in-situ spectrophotometry. In the present work, we expanded the applicable pH range for this method and measured the pH of several rock-brine-CO2 systems at GCS conditions for five rock samples collected from ongoing GCS demonstration projects. Experimental measurements were compared with pH values calculated using several geochemical modeling approaches. The effect of different thermodynamic databases on the accuracy of model prediction was evaluated. Results indicate that the accuracy of model calculations is rock-dependent. For rocks comprised of carbonate and sandstone, model results generally agreed well with experimentally measured pH; however, for basalt, significant differences were observed. These discrepancies may be due to the models’ failure to fully account for certain reaction occurring between the basalt minerals the CO2-saturated brine solutions.

  5. ORS 516 - Department of Geology and Mineral Industries | Open...

    Open Energy Info (EERE)

    6 - Department of Geology and Mineral Industries Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute: ORS 516 - Department of Geology...

  6. FMI Borehole Geology, Geomechanics and 3D Reservoir Modeling...

    Open Energy Info (EERE)

    FMI Borehole Geology, Geomechanics and 3D Reservoir Modeling Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: FMI Borehole Geology, Geomechanics and 3D...

  7. Subsurface geology of the Raft River geothermal area, Idaho ...

    Open Energy Info (EERE)

    geology of the Raft River geothermal area, Idaho Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings: Subsurface geology of the Raft River...

  8. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and...

    Office of Scientific and Technical Information (OSTI)

    Additional Journal Information: Journal Volume: 63; Journal Issue: C; Journal ID: ISSN 1876-6102 Publisher: Elsevier Research Org: Pacific Northwest National Laboratory (PNNL), ...

  9. Spatial And Temporal Geochemical Trends In The Hydrothermal System...

    Open Energy Info (EERE)

    tracking changes in river solute flux. Authors Shaul Hurwitz, Jacob B. Lowenstern and Henry Heasler Published Journal Journal of Volcanology and Geothermal Research, 2007 DOI Not...

  10. Self-Organized Pattern Formation in Sedimentary Geochemical Systems...

    Office of Scientific and Technical Information (OSTI)

    Research Org: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States) Sponsoring Org: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22) Country of ...

  11. CORE-BASED INTEGRATED SEDIMENTOLOGIC, STRATIGRAPHIC, AND GEOCHEMICAL ANALYSIS OF THE OIL SHALE BEARING GREEN RIVER FORMATION, UINTA BASIN, UTAH

    SciTech Connect (OSTI)

    Lauren P. Birgenheier; Michael D. Vanden Berg,

    2011-04-11

    An integrated detailed sedimentologic, stratigraphic, and geochemical study of Utah's Green River Formation has found that Lake Uinta evolved in three phases (1) a freshwater rising lake phase below the Mahogany zone, (2) an anoxic deep lake phase above the base of the Mahogany zone and (3) a hypersaline lake phase within the middle and upper R-8. This long term lake evolution was driven by tectonic basin development and the balance of sediment and water fill with the neighboring basins, as postulated by models developed from the Greater Green River Basin by Carroll and Bohacs (1999). Early Eocene abrupt global-warming events may have had significant control on deposition through the amount of sediment production and deposition rates, such that lean zones below the Mahogany zone record hyperthermal events and rich zones record periods between hyperthermals. This type of climatic control on short-term and long-term lake evolution and deposition has been previously overlooked. This geologic history contains key points relevant to oil shale development and engineering design including: (1) Stratigraphic changes in oil shale quality and composition are systematic and can be related to spatial and temporal changes in the depositional environment and basin dynamics. (2) The inorganic mineral matrix of oil shale units changes significantly from clay mineral/dolomite dominated to calcite above the base of the Mahogany zone. This variation may result in significant differences in pyrolysis products and geomechanical properties relevant to development and should be incorporated into engineering experiments. (3) This study includes a region in the Uinta Basin that would be highly prospective for application of in-situ production techniques. Stratigraphic targets for in-situ recovery techniques should extend above and below the Mahogany zone and include the upper R-6 and lower R-8.

  12. License for the Konrad Deep Geological Repository

    SciTech Connect (OSTI)

    Biurrun, E.; Hartje, B.

    2003-02-24

    Deep geological disposal of long-lived radioactive waste is currently considered a major challenge. Until present, only three deep geological disposal facilities have worldwide been operated: the Asse experimental repository (1967-1978) and the Morsleben repository (1971-1998) in Germany as well as the Waste Isolation Pilot Plant (WIPP) in the USA (1999 to present). Recently, the licensing procedure for the fourth such facility, the German Konrad repository, ended with a positive ''Planfeststellung'' (plan approval). With its plan approval decision, the licensing authority, the Ministry of the Environment of the state of Lower Saxony, approved the single license needed pursuant to German law to construct, operate, and later close down this facility.

  13. Groundwater geochemical modeling and simulation of a breached high-level radioactive waste repository in the northern Tularosa Basin, New Mexico

    SciTech Connect (OSTI)

    Chappell, R.W.

    1989-01-01

    The northern Tularosa Basin in south-central New Mexico was ranked favorably as a potential location for a high-level radioactive waste repository by a US Geological Survey pilot screening study of the Basin and Range Province. The favorable ranking was based chiefly on hydrogeologic and descriptive geochemical evidence. A goal of this study was to develop a methodology for predicting the performance of this or any other basin as a potential repository site using geochemical methods. The approach involves first characterizing the groundwater geochemistry, both chemically and isotopically, and reconstructing the probable evolutionary history of, and controls on the ground water chemistry through modeling. In the second phase of the approach, a hypothetically breached repository is introduced into the system, and the mobility of the parent radionuclide, uranium, in the groundwater is predicted. Possible retardation of uranium transport in the downgradient flow direction from the repository by adsorption and mineral precipitation is then considered. The Permian Yeso Formation, the primary aquifer in the northern Tularosa Basin, was selected for study, development and testing of the methodology outlined above. The Yeso Formation contains abundant gypsum and related evaporite minerals, which impart a distinctive chemical signature to the ground water. Ground water data and solubility calculations indicate a conceptual model of irreversible gypsum and dolomite dissolution with concomitant calcite precipitation. Recharge areas are apparent from temperature, {delta}{sup 18}O and {delta}{sup 2} H, and {sup 3}H trends in the aquifer. Corrected {sup 14}C ages range between modern and 31,200 years, and suggest an average ground water velocity of 0.83 m/yr.

  14. Geological problems in radioactive waste isolation

    SciTech Connect (OSTI)

    Witherspoon, P.A.

    1991-01-01

    The problem of isolating radioactive wastes from the biosphere presents specialists in the fields of earth sciences with some of the most complicated problems they have ever encountered. This is especially true for high level waste (HLW) which must be isolated in the underground and away from the biosphere for thousands of years. Essentially every country that is generating electricity in nuclear power plants is faced with the problem of isolating the radioactive wastes that are produced. The general consensus is that this can be accomplished by selecting an appropriate geologic setting and carefully designing the rock repository. Much new technology is being developed to solve the problems that have been raised and there is a continuing need to publish the results of new developments for the benefit of all concerned. The 28th International Geologic Congress that was held July 9--19, 1989 in Washington, DC provided an opportunity for earth scientists to gather for detailed discussions on these problems. Workshop W3B on the subject, Geological Problems in Radioactive Waste Isolation -- A World Wide Review'' was organized by Paul A Witherspoon and Ghislain de Marsily and convened July 15--16, 1989 Reports from 19 countries have been gathered for this publication. Individual papers have been cataloged separately.

  15. EQ3/6, a software package for geochemical modeling of aqueous systems:

    Office of Scientific and Technical Information (OSTI)

    Package overview and installation guide (Version 7.0) (Technical Report) | SciTech Connect EQ3/6, a software package for geochemical modeling of aqueous systems: Package overview and installation guide (Version 7.0) Citation Details In-Document Search Title: EQ3/6, a software package for geochemical modeling of aqueous systems: Package overview and installation guide (Version 7.0) × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of

  16. Hanford Site Guidelines for Preparation and Presentation of Geologic Information

    SciTech Connect (OSTI)

    Lanigan, David C.; Last, George V.; Bjornstad, Bruce N.; Thorne, Paul D.; Webber, William D.

    2010-04-30

    A complex geology lies beneath the Hanford Site of southeastern Washington State. Within this geology is a challenging large-scale environmental cleanup project. Geologic and contaminant transport information generated by several U.S. Department of Energy contractors must be documented in geologic graphics clearly, consistently, and accurately. These graphics must then be disseminated in formats readily acceptable by general graphics and document producing software applications. The guidelines presented in this document are intended to facilitate consistent, defensible, geologic graphics and digital data/graphics sharing among the various Hanford Site agencies and contractors.

  17. Carbon Storage Monitoring, Verification and Accounting Research |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Monitoring, Verification and Accounting Research Carbon Storage Monitoring, Verification and Accounting Research Reliable and cost-effective monitoring, verification and accounting (MVA) techniques are an important part of making geologic sequestration a safe, effective, and acceptable method for greenhouse gas control. MVA of geologic storage sites is expected to serve several purposes, including addressing safety and environmental concerns; inventory verification;

  18. A Geochemical Model of the Kilauea East Rift Zone | Open Energy...

    Open Energy Info (EERE)

    to southwest-trending complex of dikes and fractures extending more than 100 kilometers from the summit caldera to the ocean floor. Geologic, petrologic, and geophysical...

  19. Geochemical Behaviour of S, Cl and Fe in Silicate Melts/Glasses...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    E. Paris, P. Glatzel, S. Eeckhout, M. Carroll, School of Science and Technology, Geology Division, University of Camerino, Via G. III da Varano, 62032 Camerino; e-mail:...

  20. Basic Research Needs for Geosciences: Facilitating 21st Century Energy Systems

    SciTech Connect (OSTI)

    DePaolo, D. J.; Orr, F. M.; Benson, S. M.; Celia, M.; Felmy, A.; Nagy, K. L.; Fogg, G. E.; Snieder, R.; Davis, J.; Pruess, K.; Friedmann, J.; Peters, M.; Woodward, N. B.; Dobson, P.; Talamini, K.; Saarni, M.

    2007-06-01

    To identify research areas in geosciences, such as behavior of multiphase fluid-solid systems on a variety of scales, chemical migration processes in geologic media, characterization of geologic systems, and modeling and simulation of geologic systems, needed for improved energy systems.

  1. Environmental resources of selected areas of Hawaii: Geological hazards

    SciTech Connect (OSTI)

    Staub, W.P.; Reed, R.M.

    1995-03-01

    This report has been prepared to make available and archive the background scientific data and related information collected on geologic hazards during the preparation of the environmental impact statement (EIS) for Phases 3 and 4 of the Hawaii Geothermal Project (HGP) as defined by the state of Hawaii in its April 1989 proposal to Congress. The US Department of Energy (DOE) published a notice withdrawing its Notice of Intent to prepare the HGP-EIS. Since the state of Hawaii is no longer pursuing or planning to pursue the HGP, DOE considers the project to be terminated. This report presents a review of current information on geologic hazards in the Hawaiian Islands. Interrelationships among these hazards are discussed. Probabilities of occurrence of given geologic hazards are provided in various regions where sufficient geologic or historical data are available. Most of the information contained herein is compiled from recent US Geological Survey (USGS) publications and USGS open-file reports related to this project. This report describes the natural geologic hazards present in the area and does not represent an assessment of environmental impacts. Geologic hazards originate both onshore and offshore. Onshore geologic hazards such as volcanic eruptions, earthquakes, surface rupture, landslides, uplift and subsidence occur mainly on the southern third of the island of Hawaii (hereinafter referred to as Hawaii). Offshore geologic hazards are more widely distributed throughout the Hawaiian Islands. Examples of offshore geologic hazards are submarine landslides, turbidity currents, and seismic sea waves (tsunamis).

  2. Precise rare earth analysis of geological materials

    SciTech Connect (OSTI)

    Laul, J.C.; Wogman, N.A.

    1982-01-01

    Rare earth element (REE) concentrations are very informative in revealing chemical fractionation processs in geological systems. The REE's (La-Lu) behavior is characteristic of various primary and secondary minerals which comprise a rock. The REE's contents and their patterns provide a strong fingerprint in distinguishing among various rock types and in understanding the partial melting and/or fractional crystallization of the source region. The REE contents in geological materials are usually at trace levels. To measure all the REE at such levels, radiochemical neutron activation analysis (RNAA) has been used with a REE group separation scheme. To maximize detection sensitivites for individual REE, selective ..gamma..-ray/x-ray measurements have been made using normal Ge(Li) and low-energy photon detectors (LEPD), and Ge(Li)-NaI(Tl) coincidence-noncoincidence spectrometer systems. Using these detection methods an individual REE can be measured at or below the ppB levels; chemical yields of the REE are determined by reactivation.

  3. Research Techniques

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Techniques Research Techniques Print Coming Soon

  4. Building Connections with State Researchers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Connections with State Researchers Building Connections with State Researchers March 11, 2013 - 11:22am Addthis Assistant Secretary Chris Smith meets with UT undergraduate students studying geological research. | Photo by David M. Stephens, The University of Texas at Austin. Assistant Secretary Chris Smith meets with UT undergraduate students studying geological research. | Photo by David M. Stephens, The University of Texas at Austin. Gayland Barksdale Technical Writer, Office of Fossil Energy

  5. Geologic investigation :an update of subsurface geology on Kirtland Air Force Base, New Mexico.

    SciTech Connect (OSTI)

    Van Hart, Dirk

    2003-06-01

    The objective of this investigation was to generate a revised geologic model of Kirtland Air Force Base (KAFB) incorporating the geological and geophysical data produced since the Site-Wide Hydrogeologic Characterization Project (SWHC) of 1994 and 1995. Although this report has certain stand-alone characteristics, it is intended to complement the previous work and to serve as a status report as of late 2002. In the eastern portion of KAFB (Lurance Canyon and the Hubbell bench), of primary interest is the elevation to which bedrock is buried under a thin cap of alluvium. Elevation maps of the bedrock top reveal the paleodrainage that allows for the interpretation of the area's erosional history. The western portion of KAFB consists of the eastern part of the Albuquerque basin where bedrock is deeply buried under Santa Fe Group alluvium. In this area, the configuration of the down-to-the-west, basin-bounding Sandia and West Sandia faults is of primary interest. New geological and geophysical data and the reinterpretation of old data help to redefine the location and magnitude of these elements. Additional interests in this area are the internal stratigraphy and structure of the Santa Fe Group. Recent data collected from new monitoring wells in the area have led to a geologic characterization of the perched Tijeras Arroyo Groundwater system and have refined the known limits of the Ancestral Rio Grande fluvial sediments within the Santa Fe Group. Both the reinterpretation of the existing data and a review of the regional geology have shown that a segment of the boundary between the eastern and western portions of KAFB is a complicated early Tertiary (Laramide) wrench-fault system, the Tijeras/Explosive Ordnance Disposal Area/Hubbell Spring system. A portion of this fault zone is occupied by a coeval ''pull-apart'' basin filled with early Tertiary conglomerates, whose exposures form the ''Travertine Hills''.

  6. Summaries of physical research in the geosciences

    SciTech Connect (OSTI)

    Not Available

    1986-09-01

    The summaries in this document describe the scope of the individual programs and detail the research performed during 1984-1985. The Geosciences Research Program includes research in geology, petrology, geophysics, geochemistry, hydrology, solar-terrestrial relationships, aeronomy, seismology, and natural resource analysis, including their various subdivisions and interdisciplinary areas.

  7. Training and Research on Probabilistic Hydro-Thermo-Mechanical Modeling of

    Office of Scientific and Technical Information (OSTI)

    Carbon Dioxide Geological Sequestration in Fractured Porous Rocks (Technical Report) | SciTech Connect Training and Research on Probabilistic Hydro-Thermo-Mechanical Modeling of Carbon Dioxide Geological Sequestration in Fractured Porous Rocks Citation Details In-Document Search Title: Training and Research on Probabilistic Hydro-Thermo-Mechanical Modeling of Carbon Dioxide Geological Sequestration in Fractured Porous Rocks Colorado School of Mines conducted research and training in the

  8. Environmental Resources of Selected Areas of Hawaii: Geological Hazards (DRAFT)

    SciTech Connect (OSTI)

    Staub, W.P.

    1994-06-01

    This report has been prepared to make available and archive the background scientific data and related information collected on geologic hazards during the preparation of the environmental impact statement (EIS) for Phases 3 and 4 of the Hawaii Geothermal Project (HGP) as defined by the state of Hawaii in its April 1989 proposal to Congress. The U.S. Department of Energy (DOE) published a notice in the Federal Register on May 17, 1994 (Fed Regis. 5925638) withdrawing its Notice of Intent (Fed Regis. 575433) of February 14, 1992, to prepare the HGP-EIS. Since the state of Hawaii is no longer pursuing or planning to pursue the HGP, DOE considers the project to be terminated This report presents a review of current information on geologic hazards in the Hawaiian Islands. Interrelationships among these hazards are discussed. Probabilities of occurrence of given geologic hazards are provided in various regions where sufficient geologic or historical data are available. Most of the information contained herein is compiled from recent U.S. Geological Survey (USGS) publications and open-file reports. This report describes the natural geologic hazards present in the area and does not represent an assessment of environmental impacts. Geologic hazards originate both onshore and offshore. Onshore geologic hazards such as volcanic eruptions, earthquakes, surface rupture, landslides, uplift, and subsidence occur mainly on the southern third of the island of Hawaii (hereinafter referred to as Hawaii). Offshore geologic hazards are more widely distributed throughout the Hawaiian Islands. Examples of offshore geologic hazards are submarine landslides, turbidity currents, and seismic sea waves (tsunamis). First, overviews of volcanic and earthquake activity, and details of offshore geologic hazards is provided for the Hawaiian Islands. Then, a more detailed discussion of onshore geologic hazards is presented with special emphasis on the southern third of Hawaii and the east rift zone of Kilauea.

  9. Geologic Map and GIS Data for the Tuscarora Geothermal Area

    SciTech Connect (OSTI)

    Faulds, James E.

    2013-12-31

    Tuscarora—ESRI Geodatabase (ArcGeology v1.3): - Contains all the geologic map data, including faults, contacts, folds, unit polygons, and attitudes of strata and faults. - List of stratigraphic units and stratigraphic correlation diagram. - Detailed unit descriptions of stratigraphic units. - Five cross‐sections. - Locations of production, injection, and monitor wells. - 3D model constructed with EarthVision using geologic map data, cross‐sections, drill‐hole data, and geophysics (model not in the ESRI geodatabase).

  10. Geological and Anthropogenic Factors Influencing Mercury Speciation in Mine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Wastes Geological and Anthropogenic Factors Influencing Mercury Speciation in Mine Wastes Christopher S. Kim,1 James J. Rytuba,2 Gordon E. Brown, Jr.3 1Department of Physical Sciences, Chapman University, Orange, CA 92866 2U.S. Geological Survey, Menlo Park, CA 94025 3Department of Geological and Environmental Sciences, Stanford University, Stanford, CA 94305 Introduction Figure 1. Dr. Christopher Kim collects a mine waste sample from the Oat Hill mercury mine in Northern California. The

  11. Effect of curing conditions on the geotechnical and geochemical properties of CFBC ashes

    SciTech Connect (OSTI)

    Bland, A.E.

    1999-07-01

    Western Research Institute, in cooperation with the US Department of Energy Federal Energy Technology Center, initiated a multi-year program to examine the relationship between CFBC ash chemistry and geotechnical properties as they relate to ash disposal and utilization. Four CFBC facilities supplied ash from their units for the study representing high-sulfur (4%) and medium-sulfur (1.8%) bituminous coal. Sub-bituminous coal (0.9% sulfur) and petroleum coke (5--6% sulfur) fired ashes were also included in the study. The ashes were composed principally of large quantities of anhydrite (CaSO{sub 4}) and lime (CaO) and minor amounts of calcite (CaCO{sub 3}). The ash curing study addressed the impact of curing conditions (sealed and saturated curing and 23 C and 5 C curing temperature) on the geochemical and geotechnical properties of the ash. The strength development and expansion varied with the type and characteristics of the ashes. The expansion appeared to be inversely related to strength development. As the strength decreased under saturated curing, the expansion increased significantly. The application of 5 C saturated curing resulted in further strength loss and increased expansion. The hydration reaction products appeared to be principally the hydration of lime (CaO) to portlandite (Ca[OH]{sub 2}), the hydration of anhydrite (CaSO{sub 4}) to gypsum (CaSO{sub 4} {center{underscore}dot} 2H{sub 2}O), and the precipitation of ettringite (Ca{sub 6}Al{sub 2}[SO{sub 4}]{sub 3}[OH]{sub 12} {center{underscore}dot} 26H{sub 2}O) from the soluble calcium, sulfates and alumina. No thaumasite was noted in the specimens. The ashes appeared to follow one of several hydration reaction trends: (1) ettringite-only development, (2) ettringite and/or gypsum early followed by later gypsum formation, or (3) gypsum-only formation. Testing confirmed that the hydration reaction chemistry was related to geotechnical properties of the ashes. Strength development and expansion appeared to be related to ettringite and/or gypsum formation. The expansion increased with saturated curing and appeared to be predominantly gypsum based. A pore filling model was found to be consistent with the observed relationships between hydration phases (ettringite and gypsum) and strength development and expansion, as well as SEM observations and void reduction observations.

  12. Geologic Study of the Coso Formation | Open Energy Information

    Open Energy Info (EERE)

    Coso geothermal field. These studies have provided a wealth of knowledge concerning the geology of the area, including general structural characteristics and kinematic history....

  13. Co2 geological sequestration (Journal Article) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Co2 geological sequestration Citation Details In-Document Search Title: Co2 ... Publication Date: 2004-11-18 OSTI Identifier: 881725 Report Number(s): ...

  14. Geology and Mineral Deposits of Churchill County, Nevada | Open...

    Open Energy Info (EERE)

    Mineral Deposits of Churchill County, Nevada Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geology and Mineral Deposits of Churchill County, Nevada...

  15. Geological History of Lake Lahontan, a Quaternary Lake of Northwestern...

    Open Energy Info (EERE)

    a Quaternary Lake of Northwestern Nevada Abstract Abstract unavailable. Author Israel C. Russell Organization U.S. Geological Survey Published U.S. Government Printing...

  16. Imaging Wellbore Cement Degradation by Carbon Dioxide under Geologic...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Imaging Wellbore Cement Degradation by Carbon Dioxide under Geologic Sequestration Conditions Using X-ray Computed Microtomography Citation Details In-Document ...

  17. Pre-Investigation Geological Appraisal Of Geothermal Fields ...

    Open Energy Info (EERE)

    by few or faults. The probable conditions are therefore inferred from study of geological environment, structure and stratigraphy, and the type and distribution of thermal springs...

  18. United States Geological Survey, LSC | Open Energy Information

    Open Energy Info (EERE)

    Testing Facilities Name United States Geological Survey, LSC Address Leetown Science Center, Conte Anadromous Fish Laboratory, 1 Migratory Way Place Turners Falls,...

  19. Geologic Map and GIS Data for the Tuscarora Geothermal Area

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Faulds, James E.

    2013-12-31

    - 3D model constructed with EarthVision using geologic map data, cross?sections, drill?hole data, and geophysics (model not in the ESRI geodatabase).

  20. Geology and alteration of the Coso Geothermal Area, Inyo County...

    Open Energy Info (EERE)

    Deep thermal fluid flow at Coso will be controlled entirely by structural permeability developed in otherwise tight and impermeable host rocks. Neither geologic mapping...

  1. Chena Hot Springs GRED III Project: Final Report Geology, Petrology...

    Open Energy Info (EERE)

    Springs GRED III Project: Final Report Geology, Petrology, Geochemistry, Hydrothermal Alteration, and Fluid Analyses Jump to: navigation, search OpenEI Reference LibraryAdd to...

  2. Geology and alteration of the Raft River geothermal system, Idaho...

    Open Energy Info (EERE)

    Raft River geothermal system, Idaho Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings: Geology and alteration of the Raft River geothermal...

  3. International Symposium on Site Characterization for CO2Geological...

    Office of Scientific and Technical Information (OSTI)

    International Symposium on Site Characterization for CO2Geological Storage Citation ... Visit OSTI to utilize additional information resources in energy science and technology. A ...

  4. Geologic map of the Sulphur Springs Area, Valles Caldera Geothermal...

    Open Energy Info (EERE)

    and geologic deposits are indicated on the map. (MHR) Cartographers Fraser E. Goff and J. N. Gardner Published Los Alamos National Laboratory, NM, 1980 DOI Not Provided...

  5. Rock Physics of Geologic Carbon Sequestration/Storage Dvorkin...

    Office of Scientific and Technical Information (OSTI)

    Rock Physics of Geologic Carbon SequestrationStorage Dvorkin, Jack; Mavko, Gary 54 ENVIRONMENTAL SCIENCES; 58 GEOSCIENCES This report covers the results of developing the rock...

  6. Carbon Geological Sequestration Systems Bau, Domenico 54 ENVIRONMENTAL

    Office of Scientific and Technical Information (OSTI)

    Multi-Objective Optimization Approaches for the Design of Carbon Geological Sequestration Systems Bau, Domenico 54 ENVIRONMENTAL SCIENCES The main objective of this project is to...

  7. Paleomagnetism, Potassium-Argon Ages, and Geology of Rhyolites...

    Open Energy Info (EERE)

    and Dalrymple, 1966). Authors Richard R. Doell, G. Brent Dalrymple, Robert Leland Smith and Roy A. Bailey Published Journal Geological Society of America Memoirs, 1968 DOI...

  8. Geophysics, Geology and Geothermal Leasing Status of the Lightning...

    Open Energy Info (EERE)

    Leasing Status of the Lightning Dock KGRA, Animas Valley, New Mexico Author C. Smith Published New Mexico Geological Society Guidebook, 1978 DOI Not Provided Check for DOI...

  9. I I Hydrological/Geological Studies Radiochemical Analyses of...

    Office of Legacy Management (LM)

    ' HydrologicalGeological Studies Radiochemical Analyses of Water Samples from Selected Streams, Wells, Springs and Precipitation Collected Prior to Re-Entry . , Drilling, Project ...

  10. Liquid Metal Heat Exchanger for Geologic Deposits - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liquid Metal Heat Exchanger for Geologic Deposits Oak Ridge National Laboratory Contact ... The apparatus provides more efficient heat transfer than existing technologies for ...

  11. Final Supplemental Environmental Impact Statement for a Geologic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Final Supplemental Environmental Impact Statement for a Geologic Repository for the Disposal of Spent Nuclear Fuel and High-Level Radioactive Waste at Yucca Mountain, Nye County, ...

  12. United States Geological Survey, HIF | Open Energy Information

    Open Energy Info (EERE)

    HIF Jump to: navigation, search Hydro | Hydrodynamic Testing Facilities Name United States Geological Survey, HIF Address Building 2101 Stennis Space Center Place Mississippi Zip...

  13. New River Geothermal Research Program

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation: Project objectives: Demonstration of an innovative blend of modern tectonic research applied to the Imperial Valley with a proprietary compilation of existing thermal and drilling data. The developed geologic model will guide the targeting of two test wells and the identification of permeable zones capable of commercial geothermal power production.

  14. Geochemical and isotopic results for groundwater, drainage waters, snowmelt, permafrost, precipitation in Barrow, Alaska (USA) 2012-2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Wilson, Cathy; Newman, Brent; Heikoop, Jeff

    Data include a large suite of analytes (geochemical and isotopic) for samples collected in Barrow, Alaska (2012-2013). Sample types are indicated, and include soil pore waters, drainage waters, snowmelt, precipitation, and permafrost samples.

  15. Geochemical and isotopic results for groundwater, drainage waters, snowmelt, permafrost, precipitation in Barrow, Alaska (USA) 2012-2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Wilson, Cathy; Newman, Brent; Heikoop, Jeff

    2012-07-18

    Data include a large suite of analytes (geochemical and isotopic) for samples collected in Barrow, Alaska (2012-2013). Sample types are indicated, and include soil pore waters, drainage waters, snowmelt, precipitation, and permafrost samples.

  16. Kinetics of Uranium(VI) Desorption from Contaminated Sediments: Effect of Geochemical Conditions and Model Evaluation

    SciTech Connect (OSTI)

    Liu, Chongxuan; Shi, Zhenqing; Zachara, John M.

    2009-09-01

    Stirred-flow cell experiments were performed to investigate the kinetics of uranyl [U(VI)] desorption from a contaminated sediment collected from the Hanford 300 Area at the US Department of Energy (DOE) Hanford Site, Washington. Three influent solutions of variable pH, Ca and carbonate concentrations that affected U(VI) aqueous and surface speciation were used under dynamic flow conditions to evaluate the effect of geochemical conditions on the rate of U(VI) desorption. The measured rate of U(VI) desorption varied with solution chemical composition that evolved as a result of thermodynamic and kinetic interactions between the influent solutions and sediment. The solution chemical composition that led to a lower equilibrium U(VI) sorption to the solid phase yielded a faster desorption rate. The experimental results were used to evaluate a multi-rate, surface complexation model (SCM) that has been proposed to describe U(VI) desorption kinetics in the Hanford sediment that contained complex sorbed U(VI) species in mass transfer limited domains. The model was modified and supplemented by including multi-rate, ion exchange reactions to describe the geochemical interactions between the solutions and sediment. With the same set of model parameters, the modified model reasonably well described the evolution of major ions and the rates of U(VI) desorption under variable geochemical and flow conditions, implying that the multi-rate SCM is an effective way to describe U(VI) desorption kinetics in subsurface sediments.

  17. Behavior of REE in geological and biological systems

    SciTech Connect (OSTI)

    Laul, J.C.; Weimer, W.C.

    1981-05-01

    The REE abundances when normalized to primordial (chondritic) abundances behave as a smooth function of the REE ionic radii in both the geological and biological systems. The REE are hardly fractionated chemically through various stages of their transformation from soil-soil extract-plant-geological systems.

  18. A Catalog of Geologic Data for the Hanford Site

    SciTech Connect (OSTI)

    Horton, Duane G.; Last, George V.; Gilmore, Tyler J.; Bjornstad, Bruce N.; Mackley, Rob D.

    2005-08-01

    This revision of the geologic data catalog incorporates new boreholes drilled after September 2002 as well as other older wells, particularly from the 600 Area, omitted from the earlier catalogs. Additionally, borehole geophysical log data have been added to the catalog. This version of the geologic data catalog now contains 3,519 boreholes and is current with boreholes drilled as of November 2004.

  19. Geologic Map and GIS Data for the Wabuska Geothermal Area

    SciTech Connect (OSTI)

    Hinz, Nick

    2013-09-30

    Wabuska—ESRI geodatabase (ArcGeology v1.3): - Contains all the geologic map data, including faults, contacts, folds, veins, dikes, unit polygons, and attitudes of strata. - List of stratigraphic units and stratigraphic correlation diagram. - One cross‐section.

  20. Geologic Map and GIS Data for the Patua Geothermal Area

    SciTech Connect (OSTI)

    Faulds, James E.

    2011-10-31

    Patua—ESRI Geodatabase (ArcGeology v1.3): - Contains all the geologic map data, including faults, contacts, folds, veins, dikes, unit polygons, and attitudes of strata and faults. - List of stratigraphic units. - Locations of geothermal wells. - Locations of 40Ar/39Ar and tephra samples.

  1. Geochemical factors affecting radionuclide transport through near and far fields at a Low-Level Waste Disposal Site

    SciTech Connect (OSTI)

    Kaplan, D.I.; Seme, R.J.; Piepkho, M.G.

    1995-03-01

    The concentration of low-level waste (LLW) contaminants in groundwater is determined by the amount of contaminant present in the solid waste, rate of release from the waste and surrounding barriers, and a number of geochemical processes including adsorption, desorption, diffusion, precipitation, and dissolution. To accurately predict radionuclide transport through the subsurface, it is essential that the important geochemical processes affecting radionuclide transport be identified and, perhaps more importantly, accurately quantified and described in a mathematically defensible manner.

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    at a scale of 1:250,000. Hydrography data include flowing water, water bodies, and wetlands. The data source is the U.S. Geological Survey. Digital Elevation Model (DEM) data...

  3. Geology Data Package for the Single-Shell Tank Waste Management Areas at the Hanford Site

    SciTech Connect (OSTI)

    Reidel, Steve P.; Chamness, Mickie A.

    2007-01-01

    This data package discusses the geology of the single-shell tank (SST) farms and the geologic history of the area. The focus of this report is to provide the most recent geologic information available for the SST farms. This report builds upon previous reports on the tank farm geology and Integrated Disposal Facility geology with information available after those reports were published.

  4. Controlling Subsurface Fractures and Fluid Flow: A Basic Research Agenda |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Controlling Subsurface Fractures and Fluid Flow: A Basic Research Agenda Controlling Subsurface Fractures and Fluid Flow: A Basic Research Agenda PDF icon BES Report Controlling Subsurface Fractures and Fluid Flow.pdf More Documents & Publications AGU SubTER Town Hall Presentation 2015 SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical Signals in the Subsurface SubTER Crosscut White Paper

  5. Basic research needed for the development of geothermal energy

    SciTech Connect (OSTI)

    Aamodt, R.L.; Riecker, R.E.

    1980-10-01

    Basic research needed to facilitate development of geothermal energy is identified. An attempt has been made to make the report representative of the ideas of productive workers in the field. The present state of knowledge of geothermal energy is presented and then specific recommendations for further research, with status and priorities, are listed. Discussion is limited to a small number of applicable concepts, namely: origin of geothermal flux; transport of geothermal energy; geothermal reservoirs; rock-water interactions, and geophysical and geochemical exploration.

  6. Training and Research on Probabilistic Hydro-Thermo-Mechanical Modeling of

    Office of Scientific and Technical Information (OSTI)

    Carbon Dioxide Geological Sequestration in Fractured Porous Rocks (Technical Report) | SciTech Connect Training and Research on Probabilistic Hydro-Thermo-Mechanical Modeling of Carbon Dioxide Geological Sequestration in Fractured Porous Rocks Citation Details In-Document Search Title: Training and Research on Probabilistic Hydro-Thermo-Mechanical Modeling of Carbon Dioxide Geological Sequestration in Fractured Porous Rocks × You are accessing a document from the Department of Energy's

  7. Status report on the geology of the Oak Ridge Reservation

    SciTech Connect (OSTI)

    Hatcher, R.D. Jr.; Lemiszki, P.J.; Foreman, J.L.; Dreier, R.B.; Ketelle, R.H.; Lee, R.R.; Lee, Suk Young; Lietzke, D.A.; McMaster, W.M.

    1992-10-01

    This report provides an introduction to the present state of knowledge of the geology of the Oak Ridge Reservation (ORR) and a cursory introduction to the hydrogeology. An important element of this work is the construction of a modern detailed geologic map of the ORR (Plate 1), which remains in progress. An understanding of the geologic framework of the ORR is essential to many current and proposed activities related to land-use planning, waste management, environmental restoration, and waste remediation. Therefore, this report is also intended to convey the present state of knowledge of the geologic and geohydrologic framework of the ORR and vicinity and to present some of the available data that provide the basic framework for additional geologic mapping, subsurface geologic, and geohydrologic studies. In addition, some recently completed, detailed work on soils and other surficial materials is included because of the close relationships to bedrock geology and the need to recognize the weathered products of bedrock units. Weathering processes also have some influence on hydrologic systems and processes at depth.

  8. Global Sampling for Integrating Physics-Specific Subsystems and Quantifying Uncertainties of CO2 Geological Sequestration

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, Y.; Tong, C.; Trainor-Guitten, W. J.; Lu, C.; Mansoor, K.; Carroll, S. A.

    2012-12-20

    The risk of CO2 leakage from a deep storage reservoir into a shallow aquifer through a fault is assessed and studied using physics-specific computer models. The hypothetical CO2 geological sequestration system is composed of three subsystems: a deep storage reservoir, a fault in caprock, and a shallow aquifer, which are modeled respectively by considering sub-domain-specific physics. Supercritical CO2 is injected into the reservoir subsystem with uncertain permeabilities of reservoir, caprock, and aquifer, uncertain fault location, and injection rate (as a decision variable). The simulated pressure and CO2/brine saturation are connected to the fault-leakage model as a boundary condition. CO2 andmore » brine fluxes from the fault-leakage model at the fault outlet are then imposed in the aquifer model as a source term. Moreover, uncertainties are propagated from the deep reservoir model, to the fault-leakage model, and eventually to the geochemical model in the shallow aquifer, thus contributing to risk profiles. To quantify the uncertainties and assess leakage-relevant risk, we propose a global sampling-based method to allocate sub-dimensions of uncertain parameters to sub-models. The risk profiles are defined and related to CO2 plume development for pH value and total dissolved solids (TDS) below the EPA's Maximum Contaminant Levels (MCL) for drinking water quality. A global sensitivity analysis is conducted to select the most sensitive parameters to the risk profiles. The resulting uncertainty of pH- and TDS-defined aquifer volume, which is impacted by CO2 and brine leakage, mainly results from the uncertainty of fault permeability. Subsequently, high-resolution, reduced-order models of risk profiles are developed as functions of all the decision variables and uncertain parameters in all three subsystems.« less

  9. Geologic and tectonic characteristics of rockbursts

    SciTech Connect (OSTI)

    Adushkin, V.V.; Charlamov, V.A.; Kondratyev, S.V.; Rybnov, Y.S.; Shemyakin, V.M.; Sisov, I.A.; Syrnikov, N.M.; Turuntaev, S.B.; Vasilyeva, T.V.

    1995-06-01

    The modern mining enterprises have attained such scales of engineering activity that their direct influence to a rock massif and in series of cases to the region seismic regime doesn`t provoke any doubts. Excavation and removal of large volumes of rock mass, industrial explosions and other technological factors during long time can lead to the accumulation of man-made changes in rock massifs capable to cause catastrophic consequences. The stress state changes in considerable domains of massif create dangerous concentration of stresses at large geological heterogeneities - faults localized in the mining works zone. External influence can lead in that case to such phenomena as tectonic rockbursts and man-made earthquakes. The rockbursts problem in world mining practice exists for more than two hundred years. So that its actuality not only doesn`t decrease but steadily mounts up as due to the mining works depth increase, enlargement of the useful minerals excavations volumes as due to the possibility of safe use of the rock massif potential energy for facilitating the mastering of the bowels of the Earth and for making that more cheap. The purpose of present work is to study the engineering activity influence to processes occurring in the upper part of Earth crust and in particular in a rock massif. The rock massif is treated in those studies as a geophysical medium - such approach takes into account the presence of block structure of medium and the continuous exchange of energy between parts of that structure. The idea ``geophysical medium`` is applied in geophysics sufficiently wide and stresses the difference of actual Earth crust and rock massifs from the continuous media models discussed in mechanics.

  10. Federal Control of Geological Carbon Sequestration

    SciTech Connect (OSTI)

    Reitze, Arnold

    2011-04-11

    The United States has economically recoverable coal reserves of about 261 billion tons, which is in excess of a 250-­‐year supply based on 2009 consumption rates. However, in the near future the use of coal may be legally restricted because of concerns over the effects of its combustion on atmospheric carbon dioxide concentrations. In response, the U.S. Department of Energy is making significant efforts to help develop and implement a commercial scale program of geologic carbon sequestration that involves capturing and storing carbon dioxide emitted from coal-­‐burning electric power plants in deep underground formations. This article explores the technical and legal problems that must be resolved in order to have a viable carbon sequestration program. It covers the responsibilities of the United States Environmental Protection Agency and the Departments of Energy, Transportation and Interior. It discusses the use of the Safe Drinking Water Act, the Clean Air Act, the National Environmental Policy Act, the Endangered Species Act, and other applicable federal laws. Finally, it discusses the provisions related to carbon sequestration that have been included in the major bills dealing with climate change that Congress has been considering in 2009 and 2010. The article concludes that the many legal issues that exist can be resolved, but whether carbon sequestration becomes a commercial reality will depend on reducing its costs or by imposing legal requirements on fossil-­‐fired power plants that result in the costs of carbon emissions increasing to the point that carbon sequestration becomes a feasible option.

  11. Source: U.S. Energy Information Administration, based on DrillingInfo Inc., New York State Geological Survey, Ohio State Geological Survey, Pennsylvania Bureau of

    U.S. Energy Information Administration (EIA) Indexed Site

    Source: U.S. Energy Information Administration, based on DrillingInfo Inc., New York State Geological Survey, Ohio State Geological Survey, Pennsylvania Bureau of Topographic & Geologic Survey, West Virginia Geological & Economic Survey, and U.S. Geological Survey. Note: Map includes production wells from January 2003 through December 2014. Structure map of the Marcellus Formation Thickness map of the Marcellus Formation Source: U.S. Energy Information Administration, based on

  12. Radioactive Waste Management: Study of Spent Fuel Dissolution Rates in Geological Storage Using Dosimetry Modeling and Experimental Verification

    SciTech Connect (OSTI)

    Hansen, Brady; Miller, William

    2011-10-28

    This research will provide improved predictions into the mechanisms and effects of radiolysis on spent nuclear fuel dissolution in a geological respository through accurate dosimetry modeling of the dose to water, mechanistic chemistry modeling of the resulting radiolytic reactions and confirmatory experimental measurements. This work will combine effort by the Nuclear Science and Engineering Institute (NSEI) and the Missouri University Research Reactor (MURR) at the University of Missouri-Columbia, and the expertise and facilities at the Pacific Northwest National Laboratory (PNNL).

  13. Evaluation of Groundwater Movement in the Frenchman Flat CAU Using Geochemical and Isotopic Analysis

    SciTech Connect (OSTI)

    R. Hershey; J. Thomas; T. Rose; J. Paces; I. Farnham; C. Benedict, Jr.

    2005-03-01

    The principal pathway for radionuclide migration from underground tests in Frenchman Flat, on the Nevada Test Site, to the accessible environment is groundwater flow. Two potential pathways for radionuclide transport via groundwater have been identified from hydrologic data: (1) radionuclide transport downward from the alluvial and volcanic aquifers into the underlying carbonate aquifer; and (2) radionuclide transport laterally to the carbonate aquifer surrounding Frenchman Flat. This report presents an evaluation of geochemical and environmental isotopic data to test these potential pathways and to identify other groundwater flowpaths in, and out of, Frenchman Flat.

  14. Computer Modeling of Chemical and Geochemical Processes in High Ionic Strength Solutions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computer modeling of chemical and geochemical processes in high ionic strength solutions is a unique capability within Sandia's Defense Waste Managment Programs located in Carlsbad, New Mexico. We currently have use of EQ3/6 Version 8a, a version of EQ3/6 that is tailored specifically for high ionic strength systems in addition to a library of Pitzer parameters for elements found in WIPP brines. State of the art calculations for brines at WIPP are being performed using EQ3/6 Version 8a for the

  15. Geology of Southwestern New Mexico | Open Energy Information

    Open Energy Info (EERE)

    to library Conference Paper: Geology of Southwestern New Mexico Authors R.E. Clemons and G.H. Mack Conference 39th Field Conference; ConferencePlace"ConferencePlace"...

  16. Geological and geophysical studies of a geothermal area in the...

    Open Energy Info (EERE)

    geology; structure; surveys; tectonics; United States; volcanic rocks Authors Williams, P.L.; Mabey, D.R.; Pierce, K.L.; Zohdy, A.A.R.; Ackermann, H.; Hoover and D.B. Published U....

  17. DOE Manual Studies 11 Major CO2 Geologic Storage Formations

    Broader source: Energy.gov [DOE]

    A comprehensive study of 11 geologic formations suitable for permanent underground carbon dioxide (CO2) storage is contained in a new manual issued by the U.S. Department of Energy.

  18. High resolution reservoir geological modelling using outcrop information

    SciTech Connect (OSTI)

    Zhang Changmin; Lin Kexiang; Liu Huaibo

    1997-08-01

    This is China`s first case study of high resolution reservoir geological modelling using outcrop information. The key of the modelling process is to build a prototype model and using the model as a geological knowledge bank. Outcrop information used in geological modelling including seven aspects: (1) Determining the reservoir framework pattern by sedimentary depositional system and facies analysis; (2) Horizontal correlation based on the lower and higher stand duration of the paleo-lake level; (3) Determining the model`s direction based on the paleocurrent statistics; (4) Estimating the sandbody communication by photomosaic and profiles; (6) Estimating reservoir properties distribution within sandbody by lithofacies analysis; and (7) Building the reservoir model in sandbody scale by architectural element analysis and 3-D sampling. A high resolution reservoir geological model of Youshashan oil field has been built by using this method.

  19. Geologic Map of the Middle East Rift Geothermal Subzone, Kilauea...

    Open Energy Info (EERE)

    Kilauea Volcano, HawaiiInfo GraphicMapChart Authors Frank A. Trusdell and Richard B. Moore Published U.S. GEOLOGICAL SURVEY, 2006 DOI Not Provided Check for DOI availability:...

  20. Geology of the Florida Canyon gold deposit, Pershing County,...

    Open Energy Info (EERE)

    Pershing County, Nevada, in: Gold and Silver Deposits of Western Nevada Authors Hastings, J.S., Burkhart, T.H., and Richardson and R.E. Published Geological Society of Nevada 1993...

  1. Geologic interpretation of gravity and magnetic data in the Salida...

    Open Energy Info (EERE)

    interpretation of gravity and magnetic data in the Salida region, Colorado Authors J.E. Case and R.F. Sikora Published U.S. Geological Survey Open-File Report, 1984 Report...

  2. Geological aspects of the nuclear waste disposal problem

    SciTech Connect (OSTI)

    Laverov, N.P.; Omelianenko, B.L.; Velichkin, V.I.

    1994-06-01

    For the successful solution of the high-level waste (HLW) problem in Russia one must take into account such factors as the existence of the great volume of accumulated HLW, the large size and variety of geological conditions in the country, and the difficult economic conditions. The most efficient method of HLW disposal consists in the maximum use of protective capacities of the geological environment and in using inexpensive natural minerals for engineered barrier construction. In this paper, the principal trends of geological investigation directed toward the solution of HLW disposal are considered. One urgent practical aim is the selection of sites in deep wells in regions where the HLW is now held in temporary storage. The aim of long-term investigations into HLW disposal is to evaluate geological prerequisites for regional HLW repositories.

  3. Process for structural geologic analysis of topography and point data

    DOE Patents [OSTI]

    Eliason, Jay R.; Eliason, Valerie L. C.

    1987-01-01

    A quantitative method of geologic structural analysis of digital terrain data is described for implementation on a computer. Assuming selected valley segments are controlled by the underlying geologic structure, topographic lows in the terrain data, defining valley bottoms, are detected, filtered and accumulated into a series line segments defining contiguous valleys. The line segments are then vectorized to produce vector segments, defining valley segments, which may be indicative of the underlying geologic structure. Coplanar analysis is performed on vector segment pairs to determine which vectors produce planes which represent underlying geologic structure. Point data such as fracture phenomena which can be related to fracture planes in 3-dimensional space can be analyzed to define common plane orientation and locations. The vectors, points, and planes are displayed in various formats for interpretation.

  4. Title Geology of the Great Basin. Copyright Issue Entire Book

    National Nuclear Security Administration (NNSA)

    Fiero, B. 101084 Document Date 1186 Document Type Book ERC Index number 05.09.128 Box Number 1672-1 Recipients Unversity of Nevada Reno Press ADI " Geology of the Great...

  5. A Geological and Geophysical Study of Chena Hot Springs, Alaksa...

    Open Energy Info (EERE)

    Alaksa Jump to: navigation, search OpenEI Reference LibraryAdd to library M.Sc. Thesis: A Geological and Geophysical Study of Chena Hot Springs, AlaksaThesisDissertation...

  6. Geologic Mapping of the Valles Caldera National Preserve, New...

    Open Energy Info (EERE)

    and Bland) are now complete and two others will be finished by 2006 (Valle Toledo and Valle San Antonio). Eventually, the geology of the Valles caldera will be published as a...

  7. Geologic Map of the Jemez Mountains, New Mexico | Open Energy...

    Open Energy Info (EERE)

    MexicoInfo GraphicMapChart Abstract Abstract unavailable Cartographers Robert Leland Smith, Roy A. Bailey and Clarence Samuel Ross Published U.S. Geological Survey, 1970 DOI Not...

  8. Fluid Flow Model Development for Representative Geologic Media

    Broader source: Energy.gov [DOE]

    Clay and granitic geologic rock units are potential host media for future repositories for used nuclear fuel and high level waste. This report addresses the representation of flow in these two media within numerical process (discrete fracture network) models.

  9. Geology, Water Geochemistry And Geothermal Potential Of The Jemez...

    Open Energy Info (EERE)

    Geology, Water Geochemistry And Geothermal Potential Of The Jemez Springs Area, Canon De San Diego, New Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  10. Regional Geology: GIS Database for Alternative Host Rocks and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The objective of this work is to develop a spatial database that integrates both geologic data for alternative host-rock formations and information that has been historically used ...

  11. Blind Geothermal System Exploration in Active Volcanic Environments; Multi-phase Geophysical and Geochemical Surveys in Overt & Subtle Volcanic Systems, Hawaii & Maui

    Broader source: Energy.gov [DOE]

    DOE Geothermal Technologies Peer Review 2010 - Presentation. Project Objective: To use a combination of traditional geophysical and geochemical tools with exploration suites not typically used in geothermal exploration.

  12. Summaries of FY 1993 geosciences research

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    The Department of Energy supports research in the geosciences in order to provide a sound foundation of fundamental knowledge in those areas of the geosciences that are germane to the DOE`s many missions. The Geosciences Research Program is supported by the Office of Energy Research. The participants in this program include DOE laboratories, academic institutions, and other governmental agencies. These activities are formalized by a contract or grant between the DOE and the organization performing the work, providing funds for salaries, equipment, research materials, and overhead. The summaries in this document, prepared by the investigators, describe the scope of the individual programs. The Geosciences Research Program includes research in geophysics, geochemistry, resource evaluation, solar-terrestrial interactions, and their subdivisions including earth dynamics, properties of earth materials, rock mechanics, underground imaging, rock-fluid interactions, continental scientific drilling, geochemical transport, solar-atmospheric physics, and modeling, with emphasis on the interdisciplinary areas.

  13. Geological Carbon Sequestration, Spelunking and You | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Geological Carbon Sequestration, Spelunking and You Geological Carbon Sequestration, Spelunking and You August 11, 2010 - 2:45pm Addthis Niketa Kumar Niketa Kumar Public Affairs Specialist, Office of Public Affairs What does this project do? Develops and tests technologies to store CO2 in oil and gas reservoirs, deep saline formations, and basalts Here's a riddle for you: What do spelunkers, mineralogists and the latest Carbon Capture and Sequestration (CCS) awardees have in common? They're all

  14. Thermodynamic stability of actinide pyrochlore minerals in deep geologic

    Office of Scientific and Technical Information (OSTI)

    repository environments (Conference) | SciTech Connect Thermodynamic stability of actinide pyrochlore minerals in deep geologic repository environments Citation Details In-Document Search Title: Thermodynamic stability of actinide pyrochlore minerals in deep geologic repository environments Crystalline phases of pyrochlore (e.g., CaPuTi{sub 2}O{sub 7}, CaUTi{sub 2}O{sub 7}) have been proposed as a durable ceramic waste form for disposal of high level radioactive wastes including surplus

  15. State Geological Survey Contributions to the National Geothermal Data System- Final Technical Report

    SciTech Connect (OSTI)

    Allison, M. Lee; Richard, Stephen M.

    2015-03-13

    The State Geological Survey Contributions to the National Geothermal Data System project is built on the work of the project managed by Boise State University to design and build the National Geothermal Data System, by deploying it nationwide and populating it with data principally from State Geological Surveys through collaboration with the Association of American State Geologists (AASG). This project subsequently incorporated the results of the design-build and other DOE-funded projects in support of the NGDS. The NGDS (www.geothermaldata.org) provides free open access to millions of data records, images, maps, and reports, sharing relevant geoscience, production, and land use data in 30+ categories to propel geothermal development and production in the U.S. NGDS currently serves information gathered from hundreds of the U.S. Department of Energy sponsored development and research projects and geologic data feeds from 60+ data providers throughout all 50 states. These data are relevant to geothermal energy exploration and development, but also have broad applicability in other areas including natural resources (e.g., energy, minerals, water), natural hazards, and land use and management.

  16. GEO-SEQ Best Practices Manual. Geologic Carbon Dioxide Sequestration: Site Evaluation to Implementation

    SciTech Connect (OSTI)

    Benson, Sally M.; Myer, Larry R.; Oldenburg, Curtis M.; Doughty, Christine A.; Pruess, Karsten; Lewicki, Jennifer; Hoversten, Mike; Gasperikova, Erica; Daley, Thomas; Majer, Ernie; Lippmann, Marcelo; Tsang, Chin-Fu; Knauss, Kevin; Johnson, James; Foxall, William; Ramirez, Abe; Newmark, Robin; Cole, David; Phelps, Tommy J.; Parker, J.; Palumbo, A.; Horita, J.; Fisher, S.; Moline, Gerry; Orr, Lynn; Kovscek, Tony; Jessen, K.; Wang, Y.; Zhu, J.; Cakici, M.; Hovorka, Susan; Holtz, Mark; Sakurai, Shinichi; Gunter, Bill; Law, David; van der Meer, Bert

    2004-10-23

    The first phase of the GEO-SEQ project was a multidisciplinary effort focused on investigating ways to lower the cost and risk of geologic carbon sequestration. Through our research in the GEO-SEQ project, we have produced results that may be of interest to the wider geologic carbon sequestration community. However, much of the knowledge developed in GEO-SEQ is not easily accessible because it is dispersed in the peer-reviewed literature and conference proceedings in individual papers on specific topics. The purpose of this report is to present key GEO-SEQ findings relevant to the practical implementation of geologic carbon sequestration in the form of a Best Practices Manual. Because our work in GEO-SEQ focused on the characterization and project development aspects, the scope of this report covers practices prior to injection, referred to as the design phase. The design phase encompasses activities such as selecting sites for which enhanced recovery may be possible, evaluating CO{sub 2} capacity and sequestration feasibility, and designing and evaluating monitoring approaches. Through this Best Practices Manual, we have endeavored to place our GEO-SEQ findings in a practical context and format that will be useful to readers interested in project implementation. The overall objective of this Manual is to facilitate putting the findings of the GEO-SEQ project into practice.

  17. An Assessment of Geological Carbon Sequestration Options in the Illinois Basin

    SciTech Connect (OSTI)

    Robert Finley

    2005-09-30

    The Midwest Geological Sequestration Consortium (MGSC) has investigated the options for geological carbon dioxide (CO{sub 2}) sequestration in the 155,400-km{sup 2} (60,000-mi{sup 2}) Illinois Basin. Within the Basin, underlying most of Illinois, western Indiana, and western Kentucky, are relatively deeper and/or thinner coal resources, numerous mature oil fields, and deep salt-water-bearing reservoirs that are potentially capable of storing CO{sub 2}. The objective of this Assessment was to determine the technical and economic feasibility of using these geological sinks for long-term storage to avoid atmospheric release of CO{sub 2} from fossil fuel combustion and thereby avoid the potential for adverse climate change. The MGSC is a consortium of the geological surveys of Illinois, Indiana, and Kentucky joined by six private corporations, five professional business associations, one interstate compact, two university researchers, two Illinois state agencies, and two consultants. The purpose of the Consortium is to assess carbon capture, transportation, and storage processes and their costs and viability in the three-state Illinois Basin region. The Illinois State Geological Survey serves as Lead Technical Contractor for the Consortium. The Illinois Basin region has annual emissions from stationary anthropogenic sources exceeding 276 million metric tonnes (304 million tons) of CO{sub 2} (>70 million tonnes (77 million tons) carbon equivalent), primarily from coal-fired electric generation facilities, some of which burn almost 4.5 million tonnes (5 million tons) of coal per year. Assessing the options for capture, transportation, and storage of the CO{sub 2} emissions within the region has been a 12-task, 2-year process that has assessed 3,600 million tonnes (3,968 million tons) of storage capacity in coal seams, 140 to 440 million tonnes (154 to 485 million tons) of capacity in mature oil reservoirs, 7,800 million tonnes (8,598 million tons) of capacity in saline reservoirs deep beneath geological structures, and 30,000 to 35,000 million tonnes (33,069 to 38,580 million tons) of capacity in saline reservoirs on a regional dip >1,219 m (4,000 ft) deep. The major part of this effort assessed each of the three geological sinks: coals, oil reservoirs, and saline reservoirs. We linked and integrated options for capture, transportation, and geological storage with the environmental and regulatory framework to define sequestration scenarios and potential outcomes for the region. Extensive use of Geographic Information Systems (GIS) and visualization technology was made to convey results to project sponsors, other researchers, the business community, and the general public. An action plan for possible technology validation field tests involving CO{sub 2} injection was included in a Phase II proposal (successfully funded) to the U.S. Department of Energy with cost sharing from Illinois Clean Coal Institute.

  18. Mobilization of Metals from Eau Claire Siltstone and the Impact of Oxygen under Geological Carbon Dioxide Sequestration Conditions

    SciTech Connect (OSTI)

    Shao, Hongbo; Kukkadapu, Ravi K.; Krogstad, Eirik J.; Newburn, Matthew K.; Cantrell, Kirk J.

    2014-09-01

    Geologic CO2 sequestration (GCS) has been proposed as a viable strategy to reduce anthropogenic CO2 emission; however, the increased cost that will be incurred by fossil energy production facilities is a deterrent to implementation of this technology. Allowing impurities in the effluent CO2 stream could result in significant financial and energy savings for CO2 capture and separation. However, impurities such as O2 have the potential to influence the redox state and alter the geochemical interactions that occur within GCS reservoirs, which increases the concern for CO2 and brine leakage from the storage reservoir as well as the overlying groundwater contamination. In this work, to investigate the impact of O2 co-injected with CO2 on the geochemical interactions, especially the trace metal mobilization from a GCS reservoir rock, batch studies were conducted with Eau Claire siltstone collected from CO2 sequestration sites. The rock was reacted with synthetic brines in contact with either 100% CO2 or a mixture of 95 mole% CO2-5 mole% O2 at 10.1 MPa and 75 C. Both microscopic and spectroscopic measurements, including 57Fe-Mssbauer spectroscopy, Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry, powder X-ray diffraction, scanning electron microscopy-energy dispersive x-ray spectroscopy, and chemical extraction were combined in this study to investigate reaction mechanisms. The Eau Claire siltstone contains quartz (52 wt%), fluorapatite (40%), and aluminosilicate (5%) as major components, and dolomite (2%), pyrite (1%), and small-particle-/poorly-crystalline Fe-oxides as minor components. With the introduction of CO2 into the reaction vessel containing rock and brine, the leaching of small amounts of fluorapatite, aluminosilicate, and dolomite occurred. Trace metals of environmental concern, including Pb, As, Cd, and Cu were detected in the leachate with concentrations up to 400 ppb in the CO2-brine-rock reaction system within 30 days. In the presence of O2, the mobilization of Pb, Cd, and Cu was significantly enhanced, whereas As concentrations decreased, compared with the reaction system without oxygen. The presence of oxygen resulted in the formation of secondary Fe-oxides which appear to be Fe(II)-substituted P-containing ferrihydrite. Although the rock contained only 1.04 wt% total Fe, oxidative dissolution of pyrite, leaching and oxidation of structural Fe(II) in fluorapatite, and precipitation of Fe-oxides significantly decreased the pH in brine with oxygen(pH 3.3-3.7), compared with the reaction system without oxygen (pH 4.2-4.4). In the CO2-rock-brine system without O2, the majority of As remained in the rock, with about 1.1% of the total As being released from intrinsic Fe-oxides to the aqueous phase. The release behavior of As to solution was consistent with competitive adsorption between phosphate/fluoride and As on Fe-oxide surfaces. In the presence of O2 the mobility of As was reduced due to enhanced adsorption onto both intrinsic and secondary Fe-oxide surfaces.When O2 was present, the dominant species in solution was the less toxic As(V). This work will advance our understanding of the geochemical reaction mechanisms that occur under GCS conditions and help to evaluate the risks associated with geological CO2 sequestration.

  19. Final Scientific/Technical Report – DE-EE0002960 Recovery Act. Detachment faulting and Geothermal Resources - An Innovative Integrated Geological and Geophysical Investigation of Pearl Hot Spring, Nevada

    SciTech Connect (OSTI)

    Stockli, Daniel F.

    2015-11-30

    The Pearl Host Spring Geothermal Project funded by the DoE Geothermal Program was a joint academic (KU/UT & OU) and industry collaboration (Sierra and Ram Power) to investigate structural controls and the importance of low-angle normal faults on geothermal fluid flow through a multifaceted geological, geophysical, and geochemical investigation in west-central Nevada. The study clearly showed that the geothermal resources in Clayton Valley are controlled by the interplay between low-angle normal faults and active deformation related to the Walker Lane. The study not only identified potentially feasible blind geothermal resource plays in eastern Clayton Valley, but also provide a transportable template for exploration in the area of west-central Nevada and other regional and actively-deforming releasing fault bends. The study showed that deep-seated low-angle normal faults likely act as crustal scale permeability boundaries and could play an important role in geothermal circulation and funneling geothermal fluid into active fault zones. Not unique to this study, active deformation is viewed as an important gradient to rejuvenated fracture permeability aiding the long-term viability of blind geothermal resources. The technical approach for Phase I included the following components, (1) Structural and geological analysis of Pearl Hot Spring Resource, (2) (U-Th)/He thermochronometry and geothermometry, (3) detailed gravity data and modeling (plus some magnetic and resistivity), (4) Reflection and Refraction Seismic (Active Source), (5) Integration with existing and new geological/geophysical data, and (6) 3-D Earth Model, combining all data in an innovative approach combining classic work with new geochemical and geophysical methodology to detect blind geothermal resources in a cost-effective fashion.

  20. Basic Research Needs for Electrical Energy Storage. Report of the Basic Energy Sciences Workshop on Electrical Energy Storage, April 2-4, 2007

    DOE R&D Accomplishments [OSTI]

    Goodenough, J. B.; Abruna, H. D.; Buchanan, M. V.

    2007-04-04

    To identify research areas in geosciences, such as behavior of multiphase fluid-solid systems on a variety of scales, chemical migration processes in geologic media, characterization of geologic systems, and modeling and simulation of geologic systems, needed for improved energy systems.

  1. Research Mentors

    Broader source: Energy.gov [DOE]

    Research mentors are scientists and engineers committed to support and guide the applicant's research activities during the Research Award. Research mentors must be currently conducting or...

  2. THERMAL ANALYSIS OF GEOLOGIC HIGH-LEVEL RADIOACTIVE WASTE PACKAGES

    SciTech Connect (OSTI)

    Hensel, S.; Lee, S.

    2010-04-20

    The engineering design of disposal of the high level waste (HLW) packages in a geologic repository requires a thermal analysis to provide the temperature history of the packages. Calculated temperatures are used to demonstrate compliance with criteria for waste acceptance into the geologic disposal gallery system and as input to assess the transient thermal characteristics of the vitrified HLW Package. The objective of the work was to evaluate the thermal performance of the supercontainer containing the vitrified HLW in a non-backfilled and unventilated underground disposal gallery. In order to achieve the objective, transient computational models for a geologic vitrified HLW package were developed by using a computational fluid dynamics method, and calculations for the HLW disposal gallery of the current Belgian geological repository reference design were performed. An initial two-dimensional model was used to conduct some parametric sensitivity studies to better understand the geologic system's thermal response. The effect of heat decay, number of co-disposed supercontainers, domain size, humidity, thermal conductivity and thermal emissivity were studied. Later, a more accurate three-dimensional model was developed by considering the conduction-convection cooling mechanism coupled with radiation, and the effect of the number of supercontainers (3, 4 and 8) was studied in more detail, as well as a bounding case with zero heat flux at both ends. The modeling methodology and results of the sensitivity studies will be presented.

  3. Experimental study of potential wellbore cement carbonation by various phases of carbon dioxide during geologic carbon sequestration

    SciTech Connect (OSTI)

    Jung, Hun Bok; Um, Wooyong

    2013-08-16

    Hydrated Portland cement was reacted with carbon dioxide (CO2) in supercritical, gaseous, and aqueous phases to understand the potential cement alteration processes along the length of a wellbore, extending from deep CO2 storage reservoir to the shallow subsurface during geologic carbon sequestration. The 3-D X-ray microtomography (XMT) images displayed that the cement alteration was significantly more extensive by CO2-saturated synthetic groundwater than dry or wet supercritical CO2 at high P (10 MPa)-T (50C) conditions. Scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) analysis also exhibited a systematic Ca depletion and C enrichment in cement matrix exposed to CO2-saturated groundwater. Integrated XMT, XRD, and SEM-EDS analyses identified the formation of extensive carbonated zone filled with CaCO3(s), as well as the porous degradation front and the outermost silica-rich zone in cement after exposure to CO2-saturated groundwater. The cement alteration by CO2-saturated groundwater for 2-8 months overall decreased the porosity from 31% to 22% and the permeability by an order of magnitude. Cement alteration by dry or wet supercritical CO2 was slow and minor compared to CO2-saturated groundwater. A thin single carbonation zone was formed in cement after exposure to wet supercritical CO2 for 8 months or dry supercritical CO2 for 15 months. Extensive calcite coating was formed on the outside surface of a cement sample after exposure to wet gaseous CO2 for 1-3 months. The chemical-physical characterization of hydrated Portland cement after exposure to various phases of carbon dioxide indicates that the extent of cement carbonation can be significantly heterogeneous depending on CO2 phase present in the wellbore environment. Both experimental and geochemical modeling results suggest that wellbore cement exposure to supercritical, gaseous, and aqueous phases of CO2 during geologic carbon sequestration is unlikely to damage the wellbore integrity because cement alteration by all phases of CO2 is dominated by carbonation reaction. This is consistent with previous field studies of wellbore cement with extensive carbonation after exposure to CO2 for 3 decades. However, XMT imaging indicates that preferential cement alteration by supercritical CO2 or CO2-saturated groundwater can occur along the cement-steel or cement-rock interfaces. This highlights the importance of further investigation of cement degradation along the interfaces of wellbore materials to ensure permanent geologic carbon storage.

  4. On Leakage from Geologic Storage Reservoirs of CO2

    SciTech Connect (OSTI)

    Pruess, Karsten

    2006-02-14

    Large amounts of CO2 would need to be injected underground to achieve a significant reduction of atmospheric emissions. The large areal extent expected for CO2 plumes makes it likely that caprock imperfections will be encountered, such as fault zones or fractures, which may allow some CO2 to escape from the primary storage reservoir. Leakage of CO2 could also occur along wellbores. Concerns with escape of CO2 from a primary geologic storage reservoir include (1) acidification of groundwater resources, (2) asphyxiation hazard when leaking CO2 is discharged at the land surface, (3) increase in atmospheric concentrations of CO2, and (4) damage from a high-energy, eruptive discharge (if such discharge is physically possible). In order to gain public acceptance for geologic storage as a viable technology for reducing atmospheric emissions of CO2, it is necessary to address these issues and demonstrate that CO2 can be injected and stored safely in geologic formations.

  5. Niagara Falls Storage Site, Lewiston, New York: geologic report

    SciTech Connect (OSTI)

    Not Available

    1984-06-01

    This report is one of a series of engineering and environmental reports planned for the US Department of Energy's properties at Niagara Falls, New York. It describes the essential geologic features of the Niagara Falls Storage Site. It is not intended to be a definitive statement of the engineering methods and designs required to obtain desired performance features for any permanent waste disposal at the site. Results are presented of a geological investigation that consisted of two phases. Phase 1 occurred during July 1982 and included geologic mapping, geophysical surveys, and a limited drilling program in the vicinity of the R-10 Dike, planned for interim storage of radioactive materials. Phase 2, initiated in December 1982, included excavation of test pits, geophysical surveys, drilling, observation well installation, and field permeability testing in the South Dike Area, the Northern Disposal Area, and the K-65 Tower Area.

  6. Use of seismic attributes in geological description of carbonate rocks

    SciTech Connect (OSTI)

    Castrejon-Vacio, F.; Porres-Luna, A.A.

    1994-12-31

    Seismic attributes have been used widely in order to obtain geological description of petroleum reservoirs, especially as a support for the definition of horizontal continuity of strata, with special emphasis on terrigeneous formations. Nevertheless the application of seismic attributes to the study of carbonate and naturally fractured reservoirs has been limited. This paper shows the application of seismic attributes and seismic inversion to the geological and petrophysical characterization of a naturally fractured reservoir with complex lithology, which is characteristic of the most important producing formations in Mexico. The results from these techniques provide the basis for the definition of a realistic geological model, which is of prime concern for the reservoir`s characterization, numerical studies and EOR applications.

  7. Remedial action and site design for stabilization of the inactive uranium mill tailings sites at Slick Rock, Colorado. Attachment 2, Geology report

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    This report presents geologic considerations that are pertinent to the Remedial Action Plan for Slick Rock mill tailings. Topics covered include regional geology, site geology, geologic stability, and geologic suitability.

  8. Workshop on hydrologic and geochemical monitoring in the Long Valley Caldera: proceedings

    SciTech Connect (OSTI)

    Sorey, M.L.; Farrar, C.D.; Wollenberg, H.A.

    1984-10-01

    A workshop reviewed the results of hydrologic and geochemical monitoring in the Long Valley caldera. Such monitoring is being done to detect changes in the hydrothermal system induced by ongoing magmatic and tectonic processes. Workshop participants discussed the need to instrument sites for continuous measurements of several parameters and to obtain additional hydrologic and chemical information from intermediate and deep drill holes. In addition to seismic and deformation monitoring, programs are currently in progress to monitor changes in the discharge characteristics of hot springs, fumaroles, and soil gases, as well as pressures and temperatures in wells. Some hydrochemical parameters are measured continuously, others are measured monthly or at longer intervals. This report summarizes the information presented at the hydrologic monitoring workshop, following the workshop agenda which was divided into four sessions: (1) overview of the hydrothermal system; (2) monitoring springs, fumaroles, and wells; (3) monitoring gas emissions; and (4) conclusions and recommendations.

  9. Site characterization plan: Yucca Mountain site, Nevada research and development area, Nevada: Consultation draft, Nuclear Waste Policy Act: Volume 2

    SciTech Connect (OSTI)

    1988-01-01

    The Yucca Mountain site in Nevada is one of three candidate sites for the first geologic repository for radioactive waste. On May 28, 1986, it was recommended for detailed study in a program of site characterization. This site characterization plan (SCP) has been prepared in accordance with the requirements of the Nuclear Waste Policy Act to summarize the information collected to date about the geologic conditions at the site; to describe the conceptual designs for the repository and the waste package and to present the plans for obtaining the geologic information necessary to demonstrate the suitability of the site for a repository, to design the repository and the waste package, to prepare an environmental impact statement, and to obtain from the US Nuclear Regulatory Commission (NRC) an authorization to construct the repository. Chapter 3 summarizes present knowledge of the regional and site hydrologic systems. The purpose of the information presented is to (1) describe the hydrology based on available literature and preliminary site-exploration activities that have been or are being performed and (2) provide information to be used to develop the hydrologic aspects of the planned site characterization program. Chapter 4 contains geochemical information about the Yucca Mountain site. The chapter references plan for continued collection of geochemical data as a part of the site characterization program. Chapter 4 describes and evaluates data on the existing climate and site meterology, and outlines the suggested procedures to be used in developing and validating methods to predict future climatic variation. 534 refs., 100 figs., 72 tabs.

  10. The geological structure at Clearlake, California: A preliminary review

    SciTech Connect (OSTI)

    Burns, K.L.

    1992-01-01

    The compilation of geologic exploration data from a complex Franciscan terrain near Clearlake, California, was systematized by dividing the geology into three constituent geometric systems, which are a fault system, a lithotope, and a structural vector field. It is inferred the high heat flow is due to a deepseated magma that fed a line of cinder cones and andesite flows. The country rock of the proposed Hot Dry Rock facility will be autochthonous Franciscan metagreywackes on the south limb of the High Valley antiform. The metagreywacke has a foliate texture resulting in a strong mechanical axial anisotropy that caused exceptional deviation of the Audrey A-1 well.

  11. Geochemical and physical properties of wetland soils at the Savannah River site

    SciTech Connect (OSTI)

    Dixon, K.L; Rogers, V.A.; Conner, S.P.; Cummings, C.L.; Gladden, J.B.; Weber, J.M.

    1996-05-01

    The Savannah River Site (SRS), located in Aiken, Allendale, and Barnwell Counties, South Carolina, is a nuclear production facility operated for the U.S. Department of Energy (DOE) by Westinghouse Savannah River Company (WSRC). To facilitate future human health and ecological risk assessments, treatability studies, remedial investigations, and feasibility studies for its wetland areas, SRS needs a database of background geochemical and physical properties of wetland soils. These data are needed for comparison to data collected from wetland soils that may have been affected by SRS operations. SRS contains 36,000 acres of wetlands and an additional 5,000 acres of bottom land soils subject to flooding. Recent studies of wetland soils near various waste units at SRS show that some wetlands have been impacted by releases of contaminants resulting from SRS operations (WSRC, 1992). Waste waters originating from the operations facilities typically have been discharged into seepage basins located in upland soils, direct discharge of waste water to wetland areas has been minimal. This suggests that impacted wetland areas have been affected indirectly as a result of transport mechanisms such as surface runoff, groundwater seeps, fluvial or sediment transport, and leaching. Looney et al. (1990) conducted a study to characterize the geochemical and physical properties of upland soils and shallow sediments on the SRS. A primary objective of the upland study was to collect the data needed to assess the qualitative and quantitative impacts of SRS operations on the environment. By comparing the upland soils data to data collected from waste units located in similar soils, SRS impacts could be assessed. The data were also intended to aid in selection of remediation alternatives. Because waste units at SRS have historically been located in upland areas, wetland soils were not sampled. (Abstract Truncated)

  12. Joint EM-NE-International Study of Glass Behavior over Geologic Time Scales

    SciTech Connect (OSTI)

    Ryan, Joseph V.; Ebert, W. L.; Icenhower, Jonathan P.; Schreiber, Daniel K.; Strachan, Denis M.; Vienna, John D.

    2012-03-30

    Vitrification has been chosen as the best demonstrated available technology for waste immobilization worldwide. To date, the contributions of physical and chemical processes controlling the long-term glass dissolution rate in geologic disposal remain uncertain; leading to a lack of international consensus on a glass corrosion rate law. Existing rate laws have overcome the uncertainty through conservatism, but a thorough mechanistic understanding of waste form durability in geologic environments would improve public and regulator confidence, as well as lead to cost savings if it is possible to take credit for the true durability of the waste form itself in system evaluations. To this end, six nations have joined together to formulate a joint plan for collaborative research into the mechanisms controlling the long-term corrosion of glass. This report highlights the technical program plan behind the US portion of this effort, with an emphasis on the current understanding (and limitations) of several mechanistic theories for glass corrosion. Some recent results are presented to provide an example of the ongoing research.

  13. Transportation Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    transportation-research TRACC RESEARCH Computational Fluid Dynamics Computational Structural Mechanics Transportation Systems Modeling Transportation Research Current Research Overview The U.S. Department of Transportation (USDOT) has established its only high-performance computing and engineering analysis research facility at Argonne National Laboratory to provide applications support in key areas of applied research and development for the USDOT community. The Transportation Research and

  14. Research Gallery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Gallery Research Gallery Exhibits in this gallery capture Laboratory's leading-edge research in many areas of science and technology to help solve national problems...

  15. Geological challenges in radioactive waste isolation: Third worldwide review

    SciTech Connect (OSTI)

    Witherspoon Editor, P.A.; Bodvarsson Editor, G.S.

    2001-12-01

    The broad range of activities on radioactive waste isolation that are summarized in Table 1.1 provides a comprehensive picture of the operations that must be carried out in working with this problem. A comparison of these activities with those published in the two previous reviews shows the important progress that is being made in developing and applying the various technologies that have evolved over the past 20 years. There are two basic challenges in perfecting a system of radioactive waste isolation: choosing an appropriate geologic barrier and designing an effective engineered barrier. One of the most important developments that is evident in a large number of the reports in this review is the recognition that a URL provides an excellent facility for investigating and characterizing a rock mass. Moreover, a URL, once developed, provides a convenient facility for two or more countries to conduct joint investigations. This review describes a number of cooperative projects that have been organized in Europe to take advantage of this kind of a facility in conducting research underground. Another critical development is the design of the waste canister (and its accessory equipment) for the engineered barrier. This design problem has been given considerable attention in a number of countries for several years, and some impressive results are described and illustrated in this review. The role of the public as a stakeholder in radioactive waste isolation has not always been fully appreciated. Solutions to the technical problems in characterizing a specific site have generally been obtained without difficulty, but procedures in the past in some countries did not always keep the public and local officials informed of the results. It will be noted in the following chapters that this procedure has caused some problems, especially when approval for a major component in a project was needed. It has been learned that a better way to handle this problem is to keep all stakeholders fully informed of project plans and hold periodic meetings to brief the public, especially in the vicinity of the selected site. This procedure has now been widely adopted and represents one of the most important developments in the Third Worldwide Review.

  16. Geologic mapping for groundwater resource protection and assessment

    SciTech Connect (OSTI)

    Shafer, J.M. . Earth Sciences and Resources Inst.); Berg, R.C. )

    1993-03-01

    Groundwater is a vital natural resource in the US and around the world. In order to manage and protect this often threatened resource one must better understand its occurrence, extent, and susceptibility to contamination. Geologic mapping is a fundamental approach to developing more detailed and accurate assessments of groundwater resources. The stratigraphy and lithology of earth materials provide the framework for groundwater systems, whether they are deep confined aquifers or shallow, water table environments. These same earth materials control, in large part, the rates of migration of water and contaminants into and through groundwater systems thus establishing the potential yields of the systems and their vulnerability to contamination. Geologic mapping is used to delineate and display the vertical sequencing of earth materials either in cross-section or over lateral areas as in the stack-unit geologic map. These geologic maps, along with supportive hydrogeologic information, are used to identify the three-dimensional positioning and continuity of aquifer and non-aquifer earth materials. For example, detailed stack-unit mapping to a depth of 30 meters has been completed for a portion of a northern Illinois county. Groundwater contamination potentials were assigned to various vertical sequences of materials. Where aquifers are unconfined, groundwater contamination potentials are greatest. Conversely, other considerations being equal, the thicker the confining unit, the lower the contamination potential. This information is invaluable for land use decision-making; water supply assessment, development, and management; and environmental protection planning.

  17. State Geological Survey Contributions to the National Geothermal Data System

    Broader source: Energy.gov [DOE]

    Project objectives: Deploy and populate the National Geothermal Data System (NGDS) with state-specific data by creating a national, sustainable, distributed, interoperable network of state geological survey-based data providers that will develop, collect, serve, and maintain geothermal-relevant data that operates as an integral compliant component of NGDS.

  18. Geological problems in radioactive waste isolation - second worldwide review

    SciTech Connect (OSTI)

    Witherspoon, P.A.

    1996-09-01

    The first world wide review of the geological problems in radioactive waste isolation was published by Lawrence Berkeley National Laboratory in 1991. This review was a compilation of reports that had been submitted to a workshop held in conjunction with the 28th International Geological Congress that took place July 9-19, 1989 in Washington, D.C. Reports from 15 countries were presented at the workshop and four countries provided reports after the workshop, so that material from 19 different countries was included in the first review. It was apparent from the widespread interest in this first review that the problem of providing a permanent and reliable method of isolating radioactive waste from the biosphere is a topic of great concern among the more advanced, as well as the developing, nations of the world. This is especially the case in connection with high-level waste (HLW) after its removal from nuclear power plants. The general concensus is that an adequate isolation can be accomplished by selecting an appropriate geologic setting and carefully designing the underground system with its engineered barriers. This document contains the Second Worldwide Review of Geological Problems in Radioactive Waste Isolation, dated September 1996.

  19. UNITED STATES GEOLOGICAL SURVEY DEPARTMENT OF THE INTERIOR F

    Office of Legacy Management (LM)

    I i This page intentionally left blank R u l i s o n - 1 0 , 1971 UNITED STATES GEOLOGICAL ... e d b y a n a l y s i s of samples c o l l e c t e d from t h e network s t a t i o n s . ...

  20. Summaries of physical research in the geosciences

    SciTech Connect (OSTI)

    Not Available

    1983-09-01

    The Department of Energy supports research in the geosciences in order to provide a sound foundation of fundamental knowledge in those areas of earth, atmospheric, and solar-terrestrial sciences that are germane to the Department of Energy's many missions. The summaries in the document describe the scope of the individual programs and detail the research performed during 1982 to 1983. The Geoscience Research Program includes research in geology, petrology, geophysics, geochemistry, hydrology, solar-terrestrial relationships, aeronomy, seismology, and natural resource analysis, including the various subdivisions and interdisciplinary areas. All such research is related either directly or indirectly to the Department of Energy's technological needs.

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Submitter: Area of Research: Journal Reference: N/A

  2. Support of Gulf of Mexico Hydrate Research Consortium: Activities to Support Establishment of a Sea Floor Monitoring Station Project

    SciTech Connect (OSTI)

    Carol Lutken

    2006-09-30

    The Gulf of Mexico Hydrates Research Consortium (GOM-HRC) was established in 1999 to assemble leaders in gas hydrates research. The Consortium is administered by the Center for Marine Resources and Environmental Technology, CMRET, at the University of Mississippi. The primary objective of the group is to design and emplace a remote monitoring station or sea floor observatory (MS/SFO) on the sea floor in the northern Gulf of Mexico by the year 2007, in an area where gas hydrates are known to be present at, or just below, the sea floor. This mission, although unavoidably delayed by hurricanes and other disturbances, necessitates assembling a station that will monitor physical and chemical parameters of the marine environment, including sea water and sea-floor sediments, on a more-or-less continuous basis over an extended period of time. In 2005, biological monitoring, as a means of assessing environmental health, was added to the mission of the MS/SFO. Establishment of the Consortium has succeeded in fulfilling the critical need to coordinate activities, avoid redundancies and communicate effectively among researchers in the arena of gas hydrates research. Complementary expertise, both scientific and technical, has been assembled to promote innovative research methods and construct necessary instrumentation. The observatory has now achieved a microbial dimension in addition to the geophysical, geological, and geochemical components it had already included. Initial components of the observatory, a probe that collects pore-fluid samples and another that records sea floor temperatures, were deployed in Mississippi Canyon 118 in May of 2005. Follow-up deployments, planned for fall 2005, had to be postponed due to the catastrophic effects of Hurricane Katrina (and later, Rita) on the Gulf Coast. Station/observatory completion, anticipated for 2007, will likely be delayed by at least one year. The CMRET has conducted several research cruises during this reporting period: one in April, one in June, one in September. April's effort was dedicated to surveying the mound at MC118 with the Surface-Source-Deep-Receiver (SSDR) seismic surveying system. This survey was completed in June and water column and bottom samples were collected via box coring. A microbial filtering system developed by Consortium participants at the University of Georgia was also deployed, run for {approx}12 hours and retrieved. The September cruise, designed to deploy, test, and in some cases recover, geochemical and microbial instruments and experiments took place aboard Harbor Branch's Seward Johnson and employed the Johnson SeaLink manned submersible. The seafloor monitoring station/observatory is funded approximately equally by three federal Agencies: Minerals Management Services (MMS) of the Department of the Interior (DOI), National Energy Technology Laboratory (NETL) of the Department of Energy (DOE), and the National Institute for Undersea Science and Technology (NIUST), an agency of the National Oceanographic and Atmospheric Administration (NOAA). Subcontractors with FY03 funding fulfilled their technical reporting requirements in a previously submitted report (41628R10). Only unresolved matching funds issues remain and will be addressed in the report of the University of Mississippi's Office of Research and Sponsored Programs. In addition, Barrodale Computing Services Ltd. (BCS) completed their work; their final report is the bulk of the semiannual report that precedes (abstract truncated)

  3. Research Portfolio Report Unconventional Oil & Gas Resources:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Subsurface Geology and Engineering Cover image: "Fragments below exposure of fissile Marcellus black shale at Marcellus, N.Y." by Lvklock is licensed under CC by SA-3.0. Research Portfolio Report Unconventional Oil & Gas Resources: Subsurface Geology and Engineering DOE/NETL-2015/1691 Prepared by: Velda Frisco, Mari Nichols-Haining, and Christine Rueter KeyLogic Systems, Inc. National Energy Technology Laboratory (NETL) Contact: James Ammer james.ammer@netl.doe.gov Contract

  4. Database for Regional Geology, Phase 1: A Tool for Informing Regional Evaluations of Alternative Geologic Media and Decision Making

    SciTech Connect (OSTI)

    Perry, Frank Vinton; Kelley, Richard E.; Birdsell, Suzanne M.; Lugo, Alexander Bryan; Dobson, Patrick; Houseworth, James

    2014-11-12

    Reported is progress in the following areas: Phase 1 and 2 websites for the regional geology GIS database; terrane maps of crystalline basement rocks; inventory of shale formations in the US; and rock properties and in-situ conditions for shale estimated from sonic velocity measurements.

  5. Geological and production characteristics of strandplain/barrier island reservoirs in the United States

    SciTech Connect (OSTI)

    Cole, E.L.; Fowler, M.; Jackson, S.; Madden, M.P.; Reeves, T.K.; Salamy, S.P.; Young, M.A.

    1994-12-01

    The Department of Energy`s (DOE`s) primary mission in the oil research program is to maximize the economically and environmentally sound recovery of oil from domestic reservoirs and to preserve access to this resource. The Oil Recovery Field Demonstration Program supports DOE`s mission through cost-shared demonstrations of improved Oil Recovery (IOR) processes and reservoir characterization methods. In the past 3 years, the DOE has issued Program Opportunity Notices (PONs) seeking cost-shared proposals for the three highest priority, geologically defined reservoir classes. The classes have been prioritized based on resource size and risk of abandonment. This document defines the geologic, reservoir, and production characteristics of the fourth reservoir class, strandplain/barrier islands. Knowledge of the geological factors and processes that control formation and preservation of reservoir deposits, external and internal reservoir heterogeneities, reservoir characterization methodology, and IOR process application can be used to increase production of the remaining oil-in-place (IOR) in Class 4 reservoirs. Knowledge of heterogeneities that inhibit or block fluid flow is particularly critical. Using the TORIS database of 330 of the largest strandplain/barrier island reservoirs and its predictive and economic models, the recovery potential which could result from future application of IOR technologies to Class 4 reservoirs was estimated to be between 1.0 and 4.3 billion barrels, depending on oil price and the level of technology advancement. The analysis indicated that this potential could be realized through (1) infill drilling alone and in combination with polymer flooding and profile modification, (2) chemical flooding (sufactant), and (3) thermal processes. Most of this future potential is in Texas, Oklahoma, and the Rocky Mountain region. Approximately two-thirds of the potentially recoverable resource is at risk of abandonment by the year 2000.

  6. Optimization of Geological Environments for Carbon Dioxide Disposan in Saline Aquifers in the United States

    SciTech Connect (OSTI)

    Hovorka, Susan

    1999-02-01

    Recent research and applications have demonstrated technologically feasible methods, defined costs, and modeled processes needed to sequester carbon dioxide (CO{sub 2}) in saline-water-bearing formations (aquifers). One of the simplifying assumptions used in previous modeling efforts is the effect of real stratigraphic complexity on transport and trapping in saline aquifers. In this study we have developed and applied criteria for characterizing saline aquifers for very long-term sequestration of CO{sub 2}. The purpose of this pilot study is to demonstrate a methodology for optimizing matches between CO{sub 2} sources and nearby saline formations that can be used for sequestration. This project identified 14 geologic properties used to prospect for optimal locations for CO{sub 2} sequestration in saline-water-bearing formations. For this demonstration, we digitized maps showing properties of saline formations and used analytical tools in a geographic information system (GIS) to extract areas that meet variably specified prototype criteria for CO{sub 2} sequestration sites. Through geologic models, realistic aquifer properties such as discontinuous sand-body geometry are determined and can be used to add realistic hydrologic properties to future simulations. This approach facilitates refining the search for a best-fit saline host formation as our understanding of the most effective ways to implement sequestration proceeds. Formations where there has been significant drilling for oil and gas resources as well as extensive characterization of formations for deep-well injection and waste disposal sites can be described in detail. Information to describe formation properties can be inferred from poorly known saline formations using geologic models in a play approach. Resulting data sets are less detailed than in well-described examples but serve as an effective screening tool to identify prospects for more detailed work.

  7. Multipurpose bedrock surficial, and environmental geologic maps, New River valley, southwest Virginia

    SciTech Connect (OSTI)

    Schultz, A. ); Collins, T. )

    1994-03-01

    Multipurpose bedrock, surficial, and environmental geologic maps have recently been completed for portions of the Valley and Ridge province of southwest VA. The maps, at both 1:100,000 and 1:24,000 scales, show generalized and detailed bedrock geology grouped by lithology and environmental hazard associations. Also shown are a variety of alluvial, colluvial, debris flow, and landslide deposits, as well as karst features. Multidisciplinary research topics addressed during the mapping included slope evolution and geomorphology, drainage history and terrace distribution, ancient large-scale landsliding, and sinkhole development. The maps have been used by land-use planners and engineering firms in an evaluation of Appalachian paleoseismicity and to assess potential groundwater contamination and subsidence in karst areas. The maps are being used for environmental hazard assessment and site selection of a proposed large electric powerline that crosses the Jefferson National Forest. Also, the maps are proving useful in planning for a public access interpretive geologic enter focused on large-scale slope failures. Some of the largest known landslides in eastern North America took place within the map area. Field comparisons and detailed structure mapping of similar features along the Front Range of the Colorado Rockies indicate that the landslides were probably emplaced during a single catastrophic event of short duration. Although the giles County seismic zone is nearby, stability analyses of slopes in the map area have shown that failure need not have been initiated by a seismic event. Several distinct colluvial units mapped within the area of landslides document a period of extensive weathering that postdates slide emplacement. Radiocarbon dates from landslide sag ponds indicate a minimum age of 9,860 B.P. for emplacement of some of the landslides. These results indicate that pre-slide colluvial and debris flow deposits are at least Pleistocene in age.

  8. Summaries of FY 1994 geosciences research

    SciTech Connect (OSTI)

    Not Available

    1994-12-01

    The Geosciences Research Program is directed by the Department of Energy`s (DOE`s) Office of Energy Research (OER) through its Office of Basic Energy Sciences (OBES). Activities in the Geosciences Research Program are directed toward the long-term fundamental knowledge of the processes that transport, modify, concentrate, and emplace (1) the energy and mineral resources of the earth and (2) the energy byproducts of man. The Program is divided into five broad categories: Geophysics and earth dynamics; Geochemistry; Energy resource recognition, evaluation, and utilization; Hydrogeology and exogeochemistry; and Solar-terrestrial interactions. The summaries in this document, prepared by the investigators, describe the scope of the individual programs in these main areas and their subdivisions including earth dynamics, properties of earth materials, rock mechanics, underground imaging, rock-fluid interactions, continental scientific drilling, geochemical transport, solar/atmospheric physics, and modeling, with emphasis on the interdisciplinary areas.

  9. Novel Imaging Techniques, Integrated with Mineralogical, Geochemical and Microbiological Characterization to Determine the Biogeochemical Controls....

    SciTech Connect (OSTI)

    Lloyd, Jonathan R.

    2005-06-01

    Tc(VII) will be reduced and precipitated in FRC sediments under anaerobic conditions in batch experiments (progressive microcosms). The complementary microcosm experiments using low pH/nigh nitrate sediments from 3 (near FW 009) are imminent, with the sediment cores already shipped to Manchester. HYPOTHESIS 2. Tc(VII) reduction and precipitation can be visualized in discrete biogeochemical zones in sediment columns using 99mTc and a gamma-camera. Preliminary experiments testing the use of 99mTc as a radiotracer to address hypotheses 2 and 3 have suggested that the 99mTc associates with Fe(II)-bearing sediments in microcosms and stratified columns containing FRC sediments. Initial proof of concept microcosms containing Fe(II)-bearing, microbially-reduced FRC sediments were spiked with 99mTc and imaged using a gamma-camera. In comparison with oxic controls, 99mTc was significantly partitioned in the solid phase in Fe(III)-reducing sediments in batch experiments. Column experiments using FRC background area soil with stratified biogeochemical zones after stimulation of anaerobic processes through nutrient supplementation, suggested that 99mTc transport was retarded through areas of Fe(III) reduction. HYPOTHESIS 3. Sediment-bound reduced 99mTc can be solubilized by perturbations including oxidation coupled to biological nitrate reduction, and mobilization visualized in real-time using a gamma-camera. Significant progress has been made focusing on the impact of nitrate on the biogeochemical behavior of technetium. Additions of 100 mM nitrate to FRC sediment microcosms, which could potentially compete for electrons during metal reduction, inhibited the reduction of both Fe(III) and Tc(VII) completely. Experiments have also addressed the impact of high nitrate concentrations on Fe(II) and Tc(IV) in pre-reduced sediments, showing no significant resolubilization of Tc with the addition of 25 mM nitrate. A parallel set of experiments addressing the impact of aerobic conditions on the stability/solubility of Fe(II) and Tc(IV), found 80 % resolubilization of the Tc. Column experiments exploring this behavior are being planned. HYPOTHESIS 4 The mobility of 99mTc in the sediment columns can be modeled using a coupled speciation and transport code. Microbiological and geochemical characterization of the column experiments is ongoing and transport and geochemical modeling experiments are being planned.

  10. The Research Path to Determining the Natural Gas Supply Potential of Marine Gas Hydrates

    SciTech Connect (OSTI)

    Boswell, R.M.; Rose, K.K.; Baker, R.C.

    2008-06-01

    A primary goal of the U.S. National Interagency Gas Hydrates R&D program is to determine the natural gas production potential of marine gas hydrates. In pursuing this goal, four primary areas of effort are being conducted in parallel. First, are wide-ranging basic scientific investigations in both the laboratory and in the field designed to advance the understanding of the nature and behavior of gas hydrate bearing sediments (GHBS). This multi-disciplinary work has wide-ranging direct applications to resource recovery, including assisting the development of exploration and production technologies through better rock physics models for GHBS and also in providing key data for numerical simulations of productivity, reservoir geomechanical response, and other phenomena. In addition, fundamental science efforts are essential to developing a fuller understanding of the role gas hydrates play in the natural environment and the potential environmental implications of gas hydrate production, a critical precursor to commercial extraction. A second area of effort is the confirmation of resource presence and viability via a series of multi-well marine drilling expeditions. The collection of data in the field is essential to further clarifying what proportion of the likely immense in-place marine gas hydrate resource exists in accumulations of sufficient quality to represent potential commercial production prospects. A third research focus area is the integration of geologic, geophysical, and geochemical field data into an effective suite of exploration tools that can support the delineation and characterization commercial gas hydrate prospects prior to drilling. The fourth primary research focus is the development and testing of well-based extraction technologies (including drilling, completion, stimulation and production) that can safely deliver commercial gas production rates from gas hydrate reservoirs in a variety of settings. Initial efforts will take advantage of the relatively favorable economics of conducting production tests in Arctic gas-hydrate bearing sandstones with the intent of translating the knowledge gained to later testing in marine sandstone reservoirs. The full and concurrent pusuit of each of these research topics is essential to the determining the future production potential of naturally-occuring gas hydrates.

  11. The Macolumn: Desperately seeking software. [Geologic software for the Apple Macintosh

    SciTech Connect (OSTI)

    Busbey, A.B.

    1988-08-01

    The Apple Macintosh has been available since 1984, but there has been little development of commercial geological software for it. The author briefly reviews what geological software is available for the Macintosh

  12. Comparison of microbial and sorbed soil gas surgace geochemical techniques with seismic surveys from the Southern Altiplano, Bolivia

    SciTech Connect (OSTI)

    Aranibar, O.R.; Tucker, J.D.; Hiltzman, D.C.

    1995-12-31

    Yacimientos Petroliferos Fiscales Bolivianos (YPFB) undertook a large seismic evaluation in the southern Altiplano, Bolivia in 1994. As an additional layer of information, sorbed soil gas and Microbial Oil Survey Technique (MOST) geochemical surveys were conducted to evaluate the hydrocarbon microseepage potential. The Wara Sara Prospect had 387 sorbed soil gas samples, collected from one meter depth, and 539 shallow soil microbial samples, collected from 15 to 20 centimeter depth. The sorbed soil gas samples were collected every 500 meters and microbial samples every 250 meters along geochemical traverses spaced 1 km apart. The presence of anmalous hydrocarbon microseepage is indicated by (1) a single hydrocarbon source identified by gas crossplots, (2) the high gas values with a broad range, (3) the high overall gas average, (4) the clusters of elevated samples, and (5) the right hand skewed data distributions.

  13. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bacon, Diana H.; Dai, Zhenxue; Zheng, Liange

    2014-12-31

    An important risk at CO2 storage sites is the potential for groundwater quality impacts. As part of a system to assess the potential for these impacts a geochemical scaling function has been developed, based on a detailed reactive transport model of CO2 and brine leakage into an unconfined, oxidizing carbonate aquifer. Stochastic simulations varying a number of geochemical parameters were used to generate a response surface predicting the volume of aquifer that would be impacted with respect to regulated contaminants. The brine was assumed to contain several trace metals and organic contaminants. Aquifer pH and TDS were influenced by CO2more » leakage, while trace metal concentrations were most influenced by the brine concentrations rather than adsorption or desorption on calcite. Organic plume sizes were found to be strongly influenced by biodegradation.« less

  14. Improved Geothermometry Through Multivariate Reaction-path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators: Final Report

    SciTech Connect (OSTI)

    Mattson, Earl; Smith, Robert; Fujita, Yoshiko; McLing, Travis; Neupane, Ghanashyam; Palmer, Carl; Reed, David; Thompson, Vicki

    2015-03-01

    The project was aimed at demonstrating that the geothermometric predictions can be improved through the application of multi-element reaction path modeling that accounts for lithologic and tectonic settings, while also accounting for biological influences on geochemical temperature indicators. The limited utilization of chemical signatures by individual traditional geothermometer in the development of reservoir temperature estimates may have been constraining their reliability for evaluation of potential geothermal resources. This project, however, was intended to build a geothermometry tool which can integrate multi-component reaction path modeling with process-optimization capability that can be applied to dilute, low-temperature water samples to consistently predict reservoir temperature within ±30 °C. The project was also intended to evaluate the extent to which microbiological processes can modulate the geochemical signals in some thermal waters and influence the geothermometric predictions.

  15. Summary Report on CO{sub 2} Geologic Sequestration & Water Resources Workshop

    SciTech Connect (OSTI)

    Varadharajan, C.; Birkholzer, J.; Kraemer, S.; Porse, S.; Carroll, S.; Wilkin, R.; Maxwell, R.; Bachu, S.; Havorka, S.; Daley, T.; Digiulio, D.; Carey, W.; Strasizar, B.; Huerta, N.; Gasda, S.; Crow, W.

    2012-02-15

    The United States Environmental Protection Agency (EPA) and Lawrence Berkeley National Laboratory (LBNL) jointly hosted a workshop on CO{sub 2} Geologic Sequestration and Water Resources in Berkeley, June 12, 2011. The focus of the workshop was to evaluate R&D needs related to geological storage of CO{sub 2} and potential impacts on water resources. The objectives were to assess the current status of R&D, to identify key knowledge gaps, and to define specific research areas with relevance to EPAs mission. About 70 experts from EPA, the DOE National Laboratories, industry, and academia came to Berkeley for two days of intensive discussions. Participants were split into four breakout session groups organized around the following themes: Water Quality and Impact Assessment/Risk Prediction; Modeling and Mapping of Area of Potential Impact; Monitoring and Mitigation; Wells as Leakage Pathways. In each breakout group, participants identified and addressed several key science issues. All groups developed lists of specific research needs; some groups prioritized them, others developed short-term vs. long-term recommendations for research directions. Several crosscutting issues came up. Most participants agreed that the risk of CO{sub 2} leakage from sequestration sites that are properly selected and monitored is expected to be low. However, it also became clear that more work needs to be done to be able to predict and detect potential environmental impacts of CO{sub 2} storage in cases where the storage formation may not provide for perfect containment and leakage of CO{sub 2}brine might occur.

  16. Geologic map and coal resources of the Easton Gulch Quadrangle, Moffat County, Colorado

    SciTech Connect (OSTI)

    Reheis, M.C.

    1981-01-01

    This map of the Easton Gulch Quadrangle, Moffat County, Colorado is color coded to show the location of different age geologic formations. Various thickness coal bed are indicated as are abandoned coal mines or prospects, US Geologic Survey (USGS) test holes, abandoned oil and gas test holes, and USGS Mesozoic fossil localities. Various depth coal beds and other types of geologic structures are indicated on the cross-section geologic map. (BLM)

  17. Wave Propagation in Jointed Geologic Media (Technical Report) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect Wave Propagation in Jointed Geologic Media Citation Details In-Document Search Title: Wave Propagation in Jointed Geologic Media Predictive modeling capabilities for wave propagation in a jointed geologic media remain a modern day scientific frontier. In part this is due to a lack of comprehensive understanding of the complex physical processes associated with the transient response of geologic material, and in part it is due to numerical challenges that prohibit accurate

  18. HYDRATE RESEARCH ACTIVITIES THAT BOTH SUPPORT AND DERIVE FROM THE MONITORING STATION/SEA-FLOOR OBSERVATORY, MISSISSIPPI CANYON 118, NORTHERN GULF OF MEXICO

    SciTech Connect (OSTI)

    Lutken, Carol

    2013-07-31

    A permanent observatory has been installed on the seafloor at Federal Lease Block, Mississippi Canyon 118 (MC118), northern Gulf of Mexico. Researched and designed by the Gulf of Mexico Hydrates Research Consortium (GOM-HRC) with the geological, geophysical, geochemical and biological characterization of in situ gas hydrates systems as the research goal, the site has been designated by the Bureau of Ocean Energy Management as a permanent Research Reserve where studies of hydrates and related ocean systems may take place continuously and cooperatively into the foreseeable future. The predominant seafloor feature at MC118 is a carbonate-hydrate complex, officially named Woolsey Mound for the founder of both the GOM-HRC and the concept of the permanent seafloor hydrates research facility, the late James Robert “Bob” Woolsey. As primary investigator of the overall project until his death in mid-2008, Woolsey provided key scientific input and served as chief administrator for the Monitoring Station/ Seafloor Observatory (MS-SFO). This final technical report presents highlights of research and accomplishments to date. Although not all projects reached the status originally envisioned, they are all either complete or positioned for completion at the earliest opportunity. All Department of Energy funds have been exhausted in this effort but, in addition, leveraged to great advantage with additional federal input to the project and matched efforts and resources. This report contains final reports on all subcontracts issued by the University of Mississippi, Administrators of the project, Hydrate research activities that both support and derive from the monitoring station/sea-floor Observatory, Mississippi Canyon 118, northern Gulf of Mexico, as well as status reports on the major components of the project. All subcontractors have fulfilled their primary obligations. Without continued funds designated for further project development, the Monitoring Station/Seafloor Observatory is in danger of lapsing into disuse. However, for the present, interest in the site on the continental slope is healthy and The Center for Marine Resources and Environmental Technology continues to coordinate all activity at the MS/SFO as arranged through the BOEM in 2005. Field and laboratory research projects and findings are reviewed, new technologies and tests described. Many new sensors, systems and two custom ROVs have been developed specifically for this project. Characteristics of marine gas hydrates are dramatically more refined than when the project was initiated and include appear in sections entitled Accomplishments, Products and Publications.

  19. Geologic Water Storage in Pre-Columbian Peru

    SciTech Connect (OSTI)

    Fairley Jr., Jerry P.

    1997-07-14

    Agriculture in the arid and semi-arid regions that comprise much of present-day Peru, Bolivia, and Northern Chile is heavily dependent on irrigation; however, obtaining a dependable water supply in these areas is often difficult. The precolumbian peoples of Andean South America adapted to this situation by devising many strategies for transporting, storing, and retrieving water to insure consistent supply. I propose that the ''elaborated springs'' found at several Inka sites near Cuzco, Peru, are the visible expression of a simple and effective system of groundwater control and storage. I call this system ''geologic water storage'' because the water is stored in the pore spaces of sands, soils, and other near-surface geologic materials. I present two examples of sites in the Cuzco area that use this technology (Tambomachay and Tipon) and discuss the potential for identification of similar systems developed by other ancient Latin American cultures.

  20. THE ROLE OF PORE PRESSURE IN DEFORMATION IN GEOLOGIC PROCESSES

    SciTech Connect (OSTI)

    Narasimhan, T. N.; Houston, W. N.; Nur, A. M.

    1980-03-01

    A Penrose Conference entitled, "The Role of Pore Pressure in Deformation in Geologic Processes" was convened by the authors at San Diego, California between November 9 and 13, 1979. The conference was sponsored by the Geological Society of America. This report is a summary of the highlights of the issues discussed during the conference. In addition, this report also includes a topical reference list relating to the different subject areas relevant to pore pressure and deformation. The references were compiled from a list suggested by the participants and were available for consultation during the conference. Although the list is far from complete, it should prove to be a good starting point for one who is looking for key papers in the field.

  1. Geologic report for the Weldon Spring Raffinate Pits Site

    SciTech Connect (OSTI)

    1984-10-01

    A preliminary geologic site characterization study was conducted at the Weldon Spring Raffinate Pits Site, which is part of the Weldon Spring Site, in St. Charles County, Missouri. The Raffinate Pits Site is under the custody of the Department of Energy (DOE). Surrounding properties, including the Weldon Spring chemical plant, are under the control of the Department of the Army. The study determined the following parameters: site stratigraphy, lithology and general conditions of each stratigraphic unit, and groundwater characteristics and their relation to the geology. These parameters were used to evaluate the potential of the site to adequately store low-level radioactive wastes. The site investigation included trenching, geophysical surveying, borehole drilling and sampling, and installing observation wells and piezometers to monitor groundwater and pore pressures.

  2. The low temperature hydrothermal system of Campiglia, Tuscany (Italy); A geochemical approach

    SciTech Connect (OSTI)

    Celati, R.; Grassi, S.; D'Amore, F.; Marcolini, L. )

    1991-01-01

    This paper reports on the Campiglia hydrothermal system which is a low temperature hydrothermal system located in southwestern Tuscany, a region of Italy characterized by intense geothermal activity and by the presence of high temperature exploited geothermal reservoirs. Six water-points, with temperatures ranging between 20 and 47{degrees} C and different chemical and isotopic compositions, are found close to the margins of outcrops of the main regional aquifer formation. Systematic hydrogeological, geochemical and isotopic observations and temperature measurements were carried out on the different springs and wells for a period of three years (1984-1986). Constant water characteristics with time were observed in four water-points; two wells had variable trends depending on mixing processes. A groundwater circulation model characterized by flowpaths of different length and depth is suggested by the variety of chemical and isotopic characteristics and is consistent with geothermometry, which indicates temperatures up to 25{degrees} C higher than those measured at the spring emergencies. An important water supply to the system comes from local recharge, although regional circulation may also be present, particularly in the eastern part of the investigated area.

  3. Geochemical information for sites contaminated with low-level radioactive wastes: I. Niagara Falls Storage Site

    SciTech Connect (OSTI)

    Seeley, F.G.; Kelmers, A.D.

    1984-11-01

    The Niagara Falls Storage Site (NFSS) became radioactively contaminated as a result of wastes that were being stored from operations carried out to recover uranium from pitchblende ore in the 1940s and 1950s. The US Department of Energy (DOE) is considering various remedial action options for the NFSS. This report describes the results of geochemical investigations performed to help provide a quantitative evaluation of the effects of various options. NFSS soil and groundwater samples were characterized; and uranium and radium sorption ratios, as well as apparent concentration limit values, were measured in site soil/groundwater systems by employing batch contact methodology. The results suggest that any uranium which is in solution in the groundwater at the NFSS may be poorly retarded due to the low uranium sorption ratio values and high solubility measured. Further, appreciable concentrations of uranium in groundwater could be attained from soluble wastes. Release of uranium via groundwater migration could be a significant release pathway. Solubilized radium would be expected to be effectively retarded by soil at the NFSS as a result of the very high radium sorption ratios observed. The addition of iron oxyhydroxide to NFSS soils resulted in much higher uranium sorption ratios. Additional field testing of this potential remedial action additive could be desirable. 10 references.

  4. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    Office of Scientific and Technical Information (OSTI)

    3 (2014) 4684 - 4707 Energy Procedia GHGT-12 Geochemical impacts of carbon dioxide, brine, trace metal and organic leakage into an unconfined, oxidizing limestone aquifer Diana H. Bacon3'* *, Zhenxue Daib, Liange Zhengc "Pacific Northwest National Laboratory, Richland, Washington, USA bLos Alamos National Laboratory, Los Alamos, New Mexico, USA cLawrence Berkeley National Laboratory, Berkeley, California, USA Abstract An important risk at CO2 storage sites is the potential for groundwater

  5. Microbial distributions detected by an oligonucleotide microarray across geochemical zones associated with methane in marine sediments from the Ulleung Basin

    SciTech Connect (OSTI)

    Briggs, Brandon R.; Graw, Michael; Brodie, Eoin L.; Bahk, Jang-Jun; Kim, Sung-Han; Hyun, Jung-Ho; Kim, Ji-Hoon; Torres, Marta; Colwell, Frederick S.

    2013-11-01

    The biogeochemical processes that occur in marine sediments on continental margins are complex; however, from one perspective they can be considered with respect to three geochemical zones based on the presence and form of methane: sulfatemethane transition (SMTZ), gas hydrate stability zone (GHSZ), and free gas zone (FGZ). These geochemical zones may harbor distinct microbial communities that are important in biogeochemical carbon cycles. The objective of this study was to describe the microbial communities in sediments from the SMTZ, GHSZ, and FGZ using molecular ecology methods (i.e. PhyloChip microarray analysis and terminal restriction fragment length polymorphism (T-RFLP)) and examining the results in the context of non-biological parameters in the sediments. Non-metric multidimensional scaling and multi-response permutation procedures were used to determine whether microbial community compositions were significantly different in the three geochemical zones and to correlate samples with abiotic characteristics of the sediments. This analysis indicated that microbial communities from all three zones were distinct from one another and that variables such as sulfate concentration, hydrate saturation of the nearest gas hydrate layer, and depth (or unmeasured variables associated with depth e.g. temperature, pressure) were correlated to differences between the three zones. The archaeal anaerobic methanotrophs typically attributed to performing anaerobic oxidation of methane were not detected in the SMTZ; however, the marine benthic group-B, which is often found in SMTZ, was detected. Within the GHSZ, samples that were typically closer to layers that contained higher hydrate saturation had indicator sequences related to Vibrio-type taxa. These results suggest that the biogeographic patterns of microbial communities in marine sediments are distinct based on geochemical zones defined by methane.

  6. Geographical features of global water cycle during warm geological epochs

    SciTech Connect (OSTI)

    Georgiadi, A.G.

    1996-12-31

    The impact of global warming on the water cycle can be extremely complex and diverse. The goal of the investigation was to estimate the geographic features of the mean annual water budget of the world during climatic optimums of the Holocene and the Eemian interglacial periods. These geological epochs could be used as analogs of climatic warming on 1 degree, centigrade and 2 degrees, centigrade. The author used the results of climatic reconstructions based on a simplified version of a GCM.

  7. Geologic and Environmental Probe System - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Technologies Industrial Technologies Energy Analysis Energy Analysis Find More Like This Return to Search Geologic and Environmental Probe System (GEOPS) Idaho National Laboratory Contact INL About This Technology Publications: PDF Document Publication Technology Fact Sheet (144 KB) Installing an instrument in the probe casing is safe and easy. Installing an instrument in the probe casing is safe and easy. Technology Marketing Summary Migration of contaminants from buried waste sites

  8. Hedberg Research Conference on Fundamental Controls on Flow in Carbonates: Request for Travel Support for Post-Doctoral Fellows

    SciTech Connect (OSTI)

    Pyrak-Nolte, Laura J.

    2013-04-28

    Carbonate reservoirs pose a scientific and engineering challenge to geophysical prediction and monitoring of fluid flow in the subsurface. Difficulties in interpreting hydrological, reservoir and other exploration data arise because carbonates are composed of a hierarchy of geological structures, constituents and processes that span a wide spectrum of length and time scales. What makes this problem particularly challenging is that length scales associated with physical structure and processes are often not discrete, but overlap, preventing the definition of discrete elements at one scale to become the building blocks of the next scale. This is particularly true for carbonates where complicated depositional environments, subsequent post-deposition diagenesis and geochemical interactions result in pores that vary in scale from submicron to centimeters to fractures, variation in fabric composition with fossils, minerals and cement, as well as variations in structural features (e.g., oriented inter- and intra layered - interlaced bedding and/or discontinuous rock units). In addition, this complexity is altered by natural and anthropogenic processes such as changes in stress, fluid content, reactive fluid flow, etc. Thus an accurate geophysical assessment of the flow behavior of carbonate reservoirs requires a fundamental understanding of the interplay of textural and structural features subjected to physical processes that affect and occur on various length and time scales. To address this complexity related to carbonates, a Hedberg conference on “Fundamental Controls on Flow in Carbonates” was held July 8 to 13, 2012, to bring together industry and academic scientists to stimulate innovative ideas that can accelerate research advances related to flow prediction and recovery in carbonate reservoirs. Participants included scientist and engineers from multiple disciplines (such as hydrology, structural geology, geochemistry, reservoir engineering, geophysics, geomechanics, numerical modeling, physical experiments, sedimentology, well-testing, statistics, mathematics, visualization, etc.) who encompass experience as well as the latest advances in these multi-faceted fields. One of the goals was to include early career scientists and engineers (post-doctoral fellows, assistant professors, etc.). With this grant 10 early career scientists and engineers were supported to attend the conference. This reports contains a brief overview of the conference and the list of support participants supported by this grant. Full details of the outcomes of the conference are given in the publication found in the Attachment section of this report.

  9. Global Sampling for Integrating Physics-Specific Subsystems and Quantifying Uncertainties of CO2 Geological Sequestration

    SciTech Connect (OSTI)

    Sun, Y.; Tong, C.; Trainor-Guitten, W. J.; Lu, C.; Mansoor, K.; Carroll, S. A.

    2012-12-20

    The risk of CO2 leakage from a deep storage reservoir into a shallow aquifer through a fault is assessed and studied using physics-specific computer models. The hypothetical CO2 geological sequestration system is composed of three subsystems: a deep storage reservoir, a fault in caprock, and a shallow aquifer, which are modeled respectively by considering sub-domain-specific physics. Supercritical CO2 is injected into the reservoir subsystem with uncertain permeabilities of reservoir, caprock, and aquifer, uncertain fault location, and injection rate (as a decision variable). The simulated pressure and CO2/brine saturation are connected to the fault-leakage model as a boundary condition. CO2 and brine fluxes from the fault-leakage model at the fault outlet are then imposed in the aquifer model as a source term. Moreover, uncertainties are propagated from the deep reservoir model, to the fault-leakage model, and eventually to the geochemical model in the shallow aquifer, thus contributing to risk profiles. To quantify the uncertainties and assess leakage-relevant risk, we propose a global sampling-based method to allocate sub-dimensions of uncertain parameters to sub-models. The risk profiles are defined and related to CO2 plume development for pH value and total dissolved solids (TDS) below the EPA's Maximum Contaminant Levels (MCL) for drinking water quality. A global sensitivity analysis is conducted to select the most sensitive parameters to the risk profiles. The resulting uncertainty of pH- and TDS-defined aquifer volume, which is impacted by CO2 and brine leakage, mainly results from the uncertainty of fault permeability. Subsequently, high-resolution, reduced-order models of risk profiles are developed as functions of all the decision variables and uncertain parameters in all three subsystems.

  10. Summaries of physical research in the geosciences

    SciTech Connect (OSTI)

    Not Available

    1987-09-01

    The Department of Energy supports research in the geosciences in order to provide a sound foundation of fundamental knowledge in those areas that are germane to the Department of Energy's many missions. The summaries in this document, prepared by the investigators, describe the scope of the individual programs. The Geoscience Research Program includes research in geology, petrology, geophysics, geochemistry, solar-terrestrial relationships, aeronomy, seismology, and natural resource analysis, including their various subdivisions and interdisciplinary areas. All such research is related either directly or indirectly to the Department of Energy's technological needs.

  11. Summaries of physical research in the geosciences

    SciTech Connect (OSTI)

    Not Available

    1981-10-01

    The Department of Energy supports research in the geosciences in order to provide a sound foundation of fundamental knowledge in those areas of earth, atmospheric, and solar-terrestrial sciences that are germane to the Department of Energy's many missions. The summaries describe the scope of the individual programs and detail the research performed during 1980 to 1981. The Geosciences Research Program includes research in geology, petrology, geophysics, geochemistry, hydrology, solar-terrestrial relationships, aeronomy, seismology, and natural resource analysis, including the various subdivisions and interdisciplinary areas.

  12. Geologic and geotechnical assessment RFETS Building 371, Rocky Flats, Colorado

    SciTech Connect (OSTI)

    Maryak, M.E.; Wyatt, D.E.; Bartlett, S.F.; Lewis, M.R.; Lee, R.C.

    1995-12-13

    This report describes the review and evaluation of the geological, geotechnical and geophysical data supporting the design basis analysis for the Rocky Flats Environmental Test Site (RFETS) Building 371. The primary purpose of the geologic and geotechnical reviews and assessments described herein are to assess the adequacy of the crustal and near surface rock and soil model used in the seismic analysis of Building 371. This review was requested by the RFETS Seismic Evaluation Program. The purpose was to determine the adequacy of data to support the design basis for Building 371, with respect to seismic loading. The objectives required to meet this goal were to: (1) review techniques used to gather data (2) review analysis and interpretations of the data; and (3) make recommendations to gather additional data if required. Where there were questions or inadequacies in data or interpretation, recommendations were made for new data that will support the design basis analysis and operation of Building 371. In addition, recommendations are provided for a geologic and geophysical assessment for a new facility at the Rocky Flats Site.

  13. An Overview of Geologic Carbon Sequestration Potential in California

    SciTech Connect (OSTI)

    Cameron Downey; John Clinkenbeard

    2005-10-01

    As part of the West Coast Regional Carbon Sequestration Partnership (WESTCARB), the California Geological Survey (CGS) conducted an assessment of geologic carbon sequestration potential in California. An inventory of sedimentary basins was screened for preliminary suitability for carbon sequestration. Criteria included porous and permeable strata, seals, and depth sufficient for critical state carbon dioxide (CO{sub 2}) injection. Of 104 basins inventoried, 27 met the criteria for further assessment. Petrophysical and fluid data from oil and gas reservoirs was used to characterize both saline aquifers and hydrocarbon reservoirs. Where available, well log or geophysical information was used to prepare basin-wide maps showing depth-to-basement and gross sand distribution. California's Cenozoic marine basins were determined to possess the most potential for geologic sequestration. These basins contain thick sedimentary sections, multiple saline aquifers and oil and gas reservoirs, widespread shale seals, and significant petrophysical data from oil and gas operations. Potential sequestration areas include the San Joaquin, Sacramento, Ventura, Los Angeles, and Eel River basins, followed by the smaller Salinas, La Honda, Cuyama, Livermore, Orinda, and Sonoma marine basins. California's terrestrial basins are generally too shallow for carbon sequestration. However, the Salton Trough and several smaller basins may offer opportunities for localized carbon sequestration.

  14. A Catalog of Geologic Data for the Hanford Site

    SciTech Connect (OSTI)

    Horton, Duane G.; Last, George V.; Gilmore, Tyler J.; Bjornstad, Bruce N.

    2002-09-30

    This is the first update of the catalog that was published in 2001. This report catalogs the existing geologic data that can be found in various databases, published and unpublished reports, and in individuals' technical files. The scope of this catalog is primarily on the 100, 200, and 300 Areas, with a particular emphasis on the 200 Areas. Over 2,922 wells are included in the catalog. Nearly all of these wells (2,459) have some form of driller's or geologist's log. Archived samples are available for 1,742 wells. Particle size data are available from 1,078 wells and moisture data are available from 356 wells. Some form of chemical property data is available from 588 wells. However, this catalog is by no means complete. Numerous individuals have been involved in various geologic-related studies of the Hanford Site. The true extent of unpublished data retained in their technical files is unknown. However, this data catalog is believed to represent the majority (>90%) of the geologic data that is currently retrievable.

  15. A Catalog of Geologic Data for the Hanford Site

    SciTech Connect (OSTI)

    Horton, Duane G.; Last, George V.; Gilmore, Tyler J.; Bjornstad, Bruce N.

    2001-09-19

    This report catalogs the existing geologic data that can be found in various databases, published and unpublished reports, and in individuals' technical files. The scope of this catalog is primarily on the 100, 200, and 300 Areas, with a particular emphasis on the 200 Areas. Over 2,922 wells are included in the catalog. Nearly all of these wells (2,459) have some form of driller's or geologist's log. Archived samples are available for 1,742 wells. Particle size data are available from 1,078 wells and moisture data are available from 356 wells. Some form of chemical property data is available from 588 wells. However, this catalog is by no means complete. Numerous individuals have been involved in various geologic-related studies of the Hanford Site. The true extent of unpublished data retained in their technical files is unknown. However, this data catalog is believed to represent the majority (>90%) of the geologic data that is currently retrievable.

  16. Research Highlights

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Highlights Form Submit a New Research Highlight Sort Highlights Submitter Title Research Area Working Group Submission Date DOE Progress Reports Notable Research Findings for 2001-2006 Office of Science Abstracts Database Research Highlights Summaries Research Highlights Members of ARM's science team are major contributors to radiation and cloud research. ARM investigators publish about 150 refereed journal articles per year, and ARM data are used in many studies published by other scientific

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rotstayn, L., Commonwealth Scientific and Industrial Research Organization Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: Rotstayn, L.,...

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chinese Researchers Report Reliable Method for Monitoring Soil Moisture Submitter: Bhattacharya, A., Pacific Northwest National Laboratory Area of Research: Surface Properties...

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Testing and Comparing the Modified Anomalous Diffraction Approximation Submitter: Mitchell, D. L., Desert Research Institute Area of Research: Cloud DistributionsCharacterizations...

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a printable PDF Submitter: Schmid, B., Pacific Northwest National Laboratory Area of Research: Aerosol Properties Working Group(s): Aerosol Journal Reference: ARM Climate Research...

  1. Research Projects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Current Research Projects Joint Los Alamos National LaboratoryUCSD Research Projects Collaborations between Los Alamos National Laboratory and the University of California at San...

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Ensemble Simulation with the ARM IOP Data Submitter: Xu, K., NASA - Langley Research Center Area of Research: General Circulation and Single Column ModelsParameterizations ...

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM Measurements Validate New Satellite Multilayer Cloud Remote Sensing Method Submitter: Minnis, P., NASA - Langley Research Center Area of Research: Cloud Distributions...

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Terrestrial Radiation Download a printable PDF Submitter: Mitchell, D. L., Desert Research Institute Area of Research: General Circulation and Single Column Models...

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fog and Rain in the Amazon For original submission and image(s), see ARM Research Highlights http:www.arm.govsciencehighlights Research Highlight The diurnal and seasonal...

  6. Developing a robust geochemical and reactive transport model to evaluate possible sources of arsenic at the CO[subscript 2] sequestration natural analog site in Chimayo, New Mexico

    SciTech Connect (OSTI)

    Viswanathan, Hari; Dai, Zhenxue; Lopano, Christina; Keating, Elizabeth; Hakala, J. Alexandra; Scheckel, Kirk G.; Zheng, Liange; Gutherie, George D.; Pawar, Rajesh

    2012-10-24

    Migration of carbon dioxide (CO{sub 2}) from deep storage formations into shallow drinking water aquifers is a possible system failure related to geologic CO{sub 2} sequestration. A CO{sub 2} leak may cause mineral precipitation/dissolution reactions, changes in aqueous speciation, and alteration of pH and redox conditions leading to potential increases of trace metal concentrations above EPA National Primary Drinking Water Standards. In this study, the Chimayo site (NM) was examined for site-specific impacts of shallow groundwater interacting with CO{sub 2} from deep storage formations. Major ion and trace element chemistry for the site have been previously studied. This work focuses on arsenic (As), which is regulated by the EPA under the Safe Drinking Water Act and for which some wells in the Chimayo area have concentrations higher than the maximum contaminant level (MCL). Statistical analysis of the existing Chimayo groundwater data indicates that As is strongly correlated with trace metals U and Pb indicating that their source may be from the same deep subsurface water. Batch experiments and materials characterization, such as: X-ray diffraction (XRD), scanning electron microscopy (SEM), and synchrotron micro X-ray fluorescence ({mu}-XRF), were used to identify As association with Fe-rich phases, such as clays or oxides, in the Chimayo sediments as the major factor controlling As fate in the subsurface. Batch laboratory experiments with Chimayo sediments and groundwater show that pH decreases as CO{sub 2} is introduced into the system and buffered by calcite. The introduction of CO{sub 2} causes an immediate increase in As solution concentration, which then decreases over time. A geochemical model was developed to simulate these batch experiments and successfully predicted the pH drop once CO{sub 2} was introduced into the experiment. In the model, sorption of As to illite, kaolinite and smectite through surface complexation proved to be the key reactions in simulating the drop in As concentration as a function of time in the batch experiments. Based on modeling, kaolinite precipitation is anticipated to occur during the experiment, which allows for additional sorption sites to form with time resulting in the slow decrease in As concentration. This mechanism can be viewed as trace metal 'scavenging' due to sorption caused secondary mineral precipitation. Since deep geologic transport of these trace metals to the shallow subsurface by brine or CO{sub 2} intrusion is critical to assessing environmental impacts, the effective retardation of trace metal transport is an important parameter to estimate and it is dependent on multiple coupled reactions. At the field scale, As mobility is retarded due to the influence of sorption reactions, which can affect environmental performance assessment studies of a sequestration site.

  7. Biologically Enhanced Carbon Sequestration: Research Needs and Opportunities

    SciTech Connect (OSTI)

    Oldenburg, Curtis; Oldenburg, Curtis M.; Torn, Margaret S.

    2008-03-21

    Fossil fuel combustion, deforestation, and biomass burning are the dominant contributors to increasing atmospheric carbon dioxide (CO{sub 2}) concentrations and global warming. Many approaches to mitigating CO{sub 2} emissions are being pursued, and among the most promising are terrestrial and geologic carbon sequestration. Recent advances in ecology and microbial biology offer promising new possibilities for enhancing terrestrial and geologic carbon sequestration. A workshop was held October 29, 2007, at Lawrence Berkeley National Laboratory (LBNL) on Biologically Enhanced Carbon Sequestration (BECS). The workshop participants (approximately 30 scientists from California, Illinois, Oregon, Montana, and New Mexico) developed a prioritized list of research needed to make progress in the development of biological enhancements to improve terrestrial and geologic carbon sequestration. The workshop participants also identified a number of areas of supporting science that are critical to making progress in the fundamental research areas. The purpose of this position paper is to summarize and elaborate upon the findings of the workshop. The paper considers terrestrial and geologic carbon sequestration separately. First, we present a summary in outline form of the research roadmaps for terrestrial and geologic BECS. This outline is elaborated upon in the narrative sections that follow. The narrative sections start with the focused research priorities in each area followed by critical supporting science for biological enhancements as prioritized during the workshop. Finally, Table 1 summarizes the potential significance or 'materiality' of advances in these areas for reducing net greenhouse gas emissions.

  8. Basic geological and analytical properties of selected coal seams for coal interface detection. Information circular/1993

    SciTech Connect (OSTI)

    Maksimovic, S.; Mowrey, G.L.

    1993-01-01

    One important element of the U.S. Bureau of Mines computer-assisted mining research program is the development of a reliable coal interface detection (CID) system. Several candidate CID concepts currently being investigated by the Bureau include use of natural gamma radiation (NGR), vibration, passive infrared, video, and radar. To help establish which CID sensor technologies need to be developed for a given seam, the Bureau has collected geological and mining practices data from over 460 underground and surface mines in the United States. Also, over 500 coal and rock samples have been obtained for laboratory analyses of ash content, sulfur content, heating value, and NGR. The Bureau's findings indicate that the immediate roof strata in 81 percent of the underground mines and 93 percent of the surface mines are made up of shale, draw slate, or claystone. The immediate floor strata in 88 percent of both the underground and surface mines consist of fireclay, shale, draw slate, or claystone.

  9. Research Mission

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Mission Research Mission NETL's Office of Research & Development is a national resource for fossil energy research and development, with a mission to create and expand the knowledge base that enables the safe, sustainable utilization of our abundant, domestic energy resources. In support of that mission, the onsite research effort: Develops solutions to key barriers to the implementation of emerging energy technologies. Explores transformational new concepts for next generation

  10. Geochemical Data Package for the 2005 Hanford Integrated Disposal Facility Performance Assessment

    SciTech Connect (OSTI)

    Krupka, Kenneth M.; Serne, R JEFFREY.; Kaplan, D I.

    2004-09-30

    CH2M HILL Hanford Group, Inc. (CH2M HILL) is designing and assessing the performance of an integrated disposal facility (IDF) to receive low-level waste (LLW), mixed low-level waste (MLLW), immobilized low-activity waste (ILAW), and failed or decommissioned melters. The CH2M HILL project to assess the performance of this disposal facility is the Hanford IDF Performance Assessment (PA) activity. The goal of the Hanford IDF PA activity is to provide a reasonable expectation that the disposal of the waste is protective of the general public, groundwater resources, air resources, surface-water resources, and inadvertent intruders. Achieving this goal will require prediction of contaminant migration from the facilities. This migration is expected to occur primarily via the movement of water through the facilities, and the consequent transport of dissolved contaminants in the vadose zone to groundwater where contaminants may be re-introduced to receptors via drinking water wells or mixing in the Columbia River. Pacific Northwest National Laboratory (PNNL) assists CH2M HILL in their performance assessment activities. One of the PNNL tasks is to provide estimates of the geochemical properties of the materials comprising the IDF, the disturbed region around the facility, and the physically undisturbed sediments below the facility (including the vadose zone sediments and the aquifer sediments in the upper unconfined aquifer). The geochemical properties are expressed as parameters that quantify the adsorption of contaminants and the solubility constraints that might apply for those contaminants that may exceed solubility constraints. The common parameters used to quantify adsorption and solubility are the distribution coefficient (Kd) and the thermodynamic solubility product (Ksp), respectively. In this data package, we approximate the solubility of contaminants using a more simplified construct, called the solution concentration limit, a constant value. The Kd values and solution concentration limits for each contaminant are direct inputs to subsurface flow and transport codes used to predict the performance of the IDF system. In addition to the best-estimate Kd values, a reasonable conservative value and a range are provided. The data package does not list estimates for the range in solubility limits or their uncertainty. However, the data package does provide different values for both the Kd values and solution concentration limits for different spatial zones in the IDF system and does supply time-varying Kd values for the cement solidified waste. The Kd values and solution concentration limits presented for each contaminant were previously presented in a report prepared by Kaplan and Serne (2000) for the 2001 ILAW PA, and have been updated to include applicable data from investigations completed since the issuance of that report and improvements in our understanding of the geochemistry specific to Hanford. A discussion is also included of the evolution of the Kd values recommended from the original 1999 ILAW PA through the 2001 ILAW and 2003 Supplement PAs to the current values to be used for the 2005 IDF PA for the key contaminants of concern: Cr(VI), nitrate, 129I, 79Se, 99Tc, and U(VI). This discussion provides the rationale for why certain Kd have changed with time.

  11. Geochemical engineering design tools for uranium in situ recovery : the HYDROGEOCHEM codes.

    SciTech Connect (OSTI)

    Siegel, Malcolm Dean; Li, Ming-Hsu; Yeh, Gour-Tsyh

    2010-11-01

    Geochemical Engineering Design (GED) is based on applications of the principles and various computer models that describe the biogeochemistry and physics of removal of contaminants from water by adsorption, precipitation and filtration. It can be used to optimize or evaluate the efficiency of all phases of in situ recovery (ISR). The primary tools of GED are reactive transport models; this talk describes the potential application of the HYDROGEOCHEM family of codes to ISR. The codes can describe a complete suite of equilibrium or kinetic aqueous complexation, adsorption-desorption, precipitation-dissolution, redox, and acid-base reactions in variably saturated media with density-dependent fluid flow. Applications to ISR are illustrated with simulations of (1) the effectiveness of a reactive barrier to prevent off-site uranium migration and (2) evaluation of the effect of sorption hysteresis on natural attenuation. In the first example, it can be seen that the apparent effectiveness of the barrier depends on monitoring location and that it changes over time. This is due to changes in pH, saturation of sorption sites, as well as the geometry of the flow field. The second simulation shows how sorption hysteresis leads to observable attenuation of a uranium contamination plume. Different sorption mechanisms including fast (or reversible), slow, and irreversible sorption were simulated. The migration of the dissolved and total uranium plumes for the different cases are compared and the simulations show that when 50-100% of the sites have slow desorption rates, the center of mass of the dissolved uranium plume begins to move upstream. This would correspond to the case in which the plume boundaries begin to shrink as required for demonstration of natural attenuation.

  12. Model-Based Analysis of the Role of Biological, Hydrological and Geochemical Factors Affecting Uranium Bioremediation

    SciTech Connect (OSTI)

    Zhao, Jiao; Scheibe, Timothy D.; Mahadevan, Radhakrishnan

    2011-01-24

    Uranium contamination is a serious concern at several sites motivating the development of novel treatment strategies such as the Geobacter-mediated reductive immobilization of uranium. However, this bioremediation strategy has not yet been optimized for the sustained uranium removal. While several reactive-transport models have been developed to represent Geobacter-mediated bioremediation of uranium, these models often lack the detailed quantitative description of the microbial process (e.g., biomass build-up in both groundwater and sediments, electron transport system, etc.) and the interaction between biogeochemical and hydrological process. In this study, a novel multi-scale model was developed by integrating our recent model on electron capacitance of Geobacter (Zhao et al., 2010) with a comprehensive simulator of coupled fluid flow, hydrologic transport, heat transfer, and biogeochemical reactions. This mechanistic reactive-transport model accurately reproduces the experimental data for the bioremediation of uranium with acetate amendment. We subsequently performed global sensitivity analysis with the reactive-transport model in order to identify the main sources of prediction uncertainty caused by synergistic effects of biological, geochemical, and hydrological processes. The proposed approach successfully captured significant contributing factors across time and space, thereby improving the structure and parameterization of the comprehensive reactive-transport model. The global sensitivity analysis also provides a potentially useful tool to evaluate uranium bioremediation strategy. The simulations suggest that under difficult environments (e.g., highly contaminated with U(VI) at a high migration rate of solutes), the efficiency of uranium removal can be improved by adding Geobacter species to the contaminated site (bioaugmentation) in conjunction with the addition of electron donor (biostimulation). The simulations also highlight the interactive effect of initial cell concentration and flow rate on U(VI) reduction.

  13. Scaling Effects of Cr(VI) Reduction Kinetics. The Role of Geochemical Heterogeneity

    SciTech Connect (OSTI)

    Wang, Li; Li, Li

    2015-10-22

    The natural subsurface is highly heterogeneous with minerals distributed in different spatial patterns. Fundamental understanding of how mineral spatial distribution patterns regulate sorption process is important for predicting the transport and fate of chemicals. Existing studies about the sorption was carried out in well-mixed batch reactors or uniformly packed columns, with few data available on the effects of spatial heterogeneities. As a result, there is a lack of data and understanding on how spatial heterogeneities control sorption processes. In this project, we aim to understand and develop modeling capabilities to predict the sorption of Cr(VI), an omnipresent contaminant in natural systems due to its natural occurrence and industrial utilization. We systematically examine the role of spatial patterns of illite, a common clay, in determining the extent of transport limitation and scaling effects associated with Cr(VI) sorption capacity and kinetics using column experiments and reactive transport modeling. Our results showed that the sorbed mass and rates can differ by an order of magnitude due to of the illite spatial heterogeneities and transport limitation. With constraints from data, we also developed the capabilities of modeling Cr(VI) in heterogeneous media. The developed model is then utilized to understand the general principles that govern the relationship between sorption and connectivity, a key measure of the spatial pattern characteristics. This correlation can be used to estimate Cr(VI) sorption characteristics in heterogeneous porous media. Insights gained here bridge gaps between laboratory and field application in hydrogeology and geochemical field, and advance predictive understanding of reactive transport processes in the natural heterogeneous subsurface. We believe that these findings will be of interest to a large number of environmental geochemists and engineers, hydrogeologists, and those interested in contaminant fate and transport, water quality and water composition, and natural attenuation processes in natural systems.

  14. Characterizing Microbial Community and Geochemical Dynamics at Hydrothermal Vents Using Osmotically Driven Continuous Fluid Samplers

    SciTech Connect (OSTI)

    Robidart, Julie C.; Callister, Stephen J.; Song, Peng F.; Nicora, Carrie D.; Wheat, Charles G.; Girguis, Peter R.

    2013-05-07

    Microbes play a key role in mediating all aquatic biogeochemical cycles, and ongoing efforts are aimed at better understanding the relationships between microbial phylogenetic and physiological diversity, and habitat physical and chemical characteristics. Establishing such relationships is facilitated by sampling and studying microbiology and geochemistry at the appropriate spatial and temporal scales, to access information on the past and current environmental state that contributes to observed microbial abundances and activities. A modest number of sampling systems exist to date, few of which can be used in remote, harsh environments such as hydrothermal vents, where the ephemeral nature of venting underscores the necessity for higher resolution sampling. We have developed a robust, continuous fluid sampling system for co-registered microbial and biogeochemical analyses. The osmosis-powered bio-osmosampling system (BOSS) use no electricity, collects fluids with daily resolution or better, can be deployed in harsh, inaccessible environments and can sample fluids continuously for up to five years. Here we present a series of tests to examine DNA, RNA and protein stability over time, as well as material compatability, via lab experiments. We also conducted two field deployments at deep-sea hydrothermal vents to assess changes in microbial diversity and protein expression as a function of the physico-chemical environment. Our data reveal significant changes in microbial community composition co-occurring with relatively modest changes in the geochemistry. These data additionally provide new insights into the distribution of an enigmatic sulfur oxidizing symbiont in its free-living state. Data from the second deployment reveal differences in the representation of peptides over time, underscoring the utility of the BOSS in meta-proteomic studies. In concert, these data demonstrate the efficacy of this approach, and illustrate the value of using this method to study microbial and geochemical phenomena.

  15. Geochemical Evidence of the Seasonality, Affinity and Pigmenation of Solenopora jurassica

    SciTech Connect (OSTI)

    Barden, Holly E.; Behnsen, Julia; Bergmann, Uwe; Leng, Melanie J.; Manning, Phillip L.; Withers, Philip J.; Wogelius, Roy A.; van Dongen, Bart E.; Silva, Lucas C. R.

    2015-09-14

    Solenopora jurassica is a fossil calcareous alga that functioned as an important reef-building organism during the Palaeozoic. It is of significant palaeobiological interest due to its distinctive but poorly understood pink and white banding. Though widely accepted as an alga there is still debate over its taxonomic affinity, with recent work arguing that it should be reclassified as a chaetetid sponge. The banding is thought to be seasonal, but there is no conclusive evidence for this. Other recent work has, however demonstrated the presence of a unique organic boron-containing pink/red pigment in the pink bands of S. jurassica. We present new geochemical evidence concerning the seasonality and pigmentation of S. jurassica. Seasonal growth cycles are demonstrated by X-ray radiography, which shows differences in calcite density, and by varying δ13C composition of the bands. Temperature variation in the bands is difficult to constrain accurately due to conflicting patterns arising from Mg/Ca molar ratios and δ18O data. Fluctuating chlorine levels indicate increased salinity in the white bands, when combined with the isotope data this suggests more suggestive of marine conditions during formation of the white band and a greater freshwater component (lower chlorinity) during pink band precipitation (δ18O). Increased photosynthesis is inferred within the pink bands in comparison to the white, based on δ13C. Pyrolysis Gas Chromatography Mass Spectrometry (Py-GCMS) and Fourier Transform Infrared Spectroscopy (FTIR) show the presence of tetramethyl pyrrole, protein moieties and carboxylic acid groups, suggestive of the presence of the red algal pigment phycoerythrin. This is consistent with the pink colour of S. jurassica. As phycoerythrin is only known to occur in algae and cyanobacteria, and no biomarker evidence of bacteria or sponges was detected we conclude S. jurassica is most likely an alga. Pigment analysis may be a reliable classification method for fossil algae.

  16. Geochemical Evidence of the Seasonality, Affinity and Pigmenation of Solenopora jurassica

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Barden, Holly E.; Behnsen, Julia; Bergmann, Uwe; Leng, Melanie J.; Manning, Phillip L.; Withers, Philip J.; Wogelius, Roy A.; van Dongen, Bart E.; Silva, Lucas C. R.

    2015-09-14

    Solenopora jurassica is a fossil calcareous alga that functioned as an important reef-building organism during the Palaeozoic. It is of significant palaeobiological interest due to its distinctive but poorly understood pink and white banding. Though widely accepted as an alga there is still debate over its taxonomic affinity, with recent work arguing that it should be reclassified as a chaetetid sponge. The banding is thought to be seasonal, but there is no conclusive evidence for this. Other recent work has, however demonstrated the presence of a unique organic boron-containing pink/red pigment in the pink bands of S. jurassica. We presentmore » new geochemical evidence concerning the seasonality and pigmentation of S. jurassica. Seasonal growth cycles are demonstrated by X-ray radiography, which shows differences in calcite density, and by varying δ13C composition of the bands. Temperature variation in the bands is difficult to constrain accurately due to conflicting patterns arising from Mg/Ca molar ratios and δ18O data. Fluctuating chlorine levels indicate increased salinity in the white bands, when combined with the isotope data this suggests more suggestive of marine conditions during formation of the white band and a greater freshwater component (lower chlorinity) during pink band precipitation (δ18O). Increased photosynthesis is inferred within the pink bands in comparison to the white, based on δ13C. Pyrolysis Gas Chromatography Mass Spectrometry (Py-GCMS) and Fourier Transform Infrared Spectroscopy (FTIR) show the presence of tetramethyl pyrrole, protein moieties and carboxylic acid groups, suggestive of the presence of the red algal pigment phycoerythrin. This is consistent with the pink colour of S. jurassica. As phycoerythrin is only known to occur in algae and cyanobacteria, and no biomarker evidence of bacteria or sponges was detected we conclude S. jurassica is most likely an alga. Pigment analysis may be a reliable classification method for fossil algae.« less

  17. Geochemical information for sites contaminated with low-level radioactive wastes. III. Weldon Spring Storage Site

    SciTech Connect (OSTI)

    Seeley, F.G.; Kelmers, A.D.

    1985-02-01

    The Weldon Spring Storage Site (WSSS), which includes both the chemical site and the quarry, became radioactively contaminated as the result of wastes that were being stored from operations to recover uranium from pitchblende ores in the 1940s and 1950s. The US Department of Energy (DOE) is considering various remedial action options for the WSSS. This report describes the results of geochemical investigations carried out at Oak Ridge National Laboratory (ORNL) to support these activities and to help quantify various remedial action options. Soil and groundwater samples were characterized, and uranium and radium sorption ratios were measured in site soil/groundwater systems by batch contact methodology. Soil samples from various locations around the raffinate pits were found to contain major amounts of silica, along with illite as the primary clay constituent. Particle sizes of the five soil samples were variable (50% distribution point ranging from 12 to 81 ..mu..m); the surface areas varied from 13 to 62 m/sup 2//g. Elemental analysis of the samples showed them to be typical of sandy clay and silty clay soils. Groundwater samples included solution from Pit 3 and well water from Well D. Anion analyses showed significant concentrations of sulfate and nitrate (>350 and >7000 mg/L, respectively) in the solution from Pit 3. These anions were also present in the well water, but in lower concentrations. Uranium sorption ratios for four of the soil samples contacted with the solution from Pit 3 were moderate to high (approx. 300 to approx. 1000 mL/g). The fifth sample had a ratio of only 12 mL/g. Radium sorption ratios for the five samples were moderate to high (approx. 600 to approx. 1000 mL/g). These values indicate that soil at the WSSS may show favorable retardation of uranium and radium in the groundwater. 13 references, 13 figures, 10 tables.

  18. Sandia National Laboratories: Research: Research Foundations: Geoscience:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Project: Geochemistry of Interfaces Geochemistry of Interfaces From surfaces to interlayers to clusters A geoscience project under Sandia's Energy, Climate, & Infrastructure Security mission area. Problem Molecular phenomena at the metal oxide-water interface control many geochemical and environmental processes critical to water quality and treatment, the fate and transport of contaminants, radionuclide isolation and waste forms, carbon capture and sequestration, resource extraction, and

  19. Application of neutron-activation analysis to geological materials

    SciTech Connect (OSTI)

    Laul, J.C.; Wogman, N.A.

    1980-12-01

    Neutron activation analysis (NAA) is an extremely sensitive, selective, and precise method, which yields a wealth of elemental information from even a small-sized sample. By varying neutron fluxes, irradiation times, decay and counting intervals in instrumental NAA, it is possible to accurately determine about 35 elements in a geological aliquot. When INAA is coupled with coincidence-noncoincidence Ge(Li)-Na(Tl) counting, it enhances the sensitivities of various elements by order of magnitude. The attractive features of INAA are that it is fast, nondestructive and economical.

  20. Final Supplemental Environmental Impact Statement for a Geologic Repository

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for the Disposal of Spent Nuclear Fuel and High-Level Radioactive Waste at Yucca Mountain, Nye County, Nevada - Nevada Rail Transportation Corridor DOE/EIS-0250F-S2 and Final En | Department of Energy Final Supplemental Environmental Impact Statement for a Geologic Repository for the Disposal of Spent Nuclear Fuel and High-Level Radioactive Waste at Yucca Mountain, Nye County, Nevada - Nevada Rail Transportation Corridor DOE/EIS-0250F-S2 and Final En Final Supplemental Environmental Impact

  1. Monitored Geologic Repository Life Cycle Cost Estimate Assumptions Document

    SciTech Connect (OSTI)

    R. Sweeney

    2000-03-08

    The purpose of this assumptions document is to provide general scope, strategy, technical basis, schedule and cost assumptions for the Monitored Geologic Repository (MGR) life cycle cost estimate and schedule update incorporating information from the Viability Assessment (VA), License Application Design Selection (LADS), 1999 Update to the Total System Life Cycle Cost (TSLCC) estimate and from other related and updated information. This document is intended to generally follow the assumptions outlined in the previous MGR cost estimates and as further prescribed by DOE guidance.

  2. MONITORED GEOLOGIC REPOSITORY LIFE CYCLE COST ESTIMATE ASSUMPTIONS DOCUMENT

    SciTech Connect (OSTI)

    R.E. Sweeney

    2001-02-08

    The purpose of this assumptions document is to provide general scope, strategy, technical basis, schedule and cost assumptions for the Monitored Geologic Repository (MGR) life cycle cost (LCC) estimate and schedule update incorporating information from the Viability Assessment (VA) , License Application Design Selection (LADS), 1999 Update to the Total System Life Cycle Cost (TSLCC) estimate and from other related and updated information. This document is intended to generally follow the assumptions outlined in the previous MGR cost estimates and as further prescribed by DOE guidance.

  3. COLLOQUIUM: Human Impacts on the Earth's Geologic Carbon Cycle |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Princeton Plasma Physics Lab January 15, 2014, 4:00pm to 5:30pm Colloquia MBG Auditorium COLLOQUIUM: Human Impacts on the Earth's Geologic Carbon Cycle Professor David Archer University of Chicago Abstract: PDF icon COLL.01.15.14.pdf When fossil fuel CO2 is released to the atmosphere, it essentially accumulates in the relatively rapidly cycling atmosphere / ocean / land biosphere carbon cycle. The atmospheric concentration of CO2 spikes through a time period of CO2 emissions, then is

  4. Integrated geologic/engineering study of Kurten field waterflood project

    SciTech Connect (OSTI)

    Gay, A.L.

    1989-03-01

    An integrated interpretation of petrographic, geochemical, engineering, and electric-log data is used to evaluate a current waterflood project in Kurten field, Brazos County, Texas. Petrographic studies reveal three sand facies deposited in a dynamic sand ridge environment. Although electric-log porosity is relatively constant throughout the sand body, SEM, thin-section, and engineering profile studies reveal the clean well-sorted sand facies to be impermeable due to quartz overgrowths. A quartz-rich bioturbated sand is identified as the reservoir facies, having fewer quartz overgrowths and more authigenic clays. The third sand facies, a clay-rich bioturbated sand, is impermeable due to an overabundance of authigenic and detrital clays. Engineering and production data support this interpretation. A comparison of hydrocarbon composition of the oils using capillary gas chromatography supports the conclusion that the well-sorted clean sand contains many permeability barriers and is not a continuous reservoir conductive to waterflooding. Interactive computer interpretation of electric logs, using a combination of sonic and density porosities, deep resistivity, and SP, allows the mapping of the sand facies. Water saturation and net oil-in-place maps reveal the best portions of the field on which to focus the revised waterflood project. This revision should concentrate on the quartz-rich bioturbated sand in the central portion of the original unit to result in a more efficient, economical, secondary recovery program.

  5. Integrated geologic/engineering study of the Kurten Field waterflood

    SciTech Connect (OSTI)

    Gay, A.L. )

    1990-05-01

    An integrated interpretation of petrographic, geochemical, engineering, and electric-log data was used to evaluate a current waterflood project in Kurten field, Brazos County, Texas. Petrographic studies reveal three sand facies deposited in a dynamic sand ridge environment. Although electric-log porosity is relatively constant throughout the sand body, scanning electron microscope thin section and engineering profile studies reveal the clean well-sorted sand facies to be impermeable due to quartz overgrowths. A quartz-rich bioturbated sand is identified as the reservoir facies, having fewer quartz overgrowths and more authigenic clays. The third sand facies, a clay-rich bioturbated sand, is impermeable due to an overabundance of authigenic and detrital clays. Engineering and production data support this interpretation. A comparison of hydrocarbon composition of the oils, using capillary gas chromatography, supports the conclusion that the well-sorted clean sand contains many permeability barriers and is not a continuous reservoir conducive to waterflooding. Interactive computer interpretation of electric logs, using a combination of sonic and density porosities, deep resistivity, and spontaneous potential, allows the mapping of the sand facies. Water saturations and net oil in place maps reveal the best parts of the field on which to focus the revised waterflood project. This revision should concentrate on the quartz-rich bioturbated sand in the central part of the original unit to result in a more efficient economical secondary recovery program.

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SPartICus Submitter: Mishra, S., DOE - SunShot Initiative, AAAS S&T Policy Fellow Mitchell, D. L., Desert Research Institute Area of Research: General Circulation and Single...

  7. Summaries of FY 92 geosciences research

    SciTech Connect (OSTI)

    Not Available

    1992-12-01

    The Department of Energy supports research in the geosciences in order to provide a sound foundation of fundamental knowledge in those areas of the geosciences that are germane to the Department of Energy's many missions. The Division of Engineering and Geosciences, part of the Office of Basic Energy Sciences of the Office of Energy Research, supports the Geosciences Research Program. The participants in this program include Department of Energy laboratories, academic institutions, and other governmental agencies. These activities are formalized by a contract or grant between the Department of Energy and the organization performing the work, providing funds for salaries, equipment, research materials, and overhead. The summaries in this document, prepared by the investigators, describe the scope of the individual programs. The Geosciences Research Program includes research in geophysics, geochemistry, resource evaluation, solar-terrestrial interactions and their subdivisions including Earth dynamics, properties of Earth materials, rock mechanics, underground imaging, rock-fluid interactions, continental scientific drilling, geochemical transport, solar/atmospheric physics, and modeling, with emphasis on the interdisciplinary areas. All such research is related either directly or indirectly to the Department of Energy's long-range technological needs.

  8. Maximizing Storage Rate and Capacity and Insuring the Environmental Integrity of Carbon Dioxide Sequestration in Geological Reservoirs

    SciTech Connect (OSTI)

    L.A. Davis; A.L. Graham; H.W. Parker; J.R. Abbott; M.S. Ingber; A.A. Mammoli; L.A. Mondy; Quanxin Guo; Ahmed Abou-Sayed

    2005-12-07

    Maximizing Storage Rate and Capacity and Insuring the Environmental Integrity of Carbon Dioxide Sequestration in Geological Formations The U.S. and other countries may enter into an agreement that will require a significant reduction in CO2 emissions in the medium to long term. In order to achieve such goals without drastic reductions in fossil fuel usage, CO2 must be removed from the atmosphere and be stored in acceptable reservoirs. The research outlined in this proposal deals with developing a methodology to determine the suitability of a particular geologic formation for the long-term storage of CO2 and technologies for the economical transfer and storage of CO2 in these formations. A novel well-logging technique using nuclear-magnetic resonance (NMR) will be developed to characterize the geologic formation including the integrity and quality of the reservoir seal (cap rock). Well-logging using NMR does not require coring, and hence, can be performed much more quickly and efficiently. The key element in the economical transfer and storage of the CO2 is hydraulic fracturing the formation to achieve greater lateral spreads and higher throughputs of CO2. Transport, compression, and drilling represent the main costs in CO2 sequestration. The combination of well-logging and hydraulic fracturing has the potential of minimizing these costs. It is possible through hydraulic fracturing to reduce the number of injection wells by an order of magnitude. Many issues will be addressed as part of the proposed research to maximize the storage rate and capacity and insure the environmental integrity of CO2 sequestration in geological formations. First, correlations between formation properties and NMR relaxation times will be firmly established. A detailed experimental program will be conducted to determine these correlations. Second, improved hydraulic fracturing models will be developed which are suitable for CO2 sequestration as opposed to enhanced oil recovery (EOR). Although models that simulate the fracturing process exist, they can be significantly improved by extending the models to account for nonsymmetric, nonplanar fractures, coupling the models to more realistic reservoir simulators, and implementing advanced multiphase flow models for the transport of proppant. Third, it may be possible to deviate from current hydraulic fracturing technology by using different proppants (possibly waste materials that need to be disposed of, e.g., asbestos) combined with different hydraulic fracturing carrier fluids (possibly supercritical CO2 itself). Because current technology is mainly aimed at enhanced oil recovery, it may not be ideally suited for the injection and storage of CO2. Finally, advanced concepts such as increasing the injectivity of the fractured geologic formations through acidization with carbonated water will be investigated. Saline formations are located through most of the continental United States. Generally, where saline formations are scarce, oil and gas reservoirs and coal beds abound. By developing the technology outlined here, it will be possible to remove CO2 at the source (power plants, industry) and inject it directly into nearby geological formations, without releasing it into the atmosphere. The goal of the proposed research is to develop a technology capable of sequestering CO2 in geologic formations at a cost of US $10 per ton.

  9. Research Areas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Areas Our Vision National User Facilities Research Areas In Focus Global Solutions ⇒ Navigate Section Our Vision National User Facilities Research Areas In Focus Global Solutions Biosciences The Biosciences Area forges multidisciplinary teams to solve national challenges in energy, environment and health issues; and to advance the engineering of biological systems for sustainable manufacturing. Biosciences Area research is coordinated through three divisions and is enabled by Berkeley

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Thermodynamics Affect Radiative Impact of Deep Convective Cloud Systems Submitter: Jensen, M., Brookhaven National Laboratory Area of Research: Atmospheric...

  11. Research Projects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LaboratoryNational Security Education Center Menu NSEC Educational Programs Los Alamos Dynamics Summer School Science of Signatures Advanced Studies Institute Judicial Science School SHM Data Sets and Software Research Projects Current Projects Past Projects Publications NSEC » Engineering Institute » Research Projects » Joint Los Alamos National Laboratory/UCSD research projects Past Research Projects Previous collaborations between Los Alamos National Laboratory and the University of

  12. Research Facility,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | Department of Energy Research Experience in Carbon Sequestration 2013 Now Accepting Applications Research Experience in Carbon Sequestration 2013 Now Accepting Applications March 12, 2013 - 1:43pm Addthis Washington, DC - Graduate students and early career professionals can gain hands-on field research experience in areas related to carbon capture and storage (CCS) by participating in the Research Experience in Carbon Sequestration (RECS) program. The initiative, supported by DOE's Office

  13. Current Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Current Research The U.S. Department of Transportation (USDOT) has established its only high-performance computing and engineering analysis research facility at Argonne National Laboratory to provide applications support in key areas of applied research and development for the USDOT community. The Transportation Research and Analysis Computing Center (TRACC) features a state-of-the-art massively parallel computer system, advanced scientific visualization capability, high-speed network

  14. Research Library

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LANL Research Library: delivering essential knowledge services for national security sciences since 1947 About the Research Library Mission We deliver agile, responsive knowledge services, connecting people with information, technology and resources. Vision Essential knowledge services for national security sciences. The Research Library provides extensive collections of books, journals, databases, patents and technical reports and offers literature searching, training and outreach services. The

  15. Swords into plowshares: Military geology and national security projects

    SciTech Connect (OSTI)

    Neal, J.T.

    1994-12-31

    Military geology and national security projects are often comparable, achieving their rai-son d`etre in support of national goals, military operations, and/or systems-all for vital national interests. The application of Geoscience to these ends, especially engineering geology, has occurred from pole to pole and included every conceivable environment and natural condition. In the conduct of such projects, the Geosciences have advanced, and vice versa. Desert trafficability, most notably regarding playa surfaces, is both temporary and variable and not a persistent condition as some early authors believed. Playas in Australia, Iran, and the US show that saline efflorescence is removed following surface water dissolution and subsequent deflation, resulting in very hard crusts. Magadiite, a hydrous sodium silicate and possible precursor of bedded chert, was first discovered in North America at Alkali Lake, OR, during a military project. Pleistocene Lake Trinity, a small and mostly buried evaporate basin in the northern Jornada del Muerto, NM, was discovered during exploratory drilling in support of a military test program.

  16. Geological input to reservoir simulation, Champion Field, offshore Brunei

    SciTech Connect (OSTI)

    Carter, R.; Salahudin, S.; Ho, T.C.

    1994-07-01

    Brunei Shell Petroleum's giant Champion field is in a mature stage of development with about 23 yr of production history to date. The field comprises a complex sequence of Miocene shallow marine and deltaic layered clastic reservoirs cut by numerous growth faults. This study was aimed at providing a quantified estimate of the effect of lateral and vertical discontinuities within the I and J reservoirs on the recovery for both depletion drive and in a waterflood, with a view to identifying the optimal method of completing the development of the oil reserves in this area. Geological input to the ECLIPSE simulator was aimed at quantifying two key parameters: (1) STOIIP connected to the well bore and (2) permeability contrast. Connected STOIIP is a function of the domain size of interconnected sand bodies, and this parameter was quantified by the use of detailed sedimentology resulting in sand-body facies maps for each reservoir sublayer. Permeability contrast was quantified by using a wireline-log based algorithm, calibrated against core data, which improved the existing accuracy of permeability estimates in this part of the field. Results of simulation runs illustrate the importance of quantifying geologic heterogeneity and provide valuable information for future field development planning.

  17. World Energy Resources program U. S. Geological Survey

    SciTech Connect (OSTI)

    Masters, C.D.

    1986-05-01

    In 1973, with the OPEC embargo, the US was jarred into the world of insecure energy supplies - a harsh reality considering that throughout much of our history we had sufficient domestic supplies of oil and gas to meet all of our requirements. The US Government's response in 1973 was to assess domestic oil and gas potential, which was found to be substantial but nonetheless short of long-term requirements. Born of the need to become more certain about foreign as well has domestic resources, and working in conjunction with the Foreign Energy Supply Assessment Program of the US Department of Energy, the US Geological Survey undertook a program to develop a technical understanding of the reserves and undiscovered recoverable resources of petroleum in every basin in the world with petroleum potential. The World Energy Resources Program prepared an assessment of ultimate resources of crude oil for the World Petroleum Congress (WPC) in 1983, and a revision and update (including nature gas, crude oil, extra heavy oil, and tar sands) are planned for WPC in 1987. This poster session attempts to engender awareness of our scenario of world ultimate petroleum occurrence and to show some elements of the geology that guided our thinking.

  18. Geologic Analysis of Priority Basins for Exploration and Drilling

    SciTech Connect (OSTI)

    Carroll, H.B.; Reeves, T.K.

    1999-04-27

    There has been a substantial decline in both exploratory drilling and seismic field crew activity in the United States over the last 10 years, due primarily to the declining price of oil. To reverse this trend and to preserve the entrepreneurial independent operator, the U.S. DOE is attempting to encourage hydrocarbon exploration activities in some of the under exploited regions of the United States. This goal is being accomplished by conducting broad regional reviews of potentially prospective areas within the lower 48 states. Data are being collected on selected areas, and studies are being done on a regional scale generally unavailable to the smaller independent. The results of this work will be made available to the public to encourage the undertaking of operations in areas which have been overlooked until this project. Fifteen criteria have been developed for the selection of study areas. Eight regions have been identified where regional geologic analysis will be performed. This report discusses preliminary findings concerning the geology, early tectonic history, structure and potential unconventional source rocks for the Black Mesa basin and South Central states region, the two highest priority study areas.

  19. Geologic evaluation of the Oasis Valley basin, Nye County, Nevada

    SciTech Connect (OSTI)

    Fridrich, C.J.; Minor, S.A.; and Mankinen, E.A.

    2000-01-13

    This report documents the results of a geologic study of the area between the underground-nuclear-explosion testing areas on Pahute Mesa, in the northwesternmost part of the Nevada Test Site, and the springs in Oasis Valley, to the west of the Test Site. The new field data described in this report are also presented in a geologic map that is a companion product(Fridrich and others, 1999) and that covers nine 7.5-minute quadrangles centered on Thirsty Canyon SW, the quadrangle in which most of the Oasis Valley springs are located. At the beginning of this study, published detailed maps were available for 3 of the 9 quadrangles of the study area: namely Thirsty Canyon (O'Connor and others, 1966); Beatty (Maldonado and Hausback, 1990); and Thirsty Canyon SE (Lipman and others, 1966). Maps of the last two of these quadrangles, however, required extensive updating owing to recent advances in understanding of the regional structure and stratigraphy. The new map data are integrated in this re port with new geophysical data for the Oasis Valley area, include gravity, aeromagnetic, and paleomagnetic data (Grauch and others, 1997; written comm., 1999; Mankinen and others, 1999; Hildenbrand and others, 1999; Hudson and others, 1994; Hudson, unpub. data).

  20. Performance assessment implementation plan for the geologic repository program

    SciTech Connect (OSTI)

    1990-01-01

    Performance assessment is a major constituent of the program being conducted in the Civilian Radioactive Waste Management (CRWM) Program of the US Department of Energy (DOE) to develop a geologic repository. Performance assessment is the set of activities needed for quantitative evaluations of repository-system performance to access compliance with regulations and to support the development of the geologic repository. To define the strategy for these evaluations, the DOE has developed this performance assessment strategy plan. This document discusses the need for such a strategy, the objectives and scope of the strategy plan, the relationship of the plan to other program plans. Additionally, it defines performance assessment and describes the roles of performance assessment in this program, discusses concepts and general strategies needed for performance assessment, outlines the content of the Safety Analysis Report, summarizes the requirements for the repository Environmental Impact Statement, discusses the requirements that apply to the site-suitability analyses and describes the site characterization. 10 figs., 7 tabs.

  1. Sampling designs for geochemical baseline studies in the Colorado oil shale region: a manual for practical application

    SciTech Connect (OSTI)

    Klusman, R. W.; Ringrose, C. D.; Candito, R. J.; Zuccaro, B.; Rutherford, D. W.; Dean, W. E.

    1980-06-01

    This manual presents a rationale for sampling designs, and results of geochemical baseline studies in the Colorado portion of the oil-shale region. The program consists of a systematic trace element study of soils, stream sediments, and plants carried out in a way to be conservative of human and financial resources and yield maximum information. Extension of this approach to other parameters, other locations, and to environmental baseline studies in general is a primary objective. A baseline for any geochemical parameter can be defined as the concentration of that parameter in a given medium such as soil, the range of its concentration, and the geographic scale of variability. In air quality studies, and to a lesser extent for plants, the temporal scale of variability must also be considered. In studies of soil, the temporal variablility does not become a factor until such time that a study is deemed necessary to evaluate whether or not there have been changes in baseline levels as a result of development. The manual is divided into five major parts. The first is a suggested sampling protocol which is presented in an outline form for guiding baseline studies in this area. The second section is background information on the physical features of the area of study, trace elements of significance occurring in oil shale, and the sample media used in these studies. The third section is concerned primarily with sampling design and its application to the geochemical studies of the oil shale region. The last sections, in the form of appendices, provide actual data and illustrate in a systematic manner, the calculations performed to obtain the various summary data. The last segment of the appendices is a more academic discussion of the geochemistry of trace elements and the parameters of importance influencing their behavior in natural systems.

  2. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation “C”. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthitemore » component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation “C” sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.« less

  3. Hawaii Energy Resource Overviews. Volume II. Impact of geothermal development on the geology and hydrology of the Hawaiian Islands

    SciTech Connect (OSTI)

    Feldman, C.; Siegel, B.Z.

    1980-06-01

    The following topics are discussed: the geological setting of the Hawaiian Islands, regional geology of the major islands, geohydrology of the Hawaiian Islands, Hawaiis' geothermal resources, and potential geological/hydrological problems associated with geothermal development. Souces of information on the geology of Hawaii are presented. (MHR)

  4. Final Report: Molecular Basis for Microbial Adhesion and Geochemical Surface Reactions: A Study Across Scales

    SciTech Connect (OSTI)

    Dixon, David Adams

    2013-06-27

    Computational chemistry was used to help provide a molecular level description of the interactions of Gram-negative microbial membranes with subsurface materials. The goal is to develop a better understanding of the molecular processes involved in microbial metal binding, microbial attachment to mineral surfaces, and, eventually, oxidation/reduction reactions (electron transfer) that can occur at these surfaces and are mediated by the bacterial exterior surface. The project focused on the interaction of the outer microbial membrane, which is dominated by an exterior lipopolysaccharide (LPS) portion, of Pseudomonas aeruginosa with the mineral goethite and with solvated ions in the environment. This was originally a collaborative project with T.P. Straatsma and B. Lowery of the Pacific Northwest National Laboratory. The University of Alabama effort used electronic structure calculations to predict the molecular behavior of ions in solution and the behavior of the sugars which form a critical part of the LPS. The interactions of the sugars with metal ions are expected to dominate much of the microscopic structure and transport phenomena in the LPS. This work, in combination with the molecular dynamics simulations of Straatsma and the experimental electrochemistry and microscopy measurements of Lowry, both at PNNL, is providing new insights into the detailed molecular behavior of these membranes in geochemical environments. The effort at The University of Alabama has three components: solvation energies and structures of ions in solution, prediction of the acidity of the critical groups in the sugars in the LPS, and binding of metal ions to the sugar anions. An important aspect of the structure of the LPS membrane as well as ion transport in the LPS is the ability of the sugar side groups such as the carboxylic acids and the phosphates to bind positively charged ions. We are studying the acidity of the acidic side groups in order to better understand the ability of these groups to bind metal ions. We need to understand the solvation properties of the metal ions in solution and their ability to bind not only to the sugars but to proteins and to other anions. Our goal is then to be able to predict the ability of the side groups to bind metal ions. One result from the earlier molecular dynamics simulations is the exclusion of water from the inner hydrophobic part of the membrane. We thus need to investigate the binding of the cations in media with different dielectric constants.

  5. ORISE: Recent Graduate Research Experiences - Craig Joseph

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Craig Joseph Geologist studies impact of hydrofracking on groundwater Craig Joseph Master's graduate Craig Joseph, a participant in the National Energy and Technology Laboratory Postgraduate Research Program, uses his academic background in marine geology to help predict how hydrofracking will affect groundwater. To extract natural gas, the industry injects fracturing fluid into the earth at high pressure to shatter the rock deposits and release the natural gas. When the fluid resurfaces, it has

  6. Permeability, geochemical, and water quality tests in support of an aquifer thermal energy storage site in Minnesota

    SciTech Connect (OSTI)

    Blair, S.C.; Deutsch, W.J.; Mitchell, P.J.

    1985-04-01

    This report describes the Underground Energy Storage Program's efforts to characterize physicochemical processes at DOE's ATES Field Test Facility (FTF) located on the University of Minnesota campus at St. Paul, Minnesota. Experimental efforts include: field tests at the St. Paul FTF to characterize fluid injectability and to evaluate the effectiveness of fluid-conditioning equipment, geochemical studies to investigate chemical reactions resulting from alterations to the aquifer's thermal regime, and laboratory tests on sandstone core from the site. Each experimental area is discussed and results obtained thus far are reported. 23 refs., 39 figs., 12 tabs.

  7. Nature climate change features Los Alamos forest research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nature climate change features forest research Nature climate change features Los Alamos forest research The print issue features as its cover story the tree-stress research of LANL scientist A. Park Williams and partners from the U.S. Geological Survey, University of Arizona and several other organizations. February 27, 2013 Burned trees in the Jemez Mountains of New Mexico after the 2011 Las Conchas fire. Image by Craig D. Allen, USGS. Burned trees in the Jemez Mountains of New Mexico after

  8. Nature Climate Change features Los Alamos forest research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nature Climate Change Features Forest Research Nature Climate Change features Los Alamos forest research The print issue features as its cover story the tree-stress research of LANL scientist A. Park Williams and partners from the U.S. Geological Survey, University of Arizona and several other organizations. February 27, 2013 Burned trees in the Jemez Mountains of New Mexico after the 2011 Las Conchas fire. Image by Craig D. Allen, USGS. Burned trees in the Jemez Mountains of New Mexico after

  9. The consequences of failure should be considered in siting geologic carbon sequestration projects

    SciTech Connect (OSTI)

    Price, P.N.; Oldenburg, C.M.

    2009-02-23

    Geologic carbon sequestration is the injection of anthropogenic CO{sub 2} into deep geologic formations where the CO{sub 2} is intended to remain indefinitely. If successfully implemented, geologic carbon sequestration will have little or no impact on terrestrial ecosystems aside from the mitigation of climate change. However, failure of a geologic carbon sequestration site, such as large-scale leakage of CO{sub 2} into a potable groundwater aquifer, could cause impacts that would require costly remediation measures. Governments are attempting to develop regulations for permitting geologic carbon sequestration sites to ensure their safety and effectiveness. At present, these regulations focus largely on decreasing the probability of failure. In this paper we propose that regulations for the siting of early geologic carbon sequestration projects should emphasize limiting the consequences of failure because consequences are easier to quantify than failure probability.

  10. Analysis of the structural parameters that influence gas production from the Devonian shale. Annual progress report, 1979-1980. Volume III. Data repository and reports published during fiscal year 1979-1980: production, unsponsored research

    SciTech Connect (OSTI)

    Negus-De Wys, J.; Dixon, J. M.; Evans, M. A.; Lee, K. D.; Ruotsala, J. E.; Wilson, T. H.; Williams, R. T.

    1980-10-01

    This document consists of the following papers: inorganic geochemistry studies of the Eastern Kentucky Gas Field; lithology studies of upper Devonian well cuttings in the Eastern Kentucky Gas Field; possible effects of plate tectonics on the Appalachian Devonian black shale production in eastern Kentucky; preliminary depositional model for upper Devonian Huron age organic black shale in the Eastern Kentucky Gas Field; the anatomy of a large Devonian black shale gas field; the Cottageville (Mount Alto) Gas Field, Jackson County, West Virginia: a case study of Devonian shale gas production; the Eastern Kentucky Gas Field: a geological study of the relationships of Ohio Shale gas occurrences to structure, stratigraphy, lithology, and inorganic geochemical parameters; and a statistical analysis of geochemical data for the Eastern Kentucky Gas Field.

  11. Determining resistivity of a geological formation using circuitry located within a borehole casing

    DOE Patents [OSTI]

    Vail III, William Banning

    2006-01-17

    Geological formation resistivity is determined. Circuitry is located within the borehole casing that is adjacent to the geological formation. The circuitry can measure one or more voltages across two or more voltage measurement electrodes associated with the borehole casing. The measured voltages are used by a processor to determine the resistivity of the geological formation. A common mode signal can also be reduced using the circuitry.

  12. UNIRIB: Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Mission Focus Photo Courtesy of Oak Ridge National Laboratory The central mission focus of the University Radioactive Ion Beam (UNIRIB) consortium is to perform nuclear physics research, and provide training and education. UNIRIB member universities have gained decades of frontline research experience through the use of the world-class facilities at Oak Ridge National Laboratory (ORNL) and other national laboratories across the United States. The UNIRIB consortium is tasked by the U.S.

  13. Environmental Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dist. Category UC-l 1, 13 DE@ 010764 Health & Environmental Research Summary of Accomplishments Prepared by Office of Energy Research /U.S. Department of Energy Washington, D.C. 20585 Reprinted April 1984 Published by Technical Information Center/U.S. Department of Energy The purpose of this brief narrative is to foster an awareness of a publicly funded health and environmental research program chartered nearly forty years ago, of its contributions toward the national goal of safe and

  14. PNNL: Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research at PNNL Research is our business With an unwavering focus on our missions, scientists and engineers at PNNL deliver science and technology. We conduct basic research that advances the frontiers of science. We translate discoveries into tools and technologies in science, energy, the environment and national security. For more than four decades, our experts have teamed with government, industry and academia to tackle some of the toughest problems facing our nation. The result: We're

  15. Research | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Researching energy systems and technologies-and the science behind them-for a future powered by clean energy. Subscribe Stay connected with the latest news and research breakthroughs from NREL. Sign up now Photo of the U.S. Department of Energy's Energy Systems Integration Facility at NREL. Energy Systems Integration Facility The only facility in the nation focused on utility-scale clean energy grid integration. Learn More National Bioenergy Center National Center for Photovoltaics

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Partial Mechanistic Understanding of the North American Monsoon Download a printable PDF Submitter: Erfani, E., Desert Research Institute Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud-Aerosol-Precipitation Interactions Journal Reference: Erfani E and DL Mitchell. 2014. "A partial mechanistic understanding of the North American monsoon." Journal of Geophysical Research - Atmospheres, 119(23), 10.1002/2014JD022038. a) Dependence of

  17. Research Highlights

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Highlights Research Highlights Highlighting some of the extraordinary work in Chemistry Division Contact Us Division Leader David Morris Deputy Division Leader Mark McCleskey (505) 667-4457 Deputy Division Leader (acting) George Havrilla Division Office (505) 667-4457 Email 2016 Physicist wins early-career award for isotope work 5/12 LANL researchers shine more light on the mechanism of one of the most efficient artificial catalytic reactions developed to date 4/20 3D-printing

  18. Researchers - JCAP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Administration Programs Research, Development, Test, and Evaluation Forty-eight final optic assemblies are symmetrically distributed around the upper and lower hemispheres of the target chamber of the National Ignition Facility at Lawrence Livermore National Laboratory The Office of Research, Development, Test, and Evaluation directs research, development, computer simulation, and inertial confinement fusion activities to maintain the safety, security and effectiveness of the nuclear weapons

  19. Research Approach

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Approach Research Approach NETL's onsite research approach is based on integrating simulation tools with targeted experimental validation at real-life conditions in the lab and in the field. Simulation tools increase confidence in designs, thereby reducing the risk associated with incorporating multiple innovative technologies, realizing scale-up, and predicting the behavior and properties of real materials. The scientific underpinnings encoded into these models also ensure that

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Back to Basics: Theoretical Studies on Storm Clouds and Implications for Modeling For original submission and image(s), see ARM Research Highlights http://www.arm.gov/science/highlights/ Research Highlight Storms associated with deep convection are a key component of weather and climate. For example, they produce a large share of precipitation that falls to the Earth's surface, and their anvil shields act as a thermal blanket on the planet. To understand the behavior of these storms, researchers

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Radiative Forcing by Long-Lived Greenhouse Gases: Calculations with the AER Models Download a printable PDF Submitter: Iacono, M. J., Atmospheric & Environmental Research, Inc. Delamere, J. S., Tech-X Corporation Mlawer, E. J., Atmospheric & Environmental Research, Inc. Collins, W. D., Lawrence Berkeley National Laboratory Area of Research: General Circulation and Single Column Models/Parameterizations Working Group(s): Radiative Processes Journal Reference: Iacono, MJ, JS Delamere, EJ

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climatology of Aerosol Optical Depth in North-Central Oklahoma: 1992-2008 Download a printable PDF Submitter: Michalsky, J. J., Cooperative Institute for Research in Environmental Sciences Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Michalsky J, F Denn, C Flynn, G Hodges, P Kiedron, A Koontz, J Schlemmer, and SE Schwartz. 2010. "Climatology of aerosol optical depth in north-central Oklahoma: 1992-2008." Journal of Geophysical Research -

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Differences Between Tropical and Trade-Wind Shallow Cumuli Download a printable PDF Submitter: Ghate, V. P., Argonne National Laboratory Area of Research: Vertical Velocity Working...

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nucleation Events Download a printable PDF Submitter: McMurry, P. ., University of Minnesota Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal ...

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Australian Wet Seasons as Revealed by ARM Disdrometer Research Facilities (Darwin, Australia)." Journal of Applied Meteorology and Climatology, , http:dx.doi.org10.1175...

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Climate Research Facility located near Lamont, Oklahoma. Measurements from ARM Raman lidar and Doppler radar instruments were used to both initialize and evaluate the model. A...

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in the Doppler spectra. Over the North Slope of Alaska, researchers used cloud radar Doppler velocity spectra, lidar backscattering coefficients and depolarization ratios, and...

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Zhang, Q., University of California, Davis Fast, J. ., Pacific Northwest National Laboratory Area of Research: Aerosol Processes Working Group(s): Aerosol Life Cycle Journal...

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Lose Download a printable PDF Submitter: Laskin, A., Pacific Northwest National Laboratory Fast, J. ., Pacific Northwest National Laboratory Area of Research: Aerosol...

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hagos, S. M., Pacific Northwest National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Life Cycle Journal Reference: NA...

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Submitter: Westwater, E. R., University of Colorado Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Properties Journal Reference:...

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liljegren, J. C., Argonne National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Properties, Radiative Processes...

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Xie, S., Lawrence Livermore National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s): Cloud Life Cycle Journal Reference: Xie...

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effects of Sea Spray on the Thermodynamics of the Hurricane Boundary Layer Download a printable PDF Submitter: Khain, A., The Hebrew University of Jerusalem Area of Research:...

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of MBL Cloud Properties over the Azores Download a printable PDF Submitter: Dong, X., University of North Dakota Area of Research: Radiation Processes Working Group(s): Cloud...

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... data collected from 18 flights during FIRE-ACE, the researchers analyzed measurements of drop and ice crystal particle size distribution, water content, and icing rate. ...

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a printable PDF Submitter: de Boer, G., University of Colorado, BoulderCIRES Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: de...

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to improve the representation of the autoconversion process in atmospheric models. This research also reveals major deficiencies of existing empirical schemes (see the figure)....

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Simple Equation Is Good Enough Submitter: Barnard, J., University of Nevada Reno Area of Research: Cloud DistributionsCharacterizations Working Group(s): Cloud Properties Journal...

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: Paine SN, DD Turner, ...

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    "Roobik" Is Part of the Answer, Not a Puzzle Submitter: Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Radiation Processes Working Group(s): ...

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Submitter: Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: Turner DD. ...

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Turner, D. D., National Oceanic and Atmospheric Administration Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal Reference: Shupe MD, DD Turner, VP ...

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mlawer, E. J., Atmospheric & Environmental Research, Inc. Turner, D. D., National Oceanic ... Journal Reference: Cady-Pereira, K, M Shephard, E Mlawer, D Turner, S Clough, and T ...

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Size Distributions with Help from Satellites Download a printable PDF Submitter: Mitchell, D. L., Desert Research Institute d'Entremont, R. P., Atmospheric and Environmental...

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud-Radiation Effects on Sea Ice Loss Download a printable PDF Submitter: Stephens, G. L., Colorado State University Area of Research: Cloud DistributionsCharacterizations...

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a printable PDF Submitter: Marshak, A., NASA - Goddard Space Flight Center Area of Research: Radiation Processes Working Group(s): Cloud-Aerosol-Precipitation Interactions...

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Influence of Dust Composition on Cloud Droplet Formation Download a printable PDF Submitter: Chuang, C., Lawrence Livermore National Laboratory Area of Research: Aerosol Properties...

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Burning on the Prairies Submitter: Bhattacharya, A., Pacific Northwest National Laboratory Area of Research: Radiation Processes Working Group(s): Cloud-Aerosol-Precipitation...

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Long-Term Impacts of Aerosols on the Vertical Development of Clouds and Precipitation Download a printable PDF Submitter: Li, Z., University of Maryland Area of Research:...

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Complexity of Arctic Clouds Download a printable PDF Submitter: Shupe, M., University of Colorado Area of Research: Cloud Processes Working Group(s): Cloud Life Cycle Journal...

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Broadband Albedo Observations in the Southern Great Plains Submitter: Lamb, P. J., University of Oklahoma Area of Research: Aerosol Properties Working Group(s): Aerosol Journal...

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    over the MJO Download a printable PDF Submitter: Del Genio, A. D., National Aeronautics and Space Administration Area of Research: Cloud DistributionsCharacterizations...

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Get Organized Download a printable PDF Submitter: Del Genio, A. D., National Aeronautics and Space Administration Area of Research: Cloud Processes Working Group(s): Cloud...

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Into the (Cold) Pool Download a printable PDF Submitter: Del Genio, A. D., National Aeronautics and Space Administration Area of Research: General Circulation and Single Column...

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and climate change. The study, funded in large part by DOE's Atmospheric System Research program and recently discussed in the Quarterly Journal of the Royal Meteorological...

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Area of Research: Radiation Processes Working Group(s): Radiative Processes Journal Reference: NA Figure 1. MFRSR data from the TWP site (970910) Figure 2. Aerosol...

  18. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Climate Models Submitter: Zhang, G., University of California, San Diego Area of Research: General Circulation and Single Column ModelsParameterizations Working Group(s):...

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    printable PDF Submitter: Kassianov, E., Pacific Northwest National Laboratory Area of Research: Radiation Processes Working Group(s): Aerosol Life Cycle Journal Reference:...

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Experiment Submitter: McFarquhar, G., University of Illinois, Urbana Area of Research: Cloud DistributionsCharacterizations Working Group(s): Cloud Properties Journal...

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and GCM Simulations Download a printable PDF Submitter: Mitchell, D. L., Desert Research Institute Rasch, P., Pacific Northwest National Laboratory Ivanova, D., Embry-Riddle...

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Download a printable PDF Submitter: Moffet, R., University of the Pacific Area of Research: Aerosol Processes Working Group(s): Aerosol Life Cycle Journal Reference: O'Brien...

  3. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Download a printable PDF Submitter: Alexandrov, M. D., Columbia University Area of Research: Radiation Processes Working Group(s): Aerosol Journal Reference: Applied Optics,...

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PDF Submitter: Bhattacharya, A., Pacific Northwest National Laboratory Area of Research: Cloud DistributionsCharacterizations Working Group(s): Cloud Life Cycle Journal...

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    printable PDF Submitter: Kulkarni, G., Pacific Northwest National Laboratory Area of Research: Aerosol Processes Working Group(s): Aerosol Life Cycle Journal Reference: Kulkarni...

  6. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory Long, C. N., NOAA Global Monitoring DivisionCIRES Area of Research: Radiation Processes Working Group(s): Cloud Life Cycle Journal Reference: Riihimaki...

  7. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory Ronfeld, D., Pacific Northwest National Laboratory Area of Research: Radiation Processes Working Group(s): Cloud Properties Journal Reference: NA The...

  8. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a printable PDF Submitter: Laskin, A., Pacific Northwest National Laboratory Area of Research: Cloud-Aerosol-Precipitation Interactions Working Group(s): Aerosol Life Cycle...

  9. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    printable PDF Submitter: Hagos, S. M., Pacific Northwest National Laboratory Area of Research: Atmospheric Thermodynamics and Vertical Structures Working Group(s):...

  10. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Raman Lidar Observations of Aerosol Humidification Near Clouds Submitter: Ferrare, R. A., NASA LaRC Area of Research: Aerosol Properties Working Group(s): Aerosol Journal ...

  11. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Technique Successful for Measuring Thickness of Broken Clouds Submitter: Marshak, A., NASA - Goddard Space Flight Center Area of Research: Cloud DistributionsCharacterizations ...

  12. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SGP Observations Help Validate Soil Temperature Simulations Download a printable PDF Submitter: Huang, M., Pacific Northwest National Laboratory Area of Research: Surface...

  13. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Area of Research: Cloud DistributionsCharacterizations Working Group(s): Cloud Life Cycle Journal Reference: Zhao Y, GG Mace, and JM Comstock. 2011. "The occurrence of particle ...

  14. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Area of Research: Aerosol Properties Working Group(s): Aerosol Life Cycle Journal Reference: Wilson J, D Imre, J Bernek, M Shrivastava, and A Zelenyuk. 2014. "Evaporation ...

  15. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    K-Distribution Method for a SW Radiative Transfer Model Submitter: Ackerman, T. P., University of Washington Area of Research: General Circulation and Single Column Models...

  16. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    anvil cirrus: A comparison between in situ aircraft measurements and ground-based Doppler cloud radar retrievals." Geophysical Research Letters, 41, doi:10.1002...

  17. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Using Doppler Radar to Characterize Cloud Parameters Download a printable PDF Submitter: Kogan, Y., University of Oklahoma - CIMMS Area of Research: Cloud Distributions...

  18. Research Projects

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Past Research Projects Composite-to-Steel Joint Integrity Monitoring and Assessment ... engineering programs and the pit manufacturing program. STUDENT RESOURCES Precollege ...

  19. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a printable PDF Submitter: Lin, Y., Geophysical Fluid Dynamics Laboratory Area of Research: General Circulation and Single Column ModelsParameterizations Working Group(s):...

  20. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and ARM Data Submitter: Somerville, R. C., Scripps Institution of Oceanography Area of Research: General Circulation and Single Column ModelsParameterizations Working Group(s):...

  1. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PDF Submitter: McComiskey, A. C., National Oceanic and Atmospheric Administration Area of Research: Cloud-Aerosol-Precipitation Interactions Working Group(s): Aerosol Life Cycle,...

  2. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fog and Rain in the Amazon Download a printable PDF Submitter: Gentine, P., Columbia University Sobel, A., Columbia University Area of Research: Cloud-Aerosol-Precipitation...

  3. Research Areas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in diverse research areas such as cell biology, lithography, infrared microscopy, radiology, and x-ray tomography. Time-Resolved These techniques exploit the pulsed nature of...

  4. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Production Flux of Sea-Spray Aerosol Download a printable PDF Submitter: Schwartz, S. E., Brookhaven National Laboratory Area of Research: Aerosol Properties Working Group(s):...

  5. Research Highlight

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ARM Sites Enable Assessment of Cluster Analysis for Identifying Cloud Regimes Submitter: Jakob, C., Monash University Area of Research: Cloud DistributionsCharacterizations...

  6. Summaries of physical research in the geosciences

    SciTech Connect (OSTI)

    Not Available

    1990-10-01

    The Department of Energy supports research in the geosciences in order to provide a sound foundation of fundamental knowledge in those areas of the geosciences which are germane to the Department of Energy's many missions. The Division of Engineering and Geosciences, part of the Office of Basic Energy Sciences of the Office of Energy Research, supports the Geosciences Research Program. The participants in this program include Department of Energy laboratories, industry, universities, and other governmental agencies. The summaries in this document, prepared by the investigators, briefly describe the scope of the individual programs. The Geosciences Research Program includes research in geology, petrology, geophysics, geochemistry, solar physics, solar-terrestrial relationships, aeronomy, seismology, and natural resource modeling and analysis, including their various subdivisions and interdisciplinary areas. All such research is related either directly or indirectly to the Department of Energy's long-range technological needs.

  7. Preliminary paper - Development of the Reference Design Description for a geologic repository

    SciTech Connect (OSTI)

    Daniel, Russell B.; Rindskopf, M. Sam

    1997-11-20

    This report describes the current Reference Design Description (RDD) design expectations for a potential geologic repository that could be located at Yucca Mountain in Nevada.

  8. Soda Lake Well Lithology Data and Geologic Cross-Sections (Dataset...

    Office of Scientific and Technical Information (OSTI)

    Comprehensive catalogue of drill-hole data in spreadsheet, shapefile, and Geosoft database ... area; Well Lithology Data; Drill-hole database; Geologic Cross-Sections; Gravity ...

  9. Rock Sampling At Blue Mountain Geothermal Area (U.S. Geological...

    Open Energy Info (EERE)

    collected included: geographic coordinates, rock type, magnetic susceptibility, and density. References US Geological Survey (2012) Geophysical Studies in the Vicinity of Blue...

  10. Aeromagnetic Survey At Blue Mountain Geothermal Area (U.S. Geological...

    Open Energy Info (EERE)

    search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Aeromagnetic Survey At Blue Mountain Geothermal Area (U.S. Geological Survey, 2012) Exploration Activity Details...

  11. Ground Magnetics At Blue Mountain Geothermal Area (U.S. Geological...

    Open Energy Info (EERE)

    Blue Mountain Geothermal Area (U.S. Geological Survey, 2012) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Magnetics At Blue Mountain...

  12. Surficial Geology and Landscape Development in Northern Frenchman Flat, Interim Summary and Soil Data

    SciTech Connect (OSTI)

    Raytheon Services Nevada Environmental Restoration and Waste Management Division

    1995-09-01

    This report summarizes geologic studies by Raytheon Services Nevada near the Area 5 Radioactive Waste Management Site at the Nevada Test Site. These studies are part of a program to satisfy data needs of (1) the Greater Confinement Disposal (GCD) Program Performance Assessment (PA), (2) the low-level waste (LLW) PA, and (3) the Resource Conservation and Recovery Act (RCRA) permit application. The geologic studies were integrated into a single program that worked toward a landscape evolution model of northern Frenchman Flat, with more detailed geologic studies of particular topics as needed. Only the Holocene tectonism and surficial geology components of the landscape model are presented in this report.

  13. Application of geochemical techniques to deduce the reservoir performance of the Palinpinon Geothermal Field, Philippines - an update

    SciTech Connect (OSTI)

    Ramos-Candelaria, M.N.; Garcia, S.E.; Hermoso, D.Z.

    1997-12-31

    Regular monitoring of various geochemical parameters in the water and vapor phases of the production wells at the Palinpinon I and II sectors of the Southern Negros Geothermal Field have been useful in the identification of the dominant reservoir processes occurring related to the present exploitation strategy. Observed geochemical and physical changes in the output of production wells have dictated production and injection strategies adopted to maximize production to meet the steam requirements of the power plant. Correlation of both physical and chemical data have identified the following reservoir processes: (1) Injection breakthrough via the Ticala Fault of the highly mineralized (Cl {approximately}8,000-10,500 mg/kg), isotopically enriched ({delta}{sup 18}O = -3.00{per_thousand}, {delta}{sup 2} H = -39{per_thousand}), and gas depleted brine for wells in the SW and central Puhagan. Injection breakthrough is also occurring in Palinpinon II and has resulted in temperature drops of 5-10{degrees}C.2. Pressure drawdown enhanced boiling in the liquid reservoir with steam separation of 220-240{degrees}C, feeding wells tapping the natural steam zone. However, enhanced drawdown has induced the entry of shallow acid steam condensate fluids in some wells (e.g. OK-7, PN-29D, PN-18D), which if not arrested could reduce production.

  14. UNITED STATES GEOLOGICAL SURVEY DEPARTMENT OF THE INTERIOR

    Office of Scientific and Technical Information (OSTI)

    GEOLOGICAL SURVEY DEPARTMENT OF THE INTERIOR i ..- - - - . WA-5 PROJECT REPORT West A f r i c a n S t a t e s (ECOWAS) Region I n v e s t i g a t i o n (1R)WA-5 USGS-OFR--82-714 DE84 900493 ASSESSMENT OF THE PETROLEUM, COAL,, AND GEOTHERMAL RESOURCES OF THE ECONOMIC COMMUNITY OF WEST AFRICAN STATES (ECOWAS) REGION Compiled by Robert E. M a t t i c k U.S. G e o l o g i c a l Survey Open-File Report 92 - 7/4! DISCLAIMER This report was prepared as an account of work sponsored by an agency of the

  15. Geology of the lower Yellow Creek Area, Northwestern Colorado

    SciTech Connect (OSTI)

    Hail, W.J.

    1990-01-01

    The lower Yellow Creek area is located in Rio Blanco and Moffat Counties of northwestern Colorado, about midway between the towns of Rangely and Meeker. The study area is in the northwestern part of the Piceance Creek basin, a very deep structural and sedimentary basin that formed during the Laramide orogeny. Potentially important resources in the area are oil shale and related minerals, oil and gas, coal, and uranium. Topics discussed in the report include: Stratigraphy (Subsurface rocks, Cretaceous rocks, Tertiary rocks, and Quaternary deposits); Structure (Midland anticline, graben at Pinyon Ridge, and Crooked Wash syncline, Folds and faults in the vicinity of the White River, Red Wash syncline and central graben zone, Yellow Creek anticlinal nose); Economic geology (Oil shale and associated minerals, Coal, Oil and gas, Uranium, Gravel).

  16. Draft Geologic Disposal Requirements Basis for STAD Specification

    SciTech Connect (OSTI)

    Ilgen, Anastasia G.; Bryan, Charles R.; Hardin, Ernest

    2015-03-25

    This document provides the basis for requirements in the current version of Performance Specification for Standardized Transportation, Aging, and Disposal Canister Systems, (FCRD-NFST-2014-0000579) that are driven by storage and geologic disposal considerations. Performance requirements for the Standardized Transportation, Aging, and Disposal (STAD) canister are given in Section 3.1 of that report. Here, the requirements are reviewed and the rationale for each provided. Note that, while FCRD-NFST-2014-0000579 provides performance specifications for other components of the STAD storage system (e.g. storage overpack, transfer and transportation casks, and others), these have no impact on the canister performance during disposal, and are not discussed here.

  17. DOE ER63951-3 Final Report: An Integrated Assessment of Geochemical and Community Structure Determinants of Metal Reduction Rates in Subsurface Sediments

    SciTech Connect (OSTI)

    Susan Pfiffner

    2010-06-28

    The objective of this research was to examine the importance of microbial community structure in influencing uranium reduction rates in subsurface sediments. If the redox state alone is the key to metal reduction, then any organisms that can utilize the oxygen and nitrate in the subsurface can change the geochemical conditions so metal reduction becomes an energetically favored reaction. Thus, community structure would not be critical in determining rates or extent of metal reduction unless community structure influenced the rate of change in redox. Alternatively, some microbes may directly catalyze metal reduction (e.g., specifically reduce U). In this case the composition of the community may be more important and specific types of electron donors may promote the production of communities that are more adept at U reduction. Our results helped determine if the type of electron donor or the preexisting community is important in the bioremediation of metal-contaminated environments subjected to biostimulation. In a series of experiments at the DOE FRC site in Oak Ridge we have consistently shown that all substrates promoted nitrate reduction, while glucose, ethanol, and acetate always promoted U reduction. Methanol only occasionally promoted extensive U reduction which is possibly due to community heterogeneity. There appeared to be limitations imposed on the community related to some substrates (e.g. methanol and pyruvate). Membrane lipid analyses (phospholipids and respiratory quinones) indicated different communities depending on electron donor used. Terminal restriction fragment length polymorphism and clone libraries indicated distinct differences among communities even in treatments that promoted U reduction. Thus, there was enough metabolic diversity to accommodate many different electron donors resulting in the U bioimmobilization.

  18. INTEGRATED GEOLOGIC-ENGINEERING MODEL FOR REEF AND CARBONATE SHOAL RESERVOIRS ASSOCIATED WITH PALEOHIGHS: UPPER JURASSIC SMACKOVER FORMATION, NORTHEASTERN GULF OF MEXICO

    SciTech Connect (OSTI)

    Ernest A. Mancini

    2002-09-25

    The University of Alabama in cooperation with Texas A&M University, McGill University, Longleaf Energy Group, Strago Petroleum Corporation, and Paramount Petroleum Company are undertaking an integrated, interdisciplinary geoscientific and engineering research project. The project is designed to characterize and model reservoir architecture, pore systems and rock-fluid interactions at the pore to field scale in Upper Jurassic Smackover reef and carbonate shoal reservoirs associated with varying degrees of relief on pre-Mesozoic basement paleohighs in the northeastern Gulf of Mexico. The project effort includes the prediction of fluid flow in carbonate reservoirs through reservoir simulation modeling which utilizes geologic reservoir characterization and modeling and the prediction of carbonate reservoir architecture, heterogeneity and quality through seismic imaging. The primary objective of the project is to increase the profitability, producibility and efficiency of recovery of oil from existing and undiscovered Upper Jurassic fields characterized by reef and carbonate shoals associated with pre-Mesozoic basement paleohighs. The principal research effort for Year 2 of the project has been reservoir characterization, 3-D modeling and technology transfer. This effort has included six tasks: (1) the study of rockfluid interactions, (2) petrophysical and engineering characterization, (3) data integration, (4) 3-D geologic modeling, (5) 3-D reservoir simulation and (6) technology transfer. This work was scheduled for completion in Year 2. Overall, the project work is on schedule. Geoscientific reservoir characterization is essentially completed. The architecture, porosity types and heterogeneity of the reef and shoal reservoirs at Appleton and Vocation Fields have been characterized using geological and geophysical data. The study of rock-fluid interactions is near completion. Observations regarding the diagenetic processes influencing pore system development and heterogeneity in these reef and shoal reservoirs have been made. Petrophysical and engineering property characterization has been essentially completed. Porosity and permeability data at Appleton and Vocation Fields have been analyzed, and well performance analysis has been conducted. Data integration is up to date, in that, the geological, geophysical, petrophysical and engineering data collected to date for Appleton and Vocation Fields have been compiled into a fieldwide digital database. 3-D geologic modeling of the structures and reservoirs at Appleton and Vocation Fields has been completed. The model represents an integration of geological, petrophysical and seismic data. 3-D reservoir simulation of the reservoirs at Appleton and Vocation Fields has been completed. The 3-D geologic model served as the framework for the simulations. A technology workshop on reservoir characterization and modeling at Appleton and Vocation Fields was conducted to transfer the results of the project to the petroleum industry.

  19. U.S. NWTRB March Meeting to Focus on DOE R&D Related to Salt as a Geologic Medium for Disposal of SNF and HLW

    Broader source: Energy.gov [DOE]

    The U.S. Nuclear Waste Technical Review Board will hold a public meeting in Albuquerque, NM, on Wednesday, March 19, 2014. The main topic of the meeting is the U.S. Department of Energy (DOE) research and development (R&D) activities related to salt as a geologic medium for disposal of spent nuclear fuel (SNF) and high-level radioactive waste (HLW).

  20. Research | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Research Mission Statement The objective of PARC is to understand the basic scientific principles that underpin the efficient functioning of natural photosynthetic antenna systems as a basis for design of biohybrid and bioinspired architectures for next-generation systems for solar-energy conversion. Scientific Themes Through basic scientific research, PARC seeks to understand the principles of light harvesting and energy funneling as applied to The PARC Vision Graphic three