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Sample records for geologic carbon sequestration

  1. Establishing MICHCARB, a geological carbon sequestration research...

    Office of Scientific and Technical Information (OSTI)

    Western Michigan University 58 GEOSCIENCES Geological carbon sequestration Enhanced oil recovery Characterization of oil, gas and saline reservoirs Geological carbon...

  2. Risk assessment framework for geologic carbon sequestration sites

    E-Print Network [OSTI]

    Oldenburg, C.

    2010-01-01

    carbon sequestration risk assessment, in Carbon Dioxidecarbon sequestration risk assessment, Energy Procedia,Risk Assessment Framework for Geologic Carbon Sequestration

  3. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    for  Geologic  Carbon  Sequestration. ”   International  of  Energy.  “Carbon  Sequestration  Atlas  of  the  Water  Extracted  from  Carbon  Sequestration  Projects."  

  4. GEOLOGIC CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION GEOLOGIC CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA to extend our thanks to the authors of various West Coast Regional Carbon Sequestration Partnership

  5. Risk assessment framework for geologic carbon sequestration sites

    E-Print Network [OSTI]

    Oldenburg, C.

    2010-01-01

    Framework for geologic carbon sequestration risk assessment,for geologic carbon sequestration risk assessment, Energyfor Geologic Carbon Sequestration, Int. J. of Greenhouse Gas

  6. Certification Framework Based on Effective Trapping for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2009-01-01

    workshop on geologic carbon sequestration, 2002. Benson,verification of geologic carbon sequestration, Geophys. Res.CO 2 from geologic carbon sequestration sites, Vadose Zone

  7. On leakage and seepage from geological carbon sequestration sites

    E-Print Network [OSTI]

    Oldenburg, C.M.; Unger, A.J.A.; Hepple, R.P.; Jordan, P.D.

    2002-01-01

    from Geologic Carbon Sequestration Sites Orlando Lawrencefrom Geologic Carbon Sequestration Sites Farrar, C.D. , M.L.1999. Reichle, D. et al. , Carbon sequestration research and

  8. Geological carbon sequestration: critical legal issues

    E-Print Network [OSTI]

    Watson, Andrew

    Geological carbon sequestration: critical legal issues Ray Purdy and Richard Macrory January 2004 Tyndall Centre for Climate Change Research Working Paper 45 #12;1 Geological carbon sequestration an integrated assessment of geological carbon sequestration (Project ID code T2.21). #12;2 1 Introduction

  9. Coda-wave interferometry analysis of time-lapse VSP data for monitoring geological carbon sequestration

    E-Print Network [OSTI]

    Zhou, R.

    2010-01-01

    Monitoring Geological Carbon Sequestration Authors: RongmaoGeological Carbon Sequestration ABSTRACT Injection andmonitoring geological carbon sequestration. ACKNOWLEDGEMENTS

  10. The consequences of failure should be considered in siting geologic carbon sequestration projects

    E-Print Network [OSTI]

    Price, P.N.

    2009-01-01

    2007. Geologic Carbon Sequestration Strategies forfor carbon capture and sequestration. Environmental Sciencein Siting Geologic Carbon Sequestration Projects Phillip N.

  11. Model Components of the Certification Framework for Geologic Carbon Sequestration Risk Assessment

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2009-01-01

    to two geologic carbon sequestration sites, Energy Procedia,for Geologic Carbon Sequestration Based on Effectivefor geologic carbon sequestration risk assessment, Energy

  12. Case studies of the application of the Certification Framework to two geologic carbon sequestration sites

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2009-01-01

    from geologic carbon sequestration sites: unsaturated zoneverification of geologic carbon sequestration, Geophys. Res.to two geologic carbon sequestration sites Curtis M.

  13. Geologic carbon sequestration as a global strategy to mitigate CO2 emissions: Sustainability and environmental risk

    E-Print Network [OSTI]

    Oldenburg, C.M.

    2012-01-01

    from geologic carbon sequestration sites: unsaturated zone2 from geologic carbon sequestration sites: CO 2 migrationGeologic Carbon Sequestration as a Global Strategy to

  14. LUCI: A facility at DUSEL for large-scale experimental study of geologic carbon sequestration

    E-Print Network [OSTI]

    Peters, C. A.

    2011-01-01

    study of geologic carbon sequestration Catherine A. Petersleakage at geologic carbon sequestration sites. Env EarthDOE) Conference on Carbon Sequestration, 2005. Alexandria,

  15. Federal Control of Geological Carbon Sequestration

    SciTech Connect (OSTI)

    Reitze, Arnold

    2011-04-11

    The United States has economically recoverable coal reserves of about 261 billion tons, which is in excess of a 250-­?year supply based on 2009 consumption rates. However, in the near future the use of coal may be legally restricted because of concerns over the effects of its combustion on atmospheric carbon dioxide concentrations. In response, the U.S. Department of Energy is making significant efforts to help develop and implement a commercial scale program of geologic carbon sequestration that involves capturing and storing carbon dioxide emitted from coal-­?burning electric power plants in deep underground formations. This article explores the technical and legal problems that must be resolved in order to have a viable carbon sequestration program. It covers the responsibilities of the United States Environmental Protection Agency and the Departments of Energy, Transportation and Interior. It discusses the use of the Safe Drinking Water Act, the Clean Air Act, the National Environmental Policy Act, the Endangered Species Act, and other applicable federal laws. Finally, it discusses the provisions related to carbon sequestration that have been included in the major bills dealing with climate change that Congress has been considering in 2009 and 2010. The article concludes that the many legal issues that exist can be resolved, but whether carbon sequestration becomes a commercial reality will depend on reducing its costs or by imposing legal requirements on fossil-­?fired power plants that result in the costs of carbon emissions increasing to the point that carbon sequestration becomes a feasible option.

  16. Modeling the effects of topography and wind on atmospheric dispersion of CO2 surface leakage at geologic carbon sequestration sites

    E-Print Network [OSTI]

    Chow, Fotini K.

    2009-01-01

    CO 2 from geologic carbon sequestration sites, Vadose Zoneleakage at geologic carbon sequestration sites Fotini K.assessment for geologic carbon sequestration sites. We have

  17. Leakage and Sepage of CO2 from Geologic Carbon Sequestration Sites: CO2 Migration into Surface Water

    E-Print Network [OSTI]

    Oldenburg, Curt M.; Lewicki, Jennifer L.

    2005-01-01

    from geologic carbon sequestration sites: unsaturated zoneCO 2 from Geologic Carbon Sequestration Sites, Vadose Zoneseepage from geologic carbon sequestration sites may occur.

  18. Carbon Geological Sequestration Systems Bau, Domenico 54 ENVIRONMENTAL

    Office of Scientific and Technical Information (OSTI)

    Multi-Objective Optimization Approaches for the Design of Carbon Geological Sequestration Systems Bau, Domenico 54 ENVIRONMENTAL SCIENCES The main objective of this project is to...

  19. Rock Physics of Geologic Carbon Sequestration/Storage Dvorkin...

    Office of Scientific and Technical Information (OSTI)

    Rock Physics of Geologic Carbon SequestrationStorage Dvorkin, Jack; Mavko, Gary 54 ENVIRONMENTAL SCIENCES; 58 GEOSCIENCES This report covers the results of developing the rock...

  20. Carbon Dioxide Geological Sequestration in Fractured Porous Rocks

    Office of Scientific and Technical Information (OSTI)

    Training and Research on Probabilistic Hydro-Thermo-Mechanical Modeling of Carbon Dioxide Geological Sequestration in Fractured Porous Rocks Gutierrez, Marte 54 ENVIRONMENTAL...

  1. Computational Geosciences Improved Semi-Analytical Simulation of Geological Carbon Sequestration

    E-Print Network [OSTI]

    Bau, Domenico A.

    Computational Geosciences Improved Semi-Analytical Simulation of Geological Carbon Sequestration of Geological Carbon Sequestration Article Type: Manuscript Keywords: Semi-Analytical Modeling; Iterative Methods; Geological Carbon Sequestration; Injection Site Assessment Corresponding Author: Brent Cody

  2. Invitation to Present, Sponsor, and Attend Geologic Carbon Sequestration Site Integrity: Characterization and

    E-Print Network [OSTI]

    Daniels, Jeffrey J.

    Invitation to Present, Sponsor, and Attend Geologic Carbon Sequestration Site Integrity and long-term sustainability of geologic carbon sequestration sites depends upon the ability on geologic carbon sequestration site monitoring. The management framework and costs will be similar

  3. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    Area Southeast  Regional  Carbon  Sequestration  PartnershipCoast  Regional  Carbon  Sequestration  Partnership Water  West  Coast  Regional  Carbon  Sequestration  Partnership  (

  4. Coupled Vadose Zone and Atmospheric Surface-Layer Transport of CO2 from Geologic Carbon Sequestration Sites

    E-Print Network [OSTI]

    Oldenburg, Curtis M.; Unger, Andre J.A.

    2004-01-01

    1999. Reichle, D. et al. , Carbon sequestration research andfrom geologic carbon sequestration sites: unsaturated zoneof CO 2 from Geologic Carbon Sequestration Sites Curtis M.

  5. Carbon Sequestration GeoloGical SequeStration of co2

    E-Print Network [OSTI]

    Pennycook, Steve

    Growing concern over the potential adverse effects of carbon dioxide (CO2 ) buildup in the atmosphere in three world-class CO2 storage projects that are endorsed by the Carbon Sequestration Leadership Forum04/2008 Carbon Sequestration GeoloGical SequeStration of co2 : the Geo-Seq Project Background

  6. Louisiana Geologic Sequestration of Carbon Dioxide Act (Louisiana)

    Broader source: Energy.gov [DOE]

    This law establishes that carbon dioxide and sequestration is a valuable commodity to the citizens of the state. Geologic storage of carbon dioxide may allow for the orderly withdrawal as...

  7. Water Challenges for Geologic Carbon Capture and Sequestration

    E-Print Network [OSTI]

    Newmark, Robin L.; Friedmann, Samuel J.; Carroll, Susan A.

    2010-01-01

    and HB 90:Carbon capture and sequestration, http://legisweb.conference on carbon capture and sequestration, Pittsburgh,The DOE’s Regional Carbon Sequestration Partnerships are

  8. An Overview of Geologic Carbon Sequestration Potential in California

    SciTech Connect (OSTI)

    Cameron Downey; John Clinkenbeard

    2005-10-01

    As part of the West Coast Regional Carbon Sequestration Partnership (WESTCARB), the California Geological Survey (CGS) conducted an assessment of geologic carbon sequestration potential in California. An inventory of sedimentary basins was screened for preliminary suitability for carbon sequestration. Criteria included porous and permeable strata, seals, and depth sufficient for critical state carbon dioxide (CO{sub 2}) injection. Of 104 basins inventoried, 27 met the criteria for further assessment. Petrophysical and fluid data from oil and gas reservoirs was used to characterize both saline aquifers and hydrocarbon reservoirs. Where available, well log or geophysical information was used to prepare basin-wide maps showing depth-to-basement and gross sand distribution. California's Cenozoic marine basins were determined to possess the most potential for geologic sequestration. These basins contain thick sedimentary sections, multiple saline aquifers and oil and gas reservoirs, widespread shale seals, and significant petrophysical data from oil and gas operations. Potential sequestration areas include the San Joaquin, Sacramento, Ventura, Los Angeles, and Eel River basins, followed by the smaller Salinas, La Honda, Cuyama, Livermore, Orinda, and Sonoma marine basins. California's terrestrial basins are generally too shallow for carbon sequestration. However, the Salton Trough and several smaller basins may offer opportunities for localized carbon sequestration.

  9. Advancing the Science of Geologic Carbon Sequestration (Registration: www.earthsciences.osu.edu/~jeff/carbseq/carbseq 2009)

    E-Print Network [OSTI]

    Daniels, Jeffrey J.

    Advancing the Science of Geologic Carbon Sequestration (Registration: www & American Electric Power Agenda March 9 ­ Morning Session 1 ­ Geological Carbon Sequestration: Introductions, AEP) 3. Field Testing: The Laboratory for Geological Carbon Sequestration (Neeraj Gupta, Battelle

  10. March 9 Morning Session 1 Geological Carbon Sequestration: Introductions (8:30-10:15), Jeff Daniels, Moderator

    E-Print Network [OSTI]

    Daniels, Jeffrey J.

    Agenda March 9 ­ Morning Session 1 ­ Geological Carbon Sequestration: Introductions (8 Testing: The Laboratory for Geological Carbon Sequestration (Neeraj Gupta, Battelle) Session 2 ­ Carbon in Reducing the Costs for Carbon Capture (Bruce Sass, Battelle) 2. Capture and sequestration challenges

  11. An improved strategy to detect CO2 leakage for verification of geologic carbon sequestration

    E-Print Network [OSTI]

    Hilley, George

    An improved strategy to detect CO2 leakage for verification of geologic carbon sequestration J. L the success of geologic carbon sequestration projects. To detect subtle CO2 leakage signals, we present), An improved strategy to detect CO2 leakage for verification of geologic carbon sequestration, Geophys. Res

  12. State and Regional Control of Geological Carbon Sequestration

    SciTech Connect (OSTI)

    Reitze, Arnold; Durrant, Marie

    2011-03-31

    The United States has economically recoverable coal reserves of about 261 billion tons, which is in excess of a 250-­?year supply based on 2009 consumption rates. However, in the near future the use of coal may be legally restricted because of concerns over the effects of its combustion on atmospheric carbon dioxide concentrations. Carbon capture and geologic sequestration offer one method to reduce carbon emissions from coal and other hydrocarbon energy production. While the federal government is providing increased funding for carbon capture and sequestration, recent congressional legislative efforts to create a framework for regulating carbon emissions have failed. However, regional and state bodies have taken significant actions both to regulate carbon and facilitate its capture and sequestration. This article explores how regional bodies and state government are addressing the technical and legal problems that must be resolved in order to have a viable carbon sequestration program. Several regional bodies have formed regulations and model laws that affect carbon capture and storage, and three bodies comprising twenty-­?three states—the Regional Greenhouse Gas Initiative, the Midwest Regional Greenhouse Gas Reduction Accord, and the Western Climate initiative—have cap-­?and-­?trade programs in various stages of development. State property, land use and environmental laws affect the development and implementation of carbon capture and sequestration projects, and unless federal standards are imposed, state laws on torts and renewable portfolio requirements will directly affect the liability and viability of these projects. This paper examines current state laws and legislative efforts addressing carbon capture and sequestration.

  13. Evaluating variable switching and flash methods in modeling carbon sequestration in deep geologic formations

    E-Print Network [OSTI]

    Mills, Richard

    Evaluating variable switching and flash methods in modeling carbon sequestration in deep geologic performance computing to assess the risks involved in carbon sequestration in deep geologic formations-thermal- chemical processes in variably saturated, non-isothermal porous media is applied to sequestration

  14. Carbon Trading Protocols for Geologic Sequestration

    SciTech Connect (OSTI)

    Hoversten, Shanna

    2008-08-07

    Carbon capture and storage (CCS) could become an instrumental part of a future carbon trading system in the US. If the US starts operating an emissions trading scheme (ETS) similar to that of the European Union's then limits on CO{sub 2} emissions will be conservative in the beginning stages. The government will most likely start by distributing most credits for free; these free credits are called allowances. The US may follow the model of the EU ETS, which during the first five-year phase distributed 95% of the credits for free, bringing that level down to 90% for the second five-year phase. As the number of free allowances declines, companies will be forced to purchase an increasing number of credits at government auction, or else obtain them from companies selling surplus credits. In addition to reducing the number of credits allocated for free, with each subsequent trading period the number of overall credits released into the market will decline in an effort to gradually reduce overall emissions. Companies may face financial difficulty as the value of credits continues to rise due to the reduction of the number of credits available in the market each trading period. Governments operating emissions trading systems face the challenge of achieving CO{sub 2} emissions targets without placing such a financial burden on their companies that the country's economy is markedly affected.

  15. The consequences of failure should be considered in siting geologic carbon sequestration projects

    SciTech Connect (OSTI)

    Price, P.N.; Oldenburg, C.M.

    2009-02-23

    Geologic carbon sequestration is the injection of anthropogenic CO{sub 2} into deep geologic formations where the CO{sub 2} is intended to remain indefinitely. If successfully implemented, geologic carbon sequestration will have little or no impact on terrestrial ecosystems aside from the mitigation of climate change. However, failure of a geologic carbon sequestration site, such as large-scale leakage of CO{sub 2} into a potable groundwater aquifer, could cause impacts that would require costly remediation measures. Governments are attempting to develop regulations for permitting geologic carbon sequestration sites to ensure their safety and effectiveness. At present, these regulations focus largely on decreasing the probability of failure. In this paper we propose that regulations for the siting of early geologic carbon sequestration projects should emphasize limiting the consequences of failure because consequences are easier to quantify than failure probability.

  16. CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA

    E-Print Network [OSTI]

    GEOLOGIC CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA: REPORT TO THE LEGISLATURE Regional Carbon Sequestration Partnership (WESTCARB) studies that we used, including Cameron Downey

  17. GEO-SEQ Best Practices Manual. Geologic Carbon Dioxide Sequestration: Site Evaluation to Implementation

    E-Print Network [OSTI]

    2004-01-01

    geochemical studies relevant to carbon sequestration.National Conference on Carbon Sequestration, Washington, DC,Conference on Carbon Sequestration, May 14-17, Washington

  18. Certification Framework Based on Effective Trapping for Geologic Carbon Sequestration

    SciTech Connect (OSTI)

    Oldenburg, Curtis M.; Bryant, Steven L.; Nicot, Jean-Philippe

    2009-01-15

    We have developed a certification framework (CF) for certifying the safety and effectiveness of geologic carbon sequestration (GCS) sites. Safety and effectiveness are achieved if CO{sub 2} and displaced brine have no significant impact on humans, other living things, resources, or the environment. In the CF, we relate effective trapping to CO{sub 2} leakage risk which takes into account both the impact and probability of leakage. We achieve simplicity in the CF by using (1) wells and faults as the potential leakage pathways, (2) compartments to represent environmental resources that may be impacted by leakage, (3) CO{sub 2} fluxes and concentrations in the compartments as proxies for impact to vulnerable entities, (4) broad ranges of storage formation properties to generate a catalog of simulated plume movements, and (5) probabilities of intersection of the CO{sub 2} plume with the conduits and compartments. We demonstrate the approach on a hypothetical GCS site in a Texas Gulf Coast saline formation. Through its generality and flexibility, the CF can contribute to the assessment of risk of CO{sub 2} and brine leakage as part of the certification process for licensing and permitting of GCS sites around the world regardless of the specific regulations in place in any given country.

  19. Carbon sequestration

    E-Print Network [OSTI]

    Carbon sequestration is the process of capture and long-term storage of atmospheric carbon dioxide (CO 2).[1] Carbon sequestration describes long-term storage of carbon dioxide or other forms of carbon to either mitigate or defer global warming and avoid ...

  20. Geologic Carbon Sequestration and Biosequestration (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    DePaolo, Don [Director, LBNL Earth Sciences Division

    2011-06-08

    Don DePaolo, Director of LBNL's Earth Sciences Division, speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

  1. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground

    SciTech Connect (OSTI)

    Oldenburg

    2009-07-30

    July 21, 2009 Berkeley Lab summer lecture: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  2. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground (LBNL Summer Lecture Series)

    ScienceCinema (OSTI)

    Oldenburg, Curtis M [LBNL Earth Sciences Division

    2011-04-28

    Summer Lecture Series 2009: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  3. Geologic Carbon Sequestration: Mitigating Climate Change by Injecting CO2 Underground (LBNL Summer Lecture Series)

    SciTech Connect (OSTI)

    Oldenburg, Curtis M.

    2009-07-21

    Summer Lecture Series 2009: Climate change provides strong motivation to reduce CO2 emissions from the burning of fossil fuels. Carbon dioxide capture and storage involves the capture, compression, and transport of CO2 to geologically favorable areas, where its injected into porous rock more than one kilometer underground for permanent storage. Oldenburg, who heads Berkeley Labs Geologic Carbon Sequestration Program, will focus on the challenges, opportunities, and research needs of this innovative technology.

  4. RESEARCH SUMMARY BY QUANLIN ZHOU During my stay at LBNL from March 2001, I have been working on (1) geologic carbon sequestration

    E-Print Network [OSTI]

    Zhou, Quanlin

    on (1) geologic carbon sequestration (GCS) projects for mitigating global climate change, (2) the DOE projects. 1 Research Highlights 1.1. Geological Carbon Sequestration I have been working on eight research projects in the area of geologic carbon sequestration since 2006. I have been PI or Co-PI for six projects

  5. A Hydro-mechanical Model and Analytical Solutions for Geomechanical Modeling of Carbon Dioxide Geological Sequestration

    SciTech Connect (OSTI)

    Xu, Zhijie; Fang, Yilin; Scheibe, Timothy D.; Bonneville, Alain

    2012-05-15

    We present a hydro-mechanical model for geological sequestration of carbon dioxide. The model considers the poroelastic effects by taking into account the coupling between the geomechanical response and the fluid flow in greater detail. The simplified hydro-mechanical model includes the geomechanical part that relies on the linear elasticity, while the fluid flow is based on the Darcy’s law. Two parts were coupled using the standard linear poroelasticity. Analytical solutions for pressure field were obtained for a typical geological sequestration scenario. The model predicts the temporal and spatial variation of pressure field and effects of permeability and elastic modulus of formation on the fluid pressure distribution.

  6. Carbon Sequestration

    SciTech Connect (OSTI)

    2013-05-06

    Carbon Sequestration- the process of capturing the CO2 released by the burning of fossil fuels and storing it deep withing the Earth, trapped by a non-porous layer of rock.

  7. GEO-SEQ Best Practices Manual. Geologic Carbon Dioxide Sequestration: Site Evaluation to Implementation

    SciTech Connect (OSTI)

    Benson, Sally M.; Myer, Larry R.; Oldenburg, Curtis M.; Doughty, Christine A.; Pruess, Karsten; Lewicki, Jennifer; Hoversten, Mike; Gasperikova, Erica; Daley, Thomas; Majer, Ernie; Lippmann, Marcelo; Tsang, Chin-Fu; Knauss, Kevin; Johnson, James; Foxall, William; Ramirez, Abe; Newmark, Robin; Cole, David; Phelps, Tommy J.; Parker, J.; Palumbo, A.; Horita, J.; Fisher, S.; Moline, Gerry; Orr, Lynn; Kovscek, Tony; Jessen, K.; Wang, Y.; Zhu, J.; Cakici, M.; Hovorka, Susan; Holtz, Mark; Sakurai, Shinichi; Gunter, Bill; Law, David; van der Meer, Bert

    2004-10-23

    The first phase of the GEO-SEQ project was a multidisciplinary effort focused on investigating ways to lower the cost and risk of geologic carbon sequestration. Through our research in the GEO-SEQ project, we have produced results that may be of interest to the wider geologic carbon sequestration community. However, much of the knowledge developed in GEO-SEQ is not easily accessible because it is dispersed in the peer-reviewed literature and conference proceedings in individual papers on specific topics. The purpose of this report is to present key GEO-SEQ findings relevant to the practical implementation of geologic carbon sequestration in the form of a Best Practices Manual. Because our work in GEO-SEQ focused on the characterization and project development aspects, the scope of this report covers practices prior to injection, referred to as the design phase. The design phase encompasses activities such as selecting sites for which enhanced recovery may be possible, evaluating CO{sub 2} capacity and sequestration feasibility, and designing and evaluating monitoring approaches. Through this Best Practices Manual, we have endeavored to place our GEO-SEQ findings in a practical context and format that will be useful to readers interested in project implementation. The overall objective of this Manual is to facilitate putting the findings of the GEO-SEQ project into practice.

  8. A fluid pressure and deformation analysis for geological sequestration of carbon dioxide

    SciTech Connect (OSTI)

    Xu, Zhijie; Fang, Yilin; Scheibe, Timothy D.; Bonneville, Alain

    2012-06-07

    We present a hydro-mechanical model and deformation analysis for geological sequestration of carbon dioxide. The model considers the poroelastic effects by taking into account the two-way coupling between the geomechanical response and the fluid flow process in greater detail. In order for analytical solutions, the simplified hydro-mechanical model includes the geomechanical part that relies on the theory of linear elasticity, while the fluid flow is based on the Darcy’s law. The model was derived through coupling the two parts using the standard linear poroelasticity theory. Analytical solutions for fluid pressure field were obtained for a typical geological sequestration scenario and the solutions for ground deformation were obtained using the method of Green’s function. Solutions predict the temporal and spatial variation of fluid pressure, the effect of permeability and elastic modulus on the fluid pressure, the ground surface uplift, and the radial deformation during the entire injection period.

  9. Wellbore cement fracture evolution at the cement–basalt caprock interface during geologic carbon sequestration

    SciTech Connect (OSTI)

    Jung, Hun Bok; Kabilan, Senthil; Carson, James P.; Kuprat, Andrew P.; Um, Wooyong; Martin, Paul F.; Dahl, Michael E.; Kafentzis, Tyler A.; Varga, Tamas; Stephens, Sean A.; Arey, Bruce W.; Carroll, KC; Bonneville, Alain; Fernandez, Carlos A.

    2014-08-01

    Composite Portland cement-basalt caprock cores with fractures, as well as neat Portland cement columns, were prepared to understand the geochemical and geomechanical effects on the integrity of wellbores with defects during geologic carbon sequestration. The samples were reacted with CO2-saturated groundwater at 50 ºC and 10 MPa for 3 months under static conditions, while one cement-basalt core was subjected to mechanical stress at 2.7 MPa before the CO2 reaction. Micro-XRD and SEM-EDS data collected along the cement-basalt interface after 3-month reaction with CO2-saturated groundwater indicate that carbonation of cement matrix was extensive with the precipitation of calcite, aragonite, and vaterite, whereas the alteration of basalt caprock was minor. X-ray microtomography (XMT) provided three-dimensional (3-D) visualization of the opening and interconnection of cement fractures due to mechanical stress. Computational fluid dynamics (CFD) modeling further revealed that this stress led to the increase in fluid flow and hence permeability. After the CO2-reaction, XMT images displayed that calcium carbonate precipitation occurred extensively within the fractures in the cement matrix, but only partially along the fracture located at the cement-basalt interface. The 3-D visualization and CFD modeling also showed that the precipitation of calcium carbonate within the cement fractures after the CO2-reaction resulted in the disconnection of cement fractures and permeability decrease. The permeability calculated based on CFD modeling was in agreement with the experimentally determined permeability. This study demonstrates that XMT imaging coupled with CFD modeling represent a powerful tool to visualize and quantify fracture evolution and permeability change in geologic materials and to predict their behavior during geologic carbon sequestration or hydraulic fracturing for shale gas production and enhanced geothermal systems.

  10. Experimental study of potential wellbore cement carbonation by various phases of carbon dioxide during geologic carbon sequestration

    SciTech Connect (OSTI)

    Jung, Hun Bok; Um, Wooyong

    2013-08-16

    Hydrated Portland cement was reacted with carbon dioxide (CO2) in supercritical, gaseous, and aqueous phases to understand the potential cement alteration processes along the length of a wellbore, extending from deep CO2 storage reservoir to the shallow subsurface during geologic carbon sequestration. The 3-D X-ray microtomography (XMT) images displayed that the cement alteration was significantly more extensive by CO2-saturated synthetic groundwater than dry or wet supercritical CO2 at high P (10 MPa)-T (50°C) conditions. Scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS) analysis also exhibited a systematic Ca depletion and C enrichment in cement matrix exposed to CO2-saturated groundwater. Integrated XMT, XRD, and SEM-EDS analyses identified the formation of extensive carbonated zone filled with CaCO3(s), as well as the porous degradation front and the outermost silica-rich zone in cement after exposure to CO2-saturated groundwater. The cement alteration by CO2-saturated groundwater for 2-8 months overall decreased the porosity from 31% to 22% and the permeability by an order of magnitude. Cement alteration by dry or wet supercritical CO2 was slow and minor compared to CO2-saturated groundwater. A thin single carbonation zone was formed in cement after exposure to wet supercritical CO2 for 8 months or dry supercritical CO2 for 15 months. Extensive calcite coating was formed on the outside surface of a cement sample after exposure to wet gaseous CO2 for 1-3 months. The chemical-physical characterization of hydrated Portland cement after exposure to various phases of carbon dioxide indicates that the extent of cement carbonation can be significantly heterogeneous depending on CO2 phase present in the wellbore environment. Both experimental and geochemical modeling results suggest that wellbore cement exposure to supercritical, gaseous, and aqueous phases of CO2 during geologic carbon sequestration is unlikely to damage the wellbore integrity because cement alteration by all phases of CO2 is dominated by carbonation reaction. This is consistent with previous field studies of wellbore cement with extensive carbonation after exposure to CO2 for 3 decades. However, XMT imaging indicates that preferential cement alteration by supercritical CO2 or CO2-saturated groundwater can occur along the cement-steel or cement-rock interfaces. This highlights the importance of further investigation of cement degradation along the interfaces of wellbore materials to ensure permanent geologic carbon storage.

  11. Spatially-explicit impacts of carbon capture and sequestration on water supply and demand

    E-Print Network [OSTI]

    Sathre, Roger

    2014-01-01

    Laboratory). 2010. Carbon Sequestration Atlas of the United2012. National Carbon Sequestration Database and Geographicfor use in geologic carbon sequestration projects. Aquifers

  12. Sensitivity of injection costs to input petrophysical parameters in numerical geologic carbon sequestration models

    SciTech Connect (OSTI)

    Cheng, C. L.; Gragg, M. J.; Perfect, E.; White, Mark D.; Lemiszki, P. J.; McKay, L. D.

    2013-08-24

    Numerical simulations are widely used in feasibility studies for geologic carbon sequestration. Accurate estimates of petrophysical parameters are needed as inputs for these simulations. However, relatively few experimental values are available for CO2-brine systems. Hence, a sensitivity analysis was performed using the STOMP numerical code for supercritical CO2 injected into a model confined deep saline aquifer. The intrinsic permeability, porosity, pore compressibility, and capillary pressure-saturation/relative permeability parameters (residual liquid saturation, residual gas saturation, and van Genuchten alpha and m values) were varied independently. Their influence on CO2 injection rates and costs were determined and the parameters were ranked based on normalized coefficients of variation. The simulations resulted in differences of up to tens of millions of dollars over the life of the project (i.e., the time taken to inject 10.8 million metric tons of CO2). The two most influential parameters were the intrinsic permeability and the van Genuchten m value. Two other parameters, the residual gas saturation and the residual liquid saturation, ranked above the porosity. These results highlight the need for accurate estimates of capillary pressure-saturation/relative permeability parameters for geologic carbon sequestration simulations in addition to measurements of porosity and intrinsic permeability.

  13. House Committee on Natural Resources The Future of Fossil Fuels: Geological and Terrestrial Sequestration of Carbon Dioxide

    E-Print Network [OSTI]

    and sequestration (CCS) is the critical enabling technology that would reduce CO2 emissions significantly while also at a large industrial source, such as a coal-fired power plant. By capture, it is meant isolating the CO2, thank you for the opportunity to appear before you today to discuss Carbon Dioxide (CO2) geological

  14. An Assessment of Geological Carbon Sequestration Options in the Illinois Basin

    SciTech Connect (OSTI)

    Robert Finley

    2005-09-30

    The Midwest Geological Sequestration Consortium (MGSC) has investigated the options for geological carbon dioxide (CO{sub 2}) sequestration in the 155,400-km{sup 2} (60,000-mi{sup 2}) Illinois Basin. Within the Basin, underlying most of Illinois, western Indiana, and western Kentucky, are relatively deeper and/or thinner coal resources, numerous mature oil fields, and deep salt-water-bearing reservoirs that are potentially capable of storing CO{sub 2}. The objective of this Assessment was to determine the technical and economic feasibility of using these geological sinks for long-term storage to avoid atmospheric release of CO{sub 2} from fossil fuel combustion and thereby avoid the potential for adverse climate change. The MGSC is a consortium of the geological surveys of Illinois, Indiana, and Kentucky joined by six private corporations, five professional business associations, one interstate compact, two university researchers, two Illinois state agencies, and two consultants. The purpose of the Consortium is to assess carbon capture, transportation, and storage processes and their costs and viability in the three-state Illinois Basin region. The Illinois State Geological Survey serves as Lead Technical Contractor for the Consortium. The Illinois Basin region has annual emissions from stationary anthropogenic sources exceeding 276 million metric tonnes (304 million tons) of CO{sub 2} (>70 million tonnes (77 million tons) carbon equivalent), primarily from coal-fired electric generation facilities, some of which burn almost 4.5 million tonnes (5 million tons) of coal per year. Assessing the options for capture, transportation, and storage of the CO{sub 2} emissions within the region has been a 12-task, 2-year process that has assessed 3,600 million tonnes (3,968 million tons) of storage capacity in coal seams, 140 to 440 million tonnes (154 to 485 million tons) of capacity in mature oil reservoirs, 7,800 million tonnes (8,598 million tons) of capacity in saline reservoirs deep beneath geological structures, and 30,000 to 35,000 million tonnes (33,069 to 38,580 million tons) of capacity in saline reservoirs on a regional dip >1,219 m (4,000 ft) deep. The major part of this effort assessed each of the three geological sinks: coals, oil reservoirs, and saline reservoirs. We linked and integrated options for capture, transportation, and geological storage with the environmental and regulatory framework to define sequestration scenarios and potential outcomes for the region. Extensive use of Geographic Information Systems (GIS) and visualization technology was made to convey results to project sponsors, other researchers, the business community, and the general public. An action plan for possible technology validation field tests involving CO{sub 2} injection was included in a Phase II proposal (successfully funded) to the U.S. Department of Energy with cost sharing from Illinois Clean Coal Institute.

  15. Model Components of the Certification Framework for Geologic Carbon Sequestration Risk Assessment

    SciTech Connect (OSTI)

    Oldenburg, Curtis M.; Bryant, Steven L.; Nicot, Jean-Philippe; Kumar, Navanit; Zhang, Yingqi; Jordan, Preston; Pan, Lehua; Granvold, Patrick; Chow, Fotini K.

    2009-06-01

    We have developed a framework for assessing the leakage risk of geologic carbon sequestration sites. This framework, known as the Certification Framework (CF), emphasizes wells and faults as the primary potential leakage conduits. Vulnerable resources are grouped into compartments, and impacts due to leakage are quantified by the leakage flux or concentrations that could potentially occur in compartments under various scenarios. The CF utilizes several model components to simulate leakage scenarios. One model component is a catalog of results of reservoir simulations that can be queried to estimate plume travel distances and times, rather than requiring CF users to run new reservoir simulations for each case. Other model components developed for the CF and described here include fault characterization using fault-population statistics; fault connection probability using fuzzy rules; well-flow modeling with a drift-flux model implemented in TOUGH2; and atmospheric dense-gas dispersion using a mesoscale weather prediction code.

  16. Case studies of the application of the Certification Framework to two geologic carbon sequestration sites

    SciTech Connect (OSTI)

    Oldenburg, Curtis M.; Nicot, J.-P.; Bryant, S.L.

    2008-11-01

    We have developed a certification framework (CF) for certifying that the risks of geologic carbon sequestration (GCS) sites are below agreed-upon thresholds. The CF is based on effective trapping of CO2, the proposed concept that takes into account both the probability and impact of CO2 leakage. The CF uses probability estimates of the intersection of conductive faults and wells with the CO2 plume along with modeled fluxes or concentrations of CO2 as proxies for impacts to compartments (such as potable groundwater) to calculate CO2 leakage risk. In order to test and refine the approach, we applied the CF to (1) a hypothetical large-scale GCS project in the Texas Gulf Coast, and (2) WESTCARB's Phase III GCS pilot in the southern San Joaquin Valley, California.

  17. Dynamic Evolution of Cement Composition and Transport Properties under Conditions Relevant to Geological Carbon Sequestration

    SciTech Connect (OSTI)

    Brunet, Jean-Patrick Leopold; Li, Li; Karpyn, Zuleima T.; Strazisar, Brian; Bromhal Grant

    2013-08-01

    Assessing the possibility of CO{sub 2} leakage is one of the major challenges for geological carbon sequestration. Injected CO{sub 2} can react with wellbore cement, which can potentially change cement composition and transport properties. In this work, we develop a reactive transport model based on experimental observations to understand and predict the property evolution of cement in direct contact with CO{sub 2}-saturated brine under diffusion-controlled conditions. The model reproduced the observed zones of portlandite depletion and calcite formation. Cement alteration is initially fast and slows down at later times. This work also quantified the role of initial cement properties, in particular the ratio of the initial portlandite content to porosity (defined here as ?), in determining the evolution of cement properties. Portlandite-rich cement with large ? values results in a localized “sharp” reactive diffusive front characterized by calcite precipitation, leading to significant porosity reduction, which eventually clogs the pore space and prevents further acid penetration. Severe degradation occurs at the cement–brine interface with large ? values. This alteration increases effective permeability by orders of magnitude for fluids that preferentially flow through the degraded zone. The significant porosity decrease in the calcite zone also leads to orders of magnitude decrease in effective permeability, where fluids flow through the low-permeability calcite zone. The developed reactive transport model provides a valuable tool to link cement–CO{sub 2} reactions with the evolution of porosity and permeability. It can be used to quantify and predict long-term wellbore cement behavior and can facilitate the risk assessment associated with geological CO{sub 2} sequestration.

  18. 1. BACKGROUND & OBJECTIVES For geological carbon sequestration, it is essential to

    E-Print Network [OSTI]

    to generate comprehensive data sets. Due to the nature of the CO2 geological sequestration where supercritical for supercritical CO2. In this study, a mixture of Glycerol-water (8:2 by weight) and Soltrol 220 was selected as the surrogate fluids for the brine and supercritical CO2, respectively, based on the fluid properties

  19. Summary Report on CO2 Geologic Sequestration & Water Resources Workshop

    E-Print Network [OSTI]

    Varadharajan, C.

    2013-01-01

    implications for carbon sequestration. Environ Earth Sci. ,geochemistry in carbon sequestration environments. Abstractas a surveillance tool for carbon- sequestration projects.

  20. Mobilization and Transport of Organic Compounds from Reservoir Rock and Caprock in Geological Carbon Sequestration Sites

    SciTech Connect (OSTI)

    Zhong, Lirong; Cantrell, Kirk J.; Mitroshkov, Alexandre V.; Shewell, Jesse L.

    2014-05-06

    Supercritical CO2 (scCO2) is an excellent solvent for organic compounds, including benzene, toluene, ethyl-benzene, and xylene (BTEX), phenols, and polycyclic aromatic hydrocarbons (PAHs). Monitoring results from geological carbon sequestration (GCS) field tests has shown that organic compounds are mobilized following CO2 injection. Such results have raised concerns regarding the potential for groundwater contamination by toxic organic compounds mobilized during GCS. Knowledge of the mobilization mechanism of organic compounds and their transport and fate in the subsurface is essential for assessing risks associated with GCS. Extraction tests using scCO2 and methylene chloride (CH2Cl2) were conducted to study the mobilization of volatile organic compounds (VOCs, including BTEX), the PAH naphthalene, and n-alkanes (n-C20 – n-C30) by scCO2 from representative reservoir rock and caprock obtained from depleted oil reservoirs and coal from an enhanced coal-bed methane recovery site. More VOCs and naphthalene were extractable by scCO2 compared to the CH2Cl2 extractions, while scCO2 extractable alkane concentrations were much lower than concentrations extractable by CH2Cl2. In addition, dry scCO2 was found to extract more VOCs than water saturated scCO2, but water saturated scCO2 mobilized more naphthalene than dry scCO2. In sand column experiments, moisture content was found to have an important influence on the transport of the organic compounds. In dry sand columns the majority of the compounds were retained in the column except benzene and toluene. In wet sand columns the mobility of the BTEX was much higher than that of naphthalene. Based upon results determined for the reservoir rock, caprock, and coal samples studied here, the risk to aquifers from contamination by organic compounds appears to be relatively low; however, further work is necessary to fully evaluate risks from depleted oil reservoirs.

  1. LUCI: A facility at DUSEL for large-scale experimental study of geologic carbon sequestration

    SciTech Connect (OSTI)

    Peters, C. A.; Dobson, P.F.; Oldenburg, C.M.; Wang, J. S. Y.; Onstott, T.C.; Scherer, G.W.; Freifeld, B.M.; Ramakrishnan, T.S.; Stabinski, E.L.; Liang, K.; Verma, S.

    2010-10-01

    LUCI, the Laboratory for Underground CO{sub 2} Investigations, is an experimental facility being planned for the DUSEL underground laboratory in South Dakota, USA. It is designed to study vertical flow of CO{sub 2} in porous media over length scales representative of leakage scenarios in geologic carbon sequestration. The plan for LUCI is a set of three vertical column pressure vessels, each of which is {approx}500 m long and {approx}1 m in diameter. The vessels will be filled with brine and sand or sedimentary rock. Each vessel will have an inner column to simulate a well for deployment of down-hole logging tools. The experiments are configured to simulate CO{sub 2} leakage by releasing CO{sub 2} into the bottoms of the columns. The scale of the LUCI facility will permit measurements to study CO{sub 2} flow over pressure and temperature variations that span supercritical to subcritical gas conditions. It will enable observation or inference of a variety of relevant processes such as buoyancy-driven flow in porous media, Joule-Thomson cooling, thermal exchange, viscous fingering, residual trapping, and CO{sub 2} dissolution. Experiments are also planned for reactive flow of CO{sub 2} and acidified brines in caprock sediments and well cements, and for CO{sub 2}-enhanced methanogenesis in organic-rich shales. A comprehensive suite of geophysical logging instruments will be deployed to monitor experimental conditions as well as provide data to quantify vertical resolution of sensor technologies. The experimental observations from LUCI will generate fundamental new understanding of the processes governing CO{sub 2} trapping and vertical migration, and will provide valuable data to calibrate and validate large-scale model simulations.

  2. Intro to Carbon Sequestration

    ScienceCinema (OSTI)

    None

    2010-01-08

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  3. Intro to Carbon Sequestration

    SciTech Connect (OSTI)

    2008-03-06

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  4. DOE Releases Report on Techniques to Ensure Safe, Effective Geologic Carbon Sequestration

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy's National Energy Technology Laboratory has created a comprehensive new document that examines existing and emerging techniques to monitor, verify, and account for carbon dioxide stored in geologic formations.

  5. Subsurface Monitor for Dissolved Inorganic Carbon at Geological Sequestration Site Phase 1 SBIR Final Report

    SciTech Connect (OSTI)

    Sheng Wu

    2012-08-03

    Phase I research of this SBIR contract has yielded anticipated results and enable us to develop a practical new instrument to measure the Dissolved Inorganic Carbons (DIC) as well as Supercritical (SC) CO2 in underground brine water at higher sensitivity, lower cost, higher frequency and longer period of time for the Monitoring, Verification & Accounting (MVA) of CO2 sequestration as well as Enhanced Oil Recovery (EOR). We show that reduced cost and improved performance are possible; both future and emerging market exist for the proposed new instrument.

  6. FY12 ARRA-NRAP Report – Studies to Support Risk Assessment of Geologic Carbon Sequestration

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Shao, Hongbo; Thompson, C. J.; Zhong, Lirong; Jung, Hun Bok; Um, Wooyong

    2011-09-27

    This report summarizes results of research conducted during FY2012 to support the assessment of environmental risks associated with geologic carbon dioxide (CO2) sequestration and storage. Several research focus areas are ongoing as part of this project. This includes the quantification of the leachability of metals and organic compounds from representative CO2 storage reservoir and caprock materials, the fate of metals and organic compounds after release, and the development of a method to measure pH in situ under supercritical CO2 (scCO2) conditions. Metal leachability experiments were completed on 6 different rock samples in brine in equilibrium with scCO2 at representative geologic reservoir conditions. In general, the leaching of RCRA metals and other metals of concern was found to be limited and not likely to be a significant issue (at least, for the rocks tested). Metals leaching experiments were also completed on 1 rock sample with scCO2 containing oxygen at concentrations of 0, 1, 5, and 10% to simulate injection of CO2 originating from the oxy-fuel combustion process. Significant differences in the leaching behavior of certain metals were observed when oxygen is present in the CO2. These differences resulted from oxidation of sulfides, release of sulfate, ferric iron and other metals, and subsequent precipitation of iron oxides and some sulfates such as barite. Experiments to evaluate the potential for mobilization of organic compounds from representative reservoir materials and cap rock and their fate in porous media (quartz sand) have been conducted. Results with Fruitland coal and Gothic shale indicate that lighter organic compounds were more susceptible to mobilization by scCO2 compared to heavier compounds. Alkanes demonstrated very low extractability by scCO2. No significant differences were observed between the extractability of organic compounds by dry or water saturated scCO2. Reaction equilibrium appears to have been reached by 96 hours. When the scCO2 was released from the reactor, less than 60% of the injected lighter compounds (benzene, toluene) were transported through dry sand column by the CO2, while more than 90% of the heavier organics were trapped in the sand column. For wet sand columns, most (80% to 100%) of the organic compounds injected into the sand column passed through, except for naphthalene which was substantial removed from the CO2 within the column. A spectrophotometric method was developed to measure pH in brines in contact with scCO2. This method provides an alternative to fragile glass pH electrodes and thermodynamic modeling approaches for estimating pH. The method was tested in simulated reservoir fluids (CO2–NaCl–H2O) at different temperatures, pressures, and ionic strength, and the results were compared with other experimental studies and geochemical models. Measured pH values were generally in agreement with the models, but inconsistencies were present between some of the models.

  7. Assessing leakage detectability at geologic CO2 sequestration sites using the probabilistic collocation method

    E-Print Network [OSTI]

    Lu, Zhiming

    detectability at geologic carbon sequestration sites under parameter uncertainty. Uncertainty quantification (UQ and natural features, which consti- tute one of the greatest threats to the integrity of carbon sequestration for reducing greenhouse gas emission. A primary goal of geologic carbon sequestration is to ensure

  8. Regional Carbon Sequestration Partnerships

    Broader source: Energy.gov [DOE]

    DOE has created a network of seven Regional Carbon Sequestration Partnerships (RCSPs) to help develop the technology, infrastructure, and regulations to implement large-scale CO2 storage (also...

  9. Basin-Scale Leakage Risks from Geologic Carbon Sequestration: Impact on Carbon Capture and Storage Energy Market Competitiveness

    SciTech Connect (OSTI)

    Peters, Catherine; Fitts, Jeffrey; Wilson, Elizabeth; Pollak, Melisa; Bielicki, Jeffrey; Bhatt, Vatsal

    2013-03-13

    This three-year project, performed by Princeton University in partnership with the University of Minnesota and Brookhaven National Laboratory, examined geologic carbon sequestration in regard to CO{sub 2} leakage and potential subsurface liabilities. The research resulted in basin-scale analyses of CO{sub 2} and brine leakage in light of uncertainties in the characteristics of leakage processes, and generated frameworks to monetize the risks of leakage interference with competing subsurface resources. The geographic focus was the Michigan sedimentary basin, for which a 3D topographical model was constructed to represent the hydrostratigraphy. Specifically for Ottawa County, a statistical analysis of the hydraulic properties of underlying sedimentary formations was conducted. For plausible scenarios of injection into the Mt. Simon sandstone, leakage rates were estimated and fluxes into shallow drinking-water aquifers were found to be less than natural analogs of CO{sub 2} fluxes. We developed the Leakage Impact Valuation (LIV) model in which we identified stakeholders and estimated costs associated with leakage events. It was found that costs could be incurred even in the absence of legal action or other subsurface interference because there are substantial costs of finding and fixing the leak and from injection interruption. We developed a model framework called RISCS, which can be used to predict monetized risk of interference with subsurface resources by combining basin-scale leakage predictions with the LIV method. The project has also developed a cost calculator called the Economic and Policy Drivers Module (EPDM), which comprehensively calculates the costs of carbon sequestration and leakage, and can be used to examine major drivers for subsurface leakage liabilities in relation to specific injection scenarios and leakage events. Finally, we examined the competiveness of CCS in the energy market. This analysis, though qualitative, shows that financial incentives, such as a carbon tax, are needed for coal combustion with CCS to gain market share. In another part of the project we studied the role of geochemical reactions in affecting the probability of CO{sub 2} leakage. A basin-scale simulation tool was modified to account for changes in leakage rates due to permeability alterations, based on simplified mathematical rules for the important geochemical reactions between acidified brines and caprock minerals. In studies of reactive flows in fractured caprocks, we examined the potential for permeability increases, and the extent to which existing reactive transport models would or would not be able to predict it. Using caprock specimens from the Eau Claire and Amherstburg, we found that substantial increases in permeability are possible for caprocks that have significant carbonate content, but minimal alteration is expected otherwise. We also found that while the permeability increase may be substantial, it is much less than what would be predicted from hydrodynamic models based on mechanical aperture alone because the roughness that is generated tends to inhibit flow.

  10. Maximizing Storage Rate and Capacity and Insuring the Environmental Integrity of Carbon Dioxide Sequestration in Geological Reservoirs

    SciTech Connect (OSTI)

    L.A. Davis; A.L. Graham; H.W. Parker; J.R. Abbott; M.S. Ingber; A.A. Mammoli; L.A. Mondy; Quanxin Guo; Ahmed Abou-Sayed

    2005-12-07

    Maximizing Storage Rate and Capacity and Insuring the Environmental Integrity of Carbon Dioxide Sequestration in Geological Formations The U.S. and other countries may enter into an agreement that will require a significant reduction in CO2 emissions in the medium to long term. In order to achieve such goals without drastic reductions in fossil fuel usage, CO2 must be removed from the atmosphere and be stored in acceptable reservoirs. The research outlined in this proposal deals with developing a methodology to determine the suitability of a particular geologic formation for the long-term storage of CO2 and technologies for the economical transfer and storage of CO2 in these formations. A novel well-logging technique using nuclear-magnetic resonance (NMR) will be developed to characterize the geologic formation including the integrity and quality of the reservoir seal (cap rock). Well-logging using NMR does not require coring, and hence, can be performed much more quickly and efficiently. The key element in the economical transfer and storage of the CO2 is hydraulic fracturing the formation to achieve greater lateral spreads and higher throughputs of CO2. Transport, compression, and drilling represent the main costs in CO2 sequestration. The combination of well-logging and hydraulic fracturing has the potential of minimizing these costs. It is possible through hydraulic fracturing to reduce the number of injection wells by an order of magnitude. Many issues will be addressed as part of the proposed research to maximize the storage rate and capacity and insure the environmental integrity of CO2 sequestration in geological formations. First, correlations between formation properties and NMR relaxation times will be firmly established. A detailed experimental program will be conducted to determine these correlations. Second, improved hydraulic fracturing models will be developed which are suitable for CO2 sequestration as opposed to enhanced oil recovery (EOR). Although models that simulate the fracturing process exist, they can be significantly improved by extending the models to account for nonsymmetric, nonplanar fractures, coupling the models to more realistic reservoir simulators, and implementing advanced multiphase flow models for the transport of proppant. Third, it may be possible to deviate from current hydraulic fracturing technology by using different proppants (possibly waste materials that need to be disposed of, e.g., asbestos) combined with different hydraulic fracturing carrier fluids (possibly supercritical CO2 itself). Because current technology is mainly aimed at enhanced oil recovery, it may not be ideally suited for the injection and storage of CO2. Finally, advanced concepts such as increasing the injectivity of the fractured geologic formations through acidization with carbonated water will be investigated. Saline formations are located through most of the continental United States. Generally, where saline formations are scarce, oil and gas reservoirs and coal beds abound. By developing the technology outlined here, it will be possible to remove CO2 at the source (power plants, industry) and inject it directly into nearby geological formations, without releasing it into the atmosphere. The goal of the proposed research is to develop a technology capable of sequestering CO2 in geologic formations at a cost of US $10 per ton.

  11. Summary Report on CO2 Geologic Sequestration & Water Resources Workshop

    E-Print Network [OSTI]

    Varadharajan, C.

    2013-01-01

    CCS) Regional Carbon Sequestration Partnerships Developingof seven Regional Carbon Sequestration Partnerships (RCSPs)RCSP’s, the Regional Carbon Sequestration Partnerships are

  12. Big Sky Carbon Sequestration Partnership

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2005-11-01

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership in Phase I fall into four areas: evaluation of sources and carbon sequestration sinks that will be used to determine the location of pilot demonstrations in Phase II; development of GIS-based reporting framework that links with national networks; designing an integrated suite of monitoring, measuring, and verification technologies and assessment frameworks; and initiating a comprehensive education and outreach program. The groundwork is in place to provide an assessment of storage capabilities for CO2 utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research agenda in Carbon Sequestration. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other DOE regional partnerships. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the Partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long-term viability. Scientifically sound MMV is critical for public acceptance of these technologies. Deliverables for the 7th Quarter reporting period include (1) for the geological efforts: Reports on Technology Needs and Action Plan on the Evaluation of Geological Sinks and Pilot Project Deployment (Deliverables 2 and 3), and Report on the Feasibility of Mineralization Trapping in the Snake River Plain Basin (Deliverable 14); (2) for the terrestrial efforts: Report on the Evaluation of Terrestrial Sinks and a Report of the Best Production Practices for Soil C Sequestration (Deliverables 8 and 15). In addition, the 7th Quarter activities for the Partnership included further development of the proposed activities for the deployment and demonstration phase of the carbon sequestration pilots including geological and terrestrial pilots, expansion of the Partnership to encompass regions and institutions that are complimentary to the steps we have identified, building greater collaborations with industry and stakeholders in the region, contributed to outreach efforts that spanned all partnerships, co-authorship on the Carbon Capture and Separation report, and developed a regional basis to address future energy opportunities in the region. The deliverables and activities are discussed in the following sections and appended to this report. The education and outreach efforts have resulted in a comprehensive plan which serves as a guide for implementing the outreach activities under Phase I. The public website has been expanded and integrated with the GIS carbon atlas. We have made presentations to stakeholders and policy makers including two tribal sequestration workshops, and made connections to other federal and state agencies concerned with GHG emissions, climate change, and efficient and environmental

  13. Preliminary Geologic Characterization of West Coast States for Geologic Sequestration

    SciTech Connect (OSTI)

    Larry Myer

    2005-09-29

    Characterization of geological sinks for sequestration of CO{sub 2} in California, Nevada, Oregon, and Washington was carried out as part of Phase I of the West Coast Regional Carbon Sequestration Partnership (WESTCARB) project. Results show that there are geologic storage opportunities in the region within each of the following major technology areas: saline formations, oil and gas reservoirs, and coal beds. The work focused on sedimentary basins as the initial most-promising targets for geologic sequestration. Geographical Information System (GIS) layers showing sedimentary basins and oil, gas, and coal fields in those basins were developed. The GIS layers were attributed with information on the subsurface, including sediment thickness, presence and depth of porous and permeable sandstones, and, where available, reservoir properties. California offers outstanding sequestration opportunities because of its large capacity and the potential of value-added benefits from enhanced oil recovery (EOR) and enhanced gas recovery (EGR). The estimate for storage capacity of saline formations in the ten largest basins in California ranges from about 150 to about 500 Gt of CO{sub 2}, depending on assumptions about the fraction of the formations used and the fraction of the pore volume filled with separate-phase CO{sub 2}. Potential CO{sub 2}-EOR storage was estimated to be 3.4 Gt, based on a screening of reservoirs using depth, an API gravity cutoff, and cumulative oil produced. The cumulative production from gas reservoirs (screened by depth) suggests a CO{sub 2} storage capacity of 1.7 Gt. In Oregon and Washington, sedimentary basins along the coast also offer sequestration opportunities. Of particular interest is the Puget Trough Basin, which contains up to 1,130 m (3,700 ft) of unconsolidated sediments overlying up to 3,050 m (10,000 ft) of Tertiary sedimentary rocks. The Puget Trough Basin also contains deep coal formations, which are sequestration targets and may have potential for enhanced coal bed methane recovery (ECBM).

  14. Experimental Study of Carbon Sequestration Reactions Controlled

    E-Print Network [OSTI]

    Demouchy, Sylvie

    Experimental Study of Carbon Sequestration Reactions Controlled by the Percolation of CO2-Rich. Carbonation of ultramafic rocks in geological reservoirs is, in theory, the most efficient way to trap CO2 irreversibly; however, possible feedback effects between carbonation reactions and changes in the reservoir

  15. Transport of Organic Contaminants Mobilized from Coal through Sandstone Overlying a Geological Carbon Sequestration Reservoir

    SciTech Connect (OSTI)

    Zhong, Lirong; Cantrell, Kirk J.; Bacon, Diana H.; Shewell, Jesse L.

    2014-02-01

    Column experiments were conducted using a wetted sandstone rock installed in a tri-axial core holder to study the flow and transport of organic compounds mobilized by scCO2 under simulated geologic carbon storage (GCS) conditions. The sandstone rock was collected from a formation overlying a deep saline reservoir at a GCS demonstration site. Rock core effluent pressures were set at 0, 500, or 1000 psig and the core temperature was set at 20 or 50°C to simulate the transport to different subsurface depths. The concentrations of the organic compounds in the column effluent and their distribution within the sandstone core were monitored. Results indicate that the mobility though the core sample was much higher for BTEX compounds than for naphthalene. Retention of organic compounds from the vapor phase to the core appeared to be primarily controlled by partitioning from the vapor phase to the aqueous phase. Adsorption to the surfaces of the wetted sandstone was also significant for naphthalene. Reduced temperature and elevated pressure resulted in greater partitioning of the mobilized organic contaminants into the water phase.

  16. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2004-10-31

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership fall into four areas: evaluation of sources and carbon sequestration sinks; development of GIS-based reporting framework; designing an integrated suite of monitoring, measuring, and verification technologies; and initiating a comprehensive education and outreach program. At the first two Partnership meetings the groundwork was put in place to provide an assessment of capture and storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. During the third quarter, planning efforts are underway for the next Partnership meeting which will showcase the architecture of the GIS framework and initial results for sources and sinks, discuss the methods and analysis underway for assessing geological and terrestrial sequestration potentials. The meeting will conclude with an ASME workshop. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. Efforts are also being made to find funding to include Wyoming in the coverage areas for both geological and terrestrial sinks and sources. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts begun in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the Partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long-term viability. Scientifically sound information on MMV is critical for public acceptance of these technologies. Two key deliverables were completed in the second quarter--a literature review/database to assess the soil carbon on rangelands, and the draft protocols, contracting options for soil carbon trading. The protocols developed for soil carbon trading are unique and provide a key component of the mechanisms that might be used to efficiently sequester GHG and reduce CO{sub 2} concentrations. While no key deliverables were due during the third quarter, progress on other deliverables is noted in the PowerPoint presentations and in this report. A series of meetings held during the second and third quarters have laid the foundations for assessing the issues surrounding carbon sequestration in this region, the need for a holistic approach to meeting energy demands and economic development potential, and the implementation of government programs or a market-based setting for soil C credits. These meetings provide a connection to stakeholders in the region and a basis on which to draw for the DOE PEIS hearings. In the fourth quarter, three deliverables have been completed, some in draft form to be revised and updated to include Wyoming. This is due primarily to some delays in funding to LANL and INEEL and the approval of a supplemental proposal to include Wyoming in much of the GIS data sets, analysis, and related materials. The de

  17. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2004-06-30

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership fall into four areas: evaluation of sources and carbon sequestration sinks; development of GIS-based reporting framework; designing an integrated suite of monitoring, measuring, and verification technologies; and initiating a comprehensive education and outreach program. At the first two Partnership meetings the groundwork was put in place to provide an assessment of capture and storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. During the third quarter, planning efforts are underway for the next Partnership meeting which will showcase the architecture of the GIS framework and initial results for sources and sinks, discuss the methods and analysis underway for assessing geological and terrestrial sequestration potentials. The meeting will conclude with an ASME workshop (see attached agenda). The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. Efforts are also being made to find funding to include Wyoming in the coverage areas for both geological and terrestrial sinks and sources. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts begun in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the Partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long-term viability. Scientifically sound information on MMV is critical for public acceptance of these technologies. Two key deliverables were completed in the second quarter--a literature review/database to assess the soil carbon on rangelands, and the draft protocols, contracting options for soil carbon trading. The protocols developed for soil carbon trading are unique and provide a key component of the mechanisms that might be used to efficiently sequester GHG and reduce CO2 concentrations. While no key deliverables were due during the third quarter, progress on other deliverables is noted in the PowerPoint presentations and in this report. A series of meetings held during the second and third quarters have laid the foundations for assessing the issues surrounding carbon sequestration in this region, the need for a holistic approach to meeting energy demands and economic development potential, and the implementation of government programs or a market-based setting for soil C credits. These meetings provide a connection to stakeholders in the region and a basis on which to draw for the DOE PEIS hearings. A third Partnership meeting has been planned for August 04 in Idaho Falls; a preliminary agenda is attached.

  18. The role of optimality in characterizing CO2 seepage from geological carbon sequestration sites

    SciTech Connect (OSTI)

    Cortis, Andrea; Oldenburg, Curtis M.; Benson, Sally M.

    2008-09-15

    Storage of large amounts of carbon dioxide (CO{sub 2}) in deep geological formations for greenhouse gas mitigation is gaining momentum and moving from its conceptual and testing stages towards widespread application. In this work we explore various optimization strategies for characterizing surface leakage (seepage) using near-surface measurement approaches such as accumulation chambers and eddy covariance towers. Seepage characterization objectives and limitations need to be defined carefully from the outset especially in light of large natural background variations that can mask seepage. The cost and sensitivity of seepage detection are related to four critical length scales pertaining to the size of the: (1) region that needs to be monitored; (2) footprint of the measurement approach, and (3) main seepage zone; and (4) region in which concentrations or fluxes are influenced by seepage. Seepage characterization objectives may include one or all of the tasks of detecting, locating, and quantifying seepage. Each of these tasks has its own optimal strategy. Detecting and locating seepage in a region in which there is no expected or preferred location for seepage nor existing evidence for seepage requires monitoring on a fixed grid, e.g., using eddy covariance towers. The fixed-grid approaches needed to detect seepage are expected to require large numbers of eddy covariance towers for large-scale geologic CO{sub 2} storage. Once seepage has been detected and roughly located, seepage zones and features can be optimally pinpointed through a dynamic search strategy, e.g., employing accumulation chambers and/or soil-gas sampling. Quantification of seepage rates can be done through measurements on a localized fixed grid once the seepage is pinpointed. Background measurements are essential for seepage detection in natural ecosystems. Artificial neural networks are considered as regression models useful for distinguishing natural system behavior from anomalous behavior suggestive of CO{sub 2} seepage without need for detailed understanding of natural system processes. Because of the local extrema in CO{sub 2} fluxes and concentrations in natural systems, simple steepest-descent algorithms are not effective and evolutionary computation algorithms are proposed as a paradigm for dynamic monitoring networks to pinpoint CO{sub 2} seepage areas.

  19. Laboratory Investigations in Support of Carbon Dioxide-in-Water Emulsions Stabilized by Fine Particles for Ocean and Geologic Sequestration of Carbon Dioxide

    SciTech Connect (OSTI)

    Dan Golomb; David Ryan; Eugene Barry

    2007-01-08

    Since the submission of our last Semi-annual Report, dated September 2006, the research objectives of this Co-operative Agreement shifted toward geologic sequestration of carbon dioxide. In the period September 2006-February 2007, experiments were conducted in a High-Pressure Batch Reactor (HPBR) for creating emulsions of liquid carbon dioxide (/CO{sub 2})-in-water stabilized by fine particles for geologic sequestration of CO{sub 2}. Also, emulsions were created in water of a binary mixture of liquid carbon dioxide and liquid hydrogen sulfide (/H{sub 2}S), called Acid Gas (AG). This leads to the possibility of safe disposal of AG in deep geologic formations, such as saline aquifers. The stabilizing particles included pulverized limestone (CaCO{sub 3}), unprocessed flyash, collected by an electrostatic precipitator at a local coal-fired power plant, and pulverized siderite (FeCO{sub 3}). Particle size ranged from submicron to a few micrometers. The first important finding is that /CO{sub 2} and /H{sub 2}S freely mix as a binary liquid without phase separation. The next finding is that the mixture of /CO{sub 2} and /H{sub 2}S can be emulsified in water using fine particles as emulsifying agents. Such emulsions are stable over prolonged periods, so it should not be a problem to inject an emulsion into subterranean formations. The advantage of injecting an emulsion into subterranean formations is that it is denser than the pure liquid, therefore it is likely to disperse in the bottom of the geologic formation, rather than buoying upward (called fingering). In such a fashion, the risk of the liquids escaping from the formation, and possibly re-emerging into the atmosphere, is minimized. This is especially important for H{sub 2}S, because it is a highly toxic gas. Furthermore, the emulsion may interact with the surrounding minerals, causing mineral trapping. This may lead to longer sequestration periods than injecting the pure liquids alone.

  20. Uncertainty quantification for the impact of injection rate fluctuation on the geomechanical response of geological carbon sequestration

    SciTech Connect (OSTI)

    Bao, Jie; Chu, Yanjun; Xu, Zhijie; Tartakovsky, Alexandre M.; Fang, Yilin

    2014-02-02

    We present an analysis of the geomechanical effects of injection rate fluctuations for geological sequestration of carbon dioxide (CO2). Initially, we present analytical solutions for the effects of injection rate fluctuations on CO2 fluid pressure spatial distribution and temporal evolution for a typical injection scenario. Numerical calculations are performed using a finite element method to investigate the effects of injection rate fluctuations on geomechanical deformation, stresses, and potential failure of the aquifer and caprock layers. The numerical method was first validated by the fluid pressure distribution’s good agreement with the analytical solution. It was shown that for any Gaussian fluctuations of injection rate Q with given mean Q ? and variance ?_Q, the coefficients of variance for fluid pressure (?_p=?_p?p ? ), deformation (?_u=?_u?u ? ), and stresses (?_?=?_??? ? ) increase linearly with the coefficient of variance for injection rate (?_Q=?_Q?Q ? ). The proportional constants are identified, and the fluctuations have the most pronounced effect on the geomechanical stresses, and, therefore, on the potential failure of the aquifer and caprock layers. Instead of expensive computational simulation, this study provides an efficient tool to estimate the geomechanical response variance to injection rate fluctuation. A failure analysis was presented based on the numerical results, where probability of failure was estimated for fluctuating injection rates with different mean and variance during the entire injection period. It was found that with increasing injection rate fluctuation, the failure probability increases significantly. Therefore, the risk associated with injection rate fluctuations should be carefully evaluated.?

  1. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2004-01-04

    The Big Sky Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts during the first performance period fall into four areas: evaluation of sources and carbon sequestration sinks; development of GIS-based reporting framework; designing an integrated suite of monitoring, measuring, and verification technologies; and initiating a comprehensive education and outreach program. At the first Partnership meeting the groundwork was put in place to provide an assessment of capture and storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Complementary to the efforts on evaluation of sources and sinks is the development of the Big Sky Partnership Carbon Cyberinfrastructure (BSP-CC) and a GIS Road Map for the Partnership. These efforts will put in place a map-based integrated information management system for our Partnership, with transferability to the national carbon sequestration effort. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but other policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts begun in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long term viability. A series of meetings held in November and December, 2003, have laid the foundations for assessing the issues surrounding the implementation of a market-based setting for soil C credits. These include the impact of existing local, state, and federal permitting issues for terrestrial based carbon sequestration projects, consistency of final protocols and planning standards with national requirements, and alignments of carbon sequestration projects with existing federal and state cost-share programs. Finally, the education and outreach efforts during this performance period have resulted in a comprehensive plan which serves as a guide for implementing the outreach activities under Phase I. The primary goal of this plan is to increase awareness, understanding, and public acceptance of sequestration efforts and build support for a constituent based network which includes the initial Big Sky Partnership and other local and regional businesses and entities.

  2. Geologic carbon sequestration as a global strategy to mitigate CO2 emissions: Sustainability and environmental risk

    SciTech Connect (OSTI)

    Oldenburg, C.M.

    2011-04-01

    Fossil fuels are abundant, inexpensive to produce, and are easily converted to usable energy by combustion as demonstrated by mankind's dependence on fossil fuels for over 80% of its primary energy supply (13). This reliance on fossil fuels comes with the cost of carbon dioxide (CO{sub 2}) emissions that exceed the rate at which CO{sub 2} can be absorbed by terrestrial and oceanic systems worldwide resulting in increases in atmospheric CO{sub 2} concentration as recorded by direct measurements over more than five decades (14). Carbon dioxide is the main greenhouse gas linked to global warming and associated climate change, the impacts of which are currently being observed around the world, and projections of which include alarming consequences such as water and food shortages, sea level rise, and social disruptions associated with resource scarcity (15). The current situation of a world that derives the bulk of its energy from fossil fuel in a manner that directly causes climate change equates to an energy-climate crisis. Although governments around the world have only recently begun to consider policies to avoid the direst projections of climate change and its impacts, sustainable approaches to addressing the crisis are available. The common thread of feasible strategies to the energy climate crisis is the simultaneous use of multiple approaches based on available technologies (e.g., 16). Efficiency improvements (e.g., in building energy use), increased use of natural gas relative to coal, and increased development of renewables such as solar, wind, and geothermal, along with nuclear energy, are all available options that will reduce net CO{sub 2} emissions. While improvements in efficiency can be made rapidly and will pay for themselves, the slower pace of change and greater monetary costs associated with increased use of renewables and nuclear energy suggests an additional approach is needed to help bridge the time period between the present and a future when low-carbon energy is considered cheap enough to replace fossil fuels. Carbon dioxide capture and storage (CCS) is one such bridging technology (1). CCS has been the focus of an increasing amount of research over the last 15-20 years and is the subject of a comprehensive IPCC report that thoroughly covers the subject (1). CCS is currently being carried out in several countries around the world in conjunction with natural gas extraction (e.g., 2, 3) and enhanced oil recovery (17). Despite this progress, widespread deployment of CCS remains the subject of research and future plans rather than present action on the scale needed to mitigate emissions from the perspective of climate change. The reasons for delay in deploying CCS more widely are concerns about cost (18), regulatory and legal uncertainty (19), and potential environmental impacts (21). This chapter discusses the long-term (decadal) sustainability and environmental hazards associated with the geologic CO{sub 2} storage (GCS) component of large-scale CCS (e.g., 20). Discussion here barely touches on capture and transport of CO{sub 2} which will occur above ground and which are similar to existing engineering, chemical processing, and pipeline transport activities and are therefore easier to evaluate with respect to risk assessment and feasibility. The focus of this chapter is on the more uncertain part of CCS, namely geologic storage. The primary concern for sustainability of GCS is whether there is sufficient capacity in sedimentary basins worldwide to contain the large of amounts of CO{sub 2} needed to address climate change. But there is also a link between sustainability and environmental impacts. Specifically, if GCS is found to cause unacceptable impacts that are considered worse than its climate-change mitigation benefits, the approach will not be widely adopted. Hence, GCS has elements of sustainability insofar as capacity of the subsurface for CO{sub 2} is concerned, and also in terms of whether the associated environmental risks are acceptable or not to the public.

  3. Relevance of underground natural gas storage to geologic sequestration of carbon dioxide

    E-Print Network [OSTI]

    Lippmann, Marcelo J.; Benson, Sally M.

    2002-01-01

    2002). U.S. Natural Gas Storage. http://www.eia.doe.gov/oil_OF UNDERGROUND NATURAL GAS STORAGE TO GEOLOGIC SEQUESTRATIONof underground natural gas storage (UNGS), which started in

  4. Big Sky Carbon Sequestration Partnership

    SciTech Connect (OSTI)

    Susan Capalbo

    2005-12-31

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership in Phase I are organized into four areas: (1) Evaluation of sources and carbon sequestration sinks that will be used to determine the location of pilot demonstrations in Phase II; (2) Development of GIS-based reporting framework that links with national networks; (3) Design of an integrated suite of monitoring, measuring, and verification technologies, market-based opportunities for carbon management, and an economic/risk assessment framework; (referred to below as the Advanced Concepts component of the Phase I efforts) and (4) Initiation of a comprehensive education and outreach program. As a result of the Phase I activities, the groundwork is in place to provide an assessment of storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that complements the ongoing DOE research agenda in Carbon Sequestration. The geology of the Big Sky Carbon Sequestration Partnership Region is favorable for the potential sequestration of enormous volume of CO{sub 2}. The United States Geological Survey (USGS 1995) identified 10 geologic provinces and 111 plays in the region. These provinces and plays include both sedimentary rock types characteristic of oil, gas, and coal productions as well as large areas of mafic volcanic rocks. Of the 10 provinces and 111 plays, 1 province and 4 plays are located within Idaho. The remaining 9 provinces and 107 plays are dominated by sedimentary rocks and located in the states of Montana and Wyoming. The potential sequestration capacity of the 9 sedimentary provinces within the region ranges from 25,000 to almost 900,000 million metric tons of CO{sub 2}. Overall every sedimentary formation investigated has significant potential to sequester large amounts of CO{sub 2}. Simulations conducted to evaluate mineral trapping potential of mafic volcanic rock formations located in the Idaho province suggest that supercritical CO{sub 2} is converted to solid carbonate mineral within a few hundred years and permanently entombs the carbon. Although MMV for this rock type may be challenging, a carefully chosen combination of geophysical and geochemical techniques should allow assessment of the fate of CO{sub 2} in deep basalt hosted aquifers. Terrestrial carbon sequestration relies on land management practices and technologies to remove atmospheric CO{sub 2} where it is stored in trees, plants, and soil. This indirect sequestration can be implemented today and is on the front line of voluntary, market-based approaches to reduce CO{sub 2} emissions. Initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil Carbon (C) on rangelands, and forested, agricultural, and reclaimed lands. Rangelands can store up to an additional 0.05 mt C/ha/yr, while the croplands are on average four times that amount. Estimates of technical potential for soil sequestration within the region in cropland are in the range of 2.0 M mt C/yr over 20 year time horizon. This is equivalent to approximately 7.0 M mt CO{sub 2}e/yr. The forestry sinks are well documented, and the potential in the Big Sky region ranges from 9-15 M mt CO{sub 2} equivalent per year. Value-added benefits include enhanced yields, reduced erosion, and increased wildlife habitat. Thus the terrestrial sinks provide a viable, environmentally beneficial, and relatively low cost sink that is available to sequester C in the current time frame. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts in developing and implementing MMV technologies for geological and terrestrial sequestration re

  5. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2005-01-31

    The Big Sky Carbon Sequestration Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts under this Partnership in Phase I fall into four areas: evaluation of sources and carbon sequestration sinks that will be used to determine the location of pilot demonstrations in Phase II; development of GIS-based reporting framework that links with national networks; designing an integrated suite of monitoring, measuring, and verification technologies and assessment frameworks; and initiating a comprehensive education and outreach program. The groundwork is in place to provide an assessment of storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. Efforts are underway to showcase the architecture of the GIS framework and initial results for sources and sinks. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the Partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long-term viability. Scientifically sound information on MMV is critical for public acceptance of these technologies.

  6. Site Development, Operations, and Closure Plan Topical Report 5 An Assessment of Geologic Carbon Sequestration Options in the Illinois Basin. Phase III

    SciTech Connect (OSTI)

    Finley, Robert; Payne, William; Kirksey, Jim

    2015-06-01

    The Midwest Geological Sequestration Consortium (MGSC) has partnered with Archer Daniels Midland Company (ADM) and Schlumberger Carbon Services to conduct a large-volume, saline reservoir storage project at ADM’s agricultural products processing complex in Decatur, Illinois. The Development Phase project, named the Illinois Basin Decatur Project (IBDP) involves the injection of 1 million tonnes of carbon dioxide (CO2) into a deep saline formation of the Illinois Basin over a three-year period. This report focuses on objectives, execution, and lessons learned/unanticipated results from the site development (relating specifically to surface equipment), operations, and the site closure plan.

  7. Carbon Sequestration Advisory Committee (Nebraska)

    Broader source: Energy.gov [DOE]

    Under this statute, the Director of Natural Resources will document and quantify carbon sequestration and greenhouse emissions reductions associated with agricultural practices, management systems,...

  8. Carbon Sequestration Atlas IV Video

    ScienceCinema (OSTI)

    Rodosta, Traci

    2014-06-27

    The Carbon Sequestration Atlas is a collection of all the storage sites of CO2 such as, petroleum, natural gas, coal, and oil shale.

  9. Carbon Sequestration Atlas IV Video

    SciTech Connect (OSTI)

    Rodosta, Traci

    2013-04-19

    The Carbon Sequestration Atlas is a collection of all the storage sites of CO2 such as, petroleum, natural gas, coal, and oil shale.

  10. Leakage and Sepage of CO2 from Geologic Carbon SequestrationSites: CO2 Migration into Surface Water

    SciTech Connect (OSTI)

    Oldenburg, Curt M.; Lewicki, Jennifer L.

    2005-06-17

    Geologic carbon sequestration is the capture of anthropogenic carbon dioxide (CO{sub 2}) and its storage in deep geologic formations. One of the concerns of geologic carbon sequestration is that injected CO{sub 2} may leak out of the intended storage formation, migrate to the near-surface environment, and seep out of the ground or into surface water. In this research, we investigate the process of CO{sub 2} leakage and seepage into saturated sediments and overlying surface water bodies such as rivers, lakes, wetlands, and continental shelf marine environments. Natural CO{sub 2} and CH{sub 4} fluxes are well studied and provide insight into the expected transport mechanisms and fate of seepage fluxes of similar magnitude. Also, natural CO{sub 2} and CH{sub 4} fluxes are pervasive in surface water environments at levels that may mask low-level carbon sequestration leakage and seepage. Extreme examples are the well known volcanic lakes in Cameroon where lake water supersaturated with respect to CO{sub 2} overturned and degassed with lethal effects. Standard bubble formation and hydrostatics are applicable to CO{sub 2} bubbles in surface water. Bubble-rise velocity in surface water is a function of bubble size and reaches a maximum of approximately 30 cm s{sup -1} at a bubble radius of 0.7 mm. Bubble rise in saturated porous media below surface water is affected by surface tension and buoyancy forces, along with the solid matrix pore structure. For medium and fine grain sizes, surface tension forces dominate and gas transport tends to occur as channel flow rather than bubble flow. For coarse porous media such as gravels and coarse sand, buoyancy dominates and the maximum bubble rise velocity is predicted to be approximately 18 cm s{sup -1}. Liquid CO{sub 2} bubbles rise slower in water than gaseous CO{sub 2} bubbles due to the smaller density contrast. A comparison of ebullition (i.e., bubble formation) and resulting bubble flow versus dispersive gas transport for CO{sub 2} and CH{sub 4} at three different seepage rates reveals that ebullition and bubble flow will be the dominant form of gas transport in surface water for all but the smallest seepage fluxes or shallowest water bodies. The solubility of the gas species in water plays a fundamental role in whether ebullition occurs. We used a solubility model to examine CO{sub 2} solubility in waters with varying salinity as a function of depth below a 200 m-deep surface water body. In this system, liquid CO{sub 2} is stable between the deep regions where supercritical CO{sub 2} is stable and the shallow regions where gaseous CO{sub 2} is stable. The transition from liquid to gaseous CO{sub 2} is associated with a large change in density, with corresponding large change in bubble buoyancy. The solubility of CO{sub 2} is lower in high-salinity waters such as might be encountered in the deep subsurface. Therefore, as CO{sub 2} migrates upward through the deep subsurface, it will likely encounter less saline water with increasing capacity to dissolve CO{sub 2} potentially preventing ebullition, depending on the CO{sub 2} leakage flux. However, as CO{sub 2} continues to move upward through shallower depths, CO{sub 2} solubility in water decreases strongly leading to greater likelihood of ebullition and bubble flow in surface water. In the case of deep density-stratified lakes in which ebullition is suppressed, enhanced mixing and man-made degassing schemes can alleviate the buildup of CO{sub 2} and related risk of dangerous rapid discharges. Future research efforts are needed to increase understanding of CO{sub 2} leakage and seepage in surface water and saturated porous media. For example, we recommend experiments and field tests of CO{sub 2} migration in saturated systems to formulate bubble-driven water-displacement models and relative permeability functions that can be used in simulation models.

  11. Effect of Oxygen Co-Injected with Carbon Dioxide on Gothic Shale Caprock-CO2-Brine Interaction during Geologic Carbon Sequestration

    SciTech Connect (OSTI)

    Jung, Hun Bok; Um, Wooyong; Cantrell, Kirk J.

    2013-09-16

    Co-injection of oxygen, a significant component in CO2 streams produced by the oxyfuel combustion process, can cause a significant alteration of the redox state in deep geologic formations during geologic carbon sequestration. The potential impact of co-injected oxygen on the interaction between synthetic CO2-brine (0.1 M NaCl) and shale caprock (Gothic shale from the Aneth Unit in Utah) and mobilization of trace metals was investigated at ~10 MPa and ~75 °C. A range of relative volume percentages of O2 to CO2 (0, 1, 4 and 8%) were used in these experiments to address the effect of oxygen on shale-CO2-brine interaction under various conditions. Major mineral phases in Gothic shale are quartz, calcite, dolomite, montmorillonite, and pyrite. During Gothic shale-CO2-brine interaction in the presence of oxygen, pyrite oxidation occurred extensively and caused enhanced dissolution of calcite and dolomite. Pyrite oxidation and calcite dissolution subsequently resulted in the precipitation of Fe(III) oxides and gypsum (CaSO4•2H2O). In the presence of oxygen, dissolved Mn and Ni were elevated because of oxidative dissolution of pyrite. The mobility of dissolved Ba was controlled by barite (BaSO4) precipitation in the presence of oxygen. Dissolved U in the experimental brines increased to ~8–14 ?g/L, with concentrations being slightly higher in the absence of oxygen than in the presence of oxygen. Experimental and modeling results indicate the interaction between shale caprock and oxygen co-injected with CO2 during geologic carbon sequestration can exert significant impacts on brine pH, solubility of carbonate minerals, stability of sulfide minerals, and mobility of trace metals. The major impact of oxygen is most likely to occur in the zone near CO2 injection wells where impurity gases can accumulate. Oxygen in CO2-brine migrating away from the injection well will be continually consumed through the reactions with sulfide minerals in deep geologic formations.

  12. Geological Sequestration of CO2 by Hydrous Carbonate Formation with Reclaimed Slag

    SciTech Connect (OSTI)

    Von L. Richards; Kent Peaslee; Jeffrey Smith

    2008-02-06

    The concept of this project is to develop a process that improves the kinetics of the hydrous carbonate formation reaction enabling steelmakers to directly remove CO2 from their furnace exhaust gas. It is proposed to bring the furnace exhaust stream containing CO2 in contact with reclaimed steelmaking slag in a reactor that has an environment near the unit activity of water resulting in the production of carbonates. The CO2 emissions from the plant would be reduced by the amount sequestered in the formation of carbonates. The main raw materials for the process are furnace exhaust gases and specially prepared slag.

  13. Geologic carbon dioxide sequestration from the Mexican oil industry : an action plan

    E-Print Network [OSTI]

    Lacy, Rodolfo

    2005-01-01

    Climate change has become an important focus of international environmental negotiations. In response, global energy corporations have been looking for practical ways of reducing their industrial carbon dioxide (CO?) ...

  14. Optimize carbon dioxide sequestration, enhance oil recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Optimize carbon dioxide sequestration, enhance oil recovery Optimize carbon dioxide sequestration, enhance oil recovery The simulation provides an important approach to estimate...

  15. DOE's Carbon Sequestration Partnership Program Adds Canadian...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE's Carbon Sequestration Partnership Program Adds Canadian Provinces DOE's Carbon Sequestration Partnership Program Adds Canadian Provinces February 16, 2005 - 10:14am Addthis...

  16. Carbon Sequestration Conference | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Carbon Sequestration Conference Carbon Sequestration Conference May 9, 2006 - 10:37am Addthis Remarks Prepared for Energy Secretary Samuel Bodman Thank you. It's a pleasure for me...

  17. SciTech Connect: "carbon sequestration"

    Office of Scientific and Technical Information (OSTI)

    carbon sequestration" Find + Advanced Search Term Search Semantic Search Advanced Search All Fields: "carbon sequestration" Semantic Semantic Term Title: Full Text:...

  18. Simulating Geologic Co-sequestration of Carbon Dioxide and Hydrogen Sulfide in a Basalt Formation

    SciTech Connect (OSTI)

    Bacon, Diana H.; Ramanathan, Ramya; Schaef, Herbert T.; McGrail, B. Peter

    2014-01-15

    Co-sequestered CO2 with H2S impurities could affect geologic storage, causing changes in pH and oxidation state that affect mineral dissolution and precipitation reactions and the mobility of metals present in the reservoir rocks. We have developed a variable component, non-isothermal simulator, STOMP-COMP (Water, Multiple Components, Salt and Energy), which simulates multiphase flow gas mixtures in deep saline reservoirs, and the resulting reactions with reservoir minerals. We use this simulator to model the co-injection of CO2 and H2S into brecciated basalt flow top. A 1000 metric ton injection of these supercritical fluids, with 99% CO2 and 1% H2S, is sequestered rapidly by solubility and mineral trapping. CO2 is trapped mainly as calcite within a few decades and H2S is trapped as pyrite within several years.

  19. Key factors for determining groundwater impacts due to leakage from geologic carbon sequestration reservoirs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Carroll, Susan A.; Keating, Elizabeth; Mansoor, Kayyum; Dai, Zhenxue; Sun, Yunwei; Trainor-Guitton, Whitney; Brown, Chris; Bacon, Diana

    2014-09-07

    The National Risk Assessment Partnership (NRAP) is developing a science-based toolset for the analysis of potential impacts to groundwater chemistry from CO2 injection (www.netldoe.gov/nrap). The toolset adopts a stochastic approach in which predictions address uncertainties in shallow groundwater and leakage scenarios. It is derived from detailed physics and chemistry simulation results that are used to train more computationally efficient models, referred to here as reduced-order models (ROMs), for each component system. In particular, these tools can be used to help regulators and operators understand the expected sizes and longevity of plumes in pH, TDS, and dissolved metals that could resultmore »from a leakage of brine and/or CO2 from a storage reservoir into aquifers. This information can inform, for example, decisions on monitoring strategies that are both effective and efficient. We have used this approach to develop predictive reduced-order models for two common types of reservoirs, but the approach could be used to develop a model for a specific aquifer or other common types of aquifers. In this paper we describe potential impacts to groundwater quality due to CO2 and brine leakage, discuss an approach to calculate thresholds under which no impact to groundwater occurs, describe the time scale for impact on groundwater, and discuss the probability of detecting a groundwater plume should leakage occur. To facilitate this, multi-phase flow and reactive transport simulations and emulations were developed for two classes of aquifers, considering uncertainty in leakage source terms and aquifer hydrogeology. We targeted an unconfined fractured carbonate aquifer based on the Edwards aquifer in Texas and a confined alluvium aquifer based on the High Plains Aquifer in Kansas, which share characteristics typical of many drinking water aquifers in the United States. The hypothetical leakage scenarios centered on the notion that wellbores are the most likely conduits for brine and CO2 leaks. Leakage uncertainty was based on hypothetical injection of CO2 for 50 years at a rate of 5 million tons per year into a depleted oil/gas reservoir with high permeability and, one or more wells provided leakage pathways from the storage reservoir to the overlying aquifer. This scenario corresponds to a storage site with historical oil/gas production and some poorly completed legacy wells that went undetected through site evaluation, operations, and post-closure. For the aquifer systems and leakage scenarios studied here, CO2 and brine leakage are likely to drive pH below and increase total dissolved solids (TDS) above the “no-impact thresholds;” and the subsequent plumes, although small, are likely to persist for long periods of time in the absence of remediation. In these scenarios, however, risk to human health may not be significant for two reasons. First, our simulated plume volumes are much smaller than the average inter-well spacing for these representative aquifers, so the impacted groundwater would be unlikely to be pumped for drinking water. Second, even within the impacted plume volumes little water exceeds the primary maximum contamination levels.« less

  20. Key factors for determining groundwater impacts due to leakage from geologic carbon sequestration reservoirs

    SciTech Connect (OSTI)

    Carroll, Susan A.; Keating, Elizabeth; Mansoor, Kayyum; Dai, Zhenxue; Sun, Yunwei; Trainor-Guitton, Whitney; Brown, Christopher F.; Bacon, Diana H.

    2014-10-01

    The National Risk Assessment Partnership (NRAP) is developing a science-based toolset for the analysis of potential impacts to groundwater chemistry from CO2 injection (www.netldoe.gov/nrap). The toolset adopts a stochastic approach in which predictions address uncertainties in shallow groundwater and leakage scenarios. It is derived from detailed physics and chemistry simulation results that are used to train more computationally efficient models, referred to here as reduced-order models (ROMs), for each component system. In particular, these tools can be used to help regulators and operators understand the expected sizes and longevity of plumes in pH, TDS, and dissolved metals that could result from a leakage of brine and/or CO2 from a storage reservoir into aquifers. This information can inform, for example, decisions on monitoring strategies that are both effective and efficient. We have used this approach to develop predictive reduced-order models for two common types of reservoirs, but the approach could be used to develop a model for a specific aquifer or other common types of aquifers. In this paper we describe potential impacts to groundwater quality due to CO2 and brine leakage, discuss an approach to calculate thresholds under which no impact to groundwater occurs, describe the time scale for impact on groundwater, and discuss the probability of detecting a groundwater plume should leakage occur. To facilitate this, multi-phase flow and reactive transport simulations and emulations were developed for two classes of aquifers, considering uncertainty in leakage source terms and aquifer hydrogeology. We targeted an unconfined fractured carbonate aquifer based on the Edwards aquifer in Texas and a confined alluvium aquifer based on the High Plains Aquifer in Kansas, which share characteristics typical of many drinking water aquifers in the United States. The hypothetical leakage scenarios centered on the notion that wellbores are the most likely conduits for brine and CO2 leaks. Leakage uncertainty was based on hypothetical injection of CO2 for 50 years at a rate of 5 million tons per year into a depleted oil/gas reservoir with high permeability and, one or more wells provided leakage pathways from the storage reservoir to the overlying aquifer. This scenario corresponds to a storage site with historical oil/gas production and some poorly completed legacy wells that went undetected through site evaluation, operations, and post-closure. For the aquifer systems and leakage scenarios studied here, CO2 and brine leakage are likely to drive pH below and increase total dissolved solids (TDS) above the “no-impact thresholds;” and the subsequent plumes, although small, are likely to persist for long periods of time in the absence of remediation. In these scenarios, however, risk to human health may not be significant for two reasons. First, our simulated plume volumes are much smaller than the average inter-well spacing for these representative aquifers, so the impacted groundwater would be unlikely to be pumped for drinking water. Second, even within the impacted plume volumes little water exceeds the primary maximum contamination levels.

  1. BIG SKY CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Susan M. Capalbo

    2004-06-01

    The Big Sky Partnership, led by Montana State University, is comprised of research institutions, public entities and private sectors organizations, and the Confederated Salish and Kootenai Tribes and the Nez Perce Tribe. Efforts during the second performance period fall into four areas: evaluation of sources and carbon sequestration sinks; development of GIS-based reporting framework; designing an integrated suite of monitoring, measuring, and verification technologies; and initiating a comprehensive education and outreach program. At the first two Partnership meetings the groundwork was put in place to provide an assessment of capture and storage capabilities for CO{sub 2} utilizing the resources found in the Partnership region (both geological and terrestrial sinks), that would complement the ongoing DOE research. The region has a diverse array of geological formations that could provide storage options for carbon in one or more of its three states. Likewise, initial estimates of terrestrial sinks indicate a vast potential for increasing and maintaining soil C on forested, agricultural, and reclaimed lands. Both options include the potential for offsetting economic benefits to industry and society. Steps have been taken to assure that the GIS-based framework is consistent among types of sinks within the Big Sky Partnership area and with the efforts of other western DOE partnerships. Efforts are also being made to find funding to include Wyoming in the coverage areas for both geological and terrestrial sinks and sources. The Partnership recognizes the critical importance of measurement, monitoring, and verification technologies to support not only carbon trading but all policies and programs that DOE and other agencies may want to pursue in support of GHG mitigation. The efforts begun in developing and implementing MMV technologies for geological sequestration reflect this concern. Research is also underway to identify and validate best management practices for soil C in the partnership region, and to design a risk/cost effectiveness framework to make comparative assessments of each viable sink, taking into account economic costs, offsetting benefits, scale of sequestration opportunities, spatial and time dimensions, environmental risks, and long term viability. Scientifically sound information on MMV is critical for public acceptance of these technologies. Two key deliverables were completed this quarter--a literature review/database to assess the soil carbon on rangelands, and the draft protocols, contracting options for soil carbon trading. To date, there has been little research on soil carbon on rangelands, and since rangeland constitutes a major land use in the Big Sky region, this is important in achieving a better understanding of terrestrial sinks. The protocols developed for soil carbon trading are unique and provide a key component of the mechanisms that might be used to efficiently sequester GHG and reduce CO{sub 2} concentrations. Progress on other deliverables is noted in the PowerPoint presentations. A series of meetings held during the second quarter have laid the foundations for assessing the issues surrounding the implementation of a market-based setting for soil C credits. These meetings provide a connection to stakeholders in the region and a basis on which to draw for the DOE PEIS hearings. Finally, the education and outreach efforts have resulted in a comprehensive plan and process which serves as a guide for implementing the outreach activities under Phase I. While we are still working on the public website, we have made many presentations to stakeholders and policy makers, connections to other federal and state agencies concerned with GHG emissions, climate change, and efficient and environmentally-friendly energy production. In addition, we have laid plans for integration of our outreach efforts with the students, especially at the tribal colleges and at the universities involved in our partnership. This includes collaboration with the film and media arts departments at MSU, with outreach effort

  2. Drilling, Completion, and Data Collection Plans An Assessment of Geological Carbon Sequestration Options in the Illinois Basin: Phase III

    SciTech Connect (OSTI)

    Malkewicz, Nicholas; Kirksey, Jim; Finley, Robert

    2015-05-01

    Executive Summary The Illinois Basin – Decatur Project (IBDP) is managed by the Midwest Geological Sequestration Consortium (MGSC) and is led by the Illinois State Geological Survey (ISGS) at the University of Illinois. The project site is located on the Archer Daniels Midland Company (ADM) property in Decatur, Illinois, and is a fully integrated carbon capture and storage (CCS) project that uses CO? captured from the ethanol-producing fermentation process at the ADM corn-processing plant (Finley et. al., 2013). IBDP has a goal of injecting one million tonnes of CO? into the basal sands of the Mt. Simon Sandstone over a three-year period. This is a multifaceted project, and this report details the planning and results of the drilling, completions, well testing, log data acquisition, and the Health, Safety, and Environment (HSE) aspects of the project. Three deep wells were planned for the IBDP: • The injection well: Injection Well #1 (CCS1); • The monitoring well (both in-zone and above seal): Verification Well #1 (VW1); and • The geophone monitoring well: Geophysical Monitoring Well #1 (GM1). The detailed plans for these wells are attached to the appendices of this document. The wells were drilled successfully with little deviation from the original plans. The biggest change from the plan to execution was the need to adjust for larger-than-expected loss of circulation in the Potosi section of the Knox Formation. The completions reports also attached to this document detail the well constructions as they were actually built. Injectivity testing was carried out, and the perforating plans were adjusted based on the results. Additional perforations and acidizing were performed as a result of the injectivity testing. The testing plans are detailed in this report along with the actual testing results. The injectivity testing results were used in the modeling and simulation efforts. Detailed HSE plans were developed and implemented during the planning and execution phases of the project. The implementation included an HSE Bridging Document, which served to unify the HSE policies of the project partners and key subcontractors. The HSE plan and actual HSE results are presented in this document. There were no recordable HSE incidents during the project. A detailed logging program was developed based on project needs. The log data were acquired in accordance with the plan, and both the plan and log results are presented in this report. Log data were heavily utilized by the research staff, modelers, reservoir engineers, and for technical and permitting efforts. 5 Several key lessons were learned during the project: • Safety in operations and execution is paramount and is only achieved through proper planning and behavior control. The certainty of this was reinforced through implementation of this lesson and the resultant flawless HSE performance during the project. • Losses of drilling fluid circulation were larger than anticipated within the Potosi Formation. Circulation was only recovered through cementing the loss zones. • When possible, minimizing complexity in permit requirements and well designs is preferable. • The size of the wells were outside of the standard experience and expertise typical within the basin, and therefore required substantial planning and ramp-up of contractors and partners to meet project objectives. • With multiple stakeholders and research partners, establishing objectives and requirements early and adhering to change request procedures throughout the project are critical to manage competing data and sampling objectives that may be detrimental to overall progress. The well construction and completion operations were successfully executed, with all wells built in a manner that achieved excellent wellbore integrity. Log planning involved a number of stakeholders and technical specialists. Data collection from logging, coring, and testing was excellent. Time and effort spent with the associated contractors and suppliers to develop a well plan beyond normal scope proved highly success

  3. Map of Geologic Sequestration Training and Research Projects

    Broader source: Energy.gov [DOE]

    A larger map of FE's Geologic Sequestration Training and Research Projects awarded as part of the Recovery Act.

  4. Carbon sequestration and greenhouse gas emissions in urban turf

    E-Print Network [OSTI]

    Townsend-Small, Amy; Czimczik, Claudia I

    2010-01-01

    Carbon sequestration and greenhouse gas emissions in urbanCarbon sequestration and greenhouse gas emissions in urbanCarbon sequestration and greenhouse gas emissions in urban

  5. Perspectives on Carbon Capture and Sequestration in the United States

    E-Print Network [OSTI]

    Wong-Parodi, Gabrielle

    2011-01-01

    2006 Carbon sequestration: regional partnerships Accessed onCoast Carbon Sequestration Regional Partnership with supportCoast Regional Carbon Sequestration Partnership 2008 Public

  6. Biologically Enhanced Carbon Sequestration: Research Needs and Opportunities

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2008-01-01

    Enhancement of soil carbon sequestration by amendment withBiologically Enhanced Carbon Sequestration: Research Needson Biologically Enhanced Carbon Sequestration, October 29,

  7. Carbon sequestration and greenhouse gas emissions in urban turf

    E-Print Network [OSTI]

    Townsend-Small, Amy; Czimczik, Claudia I

    2010-01-01

    Article Correction to “Carbon sequestration and greenhouseCor- rection to “Carbon sequestration and greenhouse gas1 ] In the paper “Carbon sequestration and greenhouse gas

  8. Perspectives on Carbon Capture and Sequestration in the United States

    E-Print Network [OSTI]

    Wong-Parodi, Gabrielle

    2011-01-01

    West Coast Regional Carbon Sequestration Partnership 2008Community perceptions of carbon sequestration: insights fromof coal with carbon sequestration. Casper Star Tribune.

  9. Organized Research Unit (ORU) on Carbon Capture and Sequestration: Meeting the Needs of the Energy Sector

    E-Print Network [OSTI]

    Zhou, Chongwu

    Organized Research Unit (ORU) on Carbon Capture and Sequestration: Meeting the Needs of the Energy of an Organized Research Unit (ORU) on Carbon Capture and Sequestration (CCS). The purpose of this effort Frontier Research Center proposal: "Integrated Science of Geological Carbon Sequestration" to BES office

  10. Biochar and Carbon Sequestration: A Regional Perspective

    E-Print Network [OSTI]

    Everest, Graham R

    Biochar and Carbon Sequestration: A Regional Perspective A report prepared for East of England #12;Low Carbon Innovation Centre Report for EEDA Biochar and Carbon Sequestration: A Regional Perspective 20/04/2009 ii Biochar and Carbon Sequestration: A Regional Perspective A report prepared for East

  11. Mobilization of Metals from Eau Claire Siltstone and the Impact of Oxygen under Geological Carbon Dioxide Sequestration Conditions

    SciTech Connect (OSTI)

    Shao, Hongbo; Kukkadapu, Ravi K.; Krogstad, Eirik J.; Newburn, Matthew K.; Cantrell, Kirk J.

    2014-09-01

    Geologic CO2 sequestration (GCS) has been proposed as a viable strategy to reduce anthropogenic CO2 emission; however, the increased cost that will be incurred by fossil energy production facilities is a deterrent to implementation of this technology. Allowing impurities in the effluent CO2 stream could result in significant financial and energy savings for CO2 capture and separation. However, impurities such as O2 have the potential to influence the redox state and alter the geochemical interactions that occur within GCS reservoirs, which increases the concern for CO2 and brine leakage from the storage reservoir as well as the overlying groundwater contamination. In this work, to investigate the impact of O2 co-injected with CO2 on the geochemical interactions, especially the trace metal mobilization from a GCS reservoir rock, batch studies were conducted with Eau Claire siltstone collected from CO2 sequestration sites. The rock was reacted with synthetic brines in contact with either 100% CO2 or a mixture of 95 mole% CO2-5 mole% O2 at 10.1 MPa and 75 °C. Both microscopic and spectroscopic measurements, including 57Fe-Mössbauer spectroscopy, Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry, powder X-ray diffraction, scanning electron microscopy-energy dispersive x-ray spectroscopy, and chemical extraction were combined in this study to investigate reaction mechanisms. The Eau Claire siltstone contains quartz (52 wt%), fluorapatite (40%), and aluminosilicate (5%) as major components, and dolomite (2%), pyrite (1%), and small-particle-/poorly-crystalline Fe-oxides as minor components. With the introduction of CO2 into the reaction vessel containing rock and brine, the leaching of small amounts of fluorapatite, aluminosilicate, and dolomite occurred. Trace metals of environmental concern, including Pb, As, Cd, and Cu were detected in the leachate with concentrations up to 400 ppb in the CO2-brine-rock reaction system within 30 days. In the presence of O2, the mobilization of Pb, Cd, and Cu was significantly enhanced, whereas As concentrations decreased, compared with the reaction system without oxygen. The presence of oxygen resulted in the formation of secondary Fe-oxides which appear to be Fe(II)-substituted P-containing ferrihydrite. Although the rock contained only 1.04 wt% total Fe, oxidative dissolution of pyrite, leaching and oxidation of structural Fe(II) in fluorapatite, and precipitation of Fe-oxides significantly decreased the pH in brine with oxygen(pH 3.3-3.7), compared with the reaction system without oxygen (pH 4.2-4.4). In the CO2-rock-brine system without O2, the majority of As remained in the rock, with about 1.1% of the total As being released from intrinsic Fe-oxides to the aqueous phase. The release behavior of As to solution was consistent with competitive adsorption between phosphate/fluoride and As on Fe-oxide surfaces. In the presence of O2 the mobility of As was reduced due to enhanced adsorption onto both intrinsic and secondary Fe-oxide surfaces.When O2 was present, the dominant species in solution was the less toxic As(V). This work will advance our understanding of the geochemical reaction mechanisms that occur under GCS conditions and help to evaluate the risks associated with geological CO2 sequestration.

  12. Soil Carbon Sequestration and the Greenhouse Effect

    E-Print Network [OSTI]

    Archer, Steven R.

    Soil Carbon Sequestration and the Greenhouse Effect Second edition Rattan Lal & Ronald F. Follett. Printed in the United States of America. #12;181 Soil Carbon Sequestration and the Greenhouse Effect, 2nd

  13. Southeast Regional Carbon Sequestration Partnership (SECARB)

    SciTech Connect (OSTI)

    Kenneth J. Nemeth

    2005-09-30

    The Southeast Regional Carbon Sequestration Partnership (SECARB) is a diverse partnership covering eleven states involving the Southern States Energy Board (SSEB) an interstate compact; regulatory agencies and/or geological surveys from member states; the Electric Power Research Institute (EPRI); academic institutions; a Native American enterprise; and multiple entities from the private sector. Figure 1 shows the team structure for the partnership. In addition to the Technical Team, the Technology Coalition, an alliance of auxiliary participants, in the project lends yet more strength and support to the project. The Technology Coalition, with its diverse representation of various sectors, is integral to the technical information transfer, outreach, and public perception activities of the partnership. The Technology Coalition members, shown in Figure 2, also provide a breadth of knowledge and capabilities in the multiplicity of technologies needed to assure a successful outcome to the project and serve as an extremely important asset to the partnership. The eleven states comprising the multi-state region are: Alabama; Arkansas; Florida; Georgia; Louisiana; Mississippi; North Carolina; South Carolina; Tennessee; Texas; and Virginia. The states making up the SECARB area are illustrated in Figure 3. The primary objectives of the SECARB project include: (1) Supporting the U.S. Department of Energy (DOE) Carbon Sequestration Program by promoting the development of a framework and infrastructure necessary for the validation and deployment of carbon sequestration technologies. This requires the development of relevant data to reduce the uncertainties and risks that are barriers to sequestration, especially for geologic storage in the SECARB region. Information and knowledge are the keys to establishing a regional carbon dioxide (CO{sub 2}) storage industry with public acceptance. (2) Supporting the President's Global Climate Change Initiative with the goal of reducing greenhouse gas intensity by 18 percent by 2012. A corollary to the first objective, this objective requires the development of a broad awareness across government, industry, and the general public of sequestration issues and establishment of the technological and legal frameworks necessary to achieve the President's goal. The information developed by the SECARB team will play a vital role in achieving the President's goal for the southeastern region of the United States. (3) Evaluating options and potential opportunities for regional CO{sub 2} sequestration. This requires characterization of the region regarding the presence and location of sources of greenhouse gases (GHGs), primarily CO{sub 2}, the presence and location of potential carbon sinks and geological parameters, geographical features and environmental concerns, demographics, state and interstate regulations, and existing infrastructure.

  14. Biologically Enhanced Carbon Sequestration: Research Needs and Opportunities

    SciTech Connect (OSTI)

    Oldenburg, Curtis; Oldenburg, Curtis M.; Torn, Margaret S.

    2008-03-21

    Fossil fuel combustion, deforestation, and biomass burning are the dominant contributors to increasing atmospheric carbon dioxide (CO{sub 2}) concentrations and global warming. Many approaches to mitigating CO{sub 2} emissions are being pursued, and among the most promising are terrestrial and geologic carbon sequestration. Recent advances in ecology and microbial biology offer promising new possibilities for enhancing terrestrial and geologic carbon sequestration. A workshop was held October 29, 2007, at Lawrence Berkeley National Laboratory (LBNL) on Biologically Enhanced Carbon Sequestration (BECS). The workshop participants (approximately 30 scientists from California, Illinois, Oregon, Montana, and New Mexico) developed a prioritized list of research needed to make progress in the development of biological enhancements to improve terrestrial and geologic carbon sequestration. The workshop participants also identified a number of areas of supporting science that are critical to making progress in the fundamental research areas. The purpose of this position paper is to summarize and elaborate upon the findings of the workshop. The paper considers terrestrial and geologic carbon sequestration separately. First, we present a summary in outline form of the research roadmaps for terrestrial and geologic BECS. This outline is elaborated upon in the narrative sections that follow. The narrative sections start with the focused research priorities in each area followed by critical supporting science for biological enhancements as prioritized during the workshop. Finally, Table 1 summarizes the potential significance or 'materiality' of advances in these areas for reducing net greenhouse gas emissions.

  15. THE COMPARATIVE VALUE OF BIOLOGICAL CARBON SEQUESTRATION

    E-Print Network [OSTI]

    McCarl, Bruce A.

    THE COMPARATIVE VALUE OF BIOLOGICAL CARBON SEQUESTRATION 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 sequestration and between 1 and 49 percent for forest based carbon sequestration. Value adjustments 18 19 20 21 22 BRUCE A. MCCARL, BRIAN C. MURRAY, AND UWE A. SCHNEIDER Abstract Carbon sequestered via

  16. THE COMPARATIVE VALUE OF BIOLOGICAL CARBON SEQUESTRATION

    E-Print Network [OSTI]

    McCarl, Bruce A.

    THE COMPARATIVE VALUE OF BIOLOGICAL CARBON SEQUESTRATION BRUCE A. MCCARL, BRIAN C. MURRAY, AND UWE A. SCHNEIDER A. Abstract Carbon sequestration via forests and agricultural soils saturates over time to sequestration because of (1) an ecosystems limited ability to take up carbon which we will call saturation

  17. Mineral sequestration of CO2 by aqueous carbonation of1 coal combustion fly-ash2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Mineral sequestration of CO2 by aqueous carbonation of1 coal combustion fly-ash2 3 G. Montes that could possibly4 contribute to reducing carbon dioxide emissions is the in-situ mineral sequestration (long term5 geological storage) or the ex-situ mineral sequestration (controlled industrial reactors

  18. Southwest Regional Partnership on Carbon Sequestration

    SciTech Connect (OSTI)

    Brian McPherson

    2006-04-01

    The Southwest Partnership on Carbon Sequestration completed several more tasks during the period of April 1, 2005-September 30, 2005. The main objective of the Southwest Partnership project is to evaluate and demonstrate the means for achieving an 18% reduction in carbon intensity by 2012. While Phase 2 planning is well under way, the content of this report focuses exclusively on Phase 1 objectives completed during this reporting period. Progress during this period was focused in the three areas: geological carbon storage capacity in New Mexico, terrestrial sequestration capacity for the project area, and the Integrated Assessment Model efforts. The geologic storage capacity of New Mexico was analyzed and Blanco Mesaverde (which extends into Colorado) and Basin Dakota Pools were chosen as top two choices for the further analysis for CO{sub 2} sequestration in the system dynamics model preliminary analysis. Terrestrial sequestration capacity analysis showed that the four states analyzed thus far (Arizona, Colorado, New Mexico and Utah) have relatively limited potential to sequester carbon in terrestrial systems, mainly due to the aridity of these areas, but the large land area offered could make up for the limited capacity per hectare. Best opportunities were thought to be in eastern Colorado/New Mexico. The Integrated Assessment team expanded the initial test case model to include all New Mexico sinks and sources in a new, revised prototype model in 2005. The allocation mechanism, or ''String of Pearls'' concept, utilizes potential pipeline routes as the links between all combinations of the source to various sinks. This technique lays the groundwork for future, additional ''String of Pearls'' analyses throughout the SW Partnership and other regions as well.

  19. WithCarbonSequestration Biological-

    E-Print Network [OSTI]

    342928Net energy ratio 2.603.303.60$/kg H2Total cost Central Hydrogen from Biomass via Gasification · Techno-Economic Analysis of H2 Production by Gasification of Biomass · Renewables Analysis · BiomassWithCarbonSequestration Biomass Hydro Wind Solar Coal Nuclear Natural Gas Oil Biological

  20. WEST COAST REGIONAL CARBON SEQUESTRATION PARTNERSHIP

    SciTech Connect (OSTI)

    Larry Myer; Terry Surles; Kelly Birkinshaw

    2004-01-01

    The West Coast Regional Carbon Sequestration Partnership is one of seven partnerships which have been established by the US Department of Energy (DOE) to evaluate carbon dioxide capture, transport and sequestration (CT&S) technologies best suited for different regions of the country. The West Coast Region comprises Arizona, California, Nevada, Oregon, Washington, and the North Slope of Alaska. Led by the California Energy Commission, the West Coast Partnership is a consortium of over thirty five organizations, including state natural resource and environmental protection agencies; national labs and universities; private companies working on CO{sub 2} capture, transportation, and storage technologies; utilities; oil and gas companies; nonprofit organizations; and policy/governance coordinating organizations. In an eighteen month Phase I project, the Partnership will evaluate both terrestrial and geologic sequestration options. Work will focus on five major objectives: (1) Collect data to characterize major CO{sub 2} point sources, the transportation options, and the terrestrial and geologic sinks in the region, and compile and organize this data via a geographic information system (GIS) database; (2) Address key issues affecting deployment of CT&S technologies, including storage site permitting and monitoring, injection regulations, and health and environmental risks (3) Conduct public outreach and maintain an open dialogue with stakeholders in CT&S technologies through public meetings, joint research, and education work (4) Integrate and analyze data and information from the above tasks in order to develop supply curves and cost effective, environmentally acceptable sequestration options, both near- and long-term (5) Identify appropriate terrestrial and geologic demonstration projects consistent with the options defined above, and create action plans for their safe and effective implementation A kickoff meeting for the West Coast Partnership was held on Sept 30-Oct.1. Contracts were then put into place with twelve organizations which will carry out the technical work required to meet Partnership objectives.

  1. Southwest Regional Partnership on Carbon Sequestration

    SciTech Connect (OSTI)

    Brian McPherson

    2006-03-31

    The Southwest Partnership on Carbon Sequestration completed its Phase I program in December 2005. The main objective of the Southwest Partnership Phase I project was to evaluate and demonstrate the means for achieving an 18% reduction in carbon intensity by 2012. Many other goals were accomplished on the way to this objective, including (1) analysis of CO{sub 2} storage options in the region, including characterization of storage capacities and transportation options, (2) analysis and summary of CO{sub 2} sources, (3) analysis and summary of CO{sub 2} separation and capture technologies employed in the region, (4) evaluation and ranking of the most appropriate sequestration technologies for capture and storage of CO{sub 2} in the Southwest Region, (5) dissemination of existing regulatory/permitting requirements, and (6) assessing and initiating public knowledge and acceptance of possible sequestration approaches. Results of the Southwest Partnership's Phase I evaluation suggested that the most convenient and practical ''first opportunities'' for sequestration would lie along existing CO{sub 2} pipelines in the region. Action plans for six Phase II validation tests in the region were developed, with a portfolio that includes four geologic pilot tests distributed among Utah, New Mexico, and Texas. The Partnership will also conduct a regional terrestrial sequestration pilot program focusing on improved terrestrial MMV methods and reporting approaches specific for the Southwest region. The sixth and final validation test consists of a local-scale terrestrial pilot involving restoration of riparian lands for sequestration purposes. The validation test will use desalinated waters produced from one of the geologic pilot tests. The Southwest Regional Partnership comprises a large, diverse group of expert organizations and individuals specializing in carbon sequestration science and engineering, as well as public policy and outreach. These partners include 21 state government agencies and universities, five major electric utility companies, seven oil, gas and coal companies, three federal agencies, the Navajo Nation, several NGOs, and the Western Governors Association. This group is continuing its work in the Phase II Validation Program, slated to conclude in 2009.

  2. Carbon sequestration in natural gas reservoirs: Enhanced gas recovery and natural gas storage

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2003-01-01

    gas reservoirs for carbon sequestration and enhanced gasproduction and carbon sequestration, Society of Petroleumfeasibiilty of carbon sequestration with enhanced gas

  3. EIGHTH ANNUAL CONFERENCE ON CARBON CAPTURE AND SEQUESTRATION -DOE/NETL May 4 7, 2009 Detection of CO2 Seepage from Geological

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    EIGHTH ANNUAL CONFERENCE ON CARBON CAPTURE AND SEQUESTRATION - DOE/NETL May 4 ­ 7, 2009 Detection Jalali and Shahab D. Mohaghegh, West Virginia University #12;EIGHTH ANNUAL CONFERENCE ON CARBON CAPTURE to the burning of fossil fuels (1) . The increasing concentration of carbon dioxide in the atmosphere has

  4. Carbon Sequestration via Mineral Carbonation: Overview and Assessment

    E-Print Network [OSTI]

    1 Carbon Sequestration via Mineral Carbonation: Overview and Assessment 14 March 2002 Howard Herzog overview and assessment of carbon sequestration by mineral carbonation (referred to as "mineral sequestration R&D. The first is that carbonates have a lower energy state than CO2. Therefore, at least

  5. The future of carbon sequestration. 2nd ed.

    SciTech Connect (OSTI)

    2007-04-15

    The report is an overview of the opportunities for carbon sequestration to reduce greenhouse gas emissions. It provides a concise look at what is driving interest in carbon sequestration, the challenges faced in implementing carbon sequestration projects, and the current and future state of carbon sequestration. Topics covered in the report include: Overview of the climate change debate; Explanation of the global carbon cycle; Discussion of the concept of carbon sequestration; Review of current efforts to implement carbon sequestration; Analysis and comparison of carbon sequestration component technologies; Review of the economic drivers of carbon sequestration project success; and Discussion of the key government and industry initiatives supporting carbon sequestration.

  6. System-level modeling for geological storage of CO2

    E-Print Network [OSTI]

    Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan; Bodvarsson, Gudmundur S.

    2006-01-01

    Gas Reservoirs for Carbon Sequestration and Enhanced Gasfrom geologic carbon sequestration sites, Vadose Zonethe feasibility of carbon sequestration with enhanced gas

  7. EFRC Carbon Capture and Sequestration Activities at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EFRC Carbon Capture and Sequestration Activities at NERSC EFRC Carbon Capture and Sequestration Activities at NERSC Why it Matters: Carbon dioxide (CO2) gas is considered to be...

  8. Trading Water for Carbon with Biological Carbon Sequestration

    E-Print Network [OSTI]

    Jackson, Robert B.

    Trading Water for Carbon with Biological Carbon Sequestration Robert B. Jackson,1 * Esteban G. Farley,1 David C. le Maitre,5 Bruce A. McCarl,6 Brian C. Murray7 Carbon sequestration strategies plantations feature prominently among tools for carbon sequestration (1­8). Plantations typi- cally combine

  9. The Midwest Regional Carbon Sequestration Partnership (MRCSP)

    SciTech Connect (OSTI)

    James J. Dooley; Robert Dahowski; Casie Davidson

    2005-12-01

    This final report summarizes the Phase I research conducted by the Midwest regional Carbon Sequestration Partnership (MRCSP). The Phase I effort began in October 2003 and the project period ended on September 31, 2005. The MRCSP is a public/private partnership led by Battelle with the mission of identifying the technical, economic, and social issues associated with implementation of carbon sequestration technologies in its seven state geographic region (Indiana, Kentucky, Maryland, Michigan, Ohio, Pennsylvania, and West Virginia) and identifying viable pathways for their deployment. It is one of seven partnerships that together span most of the U.S. and parts of Canada that comprise the U.S. Department of Energy's (DOE's) Regional Carbon Sequestration Program led by DOE's national Energy Technology Laboratory (NETL). The MRCSP Phase I research was carried out under DOE Cooperative Agreement No. DE-FC26-03NT41981. The total value of Phase I was $3,513,513 of which the DOE share was $2,410,967 or 68.62%. The remainder of the cost share was provided in varying amounts by the rest of the 38 members of MRCSP's Phase I project. The next largest cost sharing participant to DOE in Phase I was the Ohio Coal Development Office within the Ohio Air Quality Development Authority (OCDO). OCDO's contribution was $100,000 and was contributed under Grant Agreement No. CDO/D-02-17. In this report, the MRCSP's research shows that the seven state MRCSP region is a major contributor to the U. S. economy and also to total emissions of CO2, the most significant of the greenhouse gases thought to contribute to global climate change. But, the research has also shown that the region has substantial resources for sequestering carbon, both in deep geological reservoirs (geological sequestration) and through improved agricultural and land management practices (terrestrial sequestration). Geological reservoirs, especially deep saline reservoirs, offer the potential to permanently store CO2 for literally 100s of years even if all the CO2 emissions from the region's large point sources were stored there, an unlikely scenario under any set of national carbon emission mitigation strategies. The terrestrial sequestration opportunities in the region have the biophysical potential to sequester up to 20% of annual emissions from the region's large point sources of CO2. This report describes the assumptions made and methods employed to arrive at the results leading to these conclusions. It also describes the results of analyses of regulatory issues in the region affecting the potential for deployment of sequestration technologies. Finally, it describes the public outreach and education efforts carried out in Phase I including the creation of a web site dedicated to the MRCSP at www.mrcsp.org.

  10. Geological Carbon Sequestration Storage Resource Estimates for the Ordovician St. Peter Sandstone, Illinois and Michigan Basins, USA

    SciTech Connect (OSTI)

    Barnes, David; Ellett, Kevin; Leetaru, Hannes

    2014-09-30

    The Cambro-Ordovician strata of the Midwest of the United States is a primary target for potential geological storage of CO2 in deep saline formations. The objective of this project is to develop a comprehensive evaluation of the Cambro-Ordovician strata in the Illinois and Michigan Basins above the basal Mount Simon Sandstone since the Mount Simon is the subject of other investigations including a demonstration-scale injection at the Illinois Basin Decatur Project. The primary reservoir targets investigated in this study are the middle Ordovician St Peter Sandstone and the late Cambrian to early Ordovician Knox Group carbonates. The topic of this report is a regional-scale evaluation of the geologic storage resource potential of the St Peter Sandstone in both the Illinois and Michigan Basins. Multiple deterministic-based approaches were used in conjunction with the probabilistic-based storage efficiency factors published in the DOE methodology to estimate the carbon storage resource of the formation. Extensive data sets of core analyses and wireline logs were compiled to develop the necessary inputs for volumetric calculations. Results demonstrate how the range in uncertainty of storage resource estimates varies as a function of data availability and quality, and the underlying assumptions used in the different approaches. In the simplest approach, storage resource estimates were calculated from mapping the gross thickness of the formation and applying a single estimate of the effective mean porosity of the formation. Results from this approach led to storage resource estimates ranging from 3.3 to 35.1 Gt in the Michigan Basin, and 1.0 to 11.0 Gt in the Illinois Basin at the P10 and P90 probability level, respectively. The second approach involved consideration of the diagenetic history of the formation throughout the two basins and used depth-dependent functions of porosity to derive a more realistic spatially variable model of porosity rather than applying a single estimate of porosity throughout the entire potential reservoir domains. The second approach resulted in storage resource estimates of 3.0 to 31.6 Gt in the Michigan Basin, and 0.6 to 6.1 Gt in the Illinois Basin. The third approach attempted to account for the local-scale variability in reservoir quality as a function of both porosity and permeability by using core and log analyses to calculate explicitly the net effective porosity at multiple well locations, and interpolate those results throughout the two basins. This approach resulted in storage resource estimates of 10.7 to 34.7 Gt in the Michigan Basin, and 11.2 to 36.4 Gt in the Illinois Basin. A final approach used advanced reservoir characterization as the most sophisticated means to estimating storage resource by defining reservoir properties for multiple facies within the St Peter formation. This approach was limited to the Michigan Basin since the Illinois Basin data set did not have the requisite level of data quality and sampling density to support such an analysis. Results from this approach led to storage resource estimates of 15.4 Gt to 50.1 Gt for the Michigan Basin. The observed variability in results from the four different approaches is evaluated in the context of data and methodological constraints, leading to the conclusion that the storage resource estimates from the first two approaches may be conservative, whereas the net porosity based approaches may over-estimate the resource.

  11. Vegetation succession and carbon sequestration in a coastal wetland in northwest Florida: Evidence from carbon isotopes

    E-Print Network [OSTI]

    Vegetation succession and carbon sequestration in a coastal wetland in northwest Florida: Evidence from carbon isotopes Yonghoon Choi and Yang Wang Department of Geological Sciences, Florida State. Measurements of stable carbon isotopic ratios as well as carbon (C), nitrogen (N), and phosphorus (P) contents

  12. Optimize carbon dioxide sequestration, enhance oil recovery

    E-Print Network [OSTI]

    - 1 - Optimize carbon dioxide sequestration, enhance oil recovery January 8, 2014 Los Alamos simulation to optimize carbon dioxide (CO2) sequestration and enhance oil recovery (CO2-EOR) based on known production. Due to carbon capture and storage technology advances, prolonged high oil prices

  13. Research Experience in Carbon Sequestration Training Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Training Program Now Accepting Applications Research Experience in Carbon Sequestration Training Program Now Accepting Applications March 26, 2012 - 1:00pm Addthis Washington, D.C....

  14. Greening up fossil fuels with carbon sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greening up fossil fuels with carbon sequestration 1663 Los Alamos science and technology magazine Latest Issue:October 2015 past issues All Issues submit Greening up fossil...

  15. Carbon sequestration monitoring with acoustic double-difference waveform inversion: A case study on SACROC walkaway VSP data

    E-Print Network [OSTI]

    Yang, Di

    2011-01-01

    Geological carbon sequestration involves large-scale injection of carbon dioxide into underground geologic formations and is considered as a potential approach for mitigating global warming. Changes in reservoir properties ...

  16. Center for Research on Enhancing Carbon Sequestration in Terrestrial Ecosystems

    E-Print Network [OSTI]

    #12;Center for Research on Enhancing Carbon Sequestration in Terrestrial Ecosystems Personnel. Blaine Metting #12;vii Abstract The Center for Research on Enhancing Carbon Sequestration in Terrestrial needed to evaluate the feasibility of environmentally sound strategies for enhancing carbon sequestration

  17. Southeast Regional Carbon Sequestration Partnership

    SciTech Connect (OSTI)

    Kenneth J. Nemeth

    2006-08-30

    The Southeast Regional Carbon Sequestration Partnership's (SECARB) Phase I program focused on promoting the development of a framework and infrastructure necessary for the validation and commercial deployment of carbon sequestration technologies. The SECARB program, and its subsequent phases, directly support the Global Climate Change Initiative's goal of reducing greenhouse gas intensity by 18 percent by the year 2012. Work during the project's two-year period was conducted within a ''Task Responsibility Matrix''. The SECARB team was successful in accomplishing its tasks to define the geographic boundaries of the region; characterize the region; identify and address issues for technology deployment; develop public involvement and education mechanisms; identify the most promising capture, sequestration, and transport options; and prepare action plans for implementation and technology validation activity. Milestones accomplished during Phase I of the project are listed below: (1) Completed preliminary identification of geographic boundaries for the study (FY04, Quarter 1); (2) Completed initial inventory of major sources and sinks for the region (FY04, Quarter 2); (3) Completed initial development of plans for GIS (FY04, Quarter 3); (4) Completed preliminary action plan and assessment for overcoming public perception issues (FY04, Quarter 4); (5) Assessed safety, regulatory and permitting issues (FY05, Quarter 1); (6) Finalized inventory of major sources/sinks and refined GIS algorithms (FY05, Quarter 2); (7) Refined public involvement and education mechanisms in support of technology development options (FY05, Quarter 3); and (8) Identified the most promising capture, sequestration and transport options and prepared action plans (FY05, Quarter 4).

  18. Conceptual Design of Optimized Fossil Energy Systems with Capture and Sequestration of Carbon Dioxide

    E-Print Network [OSTI]

    Ogden, Joan

    2004-01-01

    USDOE’s Carbon Sequestration Regional Partnership program.under the Carbon Sequestration Regional Partnership Program.

  19. An assessment of carbon sequestration potential in the UK

    E-Print Network [OSTI]

    Watson, Andrew

    for Climate Change Research and British Geological Survey Kingsley Dunham Centre Keyworth Nottingham NG12 5GGAn assessment of carbon sequestration potential in the UK ­ Southern North Sea case study Michele Bentham January 2006 Tyndall Centre for Climate Change Research Working Paper 85 #12;1 An assessment

  20. 2010 Carbon Sequestration Atlas of the United States and Canada...

    Open Energy Info (EERE)

    of Energy's (DOE) Carbon Sequestration Research Program, DOE's international carbon capture and sequestration (CCS) collaborations, worldwide CCS projects, and CCS regulatory...

  1. Readout of Secretary Chu Meetings on Carbon Capture and Sequestration...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Readout of Secretary Chu Meetings on Carbon Capture and Sequestration and State Grid Readout of Secretary Chu Meetings on Carbon Capture and Sequestration and State Grid July 16,...

  2. Recovery Act: Geologic Sequestration Training and Research Walsh...

    Office of Scientific and Technical Information (OSTI)

    simulation, and (6) development of an advanced undergraduategraduate level course on coal combustion and gasification, climate change, and carbon sequestration. Four graduate...

  3. November 2008 Carbon Sequestration in

    E-Print Network [OSTI]

    Pedersen, Tom

    November 2008 Carbon Sequestration in British Columbia's Forests and Management Options T. Andrew of British Columbia through the BC Ministry of the Environment. #12;3Forestry ExECutIvE SuMMary OF FuturE rESEarCh BlAckaNd rAchhpAl S. JASSAlFaculty oF laNd aNd Food SyStemS, uNiverSity oF britiSh columbia ArThur l

  4. SOUTHEAST REGIONAL CARBON SEQUESTRATION PARTNERSHP (SECARB)

    SciTech Connect (OSTI)

    Kenneth J. Nemeth

    2005-04-01

    The Southeast Regional Carbon Sequestration Partnership (SECARB) is on schedule and within budget projections for the work completed during the first 18-months of its two year program. Work during the semiannual period (fifth and sixth project quarters) of the project (October 1, 2004-March 31, 2005) was conducted within a ''Task Responsibility Matrix.'' Under Task 1.0 Define Geographic Boundaries of the Region, no changes occurred during the fifth or sixth quarters of the project. Under Task 2.0 Characterize the Region, refinements have been made to the general mapping and screening of sources and sinks. Integration and geographical information systems (GIS) mapping is ongoing. Characterization during this period was focused on smaller areas having high sequestration potential. Under Task 3.0 Identify and Address Issues for Technology Deployment, SECARB continues to expand upon its assessment of safety, regulatory, permitting, and accounting frameworks within the region to allow for wide-scale deployment of promising terrestrial and geologic sequestration approaches. Under Task 4.0 Develop Public Involvement and Education Mechanisms, SECARB has used results of a survey and focus group meeting to refine approaches that are being taken to educate and involve the public. Under Task 5.0 Identify the Most Promising Capture, Sequestration, and Transport Options, SECARB has evaluated findings from work performed during the first 18-months. The focus of the project team has shifted from region-wide mapping and characterization to a more detailed screening approach designed to identify the most promising opportunities. Under Task 6.0 Prepare Action Plans for Implementation and Technology Validation Activity, the SECARB team is developing an integrated approach to implementing the most promising opportunities and in setting up measurement, monitoring and verification (MMV) programs for the most promising opportunities. Milestones completed during the fifth and sixth project quarters included: (1) Q1-FY05--Assess safety, regulatory and permitting issues; and (2) Q2-FY05--Finalize inventory of major sources/sinks and refine GIS algorithms.

  5. DOE Manual Studies Terrestrial Carbon Sequestration

    Broader source: Energy.gov [DOE]

    There is considerable opportunity and growing technical sophistication to make terrestrial carbon sequestration both practical and effective, according to the latest carbon capture and storage "best practices" manual issued by the U.S. Department of Energy.

  6. Carbon sequestration research and development

    SciTech Connect (OSTI)

    Reichle, Dave; Houghton, John; Kane, Bob; Ekmann, Jim; and others

    1999-12-31

    Predictions of global energy use in the next century suggest a continued increase in carbon emissions and rising concentrations of carbon dioxide (CO{sub 2}) in the atmosphere unless major changes are made in the way we produce and use energy--in particular, how we manage carbon. For example, the Intergovernmental Panel on Climate Change (IPCC) predicts in its 1995 ''business as usual'' energy scenario that future global emissions of CO{sub 2} to the atmosphere will increase from 7.4 billion tonnes of carbon (GtC) per year in 1997 to approximately 26 GtC/year by 2100. IPCC also projects a doubling of atmospheric CO{sub 2} concentration by the middle of next century and growing rates of increase beyond. Although the effects of increased CO{sub 2} levels on global climate are uncertain, many scientists agree that a doubling of atmospheric CO{sub 2} concentrations could have a variety of serious environmental consequences. The goal of this report is to identify key areas for research and development (R&D) that could lead to an understanding of the potential for future use of carbon sequestration as a major tool for managing carbon emissions. Under the leadership of DOE, researchers from universities, industry, other government agencies, and DOE national laboratories were brought together to develop the technical basis for conceiving a science and technology road map. That effort has resulted in this report, which develops much of the information needed for the road map.

  7. Natural CO2 Analogs for Carbon Sequestration

    SciTech Connect (OSTI)

    Scott H. Stevens; B. Scott Tye

    2005-07-31

    The report summarizes research conducted at three naturally occurring geologic CO{sub 2} fields in the US. The fields are natural analogs useful for the design of engineered long-term storage of anthropogenic CO{sub 2} in geologic formations. Geologic, engineering, and operational databases were developed for McElmo Dome in Colorado; St. Johns Dome in Arizona and New Mexico; and Jackson Dome in Mississippi. The three study sites stored a total of 2.4 billion t (46 Tcf) of CO{sub 2} equivalent to 1.5 years of power plant emissions in the US and comparable in size with the largest proposed sequestration projects. The three CO{sub 2} fields offer a scientifically useful range of contrasting geologic settings (carbonate vs. sandstone reservoir; supercritical vs. free gas state; normally pressured vs. overpressured), as well as different stages of commercial development (mostly undeveloped to mature). The current study relied mainly on existing data provided by the CO{sub 2} field operator partners, augmented with new geochemical data. Additional study at these unique natural CO{sub 2} accumulations could further help guide the development of safe and cost-effective design and operation methods for engineered CO{sub 2} storage sites.

  8. Statistical approaches to leak detection for geological sequestration

    E-Print Network [OSTI]

    Haidari, Arman S

    2011-01-01

    Geological sequestration has been proposed as a way to remove CO? from the atmosphere by injecting it into deep saline aquifers. Detecting leaks to the atmosphere will be important for ensuring safety and effectiveness of ...

  9. ISSUES IN EVALUATING CARBON SEQUESTRATION AND ATTRIBUTING CARBON CREDITS TO GRASSLAND RESTORATION EFFORTS

    E-Print Network [OSTI]

    Wisconsin at Madison, University of

    ISSUES IN EVALUATING CARBON SEQUESTRATION AND ATTRIBUTING CARBON CREDITS TO GRASSLAND RESTORATION examines biological carbon sequestration using a grassland restoration as a model system. Chapter 1 for biological carbon sequestration. In this analysis, we found that significantly greater soil carbon

  10. Regional partnerships lead US carbon sequestration efforts

    SciTech Connect (OSTI)

    NONE

    2007-07-01

    During the sixth annual conference on carbon capture and sequestration, 7-10 May 2007, a snapshot was given of progress on characterization efforts and field validation tests being carried out through the Carbon Sequestration Regional Partnership Initiative. The initiative is built on the recognition that geographical differences in fossil fuel/energy use and CO{sub 2} storage sinks across North America will dictate approaches to carbon sequestration. The first characterization phase (2003-2005) identified regional opportunities and developed frameworks to validate and deploy technologies. The validation phase (2005-2009) includes 10 enhanced oil recovery/enhanced gas recovery field tests in progress in Alberta and six US states and is applying lessons learned from these operations to sequestration in unmineable coal seams. Storage in saline formations are the focus of 10 field tests, and terrestrial sequestration will be studied in 11 other projects. 1 tab., 3 photos.

  11. Risk-Informed Monitoring, Verification and Accounting (RI-MVA). An NRAP White Paper Documenting Methods and a Demonstration Model for Risk-Informed MVA System Design and Operations in Geologic Carbon Sequestration

    SciTech Connect (OSTI)

    Unwin, Stephen D.; Sadovsky, Artyom; Sullivan, E. C.; Anderson, Richard M.

    2011-09-30

    This white paper accompanies a demonstration model that implements methods for the risk-informed design of monitoring, verification and accounting (RI-MVA) systems in geologic carbon sequestration projects. The intent is that this model will ultimately be integrated with, or interfaced with, the National Risk Assessment Partnership (NRAP) integrated assessment model (IAM). The RI-MVA methods described here apply optimization techniques in the analytical environment of NRAP risk profiles to allow systematic identification and comparison of the risk and cost attributes of MVA design options.

  12. The Modular Borehole Monitoring Program. A research program to optimize well-based monitoring for geologic carbon sequestration

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Freifeld, Barry; Daley, Tom; Cook, Paul; Trautz, Robert; Dodds, Kevin

    2014-12-31

    Understanding the impacts caused by injection of large volumes of CO2 in the deep subsurface necessitates a comprehensive monitoring strategy. While surface-based and other remote geophysical methods can provide information on the general morphology of a CO2 plume, verification of the geochemical conditions and validation of the remote sensing data requires measurements from boreholes that penetrate the storage formation. Unfortunately, the high cost of drilling deep wellbores and deploying instrumentation systems constrains the number of dedicated monitoring borings as well as limits the technologies that can be incorporated in a borehole completion. The objective of the Modular Borehole Monitoring (MBM)more »Program was to develop a robust suite of well-based tools optimized for subsurface monitoring of CO2 that could meet the needs of a comprehensive well-based monitoring program. It should have enough flexibility to be easily reconfigured for various reservoir geometries and geologies. The MBM Program sought to provide storage operators with a turn-key fully engineered design that incorporated key technologies, function over the decades long time-span necessary for post-closure reservoir monitoring, and meet industry acceptable risk profiles for deep-well installations. While still within the conceptual design phase of the MBM program, the SECARB Anthropogenic Test in Citronelle, Alabama, USA was identified as a deployment site for our engineered monitoring systems. The initial step in designing the Citronelle MBM system was to down-select from the various monitoring tools available to include technologies that we considered essential to any program. Monitoring methods selected included U-tube geochemical sampling, discrete quartz pressure and temperature gauges, an integrated fibre-optic bundle consisting of distributed temperature and heat-pulse sensing, and a sparse string of conventional 3C-geophones. While not originally planned within the initial MBM work scope, the fibre-optic cable was able to also be used for the emergent technology of distributed acoustic sensing. The MBM monitoring string was installed in March, 2012. To date, the Citronelle MBM instruments continue to operate reliably. Results and lessons learned from the Citronelle MBM deployment are addressed along with examples of data being collected.« less

  13. The Modular Borehole Monitoring Program. A research program to optimize well-based monitoring for geologic carbon sequestration

    SciTech Connect (OSTI)

    Freifeld, Barry; Daley, Tom; Cook, Paul; Trautz, Robert; Dodds, Kevin

    2014-12-31

    Understanding the impacts caused by injection of large volumes of CO2 in the deep subsurface necessitates a comprehensive monitoring strategy. While surface-based and other remote geophysical methods can provide information on the general morphology of a CO2 plume, verification of the geochemical conditions and validation of the remote sensing data requires measurements from boreholes that penetrate the storage formation. Unfortunately, the high cost of drilling deep wellbores and deploying instrumentation systems constrains the number of dedicated monitoring borings as well as limits the technologies that can be incorporated in a borehole completion. The objective of the Modular Borehole Monitoring (MBM) Program was to develop a robust suite of well-based tools optimized for subsurface monitoring of CO2 that could meet the needs of a comprehensive well-based monitoring program. It should have enough flexibility to be easily reconfigured for various reservoir geometries and geologies. The MBM Program sought to provide storage operators with a turn-key fully engineered design that incorporated key technologies, function over the decades long time-span necessary for post-closure reservoir monitoring, and meet industry acceptable risk profiles for deep-well installations. While still within the conceptual design phase of the MBM program, the SECARB Anthropogenic Test in Citronelle, Alabama, USA was identified as a deployment site for our engineered monitoring systems. The initial step in designing the Citronelle MBM system was to down-select from the various monitoring tools available to include technologies that we considered essential to any program. Monitoring methods selected included U-tube geochemical sampling, discrete quartz pressure and temperature gauges, an integrated fibre-optic bundle consisting of distributed temperature and heat-pulse sensing, and a sparse string of conventional 3C-geophones. While not originally planned within the initial MBM work scope, the fibre-optic cable was able to also be used for the emergent technology of distributed acoustic sensing. The MBM monitoring string was installed in March, 2012. To date, the Citronelle MBM instruments continue to operate reliably. Results and lessons learned from the Citronelle MBM deployment are addressed along with examples of data being collected.

  14. Green Goals: Carbon Sequestration Grade Levels: 6 12

    E-Print Network [OSTI]

    Hammack, Richard

    Green Goals: Carbon Sequestration Grade Levels: 6 ­ 12 type of carbon sequestration. All plants sequester carbon; however, the larger Objective: To investigate the role of trees in atmospheric carbon dioxide reduction

  15. Carbon sequestration monitoring with acoustic double-difference waveform inversion: A case study on SACROC walkaway VSP data

    E-Print Network [OSTI]

    Malcolm, Alison

    Carbon sequestration monitoring with acoustic double-difference waveform inversion: A case study National Laboratory SUMMARY Geological carbon sequestration involves large-scale injection of carbon is crucial for ensuring safe and reliable carbon storage (Bickle et al., 2007). Conventional analysis of time

  16. Bioenergy with Carbon Capture and Sequestration Workshop

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy’s (DOE’s) Office of Fossil Energy (FE) and Bioenergy Technologies Office (BETO) co-hosted the Bioenergy with Carbon Capture and Sequestration (BECCS) Workshop on...

  17. Carbon Sequestration Documentary Wins Coveted Aurora Award

    Broader source: Energy.gov [DOE]

    A film about carbon sequestration produced with support from the U.S. Department of Energy has received a 2009 Gold Aurora Award in the documentary category for nature/environment.

  18. Carbon sequestration with enhanced gas recovery: Identifying candidate sites for pilot study

    E-Print Network [OSTI]

    Oldenburg, C.M.; Benson, S.M.

    2001-01-01

    Process modeling of carbon sequestration with enhanced gas2001. Reichle, D. et al.. Carbon sequestration research andCarbon Sequestration with Enhanced Gas Recovery: Identifying

  19. SOUTHEAST REGIONAL CARBON SEQUESTRATION PARTNERSHIP (SECARB)

    SciTech Connect (OSTI)

    Kenneth J. Nemeth

    2004-09-01

    The Southeast Regional Carbon Sequestration Partnership (SECARB) is on schedule and within budget projections for the work completed during the first year of its two year program. Work during the semiannual period (third and fourth quarter) of the project (April 1--September 30, 2004) was conducted within a ''Task Responsibility Matrix.'' Under Task 1.0 Define Geographic Boundaries of the Region, Texas and Virginia were added during the second quarter of the project and no geographical changes occurred during the third or fourth quarter of the project. Under Task 2.0 Characterize the Region, general mapping and screening of sources and sinks has been completed, with integration and Geographical Information System (GIS) mapping ongoing. The first step focused on the macro level characterization of the region. Subsequent characterization will focus on smaller areas having high sequestration potential. Under Task 3.0 Identify and Address Issues for Technology Deployment, SECARB has completed a preliminary assessment of safety, regulatory, permitting, and accounting frameworks within the region to allow for wide-scale deployment of promising terrestrial and geologic sequestration approaches. Under Task 4.0 Develop Public Involvement and Education Mechanisms, SECARB has conducted a survey and focus group meeting to gain insight into approaches that will be taken to educate and involve the public. Task 5.0 and 6.0 will be implemented beginning October 1, 2004. Under Task 5.0 Identify the Most Promising Capture, Sequestration, and Transport Options, SECARB will evaluate findings from work performed during the first year and shift the focus of the project team from region-wide mapping and characterization to a more detailed screening approach designed to identify the most promising opportunities. Under Task 6.0 Prepare Action Plans for Implementation and Technology Validation Activity, the SECARB team will develop an integrated approach to implementing and setting up measurement, monitoring and verification (MMV) programs for the most promising opportunities. During this semiannual period special attention was provided to Texas and Virginia, which were added to the SECARB region, to ensure a smooth integration of activities with the other 9 states. Milestones completed and submitted during the third and fourth quarter included: Q3-FY04--Complete initial development of plans for GIS; and Q4-FYO4--Complete preliminary action plan and assessment for overcoming public perception issues.

  20. The Fluid Mechanics of Carbon Dioxide Sequestration

    E-Print Network [OSTI]

    Huppert, Herbert

    with a potentially disastrous global problem owing to the current emission of 32 gigatonnes of carbon dioxide (CO2The Fluid Mechanics of Carbon Dioxide Sequestration Herbert E. Huppert1-3 and Jerome A. Neufeld4 1 FurtherANNUAL REVIEWS #12;1. INTRODUCTION Undeniably, the average global carbon dioxide (CO2) content

  1. Shallow Carbon Sequestration Demonstration Project

    SciTech Connect (OSTI)

    Pendergrass, Gary; Fraley, David; Alter, William; Bodenhamer, Steven

    2013-09-30

    The potential for carbon sequestration at relatively shallow depths was investigated at four power plant sites in Missouri. Exploratory boreholes were cored through the Davis Shale confining layer into the St. Francois aquifer (Lamotte Sandstone and Bonneterre Formation). Precambrian basement contact ranged from 654.4 meters at the John Twitty Energy Center in Southwest Missouri to over 1100 meters near the Sioux Power Plant in St. Charles County. Investigations at the John Twitty Energy Center included 3D seismic reflection surveys, downhole geophysical logging and pressure testing, and laboratory analysis of rock core and water samples. Plans to perform injectivity tests at the John Twitty Energy Center, using food grade CO{sub 2}, had to be abandoned when the isolated aquifer was found to have very low dissolved solids content. Investigations at the Sioux Plant and Thomas Hill Energy Center in Randolph County found suitably saline conditions in the St. Francois. A fourth borehole in Platte County was discontinued before reaching the aquifer. Laboratory analyses of rock core and water samples indicate that the St. Charles and Randolph County sites could have storage potentials worthy of further study. The report suggests additional Missouri areas for further investigation as well.

  2. Grassland to shrubland state transitions enhance carbon sequestration in the northern Chihuahuan Desert

    E-Print Network [OSTI]

    Grassland to shrubland state transitions enhance carbon sequestration in the northern Chihuahuan in woody vegetation may be enhanced ecosystem carbon sequestration, although the responses of arid at least be partially offset by increased ecosystem carbon sequestration. Keywords: carbon sequestration

  3. Carbonation: An Efficient and Economical Process for CO2 Sequestration

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Carbonation: An Efficient and Economical Process for CO2 Sequestration Tarun R Naik1 and Rakesh sequestration. Most of the studies related to the carbonation are limited to its effects on corrosion. The possibility of using carbonation process as a direct means for carbon dioxide sequestration is yet

  4. Understanding Sequestration as a Means of Carbon Management Howard Herzog

    E-Print Network [OSTI]

    difficult. C Carbon sequestration provides an alternate While many of the carbon management and nuclear Carbon sequestration is happening today. As part about climate change, the story is very different has imposed a carbon sequestration. They include enhancing natural tax of about $50 per tonne of CO

  5. SOUTHWEST REGIONAL PARTNERSHIP ON CARBON SEQUESTRATION

    SciTech Connect (OSTI)

    Brian McPherson

    2005-08-01

    The Southwest Partnership on Carbon Sequestration completed several more tasks during the period of October 1, 2004--March 31, 2005. The main objective of the Southwest Partnership project is to achieve an 18% reduction in carbon intensity by 2012. Action plans for possible Phase 2 carbon sequestration pilot tests in the region are completed, and a proposal was developed and submitted describing how the Partnership may develop and carry out appropriate pilot tests. The content of this report focuses on Phase 1 objectives completed during this reporting period.

  6. Carbon Code Requirements for voluntary carbon sequestration projects

    E-Print Network [OSTI]

    and individuals wishing to reduce their carbon footprint while also delivering a range of other environmentalWoodland Carbon Code Requirements for voluntary carbon sequestration projects ® Version 1.2 July of group schemes 8 2.6 Monitoring 9 2.7 Carbon statements and reporting 9 2.8 Woodland Carbon Code

  7. SOUTHWEST REGIONAL PARTNERSHIP ON CARBON SEQUESTRATION

    SciTech Connect (OSTI)

    Brian McPherson; Rick Allis; Barry Biediger; Joel Brown; Jim Cappa; George Guthrie; Richard Hughes; Eugene Kim; Robert Lee; Dennis Leppin; Charles Mankin; Orman Paananen; Rajesh Pawar; Tarla Peterson; Steve Rauzi; Jerry Stuth; Genevieve Young

    2004-11-01

    The Southwest Partnership Region includes six whole states, including Arizona, Colorado, Kansas, New Mexico, Oklahoma, and Utah, roughly one-third of Texas, and significant portions of adjacent states. The Partnership comprises a large, diverse group of expert organizations and individuals specializing in carbon sequestration science and engineering, as well as public policy and outreach. The main objective of the Southwest Partnership project is to achieve an 18% reduction in carbon intensity by 2012. The Partnership made great progress in this first year. Action plans for possible Phase II carbon sequestration pilot tests in the region are almost finished, including both technical and non-technical aspects necessary for developing and carrying out these pilot tests. All partners in the Partnership are taking an active role in evaluating and ranking optimum sites and technologies for capture and storage of CO{sub 2} in the Southwest Region. We are identifying potential gaps in all aspects of potential sequestration deployment issues.

  8. Estimation of Parameters in Carbon Sequestration Models from Net Ecosystem

    E-Print Network [OSTI]

    White, Luther

    Estimation of Parameters in Carbon Sequestration Models from Net Ecosystem Exchange Data Luther in the context of a deterministic com- partmental carbon sequestration system. Sensitivity and approximation usefulness in the estimation of parameters within a compartmental carbon sequestration model. Previously we

  9. Agricultural Soil Carbon Sequestration: Economic Issues and Research Needs

    E-Print Network [OSTI]

    McCarl, Bruce A.

    Agricultural Soil Carbon Sequestration: Economic Issues and Research Needs Draft paper Bruce A Mc............................................................................................................. 5 2 Why Consider Promoting Agricultural Soil Carbon Sequestration?...................... 6 2 Agricultural Soil Carbon Sequestration....... 11 3.1 What is the cost of GHGE offsets arising from large

  10. DEVELOPING A SET OF REGULATORY ANALOGS FOR CARBON SEQUESTRATION

    E-Print Network [OSTI]

    DEVELOPING A SET OF REGULATORY ANALOGS FOR CARBON SEQUESTRATION D.M. Reiner1 , H.J. Herzog2 1 Judge Avenue, Cambridge, MA 02139, USA, email: hjherzog@mit.edu ABSTRACT Carbon capture and sequestration variables critical for determining the success of carbon sequestration as a viable climate policy option

  11. A SEARCH FOR REGULATORY ANALOGS TO CARBON SEQUESTRATION

    E-Print Network [OSTI]

    A SEARCH FOR REGULATORY ANALOGS TO CARBON SEQUESTRATION D.M. Reiner and H.J. Herzog1 1 Laboratory for Energy and the Environment, M.I.T., Cambridge, MA. 02139, USA ABSTRACT Carbon capture and sequestration for determining the success of carbon sequestration as a viable climate policy option. INTRODUCTION To date

  12. Historical forest baselines reveal potential for continued carbon sequestration

    E-Print Network [OSTI]

    Mladenoff, David

    Historical forest baselines reveal potential for continued carbon sequestration Jeanine M-based studies suggest that land-use history is a more important driver of carbon sequestration in these systems agricultural lands are being promoted as important avenues for future carbon sequestration (8). But the degree

  13. Bioenergy with Carbon Capture and Sequestration Workshop

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy (FE) and the Bioenergy Technologies Office (BETO) in the Office of Energy Efficiency and Renewable Energy (EERE) at the U.S. Department of Energy (DOE) is hosting a Bioenergy with Carbon Capture and Sequestration (BECCS) Workshop on Monday, May 18, 2015 in Washington, DC.

  14. Carbon dioxide hydrate particles for ocean carbon sequestration

    E-Print Network [OSTI]

    Chow, Aaron C.

    This paper presents strategies for producing negatively buoyant CO[subscript 2] hydrate composite particles for ocean carbon sequestration. Our study is based on recent field observations showing that a continuous-jet ...

  15. Southwest Regional Partnership on Carbon Sequestration Phase II

    SciTech Connect (OSTI)

    James Rutledge

    2011-02-01

    The Southwest Regional Partnership (SWP) on Carbon Sequestration designed and deployed a medium-scale field pilot test of geologic carbon dioxide (CO2) sequestration in the Aneth oil field. Greater Aneth oil field, Utah's largest oil producer, was discovered in 1956 and has produced over 455 million barrels of oil (72 million m3). Located in the Paradox Basin of southeastern Utah, Greater Aneth is a stratigraphic trap producing from the Pennsylvanian Paradox Formation. Because it represents an archetype oil field of the western U.S., Greater Aneth was selected as one of three geologic pilots to demonstrate combined enhanced oil recovery (EOR) and CO2 sequestration under the auspices of the SWP on Carbon Sequestration, sponsored by the U.S. Department of Energy. The pilot demonstration focuced on the western portion of the Aneth Unit as this area of the field was converted from waterflood production to CO2 EOR starting in late 2007. The Aneth Unit is in the northwestern part of the field and has produced 149 million barrels (24 million m3) of the estimated 450 million barrels (71.5 million m3) of the original oil in place - a 33% recovery rate. The large amount of remaining oil makes the Aneth Unit ideal to demonstrate both CO2 storage capacity and EOR by CO2 flooding. This report summarizes the geologic characterization research, the various field monitoring tests, and the development of a geologic model and numerical simulations conducted for the Aneth demonstration project. The Utah Geological Survey (UGS), with contributions from other Partners, evaluated how the surface and subsurface geology of the Aneth Unit demonstration site will affect sequestration operations and engineering strategies. The UGS-research for the project are summarized in Chapters 1 through 7, and includes (1) mapping the surface geology including stratigraphy, faulting, fractures, and deformation bands, (2) describing the local Jurassic and Cretaceous stratigraphy, (3) mapping the Desert Creek zone reservoir, Gothic seal, and overlying aquifers, (4) characterizing the depositional environments and diagenetic events that produced significant reservoir heterogeneity, (5) describing the geochemical, petrographic, and geomechanical properties of the seal to determine the CO2 or hydrocarbon column it could support, and (6) evaluating the production history to compare primary production from vertical and horizontal wells, and the effects of waterflood and wateralternating- gas flood programs. The field monitoring demonstrations were conducted by various Partners including New Mexico Institute of Mining and Technology, University of Utah, National Institute of Advanced Industrial Science and Technology, Japan, Los Alamos National Laboratory and Cambridge Geosciences. The monitoring tests are summarized in Chapters 8 through 12, and includes (1) interwell tracer studies during water- and CO2-flood operations to characterize tracer behavoirs in anticipation of CO2-sequestration applications, (2) CO2 soil flux monitoring to measure background levels and variance and assess the sensitivity levels for CO2 surface monitoring, (3) testing the continuous monitoring of self potential as a means to detect pressure anomalies and electrochemical reaction due to CO2 injection, (4) conducting time-lapse vertical seismic profiling to image change near a CO2 injection well, and (5) monitoring microseismicity using a downhole string of seismic receivers to detect fracture slip and deformation associated with stress changes. Finally, the geologic modeling and numerical simulation study was conducted by researcher at the University of Utah. Chapter 13 summarizes their efforts which focused on developing a site-specific geologic model for Aneth to better understand and design CO2 storage specifically tailored to oil reservoirs.

  16. Comparison of Caprock Mineral Characteristics at Field Demonstration Sites for Saline Aquifer Sequestration of Carbon Dioxide

    SciTech Connect (OSTI)

    Griffith, C.A.; Lowry, G. (Carnegie Mellon University); Dzombak, D. (Carnegie Mellon University); Soong, Yee; Hedges, S.W.

    2008-10-01

    In 2003 the U.S Department of Energy initiated regional partnership programs to address the concern for rising atmospheric CO2. These partnerships were formed to explore regional and economical means for geologically sequestering CO2 across the United States and to set the stage for future commercial applications. Several options exist for geological sequestration and among these sequestering CO2 into deep saline aquifers is one of the most promising. This is due, in part, to the possibility of stabilized permanent storage through mineral precipitation from chemical interactions of the injected carbon dioxide with the brine and reservoir rock. There are nine field demonstration sites for saline sequestration among the regional partnerships in Phase II development to validate the overall commercial feasibility for CO2 geological sequestration. Of the nine sites considered for Phase II saline sequestration demonstration, seven are profiled in this study for their caprock lithologic and mineral characteristics.

  17. Integrating Steel Production with Mineral Carbon Sequestration

    SciTech Connect (OSTI)

    Klaus Lackner; Paul Doby; Tuncel Yegulalp; Samuel Krevor; Christopher Graves

    2008-05-01

    The objectives of the project were (i) to develop a combination iron oxide production and carbon sequestration plant that will use serpentine ores as the source of iron and the extraction tailings as the storage element for CO2 disposal, (ii) the identification of locations within the US where this process may be implemented and (iii) to create a standardized process to characterize the serpentine deposits in terms of carbon disposal capacity and iron and steel production capacity. The first objective was not accomplished. The research failed to identify a technique to accelerate direct aqueous mineral carbonation, the limiting step in the integration of steel production and carbon sequestration. Objective (ii) was accomplished. It was found that the sequestration potential of the ultramafic resource surfaces in the US and Puerto Rico is approximately 4,647 Gt of CO2 or over 500 years of current US production of CO2. Lastly, a computer model was developed to investigate the impact of various system parameters (recoveries and efficiencies and capacities of different system components) and serpentinite quality as well as incorporation of CO2 from sources outside the steel industry.

  18. Conceptual Design of a Fossil Hydrogen Infrastructure with Capture and Sequestration of Carbon Dioxide: Case Study in Ohio

    E-Print Network [OSTI]

    2005-01-01

    Annual Conference on Carbon Sequestration. 2003. WashingtonTechnology Laboratory Carbon Sequestration program andCONFERENCE ON CARBON CAPTURE AND SEQUESTRATION DOE/NETL May

  19. Trace Metal Source Terms in Carbon Sequestration Environments

    SciTech Connect (OSTI)

    Karamalidis, Athanasios K.; Torres, Sharon G.; Hakala, J. Alexandra; Shao, Hongbo; Cantrell, Kirk J.; Carroll, Susan

    2013-01-01

    Carbon dioxide sequestration in deep saline and depleted oil geologic formations is feasible and promising, however, possible CO{sub 2} or CO{sub 2}-saturated brine leakage to overlying aquifers may pose environmental and health impacts. The purpose of this study was to experimentally define trace metal source terms from the reaction of supercritical CO{sub 2}, storage reservoir brines, reservoir and cap rocks. Storage reservoir source terms for trace metals are needed to evaluate the impact of brines leaking into overlying drinking water aquifers. The trace metal release was measured from sandstones, shales, carbonates, evaporites, basalts and cements from the Frio, In Salah, Illinois Basin – Decatur, Lower Tuscaloosa, Weyburn-Midale, Bass Islands and Grand Ronde carbon sequestration geologic formations. Trace metal dissolution is tracked by measuring solution concentrations over time under conditions (e.g. pressures, temperatures, and initial brine compositions) specific to the sequestration projects. Existing metrics for Maximum Contaminant Levels (MCLs) for drinking water as defined by the U.S. Environmental Protection Agency (U.S. EPA) were used to categorize the relative significance of metal concentration changes in storage environments due to the presence of CO{sub 2}. Results indicate that Cr and Pb released from sandstone reservoir and shale cap rock exceed the MCLs by an order of magnitude while Cd and Cu were at or below drinking water thresholds. In carbonate reservoirs As exceeds the MCLs by an order of magnitude, while Cd, Cu, and Pb were at or below drinking water standards. Results from this study can be used as a reasonable estimate of the reservoir and caprock source term to further evaluate the impact of leakage on groundwater quality.

  20. Trace Metal Source Terms in Carbon Sequestration Environments

    SciTech Connect (OSTI)

    Karamalidis, Athanasios; Torres, Sharon G.; Hakala, Jacqueline A.; Shao, Hongbo; Cantrell, Kirk J.; Carroll, Susan A.

    2013-01-01

    ABSTRACT: Carbon dioxide sequestration in deep saline and depleted oil geologic formations is feasible and promising; however, possible CO2 or CO2-saturated brine leakage to overlying aquifers may pose environmental and health impacts. The purpose of this study was to experimentally define to provide a range of concentrations that can be used as the trace element source term for reservoirs and leakage pathways in risk simulations. Storage source terms for trace metals are needed to evaluate the impact of brines leaking into overlying drinking water aquifers. The trace metal release was measured from cements and sandstones, shales, carbonates, evaporites, and basalts from the Frio, In Salah, Illinois Basin, Decatur, Lower Tuscaloosa, Weyburn-Midale, Bass Islands, and Grand Ronde carbon sequestration geologic formations. Trace metal dissolution was tracked by measuring solution concentrations over time under conditions (e.g., pressures, temperatures, and initial brine compositions) specific to the sequestration projects. Existing metrics for maximum contaminant levels (MCLs) for drinking water as defined by the U.S. Environmental Protection Agency (U.S. EPA) were used to categorize the relative significance of metal concentration changes in storage environments because of the presence of CO2. Results indicate that Cr and Pb released from sandstone reservoir and shale cap rocks exceed the MCLs byan order of magnitude, while Cd and Cu were at or below drinking water thresholds. In carbonate reservoirs As exceeds the MCLs by an order of magnitude, while Cd, Cu, and Pb were at or below drinking water standards. Results from this study can be used as a reasonable estimate of the trace element source term for reservoirs and leakage pathways in risk simulations to further evaluate the impact of leakage on groundwater quality.

  1. MIDWEST REGIONAL CARBON SEQUESTRATION PARTNERSHIP (MRCSP)

    SciTech Connect (OSTI)

    David Ball; Judith Bradbury; Rattan Lal; Larry Wickstrom; Neeraj Gupta; Robert Burns; Bob Dahowski

    2004-04-30

    This is the first semiannual report for Phase I of the Midwest Carbon Sequestration Partnership (MRCSP). The project consists of nine tasks to be conducted over a two year period that started in October 2003. The makeup of the MRCSP and objectives are described. Progress on each of the active Tasks is also described and where possible, for those Tasks at some point of completion, a summary of results is presented.

  2. Fly Ash Characteristics and Carbon Sequestration Potential

    SciTech Connect (OSTI)

    Palumbo, Anthony V.; Amonette, James E.; Tarver, Jana R.; Fagan, Lisa A.; McNeilly, Meghan S.; Daniels, William L.

    2007-07-20

    Concerns for the effects of global warming have lead to an interest in the potential for inexpensive methods to sequester carbon dioxide (CO2). One of the proposed methods is the sequestration of carbon in soil though the growth of crops or forests.4,6 If there is an economic value placed on sequestration of carbon dioxide in soil there may be an an opportunity and funding to utilize fly ash in the reclamation of mine soils and other degraded lands. However, concerns associated with the use of fly ash must be addressed before this practice can be widely adopted. There is a vast extent of degraded lands across the world that has some degree of potential for use in carbon sequestration. Degraded lands comprise nearly 2 X 109 ha of land throughout the world.7 Although the potential is obviously smaller in the United States, there are still approximately 4 X 106 ha of degraded lands that previously resulted from mining operations14 and an additional 1.4 X 108 ha of poorly managed lands. Thus, according to Lal and others the potential is to sequester approximately 11 Pg of carbon over the next 50 years.1,10 The realization of this potential will likely be dependent on economic incentives and the use of soil amendments such as fly ash. There are many potential benefits documented for the use of fly ash as a soil amendment. For example, fly ash has been shown to increase porosity, water-holding capacity, pH, conductivity, and dissolved SO42-, CO32-, HCO3-, Cl- and basic cations, although some effects are notably decreased in high-clay soils.8,13,9 The potential is that these effects will promote increased growth of plants (either trees or grasses) and result in greater carbon accumulation in the soil than in untreated degraded soils. This paper addresses the potential for carbon sequestration in soils amended with fly ash and examines some of the issues that should be considered in planning this option. We describe retrospective studies of soil carbon accumulation on reclaimed mine lands, leaching studies of fly ash and carbon sorption studies of fly ash.

  3. A Strategy for Monitoring of Geologic Sequestration of CO2

    SciTech Connect (OSTI)

    Myer, Larry R.

    2000-04-17

    Monitoring of geologic sequestration projects will require the measurement of many different parameters and processes at many different locations at the surface and in the subsurface. The greatest need for technology development is for monitoring of processes in the subsurface in the region between wells. The approach to fitting this need is to build upon decades of experience in use of geophysics in the oil and gas industry. These methods can be optimized for CO2 monitoring, and customized and extended in order to meet the need for cost-effective methods applicable to saline disposal sites, coal bed methane sites, as well as oil and gas reservoir sequestration sites. The strategy for development of cost-effective methods follows a three step iterative process of sensitivity analysis using numerical and experimental techniques, field testing at a range of scale in different formations, and analysis and integration of complimentary types of data.

  4. Mechanical effect of adsorption Carbon sequestration and swelling of coal

    E-Print Network [OSTI]

    Boyer, Edmond

    Mechanical effect of adsorption Carbon sequestration and swelling of coal Laurent BROCHARD on Carbon Capture and Sequestration (2005)) Pressure,psi Time, year Pressure 0 500 1000 1500 2000 2500 Rate Université Paris-Est. Laboratoire Navier (UMR CNRS 8205). Ecole des Ponts ParisTech CONTEXT - CARBON

  5. Carbon Sequestration Atlas and Interactive Maps from the Southwest Regional Partnership on Carbon Sequestration

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    McPherson, Brian

    In November of 2002, DOE announced a global climate change initiative involving joint government-industry partnerships working together to find sensible, low cost solutions for reducing GHG emissions. As a result, seven regional partnerships were formed; the Southwest Regional Partnership on Carbon Sequestration (SWP) is one of those. These groups are utilizing their expertise to assess sequestration technologies to capture carbon emissions, identify and evaluate appropriate storage locations, and engage a variety of stakeholders in order to increase awareness of carbon sequestration. Stakeholders in this project are made up of private industry, NGOs, the general public, and government entities. There are a total of 44 current organizations represented in the partnership including electric utilities, oil and gas companies, state governments, universities, NGOs, and tribal nations. The SWP is coordinated by New Mexico Tech and encompasses New Mexico, Arizona, Colorado, Oklahoma, Utah, and portions of Kansas, Nevada, Texas, and Wyoming. Field test sites for the region are located in New Mexico (San Juan Basin), Utah (Paradox Basin), and Texas (Permian Basin).[Taken from the SWP C02 Sequestration Atlas] The SWP makes available at this website their CO2 Sequestration Atlas and an interactive data map.

  6. Efficiency of incentives to jointly increase carbon sequestration and species conservation

    E-Print Network [OSTI]

    Thomas, David D.

    Efficiency of incentives to jointly increase carbon sequestration and species conservation the provision of carbon sequestration and species conservation across heterogeneous landscapes. Using data from the Willamette Basin, Oregon, we compare the provision of carbon sequestration and species conservation under

  7. Carbon sequestration potential of tropical pasture compared with afforestation in Panama

    E-Print Network [OSTI]

    Potvin, Catherine

    Carbon sequestration potential of tropical pasture compared with afforestation in Panama S E B) to estimate the carbon sequestration potential of tropical pasture compared with afforestation; and (3 show the potential for considerable carbon sequestration of tropical afforestation and highlight

  8. Carbon dioxide reuse and sequestration: The state of the art today

    E-Print Network [OSTI]

    Benson, Sally M.; Dorchak, Thomas; Jacobs, Gary; Ekmann, James; Bishop, Jim; Grahame, Thomas

    2000-01-01

    projects related to carbon sequestration, Presented at theDOE workshop on carbon sequestration, Washington D.C. ,29. U.S. DOE, Carbon Sequestration: State of the Science,

  9. Carbon Sequestration and Its Role in the Global Carbon Cycle Geophysical Monograph Series 183

    E-Print Network [OSTI]

    Pennycook, Steve

    73 Carbon Sequestration and Its Role in the Global Carbon Cycle Geophysical Monograph Series 183. Blaine Metting2 The purpose of this chapter is to review terrestrial biological carbon sequestration Northwest National Laboratory, Richland, Washington, USA. #12;74 TERRESTRIAL BIOLOGICAL CARBON SEqUESTRATION

  10. Integrated Mid-Continent Carbon Capture, Sequestration & Enhanced Oil Recovery Project

    SciTech Connect (OSTI)

    Brian McPherson

    2010-08-31

    A consortium of research partners led by the Southwest Regional Partnership on Carbon Sequestration and industry partners, including CAP CO2 LLC, Blue Source LLC, Coffeyville Resources, Nitrogen Fertilizers LLC, Ash Grove Cement Company, Kansas Ethanol LLC, Headwaters Clean Carbon Services, Black & Veatch, and Schlumberger Carbon Services, conducted a feasibility study of a large-scale CCS commercialization project that included large-scale CO{sub 2} sources. The overall objective of this project, entitled the 'Integrated Mid-Continent Carbon Capture, Sequestration and Enhanced Oil Recovery Project' was to design an integrated system of US mid-continent industrial CO{sub 2} sources with CO{sub 2} capture, and geologic sequestration in deep saline formations and in oil field reservoirs with concomitant EOR. Findings of this project suggest that deep saline sequestration in the mid-continent region is not feasible without major financial incentives, such as tax credits or otherwise, that do not exist at this time. However, results of the analysis suggest that enhanced oil recovery with carbon sequestration is indeed feasible and practical for specific types of geologic settings in the Midwestern U.S.

  11. Proposed roadmap for overcoming legal and financial obstacles to carbon capture and sequestration

    SciTech Connect (OSTI)

    Jacobs, Wendy ); Chohen, Leah; Kostakidis-Lianos, Leah; Rundell, Sara )

    2009-03-01

    Many existing proposals either lack sufficient concreteness to make carbon capture and geological sequestration (CCGS) operational or fail to focus on a comprehensive, long term framework for its regulation, thus failing to account adequately for the urgency of the issue, the need to develop immediate experience with large scale demonstration projects, or the financial and other incentives required to launch early demonstration projects. We aim to help fill this void by proposing a roadmap to commercial deployment of CCGS in the United States.This roadmap focuses on the legal and financial incentives necessary for rapid demonstration of geological sequestration in the absence of national restrictions on CO2 emissions. It weaves together existing federal programs and financing opportunities into a set of recommendations for achieving commercial viability of geological sequestration.

  12. Risk Assessment of Geologic Formation Sequestration in The Rocky Mountain Region, USA

    SciTech Connect (OSTI)

    Lee, Si-Yong; McPherson, Brian

    2013-08-01

    The purpose of this report is to describe the outcome of a targeted risk assessment of a candidate geologic sequestration site in the Rocky Mountain region of the USA. Specifically, a major goal of the probabilistic risk assessment was to quantify the possible spatiotemporal responses for Area of Review (AoR) and injection-induced pressure buildup associated with carbon dioxide (CO?) injection into the subsurface. Because of the computational expense of a conventional Monte Carlo approach, especially given the likely uncertainties in model parameters, we applied a response surface method for probabilistic risk assessment of geologic CO? storage in the Permo-Penn Weber formation at a potential CCS site in Craig, Colorado. A site-specific aquifer model was built for the numerical simulation based on a regional geologic model.

  13. A Finite Element Model for Simulation of Carbon Dioxide Sequestration

    SciTech Connect (OSTI)

    Bao, Jie; Xu, Zhijie; Fang, Yilin

    2013-11-02

    We present a hydro-mechanical model, followed by stress, deformation, and shear-slip failure analysis for geological sequestration of carbon dioxide (CO2). The model considers the poroelastic effects by taking into account of the two-way coupling between the geomechanical response and the fluid flow process. Analytical solutions for pressure and deformation fields were derived for a typical geological sequestration scenario in our previous work. A finite element approach is introduced here for numerically solving the hydro-mechanical model with arbitrary boundary conditions. The numerical approach was built on an open-source finite element code Elmer, and results were compared to the analytical solutions. The shear-slip failure analysis was presented based on the numerical results, where the potential failure zone is identified. Information is relevant to the prediction of the maximum sustainable injection rate or pressure. The effects of caprock permeability on the fluid pressure, deformation, stress, and the shear-slip failure zone were also quantitatively studied. It was shown that a larger permeability in caprock and base rock leads to a larger uplift but a smaller shear-slip failure zone.

  14. Carbon dioxide sequestration in concrete in different curing environments

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    Carbon dioxide sequestration in concrete in different curing environments Y.-m. Chun, T.R. Naik, USA ABSTRACT: This paper summarizes the results of an investigation on carbon dioxide (CO2) sequestration in concrete. Concrete mixtures were not air entrained. Concrete mixtures were made containing

  15. Received 28 Apr 2013 | Accepted 9 Sep 2013 | Published 15 Oct 2013 Earthworms facilitate carbon sequestration through

    E-Print Network [OSTI]

    Neher, Deborah A.

    carbon sequestration through unequal amplification of carbon stabilization compared with mineralization carbon would entirely reflect the earthworms' contribution to net carbon sequestration. We show how two widespread earthworm invaders affect net carbon sequestration through impacts on the balance of carbon

  16. Carbon Dioxide Capture/Sequestration Tax Deduction (Kansas)

    Broader source: Energy.gov [DOE]

    Carbon Dioxide Capture/Sequestration Tax Deduction allows a taxpayer a deduction to adjusted gross income with respect to the amortization of the amortizable costs of carbon dioxide capture,...

  17. Investigations into Wetland Carbon Sequestration as Remediation for Global Warming

    SciTech Connect (OSTI)

    Thom, Ronald M.; Blanton, Susan L.; Borde, Amy B.; Williams, Greg D.; Woodruff, Dana L.; Huesemann, Michael H.; KW Nehring and SE Brauning

    2002-01-01

    Wetlands can potentially sequester vast amounts of carbon. However, over 50% of wetlands globally have been degraded or lost. Restoration of wetland systems may therefore result in increased sequestration of carbon. Preliminary results of our investigations into atmospheric carbon sequestration by restored coastal wetlands indicate that carbon can be sequestered in substantial quantities in the first 2-50 years after restoration of natural hydrology and sediment accretion processes.

  18. Carbon Dioxide Sequestration in Concrete Using Vacuum-Carbonation Alain Azar, Prof. Yixin Shao

    E-Print Network [OSTI]

    Barthelat, Francois

    Carbon Dioxide Sequestration in Concrete Using Vacuum-Carbonation Alain Azar, Prof. Yixin Shao promising carbon uptake results and is a viable option for carbonation curing. Carbon sequestration increase in Carbon dioxide (CO2) emissions over the past five decades, specific ways to reduce

  19. An Alternative Mechanism for Accelerated Carbon Sequestration in Concrete

    SciTech Connect (OSTI)

    Haselbach, Liv M.; Thomle, Jonathan N.

    2014-07-01

    The increased rate of carbon dioxide sequestration (carbonation) is desired in many primary and secondary life applications of concrete in order to make the life cycle of concrete structures more carbon neutral. Most carbonation rate studies have focused on concrete exposed to air under various conditions. An alternative mechanism for accelerated carbon sequestration in concrete was investigated in this research based on the pH change of waters in contact with pervious concrete which have been submerged in carbonate laden waters. The results indicate that the concrete exposed to high levels of carbonate species in water may carbonate faster than when exposed to ambient air, and that the rate is higher with higher concentrations. Validation of increased carbon dioxide sequestration was also performed via thermogravimetric analysis (TGA). It is theorized that the proposed alternative mechanism reduces a limiting rate effect of carbon dioxide dissolution in water in the micro pores of the concrete.

  20. Enhanced Performance Assessment System (EPAS) for carbon sequestration.

    SciTech Connect (OSTI)

    Wang, Yifeng; Sun, Amy Cha-Tien; McNeish, Jerry A. (Sandia National Laboratories, Livermore, CA); Dewers, Thomas A.; Hadgu, Teklu; Jove-Colon, Carlos F.

    2010-09-01

    Carbon capture and sequestration (CCS) is an option to mitigate impacts of atmospheric carbon emission. Numerous factors are important in determining the overall effectiveness of long-term geologic storage of carbon, including leakage rates, volume of storage available, and system costs. Recent efforts have been made to apply an existing probabilistic performance assessment (PA) methodology developed for deep nuclear waste geologic repositories to evaluate the effectiveness of subsurface carbon storage (Viswanathan et al., 2008; Stauffer et al., 2009). However, to address the most pressing management, regulatory, and scientific concerns with subsurface carbon storage (CS), the existing PA methodology and tools must be enhanced and upgraded. For example, in the evaluation of a nuclear waste repository, a PA model is essentially a forward model that samples input parameters and runs multiple realizations to estimate future consequences and determine important parameters driving the system performance. In the CS evaluation, however, a PA model must be able to run both forward and inverse calculations to support optimization of CO{sub 2} injection and real-time site monitoring as an integral part of the system design and operation. The monitoring data must be continually fused into the PA model through model inversion and parameter estimation. Model calculations will in turn guide the design of optimal monitoring and carbon-injection strategies (e.g., in terms of monitoring techniques, locations, and time intervals). Under the support of Laboratory-Directed Research & Development (LDRD), a late-start LDRD project was initiated in June of Fiscal Year 2010 to explore the concept of an enhanced performance assessment system (EPAS) for carbon sequestration and storage. In spite of the tight time constraints, significant progress has been made on the project: (1) Following the general PA methodology, a preliminary Feature, Event, and Process (FEP) analysis was performed for a hypothetical CS system. Through this FEP analysis, relevant scenarios for CO{sub 2} release were defined. (2) A prototype of EPAS was developed by wrapping an existing multi-phase, multi-component reservoir simulator (TOUGH2) with an uncertainty quantification and optimization code (DAKOTA). (3) For demonstration, a probabilistic PA analysis was successfully performed for a hypothetical CS system based on an existing project in a brine-bearing sandstone. The work lays the foundation for the development of a new generation of PA tools for effective management of CS activities. At a top-level, the work supports energy security and climate change/adaptation by furthering the capability to effectively manage proposed carbon capture and sequestration activities (both research and development as well as operational), and it greatly enhances the technical capability to address this national problem. The next phase of the work will include (1) full capability demonstration of the EPAS, especially for data fusion, carbon storage system optimization, and process optimization of CO{sub 2} injection, and (2) application of the EPAS to actual carbon storage systems.

  1. Overview of the United States Priorities and Research Programs on Carbon Sequestration

    E-Print Network [OSTI]

    ' Department of Energy established a Carbon Sequestration Program in 1998, Regional Carbon SequestrationOverview of the United States Priorities and Research Programs on Carbon Sequestration M. Karmis Partnerships in 2003, and FutureGen, the Integrated Sequestration and Hydrogen Research Initiative, in 2003

  2. NATCARB Interactive Maps and the National Carbon Explorer: a National Look at Carbon Sequestration

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    NATCARB is a national look at carbon sequestration. The NATCARB home page, National Carbon Explorer (http://www.natcarb.org/) provides access to information and interactive maps on a national scale about climate change, DOE's carbon sequestration program and its partnerships, CO2 emissions, and sinks. This portal provides access to interactive maps based on the Carbon Sequestration Atlas of the United States and Canada.

  3. Agricultural Soil Carbon Sequestration Offset Programs: Strengths, Difficulties, and Suggestions for Their Potential Use in AB 32's Cap and Trade Program

    E-Print Network [OSTI]

    Bernadett, Lauren

    2013-01-01

    harms involved in agricultural soil carbon sequestration.et al. , Soil Carbon Sequestration – Fundamentals , O HIO Sland-management/soil-carbon- sequestration/en/ (last visited

  4. Developing microbe-plant interactions for applications in plant-growth promotion and disease control, production of useful compounds, remediation, and carbon sequestration

    E-Print Network [OSTI]

    Bernard, S.

    2009-01-01

    Remediation, and Carbon Sequestration References Anderson,Remediation, and Carbon Sequestration rhizosphere byRemediation, and Carbon Sequestration Figure 1. Examples of

  5. Near Surface Leakage Monitoring for the Verification and Accounting of Geologic Carbon Sequestration Using a Field Ready {sup 14}C Isotopic Analyzer

    SciTech Connect (OSTI)

    Marino, Bruno

    2014-04-14

    Results for the development of a field ready multi-isotopic analyzer for {sup 12}CO{sub 2}, {sup 13}CO{sub 2} and {sup 14}CO{sub 2} and applications for carbon capture and storage (CCS) containment performance are described. A design goal of the field platform was to provide isotopic data with a high data rate, a standardized reference baseline and acceptable precision (e.g., ~ ±50 per mil D{sup 14}CO{sub 2}) for detection and quantification of fossil-fuel CO{sub 2} CCS leakage scenarios. The instrument platform was not designed to replace high precision accelerator mass spectrometry. An additional goal was to combine project scale isotopic data and associated fluxes with unique financial instruments linking CCS containment performance to a publicly traded security providing project revenue to stakeholders. While the primary goals of the project were attained additional work is needed for the instrument platform and deployment within a full scale CCS site that was not available during the project timeframe.

  6. Researchers question published no-till soil organic carbon sequestration rates | EurekAlert ...

    E-Print Network [OSTI]

    ... published no-till soil organic carbon sequestration rates ... researchers have published soil organic carbon sequestration rates. Many of the ... have suggested that soil organic carbon can be sequestered by simply ...

  7. Annual meeting of Big Sky Carbon Sequestration Partnership to be held Oct. 28, 29 | ...

    E-Print Network [OSTI]

    ... Annual meeting of Big Sky Carbon Sequestration Partnership to be held ... meeting of the Big Sky Carbon Sequestration Partnership to be held ... science policy and technology of carbon capture and storage (CCS). Panels ...

  8. Register by Oct. 21 for annual carbon sequestration meeting | EurekAlert! Science News

    E-Print Network [OSTI]

    ... by Oct. 21 for annual carbon sequestration meeting ... meeting of the Big Sky Carbon Sequestration Partnership to be held ... science policy and technology of carbon capture and storage (CCS). Panels ...

  9. Thermodynamic Data for Geochemical Modeling of Carbonate Reactions Associated with CO2 Sequestration – Literature Review

    SciTech Connect (OSTI)

    Krupka, Kenneth M.; Cantrell, Kirk J.; McGrail, B. Peter

    2010-09-28

    Permanent storage of anthropogenic CO2 in deep geologic formations is being considered as a means to reduce the concentration of atmospheric CO2 and thus its contribution to global climate change. To ensure safe and effective geologic sequestration, numerous studies have been completed of the extent to which the CO2 migrates within geologic formations and what physical and geochemical changes occur in these formations when CO2 is injected. Sophisticated, computerized reservoir simulations are used as part of field site and laboratory CO2 sequestration studies. These simulations use coupled multiphase flow-reactive chemical transport models and/or standalone (i.e., no coupled fluid transport) geochemical models to calculate gas solubility, aqueous complexation, reduction/oxidation (redox), and/or mineral solubility reactions related to CO2 injection and sequestration. Thermodynamic data are critical inputs to modeling geochemical processes. The adequacy of thermodynamic data for carbonate compounds has been identified as an important data requirement for the successful application of these geochemical reaction models to CO2 sequestration. A review of thermodynamic data for CO2 gas and carbonate aqueous species and minerals present in published data compilations and databases used in geochemical reaction models was therefore completed. Published studies that describe mineralogical analyses from CO2 sequestration field and natural analogue sites and laboratory studies were also reviewed to identify specific carbonate minerals that are important to CO2 sequestration reactions and therefore require thermodynamic data. The results of the literature review indicated that an extensive thermodynamic database exists for CO2 and CH4 gases, carbonate aqueous species, and carbonate minerals. Values of ?fG298° and/or log Kr,298° are available for essentially all of these compounds. However, log Kr,T° or heat capacity values at temperatures above 298 K exist for less than approximately one-third of these compounds. Because the temperatures of host formations that will be used for CO2 injection and sequestration will be at tempera¬tures in the range of 50ºC to 100ºC or greater, the lack of high temperature thermodynamic values for key carbonate compounds especially minerals, will impact the accuracy of some modeling calculations.

  10. Seismicity Characterization and Monitoring at WESTCARB's Proposed Montezuma Hills Geologic Sequestration Site

    SciTech Connect (OSTI)

    Daley, T.M.; Haught, R.; Peterson, J.E.; Boyle, K.; Beyer, J.H.; Hutchings, L.R.

    2010-09-15

    The West Coast Regional Carbon Sequestration Partnership (WESTCARB), in collaboration with Shell Oil Co. performed site characterization for a potential small-scale pilot test of geologic sequestration of carbon dioxide (CO2). The site area, know as Montezuma Hills, is near the town of Rio Vista in northern California. During the process of injection at a CO2 storage site, there is a potential for seismic events due to slippage upon pre-existing discontinuities or due to creation of new fractures. Observations from many injection projects have shown that the energy from these events can be used for monitoring of processes in the reservoir. Typically, the events are of relatively high frequency and very low amplitude. However, there are also well documented (non-CO2-related) cases in which subsurface injection operations have resulted in ground motion felt by near-by communities. Because of the active tectonics in California (in particular the San Andreas Fault system), and the potential for public concern, WESTCARB developed and followed an induced seismicity protocol (Myer and Daley, 2010). This protocol called for assessing the natural seismicity in the area and deploying a monitoring array if necessary. In this report, we present the results of the natural seismicity assessment and the results of an initial temporary deployment of two seismometers at the Montezuma Hills site. Following the temporary array deployment, the project was suspended and the array removed in August of 2010.

  11. Management of water extracted from carbon sequestration projects

    SciTech Connect (OSTI)

    Harto, C. B.; Veil, J. A.

    2011-03-11

    Throughout the past decade, frequent discussions and debates have centered on the geological sequestration of carbon dioxide (CO{sub 2}). For sequestration to have a reasonably positive impact on atmospheric carbon levels, the anticipated volume of CO{sub 2} that would need to be injected is very large (many millions of tons per year). Many stakeholders have expressed concern about elevated formation pressure following the extended injection of CO{sub 2}. The injected CO{sub 2} plume could potentially extend for many kilometers from the injection well. If not properly managed and monitored, the increased formation pressure could stimulate new fractures or enlarge existing natural cracks or faults, so the CO{sub 2} or the brine pushed ahead of the plume could migrate vertically. One possible tool for management of formation pressure would be to extract water already residing in the formation where CO{sub 2} is being stored. The concept is that by removing water from the receiving formations (referred to as 'extracted water' to distinguish it from 'oil and gas produced water'), the pressure gradients caused by injection could be reduced, and additional pore space could be freed up to sequester CO{sub 2}. Such water extraction would occur away from the CO{sub 2} plume to avoid extracting a portion of the sequestered CO{sub 2} along with the formation water. While water extraction would not be a mandatory component of large-scale carbon storage programs, it could provide many benefits, such as reduction of pressure, increased space for CO{sub 2} storage, and potentially, 'plume steering.' Argonne National Laboratory is developing information for the U.S. Department of Energy's (DOE's) National Energy Technology Laboratory (NETL) to evaluate management of extracted water. If water is extracted from geological formations designated to receive injected CO{sub 2} for sequestration, the project operator will need to identify methods for managing very large volumes of water most of which will contain large quantities of salt and other dissolved minerals. Produced water from oil and gas production also typically contains large quantities of dissolved solids. Therefore, many of the same practices that are established and used for managing produced water also may be applicable for extracted water. This report describes the probable composition of the extracted water that is removed from the formations, options for managing the extracted water, the pros and cons of those options, and some opportunities for beneficial use of the water. Following the introductory material in Chapter 1, the report is divided into chapters covering the following topics: (Chapter 2) examines the formations that are likely candidates for CO{sub 2} sequestration and provides a general evaluation of the geochemical characteristics of the formations; (Chapter 3) makes some preliminary estimates of the volume of water that could be extracted; (Chapter 4) provides a qualitative review of many potential technologies and practices for managing extracted water and for each technology or management practice, pros and cons are provided; (Chapter 5) explores the potential costs of water management; and (Chapter 6) presents the conclusions.

  12. Forest cover, carbon sequestration, and wildlife habitat: policy review and modeling of tradeoffs among land-use

    E-Print Network [OSTI]

    Rissman, Adena

    Forest cover, carbon sequestration, and wildlife habitat: policy review and modeling of tradeoffs and services, including timber production, carbon sequestration and storage, scenic amenities, and wildlife habitat. International efforts to mitigate climate change through forest carbon sequestration

  13. Measurements of carbon sequestration by long-term eddy covariance: methods and a critical evaluation of accuracy

    E-Print Network [OSTI]

    Goulden, ML; Munger, JW; Song-Miao, F; Daube, BC; Wofsy, SC

    1996-01-01

    182 Measurements of carbon sequestration by long-term eddyerror. The integrated carbon sequestration in 1994 was 2.1 ton the annual carbon sequestration in 1994 of -0.3 to +0.8 t

  14. GEOLOGIC CARBON SEQUESTRATION STRATEGIES FOR CALIFORNIA

    E-Print Network [OSTI]

    of Oil and Gas and Geothermal Resources in the Department of Conservation for his contributions Resources Conservation and Development Commission, in coordination with the Division of Oil, Gas National Laboratory, Vello Kuuskraa of Advanced Resources International, Inc., Sarah Wade of AJW, Inc

  15. Carbon Trading Protocols for Geologic Sequestration

    E-Print Network [OSTI]

    Hoversten, Shanna

    2009-01-01

    EU ETS: European Union Emissions Trading System GHG: Greenstarts operating an emissions trading scheme (ETS) similarGovernments operating emissions trading systems face the

  16. Carbon Trading Protocols for Geologic Sequestration

    E-Print Network [OSTI]

    Hoversten, Shanna

    2009-01-01

    apply, because the cost of capturing the CO2 at the emissionsource exceeds the cost of getting the CO2 from underground,

  17. Carbon Trading Protocols for Geologic Sequestration

    E-Print Network [OSTI]

    Hoversten, Shanna

    2009-01-01

    conventional oil or natural gas production, enhanced oil and gas production, and liquid hydrocarbons.

  18. Carbon Trading Protocols for Geologic Sequestration

    E-Print Network [OSTI]

    Hoversten, Shanna

    2009-01-01

    can an EOR project receive ERCs for re-injecting CO2 unlessthe CO2 from underground, thus awarding ERCs to an EORCO2, whereas a barrel of crude oil obtained through EOR

  19. Cost Assessment of CO2 Sequestration by Mineral Carbonation 

    E-Print Network [OSTI]

    Yeboah, F. E.; Yegulalp, T. M.; Singh, H.

    2006-01-01

    in the generation of electrical energy. The concept of clean coal technology will be introduced. This will then be followed by a description of sequestration by mineral carbonation. The various processes involved in sequestration process will also be discussed... Policy 31, p. 1315 – 1326. 4. Yeboah, F.E., 2004, Valuation of Clean Energy Investments – The Case of the Zero Emission Coal (ZEC) Technology. Unpublished Doctoral Dissertation, Fu School of Engineering, Columbia University, New York, NY. 5...

  20. Monitoring and verifying agricultural practices related to soil carbon sequestration with satellite imagery

    E-Print Network [OSTI]

    Lawrence, Rick L.

    Monitoring and verifying agricultural practices related to soil carbon sequestration with satellite on agricultural management practices related to carbon sequestration seems more realistic, and analysis practices related to carbon sequestration over large areas. Published by Elsevier B.V. Keywords: Carbon

  1. Evaluating the impact of aquifer layer properties on geomechanical response during CO2 geological sequestration

    SciTech Connect (OSTI)

    Bao, Jie; Xu, Zhijie; Lin, Guang; Fang, Yilin

    2013-04-01

    Numerical models play an essential role in understanding the facts of carbon dioxide (CO2) geological sequestration in the life cycle of a storage reservoir. We present a series of test cases that reflect a broad and realistic range of aquifer reservoir properties to systematically evaluate and compare the impacts on the geomechanical response to CO2 injection. In this study, a coupled hydro-mechanical model was introduced to simulate the sequestration process, and a quasi-Monte Carlo sampling method was introduced to efficiently sample the value of aquifer properties and geometry parameters. Aquifer permeability was found to be of significant importance to the geomechanical response to the injection. To study the influence of uncertainty of the permeability distribution in the aquifer, an additional series of tests is presented, based on a default permeability distribution site sample with various distribution deviations generated by the Monte Carlo sampling method. The results of the test series show that different permeability distributions significantly affect the displacement and possible failure zone.

  2. CONFERENCE PROCEEDINGS EIGHTH ANNUAL CONFERENCE ON CARBON CAPTURE AND SEQUESTRATION -DOE/NETL

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    CONFERENCE PROCEEDINGS EIGHTH ANNUAL CONFERENCE ON CARBON CAPTURE AND SEQUESTRATION - DOE/NETL May ON CARBON CAPTURE AND SEQUESTRATION - DOE/NETL May 4 ­ 7, 2009 Abstract Reservoir simulation is the industry

  3. GEOLOGIC SCREENING CRITERIA FOR SEQUESTRATION OF CO2 IN COAL: QUANTIFYING POTENTIAL OF THE BLACK WARRIOR COALBED METHANE FAIRWAY, ALABAMA

    SciTech Connect (OSTI)

    Jack C. Pashin; Richard E. Carroll; Richard H. Groshong Jr.; Dorothy E. Raymond; Marcella McIntyre; J. Wayne Payton

    2004-01-01

    Sequestration of CO{sub 2} in coal has potential benefits for reducing greenhouse gas emissions from the highly industrialized Carboniferous coal basins of North America and Europe and for enhancing coalbed methane recovery. Hence, enhanced coalbed methane recovery operations provide a basis for a market-based environmental solution in which the cost of sequestration is offset by the production and sale of natural gas. The Black Warrior foreland basin of west-central Alabama contains the only mature coalbed methane production fairway in eastern North America, and data from this basin provide an excellent basis for quantifying the carbon sequestration potential of coal and for identifying the geologic screening criteria required to select sites for the demonstration and commercialization of carbon sequestration technology. Coalbed methane reservoirs in the upper Pottsville Formation of the Black Warrior basin are extremely heterogeneous, and this heterogeneity must be considered to screen areas for the application of CO{sub 2} sequestration and enhanced coalbed methane recovery technology. Major screening factors include stratigraphy, geologic structure, geothermics, hydrogeology, coal quality, sorption capacity, technology, and infrastructure. Applying the screening model to the Black Warrior basin indicates that geologic structure, water chemistry, and the distribution of coal mines and reserves are the principal determinants of where CO{sub 2} can be sequestered. By comparison, coal thickness, temperature-pressure conditions, and coal quality are the key determinants of sequestration capacity and unswept coalbed methane resources. Results of this investigation indicate that the potential for CO{sub 2} sequestration and enhanced coalbed methane recovery in the Black Warrior basin is substantial and can result in significant reduction of greenhouse gas emissions while increasing natural gas reserves. Coal-fired power plants serving the Black Warrior basin in Alabama emit approximately 31 MMst (2.4 Tcf) of CO{sub 2} annually. The total sequestration capacity of the Black Warrior coalbed methane fairway at 350 psi is about 189 MMst (14.9 Tcf), which is equivalent to 6.1 years of greenhouse gas emissions from the coal-fired power plants. Applying the geologic screening model indicates that significant parts of the coalbed methane fairway are not accessible because of fault zones, coal mines, coal reserves, and formation water with TDS content less than 3,000 mg/L. Excluding these areas leaves a sequestration potential of 60 MMst (4.7 Tcf), which is equivalent to 1.9 years of emissions. Therefore, if about10 percent of the flue gas stream from nearby power plants is dedicated to enhanced coalbed methane recovery, a meaningful reduction of CO{sub 2} emissions can be realized for nearly two decades. If the fresh-water restriction were removed for the purposes of CO{sub 2} sequestration, an additional 10 MMst (0.9 Tcf) of CO{sub 2} could feasibly be sequestered. The amount of unswept coalbed methane in the fairway is estimated to be 1.49 Tcf at a pressure of 50 psi. Applying the screening model results in an accessible unswept gas resource of 0.44 Tcf. Removal of the fresh-water restriction would elevate this number to 0.57 Tcf. If a recovery factor of 80 percent can be realized, then enhanced recovery activities can result in an 18 percent expansion of coalbed methane reserves in the Black Warrior basin.

  4. Carbon Sequestration on Surface Mine Lands

    SciTech Connect (OSTI)

    Donald Graves; Christopher Barton; Richard Sweigard; Richard Warner; Carmen Agouridis

    2006-03-31

    Since the implementation of the federal Surface Mining Control and Reclamation Act of 1977 (SMCRA) in May of 1978, many opportunities have been lost for the reforestation of surface mines in the eastern United States. Research has shown that excessive compaction of spoil material in the backfilling and grading process is the biggest impediment to the establishment of productive forests as a post-mining land use (Ashby, 1998, Burger et al., 1994, Graves et al., 2000). Stability of mine sites was a prominent concern among regulators and mine operators in the years immediately following the implementation of SMCRA. These concerns resulted in the highly compacted, flatly graded, and consequently unproductive spoils of the early post-SMCRA era. However, there is nothing in the regulations that requires mine sites to be overly compacted as long as stability is achieved. It has been cultural barriers and not regulatory barriers that have contributed to the failure of reforestation efforts under the federal law over the past 27 years. Efforts to change the perception that the federal law and regulations impede effective reforestation techniques and interfere with bond release must be implemented. Demonstration of techniques that lead to the successful reforestation of surface mines is one such method that can be used to change perceptions and protect the forest ecosystems that were indigenous to these areas prior to mining. The University of Kentucky initiated a large-scale reforestation effort to address regulatory and cultural impediments to forest reclamation in 2003. During the three years of this project 383,000 trees were planted on over 556 acres in different physiographic areas of Kentucky (Table 1, Figure 1). Species used for the project were similar to those that existed on the sites before mining was initiated (Table 2). A monitoring program was undertaken to evaluate growth and survival of the planted species as a function of spoil characteristics and reclamation practice. In addition, experiments were integrated within the reforestation effort to address specific questions pertaining to sequestration of carbon (C) on these sites.

  5. What is the optimal heather moorland management regime for carbon sequestration?

    E-Print Network [OSTI]

    Guo, Zaoyang

    What is the optimal heather moorland management regime for carbon sequestration? Supervisors: Prof, the Muirburn Code has no evidence base with regard to carbon sequestration. Given the increased concern use moorland carbon sequestration to offset emissions, it is essential that the most appropriate land

  6. Silvia Solano's interest in carbon sequestration was first sparked on a six-month internship

    E-Print Network [OSTI]

    Yang, Zong-Liang

    Silvia Solano's interest in carbon sequestration was first sparked on a six-month internship experiments combining EOR with carbon sequestration. "I thought this was a win-win solution," she said. "You of a research team conduct- ing a large-scale test of carbon sequestration. "I knew I wanted to learn more about

  7. Carbon storage and sequestration by trees in urban and community areas of the United States

    E-Print Network [OSTI]

    Carbon storage and sequestration by trees in urban and community areas of the United States David J forestry Tree cover Forest inventory a b s t r a c t Carbon storage and sequestration by urban trees to determine total urban forest carbon storage and annual sequestration by state and nationally. Urban whole

  8. Carbon dioxide sequestration: how much and when? Klaus Keller & David McInerney & David F. Bradford

    E-Print Network [OSTI]

    Keller, Klaus

    Carbon dioxide sequestration: how much and when? Klaus Keller & David McInerney & David F. Bradford + Business Media B.V. 2008 Abstract Carbon dioxide (CO2) sequestration has been proposed as a key component fossil fuel requirement of CO2 sequestration, and the growth rate of carbon taxes. In this analytical

  9. Carbon Capture and Sequestration: how much does this uncertain option affect near-term policy choices?

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Carbon Capture and Sequestration: how much does this uncertain option affect near-term policy Carbon Capture and Sequestration (CCS) as a key option to avoid costly emission reduction. While Carbon Capture and Sequestration (CCS) technologies are receiving increasing atten- tion, mainly

  10. Evaluating the options for carbon sequestration Clair Gough and Simon Shackley

    E-Print Network [OSTI]

    Watson, Andrew

    Evaluating the options for carbon sequestration Clair Gough and Simon Shackley Tyndall Centre for carbon sequestration Tyndall Centre Technical Report No. 2 November 2002 This is the final report from Tyndall research project IT1.22 (Carbon sequestration: a pilot stage multi-criteria evaluation

  11. CARBON SEQUESTRATION FROM REMOTELY-SENSED NDVI AND NET ECOSYSTEM EXCHANGE

    E-Print Network [OSTI]

    Hunt Jr., E. Raymond

    Chapter 8 CARBON SEQUESTRATION FROM REMOTELY- SENSED NDVI AND NET ECOSYSTEM EXCHANGE E. Raymond sampling to determine areas of carbon sequestration. With large areas of the globe covered by rangelands, the potential for carbon sequestration may be significant. R. S. Muttiah (ed.), From Laboratory Spectroscopy

  12. Pathways to Adoption of Carbon Capture and Sequestration in India: Technologies and Policies

    E-Print Network [OSTI]

    Pathways to Adoption of Carbon Capture and Sequestration in India: Technologies and Policies, Technology and Policy Program #12;2 #12;Pathways to Carbon Capture and Sequestration in India: Technologies to control India's emissions will have to be a global priority. Carbon capture and sequestration (CCS) can

  13. ECONOMIC MODELING OF THE GLOBAL ADOPTION OF CARBON CAPTURE AND SEQUESTRATION TECHNOLOGIES

    E-Print Network [OSTI]

    ECONOMIC MODELING OF THE GLOBAL ADOPTION OF CARBON CAPTURE AND SEQUESTRATION TECHNOLOGIES J. R. Mc of carbon capture and sequestration technologies as applied to electric generating plants. The MIT Emissions, is used to model carbon capture and sequestration (CCS) technologies based on a natural gas combined cycle

  14. Carbon Sequestration in Terrestrial Ecosystems (CSiTE) PRINCIPAL INVESTIGATOR: Stan D. Wullschleger

    E-Print Network [OSTI]

    Carbon Sequestration in Terrestrial Ecosystems (CSiTE) PRINCIPAL INVESTIGATOR: Stan D. Wullschleger://csite.eds.ornl.gov PROJECT DESCRIPTION The Carbon Sequestration in Terrestrial Ecosystems (CSiTE) project conducts research of switchgrass growing in the field. #12;Carbon Sequestration in Terrestrial Ecosystems (CSiTE) tion of inputs

  15. Nonlinear root-derived carbon sequestration across a gradient of nitrogen and phosphorous deposition

    E-Print Network [OSTI]

    Jackson, Robert B.

    Nonlinear root-derived carbon sequestration across a gradient of nitrogen and phosphorous sequestration of plant-carbon (C) inputs to soil may mitigate rising atmo- spheric carbon dioxide (CO2) concentrations and related climate change but how this sequestration will respond to anthropogenic nitrogen (N

  16. Sustainability of terrestrial carbon sequestration: A case study in Duke Forest with inversion approach

    E-Print Network [OSTI]

    DeLucia, Evan H.

    Sustainability of terrestrial carbon sequestration: A case study in Duke Forest with inversion of terrestrial carbon (C) sequestration is critical for the success of any policies geared toward stabilizing. Ellsworth, A. Finzi, J. Lichter, and W. H. Schlesinger, Sustainability of terrestrial carbon sequestration

  17. 19.1 Introduction Carbon sequestration programs on land and in the

    E-Print Network [OSTI]

    Jackson, Robert B.

    Chapter 19 19.1 Introduction Carbon sequestration programs on land and in the oceans are gaining sequestration programs emphasize storing carbon in soil organic matter in agri- cultural fields,in woody sequestration and management include the feasibil- ity and permanence of the carbon sequestered, the scale

  18. Modeling Impacts of Management on Carbon Sequestration and Trace Gas Emissions in Forested

    E-Print Network [OSTI]

    Modeling Impacts of Management on Carbon Sequestration and Trace Gas Emissions in Forested Wetland-DNDC, was modified to enhance its capacity to predict the impacts of management practices on carbon sequestration nonnegligible roles in mitigation in comparison with carbon sequestration. Forests are recognized for having

  19. DRAFT, November 2, 1998 Carbon Sequestration via Tree Planting on Agricultural Lands

    E-Print Network [OSTI]

    McCarl, Bruce A.

    1 DRAFT, November 2, 1998 Carbon Sequestration via Tree Planting on Agricultural Lands: An Economic affect program cost and net carbon sequestration. The focus on the provisions of tree planting agreements the cost and net carbon gains under a sequestration program. We will also investigate design aspects

  20. Evaluating carbon sequestration efficiency in an ocean circulation model by adjoint sensitivity analysis

    E-Print Network [OSTI]

    Follows, Mick

    Evaluating carbon sequestration efficiency in an ocean circulation model by adjoint sensitivity the application of the adjoint method to develop three-dimensional maps of carbon sequestration efficiency. Sequestration efficiency (the percentage of carbon injected at a continuous point source that remains

  1. Global Change Biology (2000) 6, 317328 Soil Carbon Sequestration and Land-Use Change: Processes and

    E-Print Network [OSTI]

    2000-01-01

    Global Change Biology (2000) 6, 317­328 Soil Carbon Sequestration and Land-Use Change: Processes in enhanced soil carbon sequestration with changes in land-use and soil management. We review literature, and indicates the relative importance of some factors that influence the rates of organic carbon sequestration

  2. Carbon sequestration, optimum forest rotation and their environmental impact

    SciTech Connect (OSTI)

    Kula, Erhun, E-mail: erhun.kula@bahcesehir.edu.tr [Department of Economics, Bahcesehir University, Besiktas, Istanbul (Turkey); Gunalay, Yavuz, E-mail: yavuz.gunalay@bahcesehir.edu.tr [Department of Business Studies, Bahcesehir University, Besiktas, Istanbul (Turkey)

    2012-11-15

    Due to their large biomass forests assume an important role in the global carbon cycle by moderating the greenhouse effect of atmospheric pollution. The Kyoto Protocol recognises this contribution by allocating carbon credits to countries which are able to create new forest areas. Sequestrated carbon provides an environmental benefit thus must be taken into account in cost-benefit analysis of afforestation projects. Furthermore, like timber output carbon credits are now tradable assets in the carbon exchange. By using British data, this paper looks at the issue of identifying optimum felling age by considering carbon sequestration benefits simultaneously with timber yields. The results of this analysis show that the inclusion of carbon benefits prolongs the optimum cutting age by requiring trees to stand longer in order to soak up more CO{sub 2}. Consequently this finding must be considered in any carbon accounting calculations. - Highlights: Black-Right-Pointing-Pointer Carbon sequestration in forestry is an environmental benefit. Black-Right-Pointing-Pointer It moderates the problem of global warming. Black-Right-Pointing-Pointer It prolongs the gestation period in harvesting. Black-Right-Pointing-Pointer This paper uses British data in less favoured districts for growing Sitka spruce species.

  3. Carbonic Acid Shows Promise in Geology, Biology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Surprising Secrets of Carbonic Acid Probing the Surprising Secrets of Carbonic Acid Berkeley Lab Study Holds Implications for Geological and Biological Processes October 23,...

  4. A Finite-Element Model for Simulation of Carbon Dioxide Sequestration

    SciTech Connect (OSTI)

    Bao, Jie; Xu, Zhijie; Fang, Yilin

    2014-09-01

    Herein, we present a coupled thermal-hydro-mechanical model for geological sequestration of carbon dioxide followed by the stress, deformation, and shear-slip failure analysis. This fully coupled model considers the geomechanical response, fluid flow, and thermal transport relevant to geological sequestration. Both analytical solutions and numerical approach via finite element model are introduced for solving the thermal-hydro-mechanical model. Analytical solutions for pressure, temperature, deformation, and stress field were obtained for a simplified typical geological sequestration scenario. The finite element model is more general and can be used for arbitrary geometry. It was built on an open-source finite element code, Elmer, and was designed to simulate the entire period of CO2 injection (up to decades) both stably and accurately—even for large time steps. The shear-slip failure analysis was implemented based on the numerical results from the finite element model. The analysis reveals the potential failure zone caused by the fluid injection and thermal effect. From the simulation results, the thermal effect is shown to enhance well injectivity, especially at the early time of the injection. However, it also causes some side effects, such as the appearance of a small failure zone in the caprock. The coupled thermal-hydro-mechanical model improves prediction of displacement, stress distribution, and potential failure zone compared to the model that neglects non-isothermal effects, especially in an area with high geothermal gradient.

  5. Environmental Responses to Carbon Mitigation through Geological Storage

    SciTech Connect (OSTI)

    Cunningham, Alfred; Bromenshenk, Jerry

    2013-08-30

    In summary, this DOE EPSCoR project is contributing to the study of carbon mitigation through geological storage. Both deep and shallow subsurface research needs are being addressed through research directed at improved understanding of environmental responses associated with large scale injection of CO{sub 2} into geologic formations. The research plan has two interrelated research objectives. ? Objective 1: Determine the influence of CO{sub 2}-related injection of fluids on pore structure, material properties, and microbial activity in rock cores from potential geological carbon sequestration sites. ? Objective 2: Determine the Effects of CO{sub 2} leakage on shallow subsurface ecosystems (microbial and plant) using field experiments from an outdoor field testing facility.

  6. Geological Characterization of California's Offshore

    E-Print Network [OSTI]

    for the various data generated by the West Coast Regional Carbon Sequestration Partnership. The project's goals are to: · Perform a preliminary geologic characterization of the carbon dioxide sequestration of carbon sequestration potential. · For select formations previously studied in the Southern Sacramento

  7. Effects of Biochar and Basalt Additions on Carbon Sequestration and Fluxes of Greenhouse Gases in Soils

    E-Print Network [OSTI]

    Vallino, Joseph J.

    Effects of Biochar and Basalt Additions on Carbon Sequestration and Fluxes of Greenhouse Gases Emissions--Carbon Dioxide Emissions--Sequestration and Storage--Biochar--Basalt--Organic Fertilizers, this investigation focuses on the range of potential of different soil additives to enhance sequestration and storage

  8. A Feasibility Study of Non-Seismic Geophysical Methods forMonitoring Geologic CO2 Sequestration

    SciTech Connect (OSTI)

    Gasperikova, Erika; Hoversten, G. Michael

    2006-07-01

    Because of their wide application within the petroleumindustry it is natural to consider geophysical techniques for monitoringof CO2 movement within hydrocarbon reservoirs, whether the CO2 isintroduced for enhanced oil/gas recovery or for geologic sequestration.Among the available approaches to monitoring, seismic methods are by farthe most highly developed and applied. Due to cost considerations, lessexpensive techniques have recently been considered. In this article, therelative merits of gravity and electromagnetic (EM) methods as monitoringtools for geological CO2 sequestration are examined for two syntheticmodeling scenarios. The first scenario represents combined CO2 enhancedoil recovery (EOR) and sequestration in a producing oil field, theSchrader Bluff field on the north slope of Alaska, USA. The secondscenario is a simplified model of a brine formation at a depth of 1,900m.

  9. Effects of CO2 adsorption upon coal deformation during geological sequestration Kan Yang1,2

    E-Print Network [OSTI]

    Muzzio, Fernando J.

    ], which affect the coal seam structure, adsorption, and transport properties, such as density, surface1 Effects of CO2 adsorption upon coal deformation during geological sequestration Kan Yang1. Neimark: aneimark@rutgers.edu Yangzheng Lin: sealin2008@hotmail.com TITLE RUNNING HEAD: Effects of coal

  10. Geologic Sequestration The National Energy Technology Laboratory and Los Alamos National Laboratory

    E-Print Network [OSTI]

    a vast number of geologic sites all with varying site-specific properties, regional issues, and economic considerations. Selecting, engineering, and regulating these sites will require a comprehensive decision making sequestration program has been working to fill those basic scientific gaps through labo

  11. Development and Deployment of a Compact Eye-Safe Scanning Differential absorption Lidar (DIAL) for Spatial Mapping of Carbon Dioxide for Monitoring/Verification/Accounting at Geologic Sequestration Sites

    SciTech Connect (OSTI)

    Repasky, Kevin

    2014-03-31

    A scanning differential absorption lidar (DIAL) instrument for monitoring carbon dioxide has been developed. The laser transmitter uses two tunable discrete mode laser diodes (DMLD) operating in the continuous wave (cw) mode with one locked to the online absorption wavelength and the other operating at the offline wavelength. Two in-line fiber optic switches are used to switch between online and offline operation. After the fiber optic switch, an acousto- optic modulator (AOM) is used to generate a pulse train used to injection seed an erbium doped fiber amplifier (EDFA) to produce eye-safe laser pulses with maximum pulse energies of 66 {micro}J, a pulse repetition frequency of 15 kHz, and an operating wavelength of 1.571 {micro}m. The DIAL receiver uses a 28 cm diameter Schmidt-Cassegrain telescope to collect that backscattered light, which is then monitored using a photo-multiplier tube (PMT) module operating in the photon counting mode. The DIAL instrument has been operated from a laboratory environment on the campus of Montana State University, at the Zero Emission Research Technology (ZERT) field site located in the agricultural research area on the western end of the Montana State University campus, and at the Big Sky Carbon Sequestration Partnership site located in north-central Montana. DIAL data has been collected and profiles have been validated using a co-located Licor LI-820 Gas Analyzer point sensor.

  12. Probabilistic evaluation of shallow groundwater resources at a hypothetical carbon sequestration site

    SciTech Connect (OSTI)

    Dai, Zhenxue; Keating, Elizabeth; Bacon, Diana H.; Viswanathan, Hari; Stauffer, Philip; Jordan, Amy B.; Pawar, Rajesh

    2014-03-07

    Carbon sequestration in geologic reservoirs is an important approach for mitigating greenhouse gases emissions to the atmosphere. This study first develops an integrated Monte Carlo method for simulating CO2 and brine leakage from carbon sequestration and subsequent geochemical interactions in shallow aquifers. Then, we estimate probability distributions of five risk proxies related to the likelihood and volume of changes in pH, total dissolved solids, and trace concentrations of lead, arsenic, and cadmium for two possible consequence thresholds. The results indicate that shallow groundwater resources may degrade locally around leakage points by reduced pH and increased total dissolved solids (TDS). The volumes of pH and TDS plumes are most sensitive to aquifer porosity, permeability, and CO2 and brine leakage rates. The estimated plume size of pH change is the largest, while that of cadmium is the smallest among the risk proxies. Plume volume distributions of arsenic and lead are similar to those of TDS. The scientific results from this study provide substantial insight for understanding risks of deep fluids leaking into shallow aquifers, determining the area of review, and designing monitoring networks at carbon sequestration sites.

  13. Geologic Sequestration Training and Research Projects | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,Executive Compensation References:Sequestration Program | Department

  14. Carbon sequestration in depleted oil shale deposits

    SciTech Connect (OSTI)

    Burnham, Alan K; Carroll, Susan A

    2014-12-02

    A method and apparatus are described for sequestering carbon dioxide underground by mineralizing the carbon dioxide with coinjected fluids and minerals remaining from the extraction shale oil. In one embodiment, the oil shale of an illite-rich oil shale is heated to pyrolyze the shale underground, and carbon dioxide is provided to the remaining depleted oil shale while at an elevated temperature. Conditions are sufficient to mineralize the carbon dioxide.

  15. Soil organic carbon sequestration potential of cropland in China Zhangcai Qin,1,2

    E-Print Network [OSTI]

    Pittendrigh, Barry

    Soil organic carbon sequestration potential of cropland in China Zhangcai Qin,1,2 Yao Huang,1), Soil organic carbon sequestration potential of cropland in China, Global Biogeochem. Cycles, 27, doi:10 carbon (SOC) in cropland is of great importance to the global carbon (C) balance and to agricultural

  16. Interaction effects of climate and land use/land cover change on soil organic carbon sequestration

    E-Print Network [OSTI]

    Grunwald, Sabine

    Interaction effects of climate and land use/land cover change on soil organic carbon sequestration carbon sequestration Climate change Soil carbon change Historically, Florida soils stored the largest in Florida (FL) have acted as a sink for carbon (C) over the last 40 years. · Climate interacting with land

  17. Dynamics of carbon sequestration in a coastal wetland using radiocarbon measurements

    E-Print Network [OSTI]

    Dynamics of carbon sequestration in a coastal wetland using radiocarbon measurements Yonghoon Choi1. Wang (2004), Dynamics of carbon sequestration in a coastal wetland using radiocarbon measurements carbon cycle. However, the dynamics of carbon (C) cycling in coastal wetlands and its response to sea

  18. CARBON SEQUESTRATION IN ARABLE SOILS IS LIKELY TO INCREASE NITROUS OXIDE EMISSIONS, OFFSETTING

    E-Print Network [OSTI]

    CARBON SEQUESTRATION IN ARABLE SOILS IS LIKELY TO INCREASE NITROUS OXIDE EMISSIONS, OFFSETTING in strategies for climate protection. 1. Introduction Carbon sequestration has been highlighted recently concentration of carbon dioxide (CO2) in the atmo- sphere include sequestering carbon (C) in soils

  19. Reactive transport modeling of stable carbon isotope fractionation in a multi-phase multi-component system during carbon sequestration

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Shuo; DePaolo, Donald J.; Zheng, Liange; Mayer, Bernhard

    2014-12-31

    Carbon stable isotopes can be used in characterization and monitoring of CO2 sequestration sites to track the migration of the CO2 plume and identify leakage sources, and to evaluate the chemical reactions that take place in the CO2-water-rock system. However, there are few tools available to incorporate stable isotope information into flow and transport codes used for CO2 sequestration problems. We present a numerical tool for modeling the transport of stable carbon isotopes in multiphase reactive systems relevant to geologic carbon sequestration. The code is an extension of the reactive transport code TOUGHREACT. The transport module of TOUGHREACT was modifiedmore »to include separate isotopic species of CO2 gas and dissolved inorganic carbon (CO2, CO32-, HCO3-,…). Any process of transport or reaction influencing a given carbon species also influences its isotopic ratio. Isotopic fractionation is thus fully integrated within the dynamic system. The chemical module and database have been expanded to include isotopic exchange and fractionation between the carbon species in both gas and aqueous phases. The performance of the code is verified by modeling ideal systems and comparing with theoretical results. Efforts are also made to fit field data from the Pembina CO2 injection project in Canada. We show that the exchange of carbon isotopes between dissolved and gaseous carbon species combined with fluid flow and transport, produce isotopic effects that are significantly different from simple two-component mixing. These effects are important for understanding the isotopic variations observed in field demonstrations.« less

  20. Reactive transport modeling of stable carbon isotope fractionation in a multi-phase multi-component system during carbon sequestration

    SciTech Connect (OSTI)

    Zhang, Shuo [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); DePaolo, Donald J. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Zheng, Liange [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Mayer, Bernhard [Univ. of Calgary (Canada). Dept. of Geosciences

    2014-12-31

    Carbon stable isotopes can be used in characterization and monitoring of CO2 sequestration sites to track the migration of the CO2 plume and identify leakage sources, and to evaluate the chemical reactions that take place in the CO2-water-rock system. However, there are few tools available to incorporate stable isotope information into flow and transport codes used for CO2 sequestration problems. We present a numerical tool for modeling the transport of stable carbon isotopes in multiphase reactive systems relevant to geologic carbon sequestration. The code is an extension of the reactive transport code TOUGHREACT. The transport module of TOUGHREACT was modified to include separate isotopic species of CO2 gas and dissolved inorganic carbon (CO2, CO32-, HCO3-,…). Any process of transport or reaction influencing a given carbon species also influences its isotopic ratio. Isotopic fractionation is thus fully integrated within the dynamic system. The chemical module and database have been expanded to include isotopic exchange and fractionation between the carbon species in both gas and aqueous phases. The performance of the code is verified by modeling ideal systems and comparing with theoretical results. Efforts are also made to fit field data from the Pembina CO2 injection project in Canada. We show that the exchange of carbon isotopes between dissolved and gaseous carbon species combined with fluid flow and transport, produce isotopic effects that are significantly different from simple two-component mixing. These effects are important for understanding the isotopic variations observed in field demonstrations.

  1. Application of Cutting-Edge 3D Seismic Attribute Technology to the Assessment of Geological Reservoirs for CO2 Sequestration

    SciTech Connect (OSTI)

    Christopher Liner; Jianjun Zeng; Po Geng Heather King Jintan Li; Jennifer Califf; John Seales

    2010-03-31

    The goals of this project were to develop innovative 3D seismic attribute technologies and workflows to assess the structural integrity and heterogeneity of subsurface reservoirs with potential for CO{sub 2} sequestration. Our specific objectives were to apply advanced seismic attributes to aide in quantifying reservoir properies and lateral continuity of CO{sub 2} sequestration targets. Our study area is the Dickman field in Ness County, Kansas, a type locality for the geology that will be encountered for CO{sub 2} sequestration projects from northern Oklahoma across the U.S. midcontent to Indiana and beyond. Since its discovery in 1962, the Dickman Field has produced about 1.7 million barrels of oil from porous Mississippian carbonates with a small structural closure at about 4400 ft drilling depth. Project data includes 3.3 square miles of 3D seismic data, 142 wells, with log, some core, and oil/water production data available. Only two wells penetrate the deep saline aquifer. Geological and seismic data were integrated to create a geological property model and a flow simulation grid. We systematically tested over a dozen seismic attributes, finding that curvature, SPICE, and ANT were particularly useful for mapping discontinuities in the data that likely indicated fracture trends. Our simulation results in the deep saline aquifer indicate two effective ways of reducing free CO{sub 2}: (a) injecting CO{sub 2} with brine water, and (b) horizontal well injection. A tuned combination of these methods can reduce the amount of free CO{sub 2} in the aquifer from over 50% to less than 10%.

  2. NATional CARBon Sequestration Database and Geographic Information System (NATCARB)

    SciTech Connect (OSTI)

    Timothy R. Carr

    2006-01-09

    This report provides a brief summary of the milestone for Quarter 1 of 2006 of the NATional CARBon Sequestration Database and Geographic Information System (NATCARB) This milestone assigns consistent symbology to the ''National CO{sub 2} Facilities'' GIS layer on the NATCARB website. As a default, CO{sub 2} sources provided by the Regional Carbon Sequestration Partnerships and the National Group are now all one symbol type. In addition for sinks such as oil and gas fields where data is drawn from multiple partnerships, the symbology is given a single color. All these modifications are accomplished as the layer is passed through the national portal (www.natcarb.org). This documentation is sent to National Energy Technology Laboratory (NETL) as a Topical Report and will be included in the next Annual Report.

  3. Energy Department Awards $66.7 Million for Large-Scale Carbon...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    recent awards through the Department of Energy's (DOE) Regional Carbon Sequestration Partnership Program, DOE today awarded 66.7 million to the Midwest Geological Sequestration...

  4. Southwestern Regional Partnership For Carbon Sequestration (Phase 2) Pump Canyon CO2- ECBM/Sequestration Demonstration, San Juan Basin, New Mexico

    SciTech Connect (OSTI)

    Advanced Resources International

    2010-01-31

    Within the Southwest Regional Partnership on Carbon Sequestration (SWP), three demonstrations of geologic CO{sub 2} sequestration are being performed -- one in an oilfield (the SACROC Unit in the Permian basin of west Texas), one in a deep, unmineable coalbed (the Pump Canyon site in the San Juan basin of northern New Mexico), and one in a deep, saline reservoir (underlying the Aneth oilfield in the Paradox basin of southeast Utah). The Pump Canyon CO{sub 2}-enhanced coalbed methane (CO{sub 2}/ECBM) sequestration demonstration project plans to demonstrate the effectiveness of CO{sub 2} sequestration in deep, unmineable coal seams via a small-scale geologic sequestration project. The site is located in San Juan County, northern New Mexico, just within the limits of the high-permeability fairway of prolific coalbed methane production. The study area for the SWP project consists of 31 coalbed methane production wells located in a nine section area. CO{sub 2} was injected continuously for a year and different monitoring, verification and accounting (MVA) techniques were implemented to track the CO{sub 2} movement inside and outside the reservoir. Some of the MVA methods include continuous measurement of injection volumes, pressures and temperatures within the injection well, coalbed methane production rates, pressures and gas compositions collected at the offset production wells, and tracers in the injected CO{sub 2}. In addition, time-lapse vertical seismic profiling (VSP), surface tiltmeter arrays, a series of shallow monitoring wells with a regular fluid sampling program, surface measurements of soil composition, CO{sub 2} fluxes, and tracers were used to help in tracking the injected CO{sub 2}. Finally, a detailed reservoir model was constructed to help reproduce and understand the behavior of the reservoir under production and injection operation. This report summarizes the different phases of the project, from permitting through site closure, and gives the results of the different MVA techniques.

  5. Offshore Extension of Deccan Traps in Kachchh, Central Western India: Implications for Geological Sequestration Studies

    SciTech Connect (OSTI)

    Pandey, D. K.; Pandey, A.; Rajan, S.

    2011-03-15

    The Deccan basalts in central western India are believed to occupy large onshore-offshore area. Using geophysical and geological observations, onshore sub-surface structural information has been widely reported. On the contrary, information about offshore structural variations has been inadequate due to scarcity of marine geophysical data and lack of onshore-offshore lithological correlations. Till date, merely a few geophysical studies are reported that gauge about the offshore extent of Deccan Traps and the Mesozoic sediments (pre-Deccan). To fill this gap in knowledge, in this article, we present new geophysical evidences to demonstrate offshore continuation of the Deccan volcanics and the Mesozoic sediments. The offshore multi-channel seismic and onshore-offshore lithological correlations presented here confirm that the Mesozoic sedimentary column in this region is overlain by 0.2-1.2-km-thick basaltic cover. Two separate phases of Mesozoic sedimentation, having very distinctive physical and lithological characteristics, are observed between overlying basaltic rocks and underlying Precambrian basement. Using onshore-offshore seismic and borehole data this study provides new insight into the extent of the Deccan basalts and the sub-basalt structures. This study brings out a much clearer picture than that was hitherto available about the offshore continuation of the Deccan Traps and the Mesozoic sediments of Kachchh. Further, its implications in identifying long-term storage of anthropogenic CO{sub 2} within sub-basalt targets are discussed. The carbon sequestration potential has been explored through the geological assessment in terms of the thickness of the strata as well as lithology.

  6. Optimize carbon dioxide sequestration, enhance oil recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CO2-EOR provides about 5 percent of the total U.S. current crude oil production. Due to carbon capture and storage technology advances, prolonged high oil prices and the...

  7. CARBON SEQUESTRATION ON SURFACE MINE LANDS

    SciTech Connect (OSTI)

    Donald H. Graves; Christopher Barton; Richard Sweigard; Richard Warner

    2004-11-30

    A monitoring program to measure treatment effects on above ground, and below ground carbon and nitrogen pools for the planting areas is being conducted. The collection of soil and tissue samples from both the 2003 and 2004 plantings is complete and are currently being processed in the laboratory. Detailed studies have been initiated to address specific questions pertaining to carbon cycling. Examinations of decomposition and heterotropic respiration on carbon cycling in the reforestation plots were continued during this reporting period. A whole-tree harvesting method was employed to evaluate carbon accumulation as a function of time on the mined site. The trees were extracted from the sites and separated into the following components: foliage, stems, branches, and roots.

  8. The Physical and Chemical Mechanisms Responsible for Carbon Sequestration in Soil Microaggregates

    E-Print Network [OSTI]

    McCarthy, John F.

    The Physical and Chemical Mechanisms Responsible for Carbon Sequestration in Soil Microaggregates aggregate formation and stability have profound implications to understanding and enhancing C sequestration in soil. Soil microaggregates are particularly crucial to long-term sequestration because they protect C

  9. A General Methodology for Evaluation of Carbon Sequestration Activities and Carbon Credits

    SciTech Connect (OSTI)

    Klasson, KT

    2002-12-23

    A general methodology was developed for evaluation of carbon sequestration technologies. In this document, we provide a method that is quantitative, but is structured to give qualitative comparisons despite changes in detailed method parameters, i.e., it does not matter what ''grade'' a sequestration technology gets but a ''better'' technology should receive a better grade. To meet these objectives, we developed and elaborate on the following concepts: (1) All resources used in a sequestration activity should be reviewed by estimating the amount of greenhouse gas emissions for which they historically are responsible. We have done this by introducing a quantifier we term Full-Cycle Carbon Emissions, which is tied to the resource. (2) The future fate of sequestered carbon should be included in technology evaluations. We have addressed this by introducing a variable called Time-adjusted Value of Carbon Sequestration to weigh potential future releases of carbon, escaping the sequestered form. (3) The Figure of Merit of a sequestration technology should address the entire life-cycle of an activity. The figures of merit we have developed relate the investment made (carbon release during the construction phase) to the life-time sequestration capacity of the activity. To account for carbon flows that occur during different times of an activity we incorporate the Time Value of Carbon Flows. The methodology we have developed can be expanded to include financial, social, and long-term environmental aspects of a sequestration technology implementation. It does not rely on global atmospheric modeling efforts but is consistent with these efforts and could be combined with them.

  10. Global Change Biology (1996)2,169-182 Measurements of carbon sequestration by long-term

    E-Print Network [OSTI]

    Rose, Michael R.

    1996-01-01

    Global Change Biology (1996)2,169-182 Measurements of carbon sequestration by long-term eddy. The integrated carbon sequestration in 1994 was 2.1 t C ha-l y-l with a 90% confidence interval due to sampling an overall uncertainty on the annual carbon sequestration in 1994 of --0.3to +0.8 t C ha-l y-l. Keywords

  11. Southeast Regional Carbon Sequestration Partnership (SECARB)

    SciTech Connect (OSTI)

    Kathryn A. Baskin

    2004-03-31

    Work during the first six months of the project mainly concentrated on contracts execution and collection of data to characterize the region and input of that data into the geographical information system (GIS) system. Data was collected for source characterization, transportation options and terrestrial options. In addition, discussions were held to determine the extent of the geologic information that would be needed for the project. In addition, activities associated with the regulatory, permitting and safety issues were completed. Outreach activities are in the formative stages.

  12. Semi-analytical Solution for Multiphase Fluid Flow Applied to CO2 Sequestration in Geologic Porous Media 

    E-Print Network [OSTI]

    Mohamed, Ahmed Mohamed Anwar Sayed

    2013-08-01

    The increasing concentration of CO_(2) has been linked to global warming and changes in climate. Geologic sequestration of CO_(2) in deep saline aquifers is a proposed greenhouse gas mitigation technology with potential to significantly reduce...

  13. ANALYSIS OF ENHANCED COALBED METHANE RECOVERY THROUGH CARBON SEQUESTRATION IN THE CENTRAL

    E-Print Network [OSTI]

    potential of coalbed methane production using carbon dioxide sequestration in the Central Appalachian BasinANALYSIS OF ENHANCED COALBED METHANE RECOVERY THROUGH CARBON SEQUESTRATION IN THE CENTRAL dioxide emissions from power plants, while enhancing the recovery of coalbed methane. Injected carbon

  14. Issues with the Use of Fly Ash for Carbon Sequestration A.V. Palumbo1*

    E-Print Network [OSTI]

    Tiquia-Arashiro, Sonia M.

    Issues with the Use of Fly Ash for Carbon Sequestration A.V. Palumbo1* , L. S. Fisher1 , J experiments, fly ash and biosolid amendments can increase soil carbon. Although it appears that geochemistry and its influence on carbon sequestration. Also, addition of fly ash to soil, while generally considered

  15. Carbon sequestration in peatland: patterns and mechanisms of response to climate change

    E-Print Network [OSTI]

    Carbon sequestration in peatland: patterns and mechanisms of response to climate change L I S A R., 2000; Turunen et al., 2002; Kremenetski et al., 2003). Rates of carbon (C) sequestration (i.e., uptake in the climatic water budget is crucial to predicting potential feedbacks on the global carbon (C) cycle. To gain

  16. Oxygen production and carbon sequestration in an upwelling coastal Burke Hales,1

    E-Print Network [OSTI]

    Oxygen production and carbon sequestration in an upwelling coastal margin Burke Hales,1 Lee Karp), Oxygen production and carbon sequestration in an upwelling coastal margin, Global Biogeochem. Cycles, 20 of particulate organic carbon (POC) and dissolved O2 during the upwelling season off the Oregon coast. Oxygen

  17. REGULATION OF CARBON SEQUESTRATION AND WATER USE IN A OZARK FOREST...

    Office of Scientific and Technical Information (OSTI)

    REGULATION OF CARBON SEQUESTRATION AND WATER USE IN A OZARK FOREST: PROPOSING A NEW STRATEGICALLY LOCATED AMERIFLUX TOWER SITE IN MISSOURI Pallardy, Stephen G 59 BASIC BIOLOGICAL...

  18. Summary Report on CO2 Geologic Sequestration & Water Resources Workshop

    E-Print Network [OSTI]

    Varadharajan, C.

    2013-01-01

    and performance of oil well cement with 30 years of CO 2cement –? Carbonation –? Sulfate attack –? Acid attack State of Alaska Oil and Gas Division Old Wells

  19. Geological Carbon Storage: The Roles of Government

    E-Print Network [OSTI]

    Geological Carbon Storage: The Roles of Government and Industry in Risk Management ROSE MURPHY version of this publication, please send an email to Mark Jaccard (jaccard@sfu.ca). #12;8 Geological to a location suitable for long-term storage. CO2 can be stored in onshore or offshore geological formations

  20. Assessing the impact of changes in climate and CO2 on potential carbon sequestration in agricultural soils

    E-Print Network [OSTI]

    Assessing the impact of changes in climate and CO2 on potential carbon sequestration the influence of climate and CO2 feedbacks on soil carbon sequestration using a terrestrial carbon cycle model sequestration of 42 Tg. This is 5% of the soil carbon estimated to be potentially sequestered as the result

  1. Carbon Sequestration in Turfgrass: An Eco-Friendly Benefit of Your Lawn Dale Bremer, Kansas State University

    E-Print Network [OSTI]

    1 Carbon Sequestration in Turfgrass: An Eco-Friendly Benefit of Your Lawn Dale Bremer, Kansas State read this have no doubt heard of carbon sequestration and may even be well versed on the topic. Others't the slightest clue about carbon sequestration and others may not even care. After all, what does carbon

  2. R E V I E W Liana Impacts on Carbon Cycling, Storage and Sequestration in Tropical Forests

    E-Print Network [OSTI]

    Schnitzer, Stefan

    R E V I E W Liana Impacts on Carbon Cycling, Storage and Sequestration in Tropical Forests Geertje for carbon storage and sequestration. Lianas reduce tree growth, survival, and leaf productivity; however liana carbon stocks are unlikely to compensate for liana-induced losses in net carbon sequestration

  3. Reducing risk in basin scale sequestration: A Bayesian model selection framework for improving detection

    E-Print Network [OSTI]

    Seto, C.J.

    Geological CO[subscript 2] sequestration is a key technology for mitigating atmospheric greenhouse gas concentrations while providing low carbon energy. Deployment of sequestration at scales necessary for a material ...

  4. CARBON SEQUESTRATION ON SURFACE MINE LANDS

    SciTech Connect (OSTI)

    Donald H. Graves; Christopher Barton; Richard Sweigard; Richard Warner

    2005-02-25

    The October-December Quarter was dedicated to analyzing the first two years tree planting activities and evaluation of the results. This included the analyses of the species success at each of the sites and quantifying the data for future year determination of research levels. Additional detailed studies have been planned to further quantify total carbon storage accumulation on the research areas. At least 124 acres of new plantings will be established in 2005 to bring the total to 500 acres or more in the study area across the state of Kentucky. During the first 2 years of activities, 172,000 tree seedlings were planted on 257 acres in eastern Kentucky and 77,520 seedlings were planted on 119 acres in western Kentucky. The quantities of each species was discussed in the first Annual Report. A monitoring program was implemented to measure treatment effects on above and below ground C and nitrogen (N) pools and fluxes. A sampling strategy was devised that will allow for statistical comparisons of the various species within planting conditions and sites. Seedling heights and diameters are measured for initial status and re-measured on an annual basis. Leaves were harvested and leaf area measurements were performed. They were then dried and weighed and analyzed for C and N. Whole trees were removed to determine biomass levels and to evaluate C and N levels in all components of the trees. Clip plots were taken to determine herbaceous production and litter was collected in baskets and gathered each month to quantify C & N levels. Soil samples were collected to determine the chemical and mineralogical characterization of each area. The physical attributes of the soils are also being determined to provide information on the relative level of compaction. Hydrology and water quality monitoring is being conducted on all areas. Weather data is also being recorded that measures precipitation values, temperature, relative humidity wind speed and direction and solar radiation. Detailed studies to address specific questions pertaining to carbon flux are continuing.

  5. Big Sky Carbon Sequestration Partnership | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin: EnergyYorkColoradoBelcherCarbon Sequestration Partnership Jump

  6. Valuation of carbon capture and sequestration under Greenhouse gas regulations: CCS as an offsetting activity

    SciTech Connect (OSTI)

    Lokey, Elizabeth

    2009-08-15

    When carbon capture and sequestration is conducted by entities that are not regulated, it could be counted as an offset that is fungible in the market or sold to a voluntary market. This paper addresses the complications that arise in accounting for carbon capture and sequestration as an offset, and methodologies that exist for accounting for CCS in voluntary and compliance markets. (author)

  7. Post-Soviet farmland abandonment, forest recovery, and carbon sequestration in western Ukraine

    E-Print Network [OSTI]

    Keeton, William S.

    Post-Soviet farmland abandonment, forest recovery, and carbon sequestration in western Ukraine T O of Forest Management, Ukrainian National Forestry University, vul. Gen. Chuprynky, 103, 79031 Lviv, Ukraine fluxes in western Ukraine (57 000 km2 ) and to assess the region's future carbon sequestration potential

  8. Pre-site Characterization Risk Analysis for Commercial-Scale Carbon Sequestration

    E-Print Network [OSTI]

    Lu, Zhiming

    Pre-site Characterization Risk Analysis for Commercial-Scale Carbon Sequestration Zhenxue Dai, funders and regulators require a preinjection risk analysis that identifies potential problem areas a probability framework to evaluate subsurface risks associated with commercial-scale carbon sequestration

  9. Carbon sequestration and biodiversity of re-growing miombo woodlands in Mozambique

    E-Print Network [OSTI]

    Carbon sequestration and biodiversity of re-growing miombo woodlands in Mozambique M. Williams a in tropical woodlands is being used to sequester carbon (C), alleviate poverty and protect biodiversity, among there is a potential for C sequestration in soils on abandoned farmland. Management should focus on identifying C

  10. Development of a 1 x N Fiber Optic Sensor Array for Carbon Sequestration Site Monitoring

    SciTech Connect (OSTI)

    Repasky, Kevin

    2013-09-30

    A fiber sensor array for sub-surface CO{sub 2} concentrations measurements was developed for monitoring geologic carbon sequestration sites. The fiber sensor array uses a single temperature tunable distributed feedback (DFB) laser operating with a nominal wavelength of 2.004 􀁐m. Light from this DFB laser is direct to one of the 4 probes via an in-line 1 x 4 fiber optic switch. Each of the 4 probes are buried and allow the sub-surface CO{sub 2} to enter the probe through Millipore filters that allow the soil gas to enter the probe but keeps out the soil and water. Light from the DFB laser interacts with the CO{sub 2} before it is directed back through the in-line fiber optic switch. The DFB laser is tuned across two CO{sub 2} absorption features where a transmission measurement is made allowing the CO{sub 2} concentration to be retrieved. The fiber optic switch then directs the light to the next probe where this process is repeated allowing sub-surface CO{sub 2} concentration measurements at each of the probes to be made as a function of time. The fiber sensor array was deployed for fifty-eight days beginning June 19, 2012 at the Zero Emission Research Technology (ZERT) field site where sub-surface CO{sub 2} concentrations were monitored. Background measurements indicate the fiber sensor array can monitor background levels as low as 1,000 parts per million (ppm). A thirty four day sub-surface release of 0.15 tones CO{sub 2}/day began on July 10, 2012. The elevated subsurface CO{sub 2} concentration was easily detected by each of the four probes with values ranging to over 60,000 ppm, a factor of greater than 6 higher than background measurements. The fiber sensor array was also deploy at the Big Sky Carbon Sequestration Partnership (BSCSP) site in north-central Montana between July 9th and August 7th, 2013 where background measurements were made in a remote sequestration site with minimal infrastructure. The project provided opportunities for two graduate students to participate in research directly related to geologic carbon sequestration. Furthermore, commercialization of the technology developed is being pursued with five different companies via the Department of energy SBIR/STTR program

  11. GEOC: Division of Geochemistry 208 -Copper sequestration by black carbon in

    E-Print Network [OSTI]

    Sparks, Donald L.

    GEOC: Division of Geochemistry 208 - Copper sequestration by black carbon in contaminated soil the quality of agricultural products and underground water and impacts the stability of soil organic carbon

  12. What can ecological science tell us about opportunities for carbon sequestration on arid rangelands in the United States?

    E-Print Network [OSTI]

    Sayre, Nathan

    What can ecological science tell us about opportunities for carbon sequestration on arid rangelands). It is now commonplace to use the rationale of increasing carbon sequestration to argue for changes interest in carbon sequestration on rangelands is largely driven by their extent, while the interest

  13. Book (All chapters are peer-reviewed) Kumar, B. M. and Nair, P. K. R. (eds). Carbon Sequestration in Agroforestry

    E-Print Network [OSTI]

    Hill, Jeffrey E.

    Book (All chapters are peer-reviewed) Kumar, B. M. and Nair, P. K. R. (eds). Carbon Sequestration. K. R., Nair, V. D., Kumar, B. M., and Showalter, J. M. 2010. Carbon sequestration in agroforestry Publications on Carbon Sequestration in Agroforestry Systems 2008 ­ 2011 (Contact: pknair@ufl.edu) #12;cacao

  14. Interaction of ice storms and management practices on current carbon sequestration in forests with potential mitigation under future CO2

    E-Print Network [OSTI]

    Oren, Ram

    Interaction of ice storms and management practices on current carbon sequestration in forests with potential impacts on carbon sequestration. Common forest management practices, such as fertilization on current carbon sequestration in forests with potential mitigation under future CO2 atmosphere, J. Geophys

  15. Carbon sequestration is accelerated by the presence of seagrass in coastal habitats as the vegetation promotes the accumulation of carbon-rich sediment. Typically,

    E-Print Network [OSTI]

    Lawrence, Deborah

    #12;ii Abstract Carbon sequestration is accelerated by the presence of seagrass in coastal habitats as the vegetation promotes the accumulation of carbon-rich sediment. Typically, measurements of carbon sequestration is to quantify the carbon sequestration potential of the restored seagrass habitat at the Virginia Coast Reserve

  16. U.S. Department of the Interior U.S. Geological Survey

    E-Print Network [OSTI]

    of U.S. Forest and Soil Organic Carbon Storage and Forest Biomass Carbon Sequestration Capacity #12 and Soil Organic Carbon Storage and Forest Biomass Carbon Sequestration Capacity By Eric T. Sundquist,1 carbon sequestration capacity: U.S. Geological Survey Open-File Report 2009­1283, 15 p., available

  17. Western Economics Forum, Fall 2009 Can Carbon Find a Home on the Range?

    E-Print Network [OSTI]

    Norton, Jay B.

    for agricultural lands to provide ecosystem services related to carbon sequestration. Many geologic sequestration suggests that total carbon sequestration on these lands can impact carbon cycles. The Chicago Climate evaluate the potential effectiveness of alternative carbon sequestration policies on rangelands ex ante

  18. What is the Potential for Carbon Sequestration by the Terrestrial Biosphere?

    SciTech Connect (OSTI)

    Dahlman, R. C.; Jacobs, Gary K.; Breshears, David; Metting, F. Blaine

    2002-12-31

    This paper is a summary discussion of technical information about carbon sequestration (CS) in terrestrial ecosystems that was presented in various Sessions of the First National Conference on Carbon Sequestration, Washington D.C., May 14-17, 2001. The Earth's mantle of vegetation naturally removes CO2 from the atmosphere, and some of this carbon then becomes sequestered in biomass products and soil. As discussed at this National Conference on Carbon Sequestration, mechanisms of terrestrial biosphere carbon sequestration (TBCS) represent important options for sequestration of excess CO2 from combustion of fossil fuels. A number of studies suggest that the potential quantity of TBCS may be significant, and that economic aspects appear attractive; therefore we conclude the following points: ? Quantity of annual carbon sequestration by terrestrial ecosystems can be measured at a reasonable accuracy; ? Median measure of current NEP or sequestration by forested ecosystems is 3 metric tons per hectare per year; ? Current calculated global TBCS for forests is ~3Gt C per yr; ? Estimated future TBCS capacity is 200-250 Gt C using available knowledge and current technology and management practice at nominal estimated cost of $10-20 per metric ton of C; ? It seems reasonable to assume that advanced science, technology, and management can double the capacity at low additional costs. ? TBCS option offers potential for sequestering more than 50 percent of projected excess CO2 that will have to be managed over the next century.

  19. WEST COAST REGIONAL CARBON SEQUESTRATION PARTNERSHIP - REPORT ON GEOPHYSICAL TECHNIQUES FOR MONITORING CO2 MOVEMENT DURING SEQUESTRATION

    SciTech Connect (OSTI)

    Gasperikova, Erika; Gasperikova, Erika; Hoversten, G. Michael

    2005-10-01

    The relative merits of the seismic, gravity, and electromagnetic (EM) geophysical techniques are examined as monitoring tools for geologic sequestration of CO{sub 2}. This work does not represent an exhaustive study, but rather demonstrates the capabilities of a number of geophysical techniques on two synthetic modeling scenarios. The first scenario represents combined CO{sub 2} enhance oil recovery (EOR) and sequestration in a producing oil field, the Schrader Bluff field on the north slope of Alaska, USA. EOR/sequestration projects in general and Schrader Bluff in particular represent relatively thin injection intervals with multiple fluid components (oil, hydrocarbon gas, brine, and CO{sub 2}). This model represents the most difficult end member of a complex spectrum of possible sequestration scenarios. The time-lapse performance of seismic, gravity, and EM techniques are considered for the Schrader Bluff model. The second scenario is a gas field that in general resembles conditions of Rio Vista reservoir in the Sacramento Basin of California. Surface gravity, and seismic measurements are considered for this model.

  20. Back to Exploration 2008 CSPG CSEG CWLS Convention 1 A Computational Model of Catalyzed Carbon Sequestration

    E-Print Network [OSTI]

    Spiteri, Raymond J.

    techniques. In capture-and-storage methods, atmospheric carbon, usually carbon dioxide, is captured, often to help find the most cost effective methods possible. Most carbon sequestration methods are capture-and-storage. Introduction Growing international concern over the role of greenhouse gases (mainly carbon dioxide and methane

  1. Atmosphere-crust coupling and carbon sequestration on the young Mars Professor Martin R. Lee1

    E-Print Network [OSTI]

    Guo, Zaoyang

    Atmosphere-crust coupling and carbon sequestration on the young Mars Professor Martin R. Lee1 *, Dr the idea that CO2 was `scrubbed' by precipitation of carbonate minerals within the planet's crust - a reaction termed `carbonation'. This project will seek evidence for carbonation by analysis of martian

  2. Ocean Sciences 2006 An Estimate of Carbon Sequestration via Antarctic Intermediate Water Formation in the

    E-Print Network [OSTI]

    Talley, Lynne D.

    Ocean Sciences 2006 An Estimate of Carbon Sequestration via Antarctic Intermediate Water Formation traditional deep water formation via entrainment of carbon dioxide and other greenhouse-active species collected for oxygen, total carbon, alkalinity, nutrients, and CFCs. The alkalinity and total carbon data

  3. Advances in Geological CO{sub 2} Sequestration and Co-Sequestration with O{sub 2}

    SciTech Connect (OSTI)

    Verba, Circe A; O'Connor, William K.; Ideker, J.H.

    2012-10-28

    The injection of CO{sub 2} for Enhanced Oil Recovery (EOR) and sequestration in brine-bearing formations for long term storage has been in practice or under investigation in many locations globally. This study focused on the assessment of cement wellbore seal integrity in CO{sub 2}- and CO{sub 2}-O{sub 2}-saturated brine and supercritical CO{sub 2} environments. Brine chemistries (NaCl, MgCl{sub 2}, CaCl{sub 2}) at various saline concentrations were investigated at a pressure of 28.9 MPa (4200 psi) at both 50{degree}C and 85{degree}C. These parameters were selected to simulate downhole conditions at several potential CO{sub 2} injection sites in the United States. Class H portland cement is not thermodynamically stable under these conditions and the formation of carbonic acid degrades the cement. Dissociation occurs and leaches cations, forming a CaCO{sub 3} buffered zone, amorphous silica, and other secondary minerals. Increased temperature affected the structure of C-S-H and the hydration of the cement leading to higher degradation rates.

  4. National Carbon Sequestration Database and Geographic Information System (NatCarb)

    SciTech Connect (OSTI)

    Kenneth Nelson; Timothy Carr

    2009-03-31

    This annual and final report describes the results of the multi-year project entitled 'NATional CARBon Sequestration Database and Geographic Information System (NatCarb)' (http://www.natcarb.org). The original project assembled a consortium of five states (Indiana, Illinois, Kansas, Kentucky and Ohio) in the midcontinent of the United States (MIDCARB) to construct an online distributed Relational Database Management System (RDBMS) and Geographic Information System (GIS) covering aspects of carbon dioxide (CO{sub 2}) geologic sequestration. The NatCarb system built on the technology developed in the initial MIDCARB effort. The NatCarb project linked the GIS information of the Regional Carbon Sequestration Partnerships (RCSPs) into a coordinated regional database system consisting of datasets useful to industry, regulators and the public. The project includes access to national databases and GIS layers maintained by the NatCarb group (e.g., brine geochemistry) and publicly accessible servers (e.g., USGS, and Geography Network) into a single system where data are maintained and enhanced at the local level, but are accessed and assembled through a single Web portal to facilitate query, assembly, analysis and display. This project improves the flow of data across servers and increases the amount and quality of available digital data. The purpose of NatCarb is to provide a national view of the carbon capture and storage potential in the U.S. and Canada. The digital spatial database allows users to estimate the amount of CO{sub 2} emitted by sources (such as power plants, refineries and other fossil-fuel-consuming industries) in relation to geologic formations that can provide safe, secure storage sites over long periods of time. The NatCarb project worked to provide all stakeholders with improved online tools for the display and analysis of CO{sub 2} carbon capture and storage data through a single website portal (http://www.natcarb.org/). While the external project is ending, NatCarb will continue as an internal US Department of Energy National Energy Technology Laboratory (NETL) project with the continued cooperation of personnel at both West Virginia University and the Kansas Geological Survey. The successor project will continue to organize and enhance the information about CO{sub 2} sources and developing the technology needed to access, query, analyze, display, and distribute natural resource data critical to carbon management. Data are generated, maintained and enhanced locally at the RCSP level, or at the national level in specialized data warehouses, and assembled, accessed, and analyzed in real-time through a single geoportal. To address the broader needs of a spectrum of users form high-end technical queries to the general public, NatCarb will be moving to an improved and simplified display for the general public using readily available web tools such as Google Earth{trademark} and Google Maps{trademark}. The goal is for NatCarb to expand in terms of technology and areal coverage and remain the premier functional demonstration of distributed data-management systems that cross the boundaries between institutions and geographic areas, and forms the foundation of a functioning carbon cyber-infrastructure. NatCarb provides access to first-order information to evaluate the costs, economic potential and societal issues of CO{sub 2} capture and storage, including public perception and regulatory aspects.

  5. Evaluation of the environmental viability of direct injection schemes for ocean carbon sequestration

    E-Print Network [OSTI]

    Israelsson, Peter H. (Peter Hampus), 1973-

    2008-01-01

    This thesis evaluates the expected impact of several promising schemes for ocean carbon sequestration by direct injection of CO2, and serves as an update to the assessment by Auerbach et al. (1997) and Caulfield et al. ...

  6. Understanding Carbon Sequestration Options in the United States: Capabilities of a Carbon Management Geographic Information System

    SciTech Connect (OSTI)

    Dahowski, Robert T.; Dooley, James J.; Brown, Daryl R.; Mizoguchi, Akiyoshi; Shiozaki, Mai

    2001-04-03

    While one can discuss various sequestration options at a national or global level, the actual carbon management approach is highly site specific. In response to the need for a better understanding of carbon management options, Battelle in collaboration with Mitsubishi Corporation, has developed a state-of-the-art Geographic Information System (GIS) focused on carbon capture and sequestration opportunities in the United States. The GIS system contains information (e.g., fuel type, location, vintage, ownership, rated capacity) on all fossil-fired generation capacity in the Untied States with a rated capacity of at least 100 MW. There are also data on other CO2 sources (i.e., natural domes, gas processing plants, etc.) and associated pipelines currently serving enhanced oil recovery (EOR) projects. Data on current and prospective CO2 EOR projects include location, operator, reservoir and oil characteristics, production, and CO2 source. The system also contains information on priority deep saline aquifers and coal bed methane basins with potential for sequestering CO2. The GIS application not only enables data storage, flexible map making, and visualization capabilities, but also facilitates the spatial analyses required to solve complex linking of CO2 sources with appropriate and cost-effective sinks. A variety of screening criteria (spatial, geophysical, and economic) can be employed to identify sources and sinks most likely amenable to deployment of carbon capture and sequestration systems. The system is easily updateable, allowing it to stay on the leading edge of capture and sequestration technology as well as the ever-changing business landscape. Our paper and presentation will describe the development of this GIS and demonstrate its uses for carbon management analysis.

  7. PUBLISHED ONLINE: 21 NOVEMBER 2010 | DOI: 10.1038/NGEO1014 Rapid carbon sequestration at the termination of

    E-Print Network [OSTI]

    LETTERS PUBLISHED ONLINE: 21 NOVEMBER 2010 | DOI: 10.1038/NGEO1014 Rapid carbon sequestration sequestration of organic carbon could reflect the regrowth of carbon stocks in the biosphere or shallow ago, has been attributed to the release of thousands of petagrams of reduced carbon into the ocean

  8. An Index-Based Approach to Assessing Recalcitrance and Soil Carbon Sequestration Potential of Engineered Black Carbons (Biochars)

    SciTech Connect (OSTI)

    Harvey, Omar R.; Kuo, Li-Jung; Zimmerman, Andrew R.; Louchouarn, Patrick; Amonette, James E.; Herbert, Bruce

    2012-01-10

    The ability of engineered black carbons (or biochars) to resist abiotic and, or biotic degradation (herein referred to as recalcitrance) is crucial to their successful deployment as a soil carbon sequestration strategy. A new recalcitrance index, the R{sub 50}, for assessing biochar quality for carbon sequestration is proposed. The R{sub 50} is based on the relative thermal stability of a given biochar to that of graphite and was developed and evaluated with a variety of biochars (n = 59), and soot-like black carbons. Comparison of R{sub 50}, with biochar physicochemical properties and biochar-C mineralization revealed the existence of a quantifiable relationship between R{sub 50} and biochar recalcitrance. As presented here, the R{sub 50} is immediately applicable to pre-land application screening of biochars into Class A (R{sub 50} {>=} 0.70), Class B (0.50 {<=} R{sub 50} < 0.70) or Class C (R{sub 50} < 0.50) recalcitrance/carbon sequestration classes. Class A and Class C biochars would have carbon sequestration potential comparable to soot/graphite and uncharred plant biomass, respectively, while Class B biochars would have intermediate carbon sequestration potential. We believe that the coupling of the R{sub 50}, to an index-based degradation, and an economic model could provide a suitable framework in which to comprehensively assess soil carbon sequestration in biochars.

  9. In Situ Spectrophotometric Determination of pH under Geologic CO2 Sequestration Conditions: Method Development and Application

    SciTech Connect (OSTI)

    Shao, Hongbo; Thompson, Christopher J.; Qafoku, Odeta; Cantrell, Kirk J.

    2013-02-25

    Injecting massive amounts of CO2 into deep geologic formations will cause a range of coupled thermal, hydrodynamic, mechanical, and chemical changes. A significant perturbation in water-saturated formations is the pH drop in the reservoir fluids due to CO2 dissolution. Knowing the pH under geological CO2 sequestration conditions is important for a better understanding of the short- and long-term risks associated with geological CO2 sequestration and will help in the design of sustainable sequestration projects. Most previous studies on CO2-rock-brine interactions have utilized thermodynamic modeling to estimate the pH. In this work, a spectrophotometric method was developed to determine the in-situ pH in CO2-H2O-NaCl systems in the presence and absence of reservoir rock by observing the spectra of a pH indicator, bromophenol blue, with a UV-visible spectrophotometer. Effects of temperature, pressure, and ionic strength on the pH measurement were evaluated. Measured pH values in CO2-H2O-NaCl systems were compared with several thermodynamic models. Results indicate that bromophenol blue can be used to accurately determine the pH of brine in contact with supercritical CO2 under geologic CO2 sequestration conditions.

  10. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2004-01-01

    CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. For the Devonian shale, average total organic carbon is 3.71 (as received) and mean random vitrinite reflectance is 1.16. Measured adsorption isotherm data range from 37.5 to 2,077.6 standard cubic feet of CO{sub 2} per ton (scf/ton) of shale. At 500 psia, adsorption capacity of the Lower Huron Member of the shale is 72 scf/ton. Initial estimates indicate a sequestration capacity of 5.3 billion tons CO{sub 2} in the Lower Huron Member of the Ohio shale in parts of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker portions of the Devonian shales in Kentucky. The black shales of Kentucky could be a viable geologic sink for CO{sub 2}, and their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

  11. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2004-04-01

    CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. For the Devonian shale, average total organic carbon is 3.71 percent (as received) and mean random vitrinite reflectance is 1.16. Measured adsorption isotherm data range from 37.5 to 2,077.6 standard cubic feet of CO{sub 2} per ton (scf/ton) of shale. At 500 psia, adsorption capacity of the Lower Huron Member of the shale is 72 scf/ton. Initial estimates indicate a sequestration capacity of 5.3 billion tons CO{sub 2} in the Lower Huron Member of the Ohio shale in parts of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker portions of the Devonian shales in Kentucky. The black shales of Kentucky could be a viable geologic sink for CO{sub 2}, and their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

  12. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2003-10-29

    CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. For the Devonian shale, average total organic carbon is 3.71 (as received) and mean random vitrinite reflectance is 1.16. Measured adsorption isotherm data range from 37.5 to 2,077.6 standard cubic feet of CO{sub 2} per ton (scf/ton) of shale. At 500 psia, adsorption capacity of the Lower Huron Member of the shale is 72 scf/ton. Initial estimates indicate a sequestration capacity of 5.3 billion tons CO{sub 2} in the Lower Huron Member of the Ohio shale in parts of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker portions of the Devonian shales in Kentucky. The black shales of Kentucky could be a viable geologic sink for CO{sub 2}, and their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

  13. Mechanisms for mechanical trapping of geologically sequestered carbon dioxide

    E-Print Network [OSTI]

    Cohen, Yossi

    Carbon dioxide (CO[subscript 2]) sequestration in subsurface reservoirs is important for limiting atmospheric CO[subscript 2] concentrations. However, a complete physical picture able to predict the structure developing ...

  14. Pore scale modeling of reactive transport involved in geologic CO2 sequestration

    SciTech Connect (OSTI)

    Kang, Qinjin [Los Alamos National Laboratory; Lichtner, Peter C [Los Alamos National Laboratory; Viswanathan, Hari S [Los Alamos National Laboratory; Abdel-fattah, Amr I [Los Alamos National Laboratory

    2009-01-01

    We apply a multi-component reactive transport lattice Boltzmann model developed in previolls studies to modeling the injection of a C02 saturated brine into various porous media structures at temperature T=25 and 80 C. The porous media are originally consisted of calcite. A chemical system consisting of Na+, Ca2+, Mg2+, H+, CO2(aq), and CI-is considered. The fluid flow, advection and diHusion of aqueous species, homogeneous reactions occurring in the bulk fluid, as weB as the dissolution of calcite and precipitation of dolomite are simulated at the pore scale. The effects of porous media structure on reactive transport are investigated. The results are compared with continuum scale modeling and the agreement and discrepancy are discussed. This work may shed some light on the fundamental physics occurring at the pore scale for reactive transport involved in geologic C02 sequestration.

  15. Economic Evaluation of Leading Technology Options for Sequestration of Carbon Dioxide

    E-Print Network [OSTI]

    development. Since power plants are the largest point sources of CO2 emissions, capturing the carbon dioxide ................................................................................................................................ 7 1.1 APPROACHES TO REDUCING CARBON DIOXIDE EMISSIONS1 Economic Evaluation of Leading Technology Options for Sequestration of Carbon Dioxide by Jérémy

  16. Carbon sequestration in leaky reservoirs Alain Jean-Marie, INRIA and UMR LIRMM

    E-Print Network [OSTI]

    Boyer, Edmond

    Carbon sequestration in leaky reservoirs Alain Jean-Marie, INRIA and UMR LIRMM Michel Moreaux, February 2, 2011 Abstract We propose in this paper a model of optimal Carbon Capture and Storage in which the reservoir of sequestered carbon is leaky, and pollution eventually is released into the atmosphere. We

  17. Soil carbon sequestration and land-use change: processes and potential

    E-Print Network [OSTI]

    Soil carbon sequestration and land-use change: processes and potential W . M . P O S T * and K . C to perennial vegetation, soil organic carbon can accumulate. This accumulation process essentially reverses some of the effects respon- sible for soil organic carbon losses from when the land was converted from

  18. Integrated Experimental and Modeling Studies of Mineral Carbonation as a Mechanism for Permanent Carbon Sequestration in Mafic/Ultramafic Rocks

    SciTech Connect (OSTI)

    Wang, Zhengrong; Qiu, Lin; Zhang, Shuang; Bolton, Edward; Bercovici, David; Ague, Jay; Karato, Shun-Ichiro; Oristaglio, Michael; Zhu, Wen-Iu; Lisabeth, Harry; Johnson, Kevin

    2014-09-30

    A program of laboratory experiments, modeling and fieldwork was carried out at Yale University, University of Maryland, and University of Hawai‘i, under a DOE Award (DE-FE0004375) to study mineral carbonation as a practical method of geologic carbon sequestration. Mineral carbonation, also called carbon mineralization, is the conversion of (fluid) carbon dioxide into (solid) carbonate minerals in rocks, by way of naturally occurring chemical reactions. Mafic and ultramafic rocks, such as volcanic basalt, are natural candidates for carbonation, because the magnesium and iron silicate minerals in these rocks react with brines of dissolved carbon dioxide to form carbonate minerals. By trapping carbon dioxide (CO2) underground as a constituent of solid rock, carbonation of natural basalt formations would be a secure method of sequestering CO2 captured at power plants in efforts to mitigate climate change. Geochemical laboratory experiments at Yale, carried out in a batch reactor at 200°C and 150 bar (15 MPa), studied carbonation of the olivine mineral forsterite (Mg2SiO4) reacting with CO2 brines in the form of sodium bicarbonate (NaHCO3) solutions. The main carbonation product in these reactions is the carbonate mineral magnesite (MgCO3). A series of 32 runs varied the reaction time, the reactive surface area of olivine grains and powders, the concentration of the reacting fluid, and the starting ratio of fluid to olivine mass. These experiments were the first to study the rate of olivine carbonation under passive conditions approaching equilibrium. The results show that, in a simple batch reaction, olivine carbonation is fastest during the first 24 hours and then slows significantly and even reverses. A natural measure of the extent of carbonation is a quantity called the carbonation fraction, which compares the amount of carbon removed from solution, during a run, to the maximum amount that could have been removed if the olivine initially present had fully dissolved and the cations released had subsequently precipitated in carbonate minerals. The carbonation fractions observed in batch experiments with olivine grains and powders varied significantly, from less than 0.01 (1%) to more than 0.5 (50%). Over time, the carbonation fractions reached an upper limit after about 24 to 72 hours of reaction, then stayed constant or decreased. The peak Final Scientific/Technical Report DE-FE0004275 | Mineral Carbonation | 4 coincided with the appearance of secondary magnesium-bearing silicate minerals, whose formation competes for magnesium ions in solution and can even promote conditions that dissolve magnesite. The highest carbonation fractions resulted from experiments with low ratios of concentrated solution to olivine, during which amorphous silica spheres or meshes formed, instead of secondary silicate minerals. The highest carbonation fractions appear to result from competing effects. Precipitation of silica layers on olivine reduces the reactive surface area and, thus, the rate of olivine dissolution (which ultimately limits the carbonation rate), but these same silica layers can also inhibit the formation of secondary silicate minerals that consume magnesite formed in earlier stages of carbonation. Simulation of these experiments with simple geochemical models using the software program EQ3/6 reproduces the general trends observed—especially the results for the carbonation fraction in short-run experiments. Although further experimentation and better models are needed, this study nevertheless provides a framework for understanding the optimal conditions for sequestering carbon dioxide by reacting CO2-bearing fluids with rocks containing olivine minerals. A series of experiments at the Rock Physics Laboratory at the University of Maryland studied the carbonation process during deformation of thermally cracked olivine-rich rock samples (dunit

  19. 2009 Carb Sequestration Workshop Presentations for Download (zipped) 1. Click on Title to go to presentations and download.

    E-Print Network [OSTI]

    Daniels, Jeffrey J.

    Laboratory Geochemical Tools for Monitoring Geologic Carbon Sequestration, (David Cole, ORNL) Andre Duguid-surface carbon sequestration T.S. Ramakrishnan (Jim Johnson, speaker) Schlumberger Capacity and Injectivity2009 Carb Sequestration Workshop Presentations for Download (zipped) 1. Click on Title to go

  20. Summary Report on CO{sub 2} Geologic Sequestration & Water Resources Workshop

    SciTech Connect (OSTI)

    Varadharajan, C.; Birkholzer, J.; Kraemer, S.; Porse, S.; Carroll, S.; Wilkin, R.; Maxwell, R.; Bachu, S.; Havorka, S.; Daley, T.; Digiulio, D.; Carey, W.; Strasizar, B.; Huerta, N.; Gasda, S.; Crow, W.

    2012-02-15

    The United States Environmental Protection Agency (EPA) and Lawrence Berkeley National Laboratory (LBNL) jointly hosted a workshop on “CO{sub 2} Geologic Sequestration and Water Resources” in Berkeley, June 1–2, 2011. The focus of the workshop was to evaluate R&D needs related to geological storage of CO{sub 2} and potential impacts on water resources. The objectives were to assess the current status of R&D, to identify key knowledge gaps, and to define specific research areas with relevance to EPA’s mission. About 70 experts from EPA, the DOE National Laboratories, industry, and academia came to Berkeley for two days of intensive discussions. Participants were split into four breakout session groups organized around the following themes: Water Quality and Impact Assessment/Risk Prediction; Modeling and Mapping of Area of Potential Impact; Monitoring and Mitigation; Wells as Leakage Pathways. In each breakout group, participants identified and addressed several key science issues. All groups developed lists of specific research needs; some groups prioritized them, others developed short-term vs. long-term recommendations for research directions. Several crosscutting issues came up. Most participants agreed that the risk of CO{sub 2} leakage from sequestration sites that are properly selected and monitored is expected to be low. However, it also became clear that more work needs to be done to be able to predict and detect potential environmental impacts of CO{sub 2} storage in cases where the storage formation may not provide for perfect containment and leakage of CO{sub 2}–brine might occur.

  1. Genetic Analysis in Populus Reveals Potential to Enhance Soil Carbon Sequestration In a paper published in the August, 2005 issue of Canadian Journal of Forest Research, scientists

    E-Print Network [OSTI]

    Genetic Analysis in Populus Reveals Potential to Enhance Soil Carbon Sequestration In a paper carbon sequestration by an estimated 0.35Gt carbon/year. This represents ca. 4% of global carbon in terrestrial ecosystems. This work is supported by research funded through the Carbon Sequestration Program

  2. The Urgent Need for Carbon Dioxide Sequestration Klaus S. Lackner, Darryl P. Butt, Reed Jensen and Hans Ziock

    E-Print Network [OSTI]

    1 The Urgent Need for Carbon Dioxide Sequestration Klaus S. Lackner, Darryl P. Butt, Reed Jensen in this field. This memo explains why the development of a viable sequestration technology is a long term stra- tegic goal of utmost importance and why sequestration provides a goal worthy of the attention

  3. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2003-07-28

    CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to methane storage in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject of current research. To accomplish this investigation, drill cuttings and cores were selected from the Kentucky Geological Survey Well Sample and Core Library. Methane and carbon dioxide adsorption analyses are being performed to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, sidewall core samples are being acquired to investigate specific black-shale facies, their potential CO{sub 2} uptake, and the resulting displacement of methane. Advanced logging techniques (elemental capture spectroscopy) are being investigated for possible correlations between adsorption capacity and geophysical log measurements. Initial estimates indicate a sequestration capacity of 5.3 billion tons CO{sub 2} in the Lower Huron Member of the Ohio shale in parts of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker portions of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

  4. Managing Commercial Tree Species for Timber Production and Carbon Sequestration: Management Guidelines and Financial Returns

    SciTech Connect (OSTI)

    Gary D. Kronrad

    2006-09-19

    A carbon credit market is developing in the United States. Information is needed by buyers and sellers of carbon credits so that the market functions equitably and efficiently. Analyses have been conducted to determine the optimal forest management regime to employ for each of the major commercial tree species so that profitability of timber production only or the combination of timber production and carbon sequestration is maximized. Because the potential of a forest ecosystem to sequester carbon depends on the tree species, site quality and management regimes utilized, analyses have determined how to optimize carbon sequestration by determining how to optimally manage each species, given a range of site qualities, discount rates, prices of carbon credits and other economic variables. The effects of a carbon credit market on the method and profitability of forest management, the cost of sequestering carbon, the amount of carbon that can be sequestered, and the amount of timber products produced has been determined.

  5. Review and model-based analysis of factors influencing soil carbon sequestration beneath switchgrass (Panicum virgatum)

    SciTech Connect (OSTI)

    Garten Jr, Charles T [ORNL

    2012-01-01

    Abstract. A simple, multi-compartment model was developed to predict soil carbon sequestration beneath switchgrass (Panicum virgatum) plantations in the southeastern United States. Soil carbon sequestration is an important component of sustainable switchgrass production for bioenergy because soil organic matter promotes water retention, nutrient supply, and soil properties that minimize erosion. A literature review was included for the purpose of model parameterization and five model-based experiments were conducted to predict how changes in environment (temperature) or crop management (cultivar, fertilization, and harvest efficiency) might affect soil carbon storage and nitrogen losses. Predictions of soil carbon sequestration were most sensitive to changes in annual biomass production, the ratio of belowground to aboveground biomass production, and temperature. Predictions of ecosystem nitrogen loss were most sensitive to changes in annual biomass production, the soil C/N ratio, and nitrogen remobilization efficiency (i.e., nitrogen cycling within the plant). Model-based experiments indicated that 1) soil carbon sequestration can be highly site specific depending on initial soil carbon stocks, temperature, and the amount of annual nitrogen fertilization, 2) response curves describing switchgrass yield as a function of annual nitrogen fertilization were important to model predictions, 3) plant improvements leading to greater belowground partitioning of biomass could increase soil carbon sequestration, 4) improvements in harvest efficiency have no indicated effects on soil carbon and nitrogen, but improve cumulative biomass yield, and 5) plant improvements that reduce organic matter decomposition rates could also increase soil carbon sequestration, even though the latter may not be consistent with desired improvements in plant tissue chemistry to maximize yields of cellulosic ethanol.

  6. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    86 MIDWEST REGIONAL CARBON SEQUESTRATION PARTNERSHIP,22, 2006 MIDWEST REGIONAL CARBON SEQUESTRATION PARTNERSHIP,Midwest Regional Carbon Sequestration Partnership (MRCSP),

  7. Carbon Sequestration to Mitigate Climate Change Human activities, especially the burning of fossil fuels such as coal, oil, and gas, have caused a substantial increase

    E-Print Network [OSTI]

    Carbon Sequestration to Mitigate Climate Change Human activities, especially the burning of fossil-caused CO2 emissions and to remove CO2 from the atmosphere. 2.0 What is carbon sequestration? The term "carbon sequestration" is used to describe both natural and deliberate CARBON,INGIGATONSPERYEAR 1.5 Fossil

  8. Mathematical Modeling of Carbon Dioxide Injection in the Subsurface for Improved Hydrocarbon Recovery and Sequestration

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    Mathematical Modeling of Carbon Dioxide Injection in the Subsurface for Improved Hydrocarbon Recovery and Sequestration Philip C. Myint, Laurence Rongy, Kjetil B. Haugen, Abbas Firoozabadi Department. Combustion of fossil fuels contributes to rising atmospheric carbon dioxide (CO2) levels that have been

  9. CHARACTERIZATION OF CENTRAL APPALACHIAN BASIN CBM DEVELOPMENT: POTENTIAL FOR CARBON SEQUESTRATION

    E-Print Network [OSTI]

    including those areas where CBM production has previously been developed. The enhanced coalbed methane (ECBM0625 CHARACTERIZATION OF CENTRAL APPALACHIAN BASIN CBM DEVELOPMENT: POTENTIAL FOR CARBON of the carbon sequestration potential of the Pennsylvanian-age coalbeds in the Central Appalachian Basin

  10. GEOC R Lee Penn Sunday, March 25, 2012 12 -Biogeochemical transformation of Fe-and Mn-along a redox gradient: Implications for carbon sequestration

    E-Print Network [OSTI]

    Sparks, Donald L.

    a redox gradient: Implications for carbon sequestration within the Christina River Basin Critical Zone States Organic carbon (C)-mineral complexation mechanism is crucial in C sequestration. It is a function

  11. UBC Social Ecological Economic Development Studies (SEEDS) Student Report The carbon sequestration potential of three common turfgrasses

    E-Print Network [OSTI]

    of a project/report. #12;2 The carbon sequestration potential of three common turfgrasses: Lolium perenne1 UBC Social Ecological Economic Development Studies (SEEDS) Student Report The carbon sequestration potential of three common turfgrasses: Lolium perenne; Fescue rubra; and Poa pratensis Yihan Wu

  12. Carbon sequestration and greenhouse gas emissions in urban turf

    E-Print Network [OSTI]

    Townsend-Small, Amy; Czimczik, Claudia I

    2010-01-01

    facts: Average carbon dioxide emissions resulting fromcalculation of carbon dioxide (CO 2 ) emissions from fuel

  13. The Subsurface Fluid Mechanics of Geologic Carbon Dioxide Storage

    E-Print Network [OSTI]

    The Subsurface Fluid Mechanics of Geologic Carbon Dioxide Storage by Michael Lawrence Szulczewski S Mechanics of Geologic Carbon Dioxide Storage by Michael Lawrence Szulczewski Submitted to the Department capture and storage (CCS), CO2 is captured at power plants and then injected into deep geologic reservoirs

  14. Water Challenges for Geologic Carbon Capture and Sequestration

    E-Print Network [OSTI]

    Newmark, Robin L.; Friedmann, Samuel J.; Carroll, Susan A.

    2010-01-01

    gas recovery in conjunction with storage in unmineable coaland coal beds exist where CO 2 -enhanced product recovery iscoal, oil or even nuclear fuels to in the hundreds to thousands for more advanced processes such as enhanced oil recovery (

  15. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    seawater,  industrial  waste,   and  brine  desalination  and  seawater  concentrate  disposal  alternatives."   Desalination  

  16. Regional evaluation of brine management for geologic carbon sequestration

    E-Print Network [OSTI]

    Breunig, H.M.

    2014-01-01

    produced water from the Barnett Shale in Texas to freshwatervolume treated in the Barnett Shale project is smaller than

  17. Water Challenges for Geologic Carbon Capture and Sequestration

    E-Print Network [OSTI]

    Newmark, Robin L.; Friedmann, Samuel J.; Carroll, Susan A.

    2010-01-01

    constrained energy system. Water is already an integralSubstantial amounts of water are used in energy resourceU.S. , roughly equivalent to water withdrawals for irrigated

  18. Regional evaluation of brine management for geologic carbon sequestration

    E-Print Network [OSTI]

    Breunig, H.M.

    2014-01-01

    algae production, GCS, and other BUS options could improve joint feasibility: • Bio-diesel and/or biogas

  19. Certification Framework Based on Effective Trapping for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2009-01-01

    and W. D. Wuerch, Geothermal Gradient Map of Texas: Theto the SE. The geothermal gradient in the area is estimated

  20. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    water  management  options,  including:  geothermal  energy   extraction,  desalination,  salt  and  mineral   harvesting,  

  1. Water Challenges for Geologic Carbon Capture and Sequestration

    E-Print Network [OSTI]

    Newmark, Robin L.; Friedmann, Samuel J.; Carroll, Susan A.

    2010-01-01

    represents natural gas combined cycle, PC Sub and PC Superintegrated gasi?cation combined cycle (IGCC) plants withand natural gas combined cycle (NGCC) with amine capture (

  2. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    sites  and  favorability  of  deep  EGS  (Roberts  geothermal  system  (EGS)  recharge,   underground  EGS  .  

  3. Regional evaluation of brine management for geologic carbon sequestration

    E-Print Network [OSTI]

    Breunig, H.M.

    2014-01-01

    are: (1) geothermal energy, (2) desalination, (3) salt,desalination; saline water for cooling towers; makeup water for enhanced oil recovery (EOR) systems; and geothermal

  4. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    CO 2 ]  of  geothermal  heat,  desalination  water,  algae  geothermal  energy   extraction,  desalination,  salt  and  Geothermal  Energy  Systems CHP  Binary  Cycle Section  5.3  Non-­?potable  Water   NPV Reverse  Osmosis  Treatment Water  Sold  at  Desalination  

  5. Assessment of Brine Management for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Breunig, Hanna M.

    2014-01-01

    and  pumping  water  is  capital  and  energy  intensive,  such  as  geothermal  energy,  water  for  aquaculture,  substantial  capital,   energy,  and  water  demands  of  

  6. Certification Framework Based on Effective Trapping for Geologic Carbon Sequestration

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2009-01-01

    southeast of the Fulshear Gas Storage Reservoir at Katy,field as a natural gas storage facility and for authority torecharge, natural gas storage, solution mining, hazardous

  7. Water Challenges for Geologic Carbon Capture and Sequestration

    E-Print Network [OSTI]

    Newmark, Robin L.; Friedmann, Samuel J.; Carroll, Susan A.

    2010-01-01

    and production, natural gas storage, acid gas disposal,mitigation from the natural gas storage and oil industries.occurring in natural gas storage ?elds (Perry 2003; Kuus-

  8. Regional evaluation of brine management for geologic carbon sequestration

    E-Print Network [OSTI]

    Breunig, H.M.

    2014-01-01

    typical of enhanced geothermal systems (EGS) which rechargefor enhanced oil recovery (EOR) systems; and geothermal

  9. Rock Physics of Geologic Carbon Sequestration/Storage (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding access toSmall ReactorRaymond Davis,Robert Curl, Jr. andSciTech

  10. Geological Carbon Sequestration, Spelunking and You | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nA Guide to Tapping intoandMinimaland the 1918Generic DeepEnergy more

  11. Rock Physics of Geologic Carbon Sequestration/Storage (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail. (Conference) | SciTech Connect Robust emergent climateSciTech Connect

  12. Establishing MICHCARB, a geological carbon sequestration research and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submitKansasCommunitiesof Energy ServicesEnergy4thwrites outEssamEstablished

  13. Genome Enabled Discovery of Carbon Sequestration Genes in Poplar

    SciTech Connect (OSTI)

    Filichkin, Sergei; Etherington, Elizabeth; Ma, Caiping; Strauss, Steve

    2007-02-22

    The goals of the S.H. Strauss laboratory portion of 'Genome-enabled discovery of carbon sequestration genes in poplar' are (1) to explore the functions of candidate genes using Populus transformation by inserting genes provided by Oakridge National Laboratory (ORNL) and the University of Florida (UF) into poplar; (2) to expand the poplar transformation toolkit by developing transformation methods for important genotypes; and (3) to allow induced expression, and efficient gene suppression, in roots and other tissues. As part of the transformation improvement effort, OSU developed transformation protocols for Populus trichocarpa 'Nisqually-1' clone and an early flowering P. alba clone, 6K10. Complete descriptions of the transformation systems were published (Ma et. al. 2004, Meilan et. al 2004). Twenty-one 'Nisqually-1' and 622 6K10 transgenic plants were generated. To identify root predominant promoters, a set of three promoters were tested for their tissue-specific expression patterns in poplar and in Arabidopsis as a model system. A novel gene, ET304, was identified by analyzing a collection of poplar enhancer trap lines generated at OSU (Filichkin et. al 2006a, 2006b). Other promoters include the pGgMT1 root-predominant promoter from Casuarina glauca and the pAtPIN2 promoter from Arabidopsis root specific PIN2 gene. OSU tested two induction systems, alcohol- and estrogen-inducible, in multiple poplar transgenics. Ethanol proved to be the more efficient when tested in tissue culture and greenhouse conditions. Two estrogen-inducible systems were evaluated in transgenic Populus, neither of which functioned reliably in tissue culture conditions. GATEWAY-compatible plant binary vectors were designed to compare the silencing efficiency of homologous (direct) RNAi vs. heterologous (transitive) RNAi inverted repeats. A set of genes was targeted for post transcriptional silencing in the model Arabidopsis system; these include the floral meristem identity gene (APETALA1 or AP1), auxin response factor gene (ETTIN), the gene encoding transcriptional factor of WD40 family (TRANSPARENTTESTAGLABRA1 or TTG1), and the auxin efflux carrier (PIN-FORMED2 or PIN2) gene. More than 220 transgenic lines of the 1st, 2nd and 3rd generations were analyzed for RNAi suppression phenotypes (Filichkin et. al., manuscript submitted). A total of 108 constructs were supplied by ORNL, UF and OSU and used to generate over 1,881 PCR verified transgenic Populus and over 300 PCR verified transgenic Arabidopsis events. The Populus transgenics alone required Agrobacterium co-cultivations of 124.406 explants.

  14. 150 G. Marland et al. / Climate Policy 3 (2003) 149157 Strategies to mitigate anthropogenic climate change recognize that carbon sequestration in the terrestrial biosphere

    E-Print Network [OSTI]

    Niyogi, Dev

    2003-01-01

    anthropogenic climate change recognize that carbon sequestration in the terrestrial biosphere can reduce to create a system of credits and debits wherein emission or sequestration of carbon in the biosphere; Carbon sequestration; Land use change; Land surface change; Surface energy balance 1. Introduction Human

  15. Physical Constraints on Geologic CO2 Sequestration in Low-Volume Basalt Formations

    SciTech Connect (OSTI)

    Ryan M. Pollyea; Jerry P. Fairley; Robert K. Podgorney; Travis L. McLing

    2014-03-01

    Deep basalt formations within large igneous provinces have been proposed as target reservoirs for carbon capture and sequestration on the basis of favorable CO2-water-rock reaction kinetics that suggest carbonate mineralization rates on the order of 102–103 d. Although these results are encouraging, there exists much uncertainty surrounding the influence of fracture-controlled reservoir heterogeneity on commercial-scale CO2 injections in basalt formations. This work investigates the physical response of a low-volume basalt reservoir to commercial-scale CO2 injections using a Monte Carlo numerical modeling experiment such that model variability is solely a function of spatially distributed reservoir heterogeneity. Fifty equally probable reservoirs are simulated using properties inferred from the deep eastern Snake River Plain aquifer in southeast Idaho, and CO2 injections are modeled within each reservoir for 20 yr at a constant mass rate of 21.6 kg s–1. Results from this work suggest that (1) formation injectivity is generally favorable, although injection pressures in excess of the fracture gradient were observed in 4% of the simulations; (2) for an extensional stress regime (as exists within the eastern Snake River Plain), shear failure is theoretically possible for optimally oriented fractures if Sh is less than or equal to 0.70SV; and (3) low-volume basalt reservoirs exhibit sufficient CO2 confinement potential over a 20 yr injection program to accommodate mineral trapping rates suggested in the literature.

  16. Carbon Capture and Sequestration from a Hydrogen Production Facility in an Oil Refinery

    SciTech Connect (OSTI)

    Engels, Cheryl; Williams, Bryan, Valluri, Kiranmal; Watwe, Ramchandra; Kumar, Ravi; Mehlman, Stewart

    2010-06-21

    The project proposed a commercial demonstration of advanced technologies that would capture and sequester CO2 emissions from an existing hydrogen production facility in an oil refinery into underground formations in combination with Enhanced Oil Recovery (EOR). The project is led by Praxair, Inc., with other project participants: BP Products North America Inc., Denbury Onshore, LLC (Denbury), and Gulf Coast Carbon Center (GCCC) at the Bureau of Economic Geology of The University of Texas at Austin. The project is located at the BP Refinery at Texas City, Texas. Praxair owns and operates a large hydrogen production facility within the refinery. As part of the project, Praxair would construct a CO2 capture and compression facility. The project aimed at demonstrating a novel vacuum pressure swing adsorption (VPSA) based technology to remove CO2 from the Steam Methane Reformers (SMR) process gas. The captured CO2 would be purified using refrigerated partial condensation separation (i.e., cold box). Denbury would purchase the CO2 from the project and inject the CO2 as part of its independent commercial EOR projects. The Gulf Coast Carbon Center at the Bureau of Economic Geology, a unit of University of Texas at Austin, would manage the research monitoring, verification and accounting (MVA) project for the sequestered CO2, in conjunction with Denbury. The sequestration and associated MVA activities would be carried out in the Hastings field at Brazoria County, TX. The project would exceed DOE?s target of capturing one million tons of CO2 per year (MTPY) by 2015. Phase 1 of the project (Project Definition) is being completed. The key objective of Phase 1 is to define the project in sufficient detail to enable an economic decision with regard to proceeding with Phase 2. This topical report summarizes the administrative, programmatic and technical accomplishments completed in Phase 1 of the project. It describes the work relative to project technical and design activities (associated with CO2 capture technologies and geologic sequestration MVA), and Environmental Information Volume. Specific accomplishments of this Phase include: 1. Finalization of the Project Management Plan 2. Development of engineering designs in sufficient detail for defining project performance and costs 3. Preparation of Environmental Information Volume 4. Completion of Hazard Identification Studies 5. Completion of control cost estimates and preparation of business plan During the Phase 1 detailed cost estimate, project costs increased substantially from the previous estimate. Furthermore, the detailed risk assessment identified integration risks associated with potentially impacting the steam methane reformer operation. While the Phase 1 work identified ways to mitigate these integration risks satisfactorily from an operational perspective, the associated costs and potential schedule impacts contributed to the decision not to proceed to Phase 2. We have concluded that the project costs and integration risks at Texas City are not commensurate with the potential benefits of the project at this time.

  17. Modeling to discern nitrogen fertilization impacts on carbon sequestration in a Pacific Northwest Douglas-fir

    E-Print Network [OSTI]

    Modeling to discern nitrogen fertilization impacts on carbon sequestration in a Pacific Northwest A R K J O H N S O N } *LREIS Institute of Geographic Sciences & Nature Resources Research, Chinese of Forestry, University of British Columbia, Vancouver, BC, Canada V6T 1Z4, zBiometeorology and Soil Physics

  18. A Case Study from Norway on Gas-Fired Power Plants, Carbon Sequestration, and Politics

    E-Print Network [OSTI]

    1 A Case Study from Norway on Gas-Fired Power Plants, Carbon Sequestration, and Politics Guillaume contended the gas-fired plants would slow Norway's dependence on imported electricity from Denmark, which 81-71 in favor of building Norway's first natural gas-fired power plant.1 As a result Bondevik

  19. Permanence Discounting for Land-Based Carbon Sequestration Man-Keun Kim

    E-Print Network [OSTI]

    McCarl, Bruce A.

    are not subject to such concerns. For example, methane capture and combustion in subsequent energy production widely suggested as a potentially cost-competitive means for reducing net greenhouse gas (GHG) emissions explored the potential of land-based carbon sequestration strategies in the US such as afforestation

  20. An XFEM Model for Carbon Sequestration Journal: International Journal for Numerical Methods in Engineering

    E-Print Network [OSTI]

    Gracie, Robert

    the temperatures and pressures are such that the CO2 exists in a supercritical state. The supercritical CO2 is less method (XFEM) model is presented to analyze the injection and sequestration of carbon dioxide (CO2 method (SUPG-FEM-FDM) to approximate the distribution of CO2 in the aquifer. Near well enrichment

  1. First National Conference on Carbon Sequestration Washington, DC, May 14-17, 2001

    E-Print Network [OSTI]

    sequestration by direct injection by Ken Caldeira*, Howard J. Herzog , and Michael E. Wickett* DOE Center 02139 USA (hjherzog@mit.edu) Abstract Direct injection of CO2 into the ocean is a potentially effective with other carbon management options. Here, after a brief review of direct oceanic injection, we estimate

  2. EIS-0366: Implementation of the Office of Fossil Energy's Carbon Sequestration Program

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy (DOE) announces its intent to prepare a Programmatic Environmental Impact Statement (PEIS) to assess the potential environmental impacts from the Department of Energy’s (DOE’s) Carbon Sequestration Program, which is being implemented by the Office of Fossil Energy.

  3. Properties of Mutants of Synechocystis sp. Strain PCC 6803 Lacking Inorganic Carbon Sequestration Systems

    E-Print Network [OSTI]

    Roegner, Matthias

    ­ driven by light energy (Giordano et al. 2005, Kaplan et al. 2008, Price et al. 2008). Two CO2 uptake the significance of carbon sequestration in dissipating excess light energy. Keywords: CO2 and HCO3 À uptake -- CO2 HCO3 ­ transporter dependent on BicA (Price et al. 2005). Both CO2 and HCO3 ­ are taken up

  4. A pre-publication version of Carbon Trends in U.S. forestlands: a context for the role of soils in forest carbon sequestration. The Potential of U.S. Forest Soils to Sequester Carbon. Chapter 3

    E-Print Network [OSTI]

    in forest carbon sequestration. The Potential of U.S. Forest Soils to Sequester Carbon. Chapter 3 in: Kimble-45. Carbon Trends in U.S. Forestlands: A Context for the Role of Soils in Forest Carbon Sequestration Linda SA pre-publication version of Carbon Trends in U.S. forestlands: a context for the role of soils

  5. Comparison of methods for geologic storage of carbon dioxide...

    Office of Scientific and Technical Information (OSTI)

    storage potential in geologic formations provide critical information related to Carbon Capture, Utilization, and Storage (CCUS) technologies to mitigate COsub 2 emissions....

  6. Supercritical fluid behavior at nanoscale interfaces: implications for CO2 sequestration in geologic formations

    SciTech Connect (OSTI)

    Cole, David R [ORNL; Chialvo, Ariel A [ORNL; Rother, Gernot [ORNL; Vlcek, L. [Vanderbilt University; Cummings, Peter T [ORNL

    2010-01-01

    Injection of CO2 into subsurface geologic formations has been identified as a key strategy for mitigating the impact of anthropogenic emissions of CO2. A key aspect of this process is the prevention of leakage from the host formation by an effective cap or seal rock which has low porosity and permeability characteristics. Shales comprise the majority of cap rocks encountered in subsurface injection sites with pore sizes typically less than 100 nm and whose surface chemistries are dominated by quartz (SiO2) and clays. We report the behavior of pure CO2 interacting with simple substrates, i.e. SiO2 and mica, that act as proxies for more complex mineralogical systems. Modeling of small-angle neutron scattering (SANS) data taken from CO2- silica aerogel (95% porosity; 6 nm pores) interactions indicates the presence of fluid depletion for conditions above the critical density. A theoretical framework, i.e. integral equation approximation (IEA), is presented that describes the fundamental behavior of near-critical adsorption onto a non-confining substrate that is consistent with SANS experimental results. Structural and dynamic behavior for supercritical CO2 interaction in K-mica slit pores was assessed by classical molecular dynamics (CMD). These results indicate the development of distinct layers of CO2 within slit pores, reduced mobility by one to two orders of magnitudes compared to bulk CO2 depending on pore size and formation of bonds between CO2 oxygens and H from mica hydroxyls. Analysis of simple, well-characterized fluid-substrate systems can provide details on the thermodynamic, structural and dynamic properties of CO2 at conditions relevant to sequestration.

  7. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2003-02-10

    Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, strategy is to inject CO{sub 2} into organic-rich shales of Devonian age. Devonian black shales underlie approximately two-thirds of Kentucky and are generally thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to the way methane is stored in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane at a ratio of two to one. Black shales may similarly desorb methane in the presence of CO{sub 2}. If black shales similarly desorb methane in the presence of CO{sub 2}, the shales may be an excellent sink for CO{sub 2} with the added benefit of serving to enhance natural gas production. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject this research. To accomplish this investigation, drill cuttings and cores will be selected from the Kentucky Geological Survey Well Sample and Core Library. CO{sub 2} adsorption analyses will be performed in order to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, new drill cuttings and sidewall core samples will be acquired to investigate specific black-shale facies, their uptake of CO{sub 2}, and the resultant displacement of methane. Advanced logging techniques (elemental capture spectroscopy) will be used to investigate possible correlations between adsorption capacity and geophysical log measurements.

  8. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2003-02-11

    Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, strategy is to inject CO{sub 2} into organic-rich shales of Devonian age. Devonian black shales underlie approximately two-thirds of Kentucky and are generally thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to the way methane is stored in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane at a ratio of two to one. Black shales may similarly desorb methane in the presence of CO{sub 2}. If black shales similarly desorb methane in the presence of CO{sub 2}, the shales may be an excellent sink for CO{sub 2} with the added benefit of serving to enhance natural gas production. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject this research. To accomplish this investigation, drill cuttings and cores will be selected from the Kentucky Geological Survey Well Sample and Core Library. CO{sub 2} adsorption analyses will be performed in order to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, new drill cuttings and sidewall core samples will be acquired to investigate specific black-shale facies, their uptake of CO{sub 2}, and the resultant displacement of methane. Advanced logging techniques (elemental capture spectroscopy) will be used to investigate possible correlations between adsorption capacity and geophysical log measurements.

  9. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2003-04-28

    Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, strategy is to inject CO{sub 2} into organic-rich shales of Devonian age. Devonian black shales underlie approximately two-thirds of Kentucky and are generally thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is estimated to be between 63 and 112 trillion cubic feet. Most of this natural gas is adsorbed on clay and kerogen surfaces, analogous to the way methane is stored in coal beds. In coals, it has been demonstrated that CO{sub 2} is preferentially adsorbed, displacing methane at a ratio of two to one. Black shales may similarly desorb methane in the presence of CO{sub 2}. If black shales similarly desorb methane in the presence of CO{sub 2}, the shales may be an excellent sink for CO{sub 2} with the added benefit of serving to enhance natural gas production. The concept that black, organic-rich Devonian shales could serve as a significant geologic sink for CO{sub 2} is the subject this research. To accomplish this investigation, drill cuttings and cores will be selected from the Kentucky Geological Survey Well Sample and Core Library. CO{sub 2} adsorption analyses will be performed in order to determine the gas-storage potential of the shale and to identify shale facies with the most sequestration potential. In addition, new drill cuttings and sidewall core samples will be acquired to investigate specific black-shale facies, their uptake of CO{sub 2}, and the resultant displacement of methane. Advanced logging techniques (elemental capture spectroscopy) will be used to investigate possible correlations between adsorption capacity and geophysical log measurements.

  10. Modeling and Risk Assessment of CO{sub 2} Sequestration at the Geologic-basin Scale

    SciTech Connect (OSTI)

    Juanes, Ruben

    2013-08-31

    Objectives. The overall objective of this proposal was to develop tools for better understanding, modeling and risk assessment of CO{sub 2} permanence in geologic formations at the geologic basin scale. The main motivation was that carbon capture and storage (CCS) will play an important role as a climate change mitigation technology only if it is deployed at scale of gigatonne per year injections over a period of decades. Continuous injection of this magnitude must be understood at the scale of a geologic basin. Specifically, the technical objectives of this project were: (1) to develop mathematical models of capacity and injectivity at the basin scale; (2) to apply quantitative risk assessment methodologies that will inform on CO{sub 2} permanence; (3) to apply the models to geologic basins across the continental United States. These technical objectives go hand-in-hand with the overarching goals of: (1) advancing the science for deployment of CCS at scale; and (2) contributing to training the next generation of scientists and engineers that will implement and deploy CCS in the United States and elsewhere. Methods. The differentiating factor of this proposal was to perform fundamental research on migration and fate of CO{sub 2} and displaced brine at the geologic basin scale. We developed analytical sharp-interface models of the evolution of CO{sub 2} plumes over the duration of injection (decades) and after injection (centuries). We applied the analytical solutions of CO{sub 2} plume migration and pressure evolution to specific geologic basins, to estimate the maximum footprint of the plume, and the maximum injection rate that can be sustained during a certain injection period without fracturing the caprock. These results have led to more accurate capacity estimates, based on fluid flow dynamics, rather than ad hoc assumptions of an overall “efficiency factor.” We also applied risk assessment methodologies to evaluate the uncertainty in our predictions of storage capacity and leakage rates. This was possible because the analytical mathematical models provide ultrafast forward simulation and they contain few parameters. Impact. The project has been enormously successful both in terms of its scientific output (journal publications) as well as impact in the government and industry. The mathematical models and uncertainty quantification methodologies developed here o?er a physically-based approach for estimating capacity and leakage risk at the basin scale. Our approach may also facilitate deployment of CCS by providing the basis for a simpler and more coherent regulatory structure than an “individual-point-of-injection” permitting approach. It may also lead to better science-based policy for post-closure design and transfer of responsibility to the State.

  11. The impact of co-occurring tree and grassland species on carbon sequestration and potential biofuel production

    E-Print Network [OSTI]

    Thomas, David D.

    for terrestrial carbon sequestration and potential biofuel production. For P. strobus, above- ground plant carbonThe impact of co-occurring tree and grassland species on carbon sequestration and potential biofuel production R A M E S H L A U N G A N I and J O H A N N E S M . H . K N O P S School of Biological Sciences

  12. Research Experience in Carbon Sequestration 2010 Now Accepting...

    Broader source: Energy.gov (indexed) [DOE]

    Students and early career professionals can gain hands-on experience in areas related to carbon capture and storage (CCS) by participating in the Research Experience in Carbon...

  13. EXPERIMENTAL EVALUATION OF CHEMICAL SEQUESTRATION OF CARBON DIOXIDE IN DEEP AQUIFER MEDIA - PHASE II

    SciTech Connect (OSTI)

    Neeraj Gupta; Bruce Sass; Jennifer Ickes

    2000-11-28

    In 1998 Battelle was selected by the U.S. Department of Energy's (DOE) National Energy Technology Laboratory (NETL) under a Novel Concepts project grant to continue Phase II research on the feasibility of carbon dioxide (CO{sub 2}) sequestration in deep saline formations. The focus of this investigation is to conduct detailed laboratory experiments to examine factors that may affect chemical sequestration of CO{sub 2} in deep saline formations. Reactions between sandstone and other geologic media from potential host reservoirs, brine solutions, and CO{sub 2} are being investigated under high-pressure conditions. Some experiments also include sulfur dioxide (SO{sub 2}) gases to evaluate the potential for co-injection of CO{sub 2} and SO{sub 2} related gases in the deep formations. In addition, an assessment of engineering and economic aspects is being conducted. This current Technical Progress Report describes the status of the project as of September 2000. The major activities undertaken during the quarter included several experiments conducted to investigate the effects of pressure, temperature, time, and brine composition on rock samples from potential host reservoirs. Samples (both powder and slab) were taken from the Mt. Simon Sandstone, a potential CO{sub 2} host formation in the Ohio, the Eau Claire Shale, and Rome Dolomite samples that form the caprock for Mt. Simon Sandstone. Also, a sample with high calcium plagioclase content from Frio Formation in Texas was used. In addition, mineral samples for relatively pure Anorthite and glauconite were experimented on with and without the presence of additional clay minerals such as kaolinite and montmorillonite. The experiments were run for one to two months at pressures similar to deep reservoirs and temperatures set at 50 C or 150 C. Several enhancements were made to the experimental equipment to allow for mixing of reactants and to improve sample collection methods. The resulting fluids (gases and liquids) as well as the rock samples were characterized to evaluate the geochemical changes over the experimental period. Preliminary results from the analysis are presented in the report. More detailed interpretation of the results will be presented in the technical report at the end of Phase II.

  14. Geoscience Perspectives in Carbon Sequestration - Educational Training and Research Through Classroom, Field, and Laboratory Investigations

    SciTech Connect (OSTI)

    Wronkiewicz, David; Paul, Varum; Abousif, Alsedik; Ryback, Kyle

    2013-09-30

    The most effective mechanism to limit CO{sub 2} release from underground Geologic Carbon Sequestration (GCS) sites over multi-century time scales will be to convert the CO{sub 2} into solid carbonate minerals. This report describes the results from four independent research investigations on carbonate mineralization: 1) Colloidal calcite particles forming in Maramec Spring, Missouri, provide a natural analog to evaluate reactions that may occur in a leaking GCS site. The calcite crystals form as a result of physiochemical changes that occur as the spring water rises from a depth of more than 190'?. The resultant pressure decrease induces a loss of CO{sub 2} from the water, rise in pH, lowering of the solubility of Ca{sup 2+} and CO{sub 3}{sup 2-}, and calcite precipitation. Equilibrium modelling of the spring water resulted in a calculated undersaturated state with respect to calcite. The discontinuity between the observed occurrence of calcite and the model result predicting undersaturated conditions can be explained if bicarbonate ions (HCO{sub 3}{sup -}) are directly involved in precipitation process rather than just carbonate ions (CO{sub 3}{sup 2-}). 2) Sedimentary rocks in the Oronto Group of the Midcontinent Rift (MCR) system contain an abundance of labile Ca-, Mg-, and Fe-silicate minerals that will neutralize carbonic acid and provide alkaline earth ions for carbonate mineralization. One of the challenges in using MCR rocks for GCS results from their low porosity and permeability. Oronto Group samples were reacted with both CO{sub 2}-saturated deionized water at 90°C, and a mildly acidic leachant solution in flow-through core-flooding reactor vessels at room temperature. Resulting leachate solutions often exceeded the saturation limit for calcite. Carbonate crystals were also detected in as little as six days of reaction with Oronto Group rocks at 90oC, as well as experiments with forsterite-olivine and augite, both being common minerals this sequence. The Oronto Group samples have poor reservoir rock characteristics, none ever exceeded a permeability value of 2.0 mD even after extensive dissolution of calcite cement during the experiments. The overlying Bayfield Group – Jacobsville Formation sandstones averaged 13.4 ± 4.3% porosity and a single sample tested by core-flooding revealed a permeability of ~340 mD. The high porosity-permeability characteristics of these sandstones will allow them to be used for GCS as a continuous aquifer unit with the overlying Mt. Simon Formation. 3) Anaerobic sulfate reducing bacteria (SRB) can enhance the conversion rate of CO{sub 2} into solid minerals and thereby improve long-term storage. SRB accelerated carbonate mineralization reactions between pCO{sub 2} values of 0.0059 and 14.7 psi. Hydrogen, lactate and formate served as suitable electron donors for SRB metabolism. The use of a {sup 13}CO{sub 2} spiked gas source also produced carbonate minerals with ~53% of the carbon being derived from the gas phase. The sulfate reducing activity of the microbial community was limited, however, at 20 psi pCO{sub 2} and carbonate mineralization did not occur. Inhibition of bacterial metabolism may have resulted from the acidic conditions or CO{sub 2} toxicity. 4) Microbialite communities forming in the high turbidity and hypersaline water of Storrs’ Lake, San Salvador Island, The Bahamas, were investigated for their distribution, mineralogy and microbial diversity. Molecular analysis of the organic mats on the microbialites indicate only a trace amount of cyanobacteria, while anaerobic and photosynthetic non-sulfur bacteria of the phyla Chloroflexi and purple sulfur bacteria of class Gammaproteobacteria were abundant.

  15. Integrated Assessment Modeling of Carbon Sequestration and Land Use Emissions Using Detailed Model Results and Observations

    SciTech Connect (OSTI)

    Dr. Atul Jain

    2005-04-17

    This report outlines the progress on the development and application of Integrated Assessment Modeling of Carbon Sequestrations and Land Use Emissions supported by the DOE Office of Biological and Environmental Research (OBER), U.S. Department of Energy, Grant No. DOE-DE-FG02-01ER63069. The overall objective of this collaborative project between the University of Illinois at Urbana-Champaign (UIUC), Oak Ridge National Laboratory (ORNL), Lawrence Livermore National Laboratory (LLNL), and Pacific Northwest National Laboratory (PNNL) was to unite the latest advances in carbon cycle research with scientifically based models and policy-related integrated assessment tools that incorporate computationally efficient representations of the latest knowledge concerning science and emission trajectories, and their policy implications. As part of this research we accomplished the following tasks that we originally proposed: (1) In coordination with LLNL and ORNL, we enhanced the Integrated Science Assessment Model's (ISAM) parametric representation of the ocean and terrestrial carbon cycles that better represent spatial and seasonal variations, which are important to study the mechanisms that influence carbon sequestration in the ocean and terrestrial ecosystems; (2) Using the MiniCAM modeling capability, we revised the SRES (IPCC Special Report on Emission Scenarios; IPCC, 2000) land use emission scenarios; and (3) On the application front, the enhanced version of ISAM modeling capability is applied to understand how short- and long-term natural carbon fluxes, carbon sequestration, and human emissions contribute to the net global emissions (concentrations) trajectories required to reach various concentration (emission) targets. Under this grant, 21 research publications were produced. In addition, this grant supported a number of graduate and undergraduate students whose fundamental research was to learn a disciplinary field in climate change (e.g., ecological dynamics and ocean circulations) and then complete research on how this field could be linked to the other factors we need to consider in its dynamics (e.g., land use, ocean and terrestrial carbon sequestration and climate change).

  16. Terrestrial sequestration

    ScienceCinema (OSTI)

    Charlie Byrer

    2010-01-08

    Terrestrial sequestration is the enhancement of CO2 uptake by plants that grow on land and in freshwater and, importantly, the enhancement of carbon storage in soils where it may remain more permanently stored. Terrestrial sequestration provides an opportunity for low-cost CO2 emissions offsets.

  17. Terrestrial sequestration

    SciTech Connect (OSTI)

    Charlie Byrer

    2008-03-10

    Terrestrial sequestration is the enhancement of CO2 uptake by plants that grow on land and in freshwater and, importantly, the enhancement of carbon storage in soils where it may remain more permanently stored. Terrestrial sequestration provides an opportunity for low-cost CO2 emissions offsets.

  18. Comparison of methods for geologic storage of carbon dioxide in saline formations

    SciTech Connect (OSTI)

    Goodman, Angela L. [U.S. DOE; Bromhal, Grant S. [U.S. DOE; Strazisar, Brian [U.S. DOE; Rodosta, Traci D. [U.S. DOE; Guthrie, William J. [U.S. DOE; Allen, Douglas E. [ORISE; Guthrie, George D. [U.S. DOE

    2013-01-01

    Preliminary estimates of CO{sub 2} storage potential in geologic formations provide critical information related to Carbon Capture, Utilization, and Storage (CCUS) technologies to mitigate CO{sub 2} emissions. Currently multiple methods to estimate CO{sub 2} storage and multiple storage estimates for saline formations have been published, leading to potential uncertainty when comparing estimates from different studies. In this work, carbon dioxide storage estimates are compared by applying several commonly used methods to general saline formation data sets to assess the impact that the choice of method has on the results. Specifically, six CO{sub 2} storage methods were applied to thirteen saline formation data sets which were based on formations across the United States with adaptations to provide the geologic inputs required by each method. Methods applied include those by (1) international efforts – the Carbon Sequestration Leadership Forum (Bachu et al., 2007); (2) United States government agencies – U.S. Department of Energy – National Energy Technology Laboratory (US-DOE-NETL, 2012) and United States Geological Survey (Brennan et al., 2010); and (3) the peer-reviewed scientific community – Szulczewski et al. (2012) and Zhou et al. (2008). A statistical analysis of the estimates generated by multiple methods revealed that assessments of CO{sub 2} storage potential made at the prospective level were often statistically indistinguishable from each other, implying that the differences in methodologies are small with respect to the uncertainties in the geologic properties of storage rock in the absence of detailed site-specific characterization.

  19. Carbon sequestration monitoring with acoustic double-difference waveform inversion: A case study on SACROC walkaway VSP data

    SciTech Connect (OSTI)

    Huang, Lianjie [Los Alamos National Laboratory; Fehler, Michael [MIT; Malcolm, Alison [MIT; Yang, Di [MIT

    2011-01-01

    Geological carbon sequestration involves large-scale injection of carbon dioxide into underground geologic formations and is considered as a potential approach for mitigating global warming. Changes in reservoir properties resulting from the CO{sub 2} injection and migration can be characterized using waveform inversions of time-lapse seismic data. The conventional approach for analysis using waveform tomography is to take the difference of the images obtained using baseline and subsequent time-lapse datasets that are inverted independently. By contrast, double-difference waveform inversion uses timelapse seismic datasets to jointly invert for reservoir changes. We apply this method to a field time-lapse walkaway VSP data set acquired in 2008 and 2009 for monitoring CO{sub 2} injection at an enhanced oil recovery field at SACROC, Texas. The double-difference waveform inversion gives a cleaner and more easily interpreted image of reservoir changes, as compared to that obtained with the conventional scheme. Our results from the applicatoin of acoustic double-difference waveform tomography shows some zones with decreased P-wave velocity within the reservoir due to CO{sub 2} injection and migration.

  20. Marine transportation for Carbon Capture and Sequestration (CCS)

    E-Print Network [OSTI]

    Alexandrakis, Mary-Irene

    2010-01-01

    The objective of this report is to determine whether opportunities to use liquefied carbon dioxide carriers as part of a carbon capture and storage system will exist over the next twenty years. Factors that encourage or ...

  1. RESTORING SUSTAINABLE FORESTS ON APPALACHIAN MINED LANDS FOR WOOD PRODUCTS, RENEWABLE ENERGY, CARBON SEQUESTRATION, AND OTHER ECOSYSTEM SERVICES

    SciTech Connect (OSTI)

    J. Burger; J. Galbraith; T. Fox; G. Amacher; J. Sullivan; C. Zipper

    2003-12-18

    The overall purpose of this project is to evaluate the biological and economic feasibility of restoring high-quality forests on mined land, and to measure carbon sequestration and wood production benefits that would be achieved from forest restoration procedures. In this quarterly report, we present a preliminary comparison of the carbon sequestration benefits for two forest types used to convert abandoned grasslands for carbon sequestration. Annual mixed hardwood benefits, based on total stand carbon volume present at the end of a given year, range from a minimum of $0/ton of carbon to a maximum of $5.26/ton of carbon (low prices). White pine benefits based on carbon volume range from a minimum of $0/ton of carbon to a maximum of $18.61/ton of carbon (high prices). The higher maximum white pine carbon payment can primarily be attributed to the fact that the shorter rotation means that payments for white pine carbon are being made on far less cumulative carbon tonnage than for that of the long-rotation hardwoods. Therefore, the payment per ton of white pine carbon needs to be higher than that of the hardwoods in order to render the conversion to white pine profitable by the end of a rotation. These carbon payments may seem appealingly low to the incentive provider. However, payments (not discounted) made over a full rotation may add up to approximately $17,493/ha for white pine (30-year rotation), and $18,820/ha for mixed hardwoods (60-year rotation). The literature suggests a range of carbon sequestration costs, from $0/ton of carbon to $120/ton of carbon, although the majority of studies suggest a cost below $50/ ton of carbon, with van Kooten et al. (2000) suggesting a cutoff cost of $20/ton of carbon sequestered. Thus, the ranges of carbon payments estimated for this study fall well within the ranges of carbon sequestration costs estimated in previous studies.

  2. Comprehensive, Quantitative Risk Assessment of CO{sub 2} Geologic Sequestration

    SciTech Connect (OSTI)

    Lepinski, James

    2013-09-30

    A Quantitative Failure Modes and Effects Analysis (QFMEA) was developed to conduct comprehensive, quantitative risk assessments on CO{sub 2} capture, transportation, and sequestration or use in deep saline aquifers, enhanced oil recovery operations, or enhanced coal bed methane operations. The model identifies and characterizes potential risks; identifies the likely failure modes, causes, effects and methods of detection; lists possible risk prevention and risk mitigation steps; estimates potential damage recovery costs, mitigation costs and costs savings resulting from mitigation; and ranks (prioritizes) risks according to the probability of failure, the severity of failure, the difficulty of early failure detection and the potential for fatalities. The QFMEA model generates the necessary information needed for effective project risk management. Diverse project information can be integrated into a concise, common format that allows comprehensive, quantitative analysis, by a cross-functional team of experts, to determine: What can possibly go wrong? How much will damage recovery cost? How can it be prevented or mitigated? What is the cost savings or benefit of prevention or mitigation? Which risks should be given highest priority for resolution? The QFMEA model can be tailored to specific projects and is applicable to new projects as well as mature projects. The model can be revised and updated as new information comes available. It accepts input from multiple sources, such as literature searches, site characterization, field data, computer simulations, analogues, process influence diagrams, probability density functions, financial analysis models, cost factors, and heuristic best practices manuals, and converts the information into a standardized format in an Excel spreadsheet. Process influence diagrams, geologic models, financial models, cost factors and an insurance schedule were developed to support the QFMEA model. Comprehensive, quantitative risk assessments were conducted on three (3) sites using the QFMEA model: (1) SACROC Northern Platform CO{sub 2}-EOR Site in the Permian Basin, Scurry County, TX, (2) Pump Canyon CO{sub 2}-ECBM Site in the San Juan Basin, San Juan County, NM, and (3) Farnsworth Unit CO{sub 2}-EOR Site in the Anadarko Basin, Ochiltree County, TX. The sites were sufficiently different from each other to test the robustness of the QFMEA model.

  3. Chemical sensing and imaging in microfluidic pore network structures relevant to natural carbon cycling and industrial carbon sequestration

    SciTech Connect (OSTI)

    Grate, Jay W.; Zhang, Changyong; Wilkins, Michael J.; Warner, Marvin G.; Anheier, Norman C.; Suter, Jonathan D.; Kelly, Ryan T.; Oostrom, Martinus

    2013-06-11

    Energy and climate change represent significant factors in global security. Atmospheric carbon dioxide levels, while global in scope, are influenced by pore-scale phenomena in the subsurface. We are developing tools to visualize and investigate processes in pore network microfluidic structures with transparent covers as representations of normally-opaque porous media. In situ fluorescent oxygen sensing methods and fluorescent cellulosic materials are being used to investigate processes related to terrestrial carbon cycling involving cellulytic respiring microorganisms. These structures also enable visualization of water displacement from pore spaces by hydrophobic fluids, including carbon dioxide, in studies related to carbon sequestration.

  4. Carbon Dioxide-Water Emulsions for Enhanced Oil Recovery and Permanent Sequestration of Carbon Dioxide

    SciTech Connect (OSTI)

    Ryan, David; Golomb, Dan; Shi, Guang; Shih, Cherry; Lewczuk, Rob; Miksch, Joshua; Manmode, Rahul; Mulagapati, Srihariraju; Malepati, Chetankurmar

    2011-09-30

    This project involves the use of an innovative new invention ? Particle Stabilized Emulsions (PSEs) of Carbon Dioxide-in-Water and Water-in-Carbon Dioxide for Enhanced Oil Recovery (EOR) and Permanent Sequestration of Carbon Dioxide. The EOR emulsion would be injected into a semi-depleted oil reservoir such as Dover 33 in Otsego County, Michigan. It is expected that the emulsion would dislocate the stranded heavy crude oil from the rock granule surfaces, reduce its viscosity, and increase its mobility. The advancing emulsion front should provide viscosity control which drives the reduced-viscosity oil toward the production wells. The make-up of the emulsion would be subsequently changed so it interacts with the surrounding rock minerals in order to enhance mineralization, thereby providing permanent sequestration of the injected CO{sub 2}. In Phase 1 of the project, the following tasks were accomplished: 1. Perform laboratory scale (mL/min) refinements on existing procedures for producing liquid carbon dioxide-in-water (C/W) and water-in-liquid carbon dioxide (W/C) emulsion stabilized by hydrophilic and hydrophobic fine particles, respectively, using a Kenics-type static mixer. 2. Design and cost evaluate scaled up (gal/min) C/W and W/C emulsification systems to be deployed in Phase 2 at the Otsego County semi-depleted oil field. 3. Design the modifications necessary to the present CO{sub 2} flooding system at Otsego County for emulsion injection. 4. Design monitoring and verification systems to be deployed in Phase 2 for measuring potential leakage of CO{sub 2} after emulsion injection. 5. Design production protocol to assess enhanced oil recovery with emulsion injection compared to present recovery with neat CO{sub 2} flooding. 6. Obtain Federal and State permits for emulsion injection. Initial research focused on creating particle stabilized emulsions with the smallest possible globule size so that the emulsion can penetrate even low-permeability crude oilcontaining formations or saline aquifers. The term ?globule? refers to the water or liquid carbon dioxide droplets sheathed with ultrafine particles dispersed in the continuous external medium, liquid CO{sub 2} or H{sub 2}O, respectively. The key to obtaining very small globules is the shear force acting on the two intermixing fluids, and the use of ultrafine stabilizing particles or nanoparticles. We found that using Kenics-type static mixers with a shear rate in the range of 2700 to 9800 s{sup -1} and nanoparticles between 100-300 nm produced globule sizes in the 10 to 20 ?m range. Particle stabilized emulsions with that kind of globule size should easily penetrate oil-bearing formations or saline aquifers where the pore and throat size can be on the order of 50 ?m or larger. Subsequent research focused on creating particle stabilized emulsions that are deemed particularly suitable for Permanent Sequestration of Carbon Dioxide. Based on a survey of the literature an emulsion consisting of 70% by volume of water, 30% by volume of liquid or supercritical carbon dioxide, and 2% by weight of finely pulverized limestone (CaCO{sub 3}) was selected as the most promising agent for permanent sequestration of CO{sub 2}. In order to assure penetration of the emulsion into tight formations of sandstone or other silicate rocks and carbonate or dolomite rock, it is necessary to use an emulsion consisting of the smallest possible globule size. In previous reports we described a high shear static mixer that can create such small globules. In addition to the high shear mixer, it is also necessary that the emulsion stabilizing particles be in the submicron size, preferably in the range of 0.1 to 0.2 ?m (100 to 200 nm) size. We found a commercial source of such pulverized limestone particles, in addition we purchased under this DOE Project a particle grinding apparatus that can provide particles in the desired size range. Additional work focused on attempts to generate particle stabilized emulsions with a flow through, static mixer based apparatus under a variety

  5. Cost and U.S. public policy for new coal power plants with carbon capture and sequestration

    E-Print Network [OSTI]

    Hamilton, Michael R.

    This paper provides a financial analysis for new supercritical pulverized coal plants with carbon capture and sequestration (CCS) that compares the effects of two relevant climate policies. First, an updated cost estimate ...

  6. Past and Future Effects of Ozone on Net Primary Production and Carbon Sequestration Using a Global Biogeochemical Model

    E-Print Network [OSTI]

    Felzer, Benjamin Seth.

    Exposure of plants to ozone inhibits photosynthesis and therefore reduces vegetation production and carbon sequestration. Simulations with the Terrestrial Ecosystem Model (TEM) for the historical period (1860-1995) show ...

  7. NATIONAL CARBON SEQUESTRATION DATABASE AND GEOGRAPHIC INFORMATION SYSTEM (NATCARB) FORMER TITLE-MIDCONTINENT INTERACTIVE DIGITAL CARBON ATLAS AND RELATIONAL DATABASE (MIDCARB)

    SciTech Connect (OSTI)

    Timothy R. Carr

    2004-07-16

    This annual report describes progress in the third year of the three-year project entitled ''Midcontinent Interactive Digital Carbon Atlas and Relational Database (MIDCARB)''. The project assembled a consortium of five states (Indiana, Illinois, Kansas, Kentucky and Ohio) to construct an online distributed Relational Database Management System (RDBMS) and Geographic Information System (GIS) covering aspects of carbon dioxide (CO{sub 2}) geologic sequestration (http://www.midcarb.org). The system links the five states in the consortium into a coordinated regional database system consisting of datasets useful to industry, regulators and the public. The project has been extended and expanded as a ''NATional CARBon Sequestration Database and Geographic Information System (NATCARB)'' to provide national coverage across the Regional CO{sub 2} Partnerships, which currently cover 40 states (http://www.natcarb.org). Advanced distributed computing solutions link database servers across the five states and other publicly accessible servers (e.g., USGS) into a single system where data is maintained and enhanced at the local level but is accessed and assembled through a single Web portal and can be queried, assembled, analyzed and displayed. This project has improved the flow of data across servers and increased the amount and quality of available digital data. The online tools used in the project have improved in stability and speed in order to provide real-time display and analysis of CO{sub 2} sequestration data. The move away from direct database access to web access through eXtensible Markup Language (XML) has increased stability and security while decreasing management overhead. The MIDCARB viewer has been simplified to provide improved display and organization of the more than 125 layers and data tables that have been generated as part of the project. The MIDCARB project is a functional demonstration of distributed management of data systems that cross the boundaries between institutions and geographic areas. The MIDCARB system addresses CO{sub 2} sequestration and other natural resource issues from sources, sinks and transportation within a spatial database that can be queried online. Visualization of high quality and current data can assist decision makers by providing access to common sets of high quality data in a consistent manner.

  8. Characterization of Most Promising Sequestration Formations in the Rocky Mountain Region (RMCCS)

    SciTech Connect (OSTI)

    McPherson, Brian; Matthews, Vince

    2013-09-30

    The primary objective of the “Characterization of Most Promising Carbon Capture and Sequestration Formations in the Central Rocky Mountain Region” project, or RMCCS project, is to characterize the storage potential of the most promising geologic sequestration formations within the southwestern U.S. and the Central Rocky Mountain region in particular. The approach included an analysis of geologic sequestration formations under the Craig Power Station in northwestern Colorado, and application or extrapolation of those local-scale results to the broader region. A ten-step protocol for geologic carbon storage site characterization was a primary outcome of this project.

  9. Research Experience in Carbon Sequestration 2015 Now Accepting...

    Energy Savers [EERE]

    professionals can gain hands-on field research experience in areas related to carbon capture, utilization and storage (CCUS) by participating in the Research Experience in...

  10. Evaluation of Experimentally Measured and Model-Calculated pH for Rock-Brine-CO2 Systems under Geologic CO2 Sequestration Conditions

    SciTech Connect (OSTI)

    Shao, Hongbo; Thompson, Christopher J.; Cantrell, Kirk J.

    2013-11-14

    Reliable pH estimation is essential for understanding the geochemical reactions that occur in rock-brine-CO2 systems when CO2 is injected into deep geologic formations for long-term storage. Due to a lack of reliable experimental methods, most laboratory studies of formation reactivities conducted under geologic CO2 sequestration (GCS) conditions have relied on thermodynamic modeling to estimate pH; however, the accuracy of these model predictions is typically uncertain. In this study, we expanded the measurement range of a spectrophotometric method for pH determination, and we applied the method to measure the pH in batch-reactor experiments utilizing rock samples from five ongoing GCS demonstration projects. A combination of color-changing pH indicators, bromophenol blue and bromocresol green, was shown to enable measurements over the pH range of 2.5-5.2. In-situ pH measurements were compared with pH values calculated using geochemical models. The effect of different thermodynamic databases on the accuracy of model prediction was evaluated. For rocks comprised of carbonate, siltstone, and sandstone, model results generally agreed well with experimentally measured pH; however, for basalt, significant differences were observed. These discrepancies may be due to the models’ failure to fully account for certain proton consuming and producing reactions that occur between the basalt minerals and CO2-saturated brine solutions.

  11. Evaluation of experimentally measured and model-calculated pH for rock-brine-CO2 systems under geologic CO2 sequestration conditions

    SciTech Connect (OSTI)

    Shao, Hongbo; Thompson, Christopher J.; Cantrell, Kirk J.

    2013-11-01

    pH is an essential parameter for understanding the geochemical reactions that occur in rock-brine-CO2 systems when CO2 is injected into deep geologic formations for long-term storage. Due to a lack of reliable experimental methods, most laboratory studies conducted under geological CO2 sequestration (GCS) conditions have relied on thermodynamic modeling to estimate pH. The accuracy of these model predictions is typically uncertain. In our previous work, we have developed a method for pH determination by in-situ spectrophotometry. In the present work, we expanded the applicable pH range for this method and measured the pH of several rock-brine-CO2 systems at GCS conditions for five rock samples collected from ongoing GCS demonstration projects. Experimental measurements were compared with pH values calculated using several geochemical modeling approaches. The effect of different thermodynamic databases on the accuracy of model prediction was evaluated. Results indicate that the accuracy of model calculations is rock-dependent. For rocks comprised of carbonate and sandstone, model results generally agreed well with experimentally measured pH; however, for basalt, significant differences were observed. These discrepancies may be due to the models’ failure to fully account for certain reaction occurring between the basalt minerals the CO2-saturated brine solutions.

  12. Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration

    SciTech Connect (OSTI)

    Bill Stanley; Sandra Brown; Patrick Gonzalez; Brent Sohngen; Neil Sampson; Mark Anderson; Miguel Calmon; Sean Grimland; Ellen Hawes; Zoe Kant; Dan Morse; Sarah Woodhouse Murdock; Arlene Olivero; Tim Pearson; Sarah Walker; Jon Winsten; Chris Zganjar

    2006-09-30

    The Nature Conservancy is participating in a Cooperative Agreement with the Department of Energy (DOE) National Energy Technology Laboratory (NETL) to explore the compatibility of carbon sequestration in terrestrial ecosystems and the conservation of biodiversity. The title of the research project is ''Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration''. The objectives of the project are to: (1) improve carbon offset estimates produced in both the planning and implementation phases of projects; (2) build valid and standardized approaches to estimate project carbon benefits at a reasonable cost; and (3) lay the groundwork for implementing cost-effective projects, providing new testing ground for biodiversity protection and restoration projects that store additional atmospheric carbon. This Technical Progress Report discusses preliminary results of the six specific tasks that The Nature Conservancy is undertaking to answer research needs while facilitating the development of real projects with measurable greenhouse gas reductions. The research described in this report occurred between April 1st and July 30th 2006. The specific tasks discussed include: Task 1: carbon inventory advancements; Task 2: emerging technologies for remote sensing of terrestrial carbon; Task 3: baseline method development; Task 4: third-party technical advisory panel meetings; Task 5: new project feasibility studies; and Task 6: development of new project software screening tool.

  13. Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration

    SciTech Connect (OSTI)

    Bill Stanley; Sandra Brown; Patrick Gonzalez; Brent Sohngen; Neil Sampson; Mark Anderson; Miguel Calmon; Sean Grimland; Zoe Kant; Dan Morse; Sarah Woodhouse Murdock; Arlene Olivero; Tim Pearson; Sarah Walker; Jon Winsten; Chris Zganjar

    2007-03-31

    The Nature Conservancy is participating in a Cooperative Agreement with the Department of Energy (DOE) National Energy Technology Laboratory (NETL) to explore the compatibility of carbon sequestration in terrestrial ecosystems and the conservation of biodiversity. The title of the research project is ''Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration''. The objectives of the project are to: (1) improve carbon offset estimates produced in both the planning and implementation phases of projects; (2) build valid and standardized approaches to estimate project carbon benefits at a reasonable cost; and (3) lay the groundwork for implementing cost-effective projects, providing new testing ground for biodiversity protection and restoration projects that store additional atmospheric carbon. This Technical Progress Report discusses preliminary results of the six specific tasks that The Nature Conservancy is undertaking to answer research needs while facilitating the development of real projects with measurable greenhouse gas reductions. The research described in this report occurred between January 1st and March 31st 2007. The specific tasks discussed include: Task 1--carbon inventory advancements; Task 2--emerging technologies for remote sensing of terrestrial carbon; Task 3--baseline method development; Task 4--third-party technical advisory panel meetings; Task 5--new project feasibility studies; and Task 6--development of new project software screening tool.

  14. Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration

    SciTech Connect (OSTI)

    Bill Stanley; Sandra Brown; Patrick Gonzalez; Brent Sohngen; Neil Sampson; Mark Anderson; Miguel Calmon; Sean Grimland; Zoe Kant; Dan Morse; Sarah Woodhouse Murdock; Arlene Olivero; Tim Pearson; Sarah Walker; Jon Winsten; Chris Zganjar

    2006-12-31

    The Nature Conservancy is participating in a Cooperative Agreement with the Department of Energy (DOE) National Energy Technology Laboratory (NETL) to explore the compatibility of carbon sequestration in terrestrial ecosystems and the conservation of biodiversity. The title of the research project is ''Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration''. The objectives of the project are to: (1) improve carbon offset estimates produced in both the planning and implementation phases of projects; (2) build valid and standardized approaches to estimate project carbon benefits at a reasonable cost; and (3) lay the groundwork for implementing cost-effective projects, providing new testing ground for biodiversity protection and restoration projects that store additional atmospheric carbon. This Technical Progress Report discusses preliminary results of the six specific tasks that The Nature Conservancy is undertaking to answer research needs while facilitating the development of real projects with measurable greenhouse gas reductions. The research described in this report occurred between October 1st and December 31st 2006. The specific tasks discussed include: Task 1: carbon inventory advancements; Task 2: emerging technologies for remote sensing of terrestrial carbon; Task 3: baseline method development; Task 4: third-party technical advisory panel meetings; Task 5: new project feasibility studies; and Task 6: development of new project software screening tool.

  15. Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration

    SciTech Connect (OSTI)

    Bill Stanley; Patrick Gonzalez; Sandra Brown; Jenny Henman; Zoe Kant; Sarah Woodhouse Murdock; Neil Sampson; Gilberto Tiepolo; Tim Pearson; Sarah Walker; Miguel Calmon

    2006-01-01

    The Nature Conservancy is participating in a Cooperative Agreement with the Department of Energy (DOE) National Energy Technology Laboratory (NETL) to explore the compatibility of carbon sequestration in terrestrial ecosystems and the conservation of biodiversity. The title of the research project is ''Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration''. The objectives of the project are to: (1) improve carbon offset estimates produced in both the planning and implementation phases of projects; (2) build valid and standardized approaches to estimate project carbon benefits at a reasonable cost; and (3) lay the groundwork for implementing cost-effective projects, providing new testing ground for biodiversity protection and restoration projects that store additional atmospheric carbon. This Technical Progress Report discusses preliminary results of the six specific tasks that The Nature Conservancy is undertaking to answer research needs while facilitating the development of real projects with measurable greenhouse gas reductions. The research described in this report occurred between April 1st , 2005 and June 30th, 2005. The specific tasks discussed include: Task 1: carbon inventory advancements; Task 2: emerging technologies for remote sensing of terrestrial carbon; Task 3: baseline method development; Task 4: third-party technical advisory panel meetings; Task 5: new project feasibility studies; and Task 6: development of new project software screening tool.

  16. Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration

    SciTech Connect (OSTI)

    Bill Stanley; Sandra Brown; Patrick Gonzalez; Zoe Kant; Gilberto Tiepolo; Wilber Sabido; Ellen Hawes; Jenny Henman; Miguel Calmon; Michael Ebinger

    2004-07-10

    The Nature Conservancy is participating in a Cooperative Agreement with the Department of Energy (DOE) National Energy Technology Laboratory (NETL) to explore the compatibility of carbon sequestration in terrestrial ecosystems and the conservation of biodiversity. The title of the research project is ''Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration''. The objectives of the project are to: (1) improve carbon offset estimates produced in both the planning and implementation phases of projects; (2) build valid and standardized approaches to estimate project carbon benefits at a reasonable cost; and (3) lay the groundwork for implementing cost-effective projects, providing new testing ground for biodiversity protection and restoration projects that store additional atmospheric carbon. This Technical Progress Report discusses preliminary results of the six specific tasks that The Nature Conservancy is undertaking to answer research needs while facilitating the development of real projects with measurable greenhouse gas impacts. The research described in this report occurred between July 1, 2002 and June 30, 2003. The specific tasks discussed include: Task 1: carbon inventory advancements; Task 2: remote sensing for carbon analysis; Task 3: baseline method development; Task 4: third-party technical advisory panel meetings; Task 5: new project feasibility studies; and Task 6: development of new project software screening tool.

  17. Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration

    SciTech Connect (OSTI)

    Bill Stanley; Patrick Gonzalez; Sandra Brown; Sarah Woodhouse Murdock; Jenny Henman; Zoe Kant; Gilberto Tiepolo; Tim Pearson; Neil Sampson; Miguel Calmon

    2005-10-01

    The Nature Conservancy is participating in a Cooperative Agreement with the Department of Energy (DOE) National Energy Technology Laboratory (NETL) to explore the compatibility of carbon sequestration in terrestrial ecosystems and the conservation of biodiversity. The title of the research project is ''Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration''. The objectives of the project are to: (1) improve carbon offset estimates produced in both the planning and implementation phases of projects; (2) build valid and standardized approaches to estimate project carbon benefits at a reasonable cost; and (3) lay the groundwork for implementing cost-effective projects, providing new testing ground for biodiversity protection and restoration projects that store additional atmospheric carbon. This Technical Progress Report discusses preliminary results of the six specific tasks that The Nature Conservancy is undertaking to answer research needs while facilitating the development of real projects with measurable greenhouse gas reductions. The research described in this report occurred between April 1st , 2005 and June 30th, 2005. The specific tasks discussed include: Task 1: carbon inventory advancements; Task 2: emerging technologies for remote sensing of terrestrial carbon; Task 3: baseline method development; Task 4: third-party technical advisory panel meetings; Task 5: new project feasibility studies; and Task 6: development of new project software screening tool.

  18. Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration

    SciTech Connect (OSTI)

    Bill Stanley; Patrick Gonzalez; Sandra Brown; Jenny Henman; Sarah Woodhouse Murdock; Neil Sampson; Tim Pearson; Sarah Walker; Zoe Kant; Miguel Calmon

    2006-04-01

    The Nature Conservancy is participating in a Cooperative Agreement with the Department of Energy (DOE) National Energy Technology Laboratory (NETL) to explore the compatibility of carbon sequestration in terrestrial ecosystems and the conservation of biodiversity. The title of the research project is ''Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration''. The objectives of the project are to: (1) improve carbon offset estimates produced in both the planning and implementation phases of projects; (2) build valid and standardized approaches to estimate project carbon benefits at a reasonable cost; and (3) lay the groundwork for implementing cost-effective projects, providing new testing ground for biodiversity protection and restoration projects that store additional atmospheric carbon. This Technical Progress Report discusses preliminary results of the six specific tasks that The Nature Conservancy is undertaking to answer research needs while facilitating the development of real projects with measurable greenhouse gas reductions. The research described in this report occurred between January 1st and March 31st 2006. The specific tasks discussed include: Task 1: carbon inventory advancements; Task 2: emerging technologies for remote sensing of terrestrial carbon; Task 3: baseline method development; Task 4: third-party technical advisory panel meetings; Task 5: new project feasibility studies; and Task 6: development of new project software screening tool.

  19. GENOME-ENABLED DISCOVERY OF CARBON SEQUESTRATION GENES IN POPLAR

    SciTech Connect (OSTI)

    DAVIS J M

    2007-10-11

    Plants utilize carbon by partitioning the reduced carbon obtained through photosynthesis into different compartments and into different chemistries within a cell and subsequently allocating such carbon to sink tissues throughout the plant. Since the phytohormones auxin and cytokinin are known to influence sink strength in tissues such as roots (Skoog & Miller 1957, Nordstrom et al. 2004), we hypothesized that altering the expression of genes that regulate auxin-mediated (e.g., AUX/IAA or ARF transcription factors) or cytokinin-mediated (e.g., RR transcription factors) control of root growth and development would impact carbon allocation and partitioning belowground (Fig. 1 - Renewal Proposal). Specifically, the ARF, AUX/IAA and RR transcription factor gene families mediate the effects of the growth regulators auxin and cytokinin on cell expansion, cell division and differentiation into root primordia. Invertases (IVR), whose transcript abundance is enhanced by both auxin and cytokinin, are critical components of carbon movement and therefore of carbon allocation. Thus, we initiated comparative genomic studies to identify the AUX/IAA, ARF, RR and IVR gene families in the Populus genome that could impact carbon allocation and partitioning. Bioinformatics searches using Arabidopsis gene sequences as queries identified regions with high degrees of sequence similarities in the Populus genome. These Populus sequences formed the basis of our transgenic experiments. Transgenic modification of gene expression involving members of these gene families was hypothesized to have profound effects on carbon allocation and partitioning.

  20. EA-1835: Midwest Regional Carbon Sequestration Partnership (MRCSP) Phase II Michigan Basin Project in Chester Township, Michigan

    Broader source: Energy.gov [DOE]

    NOTE: This EA has been cancelled. This EA will evaluate the environmental impacts of a proposal to provide approximately $65.5 million in financial assistance in a cost-sharing arrangement with the project proponent, MRCSP. MRCSP's proposed project would use CO2 captured from an existing natural gas processing plant in Chester Township, pipe it approximately 1 mile to an injection well, and inject it into a deep saline aquifer for geologic sequestration. This project would demonstrate the geologic sequestration of 1,000,000 metric tons of CO2 over a 4-year period. The project and EA are on hold.

  1. Development of a coupled thermo-hydro-mechanical model in discontinuous media for carbon sequestration

    SciTech Connect (OSTI)

    Fang, Yilin; Nguyen, Ba Nghiep; Carroll, Kenneth C.; Xu, Zhijie; Yabusaki, Steven B.; Scheibe, Timothy D.; Bonneville, Alain

    2013-09-12

    Geomechanical alteration of porous media is generally ignored for most shallow subsurface applications, whereas CO2 injection, migration, and trapping in deep saline aquifers will be controlled by coupled multifluid flow, energy transfer, and geomechanical processes. The accurate assessment of the risks associated with potential leakage of injected CO2 and the design of effective injection systems requires that we represent these coupled processes within numerical simulators. The objectives of this study were to develop a coupled thermal-hydro-mechanical model into a single software, and to examine the coupling of thermal, hydrological, and geomechanical processes for simulation of CO2 injection into the subsurface for carbon sequestration. A numerical model is developed to couple nonisothermal multiphase hydrological and geomechanical processes for prediction of multiple interconnected processes for carbon sequestration in deep saline aquifers. The geomechanics model was based on Rigid Body-Spring Model (RBSM), one of the discrete methods to model discontinuous rock system. Poisson’s effect that was often ignored by RBSM was considered in the model. The simulation of large-scale and long-term coupled processes in carbon capture and storage projects requires large memory and computational performance. Global Array Toolkit was used to build the model to permit the high performance simulations of the coupled processes. The model was used to simulate a case study with several scenarios to demonstrate the impacts of considering coupled processes and Poisson’s effect for the prediction of CO2 sequestration.

  2. Lake Charles Carbon Capture and Sequestration Project U. S. Department...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    plant will not receive co-funding from DOE. The Lake Charles CCS Project will capture carbon dioxide (CO 2 ) from the LCCE Gasification plant and transport the CO 2 via a new...

  3. THE APPLICATION AND DEVELOPMENT OF APPROPRIATE TOOLS AND TECHNOLOGIES FOR COST-EFFECTIVE CARBON SEQUESTRATION

    SciTech Connect (OSTI)

    Bill Stanley; Sandra Brown; Ellen Hawes; Zoe Kant; Miguel Calmon; Gilberto Tiepolo

    2002-09-01

    The Nature Conservancy is participating in a Cooperative Agreement with the Department of Energy (DOE) National Energy Technology Laboratory (NETL) to explore the compatibility of carbon sequestration in terrestrial ecosystems and the conservation of biodiversity. The title of the research projects is ''Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration''. The objectives of the project are to: (1) improve carbon offset estimates produced in both the planning and implementation phases of projects; (2) build valid and standardized approaches to estimate project carbon benefits at a reasonable cost; and (3) lay the groundwork for implementing cost-effective projects, providing new testing ground for biodiversity protection and restoration projects that store additional atmospheric carbon. This Technical Progress Report discusses preliminary results of the six specific tasks that The Nature Conservancy is undertaking to answer research needs while facilitating the development of real projects with measurable greenhouse gas impacts. The specific tasks discussed include: Task 1: carbon inventory advancements; Task 2: advanced videography testing; Task 3: baseline method development; Task 4: third-party technical advisory panel meetings; Task 5: new project feasibility studies; and Task 6: development of new project software screening tool.

  4. Development Of An Agroforestry Sequestration Project In Khammam District Of India

    E-Print Network [OSTI]

    Sudha, P.; Ramprasad, V.; Nagendra, M.D.V.; Kulkarni, H.D.; Ravindranath, N.H.

    2007-01-01

    in estimating carbon sequestration potential, baselineA, Kandji, ST, (2003) Carbon sequestration in tropicalStudies on enhancing carbon sequestration in soils. Energy,

  5. Development of a Software Framework for System-Level Carbon Sequestration Risk Assessment

    SciTech Connect (OSTI)

    Miller, R.

    2013-02-28

    The overall purpose of this project was to identify, evaluate, select, develop, and test a suite of enhancements to the GoldSim software program, in order to make it a better tool for use in support of Carbon Capture and Sequestration (CCS) projects. The GoldSim software is a foundational tool used by scientists at NETL and at other laboratories and research institutions to evaluate system-level risks of proposed CCS projects. The primary product of the project was a series of successively improved versions of the GoldSim software, supported by an extensive User’s Guide. All of the enhancements were tested by scientists at Los Alamos National Laboratory, and several of the enhancements have already been incorporated into the CO{sub 2}-PENS sequestration model.

  6. The Water, Energy, and Carbon Dioxide Sequestration Simulation Model (WECSsim). A user's manual

    SciTech Connect (OSTI)

    Kobos, Peter Holmes; Roach, Jesse Dillon; Klise, Geoffrey Taylor; Heath, Jason E.; Dewers, Thomas A.; Gutierrez, Karen A.; Malczynski, Leonard A.; Borns, David James; McNemar, Andrea

    2014-01-01

    The Water, Energy, and Carbon Sequestration Simulation Model (WECSsim) is a national dynamic simulation model that calculates and assesses capturing, transporting, and storing CO2 in deep saline formations from all coal and natural gas-fired power plants in the U.S. An overarching capability of WECSsim is to also account for simultaneous CO2 injection and water extraction within the same geological saline formation. Extracting, treating, and using these saline waters to cool the power plant is one way to develop more value from using saline formations as CO2 storage locations. WECSsim allows for both one-to-one comparisons of a single power plant to a single saline formation along with the ability to develop a national CO2 storage supply curve and related national assessments for these formations. This report summarizes the scope, structure, and methodology of WECSsim along with a few key results. Developing WECSsim from a small scoping study to the full national-scale modeling effort took approximately 5 years. This report represents the culmination of that effort. The key findings from the WECSsim model indicate the U.S. has several decades' worth of storage for CO2 in saline formations when managed appropriately. Competition for subsurface storage capacity, intrastate flows of CO2 and water, and a supportive regulatory environment all play a key role as to the performance and cost profile across the range from a single power plant to all coal and natural gas-based plants' ability to store CO2. The overall system's cost to capture, transport, and store CO2 for the national assessment range from $74 to $208 / tonne stored ($96 to 272 / tonne avoided) for the first 25 to 50% of the 1126 power plants to between $1,585 to well beyond $2,000 / tonne stored ($2,040 to well beyond $2,000 / tonne avoided) for the remaining 75 to 100% of the plants. The latter range, while extremely large, includes all natural gas power plants in the U.S., many of which have an extremely low capacity factor and therefore relatively high system's cost to capture and store CO2.

  7. Method for carbon dioxide sequestration (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(JournalspectroscopyReport) | SciTechelementPatent:subsectionsMethod for carbon dioxide

  8. CALMIT Remote-Sensing Research Relating to Carbon Sequestration There is considerable interest in assessing the magnitude of carbon sources and sinks in terrestrial

    E-Print Network [OSTI]

    Nebraska-Lincoln, University of

    CALMIT Remote-Sensing Research Relating to Carbon Sequestration There is considerable interest in assessing the magnitude of carbon sources and sinks in terrestrial ecosystems using remote sensing techniques. We developed a novel technique to remotely assess carbon dioxide exchange in maize using

  9. Plant and Soil-Based Carbon Sequestration in Urban Areas Objective: Investigate current research into plant and soil carbon storage capacities,

    E-Print Network [OSTI]

    Wolberg, George

    Plant and Soil-Based Carbon Sequestration in Urban Areas Objective: Investigate current research into plant and soil carbon storage capacities, perform an urban land assessment in terms of these capacities matter in soils, as a result of accumulation of plant litter and other biomass. Indeed, carbon in soil

  10. Validation and Comparison of Carbon Sequestration Project Cost Models with Project Cost Data Obtained from the Southwest Partnership

    SciTech Connect (OSTI)

    Robert Lee; Reid Grigg; Brian McPherson

    2011-04-15

    Obtaining formal quotes and engineering conceptual designs for carbon dioxide (CO{sub 2}) sequestration sites and facilities is costly and time-consuming. Frequently, when looking at potential locations, managers, engineers and scientists are confronted with multiple options, but do not have the expertise or the information required to quickly obtain a general estimate of what the costs will be without employing an engineering firm. Several models for carbon compression, transport and/or injection have been published that are designed to aid in determining the cost of sequestration projects. A number of these models are used in this study, including models by J. Ogden, MIT's Carbon Capture and Sequestration Technologies Program Model, the Environmental Protection Agency and others. This report uses the information and data available from several projects either completed, in progress, or conceptualized by the Southwest Regional Carbon Sequestration Partnership on Carbon Sequestration (SWP) to determine the best approach to estimate a project's cost. The data presented highlights calculated versus actual costs. This data is compared to the results obtained by applying several models for each of the individual projects with actual cost. It also offers methods to systematically apply the models to future projects of a similar scale. Last, the cost risks associated with a project of this scope are discussed, along with ways that have been and could be used to mitigate these risks.

  11. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2005-04-26

    Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples were acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton. There is a direct correlation between measured total organic carbon content and the adsorptive capacity of the shale; CO{sub 2} adsorption capacity increases with increasing organic carbon content. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

  12. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2005-07-29

    Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples were acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton. There is a direct correlation between measured total organic carbon content and the adsorptive capacity of the shale; CO{sub 2} adsorption capacity increases with increasing organic carbon content. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

  13. ANALYSIS OF DEVONIAN BLACK SHALES IN KENTUCKY FOR POTENTIAL CARBON DIOXIDE SEQUESTRATION AND ENHANCED NATURAL GAS PRODUCTION

    SciTech Connect (OSTI)

    Brandon C. Nuttall

    2005-01-28

    Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples were acquired to investigate CO{sub 2} displacement of methane. An elemental capture spectroscopy log was acquired to investigate possible correlations between adsorption capacity and mineralogy. Average random vitrinite reflectance data range from 0.78 to 1.59 (upper oil to wet gas and condensate hydrocarbon maturity range). Total organic content determined from acid-washed samples ranges from 0.69 to 14 percent. CO{sub 2} adsorption capacities at 400 psi range from a low of 14 scf/ton in less organic-rich zones to more than 136 scf/ton. There is a direct correlation between measured total organic carbon content and the adsorptive capacity of the shale; CO{sub 2} adsorption capacity increases with increasing organic carbon content. Initial estimates based on these data indicate a sequestration capacity of 5.3 billion tons of CO{sub 2} in the Lower Huron Member of the Ohio Shale of eastern Kentucky and as much as 28 billion tons total in the deeper and thicker parts of the Devonian shales in Kentucky. Should the black shales of Kentucky prove to be a viable geologic sink for CO{sub 2}, their extensive occurrence in Paleozoic basins across North America would make them an attractive regional target for economic CO{sub 2} storage and enhanced natural gas production.

  14. Shedding light on carbon-mineral complexation in the soil environment: impacts on C sequestration and cycling

    E-Print Network [OSTI]

    Sparks, Donald L.

    42 Shedding light on carbon-mineral complexation in the soil environment: impacts on C sequestration and cycling Sparks, D.L. & C. Chen Department of Plant and Soil Sciences and Delaware@udel.edu) Abstract Organic matter (OM)-mineral complexation plays a critical role in soil carbon (C) stabilization

  15. The subsurface fluid mechanics of geologic carbon dioxide storage

    E-Print Network [OSTI]

    Szulczewski, Michael Lawrence

    2013-01-01

    In carbon capture and storage (CCS), CO? is captured at power plants and then injected into deep geologic reservoirs for long-term storage. While CCS may be critical for the continued use of fossil fuels in a carbon-constrained ...

  16. RECS student sequestration program

    SciTech Connect (OSTI)

    NONE

    2007-12-31

    The 2007 Research Experiment in Carbon Sequestration (RECS) met at the Montana State University (MSU) and a variety of field sites over the 10-day period of July 29 - Aug 10. This year's group consisted of 17 students from graduate and doctoral programs in the United States and Canada, as well as early career professionals in fields related to carbon mitigation. Appropriately, because greenhouse gas reduction and storage is a global problem, the group included seven international students, from France, Iran, Paraguay, Turkey, Russia and India. Classroom talks featured experts from academia, government, national laboratories, and the private sector, who discussed carbon capture and storage technologies and related policy issues. Then, students traveled to Colstrip, Montana to visit PPL Montana's coal-fired power plant and view the local geology along the Montana/Wyoming border. Finally, students spent several days in the hands-on work at ZERT, using carbon dioxide detection and monitoring equipment. 1 photo.

  17. Feasibility of Geophysical Monitoring of Carbon-Sequestrated Deep Saline Aquifers

    SciTech Connect (OSTI)

    Mallick, Subhashis; Alvarado, Vladimir

    2013-09-30

    As carbon dioxide (CO{sub 2}) is sequestered from the bottom of a brine reservoir and allowed to migrate upward, the effects of the relative permeability hysteresis due to capillary trapping and buoyancy driven migration tend to make the reservoir patchy saturated with different fluid phases over time. Seismically, such a patchy saturated reservoir induces an effective anisotropic behavior whose properties are primarily dictated by the nature of the saturation of different fluid phases in the pores and the elastic properties of the rock matrix. By combining reservoir flow simulation and modeling with seismic modeling, it is possible to derive these effective anisotropic properties, which, in turn, could be related to the saturation of CO{sub 2} within the reservoir volume any time during the post-injection scenario. Therefore, if time-lapse seismic data are available and could be inverted for the effective anisotropic properties of the reservoir, they, in combination with reservoir simulation could potentially predict the CO{sub 2} saturation directly from the time-lapse seismic data. It is therefore concluded that the time-lapse seismic data could be used to monitor the carbon sequestrated saline reservoirs. But for its successful implementation, seismic modeling and inversion methods must be integrated with the reservoir simulations. In addition, because CO{sub 2} sequestration induces an effective anisotropy in the sequestered reservoir and anisotropy is best detected using multicomponent seismic data compared to single component (P-wave) data, acquisition, processing, and analysis is multicomponent seismic data is recommended for these time-lapse studies. Finally, a successful implementation of using time-lapse seismic data for monitoring the carbon sequestrated saline reservoirs will require development of a robust methodology for inverting multicomponent seismic data for subsurface anisotropic properties.

  18. Carbon Nanotube Membranes: Carbon Nanotube Membranes for Energy-Efficient Carbon Sequestration

    SciTech Connect (OSTI)

    2010-03-01

    Broad Funding Opportunity Announcement Project: Porifera is developing carbon nanotube membranes that allow more efficient removal of CO2 from coal plant exhaust. Most of today’s carbon capture methods use chemical solvents, but capture methods that use membranes to draw CO2 out of exhaust gas are potentially more efficient and cost effective. Traditionally, membranes are limited by the rate at which they allow gas to flow through them and the amount of CO2 they can attract from the gas. Smooth support pores and the unique structure of Porifera’s carbon nanotube membranes allows them to be more permeable than other polymeric membranes, yet still selective enough for CO2 removal. This approach could overcome the barriers facing membrane-based approaches for capturing CO2 from coal plant exhausts.

  19. Feasibility Study of Carbon Sequestration Through Reforestation in the Chesapeake Bay Watershed of Virginia

    SciTech Connect (OSTI)

    Andy Lacatell; David Shoch; Bill Stanley; Zoe Kant

    2007-03-01

    The Chesapeake Rivers conservation area encompasses approximately 2,000 square miles of agricultural and forest lands in four Virginia watersheds that drain to the Chesapeake Bay. Consulting a time series of classified Landsat imagery for the Chesapeake Rivers conservation area, the project team developed a GIS-based protocol for identifying agricultural lands that could be reforested, specifically agricultural lands that had been without forest since 1990. Subsequent filters were applied to the initial candidate reforestation sites, including individual sites > 100 acres and sites falling within TNC priority conservation areas. The same data were also used to produce an analysis of baseline changes in forest cover within the study period. The Nature Conservancy and the Virginia Department of Forestry identified three reforestation/management models: (1) hardwood planting to establish old-growth forest, (2) loblolly pine planting to establish working forest buffer with hardwood planting to establish an old-growth core, and (3) loblolly pine planting to establish a working forest. To assess the relative carbon sequestration potential of these different strategies, an accounting of carbon and total project costs was completed for each model. Reforestation/management models produced from 151 to 171 tons carbon dioxide equivalent per acre over 100 years, with present value costs of from $2.61 to $13.28 per ton carbon dioxide equivalent. The outcome of the financial analysis was especially sensitive to the land acquisition/conservation easement cost, which represented the most significant, and also most highly variable, single cost involved. The reforestation/management models explored all require a substantial upfront investment prior to the generation of carbon benefits. Specifically, high land values represent a significant barrier to reforestation projects in the study area, and it is precisely these economic constraints that demonstrate the economic additionality of any carbon benefits produced via reforestation--these are outcomes over and above what is currently possible given existing market opportunities. This is reflected and further substantiated in the results of the forest cover change analysis, which demonstrated a decline in area of land in forest use in the study area for the 1987/88-2001 period. The project team collected data necessary to identify sites for reforestation in the study area, environmental data for the determining site suitability for a range of reforestation alternatives and has identified and addressed potential leakage and additionality issues associated with implementing a carbon sequestration project in the Chesapeake Rivers Conservation Area. Furthermore, carbon emissions reductions generated would have strong potential for recognition in existing reporting systems such as the U.S. Department of Energy 1605(b) voluntary reporting requirements and the Chicago Climate Exchange. The study identified 384,398 acres on which reforestation activities could potentially be sited. Of these candidate sites, sites totaling 26,105 acres are an appropriate size for management (> 100 acres) and located in priority conservation areas identified by The Nature Conservancy. Total carbon sequestration potential of reforestation in the study area, realized over a 100 year timeframe, ranges from 58 to 66 million tons of carbon dioxide equivalent, and on the priority sites alone, potential for carbon sequestration approaches or exceeds 4 million tons of carbon dioxide equivalent. In the absence of concerted reforestation efforts, coupled with policy strategies, the region will likely face continued declines in forest land.

  20. 2013 Carbon Management Research Symposium

    E-Print Network [OSTI]

    . BACKGROUND · As a first step towards developing risk assessment strategies for carbon sequestration projects2013 Carbon Management Research Symposium Effects of Formation Heterogeneity on CO2 Gas Phase Attenuation in the Shallow Subsurface During Possible Leakage from Geologic Sequestration Sites Michael

  1. 5, 15111543, 2008 sequestration in

    E-Print Network [OSTI]

    Boyer, Edmond

    , cloud cover and carbon sequestration. As well, we develop a procedure to convert carbon stock changes closure, carbon sequestration rate among other factors. The sensitivity of the model is investigated that the change in albedo reduces the carbon sequestration bene- fits by approximately 30% over 100 years

  2. Jointly Estimating Carbon Sequestration Supply from Forests and Agriculture Bruce A. McCarl (mccarl@tamu.edu, 979-845-1706)

    E-Print Network [OSTI]

    McCarl, Bruce A.

    Jointly Estimating Carbon Sequestration Supply from Forests and Agriculture Bruce A. McCarl (mccarl at Western Economics Association Meetings, July 5-8, 2001, San Francisco #12;2 Jointly Estimating Carbon Sequestration Supply from Forests and Agriculture Alterations in agricultural and forestry (AF) land use and

  3. Development of a Method for Measuring Carbon Balance in Chemical Sequestration of CO2

    SciTech Connect (OSTI)

    Cheng, Zhongxian; Pan, Wei-Ping; Riley, John T.

    2006-09-09

    Anthropogenic CO2 released from fossil fuel combustion is a primary greenhouse gas which contributes to “global warming.” It is estimated that stationary power generation contributes over one-third of total CO2 emissions. Reducing CO2 in the atmosphere can be accomplished either by decreasing the rate at which CO2 is emitted into the atmosphere or by increasing the rate at which it is removed from it. Extensive research has been conducted on determining a fast and inexpensive method to sequester carbon dioxide. These methods can be classified into two categories, CO2 fixation by natural sink process for CO2, or direct CO2 sequestration by artificial processes. In direct sequestration, CO2 produced from sources such as coal-fired power plants, would be captured from the exhausted gases. CO2 from a combustion exhaust gas is absorbed with an aqueous ammonia solution through scrubbing. The captured CO2 is then used to synthesize ammonium bicarbonate (ABC or NH4HCO3), an economical source of nitrogen fertilizer. In this work, we studied the carbon distribution after fertilizer is synthesized from CO2. The synthesized fertilizer in laboratory is used as a “CO2 carrier” to “transport” CO2 from the atmosphere to crops. After biological assimilation and metabolism in crops treated with ABC, a considerable amount of the carbon source is absorbed by the plants with increased biomass production. The majority of the unused carbon source percolates into the soil as carbonates, such as calcium carbonate (CaCO3) and magnesium carbonate (MgCO3). These carbonates are environmentally benign. As insoluble salts, they are found in normal rocks and can be stored safely and permanently in soil. This investigation mainly focuses on the carbon distribution after the synthesized fertilizer is applied to soil. Quantitative examination of carbon distribution in an ecosystem is a challenging task since the carbon in the soil may come from various sources. Therefore synthesized 14C tagged NH4HCO3 (ABC) was used. Products of ammonium bicarbonate (ABC) or long-term effect ammonium bicarbonate (LEABC) were tagged with 14C when they were synthesized in the laboratory. An indoor greenhouse was built and wheat was chosen as the plant to study in this ecosystem. The investigated ecosystem consists of plant (wheat), soils with three different pH values (alkaline, neutral and acid), and three types of underground water (different Ca2+ and Mg2+ concentrations). After biological assimilation and metabolism in wheat receiving ABC or LEABC, it was found that a considerable amount (up to 10%) of the carbon source is absorbed by the wheat with increased biomass production. The majority of the unused carbon source (up to 76%) percolated into the soil as carbonates, such as environmentally benign calcium carbonate (CaCO3). Generally speaking, alkaline soil has a higher capability to capture and store carbon. For the same soil, there is no apparent difference in carbon capturing capability between ABC fertilizer and LEABC fertilizer. These findings answer the question how carbon is distributed after synthesized fertilizer is applied into the ecosystem. In addition, a separate post-experiment on fertilizer carbon forms that exist in the soil was made. It was found that the up to 88% of the trapped carbon exists in the form of insoluble salts (i.e., CaCO3) in alkaline soils. This indicates that alkaline soil has a greater potential for storing carbon after the use of the synthesized fertilizer from exhausted CO2.

  4. Recovery Act: Molecular Simulation of Dissolved Inorganic Carbons for Underground Brine CO2 Sequestration

    SciTech Connect (OSTI)

    Goddard, William

    2012-11-30

    To further our understanding and develop the method for measuring the DICs under geological sequestration conditions, we studied the infrared spectra of DICs under high pressure and temperature conditions. First principles simulations of DICs in brine conditions were performed using a highly optimized ReaxFF-DIC forcefield. The thermodynamics stability of each species were determined using the 2PT method, and shown to be consistent with the Reax simulations. More importantly, we have presented the IR spectra of DIC in real brine conditions as a function of temperature and pressure. At near earth conditions, we find a breaking of the O-C-O bending modes into asymmetric and symmetric modes, separated by 100cm{sup -1} at 400K and 5 GPa. These results can now be used to calibrate FTIR laser measurements.

  5. Full Scale Bioreactor Landfill for Carbon Sequestration and Greenhouse Emission Control

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Kathy Sananikone; Don Augenstein

    2005-03-30

    The Yolo County Department of Planning and Public Works constructed a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective was to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entailed the construction of a 12-acre module that contained a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells were highly instrumented to monitor bioreactor performance. Liquid addition commenced in the 3.5-acre anaerobic cell and the 6-acre anaerobic cell. Construction of the 2.5-acre aerobic cell and biofilter has been completed. The current project status and preliminary monitoring results are summarized in this report.

  6. FULL SCALE BIOREACTOR LANDFILL FOR CARBON SEQUESTRATION AND GREENHOUSE EMISSION CONTROL

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Heather Akau

    2003-08-01

    The Yolo County Department of Planning and Public Works is constructing a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective is to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entails the construction of a 12-acre module that contains a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells are highly instrumented to monitor bioreactor performance. Liquid addition has commenced in the 3.5-acre anaerobic cell and the 6-acre anaerobic cell. Construction of the 2.5-acre aerobic cell is nearly complete with only the biofilter remaining and is scheduled to be complete by the end of August 2003. The current project status and preliminary monitoring results are summarized in this report.

  7. FULL SCALE BIOREACTOR LANDFILL FOR CARBON SEQUESTRATION AND GREENHOUSE EMISSION CONTROL

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Heather Akau

    2003-05-01

    The Yolo County Department of Planning and Public Works is constructing a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective is to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entails the construction of a 12-acre module that contains a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells are highly instrumented to monitor bioreactor performance. Construction is complete on the 3.5-acre anaerobic cell and liquid addition has commenced. Construction of the 2.5-acre aerobic cell is nearly complete with only the biofilter remaining and construction of the west-side 6-acre anaerobic cell is nearly complete with only the liquid addition system remaining. The current project status and preliminary monitoring results are summarized in this report.

  8. FULL SCALE BIOREACTOR LANDFILL FOR CARBON SEQUESTRATION AND GREENHOUSE EMISSION CONTROL

    SciTech Connect (OSTI)

    Ramin Yazdani; Jeff Kieffer; Heather Akau

    2003-12-01

    The Yolo County Department of Planning and Public Works is constructing a full-scale bioreactor landfill as a part of the Environmental Protection Agency's (EPA) Project XL program to develop innovative approaches for carbon sequestration and greenhouse emission control. The overall objective is to manage landfill solid waste for rapid waste decomposition and maximum landfill gas generation and capture for carbon sequestration and greenhouse emission control. Waste decomposition is accelerated by improving conditions for either the aerobic or anaerobic biological processes and involves circulating controlled quantities of liquid (leachate, groundwater, gray water, etc.), and, in the aerobic process, large volumes of air. The first phase of the project entails the construction of a 12-acre module that contains a 6-acre anaerobic cell, a 3.5-acre anaerobic cell, and a 2.5-acre aerobic cell at the Yolo County Central Landfill near Davis, California. The cells are highly instrumented to monitor bioreactor performance. Liquid addition has commenced in the 3.5-acre anaerobic cell and the 6-acre anaerobic cell. Construction of the 2.5-acre aerobic cell and biofilter has been completed. The remaining task to be completed is to test the biofilter prior to operation, which is currently anticipated to begin in January 2004. The current project status and preliminary monitoring results are summarized in this report.

  9. Mineral Sequestration of Carbon Dixoide in a Sandstone-Shale System

    SciTech Connect (OSTI)

    Xu, Tianfu; Apps, John A.; Pruess, Karsten

    2004-07-09

    A conceptual model of CO2 injection in bedded sandstone-shale sequences has been developed using hydrogeologic properties and mineral compositions commonly encountered in Gulf Coast sediments. Numerical simulations were performed with the reactive fluid flow and geochemical transport code TOUGHREACT to analyze mass transfer between sandstone and shale layers and CO2 immobilization through carbonate precipitation. Results indicate that most CO2 sequestration occurs in the sandstone. The major CO2 trapping minerals are dawsonite and ankerite. The CO2 mineral-trapping capacity after 100,000 years reaches about 90 kg per cubic meter of the medium. The CO2 trapping capacity depends on primary mineral composition. Precipitation of siderite and ankerite requires Fe+2 supplied mainly by chlorite and some by hematite dissolution and reduction. Precipitation of dawsonite requires Na+ provided by oligoclase dissolution. The initial abundance of chlorite and oligoclase therefore affects the CO2 mineral trapping capacity. The sequestration time required depends on the kinetic rate of mineral dissolution and precipitation. Dawsonite reaction kinetics is not well understood, and sensitivity regarding the precipitation rate was examined. The addition of CO2 as secondary carbonates results in decreased porosity. The leaching of chemical constituents from the interior of the shale causes slightly increased porosity. The limited information currently available for the mineralogy of natural high-pressure CO2 gas reservoirs is also generally consistent with our simulation. The ''numerical experiments'' give a detailed understanding of the dynamic evolution of a sandstone-shale geochemical system.

  10. International Symposium on Site Characterization for CO2 Geological Storage

    E-Print Network [OSTI]

    Tsang, Chin-Fu

    2006-01-01

    Geo- logic Carbon Dioxide Sequestration: An Analysis ofnational Conference on Carbon Sequestration, Washington DC,Annual Conference on Carbon Sequestration, Alexandria, VA,

  11. Technical Report on Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration

    SciTech Connect (OSTI)

    Bill Stanley; Sandra Brown; Zoe Kant; Patrick Gonzalez

    2009-01-07

    The Nature Conservancy participated in a Cooperative Agreement with the Department of Energy (DOE) National Energy Technology Laboratory (NETL) to explore the compatibility of carbon sequestration in terrestrial ecosystems and the conservation of biodiversity. The title of the research project was 'Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration'. The objectives of the project were to: (1) improve carbon offset estimates produced in both the planning and implementation phases of projects; (2) build valid and standardized approaches to estimate project carbon benefits at a reasonable cost; and (3) lay the groundwork for implementing cost-effective projects, providing new testing ground for biodiversity protection and restoration projects that store additional atmospheric carbon. This Final Technical Report discusses the results of the six tasks that The Nature Conservancy undertook to answer research needs while facilitating the development of real projects with measurable greenhouse gas reductions. The research described in this report occurred between July 1st 2001 and July 10th 2008. The specific tasks discussed include: Task 1: carbon inventory advancements; Task 2: emerging technologies for remote sensing of terrestrial carbon; Task 3: baseline method development; Task 4: third-party technical advisory panel meetings; Task 5: new project feasibility studies; and Task 6: development of new project software screening tool. The project occurred in two phases. The first was a focused exploration of specific carbon measurement and monitoring methodologies and pre-selected carbon sequestration opportunities. The second was a more systematic and comprehensive approach to compare various competing measurement and monitoring methodologies, and assessment of a variety of carbon sequestration opportunities in order to find those that are the lowest cost with the greatest combined carbon and other environmental benefits. In the first phase we worked in the U.S., Brazil, Belize, Bolivia, Peru, and Chile to develop and refine specific carbon inventory methods, pioneering a new remote-sensing method for cost-effectively measuring and monitoring terrestrial carbon sequestration and system for developing carbon baselines for both avoided deforestation and afforestation/reforestation projects. We evaluated the costs and carbon benefits of a number of specific terrestrial carbon sequestration activities throughout the U.S., including reforestation of abandoned mined lands in southwest Virginia, grassland restoration in Arizona and Indiana, and reforestation in the Mississippi Alluvial Delta. The most cost-effective U.S. terrestrial sequestration opportunity we found through these studies was reforestation in the Mississippi Alluvial Delta. In Phase II we conducted a more systematic assessment and comparison of several different measurement and monitoring approaches in the Northern Cascades of California, and a broad 11-state Northeast regional assessment, rather than pre-selected and targeted, analysis of terrestrial sequestration costs and benefits. Work was carried out in Brazil, Belize, Chile, Peru and the USA. Partners include the Winrock International Institute for Agricultural Development, The Sampson Group, Programme for Belize, Society for Wildlife Conservation (SPVS), Universidad Austral de Chile, Michael Lefsky, Colorado State University, UC Berkeley, the Carnegie Institution of Washington, ProNaturaleza, Ohio State University, Stephen F. Austin University, Geographical Modeling Services, Inc., WestWater, Los Alamos National Laboratory, Century Ecosystem Services, Mirant Corporation, General Motors, American Electric Power, Salt River Project, Applied Energy Systems, KeySpan, NiSource, and PSEG. This project, 'Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration', has resulted in over 50 presentations and reports, available publicly through the Department of Energy or by visiting the links listed in Appendix 1. More

  12. Training Graduate and Undergraduate Students in Simulation and Risk Assessment for Carbon Sequestration

    SciTech Connect (OSTI)

    McCray, John

    2013-09-30

    Capturing carbon dioxide (CO2) and injecting it into deep underground formations for storage (carbon capture and underground storage, or CCUS) is one way of reducing anthropogenic CO2 emissions. Gas or aqueous-phase leakage may occur due to transport via faults and fractures, through faulty well bores, or through leaky confining materials. Contaminants of concern include aqueous salts and dissolved solids, gaseous or aqueous-phase organic contaminants, and acidic gas or aqueous-phase fluids that can liberate metals from aquifer minerals. Understanding the mechanisms and parameters that can contribute to leakage of the CO2 and the ultimate impact on shallow water aquifers that overlie injection formations is an important step in evaluating the efficacy and risks associated with long-term CO2 storage. Three students were supported on the grant Training Graduate and Undergraduate Students in Simulation and Risk Assessment for Carbon Sequestration. These three students each examined a different aspect of simulation and risk assessment related to carbon dioxide sequestration and the potential impacts of CO2 leakage. Two performed numerical simulation studies, one to assess leakage rates as a function of fault and deep reservoir parameters and one to develop a method for quantitative risk assessment in the event of a CO2 leak and subsequent changes in groundwater chemistry. A third student performed an experimental evaluation of the potential for metal release from sandstone aquifers under simulated leakage conditions. This study has resulted in two student first-authored published papers {Siirila, 2012 #560}{Kirsch, 2014 #770} and one currently in preparation {Menke, In prep. #809}.

  13. Carbon Sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits &BradburyMay 1, 2013,Cafe ScientifiqueCanisterEnergy»Oil

  14. Potential and cost of carbon sequestration in the Tanzanian forest sector

    SciTech Connect (OSTI)

    Makundi, Willy R.

    2001-01-01

    The forest sector in Tanzania offers ample opportunities to reduce greenhouse gas emissions (GHG) and sequestered carbon (C) in terrestrial ecosystems. More than 90% of the country's demand for primary energy is obtained from biomass mostly procured unsustainably from natural forests. This study examines the potential to sequester C through expansion of forest plantations aimed at reducing the dependence on natural forest for wood fuel production, as well as increase the country's output of industrial wood from plantations. These were compared ton conservation options in the tropical and miombo ecosystems. Three sequestration options were analyzed, involving the establishment of short rotation and long rotation plantations on about 1.7 x 106 hectares. The short rotation community forest option has a potential to sequester an equilibrium amount of 197.4 x 106 Mg C by 2024 at a net benefit of $79.5 x 106, while yielding a NPV of $0.46 Mg-1 C. The long rotation options for softwood and hardwood plantations will reach an equilibrium sequestration of 5.6 and 11.8 x 106 Mg C at a negative NPV of $0.60 Mg-1 C and $0.32 Mg-1 C. The three options provide cost competitive opportunities for sequestering about 7.5 x 106 Mg C yr -1 while providing desired forest products and easing the pressure on the natural forests in Tanzania. The endowment costs of the sequestration options were all found to be cheaper than the emission avoidance cost for conservation options which had an average cost of $1.27 Mg-1 C, rising to $ 7.5 Mg-1 C under some assumptions on vulnerability to encroachment. The estimates shown here may represent the upper bound, because the actual potential will be influenced by market prices for inputs and forest products, land use policy constraints and the structure of global C transactions.

  15. Carbon Capture and Sequestration (via Enhanced Oil Recovery) from a Hydrogen Production Facility in an Oil Refinery

    SciTech Connect (OSTI)

    Stewart Mehlman

    2010-06-16

    The project proposed a commercial demonstration of advanced technologies that would capture and sequester CO2 emissions from an existing hydrogen production facility in an oil refinery into underground formations in combination with Enhanced Oil Recovery (EOR). The project is led by Praxair, Inc., with other project participants: BP Products North America Inc., Denbury Onshore, LLC (Denbury), and Gulf Coast Carbon Center (GCCC) at the Bureau of Economic Geology of The University of Texas at Austin. The project is located at the BP Refinery at Texas City, Texas. Praxair owns and operates a large hydrogen production facility within the refinery. As part of the project, Praxair would construct a CO2 capture and compression facility. The project aimed at demonstrating a novel vacuum pressure swing adsorption (VPSA) based technology to remove CO2 from the Steam Methane Reformers (SMR) process gas. The captured CO2 would be purified using refrigerated partial condensation separation (i.e., cold box). Denbury would purchase the CO2 from the project and inject the CO2 as part of its independent commercial EOR projects. The Gulf Coast Carbon Center at the Bureau of Economic Geology, a unit of University of Texas at Austin, would manage the research monitoring, verification and accounting (MVA) project for the sequestered CO2, in conjunction with Denbury. The sequestration and associated MVA activities would be carried out in the Hastings field at Brazoria County, TX. The project would exceed DOE’s target of capturing one million tons of CO2 per year (MTPY) by 2015. Phase 1 of the project (Project Definition) is being completed. The key objective of Phase 1 is to define the project in sufficient detail to enable an economic decision with regard to proceeding with Phase 2. This topical report summarizes the administrative, programmatic and technical accomplishments completed in Phase 1 of the project. It describes the work relative to project technical and design activities (associated with CO2 capture technologies and geologic sequestration MVA), and Environmental Information Volume. Specific accomplishments of this Phase include: 1. Finalization of the Project Management Plan 2. Development of engineering designs in sufficient detail for defining project performance and costs 3. Preparation of Environmental Information Volume 4. Completion of Hazard Identification Studies 5. Completion of control cost estimates and preparation of business plan During the Phase 1 detailed cost estimate, project costs increased substantially from the previous estimate. Furthermore, the detailed risk assessment identified integration risks associated with potentially impacting the steam methane reformer operation. While the Phase 1 work identified ways to mitigate these integration risks satisfactorily from an operational perspective, the associated costs and potential schedule impacts contributed to the decision not to proceed to Phase 2. We have concluded that the project costs and integration risks at Texas City are not commensurate with the potential benefits of the project at this time.

  16. EXPERIMENTAL DESIGN APPLICATIONS FOR MODELING AND ASSESSING CARBON DIOXIDE SEQUESTRATION IN SALINE AQUIFERS

    SciTech Connect (OSTI)

    Rogers, John

    2014-08-31

    This project was a computer modeling effort to couple reservoir simulation and ED/RSM using Sensitivity Analysis, Uncertainty Analysis, and Optimization Methods, to assess geologic, geochemical, geomechanical, and rock-fluid effects and factors on CO2 injectivity, capacity, and plume migration. The project objective was to develop proxy models to simplify the highly complex coupled geochemical and geomechanical models in the utilization and storage of CO2 in the subsurface. The goals were to investigate and prove the feasibility of the ED/RSM processes and engineering development, and bridge the gaps regarding the uncertainty and unknowns of the many geochemical and geomechanical interacting parameters in the development and operation of anthropogenic CO2 sequestration and storage sites. The bottleneck in this workflow is the high computational effort of reactive transport simulation models and large number of input variables to optimize with ED/RSM techniques. The project was not to develop the reactive transport, geomechanical, or ED/RSM software, but was to use what was commercially and/or publically available as a proof of concept to generate proxy or surrogate models. A detailed geologic and petrographic mineral assemblage and geologic structure of the doubly plunging anticline was defined using the USDOE RMOTC formations of interest data (e.g., Lower Sundance, Crow Mountain, Alcova Limestone, and Red Peak). The assemblage of 23 minerals was primarily developed from literature data and petrophysical (well log) analysis. The assemblage and structure was input into a commercial reactive transport simulator to predict the effects of CO2 injection and complex reactions with the reservoir rock. Significant impediments were encountered during the execution phase of the project. The only known commercial reactive transport simulator was incapable of simulating complex geochemistry modeled in this project. Significant effort and project funding was expended to determine the limitations of both the commercial simulator and the Lawrence Berkeley National Laboratory (LBNL) R&D simulator, TOUGHREACT available to the project. A simplified layer cake model approximating the volume of the RMOTC targeted reservoirs was defined with 1-3 minerals eventually modeled with limited success. Modeling reactive transport in porous media requires significant computational power. In this project, up to 24 processors were used to model a limited mineral set of 1-3 minerals. In addition, geomechanical aspects of injecting CO2 into closed, semi-open, and open systems in various well completion methods was simulated. Enhanced Oil Recovery (EOR) as a storage method was not modeled. A robust and stable simulation dataset or base case was developed and used to create a master dataset with embedded instructions for input to the ED/RSM software. Little success was achieved toward the objective of the project using the commercial simulator or the LBNL simulator versions available during the time of this project. Several hundred realizations were run with the commercial simulator and ED/RSM software, most having convergence problems and terminating prematurely. A proxy model for full field CO2 injection sequestration utilization and storage was not capable of being developed with software available for this project. Though the chemistry is reasonably known and understood, based on the amount of effort and huge computational time required, predicting CO2 sequestration storage capacity in geologic formations to within the program goals of ±30% proved unsuccessful.

  17. An Evaluation of the Carbon Sequestration Potential of the Cambro-Ordovician Strata of the Illinois and Michigan Basins

    SciTech Connect (OSTI)

    Leetaru, Hannes

    2014-12-01

    The studies summarized herein were conducted during 2009–2014 to investigate the utility of the Knox Group and St. Peter Sandstone deeply buried geologic strata for underground storage of carbon dioxide (CO2), a practice called CO2 sequestration (CCS). In the subsurface of the midwestern United States, the Knox and associated strata extend continuously over an area approaching 500,000 sq. km, about three times as large as the State of Illinois. Although parts of this region are underlain by the deeper Mt. Simon Sandstone, which has been proven by other Department of Energy-funded research as a resource for CCS, the Knox strata may be an additional CCS resource for some parts of the Midwest and may be the sole geologic storage (GS) resource for other parts. One group of studies assembles, analyzes, and presents regional-scale and point-scale geologic information that bears on the suitability of the geologic formations of the Knox for a CCS project. New geologic and geo-engineering information was developed through a small-scale test of CO2 injection into a part of the Knox, conducted in western Kentucky. These studies and tests establish the expectation that, at least in some locations, geologic formations within the Knox will (a) accept a commercial-scale flow rate of CO2 injected through a drilled well; (b) hold a commercial-scale mass of CO2 (at least 30 million tons) that is injected over decades; and (c) seal the injected CO2 within the injection formations for hundreds to thousands of years. In CCS literature, these three key CCS-related attributes are called injectivity, capacity, and containment. The regional-scale studies show that reservoir and seal properties adequate for commercial-scale CCS in a Knox reservoir are likely to extend generally throughout the Illinois and Michigan Basins. Information distinguishing less prospective subregions from more prospective fairways is included in this report. Another group of studies report the results of reservoir flow simulations that estimate the progress and outcomes of hypothetical CCS projects carried out within the Knox (particularly within the Potosi Dolomite subunit, which, in places, is highly permeable) and within the overlying St. Peter Sandstone. In these studies, the regional-scale information and a limited amount of detailed data from specific boreholes is used as the basis for modeling the CO2 injection process (dynamic modeling). The simulation studies were conducted progressively, with each successive study designed to refine the conclusions of the preceding one or to answer additional questions. The simulation studies conclude that at Decatur, Illinois or a geologically similar site, the Potosi Dolomite reservoir may provide adequate injectivity and capacity for commercial-scale injection through a single injection well. This conclusion depends on inferences from seismic-data attributes that certain highly permeable horizons observed in the wells represent laterally persistent, porous vuggy zones that are vertically more common than initially evident from wellbore data. Lateral persistence of vuggy zones is supported by isotopic evidence that the conditions that caused vug development (near-surface processes) were of regional rather than local scale. Other studies address aspects of executing and managing a CCS project that targets a Knox reservoir. These studies cover well drilling, public interactions, representation of datasets and conclusions using geographic information system (GIS) platforms, and risk management.

  18. Missouri University of Science and Technology 1 Geological Engineering

    E-Print Network [OSTI]

    Missouri-Rolla, University of

    International University Karst hydrology, carbon sequestration, environmental hydrogeology, groundwater

  19. Research project on CO2 geological storage and groundwater resources: Large-scale hydrological evaluation and modeling of impact on groundwater systems

    E-Print Network [OSTI]

    Birkholzer, Jens; Zhou, Quanlin; Rutqvist, Jonny; Jordan, Preston; Zhang, K.; Tsang, Chin-Fu

    2008-01-01

    Report, Midwest Regional Carbon Sequestration Partnership.West Coast Regional Carbon Sequestration Partnership, Final

  20. Integrated Reflection Seismic Monitoring and Reservoir Modeling for Geologic CO2 Sequestration

    SciTech Connect (OSTI)

    John Rogers

    2011-12-31

    The US DOE/NETL CCS MVA program funded a project with Fusion Petroleum Technologies Inc. (now SIGMA) to model the proof of concept of using sparse seismic data in the monitoring of CO{sub 2} injected into saline aquifers. The goal of the project was to develop and demonstrate an active source reflection seismic imaging strategy based on deployment of spatially sparse surface seismic arrays. The primary objective was to test the feasibility of sparse seismic array systems to monitor the CO{sub 2} plume migration injected into deep saline aquifers. The USDOE/RMOTC Teapot Dome (Wyoming) 3D seismic and reservoir data targeting the Crow Mountain formation was used as a realistic proxy to evaluate the feasibility of the proposed methodology. Though the RMOTC field has been well studied, the Crow Mountain as a saline aquifer has not been studied previously as a CO{sub 2} sequestration (storage) candidate reservoir. A full reprocessing of the seismic data from field tapes that included prestack time migration (PSTM) followed by prestack depth migration (PSDM) was performed. A baseline reservoir model was generated from the new imaging results that characterized the faults and horizon surfaces of the Crow Mountain reservoir. The 3D interpretation was integrated with the petrophysical data from available wells and incorporated into a geocellular model. The reservoir structure used in the geocellular model was developed using advanced inversion technologies including Fusion's ThinMAN{trademark} broadband spectral inversion. Seal failure risk was assessed using Fusion's proprietary GEOPRESS{trademark} pore pressure and fracture pressure prediction technology. CO{sub 2} injection was simulated into the Crow Mountain with a commercial reservoir simulator. Approximately 1.2MM tons of CO{sub 2} was simulated to be injected into the Crow Mountain reservoir over 30 years and subsequently let 'soak' in the reservoir for 970 years. The relatively small plume developed from this injection was observed migrating due to gravity to the apexes of the double anticline in the Crow Mountain reservoir of the Teapot dome. Four models were generated from the reservoir simulation task of the project which included three saturation models representing snapshots at different times during and after simulated CO{sub 2} injection and a fully saturated CO{sub 2} fluid substitution model. The saturation models were used along with a Gassmann fluid substitution model for CO{sub 2} to perform fluid volumetric substitution in the Crow Mountain formation. The fluid substitution resulted in a velocity and density model for the 3D volume at each saturation condition that was used to generate a synthetic seismic survey. FPTI's (Fusion Petroleum Technologies Inc.) proprietary SeisModelPRO{trademark} full acoustic wave equation software was used to simulate acquisition of a 3D seismic survey on the four models over a subset of the field area. The simulated acquisition area included the injection wells and the majority of the simulated plume area.

  1. Harvesting the Greenhouse: Comparing Biological Sequestration with Emissions Offsets

    E-Print Network [OSTI]

    McCarl, Bruce A.

    C. Murray Environmental and Natural Resource Economics Program Research Triangle Institute Research (e.g. increasing fuel use efficiency or switching fuels). Sequestration offsets involve the capture GHGs, then injecting the carbon into soils, aquifers, oceans or geological formations for permanent

  2. Carbon Capture and Storage, 2008

    SciTech Connect (OSTI)

    2009-03-19

    The U.S. Department of Energy is researching the safe implementation of a technology called carbon sequestration, also known as carbon capture and storage, or CCS. Based on an oilfield practice, this approach stores carbon dioxide, or CO2 generated from human activities for millennia as a means to mitigate global climate change. In 2003, the Department of Energys National Energy Technology Laboratory formed seven Regional Carbon Sequestration Partnerships to assess geologic formations suitable for storage and to determine the best approaches to implement carbon sequestration in each region. This video describes the work of these partnerships.

  3. Carbon Capture and Storage, 2008

    ScienceCinema (OSTI)

    None

    2010-01-08

    The U.S. Department of Energy is researching the safe implementation of a technology called carbon sequestration, also known as carbon capture and storage, or CCS. Based on an oilfield practice, this approach stores carbon dioxide, or CO2 generated from human activities for millennia as a means to mitigate global climate change. In 2003, the Department of Energys National Energy Technology Laboratory formed seven Regional Carbon Sequestration Partnerships to assess geologic formations suitable for storage and to determine the best approaches to implement carbon sequestration in each region. This video describes the work of these partnerships.

  4. Black Carbon’s Properties and Role in the Environment: A Comprehensive Review

    E-Print Network [OSTI]

    Shrestha, Gyami

    2010-01-01

    Keywords: soil carbon sequestration; carbon budget;of an energy efficient carbon sequestration mechanism, asin the later section on carbon sequestration. In atmospheric

  5. EA-1846: Demonstration of Carbon Dioxide Capture and Sequestration of Steam Methane Reforming Process Gas Used for Large-Scale Hydrogen Production, Port Arthur, Texas

    Broader source: Energy.gov [DOE]

    DOE completed a final environmental assessment (EA) for a project under Area I of the Industrial Carbon Capture and Sequestration from Industrial Sources and Innovative Concepts for Beneficial CO2...

  6. An analytical framework for long term policy for commercial deployment and innovation in carbon capture and sequestration technology in the United States

    E-Print Network [OSTI]

    Hamilton, Michael Roberts

    2010-01-01

    Carbon capture and sequestration (CCS) technology has the potential to be a key CO2 emissions mitigation technology for the United States. Several CCS technology options are ready for immediate commercial-scale demonstration, ...

  7. Economics and policies for carbon capture and sequestration in the western United States : a marginal cost analysis of potential power plant deployment

    E-Print Network [OSTI]

    Shu, Gary

    2010-01-01

    Carbon capture and sequestration (CCS) is a technology that can significantly reduce power sector greenhouse gas (GHG) emissions from coal-fired power plants. CCS technology is currently in development and requires higher ...

  8. Public resource allocation for programs aimed at managing woody plants on the Edwards Plateau: water yield, wildlife habitat, and carbon sequestration 

    E-Print Network [OSTI]

    Davis, Amber Marie

    2006-08-16

    The Edwards Plateau is the drainage area for the Edwards Aquifer, which provides water to over 2.2 million people. The plateau also provides other ecosystem services, such as wildlife habitat and the sequestration of atmospheric carbon dioxide...

  9. Petrophysical and Geochemical Properties of Columbia River Flood Basalt: Implications for Carbon Sequestration

    SciTech Connect (OSTI)

    Zakharova, Natalia V.; Goldberg, David S.; Sullivan, E. C.; Herron, Michael M.; Grau, Jim A.

    2012-11-02

    Abstract This study presents borehole geophysical data and sidewall core chemistry from the Wallula Pilot Sequestration Project in the Columbia River flood basalt. The wireline logging data were reprocessed, core-calibrated and interpreted in the framework of reservoir and seal characterization for carbon dioxide storage. Particular attention is paid to the capabilities and limitations of borehole spectroscopy for chemical characterization of basalt. Neutron capture spectroscopy logging is shown to provide accurate concentrations for up to 8 major and minor elements but has limited sensitivity to natural alteration in fresh-water basaltic reservoirs. The Wallula borehole intersected 26 flows from 7 members of the Grande Ronde formation. The logging data demonstrate a cyclic pattern of sequential basalt flows with alternating porous flow tops (potential reservoirs) and massive flow interiors (potential caprock). The log-derived apparent porosity is extremely high in the flow tops (20%-45%), and considerably overestimates effective porosity obtained from hydraulic testing. The flow interiors are characterized by low apparent porosity (0-8%) but appear pervasively fractured in borehole images. Electrical resistivity images show diverse volcanic textures and provide an excellent tool for fracture analysis, but neither fracture density nor log-derived porosity uniquely correlate with hydraulic properties of the Grande Ronde formation. While porous flow tops in these deep flood basalts may offer reservoirs with high mineralization rates, long leakage migration paths, and thick sections of caprock for CO2 storage, a more extensive multi- well characterization would be necessary to assess lateral variations and establish sequestration capacity in this reservoir.

  10. CO2 CAPTURE PROJECT-AN INTEGRATED, COLLABORATIVE TECHNOLOGY DEVELOPMENT PROJECT FOR NEXT GENERATION CO2 SEPARATION, CAPTURE AND GEOLOGIC SEQUESTRATION

    SciTech Connect (OSTI)

    Helen Kerr

    2004-04-01

    The CO{sub 2} Capture Project (CCP) is a joint industry project, funded by eight energy companies (BP, ChevronTexaco, EnCana, Eni, Norsk Hydro, Shell, Statoil, and Suncor) and three government agencies (European Union (DG Res & DG Tren), Norway (Klimatek) and the U.S.A. (Department of Energy)). The project objective is to develop new technologies, which could reduce the cost of CO{sub 2} capture and geologic storage by 50% for retrofit to existing plants and 75% for new-build plants. Technologies are to be developed to ''proof of concept'' stage by the end of 2003. The project budget is approximately $24 million over 3 years and the work program is divided into eight major activity areas: (1) Baseline Design and Cost Estimation--defined the uncontrolled emissions from each facility and estimate the cost of abatement in $/tonne CO{sub 2}. (2) Capture Technology, Post Combustion--technologies, which can remove CO{sub 2} from exhaust gases after combustion. (3) Capture Technology, Oxyfuel--where oxygen is separated from the air and then burned with hydrocarbons to produce an exhaust with wet high concentrations of CO{sub 2} for storage. (4) Capture Technology, Pre-Combustion--in which, natural gas and petroleum coke are converted to hydrogen and CO{sub 2} in a reformer/gasifier. (5) Common Economic Model/Technology Screening--analysis and evaluation of each technology applied to the scenarios to provide meaningful and consistent comparison. (6) New Technology Cost Estimation: on a consistent basis with the baseline above, to demonstrate cost reductions. (7) Geologic Storage, Monitoring and Verification (SMV)--providing assurance that CO{sub 2} can be safely stored in geologic formations over the long term. (8) Non-Technical: project management, communication of results and a review of current policies and incentives governing CO{sub 2} capture and storage. Technology development work dominated the past six months of the project. Numerous studies have completed their 2003 stagegate review and are reported here. Some will proceed to the next stagegate review in 2004. Some technologies are emerging as preferred over others. Pre-combustion De-carbonization (hydrogen fuel) technologies are showing excellent results and may be able to meet the CCP's aggressive cost reduction targets for new-build plants. The workscopes planned for the next key stagegates are under review before work begins based on the current economic assessment of their performance. Chemical looping to produce oxygen for oxyfuel combustion shows real promise. As expected, post-combustion technologies are emerging as higher cost options but even so some significant potential reductions in cost have been identified and will continue to be explored. Storage, measurement, and verification studies are moving rapidly forward and suggest that geologic sequestration can be a safe form of long-term CO{sub 2} storage. Hyper-spectral geo-botanical measurements may be an inexpensive and non-intrusive method for long-term monitoring. Modeling studies suggest that primary leakage routes from CO{sub 2} storage sites may be along old wellbores in areas disturbed by earlier oil and gas operations. This is good news because old wells are usually mapped and can be repaired during the site preparation process. Wells are also easy to monitor and intervention is possible if needed. The project will continue to evaluate and bring in novel studies and ideas within the project scope as requested by the DOE. The results to date are summarized in the attached report and presented in detail in the attached appendices.

  11. CO2 Capture Project-An Integrated, Collaborative Technology Development Project for Next Generation CO2 Separation, Capture and Geologic Sequestration

    SciTech Connect (OSTI)

    Helen Kerr; Linda M. Curran

    2005-04-15

    The CO{sub 2} Capture Project (CCP) was a joint industry project, funded by eight energy companies (BP, ChevronTexaco, EnCana, ENI, Norsk Hydro, Shell, Statoil, and Suncor) and three government agencies (European Union [DG RES & DG TREN], the Norwegian Research Council [Klimatek Program] and the U.S. Department of Energy [NETL]). The project objective was to develop new technologies that could reduce the cost of CO{sub 2} capture and geologic storage by 50% for retrofit to existing plants and 75% for new-build plants. Technologies were to be developed to ''proof of concept'' stage by the end of 2003. Certain promising technology areas were increased in scope and the studies extended through 2004. The project budget was approximately $26.4 million over 4 years and the work program is divided into eight major activity areas: Baseline Design and Cost Estimation--defined the uncontrolled emissions from each facility and estimate the cost of abatement in $/tonne CO{sub 2}. Capture Technology, Post Combustion: technologies, which can remove CO{sub 2} from exhaust gases after combustion. Capture Technology, Oxyfuel: where oxygen is separated from the air and then burned with hydrocarbons to produce an exhaust with high CO{sub 2} for storage. Capture Technology, Pre-Combustion: in which, natural gas and petroleum cokes are converted to hydrogen and CO{sub 2} in a reformer/gasifier. Common Economic Model/Technology Screening: analysis and evaluation of each technology applied to the scenarios to provide meaningful and consistent comparison. New Technology Cost Estimation: on a consistent basis with the baseline above, to demonstrate cost reductions. Geologic Storage, Monitoring and Verification (SMV): providing assurance that CO{sub 2} can be safely stored in geologic formations over the long term. Non-Technical: project management, communication of results and a review of current policies and incentives governing CO{sub 2} capture and storage. Pre-combustion De-carbonization (hydrogen fuel) technologies showed excellent results and may be able to meet the CCP's aggressive cost reduction targets for new-build plants. Chemical looping to produce oxygen for oxyfuel combustion shows real promise. Post-combustion technologies emerged as higher cost options that may only have niche roles. Storage, measurement, and verification studies suggest that geologic sequestration will be a safe form of long-term CO{sub 2} storage. Economic modeling shows that options to reduce costs by 50% exist. A rigorous methodology for technology evaluation was developed. Public acceptance and awareness were enhanced through extensive communication of results to the stakeholder community (scientific, NGO, policy, and general public). Two volumes of results have been published and are available to all. Well over 150 technical papers were produced. All funded studies for this phase of the CCP are complete. The results are summarized in this report and all final reports are presented in the attached appendices.

  12. Investigation of Integrated Subsurface Processing of Landfill Gas and Carbon Sequestration, Johnson County, Kansas

    SciTech Connect (OSTI)

    K. David Newell; Timothy R. Carr

    2007-03-31

    The Johnson County Landfill in Shawnee, KS is operated by Deffenbaugh Industries and serves much of metropolitan Kansas City. Refuse, which is dumped in large plastic-underlined trash cells covering several acres, is covered over with shale shortly after burial. The landfill waste, once it fills the cell, is then drilled by Kansas City LFG, so that the gas generated by anaerobic decomposition of the refuse can be harvested. Production of raw landfill gas from the Johnson County landfill comes from 150 wells. Daily production is approximately 2.2 to 2.5 mmcf, of which approximately 50% is methane and 50% is carbon dioxide and NMVOCs (non-methane volatile organic compounds). Heating value is approximately 550 BTU/scf. A upgrading plant, utilizing an amine process, rejects the carbon dioxide and NMVOCs, and upgrades the gas to pipeline quality (i.e., nominally a heating value >950 BTU/scf). The gas is sold to a pipeline adjacent to the landfill. With coal-bearing strata underlying the landfill, and carbon dioxide a major effluent gas derived from the upgrading process, the Johnson County Landfill is potentially an ideal setting to study the feasibility of injecting the effluent gas in the coals for both enhanced coalbed methane recovery and carbon sequestration. To these ends, coals below the landfill were cored and then were analyzed for their thickness and sorbed gas content, which ranged up to 79 scf/ton. Assuming 1 1/2 square miles of land (960 acres) at the Johnson County Landfill can be utilized for coalbed and shale gas recovery, the total amount of in-place gas calculates to 946,200 mcf, or 946.2 mmcf, or 0.95 bcf (i.e., 985.6 mcf/acre X 960 acres). Assuming that carbon dioxide can be imbibed by the coals and shales on a 2:1 ratio compared to the gas that was originally present, then 1682 to 1720 days (4.6 to 4.7 years) of landfill carbon dioxide production can be sequestered by the coals and shales immediately under the landfill. Three coal--the Bevier, Fleming, and Mulberry coals--are the major coals of sufficient thickness (nominally >1-foot) that can imbibe carbon dioxide gas with an enhanced coalbed injection. Comparison of the adsorption gas content of coals to the gas desorbed from the coals shows that the degree of saturation decreases with depth for the coals.

  13. An Estimate of the Cost of Electricity from Light Water Reactors and Fossil Plants with Carbon Capture and Sequestration

    SciTech Connect (OSTI)

    Simon, A J

    2009-08-21

    As envisioned in this report, LIFE technology lends itself to large, centralized, baseload (or 'always on') electrical generation. Should LIFE plants be built, they will have to compete in the electricity market with other generation technologies. We consider the economics of technologies with similar operating characteristics: significant economies of scale, limited capacity for turndown, zero dependence on intermittent resources and ability to meet environmental constraints. The five generation technologies examined here are: (1) Light Water Reactors (LWR); (2) Coal; (3) Coal with Carbon Capture and Sequestration (CCS); (4) Natural Gas; and (5) Natural Gas with Carbon Capture and Sequestration. We use MIT's cost estimation methodology (Du and Parsons, 2009) to determine the cost of electricity at which each of these technologies is viable.

  14. Carbon sequestration in natural gas reservoirs: Enhanced gas recovery and natural gas storage

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2003-01-01

    Hydrogen production from natural gas, sequestration ofunderground storage of natural gas, Jour. Petrol. Tech. 943,dioxide as cushion gas for natural gas storage, Energy and

  15. Renewal of Collaborative Research: Economically Viable Forest Harvesting Practices That Increase Carbon Sequestration

    SciTech Connect (OSTI)

    Davidson, E.A.; Dail, D.B., Hollinger, D.; Scott, N.; Richardson, A.

    2012-08-02

    Forests provide wildlife habitat, water and air purification, climate moderation, and timber and nontimber products. Concern about climate change has put forests in the limelight as sinks of atmospheric carbon. The C stored in the global vegetation, mostly in forests, is nearly equivalent to the amount present in atmospheric CO{sub 2}. Both voluntary and government-mandated carbon trading markets are being developed and debated, some of which include C sequestration resulting from forest management as a possible tradeable commodity. However, uncertainties regarding sources of variation in sequestration rates, validation, and leakage remain significant challenges for devising strategies to include forest management in C markets. Hence, the need for scientifically-based information on C sequestration by forest management has never been greater. The consequences of forest management on the US carbon budget are large, because about two-thirds of the {approx}300 million hectare US forest resource is classified as 'commercial forest.' In most C accounting budgets, forest harvesting is usually considered to cause a net release of C from the terrestrial biosphere to the atmosphere. However, forest management practices could be designed to meet the multiple goals of providing wood and paper products, creating economic returns from natural resources, while sequestering C from the atmosphere. The shelterwood harvest strategy, which removes about 30% of the basal area of the overstory trees in each of three successive harvests spread out over thirty years as part of a stand rotation of 60-100 years, may improve net C sequestration compared to clear-cutting because: (1) the average C stored on the land surface over a rotation increases, (2) harvesting only overstory trees means that a larger fraction of the harvested logs can be used for long-lived sawtimber products, compared to more pulp resulting from clearcutting, (3) the shelterwood cut encourages growth of subcanopy trees by opening up the forest canopy to increasing light penetration. Decomposition of onsite harvest slash and of wastes created during timber processing releases CO{sub 2} to the atmosphere, thus offsetting some of the C sequestered in vegetation. Decomposition of soil C and dead roots may also be temporarily stimulated by increased light penetration and warming of the forest floor. Quantification of these processes and their net effect is needed. We began studying C sequestration in a planned shelterwood harvest at the Howland Forest in central Maine in 2000. The harvest took place in 2002 by the International Paper Corporation, who assisted us to track the fates of harvest products (Scott et al., 2004, Environmental Management 33: S9-S22). Here we present the results of intensive on-site studies of the decay of harvest slash, soil respiration, growth of the remaining trees, and net ecosystem exchange (NEE) of CO{sub 2} during the first six years following the harvest. These results are combined with calculations of C in persisting off-site harvest products to estimate the net C consequences to date of this commercial shelterwood harvest operation. Tower-based eddy covariance is an ideal method for this study, as it integrates all C fluxes in and out of the forest over a large 'footprint' area and can reveal how the net C flux, as well as gross primary productivity and respiration, change following harvest. Because the size of this experiment precludes large-scale replication, we are use a paired-airshed approach, similar to classic large-scale paired watershed experiments. Measurements of biomass and C fluxes in control and treatment stands were compared during a pre-treatment calibration period, and then divergence from pre-treatment relationships between the two sites measured after the harvest treatment. Forests store carbon (C) as they accumulate biomass. Many forests are also commercial sources of timber and wood fiber. In most C accounting budgets, forest harvesting is usually considered to cause a net release of C from the terrestrial biosphere to the at

  16. Technical Progress Report on Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration

    SciTech Connect (OSTI)

    Bill Stanley; Patrick Gonzalez; Sandra Brown; Jenny Henman; Ben Poulter; Sarah Woodhouse Murdock; Neil Sampson; Tim Pearson; Sarah Walker; Zoe Kant; Miguel Calmon; Gilberto Tiepolo

    2006-06-30

    The Nature Conservancy is participating in a Cooperative Agreement with the Department of Energy (DOE) National Energy Technology Laboratory (NETL) to explore the compatibility of carbon sequestration in terrestrial ecosystems and the conservation of biodiversity. The title of the research project is ''Application and Development of Appropriate Tools and Technologies for Cost-Effective Carbon Sequestration''. The objectives of the project are to: (1) improve carbon offset estimates produced in both the planning and implementation phases of projects; (2) build valid and standardized approaches to estimate project carbon benefits at a reasonable cost; and (3) lay the groundwork for implementing cost-effective projects, providing new testing ground for biodiversity protection and restoration projects that store additional atmospheric carbon. This Technical Progress Report discusses preliminary results of the six specific tasks that The Nature Conservancy is undertaking to answer research needs while facilitating the development of real projects with measurable greenhouse gas reductions. The research described in this report occurred between April 1st and July 30th 2006. The specific tasks discussed include: Task 1: carbon inventory advancements; Task 2: emerging technologies for remote sensing of terrestrial carbon; Task 3: baseline method development; Task 4: third-party technical advisory panel meetings; Task 5: new project feasibility studies; and Task 6: development of new project software screening tool. Work is being carried out in Brazil, Belize, Chile, Peru and the USA.

  17. Carbon Dioxide Sequestration Industrial-scale processes are available for separating carbon dioxide from the post-

    E-Print Network [OSTI]

    be separated using the sorbent processes currently used to remove sulfur compounds from the synthesis gas is capable of separating up to 90 percent of the carbon dioxide content of raw synthesis gas. The carbon-intensive and would lower the thermal efficiency of coal gasification power plants. Selective separation membrane

  18. MIDWEST REGIONAL CARBON SEQUESTRATION PARTNERSHIP (MRCSP) MANAGING CLIMATE CHANGE AND SECURING A FUTURE FOR THE MIDWEST'S INDUSTRIAL BASE

    SciTech Connect (OSTI)

    David Ball; Robert Burns; Judith Bradbury; Bob Dahowski; Casie Davidson; James Dooley; Neeraj Gupta; Rattan Lal; Larry Wickstrom

    2005-04-29

    This is the third semiannual report for Phase I of the Midwest Carbon Sequestration Partnership (MRCSP). The project consists of nine tasks to be conducted over a two-year period that started in October 2003. The makeup of the MRCSP and objectives are described. Progress on each of the active Tasks is also described and where possible, for those Tasks at some point of completion, a summary of results is presented.

  19. Sequestration Offsets versus Direct Emission Reductions: Consideration of Environmental Externalities

    E-Print Network [OSTI]

    McCarl, Bruce A.

    support for allocating resources to alter the market mix of carbon sequestration and direct emission carbon sequestration practices also influence the environment by for example reducing erosion1 Sequestration Offsets versus Direct Emission Reductions: Consideration of Environmental

  20. RESTORING SUSTAINABLE FORESTS ON APPALACHIAN MINED LANDS FOR WOOD PRODUCTS, RENEWABLE ENERGY, CARBON SEQUESTRATION, AND OTHER ECOSYSTEM SERVICES

    SciTech Connect (OSTI)

    James A. Burger; J. Galbraith; T. Fox; G. Amacher; J. Sullivan; C. Zipper

    2005-06-08

    The overall purpose of this project is to evaluate the biological and economic feasibility of restoring high-quality forests on mined land, and to measure carbon sequestration and wood production benefits that would be achieved from forest restoration procedures. We are currently estimating the acreage of lands in VA, WV, KY, OH, and PA mined under SMCRA and reclaimed to non-forested post-mining land uses that are not currently under active management, and therefore can be considered as available for carbon sequestration. To determine actual sequestration under different forest management scenarios, a field study was installed as a 3 x 3 factorial in a random complete block design with three replications at each of three locations, Ohio, West Virginia, and Virginia. The treatments included three forest types (white pine, hybrid poplar, mixed hardwood) and three silvicultural regimes (competition control, competition control plus tillage, competition control plus tillage plus fertilization). Each individual treatment plot is 0.5 acres. Each block of nine plots is 4.5 acres, and the complete installation at each site is 13.5 acres. During the reporting period we compiled and evaluated all soil properties measured on the study sites. Statistical analysis of the properties was conducted, and first year survival and growth of white pine, hybrid poplars, and native hardwoods was assessed. Hardwood species survived better at all sites than white pine or hybrid poplar. Hardwood survival across treatments was 80%, 85%, and 50% for sites in Virginia, West Virginia, and Ohio, respectively, while white pine survival was 27%, 41%, and 58%, and hybrid poplar survival was 37%, 41%, and 72% for the same sites, respectively. Hybrid poplar height and diameter growth were superior to those of the other species tested, with the height growth of this species reaching 126.6cm after one year in the most intensive treatment at the site in Virginia. To determine carbon in soils on these sites, we developed a cost-effective method for partitioning total soil carbon to pedogenic carbon and geogenic carbon in mine soils. We are in the process of evaluating the accuracy and precision of the proposed carbon partitioning technique for which we are designing an experiment with carefully constructed mine soil samples. In a second effort, as part of a mined land reforestation project for carbon sequestration in southwestern Virginia we implemented the first phase of the carbon monitoring protocol that was recently delivered to DOE.

  1. A model comparison initiative for a CO2 injection field test: An introduction to Sim-SEQ

    E-Print Network [OSTI]

    Mukhopadhyay, S.

    2013-01-01

    Energy's Regional Carbon Sequestration Partnerships Programimplications for carbon sequestration, Environmental Earthtrapping for geologic carbon sequestration, International

  2. Molecular interactions of SO2 with carbonate minerals under co-sequestration conditions: a combined experimental and theoretical study

    SciTech Connect (OSTI)

    Glezakou, Vassiliki Alexandra; McGrail, B. Peter; Schaef, Herbert T.

    2012-09-01

    We present a combined experimental and theoretical study investigating the reactivity between selected and morphologically important surfaces of carbonate minerals with supercritical CO2 with co-existing H2O and SO2. Trace amounts of SO2 cause formation of CaSO3 in the form of hannebachite in the initial stages of SO2 adsorption and transformation. Atomistic simulations of these initial steps indicate a somewhat catalytic activity of water, which is enhanced by the presence of Magnesium atoms in the mineral surface. Under co-sequestration conditions, traces of water are not likely to cause carbonate dissolution, however the presence of SO2 greatly stabilizes the sulfite product.

  3. Gravity monitoring of CO2 movement during sequestration: Model studies

    E-Print Network [OSTI]

    Gasperikova, E.

    2008-01-01

    potential exists for carbon sequestration and enhanced methane recovery in coalbed methane production

  4. Carbon Sequestration in Dryland and Irrigated Agroecosystems: Quantification at Different Scales for Improved Prediction

    SciTech Connect (OSTI)

    Verma, Shashi B; Cassman, Kenneth G; Arkebauer, Timothy J; Hubbard, Kenneth G; Knops, Johannes M; Suyker, Andrew E

    2012-09-14

    The overall objective of this research is to improve our basic understanding of the biophysical processes that govern C sequestration in major rainfed and irrigated agroecosystems in the north-central USA.

  5. Carbon dioxide dissolution in structural and stratigraphic traps

    E-Print Network [OSTI]

    Hesse, M. A.

    The geologic sequestration of carbon dioxide (CO[subscript 2]) in structural and stratigraphic traps is a viable option to reduce anthropogenic emissions. While dissolution of the CO[subscript 2] stored in these traps ...

  6. Final Report for the ZERT Project: Basic Science of Retention Issues, Risk Assessment & Measurement, Monitoring and Verification for Geologic Sequestration

    SciTech Connect (OSTI)

    Spangler, Lee; Cunningham, Alfred; Lageson, David; Melick, Jesse; Gardner, Mike; Dobeck, Laura; Repasky, Kevin; Shaw, Joseph; Bajura, Richard; McGrail, B Peter; Oldenburg, Curtis M; Wagoner, Jeff; Pawar, Rajesh

    2011-03-31

    ZERT has made major contributions to five main areas of sequestration science: improvement of computational tools; measurement and monitoring techniques to verify storage and track migration of CO{sub 2}; development of a comprehensive performance and risk assessment framework; fundamental geophysical, geochemical and hydrological investigations of CO{sub 2} storage; and investigate innovative, bio-based mitigation strategies.

  7. Conceptual Design of Optimized Fossil Energy Systems with Capture and Sequestration of Carbon Dioxide

    SciTech Connect (OSTI)

    Nils Johnson; Joan Ogden

    2010-12-31

    In this final report, we describe research results from Phase 2 of a technical/economic study of fossil hydrogen energy systems with carbon dioxide (CO{sub 2}) capture and storage (CCS). CO{sub 2} capture and storage, or alternatively, CO{sub 2} capture and sequestration, involves capturing CO{sub 2} from large point sources and then injecting it into deep underground reservoirs for long-term storage. By preventing CO{sub 2} emissions into the atmosphere, this technology has significant potential to reduce greenhouse gas (GHG) emissions from fossil-based facilities in the power and industrial sectors. Furthermore, the application of CCS to power plants and hydrogen production facilities can reduce CO{sub 2} emissions associated with electric vehicles (EVs) and hydrogen fuel cell vehicles (HFCVs) and, thus, can also improve GHG emissions in the transportation sector. This research specifically examines strategies for transitioning to large-scale coal-derived energy systems with CCS for both hydrogen fuel production and electricity generation. A particular emphasis is on the development of spatially-explicit modeling tools for examining how these energy systems might develop in real geographic regions. We employ an integrated modeling approach that addresses all infrastructure components involved in the transition to these energy systems. The overall objective is to better understand the system design issues and economics associated with the widespread deployment of hydrogen and CCS infrastructure in real regions. Specific objectives of this research are to: Develop improved techno-economic models for all components required for the deployment of both hydrogen and CCS infrastructure, Develop novel modeling methods that combine detailed spatial data with optimization tools to explore spatially-explicit transition strategies, Conduct regional case studies to explore how these energy systems might develop in different regions of the United States, and Examine how the design and cost of coal-based H{sub 2} and CCS infrastructure depend on geography and location.

  8. Restoring Sustainable Forests on Appalachian Mined Lands for Wood Products, Renewable Energy, Carbon Sequestration, and Other Ecosystem Services

    SciTech Connect (OSTI)

    James A. Burger; J. Galbraith; T. Fox; G. Amacher; J. Sullivan; C. Zipper

    2005-12-01

    The overall purpose of this project is to evaluate the biological and economic feasibility of restoring high-quality forests on mined land, and to measure carbon sequestration and wood production benefits that would be achieved from forest restoration procedures. We are currently estimating the acreage of lands in Virginia, West Virginia, Kentucky, Ohio, and Pennsylvania mined under SMCRA and reclaimed to non-forested post-mining land uses that are not currently under active management, and therefore can be considered as available for carbon sequestration. To determine actual sequestration under different forest management scenarios, a field study was installed as a 3 x 3 factorial in a random complete block design with three replications at each of three locations, one each in Ohio, West Virginia, and Virginia. The treatments included three forest types (white pine, hybrid poplar, mixed hardwood) and three silvicultural regimes (competition control, competition control plus tillage, competition control plus tillage plus fertilization). Each individual treatment plot is 0.5 acres. Each block of nine plots is 4.5 acres, and the complete installation at each site is 13.5 acres. Regression models of chemical and physical soil properties were created in order to estimate the SOC content down the soil profile. Soil organic carbon concentration and volumetric percent of the fines decreased exponentially down the soil profile. The results indicated that one-third of the total SOC content on mined lands was found in the surface 0-13 cm soil layer, and more than two-thirds of it was located in the 0-53 cm soil profile. A relative estimate of soil density may be best in broad-scale mine soil mapping since actual D{sub b} values are often inaccurate and difficult to obtain in rocky mine soils. Carbon sequestration potential is also a function of silvicultural practices used for reforestation success. Weed control plus tillage may be the optimum treatment for hardwoods and white pine, as any increased growth resulting from fertilization may not offset the decreased survival that accompanied fertilization. Relative to carbon value, our analysis this quarter shows that although short-rotation hardwood management on reclaimed surface mined lands may have higher LEVs than traditional long-rotation hardwood management, it is only profitable in a limited set of circumstances.

  9. Gravity monitoring of CO2 movement during sequestration: Model studies

    E-Print Network [OSTI]

    Gasperikova, E.

    2008-01-01

    COAL MODEL Significant potential exists for carbon sequestration and enhanced methane recoverycoal zones within the Lower Pennsylvanian Pottsville Formation. Assessment of the CO 2 sequestration and enhanced recovery

  10. Glaciation, aridification, and carbon sequestration in the Permo-Carboniferous: The isotopic record from low latitudes

    E-Print Network [OSTI]

    Grossman, Ethan L.

    of Geology and Geochemistry, Russian Academy of Science, Urals Branch, Pochtovyi per. 7, Ekaterinburg, Russia

  11. Predicting long-term carbon sequestration in response to CO2 enrichment: How and why do current ecosystem models differ?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Walker, Anthony P.; Zaehle, Sönke; Medlyn, Belinda E.; De Kauwe, Martin G.; Asao, Shinichi; Hickler, Thomas; Parton, William; Ricciuto, Daniel M.; Wang, Ying -Ping; Wårlind, David; et al

    2015-04-27

    Large uncertainty exists in model projections of the land carbon (C) sink response to increasing atmospheric CO2. Free-Air CO2 Enrichment (FACE) experiments lasting a decade or more have investigated ecosystem responses to a step change in atmospheric CO2 concentration. To interpret FACE results in the context of gradual increases in atmospheric CO2 over decades to centuries, we used a suite of seven models to simulate the Duke and Oak Ridge FACE experiments extended for 300 years of CO2 enrichment. We also determine key modeling assumptions that drive divergent projections of terrestrial C uptake and evaluate whether these assumptions can bemore »constrained by experimental evidence. All models simulated increased terrestrial C pools resulting from CO2 enrichment, though there was substantial variability in quasi-equilibrium C sequestration and rates of change. In two of two models that assume that plant nitrogen (N) uptake is solely a function of soil N supply, the net primary production response to elevated CO2 became progressively N limited. In four of five models that assume that N uptake is a function of both soil N supply and plant N demand, elevated CO2 led to reduced ecosystem N losses and thus progressively relaxed nitrogen limitation. Many allocation assumptions resulted in increased wood allocation relative to leaves and roots which reduced the vegetation turnover rate and increased C sequestration. Additionally, self-thinning assumptions had a substantial impact on C sequestration in two models. As a result, accurate representation of N process dynamics (in particular N uptake), allocation, and forest self-thinning is key to minimizing uncertainty in projections of future C sequestration in response to elevated atmospheric CO2.« less

  12. ECONOMIC EVALUATION OF CO2 SEQUESTRATION TECHNOLOGIES

    SciTech Connect (OSTI)

    Bert R. Bock; Richard G. Rhudy; David E. Nichols

    2001-07-01

    In order to plan for potential CO{sub 2} mitigation mandates, utilities need better information on CO{sub 2} mitigation options, especially carbon sequestration options that involve non-utility operations. One of the major difficulties in evaluating CO{sub 2} sequestration technologies and practices, both geologic storage of captured CO{sub 2} and storage in biological sinks, is obtaining consistent, transparent, accurate, and comparable economics. This project is comparing the economics of major technologies and practices under development for CO{sub 2} sequestration, including captured CO{sub 2} storage options such as active oil reservoirs, depleted oil and gas reservoirs, deep aquifers, coal beds, and oceans, as well as the enhancement of biological sinks such as forests and croplands. An international group of experts has been assembled to compare on a consistent basis the economics of this diverse array of CO{sub 2} sequestration options. Designs and data collection are nearly complete for each of the CO{sub 2} sequestration options being compared. Initial spreadsheet development has begun on concepts involving storage of captured CO{sub 2}. No significant problems have been encountered, but some additional outside expertise will be accessed to supplement the team's expertise in the areas of life cycle analysis, oil and gas exploration and production, and comparing CO{sub 2} sequestration options that differ in timing and permanence of CO{sub 2} sequestration. Plans for the next reporting period are to complete data collection and a first approximation of the spreadsheet. We expect to complete this project on time and on budget.

  13. CONCEPTUAL DESIGN OF OPTIMIZED FOSSIL ENERGY SYSTEMS WITH CAPTURE AND SEQUESTRATION OF CARBON DIOXIDE

    SciTech Connect (OSTI)

    Joan M. Ogden

    2003-06-26

    In this semi-annual progress report, we describe research results from an ongoing study of fossil hydrogen energy systems with CO{sub 2} sequestration. This work was performed under NETL Award No. DE-FC26-02NT41623, during the six-month period September 2002 through March 2003. The primary objective of the study is to better understand system design issues and economics for a large-scale fossil energy system co-producing H{sub 2} and electricity with CO{sub 2} sequestration. This is accomplished by developing analytic and simulation methods for studying the entire system in an integrated way. We examine the relationships among the different parts of a hydrogen energy system, and attempt to identify which variables are the most important in determining both the disposal cost of CO{sub 2} and the delivered cost of H{sub 2}. A second objective is to examine possible transition strategies from today's energy system toward one based on fossil-derived H{sub 2} and electricity with CO{sub 2} sequestration. We are carrying out a geographically specific case study of development of a fossil H{sub 2} system with CO{sub 2} sequestration, for the Midwestern United States, where there is presently substantial coal conversion capacity in place, coal resources are plentiful and potential sequestration sites in deep saline aquifers are widespread.

  14. Conceptual Design of Optimized Fossil Energy Systems with Capture and Sequestration of Carbon Dioxide

    SciTech Connect (OSTI)

    Joan M. Ogden

    2005-11-29

    In this final progress report, we describe research results from Phase I of a technical/economic study of fossil hydrogen energy systems with CO{sub 2} sequestration. This work was performed under NETL Award No. DE-FC26-02NT41623, during the period September 2002 through August 2005 The primary objective of the study is to better understand system design issues and economics for a large-scale fossil energy system co-producing H{sub 2} and electricity with CO{sub 2} sequestration. This is accomplished by developing analytic and simulation methods for studying the entire system in an integrated way. We examine the relationships among the different parts of a hydrogen energy system, and identify which variables are the most important in determining both the disposal cost of CO{sub 2} and the delivered cost of H{sub 2}. A second objective is to examine possible transition strategies from today's energy system toward one based on fossil-derived H{sub 2} and electricity with CO{sub 2} sequestration. We carried out a geographically specific case study of development of a fossil H{sub 2} system with CO{sub 2} sequestration, for the Midwestern United States, where there is presently substantial coal conversion capacity in place, coal resources are plentiful and potential sequestration sites in deep saline aquifers are widespread.

  15. CONCEPTUAL DESIGN OF OPTIMIZED FOSSIL ENERGY SYSTEMS WITH CAPTURE AND SEQUESTRATION OF CARBON DIOXIDE

    SciTech Connect (OSTI)

    Joan M. Ogden

    2004-05-01

    In this third semi-annual progress report, we describe research results from an ongoing study of fossil hydrogen energy systems with CO{sub 2} sequestration. This work was performed under NETL Award No. DE-FC26-02NT41623, during the six-month period September 2003 through March 2004. The primary objective of the study is to better understand system design issues and economics for a large-scale fossil energy system co-producing H{sub 2} and electricity with CO{sub 2} sequestration. This is accomplished by developing analytic and simulation methods for studying the entire system in an integrated way. We examine the relationships among the different parts of a hydrogen energy system, and attempt to identify which variables are the most important in determining both the disposal cost of CO{sub 2} and the delivered cost of H{sub 2}. A second objective is to examine possible transition strategies from today's energy system toward one based on fossil-derived H{sub 2} and electricity with CO{sub 2} sequestration. We are carrying out a geographically specific case study of development of a fossil H{sub 2} system with CO{sub 2} sequestration, for the Midwestern United States, where there is presently substantial coal conversion capacity in place, coal resources are plentiful and potential sequestration sites in deep saline aquifers are widespread.

  16. Influence of stand age on the magnitude and seasonality of carbon fluxes in Canadian forests

    E-Print Network [OSTI]

    2012-01-01

    seasons lead to less carbon sequestration by a subalpineboreal forests to global carbon sequestration (Kurz et al. ,off- set point when carbon sequestration equals carbon loss

  17. CO{sub 2} Sequestration Capacity and Associated Aspects of the Most Promising Geologic Formations in the Rocky Mountain Region: Local-Scale Analyses

    SciTech Connect (OSTI)

    Laes, Denise; Eisinger, Chris; Morgan, Craig; Rauzi, Steve; Scholle, Dana; Scott, Phyllis; Lee, Si-Yong; Zaluski, Wade; Esser, Richard; Matthews, Vince; McPherson, Brian

    2013-07-30

    The purpose of this report is to provide a summary of individual local-­?scale CCS site characterization studies conducted in Colorado, New Mexico and Utah. These site-­? specific characterization analyses were performed as part of the “Characterization of Most Promising Sequestration Formations in the Rocky Mountain Region” (RMCCS) project. The primary objective of these local-­?scale analyses is to provide a basis for regional-­?scale characterization efforts within each state. Specifically, limits on time and funding will typically inhibit CCS projects from conducting high-­? resolution characterization of a state-­?sized region, but smaller (< 10,000 km{sup 2}) site analyses are usually possible, and such can provide insight regarding limiting factors for the regional-­?scale geology. For the RMCCS project, the outcomes of these local-­?scale studies provide a starting point for future local-­?scale site characterization efforts in the Rocky Mountain region.

  18. Modeling long-term CO2 storage, sequestration and cycling

    SciTech Connect (OSTI)

    Bacon, Diana H.

    2013-11-11

    The application of numerical and analytical models to the problem of storage, sequestration and migration of carbon dioxide in geologic formations is discussed. A review of numerical and analytical models that have been applied to CO2 sequestration are presented, as well as a description of frameworks for risk analysis. Application of models to various issues related to carbon sequestration are discussed, including trapping mechanisms, density convection mixing, impurities in the CO2 stream, changes in formation porosity and permeability, the risk of vertical leakage, and the impacts on groundwater resources if leakage does occur. A discussion of the development and application of site-specific models first addresses the estimation of model parameters and the use of natural analogues to inform the development of CO2 sequestration models, and then surveys modeling that has been done at two commercial-scale CO2 sequestration sites, Sleipner and In Salah, along with a pilot-scale injection sites used to study CO2 sequestration in saline aquifers (Frio) and an experimental site designed to test monitoring of CO2 leakage in the vadose zone (ZERT Release Facility).

  19. Carbon calculator tracks the climate benefits of managed private forests

    E-Print Network [OSTI]

    Stewart, William C; Sharma, Benktesh D

    2015-01-01

    forests provide more carbon sequestration benefits than let-the relative carbon sequestration benefits of let-growlife cycle carbon sequestration benefits, averaged over 120,

  20. Climate control of terrestrial carbon exchange across biomes and continents

    E-Print Network [OSTI]

    Yi, C.; Ricciuota, D.; Goulden, M. L.

    2010-01-01

    control, terrestrial carbon sequestration, temperature,on terrestrial carbon sequestration (Nemani et al 2003, Xiaodeposition and forest carbon sequestration Glob. Change

  1. The significance of the erosion-induced terrestrial carbon sink

    E-Print Network [OSTI]

    Berhe, A.A.; Harte, J.; Harden, J.W.; Torn, M.S.

    2006-01-01

    potential of soil carbon sequestration to mitigate theof soil movement on carbon sequestration in agriculturalEnhancement of carbon sequestration in US soils. BioScience.

  2. O P I N I O N Biogenic vs. geologic carbon emissions and forest

    E-Print Network [OSTI]

    Keeton, William S.

    O P I N I O N Biogenic vs. geologic carbon emissions and forest biomass energy production J O H N- versities articulated a concern over equating biogenic carbon (C) emissions with fossil fuel emissions the amount of carbon in circulation. In contrast, carbon dioxide released from fossil fuels increases

  3. RANGELAND SEQUESTRATION POTENTIAL ASSESSMENT

    SciTech Connect (OSTI)

    Lee Spangler; George F. Vance; Gerald E. Schuman; Justin D. Derner

    2012-03-31

    Rangelands occupy approximately half of the world's land area and store greater than 10% of the terrestrial biomass carbon and up to 30% of the global soil organic carbon. Although soil carbon sequestration rates are generally low on rangelands in comparison to croplands, increases in terrestrial carbon in rangelands resulting from management can account for significant carbon sequestration given the magnitude of this land resource. Despite the significance rangelands can play in carbon sequestration, our understanding remains limited. Researchers conducted a literature review to identify sustainably management practices that conserve existing rangeland carbon pools, as well as increase or restore carbon sequestration potentials for this type of ecosystem. The research team also reviewed the impact of grazing management on rangeland carbon dynamics, which are not well understood due to heterogeneity in grassland types. The literature review on the impact of grazing showed a wide variation of results, ranging from positive to negative to no response. On further review, the intensity of grazing appears to be a major factor in controlling rangeland soil organic carbon dynamics. In 2003, researchers conducted field sampling to assess the effect of several drought years during the period 1993-2002. Results suggested that drought can significantly impact rangeland soil organic carbon (SOC) levels, and therefore, carbon sequestration. Resampling was conducted in 2006; results again suggested that climatic conditions may have overridden management effects on SOC due to the ecological lag of the severe drought of 2002. Analysis of grazing practices during this research effort suggested that there are beneficial effects of light grazing compared to heavy grazing and non-grazing with respect to increased SOC and nitrogen contents. In general, carbon storage in rangelands also increases with increased precipitation, although researchers identified threshold levels of precipitation where sequestration begins to decrease.

  4. Comparison of caprock pore networks which potentially will be impacted by carbon sequestration projects.

    SciTech Connect (OSTI)

    McCray, John (Colorado School of Mines); Navarre-Sitchler, Alexis (Colorado School of Mines); Mouzakis, Katherine (Colorado School of Mines); Heath, Jason E.; Dewers, Thomas A.; Rother, Gernot (Oak Ridge National Laboratory)

    2010-12-01

    Injection of CO2 into underground rock formations can reduce atmospheric CO2 emissions. Caprocks present above potential storage formations are the main structural trap inhibiting CO2 from leaking into overlying aquifers or back to the Earth's surface. Dissolution and precipitation of caprock minerals resulting from reaction with CO2 may alter the pore network where many pores are of the micrometer to nanometer scale, thus altering the structural trapping potential of the caprock. However, the distribution, geometry and volume of pores at these scales are poorly characterized. In order to evaluate the overall risk of leakage of CO2 from storage formations, a first critical step is understanding the distribution and shape of pores in a variety of different caprocks. As the caprock is often comprised of mudstones, we analyzed samples from several mudstone formations with small angle neutron scattering (SANS) and high-resolution transmission electron microscopy (TEM) imaging to compare the pore networks. Mudstones were chosen from current or potential sites for carbon sequestration projects including the Marine Tuscaloosa Group, the Lower Tuscaloosa Group, the upper and lower shale members of the Kirtland Formation, and the Pennsylvanian Gothic shale. Expandable clay contents ranged from 10% to approximately 40% in the Gothic shale and Kirtland Formation, respectively. During SANS, neutrons effectively scatter from interfaces between materials with differing scattering length density (i.e., minerals and pores). The intensity of scattered neutrons, I(Q), where Q is the scattering vector, gives information about the volume and arrangement of pores in the sample. The slope of the scattering data when plotted as log I(Q) vs. log Q provides information about the fractality or geometry of the pore network. On such plots slopes from -2 to -3 represent mass fractals while slopes from -3 to -4 represent surface fractals. Scattering data showed surface fractal dimensions for the Kirtland formation and one sample from the Tuscaloosa formation close to 3, indicating very rough surfaces. In contrast, scattering data for the Gothic shale formation exhibited mass fractal behavior. In one sample of the Tuscaloosa formation the data are described by a surface fractal at low Q (larger pores) and a mass fractal at high Q (smaller pores), indicating two pore populations contributing to the scattering behavior. These small angle neutron scattering results, combined with high-resolution TEM imaging, provided a means for both qualitative and quantitative analysis of the differences in pore networks between these various mudstones.

  5. Public Review Draft: A Method for Assessing Carbon Stocks, Carbon

    E-Print Network [OSTI]

    Public Review Draft: A Method for Assessing Carbon Stocks, Carbon Sequestration, and Greenhouse, and Zhu, Zhiliang, 2010, Public review draft; A method for assessing carbon stocks, carbon sequestration

  6. Sequestration Options for the West Coast States

    SciTech Connect (OSTI)

    Myer, Larry

    2006-04-30

    The West Coast Regional Carbon Sequestration Partnership (WESTCARB) is one of seven partnerships that have been established by the U.S. Department of Energy (DOE) to evaluate carbon capture and sequestration (CCS) technologies best suited for different regions of the country. The West Coast Region comprises Arizona, California, Nevada, Oregon, Washington, Alaska, and British Columbia. Led by the California Energy Commission, WESTCARB is a consortium of about 70 organizations, including state natural resource and environmental protection agencies; national laboratories and universities; private companies working on carbon dioxide (CO{sub 2}) capture, transportation, and storage technologies; utilities; oil and gas companies; nonprofit organizations; and policy/governance coordinating organizations. Both terrestrial and geologic sequestration options were evaluated in the Region during the 18-month Phase I project. A centralized Geographic Information System (GIS) database of stationary source, geologic and terrestrial sink data was developed. The GIS layer of source locations was attributed with CO{sub 2} emissions and other data and a spreadsheet was developed to estimate capture costs for the sources in the region. Phase I characterization of regional geological sinks shows that geologic storage opportunities exist in the WESTCARB region in each of the major technology areas: saline formations, oil and gas reservoirs, and coal beds. California offers outstanding sequestration opportunities because of its large capacity and the potential of value-added benefits from enhanced oil recovery (EOR) and enhanced gas recovery. The estimate for storage capacity of saline formations in the ten largest basins in California ranges from about 150 to about 500 Gt of CO{sub 2}, the potential CO{sub 2}-EOR storage was estimated to be 3.4 Gt, and the cumulative production from gas reservoirs suggests a CO{sub 2} storage capacity of 1.7 Gt. A GIS-based method for source-sink matching was implemented and preliminary marginal cost curves developed, which showed that 20, 40, or 80 Mega tonnes (Mt) of CO{sub 2} per year could be sequestered in California at a cost of $31/tonne (t), $35/t, or $50/t, respectively. Phase I also addressed key issues affecting deployment of CCS technologies, including storage-site monitoring, injection regulations, and health and environmental risks. A framework for screening and ranking candidate sites for geologic CO{sub 2} storage on the basis of HSE risk was developed. A webbased, state-by-state compilation of current regulations for injection wells, and permits/contracts for land use changes, was developed, and modeling studies were carried out to assess the application of a number of different geophysical techniques for monitoring geologic sequestration. Public outreach activities resulted in heightened awareness of sequestration among state, community and industry leaders in the Region. Assessment of the changes in carbon stocks in agricultural lands showed that Washington, Oregon and Arizona were CO{sub 2} sources for the period from 1987 to 1997. Over the same period, forest carbon stocks decreased in Washington, but increased in Oregon and Arizona. Results of the terrestrial supply curve analyses showed that afforestation of rangelands and crop lands offer major sequestration opportunities; at a price of $20 per t CO{sub 2}, more than 1,233 MMT could be sequestered over 40-years in Washington and more than 1,813 MMT could be sequestered in Oregon.

  7. Estimation of Carbon Sequestration by Combining Remote Sensing and Net Ecosystem Exchange

    E-Print Network [OSTI]

    Hunt Jr., E. Raymond

    be used to estimate car- bon sequestration regionally in rangeland ecosystems. Natural resource management may be altered to offset CO2 emissions from fossil fuels (Paustian and others 1998, Follett and others offsets of CO2 emissions (Follett and oth- ers 2001). Because the landscape is extremely hetero- geneous

  8. Sustainable Carbon Sequestration: Increasing CO2-Storage Efficiency through a CO2-Brine Displacement Approach 

    E-Print Network [OSTI]

    Akinnikawe, Oyewande

    2012-10-19

    CO2 sequestration is one of the proposed methods for reducing anthropogenic CO2 emissions to the atmosphere and therefore mitigating global climate change. Few studies on storing CO2 in an aquifer have been conducted on a regional scale. This study...

  9. Investigating the Fundamental Scientific Issues Affecting the Long-term Geologic Storage of Carbon Dioxide

    SciTech Connect (OSTI)

    Spangler, Lee; Cunningham, Alfred; Barnhart, Elliot; Lageson, David; Nall, Anita; Dobeck, Laura; Repasky, Kevin; Shaw, Joseph; Nugent, Paul; Johnson, Jennifer; Hogan, Justin; Codd, Sarah; Bray, Joshua; Prather, Cody; McGrail, B.; Oldenburg, Curtis; Wagoner, Jeff; Pawar, Rajesh

    2014-09-30

    The Zero Emissions Research and Technology (ZERT) collaborative was formed to address basic science and engineering knowledge gaps relevant to geologic carbon sequestration. The original funding round of ZERT (ZERT I) identified and addressed many of these gaps. ZERT II has focused on specific science and technology areas identified in ZERT I that showed strong promise and needed greater effort to fully develop. Specific focal areas of ZERT II included: ? Continued use of the unique ZERT field site to test and prove detection technologies and methods developed by Montana State University, Stanford, University of Texas, several private sector companies, and others. Additionally, transport in the near surface was modelled. ? Further development of near-surface detection technologies that cover moderate area at relatively low cost (fiber sensors and compact infrared imagers). ? Investigation of analogs for escape mechanisms including characterization of impact of CO2 and deeper brine on groundwater quality at a natural analog site in Chimayo, NM and characterization of fracture systems exposed in outcrops in the northern Rockies. ? Further investigation of biofilms and biomineralization for mitigation of small aperture leaks focusing on fundamental studies of rates that would allow engineered control of deposition in the subsurface. ? Development of magnetic resonance techniques to perform muti-phase fluid measurements in rock cores. ? Laboratory investigation of hysteretic relative permeability and its effect on residual gas trapping in large-scale reservoir simulations. ? Further development of computational tools including a new version (V2) of the LBNL reactive geochemical transport simulator, TOUGHREACT, extension of the coupled flow and stress simulation capabilities in LANL’s FEHM simulator and an online gas-mixtureproperty estimation tool, WebGasEOS Many of these efforts have resulted in technologies that are being utilized in other field tests or demonstration projects.

  10. GENETIC MODIFICATION OF GIBBERELLIC ACID SIGNALING TO PROMOTE CARBON SEQUESTRATION IN TREE ROOTS AND STEMS

    SciTech Connect (OSTI)

    Busov, Victor

    2013-03-05

    Semidwarfism has been used extensively in row crops and horticulture to promote yield, reduce lodging, and improve harvest index, and it might have similar benefits for trees for short-rotation forestry or energy plantations, reclamation, phytoremediation, or other applications. We studied the effects of the dominant semidwarfism transgenes GA Insensitive (GAI) and Repressor of GAI-Like, which affect gibberellin (GA) action, and the GA catabolic gene, GA 2-oxidase, in nursery beds and in 2-year-old high-density stands of hybrid poplar (Populus tremula ? Populus alba). Twenty-nine traits were analyzed, including measures of growth, morphology, and physiology. Endogenous GA levels were modified in most transgenic events; GA(20) and GA(8), in particular, had strong inverse associations with tree height. Nearly all measured traits varied significantly among genotypes, and several traits interacted with planting density, including aboveground biomass, root-shoot ratio, root fraction, branch angle, and crown depth. Semidwarfism promoted biomass allocation to roots over shoots and substantially increased rooting efficiency with most genes tested. The increased root proportion and increased leaf chlorophyll levels were associated with changes in leaf carbon isotope discrimination, indicating altered water use efficiency. Semidwarf trees had dramatically reduced growth when in direct competition with wild-type trees, supporting the hypothesis that semidwarfism genes could be effective tools to mitigate the spread of exotic, hybrid, and transgenic plants in wild and feral populations. We modified gibberellin (GA) metabolism and signaling in transgenic poplars using dominant transgenes and studied their effects for 3 years under field conditions. The transgenes that we employed either reduced the bioactive GAs, or attenuated their signaling. The majority of transgenic trees had significant and in many cases dramatic changes in height, crown architecture, foliage morphology, flowering onset, floral structure, and vegetative phenology. Most transgenes elicited various levels of height reduction consistent with the roles of GA in elongation growth. Several other growth traits were proportionally reduced, including branch length, internode distance, and leaf length. In contrast to elongation growth, stem diameter growth was much less affected, suggesting that semi-dwarf trees in dense stands might provide high levels of biomass production and carbon sequestration. The severity of phenotypic effects was strongly correlated with transgene expression among independent transgenic events, but often in a non-linear manner, the form of which varied widely among constructs. The majority of semi-dwarfed, transgenic plants showed delayed bud flush and early bud set, and expression of a native GAI transgene accelerated first time flowering in the field. All of the phenotypic changes observed in multiple years were stable over the 3 years of field study. Our results suggest that transgenic modification of GA action may be useful for producing semi-dwarf trees with modified growth and morphology for horticulture and other uses. We studied the poplar C(19) gibberellin 2-oxidase (GA2ox) gene subfamily. We show that a set of paralogous gene pairs differentially regulate shoot and root development. ? PtGA2ox4 and its paralogous gene PtGA2ox5 are primarily expressed in aerial organs, and overexpression of PtGA2ox5 produced a strong dwarfing phenotype characteristic of GA deficiency. Suppression of PtGA2ox4 and PtGA2ox5 led to increased biomass growth, but had no effect on root development. By contrast, the PtGA2ox2 and PtGA2ox7 paralogous pair was predominantly expressed in roots, and when these two genes were RNAi-suppressed it led to a decrease of root biomass. ? The morphological changes in the transgenic plants were underpinned by tissue-specific increases in bioactive GAs that corresponded to the predominant native expression of the targeted paralogous gene pair. Although RNAi suppression of both paralogous pairs led to changes in wood developmen

  11. CARBON MITIGATION HS 2014 Prof. Nicolas Gruber

    E-Print Network [OSTI]

    Fischlin, Andreas

    CARBON MITIGATION HS 2014 Prof. Nicolas Gruber Mondays 10-12, CHN E42 (nicolas & Introduction (Gruber) Introduction to the carbon mitigation problem 9/22 2 Geological CO2 sequestration (Mazzotti) Putting the CO2 underground... 9/29 3 No class ­ group formation 10/06 4 Carbon sinks on land

  12. Restoring Sustainable Forests on Appalachian Mined Lands for Wood Products, Renewable Energy, Carbon Sequestration, and Other Ecosystem Services

    SciTech Connect (OSTI)

    Burger, James A

    2005-07-20

    The overall purpose of this project is to evaluate the biological and economic feasibility of restoring high-quality forests on mined land, and to measure carbon sequestration and wood production benefits that would be achieved from forest restoration procedures. We are currently estimating the acreage of lands in Virginia, West Virginia, Kentucky, Ohio, and Pennsylvania mined under SMCRA and reclaimed to non-forested post-mining land uses that are not currently under active management, and therefore can be considered as available for carbon sequestration. To determine actual sequestration under different forest management scenarios, a field study was installed as a 3 x 3 factorial in a random complete block design with three replications at each of three locations, one each in Ohio, West Virginia, and Virginia. The treatments included three forest types (white pine, hybrid poplar, mixed hardwood) and three silvicultural regimes (competition control, competition control plus tillage, competition control plus tillage plus fertilization). Each individual treatment plot is 0.5 acres. Each block of nine plots is 4.5 acres, and the complete installation at each site is 13.5 acres. During the reporting period we determined that by grinding the soil samples to a finer particle size of less than 250 ?m (sieve No. 60), the effect of mine soil coal particle size on the extent to which these particles will be oxidized during the thermal treatment of the carbon partitioning procedure will be eliminated, thus making the procedure more accurate and precise. In the second phase of the carbon sequestration project, we focused our attention on determining the sample size required for carbon accounting on grassland mined fields in order to achieve a desired accuracy and precision of the final soil organic carbon (SOC) estimate. A mine land site quality classification scheme was developed and some field-testing of the methods of implementation was completed. The classification model has been validated for softwoods (white pine) on several reclaimed mine sites in the southern Appalachian coal region. The classification model is a viable method for classifying post-SMCRA abandoned mined lands into productivity classes for white pine. A thinning study was established as a random complete block design to evaluate the response to thinning of a 26-year-old white pine stand growing on a reclaimed surface mine in southwest Virginia. Stand parameters were projected to age 30 using a stand table projection. Site index of the stand was found to be 32.3 m at base age 50 years. Thinning rapidly increased the diameter growth of the residual trees to 0.84 cm yr{sup -1} compared to 0.58 cm yr{sup -1} for the unthinned treatment; however, at age 26, there was no difference in volume or value per hectare. At age 30, the unthinned treatment had a volume of 457.1 m{sup 3} ha{sup -1} but was only worth $8807 ha{sup -1}, while the thinned treatment was projected to have 465.8 m{sup 3} ha{sup -1}, which was worth $11265 ha{sup -1} due to a larger percentage of the volume being in sawtimber size classes.

  13. Developing microbe-plant interactions for applications in plant-growth promotion and disease control, production of useful compounds, remediation, and carbon sequestration

    SciTech Connect (OSTI)

    Wu, C.H.; Bernard, S.; Andersen, G.L.; Chen, W.

    2009-03-01

    Interactions between plants and microbes are an integral part of our terrestrial ecosystem. Microbe-plant interactions are being applied in many areas. In this review, we present recent reports of applications in the areas of plant-growth promotion, biocontrol, bioactive compound and biomaterial production, remediation and carbon sequestration. Challenges, limitations and future outlook for each field are discussed.

  14. Carbon capture and storage in geologic formations has been proposed as a global warming mitigation strategy

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Abstract Carbon capture and storage in geologic formations has been proposed as a global warming mitigation strategy that can contribute to stabilize the atmospheric concentration of carbon dioxide to maintain adsorbed methane in the coalbed formation. But now carbon dioxide will replace the methane

  15. Geologic Sequestration of CO2 in Deep, Unmineable Coalbeds: An Integrated Researdh and Commercial-Scale Field Demonstration Project

    SciTech Connect (OSTI)

    Scott Reeves; George Koperna

    2008-09-30

    The Coal-Seq consortium is a government-industry collaborative consortium with the objective of advancing industry's understanding of complex coalbed methane and gas shale reservoir behavior in the presence of multi-component gases via laboratory experiments, theoretical model development and field validation studies. This will allow primary recovery, enhanced recovery and CO{sub 2} sequestration operations to be commercially enhanced and/or economically deployed. The project was initially launched in 2000 as a U.S. Department of Energy sponsored investigation into CO{sub 2} sequestration in deep, unmineable coalseams. The initial project accomplished a number of important objectives, which mainly revolved around performing baseline experimental studies, documenting and analyzing existing field projects, and establishing a global network for technology exchange. The results from that Phase have been documented in a series of reports which are publicly available. An important outcome of the initial phase was that serious limitations were uncovered in our knowledge of reservoir behavior when CO{sub 2} is injected into coal. To address these limitations, the project was extended in 2005 as a government-industry collaborative consortium. Selected accomplishments from this phase have included the identification and/or development of new models for multi-component sorption and diffusion, laboratory studies of coal geomechanical and permeability behavior with CO{sub 2} injection, additional field validation studies, and continued global technology exchange. Further continuation of the consortium is currently being considered. Some of the topics that have been identified for investigation include further model development/refinement related to multicomponent equations-of-state, sorption and diffusion behavior, geomechanical and permeability studies, technical and economic feasibility studies for major international coal basins, the extension of the work to gas shale reservoirs, and continued global technology exchange.

  16. An Evaluation of the Carbon Sequestration Potential of the Cambro-Ordovician Strata of the Illinois and Michigan Basins

    SciTech Connect (OSTI)

    Kirksey, Jim; Ansari, Sajjad; Malkewicz, Nick; Leetaru, Hannes

    2014-01-01

    The Knox Supergroup is a significant part of the Cambrian-Ordovician age sedimentary deposition in the Illinois Basin. While there is a very small amount of oil production associated with the upper Knox, it is more commonly used as a zone for both Class I and Class II disposal wells in certain areas around the state. Based on the three penetrations of the Knox Formation at the Illinois Basin – Decatur Project (IBDP) carbon dioxide (CO2) sequestration site in Macon County, Illinois, there is potential for certain zones in the Knox to be used for CO2 sequestration. More specifically, the Potosi member of the Knox Formation at about –3,670 feet (ft) subsea depth would be a candidate as all three penetrations had massive circulation losses while drilling through this interval. Each well required the setting of cement plugs to regain wellbore stability so that the intermediate casing could be set and successfully cemented to surface. Log and core analysis suggests significant karst porosity throughout the Potosi member. The purpose of this study is to develop a well plan for the drilling of a CO2 injection well with the capability to inject 3.5 million tons per annum (3.2 million tonnes per annum [MTPA] CO2 into the Knox Formation over a period of 30 years.

  17. RESTORING SUSTAINABLE FORESTS ON APPALACHIAN MINED LANDS FOR WOOD PRODUCTS, RENEWABLE ENERGY, CARBON SEQUESTRATION, AND OTHER ECOSYSTEM SERVICES

    SciTech Connect (OSTI)

    James A. Burger; J. Galbraith; T. Fox; G. Amacher; J. Sullivan; C. Zipper

    2005-02-15

    The overall purpose of this project is to evaluate the biological and economic feasibility of restoring high-quality forests on mined land, and to measure carbon sequestration and wood production benefits that would be achieved from forest restoration procedures. During the reporting period (October-December 2004) we completed the validation of a forest productivity classification model for mined land. A coefficient of determination (R{sup 2}) of 0.68 confirms the model's ability to predict SI based on a selection of mine soil properties. To determine carbon sequestration under different forest management scenarios, a field study was installed as a 3 x 3 factorial in a random complete block design with three replications at each of three locations, Ohio (Figure 1), West Virginia (Figure 2), and Virginia (Figure 3). The treatments included three forest types (white pine, hybrid poplar, mixed hardwood) and three silvicultural regimes (competition control, competition control plus tillage, competition control plus tillage plus fertilization). For hybrid poplar, total plant biomass differences increased significantly with the intensity of silvicultural input. Root, stem, and foliage biomass also increased with the level of silvicultural intensity. Financial feasibility analyses of reforestation on mined lands previously reclaimed to grassland have been completed for conversion to white pine and mixed hardwood species. Examination of potential policy instruments for promoting financial feasibility also have been completed, including lump sum payments at time of conversion, annual payments through the life of the stand, and payments based on carbon sequestration that provide both minimal profitability and fully offset initial reforestation outlays. We have compiled a database containing mine permit information obtained from permitting agencies in Virginia, West Virginia, Pennsylvania, Ohio, and Kentucky. Due to differences and irregularities in permitting procedures between states, we found it necessary to utilize an alternative method to determine mined land acreages in the Appalachian region. We have initiated a proof of concept study, focused in the State of Ohio, to determine the feasibility of using images from the Landsat Thematic Mapper (TM) and/or Enhanced Thematic Mapper Plus (ETM+) to accurately identify mined lands.

  18. Pressure perturbations from geologic carbon sequestration: Area-of-review boundaries and borehole leakage driving forces

    E-Print Network [OSTI]

    Nicot, J.-P.

    2010-01-01

    geothermal gradient is 30°C/km; vertical lines represent possible water density profiles in a borehole:

  19. Relevance of underground natural gas storage to geologic sequestration of carbon dioxide

    E-Print Network [OSTI]

    Lippmann, Marcelo J.; Benson, Sally M.

    2002-01-01

    Underground Storage of Natural Gas in the United States andEnergy Information Agency (2002). U.S. Natural Gas Storage.www.eia.doe.gov/oil_gas/natural_gas/info_glance/storage.html

  20. Relevance of underground natural gas storage to geologic sequestration of carbon dioxide

    E-Print Network [OSTI]

    Lippmann, Marcelo J.; Benson, Sally M.

    2002-01-01

    http://www.eia.doe.gov/oil_gas/natural_gas/info_glance/underground in depleted oil and gas reservoirs and brinestorage projects. Depleted oil and gas reservoirs and brine