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Sample records for geochemical interpretation cxs

  1. Geochemical and Isotopic Interpretations of Groundwater Flow in the Oasis Valley Flow System, Southern Nevada

    SciTech Connect (OSTI)

    J.M. Thomas; F.C. Benedict, Jr.; T.P. Rose; R.L. Hershey; J.B. Paces; Z.E. Peterman; I.M. Farnham; K.H. Johannesson; A.K. Singh; K.J. Stetzenbach; G.B. Hudson; J.M. Kenneally; G.F. Eaton; D.K. Smith

    2003-01-08

    This report summarizes the findings of a geochemical investigation of the Pahute Mesa-Oasis Valley groundwater flow system in southwestern Nevada. It is intended to provide geochemical data and interpretations in support of flow and contaminant transport modeling for the Western and Central Pahute Mesa Corrective Action Units.

  2. HBH-GEOCHEM-GEOPHY

    Energy Science and Technology Software Center (OSTI)

    003015WKSTN00 Hiereachical Bayesian Model for Combining Geochemical and Geophysical Data for Environmental Applications Software

  3. Geochemical Reaction Mechanism Discovery from Molecular Simulation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stack, Andrew G.; Kent, Paul R. C.

    2014-11-10

    Methods to explore reactions using computer simulation are becoming increasingly quantitative, versatile, and robust. In this review, a rationale for how molecular simulation can help build better geochemical kinetics models is first given. We summarize some common methods that geochemists use to simulate reaction mechanisms, specifically classical molecular dynamics and quantum chemical methods and discuss their strengths and weaknesses. Useful tools such as umbrella sampling and metadynamics that enable one to explore reactions are discussed. Several case studies wherein geochemists have used these tools to understand reaction mechanisms are presented, including water exchange and sorption on aqueous species and mineralmore » surfaces, surface charging, crystal growth and dissolution, and electron transfer. The impact that molecular simulation has had on our understanding of geochemical reactivity are highlighted in each case. In the future, it is anticipated that molecular simulation of geochemical reaction mechanisms will become more commonplace as a tool to validate and interpret experimental data, and provide a check on the plausibility of geochemical kinetic models.« less

  4. Aging and the geochemical environment

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    This report describes and assesses the aging process and related environmental aspects that may provide useful insights toward postponing some of the inevitable effects of aging. Although the Panel on Aging and the Geochemical Environment is convinced that the geochemical environment is associated with aging, it of course recognizes that other factors may also be significant or, perhaps, more important. Accordingly, the report is intended to enhance the awareness of biomedical and geochemical research scientists, decision makers in related areas, and the lay public interested in an understanding of the relation of the geochemical environment to senescence.

  5. Geochemical Speciation Mass Transfer

    Energy Science and Technology Software Center (OSTI)

    1985-12-01

    PHREEQC is designed to model geochemical reactions. Based on an ion association aqueous model, PHREEQC can calculate pH, redox potential, and mass transfer as a function of reaction progress. It can be used to describe geochemical processes for both far-field and near-field performance assessment and to evaluate data acquisition needs and test data. It can also calculate the composition of solutions in equilibrium with multiple phases. The data base, including elements, aqueous species, and mineralmore » phases, is independent of the program and is completely user-definable. PHREEQC requires thermodynamic data for each solid, gaseous, or dissolved chemical species being modeled. The two data bases, PREPHR and DEQPAK7, supplied with PHREEQC are for testing purposes only and should not be applied to real problems without first being carefully examined. The conceptual model embodied in PHREEQC is the ion-association model of Pearson and Noronha. In this model a set of mass action equations are established for each ion pair (and controlling solid phases when making mass transfer calculations) along with a set of mass balance equations for each element considered. These sets of equations are coupled using activity coefficient values for each aqueous species and solved using a continued fraction approach for the mass balances combined with a modified Newton-Raphson technique for all other equations. The activity coefficient expressions in PHREEQC include the extended Debye-Huckel, WATEQ Debye-Huckel, and Davies equations from the original United States Geological Survey version of the program. The auxiliary preprocessor program PHTL, which is derived from EQTL, converts EQ3/6 thermodynamic data to PHREEQC format so that the two programs can be compared. PHREEQC can be used to determine solubility limits on the radionuclides present in the waste form. These solubility constraints may be input to the WAPPA leach model.« less

  6. Category:Geochemical Techniques | Open Energy Information

    Open Energy Info (EERE)

    Techniques Technique Subcategories This category has only the following subcategory. G + Geochemical Data Analysis (2 categories) 4 pages Pages in category "Geochemical...

  7. Novel Coupled Thermochronometric and Geochemical Investigation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Novel Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners Novel Coupled Thermochronometric and Geochemical ...

  8. Aging and the geochemical environment

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    The report describes and assesses the aging process and related environmental aspects. Specific geographic areas of increased and decreased longevity were identified and geochemically characterized in terms of surface rocks, drinking water quality, soils, and abnormal absorption of trace elements by plants. Environmental factors that may be related to increased longevity are discussed. 11 references, 32 figures, 8 tables. (ACR)

  9. EQ3/6 A Software Package for Geochemical Modeling

    Energy Science and Technology Software Center (OSTI)

    2010-12-13

    EQ3/6 is a software package for modeling geochemical interactions between aqueous solution, solids, and gases, following principles of chemical thermodynamics and chemical kinetics. It is useful for interpreting aqueiou solution chemical compositions and for calculating the consequences of reaction of such solutions with minerals, other solids, and gases. It is designed to run in a command line environment. EQPT is a thermodynamic data file preprocessor. EQ3NR is a speciation-solubility code. EQ6 is a reaction pathmore » code.« less

  10. Interface Induced Carbonate Mineralization: A Fundamental Geochemical

    Office of Scientific and Technical Information (OSTI)

    Process Relevant to Carbon Sequestration (Technical Report) | SciTech Connect Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Citation Details In-Document Search Title: Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration We have approached the long-standing geochemical question why anhydrous high-Mg carbonate minerals (i.e., magnesite and dolomite) cannot be formed at

  11. Geochemical Data Analysis | Open Energy Information

    Open Energy Info (EERE)

    Information Provided by Technique Lithology: StratigraphicStructural: Hydrological: Thermal: Dictionary.png Geochemical Data Analysis: No definition has been provided for...

  12. Interface Induced Carbonate Mineralization: A Fundamental Geochemical

    Office of Scientific and Technical Information (OSTI)

    Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Teng, H. Henry PI, The George Washington University PI, The George...

  13. Interface Induced Carbonate Mineralization: A Fundamental Geochemical...

    Office of Scientific and Technical Information (OSTI)

    Sequestration We have approached the long-standing geochemical question why ... prevents Mgsup 2+ and COsub 3sup 2- ions from forming long-range ordered structures. ...

  14. Interface Induced Carbonate Mineralization: A Fundamental Geochemical

    Office of Scientific and Technical Information (OSTI)

    Process Relevant to Carbon Sequestration (Technical Report) | SciTech Connect Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Citation Details In-Document Search Title: Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Mica, biotite, muscovite, diopside, tremolite, ultramafic rock, hematite, Ca-Mg-carbonate, calcite, aragonite, dolomite, crystal nucleation,

  15. Application Of Geochemical Methods In The Search For Geothermal...

    Open Energy Info (EERE)

    Geochemical Methods In The Search For Geothermal Fields Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Application Of Geochemical Methods In...

  16. Book Review - Geochemical Exploration 1982 | Open Energy Information

    Open Energy Info (EERE)

    Book Review - Geochemical Exploration 1982 Jump to: navigation, search OpenEI Reference LibraryAdd to library Book Review: Book Review - Geochemical Exploration 1982 Author R. A....

  17. Geochemical Modeling Of Aqueous Systems

    Energy Science and Technology Software Center (OSTI)

    1995-09-07

    EQ3/6 is a software package for geochemical modeling of aqueous systems. This description pertains to version 7.2b. It addresses aqueous speciation, thermodynamic equilibrium, disequilibrium, and chemical kinetics. The major components of the package are EQ3NR, a speciation-solubility code, and EQ6 a reaction path code. EQ3NR is useful for analyzing groundwater chemistry data, calculating solubility limits, and determining whether certain reactions are in states of equilibrium or disequilibrium. It also initializes EQ6 calculations. EQ6 models themore » consequences of reacting an aqueous solution with a specified set of reactants (e.g., minerals or waste forms). It can also model fluid mixing and the effects of changes in temperature. Each of five supporting data files contain both standard state and activity coefficient-related data. Three support the use of the Davies or B-dot equations for the activity coefficients; the other two support the use of Pitzer''s equations. The temperature range of the thermodynamic data on the data files varies from 25 degrees C only to 0-300 degrees C.« less

  18. Geothermal/Geochemical Database | Open Energy Information

    Open Energy Info (EERE)

    to library Chart: GeothermalGeochemical DatabaseInfo GraphicMapChart Author Nevada Bureau of Mines and Geology Published Nevada Bureau of Mines and Geology, 2012 DOI Not...

  19. Nanogeochemistry: Geochemical reactions and mass transfers in...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Nanogeochemistry: Geochemical reactions and mass transfers in nanopores ... OSTI Identifier: 913493 Report Number(s): SAND2003-0369J Journal ID: ISSN 0091-7613; TRN: ...

  20. SECTION III: INTERPRETATIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7.0 - INTERPRETATIONS February 28, 2012 Rev 1 Page 1 CHAPTER 17.0 TABLE OF CONTENTS TABLE OF CONTENTS ........................................................................................................................................ 1 17.0 INTERPRETATIONS ..................................................................................................................................... 3 17.1 Scope

  1. Geochemical Enhancement Of Enhanced Geothermal System Reservoirs: An Integrated Field And Geochemical Approach

    SciTech Connect (OSTI)

    Joseph N. Moore

    2007-12-31

    The geochemical effects of injecting fluids into geothermal reservoirs are poorly understood and may be significantly underestimated. Decreased performance of injection wells has been observed in several geothermal fields after only a few years of service, but the reasons for these declines has not been established. This study had three primary objectives: 1) determine the cause(s) of the loss of injectivity; 2) utilize these observations to constrain numerical models of water-rock interactions; and 3) develop injection strategies for mitigating and reversing the potential effects of these interactions. In this study rock samples from original and redrilled injection wells at Coso and the Salton Sea geothermal fields, CA, were used to characterize the mineral and geochemical changes that occurred as a result of injection. The study documented the presence of mineral scales and at both fields in the reservoir rocks adjacent to the injection wells. At the Salton Sea, the scales consist of alternating layers of fluorite and barite, accompanied by minor anhydrite, amorphous silica and copper arsenic sulfides. Amorphous silica and traces of calcite were deposited at Coso. The formation of silica scale at Coso provides an example of the effects of untreated (unacidified) injectate on the reservoir rocks. Scanning electron microscopy and X-ray diffractometry were used to characterize the scale deposits. The silica scale in the reservoir rocks at Coso was initially deposited as spheres of opal-A 1-2 micrometers in diameter. As the deposits matured, the spheres coalesced to form larger spheres up to 10 micrometer in diameter. Further maturation and infilling of the spaces between spheres resulted in the formation of plates and sheets that substantially reduce the original porosity and permeability of the fractures. Peripheral to the silica deposits, fluid inclusions with high water/gas ratios provide a subtle record of interactions between the injectate and reservoir rocks. In contrast, fluid inclusions trapped prior to injection are relatively gas rich. These results suggest that the rocks undergo extensive microfracturing during injection and that the composition of the fluid inclusions will be biased toward the youngest event. Interactions between the reservoir rocks and injectate were modeled using the non-isothermal reactive geochemical transport code TOUGHREACT. Changes in fluid pH, fracture porosity, fracture permeability, fluid temperature, and mineral abundances were monitored. The simulations predict that amorphous silica will precipitate primarily within a few meters of the injection well and that mineral deposition will lead to rapid declines in fracture porosity and permeability, consistent with field observations. In support of Enhanced Geothermal System development, petrologic studies of Coso well 46A-19RD were conducted to determine the regions that are most likely to fail when stimulated. These studies indicate that the most intensely brecciated and altered rocks in the zone targeted for stimulation (below 10,000 ft (3048 m)) occur between 11,200 and 11,350 ft (3414 and 3459 m). This zone is interpreted as a shear zone that initially juxtaposed quartz diorite against granodiorite. Strong pervasive alteration and veining within the brecciated quartz diorite and granodiorite suggest this shear zone was permeable in the past. This zone of weakness was subsequently exploited by a granophyre dike whose top occurs at 11,350 ft (3459 m). The dike is unaltered. We anticipate, based on analysis of the well samples that failure during stimulation will most likely occur on this shear zone.

  2. The hydrogeologic-geochemical model of Cerro Prieto revisited

    SciTech Connect (OSTI)

    Lippmann, M.J.; Halfman, S.E.; Truesdell, A.H.; Manon M., A.

    1989-01-01

    As the exploitation of the Cerro Prieto, Mexico, geothermal field continues, there is increasing evidence that the hydrogeologic model developed by Halfman et al. (1984, 1986) presents the basic features controlling the movement of geothermal fluids in the system. At the present time the total installed capacity at Cerro Prieto is 620 MWe requiring the production of more than 10,500 tonnes/hr of a brine-steam mixture. This significant rate of fluid production has resulted in changes in reservoir thermodynamic conditions and in the chemistry of the produced fluids. After reviewing the hydrogeologic-geochemical model of Cerro Prieto, some of the changes observed in the field due to its exploitation are discussed and interpreted on the basis of the model. 21 refs., 11 figs., 1 tab.

  3. Nanogeochemistry: Geochemical reactions and mass transfers in nanopores

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Journal Article: Nanogeochemistry: Geochemical reactions and mass transfers in nanopores Citation Details In-Document Search Title: Nanogeochemistry: Geochemical reactions and mass transfers in nanopores Nanopores are ubiquitous in porous geologic media and may account for >90% of total mineral surface areas. Surface chemistry, ion sorption, and the related geochemical reactions within nanopores can be significantly modified by a nanometer-scale space

  4. A Geochemical Speciation Program Based on PHREEQE

    Energy Science and Technology Software Center (OSTI)

    1992-02-18

    HARPHRQ is a program based on the code PHREEQE and is designed to model geochemical reactions. Like PHREEQE, it can calculate the pH, redox potential and mass transfer as a function of reaction progress and the composition of solution in equilibrium with multiple phases. In addition, HARPHRQ includes options to allow the composition of a solution at a fixed pH to be calculated and to automatically add or remove mineral phases as they become saturatedmore » or exhausted. A separate module can also be interfaced to give a choice of sorption models including the triple-layer model.« less

  5. DNA-based methods of geochemical prospecting

    DOE Patents [OSTI]

    Ashby, Matthew

    2011-12-06

    The present invention relates to methods for performing surveys of the genetic diversity of a population. The invention also relates to methods for performing genetic analyses of a population. The invention further relates to methods for the creation of databases comprising the survey information and the databases created by these methods. The invention also relates to methods for analyzing the information to correlate the presence of nucleic acid markers with desired parameters in a sample. These methods have application in the fields of geochemical exploration, agriculture, bioremediation, environmental analysis, clinical microbiology, forensic science and medicine.

  6. Geochemical Modeling of the Near-Surface Hydrothermal System...

    Open Energy Info (EERE)

    with non-thermal groundwater. Our conceptual model is based on hypotheses in the literature and published geochemical and petrologic data. Mixing of thermal and non-thermal...

  7. Merging high resolution geophysical and geochemical surveys to...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    combine a suite of high resolution geophysical and geochemical techniques to reduce exploration risk by characterizing hydrothermal alteration, fault geometries and relationships. ...

  8. Category:Geochemical Data Analysis | Open Energy Information

    Open Energy Info (EERE)

    category, out of 4 total. G Geochemical Data Analysis Geothermometry T Thermal Ion Dispersion Thermochronometry Retrieved from "http:en.openei.orgwindex.php?titleCategory:Ge...

  9. Estimating the spatio-temporal distribution of geochemical parameters

    Office of Scientific and Technical Information (OSTI)

    associated with biostimulation using spectral induced polarization data and hierarchical Bayesian models (Journal Article) | SciTech Connect Estimating the spatio-temporal distribution of geochemical parameters associated with biostimulation using spectral induced polarization data and hierarchical Bayesian models Citation Details In-Document Search Title: Estimating the spatio-temporal distribution of geochemical parameters associated with biostimulation using spectral induced polarization

  10. Interpretation of extragalactic jets

    SciTech Connect (OSTI)

    Norman, M.L.

    1985-01-01

    The nature of extragalatic radio jets is modeled. The basic hypothesis of these models is that extragalatic jets are outflows of matter which can be described within the framework of fluid dynamics and that the outflows are essentially continuous. The discussion is limited to the interpretation of large-scale (i.e., kiloparsec-scale) jets. The central problem is to infer the physical parameters of the jets from observed distributions of total and polarized intensity and angle of polarization as a function of frequency. 60 refs., 6 figs.

  11. Geologic interpretation of gravity anomalies

    SciTech Connect (OSTI)

    Andreyev, B.A.; Klushin, I.G.

    1990-04-19

    This Russian textbook provides a sufficiently complete and systematic illumination of physico-geologic and mathematical aspect of complex problem of interpretation of gravity anomalies. The rational methods of localization of anomalies are examined in detail. All methods of interpreting gravity anomalies are described which have found successful application in practice. Also given are ideas of some new methods of the interpretation of gravity anomalies, the prospects for further development and industrial testing. Numerous practical examples to interpretation are given. Partial Contents: Bases of gravitational field theory; Physico-geologic bases of gravitational prospecting; Principles of geologic interpretation of gravity anomalies; Conversions and calculations of anomalies; Interpretation of gravity anomalies for bodies of correct geometric form and for bodies of arbitrary form; Geologic interpretation of the results of regional gravitational photographing; Searches and prospecting of oil- and gas-bearing structures and of deposits of ore and nonmetalliferous useful minerals.

  12. A Mineralogical Petrographic And Geochemical Study Of Samples...

    Open Energy Info (EERE)

    Mineralogical Petrographic And Geochemical Study Of Samples From Wells In The Geothermal Field Of Milos Island (Greece) Jump to: navigation, search OpenEI Reference LibraryAdd to...

  13. Geochemical Data on Waters, Gases, Scales, and Rocks from the...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999)...

  14. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic

    Office of Scientific and Technical Information (OSTI)

    Leakage into an Unconfined, Oxidizing Limestone Aquifer (Journal Article) | SciTech Connect Journal Article: Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer Citation Details In-Document Search Title: Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer An important risk at CO2 storage sites is the potential for groundwater quality impacts. As

  15. Monitoring CO2 intrusion and associated geochemical transformations in a

    Office of Scientific and Technical Information (OSTI)

    shallow groundwater system using complex electrical methods (Journal Article) | SciTech Connect Monitoring CO2 intrusion and associated geochemical transformations in a shallow groundwater system using complex electrical methods Citation Details In-Document Search Title: Monitoring CO2 intrusion and associated geochemical transformations in a shallow groundwater system using complex electrical methods Authors: Dafflon, B. ; Wu, Y. ; Hubbard, S. S. ; Birkholzer, J. T. ; Daley, T. M. ; Pugh,

  16. Monitoring CO2 intrusion and associated geochemical transformations in a

    Office of Scientific and Technical Information (OSTI)

    shallow groundwater system using complex electrical methods (Journal Article) | SciTech Connect Monitoring CO2 intrusion and associated geochemical transformations in a shallow groundwater system using complex electrical methods Citation Details In-Document Search Title: Monitoring CO2 intrusion and associated geochemical transformations in a shallow groundwater system using complex electrical methods × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This

  17. Self-Organized Pattern Formation in Sedimentary Geochemical Systems. (Book)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Book: Self-Organized Pattern Formation in Sedimentary Geochemical Systems. Citation Details In-Document Search Title: Self-Organized Pattern Formation in Sedimentary Geochemical Systems. Abstract not provided. Authors: Wang, Yifeng Publication Date: 2015-09-01 OSTI Identifier: 1228821 Report Number(s): SAND2015-7601B 603562 DOE Contract Number: AC04-94AL85000 Resource Type: Book Publisher: SPEM Publications Research Org: Sandia National Laboratories (SNL-NM), Albuquerque,

  18. Coffinitization of Uraninite: SEM/AEM Investigation and Geochemical

    Office of Scientific and Technical Information (OSTI)

    Modeling (Conference) | SciTech Connect Coffinitization of Uraninite: SEM/AEM Investigation and Geochemical Modeling Citation Details In-Document Search Title: Coffinitization of Uraninite: SEM/AEM Investigation and Geochemical Modeling Coffinite (USiO{sub 4}) has been found in numerous sedimentary and hydrothermal environments including those considered as natural analogues of nuclear waste repositories. Scanning electron microscopy (SEM) and analytical electron microscopy (AEM) studies

  19. Developing a robust geochemical and reactive transport model to evaluate

    Office of Scientific and Technical Information (OSTI)

    possible sources of arsenic at the CO[subscript 2] sequestration natural analog site in Chimayo, New Mexico (Journal Article) | SciTech Connect Journal Article: Developing a robust geochemical and reactive transport model to evaluate possible sources of arsenic at the CO[subscript 2] sequestration natural analog site in Chimayo, New Mexico Citation Details In-Document Search Title: Developing a robust geochemical and reactive transport model to evaluate possible sources of arsenic at the

  20. SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Signals in the Subsurface | Department of Energy SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical Signals in the Subsurface SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical Signals in the Subsurface PDF icon Grand Challenge Workshop -Imaging Subsurface.pdf More Documents & Publications AGU SubTER Town Hall Presentation 2015 SubTER Fact Sheet SubTER Presentation at Town Hall - American Geophysical Union

  1. mhtml:file://H:\CATX\APPROVED-CXS\EERE FOA 1201 - Rankine Cycle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . ., . . BNL-68599 PRODUCTION OF RADIOACTIVE IODINE David J. Schlyer Iodine-123 Probably the most 'widely used cyclotron produced radiohalogen is 1-123. It has gradually replaced I-13 1 as the isotope of choice for diagnostic radiopharmaceuticals containing radioiodine. It gives a much lower radiation dose to the patient and the gamma ray energy of 159 keV is ideally suited for use in a gamma camera. The gamma ray will penetrate tissue very effectively without excessive radiation dose. For this

  2. Geochemical Mud Logging of geothermal drilling

    SciTech Connect (OSTI)

    Tonani, F.B.; Guidi, M.; Johnson, S.D.

    1988-01-01

    The experience and results described in the present paper were developed over nearly two decades, with a major R&D project around 1980. The expression Geochemical Mud Logging (GML) has ill defined meaning in the geothermal industry, and ought to be specified. We refer here to GML as featuring mud and formation fluid tracer(s) and temperature as the bare essentials and with specified accuracies. Air and water logging are expected to be less demanding with regard to analysis accuracy, but are not discussed in this report. During application of GML to several drill holes with low formation permeabilities and under conditions of high temperature and high mud weight, GML as specified, revealed unexpected influx of formation brine. Such influx was a recurring feature that has been referenced to individual fractures and reflects both fracture size and permeability. As a consequence, continuous or subcontinuous sampling of mud systems appears more cost effective than trying to keep up with cumulative changes of bulk mud composition; although, the latter approach is more sensitive to extremely low rate, steady, inflow of formation fluid into the mud system. It appears, that based on this influx of formation fluid, permeability can be estimated well before mud losses are detected and/or drill strings are stuck. The main advantages of GML are: (1) the capability to assess formation temperature and permeability in nearly real time, resulting in (a) assessments of undisturbed formation and (b) having data in hand for holes lost during drilling operations and (2) being effective under conditions of very high temperatures where electrical logs are very costly and less reliable. Estimated cost for GML is $1500 per day (1982) based on assessments of R&D operations. However, extrapolating to larger scale services and to different operating conditions is indeed difficult. GML cost is probably the only significant point of controversy with regard to GML being a viable evaluation tool.

  3. Stochastic Joint Inversion for Integrated Data Interpretation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stochastic Joint Inversion for Integrated Data Interpretation in Geothermal Exploration Stochastic Joint Inversion for Integrated Data Interpretation in Geothermal Exploration ...

  4. Geochemical Modeling of ILAW Lysimeter Water Extracts

    SciTech Connect (OSTI)

    Cantrell, Kirk J.

    2014-12-22

    Geochemical modeling results of water extracts from simulated immobilized low-activity waste (ILAW) glasses, placed in lysimeters for eight years suggest that the secondary phase reaction network developed using product consistency test (PCT) results at 90°C may need to be modified for field conditions. For sediment samples that had been collected from near the glass samples, the impact of glass corrosion could be readily observed based upon the pH of their water extracts. For unimpacted sediments the pH ranged from 7.88 to 8.11 with an average of 8.04. Sediments that had observable impacts from glass corrosion exhibited elevated pH values (as high as 9.97). For lysimeter sediment samples that appear to have been impacted by glass corrosion to the greatest extent, saturation indices determined for analcime, calcite, and chalcedony in the 1:1 water extracts were near equilibrium and were consistent with the secondary phase reaction network developed using PCT results at 90°C. Fe(OH)3(s) also appears to be essentially at equilibrium in extracts impacted by glass corrosion, but with a solubility product (log Ksp) that is approximately 2.13 units lower than that used in the secondary phase reaction network developed using PCT results at 90°C. The solubilities of TiO2(am) and ZrO2(am) also appear to be much lower than that assumed in the secondary phase reaction network developed using PCT results at 90°C. The extent that the solubility of TiO2(am) and ZrO2(am) were reduced relative to that assumed in the secondary phase reaction network developed using PCT results at 90°C could not be quantified because the concentrations of Ti and Zr in the extracts were below the estimated quantification limit. Gibbsite was consistently highly oversaturated in the extract while dawsonite was at or near equilibrium. This suggests that dawsonite might be a more suitable phase for the secondary phase reaction network than gibbsite under field conditions. This may be due to the availability of carbonate that exists in the Hanford sediments as calcite. A significant source of carbonate was not available in the PCTs and this may account for why this phase did not appear in the PCTs. Sepiolite was consistently highly undersaturated, suggesting that another phase controls the solubility of magnesium. For samples that were most impacted by the effects of glass corrosion, magnesite appears to control glass corrosion. For samples that show less impacts from glass corrosion, clinochlore-7A or saponite-Mg appears to control the magnesium concentrations. For zinc, it appears that zincite is a better candidate than Zn(OH)2-γ for controlling zinc concentrations in the extracts; however, in some samples all zinc phases considered were highly oversaturated. As a result the phase that controls zinc concentrations in the lysimeter extracts remains uncertain.

  5. Validation of the WATEQ4 geochemical model for uranium

    SciTech Connect (OSTI)

    Krupka, K.M.; Jenne, E.A.; Deutsch, W.J.

    1983-09-01

    As part of the Geochemical Modeling and Nuclide/Rock/Groundwater Interactions Studies Program, a study was conducted to partially validate the WATEQ4 aqueous speciation-solubility geochemical model for uranium. The solubility controls determined with the WATEQ4 geochemical model were in excellent agreement with those laboratory studies in which the solids schoepite (UO/sub 2/(OH)/sub 2/ . H/sub 2/O), UO/sub 2/(OH)/sub 2/, and rutherfordine ((UO/sub 2/CO/sub 3/) were identified as actual solubility controls for uranium. The results of modeling solution analyses from laboratory studies of uranyl phosphate solids, however, identified possible errors in the characterization of solids in the original solubility experiments. As part of this study, significant deficiencies in the WATEQ4 thermodynamic data base for uranium solutes and solids were corrected. Revisions included recalculation of selected uranium reactions. Additionally, thermodynamic data for the hydroxyl complexes of U(VI), including anionic (VI) species, were evaluated (to the extent permitted by the available data). Vanadium reactions were also added to the thermodynamic data base because uranium-vanadium solids can exist in natural ground-water systems. This study is only a partial validation of the WATEQ4 geochemical model because the available laboratory solubility studies do not cover the range of solid phases, alkaline pH values, and concentrations of inorganic complexing ligands needed to evaluate the potential solubility of uranium in ground waters associated with various proposed nuclear waste repositories. Further validation of this or other geochemical models for uranium will require careful determinations of uraninite solubility over the pH range of 7 to 10 under highly reducing conditions and of uranyl hydroxide and phosphate solubilities over the pH range of 7 to 10 under oxygenated conditions.

  6. Nanogeochemistry: Geochemical reactions and mass transfers in nanopores

    Office of Scientific and Technical Information (OSTI)

    Frontiers in Geoscience SAND2015-3647C Nanogeochemistry: Nanostructures, emergent properties and their control on geochemical reactions and mass transfers Yifeng Wang Sandia National Laboratories Albuquerque, New Mexico 87185 May 11, 2015, Los Alamos National Laboratory Sandia National Laboratories Nanoscales Angstrom (10-10m) Nanometer Micron Millimeter Meter Kilometer 1000 kilometers (10-9m) (10-6m) (10-3 m) (m) (103 m) (103 m) Why so important? * Emergent properties * Key linkage between

  7. Argonne Geothermal Geochemical Database v2.0

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Harto, Christopher

    2013-05-22

    A database of geochemical data from potential geothermal sources aggregated from multiple sources as of March 2010. The database contains fields for the location, depth, temperature, pH, total dissolved solids concentration, chemical composition, and date of sampling. A separate tab contains data on non-condensible gas compositions. The database contains records for over 50,000 wells, although many entries are incomplete. Current versions of source documentation are listed in the dataset.

  8. Geochemical Triggers of Arsenic Mobilization during Managed Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recharge | Stanford Synchrotron Radiation Lightsource Geochemical Triggers of Arsenic Mobilization during Managed Aquifer Recharge Monday, February 29, 2016 Managed aquifer recharge (MAR) is an increasingly used water enhancement strategy, which involves subsurface storage of water supplies in groundwater aquifers. While MAR projects have the potential to alleviate water deficits, they can also adversely impact groundwater quality by altering the native geochemistry of the aquifer and

  9. Argonne Geothermal Geochemical Database v2.0

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Harto, Christopher

    A database of geochemical data from potential geothermal sources aggregated from multiple sources as of March 2010. The database contains fields for the location, depth, temperature, pH, total dissolved solids concentration, chemical composition, and date of sampling. A separate tab contains data on non-condensible gas compositions. The database contains records for over 50,000 wells, although many entries are incomplete. Current versions of source documentation are listed in the dataset.

  10. Geochemical drivers of organic matter decomposition in Arctic tundra soils

    SciTech Connect (OSTI)

    Herndon, Elizabeth M.; Yang, Ziming; Graham, David E.; Wullschleger, Stan D.; Gu, Baohua; Liang, Liyuan; Bargar, John; Janot, Noemie; Regier, Tom Z.

    2015-12-07

    Climate change is warming tundra ecosystems in the Arctic, resulting in the decomposition of previously-frozen soil organic matter (SOM) and release of carbon (C) to the atmosphere; however, the processes that control SOM decomposition and C emissions remain highly uncertain. In this study, we evaluate geochemical factors that influence anaerobic production of carbon dioxide (CO2) and methane (CH4) in the active layers of four ice-wedge polygons. Surface and soil pore waters were collected during the annual thaw season over a two-year period in an area containing waterlogged, low-centered polygons and well-drained, high-centered polygons. We report spatial and seasonal patterns of dissolved gases in relation to the geochemical properties of Fe and organic C as determined using spectroscopic and chromatographic techniques. Iron was present as Fe(II) in soil solution near the permafrost boundary but enriched as Fe(III) in the middle of the active layer, similar to dissolved aromatic-C and organic acids. Dissolved CH4 increased relative to dissolved CO2 with depth and varied with soil moisture in the middle of the active layer in patterns that were positively correlated with the proportion of dissolved Fe(III) in transitional and low-centered polygon soils but negatively correlated in the drier flat- and high-centered polygons. These results suggest that microbial-mediated Fe oxidation and reduction influence respiration/fermentation of SOM and production of substrates (e.g., low-molecular-weight organic acids) for methanogenesis. As a result, we infer that geochemical differences induced by water saturation dictate microbial products of SOM decomposition, and Fe geochemistry is an important factor regulating methanogenesis in anoxic tundra soils.

  11. Geochemical drivers of organic matter decomposition in Arctic tundra soils

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Herndon, Elizabeth M.; Yang, Ziming; Graham, David E.; Wullschleger, Stan D.; Gu, Baohua; Liang, Liyuan; Bargar, John; Janot, Noemie; Regier, Tom Z.

    2015-12-07

    Climate change is warming tundra ecosystems in the Arctic, resulting in the decomposition of previously-frozen soil organic matter (SOM) and release of carbon (C) to the atmosphere; however, the processes that control SOM decomposition and C emissions remain highly uncertain. In this study, we evaluate geochemical factors that influence anaerobic production of carbon dioxide (CO2) and methane (CH4) in the active layers of four ice-wedge polygons. Surface and soil pore waters were collected during the annual thaw season over a two-year period in an area containing waterlogged, low-centered polygons and well-drained, high-centered polygons. We report spatial and seasonal patterns ofmore » dissolved gases in relation to the geochemical properties of Fe and organic C as determined using spectroscopic and chromatographic techniques. Iron was present as Fe(II) in soil solution near the permafrost boundary but enriched as Fe(III) in the middle of the active layer, similar to dissolved aromatic-C and organic acids. Dissolved CH4 increased relative to dissolved CO2 with depth and varied with soil moisture in the middle of the active layer in patterns that were positively correlated with the proportion of dissolved Fe(III) in transitional and low-centered polygon soils but negatively correlated in the drier flat- and high-centered polygons. These results suggest that microbial-mediated Fe oxidation and reduction influence respiration/fermentation of SOM and production of substrates (e.g., low-molecular-weight organic acids) for methanogenesis. As a result, we infer that geochemical differences induced by water saturation dictate microbial products of SOM decomposition, and Fe geochemistry is an important factor regulating methanogenesis in anoxic tundra soils.« less

  12. Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal systems

    Broader source: Energy.gov [DOE]

    Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal systems presentation at the April 2013 peer review meeting held in Denver, Colorado.

  13. Novel Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners

    Broader source: Energy.gov [DOE]

    Novel Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners presentation at the April 2013 peer review meeting held in Denver, Colorado.

  14. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1 Citation Details...

  15. QUALITATIVE INTERPRETATION OF GALAXY SPECTRA

    SciTech Connect (OSTI)

    Sanchez Almeida, J.; Morales-Luis, A. B. [Instituto de Astrofisica de Canarias, E-38205 La Laguna, Tenerife (Spain); Terlevich, R.; Terlevich, E. [Instituto Nacional de Astrofisica, Optica y Electronica, Tonantzintla, Puebla (Mexico); Cid Fernandes, R., E-mail: jos@iac.es, E-mail: abml@iac.es, E-mail: rjt@ast.cam.ac.uk, E-mail: eterlevi@inaoep.mx, E-mail: cid@astro.ufsc.br [Departamento de Fisica-CFM, Universidade Federal de Santa Catarina, P.O. Box 476, 88040-900 Florianopolis, SC (Brazil)

    2012-09-10

    We describe a simple step-by-step guide to qualitative interpretation of galaxy spectra. Rather than an alternative to existing automated tools, it is put forward as an instrument for quick-look analysis and for gaining physical insight when interpreting the outputs provided by automated tools. Though the recipe is for general application, it was developed for understanding the nature of the Automatic Spectroscopic K-means-based (ASK) template spectra. They resulted from the classification of all the galaxy spectra in the Sloan Digital Sky Survey data release 7, thus being a comprehensive representation of the galaxy spectra in the local universe. Using the recipe, we give a description of the properties of the gas and the stars that characterize the ASK classes, from those corresponding to passively evolving galaxies, to H II galaxies undergoing a galaxy-wide starburst. The qualitative analysis is found to be in excellent agreement with quantitative analyses of the same spectra. We compare the mean ages of the stellar populations with those inferred using the code STARLIGHT. We also examine the estimated gas-phase metallicity with the metallicities obtained using electron-temperature-based methods. A number of byproducts follow from the analysis. There is a tight correlation between the age of the stellar population and the metallicity of the gas, which is stronger than the correlations between galaxy mass and stellar age, and galaxy mass and gas metallicity. The galaxy spectra are known to follow a one-dimensional sequence, and we identify the luminosity-weighted mean stellar age as the affine parameter that describes the sequence. All ASK classes happen to have a significant fraction of old stars, although spectrum-wise they are outshined by the youngest populations. Old stars are metal-rich or metal-poor depending on whether they reside in passive galaxies or in star-forming galaxies.

  16. Merging high resolution geophysical and geochemical surveys to reduce exploration risk at glass buttes, Oregon

    SciTech Connect (OSTI)

    Walsh, Patrick; Fercho, Steven; Perkin, Doug; Martini, Brigette; Boshmann, Darrick

    2015-06-01

    The engineering and studies phase of the Glass Buttes project was aimed at reducing risk during the early stages of geothermal project development. The project’s inclusion of high resolution geophysical and geochemical surveys allowed Ormat to evaluate the value of these surveys both independently and in combination to quantify the most valuable course of action for exploration in an area where structure, permeability, and temperature are the most pressing questions. The sizes of the thermal anomalies at Glass Buttes are unusually large. Over the course of Phase I Ormat acquired high resolution LIDAR data to accurately map fault manifestations at the surface and collected detailed gravity and aeromagnetic surveys to map subsurface structural features. In addition, Ormat collected airborne hyperspectral data to assist with mapping the rock petrology and mineral alteration assemblages along Glass Buttes faults and magnetotelluric (MT) survey to try to better constrain the structures at depth. Direct and indirect identification of alteration assemblages reveal not only the geochemical character and temperature of the causative hydrothermal fluids but can also constrain areas of upflow along specific fault segments. All five datasets were merged along with subsurface lithologies and temperatures to predict the most likely locations for high permeability and hot fluids. The Glass Buttes temperature anomalies include 2 areas, totaling 60 km2 (23 mi2) of measured temperature gradients over 165° C/km (10° F/100ft). The Midnight Point temperature anomaly includes the Strat-1 well with 90°C (194 °F) at 603 m (1981 ft) with a 164 °C/km (10°F/100ft) temperature gradient at bottom hole and the GB-18 well with 71°C (160 °F) at 396 m (1300 ft) with a 182°C/km (11°F/100ft) gradient. The primary area of alteration and elevated temperature occurs near major fault intersections associated with Brothers Fault Zone and Basin and Range systems. Evidence for faulting is observed in each data set as follows. Field observations include fault plane orientations, complicated fault intersections, and hydrothermal alteration apparently pre-dating basalt flows. Geophysical anomalies include large, linear gradients in gravity and aeromagnetic data with magnetic lows possibly associated with alteration. Resistivity low anomalies also appear to have offsets associated with faulting. Hyperspectral and XRF identified alteration and individual volcanic flow units, respectively. When incorporated into a 3D geologic model, the fault intersections near the highest proven temperature and geophysical anomalies provide the first priority targets at Midnight Point. Ormat geologists selected the Midnight Point 52-33 drilling target based on a combination of pre-existing drilling data, geologic field work, geophysical interpretation, and geochemical analysis. Deep temperatures of well 52-33 was lower than anticipated. Temperature gradients in the well mirrored those found in historical drilling, but they decreased below 1500 ft and were isothermal below 2000 ft.

  17. Geochemical and Geomechanical Effects on Wellbore Cement Fractures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Um, Wooyong; Jung, Hun Bok; Kabilan, Senthil; Fernandez, Carlos A.; Brown, Christopher F.

    2014-12-31

    Experimental studies were conducted using batch reactors, X-ray microtomograpy (XMT), and computational fluid dynamics (CFD) simulation to determine changes in cement fracture surfaces, fluid flow pathways, and permeability with geochemical and geomechanical processes. Composite Portland cement-basalt caprock core with artificial fractures was prepared and reacted with CO2-saturated groundwater at 50°C and 10 MPa for 3 to 3.5 months under static conditions to understand the geochemical and geomechanical effects on the integrity of wellbores containing defects. Cement-basalt interface samples were subjected to mechanical stress at 2.7 MPa before the CO2 reaction. XMT provided three-dimensional (3-D) visualization of the opening and interconnectionmore » of cement fractures due to mechanical stress. After the CO2 reaction, XMT images revealed that calcium carbonate precipitation occurred extensively within the fractures in the cement matrix, but only partially along fractures located at the cement-basalt interface. The permeability calculated based on CFD simulation was in agreement with the experimentally measured permeability. The experimental results imply that the wellbore cement with fractures is likely to be healed during exposure to CO2-saturated groundwater under static conditions, whereas fractures along the cement-caprock interface are still likely to remain vulnerable to the leakage of CO2. CFD simulation for the flow of different fluids (CO2-saturated brine and supercritical CO2) using a pressure difference of 20 kPa and 200 kPa along ~2 cm-long cement fractures showed that a pressure gradient increase resulted in an increase of CO2 fluids flux by a factor of only ~3-9 because the friction of CO2 fluids on cement fracture surfaces increased with higher flow rate as well. At the same pressure gradient, the simulated flow rate was higher for supercritical CO2 than CO2-saturated brine by a factor of only ~2-3, because the viscosity of supercritical CO2 is much lower than that of CO2-saturated brine. The study suggests that in deep geological reservoirs the geochemical and geomechanical processes have coupled effects on the wellbore cement fracture evolution and fluid flow along the fracture surfaces.« less

  18. Geochemical and Geomechanical Effects on Wellbore Cement Fractures

    SciTech Connect (OSTI)

    Um, Wooyong; Jung, Hun Bok; Kabilan, Senthil; Fernandez, Carlos A.; Brown, Christopher F.

    2014-12-31

    Experimental studies were conducted using batch reactors, X-ray microtomograpy (XMT), and computational fluid dynamics (CFD) simulation to determine changes in cement fracture surfaces, fluid flow pathways, and permeability with geochemical and geomechanical processes. Composite Portland cement-basalt caprock core with artificial fractures was prepared and reacted with CO2-saturated groundwater at 50°C and 10 MPa for 3 to 3.5 months under static conditions to understand the geochemical and geomechanical effects on the integrity of wellbores containing defects. Cement-basalt interface samples were subjected to mechanical stress at 2.7 MPa before the CO2 reaction. XMT provided three-dimensional (3-D) visualization of the opening and interconnection of cement fractures due to mechanical stress. After the CO2 reaction, XMT images revealed that calcium carbonate precipitation occurred extensively within the fractures in the cement matrix, but only partially along fractures located at the cement-basalt interface. The permeability calculated based on CFD simulation was in agreement with the experimentally measured permeability. The experimental results imply that the wellbore cement with fractures is likely to be healed during exposure to CO2-saturated groundwater under static conditions, whereas fractures along the cement-caprock interface are still likely to remain vulnerable to the leakage of CO2. CFD simulation for the flow of different fluids (CO2-saturated brine and supercritical CO2) using a pressure difference of 20 kPa and 200 kPa along ~2 cm-long cement fractures showed that a pressure gradient increase resulted in an increase of CO2 fluids flux by a factor of only ~3-9 because the friction of CO2 fluids on cement fracture surfaces increased with higher flow rate as well. At the same pressure gradient, the simulated flow rate was higher for supercritical CO2 than CO2-saturated brine by a factor of only ~2-3, because the viscosity of supercritical CO2 is much lower than that of CO2-saturated brine. The study suggests that in deep geological reservoirs the geochemical and geomechanical processes have coupled effects on the wellbore cement fracture evolution and fluid flow along the fracture surfaces.

  19. WATEQ3 geochemical model: thermodynamic data for several additional solids

    SciTech Connect (OSTI)

    Krupka, K.M.; Jenne, E.A.

    1982-09-01

    Geochemical models such as WATEQ3 can be used to model the concentrations of water-soluble pollutants that may result from the disposal of nuclear waste and retorted oil shale. However, for a model to competently deal with these water-soluble pollutants, an adequate thermodynamic data base must be provided that includes elements identified as important in modeling these pollutants. To this end, several minerals and related solid phases were identified that were absent from the thermodynamic data base of WATEQ3. In this study, the thermodynamic data for the identified solids were compiled and selected from several published tabulations of thermodynamic data. For these solids, an accepted Gibbs free energy of formation, ..delta..G/sup 0//sub f,298/, was selected for each solid phase based on the recentness of the tabulated data and on considerations of internal consistency with respect to both the published tabulations and the existing data in WATEQ3. For those solids not included in these published tabulations, Gibbs free energies of formation were calculated from published solubility data (e.g., lepidocrocite), or were estimated (e.g., nontronite) using a free-energy summation method described by Mattigod and Sposito (1978). The accepted or estimated free energies were then combined with internally consistent, ancillary thermodynamic data to calculate equilibrium constants for the hydrolysis reactions of these minerals and related solid phases. Including these values in the WATEQ3 data base increased the competency of this geochemical model in applications associated with the disposal of nuclear waste and retorted oil shale. Additional minerals and related solid phases that need to be added to the solubility submodel will be identified as modeling applications continue in these two programs.

  20. SUPERIOR ENERGY PERFORMANCE DOCUMENTS INTERPRETATIONS | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Technical Assistance » Superior Energy Performance » SUPERIOR ENERGY PERFORMANCE DOCUMENTS INTERPRETATIONS SUPERIOR ENERGY PERFORMANCE DOCUMENTS INTERPRETATIONS sep_logo_borderless.jpg Language is carefully chosen in standards documents. The intent of the language may be questioned and the answers require interpretation. To facilitate efficient Superior Energy Performance® (SEP(tm)) implementation, there is a formal process to collect these questions and track responses. The SEP

  1. Earned Value Management System Interpretation Handbook (EVMSIH) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Interpretation Handbook (EVMSIH) Earned Value Management System Interpretation Handbook (EVMSIH) The DOE EVMS Interpretation Handbook EVMSIH is the basis for defining and assessing EVMS compliance to the EIA-748 Guidelines. It was developed in collaboration with DOE and contractor EVMS experts, and based extensively on the complete EVM historical body of knowledge documents from industry and various Government organizations as well as DOE unique situations/conditions.

  2. Earned Value Management System Interpretation Handbook (EVMSIH...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The DOE EVMS Interpretation Handbook EVMSIH is the basis for defining and assessing EVMS compliance to the EIA-748 Guidelines. It was developed in collaboration with DOE and ...

  3. Aeromagnetic Survey And Interpretation, Ascention Island, South...

    Open Energy Info (EERE)

    And Interpretation, Ascention Island, South Atlantic Ocean Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Aeromagnetic Survey And...

  4. DISPLAYING AND INTERPRETING FLUID INCLUSION STRATIGRAPHY ANALYSES...

    Open Energy Info (EERE)

    DISPLAYING AND INTERPRETING FLUID INCLUSION STRATIGRAPHY ANALYSES ON MUDLOG GRAPHS Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Proceedings:...

  5. Mineralogic Interpretation Of Hymap Hyperspectral Data, Dixie...

    Open Energy Info (EERE)

    Mineralogic Interpretation Of Hymap Hyperspectral Data, Dixie Valley, Nevada, USA-Initial Results Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal...

  6. Technical Interpretation, NSTI 2003-01

    Broader source: Energy.gov [DOE]

    Technical Interpretation 2003-01 concerns Department of Energy Orders and Regulations for review and approval of the underlying scope, methods, and approaches to implement the Order requirements.

  7. General Counsel Legal Interpretation Regarding Medical Removal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Benefits Pursuant to 10 CFR Part 850, Chronic Beryllium Disease Prevention Program General Counsel Legal Interpretation Regarding Medical Removal Protection Benefits ...

  8. Modeling Background Radiation in our Environment Using Geochemical Data

    SciTech Connect (OSTI)

    Malchow, Russell L.; Marsac, Kara; Burnley, Pamela; Hausrath, Elisabeth; Haber, Daniel; Adcock, Christopher

    2015-02-01

    Radiation occurs naturally in bedrock and soil. Gamma rays are released from the decay of the radioactive isotopes K, U, and Th. Gamma rays observed at the surface come from the first 30 cm of rock and soil. The energy of gamma rays is specific to each isotope, allowing identification. For this research, data was collected from national databases, private companies, scientific literature, and field work. Data points were then evaluated for self-consistency. A model was created by converting concentrations of U, K, and Th for each rock and soil unit into a ground exposure rate using the following equation: D=1.32 K+ 0.548 U+ 0.272 Th. The first objective of this research was to compare the original Aerial Measurement System gamma ray survey to results produced by the model. The second objective was to improve the method and learn the constraints of the model. Future work will include sample data analysis from field work with a goal of improving the geochemical model.

  9. Merging high resolution geophysical and geochemical surveys to reduce exploration risk at Glass Buttes, Oregon

    Broader source: Energy.gov [DOE]

    DOE Geothermal Technologies Peer Review - 2010. The primary objective of this project is to combine a suite of high resolution geophysical and geochemical techniques to reduce exploration risk by characterizing hydrothermal alteration, fault geometries and relationships.

  10. 31 TAC, part 1, chapter 9, rule 9.11 Geophysical and Geochemical...

    Open Energy Info (EERE)

    9, rule 9.11 Geophysical and Geochemical Exploration Permits Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: 31 TAC, part...

  11. A Geological and Hydro-Geochemical Study of the Animas Geothermal...

    Open Energy Info (EERE)

    Hydro-Geochemical Study of the Animas Geothermal Area, Hidalgo County, New Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Geological...

  12. A geochemical model of the Kilauea east rift zone | Open Energy...

    Open Energy Info (EERE)

    rift zone Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A geochemical model of the Kilauea east rift zone Abstract NA Author Donald Thomas...

  13. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1 Bacon, Diana H. carbon...

  14. Geochemical Monitoring Considerations for the FutureGen 2.0 Project

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Amonette, James E.; Johnson, Timothy A.; Spencer, Clayton F.; Zhong, Lirong; Szecsody, James E.; Vermeul, Vince R.

    2014-12-31

    Geochemical monitoring is an essential component of a suite of monitoring technologies designed to evaluate CO2 mass balance and detect possible loss of containment at the FutureGen 2.0 geologic sequestration site near Jacksonville, IL. This presentation gives an overview of the potential geochemical approaches and tracer technologies that were considered, and describes the evaluation process by which the most cost-effective and robust of these were selected for implementation

  15. Extension Modules for the Python Interpretive language

    Energy Science and Technology Software Center (OSTI)

    2006-12-29

    Python is an interpreted computer language, freely available to all, which may be extended by user developed "modules". These modules ay be written in a complied language such as 'C', and then linked into the Python program

  16. Natural bacterial communities serve as quantitative geochemical biosensors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Mark B.; Rocha, Andrea M.; Smillie, Chris S.; Olesen, Scott W.; Paradis, Charles; Wu, Liyou; Campbell, James H.; Fortney, Julian L.; Mehlhorn, Tonia L.; Lowe, Kenneth A.; et al

    2015-05-12

    Biological sensors can be engineered to measure a wide range of environmental conditions. Here we show that statistical analysis of DNA from natural microbial communities can be used to accurately identify environmental contaminants, including uranium and nitrate at a nuclear waste site. In addition to contamination, sequence data from the 16S rRNA gene alone can quantitatively predict a rich catalogue of 26 geochemical features collected from 93 wells with highly differing geochemistry characteristics. We extend this approach to identify sites contaminated with hydrocarbons from the Deepwater Horizon oil spill, finding that altered bacterial communities encode a memory of prior contamination,more » even after the contaminants themselves have been fully degraded. We show that the bacterial strains that are most useful for detecting oil and uranium are known to interact with these substrates, indicating that this statistical approach uncovers ecologically meaningful interactions consistent with previous experimental observations. Future efforts should focus on evaluating the geographical generalizability of these associations. Taken as a whole, these results indicate that ubiquitous, natural bacterial communities can be used as in situ environmental sensors that respond to and capture perturbations caused by human impacts. These in situ biosensors rely on environmental selection rather than directed engineering, and so this approach could be rapidly deployed and scaled as sequencing technology continues to become faster, simpler, and less expensive. Here we show that DNA from natural bacterial communities can be used as a quantitative biosensor to accurately distinguish unpolluted sites from those contaminated with uranium, nitrate, or oil. These results indicate that bacterial communities can be used as environmental sensors that respond to and capture perturbations caused by human impacts.« less

  17. Natural bacterial communities serve as quantitative geochemical biosensors

    SciTech Connect (OSTI)

    Smith, Mark B.; Rocha, Andrea M.; Smillie, Chris S.; Olesen, Scott W.; Paradis, Charles; Wu, Liyou; Campbell, James H.; Fortney, Julian L.; Mehlhorn, Tonia L.; Lowe, Kenneth A.; Earles, Jennifer E.; Phillips, Jana; Techtmann, Steve M.; Joyner, Dominique C.; Elias, Dwayne A.; Bailey, Kathryn L.; Hurt, Richard A.; Preheim, Sarah P.; Sanders, Matthew C.; Yang, Joy; Mueller, Marcella A.; Brooks, Scott; Watson, David B.; Zhang, Ping; He, Zhili; Dubinsky, Eric A.; Adams, Paul D.; Arkin, Adam P.; Fields, Matthew W.; Zhou, Jizhong; Alm, Eric J.; Hazen, Terry C.

    2015-05-12

    Biological sensors can be engineered to measure a wide range of environmental conditions. Here we show that statistical analysis of DNA from natural microbial communities can be used to accurately identify environmental contaminants, including uranium and nitrate at a nuclear waste site. In addition to contamination, sequence data from the 16S rRNA gene alone can quantitatively predict a rich catalogue of 26 geochemical features collected from 93 wells with highly differing geochemistry characteristics. We extend this approach to identify sites contaminated with hydrocarbons from the Deepwater Horizon oil spill, finding that altered bacterial communities encode a memory of prior contamination, even after the contaminants themselves have been fully degraded. We show that the bacterial strains that are most useful for detecting oil and uranium are known to interact with these substrates, indicating that this statistical approach uncovers ecologically meaningful interactions consistent with previous experimental observations. Future efforts should focus on evaluating the geographical generalizability of these associations. Taken as a whole, these results indicate that ubiquitous, natural bacterial communities can be used as in situ environmental sensors that respond to and capture perturbations caused by human impacts. These in situ biosensors rely on environmental selection rather than directed engineering, and so this approach could be rapidly deployed and scaled as sequencing technology continues to become faster, simpler, and less expensive. Here we show that DNA from natural bacterial communities can be used as a quantitative biosensor to accurately distinguish unpolluted sites from those contaminated with uranium, nitrate, or oil. These results indicate that bacterial communities can be used as environmental sensors that respond to and capture perturbations caused by human impacts.

  18. Geochemical characteristics of bitumens and seeps from Tanzania

    SciTech Connect (OSTI)

    Mpanju, F. ); Philp, P. )

    1991-03-01

    A number of bitumen extracts from prospective source rocks and oil seeps of potential oil-producing areas in Tanzania have been characterized by a variety of geochemical techniques. The data obtained from this study have provided additional insight into the source rock potential of these areas. However, in this paper it is proposed to discuss in detail the results from two of the more unusual samples in this region, namely Wingayongo and Pemba. The Wingayongo bitumens isolated from an exposed Neocomian-aged sandstone, possibly a paleoreservoir, are almost totally devoid of n-alkanes and steranes and dominated by hopane-type biomarkers with the so-called immature {beta}{beta}-stereochemistry at the C{sub 17} and C{sub 21} positions. There is no typical evidence of biodegradation having occurred leading to the proposal of an unusual source material or maturity history for this sample. The Pemba seep samples were also characterized by relatively high concentrations of hopanes with the immature stereochemistry at the C{sub 17} and C{sub 21} positions and a virtual absence of n-alkanes and steranes. The aromatic fractions contained relatively high concentrations of hopanic acids, with the immature stereochemistry at C{sub 17} and C{sub 21} positions and a virtual absence of n-alkanes and steranes. The aromatic fractions contained relatively high concentrations of hopanic acids, with the immature stereochemistry at C{sub 17} and C{sub 21}. On the basis of these data, it is proposed that the seeps in the Pemba region are not true oil seeps. Rather they are formed as a result of extremely high levels of bacterial activity with the bacteria utilizing natural gas in the region as the substrate. The net result is a material referred to in other areas of the world as paraffin dirt whose occurrence results from extensive microbial activity in the region and not directly from seepage of products having a thermal origin.

  19. Hiereachical Bayesian Model for Combining Geochemical and Geophysical Data for Environmental Applications Software

    Energy Science and Technology Software Center (OSTI)

    2013-05-01

    Development of a hierarchical Bayesian model to estimate the spatiotemporal distribution of aqueous geochemical parameters associated with in-situ bioremediation using surface spectral induced polarization (SIP) data and borehole geochemical measurements collected during a bioremediation experiment at a uranium-contaminated site near Rifle, Colorado. The SIP data are first inverted for Cole-Cole parameters including chargeability, time constant, resistivity at the DC frequency and dependence factor, at each pixel of two-dimensional grids using a previously developed stochastic method.more » Correlations between the inverted Cole-Cole parameters and the wellbore-based groundwater chemistry measurements indicative of key metabolic processes within the aquifer (e.g. ferrous iron, sulfate, uranium) were established and used as a basis for petrophysical model development. The developed Bayesian model consists of three levels of statistical sub-models: 1) data model, providing links between geochemical and geophysical attributes, 2) process model, describing the spatial and temporal variability of geochemical properties in the subsurface system, and 3) parameter model, describing prior distributions of various parameters and initial conditions. The unknown parameters are estimated using Markov chain Monte Carlo methods. By combining the temporally distributed geochemical data with the spatially distributed geophysical data, we obtain the spatio-temporal distribution of ferrous iron, sulfate and sulfide, and their associated uncertainity information. The obtained results can be used to assess the efficacy of the bioremediation treatment over space and time and to constrain reactive transport models.« less

  20. Tracer Test Interpretation Methods for Reservior Properties

    SciTech Connect (OSTI)

    Shook, George Michael

    2001-08-01

    The purpose of this project is to develop tools that can be used to interpret tracer tests and obtain estimates of reservoir and operational parameters. These tools (mostly in the form of spreadsheet applications) can be used to optimize geothermal resource management.

  1. Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting

    SciTech Connect (OSTI)

    Mani, Devleena; Kumar, T. Satish; Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V.

    2011-03-15

    The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana-Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r{sup 2} < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

  2. Laboratory Study Supporting the Interpretation of Solar Dynamics...

    Office of Scientific and Technical Information (OSTI)

    Laboratory Study Supporting the Interpretation of Solar Dynamics Observatory data Citation Details In-Document Search Title: Laboratory Study Supporting the Interpretation of Solar ...

  3. A Regulator's Perspective on Interpretation of Performance and...

    Office of Environmental Management (EM)

    Interpretation of Performance and Risk Assessment Results A Regulator's Perspective on Interpretation of Performance and Risk Assessment Results Presentation from the 2015 Annual...

  4. Laboratory Study Supporting the Interpretation of Solar Dynamics...

    Office of Scientific and Technical Information (OSTI)

    Laboratory Study Supporting the Interpretation of Solar Dynamics Observatory data Citation Details In-Document Search Title: Laboratory Study Supporting the Interpretation of Solar...

  5. EQ3/6, a software package for geochemical modeling of aqueous systems:

    Office of Scientific and Technical Information (OSTI)

    Package overview and installation guide (Version 7.0) (Technical Report) | SciTech Connect EQ3/6, a software package for geochemical modeling of aqueous systems: Package overview and installation guide (Version 7.0) Citation Details In-Document Search Title: EQ3/6, a software package for geochemical modeling of aqueous systems: Package overview and installation guide (Version 7.0) × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of

  6. Geochemical and isotopic results for groundwater, drainage waters, snowmelt, permafrost, precipitation in Barrow, Alaska (USA) 2012-2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Wilson, Cathy; Newman, Brent; Heikoop, Jeff

    Data include a large suite of analytes (geochemical and isotopic) for samples collected in Barrow, Alaska (2012-2013). Sample types are indicated, and include soil pore waters, drainage waters, snowmelt, precipitation, and permafrost samples.

  7. Geochemical and isotopic results for groundwater, drainage waters, snowmelt, permafrost, precipitation in Barrow, Alaska (USA) 2012-2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Wilson, Cathy; Newman, Brent; Heikoop, Jeff

    2012-07-18

    Data include a large suite of analytes (geochemical and isotopic) for samples collected in Barrow, Alaska (2012-2013). Sample types are indicated, and include soil pore waters, drainage waters, snowmelt, precipitation, and permafrost samples.

  8. Kinetics of Uranium(VI) Desorption from Contaminated Sediments: Effect of Geochemical Conditions and Model Evaluation

    SciTech Connect (OSTI)

    Liu, Chongxuan; Shi, Zhenqing; Zachara, John M.

    2009-09-01

    Stirred-flow cell experiments were performed to investigate the kinetics of uranyl [U(VI)] desorption from a contaminated sediment collected from the Hanford 300 Area at the US Department of Energy (DOE) Hanford Site, Washington. Three influent solutions of variable pH, Ca and carbonate concentrations that affected U(VI) aqueous and surface speciation were used under dynamic flow conditions to evaluate the effect of geochemical conditions on the rate of U(VI) desorption. The measured rate of U(VI) desorption varied with solution chemical composition that evolved as a result of thermodynamic and kinetic interactions between the influent solutions and sediment. The solution chemical composition that led to a lower equilibrium U(VI) sorption to the solid phase yielded a faster desorption rate. The experimental results were used to evaluate a multi-rate, surface complexation model (SCM) that has been proposed to describe U(VI) desorption kinetics in the Hanford sediment that contained complex sorbed U(VI) species in mass transfer limited domains. The model was modified and supplemented by including multi-rate, ion exchange reactions to describe the geochemical interactions between the solutions and sediment. With the same set of model parameters, the modified model reasonably well described the evolution of major ions and the rates of U(VI) desorption under variable geochemical and flow conditions, implying that the multi-rate SCM is an effective way to describe U(VI) desorption kinetics in subsurface sediments.

  9. The role of interpreters in high performance computing

    SciTech Connect (OSTI)

    Naumann, Axel; Canal, Philippe; /Fermilab

    2008-01-01

    Compiled code is fast, interpreted code is slow. There is not much we can do about it, and it's the reason why interpreters use in high performance computing is usually restricted to job submission. We show where interpreters make sense even in the context of analysis code, and what aspects have to be taken into account to make this combination a success.

  10. Geochemical factors affecting radionuclide transport through near and far fields at a Low-Level Waste Disposal Site

    SciTech Connect (OSTI)

    Kaplan, D.I.; Seme, R.J.; Piepkho, M.G.

    1995-03-01

    The concentration of low-level waste (LLW) contaminants in groundwater is determined by the amount of contaminant present in the solid waste, rate of release from the waste and surrounding barriers, and a number of geochemical processes including adsorption, desorption, diffusion, precipitation, and dissolution. To accurately predict radionuclide transport through the subsurface, it is essential that the important geochemical processes affecting radionuclide transport be identified and, perhaps more importantly, accurately quantified and described in a mathematically defensible manner.

  11. Sensitivity of the interpretation of the experimental ion thermal

    Office of Scientific and Technical Information (OSTI)

    diffusivity to the determination of the ion conductive heat flux (Journal Article) | SciTech Connect Sensitivity of the interpretation of the experimental ion thermal diffusivity to the determination of the ion conductive heat flux Citation Details In-Document Search Title: Sensitivity of the interpretation of the experimental ion thermal diffusivity to the determination of the ion conductive heat flux A moments equation formalism for the interpretation of the experimental ion thermal

  12. Geochemical Behaviour of S, Cl and Fe in Silicate Melts/Glasses Simulating

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Magmas | Stanford Synchrotron Radiation Lightsource Geochemical Behaviour of S, Cl and Fe in Silicate Melts/Glasses Simulating Natural Magmas Monday, March 26, 2012 - 11:00am SSRL Conference Room 137-322 G. Giuli, R. Alonso-Mori, E. Paris, P. Glatzel, S. Eeckhout, M. Carroll, School of Science and Technology, Geology Division, University of Camerino, Via G. III da Varano, 62032 Camerino; e-mail: The solubility behaviour of S and Cl in silicate magmas is a key to understand the

  13. Remote Raman - laser induced breakdown spectroscopy (LIBS) geochemical investigation under Venus atmospheric conditions

    SciTech Connect (OSTI)

    Clegg, Sanuel M; Barefield, James E; Humphries, Seth D; Wiens, Roger C; Vaniman, D. T.; Sharma, S. K.; Misra, A. K.; Dyar, M. D.; Smrekar, S. E.

    2010-12-13

    The extreme Venus surface temperatures ({approx}740 K) and atmospheric pressures ({approx}93 atm) create a challenging environment for surface missions. Scientific investigations capable of Venus geochemical observations must be completed within hours of landing before the lander will be overcome by the harsh atmosphere. A combined remote Raman - LIBS (Laser Induced Breakdown Spectroscopy) instrument is capable of accomplishing the geochemical science goals without the risks associated with collecting samples and bringing them into the lander. Wiens et al. and Sharma et al. demonstrated that both analytical techniques can be integrated into a single instrument capable of planetary missions. The focus of this paper is to explore the capability to probe geologic samples with Raman - LIBS and demonstrate quantitative analysis under Venus surface conditions. Raman and LIBS are highly complementary analytical techniques capable of detecting both the mineralogical and geochemical composition of Venus surface materials. These techniques have the potential to profoundly increase our knowledge of the Venus surface composition, which is currently limited to geochemical data from Soviet Venera and VEGA landers that collectively suggest a surface composition that is primarily tholeiitic basaltic with some potentially more evolved compositions and, in some locations, K-rich trachyandesite. These landers were not equipped to probe the surface mineralogy as can be accomplished with Raman spectroscopy. Based on the observed compositional differences and recognizing the imprecise nature of the existing data, 15 samples were chosen to constitute a Venus-analog suite for this study, including five basalts, two each of andesites, dacites, and sulfates, and single samples of a foidite, trachyandesite, rhyolite, and basaltic trachyandesite under Venus conditions. LIBS data reduction involved generating a partial least squares (PLS) model with a subset of the rock powder standards to quantitatively determine the major elemental abundance of the remaining samples. PLS analysis suggests that the major element compositions can be determined with root mean square errors ca. 5% (absolute) for SiO{sub 2}, Al{sub 2}O{sub 3}, Fe{sub 2}O{sub 3}(total), MgO, and CaO, and ca. 2% or less for TiO{sub 2}, Cr{sub 2}O{sub 3}, MnO, K{sub 2}O, and Na{sub 2}O. Finally, the Raman experiments have been conducted under supercritical CO{sub 2} involving single-mineral and mixed-mineral samples containing talc, olivine, pyroxenes, feldspars, anhydrite, barite, and siderite. The Raman data have shown that the individual minerals can easily be identified individually or in mixtures.

  14. Evaluation of Groundwater Movement in the Frenchman Flat CAU Using Geochemical and Isotopic Analysis

    SciTech Connect (OSTI)

    R. Hershey; J. Thomas; T. Rose; J. Paces; I. Farnham; C. Benedict, Jr.

    2005-03-01

    The principal pathway for radionuclide migration from underground tests in Frenchman Flat, on the Nevada Test Site, to the accessible environment is groundwater flow. Two potential pathways for radionuclide transport via groundwater have been identified from hydrologic data: (1) radionuclide transport downward from the alluvial and volcanic aquifers into the underlying carbonate aquifer; and (2) radionuclide transport laterally to the carbonate aquifer surrounding Frenchman Flat. This report presents an evaluation of geochemical and environmental isotopic data to test these potential pathways and to identify other groundwater flowpaths in, and out of, Frenchman Flat.

  15. Computer Modeling of Chemical and Geochemical Processes in High Ionic Strength Solutions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computer modeling of chemical and geochemical processes in high ionic strength solutions is a unique capability within Sandia's Defense Waste Managment Programs located in Carlsbad, New Mexico. We currently have use of EQ3/6 Version 8a, a version of EQ3/6 that is tailored specifically for high ionic strength systems in addition to a library of Pitzer parameters for elements found in WIPP brines. State of the art calculations for brines at WIPP are being performed using EQ3/6 Version 8a for the

  16. Blind Geothermal System Exploration in Active Volcanic Environments; Multi-phase Geophysical and Geochemical Surveys in Overt & Subtle Volcanic Systems, Hawaii & Maui

    Broader source: Energy.gov [DOE]

    DOE Geothermal Technologies Peer Review 2010 - Presentation. Project Objective: To use a combination of traditional geophysical and geochemical tools with exploration suites not typically used in geothermal exploration.

  17. INTERPRETATION REGARDING THE APPLICATION OF DOE TECHNICAL STANDARD...

    Broader source: Energy.gov (indexed) [DOE]

    Department of Energy Office of General Counsel interpretation regarding the application of DOE Technical Standard 1027-92, Hazard Categorization and Accident Analysis Techniques ...

  18. Stochastic Joint Inversion for Integrated Data Interpretation in Geothermal Exploration

    Broader source: Energy.gov [DOE]

    Stochastic Joint Inversion for Integrated Data Interpretation in Geothermal Exploration presentation at the April 2013 peer review meeting held in Denver, Colorado.

  19. Los Alamos technologies help scientists detect, record & interpret...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    'Monster' burst of gamma rays Los Alamos technologies help scientists detect, record & interpret 'monster' burst of gamma rays The burst was detected by NASA's Swift satellite. ...

  20. Fluid Inclusion Stratigraphy Interpretation of New Wells in the...

    Open Energy Info (EERE)

    Stratigraphy Interpretation of New Wells in the Coso Geothermal Field Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Fluid Inclusion...

  1. DOE Withdraws Interpretive Rule and Provides Enforcement Guidance on Showerheads

    Broader source: Energy.gov [DOE]

    The Department has withdrawn as unwarranted the draft interpretative rule setting out the Department's views on the definition of a "showerhead" for purposes of the water conservation standard...

  2. Interpretation of electromagnetic soundings in the Raft River...

    Open Energy Info (EERE)

    electromagnetic soundings in the Raft River geothermal area, Idaho Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Interpretation of electromagnetic...

  3. PyGrid WSDL and XML Schema interpreter

    Energy Science and Technology Software Center (OSTI)

    2003-08-01

    PyGridWare WSDL and XMLSchema interpreter is used to automatically generate python code that maps directly to the XMLSchema objects and WSLD PortTypes

  4. Geochemical Implications of CO2 Leakage Associated with Geologic Storage: A Review

    SciTech Connect (OSTI)

    Harvey, Omar R.; Qafoku, Nikolla; Cantrell, Kirk J.; Brown, Christopher F.

    2012-07-09

    Leakage from deep storage reservoirs is a major risk factor associated with geologic sequestration of carbon dioxide (CO2). Different scientific theories exist concerning the potential implications of such leakage for near-surface environments. The authors of this report reviewed the current literature on how CO2 leakage (from storage reservoirs) would likely impact the geochemistry of near surface environments such as potable water aquifers and the vadose zone. Experimental and modeling studies highlighted the potential for both beneficial (e.g., CO2 re sequestration or contaminant immobilization) and deleterious (e.g., contaminant mobilization) consequences of CO2 intrusion in these systems. Current knowledge gaps, including the role of CO2-induced changes in redox conditions, the influence of CO2 influx rate, gas composition, organic matter content and microorganisms are discussed in terms of their potential influence on pertinent geochemical processes and the potential for beneficial or deleterious outcomes. Geochemical modeling was used to systematically highlight why closing these knowledge gaps are pivotal. A framework for studying and assessing consequences associated with each factor is also presented in Section 5.6.

  5. Interpretation of storage field well casing surface potentials

    SciTech Connect (OSTI)

    Dabkowski, J.

    1987-01-01

    The shape of a well casing-to-soil potential gradient surface profile is influenced by many variables. Hence, the interpretation of such field data can be difficult. The paper illustrates how such factors as layered ground resistivity, polarization potential variations with depth, and external interference affect the profiles and, therefore, the interpretation of field data.

  6. Geothermal well log interpretation state of the art. Final report

    SciTech Connect (OSTI)

    Sanyal, S.K.; Wells, L.E.; Bickham, R.E.

    1980-01-01

    An in-depth study of the state of the art in Geothermal Well Log Interpretation has been made encompassing case histories, technical papers, computerized literature searches, and actual processing of geothermal wells from New Mexico, Idaho, and California. A classification scheme of geothermal reservoir types was defined which distinguishes fluid phase and temperature, lithology, geologic province, pore geometry, salinity, and fluid chemistry. Major deficiencies of Geothermal Well Log Interpretation are defined and discussed with recommendations of possible solutions or research for solutions. The Geothermal Well Log Interpretation study and report has concentrated primarily on Western US reservoirs. Geopressured geothermal reservoirs are not considered.

  7. Workshop on hydrologic and geochemical monitoring in the Long Valley Caldera: proceedings

    SciTech Connect (OSTI)

    Sorey, M.L.; Farrar, C.D.; Wollenberg, H.A.

    1984-10-01

    A workshop reviewed the results of hydrologic and geochemical monitoring in the Long Valley caldera. Such monitoring is being done to detect changes in the hydrothermal system induced by ongoing magmatic and tectonic processes. Workshop participants discussed the need to instrument sites for continuous measurements of several parameters and to obtain additional hydrologic and chemical information from intermediate and deep drill holes. In addition to seismic and deformation monitoring, programs are currently in progress to monitor changes in the discharge characteristics of hot springs, fumaroles, and soil gases, as well as pressures and temperatures in wells. Some hydrochemical parameters are measured continuously, others are measured monthly or at longer intervals. This report summarizes the information presented at the hydrologic monitoring workshop, following the workshop agenda which was divided into four sessions: (1) overview of the hydrothermal system; (2) monitoring springs, fumaroles, and wells; (3) monitoring gas emissions; and (4) conclusions and recommendations.

  8. Geological, geochemical, and geophysical survey of the geothermal resources at Hot Springs Bay Valley, Akutan Island, Alaska

    SciTech Connect (OSTI)

    Motyka, R.J.; Wescott, E.M.; Turner, D.L.; Swanson, S.E.; Romick, J.D.; Moorman, M.A.; Poreda, R.J.; Witte, W.; Petzinger, B.; Allely, R.D.

    1985-01-01

    An extensive survey was conducted of the geothermal resource potential of Hot Springs Bay Valley on Akutan Island. A topographic base map was constructed, geologic mapping, geophysical and geochemical surveys were conducted, and the thermal waters and fumarolic gases were analyzed for major and minor element species and stable isotope composition. (ACR)

  9. Geochemical and physical properties of wetland soils at the Savannah River site

    SciTech Connect (OSTI)

    Dixon, K.L; Rogers, V.A.; Conner, S.P.; Cummings, C.L.; Gladden, J.B.; Weber, J.M.

    1996-05-01

    The Savannah River Site (SRS), located in Aiken, Allendale, and Barnwell Counties, South Carolina, is a nuclear production facility operated for the U.S. Department of Energy (DOE) by Westinghouse Savannah River Company (WSRC). To facilitate future human health and ecological risk assessments, treatability studies, remedial investigations, and feasibility studies for its wetland areas, SRS needs a database of background geochemical and physical properties of wetland soils. These data are needed for comparison to data collected from wetland soils that may have been affected by SRS operations. SRS contains 36,000 acres of wetlands and an additional 5,000 acres of bottom land soils subject to flooding. Recent studies of wetland soils near various waste units at SRS show that some wetlands have been impacted by releases of contaminants resulting from SRS operations (WSRC, 1992). Waste waters originating from the operations facilities typically have been discharged into seepage basins located in upland soils, direct discharge of waste water to wetland areas has been minimal. This suggests that impacted wetland areas have been affected indirectly as a result of transport mechanisms such as surface runoff, groundwater seeps, fluvial or sediment transport, and leaching. Looney et al. (1990) conducted a study to characterize the geochemical and physical properties of upland soils and shallow sediments on the SRS. A primary objective of the upland study was to collect the data needed to assess the qualitative and quantitative impacts of SRS operations on the environment. By comparing the upland soils data to data collected from waste units located in similar soils, SRS impacts could be assessed. The data were also intended to aid in selection of remediation alternatives. Because waste units at SRS have historically been located in upland areas, wetland soils were not sampled. (Abstract Truncated)

  10. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to Unconfined and Confined Aquifers

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Brown, Christopher F.; Wang, Guohui; Sullivan, E. C.; Lawter, Amanda R.; Harvey, Omar R.; Bowden, Mark

    2013-04-15

    Experimental research work has been conducted and is undergoing at Pacific Northwest National Laboratory (PNNL) to address a variety of scientific issues related with the potential leaks of the carbon dioxide (CO2) gas from deep storage reservoirs. The main objectives of this work are as follows: • Develop a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption and redox reactions) in the aquifer sediments. • Identify prevailing environmental conditions that would dictate one geochemical outcome over another. • Gather useful information to support site selection, risk assessment, policy-making, and public education efforts associated with geological carbon sequestration. In this report, we present results from experiments conducted at PNNL to address research issues related to the main objectives of this effort. A series of batch and column experiments and solid phase characterization studies (quantitative x-ray diffraction and wet chemical extractions with a concentrated acid) were conducted with representative rocks and sediments from an unconfined, oxidizing carbonate aquifer, i.e., Edwards aquifer in Texas, and a confined aquifer, i.e., the High Plains aquifer in Kansas. These materials were exposed to a CO2 gas stream simulating CO2 gas leaking scenarios, and changes in aqueous phase pH and chemical composition were measured in liquid and effluent samples collected at pre-determined experimental times. Additional research to be conducted during the current fiscal year will further validate these results and will address other important remaining issues. Results from these experimental efforts will provide valuable insights for the development of site-specific, generation III reduced order models. In addition, results will initially serve as input parameters during model calibration runs and, ultimately, will be used to test model predictive capability and competency. The results from these investigations will provide useful information to support site selection, risk assessment, and public education efforts associated with geological, deep subsurface CO2 storage and sequestration.

  11. Interpretation of self-potential measurements during injection...

    Open Energy Info (EERE)

    self-potential measurements during injection tests at Raft River, Idaho. Final report Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Interpretation of...

  12. Geologic interpretation of gravity and magnetic data in the Salida...

    Open Energy Info (EERE)

    interpretation of gravity and magnetic data in the Salida region, Colorado Authors J.E. Case and R.F. Sikora Published U.S. Geological Survey Open-File Report, 1984 Report...

  13. DOE interpretations Guide to OSH standards. Update to the Guide

    SciTech Connect (OSTI)

    Not Available

    1994-03-31

    Reflecting Secretary O`Leary`s focus on occupational safety and health, the Office of Occupational Safety is pleased to provide you with the latest update to the DOE Interpretations Guide to OSH Standards. This Guide was developed in cooperation with the Occupational Safety and Health Administration, which continued its support during this last revision by facilitating access to the interpretations found on the OSHA Computerized Information System (OCIS). This March 31, 1994 update contains 123 formal interpretation letters written OSHA. As a result of the unique requests received by the 1-800 Response Line, this update also contains 38 interpretations developed by DOE. This new occupational safety and health information adds still more important guidance to the four volume reference set that you presently have in your possession.

  14. APS Tcl/Tk library and interpreter extensions

    SciTech Connect (OSTI)

    Saunders, C.; Borland, M.

    1995-11-27

    This document serves as a User`s Manual and Reference for the library of Tcl and Tk procedures produced by the Operations Analysis Group. Also covered are compiled interpreter extensions.

  15. DOE interpretations Guide to OSH standards. Update to the Guide

    SciTech Connect (OSTI)

    Not Available

    1994-03-31

    Reflecting Secretary O`Leary`s focus on occupational safety and health, the Office of Occupational Safety is pleased to provide you with the latest update to the DOE Interpretations Guide to OSH Standards. This Guide was developed in cooperation with the Occupational Safety and Health Administration, which continued its support during this last revision by facilitating access to the interpretations found on the OSHA Computerized Information System (OCIS). This March 31, 1994 update contains 123 formal interpretation letters written by OSHA. As a result of the unique requests received by the 1-800 Response Line, this update also contains 38 interpretations developed by DOE. This new occupational safety and health information adds still more important guidance to the four volume reference set that you presently have in your possession.

  16. Laboratory Study Supporting the Interpretation of Solar Dynamics

    Office of Scientific and Technical Information (OSTI)

    Observatory data (Journal Article) | SciTech Connect Laboratory Study Supporting the Interpretation of Solar Dynamics Observatory data Citation Details In-Document Search Title: Laboratory Study Supporting the Interpretation of Solar Dynamics Observatory data Authors: Trabert, E ; Beiersdorfer, P Publication Date: 2014-08-26 OSTI Identifier: 1228006 Report Number(s): LLNL-JRNL-659433 DOE Contract Number: AC52-07NA27344 Resource Type: Journal Article Resource Relation: Journal Name: Journal

  17. Laboratory Experiments and Modeling for Interpreting Field Studies of

    Office of Scientific and Technical Information (OSTI)

    Secondary Organic Aerosol Formation Using an Oxidation Flow Reactor (Technical Report) | SciTech Connect SciTech Connect Search Results Technical Report: Laboratory Experiments and Modeling for Interpreting Field Studies of Secondary Organic Aerosol Formation Using an Oxidation Flow Reactor Citation Details In-Document Search Title: Laboratory Experiments and Modeling for Interpreting Field Studies of Secondary Organic Aerosol Formation Using an Oxidation Flow Reactor This grant was

  18. Up-Scaling Geochemical Reaction Rates for Carbon Dioxide (CO2) in Deep Saline Aquifers

    SciTech Connect (OSTI)

    Peters, Catherine A

    2013-02-28

    Geochemical reactions in deep subsurface environments are complicated by the consolidated nature and mineralogical complexity of sedimentary rocks. Understanding the kinetics of these reactions is critical to our ability to make long-term predictions about subsurface processes such as pH buffering, alteration in rock structure, permeability changes, and formation of secondary precipitates. In this project, we used a combination of experiments and numerical simulation to bridge the gap between our knowledge of these reactions at the lab scale and rates that are meaningful for modeling reactive transport at core scales. The focus is on acid-driven mineral dissolution, which is specifically relevant in the context of CO2-water-rock interactions in geological sequestration of carbon dioxide. The project led to major findings in three areas. First, we modeled reactive transport in pore-network systems to investigate scaling effects in geochemical reaction rates. We found significant scaling effects when CO2 concentrations are high and reaction rates are fast. These findings indicate that the increased acidity associated with geological sequestration can generate conditions for which proper scaling tools are yet to be developed. Second, we used mathematical modeling to investigate the extent to which SO2, if co-injected with CO2, would acidify formation brines. We found that there exist realistic conditions in which the impact on brine acidity will be limited due to diffusion rate-limited SO2 dissolution from the CO2 phase, and the subsequent pH shift may also be limited by the lack of availability of oxidants to produce sulfuric acid. Third, for three Viking sandstones (Alberta sedimentary basin, Canada), we employed backscattered electron microscopy and energy dispersive X-ray spectroscopy to statistically characterize mineral contact with pore space. We determined that for reactive minerals in sedimentary consolidated rocks, abundance alone is not a good predictor of mineral accessible surface area, and should not be used in reactive transport modeling. Our work showed that reaction rates would be overestimated by three to five times.

  19. Novel Imaging Techniques, Integrated with Mineralogical, Geochemical and Microbiological Characterization to Determine the Biogeochemical Controls....

    SciTech Connect (OSTI)

    Lloyd, Jonathan R.

    2005-06-01

    Tc(VII) will be reduced and precipitated in FRC sediments under anaerobic conditions in batch experiments (progressive microcosms). The complementary microcosm experiments using low pH/nigh nitrate sediments from 3 (near FW 009) are imminent, with the sediment cores already shipped to Manchester. HYPOTHESIS 2. Tc(VII) reduction and precipitation can be visualized in discrete biogeochemical zones in sediment columns using 99mTc and a gamma-camera. Preliminary experiments testing the use of 99mTc as a radiotracer to address hypotheses 2 and 3 have suggested that the 99mTc associates with Fe(II)-bearing sediments in microcosms and stratified columns containing FRC sediments. Initial proof of concept microcosms containing Fe(II)-bearing, microbially-reduced FRC sediments were spiked with 99mTc and imaged using a gamma-camera. In comparison with oxic controls, 99mTc was significantly partitioned in the solid phase in Fe(III)-reducing sediments in batch experiments. Column experiments using FRC background area soil with stratified biogeochemical zones after stimulation of anaerobic processes through nutrient supplementation, suggested that 99mTc transport was retarded through areas of Fe(III) reduction. HYPOTHESIS 3. Sediment-bound reduced 99mTc can be solubilized by perturbations including oxidation coupled to biological nitrate reduction, and mobilization visualized in real-time using a gamma-camera. Significant progress has been made focusing on the impact of nitrate on the biogeochemical behavior of technetium. Additions of 100 mM nitrate to FRC sediment microcosms, which could potentially compete for electrons during metal reduction, inhibited the reduction of both Fe(III) and Tc(VII) completely. Experiments have also addressed the impact of high nitrate concentrations on Fe(II) and Tc(IV) in pre-reduced sediments, showing no significant resolubilization of Tc with the addition of 25 mM nitrate. A parallel set of experiments addressing the impact of aerobic conditions on the stability/solubility of Fe(II) and Tc(IV), found 80 % resolubilization of the Tc. Column experiments exploring this behavior are being planned. HYPOTHESIS 4 The mobility of 99mTc in the sediment columns can be modeled using a coupled speciation and transport code. Microbiological and geochemical characterization of the column experiments is ongoing and transport and geochemical modeling experiments are being planned.

  20. DOE interpretations Guide to OSH standards. Update to the Guide

    SciTech Connect (OSTI)

    Not Available

    1994-03-31

    Reflecting Secretary O`Leary`s focus on occupational safety and health, the Office of Occupational Safety is pleased to provide you with the latest update to the DOE Interpretations Guide to OSH Standards. This Guide was developed in cooperation with the Occupational Safety and Health Administration, which continued it`s support during this last revision by facilitating access to the interpretations found on the OSHA Computerized Information System (OCIS). This March 31, 1994 update contains 123 formal in letter written by OSHA. As a result of the unique requests received by the 1-800 Response Line, this update also contains 38 interpretations developed by DOE. This new occupational safety and health information adds still more important guidance to the four volume reference set that you presently have in your possession.

  1. DEPARTMENT OF ENERGY OFFICE OF GENERAL COUNSEL INTERPRETATION

    Energy Savers [EERE]

    INTERPRETATION REGARDING THE APPLICATION OF DOE TECHNICAL STANDARD 1027-92, HAZARD CATEGORIZATION AND ACCIDENT ANALYSIS TECHNIQUES FOR COMPLIANCE WITH DOE ORDER 5480.23, NUCLEAR SAFETY ANALYSIS REPORTS, UNDER THE PROVISIONS OF 10 C.F.R. § 830.202(b)(3) In accordance with 10 C.F.R § 820.51, the Department of Energy (DOE) Acting General Counsel is responding to a request to provide an interpretation concerning a DOE Nuclear Safety Requirement: the application of DOE Technical Standard 1027-92,

  2. Comparison of microbial and sorbed soil gas surgace geochemical techniques with seismic surveys from the Southern Altiplano, Bolivia

    SciTech Connect (OSTI)

    Aranibar, O.R.; Tucker, J.D.; Hiltzman, D.C.

    1995-12-31

    Yacimientos Petroliferos Fiscales Bolivianos (YPFB) undertook a large seismic evaluation in the southern Altiplano, Bolivia in 1994. As an additional layer of information, sorbed soil gas and Microbial Oil Survey Technique (MOST) geochemical surveys were conducted to evaluate the hydrocarbon microseepage potential. The Wara Sara Prospect had 387 sorbed soil gas samples, collected from one meter depth, and 539 shallow soil microbial samples, collected from 15 to 20 centimeter depth. The sorbed soil gas samples were collected every 500 meters and microbial samples every 250 meters along geochemical traverses spaced 1 km apart. The presence of anmalous hydrocarbon microseepage is indicated by (1) a single hydrocarbon source identified by gas crossplots, (2) the high gas values with a broad range, (3) the high overall gas average, (4) the clusters of elevated samples, and (5) the right hand skewed data distributions.

  3. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bacon, Diana H.; Dai, Zhenxue; Zheng, Liange

    2014-12-31

    An important risk at CO2 storage sites is the potential for groundwater quality impacts. As part of a system to assess the potential for these impacts a geochemical scaling function has been developed, based on a detailed reactive transport model of CO2 and brine leakage into an unconfined, oxidizing carbonate aquifer. Stochastic simulations varying a number of geochemical parameters were used to generate a response surface predicting the volume of aquifer that would be impacted with respect to regulated contaminants. The brine was assumed to contain several trace metals and organic contaminants. Aquifer pH and TDS were influenced by CO2more » leakage, while trace metal concentrations were most influenced by the brine concentrations rather than adsorption or desorption on calcite. Organic plume sizes were found to be strongly influenced by biodegradation.« less

  4. Improved Geothermometry Through Multivariate Reaction-path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators: Final Report

    SciTech Connect (OSTI)

    Mattson, Earl; Smith, Robert; Fujita, Yoshiko; McLing, Travis; Neupane, Ghanashyam; Palmer, Carl; Reed, David; Thompson, Vicki

    2015-03-01

    The project was aimed at demonstrating that the geothermometric predictions can be improved through the application of multi-element reaction path modeling that accounts for lithologic and tectonic settings, while also accounting for biological influences on geochemical temperature indicators. The limited utilization of chemical signatures by individual traditional geothermometer in the development of reservoir temperature estimates may have been constraining their reliability for evaluation of potential geothermal resources. This project, however, was intended to build a geothermometry tool which can integrate multi-component reaction path modeling with process-optimization capability that can be applied to dilute, low-temperature water samples to consistently predict reservoir temperature within ±30 °C. The project was also intended to evaluate the extent to which microbiological processes can modulate the geochemical signals in some thermal waters and influence the geothermometric predictions.

  5. GaMin’11 – an international inter-laboratory comparison for geochemical CO₂ - saline fluid - mineral interaction experiments

    SciTech Connect (OSTI)

    Ostertag-Henning, C.; Risse, A.; Thomas, B.; Rosenbauer, R.; Rochelle, C.; Purser, G.; Kilpatrick, A.; Rosenqvist, J.; Yardley, B.; Karamalidis, A.; Griffith, C.; Hedges, S.; Dilmore, R.; Goodman, A.; Black, J.; Haese, R.; Deusner, C.; Bigalke, N.; Haeckel, M.; Fischer, S.; Liebscher, A.; Icenhower, J. P.; Daval, D.; Saldi, G. D.; Knauss, K. G.; Schmidt, M.; Mito, S.; Sorai, M.; Truche, L.

    2014-12-31

    Due to the strong interest in geochemical CO₂-fluid-rock interaction in the context of geological storage of CO₂ a growing number of research groups have used a variety of different experimental ways to identify important geochemical dissolution or precipitation reactions and – if possible – quantify the rates and extent of mineral or rock alteration. In this inter-laboratory comparison the gas-fluid-mineral reactions of three samples of rock-forming minerals have been investigated by 11 experimental labs. The reported results point to robust identification of the major processes in the experiments by most groups. The dissolution rates derived from the changes in composition of the aqueous phase are consistent overall, but the variation could be reduced by using similar corrections for changing parameters in the reaction cells over time. The comparison of experimental setups and procedures as well as of data corrections identified potential improvements for future gas-fluid-rock studies.

  6. The low temperature hydrothermal system of Campiglia, Tuscany (Italy); A geochemical approach

    SciTech Connect (OSTI)

    Celati, R.; Grassi, S.; D'Amore, F.; Marcolini, L. )

    1991-01-01

    This paper reports on the Campiglia hydrothermal system which is a low temperature hydrothermal system located in southwestern Tuscany, a region of Italy characterized by intense geothermal activity and by the presence of high temperature exploited geothermal reservoirs. Six water-points, with temperatures ranging between 20 and 47{degrees} C and different chemical and isotopic compositions, are found close to the margins of outcrops of the main regional aquifer formation. Systematic hydrogeological, geochemical and isotopic observations and temperature measurements were carried out on the different springs and wells for a period of three years (1984-1986). Constant water characteristics with time were observed in four water-points; two wells had variable trends depending on mixing processes. A groundwater circulation model characterized by flowpaths of different length and depth is suggested by the variety of chemical and isotopic characteristics and is consistent with geothermometry, which indicates temperatures up to 25{degrees} C higher than those measured at the spring emergencies. An important water supply to the system comes from local recharge, although regional circulation may also be present, particularly in the eastern part of the investigated area.

  7. Geochemical information for sites contaminated with low-level radioactive wastes: I. Niagara Falls Storage Site

    SciTech Connect (OSTI)

    Seeley, F.G.; Kelmers, A.D.

    1984-11-01

    The Niagara Falls Storage Site (NFSS) became radioactively contaminated as a result of wastes that were being stored from operations carried out to recover uranium from pitchblende ore in the 1940s and 1950s. The US Department of Energy (DOE) is considering various remedial action options for the NFSS. This report describes the results of geochemical investigations performed to help provide a quantitative evaluation of the effects of various options. NFSS soil and groundwater samples were characterized; and uranium and radium sorption ratios, as well as apparent concentration limit values, were measured in site soil/groundwater systems by employing batch contact methodology. The results suggest that any uranium which is in solution in the groundwater at the NFSS may be poorly retarded due to the low uranium sorption ratio values and high solubility measured. Further, appreciable concentrations of uranium in groundwater could be attained from soluble wastes. Release of uranium via groundwater migration could be a significant release pathway. Solubilized radium would be expected to be effectively retarded by soil at the NFSS as a result of the very high radium sorption ratios observed. The addition of iron oxyhydroxide to NFSS soils resulted in much higher uranium sorption ratios. Additional field testing of this potential remedial action additive could be desirable. 10 references.

  8. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    Office of Scientific and Technical Information (OSTI)

    3 (2014) 4684 - 4707 Energy Procedia GHGT-12 Geochemical impacts of carbon dioxide, brine, trace metal and organic leakage into an unconfined, oxidizing limestone aquifer Diana H. Bacon3'* *, Zhenxue Daib, Liange Zhengc "Pacific Northwest National Laboratory, Richland, Washington, USA bLos Alamos National Laboratory, Los Alamos, New Mexico, USA cLawrence Berkeley National Laboratory, Berkeley, California, USA Abstract An important risk at CO2 storage sites is the potential for groundwater

  9. TOUGHREACT: A Simulation Program for Non-isothermal Multiphase Reactive Geochemical Transport in Variably Saturated Geologic M

    Office of Scientific and Technical Information (OSTI)

    TOUGHREACT: A Simulation Program for Non-isothermal Multiphase Reactive Geochemical Transport in Variably Saturated Geologic Media Tianfu Xu, Eric Sonnenthal, Nicolas Spycher , and Karsten Pruess Earth Sciences Division, Lawrence Berkeley National Laboratory University of California, Berkeley, CA 94720, USA Abstract. TOUGHREACT is a numerical simulation program for chemically reactive non-isothermal flows of multiphase fluids in porous and fractured media. The program was written in Fortran 77

  10. Microbial distributions detected by an oligonucleotide microarray across geochemical zones associated with methane in marine sediments from the Ulleung Basin

    SciTech Connect (OSTI)

    Briggs, Brandon R.; Graw, Michael; Brodie, Eoin L.; Bahk, Jang-Jun; Kim, Sung-Han; Hyun, Jung-Ho; Kim, Ji-Hoon; Torres, Marta; Colwell, Frederick S.

    2013-11-01

    The biogeochemical processes that occur in marine sediments on continental margins are complex; however, from one perspective they can be considered with respect to three geochemical zones based on the presence and form of methane: sulfatemethane transition (SMTZ), gas hydrate stability zone (GHSZ), and free gas zone (FGZ). These geochemical zones may harbor distinct microbial communities that are important in biogeochemical carbon cycles. The objective of this study was to describe the microbial communities in sediments from the SMTZ, GHSZ, and FGZ using molecular ecology methods (i.e. PhyloChip microarray analysis and terminal restriction fragment length polymorphism (T-RFLP)) and examining the results in the context of non-biological parameters in the sediments. Non-metric multidimensional scaling and multi-response permutation procedures were used to determine whether microbial community compositions were significantly different in the three geochemical zones and to correlate samples with abiotic characteristics of the sediments. This analysis indicated that microbial communities from all three zones were distinct from one another and that variables such as sulfate concentration, hydrate saturation of the nearest gas hydrate layer, and depth (or unmeasured variables associated with depth e.g. temperature, pressure) were correlated to differences between the three zones. The archaeal anaerobic methanotrophs typically attributed to performing anaerobic oxidation of methane were not detected in the SMTZ; however, the marine benthic group-B, which is often found in SMTZ, was detected. Within the GHSZ, samples that were typically closer to layers that contained higher hydrate saturation had indicator sequences related to Vibrio-type taxa. These results suggest that the biogeographic patterns of microbial communities in marine sediments are distinct based on geochemical zones defined by methane.

  11. Geochemical Data Package for the 2005 Hanford Integrated Disposal Facility Performance Assessment

    SciTech Connect (OSTI)

    Krupka, Kenneth M.; Serne, R JEFFREY.; Kaplan, D I.

    2004-09-30

    CH2M HILL Hanford Group, Inc. (CH2M HILL) is designing and assessing the performance of an integrated disposal facility (IDF) to receive low-level waste (LLW), mixed low-level waste (MLLW), immobilized low-activity waste (ILAW), and failed or decommissioned melters. The CH2M HILL project to assess the performance of this disposal facility is the Hanford IDF Performance Assessment (PA) activity. The goal of the Hanford IDF PA activity is to provide a reasonable expectation that the disposal of the waste is protective of the general public, groundwater resources, air resources, surface-water resources, and inadvertent intruders. Achieving this goal will require prediction of contaminant migration from the facilities. This migration is expected to occur primarily via the movement of water through the facilities, and the consequent transport of dissolved contaminants in the vadose zone to groundwater where contaminants may be re-introduced to receptors via drinking water wells or mixing in the Columbia River. Pacific Northwest National Laboratory (PNNL) assists CH2M HILL in their performance assessment activities. One of the PNNL tasks is to provide estimates of the geochemical properties of the materials comprising the IDF, the disturbed region around the facility, and the physically undisturbed sediments below the facility (including the vadose zone sediments and the aquifer sediments in the upper unconfined aquifer). The geochemical properties are expressed as parameters that quantify the adsorption of contaminants and the solubility constraints that might apply for those contaminants that may exceed solubility constraints. The common parameters used to quantify adsorption and solubility are the distribution coefficient (Kd) and the thermodynamic solubility product (Ksp), respectively. In this data package, we approximate the solubility of contaminants using a more simplified construct, called the solution concentration limit, a constant value. The Kd values and solution concentration limits for each contaminant are direct inputs to subsurface flow and transport codes used to predict the performance of the IDF system. In addition to the best-estimate Kd values, a reasonable conservative value and a range are provided. The data package does not list estimates for the range in solubility limits or their uncertainty. However, the data package does provide different values for both the Kd values and solution concentration limits for different spatial zones in the IDF system and does supply time-varying Kd values for the cement solidified waste. The Kd values and solution concentration limits presented for each contaminant were previously presented in a report prepared by Kaplan and Serne (2000) for the 2001 ILAW PA, and have been updated to include applicable data from investigations completed since the issuance of that report and improvements in our understanding of the geochemistry specific to Hanford. A discussion is also included of the evolution of the Kd values recommended from the original 1999 ILAW PA through the 2001 ILAW and 2003 Supplement PAs to the current values to be used for the 2005 IDF PA for the key contaminants of concern: Cr(VI), nitrate, 129I, 79Se, 99Tc, and U(VI). This discussion provides the rationale for why certain Kd have changed with time.

  12. Geochemical engineering design tools for uranium in situ recovery : the HYDROGEOCHEM codes.

    SciTech Connect (OSTI)

    Siegel, Malcolm Dean; Li, Ming-Hsu; Yeh, Gour-Tsyh

    2010-11-01

    Geochemical Engineering Design (GED) is based on applications of the principles and various computer models that describe the biogeochemistry and physics of removal of contaminants from water by adsorption, precipitation and filtration. It can be used to optimize or evaluate the efficiency of all phases of in situ recovery (ISR). The primary tools of GED are reactive transport models; this talk describes the potential application of the HYDROGEOCHEM family of codes to ISR. The codes can describe a complete suite of equilibrium or kinetic aqueous complexation, adsorption-desorption, precipitation-dissolution, redox, and acid-base reactions in variably saturated media with density-dependent fluid flow. Applications to ISR are illustrated with simulations of (1) the effectiveness of a reactive barrier to prevent off-site uranium migration and (2) evaluation of the effect of sorption hysteresis on natural attenuation. In the first example, it can be seen that the apparent effectiveness of the barrier depends on monitoring location and that it changes over time. This is due to changes in pH, saturation of sorption sites, as well as the geometry of the flow field. The second simulation shows how sorption hysteresis leads to observable attenuation of a uranium contamination plume. Different sorption mechanisms including fast (or reversible), slow, and irreversible sorption were simulated. The migration of the dissolved and total uranium plumes for the different cases are compared and the simulations show that when 50-100% of the sites have slow desorption rates, the center of mass of the dissolved uranium plume begins to move upstream. This would correspond to the case in which the plume boundaries begin to shrink as required for demonstration of natural attenuation.

  13. Model-Based Analysis of the Role of Biological, Hydrological and Geochemical Factors Affecting Uranium Bioremediation

    SciTech Connect (OSTI)

    Zhao, Jiao; Scheibe, Timothy D.; Mahadevan, Radhakrishnan

    2011-01-24

    Uranium contamination is a serious concern at several sites motivating the development of novel treatment strategies such as the Geobacter-mediated reductive immobilization of uranium. However, this bioremediation strategy has not yet been optimized for the sustained uranium removal. While several reactive-transport models have been developed to represent Geobacter-mediated bioremediation of uranium, these models often lack the detailed quantitative description of the microbial process (e.g., biomass build-up in both groundwater and sediments, electron transport system, etc.) and the interaction between biogeochemical and hydrological process. In this study, a novel multi-scale model was developed by integrating our recent model on electron capacitance of Geobacter (Zhao et al., 2010) with a comprehensive simulator of coupled fluid flow, hydrologic transport, heat transfer, and biogeochemical reactions. This mechanistic reactive-transport model accurately reproduces the experimental data for the bioremediation of uranium with acetate amendment. We subsequently performed global sensitivity analysis with the reactive-transport model in order to identify the main sources of prediction uncertainty caused by synergistic effects of biological, geochemical, and hydrological processes. The proposed approach successfully captured significant contributing factors across time and space, thereby improving the structure and parameterization of the comprehensive reactive-transport model. The global sensitivity analysis also provides a potentially useful tool to evaluate uranium bioremediation strategy. The simulations suggest that under difficult environments (e.g., highly contaminated with U(VI) at a high migration rate of solutes), the efficiency of uranium removal can be improved by adding Geobacter species to the contaminated site (bioaugmentation) in conjunction with the addition of electron donor (biostimulation). The simulations also highlight the interactive effect of initial cell concentration and flow rate on U(VI) reduction.

  14. Scaling Effects of Cr(VI) Reduction Kinetics. The Role of Geochemical Heterogeneity

    SciTech Connect (OSTI)

    Wang, Li; Li, Li

    2015-10-22

    The natural subsurface is highly heterogeneous with minerals distributed in different spatial patterns. Fundamental understanding of how mineral spatial distribution patterns regulate sorption process is important for predicting the transport and fate of chemicals. Existing studies about the sorption was carried out in well-mixed batch reactors or uniformly packed columns, with few data available on the effects of spatial heterogeneities. As a result, there is a lack of data and understanding on how spatial heterogeneities control sorption processes. In this project, we aim to understand and develop modeling capabilities to predict the sorption of Cr(VI), an omnipresent contaminant in natural systems due to its natural occurrence and industrial utilization. We systematically examine the role of spatial patterns of illite, a common clay, in determining the extent of transport limitation and scaling effects associated with Cr(VI) sorption capacity and kinetics using column experiments and reactive transport modeling. Our results showed that the sorbed mass and rates can differ by an order of magnitude due to of the illite spatial heterogeneities and transport limitation. With constraints from data, we also developed the capabilities of modeling Cr(VI) in heterogeneous media. The developed model is then utilized to understand the general principles that govern the relationship between sorption and connectivity, a key measure of the spatial pattern characteristics. This correlation can be used to estimate Cr(VI) sorption characteristics in heterogeneous porous media. Insights gained here bridge gaps between laboratory and field application in hydrogeology and geochemical field, and advance predictive understanding of reactive transport processes in the natural heterogeneous subsurface. We believe that these findings will be of interest to a large number of environmental geochemists and engineers, hydrogeologists, and those interested in contaminant fate and transport, water quality and water composition, and natural attenuation processes in natural systems.

  15. Characterizing Microbial Community and Geochemical Dynamics at Hydrothermal Vents Using Osmotically Driven Continuous Fluid Samplers

    SciTech Connect (OSTI)

    Robidart, Julie C.; Callister, Stephen J.; Song, Peng F.; Nicora, Carrie D.; Wheat, Charles G.; Girguis, Peter R.

    2013-05-07

    Microbes play a key role in mediating all aquatic biogeochemical cycles, and ongoing efforts are aimed at better understanding the relationships between microbial phylogenetic and physiological diversity, and habitat physical and chemical characteristics. Establishing such relationships is facilitated by sampling and studying microbiology and geochemistry at the appropriate spatial and temporal scales, to access information on the past and current environmental state that contributes to observed microbial abundances and activities. A modest number of sampling systems exist to date, few of which can be used in remote, harsh environments such as hydrothermal vents, where the ephemeral nature of venting underscores the necessity for higher resolution sampling. We have developed a robust, continuous fluid sampling system for co-registered microbial and biogeochemical analyses. The osmosis-powered bio-osmosampling system (BOSS) use no electricity, collects fluids with daily resolution or better, can be deployed in harsh, inaccessible environments and can sample fluids continuously for up to five years. Here we present a series of tests to examine DNA, RNA and protein stability over time, as well as material compatability, via lab experiments. We also conducted two field deployments at deep-sea hydrothermal vents to assess changes in microbial diversity and protein expression as a function of the physico-chemical environment. Our data reveal significant changes in microbial community composition co-occurring with relatively modest changes in the geochemistry. These data additionally provide new insights into the distribution of an enigmatic sulfur oxidizing symbiont in its free-living state. Data from the second deployment reveal differences in the representation of peptides over time, underscoring the utility of the BOSS in meta-proteomic studies. In concert, these data demonstrate the efficacy of this approach, and illustrate the value of using this method to study microbial and geochemical phenomena.

  16. Geochemical Evidence of the Seasonality, Affinity and Pigmenation of Solenopora jurassica

    SciTech Connect (OSTI)

    Barden, Holly E.; Behnsen, Julia; Bergmann, Uwe; Leng, Melanie J.; Manning, Phillip L.; Withers, Philip J.; Wogelius, Roy A.; van Dongen, Bart E.; Silva, Lucas C. R.

    2015-09-14

    Solenopora jurassica is a fossil calcareous alga that functioned as an important reef-building organism during the Palaeozoic. It is of significant palaeobiological interest due to its distinctive but poorly understood pink and white banding. Though widely accepted as an alga there is still debate over its taxonomic affinity, with recent work arguing that it should be reclassified as a chaetetid sponge. The banding is thought to be seasonal, but there is no conclusive evidence for this. Other recent work has, however demonstrated the presence of a unique organic boron-containing pink/red pigment in the pink bands of S. jurassica. We present new geochemical evidence concerning the seasonality and pigmentation of S. jurassica. Seasonal growth cycles are demonstrated by X-ray radiography, which shows differences in calcite density, and by varying δ13C composition of the bands. Temperature variation in the bands is difficult to constrain accurately due to conflicting patterns arising from Mg/Ca molar ratios and δ18O data. Fluctuating chlorine levels indicate increased salinity in the white bands, when combined with the isotope data this suggests more suggestive of marine conditions during formation of the white band and a greater freshwater component (lower chlorinity) during pink band precipitation (δ18O). Increased photosynthesis is inferred within the pink bands in comparison to the white, based on δ13C. Pyrolysis Gas Chromatography Mass Spectrometry (Py-GCMS) and Fourier Transform Infrared Spectroscopy (FTIR) show the presence of tetramethyl pyrrole, protein moieties and carboxylic acid groups, suggestive of the presence of the red algal pigment phycoerythrin. This is consistent with the pink colour of S. jurassica. As phycoerythrin is only known to occur in algae and cyanobacteria, and no biomarker evidence of bacteria or sponges was detected we conclude S. jurassica is most likely an alga. Pigment analysis may be a reliable classification method for fossil algae.

  17. Geochemical Evidence of the Seasonality, Affinity and Pigmenation of Solenopora jurassica

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Barden, Holly E.; Behnsen, Julia; Bergmann, Uwe; Leng, Melanie J.; Manning, Phillip L.; Withers, Philip J.; Wogelius, Roy A.; van Dongen, Bart E.; Silva, Lucas C. R.

    2015-09-14

    Solenopora jurassica is a fossil calcareous alga that functioned as an important reef-building organism during the Palaeozoic. It is of significant palaeobiological interest due to its distinctive but poorly understood pink and white banding. Though widely accepted as an alga there is still debate over its taxonomic affinity, with recent work arguing that it should be reclassified as a chaetetid sponge. The banding is thought to be seasonal, but there is no conclusive evidence for this. Other recent work has, however demonstrated the presence of a unique organic boron-containing pink/red pigment in the pink bands of S. jurassica. We presentmore » new geochemical evidence concerning the seasonality and pigmentation of S. jurassica. Seasonal growth cycles are demonstrated by X-ray radiography, which shows differences in calcite density, and by varying δ13C composition of the bands. Temperature variation in the bands is difficult to constrain accurately due to conflicting patterns arising from Mg/Ca molar ratios and δ18O data. Fluctuating chlorine levels indicate increased salinity in the white bands, when combined with the isotope data this suggests more suggestive of marine conditions during formation of the white band and a greater freshwater component (lower chlorinity) during pink band precipitation (δ18O). Increased photosynthesis is inferred within the pink bands in comparison to the white, based on δ13C. Pyrolysis Gas Chromatography Mass Spectrometry (Py-GCMS) and Fourier Transform Infrared Spectroscopy (FTIR) show the presence of tetramethyl pyrrole, protein moieties and carboxylic acid groups, suggestive of the presence of the red algal pigment phycoerythrin. This is consistent with the pink colour of S. jurassica. As phycoerythrin is only known to occur in algae and cyanobacteria, and no biomarker evidence of bacteria or sponges was detected we conclude S. jurassica is most likely an alga. Pigment analysis may be a reliable classification method for fossil algae.« less

  18. Geochemical information for sites contaminated with low-level radioactive wastes. III. Weldon Spring Storage Site

    SciTech Connect (OSTI)

    Seeley, F.G.; Kelmers, A.D.

    1985-02-01

    The Weldon Spring Storage Site (WSSS), which includes both the chemical site and the quarry, became radioactively contaminated as the result of wastes that were being stored from operations to recover uranium from pitchblende ores in the 1940s and 1950s. The US Department of Energy (DOE) is considering various remedial action options for the WSSS. This report describes the results of geochemical investigations carried out at Oak Ridge National Laboratory (ORNL) to support these activities and to help quantify various remedial action options. Soil and groundwater samples were characterized, and uranium and radium sorption ratios were measured in site soil/groundwater systems by batch contact methodology. Soil samples from various locations around the raffinate pits were found to contain major amounts of silica, along with illite as the primary clay constituent. Particle sizes of the five soil samples were variable (50% distribution point ranging from 12 to 81 ..mu..m); the surface areas varied from 13 to 62 m/sup 2//g. Elemental analysis of the samples showed them to be typical of sandy clay and silty clay soils. Groundwater samples included solution from Pit 3 and well water from Well D. Anion analyses showed significant concentrations of sulfate and nitrate (>350 and >7000 mg/L, respectively) in the solution from Pit 3. These anions were also present in the well water, but in lower concentrations. Uranium sorption ratios for four of the soil samples contacted with the solution from Pit 3 were moderate to high (approx. 300 to approx. 1000 mL/g). The fifth sample had a ratio of only 12 mL/g. Radium sorption ratios for the five samples were moderate to high (approx. 600 to approx. 1000 mL/g). These values indicate that soil at the WSSS may show favorable retardation of uranium and radium in the groundwater. 13 references, 13 figures, 10 tables.

  19. Coupled Geochemical Impacts of Leaking CO2 and Contaminants from Subsurface Storage Reservoirs on Groundwater Quality

    SciTech Connect (OSTI)

    Shao, Hongbo; Qafoku, Nikolla; Lawter, Amanda R.; Bowden, Mark E.; Brown, Christopher F.

    2015-07-07

    The leakage of CO2 and the concomitant saline solutions from deep storage reservoirs to overlying groundwater aquifers is considered one of the major potential risks associated with geologic CO2 sequestration (GCS). Batch and column experiments were conducted to determine the fate of trace metals in groundwater in the scenarios of CO2 and metal contaminated brine leakage. The sediments used in this work were collected from an unconsolidated sand and gravel aquifer in Kansas, and contained 0-4 wt% carbonates. Cd and As were spiked into the reaction system to represent potential contaminants from the reservoir brine that could intrude into groundwater aquifers with leaking CO2 at initial concentrations of 114 and 40 ppb, respectively. Through this research we demonstrated that Cd and As were adsorbed on the sediments, in spite of the lowered pH due to CO2 dissolution in the groundwater. Cd concentrations were well below its MCL in both batch and column studies, even for sediment samples without detectable carbonate to buffer the pH. Arsenic concentrations in the effluent were also significantly lower than influent concentration, suggesting that the sediments tested have the capacity to mitigate the coupled adverse effects of CO2 leakage and brine intrusion. However, the mitigation capacity of sediment is a function of its geochemical properties [e.g., the calcite content; the presence of adsorbed As(III); and the presence of P in the natural sediment]. The competitive adsorption between phosphate and arsenate may result in higher concentrations of As in the aqueous phase.

  20. NREL: Jobs and Economic Development Impact (JEDI) Models - Interpreting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Results Interpreting Results Sample Results from JEDI. Download a text-version (MS Excel 44 KB) The Jobs and Economic Development Impact (JEDI) models estimate the number of jobs and economic impacts associated with power generation, fuel production, and other projects. Economic activity in input-output models is typically assessed in three categories. NREL's JEDI models classify the first category of results-on-site labor and professional services results-as dollars spent on labor from

  1. Two-dimensional interpreter for field-reversed configurations

    SciTech Connect (OSTI)

    Steinhauer, Loren

    2014-08-15

    An interpretive method is developed for extracting details of the fully two-dimensional (2D) “internal” structure of field-reversed configurations (FRC) from common diagnostics. The challenge is that only external and “gross” diagnostics are routinely available in FRC experiments. Inferring such critical quantities as the poloidal flux and the particle inventory has commonly relied on a theoretical construct based on a quasi-one-dimensional approximation. Such inferences sometimes differ markedly from the more accurate, fully 2D reconstructions of equilibria. An interpreter based on a fully 2D reconstruction is needed to enable realistic within-the-shot tracking of evolving equilibrium properties. Presented here is a flexible equilibrium reconstruction with which an extensive data base of equilibria was constructed. An automated interpreter then uses this data base as a look-up table to extract evolving properties. This tool is applied to data from the FRC facility at Tri Alpha Energy. It yields surprising results at several points, such as the inferences that the local β (plasma pressure/external magnetic pressure) of the plasma climbs well above unity and the poloidal flux loss time is somewhat longer than previously thought, both of which arise from full two-dimensionality of FRCs.

  2. ENZYME ACTIVITY PROBE AND GEOCHEMICAL ASSESSMENT FOR POTENTIAL AEROBIC COMETABOLISM OF TRICHLOROETHENE IN GROUNDWATER OF THE NORTHWEST PLUME, PADUCAH GASEOUS DIFFUSION PLANT, KENTUCKY

    SciTech Connect (OSTI)

    Looney, B; M. Hope Lee, M; S. K. Hampson, S

    2008-06-27

    The overarching objective of the Paducah Gaseous Diffusion Plant (PGDP) enzyme activity probe (EAP) effort is to determine if aerobic cometabolism is contributing to the attenuation of trichloroethene (TCE) and other chlorinated solvents in the contaminated groundwater beneath PGDP. The site-specific objective for the EAP assessment is to identify if key metabolic pathways are present and expressed in the microbial community--namely the pathways that are responsible for degradation of methane and aromatic (e.g. toluene, benzene, phenol) substrates. The enzymes produced to degrade methane and aromatic compounds also break down TCE through a process known as cometabolism. EAPs directly measure if methane and/or aromatic enzyme production pathways are operating and, for the aromatic pathways, provide an estimate of the number of active organisms in the sampled groundwater. This study in the groundwater plumes at PGDP is a major part of a larger scientific effort being conducted by Interstate Technology and Regulatory Council (ITRC), U.S. Department of Energy (DOE) Office of Environmental Management (EM), Savannah River National Laboratory (SRNL), and North Wind Inc. in which EAPs are being applied to contaminated groundwater from diverse hydrogeologic and plume settings throughout the U.S. to help standardize their application as well as their interpretation. While EAP data provide key information to support the site specific objective for PGDP, several additional lines of evidence are being evaluated to increase confidence in the determination of the occurrence of biodegradation and the rate and sustainability of aerobic cometabolism. These complementary efforts include: (1) Examination of plume flowpaths and comparison of TCE behavior to 'conservative' tracers in the plume (e.g., {sup 99}Tc); (2) Evaluation of geochemical conditions throughout the plume; and (3) Evaluation of stable isotopes in the contaminants and their daughter products throughout the plume. If the multiple lines of evidence support the occurrence of cometabolism and the potential for the process to contribute to temporal and spatial attenuation of TCE in PGDP groundwater, then a follow-up enzyme probe microcosm study to better estimate biological degradation rate(s) is warranted.

  3. Structural Analysis for Gold Mineralization Using Remote Sensing and Geochemical Techniques in a GIS Environment: Island of Lesvos, Hellas

    SciTech Connect (OSTI)

    Rokos, D. Argialas, D. Mavrantza, R. St Seymour, K.; Vamvoukakis, C.; Kouli, M.; Lamera, S.; Paraskevas, H.; Karfakis, I.; Denes, G

    2000-12-15

    Exploration for epithermal Au has been active lately in the Aegean Sea of the eastern Mediterranean Basin, both in the islands of the Quaternary arc and in those of the back-arc region. The purpose of this study was the structural mapping and analysis for a preliminary investigation of possible epithermal gold mineralization, using remotely sensed data and techniques, structural and field data, and geochemical information, for a specific area on the Island of Lesvos. Therefore, Landsat-TM and SPOT-Pan satellite images and the Digital Elevation Model (DEM) of the study area were processed digitally using spatial filtering techniques for the enhancement and recognition of the geologically significant lineaments, as well as algebraic operations with band ratios and Principal Component Analysis (PCA), for the identification of alteration zones. Statistical rose diagrams and a SCHMIDT projection Stereo Net were generated from the lineament maps and the collected field data (dip and strike measurements of faults, joints, and veins), respectively. The derived lineament map and the band ratio images were manipulated in a GIS environment, in order to study the relation of the tectonic pattern to both the alteration zoning and the geomorphology of the volcanic field of the study area. Target areas of high interest for possible mineralization also were specified using geochemical techniques, such as X-Ray Diffraction (XRD) analysis, trace-element, and fluid-inclusion analysis. Finally, preliminary conclusions were derived about possible mineralization, the type (high or low sulfidation), and the extent of mineralization, by combining the structural information with geochemical information.

  4. Sampling designs for geochemical baseline studies in the Colorado oil shale region: a manual for practical application

    SciTech Connect (OSTI)

    Klusman, R. W.; Ringrose, C. D.; Candito, R. J.; Zuccaro, B.; Rutherford, D. W.; Dean, W. E.

    1980-06-01

    This manual presents a rationale for sampling designs, and results of geochemical baseline studies in the Colorado portion of the oil-shale region. The program consists of a systematic trace element study of soils, stream sediments, and plants carried out in a way to be conservative of human and financial resources and yield maximum information. Extension of this approach to other parameters, other locations, and to environmental baseline studies in general is a primary objective. A baseline for any geochemical parameter can be defined as the concentration of that parameter in a given medium such as soil, the range of its concentration, and the geographic scale of variability. In air quality studies, and to a lesser extent for plants, the temporal scale of variability must also be considered. In studies of soil, the temporal variablility does not become a factor until such time that a study is deemed necessary to evaluate whether or not there have been changes in baseline levels as a result of development. The manual is divided into five major parts. The first is a suggested sampling protocol which is presented in an outline form for guiding baseline studies in this area. The second section is background information on the physical features of the area of study, trace elements of significance occurring in oil shale, and the sample media used in these studies. The third section is concerned primarily with sampling design and its application to the geochemical studies of the oil shale region. The last sections, in the form of appendices, provide actual data and illustrate in a systematic manner, the calculations performed to obtain the various summary data. The last segment of the appendices is a more academic discussion of the geochemistry of trace elements and the parameters of importance influencing their behavior in natural systems.

  5. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation “C”. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthitemore » component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation “C” sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.« less

  6. Final Report: Molecular Basis for Microbial Adhesion and Geochemical Surface Reactions: A Study Across Scales

    SciTech Connect (OSTI)

    Dixon, David Adams

    2013-06-27

    Computational chemistry was used to help provide a molecular level description of the interactions of Gram-negative microbial membranes with subsurface materials. The goal is to develop a better understanding of the molecular processes involved in microbial metal binding, microbial attachment to mineral surfaces, and, eventually, oxidation/reduction reactions (electron transfer) that can occur at these surfaces and are mediated by the bacterial exterior surface. The project focused on the interaction of the outer microbial membrane, which is dominated by an exterior lipopolysaccharide (LPS) portion, of Pseudomonas aeruginosa with the mineral goethite and with solvated ions in the environment. This was originally a collaborative project with T.P. Straatsma and B. Lowery of the Pacific Northwest National Laboratory. The University of Alabama effort used electronic structure calculations to predict the molecular behavior of ions in solution and the behavior of the sugars which form a critical part of the LPS. The interactions of the sugars with metal ions are expected to dominate much of the microscopic structure and transport phenomena in the LPS. This work, in combination with the molecular dynamics simulations of Straatsma and the experimental electrochemistry and microscopy measurements of Lowry, both at PNNL, is providing new insights into the detailed molecular behavior of these membranes in geochemical environments. The effort at The University of Alabama has three components: solvation energies and structures of ions in solution, prediction of the acidity of the critical groups in the sugars in the LPS, and binding of metal ions to the sugar anions. An important aspect of the structure of the LPS membrane as well as ion transport in the LPS is the ability of the sugar side groups such as the carboxylic acids and the phosphates to bind positively charged ions. We are studying the acidity of the acidic side groups in order to better understand the ability of these groups to bind metal ions. We need to understand the solvation properties of the metal ions in solution and their ability to bind not only to the sugars but to proteins and to other anions. Our goal is then to be able to predict the ability of the side groups to bind metal ions. One result from the earlier molecular dynamics simulations is the exclusion of water from the inner hydrophobic part of the membrane. We thus need to investigate the binding of the cations in media with different dielectric constants.

  7. GEOCHEMICAL INVESTIGATIONS OF CO₂-BRINE-ROCK INTERACTIONS OF THE KNOX GROUP IN THE ILLINOIS BASIN

    SciTech Connect (OSTI)

    Yoksoulian, Lois; Berger, Peter; Freiburg, Jared; Butler, Shane; Leetaru, Hannes

    2014-09-30

    Increased output of greenhouse gases, particularly carbon dioxide (CO₂), into the atmosphere from anthropogenic sources is of great concern. A potential technology to reduce CO₂ emissions is geologic carbon sequestration. This technology is currently being evaluated in the United States and throughout the world. The geology of the Illinois Basin exhibits outstanding potential as a carbon sequestration target, as demonstrated by the ongoing Illinois Basin – Decatur Project that is using the Mt. Simon Sandstone reservoir and Eau Claire Shale seal system to store and contain 1 million tonnes of CO₂. The Knox Group-Maquoketa Shale reservoir and seal system, located stratigraphically above the Mt. Simon Sandstone-Eau Claire Shale reservoir and seal system, has little economic value as a resource for fossil fuels or as a potable water source, making it ideal as a potential carbon sequestration target. In order for a reservoir-seal system to be effective, it must be able to contain the injected CO₂ without the potential for the release of harmful contaminants liberated by the reaction between CO₂-formation fluids and reservoir and seal rocks. This study examines portions of the Knox Group (Potosi Dolomite, Gunter Sandstone, New Richmond Sandstone) and St. Peter Sandstone, and Maquoketa Shale from various locations around the Illinois Basin. A total of 14 rock and fluid samples were exposed to simulated sequestration conditions (9101–9860 kPa [1320–1430 psi] and 32°–42°C [90°– 108°F]) for varying amounts of time (6 hours to 4 months). Knox Group reservoir rocks exhibited dissolution of dolomite in the presence of CO₂ as indicated by petrographic examination, X-ray diffraction analysis, and fluid chemistry analysis. These reactions equilibrated rapidly, and geochemical modeling confirmed that these reactions reached equilibrium within the time frames of the experiments. Pre-reaction sample mineralogy and postreaction fluid geochemistry from this study suggests only limited potential for the release of United States Environmental Protection Agency regulated inorganic contaminants into potable water sources. Short-term core flood experiments further verify that the carbonate reactions occurring in Knox Group reservoir samples reach equilibrium rapidly. The core flood experiments also lend insight to pressure changes that may occur during CO₂ injection. The Maquoketa Shale experiments reveal that this rock is initially chemically reactive when in contact with CO₂ and brine. However, due to the conservative nature of silicate and clay reaction kinetics and the rapid equilibration of carbonate reactions that occur in the shale, these reactions would not present a significant risk to the competency of the shale as an effective seal rock.

  8. Effect of curing conditions on the geotechnical and geochemical properties of CFBC ashes

    SciTech Connect (OSTI)

    Bland, A.E.

    1999-07-01

    Western Research Institute, in cooperation with the US Department of Energy Federal Energy Technology Center, initiated a multi-year program to examine the relationship between CFBC ash chemistry and geotechnical properties as they relate to ash disposal and utilization. Four CFBC facilities supplied ash from their units for the study representing high-sulfur (4%) and medium-sulfur (1.8%) bituminous coal. Sub-bituminous coal (0.9% sulfur) and petroleum coke (5--6% sulfur) fired ashes were also included in the study. The ashes were composed principally of large quantities of anhydrite (CaSO{sub 4}) and lime (CaO) and minor amounts of calcite (CaCO{sub 3}). The ash curing study addressed the impact of curing conditions (sealed and saturated curing and 23 C and 5 C curing temperature) on the geochemical and geotechnical properties of the ash. The strength development and expansion varied with the type and characteristics of the ashes. The expansion appeared to be inversely related to strength development. As the strength decreased under saturated curing, the expansion increased significantly. The application of 5 C saturated curing resulted in further strength loss and increased expansion. The hydration reaction products appeared to be principally the hydration of lime (CaO) to portlandite (Ca[OH]{sub 2}), the hydration of anhydrite (CaSO{sub 4}) to gypsum (CaSO{sub 4} {center{underscore}dot} 2H{sub 2}O), and the precipitation of ettringite (Ca{sub 6}Al{sub 2}[SO{sub 4}]{sub 3}[OH]{sub 12} {center{underscore}dot} 26H{sub 2}O) from the soluble calcium, sulfates and alumina. No thaumasite was noted in the specimens. The ashes appeared to follow one of several hydration reaction trends: (1) ettringite-only development, (2) ettringite and/or gypsum early followed by later gypsum formation, or (3) gypsum-only formation. Testing confirmed that the hydration reaction chemistry was related to geotechnical properties of the ashes. Strength development and expansion appeared to be related to ettringite and/or gypsum formation. The expansion increased with saturated curing and appeared to be predominantly gypsum based. A pore filling model was found to be consistent with the observed relationships between hydration phases (ettringite and gypsum) and strength development and expansion, as well as SEM observations and void reduction observations.

  9. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to an Unconfined Oxidizing Carbonate Aquifer

    SciTech Connect (OSTI)

    Wang, Guohui; Qafoku, Nikolla; Lawter, Amanda R.; Bowden, Mark E.; Harvey, Omar; Sullivan, E. C.; Brown, Christopher F.

    2015-07-15

    A series of batch and column experiments combined with solid phase characterization studies (i.e., quantitative x-ray diffraction and wet chemical extractions) were conducted to address a variety of scientific issues and evaluate the impacts of the potential leakage of carbon dioxide (CO2) from deep subsurface storage reservoirs. The main objective was to gain an understanding of how CO2 gas influences: 1) the aqueous phase pH; and 2) mobilization of major, minor, and trace elements from minerals present in an aquifer overlying potential CO2 sequestration subsurface repositories. Rocks and slightly weathered rocks representative of an unconfined, oxidizing carbonate aquifer within the continental US, i.e., the Edwards aquifer in Texas, were used in these studies. These materials were exposed to a CO2 gas stream or were leached with a CO2-saturated influent solution to simulate different CO2 gas leakage scenarios, and changes in aqueous phase pH and chemical composition were measured in the liquid samples collected at pre-determined experimental times (batch experiments) or continuously (column experiments). The results from the strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the Edward aquifer samples contain As, Cd, Pb, Cu, and occasionally Zn, which may potentially be mobilized from the solid to the aqueous phase during or after exposure to CO2. The results from the batch and column experiments confirmed the release of major chemical elements into the contacting aqueous phase (such as Ca, Mg, Ba, Sr, Si, Na, and K); the mobilization and possible rapid immobilization of minor elements (such as Fe, Al, and Mn), which are able to form highly reactive secondary phases; and sporadic mobilization of only low concentrations of trace elements (such as As, Cd, Pb, Cu, Zn, Mo, etc.). The results from this experimental research effort will help in developing a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption) in the aquifer sediments and will support site selection, risk assessment, policy-making, and public education efforts associated with geologic carbon sequestration.

  10. Permeability, geochemical, and water quality tests in support of an aquifer thermal energy storage site in Minnesota

    SciTech Connect (OSTI)

    Blair, S.C.; Deutsch, W.J.; Mitchell, P.J.

    1985-04-01

    This report describes the Underground Energy Storage Program's efforts to characterize physicochemical processes at DOE's ATES Field Test Facility (FTF) located on the University of Minnesota campus at St. Paul, Minnesota. Experimental efforts include: field tests at the St. Paul FTF to characterize fluid injectability and to evaluate the effectiveness of fluid-conditioning equipment, geochemical studies to investigate chemical reactions resulting from alterations to the aquifer's thermal regime, and laboratory tests on sandstone core from the site. Each experimental area is discussed and results obtained thus far are reported. 23 refs., 39 figs., 12 tabs.

  11. GIS Regional Spatial Data from the Great Basin Center for Geothermal Energy: Geochemical, Geodesic, Geologic, Geophysical, Geothermal, and Groundwater Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Great Basin Center for Geothermal Energy, part of the University of Nevada, Reno, conducts research towards the establishment of geothermal energy as an economically viable energy source within the Great Basin. The Center specializes in collecting and synthesizing geologic, geochemical, geodetic, geophysical, and tectonic data, and using Geographic Information System (GIS) technology to view and analyze this data and to produce favorability maps of geothermal potential. The center also makes its collections of spatial data available for direct download to the public. Data are in Lambert Conformable Conic Projection.

  12. A system for interpretation of blast furnace stockrod measurements

    SciTech Connect (OSTI)

    Hinnelae, J.; Saxen, H.

    1997-12-31

    A system for intelligent monitoring and interpretation of signals from blast furnace stockrods is presented. The system visualizes the measurements and estimates the local burden layer thickness (under the rods) after every dump. Furthermore, it analyzes the burden descent rate to distinguish between slips, hangings, normal descent and peaks, etc., and also combines the stockrod information with findings of temperature measurements from an above-burden probe. The preprocessing of the signals and some features of the system, which is under development, are treated in this paper.

  13. GaMin’11 – an international inter-laboratory comparison for geochemical CO₂ - saline fluid - mineral interaction experiments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ostertag-Henning, C.; Risse, A.; Thomas, B.; Rosenbauer, R.; Rochelle, C.; Purser, G.; Kilpatrick, A.; Rosenqvist, J.; Yardley, B.; Karamalidis, A.; et al

    2014-12-31

    Due to the strong interest in geochemical CO₂-fluid-rock interaction in the context of geological storage of CO₂ a growing number of research groups have used a variety of different experimental ways to identify important geochemical dissolution or precipitation reactions and – if possible – quantify the rates and extent of mineral or rock alteration. In this inter-laboratory comparison the gas-fluid-mineral reactions of three samples of rock-forming minerals have been investigated by 11 experimental labs. The reported results point to robust identification of the major processes in the experiments by most groups. The dissolution rates derived from the changes in compositionmore » of the aqueous phase are consistent overall, but the variation could be reduced by using similar corrections for changing parameters in the reaction cells over time. The comparison of experimental setups and procedures as well as of data corrections identified potential improvements for future gas-fluid-rock studies.« less

  14. Application of geochemical techniques to deduce the reservoir performance of the Palinpinon Geothermal Field, Philippines - an update

    SciTech Connect (OSTI)

    Ramos-Candelaria, M.N.; Garcia, S.E.; Hermoso, D.Z.

    1997-12-31

    Regular monitoring of various geochemical parameters in the water and vapor phases of the production wells at the Palinpinon I and II sectors of the Southern Negros Geothermal Field have been useful in the identification of the dominant reservoir processes occurring related to the present exploitation strategy. Observed geochemical and physical changes in the output of production wells have dictated production and injection strategies adopted to maximize production to meet the steam requirements of the power plant. Correlation of both physical and chemical data have identified the following reservoir processes: (1) Injection breakthrough via the Ticala Fault of the highly mineralized (Cl {approximately}8,000-10,500 mg/kg), isotopically enriched ({delta}{sup 18}O = -3.00{per_thousand}, {delta}{sup 2} H = -39{per_thousand}), and gas depleted brine for wells in the SW and central Puhagan. Injection breakthrough is also occurring in Palinpinon II and has resulted in temperature drops of 5-10{degrees}C.2. Pressure drawdown enhanced boiling in the liquid reservoir with steam separation of 220-240{degrees}C, feeding wells tapping the natural steam zone. However, enhanced drawdown has induced the entry of shallow acid steam condensate fluids in some wells (e.g. OK-7, PN-29D, PN-18D), which if not arrested could reduce production.

  15. INEEL Subregional Conceptual Model Report Volume 2: Summary of Existing Knowledge of Geochemical Influences on the Fate and Transport of Contaminants in the Subsurface at the INEEL

    SciTech Connect (OSTI)

    Paul L. Wichlacz; Robert C. Starr; Brennon Orr

    2003-09-01

    This document summarizes previous descriptions of geochemical system conceptual models for the vadose zone and groundwater zone (aquifer) beneath the Idaho National Engineering and Environmental Laboratory (INEEL). The primary focus is on groundwater because contaminants derived from wastes disposed at INEEL are present in groundwater, groundwater provides a pathway for potential migration to receptors, and because geochemical characteristics in and processes in the aquifer can substantially affect the movement, attenuation, and toxicity of contaminants. The secondary emphasis is perched water bodies in the vadose zone. Perched water eventually reaches the regional groundwater system, and thus processes that affect contaminants in the perched water bodies are important relative to the migration of contaminants into groundwater. Similarly, processes that affect solutes during transport from nearsurface disposal facilities downward through the vadose zone to the aquifer are relevant. Sediments in the vadose zone can affect both water and solute transport by restricting the downward migration of water sufficiently that a perched water body forms, and by retarding solute migration via ion exchange. Geochemical conceptual models have been prepared by a variety of researchers for different purposes. They have been published in documents prepared by INEEL contractors, the United States Geological Survey (USGS), academic researchers, and others. The documents themselves are INEEL and USGS reports, and articles in technical journals. The documents reviewed were selected from citation lists generated by searching the INEEL Technical Library, the INEEL Environmental Restoration Optical Imaging System, and the ISI Web of Science databases. The citation lists were generated using the keywords ground water, groundwater, chemistry, geochemistry, contaminant, INEL, INEEL, and Idaho. In addition, a list of USGS documents that pertain to the INEEL was obtained and manually searched. The documents that appeared to be the most pertinent were selected from further review. These documents are tabulated in the citation list. This report summarizes existing geochemical conceptual models, but does not attempt to generate a new conceptual model or select the ''right'' model. This document is organized as follows. Geochemical models are described in general in Section 2. Geochemical processes that control the transport and fate of contaminants introduced into groundwater are described in Section 3. The natural geochemistry of the Eastern Snake River Plain Aquifer (SRPA) is described in Section 4. The effect of waste disposal on the INEEL subsurface is described in Section 5. The geochemical behavior of the major contaminants is described in Section 6. Section 7 describes the site-specific geochemical models developed for various INEEL facilities.

  16. Interpretation of Synthetic Aperture Radar measurements of ocean currents

    SciTech Connect (OSTI)

    Rufenach, C.L.; Shuchman, R.A.; Lyzenga, D.R.

    1983-02-28

    Synthetic Aperture Radar (SAR) experiments hae been performed over the last few years to measure ocean currents inferred from shifts in the Doppler spectral peak. Interpretations of aircraft SAR measurements, when compared with limited surface values, tend to underestimate the currents by about 25%. A theory is developed that modifies the classical Doppler expression showing that the radar measurements are dependent on the radar processor (system) bandwidth and the received signal bandwidth. Measured bandwidths give a correction that increases the inferred current values by about 25%, bringing the measurements into good agreement. This new correction lends credence to the theory and increases the potential for application of SAR systems to future ocean current measurements. SAR measurements should include the determination of processor and signal bandwidths such that this correction can be applied.

  17. INTERPRETIVE GUIDANCE ON THE REQUIREMENTS OF 10 C.F.R. § 205...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    INTERPRETIVE GUIDANCE ON THE REQUIREMENTS OF 10 C.F.R. 205.322 INTERPRETIVE GUIDANCE ON THE REQUIREMENTS OF 10 C.F.R. 205.322 This guidance is intended to clarify the ...

  18. Analysis and Interpretation of Hard X-ray Emission fromthe Bullet...

    Office of Scientific and Technical Information (OSTI)

    Analysis and Interpretation of Hard X-ray Emission fromthe Bullet Cluster (1E0657-56), the ... Citation Details In-Document Search Title: Analysis and Interpretation of Hard X-ray ...

  19. Actualistic and Geochemical Modeling of Reservoir Rock, CO2 and Formation Fluid Interaction, Citronelle Oil Field, Alabama

    SciTech Connect (OSTI)

    Weislogel, Amy

    2014-01-31

    This report includes description of the Citronelle field study area and the work carried out in the project to characterize the geology and composition of reservoir rock material and to collect an analyze the geochemical composition of produced fluid waters from the Citronelle field. Reservoir rock samples collected from well bore core were made into thin-sections and assessed for textural properties, including pore types and porosity distribution. Compositional framework grain modal data were collected via point-counting, and grain and cement mineralogy was assessed using SEM-EDS. Geochemistry of fluid samples is described and modeled using PHREEQC. Composition of rock and produced fluids were used as inputs for TOUGHREACT reactive transport modeling, which determined the rock-fluid system was in disequilibrium.

  20. Geothermal prospecting by geochemical methods on natural gas and water discharges in the Vulsini Mts Volcanic District (Central Italy)

    SciTech Connect (OSTI)

    Duchi, V.; Minissale, A.A.; Ortino, S.; Romani, L.

    1987-01-01

    The Latera and Torre Alfina geothermal fields were discovered in the Vulsini Mts district (central Italy) in the 70s. The fluid produced by the two geothermal systems is a high rhoCO/sub 2/(around 7 MPa) sodium chloride solution (T.D.S. is 9200 ppm at Latera and 7800 at Torre Alfina), with high SiO/sub 2/ and H/sub 3/BO/sub 3/ contents. The fluid temperature taken at well bottom is about 155/sup 0/C at Torre Alfina, whereas at Latera it ranges from 200 to over 350/sup 0/C. In spite of these temperatures, recorded in producing wells, previous geochemical prospectings using geothermometers in natural thermal manifestations had predicted temperatures no higher than 140/sup 0/C in all the Vulsini district. This contrasting feature between real temperatures and those evaluated during prospecting is caused by the fast circulation of large amounts of meteoric waters in the aquifer located in the shallow parts of the carbonate reservoir formations, and by the short interaction between the latter and the deep geothermal fluids. In the present study a new geochemical survey on thermal and cold springs, stream samples, as well as natural gas emissions has been carried out. A critical review of the main geothermometers, some considerations about the hydraulic behavior of the reservoir formations, and the cross comparison between NH/sub 4//sup +//B ratio, rhoCO/sub 2/ and SiO/sub 2/ content in both cold and thermal waters, have led to the conclusion that in the Vulsini Mts there are no shallow anomalous areas apart from those already discovered at Latera and Torre Alfina. The present method could be successfully applied in other geothermal systems, where the potential reservoir is represented by carbonate formations.

  1. Interpretation of AMS-02 electrons and positrons data

    SciTech Connect (OSTI)

    Mauro, M. Di; Donato, F.; Fornengo, N.; Vittino, A.; Lineros, R. E-mail: donato@to.infn.it E-mail: rlineros@ific.uv.es

    2014-04-01

    We perform a combined analysis of the recent AMS-02 data on electrons, positrons, electrons plus positrons and positron fraction, in a self-consistent framework where we realize a theoretical modeling of all the astrophysical components that can contribute to the observed fluxes in the whole energy range. The primary electron contribution is modeled through the sum of an average flux from distant sources and the fluxes from the local supernova remnants in the Green catalog. The secondary electron and positron fluxes originate from interactions on the interstellar medium of primary cosmic rays, for which we derive a novel determination by using AMS-02 proton and helium data. Primary positrons and electrons from pulsar wind nebulae in the ATNF catalog are included and studied in terms of their most significant (while loosely known) properties and under different assumptions (average contribution from the whole catalog, single dominant pulsar, a few dominant pulsars). We obtain a remarkable agreement between our various modeling and the AMS-02 data for all types of analysis, demonstrating that the whole AMS-02 leptonic data admit a self-consistent interpretation in terms of astrophysical contributions.

  2. Gene set analyses for interpreting microarray experiments on prokaryotic organisms.

    SciTech Connect (OSTI)

    Tintle, Nathan; Best, Aaron; Dejongh, Matthew; VanBruggen, Dirk; Heffron, Fred; Porwollik, Steffen; Taylor, Ronald C.

    2008-11-05

    Background: Recent advances in microarray technology have brought with them the need for enhanced methods of biologically interpreting gene expression data. Recently, methods like Gene Set Enrichment Analysis (GSEA) and variants of Fisher’s exact test have been proposed which utilize a priori biological information. Typically, these methods are demonstrated with a priori biological information from the Gene Ontology. Results: Alternative gene set definitions are presented based on gene sets inferred from the SEED: open-source software environment for comparative genome annotation and analysis of microbial organisms. Many of these gene sets are then shown to provide consistent expression across a series of experiments involving Salmonella Typhimurium. Implementation of the gene sets in an analysis of microarray data is then presented for the Salmonella Typhimurium data. Conclusions: SEED inferred gene sets can be naturally defined based on subsystems in the SEED. The consistent expression values of these SEED inferred gene sets suggest their utility for statistical analyses of gene expression data based on a priori biological information

  3. Categorical Exclusion Determinations: Washington, D.C. | Department...

    Energy Savers [EERE]

    March 16, 2015 CX-013472: Categorical Exclusion Determination Geochemical Evaluation of Double Layered BSR's on the Hikurangi Margin, New Zealand CX(s) Applied: A9, B3.1, B3.6 ...

  4. CX-012479: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Assessing the Geochemical Response of CO2 Disposal in Flood Basalt Reservoirs CX(s) Applied: B3.6Date: 41862 Location(s): IllinoisOffices(s): National Energy Technology Laboratory

  5. CX-012481: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Assessing the Geochemical Response of CO2 Disposal in Flood Basalt Reservoirs CX(s) Applied: B3.1, B3.6Date: 41862 Location(s): CaliforniaOffices(s): National Energy Technology Laboratory

  6. Interpretation of simulated global warming using a simple model

    SciTech Connect (OSTI)

    Watterson, I.G.

    2000-01-01

    A simple energy balance model with two parameters, an effective heat capacity and an effective climate sensitivity, is used to interpret six GCM simulations of greenhouse gas-induced global warming. By allowing the parameters to vary in time, the model can be accurately calibrated for each run. It is found that the sensitivity can be approximated as a constant in each case. However, the effective heat capacity clearly varies, and it is important that the energy equation is formulated appropriately, and thus unlike many such models. For simulations with linear forcing and from a cold start, the capacity is in each case close to that of a homogeneous ocean with depth initially 200 m, but increasing some 4.3 m each year, irrespective of the sensitivity and forcing growth rate. Analytic solutions for t his linear capacity function are derived, and these reproduce the GCM runs well, even for cases where the forcing is stabilized after a century or so. The formation of a subsurface maximum in the mean ocean temperature anomaly is a significant feature of such cases. A simple model for a GCM run with a realistic forcing scenario starting from 1,880 is constructed using component results for forcing segments. Given this, an estimate of the cold start error of a simulation of the warming due to forcing after the present would be given by the negative of the temperature drift of the anomaly due to the past forcing. The simple model can evidently be used to give an indication of likely warming curves, at lest for this range of scenarios and GCM sensitivities.

  7. Models to interpret bedform geometries from cross-bed data

    SciTech Connect (OSTI)

    Luthi, S.M. (Schlumberger-Doll Research, Ridgefield, CT (USA)); Banavar, J.R. (Pennsylvania State Univ., University Park (USA)); Bayer, U. (Kernforschungsanlage Juelich (West Germany))

    1990-03-01

    Semi-elliptical and sinusoidal bedform crestlines were modeled with curvature and sinuosity as parameters. Both bedform crestlines are propagated at various angles of migration over a finite area of deposition. Two computational approaches are used, a statistical random sampling (Monte Carlo) technique over the area of the deposit, and an analytical method based on topology and differential geometry. The resulting foreset azimuth distributions provide a catalogue for a variety of situations. The resulting thickness distributions have a simple shape and can be combined with the azimuth distributions to constrain further the cross-strata geometry. Paleocurrent directions obtained by these models can differ substantially from other methods, especially for obliquely migrating low-curvature bedforms. Interpretation of foreset azimuth data from outcrops and wells can be done either by visual comparison with the catalogued distributions, or by iterative computational fits. Studied examples include eolian cross-strata from the Permian Rotliegendes in the North Sea, fluvial dunes from the Devonian in the Catskills (New York State), the Triassic Schilfsandstein (West Germany) and the Paleozoic-Jurassic of the Western Desert (Egypt), as well as recent tidal dunes from the German coast of the North Sea and tidal cross-strata from the Devonian Koblentquartzit (West Germany). In all cases the semi-elliptical bedform model gave a good fit to the data, suggesting that it may be applicable over a wide range of bedforms. The data from the Western Desert could only be explained by data scatter due to channel sinuosity combining with the scatter attributed to the ellipticity of the bedform crestlines. These models, therefore, may also allow simulations of some hierarchically structured bedforms.

  8. Mercury Geochemical, Groundwater Geochemical, And Radiometric...

    Open Energy Info (EERE)

    at right angles to known and suspected faults. Scintillometer readings (gamma radiation - total counts second) were also recorded at each soil sample station. At the...

  9. Solid phase evolution in the Biosphere 2 hillslope experiment as predicted by modeling of hydrologic and geochemical fluxes

    SciTech Connect (OSTI)

    Dontsova, K.; Steefel, C.I.; Desilets, S.; Thompson, A.; Chorover, J.

    2009-07-15

    A reactive transport geochemical modeling study was conducted to help predict the mineral transformations occurring over a ten year time-scale that are expected to impact soil hydraulic properties in the Biosphere 2 (B2) synthetic hillslope experiment. The modeling sought to predict the rate and extent of weathering of a granular basalt (selected for hillslope construction) as a function of climatic drivers, and to assess the feedback effects of such weathering processes on the hydraulic properties of the hillslope. Flow vectors were imported from HYDRUS into a reactive transport code, CrunchFlow2007, which was then used to model mineral weathering coupled to reactive solute transport. Associated particle size evolution was translated into changes in saturated hydraulic conductivity using Rosetta software. We found that flow characteristics, including velocity and saturation, strongly influenced the predicted extent of incongruent mineral weathering and neo-phase precipitation on the hillslope. Results were also highly sensitive to specific surface areas of the soil media, consistent with surface reaction controls on dissolution. Effects of fluid flow on weathering resulted in significant differences in the prediction of soil particle size distributions, which should feedback to alter hillslope hydraulic conductivities.

  10. Geochemical information for sites contaminated with low-level radioactive wastes: II. St. Louis Airport Storage Site

    SciTech Connect (OSTI)

    Seeley, F.G.; Kelmers, A.D.

    1985-01-01

    The St. Louis Airport Storage Site (SLASS) became radioactively contaminated as a result of wastes that were being stored from operations to recover uranium from pitchblende ores in the 1940s and 1950s. The US Department of Energy is considering various remedial action options for the SLASS under the Formerly Utilized Site Remedial Action Program (FUSRAP). This report describes the results of geochemical investigations, carried out to support the FUSRAP activities and to aid in quantifying various remedial action options. Soil and groundwater samples from the site were characterized, and sorption ratios for uranium and radium and apparent concentration limit values for uranium were measured in soil/groundwater systems by batch contact methodology. The uranium and radium concentrations in soil samples were significantly above background near the old contaminated surface horizon (now at the 0.3/sup -/ to 0.9/sup -/m depth); the maximum values were 1566 ..mu..g/g and 101 pCi/g, respectively. Below about the 6/sup -/m depth, the concentrations appeared to be typical of those naturally present in soils of this area (3.8 +- 1.2 ..mu..g/g and 3.1 +- 0.6 pCi/g). Uranium sorption ratios showed stratigraphic trends but were generally moderate to high (100 to 1000 L/kg). The sorption isotherm suggested an apparent uranium concentration limit of about 200 mg/L. This relatively high solubility can probably be correlated with the carbonate content of the soil/groundwater systems. The lower sorption ratio values obtained from the sorption isotherm may have resulted from changes in the experimental procedure or the groundwater used. The SLASS appears to exhibit generally favorable behavior for the retardation of uranium solubilized from waste in the site. Parametric tests were conducted to estimate the sensitivity of uranium sorption and solubility to the pH and carbonate content of the system.

  11. CORE-BASED INTEGRATED SEDIMENTOLOGIC, STRATIGRAPHIC, AND GEOCHEMICAL ANALYSIS OF THE OIL SHALE BEARING GREEN RIVER FORMATION, UINTA BASIN, UTAH

    SciTech Connect (OSTI)

    Lauren P. Birgenheier; Michael D. Vanden Berg,

    2011-04-11

    An integrated detailed sedimentologic, stratigraphic, and geochemical study of Utah's Green River Formation has found that Lake Uinta evolved in three phases (1) a freshwater rising lake phase below the Mahogany zone, (2) an anoxic deep lake phase above the base of the Mahogany zone and (3) a hypersaline lake phase within the middle and upper R-8. This long term lake evolution was driven by tectonic basin development and the balance of sediment and water fill with the neighboring basins, as postulated by models developed from the Greater Green River Basin by Carroll and Bohacs (1999). Early Eocene abrupt global-warming events may have had significant control on deposition through the amount of sediment production and deposition rates, such that lean zones below the Mahogany zone record hyperthermal events and rich zones record periods between hyperthermals. This type of climatic control on short-term and long-term lake evolution and deposition has been previously overlooked. This geologic history contains key points relevant to oil shale development and engineering design including: (1) Stratigraphic changes in oil shale quality and composition are systematic and can be related to spatial and temporal changes in the depositional environment and basin dynamics. (2) The inorganic mineral matrix of oil shale units changes significantly from clay mineral/dolomite dominated to calcite above the base of the Mahogany zone. This variation may result in significant differences in pyrolysis products and geomechanical properties relevant to development and should be incorporated into engineering experiments. (3) This study includes a region in the Uinta Basin that would be highly prospective for application of in-situ production techniques. Stratigraphic targets for in-situ recovery techniques should extend above and below the Mahogany zone and include the upper R-6 and lower R-8.

  12. Isotopic and geochemical tracers for U(VI) reduction and U mobility at an in situ recovery U mine

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Basu, Anirban; Brown, Shaun T.; Christensen, John N.; DePaolo, Donald J.; Reimus, Paul W.; Heikoop, Jeffrey M.; Woldegabriel, Giday; Simmons, Ardyth M.; House, Brian M.; Hartmann, Matt; et al

    2015-05-19

    In situ recovery (ISR) uranium (U) mining mobilizes U in its oxidized hexavalent form (U(VI)) by oxidative dissolution of U from the roll-front U deposits. Post-mining natural attenuation of residual U(VI) at ISR mines is a potential remediation strategy. Detection and monitoring of naturally occurring reducing subsurface environments are important for successful implementation of this remediation scheme. We used the isotopic tracers ²³⁸U/²³⁵U (δ²³⁸U), ²³⁴U/²³⁸U activity ratio, and ³⁴S/³²S (δ³⁴S), and geochemical measurements of U ore and groundwater collected from 32 wells located within, upgradient, and downgradient of a roll-front U deposit to detect U(VI) reduction and U mobility atmore » an ISR mining site at Rosita, TX, USA. The δ²³⁸U in Rosita groundwater varies from 0.61‰ to -2.49‰, with a trend toward lower δ²³⁸U in downgradient wells. The concurrent decrease in U(VI) concentration and δ²³⁸U with an ε of 0.48‰ ± 0.08‰ is indicative of naturally occurring reducing environments conducive to U(VI) reduction. Additionally, characteristic ²³⁴U/²³⁸U activity ratio and δ³⁴S values may also be used to trace the mobility of the ore zone groundwater after mining has ended. These results support the use of U isotope-based detection of natural attenuation of U(VI) at Rosita and other similar ISR mining sites.« less

  13. Analysis and Interpretation of Hard X-ray Emission fromthe Bullet...

    Office of Scientific and Technical Information (OSTI)

    Analysis and Interpretation of Hard X-ray Emission fromthe Bullet Cluster (1E0657-56), the Most Distant Cluster of Galaxies Observed by the RXTE Citation Details In-Document Search ...

  14. Erratum: "Sensitivity of the interpretation of the experimental ion

    Office of Scientific and Technical Information (OSTI)

    thermal diffusivity to the determination of the ion conductive heat flux" [Phys. Plasmas 21, 042508 (2014)] (Journal Article) | SciTech Connect Erratum: "Sensitivity of the interpretation of the experimental ion thermal diffusivity to the determination of the ion conductive heat flux" [Phys. Plasmas 21, 042508 (2014)] Citation Details In-Document Search Title: Erratum: "Sensitivity of the interpretation of the experimental ion thermal diffusivity to the determination of

  15. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    SciTech Connect (OSTI)

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation “C”. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthite component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation “C” sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.

  16. Geochemical engineering reference manual

    SciTech Connect (OSTI)

    Owen, L.B.; Michels, D.E.

    1984-01-01

    The following topics are included in this manual: physical and chemical properties of geothermal brine and steam, scale and solids control, processing spent brine for reinjection, control of noncondensable gas emissions, and goethermal mineral recovery. (MHR)

  17. Geochemical indicators of depositional environment and soruce-rock potential for the Upper Ordovician Maquoketa Group, Illinois basin

    SciTech Connect (OSTI)

    Guthrie, J.M.; Pratt, L.M. )

    1994-05-01

    Two depositional cycles are recognized within the Upper Ordovician Maquoketa Group of the Illinois basin in a core from the New Jersey Zinc 1 Parrish well of Fulton County, Illinois. Organic carbon (C[sub org]), total sulfur, [sup 13]C content of the organic carbon ([delta][sup 13]C[sub org]), hydrogen and oxygen indices (HI and OI) from Rock-Eval pyrolysis and yields of extractable organic matter (EOM) vary through the cycles. Dark-brown to black, laminated shales are present in the lower portion of each cycle and have high values of C[sub org] (1.0-3.0%), HI (500-1000 mg hydrocarbon [HC]/g total organic carbon[TOC]), and EOM (500-2500 ppm), and more negative [delta][sup 13]C[sub org] values ([delta][sup 13]C[sub org] = -30 to -30.5%). Gray to greenish-gray, bioturbated shales are present in the upper portion of each cycle and have low values of C[sub org] (<1.0%), HI (<500 mg HC/g TOC), and EOM (<500 ppm), and more positive [delta][sup 13]C[sub org] values (-28.5 to 29.5%) compared to the laminated shales. Although thermally immature or marginally mature in this core, the laminated shales represent potential source rock s for petroleum because they contain good to excellent quantities of oil-prone organic matter and are more deeply buried in other areas of the basin. Kerogen elemental data and Rock-Eval data suggest that the source of organic matter in the Maquoketa was uniform, with the notable exception of graptolite-rich layers. Distributions of saturated hydrocarbons for Maquoketa samples resemble those derived from amorphous organic matter. Variations in bulk geochemical data and carbon isotopic compositions within the Maquoketa Group indicate substantial reworking and degradation of organic matter associated with bioturbation and oxygenated depositional conditions. 64 refs., 10 figs., 1 tab.

  18. Geochemical Processes Data Package for the Vadose Zone in the Single-Shell Tank Waste Management Areas at the Hanford Site

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Zachara, John M.; Dresel, P. Evan; Krupka, Kenneth M.; Serne, R. Jeffrey

    2007-09-28

    This data package discusses the geochemistry of vadose zone sediments beneath the single-shell tank farms at the U.S. Department of Energy’s (DOE’s) Hanford Site. The purpose of the report is to provide a review of the most recent and relevant geochemical process information available for the vadose zone beneath the single-shell tank farms and the Integrated Disposal Facility. Two companion reports to this one were recently published which discuss the geology of the farms (Reidel and Chamness 2007) and groundwater flow and contamination beneath the farms (Horton 2007).

  19. Effect of non-diffusive processes on transport and its interpretation in the tokamak plasma edge

    SciTech Connect (OSTI)

    Stacey, Weston M.

    2013-11-15

    An interpretive methodology improved to account for two non-diffusive transport mechanisms—particle pinch and ion orbit loss—was applied to interpret the difference in transport (i) between a discharge with Resonance Magnetic Perturbations and a High confinement mode discharge with otherwise identical operating parameters and (ii) between the Low confinement and High confinement phases of a discharge free of Edge Localized Modes. Differences in particle and energy diffusion coefficients and in the particle pinch were inferred from the experimental data, and the inferred experiment thermal diffusion coefficients were compared with various theoretical predictions. The effect of taking ion orbit loss into account in the interpretation was quantified, and the possible relation of ion orbit loss to the observed transport “edge shortfall” is discussed.

  20. Analysis and Interpretation of Hard X-ray Emission fromthe Bullet Cluster

    Office of Scientific and Technical Information (OSTI)

    (1E0657-56), the Most Distant Cluster of Galaxies Observed by the RXTE (Journal Article) | SciTech Connect Analysis and Interpretation of Hard X-ray Emission fromthe Bullet Cluster (1E0657-56), the Most Distant Cluster of Galaxies Observed by the RXTE Citation Details In-Document Search Title: Analysis and Interpretation of Hard X-ray Emission fromthe Bullet Cluster (1E0657-56), the Most Distant Cluster of Galaxies Observed by the RXTE Evidence for non-thermal activity in clusters of

  1. DEPARTMENT OF ENERGY OFFICE OF GENERAL COUNSEL INTERPRETATION REGARDING EXEMPTION RELIEF PURSUANT TO

    Energy Savers [EERE]

    INTERPRETATION REGARDING EXEMPTION RELIEF PURSUANT TO 10 C.F.R. PART 820, PROCEDURAL RULES FOR DOE NUCLEAR ACTIVITIES, SUBPART E, EXEMPTION RELIEF, AND NON-COMPLIANT "DOCUMENTED SAFETY ANALYSES" SUBJECT TO 10 C.F.R. PART 830, NUCLEAR SAFETY MANAGEMENT, SUBPART B, SAFETY BASIS REQUIREMENTS Subpart D to 10 C.F.R Part 820 provides that the Department of Energy's (DOE) General Counsel (GC) shall be responsible for interpreting the DOE Nuclear Safety Requirements. Pursuant to that

  2. Spatial resolution and the geologic interpretation of Martian morphology - implications for subsurface volatiles

    SciTech Connect (OSTI)

    Zimbelman, J.R.

    1987-08-01

    Viking Orbiter images of the Acheron Fossae on Mars are presented and analyzed, with an emphasis on the impact of image resolution on the interpretation. High-resolution (less than 10 m/pixel) images reveal small mounds which can be interpreted as aeolian dunes, but these features are not evident on images with resolution of 50 m/pixel or greater. Also reported are the results of a visual inspection of 527 usable high-resolution images: it is found that all of the morphological features identified can arise in the absence of subsurface volatiles. 21 references.

  3. Evapotranspiration And Geochemical Controls On Groundwater Plumes At Arid Sites: Toward Innovative Alternate End-States For Uranium Processing And Tailings Facilities

    SciTech Connect (OSTI)

    Looney, Brian B.; Denham, Miles E.; Eddy-Dilek, Carol A.; Millings, Margaret R.; Kautsky, Mark

    2014-01-08

    Management of legacy tailings/waste and groundwater contamination are ongoing at the former uranium milling site in Tuba City AZ. The tailings have been consolidated and effectively isolated using an engineered cover system. For the existing groundwater plume, a system of recovery wells extracts contaminated groundwater for treatment using an advanced distillation process. The ten years of pump and treat (P&T) operations have had minimal impact on the contaminant plume primarily due to geochemical and hydrological limits. A flow net analysis demonstrates that groundwater contamination beneath the former processing site flows in the uppermost portion of the aquifer and exits the groundwater as the plume transits into and beneath a lower terrace in the landscape. The evaluation indicates that contaminated water will not reach Moenkopi Wash, a locally important stream. Instead, shallow groundwater in arid settings such as Tuba City is transferred into the vadose zone and atmosphere via evaporation, transpiration and diffuse seepage. The dissolved constituents are projected to precipitate and accumulate as minerals such as calcite and gypsum in the deep vadose zone (near the capillary fringe), around the roots of phreatophyte plants, and near seeps. The natural hydrologic and geochemical controls common in arid environments such as Tuba City work together to limit the size of the groundwater plume, to naturally attenuate and detoxify groundwater contaminants, and to reduce risks to humans, livestock and the environment. The technical evaluation supports an alternative beneficial reuse (brownfield) scenario for Tuba City. This alternative approach would have low risks, similar to the current P&T scenario, but would eliminate the energy and expense associated with the active treatment and convert the former uranium processing site into a resource for future employment of local citizens and ongoing benefit to the Native American Nations.

  4. Groundwater geochemical modeling and simulation of a breached high-level radioactive waste repository in the northern Tularosa Basin, New Mexico

    SciTech Connect (OSTI)

    Chappell, R.W.

    1989-01-01

    The northern Tularosa Basin in south-central New Mexico was ranked favorably as a potential location for a high-level radioactive waste repository by a US Geological Survey pilot screening study of the Basin and Range Province. The favorable ranking was based chiefly on hydrogeologic and descriptive geochemical evidence. A goal of this study was to develop a methodology for predicting the performance of this or any other basin as a potential repository site using geochemical methods. The approach involves first characterizing the groundwater geochemistry, both chemically and isotopically, and reconstructing the probable evolutionary history of, and controls on the ground water chemistry through modeling. In the second phase of the approach, a hypothetically breached repository is introduced into the system, and the mobility of the parent radionuclide, uranium, in the groundwater is predicted. Possible retardation of uranium transport in the downgradient flow direction from the repository by adsorption and mineral precipitation is then considered. The Permian Yeso Formation, the primary aquifer in the northern Tularosa Basin, was selected for study, development and testing of the methodology outlined above. The Yeso Formation contains abundant gypsum and related evaporite minerals, which impart a distinctive chemical signature to the ground water. Ground water data and solubility calculations indicate a conceptual model of irreversible gypsum and dolomite dissolution with concomitant calcite precipitation. Recharge areas are apparent from temperature, {delta}{sup 18}O and {delta}{sup 2} H, and {sup 3}H trends in the aquifer. Corrected {sup 14}C ages range between modern and 31,200 years, and suggest an average ground water velocity of 0.83 m/yr.

  5. Elucidating geochemical response of shallow heterogeneous aquifers to CO2 leakage using high-performance computing: Implications for monitoring of CO2 sequestration

    SciTech Connect (OSTI)

    Navarre-Sitchler, Alexis K.; Maxwell, Reed M.; Siirila, Erica R.; Hammond, Glenn E.; Lichtner, Peter C.

    2013-03-01

    Predicting and quantifying impacts of potential carbon dioxide (CO2) leakage into shallow aquifers that overlie geologic CO2 storage formations is an important part of developing reliable carbon storage techniques. Leakage of CO2 through fractures, faults or faulty wellbores can reduce groundwater pH, inducing geochemical reactions that release solutes into the groundwater and pose a risk of degrading groundwater quality. In order to help quantify this risk, predictions of metal concentrations are needed during geologic storage of CO2. Here, we present regional-scale reactive transport simulations, at relatively fine-scale, of CO2 leakage into shallow aquifers run on the PFLOTRAN platform using high-performance computing. Multiple realizations of heterogeneous permeability distributions were generated using standard geostatistical methods. Increased statistical anisotropy of the permeability field resulted in more lateral and vertical spreading of the plume of impacted water, leading to increased Pb2+ (lead) concentrations and lower pH at a well down gradient of the CO2 leak. Pb2+ concentrations were higher in simulations where calcite was the source of Pb2+ compared to galena. The low solubility of galena effectively buffered the Pb2+ concentrations as galena reached saturation under reducing conditions along the flow path. In all cases, Pb2+ concentrations remained below the maximum contaminant level set by the EPA. Results from this study, compared to natural variability observed in aquifers, suggest that bicarbonate (HCO3) concentrations may be a better geochemical indicator of a CO2 leak under the conditions simulated here.

  6. General Counsel Legal Interpretation Regarding Medical Removal Protection Benefits Pursuant to 10 CFR Part 850, Chronic Beryllium Disease Prevention Program

    Broader source: Energy.gov [DOE]

    The following document is the Office of the General Counsel (GC) interpretation regarding Medical Removal Protection Benefits Pursuant to 10 CFR Part 850, Chronic Beryllium Disease Prevention Program.

  7. Geophysical interpretations west of and within the northwestern part of the Nevada Test Site

    SciTech Connect (OSTI)

    Grauch, V.J.; Sawyer, D.A.; Fridrich, C.J.; Hudson, M.R.

    1997-12-31

    This report focuses on interpretation of gravity and new magnetic data west of the Nevada Test Site (NTS) and within the northwestern part of NTS. The interpretations integrate the gravity and magnetic data with other geophysical, geological, and rock property data to put constraints on tectonic and magmatic features not exposed at the surface. West of NTS, where drill hole information is absent, these geophysical data provide the best available information on the subsurface. Interpreted subsurface features include calderas, intrusions, basalt flows and volcanoes, Tertiary basins, structurally high pre-Tertiary rocks, and fault zones. New features revealed by this study include (1) a north-south buried tectonic fault east of Oasis Mountain, which the authors call the Hogback fault; (2) an east striking fault or accommodation zone along the south side of Oasis Valley basin, which they call the Hot Springs fault; (3) a NNE striking structural zone coinciding with the western margins of the caldera complexes; (4) regional magnetic highs that probably represent a thick sequence of Tertiary volcanic rocks; and (5) two probable buried calderas that may be related to the tuffs of Tolicha Peak and of Sleeping Butte, respectively.

  8. Data interpretation of joint compressional and shear wave survey in mountainous region

    SciTech Connect (OSTI)

    Fugiu, D. )

    1992-01-01

    The join utilization of compressional and shear wave data leads one to discover nonstructural hydrocarbon traps such as stratigraphic trap, lithologic trap, fracture trap, etc. and to ascertain fluid situation in formation, lithologic variation and fracture zone, so that the accuracy of seismic data interpretation is improved greatly. In this paper, the author describes how to determine shear wave horizon, how to interpret carbonate reservoir and how to discover gas accumulation zone in HBC area in Sichuan Province. It is very important to pay more attention to analyzing the ratio between compressional wave amplitude and shear wave amplitude, and the ratio between compressional wave velocity and shear wave velocity in data interpretation. The amplitude ratio anomaly and the velocity ratio anomaly in HBC area can be usually seen at anticlinal axis areas and small noses. Generally speaking, the amplitude ratio anomaly area reflects gas accumulation and the velocity ratio anomaly area exhibits dense fracture zone. Good results have been obtained from exploratory wells in the areas where there occur the two anomalies simultaneously.

  9. Interpretation Of Multifrequency Crosswell Electromagnetic Data With Frequency Dependent Core Data

    SciTech Connect (OSTI)

    Kirkendall, B; Roberts, J

    2005-06-07

    Interpretation of cross-borehole electromagnetic (EM) images acquired at enhanced oil recovery (EOR) sites has proven to be difficult due to the typically complex subsurface geology. Significant problems in image interpretation include correlation of specific electrical conductivity values with oil saturations, the time-dependent electrical variation of the subsurface during EOR, and the non-unique electrical conductivity relationship with subsurface conditions. In this study we perform laboratory electrical properties measurements of core samples from the EOR site to develop an interpretation approach that combines field images and petrophysical results. Cross-borehole EM images from the field indicate resistivity increases in EOR areas--behavior contrary to the intended waterflooding design. Laboratory measurements clearly show a decrease in resistivity with increasing effective pressure and are attributed to increased grain-to-grain contact enhancing a strong surface conductance. We also observe a resistivity increase for some samples during brine injection. These observations possibly explain the contrary behavior observed in the field images. Possible mechanisms for increasing the resistivity in the region include (1) increased oil content as injectate sweeps oil toward the plane of the observation wells; (2) lower conductance pore fluid displacing the high-conductivity brine; (3) degradation of grain-to-grain contacts of the initially conductive matrix; and (4) artifacts of the complicated resistivity/time history similar to that observed in the laboratory experiments.

  10. Communication: The correct interpretation of surface hopping trajectories: How to calculate electronic properties

    SciTech Connect (OSTI)

    Landry, Brian R.; Falk, Martin J.; Subotnik, Joseph E.

    2013-12-07

    In a recent paper, we presented a road map for how Tully's fewest switches surface hopping (FSSH) algorithm can be derived, under certain circumstances, from the mixed quantum-classical Liouville equation. In this communication, we now demonstrate how this new interpretation of surface hopping can yield significantly enhanced results for electronic properties in nonadiabatic calculations. Specifically, we calculate diabatic populations for the spin-boson problem using FSSH trajectories. We show that, for some Hamiltonians, without changing the FSSH algorithm at all but rather simply reinterpreting the ensemble of surface hopping trajectories, we recover excellent results and remove any and all ambiguity about the initial condition problem.

  11. Simple interpretation of shape evolution in Pt isotopes without intruder states

    SciTech Connect (OSTI)

    McCutchan, E.A.; Casten, R.F.; Zamfir, N.V.

    2005-06-01

    The most commonly accepted interpretation of the light Pt isotopes invokes the coexistence and mixing with proton intruder states from above the Z = 82 shell gap. Using an alternative description, interacting boson model (IBA) calculations are performed for the Pt isotopes with a simple, single configuration, two-parameter Hamiltonian. Excellent agreement is obtained for energies and electromagnetic transition strengths over the entire isotopic chain, spanning a wide variety of structures, and suggesting that these nuclei can be described more simply without the introduction of an intruder configuration. The Pt nuclei close to midshell are found to lie close to a region of phase/shape coexistence.

  12. INTERPRETATION OF AIRBORNE ELECTROMAGNETIC AND MAGNETIC DATA IN THE 600 AREA

    SciTech Connect (OSTI)

    CUMMINS GD

    2010-11-11

    As part of the 200-PO-1 Phase I geophysical surveys, Fugro Airborne Surveys was contracted to collect airborne electromagnetic (EM) and magnetic surveys of the Hanford Site 600 Area. Two helicopter survey systems were used with the HeliGEOTEM{reg_sign} time domain portion flown between June 19th and June 20th, 2008, and the RESOLVE{reg_sign} frequency domain portion was flown from June 29th to July 1st, 2008. Magnetic data were acquired contemporaneously with the electromagnetic surveys using a total-field cesium vapor magnetometer. Approximately 925 line kilometers (km) were flown using the HeliGEOTEM{reg_sign} II system and 412 line kilometers were flown using the RESOLVE{reg_sign} system. The HeliGEOTEM system has an effective penetration of roughly 250 meters into the ground and the RESOLVE system has an effective penetration of roughly 60 meters. Acquisition parameters and preliminary results are provided in SGW-39674, Airborne Electromagnetic Survey Report, 200-PO-1 Groundwater Operable Unit, 600 Area, Hanford Site. Airborne data are interpreted in this report in an attempt to identify areas of likely preferential groundwater flow within the aquifer system based on the presence of paleochannels or fault zones. The premise for the interpretation is that coarser-grained intervals have filled in scour channels created by episodic catastrophic flood events during the late Pleistocene. The interpretation strategy used the magnetic field anomaly data and existing bedrock maps to identify likely fault or lineament zones. Combined analysis of the magnetic, 60-Hz noise monitor, and flight-altitude (radar) data were used to identify zones where EM response is more likely due to cultural interference and or bedrock structures. Cross-sectional and map view presentations of the EM data were used to identify more electrically resistive zones that likely correlate with coarser-grained intervals. The resulting interpretation identifies one major northwest-southeast trending preferential flowpath with several minor units running along a similar trend. This presumed path of preferential flow is compared with the tritium concentration levels observed for the 600 Area. Analysis of the magnetic field data shows the location of potential bedrock faults and lineaments which may influence the horizontal and vertical flow of water. Faults lying within, or in the vicinity of preferential groundwater flow paths may allow flow into or out of the otherwise confined basalt layers.

  13. Drill-hole data, drill-site geology, and geochemical data from the study of Precambrian uraniferous conglomerates of the Medicine Bow Mountains and Sierra Madre of southeastern Wyoming

    SciTech Connect (OSTI)

    Karlstrom, K.E.; Houston, R.S.; Schmidt, T.G.; Inlow, D.; Flurkey, A.J.; Kratochvil, A.L.; Coolidge, C.M.; Sever, C.K.; Quimby, W.F.

    1981-02-01

    This volume is presented as a companion to Volume 1: The Geology and Uranium Potential of Precambrian Conglomerates in the Medicine Bow Mountains and Sierra Madre of Southeastern Wyoming; and to Volume 3: Uranium Assessment for Precambrian Pebble Conglomerates in Southeastern Wyoming. Volume 1 summarized the geologic setting and geologic and geochemical characteristics of uranium-bearing conglomerates in Precambrian metasedimentary rocks of southeastern Wyoming. Volume 3 is a geostatistical resource estimate of U and Th in quartz-pebble conglomerates. This volume contains supporting geochemical data, lithologic logs from 48 drill holes in Precambrian rocks of the Medicine Bow Mountains and Sierra Madre, and drill site geologic maps and cross-sections from most of the holes.

  14. Geochemical and Isotopic Evaluation of Groundwater Movement in Corrective Action Unit 97: Yucca Flat/Climax Mine, Nevada Test Site, Nevada, Rev. No.: 0

    SciTech Connect (OSTI)

    Farnham, Irene

    2006-02-01

    This report describes the results of a comprehensive geochemical evaluation of the groundwater flow system in the Yucca Flat/Climax Mine Corrective Action Unit (CAU). The main objectives of this study are to identify probable pathways for groundwater flow within the study area and to develop constraints on groundwater transit times between selected data collection sites. This work provides an independent means of testing and verifying predictive flow models being developed for this CAU using finite element methods. The Yucca Flat/Climax Mine CAU constitutes the largest of six underground test areas on the Nevada Test Site (NTS) specified for remedial action in the ''Federal Facility Agreement and Consent Order''. A total of 747 underground nuclear detonations were conducted in this CAU. Approximately 23 percent of these detonations were conducted below or near the water table, resulting in groundwater contamination in the vicinity and possibly downgradient of these underground test locations. Therefore, a rigorous evaluation of the groundwater flow system in this CAU is necessary to assess potential long-term risks to the public water supply at downgradient locations.

  15. Sedimentological, mineralogical and geochemical definition of oil-shale facies in the lower Parachute Creek Member of Green River Formation, Colorado

    SciTech Connect (OSTI)

    Cole, R.D.

    1984-04-01

    Sedimentological, mineralogical and geochemical studies of two drill cores penetrating the lower Saline zone of the Parachute Creek Member (middle L-4 oil-shale zone through upper R-2 zone) of the Green River Formation in north-central Piceance Creek basin, Colorado, indicate the presence of two distinct oil-shale facies. The most abundant facies has laminated stratification and frequently occurs in the L-4, L-3 and L-2 oil-shale zones. The second, and subordinate facies, has ''streaked and blebby'' stratification and is most abundant in the R-4, R-3 and R-2 zones. Laminated oil shale originated by slow, regular sedimentation during meromictic phases of ancient Lake Uinta, whereas streaked and blebby oil shale was deposited by episodic, non-channelized turbidity currents. Laminated oil shale has higher contents of nahcolite, dawsonite, quartz, K-feldspar and calcite, but less dolomite/ankerite and albite than streaked and blebby oil shale. Ca-Mg-Fe carbonate minerals in laminated oil shale have more variable compositions than those in streaked and blebby shales. Streaked and blebby oil shale has more kerogen and a greater diversity of kerogen particles than laminated oil shale. Such variations may produce different pyrolysis reactions when each shale type is retorted.

  16. EQ3NR, a computer program for geochemical aqueous speciation-solubility calculations: Theoretical manual, user`s guide, and related documentation (Version 7.0); Part 3

    SciTech Connect (OSTI)

    Wolery, T.J.

    1992-09-14

    EQ3NR is an aqueous solution speciation-solubility modeling code. It is part of the EQ3/6 software package for geochemical modeling. It computes the thermodynamic state of an aqueous solution by determining the distribution of chemical species, including simple ions, ion pairs, and complexes, using standard state thermodynamic data and various equations which describe the thermodynamic activity coefficients of these species. The input to the code describes the aqueous solution in terms of analytical data, including total (analytical) concentrations of dissolved components and such other parameters as the pH, pHCl, Eh, pe, and oxygen fugacity. The input may also include a desired electrical balancing adjustment and various constraints which impose equilibrium with special pure minerals, solid solution end-member components (of specified mole fractions), and gases (of specified fugacities). The code evaluates the degree of disequilibrium in terms of the saturation index (SI = 1og Q/K) and the thermodynamic affinity (A = {minus}2.303 RT log Q/K) for various reactions, such as mineral dissolution or oxidation-reduction in the aqueous solution itself. Individual values of Eh, pe, oxygen fugacity, and Ah (redox affinity) are computed for aqueous redox couples. Equilibrium fugacities are computed for gas species. The code is highly flexible in dealing with various parameters as either model inputs or outputs. The user can specify modification or substitution of equilibrium constants at run time by using options on the input file.

  17. Interpreting the behavior of a quarter-wave transmission line resonator in a magnetized plasma

    SciTech Connect (OSTI)

    Gogna, G. S. Turner, M. M.; Karkari, S. K.

    2014-12-15

    The quarter wave resonator immersed in a strongly magnetized plasma displays two possible resonances occurring either below or above its resonance frequency in vacuum, f{sub o}. This fact was demonstrated in our recent articles [G. S. Gogna and S. K. Karkari, Appl. Phys. Lett. 96, 151503 (2010); S. K. Karkari, G. S. Gogna, D. Boilson, M. M. Turner, and A. Simonin, Contrib. Plasma Phys. 50(9), 903 (2010)], where the experiments were carried out over a limited range of magnetic fields at a constant electron density, n{sub e}. In this paper, we present the observation of dual resonances occurring over the frequency scan and find that n{sub e} calculated by considering the lower resonance frequency is 25%–30% smaller than that calculated using the upper resonance frequency with respect to f{sub o}. At a given magnetic field strength, the resonances tend to shift away from f{sub o} as the background density is increased. The lower resonance tends to saturate when its value approaches electron cyclotron frequency, f{sub ce}. Interpretation of these resonance conditions are revisited by examining the behavior of the resonance frequency response as a function of n{sub e}. A qualitative discussion is presented which highlights the practical application of the hairpin resonator for interpreting n{sub e} in a strongly magnetized plasma.

  18. Interpreting, correlating, and predicting the multimedia concentrations of PCDD/Fs in the United Kingdom

    SciTech Connect (OSTI)

    Cole, J.G.; Mackay, D.; Jones, K.C.; Alcock, R.E.

    1999-02-01

    Reported concentrated of 17 polychlorinated dibenzo-p-dioxin and furan congeners or congener groups in ten environmental media of the UK have been compiled. The relative equilibrium status of each congener is deduced with respect to its concentration in urban air which is regarded as the primary source of multimedia contamination. This is accomplished by calculating the equilibrium lipid partitioning (ELP) concentration for each congener and medium using partitioning information derived from measured physical chemical properties. It is shown that the extents of departure from equilibrium conditions between media are consistent for all congeners except the octa-chlorinated compounds. This method of analyzing monitoring data and the consistency of intermedia ELP concentration ratios facilitates the interpretation of the fate and levels of these persistent chemicals in a multimedia environment and yields an approximate predictive capability by which levels in one medium can be used to estimate levels in other media. Benefits of this ELP concentration approach are discussed as a means of enhancing the more complete and detailed interpretation of monitoring data for persistent compounds.

  19. Interpretation of a short-term anomaly in the gravitational microlensing event MOA-2012-BLG-486

    SciTech Connect (OSTI)

    Hwang, K.-H.; Choi, J.-Y.; Han, C.; Bond, I. A.; Sumi, T.; Koshimoto, N.; Gaudi, B. S.; Gould, A.; Bozza, V.; Beaulieu, J.-P.; Tsapras, Y.; Abe, F.; Fukunaga, D.; Itow, Y.; Bennett, D. P.; Botzler, C. S.; Freeman, M.; Chote, P.; Harris, P.; Fukui, A.; Collaboration: MOA Collaboration; μFUN Collaboration; PLANET Collaboration; RoboNet Collaboration; and others

    2013-11-20

    A planetary microlensing signal is generally characterized by a short-term perturbation to the standard single lensing light curve. A subset of binary-source events can produce perturbations that mimic planetary signals, thereby introducing an ambiguity between the planetary and binary-source interpretations. In this paper, we present the analysis of the microlensing event MOA-2012-BLG-486, for which the light curve exhibits a short-lived perturbation. Routine modeling not considering data taken in different passbands yields a best-fit planetary model that is slightly preferred over the best-fit binary-source model. However, when allowed for a change in the color during the perturbation, we find that the binary-source model yields a significantly better fit and thus the degeneracy is clearly resolved. This event not only signifies the importance of considering various interpretations of short-term anomalies, but also demonstrates the importance of multi-band data for checking the possibility of false-positive planetary signals.

  20. DIRECT RADIO PROBING AND INTERPRETATION OF THE SUN'S PLASMA DENSITY PROFILE

    SciTech Connect (OSTI)

    Cairns, I. H.; Lobzin, V. V.; Li, B.; Robinson, P. A.; Warmuth, A.; Mann, G.

    2009-12-01

    The Sun's electron number density profile n{sub e} (r) is vital for solar physics but not well measured or understood within a few solar radii R{sub S} . Here, a new technique extracts n{sub e} (r) directly from coronal type III radio bursts for 40 <= f <= 180 MHz. Unexpectedly, wind-like regions with n{sub e} propor to (r - R{sub S} ){sup -2} are quite common below 2R{sub S} , and coronal type IIIs often have closely linear 1/f - t spectra. The profile n{sub e} propor to (r - R{sub S} ){sup -2} is consistent with the radio data and simulations and is interpreted in terms of conical flow from localized sources (e.g., UV funnels) close to the photosphere. It is consistent with solar wind acceleration occurring for 2 <= r/R{sub S} <= 10.

  1. Interpretation of HRTEM images by image simulation: An introduction to theory and practice

    SciTech Connect (OSTI)

    O`Keefe, M.A.

    1994-08-01

    This tutorial describes the use of image simulation as an aid to interpretation of high-resolution transmission electron microscope images. Topics include some image processing as well as image simulation. Image processing is the manipulation of experimental images in order to extract some desired information. Image simulation is the generation of a computed or simulated image from a model structure. It requires a detailed knowledge of the process of image formation in the high-resolution transmission electron microscope. This tutorial concentrates on image simulation, with examples of image processing appearing only as required as illustrations. Because this is an introduction, the theory of image simulation is described, but not explored in depth. The practice of image simulation is covered in sufficient detail to enable the student to understand the functions of the various steps in the computations, and the parameters necessary for their evaluation.

  2. Radar imagery interpretation to assess the hydrocarbon potential of four sites in the Philippines

    SciTech Connect (OSTI)

    Not Available

    1988-11-17

    The Republic of the Philippines is intensely interested in the identification, development, and conservation of natural resources. In keeping with this, the Government of the Philippines has recently completed a nationwide sedimentary basin evaluation program to assess hydrocarbon potential and assist in future exploration activities. This program of collection and interpretation of the radar imagery was designed to augment and complement the existing data base. The primary objective of the project was to further the goals of international energy development by aiding the Republic of the Philippines in the assessment of potential petroleum and geothermal prospects within the areas imaged. Secondary goals were to assist the Republic of the Philippines in utilizing state-of-the-art radar remote sensing technology for resource exploration, and to train key Philippines scientists in the use of imaging radar data. 29 refs., 30 figs., 14 tabs.

  3. Executive summary: Radar imagery interpretation to assess the hydrocarbon potential of four sites in the Phillipines

    SciTech Connect (OSTI)

    Not Available

    1988-11-17

    The Republic of the Philippines is intensely interested in the identification, development, and conservation of natural resources. In keeping with this, the Government of the Philippines has recently completed a nationwide sedimentary basin evaluation program to assess hydrocarbon potential and assist in future exploration activities. This program of collection and interpretation of the radar imagery was designed to augment and complement the existing data base. The primary objective of the project was to further the goals of international energy development by aiding the Republic of the Philippines in the assessment of potential petroleum and geothermal prospects within the areas imaged. Secondary goals were to assist the Republic of the Philippines in utilizing state-of-the-art radar remote sensing technology for resource exploration, and to train key Philippines scientists in the use of imaging radar data. 9 refs., 9 figs., 3 tabs.

  4. Radar imagery interpretation to provide information about several geothermal sites in the Philippines

    SciTech Connect (OSTI)

    Not Available

    1988-11-17

    The Republic of the Philippines is intensely interested in the identification, development, and conservation of natural resources. In keeping with this, the Government of the Philippines has recently completed a nation-wide sedimentary basin evaluation program to assess hydrocarbon potential and assist in future exploration activities. This program of collection and interpretation of the radar imagery was designed to augment and complement the existing data base. The primary objective of the project was to further the goals of international energy development by aiding the Republic of the Philippines in the assessment of potential geothermal and petroleum prospects within the areas imaged. Secondary goals were to assist the Republic of the Philippines in utilizing state-of-the-art radar remote sensing technology for resource exploration, and to train key Philippines scientists in the use of imaging radar data. 7 refs., 20 figs., 2 tabs.

  5. Interpretations of Tracer Tests Performed in the Culebra Dolomite at the Waste Isolation Pilot Plant Site

    SciTech Connect (OSTI)

    MEIGS,LUCY C.; BEAUHEIM,RICHARD L.; JONES,TOYA L.

    2000-08-01

    This report provides (1) an overview of all tracer testing conducted in the Culebra Dolomite Member of the Rustler Formation at the Waste Isolation Pilot Plant (WPP) site, (2) a detailed description of the important information about the 1995-96 tracer tests and the current interpretations of the data, and (3) a summary of the knowledge gained to date through tracer testing in the Culebra. Tracer tests have been used to identify transport processes occurring within the Culebra and quantify relevant parameters for use in performance assessment of the WIPP. The data, especially those from the tests performed in 1995-96, provide valuable insight into transport processes within the Culebra. Interpretations of the tracer tests in combination with geologic information, hydraulic-test information, and laboratory studies have resulted in a greatly improved conceptual model of transport processes within the Culebra. At locations where the transmissivity of the Culebra is low (< 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a single-porosity medium in which advection occurs largely through the primary porosity of the dolomite matrix. At locations where the transmissivity of the Culebra is high (> 4 x 10{sup -6} m{sup 2}/s), we conceptualize the Culebra as a heterogeneous, layered, fractured medium in which advection occurs largely through fractures and solutes diffuse between fractures and matrix at multiple rates. The variations in diffusion rate can be attributed to both variations in fracture spacing (or the spacing of advective pathways) and matrix heterogeneity. Flow and transport appear to be concentrated in the lower Culebra. At all locations, diffusion is the dominant transport process in the portions of the matrix that tracer does not access by flow.

  6. Loss of sex chromosomes in the hematopoietic disorders: Questions, concerns and data interpretation

    SciTech Connect (OSTI)

    Slovak, M.L. [City of Hope National Medical Center, Duarte, CA (United States)

    1994-09-01

    The significance of sex chromosome aberrations in the hematopoietic disorders has not yet been defined. Interpretive problems stem from (1) the loss of a sex chromosome associated with aging, (2) sex chromosome loss as the sole aberration in leukemia is rare, (3) random -(X or Y) is observed frequently in bone marrow samples, and (4) constitutional sex chromosome anomalies must be ruled out in cancer and follow-up may not be possible. The COH database identified 41 patients (pts) with sex chromosome loss. Loss of a sex chromosome was common in myeloid disorders (21/41). In t(8;21) leukemia (n=10), -(X or Y) was a common secondary karyotypic change. Additionally, -Y was associated with clonal evolution in 2 Ph + CML pts. In 2 elderly pts with myeloid disorders, -(X or Y) was observed in complex karyotypes with dmins; however, in the lymphoproliferative disorders -(X or Y) was noted in elderly pts without apparent pathogenetic significance. Three pts had constitutional sex chromosome aberrations: CML in 45,X; ALL in 47, XXY; and RAEB-IT in mos45,X/46,XX. In the mos45,X/46,XX pt, the leukemic clone was associated with the 45,X line without other karyotypic changes. Non-clonal aberrations were observed in 11 cases; in 3 cases these non-clonal losses were observed in serial samples. In a sex-mismatched BMT case, -(X or Y) in 4 cells was one of the first pathogenetic signs of leukemia relapse. These data suggest (1) interpretation of sex chromosome loss in leukemia must be made with caution and after a baseline sample, (2) non-clonal aberrations should be recorded, and (3) -(X or Y) appears to have pathogenetic significance in the myeloid disorders. Multi-institutional studies are needed to define (1) the incidence of leukemia in pts with constitutional sex chromosome anomalies and (2) the incidence and significance of sex chromosome aberrations as the primary (sole) cytogenetic aberration in leukemia.

  7. Computed solid phases limiting the concentration of dissolved constituents in basalt aquifers of the Columbia Plateau in eastern Washington. Geochemical modeling and nuclide/rock/groundwater interaction studies

    SciTech Connect (OSTI)

    Deutsch, W.J.; Jenne, E.A.; Krupka, K.M.

    1982-08-01

    A speciation-solubility geochemical model, WATEQ2, was used to analyze geographically-diverse, ground-water samples from the aquifers of the Columbia Plateau basalts in eastern Washington. The ground-water samples compute to be at equilibrium with calcite, which provides both a solubility control for dissolved calcium and a pH buffer. Amorphic ferric hydroxide, Fe(OH)/sub 3/(A), is at saturation or modestly oversaturated in the few water samples with measured redox potentials. Most of the ground-water samples compute to be at equilibrium with amorphic silica (glass) and wairakite, a zeolite, and are saturated to oversaturated with respect to allophane, an amorphic aluminosilicate. The water samples are saturated to undersaturated with halloysite, a clay, and are variably oversaturated with regard to other secondary clay minerals. Equilibrium between the ground water and amorphic silica presumably results from the dissolution of the glassy matrix of the basalt. The oversaturation of the clay minerals other than halloysite indicates that their rate of formation lags the dissolution rate of the basaltic glass. The modeling results indicate that metastable amorphic solids limit the concentration of dissolved silicon and suggest the same possibility for aluminum and iron, and that the processes of dissolution of basaltic glass and formation of metastable secondary minerals are continuing even though the basalts are of Miocene age. The computed solubility relations are found to agree with the known assemblages of alteration minerals in the basalt fractures and vesicles. Because the chemical reactivity of the bedrock will influence the transport of solutes in ground water, the observed solubility equilibria are important factors with regard to chemical-retention processes associated with the possible migration of nuclear waste stored in the earth's crust.

  8. Isotopic and geochemical tracers for U(VI) reduction and U mobility at an in situ recovery U mine

    SciTech Connect (OSTI)

    Basu, Anirban; Brown, Shaun T.; Christensen, John N.; DePaolo, Donald J.; Reimus, Paul W.; Heikoop, Jeffrey M.; Woldegabriel, Giday; Simmons, Ardyth M.; House, Brian M.; Hartmann, Matt; Maher, Kate

    2015-05-19

    In situ recovery (ISR) uranium (U) mining mobilizes U in its oxidized hexavalent form (U(VI)) by oxidative dissolution of U from the roll-front U deposits. Post-mining natural attenuation of residual U(VI) at ISR mines is a potential remediation strategy. Detection and monitoring of naturally occurring reducing subsurface environments are important for successful implementation of this remediation scheme. We used the isotopic tracers ²³⁸U/²³⁵U (δ²³⁸U), ²³⁴U/²³⁸U activity ratio, and ³⁴S/³²S (δ³⁴S), and geochemical measurements of U ore and groundwater collected from 32 wells located within, upgradient, and downgradient of a roll-front U deposit to detect U(VI) reduction and U mobility at an ISR mining site at Rosita, TX, USA. The δ²³⁸U in Rosita groundwater varies from 0.61‰ to -2.49‰, with a trend toward lower δ²³⁸U in downgradient wells. The concurrent decrease in U(VI) concentration and δ²³⁸U with an ε of 0.48‰ ± 0.08‰ is indicative of naturally occurring reducing environments conducive to U(VI) reduction. Additionally, characteristic ²³⁴U/²³⁸U activity ratio and δ³⁴S values may also be used to trace the mobility of the ore zone groundwater after mining has ended. These results support the use of U isotope-based detection of natural attenuation of U(VI) at Rosita and other similar ISR mining sites.

  9. DOE ER63951-3 Final Report: An Integrated Assessment of Geochemical and Community Structure Determinants of Metal Reduction Rates in Subsurface Sediments

    SciTech Connect (OSTI)

    Susan Pfiffner

    2010-06-28

    The objective of this research was to examine the importance of microbial community structure in influencing uranium reduction rates in subsurface sediments. If the redox state alone is the key to metal reduction, then any organisms that can utilize the oxygen and nitrate in the subsurface can change the geochemical conditions so metal reduction becomes an energetically favored reaction. Thus, community structure would not be critical in determining rates or extent of metal reduction unless community structure influenced the rate of change in redox. Alternatively, some microbes may directly catalyze metal reduction (e.g., specifically reduce U). In this case the composition of the community may be more important and specific types of electron donors may promote the production of communities that are more adept at U reduction. Our results helped determine if the type of electron donor or the preexisting community is important in the bioremediation of metal-contaminated environments subjected to biostimulation. In a series of experiments at the DOE FRC site in Oak Ridge we have consistently shown that all substrates promoted nitrate reduction, while glucose, ethanol, and acetate always promoted U reduction. Methanol only occasionally promoted extensive U reduction which is possibly due to community heterogeneity. There appeared to be limitations imposed on the community related to some substrates (e.g. methanol and pyruvate). Membrane lipid analyses (phospholipids and respiratory quinones) indicated different communities depending on electron donor used. Terminal restriction fragment length polymorphism and clone libraries indicated distinct differences among communities even in treatments that promoted U reduction. Thus, there was enough metabolic diversity to accommodate many different electron donors resulting in the U bioimmobilization.

  10. User's Guide of TOUGH2-EGS. A Coupled Geomechanical and Reactive Geochemical Simulator for Fluid and Heat Flow in Enhanced Geothermal Systems Version 1.0

    SciTech Connect (OSTI)

    Fakcharoenphol, Perapon; Xiong, Yi; Hu, Litang; Winterfeld, Philip H.; Xu, Tianfu; Wu, Yu-Shu

    2013-05-01

    TOUGH2-EGS is a numerical simulation program coupling geomechanics and chemical reactions for fluid and heat flows in porous media and fractured reservoirs of enhanced geothermal systems. The simulator includes the fully-coupled geomechanical (THM) module, the fully-coupled geochemical (THC) module, and the sequentially coupled reactive geochemistry (THMC) module. The fully-coupled flow-geomechanics model is developed from the linear elastic theory for the thermo-poro-elastic system and is formulated with the mean normal stress as well as pore pressure and temperature. The chemical reaction is sequentially coupled after solution of flow equations, which provides the flow velocity and phase saturation for the solute transport calculation at each time step. In addition, reservoir rock properties, such as porosity and permeability, are subjected to change due to rock deformation and chemical reactions. The relationships between rock properties and geomechanical and chemical effects from poro-elasticity theories and empirical correlations are incorporated into the simulator. This report provides the user with detailed information on both mathematical models and instructions for using TOUGH2-EGS for THM, THC or THMC simulations. The mathematical models include the fluid and heat flow equations, geomechanical equation, reactive geochemistry equations, and discretization methods. Although TOUGH2-EGS has the capability for simulating fluid and heat flows coupled with both geomechanical and chemical effects, it is up to the users to select the specific coupling process, such as THM, THC, or THMC in a simulation. There are several example problems illustrating the applications of this program. These example problems are described in details and their input data are presented. The results demonstrate that this program can be used for field-scale geothermal reservoir simulation with fluid and heat flow, geomechanical effect, and chemical reaction in porous and fractured media.

  11. LORENTZ-FACTOR-ISOTROPIC-LUMINOSITY/ENERGY CORRELATIONS OF GAMMA-RAY BURSTS AND THEIR INTERPRETATION

    SciTech Connect (OSTI)

    Lue Jing; Zou Yuanchuan; Lei Weihua; Wu Qingwen; Wang Dingxiong [School of Physics, Huazhong University of Science and Technology, Wuhan 430074 (China); Zhang Bing; Lue Houjun [Department of Physics and Astronomy, University of Nevada Las Vegas, 4505 Maryland Parkway, Box 454002, Las Vegas, NV 89154-4002 (United States); Liang Enwei, E-mail: zouyc@hust.edu.cn, E-mail: leiwh@hust.edu.cn, E-mail: zhang@physics.unlv.edu [Department of Physics, Guangxi University, Nanning 530004 (China)

    2012-05-20

    The bulk Lorentz factor of the gamma-ray burst (GRB) ejecta ({Gamma}{sub 0}) is a key parameter to understanding GRB physics. Liang et al. have discovered a correlation between {Gamma}{sub 0} and isotropic {gamma}-ray energy: {Gamma}{sub 0}{proportional_to}E{sup 0.25}{sub {gamma},iso,52}. By including more GRBs with updated data and more methods to derive {Gamma}{sub 0}, we confirm this correlation and obtain {Gamma}{sub 0} {approx_equal} 91E{sup 0.29}{sub {gamma},iso,52}. Evaluating the mean isotropic {gamma}-ray luminosities L{sub {gamma},iso} of the GRBs in the same sample, we discover an even tighter correlation {Gamma}{sub 0} {approx_equal} 249L{sup 0.30}{sub {gamma},iso,52}. We propose an interpretation to this later correlation. Invoking a neutrino-cooled hyperaccretion disk around a stellar mass black hole as the central engine of GRBs, we derive jet luminosity powered by neutrino annihilation and baryon loading from a neutrino-driven wind. Applying beaming correction, we finally derive {Gamma}{sub 0}{proportional_to}L{sup 0.22}{sub {gamma},iso}, which is consistent with the data. This suggests that the central engine of long GRBs is likely a stellar mass black hole surrounded by a hyper-accreting disk.

  12. Dynamical interpretation of average fission-fragment kinetic energy systematics and nuclear scission

    SciTech Connect (OSTI)

    Nadtochy, P.N. [GSI, Plankstrasse 1, D-64291 Darmstadt (Germany); Omsk State University, Department of Theoretical Physics, Mira Prospect 55-A, RU-644077 Omsk (Russian Federation); Adeev, G.D. [Omsk State University, Department of Theoretical Physics, Mira Prospect 55-A, RU-644077 Omsk (Russian Federation)

    2005-11-01

    A dynamical interpretation of the well-known systematics for average total kinetic energy of fission fragments over a wide range of the Coulomb parameter (600 on the Coulomb parameter. The results of dynamical calculations of within three-dimensional Langevin dynamics show that the mean distance between the centers of mass of nascent fragments at the scission configuration increases linearly with the parameter Z{sup 2}/A{sup 1/3}. This distance changes approximately from 2.35R{sub 0} for {sup 119}Xe to 2.6R{sub 0} for {sup 256}Fm. In spite of this increase in mean distance between future fragments at scission, the linear dependence of on the parameter Z{sup 2}/A{sup 1/3} remains approximately valid over a wide range of the Coulomb parameter Z{sup 2}/A{sup 1/3}.

  13. The impact of high-frequency sedimentation cycles on stratigraphic interpretation

    SciTech Connect (OSTI)

    Perlmutter, M.A.; Radovich, B.J.; Matthews, M.D.

    1997-01-01

    Global cyclostratigraphy, a methodology that utilizes climate change to evaluate sediment flux, characterizes the impact of sediment cycles on stratigraphy. Climatic succession, sediment yield cycles, and the phase relationship of sediment cycles to eustatic cycles are all determined in the early stages of basin analysis. Sedimentologic information is then used to assist in sequence evaluations. Climatic successions are intrinsically associated with global position (paleogeography) and are not necessarily synchronous with glacioeustatic sea-level cycles. A preliminary evaluation of the effect of climate on sediment supply from modem river systems indicates that sediment yield may vary by well over two orders of magnitude during one climate cycle. Consequently, basins in different climatic belts can have distinctly different volumes and lithologies for systems tracts that have similar base-level changes. The stratigraphic computer program Sedpak was utilized to examine the possible impact of different sedimentation cycles on sequence interpretation and reservoir forecasts. The effect of sedimentation cycles on reservoir distribution in real world sequences is demonstrated with a comparison of the Miocene section of the Surma basin, Bangladesh, and the Plio-Pleistocene section of the Gulf of Mexico. In the Surma basin, reservoirs are most likely to occur in transgressive and highstand systems tracts, while reservoirs in the Gulf of Mexico are more likely in lowstand prograding complexes.

  14. Simple interpretation of nuclear orientation for Coulomb barrier distributions derived from a realistic effective interaction

    SciTech Connect (OSTI)

    Ismail, M.; Seif, W. M.

    2010-03-15

    A simple straightforward method has been presented to predict the dependence of barrier distributions at arbitrary orientations on different deformations. The proposed interpretation is developed independently of the complicated numerical calculations. It is related to the change of half-density radius of the deformed nucleus, in the direction of the separation vector. The microscopic calculations of Coulomb barrier are carried out by using a realistic density dependent nucleon-nucleon (NN) interaction, BDM3Y, for the interaction between spherical, {sup 48}Ca, and deformed, {sup 244}Pu, nuclei, as an example. To do so, the double-folding model for the interaction of spherical-deformed nuclei is put in a suitable computational form for the calculation of the potential at several separation distances and orientation angles using the density dependent NN force without consuming computational time. We found that the orientation distributions of the Coulomb barrier parameters show similar patterns to those of the interacting deformed nucleus radius. It is found that the orientation distribution of the Coulomb barrier radius follows the same variation of the deformed nucleus radius while the barrier height distribution follows it inversely. This correlation (anticorrelation) allows a simple evaluation of the orientation barrier distribution which would be very helpful to estimate when the barrier parameters will increase or decrease and at which orientations they will be independent of the deformation. This also allows us to estimate the compact and elongated configurations of the interacting nuclei which lead to hot and cold fusion, respectively.

  15. HoravaLifshitz cosmology, entropic interpretation and quarkhadron phase transition

    SciTech Connect (OSTI)

    Kheyri, F. Khodadi, M. Sepangi, Hamid Reza

    2013-05-15

    Based on the assumptions of the standard model of cosmology, a phase transition associated with chiral symmetry breaking after the electroweak transition has occurred at approximately 10 ?s after the Big Bang to convert a plasma of free quarks and gluons into hadrons. We consider such a phase transition in the context of a deformed HoravaLifshitz cosmology. The Friedmann equation for the deformed HoravaLifshitz universe is obtained using the entropic interpretation of gravity, proposed by Verlinde. We investigate the effects of the parameter ? appearing in the theory on the evolution of the physical quantities relevant to a description of the early universe, namely, the energy density and temperature before, during and after the phase transition. Finally, we study the cross-over phase transition in both high and low temperature regions in view of the recent lattice QCD simulations data. -- Highlights: ? We study the problem of the quarkhadron phase transition in the early universe, in the context of HoravaLifshitz cosmology. ? We conduct this study by including the recently introduced entropic principle. ? We study the behavior of thermodynamical parameters of the theory.

  16. Integrating 3D seismic curvature and curvature gradient attributes for fracture characterization: Methodologies and interpretational implications

    SciTech Connect (OSTI)

    Gao, Dengliang

    2013-03-01

    In 3D seismic interpretation, curvature is a popular attribute that depicts the geometry of seismic reflectors and has been widely used to detect faults in the subsurface; however, it provides only part of the solutions to subsurface structure analysis. This study extends the curvature algorithm to a new curvature gradient algorithm, and integrates both algorithms for fracture detection using a 3D seismic test data set over Teapot Dome (Wyoming). In fractured reservoirs at Teapot Dome known to be formed by tectonic folding and faulting, curvature helps define the crestal portion of the reservoirs that is associated with strong seismic amplitude and high oil productivity. In contrast, curvature gradient helps better define the regional northwest-trending and the cross-regional northeast-trending lineaments that are associated with weak seismic amplitude and low oil productivity. In concert with previous reports from image logs, cores, and outcrops, the current study based on an integrated seismic curvature and curvature gradient analysis suggests that curvature might help define areas of enhanced potential to form tensile fractures, whereas curvature gradient might help define zones of enhanced potential to develop shear fractures. In certain fractured reservoirs such as at Teapot Dome where faulting and fault-related folding contribute dominantly to the formation and evolution of fractures, curvature and curvature gradient attributes can be potentially applied to differentiate fracture mode, to predict fracture intensity and orientation, to detect fracture volume and connectivity, and to model fracture networks.

  17. Interpretation of Scanning Tunneling Quasiparticle Interference and Impurity States in Cuprates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kreisel, A.; Choubey, P.; Berlijn, T.; Ku, W.; Andersen, B. M.; Hirschfeld, P. J.

    2015-05-27

    We apply a recently developed method combining first principles based Wannier functions with solutions to the Bogoliubov-de Gennes equations to the problem of interpreting STM data in cuprate superconductors. We show that the observed images of Zn on the surface of Bi2Sr2CaCu2O8 can only be understood by accounting for the tails of the Cu Wannier functions, which include significant weight on apical O sites in neighboring unit cells. This calculation thus puts earlier crude “filter” theories on a microscopic foundation and solves a long standing puzzle. We then study quasiparticle interference (QPI) phenomena induced by out-of-plane weak potential scatterers, andmore » show how patterns long observed in cuprates can be understood in terms of the interference of Wannier functions above the surface. Our results show excellent agreement with experiment and enable a better understanding of novel phenomena in the cuprates via STM imaging.« less

  18. Interpretation of scanning tunneling quasiparticle interference and impurity states in cuprates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kreisel, Andreas; Choubey, Peayush; Berlijn, Tom; Ku, W.; Andersen, Brian M.; Hirschfeld, Peter J.

    2015-05-27

    We apply a recently developed method combining first principles based Wannier functions with solutions to the Bogoliubov–de Gennes equations to the problem of interpreting STM data in cuprate superconductors. We show that the observed images of Zn on the surface of Bi2Sr2CaCu2O8 can only be understood by accounting for the tails of the Cu Wannier functions, which include significant weight on apical O sites in neighboring unit cells. This calculation thus puts earlier crude “filter” theories on a microscopic foundation and solves a long-standing puzzle. We then study quasiparticle interference phenomena induced by out-of-plane weak potential scatterers, and show howmore » patterns long observed in cuprates can be understood in terms of the interference of Wannier functions above the surface. Furthermore, our results show excellent agreement with experiment and enable a better understanding of novel phenomena in the cuprates via STM imaging.« less

  19. Benthic foraminifera of Puerto Rican mangrove-lagoon systems: Potential for paleoenvironmental interpretations

    SciTech Connect (OSTI)

    Culver, S.J. )

    1990-02-01

    Recent foraminiferal assemblages from four traverses across mangrove-lagoonal environments off Puerto Rico exhibit patterns of distribution that should be useful in paleoenvironmental interpretations. Variations in sediment substrate type, abundance and distribution of marine vegetation, and degree of exposure to wave and current activity appear to be important factors related to foraminiferal distributions and abundances. Cluster analysis of foraminiferal abundance data distinguishes four major assemblages. Other generally recognizable trends in foraminiferal assemblages include: offshore increase in species diversity; offshore increase in percent miliolids while percent rotaliids remain more or less constant; small peaks in percent textulariids immediately adjacent to mangrove growth; almost 100% agglutinated assemblages in fully mangrove environments; offshore increase in foraminiferal number except in areas of abundant Halimeda plate production where numbers of foraminifera are diluted; restriction of high abundances of Fissurina, Nonionella, Fursenkoina and Helenina to lagoons behind mangrove islands; restrictions of high abundances of Rosalina, Cibicides, Discorbis, Spiroloculina, Cyclogyra, Quinqueloculina, Amphistegina, Peneroplis and Archaias to lagoons seaward of mangrove islands. These trends provide a micropaleontological link between a potential petroleum source, mangrove swamps, and the potential petroleum reservoir, reef rocks.

  20. Automated method for the systematic interpretation of resonance peaks in spectrum data

    DOE Patents [OSTI]

    Damiano, B.; Wood, R.T.

    1997-04-22

    A method is described for spectral signature interpretation. The method includes the creation of a mathematical model of a system or process. A neural network training set is then developed based upon the mathematical model. The neural network training set is developed by using the mathematical model to generate measurable phenomena of the system or process based upon model input parameter that correspond to the physical condition of the system or process. The neural network training set is then used to adjust internal parameters of a neural network. The physical condition of an actual system or process represented by the mathematical model is then monitored by extracting spectral features from measured spectra of the actual process or system. The spectral features are then input into said neural network to determine the physical condition of the system or process represented by the mathematical model. More specifically, the neural network correlates the spectral features (i.e. measurable phenomena) of the actual process or system with the corresponding model input parameters. The model input parameters relate to specific components of the system or process, and, consequently, correspond to the physical condition of the process or system. 1 fig.

  1. Automated method for the systematic interpretation of resonance peaks in spectrum data

    DOE Patents [OSTI]

    Damiano, Brian; Wood, Richard T.

    1997-01-01

    A method for spectral signature interpretation. The method includes the creation of a mathematical model of a system or process. A neural network training set is then developed based upon the mathematical model. The neural network training set is developed by using the mathematical model to generate measurable phenomena of the system or process based upon model input parameter that correspond to the physical condition of the system or process. The neural network training set is then used to adjust internal parameters of a neural network. The physical condition of an actual system or process represented by the mathematical model is then monitored by extracting spectral features from measured spectra of the actual process or system. The spectral features are then input into said neural network to determine the physical condition of the system or process represented by the mathematical. More specifically, the neural network correlates the spectral features (i.e. measurable phenomena) of the actual process or system with the corresponding model input parameters. The model input parameters relate to specific components of the system or process, and, consequently, correspond to the physical condition of the process or system.

  2. Using the depth-velocity-size diagram to interpret equilibrium bed configurations in river flows

    SciTech Connect (OSTI)

    Southard, J.B. (Massachusetts Institute of Technology, Cambridge, MA (USA))

    1990-05-01

    Data from flume studies that report equilibrium bed configuration as well as water temperature, flow depth, flow velocity, and sediment size were used to develop the best approximation to the relationships among the various bed phases (ripples, dunes, lower regime plane bed, upper regime plane bed, and antidunes) in a three-axis graph (depth-velocity-size diagram) with dimensionless measures of mean flow depth, mean flow velocity, and sediment size along the axis. Relationships are shown in a series of depth-velocity and velocity-size sections through the diagram. Boundaries between bed-phase stability fields are drawn as surfaces that minimize, misplacement of data points. A large subset of the data, for which reliable values of bed shear stress are reported, was also used to represent the stability relationships in a graph of dimensionless boundary shear stress against dimensionless sediment size, but with results less useful for fluvial flow interpretation. The diagram covers about one order of magnitude in flow depth. To be useful for river flows, the diagram must be extrapolated in flow depth by about one more order of magnitude, but this is not a serious problem for approximate work. The depth-velocity-size diagram permits prediction of equilibrium bed configuration in river flows when the approximate flow depth and mean flow velocity are known. Because the diagram is essentially dimensionless, the effect of water temperature (via the fluid viscosity) on the bed configuration is easily accounted for by use of the diagram.

  3. Galvanic interpretation of self-potential signals associated withmicrobial sulfate-reduction

    SciTech Connect (OSTI)

    Williams, Kenneth H.; Hubbard, Susan S.; Banfield, Jillian F.

    2007-05-02

    We have evaluated the usefulness of the self-potential (SP)geophysical method to track the onset and location of microbialsulfate-reduction in saturated sediments during organic carbon amendment.Following stimulation of sulfate-reducing bacteria (SRB) by addition oflactate, anomalous voltages exceeding 600 mV correlated in space and timewith the accumulation of dissolved sulfide. Abiotic experiments in whichthe sulfide concentration at the measurement electrode was systematicallyvaried showed a positive correlation between the magnitude of the SPanomaly and differences in the half-cell potential associated with themeasurement and reference electrodes. Thus, we infer that the SPanomaliesresulted from electrochemical differences that developedbetween sulfide-rich regions and areas having higher oxidation potential.In neither experiment did generation of an SP anomaly require thepresence of an in situ electronic conductor, as is required by othermodels. These findings emphasize the importance of incorporation ofelectrochemical effects at electrode surfaces in interpretation of SPdata from geophysical studies. We conclude that SP measurements provide aminimally invasive means for monitoring stimulated sulfate-reductionwithin saturated sediments.

  4. Geochemical Techniques | Open Energy Information

    Open Energy Info (EERE)

    Geothermometers Multicomponent Geothermometers Silica Geothermometers Thermal Ion Dispersion Thermochronometry References General References Technical References No exploration...

  5. Blind Geothermal System Exploration in Active Volcanic Environments; Multi-phase Geophysical and Geochemical Surveys in Overt and Subtle Volcanic Systems, Hawai’i and Maui

    SciTech Connect (OSTI)

    Fercho, Steven; Owens, Lara; Walsh, Patrick; Drakos, Peter; Martini, Brigette; Lewicki, Jennifer L.; Kennedy, Burton M.

    2015-08-01

    Suites of new geophysical and geochemical exploration surveys were conducted to provide evidence for geothermal resource at the Haleakala Southwest Rift Zone (HSWRZ) on Maui Island, Hawai’i. Ground-based gravity (~400 stations) coupled with heli-bourne magnetics (~1500 line kilometers) define both deep and shallow fractures/faults, while also delineating potentially widespread subsurface hydrothermal alteration on the lower flanks (below approximately 1800 feet a.s.l.). Multi-level, upward continuation calculations and 2-D gravity and magnetic modeling provide information on source depths, but lack of lithologic information leaves ambiguity in the estimates. Additionally, several well-defined gravity lows (possibly vent zones) lie coincident with magnetic highs suggesting the presence of dike intrusions at depth which may represent a potentially young source of heat. Soil CO2 fluxes were measured along transects across geophysically-defined faults and fractures as well as young cinder cones along the HSWRZ. This survey generally did not detect CO2 levels above background, with the exception of a weak anomalous flux signal over one young cinder cone. The general lack of observed CO2 flux signals on the HSWRZ is likely due to a combination of lower magmatic CO2 fluxes and relatively high biogenic surface CO2 fluxes which mix with the magmatic signal. Similar surveys at the Puna geothermal field on the Kilauea Lower East Rift Zone (KLERZ) also showed a lack of surface CO2 flux signals, however aqueous geochemistry indicated contribution of magmatic CO2 and He to shallow groundwater here. As magma has been intercepted in geothermal drilling at the Puna field, the lack of measured surface CO2 flux indicative of upflow of magmatic fluids here is likely due to effective “scrubbing” by high groundwater and a mature hydrothermal system. Dissolved inorganic carbon (DIC) concentrations, δ13C compositions and 3He/4He values were sampled at Maui from several shallow groundwater samples indicating only minor additions of magmatic CO2 and He to the groundwater system, although much less than observed near Puna. The much reduced DIC and He abundances at Maui, along with a lack of hotsprings and hydrothermal alteration, as observed near Puna, does not strongly support a deeper hydrothermal system within the HSWRZ.

  6. A Comprehensive Statistically-Based Method to Interpret Real-Time Flowing Measurements

    SciTech Connect (OSTI)

    Keita Yoshioka; Pinan Dawkrajai; Analis A. Romero; Ding Zhu; A. D. Hill; Larry W. Lake

    2007-01-15

    With the recent development of temperature measurement systems, continuous temperature profiles can be obtained with high precision. Small temperature changes can be detected by modern temperature measuring instruments such as fiber optic distributed temperature sensor (DTS) in intelligent completions and will potentially aid the diagnosis of downhole flow conditions. In vertical wells, since elevational geothermal changes make the wellbore temperature sensitive to the amount and the type of fluids produced, temperature logs can be used successfully to diagnose the downhole flow conditions. However, geothermal temperature changes along the wellbore being small for horizontal wells, interpretations of a temperature log become difficult. The primary temperature differences for each phase (oil, water, and gas) are caused by frictional effects. Therefore, in developing a thermal model for horizontal wellbore, subtle temperature changes must be accounted for. In this project, we have rigorously derived governing equations for a producing horizontal wellbore and developed a prediction model of the temperature and pressure by coupling the wellbore and reservoir equations. Also, we applied Ramey's model (1962) to the build section and used an energy balance to infer the temperature profile at the junction. The multilateral wellbore temperature model was applied to a wide range of cases at varying fluid thermal properties, absolute values of temperature and pressure, geothermal gradients, flow rates from each lateral, and the trajectories of each build section. With the prediction models developed, we present inversion studies of synthetic and field examples. These results are essential to identify water or gas entry, to guide flow control devices in intelligent completions, and to decide if reservoir stimulation is needed in particular horizontal sections. This study will complete and validate these inversion studies.

  7. Waste Isolation Pilot Plant simulated RH TRU waste experiments: Data and interpretation pilot

    SciTech Connect (OSTI)

    Molecke, M.A.; Argueello, G.J.; Beraun, R.

    1993-04-01

    The simulated, i.e., nonradioactive remote-handled transuranic waste (RH TRU) experiments being conducted underground in the Waste Isolation Pilot Plant (WIPP) were emplaced in mid-1986 and have been in heated test operation since 9/23/86. These experiments involve the in situ, waste package performance testing of eight full-size, reference RH TRU containers emplaced in horizontal, unlined test holes in the rock salt ribs (walls) of WIPP Room T. All of the test containers have internal electrical heaters; four of the test emplacements were filled with bentonite and silica sand backfill materials. We designed test conditions to be ``near-reference`` with respect to anticipated thermal outputs of RH TRU canisters and their geometrical spacing or layout in WIPP repository rooms, with RH TRU waste reference conditions current as of the start date of this test program. We also conducted some thermal overtest evaluations. This paper provides a: detailed test overview; comprehensive data update for the first 5 years of test operations; summary of experiment observations; initial data interpretations; and, several status; experimental objectives -- how these tests support WIPP TRU waste acceptance, performance assessment studies, underground operations, and the overall WIPP mission; and, in situ performance evaluations of RH TRU waste package materials plus design details and options. We provide instrument data and results for in situ waste container and borehole temperatures, pressures exerted on test containers through the backfill materials, and vertical and horizontal borehole-closure measurements and rates. The effects of heat on borehole closure, fracturing, and near-field materials (metals, backfills, rock salt, and intruding brine) interactions were closely monitored and are summarized, as are assorted test observations. Predictive 3-dimensional thermal and structural modeling studies of borehole and room closures and temperature fields were also performed.

  8. Definition and interpretation of Holocene shorelines in the south Atlantic coastal zone, southeast Florida

    SciTech Connect (OSTI)

    Finkl, C.W. Jr.

    1985-01-01

    There is a wide variety of contemporary shorelines in southeastern Florida. Distinctive types range from rocky platforms, tidal flats, mangroves and marshes, to sand and gravel beaches. Because the natural sequence of shorelines in the urban coastal corridor from Miami to Palm Beach is partly obscured by dredge and fill operations initiated in the early 1920's, some coastal segments are subject to re-interpretation. Analysis of early aerial photographs, old coastal charts and bore log data indicates a much more complicated sequence of Recent coastlines than is generally appreciated. Before development, much of the coastal zone contained complicated networks of fresh-water marshes and lakes with lagoons, bays, and sounds lying behind extensively developed spits. The larger spits prograded southward (downdrift) forming long coastwise sounds that eventually led into fresh-water marshes such as Lake Mabel (now Port Everglades). When new inlets were cut to link the ICW with the sea, the spits were beheaded to form what are now called barrier islands. After subsequent inlet stabilization with inadequate sand bypassing, some spits became welded to the shore and others eroded away. Extension of boundaries marking the back sides of barriers landward into the marshes, to the position of the ICW, is not only an erroneous definition of barrier island width but dangerous for emergency (storm surge) planning because the barriers were never this wide. Beach ridge plains, ridge and swale topography, dune-covered limestone ridges, and some fossil reefs such as Key Biscayne have in addition been mistakenly identified as barrier islands.

  9. Biothems: Sequence stratigraphic units and their implications for regional tectono-stratigraphic interpretations

    SciTech Connect (OSTI)

    Lane, H.R. ); Frye, M.W. ); Couples, G.D. )

    1992-01-01

    Biothems are regional wedge- or lens-shaped bodies of strata that are bounded shelfward or cratonward by paleontologically recognizable unconformities; generally thicken on marine shelves, where they are typically conformable with underlying and overlying biothems; are commonly thinner or represent starved sequences further basinward; and in their most basinward extent, are either bounded by biostratigraphically recognizable unconformities or are conformable with underlying and overlying biothems. As recognized to date, biothems have a logical distribution of faunal and floral components, as well as facies groupings that represent internally consistent and logical sequences of depositional environments. A west-to-east transect within the North American Mississippian System which extends from the Basin and Range Province, across the Transcontinental Arch (TA), into the Anadarko Basin, was constructed to demonstrate the regional distribution and tectono-stratigraphic significance of biothems relative to the axis of the TA. The relationships portrayed on the transect, tied to an understanding of North American Mississippian paleogeography, imply that biothems deposited during relative highstand events on one flank of the TA are time-equivalent to biothems deposited during relative lowstand events on the opposite flank of the TA. This distribution is interpreted to have been controlled by intraplate tectonic events that formed piano key basins along the flanks of the TA. The spatial patterns of these basins are not consistent with published models of basin evolution. A further conclusion is that the lack of coincident, transgressive or regressive Mississippian biothems on either flank of the TA suggests that it is inadvisable to impose the Mississippi Valley-derived eustasy curve on western flank depositional sequences.

  10. AN INTERPRETATION OF GLE71 CONCURRENT CME-DRIVEN SHOCK WAVE

    SciTech Connect (OSTI)

    Firoz, Kazi A.; Rodrguez-Pacheco, J.; Zhang, Q. M.; Gan, W. Q.; Li, Y. P.; Moon, Y.-J.; Kudela, K.; Park, Y.-D.; Dorman, Lev I. E-mail: firoz.kazi@uah.es

    2014-08-01

    Particle accelerations in solar flares and CME-driven shocks can sometimes result in very high-energy particle events (?1 GeV) that are known as ground level enhancements (GLEs). Recent studies on the first GLE event (GLE71 2012 May 17 01:50 UT) of solar cycle 24 suggested that CME-driven shock played a leading role in causing the event. To verify this claim, we have made an effort to interpret the GLE71 concurrent shock wave. For this, we have deduced the possible speed and height of the shock wave in terms of the frequency (MHz) of the solar radio type II burst and its drift rate (MHz min{sup 1}), and studied the temporal evolution of the particle intensity profiles at different heights of the solar corona. For a better perception of the particle acceleration in the shock, we have studied the solar radio type II burst with concurrent solar radio and electron fluxes. When the particle intensity profiles are necessarily shifted in time at ?1 AU, it is found that the growth phases of the electron and cosmic ray intensity fluxes are strongly correlated (>0.91; ?0.87) with the frequency drift rate of the type II burst, which is also consistent with the intensive particle accelerations at upper coronal heights (??0.80 R {sub S} < 1.10 R {sub S}). Thus, we conclude that the CME-driven shock was possibly capable of producing the high-energy particle event. However, since the peaks of some flare components are found to be strongly associated with the fundamental phase of the type II burst, the preceding flare is supposed to contribute to the shock acceleration process.

  11. Models to interpret bed-form geometries from cross-bed data

    SciTech Connect (OSTI)

    Luthi, S.M. (Schlumberger-Doll Research, Ridgefield, CT (USA)); Banavar, J.R. (Pennsylvania State Univ., University Park (USA)); Bayer, U. (Institute Erdoel und Organische Chemie, Kernforschungsanlage Juelich (West Germany))

    1990-05-01

    To improve the understanding of the relation of cross-bed azimuth distributions to bed-forms, geometric models were developed for migrating bed forms using a minimum number of parameters. Semielliptical and sinusoidal bed-form crestlines were modeled with curvature and sinuosity as parameters. Both bedform crestlines are propagated at various angles of migration over a finite area of deposition. Two computational approaches are used, a statistical random sampling (Monte Carlo) technique over the area of the deposit, and an analytical method based on topology and differential geometry. The resulting foreset azimuth distributions provide a catalog for a variety of simulations. The resulting thickness distributions have a simple shape and can be combined with the azimuth distributions to further constrain the cross-strata geometry. Paleocurrent directions obtained by these models can differ substantially from other methods, especially for obliquely migrating low-curvature bed forms. Interpretation of foreset azimuth data from outcrops and wells can be done either by visual comparison with the cataloged distributions, or by iterative computational fits. Studied examples include eolian cross-strata from the Permian Rotliegendes in the North Sea, fluvial dunes from the Devonian in the Catskills (New York state), the Triassic Schilfsandstein (Federal Republic of Germany), and the Paleozoic-Jurassic of the Western Desert (Egypt), as well as recent tidal dunes from the German coast of the North Sea and tidal cross-strata from the Devonian Koblentzquartzit (Federal Republic of Germany). In all cases the semi-elliptical bed-form model gave a good fit to the data, suggesting that it may be applicable over a wide range of bed forms. The data from the Western Desert could be explained only by data scatter due to channel sinuosity combined with the scatter attributed to the ellipticity of the bed-form crestlines.

  12. Restoration of geological surface-UNFOLD method-a validation of complex structural mapping interpretation in the Andean Thrust Belt

    SciTech Connect (OSTI)

    Guillier, B. ); Oller, J.; Mendez, E.; Leconte, J.C.; Letouzey, J.; Specht, M.; Gratier, J.P.

    1993-02-01

    One of the most important problems in petroleum structural geology is dependable interpretation of structural maps obtained by seismic and sub-surface data. One method for validating the geometry of geological structures is the balancing cross-section technique which allows verification of cross-section geometry by a return to its initial horizontal state. However, this can not be used for of 3D halokinesis, shale tectonics, structures formed by polyphased noncoaxial tectonic events, or strike-slip and wrench faulting. An alternative approach is to test the restoration of folded and faulted surfaces to verify 3D structures by balancing geological surfaces represented by a structural map. This method tests the geometry of studied horizon and faults and is based upon the fact that, initially, actual folded/faulted structures were continuous at deposition. The balancing surface program, UNFOLD, restores the actual geological surface to its initial state. Misfits along faults implied poor structural map drawings or strong internal deformation of the geological level. By trial and error method, we returned to the initial data interpretation modifications. This method has been applied to 2D and 3D seismic structural interpretation in different structural styles, environments, rift zones, salt basins, wrench faulting, thrust belt,etc. Some applications to oil field structures in the Andean Thrust Belt have been done to check and validate the complex structural mapping interpretation.

  13. The effect of rotation and viscous heating on the interpretation of experimental heat diffusivities in the edge pedestal

    SciTech Connect (OSTI)

    Stacey, Weston M.

    2010-05-15

    A formalism is presented for evaluating the effect of plasma rotation, via viscous heating, on the interpretation of thermal conductivities from measured temperature and density gradients in the edge pedestal. An application to a H-mode DIII-D [J. Luxon, Nucl. Fusion 42, 614 (2002)] discharge indicates that the effect could be significant.

  14. CX-013749: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Geochemical Evaluation of Double Layered BSRs on the Hikurangi Margin, NZ CX(s) Applied: A9, B3.1, B3.6Date: 03/16/2015 Location(s): District of ColumbiaOffices(s): National Energy Technology Laboratory

  15. CX-013472: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Geochemical Evaluation of Double Layered BSR's on the Hikurangi Margin, New Zealand CX(s) Applied: A9, B3.1, B3.6Date: 03/16/2015 Location(s): District of ColumbiaOffices(s): National Energy Technology Laboratory

  16. CX-010941: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Assessing the Response of Methane Hydrates to Environmental Change at the Svalbard Continental Margin CX(s) Applied: B3.6, Other: Biological & Geochemical Analysis-Lab Date: 09/17/2013 Location(s): Oregon Offices(s): National Energy Technology Laboratory

  17. CX-100598 Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Comprehensive analysis of Hawaii's geothermal potential through Play Fairway integration of geophysical, geochemical, and geological data Award Number: DE-EE0006729 CX(s) Applied: A9, B3.1, B3.6 Geothermal Technologies Office Date: 04/25/2016 Location(s): HI Office(s): Golden Field Office

  18. Dose impact in radiographic lung injury following lung SBRT: Statistical analysis and geometric interpretation

    SciTech Connect (OSTI)

    Yu, Victoria; Kishan, Amar U.; Cao, Minsong; Low, Daniel; Lee, Percy; Ruan, Dan

    2014-03-15

    Purpose: To demonstrate a new method of evaluating dose response of treatment-induced lung radiographic injury post-SBRT (stereotactic body radiotherapy) treatment and the discovery of bimodal dose behavior within clinically identified injury volumes. Methods: Follow-up CT scans at 3, 6, and 12 months were acquired from 24 patients treated with SBRT for stage-1 primary lung cancers or oligometastic lesions. Injury regions in these scans were propagated to the planning CT coordinates by performing deformable registration of the follow-ups to the planning CTs. A bimodal behavior was repeatedly observed from the probability distribution for dose values within the deformed injury regions. Based on a mixture-Gaussian assumption, an Expectation-Maximization (EM) algorithm was used to obtain characteristic parameters for such distribution. Geometric analysis was performed to interpret such parameters and infer the critical dose level that is potentially inductive of post-SBRT lung injury. Results: The Gaussian mixture obtained from the EM algorithm closely approximates the empirical dose histogram within the injury volume with good consistency. The average Kullback-Leibler divergence values between the empirical differential dose volume histogram and the EM-obtained Gaussian mixture distribution were calculated to be 0.069, 0.063, and 0.092 for the 3, 6, and 12 month follow-up groups, respectively. The lower Gaussian component was located at approximately 70% prescription dose (35 Gy) for all three follow-up time points. The higher Gaussian component, contributed by the dose received by planning target volume, was located at around 107% of the prescription dose. Geometrical analysis suggests the mean of the lower Gaussian component, located at 35 Gy, as a possible indicator for a critical dose that induces lung injury after SBRT. Conclusions: An innovative and improved method for analyzing the correspondence between lung radiographic injury and SBRT treatment dose has been demonstrated. Bimodal behavior was observed in the dose distribution of lung injury after SBRT. Novel statistical and geometrical analysis has shown that the systematically quantified low-dose peak at approximately 35 Gy, or 70% prescription dose, is a good indication of a critical dose for injury. The determined critical dose of 35 Gy resembles the critical dose volume limit of 30 Gy for ipsilateral bronchus in RTOG 0618 and results from previous studies. The authors seek to further extend this improved analysis method to a larger cohort to better understand the interpatient variation in radiographic lung injury dose response post-SBRT.

  19. Surface speciation of yttrium and neodymium sorbed on rutile: Interpretations using the change distribution model.

    SciTech Connect (OSTI)

    Ridley, Mora K.; Hiemstra, T; Machesky, Michael L.; Wesolowski, David J; Van Riemsdijk, Willem H.

    2012-01-01

    The adsorption of Y3+ and Nd3+ onto rutile has been evaluated over a wide range of pH (3 11) and surface loading conditions, as well as at two ionic strengths (0.03 and 0.3 m), and temperatures (25 and 50 C). The experimental results reveal the same adsorption behavior for the two trivalent ions onto the rutile surface, with Nd3+ first adsorbing at slightly lower pH values. The adsorption of both Y3+ and Nd3+ commences at pH values below the pHznpc of rutile. The experimental results were evaluated using a charge distribution (CD) and multisite complexation (MUSIC) model, and Basic Stern layer description of the electric double layer (EDL). The coordination geometry of possible surface complexes were constrained by molecular-level information obtained from X-ray standing wave measurements and molecular dynamic (MD) simulation studies. X-ray standing wave measurements showed an inner-sphere tetradentate complex for Y3+ adsorption onto the (110) rutile surface (Zhang et al., 2004b). TheMDsimulation studies suggest additional bidentate complexes may form. The CD values for all surface species were calculated based on a bond valence interpretation of the surface complexes identified by X-ray and MD. The calculated CD values were corrected for the effect of dipole orientation of interfacial water. At low pH, the tetradentate complex provided excellent fits to the Y3+ and Nd3+ experimental data. The experimental and surface complexation modeling results show a strong pH dependence, and suggest that the tetradentate surface species hydrolyze with increasing pH. Furthermore, with increased surface loading of Y3+ on rutile the tetradentate binding mode was augmented by a hydrolyzed-bidentate Y3+ surface complex. Collectively, the experimental and surface complexation modeling results demonstrate that solution chemistry and surface loading impacts Y3+ surface speciation. The approach taken of incorporating molecular-scale information into surface complexation models (SCMs) should aid in elucidating a fundamental understating of ion-adsorption reactions.

  20. Developing a robust geochemical and reactive transport model to evaluate possible sources of arsenic at the CO[subscript 2] sequestration natural analog site in Chimayo, New Mexico

    SciTech Connect (OSTI)

    Viswanathan, Hari; Dai, Zhenxue; Lopano, Christina; Keating, Elizabeth; Hakala, J. Alexandra; Scheckel, Kirk G.; Zheng, Liange; Gutherie, George D.; Pawar, Rajesh

    2012-10-24

    Migration of carbon dioxide (CO{sub 2}) from deep storage formations into shallow drinking water aquifers is a possible system failure related to geologic CO{sub 2} sequestration. A CO{sub 2} leak may cause mineral precipitation/dissolution reactions, changes in aqueous speciation, and alteration of pH and redox conditions leading to potential increases of trace metal concentrations above EPA National Primary Drinking Water Standards. In this study, the Chimayo site (NM) was examined for site-specific impacts of shallow groundwater interacting with CO{sub 2} from deep storage formations. Major ion and trace element chemistry for the site have been previously studied. This work focuses on arsenic (As), which is regulated by the EPA under the Safe Drinking Water Act and for which some wells in the Chimayo area have concentrations higher than the maximum contaminant level (MCL). Statistical analysis of the existing Chimayo groundwater data indicates that As is strongly correlated with trace metals U and Pb indicating that their source may be from the same deep subsurface water. Batch experiments and materials characterization, such as: X-ray diffraction (XRD), scanning electron microscopy (SEM), and synchrotron micro X-ray fluorescence ({mu}-XRF), were used to identify As association with Fe-rich phases, such as clays or oxides, in the Chimayo sediments as the major factor controlling As fate in the subsurface. Batch laboratory experiments with Chimayo sediments and groundwater show that pH decreases as CO{sub 2} is introduced into the system and buffered by calcite. The introduction of CO{sub 2} causes an immediate increase in As solution concentration, which then decreases over time. A geochemical model was developed to simulate these batch experiments and successfully predicted the pH drop once CO{sub 2} was introduced into the experiment. In the model, sorption of As to illite, kaolinite and smectite through surface complexation proved to be the key reactions in simulating the drop in As concentration as a function of time in the batch experiments. Based on modeling, kaolinite precipitation is anticipated to occur during the experiment, which allows for additional sorption sites to form with time resulting in the slow decrease in As concentration. This mechanism can be viewed as trace metal 'scavenging' due to sorption caused secondary mineral precipitation. Since deep geologic transport of these trace metals to the shallow subsurface by brine or CO{sub 2} intrusion is critical to assessing environmental impacts, the effective retardation of trace metal transport is an important parameter to estimate and it is dependent on multiple coupled reactions. At the field scale, As mobility is retarded due to the influence of sorption reactions, which can affect environmental performance assessment studies of a sequestration site.

  1. Novel imaging techniques, integrated with mineralogical, geochemical and microbiological characterizations to determine the biogeochemical controls on technetium mobility in FRC sediments

    SciTech Connect (OSTI)

    Jonathan R. Lloyd

    2009-02-03

    The objective of this research program was to take a highly multidisciplinary approach to define the biogeochemical factors that control technetium (Tc) mobility in FRC sediments. The aim was to use batch and column studies to probe the biogeochemical conditions that control the mobility of Tc at the FRC. Background sediment samples from Area 2 (pH 6.5, low nitrate, low {sup 99}Tc) and Area 3 (pH 3.5, high nitrate, relatively high {sup 99}Tc) of the FRC were selected (http://www.esd.ornl.gov/nabirfrc). For the batch experiments, sediments were mixed with simulated groundwater, modeled on chemical constituents of FRC waters and supplemented with {sup 99}Tc(VII), both with and without added electron donor (acetate). The solubility of the Tc was monitored, alongside other biogeochemical markers (nitrate, nitrite, Fe(II), sulfate, acetate, pH, Eh) as the 'microcosms' aged. At key points, the microbial communities were also profiled using both cultivation-dependent and molecular techniques, and results correlated with the geochemical conditions in the sediments. The mineral phases present in the sediments were also characterized, and the solid phase associations of the Tc determined using sequential extraction and synchrotron techniques. In addition to the batch sediment experiments, where discrete microbial communities with the potential to reduce and precipitate {sup 99}Tc will be separated in time, we also developed column experiments where biogeochemical processes were spatially separated. Experiments were conducted both with and without amendments proposed to stimulate radionuclide immobilization (e.g. the addition of acetate as an electron donor for metal reduction), and were also planned with and without competing anions at high concentration (e.g. nitrate, with columns containing Area 3 sediments). When the columns had stabilized, as determined by chemical analysis of the effluents, we used a spike of the short-lived gamma emitter {sup 99m}Tc (50-200 MBq; half life 6 hours) and its mobility was monitored using a {gamma}-camera. Incorporation of low concentrations of the long-lived 99Tc gave a tracer that can be followed by scintillation counting, should the metastable form of the radionuclide decay to below detection limits before the end of the experiment (complete immobilization or loss of the Tc from the column). After the Tc was reduced and immobilized, or passed through the system, the columns were dismantled carefully in an anaerobic cabinet and the pore water geochemistry and mineralogy of the columns profiled. Microbial community analysis was determined, again using molecular and culture-dependent techniques. Experimental results were also modeled using an established coupled speciation and transport code, to develop a predictive tool for the mobility of Tc in FRC sediments. From this multidisciplinary approach, we hoped to obtain detailed information on the microorganisms that control the biogeochemical cycling of key elements at the FRC, and we would also be able to determine the key factors that control the mobility of Tc at environmentally relevant concentrations at this site.

  2. A discussion on the interpretation and characterization of metafilms/metasurfaces: the two-dimensional equivalent of metamaterials

    SciTech Connect (OSTI)

    O'hara, John F; Azad, Abul K

    2008-01-01

    A metafilm (also referred to as a metasurface) is the surface equivalent of a metamaterial. More precisely, a metafilm is a surface distribution of suitable chosen electrically small scatterers. Metafilms are becoming popular as an alternative to full three-dimensional metamaterials. Unfortunately, many papers in the literature present incorrect interpretations and mischaracterizations of these metafilms. In fact, some of the characterizations presented in the literature result in non-unique parameters for a uniquely defined metafilm. In this paper we discuss an appropriate interpretation and characterization of metafilms and present a correct manner to characterize a metafilm. Additionally, we illustrate the error that results from an incorrect characterization of metafilms. We present various examples to emphasize these points. Finally we present a retrieval approach for determining the uniquely defined quantities (the electric and magnetic susceptibilities of its constituent scatterers) that characterize a metafilm.

  3. Microbiological, Geochemical and Hydrologic Processes Controlling Uranium Mobility: An Integrated Field Scale Subsurface Research Challenge Site at Rifle, Colorado, February 2011 to January 2012

    SciTech Connect (OSTI)

    Long, Philip E.; Banfield, Jill; Chandler, Darrell P.; Davis, James A.; Hettich, Bob; VerBerkmoes, Nathan; Jaffe, Peter R.; Kerkhof, Lee J.; Kukkadapu, Ravi K.; Lipton, Mary; Peacock, Aaron; Williams, Kenneth H.; Yabusaki, Steven B.

    2012-02-15

    The Rifle IFRC continued to make excellent progress during the last 12 months. As noted above, a key field experiment (Best Western) was performed during 2011 as a logical follow-on to the Super 8 field experiment preformed in 2010. In the Super 8 experiment, we successfully combined desorption and bioreduction and deployed a number of novel tracer techniques to enhance our ability to interpret the biogeochemistry of the experiment. In the Best Western experiment, we used the same experimental plot (Plot C) as was used for Super 8. The overarching objective of the Best Western field experiment was to compared the impacts of abiotic vs. biotic increases in alkalinity and to assess the mass of the sorbed pool of U(VI) at Rifle at the field scale. Both of these objectives were met. Preliminary analysis of the data indicate that the underlying biogeochemical data sets were obtained that will support a mechanistic understanding of the underlying processes, including remarkable insight into previously unrecognized microbial processes taking place during acetate amendment of the subsurface for a second time.

  4. Integrated model for the natural flow regime in the Cerro Prieto hydrothermal system, B. C. , Mexico, based upon petrological and isotope geochemical criteria

    SciTech Connect (OSTI)

    Elders, W.A.; Williams, A.E.; Hoagland, J.R.

    1981-01-01

    Studies of cuttings and core at Cerro Prieto have now been extended to more than 50 boreholes. The aims of this petrological and isotopic work are to determine the shape of the reservoir, its physical properties, and its temperature distribution and flow regime before the steam field was produced. A map showing the first occurrence of hydrothermal epidote shows a dome-shaped top to the steam-producing zone. The hottest of the mapped mineral zones - the biotite vermiculite zone - shows a dome displaced to the northeast relative to the epidote zone. Patterns of mineral zones observed in wells are consistent with patterns of oxygen isotopic ratios in calcite and quartz. Using both criteria all of the boreholes so far studied were classified as belonging to one of four different regimes. These are: (a) the thermal plume of upward flowing water close to boiling, marked by a regular sequence of prograde mineral zones and large isotopic shifts; (b) the discharge system where fluid leaks to the surface, as indicated by the occurrence of only a few low temperature mineral zones, which extend over large depth intervals with little isotope exchange; (c) the horizontal flow zone, in which boreholes penetrate reversals of both mineral zones and isotope shifts with increasing depth; and (d) the recharge zone where cold water is descending. Plotting these four types of boreholes on a map reveals a simple, consistent, pattern. This is interpreted to have been produced by a thermal plume dipping at 45/sup 0/ to the northeast.

  5. A survey of radiographers' confidence and self-perceived accuracy in frontline image interpretation and their continuing educational preferences

    SciTech Connect (OSTI)

    Neep, Michael J; Steffens, Tom; Owen, Rebecca; McPhail, Steven M

    2014-06-15

    The provision of a written comment on traumatic abnormalities of the musculoskeletal system detected by radiographers can assist referrers and may improve patient management, but the practice has not been widely adopted outside the United Kingdom. The purpose of this study was to investigate Australian radiographers' perceptions of their readiness for practice in a radiographer commenting system and their educational preferences in relation to two different delivery formats of image interpretation education, intensive and non-intensive. A cross-sectional web-based questionnaire was implemented between August and September 2012. Participants included radiographers with experience working in emergency settings at four Australian metropolitan hospitals. Conventional descriptive statistics, frequency histograms, and thematic analysis were undertaken. A Wilcoxon signed-rank test examined whether a difference in preference ratings between intensive and non-intensive education delivery was evident. The questionnaire was completed by 73 radiographers (68% response rate). Radiographers reported higher confidence and self-perceived accuracy to detect traumatic abnormalities than to describe traumatic abnormalities of the musculoskeletal system. Radiographers frequently reported high desirability ratings for both the intensive and the non-intensive education delivery, no difference in desirability ratings for these two formats was evident (z = 1.66, P = 0.11). Some Australian radiographers perceive they are not ready to practise in a frontline radiographer commenting system. Overall, radiographers indicated mixed preferences for image interpretation education delivered via intensive and non-intensive formats. Further research, preferably randomised trials, investigating the effectiveness of intensive and non-intensive education formats of image interpretation education for radiographers is warranted.

  6. DOE/SC0001389 Final technical report: Investigation of uranium attenuation and release at column and pore scales in response to advective geochemical gradients

    SciTech Connect (OSTI)

    Savage, Kaye S.; Zhu, Wenyi; Barnett, Mark O.

    2013-05-13

    Experimental approach Column experiments were devised to investigate the role of changing fluid composition on mobility of uranium through a sequence of geologic media. Fluids and media were chosen to be relevant to the ground water plume emanating from the former S-3 ponds at the Oak Ridge Integrated Field Research Challenge (ORIFC) site. Synthetic ground waters were pumped upwards at 0.05 mL/minute for 21 days through layers of quartz sand alternating with layers of uncontaminated soil, quartz sand mixed with illite, quartz sand coated with iron oxides, and another soil layer. Increases in pH or concentration of phosphate, bicarbonate, or acetate were imposed on the influent solutions after each 7 pore volumes while uranium (as uranyl) remained constant at 0.1mM. A control column maintained the original synthetic groundwater composition with 0.1mM U. Pore water solutions were extracted to assess U retention and release in relation to the advective ligand or pH gradients. Following the column experiments, subsamples from each layer were characterized using microbeam X-ray absorption spectroscopy (XANES) in conjunction with X-ray fluorescence mapping and compared to sediment core samples from the ORIFC, at SSRL Beam Line 2-3. Results U retention of 55 ?? 67 mg occurred in phosphate >pH >control >acetate >carbonate columns. The mass of U retained in the first-encountered quartz layer in all columns was highest and increased throughout the experiment. The rate of increase in acetate- and bicarbonate-bearing columns declined after ligand concentrations were raised. U also accumulated in the first soil layer; the pH-varied column retained most, followed by the increasing-bicarbonate column. The mass of U retained in the upper layers was far lower. Speciation of U, interpreted from microbeam XANES spectra and XRF maps, varied within and among the columns. Evidence of minor reduction to U(IV) was observed in the first-encountered quartz layer in the phosphate, bicarbonate, and pH columns while only U(VI) was observed in the control and acetate columns. In the soil layer, the acetate and bicarbonate columns both indicate minor reduction to U(IV), but U(VI) predominated in all columns. In the ORIFC soils, U was consistently present as U(VI); sorption appears to be the main mechanism of association for U present with Fe and/or Mn, while U occurring with P appears in discrete particles consistent with a U mineral phase. U in soil locations with no other elemental associations shown by XRF are likely uranium oxide phases.

  7. Interpretation of Colloid-Homologue Tracer Test 10-03, Including Comparisons to Test 10-01

    SciTech Connect (OSTI)

    Reimus, Paul W.

    2012-06-26

    This presentation covers the interpretations of colloid-homologue tracer test 10-03 conducted at the Grimsel Test Site, Switzerland, in 2010. It also provides a comparison of the interpreted test results with those of tracer test 10-01, which was conducted in the same fracture flow system and using the same tracers than test 10-03, but at a higher extraction flow rate. A method of correcting for apparent uranine degradation in test 10-03 is presented. Conclusions are: (1) Uranine degradation occurred in test 10-03, but not in 10-01; (2) Uranine correction based on apparent degradation rate in injection loop in test 11-02 seems reasonable when applied to data from test 10-03; (3) Colloid breakthrough curves quite similar in the two tests with similar recoveries relative to uranine (after correction); and (4) Much slower apparent desorption of homologues in test 10-03 than in 10-01 (any effect of residual homologues from test 10-01 in test 10-03?).

  8. A tale of tails. Dark matter interpretations of the Fermi GeV excess in light of background model systematics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Calore, Francesca; Cholis, Ilias; McCabe, Christopher; Weniger, Christoph

    2015-03-10

    Several groups have identified an extended excess of gamma rays over the modeled foreground and background emissions towards the Galactic center (GC) based on observations with the Fermi Large Area Telescope. This excess emission is compatible in morphology and spectrum with a telltale sign from dark matter (DM) annihilation. Here, we present a critical reassessment of DM interpretations of the GC signal in light of the foreground and background uncertainties that some of us recently outlaid in Calore et al. (2014). We find that a much larger number of DM models fits the gamma-ray data than previously noted. In particular:more(1) In the case of DM annihilation into bb, we find that even large DM masses up to m??74 GeV are allowed at p-value >0.05. (2) Surprisingly, annihilation into nonrelativistic hh gives a good fit to the data. (3) The inverse Compton emission from ?+? with m? ~ 6070 GeV can also account for the excess at higher latitudes, |b|>2, both in its spectrum and morphology. We also present novel constraints on a large number of mixed annihilation channels, including cascade annihilation involving hidden sector mediators. In conclusion, we show that the current limits from dwarf spheroidal observations are not in tension with a DM interpretation when uncertainties on the DM halo profile are accounted for.less

  9. A Tale of Tails. Dark Matter Interpretations of the Fermi GeV Excess in Light of Background Model Systematics

    SciTech Connect (OSTI)

    Calore, Francesca; Cholis, Ilias; McCabe, Christopher; Weniger, Christoph

    2015-03-10

    Several groups have identified an extended excess of gamma rays over the modeled foreground and background emissions towards the Galactic center (GC) based on observations with the Fermi Large Area Telescope. The excess emission is compatible in morphology and spectrum with a telltale sign from dark matter (DM) annihilation. Here, we present a critical reassessment of DM interpretations of the GC signal in light of the foreground and background uncertainties that some of us recently outlaid in Calore et al. (2014). We also find that a much larger number of DM models fits the gamma-ray data than previously noted. In particular: (1) In the case of DM annihilation into bb, we find that even large DM masses up to m??74 GeV are allowed at p-value >0.05. (2) Surprisingly, annihilation into nonrelativistic hh gives a good fit to the data. (3) The inverse Compton emission from ?+?- with m?~6070 GeV can also account for the excess at higher latitudes, |b|>2, both in its spectrum and morphology. We also present novel constraints on a large number of mixed annihilation channels, including cascade annihilation involving hidden sector mediators. Finally, we show that the current limits from dwarf spheroidal observations are not in tension with a DM interpretation when uncertainties on the DM halo profile are accounted for.

  10. A Tale of Tails. Dark Matter Interpretations of the Fermi GeV Excess in Light of Background Model Systematics

    SciTech Connect (OSTI)

    Calore, Francesca; Cholis, Ilias; McCabe, Christopher; Weniger, Christoph

    2015-03-10

    Several groups have identified an extended excess of gamma rays over the modeled foreground and background emissions towards the Galactic center (GC) based on observations with the Fermi Large Area Telescope. The excess emission is compatible in morphology and spectrum with a telltale sign from dark matter (DM) annihilation. Here, we present a critical reassessment of DM interpretations of the GC signal in light of the foreground and background uncertainties that some of us recently outlaid in Calore et al. (2014). We also find that a much larger number of DM models fits the gamma-ray data than previously noted. In particular: (1) In the case of DM annihilation into b¯b, we find that even large DM masses up to mχ≃74 GeV are allowed at p-value >0.05. (2) Surprisingly, annihilation into nonrelativistic hh gives a good fit to the data. (3) The inverse Compton emission from μ+μ- with mχ~60–70 GeV can also account for the excess at higher latitudes, |b|>2°, both in its spectrum and morphology. We also present novel constraints on a large number of mixed annihilation channels, including cascade annihilation involving hidden sector mediators. Finally, we show that the current limits from dwarf spheroidal observations are not in tension with a DM interpretation when uncertainties on the DM halo profile are accounted for.

  11. A Tale of Tails. Dark Matter Interpretations of the Fermi GeV Excess in Light of Background Model Systematics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Calore, Francesca; Cholis, Ilias; McCabe, Christopher; Weniger, Christoph

    2015-03-10

    Several groups have identified an extended excess of gamma rays over the modeled foreground and background emissions towards the Galactic center (GC) based on observations with the Fermi Large Area Telescope. The excess emission is compatible in morphology and spectrum with a telltale sign from dark matter (DM) annihilation. Here, we present a critical reassessment of DM interpretations of the GC signal in light of the foreground and background uncertainties that some of us recently outlaid in Calore et al. (2014). We also find that a much larger number of DM models fits the gamma-ray data than previously noted. Inmore » particular: (1) In the case of DM annihilation into b¯b, we find that even large DM masses up to mχ≃74 GeV are allowed at p-value >0.05. (2) Surprisingly, annihilation into nonrelativistic hh gives a good fit to the data. (3) The inverse Compton emission from μ+μ- with mχ~60–70 GeV can also account for the excess at higher latitudes, |b|>2°, both in its spectrum and morphology. We also present novel constraints on a large number of mixed annihilation channels, including cascade annihilation involving hidden sector mediators. Finally, we show that the current limits from dwarf spheroidal observations are not in tension with a DM interpretation when uncertainties on the DM halo profile are accounted for.« less

  12. THE PHOTOSPHERIC RADIATION MODEL FOR THE PROMPT EMISSION OF GAMMA-RAY BURSTS: INTERPRETING FOUR OBSERVED CORRELATIONS

    SciTech Connect (OSTI)

    Fan Yizhong; Wei Daming; Zhang Fuwen [Purple Mountain Observatory, Chinese Academy of Sciences, Nanjing 210008 (China); Zhang Binbin, E-mail: yzfan@pmo.ac.cn, E-mail: dmwei@pmo.ac.cn, E-mail: fwzhang@pmo.ac.cn, E-mail: bbzhang@psu.edu [Department of Astronomy and Astrophysics, Pennsylvania State University, University Park, PA 16802 (United States)

    2012-08-10

    We show that the empirical E{sub p}-L, {Gamma}-L, E{sub p}-{Gamma}, and {eta}-bar{sub {gamma}}-E{sub p} correlations (where L is the time-averaged luminosity of the prompt emission, E{sub p} is the spectral peak energy, {Gamma} is the bulk Lorentz factor, and {eta}-bar{sub {gamma}} is the emission efficiency of gamma-ray bursts, GRBs) are well consistent with the relations between the analogous parameters predicted in the photospheric radiation model of the prompt emission of GRBs. The time-resolved thermal radiation of GRB 090902B does follow the E{sub p}-L and {Gamma}-L correlations. A reliable interpretation of the four correlations in alternative models is still lacking. These may point toward a photospheric origin of prompt emission of some GRBs.

  13. INL Tracer Interpretation

    Energy Science and Technology Software Center (OSTI)

    2007-03-27

    This spreadsheet application is for tracer test analysis. The analyses are based on the first temporal moment of a tracer. The governing equations are briefly discussed, and the individual steps required of the user are outlined. A series of Excel macros written in Visual Basic calculate mean residence time, swept pore volume, and flow-storage geometry from a tracer history.

  14. Meteor signature interpretation

    SciTech Connect (OSTI)

    Canavan, G.H.

    1997-01-01

    Meteor signatures contain information about the constituents of space debris and present potential false alarms to early warnings systems. Better models could both extract the maximum scientific information possible and reduce their danger. Accurate predictions can be produced by models of modest complexity, which can be inverted to predict the sizes, compositions, and trajectories of object from their signatures for most objects of interest and concern.

  15. Summary of the ATLAS experiment’s sensitivity to supersymmetry after LHC Run 1 -- interpreted in the phenomenological MSSM

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Aad, G.; Abbott, B.; Abdallah, J.; Abdinov, O.; Aben, R.; Abolins, M.; AbouZeid, O. S.; Abramowicz, H.; Abreu, H.; Abreu, R.; et al

    2015-10-21

    A summary of the constraints from the ATLAS experiment on R -parity-conserving supersymmetry is presented. Results from 22 separate ATLAS searches are considered, each based on analysis of up to 20.3 fb–1 of proton-proton collision data at centre-of-mass energies of √s =7 and 8 TeV at the Large Hadron Collider. The results are interpreted in the context of the 19-parameter phenomenological minimal supersymmetric standard model, in which the lightest supersymmetric particle is a neutralino, taking into account constraints from previous precision electroweak and flavour measurements as well as from dark matter related measurements. The results are presented in terms ofmore » constraints on supersymmetric particle masses and are compared to limits from simplified models. The impact of ATLAS searches on parameters such as the dark matter relic density, the couplings of the observed Higgs boson, and the degree of electroweak fine-tuning is also shown. As a result, spectra for surviving supersymmetry model points with low fine-tunings are presented.« less

  16. Summary of the ATLAS experiment’s sensitivity to supersymmetry after LHC Run 1 -- interpreted in the phenomenological MSSM

    SciTech Connect (OSTI)

    Aad, G.; Abbott, B.; Abdallah, J.; Abdinov, O.; Aben, R.; Abolins, M.; AbouZeid, O. S.; Abramowicz, H.; Abreu, H.; Abreu, R.; Abulaiti, Y.; Acharya, B. S.; Adamczyk, L.; Adams, D. L.; Adelman, J.; Adomeit, S.; Adye, T.; Affolder, A. A.; Agatonovic-Jovin, T.; Agricola, J.; Aguilar-Saavedra, J. A.; Ahlen, S. P.; Ahmadov, F.; Aielli, G.; Akerstedt, H.; Åkesson, T. P. A.; Akimov, A. V.; Alberghi, G. L.; Albert, J.; Albrand, S.; Alconada Verzini, M. J.; Aleksa, M.; Aleksandrov, I. N.; Alexa, C.; Alexander, G.; Alexopoulos, T.; Alhroob, M.; Alimonti, G.; Alio, L.; Alison, J.; Alkire, S. P.; Allbrooke, B. M. M.; Allport, P. P.; Aloisio, A.; Alonso, A.; Alonso, F.; Alpigiani, C.; Altheimer, A.; Alvarez Gonzalez, B.; Álvarez Piqueras, D.; Alviggi, M. G.; Amadio, B. T.; Amako, K.; Amaral Coutinho, Y.; Amelung, C.; Amidei, D.; Amor Dos Santos, S. P.; Amorim, A.; Amoroso, S.; Amram, N.; Amundsen, G.; Anastopoulos, C.; Ancu, L. S.; Andari, N.; Andeen, T.; Anders, C. F.; Anders, G.; Anders, J. K.; Anderson, K. J.; Andreazza, A.; Andrei, V.; Angelidakis, S.; Angelozzi, I.; Anger, P.; Angerami, A.; Anghinolfi, F.; Anisenkov, A. V.; Anjos, N.; Annovi, A.; Antonelli, M.; Antonov, A.; Antos, J.; Anulli, F.; Aoki, M.; Aperio Bella, L.; Arabidze, G.; Arai, Y.; Araque, J. P.; Arce, A. T. H.; Arduh, F. A.; Arguin, J-F.; Argyropoulos, S.; Arik, M.; Armbruster, A. J.; Arnaez, O.; Arnold, H.; Arratia, M.; Arslan, O.; Artamonov, A.; Artoni, G.; Asai, S.; Asbah, N.; Ashkenazi, A.; Åsman, B.; Asquith, L.; Assamagan, K.; Astalos, R.; Atkinson, M.; Atlay, N. B.; Augsten, K.; Aurousseau, M.; Avolio, G.; Axen, B.; Ayoub, M. K.; Azuelos, G.; Baak, M. A.; Baas, A. E.; Baca, M. J.; Bacci, C.; Bachacou, H.; Bachas, K.; Backes, M.; Backhaus, M.; Bagiacchi, P.; Bagnaia, P.; Bai, Y.; Bain, T.; Baines, J. T.; Baker, O. K.; Baldin, E. M.; Balek, P.; Balestri, T.; Balli, F.; Balunas, W. K.; Banas, E.; Banerjee, Sw.; Bannoura, A. A. E.; Barak, L.; Barberio, E. L.; Barberis, D.; Barbero, M.; Barillari, T.; Barisonzi, M.; Barklow, T.; Barlow, N.; Barnes, S. L.; Barnett, B. M.; Barnett, R. M.; Barnovska, Z.; Baroncelli, A.; Barone, G.; Barr, A. J.; Barreiro, F.; Barreiro Guimarães da Costa, J.; Bartoldus, R.; Barton, A. E.; Bartos, P.; Basalaev, A.; Bassalat, A.; Basye, A.; Bates, R. L.; Batista, S. J.; Batley, J. R.; Battaglia, M.; Bauce, M.; Bauer, F.; Bawa, H. S.; Beacham, J. B.; Beattie, M. D.; Beau, T.; Beauchemin, P. H.; Beccherle, R.; Bechtle, P.; Beck, H. P.; Becker, K.; Becker, M.; Beckingham, M.; Becot, C.; Beddall, A. J.; Beddall, A.; Bednyakov, V. A.; Bee, C. P.; Beemster, L. J.; Beermann, T. A.; Begel, M.; Behr, J. K.; Belanger-Champagne, C.; Bell, W. H.; Bella, G.; Bellagamba, L.; Bellerive, A.; Bellomo, M.; Belotskiy, K.; Beltramello, O.; Benary, O.; Benchekroun, D.; Bender, M.; Bendtz, K.; Benekos, N.; Benhammou, Y.; Benhar Noccioli, E.; Benitez Garcia, J. A.; Benjamin, D. P.; Bensinger, J. R.; Bentvelsen, S.; Beresford, L.; Beretta, M.; Berge, D.; Bergeaas Kuutmann, E.; Berger, N.; Berghaus, F.; Beringer, J.; Bernard, C.; Bernard, N. R.; Bernius, C.; Bernlochner, F. U.; Berry, T.; Berta, P.; Bertella, C.; Bertoli, G.; Bertolucci, F.; Bertsche, C.; Bertsche, D.; Besana, M. I.; Besjes, G. J.; Bessidskaia Bylund, O.; Bessner, M.; Besson, N.; Betancourt, C.; Bethke, S.; Bevan, A. J.; Bhimji, W.; Bianchi, R. M.; Bianchini, L.; Bianco, M.; Biebel, O.; Biedermann, D.; Bieniek, S. P.; Biesuz, N. V.; Biglietti, M.; Bilbao De Mendizabal, J.; Bilokon, H.; Bindi, M.; Binet, S.; Bingul, A.; Bini, C.; Biondi, S.; Bjergaard, D. M.; Black, C. W.; Black, J. E.; Black, K. M.; Blackburn, D.; Blair, R. E.; Blanchard, J. -B.; Blanco, J. E.; Blazek, T.; Bloch, I.; Blocker, C.; Blum, W.; Blumenschein, U.; Blunier, S.; Bobbink, G. J.; Bobrovnikov, V. S.; Bocchetta, S. S.; Bocci, A.; Bock, C.; Boehler, M.; Bogaerts, J. A.; Bogavac, D.; Bogdanchikov, A. 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E.; Suruliz, K.; Susinno, G.; Sutton, M. R.; Suzuki, S.; Svatos, M.; Swiatlowski, M.; Sykora, I.; Sykora, T.; Ta, D.; Taccini, C.; Tackmann, K.; Taenzer, J.; Taffard, A.; Tafirout, R.; Taiblum, N.; Takai, H.; Takashima, R.; Takeda, H.; Takeshita, T.; Takubo, Y.; Talby, M.; Talyshev, A. A.; Tam, J. Y. C.; Tan, K. G.; Tanaka, J.; Tanaka, R.; Tanaka, S.; Tannenwald, B. B.; Tannoury, N.; Tapia Araya, S.; Tapprogge, S.; Tarem, S.; Tarrade, F.; Tartarelli, G. F.; Tas, P.; Tasevsky, M.; Tashiro, T.; Tassi, E.; Tavares Delgado, A.; Tayalati, Y.; Taylor, F. E.; Taylor, G. N.; Taylor, P. T. E.; Taylor, W.; Teischinger, F. A.; Teixeira Dias Castanheira, M.; Teixeira-Dias, P.; Temming, K. K.; Temple, D.; Ten Kate, H.; Teng, P. K.; Teoh, J. J.; Tepel, F.; Terada, S.; Terashi, K.; Terron, J.; Terzo, S.; Testa, M.; Teuscher, R. J.; Theveneaux-Pelzer, T.; Thomas, J. P.; Thomas-Wilsker, J.; Thompson, E. N.; Thompson, P. D.; Thompson, R. J.; Thompson, A. S.; Thomsen, L. A.; Thomson, E.; Thomson, M.; Thun, R. P.; Tibbetts, M. J.; Ticse Torres, R. E.; Tikhomirov, V. O.; Tikhonov, Yu. A.; Timoshenko, S.; Tiouchichine, E.; Tipton, P.; Tisserant, S.; Todome, K.; Todorov, T.; Todorova-Nova, S.; Tojo, J.; Tokár, S.; Tokushuku, K.; Tollefson, K.; Tolley, E.; Tomlinson, L.; Tomoto, M.; Tompkins, L.; Toms, K.; Torrence, E.; Torres, H.; Torró Pastor, E.; Toth, J.; Touchard, F.; Tovey, D. R.; Trefzger, T.; Tremblet, L.; Tricoli, A.; Trigger, I. M.; Trincaz-Duvoid, S.; Tripiana, M. F.; Trischuk, W.; Trocmé, B.; Troncon, C.; Trottier-McDonald, M.; Trovatelli, M.; Truong, L.; Trzebinski, M.; Trzupek, A.; Tsarouchas, C.; Tseng, J. C-L.; Tsiareshka, P. V.; Tsionou, D.; Tsipolitis, G.; Tsirintanis, N.; Tsiskaridze, S.; Tsiskaridze, V.; Tskhadadze, E. G.; Tsukerman, I. I.; Tsulaia, V.; Tsuno, S.; Tsybychev, D.; Tudorache, A.; Tudorache, V.; Tuna, A. N.; Tupputi, S. A.; Turchikhin, S.; Turecek, D.; Turra, R.; Turvey, A. J.; Tuts, P. M.; Tykhonov, A.; Tylmad, M.; Tyndel, M.; Ueda, I.; Ueno, R.; Ughetto, M.; Ugland, M.; Ukegawa, F.; Unal, G.; Undrus, A.; Unel, G.; Ungaro, F. C.; Unno, Y.; Unverdorben, C.; Urban, J.; Urquijo, P.; Urrejola, P.; Usai, G.; Usanova, A.; Vacavant, L.; Vacek, V.; Vachon, B.; Valderanis, C.; Valencic, N.; Valentinetti, S.; Valero, A.; Valery, L.; Valkar, S.; Vallecorsa, S.; Valls Ferrer, J. A.; Van Den Wollenberg, W.; Van Der Deijl, P. C.; van der Geer, R.; van der Graaf, H.; van Eldik, N.; van Gemmeren, P.; Van Nieuwkoop, J.; van Vulpen, I.; van Woerden, M. C.; Vanadia, M.; Vandelli, W.; Vanguri, R.; Vaniachine, A.; Vannucci, F.; Vardanyan, G.; Vari, R.; Varnes, E. W.; Varol, T.; Varouchas, D.; Vartapetian, A.; Varvell, K. E.; Vazeille, F.; Vazquez Schroeder, T.; Veatch, J.; Veloce, L. M.; Veloso, F.; Velz, T.; Veneziano, S.; Ventura, A.; Ventura, D.; Venturi, M.; Venturi, N.; Venturini, A.; Vercesi, V.; Verducci, M.; Verkerke, W.; Vermeulen, J. C.; Vest, A.; Vetterli, M. C.; Viazlo, O.; Vichou, I.; Vickey, T.; Vickey Boeriu, O. E.; Viehhauser, G. H. A.; Viel, S.; Vigne, R.; Villa, M.; Villaplana Perez, M.; Vilucchi, E.; Vincter, M. G.; Vinogradov, V. B.; Vivarelli, I.; Vives Vaque, F.; Vlachos, S.; Vladoiu, D.; Vlasak, M.; Vogel, M.; Vokac, P.; Volpi, G.; Volpi, M.; von der Schmitt, H.; von Radziewski, H.; von Toerne, E.; Vorobel, V.; Vorobev, K.; Vos, M.; Voss, R.; Vossebeld, J. H.; Vranjes, N.; Vranjes Milosavljevic, M.; Vrba, V.; Vreeswijk, M.; Vuillermet, R.; Vukotic, I.; Vykydal, Z.; Wagner, P.; Wagner, W.; Wahlberg, H.; Wahrmund, S.; Wakabayashi, J.; Walder, J.; Walker, R.; Walkowiak, W.; Wang, C.; Wang, F.; Wang, H.; Wang, H.; Wang, J.; Wang, J.; Wang, K.; Wang, R.; Wang, S. M.; Wang, T.; Wang, T.; Wang, X.; Wanotayaroj, C.; Warburton, A.; Ward, C. P.; Wardrope, D. R.; Washbrook, A.; Wasicki, C.; Watkins, P. M.; Watson, A. T.; Watson, I. J.; Watson, M. F.; Watts, G.; Watts, S.; Waugh, B. M.; Webb, S.; Weber, M. S.; Weber, S. W.; Webster, J. S.; Weidberg, A. R.; Weinert, B.; Weingarten, J.; Weiser, C.; Weits, H.; Wells, P. S.; Wenaus, T.; Wengler, T.; Wenig, S.; Wermes, N.; Werner, M.; Werner, P.; Wessels, M.; Wetter, J.; Whalen, K.; Wharton, A. M.; White, A.; White, M. J.; White, R.; White, S.; Whiteson, D.; Wickens, F. J.; Wiedenmann, W.; Wielers, M.; Wienemann, P.; Wiglesworth, C.; Wiik-Fuchs, L. A. M.; Wildauer, A.; Wilkens, H. G.; Williams, H. H.; Williams, S.; Willis, C.; Willocq, S.; Wilson, A.; Wilson, J. A.; Wingerter-Seez, I.; Winklmeier, F.; Winter, B. T.; Wittgen, M.; Wittkowski, J.; Wollstadt, S. J.; Wolter, M. W.; Wolters, H.; Wosiek, B. K.; Wotschack, J.; Woudstra, M. J.; Wozniak, K. W.; Wu, M.; Wu, M.; Wu, S. L.; Wu, X.; Wu, Y.; Wyatt, T. R.; Wynne, B. M.; Xella, S.; Xu, D.; Xu, L.; Yabsley, B.; Yacoob, S.; Yakabe, R.; Yamada, M.; Yamaguchi, D.; Yamaguchi, Y.; Yamamoto, A.; Yamamoto, S.; Yamanaka, T.; Yamauchi, K.; Yamazaki, Y.; Yan, Z.; Yang, H.; Yang, H.; Yang, Y.; Yao, W-M.; Yap, Y. C.; Yasu, Y.; Yatsenko, E.; Yau Wong, K. H.; Ye, J.; Ye, S.; Yeletskikh, I.; Yen, A. L.; Yildirim, E.; Yorita, K.; Yoshida, R.; Yoshihara, K.; Young, C.; Young, C. J. S.; Youssef, S.; Yu, D. R.; Yu, J.; Yu, J. M.; Yu, J.; Yuan, L.; Yuen, S. P. Y.; Yurkewicz, A.; Yusuff, I.; Zabinski, B.; Zaidan, R.; Zaitsev, A. M.; Zalieckas, J.; Zaman, A.; Zambito, S.; Zanello, L.; Zanzi, D.; Zeitnitz, C.; Zeman, M.; Zemla, A.; Zeng, Q.; Zengel, K.; Zenin, O.; Ženiš, T.; Zerwas, D.; Zhang, D.; Zhang, F.; Zhang, G.; Zhang, H.; Zhang, J.; Zhang, L.; Zhang, R.; Zhang, X.; Zhang, Z.; Zhao, X.; Zhao, Y.; Zhao, Z.; Zhemchugov, A.; Zhong, J.; Zhou, B.; Zhou, C.; Zhou, L.; Zhou, L.; Zhou, M.; Zhou, N.; Zhu, C. G.; Zhu, H.; Zhu, J.; Zhu, Y.; Zhuang, X.; Zhukov, K.; Zibell, A.; Zieminska, D.; Zimine, N. I.; Zimmermann, C.; Zimmermann, S.; Zinonos, Z.; Zinser, M.; Ziolkowski, M.; Živković, L.; Zobernig, G.; Zoccoli, A.; zur Nedden, M.; Zurzolo, G.; Zwalinski, L.

    2015-10-21

    A summary of the constraints from the ATLAS experiment on R -parity-conserving supersymmetry is presented. Results from 22 separate ATLAS searches are considered, each based on analysis of up to 20.3 fb–1 of proton-proton collision data at centre-of-mass energies of √s =7 and 8 TeV at the Large Hadron Collider. The results are interpreted in the context of the 19-parameter phenomenological minimal supersymmetric standard model, in which the lightest supersymmetric particle is a neutralino, taking into account constraints from previous precision electroweak and flavour measurements as well as from dark matter related measurements. The results are presented in terms of constraints on supersymmetric particle masses and are compared to limits from simplified models. The impact of ATLAS searches on parameters such as the dark matter relic density, the couplings of the observed Higgs boson, and the degree of electroweak fine-tuning is also shown. As a result, spectra for surviving supersymmetry model points with low fine-tunings are presented.

  17. Impact of nucleon matrix element uncertainties on the interpretation of direct and indirect dark matter search results

    SciTech Connect (OSTI)

    Austri, R. Ruiz de

    2013-11-01

    We study in detail the impact of the current uncertainty in nucleon matrix elements on the sensitivity of direct and indirect experimental techniques for dark matter detection. We perform two scans in the framework of the cMSSM: one using recent values of the pion-sigma term obtained from Lattice QCD, and the other using values derived from experimental measurements. The two choices correspond to extreme values quoted in the literature and reflect the current tension between different ways of obtaining information about the structure of the nucleon. All other inputs in the scans, astrophysical and from particle physics, are kept unchanged. We use two experiments, XENON100 and IceCube, as benchmark cases to illustrate our case. We find that the interpretation of dark matter search results from direct detection experiments is more sensitive to the choice of the central values of the hadronic inputs than the results of indirect search experiments. The allowed regions of cMSSM parameter space after including XENON100 constraints strongly differ depending on the assumptions on the hadronic matrix elements used. On the other hand, the constraining potential of IceCube is almost independent of the choice of these values.

  18. Interpretation of brine-permeability tests of the Salado Formation at the Waste Isolation Pilot Plant site: First interim report

    SciTech Connect (OSTI)

    Beauheim, R.L. ); Saulnier, G.J. Jr.; Avis, J.D. )

    1991-08-01

    Pressure-pulse tests have been performed in bedded evaporites of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) site to evaluate the hydraulic properties controlling brine flow through the Salado. Hydraulic conductivities ranging from about 10{sup {minus}14} to 10{sup {minus}11} m/s (permeabilities of about 10{sup {minus}21} to 10{sup {minus}18} m{sup 2}) have been interpreted from nine tests conducted on five stratigraphic intervals within eleven meters of the WIPP underground excavations. Tests of a pure halite layer showed no measurable permeability. Pore pressures in the stratigraphic intervals range from about 0.5 to 9.3 MPa. An anhydrite interbed (Marker Bed 139) appears to be one or more orders of magnitude more permeable than the surrounding halite. Hydraulic conductivities appear to increase, and pore pressures decrease, with increasing proximity to the excavations. These effects are particularly evident within two to three meters of the excavations. Two tests indicated the presence of apparent zero-flow boundaries about two to three meters from the boreholes. The other tests revealed no apparent boundaries within the radii of influence of the tests, which were calculated to range from about four to thirty-five meters from the test holes. The data are insufficient to determine if brine flow through evaporites results from Darcy-like flow driven by pressure gradients within naturally interconnected porosity or from shear deformation around excavations connecting previously isolated pores, thereby providing pathways for fluids at or near lithostatic pressure to be driven towards the low-pressure excavations. Future testing will be performed at greater distances from the excavations to evaluate hydraulic properties and processes beyond the range of excavation effects.

  19. INTERPRETING ERUPTIVE BEHAVIOR IN NOAA AR 11158 VIA THE REGION'S MAGNETIC ENERGY AND RELATIVE-HELICITY BUDGETS

    SciTech Connect (OSTI)

    Tziotziou, Kostas; Georgoulis, Manolis K.; Liu Yang

    2013-08-01

    In previous works, we introduced a nonlinear force-free method that self-consistently calculates the instantaneous budgets of free magnetic energy and relative magnetic helicity in solar active regions (ARs). Calculation is expedient and practical, using only a single vector magnetogram per computation. We apply this method to a time series of 600 high-cadence vector magnetograms of the eruptive NOAA AR 11158 acquired by the Helioseismic and Magnetic Imager on board the Solar Dynamics Observatory over a five-day observing interval. Besides testing our method extensively, we use it to interpret the dynamical evolution in the AR, including eruptions. We find that the AR builds large budgets of both free magnetic energy and relative magnetic helicity, sufficient to power many more eruptions than the ones it gave within the interval of interest. For each of these major eruptions, we find eruption-related decreases and subsequent free-energy and helicity budgets that are consistent with the observed eruption (flare and coronal mass ejection (CME)) sizes. In addition, we find that (1) evolution in the AR is consistent with the recently proposed (free) energy-(relative) helicity diagram of solar ARs, (2) eruption-related decreases occur before the flare and the projected CME-launch times, suggesting that CME progenitors precede flares, and (3) self terms of free energy and relative helicity most likely originate from respective mutual terms, following a progressive mutual-to-self conversion pattern that most likely stems from magnetic reconnection. This results in the non-ideal formation of increasingly helical pre-eruption structures and instigates further research on the triggering of solar eruptions with magnetic helicity firmly placed in the eruption cadre.

  20. Quantum of area {Delta}A=8{pi}l{sub P}{sup 2} and a statistical interpretation of black hole entropy

    SciTech Connect (OSTI)

    Ropotenko, Kostiantyn

    2010-08-15

    In contrast to alternative values, the quantum of area {Delta}A=8{pi}l{sub P}{sup 2} does not follow from the usual statistical interpretation of black hole entropy; on the contrary, a statistical interpretation follows from it. This interpretation is based on the two concepts: nonadditivity of black hole entropy and Landau quantization. Using nonadditivity a microcanonical distribution for a black hole is found and it is shown that the statistical weight of a black hole should be proportional to its area. By analogy with conventional Landau quantization, it is shown that quantization of a black hole is nothing but the Landau quantization. The Landau levels of a black hole and their degeneracy are found. The degree of degeneracy is equal to the number of ways to distribute a patch of area 8{pi}l{sub P}{sup 2} over the horizon. Taking into account these results, it is argued that the black hole entropy should be of the form S{sub bh}=2{pi}{center_dot}{Delta}{Gamma}, where the number of microstates is {Delta}{Gamma}=A/8{pi}l{sub P}{sup 2}. The nature of the degrees of freedom responsible for black hole entropy is elucidated. The applications of the new interpretation are presented. The effect of noncommuting coordinates is discussed.

  1. Silica Geothermometers | Open Energy Information

    Open Energy Info (EERE)

    in the Past 20 Years: Geochemistry in Geothermal Exploration, Resource Evaluation and Reservoir Management 2.0 2.1 Lectures on Geochemical Interpretation of Hydrothermal...

  2. Geochemical, Genetic, and Community Controls on Mercury

    SciTech Connect (OSTI)

    Wall, Judy D.

    2014-11-10

    The sulfate-reducing bacteria (SRB) are soil bacteria that share two common characteristics, strict anaerobiosis and the ability to respire sulfate. The metabolic activities of these bacteria play significant roles in the global sulfur cycle, anaerobic degradation of biomass, biological metal corrosion in the environment and, recently, degradation of toxic compounds. The accumulation of evidence suggests these bacteria are also key to the production of the neurotoxin methylmercury in environmental settings. We propose to use our experience with the development of genetics in sulfate-reducing bacteria of the genus Desulfovibrio to create mutations that will eliminate the methylation of mercury, thereby identifying the genes essential for this process. This information may allow the environmental monitoring of the mercury methylation potential to learn the location and quantity of the production this toxin. From these data, more accurate predictive models of mercury cycling can be generated.

  3. Natural bacterial communities serve as quantitative geochemical...

    Office of Scientific and Technical Information (OSTI)

    approach to identify sites contaminated with hydrocarbons from the Deepwater Horizon oil spill, finding that altered bacterial communities encode a memory of prior...

  4. Natural bacterial communities serve as quantitative geochemical...

    Office of Scientific and Technical Information (OSTI)

    that respond to and capture perturbations caused by human impacts. less Authors: Smith, Mark B. 1 ; Rocha, Andrea M. 2 ; Smillie, Chris S. 1 ; Olesen, Scott W. 1 ;...

  5. Interface Induced Carbonate Mineralization: A Fundamental Geochemical...

    Office of Scientific and Technical Information (OSTI)

    Authors: Teng, H. Henry 1 ; Xu, Huifang 2 + Show Author Affiliations PI, The George Washington University PI, The George Washington University Co-PI, University of ...

  6. Optimizing parameters for predicting the geochemical behavior...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Imaging, Characterizing, and Modeling of Fracture Networks and Fluid Flow in EGS Reservoirs; II: Full-Waveform Inversion of 3D-9C VSP data from Bradys EGS Site and Update of the ...

  7. Preliminary Interpretation of a Radionuclide and Colloid Tracer Test in a Granodiorite Shear Zone at the Grimsel Test Site, Switzerland

    SciTech Connect (OSTI)

    Reimus, Paul W.

    2012-08-30

    In February and March 2012, a tracer test involving the injection of a radionuclide-colloid cocktail was conducted in the MI shear zone at the Grimsel Test Site, Switzerland, as part of the Colloids Formation and Migration (CFM) project. The colloids were derived from FEBEX bentonite, which is mined in Spain and is being considered as a potential waste package backfill in a Spanish nuclear waste repository. The tracer test, designated test 12-02 (second test in 2012), involved the injection of the tracer cocktail into borehole CFM 06.002i2 and extraction from the Pinkel surface packer at the main access tunnel wall approximately 6.1 m from the injection interval. The test configuration is depicted in Figure 1. This configuration has been used in several conservative tracer tests and two colloid-homologue tracer tests since 2007, and it is will be employed in an upcoming test involving the emplacement of a radionuclide-doped bentonite plug into CFM 06.002i2 to evaluate the swelling and erosion of the bentonite and the transport of bentonite colloids and radionuclides from the source to the extraction point at the tunnel wall. Interpretive analyses of several of the previous tracer tests, from 09-01 through 12-02 were provided in two previous Used Fuel Disposition Program milestone reports (Arnold et al., 2011; Kersting et al., 2012). However, only the data for the conservative tracer Amino-G Acid was previously analyzed from test 12-02 because the other tracer data from this test were not available at the time. This report documents the first attempt to quantitatively analyze the radionuclide and colloid breakthrough curves from CFM test 12-02. This report was originally intended to also include an experimental assessment of colloid-facilitated transport of uranium by bentonite colloids in the Grimsel system, but this assessment was not conducted because it was reported by German collaborators at the Karlsruhe Institute of Technology (KIT) that neither uranium nor neptunium adsorbed appreciably to FEBEX bentonite colloids in Grimsel groundwater (Huber et al., 2011). The Grimsel groundwater has a relatively high pH of {approx}9, so the lack of uranium and neptunium adsorption to clay is not surprising given the tendency for these actinides to form very stable negative or neutrally-charged uranyl- or calcium-uranyl-carbonate complexes at these pH, particularly in a water that is effectively saturated with respect to calcite. It was also observed in testing conducted at LANL earlier in 2012 that uranium did not adsorb measurably to Grimsel granodiorite in a synthetic Grimsel groundwater at pH {approx}8.5 (Kersting et al., 2012). Thus, the planned experimental work was not pursued because all the available information clearly pointed to an expected result that uranium transport would not be facilitated by clay colloids in the Grimsel system.

  8. Positive field-cooled dc susceptibility in granular superconductors interpreted through numerical simulations on a simple Josephson-junction-array model

    SciTech Connect (OSTI)

    Auletta, C.; Raiconi, G.; De Luca, R.; Pace, S.

    1995-05-01

    We have performed numerical simulations of a field-cooled dc susceptibility experiment carried out for granular superconductors by modeling these systems with a simple Josephson-junction array proposed by the authors. By this analysis the temperature dependence of the positive field-cooled susceptibility at very low values of the applied magnetic field, observed by Braunisch {ital et} {ital al}. [Phys. Rev. Lett. 68, 1908 (1992)] for some ceramic superonductors, has been reproduced and interpreted.

  9. The effect of ion orbit loss and X-loss on the interpretation of ion energy and particle transport in the DIII-D edge plasma

    SciTech Connect (OSTI)

    Stacey, Weston M.

    2011-10-15

    Calculation models are presented for treating ion orbit loss effects in interpretive fluid transport calculations for the tokamak edge pedestal. Both standard ion orbit loss of particles following trapped or passing orbits across the separatrix and the X-loss of particles that are poloidally trapped in a narrow null-B{sub {theta}} region extending inward from the X-point, where they gradB and curvature drift outward, are considered. Calculations are presented for a representative DIII-D [J. Luxon, Nucl. Fusion 42, 614 (2002)] shot which indicate that ion orbit loss effects are significant and should be taken into account in calculations of present and future experiments.

  10. CX-009278: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Measurement and Interpretation of Seismic Velocities and Attenuation in Hydrate-Bearing Sediments CX(s) Applied: A9, B2.2, B3.6 Date: 09/07/2012 Location(s): Colorado Offices(s): National Energy Technology Laboratory

  11. Microsoft Word - Interpretive Guidance FINAL

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    facility and a discussion of the general environmental impacts of each ... by an officer of the applicant, having knowledge of the matters therein set forth." 10 ...

  12. Back from the Brink with Something for Everyone - The Final Executed Memorandum of Agreement for Interpretation of the East Tennessee Technology Park and the K-25 Building - 13370

    SciTech Connect (OSTI)

    Cusick, Lesley T.

    2013-07-01

    When the Environmental Management (EM) Program at the Oak Ridge Office of the Department of Energy (DOE) began its major decontamination and decommissioning (D and D) program activities in the mid-1990's, it was understood that the work to demolish the gaseous diffusion process buildings at the K-25 Site, as it was then known, would be challenging. Nothing of that size and breadth had ever been done within the DOE complex and the job brought about a full menu of unique attributes: radiological contamination with enriched materials entrained in certain areas of the system, a facility that was never designed not to operate but had been shut down since 1964, and a loyal following of individuals and organizations who were committed to the physical preservation of at least some portion of the historic Manhattan Project property. DOE was able to solve and resolve the issues related to nuclear materials management, contamination control, and determining the best way to safely and efficiently deconstruct the massive building. However, for a variety of reasons, resolution of the historic preservation questions - what and how much to preserve, how to preserve it, where to preserve it, how to interpret it, how much to spend on preservation, and by and for whom preservation should occur - remained open to debate for over a decade. After a dozen years, countless meetings, phone calls, discussions and other exchanges, and four National Historic Preservation Act (NHPA) [1] Memoranda of Agreement (MOA), a final MOA [2] has been executed. The final executed MOA's measures are robust, creative, substantive, and will be effective. They include a multi-story replica of a portion of the K-25 Building, the dedication of the K-25 Building footprint for preservation purposes, an equipment building to house authentic Manhattan Project and Cold War equipment, a virtual museum, an on-site history center, a grant to preserve a historically-significant Manhattan Project-era hotel in Oak Ridge, and more. The MOA was designed to offer something for everyone. The MOA for the K- 25 Building and interpretation of the East Tennessee Technology Park (ETTP; formerly the K-25 Site) was executed by all of the signatory parties on August 7, 2012 - almost 67 years to-the-day after the 'product' of the K-25 process building became known to more than just a small group of scientists and engineers working on a secret project for the Army Corps of Engineers Manhattan District. (authors)

  13. NESC VII European project: demonstration of warm pre-stressing effect in biaxial loading conditions - Bending tests on 18MND5 cruciform specimens and their interpretation

    SciTech Connect (OSTI)

    Jacquemoud, C.; Yuritzinn, T.; Marie, S.

    2012-07-01

    In the framework of the NESC VII European project, a large experimental program has been dedicated to characterize the Warm Pre-Stressing (WPS) effect in different testing configurations. One of the CEA (France) contributions to this project is the realization of five point bending tests on large cruciform specimens considering different WPS loading cycles. The five cruciform specimens, sponsored by EDF (France) and IRSN (France), are made of 18MND5 steel. Two of them have been tested on a same LCF (Load-Cool-Fracture) loading cycle and two others on the same LCTF (Load-Cool-Transient-Fracture) loading cycle. The experimental results presented in this paper give a successful demonstration of the WPS effect in biaxial loading conditions either on a LCF or on a LCTF cycle. During the test interpretations, different models have then been tested and compared in order to evaluate their ability to predict the cleavage fracture in the case of different WPS loading cycles. They all provide very conservative predictions whatever loading cycle is concerned. (authors)

  14. Factors influencing the development and implementation of advanced radiographer practice in Australia – a qualitative study using an interpretative phenomenological approach

    SciTech Connect (OSTI)

    Page, Barbara A; Bernoth, Maree; Davidson, Rob

    2014-09-15

    The purpose of this study was to explore the factors influencing the implementation or the lack of implementation of advanced practitioner role in Australia. This study uses an interpretative phenomenological approach to explore the in-depth real life issues, which surround the advanced practitioner as a solution to radiologist workforce shortages in Australia. Research participants are radiographers, radiation therapists and health managers registered with the Australian Institute of Radiography (AIR) and holding senior professional and AIR Board positions with knowledge of current advanced practice. In total, seven interviews were conducted revealing education, governance, technical, people issues, change management, government, costs and timing as critical factors influencing advanced practice in Australia. Seven participants in this study perceived an advanced practice role might have major benefits and a positive impact on the immediate and long-term management of patients. Another finding is the greater respect and appreciation of each other's roles and expertise within the multidisciplinary healthcare team. Engagement is required of the critical stakeholders that have been identified as ‘blockers’ (radiologists, health departments) as well as identified allies (e.g. emergency clinicians, supportive radiologists, patient advocacy groups). The research supports that the AIR has a role to play for the professional identity of radiographers and shaping the advanced practice role in Australia.

  15. Interpretation of Flow Logs from Nevada Test Site Boreholes to Estimate Hydraulic conductivity Using Numerical Simulations Constrained by Single-Well Aquifer Tests

    SciTech Connect (OSTI)

    Garcia, C. Amanda; Halford, Keith J.; Laczniak, Randell J.

    2010-02-12

    Hydraulic conductivities of volcanic and carbonate lithologic units at the Nevada Test Site were estimated from flow logs and aquifer-test data. Borehole flow and drawdown were integrated and interpreted using a radial, axisymmetric flow model, AnalyzeHOLE. This integrated approach is used because complex well completions and heterogeneous aquifers and confining units produce vertical flow in the annular space and aquifers adjacent to the wellbore. AnalyzeHOLE simulates vertical flow, in addition to horizontal flow, which accounts for converging flow toward screen ends and diverging flow toward transmissive intervals. Simulated aquifers and confining units uniformly are subdivided by depth into intervals in which the hydraulic conductivity is estimated with the Parameter ESTimation (PEST) software. Between 50 and 150 hydraulic-conductivity parameters were estimated by minimizing weighted differences between simulated and measured flow and drawdown. Transmissivity estimates from single-well or multiple-well aquifer tests were used to constrain estimates of hydraulic conductivity. The distribution of hydraulic conductivity within each lithology had a minimum variance because estimates were constrained with Tikhonov regularization. AnalyzeHOLE simulated hydraulic-conductivity estimates for lithologic units across screened and cased intervals are as much as 100 times less than those estimated using proportional flow-log analyses applied across screened intervals only. Smaller estimates of hydraulic conductivity for individual lithologic units are simulated because sections of the unit behind cased intervals of the wellbore are not assumed to be impermeable, and therefore, can contribute flow to the wellbore. Simulated hydraulic-conductivity estimates vary by more than three orders of magnitude across a lithologic unit, indicating a high degree of heterogeneity in volcanic and carbonate-rock units. The higher water transmitting potential of carbonate-rock units relative to volcanic-rock units is exemplified by the large difference in their estimated maximum hydraulic conductivity; 4,000 and 400 feet per day, respectively. Simulated minimum estimates of hydraulic conductivity are inexact and represent the lower detection limit of the method. Minimum thicknesses of lithologic intervals also were defined for comparing AnalyzeHOLE results to hydraulic properties in regional ground-water flow models.

  16. INTERPRETATION REGARDING THE APPLICATION OF DOE TECHNICAL STANDARD 1027-92, HAZARD CATEGORIZATION AND ACCIDENT ANALYSIS TECHNIQUES FOR COMPLIANCE WITH DOE ORDER 5480.23, NUCLEAR SAFETY ANALYSIS REPORTS, UNDER THE PROVISIONS OF 10 C.F.R. § 830.202(b)(3).

    Broader source: Energy.gov [DOE]

    The following document is the Department of Energy Office of General Counsel interpretation regarding the application of DOE Technical Standard 1027-92, Hazard Categorization and Accident Analysis...

  17. Workshop on hydrology of crystalline basement rocks

    SciTech Connect (OSTI)

    Davis, S.N.

    1981-08-01

    This workshop covered the following subjects: measurements in relatively shallow boreholes; measurement and interpretation of data from deep boreholes; hydrologic properties of crystalline rocks as interpreted by geophysics and field geology; rock mechanics related to hydrology of crystalline rocks; the possible contributions of modeling to the understanding of the hydrology of crystalline rocks; and geochemical interpretations of the hydrology of crystalline rocks. (MHR)

  18. Property:GeochemReservoirTemp | Open Energy Information

    Open Energy Info (EERE)

    pages using this property. C Chena Geothermal Area + 383.15 K110 C 230 F 689.67 R + F Fenton Hill HDR Geothermal Area + 505.15 K232 C 449.6 F 909.27 R + L Lightning...

  19. Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater

    Energy Savers [EERE]

    Department of Energy Models and Tools: Systems Analysis of Hydrogen and Fuel Cells Analysis Models and Tools: Systems Analysis of Hydrogen and Fuel Cells The Fuel Cell Technologies Office's systems analysis program uses a consistent set of models and data for transparent analytical evaluations. The following fact sheets provide an overview and individual summaries of the models and tools used for systems analysis of hydrogen and fuel cells. View the Overview Fact Sheet and Individual

  20. Geochemical modeling of the Raft River geothermal field | Open...

    Open Energy Info (EERE)

    and additional work needed to refine the overall reservoir model. Authors Overton, H. L.; Chaney, R. E.; Mcatee, R. E.; Graham and D. L. Published DOE Information Bridge, 111...

  1. Hydrologic and Geochemical Monitoring in Long Valley Caldera...

    Open Energy Info (EERE)

    composition of water from selected stream sites, springs, and wells; pumpage from four geothermal wells; flow rates of selected springs and stream sites; mean daily water or gas...

  2. Merging High Resolution Geophysical and Geochemical Surveys to...

    Open Energy Info (EERE)

    and in combination when exploring for blind resources where structure, permeability, and temperature are the most pressing questions. The slim holes will allow testing...

  3. Trace Element Geochemical Zoning in the Roosevelt Hot Springs...

    Open Energy Info (EERE)

    this distribution may be a useful solid geothermometer. Authors O.D. Christensen, J.N. Moore and R.M. Capuano Conference GRC Annual Meeting; Salt Lake City, UT; 09091980...

  4. Temporal Geochemical Variations In Volatile Emissions From Mount...

    Open Energy Info (EERE)

    1980. Based on D modeling, approximately 63% of shallow, post-1980 magma has yet to degas. Surprisingly, Cl and F contents in the 1994 samples were only 0.47 and 3.8%,...

  5. SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon Grand Challenge Workshop -Imaging Subsurface.pdf More Documents & Publications AGU SubTER Town Hall Presentation 2015 SubTER Fact Sheet SubTER Presentation at Town Hall - ...

  6. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and...

    Office of Scientific and Technical Information (OSTI)

    Additional Journal Information: Journal Volume: 63; Journal Issue: C; Journal ID: ISSN 1876-6102 Publisher: Elsevier Research Org: Pacific Northwest National Laboratory (PNNL), ...

  7. Hg Anomalies In Soils- A Geochemical Exploration Method For Geothermal...

    Open Energy Info (EERE)

    is not possible. Hg anomaly patterns yield information on the presence as well as the geometry of shallow geothermal circulation patterns. In conjunction with structural geologic...

  8. Lattice gas automata for flow and transport in geochemical systems

    SciTech Connect (OSTI)

    Janecky, D.R.; Chen, S.; Dawson, S.; Eggert, K.C.; Travis, B.J.

    1992-05-01

    Lattice gas automata models are described, which couple solute transport with chemical reactions at mineral surfaces within pore networks. Diffusion in a box calculations are illustrated, which compare directly with Fickian diffusion. Chemical reactions at solid surfaces, including precipitation/dissolution, sorption, and catalytic reaction, can be examined with the model because hydrodynamic transport, solute diffusion and mineral surface processes are all treated explicitly. The simplicity and flexibility of the approach provides the ability to study the interrelationship between fluid flow and chemical reactions in porous materials, at a level of complexity that has not previously been computationally possible.

  9. Lattice gas automata for flow and transport in geochemical systems

    SciTech Connect (OSTI)

    Janecky, D.R.; Chen, S.; Dawson, S.; Eggert, K.C.; Travis, B.J.

    1992-01-01

    Lattice gas automata models are described, which couple solute transport with chemical reactions at mineral surfaces within pore networks. Diffusion in a box calculations are illustrated, which compare directly with Fickian diffusion. Chemical reactions at solid surfaces, including precipitation/dissolution, sorption, and catalytic reaction, can be examined with the model because hydrodynamic transport, solute diffusion and mineral surface processes are all treated explicitly. The simplicity and flexibility of the approach provides the ability to study the interrelationship between fluid flow and chemical reactions in porous materials, at a level of complexity that has not previously been computationally possible.

  10. Geochemical detection of carbon dioxide in dilute aquifers

    SciTech Connect (OSTI)

    Carroll, S; Hao, Y; Aines, R

    2009-03-27

    Carbon storage in deep saline reservoirs has the potential to lower the amount of CO{sub 2} emitted to the atmosphere and to mitigate global warming. Leakage back to the atmosphere through abandoned wells and along faults would reduce the efficiency of carbon storage, possibly leading to health and ecological hazards at the ground surface, and possibly impacting water quality of near-surface dilute aquifers. We use static equilibrium and reactive transport simulations to test the hypothesis that perturbations in water chemistry associated with a CO{sub 2} gas leak into dilute groundwater are important measures for the potential release of CO{sub 2} to the atmosphere. Simulation parameters are constrained by groundwater chemistry, flow, and lithology from the High Plains aquifer. The High Plains aquifer is used to represent a typical sedimentary aquifer overlying a deep CO{sub 2} storage reservoir. Specifically, we address the relationships between CO{sub 2} flux, groundwater flow, detection time and distance. The CO{sub 2} flux ranges from 10{sup 3} to 2 x 10{sup 6} t/yr (0.63 to 1250 t/m{sup 2}/yr) to assess chemical perturbations resulting from relatively small leaks that may compromise long-term storage, water quality, and surface ecology, and larger leaks characteristic of short-term well failure.

  11. Geochemical Data for 95 Thermal and Nonthermal Waters of the...

    Open Energy Info (EERE)

    hydrothermal alterations, and hydrothermal solution chemistry. Authors Fraser E. Goff, Tamsin McCormick, Pat E. Trujillo Jr, Dale A. Counce and Charles O. Grigsby Published...

  12. A Geochemical Model Of The Platanares Geothermal System, Honduras...

    Open Energy Info (EERE)

    concentrations reflect mixed cooling paths. Authors C. J. Janik, A. H. Truesdell, F. Goff, L. Shevenell, M. L. Stallard, P. E. Trujillo Jr and D. Counce Published Journal...

  13. Geochemical characterization of geothermal systems in the Great...

    Open Energy Info (EERE)

    Basin. Development of this database is one of the first steps in understanding the nature of geothermal systems in the Great Basin. Of particular importance in the Great Basin...

  14. GEOCHEMICAL TESTING AND MODEL DEVELOPMENT - RESIDUAL TANK WASTE TEST PLAN

    SciTech Connect (OSTI)

    CANTRELL KJ; CONNELLY MP

    2010-03-09

    This Test Plan describes the testing and chemical analyses release rate studies on tank residual samples collected following the retrieval of waste from the tank. This work will provide the data required to develop a contaminant release model for the tank residuals from both sludge and salt cake single-shell tanks. The data are intended for use in the long-term performance assessment and conceptual model development.

  15. Estimating the spatio-temporal distribution of geochemical parameters...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Office of Science (SC) Country of Publication: United States Language: English Subject: 54 ENVIRONMENTAL SCIENCES; 58 GEOSCIENCES Word Cloud More Like This ...

  16. Monitoring CO2 intrusion and associated geochemical transformations...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Office of Science (SC) Country of Publication: United States Language: English Subject: 54 ENVIRONMENTAL SCIENCES; 58 GEOSCIENCES Word Cloud More Like This ...

  17. A Geochemical Reconnaissance Of The Alid Volcaniccenter And Geothermal...

    Open Energy Info (EERE)

    Robert O. Fournier, Theoderos Tesfai, Wendell A. Duffield, Michael A. Clynne, James G. Smith, Leake Woldegiorgis, Kidane Weldemariam and Gabreab Kahsai Published Journal...

  18. Geochemical Sampling of Thermal Waters in Nevada | Open Energy...

    Open Energy Info (EERE)

    Area (136C), Buffalo Valley (130C), Pumpernickel Valley (Tipton Ranch; 125C), and Smith Creek Valley (119C). Authors Lisa Shevenell and Larry Garside Conference GRC Annual...

  19. A Reconnaissance Geochemical Study Of La Primavera Geothermal...

    Open Energy Info (EERE)

    whereas the water-rich fumaroles are high and central. The Comision Federal de Electricidad de Mexico (CFE) has recently drilled two deep holes at the center of the Sierra...

  20. Factors Controlling The Geochemical Evolution Of Fumarolic Encrustatio...

    Open Energy Info (EERE)

    Smokes (VTTS). The six-factor solution model explains a large proportion (low of 74% for Ni to high of 99% for Si) of the individual element data variance. Although the primary...

  1. Developing a robust geochemical and reactive transport model...

    Office of Scientific and Technical Information (OSTI)

    natural analog site in Chimayo, New Mexico Citation Details In-Document Search ... natural analog site in Chimayo, New Mexico Migration of carbon dioxide (COsub 2) ...

  2. Spatial And Temporal Geochemical Trends In The Hydrothermal System...

    Open Energy Info (EERE)

    tracking changes in river solute flux. Authors Shaul Hurwitz, Jacob B. Lowenstern and Henry Heasler Published Journal Journal of Volcanology and Geothermal Research, 2007 DOI Not...

  3. Hydrologic and Geochemical Monitoring in Long Valley Caldera...

    Open Energy Info (EERE)

    through 1985. The monitoring included the collection of the following types of data: chemical and isotopic composition of waters and gases from springs, wells, and steam vents;...

  4. Self-Organized Pattern Formation in Sedimentary Geochemical Systems...

    Office of Scientific and Technical Information (OSTI)

    Research Org: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States) Sponsoring Org: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22) Country of ...

  5. Coffinitization of Uraninite: SEM/AEM Investigation and Geochemical...

    Office of Scientific and Technical Information (OSTI)

    the coexistence of coffinite with quartz. A kinetic model that takes account of Ostwald processes is thus proposed. The kinetic model indicates that the presence of U(+6) in ...

  6. Estimating the spatio-temporal distribution of geochemical parameters...

    Office of Scientific and Technical Information (OSTI)

    Resource Relation: Journal Name: Water Resources Research; Journal Volume: 48; Journal Issue: 5; Related Information: Journal Publication Date: 2012 Research Org: Ernest Orlando ...

  7. Alteration And Geochemical Zoning In Bodie Bluff, Bodie Mining...

    Open Energy Info (EERE)

    Banded, epithermal quartz-adularia veins have produced about 1.5 million ounces of gold and 7 million ounces of silver from the Bodie mining district, eastern California. The...

  8. Hydrologic and Geochemical Monitoring in Long Valley Caldera...

    Open Energy Info (EERE)

    Differences since 1982 in fluid chemistry of springs has been minor except at Casa Diablo, where rapid fluctuations in chemistry result from near surface boiling and...

  9. Interpretation of Wild 2 Dust Fine Structure: Comparison of Stardust Aluminium Foil Craters to the Three-Dimensional Shape of Experimental Impacts by Artificial Aggregate Particles and Meteorite Powders

    SciTech Connect (OSTI)

    Kearsley, A T; Burchell, M J; Price, M C; Graham, G A; Wozniakiewicz, P J; Cole, M J; Foster, N J; Teslich, N

    2009-12-10

    New experimental results show that Stardust crater morphology is consistent with interpretation of many larger Wild 2 dust grains being aggregates, albeit most of low porosity and therefore relatively high density. The majority of large Stardust grains (i.e. those carrying most of the cometary dust mass) probably had density of 2.4 g cm{sup -3} (similar to soda-lime glass used in earlier calibration experiments) or greater, and porosity of 25% or less, akin to consolidated carbonaceous chondrite meteorites, and much lower than the 80% suggested for fractal dust aggregates. Although better size calibration is required for interpretation of the very smallest impacting grains, we suggest that aggregates could have dense components dominated by {micro}m-scale and smaller sub-grains. If porosity of the Wild 2 nucleus is high, with similar bulk density to other comets, much of the pore-space may be at a scale of tens of micrometers, between coarser, denser grains. Successful demonstration of aggregate projectile impacts in the laboratory now opens the possibility of experiments to further constrain the conditions for creation of bulbous (Type C) tracks in aerogel, which we have observed in recent shots. We are also using mixed mineral aggregates to document differential survival of pristine composition and crystalline structure in diverse fine-grained components of aggregate cometary dust analogues, impacted onto both foil and aerogel under Stardust encounter conditions.

  10. INTERPRETATION REGARDING EXEMPTION RELIEF UNDER 10 C.F.R. PART 820, SUBPART E, EXEMPTION RELIEF, AND NON-COMPLIANT ‘DOCUMENTED SAFETY ANALYSES’ SUBJECT TO 10 C.F.R. PART 830, NUCLEAR SAFETY MANAGEMENT, SUBPART B, SAFETY BASIS REQUIREMENTS

    Broader source: Energy.gov [DOE]

    The following document is the Office of General Counsel (GC) interpretation regarding exemption relief pursuant to 10 C.F.R. Part 820, Procedural Rules for DOE Nuclear Activities, Subpart E,...

  11. Tracers and Tracer Interpretation | Open Energy Information

    Open Energy Info (EERE)

    Component Research and DevelopmentAnalysis Nathrop, CO 1,840,000 460,000 2,300,000 Quantum Dot Tracers for Use in Engineered Geothermal Systems Utah University of Utah Recovery...

  12. ARM - Publications: Science Team Meeting Documents: Interpretation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of cloud structure anomalies over the tropical Pacific during the 199798 El Nino Cess, Robert State University of New York at Stony Brook Sun, Moguo State University of...

  13. EVMS Interpretation Handbook 2.0 Update

    Broader source: Energy.gov [DOE]

    David Kester, Office of Project Management Oversight and Assessments Rick Millikin, CHPRC/EFCOG March 22, 2016

  14. THE 2011 FEBRUARY 15 X2 FLARE, RIBBONS, CORONAL FRONT, AND MASS EJECTION: INTERPRETING THE THREE-DIMENSIONAL VIEWS FROM THE SOLAR DYNAMICS OBSERVATORY AND STEREO GUIDED BY MAGNETOHYDRODYNAMIC FLUX-ROPE MODELING

    SciTech Connect (OSTI)

    Schrijver, Carolus J.; Title, Alan M.; Aulanier, Guillaume; Pariat, Etienne; Delannee, Cecile E-mail: title@lmsal.com E-mail: etienne.pariat@obspm.fr

    2011-09-10

    The 2011 February 15 X2.2 flare and associated Earth-directed halo coronal mass ejection were observed in unprecedented detail with high resolution in spatial, temporal, and thermal dimensions by the Atmospheric Imaging Assembly (AIA) on the Solar Dynamics Observatory, as well as by instruments on the two STEREO spacecraft, then at near-quadrature relative to the Sun-Earth line. These observations enable us to see expanding loops from a flux-rope-like structure over the shearing polarity-inversion line between the central {delta}-spot groups of AR 11158, developing a propagating coronal front ('EIT wave'), and eventually forming the coronal mass ejection moving into the inner heliosphere. The observations support the interpretation that all of these features, including the 'EIT wave', are signatures of an expanding volume traced by loops (much larger than the flux rope only), surrounded by a moving front rather than predominantly wave-like perturbations; this interpretation is supported by previously published MHD models for active-region and global scales. The lateral expansion of the eruption is limited to the local helmet-streamer structure and halts at the edges of a large-scale domain of connectivity (in the process exciting loop oscillations at the edge of the southern polar coronal hole). The AIA observations reveal that plasma warming occurs within the expansion front as it propagates over quiet Sun areas. This warming causes dimming in the 171 A (Fe IX and Fe X) channel and brightening in the 193 and 211 A (Fe XII-XIV) channels along the entire front, while there is weak 131 A (Fe VIII and Fe XXI) emission in some directions. An analysis of the AIA response functions shows that sections of the front running over the quiet Sun are consistent with adiabatic warming; other sections may require additional heating which MHD modeling suggests could be caused by Joule dissipation. Although for the events studied here the effects of volumetric expansion are much more obvious than true wave phenomena, we discuss how different magnetic environments within and around the erupting region can lead to the signatures of either or both of these aspects.

  15. Calendar year 1995 groundwater quality report for the Chestnut Ridge Hydrogeologic Regime Y-12 Plant, Oak Ridge, Tennessee. Part 2: 1995 groundwater quality data interpretations and proposed program modifications

    SciTech Connect (OSTI)

    1996-08-01

    This groundwater quality report (GWQR) contains an evaluation of the groundwater monitoring data obtained during calendar year (CY) 1995 from monitoring wells and springs located at or near several hazardous and non-hazardous waste management facilities associated with the Y-12 Plant. These sites are within the boundaries of the Chestnut Ridge Hydrogeologic Regime, which is one of three hydrogeologic regimes defined for the purposes of the Y-12 Plant Groundwater Protection Program (GWPP). The objectives of the GWPP are to provide the monitoring data necessary for compliance with applicable federal, state, and local regulations, DOE Orders, and Lockheed Martin Energy Systems, Inc. corporate policy. The following evaluation of the data is organized into background regulatory information and site descriptions, an overview of the hydrogeologic framework, a summary of the CY 1995 groundwater monitoring programs and associated sampling and analysis activities, analysis and interpretation of the data for inorganic, organic, and radiological analytes, a summary of conclusions and recommendations, and a list of cited references. Appendix A contains supporting maps, cross sections, diagrams, and graphs; data tables and summaries are in Appendix B. Detailed descriptions of the data screening and evaluation criteria are included in Appendix C.

  16. Neutronics qualification of the Jules Horowitz reactor fuel by interpretation of the VALMONT experimental program - Transposition of the uncertainties on the reactivity of JHR with JEF2.2 and JEFF3.1.1

    SciTech Connect (OSTI)

    Leray, O.; Hudelot, J. P.; Antony, M.; Doederlein, C.; Santamarina, A.; Bernard, D.; Vaglio-Gaudard, C.

    2011-07-01

    The new European material testing Jules Horowitz Reactor (JHR), currently under construction in Cadarache center (CEA France), will use LEU (20% enrichment in {sup 235}U) fuels (U{sub 3}Si{sub 2} for the start up and UMoAl in the future) which are quite different from the industrial oxide fuel, for which an extensive neutronics qualification database has been established. The HORUS3D/N neutronics calculation scheme, used for the design and safety studies of the JHR, is being developed within the framework of a rigorous verification-validation-qualification methodology. In this framework, the experimental VALMONT (Validation of Aluminium Molybdenum uranium fuel for Neutronics) program has been performed in the MINERVE facility of CEA Cadarache (France), in order to qualify the capability of HORUS3D/N to accurately calculate the reactivity of the JHR reactor. The MINERVE facility using the oscillation technique provides accurate measurements of reactivity effect of samples. The VALMONT program includes oscillations of samples of UAl{sub x}/Al and UMo/Al with enrichments ranging from 0.2% to 20% and Uranium densities from 2.2 to 8 g/cm{sup 3}. The geometry of the samples and the pitch of the experimental lattice ensure maximum representativeness with the neutron spectrum expected for JHR. By comparing the effect of the sample with the one of a known fuel specimen, the reactivity effect can be measured in absolute terms and be compared to computational results. Special attention was paid to the rigorous determination and reduction of the experimental uncertainties. The calculational analysis of the VALMONT results was performed with the French deterministic code APOLLO2. A comparison of the impact of the different calculation methods, data libraries and energy meshes that were tested is presented. The interpretation of the VALMONT experimental program allowed the qualification of JHR fuel UMoAl8 (with an enrichment of 19.75% {sup 235}U) by the Minerve-dedicated interpretation tool: PIMS. The effect of energy meshes and evaluations put forward the JEFF3.1.1/SHEM scheme that leads to a better calculation of the reactivity effect of VALMONT samples. Then, in order to quantify the impact of the uncertainties linked to the basic nuclear data, their propagation from the cross section measurement to the final computational result was analysed in a rigorous way by using a nuclear data re-estimation method based on Gauss-Newton iterations. This study concludes that the prior uncertainties due to nuclear data (uranium, aluminium, beryllium and water) on the reactivity of the Begin Of Cycle (BOC) for the JHR core reach 1217 pcm at 2{sigma}. Now, the uppermost uncertainty on the JHR reactivity is due to aluminium. (authors)

  17. CX-001926: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Development of Exploration Methods for Engineered Geothermal Systems through Integrated Geologic, Geophysical, and Geochemical InterpretationCX(s) Applied: A9Date: 04/27/2010Location(s): Dixie Valley, NevadaOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  18. Geochemical character and origin of oils in Ordovician reservoir rock, Illinois and Indiana, USA

    SciTech Connect (OSTI)

    Guthrie, J.M.; Pratt, L.M.

    1995-11-01

    Twenty-three oils produced from reservoirs within the Ordovician Galena Group (Trenton equivalent) and one oil from the Mississippian Ste. Genevieve Limestone in the Illinois and Indiana portions of the Illinois basin are characterized. Two end-member oil groups (1) and (2) and one intermediate group (1A) are identified using conventional carbon isotopic analysis of whole and fractionated oils, gas chromatography (GC) of saturated hydrocarbon fractions, isotope-ratio-monitoring gas chromatography/mass spectrometry (irm-GC/MS) of n-alkanes ranging from C{sub 15} to C{sub 25}, and gas chromatography/mass spectrometry (GC/MS) of the aromatic hydrocarbon fractions. Group 1 is characterized by high odd-carbon predominance in mid-chain n-alkanes (C{sub 15}-C{sub 19}), low abundance Of C{sub 20+}, n-alkanes, and an absence of pristane and phytane. Group IA is characterized by slightly lower odd-carbon predominance of mid-chain n-alkanes, greater abundance of C{sub 20+} n-alkanes compared to group 1, and no pristane and phytane. Conventional correlations of oil to source rock based on carbon isotopic-type curves and hopane (m/z 191) and sterane (m/z 217) distributions are of limited use in distinguishing Ordovician-reservoired oil groups and determining their origin. Oil to source rock correlations using the distribution and carbon isotopic composition of n-alkanes and the m/z 133 chromatograms of n-alkylarenes show that groups 1 and 1A originated from strata of the Upper Ordovician Galena Group. Group 2 either originated solely from the Upper Ordovician Maquoketa Group or from a mixture of oils generated from the Maquoketa Group and the Galena Group. The Mississippian-reservoired oil most likely originated from the Devonian New Albany Group. The use of GC, irm-GC/MS, and GC/MS illustrates the value of integrated molecular and isotopic approaches for correlating oil groups with source rocks.

  19. Petroleum potential of the Upper Ordovician Maquoketa Group in Illinois: A coordinated geological and geochemical study

    SciTech Connect (OSTI)

    Crockett, J.E.; Oltz, D.F. ); Kruge, M.A. )

    1990-05-01

    The Ordovician Maquoketa Group in Illinois, predominantly composed of shale, calcareous shale, and carbonates, has long been considered a potential source for Illinois basin hydrocarbons. Methods used to better define the petroleum potential of the Maquoketa in the Illinois basin were lithostratigraphic study, Rock-Eval (pyrolysis) analyses, comparison of molecular markers from whole-rock extracts and produced oil, and construction of burial history models. Organic-rich submature Maquoketa potential source rocks are present in western Illinois at shallow depths on the basin flank. Deeper in the basin in southern Illinois, Rock-Eval analyses indicate that the Maquoketa shale is within the oil window. Solvent extracts of the Maquoketa from western Illinois closely resemble the Devonian New Albany Shale, suggesting that past studies may have erroneously attributed Maquoketa-generated petroleum to a New Albany source or failed to identify mixed source oils. Subtle differences between Maquoketa and New Albany solvent extracts include differences in pristane/phytane ratios, proportions of steroids, and distribution of dimethyldibenzothiophene isomers. Maquoketa solvent extracts show little resemblance to Middle Ordovician oils from the Illinois or Michigan basins. Lithostratigraphic studies identified localized thick carbonate facies in the Maquoketa, suggesting depositional response to upper Ordovician paleostructures. Sandstone facies in the Maquoketa in southwestern Illinois offer a potential source/trap play, as well as serving as potential carrier beds for hydrocarbon migration. Maquoketa source and carrier beds may feed older Ordovician rocks in faulted areas along and south of the Cottage Grove fault system in southern Illinois.

  20. Geochemical Evaluation of Uranium Fate and Transport Guterl Specialty Steel Site, New York - 12077

    SciTech Connect (OSTI)

    Frederick, Bill; Tandon, Vikas

    2012-07-01

    Between 1948 and 1952, up to 15,875 metric tons (35 million pounds) of natural uranium metal (U) were processed at the former Guterl Specialty Steel Corporation site in Lockport, New York. The resulting dust, thermal scale, mill shavings and associated land disposal contaminated both the facility and on-site soils. Uranium subsequently impacted groundwater and a fully developed plume exists below the site. Site soils are composed of anthropogenic fill and re-worked, glacially-derived native soil. This overburden is underlain by the weathered and fractured Lockport Dolostone bedrock. Shallow groundwater levels fluctuate seasonally and allow groundwater to contact U contaminated soil, which promotes transport. This condition is exemplified through coincident increases in specific conductivity and groundwater levels, which flush soluble constituents in the fill/soil to groundwater during recharge events. In addition, water-level fluctuations affect reduction-oxidation (redox) conditions at the site. The U in soils is subject to wetting and drying cycles that promote oxidation more than stable redox conditions (e.g., dry soil or fully saturated conditions). This oxidizing mechanism increases uranium solubility and mobility. Site groundwater also receives uranium via leaching from near-surface contaminated fill. The strong correlation between nitrate and uranium in groundwater indicates that uranium is mobile where oxidizing conditions occur. Analytical models of contaminant leaching determined that multiple pathways and transport mechanisms govern site risk. Uranium transport to groundwater involves three mechanisms: 1) direct contact of contaminated soil with groundwater, 2) the oxidation-state or chemical valence of uranium, and 3) the leaching of near-surface contamination to groundwater. These mechanisms require an integrated remedial solution that is sustainable and cost effective. (authors)

  1. Water quality evaluation and geochemical assessment of iron, manganese, and arsenic in a landfill site

    SciTech Connect (OSTI)

    Pisigan, R.A. Jr.

    1995-12-31

    Several monitoring wells at a landfill site were sampled for water quality parameters to determine the nature of groundwater contamination. The landfill, located beneath a limestone and dolomitic bedrock, has been used for about 20 years for trash and garbage disposal. The monitoring parameters include major cations and anions, as well as iron, manganese, arsenic, and other parameters measured in the field to characterize the subsurface conditions. Groundwater samples collected near the landfill and downgradient locations had higher levels of iron, manganese, arsenic, alkalinity, hardness than those samples from an upgradient well. The downgradient and on-site samples were also more acidic and turbid, The dissolved oxygen data tend to suggest reducing conditions in the leachate environment. The elevated groundwater concentrations of the three metals, especially iron, were most probably caused by the acidity generated by carbon dioxide and organic acids released from microbial degradation of organic compounds dumped into the landfill. The acidic pH led to the dissolution of iron, manganese, and arsenic bearing mineral phases. The buffering reactions of limestone and dolomite to neutralize the acidic degradation products increased the hardness cations, Ca{sup +2} and Mg{sup +2}. Inorganic speciation modeling indicates that iron, manganese, and arsenic predominantly exist as Fe {sup +2}, Mn{sup +2}, and H{sub 3}AsO{sub 3}. The possible presence of organic complexes of iron was discussed, but could be modeled due to lack of appropriate equilibrium constant data.

  2. Geochemical and Mineralogical Investigation of Uranium in Multielement Contaminated, Organicrich Subsurface Sediment

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Gartman, Brandy N.; Kukkadapu, Ravi K.; Arey, Bruce W.; Williams, Kenneth H.; Mouser, Paula J.; Heald, Steve M.; Bargar, John R.; Janot, Noemie; Yabusaki, Steven B.; Long, Philip E.

    2014-03-02

    Alluvial sediments characterized by an abundance of refractory or lignitic organic carbon compounds and reduced Fe and S bearing mineral phases have been identified through drilling activities at the U.S. Department of Energys (DOE) Integrated Field Research Challenge (IFRC) site at Rifle, CO. Regions of the subsurface from which such sediments are derived are referred to as Naturally Reduced Zones (NRZ). We conducted a study with NRZ sediments with the objective to: i.) Characterize solid phase contamination of U and other co-contaminants; ii.) Document the occurrence of potential U host minerals; iii.) Determine U valence state and micron scale spatial association with co-contaminants. Macroscopic (wet chemical batch extractions and a column experiment), microscopic (SEM-EDS), and spectroscopic (Mssbauer, -XRF and XANES) techniques were employed. Results showed that sediments solid phase had significant concentrations of U, S, As, Zn, V, Cr, Cu and Se, and a remarkable assortment of potential U hosts (sorbents and/or electron donors), such as Fe oxides (hematite, magnetite, Al-substituted goethite), siderite, reduced Fe(II) bearing clays, sulfides of different types, Zn sulfide framboids and multi element sulfides. Multi-contaminants, micron size (ca. 5 to 30 m) areas of mainly U(IV) and some U(VI), and/or other electron scavengers or donors such as Se, As, Cr, and V were discovered in the sediments, suggesting complex micron-scale system responses to transient redox conditions, and different extent and rates of competing U redox reactions than those of single contaminant systems. Collectively, the results improve our understanding and ability to predict U and NRZs complex behavior and will delineate future research directions to further study both the natural attenuation and persistence of contaminant plumes and their contribution to groundwater contamination.

  3. Memo: Quarry Residuals Geochemical Sampling of the Shallow USGS Piezometers in the Saint Charles County Wellfield.

    Office of Legacy Management (LM)

  4. A Geochemical Model of the Kilauea East Rift Zone | Open Energy...

    Open Energy Info (EERE)

    to southwest-trending complex of dikes and fractures extending more than 100 kilometers from the summit caldera to the ocean floor. Geologic, petrologic, and geophysical...

  5. Geological and geochemical aspects of uranium deposits. A selected, annotated bibliography

    SciTech Connect (OSTI)

    Garland, P.A.; Thomas, J.M.; Brock, M.L.; Daniel, E.W.

    1980-06-01

    A bibliography of 479 references encompassing the fields of uranium and thorium geochemistry and mineralogy, geology of uranium deposits, uranium mining, and uranium exploration techniques has been compiled by the Ecological Sciences Information Center of Oak Ridge National Laboratory. The bibliography was produced for the National Uranium Resource Evaluation Program, which is funded by the Grand Junction Office of the Department of Energy. The references contained in the bibliography have been divided into the following eight subject categories: (1) geology of deposits, (2) geochemistry, (3) genesis O deposits, (4) exploration, (5) mineralogy, (6) uranium industry, (7) reserves and resources, and (8) geology of potential uranium-bearing areas. All categories specifically refer to uranium and thorium; the last category contains basic geologic information concerning areas which the Grand Junction Office feels are particularly favorable for uranium deposition. The references are indexed by author, geographic location, quadrangle name, geoformational feature, taxonomic name, and keyword.

  6. Geochemical and Strontium Isotope Characterization of Produced Waters from Marcellus Shale Natural Gas Extraction

    SciTech Connect (OSTI)

    Chapman, Elizabeth C; Capo, Rosemary C.; Stewart, Brian W.; Kirby, Carl S.; Hammack, Richard W.; Schroeder, Karl T.; Edenborn, Harry M.

    2012-03-20

    Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of 375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (ε{sub Sr}{sup SW} = +13.8 to +41.6, where ε{sub Sr}{sup SW} is the deviation of the {sup 87}Sr/{sup 86}Sr ratio from that of seawater in parts per 10{sup 4}); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters.

  7. Geochemical and Strontium Isotope Characterization of Produced Waters from Marcellus Shale Natural Gas Extraction

    SciTech Connect (OSTI)

    Elizabeth C. Chapman,† Rosemary C. Capo,† Brian W. Stewart,*,† Carl S. Kirby,‡ Richard W. Hammack,§ Karl T. Schroeder,§ and Harry M. Edenborn

    2012-02-24

    Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of ∼375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (εSr SW = +13.8 to +41.6, where εSr SW is the deviation of the 87Sr/86Sr ratio from that of seawater in parts per 104); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters.

  8. Coal-type gas provinces in China and their geochemical characteristics

    SciTech Connect (OSTI)

    Zhang Xiaobao; Xu Yonghang; Shen Ping )

    1996-01-01

    The distribution of coal - type gases in China can be divided into the east gas province, the central gas province and the west gas province the east gas province lies in the East China Meso - Cenozoic Rift Belt, including Donghai Basin and Bohaiwan Basin. The ages of gas source rocks are Carbo - Permian and Tertiary. The types of gas reservoirs are a anticline or a hidden mountain - fault block combination reservoir. The CH[sub 4] content ofthe gases there is 83 -90%, with [delta][sup 13]C[sub 1] -35.5 [approximately] -39.9[per thousand], and [delta][sup 13]C[sub 2] -24.0 [approximately] -26.8[per thousand]. The [delta][sup 13]C of condensate oils associated with the gases ranges from -25.4[per thousand] to -26.8[per thousand]. The central gas province is inside the Central China Paleozoic Plates, including Orclos Basin and Sichuan Basin. The gas source rocks are Carbo - Permian and Triassic. The types of gas reservoirs are an anticline-fault combination or a lithological-tectonic combination reservoir. The [delta][sup 13]C[sub 1] of the gases there is -37.9 [approximately] -37. l[per thousand], with the [delta][sup 13]C of condensate oil accompanying them - 25.1 [approximately] -26.6[per thousand]. The west gas province is within the West China Late Paleozoic Intracontinental Compressive Belt, including Tarim Basin, Jungar Basin and Tuna Basin. The age of gas source rocks is Jurassic. The types of gas reservoirs are an anticline or an anticline-fault reservoir. The CH[sub 4] content of the gases there varies from 60 to 90%, with [delta][sup 13]C[sub 1] from - 38.7 to -43.7[per thousand] and [delta] [sup 13]C[sub 2] from -25.9[per thousand] to -29.9[per thousand]. The [delta] [sup 13]C of light oils and condensate oils accompanying the gases changes from 24.3[per thousand] to 27.8[per thousand].

  9. Coal-type gas provinces in China and their geochemical characteristics

    SciTech Connect (OSTI)

    Zhang Xiaobao; Xu Yonghang; Shen Ping

    1996-12-31

    The distribution of coal - type gases in China can be divided into the east gas province, the central gas province and the west gas province the east gas province lies in the East China Meso - Cenozoic Rift Belt, including Donghai Basin and Bohaiwan Basin. The ages of gas source rocks are Carbo - Permian and Tertiary. The types of gas reservoirs are a anticline or a hidden mountain - fault block combination reservoir. The CH{sub 4} content ofthe gases there is 83 -90%, with {delta}{sup 13}C{sub 1} -35.5 {approximately} -39.9{per_thousand}, and {delta}{sup 13}C{sub 2} -24.0 {approximately} -26.8{per_thousand}. The {delta}{sup 13}C of condensate oils associated with the gases ranges from -25.4{per_thousand} to -26.8{per_thousand}. The central gas province is inside the Central China Paleozoic Plates, including Orclos Basin and Sichuan Basin. The gas source rocks are Carbo - Permian and Triassic. The types of gas reservoirs are an anticline-fault combination or a lithological-tectonic combination reservoir. The {delta}{sup 13}C{sub 1} of the gases there is -37.9 {approximately} -37. l{per_thousand}, with the {delta}{sup 13}C of condensate oil accompanying them - 25.1 {approximately} -26.6{per_thousand}. The west gas province is within the West China Late Paleozoic Intracontinental Compressive Belt, including Tarim Basin, Jungar Basin and Tuna Basin. The age of gas source rocks is Jurassic. The types of gas reservoirs are an anticline or an anticline-fault reservoir. The CH{sub 4} content of the gases there varies from 60 to 90%, with {delta}{sup 13}C{sub 1} from - 38.7 to -43.7{per_thousand} and {delta} {sup 13}C{sub 2} from -25.9{per_thousand} to -29.9{per_thousand}. The {delta} {sup 13}C of light oils and condensate oils accompanying the gases changes from 24.3{per_thousand} to 27.8{per_thousand}.

  10. Geochemical Behaviour of S, Cl and Fe in Silicate Melts/Glasses...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    E. Paris, P. Glatzel, S. Eeckhout, M. Carroll, School of Science and Technology, Geology Division, University of Camerino, Via G. III da Varano, 62032 Camerino; e-mail:...

  11. Salt effects on isotope partitioning and their geochemical implications: An overview

    SciTech Connect (OSTI)

    Horita, J.; Cole, D.R.; Fortier, S.M.

    1996-01-01

    Essential to the use of stable isotopes as natural tracers and geothermometers is the knowledge of equilibrium isotope partitioning between different phases and species, which is usually a function of temperature only. The one exception known to date is oxygen and hydrogen isotope fractionation between liquid water and other phases (steam, gases, minerals), which changes upon the addition of salts to water, i.e., the isotope salt salt effect. Our knowledge of this effect, the difference between activity and composition (a-X) of isotopic water molecules in salt solutions, is very limited and controversial, especially at elevated temperatures. For the last several years, we have been conducting a detailed, systematic experimental study at Oak Ridge National Laboratory to determine the isotope salt effects from room temperature to elevated temperatures (currently to 500{degree}C). From this effort, a simple, coherent picture of the isotope salt effect is emerging, that differs markedly from the complex results reported in the literature. In this communication, we present an overview on the isotope salt effect, obtained chiefly from our study. Observed isotope salt effects in salt solutions are significant even at elevated temperatures. The importance and implications of the isotope salt effect for isotopic studies of brine-dominated systems are also discussed in general terms.

  12. Geochemical and Geomechanical Effects on Wellbore Cement Fractures: Data Information for Wellbore Reduced Order Model

    SciTech Connect (OSTI)

    Um, Wooyong; Jung, Hun Bok; Kabilan, Senthil; Suh, Dong-Myung; Fernandez, Carlos A.

    2014-01-01

    The primary objective of the National Risk Assessment Partnership (NRAP) program is to develop a defensible, generalized, and science-based methodology and platform for quantifying risk profiles at CO2 injection and storage sites. The methodology must incorporate and define the scientific basis for assessing residual risks associated with long-term stewardship and help guide site operational decision-making and risk management. Development of an integrated and risk-based protocol will help minimize uncertainty in the predicted long-term behavior of the CO2 storage site and thereby increase confidence in storage integrity. The risk profile concept has proven useful in conveying the qualitative evolution of risks for CO2 injection and storage site. However, qualitative risk profiles are not sufficient for specifying long-term liability for CO2 storage sites. Because there has been no science-based defensible and robust methodology developed for quantification of risk profiles for CO2 injection and storage, NRAP has been focused on developing a science-based methodology for quantifying risk profiles for various risk proxies.

  13. Geochemical Weathering Increases Lead Bioaccessibility in Semi-Arid Mine Tailings

    SciTech Connect (OSTI)

    Hayes, Sarah M.; Webb, Sam M.; Bargar, John R.; O?Day, Peggy A.; Maier, Raina M.; Chorover, Jon

    2012-09-05

    Mine tailings can host elevated concentrations of toxic metal(loid)s that represent a significant hazard to surrounding communities and ecosystems. Eolian transport, capable of translocating small (micrometer-sized) particles, can be the dominant mechanism of toxic metal dispersion in arid or semiarid landscapes. Human exposure to metals can then occur via direct inhalation or ingestion of particulates. The fact that measured doses of total lead (Pb) in geomedia correlate poorly with blood Pb levels highlights a need to better resolve the precise distribution of molecularly speciated metal-bearing phases in the complex particle mixtures. Species distribution controls bioaccessibility, thereby directly impacting health risk. This study seeks to correlate Pb-containing particle size and mineral composition with lability and bioaccessibility in mine tailings subjected to weathering in a semiarid environment. We employed X-ray absorption spectroscopy (XAS) and X-ray fluorescence (XRF), coupled with sequential chemical extractions, to study Pb speciation in tailings from the semiarid Arizona Klondyke State Superfund Site. Representative samples ranging in pH from 2.6 to 5.4 were selected for in-depth study of Pb solid-phase speciation. The principle lead-bearing phase was plumbojarosite (PbFe{sub 6}(SO{sub 4}){sub 4}(OH){sub 12}), but anglesite (PbSO{sub 4}) and iron oxide-sorbed Pb were also observed. Anglesite, the most bioavailable mineral species of lead identified in this study, was enriched in surficial tailings samples, where Pb concentrations in the clay size fraction were 2-3 times higher by mass relative to bulk. A mobile and bioaccessible Pb phase accumulates in surficial tailings, with a corresponding increase in risk of human exposure to atmospheric particles.

  14. Hydrology of the Greater Tongonan geothermal system, Philippines, as deduced from geochemical and isotopic data

    SciTech Connect (OSTI)

    Alvis-Isidro, R.R.; Solana, R.R.; D`amore, F.; Nuti, S.; Gonfiantini, R.

    1993-10-01

    Fluids in the Greater Tongonan geothermal system exhibit a large positive {sup 18}O shift from the Leyte meteoric water line. However, there is also a significant shift in {sup 2}H. The {delta}{sup 2}H-{delta}{sup 18}O plot shows that the geothermal fluids may be derived by the mixing of meteoric water with local magmatic water. The most enriched water in the Greater Tongonan system, in terms of {delta}{sup 18}O, {delta}{sup 2}H and Cl, is comprised of approximately 40% magmatic water. Baseline isotope results support a hydrogeochemical model in which there is increasing meteoric water dilution to the southeast, from Mahiao to Sambaloran and towards Malitbog. The Cl-{delta}{sup 18}O plot confirms that the geothermal fluid in Mahanagdong, further southeast, is distinct from that of the Mahiao-Sambaloran-Malitbog system.

  15. DOE Withdraws Interpretive Rule and Provides Enforcement Guidance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    out the Department's views on the definition of a "showerhead" for purposes of the water conservation standard enacted by Congress in 1992. To provide certainty going...

  16. DEPARTMENT OF ENERGY OFFICE OF GENERAL COUNSEL INTERPRETATION

    Office of Environmental Management (EM)

    1027-92, HAZARD CATEGORIZATION AND ACCIDENT ANALYSIS TECHNIQUES FOR COMPLIANCE WITH ... 1027-92, Hazard Categorization and Accident Analysis Techniques for Compliance with ...

  17. NUCLEAR FORENSICS ANALYSIS CENTER FORENSIC ANALYSIS TO DATA INTERPRETATION

    SciTech Connect (OSTI)

    Nichols, T.

    2011-02-07

    The Nuclear Forensics Analysis Center (NFAC) is part of Savannah River National Laboratory (SRNL) and is one of only two USG National Laboratories accredited to perform nuclear forensic analyses to the requirements of ISO 17025. SRNL NFAC is capable of analyzing nuclear and radiological samples from bulk material to ultra-trace samples. NFAC provides analytical support to the FBI's Radiological Evidence Examination Facility (REEF), which is located within SRNL. REEF gives the FBI the capability to perform traditional forensics on material that is radiological and/or is contaminated. SRNL is engaged in research and development efforts to improve the USG technical nuclear forensics capabilities. Research includes improving predictive signatures and developing a database containing comparative samples.

  18. Interpretation of Water Sample Analysis, Waunita Hot Spring Project...

    Open Energy Info (EERE)

    of Water Sample Analysis, Waunita Hot Spring Project, Gunnison County, Colorado Author R. H. Carpenter Organization Colorado Geological Survey in Cooperation with the U.S....

  19. Ch. III, Interpretation of water sample analyses Waunita Hot...

    Open Energy Info (EERE)

    of water sample analyses Waunita Hot Springs area Gunnison County, Colorado Author R. H. Carpenter Editor T. G. Zacharakis Published Colorado Geological Survey in Cooperation...

  20. Quantitative interpretation of tracer test data | Open Energy...

    Open Energy Info (EERE)

    of tracer test data Abstract Geothermal reinjection is an important part of sustainable management of geothermal resources. Reinjection started out as a method of waste-water...

  1. A Systematic Approach to the Interpretation of Magnetotelluric...

    Open Energy Info (EERE)

    modeling simply cannot be avoided in complex geological environments. Authors Stephen K. Park and Carlos Torres-Verdin Published Journal Journal of Geophysical Research,...

  2. Seismic II over I Drop Test Program results and interpretation

    SciTech Connect (OSTI)

    Thomas, B.

    1993-03-01

    The consequences of non-seismically qualified (Category 2) objects falling and striking essential seismically qualified (Category 1) objects has always been a significant, yet analytically difficult problem, particularly in evaluating the potential damage to equipment that may result from earthquakes. Analytical solutions for impact problems are conservative and available for mostly simple configurations. In a nuclear facility, the [open quotes]sources[close quotes] and [open quotes]targets[close quotes] requiring evaluation are frequently irregular in shape and configuration, making calculations and computer modeling difficult. Few industry or regulatory rules are available on this topic even though it is a source of considerable construction upgrade costs. A drop test program was recently conducted to develop a more accurate understanding of the consequences of seismic interactions. The resulting data can be used as a means to improve the judgment of seismic qualification engineers performing interaction evaluations and to develop realistic design criteria for seismic interactions. Impact tests on various combinations of sources and targets commonly found in one Savannah River Site (SRS) nuclear facility were performed by dropping the sources from various heights onto the targets. This report summarizes results of the Drop Test Program. Force and acceleration time history data are presented as well as general observations on the overall ruggedness of various targets when subjected to impacts from different types of sources.

  3. Seismic II over I Drop Test Program results and interpretation

    SciTech Connect (OSTI)

    Thomas, B.

    1993-03-01

    The consequences of non-seismically qualified (Category 2) objects falling and striking essential seismically qualified (Category 1) objects has always been a significant, yet analytically difficult problem, particularly in evaluating the potential damage to equipment that may result from earthquakes. Analytical solutions for impact problems are conservative and available for mostly simple configurations. In a nuclear facility, the {open_quotes}sources{close_quotes} and {open_quotes}targets{close_quotes} requiring evaluation are frequently irregular in shape and configuration, making calculations and computer modeling difficult. Few industry or regulatory rules are available on this topic even though it is a source of considerable construction upgrade costs. A drop test program was recently conducted to develop a more accurate understanding of the consequences of seismic interactions. The resulting data can be used as a means to improve the judgment of seismic qualification engineers performing interaction evaluations and to develop realistic design criteria for seismic interactions. Impact tests on various combinations of sources and targets commonly found in one Savannah River Site (SRS) nuclear facility were performed by dropping the sources from various heights onto the targets. This report summarizes results of the Drop Test Program. Force and acceleration time history data are presented as well as general observations on the overall ruggedness of various targets when subjected to impacts from different types of sources.

  4. Fluid Inclusion Stratigraphy: Interpretation of New Wells in...

    Open Energy Info (EERE)

    to moderate producers, problem producers, injectors, and non producers Authors Dilley, L.M.; Newman, D.L. ; McCulloch, J.; Wiggett and G. Published Geothermal Resource Council...

  5. Interpretation of chemical analyses of waters collected from...

    Open Energy Info (EERE)

    chemical analyses of waters collected from two geothermal wells at Coso, California Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  6. Interpretation of AIRS Data in Thin Cirrus Atmospheres Based...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Szu-cheng University of California, Los Angeles Kahn, Brian Jet Propulsion Laboratory Yang, Ping Texas A&M Mace, Gerald University of Utah Category: Radiation A thin cirrus cloud...

  7. Chemical analyses and preliminary interpretation of waters collected...

    Open Energy Info (EERE)

    system appears to be a hot water type. The surface expression of fumarole and acid sulfate pools and shallow steam wells gives a false indication of an extensive vapor...

  8. Remote Sensing- Principles And Interpretation | Open Energy Informatio...

    Open Energy Info (EERE)

    Geothermal Exploration Activities Activities (1) Thermal And-Or Near Infrared At Raft River Geothermal Area (1997) Areas (1) Raft River Geothermal Area Regions (0) Retrieved...

  9. A Lagrangian Interpretation of 3D Tropical Cloud Structure: ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Retrievals with Satellite Data A. M. Vogelmann, K. L. Johnson, M. P. Jensen, M. A. Miller, and M. J. Bartholomew Brookhaven National Laboratory Upton, New York M. P. Jensen...

  10. Structural interpretation of the Coso geothermal field. Summary...

    Open Energy Info (EERE)

    example of a structurally controlled geothermal resource. Authors Austin, C.F.; Moore and J.L. Published Publisher Not Provided, 911987 DOI Not Provided Check for DOI...

  11. Structural interpretation of Coso Geothermal field, Inyo County...

    Open Energy Info (EERE)

    to be completed with power on line by mid-1987. Authors Austin, C.F.; Bishop, B.P.; Moore and J. Published Journal AAPG Bulletin (American Association of Petroleum Geologists);...

  12. 3-D Interpretation Of Magnetotelluric Data At The Bajawa Geothermal...

    Open Energy Info (EERE)

    modeling was by the finite difference scheme. The sensitivity matrix was computed once for a homogeneous half space and used at all iterations to save the computation time....

  13. Interpretive geothermal heat flow map of Colorado | Open Energy...

    Open Energy Info (EERE)

    geothermal heat flow map of ColoradoInfo GraphicMapChart Authors F.E. Berkman and C.J. Carroll Published Colorado Geological Survey Map Series, 2007 DOI Not Provided Check...

  14. Interpretation of earth tide response of three deep, confined...

    Open Energy Info (EERE)

    sfrom earth tide response. Except for the fact that barometric changes act both on the water surface in the well and on the aquifer as a whole while stress changes associated...

  15. Physical interpretation of Jeans instability in quantum plasmas

    SciTech Connect (OSTI)

    Akbari-Moghanjoughi, M.

    2014-08-15

    In this paper, we use the quantum hydrodynamics and its hydrostatic limit to investigate the newly posed problem of Jeans instability in quantum plasmas from a different point of view in connection with the well-known Chandrasekhar mass-limit on highly collapsed degenerate stellar configurations. It is shown that the hydrodynamic stability of a spherically symmetric uniform quantum plasma with a given fixed mass is achieved by increase in its mass-density or decrease in the radius under the action of gravity. It is also remarked that for masses beyond the limiting Jeans-mass, the plasma becomes completely unstable and the gravitational collapse would proceed forever. This limiting mass is found to depend strongly on the composition of the quantum plasma and the atomic-number of the constituent ions, where it is observed that heavier elements rather destabilize the quantum plasma hydrodynamically. It is also shown that the Chandrasekhar mass-limit for white dwarf stars can be directly obtained from the hydrostatic limit of our model.

  16. A challenging interpretation of a hexagonally layered protein...

    Office of Scientific and Technical Information (OSTI)

    Authors: Thompson, Michael C. ; Yeates, Todd O., E-mail: yeates@mbi.ucla.edu 1 + Show Author Affiliations UCLA, Los Angeles, CA 90095 (United States) Publication Date: 2014-01-01 ...

  17. RANDOM BALLISTIC INTERPRETATION OF NONLINEAR GUIDING CENTER THEORY

    SciTech Connect (OSTI)

    Ruffolo, D.; Pianpanit, T.; Matthaeus, W. H.; Chuychai, P. E-mail: th_ee@hotmail.com E-mail: p.chuychai@sci.mfu.ac.th

    2012-03-10

    Nonlinear guiding center (NLGC) theory has been used to explain the asymptotic perpendicular diffusion coefficient {kappa} of energetic charged particles in a turbulent magnetic field, which can be applied to better understand cosmic ray transport. Here we re-derive NLGC, replacing the assumption of diffusive decorrelation with random ballistic decorrelation (RBD), which yields an explicit formula for {kappa} . We note that scattering processes can cause a reversal of the guiding center motion along the field line, i.e., 'backtracking', leading to partial cancellation of contributions to {kappa}, especially for low-wavenumber components of the magnetic turbulence. We therefore include a heuristic backtracking correction (BC) that can be used in combination with RBD. In comparison with computer simulation results for various cases, NLGC with RBD and BC provides a substantially improved characterization of the perpendicular diffusion coefficient for a fluctuation amplitude less than or equal to the large-scale magnetic field.

  18. PROCESS MONITORING FOR SAFEGUARDS VIA EVENT GENERATION, INTEGRATION, AND INTERPRETATION

    SciTech Connect (OSTI)

    Humberto E. Garcia; Wen-Chiao Lin; Tae-Sic Yoo

    2010-07-01

    There is a recognized safeguards benefit from using process monitoring (PM) on nuclear facilities to complement nuclear materials accountancy. We introduce a model-based approach for PM in which the assessment regarding the state of the monitored system is conducted at a system-centric level. The proposed architecture integrates both time-driven and event-driven data integration and analysis for decision-making. While the time-driven layers of the proposed architecture encompass more traditional PM methods based on time series data and analysis, the event-driven layers encompass operation monitoring methods based on discrete event data integration and analysis. By integrating process- and operation-related information and methodologies within an unified modeling and monitoring framework that includes not only current but also past plant behaviors, the task of anomaly detection is greatly improved because this decision-making approach can benefit from not only known time-series relationships among measured signals but also from known event sequence relationships among generated events. Building from the proposed system-centric PM architecture, we briefly introduce methods that can be used to implement its different components. The application of the proposed approach is then demonstrated via simulation experiments.

  19. ElectroChemical Noise Data Acquistion and Interpretation

    Energy Science and Technology Software Center (OSTI)

    2000-01-14

    This software is part of an effort to develop an effective measurement method, using electrochemical noise techniques, to differentiate localized pitting corrosion from general uniform corrosion. It is designed to obtain the electrochemical noise signal from in-situ electrochemical probes in a pipeline and convert the signal from a time-domain to a frequency domain by using a Fourier transform. The converted signal, named "power spectral density'', is then further used to calculate the value of characteristicmore » parameters which describe the mechanism and progress of a corrosion process. The results obtained from this software enable one to differentiate localized pitting corrosion from general uniform corrosion attack in a utility pipeline.« less

  20. Erratum: "Sensitivity of the interpretation of the experimental...

    Office of Scientific and Technical Information (OSTI)

    5; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA) Country of Publication: United States Language: English Subject: 70 ...

  1. Sensitivity of the interpretation of the experimental ion thermal...

    Office of Scientific and Technical Information (OSTI)

    4; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA) Country of Publication: United States Language: English Subject: 70 ...

  2. DEPARTMENT OF ENERGY OFFICE OF GENERAL COUNSEL INTERPRETATION...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of any DOE Nuclear Safety Requirement or relieve the contractor of its duty to comply. ... For purposes of the assessment of civil penalties, the definition of DOE Nuclear Safety ...

  3. Laboratory Experiments and Modeling for Interpreting Field Studies...

    Office of Scientific and Technical Information (OSTI)

    Much of the first year of this grant was focused on preparations for GVAX. That campaign was cancelled due to political reasons and with the consultation with our program manager, ...

  4. Oil and gas leasing in proposed wilderness areas: the Wyoming District Court's interpretation of Section 603 of the Federal Land Policy Management Act of 1976 - Rocky Mountain Oil and Gas Association v. Andrus, 500 F. Supp. 1338 (D. Wyo. 1980), appeal docketed, No. 81-1040 (10th Cir. Jan. 5, 1981)

    SciTech Connect (OSTI)

    Corbett, H.E.

    1982-01-01

    Plaintiff Rocky Mountain Oil and Gas Association, a non-profit trade association, brought suit against the Secretary of the Interior, challenging land management policies of the Department of the Interior which plaintiff contended have effectively prohibited oil and gas exploration in areas proposed as wilderness under the Federal Land Policy Management Act of 1976 (FLPMA). The principal issue at trial was Interior's interpretation of the wilderness study provisions contained in Section 603 of the Act, which directed that activities on oil and gas leases in proposed wilderness areas be managed so as to prevent impairment of wilderness values. The United States Court for the District of Wyoming, Kerr, J., held that strict application of the non-impairment standard of Section 603, FLPMA, by the Department of the Interior virtually halted oil and gas exploration in proposed wilderness areas, and is therefore statutorily erroneous, clearly contrary to Congressional intent, and counter-productive to public interest. The Trial Court's decision is being appealed to the Tenth Circuit Court of Appeals under the title Rocky Mountain Oil and Gas Association v. Watt. 91 references.

  5. Aerial photographic interpretation of lineaments and faults in late cenozoic deposits in the Eastern part of the Benton Range 1:100,000 quadrangle and the Goldfield, Last Chance Range, Beatty, and Death Valley Junction 1:100,000 quadrangles, Nevada and California

    SciTech Connect (OSTI)

    Reheis, M.C.; Noller, J.S.

    1991-09-01

    Lineaments and faults in Quaternary and late Tertiary deposits in the southern part of the Walker Lane are potentially active and form patterns that are anomalous with respect to the typical fault patterns in most of the Great Basin. Little work has been done to identify and characterize these faults, with the exception of those in the Death Valley-Furnace Creek (DVFCFZ) fault system and those in and near the Nevada Test Site. Four maps at a scale of 1:100,000 summarize the existing knowledge about these lineaments and faults based on extensive aerial-photo interpretation, limited field investigations, and published geologic maps. The lineaments and faults in all four maps can be divided geographically into two groups. The first group includes west- to north-trending lineaments and faults associated with the DVFCFZ and with the Pahrump fault zone in the Death Valley Junction quadrangle. The second group consists of north- to east-northeast-trending lineaments and faults in a broad area that lies east of the DVFCFZ and north of the Pahrump fault zone. Preliminary observations of the orientations and sense of slip of the lineaments and faults suggest that the least principle stress direction is west-east in the area of the first group and northwest-southeast in the area of the second group. The DVFCFZ appears to be part of a regional right-lateral strike-slip system. The DVFCFZ steps right, accompanied by normal faulting in an extensional zone, to the northern part of the Walker Lane a the northern end of Fish Lake Valley (Goldfield quadrangle), and appears to step left, accompanied by faulting and folding in a compressional zone, to the Pahrump fault zone in the area of Ash Meadows (Death Valley Junction quadrangle). 25 refs.

  6. Categorical Exclusion Determinations: B5.23 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hawthorne Charging Station at Lady Bird Park Rest Area Award Number: DE-EE0006992 CX(s) ... Hawthorne Charging Station at Lady Bird Park Rest Area Award Number: DE-EE0006992 CX(s) ...

  7. FE Categorical Exclusions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ENI USA Gas Marketing, LLC CX(s) Applied: B5.7 Date: 04142015 Location(s): Multiple ... ENI USA Gas Marketing, LLC CX(s) Applied: B5.7 Date: 04142015 Location(s): Multiple ...

  8. Categorical Exclusion Determinations: North Dakota | Department...

    Energy Savers [EERE]

    ... Carbon Dioxide Storage Efficiency in Deep Saline Formations CX(s) Applied: A9 Date: 0423... University of North Dakota- Novel Dry Cooling Technology for Power Plants CX(s) Applied: ...

  9. Categorical Exclusion Determinations: Naval Nuclear Propulsion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Naval Reactors Facility (NRF) Storm Sewer West Main Replacement Project CX(s) Applied: ... Kesselring Site Gate 5 Project CX(s) Applied: B1.15 Date: 06052015 Location(s): None ...

  10. Categorical Exclusion Determinations: Indiana | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plant Award Number: DE-EE0006244 CX(s) Applied: A9, B3.6 Bioenergy Technology Office ... Award Number: DE-EE0006210 CX(s) Applied: B5.1, B5.17 Weatherization & ...

  11. Categorical Exclusion Determinations: B1.23 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    E-Area Trailer and Handy House Demolition and Removal CX(s) Applied: B1.23 Date: 0520... Demolish and Dispose of Shed Located East of Test Reactor Area-607 CX(s) Applied: B1.23 ...

  12. Categorical Exclusion Determinations: Office of River Protection...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CHPRC Cleanup Actions CX(s) Applied: B6.1 Date: 41849 Location(s): Washington Offices(s): ... Waste Site Retrieval Pilot Project CX(s) Applied: B3.6 Date: 07092014 Location(s): ...

  13. Categorical Exclusion Determinations: Fossil Energy | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ConocoPhillips Alaska Natural Gas Corporation CX(s) Applied: B5.7 Date: 242016 ... Bear Head LNG Corporation and Bear Head LNG (USA) CX(s) Applied: B5.7 Date: 1282016 ...

  14. Categorical Exclusion Determinations: Advanced Technology Vehicles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reequipping and Engineering CX(s) Applied: B1.31, B5.1 Date: 09062011 ... Aptera All-Electric and Hybrid Electric Vehicles CX(s) Applied: B1.31, B5.1 Date: 0620...

  15. Appendix HYDRO: Hydrological Investigations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HYDRO-2014 Hydrological Investigations United States Department of Energy Waste Isolation Pilot Plant Carlsbad Field Office Carlsbad, New Mexico Compliance Recertification Application 2014 Appendix HYDRO-2014 Table of Contents HYDRO-1.0 Hydrological Studies HYDRO-2.0 Optimization of Culebra Monitoring Well Network HYDRO-3.0 Geochemical Analyses HYDRO-4.0 Steel-Cased Well Reconfiguration and Replacement HYDRO-5.0 Geological Information HYDRO-6.0 Hydraulic Test Interpretation HYDRO-7.0 Monitoring

  16. Quantification of Hydrological, Geochemical, and Mineralogical Processes Governing the Fate and Transport of Uranium over Multiple Scales in Hanford Sediments

    SciTech Connect (OSTI)

    Mayes, Melanie A.; Perfect, Edmund; van den Berg, Elmer; Parker, Jack C.; Jardine, Philip M.; Tang, Guoping; Fendorf, Scott

    2006-11-15

    A long-term measure of the DOE Environmental Remediation Sciences Division is to provide sufficient scientific understanding to allow a significant fraction of DOE sites to incorporate coupled biological, chemical, and physical processes into decision making for environmental remediation and long-term stewardship by 2015. Our research targets two related, major obstacles to understanding and predicting contaminant transport at DOE sites: the heterogeneity of subsurface geologic media, and the scale dependence of experimental and modeled results.

  17. Geochemical, mineralogical and microbiological characteristics of sediment from a naturally reduced zone in a uranium-contaminated aquife

    SciTech Connect (OSTI)

    Campbell, K M; K Kukkadapu, R K; Qafoku, N P; Peacock, A D; Lesher, E; Williams, K H; Bargar, J R; Wilkins, M J; Figueroa, L; Ranville, J; Davis, J A; Long, P E

    2012-05-23

    Localized zones or lenses of naturally reduced sediments have the potential to play a significant role in the fate and transport of redox-sensitive metals and metalloids in aquifers. To assess the mineralogy, microbiology and redox processes that occur in these zones, several cores from a region of naturally occurring reducing conditions in a U-contaminated aquifer (Rifle, CO) were examined. Sediment samples from a transect of cores ranging from oxic/suboxic Rifle aquifer sediment to naturally reduced sediment were analyzed for U and Fe content, oxidation state, and mineralogy; reduced S phases; and solid-phase organic C content using a suite of analytical and spectroscopic techniques on bulk sediment and size fractions. Solid-phase U concentrations were higher in the naturally reduced zone, with a high proportion of the U present as U(IV). The sediments were also elevated in reduced S phases and Fe(II), indicating it is very likely that U(VI), Fe(III), and SO4 reduction has occurred or is occurring in the sediment. The microbial community was assessed using lipid- and DNA-based techniques, and statistical redundancy analysis was performed to determine correlations between the microbial community and the geochemistry. Increased concentrations of solid-phase organic C and biomass in the naturally reduced sediment suggests that natural bioreduction is stimulated by a zone of increased organic C concentration associated with fine-grained material and lower permeability to groundwater flow. Characterization of the naturally bioreduced sediment provides an understanding of the natural processes that occur in the sediment under reducing conditions and how they may impact natural attenuation of radionuclides and other redox sensitive materials. Results also suggest the importance of recalcitrant organic C for maintaining reducing conditions and U immobilization.

  18. Assessment of Geochemical Environment for the Proposed INL Remote-Handled Low-Level Waste Disposal Facility

    SciTech Connect (OSTI)

    D. Craig Cooper

    2011-11-01

    Conservative sorption parameters have been estimated for the proposed Idaho National Laboratory Remote-Handled Low-Level Waste Disposal Facility. This analysis considers the influence of soils, concrete, and steel components on water chemistry and the influence of water chemistry on the relative partitioning of radionuclides over the life of the facility. A set of estimated conservative distribution coefficients for the primary media encountered by transported radionuclides has been recommended. These media include the vault system, concrete-sand-gravel mix, alluvium, and sedimentary interbeds. This analysis was prepared to support the performance assessment required by U.S. Department of Energy Order 435.1, 'Radioactive Waste Management.' The estimated distribution coefficients are provided to support release and transport calculations of radionuclides from the waste form through the vadose zone. A range of sorption parameters are provided for each key transport media, with recommended values being conservative. The range of uncertainty has been bounded through an assessment of most-likely-minimum and most-likely-maximum distribution coefficient values. The range allows for adequate assessment of mean facility performance while providing the basis for uncertainty analysis.

  19. Predictive modeling of CO{sub 2} sequestration in deep saline sandstone reservoirs: Impacts of geochemical kinetics

    SciTech Connect (OSTI)

    Balashov, Victor N.; Guthrie, George D.; Hakala, J. Alexandra; Lopano, Christina L. J.; Rimstidt, Donald; Brantley, Susan L.

    2013-03-01

    One idea for mitigating the increase in fossil-fuel generated CO{sub 2} in the atmosphere is to inject CO{sub 2} into subsurface saline sandstone reservoirs. To decide whether to try such sequestration at a globally significant scale will require the ability to predict the fate of injected CO{sub 2}. Thus, models are needed to predict the rates and extents of subsurface rock-water-gas interactions. Several reactive transport models for CO{sub 2} sequestration created in the last decade predicted sequestration in sandstone reservoirs of ~17 to ~90 kg CO{sub 2} m{sup -3|. To build confidence in such models, a baseline problem including rock + water chemistry is proposed as the basis for future modeling so that both the models and the parameterizations can be compared systematically. In addition, a reactive diffusion model is used to investigate the fate of injected supercritical CO{sub 2} fluid in the proposed baseline reservoir + brine system. In the baseline problem, injected CO{sub 2} is redistributed from the supercritical (SC) free phase by dissolution into pore brine and by formation of carbonates in the sandstone. The numerical transport model incorporates a full kinetic description of mineral-water reactions under the assumption that transport is by diffusion only. Sensitivity tests were also run to understand which mineral kinetics reactions are important for CO{sub 2} trapping. The diffusion transport model shows that for the first ~20 years after CO{sub 2} diffusion initiates, CO{sub 2} is mostly consumed by dissolution into the brine to form CO{sub 2,aq} (solubility trapping). From 20-200 years, both solubility and mineral trapping are important as calcite precipitation is driven by dissolution of oligoclase. From 200 to 1000 years, mineral trapping is the most important sequestration mechanism, as smectite dissolves and calcite precipitates. Beyond 2000 years, most trapping is due to formation of aqueous HCO{sub 3}{sup -}. Ninety-seven percent of the maximum CO{sub 2} sequestration, 34.5 kg CO{sub 2} per m{sup 3} of sandstone, is attained by 4000 years even though the system does not achieve chemical equilibrium until ~25,000 years. This maximum represents about 20% CO{sub 2} dissolved as CO{sub 2},aq, 50% dissolved as HCO{sub 3}{sup -}{sub ,aq}, and 30% precipitated as calcite. The extent of sequestration as HCO{sub 3}{sup -} at equilibrium can be calculated from equilibrium thermodynamics and is roughly equivalent to the amount of Na+ in the initial sandstone in a soluble mineral (here, oligoclase). Similarly, the extent of trapping in calcite is determined by the amount of Ca2+ in the initial oligoclase and smectite. Sensitivity analyses show that the rate of CO{sub 2} sequestration is sensitive to the mineral-water reaction kinetic constants between approximately 10 and 4000 years. The sensitivity of CO{sub 2} sequestration to the rate constants decreases in magnitude respectively from oligoclase to albite to smectite.

  20. Geochemical, metagenomic and metaproteomic insights into trace metal utilization by methane-oxidizing microbial consortia in sulphidic marine sediments

    SciTech Connect (OSTI)

    Glass, DR. Jennifer; Yu, DR. Hang; Steele, Joshua; Dawson, Katherine; Sun, S; Chourey, Karuna; Pan, Chongle; Hettich, Robert {Bob} L; Orphan, V

    2013-01-01

    Microbes have obligate requirements for trace metals in metalloenzymes that catalyse important biogeochemical reactions. In anoxic methane- and sulphiderich environments, microbes may have unique adaptations for metal acquisition and utilization because of decreased bioavailability as a result of metal sulphide precipitation. However, micronutrient cycling is largely unexplored in cold ( 10 C) and sulphidic (> 1 mM H2S) deep-sea methane seep ecosystems. We investigated trace metal geochemistry and microbial metal utilization in methane seeps offshore Oregon and California, USA, and report dissolved concentrations of nickel (0.5 270 nM), cobalt (0.5 6 nM), molybdenum (10 5600 nM) and tungsten (0.3 8 nM) in Hydrate Ridge sediment porewaters. Despite low levels of cobalt and tungsten, metagenomic and metaproteomic data suggest that microbial consortia catalysing anaerobic oxidation of methane (AOM) utilize both scarce micronutrients in addition to nickel and molybdenum. Genetic machinery for cobalt-containing vitamin B12 biosynthesis was present in both anaerobic methanotrophic archaea (ANME) and sulphate-reducing bacteria. Proteins affiliated with the tungsten-containing form of formylmethanofuran dehydrogenase were expressed in ANME from two seep ecosystems, the first evidence for expression of a tungstoenzyme in psychrophilic microorganisms. Overall, our data suggest that AOM consortia use specialized biochemical strategies to overcome the challenges of metal availability in sulphidic environments.

  1. Hanford 100-N Area In Situ Apatite and Phosphate Emplacement by Groundwater and Jet Injection: Geochemical and Physical Core Analysis

    SciTech Connect (OSTI)

    Szecsody, James E.; Vermeul, Vincent R.; Fruchter, Jonathan S.; Williams, Mark D.; Rockhold, Mark L.; Qafoku, Nikolla; Phillips, Jerry L.

    2010-07-01

    The purpose of this study is to evaluate emplacement of phosphate into subsurface sediments in the Hanford Site 100-N Area by two different technologies: groundwater injection of a Ca-citrate-PO4 solution and water-jet injection of sodium phosphate and/or fish-bone apatite. In situ emplacement of phosphate and apatite adsorbs, then incorporates Sr-90 into the apatite structure by substitution for calcium. Overall, both technologies (groundwater injection of Ca-citrate-PO4) and water-jet injection of sodium phosphate/fish-bone apatite) delivered sufficient phosphate to subsurface sediments in the 100-N Area. Over years to decades, additional Sr-90 will incorporate into the apatite precipitate. Therefore, high pressure water jetting is a viable technology to emplace phosphate or apatite in shallow subsurface sediments difficult to emplace by Ca-citrate-PO4 groundwater injections, but further analysis is needed to quantify the relevant areal extent of phosphate deposition (in the 5- to 15-ft distance from injection points) and cause of the high deposition in finer grained sediments.

  2. Geochemical, metagenomic and metaproteomic insights into trace metal utilization by methane-oxidizing microbial consortia in sulfidic marine sediments

    SciTech Connect (OSTI)

    Glass, DR. Jennifer; Yu, DR. Hang; Steele, Joshua; Dawson, Katherine; Sun, S; Chourey, Karuna; Hettich, Robert {Bob} L; Orphan, V

    2014-01-01

    Microbes have obligate requirements for trace metals in metalloenzymes that catalyze important biogeochemical reactions. In anoxic methane- and sulfide-rich environments, microbes may have unique adaptations for metal acquisition and utilization due to decreased bioavailability as a result of metal sulfide precipitation. However, micronutrient cycling is largely unexplored in cold ( 10 C) and sulfidic (>1 mM H2S) deep-sea methane seep ecosystems. We investigated trace metal geochemistry and microbial metal utilization in methane seeps offshore Oregon and California, USA, and report dissolved concentrations of nickel (0.5-270 nM), cobalt (0.5-6 nM), molybdenum (10-5,600 nM) and tungsten (0.3-8 nM) in Hydrate Ridge sediment porewaters. Despite low levels of cobalt and tungsten, metagenomic and metaproteomic data suggest that microbial consortia catalyzing anaerobic oxidation of methane utilize both scarce micronutrients in addition to nickel and molybdenum. Genetic machinery for cobalt-containing vitamin B12 biosynthesis was present in both anaerobic methanotrophic archaea (ANME) and sulfate-reducing bacteria (SRB). Proteins affiliated with the tungsten-containing form of formylmethanofuran dehydrogenase were expressed in ANME from two seep ecosystems, the first evidence for expression of a tungstoenzyme in psychrotolerant microorganisms. Finally, our data suggest that chemical speciation of metals in highly sulfidic porewaters may exert a stronger influence on microbial bioavailability than total concentration

  3. Geochemical Analyses of Surface and Shallow Gas Flux and Composition Over a Proposed Carbon Sequestration Site in Eastern Kentucky

    SciTech Connect (OSTI)

    Thomas Parris; Michael Solis; Kathryn Takacs

    2009-12-31

    Using soil gas chemistry to detect leakage from underground reservoirs (i.e. microseepage) requires that the natural range of soil gas flux and chemistry be fully characterized. To meet this need, soil gas flux (CO{sub 2}, CH{sub 4}) and the bulk (CO{sub 2}, CH{sub 4}) and isotopic chemistry ({delta}{sup 13}C-CO2) of shallow soil gases (<1 m, 3.3 ft) were measured at 25 locations distributed among two active oil and gas fields, an active strip mine, and a relatively undisturbed research forest in eastern Kentucky. The measurements apportion the biologic, atmospheric, and geologic influences on soil gas composition under varying degrees of human surface disturbance. The measurements also highlight potential challenges in using soil gas chemistry as a monitoring tool where the surface cover consists of reclaimed mine land or is underlain by shallow coals. For example, enrichment of ({delta}{sup 13}C-CO2) and high CH{sub 4} concentrations in soils have been historically used as indicators of microseepage, but in the reclaimed mine lands similar soil chemistry characteristics likely result from dissolution of carbonate cement in siliciclastic clasts having {delta}{sup 13}C values close to 0{per_thousand} and degassing of coal fragments. The gases accumulate in the reclaimed mine land soils because intense compaction reduces soil permeability, thereby impeding equilibration with the atmosphere. Consequently, the reclaimed mine lands provide a false microseepage anomaly. Further potential challenges arise from low permeability zones associated with compacted soils in reclaimed mine lands and shallow coals in undisturbed areas that might impede upward gas migration. To investigate the effect of these materials on gas migration and composition, four 10 m (33 ft) deep monitoring wells were drilled in reclaimed mine material and in undisturbed soils with and without coals. The wells, configured with sampling zones at discrete intervals, show the persistence of some of the aforementioned anomalies at depth. Moreover, high CO{sub 2} concentrations associated with coals in the vadose zone suggest a strong affinity for adsorbing CO{sub 2}. Overall, the low permeability of reclaimed mine lands and coals and CO2 adsorption by the latter is likely to reduce the ability of surface geochemistry tools to detect a microseepage signal.

  4. Coal fly ash interaction with environmental fluids: Geochemical and strontium isotope results from combined column and batch leaching experiments

    SciTech Connect (OSTI)

    Brubaker, Tonya M.; Stewart, Brian W.; Capo, Rosemary C.; Schroeder, Karl T.; Chapman, Elizabeth C.; Spivak-Birndorf, Lev J.; Vesper, Dorothy J.; Cardone, Carol R.; Rohar, Paul C.

    2013-05-01

    The major element and Sr isotope systematics and geochemistry of coal fly ash and its interactions with environmental waters were investigated using laboratory flow-through column leaching experiments (sodium carbonate, acetic acid, nitric acid) and sequential batch leaching experiments (water, acetic acid, hydrochloric acid). Column leaching of Class F fly ash samples shows rapid release of most major elements early in the leaching procedure, suggesting an association of these elements with soluble and surface bound phases. Delayed release of certain elements (e.g., Al, Fe, Si) signals gradual dissolution of more resistant silicate or glass phases as leaching continues. Strontium isotope results from both column and batch leaching experiments show a marked increase in {sup 87}Sr/{sup 86}Sr ratio with continued leaching, yielding a total range of values from 0.7107 to 0.7138. For comparison, the isotopic composition of fluid output from a fly ash impoundment in West Virginia falls in a narrow range around 0.7124. The experimental data suggest the presence of a more resistant, highly radiogenic silicate phase that survives the combustion process and is leached after the more soluble minerals are removed. Strontium isotopic homogenization of minerals in coal does not always occur during the combustion process, despite the high temperatures encountered in the boiler. Early-released Sr tends to be isotopically uniform; thus the Sr isotopic composition of fly ash could be distinguishable from other sources and is a useful tool for quantifying the possible contribution of fly ash leaching to the total dissolved load in natural surface and ground waters.

  5. Liquid Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    Exploration Group: Geochemical Techniques Exploration Sub Group: Geochemical Data Analysis Parent Exploration Technique: Geothermometry Information Provided by Technique...

  6. Gas Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    Exploration Group: Geochemical Techniques Exploration Sub Group: Geochemical Data Analysis Parent Exploration Technique: Geothermometry Information Provided by Technique...

  7. Isotope Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    Exploration Group: Geochemical Techniques Exploration Sub Group: Geochemical Data Analysis Parent Exploration Technique: Geothermometry Information Provided by Technique...

  8. CX-008684: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Metaline Radio Station Upgrade Project CX(s) Applied: B1.19 Date: 07/11/2012 Location(s): Washington Offices(s): Bonneville Power Administration

  9. CX-100327 Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-100327 Categorical Exclusion Determination Proposed Rulemaking for Energy Conservation Standards for Commercial Water Heating Equipment RIN: 1904-AD34 CX(s)...

  10. Categorical Exclusion Determinations: B4.9 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    September 24, 2014 CX-012808: Categorical Exclusion Determination LURR 20140504 Ross Substation Comcast Fiber Installation CX(s) Applied: B4.9 Date: 41906 Location(s): ...

  11. CX-007382: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Compressed Natural Gas Manufacturing CX(s) Applied: B5.1 Date: 10/26/2011 Location(s): Wisconsin Offices(s): Golden Field Office

  12. CX-007650: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Control Room Consolidation CX(s) Applied: B2.2 Date: 12/29/2011 Location(s): South Carolina Offices(s): Savannah River Operations Office

  13. CX-011531: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Targhee Substation Land Acquisition CX(s) Applied: B1.24 Date: 11/05/2013 Location(s): Idaho Offices(s): Bonneville Power Administration

  14. CX-012790: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Haystack Butte Radio Site Land Acquisition CX(s) Applied: B1.24Date: 41939 Location(s): WashingtonOffices(s): Bonneville Power Administration

  15. CX-008250: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Geotechnical Core Drilling for USGS 138 CX(s) Applied: B3.1 Date: 04/18/2012 Location(s): Idaho Offices(s): Nuclear Energy

  16. CX-009850: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Pittsburgh Nanomaterials Preparation Lab CX(s) Applied: B3.6 Date: 01/29/2013 Location(s): Pennsylvania Offices(s): National Energy Technology Laboratory

  17. CX-007893: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    SunShot Massachusetts CX(s) Applied: A9, A11 Date: 02/10/2012 Location(s): Massachusetts Offices(s): Golden Field Office

  18. CX-012620: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Grout Preparation CX(s) Applied: B3.6Date: 41799 Location(s): South CarolinaOffices(s): Savannah River Operations Office

  19. CX-010578: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Celilo Converter Station Upgrades CX(s) Applied: B4.11 Date: 07/25/2013 Location(s): Oregon Offices(s): Bonneville Power Administration

  20. CX-008547: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    St. Petersburg Solar Pilot Project CX(s) Applied: B5.16 Date: 05/31/2012 Location(s): Florida Offices(s): Golden Field Office

  1. CX-008884: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Rattlesnake Butte Property Funding CX(s) Applied: B1.25 Date: 08/13/2012 Location(s): Oregon Offices(s): Bonneville Power Administration

  2. CX-008307: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Deepwater Reverse-Circulation Primary Cementing CX(s) Applied: A9 Date: 04/25/2012 Location(s): Texas Offices(s): National Energy Technology Laboratory

  3. CX-010618: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Midwest Region Alternative Fuels Project CX(s) Applied: 0 Date: 07/19/2013 Location(s): Missouri Offices(s): National Energy Technology Laboratory

  4. CX-008799: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Jack Case Showers Projects CX(s) Applied: B1.3 Date: 06/04/2012 Location(s): Tennessee Offices(s): Y-12 Site Office

  5. CX-011177: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Hebo Substation Access Road Maintenance CX(s) Applied: B1.3 Date: 09/13/2013 Location(s): Oregon Offices(s): Bonneville Power Administration

  6. CX-011676: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Office Trailer Relocation CX(s) Applied: B1.22 Date: 12/09/2013 Location(s): South Carolina Offices(s): Savannah River Operations Office

  7. CX-008215: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Small Hydropower Research and Development Technology Project CX(s) Applied: A9 Date: 04/03/2012 Location(s): Colorado Offices(s): Golden Field Office

  8. CX-011194: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Particle Physics Division Outback Garage CX(s) Applied: B1.15 Date: 09/19/2013 Location(s): Illinois Offices(s): Fermi Site Office

  9. CX-012561: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Replace Department of Energy Office Trailers CX(s) Applied: B1.15Date: 41871 Location(s): South CarolinaOffices(s): Savannah River Operations Office

  10. CX-011534: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Grays River Confluence Property Funding CX(s) Applied: B1.25 Date: 11/08/2013 Location(s): Washington Offices(s): Bonneville Power Administration

  11. CX-011110: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Advancements in Algal Biomass Yield CX(s) Applied: A9 Date: 08/29/2013 Location(s): Hawaii Offices(s): Golden Field Office

  12. CX-010763: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-010763: Categorical Exclusion Determination Nevada Desert Research Institute- Photovoltaic Installation CX(s) Applied: B5.16 Date: 07172013 Location(s): Nevada Offices(s):...

  13. CX-009237: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    The Dow Chemical Company CX(s) Applied: B5.7 Date: 10/02/2012 Location(s): Texas Offices(s): Fossil Energy

  14. CX-013619: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Upper Lemhi Conservation Easement Acquisition CX(s) Applied: B1.25Date: 05/26/2015 Location(s): IdahoOffices(s): Bonneville Power Administration

  15. CX-008161: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Prosser Hatchery Backup Generator Replacement CX(s) Applied: B1.31 Date: 04/16/2012 Location(s): Washington Offices(s): Bonneville Power Administration

  16. CX-012463: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Reliable SOFC Systems CX(s) Applied: A9, B3.6Date: 41877 Location(s): ConnecticutOffices(s): National Energy Technology Laboratory

  17. CX-013624: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Ahtanum Creek Property Acquisition Funding CX(s) Applied: B1.25Date: 05/04/2015 Location(s): WashingtonOffices(s): Bonneville Power Administration

  18. CX-012585: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Grit Blasting CX(s) Applied: B3.6Date: 41835 Location(s): South CarolinaOffices(s): Savannah River Operations Office

  19. CX-013432: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Process Demonstration Unit Support Structure CX(s) Applied: B1.15Date: 02/04/2015 Location(s): IdahoOffices(s): Idaho Operations Office

  20. CX-008875: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Bingen Substation Sectionalizing Switches Disposition CX(s) Applied: B1.24 Date: 08/27/2012 Location(s): Washington Offices(s): Bonneville Power Administration

  1. CX-011401: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Minto Lodge Rehabilitation CX(s) Applied: B5.1 Date: 11/19/2013 Location(s): Alaska Offices(s): Golden Field Office

  2. CX-013450: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Ellensburg Guy Wire Installation CX(s) Applied: B4.9Date: 03/06/2015 Location(s): WashingtonOffices(s): Bonneville Power Administration

  3. CX-013823: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Electric Vehicle Infrastructure (EVI) Laboratory Upgrades CX(s) Applied: B1.31Date: 06/18/2015 Location(s): IdahoOffices(s): Nuclear Energy

  4. CX-012789: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Building 440 CNM Clean Room Expansion CX(s) Applied: B3.15Date: 41906 Location(s): IllinoisOffices(s): Argonne Site Office

  5. CX-100400 Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Corrosion-resistant non-carbon electrocatalyst supports for PEFCs Award Number: DE- EE-0007272 CX(s) Applied: A9, B3.6

  6. CX-011822: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Light Willow Demonstration CX(s) Applied: B3.6 Date: 01/09/2014 Location(s): South Carolina Offices(s): Savannah River Operations Office

  7. Categorical Exclusion Determinations: Golden Field Office | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Categorical Exclusion Determination U.S. Department of Energy Collegiate Entrepreneurship Prize Award Number: TBD FOA CX(s) Applied: A9 Date: 12222014 Location(s): CO...

  8. CX-012656: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    North Bend Communication Site Engine Generator Replacement CX(s) Applied: B1.3Date: 41848 Location(s): WashingtonOffices(s): Bonneville Power Administration

  9. CX-006520: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-006520: Categorical Exclusion Determination High Energy Density Distributed Hydrostatic Direct Drive for Large Wind Turbine and Marine Hydro-Kinetic Device Applications CX(s) ...

  10. CX-003608: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CX-003608: Categorical Exclusion Determination Sustainable Algal Energy Production and Environmental Remediation CX(s) Applied: A9, B3.6 Date: 08252010 Location(s): Virginia ...

  11. CX-012278: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Building 36 Use Permit CX(s) Applied: A9 Date: 06/23/2014 Location(s): Oregon Offices(s): National Energy Technology Laboratory

  12. CX-012434: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Low Cost Titanium Casting Technology CX(s) Applied: B3.6Date: 41878 Location(s): OhioOffices(s): National Energy Technology Laboratory

  13. CX-006646: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Restoration South of 54-TPX-10CX(s) Applied: B6.1Date: 02/09/2010Location(s): Casper, WyomingOffice(s): RMOTC

  14. CX-010717: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Moodys Radio Tower Land Acquisition CX(s) Applied: B1.24 Date: 07/15/2013 Location(s): Oklahoma Offices(s): Southwestern Power Administration

  15. CX-010155: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Augspurger Radio Tower Replacement Project CX(s) Applied: B1.19 Date: 04/03/2013 Location(s): Washington Offices(s): Bonneville Power Administration

  16. CX-008683: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Shaniko Radio Station Replacement Project CX(s) Applied: B1.19 Date: 07/11/2012 Location(s): Oregon Offices(s): Bonneville Power Administration

  17. CX-011190: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Alberton Communication Site Construction CX(s) Applied: B1.19 Date: 08/26/2013 Location(s): Montana Offices(s): Bonneville Power Administration

  18. CX-011237: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Lightspeed Networks Inc. Fiber Installation CX(s) Applied: B4.9 Date: 10/24/2013 Location(s): Oregon Offices(s): Bonneville Power Administration

  19. CX-012803: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Sacajawea Substation Expansion and Upgrade CX(s) Applied: B4.6Date: 41912 Location(s): WashingtonOffices(s): Bonneville Power Administration

  20. CX-012002: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Raver-Covington Conductor Replacement CX(s) Applied: B1.3 Date: 04/24/2014 Location(s): Washington Offices(s): Bonneville Power Administration

  1. CX-009423: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Relay and Switchboard Panel Replacements CX(s) Applied: B4.6 Date: 10/29/2012 Location(s): Arkansas Offices(s): Southwestern Power Administration

  2. CX-011214: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Sensitive Instrument Facility CX(s) Applied: B3.6 Date: 07/10/2013 Location(s): Iowa Offices(s): Ames Site Office

  3. CX-009398: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Domestic Source Recovery CX(s) Applied: B2.6 Date: 11/01/2012 Location(s): New Mexico Offices(s): Los Alamos Site Office

  4. CX-007587: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Gas Chromatography CX(s) Applied: B3.6 Date: 12/29/2011 Location(s): Oregon Offices(s): National Energy Technology Laboratory

  5. CX-010124: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Chromatography / Mass Spectrometry CX(s) Applied: B3.6 Date: 03/20/2013 Location(s): South Carolina Offices(s): Savannah River Operations Office

  6. CX-007399: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Offshore Wind Removing Market Barriers CX(s) Applied: A9, A11 Date: 12/20/2011 Location(s): Massachusetts Offices(s): Golden Field Office

  7. Categorical Exclusion Determinations: A12 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    September 29, 2011 CX-006906: Categorical Exclusion Determination Electricity Delivery and Energy Reliability Assistance to State Regulatory Utility Commissioners CX(s) Applied: ...

  8. CX-010195: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Polymer Synthesis Lab - Modification CX(s) Applied: B3.6 Date: 04/15/2013 Location(s): Pennsylvania Offices(s): National Energy Technology Laboratory

  9. CX-012437: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    High Energy Density Lithium Battery CX(s) Applied: B3.6Date: 41878 Location(s): New YorkOffices(s): National Energy Technology Laboratory

  10. CX-012028: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    High Temperature Laboratory CX(s) Applied: B3.6 Date: 04/21/2014 Location(s): Oregon Offices(s): National Energy Technology Laboratory

  11. CX-013534: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    ENI USA Gas Marketing, LLC CX(s) Applied: B5.7Date: 04/14/2015 Location(s): Multiple LocationsOffices(s): Fossil Energy

  12. CX-009797: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Eni USA Gas Marketing, LLC CX(s) Applied: B5.7 Date: 02/06/2013 Location(s): Louisiana Offices(s): Fossil Energy

  13. CX-001627: Categorical Exclusion Determination | Department of...

    Office of Environmental Management (EM)

    CX-001627: Categorical Exclusion Determination Test Reactor Cask Implementation CX(s) ... This proposed action is a process and facility modification. The Advanced Test Reactor ...

  14. CX-010338: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Eugene Substation Fiber Interconnection CX(s) Applied: B4.7 Date: 05/21/2013 Location(s): Oregon Offices(s): Bonneville Power Administration

  15. CX-010435: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    De Moss Substation Expansion CX(s) Applied: B4.6 Date: 06/03/2013 Location(s): Oregon Offices(s): Bonneville Power Administration

  16. CX-008146: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Advanced Formation Evaluator Tools (Haliburton) CX(s) Applied: B3.7 Date: 09/11/2011 Location(s): Wyoming Offices(s): RMOTC

  17. Categorical Exclusion Determinations: Idaho | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... June 18, 2015 CX-013839: Categorical Exclusion Determination Materials and Fuels Complex (MFC)-752 Analytical Laboratory Casting Laboratory Glovebox Heat Detection CX(s) Applied: ...

  18. CX-006681: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    New Drilling Location in Section 29CX(s) Applied: B3.1Date: 12/23/2009Location(s): Casper, WyomingOffice(s): RMOTC

  19. CX-009418: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Electron Beam Melting CX(s) Applied: None applied. Date: 10/30/2012 Location(s): Missouri Offices(s): Kansas City Site Office

  20. CX-013721: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Solar Vacuum Furnace CX(s) Applied: B3.6Date: 04/28/2015 Location(s): OregonOffices(s): National Energy Technology Laboratory

  1. CX-012188: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Emerald Ash Borer Control CX(s) Applied: B1.3 Date: 05/06/2014 Location(s): Illinois Offices(s): Argonne Site Office

  2. CX-011065: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Midwest Region Alternative Fuels Project CX(s) Applied: A1 Date: 08/29/2013 Location(s): Kansas Offices(s): National Energy Technology Laboratory

  3. CX-011788: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    I-75 Green Corridor Project CX(s) Applied: A1 Date: 02/10/2014 Location(s): Tennessee Offices(s): National Energy Technology Laboratory

  4. CX-007497: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Clean Energy Coalition - Michigan Green Fleets CX(s) Applied: A1 Date: 12/06/2011 Location(s): Michigan Offices(s): National Energy Technology Laboratory

  5. CX-010938: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Midwest Region Alternative Fuels Project CX(s) Applied: A1 Date: 09/17/2013 Location(s): Kansas, Kansas Offices(s): National Energy Technology Laboratory

  6. CX-011271: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Idaho Petroleum Reduction Leadership Project CX(s) Applied: A1 Date: 09/30/2013 Location(s): Idaho Offices(s): National Energy Technology Laboratory

  7. CX-008588: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    St. Petersburg Solar Pilot Project CX(s) Applied: B5.1 Date: 07/19/2012 Location(s): Florida Offices(s): Golden Field Office

  8. CX-011634: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Closure Turf Installation CX(s) Applied: B6.1 Date: 08/27/2013 Location(s): Texas Offices(s): Pantex Site Office

  9. CX-008803: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Milling Machine Replacement Projects CX(s) Applied: B1.31 Date: 05/14/2012 Location(s): Tennessee Offices(s): Y-12 Site Office

  10. CX-012725: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Materials and Fuel Complex (MFC)-782 Fire Sprinkler Installation CX(s) Applied: B2.2Date: 41829 Location(s): IdahoOffices(s): Nuclear Energy

  11. CX-010756: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Solar Utility Network Deployment Acceleration CX(s) Applied: A9, A11 Date: 08/15/2013 Location(s): Virginia Offices(s): Golden Field Office

  12. CX-011102: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    American Solar Transformation Initiative CX(s) Applied: A11 Date: 08/09/2013 Location(s): California Offices(s): Golden Field Office

  13. CX-012531: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Distributed Wireless Antenna Sensors for Boiler Condition CX(s) Applied: B3.6Date: 41836 Location(s): CaliforniaOffices(s): National Energy Technology Laboratory

  14. CX-012539: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Distributed Wireless Antenna Sensors for Boiler Condition CX(s) Applied: B3.6Date: 41836 Location(s): TexasOffices(s): National Energy Technology Laboratory

  15. CX-008984: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    State Energy Program CX(s) Applied: A9, A11 Date: 08/29/2012 Location(s): Florida Offices(s): Golden Field Office

  16. CX-012798: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Davis Creek Tap Wood Pole Replacements CX(s) Applied: B1.3Date: 41915 Location(s): CaliforniaOffices(s): Bonneville Power Administration

  17. CX-007550: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Kearney - Waste Water Treatment Plant CX(s) Applied: B5.1 Date: 01/10/2012 Location(s): Missouri Offices(s): Golden Field Office

  18. CX-007549: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Harrisonville - Waste Water Treatment Plant CX(s) Applied: B5.1 Date: 01/10/2012 Location(s): Missouri Offices(s): Golden Field Office

  19. CX-009420: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Additive Manufacturing Using EOSINT M280 CX(s) Applied: None applied. Date: 10/30/2012 Location(s): Missouri Offices(s): Kansas City Site Office

  20. CX-008700: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Natapoc Property Funding CX(s) Applied: B1.25 Date: 06/12/2012 Location(s): Washington Offices(s): Bonneville Power Administration

  1. CX-009028: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Wisconsin Biodiesel Blending Program CX(s) Applied: B5.22 Date: 08/22/2012 Location(s): Wisconsin Offices(s): Golden Field Office

  2. CX-007856: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Sacramento Regional Energy Alliance CX(s) Applied: B5.23 Date: 01/27/2012 Location(s): California Offices(s): Golden Field Office

  3. CX-011625: Categorical Exclusion Determinationc

    Broader source: Energy.gov [DOE]

    9103 Second Floor Refurbishment CX(s) Applied: B1.3 Date: 06/05/2013 Location(s): Tennessee Offices(s): Y-12 Site Office

  4. CX-012495: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Building 6 Stack Replacement CX(s) Applied: B1.3Date: 41855 Location(s): West VirginiaOffices(s): National Energy Technology Laboratory

  5. CX-013324: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Wear Laboratory CX(s) Applied: A9, B3.6Date: 01/16/2015 Location(s): OregonOffices(s): National Energy Technology Laboratory

  6. CX-007423: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Highland Independent School District CX(s) Applied: B5.18 Date: 12/13/2011 Location(s): Texas Offices(s): Golden Field Office

  7. CX-007428: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Ralls Independent School District CX(s) Applied: B5.18 Date: 12/20/2011 Location(s): Texas Offices(s): Golden Field Office

  8. CX-004649: Categorical Exclusion Determination | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Painesville Municipal Power Vanadium Redox Battery Demonstration Program CX(s) ... CX-006145: Categorical Exclusion Determination Fact Sheet: Vanadium Redox Battery ...

  9. CX-010734: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Covington District Culvert Replacements CX(s) Applied: B1.3 Date: 07/22/2013 Location(s): Washington Offices(s): Bonneville Power Administration

  10. CX-012641: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Mossy Rock-Chehalis #1 Access Road Maintenance CX(s) Applied: B1.3Date: 41865 Location(s): WashingtonOffices(s): Bonneville Power Administration

  11. CX-012799: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Malin-Hilltop Wood Pole Replacements CX(s) Applied: B1.3Date: 41915 Location(s): CaliforniaOffices(s): Bonneville Power Administration

  12. CX-012805: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Brasada-Harney #1 Wood Pole Replacements CX(s) Applied: B1.3Date: 41908 Location(s): OregonOffices(s): Bonneville Power Administration

  13. CX-008989: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    State Energy Program CX(s) Applied: A9, A11 Date: 08/27/2012 Location(s): Kansas Offices(s): Golden Field Office

  14. CX-008144: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Planned Repair of Flow Lines CX(s) Applied: B5.4 Date: 08/09/2011 Location(s): Wyoming Offices(s): RMOTC

  15. CX-011564: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Excess Facilities Deactivation and Demolition CX(s) Applied: B1.23 Date: 11/05/2013 Location(s): Idaho Offices(s): Idaho Operations Office

  16. CX-012816: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Rogue-Gold Beach Access Road Improvement CX(s) Applied: B1.3Date: 41890 Location(s): OregonOffices(s): Bonneville Power Administration

  17. CX-008724: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Rexburg Bus Lot Lease Termination CX(s) Applied: B1.24 Date: 07/05/2012 Location(s): Idaho Offices(s): Idaho Operations Office

  18. CX-009513: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Aquatic Invasive Mussels Monitoring CX(s) Applied: B3.1 Date: 10/15/2012 Location(s): CX: none Offices(s): Bonneville Power Administration

  19. CX-013632: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Alcoa Power Sales Contract Amendment CX(s) Applied: B4.11Date: 04/23/2015 Location(s): WashingtonOffices(s): Bonneville Power Administration

  20. CX-012110: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Cowlitz Falls Fish Facility Access Agreement Extension CX(s) Applied: A2 Date: 04/02/2014 Location(s): Washington Offices(s): Bonneville Power Administration