National Library of Energy BETA

Sample records for geochemical groundwater geochemical

  1. Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Rifle Processing Site, Colorado | Department of Energy and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado

  2. Geochemical and Isotopic Interpretations of Groundwater Flow in the Oasis Valley Flow System, Southern Nevada

    SciTech Connect (OSTI)

    J.M. Thomas; F.C. Benedict, Jr.; T.P. Rose; R.L. Hershey; J.B. Paces; Z.E. Peterman; I.M. Farnham; K.H. Johannesson; A.K. Singh; K.J. Stetzenbach; G.B. Hudson; J.M. Kenneally; G.F. Eaton; D.K. Smith

    2003-01-08

    This report summarizes the findings of a geochemical investigation of the Pahute Mesa-Oasis Valley groundwater flow system in southwestern Nevada. It is intended to provide geochemical data and interpretations in support of flow and contaminant transport modeling for the Western and Central Pahute Mesa Corrective Action Units.

  3. Evaluation of Groundwater Movement in the Frenchman Flat CAU Using Geochemical and Isotopic Analysis

    SciTech Connect (OSTI)

    R. Hershey; J. Thomas; T. Rose; J. Paces; I. Farnham; C. Benedict, Jr.

    2005-03-01

    The principal pathway for radionuclide migration from underground tests in Frenchman Flat, on the Nevada Test Site, to the accessible environment is groundwater flow. Two potential pathways for radionuclide transport via groundwater have been identified from hydrologic data: (1) radionuclide transport downward from the alluvial and volcanic aquifers into the underlying carbonate aquifer; and (2) radionuclide transport laterally to the carbonate aquifer surrounding Frenchman Flat. This report presents an evaluation of geochemical and environmental isotopic data to test these potential pathways and to identify other groundwater flowpaths in, and out of, Frenchman Flat.

  4. HBH-GEOCHEM-GEOPHY

    Energy Science and Technology Software Center (OSTI)

    003015WKSTN00 Hiereachical Bayesian Model for Combining Geochemical and Geophysical Data for Environmental Applications Software

  5. Coupled Geochemical Impacts of Leaking CO2 and Contaminants from Subsurface Storage Reservoirs on Groundwater Quality

    SciTech Connect (OSTI)

    Shao, Hongbo; Qafoku, Nikolla; Lawter, Amanda R.; Bowden, Mark E.; Brown, Christopher F.

    2015-07-07

    The leakage of CO2 and the concomitant saline solutions from deep storage reservoirs to overlying groundwater aquifers is considered one of the major potential risks associated with geologic CO2 sequestration (GCS). Batch and column experiments were conducted to determine the fate of trace metals in groundwater in the scenarios of CO2 and metal contaminated brine leakage. The sediments used in this work were collected from an unconsolidated sand and gravel aquifer in Kansas, and contained 0-4 wt% carbonates. Cd and As were spiked into the reaction system to represent potential contaminants from the reservoir brine that could intrude into groundwater aquifers with leaking CO2 at initial concentrations of 114 and 40 ppb, respectively. Through this research we demonstrated that Cd and As were adsorbed on the sediments, in spite of the lowered pH due to CO2 dissolution in the groundwater. Cd concentrations were well below its MCL in both batch and column studies, even for sediment samples without detectable carbonate to buffer the pH. Arsenic concentrations in the effluent were also significantly lower than influent concentration, suggesting that the sediments tested have the capacity to mitigate the coupled adverse effects of CO2 leakage and brine intrusion. However, the mitigation capacity of sediment is a function of its geochemical properties [e.g., the calcite content; the presence of adsorbed As(III); and the presence of P in the natural sediment]. The competitive adsorption between phosphate and arsenate may result in higher concentrations of As in the aqueous phase.

  6. Geochemical Modeling of the Near-Surface Hydrothermal System...

    Open Energy Info (EERE)

    with non-thermal groundwater. Our conceptual model is based on hypotheses in the literature and published geochemical and petrologic data. Mixing of thermal and non-thermal...

  7. Aging and the geochemical environment

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    This report describes and assesses the aging process and related environmental aspects that may provide useful insights toward postponing some of the inevitable effects of aging. Although the Panel on Aging and the Geochemical Environment is convinced that the geochemical environment is associated with aging, it of course recognizes that other factors may also be significant or, perhaps, more important. Accordingly, the report is intended to enhance the awareness of biomedical and geochemical research scientists, decision makers in related areas, and the lay public interested in an understanding of the relation of the geochemical environment to senescence.

  8. Geochemical and isotopic results for groundwater, drainage waters, snowmelt, permafrost, precipitation in Barrow, Alaska (USA) 2012-2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Wilson, Cathy; Newman, Brent; Heikoop, Jeff

    2012-07-18

    Data include a large suite of analytes (geochemical and isotopic) for samples collected in Barrow, Alaska (2012-2013). Sample types are indicated, and include soil pore waters, drainage waters, snowmelt, precipitation, and permafrost samples.

  9. Geochemical and isotopic results for groundwater, drainage waters, snowmelt, permafrost, precipitation in Barrow, Alaska (USA) 2012-2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Wilson, Cathy; Newman, Brent; Heikoop, Jeff

    Data include a large suite of analytes (geochemical and isotopic) for samples collected in Barrow, Alaska (2012-2013). Sample types are indicated, and include soil pore waters, drainage waters, snowmelt, precipitation, and permafrost samples.

  10. Geochemical Speciation Mass Transfer

    Energy Science and Technology Software Center (OSTI)

    1985-12-01

    PHREEQC is designed to model geochemical reactions. Based on an ion association aqueous model, PHREEQC can calculate pH, redox potential, and mass transfer as a function of reaction progress. It can be used to describe geochemical processes for both far-field and near-field performance assessment and to evaluate data acquisition needs and test data. It can also calculate the composition of solutions in equilibrium with multiple phases. The data base, including elements, aqueous species, and mineralmore » phases, is independent of the program and is completely user-definable. PHREEQC requires thermodynamic data for each solid, gaseous, or dissolved chemical species being modeled. The two data bases, PREPHR and DEQPAK7, supplied with PHREEQC are for testing purposes only and should not be applied to real problems without first being carefully examined. The conceptual model embodied in PHREEQC is the ion-association model of Pearson and Noronha. In this model a set of mass action equations are established for each ion pair (and controlling solid phases when making mass transfer calculations) along with a set of mass balance equations for each element considered. These sets of equations are coupled using activity coefficient values for each aqueous species and solved using a continued fraction approach for the mass balances combined with a modified Newton-Raphson technique for all other equations. The activity coefficient expressions in PHREEQC include the extended Debye-Huckel, WATEQ Debye-Huckel, and Davies equations from the original United States Geological Survey version of the program. The auxiliary preprocessor program PHTL, which is derived from EQTL, converts EQ3/6 thermodynamic data to PHREEQC format so that the two programs can be compared. PHREEQC can be used to determine solubility limits on the radionuclides present in the waste form. These solubility constraints may be input to the WAPPA leach model.« less

  11. Novel Coupled Thermochronometric and Geochemical Investigation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Novel Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners Novel Coupled Thermochronometric and Geochemical ...

  12. Category:Geochemical Techniques | Open Energy Information

    Open Energy Info (EERE)

    Techniques Technique Subcategories This category has only the following subcategory. G + Geochemical Data Analysis (2 categories) 4 pages Pages in category "Geochemical...

  13. Evapotranspiration And Geochemical Controls On Groundwater Plumes At Arid Sites: Toward Innovative Alternate End-States For Uranium Processing And Tailings Facilities

    SciTech Connect (OSTI)

    Looney, Brian B.; Denham, Miles E.; Eddy-Dilek, Carol A.; Millings, Margaret R.; Kautsky, Mark

    2014-01-08

    Management of legacy tailings/waste and groundwater contamination are ongoing at the former uranium milling site in Tuba City AZ. The tailings have been consolidated and effectively isolated using an engineered cover system. For the existing groundwater plume, a system of recovery wells extracts contaminated groundwater for treatment using an advanced distillation process. The ten years of pump and treat (P&T) operations have had minimal impact on the contaminant plume – primarily due to geochemical and hydrological limits. A flow net analysis demonstrates that groundwater contamination beneath the former processing site flows in the uppermost portion of the aquifer and exits the groundwater as the plume transits into and beneath a lower terrace in the landscape. The evaluation indicates that contaminated water will not reach Moenkopi Wash, a locally important stream. Instead, shallow groundwater in arid settings such as Tuba City is transferred into the vadose zone and atmosphere via evaporation, transpiration and diffuse seepage. The dissolved constituents are projected to precipitate and accumulate as minerals such as calcite and gypsum in the deep vadose zone (near the capillary fringe), around the roots of phreatophyte plants, and near seeps. The natural hydrologic and geochemical controls common in arid environments such as Tuba City work together to limit the size of the groundwater plume, to naturally attenuate and detoxify groundwater contaminants, and to reduce risks to humans, livestock and the environment. The technical evaluation supports an alternative beneficial reuse (“brownfield”) scenario for Tuba City. This alternative approach would have low risks, similar to the current P&T scenario, but would eliminate the energy and expense associated with the active treatment and convert the former uranium processing site into a resource for future employment of local citizens and ongoing benefit to the Native American Nations.

  14. Geochemical Modeling Of Aqueous Systems

    Energy Science and Technology Software Center (OSTI)

    1995-09-07

    EQ3/6 is a software package for geochemical modeling of aqueous systems. This description pertains to version 7.2b. It addresses aqueous speciation, thermodynamic equilibrium, disequilibrium, and chemical kinetics. The major components of the package are EQ3NR, a speciation-solubility code, and EQ6 a reaction path code. EQ3NR is useful for analyzing groundwater chemistry data, calculating solubility limits, and determining whether certain reactions are in states of equilibrium or disequilibrium. It also initializes EQ6 calculations. EQ6 models themore » consequences of reacting an aqueous solution with a specified set of reactants (e.g., minerals or waste forms). It can also model fluid mixing and the effects of changes in temperature. Each of five supporting data files contain both standard state and activity coefficient-related data. Three support the use of the Davies or B-dot equations for the activity coefficients; the other two support the use of Pitzer''s equations. The temperature range of the thermodynamic data on the data files varies from 25 degrees C only to 0-300 degrees C.« less

  15. Aging and the geochemical environment

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    The report describes and assesses the aging process and related environmental aspects. Specific geographic areas of increased and decreased longevity were identified and geochemically characterized in terms of surface rocks, drinking water quality, soils, and abnormal absorption of trace elements by plants. Environmental factors that may be related to increased longevity are discussed. 11 references, 32 figures, 8 tables. (ACR)

  16. GIS Regional Spatial Data from the Great Basin Center for Geothermal Energy: Geochemical, Geodesic, Geologic, Geophysical, Geothermal, and Groundwater Data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Great Basin Center for Geothermal Energy, part of the University of Nevada, Reno, conducts research towards the establishment of geothermal energy as an economically viable energy source within the Great Basin. The Center specializes in collecting and synthesizing geologic, geochemical, geodetic, geophysical, and tectonic data, and using Geographic Information System (GIS) technology to view and analyze this data and to produce favorability maps of geothermal potential. The center also makes its collections of spatial data available for direct download to the public. Data are in Lambert Conformable Conic Projection.

  17. Geochemical and Isotopic Evaluation of Groundwater Movement in Corrective Action Unit 97: Yucca Flat/Climax Mine, Nevada Test Site, Nevada, Rev. No.: 0

    SciTech Connect (OSTI)

    Farnham, Irene

    2006-02-01

    This report describes the results of a comprehensive geochemical evaluation of the groundwater flow system in the Yucca Flat/Climax Mine Corrective Action Unit (CAU). The main objectives of this study are to identify probable pathways for groundwater flow within the study area and to develop constraints on groundwater transit times between selected data collection sites. This work provides an independent means of testing and verifying predictive flow models being developed for this CAU using finite element methods. The Yucca Flat/Climax Mine CAU constitutes the largest of six underground test areas on the Nevada Test Site (NTS) specified for remedial action in the ''Federal Facility Agreement and Consent Order''. A total of 747 underground nuclear detonations were conducted in this CAU. Approximately 23 percent of these detonations were conducted below or near the water table, resulting in groundwater contamination in the vicinity and possibly downgradient of these underground test locations. Therefore, a rigorous evaluation of the groundwater flow system in this CAU is necessary to assess potential long-term risks to the public water supply at downgradient locations.

  18. Mercury Geochemical, Groundwater Geochemical, And Radiometric...

    Open Energy Info (EERE)

    at right angles to known and suspected faults. Scintillometer readings (gamma radiation - total counts second) were also recorded at each soil sample station. At the...

  19. Interface Induced Carbonate Mineralization: A Fundamental Geochemical

    Office of Scientific and Technical Information (OSTI)

    Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration Teng, H. Henry PI, The George Washington University PI, The George...

  20. Novel Coupled Thermochronometric and Geochemical Investigation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... in a well-characterized structural context (permeability and alteration) in order to ... and geochemical data integration and model Innovative approach combining structural ...

  1. Optimizing parameters for predicting the geochemical behavior...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of discrete fracture networks in geothermal systems Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal ...

  2. Geochemical Data Analysis | Open Energy Information

    Open Energy Info (EERE)

    Information Provided by Technique Lithology: StratigraphicStructural: Hydrological: Thermal: Dictionary.png Geochemical Data Analysis: No definition has been provided for...

  3. Groundwater geochemical modeling and simulation of a breached high-level radioactive waste repository in the northern Tularosa Basin, New Mexico

    SciTech Connect (OSTI)

    Chappell, R.W.

    1989-01-01

    The northern Tularosa Basin in south-central New Mexico was ranked favorably as a potential location for a high-level radioactive waste repository by a US Geological Survey pilot screening study of the Basin and Range Province. The favorable ranking was based chiefly on hydrogeologic and descriptive geochemical evidence. A goal of this study was to develop a methodology for predicting the performance of this or any other basin as a potential repository site using geochemical methods. The approach involves first characterizing the groundwater geochemistry, both chemically and isotopically, and reconstructing the probable evolutionary history of, and controls on the ground water chemistry through modeling. In the second phase of the approach, a hypothetically breached repository is introduced into the system, and the mobility of the parent radionuclide, uranium, in the groundwater is predicted. Possible retardation of uranium transport in the downgradient flow direction from the repository by adsorption and mineral precipitation is then considered. The Permian Yeso Formation, the primary aquifer in the northern Tularosa Basin, was selected for study, development and testing of the methodology outlined above. The Yeso Formation contains abundant gypsum and related evaporite minerals, which impart a distinctive chemical signature to the ground water. Ground water data and solubility calculations indicate a conceptual model of irreversible gypsum and dolomite dissolution with concomitant calcite precipitation. Recharge areas are apparent from temperature, {delta}{sup 18}O and {delta}{sup 2} H, and {sup 3}H trends in the aquifer. Corrected {sup 14}C ages range between modern and 31,200 years, and suggest an average ground water velocity of 0.83 m/yr.

  4. Book Review - Geochemical Exploration 1982 | Open Energy Information

    Open Energy Info (EERE)

    Book Review - Geochemical Exploration 1982 Jump to: navigation, search OpenEI Reference LibraryAdd to library Book Review: Book Review - Geochemical Exploration 1982 Author R. A....

  5. Application Of Geochemical Methods In The Search For Geothermal...

    Open Energy Info (EERE)

    Geochemical Methods In The Search For Geothermal Fields Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Application Of Geochemical Methods In...

  6. Computer Modeling of Chemical and Geochemical Processes in High...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computer modeling of chemical and geochemical processes in high ionic strength solutions ... in brine Computer modeling of chemical and geochemical processes in high ionic ...

  7. Geochemical Triggers of Arsenic Mobilization during Managed Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Recharge | Stanford Synchrotron Radiation Lightsource Geochemical Triggers of Arsenic Mobilization during Managed Aquifer Recharge Monday, February 29, 2016 Managed aquifer recharge (MAR) is an increasingly used water enhancement strategy, which involves subsurface storage of water supplies in groundwater aquifers. While MAR projects have the potential to alleviate water deficits, they can also adversely impact groundwater quality by altering the native geochemistry of the aquifer and

  8. Computed solid phases limiting the concentration of dissolved constituents in basalt aquifers of the Columbia Plateau in eastern Washington. Geochemical modeling and nuclide/rock/groundwater interaction studies

    SciTech Connect (OSTI)

    Deutsch, W.J.; Jenne, E.A.; Krupka, K.M.

    1982-08-01

    A speciation-solubility geochemical model, WATEQ2, was used to analyze geographically-diverse, ground-water samples from the aquifers of the Columbia Plateau basalts in eastern Washington. The ground-water samples compute to be at equilibrium with calcite, which provides both a solubility control for dissolved calcium and a pH buffer. Amorphic ferric hydroxide, Fe(OH)/sub 3/(A), is at saturation or modestly oversaturated in the few water samples with measured redox potentials. Most of the ground-water samples compute to be at equilibrium with amorphic silica (glass) and wairakite, a zeolite, and are saturated to oversaturated with respect to allophane, an amorphic aluminosilicate. The water samples are saturated to undersaturated with halloysite, a clay, and are variably oversaturated with regard to other secondary clay minerals. Equilibrium between the ground water and amorphic silica presumably results from the dissolution of the glassy matrix of the basalt. The oversaturation of the clay minerals other than halloysite indicates that their rate of formation lags the dissolution rate of the basaltic glass. The modeling results indicate that metastable amorphic solids limit the concentration of dissolved silicon and suggest the same possibility for aluminum and iron, and that the processes of dissolution of basaltic glass and formation of metastable secondary minerals are continuing even though the basalts are of Miocene age. The computed solubility relations are found to agree with the known assemblages of alteration minerals in the basalt fractures and vesicles. Because the chemical reactivity of the bedrock will influence the transport of solutes in ground water, the observed solubility equilibria are important factors with regard to chemical-retention processes associated with the possible migration of nuclear waste stored in the earth's crust.

  9. Nanogeochemistry: Geochemical reactions and mass transfers in...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Nanogeochemistry: Geochemical reactions and mass transfers in nanopores ... OSTI Identifier: 913493 Report Number(s): SAND2003-0369J Journal ID: ISSN 0091-7613; TRN: ...

  10. Geothermal/Geochemical Database | Open Energy Information

    Open Energy Info (EERE)

    to library Chart: GeothermalGeochemical DatabaseInfo GraphicMapChart Author Nevada Bureau of Mines and Geology Published Nevada Bureau of Mines and Geology, 2012 DOI Not...

  11. ENZYME ACTIVITY PROBE AND GEOCHEMICAL ASSESSMENT FOR POTENTIAL AEROBIC COMETABOLISM OF TRICHLOROETHENE IN GROUNDWATER OF THE NORTHWEST PLUME, PADUCAH GASEOUS DIFFUSION PLANT, KENTUCKY

    SciTech Connect (OSTI)

    Looney, B; M. Hope Lee, M; S. K. Hampson, S

    2008-06-27

    The overarching objective of the Paducah Gaseous Diffusion Plant (PGDP) enzyme activity probe (EAP) effort is to determine if aerobic cometabolism is contributing to the attenuation of trichloroethene (TCE) and other chlorinated solvents in the contaminated groundwater beneath PGDP. The site-specific objective for the EAP assessment is to identify if key metabolic pathways are present and expressed in the microbial community--namely the pathways that are responsible for degradation of methane and aromatic (e.g. toluene, benzene, phenol) substrates. The enzymes produced to degrade methane and aromatic compounds also break down TCE through a process known as cometabolism. EAPs directly measure if methane and/or aromatic enzyme production pathways are operating and, for the aromatic pathways, provide an estimate of the number of active organisms in the sampled groundwater. This study in the groundwater plumes at PGDP is a major part of a larger scientific effort being conducted by Interstate Technology and Regulatory Council (ITRC), U.S. Department of Energy (DOE) Office of Environmental Management (EM), Savannah River National Laboratory (SRNL), and North Wind Inc. in which EAPs are being applied to contaminated groundwater from diverse hydrogeologic and plume settings throughout the U.S. to help standardize their application as well as their interpretation. While EAP data provide key information to support the site specific objective for PGDP, several additional lines of evidence are being evaluated to increase confidence in the determination of the occurrence of biodegradation and the rate and sustainability of aerobic cometabolism. These complementary efforts include: (1) Examination of plume flowpaths and comparison of TCE behavior to 'conservative' tracers in the plume (e.g., {sup 99}Tc); (2) Evaluation of geochemical conditions throughout the plume; and (3) Evaluation of stable isotopes in the contaminants and their daughter products throughout the plume. If

  12. Hanford 100-N Area In Situ Apatite and Phosphate Emplacement by Groundwater and Jet Injection: Geochemical and Physical Core Analysis

    SciTech Connect (OSTI)

    Szecsody, James E.; Vermeul, Vincent R.; Fruchter, Jonathan S.; Williams, Mark D.; Rockhold, Mark L.; Qafoku, Nikolla; Phillips, Jerry L.

    2010-07-01

    The purpose of this study is to evaluate emplacement of phosphate into subsurface sediments in the Hanford Site 100-N Area by two different technologies: groundwater injection of a Ca-citrate-PO4 solution and water-jet injection of sodium phosphate and/or fish-bone apatite. In situ emplacement of phosphate and apatite adsorbs, then incorporates Sr-90 into the apatite structure by substitution for calcium. Overall, both technologies (groundwater injection of Ca-citrate-PO4) and water-jet injection of sodium phosphate/fish-bone apatite) delivered sufficient phosphate to subsurface sediments in the 100-N Area. Over years to decades, additional Sr-90 will incorporate into the apatite precipitate. Therefore, high pressure water jetting is a viable technology to emplace phosphate or apatite in shallow subsurface sediments difficult to emplace by Ca-citrate-PO4 groundwater injections, but further analysis is needed to quantify the relevant areal extent of phosphate deposition (in the 5- to 15-ft distance from injection points) and cause of the high deposition in finer grained sediments.

  13. Validation of the WATEQ4 geochemical model for uranium

    SciTech Connect (OSTI)

    Krupka, K.M.; Jenne, E.A.; Deutsch, W.J.

    1983-09-01

    As part of the Geochemical Modeling and Nuclide/Rock/Groundwater Interactions Studies Program, a study was conducted to partially validate the WATEQ4 aqueous speciation-solubility geochemical model for uranium. The solubility controls determined with the WATEQ4 geochemical model were in excellent agreement with those laboratory studies in which the solids schoepite (UO/sub 2/(OH)/sub 2/ . H/sub 2/O), UO/sub 2/(OH)/sub 2/, and rutherfordine ((UO/sub 2/CO/sub 3/) were identified as actual solubility controls for uranium. The results of modeling solution analyses from laboratory studies of uranyl phosphate solids, however, identified possible errors in the characterization of solids in the original solubility experiments. As part of this study, significant deficiencies in the WATEQ4 thermodynamic data base for uranium solutes and solids were corrected. Revisions included recalculation of selected uranium reactions. Additionally, thermodynamic data for the hydroxyl complexes of U(VI), including anionic (VI) species, were evaluated (to the extent permitted by the available data). Vanadium reactions were also added to the thermodynamic data base because uranium-vanadium solids can exist in natural ground-water systems. This study is only a partial validation of the WATEQ4 geochemical model because the available laboratory solubility studies do not cover the range of solid phases, alkaline pH values, and concentrations of inorganic complexing ligands needed to evaluate the potential solubility of uranium in ground waters associated with various proposed nuclear waste repositories. Further validation of this or other geochemical models for uranium will require careful determinations of uraninite solubility over the pH range of 7 to 10 under highly reducing conditions and of uranyl hydroxide and phosphate solubilities over the pH range of 7 to 10 under oxygenated conditions.

  14. Geochemical Reaction Mechanism Discovery from Molecular Simulation

    SciTech Connect (OSTI)

    Stack, Andrew G.; Kent, Paul R. C.

    2014-11-10

    Methods to explore reactions using computer simulation are becoming increasingly quantitative, versatile, and robust. In this review, a rationale for how molecular simulation can help build better geochemical kinetics models is first given. We summarize some common methods that geochemists use to simulate reaction mechanisms, specifically classical molecular dynamics and quantum chemical methods and discuss their strengths and weaknesses. Useful tools such as umbrella sampling and metadynamics that enable one to explore reactions are discussed. Several case studies wherein geochemists have used these tools to understand reaction mechanisms are presented, including water exchange and sorption on aqueous species and mineral surfaces, surface charging, crystal growth and dissolution, and electron transfer. The impact that molecular simulation has had on our understanding of geochemical reactivity are highlighted in each case. In the future, it is anticipated that molecular simulation of geochemical reaction mechanisms will become more commonplace as a tool to validate and interpret experimental data, and provide a check on the plausibility of geochemical kinetic models.

  15. Geochemical Reaction Mechanism Discovery from Molecular Simulation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stack, Andrew G.; Kent, Paul R. C.

    2014-11-10

    Methods to explore reactions using computer simulation are becoming increasingly quantitative, versatile, and robust. In this review, a rationale for how molecular simulation can help build better geochemical kinetics models is first given. We summarize some common methods that geochemists use to simulate reaction mechanisms, specifically classical molecular dynamics and quantum chemical methods and discuss their strengths and weaknesses. Useful tools such as umbrella sampling and metadynamics that enable one to explore reactions are discussed. Several case studies wherein geochemists have used these tools to understand reaction mechanisms are presented, including water exchange and sorption on aqueous species and mineralmore » surfaces, surface charging, crystal growth and dissolution, and electron transfer. The impact that molecular simulation has had on our understanding of geochemical reactivity are highlighted in each case. In the future, it is anticipated that molecular simulation of geochemical reaction mechanisms will become more commonplace as a tool to validate and interpret experimental data, and provide a check on the plausibility of geochemical kinetic models.« less

  16. Novel Coupled Thermochronometric and Geochemical Investigation of Blind

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Geothermal Resources in Fault-Controlled Dilational Corners | Department of Energy Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners Novel Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners Novel Coupled Thermochronometric and Geochemical Investigation of Blind Geothermal Resources in Fault-Controlled Dilational Corners presentation at the

  17. DNA-based methods of geochemical prospecting

    DOE Patents [OSTI]

    Ashby, Matthew

    2011-12-06

    The present invention relates to methods for performing surveys of the genetic diversity of a population. The invention also relates to methods for performing genetic analyses of a population. The invention further relates to methods for the creation of databases comprising the survey information and the databases created by these methods. The invention also relates to methods for analyzing the information to correlate the presence of nucleic acid markers with desired parameters in a sample. These methods have application in the fields of geochemical exploration, agriculture, bioremediation, environmental analysis, clinical microbiology, forensic science and medicine.

  18. A Geochemical Speciation Program Based on PHREEQE

    Energy Science and Technology Software Center (OSTI)

    1992-02-18

    HARPHRQ is a program based on the code PHREEQE and is designed to model geochemical reactions. Like PHREEQE, it can calculate the pH, redox potential and mass transfer as a function of reaction progress and the composition of solution in equilibrium with multiple phases. In addition, HARPHRQ includes options to allow the composition of a solution at a fixed pH to be calculated and to automatically add or remove mineral phases as they become saturatedmore » or exhausted. A separate module can also be interfaced to give a choice of sorption models including the triple-layer model.« less

  19. Monitoring CO2 intrusion and associated geochemical transformations...

    Office of Scientific and Technical Information (OSTI)

    Monitoring CO2 intrusion and associated geochemical transformations in a shallow ... Citation Details In-Document Search Title: Monitoring CO2 intrusion and associated ...

  20. Category:Geochemical Data Analysis | Open Energy Information

    Open Energy Info (EERE)

    category, out of 4 total. G Geochemical Data Analysis Geothermometry T Thermal Ion Dispersion Thermochronometry Retrieved from "http:en.openei.orgwindex.php?titleCategory:Ge...

  1. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and...

    Office of Scientific and Technical Information (OSTI)

    Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer Citation Details In-Document Search Title: Geochemical Impacts of Carbon ...

  2. Merging high resolution geophysical and geochemical surveys to...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    combine a suite of high resolution geophysical and geochemical techniques to reduce exploration risk by characterizing hydrothermal alteration, fault geometries and relationships. ...

  3. Code System to Model Aqueous Geochemical Equilibria.

    Energy Science and Technology Software Center (OSTI)

    2001-08-23

    Version: 00 MINTEQ is a geochemical program to model aqueous solutions and the interactions of aqueous solutions with hypothesized assemblages of solid phases. It was developed for the Environmental Protection Agency to perform the calculations necessary to simulate the contact of waste solutions with heterogeneous sediments or the interaction of ground water with solidified wastes. MINTEQ can calculate ion speciation/solubility, adsorption, oxidation-reduction, gas phase equilibria, and precipitation/dissolution ofsolid phases. MINTEQ can accept a finite massmore » for any solid considered for dissolution and will dissolve the specified solid phase only until its initial mass is exhausted. This ability enables MINTEQ to model flow-through systems. In these systems the masses of solid phases that precipitate at earlier pore volumes can be dissolved at later pore volumes according to thermodynamic constraints imposed by the solution composition and solid phases present. The ability to model these systems permits evaluation of the geochemistry of dissolved traced metals, such as low-level waste in shallow land burial sites. MINTEQ was designed to solve geochemical equilibria for systems composed of one kilogram of water, various amounts of material dissolved in solution, and any solid materials that are present. Systems modeled using MINTEQ can exchange energy and material (open systems) or just energy (closed systems) with the surrounding environment. Each system is composed of a number of phases. Every phase is a region with distinct composition and physically definable boundaries. All of the material in the aqueous solution forms one phase. The gas phase is composed of any gaseous material present, and each compositionally and structurally distinct solid forms a separate phase.« less

  4. Geochemical and Geomechanical Effects on Wellbore Cement Fractures

    SciTech Connect (OSTI)

    Um, Wooyong; Jung, Hun Bok; Kabilan, Senthil; Fernandez, Carlos A.; Brown, Christopher F.

    2014-12-31

    Experimental studies were conducted using batch reactors, X-ray microtomograpy (XMT), and computational fluid dynamics (CFD) simulation to determine changes in cement fracture surfaces, fluid flow pathways, and permeability with geochemical and geomechanical processes. Composite Portland cement-basalt caprock core with artificial fractures was prepared and reacted with CO2-saturated groundwater at 50°C and 10 MPa for 3 to 3.5 months under static conditions to understand the geochemical and geomechanical effects on the integrity of wellbores containing defects. Cement-basalt interface samples were subjected to mechanical stress at 2.7 MPa before the CO2 reaction. XMT provided three-dimensional (3-D) visualization of the opening and interconnection of cement fractures due to mechanical stress. After the CO2 reaction, XMT images revealed that calcium carbonate precipitation occurred extensively within the fractures in the cement matrix, but only partially along fractures located at the cement-basalt interface. The permeability calculated based on CFD simulation was in agreement with the experimentally measured permeability. The experimental results imply that the wellbore cement with fractures is likely to be healed during exposure to CO2-saturated groundwater under static conditions, whereas fractures along the cement-caprock interface are still likely to remain vulnerable to the leakage of CO2. CFD simulation for the flow of different fluids (CO2-saturated brine and supercritical CO2) using a pressure difference of 20 kPa and 200 kPa along ~2 cm-long cement fractures showed that a pressure gradient increase resulted in an increase of CO2 fluids flux by a factor of only ~3-9 because the friction of CO2 fluids on cement fracture surfaces increased with higher flow rate as well. At the same pressure gradient, the simulated flow rate was higher for supercritical CO2 than CO2-saturated brine by a factor of only ~2-3, because the viscosity of supercritical CO2 is much

  5. Geochemical and Geomechanical Effects on Wellbore Cement Fractures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Um, Wooyong; Jung, Hun Bok; Kabilan, Senthil; Fernandez, Carlos A.; Brown, Christopher F.

    2014-12-31

    Experimental studies were conducted using batch reactors, X-ray microtomograpy (XMT), and computational fluid dynamics (CFD) simulation to determine changes in cement fracture surfaces, fluid flow pathways, and permeability with geochemical and geomechanical processes. Composite Portland cement-basalt caprock core with artificial fractures was prepared and reacted with CO2-saturated groundwater at 50°C and 10 MPa for 3 to 3.5 months under static conditions to understand the geochemical and geomechanical effects on the integrity of wellbores containing defects. Cement-basalt interface samples were subjected to mechanical stress at 2.7 MPa before the CO2 reaction. XMT provided three-dimensional (3-D) visualization of the opening and interconnectionmore » of cement fractures due to mechanical stress. After the CO2 reaction, XMT images revealed that calcium carbonate precipitation occurred extensively within the fractures in the cement matrix, but only partially along fractures located at the cement-basalt interface. The permeability calculated based on CFD simulation was in agreement with the experimentally measured permeability. The experimental results imply that the wellbore cement with fractures is likely to be healed during exposure to CO2-saturated groundwater under static conditions, whereas fractures along the cement-caprock interface are still likely to remain vulnerable to the leakage of CO2. CFD simulation for the flow of different fluids (CO2-saturated brine and supercritical CO2) using a pressure difference of 20 kPa and 200 kPa along ~2 cm-long cement fractures showed that a pressure gradient increase resulted in an increase of CO2 fluids flux by a factor of only ~3-9 because the friction of CO2 fluids on cement fracture surfaces increased with higher flow rate as well. At the same pressure gradient, the simulated flow rate was higher for supercritical CO2 than CO2-saturated brine by a factor of only ~2-3, because the viscosity of supercritical CO2 is

  6. Geochemical factors affecting radionuclide transport through near and far fields at a Low-Level Waste Disposal Site

    SciTech Connect (OSTI)

    Kaplan, D.I.; Seme, R.J.; Piepkho, M.G.

    1995-03-01

    The concentration of low-level waste (LLW) contaminants in groundwater is determined by the amount of contaminant present in the solid waste, rate of release from the waste and surrounding barriers, and a number of geochemical processes including adsorption, desorption, diffusion, precipitation, and dissolution. To accurately predict radionuclide transport through the subsurface, it is essential that the important geochemical processes affecting radionuclide transport be identified and, perhaps more importantly, accurately quantified and described in a mathematically defensible manner.

  7. A Mineralogical Petrographic And Geochemical Study Of Samples...

    Open Energy Info (EERE)

    Mineralogical Petrographic And Geochemical Study Of Samples From Wells In The Geothermal Field Of Milos Island (Greece) Jump to: navigation, search OpenEI Reference LibraryAdd to...

  8. Geochemical Data on Waters, Gases, Scales, and Rocks from the...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999)...

  9. Geochemical and isotopic water results, Barrow, Alaska, 2012-2013

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Heikoop, Jeff; Wilson, Cathy; Newman, Brent

    2012-07-18

    Data include a large suite of analytes (geochemical and isotopic) for samples collected in Barrow, Alaska (2012-2013). Sample types are indicated, and include soil pore waters, drainage waters, snowmelt, precipitation, and permafrost samples.

  10. SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Signals in the Subsurface | Department of Energy SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical Signals in the Subsurface SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical Signals in the Subsurface Grand Challenge Workshop -Imaging Subsurface.pdf (434.52 KB) More Documents & Publications AGU SubTER Town Hall Presentation 2015 SubTER Presentation at Town Hall - American Geophysical Union Controlling Subsurface Fractures and Fluid Flow: A Basic

  11. Hiereachical Bayesian Model for Combining Geochemical and Geophysical Data for Environmental Applications Software

    Energy Science and Technology Software Center (OSTI)

    2013-05-01

    Development of a hierarchical Bayesian model to estimate the spatiotemporal distribution of aqueous geochemical parameters associated with in-situ bioremediation using surface spectral induced polarization (SIP) data and borehole geochemical measurements collected during a bioremediation experiment at a uranium-contaminated site near Rifle, Colorado. The SIP data are first inverted for Cole-Cole parameters including chargeability, time constant, resistivity at the DC frequency and dependence factor, at each pixel of two-dimensional grids using a previously developed stochastic method.more » Correlations between the inverted Cole-Cole parameters and the wellbore-based groundwater chemistry measurements indicative of key metabolic processes within the aquifer (e.g. ferrous iron, sulfate, uranium) were established and used as a basis for petrophysical model development. The developed Bayesian model consists of three levels of statistical sub-models: 1) data model, providing links between geochemical and geophysical attributes, 2) process model, describing the spatial and temporal variability of geochemical properties in the subsurface system, and 3) parameter model, describing prior distributions of various parameters and initial conditions. The unknown parameters are estimated using Markov chain Monte Carlo methods. By combining the temporally distributed geochemical data with the spatially distributed geophysical data, we obtain the spatio-temporal distribution of ferrous iron, sulfate and sulfide, and their associated uncertainity information. The obtained results can be used to assess the efficacy of the bioremediation treatment over space and time and to constrain reactive transport models.« less

  12. Geochemical Mud Logging of geothermal drilling

    SciTech Connect (OSTI)

    Tonani, F.B.; Guidi, M.; Johnson, S.D.

    1988-01-01

    The experience and results described in the present paper were developed over nearly two decades, with a major R&D project around 1980. The expression Geochemical Mud Logging (GML) has ill defined meaning in the geothermal industry, and ought to be specified. We refer here to GML as featuring mud and formation fluid tracer(s) and temperature as the bare essentials and with specified accuracies. Air and water logging are expected to be less demanding with regard to analysis accuracy, but are not discussed in this report. During application of GML to several drill holes with low formation permeabilities and under conditions of high temperature and high mud weight, GML as specified, revealed unexpected influx of formation brine. Such influx was a recurring feature that has been referenced to individual fractures and reflects both fracture size and permeability. As a consequence, continuous or subcontinuous sampling of mud systems appears more cost effective than trying to keep up with cumulative changes of bulk mud composition; although, the latter approach is more sensitive to extremely low rate, steady, inflow of formation fluid into the mud system. It appears, that based on this influx of formation fluid, permeability can be estimated well before mud losses are detected and/or drill strings are stuck. The main advantages of GML are: (1) the capability to assess formation temperature and permeability in nearly real time, resulting in (a) assessments of undisturbed formation and (b) having data in hand for holes lost during drilling operations and (2) being effective under conditions of very high temperatures where electrical logs are very costly and less reliable. Estimated cost for GML is $1500 per day (1982) based on assessments of R&D operations. However, extrapolating to larger scale services and to different operating conditions is indeed difficult. GML cost is probably the only significant point of controversy with regard to GML being a viable evaluation tool.

  13. Geochemical Modeling of ILAW Lysimeter Water Extracts

    SciTech Connect (OSTI)

    Cantrell, Kirk J.

    2014-12-22

    Geochemical modeling results of water extracts from simulated immobilized low-activity waste (ILAW) glasses, placed in lysimeters for eight years suggest that the secondary phase reaction network developed using product consistency test (PCT) results at 90°C may need to be modified for field conditions. For sediment samples that had been collected from near the glass samples, the impact of glass corrosion could be readily observed based upon the pH of their water extracts. For unimpacted sediments the pH ranged from 7.88 to 8.11 with an average of 8.04. Sediments that had observable impacts from glass corrosion exhibited elevated pH values (as high as 9.97). For lysimeter sediment samples that appear to have been impacted by glass corrosion to the greatest extent, saturation indices determined for analcime, calcite, and chalcedony in the 1:1 water extracts were near equilibrium and were consistent with the secondary phase reaction network developed using PCT results at 90°C. Fe(OH)3(s) also appears to be essentially at equilibrium in extracts impacted by glass corrosion, but with a solubility product (log Ksp) that is approximately 2.13 units lower than that used in the secondary phase reaction network developed using PCT results at 90°C. The solubilities of TiO2(am) and ZrO2(am) also appear to be much lower than that assumed in the secondary phase reaction network developed using PCT results at 90°C. The extent that the solubility of TiO2(am) and ZrO2(am) were reduced relative to that assumed in the secondary phase reaction network developed using PCT results at 90°C could not be quantified because the concentrations of Ti and Zr in the extracts were below the estimated quantification limit. Gibbsite was consistently highly oversaturated in the extract while dawsonite was at or near equilibrium. This suggests that dawsonite might be a more suitable phase for the secondary phase reaction network than gibbsite under field conditions. This may be due to the

  14. Geochemical Enhancement Of Enhanced Geothermal System Reservoirs: An Integrated Field And Geochemical Approach

    SciTech Connect (OSTI)

    Joseph N. Moore

    2007-12-31

    The geochemical effects of injecting fluids into geothermal reservoirs are poorly understood and may be significantly underestimated. Decreased performance of injection wells has been observed in several geothermal fields after only a few years of service, but the reasons for these declines has not been established. This study had three primary objectives: 1) determine the cause(s) of the loss of injectivity; 2) utilize these observations to constrain numerical models of water-rock interactions; and 3) develop injection strategies for mitigating and reversing the potential effects of these interactions. In this study rock samples from original and redrilled injection wells at Coso and the Salton Sea geothermal fields, CA, were used to characterize the mineral and geochemical changes that occurred as a result of injection. The study documented the presence of mineral scales and at both fields in the reservoir rocks adjacent to the injection wells. At the Salton Sea, the scales consist of alternating layers of fluorite and barite, accompanied by minor anhydrite, amorphous silica and copper arsenic sulfides. Amorphous silica and traces of calcite were deposited at Coso. The formation of silica scale at Coso provides an example of the effects of untreated (unacidified) injectate on the reservoir rocks. Scanning electron microscopy and X-ray diffractometry were used to characterize the scale deposits. The silica scale in the reservoir rocks at Coso was initially deposited as spheres of opal-A 1-2 micrometers in diameter. As the deposits matured, the spheres coalesced to form larger spheres up to 10 micrometer in diameter. Further maturation and infilling of the spaces between spheres resulted in the formation of plates and sheets that substantially reduce the original porosity and permeability of the fractures. Peripheral to the silica deposits, fluid inclusions with high water/gas ratios provide a subtle record of interactions between the injectate and reservoir rocks

  15. How 12 geochemical methods fared in GERT project in Permian basin

    SciTech Connect (OSTI)

    Calhoun, G.G.

    1991-05-13

    This paper reports on Geochemical Evaluation Research Team (GERT) which is an experiment conceived to identify surface geochemical exploration methods that are effective in finding oil. Many of the methods use technology developed in the last 5 years. In fact, one of the challenging jobs for the geochemical explorationist is keeping up with new techniques and improvements. The way to minimize dry holes is to screen prospects with carefully selected geochemical techniques prior to acreage acquisition and seismic surveys.

  16. Argonne Geothermal Geochemical Database v2.0

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Harto, Christopher

    A database of geochemical data from potential geothermal sources aggregated from multiple sources as of March 2010. The database contains fields for the location, depth, temperature, pH, total dissolved solids concentration, chemical composition, and date of sampling. A separate tab contains data on non-condensible gas compositions. The database contains records for over 50,000 wells, although many entries are incomplete. Current versions of source documentation are listed in the dataset.

  17. Argonne Geothermal Geochemical Database v2.0

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Harto, Christopher

    2013-05-22

    A database of geochemical data from potential geothermal sources aggregated from multiple sources as of March 2010. The database contains fields for the location, depth, temperature, pH, total dissolved solids concentration, chemical composition, and date of sampling. A separate tab contains data on non-condensible gas compositions. The database contains records for over 50,000 wells, although many entries are incomplete. Current versions of source documentation are listed in the dataset.

  18. Geochemical drivers of organic matter decomposition in Arctic tundra soils

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Herndon, Elizabeth M.; Yang, Ziming; Graham, David E.; Wullschleger, Stan D.; Gu, Baohua; Liang, Liyuan; Bargar, John; Janot, Noemie; Regier, Tom Z.

    2015-12-07

    Climate change is warming tundra ecosystems in the Arctic, resulting in the decomposition of previously-frozen soil organic matter (SOM) and release of carbon (C) to the atmosphere; however, the processes that control SOM decomposition and C emissions remain highly uncertain. In this study, we evaluate geochemical factors that influence anaerobic production of carbon dioxide (CO2) and methane (CH4) in the active layers of four ice-wedge polygons. Surface and soil pore waters were collected during the annual thaw season over a two-year period in an area containing waterlogged, low-centered polygons and well-drained, high-centered polygons. We report spatial and seasonal patterns ofmore » dissolved gases in relation to the geochemical properties of Fe and organic C as determined using spectroscopic and chromatographic techniques. Iron was present as Fe(II) in soil solution near the permafrost boundary but enriched as Fe(III) in the middle of the active layer, similar to dissolved aromatic-C and organic acids. Dissolved CH4 increased relative to dissolved CO2 with depth and varied with soil moisture in the middle of the active layer in patterns that were positively correlated with the proportion of dissolved Fe(III) in transitional and low-centered polygon soils but negatively correlated in the drier flat- and high-centered polygons. These results suggest that microbial-mediated Fe oxidation and reduction influence respiration/fermentation of SOM and production of substrates (e.g., low-molecular-weight organic acids) for methanogenesis. As a result, we infer that geochemical differences induced by water saturation dictate microbial products of SOM decomposition, and Fe geochemistry is an important factor regulating methanogenesis in anoxic tundra soils.« less

  19. Geochemical drivers of organic matter decomposition in Arctic tundra soils

    SciTech Connect (OSTI)

    Herndon, Elizabeth M.; Yang, Ziming; Graham, David E.; Wullschleger, Stan D.; Gu, Baohua; Liang, Liyuan; Bargar, John; Janot, Noemie; Regier, Tom Z.

    2015-12-07

    Climate change is warming tundra ecosystems in the Arctic, resulting in the decomposition of previously-frozen soil organic matter (SOM) and release of carbon (C) to the atmosphere; however, the processes that control SOM decomposition and C emissions remain highly uncertain. In this study, we evaluate geochemical factors that influence anaerobic production of carbon dioxide (CO2) and methane (CH4) in the active layers of four ice-wedge polygons. Surface and soil pore waters were collected during the annual thaw season over a two-year period in an area containing waterlogged, low-centered polygons and well-drained, high-centered polygons. We report spatial and seasonal patterns of dissolved gases in relation to the geochemical properties of Fe and organic C as determined using spectroscopic and chromatographic techniques. Iron was present as Fe(II) in soil solution near the permafrost boundary but enriched as Fe(III) in the middle of the active layer, similar to dissolved aromatic-C and organic acids. Dissolved CH4 increased relative to dissolved CO2 with depth and varied with soil moisture in the middle of the active layer in patterns that were positively correlated with the proportion of dissolved Fe(III) in transitional and low-centered polygon soils but negatively correlated in the drier flat- and high-centered polygons. These results suggest that microbial-mediated Fe oxidation and reduction influence respiration/fermentation of SOM and production of substrates (e.g., low-molecular-weight organic acids) for methanogenesis. As a result, we infer that geochemical differences induced by water saturation dictate microbial products of SOM decomposition, and Fe geochemistry is an important factor regulating methanogenesis in anoxic tundra soils.

  20. EQ3/6 A Software Package for Geochemical Modeling

    Energy Science and Technology Software Center (OSTI)

    2010-12-13

    EQ3/6 is a software package for modeling geochemical interactions between aqueous solution, solids, and gases, following principles of chemical thermodynamics and chemical kinetics. It is useful for interpreting aqueiou solution chemical compositions and for calculating the consequences of reaction of such solutions with minerals, other solids, and gases. It is designed to run in a command line environment. EQPT is a thermodynamic data file preprocessor. EQ3NR is a speciation-solubility code. EQ6 is a reaction pathmore » code.« less

  1. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1 Citation Details...

  2. Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators

    Broader source: Energy.gov [DOE]

    Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators presentation at the April 2013 peer review meeting held in Denver, Colorado.

  3. New Mexico Play Fairway Analysis: New Mexico available wells for geochemical sampling

    SciTech Connect (OSTI)

    Jeff Pepin

    2015-11-15

    This is a map package that is used to show the wells in New Mexico that may be available for geochemical sampling.

  4. Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal systems

    Broader source: Energy.gov [DOE]

    Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal systems presentation at the April 2013 peer review meeting held in Denver, Colorado.

  5. INEEL Subregional Conceptual Model Report Volume 2: Summary of Existing Knowledge of Geochemical Influences on the Fate and Transport of Contaminants in the Subsurface at the INEEL

    SciTech Connect (OSTI)

    Paul L. Wichlacz; Robert C. Starr; Brennon Orr

    2003-09-01

    This document summarizes previous descriptions of geochemical system conceptual models for the vadose zone and groundwater zone (aquifer) beneath the Idaho National Engineering and Environmental Laboratory (INEEL). The primary focus is on groundwater because contaminants derived from wastes disposed at INEEL are present in groundwater, groundwater provides a pathway for potential migration to receptors, and because geochemical characteristics in and processes in the aquifer can substantially affect the movement, attenuation, and toxicity of contaminants. The secondary emphasis is perched water bodies in the vadose zone. Perched water eventually reaches the regional groundwater system, and thus processes that affect contaminants in the perched water bodies are important relative to the migration of contaminants into groundwater. Similarly, processes that affect solutes during transport from nearsurface disposal facilities downward through the vadose zone to the aquifer are relevant. Sediments in the vadose zone can affect both water and solute transport by restricting the downward migration of water sufficiently that a perched water body forms, and by retarding solute migration via ion exchange. Geochemical conceptual models have been prepared by a variety of researchers for different purposes. They have been published in documents prepared by INEEL contractors, the United States Geological Survey (USGS), academic researchers, and others. The documents themselves are INEEL and USGS reports, and articles in technical journals. The documents reviewed were selected from citation lists generated by searching the INEEL Technical Library, the INEEL Environmental Restoration Optical Imaging System, and the ISI Web of Science databases. The citation lists were generated using the keywords ground water, groundwater, chemistry, geochemistry, contaminant, INEL, INEEL, and Idaho. In addition, a list of USGS documents that pertain to the INEEL was obtained and manually searched

  6. Geochemical information for sites contaminated with low-level radioactive wastes: I. Niagara Falls Storage Site

    SciTech Connect (OSTI)

    Seeley, F.G.; Kelmers, A.D.

    1984-11-01

    The Niagara Falls Storage Site (NFSS) became radioactively contaminated as a result of wastes that were being stored from operations carried out to recover uranium from pitchblende ore in the 1940s and 1950s. The US Department of Energy (DOE) is considering various remedial action options for the NFSS. This report describes the results of geochemical investigations performed to help provide a quantitative evaluation of the effects of various options. NFSS soil and groundwater samples were characterized; and uranium and radium sorption ratios, as well as apparent concentration limit values, were measured in site soil/groundwater systems by employing batch contact methodology. The results suggest that any uranium which is in solution in the groundwater at the NFSS may be poorly retarded due to the low uranium sorption ratio values and high solubility measured. Further, appreciable concentrations of uranium in groundwater could be attained from soluble wastes. Release of uranium via groundwater migration could be a significant release pathway. Solubilized radium would be expected to be effectively retarded by soil at the NFSS as a result of the very high radium sorption ratios observed. The addition of iron oxyhydroxide to NFSS soils resulted in much higher uranium sorption ratios. Additional field testing of this potential remedial action additive could be desirable. 10 references.

  7. The hydrogeologic-geochemical model of Cerro Prieto revisited

    SciTech Connect (OSTI)

    Lippmann, M.J.; Halfman, S.E.; Truesdell, A.H.; Manon M., A.

    1989-01-01

    As the exploitation of the Cerro Prieto, Mexico, geothermal field continues, there is increasing evidence that the hydrogeologic model developed by Halfman et al. (1984, 1986) presents the basic features controlling the movement of geothermal fluids in the system. At the present time the total installed capacity at Cerro Prieto is 620 MWe requiring the production of more than 10,500 tonnes/hr of a brine-steam mixture. This significant rate of fluid production has resulted in changes in reservoir thermodynamic conditions and in the chemistry of the produced fluids. After reviewing the hydrogeologic-geochemical model of Cerro Prieto, some of the changes observed in the field due to its exploitation are discussed and interpreted on the basis of the model. 21 refs., 11 figs., 1 tab.

  8. WATEQ3 geochemical model: thermodynamic data for several additional solids

    SciTech Connect (OSTI)

    Krupka, K.M.; Jenne, E.A.

    1982-09-01

    Geochemical models such as WATEQ3 can be used to model the concentrations of water-soluble pollutants that may result from the disposal of nuclear waste and retorted oil shale. However, for a model to competently deal with these water-soluble pollutants, an adequate thermodynamic data base must be provided that includes elements identified as important in modeling these pollutants. To this end, several minerals and related solid phases were identified that were absent from the thermodynamic data base of WATEQ3. In this study, the thermodynamic data for the identified solids were compiled and selected from several published tabulations of thermodynamic data. For these solids, an accepted Gibbs free energy of formation, ..delta..G/sup 0//sub f,298/, was selected for each solid phase based on the recentness of the tabulated data and on considerations of internal consistency with respect to both the published tabulations and the existing data in WATEQ3. For those solids not included in these published tabulations, Gibbs free energies of formation were calculated from published solubility data (e.g., lepidocrocite), or were estimated (e.g., nontronite) using a free-energy summation method described by Mattigod and Sposito (1978). The accepted or estimated free energies were then combined with internally consistent, ancillary thermodynamic data to calculate equilibrium constants for the hydrolysis reactions of these minerals and related solid phases. Including these values in the WATEQ3 data base increased the competency of this geochemical model in applications associated with the disposal of nuclear waste and retorted oil shale. Additional minerals and related solid phases that need to be added to the solubility submodel will be identified as modeling applications continue in these two programs.

  9. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and Organic Leakage into an Unconfined, Oxidizing Limestone Aquifer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bacon, Diana H.; Dai, Zhenxue; Zheng, Liange

    2014-12-31

    An important risk at CO2 storage sites is the potential for groundwater quality impacts. As part of a system to assess the potential for these impacts a geochemical scaling function has been developed, based on a detailed reactive transport model of CO2 and brine leakage into an unconfined, oxidizing carbonate aquifer. Stochastic simulations varying a number of geochemical parameters were used to generate a response surface predicting the volume of aquifer that would be impacted with respect to regulated contaminants. The brine was assumed to contain several trace metals and organic contaminants. Aquifer pH and TDS were influenced by CO2more » leakage, while trace metal concentrations were most influenced by the brine concentrations rather than adsorption or desorption on calcite. Organic plume sizes were found to be strongly influenced by biodegradation.« less

  10. Modeling Background Radiation in our Environment Using Geochemical Data

    SciTech Connect (OSTI)

    Malchow, Russell L.; Marsac, Kara; Burnley, Pamela; Hausrath, Elisabeth; Haber, Daniel; Adcock, Christopher

    2015-02-01

    Radiation occurs naturally in bedrock and soil. Gamma rays are released from the decay of the radioactive isotopes K, U, and Th. Gamma rays observed at the surface come from the first 30 cm of rock and soil. The energy of gamma rays is specific to each isotope, allowing identification. For this research, data was collected from national databases, private companies, scientific literature, and field work. Data points were then evaluated for self-consistency. A model was created by converting concentrations of U, K, and Th for each rock and soil unit into a ground exposure rate using the following equation: D=1.32 K+ 0.548 U+ 0.272 Th. The first objective of this research was to compare the original Aerial Measurement System gamma ray survey to results produced by the model. The second objective was to improve the method and learn the constraints of the model. Future work will include sample data analysis from field work with a goal of improving the geochemical model.

  11. 31 TAC, part 1, chapter 9, rule 9.11 Geophysical and Geochemical...

    Open Energy Info (EERE)

    9, rule 9.11 Geophysical and Geochemical Exploration Permits Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- RegulationRegulation: 31 TAC, part...

  12. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide...

    Office of Scientific and Technical Information (OSTI)

    Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1 Bacon, Diana H. carbon...

  13. Merging high resolution geophysical and geochemical surveys to reduce exploration risk at Glass Buttes, Oregon

    Broader source: Energy.gov [DOE]

    DOE Geothermal Technologies Peer Review - 2010. The primary objective of this project is to combine a suite of high resolution geophysical and geochemical techniques to reduce exploration risk by characterizing hydrothermal alteration, fault geometries and relationships.

  14. A geochemical model of the Kilauea east rift zone | Open Energy...

    Open Energy Info (EERE)

    rift zone Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A geochemical model of the Kilauea east rift zone Abstract NA Author Donald Thomas...

  15. A Geological and Hydro-Geochemical Study of the Animas Geothermal...

    Open Energy Info (EERE)

    Hydro-Geochemical Study of the Animas Geothermal Area, Hidalgo County, New Mexico Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Geological...

  16. Geochemical Monitoring Considerations for the FutureGen 2.0 Project

    SciTech Connect (OSTI)

    Amonette, James E.; Johnson, Timothy A.; Spencer, Clayton F.; Zhong, Lirong; Szecsody, James E.; Vermeul, Vince R.

    2014-12-31

    Geochemical monitoring is an essential component of a suite of monitoring technologies designed to evaluate CO2 mass balance and detect possible loss of containment at the FutureGen 2.0 geologic sequestration site near Jacksonville, IL. This presentation gives an overview of the potential geochemical approaches and tracer technologies that were considered, and describes the evaluation process by which the most cost-effective and robust of these were selected for implementation

  17. Geochemical and physical properties of wetland soils at the Savannah River site

    SciTech Connect (OSTI)

    Dixon, K.L; Rogers, V.A.; Conner, S.P.; Cummings, C.L.; Gladden, J.B.; Weber, J.M.

    1996-05-01

    The Savannah River Site (SRS), located in Aiken, Allendale, and Barnwell Counties, South Carolina, is a nuclear production facility operated for the U.S. Department of Energy (DOE) by Westinghouse Savannah River Company (WSRC). To facilitate future human health and ecological risk assessments, treatability studies, remedial investigations, and feasibility studies for its wetland areas, SRS needs a database of background geochemical and physical properties of wetland soils. These data are needed for comparison to data collected from wetland soils that may have been affected by SRS operations. SRS contains 36,000 acres of wetlands and an additional 5,000 acres of bottom land soils subject to flooding. Recent studies of wetland soils near various waste units at SRS show that some wetlands have been impacted by releases of contaminants resulting from SRS operations (WSRC, 1992). Waste waters originating from the operations facilities typically have been discharged into seepage basins located in upland soils, direct discharge of waste water to wetland areas has been minimal. This suggests that impacted wetland areas have been affected indirectly as a result of transport mechanisms such as surface runoff, groundwater seeps, fluvial or sediment transport, and leaching. Looney et al. (1990) conducted a study to characterize the geochemical and physical properties of upland soils and shallow sediments on the SRS. A primary objective of the upland study was to collect the data needed to assess the qualitative and quantitative impacts of SRS operations on the environment. By comparing the upland soils data to data collected from waste units located in similar soils, SRS impacts could be assessed. The data were also intended to aid in selection of remediation alternatives. Because waste units at SRS have historically been located in upland areas, wetland soils were not sampled. (Abstract Truncated)

  18. Natural bacterial communities serve as quantitative geochemical biosensors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smith, Mark B.; Rocha, Andrea M.; Smillie, Chris S.; Olesen, Scott W.; Paradis, Charles; Wu, Liyou; Campbell, James H.; Fortney, Julian L.; Mehlhorn, Tonia L.; Lowe, Kenneth A.; et al

    2015-05-12

    Biological sensors can be engineered to measure a wide range of environmental conditions. Here we show that statistical analysis of DNA from natural microbial communities can be used to accurately identify environmental contaminants, including uranium and nitrate at a nuclear waste site. In addition to contamination, sequence data from the 16S rRNA gene alone can quantitatively predict a rich catalogue of 26 geochemical features collected from 93 wells with highly differing geochemistry characteristics. We extend this approach to identify sites contaminated with hydrocarbons from the Deepwater Horizon oil spill, finding that altered bacterial communities encode a memory of prior contamination,more » even after the contaminants themselves have been fully degraded. We show that the bacterial strains that are most useful for detecting oil and uranium are known to interact with these substrates, indicating that this statistical approach uncovers ecologically meaningful interactions consistent with previous experimental observations. Future efforts should focus on evaluating the geographical generalizability of these associations. Taken as a whole, these results indicate that ubiquitous, natural bacterial communities can be used as in situ environmental sensors that respond to and capture perturbations caused by human impacts. These in situ biosensors rely on environmental selection rather than directed engineering, and so this approach could be rapidly deployed and scaled as sequencing technology continues to become faster, simpler, and less expensive. Here we show that DNA from natural bacterial communities can be used as a quantitative biosensor to accurately distinguish unpolluted sites from those contaminated with uranium, nitrate, or oil. These results indicate that bacterial communities can be used as environmental sensors that respond to and capture perturbations caused by human impacts.« less

  19. Geochemical characteristics of bitumens and seeps from Tanzania

    SciTech Connect (OSTI)

    Mpanju, F. ); Philp, P. )

    1991-03-01

    A number of bitumen extracts from prospective source rocks and oil seeps of potential oil-producing areas in Tanzania have been characterized by a variety of geochemical techniques. The data obtained from this study have provided additional insight into the source rock potential of these areas. However, in this paper it is proposed to discuss in detail the results from two of the more unusual samples in this region, namely Wingayongo and Pemba. The Wingayongo bitumens isolated from an exposed Neocomian-aged sandstone, possibly a paleoreservoir, are almost totally devoid of n-alkanes and steranes and dominated by hopane-type biomarkers with the so-called immature {beta}{beta}-stereochemistry at the C{sub 17} and C{sub 21} positions. There is no typical evidence of biodegradation having occurred leading to the proposal of an unusual source material or maturity history for this sample. The Pemba seep samples were also characterized by relatively high concentrations of hopanes with the immature stereochemistry at the C{sub 17} and C{sub 21} positions and a virtual absence of n-alkanes and steranes. The aromatic fractions contained relatively high concentrations of hopanic acids, with the immature stereochemistry at C{sub 17} and C{sub 21} positions and a virtual absence of n-alkanes and steranes. The aromatic fractions contained relatively high concentrations of hopanic acids, with the immature stereochemistry at C{sub 17} and C{sub 21}. On the basis of these data, it is proposed that the seeps in the Pemba region are not true oil seeps. Rather they are formed as a result of extremely high levels of bacterial activity with the bacteria utilizing natural gas in the region as the substrate. The net result is a material referred to in other areas of the world as paraffin dirt whose occurrence results from extensive microbial activity in the region and not directly from seepage of products having a thermal origin.

  20. Natural bacterial communities serve as quantitative geochemical biosensors

    SciTech Connect (OSTI)

    Smith, Mark B.; Rocha, Andrea M.; Smillie, Chris S.; Olesen, Scott W.; Paradis, Charles; Wu, Liyou; Campbell, James H.; Fortney, Julian L.; Mehlhorn, Tonia L.; Lowe, Kenneth A.; Earles, Jennifer E.; Phillips, Jana; Techtmann, Steve M.; Joyner, Dominique C.; Elias, Dwayne A.; Bailey, Kathryn L.; Hurt, Richard A.; Preheim, Sarah P.; Sanders, Matthew C.; Yang, Joy; Mueller, Marcella A.; Brooks, Scott; Watson, David B.; Zhang, Ping; He, Zhili; Dubinsky, Eric A.; Adams, Paul D.; Arkin, Adam P.; Fields, Matthew W.; Zhou, Jizhong; Alm, Eric J.; Hazen, Terry C.

    2015-05-12

    Biological sensors can be engineered to measure a wide range of environmental conditions. Here we show that statistical analysis of DNA from natural microbial communities can be used to accurately identify environmental contaminants, including uranium and nitrate at a nuclear waste site. In addition to contamination, sequence data from the 16S rRNA gene alone can quantitatively predict a rich catalogue of 26 geochemical features collected from 93 wells with highly differing geochemistry characteristics. We extend this approach to identify sites contaminated with hydrocarbons from the Deepwater Horizon oil spill, finding that altered bacterial communities encode a memory of prior contamination, even after the contaminants themselves have been fully degraded. We show that the bacterial strains that are most useful for detecting oil and uranium are known to interact with these substrates, indicating that this statistical approach uncovers ecologically meaningful interactions consistent with previous experimental observations. Future efforts should focus on evaluating the geographical generalizability of these associations. Taken as a whole, these results indicate that ubiquitous, natural bacterial communities can be used as in situ environmental sensors that respond to and capture perturbations caused by human impacts. These in situ biosensors rely on environmental selection rather than directed engineering, and so this approach could be rapidly deployed and scaled as sequencing technology continues to become faster, simpler, and less expensive. Here we show that DNA from natural bacterial communities can be used as a quantitative biosensor to accurately distinguish unpolluted sites from those contaminated with uranium, nitrate, or oil. These results indicate that bacterial communities can be used as environmental sensors that respond to and capture perturbations caused by human impacts.

  1. Geochemical information for sites contaminated with low-level radioactive wastes. III. Weldon Spring Storage Site

    SciTech Connect (OSTI)

    Seeley, F.G.; Kelmers, A.D.

    1985-02-01

    The Weldon Spring Storage Site (WSSS), which includes both the chemical site and the quarry, became radioactively contaminated as the result of wastes that were being stored from operations to recover uranium from pitchblende ores in the 1940s and 1950s. The US Department of Energy (DOE) is considering various remedial action options for the WSSS. This report describes the results of geochemical investigations carried out at Oak Ridge National Laboratory (ORNL) to support these activities and to help quantify various remedial action options. Soil and groundwater samples were characterized, and uranium and radium sorption ratios were measured in site soil/groundwater systems by batch contact methodology. Soil samples from various locations around the raffinate pits were found to contain major amounts of silica, along with illite as the primary clay constituent. Particle sizes of the five soil samples were variable (50% distribution point ranging from 12 to 81 ..mu..m); the surface areas varied from 13 to 62 m/sup 2//g. Elemental analysis of the samples showed them to be typical of sandy clay and silty clay soils. Groundwater samples included solution from Pit 3 and well water from Well D. Anion analyses showed significant concentrations of sulfate and nitrate (>350 and >7000 mg/L, respectively) in the solution from Pit 3. These anions were also present in the well water, but in lower concentrations. Uranium sorption ratios for four of the soil samples contacted with the solution from Pit 3 were moderate to high (approx. 300 to approx. 1000 mL/g). The fifth sample had a ratio of only 12 mL/g. Radium sorption ratios for the five samples were moderate to high (approx. 600 to approx. 1000 mL/g). These values indicate that soil at the WSSS may show favorable retardation of uranium and radium in the groundwater. 13 references, 13 figures, 10 tables.

  2. Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting

    SciTech Connect (OSTI)

    Mani, Devleena; Kumar, T. Satish; Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V.

    2011-03-15

    The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana-Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r{sup 2} < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

  3. Monitoring CO2 intrusion and associated geochemical transformations...

    Office of Scientific and Technical Information (OSTI)

    transformations in a shallow groundwater system using complex electrical methods Citation ... Country of Publication: United States Language: English Subject: 54 ENVIRONMENTAL ...

  4. The low temperature hydrothermal system of Campiglia, Tuscany (Italy); A geochemical approach

    SciTech Connect (OSTI)

    Celati, R.; Grassi, S.; D'Amore, F.; Marcolini, L. )

    1991-01-01

    This paper reports on the Campiglia hydrothermal system which is a low temperature hydrothermal system located in southwestern Tuscany, a region of Italy characterized by intense geothermal activity and by the presence of high temperature exploited geothermal reservoirs. Six water-points, with temperatures ranging between 20 and 47{degrees} C and different chemical and isotopic compositions, are found close to the margins of outcrops of the main regional aquifer formation. Systematic hydrogeological, geochemical and isotopic observations and temperature measurements were carried out on the different springs and wells for a period of three years (1984-1986). Constant water characteristics with time were observed in four water-points; two wells had variable trends depending on mixing processes. A groundwater circulation model characterized by flowpaths of different length and depth is suggested by the variety of chemical and isotopic characteristics and is consistent with geothermometry, which indicates temperatures up to 25{degrees} C higher than those measured at the spring emergencies. An important water supply to the system comes from local recharge, although regional circulation may also be present, particularly in the eastern part of the investigated area.

  5. Coupled Geochemical Impacts of Leaking CO2 and Contaminants from...

    Office of Scientific and Technical Information (OSTI)

    on the sediments, in spite of the lowered pH due to CO2 dissolution in the groundwater. ... without detectable carbonate to buffer the pH. Arsenic concentrations in the effluent ...

  6. Geochemical Data Package for the 2005 Hanford Integrated Disposal Facility Performance Assessment

    SciTech Connect (OSTI)

    Krupka, Kenneth M.; Serne, R JEFFREY.; Kaplan, D I.

    2004-09-30

    CH2M HILL Hanford Group, Inc. (CH2M HILL) is designing and assessing the performance of an integrated disposal facility (IDF) to receive low-level waste (LLW), mixed low-level waste (MLLW), immobilized low-activity waste (ILAW), and failed or decommissioned melters. The CH2M HILL project to assess the performance of this disposal facility is the Hanford IDF Performance Assessment (PA) activity. The goal of the Hanford IDF PA activity is to provide a reasonable expectation that the disposal of the waste is protective of the general public, groundwater resources, air resources, surface-water resources, and inadvertent intruders. Achieving this goal will require prediction of contaminant migration from the facilities. This migration is expected to occur primarily via the movement of water through the facilities, and the consequent transport of dissolved contaminants in the vadose zone to groundwater where contaminants may be re-introduced to receptors via drinking water wells or mixing in the Columbia River. Pacific Northwest National Laboratory (PNNL) assists CH2M HILL in their performance assessment activities. One of the PNNL tasks is to provide estimates of the geochemical properties of the materials comprising the IDF, the disturbed region around the facility, and the physically undisturbed sediments below the facility (including the vadose zone sediments and the aquifer sediments in the upper unconfined aquifer). The geochemical properties are expressed as parameters that quantify the adsorption of contaminants and the solubility constraints that might apply for those contaminants that may exceed solubility constraints. The common parameters used to quantify adsorption and solubility are the distribution coefficient (Kd) and the thermodynamic solubility product (Ksp), respectively. In this data package, we approximate the solubility of contaminants using a more simplified construct, called the solution concentration limit, a constant value. The Kd values and

  7. Geochemical detection of carbon dioxide in dilute aquifers

    SciTech Connect (OSTI)

    Carroll, S; Hao, Y; Aines, R

    2009-03-27

    Carbon storage in deep saline reservoirs has the potential to lower the amount of CO{sub 2} emitted to the atmosphere and to mitigate global warming. Leakage back to the atmosphere through abandoned wells and along faults would reduce the efficiency of carbon storage, possibly leading to health and ecological hazards at the ground surface, and possibly impacting water quality of near-surface dilute aquifers. We use static equilibrium and reactive transport simulations to test the hypothesis that perturbations in water chemistry associated with a CO{sub 2} gas leak into dilute groundwater are important measures for the potential release of CO{sub 2} to the atmosphere. Simulation parameters are constrained by groundwater chemistry, flow, and lithology from the High Plains aquifer. The High Plains aquifer is used to represent a typical sedimentary aquifer overlying a deep CO{sub 2} storage reservoir. Specifically, we address the relationships between CO{sub 2} flux, groundwater flow, detection time and distance. The CO{sub 2} flux ranges from 10{sup 3} to 2 x 10{sup 6} t/yr (0.63 to 1250 t/m{sup 2}/yr) to assess chemical perturbations resulting from relatively small leaks that may compromise long-term storage, water quality, and surface ecology, and larger leaks characteristic of short-term well failure.

  8. Model-Based Analysis of the Role of Biological, Hydrological and Geochemical Factors Affecting Uranium Bioremediation

    SciTech Connect (OSTI)

    Zhao, Jiao; Scheibe, Timothy D.; Mahadevan, Radhakrishnan

    2011-01-24

    Uranium contamination is a serious concern at several sites motivating the development of novel treatment strategies such as the Geobacter-mediated reductive immobilization of uranium. However, this bioremediation strategy has not yet been optimized for the sustained uranium removal. While several reactive-transport models have been developed to represent Geobacter-mediated bioremediation of uranium, these models often lack the detailed quantitative description of the microbial process (e.g., biomass build-up in both groundwater and sediments, electron transport system, etc.) and the interaction between biogeochemical and hydrological process. In this study, a novel multi-scale model was developed by integrating our recent model on electron capacitance of Geobacter (Zhao et al., 2010) with a comprehensive simulator of coupled fluid flow, hydrologic transport, heat transfer, and biogeochemical reactions. This mechanistic reactive-transport model accurately reproduces the experimental data for the bioremediation of uranium with acetate amendment. We subsequently performed global sensitivity analysis with the reactive-transport model in order to identify the main sources of prediction uncertainty caused by synergistic effects of biological, geochemical, and hydrological processes. The proposed approach successfully captured significant contributing factors across time and space, thereby improving the structure and parameterization of the comprehensive reactive-transport model. The global sensitivity analysis also provides a potentially useful tool to evaluate uranium bioremediation strategy. The simulations suggest that under difficult environments (e.g., highly contaminated with U(VI) at a high migration rate of solutes), the efficiency of uranium removal can be improved by adding Geobacter species to the contaminated site (bioaugmentation) in conjunction with the addition of electron donor (biostimulation). The simulations also highlight the interactive effect of

  9. Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimizing parameters for predicting the geochemical behavior and performance of discrete fracture networks in geothermal systems Alexandra Hakala (National Energy Technology Laboratory) Track 1 Project Officer: Lauren Boyd Total Project Funding: $995,718 April 25, 2013 This presentation does not contain any proprietary confidential, or otherwise restricted information. 2 | US DOE Geothermal Office eere.energy.gov Relevance/Impact of Research * Fractures - primary pathway for geothermal heat

  10. Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improved Geothermometry Through Multivariate Reaction Path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators Project Officer: Eric Hass Total Project Funding: $999,000 April 24, 2013 Craig Cooper Larry Hull Idaho National Laboratory This presentation does not contain any proprietary confidential, or otherwise restricted information. 2 | US DOE Geothermal Program eere.energy.gov Relevance/Impact of Research Geothermometry enables estimation of

  11. Kinetics of Uranium(VI) Desorption from Contaminated Sediments: Effect of Geochemical Conditions and Model Evaluation

    SciTech Connect (OSTI)

    Liu, Chongxuan; Shi, Zhenqing; Zachara, John M.

    2009-09-01

    Stirred-flow cell experiments were performed to investigate the kinetics of uranyl [U(VI)] desorption from a contaminated sediment collected from the Hanford 300 Area at the US Department of Energy (DOE) Hanford Site, Washington. Three influent solutions of variable pH, Ca and carbonate concentrations that affected U(VI) aqueous and surface speciation were used under dynamic flow conditions to evaluate the effect of geochemical conditions on the rate of U(VI) desorption. The measured rate of U(VI) desorption varied with solution chemical composition that evolved as a result of thermodynamic and kinetic interactions between the influent solutions and sediment. The solution chemical composition that led to a lower equilibrium U(VI) sorption to the solid phase yielded a faster desorption rate. The experimental results were used to evaluate a multi-rate, surface complexation model (SCM) that has been proposed to describe U(VI) desorption kinetics in the Hanford sediment that contained complex sorbed U(VI) species in mass transfer limited domains. The model was modified and supplemented by including multi-rate, ion exchange reactions to describe the geochemical interactions between the solutions and sediment. With the same set of model parameters, the modified model reasonably well described the evolution of major ions and the rates of U(VI) desorption under variable geochemical and flow conditions, implying that the multi-rate SCM is an effective way to describe U(VI) desorption kinetics in subsurface sediments.

  12. Groundwater Sampling At Kilauea East Rift Geothermal Area (Cox...

    Open Energy Info (EERE)

    groundwater can be a useful geochemical indicator for geothermal exploration when other water chemistry techniques are ambiguous. This research was useful for locating some areas...

  13. Thermodynamic Data for Geochemical Modeling of Carbonate Reactions Associated with CO2 Sequestration – Literature Review

    SciTech Connect (OSTI)

    Krupka, Kenneth M.; Cantrell, Kirk J.; McGrail, B. Peter

    2010-09-28

    Permanent storage of anthropogenic CO2 in deep geologic formations is being considered as a means to reduce the concentration of atmospheric CO2 and thus its contribution to global climate change. To ensure safe and effective geologic sequestration, numerous studies have been completed of the extent to which the CO2 migrates within geologic formations and what physical and geochemical changes occur in these formations when CO2 is injected. Sophisticated, computerized reservoir simulations are used as part of field site and laboratory CO2 sequestration studies. These simulations use coupled multiphase flow-reactive chemical transport models and/or standalone (i.e., no coupled fluid transport) geochemical models to calculate gas solubility, aqueous complexation, reduction/oxidation (redox), and/or mineral solubility reactions related to CO2 injection and sequestration. Thermodynamic data are critical inputs to modeling geochemical processes. The adequacy of thermodynamic data for carbonate compounds has been identified as an important data requirement for the successful application of these geochemical reaction models to CO2 sequestration. A review of thermodynamic data for CO2 gas and carbonate aqueous species and minerals present in published data compilations and databases used in geochemical reaction models was therefore completed. Published studies that describe mineralogical analyses from CO2 sequestration field and natural analogue sites and laboratory studies were also reviewed to identify specific carbonate minerals that are important to CO2 sequestration reactions and therefore require thermodynamic data. The results of the literature review indicated that an extensive thermodynamic database exists for CO2 and CH4 gases, carbonate aqueous species, and carbonate minerals. Values of ∆fG298° and/or log Kr,298° are available for essentially all of these compounds. However, log Kr,T° or heat capacity values at temperatures above 298 K exist for less than

  14. Geochemical Processes Data Package for the Vadose Zone in the Single-Shell Tank Waste Management Areas at the Hanford Site

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Zachara, John M.; Dresel, P. Evan; Krupka, Kenneth M.; Serne, R. Jeffrey

    2007-09-28

    This data package discusses the geochemistry of vadose zone sediments beneath the single-shell tank farms at the U.S. Department of Energy’s (DOE’s) Hanford Site. The purpose of the report is to provide a review of the most recent and relevant geochemical process information available for the vadose zone beneath the single-shell tank farms and the Integrated Disposal Facility. Two companion reports to this one were recently published which discuss the geology of the farms (Reidel and Chamness 2007) and groundwater flow and contamination beneath the farms (Horton 2007).

  15. Geochemical information for sites contaminated with low-level radioactive wastes: II. St. Louis Airport Storage Site

    SciTech Connect (OSTI)

    Seeley, F.G.; Kelmers, A.D.

    1985-01-01

    The St. Louis Airport Storage Site (SLASS) became radioactively contaminated as a result of wastes that were being stored from operations to recover uranium from pitchblende ores in the 1940s and 1950s. The US Department of Energy is considering various remedial action options for the SLASS under the Formerly Utilized Site Remedial Action Program (FUSRAP). This report describes the results of geochemical investigations, carried out to support the FUSRAP activities and to aid in quantifying various remedial action options. Soil and groundwater samples from the site were characterized, and sorption ratios for uranium and radium and apparent concentration limit values for uranium were measured in soil/groundwater systems by batch contact methodology. The uranium and radium concentrations in soil samples were significantly above background near the old contaminated surface horizon (now at the 0.3/sup -/ to 0.9/sup -/m depth); the maximum values were 1566 ..mu..g/g and 101 pCi/g, respectively. Below about the 6/sup -/m depth, the concentrations appeared to be typical of those naturally present in soils of this area (3.8 +- 1.2 ..mu..g/g and 3.1 +- 0.6 pCi/g). Uranium sorption ratios showed stratigraphic trends but were generally moderate to high (100 to 1000 L/kg). The sorption isotherm suggested an apparent uranium concentration limit of about 200 mg/L. This relatively high solubility can probably be correlated with the carbonate content of the soil/groundwater systems. The lower sorption ratio values obtained from the sorption isotherm may have resulted from changes in the experimental procedure or the groundwater used. The SLASS appears to exhibit generally favorable behavior for the retardation of uranium solubilized from waste in the site. Parametric tests were conducted to estimate the sensitivity of uranium sorption and solubility to the pH and carbonate content of the system.

  16. Geochemical Behaviour of S, Cl and Fe in Silicate Melts/Glasses Simulating

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Natural Magmas | Stanford Synchrotron Radiation Lightsource Geochemical Behaviour of S, Cl and Fe in Silicate Melts/Glasses Simulating Natural Magmas Monday, March 26, 2012 - 11:00am SSRL Conference Room 137-322 G. Giuli, R. Alonso-Mori, E. Paris, P. Glatzel, S. Eeckhout, M. Carroll, School of Science and Technology, Geology Division, University of Camerino, Via G. III da Varano, 62032 Camerino; e-mail: The solubility behaviour of S and Cl in silicate magmas is a key to understand the

  17. Geochemical Data Package for Performance Assessment Calculations Related to the Savannah River Site

    SciTech Connect (OSTI)

    Kaplan, Daniel I.

    2010-03-15

    The Savannah River Site disposes of low-activity radioactive waste within subsurface-engineered facilities. One of the tools used to establish the capacity of a given site to safely store radioactive waste (i.e., that a site does not exceed its Waste Acceptance Criteria) is the Performance Assessment (PA). The objective of this document is to provide the geochemical values for the PA calculations. This work is being conducted as part of the on-going maintenance program that permits the PA to periodically update existing calculations when new data becomes available.

  18. Remote Raman - laser induced breakdown spectroscopy (LIBS) geochemical investigation under Venus atmospheric conditions

    SciTech Connect (OSTI)

    Clegg, Sanuel M; Barefield, James E; Humphries, Seth D; Wiens, Roger C; Vaniman, D. T.; Sharma, S. K.; Misra, A. K.; Dyar, M. D.; Smrekar, S. E.

    2010-12-13

    The extreme Venus surface temperatures ({approx}740 K) and atmospheric pressures ({approx}93 atm) create a challenging environment for surface missions. Scientific investigations capable of Venus geochemical observations must be completed within hours of landing before the lander will be overcome by the harsh atmosphere. A combined remote Raman - LIBS (Laser Induced Breakdown Spectroscopy) instrument is capable of accomplishing the geochemical science goals without the risks associated with collecting samples and bringing them into the lander. Wiens et al. and Sharma et al. demonstrated that both analytical techniques can be integrated into a single instrument capable of planetary missions. The focus of this paper is to explore the capability to probe geologic samples with Raman - LIBS and demonstrate quantitative analysis under Venus surface conditions. Raman and LIBS are highly complementary analytical techniques capable of detecting both the mineralogical and geochemical composition of Venus surface materials. These techniques have the potential to profoundly increase our knowledge of the Venus surface composition, which is currently limited to geochemical data from Soviet Venera and VEGA landers that collectively suggest a surface composition that is primarily tholeiitic basaltic with some potentially more evolved compositions and, in some locations, K-rich trachyandesite. These landers were not equipped to probe the surface mineralogy as can be accomplished with Raman spectroscopy. Based on the observed compositional differences and recognizing the imprecise nature of the existing data, 15 samples were chosen to constitute a Venus-analog suite for this study, including five basalts, two each of andesites, dacites, and sulfates, and single samples of a foidite, trachyandesite, rhyolite, and basaltic trachyandesite under Venus conditions. LIBS data reduction involved generating a partial least squares (PLS) model with a subset of the rock powder standards to

  19. Blind Geothermal System Exploration in Active Volcanic Environments; Multi-phase Geophysical and Geochemical Surveys in Overt & Subtle Volcanic Systems, Hawaii & Maui

    Broader source: Energy.gov [DOE]

    DOE Geothermal Technologies Peer Review 2010 - Presentation. Project Objective: To use a combination of traditional geophysical and geochemical tools with exploration suites not typically used in geothermal exploration.

  20. Isotopic and geochemical tracers for U(VI) reduction and U mobility at an in situ recovery U mine

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Basu, Anirban; Brown, Shaun T.; Christensen, John N.; DePaolo, Donald J.; Reimus, Paul W.; Heikoop, Jeffrey M.; Woldegabriel, Giday; Simmons, Ardyth M.; House, Brian M.; Hartmann, Matt; et al

    2015-05-19

    In situ recovery (ISR) uranium (U) mining mobilizes U in its oxidized hexavalent form (U(VI)) by oxidative dissolution of U from the roll-front U deposits. Post-mining natural attenuation of residual U(VI) at ISR mines is a potential remediation strategy. Detection and monitoring of naturally occurring reducing subsurface environments are important for successful implementation of this remediation scheme. We used the isotopic tracers ²³⁸U/²³⁵U (δ²³⁸U), ²³⁴U/²³⁸U activity ratio, and ³⁴S/³²S (δ³⁴S), and geochemical measurements of U ore and groundwater collected from 32 wells located within, upgradient, and downgradient of a roll-front U deposit to detect U(VI) reduction and U mobility atmore » an ISR mining site at Rosita, TX, USA. The δ²³⁸U in Rosita groundwater varies from 0.61‰ to -2.49‰, with a trend toward lower δ²³⁸U in downgradient wells. The concurrent decrease in U(VI) concentration and δ²³⁸U with an ε of 0.48‰ ± 0.08‰ is indicative of naturally occurring reducing environments conducive to U(VI) reduction. Additionally, characteristic ²³⁴U/²³⁸U activity ratio and δ³⁴S values may also be used to trace the mobility of the ore zone groundwater after mining has ended. These results support the use of U isotope-based detection of natural attenuation of U(VI) at Rosita and other similar ISR mining sites.« less

  1. Geochemical Implications of CO2 Leakage Associated with Geologic Storage: A Review

    SciTech Connect (OSTI)

    Harvey, Omar R.; Qafoku, Nikolla; Cantrell, Kirk J.; Brown, Christopher F.

    2012-07-09

    Leakage from deep storage reservoirs is a major risk factor associated with geologic sequestration of carbon dioxide (CO2). Different scientific theories exist concerning the potential implications of such leakage for near-surface environments. The authors of this report reviewed the current literature on how CO2 leakage (from storage reservoirs) would likely impact the geochemistry of near surface environments such as potable water aquifers and the vadose zone. Experimental and modeling studies highlighted the potential for both beneficial (e.g., CO2 re sequestration or contaminant immobilization) and deleterious (e.g., contaminant mobilization) consequences of CO2 intrusion in these systems. Current knowledge gaps, including the role of CO2-induced changes in redox conditions, the influence of CO2 influx rate, gas composition, organic matter content and microorganisms are discussed in terms of their potential influence on pertinent geochemical processes and the potential for beneficial or deleterious outcomes. Geochemical modeling was used to systematically highlight why closing these knowledge gaps are pivotal. A framework for studying and assessing consequences associated with each factor is also presented in Section 5.6.

  2. Geochemical and geologic factors effecting the formulation of gas hydrate: Task No. 5, Final report

    SciTech Connect (OSTI)

    Kvenvolden, K.A.; Claypool, G.E.

    1988-01-01

    The main objective of our work has been to determine the primary geochemical and geological factors controlling gas hydrate information and occurrence and particularly in the factors responsible for the generation and accumulation of methane in oceanic gas hydrates. In order to understand the interrelation of geochemical/geological factors controlling gas hydrate occurrence, we have undertaken a multicomponent program which has included (1) comparison of available information at sites where gas hydrates have been observed through drilling by the Deep Sea Drilling Project (DSDP) on the Blake Outer Ridge and Middle America Trench; (2) regional synthesis of information related to gas hydrate occurrences of the Middle America Trench; (3) development of a model for the occurrence of a massive gas hydrate as DSDP Site 570; (4) a global synthesis of gas hydrate occurrences; and (5) development of a predictive model for gas hydrate occurrence in oceanic sediment. The first three components of this program were treated as part of a 1985 Department of Energy Peer Review. The present report considers the last two components and presents information on the worldwide occurrence of gas hydrates with particular emphasis on the Circum-Pacific and Arctic basins. A model is developed to account for the occurrence of oceanic gas hydrates in which the source of the methane is from microbial processes. 101 refs., 17 figs., 6 tabs.

  3. Elucidating geochemical response of shallow heterogeneous aquifers to CO2 leakage using high-performance computing: Implications for monitoring of CO2 sequestration

    SciTech Connect (OSTI)

    Navarre-Sitchler, Alexis K.; Maxwell, Reed M.; Siirila, Erica R.; Hammond, Glenn E.; Lichtner, Peter C.

    2013-03-01

    Predicting and quantifying impacts of potential carbon dioxide (CO2) leakage into shallow aquifers that overlie geologic CO2 storage formations is an important part of developing reliable carbon storage techniques. Leakage of CO2 through fractures, faults or faulty wellbores can reduce groundwater pH, inducing geochemical reactions that release solutes into the groundwater and pose a risk of degrading groundwater quality. In order to help quantify this risk, predictions of metal concentrations are needed during geologic storage of CO2. Here, we present regional-scale reactive transport simulations, at relatively fine-scale, of CO2 leakage into shallow aquifers run on the PFLOTRAN platform using high-performance computing. Multiple realizations of heterogeneous permeability distributions were generated using standard geostatistical methods. Increased statistical anisotropy of the permeability field resulted in more lateral and vertical spreading of the plume of impacted water, leading to increased Pb2+ (lead) concentrations and lower pH at a well down gradient of the CO2 leak. Pb2+ concentrations were higher in simulations where calcite was the source of Pb2+ compared to galena. The low solubility of galena effectively buffered the Pb2+ concentrations as galena reached saturation under reducing conditions along the flow path. In all cases, Pb2+ concentrations remained below the maximum contaminant level set by the EPA. Results from this study, compared to natural variability observed in aquifers, suggest that bicarbonate (HCO3) concentrations may be a better geochemical indicator of a CO2 leak under the conditions simulated here.

  4. Workshop on hydrologic and geochemical monitoring in the Long Valley Caldera: proceedings

    SciTech Connect (OSTI)

    Sorey, M.L.; Farrar, C.D.; Wollenberg, H.A.

    1984-10-01

    A workshop reviewed the results of hydrologic and geochemical monitoring in the Long Valley caldera. Such monitoring is being done to detect changes in the hydrothermal system induced by ongoing magmatic and tectonic processes. Workshop participants discussed the need to instrument sites for continuous measurements of several parameters and to obtain additional hydrologic and chemical information from intermediate and deep drill holes. In addition to seismic and deformation monitoring, programs are currently in progress to monitor changes in the discharge characteristics of hot springs, fumaroles, and soil gases, as well as pressures and temperatures in wells. Some hydrochemical parameters are measured continuously, others are measured monthly or at longer intervals. This report summarizes the information presented at the hydrologic monitoring workshop, following the workshop agenda which was divided into four sessions: (1) overview of the hydrothermal system; (2) monitoring springs, fumaroles, and wells; (3) monitoring gas emissions; and (4) conclusions and recommendations.

  5. Interface Induced Carbonate Mineralization: A Fundamental Geochemical Process Relevant to Carbon Sequestration

    SciTech Connect (OSTI)

    Teng, H. Henry; Xu, Huifang

    2013-07-17

    We have approached the long-standing geochemical question why anhydrous high-Mg carbonate minerals (i.e., magnesite and dolomite) cannot be formed at ambient conditions from a new perspective by exploring the formation of MgCO{sub 3} and Mg{sub x}Ca{sub (1-x)}CO{sub 3} in non-aqueous solutions. Data collected from our experiments in this funding period suggest that a fundamental barrier, other than cation hydration, exists that prevents Mg{sup 2+} and CO{sub 3}{sup 2-} ions from forming long-range ordered structures. We propose that this barrier mainly stems from the lattice limitation on the spatial configuration of CO{sub 3} groups in magnesite crystals. On the other hand, the measured higher distribution coefficients of Mg between magnesian calcites formed in the absence and presence of water give us a first direct proof to support and quantify the cation hydration effect.

  6. Geological, geochemical, and geophysical survey of the geothermal resources at Hot Springs Bay Valley, Akutan Island, Alaska

    SciTech Connect (OSTI)

    Motyka, R.J.; Wescott, E.M.; Turner, D.L.; Swanson, S.E.; Romick, J.D.; Moorman, M.A.; Poreda, R.J.; Witte, W.; Petzinger, B.; Allely, R.D.

    1985-01-01

    An extensive survey was conducted of the geothermal resource potential of Hot Springs Bay Valley on Akutan Island. A topographic base map was constructed, geologic mapping, geophysical and geochemical surveys were conducted, and the thermal waters and fumarolic gases were analyzed for major and minor element species and stable isotope composition. (ACR)

  7. Evaluating oil quality and monitoring production from heavy oil reservoirs using geochemical methods: Application to the Boscan Field, Venezuela

    SciTech Connect (OSTI)

    Kaufman, R.L.; Noguera, V.H.; Bantz, D.M.; Rodriguez, R.

    1996-08-01

    Many oil fields worldwide contain heavy oil in one or more reservoir units. The low gravity of these oils is most frequently due to biodegradation and/or low maturity. The challenge is to find ways to economically recover this oil. Methods which reduce the operating costs of producing heavy oil add significant value to such projects. Geochemical techniques which use the composition of the reservoir fluids as natural tracers offer cost effective methods to assist with reservoir management. The low viscosity and gravity of heavy oil, combined with frequent high water cuts, low flow rates, and the presence of downhole artificial lift equipment, make many conventional production logging methods difficult to apply. Therefore, monitoring production, especially if the produced oil is commingled from multiple reservoirs, can be difficult. Geochemical methods can be used to identify oil/water contacts, tubing string leaks and to allocate production to individual zones from commingled production. An example of a giant heavy oil field where geochemical methods may be applicable is the Boscan Field in Venezuela. Low maturity oil, averaging 10{degrees} API gravity, is produced from the Eocene Upper and Lower Boscan (Miosa) Sands. Geochemical, stratigraphic and engineering data have helped to better define the controls on oil quality within the field, identified new reservoir compartments and defined unique characteristics of the Upper and Lower Boscan oils. This information can be used to identify existing wells in need of workovers due to mechanical problems and to monitor production from new infill wells.

  8. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to Unconfined and Confined Aquifers

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Brown, Christopher F.; Wang, Guohui; Sullivan, E. C.; Lawter, Amanda R.; Harvey, Omar R.; Bowden, Mark

    2013-04-15

    Experimental research work has been conducted and is undergoing at Pacific Northwest National Laboratory (PNNL) to address a variety of scientific issues related with the potential leaks of the carbon dioxide (CO2) gas from deep storage reservoirs. The main objectives of this work are as follows: • Develop a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption and redox reactions) in the aquifer sediments. • Identify prevailing environmental conditions that would dictate one geochemical outcome over another. • Gather useful information to support site selection, risk assessment, policy-making, and public education efforts associated with geological carbon sequestration. In this report, we present results from experiments conducted at PNNL to address research issues related to the main objectives of this effort. A series of batch and column experiments and solid phase characterization studies (quantitative x-ray diffraction and wet chemical extractions with a concentrated acid) were conducted with representative rocks and sediments from an unconfined, oxidizing carbonate aquifer, i.e., Edwards aquifer in Texas, and a confined aquifer, i.e., the High Plains aquifer in Kansas. These materials were exposed to a CO2 gas stream simulating CO2 gas leaking scenarios, and changes in aqueous phase pH and chemical composition were measured in liquid and effluent samples collected at pre-determined experimental times. Additional research to be conducted during the current fiscal year will further validate these results and will address other important remaining issues. Results from these experimental efforts will provide valuable insights for the development of site-specific, generation III reduced order models. In addition, results will initially serve as input parameters during model calibration runs and, ultimately, will be used to test model predictive capability and

  9. Merging high resolution geophysical and geochemical surveys to reduce exploration risk at glass buttes, Oregon

    SciTech Connect (OSTI)

    Walsh, Patrick; Fercho, Steven; Perkin, Doug; Martini, Brigette; Boshmann, Darrick

    2015-06-01

    The engineering and studies phase of the Glass Buttes project was aimed at reducing risk during the early stages of geothermal project development. The project’s inclusion of high resolution geophysical and geochemical surveys allowed Ormat to evaluate the value of these surveys both independently and in combination to quantify the most valuable course of action for exploration in an area where structure, permeability, and temperature are the most pressing questions. The sizes of the thermal anomalies at Glass Buttes are unusually large. Over the course of Phase I Ormat acquired high resolution LIDAR data to accurately map fault manifestations at the surface and collected detailed gravity and aeromagnetic surveys to map subsurface structural features. In addition, Ormat collected airborne hyperspectral data to assist with mapping the rock petrology and mineral alteration assemblages along Glass Buttes faults and magnetotelluric (MT) survey to try to better constrain the structures at depth. Direct and indirect identification of alteration assemblages reveal not only the geochemical character and temperature of the causative hydrothermal fluids but can also constrain areas of upflow along specific fault segments. All five datasets were merged along with subsurface lithologies and temperatures to predict the most likely locations for high permeability and hot fluids. The Glass Buttes temperature anomalies include 2 areas, totaling 60 km2 (23 mi2) of measured temperature gradients over 165° C/km (10° F/100ft). The Midnight Point temperature anomaly includes the Strat-1 well with 90°C (194 °F) at 603 m (1981 ft) with a 164 °C/km (10°F/100ft) temperature gradient at bottom hole and the GB-18 well with 71°C (160 °F) at 396 m (1300 ft) with a 182°C/km (11°F/100ft) gradient. The primary area of alteration and elevated temperature occurs near major fault intersections associated with Brothers Fault Zone and Basin and Range systems. Evidence for faulting is

  10. Up-Scaling Geochemical Reaction Rates for Carbon Dioxide (CO2) in Deep Saline Aquifers

    SciTech Connect (OSTI)

    Peters, Catherine A

    2013-02-28

    Geochemical reactions in deep subsurface environments are complicated by the consolidated nature and mineralogical complexity of sedimentary rocks. Understanding the kinetics of these reactions is critical to our ability to make long-term predictions about subsurface processes such as pH buffering, alteration in rock structure, permeability changes, and formation of secondary precipitates. In this project, we used a combination of experiments and numerical simulation to bridge the gap between our knowledge of these reactions at the lab scale and rates that are meaningful for modeling reactive transport at core scales. The focus is on acid-driven mineral dissolution, which is specifically relevant in the context of CO2-water-rock interactions in geological sequestration of carbon dioxide. The project led to major findings in three areas. First, we modeled reactive transport in pore-network systems to investigate scaling effects in geochemical reaction rates. We found significant scaling effects when CO2 concentrations are high and reaction rates are fast. These findings indicate that the increased acidity associated with geological sequestration can generate conditions for which proper scaling tools are yet to be developed. Second, we used mathematical modeling to investigate the extent to which SO2, if co-injected with CO2, would acidify formation brines. We found that there exist realistic conditions in which the impact on brine acidity will be limited due to diffusion rate-limited SO2 dissolution from the CO2 phase, and the subsequent pH shift may also be limited by the lack of availability of oxidants to produce sulfuric acid. Third, for three Viking sandstones (Alberta sedimentary basin, Canada), we employed backscattered electron microscopy and energy dispersive X-ray spectroscopy to statistically characterize mineral contact with pore space. We determined that for reactive minerals in sedimentary consolidated rocks, abundance alone is not a good predictor of

  11. Novel Imaging Techniques, Integrated with Mineralogical, Geochemical and Microbiological Characterization to Determine the Biogeochemical Controls....

    SciTech Connect (OSTI)

    Lloyd, Jonathan R.

    2005-06-01

    conditions on the stability/solubility of Fe(II) and Tc(IV), found 80 % resolubilization of the Tc. Column experiments exploring this behavior are being planned. HYPOTHESIS 4 The mobility of 99mTc in the sediment columns can be modeled using a coupled speciation and transport code. Microbiological and geochemical characterization of the column experiments is ongoing and transport and geochemical modeling experiments are being planned.

  12. Isotopic and geochemical tracers for U(VI) reduction and U mobility at an in situ recovery U mine

    SciTech Connect (OSTI)

    Basu, Anirban; Brown, Shaun T.; Christensen, John N.; DePaolo, Donald J.; Reimus, Paul W.; Heikoop, Jeffrey M.; Woldegabriel, Giday; Simmons, Ardyth M.; House, Brian M.; Hartmann, Matt; Maher, Kate

    2015-05-19

    In situ recovery (ISR) uranium (U) mining mobilizes U in its oxidized hexavalent form (U(VI)) by oxidative dissolution of U from the roll-front U deposits. Post-mining natural attenuation of residual U(VI) at ISR mines is a potential remediation strategy. Detection and monitoring of naturally occurring reducing subsurface environments are important for successful implementation of this remediation scheme. We used the isotopic tracers ?U/?U (??U), ?U/?U activity ratio, and ?S/S (??S), and geochemical measurements of U ore and groundwater collected from 32 wells located within, upgradient, and downgradient of a roll-front U deposit to detect U(VI) reduction and U mobility at an ISR mining site at Rosita, TX, USA. The ??U in Rosita groundwater varies from 0.61 to -2.49, with a trend toward lower ??U in downgradient wells. The concurrent decrease in U(VI) concentration and ??U with an ? of 0.48 0.08 is indicative of naturally occurring reducing environments conducive to U(VI) reduction. Additionally, characteristic ?U/?U activity ratio and ??S values may also be used to trace the mobility of the ore zone groundwater after mining has ended. These results support the use of U isotope-based detection of natural attenuation of U(VI) at Rosita and other similar ISR mining sites.

  13. Improved Geothermometry Through Multivariate Reaction-path Modeling and Evaluation of Geomicrobiological Influences on Geochemical Temperature Indicators: Final Report

    SciTech Connect (OSTI)

    Mattson, Earl; Smith, Robert; Fujita, Yoshiko; McLing, Travis; Neupane, Ghanashyam; Palmer, Carl; Reed, David; Thompson, Vicki

    2015-03-01

    The project was aimed at demonstrating that the geothermometric predictions can be improved through the application of multi-element reaction path modeling that accounts for lithologic and tectonic settings, while also accounting for biological influences on geochemical temperature indicators. The limited utilization of chemical signatures by individual traditional geothermometer in the development of reservoir temperature estimates may have been constraining their reliability for evaluation of potential geothermal resources. This project, however, was intended to build a geothermometry tool which can integrate multi-component reaction path modeling with process-optimization capability that can be applied to dilute, low-temperature water samples to consistently predict reservoir temperature within ±30 °C. The project was also intended to evaluate the extent to which microbiological processes can modulate the geochemical signals in some thermal waters and influence the geothermometric predictions.

  14. GaMin’11 – an international inter-laboratory comparison for geochemical CO₂ - saline fluid - mineral interaction experiments

    SciTech Connect (OSTI)

    Ostertag-Henning, C.; Risse, A.; Thomas, B.; Rosenbauer, R.; Rochelle, C.; Purser, G.; Kilpatrick, A.; Rosenqvist, J.; Yardley, B.; Karamalidis, A.; Griffith, C.; Hedges, S.; Dilmore, R.; Goodman, A.; Black, J.; Haese, R.; Deusner, C.; Bigalke, N.; Haeckel, M.; Fischer, S.; Liebscher, A.; Icenhower, J. P.; Daval, D.; Saldi, G. D.; Knauss, K. G.; Schmidt, M.; Mito, S.; Sorai, M.; Truche, L.

    2014-12-31

    Due to the strong interest in geochemical CO₂-fluid-rock interaction in the context of geological storage of CO₂ a growing number of research groups have used a variety of different experimental ways to identify important geochemical dissolution or precipitation reactions and – if possible – quantify the rates and extent of mineral or rock alteration. In this inter-laboratory comparison the gas-fluid-mineral reactions of three samples of rock-forming minerals have been investigated by 11 experimental labs. The reported results point to robust identification of the major processes in the experiments by most groups. The dissolution rates derived from the changes in composition of the aqueous phase are consistent overall, but the variation could be reduced by using similar corrections for changing parameters in the reaction cells over time. The comparison of experimental setups and procedures as well as of data corrections identified potential improvements for future gas-fluid-rock studies.

  15. Preburn versus postburn mineralogical and geochemical characteristics of overburden and coal at the Hanna, Wyoming underground coal gasification site

    SciTech Connect (OSTI)

    Oliver, R.L.; Youngberg, A.D.

    1983-12-01

    Hundreds of mineralogic and geochemical tests were done under US Department of Energy contracts on core samples taken from the Hanna underground coal gasification site. These tests included x-ray diffraction studies of minerals in coal ash, overburden rocks, and heat-altered rocks; x-ray fluorescence analyses of oxides in coal ash and heat-altered rocks; semi-quantitative spectrographic analyses of elements in coal, overburden, and heat-altered rocks; chemical analyses of elements and compounds in coal, overburden, and heat-altered rocks and ASTM proximate and ultimate analyses of coal and heat-altered coal. These data sets were grouped, averaged, and analyzed to provide preburn and postburn mineralogic and geochemical characteristics of rock units at the site. Where possible, the changes in characteristics from the preburn to the postburn state are related to underground coal gasification processes. 11 references, 13 figures, 8 tables.

  16. Comparison of microbial and sorbed soil gas surgace geochemical techniques with seismic surveys from the Southern Altiplano, Bolivia

    SciTech Connect (OSTI)

    Aranibar, O.R.; Tucker, J.D.; Hiltzman, D.C.

    1995-12-31

    Yacimientos Petroliferos Fiscales Bolivianos (YPFB) undertook a large seismic evaluation in the southern Altiplano, Bolivia in 1994. As an additional layer of information, sorbed soil gas and Microbial Oil Survey Technique (MOST) geochemical surveys were conducted to evaluate the hydrocarbon microseepage potential. The Wara Sara Prospect had 387 sorbed soil gas samples, collected from one meter depth, and 539 shallow soil microbial samples, collected from 15 to 20 centimeter depth. The sorbed soil gas samples were collected every 500 meters and microbial samples every 250 meters along geochemical traverses spaced 1 km apart. The presence of anmalous hydrocarbon microseepage is indicated by (1) a single hydrocarbon source identified by gas crossplots, (2) the high gas values with a broad range, (3) the high overall gas average, (4) the clusters of elevated samples, and (5) the right hand skewed data distributions.

  17. Unearthing the Antibacterial Mechanism of Medicinal Clay: A Geochemical Approach to Combating Antibiotic Resistance

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Morrison, Keith D.; Misra, Rajeev; Williams, Lynda B.

    2016-01-08

    Natural antibacterial clays, when hydrated and applied topically, kill human pathogens including antibiotic resistant strains proliferating worldwide. Only certain clays are bactericidal; those containing soluble reduced metals and expandable clay minerals that absorb cations, providing a capacity for extended metal release and production of toxic hydroxyl radicals. Here we show the critical antibacterial components are soluble Fe2+ and Al3+ that synergistically attack multiple cellular systems in pathogens normally growth-limited by Fe supply. This geochemical process is more effective than metal solutions alone and provides an alternative antibacterial strategy to traditional antibiotics. Advanced bioimaging methods and genetic show that Al3+ misfoldsmore » cell membrane proteins, while Fe2+ evokes membrane oxidation and enters the cytoplasm inflicting hydroxyl radical attack on intracellular proteins and DNA. The lethal reaction precipitates Fe3+-oxides as biomolecular damage proceeds. In conclusion, discovery of this bactericidal mechanism demonstrated by natural clays should guide designs of new mineral-based antibacterial agents.« less

  18. Geochemical characteristics of oils from New Zealand, Papua New Guinea and Taiwan

    SciTech Connect (OSTI)

    Jung-Nan, Oung; Philp, P.R. )

    1990-05-01

    Oils from a number of convergent margin settings of the Pacific and Philippine plates have been characterized by geochemical techniques including gas chromatography-mass spectrometry and carbon isotopic analysis. The oils, collected from New Zealand, New Guinea, and Taiwan, are described in terms of their biomarker compositions, and these distributions are used to evaluate the nature of the source material responsible for the oils. For the most part these oils are of Tertiary age and the source materials were derived predominantly from higher plants. The authors describe the effects of a convergent margin on the relative maturity of the oils as reflected by their biomarker distributions. In other words, do any of the oils from these regions have anomalous maturity values that can be attributed to additional heating resulting from plate movement in the area. The results will also be compared with oils from similar source materials but not in convergent margin settings (for example, the Gippsland basin, Australia) to further evaluate the effects of the convergent margin setting on the biomarker distributions.

  19. Geochemical and physical properties of soils and shallow sediments at the Savannah River Site

    SciTech Connect (OSTI)

    Looney, B.B.; Eddy, C.A.; Ramdeen, M.; Pickett, J. ); Rogers, V. . Savannah River Site Savannah River Lab., Aiken, SC ); Scott, M.T.; Shirley, P.A. )

    1990-08-31

    A program to characterize the geochemical and physical properties of the unimpacted soils and shallow sediments at the Savannah River Site (SRS) has been completed. The maximum, minimum, median, standard deviation, and mean values for metals, radionuclides, inorganic anions, organic compounds, and agricultural indicator parameters are summarized for six soil series that were identified as representative of the 29 soil series at SRS. The soils from unimpacted areas of SRS are typical of soils found in moderately aggressive weathering environments, including the southeastern United States. Appendix 8 organic compounds were detected in all samples. Since these constituents are not generally present in soil, this portion of the investigation was intended to assess possible laboratory artifacts. An additional objective of the SRS Soil Study was to determine if the composition of the split spoon sampler biased chemical analysis of the soils. Twenty-five duplicate samples were analyzed for a number of metals, radiological and agricultural parameters, and organics by two laboratories currently contracted with to analyze samples during waste site characterization. In all cases, the absolute values of the average differences are relatively small compared to the overall variability in the population. 31 refs., 14 figs., 48 tabs.

  20. Microbial distributions detected by an oligonucleotide microarray across geochemical zones associated with methane in marine sediments from the Ulleung Basin

    SciTech Connect (OSTI)

    Briggs, Brandon R.; Graw, Michael; Brodie, Eoin L.; Bahk, Jang-Jun; Kim, Sung-Han; Hyun, Jung-Ho; Kim, Ji-Hoon; Torres, Marta; Colwell, Frederick S.

    2013-11-01

    The biogeochemical processes that occur in marine sediments on continental margins are complex; however, from one perspective they can be considered with respect to three geochemical zones based on the presence and form of methane: sulfatemethane transition (SMTZ), gas hydrate stability zone (GHSZ), and free gas zone (FGZ). These geochemical zones may harbor distinct microbial communities that are important in biogeochemical carbon cycles. The objective of this study was to describe the microbial communities in sediments from the SMTZ, GHSZ, and FGZ using molecular ecology methods (i.e. PhyloChip microarray analysis and terminal restriction fragment length polymorphism (T-RFLP)) and examining the results in the context of non-biological parameters in the sediments. Non-metric multidimensional scaling and multi-response permutation procedures were used to determine whether microbial community compositions were significantly different in the three geochemical zones and to correlate samples with abiotic characteristics of the sediments. This analysis indicated that microbial communities from all three zones were distinct from one another and that variables such as sulfate concentration, hydrate saturation of the nearest gas hydrate layer, and depth (or unmeasured variables associated with depth e.g. temperature, pressure) were correlated to differences between the three zones. The archaeal anaerobic methanotrophs typically attributed to performing anaerobic oxidation of methane were not detected in the SMTZ; however, the marine benthic group-B, which is often found in SMTZ, was detected. Within the GHSZ, samples that were typically closer to layers that contained higher hydrate saturation had indicator sequences related to Vibrio-type taxa. These results suggest that the biogeographic patterns of microbial communities in marine sediments are distinct based on geochemical zones defined by methane.

  1. Geologic, geophysical, and geochemical aspects of site-specific studies of the geopressured-geothermal energy resource of southern Louisiana. Final report

    SciTech Connect (OSTI)

    Pilger, R.H. Jr.

    1985-01-01

    The report consists of four sections dealing with progress in evaluating geologic, geochemical, and geophysical aspects of geopressured-geothermal energy resources in Louisiana. Separate abstracts have been prepared for the individual sections. (ACR)

  2. Geochemical engineering design tools for uranium in situ recovery : the HYDROGEOCHEM codes.

    SciTech Connect (OSTI)

    Siegel, Malcolm Dean; Li, Ming-Hsu; Yeh, Gour-Tsyh

    2010-11-01

    Geochemical Engineering Design (GED) is based on applications of the principles and various computer models that describe the biogeochemistry and physics of removal of contaminants from water by adsorption, precipitation and filtration. It can be used to optimize or evaluate the efficiency of all phases of in situ recovery (ISR). The primary tools of GED are reactive transport models; this talk describes the potential application of the HYDROGEOCHEM family of codes to ISR. The codes can describe a complete suite of equilibrium or kinetic aqueous complexation, adsorption-desorption, precipitation-dissolution, redox, and acid-base reactions in variably saturated media with density-dependent fluid flow. Applications to ISR are illustrated with simulations of (1) the effectiveness of a reactive barrier to prevent off-site uranium migration and (2) evaluation of the effect of sorption hysteresis on natural attenuation. In the first example, it can be seen that the apparent effectiveness of the barrier depends on monitoring location and that it changes over time. This is due to changes in pH, saturation of sorption sites, as well as the geometry of the flow field. The second simulation shows how sorption hysteresis leads to observable attenuation of a uranium contamination plume. Different sorption mechanisms including fast (or reversible), slow, and irreversible sorption were simulated. The migration of the dissolved and total uranium plumes for the different cases are compared and the simulations show that when 50-100% of the sites have slow desorption rates, the center of mass of the dissolved uranium plume begins to move upstream. This would correspond to the case in which the plume boundaries begin to shrink as required for demonstration of natural attenuation.

  3. Characterizing Microbial Community and Geochemical Dynamics at Hydrothermal Vents Using Osmotically Driven Continuous Fluid Samplers

    SciTech Connect (OSTI)

    Robidart, Julie C.; Callister, Stephen J.; Song, Peng F.; Nicora, Carrie D.; Wheat, Charles G.; Girguis, Peter R.

    2013-05-07

    microbial and geochemical phenomena.

  4. Scaling Effects of Cr(VI) Reduction Kinetics. The Role of Geochemical Heterogeneity

    SciTech Connect (OSTI)

    Wang, Li; Li, Li

    2015-10-22

    The natural subsurface is highly heterogeneous with minerals distributed in different spatial patterns. Fundamental understanding of how mineral spatial distribution patterns regulate sorption process is important for predicting the transport and fate of chemicals. Existing studies about the sorption was carried out in well-mixed batch reactors or uniformly packed columns, with few data available on the effects of spatial heterogeneities. As a result, there is a lack of data and understanding on how spatial heterogeneities control sorption processes. In this project, we aim to understand and develop modeling capabilities to predict the sorption of Cr(VI), an omnipresent contaminant in natural systems due to its natural occurrence and industrial utilization. We systematically examine the role of spatial patterns of illite, a common clay, in determining the extent of transport limitation and scaling effects associated with Cr(VI) sorption capacity and kinetics using column experiments and reactive transport modeling. Our results showed that the sorbed mass and rates can differ by an order of magnitude due to of the illite spatial heterogeneities and transport limitation. With constraints from data, we also developed the capabilities of modeling Cr(VI) in heterogeneous media. The developed model is then utilized to understand the general principles that govern the relationship between sorption and connectivity, a key measure of the spatial pattern characteristics. This correlation can be used to estimate Cr(VI) sorption characteristics in heterogeneous porous media. Insights gained here bridge gaps between laboratory and field application in hydrogeology and geochemical field, and advance predictive understanding of reactive transport processes in the natural heterogeneous subsurface. We believe that these findings will be of interest to a large number of environmental geochemists and engineers, hydrogeologists, and those interested in contaminant fate and transport

  5. Geochemical Evidence of the Seasonality, Affinity and Pigmenation of Solenopora jurassica

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Barden, Holly E.; Behnsen, Julia; Bergmann, Uwe; Leng, Melanie J.; Manning, Phillip L.; Withers, Philip J.; Wogelius, Roy A.; van Dongen, Bart E.; Silva, Lucas C. R.

    2015-09-14

    Solenopora jurassica is a fossil calcareous alga that functioned as an important reef-building organism during the Palaeozoic. It is of significant palaeobiological interest due to its distinctive but poorly understood pink and white banding. Though widely accepted as an alga there is still debate over its taxonomic affinity, with recent work arguing that it should be reclassified as a chaetetid sponge. The banding is thought to be seasonal, but there is no conclusive evidence for this. Other recent work has, however demonstrated the presence of a unique organic boron-containing pink/red pigment in the pink bands of S. jurassica. We presentmore » new geochemical evidence concerning the seasonality and pigmentation of S. jurassica. Seasonal growth cycles are demonstrated by X-ray radiography, which shows differences in calcite density, and by varying δ13C composition of the bands. Temperature variation in the bands is difficult to constrain accurately due to conflicting patterns arising from Mg/Ca molar ratios and δ18O data. Fluctuating chlorine levels indicate increased salinity in the white bands, when combined with the isotope data this suggests more suggestive of marine conditions during formation of the white band and a greater freshwater component (lower chlorinity) during pink band precipitation (δ18O). Increased photosynthesis is inferred within the pink bands in comparison to the white, based on δ13C. Pyrolysis Gas Chromatography Mass Spectrometry (Py-GCMS) and Fourier Transform Infrared Spectroscopy (FTIR) show the presence of tetramethyl pyrrole, protein moieties and carboxylic acid groups, suggestive of the presence of the red algal pigment phycoerythrin. This is consistent with the pink colour of S. jurassica. As phycoerythrin is only known to occur in algae and cyanobacteria, and no biomarker evidence of bacteria or sponges was detected we conclude S. jurassica is most likely an alga. Pigment analysis may be a reliable classification method for

  6. Geochemical Evidence of the Seasonality, Affinity and Pigmenation of Solenopora jurassica

    SciTech Connect (OSTI)

    Barden, Holly E.; Behnsen, Julia; Bergmann, Uwe; Leng, Melanie J.; Manning, Phillip L.; Withers, Philip J.; Wogelius, Roy A.; van Dongen, Bart E.; Silva, Lucas C. R.

    2015-09-14

    Solenopora jurassica is a fossil calcareous alga that functioned as an important reef-building organism during the Palaeozoic. It is of significant palaeobiological interest due to its distinctive but poorly understood pink and white banding. Though widely accepted as an alga there is still debate over its taxonomic affinity, with recent work arguing that it should be reclassified as a chaetetid sponge. The banding is thought to be seasonal, but there is no conclusive evidence for this. Other recent work has, however demonstrated the presence of a unique organic boron-containing pink/red pigment in the pink bands of S. jurassica. We present new geochemical evidence concerning the seasonality and pigmentation of S. jurassica. Seasonal growth cycles are demonstrated by X-ray radiography, which shows differences in calcite density, and by varying δ13C composition of the bands. Temperature variation in the bands is difficult to constrain accurately due to conflicting patterns arising from Mg/Ca molar ratios and δ18O data. Fluctuating chlorine levels indicate increased salinity in the white bands, when combined with the isotope data this suggests more suggestive of marine conditions during formation of the white band and a greater freshwater component (lower chlorinity) during pink band precipitation (δ18O). Increased photosynthesis is inferred within the pink bands in comparison to the white, based on δ13C. Pyrolysis Gas Chromatography Mass Spectrometry (Py-GCMS) and Fourier Transform Infrared Spectroscopy (FTIR) show the presence of tetramethyl pyrrole, protein moieties and carboxylic acid groups, suggestive of the presence of the red algal pigment phycoerythrin. This is consistent with the pink colour of S. jurassica. As phycoerythrin is only known to occur in algae and cyanobacteria, and no biomarker evidence of bacteria or sponges was detected we conclude S. jurassica is most likely an alga. Pigment analysis may be a

  7. Sampling designs for geochemical baseline studies in the Colorado oil shale region: a manual for practical application

    SciTech Connect (OSTI)

    Klusman, R. W.; Ringrose, C. D.; Candito, R. J.; Zuccaro, B.; Rutherford, D. W.; Dean, W. E.

    1980-06-01

    This manual presents a rationale for sampling designs, and results of geochemical baseline studies in the Colorado portion of the oil-shale region. The program consists of a systematic trace element study of soils, stream sediments, and plants carried out in a way to be conservative of human and financial resources and yield maximum information. Extension of this approach to other parameters, other locations, and to environmental baseline studies in general is a primary objective. A baseline for any geochemical parameter can be defined as the concentration of that parameter in a given medium such as soil, the range of its concentration, and the geographic scale of variability. In air quality studies, and to a lesser extent for plants, the temporal scale of variability must also be considered. In studies of soil, the temporal variablility does not become a factor until such time that a study is deemed necessary to evaluate whether or not there have been changes in baseline levels as a result of development. The manual is divided into five major parts. The first is a suggested sampling protocol which is presented in an outline form for guiding baseline studies in this area. The second section is background information on the physical features of the area of study, trace elements of significance occurring in oil shale, and the sample media used in these studies. The third section is concerned primarily with sampling design and its application to the geochemical studies of the oil shale region. The last sections, in the form of appendices, provide actual data and illustrate in a systematic manner, the calculations performed to obtain the various summary data. The last segment of the appendices is a more academic discussion of the geochemistry of trace elements and the parameters of importance influencing their behavior in natural systems.

  8. Structural Analysis for Gold Mineralization Using Remote Sensing and Geochemical Techniques in a GIS Environment: Island of Lesvos, Hellas

    SciTech Connect (OSTI)

    Rokos, D. Argialas, D. Mavrantza, R. St Seymour, K.; Vamvoukakis, C.; Kouli, M.; Lamera, S.; Paraskevas, H.; Karfakis, I.; Denes, G

    2000-12-15

    Exploration for epithermal Au has been active lately in the Aegean Sea of the eastern Mediterranean Basin, both in the islands of the Quaternary arc and in those of the back-arc region. The purpose of this study was the structural mapping and analysis for a preliminary investigation of possible epithermal gold mineralization, using remotely sensed data and techniques, structural and field data, and geochemical information, for a specific area on the Island of Lesvos. Therefore, Landsat-TM and SPOT-Pan satellite images and the Digital Elevation Model (DEM) of the study area were processed digitally using spatial filtering techniques for the enhancement and recognition of the geologically significant lineaments, as well as algebraic operations with band ratios and Principal Component Analysis (PCA), for the identification of alteration zones. Statistical rose diagrams and a SCHMIDT projection Stereo Net were generated from the lineament maps and the collected field data (dip and strike measurements of faults, joints, and veins), respectively. The derived lineament map and the band ratio images were manipulated in a GIS environment, in order to study the relation of the tectonic pattern to both the alteration zoning and the geomorphology of the volcanic field of the study area. Target areas of high interest for possible mineralization also were specified using geochemical techniques, such as X-Ray Diffraction (XRD) analysis, trace-element, and fluid-inclusion analysis. Finally, preliminary conclusions were derived about possible mineralization, the type (high or low sulfidation), and the extent of mineralization, by combining the structural information with geochemical information.

  9. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation “C”. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthitemore » component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation “C” sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.« less

  10. GEOCHEMICAL INVESTIGATIONS OF CO₂-BRINE-ROCK INTERACTIONS OF THE KNOX GROUP IN THE ILLINOIS BASIN

    SciTech Connect (OSTI)

    Yoksoulian, Lois; Berger, Peter; Freiburg, Jared; Butler, Shane; Leetaru, Hannes

    2014-09-30

    Increased output of greenhouse gases, particularly carbon dioxide (CO₂), into the atmosphere from anthropogenic sources is of great concern. A potential technology to reduce CO₂ emissions is geologic carbon sequestration. This technology is currently being evaluated in the United States and throughout the world. The geology of the Illinois Basin exhibits outstanding potential as a carbon sequestration target, as demonstrated by the ongoing Illinois Basin – Decatur Project that is using the Mt. Simon Sandstone reservoir and Eau Claire Shale seal system to store and contain 1 million tonnes of CO₂. The Knox Group-Maquoketa Shale reservoir and seal system, located stratigraphically above the Mt. Simon Sandstone-Eau Claire Shale reservoir and seal system, has little economic value as a resource for fossil fuels or as a potable water source, making it ideal as a potential carbon sequestration target. In order for a reservoir-seal system to be effective, it must be able to contain the injected CO₂ without the potential for the release of harmful contaminants liberated by the reaction between CO₂-formation fluids and reservoir and seal rocks. This study examines portions of the Knox Group (Potosi Dolomite, Gunter Sandstone, New Richmond Sandstone) and St. Peter Sandstone, and Maquoketa Shale from various locations around the Illinois Basin. A total of 14 rock and fluid samples were exposed to simulated sequestration conditions (9101–9860 kPa [1320–1430 psi] and 32°–42°C [90°– 108°F]) for varying amounts of time (6 hours to 4 months). Knox Group reservoir rocks exhibited dissolution of dolomite in the presence of CO₂ as indicated by petrographic examination, X-ray diffraction analysis, and fluid chemistry analysis. These reactions equilibrated rapidly, and geochemical modeling confirmed that these reactions reached equilibrium within the time frames of the experiments. Pre-reaction sample mineralogy and postreaction fluid geochemistry from this

  11. Effect of curing conditions on the geotechnical and geochemical properties of CFBC ashes

    SciTech Connect (OSTI)

    Bland, A.E.

    1999-07-01

    Western Research Institute, in cooperation with the US Department of Energy Federal Energy Technology Center, initiated a multi-year program to examine the relationship between CFBC ash chemistry and geotechnical properties as they relate to ash disposal and utilization. Four CFBC facilities supplied ash from their units for the study representing high-sulfur (4%) and medium-sulfur (1.8%) bituminous coal. Sub-bituminous coal (0.9% sulfur) and petroleum coke (5--6% sulfur) fired ashes were also included in the study. The ashes were composed principally of large quantities of anhydrite (CaSO{sub 4}) and lime (CaO) and minor amounts of calcite (CaCO{sub 3}). The ash curing study addressed the impact of curing conditions (sealed and saturated curing and 23 C and 5 C curing temperature) on the geochemical and geotechnical properties of the ash. The strength development and expansion varied with the type and characteristics of the ashes. The expansion appeared to be inversely related to strength development. As the strength decreased under saturated curing, the expansion increased significantly. The application of 5 C saturated curing resulted in further strength loss and increased expansion. The hydration reaction products appeared to be principally the hydration of lime (CaO) to portlandite (Ca[OH]{sub 2}), the hydration of anhydrite (CaSO{sub 4}) to gypsum (CaSO{sub 4} {center{underscore}dot} 2H{sub 2}O), and the precipitation of ettringite (Ca{sub 6}Al{sub 2}[SO{sub 4}]{sub 3}[OH]{sub 12} {center{underscore}dot} 26H{sub 2}O) from the soluble calcium, sulfates and alumina. No thaumasite was noted in the specimens. The ashes appeared to follow one of several hydration reaction trends: (1) ettringite-only development, (2) ettringite and/or gypsum early followed by later gypsum formation, or (3) gypsum-only formation. Testing confirmed that the hydration reaction chemistry was related to geotechnical properties of the ashes. Strength development and expansion appeared to

  12. Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to an Unconfined Oxidizing Carbonate Aquifer

    SciTech Connect (OSTI)

    Wang, Guohui; Qafoku, Nikolla; Lawter, Amanda R.; Bowden, Mark E.; Harvey, Omar; Sullivan, E. C.; Brown, Christopher F.

    2015-07-15

    leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption) in the aquifer sediments and will support site selection, risk assessment, policy-making, and public education efforts associated with geologic carbon sequestration.

  13. Final Report: Molecular Basis for Microbial Adhesion and Geochemical Surface Reactions: A Study Across Scales

    SciTech Connect (OSTI)

    Dixon, David Adams

    2013-06-27

    Computational chemistry was used to help provide a molecular level description of the interactions of Gram-negative microbial membranes with subsurface materials. The goal is to develop a better understanding of the molecular processes involved in microbial metal binding, microbial attachment to mineral surfaces, and, eventually, oxidation/reduction reactions (electron transfer) that can occur at these surfaces and are mediated by the bacterial exterior surface. The project focused on the interaction of the outer microbial membrane, which is dominated by an exterior lipopolysaccharide (LPS) portion, of Pseudomonas aeruginosa with the mineral goethite and with solvated ions in the environment. This was originally a collaborative project with T.P. Straatsma and B. Lowery of the Pacific Northwest National Laboratory. The University of Alabama effort used electronic structure calculations to predict the molecular behavior of ions in solution and the behavior of the sugars which form a critical part of the LPS. The interactions of the sugars with metal ions are expected to dominate much of the microscopic structure and transport phenomena in the LPS. This work, in combination with the molecular dynamics simulations of Straatsma and the experimental electrochemistry and microscopy measurements of Lowry, both at PNNL, is providing new insights into the detailed molecular behavior of these membranes in geochemical environments. The effort at The University of Alabama has three components: solvation energies and structures of ions in solution, prediction of the acidity of the critical groups in the sugars in the LPS, and binding of metal ions to the sugar anions. An important aspect of the structure of the LPS membrane as well as ion transport in the LPS is the ability of the sugar side groups such as the carboxylic acids and the phosphates to bind positively charged ions. We are studying the acidity of the acidic side groups in order to better understand the ability of

  14. Permeability, geochemical, and water quality tests in support of an aquifer thermal energy storage site in Minnesota

    SciTech Connect (OSTI)

    Blair, S.C.; Deutsch, W.J.; Mitchell, P.J.

    1985-04-01

    This report describes the Underground Energy Storage Program's efforts to characterize physicochemical processes at DOE's ATES Field Test Facility (FTF) located on the University of Minnesota campus at St. Paul, Minnesota. Experimental efforts include: field tests at the St. Paul FTF to characterize fluid injectability and to evaluate the effectiveness of fluid-conditioning equipment, geochemical studies to investigate chemical reactions resulting from alterations to the aquifer's thermal regime, and laboratory tests on sandstone core from the site. Each experimental area is discussed and results obtained thus far are reported. 23 refs., 39 figs., 12 tabs.

  15. Isotopic and geochemical tracers for U(VI) reduction and U mobility at an in situ recovery U mine

    SciTech Connect (OSTI)

    Basu, Anirban; Brown, Shaun T.; Christensen, John N.; DePaolo, Donald J.; Reimus, Paul W.; Heikoop, Jeffrey M.; Woldegabriel, Giday; Simmons, Ardyth M.; House, Brian M.; Hartmann, Matt; Maher, Kate

    2015-05-19

    In situ recovery (ISR) uranium (U) mining mobilizes U in its oxidized hexavalent form (U(VI)) by oxidative dissolution of U from the roll-front U deposits. Post-mining natural attenuation of residual U(VI) at ISR mines is a potential remediation strategy. Detection and monitoring of naturally occurring reducing subsurface environments are important for successful implementation of this remediation scheme. We used the isotopic tracers ²³⁸U/²³⁵U (δ²³⁸U), ²³⁴U/²³⁸U activity ratio, and ³⁴S/³²S (δ³⁴S), and geochemical measurements of U ore and groundwater collected from 32 wells located within, upgradient, and downgradient of a roll-front U deposit to detect U(VI) reduction and U mobility at an ISR mining site at Rosita, TX, USA. The δ²³⁸U in Rosita groundwater varies from 0.61‰ to -2.49‰, with a trend toward lower δ²³⁸U in downgradient wells. The concurrent decrease in U(VI) concentration and δ²³⁸U with an ε of 0.48‰ ± 0.08‰ is indicative of naturally occurring reducing environments conducive to U(VI) reduction. Additionally, characteristic ²³⁴U/²³⁸U activity ratio and δ³⁴S values may also be used to trace the mobility of the ore zone groundwater after mining has ended. These results support the use of U isotope-based detection of natural attenuation of U(VI) at Rosita and other similar ISR mining sites.

  16. Geologic, geochemical, and geographic controls on NORM in produced water from Texas oil, gas, and geothermal reservoirs. Final report

    SciTech Connect (OSTI)

    Fisher, R.

    1995-08-01

    Water from Texas oil, gas, and geothermal wells contains natural radioactivity that ranges from several hundred to several thousand Picocuries per liter (pCi/L). This natural radioactivity in produced fluids and the scale that forms in producing and processing equipment can lead to increased concerns for worker safety and additional costs for handling and disposing of water and scale. Naturally occurring radioactive materials (NORM) in oil and gas operations are mainly caused by concentrations of radium-226 ({sup 226}Ra) and radium-228 ({sup 228}Ra), daughter products of uranium-238 ({sup 238}U) and thorium-232 ({sup 232}Th), respectively, in barite scale. We examined (1) the geographic distribution of high NORM levels in oil-producing and gas-processing equipment, (2) geologic controls on uranium (U), thorium (Th), and radium (Ra) in sedimentary basins and reservoirs, (3) mineralogy of NORM scale, (4) chemical variability and potential to form barite scale in Texas formation waters, (5) Ra activity in Texas formation waters, and (6) geochemical controls on Ra isotopes in formation water and barite scale to explore natural controls on radioactivity. Our approach combined extensive compilations of published data, collection and analyses of new water samples and scale material, and geochemical modeling of scale Precipitation and Ra incorporation in barite.

  17. GaMin’11 – an international inter-laboratory comparison for geochemical CO₂ - saline fluid - mineral interaction experiments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ostertag-Henning, C.; Risse, A.; Thomas, B.; Rosenbauer, R.; Rochelle, C.; Purser, G.; Kilpatrick, A.; Rosenqvist, J.; Yardley, B.; Karamalidis, A.; et al

    2014-12-31

    Due to the strong interest in geochemical CO₂-fluid-rock interaction in the context of geological storage of CO₂ a growing number of research groups have used a variety of different experimental ways to identify important geochemical dissolution or precipitation reactions and – if possible – quantify the rates and extent of mineral or rock alteration. In this inter-laboratory comparison the gas-fluid-mineral reactions of three samples of rock-forming minerals have been investigated by 11 experimental labs. The reported results point to robust identification of the major processes in the experiments by most groups. The dissolution rates derived from the changes in compositionmore » of the aqueous phase are consistent overall, but the variation could be reduced by using similar corrections for changing parameters in the reaction cells over time. The comparison of experimental setups and procedures as well as of data corrections identified potential improvements for future gas-fluid-rock studies.« less

  18. Application of geochemical techniques to deduce the reservoir performance of the Palinpinon Geothermal Field, Philippines - an update

    SciTech Connect (OSTI)

    Ramos-Candelaria, M.N.; Garcia, S.E.; Hermoso, D.Z.

    1997-12-31

    Regular monitoring of various geochemical parameters in the water and vapor phases of the production wells at the Palinpinon I and II sectors of the Southern Negros Geothermal Field have been useful in the identification of the dominant reservoir processes occurring related to the present exploitation strategy. Observed geochemical and physical changes in the output of production wells have dictated production and injection strategies adopted to maximize production to meet the steam requirements of the power plant. Correlation of both physical and chemical data have identified the following reservoir processes: (1) Injection breakthrough via the Ticala Fault of the highly mineralized (Cl {approximately}8,000-10,500 mg/kg), isotopically enriched ({delta}{sup 18}O = -3.00{per_thousand}, {delta}{sup 2} H = -39{per_thousand}), and gas depleted brine for wells in the SW and central Puhagan. Injection breakthrough is also occurring in Palinpinon II and has resulted in temperature drops of 5-10{degrees}C.2. Pressure drawdown enhanced boiling in the liquid reservoir with steam separation of 220-240{degrees}C, feeding wells tapping the natural steam zone. However, enhanced drawdown has induced the entry of shallow acid steam condensate fluids in some wells (e.g. OK-7, PN-29D, PN-18D), which if not arrested could reduce production.

  19. Geochemical Evaluation of Uranium Fate and Transport Guterl Specialty Steel Site, New York - 12077

    SciTech Connect (OSTI)

    Frederick, Bill; Tandon, Vikas

    2012-07-01

    Between 1948 and 1952, up to 15,875 metric tons (35 million pounds) of natural uranium metal (U) were processed at the former Guterl Specialty Steel Corporation site in Lockport, New York. The resulting dust, thermal scale, mill shavings and associated land disposal contaminated both the facility and on-site soils. Uranium subsequently impacted groundwater and a fully developed plume exists below the site. Site soils are composed of anthropogenic fill and re-worked, glacially-derived native soil. This overburden is underlain by the weathered and fractured Lockport Dolostone bedrock. Shallow groundwater levels fluctuate seasonally and allow groundwater to contact U contaminated soil, which promotes transport. This condition is exemplified through coincident increases in specific conductivity and groundwater levels, which flush soluble constituents in the fill/soil to groundwater during recharge events. In addition, water-level fluctuations affect reduction-oxidation (redox) conditions at the site. The U in soils is subject to wetting and drying cycles that promote oxidation more than stable redox conditions (e.g., dry soil or fully saturated conditions). This oxidizing mechanism increases uranium solubility and mobility. Site groundwater also receives uranium via leaching from near-surface contaminated fill. The strong correlation between nitrate and uranium in groundwater indicates that uranium is mobile where oxidizing conditions occur. Analytical models of contaminant leaching determined that multiple pathways and transport mechanisms govern site risk. Uranium transport to groundwater involves three mechanisms: 1) direct contact of contaminated soil with groundwater, 2) the oxidation-state or chemical valence of uranium, and 3) the leaching of near-surface contamination to groundwater. These mechanisms require an integrated remedial solution that is sustainable and cost effective. (authors)

  20. Blind Geothermal System Exploration in Active Volcanic Environments; Multi-phase Geophysical and Geochemical Surveys in Overt and Subtle Volcanic Systems, Hawai’i and Maui

    SciTech Connect (OSTI)

    Fercho, Steven; Owens, Lara; Walsh, Patrick; Drakos, Peter; Martini, Brigette; Lewicki, Jennifer L.; Kennedy, Burton M.

    2015-08-01

    Suites of new geophysical and geochemical exploration surveys were conducted to provide evidence for geothermal resource at the Haleakala Southwest Rift Zone (HSWRZ) on Maui Island, Hawai’i. Ground-based gravity (~400 stations) coupled with heli-bourne magnetics (~1500 line kilometers) define both deep and shallow fractures/faults, while also delineating potentially widespread subsurface hydrothermal alteration on the lower flanks (below approximately 1800 feet a.s.l.). Multi-level, upward continuation calculations and 2-D gravity and magnetic modeling provide information on source depths, but lack of lithologic information leaves ambiguity in the estimates. Additionally, several well-defined gravity lows (possibly vent zones) lie coincident with magnetic highs suggesting the presence of dike intrusions at depth which may represent a potentially young source of heat. Soil CO2 fluxes were measured along transects across geophysically-defined faults and fractures as well as young cinder cones along the HSWRZ. This survey generally did not detect CO2 levels above background, with the exception of a weak anomalous flux signal over one young cinder cone. The general lack of observed CO2 flux signals on the HSWRZ is likely due to a combination of lower magmatic CO2 fluxes and relatively high biogenic surface CO2 fluxes which mix with the magmatic signal. Similar surveys at the Puna geothermal field on the Kilauea Lower East Rift Zone (KLERZ) also showed a lack of surface CO2 flux signals, however aqueous geochemistry indicated contribution of magmatic CO2 and He to shallow groundwater here. As magma has been intercepted in geothermal drilling at the Puna field, the lack of measured surface CO2 flux indicative of upflow of magmatic fluids here is likely due to effective “scrubbing” by high groundwater and a mature hydrothermal system. Dissolved inorganic carbon (DIC) concentrations, δ13C compositions and 3He/4He values were sampled at Maui from several shallow

  1. Data Package of Samples Collected for Hydrogeologic and Geochemical Characterization: 300 Area RI/FS Sediment Cores

    SciTech Connect (OSTI)

    Lindberg, Michael J.; Bjornstad, Bruce N.; Lanigan, David C.; Williams, Benjamin D.

    2011-05-01

    This is a data package for sediment samples received from the 300 FF 5 OU. This report was prepared for CHPRC. Between August 16, 2010 and April 25, 2011 sediment samples were received from 300-FF-5 for geochemical studies. The analyses for this project were performed at the 331 building located in the 300 Area of the Hanford Site. The analyses were performed according to Pacific Northwest National Laboratory (PNNL) approved procedures and/or nationally recognized test procedures. The data sets include the sample identification numbers, analytical results, estimated quantification limits (EQL), and quality control data. The preparatory and analytical quality control requirements, calibration requirements, acceptance criteria, and failure actions are defined in the on-line QA plan 'Conducting Analytical Work in Support of Regulatory Programs' (CAW). This QA plan implements the Hanford Analytical Services Quality Assurance Requirements Documents (HASQARD) for PNNL.

  2. Actualistic and Geochemical Modeling of Reservoir Rock, CO2 and Formation Fluid Interaction, Citronelle Oil Field, Alabama

    SciTech Connect (OSTI)

    Weislogel, Amy

    2014-01-31

    This report includes description of the Citronelle field study area and the work carried out in the project to characterize the geology and composition of reservoir rock material and to collect an analyze the geochemical composition of produced fluid waters from the Citronelle field. Reservoir rock samples collected from well bore core were made into thin-sections and assessed for textural properties, including pore types and porosity distribution. Compositional framework grain modal data were collected via point-counting, and grain and cement mineralogy was assessed using SEM-EDS. Geochemistry of fluid samples is described and modeled using PHREEQC. Composition of rock and produced fluids were used as inputs for TOUGHREACT reactive transport modeling, which determined the rock-fluid system was in disequilibrium.

  3. The integration of geochemical, geological and engineering data to determine reservoir continuity in the Iagifu-Hedinia field, Papua New Guinea

    SciTech Connect (OSTI)

    Kaufman, R.L.; Eisenberg, L.I.; Fitzmorris, R.E.

    1995-08-01

    A series of oil and gas fields, including Iagifu-Hedinia, occur along the leading edge of the Papuan fold and thrust belt. Formed during Pliocene to Recent compression, they are structurally complex, and typically broken into multiple reservoir compartments. The presence of the karstic Darai Limestone at the surface over most of the fold belt prevents acquisition of useful seismic data. Reservoir mapping, and establishment of reservoir continuity, is therefore based soley on (1) surface geologic data, (2) drilling data; initially dipmeter and RFT pressure data, and subsequently well production histories, and (3) geochemical correlation of reservoir fluids. During appraisal of the Iagifu-Hedinia discovery, these complimentary data sets demonstrated that (1) a single hydrocarbon column existed above a flowing aquifer in the main block of Iagifu-Hedinia field, (2) a separate acuumulation existed in the Usano area. Geochemical data have suggested the presence of reservoir compartments where other data were missing or inconclusive. Subsequently-acquired production history data have confirmed the geochemically-based interpretations. Geochemical data suggest that oils at Iagifu-Hedinia have a common source. The slight differences in oil composition between reservoirs are likely due to multiple phases of expulsion from the same source rock and/or migration-fractionation.

  4. Geothermal prospecting by geochemical methods on natural gas and water discharges in the Vulsini Mts Volcanic District (Central Italy)

    SciTech Connect (OSTI)

    Duchi, V.; Minissale, A.A.; Ortino, S.; Romani, L.

    1987-01-01

    The Latera and Torre Alfina geothermal fields were discovered in the Vulsini Mts district (central Italy) in the 70s. The fluid produced by the two geothermal systems is a high rhoCO/sub 2/(around 7 MPa) sodium chloride solution (T.D.S. is 9200 ppm at Latera and 7800 at Torre Alfina), with high SiO/sub 2/ and H/sub 3/BO/sub 3/ contents. The fluid temperature taken at well bottom is about 155/sup 0/C at Torre Alfina, whereas at Latera it ranges from 200 to over 350/sup 0/C. In spite of these temperatures, recorded in producing wells, previous geochemical prospectings using geothermometers in natural thermal manifestations had predicted temperatures no higher than 140/sup 0/C in all the Vulsini district. This contrasting feature between real temperatures and those evaluated during prospecting is caused by the fast circulation of large amounts of meteoric waters in the aquifer located in the shallow parts of the carbonate reservoir formations, and by the short interaction between the latter and the deep geothermal fluids. In the present study a new geochemical survey on thermal and cold springs, stream samples, as well as natural gas emissions has been carried out. A critical review of the main geothermometers, some considerations about the hydraulic behavior of the reservoir formations, and the cross comparison between NH/sub 4//sup +//B ratio, rhoCO/sub 2/ and SiO/sub 2/ content in both cold and thermal waters, have led to the conclusion that in the Vulsini Mts there are no shallow anomalous areas apart from those already discovered at Latera and Torre Alfina. The present method could be successfully applied in other geothermal systems, where the potential reservoir is represented by carbonate formations.

  5. Water quality evaluation and geochemical assessment of iron, manganese, and arsenic in a landfill site

    SciTech Connect (OSTI)

    Pisigan, R.A. Jr.

    1995-12-31

    Several monitoring wells at a landfill site were sampled for water quality parameters to determine the nature of groundwater contamination. The landfill, located beneath a limestone and dolomitic bedrock, has been used for about 20 years for trash and garbage disposal. The monitoring parameters include major cations and anions, as well as iron, manganese, arsenic, and other parameters measured in the field to characterize the subsurface conditions. Groundwater samples collected near the landfill and downgradient locations had higher levels of iron, manganese, arsenic, alkalinity, hardness than those samples from an upgradient well. The downgradient and on-site samples were also more acidic and turbid, The dissolved oxygen data tend to suggest reducing conditions in the leachate environment. The elevated groundwater concentrations of the three metals, especially iron, were most probably caused by the acidity generated by carbon dioxide and organic acids released from microbial degradation of organic compounds dumped into the landfill. The acidic pH led to the dissolution of iron, manganese, and arsenic bearing mineral phases. The buffering reactions of limestone and dolomite to neutralize the acidic degradation products increased the hardness cations, Ca{sup +2} and Mg{sup +2}. Inorganic speciation modeling indicates that iron, manganese, and arsenic predominantly exist as Fe {sup +2}, Mn{sup +2}, and H{sub 3}AsO{sub 3}. The possible presence of organic complexes of iron was discussed, but could be modeled due to lack of appropriate equilibrium constant data.

  6. Geochemical orientation survey of stream sediment, stream water, and ground water near uranium prospects, Monticello area, New York. National Uranium Resource Evaluation Program

    SciTech Connect (OSTI)

    Rose, A. W.; Smith, A. T.; Wesolowski, D.

    1982-08-01

    A detailed geochemical test survey has been conducted in a 570 sq km area around six small copper-uranium prospects in sandstones of the Devonian Catskill Formation near Monticello in southern New York state. This report summarizes and interprets the data for about 500 stream sediment samples, 500 stream water samples, and 500 ground water samples, each analyzed for 40 to 50 elements. The groundwater samples furnish distinctive anomalies for uranium, helium, radon, and copper near the mineralized localities, but the samples must be segregated into aquifers in order to obtain continuous well-defined anomalies. Two zones of uranium-rich water (1 to 16 parts per billion) can be recognized on cross sections; the upper zone extends through the known occurrences. The anomalies in uranium and helium are strongest in the deeper parts of the aquifers and are diluted in samples from shallow wells. In stream water, copper and uranium are slightly anomalous, as in an ore factor derived from factor analysis. Ratios of copper, uranium, and zinc to conductivity improve the resolution of anomalies. In stream sediment, extractable uranium, copper, niobium, vanadium, and an ore factor furnish weak anomalies, and ratios of uranium and copper to zinc improve the definition of anomalies. The uranium/thorium ratio is not helpful. Published analyses of rock samples from the nearby stratigraphic section show distinct anomalies in the zone containing the copper-uranium occurrences. This report is being issued without the normal detailed technical and copy editing, to make the data available to the public before the end of the National Uranium Reconnaissance Evaluation program.

  7. Solid phase evolution in the Biosphere 2 hillslope experiment as predicted by modeling of hydrologic and geochemical fluxes

    SciTech Connect (OSTI)

    Dontsova, K.; Steefel, C.I.; Desilets, S.; Thompson, A.; Chorover, J.

    2009-07-15

    A reactive transport geochemical modeling study was conducted to help predict the mineral transformations occurring over a ten year time-scale that are expected to impact soil hydraulic properties in the Biosphere 2 (B2) synthetic hillslope experiment. The modeling sought to predict the rate and extent of weathering of a granular basalt (selected for hillslope construction) as a function of climatic drivers, and to assess the feedback effects of such weathering processes on the hydraulic properties of the hillslope. Flow vectors were imported from HYDRUS into a reactive transport code, CrunchFlow2007, which was then used to model mineral weathering coupled to reactive solute transport. Associated particle size evolution was translated into changes in saturated hydraulic conductivity using Rosetta software. We found that flow characteristics, including velocity and saturation, strongly influenced the predicted extent of incongruent mineral weathering and neo-phase precipitation on the hillslope. Results were also highly sensitive to specific surface areas of the soil media, consistent with surface reaction controls on dissolution. Effects of fluid flow on weathering resulted in significant differences in the prediction of soil particle size distributions, which should feedback to alter hillslope hydraulic conductivities.

  8. Geochemical and Mineralogical Investigation of Uranium in Multielement Contaminated, Organicrich Subsurface Sediment

    SciTech Connect (OSTI)

    Qafoku, Nikolla; Gartman, Brandy N.; Kukkadapu, Ravi K.; Arey, Bruce W.; Williams, Kenneth H.; Mouser, Paula J.; Heald, Steve M.; Bargar, John R.; Janot, Noemie; Yabusaki, Steven B.; Long, Philip E.

    2014-03-02

    Alluvial sediments characterized by an abundance of refractory or lignitic organic carbon compounds and reduced Fe and S bearing mineral phases have been identified through drilling activities at the U.S. Department of Energys (DOE) Integrated Field Research Challenge (IFRC) site at Rifle, CO. Regions of the subsurface from which such sediments are derived are referred to as Naturally Reduced Zones (NRZ). We conducted a study with NRZ sediments with the objective to: i.) Characterize solid phase contamination of U and other co-contaminants; ii.) Document the occurrence of potential U host minerals; iii.) Determine U valence state and micron scale spatial association with co-contaminants. Macroscopic (wet chemical batch extractions and a column experiment), microscopic (SEM-EDS), and spectroscopic (Mssbauer, -XRF and XANES) techniques were employed. Results showed that sediments solid phase had significant concentrations of U, S, As, Zn, V, Cr, Cu and Se, and a remarkable assortment of potential U hosts (sorbents and/or electron donors), such as Fe oxides (hematite, magnetite, Al-substituted goethite), siderite, reduced Fe(II) bearing clays, sulfides of different types, Zn sulfide framboids and multi element sulfides. Multi-contaminants, micron size (ca. 5 to 30 m) areas of mainly U(IV) and some U(VI), and/or other electron scavengers or donors such as Se, As, Cr, and V were discovered in the sediments, suggesting complex micron-scale system responses to transient redox conditions, and different extent and rates of competing U redox reactions than those of single contaminant systems. Collectively, the results improve our understanding and ability to predict U and NRZs complex behavior and will delineate future research directions to further study both the natural attenuation and persistence of contaminant plumes and their contribution to groundwater contamination.

  9. CORE-BASED INTEGRATED SEDIMENTOLOGIC, STRATIGRAPHIC, AND GEOCHEMICAL ANALYSIS OF THE OIL SHALE BEARING GREEN RIVER FORMATION, UINTA BASIN, UTAH

    SciTech Connect (OSTI)

    Lauren P. Birgenheier; Michael D. Vanden Berg,

    2011-04-11

    An integrated detailed sedimentologic, stratigraphic, and geochemical study of Utah's Green River Formation has found that Lake Uinta evolved in three phases (1) a freshwater rising lake phase below the Mahogany zone, (2) an anoxic deep lake phase above the base of the Mahogany zone and (3) a hypersaline lake phase within the middle and upper R-8. This long term lake evolution was driven by tectonic basin development and the balance of sediment and water fill with the neighboring basins, as postulated by models developed from the Greater Green River Basin by Carroll and Bohacs (1999). Early Eocene abrupt global-warming events may have had significant control on deposition through the amount of sediment production and deposition rates, such that lean zones below the Mahogany zone record hyperthermal events and rich zones record periods between hyperthermals. This type of climatic control on short-term and long-term lake evolution and deposition has been previously overlooked. This geologic history contains key points relevant to oil shale development and engineering design including: (1) Stratigraphic changes in oil shale quality and composition are systematic and can be related to spatial and temporal changes in the depositional environment and basin dynamics. (2) The inorganic mineral matrix of oil shale units changes significantly from clay mineral/dolomite dominated to calcite above the base of the Mahogany zone. This variation may result in significant differences in pyrolysis products and geomechanical properties relevant to development and should be incorporated into engineering experiments. (3) This study includes a region in the Uinta Basin that would be highly prospective for application of in-situ production techniques. Stratigraphic targets for in-situ recovery techniques should extend above and below the Mahogany zone and include the upper R-6 and lower R-8.

  10. Developing a robust geochemical and reactive transport model to evaluate possible sources of arsenic at the CO[subscript 2] sequestration natural analog site in Chimayo, New Mexico

    SciTech Connect (OSTI)

    Viswanathan, Hari; Dai, Zhenxue; Lopano, Christina; Keating, Elizabeth; Hakala, J. Alexandra; Scheckel, Kirk G.; Zheng, Liange; Gutherie, George D.; Pawar, Rajesh

    2012-10-24

    Migration of carbon dioxide (CO{sub 2}) from deep storage formations into shallow drinking water aquifers is a possible system failure related to geologic CO{sub 2} sequestration. A CO{sub 2} leak may cause mineral precipitation/dissolution reactions, changes in aqueous speciation, and alteration of pH and redox conditions leading to potential increases of trace metal concentrations above EPA National Primary Drinking Water Standards. In this study, the Chimayo site (NM) was examined for site-specific impacts of shallow groundwater interacting with CO{sub 2} from deep storage formations. Major ion and trace element chemistry for the site have been previously studied. This work focuses on arsenic (As), which is regulated by the EPA under the Safe Drinking Water Act and for which some wells in the Chimayo area have concentrations higher than the maximum contaminant level (MCL). Statistical analysis of the existing Chimayo groundwater data indicates that As is strongly correlated with trace metals U and Pb indicating that their source may be from the same deep subsurface water. Batch experiments and materials characterization, such as: X-ray diffraction (XRD), scanning electron microscopy (SEM), and synchrotron micro X-ray fluorescence ({mu}-XRF), were used to identify As association with Fe-rich phases, such as clays or oxides, in the Chimayo sediments as the major factor controlling As fate in the subsurface. Batch laboratory experiments with Chimayo sediments and groundwater show that pH decreases as CO{sub 2} is introduced into the system and buffered by calcite. The introduction of CO{sub 2} causes an immediate increase in As solution concentration, which then decreases over time. A geochemical model was developed to simulate these batch experiments and successfully predicted the pH drop once CO{sub 2} was introduced into the experiment. In the model, sorption of As to illite, kaolinite and smectite through surface complexation proved to be the key reactions in

  11. Mineral dissolution and precipitation during CO2 injection at the Frio-I Brine Pilot: Geochemical modeling and uncertainty analysis

    SciTech Connect (OSTI)

    Ilgen, A. G.; Cygan, R. T.

    2015-12-07

    During the Frio-I Brine Pilot CO2 injection experiment in 2004, distinct geochemical changes in response to the injection of 1600 tons of CO2 were recorded in samples collected from the monitoring well. Previous geochemical modeling studies have considered dissolution of calcite and iron oxyhydroxides, or release of adsorbed iron, as the most likely sources of the increased ion concentrations. We explore in this modeling study possible alternative sources of the increasing calcium and iron, based on the data from the detailed petrographic characterization of the Upper Frio Formation “C”. Particularly, we evaluate whether dissolution of pyrite and oligoclase (anorthite component) can account for the observed geochemical changes. Due to kinetic limitations, dissolution of pyrite and anorthite cannot account for the increased iron and calcium concentrations on the time scale of the field test (10 days). However, dissolution of these minerals is contributing to carbonate and clay mineral precipitation on the longer time scales (1000 years). The one-dimensional reactive transport model predicts carbonate minerals, dolomite and ankerite, as well as clay minerals kaolinite, nontronite and montmorillonite, will precipitate in the Frio Formation “C” sandstone as the system progresses towards chemical equilibrium during a 1000-year period. Cumulative uncertainties associated with using different thermodynamic databases, activity correction models (Pitzer vs. B-dot), and extrapolating to reservoir temperature, are manifested in the difference in the predicted mineral phases. Furthermore, these models are consistent with regards to the total volume of mineral precipitation and porosity values which are predicted to within 0.002%.

  12. Geochemical engineering reference manual

    SciTech Connect (OSTI)

    Owen, L.B.; Michels, D.E.

    1984-01-01

    The following topics are included in this manual: physical and chemical properties of geothermal brine and steam, scale and solids control, processing spent brine for reinjection, control of noncondensable gas emissions, and goethermal mineral recovery. (MHR)

  13. Geochemical indicators of depositional environment and soruce-rock potential for the Upper Ordovician Maquoketa Group, Illinois basin

    SciTech Connect (OSTI)

    Guthrie, J.M.; Pratt, L.M. )

    1994-05-01

    Two depositional cycles are recognized within the Upper Ordovician Maquoketa Group of the Illinois basin in a core from the New Jersey Zinc 1 Parrish well of Fulton County, Illinois. Organic carbon (C[sub org]), total sulfur, [sup 13]C content of the organic carbon ([delta][sup 13]C[sub org]), hydrogen and oxygen indices (HI and OI) from Rock-Eval pyrolysis and yields of extractable organic matter (EOM) vary through the cycles. Dark-brown to black, laminated shales are present in the lower portion of each cycle and have high values of C[sub org] (1.0-3.0%), HI (500-1000 mg hydrocarbon [HC]/g total organic carbon[TOC]), and EOM (500-2500 ppm), and more negative [delta][sup 13]C[sub org] values ([delta][sup 13]C[sub org] = -30 to -30.5%). Gray to greenish-gray, bioturbated shales are present in the upper portion of each cycle and have low values of C[sub org] (<1.0%), HI (<500 mg HC/g TOC), and EOM (<500 ppm), and more positive [delta][sup 13]C[sub org] values (-28.5 to 29.5%) compared to the laminated shales. Although thermally immature or marginally mature in this core, the laminated shales represent potential source rock s for petroleum because they contain good to excellent quantities of oil-prone organic matter and are more deeply buried in other areas of the basin. Kerogen elemental data and Rock-Eval data suggest that the source of organic matter in the Maquoketa was uniform, with the notable exception of graptolite-rich layers. Distributions of saturated hydrocarbons for Maquoketa samples resemble those derived from amorphous organic matter. Variations in bulk geochemical data and carbon isotopic compositions within the Maquoketa Group indicate substantial reworking and degradation of organic matter associated with bioturbation and oxygenated depositional conditions. 64 refs., 10 figs., 1 tab.

  14. Evaluation of Pre- and Post-Redevelopment Groundwater Chemical Analyses

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from LM Monitoring Wells | Department of Energy Evaluation of Pre- and Post-Redevelopment Groundwater Chemical Analyses from LM Monitoring Wells Evaluation of Pre- and Post-Redevelopment Groundwater Chemical Analyses from LM Monitoring Wells AS&T Ancillary Work Plan (AWP) Final Well Redevelopment Evaluation Report Evaluation of Pre- and Post-Redevelopment Groundwater Chemical Analyses from LM Monitoring Wells (3.25 MB) More Documents & Publications Analysis and Geochemical Modeling

  15. Novel imaging techniques, integrated with mineralogical, geochemical and microbiological characterizations to determine the biogeochemical controls on technetium mobility in FRC sediments

    SciTech Connect (OSTI)

    Jonathan R. Lloyd

    2009-02-03

    The objective of this research program was to take a highly multidisciplinary approach to define the biogeochemical factors that control technetium (Tc) mobility in FRC sediments. The aim was to use batch and column studies to probe the biogeochemical conditions that control the mobility of Tc at the FRC. Background sediment samples from Area 2 (pH 6.5, low nitrate, low {sup 99}Tc) and Area 3 (pH 3.5, high nitrate, relatively high {sup 99}Tc) of the FRC were selected (http://www.esd.ornl.gov/nabirfrc). For the batch experiments, sediments were mixed with simulated groundwater, modeled on chemical constituents of FRC waters and supplemented with {sup 99}Tc(VII), both with and without added electron donor (acetate). The solubility of the Tc was monitored, alongside other biogeochemical markers (nitrate, nitrite, Fe(II), sulfate, acetate, pH, Eh) as the 'microcosms' aged. At key points, the microbial communities were also profiled using both cultivation-dependent and molecular techniques, and results correlated with the geochemical conditions in the sediments. The mineral phases present in the sediments were also characterized, and the solid phase associations of the Tc determined using sequential extraction and synchrotron techniques. In addition to the batch sediment experiments, where discrete microbial communities with the potential to reduce and precipitate {sup 99}Tc will be separated in time, we also developed column experiments where biogeochemical processes were spatially separated. Experiments were conducted both with and without amendments proposed to stimulate radionuclide immobilization (e.g. the addition of acetate as an electron donor for metal reduction), and were also planned with and without competing anions at high concentration (e.g. nitrate, with columns containing Area 3 sediments). When the columns had stabilized, as determined by chemical analysis of the effluents, we used a spike of the short-lived gamma emitter {sup 99m}Tc (50-200 MBq; half

  16. Pre-test geological and geochemical evaluation of the Caprock, St. Peter Sandstone and formation fluids, Yakley Field, Pike County, Illinois

    SciTech Connect (OSTI)

    Not Available

    1983-03-01

    The goal of these studies is to ensure long-term stable containment of air in the underground reservoirs used in conjunction with compressed air energy storage (CAES) plants. The specific objective is to develop stability criteria and engineering guidelines for designing CAES reservoirs in each of the three major reservoir types, including aquifers, salt cavities, and mined hard rock caverns. This document characterizes the geologic nature of porous media constituents native to the aquifer field test site near Pittsfield, Illinois. The geologic samples were subjected to geochemical evaluations to determine anticipated responses to cyclic air injection, heating and moisture - conditions typical of an operating CAES reservoir. This report documents the procedures used and results obtained from these analyses.

  17. Drill-hole data, drill-site geology, and geochemical data from the study of Precambrian uraniferous conglomerates of the Medicine Bow Mountains and Sierra Madre of southeastern Wyoming

    SciTech Connect (OSTI)

    Karlstrom, K.E.; Houston, R.S.; Schmidt, T.G.; Inlow, D.; Flurkey, A.J.; Kratochvil, A.L.; Coolidge, C.M.; Sever, C.K.; Quimby, W.F.

    1981-02-01

    This volume is presented as a companion to Volume 1: The Geology and Uranium Potential of Precambrian Conglomerates in the Medicine Bow Mountains and Sierra Madre of Southeastern Wyoming; and to Volume 3: Uranium Assessment for Precambrian Pebble Conglomerates in Southeastern Wyoming. Volume 1 summarized the geologic setting and geologic and geochemical characteristics of uranium-bearing conglomerates in Precambrian metasedimentary rocks of southeastern Wyoming. Volume 3 is a geostatistical resource estimate of U and Th in quartz-pebble conglomerates. This volume contains supporting geochemical data, lithologic logs from 48 drill holes in Precambrian rocks of the Medicine Bow Mountains and Sierra Madre, and drill site geologic maps and cross-sections from most of the holes.

  18. EQ3NR, a computer program for geochemical aqueous speciation-solubility calculations: Theoretical manual, user`s guide, and related documentation (Version 7.0); Part 3

    SciTech Connect (OSTI)

    Wolery, T.J.

    1992-09-14

    EQ3NR is an aqueous solution speciation-solubility modeling code. It is part of the EQ3/6 software package for geochemical modeling. It computes the thermodynamic state of an aqueous solution by determining the distribution of chemical species, including simple ions, ion pairs, and complexes, using standard state thermodynamic data and various equations which describe the thermodynamic activity coefficients of these species. The input to the code describes the aqueous solution in terms of analytical data, including total (analytical) concentrations of dissolved components and such other parameters as the pH, pHCl, Eh, pe, and oxygen fugacity. The input may also include a desired electrical balancing adjustment and various constraints which impose equilibrium with special pure minerals, solid solution end-member components (of specified mole fractions), and gases (of specified fugacities). The code evaluates the degree of disequilibrium in terms of the saturation index (SI = 1og Q/K) and the thermodynamic affinity (A = {minus}2.303 RT log Q/K) for various reactions, such as mineral dissolution or oxidation-reduction in the aqueous solution itself. Individual values of Eh, pe, oxygen fugacity, and Ah (redox affinity) are computed for aqueous redox couples. Equilibrium fugacities are computed for gas species. The code is highly flexible in dealing with various parameters as either model inputs or outputs. The user can specify modification or substitution of equilibrium constants at run time by using options on the input file.

  19. Sedimentological, mineralogical and geochemical definition of oil-shale facies in the lower Parachute Creek Member of Green River Formation, Colorado

    SciTech Connect (OSTI)

    Cole, R.D.

    1984-04-01

    Sedimentological, mineralogical and geochemical studies of two drill cores penetrating the lower Saline zone of the Parachute Creek Member (middle L-4 oil-shale zone through upper R-2 zone) of the Green River Formation in north-central Piceance Creek basin, Colorado, indicate the presence of two distinct oil-shale facies. The most abundant facies has laminated stratification and frequently occurs in the L-4, L-3 and L-2 oil-shale zones. The second, and subordinate facies, has ''streaked and blebby'' stratification and is most abundant in the R-4, R-3 and R-2 zones. Laminated oil shale originated by slow, regular sedimentation during meromictic phases of ancient Lake Uinta, whereas streaked and blebby oil shale was deposited by episodic, non-channelized turbidity currents. Laminated oil shale has higher contents of nahcolite, dawsonite, quartz, K-feldspar and calcite, but less dolomite/ankerite and albite than streaked and blebby oil shale. Ca-Mg-Fe carbonate minerals in laminated oil shale have more variable compositions than those in streaked and blebby shales. Streaked and blebby oil shale has more kerogen and a greater diversity of kerogen particles than laminated oil shale. Such variations may produce different pyrolysis reactions when each shale type is retorted.

  20. Geochemical, mineralogical and microbiological characteristics of sediment from a naturally reduced zone in a uranium-contaminated aquife

    SciTech Connect (OSTI)

    Campbell, K M; K Kukkadapu, R K; Qafoku, N P; Peacock, A D; Lesher, E; Williams, K H; Bargar, J R; Wilkins, M J; Figueroa, L; Ranville, J; Davis, J A; Long, P E

    2012-05-23

    Localized zones or lenses of naturally reduced sediments have the potential to play a significant role in the fate and transport of redox-sensitive metals and metalloids in aquifers. To assess the mineralogy, microbiology and redox processes that occur in these zones, several cores from a region of naturally occurring reducing conditions in a U-contaminated aquifer (Rifle, CO) were examined. Sediment samples from a transect of cores ranging from oxic/suboxic Rifle aquifer sediment to naturally reduced sediment were analyzed for U and Fe content, oxidation state, and mineralogy; reduced S phases; and solid-phase organic C content using a suite of analytical and spectroscopic techniques on bulk sediment and size fractions. Solid-phase U concentrations were higher in the naturally reduced zone, with a high proportion of the U present as U(IV). The sediments were also elevated in reduced S phases and Fe(II), indicating it is very likely that U(VI), Fe(III), and SO4 reduction has occurred or is occurring in the sediment. The microbial community was assessed using lipid- and DNA-based techniques, and statistical redundancy analysis was performed to determine correlations between the microbial community and the geochemistry. Increased concentrations of solid-phase organic C and biomass in the naturally reduced sediment suggests that natural bioreduction is stimulated by a zone of increased organic C concentration associated with fine-grained material and lower permeability to groundwater flow. Characterization of the naturally bioreduced sediment provides an understanding of the natural processes that occur in the sediment under reducing conditions and how they may impact natural attenuation of radionuclides and other redox sensitive materials. Results also suggest the importance of recalcitrant organic C for maintaining reducing conditions and U immobilization.

  1. DOE ER63951-3 Final Report: An Integrated Assessment of Geochemical and Community Structure Determinants of Metal Reduction Rates in Subsurface Sediments

    SciTech Connect (OSTI)

    Susan Pfiffner

    2010-06-28

    The objective of this research was to examine the importance of microbial community structure in influencing uranium reduction rates in subsurface sediments. If the redox state alone is the key to metal reduction, then any organisms that can utilize the oxygen and nitrate in the subsurface can change the geochemical conditions so metal reduction becomes an energetically favored reaction. Thus, community structure would not be critical in determining rates or extent of metal reduction unless community structure influenced the rate of change in redox. Alternatively, some microbes may directly catalyze metal reduction (e.g., specifically reduce U). In this case the composition of the community may be more important and specific types of electron donors may promote the production of communities that are more adept at U reduction. Our results helped determine if the type of electron donor or the preexisting community is important in the bioremediation of metal-contaminated environments subjected to biostimulation. In a series of experiments at the DOE FRC site in Oak Ridge we have consistently shown that all substrates promoted nitrate reduction, while glucose, ethanol, and acetate always promoted U reduction. Methanol only occasionally promoted extensive U reduction which is possibly due to community heterogeneity. There appeared to be limitations imposed on the community related to some substrates (e.g. methanol and pyruvate). Membrane lipid analyses (phospholipids and respiratory quinones) indicated different communities depending on electron donor used. Terminal restriction fragment length polymorphism and clone libraries indicated distinct differences among communities even in treatments that promoted U reduction. Thus, there was enough metabolic diversity to accommodate many different electron donors resulting in the U bioimmobilization.

  2. User's Guide of TOUGH2-EGS. A Coupled Geomechanical and Reactive Geochemical Simulator for Fluid and Heat Flow in Enhanced Geothermal Systems Version 1.0

    SciTech Connect (OSTI)

    Fakcharoenphol, Perapon; Xiong, Yi; Hu, Litang; Winterfeld, Philip H.; Xu, Tianfu; Wu, Yu-Shu

    2013-05-01

    TOUGH2-EGS is a numerical simulation program coupling geomechanics and chemical reactions for fluid and heat flows in porous media and fractured reservoirs of enhanced geothermal systems. The simulator includes the fully-coupled geomechanical (THM) module, the fully-coupled geochemical (THC) module, and the sequentially coupled reactive geochemistry (THMC) module. The fully-coupled flow-geomechanics model is developed from the linear elastic theory for the thermo-poro-elastic system and is formulated with the mean normal stress as well as pore pressure and temperature. The chemical reaction is sequentially coupled after solution of flow equations, which provides the flow velocity and phase saturation for the solute transport calculation at each time step. In addition, reservoir rock properties, such as porosity and permeability, are subjected to change due to rock deformation and chemical reactions. The relationships between rock properties and geomechanical and chemical effects from poro-elasticity theories and empirical correlations are incorporated into the simulator. This report provides the user with detailed information on both mathematical models and instructions for using TOUGH2-EGS for THM, THC or THMC simulations. The mathematical models include the fluid and heat flow equations, geomechanical equation, reactive geochemistry equations, and discretization methods. Although TOUGH2-EGS has the capability for simulating fluid and heat flows coupled with both geomechanical and chemical effects, it is up to the users to select the specific coupling process, such as THM, THC, or THMC in a simulation. There are several example problems illustrating the applications of this program. These example problems are described in details and their input data are presented. The results demonstrate that this program can be used for field-scale geothermal reservoir simulation with fluid and heat flow, geomechanical effect, and chemical reaction in porous and fractured media.

  3. Geochemical Techniques | Open Energy Information

    Open Energy Info (EERE)

    Geothermometers Multicomponent Geothermometers Silica Geothermometers Thermal Ion Dispersion Thermochronometry References General References Technical References No exploration...

  4. Data Package for Past and Current Groundwater Flow and Contamination beneath Single-Shell Tank Waste Management Areas

    SciTech Connect (OSTI)

    Horton, Duane G.

    2007-03-16

    This appendix summarizes historic and recent groundwater data collected from the uppermost aquifer beneath the 200 East and 200 West Areas. Although the area of interest is the Hanford Site Central Plateau, most of the information discussed in this appendix is at the scale of individual single-shell tank waste management areas. This is because the geologic, and thus the hydraulic, properties and the geochemical properties (i.e., groundwater composition) are different in different parts of the Central Plateau.

  5. Comparative metagenomics reveals impact of contaminants on groundwater microbiomes

    SciTech Connect (OSTI)

    Hemme, Christopher L.; Tu, Qichao; Shi, Zhou; Qin, Yujia; Gao, Weimin; Deng, Ye; Nostrand, Joy D. Van; Wu, Liyou; He, Zhili; Chain, Patrick S. G.; Tringe, Susannah G.; Fields, Matthew W.; Rubin, Edward M.; Tiedje, James M.; Hazen, Terry C.; Arkin, Adam P.; Zhou, Jizhong

    2015-10-31

    To understand patterns of geochemical cycling in pristine versus contaminated groundwater ecosystems, pristine shallow groundwater (FW301) and contaminated groundwater (FW106) samples from the Oak Ridge Integrated Field Research Center (OR-IFRC) were sequenced and compared to each other to determine phylogenetic and metabolic difference between the communities. Proteobacteria (e.g., Burkholderia, Pseudomonas) are the most abundant lineages in the pristine community, though a significant proportion ( >55%) of the community is composed of poorly characterized low abundance (individually <1%) lineages. The phylogenetic diversity of the pristine community contributed to a broader diversity of metabolic networks than the contaminated community. In addition, the pristine community encodes redundant and mostly complete geochemical cycles distributed over multiple lineages and appears capable of a wide range of metabolic activities. In contrast, many geochemical cycles in the contaminated community appear truncated or minimized due to decreased biodiversity and dominance by Rhodanobacter populations capable of surviving the combination of stresses at the site. In conclusion, these results indicate that the pristine site contains more robust and encodes more functional redundancy than the stressed community, which contributes to more efficient nutrient cycling and adaptability than the stressed community.

  6. Comparative metagenomics reveals impact of contaminants on groundwater microbiomes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hemme, Christopher L.; Tu, Qichao; Shi, Zhou; Qin, Yujia; Gao, Weimin; Deng, Ye; Nostrand, Joy D. Van; Wu, Liyou; He, Zhili; Chain, Patrick S. G.; et al

    2015-10-31

    To understand patterns of geochemical cycling in pristine versus contaminated groundwater ecosystems, pristine shallow groundwater (FW301) and contaminated groundwater (FW106) samples from the Oak Ridge Integrated Field Research Center (OR-IFRC) were sequenced and compared to each other to determine phylogenetic and metabolic difference between the communities. Proteobacteria (e.g., Burkholderia, Pseudomonas) are the most abundant lineages in the pristine community, though a significant proportion ( >55%) of the community is composed of poorly characterized low abundance (individually <1%) lineages. The phylogenetic diversity of the pristine community contributed to a broader diversity of metabolic networks than the contaminated community. In addition, themore » pristine community encodes redundant and mostly complete geochemical cycles distributed over multiple lineages and appears capable of a wide range of metabolic activities. In contrast, many geochemical cycles in the contaminated community appear truncated or minimized due to decreased biodiversity and dominance by Rhodanobacter populations capable of surviving the combination of stresses at the site. In conclusion, these results indicate that the pristine site contains more robust and encodes more functional redundancy than the stressed community, which contributes to more efficient nutrient cycling and adaptability than the stressed community.« less

  7. Reduced-Order Model for the Geochemical Impacts of Carbon Dioxide, Brine and Trace Metal Leakage into an Unconfined, Oxidizing Carbonate Aquifer, Version 2.1

    SciTech Connect (OSTI)

    Bacon, Diana H.

    2013-03-31

    The National Risk Assessment Partnership (NRAP) consists of 5 U.S DOE national laboratories collaborating to develop a framework for predicting the risks associated with carbon sequestration. The approach taken by NRAP is to divide the system into components, including injection target reservoirs, wellbores, natural pathways including faults and fractures, groundwater and the atmosphere. Next, develop a detailed, physics and chemistry-based model of each component. Using the results of the detailed models, develop efficient, simplified models, termed reduced order models (ROM) for each component. Finally, integrate the component ROMs into a system model that calculates risk profiles for the site. This report details the development of the Groundwater Geochemistry ROM for the Edwards Aquifer at PNNL. The Groundwater Geochemistry ROM for the Edwards Aquifer uses a Wellbore Leakage ROM developed at LANL as input. The detailed model, using the STOMP simulator, covers a 5x8 km area of the Edwards Aquifer near San Antonio, Texas. The model includes heterogeneous hydraulic properties, and equilibrium, kinetic and sorption reactions between groundwater, leaked CO2 gas, brine, and the aquifer carbonate and clay minerals. Latin Hypercube sampling was used to generate 1024 samples of input parameters. For each of these input samples, the STOMP simulator was used to predict the flux of CO2 to the atmosphere, and the volume, length and width of the aquifer where pH was less than the MCL standard, and TDS, arsenic, cadmium and lead exceeded MCL standards. In order to decouple the Wellbore Leakage ROM from the Groundwater Geochemistry ROM, the response surface was transformed to replace Wellbore Leakage ROM input parameters with instantaneous and cumulative CO2 and brine leakage rates. The most sensitive parameters proved to be the CO2 and brine leakage rates from the well, with equilibrium coefficients for calcite and dolomite, as well as the number of illite and kaolinite

  8. Intermittent Elevated Radium Concentrations in Coastal Plain Groundwater of South Carolina, U.S.A.

    SciTech Connect (OSTI)

    Denham, Miles; Millings, Margaret; Noonkester, Jay

    2005-09-22

    To learn the cause of intermittent radium concentrations in groundwater of Coastal Plain aquifers, 31 groundwater wells in South Carolina, U.S.A. were sampled for radium and other geochemical parameters. Sediments cored from near the well screens were also sampled to examine any relationship between sediment properties and radium concentration in the groundwater. Elevated radium concentrations only occurred in groundwater with low electrical conductivity and pH values below 6.3. The adsorption edge for radium on hematite--a major surface active mineral in these aquifers--is at a pH value of about 6. Near this value, small changes in pH can result in significant adsorption or desorption of radium. In groundwater with initially low alkalinity, small intermittent decreases in partial pressure of carbon dioxide in groundwater cause decreases in pH and desorption of radium. The result is intermittent elevated radium concentrations.

  9. Microbiological, Geochemical and Hydrologic Processes Controlling Uranium Mobility: An Integrated Field-Scale Subsurface Research Challenge Site at Rifle, Colorado, Quality Assurance Project Plan

    SciTech Connect (OSTI)

    Fix, N. J.

    2008-01-07

    The U.S. Department of Energy (DOE) is cleaning up and/or monitoring large, dilute plumes contaminated by metals, such as uranium and chromium, whose mobility and solubility change with redox status. Field-scale experiments with acetate as the electron donor have stimulated metal-reducing bacteria to effectively remove uranium [U(VI)] from groundwater at the Uranium Mill Tailings Site in Rifle, Colorado. The Pacific Northwest National Laboratory and a multidisciplinary team of national laboratory and academic collaborators has embarked on a research proposed for the Rifle site, the object of which is to gain a comprehensive and mechanistic understanding of the microbial factors and associated geochemistry controlling uranium mobility so that DOE can confidently remediate uranium plumes as well as support stewardship of uranium-contaminated sites. This Quality Assurance Project Plan provides the quality assurance requirements and processes that will be followed by the Rifle Integrated Field-Scale Subsurface Research Challenge Project.

  10. Hanford Site ground-water monitoring for July through December 1987

    SciTech Connect (OSTI)

    Evans, J.C.; Dennison, D.I.; Bryce, R.W.; Mitchell, P.J.; Sherwood, D.R.; Krupka, K.M.; Hinman, N.W.; Jacobson, E.A.; Freshley, M.D.

    1988-12-01

    The Pacific Northwest Laboratory monitors ground-water quality at the Hanford Site for the US Department of Energy to assess the impact of Site operations on the environment. Work undertaken between July and December 1987 included monitoring ground-water elevations across the Site, monitoring hazardous chemicals and radionuclides in ground water, geochemical evaluations of unconfined ground-water data, and calibration of ground-water flow and transport models. Water levels continued to rise in areas receiving increased recharge (e.g., beneath B Pond) and decline in areas where the release of water to disposal facilities has been terminated (e.g., U Pond). The major areas of ground-water contamination defined by monitoring activities are (1) carbon tetrachloride in the 200-West Area; (2) cyanide in and north of the 200-East and 200-West Areas; (3) hexavalent chromium contamination in the 100-B, 100-D, 100-F, 100-H, 100-K, and 200-West Areas; (4) chlorinated hydrocarbons in the vicinity of the Central Landfill and 300 Area; (5) uranium in the 100-F, 100-H, 200-West, and 300 Areas; and (6) tritium and nitrate across the Site. The MINTEQ geochemical code was used to identify chemical reactions that may be affecting the concentrations of dissolved hazardous chemicals in the unconfined ground water. Results indicate that many cations are present mainly as dissolved carbonate complexes and that a majority of the ground-water samples are in near equilibrium with carbonate minerals (e.g., calcite, dolomite, otavite).

  11. Geochemical simulation of dissolution of West Valley and DWPF [Defense Waste Product Facility] glasses in J-13 water at 90{sup 0}C.

    SciTech Connect (OSTI)

    Bruton, C.J.

    1987-11-01

    Dissolution of West Valley and Defense Waste Product Facility (DWPF) glasses in J-13 water at 90{sup 0}C at the candidate Yucca Mountain, Nevada repository was simulated using the EQ3/6 computer code package. The objectives of the study were to attempt to predict the concentrations of radionuclides and other glass components in solution resulting from glass dissolution, and to identify potential precipitates that sequester glass components. Modified projected inventories of 10,000 year-old West Valley and DWPF SRL-165 frit glasses were used as starting glass compositions. J-13 water was considered to be representative of groundwater at Yucca Mountain. A total of 10 grams of each glass was assumed to dissolve congruently into a kilogram of J-13 water in a closed system. No inhibitions to precipitation, except for crystalline SiO{sub 2} polymorphs, were assumed to exist. Radiolysis and materials interactions were not considered. Simulation results predict that radionuclides and other glass components precipitate predominantly in the form of oxides and hydroxides, together with carbonates, silicates and phosphates. Precipitates appear to be effective in limiting the concentrations of radionuclides and other elements in solution. The general compositional trends in precipitates and solution chemistry are the same in the West Valley and DWPF simulations, except for variations arising from differences in glass chemistry. 20 refs., 7 figs., 3 tabs.

  12. Probabilistic evaluation of shallow groundwater resources at...

    Office of Scientific and Technical Information (OSTI)

    atmosphere. This study first develops an integrated Monte Carlo method for simulating CO2 and brine leakage from carbon sequestration and subsequent geochemical interactions in...

  13. DOE/SC0001389 Final technical report: Investigation of uranium attenuation and release at column and pore scales in response to advective geochemical gradients

    SciTech Connect (OSTI)

    Savage, Kaye S.; Zhu, Wenyi; Barnett, Mark O.

    2013-05-13

    Experimental approach Column experiments were devised to investigate the role of changing fluid composition on mobility of uranium through a sequence of geologic media. Fluids and media were chosen to be relevant to the ground water plume emanating from the former S-3 ponds at the Oak Ridge Integrated Field Research Challenge (ORIFC) site. Synthetic ground waters were pumped upwards at 0.05 mL/minute for 21 days through layers of quartz sand alternating with layers of uncontaminated soil, quartz sand mixed with illite, quartz sand coated with iron oxides, and another soil layer. Increases in pH or concentration of phosphate, bicarbonate, or acetate were imposed on the influent solutions after each 7 pore volumes while uranium (as uranyl) remained constant at 0.1mM. A control column maintained the original synthetic groundwater composition with 0.1mM U. Pore water solutions were extracted to assess U retention and release in relation to the advective ligand or pH gradients. Following the column experiments, subsamples from each layer were characterized using microbeam X-ray absorption spectroscopy (XANES) in conjunction with X-ray fluorescence mapping and compared to sediment core samples from the ORIFC, at SSRL Beam Line 2-3. Results U retention of 55 ?? 67 mg occurred in phosphate >pH >control >acetate >carbonate columns. The mass of U retained in the first-encountered quartz layer in all columns was highest and increased throughout the experiment. The rate of increase in acetate- and bicarbonate-bearing columns declined after ligand concentrations were raised. U also accumulated in the first soil layer; the pH-varied column retained most, followed by the increasing-bicarbonate column. The mass of U retained in the upper layers was far lower. Speciation of U, interpreted from microbeam XANES spectra and XRF maps, varied within and among the columns. Evidence of minor reduction to U(IV) was observed in the first-encountered quartz layer in the phosphate

  14. Nitrate Biogeochemistry and Reactive Transport in California Groundwater: LDRD Final Report

    SciTech Connect (OSTI)

    Esser, B K; Beller, H; Carle, S; Cey, B; Hudson, G B; Leif, R; LeTain, T; Moody-Bartel, C; Moore, K; McNab, W; Moran, J; Tompson, A

    2006-02-24

    Nitrate is the number one drinking water contaminant in the United States. It is pervasive in surface and groundwater systems,and its principal anthropogenic sources have increased dramatically in the last 50 years. In California alone, one third of the public drinking-water wells has been lost since 1988 and nitrate contamination is the most common reason for abandonment. Effective nitrate management in groundwater is complicated by uncertainties related to multiple point and non-point sources, hydrogeologic complexity, geochemical reactivity, and quantification of denitrification processes. In this paper, we review an integrated experimental and simulation-based framework being developed to study the fate of nitrate in a 25 km-long groundwater subbasin south of San Jose, California, a historically agricultural area now undergoing rapid urbanization with increasing demands for groundwater. The modeling approach is driven by a need to integrate new and archival data that support the hypothesis that nitrate fate and transport at the basin scale is intricately related to hydrostratigraphic complexity, variability of flow paths and groundwater residence times, microbial activity, and multiple geochemical reaction mechanisms. This study synthesizes these disparate and multi-scale data into a three-dimensional and highly resolved reactive transport modeling framework.

  15. Natural bacterial communities serve as quantitative geochemical...

    Office of Scientific and Technical Information (OSTI)

    approach to identify sites contaminated with hydrocarbons from the Deepwater Horizon oil spill, finding that altered bacterial communities encode a memory of prior...

  16. Interface Induced Carbonate Mineralization: A Fundamental Geochemical...

    Office of Scientific and Technical Information (OSTI)

    fundamental barrier, other than cation hydration, exists that prevents Mgsup 2+ and ... of water give us a first direct proof to support and quantify the cation hydration effect. ...

  17. Precipitation in Pores: A Geochemical Frontier

    SciTech Connect (OSTI)

    Stack, Andrew G.

    2015-01-01

    This article's purpose is to review some of the recent research in which geochemists have examined precipitation of solid phases in porous media, particularly in pores a few nanometers in diameter (nanopores). While this is a “review,” it is actually more forward-looking in that the list of things about this phenomenon that we do not know or cannot control at this time is likely longer than what we do know and can control. For example, there are three directly contradictory theories on how to predict how precipitation proceeds in a medium of varying pore size, as will be discussed below. The confusion on this subject likely stems from the complexity of the phenomenon itself: One can easily clog a porous medium by inducing a rapid, homogeneous precipitation directly from solution, or have limited precipitation occur that does not affect permeability or even porosity substantially. It is more difficult to engineer mineral precipitation in order to obtain a specific outcome, such as filling all available pore space over a targeted area for the purposes of contaminant sequestration. However, breakthrough discoveries could occur in the next five to ten years that enhance our ability to predict robustly and finely control precipitation in porous media by understanding how porosity and permeability evolve in response to system perturbations. These discoveries will likely stem (at least in part) from advances in our ability to 1) perform and interpret X-ray/neutron scattering experiments that reveal the extent of precipitation and its locales within porous media (Anovitz and Cole 2015, this volume), and 2) utilize increasingly powerful simulations to test concepts and models about the evolution of porosity and permeability as precipitation occurs (Steefel et al. 2015, this volume). A further important technique to isolate specific phenomena and understand reactivity is also microfluidics cell experiments that allow specific control of flow paths and fluid velocities (Yoon et al. 2012). An improved ability to synthesize idealized porous media will allow for tailored control of pore distributions, mineralogy and will allow more reproducible results. This in turn may allow us to isolate specific processes without the competing and obfuscatory effects that hinder generalization of observations when working with solely natural samples. It is likely that no one single experiment, or simulation technique will provide the key discoveries: to make substantive progress will require a collaborative effort to understand the interplay between fluid transport and geochemistry. Finally, where rock fracturing and elevated pressures are of concern, an understanding and capability to model geomechanical properties are necessary (Scherer 1999).

  18. Geochemical, Genetic, and Community Controls on Mercury

    SciTech Connect (OSTI)

    Wall, Judy D.

    2014-11-10

    The sulfate-reducing bacteria (SRB) are soil bacteria that share two common characteristics, strict anaerobiosis and the ability to respire sulfate. The metabolic activities of these bacteria play significant roles in the global sulfur cycle, anaerobic degradation of biomass, biological metal corrosion in the environment and, recently, degradation of toxic compounds. The accumulation of evidence suggests these bacteria are also key to the production of the neurotoxin methylmercury in environmental settings. We propose to use our experience with the development of genetics in sulfate-reducing bacteria of the genus Desulfovibrio to create mutations that will eliminate the methylation of mercury, thereby identifying the genes essential for this process. This information may allow the environmental monitoring of the mercury methylation potential to learn the location and quantity of the production this toxin. From these data, more accurate predictive models of mercury cycling can be generated.

  19. Precipitation in pores: A geochemical frontier

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stack, Andrew G.

    2015-07-29

    This article's purpose is to review some of the recent research in which geochemists have examined precipitation of solid phases in porous media, particularly in pores a few nanometers in diameter (nanopores). While this is a “review,” it is actually more forward-looking in that the list of things about this phenomenon that we do not know or cannot control at this time is likely longer than what we do know and can control. For example, there are three directly contradictory theories on how to predict how precipitation proceeds in a medium of varying pore size, as will be discussed below.more » The confusion on this subject likely stems from the complexity of the phenomenon itself: One can easily clog a porous medium by inducing a rapid, homogeneous precipitation directly from solution, or have limited precipitation occur that does not affect permeability or even porosity substantially. It is more difficult to engineer mineral precipitation in order to obtain a specific outcome, such as filling all available pore space over a targeted area for the purposes of contaminant sequestration. However, breakthrough discoveries could occur in the next five to ten years that enhance our ability to predict robustly and finely control precipitation in porous media by understanding how porosity and permeability evolve in response to system perturbations. These discoveries will likely stem (at least in part) from advances in our ability to 1) perform and interpret X-ray/neutron scattering experiments that reveal the extent of precipitation and its locales within porous media (Anovitz and Cole 2015, this volume), and 2) utilize increasingly powerful simulations to test concepts and models about the evolution of porosity and permeability as precipitation occurs (Steefel et al. 2015, this volume). A further important technique to isolate specific phenomena and understand reactivity is also microfluidics cell experiments that allow specific control of flow paths and fluid velocities (Yoon et al. 2012). An improved ability to synthesize idealized porous media will allow for tailored control of pore distributions, mineralogy and will allow more reproducible results. This in turn may allow us to isolate specific processes without the competing and obfuscatory effects that hinder generalization of observations when working with solely natural samples. It is likely that no one single experiment, or simulation technique will provide the key discoveries: to make substantive progress will require a collaborative effort to understand the interplay between fluid transport and geochemistry. Finally, where rock fracturing and elevated pressures are of concern, an understanding and capability to model geomechanical properties are necessary (Scherer 1999).« less

  20. Interface Induced Carbonate Mineralization: A Fundamental Geochemical...

    Office of Scientific and Technical Information (OSTI)

    Authors: Teng, H. Henry 1 ; Xu, Huifang 2 + Show Author Affiliations PI, The George Washington University PI, The George Washington University Co-PI, University of ...

  1. Interface Induced Carbonate Mineralization: A Fundamental Geochemical...

    Office of Scientific and Technical Information (OSTI)

    On the other hand, the measured higher distribution coefficients of Mg between magnesian calcites formed in the absence and presence of water give us a first direct proof to ...

  2. Natural bacterial communities serve as quantitative geochemical...

    Office of Scientific and Technical Information (OSTI)

    that respond to and capture perturbations caused by human impacts. less Authors: Smith, Mark B. 1 ; Rocha, Andrea M. 2 ; Smillie, Chris S. 1 ; Olesen, Scott W. 1 ;...

  3. Nanogeochemistry: Geochemical reactions and mass transfers in...

    Office of Scientific and Technical Information (OSTI)

    ...een-Prokaryotic-and-Eukaryotic-Cellsslide2150310 Sandia National Laboratories ... (80 m2g) in fault gouge accounting for >50% energy consumed in earthquake http:...

  4. Groundwater monitoring plan for the Hanford Site 200 Area Treated Effluent Disposal Facility

    SciTech Connect (OSTI)

    DB Barnett

    2000-05-17

    Seven years of groundwater monitoring at the 200 Area Treated Effluent Disposal Facility (TEDF) have shown that the uppermost aquifer beneath the facility is unaffected by TEDF effluent. Effluent discharges have been well below permitted and expected volumes. Groundwater mounding from TEDF operations predicted by various models has not been observed, and waterlevels in TEDF wells have continued declining with the dissipation of the nearby B Pond System groundwater mound. Analytical results for constituents with enforcement limits indicate that concentrations of all these are below Practical Quantitation Limits, and some have produced no detections. Likewise, other constituents on the permit-required list have produced results that are mostly below sitewide background. Comprehensive geochemical analyses of groundwater from TEDF wells has shown that most constituents are below background levels as calculated by two Hanford Site-wide studies. Additionally, major ion proportions and anomalously low tritium activities suggest that groundwater in the aquifer beneath the TEDF has been sequestered from influences of adjoining portions of the aquifer and any discharge activities. This inference is supported by recent hydrogeologic investigations which indicate an extremely slow rate of groundwater movement beneath the TEDF. Detailed evaluation of TEDF-area hydrogeology and groundwater geochemistry indicate that additional points of compliance for groundwater monitoring would be ineffective for this facility, and would produce ambiguous results. Therefore, the current groundwater monitoring well network is retained for continued monitoring. A quarterly frequency of sampling and analysis is continued for all three TEDF wells. The constituents list is refined to include only those parameters key to discerning subtle changes in groundwater chemistry, those useful in detecting general groundwater quality changes from upgradient sources, or those retained for comparison with end

  5. Updated Conceptual Model for the 300 Area Uranium Groundwater Plume

    SciTech Connect (OSTI)

    Zachara, John M.; Freshley, Mark D.; Last, George V.; Peterson, Robert E.; Bjornstad, Bruce N.

    2012-11-01

    The 300 Area uranium groundwater plume in the 300-FF-5 Operable Unit is residual from past discharge of nuclear fuel fabrication wastes to a number of liquid (and solid) disposal sites. The source zones in the disposal sites were remediated by excavation and backfilled to grade, but sorbed uranium remains in deeper, unexcavated vadose zone sediments. In spite of source term removal, the groundwater plume has shown remarkable persistence, with concentrations exceeding the drinking water standard over an area of approximately 1 km2. The plume resides within a coupled vadose zone, groundwater, river zone system of immense complexity and scale. Interactions between geologic structure, the hydrologic system driven by the Columbia River, groundwater-river exchange points, and the geochemistry of uranium contribute to persistence of the plume. The U.S. Department of Energy (DOE) recently completed a Remedial Investigation/Feasibility Study (RI/FS) to document characterization of the 300 Area uranium plume and plan for beginning to implement proposed remedial actions. As part of the RI/FS document, a conceptual model was developed that integrates knowledge of the hydrogeologic and geochemical properties of the 300 Area and controlling processes to yield an understanding of how the system behaves and the variables that control it. Recent results from the Hanford Integrated Field Research Challenge site and the Subsurface Biogeochemistry Scientific Focus Area Project funded by the DOE Office of Science were used to update the conceptual model and provide an assessment of key factors controlling plume persistence.

  6. Y-12 Groundwater Protection Program Groundwater Monitoring Data Compendium, Revision 1

    SciTech Connect (OSTI)

    2006-12-01

    This document is a compendium of water quality and hydrologic characterization data obtained through December 2005 from the network of groundwater monitoring wells and surface water sampling stations (including springs and building sumps) at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) in Oak Ridge, Tennessee that have been sampled since January 2003. The primary objectives of this document, hereafter referenced as the Y-12 Groundwater Protection Program (GWPP) Compendium, are to: (1) Serve as a single-source reference for monitoring data that meet the requirements of the Y-12 GWPP, as defined in the Y-12 GWPP Management Plan (BWXT Y-12 L.L.C. [BWXT] 2004); (2) Maintain a detailed analysis and evaluation of the monitoring data for each applicable well, spring, and surface water sampling station, with a focus on results for the primary inorganic, organic, and radiological contaminants in groundwater and surface water at Y-12; and (3) Ensure retention of ''institutional knowledge'' obtained over the long-term (>20-year) history of groundwater and surface water monitoring at Y-12 and the related sources of groundwater and surface water contamination. To achieve these goals, the Y-12 GWPP Compendium brings together salient hydrologic, geologic, geochemical, water-quality, and environmental compliance information that is otherwise disseminated throughout numerous technical documents and reports prepared in support of completed and ongoing environmental contamination assessment, remediation, and monitoring activities performed at Y-12. The following subsections provide background information regarding the overall scope and format of the Y-12 GWPP Compendium and the planned approach for distribution and revision (i.e., administration) of this ''living'' document.

  7. Soil Sampling At Reese River Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    References William R. Henkle Jr., Wayne C. Gundersen, Thomas D. Gundersen (2005) Mercury Geochemical, Groundwater Geochemical, And Radiometric Geophysical Signatures At Three...

  8. Radiometrics At Reese River Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    References William R. Henkle Jr., Wayne C. Gundersen, Thomas D. Gundersen (2005) Mercury Geochemical, Groundwater Geochemical, And Radiometric Geophysical Signatures At Three...

  9. Soil Sampling At Silver Peak Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    References William R. Henkle Jr., Wayne C. Gundersen, Thomas D. Gundersen (2005) Mercury Geochemical, Groundwater Geochemical, And Radiometric Geophysical Signatures At Three...

  10. Field Mapping At Silver Peak Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    References William R. Henkle Jr., Wayne C. Gundersen, Thomas D. Gundersen (2005) Mercury Geochemical, Groundwater Geochemical, And Radiometric Geophysical Signatures At Three...

  11. Field Mapping At Reese River Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    References William R. Henkle Jr., Wayne C. Gundersen, Thomas D. Gundersen (2005) Mercury Geochemical, Groundwater Geochemical, And Radiometric Geophysical Signatures At Three...

  12. Radiometrics At Silver Peak Area (Henkle, Et Al., 2005) | Open...

    Open Energy Info (EERE)

    References William R. Henkle Jr., Wayne C. Gundersen, Thomas D. Gundersen (2005) Mercury Geochemical, Groundwater Geochemical, And Radiometric Geophysical Signatures At Three...

  13. A User’s Guide to the Comprehensive Water Quality Database for Groundwater in the Vicinity of the Nevada Test Site, Rev. No.: 1

    SciTech Connect (OSTI)

    Farnham, Irene

    2006-09-01

    This water quality database (viz.GeochemXX.mdb) has been developed as part of the Underground Test Area (UGTA) Program with the cooperation of several agencies actively participating in ongoing evaluation and characterization activities under contract to the U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Site Office (NNSA/NSO). The database has been constructed to provide up-to-date, comprehensive, and quality controlled data in a uniform format for the support of current and future projects. This database provides a valuable tool for geochemical and hydrogeologic evaluations of the Nevada Test Site (NTS) and surrounding region. Chemistry data have been compiled for groundwater within the NTS and the surrounding region. These data include major ions, organic compounds, trace elements, radionuclides, various field parameters, and environmental isotopes. Colloid data are also included in the database. The GeochemXX.mdb database is distributed on an annual basis. The extension ''XX'' within the database title is replaced by the last two digits of the release year (e.g., Geochem06 for the version released during the 2006 fiscal year). The database is distributed via compact disc (CD) and is also uploaded to the Common Data Repository (CDR) in order to make it available to all agencies with DOE intranet access. This report provides an explanation of the database configuration and summarizes the general content and utility of the individual data tables. In addition to describing the data, subsequent sections of this report provide the data user with an explanation of the quality assurance/quality control (QA/QC) protocols for this database.

  14. Rare earth elements in chloride-rich groundwater, Palo Duro Basin, Texas, USA

    SciTech Connect (OSTI)

    Gosselin, D.C. ); Smith, M.R.; Lepel, E.A. ); Laul, J.C. )

    1992-04-01

    Rare earth element (REE) data for groundwater samples from the Deep-Basin Brine aquifer of the Palo Duro Basin, Texas, USA, illustrates the potential use of REE for inferring groundwater flow paths through different geologic materials. The REE content of the groundwaters range over 2.5 orders of magnitude and are depleted by 10{sup 2} to 10{sup 5} relative to aquifer materials. The shale-normalized REE patterns for groundwater that have primarily interacted with arkosic sandstones (granite wash) are flat with similar heavy REE (HREE) enrichments ((Lu/La){sub n} = 0.60 to 0.80). The samples with highest REE contents and REE patterns, which are enriched in the intermediate REEs (IREEs; Sm-Tb) reflect variable degrees of interaction with carbonate rocks. The IREE enrichment is the result of fluid interaction with Fe-Mn coatings on carbonate minerals and/or secondary minerals in fractures and vugs. The chloride complex. (LnCl{sup 2+}), and free-ions are the predominant REE species, accounting for over 95% of the REEs. Carbonate and sulfate species account for the other 5% and have very little influence on the behavior of the REEs. Although this study indicates a potentially important role for the REEs in understanding geochemical transport and groundwater movement, it also indicates the necessity for developing a better understanding of REE speciation in high ionic strength solutions.

  15. Compilation of data to estimate groundwater migration potential for constituents in active liquid discharges at the Hanford Site

    SciTech Connect (OSTI)

    Ames, L.L.; Serne, R.J.

    1991-03-01

    A preliminary characterization of the constituents present in the 33 liquid waste streams at the US Department of Energy's Hanford Site has been completed by Westinghouse Hanford Company. In addition, Westinghouse Hanford has summarized the soil characteristics based on drill logs collected at each site that receives these liquid wastes. Literature searches were conducted and available Hanford-specific data were tabulated and reviewed. General literature on organic chemicals present in the liquid waste streams was also reviewed. Using all of this information, Pacific Northwest Laboratory has developed a best estimate of the transport characteristics (water solubility and soil adsorption properties) for those radionuclides and inorganic and organic chemicals identified in the various waste streams. We assume that the potential for transport is qualified through the four geochemical parameters: solubility, distribution coefficient, persistence (radiogenic or biochemical half-life), and volatility. Summary tables of these parameters are presented for more than 50 inorganic and radioactive species and more than 50 organic compounds identified in the liquid waste streams. Brief descriptions of the chemical characteristics of Hanford sediments, solubility, and adsorption processes, and of how geochemical parameters are used to estimate migration in groundwater-sediment environments are also presented. Groundwater monitoring data are tabulated for wells neighboring the facilities that receive the liquid wastes. 91 refs., 16 figs., 23 tabs.

  16. Independent technical evaluation and recommendations for contaminated groundwater at the department of energy office of legacy management Riverton processing site

    SciTech Connect (OSTI)

    Looney, Brain B.; Denham, Miles E.; Eddy-Dilek, Carol A.

    2014-04-01

    The U.S. Department of Energy Office of Legacy Management (DOE-LM) manages the legacy contamination at the Riverton, WY, Processing Site – a former uranium milling site that operated from 1958 to 1963. The tailings and associated materials were removed in 1988-1989 and contaminants are currently flushing from the groundwater. DOE-LM commissioned an independent technical team to assess the status of the contaminant flushing, identify any issues or opportunities for DOE-LM, and provide key recommendations. The team applied a range of technical frameworks – spatial, temporal, hydrological and geochemical – in performing the evaluation. In each topic area, an in depth evaluation was performed using DOE-LM site data (e.g., chemical measurements in groundwater, surface water and soil, water levels, and historical records) along with information collected during the December 2013 site visit (e.g., plant type survey, geomorphology, and minerals that were observed, collected and evaluated).

  17. Research Project on CO2 Geological Storage and Groundwater Resources: Water Quality Effects Caused by CO2 Intrusion into Shallow Groundwater

    SciTech Connect (OSTI)

    Birkholzer, Jens; Apps, John; Zheng, Liange; Zhang, Yingqi; Xu, Tianfu; Tsang, Chin-Fu

    2008-10-01

    One promising approach to reduce greenhouse gas emissions is injecting CO{sub 2} into suitable geologic formations, typically depleted oil/gas reservoirs or saline formations at depth larger than 800 m. Proper site selection and management of CO{sub 2} storage projects will ensure that the risks to human health and the environment are low. However, a risk remains that CO{sub 2} could migrate from a deep storage formation, e.g. via local high-permeability pathways such as permeable faults or degraded wells, and arrive in shallow groundwater resources. The ingress of CO{sub 2} is by itself not typically a concern to the water quality of an underground source of drinking water (USDW), but it will change the geochemical conditions in the aquifer and will cause secondary effects mainly induced by changes in pH, in particular the mobilization of hazardous inorganic constituents present in the aquifer minerals. Identification and assessment of these potential effects is necessary to analyze risks associated with geologic sequestration of CO{sub 2}. This report describes a systematic evaluation of the possible water quality changes in response to CO{sub 2} intrusion into aquifers currently used as sources of potable water in the United States. Our goal was to develop a general understanding of the potential vulnerability of United States potable groundwater resources in the event of CO{sub 2} leakage. This goal was achieved in two main tasks, the first to develop a comprehensive geochemical model representing typical conditions in many freshwater aquifers (Section 3), the second to conduct a systematic reactive-transport modeling study to quantify the effect of CO{sub 2} intrusion into shallow aquifers (Section 4). Via reactive-transport modeling, the amount of hazardous constituents potentially mobilized by the ingress of CO{sub 2} was determined, the fate and migration of these constituents in the groundwater was predicted, and the likelihood that drinking water

  18. Reduced order models for prediction of groundwater quality impacts from CO₂ and brine leakage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Liange; Carroll, Susan; Bianchi, Marco; Mansoor, Kayyum; Sun, Yunwei; Birkholzer, Jens

    2014-12-31

    A careful assessment of the risk associated with geologic CO₂ storage is critical to the deployment of large-scale storage projects. A potential risk is the deterioration of groundwater quality caused by the leakage of CO₂ and brine leakage from deep subsurface reservoirs. In probabilistic risk assessment studies, numerical modeling is the primary tool employed to assess risk. However, the application of traditional numerical models to fully evaluate the impact of CO₂ leakage on groundwater can be computationally complex, demanding large processing times and resources, and involving large uncertainties. As an alternative, reduced order models (ROMs) can be used as highlymore » efficient surrogates for the complex process-based numerical models. In this study, we represent the complex hydrogeological and geochemical conditions in a heterogeneous aquifer and subsequent risk by developing and using two separate ROMs. The first ROM is derived from a model that accounts for the heterogeneous flow and transport conditions in the presence of complex leakage functions for CO₂ and brine. The second ROM is obtained from models that feature similar, but simplified flow and transport conditions, and allow for a more complex representation of all relevant geochemical reactions. To quantify possible impacts to groundwater aquifers, the basic risk metric is taken as the aquifer volume in which the water quality of the aquifer may be affected by an underlying CO₂ storage project. The integration of the two ROMs provides an estimate of the impacted aquifer volume taking into account uncertainties in flow, transport and chemical conditions. These two ROMs can be linked in a comprehensive system level model for quantitative risk assessment of the deep storage reservoir, wellbore leakage, and shallow aquifer impacts to assess the collective risk of CO₂ storage projects.« less

  19. Reduced order models for prediction of groundwater quality impacts from CO? and brine leakage

    SciTech Connect (OSTI)

    Zheng, Liange; Carroll, Susan; Bianchi, Marco; Mansoor, Kayyum; Sun, Yunwei; Birkholzer, Jens

    2014-12-31

    A careful assessment of the risk associated with geologic CO? storage is critical to the deployment of large-scale storage projects. A potential risk is the deterioration of groundwater quality caused by the leakage of CO? and brine leakage from deep subsurface reservoirs. In probabilistic risk assessment studies, numerical modeling is the primary tool employed to assess risk. However, the application of traditional numerical models to fully evaluate the impact of CO? leakage on groundwater can be computationally complex, demanding large processing times and resources, and involving large uncertainties. As an alternative, reduced order models (ROMs) can be used as highly efficient surrogates for the complex process-based numerical models. In this study, we represent the complex hydrogeological and geochemical conditions in a heterogeneous aquifer and subsequent risk by developing and using two separate ROMs. The first ROM is derived from a model that accounts for the heterogeneous flow and transport conditions in the presence of complex leakage functions for CO? and brine. The second ROM is obtained from models that feature similar, but simplified flow and transport conditions, and allow for a more complex representation of all relevant geochemical reactions. To quantify possible impacts to groundwater aquifers, the basic risk metric is taken as the aquifer volume in which the water quality of the aquifer may be affected by an underlying CO? storage project. The integration of the two ROMs provides an estimate of the impacted aquifer volume taking into account uncertainties in flow, transport and chemical conditions. These two ROMs can be linked in a comprehensive system level model for quantitative risk assessment of the deep storage reservoir, wellbore leakage, and shallow aquifer impacts to assess the collective risk of CO? storage projects.

  20. Ground-water geochemistry and radionuclide activity in the Cambrian-Ordovician aquifer of Dodge and Fond du Lac counties, Wisconsin. Technical report

    SciTech Connect (OSTI)

    Weaver, T.R.; Bahr, J.M.; Anderson, M.P.

    1990-01-01

    Analyses of groundwater from wells in the Cambrian-Ordovician aquifer of eastern Wisconsin indicate that regions of the aquifer contain elevated concentrations of dissolved solids, chloride and sulfate. Groundwater from several wells in the area also approach or exceed the current drinking water standard for combined radium activity. Significant changes in groundwater chemistry occur where the aquifer becomes confined by the Maquoketa shale. Concentrations of Cl(-), SO4(2-) and Na(+) increase in the confined region, and the highest combined radium activities are typically observed in the area. Geochemical modeling implies that the observed changes in major ion groundwater chemistry occur in response to the presence of the confining unit which may act as a source of SO4(2-), through gypsum dissolution, and Na(+), through cation exchange. A finite difference groundwater flow model was linked to a particle tracking routine to determine groundwater flow paths and residence times in the aquifer near the boundary between unconfined and confined conditions. Results suggest that the presence of the confining unit produces a vertically stratified flow regime in the confined region.

  1. Chemical and isotopic data for groundwater in southern Nevada

    SciTech Connect (OSTI)

    Rose, T. P., LLNL

    1997-07-01

    This document presents a compilation of chemical and isotopic data for groundwater samples analyzed by Lawrence Livermore National Laboratory (LLNL) in support of the Hydrology and Radionuclide Migration Program (HRMP) and the Underground Test Area Program (UGTA) for the U.S. Department of Energy, Nevada Operations Office. Included are data for 107 samples collected from wells and springs located on and around the Nevada Test Site (NTS), within an area approximately bounded by latitudes 36{sup o} to 38{sup o}15'N and longitudes 115{sup o} to 117{sup o}15'W. The samples were collected during the time period 1992 to early 1997. The data represents one of the largest internally consistent geochemical data sets to be gathered for groundwater in southern Nevada. This database is available in electronic or hardcopy formats to interested parties upon request. In addition to the LLNL data we have included a table of selected isotopic data summarized from a larger database compiled by GeoTrans, Inc. (1994). This data is included for comparative purposes as a means of placing the LLNL data in the context of other data for the same geographic region.

  2. Estimating the spatio-temporal distribution of geochemical parameters...

    Office of Scientific and Technical Information (OSTI)

    Authors: Chen, J. ; Hubbard, S. S. ; Williams, K. H. ; Orozco, A. Flores ; Kemna, A. Publication Date: 2012-06-20 OSTI Identifier: 1212432 Report Number(s): LBNL-5663E Journal ID: ...

  3. Geochemical Impacts of Carbon Dioxide, Brine, Trace Metal and...

    Office of Scientific and Technical Information (OSTI)

    Peer-review under responsibility of the Organizing Committee of GHGT-12 doi: 10.1016j.egy... + ajkXjXj + ai>i,kXi2, where i 1,22 and jl,22 and k 1,37 The goodness-of-fit (R2) ...

  4. Hydrological, geochemical, and ecological characterization of Kesterson Reservoir

    SciTech Connect (OSTI)

    Not Available

    1990-06-01

    This report describes Kesterson Reservoir related research activities carried out under a cooperative program between Lawrence Berkeley Laboratory and the Division of Agriculture and Natural Resources at the University of California during FY89. The primary objectives of these investigations are: Predict the extent, probability of the occurrence, and selenium concentrations in surface water of temporary wetland habitat at Kesterson; assess rates and direction of migration of the drainage water plume that seeped into the aquifer under Kesterson; monitor and predict changes in quantity and speciation of selenium in surface soils and vadose zone pore-waters; and develop a comprehensive strategy through soil, water, and vegetation management to safely dissipate the high concentrations of selenium accumulated in Kesterson soils. This report provides an up-date on progress made in each of these areas. Chapter 2 describes results of recent investigations of water table fluctuations and plume migration. Chapter 3 describes results of ongoing monitoring of soil water selenium concentrations and evaporative accumulation of selenium at the soil surface. Chapter 4 describes early results from the soil, water, and vegetation management field trials as well as supporting laboratory and theoretical studies. In Chapter 5, new analytical methods for selenium speciation are described and quality assurance/quality control statistics for selenium and boron are provided. 110 refs., 138 figs., 62 tabs.

  5. SubTER Grand Challenge Roundtable: Imaging Geophysical and Geochemical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PDF icon Grand Challenge Workshop -Imaging Subsurface.pdf More Documents & Publications AGU SubTER Town Hall Presentation 2015 SubTER Fact Sheet SubTER Presentation at Town Hall - ...

  6. Hydrologic and Geochemical Monitoring in Long Valley Caldera...

    Open Energy Info (EERE)

    composition of water from selected stream sites, springs, and wells; pumpage from four geothermal wells; flow rates of selected springs and stream sites; mean daily water or gas...

  7. GEOCHEMICAL TESTING AND MODEL DEVELOPMENT - RESIDUAL TANK WASTE TEST PLAN

    SciTech Connect (OSTI)

    CANTRELL KJ; CONNELLY MP

    2010-03-09

    This Test Plan describes the testing and chemical analyses release rate studies on tank residual samples collected following the retrieval of waste from the tank. This work will provide the data required to develop a contaminant release model for the tank residuals from both sludge and salt cake single-shell tanks. The data are intended for use in the long-term performance assessment and conceptual model development.

  8. Hydrologic and Geochemical Monitoring in Long Valley Caldera...

    Open Energy Info (EERE)

    through 1985. The monitoring included the collection of the following types of data: chemical and isotopic composition of waters and gases from springs, wells, and steam vents;...

  9. Spatial And Temporal Geochemical Trends In The Hydrothermal System...

    Open Energy Info (EERE)

    tracking changes in river solute flux. Authors Shaul Hurwitz, Jacob B. Lowenstern and Henry Heasler Published Journal Journal of Volcanology and Geothermal Research, 2007 DOI Not...

  10. Trace Element Geochemical Zoning in the Roosevelt Hot Springs...

    Open Energy Info (EERE)

    this distribution may be a useful solid geothermometer. Authors O.D. Christensen, J.N. Moore and R.M. Capuano Conference GRC Annual Meeting; Salt Lake City, UT; 09091980...

  11. Coffinitization of Uraninite: SEM/AEM Investigation and Geochemical...

    Office of Scientific and Technical Information (OSTI)

    Scanning electron microscopy (SEM) and analytical electron microscopy (AEM) studies have been conducted on a uraninite sample from a U-deposit in Canada. It is observed that the ...

  12. Geochemical characterization of geothermal systems in the Great...

    Open Energy Info (EERE)

    Basin. Development of this database is one of the first steps in understanding the nature of geothermal systems in the Great Basin. Of particular importance in the Great Basin...

  13. Developing a robust geochemical and reactive transport model...

    Office of Scientific and Technical Information (OSTI)

    Migration of carbon dioxide (COsub 2) from deep storage formations into shallow drinking ... LEAKS; LEVELS; MATERIALS; METALS; MIGRATION; MINERALS; MOBILITY; OXIDES; ...

  14. Estimating the spatio-temporal distribution of geochemical parameters...

    Office of Scientific and Technical Information (OSTI)

    biostimulation using spectral induced polarization data and hierarchical Bayesian models ... biostimulation using spectral induced polarization data and hierarchical Bayesian models ...

  15. A Reconnaissance Geochemical Study Of La Primavera Geothermal...

    Open Energy Info (EERE)

    whereas the water-rich fumaroles are high and central. The Comision Federal de Electricidad de Mexico (CFE) has recently drilled two deep holes at the center of the Sierra...

  16. A Geochemical Reconnaissance Of The Alid Volcaniccenter And Geothermal...

    Open Energy Info (EERE)

    Robert O. Fournier, Theoderos Tesfai, Wendell A. Duffield, Michael A. Clynne, James G. Smith, Leake Woldegiorgis, Kidane Weldemariam and Gabreab Kahsai Published Journal...

  17. Geochemical Sampling of Thermal Waters in Nevada | Open Energy...

    Open Energy Info (EERE)

    Area (136C), Buffalo Valley (130C), Pumpernickel Valley (Tipton Ranch; 125C), and Smith Creek Valley (119C). Authors Lisa Shevenell and Larry Garside Conference GRC Annual...

  18. Geochemical modeling of the Raft River geothermal field | Open...

    Open Energy Info (EERE)

    and additional work needed to refine the overall reservoir model. Authors Overton, H. L.; Chaney, R. E.; Mcatee, R. E.; Graham and D. L. Published DOE Information Bridge, 111...

  19. Alteration And Geochemical Zoning In Bodie Bluff, Bodie Mining...

    Open Energy Info (EERE)

    Banded, epithermal quartz-adularia veins have produced about 1.5 million ounces of gold and 7 million ounces of silver from the Bodie mining district, eastern California. The...

  20. Reactive geochemical transport simulation to study mineral trapping...

    Office of Scientific and Technical Information (OSTI)

    ... Authors: Xu, Tianfu ; Apps, John A. ; Pruess, Karsten Publication Date: 2002-04-01 OSTI Identifier: 801952 Report Number(s): LBNL--50089 R&D Project: 468111; B& R KC0403010; TRN: ...

  1. Factors Controlling The Geochemical Evolution Of Fumarolic Encrustatio...

    Open Energy Info (EERE)

    Smokes (VTTS). The six-factor solution model explains a large proportion (low of 74% for Ni to high of 99% for Si) of the individual element data variance. Although the primary...

  2. Hg Anomalies In Soils- A Geochemical Exploration Method For Geothermal...

    Open Energy Info (EERE)

    is not possible. Hg anomaly patterns yield information on the presence as well as the geometry of shallow geothermal circulation patterns. In conjunction with structural geologic...

  3. Lattice gas automata for flow and transport in geochemical systems

    SciTech Connect (OSTI)

    Janecky, D.R.; Chen, S.; Dawson, S.; Eggert, K.C.; Travis, B.J.

    1992-05-01

    Lattice gas automata models are described, which couple solute transport with chemical reactions at mineral surfaces within pore networks. Diffusion in a box calculations are illustrated, which compare directly with Fickian diffusion. Chemical reactions at solid surfaces, including precipitation/dissolution, sorption, and catalytic reaction, can be examined with the model because hydrodynamic transport, solute diffusion and mineral surface processes are all treated explicitly. The simplicity and flexibility of the approach provides the ability to study the interrelationship between fluid flow and chemical reactions in porous materials, at a level of complexity that has not previously been computationally possible.

  4. Lattice gas automata for flow and transport in geochemical systems

    SciTech Connect (OSTI)

    Janecky, D.R.; Chen, S.; Dawson, S.; Eggert, K.C.; Travis, B.J.

    1992-01-01

    Lattice gas automata models are described, which couple solute transport with chemical reactions at mineral surfaces within pore networks. Diffusion in a box calculations are illustrated, which compare directly with Fickian diffusion. Chemical reactions at solid surfaces, including precipitation/dissolution, sorption, and catalytic reaction, can be examined with the model because hydrodynamic transport, solute diffusion and mineral surface processes are all treated explicitly. The simplicity and flexibility of the approach provides the ability to study the interrelationship between fluid flow and chemical reactions in porous materials, at a level of complexity that has not previously been computationally possible.

  5. Merging High Resolution Geophysical and Geochemical Surveys to...

    Open Energy Info (EERE)

    and in combination when exploring for blind resources where structure, permeability, and temperature are the most pressing questions. The slim holes will allow testing...

  6. Temporal Geochemical Variations In Volatile Emissions From Mount...

    Open Energy Info (EERE)

    1980. Based on D modeling, approximately 63% of shallow, post-1980 magma has yet to degas. Surprisingly, Cl and F contents in the 1994 samples were only 0.47 and 3.8%,...

  7. Hydrological and geochemical investigations of selenium behavior at Kesterson Reservoir

    SciTech Connect (OSTI)

    Zawislanski, P.T.; Tokunaga, T.K.; Benson, S.M.

    1995-05-01

    This report describes research relevant to selenium specification, fractionation, physical redistribution, reduction and oxidation, and spatial distribution as related to Kesterson Reservoir. The work was carried out by scientists and engineers from the Earth Sciences Division of the Lawrence Berkeley Laboratory over a two year period from October 1992 to September 1994. Much of the focus of these efforts was on the effects of two above-average rainfall years (1991/1992 and 1992/1993). These events marked a departure from the previous six years of drought conditions, under which oxidation of Se in the soil profile led to a marked increase in soluble Se. Evidence from the last two years show that much of the re-oxidized Se was once more reduced due to increased soil moisture content. Also, in areas of high hydraulic conductivity, major vertical displacement of selenium and other solutes due to rainfall infiltration was observed. Such observations underscore the dependence of the future of Se speciation and distribution on environmental conditions.

  8. Self-Organized Pattern Formation in Sedimentary Geochemical Systems...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Word Cloud More Like This Full Text Books Please see Document Availability for additional information on obtaining the ...

  9. Hydrologic and Geochemical Monitoring in Long Valley Caldera...

    Open Energy Info (EERE)

    Differences since 1982 in fluid chemistry of springs has been minor except at Casa Diablo, where rapid fluctuations in chemistry result from near surface boiling and...

  10. Property:GeochemReservoirTemp | Open Energy Information

    Open Energy Info (EERE)

    pages using this property. C Chena Geothermal Area + 383.15 K110 C 230 F 689.67 R + F Fenton Hill HDR Geothermal Area + 505.15 K232 C 449.6 F 909.27 R + L Lightning...

  11. Geochemical Data for 95 Thermal and Nonthermal Waters of the...

    Open Energy Info (EERE)

    hydrothermal alterations, and hydrothermal solution chemistry. Authors Fraser E. Goff, Tamsin McCormick, Pat E. Trujillo Jr, Dale A. Counce and Charles O. Grigsby Published...

  12. A Geochemical Model Of The Platanares Geothermal System, Honduras...

    Open Energy Info (EERE)

    concentrations reflect mixed cooling paths. Authors C. J. Janik, A. H. Truesdell, F. Goff, L. Shevenell, M. L. Stallard, P. E. Trujillo Jr and D. Counce Published Journal...

  13. An evaluation of groundwater travel times in the Wolfcamp Formation using the CFEST-INV stochastic hydrology library

    SciTech Connect (OSTI)

    Not Available

    1987-03-01

    Performance assessments of a nuclear waste repository must consider the hydrologic, thermal, mechanical, and geochemical environments of a candidate site. Predictions of radionuclide transport requires estimating water movement as a function of pressure, temperature, and solute concentration. CFEST (Coupled Fluid, Energy, and Solute Transport, Gupta et al., 1987) is a finite-element based groundwater code that can be used to simultaneously solve the partial differential equations for pressure heads, solute temperature, and solute concentration. The CFEST code has been designed to support site, repository, and waste package subsystem assessments. CFEST-INV is a stochastic hydrology software library that was developed to augment the CFEST technology in data processing; model calibration; performance prediction; error propagation; and data collection guidance. 18 refs., 9 figs., 4 tabs.

  14. Groundwater Monitoring

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Groundwater Monitoring Groundwater Monitoring LANL maintains an extensive groundwater monitoring and surveillance program through sampling. August 1, 2013 Conceptual model of water movement and geology at Los Alamos National Laboratory Conceptual model of water movement and geology at Los Alamos National Laboratory RELATED IMAGES http://farm4.staticflickr.com/3749/9827580556_473a91fd78_t.jpg Enlarge

  15. River stage influences on uranium transport in a hydrologically dynamic groundwater-surface water transition zone

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zachara, John M.; Chen, Xingyuan; Murray, Chris; Hammond, Glenn

    2016-03-04

    A well-field within a uranium (U) plume in the groundwater-surface water transition zone was monitored for a 3 year period for water table elevation and dissolved solutes. The plume discharges to the Columbia River, which displays a dramatic spring stage surge resulting from snowmelt. Groundwater exhibits a low hydrologic gradient and chemical differences with river water. River water intrudes the site in spring. Specific aims were to assess the impacts of river intrusion on dissolved uranium (Uaq), specific conductance (SpC), and other solutes, and to discriminate between transport, geochemical, and source term heterogeneity effects. As a result of water tablemore » elevation fluctuations, river water intrusion, and changes in groundwater flow directions, time series trends for Uaq and SpC were found to be complex and displayed large temporal and well-to-well variability. The wells were clustered into subsets exhibiting common behaviors resulting from the intrusion dynamics of river water and the location of source terms. Hot-spots in Uaq varied in location with increasing water table elevation through the combined effects of advection and source term location. Heuristic reactive transport modeling with PFLOTRAN demonstrated that mobilized Uaq was transported between wells and source terms in complex trajectories, and was diluted as river water entered and exited the groundwater system. Moreover, while Uaq time-series concentration trends varied significantly from year-to-year as a result of climate-caused differences in the spring hydrograph, common and partly predictable response patterns were observed that were driven by water table elevation, and the extent and duration of river water intrusion.« less

  16. River stage influences on uranium transport in a hydrologically dynamic groundwater-surface water transition zone

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zachara, John M.; Chen, Xingyuan; Murray, Chris; Hammond, Glenn

    2016-03-04

    In this study, a well-field within a uranium (U) plume in the groundwater-surface water transition zone was monitored for a 3 year period for water table elevation and dissolved solutes. The plume discharges to the Columbia River, which displays a dramatic spring stage surge resulting from snowmelt. Groundwater exhibits a low hydrologic gradient and chemical differences with river water. River water intrudes the site in spring. Specific aims were to assess the impacts of river intrusion on dissolved uranium (Uaq), specific conductance (SpC), and other solutes, and to discriminate between transport, geochemical, and source term heterogeneity effects. Time series trendsmore » for Uaq and SpC were complex and displayed large temporal and well-to-well variability as a result of water table elevation fluctuations, river water intrusion, and changes in groundwater flow directions. The wells were clustered into subsets exhibiting common behaviors resulting from the intrusion dynamics of river water and the location of source terms. Hot-spots in Uaq varied in location with increasing water table elevation through the combined effects of advection and source term location. Heuristic reactive transport modeling with PFLOTRAN demonstrated that mobilized Uaq was transported between wells and source terms in complex trajectories, and was diluted as river water entered and exited the groundwater system. While Uaq time-series concentration trends varied significantly from year-to-year as a result of climate-caused differences in the spring hydrograph, common and partly predictable response patterns were observed that were driven by water table elevation, and the extent and duration of river water intrusion.« less

  17. Iodine-129 and Iodine-127 speciation in groundwater at the Hanford Site, U.S.: iodate incorporation into calcite

    SciTech Connect (OSTI)

    Zhang, Saijin; Xu, Chen; Creeley, Danielle; Ho, Yi-Fang; Li, Hsiu-Ping; Grandbois, Russell; Schwehr, Kathy; Kaplan, Daniel I.; Yeager, Chris; Wellman, Dawn M.; Santschi, Peter H.

    2013-09-03

    The Hanford Site, the most contaminated nuclear site in the United States, has large radioactive waste plumes containing high 129I levels. The geochemical transport and fate of radioiodine depends largely on its chemical speciation that is greatly affected by environmental factors. This study reports, for the first time, the speciation of stable and radioactive iodine in the groundwater from the Hanford Site. Iodate was the dominant species and accounts for up to 84%, followed by organo-iodine and minimal levels of iodide. The relatively high pH and oxidizing environment may have prevented iodate reduction. Our results identified that calcite precipitation caused by degassing of CO2 during deep groundwater sampling incorporated between 7 to 40% of dissolved iodine (including 127I and 129I) that was originally in the groundwater, transforming dissolved to particulate iodate during sampling. In order to understand the mechanisms underlying iodine incorporation by calcite, laboratory experiments were carried out to replicate this iodine sequestering processes. Two methods were utilized in this study, 1) addition of sodium carbonate; 2) addition of calcium chloride followed by sodium carbonate where the pH was well controlled at ~8.2, which is close to the average pH of Hanford Site groundwater. It was demonstrated that iodate was the main species incorporated into calcite and this incorporation process could be impeded by elevated pH and decreasing ionic strength in groundwater. This study provides critical information for predicting the long-term fate and transport of 129I at the Hanford Site and reveals a potential means for improved remediation strategies of 129I.

  18. Effects of common groundwater ions on chromate removal by magnetite: Importance of chromate adsorption

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meena, Amanda H.; Arai, Yuji

    2016-04-29

    Reductive precipitation of hexavalent chromium (Cr(VI)) with magnetite is a well-known Cr(VI) remediation method to improve water quality. The rapid (< a few hr) reduction of soluble Cr(VI) to insoluble Cr(III) species by Fe(II) in magnetite has been the primary focus of the Cr(VI) removal process in the past. However, the contribution of simultaneous Cr(VI) adsorption processes in aged magnetite has been largely ignored, leaving uncertainties in evaluating the application of in situ Cr remediation technologies for aqueous systems. In this study, effects of common groundwater ions (i.e., nitrate and sulfate) on Cr(VI) sorption to magnetite were investigated using batchmore » geochemical experiments in conjunction with X-ray absorption spectroscopy. As a result, in both nitrate and sulfate electrolytes, batch sorption experiments showed that Cr(VI) sorption decreases with increasing pH from 4 to 8. In this pH range, Cr(VI) sorption decreased with increasing ionic strength of sulfate from 0.01 to 0.1 M whereas nitrate concentrations did not alter the Cr(VI) sorption behavior. This indicates the background electrolyte specific Cr(VI) sorption process in magnetite. Under the same ionic strength, Cr(VI) removal in sulfate containing solutions was greater than that in nitrate solutions. This is because the oxidation of Fe(II) by nitrate is more thermodynamically favorable than by sulfate, leaving less reduction capacity of magnetite to reduce Cr(VI) in the nitrate media. X-ray absorption spectroscopy analysis supports the macroscopic evidence that more than 75 % of total Cr on the magnetite surfaces was adsorbed Cr(VI) species after 48 h. In conclusion, this experimental geochemical study showed that the adsorption process of Cr(VI) anions was as important as the reductive precipitation of Cr(III) in describing the removal of Cr(VI) by magnetite, and these interfacial adsorption processes could be impacted by common groundwater ions like sulfate and nitrate. The

  19. Final Project Report, DE-SC0001280, Characterizing the Combined Roles of Iron and Transverse Mixing on Uranium Bioremediation in Groundwater using Microfluidic Devices

    SciTech Connect (OSTI)

    Finneran, Kevin; Werth, Charles; Strathmann, Timothy

    2015-01-10

    In situ bioremediation of U(VI) involves amending groundwater with an appropriate electron donor and limiting nutrients to promote biological reduction to the less soluble and mobile U(IV) oxidation state. Groundwater flow is laminar; mixing is controlled by hydrodynamic dispersion. Recent studies indicate that transverse dispersion along plume margins can limit mixing of the amended electron donor and accepter (such as U(VI) in remediation applications). As a result, microbial growth, and subsequently contaminant reaction, may be limited to these transverse mixing zones during bioremediation. The primary objective of this work was to characterize the combined effects of hydrology, geochemistry, and biology on the (bio)remediation of U(VI). Our underlying hypothesis was that U(VI) reaction in groundwater is controlled by transverse mixing with an electron donor along plume margins, and that iron bioavailability in these zones affects U(VI) reduction kinetics and U(IV) re-oxidation. Our specific objectives were to a) quantify reaction kinetics mediated by biological versus geochemical reactions leading to U(VI) reduction and U(IV) re-oxidation, b) understand the influence of bioavailable iron on U(VI) reduction and U(IV) re-oxidation along the transverse mixing zones, c) determine how transverse mixing limitations and the presence of biomass in pores affects these reactions, and d) identify how microbial populations that develop along transverse mixing zones are influenced by the presence of iron and the concentration of electron donor. In the completed work, transverse mixing zones along plume margins were re-created in microfluidic pore networks, referred to as micromodels. We conducted a series of experiments that allowed us to distinguish among the hydraulic, biological, and geochemical mechanisms that contribute to U(VI) reduction, U(IV) re-oxidation, and U(VI) abiotic reaction with the limiting biological nutrient HP042-. This systematic approach may lead to a

  20. Groundwater Database

    Broader source: Energy.gov [DOE]

    DOE has one of the largest ground water contamination problems and subsequent cleanup responsibilities for a single entity in the world, in terms of the sheer volume of affected groundwater, number...

  1. NNSS Groundwater

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Devils Hole meeting puts focus on NNSS groundwater. See page 8. See page 7. Moniz Confirmed Energy Secretary; Replaces Chu Dr. Ernest Moniz was officially sworn in as the 13th ...

  2. Groundwaters of Florence (Italy): Trace element distribution and vulnerability of the aquifers

    SciTech Connect (OSTI)

    Bencini, A.; Ercolanelli, R.; Sbaragli, A.

    1993-11-01

    Geochemical and hydrogeological research has been carried out in Florence, to evaluate conductivity and main chemistry of groundwaters, the pattern of some possible pollutant chemical species (Fe, Mn, Cr, Cu, Pb, Zn, NO{sub 2}, NO{sub 3}), and the vulnerability of the aquifers. The plain is made up of Plio-Quaternary alluvial and lacustrine sediments for a maximum thickness of 600 m. Silts and clays, sometimes with lenses of sandy gravels, are dominant, while considerable deposits of sands, pebbles, and gravels occur along the course of the Arno river and its tributary streams, and represent the most important aquifer of the plain. Most waters show conductivity values around 1000-1200 {mu}S, and almost all of them have an alkaline-earth-bicarbonate chemical character. In western areas higher salt content of the groundwaters is evident. Heavy metal and NO{sub 2}, NO{sub 3} analyses point out that no important pollution phenomena affect the groundwaters; all mean values are below the maximum admissible concentration (MAC) for drinkable waters. Some anomalies of NO{sub 2}, NO{sub 3}, Fe, Mn, and Zn are present. The most plausible causes can be recognized in losses of the sewage system; use of nitrate compounds in agriculture; oxidation of well pipes. All the observations of Cr, Cu, and Pb are below the MAC; the median values of <3, 3.9, and 1.1 {mu}g/l, respectively, could be considered reference concentrations for groundwaters in calcareous lithotypes, under undisturbed natural conditions. Finally, a map of vulnerability shows that the areas near the Arno river are highly vulnerable, for the minimum thickness (or lacking) of sediments covering the aquifer. On the other hand, in the case of pollution, several factors not considered could significantly increase the self-purification capacity of the aquifer, such asdilution of groundwaters, bacteria oxidation of nitrogenous species, and sorption capacity of clay minerals and organic matter. 31 refs., 6 figs., 5 tabs.

  3. Probabilistic evaluation of shallow groundwater resources at a hypothetical carbon sequestration site

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dai, Zhenxue; Keating, Elizabeth; Bacon, Diana H.; Viswanathan, Hari; Stauffer, Philip; Jordan, Amy B.; Pawar, Rajesh

    2014-03-07

    Carbon sequestration in geologic reservoirs is an important approach for mitigating greenhouse gases emissions to the atmosphere. This study first develops an integrated Monte Carlo method for simulating CO2 and brine leakage from carbon sequestration and subsequent geochemical interactions in shallow aquifers. Then, we estimate probability distributions of five risk proxies related to the likelihood and volume of changes in pH, total dissolved solids, and trace concentrations of lead, arsenic, and cadmium for two possible consequence thresholds. The results indicate that shallow groundwater resources may degrade locally around leakage points by reduced pH and increased total dissolved solids (TDS). Themore » volumes of pH and TDS plumes are most sensitive to aquifer porosity, permeability, and CO2 and brine leakage rates. The estimated plume size of pH change is the largest, while that of cadmium is the smallest among the risk proxies. Plume volume distributions of arsenic and lead are similar to those of TDS. The scientific results from this study provide substantial insight for understanding risks of deep fluids leaking into shallow aquifers, determining the area of review, and designing monitoring networks at carbon sequestration sites.« less

  4. Probabilistic evaluation of shallow groundwater resources at a hypothetical carbon sequestration site

    SciTech Connect (OSTI)

    Dai, Zhenxue; Keating, Elizabeth; Bacon, Diana H.; Viswanathan, Hari; Stauffer, Philip; Jordan, Amy B.; Pawar, Rajesh

    2014-03-07

    Carbon sequestration in geologic reservoirs is an important approach for mitigating greenhouse gases emissions to the atmosphere. This study first develops an integrated Monte Carlo method for simulating CO2 and brine leakage from carbon sequestration and subsequent geochemical interactions in shallow aquifers. Then, we estimate probability distributions of five risk proxies related to the likelihood and volume of changes in pH, total dissolved solids, and trace concentrations of lead, arsenic, and cadmium for two possible consequence thresholds. The results indicate that shallow groundwater resources may degrade locally around leakage points by reduced pH and increased total dissolved solids (TDS). The volumes of pH and TDS plumes are most sensitive to aquifer porosity, permeability, and CO2 and brine leakage rates. The estimated plume size of pH change is the largest, while that of cadmium is the smallest among the risk proxies. Plume volume distributions of arsenic and lead are similar to those of TDS. The scientific results from this study provide substantial insight for understanding risks of deep fluids leaking into shallow aquifers, determining the area of review, and designing monitoring networks at carbon sequestration sites.

  5. Groundwater Screen

    Energy Science and Technology Software Center (OSTI)

    1993-11-09

    GWSCREEN was developed for assessment of the groundwater pathway from leaching of radioactive and non radioactive substances from surface or buried sources and release to percolation ponds. The code calculates the limiting soil concentration or effluent release concentration such that, after leaching and transport to the aquifer, regulatory contaminant levels in groundwater are not exceeded. The code uses a mass conservation approach to model three processes: Contaminant release from a source volume, contaminant transport inmore » the unsaturated zone, and contaminant transport in the saturated zone. The source model considers the sorptive properties and solubility of the contaminant. Transport in the unsaturated zone is described by a plug flow model. Transport in the saturated zone is calculated with a semi-analytical solution to the advection dispersion equation in groundwater. Concentration as a function of time at a user specified receptor point and maximum concentration averaged over the exposure interval are also calculated. In addition, the code calculates transport and impacts of radioactive progeny. Input to GWSCREEN is through one, free format ASCII file. This code was designed for assessment and screening of the groundwater pathway when field data is limited. It was not intended to be a predictive tool.« less

  6. Microsoft Word - S06654_ESL.doc

    Office of Legacy Management (LM)

    Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado July 2010 LMS/RFN/S06654 ESL-RPT-2010-01 This page intentionally left blank LMS/RFN/S06654 ESL-RPT-2010-01 Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado July 2010 This page intentionally left blank U.S. Department of Energy Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater, Rifle, Colorado July

  7. Calendar Year 2004 Groundwater Monitoring Report, U.S. Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    N /A

    2005-09-01

    distinguishing sampling characteristics; (3) an evaluation of hydrologic characteristics, based on pre-sampling groundwater elevations, along with a compilation of available test results (e.g., hydraulic conductivity test data); (4) a discussion of geochemical characteristics based on evaluation of the analytical results for the primary anions and cations; and (5) a detailed analysis and interpretation of the available data for the principal groundwater contaminants at Y-12: nitrate, uranium, volatile organic compounds (VOCs), gross alpha activity, and gross beta activity. The following sections of this report provide details regarding the CY 2004 groundwater and surface water monitoring activities in the Bear Creek, East Fork, and Chestnut Ridge Regime. Section 2 briefly describes the hydrogeologic system and generalized extent of groundwater contamination in each regime. Section 3 describes the monitoring programs implemented and associated sampling activities performed in each regime during CY 2004. Section 4 presents an a summary of the CY 2004 monitoring data with regard to the provisions of DOE Order 450.1 (surveillance and exit pathway/perimeter monitoring), including highlights of notable findings and time-series plots of data for CY 2004 sampling locations that provide representative examples of long-term contaminant concentration trends. Brief conclusions and proposed recommendations are provided in Section 5. Section 6 lists the documents cited for more detailed operational, regulatory, and technical information. The narrative sections of the report reference several appendices. Figures (maps and diagrams) and tables (excluding data summary tables presented in the narrative sections) are in Appendix A and Appendix B, respectively. Monitoring well construction details are in Appendix C. Results of field measurements and laboratory analyses of the groundwater and surface water samples collected during CY 2004 are in Appendix D (Bear Creek Regime), Appendix E (East Fork

  8. Calendar Year 2005 Groundwater Monitoring Report, U.S. Department of Energy Y-12 National Security Complex, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    2006-09-01

    distinguishing sampling characteristics; (3) an evaluation of hydrologic characteristics, based on pre-sampling groundwater elevations, along with a compilation of available test results (e.g., hydraulic conductivity test data); (4) a discussion of geochemical characteristics based on evaluation of the analytical results for the primary anions and cations; and (5) a detailed analysis and interpretation of the available data for the principal groundwater contaminants at Y-12: nitrate, uranium, volatile organic compounds (VOCs), gross alpha activity, and gross beta activity. The following sections of this report provide details regarding the CY 2005 groundwater and surface water monitoring activities in the Bear Creek, East Fork, and Chestnut Ridge Regime. Section 2 briefly describes the hydrogeologic system and generalized extent of groundwater contamination in each regime. Section 3 describes the monitoring programs implemented and associated sampling activities performed in each regime during CY 2005. Section 4 presents an a summary of the CY 2005 monitoring data with regard to the provisions of DOE Order 450.1 (surveillance and exit pathway/perimeter monitoring), including highlights of notable findings and time-series plots of data for CY 2005 sampling locations that provide representative examples of long-term contaminant concentration trends. Brief conclusions and proposed recommendations are provided in Section 5. Section 6 lists the documents cited for more detailed operational, regulatory, and technical information. The narrative sections of the report reference several appendices. Figures (maps and diagrams) and tables (excluding data summary tables presented in the narrative sections) are in Appendix A and Appendix B, respectively. Monitoring well construction details are in Appendix C. Results of field measurements and laboratory analyses of the groundwater and surface water samples collected during CY 2005 are in Appendix D (Bear Creek Regime), Appendix E (East Fork

  9. Groundwater Monitoring Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Groundwater Monitoring Network Groundwater Monitoring Network The network includes 92 natural sources, 102 regional aquifer wells, 41 intermediate-depth wells and springs, and 67 wells in alluvium in canyons. August 1, 2013 Map of LANL's groundwater monitoring network Map of LANL's groundwater monitoring network

  10. Groundwater - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Groundwater Richland Operations Office Richland Operations Office River Corridor Central Plateau Groundwater PHOENIX Groundwater Annual Reports Mission Support Newsroom Groundwater Email Email Page | Print Print Page | Text Increase Font Size Decrease Font Size 200WPumpandTreat 200 West Pump and Treat The groundwater treatment project includes a number of injection and extraction wells feeding five pump and treat facilities in the 100 Area near the reactors, as well as a state-of-the-art

  11. Advances in Geochemical Testing of Key Contaminants in Residual Hanford Tank Waste

    SciTech Connect (OSTI)

    Deutsch, William J.; Krupka, Kenneth M.; Cantrell, Kirk J.; Brown, Christopher F.; Lindberg, Michael J.; Schaef, Herbert T.; Heald, Steve M.; Arey, Bruce W.; Kukkadapu, Ravi K.

    2005-11-04

    This report describes the advances that have been made over the past two years in testing and characterizing waste material in Hanford tanks.

  12. Geological and geochemical aspects of uranium deposits. A selected, annotated bibliography

    SciTech Connect (OSTI)

    Garland, P.A.; Thomas, J.M.; Brock, M.L.; Daniel, E.W.

    1980-06-01

    A bibliography of 479 references encompassing the fields of uranium and thorium geochemistry and mineralogy, geology of uranium deposits, uranium mining, and uranium exploration techniques has been compiled by the Ecological Sciences Information Center of Oak Ridge National Laboratory. The bibliography was produced for the National Uranium Resource Evaluation Program, which is funded by the Grand Junction Office of the Department of Energy. The references contained in the bibliography have been divided into the following eight subject categories: (1) geology of deposits, (2) geochemistry, (3) genesis O deposits, (4) exploration, (5) mineralogy, (6) uranium industry, (7) reserves and resources, and (8) geology of potential uranium-bearing areas. All categories specifically refer to uranium and thorium; the last category contains basic geologic information concerning areas which the Grand Junction Office feels are particularly favorable for uranium deposition. The references are indexed by author, geographic location, quadrangle name, geoformational feature, taxonomic name, and keyword.

  13. Memo: Quarry Residuals Geochemical Sampling of the Shallow USGS Piezometers in the Saint Charles County Wellfield.

    Office of Legacy Management (LM)

  14. Geochemical studies of reservoir processes in the NCPA field of The Geysers, a preliminary report

    SciTech Connect (OSTI)

    Truesdell, Alfred; Enedy, Steve; Smith, Bill

    1993-01-28

    Methods of tracing reservoir processes will be discussed and applied to the NCPA Geysers steam field. The gas and isotope chemistry of produced steam is far from uniform even in a restricted volume of the reservoir. The composition is affected by many factors. Differences in permeability, local existence of gas pockets or perched liquid and the pattern of fracture connection can cause neighboring wells to produce steam of different compositions. This study attempts to separate local effects from general influences by viewing the data across the field and over a period of time. The fits of the trend lines to the data are far from perfect but present a reasonably consistent picture.

  15. Geochemical character and origin of oils in Ordovician reservoir rock, Illinois and Indiana, USA

    SciTech Connect (OSTI)

    Guthrie, J.M.; Pratt, L.M.

    1995-11-01

    Twenty-three oils produced from reservoirs within the Ordovician Galena Group (Trenton equivalent) and one oil from the Mississippian Ste. Genevieve Limestone in the Illinois and Indiana portions of the Illinois basin are characterized. Two end-member oil groups (1) and (2) and one intermediate group (1A) are identified using conventional carbon isotopic analysis of whole and fractionated oils, gas chromatography (GC) of saturated hydrocarbon fractions, isotope-ratio-monitoring gas chromatography/mass spectrometry (irm-GC/MS) of n-alkanes ranging from C{sub 15} to C{sub 25}, and gas chromatography/mass spectrometry (GC/MS) of the aromatic hydrocarbon fractions. Group 1 is characterized by high odd-carbon predominance in mid-chain n-alkanes (C{sub 15}-C{sub 19}), low abundance Of C{sub 20+}, n-alkanes, and an absence of pristane and phytane. Group IA is characterized by slightly lower odd-carbon predominance of mid-chain n-alkanes, greater abundance of C{sub 20+} n-alkanes compared to group 1, and no pristane and phytane. Conventional correlations of oil to source rock based on carbon isotopic-type curves and hopane (m/z 191) and sterane (m/z 217) distributions are of limited use in distinguishing Ordovician-reservoired oil groups and determining their origin. Oil to source rock correlations using the distribution and carbon isotopic composition of n-alkanes and the m/z 133 chromatograms of n-alkylarenes show that groups 1 and 1A originated from strata of the Upper Ordovician Galena Group. Group 2 either originated solely from the Upper Ordovician Maquoketa Group or from a mixture of oils generated from the Maquoketa Group and the Galena Group. The Mississippian-reservoired oil most likely originated from the Devonian New Albany Group. The use of GC, irm-GC/MS, and GC/MS illustrates the value of integrated molecular and isotopic approaches for correlating oil groups with source rocks.

  16. Petroleum potential of the Upper Ordovician Maquoketa Group in Illinois: A coordinated geological and geochemical study

    SciTech Connect (OSTI)

    Crockett, J.E.; Oltz, D.F. ); Kruge, M.A. )

    1990-05-01

    The Ordovician Maquoketa Group in Illinois, predominantly composed of shale, calcareous shale, and carbonates, has long been considered a potential source for Illinois basin hydrocarbons. Methods used to better define the petroleum potential of the Maquoketa in the Illinois basin were lithostratigraphic study, Rock-Eval (pyrolysis) analyses, comparison of molecular markers from whole-rock extracts and produced oil, and construction of burial history models. Organic-rich submature Maquoketa potential source rocks are present in western Illinois at shallow depths on the basin flank. Deeper in the basin in southern Illinois, Rock-Eval analyses indicate that the Maquoketa shale is within the oil window. Solvent extracts of the Maquoketa from western Illinois closely resemble the Devonian New Albany Shale, suggesting that past studies may have erroneously attributed Maquoketa-generated petroleum to a New Albany source or failed to identify mixed source oils. Subtle differences between Maquoketa and New Albany solvent extracts include differences in pristane/phytane ratios, proportions of steroids, and distribution of dimethyldibenzothiophene isomers. Maquoketa solvent extracts show little resemblance to Middle Ordovician oils from the Illinois or Michigan basins. Lithostratigraphic studies identified localized thick carbonate facies in the Maquoketa, suggesting depositional response to upper Ordovician paleostructures. Sandstone facies in the Maquoketa in southwestern Illinois offer a potential source/trap play, as well as serving as potential carrier beds for hydrocarbon migration. Maquoketa source and carrier beds may feed older Ordovician rocks in faulted areas along and south of the Cottage Grove fault system in southern Illinois.

  17. A Geochemical Model of the Kilauea East Rift Zone | Open Energy...

    Open Energy Info (EERE)

    to southwest-trending complex of dikes and fractures extending more than 100 kilometers from the summit caldera to the ocean floor. Geologic, petrologic, and geophysical...

  18. Geochemical Behaviour of S, Cl and Fe in Silicate Melts/Glasses...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    E. Paris, P. Glatzel, S. Eeckhout, M. Carroll, School of Science and Technology, Geology Division, University of Camerino, Via G. III da Varano, 62032 Camerino; e-mail:...

  19. Geochemical and Strontium Isotope Characterization of Produced Waters from Marcellus Shale Natural Gas Extraction

    SciTech Connect (OSTI)

    Chapman, Elizabeth C; Capo, Rosemary C.; Stewart, Brian W.; Kirby, Carl S.; Hammack, Richard W.; Schroeder, Karl T.; Edenborn, Harry M.

    2012-03-20

    Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of 375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (ε{sub Sr}{sup SW} = +13.8 to +41.6, where ε{sub Sr}{sup SW} is the deviation of the {sup 87}Sr/{sup 86}Sr ratio from that of seawater in parts per 10{sup 4}); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters.

  20. Geochemical and Strontium Isotope Characterization of Produced Waters from Marcellus Shale Natural Gas Extraction

    SciTech Connect (OSTI)

    Elizabeth C. Chapman,† Rosemary C. Capo,† Brian W. Stewart,*,† Carl S. Kirby,‡ Richard W. Hammack,§ Karl T. Schroeder,§ and Harry M. Edenborn

    2012-02-24

    Extraction of natural gas by hydraulic fracturing of the Middle Devonian Marcellus Shale, a major gas-bearing unit in the Appalachian Basin, results in significant quantities of produced water containing high total dissolved solids (TDS). We carried out a strontium (Sr) isotope investigation to determine the utility of Sr isotopes in identifying and quantifying the interaction of Marcellus Formation produced waters with other waters in the Appalachian Basin in the event of an accidental release, and to provide information about the source of the dissolved solids. Strontium isotopic ratios of Marcellus produced waters collected over a geographic range of ∼375 km from southwestern to northeastern Pennsylvania define a relatively narrow set of values (εSr SW = +13.8 to +41.6, where εSr SW is the deviation of the 87Sr/86Sr ratio from that of seawater in parts per 104); this isotopic range falls above that of Middle Devonian seawater, and is distinct from most western Pennsylvania acid mine drainage and Upper Devonian Venango Group oil and gas brines. The uniformity of the isotope ratios suggests a basin-wide source of dissolved solids with a component that is more radiogenic than seawater. Mixing models indicate that Sr isotope ratios can be used to sensitively differentiate between Marcellus Formation produced water and other potential sources of TDS into ground or surface waters.

  1. Coal-type gas provinces in China and their geochemical characteristics

    SciTech Connect (OSTI)

    Zhang Xiaobao; Xu Yonghang; Shen Ping )

    1996-01-01

    The distribution of coal - type gases in China can be divided into the east gas province, the central gas province and the west gas province the east gas province lies in the East China Meso - Cenozoic Rift Belt, including Donghai Basin and Bohaiwan Basin. The ages of gas source rocks are Carbo - Permian and Tertiary. The types of gas reservoirs are a anticline or a hidden mountain - fault block combination reservoir. The CH[sub 4] content ofthe gases there is 83 -90%, with [delta][sup 13]C[sub 1] -35.5 [approximately] -39.9[per thousand], and [delta][sup 13]C[sub 2] -24.0 [approximately] -26.8[per thousand]. The [delta][sup 13]C of condensate oils associated with the gases ranges from -25.4[per thousand] to -26.8[per thousand]. The central gas province is inside the Central China Paleozoic Plates, including Orclos Basin and Sichuan Basin. The gas source rocks are Carbo - Permian and Triassic. The types of gas reservoirs are an anticline-fault combination or a lithological-tectonic combination reservoir. The [delta][sup 13]C[sub 1] of the gases there is -37.9 [approximately] -37. l[per thousand], with the [delta][sup 13]C of condensate oil accompanying them - 25.1 [approximately] -26.6[per thousand]. The west gas province is within the West China Late Paleozoic Intracontinental Compressive Belt, including Tarim Basin, Jungar Basin and Tuna Basin. The age of gas source rocks is Jurassic. The types of gas reservoirs are an anticline or an anticline-fault reservoir. The CH[sub 4] content of the gases there varies from 60 to 90%, with [delta][sup 13]C[sub 1] from - 38.7 to -43.7[per thousand] and [delta] [sup 13]C[sub 2] from -25.9[per thousand] to -29.9[per thousand]. The [delta] [sup 13]C of light oils and condensate oils accompanying the gases changes from 24.3[per thousand] to 27.8[per thousand].

  2. Coal-type gas provinces in China and their geochemical characteristics

    SciTech Connect (OSTI)

    Zhang Xiaobao; Xu Yonghang; Shen Ping

    1996-12-31

    The distribution of coal - type gases in China can be divided into the east gas province, the central gas province and the west gas province the east gas province lies in the East China Meso - Cenozoic Rift Belt, including Donghai Basin and Bohaiwan Basin. The ages of gas source rocks are Carbo - Permian and Tertiary. The types of gas reservoirs are a anticline or a hidden mountain - fault block combination reservoir. The CH{sub 4} content ofthe gases there is 83 -90%, with {delta}{sup 13}C{sub 1} -35.5 {approximately} -39.9{per_thousand}, and {delta}{sup 13}C{sub 2} -24.0 {approximately} -26.8{per_thousand}. The {delta}{sup 13}C of condensate oils associated with the gases ranges from -25.4{per_thousand} to -26.8{per_thousand}. The central gas province is inside the Central China Paleozoic Plates, including Orclos Basin and Sichuan Basin. The gas source rocks are Carbo - Permian and Triassic. The types of gas reservoirs are an anticline-fault combination or a lithological-tectonic combination reservoir. The {delta}{sup 13}C{sub 1} of the gases there is -37.9 {approximately} -37. l{per_thousand}, with the {delta}{sup 13}C of condensate oil accompanying them - 25.1 {approximately} -26.6{per_thousand}. The west gas province is within the West China Late Paleozoic Intracontinental Compressive Belt, including Tarim Basin, Jungar Basin and Tuna Basin. The age of gas source rocks is Jurassic. The types of gas reservoirs are an anticline or an anticline-fault reservoir. The CH{sub 4} content of the gases there varies from 60 to 90%, with {delta}{sup 13}C{sub 1} from - 38.7 to -43.7{per_thousand} and {delta} {sup 13}C{sub 2} from -25.9{per_thousand} to -29.9{per_thousand}. The {delta} {sup 13}C of light oils and condensate oils accompanying the gases changes from 24.3{per_thousand} to 27.8{per_thousand}.

  3. Kinetics and Mechanism of Metal Retention/Release in Geochemical Processes in Soil - Final Report

    SciTech Connect (OSTI)

    Taylor, Robert W.

    2000-12-29

    Effective, remediation of soils contaminated with heavy metals requires a better understanding of the mechanisms by which the metals are retained/released in soils over a long period of time. Studies on reaction of Cr(VI) with iron-rich clays indicated that structural iron (II) in these surfaces is capable of reducing chromate to chromium (III). We found that iron (II) either found naturally or produced by treatment of clay with sodium dithionite, effectively reduced Cr (VI) to Cr (III). Thus, in situ remediation of chromium combines reduction of Cr (VI) to Cr (III) and immobilization of chromium on mineral surfaces. During this study, lead sorption on a kaolin surface was found to be a rapid and a pH dependant process in which lead sorption significantly increased with the amount of phosphate on the clay surface. This study verifies that methylmercury cation remains intact when it binds to humic acids, forming a monodentate complex with some sub-population of humic thiol ligands .

  4. Salt effects on isotope partitioning and their geochemical implications: An overview

    SciTech Connect (OSTI)

    Horita, J.; Cole, D.R.; Fortier, S.M.

    1996-01-01

    Essential to the use of stable isotopes as natural tracers and geothermometers is the knowledge of equilibrium isotope partitioning between different phases and species, which is usually a function of temperature only. The one exception known to date is oxygen and hydrogen isotope fractionation between liquid water and other phases (steam, gases, minerals), which changes upon the addition of salts to water, i.e., the isotope salt salt effect. Our knowledge of this effect, the difference between activity and composition (a-X) of isotopic water molecules in salt solutions, is very limited and controversial, especially at elevated temperatures. For the last several years, we have been conducting a detailed, systematic experimental study at Oak Ridge National Laboratory to determine the isotope salt effects from room temperature to elevated temperatures (currently to 500{degree}C). From this effort, a simple, coherent picture of the isotope salt effect is emerging, that differs markedly from the complex results reported in the literature. In this communication, we present an overview on the isotope salt effect, obtained chiefly from our study. Observed isotope salt effects in salt solutions are significant even at elevated temperatures. The importance and implications of the isotope salt effect for isotopic studies of brine-dominated systems are also discussed in general terms.

  5. Organic geochemical evaluations of bituminous rock and coals in Miocene Himmetoglu basin (Bolu, Turkey)

    SciTech Connect (OSTI)

    Sari, A.; Geze, Y.

    2008-07-01

    The studied area is a lake basin located in Bolu basin in Turkey. In the basin, from Upper Cretaceous to Upper Miocene 3,000-m thickness sediments were deposited. Upper Miocene Himmetoglu formation consisted of sandstone, claystone, and marl. To the middle level of the formation are located coal, bituminous limestone, and bituminous shales. In the basin, there are two coal beds whose thicknesses range from 1 to 13 m. The coals are easily breakable and black in color. In the coal beds exists some bituminous limestone and bituminous shales, and their thicknesses are between 5 and 45 cm. The amount of organic matter of the bituminous rocks from the Upper Miocene Himmetoglu formation are between 6.83 and 56.34 wt%, and the amount of organic matter of the bituminous limestone from the formation are between 13.58 and 57.16 wt%. These values indicate that these rocks have very good source potential. According to hydrogen index (HI), S2/S3, HI-T{sub max}, and HI-OI (oxygen index) parameters, kerogen types of the bituminous rocks and coals belonging to Upper Miocene Himmetoglu formation are Type I, Type II, and Type III. In accordance with HI, S2/S3, HI-T{sub max}, and HI-OI parameters, the bituminous rocks and coals from the Upper Miocene Himmetoglu formation are mostly immature.

  6. Geochemical Weathering Increases Lead Bioaccessibility in Semi-Arid Mine Tailings

    SciTech Connect (OSTI)

    Hayes, Sarah M.; Webb, Sam M.; Bargar, John R.; O?Day, Peggy A.; Maier, Raina M.; Chorover, Jon

    2012-09-05

    Mine tailings can host elevated concentrations of toxic metal(loid)s that represent a significant hazard to surrounding communities and ecosystems. Eolian transport, capable of translocating small (micrometer-sized) particles, can be the dominant mechanism of toxic metal dispersion in arid or semiarid landscapes. Human exposure to metals can then occur via direct inhalation or ingestion of particulates. The fact that measured doses of total lead (Pb) in geomedia correlate poorly with blood Pb levels highlights a need to better resolve the precise distribution of molecularly speciated metal-bearing phases in the complex particle mixtures. Species distribution controls bioaccessibility, thereby directly impacting health risk. This study seeks to correlate Pb-containing particle size and mineral composition with lability and bioaccessibility in mine tailings subjected to weathering in a semiarid environment. We employed X-ray absorption spectroscopy (XAS) and X-ray fluorescence (XRF), coupled with sequential chemical extractions, to study Pb speciation in tailings from the semiarid Arizona Klondyke State Superfund Site. Representative samples ranging in pH from 2.6 to 5.4 were selected for in-depth study of Pb solid-phase speciation. The principle lead-bearing phase was plumbojarosite (PbFe{sub 6}(SO{sub 4}){sub 4}(OH){sub 12}), but anglesite (PbSO{sub 4}) and iron oxide-sorbed Pb were also observed. Anglesite, the most bioavailable mineral species of lead identified in this study, was enriched in surficial tailings samples, where Pb concentrations in the clay size fraction were 2-3 times higher by mass relative to bulk. A mobile and bioaccessible Pb phase accumulates in surficial tailings, with a corresponding increase in risk of human exposure to atmospheric particles.

  7. Hydrology of the Greater Tongonan geothermal system, Philippines, as deduced from geochemical and isotopic data

    SciTech Connect (OSTI)

    Alvis-Isidro, R.R.; Solana, R.R.; D`amore, F.; Nuti, S.; Gonfiantini, R.

    1993-10-01

    Fluids in the Greater Tongonan geothermal system exhibit a large positive {sup 18}O shift from the Leyte meteoric water line. However, there is also a significant shift in {sup 2}H. The {delta}{sup 2}H-{delta}{sup 18}O plot shows that the geothermal fluids may be derived by the mixing of meteoric water with local magmatic water. The most enriched water in the Greater Tongonan system, in terms of {delta}{sup 18}O, {delta}{sup 2}H and Cl, is comprised of approximately 40% magmatic water. Baseline isotope results support a hydrogeochemical model in which there is increasing meteoric water dilution to the southeast, from Mahiao to Sambaloran and towards Malitbog. The Cl-{delta}{sup 18}O plot confirms that the geothermal fluid in Mahanagdong, further southeast, is distinct from that of the Mahiao-Sambaloran-Malitbog system.

  8. Geochemical and Geomechanical Effects on Wellbore Cement Fractures: Data Information for Wellbore Reduced Order Model

    SciTech Connect (OSTI)

    Um, Wooyong; Jung, Hun Bok; Kabilan, Senthil; Suh, Dong-Myung; Fernandez, Carlos A.

    2014-01-01

    The primary objective of the National Risk Assessment Partnership (NRAP) program is to develop a defensible, generalized, and science-based methodology and platform for quantifying risk profiles at CO2 injection and storage sites. The methodology must incorporate and define the scientific basis for assessing residual risks associated with long-term stewardship and help guide site operational decision-making and risk management. Development of an integrated and risk-based protocol will help minimize uncertainty in the predicted long-term behavior of the CO2 storage site and thereby increase confidence in storage integrity. The risk profile concept has proven useful in conveying the qualitative evolution of risks for CO2 injection and storage site. However, qualitative risk profiles are not sufficient for specifying long-term liability for CO2 storage sites. Because there has been no science-based defensible and robust methodology developed for quantification of risk profiles for CO2 injection and storage, NRAP has been focused on developing a science-based methodology for quantifying risk profiles for various risk proxies.

  9. EQ3/6, a software package for geochemical modeling of aqueous...

    Office of Scientific and Technical Information (OSTI)

    The software deals with the concepts of thermodynamic equilibrium, thermodynamic ... whether certain reactions are in states of partial equilibrium or disequilibrium. ...

  10. The Hanford Story: Groundwater

    Broader source: Energy.gov [DOE]

    This second chapter of The Hanford Story explains how more than 100 square miles of groundwater under the Hanford Site became contaminated and what workers are doing to restore groundwater to its highest beneficial use.

  11. Appendix K Disposal Cell Groundwater Monitoring Plan

    Office of Legacy Management (LM)

    K Disposal Cell Groundwater Monitoring Plan

  12. Groundwater Monitoring Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    92 natural sources, 102 regional aquifer wells, 41 intermediate-depth wells and springs, and 67 wells in alluvium in canyons. August 1, 2013 Map of LANL's groundwater...

  13. Groundwater in the Regional Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Groundwater in the Regional Aquifer Groundwater in the Regional Aquifer LANL maintains an ... August 1, 2013 Conceptual model of water movement and geology at Los Alamos National ...

  14. Protection of the Groundwater Resource

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Protection of the Groundwater Resource Protection of the Groundwater Resource Monitoring wells act as sentinels between suspected LANL contamination and the water supply. August 1,...

  15. Measured solubilities and speciations of neptunium, plutonium, and americium in a typical groundwater (J-13) from the Yucca Mountain region; Milestone report 3010-WBS 1.2.3.4.1.3.1

    SciTech Connect (OSTI)

    Nitsche, H.; Gatti, R.C.; Standifer, E.M.

    1993-07-01

    Solubility and speciation data are important in understanding aqueous radionuclide transport through the geosphere. They define the source term for transport retardation processes such as sorption and colloid formation. Solubility and speciation data are useful in verifying the validity of geochemical codes that are part of predictive transport models. Results are presented from solubility and speciation experiments of {sup 237}NpO{sub 2}{sup +}, {sup 239}Pu{sup 4+}, {sup 241}Am{sup 3+}/Nd{sup 3+}, and {sup 243}Am{sup 3+} in J-13 groundwater (from the Yucca Mountain region, Nevada, which is being investigated as a potential high-level nuclear waste disposal site) at three different temperatures (25{degree}, 60{degree}, and 90{degree}C) and pH values (5.9, 7.0, and 8.5). The solubility-controlling steady-state solids were identified and the speciation and/or oxidation states present in the supernatant solutions were determined. The neptunium solubility decreased with increasing temperature and pH. Plutonium concentrations decreased with increasing temperature and showed no trend with pH. The americium solutions showed no clear solubility trend with increasing temperature and increasing pH.

  16. EPA's groundwater protection strategy

    SciTech Connect (OSTI)

    Smith, J. )

    1992-06-01

    What the EPA, working jointly with the states, hopes to accomplish over the next ten years in order to integrate and coordinate all the groundwater programs within the agency is discussed. Although many other EPA programs such as Superfund, Clean Air Act, and Wetlands Management are often highlighted in the media, EPA does not down rate the importance of groundwater protection. Indeed as a resource, it is one of the most important commodities. Groundwater is the basis for life in this country. Recharge rates are no where near what the withdrawal rates are in many areas of the country. Twenty-five percent of all the potable water comes from groundwater. Groundwater supplies 50 percent of the needs for all the US population. If you include strictly rural areas, it supplies 95 percent of all the use. Something that most people who are not groundwater hydrologists would not think about is the fact that groundwater is a recharge mechanism that provides over 30 percent of the flow in streams and major rivers.

  17. Groundwater Sampling and Soil Gas Data Analysis, Distler Brickyard Superfund Site, Hardin County, Kentucky -- June - August 2000

    SciTech Connect (OSTI)

    Martin, Jennifer Pauline; Peterson, Lance Nutting; Taylor, C. J.

    2000-11-01

    This report describes the results of groundwater and soil gas sampling conducted at the Distler Brickyard Site, Hardin County, Kentucky, June-August, 2000. The purpose of the sampling activities was to address remaining data gaps regarding the feasibility of monitored natural attenuation (MNA) for remediation of chloroethene/ane contamination. Specifically, data gaps fall into four categories: 1) effect of seasonal recharge on contaminant concentrations, 2) geochemical conditions in the Fine Grained Alluvium (FGA), 3) conditions along the flowpath between Wells GW-11 and MW-3, and 4) the extent of aerobic degradation in the Coarse Grained Alluvium (CGA). A data collection strategy composed of both groundwater sampling and passive soil vapor sampling devices (Gore-Sorbers?) was used. The Gore-Sorber? technology was used to collect data from the FGA, which because of its low hydraulic conductivity and variable saturation makes collection of groundwater samples problematic. Gore-Sorbers were deployed in 15 wells, most of them being in the FGA, and groundwater samples were collected in 17 wells, which were mostly in the CGA. Both sampling methods were utilized in a subset of wells (7) in order to determine the general comparability of results obtained from each method. Results indicate that water levels in both the FGA and CGA were higher in June-August 2000 than in October 1999, likely due to increased infiltration of precipitation through the FGA during the wetter months. Redox conditions in the FGA and downgradient CGA were iron-reducing, less reducing than in October-1999. In general, concentrations of chloroethenes/anes were higher in June-August 2000 than October 1999. Trichloroethene (TCE) was present at concentrations as high as 65 µg/L in the FGA and 19 µg/L in the CGA. This is substantially higher than the maximum concentration in October 1999 of 11 µg/L. The following conclusions were drawn from these data collection activities: 1) two potential

  18. Natural radionuclides in groundwaters

    SciTech Connect (OSTI)

    Laul, J.C.

    1990-01-01

    The U-234 and Th-230 radionuclides are highly retarded by factors of 10{sup 4} to 10{sup 5} in basalt groundwater (Hanford) and briny groundwaters from Texas and geothermal brine from the Salton Sea Geothermal Field (SSGF). In basalt groundwaters (low ionic strength), Ra is highly sorbed, while in brines (high ionic strength), Ra is soluble. This is probably because the sorption sites are saturated with Na{sup +} and Cl{sup {minus}} ions and RaCl{sub 2} is soluble in brines. Pb-210 is soluble in SSGF brine, probably as a chloride complex. The U-234/Th-230 ratios in basalt groundwaters and brines from Texas and SSGF are nearly unity, indicating that U is in the +4 state, suggesting a reducing environment for these aquifers. 19 refs., 3 figs.

  19. CO2 leakage impacts on shallow groundwater. Field-scale reactive-transport simulations informed by observations at a natural analog site

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Keating, Elizabeth H.; Hakala, J. Alexandra; Viswanathan, Hari; Carey, J. William; Pawar, Rajesh; Guthrie, George D.; Fessenden-Rahn, Julianna

    2013-03-01

    It is challenging to predict the degree to which shallow groundwater might be affected by leaks from a CO2 sequestration reservoir, particularly over long time scales and large spatial scales. In this study observations at a CO2 enriched shallow aquifer natural analog were used to develop a predictive model which is then used to simulate leakage scenarios. This natural analog provides the opportunity to make direct field observations of groundwater chemistry in the presence of elevated CO2, to collect aquifer samples and expose them to CO2 under controlled conditions in the laboratory, and to test the ability of multiphase reactivemore » transport models to reproduce measured geochemical trends at the field-scale. The field observations suggest that brackish water entrained with the upwelling CO2 are a more significant source of trace metals than in situ mobilization of metals due to exposure to CO2. The study focuses on a single trace metal of concern at this site: U. Experimental results indicate that cation exchange/adsorption and dissolution/precipitation of calcite containing trace amounts of U are important reactions controlling U in groundwater at this site, and that the amount of U associated with calcite is fairly well constrained. Simulations incorporating these results into a 3-D multi-phase reactive transport model are able to reproduce the measured ranges and trends between pH, pCO2, Ca, total C, U and Cl-at the field site. Although the true fluxes at the natural analog site are unknown, the cumulative CO2 flux inferred from these simulations are approximately equivalent to 37.8E-3 MT, approximately corresponding to a .001% leak rate for injection at a large (750 MW) power plant. The leakage scenario simulations suggest that if the leak only persists for a short time the volume of aquifer contaminated by CO2-induced mobilization of U will be relatively small, yet persistent over 100 a.« less

  20. Fernald Environmental Management Project Archived Soil & Groundwater...

    Office of Environmental Management (EM)

    Fernald Environmental Management Project Archived Soil & Groundwater Master Reports Fernald Environmental Management Project Archived Soil & Groundwater Master Reports Fernald ...

  1. Miamisburg Environmental Management Project Archived Soil & Groundwate...

    Office of Environmental Management (EM)

    Miamisburg Environmental Management Project Archived Soil & Groundwater Master Reports Miamisburg Environmental Management Project Archived Soil & Groundwater Master Reports ...

  2. Protection of the Groundwater Resource

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Protection of the Groundwater Resource Protection of the Groundwater Resource Monitoring wells act as sentinels between suspected LANL contamination and the water supply. August 1, 2013 Where to place a sentinel well Where

  3. In situ groundwater bioremediation

    SciTech Connect (OSTI)

    Hazen, Terry C.

    2009-02-01

    In situ groundwater bioremediation of hydrocarbons has been used for more than 40 years. Most strategies involve biostimulation; however, recently bioaugmentation have been used for dehalorespiration. Aquifer and contaminant profiles are critical to determining the feasibility and strategy for in situ groundwater bioremediation. Hydraulic conductivity and redox conditions, including concentrations of terminal electron acceptors are critical to determine the feasibility and strategy for potential bioremediation applications. Conceptual models followed by characterization and subsequent numerical models are critical for efficient and cost effective bioremediation. Critical research needs in this area include better modeling and integration of remediation strategies with natural attenuation.

  4. Quantification of Hydrological, Geochemical, and Mineralogical Processes Governing the Fate and Transport of Uranium over Multiple Scales in Hanford Sediments

    SciTech Connect (OSTI)

    Mayes, Melanie A.; Perfect, Edmund; van den Berg, Elmer; Parker, Jack C.; Jardine, Philip M.; Tang, Guoping; Fendorf, Scott

    2006-11-15

    A long-term measure of the DOE Environmental Remediation Sciences Division is to provide sufficient scientific understanding to allow a significant fraction of DOE sites to incorporate coupled biological, chemical, and physical processes into decision making for environmental remediation and long-term stewardship by 2015. Our research targets two related, major obstacles to understanding and predicting contaminant transport at DOE sites: the heterogeneity of subsurface geologic media, and the scale dependence of experimental and modeled results.

  5. Assessment of Geochemical Environment for the Proposed INL Remote-Handled Low-Level Waste Disposal Facility

    SciTech Connect (OSTI)

    D. Craig Cooper

    2011-11-01

    Conservative sorption parameters have been estimated for the proposed Idaho National Laboratory Remote-Handled Low-Level Waste Disposal Facility. This analysis considers the influence of soils, concrete, and steel components on water chemistry and the influence of water chemistry on the relative partitioning of radionuclides over the life of the facility. A set of estimated conservative distribution coefficients for the primary media encountered by transported radionuclides has been recommended. These media include the vault system, concrete-sand-gravel mix, alluvium, and sedimentary interbeds. This analysis was prepared to support the performance assessment required by U.S. Department of Energy Order 435.1, 'Radioactive Waste Management.' The estimated distribution coefficients are provided to support release and transport calculations of radionuclides from the waste form through the vadose zone. A range of sorption parameters are provided for each key transport media, with recommended values being conservative. The range of uncertainty has been bounded through an assessment of most-likely-minimum and most-likely-maximum distribution coefficient values. The range allows for adequate assessment of mean facility performance while providing the basis for uncertainty analysis.

  6. Predictive modeling of CO{sub 2} sequestration in deep saline sandstone reservoirs: Impacts of geochemical kinetics

    SciTech Connect (OSTI)

    Balashov, Victor N.; Guthrie, George D.; Hakala, J. Alexandra; Lopano, Christina L. J.; Rimstidt, Donald; Brantley, Susan L.

    2013-03-01

    One idea for mitigating the increase in fossil-fuel generated CO{sub 2} in the atmosphere is to inject CO{sub 2} into subsurface saline sandstone reservoirs. To decide whether to try such sequestration at a globally significant scale will require the ability to predict the fate of injected CO{sub 2}. Thus, models are needed to predict the rates and extents of subsurface rock-water-gas interactions. Several reactive transport models for CO{sub 2} sequestration created in the last decade predicted sequestration in sandstone reservoirs of ~17 to ~90 kg CO{sub 2} m{sup -3|. To build confidence in such models, a baseline problem including rock + water chemistry is proposed as the basis for future modeling so that both the models and the parameterizations can be compared systematically. In addition, a reactive diffusion model is used to investigate the fate of injected supercritical CO{sub 2} fluid in the proposed baseline reservoir + brine system. In the baseline problem, injected CO{sub 2} is redistributed from the supercritical (SC) free phase by dissolution into pore brine and by formation of carbonates in the sandstone. The numerical transport model incorporates a full kinetic description of mineral-water reactions under the assumption that transport is by diffusion only. Sensitivity tests were also run to understand which mineral kinetics reactions are important for CO{sub 2} trapping. The diffusion transport model shows that for the first ~20 years after CO{sub 2} diffusion initiates, CO{sub 2} is mostly consumed by dissolution into the brine to form CO{sub 2,aq} (solubility trapping). From 20-200 years, both solubility and mineral trapping are important as calcite precipitation is driven by dissolution of oligoclase. From 200 to 1000 years, mineral trapping is the most important sequestration mechanism, as smectite dissolves and calcite precipitates. Beyond 2000 years, most trapping is due to formation of aqueous HCO{sub 3}{sup -}. Ninety-seven percent of the maximum CO{sub 2} sequestration, 34.5 kg CO{sub 2} per m{sup 3} of sandstone, is attained by 4000 years even though the system does not achieve chemical equilibrium until ~25,000 years. This maximum represents about 20% CO{sub 2} dissolved as CO{sub 2},aq, 50% dissolved as HCO{sub 3}{sup -}{sub ,aq}, and 30% precipitated as calcite. The extent of sequestration as HCO{sub 3}{sup -} at equilibrium can be calculated from equilibrium thermodynamics and is roughly equivalent to the amount of Na+ in the initial sandstone in a soluble mineral (here, oligoclase). Similarly, the extent of trapping in calcite is determined by the amount of Ca2+ in the initial oligoclase and smectite. Sensitivity analyses show that the rate of CO{sub 2} sequestration is sensitive to the mineral-water reaction kinetic constants between approximately 10 and 4000 years. The sensitivity of CO{sub 2} sequestration to the rate constants decreases in magnitude respectively from oligoclase to albite to smectite.

  7. Geochemical, metagenomic and metaproteomic insights into trace metal utilization by methane-oxidizing microbial consortia in sulphidic marine sediments

    SciTech Connect (OSTI)

    Glass, DR. Jennifer; Yu, DR. Hang; Steele, Joshua; Dawson, Katherine; Sun, S; Chourey, Karuna; Pan, Chongle; Hettich, Robert {Bob} L; Orphan, V

    2013-01-01

    Microbes have obligate requirements for trace metals in metalloenzymes that catalyse important biogeochemical reactions. In anoxic methane- and sulphiderich environments, microbes may have unique adaptations for metal acquisition and utilization because of decreased bioavailability as a result of metal sulphide precipitation. However, micronutrient cycling is largely unexplored in cold ( 10 C) and sulphidic (> 1 mM H2S) deep-sea methane seep ecosystems. We investigated trace metal geochemistry and microbial metal utilization in methane seeps offshore Oregon and California, USA, and report dissolved concentrations of nickel (0.5 270 nM), cobalt (0.5 6 nM), molybdenum (10 5600 nM) and tungsten (0.3 8 nM) in Hydrate Ridge sediment porewaters. Despite low levels of cobalt and tungsten, metagenomic and metaproteomic data suggest that microbial consortia catalysing anaerobic oxidation of methane (AOM) utilize both scarce micronutrients in addition to nickel and molybdenum. Genetic machinery for cobalt-containing vitamin B12 biosynthesis was present in both anaerobic methanotrophic archaea (ANME) and sulphate-reducing bacteria. Proteins affiliated with the tungsten-containing form of formylmethanofuran dehydrogenase were expressed in ANME from two seep ecosystems, the first evidence for expression of a tungstoenzyme in psychrophilic microorganisms. Overall, our data suggest that AOM consortia use specialized biochemical strategies to overcome the challenges of metal availability in sulphidic environments.

  8. Coal fly ash interaction with environmental fluids: Geochemical and strontium isotope results from combined column and batch leaching experiments

    SciTech Connect (OSTI)

    Brubaker, Tonya M.; Stewart, Brian W.; Capo, Rosemary C.; Schroeder, Karl T.; Chapman, Elizabeth C.; Spivak-Birndorf, Lev J.; Vesper, Dorothy J.; Cardone, Carol R.; Rohar, Paul C.

    2013-05-01

    The major element and Sr isotope systematics and geochemistry of coal fly ash and its interactions with environmental waters were investigated using laboratory flow-through column leaching experiments (sodium carbonate, acetic acid, nitric acid) and sequential batch leaching experiments (water, acetic acid, hydrochloric acid). Column leaching of Class F fly ash samples shows rapid release of most major elements early in the leaching procedure, suggesting an association of these elements with soluble and surface bound phases. Delayed release of certain elements (e.g., Al, Fe, Si) signals gradual dissolution of more resistant silicate or glass phases as leaching continues. Strontium isotope results from both column and batch leaching experiments show a marked increase in {sup 87}Sr/{sup 86}Sr ratio with continued leaching, yielding a total range of values from 0.7107 to 0.7138. For comparison, the isotopic composition of fluid output from a fly ash impoundment in West Virginia falls in a narrow range around 0.7124. The experimental data suggest the presence of a more resistant, highly radiogenic silicate phase that survives the combustion process and is leached after the more soluble minerals are removed. Strontium isotopic homogenization of minerals in coal does not always occur during the combustion process, despite the high temperatures encountered in the boiler. Early-released Sr tends to be isotopically uniform; thus the Sr isotopic composition of fly ash could be distinguishable from other sources and is a useful tool for quantifying the possible contribution of fly ash leaching to the total dissolved load in natural surface and ground waters.

  9. Geochemical, metagenomic and metaproteomic insights into trace metal utilization by methane-oxidizing microbial consortia in sulfidic marine sediments

    SciTech Connect (OSTI)

    Glass, DR. Jennifer; Yu, DR. Hang; Steele, Joshua; Dawson, Katherine; Sun, S; Chourey, Karuna; Hettich, Robert {Bob} L; Orphan, V

    2014-01-01

    Microbes have obligate requirements for trace metals in metalloenzymes that catalyze important biogeochemical reactions. In anoxic methane- and sulfide-rich environments, microbes may have unique adaptations for metal acquisition and utilization due to decreased bioavailability as a result of metal sulfide precipitation. However, micronutrient cycling is largely unexplored in cold ( 10 C) and sulfidic (>1 mM H2S) deep-sea methane seep ecosystems. We investigated trace metal geochemistry and microbial metal utilization in methane seeps offshore Oregon and California, USA, and report dissolved concentrations of nickel (0.5-270 nM), cobalt (0.5-6 nM), molybdenum (10-5,600 nM) and tungsten (0.3-8 nM) in Hydrate Ridge sediment porewaters. Despite low levels of cobalt and tungsten, metagenomic and metaproteomic data suggest that microbial consortia catalyzing anaerobic oxidation of methane utilize both scarce micronutrients in addition to nickel and molybdenum. Genetic machinery for cobalt-containing vitamin B12 biosynthesis was present in both anaerobic methanotrophic archaea (ANME) and sulfate-reducing bacteria (SRB). Proteins affiliated with the tungsten-containing form of formylmethanofuran dehydrogenase were expressed in ANME from two seep ecosystems, the first evidence for expression of a tungstoenzyme in psychrotolerant microorganisms. Finally, our data suggest that chemical speciation of metals in highly sulfidic porewaters may exert a stronger influence on microbial bioavailability than total concentration

  10. Geochemical reconnaissance for uranium in middle tertiary ash-flow tuffs of the Morey Peak Quadrangle, northern Nye County, Nevada

    SciTech Connect (OSTI)

    Evans, K.C.

    1981-01-01

    Rock and water samples were collected from the Morey Peak 15' quadrangle in the northern Hot Creek Range, Nye County, Nevada. The water was analyzed for trace element content. The rock samples were analyzed for oxide composition, selected trace element composition, and K-U-Th content. Water sampled from springs, hot springs, and creeks had temperatures ranging between 8 and 60/sup 0/C, conductance between 100 and 1800 mhos, pH between 5.4 and 8.7, and Eh between -106 and -301 mv. Factor analysis of the sample set reveals a U-Li-Se association and also identifies oxidized galena in solution. This analysis suggests that water need only be analyzed for copper, lithium, selenium, uranium, and vanadium in an uranium exploration program. Oxide analyses of these samples show gross similarities to other volcanic suites in central Nevada. Correlation coefficients indicate that in this area uranium is independent of any of the tested variables. Factor analyses suggest that there is an association between beryllium and uranium, arsenic and uranium, and selenium and uranium. The K-U-Th analyses yielded a wide variance of measurements. Potassium content ranges between 0 and 7.66%, thorium between 0 and 39.09 ppM, and uranium between 0.04 and 1744 ppM. Disequilibrium plots suggest that the mineralization present in the Corral Canyon area is late.

  11. Geochemical Analyses of Surface and Shallow Gas Flux and Composition Over a Proposed Carbon Sequestration Site in Eastern Kentucky

    SciTech Connect (OSTI)

    Thomas Parris; Michael Solis; Kathryn Takacs

    2009-12-31

    Using soil gas chemistry to detect leakage from underground reservoirs (i.e. microseepage) requires that the natural range of soil gas flux and chemistry be fully characterized. To meet this need, soil gas flux (CO{sub 2}, CH{sub 4}) and the bulk (CO{sub 2}, CH{sub 4}) and isotopic chemistry ({delta}{sup 13}C-CO2) of shallow soil gases (<1 m, 3.3 ft) were measured at 25 locations distributed among two active oil and gas fields, an active strip mine, and a relatively undisturbed research forest in eastern Kentucky. The measurements apportion the biologic, atmospheric, and geologic influences on soil gas composition under varying degrees of human surface disturbance. The measurements also highlight potential challenges in using soil gas chemistry as a monitoring tool where the surface cover consists of reclaimed mine land or is underlain by shallow coals. For example, enrichment of ({delta}{sup 13}C-CO2) and high CH{sub 4} concentrations in soils have been historically used as indicators of microseepage, but in the reclaimed mine lands similar soil chemistry characteristics likely result from dissolution of carbonate cement in siliciclastic clasts having {delta}{sup 13}C values close to 0{per_thousand} and degassing of coal fragments. The gases accumulate in the reclaimed mine land soils because intense compaction reduces soil permeability, thereby impeding equilibration with the atmosphere. Consequently, the reclaimed mine lands provide a false microseepage anomaly. Further potential challenges arise from low permeability zones associated with compacted soils in reclaimed mine lands and shallow coals in undisturbed areas that might impede upward gas migration. To investigate the effect of these materials on gas migration and composition, four 10 m (33 ft) deep monitoring wells were drilled in reclaimed mine material and in undisturbed soils with and without coals. The wells, configured with sampling zones at discrete intervals, show the persistence of some of the aforementioned anomalies at depth. Moreover, high CO{sub 2} concentrations associated with coals in the vadose zone suggest a strong affinity for adsorbing CO{sub 2}. Overall, the low permeability of reclaimed mine lands and coals and CO2 adsorption by the latter is likely to reduce the ability of surface geochemistry tools to detect a microseepage signal.

  12. Geochemistry Technical Basis Document

    SciTech Connect (OSTI)

    Benedict, Jr, F Christopher; Rose, Timothy P; Thomas, James M; Waddell, Richard; Jacobson, Roger

    2004-03-18

    This document presents a methodology whereby geochemical data can more effectively contribute to the development , calibration, and verification of groundwater flow and slute transport models for the Underground Test Area (UGTA) Project.

  13. Groundwater monitoring system

    DOE Patents [OSTI]

    Ames, Kenneth R.; Doesburg, James M.; Eschbach, Eugene A.; Kelley, Roy C.; Myers, David A.

    1987-01-01

    A groundwater monitoring system includes a bore, a well casing within and spaced from the bore, and a pump within the casing. A water impermeable seal between the bore and the well casing prevents surface contamination from entering the pump. Above the ground surface is a removable operating means which is connected to the pump piston by a flexible cord. A protective casing extends above ground and has a removable cover. After a groundwater sample has been taken, the cord is disconnected from the operating means. The operating means is removed for taking away, the cord is placed within the protective casing, and the cover closed and locked. The system is thus protected from contamination, as well as from damage by accident or vandalism.

  14. Oahu Groundwater Flow Model

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Groundwater flow model for the island of Oahu. Data is from the following sources: Rotzoll, K., A.I. El-Kadi. 2007. Numerical Ground-Water Flow Simulation for Red Hill Fuel Storage Facilities, NAVFAC Pacific, Oahu, Hawaii - Prepared TEC, Inc. Water Resources Research Center, University of Hawaii, Honolulu.; Whittier, R.B., K. Rotzoll, S. Dhal, A.I. El-Kadi, C. Ray, G. Chen, and D. Chang. 2004. Hawaii Source Water Assessment Program Report – Volume VII – Island of Oahu Source Water Assessment Program Report. Prepared for the Hawaii Department of Health, Safe Drinking Water Branch. University of Hawaii, Water Resources Research Center. Updated 2008.; and Whittier, R. and A.I. El-Kadi. 2009. Human and Environmental Risk Ranking of Onsite Sewage Disposal Systems – Final. Prepared by the University of Hawaii, Dept. of Geology and Geophysics for the State of Hawaii Dept. of Health, Safe Drinking Water Branch. December 2009.

  15. TECHNICAL BASIS FOR EVALUATING SURFACE BARRIERS TO PROTECT GROUNDWATER FROM DEEP VADOSE ZONE CONTAMINATION

    SciTech Connect (OSTI)

    FAYER JM; FREEDMAN VL; WARD AL; CHRONISTER GB

    2010-02-24

    The U.S. DOE and its predecessors released nearly 2 trillion liters (450 billion gallons) of contaminated liquid into the vadose zone at the Hanford Site. Some of the contaminants currently reside in the deeper parts of the vadose zone where they are much less accessible to characterization, monitoring, and typical remediation activities. The DOE Richland Operations Office (DOE-RL) prepared a treatability test plan in 2008 to examine remediation options for addressing contaminants in the deep vadose zone; one of the technologies identified was surface barriers (also known as engineered barriers, covers, and caps). In the typical configuration, the contaminants are located relatively close to the surface, generally within 15 m, and thus they are close to the base of the surface barrier. The proximity of the surface barrier under these conditions yielded few concerns about the effectiveness of the barrier at depth, particularly for cases in which the contaminants were in a lined facility. At Hanford, however, some unlined sites have contaminants located well below depths of 15 m. The issue raised about these sites is the degree of effectiveness of a surface barrier in isolating contaminants in the deep vadose zone. Previous studies by Hanford Site and PNNL researchers suggest that surface barriers have the potential to provide a significant degree of isolation of deep vadose zone contaminants. The studies show that the actual degree of isolation is site-specific and depends on many factors, including recharge rates, barrier size, depth of contaminants, geohydrologic properties ofthe sediments, and the geochemical interactions between the contaminants and the sediments. After the DOE-RL treatability test plan was published, Pacific Northwest National Laboratory was contracted to review the information available to support surface barrier evaluation for the deep vadose zone, identify gaps in the information and outcomes necessary to fill the data gaps, and outline

  16. Microsoft Word - Groundwater Discharge Permit

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    State Renews Groundwater Discharge Permit for WIPP CARLSBAD, N.M., September 11, 2008 - The New Mexico Environment Department (NMED) has renewed the U.S. Department of Energy's (DOE) Waste Isolation Pilot Plant (WIPP) groundwater discharge permit until 2013. The permit regulates the discharge of water from WIPP facilities and operations to lined ponds, which protect groundwater resources. The permit allows WIPP to discharge domestic wastewater, non-hazardous wastewater and storm water into 13

  17. Implementation of ORR Groundwater Strategy

    Office of Environmental Management (EM)

    ... modeling * Summary of progress in annual Remediation Effectiveness Report Groundwater Program ... * first sampling event in FY 2015 Q2 was successfully completed ...

  18. TWDB Groundwater Conservation Districts website | Open Energy...

    Open Energy Info (EERE)

    TWDB Groundwater Conservation Districts website Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: TWDB Groundwater Conservation...

  19. Groundwater Periodic Monitoring Reports | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Groundwater Periodic Monitoring Reports Groundwater Periodic Monitoring Reports Topic: David Rhodes DOE, Provided Information on the Watersheds at LANL and the Monitoring Schedule ...

  20. California Groundwater Management Plans | Open Energy Information

    Open Energy Info (EERE)

    Groundwater Management Plans Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- OtherOther: California Groundwater Management PlansLegal Published...

  1. Anatomy of a Groundwater Uranium Plume

    Office of Energy Efficiency and Renewable Energy (EERE)

    Groundwater containing legacy contaminants (pollutants that remain after their sources have been controlled) moves through aquifers in response to the hydraulic gradient. As the groundwater moves,...

  2. 300 Area Process Trenches Groundwater Monitoring Plan

    SciTech Connect (OSTI)

    Lindberg, Jonathan W.; Chou, Charissa J.

    2001-08-13

    This document is a proposed groundwater monitoring plan for the 300 Area process trenches to comply with RCRA final status, corrective action groundwater monitoring.

  3. Monitoring probe for groundwater flow

    DOE Patents [OSTI]

    Looney, B.B.; Ballard, S.

    1994-08-23

    A monitoring probe for detecting groundwater migration is disclosed. The monitor features a cylinder made of a permeable membrane carrying an array of electrical conductivity sensors on its outer surface. The cylinder is filled with a fluid that has a conductivity different than the groundwater. The probe is placed in the ground at an area of interest to be monitored. The fluid, typically saltwater, diffuses through the permeable membrane into the groundwater. The flow of groundwater passing around the permeable membrane walls of the cylinder carries the conductive fluid in the same general direction and distorts the conductivity field measured by the sensors. The degree of distortion from top to bottom and around the probe is precisely related to the vertical and horizontal flow rates, respectively. The electrical conductivities measured by the sensors about the outer surface of the probe are analyzed to determine the rate and direction of the groundwater flow. 4 figs.

  4. Monitoring probe for groundwater flow

    DOE Patents [OSTI]

    Looney, Brian B.; Ballard, Sanford

    1994-01-01

    A monitoring probe for detecting groundwater migration. The monitor features a cylinder made of a permeable membrane carrying an array of electrical conductivity sensors on its outer surface. The cylinder is filled with a fluid that has a conductivity different than the groundwater. The probe is placed in the ground at an area of interest to be monitored. The fluid, typically saltwater, diffuses through the permeable membrane into the groundwater. The flow of groundwater passing around the permeable membrane walls of the cylinder carries the conductive fluid in the same general direction and distorts the conductivity field measured by the sensors. The degree of distortion from top to bottom and around the probe is precisely related to the vertical and horizontal flow rates, respectively. The electrical conductivities measured by the sensors about the outer surface of the probe are analyzed to determine the rate and direction of the groundwater flow.

  5. Bioremediation of contaminated groundwater

    DOE Patents [OSTI]

    Hazen, T.C.; Fliermans, C.B.

    1995-01-24

    An apparatus and method are described for in situ remediation of contaminated subsurface soil or groundwater contaminated by chlorinated hydrocarbons. A nutrient fluid is selected to stimulate the growth and reproduction of indigenous subsurface microorganisms that are capable of degrading the contaminants. An oxygenated fluid is selected to create a generally aerobic environment for these microorganisms to degrade the contaminants, leaving only pockets that are anaerobic. The nutrient fluid is injected periodically while the oxygenated fluid is injected continuously and both are extracted so that both are drawn across the plume. The nutrient fluid stimulates microbial colony growth. Withholding it periodically forces the larger, healthy colony of microbes to degrade the contaminants. Treatment is continued until the subsurface concentration of contaminants is reduced to an acceptable, preselected level. The nutrient fluid can be methane and the oxygenated fluid air for stimulating production of methanotrophs to break down chlorohydrocarbons, especially trichloroethylene (TCE) and tetrachloroethylene. 3 figures.

  6. Bioremediation of contaminated groundwater

    DOE Patents [OSTI]

    Hazen, Terry C.; Fliermans, Carl B.

    1995-01-01

    An apparatus and method for in situ remediation of contaminated subsurface soil or groundwater contaminated by chlorinated hydrocarbons. A nutrient fluid is selected to stimulate the growth and reproduction of indigenous subsurface microorganisms that are capable of degrading the contaminants; an oxygenated fluid is selected to create a generally aerobic environment for these microorganisms to degrade the contaminants, leaving only pockets that are anaerobic. The nutrient fluid is injected periodically while the oxygenated fluid is injected continuously and both are extracted so that both are drawn across the plume. The nutrient fluid stimulates microbial colony growth; withholding it periodicially forces the larger, healthy colony of microbes to degrade the contaminants. Treatment is continued until the subsurface concentration of contaminants is reduced to an acceptable, preselected level. The nutrient fluid can be methane and the oxygenated fluid air for stimulating production of methanotrophs to break down chlorohydrocarbons, especially trichloroethylene (TCE) and tetrachloroethylene.

  7. Bioremediation of contaminated groundwater

    DOE Patents [OSTI]

    Hazen, T.C.; Fliermans, C.B.

    1994-01-01

    Disclosed is an apparatus and method for in situ remediation of contaminated subsurface soil or groundwater contaminated by chlorinated hydrocarbons. A nutrient fluid (NF) is selected to simulated the growth and reproduction of indigenous subsurface microorganisms capable of degrading the contaminants; an oxygenated fluid (OF) is selected to create an aerobic environment with anaerobic pockets. NF is injected periodically while OF is injected continuously and both are extracted so that both are drawn across the plume. NF stimulates microbial colony growth; withholding it periodically forces the larger, healthy colony of microbes to degrade the contaminants. Treatment is continued until the subsurface concentration of contaminants is acceptable. NF can be methane and OF be air, for stimulating production of methanotrophs to break down chlorohydrocarbons, especially TCE and tetrachloroethylene.

  8. Kauai Groundwater Flow Model

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Groundwater flow model for Kauai. Data is from the following sources: Whittier, R. and A.I. El-Kadi. 2014. Human and Environmental Risk Ranking of Onsite Sewage Disposal Systems For the Hawaiian Islands of Kauai, Molokai, Maui, and Hawaii – Final. Prepared by the University of Hawaii, Dept. of Geology and Geophysics for the State of Hawaii Dept. of Health, Safe Drinking Water Branch. September 2014.; and Whittier, R.B., K. Rotzoll, S. Dhal, A.I. El-Kadi, C. Ray, G. Chen, and D. Chang. 2004. Hawaii Source Water Assessment Program Report – Volume IV – Island of Kauai Source Water Assessment Program Report. Prepared for the Hawaii Department of Health, Safe Drinking Water Branch. University of Hawaii, Water Resources Research Center. Updated 2015.

  9. Kauai Groundwater Flow Model

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Groundwater flow model for Kauai. Data is from the following sources: Whittier, R. and A.I. El-Kadi. 2014. Human and Environmental Risk Ranking of Onsite Sewage Disposal Systems For the Hawaiian Islands of Kauai, Molokai, Maui, and Hawaii Final. Prepared by the University of Hawaii, Dept. of Geology and Geophysics for the State of Hawaii Dept. of Health, Safe Drinking Water Branch. September 2014.; and Whittier, R.B., K. Rotzoll, S. Dhal, A.I. El-Kadi, C. Ray, G. Chen, and D. Chang. 2004. Hawaii Source Water Assessment Program Report Volume IV Island of Kauai Source Water Assessment Program Report. Prepared for the Hawaii Department of Health, Safe Drinking Water Branch. University of Hawaii, Water Resources Research Center. Updated 2015.

  10. Soil & Groundwater Home - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Soil & Groundwater Home Soil & Groundwater Home Annual Reports Environmental Data Access Administrative Record Soil & Groundwater Home Email Email Page | Print Print Page | Text Increase Font Size Decrease Font Size Soil & Groundwater Home Annual Reports Environmental Data Access Administrative Record Share on Last Updated 08/28/2016 4:15

  11. Groundwater in the Regional Aquifer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Groundwater in the Regional Aquifer Groundwater in the Regional Aquifer LANL maintains an extensive groundwater monitoring and surveillance program through sampling. August 1, 2013 Conceptual model of water movement and geology at Los Alamos National Laboratory Conceptual model of water movement and geology at Los Alamos National Laboratory RELATED IMAGES http://farm4.staticflickr.com/3749/9827580556_473a91fd78_t.jpg Enlarge http://farm3.staticflickr.com/2856/9804364405_b25f74cbb2_t.jpg En

  12. Groundwater Report Goes Online, Interactive

    Broader source: Energy.gov [DOE]

    RICHLAND, Wash. – EM’s Richland Operations Office (RL) has moved its 1,200-page annual report on groundwater monitoring to a fully online and interactive web application.

  13. Ground-water in Texas

    SciTech Connect (OSTI)

    Ward-McLemore, E.

    1985-01-01

    Amount 61% of the water used by Texans is ground-water. Some areas, both municipal and rural, depend entirely on ground-water. In many areas long term withdrawal is lowering the water levels, causing surface land subsidence, salt-water encroachment, and reducing future reservoir availability. The increasing probability of seepage from radioactive and toxic wastes, herbicide residues, septic systems, and oilfield brines is threatening dangerous contamination of fresh ground-water reservoirs. The Texas Department of Water Resources, the Texas Department of Health, State and private colleges and universities, the US Geological Survey, the Environmental Protection Agency, various underground water districts, among others, are cooperating with concerned hydrologists in a concentrated program to increase the efficiency of ground-water use and development, preserve the aquifer reservoirs, and decrease the pollution potential. 88 references.

  14. Liquid Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    Exploration Group: Geochemical Techniques Exploration Sub Group: Geochemical Data Analysis Parent Exploration Technique: Geothermometry Information Provided by Technique...

  15. Gas Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    Exploration Group: Geochemical Techniques Exploration Sub Group: Geochemical Data Analysis Parent Exploration Technique: Geothermometry Information Provided by Technique...

  16. Isotope Geothermometry | Open Energy Information

    Open Energy Info (EERE)

    Exploration Group: Geochemical Techniques Exploration Sub Group: Geochemical Data Analysis Parent Exploration Technique: Geothermometry Information Provided by Technique...

  17. NNSS Hosts Groundwater Open House

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Survey of the Bay Area NNSS Hosts Groundwater Open House A RSL helicopter spent part of August conducting aerial radiation flyovers in the California Bay Area. The team rocked the competition and chiseled out an impressive second place finish recently in the Security Protection Officer competition. Groundwater was the topic of discussion at a recent open house. See page 12. See page 5. See page 8. Enterprise Publication "ONEVOICE" Replaces Spotlight and SiteLines The Nevada National

  18. groundwater | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Groundwater Monitoring at NETL-Albany Ground Water Testing Program NETL is committed to the safety and health of its employees and of nearby residents and to protecting the environment. As part of a DOE environmental protection program, NETL initiated a ground water monitoring program in 2001 with the Oregon Department of Environmental Quality (DEQ) to evaluate the groundwater flowing beneath the Albany, OR facility. Ground water monitoring wells were installed at that time, and periodic samples

  19. Groundwater contamination from stormwater infiltration

    SciTech Connect (OSTI)

    Pitt, R.; Clark, S.; Parmer, K.

    1995-10-01

    The research summarized here was conducted during the first year of a 3-yr cooperative agreement (CR819573) to identify and control stormwater toxicants, especially those adversely affecting groundwater. The purpose of this research effort was to review the groundwater contamination literature as it relates to stormwater. Prior to urbanization groundwater is recharged by rainfall-runoff and snowmelt infiltrating through pervious surfaces including grasslands and woods. This infiltrating water is relatively uncontaminated. Urbanization, however, reduces the permeable soil surface area through which recharge by infiltration occurs. This results in much less groundwater recharge and greatly increased surface runoff. In addition the waters available for recharge carry increased quantities of pollutants. With urbanization, waters having elevated contaminant concentrations also recharge groundwater including effluent from domestic septic tanks, wastewater from percolation basins and industrial waste injection wells, infiltrating stormwater, and infiltrating water from agricultural irrigation. The areas of main concern that are covered by this paper are: the source of the pollutants, stormwater constituents having a high potential to contaminate groundwater, and the treatment necessary for stormwater.

  20. Hoe Creek groundwater restoration, 1989

    SciTech Connect (OSTI)

    Renk, R.R.; Crader, S.E.; Lindblom, S.R.; Covell, J.R.

    1990-01-01

    During the summer of 1989, approximately 6.5 million gallons of contaminated groundwater were pumped from 23 wells at the Hoe Creek underground coal gasification site, near Gillette, Wyoming. The organic contaminants were removed using activated carbon before the water was sprayed on 15.4 acres at the sites. Approximately 2647 g (5.8 lb) of phenols and 10,714 g (23.6 lb) of benzene were removed from the site aquifers. Phenols, benzene, toluene, ethylbenzene, and naphthalene concentrations were measured in 43 wells. Benzene is the only contaminant at the site exceeds the federal standard for drinking water (5 {mu}g/L). Benzene leaches into the groundwater and is slow to biologically degrade; therefore, the benzene concentration has remained high in the groundwater at the site. The pumping operation affected groundwater elevations across the entire 80-acre site. The water levels rebounded quickly when the pumping operation was stopped on October 1, 1989. Removing contaminated groundwater by pumping is not an effective way to clean up the site because the continuous release of benzene from coal tars is slow. Benzene will continue to leach of the tars for a long time unless its source is removed or the leaching rate retarded through mitigation techniques. The application of the treated groundwater to the surface stimulated plant growth. No adverse effects were noted or recorded from some 60 soil samples taken from twenty locations in the spray field area. 20 refs., 52 figs., 8 tabs.

  1. EM Soil and Groundwater Database Reports | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EM Soil and Groundwater Database Reports EM Soil and Groundwater Database Reports Brookhaven National Laboratory - HFBR Tritium Groundwater Database Report - Brookhaven National ...

  2. Factors Effecting the Fate and Transport of CL-20 in the Vadose Zone and Groundwater: Final Report 2002 - 2004 SERDP Project CP-1255

    SciTech Connect (OSTI)

    Szecsody, James E.; Riley, Robert G.; Devary, Brooks J.; Girvin, Donald C.; Resch, Charles T.; Campbell, James A.; Fredrickson, Herbert L.; Thompson, Karen T.; Crocker, Fiona H.; Qasim, Mohammad M.; Gamerdinger, Amy P.; Lemond, Luke A.

    2005-06-01

    This SERDP-funded project was initiated to investigate the fate of CL-20 in the subsurface environment, with a focus on identification and quantification of geochemical and microbial reactions of CL-20. CL-20 can be released to the surface and subsurface terrestrial environment by: a) manufacturing processes, b) munition storage, and c) use with low order detonation or unexploded ordnance. The risk of far-field subsurface migration was assessed through labora-tory experiments with a variety of sediments and subsurface materials to quantify processes that control CL-20 sorption-limited migration and degradation. Results of this study show that CL-20 will exhibit differing behavior in the subsurface terrestrial environment: 1. CL-20 on the sediment surface will photodegrade and interact with plants/animals (described in other SERDP projects CU 1254, 1256). CL-20 will exhibit greater sorption in humid sediments to organic matter. Transport will be solubility limited (i.e., low CL-20 aqueous solubility). 2. CL-20 infiltration into soils (<2 m) from spills will be subject to sorption to soil organic matter (if present), and low to high biodegradation rates (weeks to years) depending on the microbial population (greater in humid environment). 3. CL-20 in the vadose zone (>2 m) will be, in most cases, subject to low sorption and low degradation rates, so would persist in the subsurface environment and be at risk for deep migration. Low water content in arid regions will result in a decrease in both sorption and the degradation rate. Measured degradation rates in unsaturated sediments of years would result in significant subsurface migration distances. 4. CL-20 in groundwater will be subject to some sorption but likely very slow degradation rates. CL-20 sorption will be greater than RDX. Most CL-20 degradation will be abiotic (ferrous iron and other transition metals), because most deep subsurface systems have extremely low natural microbial populations. Degradation rates

  3. INTEC Groundwater Monitoring Report 2006

    SciTech Connect (OSTI)

    J. R. Forbes S. L. Ansley M. Leecaster

    2007-02-01

    This report summarizes 2006 perched water and groundwater monitoring activities at the Idaho Nuclear Technology and Engineering Center (INTEC) located at the Idaho National Laboratory (INL). During 2006, groundwater samples were collected from a total of 22 Snake River Plain Aquifer (SRPA) monitoring wells, plus six aquifer wells sampled for the Idaho CERCLA Disposal Facility (ICDF) monitoring program. In addition, perched water samples were collected from 21 perched wells and 19 suction lysimeters. Groundwater and perched water samples were analyzed for a suite of radionuclides and inorganic constituents. Laboratory results in this report are compared to drinking water maximum contaminant levels (MCLs). Such comparison is for reference only and it should be noted that the Operable Unit 3-13 Record of Decision does not require that perched water comply with drinking water standards.

  4. Shiprock Archived Soil & Groundwater Master Reports | Department of Energy

    Office of Environmental Management (EM)

    Shiprock Archived Soil & Groundwater Master Reports Shiprock Archived Soil & Groundwater Master Reports Shiprock Archived Soil & Groundwater Master Reports Shiprock - Shiprock (19.31 KB) More Documents & Publications Slick Rock Archived Soil & Groundwater Master Reports Tuba City Archived Soil & Groundwater Master Reports Spook Archived Soil & Groundwater Master Reports

  5. Spook Archived Soil & Groundwater Master Reports | Department of Energy

    Office of Environmental Management (EM)

    Spook Archived Soil & Groundwater Master Reports Spook Archived Soil & Groundwater Master Reports Spook Archived Soil & Groundwater Master Reports Spook - Spook (17.91 KB) More Documents & Publications Tuba City Archived Soil & Groundwater Master Reports Slick Rock Archived Soil & Groundwater Master Reports Weldon Spring Site Archived Soil & Groundwater Master Reports

  6. Hanford Story: Groundwater - Questions - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Hanford Story Hanford Story: Groundwater - Questions The Hanford Story Email Email Page | Print Print Page | Text Increase Font Size Decrease Font Size How did contamination get into the groundwater beneath the Hanford Site? What has caused the level of contamination to decrease over the years? What is the 2015 vision for Hanford? What is the goal of the water treatment systems and facilities? What is being done to treat groundwater to remove contamination? Is contaminated groundwater

  7. RDX in Groundwater | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    RDX in Groundwater RDX in Groundwater Topic: Tim Goering LANL, Provided Information on the RDX Groundwater Plume that is Located Under Technical Area 16 at Los Alamos. Information on Monitoring and Possible Clean-up Solutions was Given. RDX Update - July 8, 2015 (1.97

  8. Sanitary landfill groundwater monitoring data

    SciTech Connect (OSTI)

    Thompson, C.Y.

    1992-05-01

    This report for first quarter 1992 contains sanitary landfill groundwater monitoring data for the Savannah River Plant. The data tables presented in this report are copies of draft analytical results and therefore do contain errors. These errors will be corrected when the finalized data is received from the laboratory.

  9. Removing High Explosives from Groundwater

    Broader source: Energy.gov [DOE]

    LOS ALAMOS, N.M. – In an initiative supported by EM, Los Alamos National Laboratory’s Corrective Actions Program is addressing high explosive contamination in surface water and groundwater at a location this summer in the forests surrounding the laboratory.

  10. Work plan for the Oak Ridge National Laboratory groundwater program: Continuous groundwater collection

    SciTech Connect (OSTI)

    NONE

    1995-08-01

    The continuous collection of groundwater data is a basic and necessary part of Lockeheed Martin Energy Systems` ORNL Environmental Restoration Area-Wide Groundwater Program. Continuous groundwater data consist primarily of continually recorded groundwater levels, and in some instances, specific conductivity, pH, and/or temperature measurements. These data will be collected throughout the ORNL site. This Work Plan (WP) addresses technical objectives, equipment requirements, procedures, documentation requirements, and technical instructions for the acquisition of the continuous groundwater data. Intent of this WP is to provide an approved document that meets all the necessary requirements while retaining the flexibility necessary to effectively address ORNL`s groundwater problems.

  11. Groundwater Under Review Marathon Man

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Under Review Marathon Man NNSS team welcomes peer review of groundwater program. Nevada Teams compete in the National Science Bowl in Washington. NSTec runner finishes first Boston Marathon. See page 7. See page 6. NNSS Roads Getting a Fresh Makeover Highways, roads, parking lots - any place that has seen at least 60 years of traffic like the Nevada National Security Site (NNSS) has - will experience some normal wear and tear. That is why National Security Technologies (NSTec) is doing some

  12. Situ treatment of contaminated groundwater

    DOE Patents [OSTI]

    McNab, Jr., Walt W.; Ruiz, Roberto; Pico, Tristan M.

    2001-01-01

    A system for treating dissolved halogenated organic compounds in groundwater that relies upon electrolytically-generated hydrogen to chemically reduce the halogenated compounds in the presence of a suitable catalyst. A direct current is placed across at least a pair, or an array, of electrodes which are housed within groundwater wells so that hydrogen is generated at the cathode and oxygen at the anode. A pump is located within the well housing in which the cathode(s) is(are) located and draws in groundwater where it is hydrogenated via electrolysis, passes through a well-bore treatment unit, and then transported to the anode well(s) for reinjection into the ground. The well-bore treatment involves a permeable cylinder located in the well bore and containing a packed bed of catalyst material that facilitates the reductive dehalogenation of the halogenated organic compounds by hydrogen into environmentally benign species such as ethane and methane. Also, electro-osmatic transport of contaminants toward the cathode also contributes to contaminant mass removal. The only above ground equipment required are the transfer pipes and a direct circuit power supply for the electrodes. The electrode wells in an array may be used in pairs or one anode well may be used with a plurality of cathode wells. The DC current flow between electrode wells may be periodically reversed which controls the formation of mineral deposits in the alkaline cathode well-bore water, as well as to help rejuvenate the catalysis.

  13. NNSS Groundwater Program Welcomes Peer Review Team

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    April 18, 2014 NNSS Groundwater Program Welcomes Peer Review Team Recently, an independent peer review team was invited to assess the groundwater characterization program at the Nevada National Security Site (NNSS). This nationally recognized group of experts, from various external organizations, will examine the computer modeling approach developed to better understand how historic underground nuclear testing in Yucca Flat affected the groundwater. From April 7th to 11th, 2014, five peer

  14. Groundwater Update K. Michael Thompson Soil and Groundwater Division Richland Operations Office

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Update Jon Peschong Richland Operations Office May 2015 2 billion gallons of contaminated groundwater treated tons of contaminants removed in all pump and treat systems since the facilities began operating 12 171 HANFORD SITE GROUNDWATER NUMBERS billion of gallons of groundwater treated in 2014 1.95 tons of contaminants removed in 2014 62 3 Groundwater Key Focus Areas * Expand pump and treat systems - Continue pump and treat operations - Install and connect new and existing wells to maximize

  15. Evapotranspiration Dynamics and Effects on Groundwater Recharge...

    Office of Scientific and Technical Information (OSTI)

    Prepared for U.S. DEPARTMENT OF ENERGY Legacy Management This page intentionally ... Tuba City UMTRCA site..... 11 Figure 3. Green LAI within the Tuba City groundwater model ...

  16. Groundwater Withdrawal Permit Application | Open Energy Information

    Open Energy Info (EERE)

    Withdrawal Permit ApplicationLegal Abstract This application initiates the Drinking Water and Groundwater Protection Division's, a division of the Department of Environmental...

  17. DEQ Groundwater Permitting Guidebook | Open Energy Information

    Open Energy Info (EERE)

    search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - GuideHandbook: DEQ Groundwater Permitting GuidebookPermittingRegulatory GuidanceGuide...

  18. Compendium of ordinances for groundwater protection

    SciTech Connect (OSTI)

    Not Available

    1990-08-01

    Groundwater is an extremely important resource in the Tennessee Valley. Nearly two-thirds of the Tennessee Valley's residents rely, at least in part, on groundwater supplies for drinking water. In rural areas, approximately ninety-five percent of residents rely on groundwater for domestic supplies. Population growth and economic development increase the volume and kinds of wastes requiring disposal which can lead to groundwater contamination. In addition to disposal which can lead to groundwater contamination. In addition to disposal problems associated with increases in conventional wastewater and solid waste, technological advancements in recent decades have resulted in new chemicals and increased usage in agriculture, industry, and the home. Unfortunately, there has not been comparable progress in identifying the potential long-term effects of these chemicals, in managing them to prevent contamination of groundwater, or in developing treatment technologies for removing them from water once contamination has occurred. The challenge facing residence of the Tennessee Valley is to manage growth and economic and technological development in ways that will avoid polluting the groundwater resource. Once groundwater has been contaminated, cleanup is almost always very costly and is sometimes impractical or technically infeasible. Therefore, prevention of contamination -- not remedial treatment--is the key to continued availability of usable groundwater. This document discusses regulations to aid in this prevention.

  19. Montana Groundwater Information Center Webpage | Open Energy...

    Open Energy Info (EERE)

    Center Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Montana Groundwater Information Center Webpage Abstract Provides access to...

  20. Vermont Groundwater Withdrawal Report | Open Energy Information

    Open Energy Info (EERE)

    Not Provided DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for Vermont Groundwater Withdrawal Report Citation Vermont Agency of Natural...

  1. Hanford Treats Record Amount of Groundwater

    Broader source: Energy.gov [DOE]

    Workers have treated more than 800 million gallons of groundwater at the Hanford Site so far this year, a record annual amount.

  2. Evapotranspiration Dynamics and Effects on Groundwater Recharge...

    Office of Scientific and Technical Information (OSTI)

    Vegetation type and health had a significant effect on the site water balance. Plant cover ... Heavy grazing increased groundwater recharge (PPT > ET over the 13-year period). ...

  3. Wellbore and groundwater temperature distribution eastern Snake River

    Office of Scientific and Technical Information (OSTI)

    Plain, Idaho: Implications for groundwater flow and geothermal potential (Journal Article) | SciTech Connect Journal Article: Wellbore and groundwater temperature distribution eastern Snake River Plain, Idaho: Implications for groundwater flow and geothermal potential Citation Details In-Document Search Title: Wellbore and groundwater temperature distribution eastern Snake River Plain, Idaho: Implications for groundwater flow and geothermal potential A map of groundwater temperatures from

  4. Portsmouth Gaseous Diffusion Plant- Quadrant I Groundwater Investigative (5-Unit) Area Plume

    Broader source: Energy.gov [DOE]

    Groundwater Database Report - Portsmouth Gaseous Diffusion Plant - Quadrant I Groundwater Investigative (5-Unit) Area Plume

  5. Recovery Act Supports Construction of Site's Largest Groundwater...

    Office of Environmental Management (EM)

    Supports Construction of Site's Largest Groundwater Treatment Facility Recovery Act Supports Construction of Site's Largest Groundwater Treatment Facility Construction of the ...

  6. Passive Groundwater Cleanup Measures Save Savannah River Site...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Passive Groundwater Cleanup Measures Save Savannah River Site Millions of Dollars Passive Groundwater Cleanup Measures Save Savannah River Site Millions of Dollars November 25, ...

  7. Savannah River Site - L-Area Southern Groundwater | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    L-Area Southern Groundwater Savannah River Site - L-Area Southern Groundwater January 1, ... InstallationName, State: Savannah River Site, SC Responsible DOE Office: Savannah River ...

  8. Savannah River Site - R-Area Groundwater Operable Unit | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    R-Area Groundwater Operable Unit Savannah River Site - R-Area Groundwater Operable Unit ... InstallationName, State: Savannah River Site, SC Responsible DOE Office: Savannah River ...

  9. South Valley Archived Soil & Groundwater Master Reports | Department...

    Broader source: Energy.gov (indexed) [DOE]

    South Valley Archived Soil & Groundwater Master Reports South Valley - South Valley Plume (16.5 KB) More Documents & Publications Slick Rock Archived Soil & Groundwater Master ...

  10. Rocky Flats Environmental Technology Site Archived Soil & Groundwater...

    Office of Environmental Management (EM)

    Rocky Flats Environmental Technology Site Archived Soil & Groundwater Master Reports Rocky Flats Environmental Technology Site Archived Soil & Groundwater Master Reports Rocky ...

  11. Structure and Groundwater Flow in the Espanola Basin Near Rio...

    Office of Environmental Management (EM)

    Structure and Groundwater Flow in the Espanola Basin Near Rio Grande and Buckman Wellfield Structure and Groundwater Flow in the Espanola Basin Near Rio Grande and Buckman...

  12. New Resin Brings Efficiencies to Groundwater Treatment along...

    Broader source: Energy.gov (indexed) [DOE]

    A new treatment material is expected to increase groundwater treatment efficiency and ... A new treatment material is expected to increase groundwater treatment efficiency and ...

  13. Recommendation 222: Recommendations on Additional Off-site Groundwater...

    Office of Environmental Management (EM)

    2: Recommendations on Additional Off-site Groundwater Migration Studies Recommendation 222: Recommendations on Additional Off-site Groundwater Migration Studies ORSSAB recommends...

  14. Rocky Flats Site Expands Solar Power for Treating Groundwater...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Rocky Flats Site Expands Solar Power for Treating Groundwater Rocky Flats Site Expands Solar Power for Treating Groundwater April 17, 2013 - 1:26pm Addthis Subcontractor personnel ...

  15. Evaluation of Pre- and Post-Redevelopment Groundwater Chemical...

    Office of Environmental Management (EM)

    Evaluation of Pre- and Post-Redevelopment Groundwater Chemical Analyses from LM Monitoring Wells Evaluation of Pre- and Post-Redevelopment Groundwater Chemical Analyses from LM ...

  16. http://www.lvvwd.com/about/wr_groundwater.html

    National Nuclear Security Administration (NNSA)

    Water Resources Groundwater About 10 percent of the Las Vegas Valley's water comes from groundwater, which is a water supply under the Earth's surface. In some areas, water...

  17. Portsmouth Gaseous Diffusion Plant - Quadrant I Groundwater Investigat...

    Office of Environmental Management (EM)

    Portsmouth Gaseous Diffusion Plant - Quadrant I Groundwater Investigative (5-Unit) Area Plume Portsmouth Gaseous Diffusion Plant - Quadrant I Groundwater Investigative (5-Unit) ...

  18. Procedures for ground-water investigations

    SciTech Connect (OSTI)

    Not Available

    1992-12-01

    This manual was developed by the Pacific Northwest Laboratory (PNL) to document the procedures used to carry out and control the technical aspects of ground-water investigations at the PNL. Ground-water monitoring procedures are developed and used in accordance with the PNL Quality Assurance Program.

  19. Final Report Coupled In Silico Microbial and Geochemical Reactive Transport Models: Extension to Multi-Organism Communities, Upscaling, and Experimental Validation

    SciTech Connect (OSTI)

    Lovley, Derek R.

    2014-03-05

    The project was highly successful in improving the understanding of physiological and ecological factors controlling the growth and interaction of subsurface microorganisms and in developing better strategies for in silico modeling of the interactions of subsurface microorganisms with other species and their environment.

  20. Integrated model for the natural flow regime in the Cerro Prieto hydrothermal system, B. C. , Mexico, based upon petrological and isotope geochemical criteria

    SciTech Connect (OSTI)

    Elders, W.A.; Williams, A.E.; Hoagland, J.R.

    1981-01-01

    Studies of cuttings and core at Cerro Prieto have now been extended to more than 50 boreholes. The aims of this petrological and isotopic work are to determine the shape of the reservoir, its physical properties, and its temperature distribution and flow regime before the steam field was produced. A map showing the first occurrence of hydrothermal epidote shows a dome-shaped top to the steam-producing zone. The hottest of the mapped mineral zones - the biotite vermiculite zone - shows a dome displaced to the northeast relative to the epidote zone. Patterns of mineral zones observed in wells are consistent with patterns of oxygen isotopic ratios in calcite and quartz. Using both criteria all of the boreholes so far studied were classified as belonging to one of four different regimes. These are: (a) the thermal plume of upward flowing water close to boiling, marked by a regular sequence of prograde mineral zones and large isotopic shifts; (b) the discharge system where fluid leaks to the surface, as indicated by the occurrence of only a few low temperature mineral zones, which extend over large depth intervals with little isotope exchange; (c) the horizontal flow zone, in which boreholes penetrate reversals of both mineral zones and isotope shifts with increasing depth; and (d) the recharge zone where cold water is descending. Plotting these four types of boreholes on a map reveals a simple, consistent, pattern. This is interpreted to have been produced by a thermal plume dipping at 45/sup 0/ to the northeast.

  1. Geochemical provenance of anomalous metal concentrations in stream sediments in the Ashton 1:250,000 quadrangle, Idaho/Montana/Wyoming

    SciTech Connect (OSTI)

    Shannon, S.S. Jr.

    1982-01-01

    Stream-sediment samples from 1500 sites in the Ashton, Idaho/Montana/Wyoming 1:250,000 quadrangle were analyzed for 45 elements. Almost all samples containing anomalous concentrations (exceeding one standard deviation above the mean value of any element) were derived from drainage basins underlain by Quaternary rhyolite, Tertiary andesite or Precambrian gneiss and schist. Aluminum, barium, calcium, cobalt, iron, nickel, magnesium, scandium, sodium, strontium, and vanadium have no andesite provenance. Most anomalous manganese, europium, hafnium, and zirconium values were derived from Precambrian rocks. All other anomalous elemental concentrations are related to Quaternary rhyolite. This study demonstrates that multielemental stream-sediment analyses can be used to infer the provenance of stream sediments. Such data are available for many parts of the country as a result of the National Uranium Resource Evaluation. This study suggests that stream-sediment samples collected in the Rocky Mountains can be used either as pathfinders or as direct indicators to select targets for mineral exploration for a host of metals.

  2. Geochemical determination of biospheric CO/sub 2/ fluxes to the atmosphere. Annual progress report, June 1, 1979-August 31, 1981

    SciTech Connect (OSTI)

    Stuiver, M

    1981-03-24

    Research progress is reported - for an investigation of aspects of the carbon cycle through the use of C13/C12 and C14/C12 abundance ratios. The objective is to increase knowledge of past biospheric carbon reservoir changes that have resulted in increases or reductions of atmospheric CO/sub 2/ levels. C13 trends in trees from Kodiak Island, Alaska, and from Chile were determined. (ACR)

  3. Microbiological, Geochemical and Hydrologic Processes Controlling Uranium Mobility: An Integrated Field Scale Subsurface Research Challenge Site at Rifle, Colorado, February 2011 to January 2012

    SciTech Connect (OSTI)

    Long, Philip E.; Banfield, Jill; Chandler, Darrell P.; Davis, James A.; Hettich, Bob; VerBerkmoes, Nathan; Jaffe, Peter R.; Kerkhof, Lee J.; Kukkadapu, Ravi K.; Lipton, Mary; Peacock, Aaron; Williams, Kenneth H.; Yabusaki, Steven B.

    2012-02-15

    The Rifle IFRC continued to make excellent progress during the last 12 months. As noted above, a key field experiment (Best Western) was performed during 2011 as a logical follow-on to the Super 8 field experiment preformed in 2010. In the Super 8 experiment, we successfully combined desorption and bioreduction and deployed a number of novel tracer techniques to enhance our ability to interpret the biogeochemistry of the experiment. In the Best Western experiment, we used the same experimental plot (Plot C) as was used for Super 8. The overarching objective of the Best Western field experiment was to compared the impacts of abiotic vs. biotic increases in alkalinity and to assess the mass of the sorbed pool of U(VI) at Rifle at the field scale. Both of these objectives were met. Preliminary analysis of the data indicate that the underlying biogeochemical data sets were obtained that will support a mechanistic understanding of the underlying processes, including remarkable insight into previously unrecognized microbial processes taking place during acetate amendment of the subsurface for a second time.

  4. Geochemical Water and Sediment Data: Reformatted Data from the National Uranium Resource Evaluation (NURE) Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) Program

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Smith, Steven M. [USGS

    The National Uranium Resource Evaluation (NURE) program was initiated by the Atomic Energy Commission (AEC) in 1973 with a primary goal of identifying uranium resources in the United States. The Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) program (initiated in 1975) was one of nine components of NURE. Planned systematic sampling of the entire United States began in 1976 under the responsibility of four DOE national laboratories: Lawrence Livermore Laboratory (LLL), Los Alamos Scientific Laboratory (LASL), Oak Ridge Gaseous Diffusion Plant (ORGDP), and Savannah River Laboratory (SRL). The NURE program effectively ended about 1983-84 when funding disappeared. Out of a total of 625 quadrangles that cover the entire lower 48 States and Alaska, only 307 quadrangles were completely sampled, some were partially completed, and many had not been done at all. Over the years various efforts have been made to finish the original task or analyze the stored samples or complete final reports. The sample archive was transferred to the U.S. Geological Survey (USGS) in 1985. The archive reportedly contained about 380,000 original sediment samples from all four laboratories, about 250,000 replicates, splits, size fractions or other samples and approximately 500,000 resin samples of waters.

  5. Examination Report: OAS-RA-13-05 | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    from LM Monitoring Wells | Department of Energy AS&T Ancillary Work Plan (AWP) Final Well Redevelopment Evaluation Report Evaluation of Pre- and Post-Redevelopment Groundwater Chemical Analyses from LM Monitoring Wells (3.25 MB) More Documents & Publications Analysis and Geochemical Modeling of Vanadium Contamination in Groundwater New Rifle Processing Site, Colorado Title I Disposal Sites Annual Report Ground-Water Table and Chemical Changes in an Alluvial Aquifer During Sustained

  6. U.S. DEPARTMENT OF ENERGY * SAVANNAH RIVER SITE * AIKEN * SC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This innovative solution provides a more energy efficient and sustainable approach to protect the environment from the spread of hazardous chemicals. Where treatment of contaminated groundwater currently requires the active, expensive, and energy intensive process of pumping water to the surface for treatment, this new approach demonstrates that natural groundwater flow can be engineered to create groundwater retention and treatment zones where specifically designed geo-chemical processes can be

  7. East Maui Groundwater Flow Model

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Groundwater flow model for East Maui. Data is from the following sources: Whittier, R. and A.I. El-Kadi. 2014. Human and Environmental Risk Ranking of Onsite Sewage Disposal Systems For the Hawaiian Islands of Kauai, Molokai, Maui, and Hawaii – Final. Prepared by the University of Hawaii, Dept. of Geology and Geophysics for the State of Hawaii Dept. of Health, Safe Drinking Water Branch. September 2014; and Whittier, R.B., K. Rotzoll, S. Dhal, A.I. El-Kadi, C. Ray, G. Chen, and D. Chang. 2004. Hawaii Source Water Assessment Program Report – Volume V – Island of Maui Source Water Assessment Program Report. Prepared for the Hawaii Department of Health, Safe Drinking Water Branch. University of Hawaii, Water Resources Research Center. Updated 2008.

  8. Hawaii Island Groundwater Flow Model

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Groundwater flow model for Hawaii Island. Data is from the following sources: Whittier, R.B., K. Rotzoll, S. Dhal, A.I. El-Kadi, C. Ray, G. Chen, and D. Chang. 2004. Hawaii Source Water Assessment Program Report – Volume II – Island of Hawaii Source Water Assessment Program Report. Prepared for the Hawaii Department of Health, Safe Drinking Water Branch. University of Hawaii, Water Resources Research Center. Updated 2008; and Whittier, R. and A.I. El-Kadi. 2014. Human and Environmental Risk Ranking of Onsite Sewage Disposal Systems For the Hawaiian Islands of Kauai, Molokai, Maui, and Hawaii – Final. Prepared by the University of Hawaii, Dept. of Geology and Geophysics for the State of Hawaii Dept. of Health, Safe Drinking Water Branch. September 2014.

  9. West Maui Groundwater Flow Model

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Groundwater flow model for West Maui. Data is from the following sources: Whittier, R. and A.I. El-Kadi. 2014. Human and Environmental Risk Ranking of Onsite Sewage Disposal Systems For the Hawaiian Islands of Kauai, Molokai, Maui, and Hawaii – Final. Prepared by the University of Hawaii, Dept. of Geology and Geophysics for the State of Hawaii Dept. of Health, Safe Drinking Water Branch. September 2014; and Whittier, R.B., K. Rotzoll, S. Dhal, A.I. El-Kadi, C. Ray, G. Chen, and D. Chang. 2004. Hawaii Source Water Assessment Program Report – Volume V – Island of Maui Source Water Assessment Program Report. Prepared for the Hawaii Department of Health, Safe Drinking Water Branch. University of Hawaii, Water Resources Research Center. Updated 2008.

  10. West Maui Groundwater Flow Model

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Nicole Lautze

    2015-01-01

    Groundwater flow model for West Maui. Data is from the following sources: Whittier, R. and A.I. El-Kadi. 2014. Human and Environmental Risk Ranking of Onsite Sewage Disposal Systems For the Hawaiian Islands of Kauai, Molokai, Maui, and Hawaii Final. Prepared by the University of Hawaii, Dept. of Geology and Geophysics for the State of Hawaii Dept. of Health, Safe Drinking Water Branch. September 2014; and Whittier, R.B., K. Rotzoll, S. Dhal, A.I. El-Kadi, C. Ray, G. Chen, and D. Chang. 2004. Hawaii Source Water Assessment Program Report Volume V Island of Maui Source Water Assessment Program Report. Prepared for the Hawaii Department of Health, Safe Drinking Water Branch. University of Hawaii, Water Resources Research Center. Updated 2008.

  11. Groundwater and Wastewater Remediation Using Agricultural Oils - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Groundwater and Wastewater Remediation Using Agricultural Oils Savannah River National Laboratory Contact SRNL About This Technology Soybean oil used for groundwater and wastewater remediation Soybean oil used for groundwater and wastewater remediation Technology Marketing Summary Scientists have developed a groundwater treatment technique that employs agricultural oils to stimulate endogenous microbes which accelerates the cleanup. The oils tested include canola oil,

  12. DOE Responds to Advisory Board Recommendation on Groundwater Studies

    Broader source: Energy.gov [DOE]

    The DOE Office of Environmental Management responds to an ORSSAB recommendation on additional groundwater studies.

  13. The Groundwater Performance Assessment Project Quality Assurance Plan

    SciTech Connect (OSTI)

    Walker, Thomas G.

    2005-01-26

    This document provides the quality assurance guidelines that will be followed by the groundwater project.

  14. Burn site groundwater interim measures work plan.

    SciTech Connect (OSTI)

    Witt, Jonathan L.; Hall, Kevin A.

    2005-05-01

    This Work Plan identifies and outlines interim measures to address nitrate contamination in groundwater at the Burn Site, Sandia National Laboratories/New Mexico. The New Mexico Environment Department has required implementation of interim measures for nitrate-contaminated groundwater at the Burn Site. The purpose of interim measures is to prevent human or environmental exposure to nitrate-contaminated groundwater originating from the Burn Site. This Work Plan details a summary of current information about the Burn Site, interim measures activities for stabilization, and project management responsibilities to accomplish this purpose.

  15. Groundwater Data Package for Hanford Assessments

    SciTech Connect (OSTI)

    Thorne, Paul D.; Bergeron, Marcel P.; Williams, Mark D.; Freedman, Vicky L.

    2006-01-31

    This report presents data and interpreted information that supports the groundwater module of the System Assessment Capability (SAC) used in Hanford Assessments. The objective of the groundwater module is to predict movement of radioactive and chemical contaminants through the aquifer to the Columbia River or other potential discharge locations. This data package is being revised as part of the deliverables under the Characterization of Systems Project (#49139) aimed at providing documentation for assessments being conducted under the Hanford Assessments Project (#47042). Both of these projects are components of the Groundwater Remediation and Closure Assessments Projects, managed by the Management and Integration Project (#47043).

  16. Audit of groundwater monitoring at Hanford

    SciTech Connect (OSTI)

    1996-11-15

    The Department of Energy (DOE), Richland Operations is responsible for ensuring that its contractors` tasks are mission oriented and are completed at the least cost to the DOE. The objective of this audit was to determine whether Richland was effectively managing its groundwater monitoring activities so that unnecessary duplication would not occur. The audit`s objective was accomplished by: reviewing laws and regulations; interviewing DOE and contractor personnel; examining procurement and accounting procedures; reviewing plans, budgets, and actual expenditures; reviewing utilization of the DOE drilling equipment; observing well drilling activities; comparing drilling cost to other DOE sites; analyzing groundwater monitoring activities; and, reviewing and comparing groundwater reports.

  17. LM Conducts Groundwater and Soil Investigation at Riverton, Wyoming, in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Response to 2010 Flood | Department of Energy Conducts Groundwater and Soil Investigation at Riverton, Wyoming, in Response to 2010 Flood LM Conducts Groundwater and Soil Investigation at Riverton, Wyoming, in Response to 2010 Flood October 16, 2012 - 10:50am Addthis LM Conducts Groundwater and Soil Investigation at Riverton, Wyoming, in Response to 2010 Flood LM Conducts Groundwater and Soil Investigation at Riverton, Wyoming, in Response to 2010 Flood LM Conducts Groundwater and Soil

  18. Soil & Groundwater Remediation News | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Soil & Groundwater Remediation News Soil & Groundwater Remediation News July 28, 2016 There are four groundwater treatment facilities located along the Columbia River at the Hanford Site including the HX Pump and Treat Facility as seen above. All groundwater treatment facilities are using the newer resin. Groundwater Treatment Resin Saves an Estimated $2 Million More Than Expected - Annual efficiency three times higher than original estimates RICHLAND, Wash. - In 2010, workers with EM's

  19. The Savannah River Site's Groundwater Monitoring Program

    SciTech Connect (OSTI)

    Not Available

    1990-10-18

    This report summarizes the Savannah River Site (SRS) groundwater monitoring program conducted in the first quarter of 1990. It includes the analytical data, field data, well activity data, and the other documentation for this program and provides a record of the program's activities and rationale and an official document of the analytical results. The groundwater monitoring program includes the following activities: installation, maintenance, and abandonment of monitoring wells, environmental soil borings, development of the sampling and analytical schedule, collection and analyses of groundwater samples, review of the analytical data and other data, maintenance of the databases containing groundwater monitoring data and related data, quality assurance (QA) evaluations of laboratory performance, and reports of results to waste-site facility custodians and to the Environmental Protection Section (EPS) of EPD.

  20. Nevada National Security Site Groundwater Program

    ScienceCinema (OSTI)

    None

    2014-10-28

    From 1951 to 1992, the Unites States government conducted 828 underground nuclear tests at the Nevada National Security Site. About one-third of these tests occurred near, below or within the water table - the very top portion of the groundwater layer where rock and soil are completely saturated with water. As a result, some groundwater was contaminated. The U.S. Department of Energy (DOE) began exploring the effects of groundwater contamination in the 1970s. Though contamination from underground testing has never been detected on public land, the DOE was committed to developing an advanced, reliable monitoring network that ensures the long-term protection of the public. An intensive groundwater investigation program was launched in 1989.

  1. Agency of Natural Resources Groundwater Withdrawal Reporting...

    Open Energy Info (EERE)

    Groundwater Withdrawal Reporting and Permitting RulesLegal Abstract This rule and strategy is adopted under the authority of 10 Vermont Statutes Annotated (V.S.A.) 1390-1394.10...

  2. Soil & Groundwater Remediation | Department of Energy

    Office of Environmental Management (EM)

    The inventory at the DOE sites includes 6.5 trillion liters of contaminated groundwater, an amount equal to about four times the daily U.S. water consumption, and 40 million cubic ...

  3. The Savannah River Site's Groundwater Monitoring Program

    SciTech Connect (OSTI)

    Not Available

    1991-06-18

    This report summarizes the Savannah River Site (SRS) groundwater monitoring program conducted in the fourth quarter of 1990. It includes the analytical data, field data, well activity data, and other documentation for this program, provides a record of the program's activities and rationale, and serves as an official document of the analytical results. The groundwater monitoring program includes the following activities: installation, maintenance, and abandonment of monitoring wells, environmental soil borings, development of the sampling and analytical schedule, collection and analyses of groundwater samples, review of analytical and other data, maintenance of the databases containing groundwater monitoring data, quality assurance (QA) evaluations of laboratory performance, and reports of results to waste-site facility custodians and to the Environmental Protection Section (EPS) of EPD.

  4. X-701B Groundwater Remedy Portsmouth Ohio

    Office of Environmental Management (EM)

    X-701B Groundwater Remediation ETR Report Date: December 2008 ETR-20 United States Department of Energy Office of Environmental Management (DOE-EM) External Technical Review of the X-701B Groundwater Remedy, Portsmouth, Ohio Why DOE-EM Did This Review The Department of Energy (DOE) Portsmouth Paducah Project Office (PPPO) has responsibility for remediation of the X-701B ground water plume with the key contaminant of trichloroethene (TCE). The remedy has been divided into four phases: Phase I-

  5. Appendix IGP: Individual and Groundwater Protection Requirements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    IGP-2014 Individual and Groundwater Protection Requirements United States Department of Energy Waste Isolation Pilot Plant Carlsbad Field Office Carlsbad, New Mexico Compliance Recertification Application 2014 Appendix IGP-2014 Individual and Groundwater Protection Requirements Table of Contents IGP-1.0 Introduction IGP-2.0 Individual Protection Requirements IGP-2.1 Compliance Assessment of Undisturbed Performance IGP-2.2 Dose Calculation IGP-2.2.1 Transport Pathway IGP-2.2.2 Bounding Analysis

  6. Groundwater Level Status Report for 2005 Los Alamos National Laboratory

    SciTech Connect (OSTI)

    S.P. Allen; R.J. Koch

    2006-05-15

    The status of groundwater level monitoring at Los Alamos National Laboratory (LANL) in 2005 is provided in this report. The Groundwater Level Monitoring Project was instituted in 2005 to provide a framework for the collection and processing of quality controlled groundwater level data. This report summarizes groundwater level data for 137 monitoring wells, including 41 regional aquifer wells, 22 intermediate wells, and 74 alluvial wells. Pressure transducers were installed in 118 monitoring wells for continuous monitoring of groundwater levels. Time-series hydrographs of groundwater level data are presented along with pertinent construction and location information for each well.

  7. Oxidative particle mixtures for groundwater treatment

    DOE Patents [OSTI]

    Siegrist, Robert L.; Murdoch, Lawrence C.

    2000-01-01

    The invention is a method and a composition of a mixture for degradation and immobilization of contaminants in soil and groundwater. The oxidative particle mixture and method includes providing a material having a minimal volume of free water, mixing at least one inorganic oxidative chemical in a granular form with a carrier fluid containing a fine grained inorganic hydrophilic compound and injecting the resulting mixture into the subsurface. The granular form of the inorganic oxidative chemical dissolves within the areas of injection, and the oxidative ions move by diffusion and/or advection, therefore extending the treatment zone over a wider area than the injection area. The organic contaminants in the soil and groundwater are degraded by the oxidative ions, which form solid byproducts that can sorb significant amounts of inorganic contaminants, metals, and radionuclides for in situ treatment and immobilization of contaminants. The method and composition of the oxidative particle mixture for long-term treatment and immobilization of contaminants in soil and groundwater provides for a reduction in toxicity of contaminants in a subsurface area of contamination without the need for continued injection of treatment material, or for movement of the contaminants, or without the need for continuous pumping of groundwater through the treatment zone, or removal of groundwater from the subsurface area of contamination.

  8. TCEQ - Map of Texas Groundwater Conservation Districts | Open...

    Open Energy Info (EERE)

    Map of Texas Groundwater Conservation Districts Jump to: navigation, search OpenEI Reference LibraryAdd to library Map: TCEQ - Map of Texas Groundwater Conservation DistrictsInfo...

  9. Sustainable Groundwater Management Act of 2014 | Open Energy...

    Open Energy Info (EERE)

    Groundwater Management Act of 2014 Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- BillBill: Sustainable Groundwater Management Act of 2014Legal...

  10. Microsoft Word - HAB Adv #145 Groundwater.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 Subject: Groundwater Strategy and Groundwater Protection Adopted: April 4, 2003 Page 1 Apr. 4, 2003 Keith Klein, Manager U.S. Department of Energy, Richland Operations P.O. Box...

  11. Method to remove uranium/vanadium contamination from groundwater

    SciTech Connect (OSTI)

    Metzler, Donald R.; Morrison, Stanley

    2004-07-27

    A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

  12. Groundwater Data Package for the 2004 Composite Analysis

    SciTech Connect (OSTI)

    Thorne, Paul D.

    2004-08-11

    This report presents data and information that supports the groundwater module. The conceptual model of groundwater flow and transport at the Hanford Site is described and specific information applied in the numerical implementation module is provided.

  13. Method to Remove Uranium/Vanadium Contamination from Groundwater

    DOE Patents [OSTI]

    Metzler, Donald R.; Morrison Stanley

    2004-07-27

    A process for removing uranium/vanadium-based contaminants from groundwater using a primary in-ground treatment media and a pretreatment media that chemically adjusts the groundwater contaminant to provide for optimum treatment by the primary treatment media.

  14. Vapor port and groundwater sampling well

    DOE Patents [OSTI]

    Hubbell, Joel M.; Wylie, Allan H.

    1996-01-01

    A method and apparatus has been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing.

  15. ICDP Complex Groundwater Monitoring Plan REV 5

    SciTech Connect (OSTI)

    Cahn, L. S.

    2007-08-09

    This Groundwater Monitoring Plan, along with the Quality Assurance Project Plan for Waste Area Groups 1, 2, 3, 4, 5, 6, 7, 10, and Removal Actions, constitutes the sampling and analysis plan for groundwater and perched water monitoring at the Idaho CERCLA Disposal Facility (ICDF). A detection monitoring system was installed in the Snake River Plan Aquifer to comply with substantive requirements of "Releases from Solid Waste Management Units" of the Resource Conservation and Recovery Act. This detection monitoring wells constructed in the Snake River Plain Aquifer.

  16. Vapor port and groundwater sampling well

    DOE Patents [OSTI]

    Hubbell, J.M.; Wylie, A.H.

    1996-01-09

    A method and apparatus have been developed for combining groundwater monitoring wells with unsaturated-zone vapor sampling ports. The apparatus allows concurrent monitoring of both the unsaturated and the saturated zone from the same well at contaminated areas. The innovative well design allows for concurrent sampling of groundwater and volatile organic compounds (VOCs) in the vadose (unsaturated) zone from a single well, saving considerable time and money. The sample tubes are banded to the outer well casing during installation of the well casing. 10 figs.

  17. Source Water and Groundwater Withdrawal Permit Application Process...

    Open Energy Info (EERE)

    Permit Application Process Guidance Citation Vermont Department of Environmental Conservation. 2015. Source Water and Groundwater Withdrawal Permit Application Process...

  18. Groundwater Contamination and Treatment at Department of Energy Sites |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Groundwater Contamination and Treatment at Department of Energy Sites Groundwater Contamination and Treatment at Department of Energy Sites The purpose of this document is to provide DOE Program/Project Managers, upper management, and other interested parties with a snapshot in time of the status of major groundwater contamination and remedial approaches across the DOE Complex. Groundwater Contamination and Treatment at Department of Energy Sites (812.8 KB) More

  19. Geology and Groundwater Investigation Many Devils Wash, Shiprock Site, New

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mexico | Department of Energy Geology and Groundwater Investigation Many Devils Wash, Shiprock Site, New Mexico Geology and Groundwater Investigation Many Devils Wash, Shiprock Site, New Mexico Geology and Groundwater Investigation Many Devils Wash, Shiprock Site, New Mexico Geology and Groundwater Investigation Many Devils Wash, Shiprock Site, New Mexico (5.19 MB) More Documents & Publications Natural Contamination from the Mancos Shale Application of Environmental Isotopes to the

  20. Groundwater Contamination and Treatment at Department of Energy Sites -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2008 | Department of Energy 8 Groundwater Contamination and Treatment at Department of Energy Sites - 2008 The purpose of this document is to provide DOE Program/Project Managers, upper management, and other interested parties with a snapshot in time of the status of major groundwater contamination and remedial approaches across the DOE Complex. Groundwater Contamination and Treatment at Department of Energy Sites - 2008 (1.59 MB) More Documents & Publications Groundwater Contamination

  1. Groundwater Contamination and Treatment at Department of Energy Sites -

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2009 | Department of Energy 9 Groundwater Contamination and Treatment at Department of Energy Sites - 2009 This document provides DOE Program/Project Managers, senior management, and other interested parties with a snapshot in time of the status of major groundwater contamination and remedial approaches across the DOE Complex. Groundwater Contamination and Treatment at Department of Energy Sites - 2009 (1.47 MB) More Documents & Publications Groundwater Contamination and Treatment at

  2. Hanford Site Groundwater Monitoring for Fiscal Year 2001

    SciTech Connect (OSTI)

    Hartman, Mary J.; Morasch, Launa F.; Webber, William D.

    2002-02-28

    This report provides information on the status of groundwater monitoring at the Hanford Site during fiscal year 2001.

  3. February 2016 Groundwater and Surface Water Sampling at the Tuba...

    Office of Legacy Management (LM)

    6 Groundwater and Surface Water Sampling at the Tuba City, Arizona, Disposal Site April .........5 Water Sampling Field Activities Verification ...

  4. REMEDIATE AND RESTORE GROUNDWATER TO HIGHEST BENEFICIAL USE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    REMEDIATE AND RESTORE GROUNDWATER TO HIGHEST BENEFICIAL USE ■ Groundwater is to be cleaned up and restored to the highest bene cial use.* ■ Restoration should be within a reasonable time frame, commensurate with risk and Tri-Party Agreement timelines. ■ Ongoing groundwater remediation activities and review processes should be fully funded. ■ Technology development should continually be pursued to remediate and restore groundwater to highest bene cial use.* ■ The public and tribes must

  5. Archived Soil & Groundwater Master Reports | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Archived Soil & Groundwater Master Reports Archived Soil & Groundwater Master Reports Archived Soil & Groundwater Master Reports Amchitka Ashtabula Fernald Environmental Management Project Maybell Miamisburg Environmental Management Project Rocky Flats Environmental Technology Site Shiprock Slick Rock South Valley Spook Tuba City Weldon Spring Miscellaneous

  6. The Savannah River Site's Groundwater Monitoring Program

    SciTech Connect (OSTI)

    Not Available

    1992-08-03

    This report summarizes the Savannah River Site (SRS) groundwater monitoring program conducted during the first quarter of 1992. It includes the analytical data, field data, data review, quality control, and other documentation for this program; provides a record of the program's activities; and serves as an official document of the analytical results.

  7. Paddy field, groundwater and land subsidence

    SciTech Connect (OSTI)

    Wen, L.J.

    1995-12-31

    Through many years of research and technical interchange both at home and abroad, it is commonly recognized that paddy fields possess the functions of micro-climate adjustment, flood detection and prevention, soil and water conservation, river-flow stabilization, soil salinization prevention, water purification, groundwater recharge, rural area beautification and environmental protection which are all beneficial to the public. In recent years, the global environmental problems have become a series concern throughout the world. These include the broken ozone layer, green house effects, acid rain, land desertion, tropical rain forest disappearing etc. Among them, rain forest disappearing draws great attention. Both rain forests and paddy fields are in tropical areas. They have similar functions and are disappearing because of economic pressure. This paper describes the special functions of paddy fields on water purification, ground water recharge and prevention of land subsidence, and reiterates groundwater utilization and land subsidence prevention measures. In view of the importance of groundwater resources, paddy fields, which can not be replaced by any other artificial groundwater recharge facilities, should not be reduced in acreage, nor can they be left idle. Paddy fields shall be properly maintained and managed in order to strengthen their special functions in the years to come even under heavy pressure from foreign countries.

  8. Hanford Treats Groundwater Ahead of Schedule

    Broader source: Energy.gov [DOE]

    RICHLAND, Wash. – EM’s Richland Operations Office and contractor CH2M HILL Plateau Remediation Company (CH2M HILL) are ahead of schedule in meeting EM's annual goals for treating contaminated groundwater at the Hanford site in southeast Washington state.

  9. Chromium Groundwater Cleanup in Mortandad Canyon

    Broader source: Energy.gov [DOE]

    At the September 24, 2014 Board meeting Cheryl Rodriguez DOE and Danny Katzman LANL, Provided Information on the Status of the Characterization of the Chromium Groundwater Plume in Mortandad Canyon. Possible Clean-up Strategies were also covered in the Information Provided.

  10. The Savannah River Site's groundwater monitoring program

    SciTech Connect (OSTI)

    Not Available

    1991-10-18

    This report summarizes the Savannah River Site (SRS) groundwater monitoring program conducted by EPD/EMS in the first quarter of 1991. In includes the analytical data, field data, data review, quality control, and other documentation for this program, provides a record of the program's activities and rationale, and serves as an official document of the analytical results.

  11. Colloid characterization and quantification in groundwater samples

    SciTech Connect (OSTI)

    K. Stephen Kung

    2000-06-01

    This report describes the work conducted at Los Alamos National Laboratory for studying the groundwater colloids for the Yucca Mountain Project in conjunction with the Hydrologic Resources Management Program (HRMP) and the Underground Test Area (UGTA) Project. Colloidal particle size distributions and total particle concentration in groundwater samples are quantified and characterized. Colloid materials from cavity waters collected near underground nuclear explosion sites by HRMP field sampling personnel at the Nevada Test Site (NTS) were quantified. Selected colloid samples were further characterized by electron microscope to evaluate the colloid shapes, elemental compositions, and mineral phases. The authors have evaluated the colloid size and concentration in the natural groundwater sample that was collected from the ER-20-5 well and stored in a 50-gallon (about 200-liter) barrel for several months. This groundwater sample was studied because HRMP personnel have identified trace levels of radionuclides in the water sample. Colloid results show that even though the water sample had filtered through a series of Millipore filters, high-colloid concentrations were identified in all unfiltered and filtered samples. They had studied the samples that were diluted with distilled water and found that diluted samples contained more colloids than the undiluted ones. These results imply that colloids are probably not stable during the storage conditions. Furthermore, results demonstrate that undesired colloids have been introduced into the samples during the storage, filtration, and dilution processes. They have evaluated possible sources of colloid contamination associated with sample collection, filtrating, storage, and analyses of natural groundwaters. The effects of container types and sample storage time on colloid size distribution and total concentration were studied to evaluate colloid stability by using J13 groundwater. The data suggests that groundwater samples

  12. Uranium Contamination in the Subsurface Beneath the 300 Area, Hanford Site, Washington

    SciTech Connect (OSTI)

    Peterson, Robert E.; Rockhold, Mark L.; Serne, R. Jeffrey; Thorne, Paul D.; Williams, Mark D.

    2008-02-29

    This report provides a description of uranium contamination in the subsurface at the Hanford Site's 300 Area. The principal focus is a persistence plume in groundwater, which has not attenuated as predicted by earlier remedial investigations. Included in the report are chapters on current conditions, hydrogeologic framework, groundwater flow modeling, and geochemical considerations. The report is intended to describe what is known or inferred about the uranium contamination for the purpose of making remedial action decisions.

  13. The Groundwater Performance Assessment Project Quality Assurance Plan

    SciTech Connect (OSTI)

    Luttrell, Stuart P.

    2006-05-11

    U.S. Department of Energy (DOE) has monitored groundwater on the Hanford Site since the 1940s to help determine what chemical and radiological contaminants have made their way into the groundwater. As regulatory requirements for monitoring increased in the 1980s, there began to be some overlap between various programs. DOE established the Groundwater Performance Assessment Project (groundwater project) in 1996 to ensure protection of the public and the environment while improving the efficiency of monitoring activities. The groundwater project is designed to support all groundwater monitoring needs at the site, eliminate redundant sampling and analysis, and establish a cost-effective hierarchy for groundwater monitoring activities. This document provides the quality assurance guidelines that will be followed by the groundwater project. This QA Plan is based on the QA requirements of DOE Order 414.1C, Quality Assurance, and 10 CFR 830, Subpart A--General Provisions/Quality Assurance Requirements as delineated in Pacific Northwest National Laboratory’s Standards-Based Management System. In addition, the groundwater project is subject to the Environmental Protection Agency (EPA) Requirements for Quality Assurance Project Plans (EPA/240/B-01/003, QA/R-5). The groundwater project has determined that the Hanford Analytical Services Quality Assurance Requirements Documents (HASQARD, DOE/RL-96-68) apply to portions of this project and to the subcontractors. HASQARD requirements are discussed within applicable sections of this plan.

  14. Procedures for ground-water investigations

    SciTech Connect (OSTI)

    Not Available

    1989-09-01

    This manual was developed by the Pacific Northwest Laboratory (PNL) to document the procedures used to carry out and control the technical aspects of ground-water investigations at the PNL. Ground-water investigations are carried out to fulfill the requirements for the US Department of Energy (DOE) to meet the requirements of DOE Orders. Investigations are also performed for various clients to meet the requirements of the Resource Conservation and Recovery Act of 1976 (RCRA) and the Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA). National standards including procedures published by the American Society for Testing and Materials (ASTM) and the US Geological Survey were utilized in developing the procedures contained in this manual.

  15. Modular, multi-level groundwater sampler

    DOE Patents [OSTI]

    Nichols, Ralph L.; Widdowson, Mark A.; Mullinex, Harry; Orne, William H.; Looney, Brian B.

    1994-01-01

    Apparatus for taking a multiple of samples of groundwater or pressure measurements from a well simultaneously. The apparatus comprises a series of chambers arranged in an axial array, each of which is dimensioned to fit into a perforated well casing and leave a small gap between the well casing and the exterior of the chamber. Seals at each end of the container define the limits to the axial portion of the well to be sampled. A submersible pump in each chamber pumps the groundwater that passes through the well casing perforations into the gap from the gap to the surface for analysis. The power lines and hoses for the chambers farther down the array pass through each chamber above them in the array. The seals are solid, water-proof, non-reactive, resilient disks supported to engage the inside surface of the well casing. Because of the modular design, the apparatus provides flexibility for use in a variety of well configurations.

  16. Complexity of Groundwater Contaminants at DOE Sites

    SciTech Connect (OSTI)

    Hazen, T.C.; Faybishenko, B.; Jordan, P.

    2010-12-03

    The U.S. Department of Energy (DOE) is responsible for the remediation and long-term stewardship of one of the world's largest groundwater contamination portfolios, with a significant number of plumes containing various contaminants, and considerable total mass and activity. As of 1999, the DOE's Office of Environmental Management was responsible for remediation, waste management, or nuclear materials and facility stabilization at 144 sites in 31 states and one U.S. territory, out of which 109 sites were expected to require long-term stewardship. Currently, 19 DOE sites are on the National Priority List. The total number of contaminated plumes on DOE lands is estimated to be 10,000. However, a significant number of DOE sites have not yet been fully characterized. The most prevalent contaminated media are groundwater and soil, although contaminated sediment, sludge, and surface water also are present. Groundwater, soil, and sediment contamination are present at 72% of all DOE sites. A proper characterization of the contaminant inventory at DOE sites is critical for accomplishing one of the primary DOE missions -- planning basic research to understand the complex physical, chemical, and biological properties of contaminated sites. Note that the definitions of the terms 'site' and 'facility' may differ from one publication to another. In this report, the terms 'site,' 'facility' or 'installation' are used to identify a contiguous land area within the borders of a property, which may contain more than one plume. The term 'plume' is used here to indicate an individual area of contamination, which can be small or large. Even though several publications and databases contain information on groundwater contamination and remediation technologies, no statistical analyses of the contaminant inventory at DOE sites has been prepared since the 1992 report by Riley and Zachara. The DOE Groundwater Data Base (GWD) presents data as of 2003 for 221 groundwater plumes at 60 DOE sites

  17. GROUNDWATER MONITORING REPORT GENERATION TOOLS - 12005

    SciTech Connect (OSTI)

    Lopez, N.

    2011-11-21

    Compliance with National and State environmental regulations (e.g. Resource Conservation and Recovery Act (RCRA) and Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) aka SuperFund) requires Savannah River Site (SRS) to extensively collect and report groundwater monitoring data, with potential fines for missed reporting deadlines. Several utilities have been developed at SRS to facilitate production of the regulatory reports which include maps, data tables, charts and statistics. Components of each report are generated in accordance with complex sets of regulatory requirements specific to each site monitored. SRS developed a relational database to incorporate the detailed reporting rules with the groundwater data, and created a set of automation tools to interface with the information and generate the report components. These process improvements enhanced quality and consistency by centralizing the information, and have reduced manpower and production time through automated efficiencies.

  18. The Savannah River Site's groundwater monitoring program

    SciTech Connect (OSTI)

    Not Available

    1991-05-06

    The Environmental Protection Department/Environmental Monitoring Section (EPD/EMS) administers the Savannah River Site's (SRS) Groundwater Monitoring Program. During third quarter 1990 (July through September) EPD/EMS conducted routine sampling of monitoring wells and drinking water locations. EPD/EMS established two sets of flagging criteria in 1986 to assist in the management of sample results. The flagging criteria do not define contamination levels; instead they aid personnel in sample scheduling, interpretation of data, and trend identification. The flagging criteria are based on detection limits, background levels in SRS groundwater, and drinking water standards. All analytical results from third quarter 1990 are listed in this report, which is distributed to all site custodians. One or more analytes exceeded Flag 2 in 87 monitoring well series. Analytes exceeded Flat 2 for the first since 1984 in 14 monitoring well series. In addition to groundwater monitoring, EPD/EMS collected drinking water samples from SRS drinking water systems supplied by wells. The drinking water samples were analyzed for radioactive constituents.

  19. Potassium ferrate treatment of RFETS` contaminated groundwater

    SciTech Connect (OSTI)

    1995-01-01

    The potassium ferrate treatment study of Rocky Flats Environmental Technology Site (RFETS) groundwater was performed under the Sitewide Treatability Studies Program (STSP). This study was undertaken to determine the effectiveness of potassium ferrate in a water treatment system to remove the contaminants of concern (COCS) from groundwater at the RFETS. Potassium ferrate is a simple salt where the iron is in the plus six valence state. It is the iron at the plus six valence state (Fe {sup +6}) that makes it an unique water treatment chemical, especially in waters where the pH is greater than seven. In basic solutions where the solubility of the oxides/hydroxides of many of the COCs is low, solids are formed as the pH is raised. By using ferrate these solids are agglomerated so they can be effectively removed by sedimentation in conventional water treatment equipment. The objective of this study was to determine the quality of water after treatment with potassium ferrate and to determine if the Colorado Water Quality Control Commission (CWQCC) discharge limits for the COCs listed in Table 1.0-1 could be met. Radionuclides in the groundwater were of special concern.

  20. Integrated monitoring plan for the Hanford groundwater monitoring project

    SciTech Connect (OSTI)

    Hartman, M.J.; Dresel, P.E.; McDonald, J.P.; Mercer, R.B.; Newcomer, D.R.; Thornton, E.C.

    1998-09-01

    Groundwater is monitored in hundreds of wells at the Hanford Site to fulfill a variety of requirements. Separate monitoring plans are prepared for various requirements, but sampling is coordinated and data are shared among users to avoid duplication of effort. The US Department of Energy (DOE) manages these activities through the Hanford Groundwater Monitoring Project (groundwater project), which is the responsibility of Pacific Northwest National Laboratory. The groundwater project does not include all of the monitoring to assess performance of groundwater remediation or all monitoring associated with active facilities. This document is the first integrated monitoring plan for the groundwater project and contains: well and constituent lists for monitoring required by the Atomic Energy Act of 1954 and its implementing orders; other, established monitoring plans by reference; and a master well/constituent/frequency matrix for the entire Hanford Site.

  1. Groundwater Open House! THE SCIENCE CONTINUES The Science Continues

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Welcome to the Groundwater Open House! THE SCIENCE CONTINUES The Science Continues As part of a long-term monitoring program, ongoing scientific studies will continue into the future to identify where contaminated groundwater is located, in which direction it flows and its rate of movement. Find the latest data on posters marked with this symbol. YOUR WATER IS SAFE The Groundwater is Safe Public water supply is safe from the impacts of historic underground nuclear testing. Current research

  2. Recommendation 222: Recommendations on Additional Off-site Groundwater

    Office of Environmental Management (EM)

    Migration Studies | Department of Energy 2: Recommendations on Additional Off-site Groundwater Migration Studies Recommendation 222: Recommendations on Additional Off-site Groundwater Migration Studies ORSSAB recommends that DOE proceed with an off-site groundwater quality assessment project and that DOE secure additional baseline funding for analysis to further understanding of potential migration and effects on off-site receptors. Recommendation 222 (55.21 KB) Response to Recommendation

  3. Weldon Spring Site Archived Soil & Groundwater Master Reports | Department

    Office of Environmental Management (EM)

    of Energy Weldon Spring Site Archived Soil & Groundwater Master Reports Weldon Spring Site Archived Soil & Groundwater Master Reports Weldon Spring Site Archived Soil & Groundwater Master Reports Weldon Spring Site - Chemical Plant East Plume (17.9 KB) Weldon Spring Site - Chemical Plant Quarry (17.53 KB) Weldon Spring Site - Chemical Plant VOC (16.06 KB) Weldon Spring Site - Chemical Plant West Plume (18.61 KB) More Documents & Publications South Valley Archived Soil &

  4. Hanford Site Groundwater Monitoring for Fiscal Year 2006

    SciTech Connect (OSTI)

    Hartman, Mary J.; Morasch, Launa F.; Webber, William D.

    2007-03-01

    This report presents the results of groundwater monitoring for FY 2006 on DOE's Hanford Site. Results of groundwater remediation, vadose zone monitoring, and characterization are summarized. DOE monitors groundwater at the Hanford Site to fulfill a variety of state and federal regulations, including the Atomic Energy Act (AEA), the Resource Conservation and Recovery Act (RCRA), the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), and Washington Administrative Code (WAC).

  5. A Fresh Take on Groundwater at Amargosa Valley Open House

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    September 25, 2012 A Fresh Take on Groundwater at Amargosa Valley Open House From drilling to sampling, groundwater was the topic on everyone's mind at a recent open house in Amargosa Valley, Nevada. On September 18, 2012, residents of Beatty, Amargosa Valley, Pahrump and other neighboring communities gathered at the Amargosa Community Center for the 4th Annual Groundwater Open House. The U.S. Department of Energy, National Nuclear Security Administration Nevada Site Office conducts the annual

  6. Numerical Simulation of Groundwater Withdrawal at the Nevada Test Site

    SciTech Connect (OSTI)

    Carroll, Rosemary; Giroux, Brian; Pohll, Greg; Hershey, Ronald; Russell, Charles; Howcroft, William

    2004-01-28

    Alternative uses of the Nevada Test Site (NTS) may require large amounts of water to construct and/or operate. The only abundant source of water at the NTS is groundwater. This report describes preliminary modeling to quantify the amount of groundwater available for development from three hydrographic areas at the NTS. Modeling was conducted with a three-dimensional transient numerical groundwater flow model.

  7. Central Plateau Groundwater and Deep Vadose Zone Strategy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vadose Zone Executive Council Hanford Advisory Board River and Plateau Committee Briant L. Charboneau DOE-RL, Soil and Groundwater Federal Project Director October 9, 2012 1 Discussion Topics * Purpose of the Executive Council - Why was this established? * Who participates? * What are the integration topics of interest to the Council? * Examples of groundwater and vadose zone integration - Deep Vadose Zone treatability testing leading to evaluation of measures to protect groundwater - B complex

  8. Treatment Resin Reduces Costs, Materials in Hanford Groundwater...

    Office of Environmental Management (EM)

    southeast Washington state. The material, an ion exchange resin, is used in groundwater treatment systems to strip contaminants from the water-in this case, hexavalent...

  9. X-701B Groundwater Remedy Portsmouth Ohio | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Portsmouth Integration Director's Final Findings and Order Building C-400 Thermal Treatment 90% Remedial Design Report and Site Investigation Groundwater Contamination and ...

  10. Persistent source influences on the trailing edge of a groundwater...

    Office of Scientific and Technical Information (OSTI)

    Persistent source influences on the trailing edge of a groundwater plume, and natural attenuation timeframes: The F-Area Savannah River Site Citation Details In-Document Search ...

  11. Trace rare earth element analysis in briny groundwaters

    SciTech Connect (OSTI)

    Laul, J.C.; Lepel, E.A.; Smith, M.R.

    1986-08-01

    A rare-earth element (REE) group separation scheme has been developed. REE data for two briny groundwaters representing Granite Wash and Wolfcamp Carbonate formations are reported. (DLC)

  12. Groundwater and Leachate Monitoring and Sampling at ERDF, CY 2010

    SciTech Connect (OSTI)

    Weiss, R. L.; Lawrence, B. L.

    2011-06-09

    The purpose of this annual monitoring report is to evaluate the conditions of and identify trends for groundwater beneath the ERDF and report leachate results in fulfillment of the requirements specified in the ERDF ROD2 and the ERDF Amended ROD (EPA 1999). The overall objective of the groundwater monitoring program is to determine whether ERDF has impacted the groundwater. This objective is complicated by the fact that the ERDF is situated downgradient of the numerous groundwater contamination plumes originating from the 200 West Area.

  13. Performance assessment techniques for groundwater recovery and treatment systems

    SciTech Connect (OSTI)

    Kirkpatrick, G.L.

    1993-03-01

    Groundwater recovery and treatment (pump and treat systems) continue to be the most commonly selected remedial technology for groundwater restoration and protection programs at hazardous waste sites and RCRA facilities nationwide. Implementing a typical groundwater recovery and treatment system includes the initial assessment of groundwater quality, characterizing aquifer hydrodynamics, recovery system design, system installation, testing, permitting, and operation and maintenance. This paper focuses on methods used to assess the long-term efficiency of a pump and treat system. Regulatory agencies and industry alike are sensitive to the need for accurate assessment of the performance and success of groundwater recovery systems for contaminant plume abatement and aquifer restoration. Several assessment methods are available to measure the long-term performance of a groundwater recovery system. This paper presents six assessment techniques: degree of compliance with regulatory agency agreement (Consent Order of Record of Decision), hydraulic demonstration of system performance, contaminant mass recovery calculation, system design and performance comparison, statistical evaluation of groundwater quality and preferably, integration of the assessment methods. Applying specific recovery system assessment methods depends upon the type, amount, and quality of data available. Use of an integrated approach is encouraged to evaluate the success of a groundwater recovery and treatment system. The methods presented in this paper are for engineers and corporate management to use when discussing the effectiveness of groundwater remediation systems with their environmental consultant. In addition, an independent (third party) system evaluation is recommended to be sure that a recovery system operates efficiently and with minimum expense.

  14. Tracing And Quantifying Magmatic Carbon Discharge In Cold Groundwaters...

    Open Energy Info (EERE)

    Tracing And Quantifying Magmatic Carbon Discharge In Cold Groundwaters- Lessons Learned From Mammoth Mountain, USA Jump to: navigation, search OpenEI Reference LibraryAdd to...

  15. Tracing And Quantifying Magmatic Carbon Discharge In Cold Groundwaters...

    Open Energy Info (EERE)

    Journal Article: Tracing And Quantifying Magmatic Carbon Discharge In Cold Groundwaters- Lessons Learned From Mammoth Mountain, Usa Abstract A major campaign to quantify the...

  16. New Groundwater Treatment Facility Begins Operation: Boost in...

    Office of Environmental Management (EM)

    New Groundwater Treatment Facility Begins Operation: Boost in Cleanup Accelerated by ... the Columbia River by 40 percent with the recent completion of a new treatment facility. ...

  17. Vermont Drinking Water and Groundwater Protection Division Permit...

    Open Energy Info (EERE)

    2015 DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for Vermont Drinking Water and Groundwater Protection Division Permit Fees...

  18. Vermont Minor Amendment Application for Groundwater | Open Energy...

    Open Energy Info (EERE)

    Not Provided DOI Not Provided Check for DOI availability: http:crossref.org Online Internet link for Vermont Minor Amendment Application for Groundwater Citation Vermont...

  19. Savannah River Site - D-Area Groundwater | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Environmental Indicators (EIs) Groundwater Migration Under Control? No Current Human Exposure Acceptable? Yes Confirmed by Lead Regulator? Yes Confirmed by Lead Regulator? Yes...

  20. Groundwater Sampling At Raft River Geothermal Area (1974-1982...

    Open Energy Info (EERE)

    search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Groundwater Sampling At Raft River Geothermal Area (1974-1982) Exploration Activity Details Location Raft River...

  1. Hanford’s Groundwater Treatment System Expands Already Impressive Capabilities

    Broader source: Energy.gov [DOE]

    RICHLAND, Wash. – Construction was completed earlier this month on an expansion of Hanford’s 200 West Pump and Treat Facility to remove uranium from groundwater.

  2. Microsoft Word - Groundwater_Booklet-2008-v7 weblinks

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Groundwater Contamination and Treatment at Department of Energy Sites August 2008 Compiled by the Office of Engineering & Technology 2 Contents Acronyms ...............................................................................................................................................................................3

  3. Guidelines for the Protection of Surface and Groundwater Resources...

    Open Energy Info (EERE)

    and Groundwater Resources During Exploration Drilling Author Government of Western Australia Organization Department of Mines and Petroleum Published NA, 2002 DOI Not Provided...

  4. Conjunctive Surface and Groundwater Management in Utah. Implications...

    Office of Scientific and Technical Information (OSTI)

    Conjunctive Surface and Groundwater Management in Utah. Implications for Oil Shale and Oil Sands Development Citation Details In-Document Search Title: Conjunctive Surface and ...

  5. Groundwater Resources Assessment under the Pressures of Humanity...

    Open Energy Info (EERE)

    Resources Assessment under the Pressures of Humanity and Climate Change (GRAPHIC) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Groundwater Resources Assessment under...

  6. Key factors for determining groundwater impacts due to leakage...

    Office of Scientific and Technical Information (OSTI)

    The National Risk Assessment Partnership (NRAP) is developing a science-based toolset for the analysis of potential impacts to groundwater chemistry from CO2 injection ...

  7. Audit of Groundwater Remediation Plans at Savannah River, ER...

    Broader source: Energy.gov (indexed) [DOE]

    U.S. Department of Energy Human Resources and Administration Home Page ... groundwater contamination that represented a risk to human health or the environment. ...

  8. A Fresh Take on Groundwater at Amargosa Valley Open House

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    September 25, 2012 A Fresh Take on Groundwater at Amargosa Valley Open House From drilling ... Interactive stations on Monitoring, Drilling, Sampling, Modeling, Protection and ...

  9. Gas-Phase Treatment of Technetium in the Vadose Zone at the Hanford Site Central Plateau

    SciTech Connect (OSTI)

    Truex, Michael J.; Szecsody, James E.; Zhong, Lirong; Qafoku, Nikolla

    2014-09-01

    Technetium-99 (Tc-99) is present in the vadose zone of the Hanford Central Plateau and is a concern with respect to the protection of groundwater. The persistence, limited natural attenuation mechanisms, and geochemical behavior of Tc-99 in oxic vadose zone environments must be considered in developing effective alternatives for remediation. This report describes a new in situ geochemical manipulation technique for decreasing Tc-99 mobility using a combination of geochemical Tc-99 reduction with hydrogen sulfide gas and induced sediment mineral dissolution with ammonia vapor, which create conditions for deposition of stable precipitates that decrease the mobility of Tc-99. Laboratory experiments were conducted to examine changes in Tc-99 mobility in vadose zone sediment samples to evaluate the effectiveness of the treatment under a variety of operational and sediment conditions.

  10. Y-12 Groundwater Protection Program Groundwater And Surface Water Sampling And Analysis Plan For Calendar Year 2014

    SciTech Connect (OSTI)

    2013-09-01

    This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2014 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring is performed by the GWPP during CY 2014 to achieve the following goals: 􀁸 to protect the worker, the public, and the environment; 􀁸 to maintain surveillance of existing and potential groundwater contamination sources; 􀁸 to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; 􀁸 to identify and characterize long-term trends in groundwater quality at Y-12; and 􀁸 to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring will be performed in three hydrogeologic regimes at Y-12.

  11. Play Fairway Analysis CA-NV-OR: 2km Grid Based Analysis

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Colin M Ferguson

    2015-08-20

    Combined geochemical and geophysical data, weighted and ranked for geothermal prospect favorability.

  12. Procedures for ground-water investigations. Revision 1

    SciTech Connect (OSTI)

    Not Available

    1992-12-01

    This manual was developed by the Pacific Northwest Laboratory (PNL) to document the procedures used to carry out and control the technical aspects of ground-water investigations at the PNL. Ground-water monitoring procedures are developed and used in accordance with the PNL Quality Assurance Program.

  13. Nevada National Security Site Groundwater Program Welcomes Peer Review Team

    Office of Energy Efficiency and Renewable Energy (EERE)

    Recently, an independent peer review team was invited to assess the groundwater characterization program at the Nevada National Security Site (NNSS). This nationally recognized group of experts, from various external organizations, will examine the computer modeling approach developed to better understand how historic underground nuclear testing in Yucca Flat affected the groundwater.

  14. Hanford Groundwater Contamination Areas Shrink as EM Exceeds Cleanup Goals

    Broader source: Energy.gov [DOE]

    RICHLAND, Wash. – Workers supporting groundwater cleanup for EM’s Richland Operations Office at the Hanford site have exceeded a fiscal year goal to remove 3,500 pounds of carbon tetrachloride from groundwater under the center of the site.

  15. In-situ remediation system for groundwater and soils

    DOE Patents [OSTI]

    Corey, J.C.; Kaback, D.S.; Looney, B.B.

    1991-01-01

    The present invention relates to a system for in-situ remediation of contaminated groundwater and soil. In particular the present invention relates to stabilizing toxic metals in groundwater and soil. The United States Government has rights in this invention pursuant to Contract No. DE-AC09-89SR18035 between the US Department of Energy and Westinghouse Savannah River Company.

  16. Bioremediation of contaminated groundwater: A turnkey approach

    SciTech Connect (OSTI)

    Shivjiani, D.M.; Rudy, R.J.; Burns, B.; Heuler, G.

    1994-12-31

    The Silvex Corporation Site is a Florida state funded remedial action site in St. Augustine, Florida, that, prior to 1980, was a silver smelting facility that accepted waste materials from the Naval Air Station-Jacksonville. Fuels, reportedly consisting of waste paint, cold carbon removers, and solvent degreasers that were stored in a 25,000-gallon tank, spilled onto the property. The assessment concluded that the surficial aquifer in the spill area and the area hydrologically down-gradient of the spill were contaminated by elevated levels of ketones (acetone, methyl-ethyl ketone, and methyl-isobutyl ketone), phenols, and toluene. Subsequently, a risk assessment/feasibility study and groundwater bench-scale and pilot-scale studies were performed to determine the technical feasibility/cost-effectiveness of the recommended alternative, submerged fixed-film bioremediation. The on-site pilot study, which was conducted at three flow rates (0.5, 1, and 2 gallons per minute [gpm]), demonstrated a greater than 99% contaminant removal efficiency from the three-stage bioreactor. Due to the impact of site contamination on a nearby creek that flows into the St. Johns River, an interim remedial deign was developed and implemented to reduce the potential for migration of contaminated groundwater into the creek.

  17. Modular, multi-level groundwater sampler

    DOE Patents [OSTI]

    Nichols, R.L.; Widdowson, M.A.; Mullinex, H.; Orne, W.H.; Looney, B.B.

    1994-03-15

    An apparatus is described for taking a multiple of samples of groundwater or pressure measurements from a well simultaneously. The apparatus comprises a series of chambers arranged in an axial array, each of which is dimensioned to fit into a perforated well casing and leave a small gap between the well casing and the exterior of the chamber. Seals at each end of the container define the limits to the axial portion of the well to be sampled. A submersible pump in each chamber pumps the groundwater that passes through the well casing perforations into the gap from the gap to the surface for analysis. The power lines and hoses for the chambers farther down the array pass through each chamber above them in the array. The seals are solid, water-proof, non-reactive, resilient disks supported to engage the inside surface of the well casing. Because of the modular design, the apparatus provides flexibility for use in a variety of well configurations. 3 figures.

  18. Hanford Site groundwater monitoring: Setting, sources and methods

    SciTech Connect (OSTI)

    M.J. Hartman

    2000-04-11

    Groundwater monitoring is conducted on the Hanford Site to meet the requirements of the Resource Conservation and Recovery Act of 1976 (RCRA); Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA); U.S. Department of Energy (DOE) orders; and the Washington Administrative Code. Results of monitoring are published annually (e.g., PNNL-11989). To reduce the redundancy of these annual reports, background information that does not change significantly from year to year has been extracted from the annual report and published in this companion volume. This report includes a description of groundwater monitoring requirements, site hydrogeology, and waste sites that have affected groundwater quality or that require groundwater monitoring. Monitoring networks and methods for sampling, analysis, and interpretation are summarized. Vadose zone monitoring methods and statistical methods also are described. Whenever necessary, updates to information contained in this document will be published in future groundwater annual reports.

  19. Field demonstration of rapid turnaround, multilevel groundwater screening

    SciTech Connect (OSTI)

    Tingle, A.R.; Baker, L.; Long, D.D.; Miracle, M.

    1994-09-01

    A combined technology approach to rapidly characterizing source area and downgradient groundwater associated with a past fuel spill has been field tested. The purpose of this investigation was to determine the presence and extent of fuel-related compounds or indications of their biodegradation in groundwater. The distance from the source area to be investigated was established by calculating the potential extent of a plume based only on groundwater flow velocities. To accomplish this objective, commercially available technologies were combined and used to rapidly assess the source area and downgradient groundwater associated with the fuel discharge. The source of contamination that was investigated overlies glacial sand and gravel outwash deposits. Historical data suggest that from 1955 to 1970 as many as 1 to 6 million pi of aviation gasoline (AVGAS) were god at the study area. Although the remedial investigation (RI) for this study area indicated fuel-related groundwater contamination at the source area, fuel-related contamination was not detected in downgradient monitoring wells. Rapid horizontal groundwater velocities and the 24-year time span from the last reported spill farther suggest that a plume of contaminated groundwater could extend several thousand feet downgradient. The lack of contamination downgradient from the source suggests two possibilities: (1) monitoring wells installed during the RI did not intersect the plume or (2) fuel-related compounds had naturally degraded.

  20. Groundwater Monitoring Plan for the 216-A-29 Ditch

    SciTech Connect (OSTI)

    Sweeney, M.D.

    1999-10-07

    This document presents a groundwater monitoring plan, under Resource Conservation and Recovery Act of 1976 (RCRA) regulatory requirements found in WAC 173-303-400, and by reference, requirements in 40 CFR 265.93 (d)(6) for the 216-A-29 Ditch (A-29 Ditch) in the Hanford Site's 200 East Area. The objectives of this monitoring plan are to determine whether any hazardous constituents are detectable in the groundwater beneath the ditch. The groundwater monitoring network described in this plan includes 10 RCRA-compliant wells to monitor the aquifer in the immediate vicinity of the A-29 Ditch. Groundwater assessment activities have been conducted at the A-29 Ditch, the result of elevated specific conductivity and total organic halogens (TOX). A groundwater assessment report (Votava 1995) found that no hazardous constituents had impacted groundwater and the site returned to interim-status indicator-parameter/detection monitoring. This plan describes the process and quality objectives for conducting the indicator-parameter program. The site will be sampled semiannually for indicator parameters including pH, specific conductance, TOX, and total organic carbon. Site-specific parameters include tritium and ICP metals. These constituents, as well as anions, alkalinity, and turbidity will be sampled annually. Groundwater elevations will be recorded semiannually.

  1. Hanford Site ground-water monitoring for 1994

    SciTech Connect (OSTI)

    Dresel, P.E.; Thorne, P.D.; Luttrell, S.P.

    1995-08-01

    This report presents the results of the Ground-Water Surveillance Project monitoring for calendar year 1994 on the Hanford Site, Washington. Hanford Site operations from 1943 onward produced large quantities of radiologic and chemical waste that have impacted ground-water quality on the Site. Monitoring of water levels and ground-water chemistry is performed to track the extent of contamination and trends in contaminant concentrations. The 1994 monitoring was also designed to identify emerging ground-water quality problems. The information obtained is used to verify compliance with applicable environmental regulations and to evaluate remedial actions. Data from other monitoring and characterization programs were incorporated to provide an integrated assessment of Site ground-water quality. Additional characterization of the Site`s geologic setting and hydrology was performed to support the interpretation of contaminant distributions. Numerical modeling of sitewide ground-water flow also supported the overall project goals. Water-level monitoring was performed to evaluate ground-water flow directions, to track changes in water levels, and to relate such changes to changes in site disposal practices. Water levels over most of the Hanford Site continued to decline between June 1993 and June 1994. These declines are part of the continued response to the cessation of discharge to U Pond and other disposal facilities. The low permeability in this area which enhanced mounding of waste-water discharge has also slowed the response to the reduction of disposal.

  2. The Savannah River Site's Groundwater Monitoring Program

    SciTech Connect (OSTI)

    Not Available

    1989-01-01

    The Environmental Monitoring Section of the Environmental and Health Protection (EHP) Department administers the Savannah River Site's Groundwater Monitoring Program. During fourth quarter 1989 (October--December), EHP conducted routine sampling of monitoring wells and drinking water locations. EHP collected the drinking water samples from Savannah River Site (SRS) drinking water systems supplied by wells. EHP established two sets of flagging criteria in 1986 to assist in the management of sample results. The flagging criteria aid personnel in sample scheduling, interpretation of data, and trend identification. An explanation of flagging criteria for the fourth quarter is presented in the Flagging Criteria section of this document. All analytical results from fourth quarter 1989 are listed in this report, which is distributed to all waste-site custodians.

  3. The Savannah River Site's Groundwater Monitoring Program

    SciTech Connect (OSTI)

    Not Available

    1992-01-10

    The Environmental Protection Department/Environmental Monitoring Section (EPD/EMS) administers the Savannah River Site's (SRS) Groundwater Monitoring Program. During second quarter 1991 EPD/EMS conducted extensive sampling of monitoring wells. EPD/EMS established two sets of flagging criteria in 1986 to assist in the management of sample results. The flagging criteria do not define contamination levels; instead, they aid personnel in sample scheduling, interpretation of data, and trend identification. Beginning in 1991, the flagging criteria are based on EPA drinking water standards and method detection limits. A detailed explanation of the current flagging criteria is presented in the Flagging Criteria section of this document. Analytical results from second quarter 1991 are listed in this report.

  4. A technical approach to groundwater contamination problems

    SciTech Connect (OSTI)

    Burton, J.C.; Leser, C.; Rose, C.M.

    1993-06-01

    Argonne National Laboratory has been performing technical investigations at sites in Nebraska and Kansas that have identified groundwater contamination by carbon tetrachloride. This comprehensive program will ultimately provide the affected communities with safe drinking water. The first step in the program is to evaluate the available data and identify sites that will require an Alternate Water Supply Study (AWSS). The objective of the AWSS is to identify options for providing a safe drinking water supply to all users, in compliance with the Safe Drinking Water Act. The AWSS consists of an engineering and cost evaluation followed by implementation of the selected alternative. For sites with contamination less than a specific concentration, the AWSS is regarded as a satisfactory long term solution, and no further action is taken. For those sites with concentrations above that specific limit, the AWSS implementation is regarded as only a stopgap measure, and the site is selected for additional remedial action. The first step of the remedial action is an Expedited Site Characterization (ESC). The ESC was developed at Argonne to decrease the cost and time of the remedial investigation and feasibility study while producing a high-quality technical investigation. The ESC is designed to characterize the contaminant plume configuration and movement, which requires an understanding of the geological and hydrogeologic controls on groundwater movement as well as the nature and extent of any remaining carbon tetrachloride source in the soils. The ESC program uses a multidisciplinary technical approach that incorporates geology, geochemistry, geohydrology, and geophysics. Field activities include sampling, chemical analysis, and borehole and surface geophysical surveys.

  5. Waste Isolation Pilot Plant Groundwater Protection Management Program Plan

    SciTech Connect (OSTI)

    Washington Regulatory and Environmental Services

    2005-07-01

    The DOE established the Groundwater Monitoring Program (GMP) (WP 02-1) to monitor groundwater resources at WIPP. In the past, the GMP was conducted to establish background data of existing conditions of groundwater quality and quantity in the WIPP vicinity, and to develop and maintain a water quality database as required by regulation. Today the GMP is conducted consistent with 204.1.500 NMAC (New MexicoAdministrative Code), "Adoption of 40 CFR [Code of Federal Regulations] Part 264,"specifically 40 CFR §264.90 through §264.101. These sections of 20.4.1 NMAC provide guidance for detection monitoring of groundwater that is, or could be, affected by waste management activities at WIPP. Detection monitoring at WIPP is designed to detect contaminants in the groundwater long before the general population is exposed. Early detection will allow cleanup efforts to be accomplished before any exposure to the general population can occur. Title 40 CFR Part 264, Subpart F, stipulates minimum requirements of Resource Conservation and Recovery Act of 1976 (42 United States Code [U.S.C.] §6901 et seq.) (RCRA) groundwater monitoring programs including the number and location of monitoring wells; sampling and reporting schedules; analytical methods and accuracy requirements; monitoring parameters; and statistical treatment of monitoring data. This document outlines how WIPP intends to protect and preserve groundwater within the WIPP Land Withdrawal Area (WLWA). Groundwater protection is just one aspect of the WIPP environmental protection effort. An overview of the entire environmental protection effort can be found in DOE/WIPP 99-2194, Waste Isolation Pilot Plant Environmental Monitoring Plan. The WIPP GMP is designed to statistically determine if any changes are occurring in groundwater characteristics within and surrounding the WIPP facility. If a change is noted, the cause will then be determined and the appropriate corrective action(s) initiated.

  6. Martin Marietta Energy Systems, Inc., Groundwater Program Management Plan

    SciTech Connect (OSTI)

    Early, T.O.

    1994-05-01

    The purpose of the Martin Marietta Energy Systems, Inc., (Energy Systems) Groundwater Program Management Plan is to define the function, organizational structure (including associated matrix organizations), interfaces, roles and responsibilities, authority, and relationship to the Department of Energy for the Energy Systems Groundwater Program Office (GWPO). GWPO is charged with the responsibility of coordinating all components of the groundwater program for Energy Systems. This mandate includes activities at the three Oak Ridge facilities [Oak Ridge National Laboratory, the Oak Ridge Y-12 Plant, and the Oak Ridge K-25 Site], as well as the Paducah and Portsmouth Gaseous Diffusion Plants.

  7. Electrode Induced Removal and Recovery of Uranium (VI) from Acidic Subsurfaces

    SciTech Connect (OSTI)

    Gregory, Kelvin

    2013-08-12

    The overarching objective of this research is to provide an improved understanding of how aqueous geochemical conditions impact the removal of U and Tc from groundwater and how engineering design may be utilized to optimize removal of these radionuclides. Experiments were designed to address the unique conditions in Area 3 of ORNL while also providing broader insight into the geochemical effectors of the removal rates and extent for U and Tc. The specific tasks of this work were to: 1) quantify the impact of common aqueous geochemical and operational conditions on the rate and extent of U removal and recovery from water, 2) investigate the removal of Tc with polarized graphite electrode, and determine the influence of geochemical and operational conditions on Tc removal and recovery, 3) determine whether U and Tc may be treated simultaneous from Area 3 groundwater, and examine the bench-scale performance of electrode-based treatment, and 4) determine the capacity of graphite electrodes for U(VI) removal and develop a mathematical, kinetic model for the removal of U(VI) from aqueous solution. Overall the body of work suggests that an electrode-based approach for the remediation of acidic subsurface environments, such as those observed in Area 3 of ORNL may be successful for the removal for both U(VI) and Tc. Carbonaceous (graphite) electrode materials are likely to be the least costly means to maximize removal rates and efficiency by maximizing the electrode surface area.

  8. Y-12 Groundwater Protection Program Extent Of The Primary Groundwater Contaminants At The Y-12 National Security Complex

    SciTech Connect (OSTI)

    2013-12-01

    This report presents data summary tables and maps used to define and illustrate the approximate lateral extent of groundwater contamination at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) in Oak Ridge, Tennessee. The data tables and maps address the primary (i.e., most widespread and mobile) organic, inorganic, and radiological contaminants in the groundwater. The sampling locations, calculated contaminant concentrations, plume boundary values, and paired map format used to define, quantify, delineate, and illustrate the approximate extent of the primary organic, inorganic, and radiological contaminants in groundwater at Y-12 are described.

  9. Savannah River Site - C-Area Groundwater Operable Unit | Department of

    Office of Environmental Management (EM)

    Energy - C-Area Groundwater Operable Unit Savannah River Site - C-Area Groundwater Operable Unit January 1, 2013 - 12:00pm Addthis US Department of Energy Groundwater Database Groundwater Master Report InstallationName, State: Savannah River Site, SC Responsible DOE Office: Savannah River Site Plume Name: C-Area Groundwater Operable Unit Remediation Contractor: Savannah River Nuclear Solutions, LLC PBS Number: 30 Report Last Updated: 2013 Contaminants Halogenated VOCs/SVOCs Present?: Yes VOC

  10. Savannah River Site - P-Area Groundwater Operable Unit | Department of

    Office of Environmental Management (EM)

    Energy P-Area Groundwater Operable Unit Savannah River Site - P-Area Groundwater Operable Unit January 1, 2013 - 12:00pm Addthis US Department of Energy Groundwater Database Groundwater Master Report InstallationName, State: Savannah River Site, SC Responsible DOE Office: Savannah River Site Plume Name: P-Area Groundwater Operable Unit Remediation Contractor: Savannah River Nuclear Solutions, LLC PBS Number: 30 Report Last Updated: 2013 Contaminants Halogenated VOCs/SVOCs Present?: Yes VOC

  11. Oak Ridge EM Program Collaborates with Regulators on Groundwater Strategy

    Office of Energy Efficiency and Renewable Energy (EERE)

    OAK RIDGE, Tenn. – The Oak Ridge EM program has joined state and federal regulators in a series of workshops to address contaminated groundwater on the Oak Ridge Reservation.

  12. Oak Ridge Removes Laboratory's Greatest Source of Groundwater...

    Broader source: Energy.gov (indexed) [DOE]

    the 4,000-gallon Tank W-1A, which was ORNLs greatest source of groundwater contamination. Workers remove the 4,000-gallon Tank W-1A, which was ORNL's greatest source of ...

  13. Demolition, Groundwater Cleanup Highlight Paducah’s 2013 Accomplishments

    Office of Energy Efficiency and Renewable Energy (EERE)

    PADUCAH, Ky. – Work to remove two aging, inactive structures and clean up a leading source of groundwater contamination marked the top 2013 accomplishments for the EM program at the Paducah site.

  14. Importance of mineralogical data for groundwater quality affectedby...

    Office of Scientific and Technical Information (OSTI)

    Dissolution of COsub 2 in groundwater results in a decrease in pH. Such acidic condition ... If calcite is present in the rock, it can buffer the pH and decrease galena dissolution. ...

  15. Groundwater Cleanup Operational Changes Are Being Implemented at Fernald Preserve

    Broader source: Energy.gov [DOE]

    Uranium contamination in the Great Miami Aquifer—at the Fernald Preserve, Ohio, Site—is being removed from the groundwater through a pump-and-treatment operation, which until this year, involved...

  16. Groundwater Quantity Regulation in Vermont: A Path Forward |...

    Open Energy Info (EERE)

    Groundwater Quantity Regulation in Vermont: A Path Forward Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- Secondary Legal SourceSecondary Legal...

  17. Hanford Groundwater Contamination Areas Shrink as EM Exceeds...

    Office of Environmental Management (EM)

    June 26, 2013 - 12:00pm Addthis The 200 West Pump and Treat System is Hanfords largest facility for treating contaminated groundwater. The 200 West Pump and Treat System is ...

  18. Hanford Site Groundwater Monitoring for Fiscal Year 2004

    SciTech Connect (OSTI)

    Hartman, Mary J.; Morasch, Launa F.; Webber, William D.

    2005-03-01

    This document presents the results of groundwater and vadose zone monitoring for fiscal year 2004 (October 2003 through September 2004)on the U.S. Department of Energy's Hanford Site in southeast Washington State.

  19. The Convergence of Heat, Groundwater & Fracture Permeability. Innovative

    Office of Scientific and Technical Information (OSTI)

    Play Fairway Modelling Applied to the Tularosa Basin Phase 1 Project Report (Other) | SciTech Connect Other: The Convergence of Heat, Groundwater & Fracture Permeability. Innovative Play Fairway Modelling Applied to the Tularosa Basin Phase 1 Project Report Citation Details In-Document Search Title: The Convergence of Heat, Groundwater & Fracture Permeability. Innovative Play Fairway Modelling Applied to the Tularosa Basin Phase 1 Project Report This report summarizes the activities

  20. Hanford Site groundwater monitoring for fiscal year 1996

    SciTech Connect (OSTI)

    Hartman, M.J.; Dresel, P.E.; Borghese, J.V.

    1997-02-01

    This report presents the results of groundwater and vadose-zone monitoring for fiscal year (FY) 1996 on the Hanford Site, Washington. Hanford Site operations from 1943 onward produced large quantities of radiological and chemical waste that affected groundwater quality on the site. Characterization and monitoring of the vadose zone during FY 1996 comprised primarily spectral gamma logging, soil-gas monitoring, and electrical resistivity tomography. Water-level monitoring was performed to evaluate groundwater-flow directions, to track changes in water levels, and to relate such changes to evolving disposal practices. Water levels over most of the Hanford Site continued to decline between June 1995 and June 1996. Groundwater chemistry was monitored to track the extent of contamination, to note trends, and to identify emerging groundwater-quality problems. The most widespread radiological contaminant plumes were tritium and iodine-129. Smaller plumes of strontium-90, technetium-99, and plutonium also were present at levels above the U.S. Environmental Protection Agency or State of Washington interim drinking water standards. Uranium concentrations greater than the proposed drinking water standard were also observed. Nitrate, fluoride, chromium, carbon tetrachloride, chloroform, trichloroethylene, and cis-1,2-dichlomethylene were present in groundwater samples at levels above their U.S. Environmental Protection Agency or State of Washington maximum contaminant levels. The nitrate plume is the most extensive. Three-dimensional, numerical, groundwater models were applied to the Hanford Site to predict contaminant-flow paths and the impact of operational changes on site groundwater conditions. Other models were applied to assess the performance of three separate pump-and-treat systems.

  1. Paducah Site Undergoing Steady Groundwater Cleanup with Variety of Methods

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Site Undergoing Steady Groundwater Cleanup with Variety of Methods Paducah Site Undergoing Steady Groundwater Cleanup with Variety of Methods June 1, 2012 - 12:00pm Addthis The yellow outline depicts an area southeast of the C-400 Cleaning Building, background, where electrical resistance heating will be used to remove trichloroethene (TCE) down to 60 feet below ground. Electrodes will heat the chemical into a vapor that can be pumped to the surface and treated in the

  2. Passive Groundwater Cleanup Measures Save Savannah River Site Millions of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dollars | Department of Energy Passive Groundwater Cleanup Measures Save Savannah River Site Millions of Dollars Passive Groundwater Cleanup Measures Save Savannah River Site Millions of Dollars November 25, 2015 - 12:20pm Addthis SRNS operators Stanley Creech (left) and Paul Dobson monitor the injection of silver chloride into an aquifer at SRS. SRNS operators Stanley Creech (left) and Paul Dobson monitor the injection of silver chloride into an aquifer at SRS. AIKEN, S.C. - The EM program

  3. Environmental Sciences Division Groundwater Program Office. Annual report, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-09-30

    This first edition of the Martin Marietta Energy Systems, Inc., (Energy Systems) Groundwater Program Annual Report summarizes the work carried out by the Energy Systems GWPO for fiscal year (FY) 1993. This introductory section describes the GWPO`s staffing, organization, and funding sources. The GWPO is responsible for coordination and oversight for all components of the groundwater program at the three Oak Ridge facilities [ORNL, the Oak Ridge Y-12 Plant, and the Oak Ridge K-25 Site], and the PGDP and PORTS, respectively. Several years ago, Energy systems senior management recognized that the manner in which groundwater activities were conducted at the five facilities could result in unnecessary duplication of effort, inadequate technical input to decisions related to groundwater issues, and could create a perception within the regulatory agencies of a confusing and inconsistent approach to groundwater issues at the different facilities. Extensive interactions among management from Environmental Compliance, Environmental Restoration (ER), Environmental Sciences Division, Environmental Safety and Health, and the five facilities ultimately led to development of a net technical umbrella organization for groundwater. On April 25, 1991, the GWPO was authorized to be set up within ORNL thereby establishing a central coordinating office that would develop a consistent technical and administrative direction for the groundwater programs of all facilities and result in compliance with all relevant U.S. Environmental Protection Agency (EPA) regulations such as RCRA and Comprehensive Environmental Restoration, Compensation and Liability Act (CERCLA) as well as U.S. Department of Energy (DOE) regulations and orders. For example, DOE Order 5400.1, issued on November 9, 1988, called for each DOE facility to develop an environmental monitoring program for all media (e.g., air, surface water, and groundwater).

  4. New Wells Provide Information on Groundwater at Pahute Mesa

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    November 28, 2012 New Wells Provide Information on Groundwater at Pahute Mesa New wells drilled near historic underground test areas in Nevada are helping scientists get a clearer understanding of the groundwater in these areas while contributing to the design of a long-term monitoring system. Drilled from September to October 2012, these two wells will supplement a network of more than 20 existing characterization wells in an area called Pahute Mesa, which extends from the northwestern portion

  5. Nye County Community Groundwater Program - Signed Determination.pdf

    National Nuclear Security Administration (NNSA)

    NEPA Compliance Officer Rationale Office of Acquisition and Project Management APM 15-001 Application of DOE NEPA Procedure: Categorical Exclusions B3.1, Site characterization and environmental monitoring (10 CFR Part 1021, Subpart D, Appendix B). Rationale: The proposed action in the attached checklist (APM 15-001, Nye County Preemptive Review and Community-Based Groundwater Sampling Program) describes development and implementation of a groundwater monitoring program involving Nye County's

  6. Radioiodine Biogeochemistry and Prevalence in Groundwater

    SciTech Connect (OSTI)

    Kaplan, Daniel I.; Denham, Miles E.; Zhang, Saijin; Yeager, Chris; Xu, Chen; Schwehr, Kathy; Li, Hsiu-Ping; Ho, Yi-Fang; Wellman, Dawn M.; Santschi, Peter H.

    2014-08-03

    129I is commonly either the top or among the top risk drivers, along with 99Tc, at radiological waste disposal sites and contaminated groundwater sites where nuclear material fabrication or reprocessing has occurred. The risk stems largely from 129I having a high toxicity, a high bioaccumulation factor (90% of all the bodys iodine concentrates in the thyroid), a high inventory at source terms (due to its high fission yield), an extremely long half-life (16M yr), and rapid mobility in the subsurface environment. Another important reason that 129I is a key risk driver is that there is the uncertainty regarding its biogeochemical fate and transport in the environment. We typically can define 129I mass balance and flux at sites, but cannot predict accurately its response to changes in the environment. As a consequence of some of these characteristics, 129I has a very low Drinking Water Standard, DWS, which is set at 1 pCi/L, the lowest of all radionuclides in the Federal Register. Recently, significant advancements have been made in detecting iodine species at ambient groundwater concentrations, defining the nature of the organic matter and iodine bond, and quantifying the role of naturally occurring sediment microbes to promote iodine oxidation and reduction. These recent studies have led to a more mechanistic understanding of radioiodine biogeochemistry. The objective of this review is to describe these advances and to provide a state of the science of radioiodine biogeochemistry relevant to its fate and transport in the terrestrial environment and provide information useful for making decisions regarding the stewardship and remediation of 129I contaminated sites. As part of this review, knowledge gaps were identified that would significantly advance the goals of basic and applied research programs for accelerating 129I environmental remediation and reducing uncertainty associated with disposal of 129I waste. Together the information gained from addressing these

  7. Geologic mapping for groundwater resource protection and assessment

    SciTech Connect (OSTI)

    Shafer, J.M. . Earth Sciences and Resources Inst.); Berg, R.C. )

    1993-03-01

    Groundwater is a vital natural resource in the US and around the world. In order to manage and protect this often threatened resource one must better understand its occurrence, extent, and susceptibility to contamination. Geologic mapping is a fundamental approach to developing more detailed and accurate assessments of groundwater resources. The stratigraphy and lithology of earth materials provide the framework for groundwater systems, whether they are deep confined aquifers or shallow, water table environments. These same earth materials control, in large part, the rates of migration of water and contaminants into and through groundwater systems thus establishing the potential yields of the systems and their vulnerability to contamination. Geologic mapping is used to delineate and display the vertical sequencing of earth materials either in cross-section or over lateral areas as in the stack-unit geologic map. These geologic maps, along with supportive hydrogeologic information, are used to identify the three-dimensional positioning and continuity of aquifer and non-aquifer earth materials. For example, detailed stack-unit mapping to a depth of 30 meters has been completed for a portion of a northern Illinois county. Groundwater contamination potentials were assigned to various vertical sequences of materials. Where aquifers are unconfined, groundwater contamination potentials are greatest. Conversely, other considerations being equal, the thicker the confining unit, the lower the contamination potential. This information is invaluable for land use decision-making; water supply assessment, development, and management; and environmental protection planning.

  8. Groundwater surveillance plan for the Oak Ridge Reservation

    SciTech Connect (OSTI)

    Forstrom, J.M.; Smith, E.D.; Winters, S.L.; Haase, C.S.; King, H.L.; McMaster, W.M.

    1994-07-01

    US Department of Energy (DOE) Order 5400.1 requires the preparation of environmental monitoring plans and implementation of environmental monitoring programs for all DOE facilities. The order identifies two distinct components of environmental monitoring, namely effluent monitoring and environmental surveillance. In general, effluent monitoring has the objectives of characterizing contaminants and demonstrating compliance with applicable standards and permit requirements, whereas environmental surveillance has the broader objective of monitoring the effects of DOE activities on on- and off-site environmental and natural resources. The purpose of this document is to support the Environmental Monitoring Plan for the Oak Ridge Reservation (ORR) by describing the groundwater component of the environmental surveillance program for the DOE facilities on the ORR. The distinctions between groundwater effluent monitoring and groundwater surveillance have been defined in the Martin Marietta Energy Systems, Inc., Groundwater Surveillance Strategy. As defined in the strategy, a groundwater surveillance program consists of two parts, plant perimeter surveillance and off-site water well surveillance. This document identifies the sampling locations, parameters, and monitoring frequencies for both of these activities on and around the ORR and describes the rationale for the program design. The program was developed to meet the objectives of DOE Order 5400.1 and related requirements in DOE Order 5400.5 and to conform with DOE guidance on environmental surveillance and the Energy Systems Groundwater Surveillance Strategy.

  9. Stable isotope and groundwater flow dynamics of agricultural irrigation recharge into groundwater resources of the Central Valley, California

    SciTech Connect (OSTI)

    Davisson, M.L.; Criss, R.E.

    1995-01-01

    Intensive agricultural irrigation and overdraft of groundwater in the Central Valley of California profoundly affect the regional quality and availability of shallow groundwater resources. In the natural state, the {delta}{sup 18}O values of groundwater were relatively homogeneous (mostly -7.0 {+-} 0.5{per_thousand}), reflecting local meteoric recharge that slowly (1-3m/yr) flowed toward the valley axis. Today, on the west side of the valley, the isotope distribution is dominated by high {sup 18}O enclosures formed by recharge of evaporated irrigation waters, while the east side has bands of low {sup 18}O groundwater indicating induced recharge from rivers draining the Sierra Nevada mountains. Changes in {delta}{sup 18}O values caused by the agricultural recharge strongly correlate with elevated nitrate concentrations (5 to >100 mg/L) that form pervasive, non-point source pollutants. Small, west-side cities dependent solely on groundwater resources have experienced increases of >1.0 mg/L per year of nitrate for 10-30 years. The resultant high nitrates threaten the economical use of the groundwater for domestic purposes, and have forced some well shut-downs. Furthermore, since >80% of modern recharge is now derived from agricultural irrigation, and because modern recharge rates are {approximately}10 times those of the natural state, agricultural land retirement by urbanization will severely curtail the current safe-yields and promote overdraft pumping. Such overdrafting has occurred in the Sacramento metropolitan area for {approximately}40 years, creating cones of depression {approximately}25m deep. Today, groundwater withdrawal in Sacramento is approximately matched by infiltration of low {sup 18}O water (-11.0{per_thousand}) away from the Sacramento and American Rivers, which is estimated to occur at 100-300m/year from the sharp {sup 18}O gradients in our groundwater isotope map.

  10. Unsaturated Groundwater and Heat Transport Model

    Energy Science and Technology Software Center (OSTI)

    2008-05-15

    TOUGH2-MP is a massive parallel version of the TOUGH2 Code, designed for computationally efficient parallel simulation of isothermal and nonisothermal flows of multicomponent, multiphase fluids in one, two, and three-dimensional porous and fractured media. The code runs on computers with parallel architecture or clusters and can be used for applications, such as radioactive waste disposal, CO2 geological sequestration, environmental assessment and remediation, reservoir engineering, and groundwater hydrology. The parallel simulator has achieved orders-of-the-magnitude improvement inmore » computational time and/or modeling problem size. The parallel simulator uses fully implicit time differencing and solves large, sparse linear systems arising from discretization of the partial differential equations for mass and energy balance. A domain decomposition approach is adopted for multiphase flow simulations with coarse- granularity parallel computation. Current version of TOUGH2-MP includes following modules: EOS1, EOS2, EOS3, EOS4, EOS5, EOS7, EOS7R, E0S8, EOS9, ECO2N, EWASG, and T2R3D.« less

  11. Hanford Site Groundwater Monitoring for Fiscal Year 2005

    SciTech Connect (OSTI)

    Hartman, Mary J.; Morasch, Launa F.; Webber, William D.

    2006-02-28

    This report is one of the major products and deliverables of the Groundwater Remediation and Closure Assessment Projects detailed work plan for FY 2006, and reflects the requirements of The Groundwater Performance Assessment Project Quality Assurance Plan (PNNL-15014). This report presents the results of groundwater and vadose zone monitoring and remediation for fiscal year 2005 on the U.S. Department of Energy's Hanford Site, Washington. The most extensive contaminant plumes in groundwater are tritium, iodine-129, and nitrate, which all had multiple sources and are very mobile in groundwater. The largest portions of these plumes are migrating from the central Hanford Site to the southeast, toward the Columbia River. Carbon tetrachloride and associated organic constituents form a relatively large plume beneath the west-central part of the Hanford Site. Hexavalent chromium is present in plumes beneath the reactor areas along the river and beneath the central part of the site. Strontium-90 exceeds standards beneath all but one of the reactor areas. Technetium-99 and uranium plumes exceeding standards are present in the 200 Areas. A uranium plume underlies the 300 Area. Minor contaminant plumes with concentrations greater than standards include carbon-14, cesium-137, cis-1,2-dichloroethene, cyanide, fluoride, plutonium, and trichloroethene. Monitoring for the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 is conducted in 11 groundwater operable units. The purpose of this monitoring is to define and track plumes and to monitor the effectiveness of interim remedial actions. Interim groundwater remediation in the 100 Areas continued with the goal of reducing the amount of chromium (100-K, 100-D, and 100-H) and strontium-90 (100-N) reaching the Columbia River. The objective of two interim remediation systems in the 200 West Area is to prevent the spread of carbon tetrachloride and technetium-99/uranium plumes. Resource Conservation and

  12. DEVELOPMENT OF A GEOCHEMICAL MODEL FOR URANIUM TRANSPORT IN THE UNSATURATED AND SATURATED SEDIMENTS AT THE 200 WEST AREA OF THE US DEPARTMENT OF ENERGY HANFORD SITE WASHINGTON (SEPTEMBER 2004)

    SciTech Connect (OSTI)

    ADAMS SC; PETERSEN SW

    2010-03-24

    Final Deliverable under GWP-HQ-LMT-02 contract for Hanford Sci. & Tech. Gp. to BHI. The scope of work covered laboratory analyses and gephysical logging for 299-W19-43 near the 200 West U Plant. Other isotopic analyses were conducted for holes around 216-U-1&2, including U-236.

  13. BLT-EC (Breach, Leach and Transport-Equilibrium Chemistry) data input guide. A computer model for simulating release and coupled geochemical transport of contaminants from a subsurface disposal facility

    SciTech Connect (OSTI)

    MacKinnon, R.J.; Sullivan, T.M.; Kinsey, R.R.

    1997-05-01

    The BLT-EC computer code has been developed, implemented, and tested. BLT-EC is a two-dimensional finite element computer code capable of simulating the time-dependent release and reactive transport of aqueous phase species in a subsurface soil system. BLT-EC contains models to simulate the processes (container degradation, waste-form performance, transport, chemical reactions, and radioactive production and decay) most relevant to estimating the release and transport of contaminants from a subsurface disposal system. Water flow is provided through tabular input or auxiliary files. Container degradation considers localized failure due to pitting corrosion and general failure due to uniform surface degradation processes. Waste-form performance considers release to be limited by one of four mechanisms: rinse with partitioning, diffusion, uniform surface degradation, and solubility. Transport considers the processes of advection, dispersion, diffusion, chemical reaction, radioactive production and decay, and sources (waste form releases). Chemical reactions accounted for include complexation, sorption, dissolution-precipitation, oxidation-reduction, and ion exchange. Radioactive production and decay in the waste form is simulated. To improve the usefulness of BLT-EC, a pre-processor, ECIN, which assists in the creation of chemistry input files, and a post-processor, BLTPLOT, which provides a visual display of the data have been developed. BLT-EC also includes an extensive database of thermodynamic data that is also accessible to ECIN. This document reviews the models implemented in BLT-EC and serves as a guide to creating input files and applying BLT-EC.

  14. Utilizing Isotopic Uranium Ratios in Groundwater Evaluations at FUSRAP Sites

    SciTech Connect (OSTI)

    Frederick, W.T.; Keil, K.G.; Rhodes, M.C.; Peterson, J.M.; MacDonell, M.M.

    2007-07-01

    The U.S. Army Corps of Engineers Buffalo District is evaluating environmental radioactive contamination at several Formerly Utilized Sites Remedial Action Program (FUSRAP) sites throughout New York, Pennsylvania, Ohio, and Indiana. The investigations follow the process defined in the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA). Groundwater data from the Niagara Falls Storage Site (NFSS) in Lewiston, New York were evaluated for isotopic uranium ratios, specifically uranium-234 versus uranium-238 (U- 234 and U-238, respectively), and the results were presented at Waste Management 2006. Since uranium naturally occurs in all groundwater, it can be difficult to distinguish where low-concentration impacts from past releases differ from the high end of a site-specific natural background range. In natural groundwater, the ratio of U-234 to U-238 exceeds 1 (unity) due to the alpha particle recoil effect, in which U-234 is preferentially mobilized to groundwater from adjacent rock or soil. This process is very slow and may take hundreds to thousands of years before a measurable increase is seen in the natural isotopic ratio. If site releases are the source of uranium being measured in groundwater, the U-234 to U-238 ratio is commonly closer to 1, which normally reflects FUSRAP-related, uranium-contaminated wastes and soils. This lower ratio occurs because not enough residence time has elapsed since the 1940's and 1950's for the alpha particle recoil effect to have significantly altered the contamination-derived ratio. An evaluation of NFSS-specific and regional groundwater data indicate that an isotopic ratio of 1.2 has been identified as a signature value to help distinguish natural groundwater, which may have a broad background range, from zones impacted by past releases. (authors)

  15. Hanford Site ground-water monitoring for 1993

    SciTech Connect (OSTI)

    Dresel, P.E.; Luttrell, S.P.; Evans, J.C.

    1994-09-01

    This report presents the results of the Ground-Water Surveillance Project monitoring for calendar year 1993 on the Hanford Site, Washington. Hanford Site operations from 1943 onward produced large quantities of radiological and chemical waste that have impacted ground-water quality on the Site. Monitoring of water levels and ground-water chemistry is performed to track the extent of contamination and trends in contaminant concentrations. The 1993 monitoring was also designed to identify emerging ground-water quality problems. The information obtained is used to verify compliance with applicable environmental regulations and to evaluate remedial actions. Data from other monitoring and characterization programs were incorporated to provide an integrated assessment of Site ground-water quality. Additional characterization of the Site`s geologic setting and hydrology was performed to support the interpretation of contaminant distributions. Numerical modeling of sitewide ground-water flow also supported the overall project goals. Water-level monitoring was performed to evaluate ground-water flow directions, to track changes in water levels, and to relate such changes to changes in site disposal practices. Water levels over most of the Hanford Site continued to decline between June 1992 and June 1993. The greatest declines occurred in the 200-West Area. These declines are part of the continued response to the cessation of discharge to U Pond and other disposal facilities. The low permeability in this area which enhanced mounding of waste-water discharge has also slowed the response to the reduction of disposal. Water levels remained nearly constant in the vicinity of B Pond, as a result of continued disposal to the pond. Water levels measured from wells in the unconfined aquifer north and east of the Columbia River indicate that the primary source of recharge is irrigation practices.

  16. Classification of groundwater at the Nevada Test Site

    SciTech Connect (OSTI)

    Chapman, J.B.

    1994-08-01

    Groundwater occurring at the Nevada Test Site (NTS) has been classified according to the ``Guidelines for Ground-Water Classification Under the US Environmental Protection Agency (EPA) Ground-Water Protection Strategy`` (June 1988). All of the groundwater units at the NTS are Class II, groundwater currently (IIA) or potentially (IIB) a source of drinking water. The Classification Review Area (CRA) for the NTS is defined as the standard two-mile distance from the facility boundary recommended by EPA. The possibility of expanding the CRA was evaluated, but the two-mile distance encompasses the area expected to be impacted by contaminant transport during a 10-year period (EPA,s suggested limit), should a release occur. The CRA is very large as a consequence of the large size of the NTS and the decision to classify the entire site, not individual areas of activity. Because most activities are located many miles hydraulically upgradient of the NTS boundary, the CRA generally provides much more than the usual two-mile buffer required by EPA. The CRA is considered sufficiently large to allow confident determination of the use and value of groundwater and identification of potentially affected users. The size and complex hydrogeology of the NTS are inconsistent with the EPA guideline assumption of a high degree of hydrologic interconnection throughout the review area. To more realistically depict the site hydrogeology, the CRA is subdivided into eight groundwater units. Two main aquifer systems are recognized: the lower carbonate aquifer system and the Cenozoic aquifer system (consisting of aquifers in Quaternary valley fill and Tertiary volcanics). These aquifer systems are further divided geographically based on the location of low permeability boundaries.

  17. A Guide for Using the Transient Ground-Water Flow Model of the Death Valley Regional Ground-Water Flow System, Nevada and California

    SciTech Connect (OSTI)

    Joan B. Blainey; Claudia C. Faunt, and Mary C. Hill

    2006-05-16

    This report is a guide for executing numerical simulations with the transient ground-water flow model of the Death Valley regional ground-water flow system, Nevada and California using the U.S. Geological Survey modular finite-difference ground-water flow model, MODFLOW-2000. Model inputs, including observations of hydraulic head, discharge, and boundary flows, are summarized. Modification of the DVRFS transient ground-water model is discussed for two common uses of the Death Valley regional ground-water flow system model: predictive pumping scenarios that extend beyond the end of the model simulation period (1998), and model simulations with only steady-state conditions.

  18. Groundwater Level Status Report for Fiscal Year 2007 - Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Shannon P. Allen, Richard J. Koch

    2008-03-17

    The status of groundwater level monitoring at Los Alamos National Laboratory in Fiscal Year 2007 is provided in this report. The Groundwater Level Monitoring Project was instituted in 2005 to provide a framework for the collection and processing of quality controlled groundwater level data. This report summarizes groundwater level data for 166 monitoring wells, including 45 regional aquifer wells, 25 intermediate wells, and 96 alluvial wells, and 11 water supply wells. Pressure transducers were installed in 133 monitoring wells for continuous monitoring of groundwater levels. Time-series hydrographs of groundwater level data are presented along with pertinent construction and location information for each well.

  19. Utilizing Isotopic Uranium Ratios in Groundwater Evaluations at NFSS

    SciTech Connect (OSTI)

    Rhodes, M.C.; Keil, K.G.; Frederick, W.T.; Papura, T.R.; Leithner, J.S.; Peterson, J.M.; MacDonell, M.M.

    2006-07-01

    The U.S. Army Corps of Engineers (USACE) Buffalo District is currently evaluating environmental contamination at the Niagara Falls Storage Site (NFSS) under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) as part of its Formerly Utilized Sites Remedial Action Program (FUSRAP). The NFSS is located in the Town of Lewiston in western New York and has been used to store uranium-contaminated materials since 1944. Most of the radioactive materials are currently contained in an on-site structure, but past contamination remains in soil and groundwater. As a naturally occurring radionuclide, uranium is present in all groundwater. Because contamination levels at the site are quite low, it can be difficult to distinguish zones that have been impacted by the past releases from those at the high end of the natural background range. The differences in the isotopic ratio of uranium-234 (U-234) to uranium-238 (U-238) between natural groundwater systems and affected areas are being used in an innovative way to better define the nature and extent of groundwater contamination at NFSS. In natural groundwater, the ratio of U-234 to U-238 exceeds 1 due to the alpha particle recoil effect, in which U-234 is preferentially mobilized to groundwater from adjacent rock or soil. This process is very slow, and it can be hundreds to thousands of years before a measurable impact is seen in the isotopic ratio. Thus, as a result of the recoil effect, the ratio of U-234 to U-238 will be higher in natural groundwater than in contaminated groundwater. This means that if site releases were the source of the uranium being measured in groundwater at NFSS, the ratio of U-234 to U-238 would be expected to be very close to 1 (the same ratio that exists in wastes and soil at the site), because not enough time has elapsed for the alpha particle recoil effect to have significantly altered that ratio. From an evaluation of site and regional groundwater data, an isotopic ratio

  20. Hanford Site Groundwater Monitoring for Fiscal Year 2000

    SciTech Connect (OSTI)

    Hartman, Mary J.; Morasch, Launa F.; Webber, William D.

    2001-03-01

    This report presents the results of groundwater and vadose zone monitoring and remediation for fiscal year 2000 on the U.S. Department of Energy's Hanford Site, Washington. The most extensive contaminant plumes are tritium, iodine-129, and nitrate, which all had multiple sources and are very mobile in groundwater. Carbon tetrachloride and associated organic constituents form a relatively large plume beneath the central part of the Site. Hexavalent chromium is present in smaller plumes beneath the reactor areas along the river and beneath the central part of the site. Strontium-90 exceeds standards beneath each of the reactor areas, and technetium-99 and uranium are present in the 200 Areas. RCRA groundwater monitoring continued during fiscal year 2000. Vadose zone monitoring, characterization, remediation, and several technical demonstrations were conducted in fiscal year 2000. Soil gas monitoring at the 618-11 burial ground provided a preliminary indication of the location of tritium in the vadose zone and in groundwater. Groundwater modeling efforts focused on 1) identifying and characterizing major uncertainties in the current conceptual model and 2) performing a transient inverse calibration of the existing site-wide model. Specific model applications were conducted in support of the Hanford Site carbon tetrachloride Innovative Treatment Remediation Technology; to support the performance assessment of the Immobilized Low-Activity Waste Disposal Facility; and in development of the System Assessment Capability, which is intended to predict cumulative site-wide effects from all significant Hanford Site contaminants.