Sample records for generation eu gas

  1. Europium location in the AlN: Eu green phosphor prepared by a gas-reduction-nitridation route

    SciTech Connect (OSTI)

    Yin Liangjun; Zhu Qiangqiang; Yu Wei; Hao Luyuan; Xu Xin [Laboratory of Materials for Energy Conversion, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026 (China); Hu Fengchun [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei, Hefei 230026 (China); Lee, Ming-Hsien [Department of Physics, Tamkang University, Tamsui, Taipei 251, Taiwan (China)

    2012-03-01T23:59:59.000Z

    Eu doped aluminum nitride phosphors were successfully synthesized by a novel gas-reduction-nitridation route with a reaction temperature of 1400 deg. C and a soaking time of 3 h. The obtained AlN:Eu phosphors were analyzed to elucidate the location of the Eu luminescent center. High-resolution transmission electron microscopy and transmission electron microscopy-energy dispersive spectra proved that Eu was located in the crystal lattice of AlN, then EXAFS revealed that Eu occupied a highly distorted Al site coordinated by four nitrogen at about 2.30-2.40 Angst , and the second nearest neighbors of Eu were 12 Al. This could be confirmed by the first-principles calculations based on the obtained local structure around the Eu luminescence center, where the theoretical absorption spectrum was similar to the experimental excitation spectrum. X-ray appearance near edge structure showed that Eu existed in terms of both Eu{sup 3+} and Eu{sup 2+} ions, which could be related to the limited location space of Eu. High temperature treatment could significantly increase the amount of Eu{sup 2+} by the expansion of the crystal lattice, leading to an increased green luminescence of the obtained AlN:Eu phosphors.

  2. High Temperature Gas Reactors The Next Generation ?

    E-Print Network [OSTI]

    -Proof Advanced Reactor and Gas Turbine #12;Flow through Power Conversion Vessel 8 #12;9 TRISO Fuel Particle1 High Temperature Gas Reactors The Next Generation ? Professor Andrew C Kadak Massachusetts of Brayton vs. Rankine Cycle · High Temperature Helium Gas (900 C) · Direct or Indirect Cycle · Originally

  3. The Chemistry of Flammable Gas Generation

    SciTech Connect (OSTI)

    ZACH, J.J.

    2000-10-30T23:59:59.000Z

    The document collects information from field instrumentation, laboratory tests, and analytical models to provide a single source of information on the chemistry of flammable gas generation at the Hanford Site. It considers the 3 mechanisms of formation: radiolysis, chemical reactions, and thermal generation. An assessment of the current models for gas generation is then performed. The results are that the various phenomena are reasonably understood and modeled compared to field data.

  4. Onboard Plasmatron Generation of Hydrogen rich Gas for Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Onboard Plasmatron Generation of Hydrogen rich Gas for Diesel Aftertreatment and Other Applications Onboard Plasmatron Generation of Hydrogen rich Gas for Diesel Aftertreatment and...

  5. NEXT GENERATION GAS TURBINE SYSTEMS STUDY

    SciTech Connect (OSTI)

    Benjamin C. Wiant; Ihor S. Diakunchak; Dennis A. Horazak; Harry T. Morehead

    2003-03-01T23:59:59.000Z

    Under sponsorship of the U.S. Department of Energy's National Energy Technology Laboratory, Siemens Westinghouse Power Corporation has conducted a study of Next Generation Gas Turbine Systems that embraces the goals of the DOE's High Efficiency Engines and Turbines and Vision 21 programs. The Siemens Westinghouse Next Generation Gas Turbine (NGGT) Systems program was a 24-month study looking at the feasibility of a NGGT for the emerging deregulated distributed generation market. Initial efforts focused on a modular gas turbine using an innovative blend of proven technologies from the Siemens Westinghouse W501 series of gas turbines and new enabling technologies to serve a wide variety of applications. The flexibility to serve both 50-Hz and 60-Hz applications, use a wide range of fuels and be configured for peaking, intermediate and base load duty cycles was the ultimate goal. As the study progressed the emphasis shifted from a flexible gas turbine system of a specific size to a broader gas turbine technology focus. This shift in direction allowed for greater placement of technology among both the existing fleet and new engine designs, regardless of size, and will ultimately provide for greater public benefit. This report describes the study efforts and provides the resultant conclusions and recommendations for future technology development in collaboration with the DOE.

  6. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01T23:59:59.000Z

    utility electricity and natural gas purchases, amortized capital and maintenance costs for distributed generation (

  7. Gas Generation from Actinide Oxide Materials

    SciTech Connect (OSTI)

    George Bailey; Elizabeth Bluhm; John Lyman; Richard Mason; Mark Paffett; Gary Polansky; G. D. Roberson; Martin Sherman; Kirk Veirs; Laura Worl

    2000-12-01T23:59:59.000Z

    This document captures relevant work performed in support of stabilization, packaging, and long term storage of plutonium metals and oxides. It concentrates on the issue of gas generation with specific emphasis on gas pressure and composition. Even more specifically, it summarizes the basis for asserting that materials loaded into a 3013 container according to the requirements of the 3013 Standard (DOE-STD-3013-2000) cannot exceed the container design pressure within the time frames or environmental conditions of either storage or transportation. Presently, materials stabilized and packaged according to the 3013 Standard are to be transported in certified packages (the certification process for the 9975 and the SAFKEG has yet to be completed) that do not rely on the containment capabilities of the 3013 container. Even though no reliance is placed on that container, this document shows that it is highly likely that the containment function will be maintained not only in storage but also during transportation, including hypothetical accident conditions. Further, this document, by summarizing materials-related data on gas generation, can point those involved in preparing Safety Analysis Reports for Packages (SARPs) to additional information needed to assess the ability of the primary containment vessel to contain the contents and any reaction products that might reasonably be produced by the contents.

  8. Fuel cell generator containing a gas sealing means

    DOE Patents [OSTI]

    Makiel, Joseph M. (Monroeville, PA)

    1987-01-01T23:59:59.000Z

    A high temperature solid electrolyte electrochemical generator is made, operating with flowing fuel gas and oxidant gas, the generator having a thermal insulation layer, and a sealing means contacting or contained within the insulation, where the sealing means is effective to control the contact of the various gases utilized in the generator.

  9. Turbine Drive Gas Generator for Zero Emission Power Plants

    SciTech Connect (OSTI)

    Doyle, Stephen E.; Anderson, Roger E.

    2001-11-06T23:59:59.000Z

    The Vision 21 Program seeks technology development that can reduce energy costs, reduce or eliminate atmospheric pollutants from power plants, provide choices of alternative fuels, and increase the efficiency of generating systems. Clean Energy Systems is developing a gas generator to replace the traditional boiler in steam driven power systems. The gas generator offers the prospects of lower electrical costs, pollution free plant operations, choices of alternative fuels, and eventual net plant efficiencies in excess of 60% with sequestration of carbon dioxide. The technology underlying the gas generator has been developed in the aerospace industry over the past 30 years and is mature in aerospace applications, but it is as yet unused in the power industry. This project modifies and repackages aerospace gas generator technology for power generation applications. The purposes of this project are: (1) design a 10 MW gas generator and ancillary hardware, (2) fabricate the gas generator and supporting equipment, (3) test the gas generator using methane as fuel, (4) submit a final report describing the project and test results. The principal test objectives are: (1) define start-up, shut down and post shutdown control sequences for safe, efficient operation; (2) demonstrate the production of turbine drive gas comprising steam and carbon dioxide in the temperature range 1500 F to 3000 F, at a nominal pressure of 1500 psia; (3) measure and verify the constituents of the drive gas; and (4) examine the critical hardware components for indications of life limitations. The 21 month program is in its 13th month. Design work is completed and fabrication is in process. The gas generator igniter is a torch igniter with sparkplug, which is currently under-going hot fire testing. Fabrication of the injector and body of the gas generator is expected to be completed by year-end, and testing of the full gas generator will begin in early 2002. Several months of testing are anticipated. When demonstrated, this gas generator will be the prototype for use in demonstration power plants planned to be built in Antioch, California and in southern California during 2002. In these plants the gas generator will demonstrate durability and its operational RAM characteristics. In 2003, it is expected that the gas generator will be employed in new operating plants primarily in clean air non-attainment areas, and in possible locations to provide large quantities of high quality carbon dioxide for use in enhanced oil recovery or coal bed methane recovery. Coupled with an emission free coal gasification system, the CES gas generator would enable the operation of high efficiency, non-polluting coal-fueled power plants.

  10. Gas generation from Tank 241-SY-103 waste

    SciTech Connect (OSTI)

    Bryan, S.A.; King, C.M.; Pederson, L.R.; Forbes, S.V.; Sell, R.L.

    1996-04-01T23:59:59.000Z

    This report summarizes progress made in evaluating mechanisms by which flammable gases are generated in Hanford double-shell tank wastes, based on the results of laboratory tests using actual waste from Tank 241-SY-103. The objective of this work is to establish the identity and stoichiometry of degradation products formed in actual tank wastes by thermal and radiolytic processes as a function of temperature. The focus of the gas generation tests on Tank 241-SY-103 samples is first the effect of temperature on gas generation (volume and composition). Secondly, gas generation from irradiation of Tank 241-SY-103 samples at the corresponding temperatures as the thermal-only treatments will be measured in the presence of an external radiation source (using a {sup 137}Cs capsule). The organic content will be measured on a representative sample prior to gas generation experiments and again at the termination of heating and irradiation. The gas generation will be related to the extent of organic species consumption during heating. Described in this report are experimental methods used for producing and measuring gases generated at various temperatures from highly radioactive actual tank waste, and results of gas generation from Tank 241-SY-103 waste taken from its convective layer. The accurate measurement of gas generation rates from actual waste from highly radioactive waste tanks is needed to assess the potential for producing and storing flammable gases within the waste tanks. This report addresses the gas generation capacity of the waste from the convective layer of Tank 241-SY-103, a waste tank listed on the Flammable Gas Watch List due to its potential for flammable gas accumulation above the flammability limit.

  11. Next Generation Natural Gas Vehicle Activity: Natural Gas Engine and Vehicle Research & Development (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2003-09-01T23:59:59.000Z

    This fact sheet describes the status of the Next Generation Natural Gas Vehicle (NGNGV) activity, including goals, R&D progress, NGV implementation, and the transition to hydrogen.

  12. Fact #844: October 27, 2014 Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown Dataset

    Broader source: Energy.gov [DOE]

    Excel file with dataset for Fact #844:Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown

  13. Accounting for fuel price risk: Using forward natural gas prices instead of gas price forecasts to compare renewable to natural gas-fired generation

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2003-01-01T23:59:59.000Z

    vs. AEO 2001 Price Forecast Natural Gas Price (nominal $/if forwards forecasts) or natural gas-fired generation (ifs reference case forecast of natural gas prices delivered to

  14. Next Generation Natural Gas Vehicle (NGNGV) Program Fact Sheet

    SciTech Connect (OSTI)

    Walkowicz, K.

    2002-05-01T23:59:59.000Z

    Fact sheet describing U. S. DOE and NREL's development of next generation natural gas vehicles (NGVs) as a key element in its strategy to reduce oil import and vehicle pollutants.

  15. acid gas generation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the history of galaxy formation. Jason X. Prochaska 2002-08-06 48 A Silicon-Based Micro Gas Turbine Engine for Power Generation CERN Preprints Summary: This paper reports on our...

  16. addressing gas generation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Srikanta Bedathur; Thomas Neumann; Gerhard Weikum 2007-01-01 40 A Silicon-Based Micro Gas Turbine Engine for Power Generation CERN Preprints Summary: This paper reports on our...

  17. Gas Generation from K East Basin Sludges - Series II Testing

    SciTech Connect (OSTI)

    Bryan, Samuel A.; Delegard, Calvin H.; Schmidt, Andrew J.; Sell, Rachel L.; Silvers, Kurt L.; Gano, Susan R.; Thornton, Brenda M.

    2001-03-14T23:59:59.000Z

    This report describes work to examine the gas generation behavior of actual K East (KE) Basin floor, pit and canister sludge. Mixed and unmixed and fractionated KE canister sludge were tested, along with floor and pit sludges from areas in the KE Basin not previously sampled. The first report in this series focused on gas generation from KE floor and canister sludge collected using a consolidated sampling technique. The third report will present results of gas generation testing of irradiated uranium fuel fragments with and without sludge addition. The path forward for management of the K Basin Sludge is to retrieve, ship, and store the sludge at T Plant until final processing at some future date. Gas generation will impact the designs and costs of systems associated with retrieval, transportation and storage of sludge.

  18. NEW APPROACH TO ADDRESSING GAS GENERATION IN RADIOACTIVE MATERIAL PACKAGING

    SciTech Connect (OSTI)

    Watkins, R; Leduc, D; Askew, N

    2009-06-25T23:59:59.000Z

    Safety Analysis Reports for Packaging (SARP) document why the transportation of radioactive material is safe in Type A(F) and Type B shipping containers. The content evaluation of certain actinide materials require that the gas generation characteristics be addressed. Most packages used to transport actinides impose extremely restrictive limits on moisture content and oxide stabilization to control or prevent flammable gas generation. These requirements prevent some users from using a shipping container even though the material to be shipped is fully compliant with the remaining content envelope including isotopic distribution. To avoid these restrictions, gas generation issues have to be addressed on a case by case basis rather than a one size fits all approach. In addition, SARP applicants and review groups may not have the knowledge and experience with actinide chemistry and other factors affecting gas generation, which facility experts in actinide material processing have obtained in the last sixty years. This paper will address a proposal to create a Gas Generation Evaluation Committee to evaluate gas generation issues associated with Safety Analysis Reports for Packaging material contents. The committee charter could include reviews of both SARP approved contents and new contents not previously evaluated in a SARP.

  19. High order harmonic generation in dual gas multi-jets

    SciTech Connect (OSTI)

    Tosa, Valer, E-mail: valer.tosa@itim-cj.ro, E-mail: calin.hojbota@itim-cj.ro; Hojbota, Calin, E-mail: valer.tosa@itim-cj.ro, E-mail: calin.hojbota@itim-cj.ro [National Institute for Research and Development of Isotopic and Molecular Technologies, Donath 65-103, 400293 Cluj-Napoca (Romania)] [National Institute for Research and Development of Isotopic and Molecular Technologies, Donath 65-103, 400293 Cluj-Napoca (Romania)

    2013-11-13T23:59:59.000Z

    High order harmonic generation (HHG) in gas media suffers from a low conversion efficiency that has its origins in the interaction of the atom/molecule with the laser field. Phase matching is the main way to enhance the harmonic flux and several solutions have been designed to achieve it. Here we present numerical results modeling HHG in a system of multi-jets in which two gases alternate: the first gas jet (for example Ne) generates harmonics and the second one which ionizes easier, recover the phase matching condition. We obtain configurations which are experimentally feasible with respect to pressures and dimensions of the jets.

  20. Gas Generation Equations for CRiSP 1.6 April 21, 1998 1 Gas Generation Equations for CRiSP 1.6

    E-Print Network [OSTI]

    Washington at Seattle, University of

    Gas Generation Equations for CRiSP 1.6 April 21, 1998 1 Gas Generation Equations for CRiSP 1.6 Theory For CRiSP.1.6 new equations have been implemented for gas production from spill. As a part of the US Army Corps' Gas Abatement study, Waterways Experiment Station (WES) has developed these new

  1. Gas Generation from K East Basin Sludges - Series II Testing

    SciTech Connect (OSTI)

    Bryan, Samuel A.; Delegard, Calvin H.; Schmidt, Andrew J.; Sell, Rachel L.; Silvers, Kurt L.; Gano, Susan R.; Thornton, Brenda M.

    2004-04-26T23:59:59.000Z

    This report describes work to examine the gas generation behavior of actual K East (KE) Basin floor, pit and canister sludge. Mixed and unmixed and fractionated KE canister sludge were tested, along with floor and pit sludges from areas in the KE Basin not previously sampled. The first report in this series focuses on gas generation from KE floor and canister sludge collected using a consolidated sampling technique. The third report presents results of gas generation testing of irradiated uranium fuel fragments with and without sludge addition. The path forward for management of the K Basin Sludge is to retrieve, ship, and store the sludge at T Plant until final processing at some future date. Gas generation will impact the designs and costs of systems associated with retrieval, transportation and storage of sludge. This report was originally published in March 2001. In January 2004, a transcription error was discovered in the value reported for the uranium metal content of KE North Loadout Pit sample FE-3. This revision of the report corrects the U metal content of FE-3 from 0.0013 wt% to 0.013 wt%.

  2. Modular exhaust gas steam generator with common boiler casing

    SciTech Connect (OSTI)

    Kidaloski, R.G.; Olinger, H.S.; Bryk, S.A.

    1987-08-11T23:59:59.000Z

    A modular exhaust gas steam generator is described wherein each module comprises: (a) an open box frame through which hot exhaust gases travel, a portion of the frame being in contact with the gases; (b) casing means fixedly secured to selected perimeter surfaces of the box frame thereby forming an integral part of the box frame for sealably closing the surface of the box frame and for retaining the gases within the box frame; (c) tubing means extending within and nearly the height of the box frame, the tubing means being in contact with the hot gases for generating steam in the steam generator; (d) header means within the box frame and connected to the tubing means for distributing fluid thereto, and; (e) connecting means secured to an upper region of the box frame for top supporting the header and the tubing means; whereby adjacent modules are sealably secured together forming a unitary gas tight enclosure through which exhaust gases travel.

  3. Speaker to Address Impact of Natural Gas Production on Greenhouse Gas Emissions When used for power generation, Marcellus Shale natural gas can significantly reduce carbon

    E-Print Network [OSTI]

    Boyer, Elizabeth W.

    generation, Marcellus Shale natural gas can significantly reduce carbon dioxide emissions, but questions have been raised whether development of shale gas resources results in an overall lower greenhouse gas, "Life Cycle Greenhouse Gas Emissions of Marcellus Shale Gas," appeared in Environmental Research Letters

  4. Method of generating hydrogen gas from sodium borohydride

    DOE Patents [OSTI]

    Kravitz, Stanley H. (Placitas, NM); Hecht, Andrew M. (Sandia Park, NM); Sylwester, Alan P. (Albuquerque, NM); Bell, Nelson S. (Albuquerque, NM)

    2007-12-11T23:59:59.000Z

    A compact solid source of hydrogen gas, where the gas is generated by contacting water with micro-disperse particles of sodium borohydride in the presence of a catalyst, such as cobalt or ruthenium. The micro-disperse particles can have a substantially uniform diameter of 1-10 microns, and preferably about 3-5 microns. Ruthenium or cobalt catalytic nanoparticles can be incorporated in the micro-disperse particles of sodium borohydride, which allows a rapid and complete reaction to occur without the problems associated with caking and scaling of the surface by the reactant product sodium metaborate. A closed loop water management system can be used to recycle wastewater from a PEM fuel cell to supply water for reacting with the micro-disperse particles of sodium borohydride in a compact hydrogen gas generator. Capillary forces can wick water from a water reservoir into a packed bed of micro-disperse fuel particles, eliminating the need for using an active pump.

  5. Relativistic high harmonic generation in gas jet targets

    SciTech Connect (OSTI)

    Pirozhkov, A.S.; Kando, M.; Esirkepov, T.Zh.; and others

    2012-07-11T23:59:59.000Z

    We experimentally demonstrate a new regime of high-order harmonic generation by relativistic-irradiance lasers in gas jet targets. Bright harmonics with both odd and even orders, generated by linearly as well as circularly polarized pulses, are emitted in the forward direction, while the base harmonic frequency is downshifted. A 9 TW laser generates harmonics up to 360 eV, within the 'water window' spectral region. With a 120 TW laser producing 40 uJ/sr per harmonic at 120 eV, we demonstrate the photon number scalability. The observed harmonics cannot be explained by previously suggested scenarios. A novel high-order harmonics generation mechanism [T. Zh. Esirkepov et al., AIP Proceedings, this volume], which explains our experimental findings, is based on the phenomena inherent in the relativistic laser - underdense plasma interactions (self-focusing, cavity evacuation, and bow wave generation), mathematical catastrophe theory which explains formation of electron density singularities (cusps), and collective radiation due to nonlinear oscillations of a compact charge.

  6. Advanced Combustion Systems for Next Generation Gas Turbines

    SciTech Connect (OSTI)

    Joel Haynes; Jonathan Janssen; Craig Russell; Marcus Huffman

    2006-01-01T23:59:59.000Z

    Next generation turbine power plants will require high efficiency gas turbines with higher pressure ratios and turbine inlet temperatures than currently available. These increases in gas turbine cycle conditions will tend to increase NOx emissions. As the desire for higher efficiency drives pressure ratios and turbine inlet temperatures ever higher, gas turbines equipped with both lean premixed combustors and selective catalytic reduction after treatment eventually will be unable to meet the new emission goals of sub-3 ppm NOx. New gas turbine combustors are needed with lower emissions than the current state-of-the-art lean premixed combustors. In this program an advanced combustion system for the next generation of gas turbines is being developed with the goal of reducing combustor NOx emissions by 50% below the state-of-the-art. Dry Low NOx (DLN) technology is the current leader in NOx emission technology, guaranteeing 9 ppm NOx emissions for heavy duty F class gas turbines. This development program is directed at exploring advanced concepts which hold promise for meeting the low emissions targets. The trapped vortex combustor is an advanced concept in combustor design. It has been studied widely for aircraft engine applications because it has demonstrated the ability to maintain a stable flame over a wide range of fuel flow rates. Additionally, it has shown significantly lower NOx emission than a typical aircraft engine combustor and with low CO at the same time. The rapid CO burnout and low NOx production of this combustor made it a strong candidate for investigation. Incremental improvements to the DLN technology have not brought the dramatic improvements that are targeted in this program. A revolutionary combustor design is being explored because it captures many of the critical features needed to significantly reduce emissions. Experimental measurements of the combustor performance at atmospheric conditions were completed in the first phase of the program. Emissions measurements were obtained over a variety of operating conditions. A kinetics model is formulated to describe the emissions performance. The model is a tool for determining the conditions for low emission performance. The flow field was also modeled using CFD. A first prototype was developed for low emission performance on natural gas. The design utilized the tools anchored to the atmospheric prototype performance. The 1/6 scale combustor was designed for low emission performance in GE's FA+e gas turbine. A second prototype was developed to evaluate changes in the design approach. The prototype was developed at a 1/10 scale for low emission performance in GE's FA+e gas turbine. The performance of the first two prototypes gave a strong indication of the best design approach. Review of the emission results led to the development of a 3rd prototype to further reduce the combustor emissions. The original plan to produce a scaled-up prototype was pushed out beyond the scope of the current program. The 3rd prototype was designed at 1/10 scale and targeted further reductions in the full-speed full-load emissions.

  7. Promoting electricity from renewable energy sources -- lessons learned from the EU, U.S. and Japan

    E-Print Network [OSTI]

    Haas, Reinhard

    2008-01-01T23:59:59.000Z

    fluctuations. Electricity generation [TWh/year] EU-25 USA4 . Electricity generation [TWh/year] Japan EU-25 USA EU-25USA Japan Wind Waste Solar Biomass Geothermal Figure 2 Historical pattern of electricity

  8. Understanding the use of natural gas storage for generators of electricity

    SciTech Connect (OSTI)

    Beckman, K.L. [International Gas Consulting, Inc., Houston, TX (United States)

    1995-12-31T23:59:59.000Z

    Underground natural gas storage is aggressively used by a handful of utility electric generators in the United States. While storage facilities are often utilized by the natural gas pipeline industry and the local distribution companies (LDCs), regional electric generators have taken advantgage of abundant storage and pipeline capacity to develop very cost efficient gas fired electric generating capacity, especially for peaking demand. Most types of natural gas storage facilities are located underground, with a few based above-ground. These facilities have served two basic types of natural gas storage service requirements: seasonal baseload and needle peakshaving. Baseload services are typically developed in depleted oil and gas reservoirs and aquifers while mined caverns and LNG facilities (also Propane-air facilities) typically provide needle peakshaving services. Reengineering of the natural gas infrastructure will alter the historical use patterns, and will provide the electric industry with new gas supply management tools. Electric generators, as consumers of natural gas, were among the first open access shippers and, as a result of FERC Order 636, are now attempting to reposition themselves in the {open_quotes}new{close_quotes} gas industry. Stated in terms of historical consumption, the five largest gas burning utilities consume 40% of all the gas burned for electric generation, and the top twenty accounted for approximately 70%. Slightly more than 100 utilities, including municipals, have any gas fired generating capacity, a rather limited number. These five are all active consumers of storage services.

  9. Gas production response to price signals: Implications for electric power generators

    SciTech Connect (OSTI)

    Ferrell, M.L.

    1995-12-31T23:59:59.000Z

    Natural gas production response to price signals is outlined. The following topics are discussed: Structural changes in the U.S. gas exploration and production industry, industry outlook, industry response to price signals, and implications for electric power generators.

  10. BIOMASS GASIFICATION AND POWER GENERATION USING ADVANCED GAS TURBINE SYSTEMS

    SciTech Connect (OSTI)

    David Liscinsky

    2002-10-20T23:59:59.000Z

    A multidisciplined team led by the United Technologies Research Center (UTRC) and consisting of Pratt & Whitney Power Systems (PWPS), the University of North Dakota Energy & Environmental Research Center (EERC), KraftWork Systems, Inc. (kWS), and the Connecticut Resource Recovery Authority (CRRA) has evaluated a variety of gasified biomass fuels, integrated into advanced gas turbine-based power systems. The team has concluded that a biomass integrated gasification combined-cycle (BIGCC) plant with an overall integrated system efficiency of 45% (HHV) at emission levels of less than half of New Source Performance Standards (NSPS) is technically and economically feasible. The higher process efficiency in itself reduces consumption of premium fuels currently used for power generation including those from foreign sources. In addition, the advanced gasification process can be used to generate fuels and chemicals, such as low-cost hydrogen and syngas for chemical synthesis, as well as baseload power. The conceptual design of the plant consists of an air-blown circulating fluidized-bed Advanced Transport Gasifier and a PWPS FT8 TwinPac{trademark} aeroderivative gas turbine operated in combined cycle to produce {approx}80 MWe. This system uses advanced technology commercial products in combination with components in advanced development or demonstration stages, thereby maximizing the opportunity for early implementation. The biofueled power system was found to have a levelized cost of electricity competitive with other new power system alternatives including larger scale natural gas combined cycles. The key elements are: (1) An Advanced Transport Gasifier (ATG) circulating fluid-bed gasifier having wide fuel flexibility and high gasification efficiency; (2) An FT8 TwinPac{trademark}-based combined cycle of approximately 80 MWe; (3) Sustainable biomass primary fuel source at low cost and potentially widespread availability-refuse-derived fuel (RDF); (4) An overall integrated system that exceeds the U.S. Department of Energy (DOE) goal of 40% (HHV) efficiency at emission levels well below the DOE suggested limits; and (5) An advanced biofueled power system whose levelized cost of electricity can be competitive with other new power system alternatives.

  11. Corrosion-induced gas generation in a nuclear waste repository: Reactive geochemistry and multiphase flow effect

    E-Print Network [OSTI]

    Xu, T.

    2009-01-01T23:59:59.000Z

    Lying Repositories for Nuclear Waste, NAGRA Technical Reporthost rock formation for nuclear waste storage. EngineeringGas Generation in a Nuclear Waste Repository: Reactive

  12. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    SciTech Connect (OSTI)

    Stadler, Michael; Marnay, Chris; Cardoso, Goncalo; Megel, Olivier; Siddiqui, Afzal; Lai, Judy

    2009-08-15T23:59:59.000Z

    Lawrence Berkeley National Laboratory (LBL) is working with the California Energy Commission (CEC) to determine the role of distributed generation (DG) in greenhouse gas reductions. The impact of DG on large industrial sites is well known, and mostly, the potentials are already harvested. In contrast, little is known about the impact of DG on commercial buildings with peak electric loads ranging from 100 kW to 5 MW. We examine how DG with combined heat and power (CHP) may be implemented within the context of a cost minimizing microgrid that is able to adopt and operate various smart energy technologies, such as thermal and photovoltaic (PV) on-site generation, heat exchangers, solar thermal collectors, absorption chillers, and storage systems. We use a mixed-integer linear program (MILP) that has the minimization of a site's annual energy costs as objective. Using 138 representative commercial sites in California (CA) with existing tariff rates and technology data, we find the greenhouse gas reduction potential for California's commercial sector. This paper shows results from the ongoing research project and finished work from a two year U.S. Department of Energy research project. To show the impact of the different technologies on CO2 emissions, several sensitivity runs for different climate zones within CA with different technology performance expectations for 2020 were performed. The considered sites can contribute between 1 Mt/a and 1.8 Mt/a to the California Air Resources Board (CARB) goal of 6.7Mt/a CO2 abatement potential in 2020. Also, with lower PV and storage costs as well as consideration of a CO2 pricing scheme, our results indicate that PV and electric storage adoption can compete rather than supplement each other when the tariff structure and costs of electricity supply have been taken into consideration. To satisfy the site's objective of minimizing energy costs, the batteries will be charged also by CHP systems during off-peak and mid-peak hours and not only by PV during sunny on-peak hours.

  13. Cover and startup gas supply system for solid oxide fuel cell generator

    DOE Patents [OSTI]

    Singh, P.; George, R.A.

    1999-07-27T23:59:59.000Z

    A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell. 4 figs.

  14. Cover and startup gas supply system for solid oxide fuel cell generator

    DOE Patents [OSTI]

    Singh, Prabhakar (Export, PA); George, Raymond A. (Pittsburgh, PA)

    1999-01-01T23:59:59.000Z

    A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell.

  15. 3D multi-scale imaging of experimental fracture generation in shale gas reservoirs.

    E-Print Network [OSTI]

    Henderson, Gideon

    in research and shale unconventional reservoirs that will provide you with the skills to enter the oil and gas3D multi-scale imaging of experimental fracture generation in shale gas reservoirs. Supervisory-grained organic carbon-rich rocks (shales) are increasingly being targeted as shale gas "reservoirs". Due

  16. Abstract The natural gas price surged in 2004. As a result, the marginal cost of some generators burning gas also rose sharply.

    E-Print Network [OSTI]

    Tolbert, Leon M.

    Abstract The natural gas price surged in 2004. As a result, the marginal cost of some generators marginal cost, which is closely related to the natural gas price. Since gas units are usually the marginal the sensitivity of Var benefit with respect to generation cost. The U.S. natural gas industry has been

  17. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01T23:59:59.000Z

    holidays ICE: Internal combustion engine, GT: Gas turbine,indicate that internal combustion engines (ICE) with heatdominance of internal combustion engines with heat exchanger

  18. Modeling acid-gas generation from boiling chloride brines

    E-Print Network [OSTI]

    Zhang, Guoxiang

    2010-01-01T23:59:59.000Z

    Analysis Preliminary calculations assuming pure CaCl 2 solutions were carried out to investigate relationships between salt concentration, HCl gas fugacity (? partial pressure), and condensate

  19. Thermal and Radiolytic Gas Generation in Hanford High-Level Waste

    SciTech Connect (OSTI)

    Bryan, Samuel A.; Pederson, Larry R.; King, C. M.

    2000-01-31T23:59:59.000Z

    The Hanford Site has 177 underground storage tanks containing radioactive wastes that are complex mixes of radioactive and chemical products. Some of these wastes are known to generate and retain large quantities of flammable gases consisting of hydrogen, nitrous oxide, nitrogen, and ammonia. Because these gases are flammable and have the potential for rapid release, the gas generation rate for each tank must be determined to establish the flammability hazard (Johnson et al. 1997). An understanding of gas generation is important to operation of the waste tanks for several reasons. First, knowledge of the overall rate of generation is needed to verify that any given tank has sufficient ventilation to ensure that flammable gases are maintained at a safe level within the dome space. Understanding the mechanisms for production of the various gases is important so that future waste operations do not create conditions that promote the production of hydrogen, ammonia, and nitrous oxide. Studying the generation of gases also provides important data for the composition of the gas mixture, which in turn is needed to assess the flammability characteristics. Finally, information about generation of gases, including the influence of various chemical constituents, temperature, and dose, would aid in assessing the future behavior of the waste during interim storage, implementation of controls, and final waste treatment. This paper summarizes the current knowledge of gas generation pathways and discusses models used in predicting gas generation rates from actual Hanford radioactive wastes. A comparison is made between measured gas generation rates and rates by the predictive models.

  20. Steam generators two phase flows numerical simulation with liquid and gas momentum equations

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    . The secondary flow is another loop that links the steam generator and the turbines. Inside the exchangerSteam generators two phase flows numerical simulation with liquid and gas momentum equations M Abstract This work takes place in steam generators flow studies and we consider here steady state three

  1. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01T23:59:59.000Z

    fired natural gas chillers, waste heat or solar heat; hot-with HX can utilize waste heat for heating or coolingto utilize all the waste heat just reduces overall energy

  2. Thermal and radiolytic gas generation from Tank 241-S-102 waste

    SciTech Connect (OSTI)

    King, C.M.; Pederson, L.R.; Bryan, S.A.

    1997-07-01T23:59:59.000Z

    This report summarizes progress in evaluating thermal and radiolytic rate parameters for flammable gas generation in Hanford single-shell tank wastes based on the results of laboratory tests using actual waste from Tank 241-S-102 (S-102). Work described in this report was conducted at Pacific Northwest National Laboratory (PNNL) for the Flammable Gas Safety Project, whose purpose is to develop information to support Fluor Daniel Hanford (FDH) and its Project Management Hanford Contract (PHMC) subcontractors in their efforts to ensure the safe interim storage of wastes at the Hanford Site. This work is related to gas generation studies being performed at Georgia Institute of Technology (GIT) under subcontract to PNNL, using simulated wastes, and to studies being performed at Numatec Hanford Corporation (formerly Westinghouse Hanford Company) using actual wastes. The results of gas generation from Tank S-102 waste under thermal and radiolytic conditions are described in this report. The accurate measurement of gas generation rates in actual waste from highly radioactive waste tanks is needed to assess the potential for producing and storing flammable gases within the waste tanks. This report addresses the gas generation capacity of the waste from Tank S-102, a waste tank listed as high priority by the Flammable Gas Safety Program due to its potential for flammable gas accumulation above the flammability limit.

  3. This study explores how the EU Emissions Trading System (EU ETS) actually works on the ground affecting corporate climate strategies.

    E-Print Network [OSTI]

    This study explores how the EU Emissions Trading System (EU ETS) actually works on the ground@bookpoint.co.uk May 2013 322 pages Hardback 978-1-4094-6078-7 60.00 Corporate Responses to EU Emissions Trading at The Fridtjof Nansen Institute, Norway `With greenhouse gas emissions trading schemes emerging worldwide

  4. New generation enrichment monitoring technology for gas centrifuge enrichment plants

    SciTech Connect (OSTI)

    Ianakiev, Kiril D [Los Alamos National Laboratory; Alexandrov, Boian S. [Los Alamos National Laboratory; Boyer, Brian D. [Los Alamos National Laboratory; Hill, Thomas R. [Los Alamos National Laboratory; Macarthur, Duncan W. [Los Alamos National Laboratory; Marks, Thomas [Los Alamos National Laboratory; Moss, Calvin E. [Los Alamos National Laboratory; Sheppard, Gregory A. [Los Alamos National Laboratory; Swinhoe, Martyn T. [Los Alamos National Laboratory

    2008-06-13T23:59:59.000Z

    The continuous enrichment monitor, developed and fielded in the 1990s by the International Atomic Energy Agency, provided a go-no-go capability to distinguish between UF{sub 6} containing low enriched (approximately 4% {sup 235}U) and highly enriched (above 20% {sup 235}U) uranium. This instrument used the 22-keV line from a {sup 109}Cd source as a transmission source to achieve a high sensitivity to the UF{sub 6} gas absorption. The 1.27-yr half-life required that the source be periodically replaced and the instrument recalibrated. The instrument's functionality and accuracy were limited by the fact that measured gas density and gas pressure were treated as confidential facility information. The modern safeguarding of a gas centrifuge enrichment plant producing low-enriched UF{sub 6} product aims toward a more quantitative flow and enrichment monitoring concept that sets new standards for accuracy stability, and confidence. An instrument must be accurate enough to detect the diversion of a significant quantity of material, have virtually zero false alarms, and protect the operator's proprietary process information. We discuss a new concept for advanced gas enrichment assay measurement technology. This design concept eliminates the need for the periodic replacement of a radioactive source as well as the need for maintenance by experts. Some initial experimental results will be presented.

  5. Adapting On-site Electrical Generation Platforms for Producer Gas

    Broader source: Energy.gov [DOE]

    Internal combustion reciprocating engine generators (gensets) are regularly deployed at distribution centers, small municipal utilities, and public institutions to provide on-site electricity...

  6. Effects of Globally Waste Disturbing Activities on Gas Generation, Retention, and Release in Hanford Waste Tanks

    SciTech Connect (OSTI)

    Stewart, Charles W.; Fountain, Matthew S.; Huckaby, James L.; Mahoney, Lenna A.; Meyer, Perry A.; Wells, Beric E.

    2005-08-02T23:59:59.000Z

    Various operations are authorized in Hanford single- and double-shell tanks that disturb all or a large fraction of the waste. These globally waste-disturbing activities have the potential to release a large fraction of the retained flammable gas and to affect future gas generation, retention, and release behavior. This report presents analyses of the expected flammable gas release mechanisms and the potential release rates and volumes resulting from these activities. The background of the flammable gas safety issue at Hanford is summarized, as is the current understanding of gas generation, retention, and release phenomena. Considerations for gas monitoring and assessment of the potential for changes in tank classification and steady-state flammability are given.

  7. Heat exchanger design for thermoelectric electricity generation from low temperature flue gas streams

    E-Print Network [OSTI]

    Latcham, Jacob G. (Jacob Greco)

    2009-01-01T23:59:59.000Z

    An air-to-oil heat exchanger was modeled and optimized for use in a system utilizing a thermoelectric generator to convert low grade waste heat in flue gas streams to electricity. The NTU-effectiveness method, exergy, and ...

  8. What's New with the NGNGV Program? Next Generation Natural Gas Vehicle Program Newsletter, June 2002

    SciTech Connect (OSTI)

    Not Available

    2002-06-01T23:59:59.000Z

    A newsletter about what's new with the Next Generation Natural Gas Vehicle Program (NGNGV). This June 2002 update includes Phase II RFPs, Phase I update, and near-term engine development projects.

  9. A market and engineering study of a 3-kilowatt class gas turbine generator

    E-Print Network [OSTI]

    Monroe, Mark A. (Mark Alan)

    2003-01-01T23:59:59.000Z

    Market and engineering studies were performed for the world's only commercially available 3 kW class gas turbine generator, the IHI Aerospace Dynajet. The objectives of the market study were to determine the competitive ...

  10. Accounting for fuel price risk: Using forward natural gas prices instead of gas price forecasts to compare renewable to natural gas-fired generation

    SciTech Connect (OSTI)

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2003-08-13T23:59:59.000Z

    Against the backdrop of increasingly volatile natural gas prices, renewable energy resources, which by their nature are immune to natural gas fuel price risk, provide a real economic benefit. Unlike many contracts for natural gas-fired generation, renewable generation is typically sold under fixed-price contracts. Assuming that electricity consumers value long-term price stability, a utility or other retail electricity supplier that is looking to expand its resource portfolio (or a policymaker interested in evaluating different resource options) should therefore compare the cost of fixed-price renewable generation to the hedged or guaranteed cost of new natural gas-fired generation, rather than to projected costs based on uncertain gas price forecasts. To do otherwise would be to compare apples to oranges: by their nature, renewable resources carry no natural gas fuel price risk, and if the market values that attribute, then the most appropriate comparison is to the hedged cost of natural gas-fired generation. Nonetheless, utilities and others often compare the costs of renewable to gas-fired generation using as their fuel price input long-term gas price forecasts that are inherently uncertain, rather than long-term natural gas forward prices that can actually be locked in. This practice raises the critical question of how these two price streams compare. If they are similar, then one might conclude that forecast-based modeling and planning exercises are in fact approximating an apples-to-apples comparison, and no further consideration is necessary. If, however, natural gas forward prices systematically differ from price forecasts, then the use of such forecasts in planning and modeling exercises will yield results that are biased in favor of either renewable (if forwards < forecasts) or natural gas-fired generation (if forwards > forecasts). In this report we compare the cost of hedging natural gas price risk through traditional gas-based hedging instruments (e.g., futures, swaps, and fixed-price physical supply contracts) to contemporaneous forecasts of spot natural gas prices, with the purpose of identifying any systematic differences between the two. Although our data set is quite limited, we find that over the past three years, forward gas prices for durations of 2-10 years have been considerably higher than most natural gas spot price forecasts, including the reference case forecasts developed by the Energy Information Administration (EIA). This difference is striking, and implies that resource planning and modeling exercises based on these forecasts over the past three years have yielded results that are biased in favor of gas-fired generation (again, presuming that long-term stability is desirable). As discussed later, these findings have important ramifications for resource planners, energy modelers, and policy-makers.

  11. Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell Applications1

    E-Print Network [OSTI]

    Peng, Huei

    Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell the anode field of fuel cell stack is considered. The first reactor that generates the majority in the fuel cell anode and (ii) the temperature of the catalytic partial oxidation reactor during transient

  12. Injection of harmonics generated in gas in a free-electron laser providing intense and

    E-Print Network [OSTI]

    Loss, Daniel

    LETTERS Injection of harmonics generated in gas in a free-electron laser providing intense lasers promise to extend this down to femtosecond timescales. The process by which free-electron lasers of the free-electron laser saturation length, and the generation of nonlinear harmonics13 at 54 nm and 32 nm

  13. Life Cycle Greenhouse Gas Emissions from Electricity Generation (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-01-01T23:59:59.000Z

    Analysts at NREL have developed and applied a systematic approach to review the LCA literature, identify primary sources of variability and, where possible, reduce variability in GHG emissions estimates through a procedure called 'harmonization.' Harmonization of the literature provides increased precision and helps clarify the impacts of specific electricity generation choices, producing more robust results.

  14. Stresa, Italy, 26-28 April 2006 A SILICON-BASED MICRO GAS TURBINE ENGINE FOR POWER GENERATION

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Stresa, Italy, 26-28 April 2006 A SILICON-BASED MICRO GAS TURBINE ENGINE FOR POWER GENERATION X. C. Our research aims to develop a micro power generation systems based on micro gas turbine engine and a piezoelectric converter, as illustrated in Fig. 1 [6]. The micro gas turbine engine is composed of a centrifugal

  15. GREENHOUSE GAS REDUCTION POTENTIAL WITH COMBINED HEAT AND POWER WITH DISTRIBUTED GENERATION PRIME MOVERS - ASME 2012

    SciTech Connect (OSTI)

    Curran, Scott [ORNL; Theiss, Timothy J [ORNL; Bunce, Michael [ORNL

    2012-01-01T23:59:59.000Z

    Pending or recently enacted greenhouse gas regulations and mandates are leading to the need for current and feasible GHG reduction solutions including combined heat and power (CHP). Distributed generation using advanced reciprocating engines, gas turbines, microturbines and fuel cells has been shown to reduce greenhouse gases (GHG) compared to the U.S. electrical generation mix due to the use of natural gas and high electrical generation efficiencies of these prime movers. Many of these prime movers are also well suited for use in CHP systems which recover heat generated during combustion or energy conversion. CHP increases the total efficiency of the prime mover by recovering waste heat for generating electricity, replacing process steam, hot water for buildings or even cooling via absorption chilling. The increased efficiency of CHP systems further reduces GHG emissions compared to systems which do not recover waste thermal energy. Current GHG mandates within the U.S Federal sector and looming GHG legislation for states puts an emphasis on understanding the GHG reduction potential of such systems. This study compares the GHG savings from various state-of-the- art prime movers. GHG reductions from commercially available prime movers in the 1-5 MW class including, various industrial fuel cells, large and small gas turbines, micro turbines and reciprocating gas engines with and without CHP are compared to centralized electricity generation including the U.S. mix and the best available technology with natural gas combined cycle power plants. The findings show significant GHG saving potential with the use of CHP. Also provided is an exploration of the accounting methodology for GHG reductions with CHP and the sensitivity of such analyses to electrical generation efficiency, emissions factors and most importantly recoverable heat and thermal recovery efficiency from the CHP system.

  16. Recovery Act: Johnston Rhode Island Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas

    SciTech Connect (OSTI)

    Galowitz, Stephen

    2013-06-30T23:59:59.000Z

    The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Central Landfill in Johnston, Rhode Island. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting project reflected a cost effective balance of the following specific sub-objectives. 1) Meet environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas. 2) Utilize proven and reliable technology and equipment. 3) Maximize electrical efficiency. 4) Maximize electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Central Landfill. 5) Maximize equipment uptime. 6) Minimize water consumption. 7) Minimize post-combustion emissions. To achieve the Project Objective the project consisted of several components. 1) The landfill gas collection system was modified and upgraded. 2) A State-of-the Art gas clean up and compression facility was constructed. 3) A high pressure pipeline was constructed to convey cleaned landfill gas from the clean-up and compression facility to the power plant. 4) A combined cycle electric generating facility was constructed consisting of combustion turbine generator sets, heat recovery steam generators and a steam turbine. 5) The voltage of the electricity produced was increased at a newly constructed transformer/substation and the electricity was delivered to the local transmission system. The Project produced a myriad of beneficial impacts. 1) The Project created 453 FTE construction and manufacturing jobs and 25 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. 2) By combining state-of-the-art gas clean up systems with post combustion emissions control systems, the Project established new national standards for best available control technology (BACT). 3) The Project will annually produce 365,292 MWh?s of clean energy. 4) By destroying the methane in the landfill gas, the Project will generate CO{sub 2} equivalent reductions of 164,938 tons annually. The completed facility produces 28.3 MWnet and operates 24 hours a day, seven days a week.

  17. Microbial Gas Generation Under Expected Waste Isolation Pilot Plant Repository Conditions: Final Report

    SciTech Connect (OSTI)

    Gillow, J.B.; Francis, A.

    2011-07-01T23:59:59.000Z

    Gas generation from the microbial degradation of the organic constituents of transuranic (TRU) waste under conditions expected in the Waste Isolation Pilot Plant (WIPP) was investigated. The biodegradation of mixed cellulosic materials and electron-beam irradiated plastic and rubber materials (polyethylene, polyvinylchloride, hypalon, leaded hypalon, and neoprene) was examined. We evaluated the effects of environmental variables such as initial atmosphere (air or nitrogen), water content (humid ({approx}70% relative humidity, RH) and brine inundated), and nutrient amendments (nitogen phosphate, yeast extract, and excess nitrate) on microbial gas generation. Total gas production was determined by pressure measurement and carbon dioxide (CO{sub 2}) and methane (CH{sub 4}) were analyzed by gas chromatography; cellulose degradation products in solution were analyzed by high-performance liquid chromatography. Microbial populations in the samples were determined by direct microscopy and molecular analysis. The results of this work are summarized.

  18. Electrical power obtained from burning landfill gas into a gas turbine generator: Experience after one year of operation

    SciTech Connect (OSTI)

    Fabbri, R.; Mignani, N.

    1998-07-01T23:59:59.000Z

    A typical example of a ``waste to energy'' concept can be found also in the landfill environment. The biogas derived by fermentation process is usually burnt into gas engines. This choice is usually due to the electric efficiency that is normally higher than gas turbine application and to the size that usually, almost in Italian landfill size, does not allow power higher than 1,000 kW. On the other side gas turbine applications, typically based on generator sets greater than 1,000 kW do not require special biogas pre-treatment; require less maintenance and have an extremely higher reliability. The paper describes an application of a gas turbine generator of 4,800 kW outlining the experiences collected after one year of operation. During this period, the system fulfilled the target of a total operating time greater than 8,000 hours. Description is done of the biogas compression system feeding the turbine and also of the subsystem adopted to reach the above mentioned target reliability.

  19. Third generation residual gas ionization profile monitors at Fermilab

    E-Print Network [OSTI]

    Zagel, J R; Fellenz, B; Jensen, C; Lundberg, C; McCrory, E; Slimmer, D; Thurman-Keup, R; Tinsley, D

    2015-01-01T23:59:59.000Z

    The latest generation of IPMs installed in the Fermilab Main Injector and Recycler incorporate a 1 kG permanent magnet, a newly designed high-gain, rad-tolerant preamp, and a control grid to moderate the charge that is allowed to arrive on the anode pick-up strips. The control grid is intended to select a single Booster batch measurement per turn. Initially it is being used to allow for a faster turn-on of a single, high-intensity cycle in either machine. The expectation is that this will extend the Micro Channel Plate lifetime, which is the high-cost consumable in the measurement system. We discuss the new design and data acquired with this system.

  20. Corrosion-induced gas generation in a nuclear waste repository: Reactive geochemistry and multiphase flow effect

    SciTech Connect (OSTI)

    Xu, T.; Senger, R.; Finsterle, S.

    2008-10-15T23:59:59.000Z

    Corrosion of steel canisters, stored in a repository for spent fuel and high-level nuclear wastes, leads to the generation and accumulation of hydrogen gas in the backfilled emplacement tunnels, which may significantly affect long-term repository safety. Previous studies used H{sub 2} generation rates based on the volume of the waste or canister material and the stoichiometry of the corrosion reaction. However, iron corrosion and H{sub 2} generation rates vary with time, depending on factors such as amount of iron, water availability, water contact area, and aqueous and solid chemistry. To account for these factors and feedback mechanisms, we developed a chemistry model related to iron corrosion, coupled with two-phase (liquid and gas) flow phenomena that are driven by gas-pressure buildup associated with H{sub 2} generation and water consumption. Results indicate that by dynamically calculating H{sub 2} generation rates based on a simple model of corrosion chemistry, and by coupling this corrosion reaction with two-phase flow processes, the degree and extent of gas pressure buildup could be much smaller compared to a model that neglects the coupling between flow and reactive transport mechanisms. By considering the feedback of corrosion chemistry, the gas pressure increases initially at the canister, but later decreases and eventually returns to a stabilized pressure that is slightly higher than the background pressure. The current study focuses on corrosion under anaerobic conditions for which the coupled hydrogeochemical model was used to examine the role of selected physical parameters on the H{sub 2} gas generation and corresponding pressure buildup in a nuclear waste repository. The developed model can be applied to evaluate the effect of water and mineral chemistry of the buffer and host rock on the corrosion reaction for future site-specific studies.

  1. Gas generation from low-level radioactive waste: Concerns for disposal

    SciTech Connect (OSTI)

    Siskind, B.

    1992-01-01T23:59:59.000Z

    The Advisory Committee on Nuclear Waste (ACNW) has urged the Nuclear Regulatory Commission (NRC) to reexamine the topic of hydrogen gas generation from low-level radioactive waste (LLW) in closed spaces to ensure that the slow buildup of hydrogen from water-bearing wastes in sealed containers does not become a problem for long-term safe disposal. Brookhaven National Laboratory (BNL) has prepared a report, summarized in this paper, for the NRC to respond to these concerns. The paper discusses the range of values for G(H{sub 2}) reported for materials of relevance to LLW disposal; most of these values are in the range of 0.1 to 0.6. Most studies of radiolytic hydrogen generation indicate a leveling off of pressurization, probably because of chemical kinetics involving, in many cases, the radiolysis of water within the waste. Even if no leveling off occurs, realistic gas leakage rates (indicating poor closure by gaskets on drums and liners) will result in adequate relief of pressure for radiolytic gas generation from the majority of commercial sector LLW packages. Biodegradative gas generation, however, could pose a pressurization hazard even at realistic gas leakage rates. Recommendations include passive vents on LLW containers (as already specified for high integrity containers) and upper limits to the G values and/or the specific activity of the LLW.

  2. Gas generation from low-level radioactive waste: Concerns for disposal

    SciTech Connect (OSTI)

    Siskind, B.

    1992-04-01T23:59:59.000Z

    The Advisory Committee on Nuclear Waste (ACNW) has urged the Nuclear Regulatory Commission (NRC) to reexamine the topic of hydrogen gas generation from low-level radioactive waste (LLW) in closed spaces to ensure that the slow buildup of hydrogen from water-bearing wastes in sealed containers does not become a problem for long-term safe disposal. Brookhaven National Laboratory (BNL) has prepared a report, summarized in this paper, for the NRC to respond to these concerns. The paper discusses the range of values for G(H{sub 2}) reported for materials of relevance to LLW disposal; most of these values are in the range of 0.1 to 0.6. Most studies of radiolytic hydrogen generation indicate a leveling off of pressurization, probably because of chemical kinetics involving, in many cases, the radiolysis of water within the waste. Even if no leveling off occurs, realistic gas leakage rates (indicating poor closure by gaskets on drums and liners) will result in adequate relief of pressure for radiolytic gas generation from the majority of commercial sector LLW packages. Biodegradative gas generation, however, could pose a pressurization hazard even at realistic gas leakage rates. Recommendations include passive vents on LLW containers (as already specified for high integrity containers) and upper limits to the G values and/or the specific activity of the LLW.

  3. Life Cycle GHG Emissions from Conventional Natural Gas Power Generation: Systematic Review and Harmonization (Presentation)

    SciTech Connect (OSTI)

    Heath, G.; O'Donoughue, P.; Whitaker, M.

    2012-12-01T23:59:59.000Z

    This research provides a systematic review and harmonization of the life cycle assessment (LCA) literature of electricity generated from conventionally produced natural gas. We focus on estimates of greenhouse gases (GHGs) emitted in the life cycle of electricity generation from conventionally produced natural gas in combustion turbines (NGCT) and combined-cycle (NGCC) systems. A process we term "harmonization" was employed to align several common system performance parameters and assumptions to better allow for cross-study comparisons, with the goal of clarifying central tendency and reducing variability in estimates of life cycle GHG emissions. This presentation summarizes preliminary results.

  4. Recovery Act: Brea California Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas

    SciTech Connect (OSTI)

    Galowitz, Stephen

    2012-12-31T23:59:59.000Z

    The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Olinda Landfill near Brea, California. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting Project reflected a cost effective balance of the following specific sub-objectives: Meeting the environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas Utilizing proven and reliable technology and equipment Maximizing electrical efficiency Maximizing electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Olinda Landfill Maximizing equipment uptime Minimizing water consumption Minimizing post-combustion emissions The Project produced and will produce a myriad of beneficial impacts. o The Project created 360 FTE construction and manufacturing jobs and 15 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. o By combining state-of-the-art gas clean up systems with post combustion emissions control systems, the Project established new national standards for best available control technology (BACT). o The Project will annually produce 280,320 MWhs of clean energy o By destroying the methane in the landfill gas, the Project will generate CO2 equivalent reductions of 164,938 tons annually. The completed facility produces 27.4 MWnet and operates 24 hours a day, seven days a week.

  5. Technology on In-Situ Gas Generation to Recover Residual Oil Reserves

    SciTech Connect (OSTI)

    Sayavur Bakhtiyarov

    2008-02-29T23:59:59.000Z

    This final technical report covers the period October 1, 1995 to February 29, 2008. This chapter begins with an overview of the history of Enhanced Oil Recovery techniques and specifically, CO2 flood. Subsequent chapters conform to the manner consistent with the Activities, Tasks, and Sub-tasks of the project as originally provided in Exhibit C1 in the Project Management Plan dated September 20, 1995. These chapters summarize the objectives, status and conclusions of the major project activities performed during the project period. The report concludes by describing technology transfer activities stemming from the project and providing a reference list of all publications of original research work generated by the project team or by others regarding this project. The overall objective of this project was a final research and development in the United States a technology that was developed at the Institute for Geology and Development of Fossil Fuels in Moscow, Russia. Before the technology can be convincingly adopted by United States oil and gas producers, the laboratory research was conducted at Mew Mexico Institute of Mining and Technology. The experimental studies were conducted to measure the volume and the pressure of the CO{sub 2} gas generated according to the new Russian technology. Two experimental devices were designed, built and used at New Mexico Tech facilities for these purposes. The designed setup allowed initiating and controlling the reaction between the 'gas-yielding' (GY) and 'gas-forming' (GF) agents proposed by Russian technology. The temperature was controlled, and the generated gas pressure and volume were recorded during the reaction process. Additionally, the effect of surfactant addition on the effectiveness of the process was studied. An alternative GY reactant was tested in order to increase the efficiency of the CO2 gas generation process. The slim tube and the core flood experimental studies were conducted to define the sweep efficiency of the in-situ generated CO{sub 2} gas. A set of core flood experiments were conducted to define effect of surfactant on recovery efficiency. The results demonstrated obvious advantages of the foamy system over the brine solution in order to achieve higher sweep efficiency and recovery coefficient. It is shown that a slug injection is not an efficient method for mixing GY and GF solutions and it can't generate considerable gas inside the slim-tube.

  6. Ultraviolet-driven white light generation from oxyfluoride glass co-doped with Tm{sup 3+}-Tb{sup 3+}-Eu{sup 3+}

    SciTech Connect (OSTI)

    Kuznetsov, A. S.; Nikitin, A.; Tikhomirov, V. K.; Shestakov, M. V.; Moshchalkov, V. V. [INPAC-Institute for Nanoscale Physics and Chemistry, KULeuven, Celestijnenlaan 200D, Heverlee, 3001 Leuven (Belgium)] [INPAC-Institute for Nanoscale Physics and Chemistry, KULeuven, Celestijnenlaan 200D, Heverlee, 3001 Leuven (Belgium)

    2013-04-22T23:59:59.000Z

    Tm{sup 3+}-Tb{sup 3+}-Eu{sup 3+} co-doped oxyfluoride glasses, doped with about 3.0 mol. % TmF{sub 3}, 0.25 mol. % TbF{sub 3}, and 0.25 mol. % EuF{sub 3}, have been prepared by melt quenching technique. Under excitation at commercial 365 nm, the rare-earth co-dopants are all directly excited and emit in the blue, green, and red, respectively, without appreciable energy transfer amongst the co-dopants. Tint of the white luminescence can be adjusted by changing the ratio of the co-dopants. Properties of the glass host promote excellent dissolution of the co-dopants and low non-radiative decay rate. The white emission at 365 nm excitation is suitable for light emitting diodes applications.

  7. Generation of electron beams from a laser wakefield acceleration in pure neon gas

    SciTech Connect (OSTI)

    Li, Song; Hafz, Nasr A. M., E-mail: nasr@sjtu.edu.cn; Mirzaie, Mohammad; Elsied, Ahmed M. M.; Ge, Xulei; Liu, Feng; Sokollik, Thomas; Chen, Min; Sheng, Zhengming; Zhang, Jie, E-mail: jzhang1@sjtu.edu.cn [Key Laboratory for Laser Plasmas (MOE) and Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240 (China); Tao, Mengze; Chen, Liming [Bejing National Laboratory of Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

    2014-08-15T23:59:59.000Z

    We report on the generation of quasimonoenergetic electron beams by the laser wakefield acceleration of 1750 TW, 30 fs laser pulses in pure neon gas jet. The generated beams have energies in the range 40120?MeV and up to ?430 pC of charge. At a relatively high density, we observed multiple electron beamlets which has been interpreted by simulations to be the result of breakup of the laser pulse into multiple filaments in the plasma. Each filament drives its own wakefield and generates its own electron beamlet.

  8. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine industrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01T23:59:59.000Z

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100{degrees}F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600{degrees}F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  9. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine induustrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01T23:59:59.000Z

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100[degrees]F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600[degrees]F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  10. Closed cycle MHD generator with nonuniform gas-plasma flow driving recombinated plasma clots

    SciTech Connect (OSTI)

    Slavin, V.S. [Krasnoyarsk State Technical Univ. (Russian Federation); Danilov, V.V.; Sokolov, V.S. [Krasnoyarsk State Univ. (Russian Federation)

    1996-12-31T23:59:59.000Z

    A new concept of a closed cycle MHD generator without alkali seed has been suggested. The essence of it is the phenomenon of frozen conductivity for recombined plasma which appears for noble gas at T{sub e} > 4,000 K. At the inlet of the MHD channel in supersonic flow of noble gas (He or Ar) the plasma clots with electron density about 10{sup 15} cm{sup {minus}3} are formed by pulsed intense electron beam with energy about 300 keV. Gas flow drives these clots in a cross magnetic field along the MHD channel which has electrodes connected with the load by Faraday scheme. The gas flow pushes plasma layers and produces electric power at the expense of enthalpy extraction. The numerical simulation has shown that a supersonic gas flow, containing about 4 plasma layers in the MHD channel simultaneously, is braked without shock waves creation. This type of the MHD generator can provide more than 30% enthalpy extraction ratio and about 80% isentropic efficiency. The advantages of the new concept are the following: (a) possibility of working at higher pressure and lower temperature, (b) operation with alkali seed.

  11. Storm fronts over galaxy discs: Models of how waves generate extraplanar gas and its anomalous kinematics

    E-Print Network [OSTI]

    Curtis Struck; Daniel C. Smith

    2009-05-15T23:59:59.000Z

    The existence of partially ionized, diffuse gas and dust clouds at kiloparsec scale distances above the central planes of edge-on, galaxy discs was an unexpected discovery about 20 yrs ago. Subsequent observations showed that this EDIG (extended or extraplanar diffuse interstellar gas) has rotation velocities approximately 10-20% lower than those in the central plane, and have been hard to account for. Here we present results of hydrodynamic models, with radiative cooling and heating from star formation. We find that in models with star formation generated stochastically across the disc an extraplanar gas layer is generated as long as the star formation is sufficiently strong. However, this gas rotates at nearly the same speed as the mid-plane gas. We then studied a range of models with imposed spiral or bar waves in the disc. EDIG layers were also generated in these models, but primarily over the wave regions, not over the entire disc. Because of this partial coverage, the EDIG clouds move radially, as well as vertically, with the result that observed kinematic anomalies are reproduced. The implication is that the kinematic anomalies are the result of three-dimensional motions when the cylindrical symmetry of the disc is broken. Thus, the kinematic anomalies are the result of bars or strong waves, and more face-on galaxies with such waves should have an asymmetric EDIG component. The models also indicate that the EDIG can contain a significant fraction of cool gas, and that some star formation can be triggered at considerable heights above the disc midplane. We expect all of these effects to be more prominent in young, forming discs, to play a role in rapidly smoothing disc asymmetries, and in working to self-regulate disc structure.

  12. Accounting for fuel price risk when comparing renewable to gas-fired generation: the role of forward natural gas prices

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2004-01-01T23:59:59.000Z

    Profiles of Renewable and Natural Gas Electricity Contracts:Price Risk: Using Forward Natural Gas Prices Instead of Gas2001). Which way the natural gas price: an attempt to

  13. Variance Analysis of Wind and Natural Gas Generation under Different Market Structures: Some Observations

    SciTech Connect (OSTI)

    Bush, B.; Jenkin, T.; Lipowicz, D.; Arent, D. J.; Cooke, R.

    2012-01-01T23:59:59.000Z

    Does large scale penetration of renewable generation such as wind and solar power pose economic and operational burdens on the electricity system? A number of studies have pointed to the potential benefits of renewable generation as a hedge against the volatility and potential escalation of fossil fuel prices. Research also suggests that the lack of correlation of renewable energy costs with fossil fuel prices means that adding large amounts of wind or solar generation may also reduce the volatility of system-wide electricity costs. Such variance reduction of system costs may be of significant value to consumers due to risk aversion. The analysis in this report recognizes that the potential value of risk mitigation associated with wind generation and natural gas generation may depend on whether one considers the consumer's perspective or the investor's perspective and whether the market is regulated or deregulated. We analyze the risk and return trade-offs for wind and natural gas generation for deregulated markets based on hourly prices and load over a 10-year period using historical data in the PJM Interconnection (PJM) from 1999 to 2008. Similar analysis is then simulated and evaluated for regulated markets under certain assumptions.

  14. Accounting for fuel price risk when comparing renewable togas-fired generation: the role of forward natural gas prices

    SciTech Connect (OSTI)

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2004-07-17T23:59:59.000Z

    Unlike natural gas-fired generation, renewable generation (e.g., from wind, solar, and geothermal power) is largely immune to fuel price risk. If ratepayers are rational and value long-term price stability, then--contrary to common practice--any comparison of the levelized cost of renewable to gas-fired generation should be based on a hedged gas price input, rather than an uncertain gas price forecast. This paper compares natural gas prices that can be locked in through futures, swaps, and physical supply contracts to contemporaneous long-term forecasts of spot gas prices. We find that from 2000-2003, forward gas prices for terms of 2-10 years have been considerably higher than most contemporaneous long-term gas price forecasts. This difference is striking, and implies that comparisons between renewable and gas-fired generation based on these forecasts over this period have arguably yielded results that are biased in favor of gas-fired generation.

  15. The DOE/NREL Next Generation Natural Gas Vehicle Program - An Overview

    SciTech Connect (OSTI)

    Kevin Walkowicz; Denny Stephens; Kevin Stork

    2001-05-14T23:59:59.000Z

    This paper summarizes the Next Generation Natural Gas Vehicle (NG-NGV) Program that is led by the U.S. Department Of Energy's (DOE's) Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The goal of this program is to develop and implement one Class 3-6 compressed natural gas (CNG) prototype vehicle and one Class 7-8 liquefied natural gas (LNG) prototype vehicle in the 2004 to 2007 timeframe. OHVT intends for these vehicles to have 0.5 g/bhp-hr or lower emissions of oxides of nitrogen (NOx) by 2004 and 0.2 g/bhp-hr or lower NOx by 2007. These vehicles will also have particulate matter (PM) emissions of 0.01 g/bhp-hr or lower by 2004. In addition to ambitious emissions goals, these vehicles will target life-cycle economics that are compatible with their conventionally fueled counterparts.

  16. Rapid hydrogen gas generation using reactive thermal decomposition of uranium hydride.

    SciTech Connect (OSTI)

    Kanouff, Michael P.; Van Blarigan, Peter; Robinson, David B.; Shugard, Andrew D.; Gharagozloo, Patricia E.; Buffleben, George M.; James, Scott Carlton; Mills, Bernice E.

    2011-09-01T23:59:59.000Z

    Oxygen gas injection has been studied as one method for rapidly generating hydrogen gas from a uranium hydride storage system. Small scale reactors, 2.9 g UH{sub 3}, were used to study the process experimentally. Complimentary numerical simulations were used to better characterize and understand the strongly coupled chemical and thermal transport processes controlling hydrogen gas liberation. The results indicate that UH{sub 3} and O{sub 2} are sufficiently reactive to enable a well designed system to release gram quantities of hydrogen in {approx} 2 seconds over a broad temperature range. The major system-design challenge appears to be heat management. In addition to the oxidation tests, H/D isotope exchange experiments were performed. The rate limiting step in the overall gas-to-particle exchange process was found to be hydrogen diffusion in the {approx}0.5 {mu}m hydride particles. The experiments generated a set of high quality experimental data; from which effective intra-particle diffusion coefficients can be inferred.

  17. Chemical reaction model for oil and gas generation from type 1 and type 2 kerogen

    SciTech Connect (OSTI)

    Braun, R.L.; Burnham, A.K.

    1993-06-01T23:59:59.000Z

    A global model for the generation of oil and gas from petroleum source rocks is presented. The model consists of 13 chemical species and 10 reactions, including an alternate-pathway mechanism for kerogen pyrolysis. Reaction rate parameters and stoichiometry coefficients determined from a variety of pyrolysis data are given for both type I and type II kerogen. Use of the chemical reaction model is illustrated for typical geologic conditions.

  18. Plug-in electric vehicle introduction in the EU

    E-Print Network [OSTI]

    Sisternes, Fernando J. de $q (Fernando Jos Sisternes Jimnez)

    2010-01-01T23:59:59.000Z

    Plug-in electric vehicles (PEVs) could significantly reduce gasoline consumption and greenhouse gas (GHG) emissions in the EU's transport sector. However, PEV well-towheel (WTW) emissions depend on improvements in vehicle ...

  19. Accounting for fuel price risk: Using forward natural gas prices instead of gas price forecasts to compare renewable to natural gas-fired generation

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2003-01-01T23:59:59.000Z

    Associates, citing NYMEX natural gas bid-offer spreadAnalysis of the Market for Natural Gas Futures. The Energyas a Physical Hedge Against Natural Gas Price Movements.

  20. Slurry growth, gas retention, and flammable gas generation by Hanford radioactive waste tanks: Synthetic waste studies, FY 1991

    SciTech Connect (OSTI)

    Bryan, S.A.; Pederson, L.R.; Ryan, J.L.; Scheele, R.D.; Tingey, J.M.

    1992-08-01T23:59:59.000Z

    Of 177 high-level waste storage tanks on the Hanford Site, 23 have been placed on a safety watch list because they are suspected of producing flammable gases in flammable or explosive concentrate. One tankin particular, Tank 241-SY-101 (Tank 101-SY), has exhibited slow increases in waste volume followed by a rapid decrease accompanied by venting of large quantities of gases. The purpose of this study is to help determine the processes by which flammable gases are produced, retained, and eventually released from Tank 101-SY. Waste composition data for single- and double-shell waste tanks on the flammable gas watch listare critically reviewed. The results of laboratory studies using synthetic double-shell wastes are summarized, including physical and chemical properties of crusts that are formed, the stoichiometry and rate ofgas generation, and mechanisms responsible for formation of a floating crust.

  1. Modeling and experiments on differential pumping in linear plasma generators operating at high gas flows

    SciTech Connect (OSTI)

    Eck, H. J. N. van; Koppers, W. R.; Rooij, G. J. van; Goedheer, W. J.; Cardozo, N. J. Lopes; Kleyn, A. W. [FOM-Institute for Plasma Physics Rijnhuizen, Association EURATOM-FOM, Trilateral Euregio Cluster, P.O. Box 1207, 3430 BE Nieuwegein (Netherlands); Engeln, R.; Schram, D. C. [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)

    2009-03-15T23:59:59.000Z

    The direct simulation Monte Carlo (DSMC) method was used to investigate the efficiency of differential pumping in linear plasma generators operating at high gas flows. Skimmers are used to separate the neutrals from the plasma beam, which is guided from the source to the target by a strong axial magnetic field. In this way, the neutrals are prevented to reach the target region. The neutral flux to the target must be lower than the plasma flux to enable ITER relevant plasma-surface interaction (PSI) studies. It is therefore essential to control the neutral gas dynamics. The DSMC method was used to model the expansion of a hot gas in a low pressure vessel where a small discrepancy in shock position was found between the simulations and a well-established empirical formula. Two stage differential pumping was modeled and applied in the linear plasma devices Pilot-PSI and PLEXIS. In Pilot-PSI a factor of 4.5 pressure reduction for H{sub 2} has been demonstrated. Both simulations and experiments showed that the optimum skimmer position depends on the position of the shock and therefore shifts for different gas parameters. The shape of the skimmer has to be designed such that it has a minimum impact on the shock structure. A too large angle between the skimmer and the forward direction of the gas flow leads to an influence on the expansion structure. A pressure increase in front of the skimmer is formed and the flow of the plasma beam becomes obstructed. It has been shown that a skimmer with an angle around 53 deg. gives the best performance. The use of skimmers is implemented in the design of the large linear plasma generator Magnum-PSI. Here, a three stage differentially pumped vacuum system is used to reach low enough neutral pressures near the target, opening a door to PSI research in the ITER relevant regime.

  2. The marginal costs and pricing of gas system upgrades to accommodate new electric generators

    SciTech Connect (OSTI)

    Ambrose, B.

    1995-12-31T23:59:59.000Z

    In the coming years, competitive forces and restructuring in the electric industry can be expected to increase substantially the demand for gas delivery service to new electric generating units by local distribution companies (LDCs) and pipeline companies across the United States. In meeting this demand, it is important that the prices paid by electric generators for gas delivery service properly reflect the costs of the resources utilized in providing service to them in order that their decisions regarding what to build and where as well as the manner in which their units are dispatched are as efficient as possible from a societal standpoint. This will assure that society`s resources will be neither squandered nor underutilized in providing service to these generators and aid in assuring that, once built, the units are run in an efficient manner. While the most efficient solution to this problem is a secondary market in tradeable pipeline capacity rights, we do not have such a system in place at this time. Further, tradeable rights for LDC capacity may be difficult to establish. An interim solution that will work in the confines of the present system and not create problems for the transition to tradeable rights is required. This purpose of this paper is to set out the important first principals involved in applying marginal costing to the provision of gas delivery service to new electric generating units rather than to present empirical data on the marginal costs of such service. Experience has shown that marginal costs are usually unique to the particular situation being costed.

  3. Gas Generation from K East Basin Sludges and Irradiated Metallic Uranium Fuel Particles Series III Testing

    SciTech Connect (OSTI)

    Schmidt, Andrew J.; Delegard, Calvin H.; Bryan, Samuel A.; Elmore, Monte R.; Sell, Rachel L.; Silvers, Kurt L.; Gano, Susan R.; Thornton, Brenda M.

    2003-08-01T23:59:59.000Z

    The path forward for managing of Hanford K Basin sludge calls for it to be packaged, shipped, and stored at T Plant until final processing at a future date. An important consideration for the design and cost of retrieval, transportation, and storage systems is the potential for heat and gas generation through oxidation reactions between uranium metal and water. This report, the third in a series (Series III), describes work performed at the Pacific Northwest National Laboratory (PNNL) to assess corrosion and gas generation from irradiated metallic uranium particles (fuel particles) with and without K Basin sludge addition. The testing described in this report consisted of 12 tests. In 10 of the tests, 4.3 to 26.4 g of fuel particles of selected size distribution were placed into 60- or 800-ml reaction vessels with 0 to 100 g settled sludge. In another test, a single 3.72-g fuel fragment (i.e., 7150-mm particle) was placed in a 60 ml reaction vessel with no added sludge. The twelfth test contained only sludge. The fuel particles were prepared by crushing archived coupons (samples) from an irradiated metallic uranium fuel element. After loading the sludge materials (whether fuel particles, mixtures of fuel particles and sludge, or sludge-only) into reaction vessels, the solids were covered with an excess of K Basin water, the vessels closed and connected to a gas measurement manifold, and the vessels back-flushed with inert neon cover gas. The vessels were then heated to a constant temperature. The gas pressures and temperatures were monitored continuously from the times the vessels were purged. Gas samples were collected at various times during the tests, and the samples analyzed by mass spectrometry. Data on the reaction rates of uranium metal fuel particles with water as a function of temperature and particle size were generated. The data were compared with published studies on metallic uranium corrosion kinetics. The effects of an intimate overlying sludge layer (''blanket'') on the uranium metal corrosion rates were also evaluated.

  4. An Approach to Generating Summaries of Time Series Data in the Gas Turbine Domain Jin Yu and Jim Hunter and Ehud Reiter and Somayajulu Sripada

    E-Print Network [OSTI]

    Sripada, Yaji

    An Approach to Generating Summaries of Time Series Data in the Gas Turbine Domain Jin Yu and Jim an approach to generating summaries of time series data in the gas turbine domain using AI techniques. Through the production of textual summaries. We extend KBTA framework to the gas turbine domain and propose to generate

  5. Plant power : the cost of using biomass for power generation and potential for decreased greenhouse gas emissions

    E-Print Network [OSTI]

    Cuellar, Amanda Dulcinea

    2012-01-01T23:59:59.000Z

    To date, biomass has not been a large source of power generation in the United States, despite the potential for greenhouse gas (GHG) benefits from displacing coal with carbon neutral biomass. In this thesis, the fuel cycle ...

  6. Evaluation of an Integrated Gas-Cooled Reactor Simulator and Brayton Turbine-Generator

    SciTech Connect (OSTI)

    Hissam, D. Andy; Stewart, Eric [National Aeronautics and Space Administration, Marshall Space Flight Center, ER34, Huntsville, AL 35812 (United States)

    2006-07-01T23:59:59.000Z

    A closed-loop Brayton cycle, powered by a fission reactor, offers an attractive option for generating both planetary and in-space electric power. Non-nuclear testing of this type of system provides the opportunity to safely work out integration and system control challenges for a modest investment. Recognizing this potential, a team at Marshall Space Flight Center has evaluated the viability of integrating and testing an existing gas-cooled reactor simulator and a modified, commercially available, Brayton turbine-generator. Since these two systems were developed independently of one another, this evaluation sought to determine if they could be operated together at acceptable power levels, temperatures, and pressures. Thermal, fluid, and structural analyses show that this combined system can operate at acceptable power levels and temperatures. In addition, pressure drops across the reactor simulator, although higher than desired, are also viewed as acceptable. Three potential working fluids for the system were evaluated: N{sub 2}, He/Ar, and He/Xe. Other technical issues, such as electrical breakdown in the generator and the operation of the Brayton foil bearings using various gas mixtures, were also investigated. (authors)

  7. A Silicon-Based Micro Gas Turbine Engine for Power Generation

    E-Print Network [OSTI]

    Shan, X -C; Maeda, R; Sun, Y F; Wu, M; Hua, J S

    2007-01-01T23:59:59.000Z

    This paper reports on our research in developing a micro power generation system based on gas turbine engine and piezoelectric converter. The micro gas turbine engine consists of a micro combustor, a turbine and a centrifugal compressor. Comprehensive simulation has been implemented to optimal the component design. We have successfully demonstrated a silicon-based micro combustor, which consists of seven layers of silicon structures. A hairpin-shaped design is applied to the fuel/air recirculation channel. The micro combustor can sustain a stable combustion with an exit temperature as high as 1600 K. We have also successfully developed a micro turbine device, which is equipped with enhanced micro air-bearings and driven by compressed air. A rotation speed of 15,000 rpm has been demonstrated during lab test. In this paper, we will introduce our research results major in the development of micro combustor and micro turbine test device.

  8. Conversion of Mixed Oxygenates Generated from Synthesis Gas to Fuel Range Hydrocarbon

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Gerber, Mark A.; Lilga, Michael A.; Flake, Matthew D.

    2012-08-19T23:59:59.000Z

    The growing dependence in the U.S. on foreign crude oil supplies and increased concerns regarding greenhouse gas emission has generated considerable interest in research to develop renewable and environmentally friendly liquid hydrocarbon transportation fuels. One of the strategies for achieving this is to produce intermediate compounds such as alcohols and other simple oxygenates from biomass generated synthesis gas (mixture of carbon monoxide and hydrogen) and further convert them into liquid hydrocarbons. The focus of this research is to investigate the effects of mixed oxygenates intermediate product compositions on the conversion step to produce hydrocarbon liquids. A typical mixed oxygenate stream is expected to contain water (around 50%), alcohols, such as methanol and ethanol (around 35%), and smaller quantities of oxygenates such as acetaldehyde, acetic acid and ethyl acetate. However the ratio and the composition of the mixed oxygenate stream generated from synthesis gas vary significantly depending on the catalyst used and the process conditions. Zeolite catalyzed deoxygenation of methanol accompanied by chain growth is well understood under Methanol-to-Gasoline (MTG) like reaction conditions using an H-ZSM-5 zeolite as the catalyst6-8. Research has also been conducted to a limited extent in the past with higher alcohols, but not with other oxygenates present9-11. Also there has been little experimental investigation into mixtures containing substantial amounts of water. The latter is of particular interest because water separation from the hydrocarbon product would be less energy intensive than first removing it from the oxygenate intermediate stream prior to hydrocarbon synthesis, potentially reducing overall processing costs.

  9. Gas generation by pure and impure plutonium oxide materials in sealed containers.

    SciTech Connect (OSTI)

    Berg, J. M. (John M.); McFarlan, James T.; Padilla, D. D. (Dennis D.); Veirs, D. K. (Douglas Kirk); Worl, L. A. (Laura A.); Harradine, D. M. (David M.); McInroy, R. E. (Rhonda E.); Hill, D. D. (Dallas D.); Prenger, F. Coyne; Morris, J. S. (John S.)

    2003-01-01T23:59:59.000Z

    The Department of Energy (DOE) standard, DOE-STD-3013-2000, establishes criteria for stabilizing, packaging, and long term safe storage of plutonium-bearing materials at DOE facilities . The Standard applies to oxide or metal that contains at least 30 weight percent plutonium plus uranium. For oxide material a maximum of 5 kg of material is packaged in a nested set of two individually welded containers and the requirements include material stabilization at 950 C, 0 .5 weight percent moisture content or less, and less than nineteen watts of power per sealed container . The welded containers ensure that any gas generated due to radiolysis will be retained within the container . Although the 3013 package provides for a robust storage system, its long-term safety performance has not been demonstrated . To ensure failures do not occur while the sealed containers are being stored for up to 50 years, a DOE complex-wide integrated surveillance program has been established to measure the gas generation rates of these materials. At Los Alamos National Laboratory (LANL), the shelf life project monitors gases over oxide materials in a limited number of large-scale 3013 inner containers charged with 5 kg of material and in many small-scale containers with 10 gram samples taken from site-wide representative materials actually being stored . The small-scale containers allow more sample types and conditions to be studied. This information provides invaluable, defensible results for assuring safe long-term storage of these materials in sealed containers . Initial results on gas generation are presented.

  10. Low-NO{sub x} combustion chamber for a power generation gas-turbine unit

    SciTech Connect (OSTI)

    Gutnik, M.N.; Tumanovsky, A.G.; Soudarev, A.V.; Vinogradov, E.D.; Zakharov, Y.I.; Lobanov, D.V.; Akulov, V.A.

    1998-07-01T23:59:59.000Z

    The findings of the experimental studies over major operating characteristics of a full-scale combustion chamber (CC) for a new power generation 25 MW gas turbine unit of the AO ``Turbomotorny Zavod'' (Ekaterinburg) production are presented. A technique of the pre-mixed lean combustion with the excess air coefficient being approximately equal to 1.9--2.2 underlies the low NO{sub x} combustor design. Interrelations between the major combustor characteristics and design and duty parameters in parallel with the optimum algorithm of the combustor loading ensuring the minimum toxic exhausts into atmosphere are also shown in the paper.

  11. Technology Adoption and Regulatory Regimes: Gas Turbines Electricity Generators from 1980 to 2001

    E-Print Network [OSTI]

    Ishii, Jun

    2004-01-01T23:59:59.000Z

    Scheibel (1997) Current Gas Turbine Developments and Futurefor Heavy-Duty Gas Turbines, October 2000. Available onlineNext Evolution of the F Gas Turbine, April 2001. Available

  12. Nonlinear absorption and harmonic generation of laser in a gas with anharmonic clusters

    SciTech Connect (OSTI)

    Kumar, Manoj; Tripathi, V. K. [Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016 (India)

    2013-02-15T23:59:59.000Z

    The nonlinear absorption and harmonic generation of intense short pulse laser in a gas embedded with anharmonic clusters are investigated theoretically. When the laser induced excursion of cluster electrons becomes comparable to cluster radius, the restoration force on electrons no longer remains linearly proportional to the excursion. As a consequence, the plasmon resonance is broadened, leading to broadband laser absorption. It also leads to second and third harmonic generations, at much higher level than the one due to ponderomotive nonlinearity. The harmonic yield is resonantly enhanced at the plasmon resonance {omega}={omega}{sub pe}/{radical}(3), where {omega} is the frequency of the laser and {omega}{sub pe} is the plasma frequency of cluster electrons.

  13. PV output smoothing using a battery and natural gas engine-generator.

    SciTech Connect (OSTI)

    Johnson, Jay; Ellis, Abraham; Denda, Atsushi [Shimizu Corporation; Morino, Kimio [Shimizu Corporation; Shinji, Takao [Tokyo Gas Co., Ltd.; Ogata, Takao [Tokyo Gas Co., Ltd.; Tadokoro, Masayuki [Tokyo Gas Co., Ltd.

    2013-02-01T23:59:59.000Z

    In some situations involving weak grids or high penetration scenarios, the variability of photovoltaic systems can affect the local electrical grid. In order to mitigate destabilizing effects of power fluctuations, an energy storage device or other controllable generation or load can be used. This paper describes the development of a controller for coordinated operation of a small gas engine-generator set (genset) and a battery for smoothing PV plant output. There are a number of benefits derived from using a traditional generation resource in combination with the battery; the variability of the photovoltaic system can be reduced to a specific level with a smaller battery and Power Conditioning System (PCS) and the lifetime of the battery can be extended. The controller was designed specifically for a PV/energy storage project (Prosperity) and a gas engine-generator (Mesa Del Sol) currently operating on the same feeder in Albuquerque, New Mexico. A number of smoothing simulations of the Prosperity PV were conducted using power data collected from the site. By adjusting the control parameters, tradeoffs between battery use and ramp rates could be tuned. A cost function was created to optimize the control in order to balance, in this example, the need to have low ramp rates with reducing battery size and operation. Simulations were performed for cases with only a genset or battery, and with and without coordinated control between the genset and battery, e.g., without the communication link between sites or during a communication failure. The degree of smoothing without coordinated control did not change significantly because the battery dominated the smoothing response. It is anticipated that this work will be followed by a field demonstration in the near future.

  14. Accounting for fuel price risk: Using forward natural gas prices instead of gas price forecasts to compare renewable to natural gas-fired generation

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2003-01-01T23:59:59.000Z

    Associates, citing NYMEX natural gas bid-offer spreadAnalysis of the Market for Natural Gas Futures. The EnergyProfiles of Renewable and Natural Gas Electricity Contracts:

  15. Development of air-cooled ceramic nozzles for a power-generating gas turbine

    SciTech Connect (OSTI)

    Tsuchiya, T.; Furuse, Y.; Yoshino, S. [Tokyo Electric Power Co., Yokohama, Kanagawa (Japan). Engineering R and D Center; Chikami, R.; Tsukuda, Y.; Mori, M. [Mitsubishi Heavy Industries, Ltd., Takasago, Hyogo (Japan)

    1996-10-01T23:59:59.000Z

    The development of air-cooled ceramic nozzle vanes for a power-generating gas turbine has been reported. To make up the limited temperature resistance of present ceramic materials, the utilization of a small amount of cooling air has been studied for the first-stage nozzle vanes of a 1,500 C class gas turbine. A series of cascade tests were carried out for the designed air-cooled Si{sub 3}N{sub 4} nozzle vanes under 6 atm and 1,500 C conditions. It was confirmed that the maximum ceramic temperature can be maintained below 1,300 C by a small amount of cooling air. In spite of the increased thermal stresses from local cooling, all Si{sub 3}N{sub 4} nozzle vanes survived the cascade tests, including both steady-state and transients of emergency shutdown. The potential for an air-cooled ceramic nozzle was demonstrated for a 1,500 C class gas turbine application.

  16. Experimental and theoretical studies of particle generation afterlaser ablation of copper with background gas at atmosphericpressure

    SciTech Connect (OSTI)

    Wen, Sy-Bor; Mao, Xianglei; Greif, Ralph; Russo, Richard E.

    2007-05-31T23:59:59.000Z

    Laser ablation has proven to be an effective method for generating nanoparticles; particles are produced in the laser induced vapor plume during the cooling stage. To understand the in-situ condensation process, a series of time resolved light scattering images were recorded and analyzed. Significant changes in the condensation rate and the shape of the condensed aerosol plume were observed in two background gases, helium and argon. The primary particle shape and size distribution were measured using a transmission electron microscope (TEM), a scanning electron microscope (SEM) and a differential mobility analyzer (DMA). The gas dynamics simulation included nucleation and coagulation within the vapor plume, heat and mass transfer from the vapor plume to the background gas, and heat transfer to the sample. The experimental data and the calculated evolution of the shape of the vapor plume showed the same trend for the spatial distribution of the condensed particles in both background gases. The simulated particle size distribution also qualitatively agreed with the experimental data. It was determined that the laser energy, the physical properties of the background gas (conductivity, diffusivity and viscosity), and the shape of the ablation system (ablation chamber and the layout of the sample) have strong effects on the condensation process and the subsequent sizes, shapes and degree of aggregation of the particles.

  17. Low NO{sub x} turbine power generation utilizing low Btu GOB gas. Final report, June--August 1995

    SciTech Connect (OSTI)

    Ortiz, I.; Anthony, R.V.; Gabrielson, J.; Glickert, R.

    1995-08-01T23:59:59.000Z

    Methane, a potent greenhouse gas, is second only to carbon dioxide as a contributor to potential global warming. Methane liberated by coal mines represents one of the most promising under exploited areas for profitably reducing these methane emissions. Furthermore, there is a need for apparatus and processes that reduce the nitrogen oxide (NO{sub x}) emissions from gas turbines in power generation. Consequently, this project aims to demonstrate a technology which utilizes low grade fuel (CMM) in a combustion air stream to reduce NO{sub x} emissions in the operation of a gas turbine. This technology is superior to other existing technologies because it can directly use the varying methane content gases from various streams of the mining operation. The simplicity of the process makes it useful for both new gas turbines and retrofitting existing gas turbines. This report evaluates the feasibility of using gob gas from the 11,000 acre abandoned Gateway Mine near Waynesburg, Pennsylvania as a fuel source for power generation applying low NO{sub x} gas turbine technology at a site which is currently capable of producing low grade GOB gas ({approx_equal} 600 BTU) from abandoned GOB areas.

  18. Roadmapping the Resolution of Gas Generation Issues in Packages Containing Radioactive Waste/Materials - A Status Report

    SciTech Connect (OSTI)

    Luke, D.E. (INEEL); Hamp, S. (DOE-Albuquerque Operations Office)

    2002-01-04T23:59:59.000Z

    Gas generation issues, particularly hydrogen, have been an area of concern for the transport and storage of radioactive materials and waste in the Department of Energy (DOE) Complex. Potentially combustible gases can be generated through a variety of reactions, including chemical reactions and radiolytic decomposition of hydrogen-containing material. Since transportation regulations prohibit shipment of explosives and radioactive materials together, it was decided that hydrogen generation was a problem that warranted the execution of a high-level roadmapping effort. This paper discusses the major gas generation issues within the DOE Complex and the research that has been and is being conducted by the transuranic (TRU) waste, nuclear materials, and spent nuclear fuels (SNF) programs within DOE's Environmental Management (EM) organizations to address gas generation concerns. This paper presents a ''program level'' roadmap that links technology development to program needs and identifies the probability of success in an effort to understand the programmatic risk associated with the issue of gas generation. This paper also presents the status of the roadmap and follow-up activities.

  19. Roadmapping the Resolution of Gas Generation Issues in Packages Containing Radioactive Waste/Materials - A Status Report

    SciTech Connect (OSTI)

    Luke, Dale Elden; Hamp, S.

    2002-02-01T23:59:59.000Z

    Gas generation issues, particularly hydrogen, have been an area of concern for the transport and storage of radioactive materials and waste in the Department of Energy (DOE) Complex. Potentially combustible gases can be generated through a variety of reactions, including chemical reactions and radiolytic decomposition of hydrogen- containing material. Since transportation regulations prohibit shipment of explosives and radioactive materials together, it was decided that hydrogen generation was a problem that warranted the execution of a high-level roadmapping effort. This paper discusses the major gas generation issues within the DOE Complex and the research that has been and is being conducted by the transuranic (TRU) waste, nuclear materials, and spent nuclear fuels (SNF) programs within DOEs Environmental Management (EM) organizations to address gas generation concerns. This paper presents a "program level" roadmap that links technology development to program needs and identifies the probability of success in an effort to understand the programmatic risk associated with the issue of gas generation. This paper also presents the status of the roadmap and follow-up activities.

  20. Composition, preparation, and gas generation results from simulated wastes of Tank 241-SY-101

    SciTech Connect (OSTI)

    Bryan, S.A.; Pederson, L.R.

    1994-08-01T23:59:59.000Z

    This document reviews the preparation and composition of simulants that have been developed to mimic the wastes temporarily stored in Tank 241-SY-101 at Hanford. The kinetics and stoichiometry of gases that are generated using these simulants are also compared, considering the roles of hydroxide, chloride, and transition metal ions; the identities of organic constituents; and the effects of dilution, radiation, and temperature. Work described in this report was conducted for the Flammable Gas Safety Program at Pacific Northwest Laboratory, (a) whose purpose is to develop information that is necessary to mitigate potential safety hazards associated with waste tanks at the Hanford Site. The goal of this research and of related efforts at the Georgia Institute of Technology (GIT), Argonne National Laboratory (ANL), and Westinghouse Hanford Company (WHC) is to determine the thermal and thermal/radiolytic mechanisms by which flammable and other gases are produced in Hanford wastes, emphasizing those stored in Tank 241-SY-101. A variety of Tank 241-SY-101 simulants have been developed to date. The use of simulants in laboratory testing activities provides a number of advantages, including elimination of radiological risks to researchers, lower costs associated with experimentation, and the ability to systematically alter simulant compositions to study the chemical mechanisms of reactions responsible for gas generation. The earliest simulants contained the principal inorganic components of the actual waste and generally a single complexant such as N-(2-hydroxyethyl) ethylenediaminetriacetic acid (HEDTA) or ethylenediaminetriacetic acid (EDTA). Both homogeneous and heterogeneous compositional forms were developed. Aggressive core sampling and analysis activities conducted during Windows C and E provided information that was used to design new simulants that more accurately reflected major and minor inorganic components.

  1. Steps being taken to resolve questions on natural gas use for power generation in the New England region

    SciTech Connect (OSTI)

    Gulick, C. [Boston Gas Company, Boston, MA (United States)

    1995-12-31T23:59:59.000Z

    Steps being taken to resolve questions on natural gas use for power generation in the New England Region are outlined. The following topics are discussed: bridging the gap, gas/electric discussion group, energy consumption by fuel, NEPOOL energy mix forecast, the players and their needs, pipelines serving New England, evaluation of pipeline reliability, industry survey, summary of survey conclusions, communications, operational differences, recommended red alert information sequence, handling a crisis, and major accomplishments to date.

  2. Development of a hydrogen generator based on the partial oxidation of natural gas integrated with PEFC

    SciTech Connect (OSTI)

    Recupero, V.; Pino, L.; Di Leonardo, R.; Lagana, M. [Inst. CNR-TAE, Messina (Italy)

    1998-12-31T23:59:59.000Z

    As is well known, the most acknowledged process for generation of hydrogen for fuel cells is based upon the steam reforming of methane or natural gas. A valid alternative could be a process based on partial oxidation of methane, since the process is mildly exothermic and therefore not energy intensive. Consequently, great interest is expected from conversion of methane into syngas, if an autothermal, low energy intensive, compact and reliable process could be developed. This paper covers the activities, performed by CNR Institute Transformation and Storage of Energy, Messina, Italy, on theoretical and experimental studies for a compact hydrogen generator, via catalytic selective partial oxidation of methane, integrated with a PEFC (Polymer Electrolyte Fuel Cell). In particular, the project focuses the attention on methane partial oxidation via heterogeneous selective catalysts, in order to: demonstrate the basic Catalytic Selective Partial Oxidation of Methane (CSPOM) technology in a subscale prototype, equivalent to a nominal output of 5 kWe; develop the CSPOM technology for its application in electric energy production by means of fuel cells; assess, by a balance of plant analysis, and a techno-economic evaluation, the potential benefits of the CSPOM for different categories of fuel cells.

  3. MOX and MOX with 237Np/241Am Inert Fission Gas Generation Comparison in ATR

    SciTech Connect (OSTI)

    G. S. Chang; M. Robel; W. J. Carmack; D. J. Utterbeck

    2006-06-01T23:59:59.000Z

    The treatment of spent fuel produced in nuclear power generation is one of the most important issues to both the nuclear community and the general public. One of the viable options to long-term geological disposal of spent fuel is to extract plutonium, minor actinides (MA), and potentially long-lived fission products from the spent fuel and transmute them into short-lived or stable radionuclides in currently operating light-water reactors (LWR), thus reducing the radiological toxicity of the nuclear waste stream. One of the challenges is to demonstrate that the burnup-dependent characteristic differences between Reactor-Grade Mixed Oxide (RG-MOX) fuel and RG-MOX fuel with MA Np-237 and Am 241 are minimal, particularly, the inert gas generation rate, such that the commercial MOX fuel experience base is applicable. Under the Advanced Fuel Cycle Initiative (AFCI), developmental fuel specimens in experimental assembly LWR-2 are being tested in the northwest (NW) I-24 irradiation position of the Advanced Test Reactor (ATR). The experiment uses MOX fuel test hardware, and contains capsules with MOX fuel consisting of mixed oxide manufactured fuel using reactor grade plutonium (RG-Pu) and mixed oxide manufactured fuel using RG-Pu with added Np/Am. This study will compare the fuel neutronics depletion characteristics of Case-1 RG-MOX and Case-2 RG-MOX with Np/Am.

  4. Scaling of the generation of high-order harmonics in large gas media with focal length

    SciTech Connect (OSTI)

    Boutu, W.; Auguste, T.; Caumes, J. P.; Carre, B. [Service des Photons, Atomes et Molecules, CEA-Saclay, F-91191 Gif-sur-Yvette Cedex (France); Merdji, H. [Service des Photons, Atomes et Molecules, CEA-Saclay, F-91191 Gif-sur-Yvette Cedex (France); PULSE Institute for Ultrafast Energy Science, Stanford Linear Accelerator Center, Stanford University, 2575 Sand Hill Road, Menlo Park, California 94025 (United States)

    2011-11-15T23:59:59.000Z

    We present theoretical and experimental results on high-order harmonic generation in a low-density few-centimeter-long gas medium (L{sub med}{<=} 10 cm). We study the dependence with focal length of harmonic efficiency. Theoretically, we consider in detail the generation of the 25th harmonic of a short pulse Ti:sapphire laser in argon. Within the strong-field approximation for the atomic dipole, and a complete account of the macroscopic propagation, we compute the number of photons produced as a function of the medium parameters and the focusing conditions. The simulations show that, at constant intensity, the emission of the 25th harmonic scales with the focal length as {approx}f{sup 4} at low pressure (P=2 Torr) and as {approx}f{sup 6} at higher pressure (P=5 Torr). At constant laser energy, we find that the harmonic signal scales approximately as f{sup 2} at low pressure and as f{sup 4} at higher pressure. Those numerical results are compared with experimental data.

  5. Life Cycle Greenhouse Gas Emissions of Coal-Fired Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Whitaker, M.; Heath, G. A.; O'Donoughue, P.; Vorum, M.

    2012-04-01T23:59:59.000Z

    This systematic review and harmonization of life cycle assessments (LCAs) of utility-scale coal-fired electricity generation systems focuses on reducing variability and clarifying central tendencies in estimates of life cycle greenhouse gas (GHG) emissions. Screening 270 references for quality LCA methods, transparency, and completeness yielded 53 that reported 164 estimates of life cycle GHG emissions. These estimates for subcritical pulverized, integrated gasification combined cycle, fluidized bed, and supercritical pulverized coal combustion technologies vary from 675 to 1,689 grams CO{sub 2}-equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh) (interquartile range [IQR]= 890-1,130 g CO{sub 2}-eq/kWh; median = 1,001) leading to confusion over reasonable estimates of life cycle GHG emissions from coal-fired electricity generation. By adjusting published estimates to common gross system boundaries and consistent values for key operational input parameters (most importantly, combustion carbon dioxide emission factor [CEF]), the meta-analytical process called harmonization clarifies the existing literature in ways useful for decision makers and analysts by significantly reducing the variability of estimates ({approx}53% in IQR magnitude) while maintaining a nearly constant central tendency ({approx}2.2% in median). Life cycle GHG emissions of a specific power plant depend on many factors and can differ from the generic estimates generated by the harmonization approach, but the tightness of distribution of harmonized estimates across several key coal combustion technologies implies, for some purposes, first-order estimates of life cycle GHG emissions could be based on knowledge of the technology type, coal mine emissions, thermal efficiency, and CEF alone without requiring full LCAs. Areas where new research is necessary to ensure accuracy are also discussed.

  6. Thermal and Radiolytic Gas Generation Tests on Material from Tanks 241-U-103, 241-AW-101, 241-S-106, and 241-S-102: Status Report

    SciTech Connect (OSTI)

    King, C.M.; Bryan, S.A.

    1999-06-17T23:59:59.000Z

    This report summarizes progress in evaluating thermal and radiolytic flammable gas generation in actual Hanford single-shell tank wastes. The work described was conducted at Pacific Northwest National Laboratory (PNNL) for the Flammable Gas Safety Project, whose purpose is to develop information to support DE&S Hanford (DESH) and Project Management Hanford Contract (PHMC) subcontractors in their efforts to ensure the safe interim storage of wastes at the Hanford Site. This work is related to gas generation studies performed by Numatec Hanford Corporation (formerly Westinghouse Hanford Company). This report describes the results of laboratory tests of gas generation from actual convective layer wastes from Tank 241-U-103 under thermal and radiolytic conditions. Accurate measurements of gas generation rates from highly radioactive tank wastes are needed to assess the potential for producing and storing flammable gases within the tanks. The gas generation capacity of the waste in Tank 241-U-103 is a high priority for the Flammable Gas Safety Program due to its potential for accumulating gases above the flammability limit (Johnson et al, 1997). The objective of this work was to establish the composition of gaseous degradation products formed in actual tank wastes by thermal and radiolytic processes as a function of temperature. The gas generation tests on Tank 241-U-103 samples focused first on the effect of temperature on the composition and rate of gas generation Generation rates of nitrogen, nitrous oxide, methane, and hydrogen increased with temperature, and the composition of the product gas mixture varied with temperature.

  7. Generation of gas-phase zirconium fluoroanions by electrospray of an ionic liquid

    SciTech Connect (OSTI)

    Gary S. Groenewold; James E. Delmore; Michael T. Benson; Tetsuya Tsuda; Rika Hagiwara

    2014-06-01T23:59:59.000Z

    RATIONALE: When measuring extremely wide isotope ratios (= 1 x 109) accelerator mass spectrometry (AMS) is the instrument of choice, however it requires an anion for injection into the tandem accelerator. Since many elements do not have positive electronegativities they do not form stable negative atomic ions, and hence are not compatible for isotope ratio measurement using AMS. Thus new approaches for forming anions are sought; fluoroanions are particularly attractive because fluorine is monoisotopic, and thus will not have overlapping isobars with the isotope of interest. METHODS: An approach is described for making zirconium fluoroanions using the fluorinating ionic liquid (IL) 1-ethyl-3-methylimidazolium fluorohydrogenate, which was used to generate abundant [ZrF5-] using electrospray ionization. The IL was dissolved in acetonitrile, combined with a dilute solution of either Zr4+ or ZrO2+, and then electrosprayed. Mass analysis and collision induced dissociation were conducted using a time-of-flight mass spectrometer. Cluster structures were predicted using density functional theory calculations. RESULTS: The fluorohydrogenate IL solutions generated abundant [ZrF5-] starting from solutions of both Zr4+ and ZrO2+. The mass spectra also contained IL-bearing cluster ions, whose compositions indicated the presence of [ZrF6]2- in solution, a conclusion supported by the structural calculations. Rinsing out the zirconium-IL solution with acetonitrile decreased the IL clusters, but enhanced [ZrF5]-, which was sorbed by the polymeric electrospray supply capillary, and then released upon rinsing. This reduced the ion background in the mass spectrum. CONCLUSIONS: The fluorohydrogenate-IL solutions are a facile way to form zirconium fluoroanions in the gas phase using electrospray. The approach has potential as a source of fluoroanions for injection into an AMS, which would enable high-sensitivity measurement of minor zirconium isotopes, and benefits from the absence of overlapping isobars caused by the charge carrier (i.e., the monoisotopic fluorine atoms).

  8. Onboard Plasmatron Generation of Hydrogen rich Gas for Diesel Engine Exhaust Aftertreatment and Other Applications

    SciTech Connect (OSTI)

    Bromberg, L.; Cohn, D.R.; Heywood,J.; Rabinovich, A.

    2002-08-25T23:59:59.000Z

    Plasmatron reformers can provide attractive means for conversion of diesel fuel into hydrogen rich gas. The hydrogen rich gas can be used for improved NOx trap technology and other aftertreatment applications.

  9. Technology Adoption and Regulatory Regimes: Gas Turbines Electricity Generators from 1980 to 2001

    E-Print Network [OSTI]

    Ishii, Jun

    2004-01-01T23:59:59.000Z

    Clean Air Amendments helped lower the cost of natural gas turbines vis-a-vis coal based technologies.

  10. Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation

    SciTech Connect (OSTI)

    Rue, David

    2013-09-30T23:59:59.000Z

    The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTIs pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis found a number of modifications and adjustments that could provide higher efficiency and better use of available work. Conclusions from this analysis will help guide the analyses and CFD modeling in future process development. The MBB technology has the potential to be a disruptive technology that will enable coal combustion power plants to be built and operated in a cost effective way, cleanly with no carbon dioxide emissions. A large amount of work is needed to quantify and confirm the great promise of the MBB technology. A Phase 2 proposal was submitted to DOE and other sponsors to address the most critical MBB process technical gaps. The Phase 2 proposal was not accepted for current DOE support.

  11. A new generation of multilateral well enhances small gas field economics

    E-Print Network [OSTI]

    Atse, Jean-Philippe

    2004-09-30T23:59:59.000Z

    and performed a Monte Carlo simulation to account for cost uncertainties. In addition to the actual 70 MMSCFD gas contract, I simulated a progressive gas demand increase of 20 MMSCFD every five years and a 150 MMSCFD gas market. The study demonstrates...

  12. Comparative life-cycle air emissions of coal, domestic natural gas, LNG, and SNG for electricity generation

    SciTech Connect (OSTI)

    Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews [Carnegie Mellon University, Pittsburgh, PA (United States). Civil and Environmental Engineering Department

    2007-09-15T23:59:59.000Z

    The U.S. Department of Energy (DOE) estimates that in the coming decades the United States' natural gas (NG) demand for electricity generation will increase. Estimates also suggest that NG supply will increasingly come from imported liquefied natural gas (LNG). Additional supplies of NG could come domestically from the production of synthetic natural gas (SNG) via coal gasification-methanation. The objective of this study is to compare greenhouse gas (GHG), SOx, and NOx life-cycle emissions of electricity generated with NG/LNG/SNG and coal. This life-cycle comparison of air emissions from different fuels can help us better understand the advantages and disadvantages of using coal versus globally sourced NG for electricity generation. Our estimates suggest that with the current fleet of power plants, a mix of domestic NG, LNG, and SNG would have lower GHG emissions than coal. If advanced technologies with carbon capture and sequestration (CCS) are used, however, coal and a mix of domestic NG, LNG, and SNG would have very similar life-cycle GHG emissions. For SOx and NOx we find there are significant emissions in the upstream stages of the NG/LNG life-cycles, which contribute to a larger range in SOx and NOx emissions for NG/LNG than for coal and SNG. 38 refs., 3 figs., 2 tabs.

  13. Mitigation of Hydrogen Gas Generation from the Reaction of Water with Uranium Metal in K Basins Sludge

    SciTech Connect (OSTI)

    Sinkov, Sergey I.; Delegard, Calvin H.; Schmidt, Andrew J.

    2010-01-29T23:59:59.000Z

    Means to decrease the rate of hydrogen gas generation from the chemical reaction of uranium metal with water were identified by surveying the technical literature. The underlying chemistry and potential side reactions were explored by conducting 61 principal experiments. Several methods achieved significant hydrogen gas generation rate mitigation. Gas-generating side reactions from interactions of organics or sludge constituents with mitigating agents were observed. Further testing is recommended to develop deeper knowledge of the underlying chemistry and to advance the technology aturation level. Uranium metal reacts with water in K Basin sludge to form uranium hydride (UH3), uranium dioxide or uraninite (UO2), and diatomic hydrogen (H2). Mechanistic studies show that hydrogen radicals (H) and UH3 serve as intermediates in the reaction of uranium metal with water to produce H2 and UO2. Because H2 is flammable, its release into the gas phase above K Basin sludge during sludge storage, processing, immobilization, shipment, and disposal is a concern to the safety of those operations. Findings from the technical literature and from experimental investigations with simple chemical systems (including uranium metal in water), in the presence of individual sludge simulant components, with complete sludge simulants, and with actual K Basin sludge are presented in this report. Based on the literature review and intermediate lab test results, sodium nitrate, sodium nitrite, Nochar Acid Bond N960, disodium hydrogen phosphate, and hexavalent uranium [U(VI)] were tested for their effects in decreasing the rate of hydrogen generation from the reaction of uranium metal with water. Nitrate and nitrite each were effective, decreasing hydrogen generation rates in actual sludge by factors of about 100 to 1000 when used at 0.5 molar (M) concentrations. Higher attenuation factors were achieved in tests with aqueous solutions alone. Nochar N960, a water sorbent, decreased hydrogen generation by no more than a factor of three while disodium phosphate increased the corrosion and hydrogen generation rates slightly. U(VI) showed some promise in attenuating hydrogen but only initial testing was completed. Uranium metal corrosion rates also were measured. Under many conditions showing high hydrogen gas attenuation, uranium metal continued to corrode at rates approaching those observed without additives. This combination of high hydrogen attenuation with relatively unabated uranium metal corrosion is significant as it provides a means to eliminate uranium metal by its corrosion in water without the accompanying hazards otherwise presented by hydrogen generation.

  14. Hydordesulfurization of dibenzothiophene using hydrogen generated in situ by the water-gas shift reaction in a trickle bed reactor

    E-Print Network [OSTI]

    Hook, Bruce David

    1984-01-01T23:59:59.000Z

    ; Lands and Mrnkova, 1966). Singhal et al. (1981a, b) studied DBT desulfurization at 558-623K, 3. 1 MPa, in the gas phase over a standard CoO-MoO, /7-AlsO, catalyst. Both of these mechanisms are consistent with the generalized mechanism for HDS...HYDRODESULFURIZATION OF DIBENZOTHIOPHENE USING HYDROGEN GENERATED IN SITU BY THE WATER ? GAS SHIFT REACTION IN A TRICKLE BED REACTOR A Thesis BRUCE DAVID HOOK Submitted to the Graduate College of Texas A&M University in partial fulfillment...

  15. Landfill gas cleanup for carbonate fuel cell power generation. Final report

    SciTech Connect (OSTI)

    Steinfield, G.; Sanderson, R.

    1998-02-01T23:59:59.000Z

    Landfill gas represents a significant fuel resource both in the US and worldwide. The emissions of landfill gas from existing landfills has become an environmental liability contributing to global warming and causing odor problems. Landfill gas has been used to fuel reciprocating engines and gas turbines, and may also be used to fuel carbonate fuel cells. Carbonate fuel cells have high conversion efficiencies and use the carbon dioxide present in landfill gas as an oxidant. There are, however, a number of trace contaminants in landfill gas that contain chlorine and sulfur which are deleterious to fuel cell operation. Long-term economical operation of fuel cells fueled with landfill gas will, therefore, require cleanup of the gas to remove these contaminants. The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined to economically reduce contaminant levels to the specifications for carbonate fuel cells. A pilot plant cleaned approximately 970,000 scf of gas over 1,000 hours of operation. The testing showed that the process could achieve the following polished gas concentrations: less than 80 ppbv hydrogen sulfide; less than 1 ppmv (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv of any individual chlorinated hydrocarbon; and 1.5 ppm sulfur dioxide.

  16. Pressure control of phase matching in high-order harmonic generation in hollow fibers filled with an absorbing weakly ionizing gas

    SciTech Connect (OSTI)

    Naumov, A. N.; Zheltikov, A. M.; Fedotov, A. B.; Sidorov-Biryukov, D. A.; Tarasevitch, A. P.; Zhou, Ping; von der Linde, D.

    2001-06-01T23:59:59.000Z

    High-order harmonic generation in a hollow fiber filled with a weakly ionizing gas is theoretically analyzed within the framework of the slowly varying envelope approximation. The gas pressure that corresponds to maximum efficiency of frequency conversion, the absorption coefficient, the phase mismatch owing to gas dispersion, and the enhancement of harmonic-generation efficiency owing to waveguide phase matching are estimated for 27th-harmonic generation in hollow fibers filled with helium, neon, argon, krypton, or xenon. As a result of the ionization-induced self-phase modulation of the pump pulse in a hollow fiber filled with a weakly ionizing gas, the phase mismatch changes within the pump pulse, decreasing the overall efficiency of harmonic generation and making the harmonic-generation efficiency less sensitive to the gas pressure in the hollow fiber. {copyright} 2001 Optical Society of America

  17. ESTIMATION OF RADIOLYTIC GAS GENERATION RATE FOR CYLINDRICAL RADIOACTIVE WASTE PACKAGES - APPLICATION TO SPENT ION EXCHANGE RESIN CONTAINERS

    SciTech Connect (OSTI)

    Husain, A.; Lewis, Brent J.

    2003-02-27T23:59:59.000Z

    Radioactive waste packages containing water and/or organic substances have the potential to radiolytically generate hydrogen and other combustible gases. Typically, the radiolytic gas generation rate is estimated from the energy deposition rate and the radiolytic gas yield. Estimation of the energy deposition rate must take into account the contributions from all radionuclides. While the contributions from non-gamma emitting radionuclides are relatively easy to estimate, an average geometry factor must be computed to determine the contribution from gamma emitters. Hitherto, no satisfactory method existed for estimating the geometry factors for a cylindrical package. In the present study, a formulation was developed taking into account the effect of photon buildup. A prototype code, called PC-CAGE, was developed to numerically solve the integrals involved. Based on the selected dimensions for a cylinder, the specified waste material, the photon energy of interest and a value for either the absorption or attenuation coefficient, the code outputs values for point and average geometry factors. These can then be used to estimate the internal dose rate to the material in the cylinder and hence to calculate the radiolytic gas generation rate. Besides the ability to estimate the rates of radiolytic gas generation, PC-CAGE can also estimate the dose received by the container material. This is based on values for the point geometry factors at the surface of the cylinder. PC-CAGE was used to calculate geometry factors for a number of cylindrical geometries. Estimates for the absorbed dose rate in container material were also obtained. The results for Ontario Power Generation's 3 m3 resin containers indicate that about 80% of the source gamma energy is deposited internally. In general, the fraction of gamma energy deposited internally depends on the dimensions of the cylinder, the material within it and the photon energy; the fraction deposited increases with increasing dimensions of the cylinder and decreases with increasing photon energy.

  18. Life Cycle Greenhouse Gas Emissions of Nuclear Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Warner, E. S.; Heath, G. A.

    2012-04-01T23:59:59.000Z

    A systematic review and harmonization of life cycle assessment (LCA) literature of nuclear electricity generation technologies was performed to determine causes of and, where possible, reduce variability in estimates of life cycle greenhouse gas (GHG) emissions to clarify the state of knowledge and inform decision making. LCA literature indicates that life cycle GHG emissions from nuclear power are a fraction of traditional fossil sources, but the conditions and assumptions under which nuclear power are deployed can have a significant impact on the magnitude of life cycle GHG emissions relative to renewable technologies. Screening 274 references yielded 27 that reported 99 independent estimates of life cycle GHG emissions from light water reactors (LWRs). The published median, interquartile range (IQR), and range for the pool of LWR life cycle GHG emission estimates were 13, 23, and 220 grams of carbon dioxide equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh), respectively. After harmonizing methods to use consistent gross system boundaries and values for several important system parameters, the same statistics were 12, 17, and 110 g CO{sub 2}-eq/kWh, respectively. Harmonization (especially of performance characteristics) clarifies the estimation of central tendency and variability. To explain the remaining variability, several additional, highly influential consequential factors were examined using other methods. These factors included the primary source energy mix, uranium ore grade, and the selected LCA method. For example, a scenario analysis of future global nuclear development examined the effects of a decreasing global uranium market-average ore grade on life cycle GHG emissions. Depending on conditions, median life cycle GHG emissions could be 9 to 110 g CO{sub 2}-eq/kWh by 2050.

  19. A Low-Cost, High-Efficiency Periodic Flow Gas Turbine for Distributed Energy Generation

    SciTech Connect (OSTI)

    Dr. Adam London

    2008-06-20T23:59:59.000Z

    The proposed effort served as a feasibility study for an innovative, low-cost periodic flow gas turbine capable of realizing efficiencies in the 39-48% range.

  20. Meeting the challenges of the new energy industry: The driving forces facing electric power generators and the natural gas industry

    SciTech Connect (OSTI)

    NONE

    1995-12-31T23:59:59.000Z

    The proceedings of the IGT national conference on meeting the challenges of the New Energy Industry: The driving forces facing Electric Power Generators and the Natural Gas Industry are presented. The conference was held June 19-21, 1995 at the Ambassador West Hotel in Downtown Chicago, Illinois. A separate abstract and indexing for each of the 18 papers presented for inclusion in the Energy Science and Technology Database.

  1. Method of Generating Hydrocarbon Reagents from Diesel, Natural Gas and Other Logistical Fuels

    DOE Patents [OSTI]

    Herling, Darrell R (Richland, WA) [Richland, WA; Aardahl, Chris L. (Richland, WA) [Richland, WA; Rozmiarek, Robert T. (Middleton, WI) [Middleton, WI; Rappe, Kenneth G. (Richland, WA) [Richland, WA; Wang, Yong (Richland, WA) [Richland, WA; Holladay, Jamelyn D. (Kennewick, WA) [Kennewick, WA

    2008-10-14T23:59:59.000Z

    The present invention provides a process for producing reagents for a chemical reaction by introducing a fuel containing hydrocarbons into a flash distillation process wherein the fuel is separated into a first component having a lower average molecular weight and a second component having a higher average molecular weight. The first component is then reformed to produce synthesis gas wherein the synthesis gas is reacted catalytically to produce the desire reagent.

  2. Method of generating hydrocarbon reagents from diesel, natural gas and other logistical fuels

    DOE Patents [OSTI]

    Herling, Darrell R. (Richland, WA); Aardahl, Chris L. (Richland, WA); Rozmiarek, Robert T. (Middleton, WI); Rappe, Kenneth G. (Richland, WA); Wang, Yong (Richland, WA); Holladay, Jamelyn D. (Kennewick, WA)

    2010-06-29T23:59:59.000Z

    The present invention provides a process for producing reagents for a chemical reaction by introducing a fuel containing hydrocarbons into a flash distillation process wherein the fuel is separated into a first component having a lower average molecular weight and a second component having a higher average molecular weight. The first component is then reformed to produce synthesis gas wherein the synthesis gas is reacted catalytically to produce the desire reagent.

  3. Comparing Statewide Economic Impacts of New Generation from Wind, Coal, and Natural Gas in Arizona, Colorado, and Michigan: Preprint

    SciTech Connect (OSTI)

    Tegen, S.

    2005-08-01T23:59:59.000Z

    With increasing concerns about energy independence, job outsourcing, and risks of global climate change, it is important for policy makers to understand all impacts from their decisions about energy resources. This paper assesses one aspect of the impacts: direct economic effects. The paper compares impacts to states from equivalent new electrical generation from wind, natural gas, and coal. Economic impacts include materials and labor for construction, operations, maintenance, fuel extraction, and fuel transport, as well as project financing, property tax, and landowner revenues. We examine spending on plant construction during construction years, in addition to all other operational expenditures over a 20-year span. Initial results indicate that adding new wind power can be more economically effective than adding new gas or coal power, and that a higher percentage of dollars spent on coal and gas will leave the state. For this report, we interviewed industry representatives and energy experts, in addition to consulting government documents, models, and existing literature. The methodology for this research can be adapted to other contexts for determining economic effects of new power generation in other states and regions.

  4. Comparing Statewide Economic Impacts of New Generation from Wind, Coal, and Natural Gas in Arizona, Colorado, and Michigan

    SciTech Connect (OSTI)

    Tegen, S.

    2006-05-01T23:59:59.000Z

    With increasing concerns about energy independence, job outsourcing, and risks of global climate change, it is important for policy makers to understand all impacts from their decisions about energy resources. This paper assesses one aspect of the impacts: direct economic effects. The paper compares impacts to states from equivalent new electrical generation from wind, natural gas, and coal. Economic impacts include materials and labor for construction, operations, maintenance, fuel extraction, and fuel transport, as well as project financing, property tax, and landowner revenues. We examine spending on plant construction during construction years, in addition to all other operational expenditures over a 20-year span. Initial results indicate that adding new wind power can be more economically effective than adding new gas or coal power and that a higher percentage of dollars spent on coal and gas will leave the state. For this report, we interviewed industry representatives and energy experts, in addition to consulting government documents, models, and existing literature. The methodology for this research can be adapted to other contexts for determining economic effects of new power generation in other states and regions.

  5. Landfill gas cleanup for carbonate fuel cell power generation. CRADA final report

    SciTech Connect (OSTI)

    Steinfeld, G.; Sanderson, R.

    1998-02-01T23:59:59.000Z

    The overall objective of the work reported here was to evaluate the extent to which conventional contaminant removal processes could be combined to economically reduce contaminant levels to the specifications for carbonate fuel cells. The technical effort was conducted by EPRI, consultant David Thimsen, Kaltec of Minnesota, Energy Research Corporation (ERC) and Interpoll Laboratories. The Electric Power Research Institute (EPRI) made available two test skids originally used to test an ERC 30 kW carbonate fuel cell at the Destec Coal Gasification Plan in Plaquemine, LA. EPRI`s carbonate fuel cell pilot plant was installed at the Anoka County Regional Landfill in Ramsey, Minnesota. Additional gas cleaning equipment was installed to evaluate a potentially inexpensive, multi-stage gas cleaning process to remove sulfur and chlorine in the gas to levels acceptable for long-term, economical carbonate fuel cell operation. The pilot plant cleaned approximately 970,000 scf (27,500 Nm{sup 3}) of gas over 1,000 hours of operation. The testing showed that the process could achieve the following polished gas concentrations. Less than 80 ppbv hydrogen sulfide; less than 1 ppmv (the detection limit) organic sulfur; less than 300 ppbv hydrogen chloride; less than 20--80 ppbv of any individual chlorined hydrocarbon; and 1.5 ppm sulfur dioxide. These were the detection limits of the analytical procedures employed. It is probable that the actual concentrations are below these analytical limits.

  6. Gas generation over plutonium oxides in the 94-1 shelf-life surveillance program.

    SciTech Connect (OSTI)

    Berg, J. M. (John M.); Harradine, D. M. (David M.); Hill, D. D. (Dallas D.); McFarlan, James T.; Padilla, D. D. (Dennis D.); Prenger, F. Coyne; Veirs, D. K. (Douglas Kirk); Worl, L. A. (Laura A.)

    2002-01-01T23:59:59.000Z

    The Department of Energy (DOE) is embarking upon a program to store large quantities of plutonium-bearing materials for up to fifty years. The Los Alamos National Laboratory Shelf Life Project was established to bound the behavior of plutonium-bearing material meeting the DOE 3013 Standard. The shelf life study monitors temperature, pressure and gas composition over oxide materials in a limited number of large-scale 3013 inner containers and in many small-scale containers. For the large-scale study, baseline plutonium oxides, oxides exposed to high-humidity atmospheres, and oxides containing chloride salt impurities are planned. The first large-scale container represents a baseline and contains dry plutonium oxide prepared according to the 3013 Standard. This container has been observed for pressure, temperature and gas compositional changes for less than a year. Results indicate that no detectable changes in pressure and gas composition are observed.

  7. A Path to the Formulation of New Generations of Synthetic Jet Fuel Derived from Natural Gas

    E-Print Network [OSTI]

    Al-Nuaimi, Ibrahim Awni Omar Hassan

    2013-05-20T23:59:59.000Z

    United States n- normal-paraffins iso- iso-paraffins cyclo- cyclo-paraffins Tcf Trillion cubic foot Mta Million tons per annum LNG Liquefied Natural Gas QP Qatar Petroleum FT Fischer-Tropsch GHG?s Greenhouse Gases GC Gas... compositions in jet fuel type Mix Jet fuels mixture V Volumetric composition in jet fuel type. NP normal-paraffins IP iso-paraffins CP cyclo-paraffins Mw Average molecular weight D Average density NP_IP normal- and iso-paraffins mixture...

  8. GETRAN: A generic, modularly structured computer code for simulation of dynamic behavior of aero- and power generation gas turbine engines

    SciTech Connect (OSTI)

    Schobeiri, M.T.; Attia, M.; Lippke, C. (Texas A and M Univ., College Station, TX (United States). Dept. of Mechanical Engineering)

    1994-07-01T23:59:59.000Z

    The design concept, the theoretical background essential for the development of the modularly structured simulation code GETRAN, and several critical simulation cases are presented in this paper. The code being developed under contract with NASA Lewis Research Center is capable of simulating the nonlinear dynamic behavior of single- and multispool core engines, turbofan engines, and power generation gas turbine engines under adverse dynamic operating conditions. The modules implemented into GETRAN correspond to components of existing and new-generation aero- and stationary gas turbine engines with arbitrary configuration and arrangement. For precise simulation of turbine and compressor components, row-by-row diabatic and adiabatic calculation procedures are implemented that account for the specific turbine and compressor cascade, blade geometry, and characteristics. The nonlinear, dynamic behavior of the subject engine is calculated solving a number of systems of partial differential equations, which describe the unsteady behavior of each component individually. To identify each differential equation system unambiguously, special attention is paid to the addressing of each component. The code is capable of executing the simulation procedure at four levels, which increase with the degree of complexity of the system and dynamic event. As representative simulations, four different transient cases with single- and multispool thrust and power generation engines were simulated. These transient cases vary from throttling the exit nozzle area, operation with fuel schedule, rotor speed control, to rotating stall and surge.

  9. Final Report - Gas Generation Testing of Uranium Metal in Simulated K Basin Sludge and in Grouted Sludge Waste Forms

    SciTech Connect (OSTI)

    Delegard, Calvin H.; Schmidt, Andrew J.; Sell, Rachel L.; Sinkov, Sergei I.; Bryan, Samuel A.; Gano, Sue; Thornton, Brenda M.

    2004-08-19T23:59:59.000Z

    The Waste Isolation Pilot Plant (WIPP) is being considered for the disposal of K Basin sludge as RH-TRU. Because the hydrogen gas concentration in the 55-gallon RH-TRU sealed drums to be transported to WIPP is limited by flammability safety, the number of containers and shipments likely will be driven by the rate of hydrogen generated by the uranium metal-water reaction (U + 2 H{sub 2}O {yields} UO{sub 2} + 2 H{sub 2}) in combination with the hydrogen generated from water and organic radiolysis. Gas generation testing was conducted with uranium metal particles of known surface area, in simulated K West (KW) Basin canister sludge and immobilized in candidate grout solidification matrices. This study evaluated potential for Portland cement and magnesium phosphate grouts to inhibit the reaction of water with uranium metal in the sludge and thereby permit higher sludge loading to the disposed waste form. The best of the grouted waste forms decreased the uranium metal-water reaction by a factor of four.

  10. Electrical Power Generation Using Geothermal Fluid Co-produced from Oil & Gas

    Broader source: Energy.gov [DOE]

    Project objectives: To validate and realize the potential for the production of low temperature resource geothermal production on oil & gas sites. Test and document the reliability of this new technology.; Gain a better understanding of operational costs associated with this equipment.

  11. NO-assisted molecular-beam epitaxial growth of nitrogen substituted EuO

    SciTech Connect (OSTI)

    Wicks, R. [Department of Physics and Astronomy, University of British Columbia, Vancouver, British Columbia V6T 1Z1 (Canada); Altendorf, S. G.; Caspers, C.; Kierspel, H.; Sutarto, R. [II. Physikalisches Institut, Universitaet zu Koeln, Zuelpicher Str. 77, 50937 Koeln (Germany); Tjeng, L. H. [II. Physikalisches Institut, Universitaet zu Koeln, Zuelpicher Str. 77, 50937 Koeln (Germany); Max Planck Institute for Chemical Physics of Solids, 01187 Dresden (Germany); Damascelli, A. [Department of Physics and Astronomy, University of British Columbia, Vancouver, British Columbia V6T 1Z1 (Canada); Quantum Matter Institute, University of British Columbia, Vancouver, British Columbia V6T 1Z4 (Canada)

    2012-04-16T23:59:59.000Z

    We have investigated a method for substituting oxygen with nitrogen in EuO thin films, which is based on molecular beam epitaxy distillation with NO gas as the oxidizer. By varying the NO gas pressure, we produce crystalline, epitaxial EuO{sub 1-x}N{sub x} films with good control over the films' nitrogen concentration. In situ x-ray photoemission spectroscopy reveals that nitrogen substitution is connected to the formation Eu{sup 3+}4f{sup 6} and a corresponding decrease in the number of Eu{sup 2+}4f{sup 7}, indicating that nitrogen is being incorporated in its 3{sup -} oxidation state. While small amounts of Eu{sup 3+} in over-oxidized Eu{sub 1-{delta}}O thin films lead to a drastic suppression of the ferromagnetism, the formation of Eu{sup 3+} in EuO{sub 1-x}N{sub x} still allows the ferromagnetic phase to exist with an unaffected T{sub c}, thus providing an ideal model system to study the interplay between the magnetic f{sup 7} (J = 7/2) and the non-magnetic f{sup 6} (J = 0) states close to the Fermi level.

  12. GREENHOUSE GAS EMISSION CONTROL OPTIONS: ASSESSING TRANSPORTATION AND ELECTRICITY GENERATION TECHNOLOGIES AND

    E-Print Network [OSTI]

    Kockelman, Kara M.

    power generation, energy policy, fuel economy ABSTRACT Prioritizing the numerous technology and policy Publications for book titled "Energy Consumption: Impacts of Human Activity, Current and Future Challenges, Environmental and Ecological Effects," August 2013. KEY WORDS: Greenhouse gases, transportation energy, electric

  13. Limited Electricity Generation Supply and Limited Natural Gas Supply Cases (released in AEO2008)

    Reports and Publications (EIA)

    2008-01-01T23:59:59.000Z

    Development of U.S. energy resources and the permitting and construction of large energy facilities have become increasingly difficult over the past 20 years, and they could become even more difficult in the future. Growing public concern about global warming and CO2 emissions also casts doubt on future consumption of fossil fuels -- particularly coal, which releases the largest amount of CO2 per unit of energy produced. Even without regulations to limit greenhouse gas emissions in the United States, the investment community may already be limiting the future use of some energy options. In addition, there is considerable uncertainty about the future availability of, and access to, both domestic and foreign natural gas resources.

  14. Process for generation of hydrogen gas from various feedstocks using thermophilic bacteria

    DOE Patents [OSTI]

    Ooteghem, Suellen Van (Morgantown, WV)

    2005-09-13T23:59:59.000Z

    A method for producing hydrogen gas is provided comprising selecting a bacteria from the Order Thermotogales, subjecting the bacteria to a feedstock and to a suitable growth environment having an oxygen concentration below the oxygen concentration of water in equilibrium with air; and maintaining the environment at a predetermined pH and at a temperature of at least approximately 45.degree. C. for a time sufficient to allow the bacteria to metabolize the feedstock.

  15. VUV generation by adiabatically expanded and excited by a DC electrical discharge Argon gas

    SciTech Connect (OSTI)

    Pipergias, K.; Yasemidis, D.; Reppa, E.; Pentaris, D.; Efthimiopoulos, T. [Laser, Non linear and Quantum Optics Labs, Physics Department University of Patras, Patras, Greece 26500 (Greece); Merlemis, N. [Laser, Non linear and Quantum Optics Labs, Physics Department University of Patras, Patras, Greece 26500 (Greece); TEI of Athens, Phys. Chem. and Mater. Tech. Department, Athens, Greece, 12 210 (Greece); Giannetas, V. [Physics Department, University of Patras, Patras, Greece 26500 (Greece)

    2010-11-10T23:59:59.000Z

    We investigate the emission of Argon (Ar) gas which is adiabatically expanded through a nozzle and excited using a DC electrical discharge. Because of the expansion and the electronic excitation, Ar dimers and clusters are formed, which give radiation in the second (2nd) and in the third (3rd) continua of Ar, centered at about 126 and 254 nm respectively. We particularly focus our study on the 2nd continuum, in order to develop a laser at this wavelength.

  16. Process for Generation of Hydrogen Gas from Various Feedstocks Using Thermophilic Bacteria

    SciTech Connect (OSTI)

    Ooteghem Van, Suellen

    2005-09-13T23:59:59.000Z

    A method for producing hydrogen gas is provided comprising selecting a bacteria from the Order Thermotogales, subjecting the bacteria to a feedstock and to a suitable growth environment having an oxygen concentration below the oxygen concentration of water in equilibrium with air; and maintaining the environment at a predetermined pH and at a temperature of at least approximately 45 degrees C. for a time sufficient to allow the bacteria to metabolize the feedstock.

  17. Sweeney LUBRICATION OF STEAM, GAS AND WATER TURBINES IN POWER GENERATION- A CHEVRONTEXACO EXPERIENCE

    E-Print Network [OSTI]

    Peter James Sweeney

    On 9 October 2001 two US oil companies Chevron and Texaco merged. Their long-term joint venture operation, known as Caltex (formed in 1936 and operating in East and Southern Africa, Middle East, Asia and Australasia), was incorporated into the one global energy company. This global enterprise will be highly competitive across all energy sectors, as the new company brings together a wealth of talents, shared values and a strong commitment to developing vital energy resources around the globe. Worldwide, ChevronTexaco is the third largest publicly traded company in terms of oil and gas reserves, with some 11.8 billion barrels of oil and gas equivalent. It is the fourth largest producer, with daily production of 2.7 million barrels. The company also has 22 refineries and more than 21,000 branded service stations worldwide. This paper will review the fundamentals of lubrication as they apply to the components of turbines. It will then look at three turbine types, steam, gas and water, to address the different needs of lubricating oils and the appropriate specifications for each. The significance of oil testing both for product development and in-service oil monitoring will be reviewed, together with the supporting field experience of ChevronTexaco. The environmental emissions controls on turbines and any impact on the lubricants will be discussed. Finally, the trends in specifications for lubricating oils to address the modern turbines designs will be reviewed. Key Words: geothermal, lubrication, turbines, in-service testing 1.

  18. Apparatus and methods of reheating gas turbine cooling steam and high pressure steam turbine exhaust in a combined cycle power generating system

    DOE Patents [OSTI]

    Tomlinson, Leroy Omar (Niskayuna, NY); Smith, Raub Warfield (Ballston Lake, NY)

    2002-01-01T23:59:59.000Z

    In a combined cycle system having a multi-pressure heat recovery steam generator, a gas turbine and steam turbine, steam for cooling gas turbine components is supplied from the intermediate pressure section of the heat recovery steam generator supplemented by a portion of the steam exhausting from the HP section of the steam turbine, steam from the gas turbine cooling cycle and the exhaust from the HP section of the steam turbine are combined for flow through a reheat section of the HRSG. The reheated steam is supplied to the IP section inlet of the steam turbine. Thus, where gas turbine cooling steam temperature is lower than optimum, a net improvement in performance is achieved by flowing the cooling steam exhausting from the gas turbine and the exhaust steam from the high pressure section of the steam turbine in series through the reheater of the HRSG for applying steam at optimum temperature to the IP section of the steam turbine.

  19. Elevated Temperature Materials for Power Generation and Propulsion The energy industry is designing higher-efficiency land-based turbines for natural gas-fired

    E-Print Network [OSTI]

    Li, Mo

    Elevated Temperature Materials for Power Generation and Propulsion The energy industry is designing higher-efficiency land-based turbines for natural gas-fired power generation systems. The high inlet materials for these aggressive environments. For example, Ni-base superalloys are used to fabricate blades

  20. Danish Energy Authority Poland -Electricity and gas

    E-Print Network [OSTI]

    Danish Energy Authority Poland - Electricity and gas market development study and practical guidelines for using EU Funds Electricity sector analyses December 2004 #12;Danish Energy Authority Poland - Electricity and gas market development study and practical guidelines for using EU Funds Electricity sector

  1. ITER: Japan to assign 20 percent of construction work to EU firms; Proposal for EU official to assume chief executive

    E-Print Network [OSTI]

    Experimental Reactor (ITER). Japan yesterday revealed the details of a proposal to host the project. Tokyo has, Japan bears half price even with construction inside the EU limits of the accessory structures prospect. The experimental device in order ITER generates electricity, reproducing the fusion reaction

  2. Electric Power Generation from Co-Produced Fluids from Oil and Gas Wells

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand JumpConceptual Model,DOEHazel Crest, Illinois:EdinburghEldorado IvanpahGas Wells | Open

  3. Updated greenhouse gas and criteria air pollutant emission factors and their probability distribution functions for electricity generating units

    SciTech Connect (OSTI)

    Cai, H.; Wang, M.; Elgowainy, A.; Han, J. (Energy Systems)

    2012-07-06T23:59:59.000Z

    Greenhouse gas (CO{sub 2}, CH{sub 4} and N{sub 2}O, hereinafter GHG) and criteria air pollutant (CO, NO{sub x}, VOC, PM{sub 10}, PM{sub 2.5} and SO{sub x}, hereinafter CAP) emission factors for various types of power plants burning various fuels with different technologies are important upstream parameters for estimating life-cycle emissions associated with alternative vehicle/fuel systems in the transportation sector, especially electric vehicles. The emission factors are typically expressed in grams of GHG or CAP per kWh of electricity generated by a specific power generation technology. This document describes our approach for updating and expanding GHG and CAP emission factors in the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model developed at Argonne National Laboratory (see Wang 1999 and the GREET website at http://greet.es.anl.gov/main) for various power generation technologies. These GHG and CAP emissions are used to estimate the impact of electricity use by stationary and transportation applications on their fuel-cycle emissions. The electricity generation mixes and the fuel shares attributable to various combustion technologies at the national, regional and state levels are also updated in this document. The energy conversion efficiencies of electric generating units (EGUs) by fuel type and combustion technology are calculated on the basis of the lower heating values of each fuel, to be consistent with the basis used in GREET for transportation fuels. On the basis of the updated GHG and CAP emission factors and energy efficiencies of EGUs, the probability distribution functions (PDFs), which are functions that describe the relative likelihood for the emission factors and energy efficiencies as random variables to take on a given value by the integral of their own probability distributions, are updated using best-fit statistical curves to characterize the uncertainties associated with GHG and CAP emissions in life-cycle modeling with GREET.

  4. Laser generation of gas bubbles: Photoacoustic and photothermal effects recorded in transient grating experiments

    SciTech Connect (OSTI)

    Frez, Clifford; Diebold, Gerald J. [Department of Chemistry, Brown University, Providence, Rhode Island 02912 (United States)

    2008-11-14T23:59:59.000Z

    Absorption of high power laser radiation by colloidal suspensions or solutions containing photoreactive chemicals can result in bubble production. Here, transient grating experiments are reported where picosecond and nanosecond lasers are used to initiate photoinduced processes that lead to bubble formation. Irradiation of colloidal Pt suspensions is found to produce water vapor bubbles that condense back to liquid on a nanosecond time scale. Laser irradiation of Pt suspensions supersaturated with CO{sub 2} liberates dissolved gas to produce bubbles at the sites of the colloidal particles. Laser induced chemical reactions that produce bubbles are found in suspensions of particulate C in water, and in the sensitized decarboxylation of oxalic acid. Theory based on linear acoustics as well as the Rayleigh-Plesset equation is given for description of the bubble motion.

  5. The Next Generation Nuclear Plant/Advanced Gas Reactor Fuel Irradiation Experiments in the Advanced Test Reactor

    SciTech Connect (OSTI)

    S. Blaine Grover

    2009-09-01T23:59:59.000Z

    The United States Department of Energys Next Generation Nuclear Plant (NGNP) Program will be irradiating eight separate low enriched uranium (LEU) tri-isotopic (TRISO) particle fuel (in compact form) experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). The ATR has a long history of irradiation testing in support of reactor development and the INL has been designated as the new United States Department of Energys lead laboratory for nuclear energy development. The ATR is one of the worlds premiere test reactors for performing long term, high flux, and/or large volume irradiation test programs. These irradiations and fuel development are being accomplished to support development of the next generation reactors in the United States, and will be irradiated over the next ten years to demonstrate and qualify new particle fuel for use in high temperature gas reactors. The goals of the irradiation experiments are to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel performance and fission product transport models and codes, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing. The experiments, which will each consist of at least six separate capsules, will be irradiated in an inert sweep gas atmosphere with individual on-line temperature monitoring and control of each capsule. The sweep gas will also have on-line fission product monitoring on its effluent to track performance of the fuel in each individual capsule during irradiation. The first experiment (designated AGR-1) started irradiation in December 2006, and the second experiment (AGR-2) is currently in the design phase. The design of test trains, as well as the support systems and fission product monitoring system that will monitor and control the experiment during irradiation will be discussed. In addition, the purpose and differences between the two experiments will be compared and the irradiation results to date on the first experiment will be presented.

  6. Dissolved gas supersaturation associated with the thermal effluent of an electric generating station and some effects on fishes

    E-Print Network [OSTI]

    Ciesluk, Alexander Frank

    1974-01-01T23:59:59.000Z

    ) of bluegill sunfish, Iargemouth bass, and red shiners exposed to various levels of dissolved gas supersaturation. . 71 15 Occurrence, by location, of external symptoms of gas-bubble disease in bluegill sunfish, la rgemouth bass, and red shiners during...-27 February cage bioassay. 58 15 Mortality and incidence of gas-bubble disease in bluegill sunfish, Iargemouth bass, and red shiners subjected to various levels of dissolved gas supersaturation for 72 hours 70 16-A Gas bubbles within the left eye of a...

  7. The effect of the operation modes of a gas discharge low-pressure amalgam lamp on the intensity of generation of 185 nm UV vacuum radiation

    SciTech Connect (OSTI)

    Vasilyak, L. M., E-mail: vasilyak@ihed.ras.ru [Russian Academy of Sciences, Joint Institute of High Temperatures (Russian Federation); Drozdov, L. A., E-mail: lit@npo.lit.ru; Kostyuchenko, S. V.; Sokolov, D. V. [ZAO LIT (Russian Federation); Kudryavtsev, N. N.; Sobur, D. A., E-mail: soburda@gmail.com [Moscow Institute for Physics and Technology (Russian Federation)

    2011-12-15T23:59:59.000Z

    The effect of the discharge current, mercury vapor pressure, and the inert gas pressure on the intensity and efficiency of the 185 nm line generation are considered. The spectra of the UV radiation (vacuum ultraviolet) transmission by protective coatings from the oxides of rare earth metals and aluminum are investigated.

  8. Eu{sub 3}F{sub 4}S{sub 2}: Synthesis, crystal structure, and magnetic properties of the mixed-valent europium(II,III) fluoride sulfide EuF{sub 2}.(EuFS){sub 2}

    SciTech Connect (OSTI)

    Grossholz, Hagen; Hartenbach, Ingo [Institut fuer Anorganische Chemie, Universitaet Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart (Germany); Kotzyba, Gunter [Institut fuer Anorganische und Analytische Chemie, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Poettgen, Rainer, E-mail: pottgen@uni-muenster.d [Institut fuer Anorganische und Analytische Chemie, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Trill, Henning; Mosel, Bernd D. [Institut fuer Physikalische Chemie, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Schleid, Thomas, E-mail: schleid@iac.uni-stuttgart.d [Institut fuer Anorganische Chemie, Universitaet Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart (Germany)

    2009-11-15T23:59:59.000Z

    Using the method to synthesize rare-earth metal(III) fluoride sulfides MFS (M=Y, La, Ce-Lu), in some cases we were able to obtain mixed-valent compounds such as Yb{sub 3}F{sub 4}S{sub 2} instead. With Eu{sub 3}F{sub 4}S{sub 2} another isotypic representative has now been synthesized. Eu{sub 3}F{sub 4}S{sub 2} (tetragonal, I4/mmm, a=400.34(2), c=1928.17(9) pm, Z=2) is obtained from the reaction of metallic europium, elemental sulfur, and europium trifluoride in a molar ratio of 5:6:4 within seven days at 850 deg. C in silica-jacketed gas-tightly sealed platinum ampoules. The single-phase product consists of black plate-shaped single crystals with a square cross section, which can be obtained from a flux using equimolar amounts of NaCl as fluxing agent. The crystal structure is best described as an intergrowth structure, in which one layer of CaF{sub 2}-type EuF{sub 2} is followed by two layers of PbFCl-type EuFS when sheeted parallel to the (001) plane. Accordingly there are two chemically and crystallographically different europium cations present. One of them (Eu{sup 2+}) is coordinated by eight fluoride anions in a cubic fashion, the other one (Eu{sup 3+}) exhibits a monocapped square antiprismatic coordination sphere with four F{sup -} and five S{sup 2-} anions. Although the structural ordering of the different charged europium cations is plausible, a certain amount of charge delocalization with some polaron activity has to take place, which is suggested by the black color of the title compound. Temperature dependent magnetic susceptibility measurements of Eu{sub 3}F{sub 4}S{sub 2} show Curie-Weiss behavior with an experimental magnetic moment of 8.19(5) mu{sub B} per formula unit and a paramagnetic Curie temperature of 0.3(2) K. No magnetic ordering is observed down to 4.2 K. In accordance with an ionic formula splitting like (Eu{sup II})(Eu{sup III}){sub 2}F{sub 4}S{sub 2} only one third of the europium centers in Eu{sub 3}F{sub 4}S{sub 2} carry permanent magnetic moments. {sup 151}Eu-Moessbauer spectroscopic experiments at 4.2 K show one signal at an isomer shift of -12.4(1) mm/s and a second one at 0.42(4) mm/s. These signals occur in a ratio of 1:2 and correspond to Eu{sup 2+} and Eu{sup 3+}, respectively. The spectra at 78 and 298 K are similar, thus no change in the Eu{sup 2+}/Eu{sup 3+} fraction can be detected. - Graphical abstract: Crystal structure and {sup 151}Eu-Moessbauer spectra of mixed-valent Eu{sub 3}F{sub 4}S{sub 2}.

  9. Utilizing the heat content of gas-to-liquids by-product streams for commercial power generation

    E-Print Network [OSTI]

    Adegoke, Adesola Ayodeji

    2006-10-30T23:59:59.000Z

    The Gas-to-liquids (GTL) processes produce a large fraction of by-products whose disposal or handling ordinarily becomes a cost rather than benefit. As an alternative strategy to market stranded gas reserves, GTL...

  10. Dissolved gas supersaturation associated with the thermal effluent of an electric generating station and some effects on fishes

    E-Print Network [OSTI]

    Ciesluk, Alexander Frank

    1974-01-01T23:59:59.000Z

    saturations of total dissolved gas were determined with a Weiss Gas Saturometer and ranged from 100. 5 to 115. 04 in the discharge water. Saturation levels were directly related to the power plant AT and the gas content of the intake water. Percent... hours. Red shiners were more susceptible to gas supersaturation than bluegiils or bass. ACKNOWLEDGMENTS I would like to thank the Texas Utilities System including Dallas Power E Light Company, Texas Electric Service Company, and Texas Power C Light...

  11. Comparative Life-cycle Air Emissions of Coal, Domestic Natural Gas, LNG, and SNG for Electricity Generation

    E-Print Network [OSTI]

    Jaramillo, Paulina

    1 Comparative Life-cycle Air Emissions of Coal, Domestic Natural Gas, LNG, and SNG for Electricity from the LNG life-cycle. Notice that local distribution of natural gas falls outside our analysis boundary. Figure 1S: Domestic Natural Gas Life-cycle. Figure 2S: LNG Life-cycle. Processing Transmission

  12. A summary of volatile impurity measurements and gas generation studies on MISSTD-1, a high-purity plutonium oxide produced by low-temperature calcination of plutonium oxalate

    SciTech Connect (OSTI)

    Berg, John M. [Los Alamos National Laboratory; Narlesky, Joshua E. [Los Alamos National Laboratory; Veirs, Douglas K. [Los Alamos National Laboratory

    2012-06-08T23:59:59.000Z

    Plutonium dioxide of high specific surface area was subjected to long-term tests of gas generation in sealed containers. The material preparation and the storage conditions were outside the bounds of acceptable parameters defined by DOE-STD-3013-2012 in that the material was stabilized to a lower temperature than required and had higher moisture content than allowed. The data provide useful information for better defining the bounding conditions for safe storage. Net increases in internal pressure and transient increases in H{sub 2} and O{sub 2} were observed, but were well within the bounds of gas compositions previously shown to not threaten integrity of 3013 containers.

  13. De-Carbonizing California and the EU

    E-Print Network [OSTI]

    Berck, Peter; Brannlund, Runar

    2008-01-01T23:59:59.000Z

    the EU has set a biofuels transport target for each country,for 10% of transport fuels to be biofuels. This is about the

  14. 4/6/2014 EU Drafts Hydraulic Fracturing Guidelines to Mitigate Conflicting Laws | The DailyEnergyReport http://www.dailyenergyreport.com/eu-drafts-hydraulic-fracturing-guidelines-to-mitigate-conflicting-laws-2/ 1/7

    E-Print Network [OSTI]

    Chiao, Jung-Chih

    /eu-drafts-hydraulic-fracturing-guidelines-to-mitigate-conflicting-laws-2/ 1/7 Tweet 1 April 6, 2014 Search for a topic... GO Home Efficiency Renewables Buildings because of its durable nickel allow material and smart aerodynamic design. Post to Facebook Add to Linked The Maryland Electricity Market Americans Hop on Trains as Gas Prices Hit the Roof 1 #12;4/6/2014 EU Drafts

  15. US-EU-Japan Working Group on Critical Materials

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33Frequently20,000 Russian Nuclear Warheads into Fuel forShale_Gas.pdfUS-EU-Japan Working Group on

  16. Photoluminescence properties of Tb-Eu-Mn-codoped fluoroborate glasses under ?-irradiation

    SciTech Connect (OSTI)

    Hari Babu, B.; Ravi Kanth Kumar, V. V. [Department of Physics, Pondicherry University, R. V. Nagar, Kalapet, Puducherry 605014 (India)] [Department of Physics, Pondicherry University, R. V. Nagar, Kalapet, Puducherry 605014 (India)

    2013-09-28T23:59:59.000Z

    We report here an energy transfer from Tb{sup 3+} to Eu{sup 3+}, Mn{sup 2+} and Eu{sup 2+} to Tb{sup 3+} and Mn{sup 2+} for an un-irradiated and ?-irradiated B{sub 2}O{sub 3}-Al{sub 2}O{sub 3}-Na{sub 2}O-SrF{sub 2} glass samples, respectively. The blue emission from Eu{sup 2+} ions as well as green and red emission from Tb{sup 3+}, Eu{sup 3+}, and Mn{sup 2+} ions will contribute to the generation of white light while excited at 339 nm using a xenon lamp. Furthermore, the chromaticity color coordinates, correlated color temperature, and quantum efficiency parameters are calculated for all the glass samples, and their relative variations with respect to ?-irradiation dose are presented.

  17. Supported by GreenNet-EU27

    E-Print Network [OSTI]

    Figueiredo Integration costs of wind due to changed system operation and investment decisions in GermanySupported by GreenNet-EU27 EIE/04/049/S07.38561 GreenNet-EU27 GUIDING A LEAST COST GRID INTEGRATION cost and grid extension cost caused by intermittent RES-E grid integration Derk Jan Swider (Ed

  18. Advanced natural gas-fired turbine system utilizing thermochemical recuperation and/or partial oxidation for electricity generation, greenfield and repowering applications

    SciTech Connect (OSTI)

    NONE

    1997-03-01T23:59:59.000Z

    The performance, economics and technical feasibility of heavy duty combustion turbine power systems incorporating two advanced power generation schemes have been estimated to assess the potential merits of these advanced technologies. The advanced technologies considered were: Thermochemical Recuperation (TCR), and Partial Oxidation (PO). The performance and economics of these advanced cycles are compared to conventional combustion turbine Simple-Cycles and Combined-Cycles. The objectives of the Westinghouse evaluation were to: (1) simulate TCR and PO power plant cycles, (2) evaluate TCR and PO cycle options and assess their performance potential and cost potential compared to conventional technologies, (3) identify the required modifications to the combustion turbine and the conventional power cycle components to utilize the TCR and PO technologies, (4) assess the technical feasibility of the TCR and PO cycles, (5) identify what development activities are required to bring the TCR and PO technologies to commercial readiness. Both advanced technologies involve the preprocessing of the turbine fuel to generate a low-thermal-value fuel gas, and neither technology requires advances in basic turbine technologies (e.g., combustion, airfoil materials, airfoil cooling). In TCR, the turbine fuel is reformed to a hydrogen-rich fuel gas by catalytic contact with steam, or with flue gas (steam and carbon dioxide), and the turbine exhaust gas provides the indirect energy required to conduct the endothermic reforming reactions. This reforming process improves the recuperative energy recovery of the cycle, and the delivery of the low-thermal-value fuel gas to the combustors potentially reduces the NO{sub x} emission and increases the combustor stability.

  19. Utilizing the heat content of gas-to-liquids by-product streams for commercial power generation

    E-Print Network [OSTI]

    Adegoke, Adesola Ayodeji

    2006-10-30T23:59:59.000Z

    &PIfortheLNG,GTL,andIntegratedGTLPower- GenerationProjects?????????????????? 41 A1 OverviewofGTLProcessDesignedwithAspenPlus...???? 51 1 CHAPTERI INTRODUCTION 1.1 Background Naturalgasisaclean,versatileandthereforedesirablesourceoffuel.Astrongfactorthat defines..., usingtheheatcontentofthesteamstreamand/orthetail-gasstream. TheIntegratedGTLPower-Generationprocesswasmodeledusingacombination Aspen Plus, for the GTL process and Steam System Assessment Tool (DOE), for the power generation. The design of the integrated GTL Power-generation process...

  20. Proposal for the Award of a Contract for the Supply and Installation of a gas Turbine for Combined Generation of Electricity and Heat in the Heating Plant on the Meyrin Site

    E-Print Network [OSTI]

    1994-01-01T23:59:59.000Z

    Proposal for the Award of a Contract for the Supply and Installation of a gas Turbine for Combined Generation of Electricity and Heat in the Heating Plant on the Meyrin Site

  1. Conceptual design and system analysis of a poly-generation system for power and olefin production from natural gas

    E-Print Network [OSTI]

    Huang, Yinlun

    -production system based on coal and natural gas for the production of electric- ity and Dimethyl ether (DME) and electricity being more thermodynamically efficient and economically viable than single purpose power resources and environmental considerations. In some senses, energy shortages and environmental pollution

  2. Discovery of the $^{151}$Eu $\\alpha$ decay

    E-Print Network [OSTI]

    Casali, N; Orio, F; Pattavina, L; Beeman, J W; Bellini, F; Cardani, L; Dafinei, I; Di Domizio, S; Di Vacri, M L; Gironi, L; Kosmyna, M B; Nazarenko, B P; Nisi, S; Pessina, G; Piperno, G; Pirro, S; Rusconi, C; Shekhovtsov, A N; Tomei, C; Vignati, M

    2013-01-01T23:59:59.000Z

    We report on the observation of the $^{151}$Eu $\\alpha$ decay to the ground state of $^{147}$Pm. We measured a half-life of T_{1/2}=(4.62$\\pm$0.95(stat.)$\\pm$0.68(syst.))$\\times 10^{18}$ y and a Q-value of 1948.9$\\pm$6.9 keV, using a 6.15 g Li$_6$Eu(BO$_3$)$_3$ crystal operated as scintillating bolometer.

  3. Generation and characterization of plasma channels in gas puff targets using soft X-ray radiography technique

    SciTech Connect (OSTI)

    Wachulak, P. W., E-mail: wachulak@gmail.com; Bartnik, A.; Jarocki, R.; Fok, T.; W?grzy?ski, ?.; Kostecki, J.; Szczurek, M.; Jabczy?ski, J.; Fiedorowicz, H. [Institute of Optoelectronics, Military University of Technology, ul. gen. S. Kaliskiego 2, 00-908 Warsaw (Poland)

    2014-10-15T23:59:59.000Z

    We present our recent results of a formation and characterization of plasma channels in elongated krypton and xenon gas puff targets. The study of their formation and temporal expansion was carried out using a combination of a soft X-ray radiography (shadowgraphy) and pinhole camera imaging. Two high-energy short laser pulses were used to produce the channels. When a pumping laser pulse was shaped into a line focus, using cylindrical and spherical lenses, the channels were not produced because much smaller energy density was deposited in the gas puff target. However, when a point focus was obtained, using just a spherical lens, the plasma channels appeared. The channels were up to 9?mm in length, had a quite uniform density profile, and expanded in time with velocities of about 2?cm/?s.

  4. EU Gives Japan Until End-June to Accept Nuclear-Project Offer

    E-Print Network [OSTI]

    must begin this year. The EU made the partnership offer in November to break a deadlock in which China of negotiations.'' ITER, which would generate ``clean'' energy by fusing together light atoms such as hydrogen reach an agreement. ``Only on a political level is it possible to get a solution quickly,'' he said

  5. Mechanism and computational model for Lyman-{alpha}-radiation generation by high-intensity-laser four-wave mixing in Kr-Ar gas

    SciTech Connect (OSTI)

    Louchev, Oleg A.; Saito, Norihito; Wada, Satoshi [Advanced Science Institute, RIKEN, 2-1 Hirosawa, Wako, Saitama, 351-0198 (Japan); Bakule, Pavel [STFC, ISIS Facility, Rutherford Appleton Laboratory, Chilton, Oxfordshire OX11 0QX (United Kingdom); Yokoyama, Koji [Advanced Science Institute, RIKEN, 2-1 Hirosawa, Wako, Saitama, 351-0198 (Japan); Advanced Meson Science Laboratory, RIKEN Nishina Center, RIKEN, Wako, Saitama 351-0198 (Japan); Ishida, Katsuhiko; Iwasaki, Masahiko [Advanced Meson Science Laboratory, RIKEN Nishina Center, RIKEN, Wako, Saitama 351-0198 (Japan)

    2011-09-15T23:59:59.000Z

    We present a theoretical model combined with a computational study of a laser four-wave mixing process under optical discharge in which the non-steady-state four-wave amplitude equations are integrated with the kinetic equations of initial optical discharge and electron avalanche ionization in Kr-Ar gas. The model is validated by earlier experimental data showing strong inhibition of the generation of pulsed, tunable Lyman-{alpha} (Ly-{alpha}) radiation when using sum-difference frequency mixing of 212.6 nm and tunable infrared radiation (820-850 nm). The rigorous computational approach to the problem reveals the possibility and mechanism of strong auto-oscillations in sum-difference resonant Ly-{alpha} generation due to the combined effect of (i) 212.6-nm (2+1)-photon ionization producing initial electrons, followed by (ii) the electron avalanche dominated by 843-nm radiation, and (iii) the final breakdown of the phase matching condition. The model shows that the final efficiency of Ly-{alpha} radiation generation can achieve a value of {approx}5x10{sup -4} which is restricted by the total combined absorption of the fundamental and generated radiation.

  6. Facebook and its EU users Applicability of the EU data protection law

    E-Print Network [OSTI]

    Boyer, Edmond

    Facebook and its EU users Applicability of the EU data protection law to US based SNS* Aleksandra (SNS). The analysis will be conducted on the example of Facebook, which is one of the most popular SNS. The goal of the paper is to examine whether European users of Facebook can rely on their national data

  7. Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high temperature furnace (HITAF). Volume 1, Final report

    SciTech Connect (OSTI)

    NONE

    1996-02-01T23:59:59.000Z

    A major objective of the coal-fired high performance power systems (HIPPS) program is to achieve significant increases in the thermodynamic efficiency of coal use for electric power generation. Through increased efficiency, all airborne emissions can be decreased, including emissions of carbon dioxide. High Performance power systems as defined for this program are coal-fired, high efficiency systems where the combustion products from coal do not contact the gas turbine. Typically, this type of a system will involve some indirect heating of gas turbine inlet air and then topping combustion with a cleaner fuel. The topping combustion fuel can be natural gas or another relatively clean fuel. Fuel gas derived from coal is an acceptable fuel for the topping combustion. The ultimate goal for HIPPS is to, have a system that has 95 percent of its heat input from coal. Interim systems that have at least 65 percent heat input from coal are acceptable, but these systems are required to have a clear development path to a system that is 95 percent coal-fired. A three phase program has been planned for the development of HIPPS. Phase 1, reported herein, includes the development of a conceptual design for a commercial plant. Technical and economic feasibility have been analysed for this plant. Preliminary R&D on some aspects of the system were also done in Phase 1, and a Research, Development and Test plan was developed for Phase 2. Work in Phase 2 include s the testing and analysis that is required to develop the technology base for a prototype plant. This work includes pilot plant testing at a scale of around 50 MMBtu/hr heat input. The culmination of the Phase 2 effort will be a site-specific design and test plan for a prototype plant. Phase 3 is the construction and testing of this plant.

  8. Regulations For Gas Companies (Tennessee)

    Broader source: Energy.gov [DOE]

    The Regulations for Gas Companies, implemented by the Tennessee Regulatory Authority (Authority) outline the standards for metering, distribution and electricity generation for utilities using gas....

  9. Social Actors in the Implementation of EU Agri-Environmental Policy

    E-Print Network [OSTI]

    Moyano, Eduardo

    2005-01-01T23:59:59.000Z

    of EU Agri- Environmental Policy Eduardo Moyano Institute ofof EU Agri- Environmental Policy Eduardo Moyano and Fernandoof EU Agri-Environmental Policy. Unfortunately, neither

  10. Hetero-epitaxial EuO interfaces studied by analytic electron microscopy

    SciTech Connect (OSTI)

    Mundy, Julia A. [School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853 (United States); Hodash, Daniel; Melville, Alexander; Held, Rainer [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Mairoser, Thomas; Schmehl, Andreas [Zentrum fr Elektronische Korrelationen und Magnetismus, Universitt Augsburg, Universittsstrae 1, D-86159 Augsburg (Germany); Muller, David A.; Kourkoutis, Lena F. [School of Applied and Engineering Physics, Cornell University, Ithaca, New York 14853 (United States); Kavli Institute at Cornell for Nanoscale Science, Ithaca, New York 14853 (United States); Schlom, Darrell G. [Department of Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Kavli Institute at Cornell for Nanoscale Science, Ithaca, New York 14853 (United States)

    2014-03-03T23:59:59.000Z

    With nearly complete spin polarization, the ferromagnetic semiconductor europium monoxide could enable next-generation spintronic devices by providing efficient ohmic spin injection into silicon. Spin injection is greatly affected by the quality of the interface between the injector and silicon. Here, we use atomic-resolution scanning transmission electron microscopy in conjunction with electron energy loss spectroscopy to directly image and chemically characterize a series of EuO|Si and EuO|YAlO{sub 3} interfaces fabricated using different growth conditions. We identify the presence of europium silicides and regions of disorder at the EuO|Si interfaces, imperfections that could significantly reduce spin injection efficiencies via spin-flip scattering.

  11. Optically active centers in Eu implanted, Eu in situ doped GaN, and Eu doped GaN quantum dots

    SciTech Connect (OSTI)

    Bodiou, L.; Braud, A.; Doualan, J.-L.; Moncorge, R. [Centre de Recherche sur les Ions, les Materiaux et la Photonique (CIMAP), CNRS-CEA-ENSICAEN, Universite de Caen, UMR 6252, 14050 Caen (France); Park, J. H.; Munasinghe, C.; Steckl, A. J. [University of Cincinnati, Cincinnati, Ohio 45221-0030 (United States); Lorenz, K.; Alves, E. [Instituto Tecnologico e Nuclear, Estrada Nacional 10, PT-2685-953 Sacavem (Portugal); Daudin, B. [INAC SP2M/PSC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 9 (France)

    2009-02-15T23:59:59.000Z

    A comparison is presented between Eu implanted and Eu in situ doped GaN thin films showing that two predominant Eu sites are optically active around 620 nm in both types of samples with below and above bandgap excitation. One of these sites, identified as a Ga substitutional site, is common to both types of Eu doped GaN samples despite the difference in the GaN film growth method and in the doping technique. High-resolution photoluminescence (PL) spectra under resonant excitation reveal that in all samples these two host-sensitized sites are in small amount compared to the majority of Eu ions which occupy isolated Ga substitutional sites and thus cannot be excited through the GaN host. The relative concentrations of the two predominant host-sensitized Eu sites are strongly affected by the annealing temperature for Eu implanted samples and by the group III element time opening in the molecular beam epitaxy growth. Red luminescence decay characteristics for the two Eu sites reveal different excitation paths. PL dynamics under above bandgap excitation indicate that Eu ions occupying a Ga substitutional site are either excited directly into the {sup 5}D{sub 0} level or into higher excited levels such as {sup 5}D{sub 1}, while Eu ions sitting in the other site are only directly excited into the {sup 5}D{sub 0} level. These differences are discussed in terms of the spectral overlap between the emission band of a nearby bound exciton and the absorption bands of Eu ions. The study of Eu doped GaN quantum dots reveals the existence of only one type of Eu site under above bandgap excitation, with Eu PL dynamics features similar to Eu ions in Ga substitutional sites.

  12. Life Cycle Greenhouse Gas Emissions of Trough and Tower Concentrating Solar Power Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Burkhardt, J. J.; Heath, G.; Cohen, E.

    2012-04-01T23:59:59.000Z

    In reviewing life cycle assessment (LCA) literature of utility-scale concentrating solar power (CSP) systems, this analysis focuses on reducing variability and clarifying the central tendency of published estimates of life cycle greenhouse gas (GHG) emissions through a meta-analytical process called harmonization. From 125 references reviewed, 10 produced 36 independent GHG emissions estimates passing screens for quality and relevance: 19 for parabolic trough (trough) technology and 17 for power tower (tower) technology. The interquartile range (IQR) of published estimates for troughs and towers were 83 and 20 grams of carbon dioxide equivalent per kilowatt-hour (g CO2-eq/kWh),1 respectively; median estimates were 26 and 38 g CO2-eq/kWh for trough and tower, respectively. Two levels of harmonization were applied. Light harmonization reduced variability in published estimates by using consistent values for key parameters pertaining to plant design and performance. The IQR and median were reduced by 87% and 17%, respectively, for troughs. For towers, the IQR and median decreased by 33% and 38%, respectively. Next, five trough LCAs reporting detailed life cycle inventories were identified. The variability and central tendency of their estimates are reduced by 91% and 81%, respectively, after light harmonization. By harmonizing these five estimates to consistent values for global warming intensities of materials and expanding system boundaries to consistently include electricity and auxiliary natural gas combustion, variability is reduced by an additional 32% while central tendency increases by 8%. These harmonized values provide useful starting points for policy makers in evaluating life cycle GHG emissions from CSP projects without the requirement to conduct a full LCA for each new project.

  13. Role of Bioenergy in the Kyoto Protocol, in the EU-ETS and in future Climate Agreements

    E-Print Network [OSTI]

    of bioenergy use through: Internal emission reductions within the Greenhouse Gas capped sectors Offsetting/CDM CDM project pipeline: > 1000 projects of which: Registered projects: 334 Expected CERs (from RISOE Distribution of projects Bioenergy #12;The EU-ETS and biomass (1) In January 2005 the European

  14. Universitt Wien European Studies Vienna Romania's Way into the EU

    E-Print Network [OSTI]

    Müller, Ralf R.

    1 Universität Wien European Studies Vienna Romania's Way into the EU Author: Liana Müller Supervisor: Prof. Dr. Peter Fischer Index terms Romania, European Union, Enlargement, Accession, Acquis............................................................................. 8 3 EU ­ Romania relations

  15. act infringes eu: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Main Mall Vancouver, B.C. Canada Pauly, Daniel 44 This study explores how the EU Emissions Trading System (EU ETS) actually works on the ground affecting corporate climate...

  16. Energy Department Partners with EU on Electric Vehicle and Smart...

    Office of Environmental Management (EM)

    Partners with EU on Electric Vehicle and Smart Grid Coordination Energy Department Partners with EU on Electric Vehicle and Smart Grid Coordination July 19, 2013 - 5:17pm Addthis...

  17. ag cu eu: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  18. aquilo mas eu: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alkaline fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  19. augu eu degvielu: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fusion process is used from waste phosphors. 1. Introduction The recycling of rare earths is of importance for helping for recycling Eu from BaMgAl10O17:Eu2+ (BMA)...

  20. Edinburgh Research Explorer The Structure of Eu-III

    E-Print Network [OSTI]

    Millar, Andrew J.

    ]. Very recently, Eu has been found to be superconducting at a pressure of approximately 80 GPa, with Tc

  1. Using Backup Generators: Choosing the Right Backup Generator...

    Office of Environmental Management (EM)

    Choose the generator's fuel source-Backup generators are typically powered by either diesel fuel or natural gas, and both have associated advantages and disadvantages. Speak with...

  2. Japan, EU reach basic agreement over ITER The Yomiuri Shimbun

    E-Print Network [OSTI]

    Japan, EU reach basic agreement over ITER The Yomiuri Shimbun The government and the European Union to the unsuccessful candidate country. Japan and France, the EU's candidate, have been bidding to host the facility bidder's country. The ITER project participants--Japan, China, the EU, Russia, South Korea and the United

  3. POWER-GEN '91 conference papers: Volume 7 (Non-utility power generation) and Volume 8 (New power plants - Gas and liquid fuels/combustion turbines). [Independent Power Production

    SciTech Connect (OSTI)

    Not Available

    1991-01-01T23:59:59.000Z

    This is book 4 of papers presented at the Fourth International Power Generation Exhibition and Conference on December 4-6, 1991. The book contains Volume 7, Non-Utility Power Generation and Volume 8, New Power Plants - Gas and Liquid Fuels/Combustion Turbines. The topics of the papers include PUHCA changes and transmission access, financing and economics of independent power projects, case histories, combustion turbine based technologies, coal gasification, and combined cycle.

  4. Mitigation of Hydrogen Gas Generation from the Reaction of Uranium Metal with Water in K Basin Sludge and Sludge Waste Forms

    SciTech Connect (OSTI)

    Sinkov, Sergey I.; Delegard, Calvin H.; Schmidt, Andrew J.

    2011-06-08T23:59:59.000Z

    Prior laboratory testing identified sodium nitrate and nitrite to be the most promising agents to minimize hydrogen generation from uranium metal aqueous corrosion in Hanford Site K Basin sludge. Of the two, nitrate was determined to be better because of higher chemical capacity, lower toxicity, more reliable efficacy, and fewer side reactions than nitrite. The present lab tests were run to determine if nitrates beneficial effects to lower H2 generation in simulated and genuine sludge continued for simulated sludge mixed with agents to immobilize water to help meet the Waste Isolation Pilot Plant (WIPP) waste acceptance drainable liquid criterion. Tests were run at ~60C, 80C, and 95C using near spherical high-purity uranium metal beads and simulated sludge to emulate uranium-rich KW containerized sludge currently residing in engineered containers KW-210 and KW-220. Immobilization agents tested were Portland cement (PC), a commercial blend of PC with sepiolite clay (Aquaset II H), granulated sepiolite clay (Aquaset II G), and sepiolite clay powder (Aquaset II). In all cases except tests with Aquaset II G, the simulated sludge was mixed intimately with the immobilization agent before testing commenced. For the granulated Aquaset II G clay was added to the top of the settled sludge/solution mixture according to manufacturer application directions. The gas volumes and compositions, uranium metal corrosion mass losses, and nitrite, ammonia, and hydroxide concentrations in the interstitial solutions were measured. Uranium metal corrosion rates were compared with rates forecast from the known uranium metal anoxic water corrosion rate law. The ratios of the forecast to the observed rates were calculated to find the corrosion rate attenuation factors. Hydrogen quantities also were measured and compared with quantities expected based on non-attenuated H2 generation at the full forecast anoxic corrosion rate to arrive at H2 attenuation factors. The uranium metal corrosion rates in water alone and in simulated sludge were near or slightly below the metal-in-water rate while nitrate-free sludge/Aquaset II decreased rates by about a factor of 3. Addition of 1 M nitrate to simulated sludge decreased the corrosion rate by a factor of ~5 while 1 M nitrate in sludge/Aquaset II mixtures decreased the corrosion rate by ~2.5 compared with the nitrate-free analogues. Mixtures of simulated sludge with Aquaset II treated with 1 M nitrate had uranium corrosion rates about a factor of 8 to 10 lower than the water-only rate law. Nitrate was found to provide substantial hydrogen mitigation for immobilized simulant sludge waste forms containing Aquaset II or Aquaset II G clay. Hydrogen attenuation factors of 1000 or greater were determined at 60C for sludge-clay mixtures at 1 M nitrate. Hydrogen mitigation for tests with PC and Aquaset II H (which contains PC) were inconclusive because of suspected failure to overcome induction times and fully enter into anoxic corrosion. Lessening of hydrogen attenuation at ~80C and ~95C for simulated sludge and Aquaset II was observed with attenuation factors around 100 to 200 at 1 M nitrate. Valuable additional information has been obtained on the ability of nitrate to attenuate hydrogen gas generation from solution, simulant K Basin sludge, and simulant sludge with immobilization agents. Details on characteristics of the associated reactions were also obtained. The present testing confirms prior work which indicates that nitrate is an effective agent to attenuate hydrogen from uranium metal corrosion in water and simulated K Basin sludge to show that it is also effective in potential candidate solidified K Basin waste forms for WIPP disposal. The hydrogen mitigation afforded by nitrate appears to be sufficient to meet the hydrogen generation limits for shipping various sludge waste streams based on uranium metal concentrations and assumed waste form loadings.

  5. Induced spin-polarization of EuS at room temperature in Ni/EuS multilayers

    SciTech Connect (OSTI)

    Poulopoulos, P., E-mail: poulop@upatras.gr [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Materials Science Department, University of Patras, 26504 Patras (Greece); Goschew, A.; Straub, A.; Fumagalli, P. [Institut fr Experimentalphysik, Freie Universitt Berlin, Arnimallee 14, D-14195 Berlin-Dahlem (Germany); Kapaklis, V.; Wolff, M. [Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden); Delimitis, A. [Chemical Process and Energy Resources Institute (CPERI), Centre for Research and Technology Hellas (CERTH), 57001 Thermi, Thessaloniki (Greece); Wilhelm, F.; Rogalev, A. [European Synchrotron Radiation Facility (ESRF), B.P.220, 38043 Grenoble (France); Pappas, S. D. [Laboratory of High-Tech Materials, School of Engineering, University of Patras, 26504 Patras (Greece); Department of Physics and Astronomy, Uppsala University, Box 516, SE-751 20 Uppsala (Sweden)

    2014-03-17T23:59:59.000Z

    Ni/EuS multilayers with excellent multilayer sequencing are deposited via e-beam evaporation on the native oxide of Si(100) wafers at 4??10{sup ?9} millibars. The samples have very small surface and interface roughness and show sharp interfaces. Ni layers are nanocrystalline 48?nm thick and EuS layers are 24?nm thick and are either amorphous or nanocrystalline. Unlike for Co/EuS multilayers, all Eu ions are in divalent (ferromagnetic) state. We show a direct antiferromagnetic coupling between EuS and Ni layers. At room temperature, the EuS layers are spin-polarized due to the proximity of Ni. Therefore, Ni/EuS is a candidate for room-temperature spintronics applications.

  6. Distributed Generation Investment by a Microgrid under Uncertainty

    E-Print Network [OSTI]

    Siddiqui, Afzal

    2008-01-01T23:59:59.000Z

    Cost of Natural Gas Generation, p Figure 6. Normalised NetCost of Natural Gas Generation, p Figure 7. Wait InvestCost of Natural Gas Generation (US$/kWh e ), C Figure 8.

  7. EU,EU, EnergyEnergy, and Global, and Global ClimateClimate ChangeChange Kirsten Halsns

    E-Print Network [OSTI]

    of CO2 emissions from developing countries #12;#12;#12;#12;#12;IPCC Potential emission reductions from CO2eq).. #12;IPCC Potential emission reductions from additional CCS in new coal and gas plants at CO2 Fossil fuel share of electricity generation without CCS drops toFossil fuel share

  8. Evidence of Eu{sup 2+} 4f electrons in the valence band spectra of EuTiO{sub 3} and EuZrO{sub 3}

    SciTech Connect (OSTI)

    Kolodiazhnyi, T. [National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Valant, M. [Materials Research Laboratory, University of Nova Gorica, Vipavska 13, 5000 Nova Gorica (Slovenia); Williams, J. R. [International Center for Young Scientists (ICYS), MANA, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Bugnet, M.; Botton, G. A. [Department of Materials Science and Engineering, McMaster University, Hamilton, Ontario L8S 4L7 (Canada); Ohashi, N. [International Center for Materials Nanoarchitectonics, MANA, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Sakka, Y. [National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)

    2012-10-15T23:59:59.000Z

    We report on optical band gap and valence electronic structure of two Eu{sup 2+}-based perovskites, EuTiO{sub 3} and EuZrO{sub 3} as revealed by diffuse optical scattering, electron energy loss spectroscopy, and valence-band x-ray photoelectron spectroscopy. The data show good agreement with the first-principles studies in which the top of the valence band structure is formed by the narrow Eu 4f{sup 7} electron band. The O 2p band shows the features similar to those of the Ba(Sr)TiO{sub 3} perovskites except that it is shifted to higher binding energies. Appearance of the Eu{sup 2+} 4f{sup 7} band is a reason for narrowing of the optical band gap in the title compounds as compared to their Sr-based analogues.

  9. Optical properties of Eu{sup 2+}/Eu{sup 3+} mixed valence, silicon nitride based materials

    SciTech Connect (OSTI)

    Kate, Otmar M. ten, E-mail: o.m.tenkate@tudelft.nl [Chemical Engineering and Chemistry, Eindhoven University of Technology, Den Dolech 2, 5600 MB Eindhoven (Netherlands); Fundamental Aspects of Materials and Energy, Delft University of Technology, Mekelweg 15, 2629 JB Delft (Netherlands); Vranken, Thomas [Chemical Engineering and Chemistry, Eindhoven University of Technology, Den Dolech 2, 5600 MB Eindhoven (Netherlands); Kolk, Erik van der [Fundamental Aspects of Materials and Energy, Delft University of Technology, Mekelweg 15, 2629 JB Delft (Netherlands); Jansen, Antonius P.J.; Hintzen, Hubertus T. [Chemical Engineering and Chemistry, Eindhoven University of Technology, Den Dolech 2, 5600 MB Eindhoven (Netherlands)

    2014-05-01T23:59:59.000Z

    Eu{sub 2}SiN{sub 3}, a mixed valence europium nitridosilicate, has been prepared via solid-state reaction synthesis and its oxidation behavior and optical properties have been determined. Furthermore, the stability of several isostructural compounds of the type M{sup 2+}L{sup 3+}SiN{sub 3} has been predicted by using the density functional theory calculations, and verified by the actual synthesis of CaLaSiN{sub 3}, CaEuSiN{sub 3} and EuLaSiN{sub 3}. The band gap of CaLaSiN{sub 3} was found around 3.2 eV giving the material its yellow color. Eu{sub 2}SiN{sub 3} on the other hand is black due to a combination of the 4f5d absorption band of Eu{sup 2+} and the charge transfer band of Eu{sup 3+}. Thermogravimetric analysis and Raman spectroscopic study of Eu{sub 2}SiN{sub 3} revealed that oxidation of this compound in dry air takes place via a nitrogen retention complex. - Graphical abstract: Energy level scheme of Eu{sub 2}SiN{sub 3} showing the occupied N{sup 3?} 2p band (blue rectangle), unoccupied Eu{sup 2+} 5d band (white rectangle), occupied Eu{sup 2+} 4f ground states (filled red circles) and unoccupied Eu{sup 2+} ground states (open red circles). - Highlights: Density functional theory calculations on the stability of M{sup 2+}L{sup 3+}SiN{sub 3} compounds. Solid-state reaction synthesis of Eu{sub 2}SiN{sub 3}, CaLaSiN{sub 3}, EuLaSiN{sub 3} and CaEuSiN{sub 3}. Determination of the Eu{sup 2+} 4f5d and Eu{sup 3+} CT transitions in M{sup 2+}L{sup 3+}SiN{sub 3} compounds. Oxidation of Eu{sub 2}SiN{sub 3} in dry air takes place via a nitrogen retention complex.

  10. Syntheses, crystal structures, and properties of EuRhIn, EuIr{sub 2}, and EuIrSn{sub 2}

    SciTech Connect (OSTI)

    Poettgen, R.; Hoffmann, R.D.; Moeller, M.H.; Kotzyba, G.; Kuennen, B.; Rosenhahn, C.; Mosel, B.D. [Univ. Muenster (Germany)] [Univ. Muenster (Germany)

    1999-06-01T23:59:59.000Z

    The title compounds were prepared from the elements by reactions in sealed tantalum tubes in a high-frequency furnace. Their structures were refined from single crystal X-ray diffractometer data: Pnma, a = 744.4(1) pm, b = 434.15(9) pm, c = 845.5(1) pm, wR2 = 0.0433, 658 F{sup 2} values, 20 variables for EuRhIn, Rd3m, a = 756.5(1) pm, wR2 = 0.0349, 94 F{sup 2} values, 5 variables for EuIr{sub 2}, and Cmcm, a = 434.78(3) pm, b = 1124.0(1) pm, c = 751.20(5) pm, wR2 = 0.0561, 565 F{sup 2} values, 16 variables for EuIrSn{sub 2}. EuRhIn crystallizes with a TiNiSi type structure that consists of strongly puckered Rh{sub 3}In{sub 3} hexagons. The europium atoms fill the channels within the three-dimensional [RhIn] polyanion. EuRhIn orders ferromagnetically at 22.0(5) K with a saturation magnetic moment of 6.7(1) {mu}{sub B}/Eu at 4 k and 5.5 T. The divalent character of the europium atoms in EuRhIn was determined from temperature dependent susceptibility (7.9 {mu}{sub B}/Eu in the high-temperature part) and {sup 151}Eu Moessbauer spectroscopic experiments. The latter show an isomer shift of {delta} = {minus}8.30(2) mm/s at 78 K. At 4.2 K full magnetic hyperfine field splitting subjected to significant quadrupole splitting of {Delta}E{sub Q} = 8 mm/s is observed. EuRhIn is a metallic conductor with a room temperature value of 58 {micro}{Omega}cm for the specific resistivity. The structure of the Laves phase EuIr{sub 2} is confirmed on the basis of single crystal X-ray data. The iridium atoms form a tetrahedral network with Ir-Ir distances of 268 pm. EuIrSn{sub 2} adopts a MgCuAl{sub 2} type structure that may be described as an iridium-filled variant of a distorted CaIn{sub 2}-like sublattice of composition EuSn{sub 2}. The tin atoms in the distorted and puckered hexagonal network have shorter (303 and 322 pm) and longer (343 pm) tin-tin contacts. 40 refs., 9 figs., 5 tabs.

  11. The EU Approach for Responsible and Safe Management of Spent Fuel and Radioactive Waste - 12118

    SciTech Connect (OSTI)

    Blohm-Hieber, Ute; Necheva, Christina [European Commission, Directorate-General for Energy, Luxembourg L-2920 (Luxembourg)

    2012-07-01T23:59:59.000Z

    In July 2011 legislation on responsible and safe management of spent fuel and radioactive waste was adopted in the European Union (EU). It aims at ensuring a high level of safety, avoiding undue burdens on future generations and enhancing transparency. EU Member States are responsible for the management of their spent fuel and/or radioactive waste. Each Member State remains free to define its fuel cycle policy. The spent fuel can be regarded either as a valuable resource that may be reprocessed or as radioactive waste that is destined for direct disposal. Whatever option is chosen, the disposal of high level waste, separated at reprocessing, or of spent fuel regarded as waste should be considered. The storage of radioactive waste, including long-term storage, is an interim solution, but not an alternative to disposal. To this end, each Member State has to establish, maintain and implement national policy, framework and programme for management of spent fuel and/or radioactive waste in the long term. Member States will invite international peer reviews to ensure that high safety standards are achieved. The EU approach is anchored in internationally endorsed principles and requirements of the IAEA safety standards and the Joint Convention and in this context makes them legally binding and enforceable in the EU. The EU approach of regulating the management of spent fuel and radioactive waste is anchored in the competence of the national regulatory authorities and in the internationally endorsed principles and requirements of the IAEA Safety Standards and the Joint Convention. Member States have to report to the Commission on the implementation of Directive 2011/70/Euratom for the first time by 23 August 2015, and every 3 years thereafter, taking advantage of the review and reporting under the Joint Convention. On the basis of the Member States' reports, the Commission will submit to the European Parliament and the Council a report on progress made and an inventory of radioactive waste and spent fuel present in the EU territory and the future prospects. Directive 2011/70/Euratom is a logical next step after the Council Directive 2009/71/Euratom on the nuclear safety of nuclear installations. The EU is the first major regional actor providing a binding legal framework on nuclear safety and on responsible and safe management of spent fuel and radioactive waste, and thus is a real model to progress spent fuel and waste management in a safe and responsible manner. (authors)

  12. A New Combustion Synthesis Method for GaN:Eu3+ and Ga2O3 :Eu3+

    E-Print Network [OSTI]

    McKittrick, Joanna

    A New Combustion Synthesis Method for GaN:Eu3+ and Ga2O3 :Eu3+ Luminescent Powders G. A. Hirata1 between the precursors. The preparation of Eu-doped Ga2O3 powders was achieved using a new combustion)3 and Ga(NO3)3 as the precursors and hydrazine as (non-carbonaceous) fuel. A spontaneous combustion

  13. Chemical bonding in EuTGe (T=Ni, Pd, Pt) and physical properties of EuPdGe

    SciTech Connect (OSTI)

    Rocquefelte, Xavier [UMR 6226 Sciences Chimiques de Rennes, Universite de Rennes 1-ENSC Rennes-CNRS, Avenue du General Leclerc, F-35042 Rennes Cedex (France); Gautier, Regis [UMR 6226 Sciences Chimiques de Rennes, Universite de Rennes 1-ENSC Rennes-CNRS, Avenue du General Leclerc, F-35042 Rennes Cedex (France); Halet, Jean-Francois [UMR 6226 Sciences Chimiques de Rennes, Universite de Rennes 1-ENSC Rennes-CNRS, Avenue du General Leclerc, F-35042 Rennes Cedex (France)], E-mail: halet@univ-rennes1.fr; Muellmann, Ralf [Institut fuer Physikalische Chemie, Universitaet Muenster, Corrensstrasse 30, D-48149 Muenster (Germany); Rosenhahn, Carsten [Institut fuer Physikalische Chemie, Universitaet Muenster, Corrensstrasse 30, D-48149 Muenster (Germany); Mosel, Bernd D. [Institut fuer Physikalische Chemie, Universitaet Muenster, Corrensstrasse 30, D-48149 Muenster (Germany); Kotzyba, Gunter [Institut fuer Anorganische und Analytische Chemie, Universitaet Muenster, Corrensstrasse 30, D-48149 Muenster (Germany); Poettgen, Rainer [Institut fuer Anorganische und Analytische Chemie, Universitaet Muenster, Corrensstrasse 30, D-48149 Muenster (Germany)], E-mail: pottgen@uni-muenster.de

    2007-02-15T23:59:59.000Z

    EuPdGe was prepared from the elements by reaction in a sealed tantalum tube in a high-frequency furnace. Magnetic susceptibility measurements show Curie-Weiss behavior above 60 K with an experimental magnetic moment of 8.0(1){mu} {sub B}/Eu indicating divalent europium. At low external fields antiferromagnetic ordering is observed at T {sub N}=8.5(5) K. Magnetization measurements indicate a metamagnetic transition at a critical field of 1.5(2) T and a saturation magnetization of 6.4(1){mu} {sub B}/Eu at 5 K and 5.5 T. EuPdGe is a metallic conductor with a room-temperature value of 5000{+-}500 {mu}{omega} cm for the specific resistivity. {sup 151}Eu Moessbauer spectroscopic experiments show a single europium site with an isomer shift of {delta}=-9.7(1) mm/s at 78 K. At 4.2 K full magnetic hyperfine field splitting with a hyperfine field of B=20.7(5) T is observed. Density functional calculations show the similarity of the electronic structures of EuPdGe and EuPtGe. T-Ge interactions (T=Pd, Pt) exist in both compounds. An ionic formula splitting Eu{sup 2+} T {sup 0}Ge{sup 2-} seems more appropriate than Eu{sup 2+} T {sup 2+}Ge{sup 4-} accounting for the bonding in both compounds. Geometry optimizations of EuTGe (T=Ni, Pt, Pd) show weak energy differences between the two structural types. - Graphical abstract: Cutouts of the [PdGe] and [PtGe] polyanions in the structures of EuPdGe and EuPtGe. Atom designations and some relevant interatomic distances are given.

  14. Gas cleaning system and method

    DOE Patents [OSTI]

    Newby, Richard Allen

    2006-06-06T23:59:59.000Z

    A gas cleaning system for removing at least a portion of contaminants, such as halides, sulfur, particulates, mercury, and others, from a synthesis gas (syngas). The gas cleaning system may include one or more filter vessels coupled in series for removing halides, particulates, and sulfur from the syngas. The gas cleaning system may be operated by receiving gas at a first temperature and pressure and dropping the temperature of the syngas as the gas flows through the system. The gas cleaning system may be used for an application requiring clean syngas, such as, but not limited to, fuel cell power generation, IGCC power generation, and chemical synthesis.

  15. power generAtion College of Rural and Community Development

    E-Print Network [OSTI]

    Hartman, Chris

    to Power Generation: Maintenance.......4 PGEN F104--Gas and Steam Turbines; Co-Generation and Combined

  16. EU, U.S., Russia, Asian States Sign Nuclear-Fusion Reactor May 24 (Bloomberg) --The European Union, the U.S., Russia and Asian nations

    E-Print Network [OSTI]

    -gas emissions from fossil fuels, rising oil prices and worries about the safety of existing nuclear plants nuclear-fusion reactor, forging ahead with a 4.6 billion- euro ($5.9 billion) project to cut oil demand. ``It's a historic moment,'' Janez Potocnik, EU commissioner for science and research, told reporters

  17. Research Summary The EU Emissions Trading System: Opportunities for Forests?

    E-Print Network [OSTI]

    is currently the world's largest carbon market. It does not cover carbon sequestration by forests at present. Although the EU ETS does not currently cover forestry carbon sequestration and there is no indication. o Consider potential opportunities associated with the EU ETS and carbon sequestration that may

  18. www.meteoalarm.eu Immediate warnings of dangerous and

    E-Print Network [OSTI]

    Haak, Hein

    1 www.meteoalarm.eu Immediate warnings of dangerous and extreme weather across all of Europe.meteoalarm.eu Immediate warnings of dangerous and extreme weather across all of Europe on Internet. A cooperative Rain 8 Danger from river flooding 8 Thunderstorms 10 Lightning tips 11 Snow and ice 12 Mist and fog 13

  19. www.meteoalarm.eu Immediate warnings of dangerous and

    E-Print Network [OSTI]

    Stoffelen, Ad

    1 www.meteoalarm.eu Immediate warnings of dangerous and extreme weather across all of Europe dangers 16 Forest and bush fires 17 Avalanches 18 #12;33 www.meteoalarm.eu The weather knows no boundaries dangerous, both nationally and on a local scale of over 650 regions. Not only are gales, torrential rain

  20. EU Guide v 2d January 20141 Finance Division

    E-Print Network [OSTI]

    de Gispert, Adri

    EU Guide v 2d January 20141 Finance Division Procurement Services The EU Directives on Public purchasing practice and especially where funders require it as part of their grant conditions. In exceptional Andrew Reid (goods and services) or the Director of Estate Management and Building Services (property

  1. What (Economic) Constitution Does the EU Need ? Janvier 2007

    E-Print Network [OSTI]

    Boyer, Edmond

    of the structurally different economic performances and incentives of small and large countries under the EuropeanWhat (Economic) Constitution Does the EU Need ? N 2007-04 Janvier 2007 Eloi Laurent OFCE-FNSP eloi2014 #12;2 What (Economic) Constitution Does the EU Need? * loi Laurent (OFCE/FNSP)1 Jacques Le

  2. Japan rejects EU ITER deal 02 February 2005

    E-Print Network [OSTI]

    billion (euro 422 million) worth of orders to EU companies and to fund around half the costs this year. The joint project between Japan, the EU, the US, Russia, China and South Korea will see, supported by Russia and China proposes the French town of Cadarache for the development. Meanwhile

  3. Published on Africa EU (http://www.africa-eu-partnership.org) Home > News > Cameroon axes illegal logging > Printer-friendly

    E-Print Network [OSTI]

    Published on Africa EU (http://www.africa-eu-partnership.org) Home > News > Cameroon axes illegal logging > Printer-friendly Cameroon axes illegal logging 14/05/2010 Cameroon axes illegal logging Illegal and trade of illegal logging. The latest country to sign up to the programme is Cameroon, which completed

  4. Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high temperature furnace (HITAF). Quarterly progress report No. 7, July--September 1993

    SciTech Connect (OSTI)

    Not Available

    1993-11-01T23:59:59.000Z

    A concept for an advanced coal-fired combined-cycle power generating system is currently being developed. The first phase of this three-phase program consists of conducting the necessary research and development to define the system, evaluating the economic and technical feasibility of the concept, and preparing an R&D plan to develop the concept further. Foster Wheeler Development Corporation (FWDC) is leading a team of companies involved in this effort. The power generating system being developed in this project will be an improvement over current coal-fired systems. Goals have been specified that relate to the efficiency, emissions, costs, and general operation of the system. The system proposed to meet these goals is a combined-cycle system where air for a gas turbine is indirectly heated to approximately 1800{degrees}F in furnaces fired with coal-derived fuels and then directly heated in a natural-gas-fired combustor to about 2400{degrees}F. The system is based on a pyrolyzing process that converts the coal into a low-Btu fuel gas and char. The fuel gas is relatively clean, and it is fired to heat tube surfaces that are susceptible to corrosion and problems from ash deposition. In particular, the high-temperature air heater tubes, which will need to be a ceramic material, will be located in a separate furnace or region of a furnace that is exposed to combustion products from the low-Btu fuel gas only. A simplified process flow diagram is shown in Figure 1.

  5. A facile preparation and the luminescent properties of Eu{sup 3+}-doped Y{sub 2}O{sub 2}SO{sub 4} nanopieces

    SciTech Connect (OSTI)

    Song, Lixin; Shao, Xiaoli; Du, Pingfan; Cao, Houbao; Hui, Quan; Xing, Tonghai; Xiong, Jie, E-mail: jxiong@zstu.edu.cn

    2013-11-15T23:59:59.000Z

    Graphical abstract: - Highlights: Y{sub 2}O{sub 2}SO{sub 4}:Eu{sup 3+} nanopieces were prepared via electrospinning followed by calcination. The photoluminescence of Y{sub 2}O{sub 2}SO{sub 4}:Eu{sup 3+} nanopieces were investigated. The Y{sub 2}O{sub 2}SO{sub 4}:Eu{sup 3+} was compared to nanoribbons and commercial Y{sub 2}O{sub 3}:Eu{sup 3+}. The potential applications of the nanopieces and the facile method are suggested. - Abstract: The europium(III)-doped yttrium oxysulfate (Y{sub 2}O{sub 2}SO{sub 4}:Eu{sup 3+}) nanopieces have been prepared via electrospinning followed by calcination at 1000 C in mixed gas of sulfur dioxide and air. Based on the experimental results, a possible formation mechanism for the nanopieces is that the nanopieces are determined by the directing template of electrospun nanoribbons and the multilayer crystal structure of Y{sub 2}O{sub 2}SO{sub 4}. Besides, the nanopieces show excellent luminescent properties with emissions at 581, 589, 597, 653, 619, and 697 nm resulting from the {sup 5}D{sub 0} ? {sup 7}F{sub J} (J = 0, 1, 2, 3, 4) transition of Eu{sup 3+}. The peaks of charge transfer and {sup 5}D{sub 0} ? {sup 7}F{sub 2} transition of Eu{sup 3+} obviously have red shifts comparing to those of both Y{sub 2}O{sub 3}:Eu{sup 3+} nanoribbons and commercial Y{sub 2}O{sub 3}:Eu{sup 3+}. Moreover, the nanopieces exhibit stronger intensities than the Y{sub 2}O{sub 3}:Eu{sup 3+} in excitation and emission spectra. Concentration quenching in the nanopieces occurs when Eu{sup 3+} concentration is 11 mol%, indicating that the nanopieces have an optimum luminescent intensity under this doping concentration.

  6. Antiferromagnetism of perovskite EuZrO{sub 3}

    SciTech Connect (OSTI)

    Zong Yanhua [Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan); Fujita, Koji, E-mail: fujita@dipole7.kuic.kyoto-u.ac.j [Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan); Akamatsu, Hirofumi; Murai, Shunsuke; Tanaka, Katsuhisa [Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510 (Japan)

    2010-01-15T23:59:59.000Z

    Polycrystalline EuZrO{sub 3} has been synthesized by the solid-state reaction between EuO and ZrO{sub 2}, and its structural and magnetic properties have been investigated. Rietveld analysis of the X-ray diffraction pattern indicates that EuZrO{sub 3} crystallizes in an orthorhombic perovskite structure. {sup 151}Eu Moessbauer effect measurement reveals that almost all the europium ions are present as the divalent state and occupy distorted sites with non-axial electric field gradients, in agreement with the orthorhombic structure. In contrast to previous reports, an antiferromagnetic transition was observed around 4.1 K. The magnetic structure below the Neel temperature has been discussed. - Graphical abstract: Perovskite EuZrO{sub 3} with almost all Eu ions present as Eu{sup 2+} has been synthesized and its structure and magnetic properties have been studied. An antiferromagnetic transition was observed around 4.1 K for the first time. The mechanism of the magnetic transition has been discussed.

  7. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, R.; George, R.A.; Shockling, L.A.

    1993-04-06T23:59:59.000Z

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  8. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, Robert (Churchill Boro, PA); George, Raymond A. (Pittsburgh, PA); Shockling, Larry A. (Plum Borough, PA)

    1993-01-01T23:59:59.000Z

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  9. Optical Probing of metamagnetic phases in epitaxial EuSe

    SciTech Connect (OSTI)

    Galgano, G. D.; Henriques, A. B. [Instituto de Fisica, Universidade de Sao Paulo, Caixa Postal 66318, 05315-970 Sao Paulo (Brazil); Bauer, G.; Springholz, G. [Institut fuer Halbleiter und Festkoerperphysik, Johannes Kepler Universitaet Linz, 4040 Linz (Austria)

    2011-12-23T23:59:59.000Z

    EuSe is a wide gap magnetic semiconductors with a potential for applications in proof-of-concept spintronic devices. When the temperature is lowered, EuSe goes through sharp transitions between a variety of magnetic phases and is thus described as metamagnetic. The purpose of the present investigation is to correlate the magnetic order to the sharp dichroic doublet, discovered recently in high quality thin epitaxial layers of EuSe, grown by molecular beam epitaxy. We report detailed measurements of the doublet positions and intensities as a function of magnetic field in low temperatures, covering several magnetic phases.

  10. Fact #844: October 27, 2014 Electricity Generated from Coal has...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4: October 27, 2014 Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown Fact 844: October 27, 2014 Electricity Generated from Coal has...

  11. Distributed Generation Investment by a Microgrid Under Uncertainty

    E-Print Network [OSTI]

    Siddiqui, Afzal; Marnay, Chris

    2006-01-01T23:59:59.000Z

    option on natural gas generation, which increases in valueL ABORATORY Distributed Generation Investment by a MicrogridORMMES06 Distributed Generation Investment by a Microgrid

  12. Gas Turbine Emissions

    E-Print Network [OSTI]

    Frederick, J. D.

    1990-01-01T23:59:59.000Z

    of regulatory interest in the 'real world' test results coupled with the difficulties of gathering analogous bench test data for systems employing gas turbines with Heat Recovery Steam Generators (HRSG) and steam injection. It appears that the agencies...

  13. Stringency and distribution in the EU ETS: first evidence 41 CLIMATE POLICY

    E-Print Network [OSTI]

    Steininger, Karl W.

    Stringency and distribution in the EU Emissions Trading Scheme: first evidence CLAUDIA KETTNER1,2 , ANGELA covered by the EU Emissions Trading Scheme (EU ETS) were compared. Based on data available for 24 Member: climate policy; emissions trading; EU Emissions Trading Scheme A partir des missions vrifies pour les

  14. MHD Generating system

    DOE Patents [OSTI]

    Petrick, Michael (Joliet, IL); Pierson, Edward S. (Chicago, IL); Schreiner, Felix (Mokena, IL)

    1980-01-01T23:59:59.000Z

    According to the present invention, coal combustion gas is the primary working fluid and copper or a copper alloy is the electrodynamic fluid in the MHD generator, thereby eliminating the heat exchangers between the combustor and the liquid-metal MHD working fluids, allowing the use of a conventional coalfired steam bottoming plant, and making the plant simpler, more efficient and cheaper. In operation, the gas and liquid are combined in a mixer and the resulting two-phase mixture enters the MHD generator. The MHD generator acts as a turbine and electric generator in one unit wherein the gas expands, drives the liquid across the magnetic field and thus generates electrical power. The gas and liquid are separated, and the available energy in the gas is recovered before the gas is exhausted to the atmosphere. Where the combustion gas contains sulfur, oxygen is bubbled through a side loop to remove sulfur therefrom as a concentrated stream of sulfur dioxide. The combustor is operated substoichiometrically to control the oxide level in the copper.

  15. Agricultural policies in France: from EU regulation to national design

    E-Print Network [OSTI]

    Boyer, Edmond

    Agricultural policies in France: from EU regulation to national design Yann Desjeux, Herv Guyomard.................................................................................2 I.2. Short characteristics of the French agriculture and its strategic problems ...............8.......................................................................................................................13 II. Agricultural market policy (Pillar I

  16. Forschung und EU-Hochschulbro, Technologietransfer Februar 2012

    E-Print Network [OSTI]

    Nejdl, Wolfgang

    .7. Forschungsinfrastrukturen 8 2.7.1. Arbeitsprogramm 2013 Geplante Ausschreibungen 8 2.8. Euratom 9 2.8.1. Nuclear Fission.1.1. EU/BMELV: ICT and Automation for a Greener Agriculture (ERA-NET ICT-AGRI) Vorankndigung 16 6 Entwurf Arbeitsprogramm 2012 19 8.1.2. EU/BMELV: ICT and Automation for a Greener Agriculture (ERA-NET ICT

  17. Luminescent properties of Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} and its potential application in white light emitting diodes

    SciTech Connect (OSTI)

    Wang, Zhijun, E-mail: wangzhijunmail@yahoo.com.cn [College of Physics Science and Technology, Hebei University, Baoding 071002 (China); Li, Panlai; Li, Ting; Zhang, Xing; Li, Qingxuan; Yang, Zhiping; Guo, Qinglin [College of Physics Science and Technology, Hebei University, Baoding 071002 (China)

    2013-06-01T23:59:59.000Z

    Graphical abstract: Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} phosphor can be effectively excited by an ultraviolet and near-ultraviolet light, and produce a bright blue emission centered at 436 nm. The CIE chromaticity coordinations (x, y) of Na{sub 2}CaSiO{sub 4}:Eu{sup 2+}(NSCE)/Li{sub 2}SrSiO{sub 4}:Eu{sup 2+}(LSSE) vary with the molar ratio of the two constituents. When NSCE/LSSE is 1:3, the CIE chromaticity coordination is (0.332, 0.346), which is close to that of the natural sunlight (0.33, 0.33). The results indicate that Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} may be a promising blue phosphor for UV chip-based multi-phosphor converted white light emitting diodes. Highlights: ? Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} shows the blue emission with a peak at 436 nm and broad excitation band in the UV/n-UV range. ? White light with CIE coordinates (0.332, 0.346) is generated by mixing the blue phosphor with the Li{sub 2}SrSiO{sub 4}:Eu{sup 2+} yellow phosphor. ? Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} would be a promising blue phosphor candidate for UV chip-based multi-phosphor converted white LEDs. - Abstract: A novel blue phosphor Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} is synthesized by a high temperature solid-state reaction, and its luminescent properties are systematically studied. Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} can be effectively excited by the 354 nm radiation, and create blue emission (436 nm). The emission intensity of Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} is influenced by the Eu{sup 2+} doping content, and the optimal doping content is 1.5%, and the concentration quenching mechanism of Eu{sup 2+} in Na{sub 2}CaSiO{sub 4} can be attributed to the multipolar interaction. The white light with CIE coordinates (0.332, 0.346) is generated by mixing the blue phosphor Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} with the yellow phosphor Li{sub 2}SrSiO{sub 4}:Eu{sup 2+}. The results indicate that Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} may be a potential blue emitting phosphor for UV chip-based multi-phosphor converted white light emitting diodes.

  18. Natural gas leak mapper

    DOE Patents [OSTI]

    Reichardt, Thomas A. (Livermore, CA); Luong, Amy Khai (Dublin, CA); Kulp, Thomas J. (Livermore, CA); Devdas, Sanjay (Albany, CA)

    2008-05-20T23:59:59.000Z

    A system is described that is suitable for use in determining the location of leaks of gases having a background concentration. The system is a point-wise backscatter absorption gas measurement system that measures absorption and distance to each point of an image. The absorption measurement provides an indication of the total amount of a gas of interest, and the distance provides an estimate of the background concentration of gas. The distance is measured from the time-of-flight of laser pulse that is generated along with the absorption measurement light. The measurements are formated into an image of the presence of gas in excess of the background. Alternatively, an image of the scene is superimosed on the image of the gas to aid in locating leaks. By further modeling excess gas as a plume having a known concentration profile, the present system provides an estimate of the maximum concentration of the gas of interest.

  19. Metastable states in InGaN/GaN MQW structures doped with Sm, Eu, and Eu + Sm

    SciTech Connect (OSTI)

    Mezdrogina, M. M., E-mail: Margaret.M@mail.ioffe.ru [Russian Academy of Sciences, Ioffe Physical-Technical Institute (Russian Federation); Kozhanova, Yu. V. [St. Petersburg State Polytechnical University (Russian Federation)

    2013-04-15T23:59:59.000Z

    Measurements of the microphotoluminescence (microPL) spectra of InGaN/GaN:Sm and InGaN/GaN:Eu quantum well (QW) structures show that the action of a magnetic field gives rise to Van Vleck paramagnetism for Eu{sup 3+} and Sm{sup 3+}. The macrophotoluminescence (macroPL) spectra recorded after measuring the microPL spectra of InGaN/GaN QW structures doped with Sm or Eu + Sm at a high excitation level (>10{sup 23} photons cm{sup -2} s{sup -1}) in magnetic fields contain no QW emission lines which are present in the macroPL spectra recorded before these microPL measurements. This is indicative of the presence of photoinduced defects. Annealing of the InGaN/GaN:Sm and InGaN/GaN:(Eu + Sm) structures reduces the concentration of photoinduced defects.

  20. Power System Modeling of 20percent Wind-Generated Electricity by 2030

    E-Print Network [OSTI]

    Hand, Maureen

    2008-01-01T23:59:59.000Z

    generation by 18%. Natural gas combustion turbine capacitycombined cycle natural gas plants, combustion turbinenuclear plants, combustion turbine natural gas plants, and

  1. Power System Modeling of 20percent Wind-Generated Electricity by 2030

    E-Print Network [OSTI]

    Hand, Maureen

    2008-01-01T23:59:59.000Z

    generation by 18%. Natural gas combustion turbine capacitycycle natural gas plants, combustion turbine natural gasnuclear plants, combustion turbine natural gas plants, and

  2. Retained Gas Sampling Results for the Flammable Gas Program

    SciTech Connect (OSTI)

    J.M. Bates; L.A. Mahoney; M.E. Dahl; Z.I. Antoniak

    1999-11-18T23:59:59.000Z

    The key phenomena of the Flammable Gas Safety Issue are generation of the gas mixture, the modes of gas retention, and the mechanisms causing release of the gas. An understanding of the mechanisms of these processes is required for final resolution of the safety issue. Central to understanding is gathering information from such sources as historical records, tank sampling data, tank process data (temperatures, ventilation rates, etc.), and laboratory evaluations conducted on tank waste samples.

  3. EIS-0105: Conversion to Coal, Baltimore Gas & Electric Company, Brandon Shores Generating Station Units 1 and 2, Anne Arundel County, Maryland

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energys Economic Regulatory Administration Office of Fuels Program, Coal and Electricity Division prepared this statement to assess the potential environmental and socioeconomic impacts associated with prohibiting the use of petroleum products as a primary energy source for Units 1 and 2 of the Brandon Shores Generating Station, located in Anne Arundel County, Maryland.

  4. Optically induced magnetic polarons in EuTe

    SciTech Connect (OSTI)

    Henriques, A. B.; Galgano, G. D. [Instituto de Fsica, Universidade de So Paulo, Caixa Postal 66318, 05315-970, So Paulo (Brazil); Abramof, E.; Rappl, P. H. O. [LAS - INPE, Av. Dos Astronautas, 1758, 12227-010, So Jos dos Campos (Brazil)

    2013-12-04T23:59:59.000Z

    Direct measurements of the photoinduced magnetization in EuTe, using a two color pump-and-probe technique, are presented. The photoinduced effect was pumped using photons of above-the-bandgap energy, and detected by the Faraday rotation of a probe beam of energy below-the-bandgap. The photoinduced Faraday rotation changes sign, as expected from our model for the optically induced magnetic polaron. The EuTe spin-flop transition at low fields is also detected as a sharp step in the photoinduced Faraday rotation, and its observation provides additional supports for the photoinduced polaron model.

  5. Method of Liquifying a gas

    DOE Patents [OSTI]

    Zollinger, William T.; Bingham, Dennis N.; McKellar, Michael G.; Wilding, Bruce M.; Klingler, Kerry M.

    2006-02-14T23:59:59.000Z

    A method of liquefying a gas is disclosed and which includes the steps of pressurizing a liquid; mixing a reactant composition with the pressurized liquid to generate a high pressure gas; supplying the high pressure gas to an expansion engine which produces a gas having a reduced pressure and temperature, and which further generates a power and/or work output; coupling the expansion engine in fluid flowing relation relative to a refrigeration assembly, and wherein the gas having the reduced temperature is provided to the refrigeration assembly; and energizing and/or actuating the refrigeration assembly, at least in part, by supplying the power and/or work output generated by the expansion engine to the refrigeration assembly, the refrigeration assembly further reducing the temperature of the gas to liquefy same.

  6. Gas Filled Detectors counting & tracking of

    E-Print Network [OSTI]

    Peletier, Reynier

    Gas Filled Detectors counting & tracking of particles energy loss generation of electron-ion+ pairs #12;Gas Filled Detectors Primary and Total Ionization fast charged particles ionize the atoms of a gas fraction of resulting primary electrons have enough kinetic energy to ionize other atoms #12;Gas Filled

  7. Utilization of coal mine ventilation exhaust as combustion air in gas-fired turbines for electric and/or mechanical power generation. Semi-annual topical report, June 1995--August 1995

    SciTech Connect (OSTI)

    NONE

    1995-12-01T23:59:59.000Z

    Methane emitted during underground coal mining operations is a hazard that is dealt with by diluting the methane with fresh air and exhausting the contaminated air to the atmosphere. Unfortunately this waste stream may contain more than 60% of the methane resource from the coal, and in the atmosphere the methane acts as a greenhouse gas with an effect about 24.5 times greater than CO{sub 2}. Though the waste stream is too dilute for normal recovery processes, it can be used as combustion air for a turbine-generator, thereby reducing the turbine fuel requirements while reducing emissions. Preliminary analysis indicates that such a system, built using standard equipment, is economically and environmentally attractive, and has potential for worldwide application.

  8. Reforming the EU: The Future of European Law and Policy IV CONFERENCE PROGRAMME

    E-Print Network [OSTI]

    Birmingham, University of

    Reforming the EU: The Future of European Law and Policy IV CONFERENCE session "Reforming the EU" Chair: Dr Luca Rubini, Deputy Director Institute Rubini Reforming European competition law: should the European Commission have

  9. The EU ETS: CO2 prices drivers during the learning experience (2005-2007)

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Union Allowances (EUAs), valid for compliance under the European Union Emissions Trading Scheme (EU ETS of the European Union Emissions Trading Scheme (EU ETS) is to regulate CO2 emissions from the most energy

  10. EU, CHINA AND THE ENVIRONMENTAL CHALLENGE IN AFRICA A case study from timber industry in Gabon

    E-Print Network [OSTI]

    1 EU, CHINA AND THE ENVIRONMENTAL CHALLENGE IN AFRICA A case study from timber industry: .....................................................................................................................................................2 Part I: The EU, China and the external environmental dimension....................................................................3 1.1 China as a competitor normative power in the environmental sector

  11. Enlargement and the EU Periphery: The Impact of Changing Market Potential

    E-Print Network [OSTI]

    Boyer, Edmond

    proximate to the new accession countries than in "interior" EU regions. We also find that a future Balkans through which EU enlargement may affect the economies of Western Europe: increased specialisation

  12. ANNUAL TRILATERAL U.S. - EU - JAPAN CONFERENCE ON CRITICAL MATERIALS...

    Office of Environmental Management (EM)

    ANNUAL TRILATERAL U.S. - EU - JAPAN CONFERENCE ON CRITICAL MATERIALS FOR A CLEAN ENERGY FUTURE, SEPTEMBER 8-9, 2014 ANNUAL TRILATERAL U.S. - EU - JAPAN CONFERENCE ON CRITICAL...

  13. The Political Economy of Agri-Environmental Policies in the EU

    E-Print Network [OSTI]

    Swinnen, Johan

    2005-01-01T23:59:59.000Z

    Economy of Agri-Environmental Policies in the EU JohanEconomy of Agri-Environmental Policies in the EU Johan F.M.changes Agri-environmental policies are only fraction of

  14. How EU Agri-Environmental Policy Might Have Differed Under Various WTO Scenarios

    E-Print Network [OSTI]

    Swinbank, Alan

    2005-01-01T23:59:59.000Z

    No. 12 How EU Agri-Environmental Policy Might Have DifferedEconomy of Agri-environmental Policies in the U.S. and the2005 How EU agri-environmental policy might have differed

  15. Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high-temperature furnace (HITAF): Volume 3. Final report

    SciTech Connect (OSTI)

    NONE

    1996-05-01T23:59:59.000Z

    Testing of an atmospheric circulating bed pyrolyzer was done at Southern Illinois University. A variety of experiments have been conducted in a laboratory scale pyrolyzer with coal input flow rates from 2 to 6 lb/h. three feed coal particle sizes, corresponding to a nominal -40 mesh, -30 mesh and -18 mesh were used. The limestone used in the tests was a Genstar limestone. Parameters investigated in the tests include the influence of superficial velocity, temperature and coal-air mass ratios. Char particle size distributions under various test conditions have been measured and the char composition determined. Fuel gas composition, yields and heating values have been investigated. Char morphology has been studied using scanning electron microscopy. Char reactivity for selected samples has been measures, and the influence of feed coal size, bed temperature and superficial velocity has been determined. Material balance calculations have been performed and found to be in very good agreement. Energy audit calculations for the process have been made to investigate the flow of energy and to estimate the losses during the process. Full details of the data, results obtained and conclusions drawn are presented.

  16. Catalytic hydrolysis of urea with fly ash for generation of ammonia in a batch reactor for flue gas conditioning and NOx reduction

    SciTech Connect (OSTI)

    Sahu, J.N.; Gangadharan, P.; Patwardhan, A.V.; Meikap, B.C. [Indian Institute of Technology, Kharagpur (India). Dept. of Chemical Engineering

    2009-01-15T23:59:59.000Z

    Ammonia is a highly volatile noxious material with adverse physiological effects, which become intolerable even at very low concentrations and present substantial environmental and operating hazards and risk. Yet ammonia has long been known to be used for feedstock of flue gas conditioning and NOx reduction. Urea as the source of ammonia for the production of ammonia has the obvious advantages that no ammonia shipping, handling, and storage is required. The process of this invention minimizes the risks and hazards associated with the transport, storage, and use of anhydrous and aqueous ammonia. Yet no such rapid urea conversion process is available as per requirement of high conversion in shorter time, so here we study the catalytic hydrolysis of urea for fast conversion in a batch reactor. The catalyst used in this study is fly ash, a waste material originating in great amounts in combustion processes. A number of experiments were carried out in a batch reactor at different catalytic doses, temperatures, times, and at a constant concentration of urea solution 10% by weight, and equilibrium and kinetic studies have been made.

  17. Heat transfer and flow on the first-stage blade tip of a power generation gas turbine: Part 2 -- Simulation results

    SciTech Connect (OSTI)

    Ameri, A.A.; Bunker, R.S.

    2000-04-01T23:59:59.000Z

    A combined experimental and computational study has been performed to investigate the detailed distribution of convective heat transfer coefficients on the first-stage blade tip surface for a geometry typical of large power generation turbines (> 100 MW). This paper is concerned with the numerical prediction of the tip surface heat transfer. Good comparison with the experimental measured distribution was achieved through accurate modeling of the most important features of the blade passage and heating arrangement as well as the details of experimental rig likely to affect the tip heat transfer. A sharp edge and a radiused edge tip was considered. The results using the radiused edge tip agreed better with the experimental data. This improved agreement was attributed to the absence of edge separation on the tip of the radiused edge blade.

  18. The EU Emission Trading Scheme Insights from the First Trading Years

    E-Print Network [OSTI]

    Steininger, Karl W.

    observed in the Kyoto period. Price development in the EU ETS is mainly driven by the perceived stringency

  19. High gas flow alpha detector

    DOE Patents [OSTI]

    Bolton, R.D.; Bounds, J.A.; Rawool-Sullivan, M.W.

    1996-05-07T23:59:59.000Z

    An alpha detector for application in areas of high velocity gas flows, such as smokestacks and air vents. A plurality of spaced apart signal collectors are placed inside an enclosure, which would include smokestacks and air vents, in sufficient numbers to substantially span said enclosure so that gas ions generated within the gas flow are electrostatically captured by the signal collector means. Electrometer means and a voltage source are connected to the signal collectors to generate an electrical field between adjacent signal collectors, and to indicate a current produced through collection of the gas ions by the signal collectors. 4 figs.

  20. High gas flow alpha detector

    DOE Patents [OSTI]

    Bolton, Richard D. (Los Alamos, NM); Bounds, John A. (Los Alamos, NM); Rawool-Sullivan, Mohini W. (Los Alamos, NM)

    1996-01-01T23:59:59.000Z

    An alpha detector for application in areas of high velocity gas flows, such as smokestacks and air vents. A plurality of spaced apart signal collectors are placed inside an enclosure, which would include smokestacks and air vents, in sufficient numbers to substantially span said enclosure so that gas ions generated within the gas flow are electrostatically captured by the signal collector means. Electrometer means and a voltage source are connected to the signal collectors to generate an electrical field between adjacent signal collectors, and to indicate a current produced through collection of the gas ions by the signal collectors.

  1. Forschung und EU-Hochschulbro, Technologietransfer September 2014

    E-Print Network [OSTI]

    Nejdl, Wolfgang

    Nachwuchswissenschaftler/innen 4 1.2. LEIT: Information and communication technologies 4 1.2.1. ffentliche Konsultation zu Programme Chemical Biology of Native Nucleic Acid Modifications (SPP 1784) 13 4.1.4. Volkswagen.1.8. NIH: Research Grants 16 5. Umweltwissenschaften und Energie 16 5.1.1. EU/KIC InnoEnergy: Call

  2. Limited Sectoral Trading between the EU ETS and China

    E-Print Network [OSTI]

    Limited Sectoral Trading between the EU ETS and China Claire Gavard, Niven Winchester and Sergey established research centers at MIT: the Center for Global Change Science (CGCS) and the Center for Energy analysis need to be related to the economic, technological, and political forces that drive emissions

  3. EU signs ITER deal Negotiations on the ITER international nuclear

    E-Print Network [OSTI]

    Korea and the US, the agreement aims to develop a project that will test the feasibility of nuclearEU signs ITER deal Negotiations on the ITER international nuclear fusion project have been on Wednesday reached a final agreement on the ITER project after years of talks. "The completion

  4. Transitioning Applications to Ontologies http://www.tao-project.eu/

    E-Print Network [OSTI]

    Bontcheva, Kalina

    Transitioning Applications to Ontologies http://www.tao-project.eu/ GOAL Define a low-cost route) in aerospace and automotive industries Software applications maintenance and user support Other areas existing application documentation (specifications, UML diagrams, code documentation, software manuals

  5. Transitioning Applications to Ontologies http://www.tao-project.eu

    E-Print Network [OSTI]

    Bontcheva, Kalina

    Transitioning Applications to Ontologies http://www.tao-project.eu TAO Transitioning Applications to Ontologies The goal of the TAO project is to define a low-cost route to transitioning legacy systems will be validated in two high-profile case studies: a comprehensive open source platform (with thousands of users

  6. Mossbauer studies of 151 Eu in europium oxalate,

    E-Print Network [OSTI]

    Ryan, Dominic

    Mossbauer studies of 151 Eu in europium oxalate, europium bissalen ammonium and europium benzoate of europium water insoluble chelates have been prepared for several decades, the covalent nature temperatures (qD) of three europium chelates: namely europium oxalate, europium bissalen ammonium (recently

  7. Luminescence properties of a blue-emitting phosphor: (Sr{sub 1?x}Eu{sub x})Si{sub 9}Al{sub 19}ON{sub 31} (0

    SciTech Connect (OSTI)

    Liu, Lihong [Structural and Functional Integration of Ceramics Group, The Division of Functional Materials and Nanodevices, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201 (China); Xie, Rong-Jun, E-mail: XIE.Rong-Jun@nims.go.jp [Sialon Group, Sialon Unit, National Institute for Materials Science, Namiki 1-1, Tsukuba, Ibaraki 305-0044 (Japan); Hirosaki, Naoto; Dierre, Benjamin [Sialon Group, Sialon Unit, National Institute for Materials Science, Namiki 1-1, Tsukuba, Ibaraki 305-0044 (Japan); Sekiguchi, Takashi [Advanced Electronic Materials Center, National Institute for Materials Science, Namiki 1-1, Tsukuba, Ibaraki 305-0044 (Japan)

    2013-11-15T23:59:59.000Z

    Blue-emitting Sr{sub 1?x}Eu{sub x}Si{sub 9}Al{sub 19}ON{sub 31} phosphors were synthesized at 1800 C for 2 h under 1 MPa N{sub 2} by using the gas-pressure sintering method (GPS). The microstructure, photoluminescence (PL) properties of the prepared phosphors were investigated. Under the 290 nm excitation, broad PL emission bands with peak positions at 448490 nm were detected. The concentration quenching was not observed owing to the large distance betweenEu{sup 2+} ions that made the nonradiative energy transfer between neighboring Eu{sup 2+} ions difficult. The blue phosphor generally showed a small thermal quenching at low Eu{sup 2+} concentrations. The absorption and external quantum efficiency of the synthesized Sr{sub 0.5}Eu{sub 0.5}Si{sub 9}Al{sub 19}ON{sub 31} were 85% and 62% upon the 365 nm excitation, respectively. The interesting PL results indicate that Sr{sub 1?x}Eu{sub x}Si{sub 9}Al{sub 19}ON{sub 31} has great potentials as a blue phosphor for white LEDs applications. - Graphical abstract: Sr{sub 0.7}Eu{sub 0.3}Si{sub 9}Al{sub 19}ON{sub 31} gives blue-emitting at 471 nm. Excitation spectrum is composed of five bands in the range of 250450 nm, which are matching well with emission wavelength of UV LEDs. Display Omitted - Highlights: Blue-emitting Sr{sub 1?x}Eu{sub x}Si{sub 9}Al{sub 19}ON{sub 31} phosphors were synthesized by gas-pressure sintering method. The concentration quenching was not observed in this phosphor. This blue phosphor generally showed a small thermal quenching at low Eu{sup 2+} concentrations. The absorption and external quantum efficiency of the synthesized Sr{sub 0.5}Eu{sub 0.5}Si{sub 9}Al{sub 19}ON{sub 31} were 85% and 62% upon the 365 nm excitation.

  8. Oil and Gas Gross Production Tax (North Dakota)

    Broader source: Energy.gov [DOE]

    A gross production tax applies to most gas produced in North Dakota. Gas burned at the well site to power an electrical generator that consumes at least 75 percent of the gas is exempt from...

  9. Sorption of Eu(III) on Attapulgite Studied by Batch, XPS and EXAFS Techniques

    E-Print Network [OSTI]

    Boyer, Edmond

    , the sorption of Eu(III) at the solid-water interface is important for the performance assessment of nuclear and absence of fulvic acid (FA) and humic acid (HA). The results indicated that the sorption of Eu. The extended X-ray absorption fine structure (EXAFS) analysis of Eu-HA complexes indicated that the distances

  10. Carbon Leakage in the Primary Aluminium Sector: What evidence after 6 years of the EU ETS?

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    of the European Union Emissions Trading Scheme (EU ETS). The findings suggest that while rising electricity prices. Keywords: carbon leakage, European Union Emissions Trading Scheme (EU ETS), CO2 pricing 1 1 #12;32 2 1 - Introduction Since the European Union Emissions Trading Scheme (EU ETS) began pricing CO2 emissions within

  11. Call for expression of interest EU-Brazil Technology and Innovation Forum

    E-Print Network [OSTI]

    Call for expression of interest EU-Brazil Technology and Innovation Forum Participation to B2B targeting research and innovation actors. Among them, this year the EU-Brazil Technology and Innovation and Innovation Forum The EU-Brazil Technology and Innovation Forum is organized by the B.BICE+ consortium

  12. Copyright reform on the EU level European Network for Copyright in support of

    E-Print Network [OSTI]

    Kuhlen, Rainer

    Copyright reform on the EU level European Network for Copyright in support of Education and Budapest Business School #12;Copyright reform on the EU level What can science and education expect from a copyright reform on the EU level? Rainer Kuhlen University of Konstanz, HumboldtUniversity Berlin, IPR

  13. EU BIOFUEL USE AND AGRICULTURAL COMMODITY PRICES: A REVIEW OF THE EVIDENCE BASE

    E-Print Network [OSTI]

    EU BIOFUEL USE AND AGRICULTURAL COMMODITY PRICES: A REVIEW OF THE EVIDENCE BASE Report prepared: Kretschmer, B, Bowyer, C and Buckwell, A (2012) EU Biofuel Use and Agricultural Commodity Prices: A Review............................................................................................................. 8 2 EU POLICY DRIVING BIOFUELS DEMAND AND OUTLOOK FOR THIS DEMAND TO 2020. 9 2.1 What is the current

  14. Issue No. 13 of 2 July 2010 The EU bans illegal timber and timber products

    E-Print Network [OSTI]

    Issue No. 13 of 2 July 2010 The EU bans illegal timber and timber products On 16 June 2010, the EU Parliament and the EU Council reached an agreement on the ban of illegally-logged or illegally-sourced timber in October 2008. Illegal logging is defined as the harvest, processing or trading of timber in violation

  15. Oxygen off-stoichiometry and phase separation in EuO thin films

    SciTech Connect (OSTI)

    Altendorf, S. G.; Efimenko, A.; Oliana, V. [II. Physikalisches Institut, Universitaet zu Koeln, Zuelpicher Str. 77, DE-50937 Koeln (Germany); Max Planck Institute for Chemical Physics of Solids, Noethnitzerstr. 40, DE-01187 Dresden (Germany); Kierspel, H. [II. Physikalisches Institut, Universitaet zu Koeln, Zuelpicher Str. 77, DE-50937 Koeln (Germany); Rata, A. D.; Tjeng, L. H. [Max Planck Institute for Chemical Physics of Solids, Noethnitzerstr. 40, DE-01187 Dresden (Germany)

    2011-10-15T23:59:59.000Z

    We report on our study on the influence of the growth conditions on the europium/oxygen stoichiometry, morphology, magnetic properties, and electrical conductivity of EuO thin films. SQUID magnetometry and x-ray photoelectron spectroscopy were utilized as complementary techniques to determine the oxygen content of EuO{sub 1{+-}x} thin films grown by molecular beam epitaxy with and without the employment of the so-called Eu distillation process. We found indications for phase separation to occur in Eu-rich as well as in over-oxidized EuO for films grown at substrate temperatures below the Eu distillation temperature. Only a fraction of the excess Eu contributes to the metal-insulator transition in Eu-rich films grown under these conditions. We also observed that the surfaces of these films were ill defined and may even contain more Eu excess than the film average. Only EuO films grown under distillation conditions are guaranteed to have the same magnetic and electrical properties as stoichiometric bulk EuO, and to have surfaces with the proper Eu/O stoichiometry and electronic structure.

  16. How regulators should use natural gas price forecasts

    SciTech Connect (OSTI)

    Costello, Ken

    2010-08-15T23:59:59.000Z

    Natural gas prices are critical to a range of regulatory decisions covering both electric and gas utilities. Natural gas prices are often a crucial variable in electric generation capacity planning and in the benefit-cost relationship for energy-efficiency programs. High natural gas prices can make coal generation the most economical new source, while low prices can make natural gas generation the most economical. (author)

  17. Power generation method including membrane separation

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A. (Union City, CA)

    2000-01-01T23:59:59.000Z

    A method for generating electric power, such as at, or close to, natural gas fields. The method includes conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas by means of a membrane separation step. This step creates a leaner, sweeter, drier gas, which is then used as combustion fuel to run a turbine, which is in turn used for power generation.

  18. Chena Hot Springs Resort - Electric Power Generation Using Geothermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hot Springs Resort - Electric Power Generation Using Geothermal Fluid Coproduced from Oil andor Gas Wells Chena Hot Springs Resort - Electric Power Generation Using Geothermal...

  19. REQUEST BY WESTINGHOUSE POWER GENERATION, A FORMER DIVISION OF...

    Broader source: Energy.gov (indexed) [DOE]

    selection and optimization to develop the next generation of gas-fired advanced turbine systems (ATS's) for green field and repowered electricity generation applications....

  20. Dealing with natural gas uncertainties

    SciTech Connect (OSTI)

    Clements, J.; Graeber, D. (J.R. Clements and Associates (US))

    1991-04-01T23:59:59.000Z

    The fuel of choice for generating new power is and will continue over the next two decades to be natural gas. It is the fuel of choice because it is plentiful, environmentally acceptable, and relatively inexpensive. This paper reports that gas reserves on the North American continent continue to be discovered in amounts that may keep the gas bubble inflated far longer than currently estimated. New gas transportation capacity is actively being developed to overcome the capacity bottlenecks and deliverability shortfalls. Natural gas prices will probably remain stable (with expected CPI-related increases) for the short run (2-4 years), and probably will be higher than CPI increases thereafter.

  1. Heat transfer and flow on the first-stage blade tip of a power generation gas turbine: Part 1 -- Experimental results

    SciTech Connect (OSTI)

    Bunker, R.S.; Bailey, J.C.; Ameri, A.A.

    2000-04-01T23:59:59.000Z

    A combined experimental and computational study has been performed to investigate the detailed distribution of convective heat transfer coefficients on the first-stage blade tip surface for a geometry typical of large power generation turbines (> 100 MW). This paper is concerned with the design and execution of the experimental portion of the study, which represents the first reported investigation to obtain nearly full surface information on heat transfer coefficients within an environment that develops an appropriate pressure distribution about an airfoil blade tip and shroud model. A stationary blade cascade experiment has been run consisting of three airfoils, the center airfoil having a variable tip gap clearance. The airfoil models the aerodynamic tip section of a high-pressure turbine blade with inlet Mach number of 0.30, exit Mach number of 0.75, pressure ratio of 1.45, exit Reynolds number based on axial chord of 2.57 x 10{sup 6}, and total turning of about 110 degrees. A hue detection based liquid crystal method is used to obtain the detailed heat transfer coefficient distribution on the blade tip surface for flat, smooth tip surfaces with both sharp and rounded edges. The cascade inlet turbulence intensity level took on values of either 5 or 9%. The cascade also models the casing recess in the shroud surface ahead of the blade. Experimental results are shown for the pressure distribution measurements on the airfoil near the tip gap, on the blade tip surface, and on the opposite shroud surface. Tip surface heat transfer coefficient distributions are shown for sharp edge and rounded edge tip geometries at each of the inlet turbulence intensity levels.

  2. A NEW GAS TURBINE ENGINE CONCEPT FOR ELECTRICITY

    E-Print Network [OSTI]

    A NEW GAS TURBINE ENGINE CONCEPT FOR ELECTRICITY GENERATION WITH INCREASED EFFICIENCY AND POWER REPORT (FAR) A NEW GAS TURBINE ENGINE CONCEPT FOR ELECTRICITY GENERATION WITH INCREASED EFFICIENCY://www.energy.ca.gov/research/index.html. #12;Page 1 A New Gas Turbine Engine Concept For Electricity Generation With Increased

  3. Power System Modeling of 20percent Wind-Generated Electricity by 2030

    E-Print Network [OSTI]

    Hand, Maureen

    2008-01-01T23:59:59.000Z

    of about 80 GW of coal-based generation technologyand reduces coal-based electricity generation by 18%.to offset coal- and natural gas-based electricity generation

  4. Gas concentration cells for utilizing energy

    DOE Patents [OSTI]

    Salomon, R.E.

    1987-06-30T23:59:59.000Z

    An apparatus and method are disclosed for utilizing energy, in which the apparatus may be used for generating electricity or as a heat pump. When used as an electrical generator, two gas concentration cells are connected in a closed gas circuit. The first gas concentration cell is heated and generates electricity. The second gas concentration cell repressurizes the gas which travels between the cells. The electrical energy which is generated by the first cell drives the second cell as well as an electrical load. When used as a heat pump, two gas concentration cells are connected in a closed gas circuit. The first cell is supplied with electrical energy from a direct current source and releases heat. The second cell absorbs heat. The apparatus has no moving parts and thus approximates a heat engine. 4 figs.

  5. Gas concentration cells for utilizing energy

    DOE Patents [OSTI]

    Salomon, Robert E. (Philadelphia, PA)

    1987-01-01T23:59:59.000Z

    An apparatus and method for utilizing energy, in which the apparatus may be used for generating electricity or as a heat pump. When used as an electrical generator, two gas concentration cells are connected in a closed gas circuit. The first gas concentration cell is heated and generates electricity. The second gas concentration cell repressurizes the gas which travels between the cells. The electrical energy which is generated by the first cell drives the second cell as well as an electrical load. When used as a heat pump, two gas concentration cells are connected in a closed gas circuit. The first cell is supplied with electrical energy from a direct current source and releases heat. The second cell absorbs heat. The apparatus has no moving parts and thus approximates a heat engine.

  6. Seeking the optimal LaTaO{sub 4}:Eu phosphor

    SciTech Connect (OSTI)

    Bleier, Grant C. [Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185 (United States); Nyman, May, E-mail: mdnyman@sandia.gov [Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185 (United States); Rohwer, Lauren E.S.; Rodriguez, Mark A. [Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185 (United States)

    2011-12-15T23:59:59.000Z

    Lanthanum orthotantalate, LaTaO{sub 4}, is an excellent host lattice for rare-earth luminescent ions such as Eu{sup 3+} for red emission. However, there are multiple RETaO{sub 4} (RE=rare earth) polymorphs, and the stability of these is controlled predominantly by the RE-radius. Thus it is difficult to obtain a pure phase of LaTaO{sub 4}:Eu as Eu concentration and consequently the RE radius is varied. We recently reported a 'soft-chemical' route that allows crystallization of pure-phase LaTaO{sub 4}:Eu at temperatures as low as 800 Degree-Sign C. In the current report, we investigate polymorph evolution and Eu emission as a function of Eu concentration and annealing temperature. We obtain a maximum quantum yield (QY) of 83% at the highest Eu substitution (25%) for which the low temperature orthorhombic (Pbca) polymorph is stable. Therefore, QY is not limited necessarily by concentration quenching; rather it is limited by polymorph stability as the RE-radius decreases with increasing Eu substitution. - Graphical Abstract: Eu-substituted lanthanum orthotantalates, LaTaO{sub 4}:Eu, are excellent red phosphors. They exhibit up to 83% quantum-yield emission under blue light excitation, optimized through both 'soft chemical processing' and polymorph purity. Highlights: Black-Right-Pointing-Pointer LaTaO{sub 4}:Eu phosphors were synthesized via 'soft-chemical' and solid-state routes. Black-Right-Pointing-Pointer Quantum-yield of Eu emission depends on host polymorph, which changes with La:Eu ratio. Black-Right-Pointing-Pointer Polymorph with optimal Eu-emission is only obtained by 'soft-chemistry'.

  7. EuTZn (T=Pd, Pt, Au) with TiNiSi-type structure-Magnetic properties and {sup 151}Eu Moessbauer spectroscopy

    SciTech Connect (OSTI)

    Mishra, Trinath; Hermes, Wilfried; Harmening, Thomas; Eul, Matthias [Institut fuer Anorganische und Analytische Chemie and NRW Graduate School of Chemistry, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Poettgen, Rainer, E-mail: pottgen@uni-muenster.d [Institut fuer Anorganische und Analytische Chemie and NRW Graduate School of Chemistry, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany)

    2009-09-15T23:59:59.000Z

    The europium compounds EuTZn (T=Pd, Pt, Au) were synthesized from the elements in sealed tantalum tubes in an induction furnace. These intermetallics crystallize with the orthorhombic TiNiSi-type structure, space group Pnma. The structures were investigated by X-ray diffraction on powders and single crystals: a=732.3(2), b=448.5(2), c=787.7(2) pm, R{sub 1}/wR{sub 2}=0.0400/0.0594, 565 F{sup 2} values for EuPdZn, a=727.8(3), b=443.7(1), c=781.7(3) pm, R{sub 1}/wR{sub 2}=0.0605/0.0866, 573 F{sup 2} values for EuPtZn, and a=747.4(2), b=465.8(2), c=789.1(4) pm, R{sub 1}/wR{sub 2}=0.0351/0.0590, 658 F{sup 2} values for EuAuZn, with 20 variables per refinement. Together the T and zinc atoms build up three-dimensional [TZn] networks with short T-Zn distances. The EuTZn compounds show Curie-Weiss behavior in the temperature range from 75 to 300 K with mu{sub eff}=7.97(1), 7.70(1), and 7.94(1) mu{sub B}/Eu atom and theta{sub P}=18.6(1), 34.9(1), and 55.5(1) K for T=Pd, Pt, and Au, respectively, indicating divalent europium. Antiferromagntic ordering was detected at 15.1(3) K for EuPdZn and canted ferromagnetic ordering at 21.2(3) and 51.1(3) K for EuPtZn and EuAuZn. {sup 151}Eu Moessbauer spectroscopic measurements confirm the divalent nature of the europium atoms by isomer shift values ranging from -8.22(8) (EuPtZn) to -9.23(2) mm/s (EuAuZn). At 4.2 K full magnetic hyperfine field splitting is observed in all three compounds due to magnetic ordering of the europium magnetic moments. - Graphical abstract: Europium coordination in EuPdZn, EuPtZn, and EuAuZn.

  8. Generation IV Nuclear Energy Systems ...

    E-Print Network [OSTI]

    Kemner, Ken

    of electricity and total emissions of carbon dioxide (CO2 )--a greenhouse gas. According to the U.S. Environmental Protection Agency, electricity generation currently produces about 40 percent of our CO2 emissions in per capita use of electricity and total emissions of carbon dioxide (CO2 )--a greenhouse gas

  9. Generating Resources Advisory Committee

    E-Print Network [OSTI]

    Generating Resources Advisory Committee February 27, 2014 Steven Simmons and Gillian Charles Upcoming Symposium 9:15 am Natural Gas Peaking Technologies Technology Trends Proposed reference plant Costing, Economies of Scale, Normalizations Reference Plants 12:30 pm Discussion of Next GRAC Meetings

  10. Waste Heat Recovery Power Generation with WOWGen

    E-Print Network [OSTI]

    Romero, M.

    applications of heat recovery power generation can be found in Industry (e.g. steel, glass, cement, lime, pulp and paper, refining and petrochemicals), Power Generation (CHP, biomass, biofuel, traditional fuels, gasifiers, diesel engines) and Natural Gas...

  11. Radioactive contamination of SrI2(Eu) crystal scintillator

    E-Print Network [OSTI]

    Belli, P; Cerulli, R; Danevich, F A; Galenin, E; Gektin, A; Incicchitti, A; Isaienko, V; Kobychev, V V; Laubenstein, M; Nagorny, S S; Podviyanuk, R B; Tkachenko, S; Tretyak, V I

    2011-01-01T23:59:59.000Z

    A strontium iodide crystal doped by europium (SrI2(Eu)) was produced by using the Stockbarger growth technique. The crystal was subjected to characterisation that included relative photoelectron output and energy resolution for gamma quanta. The intrinsic radioactivity of SrI2(Eu) crystal scintillator was tested both in scintillation mode and by using ultra-low background HPGe gamma spectrometry deep underground. The response of the SrI2(Eu) detector to alpha particles (alpha/beta ratio and pulse shape) was estimated by analysing the 226Ra trace contamination internal to the crystal. We have found alpha/beta=0.55 and no difference in scintillation decay for alpha particles and gamma quanta. The application of the obtained results in the search for the double electron capture and electron capture with positron emission in 84Sr has been investigated at a level of sensitivity T_1/2 \\sim 10^15-10^16 yr. The results of these studies demonstrate the potentiality of this material for a variety of scintillation appli...

  12. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel Morrison

    2005-09-14T23:59:59.000Z

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of April 1, 2005 through June 30, 2005. During this time period efforts were directed toward (1) GSTC administration changes, (2) participating in the American Gas Association Operations Conference and Biennial Exhibition, (3) issuing a Request for Proposals (RFP) for proposal solicitation for funding, and (4) organizing the proposal selection meeting.

  13. NuclearHydrogen Oil and gas

    E-Print Network [OSTI]

    Birmingham, University of

    Policy NuclearHydrogen Transport Education Oil and gas Distribution Society Supply Ecology Demand Hydrogen 08 Policy and society 10 Environment 11 Transport 12 Manufacturing 14 Oil and gas 15 Nuclear 16 and infrastructure, and broaden our methods of generation. Our declining reserves of oil and gas must be repla

  14. The potential for distributed generation in Japanese prototype buildings: A DER-CAM analysis of policy, tariff design, building energy use, and technology development (English Version)

    E-Print Network [OSTI]

    Zhou, Nan; Marnay, Chris; Firestone, Ryan; Gao, Weijun; Nishida, Masaru

    2004-01-01T23:59:59.000Z

    Industry, Japan MT microturbine NEGA Japan Engine GeneratorGE), gas turbine (GT), microturbine (MT), fuel cell (FC),Fuel Cell Gas Turbine Microturbine Natual Gas Reciprocating

  15. North American Natural Gas Markets

    SciTech Connect (OSTI)

    Not Available

    1989-02-01T23:59:59.000Z

    This report summarizes die research by an Energy Modeling Forum working group on the evolution of the North American natural gas markets between now and 2010. The group's findings are based partly on the results of a set of economic models of the natural gas industry that were run for four scenarios representing significantly different conditions: two oil price scenarios (upper and lower), a smaller total US resource base (low US resource case), and increased potential gas demand for electric generation (high US demand case). Several issues, such as the direction of regulatory policy and the size of the gas resource base, were analyzed separately without the use of models.

  16. North American Natural Gas Markets

    SciTech Connect (OSTI)

    Not Available

    1988-12-01T23:59:59.000Z

    This report sunnnarizes the research by an Energy Modeling Forum working group on the evolution of the North American natural gas markets between now and 2010. The group's findings are based partly on the results of a set of economic models of the natural gas industry that were run for four scenarios representing significantly different conditions: two oil price scenarios (upper and lower), a smaller total US resource base (low US resource case), and increased potential gas demand for electric generation (high US demand case). Several issues, such as the direction of regulatory policy and the size of the gas resource base, were analyzed separately without the use of models.

  17. International Natural Gas Prices for Electricity Generation ...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    - Gross Calorific Value2 Country 2001 2002 2003 2004 2005 2006 2007 2008 2009 Argentina NA NA NA NA NA NA NA NA NA Austria 368.5 379.3 590.6 686.2 729.6 785.0 936.5 1,024.3...

  18. International Natural Gas Prices for Electricity Generation ...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    323.8 NA NA NA NA NA Spain 176.0 165.5 204.0 215.6 254.2 354.9 380.3 486.6 433.8 390.4 Sweden NA NA NA NA NA NA 609.3 776.5 585.4 662.7 Switzerland 296.4 279.2 320.3 352.4 402.6...

  19. EU Framework 6 Project: Predictive Toxicology (PredTox)-overview and outcome

    SciTech Connect (OSTI)

    Suter, Laura, E-mail: Laura.suter-dick@roche.com [Hoffmann-La Roche AG, Basel (Switzerland); Schroeder, Susanne [Nycomed GmbH, Barsbuettel (Germany); Meyer, Kirstin [Bayer Schering Pharma AG, Berlin (Germany); Gautier, Jean-Charles [Sanofi aventis R and D, Disposition, Safety and Animal Research, Vitry sur Seine (France); Amberg, Alexander [Sanofi aventis R and D, Disposition, Safety and Animal Research, Frankfurt (Germany); Wendt, Maria; Gmuender, Hans [Genedata AG, Basel (Switzerland); Mally, Angela [University of Wuerzburg, Institut fuer Toxikologie, Wuerzburg (Germany); Boitier, Eric [Sanofi aventis R and D, Disposition, Safety and Animal Research, Vitry sur Seine (France); Ellinger-Ziegelbauer, Heidrun [Bayer Schering Pharma AG, Wuppertal (Germany); Matheis, Katja [Boehringer Ingelheim Pharma GmbH and Co. KG, Biberach (Germany); Pfannkuch, Friedlieb [Hoffmann-La Roche AG, Basel (Switzerland)

    2011-04-15T23:59:59.000Z

    In this publication, we report the outcome of the integrated EU Framework 6 Project: Predictive Toxicology (PredTox), including methodological aspects and overall conclusions. Specific details including data analysis and interpretation are reported in separate articles in this issue. The project, partly funded by the EU, was carried out by a consortium of 15 pharmaceutical companies, 2 SMEs, and 3 universities. The effects of 16 test compounds were characterized using conventional toxicological parameters and 'omics' technologies. The three major observed toxicities, liver hypertrophy, bile duct necrosis and/or cholestasis, and kidney proximal tubular damage were analyzed in detail. The combined approach of 'omics' and conventional toxicology proved a useful tool for mechanistic investigations and the identification of putative biomarkers. In our hands and in combination with histopathological assessment, target organ transcriptomics was the most prolific approach for the generation of mechanistic hypotheses. Proteomics approaches were relatively time-consuming and required careful standardization. NMR-based metabolomics detected metabolite changes accompanying histopathological findings, providing limited additional mechanistic information. Conversely, targeted metabolite profiling with LC/GC-MS was very useful for the investigation of bile duct necrosis/cholestasis. In general, both proteomics and metabolomics were supportive of other findings. Thus, the outcome of this program indicates that 'omics' technologies can help toxicologists to make better informed decisions during exploratory toxicological studies. The data support that hypothesis on mode of action and discovery of putative biomarkers are tangible outcomes of integrated 'omics' analysis. Qualification of biomarkers remains challenging, in particular in terms of identification, mechanistic anchoring, appropriate specificity, and sensitivity.

  20. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel L. Morrison; Sharon L. Elder

    2006-07-06T23:59:59.000Z

    Gas storage is a critical element in the natural gas industry. Producers, transmission & distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of April 1 to June 30, 2006. Key activities during this time period include: (1) Develop and process subcontract agreements for the eight projects selected for cofunding at the February 2006 GSTC Meeting; (2) Compiling and distributing the three 2004 project final reports to the GSTC Full members; (3) Develop template, compile listserv, and draft first GSTC Insider online newsletter; (4) Continue membership recruitment; (5) Identify projects and finalize agenda for the fall GSTC/AGA Underground Storage Committee Technology Transfer Workshop in San Francisco, CA; and (6) Identify projects and prepare draft agenda for the fall GSTC Technology Transfer Workshop in Pittsburgh, PA.

  1. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel L. Morrison; Sharon L. Elder

    2007-06-30T23:59:59.000Z

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is crucial in meeting the needs of these new markets. To address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance the operational flexibility and deliverability of the nation's gas storage system, and provide a cost-effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of April 1, 2007 through June 30, 2007. Key activities during this time period included: (1) Organizing and hosting the 2007 GSTC Spring Meeting; (2) Identifying the 2007 GSTC projects, issuing award or declination letters, and begin drafting subcontracts; (3) 2007 project mentoring teams identified; (4) New NETL Project Manager; (5) Preliminary planning for the 2007 GSTC Fall Meeting; (6) Collecting and compiling the 2005 GSTC project final reports; and (7) Outreach and communications.

  2. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel L. Morrison; Sharon L. Elder

    2006-05-10T23:59:59.000Z

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of January 1, 2006 through March 31, 2006. Activities during this time period were: (1) Organize and host the 2006 Spring Meeting in San Diego, CA on February 21-22, 2006; (2) Award 8 projects for co-funding by GSTC for 2006; (3) New members recruitment; and (4) Improving communications.

  3. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel L. Morrison; Sharon L. Elder

    2007-03-31T23:59:59.000Z

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is crucial in meeting the needs of these new markets. To address the gas storage needs of the natural gas industry, an industry-driven consortium was created - the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance the operational flexibility and deliverability of the nation's gas storage system, and provide a cost-effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of January1, 2007 through March 31, 2007. Key activities during this time period included: {lg_bullet} Drafting and distributing the 2007 RFP; {lg_bullet} Identifying and securing a meeting site for the GSTC 2007 Spring Proposal Meeting; {lg_bullet} Scheduling and participating in two (2) project mentoring conference calls; {lg_bullet} Conducting elections for four Executive Council seats; {lg_bullet} Collecting and compiling the 2005 GSTC Final Project Reports; and {lg_bullet} Outreach and communications.

  4. GASIFICATION FOR DISTRIBUTED GENERATION

    SciTech Connect (OSTI)

    Ronald C. Timpe; Michael D. Mann; Darren D. Schmidt

    2000-05-01T23:59:59.000Z

    A recent emphasis in gasification technology development has been directed toward reduced-scale gasifier systems for distributed generation at remote sites. The domestic distributed power generation market over the next decade is expected to be 5-6 gigawatts per year. The global increase is expected at 20 gigawatts over the next decade. The economics of gasification for distributed power generation are significantly improved when fuel transport is minimized. Until recently, gasification technology has been synonymous with coal conversion. Presently, however, interest centers on providing clean-burning fuel to remote sites that are not necessarily near coal supplies but have sufficient alternative carbonaceous material to feed a small gasifier. Gasifiers up to 50 MW are of current interest, with emphasis on those of 5-MW generating capacity. Internal combustion engines offer a more robust system for utilizing the fuel gas, while fuel cells and microturbines offer higher electric conversion efficiencies. The initial focus of this multiyear effort was on internal combustion engines and microturbines as more realistic near-term options for distributed generation. In this project, we studied emerging gasification technologies that can provide gas from regionally available feedstock as fuel to power generators under 30 MW in a distributed generation setting. Larger-scale gasification, primarily coal-fed, has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries. Commercial-scale gasification activities are under way at 113 sites in 22 countries in North and South America, Europe, Asia, Africa, and Australia, according to the Gasification Technologies Council. Gasification studies were carried out on alfalfa, black liquor (a high-sodium waste from the pulp industry), cow manure, and willow on the laboratory scale and on alfalfa, black liquor, and willow on the bench scale. Initial parametric tests evaluated through reactivity and product composition were carried out on thermogravimetric analysis (TGA) equipment. These tests were evaluated and then followed by bench-scale studies at 1123 K using an integrated bench-scale fluidized-bed gasifier (IBG) which can be operated in the semicontinuous batch mode. Products from tests were solid (ash), liquid (tar), and gas. Tar was separated on an open chromatographic column. Analysis of the gas product was carried out using on-line Fourier transform infrared spectroscopy (FT-IR). For selected tests, gas was collected periodically and analyzed using a refinery gas analyzer GC (gas chromatograph). The solid product was not extensively analyzed. This report is a part of a search into emerging gasification technologies that can provide power under 30 MW in a distributed generation setting. Larger-scale gasification has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries, and it is probable that scaled-down applications for use in remote areas will become viable. The appendix to this report contains a list, description, and sources of currently available gasification technologies that could be or are being commercially applied for distributed generation. This list was gathered from current sources and provides information about the supplier, the relative size range, and the status of the technology.

  5. Growth and characterization of Sc-doped EuO thin films

    SciTech Connect (OSTI)

    Altendorf, S. G.; Reisner, A.; Chang, C. F.; Hollmann, N.; Rata, A. D.; Tjeng, L. H. [Max Planck Institute for Chemical Physics of Solids, Nthnitzer Str. 40, 01187 Dresden (Germany)

    2014-02-03T23:59:59.000Z

    The preparation of 3d-transition metal-doped EuO thin films by molecular beam epitaxy is investigated using the example of Sc doping. The Sc-doped EuO samples display a good crystalline structure, despite the relatively small ionic radius of the dopant. The Sc doping leads to an enhancement of the Curie temperature to up to 125?K, remarkably similar to previous observations on lanthanide-doped EuO.

  6. Reliability Evaluation of Electric Power Generation Systems with Solar Power

    E-Print Network [OSTI]

    Samadi, Saeed

    2013-11-08T23:59:59.000Z

    Conventional power generators are fueled by natural gas, steam, or water flow. These generators can respond to fluctuating load by varying the fuel input that is done by a valve control. Renewable power generators such as wind or solar, however...

  7. Economics of natural gas upgrading

    SciTech Connect (OSTI)

    Hackworth, J.H.; Koch, R.W.

    1995-07-01T23:59:59.000Z

    Natural gas could be an important alternative energy source in meeting some of the market demand presently met by liquid products from crude oil. This study was initiated to analyze three energy markets to determine if greater use could be made of natural gas or natural gas derived products and if those products could be provided on an economically competitive basis. The three markets targeted for possible increases in gas use were motor fuels, power generation, and the chemical feedstocks market. The economics of processes to convert natural gas to transportation fuels, chemical products, and power were analyzed. The economic analysis was accomplished by drawing on a variety of detailed economic studies, updating them and bringing the results to a common basis. The processes analyzed included production of methanol, MTBE, higher alcohols, gasoline, CNG, and LNG for the transportation market. Production and use of methanol and ammonia in the chemical feedstock market and use of natural gas for power generation were also assessed. Use of both high and low quality gas as a process feed stream was evaluated. The analysis also explored the impact of various gas price growth rates and process facility locations, including remote gas areas. In assessing the transportation fuels market the analysis examined production and use of both conventional and new alternative motor fuels.

  8. Flammable gas project topical report

    SciTech Connect (OSTI)

    Johnson, G.D.

    1997-01-29T23:59:59.000Z

    The flammable gas safety issue was recognized in 1990 with the declaration of an unreviewed safety question (USQ) by the U. S. Department of Energy as a result of the behavior of the Hanford Site high-level waste tank 241-SY-101. This tank exhibited episodic releases of flammable gas that on a couple of occasions exceeded the lower flammability limit of hydrogen in air. Over the past six years there has been a considerable amount of knowledge gained about the chemical and physical processes that govern the behavior of tank 241-SY-1 01 and other tanks associated with the flammable gas safety issue. This report was prepared to provide an overview of that knowledge and to provide a description of the key information still needed to resolve the issue. Items covered by this report include summaries of the understanding of gas generation, retention and release mechanisms, the composition and flammability behavior of the gas mixture, the amounts of stored gas, and estimated gas release fractions for spontaneous releases. `Me report also discusses methods being developed for evaluating the 177 tanks at the Hanford Site and the problems associated with these methods. Means for measuring the gases emitted from the waste are described along with laboratory experiments designed to gain more information regarding rates of generation, species of gases emitted and modes of gas storage and release. Finally, the process for closing the USQ is outlined as are the information requirements to understand and resolve the flammable gas issue.

  9. Optical and structural stability of blue SrO:Eu{sup 2+} phosphor

    SciTech Connect (OSTI)

    Komatsu, Keiji, E-mail: Keiji_Komatsu@mst.nagaokaut.ac.jp [Department of Material Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188 (Japan); Nakamura, Atsushi [Department of Material Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188 (Japan); Chubu Chelest Co. Ltd., 3-3-3 Hinagahigashi, Yokkaichi, Mie 510-0886 (Japan); Ohshio, Shigeo; Toda, Ikumi; Muramatsu, Hiroyuki; Saitoh, Hidetoshi [Department of Material Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188 (Japan)

    2013-08-15T23:59:59.000Z

    Chemical stability of 6-coodinated SrO is a fundamental problem when this is used for various applications. In this study, optical and chemical stabilities of 8-coordinated SrO:Eu{sup 2+} phosphor were investigated. SrO:Eu{sup 2+} phosphor was synthesized from thermal treatment of SrO:Eu powder located on a single crystalline MgO at 1500 C under reduction atmosphere. Obtained 8-coordinated SrO:Eu{sup 2+} phosphor exhibit strong blue luminescence and chemical stability in distilled water for 3 days. Our findings prove that obtained 8-coordinated SrO:Eu{sup 2+} possesses relative optical and chemical stabilities in water. - Graphical abstract: Obtained 8-coordinated SrO:Eu{sup 2+} phosphor exhibit strong blue luminescence in distilled water. Highlights: We investigated optical and chemical stabilities of 8-coordinated SrO:Eu{sup 2+} phosphor in water. Obtained 8-coordinated SrO:Eu{sup 2+} phosphor exhibit strong blue luminescence and chemical stability in distilled water for 3 days. We found that the 8-coodrodinated SrO crystal structure changed to SrCO{sub 3} crystal structure after the 5 days immersion. The obtained SrO:Eu{sup 2+} phosphor possesses high chemical stability under water, compared with commercial (6-coordinated) SrO.

  10. A facile method for the preparation of Eu{sup 2+}-doped nanocrystalline BaFCl

    SciTech Connect (OSTI)

    Wang, Xianglei; Liu, Zhiqiang [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, UNSW Canberra (ADFA), Canberra, ACT 2600 (Australia); Stevens-Kalceff, Marion A. [School of Physics and Electron Microscope Unit, Mark Wainwright Analytical Centre, The University of New South Wales, Sydney, NSW 2052 (Australia); Riesen, Hans, E-mail: h.riesen@adfa.edu.au [School of Physical, Environmental and Mathematical Sciences, The University of New South Wales, UNSW Canberra (ADFA), Canberra, ACT 2600 (Australia)

    2013-10-15T23:59:59.000Z

    Graphical abstract: - Highlights: A facile co-precipitation method for the preparation of Eu{sup 2+}-doped BaFCl. Reduction of Eu{sup 3+} to Eu{sup 2+} by zinc granular under nitrogen flow. Photoluminescence and cathodoluminescence spectroscopy of the as-prepared BaFCl:Eu{sup 2+}. Temperature dependent photoluminescence properties of Eu{sup 2+} ions in BaFCl. - Abstract: A facile method for the preparation of Eu{sup 2+}-doped BaFCl is reported. The method is based on the co-precipitation of aqueous solutions of BaCl{sub 2} and NH{sub 4}F to yield BaFCl. The doping by europium in the 2+ oxidation state is realized by the reduction of Eu{sup 3+} to Eu{sup 2+} employing granular zinc in the BaCl{sub 2} solution under nitrogen. Powder X-ray diffraction and electron microscopy have been used to confirm the BaFCl phase and photoluminescence, in the temperature range of 2.5290 K, and room-temperature cathodoluminescence spectra have been measured to characterize the Eu{sup 2+} ions in the sample.

  11. Eu(III) Complexes of Octadentate 1-Hydroxy-2-pyridinones: Stability and Improved Photophysical Performance

    E-Print Network [OSTI]

    Moore, Evan G.

    2010-01-01T23:59:59.000Z

    1,2-HOPO) 2 ] ? , which lack a water molecule in the innerEu(III) complexes that lack a water molecule in their inner

  12. OUT OF EGYPT: Globalisation, marginalisation and illegal Muslim migration to the EU

    E-Print Network [OSTI]

    Talani, Leila Simona

    2005-01-01T23:59:59.000Z

    marginalisation and illegal Muslim migration to the EU: Drbased in Cairo working on illegal migration from the Middleunderstand the problem of illegal migration in the context

  13. AirShares EU Carbon Allowances Fund | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit withTianlinPapersWindeySanta2004) |Agawam,Ahmeek,Wisconsin: EnergyAirAirShares EU

  14. Model Catalysis of Ammonia Synthesis ad Iron-Water Interfaces - ASum Frequency Generation Vibrational Spectroscopic Study of Solid-GasInterfaces and Anion Photoelectron Spectroscopic Study of Selected Anionclusters

    SciTech Connect (OSTI)

    Ferguson, Michael James

    2005-12-15T23:59:59.000Z

    The ammonia synthesis reaction has been studied using single crystal model catalysis combined with sum frequency generation (SFG) vibrational spectroscopy. The adsorption of gases N{sub 2}, H{sub 2}, O{sub 2} and NH{sub 3} that play a role in ammonia synthesis have been studied on the Fe(111) crystal surface by sum frequency generation vibrational spectroscopy using an integrated Ultra-High Vacuum (UHV)/high-pressure system. SFG spectra are presented for the dissociation intermediates, NH{sub 2} ({approx}3325 cm{sup -1}) and NH ({approx}3235 cm{sup -1}) under high pressure of ammonia or equilibrium concentrations of reactants and products on Fe(111) surfaces. Special attention was paid to understand how potassium promotion of the iron catalyst affects the intermediates of ammonia synthesis. An Fe(111) surface promoted with 0.2 monolayers of potassium red shifts the vibrational frequencies of the reactive surface intermediates, NH and NH{sub 2}, providing evidence for weakened the nitrogen-hydrogen bonds relative to clean Fe(111). Spectral features of these surface intermediates persisted to higher temperatures for promoted iron surfaces than for clean Fe(111) surfaces implying that nitrogen-iron bonds are stronger for the promoted surface. The ratio of the NH to NH{sub 2} signal changed for promoted surfaces in the presence of equilibrium concentrations of reactants and products. The order of adding oxygen and potassium to promoted surfaces does not alter the spectra indicating that ammonia induces surface reconstruction of the catalyst to produce the same surface morphology. When oxygen is co-adsorbed with nitrogen, hydrogen, ammonia or potassium on Fe(111), a relative phase shift of the spectra occurs as compared to the presence of adsorbates on clean iron surfaces. Water adsorption on iron was also probed using SFG vibrational spectroscopy. For both H{sub 2}O and D{sub 2}O, the only spectral feature was in the range of the free OH or free OD. From the absence of SFG spectra of ice-like structure we conclude that surface hydroxides are formed and no liquid water is present on the surface. Other than model catalysis, gas phase anion photoelectron spectroscopy of the Cl + H{sub 2} van der Waals well, silicon clusters, germanium clusters, aluminum oxide clusters and indium phosphide clusters were studied. The spectra help to map out the neutral potential energy surfaces of the clusters. For aluminum oxide, the structures of the anions and neutrals were explored and for silicon, germanium and indium phosphide the electronic structure of larger clusters was mapped out.

  15. E-Print Network 3.0 - advanced flue gas Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    flue gas losses and minimized in... generated from flue gas condensation for district heating. Twence is another example, where a high degree... into a reusable ash and that...

  16. Settlement Prediction, Gas Modeling and Slope Stability Analysis

    E-Print Network [OSTI]

    Politcnica de Catalunya, Universitat

    Settlement Prediction, Gas Modeling and Slope Stability Analysis in Coll Cards Landfill Li Yu using mechanical models Simulation of gas generation, transport and extraction in MSW landfill 1 models Simulation of gas generation, transport and extraction in MSW landfill 1) Analytical solution

  17. Assessing the fuel Use and greenhouse gas emissions of future light-duty vehicles in Japan

    E-Print Network [OSTI]

    Nishimura, Eriko

    2011-01-01T23:59:59.000Z

    Reducing greenhouse gas (GHG) emissions is of great concern in Japan, as well as elsewhere, such as in the U.S. and EU. More than 20% of GHG emissions in Japan come from the transportation sector, and a more than 70% ...

  18. Gas-driven microturbine

    SciTech Connect (OSTI)

    Sniegowski, J.J.; Rodgers, M.S.; McWhorter, P.J.; Aeschliman, D.P.; Miller, W.M.

    1996-06-27T23:59:59.000Z

    This paper describes an invention which relates to microtechnology and the fabrication process for developing microelectrical systems. It describes a means for fabricating a gas-driven microturbine capable of providing autonomous propulsion in which the rapidly moving gases are directed through a micromachined turbine to power devices by direct linkage or turbo-electric generators components in a domain ranging from tenths of micrometers to thousands of micrometers.

  19. SrAgZn and EuAgZn with KHg{sub 2}-type structureStructure, magnetic properties, and {sup 151}Eu Mssbauer spectroscopy

    SciTech Connect (OSTI)

    Gerke, Birgit; Rodewald, Ute Ch.; Niehaus, Oliver; Pttgen, Rainer, E-mail: pottgen@uni-muenster.de

    2013-07-15T23:59:59.000Z

    Samples of SrAgZn and EuAgZn were synthesized by reaction of the elements in sealed tantalum crucibles. Both structures were refined on the basis of single crystal X-ray diffractometer data: KHg{sub 2}-type, Imma, a=476.7(1), b=780.9(2), c=810.1(2) pm, R{sub 1}/wR{sub 2}=0.0189/0.0119, 381 F values for SrAg{sub 1.12}Zn{sub 0.88} and a=474.43(9), b=760.8(2), c=799.0(2) pm, R{sub 1}/wR{sub 2}=0.0226/0.0483, 370 F values for EuAg{sub 1.17}Zn{sub 0.83} with 13 variables per refinement. Silver and zinc are randomly distributed on the Hg position and build up three-dimensional networks. EuAgZn shows ferromagnetic ordering at 29(1) K. In the temperature range from 75 to 300 K the sample shows CurieWeiss behaviour with ?{sub eff}=7.87(1) ?{sub B}/Eu atom and ?{sub P}=37.1(1) K, indicating divalent europium. {sup 151}Eu Mssbauer spectroscopic measurements confirmed the divalent state with an isomer shift of ?9.31 mm/s at 78 K. Temperature dependent {sup 151}Eu data show first magnetic hyperfine field splitting at 25 K and a saturated magnetization of 17 T at 5.2 K. The temperature dependence can be described by an S=7/2 Brillouin function. - Graphical abstract: The near neighbor coordination of the strontium and europium atoms in SrAg{sub 1.12}Zn{sub 0.88}, EuAg{sub 1.17}Zn{sub 0.83}, and EuAuZn. - Highlights: Synthesis of new intermetallic zinc compounds SrAgZn and EuAgZn. Ferromagnetic ordering of EuAgZn at 29 K. Magnetic hyperfine field splitting in the {sup 151}Eu Mssbauer spectrum.

  20. Cross Border Trading and Borrowing in the EU ETS A. Denny Ellerman* and Raphael Trotignon**

    E-Print Network [OSTI]

    multi- national trading system, the European Union's CO2 Emissions Trading Scheme (EU ETS) provides** This paper exploits a little used data resource within the central registry of the European Union's Emissions Trading System (EU ETS) to analyze cross border trading and inter-year borrowing during the first trading

  1. building science into EU policy The current status of biofuels in the

    E-Print Network [OSTI]

    easac building science into EU policy The current status of biofuels in the European Union the EASAC Secretariat at secretariat@easac.eu #12;The current status of biofuels in the European Union, their environmental impacts and future prospects easac #12;ii | December 2012 | Sustainable Biofuels EASAC ISBN 978

  2. Price relationships in the EU emissions trading system Julien Chevallier1

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    1 Price relationships in the EU emissions trading system Julien Chevallier1 Universit Paris Dauphine Abstract The Emissions Trading Scheme (ETS) constrains industrial polluters to buy/sell CO2 the price relationships in the EU emissions trading system. The United Nations Framework Convention

  3. A bottom-up analysis of including aviation within theEU's Emissions Trading Scheme

    E-Print Network [OSTI]

    Watson, Andrew

    A bottom-up analysis of including aviation within theEU's Emissions Trading Scheme Alice Bows-up analysis of including aviation within the EU's Emissions Trading Scheme Alice Bows & Kevin Anderson Tyndall's emissions trading scheme. Results indicate that unless the scheme adopts both an early baseline year

  4. Detailed search S&T key figures reveal China breathing down EU's neck

    E-Print Network [OSTI]

    , revealing stagnation in research and development (R&D) investment in the EU, which Science and Research in the proportion of GDP that it spends on research) was around 0.7 per cent between 2000 and 2003. 'If this trend at the Barcelona European Council to raise R&D spending to 3 per cent of EU GDP by 2010. Yet according

  5. Ris DTU Dec.3 2009WindScanner.eu 1 Ris DTU, Technical University of Denmark

    E-Print Network [OSTI]

    % to the average Danish electricity consumption · Today DK is leading worldwide regarding research and development market · By year 2020 EU's goal is to cover ~20% of the Unions electricity consumption via sustainable of wind power technology · EU Governments wish to maintain the lead Internationally on the wind power

  6. THE EU-AFRICA ENERGY COOPERATION: CHALLENGES AND OPPORTUNITIES FOR PUBLIC AND PRIVATE BUSINESSES

    E-Print Network [OSTI]

    Boyer, Edmond

    multilateral and bilateral energy relationships with Africa. There are three EU-Africa energy initiativesTHE EU-AFRICA ENERGY COOPERATION: CHALLENGES AND OPPORTUNITIES FOR PUBLIC AND PRIVATE BUSINESSESD Candidate Energy security, sustainable development and mutual benefits are the three keywords

  7. CARBON LEAKAGE AND CAPACITY-BASED ALLOCATIONS. IS THE EU RIGHT?

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    , California, China, India, New Zealand...). The EU implemented its ETS in 2005 and has signicantly revised Organization (Wooders and Cosbey, 2010). The main approach to circumvent this political constraint relies in Australia if the new majority does not repeal the Clean Energy Future legislation). The EU has followed

  8. Volume 1, Issue 2 2009 Article 5 Effectiveness of Poverty Reduction in the EU: A Descriptive

    E-Print Network [OSTI]

    Galis, Frietson

    Volume 1, Issue 2 2009 Article 5 Effectiveness of Poverty Reduction in the EU: A Descriptive Organization Caminada, Koen and Goudswaard, Kees (2009) "Effectiveness of Poverty Reduction in the EU: A Descriptive Analysis," Poverty & Public Policy: Vol. 1: Iss. 2, Article 5. Available at: http

  9. Carbon leakage and competitiveness of cement and steel industries under the EU

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    No 53-2013 Carbon leakage and competitiveness of cement and steel industries under the EU ETS: much2014 #12;Carbon leakage and competitiveness of cement and steel industries under the EU ETS: much ado about nothing Abstract In a world of uneven climate policies, concerns about carbon leakage

  10. Growth and optical properties of partially transparent Eu doped CaF{sub 2} ceramic

    SciTech Connect (OSTI)

    Ghosh, Manoranjan, E-mail: mghosh@barc.gov.in; Sen, Shashwati, E-mail: mghosh@barc.gov.in; Pitale, S. S., E-mail: mghosh@barc.gov.in; Goutam, U. K., E-mail: mghosh@barc.gov.in; Shinde, Seema, E-mail: mghosh@barc.gov.in; Patra, G. D., E-mail: mghosh@barc.gov.in; Gadkari, S. C., E-mail: mghosh@barc.gov.in [Technical Physics Division, Bhabha Atomic Research Centre, Mumbai - 400085 (India)

    2014-04-24T23:59:59.000Z

    Partially transparent ceramic of 2 at.% Eu doped CaF{sub 2} have been grown preferentially towards [111] direction. For this purpose, Eu doped CaF{sub 2} nanoparticles (size?12 nm) obtained by a low temperature solution growth method has been pressed at 1000C under vacuum. The preferentially grown ceramic shows 15% transparency within the visible range of spectrum. As confirmed by the X-ray diffraction result, the hot pressed ceramic exhibits reduced lattice volume than the nanopowder. It indicates Eu{sup 3+} as the dominant substituting ions at the Ca{sup 2+} sites of CaF{sub 2} lattice in the hot pressed ceramic material. It is corroborated by the photoluminescence results of hot pressed ceramic which shows strong red emission corresponding to Eu{sup 3+} sites. However, photoluminescence of nanopowder exhibits intense peak in the blue region of the spectrum which is characteristics of Eu2+ sites.

  11. Multi-level governance revisited: comparing the strategies of interest representation of legislative regions in EU environmental policy- making.

    E-Print Network [OSTI]

    Hgenauer, Anna-Lena

    2011-07-04T23:59:59.000Z

    Since the 1980s, regions have taken a strong interest in EU policy-making and increasingly demanded representation in the process. This has given rise to the concept of multi-level governance (MLG) in EU policy-making, ...

  12. Trinity Gas to explore for gas in Colombia

    SciTech Connect (OSTI)

    NONE

    1997-07-01T23:59:59.000Z

    Trinity Gas Corp. officials signed an agreement on May 20, 1997, with the Cauca Valley Corp. (CVC) allowing Trinity to use CVC data to explore for natural gas in the Cauca Valley of Colombia. CVC, Colombia`s Valle del Cauca water resources and environmental division, is evaluating Colombia`s underground water reserves to protect, control and preserve fresh water aquifers, some of which contain natural gas pockets that cause blowouts in farmers` water wells. Preparations now are underway for drilling Trinity`s first well at the Palmira 1 site on the San Jose Hacienda, the largest privately owned sugar cane plantation in the valley. Trinity also entered into an agreement with the Cauca Valley Natural Gas and Electricity Project to furnish natural gas, generated electricity and energy fuel for the industrial district in the region. According to this contract, many valley residents will have electric service for the first time.

  13. Gas Storage Technology Consortium

    SciTech Connect (OSTI)

    Joel L. Morrison; Sharon L. Elder

    2006-09-30T23:59:59.000Z

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created-the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. This report addresses the activities for the quarterly period of July 1, 2006 to September 30, 2006. Key activities during this time period include: {lg_bullet} Subaward contracts for all 2006 GSTC projects completed; {lg_bullet} Implement a formal project mentoring process by a mentor team; {lg_bullet} Upcoming Technology Transfer meetings: {sm_bullet} Finalize agenda for the American Gas Association Fall Underground Storage Committee/GSTC Technology Transfer Meeting in San Francisco, CA. on October 4, 2006; {sm_bullet} Identify projects and finalize agenda for the Fall GSTC Technology Transfer Meeting, Pittsburgh, PA on November 8, 2006; {lg_bullet} Draft and compile an electronic newsletter, the GSTC Insider; and {lg_bullet} New members update.

  14. GAS STORAGE TECHNOLOGY CONSORTIUM

    SciTech Connect (OSTI)

    Robert W. Watson

    2004-04-17T23:59:59.000Z

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. To accomplish this objective, the project is divided into three phases that are managed and directed by the GSTC Coordinator. Base funding for the consortium is provided by the U.S. Department of Energy (DOE). In addition, funding is anticipated from the Gas Technology Institute (GTI). The first phase, Phase 1A, was initiated on September 30, 2003, and is scheduled for completion on March 31, 2004. Phase 1A of the project includes the creation of the GSTC structure, development of constitution (by-laws) for the consortium, and development and refinement of a technical approach (work plan) for deliverability enhancement and reservoir management. This report deals with the second 3-months of the project and encompasses the period December 31, 2003, through March 31, 2003. During this 3-month, the dialogue of individuals representing the storage industry, universities and the Department of energy was continued and resulted in a constitution for the operation of the consortium and a draft of the initial Request for Proposals (RFP).

  15. GAS STORAGE TECHNOLOGY CONSORTIUM

    SciTech Connect (OSTI)

    Robert W. Watson

    2004-07-15T23:59:59.000Z

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. To accomplish this objective, the project is divided into three phases that are managed and directed by the GSTC Coordinator. Base funding for the consortium is provided by the U.S. Department of Energy (DOE). In addition, funding is anticipated from the Gas Technology Institute (GTI). The first phase, Phase 1A, was initiated on September 30, 2003, and was completed on March 31, 2004. Phase 1A of the project included the creation of the GSTC structure, development and refinement of a technical approach (work plan) for deliverability enhancement and reservoir management. This report deals with Phase 1B and encompasses the period April 1, 2004, through June 30, 2004. During this 3-month period, a Request for Proposals (RFP) was made. A total of 17 proposals were submitted to the GSTC. A proposal selection meeting was held June 9-10, 2004 in Morgantown, West Virginia. Of the 17 proposals, 6 were selected for funding.

  16. Gas permeable electrode for electrochemical system

    DOE Patents [OSTI]

    Ludwig, Frank A. (Rancho Palos Verdes, CA); Townsend, Carl W. (Los Angeles, CA)

    1989-01-01T23:59:59.000Z

    An electrode apparatus adapted for use in electrochemical systems having an anode compartment and a cathode compartment in which gas and ions are produced and consumed in the compartments during generation of electrical current. The electrode apparatus includes a membrane for separating the anode compartment from the cathode compartment wherein the membrane is permeable to both ions and gas. The cathode and anode for the assembly are provided on opposite sides of the membrane. During use of the membrane-electrode apparatus in electrochemical cells, the gas and ions generated at the cathode or anode migrate through the membrane to provide efficient transfer of gas and ions between the anode and cathode compartments.

  17. The Role of Domestic Factors in the Formation of Trade Unions: A Look at Turkey/EU Relations

    E-Print Network [OSTI]

    Youngblood, Kristina Lynne

    2008-08-19T23:59:59.000Z

    studied Turkey and the European Union (EU). Turkey was officially admitted as a candidate country to the EU in 1997. Despite efforts to meet EU demands, Turkeys admittance has been blocked. As recently as 2007 Turkey was denied membership, while...

  18. EU could go it alone on nuclear fusion plant 29.11.2004 -10:02 CET | By Richard Carter

    E-Print Network [OSTI]

    EU could go it alone on nuclear fusion plant 29.11.2004 - 10:02 CET | By Richard Carter The EU if no agreement can be reached with Japan by the end of the year over where to build the plant, according to EU research ministers. Talks over the world's first nuclear fusion reactor have stalled because Japan

  19. Methodology for flammable gas evaluations

    SciTech Connect (OSTI)

    Hopkins, J.D., Westinghouse Hanford

    1996-06-12T23:59:59.000Z

    There are 177 radioactive waste storage tanks at the Hanford Site. The waste generates flammable gases. The waste releases gas continuously, but in some tanks the waste has shown a tendency to trap these flammable gases. When enough gas is trapped in a tank`s waste matrix, it may be released in a way that renders part or all of the tank atmosphere flammable for a period of time. Tanks must be evaluated against previously defined criteria to determine whether they can present a flammable gas hazard. This document presents the methodology for evaluating tanks in two areas of concern in the tank headspace:steady-state flammable-gas concentration resulting from continuous release, and concentration resulting from an episodic gas release.

  20. COAL CLEANING BY GAS AGGLOMERATION

    SciTech Connect (OSTI)

    MEIYU SHEN; ROYCE ABBOTT; T.D. WHEELOCK

    1998-09-30T23:59:59.000Z

    The agglomeration of ultrafine-size coal particles in an aqueous suspension by means of microscopic gas bubbles was demonstrated in numerous experiments with a scale model mixing system. Coal samples from both the Pittsburgh No. 8 Seam and the Upper Freeport Seam were used for these experiments. A small amount of i-octane was added to facilitate the process. Microscopic gas bubbles were generated by saturating the water used for suspending coal particles with gas under pressure and then reducing the pressure. Microagglomerates were produced which appeared to consist of gas bubbles encapsulated in coal particles. Since dilute particle suspensions were employed, it was possible to monitor the progress of agglomeration by observing changes in turbidity. By such means it became apparent that the rate of agglomeration depends on the concentration of microscopic gas bubbles and to a lesser extent on the concentration of i-octane. Similar results were obtained with both Pittsburgh No. 8 coal and Upper Freeport coal.

  1. Demonstration of a Low-NOx Heavy-Duty Natural Gas Engine

    SciTech Connect (OSTI)

    Not Available

    2004-02-01T23:59:59.000Z

    Results of a Next Generation Natural Gas Vehicle engine research project: A Caterpillar C-12 natural gas engine with Clean Air Power Dual-Fuel technology and exhaust gas recirculation demonstrated low NOx and PM emissions.

  2. Case Study of Optimal Byproduct Gas Distribution in Integrated Steel Mill Using Multi-Period Optimization

    E-Print Network [OSTI]

    Makinen, K.; Kymalainen, T.; Junttila, J.

    2012-01-01T23:59:59.000Z

    byproduct gases at varying rates. The differences between gas generation and consumption rates are compensated with gas holders. However, under certain circumstances the imbalances can lead to the flaring of excessive gas or require the purchase...

  3. Stability of natural gas in the deep subsurface

    SciTech Connect (OSTI)

    Barker, C.

    1996-07-01T23:59:59.000Z

    Natural gas is becoming increasingly important as a fuel because of its widespread occurrence and because it has a less significant environmental impact than oil. Many of the known gas accumulations were discovered by accident during exploration for oil, but with increasing demand for gas, successful exploration will require a clearer understanding of the factors that control gas distribution and gas composition. Natural gas is generated by three main processes. In oxygen-deficient, sulfate-free, shallow (few thousand feet) environments bacteria generate biogenic gas that is essentially pure methane with no higher hydrocarbons ({open_quotes}dry gas{close_quotes}). Gas is also formed from organic matter ({open_quotes}kerogen{close_quotes}), either as the initial product from the thermal breakdown of Type III, woody kerogens, or as the final hydrocarbon product from all kerogen types. In addition, gas can be formed by the thermal cracking of crude oil in the deep subsurface. The generation of gas from kerogen requires higher temperatures than the generation of oil. Also, the cracking of oil to gas requires high temperatures, so that there is a general trend from oil to gas with increasing depth. This produces a well-defined {open_quotes}floor for oil{close_quotes}, below which crude oil is not thermally stable. The possibility of a {open_quotes}floor for gas{close_quotes} is less well documented and understanding the limits on natural gas occurrence was one of the main objectives of this research.

  4. Short rise time intense electron beam generator

    DOE Patents [OSTI]

    Olson, Craig L. (Albuquerque, NM)

    1987-01-01T23:59:59.000Z

    A generator for producing an intense relativistic electron beam having a subnanosecond current rise time includes a conventional generator of intense relativistic electrons feeding into a short electrically conductive drift tube including a cavity containing a working gas at a low enough pressure to prevent the input beam from significantly ionizing the working gas. Ionizing means such as a laser simultaneously ionize the entire volume of working gas in the cavity to generate an output beam having a rise time less than one nanosecond.

  5. Short rise time intense electron beam generator

    DOE Patents [OSTI]

    Olson, C.L.

    1984-03-16T23:59:59.000Z

    A generator for producing an intense relativisitc electron beam having a subnanosecond current rise time includes a conventional generator of intense relativistic electrons feeding into a short electrically conductive drift tube including a cavity containing a working gas at a low enough pressure to prevent the input beam from significantly ionizing the working gas. Ionizing means such as a laser simultaneously ionize the entire volume of working gas in the cavity to generate an output beam having a rise time less than one nanosecond.

  6. Cost Curves for Gas Supply Security: The Case of Bulgaria

    E-Print Network [OSTI]

    Silve, Florent; Nol, Pierre

    . Interconnections: 8.64 7.92 14 - 5 Figure 2. Structure of gas consumption by sector, Bulgaria (2007) Figure 3. Structure of heat generation by fuel type, Bulgaria (2007) Figure 4. Electricity generation mix, Bulgaria (2007) Chemical industry 31... to put the vertical dotted line). The government may want to insure the gas consumption of some specific categories of customers, the interruption of which Cost per unit of peak gas consumption insured (m/mcm/day) Cumulative level of peak gas...

  7. 3rd Generation SCR System Using Solid Ammonia Storage and Direct...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing 3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing SCR system provides direct...

  8. Preparation of blue-emitting CaMgSi{sub 2}O{sub 6}:Eu{sup 2+} phosphors in reverse micellar system and their application to transparent emissive display devices

    SciTech Connect (OSTI)

    Choi, Sungho, E-mail: shochoi@krict.re.kr [Device Materials Research Center, Korea Research Institute of Chemical Technology, P.O. Box 107, Yuseong, Daejeon 305-600 (Korea, Republic of); Tae, Se-Won [Seoul Semiconductor, Wonsi-dong, Danwon-gu, Ansan-city, Gyeonggi-do (Korea, Republic of); Seo, Jung-Hyun [Device Materials Research Center, Korea Research Institute of Chemical Technology, P.O. Box 107, Yuseong, Daejeon 305-600 (Korea, Republic of); Department of Materials Science and Engineering, Korea University, Anam-dong, Seoul (Korea, Republic of); Jung, Ha-Kyun [Device Materials Research Center, Korea Research Institute of Chemical Technology, P.O. Box 107, Yuseong, Daejeon 305-600 (Korea, Republic of)

    2011-06-15T23:59:59.000Z

    Blue-emitting Eu{sup 2+}-doped CaMgSi{sub 2}O{sub 6} phosphors were prepared by the reverse micelle method. The resultant particles were nanocrystalline with a grain size of about <300 nm and exhibited a characteristic blue emission spectrum centered at 445 nm induced by the oxygen coordinated Eu{sup 2+} ions. By using the corresponding nanophosphors followed by the formation of a uniform phosphor layer, we have demonstrated the mini-sized transparent plasma-discharge panels and investigated their luminance characteristics. Phosphor coated panel is properly transparent, {>=}65%, at the visible wavelength region and illuminates a characteristic blue emission under Ne/Xe plasma discharge conditions. Thus, we can obtain a fast decaying, robust blue-emitting silicate phosphor layer under excited plasma radiation for upcoming emissive display devices like as transparent and three-dimensional plasma display panels. - Graphical abstract: Blue-emitting CaMgSi{sub 2}O{sub 6}:Eu{sup 2+} nanophosphors coated transparent luminescent layers can be obtained. It illuminates the characteristic blue emission, spectrum centered at 425 nm wavelength, under the Ne-Xe mixed gas plasma discharge condition. Highlights: > Blue-emitting CaMgSi{sub 2}O{sub 6}:Eu{sup 2+} nanophosphors via reverse micelle method. > Transparent blue-emitting layer was prepared by using corresponding phosphors. > Fast decaying with degradation-free luminescent layer under plasma radiation. > Promising luminescent layer for the upcoming plasma discharged transparent displays.

  9. System and method for detecting gas

    DOE Patents [OSTI]

    Chow, Oscar Ken (Simsbury, CT); Moulthrop, Lawrence Clinton (Windsor, CT); Dreier, Ken Wayne (Madison, CT); Miller, Jacob Andrew (Dexter, MI)

    2010-03-16T23:59:59.000Z

    A system to detect a presence of a specific gas in a mixture of gaseous byproducts comprising moisture vapor is disclosed. The system includes an electrochemical cell, a transport to deliver the mixture of gaseous byproducts from the electrochemical cell, a gas sensor in fluid communication with the transport, the sensor responsive to a presence of the specific gas to generate a signal corresponding to a concentration of the specific gas, and a membrane to prevent transmission of liquid moisture, the membrane disposed between the transport and the gas sensor.

  10. Template synthesis and luminescence properties of TiO{sub 2}:Eu{sup 3+} nanotubes

    SciTech Connect (OSTI)

    Zhao, Huan; Zheng, Keyan; Sheng, Ye; Li, Hongbo; Zhang, Hongguang; Qi, Xiaofei [College of Chemistry, Jilin University, Changchun 130012 (China); Shi, Zhan [State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012 (China); Zou, Haifeng, E-mail: zouhf@jlu.edu.cn [College of Chemistry, Jilin University, Changchun 130012 (China)

    2014-02-15T23:59:59.000Z

    Uniform TiO{sub 2}:Eu{sup 3+} nanotubes have been successfully synthesized through a simple solvothermal process with carbon nanotubes (CNTs) as templates, free of any surfactant or catalyst. X-ray diffraction (XRD) results demonstrate that the product is a pure anatase phase of TiO{sub 2}. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images indicate that the as-obtained TiO{sub 2}:Eu{sup 3+} nanotubes are uniform in size and distribution, and the thickness of the wall is about 8 nm. The possible formation mechanism has also been proposed. The luminescent spectrum shows that TiO{sub 2}:Eu{sup 3+} nanotubes exhibit a red emission at 612 nm due to the {sup 5}D{sub 0}?{sup 7}F{sub 2} transition. Furthermore, this synthetic route is promising for the preparation of other one-dimensional inorganic nanomaterials because of its simplicity and the low cost of the starting reagents. - Graphical abstract: This picture is the illustration for the formation process of TiO{sub 2}:Eu{sup 3+} nanotubes. Display Omitted - Highlights: TiO{sub 2}:Eu{sup 3+} nanotubes have been prepared through a simple solvothermal process. The TiO{sub 2}:Eu{sup 3+} nanotubes are uniform in size and distribution. Under UV light excitation, the TiO{sub 2}:Eu{sup 3+} nanotubes show strong red emission.

  11. GAS STORAGE TECHNOLOGY CONSORTIUM

    SciTech Connect (OSTI)

    Robert W. Watson

    2004-10-18T23:59:59.000Z

    Gas storage is a critical element in the natural gas industry. Producers, transmission and distribution companies, marketers, and end users all benefit directly from the load balancing function of storage. The unbundling process has fundamentally changed the way storage is used and valued. As an unbundled service, the value of storage is being recovered at rates that reflect its value. Moreover, the marketplace has differentiated between various types of storage services, and has increasingly rewarded flexibility, safety, and reliability. The size of the natural gas market has increased and is projected to continue to increase towards 30 trillion cubic feet (TCF) over the next 10 to 15 years. Much of this increase is projected to come from electric generation, particularly peaking units. Gas storage, particularly the flexible services that are most suited to electric loads, is critical in meeting the needs of these new markets. In order to address the gas storage needs of the natural gas industry, an industry-driven consortium was created--the Gas Storage Technology Consortium (GSTC). The objective of the GSTC is to provide a means to accomplish industry-driven research and development designed to enhance operational flexibility and deliverability of the Nation's gas storage system, and provide a cost effective, safe, and reliable supply of natural gas to meet domestic demand. To accomplish this objective, the project is divided into three phases that are managed and directed by the GSTC Coordinator. The first phase, Phase 1A, was initiated on September 30, 2003, and was completed on March 31, 2004. Phase 1A of the project included the creation of the GSTC structure, development and refinement of a technical approach (work plan) for deliverability enhancement and reservoir management. This report deals with Phase 1B and encompasses the period July 1, 2004, through September 30, 2004. During this time period there were three main activities. First was the ongoing negotiations of the four sub-awards working toward signed contracts with the various organizations involved. Second, an Executive Council meeting was held at Penn State September 9, 2004. And third, the GSTC participated in the SPE Eastern Regional Meeting in Charleston, West Virginia, on September 16th and 17th. We hosted a display booth with the Stripper Well Consortium.

  12. Thermoelectric generator cooling system and method of control

    DOE Patents [OSTI]

    Prior, Gregory P; Meisner, Gregory P; Glassford, Daniel B

    2012-10-16T23:59:59.000Z

    An apparatus is provided that includes a thermoelectric generator and an exhaust gas system operatively connected to the thermoelectric generator to heat a portion of the thermoelectric generator with exhaust gas flow through the thermoelectric generator. A coolant system is operatively connected to the thermoelectric generator to cool another portion of the thermoelectric generator with coolant flow through the thermoelectric generator. At least one valve is controllable to cause the coolant flow through the thermoelectric generator in a direction that opposes a direction of the exhaust gas flow under a first set of operating conditions and to cause the coolant flow through the thermoelectric generator in the direction of exhaust gas flow under a second set of operating conditions.

  13. Preliminary Estimates of Combined Heat and Power Greenhouse Gas Abatement Potential for California in 2020

    E-Print Network [OSTI]

    Firestone, Ryan; Ling, Frank; Marnay, Chris; Hamachi LaCommare, Kristina

    2007-01-01T23:59:59.000Z

    generation: 50% of electricity from central grid natural gas plantsgeneration: 100% of electricity from central grid natural gas plantselectricity comes from central station natural-gas- fired combined cycle generation, and the other half comes from natural-gas-fired single cycle plants.

  14. September 2013 Most Viewed Documents for Power Generation And...

    Office of Scientific and Technical Information (OSTI)

    Gas Turbine Exhaust Diffuser Norris, Thomas R. (2009) 23 > Dynamic performance and control of a static var generator using cascade multilevel inverters Peng, Fang Zheng...

  15. Bush Administration Moves Forward to Develop Next Generation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    identified six next generation technologies for development including: the Gas Cooled Fast Reactor; the Sodium Fast Reactor; the Lead-Cooled Fast Reactor; the Molten Salt...

  16. Poland - Economic and Financial Benefits of Distributed Generation...

    Open Energy Info (EERE)

    of Distributed Generation Small-Scale, Gas-Fired CHP AgencyCompany Organization Argonne National Laboratory Sector Energy Topics Background analysis Website http:...

  17. Preparation and fluorescence property of red-emitting Eu{sup 3+}-activated amorphous calcium silicate phosphor

    SciTech Connect (OSTI)

    Kojima, Yoshiyuki, E-mail: ykojima@chem.cst.nihon-u.ac.jp [Department of Materials and Applied Chemistry, Faculty of Science and Technology, Nihon University, Tokyo 101-8308 (Japan)] [Department of Materials and Applied Chemistry, Faculty of Science and Technology, Nihon University, Tokyo 101-8308 (Japan); Kamei, Shinnosuke; Nishimiya, Nobuyuki [Department of Materials and Applied Chemistry, Faculty of Science and Technology, Nihon University, Tokyo 101-8308 (Japan)] [Department of Materials and Applied Chemistry, Faculty of Science and Technology, Nihon University, Tokyo 101-8308 (Japan)

    2010-02-15T23:59:59.000Z

    This paper describes the energy efficient synthesis of a red-emitting Eu{sup 3+}-activated amorphous calcium silicate phosphor produced by heating a Eu{sup 3+}-activated calcium silicate hydrate phosphor. Concentration quenching of the Eu{sup 3+}-activated calcium silicate hydrate phosphor was not observed and the emission intensity did not decrease up to a Eu/(Ca+Eu) atomic ratio of 0.46. Heating of the Eu{sup 3+}-activated calcium silicate hydrate (Eu/(Ca+Eu) atomic ratio = 0.32) phosphor produced an amorphous Eu{sup 3+}-activated calcium silicate phosphor, which had a maximum emission intensity at 870 {sup o}C and emitted in the red under near-ultraviolet irradiation (395 nm). The emission intensity of the Eu{sup 3+}-activated amorphous calcium silicate phosphor was about half that of a commercial BaMgAl{sub 10}O{sub 17}:Eu{sup 2+} phosphor, and shows great potential for application in white light-emitting diodes.

  18. Synthesis and determination of the structural and optical characteristics of cBN micropowder with Eu{sup 3+} ions

    SciTech Connect (OSTI)

    Leonchik, S. V., E-mail: Leonchik@physics.by; Karotki, A. V. [National Academy of Sciences of Belarus, Scientific-Practical Materials Research Center (Belarus)] [National Academy of Sciences of Belarus, Scientific-Practical Materials Research Center (Belarus)

    2013-10-15T23:59:59.000Z

    Cubic boron-nitride micropowder with Eu{sup 3+} ions (cBN:Eu) is synthesized under conditions of high pressures and temperatures. The structural, morphological, chemical, and optical characteristics of the cBN:Eu micropowder are studied using X-ray diffraction, energy-dispersive X-ray spectral microanalysis, photoluminescence, and optical transmission methods. It is found that the cBN:Eu lattice parameter is {approx}3.615 A. The intense red luminescence of the cBN:Eu micropowder (red glow), measured in the visible region of the spectrum in the range from 550 to 750 nm, is attributed to intracenter 4f-electron transitions of the Eu{sup 3+} ions. The possible nature of the cBN:Eu micropowder luminescence is discussed.

  19. Saudi Aramco Gas Operations Energy Efficiency Program

    E-Print Network [OSTI]

    Al-Dossary, F. S.

    2012-01-01T23:59:59.000Z

    Saudi Aramco Gas Operations (GO) created energy efficiency strategies for its 5-year business plan (2011-2015), supported by a unique energy efficiency program, to reduce GO energy intensity by 26% by 2015. The program generated an energy savings...

  20. Saudi Aramco Gas Operations Energy Efficiency Program

    E-Print Network [OSTI]

    Al-Dossary, F. S.

    2012-01-01T23:59:59.000Z

    Saudi Aramco Gas Operations (GO) created energy efficiency strategies for its 5-year business plan (2011-2015), supported by a unique energy efficiency program, to reduce GO energy intensity by 26% by 2015. The program generated an energy savings...

  1. Hardware model of a shipboard generator

    E-Print Network [OSTI]

    Elkins, Gregory L. (Gregory Lewis)

    2009-01-01T23:59:59.000Z

    A hardware model of the Gas Turbine Generator (GTG) in use on the US Navy's DDG-51 Class Destroyer is constructed for use as a lab apparatus at the Massachusetts Institute of Technology's Laboratory for Electromagnetic and ...

  2. Occupancy and site distribution of europium in barium magnesium aluminate Eu Mossbauer spectroscopy

    E-Print Network [OSTI]

    Boolchand, Punit

    Occupancy and site distribution of europium in barium magnesium aluminate by 151 Eu Mossbauer Mossbauer spectroscopy. Analysis of the Mossbauer line shapes reveals a pentamodal or higher site

  3. The EUs Emissions Trading Scheme: A Proto-Type Global System?

    E-Print Network [OSTI]

    Ellerman, A. Denny

    2008-01-01T23:59:59.000Z

    The European Union's Emission Trading Scheme (EU ETS) is the world's first multinational cap-and-trade system for greenhouse gases. As an agreement between sovereign nations with diverse historical, institutional, and ...

  4. The EUs Emissions Trading Scheme: A Prototype Global System?

    E-Print Network [OSTI]

    Ellerman, A. Denny

    The European Union's Emission Trading Scheme (EU ETS) is the world's first multinational cap-and-trade system for greenhouse gases. As an agreement between sovereign nations with diverse historical, institutional, and ...

  5. Allocation and competitiveness in the EU emissions trading scheme: policy overview

    E-Print Network [OSTI]

    Grubb, Michael; Neuhoff, Karsten

    The European emissions trading scheme (EU ETS) has an efficient and effective market design that risks being undermined by three interrelated problems: the approach to allocation; the absence of a credible commitment to post-2012 continuation...

  6. The EUs CAP, the Doha Round and Developing Countries

    E-Print Network [OSTI]

    Halderman, Michael; Nelson, Michael

    2004-01-01T23:59:59.000Z

    Development IFPRI IGC ILRI IPSA LDC LEI LFA LLPs MGQ MS MTRDev.ing - America Dev.ing LDC EU Candidate Accession Becauseparticularly important to LDC trade including bananas,

  7. CO2 Abatement in the UK Power Sector: Evidence from the EU ETS Trial Period

    E-Print Network [OSTI]

    Ellerman, A. Denny

    2008-01-01T23:59:59.000Z

    This paper provides an empirical assessment of CO2 emissions abatement in the UK power sector during the trial period of the EU ETS. Using an econometrically estimated model of fuel switching, it separates the impacts of ...

  8. Manufacturing industry challenges and responses to EU, California, and other product-targeted environmental regulations

    E-Print Network [OSTI]

    Kirschner, Michael

    2008-01-01T23:59:59.000Z

    directive (2002/96/EC, WEEE ) the EU expanded its scope ofe-waste) regulation like WEEE, decided to take matters intake its cues from RoHS and WEEE. While industry lobbying

  9. Compliance Behavior in the EU-ETS: Cross Border Trading, Banking and Borrowing

    E-Print Network [OSTI]

    Ellerman, A. Denny

    2008-01-01T23:59:59.000Z

    This paper exploits a little used data resource within the central registry of the European Unions Emissions Trading System (EU ETS) to analyze cross border flows of allowances for compliance purposes during the first ...

  10. An EIE/Altener project Co-funded by the EU Commission

    E-Print Network [OSTI]

    the treatment of waste from industries by biomethanation), to in- crease the price for the electricity (the of the biogas production by centralised co-digestion in selected areas of six EU countries. The assessment

  11. STYRIAN ACADEMY for Sustainable Energies | http://styrianacademy.eu BER DIE STYRIAN ACADEMY

    E-Print Network [OSTI]

    STYRIAN ACADEMY for Sustainable Energies | http://styrianacademy.eu #12;BER DIE STYRIAN ACADEMY Die STYRIAN ACADEMY ist eine europische Aus- und Weiterbildungsplattform mit Standort Steiermark. Die STYRIAN ACADEMY 2010/2011 ist dem europischen Zukunftsthema nachhaltige Energiesysteme gewidmet. Die

  12. -News Home Help EU reiterates warning to Japan over nuclear project

    E-Print Network [OSTI]

    reactor without Japanese support, to end a standoff with Tokyo about who will host the project. news web and Russia back France's bid for it to be based in Cadarache, southern France. news web sites EU science

  13. Print this article Close This Window EU OKs India joining ITER nuclear reactor project

    E-Print Network [OSTI]

    Print this article Close This Window EU OKs India joining ITER nuclear reactor project Fri Dec 2 trademarks and trademarks of the Reuters group of companies around the world. Close This Window 12/2/05 4

  14. EU Agri-Environmental Payments: Appropriate Policy or Protectionism in Disguise?

    E-Print Network [OSTI]

    Glebe, Thilo

    2005-01-01T23:59:59.000Z

    1 Theory of agri-environmental policy Dr. Thilo Glebe EUto look at the agri-environmental policy from a theoreticalto the EU agri- environmental policy I want to ask therefore

  15. Eu(III) Complexes of Octadentate 1-Hydroxy-2-pyridinones: Stability and Improved Photophysical Performance

    E-Print Network [OSTI]

    Moore, Evan G.

    2010-01-01T23:59:59.000Z

    In particular, terbium and europium are of primary interestand similar size as the europium cation (4f 6 ), but with anof ? Eu , the overall europium quantum yield, will also

  16. Vanadium hydride deuterium-tritium generator

    DOE Patents [OSTI]

    Christensen, Leslie D. (Livermore, CA)

    1982-01-01T23:59:59.000Z

    A pressure controlled vanadium hydride gas generator to provide deuterium-tritium gas in a series of pressure increments. A high pressure chamber filled with vanadium-deuterium-tritium hydride is surrounded by a heater which controls the hydride temperature. The heater is actuated by a power controller which responds to the difference signal between the actual pressure signal and a programmed pressure signal.

  17. A Portable Expert System for Gas Turbine Maintenance

    E-Print Network [OSTI]

    Quentin, G. H.

    1989-01-01T23:59:59.000Z

    Combustion turbines for electric power generation and industrial applications have steadily increased in size, efficiency and prominence. The newest class of gas turbine-generators coming into service will deliver 150 megawatts, with turbine inlet...

  18. Modeling and Control of Co-generation Power Plants: A Hybrid System Approach

    E-Print Network [OSTI]

    Ferrari-Trecate, Giancarlo

    of turning on/off the gas and steam turbine, the operat- ing constraints (minimum up and down times and produces electric power through the expansion of the gas in the gas turbine; the steam cycle is supplied with the output ex- haust gas from the gas turbine and generates both electricity and steam for the industrial

  19. Gas sensor

    DOE Patents [OSTI]

    Schmid, Andreas K.; Mascaraque, Arantzazu; Santos, Benito; de la Figuera, Juan

    2014-09-09T23:59:59.000Z

    A gas sensor is described which incorporates a sensor stack comprising a first film layer of a ferromagnetic material, a spacer layer, and a second film layer of the ferromagnetic material. The first film layer is fabricated so that it exhibits a dependence of its magnetic anisotropy direction on the presence of a gas, That is, the orientation of the easy axis of magnetization will flip from out-of-plane to in-plane when the gas to be detected is present in sufficient concentration. By monitoring the change in resistance of the sensor stack when the orientation of the first layer's magnetization changes, and correlating that change with temperature one can determine both the identity and relative concentration of the detected gas. In one embodiment the stack sensor comprises a top ferromagnetic layer two mono layers thick of cobalt deposited upon a spacer layer of ruthenium, which in turn has a second layer of cobalt disposed on its other side, this second cobalt layer in contact with a programmable heater chip.

  20. EU Blanket Design Activities and Neutronics Support Efforts

    SciTech Connect (OSTI)

    Fischer, U. [Forschungszentrum Karlsruhe (Germany); Batistoni, P. [ENEA Fusion Division (Italy); Boccaccini, L.V. [Forschungszentrum Karlsruhe (Germany); Giancarli, L. [CEA Saclay (France); Hermsmeyer, S. [Forschungszentrum Karlsruhe (Germany); Poitevin, Y. [CEA Saclay (France)

    2005-05-15T23:59:59.000Z

    An overview is provided of the design activities and the related neutronics support efforts conducted in the European Union for the development of breeder blankets for future fusion power reactors. The EU fusion programme considers two blanket lines, the Helium-Cooled Pebble Bed (HCPB) blanket with Lithium ceramics pebbles (Li{sub 4}SiO{sub 4} or Li{sub 2}TiO{sub 3}) as breeder and beryllium pebbles as neutron multiplier, and the Helium-Cooled Lithium-Lead (HCLL) blanket with the Pb-Li eutectic alloy as breeder and neutron multiplier. The blanket design and the related R and D efforts are based on the use of the same coolant and the same modular blanket structure to minimise the development costs as much as possible. The neutronic support efforts include design analyses for the layout and optimization of the modular HCPB/HCLL blankets based on detailed three-dimensional Monte Carlo calculations as well as underlying neutronics activities conducted in the frame of the European Fusion and Activation File (EFF/EAF) projects to develop qualified nuclear data and computational tools for reliable neutronics design calculations.

  1. Associated Shale Gas- From Flares to Rig Power

    E-Print Network [OSTI]

    Wallace, Elizabeth Michelle

    2014-10-16T23:59:59.000Z

    , compressed natural gas (CNG), or liquefied natural gas (LNG) (Soares 2008). Another option that can be considered to use natural gas and meet power load requirements is to convert diesel generators to a dual-fuel engines. Using both diesel and natural gas...-scale gas process could provide the solution to variable gas quality from different locations for use in power sources using natural gas. This micro-scale process is comparable to full scale LNG and CNG processing, first separating the liquids...

  2. Luminescence characterization of (Ca{sub 1-x}Zn{sub x})Ga{sub 2}S{sub 4}:Eu{sup 2+} phosphors for a white light-emitting diode

    SciTech Connect (OSTI)

    Kim, Yong-Kyu; Cho, Dong-Hee; Jeong, Yong-Kwang; Nah, Min-Kook [Department of Chemistry, Chungnam National University, Daejeon 305-764 (Korea, Republic of)] [Department of Chemistry, Chungnam National University, Daejeon 305-764 (Korea, Republic of); Kim, Kwang-Bok [Kumho Electric Inc., 64-1 Bongmyung-Ri, Namsa-Myun, Youngin, Gyeonggi-Do 449-883 (Korea, Republic of)] [Kumho Electric Inc., 64-1 Bongmyung-Ri, Namsa-Myun, Youngin, Gyeonggi-Do 449-883 (Korea, Republic of); Kang, Jun-Gill, E-mail: jgkang@cnu.ac.kr [Department of Chemistry, Chungnam National University, Daejeon 305-764 (Korea, Republic of)] [Department of Chemistry, Chungnam National University, Daejeon 305-764 (Korea, Republic of)

    2010-08-15T23:59:59.000Z

    We investigated the luminescence properties of (Ca{sub 1-x}Zn{sub x})Ga{sub 2}S{sub 4}:Eu{sup 2+} phosphor as a function of Zn{sup 2+} and Eu{sup 2+} concentrations. The luminescence intensity was markedly enhanced by increasing the mole fraction of Zn{sup 2+} at Ca{sup 2+} sites. Lacking any Zn{sup 2+} ions, CaGa{sub 2}S{sub 4}:0.01Eu{sup 2+} converted only 18.1% of the absorbed blue light into luminescence. As the Zn{sup 2+} concentration increased, the quantum yield increased and reached a maximum of 24.4% at x = 0.1. Furthermore, to fabricate the device, the optimized green-yellow (Ca{sub 0.9}Zn{sub 0.1})Ga{sub 2}S{sub 4}:Eu{sup 2+} phosphor was coated with MgO. White light was generated by combining the MgO-coated phosphor and the blue emission from a GaN chip.

  3. Thermoelectric Generators 1. Thermoelectric generator

    E-Print Network [OSTI]

    Lee, Ho Sung

    1 Thermoelectric Generators HoSung Lee 1. Thermoelectric generator 1.1 Basic Equations In 1821 effects are called the thermoelectric effects. The mechanisms of thermoelectricity were not understood. Cold Hot I - -- - - - - -- Figure 1 Electron concentration in a thermoelectric material. #12;2 A large

  4. Management of waste electrical and electronic equipment in two EU countries: A comparison

    SciTech Connect (OSTI)

    Torretta, Vincenzo, E-mail: vincenzo.torretta@uninsubria.it [Department of Science and High Technology, Insubria University of Varese, Via G.B. Vico 46, I-21100 Varese (Italy); Ragazzi, Marco [Department of Civil and Environmental Engineering, University of Trento, Via Mesiano 77, I-38123 Trento (Italy); Istrate, Irina Aura [Department of Energy Production and Use, Politehnica University of Bucharest, Splaiul Independentei 313, 060042 Bucharest (Romania); Rada, Elena Cristina [Department of Civil and Environmental Engineering, University of Trento, Via Mesiano 77, I-38123 Trento (Italy)

    2013-01-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer Review on data regarding WEEE management in Italy and in Romania. Black-Right-Pointing-Pointer Problems that countries that will enter in the EU will have to solve facing with the WEEE management. Black-Right-Pointing-Pointer Pilot experiences useful for the awareness campaign of the population. - Abstract: The paper presents some data regarding waste electrical and electronic (WEEE) management in one of the founding countries of the EU, Italy, and in a recent entry into the EU, Romania. The aim of this research was to analyze some problems that countries entering the EU will have to solve with respect to WEEE management. The experiences of Italy and Romania could provide an interesting reference point. The strengths and weaknesses that the two EU countries have encountered can be used in order to give a more rational plan for other countries. In Italy the increase of WEEE collection was achieved in parallel with the increase of the efficiency of selective Municipal Solid Waste collection. In Romania, pilot experiences were useful to increase the awareness of the population. The different interests of the two populations towards recyclable waste led to a different scenario: in Romania all types of WEEE have been collected since its entrance into the EU; in Italy the 'interest' in recycling is typically related to large household appliances, with a secondary role of lighting equipment.

  5. NATURAL GAS MARKET ASSESSMENT

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION NATURAL GAS MARKET ASSESSMENT PRELIMINARY RESULTS In Support.................................................................................... 6 Chapter 2: Natural Gas Demand.................................................................................................. 10 Chapter 3: Natural Gas Supply

  6. Discharge cell for ozone generator

    DOE Patents [OSTI]

    Nakatsuka, Suguru (Amagasaki, JP)

    2000-01-01T23:59:59.000Z

    A discharge cell for use in an ozone generator is provided which can suppress a time-related reduction in ozone concentration without adding a catalytic gas such as nitrogen gas to oxygen gas as a raw material gas. The discharge cell includes a pair of electrodes disposed in an opposed spaced relation with a discharge space therebetween, and a dielectric layer of a three-layer structure consisting of three ceramic dielectric layers successively stacked on at least one of the electrodes, wherein a first dielectric layer of the dielectric layer contacting the one electrode contains no titanium dioxide, wherein a second dielectric layer of the dielectric layer exposed to the discharge space contains titanium dioxide in a metal element ratio of not lower than 10 wt %.

  7. Method for mapping a natural gas leak

    DOE Patents [OSTI]

    Reichardt, Thomas A. (Livermore, CA); Luong, Amy Khai (Dublin, CA); Kulp, Thomas J. (Livermore, CA); Devdas, Sanjay (Albany, CA)

    2009-02-03T23:59:59.000Z

    A system is described that is suitable for use in determining the location of leaks of gases having a background concentration. The system is a point-wise backscatter absorption gas measurement system that measures absorption and distance to each point of an image. The absorption measurement provides an indication of the total amount of a gas of interest, and the distance provides an estimate of the background concentration of gas. The distance is measured from the time-of-flight of laser pulse that is generated along with the absorption measurement light. The measurements are formatted into an image of the presence of gas in excess of the background. Alternatively, an image of the scene is superimposed on the image of the gas to aid in locating leaks. By further modeling excess gas as a plume having a known concentration profile, the present system provides an estimate of the maximum concentration of the gas of interest.

  8. Evaluating Policies to Increase the Generation of Electricity from Renewable Energy

    E-Print Network [OSTI]

    Schmalensee, Richard

    Focusing on the U.S. and the E.U., this essay seeks to advance four main propositions. First, the incidence of the short-run costs of programs to subsidize the generation of electricity from renewable sources varies with ...

  9. The impact of the European Union Emission Trading Scheme on electricity generation sectors

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    The impact of the European Union Emission Trading Scheme on electricity generation sectors Djamel the Kyoto Protocol, France and Germany par- ticipate to the European Union Emission Trading Scheme (EU ETS, the European market for emission allowances has increased the market power of the historical French electricity

  10. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems, Volume 4. Appendix C: Design and performance of standardized fixed bed air-blown gasifier IGCC systems for future electric power generation: Final report

    SciTech Connect (OSTI)

    Not Available

    1991-02-01T23:59:59.000Z

    This appendix is a compilation of work done to predict overall cycle performance from gasifier to generator terminals. A spreadsheet has been generated for each case to show flows within a cycle. The spreadsheet shows gaseous or solid composition of flow, temperature of flow, quantity of flow, and heat heat content of flow. Prediction of steam and gas turbine performance was obtained by the computer program GTPro. Outputs of all runs for each combined cycle reviewed has been added to this appendix. A process schematic displaying all flows predicted through GTPro and the spreadsheet is also added to this appendix. The numbered bubbles on the schematic correspond to columns on the top headings of the spreadsheet.

  11. Assessment of coal bed gas prospects

    SciTech Connect (OSTI)

    Moore, T.R. [Phillips Petroleum Co., Bartlesville, OK (United States)

    1996-12-31T23:59:59.000Z

    Coal bed gas is an often overlooked source of clean, methane-rich, H{sub 2}S-free natural gas. The economic development of coal bed gas requires a knowledge of coal gas reservoir characteristics and certain necessary departures from conventional evaluation, drilling, completion, and production practices. In many ways coal seam reservoirs are truly unconventional. Most coals sufficient rank have generated large volumes of gas that may be retained depth in varying amounts through adsorption. Coal gas production can take place only when the reservoir pressure is reduced sufficiently to allow the gas to desorb. Gas flow to the well bore takes place through a hierarchy of natural fractures, not the relatively impermeable coal matrix. Economic production is dependent upon critical factors intrinsic to the reservoir, including coal petrology, gas content, internal formation stratigraphy, fracture distribution, hydrogeology, in situ stress conditions, initial reservoir pressure and pressure regime, and the presence or absence of a {open_quote}free{close_quotes} gas saturation. Further, the coal bed reservoir is readily subject to formation damage through improper drilling, completion, or production techniques. This presentation will review the data types critical to the assessment of any coal seam gas prospect, suggest an outline method for screening such prospects, and point out some possible pitfalls to be considered in any coal bed gas development project.

  12. EU-Canada Student Mobility Program Personal Experience

    E-Print Network [OSTI]

    Payandeh, Shahram

    System, we visited the city's main attractions, it's famous districts, buildings. I loved China Town, Gas part that it is that you are surrounded with beautiful nature: everywhere you turn you can see trees facilities and its natural attributes. The forest gives the park a more natural character than most other

  13. Illegal Logging Gives EU Massive Eco-Headache With tropical rainforests continuing to disappear at an alarming rate, the EU is partially to

    E-Print Network [OSTI]

    17.04.2008 Illegal Logging Gives EU Massive Eco-Headache With tropical rainforests continuing. The problem of illegal logging is particularly acute in Indonesia, allegedly the world's third largest gases and global warming, rising demand for palm oil has resulted in local companies burning woods

  14. Georgia Tech Dangerous Gas

    E-Print Network [OSTI]

    Sherrill, David

    1 Georgia Tech Dangerous Gas Safety Program March 2011 #12;Georgia Tech Dangerous Gas Safety.......................................................................................................... 5 6. DANGEROUS GAS USAGE REQUIREMENTS................................................. 7 6.1. RESTRICTED PURCHASE/ACQUISITION RULES: ................................................ 7 7. FLAMMABLE GAS

  15. Identifying Options for Deep Reductions in Greenhouse Gas Emissions from California Transportation: Meeting an 80% Reduction Goal in 2050

    E-Print Network [OSTI]

    Yang, Christopher; McCollum, David L; McCarthy, Ryan; Leighty, Wayne

    2008-01-01T23:59:59.000Z

    natural gas reformation with pipeline distribution (64%),gas reformation (71%), centralized biomass gasification with pipeline distribution (pipeline distribution (65%), and onsite electrolysis (67%); and electricity generation from: biomass (40%), coal (45%) and natural gas

  16. Gas stream cleanup

    SciTech Connect (OSTI)

    Bossart, S.J.; Cicero, D.C.; Zeh, C.M.; Bedick, R.C.

    1990-08-01T23:59:59.000Z

    This report describes the current status and recent accomplishments of gas stream cleanup (GSCU) projects sponsored by the Morgantown Energy Technology Center (METC) of the US Department of Energy (DOE). The primary goal of the Gas Stream Cleanup Program is to develop contaminant control strategies that meet environmental regulations and protect equipment in advanced coal conversion systems. Contaminant control systems are being developed for integration into seven advanced coal conversion processes: Pressurized fludized-bed combustion (PFBC), Direct coal-fueled turbine (DCFT), Intergrated gasification combined-cycle (IGCC), Gasification/molten carbonate fuel cell (MCFC), Gasification/solid oxide fuel cell (SOFC), Coal-fueled diesel (CFD), and Mild gasification (MG). These advanced coal conversion systems present a significant challenge for development of contaminant control systems because they generate multi-contaminant gas streams at high-pressures and high temperatures. Each of the seven advanced coal conversion systems incorporates distinct contaminant control strategies because each has different contaminant tolerance limits and operating conditions. 59 refs., 17 figs., 5 tabs.

  17. Generation Gaps Revisited Kenneth A. De Jong Jayshree Sarma

    E-Print Network [OSTI]

    George Mason University

    . In spite of considerable progress in our understanding of GAs since then, the pros/cons of overlapping of considerable progress in our understanding of GAs, the pros/cons of overlapping generations remains a somewhat There has been a lot of recent interest in so-called "steady state" genetic algorithms (GAs) which, among

  18. Generation Gaps Revisited Kenneth A. De Jong Jayshree Sarma

    E-Print Network [OSTI]

    George Mason University

    . In spite of considerable progress in our understanding of GAs since then, the pros/cons of overlapping. In spite of considerable progress in our understanding of GAs, the pros/cons of overlapping generations There has been a lot of recent interest in so­called "steady state" genetic algorithms (GAs) which, among

  19. Cascading of Fluctuations in Interdependent Energy Infrastructures: Gas-Grid Coupling

    E-Print Network [OSTI]

    Chertkov, Michael; Backhaus, Scott

    2014-01-01T23:59:59.000Z

    The revolution of hydraulic fracturing has dramatically increased the supply and lowered the cost of natural gas in the United States driving an expansion of natural gas-fired generation capacity in many electrical grids. Unrelated to the natural gas expansion, lower capital costs and renewable portfolio standards are driving an expansion of intermittent renewable generation capacity such as wind and photovoltaic generation. These two changes may potentially combine to create new threats to the reliability of these interdependent energy infrastructures. Natural gas-fired generators are often used to balance the fluctuating output of wind generation. However, the time-varying output of these generators results in time-varying natural gas burn rates that impact the pressure in interstate transmission pipelines. Fluctuating pressure impacts the reliability of natural gas deliveries to those same generators and the safety of pipeline operations. We adopt a partial differential equation model of natural gas pipeli...

  20. North American Natural Gas Markets. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1988-12-01T23:59:59.000Z

    This report sunnnarizes the research by an Energy Modeling Forum working group on the evolution of the North American natural gas markets between now and 2010. The group`s findings are based partly on the results of a set of economic models of the natural gas industry that were run for four scenarios representing significantly different conditions: two oil price scenarios (upper and lower), a smaller total US resource base (low US resource case), and increased potential gas demand for electric generation (high US demand case). Several issues, such as the direction of regulatory policy and the size of the gas resource base, were analyzed separately without the use of models.

  1. North American Natural Gas Markets. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1989-02-01T23:59:59.000Z

    This report summarizes die research by an Energy Modeling Forum working group on the evolution of the North American natural gas markets between now and 2010. The group`s findings are based partly on the results of a set of economic models of the natural gas industry that were run for four scenarios representing significantly different conditions: two oil price scenarios (upper and lower), a smaller total US resource base (low US resource case), and increased potential gas demand for electric generation (high US demand case). Several issues, such as the direction of regulatory policy and the size of the gas resource base, were analyzed separately without the use of models.

  2. Design and Performance Aspects of Steam Generators

    E-Print Network [OSTI]

    Ganapathy, V.

    1994-01-01T23:59:59.000Z

    -DESIGNING The concept of custom designing packaged steam generators is not new. Those familiar with heat recovery applications know that efficency and gas pressure drop are critical factors from boiler performance viewpoint and efforts should be made... gas pressure drop in a 100,000 lb/h boiler is equivalent to 15-18 kw of additional power or $ 7500 per year electricity bill, not to mention the larger fan size. Due to higher gas flow,the boiler efficency will also be affected. The exit gas...

  3. Abstract--South America has emerged in recent years as one of the most dynamic regions for natural gas and electricity

    E-Print Network [OSTI]

    Catholic University of Chile (Universidad Catlica de Chile)

    for natural gas and electricity development. The continent boasts natural gas reserves and high- growth energy countries to promote the use of natural gas, especially for power generation. On the other hand, challenges-country natural gas agreements, competition between natural gas and other resources for power generation

  4. Study and Development of Anti-Islanding Control for Synchronous Machine-Based Distributed Generators: November 2001--March 2004

    SciTech Connect (OSTI)

    Ye, Z.

    2006-03-01T23:59:59.000Z

    This report summarizes the study and development of new active anti-islanding control schemes for synchronous machine-based distributed generators, including engine generators and gas turbines.

  5. Gas tagging and cover gas combination for nuclear reactor

    DOE Patents [OSTI]

    Gross, Kenny C. (Lemont, IL); Laug, Matthew T. (Idaho Falls, ID)

    1985-01-01T23:59:59.000Z

    The invention discloses the use of stable isotopes of neon and argon, that are grouped in preselected different ratios one to the other and are then sealed as tags in different cladded nuclear fuel elements to be used in a liquid metal fast breeder reactor. Failure of the cladding of any fuel element allows fission gases generated in the reaction and these tag isotopes to escape and to combine with the cover gas held in the reactor over the fuel elements. The isotopes specifically are Ne.sup.20, Ne.sup.21 and Ne.sup.22 of neon and Ar.sup.36, Ar.sup.38 and Ar.sup.40 of argon, and the cover gas is helium. Serially connected cryogenically operated charcoal beds are used to clean the cover gas and to separate out the tags. The first or cover gas cleanup bed is held between approximately 0.degree. and -25.degree. C. operable to remove the fission gases from the cover gas and tags and the second or tag recovery system bed is held between approximately -170.degree. and -185.degree. C. operable to isolate the tags from the cover gas. Spectrometric analysis further is used to identify the specific tags that are recovered, and thus the specific leaking fuel element. By cataloging the fuel element tags to the location of the fuel elements in the reactor, the location of the leaking fuel element can then be specifically determined.

  6. Preliminary Estimates of Combined Heat and Power Greenhouse Gas Abatement Potential for California in 2020

    E-Print Network [OSTI]

    Firestone, Ryan; Ling, Frank; Marnay, Chris; Hamachi LaCommare, Kristina

    2007-01-01T23:59:59.000Z

    for out-of-state coal generation, then clearly the GHGElectricity Generation (TWh/a) Natural Gas Coal Natural Gascoal becomes the marginal fuel. Note that the marginal generation

  7. Differentiation and Dynamics of Competitiveness Impacts from the EU ETS

    E-Print Network [OSTI]

    Sato, Misato; Grubb, Michael; Cust, J; Chan, Katie; Korppoo, Anna; Ceppi, Pablo

    efficiency measures or adopting more advanced technologies, without switching technology. For example, replacing a coal- fired steam turbine with pulverised-coal technology can achieve 27% emissions reductions and replacing a single cycle gas turbine... competitiveness on a country level because a household or transportation in one country does not compete with their counterpart in another country, hence the concept of nationwide competitiveness is ill- 3...

  8. Promoting electricity from renewable energy sources -- lessons learned from the EU, U.S. and Japan

    E-Print Network [OSTI]

    Haas, Reinhard

    2008-01-01T23:59:59.000Z

    Biomass, Biogas, Landfill gas, Sewage gas, Geothermal)/MWh; Sewage and landfill gas: 45-60 /MWh; Wind OnshoreMWh; Landfill-, Sewage- & Landfill gas: 64.5-74.4 /MWh; PV:

  9. Aryl Bridged 1-Hydroxypyridin-2-one: Effect of the Bridge on the Eu(III) Sensitization Process

    E-Print Network [OSTI]

    D'Aleo, Anthony

    2010-01-01T23:59:59.000Z

    kinetic parameters for the europium emission were completed.water molecule bound to the europium cation while for [Eu(Lsensitization of the europium ion. Keywords: europium,

  10. Generator configuration for solid oxide fuel cells

    DOE Patents [OSTI]

    Reichner, Philip (Plum Boro, PA)

    1989-01-01T23:59:59.000Z

    Disclosed are improvements in a solid oxide fuel cell generator 1 having a multiplicity of electrically connected solid oxide fuel cells 2, where a fuel gas is passed over one side of said cells and an oxygen-containing gas is passed over the other side of said cells resulting in the generation of heat and electricity. The improvements comprise arranging the cells in the configuration of a circle, a spiral, or folded rows within a cylindrical generator, and modifying the flow rate, oxygen concentration, and/or temperature of the oxygen-containing gases that flow to those cells that are at the periphery of the generator relative to those cells that are at the center of the generator. In these ways, a more uniform temperature is obtained throughout the generator.

  11. Statkraft is Europe's largest generator of renewable energy and is the leading power company in Norway. The company owns, produces and develops hydropower, wind power, gas-fired power and

    E-Print Network [OSTI]

    Morik, Katharina

    Statkraft is Europe's largest generator of renewable energy and is the leading power company countries. For our office in Dsseldorf we are currently looking to hire a System Manager Renewable Energy. Share our passion for renewable energy and be a part of tomorrow's energy world. Your department

  12. EuCuOSe: Crystal structure refinement, electrical and magnetic properties

    SciTech Connect (OSTI)

    Llanos, Jaime [Departamento de Quimica, Universidad Catolica del Norte, Avda. Angamos 0610, Casilla 1280, Antofagasta (Chile)], E-mail: jllanos@ucn.cl; Cortes, Rodrigo; Sanchez, Victor [Departamento de Quimica, Universidad Catolica del Norte, Avda. Angamos 0610, Casilla 1280, Antofagasta (Chile)

    2008-02-05T23:59:59.000Z

    The europium copper oxyselenide EuCuOSe has been prepared by reacting Eu, CuO and Se in the ratio 1:1:1 at 1123 K for a period of 10 days in sealed quartz ampoule. The structure has been determined by single-crystal X-ray methods. The compound crystallizes tetragonal in the space group P4/nmm (no. 129) with two formula units in the cell with dimensions a = 393.65(8) pm and c = 871.80(17) pm. The structure is composed of {sup 2}{sub {infinity}}{l_brace}[(Eu{sup 3+})(O{sup 2-}){sub 4/4}(Se{sup 2-}){sub 4/4}]{sup -}{r_brace} double layers separated by copper atoms, which are tetrahedrally coordinated to Se{sup 2-} anions. According to the resistivity measurements, EuCuOSe is a semiconductor. The magnetic susceptibility data shows the typical non-Curie-Weiss behavior of the {sup 7}F{sub J} states of Eu in the 4f{sup 6} configuration.

  13. Chemical Feature of Eu abundance in the Draco dwarf spheroidal galaxy

    E-Print Network [OSTI]

    Tsujimoto, Takuji; Shigeyama, Toshikazu; Aoki, Wako

    2015-01-01T23:59:59.000Z

    Chemical abundance of r-process elements in nearby dwarf spheroidal (dSph) galaxies is a powerful tool to probe the site of r-process since their small-mass scale can sort out individual events producing r-process elements. A merger of binary neutron stars is a promising candidate of this site. In faint, or less massive dSph galaxies such as the Draco, a few binary neutron star mergers are expected to have occurred at most over the whole past. We have measured chemical abundances including Eu and Ba of three red giants in the Draco dSph by Subaru/HDS observation. The Eu detection for one star with [Fe/H]=-1.45 confirms a broadly constant [Eu/H] of ~-1.3 for stars with [Fe/H]>-2. This feature is shared by other dSphs with similar masses, i.e., the Sculptor and the Carina, and suggests that neutron star merger is the origin of r-process elements in terms of its rarity. In addition, two very metal-poor stars with [Fe/H]=-2.12 and -2.51 are found to exhibit very low Eu abundances such as [Eu/H]<-2 with an impl...

  14. A violet emission in ZnS:Mn,Eu: Luminescence and applications for radiation detection

    SciTech Connect (OSTI)

    Ma, Lun; Chen, Wei, E-mail: weichen@uta.edu [Department of Physics and the SAVANT Center, The University of Texas at Arlington, Arlington, Texas 76019-0059 (United States); Jiang, Ke [Center for Biofrontiers Institute, University of Colorado at Colorado Springs, 1420 Austin Bluffs Pkwy., Colorado Springs, Colorado 80918 (United States); Liu, Xiao-tang [Department of Physics and the SAVANT Center, The University of Texas at Arlington, Arlington, Texas 76019-0059 (United States); Department of Applied Chemistry, College of Science, South China Agricultural University, Guangzhou 510642 (China)

    2014-03-14T23:59:59.000Z

    We prepared manganese and europium co-doped zinc sulfide (ZnS:Mn,Eu) phosphors and used them for radiation detection. In addition to the red fluorescence at 583?nm due to the d-d transition of Mn ions, an intense violet emission at 420?nm is newly observed in ZnS:Mn,Eu phosphors. The emission is related to Eu{sup 2+} doping but only appears at certain Eu{sup 2+} concentrations. It is found that the intensity of the 420?nm violet fluorescence is X-ray does-dependent, while the red fluorescence of 583?nm is not. The ratio of fluorescence intensities at 420?nm and 583?nm has been monitored as a function of X-ray doses that exposed upon the ZnS:Mn,Eu phosphors. Empirical formulas are provided to estimate the doses of applied X-ray irradiation. Finally, possible mechanisms of X-ray irradiation induced fluorescence quenching are discussed. The intense 420?nm emission not only provides a violet light for solid state lighting but also offers a very sensitive method for radiation detection.

  15. Optical studies on Eu{sup 3+} doped boro-tellurite glasses

    SciTech Connect (OSTI)

    Maheshvaran, K.; Marimuthu, K. [Department of Physics, Gandhigram Rural Institute - Deemed University, Gandhigram - 624 302 (India)

    2012-06-05T23:59:59.000Z

    Eu{sup 3+} doped boro-tellurite glasses with the chemical composition (39-x)B{sub 2}O{sub 3}+30TeO{sub 2}+15MgO+15K{sub 2}O +xEu{sub 2}O{sub 3} (where x = 0.01, 0.1, 1, 2 and 3 wt%) have been prepared by following conventional melt quenching technique. Spectroscopic properties of the Eu{sup 3+} doped boro-tellurite glasses have been studied by recording the optical absorption and luminescence measurements. Through the optical absorption spectra, bonding parameters ({beta}-bar, {delta}) have been calculated to identify the ionic/covalent nature of the glasses. Judd-Ofelt (JO) analysis have been carried out using the luminescence spectra. The JO parameters ({Omega}{sub {lambda}}= 2, 4 and 6) were used to calculate the radiative properties for the {sup 5}D{sub 0}{yields}{sup 7}F{sub J} (J = 1, 2, 3 and 4) emission transitions of the Eu{sup 3+} ions. The change in optical properties with the variation of Eu{sup 3+} ion concentration have been studied and discussed with similar studies.

  16. New ternary phosphides and arsenides. Syntheses, crystal structures, physical properties of Eu{sub 2}ZnP{sub 2}, Eu{sub 2}Zn{sub 2}P{sub 3} and Eu{sub 2}Cd{sub 2}As{sub 3}

    SciTech Connect (OSTI)

    Wang, Jian [State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, Shandong 250100 (China); Xia, Sheng-Qing, E-mail: shqxia@sdu.edu.cn [State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, Shandong 250100 (China); Tao, Xu-Tang [State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan, Shandong 250100 (China); Schfer, Marion C. [Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716 (United States); Bobev, Svilen, E-mail: bobev@udel.edu [Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716 (United States)

    2013-09-15T23:59:59.000Z

    Three new europium pnictides Eu{sub 2}ZnP{sub 2}, Eu{sub 2}Zn{sub 2}P{sub 3} and Eu{sub 2}Cd{sub 2}As{sub 3} have been synthesized and their structures were determined by single-crystal X-ray diffraction. Eu{sub 2}ZnP{sub 2} is isotypic with Yb{sub 2}CdSb{sub 2} (Cmc2{sub 1} (No. 36); cell parameters a=4.1777(7) , b=15.925(3) , c=7.3008(12) ), while the latter two compounds crystallize with the Ba{sub 2}Cd{sub 2}Sb{sub 3} structure type (C2/m (No. 12); cell parameters a=15.653(5)/16.402(1) , b=4.127(1)/4.445(4) , c=11.552(4)/12.311(1) and ?=126.647(4)/126.515(7) for Eu{sub 2}Zn{sub 2}P{sub 3} and Eu{sub 2}Cd{sub 2}As{sub 3}, respectively). Magnetic susceptibility measurements in the interval 5300 K confirm paramagnetic behavior and effective magnetic moments characteristic of Eu{sup 2+} ([Xe] 4f{sup 7}) ground states. Temperature-dependent electrical conductivity measurements also prove that Eu{sub 2}Cd{sub 2}As{sub 3} is a semiconducting compound with a narrow band gap of 0.059 eV below 100 K. According to TG/DSC analyses, Eu{sub 2}Cd{sub 2}As{sub 3} starts to decompose at about 950 K. - Graphical abstract: A polyhedral view of the crystal structure of new pnictides Eu{sub 2}T{sub 2}Pn{sub 3} (T=Zn or Cd; Pn=P or As). Display Omitted - Highlights: Three new ternary pnictide Zintl compounds, Eu{sub 2}ZnP{sub 2}, Eu{sub 2}Zn{sub 2}P{sub 3} and Eu{sub 2}Cd{sub 2}As{sub 3}, have been synthesized and characterized. The europium cations are divalent and ferromagnetically coupled in both Eu{sub 2}Zn{sub 2}P{sub 3} and Eu{sub 2}Cd{sub 2}As{sub 3}. Eu{sub 2}Cd{sub 2}As{sub 3} has a very small band gap of 0.06 eV and starts to decompose over 950 K.

  17. Discharge source with gas curtain for protecting optics from particles

    DOE Patents [OSTI]

    Fornaciari, Neal R.; Kanouff, Michael P.

    2004-03-30T23:59:59.000Z

    A gas curtain device is employed to deflect debris that is generated by an extreme ultraviolet and soft x-ray radiation discharge source such as an electric discharge plasma source. The gas curtain device projects a stream of gas over the path of the radiation to deflect debris particles into a direction that is different from that of the path of the radiation. The gas curtain can be employed to prevent debris accumulation on the optics used in photolithography.

  18. Synthesis gas production by mixed conducting membranes with integrated conversion into liquid products

    DOE Patents [OSTI]

    Nataraj, Shankar (Allentown, PA); Russek, Steven Lee (Allentown, PA); Dyer, Paul Nigel (Allentown, PA)

    2000-01-01T23:59:59.000Z

    Natural gas or other methane-containing feed gas is converted to a C.sub.5 -C.sub.19 hydrocarbon liquid in an integrated system comprising an oxygenative synthesis gas generator, a non-oxygenative synthesis gas generator, and a hydrocarbon synthesis process such as the Fischer-Tropsch process. The oxygenative synthesis gas generator is a mixed conducting membrane reactor system and the non-oxygenative synthesis gas generator is preferably a heat exchange reformer wherein heat is provided by hot synthesis gas product from the mixed conducting membrane reactor system. Offgas and water from the Fischer-Tropsch process can be recycled to the synthesis gas generation system individually or in combination.

  19. Fuel gas conditioning process

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A. (Union City, CA)

    2000-01-01T23:59:59.000Z

    A process for conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas, so that it can be used as combustion fuel to run gas-powered equipment, including compressors, in the gas field or the gas processing plant. Compared with prior art processes, the invention creates lesser quantities of low-pressure gas per unit volume of fuel gas produced. Optionally, the process can also produce an NGL product.

  20. Climate for Collaboration: Analysis of US and EU Lessons and Opportunities in Energy and Climate Policy

    SciTech Connect (OSTI)

    De Vita, A.; de Connick, H.; McLaren, J.; Cochran, J.

    2009-11-01T23:59:59.000Z

    A deepening of cooperation between the United States and the European Union requires mutual trust, and understanding of current policies, challenges and successes. Through providing such understanding among policymakers, industry and other stakeholders in both economies, opportunities for transatlantic cooperation on climate change and energy policy emerge. This paper sets out by discussing the environmental, legislative, and economic contexts of the EU and US as related to climate. This context is essential to understanding how cap-and-trade, renewable energy and sustainable transportation policies have taken shape in the EU and the US, as described in Chapter 3.1. For each of these policies, a barrier analysis and discussion is provided. Chapter 4 builds off this improved understanding to listobservations and possible lessons learned. The paper concludes with recommendations on topics where EU and US interests align, and where further cooperation could prove beneficial.

  1. Optical properties of Eu{sup 2+} doped antipervoskite fluoride single crystals

    SciTech Connect (OSTI)

    Daniel, D. Joseph; Ramasamy, P. [Centre for Crystal Growth, SSN College of Engineering, kalavakkam, Tamilnadu- 603 110 (India); Nithya, R. [Materials Science Group, Indira Gandhi Centre for Atomic Research, Kalpakkam, Tamilnadu - 603 102 (India); Madhusoodanan, U. [Radiological Safety Division, Indira Gandhi Centre for Atomic Research, Kalpakkam, Tamilnadu - 603 102 (India)

    2013-02-05T23:59:59.000Z

    Single crystals of pure and Eu{sup 2+} doped LiBaF{sub 3} have been grown from melt by using a vertical Bridgman-Stockbarger method. Absorption and luminescence spectra for pure and rare-earth-doped LiBaF{sub 3} were studied. At ambient conditions the photoluminescence spectra consisted of sharp lines peaked at {approx}359 nm attributed to the {sup 6}P7/2{yields}{sup 8}S7/2 transitions in the 4f{sub 7} electronic configuration of Eu{sup 2+} and a broad band extending between 370 and 450 nm attributed to Eu{sup 2+} trapped exciton recombination. The effect of {sup 60}Co gamma irradiation has also been investigated.

  2. Sr{sub 3}Al{sub 2}O{sub 5}Cl{sub 2}:Ce{sup 3+},Eu{sup 2+}: A potential tunable yellow-to-white-emitting phosphor for ultraviolet light emitting diodes

    SciTech Connect (OSTI)

    Song Yanhua; Jia Guang; Yang Mei; Huang Yeju; You Hongpeng; Zhang Hongjie [State Key laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China) and Graduate University of the Chinese Academy of Sciences, Beijing 100049 (China)

    2009-03-02T23:59:59.000Z

    The Sr{sub 3}Al{sub 2}O{sub 5}Cl{sub 2}:Ce{sup 3+},Eu{sup 2+} phosphors were prepared by solid state reaction. The obtained phosphors exhibit a strong absorption in the UV-visible region and have two intense emission bands at 444 and 609 nm. The energy transfer from the Ce{sup 3+} to Eu{sup 2+} ions was observed, and the critical distance has been estimated to be about 24.5 A by spectral overlap method. Furthermore, the developed phosphors can generate lights from yellow-to-white region under the excitation of UV radiation by appropriately tuning the activator content, indicating that they have potential applications as an UV-convertible phosphor for white light emitting diodes.

  3. 25%Eu : KGd(WO{sub 4}){sub 2} laser crystal: spectroscopy and lasing on the {sup 5}D{sub 0}{yields}{sup 7}F{sub 4} transition

    SciTech Connect (OSTI)

    Bagaev, Sergei N; Dashkevich, V I; Orlovich, Valentin A; Vatnik, S M; Pavlyuk, A A; Yurkin, A M

    2011-03-31T23:59:59.000Z

    25%Eu : KGd(WO{sub 4}){sub 2} crystal is grown by a modified Czochralski method and its spectral and lasing properties are studied. Generation of stimulated emission in this crystal on the {sup 5}D{sub 0}{yields}{sup 7}F{sub 4} transition of the Eu{sup 3+} ion is obtained, as far as we know, for the first time. The laser operates at room temperature at a wavelength of {approx}703 nm under pumping into the {sup 7}F{sub 0}{yields}{sup 5}D{sub 1} absorption band of the europium ion by the second harmonic of a Q-switched Nd : KGW laser ({lambda}{sub pump}= 533.6 nm). With a 9.4-mm-long active element, the output energy in the free-running regime reached 244 {mu}J, while the optical efficiency was 1.5%. (lasers and active media)

  4. Development of an efficient, low cost, small-scale natural gas fuel reformer for residential scale electric power generation. Final report for the period October 1, 1998 - December 31, 1999

    SciTech Connect (OSTI)

    Kreutz, Thomas G.; Ogden, Joan M.

    2000-07-01T23:59:59.000Z

    In the final report, we present results from a technical and economic assessment of residential scale PEM fuel cell power systems. The objectives of our study are to conceptually design an inexpensive, small-scale PEMFC-based stationary power system that converts natural gas to both electricity and heat, and then to analyze the prospective performance and economics of various system configurations. We developed computer models for residential scale PEMFC cogeneration systems to compare various system designs (e.g., steam reforming vs. partial oxidation, compressed vs. atmospheric pressure, etc.) and determine the most technically and economically attractive system configurations at various scales (e.g., single family, residential, multi-dwelling, neighborhood).

  5. EU promises new biofuel rules won't harm the environment http://www.pr-inside.com/eu-promises-new-biofuel-rules-won-t-r385258.htm 1 of 2 1/16/2008 12:32 PM

    E-Print Network [OSTI]

    EU promises new biofuel rules won't harm the environment http://www.pr-inside.com/eu-promises-new-biofuel promises new biofuel rules won't harm the environment AP 2008-01-14 16:21:49 - BRUSSELS, Belgium (AP) - The European Union promised Monday that its new push to promote biofuels will try to prevent harming

  6. Coke oven gas injection to blast furnaces

    SciTech Connect (OSTI)

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L. [U.S. Steel, Clairton, PA (United States)

    1995-12-01T23:59:59.000Z

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  7. Trapping processes in CaS:Eu{sup 2+},Tm{sup 3+}

    SciTech Connect (OSTI)

    Jia, Dongdong [Department of Materials Science and Engineering, Tsinghua University, Beijing, (China)] [Department of Materials Science and Engineering, Tsinghua University, Beijing, (China); Jia, Weiyi [Department of Physics, University of Puerto Rico, Mayaguez, Puerto Rico 00681 (Puerto Rico)] [Department of Physics, University of Puerto Rico, Mayaguez, Puerto Rico 00681 (Puerto Rico); Evans, D. R. [Department of Physics and Astronomy, University of Georgia, Athens, Georgia 30602 (United States)] [Department of Physics and Astronomy, University of Georgia, Athens, Georgia 30602 (United States); Dennis, W. M. [Department of Physics and Astronomy, University of Georgia, Athens, Georgia 30602 (United States)] [Department of Physics and Astronomy, University of Georgia, Athens, Georgia 30602 (United States); Liu, Huimin [Department of Physics, University of Puerto Rico, Mayaguez, Puerto Rico 00681 (Puerto Rico)] [Department of Physics, University of Puerto Rico, Mayaguez, Puerto Rico 00681 (Puerto Rico); Zhu, Jing [Department of Materials Science and Engineering, Tsinghua University, Beijing, (China)] [Department of Materials Science and Engineering, Tsinghua University, Beijing, (China); Yen, W. M. [Department of Physics and Astronomy, University of Georgia, Athens, Georgia 30602 (United States)] [Department of Physics and Astronomy, University of Georgia, Athens, Georgia 30602 (United States)

    2000-09-15T23:59:59.000Z

    CaS:Eu{sup 2+},Tm{sup 3+} is a persistent red phosphor. Thermoluminescence was measured under different excitation and thermal treatment conditions. The results reveal that the charge defects, created by substituting Tm{sup 3+} for Ca{sup 2+}, serve as hole traps for the afterglow at room temperature. Tm{sup 3+} plays the role of deep electron trapping centers, capturing electrons either through the conduction band or directly from the excited Eu{sup 2+} ions. These two processes, in which two different sites of Tm{sup 3+} are involved, correspond to two traps with different depths. (c) 2000 American Institute of Physics.

  8. Temperature dependent band offsets in PbSe/PbEuSe quantum well heterostructures

    SciTech Connect (OSTI)

    Simma, M.; Bauer, G.; Springholz, G. [Institut fuer Halbleiter und Festkoerperphysik, Johannes Kepler Universitaet, A-4040 Linz (Austria)

    2012-10-22T23:59:59.000Z

    The band offsets of PbSe/Pb{sub 1-x}Eu{sub x}Se multi-quantum wells grown by molecular beam epitaxy are determined as a function of temperature and europium content using temperature-modulated differential transmission spectroscopy. The confined quantum well states in the valence and conduction bands are analyzed using a k{center_dot}p model with envelope function approximation. From the fit of the experimental data, the normalized conduction band offset is determined as 0.45{+-}0.15 of the band gap difference, independently of Eu content up to 14% and temperature from 20 to 300 K.

  9. Dubuque generation station, Dubuque, Iowa

    SciTech Connect (OSTI)

    Peltier, R.

    2008-10-15T23:59:59.000Z

    Alliant Energy's Dubuque generation station is a fine example of why small does not mean insignificant in the power generation industry. This winner of the EUCG best performer award in the small plant category shows that its operating excellence towers over that of many larger and much newer coal-fired power plants. The plant has three operating units with boilers originally designed for Illinois basin coal but now Powder River Basin coal makes up 75% of the coal consumed. The boilers can also burn natural gas. 4 photos.

  10. If it's Broken, Don't Fix it: The Government of the Euro area in the EU "Reform Treaty"

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    If it's Broken, Don't Fix it: The Government of the Euro area in the EU "Reform Treaty" N 2007: The Government of the Euro area in the EU "Reform Treaty" loi Laurent OFCE (Sciences-po Center for Economic failure. This paper examines the reforms of the "economic governance" of the euro area proposed

  11. Japan, EU adamant about their proposals to host ITER, put off negotiations to next year; Joint construction plan involving Japan,

    E-Print Network [OSTI]

    Japan, EU adamant about their proposals to host ITER, put off negotiations to next year; Joint construction plan involving Japan, U.S. South Korea also emerging NIHON KEIZAI, December 20, 2004 Japan are likely to enter a crucial stage early in the next year. In addition to Japan and the EU, the United

  12. Thermochemically recuperated and steam cooled gas turbine system

    DOE Patents [OSTI]

    Viscovich, Paul W. (Longwood, FL); Bannister, Ronald L. (Winter Springs, FL)

    1995-01-01T23:59:59.000Z

    A gas turbine system in which the expanded gas from the turbine section is used to generate the steam in a heat recovery steam generator and to heat a mixture of gaseous hydrocarbon fuel and the steam in a reformer. The reformer converts the hydrocarbon gas to hydrogen and carbon monoxide for combustion in a combustor. A portion of the steam from the heat recovery steam generator is used to cool components, such as the stationary vanes, in the turbine section, thereby superheating the steam. The superheated steam is mixed into the hydrocarbon gas upstream of the reformer, thereby eliminating the need to raise the temperature of the expanded gas discharged from the turbine section in order to achieve effective conversion of the hydrocarbon gas.

  13. Thermochemically recuperated and steam cooled gas turbine system

    DOE Patents [OSTI]

    Viscovich, P.W.; Bannister, R.L.

    1995-07-11T23:59:59.000Z

    A gas turbine system is described in which the expanded gas from the turbine section is used to generate the steam in a heat recovery steam generator and to heat a mixture of gaseous hydrocarbon fuel and the steam in a reformer. The reformer converts the hydrocarbon gas to hydrogen and carbon monoxide for combustion in a combustor. A portion of the steam from the heat recovery steam generator is used to cool components, such as the stationary vanes, in the turbine section, thereby superheating the steam. The superheated steam is mixed into the hydrocarbon gas upstream of the reformer, thereby eliminating the need to raise the temperature of the expanded gas discharged from the turbine section in order to achieve effective conversion of the hydrocarbon gas. 4 figs.

  14. WHAT IS A NETWORK? (Gas and Electricity) A complex, interconnected group or

    E-Print Network [OSTI]

    Wright, Francis

    WHAT IS A NETWORK? (Gas and Electricity) A complex, interconnected group or system Electricity and Gas: A system used to distribute electricity and gas around the world/certain area, by compromising to minimise costs and generate the most electricity and gas as possible, which maximises profits

  15. On optimization of sensor selection for aircraft gas turbine engines Ramgopal Mushini

    E-Print Network [OSTI]

    Simon, Dan

    for generating an optimal sensor set [3]. 3. Aircraft gas turbine engines An aircraft gas turbine engineOn optimization of sensor selection for aircraft gas turbine engines Ramgopal Mushini Cleveland sets for the problem of aircraft gas turbine engine health parameter estimation. The performance metric

  16. Last Updated: 05.30.2013 Part I: California Uses for Natural Gas

    E-Print Network [OSTI]

    1 Last Updated: 05.30.2013 Part I: California Uses for Natural Gas Natural gas is the second most shares of natural gas consumed by end-use sectors and in-state electricity generation. Table 1: Natural and Energy Reports. * Does not include out-of-state natural gas used to produce electricity that is imported

  17. LANDFILL-GAS-TO-ENERGY PROJECTS: AN ANALYSIS OF NET PRIVATE AND SOCIAL BENEFITS

    E-Print Network [OSTI]

    Jaramillo, Paulina

    Materials Table A1: Model Results for West Lake Landfill WEST LAKE IC Engine Gas Turbine Steam Turbine Landfill WEST COUNTY IC Engine Gas Turbine Steam Turbine Average Landfill Gas Generation (mmcf/yr) 1,075 1,735 $1,250 Table A3: Model Results for Modern Landfill MODERN IC Engine Gas Turbine Steam Turbine Average

  18. Detection of gas leakage

    DOE Patents [OSTI]

    Thornberg, Steven (Peralta, NM); Brown, Jason (Albuquerque, NM)

    2012-06-19T23:59:59.000Z

    A method of detecting leaks and measuring volumes as well as an apparatus, the Power-free Pump Module (PPM), that is a self-contained leak test and volume measurement apparatus that requires no external sources of electrical power during leak testing or volume measurement, where the invention is a portable, pneumatically-controlled instrument capable of generating a vacuum, calibrating volumes, and performing quantitative leak tests on a closed test system or device, all without the use of alternating current (AC) power. Capabilities include the ability is to provide a modest vacuum (less than 10 Torr), perform a pressure rise leak test, measure the gas's absolute pressure, and perform volume measurements. All operations are performed through a simple rotary control valve which controls pneumatically-operated manifold valves.

  19. Fuel Interchangeability Considerations for Gas Turbine Combustion

    SciTech Connect (OSTI)

    Ferguson, D.H.

    2007-10-01T23:59:59.000Z

    In recent years domestic natural gas has experienced a considerable growth in demand particularly in the power generation industry. However, the desire for energy security, lower fuel costs and a reduction in carbon emissions has produced an increase in demand for alternative fuel sources. Current strategies for reducing the environmental impact of natural gas combustion in gas turbine engines used for power generation experience such hurdles as flashback, lean blow-off and combustion dynamics. These issues will continue as turbines are presented with coal syngas, gasified coal, biomass, LNG and high hydrogen content fuels. As it may be impractical to physically test a given turbine on all of the possible fuel blends it may experience over its life cycle, the need to predict fuel interchangeability becomes imperative. This study considers a number of historical parameters typically used to determine fuel interchangeability. Also addressed is the need for improved reaction mechanisms capable of accurately modeling the combustion of natural gas alternatives.

  20. Gas permeable electrode for electrochemical system

    DOE Patents [OSTI]

    Ludwig, F.A.; Townsend, C.W.

    1989-09-12T23:59:59.000Z

    An electrode apparatus is described which is adapted for use in electrochemical systems having an anode compartment and a cathode compartment in which gas and ions are produced and consumed in the compartments during generation of electrical current. The electrode apparatus includes a membrane for separating the anode compartment from the cathode compartment wherein the membrane is permeable to both ions and gas. The cathode and anode for the assembly are provided on opposite sides of the membrane. During use of the membrane-electrode apparatus in electrochemical cells, the gas and ions generated at the cathode or anode migrate through the membrane to provide efficient transfer of gas and ions between the anode and cathode compartments. 3 figs.

  1. Gas deliverability: Flexibility within the system

    SciTech Connect (OSTI)

    Tom, D. [Associated Power Services, Inc., Houston, TX (United States)

    1995-12-31T23:59:59.000Z

    This paper presents the text of my comments to the national conference on Meeting the Challenges of the New Energy Industry: The Driving Forces Facing Electric Power Generators and the Natural Gas Industry. The F.E.R.C. gas tariffs and operational characteristics of the various gas pipeline systems contain numerous mechanisms and provide flexibility to their shippers. Pipeline customers are empowered with the ability to maximize their supply portfolio by utilizing the appropriate blend of transportation and storage services that best fits their demand needs. I have presented a brief overview of supply availability, seven topics that can enhance assurance of system delivery and an update on The Natural Gas Council`s Electric Generation Task Force.

  2. Gas Storage Act (Illinois)

    Broader source: Energy.gov [DOE]

    Any corporation which is engaged in or desires to engage in, the distribution, transportation or storage of natural gas or manufactured gas, which gas, in whole or in part, is intended for ultimate...

  3. Gas Companies Program (Tennessee)

    Broader source: Energy.gov [DOE]

    The Gas Companies program is a set of rules that encourage the development of the natural gas industry in Tennessee. They empower gas companies to lay piped and extend conductors through the...

  4. Gas Utilities (Maine)

    Broader source: Energy.gov [DOE]

    Rules regarding the production, sale, and transfer of manufactured gas will also apply to natural gas. This section regulates natural gas utilities that serve ten or more customers, more than one...

  5. Gas Utilities (New York)

    Broader source: Energy.gov [DOE]

    This chapter regulates natural gas utilities in the State of New York, and describes standards and procedures for gas meters and accessories, gas quality, line and main extensions, transmission and...

  6. Future of Natural Gas

    Office of Environmental Management (EM)

    of Natural Gas Bill Eisele, CEM SC Electric & Gas Co Hosted by: FEDERAL UTILITY PARTNERSHIP WORKING GROUP SEMINAR November 5-6, 2014 Cape Canaveral. Florida Agenda * Gas Facts *...

  7. Industrial Gas Turbines

    Broader source: Energy.gov [DOE]

    A gas turbine is a heat engine that uses high-temperature, high-pressure gas as the working fluid. Part of the heat supplied by the gas is converted directly into mechanical work. High-temperature,...

  8. Supervisory Natural Gas Analyst

    Broader source: Energy.gov [DOE]

    The Department of Energys Office of Fossil Energy, Office of Oil and Natural Gas, Office of Oil and Gas Global Security and Supply (FE) is responsible for regulating natural gas imports and exports...

  9. Les dterminants du prix du carbone sur le march europen des quotas Carbon price drivers in the EU Emissions Trading Scheme

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    in the EU Emissions Trading Scheme Emilie Alberola1 et Julien Chevallier2 Rsum: L'article examine le prix des quotas durant la premire priode (2005-2007) de l'European Union Emissions Trading Scheme (EU

  10. NATURAL GAS RESOURCES IN DEEP SEDIMENTARY BASINS

    SciTech Connect (OSTI)

    Thaddeus S. Dyman; Troy Cook; Robert A. Crovelli; Allison A. Henry; Timothy C. Hester; Ronald C. Johnson; Michael D. Lewan; Vito F. Nuccio; James W. Schmoker; Dennis B. Riggin; Christopher J. Schenk

    2002-02-05T23:59:59.000Z

    From a geological perspective, deep natural gas resources are generally defined as resources occurring in reservoirs at or below 15,000 feet, whereas ultra-deep gas occurs below 25,000 feet. From an operational point of view, ''deep'' is often thought of in a relative sense based on the geologic and engineering knowledge of gas (and oil) resources in a particular area. Deep gas can be found in either conventionally-trapped or unconventional basin-center accumulations that are essentially large single fields having spatial dimensions often exceeding those of conventional fields. Exploration for deep conventional and unconventional basin-center natural gas resources deserves special attention because these resources are widespread and occur in diverse geologic environments. In 1995, the U.S. Geological Survey estimated that 939 TCF of technically recoverable natural gas remained to be discovered or was part of reserve appreciation from known fields in the onshore areas and State waters of the United. Of this USGS resource, nearly 114 trillion cubic feet (Tcf) of technically-recoverable gas remains to be discovered from deep sedimentary basins. Worldwide estimates of deep gas are also high. The U.S. Geological Survey World Petroleum Assessment 2000 Project recently estimated a world mean undiscovered conventional gas resource outside the U.S. of 844 Tcf below 4.5 km (about 15,000 feet). Less is known about the origins of deep gas than about the origins of gas at shallower depths because fewer wells have been drilled into the deeper portions of many basins. Some of the many factors contributing to the origin of deep gas include the thermal stability of methane, the role of water and non-hydrocarbon gases in natural gas generation, porosity loss with increasing thermal maturity, the kinetics of deep gas generation, thermal cracking of oil to gas, and source rock potential based on thermal maturity and kerogen type. Recent experimental simulations using laboratory pyrolysis methods have provided much information on the origins of deep gas. Technologic problems are one of the greatest challenges to deep drilling. Problems associated with overcoming hostile drilling environments (e.g. high temperatures and pressures, and acid gases such as CO{sub 2} and H{sub 2}S) for successful well completion, present the greatest obstacles to drilling, evaluating, and developing deep gas fields. Even though the overall success ratio for deep wells is about 50 percent, a lack of geological and geophysical information such as reservoir quality, trap development, and gas composition continues to be a major barrier to deep gas exploration. Results of recent finding-cost studies by depth interval for the onshore U.S. indicate that, on average, deep wells cost nearly 10 times more to drill than shallow wells, but well costs and gas recoveries vary widely among different gas plays in different basins. Based on an analysis of natural gas assessments, many topical areas hold significant promise for future exploration and development. One such area involves re-evaluating and assessing hypothetical unconventional basin-center gas plays. Poorly-understood basin-center gas plays could contain significant deep undiscovered technically-recoverable gas resources.

  11. Alternative Fuels and Chemicals from Synthesis Gas

    SciTech Connect (OSTI)

    Peter Tijrn

    2003-01-02T23:59:59.000Z

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  12. A Wood-Fired Gas Turbine Plant

    E-Print Network [OSTI]

    Powell, S. H.; Hamrick, J. T.

    A WOOD-FIRED GAS TURBINE PLANT Sam H. Powell, Tennessee Valley Authority, Chattanooga, Tennessee Joseph T. Hamrick, Aerospace Research Corporation, RBS Electric, Roanoke, VA Abstract This paper covers the research and development of a wood...-fired gas turbine unit that is used for generating electricity. The system uses one large cyclonic combustor and a cyclone cleaning system in series to provide hot gases to drive an Allison T-56 aircraft engine (the industrial version is the 50l-k). A...

  13. Alternative Fuels and Chemicals From Synthesis Gas

    SciTech Connect (OSTI)

    none

    1998-07-01T23:59:59.000Z

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  14. Forschung und EU-Hochschulbro, Technologietransfer Anschrift: Brhlstr. 27 30169 Hannover Tel.: (0511) 762 4091 Fax: 3009 dezernat4@zuv.uni-hannover.de

    E-Print Network [OSTI]

    Nejdl, Wolfgang

    for a Greener Agriculture (ERA-Net ICT-AGRI) 12 6.1.2. EU/BMELV: Transnationale Projekte im Bereich Bioenergie 10. Agrarwissenschaften 17 10.1.1. EU/BMELV: Transnationale Projekte im Bereich "Agricultural Umweltschutzprojekten 17 11.1.2. EU/BMELV: ICT and Automation for a Greener Agriculture (ERA-Net ICT-AGRI) 18 11.1.3. EU

  15. Natural Gas Monthly Update

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    other liquids including biofuels and natural gas liquids. Natural Gas Exploration and reserves, storage, imports and exports, production, prices, sales. Electricity Sales, revenue...

  16. Gas Production Tax (Texas)

    Broader source: Energy.gov [DOE]

    A tax of 7.5 percent of the market value of natural gas produced in the state of Texas is imposed on every producer of gas.

  17. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    8 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  18. Natural gas dehydration apparatus

    DOE Patents [OSTI]

    Wijmans, Johannes G; Ng, Alvin; Mairal, Anurag P

    2006-11-07T23:59:59.000Z

    A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.

  19. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    6 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  20. Historical Natural Gas Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    7 The Historical Natural Gas Annual contains historical information on supply and disposition of natural gas at the national, regional, and State level as well as prices at...

  1. Vanadium hydride deuterium-tritium generator

    DOE Patents [OSTI]

    Christensen, L.D.

    1980-03-13T23:59:59.000Z

    A pressure controlled vanadium hydride gas generator was designed to provide deuterium-tritium gas in a series of pressure increments. A high pressure chamber filled with vanadium-deuterium-tritium hydride is surrounded by a heater which controls the hydride temperature. The heater is actuated by a power controller which responds to the difference signal between the actual pressure signal and a programmed pressure signal.

  2. Co-generation: a new energy system to generate both steam and electricity

    SciTech Connect (OSTI)

    Carraway, P.M.; Kloth, T.L.; Bull, A.D.

    1981-01-01T23:59:59.000Z

    A discussion is presented of the installation and operation of a co-generation system at Tenneco's Fee ''C'' Lease, whereby hot combustion gas from a turbine fueled by gas or lease crude will be used to generate steam for enhanced recovery, with the same turbine providing the power to generate electricity for sale to a utility. A summary is also given of the history of the project, some of the contractual requirements, the physical layout of the system, component descriptions, environmental considerations, and the composition of the final system.

  3. Fact sheet EU poll illegal timber trade Illegal logging and related timber trade

    E-Print Network [OSTI]

    March 2009 Fact sheet EU poll illegal timber trade Illegal logging and related timber trade Illegal level is needed to halt the trade in illegal timber and timber products on the European market trade. It has clarified obligations for all companies in the supply chain to prove the legality

  4. Water Research 39 (2005) 239247 Biosorption of La, Eu and Yb using Sargassum biomass

    E-Print Network [OSTI]

    Volesky, Bohumil

    Water Research 39 (2005) 239­247 Biosorption of La, Eu and Yb using Sargassum biomass Vivian Diniz-loaded biomass was studied. The ion exchange sorption mechanism was confirmed by the release of calcium ions from the biomass that matched the total number of metal and protons removed from the solution. The metal binding

  5. Influence of high magnetic field on the luminescence of Eu{sup 3+}-doped glass ceramics

    SciTech Connect (OSTI)

    Jiang, Wei; Chen, Weibo; Chen, Ping; Xu, Beibei; Zheng, Shuhong; Guo, Qiangbing; Liu, Xiaofeng, E-mail: xfliu@zju.edu.cn, E-mail: qjr@zju.edu.cn [State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou, Zhejiang 310027 (China); Zhang, Junpei; Han, Junbo [Wuhan National High Magnetic field Center, Huazhong University of Science and Technology, Wuhan, Hubei 430074 (China); Qiu, Jianrong, E-mail: xfliu@zju.edu.cn, E-mail: qjr@zju.edu.cn [State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou, Zhejiang 310027 (China); State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou, Guangdong 510640 (China)

    2014-09-28T23:59:59.000Z

    Rare earth (RE) doped materials have been widely exploited as the intriguing electronic configuration of RE ions offers diverse functionalities from optics to magnetism. However, the coupling of magnetism with photoluminescence (PL) in such materials has been rarely reported in spite of its fundamental significance. In the present paper, the effect of high pulsed magnetic field on the photoluminescence intensity of Eu{sup 3+}-doped nano-glass-ceramics has been investigated. In our experiment, Eu-doped oxyfluoride glass and glass ceramic were prepared by the conventional melt-quenching process and controlled heat treatment. The results demonstrate that the integrated PL intensity of Eu{sup 3+} decreases with the enhancement of magnetic field, which can be interpreted in terms of cooperation effect of Zeeman splitting and magnetic field induced change in site symmetry. Furthermore, as a result of Zeeman splitting, both blue and red shift in the emission peaks of Eu{sup 3+} can be observed, and this effect becomes more prominent with the increase of magnetic field. Possible mechanisms associated with the observed magneto-optical behaviors are suggested. The results of the present paper may open a new gate for modulation of luminescence by magnetic field and remote optical detection of magnetic field.

  6. GEE Workshop, Mnchen, 6 Juni 2008 The EU Policy Framework for the Promotion

    E-Print Network [OSTI]

    production but also distribution and end-use pose enormous challenges ­ Hydrogen and fuel cells are still to hydrogen and fuel cell development ­ Regional dimension/cluster policy We therefore address the following questions ­ To what extent is the current EU policy framework conducive to hydrogen and fuel cell

  7. Eos,Vol. 85, No. 46, 16 November 2004 use among European Union (EU) member

    E-Print Network [OSTI]

    Wang, Chunzai

    Eos,Vol. 85, No. 46, 16 November 2004 use among European Union (EU) member states applications of the atlas contents should have no problem doing so. The price of the atlas is a hefty $310 the substantial amount of information contained within the atlas,the price represents a good value,and university

  8. TRANSFORMING THE EUROPEAN ENERGY SYSTEM: MEMBER STATES' PROSPECTS WITHIN THE EU FRAMEWORK

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    and energy policy; National Renewable Action Plans (NREAPs); environmental federalism; mitigation scenarios energies in the official National Renewable Energy Action Plans (NREAPs) (EEA, 2012). In 2011, the EuropeanTRANSFORMING THE EUROPEAN ENERGY SYSTEM: MEMBER STATES' PROSPECTS WITHIN THE EU FRAMEWORK BRIGITTE

  9. HEAT ROADMAP EUROPE 2050 SECOND PRE-STUDY FOR THE EU27

    E-Print Network [OSTI]

    Kolaei, Alireza Rezania

    HEAT ROADMAP EUROPE 2050 SECOND PRE-STUDY FOR THE EU27 By Aalborg University David Connolly Brian in various reports and studies, i.e. in the Energy Efficiency of the Energy Roadmap 2050 published) of the Energy Roadmap are over-ambitious as regards the reduction of final heat demands in buildings (72

  10. Carbon Prices during the EU ETS Phase II: Dynamics and Volume Analysis

    E-Print Network [OSTI]

    Boyer, Edmond

    Universit Paris Dauphine Abstract The European Union Emissions Trading Scheme (EU ETS) is the largest emissions trading scheme to date. This article summarizes the principle elements behind the trading system of reducing CO2 emissions and achieving the Kyoto Protocol target. The European Union Emissions Trading Scheme

  11. The knowledge economy in Europe A report prepared for the 2007 EU Spring Council

    E-Print Network [OSTI]

    Chen-Burger, Yun-Heh (Jessica)

    The knowledge economy in Europe A report prepared for the 2007 EU Spring Council Prepared by Ian. Knowledge industry employment in Europe 6 4. Moving towards a knowledge based economy in Europe 7 5 10 8. Investing in knowledge 11 9. Next steps 23 Sponsors for the knowledge economy programme include

  12. EU to build experimental fusion reactor Associated Press, THE JERUSALEM POST Sep 25, 2006

    E-Print Network [OSTI]

    EU to build experimental fusion reactor Associated Press, THE JERUSALEM POST Sep 25, 2006 European Union nations on Monday endorsed a pact to build an experimental fusion reactor with the aim, China, Japan, South Korea and Russia - also aim to ratify the International Thermonuclear Experimental

  13. -News Home Help Chirac defends planned EU arms sales to China to nervous Japan

    E-Print Network [OSTI]

    -News Home Help Chirac defends planned EU arms sales to China to nervous Japan Sun Mar 27,11:33 AM Union ( - ) arms embargo on China, telling a nervous Japan the move would not entail transfers ban, acknowledged that Japan was worried about arms sales to its neighbor and growing rival but said

  14. ASTRONOMY TO INSPIRE AND EDUCATE YOUNG CHILDREN EU-UNAWE Lorentz Center Workshop

    E-Print Network [OSTI]

    Galis, Frietson

    Africa (provisional title) (10 min) Right Honorable Dr. E. N. N. Ngcobo MP, Chair, South African between Europe and Africa Prof. T Riera, MEP, EU Parliamentary Committee: Industry, Research and Energy: Astronomy for Development, South Africa Reaching disadvantaged children using astronomy and space (5 min

  15. Summary of the 1st EuCAN Workshop "Universities meet laboratories (ULA2014)"

    E-Print Network [OSTI]

    Aleksan, R; Appleby, R; Arduini, G; Assmann, R; Aulenbacher, K; Bambade, P; Barletta, W; Boine-Frankenheim, O; Burrows, P; Faus-Golfe, A; Guiducci, S; Herr, W; Pavlovi?, M; Podlech, H; Rinolfi, L; Rivkin, L; Russenschuck, S; Schleiff, E; Seidel, M; Stoecker, H; Stroth, J; Valloni, A; Ziemann, V

    2014-01-01T23:59:59.000Z

    The 1st EuCAN workshop ULA2014 illuminated the interplay of universities and laboratories. The workshop took place at the Faculty of Applied Physics of the Goethe-University Frankfurt from 30 September to 1 October 2014. The 40 participants (see Fig. 1) mainly came from European countries.

  16. EU in push for support on nuclear fusion reactor September 26, 2004

    E-Print Network [OSTI]

    to obtain power through nuclear fusion, a clean energy source. But views are split on where the ITER reactor, estimated to cost around $10 billion over 30 years, should be based. While the EU, backed by China yesterday. Diplomats said the US resistance seemed to be political rather than based on scientific grounds

  17. An EIE/Altener project Co-funded by the EU Commission

    E-Print Network [OSTI]

    and energy aspects of the biogas production by centralised co-digestion in selected areas of six EU countries-technical barriers for the implementation and development of biogas from centralised co-digestion in the studied Assessment of a Centralised co-digestion Plant hypothetically sited in Aveyron, Midi Pyrenees France June

  18. An EIE/Altener project Co-funded by the EU Commission

    E-Print Network [OSTI]

    is to assess the economic, environmental and energy aspects of the biogas production by centralised co-digestion and processed in digesting tanks for 15 days. During this period the biogas emerges and is collected. After of Biogas for Electricity and Heat Production in EU countries. Economic and Environmental Benefits of Biogas

  19. Call title: ENERGY -EU India Call Call identifier: FP7-ENERGY-2010-INDIA

    E-Print Network [OSTI]

    Milano-Bicocca, Universit

    Collaborative ProjectAREA ENERGY.2.1: PHOTOVOLTAICS ENERGY.2010.2.1-3: Development of new concentrator modules and field performance evaluation of Concentrated PV systems - EU-India Call Collaborative Project AREA will be constituted if there is a sufficient number of good quality proposals. It will be used if extra budget becomes

  20. CARBON LEAKAGE AND CAPACITY-BASED ALLOCATIONS. IS THE EU RIGHT?

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    petroleum...). Three main approaches have been proposed: output based allocation (Aus- tralia, California makes the dierence. A calibration of the model is used to evaluate the EU scheme for the cement sec- tor and Business Economics (Guy Meunier and Jean-Pierre Ponssard). 1 hal-00672907,version1-22Feb2012 #12

  1. EU Informal Competitiveness Council (Ian Lucas, Parliamentary Under-Secretary (Business and Regulatory

    E-Print Network [OSTI]

    prioritised recovery from the economic crisis and financial stability, focusing on external (i.e. outside EU-efficient economy. There was general support among member states that economic growth and environmental protection to be strengthened and that the mandate of the Centre for Renewable Energy Systems Technology (CREST) advisory

  2. Options introduction and volatility in the EU ETS1 Julien Chevallier 2

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    of derivatives instruments on the underlying crude oil market and derived products. Thus, detecting whether identify a potential destabilizing effect of the introduction of options on the underlying market (EU ETS either decrease (due to more market depth) or increase (due to more speculation) volatility

  3. STYRIAN ACADEMY for Sustainable Energies | http://styrianacademy.eu Graz University of Technology

    E-Print Network [OSTI]

    STYRIAN ACADEMY for Sustainable Energies | http://styrianacademy.eu Graz University of Technology #12;ABOUT THE STYRIAN ACADEMY The STYRIAN ACADEMY is a unique international European life. The STYRIAN ACADEMY addresses business, science and politics as well as excellent students and an interested

  4. Preprint 24th EU PVSEC, 2009, Hamburg FITTING OF LATERAL RESISTANCES IN SILICON SOLAR CELLS

    E-Print Network [OSTI]

    Junk, Michael

    Preprint 24th EU PVSEC, 2009, Hamburg FITTING OF LATERAL RESISTANCES IN SILICON SOLAR CELLS cell from electroluminescence (EL) is introduced. A two-dimensional model of the solar cell screen printed monocrystalline silicon solar cell are shown and the influence of lateral diffusion

  5. International Internship at EuCham For students participating in LLP-ERASMUS programme

    E-Print Network [OSTI]

    Schler, Axel

    International Internship at EuCham For students participating in LLP-ERASMUS programme We coordination. We offer an internship in an international environment, in which you can both gain knowledge Minimum duration of 6 months Internship takes place in Budapest Internship is unpaid Official language

  6. -News Home Help EU again warns could mount nuclear project without Japan

    E-Print Network [OSTI]

    revealed. news web sites The European Commission ( - ) is set to propose that negotiating strategy next the International Thermonuclear Experimental Reactor (ITER). news web sites Talks in Vienna on Tuesday made some support the Japanese bid -- and Russia and China, which back the EU bid. news web sites Ambassadors from

  7. -News Home Help EU offers 'sweetener' to Japan to let France host nuclear project

    E-Print Network [OSTI]

    to host a revolutionary nuclear fusion project. news web sites "I cannot elaborate on the sweetener, but I Wednesday after talks in Vienna on the International Thermonuclear Experimental Reactor (ITER). news web ( - ) -- which have supported the Japanese bid -- plus Russia and China, which back the EU bid.news web sites

  8. A nuclear magnetic resonance probe of Fe-Al and Al20V2Eu intermetallics

    E-Print Network [OSTI]

    Chi, Ji

    2009-05-15T23:59:59.000Z

    Al-rich Fe-Al systems (FeAl2, Fe2 Al5 and Fe4Al13) and Al20V2Eu have complicated structures with quasicrystal-like features making these materials potentially of interest for magnetic behavior. However, there is not much work on these materials...

  9. pEtrolEuM EnginEEring College of Engineering and Mines

    E-Print Network [OSTI]

    Hartman, Chris

    pEtrolEuM EnginEEring College of Engineering and Mines Department of Petroleum Engineering 907 engineering offers a unique look at the challenging problems confronting the petroleum industry. This program and engineering science. Courses in petroleum engineering deal with drilling, formation evaluation, production

  10. DeclanButler,Paris Japan and the European Union (EU) will this

    E-Print Network [OSTI]

    been withdrawnfromthecompetition. The ITER partners -- the EU, Japan, Russia, Canada, China, South." Adealwillinvolveconsensusonengineer- ing, costs, culture and politics, though per- haps not in that order. On paper, the French partners Korea and China. The amount of money each party is prepared to put on the table this week could

  11. EU warns of breakaway plans on nuclear project 24 September 2004

    E-Print Network [OSTI]

    . He argued the project could be launched with Russia paying 10 percent of the costs and China -- which is backed by South Korea, China, the United States and Russia as well as the EU. But the European support from China and Russia. South Korea and the United States appear to prefer the Japanese site

  12. Generation Planning (pbl/generation)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist.Newof EnergyFundingGene ControlsCounselGeneral User Generation

  13. Plasma reforming and partial oxidation of hydrocarbon fuel vapor to produce synthesis gas and/or hydrogen gas

    DOE Patents [OSTI]

    Kong, Peter C.; Detering, Brent A.

    2003-08-19T23:59:59.000Z

    Methods and systems for treating vapors from fuels such as gasoline or diesel fuel in an internal combustion engine, to form hydrogen gas or synthesis gas, which can then be burned in the engine to produce more power. Fuel vapor, or a mixture of fuel vapor and exhaust gas and/or air, is contacted with a plasma, to promote reforming reactions between the fuel vapor and exhaust gas to produce carbon monoxide and hydrogen gas, partial oxidation reactions between the fuel vapor and air to produce carbon monoxide and hydrogen gas, or direct hydrogen and carbon particle production from the fuel vapor. The plasma can be a thermal plasma or a non-thermal plasma. The plasma can be produced in a plasma generating device which can be preheated by contact with at least a portion of the hot exhaust gas stream, thereby decreasing the power requirements of the plasma generating device.

  14. Plasma Reforming And Partial Oxidation Of Hydrocarbon Fuel Vapor To Produce Synthesis Gas And/Or Hydrogen Gas

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Detering, Brent A. (Idaho Falls, ID)

    2004-10-19T23:59:59.000Z

    Methods and systems are disclosed for treating vapors from fuels such as gasoline or diesel fuel in an internal combustion engine, to form hydrogen gas or synthesis gas, which can then be burned in the engine to produce more power. Fuel vapor, or a mixture of fuel vapor and exhaust gas and/or air, is contacted with a plasma, to promote reforming reactions between the fuel vapor and exhaust gas to produce carbon monoxide and hydrogen gas, partial oxidation reactions between the fuel vapor and air to produce carbon monoxide and hydrogen gas, or direct hydrogen and carbon particle production from the fuel vapor. The plasma can be a thermal plasma or a non-thermal plasma. The plasma can be produced in a plasma generating device which can be preheated by contact with at least a portion of the hot exhaust gas stream, thereby decreasing the power requirements of the plasma generating device.

  15. Why Condensing Steam Turbines are More Efficient than Gas Turbines

    E-Print Network [OSTI]

    Nelson, K. E.

    1988-01-01T23:59:59.000Z

    with gas in a combustion chamber. The gas burns and the hot combustion gases are expanded through a turbine. generating electricity. The gases exit at about 1000oF. slightly above atmospheric pressure. They enter a heat recovery unit. which is a series... statement. however, is relevant to value. GAS TURBINE CYCLE Figure :> shows the enthalpy analysis for a gas turbine cycle employing a heat recovery unit for steam generation. Air enters the compressor where it's boosted to about 190 psi and mixed...

  16. Flammable gas tank safety program: Technical basis for gas analysis and monitoring

    SciTech Connect (OSTI)

    Sherwood, D.J.

    1995-09-08T23:59:59.000Z

    Flammable gases generated in radioactive liquids. Twenty-five high level radioactive liquid waste storage tanks located underground at the Hanford Site are on a Flammable Gas Watch List because they contain waste which tends to retain the gases generated in it until rather large quantities are available for sudden release to the tank head space; if a tank is full it has little dome space, and a flammable concentration of gases could be produced--even if the tank is ventilated. If the waste has no tendency to retain gas generated in it then a continual flammable gas concentration in the tank dome space is established by the gas production rate and the tank ventilation rate (or breathing rate for unventilated tanks); this is also a potential problem for Flammable Gas Watch List tanks, and perhaps other Hanford tanks too. All Flammable Gas Watch List tanks will be fitted with Standard Hydorgen Monitoring Systems so that their behavior can be observed. In some cases, such as tank 241-SY-101, the data gathered from such observations will indicate that tank conditions need to be mitigated so that gas release events are either eliminated or rendered harmless. For example, a mixer pump was installed in tank 241-SY-101; operating the pump stirs the waste, replacing the large gas release events with small releases of gas that are kept below twenty-five percent of the lower flammability limit by the ventilation system. The concentration of hydrogen measured in Hanford waste tanks is greater than that of any other flammable gas. Hydrogen levels measured with a Standard Hydrogen Monitoring System in excess of 0.6 volume percent will cause Westinghouse Hanford Company to consider actions which will decrease the amount of flammable gas in the tank

  17. Development of fission gas swelling and release models for metallic nuclear fuels

    E-Print Network [OSTI]

    Andrews, Nathan Christopher

    2012-01-01T23:59:59.000Z

    Fuel swelling and fission gas generation for fast reactor fuels are of high importance since they are among the main limiting factors in the development of metallic fast reactor fuel. Five new fission gas and swelling ...

  18. THE EFFECTS OF FLAME TEMPERATURE, PARTICLE SIZE AND EUROPIUM DOPING CONCENTRATION ON THE PROPERTIES OF Y2O3:EU PARTICLES FORMED IN A FLAME AEROSOL PROCESS

    E-Print Network [OSTI]

    Yim, Hoon

    2010-07-14T23:59:59.000Z

    Y2O3:Eu particles are phosphors that have found wide applications. Flamesynthesized Y2O3:Eu particles may have either the cubic or the monoclinic structure. The effects of particle size and Eu doping concentration on crystal structure...

  19. Structural Properties of Eu-Doped GaN Investigated by Raman Spectroscopy

    SciTech Connect (OSTI)

    Senawiratne, J; Xia, Y; Detchprohm, T; Tringe, J W; Stevens, C G; Wetzel, C

    2006-06-20T23:59:59.000Z

    Rare-earth (RE) impurities doped GaN are highly promising candidates for light emitting device applications due to their efficient electroluminescence properties at room temperature. Among those, Eu doped GaN has been identified as an excellent material for the red spectral region due to its strong emission at 620 nm. As a transition internal to the Eu doping atom (4f-4f), light emission originates in a much smaller complex than the more flexibly controllable quantum structures of wells, wires, and dots. This is thought to make the center less susceptible to structural defects and in particular radiation damage in the lattice host. Nevertheless, the lattice host is crucial for providing the excitation in from of free electrons and holes. In this respect, the actual lattice site Eu occupies in the host lattice, i.e. in GaN, is important. A large fraction of Eu atoms are typically inactive which must be attributed to their lattice site and local environment. GaN films implanted with Eu to concentrations of {approx}10{sup 18} cm{sup -3} were subjected to a highly directed beam of 500 keV He{sup +} at a dose of 5 x 10{sup 14} cm{sup -2}. By means of a shadow mask, irradiated and unexposed regions lie very close to each other on the same sample. We used optical and structural analysis to identify the exerted radiation damage. At the full radiation dose, photoluminescence intensity has decayed to {approx}0.01 of its initial value. From the dose dependence of the radiation decay we previously concluded, that this decay is in part due to the destruction of radiative Eu sites [J.W. Tringe, unpublished (2006)]. Along the transition from virgin to irradiated material we analyze the accumulated damage in terms of surface morphology (atomic force microscopy), crystallinity (x-ray diffraction), and phonon dispersion using micro-Raman spectroscopy. In addition to the well-studied E{sub 2}(high) mode, two new vibrational modes at 659 cm{sup -1} and 201 cm{sup -1} were observed in the Eu implanted and annealed sample, prior to He{sup +} irradiation. These modes are either remnants of the implantation damage or related to the Eu impurity. As such they can be indicative of the actual lattice site the Eu atom resides on. After irradiation, broad Raman modes at 300 cm-1 are being observed. This band indicates disorder activated Raman scattering (DARS) due to the radiation damage. An additional narrow mode appears at 672 cm{sup -1}, which can possibly be due to a nitrogen vacancy related vibrational mode. The continuous transition from irradiated to un-irradiated sample allows the direct evolution of radiation damage and its coordinated effects in structural, optical and vibrational properties. By its systematic correlation we anticipate to be able to elucidate the Eu lattice interaction and the processes of radiation damage.

  20. Comparing the risk profiles of renewable and natural gas electricity contracts: A summary of the California Department of Water Resources contracts

    E-Print Network [OSTI]

    Bachrach, Devra; Wiser, Ryan; Bolinger, Mark; Golove, William

    2003-01-01T23:59:59.000Z

    M W of geothermal, and 3 M W of landfill gas. The wind powerwind, geothermal, and landfill gas generators, provide theRISK: SUMMARY advance. Landfill gas and geothermal resources

  1. Cornell's conversion of a coal fired heating plant to natural Gas -BACKGROUND: In December 2009, the Combined Heat and Power Plant

    E-Print Network [OSTI]

    Keinan, Alon

    Cornell's conversion of a coal fired heating plant to natural Gas University began operating with natural gas, instead of the coal-fired generators of the coal that had been stockpiled, the Plant is running completely on natural gas

  2. Integrated production of fuel gas and oxygenated organic compounds from synthesis gas

    DOE Patents [OSTI]

    Moore, Robert B. (Allentown, PA); Hegarty, William P. (State College, PA); Studer, David W. (Wescosville, PA); Tirados, Edward J. (Easton, PA)

    1995-01-01T23:59:59.000Z

    An oxygenated organic liquid product and a fuel gas are produced from a portion of synthesis gas comprising hydrogen, carbon monoxide, carbon dioxide, and sulfur-containing compounds in a integrated feed treatment and catalytic reaction system. To prevent catalyst poisoning, the sulfur-containing compounds in the reactor feed are absorbed in a liquid comprising the reactor product, and the resulting sulfur-containing liquid is regenerated by stripping with untreated synthesis gas from the reactor. Stripping offgas is combined with the remaining synthesis gas to provide a fuel gas product. A portion of the regenerated liquid is used as makeup to the absorber and the remainder is withdrawn as a liquid product. The method is particularly useful for integration with a combined cycle coal gasification system utilizing a gas turbine for electric power generation.

  3. Fuel Cells on Bio-Gas (Presentation)

    SciTech Connect (OSTI)

    Remick, R. J.

    2009-03-04T23:59:59.000Z

    The conclusions of this presentation are: (1) Fuel cells operating on bio-gas offer a pathway to renewable electricity generation; (2) With federal incentives of $3,500/kW or 30% of the project costs, reasonable payback periods of less than five years can be achieved; (3) Tri-generation of electricity, heat, and hydrogen offers an alternative route to solving the H{sub 2} infrastructure problem facing fuel cell vehicle deployment; and (4) DOE will be promoting bio-gas fuel cells in the future under its Market Transformation Programs.

  4. Oxygen sensor for monitoring gas mixtures containing hydrocarbons

    DOE Patents [OSTI]

    Ruka, R.J.; Basel, R.A.

    1996-03-12T23:59:59.000Z

    A gas sensor measures O{sub 2} content of a reformable monitored gas containing hydrocarbons, H{sub 2}O and/or CO{sub 2}, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system. 4 figs.

  5. Oxygen sensor for monitoring gas mixtures containing hydrocarbons

    DOE Patents [OSTI]

    Ruka, Roswell J. (Pittsburgh, PA); Basel, Richard A. (Pittsburgh, PA)

    1996-01-01T23:59:59.000Z

    A gas sensor measures O.sub.2 content of a reformable monitored gas containing hydrocarbons H.sub.2 O and/or CO.sub.2, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system.

  6. Promoting electricity from renewable energy sources -- lessons learned from the EU, U.S. and Japan

    E-Print Network [OSTI]

    Haas, Reinhard

    2008-01-01T23:59:59.000Z

    biomass, hydro power and biogas. Other options with vastTechnologies addressed Wind, biogas All technologies (exceptelectricity, Biomass, Biogas, Landfill gas, Sewage gas,

  7. Morphology of Gas Release in Physical Simulants

    SciTech Connect (OSTI)

    Daniel, Richard C.; Burns, Carolyn A.; Crawford, Amanda D.; Hylden, Laura R.; Bryan, Samuel A.; MacFarlan, Paul J.; Gauglitz, Phillip A.

    2014-07-03T23:59:59.000Z

    This report documents testing activities conducted as part of the Deep Sludge Gas Release Event Project (DSGREP). The testing described in this report focused on evaluating the potential retention and release mechanisms of hydrogen bubbles in underground radioactive waste storage tanks at Hanford. The goal of the testing was to evaluate the rate, extent, and morphology of gas release events in simulant materials. Previous, undocumented scoping tests have evidenced dramatically different gas release behavior from simulants with similar physical properties. Specifically, previous gas release tests have evaluated the extent of release of 30 Pa kaolin and 30 Pa bentonite clay slurries. While both materials are clays and both have equivalent material shear strength using a shear vane, it was found that upon stirring, gas was released immediately and completely from bentonite clay slurry while little if any gas was released from the kaolin slurry. The motivation for the current work is to replicate these tests in a controlled quality test environment and to evaluate the release behavior for another simulant used in DSGREP testing. Three simulant materials were evaluated: 1) a 30 Pa kaolin clay slurry, 2) a 30 Pa bentonite clay slurry, and 3) Rayleigh-Taylor (RT) Simulant (a simulant designed to support DSGREP RT instability testing. Entrained gas was generated in these simulant materials using two methods: 1) application of vacuum over about a 1-minute period to nucleate dissolved gas within the simulant and 2) addition of hydrogen peroxide to generate gas by peroxide decomposition in the simulants over about a 16-hour period. Bubble release was effected by vibrating the test material using an external vibrating table. When testing with hydrogen peroxide, gas release was also accomplished by stirring of the simulant.

  8. Evaluation of Reformer Produced Synthesis Gas for Emissions Reductions in Natural Gas Reciprocating Engines

    SciTech Connect (OSTI)

    Mark Scotto

    2010-05-30T23:59:59.000Z

    Rolls-Royce Fuel Cell Systems (US) Inc. (RRFCS) has developed a system that produces synthesis gas from air and natural gas. A near-term application being considered for this technology is synthesis gas injection into reciprocating engines for reducing NO{sub x} emissions. A proof of concept study using bottled synthesis gas and a two-stroke reciprocating engine showed that injecting small amounts of high-flammable content synthesis gas significantly improved combustion stability and enabled leaner engine operation resulting in over 44% reduction in NO{sub x} emissions. The actual NO{sub x} reduction that could be achieved in the field is expected to be engine specific, and in many cases may be even greater. RRFCS demonstrated that its synthesis gas generator could produce synthesis gas with the flammable content that was successfully used in the engine testing. An economic analysis of the synthesis gas approach estimates that its initial capital cost and yearly operating cost are less than half that of a competing NO{sub x} reduction technology, Selective Catalytic Reduction. The next step in developing the technology is an integrated test of the synthesis gas generator with an engine to obtain reliability data for system components and to confirm operating cost. RRFCS is actively pursuing opportunities to perform the integrated test. A successful integrated test would demonstrate the technology as a low-cost option to reduce NO{sub x} emissions from approximately 6,000 existing two-stroke, natural gas-fired reciprocating engines used on natural gas pipelines in North America. NO{sub x} emissions reduction made possible at a reasonable price by this synthesis gas technology, if implemented on 25% of these engines, would be on the order of 25,000 tons/year.

  9. Evaluation of Reformer Produced Synthesis Gas for Emissions Reductions in Natural Gas Reciprocating Engines

    SciTech Connect (OSTI)

    Mark V. Scotto; Mark A. Perna

    2010-05-30T23:59:59.000Z

    Rolls-Royce Fuel Cell Systems (US) Inc. (RRFCS) has developed a system that produces synthesis gas from air and natural gas. A near-term application being considered for this technology is synthesis gas injection into reciprocating engines for reducing NOx emissions. A proof of concept study using bottled synthesis gas and a two-stroke reciprocating engine showed that injecting small amounts of highflammables content synthesis gas significantly improved combustion stability and enabled leaner engine operation resulting in over 44% reduction in NOx emissions. The actual NOx reduction that could be achieved in the field is expected to be engine specific, and in many cases may be even greater. RRFCS demonstrated that its synthesis gas generator could produce synthesis gas with the flammables content that was successfully used in the engine testing. An economic analysis of the synthesis gas approach estimates that its initial capital cost and yearly operating cost are less than half that of a competing NOx reduction technology, Selective Catalytic Reduction. The next step in developing the technology is an integrated test of the synthesis gas generator with an engine to obtain reliability data for system components and to confirm operating cost. RRFCS is actively pursuing opportunities to perform the integrated test. A successful integrated test would demonstrate the technology as a low-cost option to reduce NOx emissions from approximately 6,000 existing two-stroke, natural gas-fired reciprocating engines used on natural gas pipelines in North America. NOx emissions reduction made possible at a reasonable price by this synthesis gas technology, if implemented on 25% of these engines, would be on the order of 25,000 tons/year.

  10. Closing the Gap: Using the Clean Air Act to Control Lifecycle Greenhouse Gas Emissions from Energy Facilities

    E-Print Network [OSTI]

    Hagan, Colin R.

    2012-01-01T23:59:59.000Z

    associated with coal generation occur at the smokestack. Theassociated with coal-fired electricity generation by up toCoal, Domestic Natural Gas, LNG, and SNG for Electricity Generation,

  11. Transportation and Greenhouse Gas Mitigation

    E-Print Network [OSTI]

    Lutsey, Nicholas P.; Sperling, Dan

    2008-01-01T23:59:59.000Z

    fuels (eg diesel, compressed natural gas). Electricity (infossil fuels, such as compressed natural gas and liquefied

  12. Structure and physical properties of EuTa{sub 2}O{sub 6} tungsten bronze polymorph

    SciTech Connect (OSTI)

    Kolodiazhnyi, T., E-mail: kolodiazhnyi.taras@nims.go.jp; Sakurai, H.; Vasylkiv, O.; Borodianska, H. [National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Forbes, S.; Mozharivskyj, Y. [Department of Chemistry and Chemical Biology, McMaster University, 1280 Main Street West, Hamilton, Ontario L8S4M1 (Canada)

    2014-08-11T23:59:59.000Z

    A tetragonal tungsten bronze (TTB) polymorph of EuTa{sub 2}O{sub 6} was prepared and analyzed. EuTa{sub 2}O{sub 6} crystallizes in the centrosymmetric Pnam space group (with unit cell: a?=?12.3693, b?=?12.4254, and c?=?7.7228?) isomorphous with orthorhombic ?-SrTa{sub 2}O{sub 6}. In contrast to early reports, we see no evidence of deviation from paramagnetic Curie-Weiss behavior among the Eu{sup 2+} 4f{sup 7}spins in EuTa{sub 2}O{sub 6} down to 2?K. Dielectric constant shows a broad peak at ca. 50?K with dielectric dispersion resembling diffuse phase transition. The relaxation time, however, follows a simple (non-freezing) thermally activated process with an activation energy of 92?meV and an attempt frequency of f{sub 0}?=?5.79??10{sup 12?}Hz. A thermal conductivity of EuTa{sub 2}O{sub 6} shows a low-temperature (T???30?K) plateau region reminiscent of a glass-like behaviour in Nb-based TTB compounds. This behaviour can be attributed to the loosely bound Eu{sup 2+} ions occupying large tricapped trigonal prismatic sites in the EuTa{sub 2}O{sub 6} structure.

  13. Synthesis, Crystal and Electronic Structure of the Quaternary Magnetic EuTAl4Si2 (T = Rh and Ir) Compounds

    SciTech Connect (OSTI)

    Maurya, Arvind [Tata Institute of Fundamental Research; Thamizhavel, Arumugam [Tata Institute of Fundamental Research; Provino, Alessia [University of Genova; Pani, Marcella [University of Genova; Manfrinetti, Pietro [University of Genova; Paudyal, Durga [Ames Laboratory; Dhar, Sudesh Kumar [Tata Institute of Fundamental Research

    2014-01-22T23:59:59.000Z

    Single crystals of the quaternary europium compounds EuRhAl4Si2 and EuIrAl4Si2 were synthesized by using the AlSi binary eutectic as a flux. The structure of the two quaternary compounds has been refined by single crystal X-ray diffraction. Both compounds are stoichiometric and adopt an ordered derivative of the ternary KCu4S3 structure type (tetragonal tP8, P4/mmm). The two compounds reported here represent the first example of a quaternary and truly stoichiometric 1:1:4:2 phase crystallizing with this structure type. In light of our present results, the structure of the BaMg4Si3 compound given in literature as representing a new prototype is actually isotypic with the KCu4S3 structure. Local spin density approximation including the Hubbard U parameter (LSDA + U) calculations show that Eu ions are in the divalent state, with a significant hybridization between the Eu 5d, Rh (Ir) 4d (5d), Si 3p and Al 3p states. Magnetic susceptibility measured along the [001] direction confirms the divalent nature of the Eu ions in EuRhAl4Si2 and EuIrAl4Si2, which order magnetically near 11 and 15 K, respectively.

  14. Light-induced structural changes in Eu-doped (Pb,La)(Zr,Ti)O{sub 3} ceramics

    SciTech Connect (OSTI)

    Myint, Thandar; Gunawidjaja, Ray; Eilers, Hergen [Applied Sciences Laboratory, Institute for Shock Physics, Washington State University, Spokane, Washington 99210-1495 (United States)

    2011-04-25T23:59:59.000Z

    Fluorescence spectra of poled and unpoled Eu-doped (Pb,La)(Zr,Ti)O{sub 3} ceramics with various compositions were measured using 580 nm excitation. The ratio of the intensities of the Eu{sup 3+} {sup 5}D{sub 0}{yields}{sup 7}F{sub 2}/{sup 5}D{sub 0}{yields}{sup 7}F{sub 1} fluorescence transitions was used as an indicator for the symmetry of the Eu{sup 3+} site. As the symmetry decreases, the ratio increases. Increasing the Zr content in (Pb,La)(Zr,Ti)O{sub 3} increases the ratio, indicating that the symmetry of the Eu{sup 3+} site decreases. Exposure of the Eu-doped (Pb,La)(Zr,Ti)O{sub 3} samples to UV light also increases the intensity ratio, indicating that UV light exposure leads to structural distortions in Eu-doped (Pb,La)(Zr,Ti)O{sub 3} samples, lowering the Eu{sup 3+} site symmetry.

  15. Compressed gas manifold

    DOE Patents [OSTI]

    Hildebrand, Richard J. (Edgemere, MD); Wozniak, John J. (Columbia, MD)

    2001-01-01T23:59:59.000Z

    A compressed gas storage cell interconnecting manifold including a thermally activated pressure relief device, a manual safety shut-off valve, and a port for connecting the compressed gas storage cells to a motor vehicle power source and to a refueling adapter. The manifold is mechanically and pneumatically connected to a compressed gas storage cell by a bolt including a gas passage therein.

  16. Noble gas magnetic resonator

    DOE Patents [OSTI]

    Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

    2014-04-15T23:59:59.000Z

    Precise measurements of a precessional rate of noble gas in a magnetic field is obtained by constraining the time averaged direction of the spins of a stimulating alkali gas to lie in a plane transverse to the magnetic field. In this way, the magnetic field of the alkali gas does not provide a net contribution to the precessional rate of the noble gas.

  17. OIL & GAS INSTITUTE Introduction

    E-Print Network [OSTI]

    Mottram, Nigel

    OIL & GAS INSTITUTE CONTENTS Introduction Asset Integrity Underpinning Capabilities 2 4 4 6 8 9 10 COMPETITIVENESS UNIVERSITY of STRATHCLYDE OIL & GAS INSTITUTE OIL & GAS EXPERTISE AND PARTNERSHIPS #12;1 The launch of the Strathclyde Oil & Gas Institute represents an important step forward for the University

  18. NOVEL GAS CLEANING/CONDITIONING FOR INTEGRATED GASIFICATION COMBINED CYCLE

    SciTech Connect (OSTI)

    Dennis A. Horazak; Richard A. Newby; Eugene E. Smeltzer; Rachid B. Slimane; P. Vann Bush; James L. Aderhold Jr; Bruce G. Bryan

    2005-12-01T23:59:59.000Z

    Development efforts have been underway for decades to replace dry-gas cleaning technology with humid-gas cleaning technology that would maintain the water vapor content in the raw gas by conducting cleaning at sufficiently high temperature to avoid water vapor condensation and would thus significantly simplify the plant and improve its thermal efficiency. Siemens Power Generation, Inc. conducted a program with the Gas Technology Institute (GTI) to develop a Novel Gas Cleaning process that uses a new type of gas-sorbent contactor, the ''filter-reactor''. The Filter-Reactor Novel Gas Cleaning process described and evaluated here is in its early stages of development and this evaluation is classified as conceptual. The commercial evaluations have been coupled with integrated Process Development Unit testing performed at a GTI coal gasifier test facility to demonstrate, at sub-scale the process performance capabilities. The commercial evaluations and Process Development Unit test results are presented in Volumes 1 and 2 of this report, respectively. Two gas cleaning applications with significantly differing gas cleaning requirements were considered in the evaluation: IGCC power generation, and Methanol Synthesis with electric power co-production. For the IGCC power generation application, two sets of gas cleaning requirements were applied, one representing the most stringent ''current'' gas cleaning requirements, and a second set representing possible, very stringent ''future'' gas cleaning requirements. Current gas cleaning requirements were used for Methanol Synthesis in the evaluation because these cleaning requirements represent the most stringent of cleaning requirements and the most challenging for the Filter-Reactor Novel Gas Cleaning process. The scope of the evaluation for each application was: (1) Select the configuration for the Filter-Reactor Novel Gas Cleaning Process, the arrangement of the individual gas cleaning stages, and the probable operating conditions of the gas cleaning stages to conceptually satisfy the gas cleaning requirements; (2) Estimate process material & energy balances for the major plant sections and for each gas cleaning stage; (3) Conceptually size and specify the major gas cleaning process equipment; (4) Determine the resulting overall performance of the application; and (5) Estimate the investment cost and operating cost for each application. Analogous evaluation steps were applied for each application using conventional gas cleaning technology, and comparison was made to extract the potential benefits, issues, and development needs of the Filter-Reactor Novel Gas Cleaning technology. The gas cleaning process and related gas conditioning steps were also required to meet specifications that address plant environmental emissions, the protection of the gas turbine and other Power Island components, and the protection of the methanol synthesis reactor. Detailed material & energy balances for the gas cleaning applications, coupled with preliminary thermodynamic modeling and laboratory testing of candidate sorbents, identified the probable sorbent types that should be used, their needed operating conditions in each stage, and their required levels of performance. The study showed that Filter-Reactor Novel Gas Cleaning technology can be configured to address and conceptually meet all of the gas cleaning requirements for IGCC, and that it can potentially overcome several of the conventional IGCC power plant availability issues, resulting in improved power plant thermal efficiency and cost. For IGCC application, Filter-Reactor Novel Gas Cleaning yields 6% greater generating capacity and 2.3 percentage-points greater efficiency under the Current Standards case, and more than 9% generating capacity increase and 3.6 percentage-points higher efficiency in the Future Standards case. While the conceptual equipment costs are estimated to be only slightly lower for the Filter-Reactor Novel Gas Cleaning processes than for the conventional processes, the improved power plant capacity results in the potentia

  19. Gas-cooled nuclear reactor

    DOE Patents [OSTI]

    Peinado, Charles O. (La Jolla, CA); Koutz, Stanley L. (San Diego, CA)

    1985-01-01T23:59:59.000Z

    A gas-cooled nuclear reactor includes a central core located in the lower portion of a prestressed concrete reactor vessel. Primary coolant gas flows upward through the core and into four overlying heat-exchangers wherein stream is generated. During normal operation, the return flow of coolant is between the core and the vessel sidewall to a pair of motor-driven circulators located at about the bottom of the concrete pressure vessel. The circulators repressurize the gas coolant and return it back to the core through passageways in the underlying core structure. If during emergency conditions the primary circulators are no longer functioning, the decay heat is effectively removed from the core by means of natural convection circulation. The hot gas rising through the core exits the top of the shroud of the heat-exchangers and flows radially outward to the sidewall of the concrete pressure vessel. A metal liner covers the entire inside concrete surfaces of the concrete pressure vessel, and cooling tubes are welded to the exterior or concrete side of the metal liner. The gas coolant is in direct contact with the interior surface of the metal liner and transfers its heat through the metal liner to the liquid coolant flowing through the cooling tubes. The cooler gas is more dense and creates a downward convection flow in the region between the core and the sidewall until it reaches the bottom of the concrete pressure vessel when it flows radially inward and up into the core for another pass. Water is forced to flow through the cooling tubes to absorb heat from the core at a sufficient rate to remove enough of the decay heat created in the core to prevent overheating of the core or the vessel.

  20. Natural gas monthly

    SciTech Connect (OSTI)

    NONE

    1998-01-01T23:59:59.000Z

    The Natural Gas Monthly highlights activities, events, and analyses of interest to public and private sector organizations associated with the natural gas industry. Volume and price data are presented each month for natural gas production, distribution, consumption, and interstate pipeline activities. Producer-related activities and underground storage data are also reported. From time to time, the Natural Gas Monthly features articles designed to assist readers in using and interpreting natural gas information.