National Library of Energy BETA

Sample records for generation eu gas

  1. Reducing gas generators and methods for generating a reducing gas

    SciTech Connect (OSTI)

    Scotto, Mark Vincent; Perna, Mark Anthony

    2015-11-03

    One embodiment of the present invention is a unique reducing gas generator. Another embodiment is a unique method for generating a reducing gas. Other embodiments include apparatuses, systems, devices, hardware, methods, and combinations for generating reducing gas. Further embodiments, forms, features, aspects, benefits, and advantages of the present application will become apparent from the description and figures provided herewith.

  2. The Chemistry of Flammable Gas Generation

    SciTech Connect (OSTI)

    ZACH, J.J.

    2000-10-30

    The document collects information from field instrumentation, laboratory tests, and analytical models to provide a single source of information on the chemistry of flammable gas generation at the Hanford Site. It considers the 3 mechanisms of formation: radiolysis, chemical reactions, and thermal generation. An assessment of the current models for gas generation is then performed. The results are that the various phenomena are reasonably understood and modeled compared to field data.

  3. Onboard Plasmatron Generation of Hydrogen rich Gas for Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Onboard Plasmatron Generation of Hydrogen rich Gas for Diesel Aftertreatment and Other Applications Onboard Plasmatron Generation of Hydrogen rich Gas for Diesel Aftertreatment and...

  4. Gas turbine power generation from biomass gasification

    SciTech Connect (OSTI)

    Paisley, M.A.; Litt, R.D.; Overend, R.P.; Bain, R.L.

    1994-12-31

    The Biomass Power Program of the US Department of Energy (DOE) has as a major goal the development of cost-competitive technologies for the production of power from renewable biomass crops. The gasification of biomass provides the potential to meet this goal by efficiently and economically producing a renewable source of a clean gaseous fuel suitable for use in high efficiency gas turbines or as a substitute fuel in other combustion devices such as boilers, kilns, or other natural gas fired equipment. This paper discusses the development of the use of the Battelle high-throughput gasification process for power generation systems. Projected process economics are presented along with a description of current experimental operations coupling a gas turbine power generation system to the research scale gasifier.

  5. Gas generation from Tank 241-SY-103 waste

    SciTech Connect (OSTI)

    Bryan, S.A.; King, C.M.; Pederson, L.R.; Forbes, S.V.; Sell, R.L.

    1996-04-01

    This report summarizes progress made in evaluating mechanisms by which flammable gases are generated in Hanford double-shell tank wastes, based on the results of laboratory tests using actual waste from Tank 241-SY-103. The objective of this work is to establish the identity and stoichiometry of degradation products formed in actual tank wastes by thermal and radiolytic processes as a function of temperature. The focus of the gas generation tests on Tank 241-SY-103 samples is first the effect of temperature on gas generation (volume and composition). Secondly, gas generation from irradiation of Tank 241-SY-103 samples at the corresponding temperatures as the thermal-only treatments will be measured in the presence of an external radiation source (using a {sup 137}Cs capsule). The organic content will be measured on a representative sample prior to gas generation experiments and again at the termination of heating and irradiation. The gas generation will be related to the extent of organic species consumption during heating. Described in this report are experimental methods used for producing and measuring gases generated at various temperatures from highly radioactive actual tank waste, and results of gas generation from Tank 241-SY-103 waste taken from its convective layer. The accurate measurement of gas generation rates from actual waste from highly radioactive waste tanks is needed to assess the potential for producing and storing flammable gases within the waste tanks. This report addresses the gas generation capacity of the waste from the convective layer of Tank 241-SY-103, a waste tank listed on the Flammable Gas Watch List due to its potential for flammable gas accumulation above the flammability limit.

  6. Fact #844: October 27, 2014 Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown – Dataset

    Broader source: Energy.gov [DOE]

    Excel file with dataset for Fact #844: Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown

  7. Next Generation Natural Gas Vehicle Activity: Natural Gas Engine and Vehicle Research & Development (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2003-09-01

    This fact sheet describes the status of the Next Generation Natural Gas Vehicle (NGNGV) activity, including goals, R&D progress, NGV implementation, and the transition to hydrogen.

  8. High Temperature Gas Reactors The Next Generation ?

    E-Print Network [OSTI]

    %) · Microsphere Coated Particle Fuel #12;3 History of Gas Reactors in US · Peach Bottom (40 MWe) 1967-1974 - First MWD/kg Disadvantages · Poor History in US · Little Helium Turbine Experience · US Technology Water Africa - 250 MWth Pebble - 2006 · Russia - 290 MWe - Pu Burner Prismatic 2007 (GA, Framatome, DOE, etc

  9. Next Generation Natural Gas Vehicle (NGNGV) Program Fact Sheet

    SciTech Connect (OSTI)

    Walkowicz, K.

    2002-05-01

    Fact sheet describing U. S. DOE and NREL's development of next generation natural gas vehicles (NGVs) as a key element in its strategy to reduce oil import and vehicle pollutants.

  10. NEW APPROACH TO ADDRESSING GAS GENERATION IN RADIOACTIVE MATERIAL PACKAGING

    SciTech Connect (OSTI)

    Watkins, R; Leduc, D; Askew, N

    2009-06-25

    Safety Analysis Reports for Packaging (SARP) document why the transportation of radioactive material is safe in Type A(F) and Type B shipping containers. The content evaluation of certain actinide materials require that the gas generation characteristics be addressed. Most packages used to transport actinides impose extremely restrictive limits on moisture content and oxide stabilization to control or prevent flammable gas generation. These requirements prevent some users from using a shipping container even though the material to be shipped is fully compliant with the remaining content envelope including isotopic distribution. To avoid these restrictions, gas generation issues have to be addressed on a case by case basis rather than a one size fits all approach. In addition, SARP applicants and review groups may not have the knowledge and experience with actinide chemistry and other factors affecting gas generation, which facility experts in actinide material processing have obtained in the last sixty years. This paper will address a proposal to create a Gas Generation Evaluation Committee to evaluate gas generation issues associated with Safety Analysis Reports for Packaging material contents. The committee charter could include reviews of both SARP approved contents and new contents not previously evaluated in a SARP.

  11. Next Generation Natural Gas Vehicle (NGNGV) Program Brochure

    SciTech Connect (OSTI)

    Elling, J.

    2000-10-26

    The Department of Energy's Office of Transportation Technologies is initiating the Next Generation Natural Gas Vehicle (NGNGV) Program to develop commercially viable medium- and heavy-duty natural gas vehicles. These new vehicles will incorporate advanced alternative fuel vehicle technologies that were developed by DOE and others.

  12. Gas generation matrix depletion quality assurance project plan

    SciTech Connect (OSTI)

    NONE

    1998-05-01

    The Los Alamos National Laboratory (LANL) is to provide the necessary expertise, experience, equipment and instrumentation, and management structure to: Conduct the matrix depletion experiments using simulated waste for quantifying matrix depletion effects; and Conduct experiments on 60 cylinders containing simulated TRU waste to determine the effects of matrix depletion on gas generation for transportation. All work for the Gas Generation Matrix Depletion (GGMD) experiment is performed according to the quality objectives established in the test plan and under this Quality Assurance Project Plan (QAPjP).

  13. High order harmonic generation in dual gas multi-jets

    SciTech Connect (OSTI)

    Tosa, Valer E-mail: calin.hojbota@itim-cj.ro; Hojbota, Calin E-mail: calin.hojbota@itim-cj.ro

    2013-11-13

    High order harmonic generation (HHG) in gas media suffers from a low conversion efficiency that has its origins in the interaction of the atom/molecule with the laser field. Phase matching is the main way to enhance the harmonic flux and several solutions have been designed to achieve it. Here we present numerical results modeling HHG in a system of multi-jets in which two gases alternate: the first gas jet (for example Ne) generates harmonics and the second one which ionizes easier, recover the phase matching condition. We obtain configurations which are experimentally feasible with respect to pressures and dimensions of the jets.

  14. Noble Gas Clusters and Nanoplasmas in High Harmonic Generation

    E-Print Network [OSTI]

    Aladi, M; Rácz, P; Földes, I B

    2015-01-01

    We report a study of high harmonic generation from noble gas clusters of xenon atoms in a gas jet. Harmonic spectra were investigated as a function of backing pressure, showing spectral shifts due to the nanoplasma electrons in the clusters. At certain value of laser intensity this process may oppose the effect of the well-known ionization-induced blueshift. In addition, these cluster-induced harmonic redshifts may give the possibility to estimate cluster density and cluster size in the laser-gas jet interaction range.

  15. Gas Generation Equations for CRiSP 1.6 April 21, 1998 1 Gas Generation Equations for CRiSP 1.6

    E-Print Network [OSTI]

    Washington at Seattle, University of

    Gas Generation Equations for CRiSP 1.6 April 21, 1998 1 Gas Generation Equations for CRiSP 1.6 Theory For CRiSP.1.6 new equations have been implemented for gas production from spill. As a part of the US Army Corps' Gas Abatement study, Waterways Experiment Station (WES) has developed these new

  16. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    SciTech Connect (OSTI)

    Marnay, Chris; Stadler, Michael; Lipman, Tim; Lai, Judy; Cardoso, Goncalo; Megel, Olivier

    2009-09-01

    The motivation and objective of this research is to determine the role of distributed generation (DG) in greenhouse gas reductions by: (1) applying the Distributed Energy Resources Customer Adoption Model (DER-CAM); (2) using the California Commercial End-Use Survey (CEUS) database for commercial buildings; (3) selecting buildings with electric peak loads between 100 kW and 5 MW; (4) considering fuel cells, micro-turbines, internal combustion engines, gas turbines with waste heat utilization, solar thermal, and PV; (5) testing of different policy instruments, e.g. feed-in tariff or investment subsidies.

  17. Promoting electricity from renewable energy sources -- lessons learned from the EU, U.S. and Japan

    E-Print Network [OSTI]

    Haas, Reinhard

    2008-01-01

    fluctuations. Electricity generation [TWh/year] EU-25 USA4 . Electricity generation [TWh/year] Japan EU-25 USA EU-25USA Japan Wind Waste Solar Biomass Geothermal Figure 2 Historical pattern of electricity

  18. Biomass gasification for gas turbine-based power generation

    SciTech Connect (OSTI)

    Paisley, M.A.; Anson, D.

    1998-04-01

    The Biomass Power Program of the US Department of Energy (DOE) has as a major goal the development of cost-competitive technologies for the production of power from renewable biomass crops. The gasification of biomass provides the potential to meet this goal by efficiently and economically producing a renewable source of a clean gaseous fuel suitable for use in high-efficiency gas turbines. This paper discusses the development and first commercial demonstration of the Battelle high-throughput gasification process for power generation systems. Projected process economics are presented along with a description of current experimental operations coupling a gas turbine power generation system to the research scale gasifier and the process scaleup activities in Burlington, Vermont.

  19. Modeling acid-gas generation from boiling chloride brines

    SciTech Connect (OSTI)

    Zhang, Guoxiang; Spycher, Nicolas; Sonnenthal, Eric; Steefel, Carl

    2009-11-16

    This study investigates the generation of HCl and other acid gases from boiling calcium chloride dominated waters at atmospheric pressure, primarily using numerical modeling. The main focus of this investigation relates to the long-term geologic disposal of nuclear waste at Yucca Mountain, Nevada, where pore waters around waste-emplacement tunnels are expected to undergo boiling and evaporative concentration as a result of the heat released by spent nuclear fuel. Processes that are modeled include boiling of highly concentrated solutions, gas transport, and gas condensation accompanied by the dissociation of acid gases, causing low-pH condensate. Simple calculations are first carried out to evaluate condensate pH as a function of HCl gas fugacity and condensed water fraction for a vapor equilibrated with saturated calcium chloride brine at 50-150 C and 1 bar. The distillation of a calcium-chloride-dominated brine is then simulated with a reactive transport model using a brine composition representative of partially evaporated calcium-rich pore waters at Yucca Mountain. Results show a significant increase in boiling temperature from evaporative concentration, as well as low pH in condensates, particularly for dynamic systems where partial condensation takes place, which result in enrichment of HCl in condensates. These results are in qualitative agreement with experimental data from other studies. The combination of reactive transport with multicomponent brine chemistry to study evaporation, boiling, and the potential for acid gas generation at the proposed Yucca Mountain repository is seen as an improvement relative to previously applied simpler batch evaporation models. This approach allows the evaluation of thermal, hydrological, and chemical (THC) processes in a coupled manner, and modeling of settings much more relevant to actual field conditions than the distillation experiment considered. The actual and modeled distillation experiments do not represent expected conditions in an emplacement drift, but nevertheless illustrate the potential for acid-gas generation at moderate temperatures (<150 C).

  20. Fuel switching in the electricity sector under the EU ETS: Review and prospective

    SciTech Connect (OSTI)

    Delarue, E.; Voorspools, K.; D'haeseleer, W.

    2008-06-15

    The European Union has implemented the European Union emission trading scheme (EU ETS) as an instrument to facilitate greenhouse gas (GHG) emission abatement stipulated in the Kyoto protocol. Empirical data show that in the early stages of the EU ETS, the value of a ton of CO{sub 2} has already led to emission abatement through switching from coal to gas in the European electric power sector. In the second part of this paper, an electricity generation simulation model is used to perform simulations on the switching behavior in both the first and the second trading periods of the EU ETS. In 2005, the reduction in GHG emissions in the electric power sector due to EU ETS is estimated close to 88 Mton. For the second trading period, a European Union allowance (EUA) price dependent GHG reduction curve has been determined. The obtained switching potential turns out to be significant, up to 300 Mton/year, at sufficiently high EUA prices.

  1. Method of generating hydrogen gas from sodium borohydride

    DOE Patents [OSTI]

    Kravitz, Stanley H. (Placitas, NM); Hecht, Andrew M. (Sandia Park, NM); Sylwester, Alan P. (Albuquerque, NM); Bell, Nelson S. (Albuquerque, NM)

    2007-12-11

    A compact solid source of hydrogen gas, where the gas is generated by contacting water with micro-disperse particles of sodium borohydride in the presence of a catalyst, such as cobalt or ruthenium. The micro-disperse particles can have a substantially uniform diameter of 1-10 microns, and preferably about 3-5 microns. Ruthenium or cobalt catalytic nanoparticles can be incorporated in the micro-disperse particles of sodium borohydride, which allows a rapid and complete reaction to occur without the problems associated with caking and scaling of the surface by the reactant product sodium metaborate. A closed loop water management system can be used to recycle wastewater from a PEM fuel cell to supply water for reacting with the micro-disperse particles of sodium borohydride in a compact hydrogen gas generator. Capillary forces can wick water from a water reservoir into a packed bed of micro-disperse fuel particles, eliminating the need for using an active pump.

  2. Fact #844: October 27, 2014 Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown

    Broader source: Energy.gov [DOE]

    From 2002 to 2012, most states have reduced their reliance on coal for electricity generation. The figure below shows the percent change in electricity generated by coal and natural gas for each...

  3. Gas cleanup for combined cycle power generation using a hot gas conditioning catalyst

    SciTech Connect (OSTI)

    Paisley, M.A.; Gebhard, S.C.

    1995-11-01

    Biomass gasification provides the potential to efficiently and economically produce a renewable source of a clean gaseous fuel suitable for power generation or synthesis gas (syngas) applications. Biomass as the feedstock for the process is uniquely suited to this application because it provides the means to increase the nation`s energy security, and also, to potentially provide a more stable agricultural industry. An important side benefit of the use of biomass is the effective minimization of the primary greenhouse gas, carbon dioxide (CO{sub 2}), by providing a means to close-loop the CO{sub 2} cycle. However, high molecular weight hydrocarbon constituents (tar) in the product gas from gasification can complicate the downstream uses of the gas. This paper discusses both the development of a low cost, disposable catalyst system that can eliminate these heavy hydrocarbons from the gas and the use of the catalyst in conjunction with the Battelle high-throughput gasification process for power generation systems.

  4. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Marnay, Chris

    2010-01-01

    BERKELEY NATIONAL LABORATORY Greenhouse Gas Abatement withan equal opportunity employer. Greenhouse Gas Abatement withgeneration (DG) in greenhouse gas reductions by * a p p l y

  5. BIOMASS GASIFICATION AND POWER GENERATION USING ADVANCED GAS TURBINE SYSTEMS

    SciTech Connect (OSTI)

    David Liscinsky

    2002-10-20

    A multidisciplined team led by the United Technologies Research Center (UTRC) and consisting of Pratt & Whitney Power Systems (PWPS), the University of North Dakota Energy & Environmental Research Center (EERC), KraftWork Systems, Inc. (kWS), and the Connecticut Resource Recovery Authority (CRRA) has evaluated a variety of gasified biomass fuels, integrated into advanced gas turbine-based power systems. The team has concluded that a biomass integrated gasification combined-cycle (BIGCC) plant with an overall integrated system efficiency of 45% (HHV) at emission levels of less than half of New Source Performance Standards (NSPS) is technically and economically feasible. The higher process efficiency in itself reduces consumption of premium fuels currently used for power generation including those from foreign sources. In addition, the advanced gasification process can be used to generate fuels and chemicals, such as low-cost hydrogen and syngas for chemical synthesis, as well as baseload power. The conceptual design of the plant consists of an air-blown circulating fluidized-bed Advanced Transport Gasifier and a PWPS FT8 TwinPac{trademark} aeroderivative gas turbine operated in combined cycle to produce {approx}80 MWe. This system uses advanced technology commercial products in combination with components in advanced development or demonstration stages, thereby maximizing the opportunity for early implementation. The biofueled power system was found to have a levelized cost of electricity competitive with other new power system alternatives including larger scale natural gas combined cycles. The key elements are: (1) An Advanced Transport Gasifier (ATG) circulating fluid-bed gasifier having wide fuel flexibility and high gasification efficiency; (2) An FT8 TwinPac{trademark}-based combined cycle of approximately 80 MWe; (3) Sustainable biomass primary fuel source at low cost and potentially widespread availability-refuse-derived fuel (RDF); (4) An overall integrated system that exceeds the U.S. Department of Energy (DOE) goal of 40% (HHV) efficiency at emission levels well below the DOE suggested limits; and (5) An advanced biofueled power system whose levelized cost of electricity can be competitive with other new power system alternatives.

  6. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    Lai (2009b), “Control of Greenhouse Gas Emissions by Optimal2008), “Developing a Greenhouse Gas Tool for Buildings inERKELEY N ATIONAL L ABORATORY Greenhouse Gas Abatement with

  7. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    SciTech Connect (OSTI)

    Stadler, Michael; Marnay, Chris; Cardoso, Goncalo; Megel, Olivier; Siddiqui, Afzal; Lai, Judy

    2009-08-15

    Lawrence Berkeley National Laboratory (LBL) is working with the California Energy Commission (CEC) to determine the role of distributed generation (DG) in greenhouse gas reductions. The impact of DG on large industrial sites is well known, and mostly, the potentials are already harvested. In contrast, little is known about the impact of DG on commercial buildings with peak electric loads ranging from 100 kW to 5 MW. We examine how DG with combined heat and power (CHP) may be implemented within the context of a cost minimizing microgrid that is able to adopt and operate various smart energy technologies, such as thermal and photovoltaic (PV) on-site generation, heat exchangers, solar thermal collectors, absorption chillers, and storage systems. We use a mixed-integer linear program (MILP) that has the minimization of a site's annual energy costs as objective. Using 138 representative commercial sites in California (CA) with existing tariff rates and technology data, we find the greenhouse gas reduction potential for California's commercial sector. This paper shows results from the ongoing research project and finished work from a two year U.S. Department of Energy research project. To show the impact of the different technologies on CO2 emissions, several sensitivity runs for different climate zones within CA with different technology performance expectations for 2020 were performed. The considered sites can contribute between 1 Mt/a and 1.8 Mt/a to the California Air Resources Board (CARB) goal of 6.7Mt/a CO2 abatement potential in 2020. Also, with lower PV and storage costs as well as consideration of a CO2 pricing scheme, our results indicate that PV and electric storage adoption can compete rather than supplement each other when the tariff structure and costs of electricity supply have been taken into consideration. To satisfy the site's objective of minimizing energy costs, the batteries will be charged also by CHP systems during off-peak and mid-peak hours and not only by PV during sunny on-peak hours.

  8. Next Generation * Natural Gas (NG)2 Information Requirements--Executive Summary

    Reports and Publications (EIA)

    2000-01-01

    The Energy Information Administration (EIA) has initiated the Next Generation * Natural Gas (NG)2 project to design and implement a new and comprehensive information program for natural gas to meet customer requirements in the post-2000 time frame.

  9. This study explores how the EU Emissions Trading System (EU ETS) actually works on the ground affecting corporate climate strategies.

    E-Print Network [OSTI]

    This study explores how the EU Emissions Trading System (EU ETS) actually works on the ground@bookpoint.co.uk May 2013 322 pages Hardback 978-1-4094-6078-7 £60.00 Corporate Responses to EU Emissions Trading at The Fridtjof Nansen Institute, Norway `With greenhouse gas emissions trading schemes emerging worldwide

  10. Corrosion-induced gas generation in a nuclear waste repository: Reactive geochemistry and multiphase flow effect

    E-Print Network [OSTI]

    Xu, T.

    2009-01-01

    Lying Repositories for Nuclear Waste, NAGRA Technical Reporthost rock formation for nuclear waste storage. EngineeringGas Generation in a Nuclear Waste Repository: Reactive

  11. Quality Assurance Program Plan for TRUPACT-II Gas Generation Test Program

    SciTech Connect (OSTI)

    Carlsbad Field Office

    2002-03-01

    The Gas Generation Test Program (GGTP), referred to as the Program, is designed to establish the concentration of flammable gases and/or gas generation rates in a test category waste container intended for shipment in the Transuranic Package Transporter-II (TRUPACT-II). The phrase "gas generationtesting" shall refer to any activity that establishes the flammable gas concentration or the flammable gas generation rate. This includes, but is not limited to, measurements performed directly on waste containers or during tests performed on waste containers. This Quality Assurance Program Plan (QAPP) documents the quality assurance (QA) and quality control (QC) requirements that apply to the Program. The TRUPACT-II requirements and technical bases for allowable flammable gas concentration and gas generation rates are described in the TRUPACT-II Authorized Methods for Payload Control (TRAMPAC).

  12. PROOF-OF-CONCEPT OF A DUAL-FIRED (SOLAR & NATURAL GAS) GENERATOR

    E-Print Network [OSTI]

    PROOF-OF-CONCEPT OF A DUAL-FIRED (SOLAR & NATURAL GAS) GENERATOR FOR USE IN A SPACE-COOLING SYSTEM REPORT (FAR) PROOF-OF-CONCEPT OF A DUAL-FIRED (SOLAR & NATURAL GAS) GENERATOR FOR USE IN A SPACE COOLING Investigator: Michael Garrabrant AUTHOR EISG Program Administrator Grant #: 52327A/01-06 Grant Funding: $75

  13. Cover and startup gas supply system for solid oxide fuel cell generator

    DOE Patents [OSTI]

    Singh, Prabhakar (Export, PA); George, Raymond A. (Pittsburgh, PA)

    1999-01-01

    A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell.

  14. Cover and startup gas supply system for solid oxide fuel cell generator

    DOE Patents [OSTI]

    Singh, P.; George, R.A.

    1999-07-27

    A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell. 4 figs.

  15. Adapting On-site Electrical Generation Platforms for Producer Gas

    Broader source: Energy.gov [DOE]

    Internal combustion reciprocating engine generators (gensets) are regularly deployed at distribution centers, small municipal utilities, and public institutions to provide on-site electricity...

  16. Abstract The natural gas price surged in 2004. As a result, the marginal cost of some generators burning gas also rose sharply.

    E-Print Network [OSTI]

    Tolbert, Leon M.

    Abstract ­ The natural gas price surged in 2004. As a result, the marginal cost of some generators marginal cost, which is closely related to the natural gas price. Since gas units are usually the marginal the sensitivity of Var benefit with respect to generation cost. The U.S. natural gas industry has been

  17. New generation enrichment monitoring technology for gas centrifuge enrichment plants

    SciTech Connect (OSTI)

    Ianakiev, Kiril D; Alexandrov, Boian S.; Boyer, Brian D.; Hill, Thomas R.; Macarthur, Duncan W.; Marks, Thomas; Moss, Calvin E.; Sheppard, Gregory A.; Swinhoe, Martyn T.

    2008-06-13

    The continuous enrichment monitor, developed and fielded in the 1990s by the International Atomic Energy Agency, provided a go-no-go capability to distinguish between UF{sub 6} containing low enriched (approximately 4% {sup 235}U) and highly enriched (above 20% {sup 235}U) uranium. This instrument used the 22-keV line from a {sup 109}Cd source as a transmission source to achieve a high sensitivity to the UF{sub 6} gas absorption. The 1.27-yr half-life required that the source be periodically replaced and the instrument recalibrated. The instrument's functionality and accuracy were limited by the fact that measured gas density and gas pressure were treated as confidential facility information. The modern safeguarding of a gas centrifuge enrichment plant producing low-enriched UF{sub 6} product aims toward a more quantitative flow and enrichment monitoring concept that sets new standards for accuracy stability, and confidence. An instrument must be accurate enough to detect the diversion of a significant quantity of material, have virtually zero false alarms, and protect the operator's proprietary process information. We discuss a new concept for advanced gas enrichment assay measurement technology. This design concept eliminates the need for the periodic replacement of a radioactive source as well as the need for maintenance by experts. Some initial experimental results will be presented.

  18. Thermal and radiolytic gas generation from Tank 241-S-102 waste

    SciTech Connect (OSTI)

    King, C.M.; Pederson, L.R.; Bryan, S.A.

    1997-07-01

    This report summarizes progress in evaluating thermal and radiolytic rate parameters for flammable gas generation in Hanford single-shell tank wastes based on the results of laboratory tests using actual waste from Tank 241-S-102 (S-102). Work described in this report was conducted at Pacific Northwest National Laboratory (PNNL) for the Flammable Gas Safety Project, whose purpose is to develop information to support Fluor Daniel Hanford (FDH) and its Project Management Hanford Contract (PHMC) subcontractors in their efforts to ensure the safe interim storage of wastes at the Hanford Site. This work is related to gas generation studies being performed at Georgia Institute of Technology (GIT) under subcontract to PNNL, using simulated wastes, and to studies being performed at Numatec Hanford Corporation (formerly Westinghouse Hanford Company) using actual wastes. The results of gas generation from Tank S-102 waste under thermal and radiolytic conditions are described in this report. The accurate measurement of gas generation rates in actual waste from highly radioactive waste tanks is needed to assess the potential for producing and storing flammable gases within the waste tanks. This report addresses the gas generation capacity of the waste from Tank S-102, a waste tank listed as high priority by the Flammable Gas Safety Program due to its potential for flammable gas accumulation above the flammability limit.

  19. Heat exchanger design for thermoelectric electricity generation from low temperature flue gas streams

    E-Print Network [OSTI]

    Latcham, Jacob G. (Jacob Greco)

    2009-01-01

    An air-to-oil heat exchanger was modeled and optimized for use in a system utilizing a thermoelectric generator to convert low grade waste heat in flue gas streams to electricity. The NTU-effectiveness method, exergy, and ...

  20. What's New with the NGNGV Program? Next Generation Natural Gas Vehicle Program Newsletter, June 2002

    SciTech Connect (OSTI)

    Not Available

    2002-06-01

    A newsletter about what's new with the Next Generation Natural Gas Vehicle Program (NGNGV). This June 2002 update includes Phase II RFPs, Phase I update, and near-term engine development projects.

  1. A market and engineering study of a 3-kilowatt class gas turbine generator

    E-Print Network [OSTI]

    Monroe, Mark A. (Mark Alan)

    2003-01-01

    Market and engineering studies were performed for the world's only commercially available 3 kW class gas turbine generator, the IHI Aerospace Dynajet. The objectives of the market study were to determine the competitive ...

  2. Life Cycle Greenhouse Gas Emissions from Electricity Generation (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-01-01

    Analysts at NREL have developed and applied a systematic approach to review the LCA literature, identify primary sources of variability and, where possible, reduce variability in GHG emissions estimates through a procedure called 'harmonization.' Harmonization of the literature provides increased precision and helps clarify the impacts of specific electricity generation choices, producing more robust results.

  3. Effects of Globally Waste Disturbing Activities on Gas Generation, Retention, and Release in Hanford Waste Tanks

    SciTech Connect (OSTI)

    Stewart, Charles W.; Fountain, Matthew S.; Huckaby, James L.; Mahoney, Lenna A.; Meyer, Perry A.; Wells, Beric E.

    2005-08-02

    Various operations are authorized in Hanford single- and double-shell tanks that disturb all or a large fraction of the waste. These globally waste-disturbing activities have the potential to release a large fraction of the retained flammable gas and to affect future gas generation, retention, and release behavior. This report presents analyses of the expected flammable gas release mechanisms and the potential release rates and volumes resulting from these activities. The background of the flammable gas safety issue at Hanford is summarized, as is the current understanding of gas generation, retention, and release phenomena. Considerations for gas monitoring and assessment of the potential for changes in tank classification and steady-state flammability are given.

  4. Deep generation of magmatic gas on the Moon and implications for pyroclastic eruptions

    E-Print Network [OSTI]

    Head III, James William

    ,2 and J. W. Head III1 Received 9 August 2002; revised 17 February 2003; accepted 4 March 2003; published. We propose a model in which these conundrums are resolved through gas build-up in a low- pressure: Wilson, L., and J. W. Head III, Deep generation of magmatic gas on the Moon and implications

  5. GREENHOUSE GAS EMISSION CONTROL OPTIONS: ASSESSING TRANSPORTATION AND ELECTRICITY GENERATION TECHNOLOGIES AND

    E-Print Network [OSTI]

    Kockelman, Kara M.

    1 GREENHOUSE GAS EMISSION CONTROL OPTIONS: ASSESSING TRANSPORTATION AND ELECTRICITY GENERATION, Environmental and Ecological Effects," August 2013. KEY WORDS: Greenhouse gases, transportation energy, electric options is an important step in formulating a cohesive strategy to abate U.S. greenhouse gas (GHG

  6. New Generating Technology to Reduce Greenhouse Gas Emissions

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets16 (next20, 2008 Next3,4,04,5,797

  7. Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell Applications1

    E-Print Network [OSTI]

    Peng, Huei

    Control of Natural Gas Catalytic Partial Oxidation for Hydrogen Generation in Fuel Cell the anode field of fuel cell stack is considered. The first reactor that generates the majority in the fuel cell anode and (ii) the temperature of the catalytic partial oxidation reactor during transient

  8. Life Cycle Greenhouse Gas Emissions from Electricity Generation Fact Sheet

    Broader source: Energy.gov [DOE]

    As clean energy increasingly becomes part of the national dialogue, lenders, utilities, and lawmakers need the most comprehensive and accurate information on GHG emissions from various sources of energy to inform policy, planning, and investment decisions. The National Renewable Energy Laboratory (NREL) recently led the Life Cycle Assessment (LCA) Harmonization Project, a study that gives decision makers and investors more precise estimates of life cycle GHG emissions for renewable and conventional generation, clarifying inconsistent and conflicting estimates in the published literature, and reducing uncertainty.

  9. Accounting for fuel price risk: Using forward natural gas prices instead of gas price forecasts to compare renewable to natural gas-fired generation

    SciTech Connect (OSTI)

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2003-08-13

    Against the backdrop of increasingly volatile natural gas prices, renewable energy resources, which by their nature are immune to natural gas fuel price risk, provide a real economic benefit. Unlike many contracts for natural gas-fired generation, renewable generation is typically sold under fixed-price contracts. Assuming that electricity consumers value long-term price stability, a utility or other retail electricity supplier that is looking to expand its resource portfolio (or a policymaker interested in evaluating different resource options) should therefore compare the cost of fixed-price renewable generation to the hedged or guaranteed cost of new natural gas-fired generation, rather than to projected costs based on uncertain gas price forecasts. To do otherwise would be to compare apples to oranges: by their nature, renewable resources carry no natural gas fuel price risk, and if the market values that attribute, then the most appropriate comparison is to the hedged cost of natural gas-fired generation. Nonetheless, utilities and others often compare the costs of renewable to gas-fired generation using as their fuel price input long-term gas price forecasts that are inherently uncertain, rather than long-term natural gas forward prices that can actually be locked in. This practice raises the critical question of how these two price streams compare. If they are similar, then one might conclude that forecast-based modeling and planning exercises are in fact approximating an apples-to-apples comparison, and no further consideration is necessary. If, however, natural gas forward prices systematically differ from price forecasts, then the use of such forecasts in planning and modeling exercises will yield results that are biased in favor of either renewable (if forwards < forecasts) or natural gas-fired generation (if forwards > forecasts). In this report we compare the cost of hedging natural gas price risk through traditional gas-based hedging instruments (e.g., futures, swaps, and fixed-price physical supply contracts) to contemporaneous forecasts of spot natural gas prices, with the purpose of identifying any systematic differences between the two. Although our data set is quite limited, we find that over the past three years, forward gas prices for durations of 2-10 years have been considerably higher than most natural gas spot price forecasts, including the reference case forecasts developed by the Energy Information Administration (EIA). This difference is striking, and implies that resource planning and modeling exercises based on these forecasts over the past three years have yielded results that are biased in favor of gas-fired generation (again, presuming that long-term stability is desirable). As discussed later, these findings have important ramifications for resource planners, energy modelers, and policy-makers.

  10. Status and integration of studies of gas generation in Hanford wastes

    SciTech Connect (OSTI)

    Pederson, L.R.; Bryan, S.A.

    1996-10-01

    The purpose of this report is to review recent progress in determining the mechanism, kinetics, and stoichiometry of gas generation in Hanford waste tanks. Information has been gathered from the results of (1) laboratory studies with simulated wastes; (2) laboratory studies with actual waste core samples (Tanks SY-101 and SY-103); (3) studies of thermal and radiolytic reactions in the gas phase; (4) gas solubility evaluations; and (5) in-tank gas composition data. The results of laboratory studies using simulated wastes, which were aimed at determining chemical mechanisms responsible for gas generation, are summarized in Section 2. Emphasized are findings from work performed at the Georgia Institute of Technology (GIT), which was conducted under subcontract to Pacific Northwest National Laboratory (PNNL) and completed in FY 1996. Thermally activated pathways for the decomposition of hydroxyethylethylene-diaminetriacetic acid (HEDTA, trisodium salt) in simulated wastes were established by this work, among other accomplishments.

  11. SULFUR REMOVAL FROM PIPE LINE NATURAL GAS FUEL: APPLICATION TO FUEL CELL POWER GENERATION SYSTEMS

    SciTech Connect (OSTI)

    King, David L.; Birnbaum, Jerome C.; Singh, Prabhakar

    2003-11-21

    Pipeline natural gas is being considered as the fuel of choice for utilization in fuel cell-based distributed generation systems because of its abundant supply and the existing supply infrastructure (1). For effective utilization in fuel cells, pipeline gas requires efficient removal of sulfur impurities (naturally occurring sulfur compounds or sulfur bearing odorants) to prevent the electrical performance degradation of the fuel cell system. Sulfur odorants such as thiols and sulfides are added to pipeline natural gas and to LPG to ensure safe handling during transportation and utilization. The odorants allow the detection of minute gas line leaks, thereby minimizing the potential for explosions or fires.

  12. Third generation residual gas ionization profile monitors at Fermilab

    E-Print Network [OSTI]

    Zagel, J R; Fellenz, B; Jensen, C; Lundberg, C; McCrory, E; Slimmer, D; Thurman-Keup, R; Tinsley, D

    2015-01-01

    The latest generation of IPMs installed in the Fermilab Main Injector and Recycler incorporate a 1 kG permanent magnet, a newly designed high-gain, rad-tolerant preamp, and a control grid to moderate the charge that is allowed to arrive on the anode pick-up strips. The control grid is intended to select a single Booster batch measurement per turn. Initially it is being used to allow for a faster turn-on of a single, high-intensity cycle in either machine. The expectation is that this will extend the Micro Channel Plate lifetime, which is the high-cost consumable in the measurement system. We discuss the new design and data acquired with this system.

  13. Electrical Generation Using Non-Salable Low BTU Natural Gas

    SciTech Connect (OSTI)

    Scott Corsair

    2005-12-01

    High operating costs are a significant problem for independent operators throughout the U.S. Often, decisions to temporarily idle or abandon a well or lease are dictated by these cost considerations, which are often seen as unavoidable. Options for continuing operations on a marginal basis are limited, but must include non-conventional approaches to problem solving, such as the use of alternative sources of lease power, and scrupulous reduction of non-productive operating techniques and costs. The loss of access to marginal oil and gas productive reservoirs is of major concern to the DOE. The twin difficulties of high operating costs and low or marginal hydrocarbon production often force independent operators to temporarily or permanently abandon existing lease facilities, including producing wells. Producing well preservation, through continued economical operation of marginal wells, must be maintained. Reduced well and lease operating costs are expected to improve oil recovery of the Schaben field, in Ness County, Kansas, by several hundred thousands of barrels of oil. Appropriate technology demonstrated by American Warrior, allows the extension of producing well life and has application for many operators throughout the area.

  14. Performance and Economics of Catalytic Glow Plugs and Shields in Direct Injection Natural Gas Engines for the Next Generation Natural Gas Vehicle Program: Final Report

    SciTech Connect (OSTI)

    Mello, J. P.; Bezaire, D.; Sriramulu, S.; Weber, R.

    2003-08-01

    Subcontractor report details work done by TIAX and Westport to test and perform cost analysis for catalytic glow plugs and shields for direct-injection natural gas engines for the Next Generation Natural Gas Vehicle Program.

  15. The heat recovery steam generator (HRSG) is a key component of Combined Cycle Power Plants (CCPP). The exhaust (flue gas) from the CCPP gas turbine flows through the HRSG -this gas typically contains a high

    E-Print Network [OSTI]

    The heat recovery steam generator (HRSG) is a key component of Combined Cycle Power Plants (CCPP). The exhaust (flue gas) from the CCPP gas turbine flows through the HRSG - this gas typically contains a high

  16. GREENHOUSE GAS REDUCTION POTENTIAL WITH COMBINED HEAT AND POWER WITH DISTRIBUTED GENERATION PRIME MOVERS - ASME 2012

    SciTech Connect (OSTI)

    Curran, Scott; Theiss, Timothy J; Bunce, Michael

    2012-01-01

    Pending or recently enacted greenhouse gas regulations and mandates are leading to the need for current and feasible GHG reduction solutions including combined heat and power (CHP). Distributed generation using advanced reciprocating engines, gas turbines, microturbines and fuel cells has been shown to reduce greenhouse gases (GHG) compared to the U.S. electrical generation mix due to the use of natural gas and high electrical generation efficiencies of these prime movers. Many of these prime movers are also well suited for use in CHP systems which recover heat generated during combustion or energy conversion. CHP increases the total efficiency of the prime mover by recovering waste heat for generating electricity, replacing process steam, hot water for buildings or even cooling via absorption chilling. The increased efficiency of CHP systems further reduces GHG emissions compared to systems which do not recover waste thermal energy. Current GHG mandates within the U.S Federal sector and looming GHG legislation for states puts an emphasis on understanding the GHG reduction potential of such systems. This study compares the GHG savings from various state-of-the- art prime movers. GHG reductions from commercially available prime movers in the 1-5 MW class including, various industrial fuel cells, large and small gas turbines, micro turbines and reciprocating gas engines with and without CHP are compared to centralized electricity generation including the U.S. mix and the best available technology with natural gas combined cycle power plants. The findings show significant GHG saving potential with the use of CHP. Also provided is an exploration of the accounting methodology for GHG reductions with CHP and the sensitivity of such analyses to electrical generation efficiency, emissions factors and most importantly recoverable heat and thermal recovery efficiency from the CHP system.

  17. Recovery Act: Johnston Rhode Island Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas

    SciTech Connect (OSTI)

    Galowitz, Stephen

    2013-06-30

    The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Central Landfill in Johnston, Rhode Island. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting project reflected a cost effective balance of the following specific sub-objectives. 1) Meet environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas. 2) Utilize proven and reliable technology and equipment. 3) Maximize electrical efficiency. 4) Maximize electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Central Landfill. 5) Maximize equipment uptime. 6) Minimize water consumption. 7) Minimize post-combustion emissions. To achieve the Project Objective the project consisted of several components. 1) The landfill gas collection system was modified and upgraded. 2) A State-of-the Art gas clean up and compression facility was constructed. 3) A high pressure pipeline was constructed to convey cleaned landfill gas from the clean-up and compression facility to the power plant. 4) A combined cycle electric generating facility was constructed consisting of combustion turbine generator sets, heat recovery steam generators and a steam turbine. 5) The voltage of the electricity produced was increased at a newly constructed transformer/substation and the electricity was delivered to the local transmission system. The Project produced a myriad of beneficial impacts. 1) The Project created 453 FTE construction and manufacturing jobs and 25 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. 2) By combining state-of-the-art gas clean up systems with post combustion emissions control systems, the Project established new national standards for best available control technology (BACT). 3) The Project will annually produce 365,292 MWh?s of clean energy. 4) By destroying the methane in the landfill gas, the Project will generate CO{sub 2} equivalent reductions of 164,938 tons annually. The completed facility produces 28.3 MWnet and operates 24 hours a day, seven days a week.

  18. Conceptual design and system analysis of a poly-generation system for power and olefin production from natural gas

    E-Print Network [OSTI]

    Huang, Yinlun

    from natural gas Yu Qian a,*, Jingyao Liu a , Zhixian Huang a , Andrzej Kraslawski b , Jian Cui Keywords: Poly-generation Thermodynamic analysis Natural gas Olefin a b s t r a c t In this paper, a novel poly-generation system for olefin and power production from natural gas is pro- posed, which integrates

  19. Stresa, Italy, 26-28 April 2006 A SILICON-BASED MICRO GAS TURBINE ENGINE FOR POWER GENERATION

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Stresa, Italy, 26-28 April 2006 A SILICON-BASED MICRO GAS TURBINE ENGINE FOR POWER GENERATION X. C in developing a micro power generation system based on gas turbine engine and piezoelectric converter. The micro gas turbine engine consists of a micro combustor, a turbine and a centrifugal compressor

  20. CALCULATION OF DEMONSTRATION BULK VITRIFICATION SYSTEM MELTER INLEAKAGE AND OFF-GAS GENERATION RATE

    SciTech Connect (OSTI)

    MAY TH

    2008-04-16

    The River Protection Project (RPP) mission is to safely store, retrieve, treat, immobilize, and dispose of the Hanford Site tank waste. The Demonstration Bulk Vitrification System (DBVS) is a research and development project whose objective is to demonstrate the suitability of Bulk Vitrification treatment technology waste form for disposing of low-activity waste from the Tank Farms. The objective of this calculation is to determine the DBVS melter inleakage and off-gas generation rate based on full scale testing data from 38D. This calculation estimates the DBVS melter in leakage and gas generation rate based on test data. Inleakage is estimated before the melt was initiated, at one point during the melt, and at the end of the melt. Maximum gas generation rate is also estimated.

  1. Quality Assurance Project Plan for the Gas Generation Testing Program at the INEL

    SciTech Connect (OSTI)

    NONE

    1994-10-01

    The data quality objectives (DQOs) for the Program are to evaluate compliance with the limits on total gas generation rates, establish the concentrations of hydrogen and methane in the total gas flow, determine the headspace concentration of VOCs in each drum prior to the start of the test, and obtain estimates of the concentrations of several compounds for mass balance purposes. Criteria for the selection of waste containers at the INEL and the parameters that must be characterized prior to and during the tests are described. Collection of gaseous samples from 55-gallon drums of contact-handled transuranic waste for the gas generation testing is discussed. Analytical methods and calibrations are summarized. Administrative quality control measures described in this QAPjP include the generation, review, and approval of project documentation; control and retention of records; measures to ensure that personnel, subcontractors or vendors, and equipment meet the specifications necessary to achieve the required data quality for the project.

  2. Gas generation from low-level radioactive waste: Concerns for disposal

    SciTech Connect (OSTI)

    Siskind, B.

    1992-01-01

    The Advisory Committee on Nuclear Waste (ACNW) has urged the Nuclear Regulatory Commission (NRC) to reexamine the topic of hydrogen gas generation from low-level radioactive waste (LLW) in closed spaces to ensure that the slow buildup of hydrogen from water-bearing wastes in sealed containers does not become a problem for long-term safe disposal. Brookhaven National Laboratory (BNL) has prepared a report, summarized in this paper, for the NRC to respond to these concerns. The paper discusses the range of values for G(H{sub 2}) reported for materials of relevance to LLW disposal; most of these values are in the range of 0.1 to 0.6. Most studies of radiolytic hydrogen generation indicate a leveling off of pressurization, probably because of chemical kinetics involving, in many cases, the radiolysis of water within the waste. Even if no leveling off occurs, realistic gas leakage rates (indicating poor closure by gaskets on drums and liners) will result in adequate relief of pressure for radiolytic gas generation from the majority of commercial sector LLW packages. Biodegradative gas generation, however, could pose a pressurization hazard even at realistic gas leakage rates. Recommendations include passive vents on LLW containers (as already specified for high integrity containers) and upper limits to the G values and/or the specific activity of the LLW.

  3. Gas generation from low-level radioactive waste: Concerns for disposal

    SciTech Connect (OSTI)

    Siskind, B.

    1992-04-01

    The Advisory Committee on Nuclear Waste (ACNW) has urged the Nuclear Regulatory Commission (NRC) to reexamine the topic of hydrogen gas generation from low-level radioactive waste (LLW) in closed spaces to ensure that the slow buildup of hydrogen from water-bearing wastes in sealed containers does not become a problem for long-term safe disposal. Brookhaven National Laboratory (BNL) has prepared a report, summarized in this paper, for the NRC to respond to these concerns. The paper discusses the range of values for G(H{sub 2}) reported for materials of relevance to LLW disposal; most of these values are in the range of 0.1 to 0.6. Most studies of radiolytic hydrogen generation indicate a leveling off of pressurization, probably because of chemical kinetics involving, in many cases, the radiolysis of water within the waste. Even if no leveling off occurs, realistic gas leakage rates (indicating poor closure by gaskets on drums and liners) will result in adequate relief of pressure for radiolytic gas generation from the majority of commercial sector LLW packages. Biodegradative gas generation, however, could pose a pressurization hazard even at realistic gas leakage rates. Recommendations include passive vents on LLW containers (as already specified for high integrity containers) and upper limits to the G values and/or the specific activity of the LLW.

  4. Life Cycle GHG Emissions from Conventional Natural Gas Power Generation: Systematic Review and Harmonization (Presentation)

    SciTech Connect (OSTI)

    Heath, G.; O'Donoughue, P.; Whitaker, M.

    2012-12-01

    This research provides a systematic review and harmonization of the life cycle assessment (LCA) literature of electricity generated from conventionally produced natural gas. We focus on estimates of greenhouse gases (GHGs) emitted in the life cycle of electricity generation from conventionally produced natural gas in combustion turbines (NGCT) and combined-cycle (NGCC) systems. A process we term "harmonization" was employed to align several common system performance parameters and assumptions to better allow for cross-study comparisons, with the goal of clarifying central tendency and reducing variability in estimates of life cycle GHG emissions. This presentation summarizes preliminary results.

  5. Recovery Act: Brea California Combined Cycle Electric Generating Plant Fueled by Waste Landfill Gas

    SciTech Connect (OSTI)

    Galowitz, Stephen

    2012-12-31

    The primary objective of the Project was to maximize the productive use of the substantial quantities of waste landfill gas generated and collected at the Olinda Landfill near Brea, California. An extensive analysis was conducted and it was determined that utilization of the waste gas for power generation in a combustion turbine combined cycle facility was the highest and best use. The resulting Project reflected a cost effective balance of the following specific sub-objectives: • Meeting the environmental and regulatory requirements, particularly the compliance obligations imposed on the landfill to collect, process and destroy landfill gas • Utilizing proven and reliable technology and equipment • Maximizing electrical efficiency • Maximizing electric generating capacity, consistent with the anticipated quantities of landfill gas generated and collected at the Olinda Landfill • Maximizing equipment uptime • Minimizing water consumption • Minimizing post-combustion emissions • The Project produced and will produce a myriad of beneficial impacts. o The Project created 360 FTE construction and manufacturing jobs and 15 FTE permanent jobs associated with the operation and maintenance of the plant and equipment. o By combining state-of-the-art gas clean up systems with post combustion emissions control systems, the Project established new national standards for best available control technology (BACT). o The Project will annually produce 280,320 MWh’s of clean energy o By destroying the methane in the landfill gas, the Project will generate CO2 equivalent reductions of 164,938 tons annually. The completed facility produces 27.4 MWnet and operates 24 hours a day, seven days a week.

  6. Implications of Lower Natural Gas Prices for Electric Generators in the Southeast, The

    Reports and Publications (EIA)

    2009-01-01

    This supplement to the Energy Information Administration's (EIA) May 2009 Short-Term Energy Outlook (STEO) focuses on changes in the utilization of coal- and natural-gas-fired generation capacity in the electric utility sector as the differential between delivered fuel prices narrows.

  7. Technology on In-Situ Gas Generation to Recover Residual Oil Reserves

    SciTech Connect (OSTI)

    Sayavur Bakhtiyarov

    2008-02-29

    This final technical report covers the period October 1, 1995 to February 29, 2008. This chapter begins with an overview of the history of Enhanced Oil Recovery techniques and specifically, CO2 flood. Subsequent chapters conform to the manner consistent with the Activities, Tasks, and Sub-tasks of the project as originally provided in Exhibit C1 in the Project Management Plan dated September 20, 1995. These chapters summarize the objectives, status and conclusions of the major project activities performed during the project period. The report concludes by describing technology transfer activities stemming from the project and providing a reference list of all publications of original research work generated by the project team or by others regarding this project. The overall objective of this project was a final research and development in the United States a technology that was developed at the Institute for Geology and Development of Fossil Fuels in Moscow, Russia. Before the technology can be convincingly adopted by United States oil and gas producers, the laboratory research was conducted at Mew Mexico Institute of Mining and Technology. The experimental studies were conducted to measure the volume and the pressure of the CO{sub 2} gas generated according to the new Russian technology. Two experimental devices were designed, built and used at New Mexico Tech facilities for these purposes. The designed setup allowed initiating and controlling the reaction between the 'gas-yielding' (GY) and 'gas-forming' (GF) agents proposed by Russian technology. The temperature was controlled, and the generated gas pressure and volume were recorded during the reaction process. Additionally, the effect of surfactant addition on the effectiveness of the process was studied. An alternative GY reactant was tested in order to increase the efficiency of the CO2 gas generation process. The slim tube and the core flood experimental studies were conducted to define the sweep efficiency of the in-situ generated CO{sub 2} gas. A set of core flood experiments were conducted to define effect of surfactant on recovery efficiency. The results demonstrated obvious advantages of the foamy system over the brine solution in order to achieve higher sweep efficiency and recovery coefficient. It is shown that a slug injection is not an efficient method for mixing GY and GF solutions and it can't generate considerable gas inside the slim-tube.

  8. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine induustrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100[degrees]F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600[degrees]F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  9. Second-Generation Pressurized Fluidized Bed Combustion: Small gas turbine industrial plant study

    SciTech Connect (OSTI)

    Shenker, J.; Garland, R.; Horazak, D.; Seifert, F.; Wenglarz, R.

    1992-07-01

    Second-Generation Pressurized Fluidized Bed Combustion (PFBC) plants provide a coal-fired, high-efficiency, combined-cycle system for the generation of electricity and steam. The plants use lime-based sorbents in PFB combustors to meet environmental air standards without back-end gas desulfurization equipment. The second-generation system is an improvement over earlier PFBC concepts because it can achieve gas temperatures of 2100{degrees}F and higher for improved cycle efficiency while maintaining the fluidized beds at 1600{degrees}F for enhanced sulfur capture and minimum alkali release. Second-generation PFBC systems are capable of supplying the electric and steam process needs of industrial plants. The basic second-generation system can be applied in different ways to meet a variety of process steam and electrical requirements. To evaluate the potential of these systems in the industrial market, conceptual designs have been developed for six second-generation PFBC plants. These plants cover a range of electrical outputs from 6.3 to 41.5 MWe and steam flows from 46,067 to 442,337 lb/h. Capital and operating costs have been estimated for these six plants and for equivalent (in size) conventional, coal-fired atmospheric fluidized bed combustion cogeneration plants. Economic analyses were conducted to compare the cost of steam for both the second-generation plants and the conventional plants.

  10. Plug-in electric vehicle introduction in the EU

    E-Print Network [OSTI]

    Sisternes, Fernando J. de $q (Fernando José Sisternes Jiménez)

    2010-01-01

    Plug-in electric vehicles (PEVs) could significantly reduce gasoline consumption and greenhouse gas (GHG) emissions in the EU's transport sector. However, PEV well-towheel (WTW) emissions depend on improvements in vehicle ...

  11. Variance Analysis of Wind and Natural Gas Generation under Different Market Structures: Some Observations

    SciTech Connect (OSTI)

    Bush, B.; Jenkin, T.; Lipowicz, D.; Arent, D. J.; Cooke, R.

    2012-01-01

    Does large scale penetration of renewable generation such as wind and solar power pose economic and operational burdens on the electricity system? A number of studies have pointed to the potential benefits of renewable generation as a hedge against the volatility and potential escalation of fossil fuel prices. Research also suggests that the lack of correlation of renewable energy costs with fossil fuel prices means that adding large amounts of wind or solar generation may also reduce the volatility of system-wide electricity costs. Such variance reduction of system costs may be of significant value to consumers due to risk aversion. The analysis in this report recognizes that the potential value of risk mitigation associated with wind generation and natural gas generation may depend on whether one considers the consumer's perspective or the investor's perspective and whether the market is regulated or deregulated. We analyze the risk and return trade-offs for wind and natural gas generation for deregulated markets based on hourly prices and load over a 10-year period using historical data in the PJM Interconnection (PJM) from 1999 to 2008. Similar analysis is then simulated and evaluated for regulated markets under certain assumptions.

  12. Gas Generation and Release in Near-Surface Repository at Armenian NPP - 13372

    SciTech Connect (OSTI)

    Grigoryan, G.; Amirjanyan, A.; Hovhannisyan, A.; Gondakyan, Y.

    2013-07-01

    The potential nuclear waste repository at Armenian Nuclear Power Plant (ANPP) can store Low and Intermediate Level Radioactive waste (LL/ILW). In this kind of near-surface repository for radioactive waste, significant quantities of gases may be generated as a result of microbial degradation and corrosion. A discussion is presented of the microbial and chemical degradation of cellulose. For the release of gas, it is assumed that the complete conversion of cellulosic wastes to gases by the action of microbes, is, in principle, permitted. Released radioactive gases such as {sup 14}CO{sub 2} and {sup 14}CH{sub 4} could have a direct pathway to the atmosphere. The potential impact of gas generation, accumulation and migration on the long-term of repository, should therefore be assessed properly. We present here safety assessment result of gas producing radioactive waste disposal by the inhalation dose to a maximally exposed individual above ground, based on some conservative assumptions about release from waste as well as gas generation calculations. (authors)

  13. Technology Adoption and Regulatory Regimes: Gas Turbines Electricity Generators from 1980 to 2001

    E-Print Network [OSTI]

    Ishii, Jun

    2004-01-01

    operation of gas turbines (especially combustion turbines inthe development of gas turbines, especially combustion gas

  14. GAS-GENERATION EXPERIMENTS FOR LONG-TERM STORAGE OF TRU WASTES AT WIPP

    SciTech Connect (OSTI)

    Felicione, F.S.; Carney, K.P.; Dwight, C.C.; Cummings, D.G.; Foulkrod, L.E.

    2003-02-27

    An experimental investigation was conducted for gas generation in contact-handled transuranic (CH-TRU) wastes subjected for several years to conditions similar to those expected to occur at the Waste Isolation Pilot Plant (WIPP) should the repository eventually become inundated with brine. Various types of actual CH-TRU wastes were placed into 12 corrosion-resistant vessels. The vessels were loosely filled with the wastes, which were submerged in synthetic brine having the same chemical composition as that in the WIPP vicinity. The vessels were also inoculated with microbes found in the Salado Formation at WIPP. The vessels were sealed, purged, and the approximately 750-ml headspace was pressurized with nitrogen gas to approximately 146 atmospheres to create anoxic conditions at the lithostatic pressure expected in the repository were it inundated. The temperature was maintained at the expected 30 C. The test program objective was to measure the quantities and species of gases generate d by metal corrosion, radiolysis, and microbial activity. These data will assist in the specification of the rates at which gases are produced under inundated repository conditions for use in the WIPP Performance Assessment computer models. These experiments were very carefully designed, constructed, instrumented, and performed. Approximately 6-1/2 years of continuous, undisturbed testing were accumulated. Several of the vessels showed significantly elevated levels of generated gases, virtually all of which was hydrogen. One vessel measured over 4.2% hydrogen, by volume. Two other vessels generated well over 1% hydrogen, and another was at nearly 1%. Only small quantities of other gases, principally carbon dioxide, were detected. Gas generation was found to depend strongly on the waste composition. The maximum hydrogen generation occurred in tests containing carbon steel. Average corrosion penetration rates in carbon-steel of up to 2.3 microns per year were deduced. Conversion of carbon to carbon dioxide was calculated to be up to 4.7 {micro}g-mol/yr/g-carbon.

  15. Hydrogen Gas Generation Model for Fuel Based Remote Handled TRU Waste Stored at INEEL

    SciTech Connect (OSTI)

    Soli T. Khericha; Rajiv N. Bhatt; Kevin Liekhus

    2003-02-01

    The Idaho National Environmental and Engineering Laboratory (INEEL) initiated efforts to calculate the hydrogen gas generation in remote-handled transuranic (RH-TRU) containers in order to evaluate continued storage of unvented RH-TRU containers in vaults and to identify any potential problems during retrieval and aboveground storage. A computer code is developed to calculate the hydrogen concentration in the stored RH-TRU waste drums for known configuration, waste matrix, and radionuclide inventories as a function of time.

  16. The DOE/NREL Next Generation Natural Gas Vehicle Program - An Overview

    SciTech Connect (OSTI)

    Kevin Walkowicz; Denny Stephens; Kevin Stork

    2001-05-14

    This paper summarizes the Next Generation Natural Gas Vehicle (NG-NGV) Program that is led by the U.S. Department Of Energy's (DOE's) Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The goal of this program is to develop and implement one Class 3-6 compressed natural gas (CNG) prototype vehicle and one Class 7-8 liquefied natural gas (LNG) prototype vehicle in the 2004 to 2007 timeframe. OHVT intends for these vehicles to have 0.5 g/bhp-hr or lower emissions of oxides of nitrogen (NOx) by 2004 and 0.2 g/bhp-hr or lower NOx by 2007. These vehicles will also have particulate matter (PM) emissions of 0.01 g/bhp-hr or lower by 2004. In addition to ambitious emissions goals, these vehicles will target life-cycle economics that are compatible with their conventionally fueled counterparts.

  17. Accounting for fuel price risk when comparing renewable togas-fired generation: the role of forward natural gas prices

    SciTech Connect (OSTI)

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2004-07-17

    Unlike natural gas-fired generation, renewable generation (e.g., from wind, solar, and geothermal power) is largely immune to fuel price risk. If ratepayers are rational and value long-term price stability, then--contrary to common practice--any comparison of the levelized cost of renewable to gas-fired generation should be based on a hedged gas price input, rather than an uncertain gas price forecast. This paper compares natural gas prices that can be locked in through futures, swaps, and physical supply contracts to contemporaneous long-term forecasts of spot gas prices. We find that from 2000-2003, forward gas prices for terms of 2-10 years have been considerably higher than most contemporaneous long-term gas price forecasts. This difference is striking, and implies that comparisons between renewable and gas-fired generation based on these forecasts over this period have arguably yielded results that are biased in favor of gas-fired generation.

  18. Rapid hydrogen gas generation using reactive thermal decomposition of uranium hydride.

    SciTech Connect (OSTI)

    Kanouff, Michael P.; Van Blarigan, Peter; Robinson, David B.; Shugard, Andrew D.; Gharagozloo, Patricia E.; Buffleben, George M.; James, Scott Carlton; Mills, Bernice E.

    2011-09-01

    Oxygen gas injection has been studied as one method for rapidly generating hydrogen gas from a uranium hydride storage system. Small scale reactors, 2.9 g UH{sub 3}, were used to study the process experimentally. Complimentary numerical simulations were used to better characterize and understand the strongly coupled chemical and thermal transport processes controlling hydrogen gas liberation. The results indicate that UH{sub 3} and O{sub 2} are sufficiently reactive to enable a well designed system to release gram quantities of hydrogen in {approx} 2 seconds over a broad temperature range. The major system-design challenge appears to be heat management. In addition to the oxidation tests, H/D isotope exchange experiments were performed. The rate limiting step in the overall gas-to-particle exchange process was found to be hydrogen diffusion in the {approx}0.5 {mu}m hydride particles. The experiments generated a set of high quality experimental data; from which effective intra-particle diffusion coefficients can be inferred.

  19. Accounting for fuel price risk when comparing renewable to gas-fired generation: the role of forward natural gas prices

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2004-01-01

    Profiles of Renewable and Natural Gas Electricity Contracts:Price Risk: Using Forward Natural Gas Prices Instead of Gas2001). “Which way the natural gas price: an attempt to

  20. Accounting for fuel price risk when comparing renewable to gas-fired generation: the role of forward natural gas prices

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2004-01-01

    Risk: Using Forward Natural Gas Prices Instead of Gas Price2001). “Which way the natural gas price: an attempt toThe Role of Forward Natural Gas Prices Mark Bolinger, Ryan

  1. Slurry growth, gas retention, and flammable gas generation by Hanford radioactive waste tanks: Synthetic waste studies, FY 1991

    SciTech Connect (OSTI)

    Bryan, S.A.; Pederson, L.R.; Ryan, J.L.; Scheele, R.D.; Tingey, J.M.

    1992-08-01

    Of 177 high-level waste storage tanks on the Hanford Site, 23 have been placed on a safety watch list because they are suspected of producing flammable gases in flammable or explosive concentrate. One tankin particular, Tank 241-SY-101 (Tank 101-SY), has exhibited slow increases in waste volume followed by a rapid decrease accompanied by venting of large quantities of gases. The purpose of this study is to help determine the processes by which flammable gases are produced, retained, and eventually released from Tank 101-SY. Waste composition data for single- and double-shell waste tanks on the flammable gas watch listare critically reviewed. The results of laboratory studies using synthetic double-shell wastes are summarized, including physical and chemical properties of crusts that are formed, the stoichiometry and rate ofgas generation, and mechanisms responsible for formation of a floating crust.

  2. A Silicon-Based Micro Gas Turbine Engine for Power Generation

    E-Print Network [OSTI]

    Shan, X -C; Maeda, R; Sun, Y F; Wu, M; Hua, J S

    2007-01-01

    This paper reports on our research in developing a micro power generation system based on gas turbine engine and piezoelectric converter. The micro gas turbine engine consists of a micro combustor, a turbine and a centrifugal compressor. Comprehensive simulation has been implemented to optimal the component design. We have successfully demonstrated a silicon-based micro combustor, which consists of seven layers of silicon structures. A hairpin-shaped design is applied to the fuel/air recirculation channel. The micro combustor can sustain a stable combustion with an exit temperature as high as 1600 K. We have also successfully developed a micro turbine device, which is equipped with enhanced micro air-bearings and driven by compressed air. A rotation speed of 15,000 rpm has been demonstrated during lab test. In this paper, we will introduce our research results major in the development of micro combustor and micro turbine test device.

  3. Conversion of Mixed Oxygenates Generated from Synthesis Gas to Fuel Range Hydrocarbon

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Gerber, Mark A.; Lilga, Michael A.; Flake, Matthew D.

    2012-08-19

    The growing dependence in the U.S. on foreign crude oil supplies and increased concerns regarding greenhouse gas emission has generated considerable interest in research to develop renewable and environmentally friendly liquid hydrocarbon transportation fuels. One of the strategies for achieving this is to produce intermediate compounds such as alcohols and other simple oxygenates from biomass generated synthesis gas (mixture of carbon monoxide and hydrogen) and further convert them into liquid hydrocarbons. The focus of this research is to investigate the effects of mixed oxygenates intermediate product compositions on the conversion step to produce hydrocarbon liquids. A typical mixed oxygenate stream is expected to contain water (around 50%), alcohols, such as methanol and ethanol (around 35%), and smaller quantities of oxygenates such as acetaldehyde, acetic acid and ethyl acetate. However the ratio and the composition of the mixed oxygenate stream generated from synthesis gas vary significantly depending on the catalyst used and the process conditions. Zeolite catalyzed deoxygenation of methanol accompanied by chain growth is well understood under Methanol-to-Gasoline (MTG) like reaction conditions using an H-ZSM-5 zeolite as the catalyst6-8. Research has also been conducted to a limited extent in the past with higher alcohols, but not with other oxygenates present9-11. Also there has been little experimental investigation into mixtures containing substantial amounts of water. The latter is of particular interest because water separation from the hydrocarbon product would be less energy intensive than first removing it from the oxygenate intermediate stream prior to hydrocarbon synthesis, potentially reducing overall processing costs.

  4. Gas Generation Rates as an Indicator for the Long Term Stability of Radioactive Waste Products

    SciTech Connect (OSTI)

    Steyer, S.; Brennecke, P.; Bandt, G.; Kroger, H.

    2007-07-01

    Pursuant to the 'Act on the Peaceful Utilization of Atomic Energy and the Protection against its Hazards' (Atomic Energy Act) the Federal Office for Radiation Protection (Bundesamt fuer Strahlenschutz, BfS) is legally responsible for the construction and operation of federal facilities for the disposal of radioactive waste. Within the scope of this responsibility, particular due to par. 74(1) Ordinance on Radiation Protection, BfS defines all safety-related requirements on waste packages envisaged for disposal, establishes guidelines for the conditioning of radioactive waste and approves the fulfillment of the waste acceptance requirements within the radioactive waste quality control system. BfS also provides criteria to enable the assessment of methods for the treatment and packaging of radioactive waste to produce waste packages suitable for disposal according to par. 74(2) Ordinance on Radiation Protection. Due to the present non-availability of a repository in Germany, quality control measures for all types of radioactive waste products are carried out prior to interim storage with respect to the future disposal. As a result BfS approves the demonstrated properties of the radioactive waste packages and confirms the fulfillment of the respective requirements. After several years of storage the properties of waste packages might have changed. By proving, that such changes have no significant impact on the quality of the waste product, the effort of requalification could be minimized. Therefore, data on the long-term behavior of radioactive waste products need to be acquired and indicators to prove the long-term stability have to be quantified. Preferably, such indicators can be determined easily with non-destructive methods, even for legacy waste packages. A promising parameter is the gas generation rate. The relationship between gas generation rate and long term stability is presented as first result of an ongoing study on behalf of BfS. Permissible gas generation rates that ensure adequate product stability with respect to future disposal are to be identified. (authors)

  5. Plant power : the cost of using biomass for power generation and potential for decreased greenhouse gas emissions

    E-Print Network [OSTI]

    Cuellar, Amanda Dulcinea

    2012-01-01

    To date, biomass has not been a large source of power generation in the United States, despite the potential for greenhouse gas (GHG) benefits from displacing coal with carbon neutral biomass. In this thesis, the fuel cycle ...

  6. Accounting for fuel price risk: Using forward natural gas prices instead of gas price forecasts to compare renewable to natural gas-fired generation

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2003-01-01

    Associates, citing NYMEX natural gas bid-offer spreadAnalysis of the Market for Natural Gas Futures. ” The Energyas a Physical Hedge Against Natural Gas Price Movements. ”

  7. PV output smoothing using a battery and natural gas engine-generator.

    SciTech Connect (OSTI)

    Johnson, Jay; Ellis, Abraham; Denda, Atsushi; Morino, Kimio; Shinji, Takao; Ogata, Takao; Tadokoro, Masayuki

    2013-02-01

    In some situations involving weak grids or high penetration scenarios, the variability of photovoltaic systems can affect the local electrical grid. In order to mitigate destabilizing effects of power fluctuations, an energy storage device or other controllable generation or load can be used. This paper describes the development of a controller for coordinated operation of a small gas engine-generator set (genset) and a battery for smoothing PV plant output. There are a number of benefits derived from using a traditional generation resource in combination with the battery; the variability of the photovoltaic system can be reduced to a specific level with a smaller battery and Power Conditioning System (PCS) and the lifetime of the battery can be extended. The controller was designed specifically for a PV/energy storage project (Prosperity) and a gas engine-generator (Mesa Del Sol) currently operating on the same feeder in Albuquerque, New Mexico. A number of smoothing simulations of the Prosperity PV were conducted using power data collected from the site. By adjusting the control parameters, tradeoffs between battery use and ramp rates could be tuned. A cost function was created to optimize the control in order to balance, in this example, the need to have low ramp rates with reducing battery size and operation. Simulations were performed for cases with only a genset or battery, and with and without coordinated control between the genset and battery, e.g., without the communication link between sites or during a communication failure. The degree of smoothing without coordinated control did not change significantly because the battery dominated the smoothing response. It is anticipated that this work will be followed by a field demonstration in the near future.

  8. Waste drum gas generation sampling program at Rocky Flats during FY 1988

    SciTech Connect (OSTI)

    Roggenthen, D.K.; McFeeters, T.L.; Nieweg, R.G.

    1991-02-11

    Rocky Flats Plant Transuranic Waste Drums were sampled for gas composition. Combustibles, plastics, Raschig rings, solidified organic sludge, and solidified inorganic sludge transuranic waste forms were sampled. Plastic bag material and waste samples were also taken from some solidified sludge waste drums. A vacuum system was used to sample each layer of containment inside a waste drum, including individual waste bags. G values (gas generation) were calculated for the waste drums. Analytical results indicate that very low concentrations of potentially flammable or corrosive gas mixtures will be found in vented drums. G(H{sub 2}) was usually below 1.6, while G(Total) was below 4.0. Hydrogen permeability tests on different types of plastic waste bags used at Rocky Flats were also conducted. Polyvinylchloride was slightly more permeable to hydrogen than polyethylene for new or creased material. Permeability of aged material to hydrogen was slightly higher than for new material. Solidified organic and inorganic sludges were sampled for volatile organics. The analytical results from two drums of solidified organic sludges showed concentrations were above detection limits for four of the 36 volatile organics analyzed. The analytical results for four of the five solidified inorganic sludges show that concentrations were below detection limits for all volatile organics analyzed. 3 refs., 5 figs., 2 tabs.

  9. Technology Adoption and Regulatory Regimes: Gas Turbines Electricity Generators from 1980 to 2001

    E-Print Network [OSTI]

    Ishii, Jun

    2004-01-01

    the Relibability of Advanced Gas Turbines,” POWER Magazine.Scheibel (1997) “Current Gas Turbine Developments and Futurefor Heavy-Duty Gas Turbines,” October 2000. Available online

  10. Apples with apples: accounting for fuel price risk in comparisons of gas-fired and renewable generation

    SciTech Connect (OSTI)

    Bolinger, Mark; Wiser, Ryan

    2003-12-18

    For better or worse, natural gas has become the fuel of choice for new power plants being built across the United States. According to the US Energy Information Administration (EIA), natural gas combined-cycle and combustion turbine power plants accounted for 96% of the total generating capacity added in the US between 1999 and 2002--138 GW out of a total of 144 GW. Looking ahead, the EIA expects that gas-fired technology will account for 61% of the 355 GW new generating capacity projected to come on-line in the US up to 2025, increasing the nationwide market share of gas-fired generation from 18% in 2002 to 22% in 2025. While the data are specific to the US, natural gas-fired generation is making similar advances in other countries as well. Regardless of the explanation for (or interpretation of) the empirical findings, however, the basic implications remain the same: one should not blindly rely on gas price forecasts when comparing fixed-price renewable with variable-price gas-fired generation contracts. If there is a cost to hedging, gas price forecasts do not capture and account for it. Alternatively, if the forecasts are at risk of being biased or out of tune with the market, then one certainly would not want to use them as the basis for resource comparisons or investment decisions if a more certain source of data (forwards) existed. Accordingly, assuming that long-term price stability is valued, the most appropriate way to compare the levelized cost of these resources in both cases would be to use forward natural gas price data--i.e. prices that can be locked in to create price certainty--as opposed to uncertain natural gas price forecasts. This article suggests that had utilities and analysts in the US done so over the sample period from November 2000 to November 2003, they would have found gas-fired generation to be at least 0.3-0.6 cents/kWh more expensive (on a levelized cost basis) than otherwise thought. With some renewable resources, in particular wind power, now largely competitive with gas-fired generation in the US (including the impact of the federal production tax credit and current high gas prices), a margin of 0.3-0.6 cents/kWh may in some cases be enough to sway resource decisions in favor of renewables.

  11. Effects of current on droplet generation and arc plasma in gas metal arc welding

    SciTech Connect (OSTI)

    Hu, J.; Tsai, H. L.

    2006-09-01

    In gas metal arc welding (GMAW), a technology using pulsed currents has been employed to achieve the one-droplet-per-pulse (ODPP) metal transfer mode with the advantages of low average currents, a stable and controllable droplet generation, and reduced spatter. In this paper, a comprehensive model was developed to study the effects of different current profiles on the droplet formation, plasma generation, metal transfer, and weld pool dynamics in GMAW. Five types of welding currents were studied, including two constant currents and three wave form currents. In each type, the transient temperature and velocity distributions of the arc plasma and the molten metal, and the shapes of the droplet and the weld pool were calculated. The results showed that a higher current generates smaller droplets, higher droplet frequency, and higher electromagnetic force that becomes the dominant factor detaching the droplet from the electrode tip. The model has demonstrated that a stable ODPP metal transfer mode can be achieved by choosing a current with proper wave form for given welding conditions.

  12. Accounting for fuel price risk: Using forward natural gas prices instead of gas price forecasts to compare renewable to natural gas-fired generation

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2003-01-01

    Associates, citing NYMEX natural gas bid-offer spreadAnalysis of the Market for Natural Gas Futures. ” The EnergyProfiles of Renewable and Natural Gas Electricity Contracts:

  13. Accounting for fuel price risk: Using forward natural gas prices instead of gas price forecasts to compare renewable to natural gas-fired generation

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2003-01-01

    Theis. 2001. “Which way the natural gas price: an attempt toHedge Against Natural Gas Price Movements. ” http://Downward Pressure on Natural Gas Prices: The Impact of

  14. Preferential Eu Site Occupation and Its Consequences in the Ternary Luminescent HalidesAB2I5:Eu2+(A=Li–Cs;B=Sr, Ba)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fang, C.? M.; Biswas, Koushik

    2015-07-22

    Several rare-earth-doped, heavy-metal halides have recently been identified as potential next-generation luminescent materials with high efficiency at low cost. AB2I5:Eu2+ (A=Li–Cs; B=Sr, Ba) is one such family of halides. Its members, such as CsBa2I5:Eu2+ and KSr2I5:Eu2+, are currently being investigated as high-performance scintillators with improved sensitivity, light yield, and energy resolution less than 3% at 662 keV. Within the AB2I5 family, our first-principles-based calculations reveal two remarkably different trends in Eu site occupation. The substitutional Eu ions occupy both eightfold-coordinated B1(VIII) and the sevenfold-coordinated B2(VII) sites in the Sr-containing compounds. However, in the Ba-containing crystals, Eu ions strongly prefer themore »B2(VII)sites. This random versus preferential distribution of Eu affects their electronic properties. The calculations also suggest that in the Ba-containing compounds one can expect the formation of Eu-rich domains. These results provide atomistic insight into recent experimental observations about the concentration and temperature effects in Eu-doped CsBa2I5. We discuss the implications of our results with respect to luminescent properties and applications. We also hypothesize Sr, Ba-mixed quaternary iodides ABaVIIISrVIII5:Eu as scintillators having enhanced homogeneity and electronic properties.« less

  15. Development and application of an analysis methodology for interpreting ambiguous historical pressure data in the WIPP gas-generation experiments.

    SciTech Connect (OSTI)

    Felicione, F. S.

    2006-01-23

    The potential for generation of gases in transuranic (TRU) waste by microbial activity, chemical interactions, corrosion, and radiolysis was addressed in the Argonne National Laboratory-West (ANL-West) Gas-Generation Experiments (GGE). Data was collected over several years by simulating the conditions in the Waste Isolation Pilot Plant (WIPP) after the eventual intrusion of brine into the repository. Fourteen test containers with various actual TRU waste immersed in representative brine were inoculated with WIPP-relevant microbes, pressurized with inert gases, and kept in an inert-atmosphere environment for several years to provide estimates of the gas-generation rates that will be used in computer models for future WIPP Performance Assessments. Modest temperature variations occurred during the long-term ANL-West experiments. Although the experiment temperatures always remained well within the experiment specifications, the small temperature variation was observed to affect the test container pressure far more than had been anticipated. In fact, the pressure variations were so large, and seemingly erratic, that it was impossible to discern whether the data was even valid and whether the long-term pressure trend was increasing, decreasing, or constant. The result was that no useful estimates of gas-generation rates could be deduced from the pressure data. Several initial attempts were made to quantify the pressure fluctuations by relating these to the measured temperature variation, but none was successful. The work reported here carefully analyzed the pressure measurements to determine if these were valid or erroneous data. It was found that a thorough consideration of the physical phenomena that were occurring can, in conjunction with suitable gas laws, account quite accurately for the pressure changes that were observed. Failure of the earlier attempts to validate the data was traced to the omission of several phenomena, the most important being the variation in the headspace volume caused by thermal expansion and contraction within the brine and waste. A further effort was directed at recovering useful results from the voluminous archived pressure data. An analytic methodology to do this was developed. This methodology was applied to each archived pressure measurement to nullify temperature and other effects to yield an adjusted pressure, from which gas-generation rates could be calculated. A review of the adjusted-pressure data indicated that generated-gas concentrations among these containers after approximately 3.25 years of test operation ranged from zero to over 17,000 ppm by volume. Four test containers experienced significant gas generation. All test containers that showed evidence of significant gas generation contained carbon-steel in the waste, indicating that corrosion was the predominant source of gas generation.

  16. The Case for Natural Gas Fueled Solid Oxide Fuel Cell Power Systems for Distributed Generation

    SciTech Connect (OSTI)

    Chick, Lawrence A.; Weimar, Mark R.; Whyatt, Greg A.; Powell, Michael R.

    2015-02-01

    Natural-gas-fueled solid oxide fuel cell (NGSOFC) power systems yield electrical conversion efficiencies exceeding 60% and may become a viable alternative for distributed generation (DG) if stack life and manufacturing economies of scale can be realized. Currently, stacks last approximately 2 years and few systems are produced each year because of the relatively high cost of electricity from the systems. If mass manufacturing (10,000 units per year) and a stack life of 15 years can be reached, the cost of electricity from an NGSOFC system is estimated to be about 7.7 ¢/kWh, well within the price of commercial and residential retail prices at the national level (9.9-10¢/kWh and 11-12 ¢/kWh, respectively). With an additional 5 ¢/kWh in estimated additional benefits from DG, NGSOFC could be well positioned to replace the forecasted 59-77 gigawatts of capacity loss resulting from coal plant closures due to stricter emissions regulations and low natural gas prices.

  17. MOX and MOX with 237Np/241Am Inert Fission Gas Generation Comparison in ATR

    SciTech Connect (OSTI)

    G. S. Chang; M. Robel; W. J. Carmack; D. J. Utterbeck

    2006-06-01

    The treatment of spent fuel produced in nuclear power generation is one of the most important issues to both the nuclear community and the general public. One of the viable options to long-term geological disposal of spent fuel is to extract plutonium, minor actinides (MA), and potentially long-lived fission products from the spent fuel and transmute them into short-lived or stable radionuclides in currently operating light-water reactors (LWR), thus reducing the radiological toxicity of the nuclear waste stream. One of the challenges is to demonstrate that the burnup-dependent characteristic differences between Reactor-Grade Mixed Oxide (RG-MOX) fuel and RG-MOX fuel with MA Np-237 and Am 241 are minimal, particularly, the inert gas generation rate, such that the commercial MOX fuel experience base is applicable. Under the Advanced Fuel Cycle Initiative (AFCI), developmental fuel specimens in experimental assembly LWR-2 are being tested in the northwest (NW) I-24 irradiation position of the Advanced Test Reactor (ATR). The experiment uses MOX fuel test hardware, and contains capsules with MOX fuel consisting of mixed oxide manufactured fuel using reactor grade plutonium (RG-Pu) and mixed oxide manufactured fuel using RG-Pu with added Np/Am. This study will compare the fuel neutronics depletion characteristics of Case-1 RG-MOX and Case-2 RG-MOX with Np/Am.

  18. Accounting for fuel price risk when comparing renewable to gas-fired generation: the role of forward natural gas prices

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2004-01-01

    Energy Futures: Recent Evidence for Crude Oil, Natural Gas,Gasoline and Heating Oil. UCSC Economics Working Paper No.Papapetrou, E. (2001). "Oil Price Shocks, Stock Market,

  19. Life Cycle Greenhouse Gas Emissions of Coal-Fired Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Whitaker, M.; Heath, G. A.; O'Donoughue, P.; Vorum, M.

    2012-04-01

    This systematic review and harmonization of life cycle assessments (LCAs) of utility-scale coal-fired electricity generation systems focuses on reducing variability and clarifying central tendencies in estimates of life cycle greenhouse gas (GHG) emissions. Screening 270 references for quality LCA methods, transparency, and completeness yielded 53 that reported 164 estimates of life cycle GHG emissions. These estimates for subcritical pulverized, integrated gasification combined cycle, fluidized bed, and supercritical pulverized coal combustion technologies vary from 675 to 1,689 grams CO{sub 2}-equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh) (interquartile range [IQR]= 890-1,130 g CO{sub 2}-eq/kWh; median = 1,001) leading to confusion over reasonable estimates of life cycle GHG emissions from coal-fired electricity generation. By adjusting published estimates to common gross system boundaries and consistent values for key operational input parameters (most importantly, combustion carbon dioxide emission factor [CEF]), the meta-analytical process called harmonization clarifies the existing literature in ways useful for decision makers and analysts by significantly reducing the variability of estimates ({approx}53% in IQR magnitude) while maintaining a nearly constant central tendency ({approx}2.2% in median). Life cycle GHG emissions of a specific power plant depend on many factors and can differ from the generic estimates generated by the harmonization approach, but the tightness of distribution of harmonized estimates across several key coal combustion technologies implies, for some purposes, first-order estimates of life cycle GHG emissions could be based on knowledge of the technology type, coal mine emissions, thermal efficiency, and CEF alone without requiring full LCAs. Areas where new research is necessary to ensure accuracy are also discussed.

  20. Low NO{sub x} turbine power generation utilizing low Btu GOB gas. Final report, June--August 1995

    SciTech Connect (OSTI)

    Ortiz, I.; Anthony, R.V.; Gabrielson, J.; Glickert, R.

    1995-08-01

    Methane, a potent greenhouse gas, is second only to carbon dioxide as a contributor to potential global warming. Methane liberated by coal mines represents one of the most promising under exploited areas for profitably reducing these methane emissions. Furthermore, there is a need for apparatus and processes that reduce the nitrogen oxide (NO{sub x}) emissions from gas turbines in power generation. Consequently, this project aims to demonstrate a technology which utilizes low grade fuel (CMM) in a combustion air stream to reduce NO{sub x} emissions in the operation of a gas turbine. This technology is superior to other existing technologies because it can directly use the varying methane content gases from various streams of the mining operation. The simplicity of the process makes it useful for both new gas turbines and retrofitting existing gas turbines. This report evaluates the feasibility of using gob gas from the 11,000 acre abandoned Gateway Mine near Waynesburg, Pennsylvania as a fuel source for power generation applying low NO{sub x} gas turbine technology at a site which is currently capable of producing low grade GOB gas ({approx_equal} 600 BTU) from abandoned GOB areas.

  1. An Approach to Generating Summaries of Time Series Data in the Gas Turbine Domain Jin Yu and Jim Hunter and Ehud Reiter and Somayajulu Sripada

    E-Print Network [OSTI]

    Sripada, Yaji

    An Approach to Generating Summaries of Time Series Data in the Gas Turbine Domain Jin Yu and Jim an approach to generating summaries of time series data in the gas turbine domain using AI techniques. Through), both domain knowledge from experts about how to solve problems in the gas turbine and information about

  2. EU Gas Supply Security: Unfinished Business

    E-Print Network [OSTI]

    Noël, Pierre

    2013-04-01

    production. Exploration work was suspended after hydraulic fracturing-induced seismic activity was reported but the government allowed companies to resume work in late 2012. The UK enjoys a relatively wide political consensus that, given the right... increasingly unlikely to be materialised. A summary of the situation is provided by an IEA report from 2012. 15 The bleak situation in France – where most of western Europe’s reserves are located but hydraulic fracturing was banned by a law passed nearly...

  3. Assessment of the impact of the next generation solvent on DWPF melter off-gas flammability

    SciTech Connect (OSTI)

    Daniel, W. E.

    2013-02-13

    An assessment has been made to evaluate the impact on the DWPF melter off-gas flammability of replacing the current solvent used in the Modular Caustic-Side Solvent Extraction Process Unit (MCU) process with the Next Generation Solvent (NGS-MCU) and blended solvent. The results of this study showed that the concentrations of nonvolatile carbon and hydrogen of the current solvent in the Slurry Mix Evaporator (SME) product would both be about 29% higher than their counterparts of the NGS-MCU and blended solvent in the absence of guanidine partitioning. When 6 ppm of guanidine (TiDG) was added to the effluent transfer to DWPF to simulate partitioning for the NGS-MCU and blended solvent cases and the concentration of Isopar{reg_sign} L in the effluent transfer was controlled below 87 ppm, the concentrations of nonvolatile carbon and hydrogen of the NGS-MCU and blended solvent were still about 12% and 4% lower, respectively, than those of the current solvent. It is, therefore, concluded that as long as the volume of MCU effluent transfer to DWPF is limited to 15,000 gallons per Sludge Receipt and Adjustment Tank (SRAT)/SME cycle and the concentration of Isopar{reg_sign} L in the effluent transfer is controlled below 87 ppm, using the current solvent assumption of 105 ppm Isopar{reg_sign} L or 150 ppm solvent in lieu of NGS-MCU or blended solvent in the DWPF melter off-gas flammability assessment is conservative for up to an additional 6 ppm of TiDG in the effluent due to guanidine partitioning. This report documents the calculations performed to reach this conclusion.

  4. Generation of gas-phase zirconium fluoroanions by electrospray of an ionic liquid

    SciTech Connect (OSTI)

    Gary S. Groenewold; James E. Delmore; Michael T. Benson; Tetsuya Tsuda; Rika Hagiwara

    2014-06-01

    RATIONALE: When measuring extremely wide isotope ratios (= 1 x 109) accelerator mass spectrometry (AMS) is the instrument of choice, however it requires an anion for injection into the tandem accelerator. Since many elements do not have positive electronegativities they do not form stable negative atomic ions, and hence are not compatible for isotope ratio measurement using AMS. Thus new approaches for forming anions are sought; fluoroanions are particularly attractive because fluorine is monoisotopic, and thus will not have overlapping isobars with the isotope of interest. METHODS: An approach is described for making zirconium fluoroanions using the fluorinating ionic liquid (IL) 1-ethyl-3-methylimidazolium fluorohydrogenate, which was used to generate abundant [ZrF5-] using electrospray ionization. The IL was dissolved in acetonitrile, combined with a dilute solution of either Zr4+ or ZrO2+, and then electrosprayed. Mass analysis and collision induced dissociation were conducted using a time-of-flight mass spectrometer. Cluster structures were predicted using density functional theory calculations. RESULTS: The fluorohydrogenate IL solutions generated abundant [ZrF5-] starting from solutions of both Zr4+ and ZrO2+. The mass spectra also contained IL-bearing cluster ions, whose compositions indicated the presence of [ZrF6]2- in solution, a conclusion supported by the structural calculations. Rinsing out the zirconium-IL solution with acetonitrile decreased the IL clusters, but enhanced [ZrF5]-, which was sorbed by the polymeric electrospray supply capillary, and then released upon rinsing. This reduced the ion background in the mass spectrum. CONCLUSIONS: The fluorohydrogenate-IL solutions are a facile way to form zirconium fluoroanions in the gas phase using electrospray. The approach has potential as a source of fluoroanions for injection into an AMS, which would enable high-sensitivity measurement of minor zirconium isotopes, and benefits from the absence of overlapping isobars caused by the charge carrier (i.e., the monoisotopic fluorine atoms).

  5. Next generation gas turbines will be required to produce low concentrations of pollutants such as oxides of nitrogen (NOx), carbon monoxide (CO), and soot. In order to design gas turbines which produce lower emissions it is essential

    E-Print Network [OSTI]

    Next generation gas turbines will be required to produce low concentrations of pollutants such as oxides of nitrogen (NOx), carbon monoxide (CO), and soot. In order to design gas turbines which produce

  6. Accounting for fuel price risk: Using forward natural gas prices instead of gas price forecasts to compare renewable to natural gas-fired generation

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan; Golove, William

    2003-01-01

    and renewable generation. For example, utilities and independent system operators sometimes financially penalize wind power to

  7. Thermal and Radiolytic Gas Generation Tests on Material from Tanks 241-U-103, 241-AW-101, 241-S-106, and 241-S-102: Status Report

    SciTech Connect (OSTI)

    King, C.M.; Bryan, S.A.

    1999-06-17

    This report summarizes progress in evaluating thermal and radiolytic flammable gas generation in actual Hanford single-shell tank wastes. The work described was conducted at Pacific Northwest National Laboratory (PNNL) for the Flammable Gas Safety Project, whose purpose is to develop information to support DE&S Hanford (DESH) and Project Management Hanford Contract (PHMC) subcontractors in their efforts to ensure the safe interim storage of wastes at the Hanford Site. This work is related to gas generation studies performed by Numatec Hanford Corporation (formerly Westinghouse Hanford Company). This report describes the results of laboratory tests of gas generation from actual convective layer wastes from Tank 241-U-103 under thermal and radiolytic conditions. Accurate measurements of gas generation rates from highly radioactive tank wastes are needed to assess the potential for producing and storing flammable gases within the tanks. The gas generation capacity of the waste in Tank 241-U-103 is a high priority for the Flammable Gas Safety Program due to its potential for accumulating gases above the flammability limit (Johnson et al, 1997). The objective of this work was to establish the composition of gaseous degradation products formed in actual tank wastes by thermal and radiolytic processes as a function of temperature. The gas generation tests on Tank 241-U-103 samples focused first on the effect of temperature on the composition and rate of gas generation Generation rates of nitrogen, nitrous oxide, methane, and hydrogen increased with temperature, and the composition of the product gas mixture varied with temperature.

  8. Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation

    SciTech Connect (OSTI)

    Rue, David

    2013-09-30

    The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis found a number of modifications and adjustments that could provide higher efficiency and better use of available work. Conclusions from this analysis will help guide the analyses and CFD modeling in future process development. The MBB technology has the potential to be a disruptive technology that will enable coal combustion power plants to be built and operated in a cost effective way, cleanly with no carbon dioxide emissions. A large amount of work is needed to quantify and confirm the great promise of the MBB technology. A Phase 2 proposal was submitted to DOE and other sponsors to address the most critical MBB process technical gaps. The Phase 2 proposal was not accepted for current DOE support.

  9. Onboard Plasmatron Generation of Hydrogen rich Gas for Diesel Engine Exhaust Aftertreatment and Other Applications

    SciTech Connect (OSTI)

    Bromberg, L.; Cohn, D.R.; Heywood,J.; Rabinovich, A.

    2002-08-25

    Plasmatron reformers can provide attractive means for conversion of diesel fuel into hydrogen rich gas. The hydrogen rich gas can be used for improved NOx trap technology and other aftertreatment applications.

  10. 3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing

    Broader source: Energy.gov [DOE]

    SCR system provides direct ammonia gas dosing for optimal SCR performance with simplified and flexible exhaust layout.

  11. Mitigation of Hydrogen Gas Generation from the Reaction of Water with Uranium Metal in K Basins Sludge

    SciTech Connect (OSTI)

    Sinkov, Sergey I.; Delegard, Calvin H.; Schmidt, Andrew J.

    2010-01-29

    Means to decrease the rate of hydrogen gas generation from the chemical reaction of uranium metal with water were identified by surveying the technical literature. The underlying chemistry and potential side reactions were explored by conducting 61 principal experiments. Several methods achieved significant hydrogen gas generation rate mitigation. Gas-generating side reactions from interactions of organics or sludge constituents with mitigating agents were observed. Further testing is recommended to develop deeper knowledge of the underlying chemistry and to advance the technology aturation level. Uranium metal reacts with water in K Basin sludge to form uranium hydride (UH3), uranium dioxide or uraninite (UO2), and diatomic hydrogen (H2). Mechanistic studies show that hydrogen radicals (H·) and UH3 serve as intermediates in the reaction of uranium metal with water to produce H2 and UO2. Because H2 is flammable, its release into the gas phase above K Basin sludge during sludge storage, processing, immobilization, shipment, and disposal is a concern to the safety of those operations. Findings from the technical literature and from experimental investigations with simple chemical systems (including uranium metal in water), in the presence of individual sludge simulant components, with complete sludge simulants, and with actual K Basin sludge are presented in this report. Based on the literature review and intermediate lab test results, sodium nitrate, sodium nitrite, Nochar Acid Bond N960, disodium hydrogen phosphate, and hexavalent uranium [U(VI)] were tested for their effects in decreasing the rate of hydrogen generation from the reaction of uranium metal with water. Nitrate and nitrite each were effective, decreasing hydrogen generation rates in actual sludge by factors of about 100 to 1000 when used at 0.5 molar (M) concentrations. Higher attenuation factors were achieved in tests with aqueous solutions alone. Nochar N960, a water sorbent, decreased hydrogen generation by no more than a factor of three while disodium phosphate increased the corrosion and hydrogen generation rates slightly. U(VI) showed some promise in attenuating hydrogen but only initial testing was completed. Uranium metal corrosion rates also were measured. Under many conditions showing high hydrogen gas attenuation, uranium metal continued to corrode at rates approaching those observed without additives. This combination of high hydrogen attenuation with relatively unabated uranium metal corrosion is significant as it provides a means to eliminate uranium metal by its corrosion in water without the accompanying hazards otherwise presented by hydrogen generation.

  12. Modeling EU electricity market competition using the residual supply index

    SciTech Connect (OSTI)

    Swinand, Gregory; Scully, Derek; Ffoulkes, Stuart; Kessler, Brian

    2010-11-15

    An econometric approach to related hourly Residual Supply Index to price-cost margins in the major EU electricity generation markets suggests that market structure, as measured by the RSI, is a significant explanatory factor for markups, even when scarcity and other explanatory variables are included. (author)

  13. Comparative life-cycle air emissions of coal, domestic natural gas, LNG, and SNG for electricity generation

    SciTech Connect (OSTI)

    Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews

    2007-09-15

    The U.S. Department of Energy (DOE) estimates that in the coming decades the United States' natural gas (NG) demand for electricity generation will increase. Estimates also suggest that NG supply will increasingly come from imported liquefied natural gas (LNG). Additional supplies of NG could come domestically from the production of synthetic natural gas (SNG) via coal gasification-methanation. The objective of this study is to compare greenhouse gas (GHG), SOx, and NOx life-cycle emissions of electricity generated with NG/LNG/SNG and coal. This life-cycle comparison of air emissions from different fuels can help us better understand the advantages and disadvantages of using coal versus globally sourced NG for electricity generation. Our estimates suggest that with the current fleet of power plants, a mix of domestic NG, LNG, and SNG would have lower GHG emissions than coal. If advanced technologies with carbon capture and sequestration (CCS) are used, however, coal and a mix of domestic NG, LNG, and SNG would have very similar life-cycle GHG emissions. For SOx and NOx we find there are significant emissions in the upstream stages of the NG/LNG life-cycles, which contribute to a larger range in SOx and NOx emissions for NG/LNG than for coal and SNG. 38 refs., 3 figs., 2 tabs.

  14. Radcalc for windows benchmark study: A comparison of software results with Rocky Flats hydrogen gas generation data

    SciTech Connect (OSTI)

    MCFADDEN, J.G.

    1999-07-19

    Radcalc for Windows Version 2.01 is a user-friendly software program developed by Waste Management Federal Services, Inc., Northwest Operations for the U.S. Department of Energy (McFadden et al. 1998). It is used for transportation and packaging applications in the shipment of radioactive waste materials. Among its applications are the classification of waste per the US. Department of Transportation regulations, the calculation of decay heat and daughter products, and the calculation of the radiolytic production of hydrogen gas. The Radcalc program has been extensively tested and validated (Green et al. 1995, McFadden et al. 1998) by comparison of each Radcalc algorithm to hand calculations. An opportunity to benchmark Radcalc hydrogen gas generation calculations to experimental data arose when the Rocky Flats Environmental Technology Site (RFETS) Residue Stabilization Program collected hydrogen gas generation data to determine compliance with requirements for shipment of waste in the TRUPACT-II (Schierloh 1998). The residue/waste drums tested at RFETS contain contaminated, solid, inorganic materials in polyethylene bags. The contamination is predominantly due to plutonium and americium isotopes. The information provided by Schierloh (1 998) of RFETS includes decay heat, hydrogen gas generation rates, calculated G{sub eff} values, and waste material type, making the experimental data ideal for benchmarking Radcalc. The following sections discuss the RFETS data and the Radcalc cases modeled with the data. Results are tabulated and also provided graphically.

  15. EU,EU, EnergyEnergy, and Global, and Global ClimateClimate ChangeChange Kirsten Halsns

    E-Print Network [OSTI]

    about mitigation cost estimates incl. USA, EU, China, India and other DC's. · But of renewablesrenewables in the total electricity supply can rise fromin the total electricity supply can rise from 18 at electricity generation without CCS drops toFossil fuel share

  16. ITER: Japan to assign 20 percent of construction work to EU firms; Proposal for EU official to assume chief executive

    E-Print Network [OSTI]

    Experimental Reactor (ITER). Japan yesterday revealed the details of a proposal to host the project. Tokyo has, Japan bears half price even with construction inside the EU limits of the accessory structures prospect. The experimental device in order ITER generates electricity, reproducing the fusion reaction

  17. Steam Generator Component Model in a Combined Cycle of Power Conversion Unit for Very High Temperature Gas-Cooled Reactor

    SciTech Connect (OSTI)

    Oh, Chang H; Han, James; Barner, Robert; Sherman, Steven R

    2007-06-01

    The Department of Energy and the Idaho National Laboratory are developing a Next Generation Nuclear Plant (NGNP), Very High Temperature Gas-Cooled Reactor (VHTR) to serve as a demonstration of state-of-the-art nuclear technology. The purpose of the demonstration is two fold 1) efficient low cost energy generation and 2) hydrogen production. Although a next generation plant could be developed as a single-purpose facility, early designs are expected to be dual-purpose. While hydrogen production and advanced energy cycles are still in its early stages of development, research towards coupling a high temperature reactor, electrical generation and hydrogen production is under way. A combined cycle is considered as one of the power conversion units to be coupled to the very high-temperature gas-cooled reactor (VHTR). The combined cycle configuration consists of a Brayton top cycle coupled to a Rankine bottoming cycle by means of a steam generator. A detailed sizing and pressure drop model of a steam generator is not available in the HYSYS processes code. Therefore a four region model was developed for implementation into HYSYS. The focus of this study was the validation of a HYSYS steam generator model of two phase flow correlations. The correlations calculated the size and heat exchange of the steam generator. To assess the model, those calculations were input into a RELAP5 model and its results were compared with HYSYS results. The comparison showed many differences in parameters such as the heat transfer coefficients and revealed the different methods used by the codes. Despite differences in approach, the overall results of heat transfer were in good agreement.

  18. A Low-Cost, High-Efficiency Periodic Flow Gas Turbine for Distributed Energy Generation

    SciTech Connect (OSTI)

    Dr. Adam London

    2008-06-20

    The proposed effort served as a feasibility study for an innovative, low-cost periodic flow gas turbine capable of realizing efficiencies in the 39-48% range.

  19. High Pressure Superheater 1 (HPSH1) is the first heat exchange tube bank inside the Heat Recovery Steam Generator (HRSG) to encounter exhaust flue gas from the gas turbine of a Combined Cycle Power Plant. Steam

    E-Print Network [OSTI]

    Steam Generator (HRSG) to encounter exhaust flue gas from the gas turbine of a Combined Cycle Power Plant. Steam flowing through the HPSH1 gains heat from the flue gas prior to entering the steam turbine changes that occurred, especially in the steam temperature at the HPSH1 entry, and the different rates

  20. Generating Methane Gas From Manure Charles D. Fulhage, Dennis Sievers and James R. Fischer

    E-Print Network [OSTI]

    Laughlin, Robert B.

    potential The immediate and obvious benefit from methane production is the energy value of the gas itself the pH, inhibiting the methane bacteria and stopping gas production. To help buffer the system against of livestock manure. To avoid the problem, loading rates must be carefully controlled. Methane production

  1. Hydrogen Gas Generation Model for Fuel-Based Remote-Handled Transuranic Waste Stored at the INEEL

    SciTech Connect (OSTI)

    Khericha, S.; Bhatt, R.; Liekhus, K.

    2003-01-14

    The Idaho National Environmental and Engineering Laboratory (INEEL) initiated efforts to calculate the hydrogen gas generation in remote-handled transuranic (RH-TRU) containers in order to evaluate continued storage of unvented RH-TRU containers in vaults and to identify any potential problems during retrieval and aboveground storage. A computer code is developed to calculate the hydrogen concentration in the stored RH-TRU waste drums for known configuration, waste matrix, and radionuclide inventories as a function of time.

  2. Control Scheme Modifications Increase Efficiency of Steam Generation System at Exxon Mobil Gas Plant

    SciTech Connect (OSTI)

    2002-01-01

    This case study highlights control scheme modifications made to the steam system at ExxonMobil's Mary Ann Gas Plant in Mobile, Alabama, which improved steam flow efficiency and reduced energy costs.

  3. Method of Generating Hydrocarbon Reagents from Diesel, Natural Gas and Other Logistical Fuels

    DOE Patents [OSTI]

    Herling, Darrell R (Richland, WA) [Richland, WA; Aardahl, Chris L. (Richland, WA) [Richland, WA; Rozmiarek, Robert T. (Middleton, WI) [Middleton, WI; Rappe, Kenneth G. (Richland, WA) [Richland, WA; Wang, Yong (Richland, WA) [Richland, WA; Holladay, Jamelyn D. (Kennewick, WA) [Kennewick, WA

    2008-10-14

    The present invention provides a process for producing reagents for a chemical reaction by introducing a fuel containing hydrocarbons into a flash distillation process wherein the fuel is separated into a first component having a lower average molecular weight and a second component having a higher average molecular weight. The first component is then reformed to produce synthesis gas wherein the synthesis gas is reacted catalytically to produce the desire reagent.

  4. Method of generating hydrocarbon reagents from diesel, natural gas and other logistical fuels

    DOE Patents [OSTI]

    Herling, Darrell R. (Richland, WA); Aardahl, Chris L. (Richland, WA); Rozmiarek, Robert T. (Middleton, WI); Rappe, Kenneth G. (Richland, WA); Wang, Yong (Richland, WA); Holladay, Jamelyn D. (Kennewick, WA)

    2010-06-29

    The present invention provides a process for producing reagents for a chemical reaction by introducing a fuel containing hydrocarbons into a flash distillation process wherein the fuel is separated into a first component having a lower average molecular weight and a second component having a higher average molecular weight. The first component is then reformed to produce synthesis gas wherein the synthesis gas is reacted catalytically to produce the desire reagent.

  5. Introduction: Explaining the EU Political System The EU: a political system but not a state

    E-Print Network [OSTI]

    Franz, Sven Oliver

    but not a state How the EU political system works Actors, institutions and outcomes: the basics of modern1 Chapter 1 Introduction: Explaining the EU Political System The EU: a political system political science Theories of European integration and EU politics The allocation of policy competences

  6. Impact study on the use of biomass-derived fuels in gas turbines for power generation

    SciTech Connect (OSTI)

    Moses, C.A.; Bernstein, H.

    1994-01-01

    This report evaluates the properties of fuels derived from biomass, both gaseous and liquid, against the fuel requirements of gas turbine systems for gernating electrical power. The report attempts to be quantitative rather than merely qualitative to establish the significant variations in the properties of biomass fuels from those of conventional fuels. Three general categories are covered: performance, durability, and storage and handling.

  7. Electrical Power Generation Using Geothermal Fluid Co-produced from Oil & Gas

    Broader source: Energy.gov [DOE]

    Project objectives: To validate and realize the potential for the production of low temperature resource geothermal production on oil & gas sites. Test and document the reliability of this new technology.; Gain a better understanding of operational costs associated with this equipment.

  8. Elevated Temperature Materials for Power Generation and Propulsion The energy industry is designing higher-efficiency land-based turbines for natural gas-fired

    E-Print Network [OSTI]

    Nair, Sankar

    higher-efficiency land-based turbines for natural gas-fired power generation systems. The high inlet is significant for modeling cyclic deformation in directionally solidified and single crystal turbine blades

  9. Limited Electricity Generation Supply and Limited Natural Gas Supply Cases (released in AEO2008)

    Reports and Publications (EIA)

    2008-01-01

    Development of U.S. energy resources and the permitting and construction of large energy facilities have become increasingly difficult over the past 20 years, and they could become even more difficult in the future. Growing public concern about global warming and CO2 emissions also casts doubt on future consumption of fossil fuels -- particularly coal, which releases the largest amount of CO2 per unit of energy produced. Even without regulations to limit greenhouse gas emissions in the United States, the investment community may already be limiting the future use of some energy options. In addition, there is considerable uncertainty about the future availability of, and access to, both domestic and foreign natural gas resources.

  10. Development of the next generation medium-duty natural gas engine

    SciTech Connect (OSTI)

    Podnar, D.J.; Kubesh, J.T.

    2000-02-28

    This report summarizes the work done under this subcontract in the areas of System Design, System Fabrication, and Experimental Program. The report contains the details of the engine development process for achieving throttleless stratified charge spark ignition (SI) engine operation as well as advanced turbocharging strategies. Engine test results showing the potential of the direct-injection stratified charge combustion strategy for increasing part-load engine efficiency on a John Deere 8.1-liter natural gas engine are also included in this report. In addition, steady state and step transient engine data are presented that quantify the performance of a variable geometry turbocharger (VGT) as well as a modified waste-gated turbocharger on the engine. The benefits of the technologies investigated during this project will be realized in the form of increased drive-cycle efficiency to diesel-like levels, while retaining the low emissions characteristics of a lean-burn natural gas engine.

  11. Waste drum gas generation sampling program at Rocky Flats during FY 1989

    SciTech Connect (OSTI)

    Roggenthen, D.K.; Nieweg, R.G.

    1990-10-01

    Rocky Flats Plant transuranic waste drums were sampled for gas composition. Glass, metal, graphite, and solidified inorganic sludge transuranic waste forms were sampled. A vacuum system was used to sample each layer of containment inside a waste drum, including individual waste bags. G values were calculated for the waste drums. G(H{sub 2}) was below 0.6 and G(Total) was below 1.3 for all waste forms discussed in this report. 5 refs., 3 figs., 3 tabs.

  12. Process for generation of hydrogen gas from various feedstocks using thermophilic bacteria

    DOE Patents [OSTI]

    Ooteghem, Suellen Van (Morgantown, WV)

    2005-09-13

    A method for producing hydrogen gas is provided comprising selecting a bacteria from the Order Thermotogales, subjecting the bacteria to a feedstock and to a suitable growth environment having an oxygen concentration below the oxygen concentration of water in equilibrium with air; and maintaining the environment at a predetermined pH and at a temperature of at least approximately 45.degree. C. for a time sufficient to allow the bacteria to metabolize the feedstock.

  13. VUV generation by adiabatically expanded and excited by a DC electrical discharge Argon gas

    SciTech Connect (OSTI)

    Pipergias, K.; Yasemidis, D.; Reppa, E.; Pentaris, D.; Efthimiopoulos, T.; Merlemis, N.; Giannetas, V.

    2010-11-10

    We investigate the emission of Argon (Ar) gas which is adiabatically expanded through a nozzle and excited using a DC electrical discharge. Because of the expansion and the electronic excitation, Ar dimers and clusters are formed, which give radiation in the second (2nd) and in the third (3rd) continua of Ar, centered at about 126 and 254 nm respectively. We particularly focus our study on the 2nd continuum, in order to develop a laser at this wavelength.

  14. Electric Power Generation from Co-Produced Fluids from Oil and Gas Wells

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, AlabamaETEC GmbH Jump to:Providence,NewInformation at Santa Fe, NewSettingGas

  15. Electric Power Generation from Coproduced Fluids from Oil and Gas Wells |

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n cEnergy (AZ,Local Government Nonprofit ResidentialofUlrichDepartment of

  16. Adapting On-Site Electrical Generation Platforms for Producer Gas - Fact

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u t y A s sconveyance(EPACT)SpringDOE during the DOESheet,

  17. Eu{sub 3}F{sub 4}S{sub 2}: Synthesis, crystal structure, and magnetic properties of the mixed-valent europium(II,III) fluoride sulfide EuF{sub 2}.(EuFS){sub 2}

    SciTech Connect (OSTI)

    Grossholz, Hagen; Hartenbach, Ingo [Institut fuer Anorganische Chemie, Universitaet Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart (Germany); Kotzyba, Gunter [Institut fuer Anorganische und Analytische Chemie, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Poettgen, Rainer, E-mail: pottgen@uni-muenster.d [Institut fuer Anorganische und Analytische Chemie, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Trill, Henning; Mosel, Bernd D. [Institut fuer Physikalische Chemie, Westfaelische Wilhelms-Universitaet Muenster, Corrensstrasse 30, 48149 Muenster (Germany); Schleid, Thomas, E-mail: schleid@iac.uni-stuttgart.d [Institut fuer Anorganische Chemie, Universitaet Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart (Germany)

    2009-11-15

    Using the method to synthesize rare-earth metal(III) fluoride sulfides MFS (M=Y, La, Ce-Lu), in some cases we were able to obtain mixed-valent compounds such as Yb{sub 3}F{sub 4}S{sub 2} instead. With Eu{sub 3}F{sub 4}S{sub 2} another isotypic representative has now been synthesized. Eu{sub 3}F{sub 4}S{sub 2} (tetragonal, I4/mmm, a=400.34(2), c=1928.17(9) pm, Z=2) is obtained from the reaction of metallic europium, elemental sulfur, and europium trifluoride in a molar ratio of 5:6:4 within seven days at 850 deg. C in silica-jacketed gas-tightly sealed platinum ampoules. The single-phase product consists of black plate-shaped single crystals with a square cross section, which can be obtained from a flux using equimolar amounts of NaCl as fluxing agent. The crystal structure is best described as an intergrowth structure, in which one layer of CaF{sub 2}-type EuF{sub 2} is followed by two layers of PbFCl-type EuFS when sheeted parallel to the (001) plane. Accordingly there are two chemically and crystallographically different europium cations present. One of them (Eu{sup 2+}) is coordinated by eight fluoride anions in a cubic fashion, the other one (Eu{sup 3+}) exhibits a monocapped square antiprismatic coordination sphere with four F{sup -} and five S{sup 2-} anions. Although the structural ordering of the different charged europium cations is plausible, a certain amount of charge delocalization with some polaron activity has to take place, which is suggested by the black color of the title compound. Temperature dependent magnetic susceptibility measurements of Eu{sub 3}F{sub 4}S{sub 2} show Curie-Weiss behavior with an experimental magnetic moment of 8.19(5) mu{sub B} per formula unit and a paramagnetic Curie temperature of 0.3(2) K. No magnetic ordering is observed down to 4.2 K. In accordance with an ionic formula splitting like (Eu{sup II})(Eu{sup III}){sub 2}F{sub 4}S{sub 2} only one third of the europium centers in Eu{sub 3}F{sub 4}S{sub 2} carry permanent magnetic moments. {sup 151}Eu-Moessbauer spectroscopic experiments at 4.2 K show one signal at an isomer shift of -12.4(1) mm/s and a second one at 0.42(4) mm/s. These signals occur in a ratio of 1:2 and correspond to Eu{sup 2+} and Eu{sup 3+}, respectively. The spectra at 78 and 298 K are similar, thus no change in the Eu{sup 2+}/Eu{sup 3+} fraction can be detected. - Graphical abstract: Crystal structure and {sup 151}Eu-Moessbauer spectra of mixed-valent Eu{sub 3}F{sub 4}S{sub 2}.

  18. Proposal for Qualification of Gas-Generating Radioactive Payloads for Transportation within a Type B Package

    SciTech Connect (OSTI)

    Houghtaling, T.K.

    2002-06-07

    Characterization data describing radioactive materials (RAM) in storage are likely those associated with the processes that produced the materials or with the mission for which they were produced. Along with impurity data, often absent or unknown as a result of post-processing storage environment is moisture content. Radiolysis of moisture may lead to a hydrogen flammability hazard within a closed volume such as a storage can or a transportation package. This paper offers a practical means of qualifying payloads of unknown moisture content for shipment within Type B packaging, while supporting the DOE program to maintain radworker dose as low as reasonable achievable (ALARA). Specifically, the paper discusses part of a qualification program carried out at the Savannah River Site for onsite shipment of legacy RAM within the DDF-1 package. The DDF-1 is an onsite-only prototype of the currently certified 9975 package. Measurement of storage-can lid bulge can provide an upper bound for pressure within a storage can. Subsequent belljar testing can measure the rate of gas leakage from a storage can. These actions are shown sufficient to ensure that the performance of the 9975 containment vessels can accommodate the deflagration energy from flammable gas mixtures within Normal Conditions of Transport, and, and the consequences of a detonation shock wave within Hypothetical Accident Conditions.

  19. Updated greenhouse gas and criteria air pollutant emission factors and their probability distribution functions for electricity generating units

    SciTech Connect (OSTI)

    Cai, H.; Wang, M.; Elgowainy, A.; Han, J.

    2012-07-06

    Greenhouse gas (CO{sub 2}, CH{sub 4} and N{sub 2}O, hereinafter GHG) and criteria air pollutant (CO, NO{sub x}, VOC, PM{sub 10}, PM{sub 2.5} and SO{sub x}, hereinafter CAP) emission factors for various types of power plants burning various fuels with different technologies are important upstream parameters for estimating life-cycle emissions associated with alternative vehicle/fuel systems in the transportation sector, especially electric vehicles. The emission factors are typically expressed in grams of GHG or CAP per kWh of electricity generated by a specific power generation technology. This document describes our approach for updating and expanding GHG and CAP emission factors in the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model developed at Argonne National Laboratory (see Wang 1999 and the GREET website at http://greet.es.anl.gov/main) for various power generation technologies. These GHG and CAP emissions are used to estimate the impact of electricity use by stationary and transportation applications on their fuel-cycle emissions. The electricity generation mixes and the fuel shares attributable to various combustion technologies at the national, regional and state levels are also updated in this document. The energy conversion efficiencies of electric generating units (EGUs) by fuel type and combustion technology are calculated on the basis of the lower heating values of each fuel, to be consistent with the basis used in GREET for transportation fuels. On the basis of the updated GHG and CAP emission factors and energy efficiencies of EGUs, the probability distribution functions (PDFs), which are functions that describe the relative likelihood for the emission factors and energy efficiencies as random variables to take on a given value by the integral of their own probability distributions, are updated using best-fit statistical curves to characterize the uncertainties associated with GHG and CAP emissions in life-cycle modeling with GREET.

  20. Life Cycle Greenhouse Gas Emissions of Nuclear Electricity Generation: Systematic Review and Harmonization

    Broader source: Energy.gov [DOE]

    As clean energy increasingly becomes part of the national dialogue, lenders, utilities, and lawmakers need the most comprehensive and accurate information on GHG emissions from various sources of energy to inform policy, planning, and investment decisions. The National Renewable Energy Laboratory (NREL) recently led the Life Cycle Assessment (LCA) Harmonization Project, a study that gives decision makers and investors more precise estimates of life cycle GHG emissions for renewable and conventional generation, clarifying inconsistent and conflicting estimates in the published literature, and reducing uncertainty.

  1. Life Cycle Greenhouse Gas Emissions of Crystalline Silicon Photovoltaic Electricity Generation: Systematic Review and Harmonization

    Broader source: Energy.gov [DOE]

    As clean energy increasingly becomes part of the national dialogue, lenders, utilities, and lawmakers need the most comprehensive and accurate information on GHG emissions from various sources of energy to inform policy, planning, and investment decisions. The National Renewable Energy Laboratory (NREL) recently led the Life Cycle Assessment (LCA) Harmonization Project, a study that gives decision makers and investors more precise estimates of life cycle GHG emissions for renewable and conventional generation, clarifying inconsistent and conflicting estimates in the published literature, and reducing uncertainty.

  2. Life Cycle Greenhouse Gas Emissions of Thin-film Photovoltaic Electricity Generation: Systematic Review and Harmonization

    Office of Energy Efficiency and Renewable Energy (EERE)

    As clean energy increasingly becomes part of the national dialogue, lenders, utilities, and lawmakers need the most comprehensive and accurate information on GHG emissions from various sources of energy to inform policy, planning, and investment decisions. The National Renewable Energy Laboratory (NREL) recently led the Life Cycle Assessment (LCA) Harmonization Project, a study that gives decision makers and investors more precise estimates of life cycle GHG emissions for renewable and conventional generation, clarifying inconsistent and conflicting estimates in the published literature, and reducing uncertainty.

  3. Life Cycle Greenhouse Gas Emissions of Coal-Fired Electricity Generation: Systematic Review and Harmonization

    Broader source: Energy.gov [DOE]

    As clean energy increasingly becomes part of the national dialogue, lenders, utilities, and lawmakers need the most comprehensive and accurate information on GHG emissions from various sources of energy to inform policy, planning, and investment decisions. The National Renewable Energy Laboratory (NREL) recently led the Life Cycle Assessment (LCA) Harmonization Project, a study that gives decision makers and investors more precise estimates of life cycle GHG emissions for renewable and conventional generation, clarifying inconsistent and conflicting estimates in the published literature, and reducing uncertainty.

  4. State-level Greenhouse Gas Emission Factors for Electricity Generation, Updated

    Reports and Publications (EIA)

    2001-01-01

    To assist reporters in estimating emissions and emission reductions, The Energy Information Administration (EIA) has made available in the instructions to Forms EIA-1605 and EIA-1605EZ emission coefficients for most commonly used fossil fuels and electricity. These coefficients were based on 1992 emissions and generation data. In 1999, updated coefficients were prepared based on the most recent data (1998) then available; however, the updated coefficients were not included in the instructions for the 1999 data year. This year, they have been updated again, but based on three years worth of data (1997, 1998, and 1999) rather than a single year.

  5. Apparatus and methods of reheating gas turbine cooling steam and high pressure steam turbine exhaust in a combined cycle power generating system

    DOE Patents [OSTI]

    Tomlinson, Leroy Omar (Niskayuna, NY); Smith, Raub Warfield (Ballston Lake, NY)

    2002-01-01

    In a combined cycle system having a multi-pressure heat recovery steam generator, a gas turbine and steam turbine, steam for cooling gas turbine components is supplied from the intermediate pressure section of the heat recovery steam generator supplemented by a portion of the steam exhausting from the HP section of the steam turbine, steam from the gas turbine cooling cycle and the exhaust from the HP section of the steam turbine are combined for flow through a reheat section of the HRSG. The reheated steam is supplied to the IP section inlet of the steam turbine. Thus, where gas turbine cooling steam temperature is lower than optimum, a net improvement in performance is achieved by flowing the cooling steam exhausting from the gas turbine and the exhaust steam from the high pressure section of the steam turbine in series through the reheater of the HRSG for applying steam at optimum temperature to the IP section of the steam turbine.

  6. Danish Energy Authority Poland -Electricity and gas

    E-Print Network [OSTI]

    Danish Energy Authority Poland - Electricity and gas market development study and practical guidelines for using EU Funds Electricity sector analyses December 2004 #12;Danish Energy Authority Poland - Electricity and gas market development study and practical guidelines for using EU Funds Electricity sector

  7. Internet: http://ue.eu.int E-mail: press.office@consilium.eu.int

    E-Print Network [OSTI]

    Internet: http://ue.eu.int E-mail: press.office@consilium.eu.int For further information call 32 2 references are given in the text are available on the Council's Internet site http://ue.eu.int. Acts adopted; these statements are available on the above mentioned Council Internet site or may be obtained from the Press

  8. Published on Africa EU (http://www.africa-eu-partnership.org) Home > News > Cameroon axes illegal logging > Printer-friendly

    E-Print Network [OSTI]

    Published on Africa EU (http://www.africa-eu-partnership.org) Home > News > Cameroon axes illegal on the EU side. 9/13/2010 Cameroon axes illegal logging www.africa-eu-partnership.org/print/122 1/2 #12;The goes a long way in supporting the Africa-EU Partnership on Trade, Regional Integration

  9. Thermal and combined thermal and radiolytic reactions involving nitrous oxide, hydrogen, and nitrogen in the gas phase; comparison of gas generation rates in supernate and solid fractions of Tank 241-SY-101 simulated waste

    SciTech Connect (OSTI)

    Bryan, S.A.; Pederson, L.R.

    1995-03-01

    This report summarizes progress made in evaluating me by which flammable gases are generated in Hanford double-shell tank wastes, based on the results of laboratory tests using simulated waste mixtures. Work described in this report. was conducted at Pacific Northwest Laboratory (PNL) for the Flammable Gas Safety Project, the purpose of which is to develop information needed to support Westinghouse Hanford Company (WHC) in their efforts to ensure the safe interim storage of wastes at the Hanford Site. This work is related to gas generation studies being performed at Georgia Institute of Technology (GIT), under subcontract to PNL, using simulated wastes, and to studies being performed at VMC using actual wastes.

  10. The effect of the operation modes of a gas discharge low-pressure amalgam lamp on the intensity of generation of 185 nm UV vacuum radiation

    SciTech Connect (OSTI)

    Vasilyak, L. M., E-mail: vasilyak@ihed.ras.ru [Russian Academy of Sciences, Joint Institute of High Temperatures (Russian Federation); Drozdov, L. A., E-mail: lit@npo.lit.ru; Kostyuchenko, S. V.; Sokolov, D. V. [ZAO LIT (Russian Federation); Kudryavtsev, N. N.; Sobur, D. A., E-mail: soburda@gmail.com [Moscow Institute for Physics and Technology (Russian Federation)

    2011-12-15

    The effect of the discharge current, mercury vapor pressure, and the inert gas pressure on the intensity and efficiency of the 185 nm line generation are considered. The spectra of the UV radiation (vacuum ultraviolet) transmission by protective coatings from the oxides of rare earth metals and aluminum are investigated.

  11. Appendix A MIT Joint Program Report 193 1 Appendix A: Sectoral Trading between the EU-ETS and Emerging Countries1

    E-Print Network [OSTI]

    investment in low carbon technologies in developing countries. In the main report (MIT Joint Program Report sectors in some developing countries. Our analysis seeks to quantify the effects of sectoral trading electricity generation induced by the EU-ETS persist. Sectoral trading between the EU and the four countries

  12. Study on multiphase flow and mixing in semidry flue gas desulfurization with a multifluid alkaline spray generator using particle image velocimetry

    SciTech Connect (OSTI)

    Zhou, Y.G.; Wang, D.F.; Zhang, M.C. [Shanghai Jiao Tong University, Shanghai (China)

    2009-06-15

    Particle image velocimetry (PIV) technique was used to measure the velocity fields of gas-droplet-solid multiphase flow in the experimental setup of a novel semidry flue gas desulfurization process with a multifluid alkaline spray generator. The flow structure, mixing characteristic, and interphase interaction of gas-droplet-solid multiphase flow were investigated both in the confined alkaline spray generator and in the duct bent pipe section. The results show that sorbent particles in the confined alkaline spray generator are entrained into the spray core zone by a high-speed spray jet and most of the sorbent particles can be effectively humidified by spray water fine droplets to form aqueous lime slurry droplets. Moreover, a minimum amount of air stream in the generator is necessary to achieve higher collision humidification efficiency between sorbent particles and spray water droplets and to prevent the possible deposition of fine droplets on the wall. The appropriate penetration length of the slurry droplets from the generator can make uniform mixing between the formed slurry droplets and main air stream in the duct bent pipe section, which is beneficial to improving sulfur dioxide removal efficiency and to preventing the deposition of droplets on the wall.

  13. EuCARD final project report

    E-Print Network [OSTI]

    Koutchouk, J P

    2014-01-01

    After four years of activity, EuCARD has most of its objectives fulfilled, with some new objectives added and a few others on excellent tracks while requiring additional time. The management has been active in reinforcing the collaborative links between partners and projects, contributing to the preparation of FP7-EuCARD2, initiating FP7-HiLumi-LHC Design Study, to favour sustained collaborations beyond EuCARD. An out-of-contract network has been successfully launched on laser plasma acceleration, to combine forces between accelerator, laser and plasma communities. Communication and dissemination activities have led to two highlights: Accelerating News, an accelerator R&D newsletter initiated by EuCARD and now common to all FP7 accelerator projects (over 1000 subscribers) and a series of monographs on accelerator sciences that is progressively finding its public. The scientific networks have more than fulfilled their initial objectives: roadmaps are defined for neutrino facilities, submitted to the Europe...

  14. Agricultural Biotechnology in California and the EU

    E-Print Network [OSTI]

    Hochman, Gal; Rausser, Gordon; Sexton, Steve; Zilberman, David

    2008-01-01

    genetically-modified organisms (GMO) is a prime example ofof food products containing GMO and has also restricted usea de facto moratorium on GMO approvals while the EU was

  15. Discovery of the $^{151}$Eu $\\alpha$ decay

    E-Print Network [OSTI]

    Casali, N; Orio, F; Pattavina, L; Beeman, J W; Bellini, F; Cardani, L; Dafinei, I; Di Domizio, S; Di Vacri, M L; Gironi, L; Kosmyna, M B; Nazarenko, B P; Nisi, S; Pessina, G; Piperno, G; Pirro, S; Rusconi, C; Shekhovtsov, A N; Tomei, C; Vignati, M

    2013-01-01

    We report on the observation of the $^{151}$Eu $\\alpha$ decay to the ground state of $^{147}$Pm. We measured a half-life of T_{1/2}=(4.62$\\pm$0.95(stat.)$\\pm$0.68(syst.))$\\times 10^{18}$ y and a Q-value of 1948.9$\\pm$6.9 keV, using a 6.15 g Li$_6$Eu(BO$_3$)$_3$ crystal operated as scintillating bolometer.

  16. Internet: http://ue.eu.int/ E-mail: press.office@consilium.eu.int

    E-Print Network [OSTI]

    Internet: http://ue.eu.int/ E-mail: press.office@consilium.eu.int For further information call 32 2 marks. The documents whose references are given in the text are available on the Council's Internet Internet site or may be obtained from the Press Office. #12;PROVISIONAL VERSION 11.III.2004 6648/04 (Presse

  17. Internet: http://ue.eu.int/ E-mail: press.office@consilium.eu.int

    E-Print Network [OSTI]

    Internet: http://ue.eu.int/ E-mail: press.office@consilium.eu.int For further information call 32 2. The documents whose references are given in the text are available on the Council's Internet site http by an asterisk; these statements are available on the above mentioned Council Internet site or may be #12;22.IX

  18. Internet: http://ue.eu.int/ E-mail: press.office@consilium.eu.int

    E-Print Network [OSTI]

    Internet: http://ue.eu.int/ E-mail: press.office@consilium.eu.int For further information call 32 2. A The documents whose references are given in the text are available on the Council's Internet site http by an asterisk; these statements are available on the above mentioned Council Internet site or may be obtained

  19. Social Actors in the Implementation of EU Agri-Environmental Policy

    E-Print Network [OSTI]

    Moyano, Eduardo

    2005-01-01

    of EU Agri- Environmental Policy Eduardo Moyano Institute ofof EU Agri- Environmental Policy Eduardo Moyano and Fernandoof EU Agri-Environmental Policy”. Unfortunately, neither

  20. Hetero-epitaxial EuO interfaces studied by analytic electron microscopy

    SciTech Connect (OSTI)

    Mundy, Julia A.; Hodash, Daniel; Melville, Alexander; Held, Rainer; Mairoser, Thomas; Schmehl, Andreas; Muller, David A.; Kourkoutis, Lena F.; Schlom, Darrell G.

    2014-03-03

    With nearly complete spin polarization, the ferromagnetic semiconductor europium monoxide could enable next-generation spintronic devices by providing efficient ohmic spin injection into silicon. Spin injection is greatly affected by the quality of the interface between the injector and silicon. Here, we use atomic-resolution scanning transmission electron microscopy in conjunction with electron energy loss spectroscopy to directly image and chemically characterize a series of EuO|Si and EuO|YAlO{sub 3} interfaces fabricated using different growth conditions. We identify the presence of europium silicides and regions of disorder at the EuO|Si interfaces, imperfections that could significantly reduce spin injection efficiencies via spin-flip scattering.

  1. Dissolved gas supersaturation associated with the thermal effluent of an electric generating station and some effects on fishes 

    E-Print Network [OSTI]

    Ciesluk, Alexander Frank

    1974-01-01

    canal and discharge pond, Big Brown Steam Electric Station, 7-8 December 1973, plant AT = 10. 9-11. 1 C, and 19-20 January 1974, plant AT = 10. 4-11. 0 C 51 13 Diel pattern of percent saturation of dissolved oxygen, nitrogen, and total gas.... 77 LIST OF FIGURES (Continued) FIGURE PAGE 18 Gas bubbles and extensive hemorrhaging in the gili of a bluegill sunfish afflicted with gas-bubble disease . . . . . . . . . . . . . . 77 l9 The solubility of oxygen and nitrogen in water at various...

  2. Integrated pressure-dependence in automated mechanism generation : a new tool for building gas-phase kinetic models

    E-Print Network [OSTI]

    Matheu, David M. (David Michael), 1974-

    2003-01-01

    A host of vital, current, and developing technologies, such as pyrolysis, thermal cracking, partial oxidation, and high-efficiency combustion engines, involve complex, gas-phase chemical mechanisms with hundreds of species ...

  3. Edinburgh Research Explorer The Structure of Eu-III

    E-Print Network [OSTI]

    Millar, Andrew J.

    ]. Very recently, Eu has been found to be superconducting at a pressure of approximately 80 GPa, with Tc

  4. Utilizing the heat content of gas-to-liquids by-product streams for commercial power generation 

    E-Print Network [OSTI]

    Adegoke, Adesola Ayodeji

    2006-10-30

    provides middle distillates to an unsaturated global market and offers opportunities to generate power for commercial purposes from waste by-product streams, which normally are associated with increased expenses incurred from additional...

  5. Industrial co-generation through use of a medium BTU gas from biomass produced in a high throughput reactor

    SciTech Connect (OSTI)

    Feldmann, H.F.; Ball, D.A.; Paisley, M.A.

    1983-01-01

    A high-throughput gasification system has been developed for the steam gasification of woody biomass to produce a fuel gas with a heating value of 475 to 500 Btu/SCF without using oxygen. Recent developments have focused on the use of bark and sawdust as feedstocks in addition to wood chips and the testing of a new reactor concept, the so-called controlled turbulent zone (CTZ) reactor to increase gas production per unit of wood fed. Operating data from the original gasification system and the CTZ system are used to examine the preliminary economics of biomass gasification/gas turbine cogeneration systems. In addition, a ''generic'' pressurized oxygen-blown gasification system is evaluated. The economics of these gasification systems are compared with a conventional wood boiler/steam turbine cogeneration system.

  6. Research Summary The EU Emissions Trading System: Opportunities for Forests?

    E-Print Network [OSTI]

    Research Summary The EU Emissions Trading System: Opportunities for Forests? European forestry has sequestration provided by European forests has not been recognised by markets. The EU Emissions Trading System as part of a wider review covering emerging carbon markets. Background The EU Emissions Trading Scheme

  7. Proposal for the Award of a Contract for the Supply and Installation of a gas Turbine for Combined Generation of Electricity and Heat in the Heating Plant on the Meyrin Site

    E-Print Network [OSTI]

    1994-01-01

    Proposal for the Award of a Contract for the Supply and Installation of a gas Turbine for Combined Generation of Electricity and Heat in the Heating Plant on the Meyrin Site

  8. Hydordesulfurization of dibenzothiophene using hydrogen generated in situ by the water-gas shift reaction in a trickle bed reactor 

    E-Print Network [OSTI]

    Hook, Bruce David

    1984-01-01

    in situ by the Water ? Gas Shift Reaction in a Trickle Bed Reactor (December 1984) Bruce David Hook, B. S. , Texas AgtM University Chairman of Advisory Committee: Dr. Aydin Akgerman Global depletion of sweet crude oil has required greater use of high.... Hook et al. (1984) have presented a technique for extracting intrinsic kinetics from trickle bed reactors operating at high temperatures and pressures. The Hook et al. technique uses the Soave-Redlich- Kwong equation of state to predict...

  9. Mechanism and computational model for Lyman-{alpha}-radiation generation by high-intensity-laser four-wave mixing in Kr-Ar gas

    SciTech Connect (OSTI)

    Louchev, Oleg A.; Saito, Norihito; Wada, Satoshi; Bakule, Pavel; Yokoyama, Koji; Ishida, Katsuhiko; Iwasaki, Masahiko

    2011-09-15

    We present a theoretical model combined with a computational study of a laser four-wave mixing process under optical discharge in which the non-steady-state four-wave amplitude equations are integrated with the kinetic equations of initial optical discharge and electron avalanche ionization in Kr-Ar gas. The model is validated by earlier experimental data showing strong inhibition of the generation of pulsed, tunable Lyman-{alpha} (Ly-{alpha}) radiation when using sum-difference frequency mixing of 212.6 nm and tunable infrared radiation (820-850 nm). The rigorous computational approach to the problem reveals the possibility and mechanism of strong auto-oscillations in sum-difference resonant Ly-{alpha} generation due to the combined effect of (i) 212.6-nm (2+1)-photon ionization producing initial electrons, followed by (ii) the electron avalanche dominated by 843-nm radiation, and (iii) the final breakdown of the phase matching condition. The model shows that the final efficiency of Ly-{alpha} radiation generation can achieve a value of {approx}5x10{sup -4} which is restricted by the total combined absorption of the fundamental and generated radiation.

  10. Induced spin-polarization of EuS at room temperature in Ni/EuS multilayers

    SciTech Connect (OSTI)

    Poulopoulos, P.; Goschew, A.; Straub, A.; Fumagalli, P.; Kapaklis, V.; Wolff, M.; Delimitis, A.; Wilhelm, F.; Rogalev, A.; Pappas, S. D.

    2014-03-17

    Ni/EuS multilayers with excellent multilayer sequencing are deposited via e-beam evaporation on the native oxide of Si(100) wafers at 4?×?10{sup ?9} millibars. The samples have very small surface and interface roughness and show sharp interfaces. Ni layers are nanocrystalline 4–8?nm thick and EuS layers are 2–4?nm thick and are either amorphous or nanocrystalline. Unlike for Co/EuS multilayers, all Eu ions are in divalent (ferromagnetic) state. We show a direct antiferromagnetic coupling between EuS and Ni layers. At room temperature, the EuS layers are spin-polarized due to the proximity of Ni. Therefore, Ni/EuS is a candidate for room-temperature spintronics applications.

  11. Measurement and analysis of the muonic x rays of /sup 151/Eu and /sup 153/Eu

    SciTech Connect (OSTI)

    Tanaka, Y.; Steffen, R.M.; Shera, E.B.; Reuter, W.; Hoehn, M.V.; Zumbro, J.D.

    1984-05-01

    Monopole and quadrupole charge distributions of /sup 151/Eu and /sup 153/Eu were investigated by muonic atom K and L x-ray measurements. The model-independent Barrett charge radii R/sub k/ and the isotope shift ..delta..R/sub k/ were measured, and the value of ..delta.. = 0.606(18) fm/sup 2/ was deduced. This isotope shift is the largest known of all nuclear pairs. The isomer shift of the first excited state of /sup 153/Eu is found to be close to zero, in contrast to the large isomer shifts observed in its neighbors: /sup 152/Sm and /sup 154/Gd. The quadrupole moments of the first excited states were determined as Q/sup 151/((7/2)/sup +/) = 1.28(2) e b and Q/sup 153/((7/2)/sup +/) = 0.44(2) e b. The value for /sup 151/Eu and its ground-state quadrupole moment of Q/sup 151/((5/2)/sup +/) = 0.90(1) e b reported previously are several times larger than the respective single particle units. This fact shows that a fair amount of collectivity is involved in the (5/2)/sup +/ ground state and in the (7/2)/sup +/ first excited state of /sup 151/Eu.

  12. Chena Hot Springs Resort - Electric Power Generation Using Geothermal Fluid Coproduced from Oil and/or Gas Wells

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a lCaribElectricSouthApplying2-2002 July 2002 DOEchemicals industry

  13. Cluster generator

    DOE Patents [OSTI]

    Donchev, Todor I. (Urbana, IL); Petrov, Ivan G. (Champaign, IL)

    2011-05-31

    Described herein is an apparatus and a method for producing atom clusters based on a gas discharge within a hollow cathode. The hollow cathode includes one or more walls. The one or more walls define a sputtering chamber within the hollow cathode and include a material to be sputtered. A hollow anode is positioned at an end of the sputtering chamber, and atom clusters are formed when a gas discharge is generated between the hollow anode and the hollow cathode.

  14. Life Cycle Greenhouse Gas Emissions of Trough and Tower Concentrating Solar Power Electricity Generation: Systematic Review and Harmonization

    Broader source: Energy.gov [DOE]

    As clean energy increasingly becomes part of the national dialogue, lenders, utilities, and lawmakers need the most comprehensive and accurate information on GHG emissions from various sources of energy to inform policy, planning, and investment decisions. The National Renewable Energy Laboratory (NREL) recently led the Life Cycle Assessment (LCA) Harmonization Project, a study that gives decision makers and investors more precise estimates of life cycle GHG emissions for renewable and conventional generation, clarifying inconsistent and conflicting estimates in the published literature, and reducing uncertainty.

  15. Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high temperature furnace (HITAF). Volume 1, Final report

    SciTech Connect (OSTI)

    NONE

    1996-02-01

    A major objective of the coal-fired high performance power systems (HIPPS) program is to achieve significant increases in the thermodynamic efficiency of coal use for electric power generation. Through increased efficiency, all airborne emissions can be decreased, including emissions of carbon dioxide. High Performance power systems as defined for this program are coal-fired, high efficiency systems where the combustion products from coal do not contact the gas turbine. Typically, this type of a system will involve some indirect heating of gas turbine inlet air and then topping combustion with a cleaner fuel. The topping combustion fuel can be natural gas or another relatively clean fuel. Fuel gas derived from coal is an acceptable fuel for the topping combustion. The ultimate goal for HIPPS is to, have a system that has 95 percent of its heat input from coal. Interim systems that have at least 65 percent heat input from coal are acceptable, but these systems are required to have a clear development path to a system that is 95 percent coal-fired. A three phase program has been planned for the development of HIPPS. Phase 1, reported herein, includes the development of a conceptual design for a commercial plant. Technical and economic feasibility have been analysed for this plant. Preliminary R&D on some aspects of the system were also done in Phase 1, and a Research, Development and Test plan was developed for Phase 2. Work in Phase 2 include s the testing and analysis that is required to develop the technology base for a prototype plant. This work includes pilot plant testing at a scale of around 50 MMBtu/hr heat input. The culmination of the Phase 2 effort will be a site-specific design and test plan for a prototype plant. Phase 3 is the construction and testing of this plant.

  16. Evidence of Eu{sup 2+} 4f electrons in the valence band spectra of EuTiO{sub 3} and EuZrO{sub 3}

    SciTech Connect (OSTI)

    Kolodiazhnyi, T.; Valant, M.; Williams, J. R.; Bugnet, M.; Botton, G. A.; Ohashi, N.; Sakka, Y.

    2012-10-15

    We report on optical band gap and valence electronic structure of two Eu{sup 2+}-based perovskites, EuTiO{sub 3} and EuZrO{sub 3} as revealed by diffuse optical scattering, electron energy loss spectroscopy, and valence-band x-ray photoelectron spectroscopy. The data show good agreement with the first-principles studies in which the top of the valence band structure is formed by the narrow Eu 4f{sup 7} electron band. The O 2p band shows the features similar to those of the Ba(Sr)TiO{sub 3} perovskites except that it is shifted to higher binding energies. Appearance of the Eu{sup 2+} 4f{sup 7} band is a reason for narrowing of the optical band gap in the title compounds as compared to their Sr-based analogues.

  17. Distributed Generation with Heat Recovery and Storage

    E-Print Network [OSTI]

    Siddiqui, Afzal S.; Marnay, Chris; Firestone, Ryan M.; Zhou, Nan

    2008-01-01

    Weekday Total Electricity Generation (Storage AdoptionWeekday Total Electricity Generation (Storage Adoptionrecovery and storage) utility electricity and natural gas

  18. Distributed Generation Investment by a Microgrid under Uncertainty

    E-Print Network [OSTI]

    Siddiqui, Afzal

    2008-01-01

    the long-term natural gas generation cost is stochastic, wethe consideration of generation cost threshold that triggersthat of natural gas generation cost delays investment while

  19. Optical properties of Eu{sup 2+}/Eu{sup 3+} mixed valence, silicon nitride based materials

    SciTech Connect (OSTI)

    Kate, Otmar M. ten, E-mail: o.m.tenkate@tudelft.nl [Chemical Engineering and Chemistry, Eindhoven University of Technology, Den Dolech 2, 5600 MB Eindhoven (Netherlands); Fundamental Aspects of Materials and Energy, Delft University of Technology, Mekelweg 15, 2629 JB Delft (Netherlands); Vranken, Thomas [Chemical Engineering and Chemistry, Eindhoven University of Technology, Den Dolech 2, 5600 MB Eindhoven (Netherlands); Kolk, Erik van der [Fundamental Aspects of Materials and Energy, Delft University of Technology, Mekelweg 15, 2629 JB Delft (Netherlands); Jansen, Antonius P.J.; Hintzen, Hubertus T. [Chemical Engineering and Chemistry, Eindhoven University of Technology, Den Dolech 2, 5600 MB Eindhoven (Netherlands)

    2014-05-01

    Eu{sub 2}SiN{sub 3}, a mixed valence europium nitridosilicate, has been prepared via solid-state reaction synthesis and its oxidation behavior and optical properties have been determined. Furthermore, the stability of several isostructural compounds of the type M{sup 2+}L{sup 3+}SiN{sub 3} has been predicted by using the density functional theory calculations, and verified by the actual synthesis of CaLaSiN{sub 3}, CaEuSiN{sub 3} and EuLaSiN{sub 3}. The band gap of CaLaSiN{sub 3} was found around 3.2 eV giving the material its yellow color. Eu{sub 2}SiN{sub 3} on the other hand is black due to a combination of the 4f–5d absorption band of Eu{sup 2+} and the charge transfer band of Eu{sup 3+}. Thermogravimetric analysis and Raman spectroscopic study of Eu{sub 2}SiN{sub 3} revealed that oxidation of this compound in dry air takes place via a nitrogen retention complex. - Graphical abstract: Energy level scheme of Eu{sub 2}SiN{sub 3} showing the occupied N{sup 3?} 2p band (blue rectangle), unoccupied Eu{sup 2+} 5d band (white rectangle), occupied Eu{sup 2+} 4f ground states (filled red circles) and unoccupied Eu{sup 2+} ground states (open red circles). - Highlights: • Density functional theory calculations on the stability of M{sup 2+}L{sup 3+}SiN{sub 3} compounds. • Solid-state reaction synthesis of Eu{sub 2}SiN{sub 3}, CaLaSiN{sub 3}, EuLaSiN{sub 3} and CaEuSiN{sub 3}. • Determination of the Eu{sup 2+} 4f–5d and Eu{sup 3+} CT transitions in M{sup 2+}L{sup 3+}SiN{sub 3} compounds. • Oxidation of Eu{sub 2}SiN{sub 3} in dry air takes place via a nitrogen retention complex.

  20. The magnetic structure of EuCu2Sb2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ryan, D. H.; Cadogan, J. M.; Anand, V. K.; Johnston, D. C.; Flacau, R.

    2015-05-06

    Antiferromagnetic ordering of EuCu2Sb2 which forms in the tetragonal CaBe2Ge2-type structure (space group P4/nmm #129) has been studied using neutron powder diffraction and 151Eu Mössbauer spectroscopy. The room temperature 151Eu isomer shift of –12.8(1) mm/s shows the Eu to be divalent, while the 151Eu hyperfine magnetic field (Bhf) reaches 28.7(2) T at 2.1 K, indicating a full Eu2+ magnetic moment. Bhf(T) follows a smooth $S=\\frac{7}{2}$ Brillouin function and yields an ordering temperature of 5.1(1) K. Refinement of the neutron diffraction data reveals a collinear A-type antiferromagnetic arrangement with the Eu moments perpendicular to the tetragonal c-axis. As a result, themore »refined Eu magnetic moment at 0.4 K is 7.08(15) ?B which is the full free-ion moment expected for the Eu2+ ion with $S=\\frac{7}{2}$ and a spectroscopic splitting factor of g = 2.« less

  1. CHO Invest EU1 | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLC JumpBiossenceBrunswick, Maine:IAEAT JumpCEECHO Invest EU1 Jump to:

  2. The EU Approach for Responsible and Safe Management of Spent Fuel and Radioactive Waste - 12118

    SciTech Connect (OSTI)

    Blohm-Hieber, Ute; Necheva, Christina [European Commission, Directorate-General for Energy, Luxembourg L-2920 (Luxembourg)

    2012-07-01

    In July 2011 legislation on responsible and safe management of spent fuel and radioactive waste was adopted in the European Union (EU). It aims at ensuring a high level of safety, avoiding undue burdens on future generations and enhancing transparency. EU Member States are responsible for the management of their spent fuel and/or radioactive waste. Each Member State remains free to define its fuel cycle policy. The spent fuel can be regarded either as a valuable resource that may be reprocessed or as radioactive waste that is destined for direct disposal. Whatever option is chosen, the disposal of high level waste, separated at reprocessing, or of spent fuel regarded as waste should be considered. The storage of radioactive waste, including long-term storage, is an interim solution, but not an alternative to disposal. To this end, each Member State has to establish, maintain and implement national policy, framework and programme for management of spent fuel and/or radioactive waste in the long term. Member States will invite international peer reviews to ensure that high safety standards are achieved. The EU approach is anchored in internationally endorsed principles and requirements of the IAEA safety standards and the Joint Convention and in this context makes them legally binding and enforceable in the EU. The EU approach of regulating the management of spent fuel and radioactive waste is anchored in the competence of the national regulatory authorities and in the internationally endorsed principles and requirements of the IAEA Safety Standards and the Joint Convention. Member States have to report to the Commission on the implementation of Directive 2011/70/Euratom for the first time by 23 August 2015, and every 3 years thereafter, taking advantage of the review and reporting under the Joint Convention. On the basis of the Member States' reports, the Commission will submit to the European Parliament and the Council a report on progress made and an inventory of radioactive waste and spent fuel present in the EU territory and the future prospects. Directive 2011/70/Euratom is a logical next step after the Council Directive 2009/71/Euratom on the nuclear safety of nuclear installations. The EU is the first major regional actor providing a binding legal framework on nuclear safety and on responsible and safe management of spent fuel and radioactive waste, and thus is a real model to progress spent fuel and waste management in a safe and responsible manner. (authors)

  3. A New Combustion Synthesis Method for GaN:Eu3+ and Ga2O3 :Eu3+

    E-Print Network [OSTI]

    McKittrick, Joanna

    A New Combustion Synthesis Method for GaN:Eu3+ and Ga2O3 :Eu3+ Luminescent Powders G. A. Hirata1 between the precursors. The preparation of Eu-doped Ga2O3 powders was achieved using a new combustion)3 and Ga(NO3)3 as the precursors and hydrazine as (non-carbonaceous) fuel. A spontaneous combustion

  4. Capital investment requirements for greenhouse gas emissions mitigation in power generation on near term to century time scales and global to regional spatial scales

    SciTech Connect (OSTI)

    Chaturvedi, Vaibhav; Clarke, Leon E.; Edmonds, James A.; Calvin, Katherine V.; Kyle, G. Page

    2014-11-01

    Electrification plays a crucial role in cost-effective greenhouse gas emissions mitigation strategies. Such strategies in turn carry implications for financial capital markets. This paper explores the implication of climate mitigation policy for capital investment demands by the electric power sector on decade to century time scales. We go further to explore the implications of technology performance and the stringency of climate policy for capital investment demands by the power sector. Finally, we discuss the regional distribution of investment demands. We find that stabilizing GHG emissions will require additional investment in the electricity generation sector over and above investments that would be need in the absence of climate policy, in the range of 16 to 29 Trillion US$ (60-110%) depending on the stringency of climate policy during the period 2015 to 2095 under default technology assumptions. This increase reflects the higher capital intensity of power systems that control emissions. Limits on the penetration of nuclear and carbon capture and storage technology could increase costs substantially. Energy efficiency improvements can reduce the investment requirement by 8 to21 Trillion US$ (default technology assumptions), depending on climate policy scenario with higher savings being obtained under the most stringent climate policy. The heaviest investments in power generation were observed in the China, India, SE Asia and Africa regions with the latter three regions dominating in the second half of the 21st century.

  5. Social Actors in the Implementation of EU Agri-Environmental Policy

    E-Print Network [OSTI]

    Moyano, Eduardo

    2005-01-01

    Policy ? EU Agri-Environmental Policy and CAP Reforms ? Keybetween the EU agri-environmental policy and the CAP reformsof the EU agri-environmental policies and their specific

  6. Pennsylvania's Natural Gas Future

    E-Print Network [OSTI]

    Lee, Dongwon

    1 Pennsylvania's Natural Gas Future Penn State Natural Gas Utilization Workshop Bradley Hall sales to commercial and industrial customers ­ Natural gas, power, oil · Power generation ­ FossilMMBtuEquivalent Wellhead Gas Price, $/MMBtu Monthly US Spot Oil Price, $/MMBtu* U.S. Crude Oil vs. Natural Gas Prices, 2005

  7. Limited Sectoral Trading between the EU ETS and China

    E-Print Network [OSTI]

    Limited Sectoral Trading between the EU ETS and China Claire Gavard, Niven Winchester and Sergey established research centers at MIT: the Center for Global Change Science (CGCS) and the Center for Energy://globalchange.mit.edu/ Printed on recycled paper #12;1 Limited Sectoral Trading between the EU ETS and China Claire Gavard

  8. EU Guide v 2d January 20141 Finance Division

    E-Print Network [OSTI]

    de Gispert, Adrià

    EU Guide v 2d January 20141 Finance Division Procurement Services The EU Directives on Public purchasing practice and especially where funders require it as part of their grant conditions. In exceptional Andrew Reid (goods and services) or the Director of Estate Management and Building Services (property

  9. www.meteoalarm.eu Immediate warnings of dangerous and

    E-Print Network [OSTI]

    Haak, Hein

    1 www.meteoalarm.eu Immediate warnings of dangerous and extreme weather across all of Europe.meteoalarm.eu Immediate warnings of dangerous and extreme weather across all of Europe on Internet. A cooperative Rain 8 Danger from river flooding 8 Thunderstorms 10 Lightning tips 11 Snow and ice 12 Mist and fog 13

  10. www.meteoalarm.eu Immediate warnings of dangerous and

    E-Print Network [OSTI]

    Stoffelen, Ad

    1 www.meteoalarm.eu Immediate warnings of dangerous and extreme weather across all of Europe dangers 16 Forest and bush fires 17 Avalanches 18 #12;33 www.meteoalarm.eu The weather knows no boundaries dangerous, both nationally and on a local scale of over 650 regions. Not only are gales, torrential rain

  11. Mitigation of Hydrogen Gas Generation from the Reaction of Uranium Metal with Water in K Basin Sludge and Sludge Waste Forms

    SciTech Connect (OSTI)

    Sinkov, Sergey I.; Delegard, Calvin H.; Schmidt, Andrew J.

    2011-06-08

    Prior laboratory testing identified sodium nitrate and nitrite to be the most promising agents to minimize hydrogen generation from uranium metal aqueous corrosion in Hanford Site K Basin sludge. Of the two, nitrate was determined to be better because of higher chemical capacity, lower toxicity, more reliable efficacy, and fewer side reactions than nitrite. The present lab tests were run to determine if nitrate’s beneficial effects to lower H2 generation in simulated and genuine sludge continued for simulated sludge mixed with agents to immobilize water to help meet the Waste Isolation Pilot Plant (WIPP) waste acceptance drainable liquid criterion. Tests were run at ~60°C, 80°C, and 95°C using near spherical high-purity uranium metal beads and simulated sludge to emulate uranium-rich KW containerized sludge currently residing in engineered containers KW-210 and KW-220. Immobilization agents tested were Portland cement (PC), a commercial blend of PC with sepiolite clay (Aquaset II H), granulated sepiolite clay (Aquaset II G), and sepiolite clay powder (Aquaset II). In all cases except tests with Aquaset II G, the simulated sludge was mixed intimately with the immobilization agent before testing commenced. For the granulated Aquaset II G clay was added to the top of the settled sludge/solution mixture according to manufacturer application directions. The gas volumes and compositions, uranium metal corrosion mass losses, and nitrite, ammonia, and hydroxide concentrations in the interstitial solutions were measured. Uranium metal corrosion rates were compared with rates forecast from the known uranium metal anoxic water corrosion rate law. The ratios of the forecast to the observed rates were calculated to find the corrosion rate attenuation factors. Hydrogen quantities also were measured and compared with quantities expected based on non-attenuated H2 generation at the full forecast anoxic corrosion rate to arrive at H2 attenuation factors. The uranium metal corrosion rates in water alone and in simulated sludge were near or slightly below the metal-in-water rate while nitrate-free sludge/Aquaset II decreased rates by about a factor of 3. Addition of 1 M nitrate to simulated sludge decreased the corrosion rate by a factor of ~5 while 1 M nitrate in sludge/Aquaset II mixtures decreased the corrosion rate by ~2.5 compared with the nitrate-free analogues. Mixtures of simulated sludge with Aquaset II treated with 1 M nitrate had uranium corrosion rates about a factor of 8 to 10 lower than the water-only rate law. Nitrate was found to provide substantial hydrogen mitigation for immobilized simulant sludge waste forms containing Aquaset II or Aquaset II G clay. Hydrogen attenuation factors of 1000 or greater were determined at 60°C for sludge-clay mixtures at 1 M nitrate. Hydrogen mitigation for tests with PC and Aquaset II H (which contains PC) were inconclusive because of suspected failure to overcome induction times and fully enter into anoxic corrosion. Lessening of hydrogen attenuation at ~80°C and ~95°C for simulated sludge and Aquaset II was observed with attenuation factors around 100 to 200 at 1 M nitrate. Valuable additional information has been obtained on the ability of nitrate to attenuate hydrogen gas generation from solution, simulant K Basin sludge, and simulant sludge with immobilization agents. Details on characteristics of the associated reactions were also obtained. The present testing confirms prior work which indicates that nitrate is an effective agent to attenuate hydrogen from uranium metal corrosion in water and simulated K Basin sludge to show that it is also effective in potential candidate solidified K Basin waste forms for WIPP disposal. The hydrogen mitigation afforded by nitrate appears to be sufficient to meet the hydrogen generation limits for shipping various sludge waste streams based on uranium metal concentrations and assumed waste form loadings.

  12. Antiferromagnetism in EuCu2As2 and EuCu1.82Sb2 single crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Anand, V. K.; Johnston, D. C.

    2015-05-07

    Single crystals of EuCu2As2 and EuCu2Sb2 were grown from CuAs and CuSb self-flux, respectively. The crystallographic, magnetic, thermal, and electronic transport properties of the single crystals were investigated by room-temperature x-ray diffraction (XRD), magnetic susceptibility ? versus temperature T, isothermal magnetization M versus magnetic field H, specific heat Cp(T), and electrical resistivity ?(T) measurements. EuCu2As2 crystallizes in the body-centered tetragonal ThCr2Si2-type structure (space group I4/mmm), whereas EuCu2Sb2 crystallizes in the related primitive tetragonal CaBe2Ge2-type structure (space group P4/nmm). The energy-dispersive x-ray spectroscopy and XRD data for the EuCu2Sb2 crystals showed the presence of vacancies on the Cu sites, yielding themore »actual composition EuCu1.82Sb2. The ?(T) and Cp(T) data reveal metallic character for both EuCu2As2 and EuCu1.82Sb2. Antiferromagnetic (AFM) ordering is indicated from the ?(T),Cp(T), and ?(T) data for both EuCu2As2 (TN = 17.5 K) and EuCu1.82Sb2 (TN = 5.1 K). In EuCu1.82Sb2, the ordered-state ?(T) and M(H) data suggest either a collinear A-type AFM ordering of Eu+2 spins S = 7/2 or a planar noncollinear AFM structure, with the ordered moments oriented in the tetragonal ab plane in either case. This ordered-moment orientation for the A-type AFM is consistent with calculations with magnetic dipole interactions. As a result, the anisotropic ?(T) and isothermal M(H) data for EuCu2As2, also containing Eu+2 spins S = 7/2, strongly deviate from the predictions of molecular field theory for collinear AFM ordering and the AFM structure appears to be both noncollinear and noncoplanar.« less

  13. Solid aerosol generator

    DOE Patents [OSTI]

    Prescott, D.S.; Schober, R.K.; Beller, J.

    1992-03-17

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration is disclosed. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates. 2 figs.

  14. Improved solid aerosol generator

    DOE Patents [OSTI]

    Prescott, D.S.; Schober, R.K.; Beller, J.

    1988-07-19

    An improved solid aerosol generator used to produce a gas borne stream of dry, solid particles of predetermined size and concentration. The improved solid aerosol generator nebulizes a feed solution of known concentration with a flow of preheated gas and dries the resultant wet heated aerosol in a grounded, conical heating chamber, achieving high recovery and flow rates. 2 figs.

  15. Gas turbines have become widely used in the generation of power for cities. They are used all over the world and must operate under a wide variety of ambient conditions. Every turbine has a temperature at

    E-Print Network [OSTI]

    Gas turbines have become widely used in the generation of power for cities. They are used all over the world and must operate under a wide variety of ambient conditions. Every turbine has a temperature to the turbine has not been extensively studied or documented. It is important to understand how the droplets

  16. Optical Probing of metamagnetic phases in epitaxial EuSe

    SciTech Connect (OSTI)

    Galgano, G. D.; Henriques, A. B.; Bauer, G.; Springholz, G.

    2011-12-23

    EuSe is a wide gap magnetic semiconductors with a potential for applications in proof-of-concept spintronic devices. When the temperature is lowered, EuSe goes through sharp transitions between a variety of magnetic phases and is thus described as metamagnetic. The purpose of the present investigation is to correlate the magnetic order to the sharp dichroic doublet, discovered recently in high quality thin epitaxial layers of EuSe, grown by molecular beam epitaxy. We report detailed measurements of the doublet positions and intensities as a function of magnetic field in low temperatures, covering several magnetic phases.

  17. EU, U.S., Russia, Asian States Sign Nuclear-Fusion Reactor May 24 (Bloomberg) --The European Union, the U.S., Russia and Asian nations

    E-Print Network [OSTI]

    -gas emissions from fossil fuels, rising oil prices and worries about the safety of existing nuclear plantsEurope EU, U.S., Russia, Asian States Sign Nuclear-Fusion Reactor Pact May 24 (Bloomberg nuclear-fusion reactor, forging ahead with a 4.6 billion- euro ($5.9 billion) project to cut oil demand

  18. Eu{sup 3+} luminescence enhancement by intercalation of benzenepolycarboxylic guests into Eu{sup 3+}-doped layered gadolinium hydroxide

    SciTech Connect (OSTI)

    Gu, Qingyang; Pan, Guohua; Ma, Teng; Huang, Gailing; Sun, Genban; Ma, Shulan; Yang, Xiaojing

    2014-05-01

    Graphical abstract: Two benzenepolycarboxylic sensitizers, 1,3,5-benzenetricarboxylic acid (BTA) and 1,2,4,5-benzenetetracarboxylic acid (BA), were intercalated into NO{sub 3}–LGdH:Eu, in which different structures of the compounds resulted in varied arrangement in the gallery. The two organic compounds especially BA markedly enhanced the red luminescence of Eu{sup 3+} due to efficient energy transfer between the organic guests and Eu{sup 3+} centers. - Highlights: • We report the intercalation of benzenepolycarboxylic organic sensitizers into LRH. • We study the intercalation structure and the arrangement of the interlayer guests. • The two organic compounds can markedly enhance the luminescence of Eu{sup 3+}. • There exists efficient energy transfer between organic guests and Eu{sup 3+} centers. • This material opens a route for fabricating new multifunctional luminescent materials. - Abstract: Two benzenepolycarboxylic organic sensitizers, 1,3,5-benzenetricarboxylic acid (BTA) and 1,2,4,5-benzenetetracarboxylic acid (BA), were intercalated into the gallery of NO{sub 3}{sup ?} type Eu{sup 3+}-doped layered gadolinium hydroxide (NO{sub 3}–LGdH:Eu). CHN analysis, FTIR, and SEM were employed to characterize the intercalation structures of the as-prepared organic/inorganic hybrids. The area per unit charge (S{sub charge}) was used to explain the intercalation structure and the arrangement of the interlayer guests. Different structures of the two organic compounds resulted in varied arrangement of guests. Photoluminescence studies indicated that both of the two organic compounds especially BA markedly enhanced the red luminescence of Eu{sup 3+} due to efficient energy transfer between the organic guests and Eu{sup 3+} centers.

  19. Distributed Generation Investment by a Microgrid under Uncertainty

    E-Print Network [OSTI]

    Siddiqui, Afzal

    2008-01-01

    Cost of Natural Gas Generation, p Figure 6. Normalised NetCost of Natural Gas Generation, p Figure 7. Wait InvestCost of Natural Gas Generation (US$/kWh e ), C Figure 8.

  20. Distributed Generation Investment by a Microgrid Under Uncertainty

    E-Print Network [OSTI]

    Siddiqui, Afzal; Marnay, Chris

    2006-01-01

    the long-term natural gas generation cost is stochastic, weterm natural gas generation cost, C (US$/kWh) 1 , evolvesonly if the natural gas generation cost decreases to US$

  1. Stringency and distribution in the EU ETS: first evidence 41 CLIMATE POLICY

    E-Print Network [OSTI]

    Steininger, Karl W.

    Stringency and distribution in the EU Emissions Trading Scheme: first evidence CLAUDIA KETTNER1,2 , ANGELA covered by the EU Emissions Trading Scheme (EU ETS) were compared. Based on data available for 24 Member: climate policy; emissions trading; EU Emissions Trading Scheme A partir des émissions vérifiées pour les

  2. Auctions to gas transmission access: The British experience

    E-Print Network [OSTI]

    McDaniel, Tanga; Neuhoff, Karsten

    2004-06-16

    combined cycle gas turbines, which were previously prohibited under EU energy law (UK Energy in Brief, July 2001, DTI). Figure 2 UK gas consumption (source: UK Energy in Brief, July 2001, DTI and national statistics) The concentration... illustrates the main gas pipeline network in Northern Europe. Most underwater pipelines start from gas fields and transport gas of different consistencies that has to be processed at the beach before it can be inserted to the National Transmission Network...

  3. New optimal power flow techniques to improve integration of distributed generation in responsive distribution networks 

    E-Print Network [OSTI]

    Robertson, James George

    2015-06-29

    Climate change has brought about legally-binding targets for Scotland, the U.K. and the E.U. to reduce greenhouse gas emissions and source a share of overall energy consumption from renewable energy resources by 2020. ...

  4. Luminescent properties of Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} and its potential application in white light emitting diodes

    SciTech Connect (OSTI)

    Wang, Zhijun; Li, Panlai; Li, Ting; Zhang, Xing; Li, Qingxuan; Yang, Zhiping; Guo, Qinglin

    2013-06-01

    Graphical abstract: Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} phosphor can be effectively excited by an ultraviolet and near-ultraviolet light, and produce a bright blue emission centered at 436 nm. The CIE chromaticity coordinations (x, y) of Na{sub 2}CaSiO{sub 4}:Eu{sup 2+}(NSCE)/Li{sub 2}SrSiO{sub 4}:Eu{sup 2+}(LSSE) vary with the molar ratio of the two constituents. When NSCE/LSSE is 1:3, the CIE chromaticity coordination is (0.332, 0.346), which is close to that of the natural sunlight (0.33, 0.33). The results indicate that Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} may be a promising blue phosphor for UV chip-based multi-phosphor converted white light emitting diodes. Highlights: ? Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} shows the blue emission with a peak at 436 nm and broad excitation band in the UV/n-UV range. ? White light with CIE coordinates (0.332, 0.346) is generated by mixing the blue phosphor with the Li{sub 2}SrSiO{sub 4}:Eu{sup 2+} yellow phosphor. ? Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} would be a promising blue phosphor candidate for UV chip-based multi-phosphor converted white LEDs. - Abstract: A novel blue phosphor Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} is synthesized by a high temperature solid-state reaction, and its luminescent properties are systematically studied. Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} can be effectively excited by the 354 nm radiation, and create blue emission (436 nm). The emission intensity of Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} is influenced by the Eu{sup 2+} doping content, and the optimal doping content is 1.5%, and the concentration quenching mechanism of Eu{sup 2+} in Na{sub 2}CaSiO{sub 4} can be attributed to the multipolar interaction. The white light with CIE coordinates (0.332, 0.346) is generated by mixing the blue phosphor Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} with the yellow phosphor Li{sub 2}SrSiO{sub 4}:Eu{sup 2+}. The results indicate that Na{sub 2}CaSiO{sub 4}:Eu{sup 2+} may be a potential blue emitting phosphor for UV chip-based multi-phosphor converted white light emitting diodes.

  5. Constructing Britain and the EU: a discourse theoretical account of the EU treaty reform process 2003-2007 

    E-Print Network [OSTI]

    Hawkins, Benjamin Robert

    2010-01-01

    This study aims to address the longstanding questions surrounding the consistently low levels of support articulated towards the European Union (EU)by British citizens. Existing studies highlight that political identities ...

  6. Electric Power Generation from Coproduced Fluids from Oil and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electric Power Generation from Coproduced Fluids from Oil and Gas Wells Electric Power Generation from Coproduced Fluids from Oil and Gas Wells The primary objective of this...

  7. Adapting On-Site Electrical Generation Platforms for Producer...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Adapting On-Site Electrical Generation Platforms for Producer Gas - Fact Sheet, April 2014 Adapting On-Site Electrical Generation Platforms for Producer Gas - Fact Sheet, April...

  8. The Gas/Electric Partnership 

    E-Print Network [OSTI]

    Schmeal, W. R.; Royall, D.; Wrenn, K. F. Jr.

    1997-01-01

    The electric and gas industries are each in the process of restructuring and "converging" toward one mission: providing energy. Use of natural gas in generating electric power and use of electricity in transporting natural gas will increase...

  9. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, R.; George, R.A.; Shockling, L.A.

    1993-04-06

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  10. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, Robert (Churchill Boro, PA); George, Raymond A. (Pittsburgh, PA); Shockling, Larry A. (Plum Borough, PA)

    1993-01-01

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  11. Bull. Mater. Sci., Vol. 35, No. 5, October 2012, pp. 767772. c Indian Academy of Sciences. Anti-tumor activity of self-charged (Eu,Ca):WO3 and Eu:CaWO4

    E-Print Network [OSTI]

    Volinsky, Alex A.

    -tumor activity of self-charged (Eu,Ca):WO3 and Eu:CaWO4 nanoparticles CAO LIN , CAO JIEXIN , WANG CONG, CHE PING July 2011 Abstract. Non-stoichiometric (Eu,Ca):WO3 and Eu:CaWO4 nanoparticles with anti-tumor activity structure. Colorimetric assay shows that 10 nm (Eu,Ca):WO3 and Eu:CaWO4 nanoparticles can effectively

  12. MHD Generating system

    DOE Patents [OSTI]

    Petrick, Michael (Joliet, IL); Pierson, Edward S. (Chicago, IL); Schreiner, Felix (Mokena, IL)

    1980-01-01

    According to the present invention, coal combustion gas is the primary working fluid and copper or a copper alloy is the electrodynamic fluid in the MHD generator, thereby eliminating the heat exchangers between the combustor and the liquid-metal MHD working fluids, allowing the use of a conventional coalfired steam bottoming plant, and making the plant simpler, more efficient and cheaper. In operation, the gas and liquid are combined in a mixer and the resulting two-phase mixture enters the MHD generator. The MHD generator acts as a turbine and electric generator in one unit wherein the gas expands, drives the liquid across the magnetic field and thus generates electrical power. The gas and liquid are separated, and the available energy in the gas is recovered before the gas is exhausted to the atmosphere. Where the combustion gas contains sulfur, oxygen is bubbled through a side loop to remove sulfur therefrom as a concentrated stream of sulfur dioxide. The combustor is operated substoichiometrically to control the oxide level in the copper.

  13. Fact #844: October 27, 2014 Electricity Generated from Coal has...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4: October 27, 2014 Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown Fact 844: October 27, 2014 Electricity Generated from Coal has...

  14. Distributed Generation Investment by a Microgrid Under Uncertainty

    E-Print Network [OSTI]

    Siddiqui, Afzal; Marnay, Chris

    2006-01-01

    option on natural gas generation, which increases in valueL ABORATORY Distributed Generation Investment by a MicrogridORMMES’06 Distributed Generation Investment by a Microgrid

  15. The Political Economy of Agri-Environmental Policies in the EU

    E-Print Network [OSTI]

    Swinnen, Johan

    2005-01-01

    Economy of Agri-Environmental Policies in the EU JohanEconomy of Agri-Environmental Policies in the EU Johan F.M.changes” Agri-environmental policies are only fraction of

  16. How EU Agri-Environmental Policy Might Have Differed Under Various WTO Scenarios

    E-Print Network [OSTI]

    Swinbank, Alan

    2005-01-01

    No. 12 How EU Agri-Environmental Policy Might Have DifferedEconomy of Agri-environmental Policies in the U.S. and the2005 How EU agri-environmental policy might have differed

  17. ANNUAL TRILATERAL U.S. - EU - JAPAN CONFERENCE ON CRITICAL MATERIALS...

    Energy Savers [EERE]

    TRILATERAL U.S. - EU - JAPAN CONFERENCE ON CRITICAL MATERIALS FOR A CLEAN ENERGY FUTURE, SEPTEMBER 8-9, 2014 ANNUAL TRILATERAL U.S. - EU - JAPAN CONFERENCE ON CRITICAL...

  18. UN-EU cooperation in international peace and security : the driving force behind peacekeeping cooperation 

    E-Print Network [OSTI]

    Choi, Yunmi

    2013-11-27

    In recent years, cooperation between the UN and the EU in the realm of international peacekeeping has gone through major changes, including the remarkable achievement of a ‘Joint Declaration on UN-EU Cooperation in Crisis ...

  19. Effect of Eu substitution on superconductivity in Ba{sub 8?x}Eu{sub x}Al{sub 6}Si{sub 40} clathrates

    SciTech Connect (OSTI)

    Liu, Lihua; Bi, Shanli; Peng, Bailu; Li, Yang

    2015-05-07

    The silicon clathrate superconductor is uncommon as its structure is dominated by strong Si-Si covalent bonds, rather than the metallic bond, that are more typical of traditional superconductors. To understand the influence of large magnetic moment of Eu on superconductivity for type-I clathrates, a series of samples with the chemical formula Ba{sub 8?x}Eu{sub x}Al{sub 6}Si{sub 40} (x?=?0, 0.5, 1, and 2) were synthesised in which Eu occupied Ba sites in cage center. With the increase of Eu content, the cubic lattice parameter decreases monotonically signifying continuous shrinkage of the constituting (Ba/Eu)@Si{sub 20} and (Ba/Eu)@Si{sub 24} cages. The temperature dependence of magnetization at low temperature revealed that Ba{sub 8}Al{sub 6}Si{sub 40} is superconductive with transition temperature at T{sub C}?=?5.6?K. The substitution of Eu for Ba results in a strong superconductivity suppression; Eu-doping largely decreases the superconducting volume and transition temperature T{sub C}. Eu atoms enter the clathrate lattice and their magnetic moments break paired electrons. The Curie-Weiss temperatures were observed at 3.9, 6.6, and 10.9?K, respectively, for samples with x?=?0.5, 1.0, and 2.0. Such ferromagnetic interaction of Eu can destroy superconductivity.

  20. The EU Emission Trading Scheme Insights from the First Trading Years

    E-Print Network [OSTI]

    Steininger, Karl W.

    observed in the Kyoto period. Price development in the EU ETS is mainly driven by the perceived stringency

  1. India, EU to work towards blocking terror C R Jayachandran

    E-Print Network [OSTI]

    and investment agreement. An India-EU Initiative on Clean Development and Climate Change, with the aim of promoting cleaner technologies and their use, has also been launched. Energy Sector The two sides decided to strenghten cooperation in the energy sector to develop more efficient, cleaner and alternative energy chains

  2. EU 'confident' of star power site By Jo Twist

    E-Print Network [OSTI]

    option because of its position on the war in Iraq. Star power After the International Space Station, Iter stations, and would pave the way for commercial power production. In a fusion reaction, energy is producedEU 'confident' of star power site By Jo Twist BBC News Online science staff Europe is still

  3. Tapping Landfill Gas to Provide Significant Energy Savings and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    impurities inherent in landfill gas and to compress the gas * Pipeline: Transports the gas to the power plant * Power plant: A combined cycle generating facility comprised of...

  4. EU, CHINA AND THE ENVIRONMENTAL CHALLENGE IN AFRICA A case study from timber industry in Gabon

    E-Print Network [OSTI]

    level. This paper does not aim to broadly discuss EU environmental policy, but it rather1 EU, CHINA AND THE ENVIRONMENTAL CHALLENGE IN AFRICA A case study from timber industry: .....................................................................................................................................................2 Part I: The EU, China and the external environmental dimension

  5. Carbon Leakage in the Primary Aluminium Sector: What evidence after 6 years of the EU ETS?

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of the European Union Emissions Trading Scheme (EU ETS). The findings suggest that while rising electricity prices. Keywords: carbon leakage, European Union Emissions Trading Scheme (EU ETS), CO2 pricing 1 1 #12;32 2 1 - Introduction Since the European Union Emissions Trading Scheme (EU ETS) began pricing CO2 emissions within

  6. Copyright reform on the EU level European Network for Copyright in support of

    E-Print Network [OSTI]

    Kuhlen, Rainer

    Copyright reform on the EU level European Network for Copyright in support of Education and Budapest Business School #12;Copyright reform on the EU level What can science and education expect from a copyright reform on the EU level? Rainer Kuhlen University of Konstanz, HumboldtUniversity Berlin, IPR

  7. EIS-0105: Conversion to Coal, Baltimore Gas & Electric Company, Brandon Shores Generating Station Units 1 and 2, Anne Arundel County, Maryland

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy’s Economic Regulatory Administration Office of Fuels Program, Coal and Electricity Division prepared this statement to assess the potential environmental and socioeconomic impacts associated with prohibiting the use of petroleum products as a primary energy source for Units 1 and 2 of the Brandon Shores Generating Station, located in Anne Arundel County, Maryland.

  8. Gas cleaning system and method

    DOE Patents [OSTI]

    Newby, Richard Allen

    2006-06-06

    A gas cleaning system for removing at least a portion of contaminants, such as halides, sulfur, particulates, mercury, and others, from a synthesis gas (syngas). The gas cleaning system may include one or more filter vessels coupled in series for removing halides, particulates, and sulfur from the syngas. The gas cleaning system may be operated by receiving gas at a first temperature and pressure and dropping the temperature of the syngas as the gas flows through the system. The gas cleaning system may be used for an application requiring clean syngas, such as, but not limited to, fuel cell power generation, IGCC power generation, and chemical synthesis.

  9. Luminescence properties of a blue-emitting phosphor: (Sr{sub 1?x}Eu{sub x})Si{sub 9}Al{sub 19}ON{sub 31} (0

    SciTech Connect (OSTI)

    Liu, Lihong; Xie, Rong-Jun; Hirosaki, Naoto; Dierre, Benjamin; Sekiguchi, Takashi

    2013-11-15

    Blue-emitting Sr{sub 1?x}Eu{sub x}Si{sub 9}Al{sub 19}ON{sub 31} phosphors were synthesized at 1800 °C for 2 h under 1 MPa N{sub 2} by using the gas-pressure sintering method (GPS). The microstructure, photoluminescence (PL) properties of the prepared phosphors were investigated. Under the 290 nm excitation, broad PL emission bands with peak positions at 448–490 nm were detected. The concentration quenching was not observed owing to the large distance betweenEu{sup 2+} ions that made the nonradiative energy transfer between neighboring Eu{sup 2+} ions difficult. The blue phosphor generally showed a small thermal quenching at low Eu{sup 2+} concentrations. The absorption and external quantum efficiency of the synthesized Sr{sub 0.5}Eu{sub 0.5}Si{sub 9}Al{sub 19}ON{sub 31} were 85% and 62% upon the 365 nm excitation, respectively. The interesting PL results indicate that Sr{sub 1?x}Eu{sub x}Si{sub 9}Al{sub 19}ON{sub 31} has great potentials as a blue phosphor for white LEDs applications. - Graphical abstract: Sr{sub 0.7}Eu{sub 0.3}Si{sub 9}Al{sub 19}ON{sub 31} gives blue-emitting at 471 nm. Excitation spectrum is composed of five bands in the range of 250–450 nm, which are matching well with emission wavelength of UV LEDs. Display Omitted - Highlights: • Blue-emitting Sr{sub 1?x}Eu{sub x}Si{sub 9}Al{sub 19}ON{sub 31} phosphors were synthesized by gas-pressure sintering method. • The concentration quenching was not observed in this phosphor. • This blue phosphor generally showed a small thermal quenching at low Eu{sup 2+} concentrations. • The absorption and external quantum efficiency of the synthesized Sr{sub 0.5}Eu{sub 0.5}Si{sub 9}Al{sub 19}ON{sub 31} were 85% and 62% upon the 365 nm excitation.

  10. Preferential Eu Site Occupation and Its Consequences in the Ternary Luminescent HalidesAB2I5:Eu2+(A=LiCs;B=Sr, Ba)

    SciTech Connect (OSTI)

    Fang, C.? M.; Biswas, Koushik

    2015-07-22

    Several rare-earth-doped, heavy-metal halides have recently been identified as potential next-generation luminescent materials with high efficiency at low cost. AB2I5:Eu2+ (A=Li–Cs; B=Sr, Ba) is one such family of halides. Its members, such as CsBa2I5:Eu2+ and KSr2I5:Eu2+, are currently being investigated as high-performance scintillators with improved sensitivity, light yield, and energy resolution less than 3% at 662 keV. Within the AB2I5 family, our first-principles-based calculations reveal two remarkably different trends in Eu site occupation. The substitutional Eu ions occupy both eightfold-coordinated B1(VIII) and the sevenfold-coordinated B2(VII) sites in the Sr-containing compounds. However, in the Ba-containing crystals, Eu ions strongly prefer the B2(VII)sites. This random versus preferential distribution of Eu affects their electronic properties. The calculations also suggest that in the Ba-containing compounds one can expect the formation of Eu-rich domains. These results provide atomistic insight into recent experimental observations about the concentration and temperature effects in Eu-doped CsBa2I5. We discuss the implications of our results with respect to luminescent properties and applications. We also hypothesize Sr, Ba-mixed quaternary iodides ABaVIIISrVIII5:Eu as scintillators having enhanced homogeneity and electronic properties.

  11. The origin of bimodal luminescence of ?-SiAlON:Eu{sup 2+} phosphors as revealed by fluorescence microscopy and cathodoluminescence analysis

    SciTech Connect (OSTI)

    Gan, Lin; Mao, Zhi-Yong; Zeng, Xiong-Hui; Zhang, Yu-Qiang; Zhao, Yang; Xu, Fang-Fang; Zhu, Ying-Chun; Liu, Xue-Jian

    2014-03-01

    Graphical abstract: - Highlights: • Bimodal emission is originated from ?-SiAlON grains with z ? 2. • Coexistence of two kinds of emission centers in the ?-SiAlON phase is definite. • Fluorescence microscopy shows influence of the z value on emission of ?-SiAlON. - Abstract: Eu{sup 2+}-doped SiAlON phosphors with the composition of Eu{sub x}Si{sub 6?z}Al{sub z}O{sub z}N{sub 8?z} (0.5 ? z ? 3) at a fixed x = 0.01 were synthesized by the gas pressure sintering method. Dependence of luminescence properties on the phase compositions in ?-SiAlON:Eu{sup 2+} phosphors has been examined via fluorescence microscope and scanning electron microscope equipped with a cathodoluminescence spectrometer and an energy dispersive spectrometer. Bimodal emission (green and violet) from ?-SiAlON phase is observed in the samples with z ? 2, indicating co-existence of two different kinds of coordination for Eu{sup 2+} ions in the host lattice.

  12. Seeking the optimal LaTaO{sub 4}:Eu phosphor

    SciTech Connect (OSTI)

    Bleier, Grant C. [Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185 (United States); Nyman, May, E-mail: mdnyman@sandia.gov [Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185 (United States); Rohwer, Lauren E.S.; Rodriguez, Mark A. [Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185 (United States)

    2011-12-15

    Lanthanum orthotantalate, LaTaO{sub 4}, is an excellent host lattice for rare-earth luminescent ions such as Eu{sup 3+} for red emission. However, there are multiple RETaO{sub 4} (RE=rare earth) polymorphs, and the stability of these is controlled predominantly by the RE-radius. Thus it is difficult to obtain a pure phase of LaTaO{sub 4}:Eu as Eu concentration and consequently the RE radius is varied. We recently reported a 'soft-chemical' route that allows crystallization of pure-phase LaTaO{sub 4}:Eu at temperatures as low as 800 Degree-Sign C. In the current report, we investigate polymorph evolution and Eu emission as a function of Eu concentration and annealing temperature. We obtain a maximum quantum yield (QY) of 83% at the highest Eu substitution (25%) for which the low temperature orthorhombic (Pbca) polymorph is stable. Therefore, QY is not limited necessarily by concentration quenching; rather it is limited by polymorph stability as the RE-radius decreases with increasing Eu substitution. - Graphical Abstract: Eu-substituted lanthanum orthotantalates, LaTaO{sub 4}:Eu, are excellent red phosphors. They exhibit up to 83% quantum-yield emission under blue light excitation, optimized through both 'soft chemical processing' and polymorph purity. Highlights: Black-Right-Pointing-Pointer LaTaO{sub 4}:Eu phosphors were synthesized via 'soft-chemical' and solid-state routes. Black-Right-Pointing-Pointer Quantum-yield of Eu emission depends on host polymorph, which changes with La:Eu ratio. Black-Right-Pointing-Pointer Polymorph with optimal Eu-emission is only obtained by 'soft-chemistry'.

  13. Coupled natural gas and electric power systems

    E-Print Network [OSTI]

    Leung, Tommy (Tommy Chun Ting)

    2015-01-01

    Scarce pipeline capacity in regions that rely on natural gas technologies for electricity generation has created volatile prices and reliability concerns. Gas-fired generation firms uniquely operate as large consumers in ...

  14. Diophantine Generation,

    E-Print Network [OSTI]

    Shlapentokh, Alexandra

    Diophantine Generation, Horizontal and Vertical Problems, and the Weak Vertical Method Alexandra Shlapentokh Diophantine Sets, Definitions and Generation Diophantine Sets Diophantine Generation Properties of Diophantine Generation Diophantine Family of Z Diophantine Family of a Polynomial Ring Going Down Horizontal

  15. Are the Radical Centers in Peptide Radical Cations Mobile? The Generation, Tautomerism, and Dissociation of Isomeric ?-Carbon-Centered Triglycine Radical Cations in the Gas Phase

    SciTech Connect (OSTI)

    Chu, Ivan K.; Zhao, Junfang; Xu, Minjie; Siu, Shiu On; Hopkinson, Alan C.; Siu , K W Michael

    2008-05-31

    The mobility of the radical center in three isomeric triglycine radical cationss[G•GG]+, [GG•G]+, and [GGG•]+shas been investigated theoretically via density functional theory (DFT) and experimentally via tandem mass spectrometry. These radical cations were generated by collision-induced dissociations (CIDs) of Cu(II)-containing ternary complexes that contain the tripeptides YGG, GYG, and GGY, respectively (G and Y are the glycine and tyrosine residues, respectively). Dissociative electron transfer within the complexes led to observation of [Y•GG]+, [GY•G]+, and [GGY•]+; CID resulted in cleavage of the tyrosine side chain as p-quinomethide, yielding [G•GG]+, [GG•G]+, and [GGG•]+, respectively. Interconversions between these isomeric triglycine radical cations have relatively high barriers (g44.7 kcal/mol), in support of the thesis that isomerically pure [G•GG]+, [GG•G]+, and [GGG•]+ can be experimentally produced. This is to be contrasted with barriers < 17 kcal/mol that were encountered in the tautomerism of protonated triglycine [Rodriquez C. F. et al. J. Am. Chem. Soc. 2001, 123, 3006-3012]. The CID spectra of [G•GG]+, [GG•G]+, and [GGG•]+ were substantially different, providing experimental proof that initially these ions have distinct structures. DFT calculations showed that direct dissociations are competitive with interconversions followed by dissociation.

  16. Optical and structural stability of blue SrO:Eu{sup 2+} phosphor

    SciTech Connect (OSTI)

    Komatsu, Keiji; Nakamura, Atsushi; Ohshio, Shigeo; Toda, Ikumi; Muramatsu, Hiroyuki; Saitoh, Hidetoshi

    2013-08-15

    Chemical stability of 6-coodinated SrO is a fundamental problem when this is used for various applications. In this study, optical and chemical stabilities of 8-coordinated SrO:Eu{sup 2+} phosphor were investigated. SrO:Eu{sup 2+} phosphor was synthesized from thermal treatment of SrO:Eu powder located on a single crystalline MgO at 1500° C under reduction atmosphere. Obtained 8-coordinated SrO:Eu{sup 2+} phosphor exhibit strong blue luminescence and chemical stability in distilled water for 3 days. Our findings prove that obtained 8-coordinated SrO:Eu{sup 2+} possesses relative optical and chemical stabilities in water. - Graphical abstract: Obtained 8-coordinated SrO:Eu{sup 2+} phosphor exhibit strong blue luminescence in distilled water. Highlights: • We investigated optical and chemical stabilities of 8-coordinated SrO:Eu{sup 2+} phosphor in water. • Obtained 8-coordinated SrO:Eu{sup 2+} phosphor exhibit strong blue luminescence and chemical stability in distilled water for 3 days. • We found that the 8-coodrodinated SrO crystal structure changed to SrCO{sub 3} crystal structure after the 5 days immersion. • The obtained SrO:Eu{sup 2+} phosphor possesses high chemical stability under water, compared with commercial (6-coordinated) SrO.

  17. EcoGrid EU (Smart Grid Project) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, AlabamaETEC GmbH Jump to:Providence, RhodeEchols County,EU (Smart Grid Project) Jump

  18. Distributed Generation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electricity, US Data. 6. Distributed Generation: Standby Generation and Cogeneration Ozz Energy Solutions, Inc. February 28 th , 2005. For more information about...

  19. Chena Hot Springs Resort - Electric Power Generation Using Geothermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hot Springs Resort - Electric Power Generation Using Geothermal Fluid Coproduced from Oil andor Gas Wells Chena Hot Springs Resort - Electric Power Generation Using Geothermal...

  20. Generating Resources Advisory Committee

    E-Print Network [OSTI]

    Generating Resources Advisory Committee February 27, 2014 Steven Simmons and Gillian Charles Upcoming Symposium 9:15 am Natural Gas Peaking Technologies Technology Trends Proposed reference plant Costing, Economies of Scale, Normalizations Reference Plants 12:30 pm Discussion of Next GRAC Meetings

  1. Natural gas leak mapper

    DOE Patents [OSTI]

    Reichardt, Thomas A. (Livermore, CA); Luong, Amy Khai (Dublin, CA); Kulp, Thomas J. (Livermore, CA); Devdas, Sanjay (Albany, CA)

    2008-05-20

    A system is described that is suitable for use in determining the location of leaks of gases having a background concentration. The system is a point-wise backscatter absorption gas measurement system that measures absorption and distance to each point of an image. The absorption measurement provides an indication of the total amount of a gas of interest, and the distance provides an estimate of the background concentration of gas. The distance is measured from the time-of-flight of laser pulse that is generated along with the absorption measurement light. The measurements are formated into an image of the presence of gas in excess of the background. Alternatively, an image of the scene is superimosed on the image of the gas to aid in locating leaks. By further modeling excess gas as a plume having a known concentration profile, the present system provides an estimate of the maximum concentration of the gas of interest.

  2. Power generation method including membrane separation

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A. (Union City, CA)

    2000-01-01

    A method for generating electric power, such as at, or close to, natural gas fields. The method includes conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas by means of a membrane separation step. This step creates a leaner, sweeter, drier gas, which is then used as combustion fuel to run a turbine, which is in turn used for power generation.

  3. Table 2. Ten largest plants by generation capacity, 2013

    U.S. Energy Information Administration (EIA) Indexed Site

    Sandy","Coal","Kentucky Power Co",1060 9,"Riverside Generating LLC","Natural gas","Riverside Generating Co LLC",825 10,"J K Smith","Natural gas","East Kentucky Power Coop, Inc",784...

  4. SrAgZn and EuAgZn with KHg{sub 2}-type structure—Structure, magnetic properties, and {sup 151}Eu Mössbauer spectroscopy

    SciTech Connect (OSTI)

    Gerke, Birgit; Rodewald, Ute Ch.; Niehaus, Oliver; Pöttgen, Rainer

    2013-07-15

    Samples of SrAgZn and EuAgZn were synthesized by reaction of the elements in sealed tantalum crucibles. Both structures were refined on the basis of single crystal X-ray diffractometer data: KHg{sub 2}-type, Imma, a=476.7(1), b=780.9(2), c=810.1(2) pm, R{sub 1}/wR{sub 2}=0.0189/0.0119, 381 F² values for SrAg{sub 1.12}Zn{sub 0.88} and a=474.43(9), b=760.8(2), c=799.0(2) pm, R{sub 1}/wR{sub 2}=0.0226/0.0483, 370 F² values for EuAg{sub 1.17}Zn{sub 0.83} with 13 variables per refinement. Silver and zinc are randomly distributed on the Hg position and build up three-dimensional networks. EuAgZn shows ferromagnetic ordering at 29(1) K. In the temperature range from 75 to 300 K the sample shows Curie–Weiss behaviour with ?{sub eff}=7.87(1) ?{sub B}/Eu atom and ?{sub P}=37.1(1) K, indicating divalent europium. {sup 151}Eu Mössbauer spectroscopic measurements confirmed the divalent state with an isomer shift of ?9.31 mm/s at 78 K. Temperature dependent {sup 151}Eu data show first magnetic hyperfine field splitting at 25 K and a saturated magnetization of 17 T at 5.2 K. The temperature dependence can be described by an S=7/2 Brillouin function. - Graphical abstract: The near neighbor coordination of the strontium and europium atoms in SrAg{sub 1.12}Zn{sub 0.88}, EuAg{sub 1.17}Zn{sub 0.83}, and EuAuZn. - Highlights: • Synthesis of new intermetallic zinc compounds SrAgZn and EuAgZn. • Ferromagnetic ordering of EuAgZn at 29 K. • Magnetic hyperfine field splitting in the {sup 151}Eu Mössbauer spectrum.

  5. Jobs and Economic Development from New Transmission and Generation...

    Wind Powering America (EERE)

    Construction- and Operations-related Economic Activity from 1,800 MW of New Natural Gas Generation ......

  6. E.U. Tensions Surface Over Radical Nuclear AFP: 9/24/2004

    E-Print Network [OSTI]

    prototype reactor for nuclear fusion, which is billed as a clean, safe, inexhaustible energy source energy project, the subject of rival bids from France and Japan. But sources said the EU was also growing strong preference" for Cadarache, and "would support an initiative by the EU to unblock the situation

  7. CARBON LEAKAGE AND CAPACITY-BASED ALLOCATIONS. IS THE EU RIGHT?

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , California, China, India, New Zealand...). The EU implemented its ETS in 2005 and has signicantly revised Organization (Wooders and Cosbey, 2010). The main approach to circumvent this political constraint relies in Australia if the new majority does not repeal the Clean Energy Future legislation). The EU has followed

  8. Cross Border Trading and Borrowing in the EU ETS A. Denny Ellerman* and Raphael Trotignon**

    E-Print Network [OSTI]

    multi- national trading system, the European Union's CO2 Emissions Trading Scheme (EU ETS) provides** This paper exploits a little used data resource within the central registry of the European Union's Emissions Trading System (EU ETS) to analyze cross border trading and inter-year borrowing during the first trading

  9. Price relationships in the EU emissions trading system Julien Chevallier1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Price relationships in the EU emissions trading system Julien Chevallier1 Université Paris Dauphine Abstract The Emissions Trading Scheme (ETS) constrains industrial polluters to buy/sell CO2 the price relationships in the EU emissions trading system. The United Nations Framework Convention

  10. A bottom-up analysis of including aviation within theEU's Emissions Trading Scheme

    E-Print Network [OSTI]

    Watson, Andrew

    A bottom-up analysis of including aviation within theEU's Emissions Trading Scheme Alice Bows-up analysis of including aviation within the EU's Emissions Trading Scheme Alice Bows & Kevin Anderson Tyndall's emissions trading scheme. Results indicate that unless the scheme adopts both an early baseline year

  11. Print this article Close This Window EU OKs India joining ITER nuclear reactor project

    E-Print Network [OSTI]

    Print this article Close This Window EU OKs India joining ITER nuclear reactor project Fri Dec 2-billion-euro project to build an experimental nuclear fusion reactor that in the long-run could provide virtually unlimited, cheap and clean energy. The EU's willingness to work with India on a civil nuclear

  12. EU warns of breakaway plans on nuclear project 24 September 2004

    E-Print Network [OSTI]

    without digging into EU funds, he added. That is a key demand of Germany and Britain, as well as the Dutch -- which is backed by South Korea, China, the United States and Russia as well as the EU. But the European

  13. building science into EU policy The current status of biofuels in the

    E-Print Network [OSTI]

    easac building science into EU policy The current status of biofuels in the European Union the EASAC Secretariat at secretariat@easac.eu #12;The current status of biofuels in the European Union, their environmental impacts and future prospects easac #12;ii | December 2012 | Sustainable Biofuels EASAC ISBN 978

  14. An EIE/Altener project Co-funded by the EU Commission

    E-Print Network [OSTI]

    of Biogas for Electricity and Heat Production in EU countries. Economic and Environmental Benefits of Biogas is to assess the economic, environmental and energy aspects of the biogas production by centralised co-digestion in selected areas of six EU countries, which have been slow to implement biogas technology. The assessment

  15. EU Gives Japan Until End-June to Accept Nuclear-Project Offer

    E-Print Network [OSTI]

    Print EU Gives Japan Until End-June to Accept Nuclear- Project Offer March 7 (Bloomberg) -- The European Union gave Japan until the end of June to accept an offer of a ``privileged partnership'' in a 4 must begin this year. The EU made the partnership offer in November to break a deadlock in which China

  16. EU BIOFUEL USE AND AGRICULTURAL COMMODITY PRICES: A REVIEW OF THE EVIDENCE BASE

    E-Print Network [OSTI]

    EU BIOFUEL USE AND AGRICULTURAL COMMODITY PRICES: A REVIEW OF THE EVIDENCE BASE Report prepared: Kretschmer, B, Bowyer, C and Buckwell, A (2012) EU Biofuel Use and Agricultural Commodity Prices: A Review ....................................................................................................... 20 4 THE ROLE OF VARIOUS KEY FACTORS IN DETERMINING AGRICULTURAL COMMODITY PRICES

  17. Volume 1, Issue 2 2009 Article 5 Effectiveness of Poverty Reduction in the EU: A Descriptive

    E-Print Network [OSTI]

    Galis, Frietson

    Volume 1, Issue 2 · 2009 · Article 5 Effectiveness of Poverty Reduction in the EU: A Descriptive Organization Caminada, Koen and Goudswaard, Kees (2009) "Effectiveness of Poverty Reduction in the EU: A Descriptive Analysis," Poverty & Public Policy: Vol. 1: Iss. 2, Article 5. Available at: http

  18. Preliminary Estimates of Combined Heat and Power Greenhouse Gas Abatement Potential for California in 2020

    E-Print Network [OSTI]

    Firestone, Ryan; Ling, Frank; Marnay, Chris; Hamachi LaCommare, Kristina

    2007-01-01

    sources listed here, non-cogeneration natural gas sourcesthe conclusion that only non-cogeneration natural-gas-firedforecasted level of non-cogeneration natural gas generation

  19. Growth and optical properties of partially transparent Eu doped CaF{sub 2} ceramic

    SciTech Connect (OSTI)

    Ghosh, Manoranjan Sen, Shashwati Pitale, S. S. Goutam, U. K. Shinde, Seema Patra, G. D. Gadkari, S. C.

    2014-04-24

    Partially transparent ceramic of 2 at.% Eu doped CaF{sub 2} have been grown preferentially towards [111] direction. For this purpose, Eu doped CaF{sub 2} nanoparticles (size?12 nm) obtained by a low temperature solution growth method has been pressed at 1000°C under vacuum. The preferentially grown ceramic shows 15% transparency within the visible range of spectrum. As confirmed by the X-ray diffraction result, the hot pressed ceramic exhibits reduced lattice volume than the nanopowder. It indicates Eu{sup 3+} as the dominant substituting ions at the Ca{sup 2+} sites of CaF{sub 2} lattice in the hot pressed ceramic material. It is corroborated by the photoluminescence results of hot pressed ceramic which shows strong red emission corresponding to Eu{sup 3+} sites. However, photoluminescence of nanopowder exhibits intense peak in the blue region of the spectrum which is characteristics of Eu2+ sites.

  20. Multi-level governance revisited: comparing the strategies of interest representation of legislative regions in EU environmental policy- making. 

    E-Print Network [OSTI]

    Högenauer, Anna-Lena

    2011-07-04

    Since the 1980s, regions have taken a strong interest in EU policy-making and increasingly demanded representation in the process. This has given rise to the concept of multi-level governance (MLG) in EU policy-making, ...

  1. Retained Gas Sampling Results for the Flammable Gas Program

    SciTech Connect (OSTI)

    J.M. Bates; L.A. Mahoney; M.E. Dahl; Z.I. Antoniak

    1999-11-18

    The key phenomena of the Flammable Gas Safety Issue are generation of the gas mixture, the modes of gas retention, and the mechanisms causing release of the gas. An understanding of the mechanisms of these processes is required for final resolution of the safety issue. Central to understanding is gathering information from such sources as historical records, tank sampling data, tank process data (temperatures, ventilation rates, etc.), and laboratory evaluations conducted on tank waste samples.

  2. GASIFICATION FOR DISTRIBUTED GENERATION

    SciTech Connect (OSTI)

    Ronald C. Timpe; Michael D. Mann; Darren D. Schmidt

    2000-05-01

    A recent emphasis in gasification technology development has been directed toward reduced-scale gasifier systems for distributed generation at remote sites. The domestic distributed power generation market over the next decade is expected to be 5-6 gigawatts per year. The global increase is expected at 20 gigawatts over the next decade. The economics of gasification for distributed power generation are significantly improved when fuel transport is minimized. Until recently, gasification technology has been synonymous with coal conversion. Presently, however, interest centers on providing clean-burning fuel to remote sites that are not necessarily near coal supplies but have sufficient alternative carbonaceous material to feed a small gasifier. Gasifiers up to 50 MW are of current interest, with emphasis on those of 5-MW generating capacity. Internal combustion engines offer a more robust system for utilizing the fuel gas, while fuel cells and microturbines offer higher electric conversion efficiencies. The initial focus of this multiyear effort was on internal combustion engines and microturbines as more realistic near-term options for distributed generation. In this project, we studied emerging gasification technologies that can provide gas from regionally available feedstock as fuel to power generators under 30 MW in a distributed generation setting. Larger-scale gasification, primarily coal-fed, has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries. Commercial-scale gasification activities are under way at 113 sites in 22 countries in North and South America, Europe, Asia, Africa, and Australia, according to the Gasification Technologies Council. Gasification studies were carried out on alfalfa, black liquor (a high-sodium waste from the pulp industry), cow manure, and willow on the laboratory scale and on alfalfa, black liquor, and willow on the bench scale. Initial parametric tests evaluated through reactivity and product composition were carried out on thermogravimetric analysis (TGA) equipment. These tests were evaluated and then followed by bench-scale studies at 1123 K using an integrated bench-scale fluidized-bed gasifier (IBG) which can be operated in the semicontinuous batch mode. Products from tests were solid (ash), liquid (tar), and gas. Tar was separated on an open chromatographic column. Analysis of the gas product was carried out using on-line Fourier transform infrared spectroscopy (FT-IR). For selected tests, gas was collected periodically and analyzed using a refinery gas analyzer GC (gas chromatograph). The solid product was not extensively analyzed. This report is a part of a search into emerging gasification technologies that can provide power under 30 MW in a distributed generation setting. Larger-scale gasification has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries, and it is probable that scaled-down applications for use in remote areas will become viable. The appendix to this report contains a list, description, and sources of currently available gasification technologies that could be or are being commercially applied for distributed generation. This list was gathered from current sources and provides information about the supplier, the relative size range, and the status of the technology.

  3. EU Funded Research Activities on NPPS Operational Safety

    SciTech Connect (OSTI)

    Manolatos, P.; Van Goethem, G. [European Commission, DG Research J.4 Nuclear Fission and Radiation Protection, 1049 Brussels (Belgium)

    2002-07-01

    The 5. framework programme (FP-5), the pluri-annual research programme of the European Union (EU), covers the period 1998-2002. Research on nuclear energy, fusion and fission, is covered by the EURATOM part of the FP-5. An overview of the Euratom's research on Nuclear Reactor Safety, managed by the DG-RTD of the European Commission (EC), is presented. This concerns 70 multi-partner projects of approximately euro 82.5 million total contract value that have been selected and co-financed during the period 1999-2001. They form the three clusters of projects dealing with the 'Operational Safety of Existing Installations'. 'Plant Life Extension and Management' (PLEM), 'Severe Accident Management' (SAM) and 'Evolutionary concepts' (EVOL). Emphasis is given here to the projects of the PLEM cluster. (authors)

  4. The Role of Domestic Factors in the Formation of Trade Unions: A Look at Turkey/EU Relations 

    E-Print Network [OSTI]

    Youngblood, Kristina Lynne

    2008-08-19

    I studied Turkey and the European Union (EU). Turkey was officially admitted as a candidate country to the EU in 1997. Despite efforts to meet EU demands, Turkey’s admittance has been blocked. As recently as 2007 Turkey was denied membership...

  5. Turkey Watch: EU Member States' Perceptions on Turkey's Accession to ISBN: 978-605-89751-2-5

    E-Print Network [OSTI]

    Hasýrcý, Vasýf

    #12;#12;#12;#12;#12;1 Turkey Watch: EU Member States' Perceptions on Turkey's Accession to the EU Technical University, Ankara, Turkey. SInAN logosu ve Strengthening and Integrating Academic Networks University under the Programme `Promotion of Civil Society Dialogue between the EU and Turkey: Universities

  6. A least-cost optimisation model of CO{sub 2} capture applied to major UK power plants within the EU-ETS framework

    SciTech Connect (OSTI)

    Kemp, A.G.; Kasim, A.S.

    2008-02-15

    Concerns about the cost of CO{sub 2} capture and sequestration, and the effectiveness of carbon abatement policies loom large in discussions on climate change mitigation. Several writers address the issue from various perspectives. This paper attempts to add relative realism to discussions on CO{sub 2} capture costs and the deployment of carbon capture technology in the UK by using publicly available company data on the long term capacity expansion and CO{sub 2} capture investment programmes of selected power plants in the UK. With an estimated 8 billion plan to install a generation capacity of GW and capture capability of 44 Mt CO{sub 2}/year, it is imperative to optimise this huge potential investment. A least-cost optimisation model was formulated and solved with the LP algorithm available in GAMS. The model was then applied to address a number of issues, including the choice of an optimal carbon abatement policy within the EU-ETS framework. The major findings of the study include (a) the long term total cost curve of CO{sub 2} capture has three phases rising, plateau, rising; (b) alternative capture technologies do not have permanent relative cost advantages or disadvantages; (c) Government incentives encourage carbon capture and the avoidance of emission penalty charges; and (d) the goals of EU-ETS are more effectively realised with deeper cuts in the EUA ratios than merely hiking the emission penalty, as proposed in EU-ETS Phase II.

  7. Reliability Evaluation of Electric Power Generation Systems with Solar Power 

    E-Print Network [OSTI]

    Samadi, Saeed

    2013-11-08

    Conventional power generators are fueled by natural gas, steam, or water flow. These generators can respond to fluctuating load by varying the fuel input that is done by a valve control. Renewable power generators such as ...

  8. Satoshi Hada Department of Gas Turbine Engineering,

    E-Print Network [OSTI]

    Thole, Karen A.

    Satoshi Hada Department of Gas Turbine Engineering, Mitsubishi Heavy Industries, Ltd., Takasago must be prevented by developing envi- ronmentally friendly power plants. Industrial gas turbines play a major role in power generation with modern high temperature gas turbines being applied in the gas

  9. Distributed generation

    SciTech Connect (OSTI)

    Ness, E.

    1999-09-02

    Distributed generation, locating electricity generators close to the point of consumption, provides some unique benefits to power companies and customers that are not available from centralized electricity generation. Photovoltaic (PV) technology is well suited to distributed applications and can, especially in concert with other distributed resources, provide a very close match to the customer demand for electricity, at a significantly lower cost than the alternatives. In addition to augmenting power from central-station generating plants, incorporating PV systems enables electric utilities to optimize the utilization of existing transmission and distribution.

  10. Preparation of blue-emitting CaMgSi{sub 2}O{sub 6}:Eu{sup 2+} phosphors in reverse micellar system and their application to transparent emissive display devices

    SciTech Connect (OSTI)

    Choi, Sungho; Tae, Se-Won; Seo, Jung-Hyun; Jung, Ha-Kyun

    2011-06-15

    Blue-emitting Eu{sup 2+}-doped CaMgSi{sub 2}O{sub 6} phosphors were prepared by the reverse micelle method. The resultant particles were nanocrystalline with a grain size of about <300 nm and exhibited a characteristic blue emission spectrum centered at 445 nm induced by the oxygen coordinated Eu{sup 2+} ions. By using the corresponding nanophosphors followed by the formation of a uniform phosphor layer, we have demonstrated the mini-sized transparent plasma-discharge panels and investigated their luminance characteristics. Phosphor coated panel is properly transparent, {>=}65%, at the visible wavelength region and illuminates a characteristic blue emission under Ne/Xe plasma discharge conditions. Thus, we can obtain a fast decaying, robust blue-emitting silicate phosphor layer under excited plasma radiation for upcoming emissive display devices like as transparent and three-dimensional plasma display panels. - Graphical abstract: Blue-emitting CaMgSi{sub 2}O{sub 6}:Eu{sup 2+} nanophosphors coated transparent luminescent layers can be obtained. It illuminates the characteristic blue emission, spectrum centered at 425 nm wavelength, under the Ne-Xe mixed gas plasma discharge condition. Highlights: > Blue-emitting CaMgSi{sub 2}O{sub 6}:Eu{sup 2+} nanophosphors via reverse micelle method. > Transparent blue-emitting layer was prepared by using corresponding phosphors. > Fast decaying with degradation-free luminescent layer under plasma radiation. > Promising luminescent layer for the upcoming plasma discharged transparent displays.

  11. Model Catalysis of Ammonia Synthesis ad Iron-Water Interfaces - ASum Frequency Generation Vibrational Spectroscopic Study of Solid-GasInterfaces and Anion Photoelectron Spectroscopic Study of Selected Anionclusters

    SciTech Connect (OSTI)

    Ferguson, Michael James

    2005-12-15

    The ammonia synthesis reaction has been studied using single crystal model catalysis combined with sum frequency generation (SFG) vibrational spectroscopy. The adsorption of gases N{sub 2}, H{sub 2}, O{sub 2} and NH{sub 3} that play a role in ammonia synthesis have been studied on the Fe(111) crystal surface by sum frequency generation vibrational spectroscopy using an integrated Ultra-High Vacuum (UHV)/high-pressure system. SFG spectra are presented for the dissociation intermediates, NH{sub 2} ({approx}3325 cm{sup -1}) and NH ({approx}3235 cm{sup -1}) under high pressure of ammonia or equilibrium concentrations of reactants and products on Fe(111) surfaces. Special attention was paid to understand how potassium promotion of the iron catalyst affects the intermediates of ammonia synthesis. An Fe(111) surface promoted with 0.2 monolayers of potassium red shifts the vibrational frequencies of the reactive surface intermediates, NH and NH{sub 2}, providing evidence for weakened the nitrogen-hydrogen bonds relative to clean Fe(111). Spectral features of these surface intermediates persisted to higher temperatures for promoted iron surfaces than for clean Fe(111) surfaces implying that nitrogen-iron bonds are stronger for the promoted surface. The ratio of the NH to NH{sub 2} signal changed for promoted surfaces in the presence of equilibrium concentrations of reactants and products. The order of adding oxygen and potassium to promoted surfaces does not alter the spectra indicating that ammonia induces surface reconstruction of the catalyst to produce the same surface morphology. When oxygen is co-adsorbed with nitrogen, hydrogen, ammonia or potassium on Fe(111), a relative phase shift of the spectra occurs as compared to the presence of adsorbates on clean iron surfaces. Water adsorption on iron was also probed using SFG vibrational spectroscopy. For both H{sub 2}O and D{sub 2}O, the only spectral feature was in the range of the free OH or free OD. From the absence of SFG spectra of ice-like structure we conclude that surface hydroxides are formed and no liquid water is present on the surface. Other than model catalysis, gas phase anion photoelectron spectroscopy of the Cl + H{sub 2} van der Waals well, silicon clusters, germanium clusters, aluminum oxide clusters and indium phosphide clusters were studied. The spectra help to map out the neutral potential energy surfaces of the clusters. For aluminum oxide, the structures of the anions and neutrals were explored and for silicon, germanium and indium phosphide the electronic structure of larger clusters was mapped out.

  12. How regulators should use natural gas price forecasts

    SciTech Connect (OSTI)

    Costello, Ken

    2010-08-15

    Natural gas prices are critical to a range of regulatory decisions covering both electric and gas utilities. Natural gas prices are often a crucial variable in electric generation capacity planning and in the benefit-cost relationship for energy-efficiency programs. High natural gas prices can make coal generation the most economical new source, while low prices can make natural gas generation the most economical. (author)

  13. EU Agri-Environmental Payments: Appropriate Policy or Protectionism in Disguise?

    E-Print Network [OSTI]

    Glebe, Thilo

    2005-01-01

    1 Theory of agri-environmental policy Dr. Thilo Glebe EUto look at the agri-environmental policy from a theoreticalto the EU agri- environmental policy I want to ask therefore

  14. CO2 Abatement in the UK Power Sector: Evidence from the EU ETS Trial Period

    E-Print Network [OSTI]

    Ellerman, A. Denny

    2008-01-01

    This paper provides an empirical assessment of CO2 emissions abatement in the UK power sector during the trial period of the EU ETS. Using an econometrically estimated model of fuel switching, it separates the impacts of ...

  15. The EU’s Emissions Trading Scheme: A Proto-Type Global System?

    E-Print Network [OSTI]

    Ellerman, A. Denny

    2008-01-01

    The European Union's Emission Trading Scheme (EU ETS) is the world's first multinational cap-and-trade system for greenhouse gases. As an agreement between sovereign nations with diverse historical, institutional, and ...

  16. The EU’s Emissions Trading Scheme: A Prototype Global System?

    E-Print Network [OSTI]

    Ellerman, A. Denny

    The European Union's Emission Trading Scheme (EU ETS) is the world's first multinational cap-and-trade system for greenhouse gases. As an agreement between sovereign nations with diverse historical, institutional, and ...

  17. Allocation and competitiveness in the EU emissions trading scheme: policy overview

    E-Print Network [OSTI]

    Grubb, Michael; Neuhoff, Karsten

    The European emissions trading scheme (EU ETS) has an efficient and effective market design that risks being undermined by three interrelated problems: the approach to allocation; the absence of a credible commitment to post-2012 continuation...

  18. U.S. and EU Unite to Strengthen Economic Integration and Boost...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    clean energy technology investments." Following the adoption of a joint strategy to fight soaring global illegal trade in counterfeit and pirate goods, U.S. and EU experts are...

  19. Compliance Behavior in the EU-ETS: Cross Border Trading, Banking and Borrowing

    E-Print Network [OSTI]

    Ellerman, A. Denny

    2008-01-01

    This paper exploits a little used data resource within the central registry of the European Union’s Emissions Trading System (EU ETS) to analyze cross border flows of allowances for compliance purposes during the first ...

  20. An EIE/Altener project Co-funded by the EU Commission

    E-Print Network [OSTI]

    the treatment of waste from industries by biomethanation), to in- crease the price for the electricity (the of the biogas production by centralised co-digestion in selected areas of six EU countries. The assessment

  1. Advanced Natural Gas Reciprocating Engines (ARES)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in owning and operating costs thereby improving the economics of distributed power generation using reciprocating gas engines. Market impact: *Phase I technologies...

  2. A NEW GAS TURBINE ENGINE CONCEPT FOR ELECTRICITY

    E-Print Network [OSTI]

    A NEW GAS TURBINE ENGINE CONCEPT FOR ELECTRICITY GENERATION WITH INCREASED EFFICIENCY AND POWER REPORT (FAR) A NEW GAS TURBINE ENGINE CONCEPT FOR ELECTRICITY GENERATION WITH INCREASED EFFICIENCY://www.energy.ca.gov/research/index.html. #12;Page 1 A New Gas Turbine Engine Concept For Electricity Generation With Increased

  3. Fast Generators of Direct Photons

    E-Print Network [OSTI]

    S. M. Kiselev

    2008-11-17

    Three fast generators of direct photons in the central rapidity region of high-energy heavy-ion collisions have been presented The generator of prompt photons is based on a tabulation of $p+p(\\bar p)$ data and binary scaling. Two generators of thermal direct photons, for hot hadron gas (HHG) and quark-gluon plasma (QGP) scenarios, assume the 1+1 Bjorken hydrodynamics. SPS and RHIC data can be fitted better by scenario with QGP. Predictions for the LHC energy have been made. The generators have been realized as macros for the ROOT analysis package.

  4. Eu(III) Complexes of Octadentate 1-Hydroxy-2-pyridinones: Stability and Improved Photophysical Performance

    SciTech Connect (OSTI)

    Moore, Evan G.; D'Aleo, Anthony; Xu, Jide; Raymond, Kenneth N.

    2009-05-29

    The luminescence properties of lanthanoid ions can be dramatically enhanced by coupling them to antenna ligands that absorb light in the UV-visible and then efficiently transfer the energy to the lanthanoid centre. The synthesis and the complexation of Ln{sup III} cations (Ln = Eu, Gd) for a ligand based on four 1-hydroxy-2-pyridinone (1,2-HOPO) chelators appended to a ligand backbone derived by linking two L-lysine units (3LI-bis-LYS) is described. This octadentate Eu{sup III} complex ([Eu(3LI-bis-LYS-1,2-HOPO)]{sup -}) has been evaluated in terms of its thermodynamic stability, UV-visible absorption and luminescence properties. For this complex, the conditional stability constant (pM) is 19.9, which is an order of magnitude higher than diethylenetriaminepentacetic acid at pH = 7.4. This Eu{sup III} complex also shows an almost two-fold increase in its luminescence quantum yield in aqueous solution (pH = 7.4) when compared with other octadentate ligands. Hence, despite a slight decrease of the molar absorption coefficient, a much higher brightness is obtained for [Eu(3LI-bis-LYS-1,2-HOPO)]{sup -}. This overall improvement was achieved by saturating the coordination sphere of the Eu{sup III} cation, yielding an increased metal-centred efficiency by excluding solvent water molecules from the metal's inner sphere.

  5. Management of waste electrical and electronic equipment in two EU countries: A comparison

    SciTech Connect (OSTI)

    Torretta, Vincenzo; Ragazzi, Marco; Istrate, Irina Aura; Rada, Elena Cristina

    2013-01-15

    Highlights: Black-Right-Pointing-Pointer Review on data regarding WEEE management in Italy and in Romania. Black-Right-Pointing-Pointer Problems that countries that will enter in the EU will have to solve facing with the WEEE management. Black-Right-Pointing-Pointer Pilot experiences useful for the awareness campaign of the population. - Abstract: The paper presents some data regarding waste electrical and electronic (WEEE) management in one of the founding countries of the EU, Italy, and in a recent entry into the EU, Romania. The aim of this research was to analyze some problems that countries entering the EU will have to solve with respect to WEEE management. The experiences of Italy and Romania could provide an interesting reference point. The strengths and weaknesses that the two EU countries have encountered can be used in order to give a more rational plan for other countries. In Italy the increase of WEEE collection was achieved in parallel with the increase of the efficiency of selective Municipal Solid Waste collection. In Romania, pilot experiences were useful to increase the awareness of the population. The different interests of the two populations towards recyclable waste led to a different scenario: in Romania all types of WEEE have been collected since its entrance into the EU; in Italy the 'interest' in recycling is typically related to large household appliances, with a secondary role of lighting equipment.

  6. Luminescence characterization of (Ca{sub 1-x}Zn{sub x})Ga{sub 2}S{sub 4}:Eu{sup 2+} phosphors for a white light-emitting diode

    SciTech Connect (OSTI)

    Kim, Yong-Kyu; Cho, Dong-Hee; Jeong, Yong-Kwang; Nah, Min-Kook [Department of Chemistry, Chungnam National University, Daejeon 305-764 (Korea, Republic of)] [Department of Chemistry, Chungnam National University, Daejeon 305-764 (Korea, Republic of); Kim, Kwang-Bok [Kumho Electric Inc., 64-1 Bongmyung-Ri, Namsa-Myun, Youngin, Gyeonggi-Do 449-883 (Korea, Republic of)] [Kumho Electric Inc., 64-1 Bongmyung-Ri, Namsa-Myun, Youngin, Gyeonggi-Do 449-883 (Korea, Republic of); Kang, Jun-Gill, E-mail: jgkang@cnu.ac.kr [Department of Chemistry, Chungnam National University, Daejeon 305-764 (Korea, Republic of)] [Department of Chemistry, Chungnam National University, Daejeon 305-764 (Korea, Republic of)

    2010-08-15

    We investigated the luminescence properties of (Ca{sub 1-x}Zn{sub x})Ga{sub 2}S{sub 4}:Eu{sup 2+} phosphor as a function of Zn{sup 2+} and Eu{sup 2+} concentrations. The luminescence intensity was markedly enhanced by increasing the mole fraction of Zn{sup 2+} at Ca{sup 2+} sites. Lacking any Zn{sup 2+} ions, CaGa{sub 2}S{sub 4}:0.01Eu{sup 2+} converted only 18.1% of the absorbed blue light into luminescence. As the Zn{sup 2+} concentration increased, the quantum yield increased and reached a maximum of 24.4% at x = 0.1. Furthermore, to fabricate the device, the optimized green-yellow (Ca{sub 0.9}Zn{sub 0.1})Ga{sub 2}S{sub 4}:Eu{sup 2+} phosphor was coated with MgO. White light was generated by combining the MgO-coated phosphor and the blue emission from a GaN chip.

  7. Next Generation Radioisotope Generators | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Generators Next Generation Radioisotope Generators Advanced Stirling Radioisotope Generator (ASRG) - The ASRG is currently being developed as a high-efficiency RPS technology...

  8. Comparison of AEO 2007 Natural Gas Price Forecast to NYMEX Futures Prices

    E-Print Network [OSTI]

    Bolinger, Mark; Wiser, Ryan

    2006-01-01

    or other forms of generation whose costs are not tied to thethe levelized cost of gas-fired generation by 0.25¢/kWh (the levelized cost of gas-fired generation (assuming 7,000

  9. Comparison of AEO 2008 Natural Gas Price Forecast to NYMEX Futures Prices

    E-Print Network [OSTI]

    Bolinger, Mark

    2008-01-01

    or other forms of generation whose costs are not tied to thethe levelized cost of gas-fired generation by 0.33¢/kWh (the levelized cost of gas-fired generation (assuming 7,000

  10. Evaluating Policies to Increase the Generation of Electricity from Renewable Energy

    E-Print Network [OSTI]

    Schmalensee, Richard

    Focusing on the U.S. and the E.U., this essay seeks to advance four main propositions. First, the incidence of the short-run costs of programs to subsidize the generation of electricity from renewable sources varies with ...

  11. Gas concentration cells for utilizing energy

    DOE Patents [OSTI]

    Salomon, Robert E. (Philadelphia, PA)

    1987-01-01

    An apparatus and method for utilizing energy, in which the apparatus may be used for generating electricity or as a heat pump. When used as an electrical generator, two gas concentration cells are connected in a closed gas circuit. The first gas concentration cell is heated and generates electricity. The second gas concentration cell repressurizes the gas which travels between the cells. The electrical energy which is generated by the first cell drives the second cell as well as an electrical load. When used as a heat pump, two gas concentration cells are connected in a closed gas circuit. The first cell is supplied with electrical energy from a direct current source and releases heat. The second cell absorbs heat. The apparatus has no moving parts and thus approximates a heat engine.

  12. Gas concentration cells for utilizing energy

    DOE Patents [OSTI]

    Salomon, R.E.

    1987-06-30

    An apparatus and method are disclosed for utilizing energy, in which the apparatus may be used for generating electricity or as a heat pump. When used as an electrical generator, two gas concentration cells are connected in a closed gas circuit. The first gas concentration cell is heated and generates electricity. The second gas concentration cell repressurizes the gas which travels between the cells. The electrical energy which is generated by the first cell drives the second cell as well as an electrical load. When used as a heat pump, two gas concentration cells are connected in a closed gas circuit. The first cell is supplied with electrical energy from a direct current source and releases heat. The second cell absorbs heat. The apparatus has no moving parts and thus approximates a heat engine. 4 figs.

  13. Method for generating surface plasma

    DOE Patents [OSTI]

    Miller, Paul A. (Albuquerque, NM); Aragon, Ben P. (Albuquerque, NM)

    2003-05-27

    A method for generating a discharge plasma which covers a surface of a body in a gas at pressures from 0.01 Torr to atmospheric pressure, by applying a radio frequency power with frequencies between approximately 1 MHz and 10 GHz across a plurality of paired insulated conductors on the surface. At these frequencies, an arc-less, non-filamentary plasma can be generated to affect the drag characteristics of vehicles moving through the gas. The plasma can also be used as a source in plasma reactors for chemical reaction operations.

  14. Assessing the fuel Use and greenhouse gas emissions of future light-duty vehicles in Japan

    E-Print Network [OSTI]

    Nishimura, Eriko

    2011-01-01

    Reducing greenhouse gas (GHG) emissions is of great concern in Japan, as well as elsewhere, such as in the U.S. and EU. More than 20% of GHG emissions in Japan come from the transportation sector, and a more than 70% ...

  15. Power System Modeling of 20percent Wind-Generated Electricity by 2030

    E-Print Network [OSTI]

    Hand, Maureen

    2008-01-01

    fuel price forecast Coal prices follow AEO 2007 referencecoal- and natural gas-based electricity generation analyzed here include decreased natural gas prices,

  16. Gas Mask 

    E-Print Network [OSTI]

    Unknown

    2011-09-05

    The gas industry fostered more efficient energy utilization long before the idea of energy conservation became fashionable. It became apparent in the late '60's that misguided Federal Legislation was discouraging necessary search for new gas...

  17. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  18. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye (Newton, MA)

    1988-01-01

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  19. Properties of molecular beam epitaxy grown Eu{sub x}(transition metal){sub y} films (transition metals: Mn, Cr)

    SciTech Connect (OSTI)

    Balin, K.; Nowak, A.; Gibaud, A.; Szade, J.; Celinski, Z.

    2011-04-01

    The electronic and crystallographic structures, as well as the magnetic properties, of Eu{sub x}(transition metal){sub y} (transition metals: Mn, Cr) thin films grown by molecular beam epitaxy were studied. Relative changes of the Eu/Mn and Eu/Cr ratios derived from the XPS lines, as well as x-ray reflectivity, indicate mixing of the Eu/Mn and Eu/Cr layers. Valency transitions from Eu{sup 2+} to Eu{sup 3+} were observed in both systems for most studied stoichiometries. A transition to a magnetically ordered phase was observed at 15 K, 40 K, and 62 K for selected films in the Eu-Mn system, and at 50 K for the film with a Eu/Cr ratio of 0.5.

  20. Chemical Feature of Eu abundance in the Draco dwarf spheroidal galaxy

    E-Print Network [OSTI]

    Tsujimoto, Takuji; Shigeyama, Toshikazu; Aoki, Wako

    2015-01-01

    Chemical abundance of r-process elements in nearby dwarf spheroidal (dSph) galaxies is a powerful tool to probe the site of r-process since their small-mass scale can sort out individual events producing r-process elements. A merger of binary neutron stars is a promising candidate of this site. In faint, or less massive dSph galaxies such as the Draco, a few binary neutron star mergers are expected to have occurred at most over the whole past. We have measured chemical abundances including Eu and Ba of three red giants in the Draco dSph by Subaru/HDS observation. The Eu detection for one star with [Fe/H]=-1.45 confirms a broadly constant [Eu/H] of ~-1.3 for stars with [Fe/H]>-2. This feature is shared by other dSphs with similar masses, i.e., the Sculptor and the Carina, and suggests that neutron star merger is the origin of r-process elements in terms of its rarity. In addition, two very metal-poor stars with [Fe/H]=-2.12 and -2.51 are found to exhibit very low Eu abundances such as [Eu/H]<-2 with an impl...

  1. Thermoelectric generator cooling system and method of control

    DOE Patents [OSTI]

    Prior, Gregory P; Meisner, Gregory P; Glassford, Daniel B

    2012-10-16

    An apparatus is provided that includes a thermoelectric generator and an exhaust gas system operatively connected to the thermoelectric generator to heat a portion of the thermoelectric generator with exhaust gas flow through the thermoelectric generator. A coolant system is operatively connected to the thermoelectric generator to cool another portion of the thermoelectric generator with coolant flow through the thermoelectric generator. At least one valve is controllable to cause the coolant flow through the thermoelectric generator in a direction that opposes a direction of the exhaust gas flow under a first set of operating conditions and to cause the coolant flow through the thermoelectric generator in the direction of exhaust gas flow under a second set of operating conditions.

  2. Trends in packaged steam generators

    SciTech Connect (OSTI)

    Ganapathy, V. [ABCO Industries, Abilene, TX (United States)

    1996-09-01

    Oil and gas-fired packaged steam generators are used in many industrial plants. They generate saturated or superheated steam up to 250,000 lb/hr, 1000 psig, and 950 F. They may be used for continuous steam generation or as standby boilers in cogeneration systems. Numerous variables affect the design of this equipment. A few important considerations should be addressed at an early point by the plant engineer specifying or evaluating equipment options. These considerations include trends such as customized designs that minimize operating costs and ensure emissions regulations are met. The paper discusses efficiency considerations first.

  3. North Dakota: EERE-Funded Project Recycles Energy, Generates...

    Office of Environmental Management (EM)

    of its Flare Gas Micro-turbine. The microturbine pilot project places generators at oil production well sites to transform wellhead flare gas into high-quality, three-phase...

  4. NuclearHydrogen Oil and gas

    E-Print Network [OSTI]

    Birmingham, University of

    Policy NuclearHydrogen Transport Education Oil and gas Distribution Society Supply Ecology Demand Hydrogen 08 Policy and society 10 Environment 11 Transport 12 Manufacturing 14 Oil and gas 15 Nuclear 16 and infrastructure, and broaden our methods of generation. Our declining reserves of oil and gas must be repla

  5. North American Natural Gas Markets

    SciTech Connect (OSTI)

    Not Available

    1989-02-01

    This report summarizes die research by an Energy Modeling Forum working group on the evolution of the North American natural gas markets between now and 2010. The group's findings are based partly on the results of a set of economic models of the natural gas industry that were run for four scenarios representing significantly different conditions: two oil price scenarios (upper and lower), a smaller total US resource base (low US resource case), and increased potential gas demand for electric generation (high US demand case). Several issues, such as the direction of regulatory policy and the size of the gas resource base, were analyzed separately without the use of models.

  6. Hardware model of a shipboard generator

    E-Print Network [OSTI]

    Elkins, Gregory L. (Gregory Lewis)

    2009-01-01

    A hardware model of the Gas Turbine Generator (GTG) in use on the US Navy's DDG-51 Class Destroyer is constructed for use as a lab apparatus at the Massachusetts Institute of Technology's Laboratory for Electromagnetic and ...

  7. Photon generator

    DOE Patents [OSTI]

    Srinivasan-Rao, Triveni (Shoreham, NY)

    2002-01-01

    A photon generator includes an electron gun for emitting an electron beam, a laser for emitting a laser beam, and an interaction ring wherein the laser beam repetitively collides with the electron beam for emitting a high energy photon beam therefrom in the exemplary form of x-rays. The interaction ring is a closed loop, sized and configured for circulating the electron beam with a period substantially equal to the period of the laser beam pulses for effecting repetitive collisions.

  8. Electric generator

    DOE Patents [OSTI]

    Foster, Jr., John S. (Pleasanton, CA); Wilson, James R. (Livermore, CA); McDonald, Jr., Charles A. (Danville, CA)

    1983-01-01

    1. In an electrical energy generator, the combination comprising a first elongated annular electrical current conductor having at least one bare surface extending longitudinally and facing radially inwards therein, a second elongated annular electrical current conductor disposed coaxially within said first conductor and having an outer bare surface area extending longitudinally and facing said bare surface of said first conductor, the contiguous coaxial areas of said first and second conductors defining an inductive element, means for applying an electrical current to at least one of said conductors for generating a magnetic field encompassing said inductive element, and explosive charge means disposed concentrically with respect to said conductors including at least the area of said inductive element, said explosive charge means including means disposed to initiate an explosive wave front in said explosive advancing longitudinally along said inductive element, said wave front being effective to progressively deform at least one of said conductors to bring said bare surfaces thereof into electrically conductive contact to progressively reduce the inductance of the inductive element defined by said conductors and transferring explosive energy to said magnetic field effective to generate an electrical potential between undeformed portions of said conductors ahead of said explosive wave front.

  9. 3rd Generation SCR System Using Solid Ammonia Storage and Direct...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing 3rd Generation SCR System Using Solid Ammonia Storage and Direct Gas Dosing SCR system provides direct...

  10. Flammable gas project topical report

    SciTech Connect (OSTI)

    Johnson, G.D.

    1997-01-29

    The flammable gas safety issue was recognized in 1990 with the declaration of an unreviewed safety question (USQ) by the U. S. Department of Energy as a result of the behavior of the Hanford Site high-level waste tank 241-SY-101. This tank exhibited episodic releases of flammable gas that on a couple of occasions exceeded the lower flammability limit of hydrogen in air. Over the past six years there has been a considerable amount of knowledge gained about the chemical and physical processes that govern the behavior of tank 241-SY-1 01 and other tanks associated with the flammable gas safety issue. This report was prepared to provide an overview of that knowledge and to provide a description of the key information still needed to resolve the issue. Items covered by this report include summaries of the understanding of gas generation, retention and release mechanisms, the composition and flammability behavior of the gas mixture, the amounts of stored gas, and estimated gas release fractions for spontaneous releases. `Me report also discusses methods being developed for evaluating the 177 tanks at the Hanford Site and the problems associated with these methods. Means for measuring the gases emitted from the waste are described along with laboratory experiments designed to gain more information regarding rates of generation, species of gases emitted and modes of gas storage and release. Finally, the process for closing the USQ is outlined as are the information requirements to understand and resolve the flammable gas issue.

  11. Electric Power Generation Using Geothermal Fluid Coproduced from...

    Open Energy Info (EERE)

    Electric Power Generation Using Geothermal Fluid Coproduced from Oil andor Gas Wells Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Electric...

  12. Electric Power Generation Systems | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electric Power Generation Systems Coal gasification-based power plants Coal combustion-based power plants Natural gas-fueled power plants Turbines Fuel cells Existing power plants...

  13. North Dakota: EERE-Funded Project Recycles Energy, Generates...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development grant, funded by EERE, to demonstrate the commercial viability of its Flare Gas Micro-turbine. The microturbine pilot project places generators at oil production well...

  14. Table 2. Ten Largest Plants by Generation Capacity, 2013

    U.S. Energy Information Administration (EIA) Indexed Site

    General Electric Co",487 9,"Hermiston Generating Plant","Natural gas","Hermiston Generating Co LP",464 10,"Biglow Canyon Wind Farm","Wind","Portland General Electric Co",449....

  15. Gas separating

    DOE Patents [OSTI]

    Gollan, A.Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  16. Gas separating

    DOE Patents [OSTI]

    Gollan, A.

    1988-03-29

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  17. Preliminary Estimates of Combined Heat and Power Greenhouse Gas Abatement Potential for California in 2020

    E-Print Network [OSTI]

    Firestone, Ryan; Ling, Frank; Marnay, Chris; Hamachi LaCommare, Kristina

    2007-01-01

    natural-gas- fired combined cycle generation, and the othernatural-gas-fired combined cycle plants. This assumptionplants were efficient combined cycle plants. The four

  18. Antje Wittenberg, Directorate General for Enterprise and Industry, The EU

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u t yWaste |4 2014 Annual PlanningLaboratory |

  19. Discharge cell for ozone generator

    DOE Patents [OSTI]

    Nakatsuka, Suguru (Amagasaki, JP)

    2000-01-01

    A discharge cell for use in an ozone generator is provided which can suppress a time-related reduction in ozone concentration without adding a catalytic gas such as nitrogen gas to oxygen gas as a raw material gas. The discharge cell includes a pair of electrodes disposed in an opposed spaced relation with a discharge space therebetween, and a dielectric layer of a three-layer structure consisting of three ceramic dielectric layers successively stacked on at least one of the electrodes, wherein a first dielectric layer of the dielectric layer contacting the one electrode contains no titanium dioxide, wherein a second dielectric layer of the dielectric layer exposed to the discharge space contains titanium dioxide in a metal element ratio of not lower than 10 wt %.

  20. Power System Modeling of 20percent Wind-Generated Electricity by 2030

    E-Print Network [OSTI]

    Hand, Maureen

    2008-01-01

    pulverized coal plants, combined cycle natural gas plants,natural gas plants, and combined cycle natural gas plants.generated largely from combined-cycle Capacity (GW) yd r as

  1. Les dterminants du prix du carbone sur le march europen des quotas Carbon price drivers in the EU Emissions Trading Scheme

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    in the EU Emissions Trading Scheme Emilie Alberola1 et Julien Chevallier2 Résumé: L'article examine le prix des quotas durant la première période (2005-2007) de l'European Union Emissions Trading Scheme (EU

  2. Personalisation and Recommender Systems in Digital Joint NSF-EU DELOS Working Group Report

    E-Print Network [OSTI]

    Callan, Jamie

    Personalisation and Recommender Systems in Digital Libraries Joint NSF-EU DELOS Working Group, Ireland Micheline Beaulieu, University of Sheffield, UK Pia Borlund, Royal School of Library, University of Toronto, Canada Digital libraries are collections of information that have associated services

  3. -News Home Help Chirac defends planned EU arms sales to China to nervous Japan

    E-Print Network [OSTI]

    of sensitive weapons or technology. news web sites Chirac, the prime proponent of lifting the 16-year-old EU arms or technology to China as they are subject to rules which cannot be broken," Chirac said. "Hence had seen double-digit growth for more than 10 years. As for Japan, the defense spending has been

  4. Carbon Prices during the EU ETS Phase II: Dynamics and Volume Analysis

    E-Print Network [OSTI]

    Boyer, Edmond

    Université Paris Dauphine Abstract The European Union Emissions Trading Scheme (EU ETS) is the largest emissions trading scheme to date. This article summarizes the principle elements behind the trading system of reducing CO2 emissions and achieving the Kyoto Protocol target. The European Union Emissions Trading Scheme

  5. EU:France, UK,etc. East Asia: Japan, China,etc.

    E-Print Network [OSTI]

    : The advanced T-lean fusion fuel reactor US HIF Science Virtual National Lab.(LBNL, LLNL,PPPL) has been Heating Heated plasma image SNL-Z project #12;Fast Ignition opens a new rout to compact IF Reactor 1983EU:France, UK,etc. East Asia: Japan, China,etc. US: LLNL, SNL, U. Rochester Inertial Fusion Power

  6. Hydroxyl-Quenching Effects on the Photoluminescence Properties of SnO2:Eu3+ Nanoparticles

    E-Print Network [OSTI]

    Park, Byungwoo

    Hydroxyl-Quenching Effects on the Photoluminescence Properties of SnO2:Eu3+ Nanoparticles Taeho: January 20, 2007 The effects of hydroxyl quenching were examined on the photoluminescence properties of Sn, and this behavior with XPS confirmed the hydroxyl-quenching effect. Introduction For display devices, such as plasma

  7. Preprint 24th EU PVSEC, 2009, Hamburg FITTING OF LATERAL RESISTANCES IN SILICON SOLAR CELLS

    E-Print Network [OSTI]

    Junk, Michael

    Preprint 24th EU PVSEC, 2009, Hamburg FITTING OF LATERAL RESISTANCES IN SILICON SOLAR CELLS cell from electroluminescence (EL) is introduced. A two-dimensional model of the solar cell screen printed monocrystalline silicon solar cell are shown and the influence of lateral diffusion

  8. -News Home Help EU again warns could mount nuclear project without Japan

    E-Print Network [OSTI]

    revealed. news web sites The European Commission ( - ) is set to propose that negotiating strategy next the International Thermonuclear Experimental Reactor (ITER). news web sites Talks in Vienna on Tuesday made some support the Japanese bid -- and Russia and China, which back the EU bid. news web sites Ambassadors from

  9. An EIE/Altener project Co-funded by the EU Commission

    E-Print Network [OSTI]

    and energy aspects of the biogas production by centralised co-digestion in selected areas of six EU countries. The assessment will provide incentives for the implementation of biogas systems in those areas and will help-technical barriers for the implementation and development of biogas from centralised co-digestion in the studied

  10. An EIE/Altener project Co-funded by the EU Commission

    E-Print Network [OSTI]

    , environmental and energy aspects of the biogas production by centralised co-digestion in selected areas of six EU countries. The assessment will provide incentives for the implementation of biogas systems for the implementation and development of biogas from centralised co-digestion in the studied areas and to propose some

  11. US, EU Consumption Driving Chinese Imports of Illegal Wood from Around the World

    E-Print Network [OSTI]

    US, EU Consumption Driving Chinese Imports of Illegal Wood from Around the World Chinese Government the world's leading importer of wood from tropical, developing countries. China has captured one, and environmental destruction and poverty in forest areas around the world. It also presents a number

  12. The knowledge economy in Europe A report prepared for the 2007 EU Spring Council

    E-Print Network [OSTI]

    Chen-Burger, Yun-Heh (Jessica)

    The knowledge economy in Europe A report prepared for the 2007 EU Spring Council Prepared by Ian. Knowledge industry employment in Europe 6 4. Moving towards a knowledge based economy in Europe 7 5 10 8. Investing in knowledge 11 9. Next steps 23 Sponsors for the knowledge economy programme include

  13. -News Home Help EU offers 'sweetener' to Japan to let France host nuclear project

    E-Print Network [OSTI]

    -News Home Help EU offers 'sweetener' to Japan to let France host nuclear project Wed Nov 10, 9:45 AM ET BRUSSELS (AFP) - The European Union ( - ) has offered Japan a "sweetener" to allow France think we have made reasonable offers," European Commission ( - ) spokesman Fabio Fabbi told reporters

  14. EU to build experimental fusion reactor Associated Press, THE JERUSALEM POST Sep 25, 2006

    E-Print Network [OSTI]

    EU to build experimental fusion reactor Associated Press, THE JERUSALEM POST Sep 25, 2006 European Union nations on Monday endorsed a pact to build an experimental fusion reactor with the aim, China, Japan, South Korea and Russia - also aim to ratify the International Thermonuclear Experimental

  15. Influence of high magnetic field on the luminescence of Eu{sup 3+}-doped glass ceramics

    SciTech Connect (OSTI)

    Jiang, Wei; Chen, Weibo; Chen, Ping; Xu, Beibei; Zheng, Shuhong; Guo, Qiangbing; Liu, Xiaofeng E-mail: qjr@zju.edu.cn; Zhang, Junpei; Han, Junbo; Qiu, Jianrong E-mail: qjr@zju.edu.cn

    2014-09-28

    Rare earth (RE) doped materials have been widely exploited as the intriguing electronic configuration of RE ions offers diverse functionalities from optics to magnetism. However, the coupling of magnetism with photoluminescence (PL) in such materials has been rarely reported in spite of its fundamental significance. In the present paper, the effect of high pulsed magnetic field on the photoluminescence intensity of Eu{sup 3+}-doped nano-glass-ceramics has been investigated. In our experiment, Eu-doped oxyfluoride glass and glass ceramic were prepared by the conventional melt-quenching process and controlled heat treatment. The results demonstrate that the integrated PL intensity of Eu{sup 3+} decreases with the enhancement of magnetic field, which can be interpreted in terms of cooperation effect of Zeeman splitting and magnetic field induced change in site symmetry. Furthermore, as a result of Zeeman splitting, both blue and red shift in the emission peaks of Eu{sup 3+} can be observed, and this effect becomes more prominent with the increase of magnetic field. Possible mechanisms associated with the observed magneto-optical behaviors are suggested. The results of the present paper may open a new gate for modulation of luminescence by magnetic field and remote optical detection of magnetic field.

  16. An EIE/Altener project Co-funded by the EU Commission

    E-Print Network [OSTI]

    doubled the electricity price (a claim issued also from this project), which has dramatically changedPROBIOGAS An EIE/Altener project Co-funded by the EU Commission National Assessment Report analysis of the externalities implicated in the agroindustrial wastes digestion carried out in this project

  17. An EIE/Altener project Co-funded by the EU Commission

    E-Print Network [OSTI]

    · a low electricity price (7.2c/kw sales price (economic assessment) and 3.36c/kw 20year pro- jectedPROBIOGAS An EIE/Altener project Co-funded by the EU Commission National Assessment Report CAD situation. However, because the situation is not a live project, but only a potential one

  18. Promoting policy development and an EU Action Plan for the Woody Energy Crops Sector

    E-Print Network [OSTI]

    Promoting policy development and an EU Action Plan for the Woody Energy Crops Sector Kevin Lindegaard, Crops for Energy Ltd #12;What are short rotation plantations (SRPs)? · Woody crops grown at close, Germany, Poland, Belgium Industry Public bodies Research Institutions Joint Action Plan Common Strategies

  19. GRAPHENE FLAGSHIP, 28 Jan 2013 Graphene appointed an EU Future Emerging Technology flagship

    E-Print Network [OSTI]

    GRAPHENE FLAGSHIP, 28 Jan 2013 Graphene appointed an EU Future Emerging Technology flagship The European Commission has chosen Graphene as one of Europe's first 10-year, 1,000 million euro FET flagships. The mission of Graphene is to take graphene and related layered materials from academic laboratories

  20. GENERATION OF ELECTRIC Hesham E. Shaalan

    E-Print Network [OSTI]

    Powell, Warren B.

    of generating systems. These include steam cycles, combined steam- and gas-turbine cycles (systems where the hot a steam turbine), and a number of advanced technology processes such as fuel cells (i.e., systems having exhaust gases are delivered to a heat-recovery steam generator to produce steam that is used to drive

  1. THE EFFECTS OF FLAME TEMPERATURE, PARTICLE SIZE AND EUROPIUM DOPING CONCENTRATION ON THE PROPERTIES OF Y2O3:EU PARTICLES FORMED IN A FLAME AEROSOL PROCESS 

    E-Print Network [OSTI]

    Yim, Hoon

    2010-07-14

    Y2O3:Eu particles are phosphors that have found wide applications. Flamesynthesized Y2O3:Eu particles may have either the cubic or the monoclinic structure. The effects of particle size and Eu doping concentration on crystal structure...

  2. Generator configuration for solid oxide fuel cells

    DOE Patents [OSTI]

    Reichner, Philip (Plum Boro, PA)

    1989-01-01

    Disclosed are improvements in a solid oxide fuel cell generator 1 having a multiplicity of electrically connected solid oxide fuel cells 2, where a fuel gas is passed over one side of said cells and an oxygen-containing gas is passed over the other side of said cells resulting in the generation of heat and electricity. The improvements comprise arranging the cells in the configuration of a circle, a spiral, or folded rows within a cylindrical generator, and modifying the flow rate, oxygen concentration, and/or temperature of the oxygen-containing gases that flow to those cells that are at the periphery of the generator relative to those cells that are at the center of the generator. In these ways, a more uniform temperature is obtained throughout the generator.

  3. Flammable gas program topical report

    SciTech Connect (OSTI)

    Johnson, G.D.

    1996-10-30

    The major emphasis of this report is to describe what has been learned about the generation, retention, and release of flammable gas mixtures in high-level waste tanks. A brief overview of efforts to characterize the gas composition will be provided. The report also discusses what needs to be learned about the phenomena, how the Unreviewed Safety Question will be closed, and the approach for removing tanks from the Watch List.

  4. Statkraft is Europe's largest generator of renewable energy and is the leading power company in Norway. The company owns, produces and develops hydropower, wind power, gas-fired power and

    E-Print Network [OSTI]

    Morik, Katharina

    Statkraft is Europe's largest generator of renewable energy and is the leading power company countries. For our office in Düsseldorf we are currently looking to hire a System Manager Renewable Energy. Share our passion for renewable energy and be a part of tomorrow's energy world. Your department

  5. Gas permeable electrode for electrochemical system

    DOE Patents [OSTI]

    Ludwig, Frank A. (Rancho Palos Verdes, CA); Townsend, Carl W. (Los Angeles, CA)

    1989-01-01

    An electrode apparatus adapted for use in electrochemical systems having an anode compartment and a cathode compartment in which gas and ions are produced and consumed in the compartments during generation of electrical current. The electrode apparatus includes a membrane for separating the anode compartment from the cathode compartment wherein the membrane is permeable to both ions and gas. The cathode and anode for the assembly are provided on opposite sides of the membrane. During use of the membrane-electrode apparatus in electrochemical cells, the gas and ions generated at the cathode or anode migrate through the membrane to provide efficient transfer of gas and ions between the anode and cathode compartments.

  6. DRAFT DRAFT Electricity and Natural Gas Sector Description

    E-Print Network [OSTI]

    DRAFT DRAFT Electricity and Natural Gas Sector Description For Public Distribution AB 32 Scoping of electricity and natural gas; including electricity generation, combined heat and power, and electricity and natural gas end uses for residential and commercial purposes. Use of electricity and/or gas for industrial

  7. Natural gas strategic plan and program crosscut plans

    SciTech Connect (OSTI)

    NONE

    1995-06-01

    The natural gas strategic plan recognizes the challenges and opportunities facing increased U.S. natural gas use. Focus areas of research include natural gas supply, delivery, and storage, power generation, industrial, residential and commercial, natural gas vehicles, and the environment. Historical aspects, mission, situation analysis, technology trends, strategic issues, performance indicators, technology program overviews, and forecasting in the above areas are described.

  8. Hot-gas conditioning of biomass derived synthesis gas

    SciTech Connect (OSTI)

    Paisley, M.A.; Litt, R.D.

    1993-12-31

    Battelle has tested selected catalysts to evaluate the potential for hot-gas conditioning of biomass gasifier product gas to modify the product gas to produce a gas suitable for methanol synthesis. The Battelle Process Research Unit (PRU) gasifier was utilized as a source of a stable supply of product gas that contained all of the trace constituents that might be present in a commercial scale gasification system. One goal of alternate fuel generation with renewable biomass fuels is the production of a liquid transportation fuel such as methanol. The hot-gas conditioning tests run were planned to evaluate commercial catalysts that would crack hydrocarbons and provide water gas shift activity to adjust the product gas composition for methanol synthesis. During the test program, a novel, low cost catalyst, was identified that showed high levels of activity and stability. The composition of this catalyst is such that it has the potential to be a disposable catalyst and is free from hazardous materials. The initial tests with this catalyst showed high levels of water gas shift activity superior to, and hydrocarbon cracking activity nearly as high as, a commercial cracking catalyst tested.

  9. Vapor generation methods for explosives detection research

    SciTech Connect (OSTI)

    Grate, Jay W.; Ewing, Robert G.; Atkinson, David A.

    2012-12-01

    The generation of calibrated vapor samples of explosives compounds remains a challenge due to the low vapor pressures of the explosives, adsorption of explosives on container and tubing walls, and the requirement to manage (typically) multiple temperature zones as the vapor is generated, diluted, and delivered. Methods that have been described to generate vapors can be classified as continuous or pulsed flow vapor generators. Vapor sources for continuous flow generators are typically explosives compounds supported on a solid support, or compounds contained in a permeation or diffusion device. Sources are held at elevated isothermal temperatures. Similar sources can be used for pulsed vapor generators; however, pulsed systems may also use injection of solutions onto heated surfaces with generation of both solvent and explosives vapors, transient peaks from a gas chromatograph, or vapors generated by s programmed thermal desorption. This article reviews vapor generator approaches with emphasis on the method of generating the vapors and on practical aspects of vapor dilution and handling. In addition, a gas chromatographic system with two ovens that is configurable with up to four heating ropes is proposed that could serve as a single integrated platform for explosives vapor generation and device testing. Issues related to standards, calibration, and safety are also discussed.

  10. Methodology for flammable gas evaluations

    SciTech Connect (OSTI)

    Hopkins, J.D., Westinghouse Hanford

    1996-06-12

    There are 177 radioactive waste storage tanks at the Hanford Site. The waste generates flammable gases. The waste releases gas continuously, but in some tanks the waste has shown a tendency to trap these flammable gases. When enough gas is trapped in a tank`s waste matrix, it may be released in a way that renders part or all of the tank atmosphere flammable for a period of time. Tanks must be evaluated against previously defined criteria to determine whether they can present a flammable gas hazard. This document presents the methodology for evaluating tanks in two areas of concern in the tank headspace:steady-state flammable-gas concentration resulting from continuous release, and concentration resulting from an episodic gas release.

  11. Magnetic ordering of divalent europium in double perovskites Eu{sub 2}LnTaO{sub 6} (Ln=rare earths)

    SciTech Connect (OSTI)

    Misawa, Yoshitaka; Doi, Yoshihiro [Division of Chemistry, Hokkaido University, Sapporo 060-0810 (Japan); Hinatsu, Yukio, E-mail: hinatsu@sci.hokudai.ac.jp [Division of Chemistry, Hokkaido University, Sapporo 060-0810 (Japan)

    2011-06-15

    Structures and magnetic properties of double perovskite-type oxides Eu{sub 2}LnTaO{sub 6} (Ln=Eu, Dy-Lu) were investigated. These compounds adopt a distorted double perovskite structure with space group P2{sub 1}/n. Magnetic susceptibility, specific heat, and {sup 151}Eu Moessbauer spectrum measurements show that the Eu{sup 2+} ions at the 12-coordinate sites of the perovskite structure are antiferromagnetically ordered at {approx}4 K, and that Ln{sup 3+} ions at the 6-coordinate site are in the paramagnetic state down to 1.8 K. - Graphical abstract: Magnetic properties of double perovskite-type oxides Eu{sub 2}LnTaO{sub 6} (Ln=Eu, Dy-Lu) were investigated. Magnetic susceptibility, specific heat, and {sup 151}Eu Moessbauer spectrum measurements show that the Eu{sup 2+} ions at the 12-coordinate sites of the perovskite structure are antiferromagnetically ordered at {approx}4 K. Highlights: > Crystal structures of double perovskites Eu{sub 2}LnTaO{sub 6} (Ln=rare earth) were determined. > We found that these compounds show an antiferromagnetic ordering at {approx}4 K. > The magnetic ordering is due to the interactions of Eu{sup 2+} ions. > It was elucidated by specific heat and {sup 151}Eu Moessbauer spectrum measurements.

  12. Modeling and Control of Co-generation Power Plants: A Hybrid System Approach

    E-Print Network [OSTI]

    Ferrari-Trecate, Giancarlo

    of turning on/off the gas and steam turbine, the operat- ing constraints (minimum up and down times and produces electric power through the expansion of the gas in the gas turbine; the steam cycle is supplied with the output ex- haust gas from the gas turbine and generates both electricity and steam for the industrial

  13. Gas hydrates

    SciTech Connect (OSTI)

    Not Available

    1985-04-01

    There is a definite need for the US government to provide leadership for research in gas hydrates and to coordinate its activities with academia, industry, private groups, federal agencies, and their foreign counterparts. In response to this need, the DOE Morgantown Energy Technology Center implemented a gas hydrates R and D program. Understanding the resource will be achieved through: assessment of current technology; characterization of gas hydrate geology and reservoir engineering; and development of diagnostic tools and methods. Research to date has focused on geology. As work progressed, areas where gas hydrates are likely to occur were identified, and specific high potential areas were targeted for future detailed investigation. Initial research activities involved the development of the Geologic Analysis System (GAS); which will provide, through approximately 30 software packages, the capability to manipulate and correlate several types of geologic and petroleum data into maps, graphics, and reports. Preliminary mapping of hydrate prospects for the Alaskan North Slope is underway. Geological research includes physical system characterization which focuses on creating synthetic methane hydrates and developing synthetic hydrate cores using tetrahydrofuran, consolidated rock cores, frost base mixtures, water/ice base mixtures, and water base mixtures. Laboratory work produced measurements of the sonic velocity and electrical resistivity of these synthetic hydrates. During 1983, a sample from a natural hydrate core recovered from the Pacific coast of Guatemala was tested for these properties by METC. More recently, a natural hydrate sample from the Gulf of Mexico was also acquired and testing of this sample is currently underway. In addition to the development of GAS, modeling and systems analysis work focused on the development of conceptual gas hydrate production models. 16 figs., 6 tabs.

  14. Study and Development of Anti-Islanding Control for Synchronous Machine-Based Distributed Generators: November 2001--March 2004

    SciTech Connect (OSTI)

    Ye, Z.

    2006-03-01

    This report summarizes the study and development of new active anti-islanding control schemes for synchronous machine-based distributed generators, including engine generators and gas turbines.

  15. EU promises new biofuel rules won't harm the environment http://www.pr-inside.com/eu-promises-new-biofuel-rules-won-t-r385258.htm 1 of 2 1/16/2008 12:32 PM

    E-Print Network [OSTI]

    -inside Special Pages Gold Medal Mortgage Get the latest news with our RSS feed More information Finance EU, rapeseed or sugar cane, to replace polluting oil _ aiming also to cut down on expensive energy imports

  16. Demonstration of a Low-NOx Heavy-Duty Natural Gas Engine

    SciTech Connect (OSTI)

    Not Available

    2004-02-01

    Results of a Next Generation Natural Gas Vehicle engine research project: A Caterpillar C-12 natural gas engine with Clean Air Power Dual-Fuel technology and exhaust gas recirculation demonstrated low NOx and PM emissions.

  17. Synthesis, crystal structure and magnetic properties of Li{sub 0.44}Eu{sub 3}[B{sub 3}N{sub 6}

    SciTech Connect (OSTI)

    Kokal, I.; Aydemir, U.; Prots, Yu.; Förster, T.; Sichelschmidt, J.; Yahyaoglu, M.; Auffermann, G.; Schnelle, W.; Schappacher, F.; Pöttgen, R.; Somer, M.

    2014-02-15

    Li{sub 0.44}Eu{sub 3}[B{sub 3}N{sub 6}] was synthesized from the metathesis reaction of Li{sub 3}[BN{sub 2}] and EuCl{sub 3} at 850 °C. Li{sub 0.44}Eu{sub 3}[B{sub 3}N{sub 6}] crystallizes in the trigonal space group R3{sup ¯}c (No. 167) with a=12.0225(2) Å, c=6.8556(2) Å and Z=6. In the crystal structure, isolated, planar cyclic [B{sub 3}N{sub 6}]{sup 9?} units are charge-balanced by the mixed-valence Eu{sup 3+}/Eu{sup 2+} and Li{sup +} cations. Li{sup +} occupies partially (44%) the Wyckoff site 6b and is sandwiched between the [B{sub 3}N{sub 6}]{sup 9?} anions. Mössbauer spectroscopy results show the resonance lines of Eu{sup 2+} and Eu{sup 3+}, respectively, indicating the heterogeneous mixed valency of the Eu atoms. X-Band ESR investigations between 5 and 300 K reveal an intense signal over the whole temperature range originating from Eu{sup 2+}. Magnetic susceptibility measurements indicate a Curie–Weiss behavior with an experimental effective magnetic moment of ?{sub eff}=8.28 ?{sub B} per formula unit. - Graphical abstract: Single crystals of Li{sub 0.44}Eu{sub 3}[B{sub 3}N{sub 6}] was obtained from the metathesis reaction of Li{sub 3}[BN{sub 2}] and EuCl{sub 3.}{sup 151}Eu Mössbauer, ESR and magnetic susceptibility measurements reveal the heterogeneous mixed valency of the Eu atoms. Display Omitted - Highlights: • Single crystals of Li{sub 0.44}Eu{sub 3}[B{sub 3}N{sub 6}] was obtained from the metathesis reaction of Li{sub 3}[BN{sub 2}] and EuCl{sub 3} at 850 °C. • Crystal structure is built up by isolated, planar cyclic [B{sub 3}N{sub 6}]{sup 9?} units which are surrounded by mixed valence Eu{sup 3+}/Eu{sup 2+}. • Li{sup +} occupies partially (44%) the site 6b and is sandwiched between the [B{sub 3}N{sub 6}]{sup 9?} anions. • The {sup 151}Eu Mössbauer spectroscopy, electron spin resonance spectroscopy and magnetic susceptibility measurements confirm the heterogeneous mixed valency of Eu.

  18. A Portable Expert System for Gas Turbine Maintenance 

    E-Print Network [OSTI]

    Quentin, G. H.

    1989-01-01

    Combustion turbines for electric power generation and industrial applications have steadily increased in size, efficiency and prominence. The newest class of gas turbine-generators coming into service will deliver 150 megawatts, with turbine inlet...

  19. Saudi Aramco Gas Operations Energy Efficiency Program 

    E-Print Network [OSTI]

    Al-Dossary, F. S.

    2012-01-01

    Saudi Aramco Gas Operations (GO) created energy efficiency strategies for its 5-year business plan (2011-2015), supported by a unique energy efficiency program, to reduce GO energy intensity by 26% by 2015. The program generated an energy savings...

  20. Photon Physics and Plasma Research, WILGA 2012; EuCARD Sessions

    E-Print Network [OSTI]

    Romaniuk, R S

    2012-01-01

    Wilga Sessions on HEP experiments, astroparticle physica and accelerator technology were organized under the umbrella of the EU FP7 Project EuCARD – European Coordination for Accelerator Research and Development. This paper is the third part (out of five) of the research survey of WILGA Symposium work, May 2012 Edition, concerned with Photon Physics and Plasma Research. It presents a digest of chosen technical work results shown by young researchers from different technical universities from this country during the Jubilee XXXth SPIE-IEEE Wilga 2012, May Edition, symposium on Photonics and Web Engineering. Topical tracks of the symposium embraced, among others, nanomaterials and nanotechnologies for photonics, sensory and nonlinear optical fibers, object oriented design of hardware, photonic metrology, optoelectronics and photonics applications, photonics-electronics co-design, optoelectronic and electronic systems for astronomy and high energy physics experiments, JET tokamak and pi-of-the sky experiments ...

  1. Brilliant Sm, Eu, Tb and Dy chiral lanthanide complexes withstrong circularly polarized luminescence

    SciTech Connect (OSTI)

    Petoud, Stephane; Muller, Gilles; Moore, Evan G.; Xu, Jide; Sokolnicki, Jurek; Riehl, James P.; Le, Uyen; Cohen, Seth M.; Raymond,Kenneth N.

    2006-07-10

    The synthesis, characterization and luminescent behavior of trivalent Sm, Eu, Dy and Tb complexes of two enantiomeric, octadentate, chiral, 2-hydroxyisophthalamide ligands are reported. These complexes are highly luminescent in solution. Functionalization of the achiral parent ligand with a chiral 1-phenylethylamine substituent on the open face of the complex in close proximity to the metal center yields complexes with strong circularly polarized luminescence (CPL) activity. This appears to be the first example of a system utilizing the same ligand architecture to sensitize four different lanthanide cations and display CPL activity. The luminescence dissymmetry factor, g{sub lum}, recorded for the Eu(III) complex is one of the highest values reported, and this is the first time the CPL effect has been demonstrated for a Sm(III) complex with a chiral ligand. The combination of high luminescence intensity with CPL activity should enable new bioanalytical applications of macromolecules in chiral environments.

  2. Generators, Recursion, and Fractals 1 Generators

    E-Print Network [OSTI]

    Verschelde, Jan

    Generators, Recursion, and Fractals 1 Generators computing a list of Fibonacci numbers defining a generator with yield putting yield in the function fib 2 Recursive Functions computing factorials, 24 April 2015 Intro to Computer Science (MCS 260) generators and recursion L-41 24 April 2015 1 / 36

  3. Over-Allocation or Abatement? A Preliminary Analysis of the EU Emissions Trading Scheme Based on the 2005 Emissions Data

    E-Print Network [OSTI]

    Ellerman, A. Denny.

    This paper provides an initial analysis of the European Union Emissions Trading Scheme (EU ETS) based on the installation-level data for verified emissions and allowance allocations in the first trading year. Those data, ...

  4. Review of EU airport energy interests and priorities with respect to ICT, energy efficiency and enhanced building operation 

    E-Print Network [OSTI]

    Costa, A.; Blanes, L. M.; Donnelly, C.; Keane, M. M.

    2012-01-01

    This paper gives an overview on EU airport energy interests and priorities with respect to ICT, energy efficiency and enhanced building operation. To achieve this objective the paper begins with an overview on airports role on energy consumption...

  5. First evidence of asymmetric cost pass-through of Eu emissions allowances : examining wholesale electricity prices in Germany

    E-Print Network [OSTI]

    Zachmann, Georg

    2007-01-01

    This paper applies the literature on asymmetric price transmission to the emerging commodity market for EU emissions allowances (EUA). We utilize an error correction model and an autoregressive distributed lag model to ...

  6. Comparison of the Evolution of Energy Intensity in Spain and in the EU15. Why is Spain Different?

    E-Print Network [OSTI]

    Ocaña, Carlos

    Energy intensity in Spain has increased since 1990, while the opposite has happened in the EU15. Decomposition analysis of primary energy intensity ratios has been used to identify which are the key sectors driving the ...

  7. Over-allocation or abatement? : a preliminary analysis of the EU ETS based on the 2005 emission data

    E-Print Network [OSTI]

    Ellerman, A. Denny

    2006-01-01

    This paper provides an initial analysis of the EU ETS based on the installation-level data for verified emissions and allowance allocations in the first trading year. Those data, released on May 15, 2006, and subsequent ...

  8. System and method for detecting gas

    DOE Patents [OSTI]

    Chow, Oscar Ken (Simsbury, CT); Moulthrop, Lawrence Clinton (Windsor, CT); Dreier, Ken Wayne (Madison, CT); Miller, Jacob Andrew (Dexter, MI)

    2010-03-16

    A system to detect a presence of a specific gas in a mixture of gaseous byproducts comprising moisture vapor is disclosed. The system includes an electrochemical cell, a transport to deliver the mixture of gaseous byproducts from the electrochemical cell, a gas sensor in fluid communication with the transport, the sensor responsive to a presence of the specific gas to generate a signal corresponding to a concentration of the specific gas, and a membrane to prevent transmission of liquid moisture, the membrane disposed between the transport and the gas sensor.

  9. Hydrogen gas relief valve

    DOE Patents [OSTI]

    Whittlesey, Curtis C. (Birmingham, MI)

    1985-01-01

    An improved battery stack design for an electrochemical system having at least one cell from which a gas is generated and an electrolyte in communication with the cell is described. The improved battery stack design features means for defining a substantially closed compartment for containing the battery cells and at least a portion of the electrolyte for the system, and means in association with the compartment means for selectively venting gas from the interior of the compartment means in response to the level of the electrolyte within the compartment means. The venting means includes a relief valve having a float member which is actuated in response to the level of the electrolyte within the compartment means. This float member is adapted to close the relief valve when the level of the electrolyte is above a predetermined level and open the relief valve when the level of electrolyte is below this predetermined level.

  10. Gas Drill 

    E-Print Network [OSTI]

    Unknown

    2011-09-05

    .C. Wang, B.T. Lovell, Program, Summary Report TE4258-5-84, J. McCrank, "Topping of a Combined Gas DOE/ET/11292, Oct. 1984. and Steam Turbine Powerplant using a TAM Combustor," Thermo Electron [4J Final Report: "Thermionic Energy Report No. 4258... for each Btu fired in the burners has been cal culated with the process gas temperature as a variable. It was shown [2 ] that the maximum thermionic power produced is 18 kW per million Btu fired per hour. All com bustors are similar but progressively...

  11. Gas sensor

    DOE Patents [OSTI]

    Schmid, Andreas K.; Mascaraque, Arantzazu; Santos, Benito; de la Figuera, Juan

    2014-09-09

    A gas sensor is described which incorporates a sensor stack comprising a first film layer of a ferromagnetic material, a spacer layer, and a second film layer of the ferromagnetic material. The first film layer is fabricated so that it exhibits a dependence of its magnetic anisotropy direction on the presence of a gas, That is, the orientation of the easy axis of magnetization will flip from out-of-plane to in-plane when the gas to be detected is present in sufficient concentration. By monitoring the change in resistance of the sensor stack when the orientation of the first layer's magnetization changes, and correlating that change with temperature one can determine both the identity and relative concentration of the detected gas. In one embodiment the stack sensor comprises a top ferromagnetic layer two mono layers thick of cobalt deposited upon a spacer layer of ruthenium, which in turn has a second layer of cobalt disposed on its other side, this second cobalt layer in contact with a programmable heater chip.

  12. Understanding and Managing Generation Y

    E-Print Network [OSTI]

    Wallace, Kevin

    2007-12-14

    There are four generations in the workplace today; they consist of the Silent Generation, Baby Boom Generation, Generation X, and Generation Y. Generation Y, being the newest generation, is the least understood generation although marketers...

  13. HIGH EFFICIENCY SYNGAS GENERATION

    SciTech Connect (OSTI)

    Robert J. Copeland; Yevgenia Gershanovich; Brian Windecker

    2005-02-01

    This project investigated an efficient and low cost method of auto-thermally reforming natural gas to hydrogen and carbon monoxide. Reforming is the highest cost step in producing products such as methanol and Fisher Tropsch liquids (i.e., gas to liquids); and reducing the cost of reforming is the key to reducing the cost of these products. Steam reforming is expensive because of the high cost of the high nickel alloy reforming tubes (i.e., indirectly fired reforming tubes). Conventional auto-thermal or Partial Oxidation (POX) reforming minimizes the size and cost of the reformers and provides a near optimum mixture of CO and hydrogen. However POX requires pure oxygen, which consumes power and significantly increases the cost to reforming. Our high efficiency process extracts oxygen from low-pressure air with novel oxygen sorbent and transfers the oxygen to a nickel-catalyzed reformer. The syngas is generated at process pressure (typically 20 to 40 bar) without nitrogen dilution and has a 1CO to 2H{sub 2} ratio that is near optimum for the subsequent production of Fisher-Tropsch liquid to liquids and other chemicals (i.e., Gas to Liquids, GTL). Our high process efficiency comes from the way we transfer the oxygen into the reformer. All of the components of the process, except for the oxygen sorbent, are commonly used in commercial practice. A process based on a longlived, regenerable, oxygen transfer sorbent could substantially reduce the cost of natural gas reforming to syngas. Lower cost syngas (CO + 2H{sub 2}) that is the feedstock for GTL would reduce the cost of GTL and for other commercial applications (e.g., methanol, other organic chemicals). The vast gas resources of Alaska's North Slope (ANS) offer more than 22 Tcf of gas and GTL production in this application alone, and could account for as much as 300,000 to 700,000 bpd for 20 to 30+ years. We developed a new sorbent, which is an essential part of the High Efficiency Oxygen Process (HOP). We tested the sorbent and observed that it has both a good oxygen capacity and operates as a highly effective reforming catalyst. We conducted a long duration tests of the sorbent (1,500 hours of continuous operation in the HOP cycle). Although the sorbent lost some oxygen capacity with cycling, the sorbent oxygen capacity stabilized after 1,000 hours and remained constant to the end of the test, 1,500 hour. The activity of the catalyst to reform methane to a hydrogen and carbon monoxide mixture was unchanged through the oxidation/reduction cycling. Our cost and performance analyses indicated a significant reduction in the cost of GTL production when using the HOP process integrated into a GTL plant.

  14. Promoting electricity from renewable energy sources -- lessons learned from the EU, U.S. and Japan

    E-Print Network [OSTI]

    Haas, Reinhard

    2008-01-01

    biomass, hydro power and biogas. Other options with vastTechnologies addressed Wind, biogas All technologies (exceptelectricity, Biomass, Biogas, Landfill gas, Sewage gas,

  15. Last Updated: 05.30.2013 Part I: California Uses for Natural Gas

    E-Print Network [OSTI]

    into California. ** Includes transportation sector natural gas demand. Total natural gas consumed in-state has1 Last Updated: 05.30.2013 Part I: California Uses for Natural Gas Natural gas is the second most shares of natural gas consumed by end-use sectors and in-state electricity generation. Table 1: Natural

  16. Aryl Bridged 1-Hydroxypyridin-2-one: Effect of the Bridge on the Eu(III) Sensitization Process

    SciTech Connect (OSTI)

    D'Aleo, Anthony; Moore, Evan G.; Szigethy, Geza; Xu, Jide; Raymond, Kenneth N.

    2009-06-17

    The efficiency of Eu3+ luminescence by energy transfer from an antenna ligand can be strongly dependent on the metal ion coordination geometry. The geometric component of the Eu(III) sensitization has been probed using series of tetradentate 1,2-HOPO derivatives that are connected by bridges of varying length and geometry. The ligands are N,N'-(1,2-phenylene)bis(1-hydroxy-6-oxo-1,6-dihydropyridine-2-carboxamide) for the ligand (L{sup 1}), 1-hydroxy-N-(2-(1-hydroxy-6-oxo-1,6-dihydropyridine-2-carboxamido)benzyl)-6-oxo-1,6-dihydropyridine-2-carboxamide (L{sup 2}) and N,N'-(1,2-phenylenebis(methylene))bis(1-hydroxy-6-oxo-1,6-dihydropyridine-2-carboxamide) (L{sup 3}). Spectroscopic characterization of both the Gd(III) and Eu(III) metal complexes, TD-DFT analysis of model compounds and evaluation of the kinetic parameters for the europium emission were completed. Some striking differences were observed in the luminescence quantum yield by altering the bridging unit. The [Eu(L{sup 2}){sub 2}]{sup -} derivative shows efficient sensitization coupled with good metal centered emission. For [Eu(L{sup 3}){sub 2}]{sup -}, the large quenching of the luminescence quantum yield compared to [Eu(L{sup 2}){sub 2}]{sup -} is primarily a result of one inner sphere water molecule bound to the europium cation while for [Eu(L{sup 1}){sub 2}]{sup -}, the low luminescence quantum yield can be attributed to inefficient sensitization of the europium ion.

  17. Method for mapping a natural gas leak

    DOE Patents [OSTI]

    Reichardt, Thomas A. (Livermore, CA); Luong, Amy Khai (Dublin, CA); Kulp, Thomas J. (Livermore, CA); Devdas, Sanjay (Albany, CA)

    2009-02-03

    A system is described that is suitable for use in determining the location of leaks of gases having a background concentration. The system is a point-wise backscatter absorption gas measurement system that measures absorption and distance to each point of an image. The absorption measurement provides an indication of the total amount of a gas of interest, and the distance provides an estimate of the background concentration of gas. The distance is measured from the time-of-flight of laser pulse that is generated along with the absorption measurement light. The measurements are formatted into an image of the presence of gas in excess of the background. Alternatively, an image of the scene is superimposed on the image of the gas to aid in locating leaks. By further modeling excess gas as a plume having a known concentration profile, the present system provides an estimate of the maximum concentration of the gas of interest.

  18. Cascading of Fluctuations in Interdependent Energy Infrastructures: Gas-Grid Coupling

    E-Print Network [OSTI]

    Chertkov, Michael; Backhaus, Scott

    2014-01-01

    The revolution of hydraulic fracturing has dramatically increased the supply and lowered the cost of natural gas in the United States driving an expansion of natural gas-fired generation capacity in many electrical grids. Unrelated to the natural gas expansion, lower capital costs and renewable portfolio standards are driving an expansion of intermittent renewable generation capacity such as wind and photovoltaic generation. These two changes may potentially combine to create new threats to the reliability of these interdependent energy infrastructures. Natural gas-fired generators are often used to balance the fluctuating output of wind generation. However, the time-varying output of these generators results in time-varying natural gas burn rates that impact the pressure in interstate transmission pipelines. Fluctuating pressure impacts the reliability of natural gas deliveries to those same generators and the safety of pipeline operations. We adopt a partial differential equation model of natural gas pipeli...

  19. NATURAL GAS MARKET ASSESSMENT

    E-Print Network [OSTI]

    CALIFORNIA ENERGY COMMISSION NATURAL GAS MARKET ASSESSMENT PRELIMINARY RESULTS In Support.................................................................................... 6 Chapter 2: Natural Gas Demand.................................................................................................. 10 Chapter 3: Natural Gas Supply

  20. Natural Gas Applications

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas Applications. If you need assistance viewing this page, please call (202) 586-8800. Energy Information Administration Home Page Home > Natural Gas > Natural Gas Applications...

  1. ,"Natural Gas Consumption",,,"Natural Gas Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    Census Division, 1999" ,"Natural Gas Consumption",,,"Natural Gas Expenditures" ,"per Building (thousand cubic feet)","per Square Foot (cubic feet)","per Worker (thousand cubic...

  2. Enhanced electrodes for solid state gas sensors

    DOE Patents [OSTI]

    Garzon, Fernando H. (Santa Fe, NM); Brosha, Eric L. (Los Alamos, NM)

    2001-01-01

    A solid state gas sensor generates an electrical potential between an equilibrium electrode and a second electrode indicative of a gas to be sensed. A solid electrolyte substrate has the second electrode mounted on a first portion of the electrolyte substrate and a composite equilibrium electrode including conterminous transition metal oxide and Pt components mounted on a second portion of the electrolyte substrate. The composite equilibrium electrode and the second electrode are electrically connected to generate an electrical potential indicative of the gas that is being sensed. In a particular embodiment of the present invention, the second electrode is a reference electrode that is exposed to a reference oxygen gas mixture so that the electrical potential is indicative of the oxygen in a gas stream.

  3. Natural Gas

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYear Jan Feb MarNGPL Production,Energy Office

  4. Generation gaps in engineering?

    E-Print Network [OSTI]

    Kim, David J. (David Jinwoo)

    2008-01-01

    There is much enthusiastic debate on the topic of generation gaps in the workplace today; what the generational differences are, how to address the apparent challenges, and if the generations themselves are even real. ...

  5. Elastic and anelastic relaxations associated with phase transitions in EuTiO3

    E-Print Network [OSTI]

    Spalek, Leszek J.; Saxena, Siddharth S.; Panagopoulos, Christos; Katsufuji, Takuro; Schiemer, Jason A.; Carpenter, Michael A.

    2014-08-29

    crystals of EuTiO3 used 6 had irregular shapes, with edge dimensions between ~0.5 and ~1 mm and masses 0.0568 gm (crystal 1), 0.0222 gm (crystal 2). For crystal 1, spectra were collected in the frequency range 0.3 – 2 MHz in 30 K steps during cooling... , Phase Trans. 68, 501 (1999). 46A. Migliori, J. L. Sarrao, W. M. Visscher, T. M. Bell, M. Lei, Z. Fisk, and R. G. Leisure, Physica B 183, 1 (1993). 47R. J. Harrison, and S. A. T. Redfern, Phys. Earth Planet. Inter. 134, 253 (2002). 48R. J. Harrison, S...

  6. Analysis of alpha-induced reactions on $^{151}$Eu below the Coulomb barrier

    E-Print Network [OSTI]

    V. Avrigeanu; M. Avrigeanu

    2010-12-05

    Novel measurements of $(\\alpha,\\gamma)$ and $(\\alpha$,n) reaction cross sections on the target nucleus $^{151}$Eu, close to the reaction thresholds, support the setting up of recent parameters of the $\\alpha$-particle optical model potential below the Coulomb barrier. A better understanding of the $\\alpha$-particle optical potential at these energies leads to a statistical model analysis of additional partial cross sections that were formerly measured but not considered within the model analysis. On this basis we have tentatively assigned a modified $J^{\\pi}$=9$^-$ spin and parity to the 22.7-h isomer in $^{154}$Tb.

  7. EU Energy Renewables Ltd now part of DeWind | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, AlabamaETEC GmbH Jump to: navigation, search Name: ETEC GmbH Place: GermanyEU Energy

  8. Mexico-EU-UNDP Low Emission Capacity Building Programme (LECBP) | Open

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: Energy ResourcesDec 2005 WindPRO is developed byEnergy Information EU-UNDP

  9. Trinidad and Tobago-EU-UNDP Low Emission Capacity Building Programme

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EISTJThin Film SolarTown(LECBP) | Open Energy Information EU-UNDP Low

  10. Costa Rica-EU-UNDP Climate Change Capacity Building Program | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePower VenturesInformation EU-UNDP Climate Change Capacity Building Program

  11. Structure, magnetism, specific heat, and dielectric properties of Eu{sub 2}Ta{sub 2}O{sub 7}

    SciTech Connect (OSTI)

    Kolodiazhnyi, T. Sakurai, H.; Matsushita, Y.

    2014-11-17

    Polycrystalline Eu{sub 2}Ta{sub 2}O{sub 7} containing layered perovskite slabs was prepared and analyzed. Eu{sub 2}Ta{sub 2}O{sub 7} crystallizes in the orthorhombic centrosymmetric Cmcm space group (with unit cell: a?=?3.95156(9), b?=?27.0775(6), and c?=?5.68279(13) Å) isomorphous with high-temperature Sr{sub 2}Ta{sub 2}O{sub 7}. Dielectric measurements reveal that, in contrast to Sr{sub 2}Ta{sub 2}O{sub 7} which is ferroelectric below 166?K, Eu{sub 2}Ta{sub 2}O{sub 7} remains paraelectric down to at least 0.45?K and shows no magneto-dielectric coupling. Magnetic data in the 2–400?K range indicate an antiferromagnetic phase transition with a sharp susceptibility peak at 2.71(5) K. Further analysis using specific heat measurements reveals that the second magnetic phase transition occurs at 1.10(5) K and dominates the spin entropy of the Eu{sup 2+} 4f{sup 7} ions. The possible origin of the two successive magnetic phase transitions in Eu{sub 2}Ta{sub 2}O{sub 7} requires further studies.

  12. North American Natural Gas Markets. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1989-02-01

    This report summarizes die research by an Energy Modeling Forum working group on the evolution of the North American natural gas markets between now and 2010. The group`s findings are based partly on the results of a set of economic models of the natural gas industry that were run for four scenarios representing significantly different conditions: two oil price scenarios (upper and lower), a smaller total US resource base (low US resource case), and increased potential gas demand for electric generation (high US demand case). Several issues, such as the direction of regulatory policy and the size of the gas resource base, were analyzed separately without the use of models.

  13. How EIA Estimates Natural Gas Production

    Reports and Publications (EIA)

    2004-01-01

    The Energy Information Administration (EIA) publishes estimates monthly and annually of the production of natural gas in the United States. The estimates are based on data EIA collects from gas producing states and data collected by the U. S. Minerals Management Service (MMS) in the Department of Interior. The states and MMS collect this information from producers of natural gas for various reasons, most often for revenue purposes. Because the information is not sufficiently complete or timely for inclusion in EIA's Natural Gas Monthly (NGM), EIA has developed estimation methodologies to generate monthly production estimates that are described in this document.

  14. Small Generator Aggregation (Maine)

    Broader source: Energy.gov [DOE]

    This section establishes requirements for electricity providers to purchase electricity from small generators, with the goal of ensuring that small electricity generators (those with a nameplate...

  15. Georgia Tech Dangerous Gas

    E-Print Network [OSTI]

    Li, Mo

    1 Georgia Tech Dangerous Gas Safety Program March 2011 #12;Georgia Tech Dangerous Gas Safety.......................................................................................................... 5 6. DANGEROUS GAS USAGE REQUIREMENTS................................................. 7 6.1. RESTRICTED PURCHASE/ACQUISITION RULES: ................................................ 7 7. FLAMMABLE GAS

  16. Gas tagging and cover gas combination for nuclear reactor

    DOE Patents [OSTI]

    Gross, Kenny C. (Lemont, IL); Laug, Matthew T. (Idaho Falls, ID)

    1985-01-01

    The invention discloses the use of stable isotopes of neon and argon, that are grouped in preselected different ratios one to the other and are then sealed as tags in different cladded nuclear fuel elements to be used in a liquid metal fast breeder reactor. Failure of the cladding of any fuel element allows fission gases generated in the reaction and these tag isotopes to escape and to combine with the cover gas held in the reactor over the fuel elements. The isotopes specifically are Ne.sup.20, Ne.sup.21 and Ne.sup.22 of neon and Ar.sup.36, Ar.sup.38 and Ar.sup.40 of argon, and the cover gas is helium. Serially connected cryogenically operated charcoal beds are used to clean the cover gas and to separate out the tags. The first or cover gas cleanup bed is held between approximately 0.degree. and -25.degree. C. operable to remove the fission gases from the cover gas and tags and the second or tag recovery system bed is held between approximately -170.degree. and -185.degree. C. operable to isolate the tags from the cover gas. Spectrometric analysis further is used to identify the specific tags that are recovered, and thus the specific leaking fuel element. By cataloging the fuel element tags to the location of the fuel elements in the reactor, the location of the leaking fuel element can then be specifically determined.

  17. Natural Gas Basics

    SciTech Connect (OSTI)

    NREL Clean Cities

    2010-04-01

    Fact sheet answers questions about natural gas production and use in transportation. Natural gas vehicles are also described.

  18. Comparative analysis of SOFC-GT freight locomotive fueled by natural gas and diesel with onboard reformation

    E-Print Network [OSTI]

    Martinez, AS; Brouwer, J; Samuelsen, GS

    2015-01-01

    using the mercury 50 advanced turbine systems gas turbine.J Eng Gas Turbines Power 2003;125:51–8. [55] Caterpillar.>. [58] Kawasaki. Kawasaki gas turbine generator sets; 2007.

  19. Assessing the Potential of Using Hydrate Technology to Capture, Store and Transport Gas for the Caribbean Region 

    E-Print Network [OSTI]

    Rajnauth, Jerome Joel

    2012-02-14

    Monetizing gas has now become a high priority issue for many countries. Natural gas is a much cleaner fuel than oil and coal especially for electricity generation. Approximately 40 percent of the world's natural gas reserves remain unusable because...

  20. Generating power with drained coal mine methane

    SciTech Connect (OSTI)

    2005-09-01

    The article describes the three technologies most commonly used for generating electricity from coal mine methane: internal combustion engines, gas turbines, and microturbines. The most critical characteristics and features of these technologies, such as efficiency, output and size are highlighted. 5 refs.

  1. Promoting electricity from renewable energy sources -- lessons learned from the EU, U.S. and Japan

    E-Print Network [OSTI]

    Haas, Reinhard

    2008-01-01

    Electricity generation [GWh/year] Wind onshore BiogasElectricity generation [GWh/year] Wind onshore Hydro small-scale Solid biomass PV Hydro large-scale Biogas

  2. Report on the EU-US Environmental Biotechnology Workshop on Microbial Community Dynamics: Cooperation and Competition

    SciTech Connect (OSTI)

    Wall, Judy D.

    2013-07-01

    The Workshop on Microbial Community Dynamics: Cooperation and Competition to be held in the fall of 2012 in St. Louis, Missouri, USA, is an initiative of the Environmental Biotechnology Working Group of the EU-US Taskforce on Biotechnology Research, a cooperative program between the European Commission and the United States of America. The activities of the Environmental Biotechnology Working Group have as their goals to provide a forum for early career scientists from the US and EU to meet, to learn cutting edge research in the area of microbial biotechnology from world experts and to set the groundwork for future cooperation and collaboration. Workshop topics will address fundamental physiology and genetics of microbial communities that will contribute to advances in bioremediation, bioenergy conversion and carbon sequestration. Senior scientist participants will be world renowned experts who will present the current status of their fields and forecast research challenges and opportunities. It is a goal of the Environmental Biotechnology Working Group to facilitate the formation of direct collaborations among US and European scientists in programs of mutual interest and benefit. Therefore, the workshop will also provide an opportunity for members of the Working Group and attendees to identify areas where advancement is necessary and plan the steps necessary for realizing future research collaborations. In addition, time will be provided for mentoring of the early career scientists by the senior scientists on an individual basis.

  3. Structural consideration on the emission properties of Eu²?-doped Ba(Sr, Ca)?MgSi?O?

    SciTech Connect (OSTI)

    Yonesaki, Yoshinori, E-mail: yonesaki@yamanashi.ac.jp [Interdisciplinary Graduate School of Medicine and Engineering, University of Yamanashi, Miyamae 7-32, Kofu 400-8511 (Japan)

    2013-05-01

    Emission properties of Eu²?-doped Ba(Sr, Ca)?MgSi?O? are discussed in terms of the crystal structure refined by Rietveld method. Ba(Sr, Ca)?MgSi?O? has glaserite-type layered structure. In response to Sr/(Sr+Ca) ratio, the layer-framework build up by corner-sharing of MgO? octahedra and SiO? tetrahedra twists around C? axes to match the size of B-site cation (Sr²?/Ca²?). This twist significantly affects the unit cell size and the coordination environment around B-site. Eu²?-doped Ba(Sr, Ca)?MgSi?O? exhibited blue emission under ultraviolet irradiation. The emission spectra have been characterized by two emission components derived from Eu²? ions occupying A- and B-site. Both components showed similar wavelength shift for different Sr/(Sr+Ca), in response to Si–O? polarization and to the structural change. - Graphical abstract: Emission properties of Eu²?-doped Ba(Sr, Ca)?MgSi?O? are discussed in terms of the crystal structure refined by Rietveld method. Highlights: • Glaserite-type Ba(Sr, Ca)?MgS?O? has been prepared by a solid state reaction. • Ba(Sr, Ca)?MgSi?O? changes the crystal structure, depending on Sr/(Sr+Ca) ratio. • Eu²?-doped Ba(Sr, Ca)?MgSi?O? exhibits blue emission under ultraviolet irradiation. • Emission from Ba(Sr, Ca)?MgSi?O? is characterized by two Eu²? emission components. • The two emissions show wavelength shift in a similar manner against Sr/(Sr+Ca)

  4. Combined fuel and air staged power generation system

    SciTech Connect (OSTI)

    Rabovitser, Iosif K; Pratapas, John M; Boulanov, Dmitri

    2014-05-27

    A method and apparatus for generation of electric power employing fuel and air staging in which a first stage gas turbine and a second stage partial oxidation gas turbine power operated in parallel. A first portion of fuel and oxidant are provided to the first stage gas turbine which generates a first portion of electric power and a hot oxidant. A second portion of fuel and oxidant are provided to the second stage partial oxidation gas turbine which generates a second portion of electric power and a hot syngas. The hot oxidant and the hot syngas are provided to a bottoming cycle employing a fuel-fired boiler by which a third portion of electric power is generated.

  5. Inversionless lasing with self-generated driving field 

    E-Print Network [OSTI]

    Belyanin, Alexey; Bentley, C.; Capasso, F.; Kocharovskaya, O.; Scully, Marlan O.

    2001-01-01

    inversionless ultraviolet and soft x-ray lasing in gas lasers and inversionless generation of coherent mid/far-infrared emission on intersubband (interlevel) transitions in multiple quantum-well or quantum-dot laser diodes....

  6. Table 2. Ten largest plants by generation capacity, 2013

    U.S. Energy Information Administration (EIA) Indexed Site

    Mile Point Nuclear Sta LLC",1924.1 4,"Northport","Natural gas","National Grid Generation LLC",1593.1 5,"Oswego Harbor Power","Petroleum","NRG Oswego Harbor Power...

  7. Table 2. Ten Largest Plants by Generation Capacity, 2013

    U.S. Energy Information Administration (EIA) Indexed Site

    Generating Station","Natural gas","Public Service Co of NM",235.6 9,"New Mexico Wind Energy Center","Wind","FPL Energy New Mexico Wind LLC",204 10,"Maddox","Natural...

  8. Carbon sequestration in natural gas reservoirs: Enhanced gas recovery and natural gas storage

    E-Print Network [OSTI]

    Oldenburg, Curtis M.

    2003-01-01

    cushion gas for natural gas storage, Energy and Fuels, 17(RECOVERY AND NATURAL GAS STORAGE Curtis M. Oldenburg Eartheffective cushion gas for gas storage reservoirs. Thus at

  9. Synthesis gas production by mixed conducting membranes with integrated conversion into liquid products

    DOE Patents [OSTI]

    Nataraj, Shankar (Allentown, PA); Russek, Steven Lee (Allentown, PA); Dyer, Paul Nigel (Allentown, PA)

    2000-01-01

    Natural gas or other methane-containing feed gas is converted to a C.sub.5 -C.sub.19 hydrocarbon liquid in an integrated system comprising an oxygenative synthesis gas generator, a non-oxygenative synthesis gas generator, and a hydrocarbon synthesis process such as the Fischer-Tropsch process. The oxygenative synthesis gas generator is a mixed conducting membrane reactor system and the non-oxygenative synthesis gas generator is preferably a heat exchange reformer wherein heat is provided by hot synthesis gas product from the mixed conducting membrane reactor system. Offgas and water from the Fischer-Tropsch process can be recycled to the synthesis gas generation system individually or in combination.

  10. Modeling a Helical-coil Steam Generator in RELAP5-3D for the Next Generation Nuclear Plant

    SciTech Connect (OSTI)

    Nathan V. Hoffer; Piyush Sabharwall; Nolan A. Anderson

    2011-01-01

    Options for the primary heat transport loop heat exchangers for the Next Generation Nuclear Plant are currently being evaluated. A helical-coil steam generator is one heat exchanger design under consideration. Safety is an integral part of the helical-coil steam generator evaluation. Transient analysis plays a key role in evaluation of the steam generators safety. Using RELAP5-3D to model the helical-coil steam generator, a loss of pressure in the primary side of the steam generator is simulated. This report details the development of the steam generator model, the loss of pressure transient, and the response of the steam generator primary and secondary systems to the loss of primary pressure. Back ground on High Temperature Gas-cooled reactors, steam generators, the Next Generation Nuclear Plant is provided to increase the readers understanding of the material presented.

  11. Gas sensor with attenuated drift characteristic

    DOE Patents [OSTI]

    Chen, Ing-Shin (Danbury, CT) [Danbury, CT; Chen, Philip S. H. (Bethel, CT) [Bethel, CT; Neuner, Jeffrey W. (Bethel, CT) [Bethel, CT; Welch, James (Fairfield, CT) [Fairfield, CT; Hendrix, Bryan (Danbury, CT) [Danbury, CT; Dimeo, Jr., Frank [Danbury, CT

    2008-05-13

    A sensor with an attenuated drift characteristic, including a layer structure in which a sensing layer has a layer of diffusional barrier material on at least one of its faces. The sensor may for example be constituted as a hydrogen gas sensor including a palladium/yttrium layer structure formed on a micro-hotplate base, with a chromium barrier layer between the yttrium layer and the micro-hotplate, and with a tantalum barrier layer between the yttrium layer and an overlying palladium protective layer. The gas sensor is useful for detection of a target gas in environments susceptible to generation or incursion of such gas, and achieves substantial (e.g., >90%) reduction of signal drift from the gas sensor in extended operation, relative to a corresponding gas sensor lacking the diffusional barrier structure of the invention

  12. Gamma ray generator

    DOE Patents [OSTI]

    Firestone, Richard B; Reijonen, Jani

    2014-05-27

    An embodiment of a gamma ray generator includes a neutron generator and a moderator. The moderator is coupled to the neutron generator. The moderator includes a neutron capture material. In operation, the neutron generator produces neutrons and the neutron capture material captures at least some of the neutrons to produces gamma rays. An application of the gamma ray generator is as a source of gamma rays for calibration of gamma ray detectors.

  13. Generation to Generation: The Heart of Family Medicine

    E-Print Network [OSTI]

    Winter, Robin O

    2012-01-01

    Ageism in the Workplace. Generations Spring, 5. Westman,of caring for multiple generations simultaneously. StronglyGeneration to Generation: The Heart of Family Medicine

  14. Cold weather hydrogen generation system and method of operation

    SciTech Connect (OSTI)

    Dreier, Ken Wayne; Kowalski, Michael Thomas; Porter, Stephen Charles; Chow, Oscar Ken; Borland, Nicholas Paul; Goyette, Stephen Arthur

    2010-12-14

    A system for providing hydrogen gas is provided. The system includes a hydrogen generator that produces gas from water. One or more heat generation devices are arranged to provide heating of the enclosure during different modes of operation to prevent freezing of components. A plurality of temperature sensors are arranged and coupled to a controller to selectively activate a heat source if the temperature of the component is less than a predetermined temperature.

  15. Detection of gas leakage

    DOE Patents [OSTI]

    Thornberg, Steven (Peralta, NM); Brown, Jason (Albuquerque, NM)

    2012-06-19

    A method of detecting leaks and measuring volumes as well as an apparatus, the Power-free Pump Module (PPM), that is a self-contained leak test and volume measurement apparatus that requires no external sources of electrical power during leak testing or volume measurement, where the invention is a portable, pneumatically-controlled instrument capable of generating a vacuum, calibrating volumes, and performing quantitative leak tests on a closed test system or device, all without the use of alternating current (AC) power. Capabilities include the ability is to provide a modest vacuum (less than 10 Torr), perform a pressure rise leak test, measure the gas's absolute pressure, and perform volume measurements. All operations are performed through a simple rotary control valve which controls pneumatically-operated manifold valves.

  16. Discharge source with gas curtain for protecting optics from particles

    DOE Patents [OSTI]

    Fornaciari, Neal R.; Kanouff, Michael P.

    2004-03-30

    A gas curtain device is employed to deflect debris that is generated by an extreme ultraviolet and soft x-ray radiation discharge source such as an electric discharge plasma source. The gas curtain device projects a stream of gas over the path of the radiation to deflect debris particles into a direction that is different from that of the path of the radiation. The gas curtain can be employed to prevent debris accumulation on the optics used in photolithography.

  17. Presentation 1.1: An overview of existing and emerging EU policies relating to energy from biomass and their effects on forest based industries

    E-Print Network [OSTI]

    : - raw material operator and "co-ordinator" - as a large energy user of electricity & heat - as producer of electricity & heat for "export" - as innovator and developer of new product and process technologies Therefore) BUT: Mostly SMEs; low investment in R&D & education; high costs; risk of relocation outside EU EU

  18. Japan hopes for rapid accord with EU on nuclear reactor Japanese Prime Minister Junichiro Koizumi said Monday that he hopes to resolve a dispute with the

    E-Print Network [OSTI]

    Japan hopes for rapid accord with EU on nuclear reactor 02/05/2005 Japanese Prime Minister nuclear reactor as soon as possible. Koizumi discussed the row over plans for the International Terms and Conditions 5/2/05 8:59 AMEUbusiness - Japan hopes for rapid accord with EU on nuclear reactor

  19. Fuel gas conditioning process

    DOE Patents [OSTI]

    Lokhandwala, Kaaeid A. (Union City, CA)

    2000-01-01

    A process for conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas, so that it can be used as combustion fuel to run gas-powered equipment, including compressors, in the gas field or the gas processing plant. Compared with prior art processes, the invention creates lesser quantities of low-pressure gas per unit volume of fuel gas produced. Optionally, the process can also produce an NGL product.

  20. NEXT GENERATION TURBINE PROGRAM

    SciTech Connect (OSTI)

    William H. Day

    2002-05-03

    The Next Generation Turbine (NGT) Program's technological development focused on a study of the feasibility of turbine systems greater than 30 MW that offer improvement over the 1999 state-of-the-art systems. This program targeted goals of 50 percent turndown ratios, 15 percent reduction in generation cost/kW hour, improved service life, reduced emissions, 400 starts/year with 10 minutes to full load, and multiple fuel usage. Improvement in reliability, availability, and maintainability (RAM), while reducing operations, maintenance, and capital costs by 15 percent, was pursued. This program builds on the extensive low emissions stationary gas turbine work being carried out by Pratt & Whitney (P&W) for P&W Power Systems (PWPS), which is a company under the auspices of the United Technologies Corporation (UTC). This study was part of the overall Department of Energy (DOE) NGT Program that extends out to the year 2008. A follow-on plan for further full-scale component hardware testing is conceptualized for years 2002 through 2008 to insure a smooth and efficient transition to the marketplace for advanced turbine design and cycle technology. This program teamed the National Energy Technology Laboratory (NETL), P&W, United Technologies Research Center (UTRC), kraftWork Systems Inc., a subcontractor on-site at UTRC, and Multiphase Power and Processing Technologies (MPPT), an off-site subcontractor. Under the auspices of the NGT Program, a series of analyses were performed to identify the NGT engine system's ability to serve multiple uses. The majority were in conjunction with a coal-fired plant, or used coal as the system fuel. Identified also was the ability of the NGT system to serve as the basis of an advanced performance cycle: the humid air turbine (HAT) cycle. The HAT cycle is also used with coal gasification in an integrated cycle HAT (IGHAT). The NGT systems identified were: (1) Feedwater heating retrofit to an existing coal-fired steam plant, which could supply both heat and peaking power (Block 2 engine); (2) Repowering of an older coal-fired plant (Block 2 engine); (3) Gas-fired HAT cycle (Block 1 and 2 engines); (4) Integrated gasification HAT (Block 1 and 2 engines). Also under Phase I of the NGT Program, a conceptual design of the combustion system has been completed. An integrated approach to cycle optimization for improved combustor turndown capability has been employed. The configuration selected has the potential for achieving single digit NO{sub x}/CO emissions between 40 percent and 100 percent load conditions. A technology maturation plan for the combustion system has been proposed. Also, as a result of Phase I, ceramic vane technology will be incorporated into NGT designs and will require less cooling flow than conventional metallic vanes, thereby improving engine efficiency. A common 50 Hz and 60 Hz power turbine was selected due to the cost savings from eliminating a gearbox. A list of ceramic vane technologies has been identified for which the funding comes from DOE, NASA, the U.S. Air Force, and P&W.

  1. Cylindrical neutron generator

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA)

    2009-12-29

    A cylindrical neutron generator is formed with a coaxial RF-driven plasma ion source and target. A deuterium (or deuterium and tritium) plasma is produced by RF excitation in a cylindrical plasma ion generator using an RF antenna. A cylindrical neutron generating target is coaxial with the ion generator, separated by plasma and extraction electrodes which contain many slots. The plasma generator emanates ions radially over 360.degree. and the cylindrical target is thus irradiated by ions over its entire circumference. The plasma generator and target may be as long as desired. The plasma generator may be in the center and the neutron target on the outside, or the plasma generator may be on the outside and the target on the inside. In a nested configuration, several concentric targets and plasma generating regions are nested to increase the neutron flux.

  2. Cylindrical neutron generator

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA)

    2008-04-22

    A cylindrical neutron generator is formed with a coaxial RF-driven plasma ion source and target. A deuterium (or deuterium and tritium) plasma is produced by RF excitation in a cylindrical plasma ion generator using an RF antenna. A cylindrical neutron generating target is coaxial with the ion generator, separated by plasma and extraction electrodes which contain many slots. The plasma generator emanates ions radially over 360.degree. and the cylindrical target is thus irradiated by ions over its entire circumference. The plasma generator and target may be as long as desired. The plasma generator may be in the center and the neutron target on the outside, or the plasma generator may be on the outside and the target on the inside. In a nested configuration, several concentric targets and plasma generating regions are nested to increase the neutron flux.

  3. Cylindrical neutron generator

    DOE Patents [OSTI]

    Leung, Ka-Ngo

    2005-06-14

    A cylindrical neutron generator is formed with a coaxial RF-driven plasma ion source and target. A deuterium (or deuterium and tritium) plasma is produced by RF excitation in a cylindrical plasma ion generator using an RF antenna. A cylindrical neutron generating target is coaxial with the ion generator, separated by plasma and extraction electrodes which contain many slots. The plasma generator emanates ions radially over 360.degree. and the cylindrical target is thus irradiated by ions over its entire circumference. The plasma generator and target may be as long as desired. The plasma generator may be in the center and the neutron target on the outside, or the plasma generator may be on the outside and the target on the inside. In a nested configuration, several concentric targets and plasma generating regions are nested to increase the neutron flux.

  4. This is the pre-peer reviewed version of the following article: "Can hydraulic fracturing make Poland self-sufficient in natural gas?", which will be published in final form in a

    E-Print Network [OSTI]

    Patzek, Tadeusz W.

    The International Energy Agency (IEA) has highlighted hydraulic fracturing (fracking) as the key to a "Golden Age in the future. In order to improve energy security in the EU, hydraulic fracturing or "fracking," as it commonly of Energy Technology on Shale Gas Technology. http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)2194

  5. Reliability of natural gas cogeneration systems

    SciTech Connect (OSTI)

    1995-12-01

    Cogeneration systems fueled by natural gas exceed the reliability of most central station power generating units, according to a study conducted by RINC Corporation for Gas Research Institute (GRI). In the study, researchers obtained operating data from 122 natural gas cogeneration units nationwide representing 2,200 megawatts (MW) of capacity and nearly 2 million hours of operating time at 37 facilities. Units were grouped into categories reflecting size (from 60 kilowatts to 100 MW), type of system (gas engine or gas turbine technology), use of emission controls, and type of thermal application. Various types and sizes of gas systems reported average availability factors ranging from 90.0 to 95.8 versus a weighted average of 85.9 percent for fossil-fuel steam, nuclear, and gas-turbine-based central station power generating units. Comparisons are based on study data and data reported by the North American Electric Reliability Council for utility power plants. Gas cogeneration can improve utility operations because as a group the relatively small, dispersed cogeneration units are more reliable than one or more large central station units of similar capacity.

  6. Thermochemically recuperated and steam cooled gas turbine system

    DOE Patents [OSTI]

    Viscovich, P.W.; Bannister, R.L.

    1995-07-11

    A gas turbine system is described in which the expanded gas from the turbine section is used to generate the steam in a heat recovery steam generator and to heat a mixture of gaseous hydrocarbon fuel and the steam in a reformer. The reformer converts the hydrocarbon gas to hydrogen and carbon monoxide for combustion in a combustor. A portion of the steam from the heat recovery steam generator is used to cool components, such as the stationary vanes, in the turbine section, thereby superheating the steam. The superheated steam is mixed into the hydrocarbon gas upstream of the reformer, thereby eliminating the need to raise the temperature of the expanded gas discharged from the turbine section in order to achieve effective conversion of the hydrocarbon gas. 4 figs.

  7. Thermochemically recuperated and steam cooled gas turbine system

    DOE Patents [OSTI]

    Viscovich, Paul W. (Longwood, FL); Bannister, Ronald L. (Winter Springs, FL)

    1995-01-01

    A gas turbine system in which the expanded gas from the turbine section is used to generate the steam in a heat recovery steam generator and to heat a mixture of gaseous hydrocarbon fuel and the steam in a reformer. The reformer converts the hydrocarbon gas to hydrogen and carbon monoxide for combustion in a combustor. A portion of the steam from the heat recovery steam generator is used to cool components, such as the stationary vanes, in the turbine section, thereby superheating the steam. The superheated steam is mixed into the hydrocarbon gas upstream of the reformer, thereby eliminating the need to raise the temperature of the expanded gas discharged from the turbine section in order to achieve effective conversion of the hydrocarbon gas.

  8. Fuel Interchangeability Considerations for Gas Turbine Combustion

    SciTech Connect (OSTI)

    Ferguson, D.H.

    2007-10-01

    In recent years domestic natural gas has experienced a considerable growth in demand particularly in the power generation industry. However, the desire for energy security, lower fuel costs and a reduction in carbon emissions has produced an increase in demand for alternative fuel sources. Current strategies for reducing the environmental impact of natural gas combustion in gas turbine engines used for power generation experience such hurdles as flashback, lean blow-off and combustion dynamics. These issues will continue as turbines are presented with coal syngas, gasified coal, biomass, LNG and high hydrogen content fuels. As it may be impractical to physically test a given turbine on all of the possible fuel blends it may experience over its life cycle, the need to predict fuel interchangeability becomes imperative. This study considers a number of historical parameters typically used to determine fuel interchangeability. Also addressed is the need for improved reaction mechanisms capable of accurately modeling the combustion of natural gas alternatives.

  9. Gas permeable electrode for electrochemical system

    DOE Patents [OSTI]

    Ludwig, F.A.; Townsend, C.W.

    1989-09-12

    An electrode apparatus is described which is adapted for use in electrochemical systems having an anode compartment and a cathode compartment in which gas and ions are produced and consumed in the compartments during generation of electrical current. The electrode apparatus includes a membrane for separating the anode compartment from the cathode compartment wherein the membrane is permeable to both ions and gas. The cathode and anode for the assembly are provided on opposite sides of the membrane. During use of the membrane-electrode apparatus in electrochemical cells, the gas and ions generated at the cathode or anode migrate through the membrane to provide efficient transfer of gas and ions between the anode and cathode compartments. 3 figs.

  10. Coke oven gas injection to blast furnaces

    SciTech Connect (OSTI)

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L. [U.S. Steel, Clairton, PA (United States)

    1995-12-01

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  11. Catalytic CVD generation of high-purity single-walled carbon nanotubes at low temperature

    E-Print Network [OSTI]

    Maruyama, Shigeo

    CVD Catalytic CVD generation of high-purity single-walled carbon nanotubes at low temperature-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 We have demonstrated the high-quality and low-temperature generation on the generation temperature and gas flow rate. In order to create nanotube devices, we tried to generate SWNTs

  12. DIRECTIVE 2010/63/EU OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 22 September 2010

    E-Print Network [OSTI]

    Spang, Rainer

    DIRECTIVES DIRECTIVE 2010/63/EU OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 22 September 2010 the Council adopted Directive 86/609/EEC (3) in order to eliminate disparities between laws, regulations of the European Union (TFEU). (3) On 23 March 1998 the Council adopted Decision 1999/575/EC concerning

  13. On the peculiar properties of triangular-chain EuCr{sub 3}(BO{sub 3}){sub 4} antiferromagnet

    SciTech Connect (OSTI)

    Gondek, ?.; Szytu?a, A.; Przewo?nik, J.; ?ukrowski, J.; Prokhorov, A.; Chernush, L.; Zubov, E.; Dyakonov, V.; Tyvanchuk, Yu.

    2014-02-15

    In this paper we report studies on EuCr{sub 3}(BO{sub 3}){sub 4} compound, that is a member of newly discovered family of huntite-related specimens for non-linear optics. For the first time, the uncommon temperature dependence of the EuCr{sub 3}(BO{sub 3}){sub 4} lattice parameters is reported. Additionally, the magnetism of this compound is extremely interesting. Namely, a possible interplay in between potentially magnetic rare-earth ions and 3d metal stacked within quasi-1D chain that can lead to a great variety of magnetic behaviour. Indeed, in our studies we have found 3D-long range ordering with metamagnetic behaviour, while at higher temperature the magnetic chains become uncoupled. - Graphical abstract: Torsion-like vibrations are the key to understand negative thermal expansion along the a-axis. Display Omitted - Highlights: • EuCr{sub 3}(BO{sub 3}){sub 4} is a peculiar triangular-chain antiferromagnet. • Rare earth sublattice is non-magnetic with Eu{sup 3+} configuration. • Cr{sup 3+} magnetic moments show 1-D behaviour along with spin fluctuations. • Torsion vibrations of Cr triangular tubes lead to anomalous expansion of unit cell.

  14. Fair Weather Friends or Pillars of Support: Assessing the Sources of Legitimacy of EU Governance Among the Public Across Europe 

    E-Print Network [OSTI]

    Bastin, Mariah Margareta

    2013-02-04

    of national institutions and priorities shaping the European Union’s response to the current fiscal and economic crisis flowing from the global “Great Recession”, is a growing concern for policy makers and scholars alike regarding the legitimacy of the EU...

  15. A Top-down and Bottom-up look at Emissions Abatement in Germany in response to the EU ETS

    E-Print Network [OSTI]

    Feilhauer, Stephan M. (Stephan Marvin)

    2008-01-01

    This paper uses top-down trend analysis and a bottom-up power sector model to define upper and lower boundaries on abatement in Germany in the first phase of the EU Emissions Trading Scheme (2005-2007). Long-term trend ...

  16. REFUEL: an EU road map for biofuels , E. Deurwaarder and S. Lensink, ECN policy Studies, the Netherlands

    E-Print Network [OSTI]

    REFUEL: an EU road map for biofuels M. Londo1 , E. Deurwaarder and S. Lensink, ECN policy Studies), Poland K. Könighofer, Joanneum Research, Austria Abstract A successful mid-term development of biofuels calls for a robust road map. REFUEL assesses inter alia least-cost biofuel chain options, their benefits

  17. Japan, EU adamant about their proposals to host ITER, put off negotiations to next year; Joint construction plan involving Japan,

    E-Print Network [OSTI]

    billion yen to companies in the defeated bidder and would expand the number of researchers from the EU States, Russia, China and South Korea are taking part in the 500-billion-yen largest ever energy project facility and to enable its domestic companies to receive orders for constructing a part of the reactor

  18. Structural and magnetic phase transitions inEuTi1-xNbxO3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Ling; Morris, James R.; Koehler, Michael R.; Dun, Zhiling; Zhou, Haidong; Yan, Jiaqiang; Mandrus, David; Keppens, Veerle

    2015-07-30

    We have investigated the structural and magnetic phase transitions in EuTi1-xNbxO3 (0 ? x ? 0.3) with synchrotron powder x-ray diffraction, resonant ultrasound spectroscopy, and magnetization measurements. Upon Nb doping, the Pm3¯m ? I4/mcm structural transition shifts to higher temperatures and the room temperature lattice parameter increases while the magnitude of the octahedral tilting decreases. In addition, Nb substitution for Ti destabilizes the antiferromagnetic ground state of the parent compound and long-range ferromagnetic order is observed in the samples with x ? 0.1. The structural transition in pure and doped compounds is marked by a dramatic steplike softening of themore »elastic moduli near TS , which resembles that of SrTiO3 and can be adequately modeled using the Landau free energy model employing the same coupling between strain and octahedral tilting order parameter as previously used to model SrTiO3.« less

  19. Antimagnetic rotation and sudden change of electric quadrupole transition strength in 143Eu

    E-Print Network [OSTI]

    S. Rajbanshi; S. Roy; Somnath Nag; Abhijit Bisoi; S. Saha; J. Sethi; T. Trivedi; T. Bhattacharjee; S. Bhattacharyya; S. Chattopadhyay; G. Gangopadhyay; G. Mukherjee; R. Palit; R. Raut; M. Saha Sarkar; A. K. Singh; A. Goswami

    2015-05-22

    Lifetimes of the states in the quadrupole structure in 143Eu have been measured using the Doppler shift attenuation method as well as parity of the states in the sequence has been firmly identified from polarization measurement using the Indian National Gamma Array. The decreasing trends of the deduced quadrupole transition strength B(E2) with spin, along with increasing J (2) /B(E2) values before band crossing, conclusively establish the origin of these states as arising out of antimagnetic rotation. The abrupt increase in the B(E2) values after the band crossing in the quadrupole band, a novel feature observed in the present experiment, may indicates the crossing of different shears configurations resulting in re-opening of shears structure. The results are well reproduced by numerical calculation within the framework of semi-classical geometric model.

  20. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    1999-10-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  1. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2000-03-31

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  2. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    1999-04-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  3. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    2000-10-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  4. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2000-09-30

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  5. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    1999-01-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  6. Alternative Fuels and Chemicals from Synthesis Gas

    SciTech Connect (OSTI)

    Peter Tijrn

    2003-01-02

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  7. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Marnay, Chris

    2010-01-01

    2020 S00 S/t of carbon mpared to CHP, PV a n d solar t h e rm a l as options in DE R-CAM only CHP as optioninDER-CAM CHP Capacity: 2.25 GW CHP Electricity: 10.05 TWh

  8. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    and may also be charged by CHP systems during off-peak andDarrow, K et al. (2009), “CHP Market Assessment”, Integratedwith combined heat and power (CHP) may be implemented within

  9. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    Modeling with Combined Heat and Power Applications”,Committee, Combined Heat and Power Workshop, CaliforniaJuly 23, 2009 Combined Heat and Power Installation

  10. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    Department of Energy research project. To show the impact ofResearch, Development, and Demonstration Projects”, IEEE power & energy

  11. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    N. et al. , (2007), “Microgrids, An Overview of Ongoingof Commercial-Building Microgrids,” IEEE Transactions onsuccessful deployment of microgrids will depend heavily on

  12. Modeling acid-gas generation from boiling chloride brines

    E-Print Network [OSTI]

    Zhang, Guoxiang

    2010-01-01

    WAJ: Chemistry and geothermal systems. Academic Press 1977,system corrosion in geothermal systems [11–13]. For thisat the Geysers geothermal system in Northern California.

  13. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    adoption and reduced PV adoption, but ICEs are still veryindicate that PV and electric storage adoption can competeindicate that PV and electric storage adoption can compete

  14. Modeling acid-gas generation from boiling chloride brines

    E-Print Network [OSTI]

    Zhang, Guoxiang

    2010-01-01

    solutions, Journal of nuclear technology 2008, 164:180– 35.Modeling and Analysis. Nuclear Technology 1993, 104: 418- 2.

  15. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    and does consider CHP in commercial buildings as an option.for CHP installations are office buildings, hospitals,building sector can install 1.4 GW of economic CHP capacity

  16. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    and not only by PV / solar thermal systems. To satisfy theheat exchangers, solar thermal collectors, absorptionphotovoltaics and solar thermal collectors; • electrical

  17. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    Effect of Heat and Electricity Storage and Reliability onsand_doc/2001/012022p.pdf). Electricity Storage Association,Symons and Butler 2001, Electricity Storage Association, own

  18. Modeling acid-gas generation from boiling chloride brines

    E-Print Network [OSTI]

    Zhang, Guoxiang

    2010-01-01

    of the unsaturated zone at Yucca Mountain, Nevada. J. ofwaste emplacement tunnels at Yucca Mountain, Nevada. J. ofScale Heater Test at Yucca Mountain. International Journal

  19. Exhaust gas bypass valve control for thermoelectric generator

    DOE Patents [OSTI]

    Reynolds, Michael G; Yang, Jihui; Meisner, Greogry P.; Stabler, Francis R.; De Bock, Hendrik Pieter (Peter) Jacobus; Anderson, Todd Alan

    2012-09-04

    A method of controlling engine exhaust flow through at least one of an exhaust bypass and a thermoelectric device via a bypass valve is provided. The method includes: determining a mass flow of exhaust exiting an engine; determining a desired exhaust pressure based on the mass flow of exhaust; comparing the desired exhaust pressure to a determined exhaust pressure; and determining a bypass valve control value based on the comparing, wherein the bypass valve control value is used to control the bypass valve.

  20. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    photovoltaics and solar thermal collectors; • electricalexchangers, solar thermal collectors, absorption chillers,

  1. Modeling acid-gas generation from boiling chloride brines

    E-Print Network [OSTI]

    Zhang, Guoxiang

    2010-01-01

    chloride in superheated geothermal steam. Geothermics 1989,condensate from superheated geothermal steam. Implicationsexpansion of superheated geothermal steam, with implications

  2. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    exchangers, solar thermal collectors, absorption chillers,photovoltaics and solar thermal collectors; • electrical

  3. Greenhouse Gas Abatement with Distributed Generation in California's Commercial Buildings

    E-Print Network [OSTI]

    Stadler, Michael

    2010-01-01

    lead acid absorption solar photo- storage batteries chillersolar thermal collectors, absorption chillers, and storageand solar thermal collectors; • electrical storage, flow

  4. Relativistic high harmonic generation in gas jet targets (Journal Article)

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnical Report:Speeding accessby aLEDSpeeding FINAL Progress ReportEnergy,Regulatory|

  5. New wave generation

    E-Print Network [OSTI]

    Mercier, Matthieu J.

    We present the results of a combined experimental and numerical study of the generation of internal waves using the novel internal wave generator design of Gostiaux et al. (Exp. Fluids, vol. 42, 2007, pp. 123–130). This ...

  6. features Utility Generator

    E-Print Network [OSTI]

    Chang, Shih-Fu

    #12;#12;#12;#12;features function utility Training Pool Utility Generator Per-frame function content utility classes utility classes utility Tree Decision Generator Module Utility Clustering Adaptive

  7. High harmonic generation and attosecond pulse production in dense medium

    E-Print Network [OSTI]

    Becker, Andreas

    High harmonic generation and attosecond pulse production in dense medium v.v. Stre1kov1'2', V ABSTRACT We have studied the high harmonic generation and attosecond pulse production in a plasma or gas positions of the particles using the Monte-Carlo method. We observe a change of the harmonic properties due

  8. Distributed Generation Investment by a Microgrid under Uncertainty++++ Afzal Siddiqui

    E-Print Network [OSTI]

    Guillas, Serge

    1 Distributed Generation Investment by a Microgrid under Uncertainty++++ Afzal Siddiqui University, CA 94720-8163, USA, c_marnay@lbl.gov ABSTRACT. This paper examines a California-based microgrid-term natural gas generation cost is stochastic, we initially assume that the microgrid may purchase electricity

  9. Fuel Cells on Bio-Gas (Presentation)

    SciTech Connect (OSTI)

    Remick, R. J.

    2009-03-04

    The conclusions of this presentation are: (1) Fuel cells operating on bio-gas offer a pathway to renewable electricity generation; (2) With federal incentives of $3,500/kW or 30% of the project costs, reasonable payback periods of less than five years can be achieved; (3) Tri-generation of electricity, heat, and hydrogen offers an alternative route to solving the H{sub 2} infrastructure problem facing fuel cell vehicle deployment; and (4) DOE will be promoting bio-gas fuel cells in the future under its Market Transformation Programs.

  10. Novel yellowish-green emitting luminescence in Ca{sub 7}Si{sub 2}P{sub 2}O{sub 16}:Eu{sup 2+} phosphor

    SciTech Connect (OSTI)

    Wei, Donglei [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China); Interdisciplinary Program of LED and Solid State Lighting Engineering, Pukyong National University, Busan 608-737 (Korea, Republic of); Department of Physics, Pukyong National University, Busan 608-737 (Korea, Republic of); Huang, Yanlin, E-mail: huang@suda.edu.cn [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123 (China); Seo, Hyo Jin, E-mail: hjseo@pknu.ac.kr [Interdisciplinary Program of LED and Solid State Lighting Engineering, Pukyong National University, Busan 608-737 (Korea, Republic of); Department of Physics, Pukyong National University, Busan 608-737 (Korea, Republic of)

    2013-09-01

    Graphical abstract: The phosphor has two separated emission centers with the dependent emission intensity on Eu{sup 2+} doping. There is a red-shift in the emission due to energy transfer with increasing the Eu{sup 2+}-doping. - Highlights: • Green-origin-emitting phosphors of Eu{sup 2+}-doped Ca{sub 7}Si{sub 2}P{sub 2}O{sub 16} were firstly prepared by chemical sol–gel method. • The tunable luminescence color was realized by the changing Eu{sup 2+}-doping in Ca{sub 7}Si{sub 2}P{sub 2}O{sub 16}. • Ca{sub 7}Si{sub 2}P{sub 2}O{sub 16}:Eu{sup 2+} displays two typical luminescence centers with the emission depending on Eu{sup 2+} doping. • Eu{sup 2+}-doped Ca{sub 7}Si{sub 2}P{sub 2}O{sub 16} phosphor has an excellent thermal stability on the temperature quenching. - Abstract: Color tunable green-origin-emitting phosphor of Eu{sup 2+}-doped phosphate-silicate Ca{sub 7}Si{sub 2}P{sub 2}O{sub 16} was prepared by chemical sol–gel method. The X-ray powder diffraction, the photoluminescence excitation and emission spectra, time resolved spectra, and thermal stability were measured. The excitation spectra can well match with the emission light of near UV-LED chips (360–400 nm). The tunable luminescence was realized by changing Eu{sup 2+}-doping concentration. Ca{sub 7}Si{sub 2}P{sub 2}O{sub 16}:Eu{sup 2+} displays two typical luminescence centers, which were suggested to originate from two Ca{sup 2+} sites in the host. With increasing Eu{sup 2+} doping concentrations, the green emission band shifts to long wavelength. Energy transfer between the two different Eu{sup 2+} ions is discussed by analyzing the photoluminescence excitation and emission spectra, concentration-dependent luminescence intensity, and lifetimes. The dependence of the luminescence intensity of Ca{sub 7}Si{sub 2}P{sub 2}O{sub 16}:Eu{sup 2+} on temperatures was measured. The activation energy (?E) for thermal quenching was reported.

  11. Corner heating in rectangular solid oxide electrochemical cell generators

    DOE Patents [OSTI]

    Reichner, Philip (Plum Boro, PA)

    1989-01-01

    Disclosed is an improvement in a solid oxide electrochemical cell generator 1 having a rectangular design with four sides that meet at corners, and containing multiplicity of electrically connected fuel cells 11, where a fuel gas is passed over one side of said cells and an oxygen containing gas is passed into said cells, and said fuel is burned to form heat, electricity, and an exhaust gas. The improvement comprises passing the exhaust gases over the multiplicity of cells 11 in such a way that more of the heat in said exhaust gases flows at the corners of the generator, such as through channels 19.

  12. Supervisory Natural Gas Analyst

    Broader source: Energy.gov [DOE]

    The Department of Energys Office of Fossil Energy, Office of Oil and Natural Gas, Office of Oil and Gas Global Security and Supply (FE) is responsible for regulating natural gas imports and exports...

  13. Industrial Gas Turbines

    Broader source: Energy.gov [DOE]

    A gas turbine is a heat engine that uses high-temperature, high-pressure gas as the working fluid. Part of the heat supplied by the gas is converted directly into mechanical work. High-temperature,...

  14. Future of Natural Gas

    Energy Savers [EERE]

    of Natural Gas Bill Eisele, CEM SC Electric & Gas Co Hosted by: FEDERAL UTILITY PARTNERSHIP WORKING GROUP SEMINAR November 5-6, 2014 Cape Canaveral. Florida Agenda * Gas Facts *...

  15. Gas Kick Mechanistic Model 

    E-Print Network [OSTI]

    Zubairy, Raheel

    2014-04-18

    Gas kicks occur during drilling when the formation pressure is greater than the wellbore pressure causing influx of gas into the wellbore. Uncontrolled gas kicks could result in blowout of the rig causing major financial ...

  16. Generating Functions Introduction

    E-Print Network [OSTI]

    Gould, Ron

    CHAPTER 10 Ordinary Generating Functions Introduction We'll begin this chapter by introducing the notion of ordinary generating functions and discussing the basic techniques for manipulating them must master these basic ideas before reading further. In Section 2, we apply generating functions

  17. The Clemson First Generation

    E-Print Network [OSTI]

    Stuart, Steven J.

    The Clemson First Generation Success Program A First-RAte expeRience College is an experience college. First-generation college students are students whose parents do not hold a degree from a four-year college or university. Clemson is proud of its first- generation students and is committed

  18. Superconducting Power Generation

    E-Print Network [OSTI]

    Mario Rabinowitz

    2003-02-20

    The superconducting ac generator has the greatest potential for large-scale commercial application of superconductivity that can benefit the public. Electric power is a vital ingredient of modern society, and generation may be considered to be the vital ingredient of a power system. This articles gives background, and an insight into the physics and engineering of superconducting power generation.

  19. Mesh Generator Matthew Hanlon

    E-Print Network [OSTI]

    Nebel, Jean-Christophe

    1 Mesh Generator Matthew Hanlon 9804817 hanlonmj@dsc.gla.ac.uk Class CS4H Session 2002 from two dimensional slices. Medical data stored as sets of slices can be used to generate a three was developed with the following requirements: · Load a set of slices into the system · Generate a mesh for each

  20. On optimization of sensor selection for aircraft gas turbine engines Ramgopal Mushini

    E-Print Network [OSTI]

    Simon, Dan

    On optimization of sensor selection for aircraft gas turbine engines Ramgopal Mushini Cleveland sets for the problem of aircraft gas turbine engine health parameter estimation. The performance metric for generating an optimal sensor set [3]. 3. Aircraft gas turbine engines An aircraft gas turbine engine

  1. Detrending Daily Natural Gas Consumption Series to Improve Short-Term Forecasts

    E-Print Network [OSTI]

    Povinelli, Richard J.

    Detrending Daily Natural Gas Consumption Series to Improve Short-Term Forecasts Ronald H. Brown1 that allows long-term natural gas demand signals to be used effect- ively to generate high quality short-term natural gas demand forecasting models. Short data sets in natural gas forecasting inadequately represent

  2. LANDFILL-GAS-TO-ENERGY PROJECTS: AN ANALYSIS OF NET PRIVATE AND SOCIAL BENEFITS

    E-Print Network [OSTI]

    Jaramillo, Paulina

    Materials Table A1: Model Results for West Lake Landfill WEST LAKE IC Engine Gas Turbine Steam Turbine Landfill WEST COUNTY IC Engine Gas Turbine Steam Turbine Average Landfill Gas Generation (mmcf/yr) 1,075 1,735 $1,250 Table A3: Model Results for Modern Landfill MODERN IC Engine Gas Turbine Steam Turbine Average

  3. Development of the High-Pressure Direct-Injection ISX G Natural Gas Engine

    SciTech Connect (OSTI)

    Not Available

    2004-08-01

    Fact sheet details work by Cummins and Westport Innovations to develop a heavy-duty, low-NOx, high-pressure direct-injection natural gas engine for the Next Generation Natural Gas Vehicle activity.

  4. Experimental study of rotordynamic coefficients of squeeze film dampers of an aircraft gas turbine engine 

    E-Print Network [OSTI]

    Na, Uhn Joo

    1996-01-01

    The rotordynamic coefficients of squeeze film dampers of an aircraft gas turbine engine were investigated experimentally. Rotordynamic model(XLROTOR) for Gas Generator and Power Turbine were constructed. The XLROTOR response plots with changing...

  5. Development of fission gas swelling and release models for metallic nuclear fuels

    E-Print Network [OSTI]

    Andrews, Nathan Christopher

    2012-01-01

    Fuel swelling and fission gas generation for fast reactor fuels are of high importance since they are among the main limiting factors in the development of metallic fast reactor fuel. Five new fission gas and swelling ...

  6. Generator stator core vent duct spacer posts

    DOE Patents [OSTI]

    Griffith, John Wesley (Schenectady, NY); Tong, Wei (Clifton Park, NY)

    2003-06-24

    Generator stator cores are constructed by stacking many layers of magnetic laminations. Ventilation ducts may be inserted between these layers by inserting spacers into the core stack. The ventilation ducts allow for the passage of cooling gas through the core during operation. The spacers or spacer posts are positioned between groups of the magnetic laminations to define the ventilation ducts. The spacer posts are secured with longitudinal axes thereof substantially parallel to the core axis. With this structure, core tightness can be assured while maximizing ventilation duct cross section for gas flow and minimizing magnetic loss in the spacers.

  7. Flammable gas tank safety program: Technical basis for gas analysis and monitoring

    SciTech Connect (OSTI)

    Sherwood, D.J.

    1995-09-08

    Flammable gases generated in radioactive liquids. Twenty-five high level radioactive liquid waste storage tanks located underground at the Hanford Site are on a Flammable Gas Watch List because they contain waste which tends to retain the gases generated in it until rather large quantities are available for sudden release to the tank head space; if a tank is full it has little dome space, and a flammable concentration of gases could be produced--even if the tank is ventilated. If the waste has no tendency to retain gas generated in it then a continual flammable gas concentration in the tank dome space is established by the gas production rate and the tank ventilation rate (or breathing rate for unventilated tanks); this is also a potential problem for Flammable Gas Watch List tanks, and perhaps other Hanford tanks too. All Flammable Gas Watch List tanks will be fitted with Standard Hydorgen Monitoring Systems so that their behavior can be observed. In some cases, such as tank 241-SY-101, the data gathered from such observations will indicate that tank conditions need to be mitigated so that gas release events are either eliminated or rendered harmless. For example, a mixer pump was installed in tank 241-SY-101; operating the pump stirs the waste, replacing the large gas release events with small releases of gas that are kept below twenty-five percent of the lower flammability limit by the ventilation system. The concentration of hydrogen measured in Hanford waste tanks is greater than that of any other flammable gas. Hydrogen levels measured with a Standard Hydrogen Monitoring System in excess of 0.6 volume percent will cause Westinghouse Hanford Company to consider actions which will decrease the amount of flammable gas in the tank

  8. ,"Total Natural Gas Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas Consumption (billion cubic feet)",,,,,"Natural Gas Energy Intensity (cubic feetsquare foot)" ,"Total ","Space Heating","Water Heating","Cook- ing","Other","Total ","Space...

  9. Natural gas dehydration apparatus

    DOE Patents [OSTI]

    Wijmans, Johannes G; Ng, Alvin; Mairal, Anurag P

    2006-11-07

    A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.

  10. Motor/generator

    DOE Patents [OSTI]

    Hickam, Christopher Dale (Glasford, IL)

    2008-05-13

    A motor/generator is provided for connecting between a transmission input shaft and an output shaft of a prime mover. The motor/generator may include a motor/generator housing, a stator mounted to the motor/generator housing, a rotor mounted at least partially within the motor/generator housing and rotatable about a rotor rotation axis, and a transmission-shaft coupler drivingly coupled to the rotor. The transmission-shaft coupler may include a clamp, which may include a base attached to the rotor and a plurality of adjustable jaws.

  11. Plasma reforming and partial oxidation of hydrocarbon fuel vapor to produce synthesis gas and/or hydrogen gas

    DOE Patents [OSTI]

    Kong, Peter C.; Detering, Brent A.

    2003-08-19

    Methods and systems for treating vapors from fuels such as gasoline or diesel fuel in an internal combustion engine, to form hydrogen gas or synthesis gas, which can then be burned in the engine to produce more power. Fuel vapor, or a mixture of fuel vapor and exhaust gas and/or air, is contacted with a plasma, to promote reforming reactions between the fuel vapor and exhaust gas to produce carbon monoxide and hydrogen gas, partial oxidation reactions between the fuel vapor and air to produce carbon monoxide and hydrogen gas, or direct hydrogen and carbon particle production from the fuel vapor. The plasma can be a thermal plasma or a non-thermal plasma. The plasma can be produced in a plasma generating device which can be preheated by contact with at least a portion of the hot exhaust gas stream, thereby decreasing the power requirements of the plasma generating device.

  12. Plasma Reforming And Partial Oxidation Of Hydrocarbon Fuel Vapor To Produce Synthesis Gas And/Or Hydrogen Gas

    DOE Patents [OSTI]

    Kong, Peter C. (Idaho Falls, ID); Detering, Brent A. (Idaho Falls, ID)

    2004-10-19

    Methods and systems are disclosed for treating vapors from fuels such as gasoline or diesel fuel in an internal combustion engine, to form hydrogen gas or synthesis gas, which can then be burned in the engine to produce more power. Fuel vapor, or a mixture of fuel vapor and exhaust gas and/or air, is contacted with a plasma, to promote reforming reactions between the fuel vapor and exhaust gas to produce carbon monoxide and hydrogen gas, partial oxidation reactions between the fuel vapor and air to produce carbon monoxide and hydrogen gas, or direct hydrogen and carbon particle production from the fuel vapor. The plasma can be a thermal plasma or a non-thermal plasma. The plasma can be produced in a plasma generating device which can be preheated by contact with at least a portion of the hot exhaust gas stream, thereby decreasing the power requirements of the plasma generating device.

  13. Promoting electricity from renewable energy sources -- lessons learned from the EU, U.S. and Japan

    E-Print Network [OSTI]

    Haas, Reinhard

    2008-01-01

    cost disadvantage compared to electricity generated from fossil or nuclear fuels 2 . A significant switch to a renewable energy

  14. NATURAL GAS RESOURCES IN DEEP SEDIMENTARY BASINS

    SciTech Connect (OSTI)

    Thaddeus S. Dyman; Troy Cook; Robert A. Crovelli; Allison A. Henry; Timothy C. Hester; Ronald C. Johnson; Michael D. Lewan; Vito F. Nuccio; James W. Schmoker; Dennis B. Riggin; Christopher J. Schenk

    2002-02-05

    From a geological perspective, deep natural gas resources are generally defined as resources occurring in reservoirs at or below 15,000 feet, whereas ultra-deep gas occurs below 25,000 feet. From an operational point of view, ''deep'' is often thought of in a relative sense based on the geologic and engineering knowledge of gas (and oil) resources in a particular area. Deep gas can be found in either conventionally-trapped or unconventional basin-center accumulations that are essentially large single fields having spatial dimensions often exceeding those of conventional fields. Exploration for deep conventional and unconventional basin-center natural gas resources deserves special attention because these resources are widespread and occur in diverse geologic environments. In 1995, the U.S. Geological Survey estimated that 939 TCF of technically recoverable natural gas remained to be discovered or was part of reserve appreciation from known fields in the onshore areas and State waters of the United. Of this USGS resource, nearly 114 trillion cubic feet (Tcf) of technically-recoverable gas remains to be discovered from deep sedimentary basins. Worldwide estimates of deep gas are also high. The U.S. Geological Survey World Petroleum Assessment 2000 Project recently estimated a world mean undiscovered conventional gas resource outside the U.S. of 844 Tcf below 4.5 km (about 15,000 feet). Less is known about the origins of deep gas than about the origins of gas at shallower depths because fewer wells have been drilled into the deeper portions of many basins. Some of the many factors contributing to the origin of deep gas include the thermal stability of methane, the role of water and non-hydrocarbon gases in natural gas generation, porosity loss with increasing thermal maturity, the kinetics of deep gas generation, thermal cracking of oil to gas, and source rock potential based on thermal maturity and kerogen type. Recent experimental simulations using laboratory pyrolysis methods have provided much information on the origins of deep gas. Technologic problems are one of the greatest challenges to deep drilling. Problems associated with overcoming hostile drilling environments (e.g. high temperatures and pressures, and acid gases such as CO{sub 2} and H{sub 2}S) for successful well completion, present the greatest obstacles to drilling, evaluating, and developing deep gas fields. Even though the overall success ratio for deep wells is about 50 percent, a lack of geological and geophysical information such as reservoir quality, trap development, and gas composition continues to be a major barrier to deep gas exploration. Results of recent finding-cost studies by depth interval for the onshore U.S. indicate that, on average, deep wells cost nearly 10 times more to drill than shallow wells, but well costs and gas recoveries vary widely among different gas plays in different basins. Based on an analysis of natural gas assessments, many topical areas hold significant promise for future exploration and development. One such area involves re-evaluating and assessing hypothetical unconventional basin-center gas plays. Poorly-understood basin-center gas plays could contain significant deep undiscovered technically-recoverable gas resources.

  15. Overview: Gas hydrate geology and geography

    SciTech Connect (OSTI)

    Malone, R.D.

    1993-01-01

    Several geological factors which are directly responsible for the presence or absence of gas hydrates have been reviewed and are: tectonic position of the region; sedimentary environments; structural deformation; shale diapirism; hydrocarbon generation and migration; thermal regime in the hydrate formation zone (HFZ); pressure conditions; and hydrocarbon gas supply to the HFZ. Work on gas hydrate formation in the geological environment has made significant advances, but there is still much to be learned. Work is continuing in the deeper offshore areas through the Ocean Drilling Program, Government Agencies, and Industry. The pressure/temperature conditions necessary for formation has been identified for various compositions of natural gas through laboratory investigations and conditions for formation are being advanced through drilling in areas where gas hydrates exist.

  16. Overview: Gas hydrate geology and geography

    SciTech Connect (OSTI)

    Malone, R.D.

    1993-06-01

    Several geological factors which are directly responsible for the presence or absence of gas hydrates have been reviewed and are: tectonic position of the region; sedimentary environments; structural deformation; shale diapirism; hydrocarbon generation and migration; thermal regime in the hydrate formation zone (HFZ); pressure conditions; and hydrocarbon gas supply to the HFZ. Work on gas hydrate formation in the geological environment has made significant advances, but there is still much to be learned. Work is continuing in the deeper offshore areas through the Ocean Drilling Program, Government Agencies, and Industry. The pressure/temperature conditions necessary for formation has been identified for various compositions of natural gas through laboratory investigations and conditions for formation are being advanced through drilling in areas where gas hydrates exist.

  17. Photochemical Heating of Dense Molecular Gas

    E-Print Network [OSTI]

    Glassgold, A E

    2015-01-01

    Photochemical heating is analyzed with emphasis on the heating generated by chemical reactions initiated by the products of photodissociation and photoionization. The immediate products are slowed down by collisions with the ambient gas and heat the gas. In addition to this direct process, heating is also produced by the subsequent chemical reactions initiated by these products. Some of this chemical heating comes from the kinetic energy of the reaction products and the rest from collisional de-excitation of the product atoms and molecules. In considering dense gas dominated by molecular hydrogen, we find that the chemical heating is sometimes as large if not much larger than the direct heating. In very dense gas the total photochemical heating approaches 10 eV per photodissociation (or photoionization), competitive with other ways of heating molecular gas.

  18. Solvothermal synthesis and tunable luminescence of Tb{sup 3+}, Eu{sup 3+} codoped YF{sub 3} nano- and micro-crystals with uniform morphologies

    SciTech Connect (OSTI)

    Tian, Yue [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China) [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China); College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China); Chen, Baojiu, E-mail: chenmbj@sohu.com [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China)] [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China); Li, Xiangping; Zhang, Jinsu; Tian, Bining; Sun, Jiashi; Cheng, Lihong; Zhong, Haiyang; Zhong, Hua [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China)] [Department of Physics, Dalian Maritime University, Dalian, Liaoning 116026 (China); Hua, Ruinian, E-mail: rnhua@dlnu.edu.cn [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China)] [College of Life Science, Dalian Nationalities University, Dalian, Liaoning 116600 (China)

    2012-12-15

    Tb{sup 3+}, Eu{sup 3+} codoped YF{sub 3} nano- and micro-crystals with the morphologies of ellipsoid-like nanoplate, spindle, sandwich-structural rhombus and nanoaggregate were synthesized through a solvothermal method. The morphologies of the prepared products can be tailored by controlling the volume ratio of ethylene glycol (EG) to H{sub 2}O, solvent type or the reaction time. A possible formation mechanism of the sandwich-structural rhombus like YF{sub 3} phosphor was proposed. The emitting colors of YF{sub 3}:Tb{sup 3+},Eu{sup 3+} phosphors can be easily tuned from yellowish green, yellow to orange by increasing Eu{sup 3+} concentration. The energy transfer from Tb{sup 3+} to Eu{sup 3+} in YF{sub 3} phosphors was studied. It was found that the interaction type between Tb{sup 3+} and Eu{sup 3+} is electric dipole-dipole interaction. - Graphical abstract: Sandwich-structural rhombus like YF{sub 3}:Tb{sup 3+}, Eu{sup 3+} phosphors were synthesized through a solvothermal process. The formation mechanism of the sandwich-structural rhombus like YF{sub 3}:Tb{sup 3+}, Eu{sup 3+} phosphors was studied. Highlights: Black-Right-Pointing-Pointer YF{sub 3} nano- and micro-crystals were synthesized through solvothermal route. Black-Right-Pointing-Pointer A formation mechanism of the sandwich-structural rhombus like YF{sub 3} was proposed. Black-Right-Pointing-Pointer The emitting colors of YF{sub 3}:Tb{sup 3+},Eu{sup 3+} phosphors can be tuned. Black-Right-Pointing-Pointer Energy transfer from Tb{sup 3+} to Eu{sup 3+} is confirmed as electric dipole-dipole interaction.

  19. Morphology of Gas Release in Physical Simulants

    SciTech Connect (OSTI)

    Daniel, Richard C.; Burns, Carolyn A.; Crawford, Amanda D.; Hylden, Laura R.; Bryan, Samuel A.; MacFarlan, Paul J.; Gauglitz, Phillip A.

    2014-07-03

    This report documents testing activities conducted as part of the Deep Sludge Gas Release Event Project (DSGREP). The testing described in this report focused on evaluating the potential retention and release mechanisms of hydrogen bubbles in underground radioactive waste storage tanks at Hanford. The goal of the testing was to evaluate the rate, extent, and morphology of gas release events in simulant materials. Previous, undocumented scoping tests have evidenced dramatically different gas release behavior from simulants with similar physical properties. Specifically, previous gas release tests have evaluated the extent of release of 30 Pa kaolin and 30 Pa bentonite clay slurries. While both materials are clays and both have equivalent material shear strength using a shear vane, it was found that upon stirring, gas was released immediately and completely from bentonite clay slurry while little if any gas was released from the kaolin slurry. The motivation for the current work is to replicate these tests in a controlled quality test environment and to evaluate the release behavior for another simulant used in DSGREP testing. Three simulant materials were evaluated: 1) a 30 Pa kaolin clay slurry, 2) a 30 Pa bentonite clay slurry, and 3) Rayleigh-Taylor (RT) Simulant (a simulant designed to support DSGREP RT instability testing. Entrained gas was generated in these simulant materials using two methods: 1) application of vacuum over about a 1-minute period to nucleate dissolved gas within the simulant and 2) addition of hydrogen peroxide to generate gas by peroxide decomposition in the simulants over about a 16-hour period. Bubble release was effected by vibrating the test material using an external vibrating table. When testing with hydrogen peroxide, gas release was also accomplished by stirring of the simulant.

  20. Integrated production of fuel gas and oxygenated organic compounds from synthesis gas

    DOE Patents [OSTI]

    Moore, Robert B. (Allentown, PA); Hegarty, William P. (State College, PA); Studer, David W. (Wescosville, PA); Tirados, Edward J. (Easton, PA)

    1995-01-01

    An oxygenated organic liquid product and a fuel gas are produced from a portion of synthesis gas comprising hydrogen, carbon monoxide, carbon dioxide, and sulfur-containing compounds in a integrated feed treatment and catalytic reaction system. To prevent catalyst poisoning, the sulfur-containing compounds in the reactor feed are absorbed in a liquid comprising the reactor product, and the resulting sulfur-containing liquid is regenerated by stripping with untreated synthesis gas from the reactor. Stripping offgas is combined with the remaining synthesis gas to provide a fuel gas product. A portion of the regenerated liquid is used as makeup to the absorber and the remainder is withdrawn as a liquid product. The method is particularly useful for integration with a combined cycle coal gasification system utilizing a gas turbine for electric power generation.