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1

RESULTS OF CESIUM MASS TRANSFER TESTING FOR NEXT GENERATION SOLVENT WITH HANFORD WASTE SIMULANT AP-101  

SciTech Connect (OSTI)

SRNL has performed an Extraction, Scrub, Strip (ESS) test using the next generation solvent and AP-101 Hanford Waste simulant. The results indicate that the next generation solvent (MG solvent) has adequate extraction behavior even in the face of a massive excess of potassium. The stripping results indicate poorer behavior, but this may be due to inadequate method detection limits. SRNL recommends further testing using hot tank waste or spiked simulant to provide for better detection limits. Furthermore, strong consideration should be given to performing an actual waste, or spiked waste demonstration using the 2cm contactor bank. The Savannah River Site currently utilizes a solvent extraction technology to selectively remove cesium from tank waste at the Multi-Component Solvent Extraction unit (MCU). This solvent consists of four components: the extractant - BoBCalixC6, a modifier - Cs-7B, a suppressor - trioctylamine, and a diluent, Isopar L{trademark}. This solvent has been used to successfully decontaminate over 2 million gallons of tank waste. However, recent work at Oak Ridge National Laboratory (ORNL), Argonne National Laboratory (ANL), and Savannah River National Laboratory (SRNL) has provided a basis to implement an improved solvent blend. This new solvent blend - referred to as Next Generation Solvent (NGS) - is similar to the current solvent, and also contains four components: the extractant - MAXCalix, a modifier - Cs-7B, a suppressor - LIX-79{trademark} guanidine, and a diluent, Isopar L{trademark}. Testing to date has shown that this 'Next Generation' solvent promises to provide far superior cesium removal efficiencies, and furthermore, is theorized to perform adequately even in waste with high potassium concentrations such that it could be used for processing Hanford wastes. SRNL has performed a cesium mass transfer test in to confirm this behavior, using a simulant designed to simulate Hanford AP-101 waste.

Peters, T.; Washington, A.; Fink, S.

2011-09-27T23:59:59.000Z

2

Single Stage Contactor Testing Of The Next Generation Solvent Blend  

SciTech Connect (OSTI)

The Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU) facility at the Savannah River Site (SRS) is actively pursuing the transition from the current BOBCalixC6 based solvent to the Next Generation Solvent (NGS)-MCU solvent to increase the cesium decontamination factor. To support this integration of NGS into the MCU facility the Savannah River National Laboratory (SRNL) performed testing of a blend of the NGS (MaxCalix based solvent) with the current solvent (BOBCalixC6 based solvent) for the removal of cesium (Cs) from the liquid salt waste stream. This testing utilized a blend of BOBCalixC6 based solvent and the NGS with the new extractant, MaxCalix, as well as a new suppressor, tris(3,7dimethyloctyl) guanidine. Single stage tests were conducted using the full size V-05 and V-10 liquid-to-liquid centrifugal contactors installed at SRNL. These tests were designed to determine the mass transfer and hydraulic characteristics with the NGS solvent blended with the projected heel of the BOBCalixC6 based solvent that will exist in MCU at time of transition. The test program evaluated the amount of organic carryover and the droplet size of the organic carryover phases using several analytical methods. The results indicate that hydraulically, the NGS solvent performed hydraulically similar to the current solvent which was expected. For the organic carryover 93% of the solvent is predicted to be recovered from the stripping operation and 96% from the extraction operation. As for the mass transfer, the NGS solvent significantly improved the cesium DF by at least an order of magnitude when extrapolating the One-stage results to actual Seven-stage extraction operation with a stage efficiency of 95%.

Herman, D. T.; Peters, T. B.; Duignan, M. R.; Williams, M. R.; Poirier, M. R.; Brass, E. A.; Garrison, A. G.; Ketusky, E. T.

2014-01-06T23:59:59.000Z

3

Development of a Novel Solvent for the Simultaneous Separation of Strontium and Cesium from Acidic Solutions  

SciTech Connect (OSTI)

A synergistic extraction solvent for the simultaneous removal of cesium and strontium from acidic solutions has been investigated. The extraction solvent consists of, 4,4',(5')-di-(t-butyldicyclo-hexano)-18-crown-6 (DtBuCH18C6), calix[4]arene-bis-(tert-octylbenzo-crown-6) (BOBCalixC6), and 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol (Cs-7SB modifier) in a branched aliphatic kerosene (Isopar® L). Extraction synergy for strontium was observed when DtBuCH18C6 was combined with the BOBCalixC6 cesium extractant solvent and Cs-7SB modifier or if the Cs-7SB modifier was substituted into the SREX (Strontium Extraction) solvent in place of TBP. The novel process extracted both cesium and strontium simultaneously from 1 M nitric acid solutions with distribution ratios of 8.8 and 7.7 for strontium and cesium, respectively, at ambient temperature. Distribution coefficients for cesium and strontium as a function of nitric acid concentration and temperature were also obtained with 0.5 M<[HNO3]<2.5 M giving favorable distribution ratios. This new process utilizing the combined solvent has been named the Fission Product Extraction Process (FPEX).

Catherine L. Riddle; John D. Baker; Jack D. Law; Christopher A. McGrath; David H. Meikrantz; Bruce J. Mincher; Dean R. Peterman; Terry A. Todd

2005-03-01T23:59:59.000Z

4

RESULTS OF ANALYSES OF THE NEXT GENERATION SOLVENT FOR PARSONS  

SciTech Connect (OSTI)

Savannah River National Laboratory (SRNL) prepared a nominal 150 gallon batch of Next Generation Solvent (NGS) for Parsons. This material was then analyzed and tested for cesium mass transfer efficiency. The bulk of the results indicate that the solvent is qualified as acceptable for use in the upcoming pilot-scale testing at Parsons Technology Center. This report describes the analysis and testing of a batch of Next Generation Solvent (NGS) prepared in support of pilot-scale testing in the Parsons Technology Center. A total of {approx}150 gallons of NGS solvent was prepared in late November of 2011. Details for the work are contained in a controlled laboratory notebook. Analysis of the Parsons NGS solvent indicates that the material is acceptable for use. SRNL is continuing to improve the analytical method for the guanidine.

Peters, T.; Washington, A.; Fink, S.

2012-03-12T23:59:59.000Z

5

Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions  

DOE Patents [OSTI]

A solvent composition and corresponding method for extracting cesium (Cs) from aqueous neutral and alkaline solutions containing Cs and perhaps other competing metal ions is described. The method entails contacting an aqueous Cs-containing solution with a solvent consisting of a specific class of lipophilic calix[4]arene-crown ether extractants dissolved in a hydrocarbon-based diluent containing a specific class of alkyl-aromatic ether alcohols as modifiers. The cesium values are subsequently recovered from the extractant, and the solvent subsequently recycled, by contacting the Cs-containing organic solution with an aqueous stripping solution. This combined extraction and stripping method is especially useful as a process for removal of the radionuclide cesium-137 from highly alkaline waste solutions which are also very concentrated in sodium and potassium. No pre-treatment of the waste solution is necessary, and the cesium can be recovered using a safe and inexpensive stripping process using water, dilute (millimolar) acid solutions, or dilute (millimolar) salt solutions. An important application for this invention would be treatment of alkaline nuclear tank wastes. Alternatively, the invention could be applied to decontamination of acidic reprocessing wastes containing cesium-137.

Moyer, Bruce A. (Oak Ridge, TN); Sachleben, Richard A. (Knoxville, TN); Bonnesen, Peter V. (Knoxville, TN); Presley, Derek J. (Ooltewah, TN)

2001-01-01T23:59:59.000Z

6

CHEMICAL STABILITY OF POLYPHENYLENE SULFIDE IN THE NEXT GENERATION SOLVENT FOR CAUSTIC-SIDE SOLVENT EXTRACTION  

SciTech Connect (OSTI)

The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. For simplicity, this solvent is referred to as the Next Generation Solvent (NGS). The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The initial deployment target envisioned for the technology was within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with polyphenylene sulfide (PPS), the polymer used in the coalescers within MCU. This report provides the data from exposing PPS polymer to NGS. The test was conducted over a three month period. PPS is remarkably stable in the presence of the next generation solvent. Testing showed no indication of swelling or significant leaching. Preferential sorption of the Modifier on PPS was observed but the same behavior occurs with the baseline solvent. Therefore, PPS coalescers exposed to the NGS are expected to perform comparably to those in contact with the baseline solvent.

Fondeur, F.; Fink, S.

2011-12-08T23:59:59.000Z

7

Cesium and strontium extraction using a mixed extractant solvent including crown ether and calixarene extractants  

DOE Patents [OSTI]

A mixed extractant solvent including calix[4]arene-bis-(tert-octylbenzo)-crown-6 ("BOBCalixC6"), 4',4',(5')-di-(t-butyldicyclo-hexano)-18-crown-6 ("DtBu18C6"), and at least one modifier dissolved in a diluent. The mixed extractant solvent may be used to remove cesium and strontium from an acidic solution. The DtBu18C6 may be present from approximately 0.01 M to approximately 0.4M, such as from approximately 0.086 M to approximately 0.108 M. The modifier may be 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol ("Cs-7SB") and may be present from approximately 0.01M to approximately 0.8M. In one embodiment, the mixed extractant solvent includes approximately 0.15M DtBu18C6, approximately 0.007M BOBCalixC6, and approximately 0.75M Cs-7SB modifier dissolved in an isoparaffinic hydrocarbon diluent. The mixed extractant solvent may form an organic phase in an extraction system that also includes an aqueous phase. Methods of extracting cesium and strontium as well as strontium alone are also disclosed.

Meikrantz, David H. (Idaho Falls, ID); Todd, Terry A. (Aberdeen, ID); Riddle, Catherine L. (Idaho Falls, ID); Law, Jack D. (Pocatello, ID); Peterman, Dean R. (Idaho Falls, ID); Mincher, Bruce J. (Idaho Falls, ID); McGrath, Christopher A. (Blackfoot, ID); Baker, John D. (Blackfoot, ID)

2007-11-06T23:59:59.000Z

8

NEXT GENERATION SOLVENT MATERIALS COMPATIBILITY WITH POLYMER COMPONENTS WITHIN MODULAR CAUSTIC-SIDE SOLVENT EXTRACTION UNIT  

SciTech Connect (OSTI)

The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The first deployment target for the technology is within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with organic polymers used in the facility. This report provides the data from exposing these polymers to the Next Generation Solvent (NGS). The test was conducted over six months. An assessment of the dimensional stability of polymers present in MCU (i.e., PEEK, Grafoil{reg_sign}, Tefzel{reg_sign} and Isolast{reg_sign}) in the modified NGS (where the concentration of the guanidine suppressor and MaxCalix was varied systematically) showed that guanidine (LIX{reg_sign}79) selectively affected Tefzel{reg_sign} (by an increase in size and lowering its density). The copolymer structure of Tefzel{reg_sign} and possibly its porosity allows for the easier diffusion of guanidine. Tefzel{reg_sign} is used as the seat material in some of the valves at MCU. Long term exposure to guanidine, may make the valves hard to operate over time due to the seat material (Tefzel{reg_sign}) increasing in size. However, since the physical changes of Tefzel{reg_sign} in the improved solvent are comparable to the changes in the CSSX baseline solvent, no design changes are needed with respect to the Tefzel{reg_sign} seating material. PEEK, Grafoil{reg_sign} and Isolast{reg_sign} were not affected by guanidine and MaxCalix within six months of exposure. The initial rapid weight gain observed in every polymer is assigned to the finite and limited uptake of Isopar{reg_sign} L/Modifier by the polymers probably due to the polymers porosity and rough surfaces. Spectroscopic data on the organic liquid and the polymer surfaces showed no preferential adsorption of any component in the NGS to the polymers and no leachate was observed in the NGS from any of the polymers studied.

Fondeur, F.; Peters, T.; Fink, S.

2011-09-29T23:59:59.000Z

9

PERFORMANCE TESTING OF THE NEXT-GENERATION CSSX SOLVENT WITH ACTUAL SRS TANK WASTE  

SciTech Connect (OSTI)

Efforts are underway to qualify the Next-Generation Solvent for the Caustic Side Solvent Extraction (CSSX) process. Researchers at multiple national laboratories have been involved in this effort. As part of the effort to qualify the solvent extraction system at the Savannah River Site (SRS), SRNL performed a number of tests at various scales. First, SRNL completed a series of batch equilibrium, or Extraction-Scrub-Strip (ESS), tests. These tests used {approx}30 mL of Next-Generation Solvent and either actual SRS tank waste, or waste simulant solutions. The results from these cesium mass transfer tests were used to predict solvent behavior under a number of conditions. At a larger scale, SRNL assembled 12 stages of 2-cm (diameter) centrifugal contactors. This rack of contactors is structurally similar to one tested in 2001 during the demonstration of the baseline CSSX process. Assembly and mechanical testing found no issues. SRNL performed a nonradiological test using 35 L of cesium-spiked caustic waste simulant and 39 L of actual tank waste. Test results are discussed; particularly those related to the effectiveness of extraction.

Pierce, R.; Peters, T.; Crowder, M.; Fink, S.

2011-11-01T23:59:59.000Z

10

Preparation and use of tetra-alkyl cobalt dicarbollide for extraction of cesium and strontium into hydrocarbon solvents  

DOE Patents [OSTI]

Preparation and use of tetra-C-alkyl cobalt dicarbollide for extraction of cesium and strontium into hydrocarbon solvents. Tetra-C-alkyl derivatives of cobalt dicarbollide, Co(C.sub.2 R.sub.2 B.sub.9 H.sub.9).sub.2.sup.- (CoB.sub.2 R.sub.4.sup.- ; R=CH.sub.3 and C.sub.6 H.sub.13) are demonstrated to be significant cesium and strontium extractants from acidic and alkaline solutions into non-toxic organic solvent systems. Extractions using mesitylene and diethylbenzene are compared to those with nitrobenzene as the organic phase. CoB.sub.2 -hexyl.sub.4.sup.- in diethylbenzene shows improved selectivity (10.sup.4) for Cs over Na in acidic solution. In dilute alkaline solution, CoB.sub.2 -hexyl.sub.4.sup.- extracts Cs less efficiently, but more effectively removes Sr from higher base concentrations. A general synthesis of tetra-C-alkyl cobalt dicarbollides is described.

Miller, Rebecca L. (Los Alamos, NM); Pinkerton, Anthony B. (Santa Fe, NM); Abney, Kent D. (Los Alamos, NM); Kinkead, Scott A. (Los Alamos, NM)

1997-01-01T23:59:59.000Z

11

Evaluation of an alkaline-side solvent extraction process for cesium removal from SRS tank waste using laboratory-scale centrifugal contactors  

SciTech Connect (OSTI)

An alkaline-side solvent extraction process for cesium removal from Savannah River Site (SRS) tank waste was evaluated experimentally using a laboratory-scale centrifugal contactor. Single-stage and multistage tests were conducted with this contactor to determine hydraulic performance, stage efficiency, and general operability of the process flowsheet. The results and conclusions of these tests are reported along with those from various supporting tests. Also discussed is the ability to scale-up from laboratory- to plant-scale operation when centrifugal contractors are used to carry out the solvent extraction process. While some problems were encountered, a promising solution for each problem has been identified. Overall, this alkaline-side cesium extraction process appears to be an excellent candidate for removing cesium from SRS tank waste.

Leonard, R. A.; Conner, C.; Liberatore, M. W.; Sedlet, J.; Aase, S. B.; Vandegrift, G. F.

1999-11-29T23:59:59.000Z

12

Solvent Effects on Cesium Complexation with Crown Ethers from Liquid to Supercritical Fluids  

SciTech Connect (OSTI)

Nuclear magnetic resonance (NMR) techniques were used to study crown ether-water interactions in solvents of low dielectric constants such as chloroform and carbon tetrachloride. Water forms a 1:1 complex with a number of crown ethers including 12-crown-4, 15-crown-5, 18-crown-6, dicyclohexano-18=crown-6, dicyclohexano-24-crown 8, and dibenzl-24-crown-8 in chloroform. Among these crown ethers, the 18-crown-6-H2 complex has the largest equilibrium constant (K=545) and 97% of the crown is complexed to water in chloroform. Addition of carbon tetrachloride to chloroform lowers the equilibrium constants of the crown-water complexes. The partition coefficients of crown ethers (D=crown in water/crown in solvent) between water and organic solvent also vary with solvent composition.

Chien M. Wai; Anne Rustenholtz; Shaofen Wang; Su-Chen Lee; Jamie Herman; Richard A. Porter

2004-03-15T23:59:59.000Z

13

NEXT GENERATION SOLVENT-MATERIALS COMPATIBILITY WITH POLYMER COMPONENTS WITHIN MODULAR CAUSTIC-SIDE SOLVENT EXTRACTION UNIT (FINAL REPORT)  

SciTech Connect (OSTI)

The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent for deployment at the Savannah River Site for removal of cesium from High Level Waste. The technical effort is collaboration between Oak Ridge National Laboratory (ORNL), Savannah River National Laboratory (SRNL), and Argonne National Laboratory. The first deployment target for the technology is within the Modular Caustic-Side Solvent Extraction Unit (MCU). Deployment of a new chemical within an existing facility requires verification that the chemical components are compatible with the installed equipment. In the instance of a new organic solvent, the primary focus is on compatibility of the solvent with organic polymers used in the facility. This report provides the data from exposing these polymers to the Next Generation Solvent (NGS). The test was conducted over six months. An assessment of the dimensional stability of polymers present in MCU (i.e., PEEK, Grafoil, Tefzel and Isolast) in the modified NGS (where the concentration of LIX{reg_sign}79 and MaxCalix was varied systematically) showed that LIX{reg_sign}79 selectively affected Tefzel and its different grades (by an increase in size and lowering its density). The copolymer structure of Tefzel and possibly its porosity allows for the easier diffusion of LIX{reg_sign}79. Tefzel is used as the seat material in some of the valves at MCU. Long term exposure to LIX{reg_sign}79, may make the valves hard to operate over time due to the seat material (Tefzel) increasing in size. However, since the physical changes of Tefzel in the improved solvent are comparable to the changes in the CSSX baseline solvent, no design changes are needed with respect to the Tefzel seating material. PEEK, Grafoil and Isolast were not affected by LIX{reg_sign}79 and MaxCalix within six months of exposure. The initial rapid weight gain observed in every polymer is assigned to the finite and limited uptake of Isopar{reg_sign} L/Modifier by the polymers probably due to the polymers porosity and rough surfaces. Spectroscopic data on the organic liquid and the polymer surfaces showed no preferential adsorption of any component in the NGS to the polymers and with the exception of CPVC, no leachate was observed in the NGS from any of the polymers studied. The testing shows no major concerns for compatibility over the short duration of these tests but does indicate that longer duration exposure studies are warranted, especially for Tefzel. However, the physical changes experienced by Tefzel in the improved solvent were comparable to the physical changes obtained when Tefzel is placed in CSSX baseline solvent. Therefore, there is no effect of the improved solvent beyond those observed in CSSX baseline solvent.

Fondeur, F.; Peters, T.; Fink, S.

2012-01-17T23:59:59.000Z

14

INVESTIGATION OF PLUTONIUM AND URANIUM UPTAKE INTO MCU SOLVENT AND NEXT GENERATION SOLVENT  

SciTech Connect (OSTI)

At the request of the Savannah River Remediation (SRR) customer, the Savannah River National Laboratory (SRNL) examined the plutonium (Pu) and uranium (U) uptake into the Next Generation Solvent (NGS) that will be used at the Salt Waste Processing Facility (SWPF). SRNL examined archived samples of solvent used in Extraction-Scrub-Strip (ESS) tests, as well as samples from new tests designed explicitly to examine the Pu and U uptake. Direct radiocounting for Pu and U provided the best results. Using the radiocounting results, we found that in all cases there were <3.41E-12 g Pu/g of NGS and <1.17E-05 g U/g of NGS in multiple samples, even after extended contact times and high aqueous:organic volume phase ratios. These values are conservative as they do not allow for release or removal of the actinides by scrub, strip, or solvent wash processes. The values do not account for extended use or any increase that may occur due to radiolytic damage of the solvent.

Peters, T.; Fink, S.

2012-01-06T23:59:59.000Z

15

Development of a novel solvent for the simultaneous separation of strontium and cesium from dissolved Spent Nuclear Fuel solutions  

SciTech Connect (OSTI)

The recovery of Cs and Sr from acidic solutions by solvent extraction has been investigated. The goal of this project was to develop an extraction process to remove Cs and Sr from high-level waste in an effort to reduce the heat loading in storage. Solvents for the extraction of Cs and Sr separately have been used on both caustic and acidic spent nuclear fuel waste in the past. The objective of this research was to find a suitable solvent for the extraction of both Cs and Sr simultaneously from acidic nitrate media. The solvents selected for this research possess good stability and extraction behavior when mixed together. The extraction experiments were performed with 4 ,4,(5 )-Di-(tbutyldicyclohexano)- 18-crown-6 {DtBuCH18C6}, Calix[4]arene-bis-(tert-octylbenzocrown-6) {BOBCalixC6} and 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol {Cs-7SB modifier} in a branched aliphatic kerosene {Isopar® L}. The BOBCalixC6 and Cs-7SB modifier were developed at Oak Ridge National Laboratory (ORNL) by Bonnesen et al. [1]. The values obtained from the SREX solvent for DSr in 1 M nitric acid ranged from 0.7 to 2.2 at 25oC and 10oC respectively. The values for DCs in 1 M nitric acid with the CSSX solvent ranged from 8.0 to 46.0 at 25oC and 10oC respectively. A new mixed solvent, developed at the Idaho National Engineering and Environmental Laboratory (INEEL) by Riddle et al. [2], showed distributions for Sr ranging from 8.8 to 17.4 in 1 M nitric acid at 25oC and 10oC respectively. The DCs for the mixed solvent ranged from 7.7 to 20.2 in 1 M nitric acid at 25oC to 10oC respectively. The unexpectedly high distributions for Sr at both 25oC and 10oC show a synergy in the mixed solvent. The DCs, although lower than with CSSX solvent, still showed good extraction behavior.

Catherine L. Riddle; John D. Baker; Jack D. Law; Christopher A. McGrath; David H. Meikrantz; Bruce J. Mincher; Dean R. Peterman; Terry A. Todd

2004-10-01T23:59:59.000Z

16

DEMONSTRATION OF THE NEXT-GENERATION CAUSTIC-SIDE SOLVENT EXTRACTION SOLVENT WITH 2-CM CENTRIGUGAL CONTRACTORS USING TANK 49H WASTE AND WASTE SIMULANT  

SciTech Connect (OSTI)

Researchers successfully demonstrated the chemistry and process equipment of the Caustic-Side Solvent Extraction (CSSX) flowsheet using MaxCalix for the decontamination of high level waste (HLW). The demonstration was completed using a 12-stage, 2-cm centrifugal contactor apparatus at the Savannah River National Laboratory (SRNL). This represents the first CSSX process demonstration of the MaxCalix solvent system with Savannah River Site (SRS) HLW. Two tests lasting 24 and 27 hours processed non-radioactive simulated Tank 49H waste and actual Tank 49H HLW, respectively. A solvent extraction system for removal of cesium from alkaline solutions was developed utilizing a novel solvent invented at the Oak Ridge National Laboratory (ORNL). This solvent consists of a calix[4]arene-crown-6 extractant dissolved in an inert hydrocarbon matrix. A modifier is added to the solvent to enhance the extraction power of the calixarene and to prevent the formation of a third phase. An additional additive is used to improve stripping performance and to mitigate the effects of any surfactants present in the feed stream. The process that deploys this solvent system is known as Caustic Side Solvent Extraction (CSSX). The solvent system has been deployed at the Savannah River Site (SRS) in the Modular CSSX Unit (MCU) since 2008.

Pierce, R.; Peters, T.; Crowder, M.; Pak, D.; Fink, S.; Blessing, R.; Washington, A.; Caldwell, T.

2011-11-29T23:59:59.000Z

17

EM National Laboratory's Solvent to Save an Estimated $1.35 Billion |  

Broader source: Energy.gov (indexed) [DOE]

EM National Laboratory's Solvent to Save an Estimated $1.35 EM National Laboratory's Solvent to Save an Estimated $1.35 Billion EM National Laboratory's Solvent to Save an Estimated $1.35 Billion December 24, 2013 - 12:00pm Addthis The "MaxCalix" solvent improves the process for removing Cesium-137 from radioactive waste solutions. The "MaxCalix" solvent improves the process for removing Cesium-137 from radioactive waste solutions. AIKEN, S.C. - For the Savannah River National Laboratory (SRNL), successful deployment is the ultimate validation of science and technology's value to the EM program. In 2013, EM and its Savannah River Site (SRS) liquid waste contractor, Savannah River Remediation (SRR), deployed a Next Generation Solvent in a radioactive cesium extraction process. This marked the latest advancement

18

EM National Laboratory's Solvent to Save an Estimated $1.35 Billion |  

Broader source: Energy.gov (indexed) [DOE]

National Laboratory's Solvent to Save an Estimated $1.35 National Laboratory's Solvent to Save an Estimated $1.35 Billion EM National Laboratory's Solvent to Save an Estimated $1.35 Billion December 24, 2013 - 12:00pm Addthis The "MaxCalix" solvent improves the process for removing Cesium-137 from radioactive waste solutions. The "MaxCalix" solvent improves the process for removing Cesium-137 from radioactive waste solutions. AIKEN, S.C. - For the Savannah River National Laboratory (SRNL), successful deployment is the ultimate validation of science and technology's value to the EM program. In 2013, EM and its Savannah River Site (SRS) liquid waste contractor, Savannah River Remediation (SRR), deployed a Next Generation Solvent in a radioactive cesium extraction process. This marked the latest advancement

19

RESULTS OF ANALYSIS OF NGS CONCENTRATE DRUM SAMPLES [Next Generation Solvent  

SciTech Connect (OSTI)

Savannah River National Laboratory (SRNL) prepared two drums (50 gallons each in ?Drum#2? and ?Drum#4?) of NGS-MCU (Next Generation Solvent-Modular CSSX Unit) concentrate for future use at MCU in downblending the BOBCalixC6 based solvent to produce NGS-MCU solvent. Samples of each drum were sent for analysis. The results of all the analyses indicate that the blend concentrate is of the correct composition and should produce a blended solvent at MCU of the desired formulation.

Peters, T.; Williams, M.

2013-09-13T23:59:59.000Z

20

Assessment of the impact of the next generation solvent on DWPF melter off-gas flammability  

SciTech Connect (OSTI)

An assessment has been made to evaluate the impact on the DWPF melter off-gas flammability of replacing the current solvent used in the Modular Caustic-Side Solvent Extraction Process Unit (MCU) process with the Next Generation Solvent (NGS-MCU) and blended solvent. The results of this study showed that the concentrations of nonvolatile carbon and hydrogen of the current solvent in the Slurry Mix Evaporator (SME) product would both be about 29% higher than their counterparts of the NGS-MCU and blended solvent in the absence of guanidine partitioning. When 6 ppm of guanidine (TiDG) was added to the effluent transfer to DWPF to simulate partitioning for the NGS-MCU and blended solvent cases and the concentration of Isopar{reg_sign} L in the effluent transfer was controlled below 87 ppm, the concentrations of nonvolatile carbon and hydrogen of the NGS-MCU and blended solvent were still about 12% and 4% lower, respectively, than those of the current solvent. It is, therefore, concluded that as long as the volume of MCU effluent transfer to DWPF is limited to 15,000 gallons per Sludge Receipt and Adjustment Tank (SRAT)/SME cycle and the concentration of Isopar{reg_sign} L in the effluent transfer is controlled below 87 ppm, using the current solvent assumption of 105 ppm Isopar{reg_sign} L or 150 ppm solvent in lieu of NGS-MCU or blended solvent in the DWPF melter off-gas flammability assessment is conservative for up to an additional 6 ppm of TiDG in the effluent due to guanidine partitioning. This report documents the calculations performed to reach this conclusion.

Daniel, W. E.

2013-02-13T23:59:59.000Z

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21

Recovery of cesium  

DOE Patents [OSTI]

A process of recovering cesium ions from mixtures of ions containing them and other ions, e.g., a solution of nuclear waste materials, which comprises establishing a separate source phase containing such a mixture of ions, establishing a separate recipient phase, establishing a liquid membrane phase in interfacial contact with said source and recipient phases, said membrane phase containing a ligand, preferably a selected calixarene as depicted in the drawing, maintaining said interfacial contact for a period of time long enough to transport by said ligand a substantial portion of the cesium ion from the source phase to the recipient phase, and recovering the cesium ion from the recipient phase. The separation of the source and recipient phases may be by the membrane phase only, e.g., where these aqueous phases are emulsified as dispersed phases in a continuous membrane phase, or may include a physical barrier as well, e.g., an open-top outer container with an inner open-ended container of smaller cross-section mounted in the outer container with its open bottom end spaced from and above the closed bottom of the outer container so that the membrane phase may fill the outer container to a level above the bottom of the inner container and have floating on its upper surface a source phase and a recipient phase separated by the wall of the inner container as a physical barrier. A preferred solvent for the ligand is a mixture of methylene chloride and carbon tetrachloride.

Izatt, Reed M. (Provo, UT); Christensen, James J. (Provo, UT); Hawkins, Richard T. (Orem, UT)

1984-01-01T23:59:59.000Z

22

Sample Results From The Next Generation Solvent Program Real Waste Extraction-Scrub-Strip Testing  

SciTech Connect (OSTI)

Savannah River National Laboratory (SRNL) performed multiple Extraction-Scrub-Strip (ESS) testing using real waste solutions, and three Next Generation Solvent (NGS) variations, which included radiologically clean pure NGS, a blend of radiologically clean NGS and radiologically clean BOBCalixC6 (NGS-MCU), and a blend of radiologically clean NGS and radiologically contaminated BOBCalixC6 from the MCU Solvent system. The results from the tests indicate that both the NGS and the NGS-MCU blend exhibit adequate extraction, scrub and strip behavior.

Peters, T. B.; Washington, A. L. II

2013-08-08T23:59:59.000Z

23

SAMPLE RESULTS FROM THE NEXT GENERATION SOLVENT PROGRAM REAL WASTE EXTRACTION-SCRUB-STRIP TESTING  

SciTech Connect (OSTI)

Savannah River National Laboratory (SRNL) performed multiple Extraction-Scrub-Strip (ESS) testing using real waste solutions, and three Next Generation Solvent (NGS) variations, which included radiologically clean pure NGS, a blend of radiologically clean NGS and radiologically clean BOBCalixC6 (NGS-MCU), and a blend of radiologically clean NGS and radiologically contaminated BOBCalixC6 from the MCU Solvent system. The results from the tests indicate that both the NGS and the NGS-MCU blend exhibit adequate extraction, scrub and strip behavior.

Peters, T.; Washington, A.

2013-06-03T23:59:59.000Z

24

Recommended Guanidine Suppressor for the Next-Generation Caustic-Side Solvent Extraction Process  

SciTech Connect (OSTI)

The guanidine recommended for the Next-Generation Caustic-Side is N,N ,N -tris(3,7-dimethyloctyl)guanidine (TiDG). Systematic testing has shown that it is significantly more lipophilic than the previously recommended guanidine DCiTG, the active extractant in the commercial guanidine product LIX -79, while not otherwise changing the solvent performance. Previous testing indicated that the extent of partitioning of the DCiTG suppressor to the aqueous strip solution is significantly greater than expected, potentially leading to rapid depletion of the suppressor from the solvent and unwanted organic concentrations in process effluents. Five candidate guanidines were tested as potential replacements for DCiTG. The tests included batch extraction with simulated waste and flowsheet solutions, third-phase formation, emulsion formation, and partition ratios of the guanidine between the solvent and aqueous strip solution. Preliminary results of a thermal stability test of the TiDG solvent at one month duration indicated performance approximately equivalent to DCiTG. Two of the guanidines proved adequate in all respects, and the choice of TiDG was deemed slightly preferable vs the next best guanidine BiTABG.

Moyer, Bruce A [ORNL; Delmau, Laetitia Helene [ORNL; Duncan, Nathan C [ORNL; Ensor, Dale [Tennessee Technological University; Hill, Talon G [ORNL; Lee, Denise L [ORNL; Roach, Benjamin D [ORNL; Sloop Jr, Frederick {Fred} V [ORNL; Williams, Neil J [ORNL

2013-01-01T23:59:59.000Z

25

DEMONSTRATION OF THE NEXT-GENERATION CAUSTIC-SIDE SOLVENT EXTRACTION SOLVENT WITH 2-CM CENTRIFUGAL CONTRACTORS USING TANK 49H WASTE AND WASTE SIMULANT  

SciTech Connect (OSTI)

Researchers successfully demonstrated the chemistry and process equipment of the Caustic-Side Solvent Extraction (CSSX) flowsheet using MaxCalix for the decontamination of high level waste (HLW). The demonstration was completed using a 12-stage, 2-cm centrifugal contactor apparatus at the Savannah River National Laboratory (SRNL). This represents the first CSSX process demonstration of the MaxCalix solvent system with Savannah River Site (SRS) HLW. Two tests lasting 24 and 27 hours processed non-radioactive simulated Tank 49H waste and actual Tank 49H HLW, respectively. Conclusions from this work include the following. The CSSX process is capable of reducing {sup 137}Cs in high level radioactive waste by a factor of more than 40,000 using five extraction, two scrub, and five strip stages. Tests demonstrated extraction and strip section stage efficiencies of greater than 93% for the Tank 49H waste test and greater than 88% for the simulant waste test. During a test with HLW, researchers processed 39 liters of Tank 49H solution and the waste raffinate had an average decontamination factor (DF) of 6.78E+04, with a maximum of 1.08E+05. A simulant waste solution ({approx}34.5 liters) with an initial Cs concentration of 83.1 mg/L was processed and had an average DF greater than 5.9E+03, with a maximum DF of greater than 6.6E+03. The difference may be attributable to differences in contactor stage efficiencies. Test results showed the solvent can be stripped of cesium and recycled for {approx}25 solvent turnovers without the occurrence of any measurable solvent degradation or negative effects from minor components. Based on the performance of the 12-stage 2-cm apparatus with the Tank 49H HLW, the projected DF for MCU with seven extraction, two scrub, and seven strip stages operating at a nominal efficiency of 90% is {approx}388,000. At 95% stage efficiency, the DF in MCU would be {approx}3.2 million. Carryover of organic solvent in aqueous streams (and aqueous in organic streams) was less than 0.1% when processing Tank 49H HLW. The entrained solvent concentration measured in the decontaminated salt solution (DSS) was as much as {approx}140 mg/L, although that value may be overstated by as much as 50% due to modifier solubility in the DSS. The entrained solvent concentration was measured in the strip effluent (SE) and the results are pending. A steady-state concentration factor (CF) of 15.9 was achieved with Tank 49H HLW. Cesium distribution ratios [D(Cs)] were measured with non-radioactive Tank 49H waste simulant and actual Tank 49H waste. Below is a comparison of D(Cs) values of ESS and 2-cm tests. Batch Extraction-Strip-Scrub (ESS) tests yielded D(Cs) values for extraction of {approx}81-88 for tests with Tank 49H waste and waste simulant. The results from the 2-cm contactor tests were in agreement with values of 58-92 for the Tank 49H HLW test and 54-83 for the simulant waste test. These values are consistent with the reference D(Cs) for extraction of {approx}60. In tests with Tank 49H waste and waste simulant, batch ESS tests measured D(Cs) values for the two scrub stages as {approx}3.5-5.0 for the first scrub stage and {approx}1.0-3.0 for the second scrub stage. In the Tank 49H test, the D(Cs) values for the 2-cm test were far from the ESS values. A D(Cs) value of 161 was measured for the first scrub stage and 10.8 for the second scrub stage. The data suggest that the scrub stage is not operating as effectively as intended. For the simulant test, a D(Cs) value of 1.9 was measured for the first scrub stage; the sample from the second scrub stage was compromised. Measurements of the pH of all stage samples for the Tank 49H test showed that the pH for extraction and scrub stages was 14 and the pH for the strip stages was {approx}7. It is expected that the pH of the second scrub stage would be {approx}12-13. Batch ESS tests measured D(Cs) values for the strip stages to be {approx}0.002-0.010. A high value in Strip No.3 of a test with simulant solution has been attributed to issues associated with the limits of detection for the

Pierce, R.; Peters, T.; Crowder, M.; Caldwell, T.; Pak, D; Fink, S.; Blessing, R.; Washington, A.

2011-09-27T23:59:59.000Z

26

Results From The Salt Disposition Project Next Generation Solvent Demonstration Plan  

SciTech Connect (OSTI)

Strip Effluent Hold Tank (SEHT), Decontaminated Salt Solution Hold Tank (DSSHT), Caustic Wash Tank (CWT) and Solvent Hold Tank (SHT) samples were taken throughout the Next Generation Solvent (NGS) Demonstration Plan. These samples were analyzed and the results are reported. SHT: The solvent behaved as expected, with no bulk changes in the composition over time, with the exception of the TOA and TiDG. The TiDG depletion is higher than expected, and consideration must be taken on the required rate of replenishment. Monthly sampling of the SHT is warranted. If possible, additional SHT samples for TiDG analysis (only) would help SRNL refine the TiDG degradation model. CWT: The CWT samples show the expected behavior in terms of bulk chemistry. The 137Cs deposited into the CWT varies somewhat, but generally appears to be lower than during operations with the BOBCalix solvent. While a few minor organic components were noted to be present in the Preliminary sample, at this time these are thought to be artifacts of the sample preparation or may be due to the preceding solvent superwash. DSSHT: The DSSHT samples show the predicted bulk chemistry, although they point towards significant dilution at the front end of the Demonstration. The 137Cs levels in the DSSHT are much lower than during the BOBCalix operations, which is the expected observation. SEHT: The SEHT samples represent the most different output of all four of the outputs from MCU. While the bulk chemistry is as expected, something is causing the pH of the SEHT to be higher than what would be predicted from a pure stream of 0.01 M boric acid. There are several possible different reasons for this, and SRNL is in the process of investigating. Other than the pH issue, the SEHT is as predicted. In summary, the NGS Demonstration Plan samples indicate that the MCU system, with the Blend Solvent, is operating as expected. The only issue of concern regards the pH of the SEHT, and SRNL is in the process of investigating this. SRNL results support the transition to routine operations.

Peters, T. B.; Fondeur, F. F.; Taylor-Pashow, K. M.L.

2014-04-02T23:59:59.000Z

27

RESULTS OF THE EXTRACTION-SCRUB-STRIP TESTING USING AN IMPROVED SOLVENT FORMULATION AND SALT WASTE PROCESSING FACILITY SIMULATED WASTE  

SciTech Connect (OSTI)

The Office of Waste Processing, within the Office of Technology Innovation and Development, is funding the development of an enhanced solvent - also known as the next generation solvent (NGS) - for deployment at the Savannah River Site to remove cesium from High Level Waste. The technical effort is a collaborative effort between Oak Ridge National Laboratory (ORNL) and Savannah River National Laboratory (SRNL). As part of the program, the Savannah River National Laboratory (SRNL) has performed a number of Extraction-Scrub-Strip (ESS) tests. These batch contact tests serve as first indicators of the cesium mass transfer solvent performance with actual or simulated waste. The test detailed in this report used simulated Tank 49H material, with the addition of extra potassium. The potassium was added at 1677 mg/L, the maximum projected (i.e., a worst case feed scenario) value for the Salt Waste Processing Facility (SWPF). The results of the test gave favorable results given that the potassium concentration was elevated (1677 mg/L compared to the current 513 mg/L). The cesium distribution value, DCs, for extraction was 57.1. As a comparison, a typical D{sub Cs} in an ESS test, using the baseline solvent formulation and the typical waste feed, is {approx}15. The Modular Caustic Side Solvent Extraction Unit (MCU) uses the Caustic-Side Solvent Extraction (CSSX) process to remove cesium (Cs) from alkaline waste. This process involves the use of an organic extractant, BoBCalixC6, in an organic matrix to selectively remove cesium from the caustic waste. The organic solvent mixture flows counter-current to the caustic aqueous waste stream within centrifugal contactors. After extracting the cesium, the loaded solvent is stripped of cesium by contact with dilute nitric acid and the cesium concentrate is transferred to the Defense Waste Processing Facility (DWPF), while the organic solvent is cleaned and recycled for further use. The Salt Waste Processing Facility (SWPF), under construction, will use the same process chemistry. The Office of Waste Processing (EM-31) expressed an interest in investigating the further optimization of the organic solvent by replacing the BoBCalixC6 extractant with a more efficient extractant. This replacement should yield dividends in improving cesium removal from the caustic waste stream, and in the rate at which the caustic waste can be processed. To that end, EM-31 provided funding for both the Savannah River National Laboratory (SRNL) and the Oak Ridge National Laboratory (ORNL). SRNL wrote a Task Technical Quality and Assurance Plan for this work. As part of the envisioned testing regime, it was decided to perform an ESS test using a simulated waste that simulated a typical envisioned SWPF feed, but with added potassium to make the waste more challenging. Potassium interferes in the cesium removal, and its concentration is limited in the feed to <1950 mg/L. The feed to MCU has typically contained <500 mg/L of potassium.

Peters, T.; Washington, A.; Fink, S.

2012-01-09T23:59:59.000Z

28

Cesium-131 Production - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cesium-131 Production Idaho National Laboratory Contact INL About This Technology Technology Marketing SummaryCesium-131 production.Description This invention produces Cesium 131...

29

Life extension program for the modular caustic side solvent extraction unit at Savannah River Site  

SciTech Connect (OSTI)

Caustic Side Solvent Extraction (CSSX) is currently used at the U.S. Department of Energy (DOE) Savannah River Site (SRS) for removal of cesium from the high-level salt-wastes stored in underground tanks. At SRS, the CSSX process is deployed in the Modular CSSX Unit (MCU). The CSSX technology utilizes a multi-component organic solvent and annular centrifugal contactors to extract cesium from alkaline salt waste. Coalescers and decanters process the Decontaminated Salt Solution (DSS) and Strip Effluent (SE) streams to allow recovery and reuse of the organic solvent and to limit the quantity of solvent transferred to the downstream facilities. MCU is operated in series with the Actinide Removal Process (ARP) which removes strontium and actinides from salt waste utilizing monosodium titanate. ARP and MCU were developed and implemented as interim salt processing until future processing technology, the CSSX-based Salt Waste Processing Facility (SWPF), is operational. SWPF is slated to come on-line in October 2014. The three year design life of the ARP/MCU process, however, was reached in April 2011. Nevertheless, most of the individual process components are capable of operating longer. An evaluation determined ARP/MCU can operate until 2015 before major equipment failure is expected. The three year design life of the ARP/MCU Life Extension (ARP/MCU LE) program will bridge the gap between current ARP/MCU operations and the start of SWPF operation. The ARP/MCU LE program introduces no new technologies. As a portion of this program, a Next Generation Solvent (NGS) and corresponding flowsheet are being developed to provide a major performance enhancement at MCU. This paper discusses all the modifications performed in the facility to support the ARP/MCU Life Extension. It will also discuss the next generation chemistry, including NGS and new stripping chemistry, which will increase cesium removal efficiency in MCU. Possible implementation of the NGS chemistry in MCU accomplishes two objectives. MCU serves as a demonstration facility for improved flowsheet deployment at SWPF; operating with NGS and boric acid validates improved cesium removal performance and increased throughput as well as confirms Defense Waste Processing Facility (DWPF) ability to vitrify waste streams containing boron. NGS implementation at MCU also aids the ARP/MCU LE operation, mitigating the impacts of delays and sustaining operations until other technology is able to come on-line.

Samadi-Dezfouli, Azadeh

2012-11-14T23:59:59.000Z

30

It's Elemental - The Element Cesium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Xenon Xenon Previous Element (Xenon) The Periodic Table of Elements Next Element (Barium) Barium The Element Cesium [Click for Isotope Data] 55 Cs Cesium 132.9054519 Atomic Number: 55 Atomic Weight: 132.9054519 Melting Point: 301.59 K (28.44°C or 83.19°F) Boiling Point: 944 K (671°C or 1240°F) Density: 1.93 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Metal Period Number: 6 Group Number: 1 Group Name: Alkali Metal What's in a name? From the Latin word for sky blue, caesius. Say what? Cesium is pronounced as SEE-zee-em. History and Uses: Cesium was discovered by Robert Wilhelm Bunsen and Gustav Robert Kirchhoff, German chemists, in 1860 through the spectroscopic analysis of Durkheim mineral water. They named cesium after the blue lines they observed in its

31

Sample Results From The Extraction, Scrub, And Strip Test For The Blended NGS Solvent  

SciTech Connect (OSTI)

This report summarizes the results of the extraction, scrub, and strip testing for the September 2013 sampling of the Next Generation Solvent (NGS) Blended solvent from the Modular Caustic Side-Solvent Extraction Unit (MCU) Solvent Hold Tank. MCU is in the process of transitioning from the BOBCalixC6 solvent to the NGS Blend solvent. As part of that transition, MCU has intentionally created a blended solvent to be processed using the Salt Batch program. This sample represents the first sample received from that blended solvent. There were two ESS tests performed where NGS blended solvent performance was assessed using either the Tank 21 material utilized in the Salt Batch 7 analyses or a simulant waste material used in the V-5/V-10 contactor testing. This report tabulates the temperature corrected cesium distribution, or DCs values, step recovery percentage, and actual temperatures recorded during the experiment. This report also identifies the sample receipt date, preparation method, and analysis performed in the accumulation of the listed values. The calculated extraction DCs values using the Tank 21H material and simulant are 59.4 and 53.8, respectively. The DCs values for two scrub and three strip processes for the Tank 21 material are 4.58, 2.91, 0.00184, 0.0252, and 0.00575, respectively. The D-values for two scrub and three strip processes for the simulant are 3.47, 2.18, 0.00468, 0.00057, and 0.00572, respectively. These values are similar to previous measurements of Salt Batch 7 feed with lab-prepared blended solvent. These numbers are considered compatible to allow simulant testing to be completed in place of actual waste due to the limited availability of feed material.

Washington, A. L. II; Peters, T. B.

2014-03-03T23:59:59.000Z

32

CAUSTIC SIDE SOLVENT EXTRACTION AT THE SAVANNAH RIVER SITE OPERATING EXPERIENCE AND LESSONS LEARNED  

SciTech Connect (OSTI)

The Modular Caustic-Side Solvent Extraction Unit (MCU) is the first, production-scale Caustic-Side Solvent Extraction process for cesium separation to be constructed. The process utilizes an engineered solvent to remove cesium from waste alkaline salt solution resulting from nuclear processes. While the application of this solvent extraction process is unique, the process uses commercially available centrifugal contactors for the primary unit operation as well as other common methods of physical separation of immiscible liquids. The fission product, cesium-137, is the primary focus of the process due to the hazards associated with its decay. The cesium is extracted from the waste, concentrated, and stripped out of the solvent resulting in a low-level waste salt solution and a concentrated cesium nitrate stream. The concentrated cesium stream can be vitrified into borosilicate glass with almost no increase in glass volume, and the salt solution can be dispositioned as a low-level grout. The unit is deployed as an interim process to disposition waste prior to start-up of the Salt Waste Processing Facility. The Salt Waste Processing Facility utilizes the same cesium removal technology, but will treat more contaminated waste. The MCU is not only fulfilling a critical need, it is the first demonstration of the process at production-scale.

Brown, S.

2010-01-06T23:59:59.000Z

33

Engineered Materials for Cesium and Strontium Storage Final Technical Report  

SciTech Connect (OSTI)

Closing the nuclear fuel cycle requires reprocessing spent fuel to recover the long-lived components that still have useful energy content while immobilizing the remnant waste fission products in stable forms. At the genesis of this project, next generation spent fuel reprocessing methods were being developed as part of the U.S. Department of Energy's Advanced Fuel Cycle Initiative. One of these processes was focused on solvent extraction schemes to isolate cesium (Cs) and strontium (Sr) from spent nuclear fuel. Isolating these isotopes for short-term decay storage eases the design requirements for long-term repository disposal; a significant amount of the radiation and decay heat in fission product waste comes from Cs-137 and Sr-90. For the purposes of this project, the Fission Product Extraction (FPEX) process is being considered to be the baseline extraction method. The objective of this project was to evaluate the nature and behavior of candidate materials for cesium and strontium immobilization; this will include assessments with minor additions of yttrium, barium, and rubidium in these materials. More specifically, the proposed research achieved the following objectives (as stated in the original proposal): (1) Synthesize simulated storage ceramics for Cs and Sr using an existing labscale steam reformer at Purdue University. The simulated storage materials will include aluminosilicates, zirconates and other stable ceramics with the potential for high Cs and Sr loading. (2) Characterize the immobilization performance, phase structure, thermal properties and stability of the simulated storage ceramics. The ceramic products will be stable oxide powders and will be characterized to quantify their leach resistance, phase structure, and thermophysical properties. The research progressed in two stages. First, a steam reforming process was used to generate candidate Cs/Sr storage materials for characterization. This portion of the research was carried out at Purdue University and is detailed in Appendix A. Steam reforming proved to be too rigorous for efficient The second stage of this project was carried out at Texas A&M University and is Detailed in Appendix B. In this stage, a gentler ceramic synthesis process using Cs and Sr loaded kaolinite and bentonite clays was developed in collaboration with Dr. M. Kaminski at Argonne National Laboratory.

Sean M. McDeavitt

2010-04-14T23:59:59.000Z

34

RESORCINOL-FORMALDEHYDE ADSORPTION OF CESIUM (Cs+) FROM HANFORD WASTE SOLUTIONS-PART I: BATCH EQUILIBRIUM STUDY  

SciTech Connect (OSTI)

Batch equilibrium measurements were conducted with a granular Resorcinol-Formaldehyde (RF) resin to determine the distribution coefficients (Kds) for cesium. In the tests, Hanford Site actual waste sample containing radioactive cesium and a pretreated waste sample that was spiked with non-radioactive cesium were used. Initial concentrations of non-radioactive cesium in the waste sample were varied to generate an equilibrium isotherm for cesium. Two additional tests were conducted using a liquid to solid phase ratio of 10 and a contact time of 120 hours. The measured distribution coefficient (Kd) for radioactive cesium (137Cs) was 948 mL/g; the Kd for non-radioactive cesium (133Cs) was 1039 mL/g. The Kd for non-radioactive cesium decreased from 1039 to 691 mL/g as the initial cesium concentration increased. Very little change of the Kd was observed at initial cesium concentrations above 64 mg/mL. The maximum sorption capacity for cesium on granular RF resin was 1.17 mmole/g dry resin. T his value was calculated from the fit of the equilibrium isotherm data to the Dubinin-Radushkevich equation. Previously, a total capacity of 2.84 mmole/g was calculated by Bibler and Wallace for air-dried RF resin.

HASSAN, NEGUIBM

2004-03-30T23:59:59.000Z

35

Photoabsorption by Cesium  

Science Journals Connector (OSTI)

Oscillator strengths and the photoionization cross section for the ground state of cesium are computed using a semiempirical model potential involving two adjustable parameters and based only on the lowest few spectroscopic term values. The spin-orbit interaction is included in the model potential, and the effects of core polarization are explicitly taken into account in both the model potential and the dipole transition matrix element. The doublet-line-strength ratios for discrete transitions are in good agreement with Agnew's measured values, and no support is given other indications that the line strength for 6s12-np12 is vanishingly small somewhere in the region n=10-15. Good agreement with two recent measurements of the spin-orbit effect in photoionization is also obtained. The oscillator strengths and photoionization cross section are significantly lower than the measured values of Agnew, and Marr and Creek, respectively, but the total atomic polarizability is in excellent agreement with a recent measurement.

David W. Norcross

1973-02-01T23:59:59.000Z

36

Cesium removal from liquid acidic wastes with the primary focus on ammonium molybdophosphate as an ion exchanger: A literature review  

SciTech Connect (OSTI)

Many articles have been written concerning the selective removal of cesium from both acidic and alkaline defense wastes. The majority of the work performed for cesium removal from defense wastes involves alkaline feed solutions. Several different techniques for cesium removal from acidic solutions have been evaluated such as precipitation, solvent extraction, and ion exchange. The purpose of this paper is to briefly review various techniques for cesium removal from acidic solutions. The main focus of the review will be on ion exchange techniques, particularly those involving ammonium molybdophosphate as the exchanger. The pertinent literature sources are condensed into a single document for quick reference. The information contained in this document was used as an aid in determining techniques to evaluate cesium removal from the acidic Idaho Chemical Processing Plant waste matrices. 47 refs., 2 tabs.

Miller, C.J.

1995-03-01T23:59:59.000Z

37

Preparation and use of polymeric materials containing hydrophobic anions and plasticizers for separation of cesium and strontium  

DOE Patents [OSTI]

Preparation and use is described for polymeric materials containing hydrophobic anions and plasticizers for extraction of cesium and strontium. The use of polymeric materials containing plasticizers which are solvents for hydrophobic anions such as derivatives of cobalt dicarbollide or tetraphenylborate which are capable of extracting cesium and strontium ions from aqueous solutions in contact with the polymeric materials, is described. The polymeric material may also include a synergistic agent for a given ion like polyethylene glycol or a crown ether, for removal of radioactive isotopes of cesium and strontium from solutions of diverse composition and, in particular, for solutions containing large excess of sodium nitrate.

Abney, K.D.; Kinkead, S.A.; Mason, C.F.V.; Rais, J.

1997-09-09T23:59:59.000Z

38

Preparation and use of polymeric materials containing hydrophobic anions and plasticizers for separation of cesium and strontium  

DOE Patents [OSTI]

Preparation and use of polymeric materials containing hydrophobic anions and plasticizers for extraction of cesium and strontium. The use of polymeric materials containing plasticizers which are solvents for hydrophobic anions such as derivatives of cobalt dicarbollide or tetraphenylborate which are capable of extracting cesium and strontium ions from aqueous solutions in contact with the polymeric materials, is described. The polymeric material may also include a synergistic agent for a given ion like polyethylene glycol or a crown ether, for removal of radioactive isotopes of cesium and strontium from solutions of diverse composition and, in particular, for solutions containing large excess of sodium nitrate.

Abney, Kent D. (30 San Juan St., Los Alamos, NM 87544); Kinkead, Scott A. (70 Canada Cir., Los Alamos, NM 87544); Mason, Caroline F. V. (148 Piedra Loop, Los Alamos, NM 87544); Rais, Jiri (Fr. Krizka 11, 17000 Praha 7, CZ)

1997-01-01T23:59:59.000Z

39

Caustic-Side Solvent Extraction: Chemical and Physical Properties of the Optimized Solvent  

SciTech Connect (OSTI)

This work was undertaken to optimize the solvent used in the Caustic Side Solvent Extraction (CSSX) process and to measure key chemical and physical properties related to its performance in the removal of cesium from the alkaline high-level salt waste stored in tanks at the Savannah River Site. The need to adjust the solvent composition arose from the prior discovery that the previous baseline solvent was supersaturated with respect to the calixarene extractant. The following solvent-component concentrations in Isopar{reg_sign} L diluent are recommended: 0.007 M calix[4]arene-bis(tert-octylbenzo-crown-6) (BOBCalixC6) extractant, 0.75 M 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol (Cs-7SB) phase modifier, and 0.003 M tri-n-octylamine (TOA) stripping aid. Criteria for this selection included BOBCalixC6 solubility, batch cesium distribution ratios (D{sub Cs}), calculated flowsheet robustness, third-phase formation, coalescence rate (dispersion numbers), and solvent density. Although minor compromises within acceptable limits were made in flowsheet robustness and solvent density, significant benefits were gained in lower risk of third-phase formation and lower solvent cost. Data are also reported for the optimized solvent regarding the temperature dependence of D{sub Cs} in extraction, scrubbing, and stripping (ESS); ESS performance on recycle; partitioning of BOBCalixC6, Cs-7SB, and TOA to aqueous process solutions; partitioning of organic anions; distribution of metals; solvent phase separation at low temperatures; solvent stability to elevated temperatures; and solvent density and viscosity. Overall, the technical risk of the CSSX process has been reduced by resolving previously identified issues and raising no new issues.

Delmau, L.H.

2002-10-08T23:59:59.000Z

40

Process for cesium decontamination and immobilization  

DOE Patents [OSTI]

Cesium can be selectively recovered from a nuclear waste solution containing cesium together with other metal ions by contact with a modified phlogopite which is a hydrated, sodium phlogopite mica. Once the cesium has entered the modified phlogopite it is fixed and can be safely stored for long periods of time.

Komarneni, Sridhar (Altoona, PA); Roy, Rustum (State College, PA)

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Preliminary Evaluation of Cesium Distribution for Wet Sieving Process Planned for Soil Decontamination in Japan - 13104  

SciTech Connect (OSTI)

For the purpose of decontaminating radioactive cesium from a huge amount of soil, which has been estimated to be 1.2x10{sup 8} m{sup 3} by excavating to a 5-cm depth from the surface of Fukushima Prefecture where a severe nuclear accident occurred at TEPCO's power generating site and has emitted a significant amount of radioactive materials, mainly radioactive cesium, a wet sieving process was selected as one of effective methods available in Japan. Some private companies have demonstrated this process for soil treatment in the Fukushima area by testing at their plants. The results were very promising, and a full-fledged application is expected to follow. In the present study, we spiked several aqueous samples containing soil collected from an industrial wet sieving plant located near our university for the recycling of construction wastes with non-radioactive cesium hydroxide. The present study provides scientific data concerning the effectiveness in volume reduction of the contaminated soil by a wet sieving process as well as the cesium distribution between the liquid phase and clay minerals for each sub-process of the full-scale one, but a simulating plant equipped with a process of coagulating sedimentation and operational safety fundamentals for the plant. Especially for the latter aspect, the study showed that clay minerals of submicron size strongly bind a high content of cesium, which was only slightly removed by coagulation with natural sedimentation (1 G) nor centrifugal sedimentation (3,700 G) and some of the cesium may be transferred to the effluent or recycled water. By applying ultracentrifugation (257,000 G), most of submicron clay minerals containing cesium was removed, and the cesium amount which might be transferred to the effluent or recycled water, could be reduced to less than 2.3 % of the original design by the addition of a cesium barrier consisting of ultracentrifugation or a hollow fiber membrane. (authors)

Enokida, Y.; Tanada, Y.; Hirabayashi, D. [Graduate School of Engineering, 1 Furo-cho Nagoya-shi, Aichi-ken, 4648603 (Japan)] [Graduate School of Engineering, 1 Furo-cho Nagoya-shi, Aichi-ken, 4648603 (Japan); Sawada, K. [EcoTopia Science Institute, Nagoya University, 1 Furo-cho Nagoya-shi, Aichi-ken, 4648603 (Japan)] [EcoTopia Science Institute, Nagoya University, 1 Furo-cho Nagoya-shi, Aichi-ken, 4648603 (Japan)

2013-07-01T23:59:59.000Z

42

Laboratory solvent reuse -- Liquid chromatography  

SciTech Connect (OSTI)

The objective of this work was to develop a method for reduction of waste solvent in the Process Engineering Chemistry Laboratory. The liquid chromatographs are the largest generators of explosive-contaminated waste in the laboratory. We developed a successful process for the reuse of solvents from the liquid chromatographs and demonstrated the utility of the process in the assay of hexanitrostilbene.

Quinlin, W.T.; Schaffer, C.L.

1992-11-01T23:59:59.000Z

43

Thermal analysis of the ATI thermionic converter for optimum cesium reservoir location  

SciTech Connect (OSTI)

A first-order thermal analysis was performed on the emitter lead region of the Advanced Thermionic Initiative (ATI) Thermionic Fuel Element (TFE) design. The lead region is the candidate location for a metal-matrix, cesium-graphite reservoir to supply cesium vapor to the thermionic converter. The cesium pressure developed is dependent upon the temperature and cesium-carbon equilibrium reaction of the reservoir. Steady-state, one dimensional conduction, with thermal radiation losses and Joulean heat generation, was used to calculate the temperature distribution in the non-fueled lead region. This temperature distribution was linked to the ATI reactor core design through the integration of axial emitter temperature distributions for the maximum, minimum, and average power TFE fuel pins. The axial temperature distribution in the emitter lead region was found to be most pronounced for the maximum power fuel element and least pronounced for the minimum power TFE.

Young, T.J. (Aerospace Power Division, Wright Laboratory/POOC, Wright-Patterson AFB, Ohio 45433-6563 (United States)); Thayer, K.L.; Ramalingam, M.L. (UES, Inc., 4401 Dayton-Xenia Road, Dayton, Ohio 45432-1894 (United States))

1993-01-15T23:59:59.000Z

44

Sintered wire cesium dispenser photocathode  

DOE Patents [OSTI]

A photoelectric cathode has a work function lowering material such as cesium placed into an enclosure which couples a thermal energy from a heater to the work function lowering material. The enclosure directs the work function lowering material in vapor form through a low diffusion layer, through a free space layer, and through a uniform porosity layer, one side of which also forms a photoelectric cathode surface. The low diffusion layer may be formed from sintered powdered metal, such as tungsten, and the uniform porosity layer may be formed from wires which are sintered together to form pores between the wires which are continuous from the a back surface to a front surface which is also the photoelectric surface.

Montgomery, Eric J; Ives, R. Lawrence; Falce, Louis R

2014-03-04T23:59:59.000Z

45

Alternate Methods For Eluting Cesium From Spherical Resorcinol-Formaldehyde Resin  

SciTech Connect (OSTI)

A Small Column Ion Exchange (SCIX) system has been proposed for removing cesium from the supernate and dissolved salt solutions in the high level waste tanks at the Savannah River Site (SRS). The SCIX system could use either crystalline silicotitanate (CST) an inorganic, non-regenerable sorbent or spherical resorcinol-formaldehyde (RF), a new regenerable resin, to remove cesium from the waste solutions. The standard method for eluting the cesium from the RF resin uses 15-20 bed volumes (BV) of 0.5 M nitric acid (HNO3). The nitric acid eluate, containing the radioactive cesium, would be combined with the sludge from the waste tanks, and would be converted into glass at the Defense Waste Processing Facility (DWPF) at SRS. The amount of nitric acid generated by the standard elution method exceeds the capacity of DWPF to destroy the nitrate ions and maintain the required chemical reducing conditions in the glass melt. Alternate methods for eluting the resin have been tested, including using lower concentrations of nitric acid, other acids, and changing the flow regimes. About 4 bed volumes of 0.5 M nitric acid are required to remove the sodium (titrate the resin) and most of the cesium from the resin, so the bulk of the acid used for the standard elution method removes a very small quantity of cesium from the resin. The resin was loaded with 9.5 g Cs/L of resin prior to elution, which is the maximum expected loading for RF resin treating the actual dissolved salt waste at SRS. For the baseline elution method, 465 g of nitrate is used per liter of resin, and >99.9999% of the cesium is removed from the resin. An alternative method that used 4 bed volumes of 0.5 M HNO3 followed by 11 bed volumes of 0.05 M HNO3, used 158 g of nitrate per liter of resin (66% less nitrate than used for the standard elution) and removed >99.998% of the cesium. A staccato flow mode using 0.5 M HNO3 (1 hr on at 1 BV/hr, followed by 3 hrs off) after the resin had been titrated using a continuous flow of acid at 1 BV/hr removed 99.9998% of the cesium while using 12 BV of acid (20% less than the baseline). Formic acid was slightly less efficient than nitric acid for eluting the resin, but 20 BV of 0.5 M HCOOH removed 99.98% of the cesium from the resin.

Taylor, Paul Allen [ORNL; Johnson, Heather Lauren [University of Tennessee, Knoxville (UTK)

2009-01-01T23:59:59.000Z

46

Solvent Immersion Imprint Lithography  

SciTech Connect (OSTI)

The mechanism of polymer disolution was explored for polymer microsystem prototyping, including microfluidics and optofluidics. Polymer films are immersed in a solvent, imprinted and finally brought into contact with a non-modified surface to permanently bond. The underlying polymer-solvent interactions were experimentally and theoretically investigated, and enabled rapid polymer microsystem prototyping. During imprinting, small molecule integration in the molded surfaces was feasible, a principle applied to oxygen sensing. Polystyrene (PS) was employed for microbiological studies at extreme environmental conditions. The thermophile anaerobe Clostridium Thermocellum was grown in PS pore-scale micromodels, revealing a double mean generation lifetime than under ideal culture conditions. Microsystem prototyping through directed polymer dissolution is simple and accessible, while simultaneous patterning, bonding, and surface/volume functionalization are possible in less than one minute.

Vasdekis, Andreas E.; Wilkins, Michael J.; Grate, Jay W.; Kelly, Ryan T.; Konopka, Allan; Xantheas, Sotiris S.; Chang, M. T.

2014-06-21T23:59:59.000Z

47

Evaluation of a New Cesium Ion Source for SIMS  

Science Journals Connector (OSTI)

Cesium is commonly used as the primary ion beam constituent in the SIMS analysis of many species to chemically enhance...

D. G. Welkie

1986-01-01T23:59:59.000Z

48

Solvent wash solution  

DOE Patents [OSTI]

A process is claimed for removing diluent degradation products from a solvent extraction solution, which has been used to recover uranium and plutonium from spent nuclear fuel. A wash solution and the solvent extraction solution are combined. The wash solution contains (a) water and (b) up to about, and including, 50 vol % of at least one-polar water-miscible organic solvent based on the total volume of the water and the highly-polar organic solvent. The wash solution also preferably contains at least one inorganic salt. The diluent degradation products dissolve in the highly-polar organic solvent and the organic solvent extraction solvent do not dissolve in the highly-polar organic solvent. The highly-polar organic solvent and the extraction solvent are separated.

Neace, J.C.

1984-03-13T23:59:59.000Z

49

Composition and process for separating cesium ions from an acidic aqueous solution also containing other ions  

DOE Patents [OSTI]

A crown ether cesium ion extractant is disclosed as is its synthesis. The crown ether cesium ion extractant is useful for the selective purification of cesium ions from aqueous acidic media, and more particularly useful for the isolation of radioactive cesium-137 from nuclear waste streams. Processes for isolating cesium ions from aqueous acidic media using the crown ether cesium extractant are disclosed as are processes for recycling the crown ether cesium extractant and processes for recovering cesium from a crown ether cesium extractant solution.

Dietz, Mark L. (Elmhurst, IL); Horwitz, E. Philip (Naperville, IL); Bartsch, Richard A. (Lubbock, TX); Barrans, Jr., Richard E. (Downers Grove, IL); Rausch, David (Naperville, IL)

1999-01-01T23:59:59.000Z

50

15 - Cleaning with Solvents  

Science Journals Connector (OSTI)

Publisher Summary This chapter focuses on the solvent-cleaning process, rather than on just the solvent. The role of well-chosen solvents is to fulfill the requirements of that process. It is the process (washing, rinsing, and drying) that provides effective cleaning. There are only two types of processes: those in which the solvent is vaporized, which are usually called vapor degreasing and those in which the solvent is not vaporized, usually called cold cleaning. The term “vapor degreasing,” while commonly used, is actually a misnomer. The solvent vapor is not the degreasing agent. It is the condensed solvent vapor (liquid) that solubilizes the soil and is the degreasing agent. The virtue of this scheme (vapor degreasing) is that the parts are washed at every stage of cleaning with pristine (hopefully) soil-free distilled solvent. Environmental regulations pertaining to emission of volatile organic components have become a dominant factor in the selection of one of these types of processes.

John B. Durkee

2008-01-01T23:59:59.000Z

51

Assessment of commercially available ion exchange materials for cesium removal from highly alkaline wastes  

SciTech Connect (OSTI)

Approximately 61 million gallons of nuclear waste generated in plutonium production, radionuclide removal campaigns, and research and development activities is stored on the Department of Energy`s Hanford Site, near Richland, Washington. Although the pretreatment process and disposal requirements are still being defined, most pretreatment scenarios include removal of cesium from the aqueous streams. In many cases, after cesium is removed, the dissolved salt cakes and supernates can be disposed of as LLW. Ion exchange has been a leading candidate for this separation. Ion exchange systems have the advantage of simplicity of equipment and operation and provide many theoretical stages in a small space. The organic ion exchange material Duolite{trademark} CS-100 has been selected as the baseline exchanger for conceptual design of the Initial Pretreatment Module (IPM). Use of CS-100 was chosen because it is considered a conservative, technologically feasible approach. During FY 96, final resin down-selection will occur for IPM Title 1 design. Alternate ion exchange materials for cesium exchange will be considered at that time. The purpose of this report is to conduct a search for commercially available ion exchange materials which could potentially replace CS-100. This report will provide where possible a comparison of these resin in their ability to remove low concentrations of cesium from highly alkaline solutions. Materials which show promise can be studied further, while less encouraging resins can be eliminated from consideration.

Brooks, K.P.; Kim, A.Y.; Kurath, D.E.

1996-04-01T23:59:59.000Z

52

Solvent recycle/recovery  

SciTech Connect (OSTI)

This report describes Phase I of the Solvent Recycle/Recovery Task of the DOE Chlorinated Solvent Substitution Program for the US Air Force by the Idaho National Engineering Laboratory, EG G Idaho, Inc., through the US Department of Energy, Idaho Operations Office. The purpose of the task is to identify and test recovery and recycling technologies for proposed substitution solvents identified by the Biodegradable Solvent Substitution Program and the Alternative Solvents/Technologies for Paint Stripping Program with the overall objective of minimizing hazardous wastes. A literature search to identify recycle/recovery technologies and initial distillation studies has been conducted. 4 refs.

Paffhausen, M.W.; Smith, D.L.; Ugaki, S.N.

1990-09-01T23:59:59.000Z

53

SOLvent | Open Energy Information  

Open Energy Info (EERE)

SOLvent SOLvent Jump to: navigation, search Name SOLvent Place Kamen, Germany Zip 59174 Sector Services, Solar, Wind energy Product Planning and consultancy services for wind and solar projects. References SOLvent[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. SOLvent is a company located in Kamen, Germany . References ↑ "SOLvent" Retrieved from "http://en.openei.org/w/index.php?title=SOLvent&oldid=351528" Categories: Clean Energy Organizations Companies Organizations Stubs What links here Related changes Special pages Printable version Permanent link Browse properties 429 Throttled (bot load) Error 429 Throttled (bot load) Throttled (bot load) Guru Meditation:

54

Cesium sorption and desorption on selected Los Alamos soils  

SciTech Connect (OSTI)

Laboratory experiments were conducted to evaluate the sorptivity of cesium onto Los Alamos soils under controlled experimental conditions. Four soil profiles were collected and each soil profile which is broken into layers according to previously identified soil horizons were studied. Batch sorption isotherms were studied to quantify the chemical reactivity of each soil horizon toward cesium ion. Radioactive cesium-137 was used as sorbent and gamma counting was used to quantify the amount of sorption. Desorption experiments were conducted after the sorption experiments. Batch desorption isotherms were studied to quantify the desorption of presorbed cesium from these Los Alamos soils. This study suggests cesium may sorb strongly and irreversibly on most Los Alamos soils. The amount of cesium sorption and desorption is possibly related to the clay content of the soil sample since subsurface sample has a higher clay content than that of surface sample.

Kung, K.S.; Chan, J.; Longmire, P.; Fowler, M.

1995-08-01T23:59:59.000Z

55

Selective Capture of Cesium and Thallium from Natural Waters...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

evaluated against iron(III) hexacyanoferrate(II) (insoluble Prussian blue) for the sorption of cesium (Cs+) and thallium (Tl+) from natural waters and simulated wastes. The...

56

ANALYSIS OF SOLVENT RECOVERED FROM WRIGHT INDUSTRIES, INCORPORATED TESTING  

SciTech Connect (OSTI)

Washington Savannah River Company (WSRC) began designing and building a Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU) at the Savannah River Site (SRS) to process liquid waste for an interim period. The MCU Project Team conducted testing of the contactors, coalescers, and decanters at Wright Industries, Incorporated (WII) in Nashville, Tennessee. That testing used MCU solvent and simulated SRS dissolved salt. Because of the value of the solvent, the MCU Project wishes to recover it for use in the MCU process in the H-Tank Farm. Following testing, WII recovered approximately 62 gallons of solvent (with entrained aqueous) and shipped it to SRS. The solvent arrived in two stainless steel drums. The MCU Project requested SRNL to analyze the solvent to determine whether it is suitable for use in the MCU Process. SRNL analyzed the solvent for Isopar{reg_sign} L by Gas Chromatography--Mass Spectroscopy (GC-MS), for Modifier and BOBCalixC6 by High Pressure Liquid Chromatography (HPLC), and for Isopar{reg_sign} L-to-Modifier ratio by Fourier-Transform Infrared (FTIR) spectroscopy. They also measured the solvent density gravimetrically and used that measurement to calculate the Isopar{reg_sign} L and Modifier concentration. The conclusions from this work are: (1) The constituents of the used WII solvent are collectively low in Isopar{reg_sign} L, most likely due to evaporation. This can be easily corrected through the addition of Isopar{reg_sign} L. (2) Compared to a sample of the WII Partial Solvent (without BOBCalixC6) archived before transfer to WII, the Reworked WII Solvent showed a significant improvement (i.e., nearly doubling) in the dispersion numbers for tests with simulated salt solution and with strip acid. Hence, the presence of the plasticizer impurity has no detrimental impact on phase separation. While there are no previous dispersion tests using the exact same materials, the results seem to indicate that the washing of the solvent gives a dispersion benefit. (3) WII Solvent that underwent a cleaning cycle provides an acceptable set of cesium distribution (i.e., D) values when used in a standard Extraction, Scrub, and Strip (ESS) test.

Poirier, M; Thomas Peters, T; Fernando Fondeur, F; Samuel Fink, S

2007-01-11T23:59:59.000Z

57

Caustic-Side Solvent-Extraction Modeling for Hanford Interim Pretreatment System  

SciTech Connect (OSTI)

The purpose of this work is to examine the applicability of the Caustic-Side Solvent Extraction (CSSX) process for the removal of cesium from Hanford tank-waste supernatant solutions in support of the Hanford Interim Pretreatment System (IPS). The Hanford waste types are more challenging than those at the Savannah River Site (SRS) in that they contain significantly higher levels of potassium, the chief competing ion in the extraction of cesium. It was confirmed by use of the CSSX model that the higher levels of potassium depress the cesium distribution ratio (DCs), as validated by measurement of DCs values for four of eight specified Hanford waste-simulant compositions. The model predictions were good to an apparent standard error of ±11%. It is concluded from batch distribution experiments, physical-property measurements, equilibrium modeling, flowsheet calculations, and contactor sizing that the CSSX process as currently employed for cesium removal from alkaline salt waste at the SRS is capable of treating similar Hanford tank feeds. For the most challenging waste composition, 41 stages would be required to provide a cesium decontamination factor (DF) of 5000 and a concentration factor (CF) of 5. Commercial contacting equipment with rotor diameters of 10 in. for extraction and 5 in. for stripping should have the capacity to meet throughput requirements, but testing will be required to confirm that the needed efficiency and hydraulic performance are actually obtainable. Markedly improved flowsheet performance was calculated for a new solvent formulation employing the more soluble cesium extractant BEHBCalixC6 used with alternative scrub and strip solutions, respectively 0.1 M NaOH and 10 mM boric acid. The improved system can meet minimum requirements (DF = 5000 and CF = 5) with 17 stages or more ambitious goals (DF = 40,000 and CF = 15) with 19 stages. Potential benefits of further research and development are identified that would lead to reduced costs, greater adaptability of the process to DOE alkaline salt wastes, and greater readiness for implementation. Such benefits accrue from optimal sizing of centrifugal contactors for application of the CSSX process for the IPS; more accurate modeling of cesium extraction with greater flexibility and applicability to a variety of feeds and flowsheet conditions; and further improving and optimizing the alternative CSSX solvent and scrub/strip system.

Moyer, B.A.; Birdwell, J.F.; Delmau, L. H.; McFarlane, J.

2008-06-01T23:59:59.000Z

58

Method for synthesizing pollucite from chabazite and cesium chloride  

DOE Patents [OSTI]

A method is described for immobilizing waste chlorides salts containing radionuclides and hazardous nuclear material for permanent disposal, and in particular, a method is described for immobilizing waste chloride salts containing cesium, in a synthetic form of pollucite. The method for synthesizing pollucite from chabazite and cesium chloride includes mixing dry, non-aqueous cesium chloride with chabazite and heating the mixture to a temperature greater than the melting temperature of the cesium chloride, or above about 700 C. The method further comprises significantly improving the rate of retention of cesium in ceramic products comprised of a salt-loaded zeolite by adding about 10% chabazite by weight to the salt-loaded zeolite prior to conversion at elevated temperatures and pressures to the ceramic composite. 3 figs.

Pereira, C.

1999-02-23T23:59:59.000Z

59

Method for synthesizing pollucite from chabazite and cesium chloride  

DOE Patents [OSTI]

A method for immobilizing waste chlorides salts containing radionuclides and hazardous nuclear material for permanent disposal, and in particular, a method for immobilizing waste chloride salts containing cesium, in a synthetic form of pollucite. The method for synthesizing pollucite from chabazite and cesium chloride includes mixing dry, non-aqueous cesium chloride with chabazite and heating the mixture to a temperature greater than the melting temperature of the cesium chloride, or above about 700.degree. C. The method further comprises significantly improving the rate of retention of cesium in ceramic products comprised of a salt-loaded zeolite by adding about 10% chabazite by weight to the salt-loaded zeolite prior to conversion at elevated temperatures and pressures to the ceramic composite.

Pereira, Candido (Naperville, IL)

1999-01-01T23:59:59.000Z

60

Essential Oils as Green Solvents  

Science Journals Connector (OSTI)

This chapter introduces the solvency of essential oils (EOs) as green solvents, in particular, application of terpenes as solvents in extraction. The physiochemical properties of such solvents are predicted in co...

Ying Li; Anne-Sylvie Fabiano-Tixier…

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Integral cesium reservoir: Design and transient operation  

SciTech Connect (OSTI)

An electrically heated thermionic converter has been designed built and successfully tested in air (Homer et.al., 1995). One of the unique features of this converter was an integral cesium reservoir thermally coupled to the emitter. The reservoir consisted of fifteen cesiated graphite pins located in pockets situated in the emitter lead with thermal coupling to the emitter, collector and the emitter terminal; there were no auxiliary electric heaters on the reservoir. Test results are described for conditions in which the input thermal power to the converter was ramped up and down between 50% and 100% of full power in times as short as 50 sec, with data acquisition occurring every 12 sec. During the ramps the emitter and collector temperature profiles. the reservoir temperature and the electric output into a fixed load resistor are reported. The converter responded promptly to the power ramps without excessive overshoot and with no tendency to develop instabilities. This is the rust demonstration of the performance of a cesium-graphite integral reservoir in a fast transient

Smith, J.N. Jr.; Horner, M.H.; Begg, L.L. [General Atomics, San Diego, CA (United States); Wrobleski, W.J. [Westinghouse Electric Corp., West Mifflin, PA (United States). Bettis Atomic Power Lab.

1995-01-01T23:59:59.000Z

62

Thermionic converter with differentially heated cesium-oxygen source and method of operation  

SciTech Connect (OSTI)

A thermionic converter having an emitter, a collector, and a source of cesium vapor is provided wherein the source of cesium vapor is differentially heated so that said source has a hotter end and a cooler end, with cesium vapor evaporating from said hotter end into the space between the emitter and the collector and with cesium vapor condensing at said cooler end. The condensed cesium vapor migrates through a porous element from the cooler end to the hotter end.

Rasor, Ned S. (Cupertino, CA); Riley, David R. (West Newton, PA); Murray, Christopher S. (Bethel Park, PA); Geller, Clint B. (Pittsburgh, PA)

2000-01-01T23:59:59.000Z

63

Thermionic converter with differentially heated cesium-oxygen source and method of operation  

SciTech Connect (OSTI)

A thermionic converter having an emitter, a collector, and a source of cesium vapor is provided, wherein the source of cesium vapor is differentially heated so that said source has a hotter end and a cooler end, with cesium vapor evaporating from said hotter end into the space between the emitter and the collector and with cesium vapor condensing at said cooler end. The condensed cesium vapor migrates through a porous element from the cooler end to the hotter end.

Rasor, N.S.; Riley, D.R.; Murray, C.S.; Geller, C.B.

1998-12-01T23:59:59.000Z

64

Continuous countercurrent membrane column for the separation of solute/solvent and solvent/solvent systems  

DOE Patents [OSTI]

A reverse osmosis membrane process or hybrid membrane - complementary separator process for producing enriched product or waste streams from concentrated and dilute feed streams for both solvent/solvent and solute/solvent systems is described.

Nerad, Bruce A. (Longmont, CO); Krantz, William B. (Boulder, CO)

1988-01-01T23:59:59.000Z

65

Method for removing cesium from a nuclear reactor coolant  

DOE Patents [OSTI]

A method of and system for removing cesium from a liquid metal reactor coolant including a carbon packing trap in the primary coolant system for absorbing a major portion of the radioactive cesium from the coolant flowing therethrough at a reduced temperature. A regeneration subloop system having a secondary carbon packing trap is selectively connected to the primary system for isolating the main trap therefrom and connecting it to the regeneration system. Increasing the temperature of the sodium flowing through the primary trap diffuses a portion of the cesium

Colburn, Richard P. (Pasco, WA)

1986-01-01T23:59:59.000Z

66

CSSX Radiolytic H2 Generation ("Thermolysis") -- Final Report  

SciTech Connect (OSTI)

The purpose of this work was to determine the radiolytic hydrogen gas yield of irradiated CSSX solvent at several temperatures. The active ingredient of this solvent is calix[4]arene-bis-(t-octylbenzo) crown-6, a calixarene crown ether used for cesium complexation. The solvent also contains 1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol, a fluorinated alcoholic solvent modifer used to improve the solubility of the calixarene and its cesium complex in the Isopar L diluent. Isopar L is a branch-chain alkane and comprises most of the mixture. Samples of this solution were irradiated to various absorbed ?-ray doses in gas-tight sample containers, which were then sampled for hydrogen gas content. The methods are described below.

Bruce J. Mincher

2009-01-01T23:59:59.000Z

67

Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study  

E-Print Network [OSTI]

1 Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study by Anusha Kothandaraman Students #12;2 #12;3 Carbon Dioxide Capture by Chemical Absorption: A Solvent Comparison Study by Anusha with electricity generation accounting for 40% of the total1 . Carbon capture and sequestration (CCS) is one

68

Organic solvent topical report  

SciTech Connect (OSTI)

This report is the technical basis for the accident and consequence analyses used in the Hanford Tank Farms Basis for Interim Operation. The report also contains the scientific and engineering information and reference material needed to understand the organic solvent safety issue. This report includes comments received from the Chemical Reactions Subcommittee of the Tank Advisory Panel.

Cowley, W.L.

1998-04-30T23:59:59.000Z

69

CACI: The Cesium-137 Agricultural Commodities Irradiator  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE's Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the [sup 137]Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site. This Volume, VI, provides the CACI final design features regarding shielding, mechanical and electrical.

Not Available

1986-12-19T23:59:59.000Z

70

CACI: The Cesium-137 Agricultural Commodities Irradiator  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE's Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the [sup 137]Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site. The CACI final design is described in eight volumes. This Volume V, describes plans, criteria, and requirements.

Not Available

1986-12-19T23:59:59.000Z

71

CACI: The Cesium-137 Agricultural Commodities Irradiator  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE's Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the [sup 137]Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site. This Volume, IV, provides specifications as developed for the CACI final design.

Not Available

1986-12-01T23:59:59.000Z

72

CACI: The Cesium-137 Agricultural Commodities Irradiator  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE's Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the 137 Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site. The CACI final design is described in eight volumes. This volume, Volume VII, describes Safety Analysis, Thermal Analysis, and Thermal Testing.

Not Available

1986-12-19T23:59:59.000Z

73

CACI: The Cesium-137 Agricultural Commodities Irradiator  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE's Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the 137 Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site. The CACI final design is described in eight volumes. This volume Volume III, describes the Shielding Window.

Not Available

1986-12-19T23:59:59.000Z

74

Electron electric dipole moment experiment using electric-field quantized slow cesium atoms  

E-Print Network [OSTI]

eld quantized slow cesium atoms Jason M. Amini, ? Charles T.experiment using slow cesium atoms, nulled magnetic ?elds,magnetic ?elds seen by the atoms reduced to less than 200

Amini, Jason M.; Munger Jr., Charles T.; Gould, Harvey

2007-01-01T23:59:59.000Z

75

The mechanism of porosity formation during solvent-mediated phase transformations  

Science Journals Connector (OSTI)

...importance of porosity generation by solvent-mediated phase transformation...used for most imaging, and green light (lambda g=547nm...insights into the mechanisms of solvent-mediated phase transformation...reprecipitation processes in solvent-mediated phase transformation...

2011-01-01T23:59:59.000Z

76

Cesium removal from Savannah River Site radioactive waste using crystalline silicotitanate (IONSIV(R) IE-911)  

SciTech Connect (OSTI)

This study measured the ability of crystalline silicotitanate to remove cesium from Savannah River Site radioactive waste.

Walker, D.D.

1999-12-15T23:59:59.000Z

77

Solvent–Coal–Mineral Interaction during Solvent Extraction of Coal  

Science Journals Connector (OSTI)

The solvent extraction of Poplar lignite coal was studied with three model solvents (tetralin, quinoline, and 1-naphtol) and one industrial coal liquid derived solvent. ... Thanks to its wide distribution and large reserves, coal is a feasible local substitute feed material for conventional crude oil in many countries. ... Physical dissolution dominates at lower temperature, around 200 °C and lower temperatures for lignites; the role of the solvent is to relax the coal matrix and drag soluble molecules from the coal into the bulk solvent phase. ...

Mariangel Rivolta Hernández; Carolina Figueroa Murcia; Rajender Gupta; Arno de Klerk

2012-10-26T23:59:59.000Z

78

Cesium in the Savannah River Site environment  

SciTech Connect (OSTI)

Cesium in the Savannah River Site Environment is published as a part of the Radiological Assessment Program (RAP). It is the fourth in a series of eight documents on individual radioisotopes released to the environment as a result of Savannah River Site (SRS) operations. The earlier documents describe the environmental consequences of tritium, iodine, and uranium. Documents on plutonium, strontium, carbon, and technetium will be published in the future. These are dynamic documents and current plans call for revising and updating each one on a two-year schedule.Radiocesium exists in the environment as a result of above-ground nuclear weapons tests, the Chernobyl accident, the destruction of satellite Cosmos 954, small releases from reactors and reprocessing plants, and the operation of industrial, medical, and educational facilities. Radiocesium has been produced at SRS during the operation of five production reactors. Several hundred curies of [sup 137]Cs was released into streams in the late 50s and 60s from leaking fuel elements. Smaller quantities were released from the fuel reprocessing operations. About 1400 Ci of [sup 137]Cs was released to seepage basins where it was tightly bound by clay in the soil. A much smaller quantity, about four Ci. was released to the atmosphere. Radiocesium concentration and mechanisms for atmospheric, surface water, and groundwater have been extensively studied by Savannah River Technology Center (SRTC) and ecological mechanisms have been studied by Savannah River Ecology Laboratory (SREL). The overall radiological impact of SRS releases on the offsite maximum individual can be characterized by total doses of 033 mrem (atmospheric) and 60 mrem (liquid), compared with a dose of 12,960 mrem from non-SRS sources during the same period of time. Isotope [sup 137]Cs releases have resulted in a negligible risk to the environment and the population it supports.

Carlton, W.H.; Bauer, L.R.; Evans, A.G.; Geary, L.A.; Murphy, C.E. Jr.; Pinder, J.E.; Strom, R.N.

1992-03-01T23:59:59.000Z

79

Cesium in the Savannah River Site environment  

SciTech Connect (OSTI)

Cesium in the Savannah River Site Environment is published as a part of the Radiological Assessment Program (RAP). It is the fourth in a series of eight documents on individual radioisotopes released to the environment as a result of Savannah River Site (SRS) operations. The earlier documents describe the environmental consequences of tritium, iodine, and uranium. Documents on plutonium, strontium, carbon, and technetium will be published in the future. These are dynamic documents and current plans call for revising and updating each one on a two-year schedule.Radiocesium exists in the environment as a result of above-ground nuclear weapons tests, the Chernobyl accident, the destruction of satellite Cosmos 954, small releases from reactors and reprocessing plants, and the operation of industrial, medical, and educational facilities. Radiocesium has been produced at SRS during the operation of five production reactors. Several hundred curies of {sup 137}Cs was released into streams in the late 50s and 60s from leaking fuel elements. Smaller quantities were released from the fuel reprocessing operations. About 1400 Ci of {sup 137}Cs was released to seepage basins where it was tightly bound by clay in the soil. A much smaller quantity, about four Ci. was released to the atmosphere. Radiocesium concentration and mechanisms for atmospheric, surface water, and groundwater have been extensively studied by Savannah River Technology Center (SRTC) and ecological mechanisms have been studied by Savannah River Ecology Laboratory (SREL). The overall radiological impact of SRS releases on the offsite maximum individual can be characterized by total doses of 033 mrem (atmospheric) and 60 mrem (liquid), compared with a dose of 12,960 mrem from non-SRS sources during the same period of time. Isotope {sup 137}Cs releases have resulted in a negligible risk to the environment and the population it supports.

Carlton, W.H.; Bauer, L.R.; Evans, A.G.; Geary, L.A.; Murphy, C.E. Jr.; Pinder, J.E.; Strom, R.N.

1992-03-01T23:59:59.000Z

80

SOLVENT FIRE BY-PRODUCTS  

SciTech Connect (OSTI)

Southwest Research Institute (SwRI) conducted a burn test of the Caustic-Side Solvent Extraction (CSSX) solvent to determine the combustion products. The testing showed hydrogen fluoride gas is not a combustion product from a solvent fire when up to 70% of the solvent is consumed. The absence of HF in the combustion gases may reflect concentration of the modifier containing the fluoride groups in the unburned portion. SwRI reported results for other gases (CO, HCN, NOx, formaldehyde, and hydrocarbons). The results, with other supporting information, can be used for evaluating the consequences of a facility fire involving the CSSX solvent inventory.

Walker, D; Samuel Fink, S

2006-05-22T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

The Impact Of The MCU Life Extension Solvent On Sludge Batch 8 Projected Operating Windows  

SciTech Connect (OSTI)

As a part of the Actinide Removal Process (ARP)/Modular Caustic Side Solvent Extraction Unit (MCU) Life Extension Project, a next generation solvent (NGS) and a new strip acid will be deployed. The strip acid will be changed from dilute nitric acid to dilute boric acid (0.01 M). Because of these changes, experimental testing or evaluations with the next generation solvent are required to determine the impact of these changes (if any) to Chemical Process Cell (CPC) activities, glass formulation strategies, and melter operations at the Defense Waste Processing Facility (DWPF). The introduction of the dilute (0.01M) boric acid stream into the DWPF flowsheet has a potential impact on glass formulation and frit development efforts since B2O3 is a major oxide in frits developed for DWPF. Prior knowledge of this stream can be accounted for during frit development efforts but that was not the case for Sludge Batch 8 (SB8). Frit 803 has already been recommended and procured for SB8 processing; altering the frit to account for the incoming boron from the strip effluent (SE) is not an option for SB8. Therefore, the operational robustness of Frit 803 to the introduction of SE including its compositional tolerances (i.e., up to 0.0125M boric acid) is of interest and was the focus of this study. The primary question to be addressed in the current study was: What is the impact (if any) on the projected operating windows for the Frit 803 – SB8 flowsheet to additions of B2O3 from the SE in the Sludge Receipt and Adjustment Tank (SRAT)? More specifically, will Frit 803 be robust to the potential compositional changes occurring in the SRAT due to sludge variation, varying additions of ARP and/or the introduction of SE by providing access to waste loadings (WLs) of interest to DWPF? The Measurement Acceptability Region (MAR) results indicate there is very little, if any, impact on the projected operating windows for the Frit 803 – SB8 system regardless of the presence or absence of ARP and SE (up to 2 wt% B2O3 contained in the SRAT and up to 2000 gallons of ARP). It should be noted that 0.95 wt% B2O3 is the nominal projected concentration in the SRAT based on a 0.0125M boric acid flowsheet with 70,000 liters of SE being added to the SRAT. The impact on CPC processing of a 0.01M boric acid solution for elution of cesium during Modular Caustic Side Solvent Extraction Unit (MCU) processing has previously been evaluated by the Savannah River National Laboratory (SRNL). Increasing the acid strength to 0.0125M boric acid to account for variations in the boric acid strength has been reviewed versus the previous evaluation. The amount of acid from the boric acid represented approximately 5% of the total acid during the previous evaluation. An increase from 0.01 to 0.0125M boric acid represents a change of approximately 1.3% which is well within the error of the acid calculation. Therefore, no significant changes to CPC processing (hydrogen generation, metal solubilities, rheological properties, REDOX control, etc.) are expected from an increase in allowable boric acid concentration from 0.01M to 0.0125M.

Peeler, D. K.; Edwards, T. B.; Stone, M. E.

2013-08-14T23:59:59.000Z

82

Distribution of cesium-137 in the Mississippi Delta  

E-Print Network [OSTI]

in the soil (Tamura, 1964; Jenne and Wahlberg, 1968; Wahlberg and Fisbman, 1962), The amount of Cs retained by soils and the amount leached into streams and rivers in the dissolved form depends upon the properties of the clay minerals present (Tamura... and Jacobs, 1960; Wahlberg and Fishman, 1962). Cesium adsorption on clay minerals found in the soils appears to be governed by a clay mineral's tendency to undergo and maintain collapse of the c-axis during cesium and potassium adsorption rather than...

Pflaum, Ronald Charles

1982-01-01T23:59:59.000Z

83

Solvent Fractionation of Lignin  

SciTech Connect (OSTI)

Lignin is a highly abundant source of renewable carbon that can be considered as a valuable sustainable source of biobased materials. The major issues for the commercial production of value added high performance lignin products are lignin s physical and chemical heterogenities. To overcome these problems, a variety of procedures have been developed to produce pure lignin suitable for high performace applications such as lignin-derived carbon materials. However, most of the isolation procedures affect lignin s properties and structure. In this chapter, a short review of the effect of solvent fractionation on lignin s properties and structure is presented.

Chatterjee, Sabornie [ORNL; Saito, Tomonori [ORNL

2014-01-01T23:59:59.000Z

84

Linking Cesium and Strontium Uptake to Kaolinite Weathering in  

E-Print Network [OSTI]

Linking Cesium and Strontium Uptake to Kaolinite Weathering in Simulated Tank Waste Leachate J O N and Sr. Strontium sorption was nearly complete within 24 h for initial Sr concentrations (Sr0) e 10-3 to 2 Ã? 10-3 d-1 as Cs and Sr concentrations were increased from 10-5 to 10-3 M. Discrete strontium

Chorover, Jon

85

A transient model for a cesium vapor thermionic converter. [Cs  

SciTech Connect (OSTI)

This paper presents an analytical model for simulating the transient and steady-state operation of cesium vapor thermionic converters. A parametric analysis is performed to assess the transient response of the converter to changes in fission power and width of interelectrode gap. The model optimizes the converter performance for maximum electric power to the load.(AIP)

El-Genk, M.S.; Murray, C.S.; Chaudhuri, S. (Institute for Space Nuclear Power Studies, Department of Chemical and Nuclear Engineering, The University of New Mexico, Albuquerque, New Mexico (USA))

1991-01-10T23:59:59.000Z

86

Discovery of Cesium, Lanthanum, Praseodymium and Promethium Isotopes  

E-Print Network [OSTI]

Currently, forty-one cesium, thirty-five lanthanum, thirty-two praseodymium, and thirty-one promethium, isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

May, E

2011-01-01T23:59:59.000Z

87

Discovery of Cesium, Lanthanum, Praseodymium and Promethium Isotopes  

E-Print Network [OSTI]

Currently, forty-one cesium, thirty-five lanthanum, thirty-two praseodymium, and thirty-one promethium, isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

E. May; M. Thoennessen

2011-09-08T23:59:59.000Z

88

Alkaline-Side Extraction of Cesium from Savannah River Tank Waste Using a Calixarene-Crown Ether Extractant  

SciTech Connect (OSTI)

Results are presented supporting the viability of the alkaline-side CSEX process as a potential replacement for the In-Tank Precipitation process for removal of cesium from aqueous high-level waste (HLW) at the Savannah River Site (SRS). Under funding from the USDOE Efficient Separations and Crosscutting program, a flowsheet was suggested in early June of 1998, and in the following four months, this flowsheet underwent extensive testing, both in batch tests at ORNL and ANL and in two centrifugal-contactor tests at ANL. To carry out these tests, the initial ESP funding was augmented by direct funds from Westinghouse Savannah River Corporation. The flowsheet employed a solvent containing a calixarene-crown hybrid compound called BoBCalixC6 that was invented at ORNL and can now be obtained commercially for government use from IBC Advanced Technologies. This special extractant is so powerful and selective that it can be used at only 0.01 M, compensating for its expense, but a modifier is required for use in an aliphatic diluent, primarily to increase the cesium distribution ratio D{sub Cs} in extraction. The modifier selected is a relatively economical fluorinated alcohol called Cs3, invented at ORNL and so far available. only from ORNL. For the flowsheet, the modifier is used at 0.2 M in the branched aliphatic kerosene Isopar{reg_sign} L. Testing at ORNL and ANL involved simulants of the SRS HLW. After extraction of the Cs from the waste simulant, the solvent is scrubbed with 0.05 M HNO{sub 3} and stripped with a solution comprised of 0.0005 M HNO{sub 3} and 0.0001 M CsNO{sub 3}. The selection of these conditions is justified in this report, both on the basis of experimental data and underlying theory.

Bonnesen, P.V.; Delmau, L.H.; Haverlock, T.J.; Moyer, B.A.

1998-12-01T23:59:59.000Z

89

Method and article for primary containment of cesium wastes. [DOE patent application  

DOE Patents [OSTI]

A method for producing a cesium-retentive waste form, characterized by a high degree of compositional stability and mechanical integrity, is provided by subjecting a cesium-loaded zeolite to heat under conditions suitable for stabilizing the zeolite and immobilizing the cesium, and coating said zeolite for sufficient duration within a suitable environment with at least one dense layer of pyrolytic carbon to seal therein said cesium to produce a final, cesium-bearing waste form. Typically, the zolite is stabilized and the cesium immobilized in less than four hours by confinement within an air environment maintained at about 600/sup 0/C. Coatings are thereafter applied by confining the calcined zeolite within a coating environment comprising inert fluidizing and carbon donor gases maintained at 1000/sup 0/C for a suitable duration.

Angelini, P.; Lackey, W.J.; Stinton, D.P.; Blanco, R.E.; Bond, W.D.; Arnold, W.D. Jr.

1981-09-03T23:59:59.000Z

90

The reaction of cesium hydroxide with 4-phenylvaleric acid  

E-Print Network [OSTI]

Alkali Metal Hycroxide Solutions Used in Potentio- metric and Spectrophotometric Titrations with 4-Phenylvaleric Acid 17 Samples for Nuclear Magnetic Resonance Spectra 18 Concentration of 4-Phenylvaleric Acid in Carbon Tetrachloride for Infrared.... Similarly, nuclear magnetic resonance techniques may be used to determine whether any TT-bonding involving the phenyl ring of 4- phenylvaleric acid occurs during its reaction with cesium hydroxide. If any such bonding to the n-electrons of the ring occurs...

Caughfield, Arvie Jeane

2012-06-07T23:59:59.000Z

91

Extraction of cesium and strontium from nuclear waste  

DOE Patents [OSTI]

Cesium is extracted from acidified nuclear waste by contacting the waste with a bis 4,4'(5) [1-hydroxy-2-ethylhexyl]benzo 18-crown-6 compound and a cation exchanger in a matrix solution. Strontium is extracted from acidified nuclear waste by contacting the waste with a bis 4,4'(5') [1-hydroxyheptyl]cyclohexo 18-crown-6 compound, and a cation exchanger in a matrix solution.

Davis, Jr., Milton W. (Lexington, SC); Bowers, Jr., Charles B. (Columbia, SC)

1988-01-01T23:59:59.000Z

92

Green Solvents in Thin-Layer Chromatography  

Science Journals Connector (OSTI)

In this chapter green solvents used in thin-layer chromatography (TLC) are discussed in detail. These green solvents eradicate or minimize the use of volatile organic solvents and protect the environment from fur...

Ali Mohammad; Inamuddin; Asma Siddiq; Mu. Naushad; Gaber E. El-Desoky

2012-01-01T23:59:59.000Z

93

Electron electric dipole moment experiment using electric-field quantized slow cesium atoms  

E-Print Network [OSTI]

LBNL-51xxx Electron electric dipole momentexperiment using electric-?eld quantized slow cesium atomsA proof-of-principle electron electric dipole moment (e-EDM)

Amini, Jason M.; Munger Jr., Charles T.; Gould, Harvey

2007-01-01T23:59:59.000Z

94

Strontium and cesium release mechanisms during unsaturated flow through waste-weathered Hanford sediments  

E-Print Network [OSTI]

magnesium, calcium and strontium in Hanford tank wasteK. T. , Linking cesium and strontium uptake to kaoliniteS. ; Chorover, J. , Strontium speciation during reaction of

Chang, H.

2013-01-01T23:59:59.000Z

95

In Silico Search for Alternative Green Solvents  

Science Journals Connector (OSTI)

The selection of the most appropriate alternative solvents requires efficient predictive tools that avoid resorting ... and error experiments. Several classifications of organic solvents exist but they most often...

Laurianne Moity; Morgan Durand…

2014-01-01T23:59:59.000Z

96

Cesium Removal at Fukushima Nuclear Plant - 13215  

SciTech Connect (OSTI)

The Great East Japan Earthquake that took place on March 11, 2011 created a number of technical challenges at the Fukushima Daiichi Nuclear Plant. One of the primary challenges involved the treatment of highly contaminated radioactive wastewater. Avantech Inc. developed a unique patent pending treatment system that addressed the numerous technical issues in an efficient and safe manner. Our paper will address the development of the process from concept through detailed design, identify the lessons learned, and provide the updated results of the project. Specific design and operational parameters/benefits discussed in the paper include: - Selection of equipment to address radionuclide issues; - Unique method of solving the additional technical issues associated with Hydrogen Generation and Residual Heat; - Operational results, including chemistry, offsite discharges and waste generation. Results show that the customized process has enabled the utility to recycle the wastewater for cooling and reuse. This technology had a direct benefit to nuclear facilities worldwide. (authors)

Braun, James L.; Barker, Tracy A. [Avantech Incorporated, 95A Sunbelt Blvd Columbia, SC 29203 (United States)] [Avantech Incorporated, 95A Sunbelt Blvd Columbia, SC 29203 (United States)

2013-07-01T23:59:59.000Z

97

Sustainable Reactions in Tunable Solvents  

Science Journals Connector (OSTI)

Sustainable Reactions in Tunable Solvents ... Molecular dynamics simulations are used to calculate several free energy profiles relevant to the recombination/dissociation and transport of individual ions and ion pairs across the water/chloroform interface. ...

Charles A. Eckert; Charles L. Liotta; David Bush; James S. Brown; Jason P. Hallett

2004-09-14T23:59:59.000Z

98

Cesium reservoir and interconnective components. Final test report: TFE Verification Program  

SciTech Connect (OSTI)

The program objective is to demonstrate the technology readiness of a TFE (thermionic fuel element) suitable for use as the basic element in a thermionic reactor with electric power output in the 0.5 to 5.0 MW range. A thermionic converter must be supplied with cesium vapor for two reasons. Cesium atoms adsorbed on the surface of the emitter cause a reduction of the emitter work function to permit high current densities without excessive heating of the emitter. The second purpose of the cesium vapor is to provide space-charge neutralization in the emitter-collector gap so that the high current densities may flow across the gap unattenuated. The function of the cesium reservoir is to provide a source of cesium atoms, and to provide a reserve in the event that cesium is lost from the plasma by any mechanism. This can be done with a liquid cesium metal reservoir in which case it is heated to the desired temperature with auxiliary heaters. In a TFE, however, it is desirable to have the reservoir passively heated by the nuclear fuel. In this case, the reservoir must operate at a temperature intermediate between the emitter and the collector, ruling out the use of liquid reservoirs. Integral reservoirs contained within the TFE will produce cesium vapor pressures in the desired range at typical electrode temperatures. The reservoir material that appears to be the best able to meet requirements is graphite. Cesium intercalates easily into graphite, and the cesium pressure is insensitive to loading for a given intercalation stage. The goals of the cesium reservoir test program were to verify the performance of Cs-graphite reservoirs in the temperature-pressure range of interest to TFE operation, and to test the operation of these reservoirs after exposure to a fast neutron fluence corresponding to seven year mission lifetime. In addition, other materials were evaluated for possible use in the integral reservoir.

Not Available

1994-03-01T23:59:59.000Z

99

Sequestration and release mechanisms of strontium and cesium in zeolite/feldspathoid systems and laboratory reacted Hanford sediments  

E-Print Network [OSTI]

from the release of strontium-90 and cesium-137 isotopes. SrK.T. (2006) NMR study of strontium binding by a micaceousChorover, J. (2011) Strontium and Cesium Release Mechanisms

Rivera, Nelson Antonio Jr.

2011-01-01T23:59:59.000Z

100

Automated spray cleaning using flammable solvents in a glovebox environment  

SciTech Connect (OSTI)

The Clean Air Act Amendments that have phased out the use of ozone depleting solvents (ODS) have given the precision cleaning industry a challenge that they must respond to if they are to continuously and economically improve quality of service. The phase out of the ozone depleting solvents has forced industry to look to solvents such as alcohol, terpenes and other flammable solvents to perform the critical cleaning processes. These solvents are not as efficient as their ODS counterparts in terms of soil loading, cleaning time and drying when used in standard cleaning processes such as manual sprays or ultrasonic baths. They also require special equipment designs to meet part cleaning specifications and operator safety requirements. This paper describes a cleaning system that incorporates the automated spraying of flammable solvents to effectively perform precision cleaning processes. The prototype workcell under development uses a robot that sprays Isopropyl Alcohol (IPA) and terpene at pressures ranging to 600 psi in a glovebox environment. Key to the projects success was the development of software that controls the robotic system and automatically generates robotic cleaning paths from three dimensional CAD models of the items to be cleaned. Also key to the success of this prototype development is FM approval of the process and associated hardware which translates directly into operator and facilities safety.

McKee, R.; Meirans, L.; Watterberg, P.; Drotning, W. [Sandia National Labs., Albuquerque, NM (United States)

1997-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Replacement solvents for use in chemical synthesis  

DOE Patents [OSTI]

Replacement solvents for use in chemical synthesis include polymer-immobilized solvents having a flexible polymer backbone and a plurality of pendant groups attached onto the polymer backbone, the pendant groups comprising a flexible linking unit bound to the polymer backbone and to a terminal solvating moiety. The polymer-immobilized solvent may be dissolved in a benign medium. Replacement solvents for chemical reactions for which tetrahydrofuran or diethyl may be a solvent include substituted tetrahydrofurfuryl ethers and substituted tetrahydro-3-furan ethers. The replacement solvents may be readily recovered from the reaction train using conventional methods.

Molnar, Linda K. (Philadelphia, PA); Hatton, T. Alan (Sudbury, MA); Buchwald, Stephen L. (Newton, MA)

2001-05-15T23:59:59.000Z

102

Pore-Level Investigation of Heavy Oil Recovery During Water Alternating Solvent Injection Process  

Science Journals Connector (OSTI)

This study concerns with the microscopic and macroscopic fluid distribution and flow behavior during water alternating solvent (WAS) injection process to heavy oil using micromodel generated from thin section ...

A. A. Dehghan; S. A. Farzaneh; R. Kharrat; M. H. Ghazanfari…

2010-07-01T23:59:59.000Z

103

Microstructure analysis for chemical interaction between cesium and SUS 316 steel in fast breeder reactor application  

SciTech Connect (OSTI)

In this study the corrosion products on a surface after cesium corrosion examination at 650 deg. C for 100 hrs were characterized by TEM observation around the corroded area on the surface in order to understand the corrosion mechanism of cesium fission product for cladding materials in fast reactor. The experimental results suggest the main corrosion mechanism occurred in the process of the separation of cesium chromate and metal (Fe, Ni). The main reaction of corrosion process was considered to be equation, 2Cs + 7/2 O{sub 2} + 2Cr {yields} Cs{sub 2}Cr{sub 2}O{sub 7}(L). (authors)

Sasaki, K.; Fukumoto, K. I.; Oshima, T.; Tanigaki, T.; Masayoshi, U. [RINE, Univ. of Fukui, 3-9-1, Bunkyo, Fukui, 910-8507 (Japan)

2012-07-01T23:59:59.000Z

104

Solvent-induced forces in protein folding  

SciTech Connect (OSTI)

The solvent-induced forces between various groups on the protein are examined. It is found that the intramolecular hydrophilic forces are likely to be the strongest forces mediated through the solvent. It is argued that these are probably the most important solvent-induced driving forces in the process of protein folding.

Ben-Naim, A. (Hebrew Univ., Jerusalem (Israel))

1990-08-23T23:59:59.000Z

105

Firing of pulverized solvent refined coal  

DOE Patents [OSTI]

An air-purged burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired without the coking thereof on the burner components. The air-purged burner is designed for the firing of pulverized solvent refined coal in a tangentially fired boiler.

Derbidge, T. Craig (Sunnyvale, CA); Mulholland, James A. (Chapel Hill, NC); Foster, Edward P. (Macungie, PA)

1986-01-01T23:59:59.000Z

106

CACI: Cesium-137 Agricultural Commodities Irradiator: Final design report  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE's Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the 137 Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of Irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site.

Subbaraman, G.; Conners, C.C.

1986-12-19T23:59:59.000Z

107

Quality assurance program plan for cesium legacy project  

SciTech Connect (OSTI)

This Quality Assurance Program Plan (QAPP) provides information on how the Quality Assurance Program is implemented for the Cesium Legacy Project. It applies to those items and tasks which affect the completion of activities identified in the work breakdown structure of the Project Management Plan (PMP). These activities include all aspects of cask transportation, project related operations within the 324 Building, and waste management as it relates to the specific activities of this project. General facility activities (i.e. 324 Building Operations, Central Waste Complex Operations, etc.) are covered in other appropriate QAPPs. The 324 Building is currently transitioning from being a Pacific Northwest National Laboratory (PNNL) managed facility to a B and W Hanford Company (BWHC) managed facility. During this transition process existing PNNL procedures and documents will be utilized until replaced by BWHC procedures and documents.

Tanke, J.M.

1997-05-22T23:59:59.000Z

108

Sorption-desorption characteristics of uranium, cesium and strontium in typical podzol soils from Ukraine  

Science Journals Connector (OSTI)

......cesium and strontium in typical podzol soils from Ukraine S. Mishra 1 H. Arae 1 P. V. Zamostyan 2 T. Ishikawa...Radiation Medicine of Academy of Medical Sciences of Ukraine, Kiev, Ukraine Sorption-desorption behaviour of uranium (U......

S. Mishra; H. Arae; P. V. Zamostyan; T. Ishikawa; H. Yonehara; S. K. Sahoo

2012-11-01T23:59:59.000Z

109

Long-Term Storage of Cesium and Strontium at the Hanford Site  

Energy Savers [EERE]

From 1974 to 1985, cesium and strontium were recovered from high-level waste storage tanks at the Hanford Site, packed in corrosion-resistant capsules, and placed in underwater...

110

High-frequency two-photon ionization of helium and cesium  

Science Journals Connector (OSTI)

Calculations of the two-photon ionization of metastable levels of helium and the first three s levels of cesium are presented. The calculations are carried out to second order in a...

Marinescu, M; Sadeghpour, H R; Dalgarno, A

1993-01-01T23:59:59.000Z

111

E-Print Network 3.0 - absorption du cesium Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of SPIE Vol. 6871, 87112, (2008) Summary: from 9.192 GHz - of the fundamental Cesium atomic level have been scanned on a saturated absorption set... of the absorption line...

112

MODELING AN ION EXCHANGE PROCESS FOR CESIUM REMOVAL FROM ALKALINE RADIOACTIVE WASTE SOLUTIONS  

SciTech Connect (OSTI)

The performance of spherical Resorcinol-Formaldehyde ion-exchange resin for the removal of cesium from alkaline radioactive waste solutions has been investigated through computer modeling. Cesium adsorption isotherms were obtained by fitting experimental data using a thermodynamic framework. Results show that ion-exchange is an efficient method for cesium removal from highly alkaline radioactive waste solutions. On average, two 1300 liter columns operating in series are able to treat 690,000 liters of waste with an initial cesium concentration of 0.09 mM in 11 days achieving a decontamination factor of over 50,000. The study also tested the sensitivity of ion-exchange column performance to variations in flow rate, temperature and column dimensions. Modeling results can be used to optimize design of the ion exchange system.

Smith, F; Luther Hamm, L; Sebastian Aleman, S; Johnston Michael, J

2008-08-26T23:59:59.000Z

113

The beta decay of cesium 138 to levels in barium 138  

E-Print Network [OSTI]

THE BETA DECAY OP CESIUM 138 TO LEVELS IE BARIUM 138 A Thesis by DOUGLAS PERIL PULLER Submitted to the Graduate College of Texas A&M University in partial fulfillment of the recpxirements for the degree of MASTER OP SCIENCE August 19 IO... Major Subject: Physics THE BETA DECAY OF CESIUM 138 TO LEVELS IN BARIUM 138 A Thesis DOUGLAS PERIL FULLER Approved as to style and content by: (Chairman of Committee) ( ad of Department (Member Member (Member) Member) (Member August 1970...

Fuller, Douglas Feril

2012-06-07T23:59:59.000Z

114

Modeling Ion-Exchange Processing With Spherical Resins For Cesium Removal  

SciTech Connect (OSTI)

The spherical Resorcinol-Formaldehyde and hypothetical spherical SuperLig(r) 644 ion-exchange resins are evaluated for cesium removal from radioactive waste solutions. Modeling results show that spherical SuperLig(r) 644 reduces column cycling by 50% for high-potassium solutions. Spherical Resorcinol Formaldehyde performs equally well for the lowest-potassium wastes. Less cycling reduces nitric acid usage during resin elution and sodium addition during resin regeneration, therefore, significantly decreasing life-cycle operational costs. A model assessment of the mechanism behind ''cesium bleed'' is also conducted. When a resin bed is eluted, a relatively small amount of cesium remains within resin particles. Cesium can bleed into otherwise decontaminated product in the next loading cycle. The bleed mechanism is shown to be fully isotherm-controlled vs. mass transfer controlled. Knowledge of residual post-elution cesium level and resin isotherm can be utilized to predict rate of cesium bleed in a mostly non-loaded column. Overall, this work demonstrates the versatility of the ion-exchange modeling to study the effects of resin characteristics on processing cycles, rates, and cold chemical consumption. This evaluation justifies further development of a spherical form of the SL644 resin.

Hang, T.; Nash, C. A.; Aleman, S. E.

2012-09-19T23:59:59.000Z

115

Prediction of Corrosion of Alloys in Mixed-Solvent Environments  

SciTech Connect (OSTI)

Corrosion is much less predictable in organic or mixed-solvent environments than in aqueous process environments. As a result, US chemical companies face greater uncertainty when selecting process equipment materials to manufacture chemical products using organic or mixed solvents than when the process environments are only aqueous. Chemical companies handle this uncertainty by overdesigning the equipment (wasting money and energy), rather than by accepting increased risks of corrosion failure (personnel hazards and environmental releases). Therefore, it is important to develop simulation tools that would help the chemical process industries to understand and predict corrosion and to develop mitigation measures. To create such tools, we have developed models that predict (1) the chemical composition, speciation, phase equilibria, component activities and transport properties of the bulk (aqueous, nonaqueous or mixed) phase that is in contact with the metal; (2) the phase equilibria and component activities of the alloy phase(s) that may be subject to corrosion and (3) the interfacial phenomena that are responsible for corrosion at the metal/solution or passive film/solution interface. During the course of this project, we have completed the following: (1) Development of thermodynamic modules for calculating the activities of alloy components; (2) Development of software that generates stability diagrams for alloys in aqueous systems; these diagrams make it possible to predict the tendency of metals to corrode; (3) Development and extensive verification of a model for calculating speciation, phase equilibria and thermodynamic properties of mixed-solvent electrolyte systems; (4) Integration of the software for generating stability diagrams with the mixed-solvent electrolyte model, which makes it possible to generate stability diagrams for nonaqueous or mixed-solvent systems; (5) Development of a model for predicting diffusion coefficients in mixed-solvent electrolyte systems; (6) Development of fundamentals of a detailed kinetic model of general corrosion, which includes a detailed treatment of local chemistry changes near the metal/solution interface coupled with transport through a liquid layer and solid phases at the interface; (7) Development of parameters for OLI's kinetic model of general corrosion of common engineering alloys in aqueous systems with a variety of solutes. With this model, the users will be able to predict the effect of various process conditions (such as environment composition, temperature, pressure) on the general corrosion of alloys; (8)Comprehensive review of the fundamentals of the models by an Academic Review Panel, which was performed in conjunction with three annual review meetings; (9)Development and commercial release of the Corrosion Analyzer, a Windows software product that encompasses the thermodynamic model, a facility for generating stability diagrams and the model for predicting the rates of general corrosion of selected alloys in aqueous systems.

A. Anderko, P. Wang, R. D. Young, D. P. Riemer, P. McKenzie and M. M. Lencka (OLI Systems Inc.); S. S. Babu and P. Angelini (Oak Ridge National Laboratory)

2003-06-05T23:59:59.000Z

116

Solvent refined coal (SRC) process  

SciTech Connect (OSTI)

This report summarizes the progress of the Solvent Refined Coal (SRC) project by The Pittsburg and Midway Coal Mining Co. at the SRC Pilot Plant in Fort Lewis, Washington and the Gulf Science and Technology Company Process Development Unit (P-99) in Harmarville, Pennsylvania, for the Department of Energy during the month of October, 1980. The Fort Lewis Pilot Plant was shut down the entire month of October, 1980 for inspection and maintenance. PDU P-99 completed two runs during October investigating potential start-up modes for the Demonstration Plant.

Not Available

1980-12-01T23:59:59.000Z

117

SOLVENT HOLD TANK SAMPLE RESULTS FOR MCU-11-314, MCU-11-315, MCU-11-316, MCU-11-317, MCU-11-318 AND MCU-11-319  

SciTech Connect (OSTI)

Savannah River National Laboratory (SRNL) analyzed solvent samples from Modular Caustic-Side Solvent Extraction Unit (MCU) in support of continuing operations. A quarterly analysis of the solvent is required to maintain solvent composition within specifications. Analytical results of the analyses of Solvent Hold Tank (SHT) samples MCU-11-314, MCU-11-315, MCU-11-316, MCU-11-317, MCU-11-318 and MCU-11-319 are reported. The results show that the solvent at MCU does not require an Isopar{reg_sign} L addition, but it will require addition of trioctylamine. Cesium mass transfer testing with the solvent matches expected extraction behavior but shows a slightly lower stripping efficiency than seen in the original process demonstration for Macrobatch 3. The entrained aqueous solution indicates the scrub wash is significantly out of specification. As a result, the facility replaced the scrub wash. Unlike the previous solvent sample results, these analyses indicate that the solvent does not require minor Isopar{reg_sign} L trimming at this time. However, addition of TOA is warranted. These findings indicate that the new protocols for solvent monitoring and control are yielding favorable results. Nevertheless, the deviation in the TOA concentration since the last analysis indicates continued periodic (i.e., quarterly) monitoring is recommended. The {sup 137}Cs mass transfer results from the solvent sample testing show possible evidence of slightly reduced stripping efficiency. An evaluation (using a model) of expected system performance for MCU using the measured distribution values predicts an {approx}50% decline in DFs given the ESS test results. The customer should consider pulling a SHT sample for reanalysis.

Peters, T.; Washington, A.; Fondeur, F.; Fink, S.

2011-06-09T23:59:59.000Z

118

The Cesium-137 Agricultural Commodities Irradiator (CACI) final design report  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE's Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the 137 Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site. Over 100 engineering drawings are included.

Not Available

1986-12-19T23:59:59.000Z

119

The Cesium-137 Agricultural Commodities Irradiator (CACI) final design report  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE's Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the 137 Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site. Site characterization data and equipment engineering drawings are included.

Not Available

1986-12-19T23:59:59.000Z

120

Ion exchange performance of commercial crystalline silicotitanates for cesium removal  

SciTech Connect (OSTI)

A new class of inorganic ion exchangers called crystalline silicotitanates (CST), invented by researchers at Sandia National Laboratories and Texas A&M University, has been commercialized in a joint Sandia-UOP effort. The original developmental materials exhibited high selectivity for the ion exchange of cesium, strontium, and several other radionuclides from highly alkaline solutions containing molar concentrations of Na{sup +}. The materials also showed excellent chemical and radiation stability. Together, the high selectivity and stability of the CSTs made them excellent candidates for treatment of solutions such as the Hanford tank supernates and other DOE radwastes. Sandia National Laboratories and UOP have teamed under a Cooperative Research and Development Agreement (CRADA) to develop CSTs in the powdered form and in an engineered form suitable for column ion exchange use. A continuous-flow, column ion exchange process is expected to be used to remove Cs and other radionuclides from the Hanford supernatant. The powder material invented by the Sandia and Texas A&M team consists of submicron-size particles. It is not designed for column ion exchange but may be used in other applications.

Braun, R.; Dangieri, T.J.; Fennelly, D.J. [and others

1996-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Assessment of the exposure pathway in the uptake and distribution of1 americium and cesium in cuttlefish (Sepia officinalis) at different stages of2  

E-Print Network [OSTI]

1 Assessment of the exposure pathway in the uptake and distribution of1 americium and cesium experiments were performed to study the uptake,19 assimilation and retention of americium (241 Am) and cesium

Paris-Sud XI, Université de

122

Determining Reactor Flux from Xenon-136 and Cesium-135 in Spent Fuel  

E-Print Network [OSTI]

The ability to infer the reactor flux from spent fuel or seized fissile material would enhance the tools of nuclear forensics and nuclear nonproliferation significantly. We show that reactor flux can be inferred from the ratios of xenon-136 to xenon-134 and cesium-135 to cesium-137. If the average flux of a reactor is known, the flux inferred from measurements of spent fuel could help determine whether that spent fuel was loaded as a blanket or close to the mid-plane of the reactor. The cesium ratio also provides information on reactor shutdowns during the irradiation of fuel, which could prove valuable for identifying the reactor in question through comparisons with satellite reactor heat monitoring data. We derive analytic expressions for these correlations and compare them to experimental data and to detailed reactor burn simulations. The enrichment of the original uranium fuel affects the correlations by up to 3 percent, but only at high flux.

A. C. Hayes; Gerard Jungman

2012-05-30T23:59:59.000Z

123

The effects of using Cesium-137 teletherapy sources as a radiological weapon (dirty bomb)  

E-Print Network [OSTI]

While radioactive sources used in medical diagnosis do not pose a great security risk due to their low level of radioactivity, therapeutic sources are extremely radioactive and can presumably be used as a radiological weapon. Cobalt-60 and Cesium-137 sources are the most common ones used in radiotherapy with over 10,000 of such sources currently in use worldwide, especially in the developing world, which cannot afford modern accelerators. The present study uses computer simulations to investigate the effects of using Cesium-137 sources from teletherapy devices as a radiological weapon. Assuming a worst-case terrorist attack scenario, we estimate the ensuing cancer mortality, land contamination, evacuation area, as well as the relevant evacuation, decontamination, and health costs in the framework of the linear risk model. The results indicate that an attack with a Cesium-137 dirty bomb in a large metropolitan city (especially one that would involve several teletherapy sources) although would not cause any sta...

Liolios, Theodore

2009-01-01T23:59:59.000Z

124

Decontamination of Radioactive Cesium Released from Fukushima Daiichi Nuclear Power Plant - 13277  

SciTech Connect (OSTI)

Peculiar binding of Cesium to the soil clay minerals remained the major obstacle for the immediate Cs-decontamination of soil and materials containing clay minerals like sludge. Experiments for the removal of Cesium from soil and ash samples from different materials were performed in the lab scale. For soil and sludge ash formed by the incineration of municipal sewage sludge, acid treatment at high temperature is effective while washing with water removed Cesium from ashes of plants or burnable garbage. Though total removal seems a difficult task, water-washing of wood-ash or garbage-ash at 40 deg. C removes >90% radiocesium, while >60% activity can be removed from soil and sludge-ash by acid washing at 95 deg. C. (authors)

Parajuli, Durga; Minami, Kimitaka; Tanaka, Hisashi; Kawamoto, Tohru [Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology - AIST (Japan)] [Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology - AIST (Japan)

2013-07-01T23:59:59.000Z

125

Study of the potential oxidative stress induced by six solvents in the rat brain  

Science Journals Connector (OSTI)

The mechanisms of action involved in the neurotoxicity of solvents are poorly understood. In vitro studies have suggested that the effects of some solvents might be due to the formation of reactive oxygen species (ROS). This study assesses hydroxyl radical (OH) generation and measures malondialdehyde (MDA) levels in the cerebral tissue of rats exposed to six solvents (n-hexane, n-octane, toluene, n-butylbenzene, cyclohexane and 1,2,4-trimethylcyclohexane). Three of these solvents have been shown to generate ROS in studies carried out in vitro on granular cell cultures from rat cerebellum. We assessed OH production by quantifying the rate of formation of 3,4-dihydroxybenzoic acid using a trapping agent, 4-hydroxybenzoic acid, infused via the microdialysis probe, into the prefrontal cortex of rats exposed intraperitoneally to the solvents. Extracellular MDA was quantified in microdialysates collected from the prefrontal cortex of rats exposed, 6 h/day for ten days, to 1000 ppm of the solvents (except for n-butylbenzene, generated at 830 ppm) in inhalation chambers. Tissue levels of free and total MDA were measured in different brain structures for rats acutely (intraperitoneal route) and sub-acutely (inhalation) exposed to solvents. None of the six solvents studied increased the production of hydroxyl radicals in the prefrontal cortex after acute administration. Nor did they increase extracellular or tissue levels of MDA after 10 days’ inhalation exposure. On the other hand, a decrease in the concentrations of free MDA in brain structures was observed after acute administration of n-hexane, 1,2,4-trimethylcyclohexane, toluene and n-butylbenzene. Therefore, data of this study carried out in vivo did not confirm observations made in vitro on cell cultures.

Monique Chalansonnet; Nathalie Carabin; Stéphane Boucard; Frédéric Cosnier; Hervé Nunge; François Gagnaire

2013-01-01T23:59:59.000Z

126

Cesium and Strontium Specific Exchangers for Nuclear Waste Effluent Remediation  

SciTech Connect (OSTI)

During the past 50 years, nuclear defense activities have produced large quantities of nuclear waste that now require safe and permanent disposal. The general procedure to be implemented involves the removal of cesium and strontium from the waste solutions for disposal in permanently vitrified media. This requires highly selective sorbents or ion exchangers. Further, at the high radiation doses present in the solution, organic exchangers or sequestrants are likely to decompose over time. Inorganic ion exchangers are resistant to radiation damage and can exhibit remarkably high selectivities. We have synthesized three families of tunnel-type ion exchangers. The crystal structures of these compounds as well as their protonated phases, coupled with ion exchange titrations, were determined and this information was used to develop an understanding of their ion exchange behavior. The ion exchange selectivities of these phases could be regulated by isomorphous replacement of the framework metals by larger or smaller radius metals. In the realm of layered compounds, we prepared alumina, silica, and zirconia pillared clays and sodium micas. The pillared clays yielded very high Kd values for Cs+ and were very effective in removing Cs+ from groundwaters. The sodium micas also had a high affinity for Cs+ but an even greater attraction for S42+. They also possess the property of trapping these ions permanently as the layers slowly decrease their interlayer distance as loading occurs. Sodium nonatitanate exhibited extremely high Kd values for Sr2+ in alkaline tank wastes and should be considered for removal of Sr2+ in such cases. For tank wastes containing complexing agents, we have found that adding Ca2+ to the solution releases the complexed Sr2+ which may then be removed with the CST exchanger.

A. Clearfield; A. I. Bortun; L. A. Bortun; E. A. Bhlume; P. Sylvester; G. M. Graziano

2000-09-01T23:59:59.000Z

127

New approaches for the reduction of plasma arc drop in second-generation thermionic converters. Final report  

SciTech Connect (OSTI)

Investigations of ion generation and recombination mechanisms in the cesium plasma as they pertain to the advanced mode thermionic energy converter are described. The changes in plasma density and temperature within the converter have been studied under the influence of several promising auxiliary ionization candidate sources. Three novel approaches of external cesium ion generation have been investigated in some detail, namely vibrationally excited N/sub 2/ as an energy source of ionization of Cs ions in a DC discharge, microwave power as a means of resonant sustenance of the cesium plasma, and ion generation in a pulse N/sub 2/-Cs mixture. The experimental data obtained and discussed show that all three techniques - i.e. the non-LTE high-voltage pulsing, the energy transfer from vibrationally excited diatomic gases, and the external pumping with a microwave power - have considerable promise as schemes in auxiliary ion generation applicable to the advanced thermionic energy converter.

Hatziprokopiou, M.E.; Shaw, D.T.

1981-03-31T23:59:59.000Z

128

EVALUATION OF POTENTIAL ELUANTS FOR NON-ACID ELUTION OF CESIUM FROM RESORCINOL-FORMALDEHYDE RESIN  

SciTech Connect (OSTI)

Small-column ion exchange (SCIX) units installed in high-level waste tanks to remove Cs-137 from highly alkaline salt solutions are among the waste treatment plans in the DOE-complex. Spherical Resorcinol-Formaldehyde (sRF) is the ion exchange resin selected for use in the Hanford Waste Treatment and Immobilization Plant (WTP). It is also the primary ion exchange material under consideration for SCIX at the Hanford site. The elution step of the multi-step ion exchange process is typically done with 0.5 M nitric acid. An acid eluant is a potential hazard in the event of a spill, leak, etc. because the high-level waste tanks are made of carbon steel. Corrosion and associated structural damage may ensue. A study has been conducted to explore non-acid elution as an alternative. Batch contact sorption equilibrium screening tests have been conducted with 36 potential non-acid eluants. The sorption tests involve equilibrating each cesium-containing eluant solution with the sRF resin for 48 hours at 25 C in a shaker oven. In the sorption tests, an eluant is deemed to have a high cesium elution potential if it minimizes cesium sorption onto the sRF resin. The top candidates (based on lowest cesium sorption distribution coefficients) include ammonium carbonate, ammonium carbonate/ammonium hydroxide, ammonium bicarbonate, rubidium carbonate, ammonium acetate, ammonium acetate/ammonium hydroxide, ammonium bicarbonate/ammonium hydroxide, calcium chloride, and magnesium chloride. A select few of the top candidate eluants from the screening tests were subjected to actual sorption (loading) and elution tests to confirm their elution ability. The actual sorption (loading) and elution tests mimicked the typical sRF-cesium ion exchange process (i.e., sorption or loading, caustic wash, water rinse, and elution) via batch contact sorption and quasi column caustic wash/water rinse/elution. The eluants tested included ammonium carbonate, ammonium acetate, calcium acetate, magnesium acetate, and nitric acid. Calcium acetate and magnesium acetate were substitutes for calcium chloride and magnesium chloride respectively due to corrosion concerns. Nitric acid was selected for benchmarking since it is the baseline cesium eluant for sRF resin. The cesium elution performance of ammonium carbonate and ammonium acetate was approximately the same as the benchmark eluant, nitric acid. Ninety-seven (97), 94, and 100% percent of the cesium sorbed or loaded were eluted by ammonium carbonate, ammonium acetate, and nitric acid was respectively. The performance of calcium acetate and magnesium acetate, on the other hand, was mediocre. Percent elution was 16 and 8 respectively.

Adu-Wusu, K.; Pennebaker, F.

2010-12-22T23:59:59.000Z

129

Ionic Liquids as Green Solvents for Alkylation and Acylation  

Science Journals Connector (OSTI)

Many clean solvents like water, ionic liquids, supercritical fluid, polyglycol, fluorine-containing solvents, and so on are employed to replace the conventional organic solvents. Among these, ionic liquids have a...

Zhongkui Zhao; Yitao Dai

2012-01-01T23:59:59.000Z

130

Solvent Isotope-Induced Equilibrium Perturbation for Isocitrate Lyase  

Science Journals Connector (OSTI)

Solvent Isotope-Induced Equilibrium Perturbation for Isocitrate Lyase ... Solvent isotopic composition can influence both the rates of enzyme-catalyzed reactions (solvent kinetic isotope effects) and, in the case of solvent-derived deuterium incorporation into nonexchangeable C–H bonds in products, solvent equilibrium isotope effects. ... In this study, we report the solvent isotope-induced transient change in the concentration and isotopic composition of the reactants. ...

Christine E. Quartararo; Timin Hadi; Sean M. Cahill; John S. Blanchard

2013-11-21T23:59:59.000Z

131

EVALUATION OF ARG-1 SAMPLES PREPARED BY CESIUM CARBONATE DISSOLUTION DURING THE ISOLOK SME ACCEPTABILITY TESTING  

SciTech Connect (OSTI)

Evaluation of Defense Waste Processing Facility (DWPF) Chemical Process Cell (CPC) cycle time identified several opportunities to improve the CPC processing time. The Mechanical Systems & Custom Equipment Development (MS&CED) Section of the Savannah River National Laboratory (SRNL) recently completed the evaluation of one of these opportunities - the possibility of using an Isolok sampling valve as an alternative to the Hydragard valve for taking DWPF process samples at the Slurry Mix Evaporator (SME). The use of an Isolok for SME sampling has the potential to improve operability, reduce maintenance time, and decrease CPC cycle time. The SME acceptability testing for the Isolok was requested in Task Technical Request (TTR) HLW-DWPF-TTR-2010-0036 and was conducted as outlined in Task Technical and Quality Assurance Plan (TTQAP) SRNLRP-2011-00145. RW-0333P QA requirements applied to the task, and the results from the investigation were documented in SRNL-STI-2011-00693. Measurement of the chemical composition of study samples was a critical component of the SME acceptability testing of the Isolok. A sampling and analytical plan supported the investigation with the analytical plan directing that the study samples be prepared by a cesium carbonate (Cs{sub 2}CO{sub 3}) fusion dissolution method and analyzed by Inductively Coupled Plasma - Optical Emission Spectroscopy (ICP-OES). The use of the cesium carbonate preparation method for the Isolok testing provided an opportunity for an additional assessment of this dissolution method, which is being investigated as a potential replacement for the two methods (i.e., sodium peroxide fusion and mixed acid dissolution) that have been used at the DWPF for the analysis of SME samples. Earlier testing of the Cs{sub 2}CO{sub 3} method yielded promising results which led to a TTR from Savannah River Remediation, LLC (SRR) to SRNL for additional support and an associated TTQAP to direct the SRNL efforts. A technical report resulting from this work was issued that recommended that the mixed acid method be replaced by the Cs{sub 2}CO{sub 3} method for the measurement of magnesium (Mg), sodium (Na), and zirconium (Zr) with additional testing of the method by DWPF Laboratory being needed before further implementation of the Cs{sub 2}CO{sub 3} method at that laboratory. While the SME acceptability testing of the Isolok does not address any of the open issues remaining after the publication of the recommendation for the replacement of the mixed acid method by the Cs{sub 2}CO{sub 3} method (since those issues are to be addressed by the DWPF Laboratory), the Cs{sub 2}CO{sub 3} testing associated with the Isolok testing does provide additional insight into the performance of the method as conducted by SRNL. The performance is to be investigated by looking to the composition measurement data generated by the samples of a standard glass, the Analytical Reference Glass - 1 (ARG-1), that were prepared by the Cs{sub 2}CO{sub 3} method and included in the SME acceptability testing of the Isolok. The measurements of these samples were presented as part of the study results, but no statistical analysis of these measurements was conducted as part of those results. It is the purpose of this report to provide that analysis, which was supported using JMP Version 7.0.2.

Edwards, T.; Hera, K.; Coleman, C.

2011-12-05T23:59:59.000Z

132

Cleaning solvent substitution in electronic assemblies  

SciTech Connect (OSTI)

Alternatives to chlorinated and fluorinated solvents have been identified, qualified, and implemented into production of complex electronic assemblies. Extensive compatibility studies were performed with components, piece-parts, and materials. Electrical testing and accelerated aging were used to screen for detrimental, long-term effects. A terpene, d-limonene, has been selected as the solvent of choice for cleaning complex electronic assemblies, and has been found to be compatible with the components and materials tested. A brief history of the overall project will be presented, along with representative cleaning efficiency results, compatibility results, and residual solvent data.

Meier, G.J.

1993-09-01T23:59:59.000Z

133

Firing of pulverized solvent refined coal  

DOE Patents [OSTI]

A burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired successfully without any performance limitations and without the coking of the solvent refined coal on the burner components. The burner is provided with a tangential inlet of primary air and pulverized fuel, a vaned diffusion swirler for the mixture of primary air and fuel, a center water-cooled conical diffuser shielding the incoming fuel from the heat radiation from the flame and deflecting the primary air and fuel steam into the secondary air, and a watercooled annulus located between the primary air and secondary air flows.

Lennon, Dennis R. (Allentown, PA); Snedden, Richard B. (McKeesport, PA); Foster, Edward P. (Macungie, PA); Bellas, George T. (Library, PA)

1990-05-15T23:59:59.000Z

134

Switchable solvents and methods of use thereof  

DOE Patents [OSTI]

A solvent that reversibly converts from a nonionic liquid mixture to an ionic liquid upon contact with a selected trigger, e.g., contact with CO.sub.2, is described. In preferred embodiments, the ionic solvent is readily converted back to the nonionic liquid mixture. The nonionic liquid mixture includes an amidine or guanidine or both, and water, alcohol, or a combination thereof. Single component amine solvents that reversibly convert between ionic and non-ionic states are also described. Some embodiments require increased pressure to convert; others convert at 1 atmosphere.

Jessop, Philip G; Eckert, Charles A; Liotta, Charles L; Heldebrant, David J

2014-04-29T23:59:59.000Z

135

Motion planning for robotic spray cleaning with environmentally safe solvents  

SciTech Connect (OSTI)

Automatic motion planning of a spray cleaning robot with collision avoidance is presented in this paper. In manufacturing environments, electronic and mechanical components are traditionally cleaned by spraying or dipping them using chlorofluorocarbon (CFC) solvents. As new scientific data show that such solvents are major causes for stratospheric ozone depletion, an alternate cleaning method is needed. Part cleaning with aqueous solvents is environmentally safe, but can require precision spraying at high pressures for extended time periods. Operator fatigue during manual spraying can decrease the quality of the cleaning process. By spraying with a robotic manipulator, the necessary spray accuracy and consistency to manufacture highreliability components can be obtained. Our motion planner was developed to automatically generate motions for spraying robots based on the part geometry and cleaning process parameters. For spraying paint and other coatings a geometric description of the parts and robot may be sufficient for motion planning, since coatings are usually done over the visible surfaces. For spray cleaning, the requirement to reach hidden surfaces necessitates the addition of a rule-based method to the geometric motion planning.

Hwang, Yong K.; Meirans, L.; Drotning, W.D.

1993-09-01T23:59:59.000Z

136

Kinetics and Solvent Effects in the Synthesis of Ionic Liquids.  

E-Print Network [OSTI]

??Ionic liquids (ILs) are being recognized as environmentally friendly ("green") solvents. However, their synthesis is often conducted in the very solvents that they will reportedly… (more)

Schleicher, Jay C.

2007-01-01T23:59:59.000Z

137

Ionic Liquids as Green Solvents: Progress and Prospects  

Science Journals Connector (OSTI)

Volatile organic solvents (VOS) creating increasing air pollution are ... researches are directed on developing alternative environmental friendly solvent systems to replace traditional volatile organics. Within ...

Shadpour Mallakpour; Mohammad Dinari

2012-01-01T23:59:59.000Z

138

Designing Switchable-Hydrophilicity Solvents and Modelling Their Behaviour.  

E-Print Network [OSTI]

??Switchable-hydrophilicity solvents (SHSs) are solvents that in one state forms a biphasic mixture with water but can be reversibly switched to another state that is… (more)

DURELLE, JEREMY RONALD

2014-01-01T23:59:59.000Z

139

Advanced Water Removal via Membrane Solvent Extraction | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Water Removal via Membrane Solvent Extraction Advanced Water Removal via Membrane Solvent Extraction advwaterremovalmse.pdf More Documents & Publications Advance Patent Waiver...

140

Release and transport of fission product cesium in the TMI-2 accident  

SciTech Connect (OSTI)

Approximately 50% of the fission product cesium was released from the overheated UO/sub 2/ fuel in the TMI-2 accident. Steam that boiled away from a water pool in the bottom of the reactor vessel transported the released fission products throughout the reactor coolant system (RCS). Some fission products passed directly through a leaking valve with steam and water into the containment structure, but most deposited on dry surfaces inside of the RCS before being dissolved or resuspended when the RCS was refilled with water. A cesium transport model was developed that extended measured cesium in the RCS back to the first day of the accident. The model revealed that approx.62% of the released /sup 137/Cs deposited on dry surfaces inside of the RCS before being slowly leached and transported out of the RCS in leaked or letdown water. The leach rates from the model agreed reasonably well with those measured in the laboratory. The chemical behavior of cesium in the TMI-2 accident agreed with that observed in fission product release tests at Oak Ridge National Laboratory (ORNL).

Lorenz, R.A.; Collins, J.L.

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

CESIUM SORPTION TO ILLITE AS AFFECTED BY OXALATE LAURA A. WENDLING  

E-Print Network [OSTI]

in shallow soil systems contaminated as a result of nuclear weapons testing, nuclear reactor accidents, and past waste-disposal practices at nuclear facilities. Cesium contributes a major portion of the radio- activity at many sites associated with nuclear weapons production (Riley et al., 1992

Flury, Markus

142

Versatile Ionic Liquids as Green Solvents  

Science Journals Connector (OSTI)

The commonly used solvents like benzene, toluene, methylene chloride etc. for organic synthesis, particularly in industrial production, are known to cause health and environmental problems. In view of this, th...

V. K. Ahluwalia; M. Kidwai

2004-01-01T23:59:59.000Z

143

Green Solvents Fundamental and Industrial Applications  

Science Journals Connector (OSTI)

The toxicity and volatile nature of many organic solvents, widely utilized in huge amounts for organic ... to the environment. Thus, the principles of green chemistry direct to use safer and environmentally frien...

Shadpour Mallakpour; Zahra Rafiee

2012-01-01T23:59:59.000Z

144

Novel Solvent System for CO2 Capture  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Solvent System for CO Solvent System for CO 2 Capture Background The mission of the U.S. Department of Energy/National Energy Technology Laboratory (DOE/NETL) Existing Plants, Emissions & Capture (EPEC) Research & Development (R&D) Program is to develop innovative environmental control technologies to enable full use of the nation's vast coal reserves, while at the same time allowing the current fleet of coal-fired power plants to comply with existing and emerging environmental

145

Hydrogen recovery by novel solvent systems  

SciTech Connect (OSTI)

The objective of this work is to develop a novel method for purification of hydrogen from coal-derived synthesis gas. The study involved a search for suitable mixtures of solvents for their ability to separate hydrogen from the coal derived gas stream in significant concentration near their critical point of miscibility. The properties of solvent pairs identified were investigated in more detail to provide data necessary for economic evaluation and process development.

Shinnar, R.; Ludmer, Z.; Ullmann, A.

1991-08-01T23:59:59.000Z

146

Performance modeling of an integral, self-regulating cesium reservoir for the ATI-TFE  

SciTech Connect (OSTI)

This work covers the performance modeling of an integral metal-matrix cesium-graphite reservoir for operation in the Advanced Thermionic Initiative-Thermionic Fuel Element (ATI-TFE) converter configuration. The objectives of this task were to incorporate an intercalated cesium-graphite reservoir for the 3C[sub 24]Cs[r arrow]2C[sub 36]Cs+Cs[sub (g)] two phase equilibrium reaction into the emitter lead region of the ATI-TFE. A semi two-dimensional, cylindrical TFE computer model was used to obtain thermal and electrical converter output characteristics for various reservoir locations. The results of this study are distributions for the interelectrode voltage, output current density, and output power density as a function of axial position along the TFE emitter. This analysis was accomplished by identifying an optimum cesium pressure for three representative pins in the ATI driverless'' reactor core and determining the corresponding position of the graphite reservoir in the ATI-TFE lead region. The position for placement of the graphite reservoir was determined by performing a first-order heat transfer analysis of the TFE lead region to determine its temperature distribution. The results of this analysis indicate that for the graphite reservoirs investigated the 3C[sub 24]Cs[r arrow]2C[sub 36]Cs+Cs[sub (g)] equilibrium reaction reservoir is ideal for placement in the TFE emitter lead region. This reservoir can be directly coupled to the emitter, through conduction, to provide the desired cesium pressure for optimum performance. The cesium pressure corresponding to the optimum converter output performance was found to be 2.18 torr for the ATI core least power TFE, 2.92 torr for the average power TFE, and 4.93 torr for the maximum power TFE.

Thayer, K.L.; Ramalingam, M.L. (UES, In., 4401 Dayton-Xenia Road, Dayton, Ohio 45432-1894 (United States)); Young, T.J. (Aerospace Power Division, Wright Laboratory/POOC, Wright-Patterson AFB, Ohio 45433-6563 (United States))

1993-01-20T23:59:59.000Z

147

Influence of solute-solvent coordination on the orientational relaxation of ion assemblies in polar solvents  

Science Journals Connector (OSTI)

We have investigated the rotational dynamics of lithium thiocyanate (LiNCS) dissolved in various polar solvents with time and polarization resolved vibrational spectroscopy. LiNCS forms multiple distinct ionic structures in solution that can be distinguished with the CN stretch vibrational frequency of the different ionic assemblies. By varying the solvent and the LiNCS concentration the number and type of ionic structures present in solution can be controlled. Control of the ionic structure provides control over the volume shape and dipole moment of the solute critical parameters for hydrodynamic and dielectric continuum models of friction. The use of solutes with sizes comparable to or smaller than the solvent molecules also helps amplify the sensitivity of the measurement to the short-ranged solute-solvent interaction. The measured orientational relaxation dynamics show many clear and distinct deviations from simple hydrodynamic behavior. All ionic structures in all solvents exhibit multi-exponential relaxation dynamics that do not scale with the solute volume. For Lewis base solvents such as benzonitrile dimethyl carbonate and ethyl acetate the observed dynamics strongly show the effect of solute-solvent complex formation. For the weak Lewis base solvent nitromethane we see no evidence for solute-solvent complex formation but still see strong deviation from the predictions of simple hydrodynamic theory.

Minbiao Ji; Robert W. Hartsock; Zheng Sung; Kelly J. Gaffney

2012-01-01T23:59:59.000Z

148

Comments on Origin of Solvent Knight Shifts in Alloys  

Science Journals Connector (OSTI)

The various sources of changes in solvent Knight shifts upon alloying, and nonlinear effects are examined.

R. E. WATSON; L. H. BENNETT; A. J. FREEMAN

1969-03-10T23:59:59.000Z

149

An approach for solvent selection in extractive distillation systems including safety considerations  

E-Print Network [OSTI]

Chemical Engineering Department, Instituto Tecnológico de Celaya, Celaya, GTO 38060 México 2 Chemical Engineering, Texas A&M University, College Station, TX 77843 and The Mary Kay O'Connor Process Safety Center implications that a given solvent generates for the process, are generally left for their consideration after

Grossmann, Ignacio E.

150

Water quality criteria for colored smokes: Solvent Yellow 33, Final report. [Contains glossary  

SciTech Connect (OSTI)

The available data on the environmental fate, aquatic toxicity, and mammalian toxicity of Solvent Yellow 33, a quinoline dye used in colored smoke grenades, were reviewed. The US Environmental Protection Agency (USEPA) guidelines were used in an attempt to generate water quality criteria for the protection of aquatic life and its use and of human health. 87 refs., 2 figs., 13 tabs.

Davidson, K.A.; Hovatter, P.S.

1987-11-01T23:59:59.000Z

151

Structure-Property Relationships in Lithium, Silver, and Cesium Uranyl Borates  

SciTech Connect (OSTI)

Four new uranyl borates, Li[UO{sub 2}B{sub 5}O{sub 9}]·H{sub 2}O (LiUBO-1), Ag[(UO{sub 2})B{sub 5}O{sub 8}(OH){sub 2}] (AgUBO-1), ?-Cs[(UO{sub 2}){sub 2}B{sub 11}O{sub 16}(OH){sub 6}] (CsUBO-1), and ?-Cs[(UO{sub 2}){sub 2}B{sub 11}O{sub 16}(OH){sub 6}] (CsUBO-2) were synthesized via the reaction of uranyl nitrate with a large excess of molten boric acid in the presence of lithium, silver, or cesium nitrate. These compounds share a common structural motif consisting of a linear uranyl, UO{sub 2}{sup 2+}, cation surrounded by BO{sub 3} triangles and BO{sub 4} tetrahedra to create an UO{sub 8} hexagonal bipyramidal environment around uranium. The borate anions bridge between uranyl units to create sheets. Additional BO{sub 3} triangles extend from the polyborate layers, and are directed approximately perpendicular to the sheets. In Li[(UO{sub 2})B{sub 5}O{sub 9}]·H{sub 2}O, the additional BO{sub 3} triangles connect these sheets together to form a three-dimensional framework structure. Li[UO{sub 2})B{sub 5}O{sub 9}]·H{sub 2}O and ?-Cs[(UO{sub 2}){sub 2}B{sub 11}O{sub 16}(OH){sub 6}] adopt noncentrosymmetric structures, while Ag[(UO{sub 2})B{sub 5}O{sub 8}(OH){sub 2}] and ?-Cs[(UO{sub 2}){sub 2}B{sub 11}O{sub 16}(OH){sub 6}] are centrosymmetric. Li[(UO{sub 2})B{sub 5}O{sub 9}]·H{sub 2}O, which can be obtained as pure phase, displays second-harmonic generation of 532 nm light from 1064 nm light. Topological relationships of all actinyl borates are developed.

Wang, Shuao; Alekseev, Evgeny V.; Stritzinger, Jared T.; Liu, Guokui; Depmeier, Wulf; Albrecht-Schmitt, Thomas E.

2010-01-01T23:59:59.000Z

152

Solvent-resistant microporous polymide membranes  

DOE Patents [OSTI]

An asymmetric microporous membrane with exceptional solvent resistance and highly desirable permeability is disclosed. The membrane is made by a solution-casting or solution-spinning process from a copolyamic acid comprising the condensation reaction product in a solvent of at least three reactants selected from certain diamines and dianhydrides and post-treated to imidize and in some cases cross-link the copolyamic acid. The membrane is useful as an uncoated membrane for ultrafiltration, microfiltration, and membrane contactor applications, or may be used as a support for a permselective coating to form a composite membrane useful in gas separations, reverse osmosis, nanofiltration, pervaporation, or vapor permeation.

Miller, W.K.; McCray, S.B.; Friesen, D.T.

1998-03-10T23:59:59.000Z

153

Solvent-resistant microporous polymide membranes  

DOE Patents [OSTI]

An asymmetric microporous membrane with exceptional solvent resistance and highly desirable permeability is disclosed. The membrane is made by a solution-casting or solution-spinning process from a copolyamic acid comprising the condensation reaction product in a solvent of at least three reactants selected from certain diamines and dianhydrides and post-treated to imidize and in some cases cross-link the copolyamic acid. The membrane is useful as an uncoated membrane for ultrafiltration, microfiltration, and membrane contactor applications, or may be used as a support for a permselective coating to form a composite membrane useful in gas separations, reverse osmosis, nanofiltration, pervaporation, or vapor permeation.

Miller, Warren K. (Bend, OR); McCray, Scott B. (Bend, OR); Friesen, Dwayne T. (Bend, OR)

1998-01-01T23:59:59.000Z

154

Low Level Gamma Spectroscopy Measurements of Radium and Cesium in Lucerne (Medicago Sativa)  

SciTech Connect (OSTI)

Nineteen years after Chernobyl nuclear accident, activity concentration of 137Cs still could be detected in food and soil samples in Central and Eastern Europe. In this paper radiation levels of radium and cesium in Lucerne will be presented. It is a perennial plant with a deep root system and it is widely grown throughout the world as forage for cattle. The samples of Lucerne were taken from twelve different locations in Vojvodina in the summer period July-September 2004. The samples were specially dried on the air and after that ground, powdered and mineralized by method of dry burning on the temperature of 450 deg. C. Gamma spectrometry measurements of the ash were performed by means of actively shielded germanium detector with maximal background reduction. For cesium 137Cs 10 mBq/kg order of magnitude detection limits were achieved.

Fokapic, S.; Bikit, I.; Mrda, D.; Veskovic, M.; Slivka, J. [Department of Physics, Faculty of Sciences, University of Novi Sad, Trg Dositeja Obradovica 4, 21 000 Novi Sad (Serbia); Mihaljev, Z. [Scientific Veterinary Institute, Rumenacki put 20, 21 000 Novi Sad (Serbia); Cupic, Z. [Research Institute for Reproduction, A.I. and Embryo Transfer Temerin, 21235 Temerin, Industrijska zona bb. (Serbia)

2007-04-23T23:59:59.000Z

155

Intermediate-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-102  

SciTech Connect (OSTI)

Ion exchange tests have been completed at the Savannah River Technology Center for British Nuclear Fuels Limited, Inc. as part of the Hanford River Protection Project. Radioactive cesium and technetium (pertechnetate form only) were removed by ion exchange from a sample of Envelope C salt solution from Hanford Tank 241-AN-102 (sample volume: approximately 17 L at 4.8 M Na plus). The original sample was diluted and subjected to strontium/transuranics (Sr/TRU) precipitation and filtration processes before ion exchange processing was performed. Batch contact and column tests for the ion exchange removal of cesium and technetium were then completed on the Sr/TRU-decontaminated product. Previous ion exchange tests were conducted on a smaller portion (0.5 L) of the Tank 241-AN-102 supernate sample, which had been similarly pretreated, and the results were reported in a separate document.

King, W.D.

2001-02-15T23:59:59.000Z

156

Intermediate-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-102  

SciTech Connect (OSTI)

Ion exchange tests have been completed at the Savannah River Technology Center for British Nuclear Fuels Limited, Inc. as part of the Hanford River Protection Project. Radioactive cesium and technetium (pertechnetate form only) were removed by ion exchange from a sample of Envelope C salt solution from Hanford Tank 241-AN-102 (sample volume: approximately 18 L at 4.8 M Na plus). The original sample was diluted and subjected to strontium/transuranics (Sr/TRU) precipitation and filtration processes before ion exchange processing was performed. Batch contact and column tests for the ion exchange removal of cesium and technetium were then completed on the Sr/TRU-decontaminated product. Previous ion exchange tests were conducted on a smaller portion (0.5 L) of the Tank 241-AN-102 supernate sample, which had been similarly pretreated, and the results were reported in a separate document.

King, W.D.

2001-09-10T23:59:59.000Z

157

Light storage via coherent population oscillation in a thermal cesium vapor  

E-Print Network [OSTI]

We report on the storage of light via the phenomenon of Coherent Population Oscillation (CPO) in an atomic cesium vapor at room temperature. In the experiment the optical information of a probe field is stored in the CPO of two ground states of a Lambda three-level system formed by the Zeeman sublevels of the hyperfine transition F = 3 - F' = 2 of cesium D2 line. We show directly that this CPO based memory is very insensitive to stray magnetic field inhomogeneities and presents a lifetime which is mainly limited only by atomic motion. A theoretical simulation of the measured spectra was also developed and is in very good agreement with the experiment.

A. J. F. de Almeida; J. Sales; M. -A. Maynard; T. Laupretre; F. Bretenaker; D. Felinto; F. Goldfarb; J. W. R. Tabosa

2014-09-19T23:59:59.000Z

158

Modeling the Effect of Sedimentation on Cesium Transport in Fourmile Branch  

SciTech Connect (OSTI)

The major mechanisms of radioactive material transport and fate in surface water are (1) sources, (2) dilution, advection and dispersion of radionuclides by flow and surface waves, (3) radionuclide decay, and (4) interaction between sediment and radionuclides. STREAM II, an aqueous transport module of the Savannah River Site emergency response WIND system, accounts for the source term, and the effects of dilution, advection and dispersion. Although the model has the capability to account for nuclear decay, due to the short time interval of interest for emergency response, the effect of nuclear decay is very small and so it is not employed. The interactions between the sediment and radionuclides are controlled by the flow conditions and physical and chemical characteristics of the radionuclides and the sediment constituents. The STREAM II version used in emergency response does not model the effects of sediment deposition/resuspension to minimize computing time. This study estimates the effects of sediment deposition/resuspension on radionuclide aqueous transport. For radionuclides that adsorb onto suspended sediment, the omission of deposition/resuspension effects overestimates the downstream radionuclide peak concentration and is therefore conservative. For the case of cesium transport in the Fourmile Branch, the calculated reduction in peak concentration as the cesium is transported downstream is greater with sediment deposition modeled than without. For example, including the effects of sediment deposition/resuspension in the STREAM II calculation results in a 72 percent reduction in the downstream (5075 meters downstream from H-Area) peak cesium concentration. It is important to note that the high partition coefficient appropriate for cesium enhances the importance of sediment deposition/resuspension; the reduction in the calculated peak concentration would be less for radioisotopes with lower partition coefficients.

Chen, K.F.

2001-02-22T23:59:59.000Z

159

A kinetic model for ion exchange between cesium and sodium using silico-titanates  

E-Print Network [OSTI]

over this entire range of pH. This unique characteristic makes the TAMS material desirable. Two other available organic ion exchangers (carboxylic acid based resin and resorcinol formaldehyde resin) show some capability for cesium removal; however... et al. (1947) used this method successfully to predict their data with the phenol-formaldehyde resinous exchanger, Amberlite IR-1. Similarly, Nachod and Wood (1944) and Turse and Rieman (1961) found their data fitted quite well on both zeolites...

Nguyen, Luan Thanh

1994-01-01T23:59:59.000Z

160

Small-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-102  

SciTech Connect (OSTI)

The pretreatment process for BNFL, Inc.'s Hanford River Protection Project is to provide decontaminated low activity waste and concentrated eluate streams for vitrification into low and high activity waste glass, respectively. The pretreatment includes sludge washing, filtration, precipitation, and ion exchange processes to remove entrained solids, cesium, transuranics, technetium, and strontium. The cesium (Cs-137) and technetium (Tc-99) ion exchange removal is accomplished by using SuperLig 644, and 639 resins from IBC Advanced Technologies, American Fork, Utah. The resins were shown to selectively remove cesium and technetium (as anionic pertechnetate ) from alkaline salt solutions. The efficiency of ion exchange column loading and elution is a complex function involving feed compositions, equilibrium and kinetic behavior of ion exchange resins, diffusion, and the ionic strength and pH of the aqueous solution. A previous experimental program completed at the Savannah River Tech nology Center2 demonstrated the conceptualized flow sheet parameters with an Envelope C sample from Hanford Tank 241-AN-107. Those experiments also included determination of Cs and Tc batch distribution coefficients by SuperLig 644 and 639 resins and demonstration of small-scale column breakthrough and elution. The experimental findings were used in support of preliminary design bases and pretreatment flow sheet development by BNFL, Inc.

Hassan, N.M.

2000-07-27T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Small-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-103  

SciTech Connect (OSTI)

The pretreatment process for BNFL, Inc.'s Hanford River Protection Project is to provide decontaminated low activity waste and concentrated eluate streams for vitrification into low activity and high level waste glass, respectively. The pretreatment includes sludge washing, filtration, precipitation, and ion exchange processes to remove entrained solids, cesium, transuranics, technetium, and strontium. The ion exchange removal of cesium (Cs) and technetium (Tc) ions is accomplished by using SuperLig 644, and 639 resins from IBC Advanced Technologies, American Fork, Utah. The resins were shown to selectively remove cesium and technetium (as pertechnetate), from alkaline salt solutions. The efficiency of ion exchange column loading and elution is a complex function involving feed compositions, equilibrium and kinetic behavior of ion exchange resins, diffusion, and the ionic strength and pH of the aqueous solution. A previous experimental program completed at the Savannah River Technology Center demonstrated the conceptualized flow sheet parameters with a similar Hanford tank sample (241-AW-101). Those experiments included determination of Cs and Tc batch distribution coefficients by SuperLig 644 and 639 resins and demonstration of small-scale column breakthrough and elution. The experimental findings were used in support of preliminary design bases and pretreatment flow sheet development by BNFL, Inc.

Hassan, N.M.

2000-07-27T23:59:59.000Z

162

Fire Safety Tests for Cesium-Loaded Spherical Resorcinol Formaldehyde Resin: Data Summary Report  

SciTech Connect (OSTI)

A draft safety evaluation of the scenario for spherical resorcinol formaldehyde (SRF) resin fire inside the ion exchange column was performed by the Hanford Tank Waste Treatment and Immobilization Plant (WTP) Fire Safety organization. The result of this draft evaluation suggested a potential change of the fire safety classification for the Cesium Ion Exchange Process System (CXP) emergency elution vessels, equipment, and piping. To resolve this question, the fire properties of the SRF resin were measured by Southwest Research Institute (SwRI) through a subcontract managed by Pacific Northwest National Laboratory (PNNL). The results of initial fire safety tests on the SRF resin were documented in a previous report (WTP-RPT-218). The present report summarizes the results of additional tests performed by SwRI on the cesium-loaded SRF resin. The efforts by PNNL were limited to summarizing the test results provided by SwRI into one consolidated data report. The as-received SwRI report is attached to this report in the Appendix A. Where applicable, the precision and bias of each test method, as given by each American Society for Testing and Materials (ASTM) standard procedure, are included and compared with the SwRI test results of the cesium-loaded SRF resin.

Kim, Dong-Sang; Schweiger, Michael J.; Peterson, Reid A.

2012-09-01T23:59:59.000Z

163

DEGRADED TBP SOLVENT REGENERATION TECHNOLOGY USING BUTYLAMINE AS A SOLVENT WASHING TO REDUCE SOLID SALT WASTE  

SciTech Connect (OSTI)

Normal butylamine compounds are studied as salt-free wash reagents for degraded solvent used in PUREX process in spent fuel reprocessing. The solvent wash tests were carried out with two types of butylamine compounds, n-butylamine oxalate and n-butylamine bicarbonate, by counter-current mode using a small size mixer-settler composed of two 4-stage wash steps. Di-n-butyl phosphoric acid (HDBP), the main degradation product from TBP, was removed from real degraded solvent with decontamination factor of 2.5 {approx} 7.9. The study on electrolytic decomposition of butylamine compounds was also conducted for waste treatment.

Asakura, T.; Itoh, Y.; Hotoku, S.; Morita, Y.; Uchiyama, G.

2003-02-27T23:59:59.000Z

164

Gas separation by composite solvent-swollen membranes  

DOE Patents [OSTI]

There is disclosed a composite immobilized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorus or sulfur atom, and having a boiling point of at least 100 C and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation. 3 figs.

Matson, S.L.; Lee, E.K.L.; Friesen, D.T.; Kelly, D.J.

1989-04-25T23:59:59.000Z

165

Gas separation by composite solvent-swollen membranes  

DOE Patents [OSTI]

There is disclosed a composite immobulized liquid membrane of a solvent-swollen polymer and a microporous organic or inorganic support, the solvent being at least one highly polar solvent containing at least one nitrogen, oxygen, phosphorous or sulfur atom, and having a boiling point of at least 100.degree. C. and a specified solubility parameter. The solvent or solvent mixture is homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. The membrane is suitable for acid gas scrubbing and oxygen/nitrogen separation.

Matson, Stephen L. (Harvard, MA); Lee, Eric K. L. (Acton, MA); Friesen, Dwayne T. (Bend, OR); Kelly, Donald J. (Bend, OR)

1989-01-01T23:59:59.000Z

166

Conserve Energy: Modernize Your Solvent Deasphalting Unit  

E-Print Network [OSTI]

of Catalytic Cracking-Hydro cracking Feed & Asphalt"; Presented at NPRA Annual Meeting, March 1971, Paper AM-71-15. 4. nitman, J. G.; "Solvent Deasphalting A Versatile Tool for the Preparation of Lube Hydrotreated Feed Stocks"; Presented at API Midyear...

Lambert, J. S.; Gleitsmann, J. W.

1983-01-01T23:59:59.000Z

167

Ionic Liquids as Green Solvents for Glycosylation Reactions  

Science Journals Connector (OSTI)

Ionic liquids are among the most promising alternatives to molecular organic solvents due to their unique properties and, in particular, are considered to be green solvents due to their nonvolatile and nonflammab...

Kaname Sasaki; Daisuke Takahashi; Kazunobu Toshima

2012-01-01T23:59:59.000Z

168

Terpenes as Green Solvents for Natural Products Extraction  

Science Journals Connector (OSTI)

This chapter presents a complete picture of current knowledge on useful and green bio-solvent “terpenes” obtained from aromatic plants and ... Terpenes could be a successful substitute for petroleum solvents, suc...

Chahrazed Boutekedjiret; Maryline Abert Vian…

2014-01-01T23:59:59.000Z

169

Organic Ionic Liquids: Ultimate Green Solvents in Organic Synthesis  

Science Journals Connector (OSTI)

Ionic liquids are ground-breaking green alternatives to the highly toxic solvents that are hazardous to the environment and ... liquids offer certain advantages as alternatives to conventional solvents. Ionic liq...

Mohammed Abid Shaikh; Xudong Huang

2012-01-01T23:59:59.000Z

170

The Stability of Organic Solvents and Carbon Electrode in Nonaqueous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The Stability of Organic Solvents and Carbon Electrode in Nonaqueous Li-O2 Batteries. The Stability of Organic Solvents and Carbon Electrode in Nonaqueous Li-O2 Batteries....

171

Solvent-Mediated Folding of a Doubly Charged Anion. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Solvent-Mediated Folding of a Doubly Charged Anion. Solvent-Mediated Folding of a Doubly Charged Anion. Abstract: The microsolvation of suberate dianion, -O2C(CH2)6CO2-, with two...

172

Kinetics and Solvent Effects in the Synthesis of Ionic Liquids  

E-Print Network [OSTI]

Ionic liquids (ILs) are being recognized as environmentally friendly ("green") solvents. However, their synthesis is often conducted in the very solvents that they will reportedly replace. This research has investigated ...

Schleicher, Jay C.

2007-12-12T23:59:59.000Z

173

Construction of prototype system for directional solvent extraction desalination  

E-Print Network [OSTI]

Directional solvent extraction has been demonstrated as a low temperature, membrane free desalination process. This method dissolves the water into an inexpensive, benign directional solvent, rejects the contaminants, then ...

Fowler, Michael James

2012-01-01T23:59:59.000Z

174

Use of solvents and environmental friendly materials for applications in Green Chemistry.  

E-Print Network [OSTI]

??The present Thesis studies three alternative solvent groups as sustainable replacement of traditional organic solvents. Some aspects of fluorinated solvents, supercritical fluids and ionic liquids,… (more)

Samorì, Chiara and#60;1982and#62

2010-01-01T23:59:59.000Z

175

Catalytic coal liquefaction with treated solvent and SRC recycle  

DOE Patents [OSTI]

A process for the solvent refining of coal to distillable, pentane soluble products using a dephenolated and denitrogenated recycle solvent and a recycled, pentane-insoluble, solvent-refined coal material, which process provides enhanced oil-make in the conversion of coal.

Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA); Schweighardt, Frank K. (Allentown, PA)

1986-01-01T23:59:59.000Z

176

Catalytic coal liquefaction with treated solvent and SRC recycle  

DOE Patents [OSTI]

A process is described for the solvent refining of coal to distillable, pentane soluble products using a dephenolated and denitrogenated recycle solvent and a recycled, pentane-insoluble, solvent-refined coal material, which process provides enhanced oil-make in the conversion of coal. 2 figs.

Garg, D.; Givens, E.N.; Schweighardt, F.K.

1986-12-09T23:59:59.000Z

177

Production of biodiesel using expanded gas solvents  

SciTech Connect (OSTI)

A method of producing an alkyl ester. The method comprises providing an alcohol and a triglyceride or fatty acid. An expanding gas is dissolved into the alcohol to form a gas expanded solvent. The alcohol is reacted with the triglyceride or fatty acid in a single phase to produce the alkyl ester. The expanding gas may be a nonpolar expanding gas, such as carbon dioxide, methane, ethane, propane, butane, pentane, ethylene, propylene, butylene, pentene, isomers thereof, and mixtures thereof, which is dissolved into the alcohol. The gas expanded solvent may be maintained at a temperature below, at, or above a critical temperature of the expanding gas and at a pressure below, at, or above a critical pressure of the expanding gas.

Ginosar, Daniel M [Idaho Falls, ID; Fox, Robert V [Idaho Falls, ID; Petkovic, Lucia M [Idaho Falls, ID

2009-04-07T23:59:59.000Z

178

Optimization of a Solvent Extraction Desalination Plant  

E-Print Network [OSTI]

OPTIHIZATION OF A SOLEENT EXTRACTION DESALINATION PLANT A Thesis by PHILLIP LEN BEIGHLE Submitted to the Graduate College of Texas ABEAM University in partial fulfillment of the requirements for the degree of NASTER OF SCIENCE May lg6...$ Najor Subject: Chemical Erugincering OPTIMI7&TION OF A SOLVENT EXTRACTION DESALINATION PLANT A Thesis By PHILLIP LEN BEIGHLE Approved as to style and content by: (Chairman of Committee) (Head of Department) (Member) (Member) (Member) (Member...

Beighle, Phillip Lew

2012-06-07T23:59:59.000Z

179

Emission and transport of cesium-137 from boreal biomass burning in the summer of 2010  

SciTech Connect (OSTI)

While atmospheric concentrations of cesium-137 have decreased since the nuclear testing era, resuspension of Cs-137 during biomass burning provides an ongoing emission source. The summer of 2010 was an intense biomass burning season in western Russia, with high levels of particulate matter impacting air quality and visibility. A radionuclide monitoring station in western Russia shows enhanced airborne Cs-137 concentrations during the wildfire period. Since Cs-137 binds to aerosols, satellite observations of aerosols and fire occurrences can provide a global-scale context for Cs-137 emissions and transport during biomass burning events.

Strode, S.; Ott, Lesley E.; Pawson, Steven; Bowyer, Ted W.

2012-05-09T23:59:59.000Z

180

The reactivity of cesium nickel ferrocyanide towards nitrate and nitrite salts  

SciTech Connect (OSTI)

Beginning in late 1988, the Pacific Northwest Laboratory (PNL) began an experimental program at the request of Westinghouse Hanford Company (WHC) to investigate the effects of temperature on the oxidation reaction between synthetic nickel cesium ferrocyanide (FeCN) and nitrates and nitrites representative of materials present in some of the Hanford single-shell tanks (SSTs). After completing a preliminary series of experiments in 1988, the program was expanded to include five tasks to evaluate the effect of selected compositional and operational parameters on the reaction and explosion temperatures of FeCN and nitrate and/or nitrite mixtures. 10 refs., 4 figs., 6 tabs.

Burger, L.L.; Scheele, R.D.

1991-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

H{sup -} beam extraction from a cesium seeded field effect transistor based radio frequency negative hydrogen ion source  

SciTech Connect (OSTI)

H{sup -} beam was successfully extracted from a cesium seeded ion source operated using a field effect transistor inverter power supply as a radio frequency (RF) wave source. High density hydrogen plasma more than 10{sup 19} m{sup -3} was obtained using an external type antenna with RF frequency of lower than 0.5 MHz. The source was isolated by an isolation transformer and H{sup -} ion beam was extracted from a single aperture. Acceleration current and extraction current increased with the increase of extraction voltage. Addition of a small amount of cesium vapor into the source enhanced the currents.

Ando, A.; Matsuno, T.; Funaoi, T.; Tanaka, N. [School of Engineering, Tohoku University, Sendai 980-8579 (Japan); Tsumori, K.; Takeiri, Y. [National Institute for Fusion Science, Toki 509-5292 (Japan)

2012-02-15T23:59:59.000Z

182

Membrane separation of hydrocarbons using cycloparaffinic solvents  

DOE Patents [OSTI]

Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

1988-06-14T23:59:59.000Z

183

Strontium and cesium radionuclide leak detection alternatives in a capsule storage pool  

SciTech Connect (OSTI)

A study was performed to assess radionuclide leak-detection systems for use in locating a capsule leaking strontium-90 or cesium-137 into a water-filled pool. Each storage pool contains about 35,000 L of water and up to 715 capsules, each of which contains up to 150 kCi strontium-90 or 80 kCi cesium-137. Potential systems assessed included instrumental chemical analyses, radionuclide detection, visual examination, and other nondestructive nuclear-fuel examination techniques. Factors considered in the assessment include: cost, simplicity of maintenance and operation, technology availability, reliability, remote operation, sensitivity, and ability to locate an individual leaking capsule in its storage location. The study concluded that an adaption of the spent nuclear-fuel examination technique of wet sipping be considered for adaption. In the suggested approoch, samples would be taken continuously from pool water adjacent to the capsule(s) being examined for remote radiation detection. In-place capsule isolation and subsequent water sampling would confirm that a capsule was leaking radionuclides. Additional studies are needed before implementing this option. Two other techniques that show promise are ultrasonic testing and eddy-current testing.

Larson, D.E.; Crawford, T.W.; Joyce, S.M.

1981-08-01T23:59:59.000Z

184

A Novel Approach to Solvation Time Scale in Nonpolar Solvents via Instability of Solvent Density Modes  

E-Print Network [OSTI]

. The molecular processes underlying the rate-determining factors can be probed by the solvation time1, theoretical, and simulation techniques have been extensively used to understand the solvation time in solvents to study the nonpolar solvation dynamics. Nonpolar solvation dynamics involves changes in the shape and

Biswas, Ranjit

185

Influence of Solvent on Polymer Prequaternization toward Anion-Conductive Membrane Fabrication for All-Vanadium Flow Battery  

Science Journals Connector (OSTI)

Influence of Solvent on Polymer Prequaternization toward Anion-Conductive Membrane Fabrication for All-Vanadium Flow Battery ... The all-vanadium redox flow battery (VFB) can potentially circumvent the mismatch between the generation and end use of renewable but unsteady energies such as photovoltaics and wind turbines. ... 2.3 All-Vanadium Redox Flow Battery (VFB) Performance ...

Fengxiang Zhang; Huamin Zhang; Chao Qu

2012-07-09T23:59:59.000Z

186

Documentation associated with the WESF preparation for receiving 25 cesium capsules from the Applied Radiant Energy Corporation (ARECO)  

SciTech Connect (OSTI)

The purpose of this report is to compile all documentation associated with facility preparation of WESF to receive 25 cesium capsules from ARECO. The WESF validated it`s preparedness by completing a facility preparedness review using a performance indicator checklist.

Pawlak, M.W.

1996-10-21T23:59:59.000Z

187

Small-Scale Ion Exchange Removal of Cesium and Technetium from Envelope B Hanford Tank 241-AZ-102  

SciTech Connect (OSTI)

The pretreatment process for the Hanford River Protection Project Waste Treatment Plant is to provide decontaminated Low-Activity Waste and concentrated elute streams for vitrification into low- and high-activity waste glass, respectively. The pretreatment includes sludge washing, filtration, precipitation, and ion exchange processes to remove entrained solids, strontium, transuranics, cesium, and technetium.

King, W.D.

2001-02-15T23:59:59.000Z

188

Detection of slow atoms confined in a Cesium vapor cell by spatially separated pump and probe laser beams  

E-Print Network [OSTI]

Detection of slow atoms confined in a Cesium vapor cell by spatially separated pump and probe laser distribution of atoms in a thermal gas is usually described through a Maxwell-Boltzman distribution of energy, and assumes isotropy. As a consequence, the probability for an atom to leave the surface under an azimuth

Boyer, Edmond

189

Preliminary Ion Exchange Modeling for Removal of Cesium from Hanford Waste Using SuperLig 644 Resin  

SciTech Connect (OSTI)

A proposed facility is being designed for the immobilization of Hanford high-level radioactive waste. One unit process in the facility is designed to remove radioactive cesium by ion-exchange from the strongly alkaline aqueous phase. A resin specifically designed with high selectivity of cesium under alkaline conditions is being investigated. The resin also is elutable under more acidic conditions. The proposed design of the facility consists of two sets of two packed columns placed in series (i.e., a lead column followed by a lag (guard) column configuration). During operation, upon reaching a specified cesium concentration criterion at the exit of the lag column, operation is switched to the second set of lead and lag columns. The cesium-loaded lead column is processed (i.e., washed and eluted) and switched to the lag position. the previous lag column is then placed in the lead position (without eluting) and the system is ready for use in the next cycle. For a well designed process, the loading and elution processes result in significant volume reductions in aqueous high-level waste.

Hamm, L.L.

2000-08-23T23:59:59.000Z

190

Acid gas scrubbing by composite solvent-swollen membranes  

DOE Patents [OSTI]

A composite immobilized liquid membrane suitable for acid gas scrubbing is disclosed. The membrane is a solvent-swollen polymer and a microporous polymeric support, the solvent being selected from a class of highly polar solvents containing at least one atom selected from nitrogen, oxygen, phosphorus and sulfur, and having a boiling point of at least 100 C and a solubility parameter of from about 7.5 to about 13.5 (cal/cm[sup 3]-atm)[sup 1/2]. Such solvents are homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. Also disclosed are methods of acid gas scrubbing of high- and low-Btu gas effluents with such solvent-swollen membranes. 3 figs.

Matson, S.L.; Lee, E.K.L.; Friesen, D.T.; Kelly, D.J.

1988-04-12T23:59:59.000Z

191

Acid gas scrubbing by composite solvent-swollen membranes  

DOE Patents [OSTI]

A composite immobilized liquid membrane suitable for acid gas scrubbing is disclosed. The membrane is a solvent-swollen polymer and a microporous polymeric support, the solvent being selected from a class of highly polar solvents containing at least one atom selected from nitrogen, oxygen, phosphorous and sulfur, and having a boiling point of at least 100.degree. C. and a solubility parameter of from about 7.5 to about 13.5 (cal/cm.sup.3 -atm).sup.1/2. Such solvents are homogeneously distributed through the solvent-swollen polymer from 20% to 95% by weight. Also disclosed are methods of acid gas scrubbing of high- and low-Btu gas effluents with such solvent-swollen membranes.

Matson, Stephen L. (Harvard, MA); Lee, Eric K. L. (Acton, MA); Friesen, Dwayne T. (Bend, OR); Kelly, Donald J. (Bend, OR)

1988-01-01T23:59:59.000Z

192

Evaluation of interim and final waste forms for the newly generated liquid low-level waste flowsheet  

SciTech Connect (OSTI)

The purpose of this review is to evaluate the final forms that have been proposed for radioactive-containing solid wastes and to determine their application to the solid wastes that will result from the treatment of newly generated liquid low-level waste (NGLLLW) and Melton Valley Storage Tank (MVST) supernate at the Oak Ridge National Laboratory (ORNL). Since cesium and strontium are the predominant radionuclides in NGLLLW and MVST supernate, this review is focused on the stabilization and solidification of solid wastes containing these radionuclides in cement, glass, and polymeric materials-the principal waste forms that have been tested with these types of wastes. Several studies have shown that both cesium and strontium are leached by distilled water from solidified cement, although the leachabilities of cesium are generally higher than those of strontium under similar conditions. The situation is exacerbated by the presence of sulfates in the solution, as manifested by cracking of the grout. Additives such as bentonite, blast-furnace slag, fly ash, montmorillonite, pottery clay, silica, and zeolites generally decrease the cesium and strontium release rates. Longer cement curing times (>28 d) and high ionic strengths of the leachates, such as those that occur in seawater, also decrease the leach rates of these radionuclides. Lower cesium leach rates are observed from vitrified wastes than from grout waste forms. However, significant quantities of cesium are volatilized due to the elevated temperatures required to vitrify the waste. Hence, vitrification will generally require the use of cleanup systems for the off-gases to prevent their release into the atmosphere.

Abotsi, G.M.K. [Clark Atlanta Univ., GA (United States); Bostick, D.T.; Beck, D.E. [Oak Ridge National Lab., TN (United States)] [and others

1996-05-01T23:59:59.000Z

193

NETL: Ion Advanced Solvent CO2 Capture Pilot Project  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ion Advanced Solvent CO2 Capture Pilot Project Ion Advanced Solvent CO2 Capture Pilot Project Project No.: DE-FE0013303 ION Engineering is conducting small pilot-scale (~ 0.7 MW) testing of an advanced CO2 capture solvent technology that has previously undergone bench-scale testing. The small pilot-scale testing will involve continuous long-term operation in order to gather the necessary data ultimately required for further scale-up. Activities will include the design and fabrication of the 0.5-0.7 MWe (equivalent) slipstream pilot plant; scale-up of solvent manufacturing; testing, data collection, and analysis of solvent performance; degradation and air emission analysis; modeling and simulation for the detailed preliminary and final techno-economic analyses; and decommissioning of pilot plant equipment upon completion of solvent testing. The advanced solvent is anticipated to have significant operating and capital cost advantages over other solvents currently in development. Advantages include significant reductions in parasitic load and liquid flow rates which directly translate to smaller more efficient CO2 capture processes. Make-up water and amine emissions rates will be examined during this project. There is the potential that additional solvent, system, and integration savings will be identified, which could result in further operating and capital cost reductions.

194

solvent-babcock-wilcox | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and optimizing the formulation of a novel solvent as a critical enabler for economic, energy efficient and environmentally-friendly capture of CO2 at coal-fired...

195

Study on the Volatility of Cesium in Dry Ashing Pretreatment and Dissolution of Ash by Microwave Digestion System - 13331  

SciTech Connect (OSTI)

Based on the regulation of the activity concentration of Cs-137, Co-58, Co-60, Fe-55, Ni-59, Ni-63, Sr-90, Nb-94, and Tc-99, and the total alpha from the radioactive waste acceptance criteria, the measurement of the activity concentration of these nuclides in low and intermediate levels of radioactive waste such as in paper, cotton, vinyl and plastic samples was investigated. A dry ashing method was applied to obtain a concentration effect of the samples. Owing to the temperature dependence of the volatility for cesium, the temperature of 300 to 650 deg. C was examined. It was found that 450 deg. C is the optimum dry ashing temperature. After dry ashing, the produced ash was dissolved with HNO{sub 3}, HCl, and HF by a high-performance microwave digestion system. The ash sample, for the most part, was completely dissolved with 10 mL of HNO{sub 3}, 4 mL of HCl, and 0.25 mL of HF by a high-performance microwave digestion system using a nova high temperature rotor at 250 deg. C for 90 min until reaching 0.2 g. To confirm the reliability of cesium loss after the performance of the dry ashing procedure, a cesium standard solution for AAS and a Cs-137 standard solution for gamma spectrometry were added to a paper towel or a planchet of stainless steel, respectively. Cesium was measured by AAS, ICP-MS, and gamma spectrometry. The volatility of cesium did not occur until 450 deg. C ashing. (authors)

Choi, Kwang-Soon; Lee, Chang Heon; Ahn, Hong-Joo; Park, Yong Joon; Song, Kyuseok [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)] [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daedeok-daero 989-111, Yuseong-gu, Daejeon, 305-353 (Korea, Republic of)

2013-07-01T23:59:59.000Z

196

Cellulose solvent- and organic solvent-based lignocellulose fractionation enabled efficient sugar release from a variety of lignocellulosic feedstocks  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cellulose solvent- and organic solvent-based lignocellulose fractionation ena- Cellulose solvent- and organic solvent-based lignocellulose fractionation ena- bled efficient sugar release from a variety of lignocellulosic feedstocks Noppadon Sathitsuksanoh, Zhiguang Zhu, Y.-H. Percival Zhang PII: S0960-8524(12)00712-2 DOI: http://dx.doi.org/10.1016/j.biortech.2012.04.088 Reference: BITE 9966 To appear in: Bioresource Technology Received Date: 29 February 2012 Revised Date: 21 April 2012 Accepted Date: 21 April 2012 Please cite this article as: Sathitsuksanoh, N., Zhu, Z., Percival Zhang, Y.-H., Cellulose solvent- and organic solvent- based lignocellulose fractionation enabled efficient sugar release from a variety of lignocellulosic feedstocks, Bioresource Technology (2012), doi: http://dx.doi.org/10.1016/j.biortech.2012.04.088 This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers

197

Water – A magic solvent for biomass conversion  

Science Journals Connector (OSTI)

Abstract Hydrothermal biomass conversion processes provide the opportunity to use feedstocks with high water content for the formation of energy carriers or platform chemicals. The water plays an active role in the processes as solvent, reactant and catalyst or catalyst precursor. In this paper, the different hydrothermal processes of carbonization, gasification and liquefaction are introduced and the specific role of water is discussed for each of them. The high reactivity of the polar components of biomass in hot compressed water and its changing properties with temperature are the key to obtain high selectivities of the desired products. Despite the obvious advantages of hydrothermal conversion examples for industrial applications are rare. The main reason for not commercial application of water in the high temperature state is that there are no products that can be sold with profit and cannot be produced cheaper, with less capital risk, and with more simple processes.

Andrea Kruse; Nicolaus Dahmen

2014-01-01T23:59:59.000Z

198

CACI: Cesium-137 Agricultural Commodities Irradiator: Final design report. Volume 1, Project summary  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE`s Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the 137 Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of Irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site.

Subbaraman, G.; Conners, C.C.

1986-12-19T23:59:59.000Z

199

Solvent polarity and nanoscale morphology in bulk heterojunction organic solar cells: A case study  

SciTech Connect (OSTI)

Organic bulk heterojunction solar cells were fabricated under identical experimental conditions, except by varying the solvent polarity used for spin coating the active layer components and their performance was evaluated systematically. Results showed that presence of nitrobenzene-chlorobenzene composition governs the morphology of active layer formed, which is due to the tuning of solvent polarity as well as the resulting solubility of the P3HT:PCBM blend. Trace amount of nitrobenzene favoured the formation of better organised P3HT domains, as evident from conductive AFM, tapping mode AFM and surface, and cross-sectional SEM analysis. The higher interfacial surface area thus generated produced cells with high efficiency. But, an increase in the nitrobenzene composition leads to a decrease in cell performance, which is due to the formation of an active layer with larger size polymer domain networks with poor charge separation possibility.

Thomas, Ajith [Centre for Nano-Bio-Polymer Science and Technology, Department of Physics, St. Thomas College, Pala, Kerala 686574 (India); Research and Development Centre, Bharathiar University, Coimbatore, Tamilnadu 641046 (India); Elsa Tom, Anju; Ison, V. V., E-mail: isonvv@yahoo.in, E-mail: praveen@materials.iisc.ernet.in [Centre for Nano-Bio-Polymer Science and Technology, Department of Physics, St. Thomas College, Pala, Kerala 686574 (India); Rao, Arun D.; Varman, K. Arul; Ranjith, K.; Ramamurthy, Praveen C., E-mail: isonvv@yahoo.in, E-mail: praveen@materials.iisc.ernet.in [Department of Materials Engineering, Indian Institute of Science Bangalore, Karnataka 560012 (India); Vinayakan, R. [Department of Chemistry, SVR NSS College Vazhoor, Kerala 686505 (India)

2014-03-14T23:59:59.000Z

200

Next generation solar bimodal systems  

SciTech Connect (OSTI)

One of the principal advantages of a solar thermal propulsion system as compared to a conventional chemical propulsion one is high specific impulse which is proportional to the square root of a propellant temperature. Obviously, next generation solar propulsion and bimodal systems must take advantage of high and ultra-high temperatures. This requires use of an appropriate energy conversion system capable to take advantage of high temperature potentially achievable in a solar receiver. High efficiency and power density of a high temperature thermionic converter open new perspectives in the development of advanced bimodal power systems having performance significantly higher than that achievable by the state-of-the-art technology. The paper presents an innovative concept of a cascaded solar bimodal power system with a high temperature Cs-Ba thermionic converter. The paper shows that the use of high temperature Knudsen cesium-barium thermionic converter in a solar bimodal system allows to eliminate thermal insulation sleeve, generate electrical power in the propulsion mode, and precise control thermal state of the solar receiver. In the Cs-Ba thermionic converter an electron instability and high amplitude current oscillations develop. These effects can be used to obtain alternate current power directly in the converter. Possibility and potential advantage of such a generator are discussed.

Babanin, V.I.; Ender, A.Y.; Kolyshkin, I.N.; Kuznetsov, V.I.; Sitnov, V.I. [Ioffe Physico-Technical Institute, St. Petersburg (Russian Federation); Paramonov, D.V. [Westinghouse Science and Technology Center, Pittsburgh, PA (United States)

1997-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Can green solvents be alternatives for thermal stabilization of collagen?  

Science Journals Connector (OSTI)

Abstract “Go Green” campaign is gaining light for various industrial applications where water consumption needs to be reduced. To resolve this, industries have adopted usage of green, organic solvents, as an alternative to water. For leather making, tanning industry consumes gallons of water. Therefore, for adopting green solvents in leather making, it is necessary to evaluate its influence on type I collagen, the major protein present in the skin matrix. The thermal stability of collagen from rat tail tendon fiber (RTT) treated with seven green solvents namely, ethanol, ethyl lactate, ethyl acetate, propylene carbonate, propylene glycol, polyethylene glycol-200 and heptane was determined using differential scanning calorimetry (DSC). Crosslinking efficiency of basic chromium sulfate and wattle on RTT in green solvents was determined. DSC thermograms show increase in thermal stability of RTT collagen against heat with green solvents (>78 °C) compared to water (63 °C). In the presence of crosslinkers, RTT demonstrated thermal stability >100 °C in some green solvents, resulting in increased intermolecular forces between collagen, solvent and crosslinkers. The significant improvement in thermal stability of collagen potentiates the capability of green solvents as an alternative for water.

Ami Mehta; J. Raghava Rao; Nishter Nishad Fathima

2014-01-01T23:59:59.000Z

202

Droplet Formation via Solvent Shifting in a Microfluidic Device  

E-Print Network [OSTI]

Solvent shifting is a process in which a non-solvent is added to a solvent/solute mixture and extracts the solvent. The solvent and the non-solvent are miscible. Because of solution supersaturation a portion of the solute transforms to droplets. In this paper, based on this process, we present an investigation on droplet formation and their radial motion in a microfluidic device in which a jet is injected in a co-flowing liquid stream. Thanks to the laminar flow, the microfluidic setup enables studying diffusion mass transfer in radial direction and obtaining well-defined concentration distributions. Such profiles together with Ternary Phase Diagram (TPD) give detailed information about the conditions for droplet formation condition as well as their radial migration in the channel. The ternary system is composed of ethanol (solvent), de-ionized water (non-solvent) and divinyle benzene (solute). We employ analytical/numerical solutions of the diffusion equation to obtain concentration profiles of the component...

Hajian, Ramin

2014-01-01T23:59:59.000Z

203

SEQUESTRATION AND TREATMENT OF VADOSE ZONE SOLVENTS USING EDIBLE OILS  

SciTech Connect (OSTI)

Edible oils have emerged as an effective treatment amendment for a variety of contaminants. When applied to chlorinated volatile organic compounds (cVOCs) in the saturated zone, edible oils have been shown to enhance anaerobic bioremediation and sequester the contaminants. However, edible oils have not been applied to the vadose zone for contaminant treatment. Soybean oil was injected into the vadose zone in M-Area at the Department of Energy's (DOE) Savannah River Site (SRS) as a research study to evaluate the effectiveness of edible oils for solvent sequestration and the ability to change a vadose system from aerobic to anaerobic to initiate reductive dechlorination. The proposed use of this technique would be an enhanced attenuation/transition step after active remediation. The goals of the research were to evaluate oil emplacement methods and monitoring techniques to measure oil placement, partitioning and degradation. Gas sampling was the cornerstone for this evaluation. Analyses for cVOCs and biotransformation products were performed. Overall, the cVOC concentration/flux reduction was 75-85% in this vadose zone setting. Destruction of the cVOCs by biotic or abiotic process has not yet been verified at this site. No reductive dechlorination products have been measured. The deployment has resulted in a substantial generation of light hydrocarbon gases and geochemical conditions that would support cometabolism.

Riha, B; Brian02 Looney, B; Richard Hall (NOEMAIL), R

2008-03-28T23:59:59.000Z

204

Co-Solvent Enhanced Production of Platform Fuel Precursors From Lignocellulosic Biomass  

E-Print Network [OSTI]

THF is a promising green solvent that is relatively non-is a biomass-sourced green solvent with catalytic qualitieswith THF as a novel green co-solvent in a highly effective

Cai, Charles Miao-Zi

2014-01-01T23:59:59.000Z

205

Green Solvents for Polymerization of Methyl Methacrylate to Poly(Methyl Methacrylate)  

Science Journals Connector (OSTI)

Solvents are often volatile organic compounds (VOCs) ... decade, chemistry research into the use of greener, alternative solvents has been grown enormously. Alternative solvents suitable for green chemistry are t...

S. Krishna Mohan

2012-01-01T23:59:59.000Z

206

Purification of lipoteichoic acid by chromatography in water-organic solvent systems.  

Science Journals Connector (OSTI)

...Research Article Purification of lipoteichoic...chromatography in water-organic solvent...of acyl groups. Purification of lipoteichoic...chromatography in water-organic solvent...for Microbiology Purification of Lipoteichoic...Chromatography in Water-Organic Solvent...

S L Josephson; M W Stinson; S J Millar; R E Cohen

1986-02-01T23:59:59.000Z

207

THE EFFECTS OF SOLVENTS ON SUB-BITUMINOUS COAL BELOW ITS PYROLYSIS TEMPERATURE  

E-Print Network [OSTI]

W. S. , "Solvent Treatment of Coal", Mills and Boon, London,of this solvent with the coal structure. When coupled withis indeed quite an unusual coal solvent. REFEREMCES Oele, A.

Grens III., Edward A.

2013-01-01T23:59:59.000Z

208

Kinetics of band bending and electron affinity at GaAs(001) surface with nonequilibrium cesium overlayers  

SciTech Connect (OSTI)

The dosage dependences of surface band bending and effective electron affinity under cesium deposition on the Ga-rich GaAs(001) surface, along with the relaxation of these electronic properties after switching off the Cs source are experimentally studied by means of modified photoreflectance spectroscopy and photoemission quantum yield spectroscopy. At small Cs coverages, below half of a monolayer, additional features in the dosage dependence and subsequent downward relaxation of the photoemission current are determined by the variations of band bending. At coverages above half of a monolayer the upward relaxation of the photocurrent is caused supposedly by the decrease of the electron affinity due to restructuring in the nonequilibrium cesium overlayer.

Zhuravlev, A. G.; Savchenko, M. L.; Paulish, A. G.; Alperovich, V. L. [Rzhanov Institute of Semiconductor Physics, Lavrentieva, 13, 630090 Novosibirsk, Russia and Novosibirsk State University, Pirogova, 2, 630090 Novosibirsk (Russian Federation); Scheibler, H. E.; Jaroshevich, A. S. [Rzhanov Institute of Semiconductor Physics, Lavrentieva, 13, 630090 Novosibirsk (Russian Federation)

2013-12-04T23:59:59.000Z

209

Diophantine Generation,  

E-Print Network [OSTI]

Diophantine Generation, Horizontal and Vertical Problems, and the Weak Vertical Method Alexandra Shlapentokh Diophantine Sets, Definitions and Generation Diophantine Sets Diophantine Generation Properties of Diophantine Generation Diophantine Family of Z Diophantine Family of a Polynomial Ring Going Down Horizontal

Shlapentokh, Alexandra

210

Acetone as a solvent for extraction of cottonseed oil  

E-Print Network [OSTI]

ACETONE AS A SOLVENT FOR EXTRACTION GP COTTONSEED OIL A Thesis In-Wai Hui June 1950 Approval as to style and content recommended c t Head oi' the Department of Chemical Engineering ACETONE AS A SOLVENT FOR EXT "ACTION OF COTTONSEED OIL A... Thesis In-Nai Hui June 1950 ACETONE AS A SOLVENT FOR EXTRACTION QF COTTONSEED OIL A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas Partis1 Fulfillment of the Recuirements for the Degree of Master of Science...

Hui, In-Wai

2012-06-07T23:59:59.000Z

211

DEVELOPMENT OF PROTOTYPE TITANATE ION EXCHANGE LOADED MEMBRANES FOR STRONTIUM, CESIUM AND ACTINIDE DECONTAMINATION FROM AQUEOUS MEDIA  

SciTech Connect (OSTI)

We have successfully incorporated high surface area particles of titanate ion exchange materials (monosodium titanate and crystalline silicotitanate) with acceptable particle size distribution into porous and inert support membrane fibrils consisting of polytetrafluoroethylene (Teflon{reg_sign}), polyethylene and cellulose materials. The resulting membrane sheets, under laboratory conditions, were used to evaluate the removal of surrogate radioactive materials for cesium-137 and strontium-90 from high caustic nuclear waste simulants. These membrane supports met the nominal requirement for nonchemical interaction with the embedded ion exchange materials and were porous enough to allow sufficient liquid flow. Some of this 47-mm size stamped out prototype titanium impregnated ion exchange membrane discs was found to remove more than 96% of dissolved cesium-133 and strontium-88 from a caustic nuclear waste salt simulants. Since in traditional ion exchange based column technology monosodium titanate (MST) is known to have great affinity for the sorbing of other actinides like plutonium, neptunium and even uranium, we expect that the MST-based membranes developed here, although not directly evaluated for uptake of these three actinides because of costs associated with working with actinides which do not have 'true' experimental surrogates, would also show significant affinity for these actinides in aqueous media. It was also observed that crystalline silicotitanate impregnated polytetrafluoroethylene or polyethylene membranes became less selective and sorbed both cesium and strontium from the caustic aqueous salt simulants.

Oji, L; Keisha Martin, K; David Hobbs, D

2008-05-30T23:59:59.000Z

212

Simulation of Sediment and Cesium Transport in the Ukedo River and the Ogi Dam Reservoir during a Rainfall Event using the TODAM Code  

SciTech Connect (OSTI)

The accident at the Fukushima Daiichi Nuclear Power Plant in March 2011 caused widespread environmental contamination. Although decontamination activities have been performed in residential areas of the Fukushima area, decontamination of forests, rivers, and reservoirs is still controversial because of the economical, ecological, and technical difficulties. Thus, an evaluation of contaminant transport in such an environment is important for safety assessment and for implementation of possible countermeasures to reduce radiation exposure to the public. The investigation revealed that heavy rainfall events play a significant role in transporting radioactive cesium deposited on the land surface, via soil erosion and sediment transport in rivers. Therefore, we simulated the sediment and cesium transport in the Ukedo River and its tributaries in Fukushima Prefecture, including the Ogaki Dam Reservoir, and the Ogi Dam Reservoir of the Oginosawa River in Fukushima Prefecture during and after a heavy rainfall event by using the TODAM (Time-dependent, One-dimensional Degradation And Migration) code. The main outcomes are the following: • Suspended sand is mostly deposited on the river bottom. Suspended silt and clay, on the other hand, are hardly deposited in the Ukedo River and its tributaries except in the Ogaki Dam Reservoir in the Ukedo River even in low river discharge conditions. • Cesium migrates mainly during high river discharge periods during heavy rainfall events. Silt and clay play more important roles in cesium transport to the sea than sand does. • The simulation results explain variations in the field data on cesium distributions in the river. Additional field data currently being collected and further modeling with these data may shed more light on the cesium distribution variations. • Effects of 40-hour heavy rainfall events on clay and cesium transport continue for more than a month. This is because these reservoirs slow down the storm-induced high flow moving through these reservoirs. • The reservoirs play a major role as a sink of sediment and cesium in the river systems. Some amounts of sediment pass through them along with cesium in dissolved and clay-sorbed cesium forms. • Effects of countermeasures such as overland decontamination, dam control and sorbent injection were tentatively estimated. The simulation suggested that overland decontamination and sorbent injection would be effective for decreasing the contamination of water in the reservoir and in the river below the dam.

Onishi, Yasuo; Yokuda, Satoru T.; Kurikami, Hiroshi

2014-03-28T23:59:59.000Z

213

Folding of a DNA Hairpin Loop Structure in Explicit SolventUsingRepli...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Folding of a DNA Hairpin Loop Structure in Explicit Solvent UsingReplica-Exchange Molecular Dynamics Simulations. Folding of a DNA Hairpin Loop Structure in Explicit Solvent...

214

E-Print Network 3.0 - advanced integrated solvent Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

divided into three regimes which delineate three different transport processes. Solvent penetration... in a diffusion boundary layer adjacent to the rubbery-solvent interface,...

215

E-Print Network 3.0 - alkaline-side solvent extraction Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

extractability and solvent swelling.15 Nishioka and Larsen16 found that by heating coal... in a slightly polar solvent (chlorobenzene) to 115 ... Source: Thomas, Mark - School...

216

Novel Carbon Capture Solvent Begins Pilot-Scale Testing for Emissions...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Novel Carbon Capture Solvent Begins Pilot-Scale Testing for Emissions Control Novel Carbon Capture Solvent Begins Pilot-Scale Testing for Emissions Control January 13, 2015 -...

217

Tuning the Morphology and Performance of Low Bandgap Polymer: Fullerene Heterojunctions via Solvent Annealing in Selective Solvents  

SciTech Connect (OSTI)

Low bandgap polymer (LBG):fullerene mixtures are some of the most promising organic photovoltaic active layers. Unfortunately, there are no post-deposition treatments available to rationally improve the morphology and performance of as-cast LBG:fullerene OPV active layers, where thermal annealing usually fails. Therefore, there is a glaring need to develop postdeposition methods to guide the morphology of LBG:fullerene bulk heterojunctions towards targeted structures and performance. In this paper, the structural evolution of PCPDTBT:PCBM mixtures with solvent annealing (SA) is examined, focusing on the effect of solvent quality of the fullerene and polymer in the annealing vapor on morphological evolution and device performance. The results indicate that exposure of this active layer to the solvent vapor controls the ordering of PCPDTBT and PCBM phase separation very effectively, presumably by inducing component mobility as the solvent plasticizes the mixture. These results also unexpectedly indicate that solvent annealing in a selective solvent provides a method to invert the morphology of the LBG:fullerene mixture from a polymer aggregate dispersed in a polymer:fullerene matrix to fullerene aggregates dispersed in a polymer:fullerene matrix. The judicious choice of solvent vapor, therefore, provides a unique method to exquisitely control and optimize the morphology of LBG conjugated polymer/fullerene mixtures.

Chen, Huipeng [ORNL; Hsiao, Yu-Che [ORNL; Hu, Bin [ORNL; Dadmun, Mark D [ORNL

2014-01-01T23:59:59.000Z

218

Solvent Penetration Rate in Tablet Measurement Using Video Image Processing  

Science Journals Connector (OSTI)

We describe a simple technique for the measurement of solvent penetration rates into spray-dried lactose (DCL) tablets ... results of the experimental study show that the penetration rate in some cases appears to...

D. Braido; Y. Gulak; A. Cuitino

2012-06-01T23:59:59.000Z

219

Solvent for urethane adhesives and coatings and method of use  

DOE Patents [OSTI]

A solvent for urethane adhesives and coatings, the solvent having a carbaldehyde and a cyclic amide as constituents. In some embodiments the solvent consists only of miscible constituents. In some embodiments the carbaldehyde is benzaldehyde and in some embodiments the cyclic amide is N-methylpyrrolidone (M-pyrole). An extender may be added to the solvent. In some embodiments the extender is miscible with the other ingredients, and in some embodiments the extender is non-aqueous. For example, the extender may include isopropanol, ethanol, tetrahydro furfuryl alcohol, benzyl alcohol, Gamma-butyrolactone or a caprolactone. In some embodiments a carbaldehyde and a cyclic amide are heated and used to separate a urethane bonded to a component.

Simandl, Ronald F. (Knoxville, TN); Brown, John D. (Harriman, TN); Holt, Jerrid S. (Knoxville, TN)

2010-08-03T23:59:59.000Z

220

Subcritical Water as a Green Solvent for Plant Extraction  

Science Journals Connector (OSTI)

Subcritical water extraction (SWE), as a method, is non-toxic, non-flammable, cheap, readily available, safe, environmental friendly and uses a green solvent. Chemicals with different functional groups such as .....

Mustafa Zafer Özel; Fahrettin Gö?ü?

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Does Occupational Exposure to Organic Solvents Affect Colour Discrimination?  

Science Journals Connector (OSTI)

Among the commonly used organic solvents, styrene has been investigated the most thoroughly ... yellow) type, although some cases of red-green impairment have also been found. The limited...

Richard B. Lomax; Peter Ridgway; Maureen Meldrum

2004-06-01T23:59:59.000Z

222

Development of integrated separation processes with green solvents.  

E-Print Network [OSTI]

??Dissertação para obtenção do Grau de Doutor em Química Sustentável This thesis explores the fractionation of mixtures with unconventional solvents, like supercritical carbon dioxide (scCO2)… (more)

Couto, Ricardo Miguel Tomás do

2012-01-01T23:59:59.000Z

223

TRL Acid and Solvent Wet Processing Rules and Guidelines  

E-Print Network [OSTI]

: General rules and guidelines for wet chemical processing in TRL. Author: KFlo hood and when transporting or handling chemicals. An acid-proof apron, sleeveTRL Acid and Solvent Wet Processing Rules and Guidelines Purpose

Reif, Rafael

224

Wool grease from the commercial solvent degreasing of raw wool  

Science Journals Connector (OSTI)

Some differences between wool grease obtained by the solvent extraction of raw wool and wool grease recovered centrifugally from emulsion scour liquors are described. Refining problems arising from the peculiar p...

G. F. Wood

1961-04-01T23:59:59.000Z

225

novel-solvent-system | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Solvent System for Post Combustion CO2 Capture Project No.: DE-FE0005799 ION Engineering Ionic Liquid ION Engineering Ionic Liquid ION Engineering, LLC will conduct bench-scale...

226

CATALYTIC CONVERSION OF SOLVENT REFINED COAL TO LIQUID PRODUCTS  

E-Print Network [OSTI]

I. Solvent Refined Coal II. Catalysts III. Purpose andSondreal, E.A. , "Viscosity of Coal Liquids - The Effect ofAnthraxylon - Kinetics of Coal Hydrogenation," Ind. and Eng.

Tanner, K.I.

2010-01-01T23:59:59.000Z

227

PRELIMINARY REPORT ON EVALUATION OF POTENTIAL ELUANTS FOR NON-ACID ELUTION OF CESIUM FROM RESORCINOL-FORMALDEHYDE RESIN  

SciTech Connect (OSTI)

Small-column ion exchange (SCIX) units installed in high-level waste tanks to remove Cs-137 from highly alkaline salt solutions are among the waste treatment plans in the DOE-complex. Spherical Resorcinol-Formaldehyde (sRF) is the ion exchange resin selected for use in the Hanford Waste Treatment and Immobilization Plant (WTP). It is also the primary ion exchange material under consideration for SCIX at the Hanford site. The elution step of the multi-step ion exchange process is typically done with 0.5 M nitric acid. An acid eluant is a potential hazard in the event of a spill, leak, etc. because the high-level waste tanks are made of carbon steel. Corrosion and associated structural damage may ensue. Studies are ongoing to explore non-acid elution as an alternative. Batch contact sorption equilibrium screening tests have been conducted with 36 potential non-acid eluants. The sorption tests involve equilibrating each cesium-containing eluant solution with the sRF resin for 48 hours at 25 C in a shaker oven. In the sorption tests, an eluant is deemed to have a high cesium elution potential if it minimizes cesium sorption onto the sRF resin. The top candidates (based on lowest cesium sorption distribution coefficients) include ammonium carbonate, ammonium carbonate/ammonium hydroxide, ammonium bicarbonate, rubidium carbonate, ammonium acetate, ammonium acetate/ammonium hydroxide, ammonium bicarbonate/ammonium hydroxide, calcium chloride, and magnesium chloride. The next phase of testing for this work will focus on the following down selected eluants: Ammonium carbonate, ammonium acetate, calcium acetate, magnesium acetate, nitric acid, and ammonium hydroxide. The next testing phase is a confirmation of the elution ability of the selected eluants. It will mimic a typical sRF cesium ion exchange process i.e., sorption or loading, caustic wash, water rinse, and elution via batch contact sorption and quasi column caustic wash/water rinse/elution. Due to corrosion concerns, calcium acetate and magnesium acetate will be tested instead of calcium chloride and magnesium chloride respectively. Nitric acid is for benchmarking since it is the baseline sRF eluant. The information at hand indicates ammonium hydroxide, while a weak base, may hold promise as an effective eluant. Hence, its inclusion among the eluants to be studied despite the fact that it was not tested as a stand-alone eluant earlier.

Adu-Wusu, K.; Pennebaker, F.

2010-09-01T23:59:59.000Z

228

Hydrogen recovery by novel solvent systems. Final report  

SciTech Connect (OSTI)

The objective of this work is to develop a novel method for purification of hydrogen from coal-derived synthesis gas. The study involved a search for suitable mixtures of solvents for their ability to separate hydrogen from the coal derived gas stream in significant concentration near their critical point of miscibility. The properties of solvent pairs identified were investigated in more detail to provide data necessary for economic evaluation and process development.

Shinnar, R.; Ludmer, Z.; Ullmann, A.

1991-08-01T23:59:59.000Z

229

Coal liquefaction process using pretreatment with a binary solvent mixture  

DOE Patents [OSTI]

An improved process for thermal solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprises pretreating the coal with a binary mixture of an aromatic hydrocarbon and an aliphatic alcohol at a temperature below 300 C before the hydroliquefaction step. This treatment generally increases both conversion of coal and yields of oil. 1 fig.

Miller, R.N.

1986-10-14T23:59:59.000Z

230

Chemical phenomena in solid-state voltammetry in polymer solvents  

SciTech Connect (OSTI)

This paper, aimed at delineating significant chemical effects in solid-state voltammetry, describes electrochemical oxidations and reductions of electroactive monomer solutes dissolved in and diffusing through rigid and semirigid polymer electrolyte solvents. Sorption of organic monomer vapors into poly(ethylene oxide) films yields polymer solvents whose chemistry is dominated by that of the sorbed monomer as shown by coordination and precipitation effects. The dynamics of plasticization-induced changes in transport rates are quite rapid. Physical diffusion in the polymer solvent in slow enough that electron hopping reactions measurably enhance charge transport rates; the effect was used to estimate a lower limit for the (Co(bpy)/sub 3/)/sup 2+/+/ self-exchange rate constant of 2 /times/ 10/sup 9/ M/sup /minus/1/ s/sup /minus/1/. It is possible to erect polymeric film transport barriers at the electrode/polymer solvent interface and to measure the rate of permeation of monomer complexes from the polymer solvent into the polymer transport barrier film. Polymeric films of Os and Ru polypyridine complexes can be electropolymerized from polymer solutions of the corresponding monomers. Solid-state voltammetry can be extended to other polymer solvents including sulfonated polystyrene, poly(vinyl chloride), Nafion, and poly(acrylamide) gel.

Geng, L.; Reed, R.A.; Kim, M.H.; Wooster, T.T.; Oliver, B.N.; Egekeze, J.; Kennedy, R.T.; Jorgenson, J.W.; Parcher, J.F.; Murray, R.W.

1989-03-01T23:59:59.000Z

231

CACI: The Cesium-137 Agricultural Commodities Irradiator. Final design report: Volume 4, Specifications  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE`s Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the {sup 137}Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site. This Volume, IV, provides specifications as developed for the CACI final design.

Not Available

1986-12-01T23:59:59.000Z

232

CACI: The Cesium-137 Agricultural Commodities Irradiator. Final design report: Volume 6, Shielding, mechanical, and electrical  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE`s Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the {sup 137}Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site. This Volume, VI, provides the CACI final design features regarding shielding, mechanical and electrical.

Not Available

1986-12-19T23:59:59.000Z

233

The Cesium-137 Agricultural Commodities Irradiator (CACI) final design report. Volume 2, Drawings [Engineering Materials  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE`s Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the 137 Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site. Over 100 engineering drawings are included.

Not Available

1986-12-19T23:59:59.000Z

234

CACI: The Cesium-137 Agricultural Commodities Irradiator. Final design report: Volume 5, Plans, criteria, and requirements  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE`s Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the {sup 137}Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site. The CACI final design is described in eight volumes. This Volume V, describes plans, criteria, and requirements.

Not Available

1986-12-19T23:59:59.000Z

235

CACI: The Cesium-137 Agricultural Commodities Irradiator. Final design report: Volume 8, Shielding window  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE`s Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the 137 Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site. The CACI final design is described in eight volumes. This volume Volume III, describes the Shielding Window.

Not Available

1986-12-19T23:59:59.000Z

236

The Cesium-137 Agricultural Commodities Irradiator (CACI) final design report. Volume 3, Supplied data [Engineering Materials  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE`s Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the 137 Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site. Site characterization data and equipment engineering drawings are included.

Not Available

1986-12-19T23:59:59.000Z

237

WHEN IT COMES TO SOLVENTS, IONIC LIQUIDS are in a class by themselves. Compared to other  

E-Print Network [OSTI]

are a groundbreaking green alternative to highly toxic solvents capable of causing signifi- cant environmental harm WITTKOP IONIC LIQUIDS: THE GREEN SUPER-SOLVENTS AUTHOR: DEAN L. MASKEVICH is editor of NJIT Magazine. #12WHEN IT COMES TO SOLVENTS, IONIC LIQUIDS are in a class by themselves. Compared to other solvents

Bieber, Michael

238

1. Generation 1 1. Generation  

E-Print Network [OSTI]

1. Generation 1 _________________________________________________________________________ 1. Generation Sound and vibrations or, in more general terms, oscillations of matter (solids or fluids) are generated in many different dynamic processes. The basic mechanisms which underlie these oscillations

Berlin,Technische Universität

239

Methods for recovering a solvent from a fluid volume and methods of removing at least one compound from a nonpolar solvent  

SciTech Connect (OSTI)

A method of removing a nonpolar solvent from a fluid volume that includes at least one nonpolar compound, such as a fat, an oil or a triglyceride, is provided. The method comprises contacting a fluid volume with an expanding gas to expand the nonpolar solvent and form a gas-expanded solvent. The gas-expanded solvent may have a substantially reduced density in comparison to the at least one nonpolar compound and/or a substantially reduced capacity to solubilize the nonpolar compound, causing the nonpolar compounds to separate from the gas-expanded nonpolar solvent into a separate liquid phase. The liquid phase including the at least one nonpolar compound may be separated from the gas-expanded solvent using conventional techniques. After separation of the liquid phase, at least one of the temperature and pressure may be reduced to separate the nonpolar solvent from the expanding gas such that the nonpolar solvent may be recovered and reused.

Ginosar, Daniel M.; Wendt, Daniel S.; Petkovic, Lucia M.

2014-06-10T23:59:59.000Z

240

Phase Behavior of Light Gases in Hydrocarbon and Aqueous Solvents  

SciTech Connect (OSTI)

Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, our solubility apparatus was refurbished and restored to full service. To test the experimental apparatus and procedures used, measurements were obtained for the solubility Of C0{sub 2} in benzene at 160{degrees}F. Having confirmed the accuracy of the newly acquired data in comparison with our previous measurements and data reported in the literature for this test system, we have begun to measure the solubility of hydrogen in hexane. The measurements for this system will cover the temperature range from 160 to 280{degrees}F at pressures to 2,500 psia. As part of our model evaluation efforts, we examined the predictive abilities of an alternative approach we have proposed for calculating the phase behavior properties of highly non-ideal systems. Using this approach, the liquid phase fugacities generated from an equation of state (EOS) are augmented by a fugacity deviation function correction. The correlative abilities of this approach are compared with those of an EOS equipped with the recently introduced Wong-Sandler (MWS) mixing rules. These two approaches are compared with the current methods for vapor-liquid equilibrium (VLE) calculations, i.e., the EOS (0/0) approach with the van der Waals mixing rules and the split (y/0) approach. The evaluations were conducted on a database comprised of non-ideal low pressure binary systems as well as asymmetric high pressure binary systems. These systems are of interest in the coal liquefaction and utilization processes. The Peng-Robinson EOS was selected for the purposes of this evaluation.

Gasem, K.A.M.; Robinson, R.L., Jr.; Trvedi, N.J., Gao, W.

1997-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

SOLVENT EXTRACTION FOR URANIUM MOLYBDENUM ALLOY DISSOLUTION FLOWSHEET  

SciTech Connect (OSTI)

H-Canyon Engineering requested the Savannah River National Laboratory (SRNL) to perform two solvent extraction experiments using dissolved Super Kukla (SK) material. The SK material is an uranium (U)-molybdenum (Mo) alloy material of 90% U/10% Mo by weight with 20% 235U enrichment. The first series of solvent extraction tests involved a series of batch distribution coefficient measurements with 7.5 vol % tributylphosphate (TBP)/n-paraffin for extraction from 4-5 M nitric acid (HNO{sub 3}), using 4 M HNO{sub 3}-0.02 M ferrous sulfamate (Fe(SO3NH2)2) scrub, 0.01 M HNO3 strip steps with particular emphasis on the distribution of U and Mo in each step. The second set of solvent extraction tests determined whether the 2.5 wt % sodium carbonate (Na2CO3) solvent wash change frequency would need to be modified for the processing of the SK material. The batch distribution coefficient measurements were performed using dissolved SK material diluted to 20 g/L (U + Mo) in 4 M HNO{sub 3} and 5 M HNO{sub 3}. In these experiments, U had a distribution coefficient greater than 2.5 while at least 99% of the nickel (Ni) and greater than 99.9% of the Mo remained in the aqueous phase. After extraction, scrub, and strip steps, the aqueous U product from the strip contains nominally 7.48 {micro}g Mo/g U, significantly less than the maximum allowable limit of 800 {micro}g Mo/g U. Solvent washing experiments were performed to expose a 2.5 wt % Na2CO3 solvent wash solution to the equivalent of 37 solvent wash cycles. The low Mo batch distribution coefficient in this solvent extraction system yields only 0.001-0.005 g/L Mo extracted to the organic. During the solvent washing experiments, the Mo appears to wash from the organic.

Visser, A; Robert Pierce, R

2007-06-07T23:59:59.000Z

242

Determination of the relationship between permeation rates and solubility parameter differences for selected protective glove/solvent and boot/solvent combinations  

E-Print Network [OSTI]

DETERMINATION OF THE RELATIONSHIP BETWEEN PERMEATION RATES AND SOLUBILITY PARAMETER DIFFERENCES FOR SELECTED PROTECTIVE GLOVE/SOLVENT AND BOOT/SOLVENT COMBINATIONS A Thesis by THOMAS JOSEPH JANICIK Submitted to the Graduate College of Texas A... PROTECTIVE GLOVE/SOLVENT AND BOOT/SOLVENT COMBINATIONS A Thesis by THOMAS JOSEPH JANICIK Approved as to style and content by: H . Sug (Chai a of Com ttee) Charles L. Gilmore (Member) Leon H. Russell (Member) ewton . is (Head of Department) August...

Janicik, Thomas Joseph

2012-06-07T23:59:59.000Z

243

2012 Annual Report: Simulate and Evaluate the Cesium Transport and Accumulation in Fukushima-Area Rivers by the TODAM Code  

SciTech Connect (OSTI)

Pacific Northwest National Laboratory initiated the application of the time-varying, one-dimensional sediment-contaminant transport code, TODAM (Time-dependent, One-dimensional, Degradation, And Migration) to simulate the cesium migration and accumulation in the Ukedo River in Fukushima. This report describes the preliminary TODAM simulation results of the Ukedo River model from the location below the Ougaki Dam to the river mouth at the Pacific Ocean. The major findings of the 100-hour TODAM simulation of the preliminary Ukedo River modeling are summarized as follows:

Onishi, Yasuo; Yokuda, Satoru T.

2013-03-28T23:59:59.000Z

244

REMOVAL OF CESIUM FROM SAVANNAH RIVER SITE WASTE WITH SPHERICAL RESORCINOL FORMALDEHYDE ION EXCHANGE RESIN EXPERIMENTAL TESTS  

SciTech Connect (OSTI)

A principal goal at the Savannah River Site (SRS) is to safely dispose of the large volume of liquid nuclear waste held in many storage tanks. In-tank ion exchange (IX) columns are being considered for cesium removal. The spherical form of resorcinol formaldehyde ion exchange resin (sRF) is being evaluated for decontamination of dissolved saltcake waste at SRS, which is generally lower in potassium and organic components than Hanford waste. The sRF performance with SRS waste was evaluated in two phases: resin batch contacts and IX column testing with both simulated and actual dissolved salt waste. The tests, equipment, and results are discussed.

Duignan, M.; Nash, C.

2010-03-31T23:59:59.000Z

245

Monitored Natural Attenuation of Chlorinated Solvents - Moving Beyond Reuctive Dechlorination  

SciTech Connect (OSTI)

Monitored natural attenuation (MNA), while a remedy of choice for many sites, can be challenging when the contaminants are chlorinated solvents. Even with many high quality technical guidance references available there continue to be challenges implementing MNA at some chlorinated solvent sites. The U.S. Department of Energy, as one organization facing such challenges, is leading a project that will incorporate developing concepts and tools into the existing toolbox for selecting and implementing MNA as a remediation option at sites with chlorinated solvents contamination. The structure and goals of this project were introduced in an article in the Winter 2004 issue of Remediation (Sink et al.). This article is a summary of the three technical areas being developed through the project: mass balance, enhanced attenuation, and characterization and monitoring supporting the first two areas. These topics will be documented in separate reports available from the US Department of Energy Office of Scientific and Technical Information at www.osti.gov.

Vangelas, K

2006-04-10T23:59:59.000Z

246

Structural Transitions of Solvent-Free Oligomer-Grafted Nanoparticles  

Science Journals Connector (OSTI)

Novel structural transitions of solvent-free oligomer-grafted nanoparticles are investigated by using molecular dynamics simulations of a coarse-grained bead-spring model. Variations in core size and grafting density lead to self-assembly of the nanoparticles into a variety of distinct structures. At the boundaries between different structures, the nanoparticle systems undergo thermoreversible transitions. This structural behavior, which has not been previously reported, deviates significantly from that of simple liquids. The reversible nature of these transitions in solvent-free conditions offers new ways to control self-assembly of nanoparticles at experimentally accessible conditions.

Alexandros Chremos and Athanassios Z. Panagiotopoulos

2011-09-01T23:59:59.000Z

247

A study of a solvent extraction desalination process  

E-Print Network [OSTI]

Major Subject: Chemical Engineering A STDDY OF A SOLVENT EXTRACTION DESALINATION PROCESS A Thesis By ARTHUR RANSOM MCFERRIN, JR, Approved as to style and content by: (Chairman of Committee) (Head of De artment) (Member) (M ' er) (Member) (Member...) (Member) August 1969 111 ABSTRACT A Study of a Solve. it Extr~c' ion Desalination Process (August 1969) Arthur Ransom McFerrin, Jr. , B. S. , Texas A&M University Directed by: Dr. R. R. Davison A study of a desalination by solvent extraction...

McFerrin, Arthur Ransom

2012-06-07T23:59:59.000Z

248

A new model for solvent extraction in columns  

SciTech Connect (OSTI)

A new model was developed for analyzing solvent extraction processes carried out in columns. Each column is treated as a series of well-defined equilibrium stages where the backmixing (other-phase carryover) between stages can be large. By including all mass transfer effects in the backmixing value, the same number of stages can be used for all extracted components no matter what their distribution coefficients. This greatly simplifies the calculations required when modeling multicomponent solvent extraction processes. Initial testing shows the new model to be better than either the Height of an Equivalent Theoretical Plate (HETP) or the Height of a Transfer Unit (HTU) method.

Leonard, R.A.; Regalbuto, M.C.; Chamberlain, D.B.; Vandegrift, G.F.

1989-12-08T23:59:59.000Z

249

Distributed Generation  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Untapped Value of Backup Generation Untapped Value of Backup Generation While new guidelines and regulations such as IEEE (Institute of Electrical and Electronics Engineers) 1547 have come a long way in addressing interconnection standards for distributed generation, utilities have largely overlooked the untapped potential of these resources. Under certain conditions, these units (primarily backup generators) represent a significant source of power that can deliver utility services at lower costs than traditional centralized solutions. These backup generators exist today in large numbers and provide utilities with another option to reduce peak load, relieve transmission congestion, and improve power reliability. Backup generation is widely deployed across the United States. Carnegie Mellon's Electricity

250

Microsoft PowerPoint - 1-08 Moyer+_TechExchMtg2010.pptx  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Technical Exchange Technical Exchange Meeting Atlanta, GA, Nov. 16-18, 2010 Next Generation Cesium Solvent Next Generation Cesium Solvent Bruce A. Moyer, Joseph F. Birdwell, Lætitia H. Delmau, Denise L. Schuh, Erica L. Stoner, Neil J. Williams Samuel D. Fink, Thomas B. Peters, Robert A. Pierce Ralph A. Leonard, Mark W. Geeting O O O O O O O O Fr + 137 Cs + Savannah River National Laboratory Print Close A Next-Generation CSSX process can accelerate tank-waste cleanup Improved Cs removal for SRS and possibly even Hanford It is possible for SRS MCU performance to be increased to DF ≥ 40,000 and CF = 15 for SRS waste treatment, probably at increased throughput. SWPF throughput can likely be increased. A modular CSSX process for the more challenging Hanford waste is now feasible. 2 Next Generation Cesium Solvent

251

Interim salt disposition program macrobatch 6 tank 21H qualification monosodium titanate and cesium mass transfer tests  

SciTech Connect (OSTI)

Savannah River National Laboratory (SRNL) performed experiments on qualification material for use in the Interim Salt Disposition Program (ISDP) Batch 6 processing. This qualification material was a set of six samples from Tank 21H in October 2012. This sample was used as a real waste demonstration of the Actinide Removal Process (ARP) and the Extraction-Scrub-Strip (ESS) tests process. The Tank 21H sample was contacted with a reduced amount (0.2 g/L) of MST and characterized for strontium and actinide removal at 0 and 8 hour time intervals in this salt batch. {sup 237}Np and {sup 243}Am were both observed to be below detection limits in the source material, and so these results are not reported in this report. The plutonium and uranium samples had decontamination factor (DF) values that were on par or slightly better than we expected from Batch 5. The strontium DF values are slightly lower than expected but still in an acceptable range. The Extraction, Scrub, and Strip (ESS) testing demonstrated cesium removal, stripping and scrubbing within the acceptable range. Overall, the testing indicated that cesium removal is comparable to prior batches at MCU.

Washington, A. L. II; Peters, T. B.; Fink, S. D.

2013-02-25T23:59:59.000Z

252

Dimethyl carbonate as a modern green reagent and solvent  

Science Journals Connector (OSTI)

Published data on dimethyl carbonate as a safe reagent and solvent in organic synthesis are generalized and analyzed. The methods of dimethyl carbonate preparation and its use as methylating and carboxymethylating reagent are considered. The attention is focused on the environmentally safe processes corresponding to the green chemistry principles.

F Aricò; Pietro Tundo

2010-01-01T23:59:59.000Z

253

Note on the Origin of Solvent Knight Shifts in Alloys  

Science Journals Connector (OSTI)

It is shown that the good agreement between theory and experiment which Watson, Bennett, and Freeman claim in a recent paper on the origin of solvent Knight shifts in alloys does not exist and that consequently one cannot conclude that their results per se point to deficiencies in other methods of evaluating Knight shifts.

D. O. Van Ostenburg and L. C. R. Alfred

1968-06-24T23:59:59.000Z

254

Solvent Selection Use dry ice/isopropanol for cooling baths  

E-Print Network [OSTI]

Solvent Selection Use dry ice/isopropanol for cooling baths Reaches essentially the same temperature as dry ice/acetone (-77°C vs. -78°C), but the lower volatility of isopropanol minimizes vapor a closed-loop cooling system for condensers Closed-loop cooling systems eliminate wastewater and accidental

Chan, Hue Sun

255

Injection Solvent Effect on Peak Height in Ion Exchange HPLC  

Science Journals Connector (OSTI)

......2. To further evaluate the effect of the injection volume only...injection volume were varied. Effect of weak injection solvent There...same eluent ion strength. The effect of eluent ion strength. Figure...nitrate in the mobile phase. 418 ship of the peak height of phenylacetate......

Hyunjoo Kim Lee; Norman E. Hoffman

1992-10-01T23:59:59.000Z

256

Generation Planning (pbl/generation)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Generation Hydro Power Wind Power Monthly GSP BPA White Book Dry Year Tools Firstgov Generation Planning Thumbnail image of BPA White Book BPA White Book (1998 - 2011) Draft Dry...

257

Evaluation of toxicity and biodegradability of choline chloride based deep eutectic solvents  

Science Journals Connector (OSTI)

Abstract Deep eutectic solvents (DESs) have been dramatically expanding in popularity as a new generation of environmentally friendly solvents with possible applications in various industrial fields, but their ecological footprint has not yet been thoroughly investigated. In the present study, three choline chloride-based \\{DESs\\} with glucose, glycerol and oxalic acid as hydrogen bond donors were evaluated for in vitro toxicity using fish and human cell line, phytotoxicity using wheat and biodegradability using wastewater microorganisms through closed bottle test. Obtained in vitro toxicity data on cell lines indicate that choline chloride: glucose and choline chloride:glycerol possess low cytotoxicity (EC50>10 mM for both cell lines) while choline chloride:oxalic acid possess moderate cytotoxicity (EC50 value 1.64 mM and 4.19 mM for fish and human cell line, respectively). Results on phytotoxicity imply that tested \\{DESs\\} are non-toxic with seed germination EC50 values higher than 5000 mg l?1. All tested \\{DESs\\} were classified as?readily biodegradable? based on their high levels of mineralization (68–96%). These findings indicate that \\{DESs\\} have a green profile and a good prospect for a wider use in the field of green technologies.

Kristina Radoševi?; Marina Cvjetko Bubalo; Višnje Gaurina Sr?ek; Dijana Grgas; Tibela Landeka Dragi?evi?; Ivana Radoj?i? Redovnikovi?

2015-01-01T23:59:59.000Z

258

Stabilization of Rocky Flats combustible residues contaminated with plutonium metal and organic solvents  

SciTech Connect (OSTI)

This report describes tests on a proposed flowsheet designed to stabilize combustible residues that were generated at the Rocky Flats Environmental Technology Site (RFETS) during the machining of plutonium metal. Combustible residues are essentially laboratory trash contaminated with halogenated organic solvents and plutonium metal. The proposed flowsheet, designed by RFETS, follows a glovebox procedure that includes (1) the sorting and shredding of materials, (2) a low temperature thermal desorption of solvents from the combustible materials, (3) an oxidation of plutonium metal with steam, and (4) packaging of the stabilized residues. The role of Los Alamos National Laboratory (LANL) in this study was to determine parameters for the low temperature thermal desorption and steam oxidation steps. Thermal desorption of carbon tetrachloride (CCl{sub 4}) was examined using a heated air stream on a Rocky Flats combustible residue surrogate contaminated with CCl{sub 4}. Three types of plutonium metal were oxidized with steam in a LANL glovebox to determine the effectiveness of this procedure for residue stabilization. The results from these LANL experiments are used to recommend parameters for the proposed RFETS stabilization flowsheet.

Bowen, S.M.; Cisneros, M.R.; Jacobson, L.L.; Schroeder, N.C.; Ames, R.L.

1998-09-30T23:59:59.000Z

259

Production of biodiesel from Vietnamese Jatropha curcas oil by a co-solvent method  

Science Journals Connector (OSTI)

Abstract Biodiesel fuels (BDFs) was successfully produced from Vietnamese Jatropha curcas oil with high content of free fatty acids (FFAs) in two stages. In the first stage, the esterification process was carried out with the optimal conditions as follows; a methanol-to-FFAs molar ratio of 6:1, 1 wt% H2SO4, at a temperature of 65 °C, and using 30% (wt/wt) acetonitrile as co-solvent. This step reduced the concentration of \\{FFAs\\} in the reaction mixture from 15.93 to 2 wt% in 60 min. In the second stage, the transesterification process generated fatty acid methyl esters (FAMEs) with 99% efficiency was performed in 30 min with the optimal conditions as follows; a methanol-to-oil molar ratio of 6:1, 1 wt% KOH, at a temperature of 40 °C, and 20% (wt/wt) acetone as co-solvent. The produced biodiesel quality meets the standards JIS K2390 and EN 14214 regarding FAME yield, \\{FFAs\\} and water contents.

Phuong Duc Luu; Hoa Thi Truong; Boi Van Luu; Lan Ngoc Pham; Kyoshi Imamura; Norimichi Takenaka; Yasuaki Maeda

2014-01-01T23:59:59.000Z

260

Separation of Underivatised Amino Acid Enantiomers by Means of a Chiral Solvent-Generated Phase  

Science Journals Connector (OSTI)

......the separation o f -amino and -hydroxy car boxylic acid enantiomers. A n alternative...from Mutant Strains of Escherichia coli Defective in the Energy- Transducing Atpase. Wachter...Complete Amino Acid Sequence of Bovine Car diac Troponin C. J.P. Van Eerd and......

Rainer Wernicke

1985-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Simultaneous Extraction of Flavonoids from Chamaecyparis obtusa Using Deep Eutectic Solvents as Additives of Conventional Extractions Solvents  

Science Journals Connector (OSTI)

......complicated synthetic processes (10). Therefore...solvent in the heating process (60C) for 120 min...Extraction of glycerol from biodiesel into a eutectic based...from palm oil-based biodiesel using ionic liquids...Tian M., Row K.H. Evaluation of alcohol-based deep......

Baokun Tang; Ha Eun Park; Kyung Ho Row

2014-09-01T23:59:59.000Z

262

Preliminary Three-Dimensional Simulation of Sediment and Cesium Transport in the Ogi Dam Reservoir using FLESCOT – Task 6, Subtask 2  

SciTech Connect (OSTI)

After the accident at the Fukushima Daiichi Nuclear Power Plant in March 2011, the Japan Atomic Energy Agency and the Pacific Northwest National Laboratory initiated a collaborative project on environmental restoration. In October 2013, the collaborative team started a task of three-dimensional modeling of sediment and cesium transport in the Fukushima environment using the FLESCOT (Flow, Energy, Salinity, Sediment Contaminant Transport) code. As the first trial, we applied it to the Ogi Dam Reservoir that is one of the reservoirs in the Japan Atomic Energy Agency’s (JAEA’s) investigation project. Three simulation cases under the following different temperature conditions were studied: • incoming rivers and the Ogi Dam Reservoir have the same water temperature • incoming rivers have lower water temperature than that of the reservoir • incoming rivers have higher water temperature than that of the reservoir. The preliminary simulations suggest that seasonal temperature changes influence the sediment and cesium transport. The preliminary results showed the following: • Suspended sand, and cesium adsorbed by sand, coming into the reservoirs from upstream rivers is deposited near the reservoir entrance. • Suspended silt, and cesium adsorbed by silt, is deposited farther in the reservoir. • Suspended clay, and cesium adsorbed by clay, travels the farthest into the reservoir. With sufficient time, the dissolved cesium reaches the downstream end of the reservoir. This preliminary modeling also suggests the possibility of a suitable dam operation to control the cesium migration farther downstream from the dam. JAEA has been sampling in the Ogi Dam Reservoir, but these data were not yet available for the current model calibration and validation for this reservoir. Nonetheless these preliminary FLESCOT modeling results were qualitatively valid and confirmed the applicability of the FLESCOT code to the Ogi Dam Reservoir, and in general to other reservoirs in the Fukushima environment. The issues to be addressed in future are the following: • Validate the simulation results by comparison with the investigation data. • Confirm the applicability of the FLESCOT code to Fukushima coastal areas. • Increase computation speed by parallelizing the FLESCOT code.

Onishi, Yasuo; Kurikami, Hiroshi; Yokuda, Satoru T.

2014-03-28T23:59:59.000Z

263

Impact of solvent type and injection sequence on Enhanced Cyclic Solvent Process (ECSP) for thin heavy oil reservoirs  

Science Journals Connector (OSTI)

Abstract A considerable portion of the western Canada's heavy oil resides in thin formations. In this situation, thermal methods cannot be used due to heat loss to overburden and underburden. Vapor extraction (VAPEX) fails because of inefficient gravity drainage and low initial production rate. Studies have been done on the cyclic solvent process (CSP) in an attempt to speed up the oil production rate in the solvent injection process. CSP performs poorly because the presence of continuous free methane saturation at the start of production cycles results in high gas mobility, and, consequently, quick methane production, quick pressure depletion, and a significant loss of oil viscosity reduction. As a result, the drive energy becomes depleted by methane production. Also, if low or intermediate initial production pressures are used, the methane solubility in the oil is not high, and the viscosity reduction is not significant. To resolve the above problems of CSP, Yadali Jamaloei et al. (2012) introduced a new process for thin reservoirs – Enhanced Cyclic Solvent Process (ECSP). In ECSP, two types of hydrocarbon solvents are injected separately, in a cyclic manner; one slug is more volatile (methane) and the other is more soluble (propane or ethane) in heavy oil and bitumen. The focus of this study is finding the optimum solvent injection sequence; this will be accomplished through examining the impact of the solvent injection sequence on the performance of ECSP, using different solvent pairs. The experimental results obtained from four series of ECSP tests, each consisting of six cycles, show higher oil recovery and production rate, and lower gas requirement and drawdown when methane is injected before ethane or propane. Wabiskaw formation in the Pelican oilfield in northern Alberta with 17 wells was chosen for performing simulation of ECSP. History matching was conducted for field-scale cumulative oil, gas and water production, and average reservoir pressure. Injection rate and injection time of methane and propane, soaking time and minimum well bottom-hole pressure in the methane–propane ECSP scheme were optimized to predict the field production performance of ECSP. Field-scale simulation revealed that the proposed methane–propane ECSP scheme is a highly effective method for improving heavy oil recovery in thin reservoirs.

Benyamin Yadali Jamaloei; Mingzhe Dong; Ping Yang; Daoyong Yang; Nader Mahinpey

2013-01-01T23:59:59.000Z

264

STUDY OF SOLVENT AND CATALYST INTERACTIONS IN DIRECT COAL LIQUEFACTION  

SciTech Connect (OSTI)

There are several aspects of the Direct Coal Liquefaction process which are not fully understood and which if better understood might lead to improved yields and conversions. Among these questions are the roles of the catalyst and the solvent. While the solvent is known to act by transfer of hydrogen atoms to the free radicals formed by thermal breakdown of the coal in an uncatalyzed system, in the presence of a solid catalyst as is now currently practiced, the yields and conversions are higher than in an uncatalyzed system. The role of the catalyst in this case is not completely understood. DOE has funded many projects to produce ultrafine and more active catalysts in the expectation that better contact between catalyst and coal might result. This approach has met with limited success probably because mass transfer between two solids in a fluid medium i.e. the catalyst and the coal, is very poor. It is to develop an understanding of the role of the catalyst and solvent in Direct Liquefaction that this project was initiated. Specifically it was of interest to know whether direct contact between the coal and the catalyst was important. By separating the solid catalyst in a stainless steel basket permeable to the solvent but not the coal in the liquefaction reactor, it was shown that the catalyst still maintains a catalytic effect on the liquefaction process. There is apparently transfer of hydrogen atoms from the catalyst through the basket wall to the coal via the solvent. Strong hydrogen donor solvents appear to be more effective in this respect than weak hydrogen donors. It therefore appears that intimate contact between catalyst and coal is not a requirement, and that the role of the catalyst may be to restore the hydrogen donor strength to the solvent as the reaction proceeds. A range of solvents of varying hydrogen donor strength was investigated. Because of the extensive use of thermogravimetric analysis in this laboratory in was noted that the peak temperature for volatile evolution from coal was a reliable measure of coal rank. Because of this observation, a wide variety of coals of a wide range of ranks was investigated. It was shown in this work that measuring the peak temperature for volatile evolution was quite a precise indicator of rank and correlated closely wit the rank values obtained by measuring vitrinite reflectance, a more difficult measurement to make. This prompted the desire to know the composition of the volatile materials evolved as a function of coal rank. This was then measured by coupling a TGA to a mass spectrometer using laser activation and photoionization detection TG-PI-MS. The predominant species in volatiles of low rank coal turned out to be phenols with some alkenes. As the rank increases, the relative amount of alkenes and aromatic hydrocarbons increases and the oxygenated species decrease. It was shown that these volatiles were actually pyrolitic products and not volatilization products of coal. Solvent extraction experiments coupled with TG-PI-MS indicates that the low oiling and more extractable material are essentially similar in chemical types to the non-extractable portions but apparently higher molecular weight and therefor less extractable.

Michael T. Klein

2000-01-01T23:59:59.000Z

265

Effect of solvent debinding variables on the shape maintenance of green molded bodies  

Science Journals Connector (OSTI)

In order to study the effect of solvent extraction debinding variables on the shape maintenance of green molded bodies, powder compression molded bodies (the feed) were debound in various organic solvents such as...

M. T. Zaky

266

Effects of Solvent on Polymer Chain Dimensions: A Born-Green-Yvon Integral Equation Study  

E-Print Network [OSTI]

The equilibrium properties of a tangent-hard-sphere polymer chain in a hard sphere monomer solvent are studied using a Born-Green-Yvon integral equation in conjunction with a two-site solvation potential. The solvation potential is constructed using low density results for a hard-sphere trimer in a hard sphere solvent. The BGY equation has been solved for polymers of lengths up to 100 for a range of solvent densities and solvent diameters. The theory accurately describes the compression of the average polymer dimensions with increasing solvent density. The theory also accurately describes the variation in this compression as a function of the solvent diameter, predicting a maximum effect when the solvent diameter is two to three times larger than the polymer site diameter. Scaling exponents relating the polymer dimensions to chain length and solvent density are also obtained.

Mark P. Taylor; J. E. G. Lipson

1997-08-16T23:59:59.000Z

267

Extraction of catechin compounds from green tea with a new green solvent  

Science Journals Connector (OSTI)

An emerging green solvent called a deep eutectic solvent(DES) was applied to the extraction and ... and (?)epigallocatechin gallate(EGCG) from Chinese green tea. After evaluating different combinations of them .....

Heng Zhang; Baokun Tang; Kyungho Row

2014-02-01T23:59:59.000Z

268

E-Print Network 3.0 - alternative solvent systems Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

polymer in this mixed solvent system in the temperature range 20-90C... of the solvent penetration (or dissolution rate defined as the amount of polymer dissolved per unit time...

269

Solvent effects on gravure-printed organic layers of nanoscale thickness for organic solar cells  

Science Journals Connector (OSTI)

The effects of different solvents on the fabrication of organic photovoltaic cells by gravure printing are reported. Polymer bulk heterojunction solar cells were fabricated with ITO/PEDOT: PSS/P3HT ... of solvent...

Jiyeon Lee; Aran Kim; Sung Min Cho; Heeyeop Chae

2012-03-01T23:59:59.000Z

270

The Extraction?Flocculation Re-refining Lubricating Oil Process Using Ternary Organic Solvents  

Science Journals Connector (OSTI)

The Extraction?Flocculation Re-refining Lubricating Oil Process Using Ternary Organic Solvents ... Res., 1997, 36 (9), ... Waste lubricating oils may be re-refined with organic solvents that dissolve base oil and segregate the additives and solid particles. ...

J. P. Martins

1997-09-02T23:59:59.000Z

271

THE COMBUSTION OF SOLVENT REPINED COAL IN AN OPPOSED FLOW DIFFUSION FLAME  

E-Print Network [OSTI]

R.F. (1977). Combustion of coal in an opposed flow diffusionpulverized, solvent-refined coal. ASME Paper No. 76-WA/FU-6.OF SOLVENT REFINED COAL IN AN OPPOSED FLOW DIFFUSION FLAME*

Chin, W.K.

2011-01-01T23:59:59.000Z

272

Ionic Liquids as an Attractive Alternative Solvent for Thermal Lens Measurements  

E-Print Network [OSTI]

in volatile organic solvents such as benzene, carbon tetrachloride, and hexane. However, the ILs are more,2 Nonpolar, volative organic solvents such as benzene, carbon tetrachloride, and hexane should provide good

Reid, Scott A.

273

POLYMER SOLUTIONS AND SOLVENT-SUPERCRITICAL CARBON DIOXIDE STUDIES APPLIYING PC-SAFT.  

E-Print Network [OSTI]

??ABSTRACTIn this thesis is presented the phase equilibria predictions for several polymer solutions and polymer-solvent-solvent systems with the presence of supercritical carbon dioxide (scCO2) applying… (more)

Catano-Barrera, Alma

2011-01-01T23:59:59.000Z

274

SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION-EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATIONS-12092  

SciTech Connect (OSTI)

Experimental results for the selective removal of strontium and cesium from simulated waste solutions with monosodium titanate and crystalline silicotitanate laden filter cartridges are presented. In these proof-of-principle tests, effective uptake of both strontium-85 and cesium-137 were observed using ion-exchangers in this filter cartridge configuration. At low salt simulant conditions, the instantaneous decontamination factor for strontium-85 with monosodium titanate impregnated filter membrane cartridges measured 26, representing 96% strontium-85 removal efficiency. On the other hand, the strontium-85 instantaneous decontamination factor with co-sintered active monosodium titanate cartridges measured 40 or 98% Sr-85 removal efficiency. Strontium-85 removal with the monosodium titanate impregnated membrane cartridges and crystalline silicotitanate impregnated membrane cartridges, placed in series arrangement, produced an instantaneous decontamination factor of 41 compared to an instantaneous decontamination factor of 368 for strontium-85 with co-sintered active monosodium titanate cartridges and co-sintered active crystalline silicotitanate cartridges placed in series. Overall, polyethylene co-sintered active titanates cartridges performed as well as titanate impregnated filter membrane cartridges in the uptake of strontium. At low ionic strength conditions, there was a significant uptake of cesium-137 with co-sintered crystalline silicotitanate cartridges. Tests results with crystalline silicotitanate impregnated membrane cartridges for cesium-137 decontamination are currently being re-evaluated. Based on these preliminary findings we conclude that incorporating monosodium titanate and crystalline silicotitanate sorbents into membranes represent a promising method for the semicontinuous removal of radioisotopes of strontium and cesium from nuclear waste solutions.

Oji, L.; Martin, K.; Hobbs, D.

2012-01-03T23:59:59.000Z

275

Hydrogen Generation for Refineries  

Broader source: Energy.gov (indexed) [DOE]

bottoms (VTB), vacuum resid) * Dilbit (tar sand bitumen diluted with 30% condensate) * Biomass fast pyrolysis oil (whole raw oil) * Norpar 12 (C 11 C 12 paraffinic solvent -...

276

A mixed-solvent strategy for facile and green preparation of graphene by liquid-phase exfoliation of graphite  

Science Journals Connector (OSTI)

A versatile and scalable mixed-solvent strategy, by which two mediocre solvents could be combined into good solvents for exfoliating graphite, is demonstrated for facile and green preparation of graphene by liqui...

Min Yi; Zhigang Shen; Shulin Ma; Xiaojing Zhang

2012-07-01T23:59:59.000Z

277

An Analytical Model for Determination of the Solvent Convective Dispersion Coefficient in the Vapor Extraction Heavy Oil Recovery Process  

Science Journals Connector (OSTI)

In this article, a new model is developed to determine the solvent convective dispersion coefficient in a solvent vapor extraction (VAPEX) heavy oil recovery process. It is assumed that solvent mass transfer b...

Mohammad Derakhshanfar; Yongan Gu

2012-03-01T23:59:59.000Z

278

Solvent-refined-coal (SRC) process. Volume II. Sections V-XIV. Final report  

SciTech Connect (OSTI)

This report documents the completion of development work on the Solvent Refined Coal Process by The Pittsburgh and Midway Coal Mining Co. The work was initiated in 1966 under Office of Coal Research, US Department of Interior, Contract No. 14-01-0001-496 and completed under US Department of Energy Contract No. DE-AC05-79ET10104. This report discusses work leading to the development of the SRC-I and SRC-II processes, construction of the Fort Lewis Pilot Plant for the successful development of these processes, and results from the operation of this pilot plant. Process design data generated on a 1 ton-per-day Process Development Unit, bench-scale units and through numerous research projects in support of the design of major demonstration plants are also discussed in summary form and fully referenced in this report.

Not Available

1982-05-01T23:59:59.000Z

279

Scientific Correspondence Are Natural Deep Eutectic Solvents the Missing Link in  

E-Print Network [OSTI]

Scientific Correspondence Are Natural Deep Eutectic Solvents the Missing Link in Understanding in the biochemistry of cells and organisms. The theory is based on analogy with green chemistry, where in past years and deep eutectic solvents (DES) have been revisited by chemical engineering, because such solvents can

Galis, Frietson

280

Solvent-Induced Frequency Shifts of 5-Hydroxymethylfurfural Deduced via Infrared Spectroscopy and ab Initio Calculations  

Science Journals Connector (OSTI)

Solvent-Induced Frequency Shifts of 5-Hydroxymethylfurfural Deduced via Infrared Spectroscopy and ab Initio Calculations ... Solvent-induced frequency shifts (SIFS) of the carbonyl stretching vibration ?(C?O) of 5-hydroxymethylfurfural were measured in protic, polar aprotic, and nonpolar solvents. ...

Tyler R. Josephson; George Tsilomelekis; Christina Bagia; Vladimiros Nikolakis; Dionisios G. Vlachos; Stavros Caratzoulas

2014-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Biomass to Jetfuel-Solvent Optimization in Biphasic Maheen Khan, Doctor Geoff Tompsett, Professor George Huber  

E-Print Network [OSTI]

Biomass to Jetfuel- Solvent Optimization in Biphasic Reaction Maheen Khan, Doctor Geoff Tompsett to simulate reactor conditions · Run dehydration reaction with solvents and determine whether partition. REACTOR DECANTOR SEPARATEFEED PRODUCT AQUEOUS ORGANIC SOLVENT MAKE-UP FURFURAL Figure 5. Aspen

Mountziaris, T. J.

282

Development of carbon-carbon composites from solvent extracted pitch  

SciTech Connect (OSTI)

There are several methods used to fabricate carbon-carbon composites. One used extensively in the fabrication of aerospace components such as rocket nozzles and reentry vehicle nosetips, as well as commercial components for furnace fixturing and glass manufacturing, is the densification of a woven preform with molten pitch, and the subsequent conversion of the pitch to graphite through heat treatment. Two types of pitch are used in this process; coal tar pitch and petroleum pitch. The objective of this program was to determine if a pitch produced by the direct extraction of coal could be used as a substitute for these pitches in the fabrication of carbon-carbon composites. The program involved comparing solvent extracted pitch with currently accepted pitches and rigidizing a carbon-carbon preform with solvent extracted pitch for comparison with carbon-carbon fabricated with currently available pitch.

NONE

1996-06-24T23:59:59.000Z

283

The Impact Of The MCU Life Extension Solvent On Sludge Batch 8 Projected Operating Windows  

SciTech Connect (OSTI)

As a part of the Actinide Removal Process (ARP)/Modular Caustic Side Solvent Extraction Unit (MCU) Life Extension Project, a next generation solvent (NGS) and a new strip acid will be deployed. The strip acid will be changed from dilute nitric acid to dilute boric acid (0.01 M). Because of these changes, experimental testing or evaluations with the next generation solvent are required to determine the impact of these changes (if any) to Chemical Process Cell (CPC) activities, glass formulation strategies, and melter operations at the Defense Waste Processing Facility (DWPF). The introduction of the dilute (0.01 M) boric acid stream into the DWPF flowsheet has a potential impact on glass formulation and frit development efforts since B203 is a major oxide in frits developed for DWPF. Prior knowledge of this stream can be accounted for during frit development efforts but that was not the case for Sludge Batch 8 (SB8). Frit 803 has already been recommended and procured for SB8 processing; altering the frit to account for the incoming boron from the strip effluent (SE) is not an option for SB8. Therefore, the operational robustness of Frit 803 to the introduction of SE including its compositional tolerances (i.e., up to 0.0125M boric acid) is of interest and was the focus of this study. The primary question to be addressed in the current study was: What is the impact (if any) on the projected operating windows for the Frit 803 - SB8 flowsheet to additions of B203 from the SE in the Sludge Receipt and Adjustment Tank (SRAT)? More specifically, will Frit 803 be robust to the potential compositional changes occurring in the SRAT due to sludge variation, varying additions of ARP and/or the introduction of SE by providing access to waste loadings (WLs) of interest to DWPF? The Measurement Acceptability Region (MAR) results indicate there is very little, if any, impact on the projected operating windows for the Frit 803 - SB8 system regardless of the presence or absence of ARP and SE (up to 2 wt% B203 contained in the SRAT and up to 2000 gallons of ARP). It should be noted that 0.95 wt% B203 is the nominal projected concentration in the SRAT based on a 0.0125M boric acid flowsheet with 70,000 liters of SE being added to the SRAT.

Peeler, D. K.; Edwards, T. B.

2013-06-26T23:59:59.000Z

284

Concrete characterization for the 300 Area Solvent Evaporator Closure Site  

SciTech Connect (OSTI)

This report summarizes the sampling activities undertaken and the analytical results obtained in a concrete sampling and analyses study performed for the 300 Area Solvent Evaporator (300 ASE) closure site. The 300 ASE is identified as a Resource Conservation and Recovery Act (RCRA) treatment, storage, or disposal (TSD) unit that will be closed in accordance with the applicable laws and regulations. No constituents of concern were found in concentrations indicating contamination of the concrete by 300 ASE operations.

Prignano, A.L.

1995-02-21T23:59:59.000Z

285

Polymeric Assembly of Gluten Proteins in an Aqueous Ethanol Solvent  

E-Print Network [OSTI]

The supramolecular organization of wheat gluten proteins is largely unknown due to the intrinsic complexity of this family of proteins and their insolubility in water. We fractionate gluten in a water/ethanol (50/50 v/v) and obtain a protein extract which is depleted in gliadin, the monomeric part of wheat gluten proteins, and enriched in glutenin, the polymeric part of wheat gluten proteins. We investigate the structure of the proteins in the solvent used for extraction over a wide range of concentration, by combining X-ray scattering and multi-angle static and dynamic light scattering. Our data show that, in the ethanol/water mixture, the proteins display features characteristic of flexible polymer chains in a good solvent. In the dilute regime, the protein form very loose structures of characteristic size 150 nm, with an internal dynamics which is quantitatively similar to that of branched polymer coils. In more concentrated regimes, data highlight a hierarchical structure with one characteristic length scale of the order of a few nm, which displays the scaling with concentration expected for a semi-dilute polymer in good solvent, and a fractal arrangement at much larger length scale. This structure is strikingly similar to that of polymeric gels, thus providing some factual knowledge to rationalize the viscoelastic properties of wheat gluten proteins and their assemblies.

Mohsen Dahesh; Amélie Banc; Agnès Duri; Marie-Hélène Morel; Laurence Ramos

2014-09-02T23:59:59.000Z

286

Improved solvents for seawater desalination (the Puraq process)  

SciTech Connect (OSTI)

The Puraq process for desalinating seawater is based on solven extraction of fresh water from seawater using specially tailored liquid polymers with molecular weights of 3000 or less. This polymeric solvent insures that the solubility of solvent in the coexistent aqueous phases within the process will be essentially zero. Although it was indicated earlier that the upper limit of polymer content in recycle solvent stream could not exceed 92%, this restrictive upper limit could be exceeded by broadening the field of possible polymer compositions used in choosing a particular sample. This would further decrease the projected cost of product water from $2.03 to $1.08 per thousand gallons. Presence in the polymer of water-soluble components prevented the separation of water droplets when determining the cloud point with small amounts of water in the sample. A number of measurements of true'' phase points indicated that for most samples, the difference in temperatures of phase separation between compositions of 80 and 98% was 15 C or less.

Not Available

1991-01-01T23:59:59.000Z

287

Thermoelectric Generators 1. Thermoelectric generator  

E-Print Network [OSTI]

. Cold Hot I - -- - - - - -- Figure 1 Electron concentration in a thermoelectric material. #12;2 A large1 Thermoelectric Generators HoSung Lee 1. Thermoelectric generator 1.1 Basic Equations In 1821 on the direction of current and material [3]. This is called the Thomson effect (or Thomson heat). These three

Lee, Ho Sung

288

Ion exchange kinetics of cesium for various reaction designs using crystalline silicotitanate, UOP IONSIV IE-911  

E-Print Network [OSTI]

, the major component of CST, slowly dissolved at hydrogen peroxide concentrations greater than 1 M. A simple and novel experimental apparatus for a single-layer ion exchange column was developed to generate experimental data for estimation...

Kim, Sung Hyun

2004-09-30T23:59:59.000Z

289

Gasflooding-assisted cyclic solvent injection (GA-CSI) for enhancing heavy oil recovery  

Science Journals Connector (OSTI)

Abstract Cyclic solvent injection (CSI) process has showed great potential to enhance heavy oil recovery because it takes advantages of solution-gas drive and foamy oil flow for oil production. However, CSI suffers from solvent release during the production period so that the viscosity of the solvent-diluted heavy oil is re-increased and its mobility is re-decreased. How to effectively recover the solvent-diluted heavy oil becomes a key technical challenge in a CSI process. This paper first experimentally analyzed a conventional CSI process that used a solvent injector as an oil producer alternately. It is found that foamy oil was induced and flowed to the producer during the production period of a cycle but some foamy oil was pushed back by solvent during the solvent injection period of the following cycle. Such “back-and-forth” movement of foamy oil seriously hindered the productivity of the CSI process. On the basis of this knowledge, this study proposed a new process, gasflooding-assisted cyclic solvent injection (GA-CSI), to enhance the performance of CSI. In a GA-CSI process, the solvent injector and the oil producer were placed horizontally apart. An additional solvent gasflooding process was applied immediately after the pressure drawdown process to produce the foamy oil that lost its mobility due to solvent release. The experimental results showed that the oil production rate of the newly proposed GA-CSI process is 3?4 times of that for a conventional CSI process.

Xinfeng Jia; Fanhua Zeng; Yongan Gu

2015-01-01T23:59:59.000Z

290

Oak Ridge K-25 Site chlorinated solvent pollution prevention opportunity assessment  

SciTech Connect (OSTI)

A pollution prevention opportunity assessment (PPOA) was conducted at the Oak Ridge K-25 Site to identify opportunities to reduce and better manage the use of chlorinated solvents. At the K-25 Site, 67 control areas were examined for their potential use of chlorinated solvents. Of these areas, 27 were found to be using (1) chlorinated solvents for cleaning, degreasing, and lubricating; (2) laboratory standards and solvents; and (3) test medium. Current management practices encourage the identification and use of nonhazardous chemicals, including the use of chlorinated solvents. The main pollution prevention principles are source reduction and recycling, and a number of pollution prevention options based on these principles were identified and evaluated as part of this chlorinated solvent PPOA. Source reduction options evaluated for the K-25 Site include the substitution of chlorinated solvents with nonchlorinated solvents. Recycling was identified for those areas that would benefit most from the reuse of the chlorinated solvents in use. The pollution prevention options that offer the greatest opportunity for success at the K-25 Site are the implementation of substitutes at the 10 control areas using chlorinated solvents for cleaning, degreasing, and lubrication. A change in the process may be all that is needed to eliminate the use of a chlorinated solvent. Once a decision is made to implement a substitution, the information should be communicated to all shops and laboratories. Another option to consider is the installation of recycling units to recycle the large amounts of methylene chloride used in the analytical sampling procedure.

Not Available

1994-08-01T23:59:59.000Z

291

Quasiseparable Generators  

Science Journals Connector (OSTI)

It is clear from the preceding chapter that any matrix has quasiseparable representations. By padding given quasiseparable generators with zero matrices of large sizes one ... large orders. However, one is lookin...

Yuli Eidelman; Israel Gohberg…

2014-01-01T23:59:59.000Z

292

CO2 emission reduction from natural gas power stations using a precipitating solvent absorption process  

Science Journals Connector (OSTI)

Abstract There has been a rapid increase in the use of natural gas for power generation based on gas turbine technology which elevates the importance of carbon dioxide (CO2) capture technology to reduce CO2 emissions from gas turbine based power stations. The low content of CO2 in the gas turbine exhaust results in low rates of CO2 absorption and larger absorption equipment when compared to studies done on coal fired power stations. Furthermore the high oxygen (O2) content in the exhaust gas adversely affects the solvent stability, particularly for the traditional amine based solvents. This paper describes how exhaust gas recirculation (EGR) along with CO2CRC's low cost “UNO MK 3” precipitating potassium carbonate (K2CO3) process can overcome the challenges of CO2 capture from gas turbine power stations. To further bring down the energy requirements of the capture process, heat integration of the UNO MK 3 process with power generation process is carried out. An economic analysis of the various retrofit options is performed. The current study shows that in the case of retrofitting the UNO MK 3 process to a natural gas combined cycle (NGCC), the use of EGR can reduce the energy penalty of CO2 capture by 15%, whilst a reduction of up to 25% can be achieved with the heat integration strategies described. Significantly the study shows that converting an existing open cycle gas turbine (OCGT) to a combined cycle with steam generation along with retrofitting CO2 capture presents a different steam cycle design for the maximum power output from the combined cycle with CO2 capture. Such a conversion actually produces more power and offers an alternative low emission retrofit pathway for gas fired power. Cost analysis shows that inclusion of the UNO MK 3 CO2 capture process with EGR to an existing NGCC is expected to increase the cost of electricity (COE) by 20%. However, retrofit/repowering of an underutilised or peaking OCGT station with the inclusion of CO2 capture can reduce the COE as well as produce low emission power. This is achieved by increasing the load factor and incorporating a purpose built steam generation cycle.

Jai Kant Pandit; Trent Harkin; Clare Anderson; Minh Ho; Dianne Wiley; Barry Hooper

2014-01-01T23:59:59.000Z

293

In silico design of solvents for carbon capture with simultaneous optimisation of operating conditions  

Science Journals Connector (OSTI)

Abstract This paper presents an in silico optimisation methodology that simultaneously targets an optimal solvent as well as optimal process conditions for a pre-combustion carbon capture process. A mixed integer non-linear programming (MINLP) method is formulated to minimise the energy requirement for capturing and compressing carbon dioxide. The optimisation is founded on a Computer Aided Molecular Design (CAMD) framework and is firstly carried out to obtain an optimal pure solvent, while an optimal binary solvent blend is targeted through a second separate optimisation. When targeting a solvent blend, a 9% decrease in capture energy requirement is achieved with simultaneous optimisation of solvent and operating conditions over the case with operating conditions optimisation only. Moreover, a 2% decrease in energy requirement is achieved when a binary solvent mixture is optimised as opposed to a pure solvent.

Abdul Qadir; Matteo Chiesa; Ali Abbas

2014-01-01T23:59:59.000Z

294

Acid-Catalyzed Conversion of Xylose in 20 Solvents: Insight into Interactions of the Solvents with Xylose, Furfural, and the Acid Catalyst  

Science Journals Connector (OSTI)

In this study, the acid-catalyzed conversion of xylose to furfural was investigated in 20 solvents ranging from water, alcohol, ketones, furans, ethers, esters, hydrocarbons, and aromatics with the aim to understand their involvement in each step from ...Xylose can be converted to levulinic acid in iso-alcohols or to furfural in other solvents with very different yields.

Xun Hu; Roel J. M. Westerhof; Dehua Dong; Liping Wu; Chun-Zhu Li

2014-10-10T23:59:59.000Z

295

Understanding Partition Coefficient, Kd, Values Volume II: Review of Geochemistry and Available Kd Values for Cadmium, Cesium, Chromium, Lead, Plutonium, Radon, Strontium, Thorium, Tritium (3H), and Uranium  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Air and Radiation Air and Radiation EPA 402-R-99-004B Environmental Protection August 1999 Agency UNDERSTANDING VARIATION IN PARTITION COEFFICIENT, K d , VALUES Volume II: Review of Geochemistry and Available K d Values for Cadmium, Cesium, Chromium, Lead, Plutonium, Radon, Strontium, Thorium, Tritium ( 3 H), and Uranium UNDERSTANDING VARIATION IN PARTITION COEFFICIENT, K d , VALUES Volume II: Review of Geochemistry and Available K d Values for Cadmium, Cesium, Chromium, Lead, Plutonium, Radon, Strontium, Thorium, Tritium ( 3 H), and Uranium August 1999 A Cooperative Effort By: Office of Radiation and Indoor Air Office of Solid Waste and Emergency Response U.S. Environmental Protection Agency Washington, DC 20460 Office of Environmental Restoration U.S. Department of Energy Washington, DC 20585

296

Microwave generator  

DOE Patents [OSTI]

A microwave generator is provided for generating microwaves substantially from virtual cathode oscillation. Electrons are emitted from a cathode and accelerated to an anode which is spaced apart from the cathode. The anode has an annular slit there through effective to form the virtual cathode. The anode is at least one range thickness relative to electrons reflecting from the virtual cathode. A magnet is provided to produce an optimum magnetic field having the field strength effective to form an annular beam from the emitted electrons in substantial alignment with the annular anode slit. The magnetic field, however, does permit the reflected electrons to axially diverge from the annular beam. The reflected electrons are absorbed by the anode in returning to the real cathode, such that substantially no reflexing electrons occur. The resulting microwaves are produced with a single dominant mode and are substantially monochromatic relative to conventional virtual cathode microwave generators. 6 figs.

Kwan, T.J.T.; Snell, C.M.

1987-03-31T23:59:59.000Z

297

Models of the solvent-accessible surface of biopolymers  

SciTech Connect (OSTI)

Many biopolymers such as proteins, DNA, and RNA have been studied because they have important biomedical roles and may be good targets for therapeutic action in treating diseases. This report describes how plastic models of the solvent-accessible surface of biopolymers were made. Computer files containing sets of triangles were calculated, then used on a stereolithography machine to make the models. Small (2 in.) models were made to test whether the computer calculations were done correctly. Also, files of the type (.stl) required by any ISO 9001 rapid prototyping machine were written onto a CD-ROM for distribution to American companies.

Smith, R.E.

1996-09-01T23:59:59.000Z

298

Direct Measurement of Colloidal Forces in an Anisotropic Solvent  

Science Journals Connector (OSTI)

We present a new method to measure attractive interactions between colloidal particles, and determine the nature of the attraction between particles suspended in a nematic liquid crystal. We confine droplets filled with ferrofluid to a thin layer and apply a magnetic field to induce dipole moments that drive the droplets apart. When the field is removed, the attractive interactions pull the droplets back together. The force is determined from the velocity because the motion is viscously damped. We confirm the dipolar character of the interaction between droplets in a nematic solvent.

P. Poulin; V. Cabuil; D. A. Weitz

1997-12-15T23:59:59.000Z

299

A unified description of solvent effects in the helix-coil transition  

E-Print Network [OSTI]

We analyze the problem of the helix-coil transition in explicit solvents analytically by using spin-based models incorporating two different mechanisms of solvent action: explicit solvent action through the formation of solvent-polymer hydrogen bonds that can compete with the intrinsic intra-polymer hydrogen bonded configurations (competing interactions) and implicit solvent action, where the solvent-polymer interactions tune biopolymer configurations by changing the activity of the solvent (non-competing interactions). The overall spin Hamiltonian is comprised of three terms: the background \\emph{in vacuo} Hamiltonian of the "Generalized Model of Polypeptide Chain" type and two additive terms that account for the two above mechanisms of solvent action. We show that on this level the solvent degrees of freedom can be {\\sl explicitly} and {\\sl exactly} traced over, the ensuing effective partition function combining all the solvent effects in a unified framework. In this way we are able to address helix-coil transitions for polypeptides, proteins, and DNA, with different buffers and different external constraints. Our spin-based effective Hamiltonian is applicable for treatment of such diverse phenomena as cold denaturation, effects of osmotic pressure on the cold and warm denaturation, complicated temperature dependence of the hydrophobic effect as well as providing a conceptual base for understanding the behavior of Intrinsically Disordered Proteins and their analogues.

Artem Badasyan; Shushanik A. Tonoyan; Achille Giacometti; Rudolf Podgornik; V. Adrian Parsegian; Yevgeni Sh. Mamasakhlisov; Vladimir F. Morozov

2014-01-01T23:59:59.000Z

300

Removal of post-etch photoresist and sidewall residues using organic solvent and additive combined with physical forces  

Science Journals Connector (OSTI)

The effect of tetramethyl ammonium hydroxide (TMAH) used as additive in organic solvent (N-methyl pyrrolidone, NMP) on removal efficiency of post-etch photoresist was investigated on both blanket substrate and single damascene structures. In contrast to plasma ashing, photoresist removal using NMP/TMAH combined with megasonics showed no carbon depletion and no significant change in k-value. Mixing TMAH with NMP enhanced photoresist removal efficiency with respect to pure NMP. Photoresist removal using NMP/TMAH resulted in lower low-k capacitance (lower k-value) compared with that of plasma ashing process, due to the removal of the damaged layer generated during plasma etching. As a consequence of the removal of the damaged layer, a CD change was observed. The CD loss was estimated to be about 7 nm for 1% TMAH, and became negligible for 0.1% TMAH. Analysis of low-k sidewall using angle-resolved X-ray photoelectron spectroscopy showed that solvent mixture containing TMAH also removed sidewall residues generated by the etch plasma.

Q.T. Le; M. Claes; T. Conard; E. Kesters; M. Lux; G. Vereecke

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Ammoniated electron as a solvent stabilized multimer radical anion  

E-Print Network [OSTI]

The excess electron in liquid ammonia ("ammoniated electron") is commonly viewed as a cavity electron in which the s-type wave function fills the interstitial void between 6-9 ammonia molecules. Herewith an alternative model is examined in which the ammoniated electron is regarded as a solvent stabilized multimer radical anion, as was originally suggested by Symons [Chem. Soc. Rev. 1976, 5, 337]. In this model, most of the excess electron density resides in the frontier orbitals of N atoms in the ammonia molecules forming the solvation cavity; a fraction of this spin density is transferred to the molecules in the second solvation shell. The cavity is formed due to the repulsion between negatively charged solvent molecules. Using density functional theory calculations for small ammonia cluster anions in the gas phase, it is demonstrated that such core anions would quantitatively account for the observed pattern of Knight shifts for 1H and 14N nuclei as observed by NMR spectroscopy and the downshifted stretchin...

Shkrob, I A

2005-01-01T23:59:59.000Z

302

SWITCHABLE POLARITY SOLVENTS AS DRAW SOLUTES FOR FORWARD OSMOSIS  

SciTech Connect (OSTI)

Switchable polarity solvents (SPS), mixtures of carbon dioxide, water, and tertiary amines, are presented as viable forward osmosis (FO) draw solutes allowing a novel SPS FO process. In this study substantial osmotic strengths of SPS are measured with freezing point osmometry and were demonstrated to induce competitive ?uxes at high salt concentrations on a laboratory-scale FO unit utilizing a ?at sheet cellulose triacetate (CTA) membrane. Under the experimental conditions the SPS degrades the CTA membrane; however experiments with polyamide reverse osmosis (RO) membranes display stability towards SPS. Once the draw is diluted the major fraction of the switchable polarity solvent can be mechanically separated from the puri?ed water after polar to nonpolar phase shift induced by introduction of 1 atm carbon dioxide to 1 atm of air or nitrogen with mild heating. Trace amounts of SPS can be removed from the separated water with RO in a process that avoids solution concentration polarization. The separated nonpolar phase can be regenerated to a full strength draw and recycled with the re-addition of 1 atm of carbon dioxide.

Frederick F. Stewart; Mark L. Stone; Aaron D. Wilson; Cathy Rae

2013-03-01T23:59:59.000Z

303

Time-Dependent Implementation of Argonne’s Model for Universal Solvent Extraction  

Science Journals Connector (OSTI)

Time-Dependent Implementation of Argonne’s Model for Universal Solvent Extraction ... Chemical Sciences and Engineering, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, Illinois 60439, United States ... Argonne’s Model for Universal Solvent Extraction (AMUSE) simulates multistage counter-current solvent extraction processes for species of interest to spent nuclear fuel reprocessing; it is a model of a liquid–liquid extraction unit operation. ...

Kurt Frey; John F. Krebs; Candido Pereira

2012-09-04T23:59:59.000Z

304

Magnetocumulative generator  

DOE Patents [OSTI]

An improved magnetocumulative generator is described that is useful for producing magnetic fields of very high energy content over large spatial volumes. The polar directed pleated magnetocumulative generator has a housing providing a housing chamber with an electrically conducting surface. The chamber forms a coaxial system having a small radius portion and a large radius portion. When a magnetic field is injected into the chamber, from an external source, most of the magnetic flux associated therewith positions itself in the small radius portion. The propagation of an explosive detonation through high-explosive layers disposed adjacent to the housing causes a phased closure of the chamber which sweeps most of the magnetic flux into the large radius portion of the coaxial system. The energy content of the magnetic field is greatly increased by flux stretching as well as by flux compression. The energy enhanced magnetic field is utilized within the housing chamber itself.

Pettibone, J.S.; Wheeler, P.C.

1981-06-08T23:59:59.000Z

305

Monthly Generation System Peak (pbl/generation)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Generation > Generation Hydro Power Wind Power Monthly GSP BPA White Book Dry Year Tools Firstgov Monthly Generation System Peak (GSP) This site is no longer maintained. Page last...

306

Photon generator  

DOE Patents [OSTI]

A photon generator includes an electron gun for emitting an electron beam, a laser for emitting a laser beam, and an interaction ring wherein the laser beam repetitively collides with the electron beam for emitting a high energy photon beam therefrom in the exemplary form of x-rays. The interaction ring is a closed loop, sized and configured for circulating the electron beam with a period substantially equal to the period of the laser beam pulses for effecting repetitive collisions.

Srinivasan-Rao, Triveni (Shoreham, NY)

2002-01-01T23:59:59.000Z

307

The application of green chemistry and engineering to novel sustainable solvents and processes.  

E-Print Network [OSTI]

??The implementation of sustainable solvents and processes is critical to new developments in reducing environmental impact, improving net efficiency, and securing economic profitability in the… (more)

Marus, Gregory Alan

2011-01-01T23:59:59.000Z

308

Application of deep eutectic solvents and ionic liquids to hydrolase-catalyzed reactions.  

E-Print Network [OSTI]

??Hydrolases are important enzymes for stereoselective and environmentally benign synthesis. In nature, hydrolases cleave bonds with water. When used in organic solvents, these enzymes can… (more)

Gorke, Johnathan Thomas

2010-01-01T23:59:59.000Z

309

Development and application of novel solvents for sustainable reactions and separations.  

E-Print Network [OSTI]

??Environmentally benign alternatives for solvents and catalysts are essential for the development of sustainable chemical processes. Toward this end, we focused our research on the… (more)

Donaldson, Megan Elizabeth

2008-01-01T23:59:59.000Z

310

E-Print Network 3.0 - acid solvent extraction Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by the university, March 2006. HPLCAmino acid analyzer GC-MS Soy germination Danhua... green solvents), separation and identification (column ... Source: Brye, Kristofor R. -...

311

E-Print Network 3.0 - ash solvent extraction Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energy 4 The chemistry of minerals obtained from the combustion of Jordanian oil shale Summary: by solvent extraction of spent shale: experiment and kinetic analysis....

312

Solvent-induced forces in protein folding reflections on the protein folding problem  

Science Journals Connector (OSTI)

Abstract It is shown that the solvent induced forces on hydrophilic groups are the strongest ones. The relevance of this finding to protein folding is discussed.

Arieh Ben-Naim

2013-01-01T23:59:59.000Z

313

E-Print Network 3.0 - automated on-line solvent Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

is connected to an industrial project on solvent recovery in pharmaceutical production and fine- and ... Source: Skogestad, Sigurd - Department of Chemical Engineering,...

314

Solvent-vented injection in the analysis of agrochemicals by capillary supercritical fluid chromatography  

Science Journals Connector (OSTI)

Capillary supercritical fluid chromatography was performed with solvent-vented injection. Dilute samples of agrochemical mixtures were chromatographed and a study of detector response vs. quantity injected made.

S. Ashraf; K. D. Bartle; A. A. Clifford; I. L. Davies; R. Moulder

1990-12-01T23:59:59.000Z

315

Optimization of Cesium Removal from Hanford Envelope A Simulant with SuperLig 639 Ion Exchange Resin  

SciTech Connect (OSTI)

Hanford RadioactiveWaste materials have been categorized into four envelopes labeled A through D as specified in the Tank Waste Remediation Contract between BNFL and DOE. 1 Envelopes A, B and C contain only solubilized species and are specified as Low-Activity Waste (LAW). Each envelope is defined based on compositional maximums of chemical and radioactive constituents. Envelopes A and B contain low concentrations of organic species and the primary form of technetium is pertechnetate (TcO4-). Envelope C contains higher levels of organic species and technetium which is primarily in the nonpertechnetate form (presumably complexed TcO2). Envelope D is sludge which has been separated from the supernate and is referred to as High Activity Waste. The current plant design utilizes SuperLig ion exchange resins to remove cesium and technetium (the primary radioactive constituents) from the Hanford LAW. The process is designed to produce a decontaminated waste stream and a concentrated eluate waste stream for vitrification into low and high activity glasses, respectively.

King, W.D.

2000-07-27T23:59:59.000Z

316

CACI: The Cesium-137 Agricultural Commodities Irradiator. Final design report: Volume 7, Safety analysis, thermal analysis, and thermal testing  

SciTech Connect (OSTI)

This report provides a complete description of the final detailed design of the Cesium-137 Agricultural Commodities Irradiator (CACI). The design was developed and successfully completed by the Rocketdyne Division of Rockwell International for the US Department of Energy (DOE). The CACI project was initiated in April 1985 under DOE`s Byproducts Utilization Program, with the objectives of transferring food irradiation technology to the industry and thereby demonstrating a beneficial use for the 137 Cs nuclear by-product isotope. As designed, CACI will meet the intended requirements for research, development, and demonstration of irradiation processing of food. Further, as shown in the safety analyses performed during the project, the design conforms to all the safety and licensing requirements set forth for the project. The original scope of the CACI project included completion of its construction. However, the project was terminated for the convenience of the government during the final design phase in February 1986 for lack of a specific site. The CACI final design is described in eight volumes. This volume, Volume VII, describes Safety Analysis, Thermal Analysis, and Thermal Testing.

Not Available

1986-12-19T23:59:59.000Z

317

Adsorption and desorption kinetics of cesium in an organic matter-rich soil saturated with different cations  

SciTech Connect (OSTI)

The fallout from nuclear weapons tests conducted on Bikini Atoll Island in 1954 resulted in contamination of soil with Cesium 137. To develop effective regimes for decontaminating the Bikini Atoll soil, the exchange of Cs for K, Na, and other cations on the soil must be understood. Samples of soils made homoionic with K, Na, or Ca were reacted with solutions containing Cs ions, and the quantities of Cs sorbed and the rates of exchange were measured. The samples were then reacted with solutions containing K, Na, or Ca, and the quantities of Cs desorbed and the rates of exchange were again measured. Samples made homoionic with Na had a greater ion exchange capacity than samples made homoionic with K, and, in both cases, the ion exchange capacity increased with the organic matter content of the soil. For samples pretreated with Ca, the ion exchange capacity is not related in a simple way to the organic matter content. The kinetics were assessed by plotting the rate of exchange vs. the time and vs. the quantity exchanged. A first-order equation was obeyed during most of the run in Cs desorption experiments and during a limited part of the run in Cs adsorption experiments. An increase in the rate of Cs exchange was observed at the beginning of the experiments especially for Cs adsorption. This increase is presumably due to an increase of the ionic strength of the liquid phase during the exchange process. 33 refs., 9 figs., 2 tabs.

Aharoni, C. (Technion-Israel Inst. of Technology, Haifa (Israel)); Pasricha, N.S. (Punjab Agricultural Univ., Ludihana (India)); Sparks, D.L. (Univ. of Delaware, Newark, DE (United States))

1993-10-01T23:59:59.000Z

318

Process for preparing chemically modified micas for removal of cesium salts from aqueous solution  

DOE Patents [OSTI]

A chemically modified mica composite formed by heating a trioctahedral mica in an aqueous solution of sodium chloride having a concentration of at least 1 mole/liter at a temperature greater than 180 degrees Centigrade for at least 20 hours, thereby replacing exchangeable ions in the mica with sodium. Formation is accomplished at temperatures and pressures which are easily accessed by industrial equipment. The reagent employed is inexpensive and non-hazardous, and generates a precipitate which is readily separated from the modified mica.

Yates, Stephen Frederic (1539 S. Kennicott Dr., Arlington Heights, IL 60005); DeFilippi, Irene (208 E. Edgewood La., Palatine, IL 60067); Gaita, Romulus (6646 Davis Rd., Morton Grove, IL 60053); Clearfield, Abraham (Department of Chemistry, Texas A& M University, College Station, TX 77843); Bortun, Lyudmila (Department of Chemistry, Texas A& M University, College Station, TX 77843); Bortun, Anatoly (Department of Chemistry, Texas A& M University, College Station, TX 77843)

2000-09-05T23:59:59.000Z

319

New lignocellulose pretreatments using cellulose solvents: a review  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Received: Received: 7 September 2012 Accepted: 13 September 2012 Published online in Wiley Online Library: (wileyonlinelibrary.com) DOI 10.1002/jctb.3959 New lignocellulose pretreatments using cellulose solvents: a review Noppadon Sathitsuksanoh, a† Anthe George b,c and Y-H Percival Zhang a,d,e∗ Abstract Non-food lignocellulosic biomass is the most abundant renewable bioresource as a collectable, transportable, and storable chemical energy that is far from fully utilized. The goal of biomass pretreatment is to improve the enzymatic digestibility of pretreated lignocellulosic biomass. Many substrate factors, such as substrate accessibility, lignin content, particle size and so on, contribute to its recalcitrance. Cellulose accessibility to hydrolytic enzymes is believed to be the most important substrate characteristic limiting enzymatic hydrolysis. Cellulose

320

Solvent extraction of heptavalent technetium by tributyl phosphate  

SciTech Connect (OSTI)

The solvent extraction of heptavalent technetium from aqueous nitric or hydrochloric acid by tributyl phosphate in n-dodecane (TBP-NDD) has been studied over a wide range of TBP and acid concentrations at 25, 50, and 60/sup 0/C. The extraction was found to proceed according to the reaction 3TBP + H/sup +/ + TcO/sub 4//sup -/ ..-->.. (HTcO/sub 4/ 3TBP). A discussion of possible reaction mechanisms is presented, along with values for ..delta..G, ..delta..H, ..delta..S, and the equilibrium constant for the extraction reaction. Finally, evidence for the coextraction of technetium by uranyl ions is discussed. 10 figures, 5 tables.

Pruett, D.J.

1981-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Distribution of 1-butanol between organic solvent and acidic solution  

SciTech Connect (OSTI)

1-butanol, a major TBP-degraded product, is known to react explosively with concentrated nitric acid under non-heated conditions. However, no quantitative data is available on the distribution behavior in the Purex solution. The distribution of 1-butanol between tributyl phosphate(TBP) diluted with n-dodecane and aqueous solution of nitric acid and uranyl nitrate was investigated under various conditions, by changing the concentration of nitric acid, uranyl nitrate, the composition of the organic mixture, the organic to aqueous phase volume ratio, and temperature. 1-butanol was found to distribute more in solvent phase, but the distribution ratio is not large, less than four under typical Purex solution conditions. The ratio was found to be correlated with the molar concentration of free TBP and 1-butanol. Effects of these characteristics on safety in radiochemical plants will be discussed from the local accumulation of 1-butanol.

Asakura, T.; Nemoto, H.; Uchiyama, G. [Japan Atomic Energy Research Institute, Ibaraki-ken (Japan)] [and others

1995-12-01T23:59:59.000Z

322

Generation Technologies  

E-Print Network [OSTI]

Many local governments are using green power in their facilities and providing assistance to local businesses and residents to do the same. Green power is a subset of renewable energy that is produced with no GHG emissions, typically from solar, wind, geothermal, biogas, biomass, or low-impact small hydroelectric sources, includes three types of products: utility products (i.e., green power purchased from the utility through the electricity grid), renewable energy certificates (RECs), and on-site generation. Opportunities to purchase these products are increasing significantly, with annual green power market growth rates

Green Power

2005-01-01T23:59:59.000Z

323

Magnetocumulative generator  

DOE Patents [OSTI]

An improved magnetocumulative generator is described that is useful for producing magnetic fields of very high energy content over large spatial volumes. The polar directed pleated magnetocumulative generator has a housing (100, 101, 102, 103, 104, 105) providing a housing chamber (106) with an electrically conducting surface. The chamber (106) forms a coaxial system having a small radius portion and a large radius portion. When a magnetic field is injected into the chamber (106), from an external source, most of the magnetic flux associated therewith positions itself in the small radius portion. The propagation of an explosive detonation through high-explosive layers (107, 108) disposed adjacent to the housing causes a phased closure of the chamber (106) which sweeps most of the magnetic flux into the large radius portion of the coaxial system. The energy content of the magnetic field is greatly increased by flux stretching as well as by flux compression. The energy enhanced magnetic field is utilized within the housing chamber itself.

Pettibone, Joseph S. (Livermore, CA); Wheeler, Paul C. (Livermore, CA)

1983-01-01T23:59:59.000Z

324

Processing and analysis techniques involving in-vessel material generation  

DOE Patents [OSTI]

In at least one embodiment, the inventive technology relates to in-vessel generation of a material from a solution of interest as part of a processing and/or analysis operation. Preferred embodiments of the in-vessel material generation (e.g., in-vessel solid material generation) include precipitation; in certain embodiments, analysis and/or processing of the solution of interest may include dissolution of the material, perhaps as part of a successive dissolution protocol using solvents of increasing ability to dissolve. Applications include, but are by no means limited to estimation of a coking onset and solution (e.g., oil) fractionating.

Schabron, John F. (Laramie, WY); Rovani, Jr., Joseph F. (Laramie, WY)

2011-01-25T23:59:59.000Z

325

Processing and analysis techniques involving in-vessel material generation  

DOE Patents [OSTI]

In at least one embodiment, the inventive technology relates to in-vessel generation of a material from a solution of interest as part of a processing and/or analysis operation. Preferred embodiments of the in-vessel material generation (e.g., in-vessel solid material generation) include precipitation; in certain embodiments, analysis and/or processing of the solution of interest may include dissolution of the material, perhaps as part of a successive dissolution protocol using solvents of increasing ability to dissolve. Applications include, but are by no means limited to estimation of a coking onset and solution (e.g., oil) fractionating.

Schabron, John F. (Laramie, WY); Rovani, Jr., Joseph F. (Laramie, WY)

2012-09-25T23:59:59.000Z

326

Self-assembly of surfactants in a supercritical solvent from lattice Monte Carlo simulations  

E-Print Network [OSTI]

Self-assembly of surfactants in a supercritical solvent from lattice Monte Carlo simulations Martin self-assembly of surfactants in a supercritical solvent by large-scale Monte Carlo simulations. CarbonCO2.3 Surfactant molecules used in scCO2 have two mutually incompatible components: a CO2-philic tail

Lisal, Martin

327

Solvent-free microwave extraction of bioactive compounds provides a tool for green analytical chemistry  

Science Journals Connector (OSTI)

Abstract We present an overview on solvent-free microwave-extraction techniques of bioactive compounds from natural products. This new technique is based on the concept of green analytical chemistry. It has proved to be an alternative to other techniques with the advantages of reducing extraction times, energy consumption, solvent use and CO2 emissions.

Ying Li; Anne Sylvie Fabiano-Tixier; Maryline Abert Vian; Farid Chemat

2013-01-01T23:59:59.000Z

328

Solvent quality influence on the dielectric properties of polyelectrolyte solutions: A scaling approach  

Science Journals Connector (OSTI)

The dielectric properties of polyelectrolytes in solvent of different quality have been measured in an extended frequency range and the dielectric parameters associated with the polarization induced by counterion fluctuation over some peculiar polyion lengths have been evaluated. Following the scaling theory of polyelectrolyte solutions and the recent models developed by Dobrynin and Rubinstein that explicitly take into account the quality of the solvent on the polyion chain conformation, we have reviewed and summarized a set of scaling laws that describe the dielectric behavior of these systems in the dilute and semidilute regime. Moreover, for poorer solvents, where theory of hydrophobic polyelectrolytes predicts, and computer simulation confirms, a particular chain structure consisting of partially collapsed monomers (beads) connected by monomer strings, we derived a scaling law. These predictions are compared with the results obtained from the dielectric parameters (the dielectric increment ?? and the relaxation time ?ion) of the “intermediate” frequency relaxation of two partially charged polymers, which possess a carbon-based backbone for which water is a poor solvent and ethylene glycol is a good solvent. By varying the solvent composition (a water-ethylene glycol mixture), we have tuned the quality of the solvent, passing from poor to good condition and have observed the predicted scaling for all the systems investigated. These findings give a further support to the scaling theory of polyelectrolyte solutions and to the necklace model for hydrophobic polyelectrolytes in poor solvents.

F. Bordi; C. Cametti; T. Gili; S. Sennato; S. Zuzzi; S. Dou; R. H. Colby

2005-09-16T23:59:59.000Z

329

Artificial Neural Network Approach to Predict the Solubility of C60 in Various Solvents  

Science Journals Connector (OSTI)

Artificial Neural Network Approach to Predict the Solubility of C60 in Various Solvents ... Kohonen ANNs have been widely applied to map a multidimensional parameter space to a two-dimensional array of neurons. ... Therefore, provided that proper molecular parameters were chosen, if two solvents are mapped onto the same (or nearby) neuron the solubility should be close in them. ...

István Z. Kiss; Géza Mándi; Mihály T. Beck

2000-08-03T23:59:59.000Z

330

Collapse of a semiflexible polymer in poor solvent Alberto Montesi,1,2  

E-Print Network [OSTI]

with a bead-stiff spring model with excluded volume interaction, bending stiffness, and exponentially decaying and with a phantom bead-spring chain. Finally, we show preliminary results on how steady shear flow influences. This effect leads to a swollen coil conformation for flexible polymers in good solvent. In poor solvent, con

MacKintosh, F.C.

331

Hydrophobic Aided Replica Exchange: an Efficient Algorithm for Protein Folding in Explicit Solvent  

E-Print Network [OSTI]

Hydrophobic Aided Replica Exchange: an Efficient Algorithm for Protein Folding in Explicit Solvent protein folding in explicit solvent. This method is based on exaggerating the hydrophobic effect understanding of protein folding and misfolding is critical to many problems in computational biology.1 Many

Berne, Bruce J.

332

Improving the quality of deteriorated recycle solvents. Quarterly report, August 1982-November 1982  

SciTech Connect (OSTI)

The overall objective of this work is to identify reasons for solvent degeneration and to determine a feasible mechanism whereby coal-liquefaction processes can be modified to inhibit solvent degradation during the liquefaction process. In this work, the response in product distribution (or oil yield) to different pre-treatment methods was investigated. In related past works, solvent quality was based solely on the amount of standard coal conversion. In this work, solvent quality was also determined with the use of a standard product separation procedure. A brief discussion of related past works is followed up by a discussion of current work in the area of upgrading deteriorated recycle solvents. The effect of solvent pre-treatment on quality during thermal (non-catalytic) and catalytic liquefaction of coal was examined, and a comparison was made. In addition, the effect of the presence of typical compounds found in coal liquids (e.g. pyrene), during solvent pre-treatment, on solvent quality was also investigated. 2 references, 3 figures, 5 tables.

Tarrer, A.R.; Guin, J.A.; Curtis, C.W.

1982-01-01T23:59:59.000Z

333

Biogass Generator  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Another internet tool by: Another internet tool by: Build Your Own Page 1 of 5 Teach...build...learn...renewable energy! Biogas Generator A Renewable Energy Project Kit The Pembina Institute What Is Biogas? Biogas is actually a mixture of gases, usually carbon dioxide and methane. It is produced by a few kinds of microorganisms, usually when air or oxygen is absent. (The absence of oxygen is called "anaerobic conditions.") Animals that eat a lot of plant material, particularly grazing animals such as cattle, produce large amounts of biogas. The biogas is produced not by the cow or elephant, but by billions of microor- ganisms living in its digestive system. Biogas also develops in bogs and at the bottom of lakes, where decaying organic matter builds up under wet and

334

Modeling morphology evolution during solvent-based fabrication of organic solar cells  

E-Print Network [OSTI]

Solvent-based techniques usually involve preparing dilute blends of electron-donor and electron-acceptor materials dissolved in a volatile solvent. After some form of coating onto a substrate, the solvent evaporates. An initially homogeneous mixture separates into electron-acceptor rich and electron-donor rich regions as the solvent evaporates. Depending on the specifics of the blend and processing conditions different morphologies are typically formed. Experimental evidence consistently confirms that the morphology critically affects device performance. A computational framework that can predict morphology evolution can significantly augment experimental analysis. Such a framework will also allow high throughput analysis of the large phase space of processing parameters, thus yielding insight into the process-structure-property relationships. In this paper, we formulate a computational framework to predict evolution of morphology during solvent-based fabrication of organic thin films. This is accomplished by...

Wodo, Olga

2011-01-01T23:59:59.000Z

335

Water-enhanced solubility of carboxylic acids in organic solvents and its applications to extraction processes  

SciTech Connect (OSTI)

The solubilities of carboxylic acids in certain organic solvents increase remarkably with an increasing amount of water in the organic phase. This phenomenon leads to a novel extract regeneration process in which the co-extracted water is selectively removed from an extract, and the carboxylic acid precipitates. This approach is potentially advantageous compared to other regeneration processes because it removes a minor component of the extract in order to achieve a large recovery of acid from the extract. Carboxylic acids of interest include adipic acid, fumaric acid, and succinic acid because of their low to moderate solubilities in organic solvents. Solvents were screened for an increase in acid solubility with increased water concentration in the organic phase. Most Lewis-base solvents were found to exhibit this increased solubility phenomena. Solvents that have a carbonyl functional group showed a very large increase in acid solubility. 71 refs., 52 figs., 38 tabs.

Starr, J.N.; King, C.J.

1991-11-01T23:59:59.000Z

336

Explicit Solvent Simulations of Friction between Brush Layers of Charged and Neutral Bottle-Brush Macromolecules  

SciTech Connect (OSTI)

We study friction between charged and neutral brush layers of bottle-brush macromolecules using molecular dynamics simulations. In our simulations the solvent molecules were treated explicitly. The deformation of the bottle-brush macromolecules under the shear were studied as a function of the substrate separation and shear stress. For charged bottle-brush layers we study effect of the added salt on the brush lubricating properties to elucidate factors responsible for energy dissipation in charged and neutral brush systems. Our simulations have shown that for both charged and neutral brush systems the main deformation mode of the bottle-brush macromolecule is associated with the backbone deformation. This deformation mode manifests itself in the backbone deformation ratio, , and shear viscosity, , to be universal functions of the Weissenberg number W. The value of the friction coefficient, , and viscosity, , are larger for the charged bottle-brush coatings in comparison with those for neutral brushes at the same separation distance, D, between substrates. The additional energy dissipation generated by brush sliding in charged bottle-brush systems is due to electrostatic coupling between bottle-brush and counterion motion. This coupling weakens as salt concentration, cs, increases resulting in values of the viscosity, , and friction coefficient, , approaching corresponding values obtained for neutral brush systems.

Carrillo, Jan-Michael [University of Connecticut] [University of Connecticut; Brown, W Michael [ORNL] [ORNL; Dobrynin, Andrey [University of Connecticut] [University of Connecticut

2012-01-01T23:59:59.000Z

337

In situ nitrogen generation removes wax from flowlines  

SciTech Connect (OSTI)

Formation of paraffin (wax) in cold deepwater flowlines is a major problem for offshore operators of such facilities. Petrobras faces this problem continuously in its deepwater operations in the Campos basin, offshore Brazil. Since 1990, through its Petrobras Research Center (CENPES), the company has developed, extensively field tested, and recently commercialized, a novel technique for chemically removing such wax depositions. The process involves mixing and introducing to the line, two inorganic salts and organic solvents. The ensuing chemical reaction--which both generates nitrogen and heats the inside of the blocked flowline--allows the solvent to dissolve and dislodge the buildup, which is then flushed from the line. The process is called the Nitrogen Generation System (SGN). Petrobras/CENPES has recently formed a joint venture with the Brazilian service company Maritima Navegacao e Engenharia Ltda. to offer SGN services worldwide.

Khalil, C.N. [Petrobras S.A., Rio de Janeiro (Brazil)

1996-07-01T23:59:59.000Z

338

PHASE BEHAVIOR OF LIGHT GASES IN HYDROCARBON AND AQUEOUS SOLVENTS  

SciTech Connect (OSTI)

Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present period, the Park-Gasem-Robinson (PGR) equation of state (EOS) has been modified to improve its volumetric and equilibrium predictions. Specifically, the attractive term of the PGR equation was modified to enhance the flexibility of the model, and a new expression was developed for the temperature dependence of the attractive term in this segment-segment interaction model. The predictive capability of the modified PGR EOS for vapor pressure, and saturated liquid and vapor densities was evaluated for selected normal paraffins, normal alkenes, cyclo-paraffins, light aromatics, argon, carbon dioxide and water. The generalized EOS constants and substance-specific characteristic parameters in the modified PGR EOS were obtained from the pure component vapor pressures, and saturated liquid and vapor molar volumes. The calculated phase properties were compared to those of the Peng-Robinson (PR), the simplified-perturbed-hard-chain theory (SPHCT) and the original PGR equations. Generally, the performance of the proposed EOS was better than the PR, SPHCT and original PGR equations in predicting the pure fluid properties (%AAD of 1.3, 2.8 and 3.7 for vapor pressure, saturated liquid and vapor densities, respectively).

KHALED A.M. GASEM; ROBERT L. ROBINSON, JR.

1998-08-31T23:59:59.000Z

339

Thermoelectric generator  

SciTech Connect (OSTI)

A thermoelectric generator unit is described comprising: a hot side heat exchanger including a plate having extruded retention posts projecting from one surface of the plate, and fins adapted for contact with a heating source. The fins are positioned between two of the retention posts. Retention rods are inserted between the retention posts and the base of the fins to retain the fin in thermal contact with the plate surface upon insertion of the retention rod between the engaging surface of the post and the corresponding fin. Thermoelectric semi-conductor modules are in thermal contact with the opposite side of the hot side heat exchanger plate from the contact with the fins. The modules are arranged in a grid pattern so that heat flow is directed into each of the modules from the hot side heat exchanger. The modules are connected electrically so as to combine their electrical output; and a cold side heat exchanger is in thermal contact with the modules acting as a heat sink on the opposite side of the module from the hot side heat exchanger plate so as to produce a thermal gradient across the modules.

Shakun, W.; Bearden, J.H.; Henderson, D.R.

1988-03-29T23:59:59.000Z

340

A comparative study on the stability and structure of two different green fluorescent proteins in organic co-solvent systems  

Science Journals Connector (OSTI)

Green fluorescent protein (GFP) has been used ... requires the stability of GFP in organic co-solvent systems. This prompted us to examine the ... stability, under a range of organic co-solvent systems. n-GFP and...

Govindan Raghunathan; Sriram Sokalingam…

2013-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Environmentally preferable solvents promoted resolution of multi-component mixtures of amino acids: an approach to perform green chromatography  

Science Journals Connector (OSTI)

Solvents being important components of chemical reactions and...2007). The toxic organic solvents used in any chemical process if released ... the quality of environment. Therefore, the term green chemistry came ...

Ali Mohammad; Asma Siddiq…

2013-08-01T23:59:59.000Z

342

Solvent extraction of rare-earth metals by carboxylic acids  

SciTech Connect (OSTI)

The solvent extraction of the trivalent lanthanides and yttrium from nitrate media by solutions of carboxylic acids in xylene has been studied. Commercially available carboxylic acids such as Versatic 10 and naphthenic acids were used, as well as model compounds of known structure, such as 2-ethylhexanoic and 3-cyclohexylpropanoic acids. In a few cases, extraction of the metals from sulphate and chloride solutions was also investigated. The dependence of the extraction properties of the carboxylic acids on the atomic number of the lanthanide shows a definite relationship to the steric bulk of the carboxylic acid molecule quantified by means of the steric parameter, E{sub s}{prime} of the substituent alkyl group. The stoichiometries of the extracted complexes for representative light (La), middle (Gd) and heavy (Lu) rare-earth metals were investigated by the slope-analysis technique for a sterically hindered acid (Versatic 10 acid; -E{prime}{sub s} = 3.83) and an acid with low steric hindrance (3-cyclohexylpropanoic acid; -E{prime}{sub s} = 0.28). 14 refs., 13 figs., 3 tabs.

Preez, A.C. du; Preston, J.S. [Mintek, Randburg (South Africa)

1992-04-01T23:59:59.000Z

343

Solvent extraction of oil shale or tar sands  

SciTech Connect (OSTI)

Oil shales or tar sands are extracted under non-thermally destructive conditions with a solvent liquid containing a compound having the general formula: R(N)-M(=O)(-R1)-N(-R2)-R3 where M is a carbon, sulfur or phosphorus atom, R/sup 2/ and R/sup 3/ are each a hydrogen atom or a lowe alkyl group, R and R/sup 1/ are each a lower alkyl group, another -N(-R2)-R3 group, a monocyclic arom group, or R/sup 1/ can be another -N(-R3)-M(=O)(-R1)-R(N) group or R/sup 1/ and R/sup 2/ together can represent the atoms necessary to close a heterocyclic ring, and n=1 where M=phosphorus and is otherwise 0, to substantially remove the non-fixed carbon content of the oil shale or tar sands, leaving a solid residue of fixed carbon, ash minerals, and non-extractable matter.

Stiller, A.H.; Hammack, R.W.; Sears, J.T.

1983-08-02T23:59:59.000Z

344

Organic solvent soluble oxide supported hydrogenation catalyst precursors  

DOE Patents [OSTI]

The present invention discloses two polyoxoanion supported metal complexes found to be useful in olefin hydrogenation. The complexes are novel compositions of matter which are soluble in organic solvents. In particular, the compositions of matter comprise A.sub.x [L.sub.n Ir.sup.(I) .multidot.X.sub.2 M.sub.15 M'.sub.3 O.sub.62 ].sup.x- and A.sub.y [L.sub.n Ir.sup.(I) .multidot.X.sub.2 M.sub.9 M'.sub.3 O.sub.40 ].sup.y- where L is a ligand preferably chosen from 1,5-cyclooctadiene (COD), ethylene, cyclooctene, norbornadiene and other olefinic ligands; n=1 or 2 depending upon the number of double bonds present in the ligand L; X is a "hetero" atom chosen from B, Si, Ge, P, As, Se, Te, I, Co, Mn and Cu; M is either W or Mo; M' is preferably Nb or V but Ti, Zr, Ta, Hf are also useful; and A is a countercation preferably selected from tetrabutyl ammonium and alkali metal ions.

Edlund, David J. (Bend, OR); Finke, Richard G. (Eugene, OR); Saxton, Robert J. (Sunnyvale, CA)

1992-01-01T23:59:59.000Z

345

Solvent refined coal process: operation of the solvent refined coal pilot plant, Wilsonville, Alabama. First quarter report, January-March 1981  

SciTech Connect (OSTI)

This report summarizes the operating conditions and test results obtained during the first quarter of 1981 at the six ton per day solvent refined coal (SRC-I) pilot plant in Wilsonville, Alabama. The plant operated for approximately two-thirds of the period with a scheduled shutdown, from 22 February to 17 March, accounting for most of the downtime. Kentucky 9 coal from the Fies mine was processed throughout the period. The following potential process improvements and tests were evaluated in the respective process units. SRC Unit: Low severity run tests to evaluate SRC reactor conditions for two-stage liquefaction; process solvent quality studies while simulating demonstration plant conditions with low quality process solvent (anthracene oil); operation of the new, reduced volume and residence time, V103 High Pressure Separator; Evaluation of the hot separator mode of operation; and adjustment of the T102 Vacuum Column operation to determine if it can produce a combined trays 3 and 8 stream that would be an acceptable process solvent (95% boiling at over 450/sup 0/F). CSD Unit: Steam stripping of SRC and LSRC to reduce product-related DAS losses; and ambient and cryogenic SRC sampling comparisons for DAS determination tests. Pressure checking of the hydrotreater unit was completed, and the Dowtherm system was placed in service. Solvent circulation was initiated in the unit as efforts continued to verify equipment performance.

Lewis, H.E.

1981-01-01T23:59:59.000Z

346

PAPER www.rsc.org/greenchem | Green Chemistry Carbonates: eco-friendly solvents for palladium-catalysed direct arylation  

E-Print Network [OSTI]

PAPER www.rsc.org/greenchem | Green Chemistry Carbonates: eco-friendly solvents for palladium of heteroaromatics with aryl halides proceed in moderate to good yields using the eco-friendly solvents carbonates using Pd(PPh3)4 as the catalyst and DMAc as the solvent.2 Since these exciting results, the palladium

Paris-Sud XI, Université de

347

Extractive stripping of inert-rich hydrocarbon gases with a preferential physical solvent  

SciTech Connect (OSTI)

A process is described for treating a natural gas stream containing methane, heavier hydrocarbons, and an inert gas, an improvement comprising: selectivity extracting natural gas liquids from the natural gas stream with a preferential physical solvent which provides selective capability for recovery according to the selected degree of: (a) ethane in amounts ranging from 2-98%, (b) propane in amounts ranging from 2-99%, (c) butanes in amounts ranging from 2-100%, or (d) pentanes and higher molecular weight hydrocarbons in amounts ranging up to 100%, the improvement comprising the following steps: A. selecting the preferential physical solvent which is selective for ethane and heavier hydrocarbon components of the gas stream such that: (1) relative volatility of methane over ethane is at least 5.0 and the hydrocarbon loading capacity, defined as solubility of ethane in the solvent, is at least 0.25 standard cubic feet of ethane per gallon of the solvent, or (2) the preferential factor, determined by the multiplication of relative volatility of methane over ethane by the solubility of ethane in solvent, in standard cubic feet of ethane per gallon of solvent, is at least 1.25; B. selectively extracting and stripping the natural gas stream with the physical solvent to produce an inert gas stream and a rich solvent stream containing methane and the hydrocarbons heavier than methane; and C. distilling the rich solvent stream to produce a stream vent to form a solution having a molar ratio of silicon alkoxide to water in the range of about 1 to about 10.

Mehra, Y.R.

1987-07-14T23:59:59.000Z

348

Introduction Minimal generation  

E-Print Network [OSTI]

Introduction Minimal generation Random generation Minimal and probabilistic generation of finite generation of finite groups #12;Introduction Minimal generation Random generation Some motivation Let x1 random elements of G = x1, . . . , xk . (G is the group generated by x1, . . . , xk : all possible

St Andrews, University of

349

Automated apparatus for solvent separation of a coal liquefaction product stream  

SciTech Connect (OSTI)

An automated apparatus for the solvent separation of a coal liquefaction product stream that operates continuously and unattended and eliminates potential errors resulting from subjectivity and the aging of the sample during analysis. In use of the apparatus, metered amounts of one or more solvents are passed sequentially through a filter containing the sample under the direction of a microprocessor control means. The mixture in the filter is agitated by means of ultrasonic cavitation for a timed period and the filtrate is collected. The filtrate of each solvent extraction is collected individually and the residue on the filter element is collected to complete the extraction process.

Schweighardt, F.K.

1985-01-08T23:59:59.000Z

350

Removing oxygen from a solvent extractant in an uranium recovery process  

DOE Patents [OSTI]

An improvement in effecting uranium recovery from phosphoric acid solutions is provided by sparging dissolved oxygen contained in solutions and solvents used in a reductive stripping stage with an effective volume of a nonoxidizing gas before the introduction of the solutions and solvents into the stage. Effective volumes of nonoxidizing gases, selected from the group consisting of argon, carbon dioxide, carbon monoxide, helium, hydrogen, nitrogen, sulfur dioxide, and mixtures thereof, displace oxygen from the solutions and solvents thereby reduce deleterious effects of oxygen such as excessive consumption of elemental or ferrous and accumulation of complex iron phosphates or cruds.

Hurst, Fred J. (Oak Ridge, TN); Brown, Gilbert M. (Knoxville, TN); Posey, Franz A. (Concord, TN)

1984-01-01T23:59:59.000Z

351

Optimized Solvent for Energy-Efficient, Environmentally-Friendly Capture of CO{sub 2} at Coal-Fired Power Plants  

SciTech Connect (OSTI)

The overall goal of this project, as originally proposed, was to optimize the formulation of a novel solvent as a critical enabler for the cost-effective, energy-efficient, environmentally-friendly capture of CO{sub 2} at coal-fired utility plants. Aqueous blends of concentrated piperazine (PZ) with other compounds had been shown to exhibit high rates of CO{sub 2} absorption, low regeneration energy, and other desirable performance characteristics during an earlier 5-year development program conducted by B&W. The specific objective of this project was to identify PZ-based solvent formulations that globally optimize the performance of coal-fired power plants equipped with CO{sub 2} scrubbing systems. While previous solvent development studies have tended to focus on energy consumption and absorber size, important issues to be sure, the current work seeks to explore, understand, and optimize solvent formulation across the full gamut of issues related to commercial application of the technology: capital and operating costs, operability, reliability, environmental, health and safety (EH&S), etc. Work on the project was intended to be performed under four budget periods. The objective of the work in the first budget period has been to identify several candidate formulations of a concentrated PZ-based solvent for detailed characterization and evaluation. Work in the second budget period would generate reliable and comprehensive property and performance data for the identified formulations. Work in the third budget period would quantify the expected performance of the selected formulations in a commercial CO{sub 2} scrubbing process. Finally, work in the fourth budget period would provide a final technology feasibility study and a preliminary technology EH&S assessment. Due to other business priorities, however, B&W has requested that this project be terminated at the end of the first budget period. This document therefore serves as the final report for this project. It is the first volume of the two-volume final report and summarizes Budget Period 1 accomplishments under Tasks 1-5 of the project, including the selection of four solvent formulations for further study.

Farthing, G. A.; Rimpf, L. M.

2014-04-30T23:59:59.000Z

352

RESULTS OF IONSIV® IE-95 STUDIES FOR THE REMOVAL OF RADIOACTIVE CESIUM FROM K-EAST BASIN SPENT NUCLEAR FUEL POOL DURING DECOMMISSIONING ACTIVITIES  

SciTech Connect (OSTI)

This report delineates the results obtained from laboratory testing of IONISIV{reg_sign} IE-95 to determine the efficacy of the zeolite for the removal of radioactive cesium from the KE Basin water prior to transport to the Effluent Treatment Facility, as described in RPP-PLAN-36158, IONSIV{reg_sign} IE-95 Studies for the removal of Radioactive Cesium from KE Basin Spent Nuclear Fuel Pool during Decommissioning Activities. The spent nuclear fuel was removed from KE Basin and the remaining sludge was layered with a grout mixture consisting of 26% Lehigh Type I/II portland cement and 74% Boral Mohave type F fly ash with a water-to-cement ratio of 0.43. The first grout pour was added to the basin floor to a depth of approximately 14 in. covering an area of 12,000 square feet. A grout layer was also added to the sludge containers located in the attached Weasel and Technical View pits.

DUNCAN JB; BURKE SP

2008-07-07T23:59:59.000Z

353

PHASE BEHAVIOR OF LIGHT GASES IN HYDROGEN AND AQUEOUS SOLVENTS  

SciTech Connect (OSTI)

Under previous support from the US Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, the solubilities of hydrogen in n-hexane, carbon monoxide in cyclohexane, and nitrogen in phenanthrene and pyrene were measured using a static equilibrium cell over the temperature range from 344.3 to 433.2 K and pressures to 22.8 MPa. The uncertainty in these new solubility measurements is estimated to be less than 0.001 in mole fraction. The data were analyzed using the Peng-Robinson (PR) equation of state (EOS). In general, the PR EOS represents the experimental data well when a single interaction parameter (C{sub ij}) is used for each isotherm. In addition, the predictive capability of the modified Park-Gasem-Robinson (PGR) equation of state (EOS) was evaluated for selected carbon dioxide + normal paraffins, ethane + normal paraffins, and hydrogen + normal paraffins. A set of mixing rules was proposed for the modified EOS to extend its predictive capabilities to mixtures. The predicted bubble point pressures for the ethane + n-paraffin and carbon dioxide + n-paraffin binaries were compared to those of the Peng-Robinson (PR), simplified-perturbed-hard-chain theory (SPHCT) and original PGR equations. The predictive capability of the proposed equation is better or comparable to the PR, SPHCT and original PGR equations of state for the ethane binaries (%AAD of 1.9) and carbon dioxide binaries (%AAD of 2.0). For the hydrogen binaries, the modified PGR EOS showed much better performance (%AAD of 1.7) than the original PGR equation and comparable to the PR equation.

KHALED A.M. GASEM; ROBERT L. ROBINSON, JR.

1999-03-31T23:59:59.000Z

354

Solvent-mediated repair and patterning of surfaces by AFM  

SciTech Connect (OSTI)

A tip-based approach to shaping surfaces of soluble materials with nanometer-scale control is reported. The proposed method can be used, for example, to eliminate defects and inhomogeneities in surface shape, repair mechanical or laser-induced damage to surfaces, or perform 3D lithography on the length scale of an AFM tip. The phenomenon that enables smoothing and repair of surfaces is based on the transport of material from regions of high- to low-curvature within the solution meniscus formed in a solvent-containing atmosphere between the surface in question and an AFM tip scanned over the surface. Using in situ AFM measurements of the kinetics of surface remodeling on KDP (KH{sub 2}PO{sub 4}) crystals in humid air, we show that redistribution of solute material during relaxation of grooves and mounds is driven by a reduction in surface free energy as described by the Gibbs-Thomson law. We find that the perturbation from a flat interface evolves according to the diffusion equation where the effective diffusivity is determined by the product of the surface stiffness and the step kinetic coefficient. We also show that, surprisingly, if the tip is instead scanned over or kept stationary above an atomically flat area of the surface, a convex structure is formed with a diameter that is controlled by the dimensions of the meniscus, indicating that the presence of the tip and meniscus reduces the substrate chemical potential beneath that of the free surface. This allows one to create nanometer-scale 3D structures of arbitrary shape without the removal of substrate material or the use of extrinsic masks or chemical compounds. Potential applications of these tip-based phenomena are discussed.

Elhadj, S; Chernov, A; De Yoreo, J

2007-10-30T23:59:59.000Z

355

Evidence for Complex Molecular Architectures for Solvent-Extracted Lignins  

SciTech Connect (OSTI)

Lignin, an abundant, naturally occurring biopolymer, is often considered 'waste' and used as a simple fuel source in the paper-making process. However, lignin has emerged as a promising renewable resource for engineering materials, such as carbon fibers. Unfortunately, the molecular architecture of lignin (in vivo and extracted) is still elusive, with numerous conflicting reports in the literature, and knowledge of this structure is extremely important, not only for materials technologies, but also for production of biofuels such as cellulosic ethanol due to biomass recalcitrance. As such, the molecular structures of solvent-extracted (sulfur-free) lignins, which have been modified using various acyl chlorides, have been probed using small-angle X-ray (SAXS) and neutron (SANS) scattering in tetrahydrofuran (THF) solution along with hydrodynamic characterization using dilute solution viscometry and gel permeation chromatography (GPC) in THF. Mass spectrometry shows an absolute molecular weight {approx}18-30 kDa ({approx}80-140 monomers), while GPC shows a relative molecular weight {approx}3 kDa. A linear styrene oligomer (2.5 kDa) was also analyzed in THF using SANS. Results clearly show that lignin molecular architectures are somewhat rigid and complex, ranging from nanogels to hyperbranched macromolecules, not linear oligomers or physical assemblies of oligomers, which is consistent with previously proposed delignification (extraction) mechanisms. Future characterization using the methods discussed here can be used to guide extraction processes as well as genetic engineering technologies to convert lignin into value added materials with the potential for high positive impact on global sustainability.

Rials, Timothy G [ORNL; Urban, Volker S [ORNL; Langan, Paul [Los Alamos National Laboratory (LANL)

2012-01-01T23:59:59.000Z

356

Solvent Effects and Bioconcentration Patterns of Antimicrobial Compounds in Wetland Plants.  

E-Print Network [OSTI]

??This study looked at effects of organic solvents dimethylsulfoxide, dimethylformamide and acetone at 0.01%, 0.05% and 0.1% concentration on germination and seedling development wetland plants.… (more)

Adhikari, Sajag

2011-01-01T23:59:59.000Z

357

Method for sizing and desizing yarns with liquid and supercritical carbon dioxide solvent  

DOE Patents [OSTI]

Disclosed is a method of sizing and desizing yarn, or more specifically to a method of coating yarn with size and removing size from yarn with liquid carbon dioxide solvent. 3 figs.

Fulton, J.L.; Yonker, C.R.; Hallen, R.R.; Baker, E.G.; Bowman, L.E.; Silva, L.J.

1999-01-26T23:59:59.000Z

358

Sodalite ion exchange in polyethylene oxide oligomer solvents Gina M. Canfield,a  

E-Print Network [OSTI]

Sodalite ion exchange in polyethylene oxide oligomer solvents Gina M. Canfield,a Michael Bizimisb and rare earth ions. Ethylene oxide-based oligomers (polyethylene glycol, polyethylene glycol methyl ether

Latturner, Susan

359

DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS  

SciTech Connect (OSTI)

The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the development of carbon electrodes for Direct Carbon Fuel Cells (DCFC), and on carbon foam composites used in ballistic armor, as well as the hydrotreatment of solvents used in the basic solvent extraction process. A major goal is the production of 1500 pounds of binder pitch, corresponding to about 3000 pounds of hydrotreated solvent.

Elliot B. Kennel; Quentin C. Berg; Stephen P. Carpenter; Dady Dadyburjor; Jason C. Hissam; Manoj Katakdaunde; Liviu Magean; Abha Saddawi; Alfred H. Stiller; John W. Zondlo

2006-03-07T23:59:59.000Z

360

Molecular insights on the solvent effect of methanol additive in glycine polymorph selection  

E-Print Network [OSTI]

In an effort to improve control and design in organic crystallization, the effect of solvent on polymorph selection has gained tremendous interest in recent years. In this thesis, molecular simulation techniques are used ...

Patala, Srikanth

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

E-Print Network 3.0 - accelerated solvent extraction Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

17 ACADEMIE D'AIX-MARSEILLE UNIVERSITE D'AVIGNON ET DES PAYS DE VAUCLUSE Summary: : Optimising solvent free microwave extraction method Zill-e-HUMA, Maryline ABERT-VIAN, Jean...

362

Solvent effects on the electronic state of monolignol radicals as predicted by molecular orbital calculations  

Science Journals Connector (OSTI)

The spin and charge densities in three monolignol radicals were computed using the UB3LYP/6-31G* method of molecular orbital calculation. As well, the effects of solvents were simulated by using an SCI-PCM mod...

Mikiji Shigematsu; Hiroshi Masamoto

2008-08-01T23:59:59.000Z

363

A Polarizable QM/MM Explicit Solvent Model for Computational Electrochemistry in Water  

E-Print Network [OSTI]

We present a quantum mechanical/molecular mechanical (QM/MM) explicit solvent model for the computation of standard reduction potentials E[subscript 0]. The QM/MM model uses density functional theory (DFT) to model the ...

Wang, Lee-Ping

364

VOLUME 80, NUMBER 9 P H Y S I C A L R E V I E W L E T T E R S 2 MARCH 1998 Giant Spin Relaxation of an Ultracold Cesium Gas  

E-Print Network [OSTI]

of attention. The atomic sample is spin polarized and confined in a mag- netic trap. The condensation of an Ultracold Cesium Gas J. Söding, D. Guéry-Odelin, P. Desbiolles, G. Ferrari,* and J. Dalibard Laboratoire of magnitude larger than predicted, ruling out a Bose-Einstein condensation of Cs in this internal state. [S

Guéry-Odelin, David

365

Low-Energy Solvents for CO2 Capture Enabled by a Combination fo Enzymes and Ultrasonics  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energy Solvents for CO Energy Solvents for CO 2 Capture Enabled by a Combination of Enzymes and Ultrasonics Background The mission of the U.S. Department of Energy/National Energy Technology Laboratory (DOE/NETL) Existing Plants, Emissions, & Capture (EPEC) Research & Development (R&D) Program is to develop innovative environmental control technologies to enable full use of the nation's vast coal reserves, while at the same time allowing the current fleet of

366

Finite-size effect on the charging free energy of protein in explicit solvent  

Science Journals Connector (OSTI)

Finite-size effect on the charging free energy of protein in explicit solvent ... The finite-size effect in periodic system is examined for the charging free energy of protein in explicit solvent over a variety of charged states. ... The key to the finite-size correction is the self-energy, which is defined as the interaction energy of the solute with its own periodic images and the neutralizing background. ...

Toru Ekimoto; Nobuyuki Matubayasi; Mitsunori Ikeguchi

2014-12-09T23:59:59.000Z

367

Use of once-through treat gas to remove the heat of reaction in solvent hydrogenation processes  

DOE Patents [OSTI]

In a coal liquefaction process wherein feed coal is contacted with molecular hydrogen and a hydrogen-donor solvent in a liquefaction zone to form coal liquids and vapors and coal liquids in the solvent boiling range are thereafter hydrogenated to produce recycle solvent and liquid products, the improvement which comprises separating the effluent from the liquefaction zone into a hot vapor stream and a liquid stream; cooling the entire hot vapor stream sufficiently to condense vaporized liquid hydrocarbons; separating condensed liquid hydrocarbons from the cooled vapor; fractionating the liquid stream to produce coal liquids in the solvent boiling range; dividing the cooled vapor into at least two streams; passing the cooling vapors from one of the streams, the coal liquids in the solvent boiling range, and makeup hydrogen to a solvent hydrogenation zone, catalytically hydrogenating the coal liquids in the solvent boiling range and quenching the hydrogenation zone with cooled vapors from the other cooled vapor stream.

Nizamoff, Alan J. (Convent Station, NJ)

1980-01-01T23:59:59.000Z

368

SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATION  

SciTech Connect (OSTI)

This report describes experimental results for the selective removal of strontium and cesium from simulated waste solutions using monosodium titanate (MST) and crystalline silicotitanate (CST)-laden filter cartridges. Four types of ion exchange cartridge media (CST and MST designed by both 3M and POROX{reg_sign}) were evaluated. In these proof-of-principle tests effective uptake of both Sr-85 and Cs-137 was observed. However, the experiments were not performed long enough to determine the saturation levels or breakthrough curve for each filter cartridge. POREX{reg_sign} MST cartridges, which by design were based on co-sintering of the active titanates with polyethylene particles, seem to perform as well as the 3M-designed MST cartridges (impregnated filter membrane design) in the uptake of strontium. At low salt simulant conditions (0.29 M Na{sup +}), the instantaneous decontamination factor (D{sub F}) for Sr-85 with the 3M-design MST cartridge measured 26, representing the removal of 96% of the Sr-85. On the other hand, the Sr-85 instantaneous D{sub F} with the POREX{reg_sign} design MST cartridge measured 40 or 98% removal of the Sr-85. Strontium removal with the 3M-design MST and CST cartridges placed in series filter arrangement produced an instantaneous decontamination factor of 41 or 97.6% removal compared to an instantaneous decontamination factor of 368 or 99.7% removal of the strontium with the POREX{reg_sign} MST and CST cartridge design placed in series. At high salt simulant conditions (5.6 M Na{sup +}), strontium removal with 3M-designed MST cartridge only and with 3M-designed MST and CST cartridges operated in a series configuration were identical. The instantaneous decontamination factor and the strontium removal efficiency, under the above configuration, averaged 8.6 and 88%, respectively. There were no POREX{reg_sign} cartridge experiments using the higher ionic strength simulant solution. At low salt simulant conditions, the uptake of Cs-137 with POREX{reg_sign} CST cartridge out performed the 3M-designed CST cartridges. The POREX{reg_sign} CST cartridge, with a Cs-137 instantaneous decontamination factor of 55 and a Cs-137 removal efficiency of 98% does meet the Cs-137 decontamination goals in the low salt simulant liquor. The Cs-137 removal with 3M-designed CST cartridge produced a decontamination factor of 2 or 49% removal efficiency. The Cs-137 performance graph for the 3M-designed CST cartridge showed an early cessation in the uptake of cesium-137. This behavior was not observed with the POREX{reg_sign} CST cartridges. No Cs-137 uptake tests were performed with the POREX{reg_sign} CST cartridges at high salt simulant conditions. The 3M-designed CST cartridges, with an instantaneous Cs-137 decontamination factor of less than 3 and a Cs-137 removal efficiency of less than 50% failed to meet the Cs-137 decontamination goals in both the low and high salt simulant liquors. This poor performance in the uptake of Cs-137 by the 3M CST cartridges may be attributed to fabrication flaws for the 3M-designed CST cartridges. The reduced number of CST membrane wraps per cartridge during the cartridge design phase, from 3-whole wraps to about 1.5, may have contributed to Cs-137 laden simulant channeling/by-pass which led to the poor performance in terms of Cs-137 sorption characteristics for the 3M designed CST cartridges. The grinding of CST ion exchange materials, to reduce the particle size distribution and thus enhance their easy incorporation into the filter membranes and the co-sintering of MST with polyethylene particles, did not adversely affect the sorption kinetics of both CST and MST in the uptake of Cs-137 and Sr-85, respectively. In general, the POREX{reg_sign} based cartridges showed more resistance to simulant flow through the filter cartridges as evidenced by higher pressure differences across the cartridges. Based on these findings they conclude that incorporating MST and CST sorbents into filter membranes represent a promising method for the semi-continuous removal of radioisotopes of strontium a

Oji, L.; Martin, K.; Hobbs, D.

2011-05-26T23:59:59.000Z

369

Nonadiabatic dynamics of electron transfer in solution: Explicit and implicit solvent treatments that include multiple relaxation time scales  

SciTech Connect (OSTI)

The development of efficient theoretical methods for describing electron transfer (ET) reactions in condensed phases is important for a variety of chemical and biological applications. Previously, dynamical dielectric continuum theory was used to derive Langevin equations for a single collective solvent coordinate describing ET in a polar solvent. In this theory, the parameters are directly related to the physical properties of the system and can be determined from experimental data or explicit molecular dynamics simulations. Herein, we combine these Langevin equations with surface hopping nonadiabatic dynamics methods to calculate the rate constants for thermal ET reactions in polar solvents for a wide range of electronic couplings and reaction free energies. Comparison of explicit and implicit solvent calculations illustrates that the mapping from explicit to implicit solvent models is valid even for solvents exhibiting complex relaxation behavior with multiple relaxation time scales and a short-time inertial response. The rate constants calculated for implicit solvent models with a single solvent relaxation time scale corresponding to water, acetonitrile, and methanol agree well with analytical theories in the Golden rule and solvent-controlled regimes, as well as in the intermediate regime. The implicit solvent models with two relaxation time scales are in qualitative agreement with the analytical theories but quantitatively overestimate the rate constants compared to these theories. Analysis of these simulations elucidates the importance of multiple relaxation time scales and the inertial component of the solvent response, as well as potential shortcomings of the analytical theories based on single time scale solvent relaxation models. This implicit solvent approach will enable the simulation of a wide range of ET reactions via the stochastic dynamics of a single collective solvent coordinate with parameters that are relevant to experimentally accessible systems.

Schwerdtfeger, Christine A.; Soudackov, Alexander V.; Hammes-Schiffer, Sharon, E-mail: shs3@illinois.edu [Department of Chemistry, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, Illinois 61801 (United States)] [Department of Chemistry, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, Illinois 61801 (United States)

2014-01-21T23:59:59.000Z

370

Understanding and Managing Generation Y  

E-Print Network [OSTI]

There are four generations in the workplace today; they consist of the Silent Generation, Baby Boom Generation, Generation X, and Generation Y. Generation Y, being the newest generation, is the least understood generation although marketers...

Wallace, Kevin

2007-12-14T23:59:59.000Z

371

Requirements for a Dynamic Solvent Extraction Module to Support Development of Advanced Technologies for the Recycle of Used Nuclear Fuel  

SciTech Connect (OSTI)

The Department of Energy's Nuclear Energy Advanced Modeling and Simulation (NEAMS) Program has been established to create and deploy next generation, verified and validated nuclear energy modeling and simulation capabilities for the design, implementation, and operation of future nuclear energy systems to improve the U.S. energy security. As part of the NEAMS program, Integrated Performance and Safety Codes (IPSC's) are being produced to significantly advance the status of modeling and simulation of energy systems beyond what is currently available to the extent that the new codes be readily functional in the short term and extensible in the longer term. The four IPSC areas include Safeguards and Separations, Reactors, Fuels, and Waste Forms. As part of the Safeguards and Separations (SafeSeps) IPSC effort, interoperable process models are being developed that enable dynamic simulation of an advanced separations plant. A SafeSepss IPSC 'toolkit' is in development to enable the integration of separation process modules and safeguards tools into the design process by providing an environment to compose, verify and validate a simulation application to be used for analysis of various plant configurations and operating conditions. The modules of this toolkit will be implemented on a modern, expandable architecture with the flexibility to explore and evaluate a wide range of process options while preserving their stand-alone usability. Modules implemented at the plant-level will initially incorporate relatively simple representations for each process through a reduced modeling approach. Final versions will incorporate the capability to bridge to subscale models to provide required fidelity in chemical and physical processes. A dynamic solvent extraction model and its module implementation are needed to support the development of this integrated plant model. As a stand-alone application, it will also support solvent development of extraction flowsheets and integrated safeguards approaches within the Fuel Cycle Research and Development (FCR&D) Program. The purpose of this document is to identify the requirements for this dynamic solvent extraction model to guide process modelers and code developers to produce a computational module that meets anticipated future needs.

Jack Law; Veronica Rutledge; Candido Pereira; Jackie Copple; Kurt Frey; John Krebs; Laura Maggos; Kevin Nichols; Kent Wardle; Pratap Sadasivan; Valmor DeAlmieda; David Depaoli

2011-06-01T23:59:59.000Z

372

Natural deep eutectic solvents as new potential media for green technology  

Science Journals Connector (OSTI)

Developing new green solvents is one of the key subjects in Green Chemistry. Ionic liquids (ILs) and deep eutectic solvents, thus, have been paid great attention to replace current harsh organic solvents and have been applied to many chemical processing such as extraction and synthesis. However, current ionic liquids and deep eutectic solvents have still limitations to be applied to a real chemical industry due to toxicity against human and environment and high cost of \\{ILs\\} and solid state of most deep eutectic solvents at room temperature. Recently we discovered that many plant abundant primary metabolites changed their state from solid to liquid when they were mixed in proper ratio. This finding made us hypothesize that natural deep eutectic solvents (NADES) play a role as alternative media to water in living organisms and tested a wide range of natural products, which resulted in discovery of over 100 NADES from nature. In order to prove deep eutectic feature the interaction between the molecules was investigated by nuclear magnetic resonance spectroscopy. All the tested NADES show clear hydrogen bonding between components. As next step physical properties of NADES such as water activity, density, viscosity, polarity and thermal properties were measured as well as the effect of water on the physical properties. In the last stage the novel NADES were applied to the solubilization of wide range of biomolecules such as non-water soluble bioactive natural products, gluten, starch, and DNA. In most cases the solubility of the biomolecules evaluated in this study was greatly higher than water. Based on the results the novel NADES may be expected as potential green solvents at room temperature in diverse fields of chemistry.

Yuntao Dai; Jaap van Spronsen; Geert-Jan Witkamp; Robert Verpoorte; Young Hae Choi

2013-01-01T23:59:59.000Z

373

Efficient Regeneration of Physical and Chemical Solvents for CO{sub 2} Capture  

SciTech Connect (OSTI)

The objective of this project was to evaluate the use of composite polymer membranes and porous membrane contactors to regenerate physical and chemical solvents for capture of carbon dioxide (CO{sub 2}) from synthesis gas or flue gas, with the goal of improving the energy efficiency of carbon capture. Both a chemical solvent (typical for a post-combustion capture of CO{sub 2} from flue gas) and a physical solvent (typical for pre- combustion capture of CO{sub 2} from syngas) were evaluated using two bench-scale test systems constructed for this project. For chemical solvents, polytetrafluoroethylene and polypropylene membranes were found to be able to strip CO{sub 2} from a monoethanolamine (MEA) solution with high selectivity without significant degradation of the material. As expected, the regeneration temperature was the most significant parameter affecting the CO{sub 2} flux through the membrane. Pore size was also found to be important, as pores larger than 5 microns lead to excessive pore wetting. For physical solvents, polydimethyl-siloxane (PDMS)-based membranes were found to have a higher CO{sub 2} permeability than polyvinylalcohol (PVOH) based membranes, while also minimizing solvent loss. Overall, however, the recovery of CO{sub 2} in these systems is low – less than 2% for both chemical and physical solvents – primarily due to the small surface area of the membrane test apparatus. To obtain the higher regeneration rates needed for this application, a much larger surface area would be needed. Further experiments using, for example, a hollow fiber membrane module could determine if this process could be commercially viable.

Tande, Brian; Seames, Wayne; Benson, Steve

2013-05-31T23:59:59.000Z

374

Relaxation mechanisms affecting magneto-optical resonances in an extremely thin cell: experiment and theory for the cesium D$_1$ line  

E-Print Network [OSTI]

We have measured magneto-optical signals obtained by exciting the $D_1$ line of cesium atoms confined to an extremely thin cell (ETC), whose walls are separated by less than one micrometer, and developed an improved theoretical model to describe these signals with experimental precision. The theoretical model was based on the optical Bloch equations and included all neighboring hyperfine transitions, the mixing of the magnetic sublevels in an external magnetic field, and the Doppler effect, as in previous studies. However, in order to model the extreme conditions in the ETC more realistically, the model was extended to include a unified treatment of transit relaxation and wall collisions with relaxation rates that were obtained directly from the thermal velocities of the atoms and the length scales involved. Furthermore, the interaction of the atoms with different regions of the laser beam were modeled separately to account for the varying laser beam intensity over the beam profile as well as saturation effec...

Auzinsh, M; Ferber, R; Gahbauer, F; Kalnins, U; Kalvans, L; Rundans, R; Sarkisyan, D

2014-01-01T23:59:59.000Z

375

Next Generation Radioisotope Generators | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

» Next Generation Radioisotope Generators » Next Generation Radioisotope Generators Next Generation Radioisotope Generators Advanced Stirling Radioisotope Generator (ASRG) - The ASRG is currently being developed as a high-efficiency RPS technology to support future space missions on the Martian surface or in the vacuum of space. This system uses Stirling convertors, which have moving parts to mechanically convert heat to electricity. This power conversion system, if successfully deployed, will reduce the weight of each RPS and the amount of Pu-238 needed per mission. A HISTORY OF MISSION SUCCESSES For over fifty years, the Department of Energy has enabled space exploration on 27 missions by providing safe reliable radioistope power systems and radioisotope heater units for NASA, Navy and Air Force.

376

SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION-EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATIONS-12092  

SciTech Connect (OSTI)

Experimental results for the selective removal of strontium and cesium from simulated waste solutions with monosodium titanate (MST) and crystalline silicotitanate (CST) laden filter cartridges are presented. In these proof-of-principle tests, effective uptake of both Sr-85 and Cs-137 were observed using ion-exchangers in this filter cartridge configuration. At low salt simulant conditions, the instantaneous decontamination factor (D{sub F}) for Sr-85 with MST impregnated filter membrane cartridges measured 26, representing 96% Sr-85 removal efficiency. On the other hand, the Sr-85 instantaneous D{sub F} with co-sintered active MST cartridges measured 40 or 98% Sr-85 removal efficiency. Strontium-85 removal with the MST impregnated membrane cartridges and CST impregnated membrane cartridges, placed in series arrangement, produced an instantaneous decontamination factor of 41 compared to an instantaneous decontamination factor of 368 for strontium-85 with co-sintered active MST cartridges and co-sintered active CST cartridges placed in series. Overall, polyethylene co-sintered active titanates cartridges performed as well as titanate impregnated filter membrane cartridges in the uptake of strontium. At low ionic strength conditions, there was a significant uptake of Cs-137 with co-sintered CST cartridges. Tests results with CST impregnated membrane cartridges for Cs-137 decontamination are currently being re-evaluated. Based on these preliminary findings we conclude that incorporating MST and CST sorbents into membranes represent a promising method for the semi-continuous removal of radioisotopes of strontium and cesium from nuclear waste solutions.

Oji, L.; Martin, K.; Hobbs, D.

2011-11-10T23:59:59.000Z

377

Lanthanide-organic complexes based on polyoxometalates: Solvent effect on the luminescence properties  

SciTech Connect (OSTI)

A series of lanthanide-organic complexes based on polyoxometalates (POMs) [Ln{sub 2}(DNBA){sub 4}(DMF){sub 8}][W{sub 6}O{sub 19}] (Ln=La(1), Ce(2), Sm(3), Eu(4), Gd(5); DNBA=3,5-dinitrobenzoate; DMF=N,N-dimethylformamide) has been synthesized. These complexes consist of [W{sub 6}O{sub 19}]{sup 2-} and dimeric [Ln{sub 2}(DNBA){sub 4}(DMF){sub 8}]{sup 2+} cations. The luminescence properties of 4 are measured in solid state and different solutions, respectively. Notably, the emission intensity increases gradually with the increase of solvent permittivity, and this solvent effect can be directly observed by electrospray mass spectrometry (ESI-MS). The analyses of ESI-MS show that the eight coordinated solvent DMF units of dimeric cation are active. They can move away from dimeric cations and exchange with solvent molecules. Although the POM anions escape from 3D supramolecular network, the dimeric state structure of [Ln{sub 2}(DNBA){sub 4}]{sup 2+} remains unchanged in solution. The conservation of red luminescence is attributed to the maintenance of the aggregated state structures of dimeric cations. - Graphical abstract: 3D POMs-based lanthanide-organic complexes performed the solvent effect on the luminescence property. The origin of such solvent effect can be understood and explained on the basis of the existence of coordinated active sites by the studies of ESI-MS. Highlights: Black-Right-Pointing-Pointer The solvent effect on the luminescence property of POMs-based lanthanide-organic complexes. Black-Right-Pointing-Pointer ESI-MS analyses illuminate the correlation between the structure and luminescence property. Black-Right-Pointing-Pointer The dimeric cations have eight active sites of solvent coordination. Black-Right-Pointing-Pointer The aggregated state structure of dimer cation remains unchanged in solution. Black-Right-Pointing-Pointer Luminescence associating with ESI-MS is a new method for investigating the interaction of complex and solvent.

Tang Qun [Key Laboratory of Polyoxometalate Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (China); Liu Shuxia, E-mail: liusx@nenu.edu.cn [Key Laboratory of Polyoxometalate Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (China); Liang Dadong; Ma Fengji; Ren Guojian; Wei Feng; Yang Yuan; Li Congcong [Key Laboratory of Polyoxometalate Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 130024 (China)

2012-06-15T23:59:59.000Z

378

Generation gaps in engineering?  

E-Print Network [OSTI]

There is much enthusiastic debate on the topic of generation gaps in the workplace today; what the generational differences are, how to address the apparent challenges, and if the generations themselves are even real. ...

Kim, David J. (David Jinwoo)

2008-01-01T23:59:59.000Z

379

Process for producing low-sulfur boiler fuel by hydrotreatment of solvent deashed SRC  

DOE Patents [OSTI]

In this invention, a process is disclosed characterized by heating a slurry of coal in the presence of a process-derived recycle solvent and passing same to a dissolver zone, separating the resultant gases and liquid/solid products therefrom, vacuum distilling the liquid/solids products, separating the portions of the liquid/solids vacuum distillation effluent into a solid ash, unconverted coal particles and SRC material having a boiling point above 850.degree. F. and subjecting same to a critical solvent deashing step to provide an ash-free SRC product. The lighter liquid products from the vacuum distillation possess a boiling point below 850.degree. F. and are passed through a distillation tower, from which recycled solvent is recovered in addition to light distillate boiling below 400.degree. F. (overhead). The ash-free SRC product in accompanyment with at least a portion of the process derived solvent is passed in combination to a hydrotreating zone containing a hydrogenation catalyst and in the presence of hydrogen is hydroprocessed to produce a desulfurized and denitrogenized low-sulfur, low-ash boiler fuel and a process derived recycle solvent which is recycled to slurry the coal in the beginning of the process before heating.

Roberts, George W. (Emmaus, PA); Tao, John C. (Perkiomenville, PA)

1985-01-01T23:59:59.000Z

380

Greener construction of 4H-chromenes based dyes in deep eutectic solvent  

Science Journals Connector (OSTI)

Abstract Green solvents such as deep eutectic solvents are new emerging alternatives to the conventional harmful organic solvents which may find a number of interesting applications in industrial and chemical processes. A facile, atom-economic and environmentally-benign one-pot reaction of salicylaldehyde and malononitrile with various nucleophiles, including indoles, thiols, secondary amines, cyanide and azide were efficiently achieved in choline chloride based deep eutectic solvent (DES). Products distribution of the current green protocol depend on the nature of the nucleophile used in the reaction. The one-pot reaction of salicylaldehyde derivatives and malononitrile with thiols, indoles, and cyanide give 2-amino-3-cyano-4H-chromene derivatives. Secondary amines result in the formation of benzopyrano[2,3-d] pyrimidines, due to the further reaction of salicylaldehyde with 4H-chromene under the same reaction condition. The DES was recycled without any reduction in activity or yield. Therefore, the synthesis of chromene based dyes in green solvents at room temperature under catalyst-free conditions is a promising alternative to previously used procedures.

Najmedin Azizi; Mahboobe Mariami; Mahtab Edrisi

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Solvent Extraction of Chemical Attribution Signature Compounds from Painted Wall Board: Final Report  

SciTech Connect (OSTI)

This report summarizes work that developed a robust solvent extraction procedure for recovery of chemical attribution signature (CAS) compound dimethyl methyl phosphonate (DMMP) (as well as diethyl methyl phosphonate (DEMP), diethyl methyl phosphonothioate (DEMPT), and diisopropyl methyl phosphonate (DIMP)) from painted wall board (PWB), which was selected previously as the exposed media by the chemical attribution scientific working group (CASWG). An accelerated solvent extraction approach was examined to determine the most effective method of extraction from PWB. Three different solvent systems were examined, which varied in solvent strength and polarity (i.e., 1:1 dichloromethane : acetone,100% methanol, and 1% isopropanol in pentane) with a 1:1 methylene chloride : acetone mixture having the most robust and consistent extraction for four original target organophosphorus compounds. The optimum extraction solvent was determined based on the extraction efficiency of the target analytes from spiked painted wallboard as determined by gas chromatography x gas chromatography mass spectrometry (GCxGC-MS) analysis of the extract. An average extraction efficiency of approximately 60% was obtained for these four compounds. The extraction approach was further demonstrated by extracting and detecting the chemical impurities present in neat DMMP that was vapor-deposited onto painted wallboard tickets.

Wahl, Jon H.; Colburn, Heather A.

2009-10-29T23:59:59.000Z

382

Hydrogen Generation by Electrolysis  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Better Engineered Solutions. Better Engineered Solutions. What Listening Generates. Better Engineered Solutions. What Listening Generates. Hydrogen Generation by Electrolysis September 2004 Steve Cohen Hydrogen Generation by Electrolysis September 2004 Steve Cohen NREL H 2 Electrolysis - Utility Integration Workshop NREL H 2 Electrolysis - Utility Integration Workshop 2 Hydrogen Generation by Electrolysis Hydrogen Generation by Electrolysis  Intro to Teledyne Energy Systems  H 2 Generator Basics & Major Subsystems  H 2 Generating & Storage System Overview  Electrolysis System Efficiency & Economics  Focus for Attaining DOE H 2 Production Cost Goals 3 Teledyne Energy Systems Locations - ISO 9001 Teledyne Energy Systems Locations - ISO 9001 Hunt Valley, Maryland  State-of-the-art thermoelectric,

383

A study of solvent refining of cottonseed oil by use of a rotating core countercurrent extraction column  

E-Print Network [OSTI]

. Conclusions 7. Bibliography 8. Appendix 23 27 A STUDY OF SOLVENT REFINING OP COTTONSEED OIL BY USE OF A ROTATING CORE COUNTERCURRENT EXTRACTION COLUMN INTRODUCTION In th1s study the applicability oi several solvents for solvent refining crude... countercurrent ex- traction column. Cottonseed oil is essent1ally a triglyceride but contains also a number of impurities. Jamieson and Baughman (7) report the following 1n crude cottonseed oil& rai'finose, pentosans, resins, proteoses, peptones...

Holbrook, Charles Ray

1953-01-01T23:59:59.000Z

384

Solvent Viscosity and Interrelated Effects on Electrochemiluminescence Intensity of Tris(2,2‘-bipyridyl)ruthenium(II)  

Science Journals Connector (OSTI)

Solvent Viscosity and Interrelated Effects on Electrochemiluminescence Intensity of Tris(2,2‘-bipyridyl)ruthenium(II)† ... 1 The mechanism accepted in the literature1b is the following: Clearly several processes occur in the mechanism, and each is dependent upon solvent properties to a certain degree. ... Solvent viscosity maps the macroscopic transition between the liquid and solid states and affects each component process of ECL. ...

Amy M. Scott; Radha Pyati

2001-08-02T23:59:59.000Z

385

Shift of the emission band upon excitation at the long wavelength absorption edge. II. Importance of the solute–solvent interaction and the solvent reorientation relaxation process  

Science Journals Connector (OSTI)

Fluorescence and phosphorescence of quinine and its related compounds such as 6?methoxyquinoline are found to exhibit a red shift when excitation is achieved at the long wavelength edge of the first absorption band and this anomalous shift is investigated in detail. The anomalous shift is observed not only in room temperature fluorescence but also in low temperature fluorescence and phophorescence. The term e d g e e x c i t a t i o n r e d s h i f t (EERS) is introduced. After various plausible interpretations we have suggested a logical mechanism for EERS. In the suggested mechanism EERS is observed if the solvent reorientation relaxation rate is small compared with the emission rate and the Franck–Condon solvation energy is reasonably large with respect to solvent orientation. All the experimental observations are satisfactorily interpreted within the framework of the suggested mechanism.

Ken?ichi Itoh; Tohru Azumi

1975-01-01T23:59:59.000Z

386

APPENDIX B: CARBON DIOXIDE CAPTURE TECHNOLOGY SHEETS PRE-COMBUSTION SOLVENTS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CARBON DIOXIDE CAPTURE TECHNOLOGY SHEETS PRE-COMBUSTION SOLVENTS PRE-COMBUSTION SORBENTS PRE-COMBUSTION MEMBRANES POST-COMBUSTION SOLVENTS POST-COMBUSTION SORBENTS POST-COMBUSTION MEMBRANES OXY-COMBUSTION OXYGEN PRODUCTION CHEMICAL LOOPING ADVANCED COMPRESSION R&D COLLABORATIONS B-1 APPENDIX B: CARBON DIOXIDE CAPTURE TECHNOLOGY SHEETS APPENDIX B: CARBON DIOXIDE CAPTURE TECHNOLOGY SHEETS NATIONAL ENERGY TECHNOLOGY LABORATORY PRE-COMBUSTION SOLVENTS B-6 SRI International - CO 2 Capture Using AC-ABC Processt B-7 PRE-COMBUSTION SORBENTS B-14 TDA Research - CO 2 Capture for Low-Rank Coal IGCC Systems B-15 URS Group - Sorbent Development for WGS B-18 Air Products and Chemicals - Advanced Acid Gas Separation B-24 Ohio State University-Department of Chemical Engineering - Calcium Looping for Hydrogen Production B-33

387

Slow relaxation and solvent effects in the collapse of a polymer  

Science Journals Connector (OSTI)

Using molecular dynamic simulations we study the quench of a homopolymer chain into a poor solvent at finite temperature. We show that, depending on the quench depth, there are different relaxation pathways to the collapsed state. Solvent effects are introduced through an effective Lennard-Jones potential depending on the local monomer density. The various relaxation regimes are characterized by the contact correlation function. As the quench depth increases, the system evolves towards a glassy state, and the relaxation dynamics continuously changes from an exponential to a stretched exponential law. The characteristic relaxation time diverges at low temperature following an Arrhenius law, like in the case of strong glasses. We found that the stretching exponent depends on aging in a nonuniversal way. The solvent modifies the globular state by diminishing the effects of frustration and glassy behavior.

Thomas Frisch and Alberto Verga

2002-10-28T23:59:59.000Z

388

A Combustion Chemistry Analysis of Carbonate Solvents in Li-Ion Batteries  

SciTech Connect (OSTI)

Under abusive conditions Li-ion batteries can rupture, ejecting electrolyte and other flammable gases. In this paper we consider some of the thermochemical properties of these gases that will determine whether they ignite and how energetically they burn. We show that flames of carbonate solvents are fundamentally less energetic than those of conventional hydrocarbons. An example of this difference is given using a recently developed mechanism for dimethyl carbonate (DMC) combustion, where we show that a diffusion flame burning DMC has only half the peak energy release rate of an analogous propane flame. We find a significant variation among the carbonate solvents in the factors that are important to determining flammability, such as combustion enthalpy and vaporization enthalpy. This result suggests that thermochemical and kinetic factors might well be considered when choosing solvent mixtures.

Harris, S J; Timmons, A; Pitz, W J

2008-11-13T23:59:59.000Z

389

Solvent-side observation on vibrational energy transfer by transient grating spectroscopy: Bridged azulene-anthracene  

E-Print Network [OSTI]

Transient grating acoustic spectroscopy has been applied to studies on the vibrational energy relaxation process of the electronic ground state of azulene, two 1-alkylazulenes, and five bridged azulene-anthracenes in three different solvents: 1,1,1-trichloro-1,2,2-trifluoroethane, acetonitrile, and xenon. The solute molecule was vibrationally excited by the photo-excitation of the auzlenyl group to the S1 state through the fast internal conversion, and the rate of solvent thermalization due to the vibrational energy relaxation was determined. The thermalization rates for 1-alkylazulenes and bridged azulene-anthracenes were faster than that of azulene. Based on the results of the thermalization rates of 1-alkylazulenes, we concluded that the acceleration of the energy dissipation from the azulenyl group induced the faster energy dissipation from the solute to the solvent. The vibrational normal mode analysis suggests that the density of the vibrational modes and anharmonic coupling between the vibrational mode...

Fujiwara, Hiroki

2014-01-01T23:59:59.000Z

390

Solvent-Dependent Assembly of Terphenyl- and Quaterphenyldithiol on Gold and Gallium Arsenide  

Science Journals Connector (OSTI)

Solvent-Dependent Assembly of Terphenyl- and Quaterphenyldithiol on Gold and Gallium Arsenide ... This solvent pair was chosen because of an apparent solubility conflict:? while EtOH is the most common solvent for assembling alkylthiol and conjugated monothiol molecules,43-45 the longer n-phenyldithiols (n = 3, 4), in their thioacetyl forms (compounds 3 and 4 in Scheme 1), are poorly soluble in EtOH. ... The precipitate was filtered, washed with water, hexane, and methylene chloride, and dried overnight at 40 °C under vacuum to afford a light-yellow solid (5.90 g, 92%). 1H NMR (200 MHz, CDCl3) ? 7.65 (s, 4H), 7.55 (d, J = 8.0 Hz, 4H), 7.32 (d, J = 8.0 Hz, 4H), 2.55 (s, 6H). ...

Dmitry A. Krapchetov; Hong Ma; Alex K. Y. Jen; Daniel A. Fischer; Yueh-Lin Loo

2005-05-17T23:59:59.000Z

391

Argonne CNM Highlight: Solvent-Mediated End-to-End Assembly of Gold  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Solvent-Mediated End-to-End Assembly of Gold Nanorods Solvent-Mediated End-to-End Assembly of Gold Nanorods gold nanorods Transmission-electron-microscope image of 70-nm-long gold nanorods assembled end to end via solvent-mediated interactions. CNM scientists have developed a new method for the controlled end-to-end assembly of rod-shaped gold nanoparticles. The nanoparticles are synthesized chemically using an established technique, producing high-quality gold nanorods with lengths of approximately 70 nm and diameters of approximately 15 nm, stabilized in water by hydrophilic surfactant molecules. The sides of the rods are better protected by the surfactants than the ends, so that when additional ligand molecules that bind to gold are added to the solution, they preferentially attach to the ends of the rods. If these ligands are hydrophobic, then the rods will

392

Decontamination of process equipment using recyclable chelating solvent  

SciTech Connect (OSTI)

The Department of Energy (DOE) is now faced with the task of meeting decontamination and decommissioning obligations at numerous facilities by the year 2019. Due to the tremendous volume of material involved, innovative decontamination technologies are being sought that can reduce the volumes of contaminated waste materials and secondary wastes requiring disposal. With sufficient decontamination, some of the material from DOE facilities could be released as scrap into the commercial sector for recycle, thereby reducing the volume of radioactive waste requiring disposal. Although recycling may initially prove to be more costly than current disposal practices, rapidly increasing disposal costs are expected to make recycling more and more cost effective. Additionally, recycling is now perceived as the ethical choice in a world where the consequences of replacing resources and throwing away reusable materials are impacting the well-being of the environment. Current approaches to the decontamination of metals most often involve one of four basic process types: (1) chemical, (2) manual and mechanical, (3) electrochemical, and (4) ultrasonic. {open_quotes}Hard{close_quotes} chemical decontamination solutions, capable of achieving decontamination factors (Df`s) of 50 to 100, generally involve reagent concentrations in excess of 5%, tend to physically degrade the surface treated, and generate relatively large volumes of secondary waste. {open_quotes}Soft{close_quotes} chemical decontamination solutions, capable of achieving Df`s of 5 to 10, normally consist of reagents at concentrations of 0.1 to 1%, generally leave treated surfaces in a usable condition, and generate relatively low secondary waste volumes. Under contract to the Department of Energy, the Babcock & Wilcox Company is developing a chemical decontamination process using chelating agents to remove uranium compounds and other actinide species from process equipment.

Jevec, J.; Lenore, C.; Ulbricht, S.

1995-12-01T23:59:59.000Z

393

Comparisons of amine solvents for post-combustion CO{sub 2} capture: A multi-objective analysis approach  

SciTech Connect (OSTI)

Amine solvents are of great interest for post-combustion CO{sub 2} capture applications. Although the development of new solvents is predominantly conducted at the laboratory scale, the ability to assess the performance of newly developed solvents at the process scale is crucial to identifying the best solvents for CO{sub 2} capture. In this work we present a methodology to evaluate and objectively compare the process performance of different solvents. We use Aspen Plus, with the electrolyte-NRTL thermodynamic model for the solvent CO{sub 2} interactions, coupled with a multi-objective genetic algorithm optimization to determine the best process design and operating conditions for each solvent. This ensures that the processes utilized for the comparison are those which are best suited for the specific solvent. We evaluate and compare the process performance of monoethanolamine (MEA), diethanolamine (DEA), and 2-amino-2-methyl-1-propanol (AMP) in a 90% CO{sub 2} capture process from a 550 MW coal fired power plant. From our analysis the best process specifications are amine specific and with those specific, optimized specifications DEA has the potential to be a better performing solvent than MEA, with a lower energy penalty and lower capital cost investment.

Lee, Anita S.; Eslick, John C.; Miller, David C.; Kitchin, John R.

2013-10-01T23:59:59.000Z

394

DELAYED COKING OF SOLVENT EXTRACTED COAL FOR PRODUCTION OF ANODE GRADE COKE: CHARACTERIZATION OF SOLID AND LIQUID PRODUCTS.  

E-Print Network [OSTI]

??This study investigates the feasibility of using high temperature solvent extraction of coal to produce feedstock for the production of anode grade coke through delayed… (more)

Karri, Vamsi

2011-01-01T23:59:59.000Z

395

Characterization of Samples from Old Solvent Tanks S1 through S22  

SciTech Connect (OSTI)

The Old Radioactive Waste Burial Ground (ORWBG, 643-E) contains 22 old solvent tanks (S1 - S22) which were used to receive and store spent PUREX solvent from F- and H-Canyons. The tanks are cylindrical, carbon-steel, single-wall vessels buried at varying depths. A detailed description of the tanks and their history can be found in Reference 1. A Sampling and Analysis Plan for the characterization of the material contained in the old solvent tanks was developed by the Analytical Development Section (ADS) in October of 19972. The Sampling and Analysis Plan identified several potential disposal facilities for the organic and aqueous phases present in the old solvent tanks which included the Solvent Storage Tank Facility (SSTF), the Mixed Waste Storage Facilities (MWSF), Transuranic (TRU) Pad, and/or the Consolidated Incineration Facility (CIF). In addition, the 241-F/H Tank Farms, TRU Pads, and/or the MWSF were identified as potential disposal facilities for the sludge phases present in the tanks. The purpose of this sampling and characterization was to obtain sufficient data on the material present in the old solvent tanks so that a viable path forward could be established for the closure of the tanks. Therefore, the parameters chosen for the characterization of the various materials present in the tanks were based upon the Waste Acceptance Criteria (WAC) of the SSTF3, TRU Pads4, MWSF5, CIF6, and/or 241-F/H Tank Farms7. Several of the WAC's have been revised, canceled, or replaced by new procedures since October of 1997 and hence where required, the results of this characterization program were compared against the latest revision of the appropriate WAC.

Leyba, J.D.

1999-03-25T23:59:59.000Z

396

Vapor-liquid equilibria for copolymer+solvent systems: Effect of intramolecular repulsion  

SciTech Connect (OSTI)

Role of intramolecular interactions in blend miscibility is well documented for polymer+copolymer mixtures. Some copolymer+polymer mixtures are miscible although their corresponding homopolymers are not miscible; for example, over a range of acrylonitrile content, styrene/acrylonitrile copolymers are miscible with poly(methyl methacrylate) but neither polystyrene nor polyacrylonitrile is miscible with poly(methyl methacrylate). Similarly, over a composition range, butadiene/acrylonitrile copolymers are miscible with poly(vinyl chloride) while none of the binary combinations of the homopolymers [polybutadiene, polyacrylonitrile, and poly(vinyl chloride)] are miscible. This behavior has been attributed to ``intramolecular repulsion`` between unlike copolymer segments. We have observed similar behavior in vapor-liquid equilibria (VLE) of copolymer+solvent systems. We find that acrylonitrile/butadiene copolymers have higher affinity for acetonitrile solvent than do polyacrylonitrile or polybutadiene. We attribute this non-intuitive behavior to ``intramolecular repulsion`` between unlike segments of the copolymer. This repulsive interaction is weakened when acetonitrile molecules are in the vicinity of unlike copolymer segments, favoring copolymer+solvent miscibility. We find similar behavior when acetonitrile is replaced by methyl ethyl ketone. To best knowledge, this effect has not been reported previously for VLE. We have obtained VLE data for mixtures containing a solvent and a copolymer as a function of copolymer composition. It appears that, at a given solvent partial pressure, there may be copolymer composition that yields maximum absorption of the solvent. This highly non-ideal VLE phase behavior may be useful for optimum design of a membrane for a separation process.

Gupta, R.B.; Prausnitz, J.M.

1995-03-01T23:59:59.000Z

397

Computational analysis of 3D-flows in rocket produced H2/H2O plasma based MHD generators for space applications  

Science Journals Connector (OSTI)

In this paper, a study is presented in which the magnetohydrodynamic interactions have been analysed in Faraday connection generators, which show potential for space applications. The channel design of an extensively studied Sakhalin generator developed in the former USSR has been used and coupled with a cesium seeded liquid hydrogen and liquid oxygen combustion based chemical rocket. The CFD analysis of this design has been done using a program code based on multigrid algorithms for the solution of momentum and electrical equations. The code implements corrections in k-epsilon turbulence equations and for the calculations of transport properties of the plasma. The development of the secondary flows with complicated six vortex cells in the MHD channel has been analysed, which show agreement with a previous experimental study. Also, it has been shown that power output of the MHD generator could be significantly improved by changing the configuration of the MHD channel.

Ayush Saurabh; Ali Turan

2013-01-01T23:59:59.000Z

398

Preparation of membranes using solvent-less vapor deposition followed by in-situ polymerization  

DOE Patents [OSTI]

A system of fabricating a composite membrane from a membrane substrate using solvent-less vapor deposition followed by in-situ polymerization. A first monomer and a second monomer are directed into a mixing chamber in a deposition chamber. The first monomer and the second monomer are mixed in the mixing chamber providing a mixed first monomer and second monomer. The mixed first monomer and second monomer are solvent-less vapor deposited onto the membrane substrate in the deposition chamber. The membrane substrate and the mixed first monomer and second monomer are heated to produce in-situ polymerization and provide the composite membrane.

O'Brien, Kevin C. (San Ramon, CA); Letts, Stephan A. (San Ramon, CA); Spadaccini, Christopher M. (Oakland, CA); Morse, Jeffrey C. (Pleasant Hill, CA); Buckley, Steven R. (Modesto, CA); Fischer, Larry E. (Los Gatos, CA); Wilson, Keith B. (San Ramon, CA)

2012-01-24T23:59:59.000Z

399

Laboratory and pilot field-scale testing of surfactants for environmental restoration of chlorinated solvent DNAPLs  

SciTech Connect (OSTI)

This project is composed of two phases and has the objective of demonstrating surfactant-enhanced aquifer remediation (SEAR) as a practical remediation technology at DOE sites with ground water contaminated by dense, non-aqueous phase liquids (DNAPLs), in particular, chlorinated solvents. The first phase of this project, Laboratory and Pilot Field Scale Testing, which is the subject of the work so far, involves (1) laboratory experiments to examine the solubilization of multiple component DNAPLs, e.g., solvents such as perchloroethylene (PCE) and trichloroethylene (TCE), by dilute surfactant solutions, and (2) a field test to demonstrate SEAR technology on a small scale and in an existing well.

Jackson, R.E. [INTERA, Inc., Austin, TX (United States); Fountain, J.C. [State Univ. of New York, Buffalo, NY (United States)

1994-12-31T23:59:59.000Z

400

ENERGY GENERATION RESEARCH PIER Energy Generation Research  

E-Print Network [OSTI]

ENERGY GENERATION RESEARCH PIER Energy Generation Research www.energy.ca.gov/research/ renewable/ November 2010 Sonoma County RESCO A Local Level Approach to Renewable Energy Portfolios. The Issue To address energy usage that contributes to climate change, California has enacted legislation to guide

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Gamma ray generator  

DOE Patents [OSTI]

An embodiment of a gamma ray generator includes a neutron generator and a moderator. The moderator is coupled to the neutron generator. The moderator includes a neutron capture material. In operation, the neutron generator produces neutrons and the neutron capture material captures at least some of the neutrons to produces gamma rays. An application of the gamma ray generator is as a source of gamma rays for calibration of gamma ray detectors.

Firestone, Richard B; Reijonen, Jani

2014-05-27T23:59:59.000Z

402

Generation to Generation: The Heart of Family Medicine  

E-Print Network [OSTI]

Ageism in the Workplace. Generations Spring, 5. Westman,of caring for multiple generations simultaneously. StronglyGeneration to Generation: The Heart of Family Medicine

Winter, Robin O

2012-01-01T23:59:59.000Z

403

Removal of deposited copper from nuclear steam generators  

SciTech Connect (OSTI)

A review of the copper-removal process implemented during the cleaning of the NPD nuclear steam generator in Ontario revealed that major shortcomings in the process were depletion of the strong ammonia solution and relatively poor copper removal. Tests have shown that the concentration of the ammonia solution can be preserved close to its initial value, and high concentrations of complexed copper obtained, by sparging the ammonia solution with oxygen recirculating through a gas recirculation loop. Using recirculating oxygen for sparging at ambient air temperature, approximately 11 g/l of copper were dissolved by 100 g/l ammonia solution while the gaseous ammonia content of the recirculating gas remained well below the lower flammability limit. The corrosion rates of mild steel and commonly used nuclear steam generator tube materials in oxygenated ammonia solution were less than 30 mil/yr and no intergranular attack of samples was observed during tests. A second technique studied for the removal of copper is to ammoniate the spent iron-removal solvent to approximately pH 9.5 and sparge with recirculating oxygen. Complexed ferric iron in the spent iron-removal solvent was found to be the major oxidizing agent for metallic copper. The ferric iron can be derived from oxidation of dissolved ferrous iron to the ferric state or from dissolved oxides of iron directly. To extract copper from the secondary sides of nuclear steam generators, strong ammonia solution sparged with recirculating oxygen is recommended as the first stage, while ammoniated spent iron-removal solvent sparged with recirculating oxygen may be used to remove the copper freshly exposed during the removal of iron.

McSweeney, P.

1982-05-01T23:59:59.000Z

404

Field application of a chemical heat and nitrogen generating system  

SciTech Connect (OSTI)

Heat is often required to stimulate production in wells with recurrent histories of paraffin deposition and plugging. A chemical system which produces heat and nitrogen at a predetermined well depth is proposed as an alternative to the traditional hot oil and steam generation treatments. The system is described briefly and case histories are given for 3 wells in California and 5 wells in Wyoming. The field results indicate that heat produced by the nitrogen generating system effectively stimulates production from paraffin plugged wells. The heat and nitrogen generating system further shows increased production cycle lengths over those which result from hot oil or paraffin solvent treatments. Beneficial effects of including a paraffin inhibitor in the treatment design are discussed, along with other potential applications for the heat produced by this system.

Mitchell, T.I.; Collesi, J.B.; Donovan, S.C.; McSpadden, H.W.

1984-04-01T23:59:59.000Z

405

A Comparison of Electron-Transfer Dynamics inIonic Liquids and Neutral Solvents  

SciTech Connect (OSTI)

The effect of ionic liquids on photoinduced electron-transfer reactions in a donor-bridge-acceptor system is examined for two ionic liquid solvents, 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide and tributylmethylammonium bis(trifluoromethylsulfonyl)amide. The results are compared with those for the same system in methanol and acetonitrile solution. Electron-transfer rates were measured using time-resolved fluorescence quenching for the donor-bridge-acceptor system comprising a 1-N,1-N-dimethylbenzene-1,4-diamine donor, a proline bridge, and a coumarin 343 acceptor. The photoinduced electron-transfer processes are in the inverted regime (-{Delta}G > {lambda}) in all four solvents, with driving forces of -1.6 to -1.9 eV and estimated reorganization energies of about 1.0 eV. The observed electron-transfer kinetics have broadly distributed rates that are generally slower in the ionic liquids compared to the neutral solvents, which also have narrower rate distributions. To describe the broad distributions of electron-transfer kinetics, we use two different models: a distribution of exponential lifetimes and a discrete sum of exponential lifetimes. Analysis of the donor-acceptor electronic coupling shows that for ionic liquids this intramolecular electron-transfer reaction should be treated using a solvent-controlled electron-transfer model.

Wishart J. F.; Lee, H.Y.; Issa, J.B.; Isied, S.S.; Castner, Jr., E.W.; Pan, Y.; Hussey, C.L.; Lee, K.S.

2012-03-01T23:59:59.000Z

406

Viscosity and longest relaxation time of semi-dilute polymer solutions. I. Good solvent  

E-Print Network [OSTI]

1185 Viscosity and longest relaxation time of semi-dilute polymer solutions. I. Good solvent M expliqués par un modèle de reptation classique. Abstract. 2014 The zero shear viscosity and longest concentration (4 c/c* 70), we find that : 2014 both the relative viscosity ~r and the longest relaxation time TR

Paris-Sud XI, Université de

407

Volume 79, number 3 CHEMICAL PHYSICS LETTERS 1 hfay1981 EFFECTS OF CONFORMATION AND SOLVENT POLARITY  

E-Print Network [OSTI]

Volume 79, number 3 CHEMICAL PHYSICS LETTERS 1 hfay1981 EFFECTS OF CONFORMATION AND SOLVENT for molecules in extended con- formations, producing solvated ion pairs without passing through the exciplex of this is the relatively slow rate for intramolecular exciplex forma- tion (ns) in A-(CH,),-D 0 00 0 CHp12cH2 - a- N/CH3

Eisenthal, Kenneth B.

408

Roughening transition and formation of bicontinuous structures of immiscible solvents embedded in surfactant diblock copolymers  

E-Print Network [OSTI]

L-967 Roughening transition and formation of bicontinuous structures of immiscible solvents The roughening transition of the interface in a model mixture of amphiphilic diblock copolymers, two immiscible has a random nonperiodic structure throughout the sample volume. The roughening transition associated

Boyer, Edmond

409

Observation of Solvent Penetration during Cold Denaturation of E. coli Phosphofructokinase-2  

E-Print Network [OSTI]

Observation of Solvent Penetration during Cold Denaturation of E. coli Phosphofructokinase-2 Ce; unexpectedly, amide exchange increased throughout the protein over time at 3 C. The rate of increase in amide exchange over time at 3 C was the same for each region and equaled the rate of dimer dissociation measured

Komives, Elizabeth A.

410

Ten years of probabilistic estimates of biocrystal solvent content: new insights via nonparametric kernel density estimate  

Science Journals Connector (OSTI)

The widely used 2003 Matthews probability calculator predicting the most probable number of molecules in the asymmetric unit as a function of resolution has been updated with 2013 data, and a new parameter-free kernel density estimator has been implemented. Analysis of multiple parameters confirms that solvent content remains the primary and dominating parameter determining the diffraction limit (resolution) of protein crystals.

Weichenberger, C.X.

2014-05-24T23:59:59.000Z

411

Study of the surface tension of polymer solutions: theory and experiments in theta solvent conditions  

E-Print Network [OSTI]

1035 Study of the surface tension of polymer solutions: theory and experiments in theta solvent interest for experimental measurements. In a previous paper [ 11 ], the surface tension of semi Cedex 05, France (Reçu le 24 fevrier 1983, accepté le 30 mai 1983) Resumé. 2014 La tension superficielle

Paris-Sud XI, Université de

412

CRYSTAL GROWTH BY SOLVENT TECHNIQUES AND CHARACTERISTIC PROPERTIES OF CdTe  

E-Print Network [OSTI]

117 CRYSTAL GROWTH BY SOLVENT TECHNIQUES AND CHARACTERISTIC PROPERTIES OF CdTe T. TAGUCHI, J and holes are obtained. REVUE DE PHYSIQUE APPLIQUÃ?E TOME 12, FÃ?VRIER 1977, PAGE 117 1. Introduction. - CdTe during donor doping since CdTe has a strong tendency for self compensation However, in spite of a great

Paris-Sud XI, Université de

413

The Stability of Organic Solvents and Carbon Electrode in Nonaqueous Li-O2 Batteries  

SciTech Connect (OSTI)

The effect of different kinds of aprotic organic solvents on the discharge performance and discharge products in Li-O2 batteries was systematically investigated. The discharge products deposited in air cathodes were analyzed by X-ray diffraction, in situ gas chromatography/mass spectroscopy and X-ray photoelectron spectroscopy. We found that a significant amount of Li2O2 can be formed in glyme-based electrolytes during the discharge process, while only small amount of Li2O2 is produced in electrolytes of phosphate, nitrile, ionic liquid and sulfoxide. However, in all the seven types of solvent systems we studied, Li2CO3 and LiF were still formed as byproducts whose compositions are strongly related to the solvents. Li2CO3 is produced not from the carbon air electrode but from oxidation and decomposition of the solvent as we verified by using a 13C-labeled carbon electrode and the solid-state 13C-MAS NMR technique. The formation of Li2CO3 and LiF during discharge will greatly reduce the Coulombic efficiency and cycle life of the Li-air batteries. Therefore, better electrolytes that can ensure the formation of Li2O2 but minimize other reaction products formed on air electrodes of Li-air batteries need to be further investigated.

Xu, Wu; Hu, Jian Z.; Engelhard, Mark H.; Towne, Silas A.; Hardy, John S.; Xiao, Jie; Feng, Ju; Hu, Mary Y.; Zhang, Jian; Ding, Fei; Gross, Mark E.; Zhang, Jiguang

2012-05-18T23:59:59.000Z

414

The SX Solver: A Computer Program for Analyzing Solvent-Extraction Equilibria: Version 3.0  

SciTech Connect (OSTI)

A new computer program, the SX Solver, has been developed to analyze solvent-extraction equilibria. The program operates out of Microsoft Excel and uses the built-in Solver function to minimize the sum of the square of the residuals between measured and calculated distribution coefficients. The extraction of nitric acid by tributyl phosphate has been modeled to illustrate the programs use.

Lumetta, Gregg J.

2002-01-17T23:59:59.000Z

415

Molecular dynamics study of the weakly solvent dependent relaxation dynamics following chlorine dioxide photoexcitation  

E-Print Network [OSTI]

in population of the predissociative 2 A2 state which undergoes internal conversion to lower-energy excited, and virtually no contribution to energy gap relaxation is achieved through intramolecular solvent motions-temperature matrices.12­14 Current interest in OClO photochemistry in- volves understanding the factors responsible

416

Ultrafast Viscous Permeation of Organic Solvents Through Diamond-Like Carbon Nanosheets  

Science Journals Connector (OSTI)

...fig. S14 and table S3). This membrane thus offers an innovative ultrafiltration membrane for organic solvents. The observed flux is overwhelmingly...synthesis (23), production of biofuels (24), environmental remediation (25), and oil extraction in the food industry (19...

Santanu Karan; Sadaki Samitsu; Xinsheng Peng; Keiji Kurashima; Izumi Ichinose

2012-01-27T23:59:59.000Z

417

Molecular simulation study of nanoscale friction between alkyl monolayers on Si,,111... immersed in solvents  

E-Print Network [OSTI]

of friction at different interfaces in various solvents is very important to micro- or nanoelectro- mechanical.1063/1.1578055 I. INTRODUCTION Micro- or nanoelectromechanical systems MEMS/ NEMS are the integration/hydrophobic hydrophilic/hydrophilic hydro- philic/hydrophobic interfaces in water.8,13 Thus, it is ex- pected

Zhang, Luzheng

418

Natural and Enhanced Attenuation of Chlorinated Solvents Using RT3D  

SciTech Connect (OSTI)

RT3D (Reactive Transport in 3-Dimensions) is a reactive transport code that can be applied to model solute fate and transport for many different purposes. This document specifically addresses application of RT3D for modeling related to evaluation and implementation of Monitored Natural Attenuation (MNA). Selection of MNA as a remedy requires an evaluation process to demonstrate that MNA will meet the remediation goals. The U.S. EPA, through the Office of Solid Waste and Emergency Response (OSWER) Directive 9200.4?17P, provides the regulatory context for the evaluation and implementation of MNA. In a complementary fashion, the context for using fate and transport modeling as part of MNA evaluation is described in the EPA?s technical protocol for chlorinated solvent MNA, the Scenarios Evaluation Tool for Chlorinated Solvent MNA, and in this document. The intent of this document is to describe (1) the context for applying RT3D for chlorinated solvent MNA and (2) the attenuation processes represented in RT3D, (3) dechlorination reactions that may occur, and (4) the general approach for using RT3D reaction modules (including a summary of the RT3D reaction modules that are available) to model fate and transport of chlorinated solvents as part of MNA or for combinations of MNA and selected types of active remediation.

Johnson, Christian D.; Truex, Michael J.; Clement, T P.

2006-07-25T23:59:59.000Z

419

Liquefaction process wherein solvents derived from the material liquefied and containing increased concentrations of donor species are employed  

DOE Patents [OSTI]

An improved process for the liquefaction of solid carbonaceous materials wherein a solvent or diluent derived from the solid carbonaceous material being liquefied is used to form a slurry of the solid carbonaceous material and wherein the solvent or diluent comprises from about 65 to about 85 wt. % hydroaromatic components. The solvent is prepared by first separating a solvent or diluent distillate fraction from the liquefaction product, subjecting this distillate fraction to hydrogenation and then extracting the naphthenic components from the hydrogenated product. The extracted naphthenic components are then dehydrogenated and hydrotreated to produce additional hydroaromatic components. These components are combined with the solvent or diluent distillate fraction. The solvent may also contain hydroaromatic constituents prepared by extracting naphthenic components from a heavy naphtha, dehydrogenating the same and then hydrotreating the dehydrogenated product. When the amount of solvent produced in this manner exceeds that required for steady state operation of the liquefaction process a portion of the solvent or diluent distillated fraction will be withdrawn as product.

Fant, B. T. (Kingwood, TX); Miller, John D. (Baytown, TX); Ryan, D. F. (Friendswood, TX)

1982-01-01T23:59:59.000Z

420

Click grafting of seaweed bioactive polysaccharides onto PVC surfaces using ionic liquid as green solvent and catalyst  

E-Print Network [OSTI]

-6 . Their recyclable characteristics and their catalytic activities make them a green alternative to organic solventsClick grafting of seaweed bioactive polysaccharides onto PVC surfaces using ionic liquid as green solvent and catalyst Sandra Bigota , Guy Louarnb , Nasreddine Kébir*a and Fabrice Burela a Normandie

Boyer, Edmond

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Liquefaction process wherein solvents derived from the material liquefied and containing increased concentrations of donor species are employed  

SciTech Connect (OSTI)

An improved process is disclosed for the liquefaction of solid carbonaceous materials. A solvent or diluent derived from the solid carbonaceous material being liquefied is used to form a slurry of the solid carbonaceous material. The solvent or diluent comprises from about 65 to about 85 wt. % hydroaromatic components. The solvent is prepared by first separating a solvent or diluent distillate fraction from the liquefaction product, subjecting this distillate fraction to hydrogenation and then extracting the naphthenic components from the hydrogenated product. The extracted naphthenic components are then dehydrogenated and hydrotreated to produce additional hydroaromatic components. These components are combined with the solvent or diluent distillate fraction. The solvent may also contain hydroaromatic constituents prepared by extracting naphthenic components from a heavy naphtha, dehydrogenating the same and then hydrotreating the dehydrogenated product. When the amount of solvent produced in this manner exceeds that required for steady state operation of the liquefaction process a portion of the solvent or diluent distillated fraction will be withdrawn as product.

Fant, B.; Miller, J.D.; Ryan, D.F.

1982-01-19T23:59:59.000Z

422

Tunable Solvents for Homogeneous Catalyst Recycle Jie Lu, Michael J. Lazzaroni, Jason P. Hallett, Andreas S. Bommarius,  

E-Print Network [OSTI]

Tunable Solvents for Homogeneous Catalyst Recycle Jie Lu, Michael J. Lazzaroni, Jason P. Hallett-0100 A novel class of tunable solvents facilitates recycle of homogeneous catalysts for both economic-soluble catalysts and moderately hydrophobic substrates can be run homoge- neously, with subsequent phase separation

423

Hydrogen Bond Lifetimes and Energetics for Solute/Solvent Complexes Studied with 2D-IR Vibrational Echo Spectroscopy  

E-Print Network [OSTI]

Hydrogen Bond Lifetimes and Energetics for Solute/Solvent Complexes Studied with 2D-IR Vibrational@stanford.edu Abstract: Weak hydrogen-bonded solute/solvent complexes are studied with ultrafast two the dissociation and formation rates of the hydrogen-bonded complexes. The dissociation rates of the weak hydrogen

Fayer, Michael D.

424

Microbial process for the preparation of acetic acid as well as solvent for its extraction from the fermentation broth  

DOE Patents [OSTI]

A modified water-immiscible solvent useful in the extraction of acetic acid from aqueous streams is a substantially pure mixture of isomers of highly branched di-alkyl amines. This solvent is substantially devoid of mono-alkyl amines and alcohols. Solvent mixtures formed of such a modified solvent with a desired cosolvent, preferably a low boiling hydrocarbon which forms an azeotrope with water are useful in the extraction of acetic acid from aqueous gaseous streams. An anaerobic microbial fermentation process for the production of acetic acid employs such solvents, under conditions which limit amide formation by the solvent and thus increase the efficiency of acetic acid recovery. Methods for the direct extraction of acetic acid and the extractive fermentation of acetic acid also employ the modified solvents and increase efficiency of acetic acid production. Such increases in efficiency are also obtained where the energy source for the microbial fermentation contains carbon dioxide and the method includes a carbon dioxide stripping step prior to extraction of acetic acid in solvent.

Gaddy, James L. (Fayetteville, AR); Clausen, Edgar C. (Fayetteville, AR); Ko, Ching-Whan (Fayetteville, AR); Wade, Leslie E. (Corpus Christi, TX); Wikstrom, Carl V. (Fayetteville, AR)

2002-01-01T23:59:59.000Z

425

Numerical simulation of discharge structures in Ar/Cs nonequilibrium plasma MHD generator  

SciTech Connect (OSTI)

As reported in previous papers, the quasi-one-dimensional simulation code has come to predict almost satisfactorily the performance of the shock tube driven disk MHD generator using cesium seeded argon plasma as working fluid. However, the agreement between experimental and predicted performances was not so good on the conditions that the external load resistance was small, the seed fraction was high or the stagnation pressure was low. On these conditions, it was observed that ionization instabilities occur in the MHD channel. On the other hand, high-speed photographs of the nonequilibrium plasma discharge in the MHD generator were taken on several working conditions during the experiment. From these photographs, discharges were classified into almost three kinds of patterns. (a) A single strong luminous ring-type discharge near the nozzle exit for low seed fraction, (b) an almost uniform discharge inside the MHD channel for medium seed fraction, (c) multiple ring-type or spiral discharges in the MHD channel for high seed fraction. The structures of the discharge were sometimes two-dimensional especially for high seed fraction. Therefore, it may be impossible in this case to simulate them and to predict the performance precisely with one-dimensional simulation code. In the present study, two-dimensional (r-q) numerical simulations were made on the disk MHD power generation experiment (thermal input is about 1.5MW). The objectives were to develop a numerical simulator with high accuracy for the disk MHD generator and to explain some interesting phenomena concerned with nonequilibrium plasma discharges. The system of basic equations was solved mainly using CIP method. The calculation region was taken as that located between the throat to the inlet of the second (final) cathode. The main results are summarized as follows; (A) On the condition that the seed fraction was lower than the optimum value, it was succeeded to simulate numerically the single strong luminous ring-type discharge. The ring-type discharge was caused by the partial ionization of argon due to the rapid increase in the electron temperature in the nozzle. The pressure increase like a shock wave was also induced there. (B) On the condition that the seed fraction was near the optimum value, an almost uniform plasma was obtained in the simulation and in the experiment. (C) On the condition that seed fraction was higher than the optimum value, A similar structure of discharge to experimental one was obtained in the calculation due to an ionization instability (streamer) caused by the partial ionization of seeded cesium. (D) The performances of the generator such as enthalpy extraction can be predicted well with this simulation code.

Okubo, M.; Kabashima, S.; Okuno, Y.; Yamasaki, H.

1998-07-01T23:59:59.000Z

426

Influence of solvent on the antioxidant and antimicrobial properties of walnut (Juglans regia L.) green husk extracts  

Science Journals Connector (OSTI)

Walnut green husk is an agro-forest waste generated in the walnut (Juglans regia L.) harvest that could be valued as a source of natural compounds with antioxidant and antimicrobial properties. At this respect, the effect of the solvent (water, methanol, ethanol and 50% aqueous solutions of methanol and ethanol) on the extraction yields and extracts bioactive properties was analysed. Total phenols content of the extracts was determined by the Folin–Ciocalteau method. Extract antioxidant activity was evaluated using the reducing power assay and by the ability of the extracts to scavenge the DPPH radical. The scavenging effect of the aqueous extracts on the nitric oxide radical was also evaluated. The highest extraction yield was achieved with water (44.11%) and high bioactive potential was shown by the samples extracted with water/ethanol (1:1) (84.46 mg GAE/g extract; EC50 = 0.95 mg/mL for reducing power and EC50 = 0.33 mg/mL for DPPH assay). All the antioxidant properties analysed showed a concentration-dependent activity. The antimicrobial activity of the aqueous extracts was assessed and showed ability to inhibit the growth of Gram positive bacteria. The results obtained demonstrated the potential of the walnut green husk as an economical source of antioxidant and antimicrobial agents.

A. Fernández-Agulló; E. Pereira; M.S. Freire; P. Valentão; P.B. Andrade; J. González-Álvarez; J.A. Pereira

2013-01-01T23:59:59.000Z

427

NETL: Bench-Scale Development of a Non-Aqueous Solvent CO2 Capture Process  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bench-Scale Development of a Non-Aqueous Solvent (NAS) CO2 Capture Process for Coal-Fired Power Plants Bench-Scale Development of a Non-Aqueous Solvent (NAS) CO2 Capture Process for Coal-Fired Power Plants Project No.: DE-FE0013865 Research Triangle Institute (RTI) is continuing the development process for a non-aqueous solvent (NAS)-based CO2 capture process that was originated at laboratory scale under an ARPA-E project. This project will conduct bench-scale testing to show the potential of the technology to reduce the parasitic energy penalty. Key technical and economic challenges and uncertainties to be addressed include solvent makeup cost, scalable regenerator design, development of a complete NAS process arrangement, and improved confidence in the capital cost estimate that will enable the scale up of the process. One major focus is identification of best-candidate NAS formulations. This will entail reducing solvent makeup costs by reducing the formulation cost. In addition, efforts will be made to reduce evaporative and degradation losses while maintaining the desired CO2 absorption chemistry. A second focus area involves advancing the design of the process. This will be done by developing and evaluating the effectiveness of two process units specific to NASs - the NAS Recovery/Wash Section and NAS Regenerator. As the project proceeds, the testing campaign will evaluate thermal regeneration energy requirements [kJt / kg CO2] and develop a detailed understanding of the operation of the process. Preliminary analyses indicate that the NAS process can reduce energy consumption by 30 to 50 percent compared to current state of the art CO2 capture processes.

428

Development of a Conceptual Process for Selective CO{sub 2} Capture from Fuel Gas Streams Using [hmim][Tf2N] Ionic Liquid as a Physical Solvent  

SciTech Connect (OSTI)

The Ionic Liquid (IL) [hmim][Tf2N] was used as a physical solvent in an Aspen Plus simulation, employing the Peng-Robinson Equation of State (P-R EOS) with Boston-Mathias (BM) alpha function and standard mixing rules, to develop a conceptual process for CO{sub 2} capture from a shifted warm fuel gas stream produced from Pittsburgh # 8 coal for a 400 MWe power plant. The physical properties of the IL, including density, viscosity, surface tension, vapor pressure and heat capacity were obtained from literature and modeled as a function of temperature. Also, available experimental solubility values for CO{sub 2}, H{sub 2}, H{sub 2}S, CO, and CH{sub 4} in this IL were compiled and their binary interaction parameters ({delta}{sub ij} and l{sub ij}) were optimized and correlated as functions of temperature. The Span-Wager Equation-of-State EOS was also employed to generate CO{sub 2} solubilities in [hmim][Tf2N] at high pressures (up to 10 MPa) and temperatures (up to 510 K). The conceptual process developed consisted of 4 adiabatic absorbers (2.4 m ID, 30 m high) arranged in parallel and packed with Plastic Pall Rings of 0.025 m for CO{sub 2} capture; 3 flash drums arranged in series for solvent (IL) regeneration with the pressure-swing option; and a pressure-intercooling system for separating and pumping CO{sub 2} up to 153 bar to the sequestration sites. The compositions of all process streams, CO{sub 2} capture efficiency, and net power were calculated using Aspen Plus simulator. The results showed that, based on the composition of the inlet gas stream to the absorbers, 95.67 mol% of CO{sub 2} was captured and sent to sequestration sites; 99.5 mol% of H{sub 2} was separated and sent to turbines; the solvent exhibited a minimum loss of 0.31 mol%; and the net power balance of the entire system was 30.81 MW. These results indicated that [hmim][Tf2N] IL could be used as a physical solvent for CO{sub 2} capture from warm shifted fuel gas streams with high efficiency.

Basha, Omar M.; Keller, Murphy J.; Luebke, David R.; Resnik, Kevin; P Morsi, Badie I.

2013-07-01T23:59:59.000Z

429

Contaminant-Generation Mechanisms  

Science Journals Connector (OSTI)

In the last chapter, the areas where contaminants are generated were discussed. Knowing the location of contaminant generation is helpful in controlling that contamination, but understanding the mechanisms is ...

Alvin Lieberman

1992-01-01T23:59:59.000Z

430

Using Backup Generators  

Broader source: Energy.gov [DOE]

Power outages are commonplace during disasters, and they may last for several days. You can reduce losses and speed the recovery process by installing an emergency generator. Portable generators...

431

X-Ray Generators  

Science Journals Connector (OSTI)

There are many types of X-ray generators sold commercially. The following are some of ... that should be considered when selecting a particular generator for a particular purpose. All the companies listed below s...

Reuben Rudman

1972-01-01T23:59:59.000Z

432

Geothermal Power Generation  

SciTech Connect (OSTI)

The report provides an overview of the renewed market interest in using geothermal for power generation including a concise look at what's driving interest in geothermal power generation, the current status of geothermal power generation, and plans for the future. Topics covered in the report include: an overview of geothermal power generation including its history, the current market environment, and its future prospects; an analysis of the key business factors that are driving renewed interest in geothermal power generation; an analysis of the challenges that are hindering the implementation of geothermal power generation projects; a description of geothermal power generation technologies; a review of the economic drivers of geothermal power generation project success; profiles of the major geothermal power producing countries; and, profiles of the major geothermal power project developers.

NONE

2007-11-15T23:59:59.000Z

433

A Generative Dependency Grammar  

Science Journals Connector (OSTI)

We propose a new kind of grammar: the Generative Dependency Grammar (GDG) based on dependency trees (DT) and a generative process. By generating a surface text using these GDG, the DT of the text is obtained too. GDG formalism is starting to be used ...

Stefan Diaconescu

2002-08-01T23:59:59.000Z

434

Controlling Pattern Formation in Nanoparticle Assemblies via Directed Solvent Dewetting Christopher P. Martin, Matthew O. Blunt, Emmanuelle Pauliac-Vaujour, Andrew Stannard, and Philip Moriarty*  

E-Print Network [OSTI]

Controlling Pattern Formation in Nanoparticle Assemblies via Directed Solvent Dewetting Christopher highly localized control of pattern formation in two-dimensional nanoparticle assemblies by direct modification of solvent dewetting dynamics. A striking dependence of nanoparticle organization on the size

Nielsen, Steven O.

435

J. Chem. Sci. Vol. 123, No. 3, May 2011, pp. 265277. c Indian Academy of Sciences. Excited state charge transfer reaction in (mixed solvent + electrolyte)  

E-Print Network [OSTI]

-propanol + ethyl acetate) and (propylene carbonate + acetonitrile), in the absence and presence of a strong electrolyte, lithium perchlorate. These two sets of mixed solvent systems represent binary solvent mixtures

Biswas, Ranjit

436

Computer Simulation of a "Green Chemistry" Room-Temperature Ionic Solvent C. J. Margulis, H. A. Stern, and B. J. Berne*  

E-Print Network [OSTI]

Computer Simulation of a "Green Chemistry" Room-Temperature Ionic Solvent C. J. Margulis, H. A, room-temperature ionic liquids are currently being investigated as alternative solvents in industry that is clean, recyclable, and a good solvent for both organic and inorganic compounds is appealing

Berne, Bruce J.

437

PEER-REVIEWED ARTICLE bioresources.com Chang et al. (2012). "Swelling green wood in solvents," BioResources 7(2), 2418-2430. 2418  

E-Print Network [OSTI]

PEER-REVIEWED ARTICLE bioresources.com Chang et al. (2012). "Swelling green wood in solvents," BioResources 7(2), 2418-2430. 2418 SOLVENT POLARITY AND INTERNAL STRESSES CONTROL THE SWELLING BEHAVIOUR OF GREEN,b and Bruno Clair a, * The dimensional variations of green wood samples induced by organic solvents have been

Paris-Sud XI, Université de

438

Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Solvent Tuning of Properties of Solvent Tuning of Properties of Iron-Sulfur Clusters in Proteins Figure 1. Schematic repre-sentation of the common active-site iron-sulfur cluster structural motif. Proteins containing Fe4S4 iron-sulfur clusters are ubiquitous in nature and catalyze one-electron transfer processes. These proteins have evolved into two classes that have large differences in their electrochemical potentials: high potential iron-sulfur proteins (HiPIPs) and bacterial ferredoxins (Fds). The role of the surrounding protein environment in tuning the redox potential of these iron sulfur clusters has been a persistent puzzle in biological electron transfer [1]. Although HiPIPs and Fds have the same iron sulfur structural motif - a cubane-type structure - (Figure 1), there are large differences in their electrochemical

439

In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents  

DOE Patents [OSTI]

An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants are described. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating. 21 figs.

Taylor, R.T.; Jackson, K.J.; Duba, A.G.; Chen, C.I.

1998-05-19T23:59:59.000Z

440

In situ thermally enhanced biodegradation of petroleum fuel hydrocarbons and halogenated organic solvents  

DOE Patents [OSTI]

An in situ thermally enhanced microbial remediation strategy and a method for the biodegradation of toxic petroleum fuel hydrocarbon and halogenated organic solvent contaminants. The method utilizes nonpathogenic, thermophilic bacteria for the thermal biodegradation of toxic and carcinogenic contaminants, such as benzene, toluene, ethylbenzene and xylenes, from fuel leaks and the chlorinated ethenes, such as trichloroethylene, chlorinated ethanes, such as 1,1,1-trichloroethane, and chlorinated methanes, such as chloroform, from past solvent cleaning practices. The method relies on and takes advantage of the pre-existing heated conditions and the array of delivery/recovery wells that are created and in place following primary subsurface contaminant volatilization efforts via thermal approaches, such as dynamic underground steam-electrical heating.

Taylor, Robert T. (Livermore, CA); Jackson, Kenneth J. (San Leandro, CA); Duba, Alfred G. (Livermore, CA); Chen, Ching-I (Danville, CA)

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "generation cesium solvent" from the National Library of EnergyBeta (NLEBeta).
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441

Organic solvent-free water-developable sugar resist material derived from biomass in green lithography  

Science Journals Connector (OSTI)

Abstract We have demonstrated an organic solvent-free water-developable branched sugar resist material derived from biomass for its use in green electron beam lithography. This emphasizes the use of plant products instead of conventionally used tetramethylammonium hydroxide and organic solvents. The rationally designed water-developable branched sugar resist material developed in this study can be patterned with an excellent sensitivity of 7 ?C/cm2 and a resolution of 50–200 nm lines. In addition, it indicated sufficient thermal stability at ?180 °C, acceptable CF4 etch selectivity with a hardmask material, 42–53% rate of chemical reaction of acryloyl groups affected by the tacticity of branched sugar chain polymers, and developable in pure water at 23 °C for 60 s.

Satoshi Takei; Akihiro Oshima; Takumi Ichikawa; Atsushi Sekiguchi; Miki Kashiwakura; Takahiro Kozawa; Seiichi Tagawa; Tomoko G. Oyama; Syoji Ito; Hiroshi Miyasaka

2014-01-01T23:59:59.000Z

442

Unsaturated Phosphazenes as Co-Solvents for Lithium-Ion Battery Electrolytes  

SciTech Connect (OSTI)

This paper covers the synthesis and use of a related family of cyclic phosphazene solvents containing terminal unsaturations. A brief synopsis on the synthesis and purification of these compounds is given. Data will be presented that covers physical and chemical properties of the phosphazenes as well as the properties when blended at various level with representative organic carbonate baseline solvents. Cycling data will be presented using commercially available electrode couples (LRMR/C) as well as studies focusing on cell performance at early lifetime as well as after repeated cycles. Conclusions regarding the effect of the unsaturated phosphazene compounds and their interaction with various alkyl carbonates, and their effect on cell performance will be presented.

Mason K Harrup; Harry W. Rollins; David K. Jamison; Eric J Dufek; Kevin L Gering; Thomas A Luther

2014-07-01T23:59:59.000Z

443

DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS  

SciTech Connect (OSTI)

The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. The largest applications are those which support metals smelting, such as anodes for aluminum smelting and electrodes for arc furnaces. Other carbon products include materials used in creating fuels for the Direct Carbon Fuel Cell, and porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, hydrotreatment of solvent was completed in preparation for pitch fabrication for graphite electrodes. Coal digestion has lagged but is expected to be complete by next quarter. Studies are reported on coal dissolution, pitch production, foam synthesis using physical blowing agents, and alternate coking techniques.

Dady B. Dadyburjor; Mark E. Heavner; Manoj Katakdaunde; Liviu Magean; J. Joshua Maybury; Alfred H. Stiller; Joseph M. Stoffa; John W. Zondlo

2006-08-01T23:59:59.000Z

444

Effects of solvent recycling on radiolytic degradation of 30% tributyl phosphate--n-dodecane-HNO{sub 3} system  

SciTech Connect (OSTI)

Samples of 30% tributyl phosphate (TBP)-n-dodecane-HNO{sub 3} undergoing gamma radiolysis with and without solvent cleanup have been examined by GLC and IR spectrometry. In order to assess the rate of buildup of various radiolytic species in the solvent, their relative hydrophobicities with respect to alkaline wash have been determined. The differences in the Pu extraction and retention behaviors of the two solvent systems with increasing dose are explained in terms of the formation of derivatives of nitroparaffins and high molecular weight organophosphates.

Tripathi, S.C.; Sumathi, S.; Ramanujam, A.

1999-10-01T23:59:59.000Z

445

DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS  

SciTech Connect (OSTI)

The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the development of continuous processes for hydrogenation as well as continuous production of carbon foam and coke.

Elliot B. Kennel; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

2005-06-08T23:59:59.000Z

446

Development of Continuous Solvent Extraction Processes for Coal Derived Carbon Products  

SciTech Connect (OSTI)

This DOE NETL-sponsored effort seeks to develop continuous processes for producing carbon products from solvent-extracted coal. A key process step is removal of solids from liquefied coal. Three different processes were compared: gravity separation, centrifugation using a decanter-type Sharples Pennwalt centrifuge, and a Spinner-II centrifuge. The data suggest that extracts can be cleaned to as low as 0.5% ash level and probably lower using a combination of these techniques.

Elliot B. Kennel

2006-12-31T23:59:59.000Z

447

Passivating ligand and solvent contributions to the electronic properties of semiconductor nanocrystals  

SciTech Connect (OSTI)

We examine in detail the impact of passivating ligands (i.e., amines, phosphines, phosphine oxides and pyridines) on the electronic and optical spectra of Cd{sub 33}Se{sub 33} quantum dots (QDs) using density functional theory (DFT) and time-dependent DFT (TDDFT) quantum-chemical methodologies. Most ligand orbitals are found deep inside in the valence and conduction bands of the QD, with pyridine being an exception by introducing new states close to the conduction band edge. Importantly, all ligands contribute states which are highly delocalized over both the QD surface and ligands, forming hybridized orbitals rather than ligand-localized trap states. In contrast, the states close to the band gap are delocalized over the QD atoms only and define the lower energy absorption spectra. The random detachment of one of ligands from the QD surface results in the appearance of a highly localized unoccupied state inside the energy gap of the QD. Such changes in the electronic structure are correlated with the respective QD-ligand binding energy and steric ligand-ligand interactions. Polar solvent significantly reduces both effects leading to delocalization and stabilization of the surface states. Thus, trap and surface states are substantially eliminated by the solvent. Polar solvent also blue-shifts (e.g., 0.3-0.4 eV in acetonitrile) the calculated absorption spectra. This shift increases with an increase of the dielectric constant of the solvent. We also found that the approximate single-particle Kohn-Sham (KS) approach is adequate for calculating the absorption spectra of the ligated QDs. Besides a systematic blue-shift, the KS spectra are in very good agreement with their respective counterparts calculated with the more accurate TDDFT method.

Fischer, S.; Crotty, A.; Kilina, S.; Ivanov, I.; Tretiak, S

2012-01-01T23:59:59.000Z

448

The SX Solver: A New Computer Program for Analyzing Solvent-Extraction Equilibria  

SciTech Connect (OSTI)

A new computer program, the SX Solver, has been developed to analyze solvent-extraction equilibria. The program operates out of Microsoft Excel{reg_sign} and uses the built-in ''Solver'' function to minimize the sum of the square of the residuals between measured and calculated distribution coefficients. The extraction of nitric acid by tributylphosphate has been modeled to illustrate the program's use.

McNamara, B.K.; Rapko, B.M.; Lumetta, G.J.

1999-02-09T23:59:59.000Z

449

The SX Solver: A New Computer Program for Analyzing Solvent-Extraction Equilibria.  

SciTech Connect (OSTI)

A new computer program, the SX Solver, has been developed to analyze solvent-extraction equilibria. The program operates out of Microsoft Excel{reg_sign} and uses the built-in ''Solver'' function to minimize the sum of the square of the residuals between measured and calculated distribution coefficients. The extraction of nitric acid by tributyl phosphate has been modeled to illustrate the program's use.

Lumetta, Gregg J; McNamara, Bruce K; Rapko, Brian M

1999-01-08T23:59:59.000Z

450

The effect of the volume of liquid injected on recovery in solvent slug flooding  

E-Print Network [OSTI]

the effect of slug size on oil recovered. A series of verti. cal displacements was performed on a kerosene- and-water saturated core 10 feet in length, using butane as the solvent and methane as the inert dksplacing medium. Breakthrough recovery was fo... storage problem, it mrght be ea, sily possible to solve two difficultres 11 simultaneously, as suggested by Kennedy. The LPG is easily recovered following the displacement by the srmple expedient of blowing down the reservoir, Much interest has...

Bowman, Charles Hay

1959-01-01T23:59:59.000Z

451

DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS  

SciTech Connect (OSTI)

The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the facility modifications for continuous hydrotreating, as well as developing improved protocols for producing synthetic pitches.

Elliot B. Kennel; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

2005-08-11T23:59:59.000Z

452

DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS  

SciTech Connect (OSTI)

The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. During this reporting period, efforts have focused on the development of continuous processes for hydrogenation as well as continuous production of carbon foam and coke.

Elliot B. Kennel; Stephen P. Carpenter; Dady Dadyburjor; Manoj Katakdaunde; Liviu Magean; Madhavi Nallani-Chakravartula; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

2006-03-27T23:59:59.000Z

453

Batch polymerization of styrene initiated by n-butyl lithium in a cyclohexane solvent  

E-Print Network [OSTI]

anionic mechanism. A mathematical model is de- veloped and the predicted values are compared with their corresponding experimental values. Initiator and monomer concentrations are varied and their conversion time profiles are studied. A G&el... and Storage Vessels Purification of Monomer Purification of Solvent Polymerization Reaction Scavenger Level Analysis o f Butyl Lithium Analysis of Molecular Weight Distributions by the Use of Gel Permeation Technique 10 19 19 ZO Zl ZZ 24 25 25...

Landon, Thomas Rodman

1971-01-01T23:59:59.000Z

454

COAL CLEANING VIA LIQUID-FLUIDIZED CLASSIFICAITON (LFBC) WITH SELECTIVE SOLVENT SWELLING  

SciTech Connect (OSTI)

The concept of coal beneficiation due to particle segregation in water-fluidized beds, and its improvement via selective solvent-swelling of organic material-rich coal particles, was investigated in this study. Particle size distributions and their behavior were determined using image analysis techniques, and beneficiation effects were explored via measurements of the ash content of segregated particle samples collected from different height locations in a 5 cm diameter liquid-fluidized bed column (LFBC). Both acetone and phenol were found to be effective swelling agents for both Kentucky No.9 and Illinois No.6 coals, considerably increasing mean particle diameters, and shifting particle size distributions to larger sizes. Acetone was a somewhat more effective swelling solvent than phenol. The use of phenol was investigated, however, to demonstrate that low cost, waste solvents can be effective as well. For unswollen coal particles, the trend of increasing particle size from top to bottom in the LFBC was observed in all cases. Since the organic matter in the coal tends to concentrate in the smaller particles, the larger particles are typically denser. Consequently, the LFBC naturally tends to separate coal particles according to mineral matter content, both due to density and size. The data for small (40-100 {micro}m), solvent-swollen particles clearly showed improved beneficiation with respect to segregation in the water-fluidized bed than was achieved with the corresponding unswollen particles. This size range is quite similar to that used in pulverized coal combustion. The original process concept was amply demonstrated in this project. Additional work remains to be done, however, in order to develop this concept into a full-scale process.

J. M. Calo

2000-12-01T23:59:59.000Z

455

Reversible Ionic Liquids as Double-action Solvents for Efficient CO2 Capture  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reversible Ionic Liquids as Double-action Reversible Ionic Liquids as Double-action Solvents for Efficient CO 2 Capture Background Post-combustion carbon dioxide (CO 2 ) capture presents technical challenges because the flue gas is at atmospheric pressure and the CO 2 concentration is 10 to 15 volume percent, resulting in a low CO 2 partial pressure and a large volume of gas that needs to be treated. In spite of this difficulty, post-combustion CO 2 capture offers the

456

Steam generator support system  

DOE Patents [OSTI]

A support system for connection to an outer surface of a J-shaped steam generator for use with a nuclear reactor or other liquid metal cooled power source. The J-shaped steam generator is mounted with the bent portion at the bottom. An arrangement of elongated rod members provides both horizontal and vertical support for the steam generator. The rod members are interconnected to the steam generator assembly and a support structure in a manner which provides for thermal distortion of the steam generator without the transfer of bending moments to the support structure and in a like manner substantially minimizes forces being transferred between the support structure and the steam generator as a result of seismic disturbances.

Moldenhauer, James E. (Simi Valley, CA)

1987-01-01T23:59:59.000Z

457

Steam generator support system  

DOE Patents [OSTI]

A support system for connection to an outer surface of a J-shaped steam generator for use with a nuclear reactor or other liquid metal cooled power source is disclosed. The J-shaped steam generator is mounted with the bent portion at the bottom. An arrangement of elongated rod members provides both horizontal and vertical support for the steam generator. The rod members are interconnected to the steam generator assembly and a support structure in a manner which provides for thermal distortion of the steam generator without the transfer of bending moments to the support structure and in a like manner substantially minimizes forces being transferred between the support structure and the steam generator as a result of seismic disturbances. 4 figs.

Moldenhauer, J.E.

1987-08-25T23:59:59.000Z

458

generation | OpenEI  

Open Energy Info (EERE)

generation generation Dataset Summary Description This dataset comes from the Energy Information Administration (EIA), and is part of the 2011 Annual Energy Outlook Report (AEO2011). This dataset is table 16, and contains only the reference case. Source EIA Date Released April 26th, 2011 (3 years ago) Date Updated Unknown Keywords AEO generation renewable energy renewable energy generating capacity Data application/vnd.ms-excel icon AEO2011: Renewable Energy Generating Capacity and Generation- Reference Case (xls, 118.9 KiB) Quality Metrics Level of Review Peer Reviewed Comment Temporal and Spatial Coverage Frequency Annually Time Period 2008-2035 License License Open Data Commons Public Domain Dedication and Licence (PDDL) Comment Rate this dataset Usefulness of the metadata

459

Coupling a Transient Solvent Extraction Module with the Separations and Safeguards Performance Model  

SciTech Connect (OSTI)

A past difficulty in safeguards design for reprocessing plants is that no code existed for analysis and evaluation of the design. A number of codes have been developed in the past, but many are dated, and no single code is able to cover all aspects of materials accountancy, process monitoring, and diversion scenario analysis. The purpose of this work was to integrate a transient solvent extraction simulation module developed at Oak Ridge National Laboratory, with the SSPM Separations and Safeguards Performance Model, developed at Sandia National Laboratory, as a first step toward creating a more versatile design and evaluation tool. The SSPM was designed for materials accountancy and process monitoring analyses, but previous versions of the code have included limited detail on the chemical processes, including chemical separations. The transient solvent extraction model is based on the ORNL SEPHIS code approach to consider solute build up in a bank of contactors in the PUREX process. Combined, these capabilities yield a much more robust transient separations and safeguards model for evaluating safeguards system design. This coupling and the initial results are presented. In addition, some observations toward further enhancement of separations and safeguards modeling based on this effort are provided, including: items to be addressed in