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We encourage you to perform a real-time search of NLEBeta
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1

Gasohol - Where We Are Today  

E-Print Network [OSTI]

With the advent of the crude oil price increases, associated with the Middle East crisis, many countries, particularly Brazil, began producing ethanol for the use as fuel in mixture with gasoline. In the United States, 'gasohol', a blend...

McCammon, W. L.

1982-01-01T23:59:59.000Z

2

Vehicle Technologies Office: Fact #351: December 20, 2004 Gasohol Use Is Up  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1: December 20, 1: December 20, 2004 Gasohol Use Is Up to someone by E-mail Share Vehicle Technologies Office: Fact #351: December 20, 2004 Gasohol Use Is Up on Facebook Tweet about Vehicle Technologies Office: Fact #351: December 20, 2004 Gasohol Use Is Up on Twitter Bookmark Vehicle Technologies Office: Fact #351: December 20, 2004 Gasohol Use Is Up on Google Bookmark Vehicle Technologies Office: Fact #351: December 20, 2004 Gasohol Use Is Up on Delicious Rank Vehicle Technologies Office: Fact #351: December 20, 2004 Gasohol Use Is Up on Digg Find More places to share Vehicle Technologies Office: Fact #351: December 20, 2004 Gasohol Use Is Up on AddThis.com... Fact #351: December 20, 2004 Gasohol Use Is Up Gasohol, a blend of fuel containing gasoline and 5.7-10% ethanol, has a

3

Exhaust and evaporative emissions from gasohol-type fuels  

SciTech Connect (OSTI)

An experimental study was conducted at the US Department of Energy's Bartlesville (Okla.) Energy Technology Center in cooperation with the Environmental Protection Agency to determine the characteristics of gasohol-type fuels with respect to exhaust and evaporative emissions. Five fuels, 2 gasolines (reference and commercial unleaded) and 3 gasohols (90% gasoline/10% ethanol) were tested in a fleet of 10 late-model automobiles. Six were equipped with oxidation catalysts and 4 were equipped with three-way catalysts. The results obtained from the 1978 Federal test procedure indicate that the addition of ethanol to the base gasoline, whether it is a reference fuel (Indolene) or a commercial fuel, has measurable effects on exhaust and evaporative emissions. However, on the average, the magnitude of these effects was generally within the 1978 emission standards established by the EPA. More specifically, the addition of ethanol, in the case of vehicles with oxidation catalysts, decreased hydrocarbons by an average of 27%, decreased carbon monoxide by 43%, decreased volumetric fuel economy by 3%, and increased oxides of nitrogen by 16%. Evaporative emissions were increased by 40%. In the case of vehicles with three-way catalysts, the addition of ethanol to the base fuel, on the average, decreased carbon monoxide by 7%, decreased fuel economy by 5%, increased hydrocarbons by 12%, increased oxides of nitrogen by 7%, and increased evaporative emissions by 49%.

Naman, T.M.; Allsup, J.R.

1980-08-01T23:59:59.000Z

4

Liquid--liquid equilibria by use of UNIFAC for gasohol extraction systems  

SciTech Connect (OSTI)

A synthetic naphtha cut composed of a mixture of paraffinic, aromatic, and naphthenic hydrocarbons has been studied as a solvent to directly produce gasohol. The equilibria in these highly nonideal liquid mixtures has been estimated by the UNIFAC group contribution method. The process would appear to be simple and direct to produce gasohol by liquid--liquid extraction with this naphtha and could compete with existing azeotropic distillation processes.

Furzer, I.A.

1984-04-01T23:59:59.000Z

5

THE FEDERAL HIGHWAY ADMINISTRATION GASOHOL CONSUMPTION ESTIMATION MODEL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

10 10 THE FEDERAL HIGHWAY ADMINISTRATION GASOHOL CONSUMPTION ESTIMATION MODEL August 2003 Ho-Ling Hwang Lorena F. Truett Stacy C. Davis DOCUMENT AVAILABILITY Reports produced after January 1, 1996, are generally available free via the U.S. Department of Energy (DOE) Information Bridge. Web site http://www.osti.gov/bridge Reports produced before January 1, 1996, may be purchased by members of the public from the following source. National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Telephone 703-605-6000 (1-800-553-6847) TDD 703-487-4639 Fax 703-605-6900 E-mail info@ntis.fedworld.gov Web site http://www.ntis.gov/support/ordernowabout.htm Reports are available to DOE employees, DOE contractors, Energy Technology Data Exchange

6

Environmental implications of accelerated gasohol production: preliminary assessment  

SciTech Connect (OSTI)

This report assesses the environmental impacts of increasing US production of fuel ethanol by 330 million gallons per year in the 1980 to 1981 time frame in order to substitute gasohol for 10% of the unleaded gasoline consumed in the United States. Alternate biomass feedstocks are examined and corn is selected as the most logical feedstock, based on its availability and cost. Three corn conversion processes that could be used to attain the desired 1980 to 1981 production are identified; fermentation plants that use a feedstock of starch and wastes from an adjacent corn refining plants are found to have environmental and economic advantages. No insurmountable environmental problems can be achieved using current technology; the capital and operating costs of this control are estimated. If ethanol production is increased substantially after 1981, the environmentally acceptable use or disposal of stillage, a liquid by-product of fermentation, could become a serious problem.

Not Available

1980-01-01T23:59:59.000Z

7

Farm Fuel Safety Accidents in the handling, use and storage of gasoline, gasohol, diesel fuel, LP-gas and  

E-Print Network [OSTI]

112 Farm Fuel Safety Accidents in the handling, use and storage of gasoline, gasohol, diesel fuel and by keeping fuel storage facilities in top condition. Flammable Liquids and Gases Gasoline, diesel fuel, LP flammability and safety precautions. Do not keep gasoline inside the home or transport it in the trunks

8

Countries Diesel Prices Excluding Taxes  

Gasoline and Diesel Fuel Update (EIA)

excluding taxes) excluding taxes) Date Belgium France Germany Italy Netherlands UK US 01/13/14 3.56 3.46 3.55 3.80 3.63 3.57 3.40 01/06/14 3.70 3.49 3.62 3.82 3.63 3.55 3.43 12/30/13 NA NA NA NA NA NA 3.42 12/23/13 NA NA NA NA NA NA 3.39 12/16/13 3.63 3.50 3.71 3.85 3.71 3.56 3.38 12/9/13 3.83 3.53 3.77 3.86 3.72 3.57 3.39 12/2/13 3.70 3.46 3.75 3.80 3.67 3.53 3.40 11/25/13 3.60 3.38 3.74 3.75 3.61 3.48 3.36 11/18/13 3.74 3.36 3.67 3.70 3.55 3.45 3.33 11/11/13 3.57 3.34 3.57 3.66 3.51 3.42 3.34 11/4/13 3.60 3.36 3.65 3.69 3.58 3.43 3.37 10/28/13 3.60 3.48 3.71 3.84 3.67 3.53 3.38 10/21/13 3.64 3.50 3.75 3.84 3.70 3.54 3.40 10/14/13 3.70 3.45 3.74 3.82 3.70 3.51 3.40 10/7/13 3.63 3.46 3.75 3.83 3.70 3.52 3.41

9

Gasohol - Boon or Boondoggle?  

E-Print Network [OSTI]

. enzymes which convert its starch to sugar. The This paper presents information on the overall resulting sugar is fermented, producing ethyl energy balance and clears up the recent contro alcohol (ethanol). Presently most plants use versy on the actual... of making alcohol is claimed are fairly standard- the application to ethanol to be as low as 40% by opponents while is not yet in common practice. The heat required proponents talk of over 100% for distillation can be supplied by waste heat or -Effects...

Hyland, M. J.

1981-01-01T23:59:59.000Z

10

Clean Water Act (excluding Section 404)  

SciTech Connect (OSTI)

This Reference Book contains a current copy of the Clean Water Act (excluding Section 404) and those regulations that implement the statutes and appear to be most relevant to US Department of Energy (DOE) activities. The document is provided to DOE and contractor staff for informational purposes only and should not be interpreted as legal guidance. Updates that include important new requirements will be provided periodically. Questions concerning this Reference Book may be directed to Mark Petts, EH-231 (202/586-2609).

Not Available

1993-01-15T23:59:59.000Z

11

Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

Administration Petroleum Marketing Annual 1995 Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon Excluding...

12

Nucleosome positioning by genomic excluding-energy barriers  

Science Journals Connector (OSTI)

...genomic excluding-energy barriers 10.1073...Vaillant Benjamin Audit Zofia Haftek-Terreau...Sequence motifs and free energies of selected natural and non-natural...174 . 14 Vaillant C Audit B Arneodo A ( 2007...excluding genomic energy barriers Pascale Milani...Vaillant, Benjamin Audit, Zofia Haftek-Terreau...

Pascale Milani; Guillaume Chevereau; Cédric Vaillant; Benjamin Audit; Zofia Haftek-Terreau; Monique Marilley; Philippe Bouvet; Françoise Argoul; Alain Arneodo

2009-01-01T23:59:59.000Z

13

Thermodynamical Consistency of Excluded Volume Hadron Gas Models  

E-Print Network [OSTI]

The new excluded volume hadron gas model by Singh et al. [1-7] is critically discussed. We demonstrate that in this model the results obtained from relations between thermodynamical quantities disagree with the corresponding results obtained by statistical ensemble averaging. Thus, the model does not satisfy the requirements of thermodynamical consistency.

M. I. Gorenstein

2012-05-08T23:59:59.000Z

14

National Environmental Policy Act (NEPA) Categorically Excluded Actions |  

Broader source: Energy.gov (indexed) [DOE]

NEPA » National NEPA » National Environmental Policy Act (NEPA) Categorically Excluded Actions National Environmental Policy Act (NEPA) Categorically Excluded Actions Categorical Exclusions (CX) - Categorical exclusions are categories of actions that DOE has determined, by regulation, do not individually or cumulatively have a significant effect on the human environment and for which neither an environmental assessment nor an environmental impact statement is typically required. Title 10 Code of Federal Regulations Part 1021, National Environmental Policy Act Implementing Procedures, Appendices A and B to Subpart D, list DOE's categorical exclusions. Appendix A classes of actions are those actions considered to be general agency actions, such as awarding a contract or hiring personnel. Appendix B classes of actions

15

"ENDING STOCKS OF CRUDE OIL (excluding SPR)"  

U.S. Energy Information Administration (EIA) Indexed Site

ENDING STOCKS OF CRUDE OIL (excluding SPR)" ENDING STOCKS OF CRUDE OIL (excluding SPR)" "Sourcekey","WCESTP11","WCESTP11","WCESTP21","WCESTP21","WCESTP31","WCESTP31","WCESTP41","WCESTP41","WCESTP51","WCESTP51","WCESTUS1","WCESTUS1" "Date","Weekly East Coast (PADD 1) Ending Stocks excluding SPR of Crude Oil (Thousand Barrels)","Weekly East Coast (PADD 1) Ending Stocks excluding SPR of Crude Oil (Thousand Barrels)","Weekly Midwest (PADD 2) Ending Stocks excluding SPR of Crude Oil (Thousand Barrels)","Weekly Midwest (PADD 2) Ending Stocks excluding SPR of Crude Oil (Thousand Barrels)","Weekly Gulf Coast (PADD 3) Ending Stocks excluding SPR of Crude Oil (Thousand Barrels)","Weekly Gulf Coast (PADD 3) Ending Stocks excluding SPR of Crude Oil (Thousand Barrels)","Weekly Rocky Mountain (PADD 4) Ending Stocks excluding SPR of Crude Oil (Thousand Barrels)","Weekly Rocky Mountain (PADD 4) Ending Stocks excluding SPR of Crude Oil (Thousand Barrels)","Weekly West Coast (PADD 5) Ending Stocks excluding SPR of Crude Oil (Thousand Barrels)","Weekly West Coast (PADD 5) Ending Stocks excluding SPR of Crude Oil (Thousand Barrels)","Weekly U.S. Ending Stocks excluding SPR of Crude Oil (Thousand Barrels)","Weekly U.S. Ending Stocks excluding SPR of Crude Oil (Thousand Barrels)"

16

E-Print Network 3.0 - advanced cancer excluding Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Powered by Explorit Topic List Advanced Search Sample search results for: advanced cancer excluding Page: << < 1 2 3 4 5 > >> 1 Eur J Cancer. Author manuscript Social...

17

Artificial oxygen transport protein  

DOE Patents [OSTI]

This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

Dutton, P. Leslie

2014-09-30T23:59:59.000Z

18

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory . Covalency in Metal-Oxygen Multiple Bonds Evaluated Using...

19

Particle number fluctuations in nuclear collisions within excluded volume hadron gas model  

E-Print Network [OSTI]

The multiplicity fluctuations are studied in the van der Waals excluded volume hadron-resonance gas model. The calculations are done in the grand canonical ensemble within the Boltzmann statistics approximation. The scaled variances for positive, negative and all charged hadrons are calculated along the chemical freeze-out line of nucleus-nucleus collisions at different collision energies. The multiplicity fluctuations are found to be suppressed in the van der Waals gas. The numerical calculations are presented for two values of hard-core hadron radius, $r=0.3$ fm and 0.5 fm, as well as for the upper limit of the excluded volume suppression effects.

M. I. Gorenstein; M. Hauer; D. O. Nikolajenko

2007-02-26T23:59:59.000Z

20

Oxygen enriched fireflooding  

SciTech Connect (OSTI)

Both pure oxygen and enriched air have been considered in fireflooding for enhanced oil recovery. Laboratory and field testing have conclusively shown that oxygen is practical and cost effective for this application. For reservoirs that require a large volume of high pressure gas, oxygen is cheaper than air simply based on compression costs. Additional process benefits with oxygen include: Faster Oil Production; Lower Injection Pressure; Greater Well Spacing; Increased Carbon Dioxide Partial Pressure; Lower Gas-to-Oil Ratios; and Purer Produced Gas. These features provide a compelling case for oxygen, once the safety and materials compatibility issues are properly addressed.

Shahani, G.H.; Gunardson, H.H. [Air Products and Chemicals, Allentown, PA (United States)

1995-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

2003-01-01T23:59:59.000Z

22

Ionic Asymmetry and Solvent Excluded Volume Effects on Spherical Electric Double Layers: A Density Functional Approach  

SciTech Connect (OSTI)

In this article we present a classical density functional theory for electrical double layers of spherical macroions that extends the capabilities of conventional approaches by accounting for electrostatic ion correlations, size asymmetry and excluded volume effects. The approach is based on a recent approximation introduced by Hansen-Goos and Roth for the hard sphere excess free energy of inhomogeneous fluids (J. Chem. Phys. 124, 154506). It accounts for the proper and efficient description of the effects of ionic asymmetry and solvent excluded volume, especially at high ion concentrations and size asymmetry ratios including those observed in experimental studies. Additionally, we utilize a leading functional Taylor expansion approximation of the ion density profiles. In addition, we use the Mean Spherical Approximation for multi-component charged hard sphere fluids to account for the electrostatic ion correlation effects. These approximations are implemented in our theoretical formulation into a suitable decomposition of the excess free energy which plays a key role in capturing the complex interplay between charge correlations and excluded volume effects. We perform Monte Carlo simulations in various scenarios to validate the proposed approach, obtaining a good compromise between accuracy and computational cost. We use the proposed computational approach to study the effects of ion size, ion size asymmetry and solvent excluded volume on the ion profiles, integrated charge, mean electrostatic potential, and ionic coordination number around spherical macroions in various electrolyte mixtures. Our results show that both solvent hard sphere diameter and density play a dominant role in the distribution of ions around spherical macroions, mainly for experimental water molarity and size values where the counterion distribution is characterized by a tight binding to the macroion, similar to that predicted by the Stern model.

Medasani, Bharat; Ovanesyan, Zaven; Thomas, Dennis G.; Sushko, Maria L.; Marucho, Marcelo

2014-05-29T23:59:59.000Z

23

Clean Water Act (excluding Section 404). Environmental guidance program reference book: Revision 6  

SciTech Connect (OSTI)

This Reference Book contains a current copy of the Clean Water Act (excluding Section 404) and those regulations that implement the statutes and appear to be most relevant to US Department of Energy (DOE) activities. The document is provided to DOE and contractor staff for informational purposes only and should not be interpreted as legal guidance. Updates that include important new requirements will be provided periodically. Questions concerning this Reference Book may be directed to Mark Petts, EH-231 (202/586-2609).

Not Available

1993-01-15T23:59:59.000Z

24

Plants making oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Plants making oxygen Plants making oxygen Name: Doug Status: N/A Age: N/A Location: N/A Country: N/A Date: Around 1993 Question: How many plants are needed to make enough oxygen for one person for one hour? We are experimenting with Anacharis plants. Replies: The problem can be solved when broken down into smaller questions: 1. How much oxygen does a person need in an hour? 2. How much oxygen does a plant produce in an hour? 3. Based on the above, how many plants will provide the oxygen needs of the person for the hour? Here is the solution to the first question: A resting, healthy adult on an average, cool day breathes in about 53 liters of oxygen per hour. An average, resting, health adult breathes in about 500 mL of air per breath. This is called the normal tidal volume. Now, 150 mL of this air will go to non- functioning areas of the lung, called the "dead space." The average breath rate for this average person is 12 breaths per minute. So, the amount of air breathed in by the person which is available for use is 12 x (500 mL -150 mL) = 4,200 mL/minute. Multiply by 60 to get 252,000 mL/hour. That is, every hour, the person will breathe in 252 L of air. Now, on an average, cool, clear day, only 21% of that air is oxygen. So, 21% of 252 L is 53 L. So, in an hour, the person breathes in about 53 L of oxygen.

25

Algae for Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Algae for Oxygen Algae for Oxygen Name: Pam Burkardt Status: N/A Age: N/A Location: N/A Country: N/A Date: N/A Question: Hi, I am Pam Burkardt, a seventh grader at Fox Chapel School. I have a question on algae. I read somewhere that someday people might take bath tubs full of algae onto spaceships to provide oxygen for the crew. How much oxygen does algae give off, is this really possible? Replies: I think that most of the oxygen in the atmosphere comes in fact from one-celled plants in the oceans, like algae. They are likely to produce a lot of oxygen per unit weight because they don't have non-photosynthesizing bark, roots, branches, etc., nor (I think) a major dormant period like temperate-zone plants. The cost of space travel at present is dominated by the expense of heaving weight up into Earth orbit (it costs very little extra to send it to the Moon, for example, or Mars). For missions of short duration the weight of the compressed oxygen you need to carry is less than the weight of algae, water and extra plumbing you'd need to carry if you relied on algae to produce your oxygen. The important use of green plants would be in very long duration space flight (years) or permanent inhabitation of worlds like the Moon, where you need an unlimited supply of oxygen. Now if you want to fantasize, Venus' atmosphere is almost all carbon dioxide. Suppose you dropped a whole lot of specially gene-tailored one-celled plants into the atmosphere (not the surface, it's too hot). Why then they might eat up all the carbon dioxide and produce a breathable atmosphere. The "greenhouse effect" would go away, and Venus would become a nice habitable if tropical world only 50 million miles away.

26

Description of Hot and Dense Hadron Gas Properties in a New Excluded-Volume model  

E-Print Network [OSTI]

A new equation of state for a hot and dense hadron gas (HG) is obtained where the finite hard-core size of baryons has been incorporated in a thermodynamically consistent formulation of excluded volume correction. Our model differs from other existing approaches on the following points. We assign a hard-core volume only to each baryon and mesons though possess a small volume but they can fuse and interpenetrate into one another. Use of the full quantum statistics is made in obtaining the grand canonical partition function where excluded-volume correction has been incorporated by explicitly integrating over volume. We thus find that the new model works even for the cases of extreme temperatures and/or densities where most of other approaches fail. The model does not violate causality even at extreme densities. The temperature and density dependence of various thermodynamical quantities, e.g. pressure, baryon density, entropy and energy density compare well with the results of other microscopic HG models. After suitable parametrization of the centre-of-mass energy in terms of temperature and baryon chemical potential, we explore some new freeze-out criteria which exhibit full independence of the collision energy and of the structures of the colliding nuclei. We further demonstrate the suitability of our model in explaining various experimental results of the multiplicity-ratios of various particles and their antiparticles. Finally, we use our excluded-volume model to obtain the transport behaviour of the hot and/or dense HG such as shear viscosity to entropy ratio, speed of sound etc. and compare the results with earlier calculations.

S. K. Tiwari; P. K. Srivastava; C. P. Singh

2011-11-10T23:59:59.000Z

27

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

In the present quarter, oxygen transport perovskite ceramic membranes are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-07-01T23:59:59.000Z

28

Bifurcated Endograft (Excluder) in the Treatment of Isolated Iliac Artery Aneurysm: Preliminary Report  

SciTech Connect (OSTI)

The aim of this study was to evaluate the effectiveness of endovascular repair in the treatment of isolated iliac artery aneurysm (IAA) using Excluder bifurcated endograft. Eight consecutive patients with IAA were treated during a period of 45 months using Excluder bifurcated endograft. Two patients presented with isolated IAA rupture and were treated emergently, whereas the other six patients underwent elective treatment. All aneurysms lacked sufficient proximal necks and therefore were not suitable for tubular-shaped endograft. Follow-up imaging was performed at 1 week, at every 3 months during the first year, semiannually until 2 years, and annually afterward using angio-computed axial tomography and plain films. Technical success was achieved in all patients. No mortality was seen despite two patients having IAA rupture. Follow-up (12 to 60 months) was done in all but one patient. During this period, complications were observed in three patients. One patient developed sexual impotence at 3-month follow up; one patient presented unilateral gluteal claudication after the procedure, which resolved at 3 months; and one patient developed a graft porosity-related endoleak, which was successfully managed with placement of an additional ipsilateral iliac extension. Endovascular treatment of isolated IAA using bifurcated endograft is safe and can be an alternative to surgical treatment. The benefits from decreased morbidity and mortality of endoluminal treatment of isolated IAA using bifurcated endograft outweigh the minor complications associated with this technique, which are mostly related to occlusion of hypogastric arteries.

Zander, Tobias, E-mail: tobiaszander@gmx.de; Baldi, Sebastian; Rabellino, Martin [Las Palmas de Gran Canaria University, Endoluminal Vascular Department, Rambla Hospiten Clinic Group (Spain); Kirsch, David [Louisiana State University Health Sciences Center (United States); Llorens, Rafael; Zerolo, Ignacio [Las Palmas de Gran Canaria University, Department of Cardiosurgery, Rambla Hospiten Clinic Group (Spain); Qian, Zhong [Louisiana State University Health Sciences Center (United States); Maynar, Manuel [Las Palmas de Gran Canaria University, Endoluminal Vascular Department, Rambla Hospiten Clinic Group (Spain)

2009-09-15T23:59:59.000Z

29

Solar energy: Hydrogen and oxygen  

Science Journals Connector (OSTI)

Solar energy: Hydrogen and oxygen ... Demonstrating the electrolysis of water with solar energy. ...

John J. Farrell

1982-01-01T23:59:59.000Z

30

Optical oxygen concentration monitor  

DOE Patents [OSTI]

A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen`s A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2,000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest. 4 figs.

Kebabian, P.

1997-07-22T23:59:59.000Z

31

Infection with Strains of Citrus Tristeza Virus Does Not Exclude Superinfection by Other Strains of the Virus  

Science Journals Connector (OSTI)

...distinct strains. However, this model does not explain how hybrid viruses containing...Graft-transmissible diseases of detritus: handbook for detection and diagnosis. FAO, Rome...Infection with strains of Citrus tristeza virus does not exclude superinfection by other strains...

Svetlana Y. Folimonova; Cecile J. Robertson; Turksen Shilts; Alexey S. Folimonov; Mark E. Hilf; Stephen M. Garnsey; William O. Dawson

2009-11-18T23:59:59.000Z

32

On The Importance of Organic Oxygen for Understanding Organic Aerosol  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

On The Importance of Organic Oxygen for Understanding Organic Aerosol On The Importance of Organic Oxygen for Understanding Organic Aerosol Particles Title On The Importance of Organic Oxygen for Understanding Organic Aerosol Particles Publication Type Journal Article Year of Publication 2006 Authors Pang, Yanbo, B. J. Turpin, and Lara A. Gundel Journal Journal of Aerosol Science and Technology Volume 40 Start Page Chapter Pagination 128-133 Abstract This study shows how aerosol organic oxygen data could provide new and independent information about organic aerosol mass, aqueous solubility of organic aerosols, formation of secondary organic aerosol (SOA) and the relative contributions of anthropogenic and biogenic sources. For more than two decades atmospheric aerosol organic mass concentration has usually been estimated by multiplying the measured carbon content by an assumed organic mass (OM)-to-organic carbon (OC ) factor of 1.4. However, this factor can vary from 1.0 to 2.5 depending on location. This great uncertainty about aerosol organic mass limits our understanding of the influence of organic aerosol on climate, visibility and health.New examination of organic aerosol speciation data shows that the oxygen content is the key factor responsible for the observed range in the OM-to-OC factor. When organic oxygen content is excluded, the ratio of non-oxygen organic mass to carbon mass varies very little across different environments (1.12 to 1.14). The non-oxygen-OM-to-non-oxygen OC factor for all studied sites (urban and non-urban) is 1.13± 0.02. The uncertainty becomes an order of magnitude smaller than the uncertainty in the best current estimates of organic mass to organic carbon ratios (1.6± 0.2 for urban and 2.1± 0.2 for non-urban areas). When aerosol organic oxygen data become available, organic aerosol mass can be quite accurately estimated using just OC and organic oxygen (OO) without the need to know whether the aerosol is fresh or aged. In addition, aerosol organic oxygen data will aid prediction of water solubility since compounds with OO-to-OC higher than 0.4 have water solubilities higher than 1g per 100 g water

33

Oxygen in Underwater Cave  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen in Underwater Cave Oxygen in Underwater Cave Name: Natalie Status: student Grade: 9-12 Location: HI Country: USA Date: Spring 2011 Question: Is it possible for there to be free oxygen in an underwater cave? If it is, then how does it work? Replies: Yes it is possible as I have personally experienced. If the cave roof rises to a level above the water, air dissolved in the water will slowly out gas until the water is at the same level at all places. A pocket of breathable air will form. In many caves the roof dips below water level in one place but it above it on both sides. Think of a U shaped tube where the bottom of the U is blocked by water. This is called a siphon and I have passed through many of these to find breathable air on the other side. R. W. "Bob" Avakian Oklahoma State Univ. Inst. of Technology

34

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

In the present quarter, the possibility of using a more complex interfacial engineering approach to the development of reliable and stable oxygen transport perovskite ceramic membranes/metal seals is discussed. Experiments are presented and ceramic/metal interactions are characterized. Crack growth and fracture toughness of the membrane in the reducing conditions are also discussed. Future work regarding this approach is proposed are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2003-01-01T23:59:59.000Z

35

Optical oxygen concentration monitor  

DOE Patents [OSTI]

A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen's A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest.

Kebabian, Paul (Acton, MA)

1997-01-01T23:59:59.000Z

36

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

Morris, D.E.

1992-07-14T23:59:59.000Z

37

High pressure oxygen furnace  

DOE Patents [OSTI]

A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

Morris, Donald E. (Kensington, CA)

1992-01-01T23:59:59.000Z

38

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the previous research, the reference point of oxygen occupancy was determined and verified. In the current research, the oxygen occupancy was investigated at 1200 C as a function of oxygen activity and compared with that at 1000 C. The cause of bumps at about 200 C was also investigated by using different heating and cooling rates during TGA. The fracture toughness of LSFT and dual phase membranes at room temperature is an important mechanical property. Vicker's indentation method was used to evaluate this toughness. Through this technique, a K{sub Ic} (Mode-I Fracture Toughness) value is attained by means of semi-empirical correlations between the indentation load and the length of the cracks emanating from the corresponding Vickers indentation impression. In the present investigation, crack propagation behavior was extensively analyzed in order to understand the strengthening mechanisms involved in the non-transforming La based ceramic composites. Cracks were generated using Vicker's indenter and used to identify and evaluate the toughening mechanisms involved. Preliminary results of an electron microscopy study of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Modeling of the isotopic transients on operating membranes (LSCrF-2828 at 900 C) and a ''frozen'' isotope profile have been analyzed in conjunction with a 1-D model to reveal the gradient in oxygen diffusivity through the membrane under conditions of high chemical gradients.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-08-01T23:59:59.000Z

39

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. The in situ electrical conductivity and Seebeck coefficient measurements were made on LSFT at 1000 and 1200 C over the oxygen activity range from air to 10{sup -15} atm. The electrical conductivity measurements exhibited a p to n type transition at an oxygen activity of 1 x 10{sup -10} at 1000 C and 1 x 10{sup -6} at 1200 C. Thermogravimetric studies were also carried out over the same oxygen activities and temperatures. Based on the results of these measurements, the chemical and mechanical stability range of LSFT were determined and defect structure was established. The studies on the fracture toughness of the LSFT and dual phase membranes exposed to air and N{sub 2} at 1000 C was done and the XRD and SEM analysis of the specimens were carried out to understand the structural and microstructural changes. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affect the mechanical properties. A complete transformation of fracture behavior was observed in the N{sub 2} treated LSFT samples. Further results to investigate the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Recent results on transient kinetic data are presented. The 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model is used to study ''frozen'' profiles in patterned or composite membranes.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-02-01T23:59:59.000Z

40

Oxygen abundances in the most oxygen-rich spiral galaxies  

E-Print Network [OSTI]

Oxygen abundances in the spiral galaxies expected to be richest in oxygen are estimated. The new abundance determinations are based on the recently discovered ff-relation between auroral and nebular oxygen line fluxes in HII regions. We find that the maximum gas-phase oxygen abundance in the central regions of spiral galaxies is 12+log(O/H)~8.75. This value is significantly lower than the previously accepted value. The central oxygen abundance in the Milky Way is similar to that in other large spirals.

L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

2006-01-06T23:59:59.000Z

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Oxygen Concentration Microgradients for Cell Culture  

E-Print Network [OSTI]

The Chemotactic Effect of Oxygen on Bacteria,” J. Pathol.Measurement and Control of Oxygen Levels in MicrofluidicA Microfabricated Electrochemical Oxygen Generator for High-

Park, Jaehyun

2010-01-01T23:59:59.000Z

42

Oxygen Transport Membranes  

SciTech Connect (OSTI)

The focus of this research was to develop new membrane materials by synthesizing different compounds and determining their defect structures, crystallographic structures and electrical properties. In addition to measuring electrical conductivity, oxygen vacancy concentration was also evaluated using thermogravimetry, Neutron diffraction and Moessbauer Spectroscopy. The reducing conditions (CO{sub 2}/CO/H{sub 2} gas mixtures with steam) as encountered in a reactor environment can be expected to have significant influence on the mechanical properties of the oxides membranes. Various La based materials with and without Ti were selected as candidate membrane materials for OTM. The maximum electrical conductivity of LSF in air as a function of temperature was achieved at < 600 C and depends on the concentration of Sr (acceptor dopant). Oxygen occupancy in LSF was estimated using Neutron diffractometry and Moessbauer Spectroscopy by measuring magnetic moment changes depending on the Fe{sup 3+} and Fe{sup 4+} ratio. After extensive studies of candidate materials, lanthanum ferrites (LSF and LSFT) were selected as the favored materials for the oxygen transport membrane (OTM). LSF is a very good material for an OTM because of its high electronic and oxygen ionic conductivity if long term stability and mechanical strength are improved. LSFT not only exhibits p-type behavior in the high oxygen activity regime, but also has n-type conduction in reducing atmospheres. Higher concentrations of oxygen vacancies in the low oxygen activity regime may improve the performance of LSFT as an OTM. The hole concentration is related to the difference in the acceptor and donor concentration by the relation p = [Sr'{sub La}]-[Ti{sm_bullet}{sub Fe}]. The chemical formulation predicts that the hole concentration is, p = 0.8-0.45 or 0.35. Experimental measurements indicated that p is about {approx} 0.35. The activation energy of conduction is 0.2 eV which implies that LSCF conducts via the small polaron conduction mechanism. Scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS) were used to develop strategies to detect and characterize vacancy creation, dopant segregations and defect association in the oxygen conducting membrane material. The pO{sub 2} and temperature dependence of the conductivity, non-stoichiometry and thermal-expansion behavior of compositions with increasing complexity of substitution on the perovskite A and B sites were studied. Studies with the perovskite structure show anomalous behavior at low oxygen partial pressures (<10{sup -5} atm). The anomalies are due to non-equilibrium effects and can be avoided by using very strict criteria for the attainment of equilibrium. The slowness of the oxygen equilibration kinetics arises from two different mechanisms. In the first, a two phase region occurs between an oxygen vacancy ordered phase such as brownmillerite SrFeO{sub 2.5} and perovskite SrFeO{sub 3-x}. The slow kinetics is associated with crossing the two phase region. The width of the miscibility gap decreases with increasing temperature and consequently the effect is less pronounced at higher temperature. The preferred kinetic pathway to reduction of perovskite ferrites when the vacancy concentration corresponds to the formation of significant concentrations of Fe{sup 2+} is via the formation of a Ruddlesden-Popper (RP) phases as clearly observed in the case of La{sub 0.5}Sr{sub 0.5}FeO{sub 3-x} where LaSrFeO{sub 4} is found together with Fe. In more complex compositions, such as LSFTO, iron or iron rich phases are observed locally with no evidence for the presence of discrete RP phase. Fracture strength of tubular perovskite membranes was determined in air and in reducing atmospheric conditions. The strength of the membrane decreased with temperature and severity of reducing conditions although the strength distribution (Weibull parameter, m) was relatively unaltered. Surface and volume dominated the fracture origins and the overall fracture was purely transgranular. The dual phas

S. Bandopadhyay

2008-08-30T23:59:59.000Z

43

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. Thermogravimetric analysis (TGA) was carried out on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} to investigate oxygen deficiency ({delta}) of the sample. The TGA was performed in a controlled atmosphere using oxygen, argon, carbon monoxide and carbon dioxide with adjustable gas flow rates. In this experiment, the weight loss and gain of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} was directly measured by TGA. The weight change of the sample was evaluated at between 600 and 1250 C in air or 1000 C as a function of oxygen partial pressure. The oxygen deficiencies calculated from TGA data as a function of oxygen activity and temperature will be estimated and compared with that from neutron diffraction measurement in air. The LSFT and LSFT/CGO membranes were fabricated from the powder obtained from Praxair Specialty Ceramics. The sintered membranes were subjected to microstructure analysis and hardness analysis. The LSFT membrane is composed of fine grains with two kinds of grain morphology. The grain size distribution was characterized using image analysis. In LSFT/CGO membrane a lot of grain pullout was observed from the less dense, porous phase. The hardness of the LSFT and dual phase membranes were studied at various loads. The hardness values obtained from the cross section of the membranes were also compared to that of the values obtained from the surface. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. Measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} as a function of temperature an oxygen partial pressure are reported. Further analysis of the dilatometry data obtained previously is presented. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-02-01T23:59:59.000Z

44

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

Ti doping on La{sub 1-x}Sr{sub x}FeO{sub 3-{delta}} (LSF) tends to increase the oxygen equilibration kinetics of LSF in lower oxygen activity environment because of the high valence state of Ti. However, the addition of Ti decreases the total conductivity because the acceptor ([Sr{prime}{sub La}]) is compensated by the donor ([Ti{sub Fe}{sup {sm_bullet}}]) which decreases the carrier concentration. The properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 1-x}Ti{sub x}O{sub 3-{delta}} (LSFT, x = 0.45) have been experimentally and theoretically investigated to elucidate (1) the dependence of oxygen occupancy and electrochemical properties on temperature and oxygen activity by thermogravimetric analysis (TGA) and (2) the electrical conductivity and carrier concentration by Seebeck coefficient and electrical measurements. In the present study, dual phase (La{sub 0.2}Sr{sub 0.8}Fe{sub 0.6}Ti{sub 0.4}O{sub 3-{delta}}/Ce{sub 0.9}Gd{sub 0.1}O{sub 2-{delta}}) membranes have been evaluated for structural properties such as hardness, fracture toughness and flexural strength. The effect of high temperature and slightly reducing atmosphere on the structural properties of the membranes was studied. The flexural strength of the membrane decreases upon exposure to slightly reducing conditions at 1000 C. The as-received and post-fractured membranes were characterized using XRD, SEM and TG-DTA to understand the fracture mechanisms. Changes in structural properties of the composite were sought to be correlated with the physiochemical features of the two-phases. We have reviewed the electrical conductivity data and stoichiometry data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} some of which was reported previously. Electrical conductivity data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} (LSCrF) were obtained in the temperature range, 752 {approx} 1055 C and in the pO{sub 2} range, 10{sup -18} {approx} 0.5 atm. The slope of the plot of log {sigma} vs. log pO{sub 2} is {approx} 1/5 in the p-type region, pO{sub 2} = 10{sup -5} {approx} 10{sup -1} atm. The pO{sub 2} at which the p-n transition is observed increases with increasing temperature. The activation energy for ionic conduction was estimated to be 0.86 eV from an Arrhenius plot of the minimum conductivity vs. reciprocal temperature. At temperatures below 940 C, a plateau in the conductivity isotherm suggests the presence of a two-phase region. Most likely, phase separation occurs to form a mixture of a perovskite phase and an oxygen vacancy ordered phase related to brownmillerite. Additional data for the oxygen non stoichiometry are presented.

S. Bandopadhyay; T. Nithyanantham

2006-12-31T23:59:59.000Z

45

Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Platinum Nanoparticle Electrocatalysts for Oxygen Reduction Using Poly(diallyldimethylammonium chloride). Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

46

Water treatment facilities (excluding wastewater facilities). (Latest citations from the Selected Water Resources Abstracts database). Published Search  

SciTech Connect (OSTI)

The bibliography contains citations concerning the design, construction, costs, and operation of water treatment facilities. Facilities covered include those that provide drinking water, domestic water, and water for industrial use. Types of water treatment covered include reverse osmosis, chlorination, filtration, and ozonization. Waste water treatment facilities are excluded from this bibliography. (Contains 250 citations and includes a subject term index and title list.)

Not Available

1993-07-01T23:59:59.000Z

47

Composite oxygen transport membrane  

DOE Patents [OSTI]

A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

Christie, Gervase Maxwell; Lane, Jonathan A.

2014-08-05T23:59:59.000Z

48

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This is the third quarterly report on oxygen Transport Ceramic Membranes. In the following, the report describes the progress made by our university partners in Tasks 1 through 6, experimental apparatus that was designed and built for various tasks of this project, thermodynamic calculations, where applicable and work planned for the future. (Task 1) Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. (Task 2) Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. (Task 3) Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. (Task 4) Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. (Task 5) Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. (Task 6) Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2000-10-01T23:59:59.000Z

49

OXYGEN ABUNDANCES IN CEPHEIDS  

SciTech Connect (OSTI)

Oxygen abundances in later-type stars, and intermediate-mass stars in particular, are usually determined from the [O I] line at 630.0 nm, and to a lesser extent, from the O I triplet at 615.7 nm. The near-IR triplets at 777.4 nm and 844.6 nm are strong in these stars and generally do not suffer from severe blending with other species. However, these latter two triplets suffer from strong non-local thermodynamic equilibrium (NLTE) effects and thus see limited use in abundance analyses. In this paper, we derive oxygen abundances in a large sample of Cepheids using the near-IR triplets from an NLTE analysis, and compare those abundances to values derived from a local thermodynamic equilibrium (LTE) analysis of the [O I] 630.0 nm line and the O I 615.7 nm triplet as well as LTE abundances for the 777.4 nm triplet. All of these lines suffer from line strength problems making them sensitive to either measurement complications (weak lines) or to line saturation difficulties (strong lines). Upon this realization, the LTE results for the [O I] lines and the O I 615.7 nm triplet are in adequate agreement with the abundance from the NLTE analysis of the near-IR triplets.

Luck, R. E.; Andrievsky, S. M. [Department of Astronomy, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106-7215 (United States); Korotin, S. N.; Kovtyukh, V. V., E-mail: luck@fafnir.astr.cwru.edu, E-mail: serkor@skyline.od.ua, E-mail: val@deneb1.odessa.ua, E-mail: scan@deneb1.odessa.ua [Department of Astronomy and Astronomical Observatory, Odessa National University, Isaac Newton Institute of Chile, Odessa Branch, Shevchenko Park, 65014 Odessa (Ukraine)

2013-07-01T23:59:59.000Z

50

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C. It was found that space group of R3c yielded a better refinement than a cubic structure of Pm3m. Oxygen occupancy was nearly 3 in the region from room temperature to 700 C, above which the occupancy decreased due to oxygen loss. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. The X-Ray data and fracture mechanisms points to non-equilibrium decomposition of the LSFCO OTM membrane. The non-equilibrium conditions could probably be due to the nature of the applied stress field (stressing rates) and leads to transition in crystal structures and increased kinetics of decomposition. The formations of a Brownmillerite or Sr2Fe2O5 type structures, which are orthorhombic are attributed to the ordering of oxygen vacancies. The cubic to orthorhombic transitions leads to 2.6% increase in strains and thus residual stresses generated could influence the fracture behavior of the OTM membrane. Continued investigations on the thermodynamic properties (stability and phase-separation behavior) and total conductivity of prototype membrane materials were carried out. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previously characterization, stoichiometry and conductivity measurements for samples of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were reported. In this report, measurements of the chemical and thermal expansion as a function of temperature and p{sub O2} are described.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-05-01T23:59:59.000Z

51

BWR oxygen control demonstration program  

SciTech Connect (OSTI)

A number of cracks have occurred recently in certain BWR piping systems. The operating environment associated with oxidizing species such as oxygen and hydrogen peroxide is considered one of the factors in the mechanism of cracking. In April 1976, NWT Corporation was contracted to perform a BWR oxygen control demonstration program. Means for reducing reactor water oxygen and hydrogen peroxide concentrations during startup and shutdown transients were defined and demonstrated at Vermont Yankee and Browns Ferry Unit 3. Results of the demonstrations and an analytical review of impacts of major system variables on oxygen transients are discussed herein.

Pearl, W.L.; Kassen, W.R.; Sawochka, S.G.

1981-05-01T23:59:59.000Z

52

Oxygen to the core  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1-01 1-01 For immediate release: 01/10/2013 | NR-13-01-01 Oxygen to the core Anne M Stark, LLNL, (925) 422-9799, stark8@llnl.gov Printer-friendly An artist's conception of Earth's inner and outer core. LIVERMORE, Calif. -- An international collaboration including researchers from Lawrence Livermore National Laboratory has discovered that the Earth's core formed under more oxidizing conditions than previously proposed. Through a series of laser-heated diamond anvil cell experiments at high pressure (350,000 to 700,000 atmospheres of pressure) and temperatures (5,120 to 7,460 degrees Fahrenheit), the team demonstrated that the depletion of siderophile (also known as "iron loving") elements can be produced by core formation under more oxidizing conditions than earlier

53

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

This report covers the following tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints; Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability; Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres; Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures; Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability; and Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-04-01T23:59:59.000Z

54

Pool octanes via oxygenates  

SciTech Connect (OSTI)

Increasingly stringent antipollution regulations placed on automobile exhaust gases with consequent reduction or complete lead ban from motor gasoline result in octane shortage at many manufacturing sites. Attractive solutions to this problem, especially in conjunction with abundant methanol supplies, are the hydration and etherification of olefins contained in light product streams from cracking unit or produced by field gas dehydrogenation. A comparison is made between oxygenates octane-volume pool contributions and established refinery technologies. Process reviews for bulk manufacture of fuel-grade isopropanol (IPA), secondary butanol (SBA), tertiary butanol (TBA), methyl tertiary butyl ether (MTBE) and tertiary amyl methyl ether (TAME) are presented together with the characteristic investment and operating data. The implantation of these processes into a typical FCCU refinery complex with the resulting octane-pool improvement possibilities is descried.

Prezelj, M.

1987-09-01T23:59:59.000Z

55

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals. This project has the following 6 main tasks: Task 1--Design, fabricate and evaluate ceramic to metal seals based on graded ceramic powder/metal braze joints. Task 2--Evaluate the effect of defect configuration on ceramic membrane conductivity and long term chemical and structural stability. Task 3--Determine materials mechanical properties under conditions of high temperatures and reactive atmospheres. Task 4--Evaluate phase stability and thermal expansion of candidate perovskite membranes and develop techniques to support these materials on porous metal structures. Task 5--Assess the microstructure of membrane materials to evaluate the effects of vacancy-impurity association, defect clusters, and vacancy-dopant association on the membrane performance and stability. Task 6--Measure kinetics of oxygen uptake and transport in ceramic membrane materials under commercially relevant conditions using isotope labeling techniques.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2001-12-01T23:59:59.000Z

56

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, Moessbauer spectroscopy was used to study the local environmentals of LSFT with various level of oxygen deficiency. Ionic valence state, magnetic interaction and influence of Ti on superexchange are discussed Stable crack growth studies on Dense OTM bars provided by Praxair were done at elevated temperature, pressure and elevated conditions. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. The initial measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Neutron diffraction measurements of the same composition are in agreement with both the stoichiometry and the kinetic behavior observed in coulometric titration measurements. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The COCO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-10-01T23:59:59.000Z

57

MTBE, Oxygenates, and Motor Gasoline  

Gasoline and Diesel Fuel Update (EIA)

MTBE, Oxygenates, and MTBE, Oxygenates, and Motor Gasoline Contents * Introduction * Federal gasoline product quality regulations * What are oxygenates? * Who gets gasoline with oxygenates? * Which areas get MTBE? * How much has been invested in MTBE production capacity? * What does new Ethanol capacity cost? * What would an MTBE ban cost? * On-line information resources * Endnotes * Summary of revisions to this analysis Introduction The blending of methyl tertiary butyl ether (MTBE) into motor gasoline has increased dramatically since it was first produced 20 years ago. MTBE usage grew in the early 1980's in response to octane demand resulting initially from the phaseout of lead from gasoline and later from rising demand for premium gasoline. The oxygenated gasoline program stimulated an

58

Plants and Night Oxygen Production  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Plants and Night Oxygen Production Plants and Night Oxygen Production Name: Ashar Status: other Grade: other Location: Outside U.S. Country: India Date: Winter 2011-2012 Question: I would like to know if there are any plants which produces oxygen at night (without photosynthesis). I was told by a friend that Holy Basil (Ocimum tenuiflorum) produces oxygen even at night and I'm not convinced. I would like to get confirmation from experts. Replies: Some plants (particularly those of dry regions, e.g., deserts) only open their stomates at night to avoid drying out to intake CO2 (and output O2) (CAM photosynthesis) http://en.wikipedia.org/wiki/Crassulacean_acid_metabolism Sincerely, Anthony R. Brach, PhD Missouri Botanical Garden Bringing oxygen producing plants into your home is a way to mimic the healthy lifestyle factors of longevity in humans from the longest lived cultures.

59

Oxygen detection using evanescent fields  

DOE Patents [OSTI]

An apparatus and method for the detection of oxygen using optical fiber based evanescent light absorption. Methylene blue was immobilized using a sol-gel process on a portion of the exterior surface of an optical fiber for which the cladding has been removed, thereby forming an optical oxygen sensor. When light is directed through the optical fiber, transmitted light intensity varies as a result of changes in the absorption of evanescent light by the methylene blue in response to the oxygen concentration to which the sensor is exposed. The sensor was found to have a linear response to oxygen concentration on a semi-logarithmic scale within the oxygen concentration range between 0.6% and 20.9%, a response time and a recovery time of about 3 s, ant to exhibit good reversibility and repeatability. An increase in temperature from 21.degree. C. to 35.degree. C. does not affect the net absorption of the sensor.

Duan, Yixiang (Los Alamos, NM); Cao, Weenqing (Los Alamos, NM)

2007-08-28T23:59:59.000Z

60

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and initial studies on newer composition of Ti doped LSF. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. In addition, studies were also begun to obtain reliable estimates of fracture toughness and stable crack growth in specific environments. Newer composition of Ti doped LSF membranes were characterized by neutron diffraction analysis. Quench studies indicated an apparent correlation between the unit cell volume and oxygen occupancy. The studies however, indicated an anomaly of increasing Fe/Ti ratio with change in heat treatment. Ti doped LSF was also characterized for stoichiometry as a function of temp and pO{sub 2}. The non stoichiometry parameter {delta} was observed to increase almost linearly on lowering pO{sub 2} until a ideal stoichiometric composition of {delta} = 0.175 was approached.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; W.B. Yelon; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

OXYGEN TRANSPORT CERAMIC MEMBRANES  

SciTech Connect (OSTI)

Conversion of natural gas to liquid fuels and chemicals is a major goal for the Nation as it enters the 21st Century. Technically robust and economically viable processes are needed to capture the value of the vast reserves of natural gas on Alaska's North Slope, and wean the Nation from dependence on foreign petroleum sources. Technologies that are emerging to fulfill this need are all based syngas as an intermediate. Syngas (a mixture of hydrogen and carbon monoxide) is a fundamental building block from which chemicals and fuels can be derived. Lower cost syngas translates directly into more cost-competitive fuels and chemicals. The currently practiced commercial technology for making syngas is either steam methane reforming (SMR) or a two-step process involving cryogenic oxygen separation followed by natural gas partial oxidation (POX). These high-energy, capital-intensive processes do not always produce syngas at a cost that makes its derivatives competitive with current petroleum-based fuels and chemicals.

Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

2002-01-01T23:59:59.000Z

62

Low Oxygen Environments in Chesapeake Bay  

E-Print Network [OSTI]

Low Oxygen Environments in Chesapeake Bay Jeremy Testa Chesapeake Biological Laboratory University of Maryland Center for Environmental Science Why we care about low oxygen? What causes low oxygen? Where and When does Chesapeake Bay lose oxygen? #12;#12;Hypoxia and Chesapeake Animals Low dissolved oxygen

Boynton, Walter R.

63

Magnetism of solid oxygen  

Science Journals Connector (OSTI)

Magnetic susceptibilities of single-crystal ?-O2 and preferentially oriented polycrystalline samples of ?-O2 and ?-O2 have been measured, employing a mutual-inductance bridge method. The susceptibility of paramagnetic ?-O2 is isotropic and exhibits a temperature dependence which is not strictly Curie-Weiss, due to short-range correlations and partially hindered rotation. The susceptibility of ?-O2 exhibits very little anisotropy, but has an unusual temperature dependence which is probably due to the novel behavior of the lattice constants, modulation of inplane and out-of-plane exchange interactions, and short-range order. The susceptibility of anti-ferromagnetic ?-O2 is anisotropic, and data from five differently oriented samples have been analyzed in terms of principal antiferromagnetic susceptibilities. The data are consistent with the assumption that the easy axis is the twofold axis, b??, though the direction a?? cannot be excluded. A comprehensive analysis of the present susceptibility results and other magnetic, spectroscopic, and thermal measurements is made, with special reference to ?-O2. The perpendicular susceptibility implies an unreasonably large Néel temperature, 211 K, and a correspondingly large intersublattice exchange interaction, |J2|k=19.8 K. The effects of anisotropy and zeropoint spin deviations do not reduce this estimate by more than 15%. The temperature dependence of the parallel susceptibility suggests a much smaller value for the effective exchange interaction, |J|k=5.3 K, and appears to be well accounted for assuming a single spin-wave excitation. Antiferromagnetic resonance frequencies are analyzed and shown to yield, on assuming a dominant anisotropy equal to that of the free molecule, |J2|k=4.3 K. An approximate separation of lattice and magnetic heat capacities is effected, and a value |J|k=3.0 K deduced. The data appear to require the assumption of two spin-wave modes. Except for the perpendicular susceptibility, experimental results suggest a Néel temperature between 30 and 40 K. Meanfield and other theories lead to similar estimates, assuming that |J|k is between 3 and 4 K. The effect of the anisotropy on TN is minor, and no significant spin-shortening effect is predicted. Other experimental results are considered, and a disparate set of estimates for the exchange interaction and zone-boundary spin-wave energies is discussed. Including the effects of intrasublattice exchange interactions within the context of a two-sublattice model does not seem sufficient to remove the various discrepancies. An approximate calculation of relative overlap integrals and exchange interactions between different pairs of molecules in ?-O2 is made. It is suggested that a multisublattice model for the magnetic structure, and possibly one involving noncollinear sublattices, may provide an eventual resolution of the various difficulties. A "quasi-two-dimensional" description of ?-O2 is also considered, but appears not to offer a satisfactory explanation of the unusual and imperfectly correlated properties of this phase.

Gary C. DeFotis

1981-05-01T23:59:59.000Z

64

Frostbite Theater - Liquid Oxygen vs. Liquid Nitrogen - Liquid Oxygen and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cells vs. Liquid Nitrogen! Cells vs. Liquid Nitrogen! Previous Video (Cells vs. Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Paramagnetism) Paramagnetism Liquid Oxygen and Fire! What happens when nitrogen and oxygen are exposed to fire? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a test tube of liquid nitrogen! Steve: And this is a test tube of liquid oxygen! Joanna: Let's see what happens when nitrogen and oxygen are exposed to fire. Steve: Fire?! Joanna: Yeah! Steve: Really?! Joanna: Why not! Steve: Okay! Joanna: As nitrogen boils, it changes into nitrogen gas. Because it's so cold, it's denser than the air in the room. The test tube fills up with

65

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the current research, the electrical conductivity and Seebeck coefficient were measured as a function of temperature in air. Based on these measurements, the charge carrier concentration, net acceptor dopant concentration, activation energy of conduction and mobility were estimated. The studies on the fracture toughness of the LSFT and dual phase membranes at room temperature have been completed and reported previously. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affects the mechanical properties. To study the effect of temperature on the membranes when exposed to an inert environment, the membranes (LAFT and Dual phase) were heat treated at 1000 C in air and N{sub 2} atmosphere and hardness and fracture toughness of the membranes were studied after the treatment. The indentation method was used to find the fracture toughness and the effect of the heat treatment on the mechanical properties of the membranes. Further results on the investigation of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appears to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model will serve to study ''frozen'' profiles in patterned or composite membranes.

S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

2005-11-01T23:59:59.000Z

66

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

S. Bandopadhyay; N. Nagabhushana

2003-08-07T23:59:59.000Z

67

Oxygen transfer in the implant environment  

E-Print Network [OSTI]

Temperature dependence of oxygen diffusion and consumptionRN. Influence of temperature on oxygen diffusion in hamster341-347, 1988. Cox ME. Oxygen Diffusion in Poly(dimethyl

Goor, Jared Braden

2007-01-01T23:59:59.000Z

68

OXYGEN DIFFUSION IN UO2-x  

E-Print Network [OSTI]

~ K.C. K:i.m, "Oxygen Diffusion in Hypostoichiometricsystem for enriching uo 2 in oxygen-18 or for stoichiometry+nal of Nuclear Materials OXYGEN DIFFUSION IN U0 2 _:x K.C.

Kim, K.C.

2013-01-01T23:59:59.000Z

69

PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux  

E-Print Network [OSTI]

PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux: patterns of oxygen dissolved oxygen (DO) levels often occur during summer in tidal creeks along the southeastern coast of the USA. We analyzed rates of oxygen loss as water-column biochemical oxygen demand (BOD5) and sediment

Mallin, Michael

70

Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies  

E-Print Network [OSTI]

The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold ...

VanVeller, Brett

71

Electrocatalytic Reactivity for Oxygen Reduction of Palladium...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reactivity for Oxygen Reduction of Palladium-Modified Carbon Nanotubes Synthesized in Supercritical Fluid. Electrocatalytic Reactivity for Oxygen Reduction of Palladium-Modified...

72

Angling chromium to let oxygen through | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

which enable facile oxygen anion diffusion at low temperature. Brighter spheres are strontium ions; less-bright spheres are chromium ions. Oxygen anions are barely visible, and...

73

Extracorporeal membrane oxygenation promotes long chain fatty...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

membrane oxygenation promotes long chain fatty acid oxidation in the immature swine heart in vivo. Extracorporeal membrane oxygenation promotes long chain fatty acid oxidation...

74

OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC URANIUM DIOXIDE  

E-Print Network [OSTI]

Research Division OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC11905 -DISCLAIMER - OXYGEN DIFFUSION IN HYPOSTOICHIOMETRICc o n e e n i g woroxygen self-diffusion coefficient

Kim, Kee Chul

2010-01-01T23:59:59.000Z

75

Formation, characterization and reactivity of adsorbed oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Abstract: The formation...

76

Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction...  

Broader source: Energy.gov (indexed) [DOE]

Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Presentation slides from the June 19, 2012, Fuel...

77

Oxygenate Supply/Demand Balances  

Gasoline and Diesel Fuel Update (EIA)

Oxygenate Supply/Demand Oxygenate Supply/Demand Balances in the Short-Term Integrated Forecasting Model By Tancred C.M. Lidderdale This article first appeared in the Short-Term Energy Outlook Annual Supplement 1995, Energy Information Administration, DOE/EIA-0202(95) (Washington, DC, July 1995), pp. 33-42, 83-85. The regression results and historical data for production, inventories, and imports have been updated in this presentation. Contents * Introduction o Table 1. Oxygenate production capacity and demand * Oxygenate demand o Table 2. Estimated RFG demand share - mandated RFG areas, January 1998 * Fuel ethanol supply and demand balance o Table 3. Fuel ethanol annual statistics * MTBE supply and demand balance o Table 4. EIA MTBE annual statistics * Refinery balances

78

It's Elemental - The Element Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nitrogen Nitrogen Previous Element (Nitrogen) The Periodic Table of Elements Next Element (Fluorine) Fluorine The Element Oxygen [Click for Isotope Data] 8 O Oxygen 15.9994 Atomic Number: 8 Atomic Weight: 15.9994 Melting Point: 54.36 K (-218.79°C or -361.82°F) Boiling Point: 90.20 K (-182.95°C or -297.31°F) Density: 0.001429 grams per cubic centimeter Phase at Room Temperature: Gas Element Classification: Non-metal Period Number: 2 Group Number: 16 Group Name: Chalcogen What's in a name? From the greek words oxys and genes, which together mean "acid forming." Say what? Oxygen is pronounced as OK-si-jen. History and Uses: Oxygen had been produced by several chemists prior to its discovery in 1774, but they failed to recognize it as a distinct element. Joseph

79

The System Boron—Oxygen  

Science Journals Connector (OSTI)

This presentation covers the years 1985 to 1988 and, in part, to 1992. It continues the previous discussion of the system boron—oxygen in “Boron Compounds” 3rd Suppl. Vol. 2, 1987, pp. 1/184, and earlier liter...

Gert Heller

1993-01-01T23:59:59.000Z

80

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the initial studies on newer compositions and also includes newer approaches to address various materials issues such as in metal-ceramic sealing. The current quarter's research has also focused on developing a comprehensive reliability model for predicting the structural behavior of the membranes in realistic conditions. In parallel to industry provided compositions, models membranes have been evaluated in varying environment. Of importance is the behavior of flaws and generation of new flaws aiding in fracture. Fracture mechanics parameters such as crack tip stresses are generated to characterize the influence of environment. Room temperature slow crack growth studies have also been initiated in industry provided compositions. The electrical conductivity and defect chemistry of an A site deficient compound (La{sub 0.55}Sr{sub 0.35}FeO{sub 3}) was studied. A higher conductivity was observed for La{sub 0.55}Sr{sub 0.35}FeO{sub 3} than that of La{sub 0.60}Sr{sub 0.40}FeO{sub 3} and La{sub 0.80}Sr{sub 0.20}FeO{sub 3}. Defect chemistry analysis showed that it was primarily contributed by a higher carrier concentration in La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. Moreover, the ability for oxygen vacancy generation is much higher in La{sub 0.55}Sr{sub 0.35}FeO{sub 3} as well, which indicates a lower bonding strength between Fe-O and a possible higher catalytic activity for La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. The program continued to investigate the thermodynamic properties (stability and phase separation behavior) and total conductivity of prototype membrane materials. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previous report listed initial measurements on a sample of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-x} prepared in-house by Praxair. Subsequently, a second sample of powder from a larger batch of sample were characterized and compared with the results from the previous batch.

S. Bandopadhyay; N. Nagabhushana; Thomas W. Eagar; Harold R. Larson; Raymundo Arroyave; X.-D Zhou; Y.-W. Shin; H.U. Anderson; Nigel Browning; Alan Jacobson; C.A. Mims

2003-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Water column oxygen demand and sediment oxygen flux: patterns of oxygen depletion in tidal creeks  

Science Journals Connector (OSTI)

Five study sites were chosen in Futch Creek, Hewletts Creek and Pages Creek,...1). Sites were chosen to reflect a range in the values of dissolved oxygen levels, chlorophyll a concentrations and nutrient (nitroge...

Tara A. MacPherson; Lawrence B. Cahoon; Michael A. Mallin

2007-07-01T23:59:59.000Z

82

Oxygen Transport Ceramic Membranes  

SciTech Connect (OSTI)

The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C in N{sub 2}. Space group of R3c was found to result in a better refinement and is used in this study. The difference for crystal structure, lattice parameters and local crystal chemistry for LSFT nearly unchanged when gas environment switched from air to N{sub 2}. Stable crack growth studies on Dense OTM bars provided by Praxair were done at room temperature in air. A bridge-compression fixture was fabricated to achieve stable pre-cracks from Vickers indents. Post fracture evaluation indicated stable crack growth from the indent and a regime of fast fracture. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. The thermal and chemical expansion of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were studied at 800 {le} T {le} 1000 C and at {approx} 1 x 10{sup -15} {le} pO{sub 2} {le} 0.21 atm. The thermal expansion coefficient of the sample was calculated from the dilatometric analysis in the temperature range between room temperature and 1200 C in air. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

2004-05-01T23:59:59.000Z

83

Researchers Directly Observe Oxygen Signature in the Oxygen-evolving  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Researchers Directly Observe Oxygen Signature in the Researchers Directly Observe Oxygen Signature in the Oxygen-evolving Complex of Photosynthesis Arguably the most important chemical reaction on earth is the photosynthetic splitting of water to molecular oxygen by the Mn-containing oxygen-evolving complex (Mn-OEC) in the protein known as photosystem II (PSII). It is this reaction which has, over the course of some 3.8 billion years, gradually filled our atmosphere with O2 and consequently enabled and sustained the evolution of complex aerobic life. Coupled to the reduction of carbon dioxide, biological photosynthesis contributes foodstuffs for nutrition while recycling CO2 from the atmosphere and replacing it with O2. By utilizing sunlight to power these energy-requiring reactions, photosynthesis also serves as a model for addressing societal energy needs as we enter an era of diminishing fossil fuel resources and climate change. Understanding, at the molecular level, the dynamics and mechanisms behind photosynthesis is of fundamental importance and will prove critical to the future design of devices aimed at converting sunlight into electrochemical energy and transportable fuel.

84

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES  

E-Print Network [OSTI]

OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES Alejandro Montoya, Jorge O. Gil, Fanor-rich site of the carbon basal plane of graphite and then, it dissociates into oxygen atoms.1,2 Oxygen atoms at the edge of the carbon surface can form covalent bonds with oxygen. These sites can chemisorb

Truong, Thanh N.

85

Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides  

E-Print Network [OSTI]

Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides Bassat J we obtain in both cases data concerning the oxygen diffusion in the bulk and the oxygen exchange with regards to the oxygen reduction reaction. Detailed experimental and analytical processes are given

Paris-Sud XI, Université de

86

Quantifying the areal extent and dissolved oxygen concentrations of Archean oxygen oases.  

E-Print Network [OSTI]

??Several lines of evidence indicate that the advent of oxygenic photosynthesis preceded the oxygenation of the atmosphere—perhaps by as much as 300 million years. The… (more)

Olson, Stephanie

2013-01-01T23:59:59.000Z

87

Mitochondrial reactive oxygen species and cancer  

E-Print Network [OSTI]

Mitochondria produce reactive oxygen species (mROS) as a natural by-product of electron transport chain activity. While initial studies focused on the damaging effects of reactive oxygen species, a recent paradigm shift ...

Chandel, Navdeep S

88

Microbial oceanography of anoxic oxygen minimum zones  

E-Print Network [OSTI]

Vast expanses of oxygen-deficient and nitrite-rich water define the major oxygen minimum zones (OMZs) of the global ocean. They support diverse microbial communities that influence the nitrogen economy of the oceans, ...

Ulloa, Osvaldo

89

The Role of Oxygen in Coal Gasification  

E-Print Network [OSTI]

Air Products supplies oxygen to a number of coal gasification and partial oxidation facilities worldwide. At the high operating pressures of these processes, economics favor the use of 90% and higher oxygen purities. The effect of inerts...

Klosek, J.; Smith, A. R.; Solomon, J.

90

Oxygen reduction on platinum : an EIS study  

E-Print Network [OSTI]

The oxygen reduction reaction (ORR) on platinum over yttria-stabilized zirconia (YSZ) is examined via electrochemical impedance spectroscopy (EIS) for oxygen partial pressures between 10-4 and 1 atm and at temperatures ...

Golfinopoulos, Theodore

2009-01-01T23:59:59.000Z

91

Microchemical systems for singlet oxygen generation  

E-Print Network [OSTI]

Chemical Oxygen-Iodine Lasers (COIL) are a technology of interest for industrial and military audiences. COILs are flowing gas lasers where the gain medium of iodine atoms is collisionally pumped by singlet delta oxygen ...

Hill, Tyrone F. (Tyrone Frank), 1980-

2008-01-01T23:59:59.000Z

92

Imaging Oxygen Molecules Up Close | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Imaging Oxygen Molecules Up Close Imaging Oxygen Molecules Up Close ARRA-enabled upgrades enhance research capabilities STM images of the same TiO2(110) area upon O2 chemisorption...

93

Composite oxygen ion transport element  

SciTech Connect (OSTI)

A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo.sub.5Si.sub.3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

Chen, Jack C. (Getzville, NY); Besecker, Charles J. (Batavia, IL); Chen, Hancun (Williamsville, NY); Robinson, Earil T. (Mentor, OH)

2007-06-12T23:59:59.000Z

94

Catalyst containing oxygen transport membrane  

SciTech Connect (OSTI)

A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

2012-12-04T23:59:59.000Z

95

Respiration, photosynthesis, and oxygen isotope fractionation in ...  

Science Journals Connector (OSTI)

Jan 25, 1971 ... Respiration, photosynthesis, and oxygen isotope fractionation in oceanic surface water1. Peter M. Kroopnick. Department of Oceanography,.

2000-01-04T23:59:59.000Z

96

Oxygen Detection via Nanoscale Optical Indicators  

E-Print Network [OSTI]

Oxygen Detection via Nanoscale Optical Indicators Ruby N. Ghosh Dept. of Physics Michigan State University East Lansing, MI, USA weekschr@msu.edu Abstract--Oxygen plays a ubiquitous role in terrestrial developed an optical technique for monitoring oxygen in both gas and liquid phases utilizing nanoscale metal

Ghosh, Ruby N.

97

8, 22252248, 2008 Detection of oxygen  

E-Print Network [OSTI]

ACPD 8, 2225­2248, 2008 Detection of oxygen emission related to spring bloom H. Yamagishi et al Chemistry and Physics Discussions Detection of regional scale sea-to-air oxygen emission related to spring bloom near Japan by using in-situ measurements of atmospheric oxygen/nitrogen ratio H. Yamagishi 1 , Y

Paris-Sud XI, Université de

98

Oxygen and Nitrogen Contamination During Arc Welding  

E-Print Network [OSTI]

) ) : ,- Oxygen and Nitrogen Contamination During Arc Welding T. W. Eagar Department of }faterials, mechanisms, and expected levels of oxygen and nitrogen contamination during gas tungsten arc, gas metal arc indicating the importance of dec9mposition of SiOz into silicon monoxide and oxygen are presented, indicating

Eagar, Thomas W.

99

Direct constraints on diffusion models from cosmic-ray positron data: Excluding the minimal model for dark matter searches  

Science Journals Connector (OSTI)

Galactic cosmic-ray (CR) transport parameters are usually constrained by the boron-to-carbon ratio. This procedure is generically plagued with degeneracies between the diffusion coefficient and the vertical extent of the Galactic magnetic halo. The latter is of paramount importance for indirect dark matter (DM) searches because it fixes the amount of DM annihilation or decay that contributes to the local antimatter CR flux. These degeneracies could be broken by using secondary radioactive species, but the current data still have large error bars, and this method is extremely sensitive to the very local interstellar medium properties. Here, we propose to use the low-energy CR positrons in the GeV range as another direct constraint on diffusion models. We show that the PAMELA data disfavor small diffusion halo (L?3??kpc) and large diffusion slope models and exclude the minimal configuration [Maurin et al. Astrophys. J. 555, 585 (2001); Donato et al. Phys. Rev. D 69, 063501 (2004)] widely used in the literature to bracket the uncertainties in the DM signal predictions. This is complementary to indirect constraints (diffuse radio and gamma-ray emissions) and has a strong impact on DM searches. Indeed, this makes the antiproton constraints more robust while enhancing the discovery/exclusion potential of current and future experiments, like AMS-02 and GAPS, especially in the antiproton and antideuteron channels.

Julien Lavalle; David Maurin; Antje Putze

2014-10-15T23:59:59.000Z

100

Dynamics of pulled desorption with effects of excluded volume interaction: The p-Laplacian diffusion equation and its exact solution  

E-Print Network [OSTI]

We analyze the dynamics of desorption of a polymer molecule which is pulled at one of its ends with force $f$, trying to desorb it. We assume a monomer to desorb when the pulling force on it exceeds a critical value $f_{c}$. We formulate an equation for the average position of the $n^{th}$ monomer, which takes into account excluded volume interaction through the blob-picture of a polymer under external constraints. The approach leads to a diffusion equation with a $p$-Laplacian for the propagation of the stretching along the chain. This has to be solved subject to a moving boundary condition. Interestingly, within this approach, the problem can be solved exactly in the trumpet, stem-flower and stem regimes. In the trumpet regime, we get $\\tau=\\tau_{0}n_d^{2}$ where $n_d$ is the number of monomers that have desorbed at the time $\\tau$. $\\tau_{0}$ is known only numerically, but for $f$ close to $f_{c}$, it is found to be $\\tau_{0}\\sim f_c/(f^{2/3}-f_{c}^{2/3})$. If one used simple Rouse dynamics, this result changes to {\

K. L. Sebastian; V. G. Rostiashvili; T. A. Vilgis

2011-08-31T23:59:59.000Z

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Direct constraints on diffusion models from cosmic-ray positron data: Excluding the Minimal model for dark matter searches  

E-Print Network [OSTI]

Galactic Cosmic-ray (CR) transport parameters are usually constrained by the boron-to-carbon ratio. This procedure is generically plagued with degeneracies between the diffusion coefficient and the vertical extent of the Galactic magnetic halo. The latter is of paramount importance for indirect dark matter (DM) searches, because it fixes the amount of DM annihilation or decay that contributes to the local antimatter CR flux. These degeneracies could be broken by using secondary radioactive species, but the current data still have large error bars, and this method is extremely sensitive to the very local interstellar medium (ISM) properties. Here, we propose to use the low-energy CR positrons in the GeV range as another direct constraint on diffusion models. We show that the PAMELA data disfavor small diffusion halo ($L\\lesssim 3$ kpc) and large diffusion slope models, and exclude the minimal ({\\em min}) configuration (Maurin et al. 2001, Donato et al. 2004) widely used in the literature to bracket the uncertainties in the DM signal predictions. This is complementary to indirect constraints (diffuse radio and gamma-ray emissions) and has strong impact on DM searches. Indeed this makes the antiproton constraints more robust while enhancing the discovery/exclusion potential of current and future experiments, like AMS-02 and GAPS, especially in the antiproton and antideuteron channels.

Julien Lavalle; David Maurin; Antje Putze

2015-01-22T23:59:59.000Z

102

The Mechanisms of Oxygen Reduction and Evolution Reactions in...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries. The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous...

103

Oxygen consumption of bovine granulosa cells in vitro.  

E-Print Network [OSTI]

??The oxygen consumption rate of granulosa cells is considered to be a key determinant of oocyte oxygenation in follicles. The oxygen status of the oocyte… (more)

Li, Dongxing

2012-01-01T23:59:59.000Z

104

Thickness Dependency of Thin Film Samaria Doped Ceria for Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dependency of Thin Film Samaria Doped Ceria for Oxygen Sensing . Thickness Dependency of Thin Film Samaria Doped Ceria for Oxygen Sensing . Abstract: High temperature oxygen...

105

Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as  

E-Print Network [OSTI]

Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as cancer treatment, photosensitized oxidations, and biomolecular degradation. Ground state oxygen state of an oxygen molecule is a singlet state, which can readily react with other singlet molecules

Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

106

Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes  

E-Print Network [OSTI]

1 Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes E;2 Abstract Oxygen permeation measurements were performed on two layered bismuth based oxide ceramics. Oxygen permeability for these systems was compared to permeability of the cubic fluorite type structure

Paris-Sud XI, Université de

107

Muon Capture in Oxygen-16  

Science Journals Connector (OSTI)

The muon capture rate in oxygen is used as a means for measuring the induced pseudoscalar coupling constant (CP) of weak interactions. The capture rate between the JP=0+ ground state of O16 and the 0-, 1-, 2-, and 3- states of N16 are calculated as a function of CP with different nuclear models. Using the experimental values of the transition rates, we then determine CP. We find that the transition rate, and therefore CP, depends strongly on the nuclear model. We conclude that 5

Vincent Gillet and David A. Jenkins

1965-10-11T23:59:59.000Z

108

(Data in thousand metric tons of silicon content unless otherwise noted) Domestic Production and Use: Estimated value of silicon alloys and metal (excluding semiconductor-and solar-  

E-Print Network [OSTI]

Production and Use: Estimated value of silicon alloys and metal (excluding semiconductor- and solar- grade and aluminum alloys and the chemical industry. The semiconductor and solar industries, which manufacture chips%; Venezuela, 15%; Canada, 8%; and other, 8%. Silicon metal: Brazil, 38%; South Africa, 24%; Canada, 16

109

Device and method for separating oxygen isotopes  

DOE Patents [OSTI]

A device and method for separating oxygen isotopes with an ArF laser which produces coherent radiation at approximately 193 nm. The output of the ArF laser is filtered in natural air and applied to an irradiation cell where it preferentially photodissociates molecules of oxygen gas containing .sup.17 O or .sup.18 O oxygen nuclides. A scavenger such as O.sub.2, CO or ethylene is used to collect the preferentially dissociated oxygen atoms and recycled to produce isotopically enriched molecular oxygen gas. Other embodiments utilize an ArF laser which is narrowly tuned with a prism or diffraction grating to preferentially photodissociate desired isotopes. Similarly, desired mixtures of isotopic gas can be used as a filter to photodissociate enriched preselected isotopes of oxygen.

Rockwood, Stephen D. (Los Alamos, NM); Sander, Robert K. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

110

A survey of alternative oxygen production technologies  

Science Journals Connector (OSTI)

Utilization of the Martian atmosphere for the production of fuel and oxygen has been extensively studied. The baseline fuel production process is a Sabatier reactor which produces methane and water from carbon dioxide and hydrogen. The oxygen produced from the electrolysis of the water is only half of that needed for methane-based rocket propellant and additional oxygen is needed for breathing air fuel cells and other energy sources. Zirconia electrolysis cells for the direct reduction of CO 2 are being developed as an alternative means of producing oxygen but present many challenges for a large-scale oxygen production system. The very high operating temperatures and fragile nature of the cells coupled with fairly high operating voltages leave room for improvement. This paper will survey alternative oxygen production technologies present data on operating characteristics materials of construction and some preliminary laboratory results on attempts to implement each.

Dale E. Lueck; Clyde F. Parrish; William J. Buttner; Jan M. Surma

2001-01-01T23:59:59.000Z

111

Oxygen penetration into the bulk of palladium  

Science Journals Connector (OSTI)

Oxygen penetration into the bulk of palladium ... During heating, the reaction rate exhibited an activity maximum at 650 K, whereas no activity maximum was found during the ... ...

C. T. Campbell; D. C. Foyt; J. M. White

1977-01-01T23:59:59.000Z

112

Oxygen-Enriched Combustion | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

tip sheet discusses how an increase in oxygen in combustion air can reduce the energy loss in the exhaust gases and increase process heating system efficiency. PROCESS HEATING...

113

Renewable Oxygenate Blending Effects on Gasoline Properties  

Science Journals Connector (OSTI)

Renewable Oxygenate Blending Effects on Gasoline Properties ... National Renewable Energy Laboratory, Golden, Colorado 80401, United States ... Energy Fuels, 2011, 25 (10), ...

Earl Christensen; Janet Yanowitz; Matthew Ratcliff; Robert L. McCormick

2011-08-16T23:59:59.000Z

114

Oxygen Concentration Microgradients for Cell Culture.  

E-Print Network [OSTI]

??There is a growing need for technology that can control microscale oxygen gradients onto a tissue or culture sample in vitro. This dissertation introduces the… (more)

Park, Jaehyun

2010-01-01T23:59:59.000Z

115

Oxygen ion-beam microlithography  

DOE Patents [OSTI]

A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used. 5 figures.

Tsuo, Y.S.

1991-08-20T23:59:59.000Z

116

Oxygen ion-beam microlithography  

DOE Patents [OSTI]

A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used.

Tsuo, Y. Simon (Lakewood, CO)

1991-01-01T23:59:59.000Z

117

Direct Observation of the Oxygenated Species during Oxygen Reduction on a  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Direct Observation of the Oxygenated Species during Oxygen Reduction on a Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray spectroscopy identification and DFT simulations of oxygenated intermediates on a platinum fuel-cell cathode. The study shows that two types of hydroxyl intermediates (non-hydrated OH and hydrated OH) with distinct activities coexist on a fuel-cell cathode. The performance of polymer-electrolyte-membrane (PEM) fuel cells is limited by the reduction at the cathode of various oxygenated intermediates in the four-electron pathway of the oxygen reduction reaction. A research team led by SLAC scientists performed x-ray spectroscopy identification and DFT simulations of oxygenated intermediates on a platinum fuel-cell cathode

118

Transient oxygen consumption rate measurements with the BDT?M? oxygen biosensor system  

E-Print Network [OSTI]

Oxygen consumption rate (OCR) is a reliable indicator of tissue health. Recently, the OCR of isolated human islets has been shown to predict transplant outcome in diabetic mice. The Oxygen Biosensor System (OBS) is a ...

Low, Clarke Alan

2008-01-01T23:59:59.000Z

119

High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen  

E-Print Network [OSTI]

High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen K. D. Gibson, Mark Viste, Errol C. Sanchez, and S. J. Sibener The James Franck Institute; accepted 30 November 1998 Exposure of Rh 111 to atomic oxygen leads to the facile formation of a full

Sibener, Steven

120

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Oxygenate Production Oxygenate Production Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Captive Refinery Oxygenate Plants Oxygenate production facilities located within or adjacent to a refinery complex. Fuel Ethanol An anhydrous denatured aliphatic alcohol intended for gasoline blending as described in Oxygenates definition. Gasohol A blend of finished motor gasoline containing alcohol (generally ethanol but sometimes methanol) at a concentration of 10 percent or less by volume. Data on gasohol that has at least 2.7 percent oxygen, by weight, and is intended for sale inside carbon monoxide nonattainment areas are included in data on oxygenated gasoline. Merchant Oxygenate Plants Oxygenate production facilities that are not associated with a petroleum refinery. Production from these facilities is sold under contract or on the spot market to refiners or other gasoline blenders.

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2001-04-01T23:59:59.000Z

122

Oxygen ion-conducting dense ceramic  

DOE Patents [OSTI]

Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

1997-01-01T23:59:59.000Z

123

Oxygen ion-conducting dense ceramic  

DOE Patents [OSTI]

Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

Balachandran, Uthamalingam (Hinsdale, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Morissette, Sherry L. (Las Cruces, NM); Pei, Shiyou (Naperville, IL)

1996-01-01T23:59:59.000Z

124

Singlet oxygen luminescence detection with a fibre-coupled superconducting  

E-Print Network [OSTI]

Singlet oxygen luminescence detection with a fibre-coupled superconducting nanowire single Triplet State Singlet State 1O2 Ground State Oxygen 3O2 Singlet oxygen Free space singlet oxygen luminescence detection Fibre-based singlet oxygen luminescence detection References Superconducting Detector

Greenaway, Alan

125

Selective photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents [OSTI]

A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

1998-01-01T23:59:59.000Z

126

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2004-04-01T23:59:59.000Z

127

Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen minimum zone (7001100 m)  

E-Print Network [OSTI]

Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen increased animal activity associated with increasing bottom-water oxygen concentration. We examined faunal community responses to oxygen and organic matter gradients across the lower oxygen minimum zone (OMZ

Levin, Lisa

128

Natural Ores as Oxygen Carriers in Chemical Looping Combustion  

Science Journals Connector (OSTI)

Natural Ores as Oxygen Carriers in Chemical Looping Combustion ... Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. ...

Hanjing Tian; Ranjani Siriwardane; Thomas Simonyi; James Poston

2013-01-02T23:59:59.000Z

129

Reactive oxygen species: a breath of life or death?  

E-Print Network [OSTI]

AP1, activator protein-1; ODD, oxygen-dependent degradationSignaling response when oxygen levels decrease (Fig. 1C;3. Halliwell B. Reactive oxygen species in living sys- tems:

Fruehauf, John P; Meyskens, Frank L Jr

2007-01-01T23:59:59.000Z

130

Blood oxygen transport and depletion : the key of consummate divers  

E-Print Network [OSTI]

and Dill, D. B. (1935). Oxygen dissociation curves of birdE. (1964). A venous blood oxygen reservoir in the divingand Torrance, J. D. (1977). Oxygen-Affinity of Avian Blood.

Meir, Jessica Ulrika

2009-01-01T23:59:59.000Z

131

Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Abstract: Since oxygen atom...

132

Oxygen Tension Modulates Neurite Outgrowth in PC12 Cells Through A Mechanism Involving HIF and VEGF  

E-Print Network [OSTI]

neural repair. Keywords Oxygen tension . Neurite extension .respective physiological oxygen microenvironments (Chen etet al. 2008). For example, oxygen tension differentially

Genetos, Damian C.; Cheung, Whitney K.; Decaris, Martin L.; Leach, J. Kent

2010-01-01T23:59:59.000Z

133

Long-term oxygen sensor implantation in the porcine subcutaneous environment  

E-Print Network [OSTI]

Membrane-­?Covered  Oxygen  Electrode.   Analytical  Microvascular  and  tissue  oxygen   distribution.  vitro  stability  of  an  oxygen  sensor.   Anal  Chem,  

Kumosa, Lucas Stefan

2011-01-01T23:59:59.000Z

134

On the maximum value of the cosmic abundance of oxygen and the oxygen yield  

E-Print Network [OSTI]

We search for the maximum oxygen abundance in spiral galaxies. Because this maximum value is expected to occur in the centers of the most luminous galaxies, we have constructed the luminosity - central metallicity diagram for spiral galaxies, based on a large compilation of existing data on oxygen abundances of HII regions in spiral galaxies. We found that this diagram shows a plateau at high luminosities (-22.3 oxygen abundance 12+log(O/H) ~ 8.87. This provides strong evidence that the oxygen abundance in the centers of the most luminous metal-rich galaxies reaches the maximum attainable value of oxygen abundance. Since some fraction of the oxygen (about 0.08 dex) is expected to be locked into dust grains, the maximum value of the true gas+dust oxygen abundance in spiral galaxies is 12+log(O/H) ~ 8.95. This value is a factor of ~ 2 higher than the recently estimated solar value. Based on the derived maximum oxygen abundance in galaxies, we found the oxygen yield to be about 0.0035, depending on the fraction of oxygen incorporated into dust grains.

L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

2007-01-11T23:59:59.000Z

135

Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies. Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies....

136

Density Functional Theory Study of Oxygen Reduction Activity...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Study of Oxygen Reduction Activity on Ultrathin Platinum Nanotubes. Density Functional Theory Study of Oxygen Reduction Activity on Ultrathin Platinum Nanotubes. Abstract: The...

137

Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers National Energy Technology Laboratory Contact NETL...

138

Testing Oxygen Reduction Reaction Activity with the Rotating...  

Broader source: Energy.gov (indexed) [DOE]

Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique...

139

Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium 2007 Diesel Engine-Efficiency &...

140

Oxygen detected in atmosphere of Saturn's moon Dione  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of...

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for...

142

Effects of Oxygen-Containing Functional Groups on Supercapacitor...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen-Containing Functional Groups on Supercapacitor Performance. Effects of Oxygen-Containing Functional Groups on Supercapacitor Performance. Abstract: Molecular dynamics (MD)...

143

Isolation, Characterization of an Intermediate in an Oxygen Atom...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Characterization of an Intermediate in an Oxygen Atom-Transfer Reaction, and the Determination of the Bond Isolation, Characterization of an Intermediate in an Oxygen Atom-Transfer...

144

Direct Measurement of Oxygen Incorporation into Thin Film Oxides...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Measurement of Oxygen Incorporation into Thin Film Oxides at Room Temperature Upon Ultraviolet Phton Irradiation. Direct Measurement of Oxygen Incorporation into Thin Film Oxides...

145

Oxygen Transport Studies in Nanocrystalline Ceria Films. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transport Studies in Nanocrystalline Ceria Films. Oxygen Transport Studies in Nanocrystalline Ceria Films. Abstract: Oxygen uptake and conductivity were measured by nuclear...

146

Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated Nanocrystalline Cubic Zirconia. Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated...

147

Density Functional Study of the Structure, Stability and Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Study of the Structure, Stability and Oxygen Reduction Activity of Ultrathin Platinum Nanowires. Density Functional Study of the Structure, Stability and Oxygen Reduction Activity...

148

Electron-Stimulated Production of Molecular Oxygen in Amorphous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water. Electron-Stimulated Production of Molecular Oxygen in Amorphous Solid Water. Abstract: The low-energy, electron-stimulated production of molecular oxygen from pure amorphous...

149

Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Abstract: The research described in...

150

Advantages of Oxygenates Fuels over Gasoline in Direct Injection...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines...

151

LED–LED portable oxygen gas sensor  

Science Journals Connector (OSTI)

A portable instrument for oxygen determination, based on the quenching of phosphorescent octaethylporphyrin by gaseous O2..., has been developed using the fluorimetric paired emitter–detector diode technique (FPE...

I. M. Perez de Vargas-Sansalvador; C. Fay…

2012-12-01T23:59:59.000Z

152

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-08-01T23:59:59.000Z

153

Electron-impact excitation of neutral oxygen  

E-Print Network [OSTI]

Aims: To calculate transition rates from ground and excited states in neutral oxygen atoms due to electron collisions for non-LTE modelling of oxygen in late-type stellar atmospheres, thus enabling reliable interpretation of oxygen lines in stellar spectra. Methods: A 38-state R-matrix calculation in LS-coupling has been performed. Basis orbitals from the literature (Thomas et al.) are adopted, and a large set of configurations are included to obtain good representations of the target wavefunctions. Rate coefficients are calculated by averaging over a Maxwellian velocity distribution. Results: Estimates for the cross sections and rate coefficients are presented for transitions between the seven lowest LS states of neutral oxygen. The cross sections for excitation from the ground state compare well with existing experimental and recent theoretical results.

P. S. Barklem

2006-09-25T23:59:59.000Z

154

Design optimization of oxygenated fluid pump  

E-Print Network [OSTI]

In medical emergencies, an oxygen-starved brain quickly suffers irreparable damage. In many cases, patients who stop breathing can be resuscitated but suffer from brain damage. Dr. John Kheir from Boston Children's Hospital ...

Piazzarolo, Bruno Aiala

2012-01-01T23:59:59.000Z

155

Interactions of oxygen with Zr(0001)  

SciTech Connect (OSTI)

Interaction of oxygen with Zr(0001) have been studied using low energy electron diffraction (LEED), work function ([Delta][phi]), static and dynamic secondary ion mass spectrometry (SSIMS, DSIMS), thermal desorption spectroscopy (TDS), Auger electron spectroscopy (AES) and nuclear reaction analysis (NRA). The initial sticking coefficient of oxygen is close to unity up to [approximately]0.75 ML at 90, 293 and 473 K. Oxygen chemisorption is disordered at room temperature and below. Heating the disordered surface to [approximately]473 K causes all oxygen to move to subsurface sites. A (1x2) ordered oxygen underlayer is formed consisting of three rotated domains of (1x2) superstructure with the oxygen atoms located between the first and second planes of zirconium atoms. This structure is stable up to about 573 K, above which temperature oxygen diffuses into the bulk. AES measurements employing oxide and metal signals were used to model the growth of oxide which was found to be temperature dependent. Both NRA and AES indicate linear oxygen uptake kinetics at 90 K with abrupt passivation as the limiting thickness is reached. SSIMS ion yield data taken during the oxidation of Zr(0001) at 90, 293 and 473 K was interpretable in the context of the oxygen coverage. Dissolution into the bulk of the saturated oxide layer grown at 90 K appears to occur by an island-type mechanism rather than layer-by-layer dissolution from the oxide-metal interface. Large [Delta][phi] changes that occur upon oxidation at 90 K and temperature ramping of the saturated oxide to 300 K are attributable to reversible molecular oxygen adsorption on the oxide. The diffusion of oxygen normal to the [0001] plane of zirconium has been measured by AES: D[sub 0] = (4.14.[+-]1.92) x 10[sup [minus]2] cm[sup [minus]2] s[sup [minus]1] and E[sub a]= 199.1 [+-]2.6 kJ mol[sup [minus]1]. The fundamental vibrational frequency for the [alpha]-Zr lattice was calculated to be (6.3 [+-] 2.9) x 10[sup 13]s[sup [minus]1].

Flinn, B.J.

1992-01-01T23:59:59.000Z

156

Oxy-combustion: Oxygen Transport Membrane Development  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

combustion: Oxygen Transport combustion: Oxygen Transport Membrane Development Background The mission of the U.S. Department of Energy's (DOE) Existing Plants, Emissions & Capture (EPEC) Research & Development (R&D) Program is to develop innovative environmental control technologies to enable full use of the nation's vast coal reserves, while at the same time allowing the current fleet of coal-fired power plants to comply with existing and emerging environmental regulations. The EPEC R&D

157

Underground coal gasification using oxygen and steam  

SciTech Connect (OSTI)

In this paper, through model experiment of the underground coal gasification, the effects of pure oxygen gasification, oxygen-steam gasification, and moving-point gasification methods on the underground gasification process and gas quality were studied. Experiments showed that H{sub 2} and CO volume fraction in product gas during the pure oxygen gasification was 23.63-30.24% and 35.22-46.32%, respectively, with the gas heating value exceeding 11.00 MJ/m{sup 3}; under the oxygen-steam gasification, when the steam/oxygen ratio stood at 2: 1, gas compositions remained virtually stable and CO + H{sub 2} was basically between 61.66 and 71.29%. Moving-point gasification could effectively improve the changes in the cavity in the coal seams or the effects of roof inbreak on gas quality; the ratio of gas flowing quantity to oxygen supplying quantity was between 3.1:1 and 3.5:1 and took on the linear changes; on the basis of the test data, the reasons for gas quality changes under different gasification conditions were analyzed.

Yang, L.H.; Zhang, X.; Liu, S. [China University of Mining & Technology, Xuzhou (China)

2009-07-01T23:59:59.000Z

158

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program in the seventh quarter October-December 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. Computational fluid dynamic (CFD) modeling of oxygen injection strategies was performed during the quarter resulting in data that suggest the oxygen injection reduces NOx emissions while reducing LOI. Pilot-scale testing activities concluded at the University of Utah this quarter. Testing demonstrated that some experimental conditions can lead to NOx emissions well below the 0.15 lb/MMBtu limit. Evaluation of alternative OTM materials with improved mechanical properties continued this quarter. Powder procedure optimization continued and sintering trial began on an element with a new design. Several OTM elements were tested in Praxair's single tube high-pressure test facility under various conditions. A modified PSO1d element demonstrated stable oxygen product purity of >98% and oxygen flux of 68% of target. Updated test results and projected economic performance have been reviewed with the Utility Industrial Advisors. The economic comparison remains very favorable for O{sub 2} enhanced combustion. Discussions regarding possible Beta sites have been held with three other utilities in addition to the industrial advisors. Proposals will be prepared after the completion of full scale burner testing. Beta test cost estimating work has been initiated.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-01-01T23:59:59.000Z

159

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the second year. The first round of pilot scale testing with 3 bituminous coals was completed at the University of Utah. Full-scale testing equipment is in place and experiments are underway. Coal combustion lab-scale testing was completed at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. Combustion modeling activities continued with pilot-scale combustion test furnace simulations. 75% of target oxygen flux was demonstrated with small PSO1 tube in Praxair's single tube high-pressure test facility. The production of oxygen with a purity of better than 99.999% was demonstrated. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host sites have been identified.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-04-01T23:59:59.000Z

160

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

Increased environmental regulations will require utility boilers to reduce NO{sub x} emissions to less than 0.15lb/MMBtu in the near term. Conventional technologies such as Selective Catalytic Reduction (SCR) and Selective Non-Catalytic Reduction (SNCR) are unable to achieve these lowered emission levels without substantially higher costs and major operating problems. Oxygen enhanced combustion is a novel technology that allows utilities to meet the NO{sub x} emission requirements without the operational problems that occur with SCR and SNCR. Furthermore, oxygen enhanced combustion can achieve these NO{sub x} limits at costs lower than conventional technologies. The objective of this program is to demonstrate the use of oxygen enhanced combustion as a technical and economical method of meeting the EPA State Implementation Plan for NO{sub x} reduction to less than 0.15lb/MMBtu for a wide range of boilers and coal. The oxygen enhanced coal combustion program (Task 1) focused this quarter on the specific objective of exploration of the impact of oxygen enrichment on NO{sub x} formation utilizing small-scale combustors for parametric testing. Research efforts toward understanding any limitations to the applicability of the technology to different burners and fuels such as different types of coal are underway. The objective of the oxygen transport membrane (OTM) materials development program (Task 2.1) is to ascertain a suitable material composition that can be fabricated into dense tubes capable of producing the target oxygen flux under the operating conditions. This requires that the material have sufficient oxygen permeation resulting from high oxygen ion conductivity, high electronic conductivity and high oxygen surface exchange rate. The OTM element development program (Task 2.2) objective is to develop, fabricate and characterize OTM elements for laboratory and pilot reactors utilizing quality control parameters to ensure reproducibility and superior performance. A specific goal is to achieve a material that will sinter to desired density without compromising other variables such as reaction to binder systems or phase purity. Oxygen-enhanced combustion requires a facility which is capable of supplying high purity oxygen (>99.5%) at low costs. This goal can be achieved through the thermal integration of high temperature air separation with ceramic OTM. The objective of the OTM process development program (Task 2.3) is to demonstrate successfully the program objectives on a lab-scale single OTM tube reactor under process conditions comparable to those of an optimum large-scale oxygen facility. This quarterly technical progress report will summarize work accomplished for the Program through the first quarter April--June 2000 in the following task areas: Task 1 Oxygen Enhanced Coal Combustion; Task 2 Oxygen Transport Membranes; and Task 4 Program Management.

Lawrence E. Bool; Jack C. Chen; David R. Thompson

2000-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Oxygen generator for medical applications (USIC)  

SciTech Connect (OSTI)

The overall Project objective is to develop a portable, non-cryogenic oxygen generator capable of supplying medical grade oxygen at sufficient flow rates to allow the field application of the Topical Hyperbaric Oxygen Therapy (THOT{reg_sign}) developed by Numotech, Inc. This project was sponsored by the U.S. Department of Energy Global Initiatives for Proliferation Prevention (GIPP) and is managed by collaboration between Sandia National Laboratories (SNL), Numotech, Inc, and LLC SPE 'Spektr-Conversion.' The project had two phases, with the objective of Phase I being to develop, build and test a laboratory prototype of the membrane-pressure swing adsorber (PSA) system producing at 15 L/min of oxygen with a minimum of 98% oxygen purity. Phase II objectives were to further refine and identify the pre-requisites needed for a commercial product and to determine the feasibility of producing 15 L/min of oxygen with a minimum oxygen purity of 99%. In Phase I, Spektr built up the necessary infrastructure to perform experimental work and proceeded to build and demonstrate a membrane-PSA laboratory prototype capable of producing 98% purity oxygen at a flow rate of 5 L/min. Spektr offered a plausible path to scale up the process for 15 L/min. Based on the success and experimental results obtained in Phase I, Spektr performed work in three areas for Phase II: construction of a 15 L/min PSA; investigation of compressor requirements for the front end of the membrane/PSA system; and performing modeling and simulation of assess the feasibility of producing oxygen with a purity greater than 99%. Spektr successfully completed all of the tasks under Phase II. A prototype 15 L/min PSA was constructed and operated. Spektr determined that no 'off the shelf' air compressors met all of the specifications required for the membrane-PSA, so a custom compressor will likely need to be built. Modeling and simulation concluded that production of oxygen with purities greater than 99% was possible using a Membrane-PSA system.

Staiger, C. L.

2012-03-01T23:59:59.000Z

162

Absorption process for producing oxygen and nitrogen and solution therefor  

DOE Patents [OSTI]

Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible. 1 figure

Roman, I.C.; Baker, R.W.

1990-09-25T23:59:59.000Z

163

Absorption process for producing oxygen and nitrogen and solution therefor  

DOE Patents [OSTI]

Process for the separation and purification of oxygen and nitrogen is disclosed which utilizes solutions of oxygen carriers to selectively absorb oxygen from a gaseous stream, leaving nitrogen as a byproduct. In the process, an oxygen carrier capable of reversibly binding molecular oxygen is dissolved in a solvent solution, which absorbs oxygen from an oxygen-containing gaseous feed stream such as atmospheric air and desorbs oxygen to a gaseous product stream. The feed stream is maintained at a sufficiently high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, while the product stream is maintained at a sufficiently low oxygen pressure to keep the carrier in its deoxygenated form during desorption. In an alternate mode of operation, the carrier solution is maintained at a sufficiently low temperature and high oxygen pressure to keep the oxygen carrier in its oxygenated form during absorption, and at a sufficiently high temperature to keep the carrier in its deoxygenated form during desorption. Under such conditions, exceptionally high oxygen concentrations on the order of 95% to 99% are obtained, as well as a long carrier lifetime in excess of 3 months, making the process commercially feasible.

Roman, Ian C. [Wilmington, DE; Baker, Richard W. [Palo Alto, CA

1990-09-25T23:59:59.000Z

164

Oxygen Toxicity Calculations by Erik C. Baker, P.E.  

E-Print Network [OSTI]

1 Oxygen Toxicity Calculations by Erik C. Baker, P.E. Management of exposure to oxygen toxicity myself using the good ole' FORTRAN programming language, I found that incorporating oxygen toxicity for others. Background Two oxygen toxicity parameters are typically "tracked" in technical diving

Read, Charles

165

Energetic neutral atoms at Mars 4. Imaging of planetary oxygen  

E-Print Network [OSTI]

Energetic neutral atoms at Mars 4. Imaging of planetary oxygen S. Barabash and M. Holmstro of the Martian oxygen exosphere/corona results in the production of planetary oxygen ions. The newborn ions start. The oxygen ions can then charge exchange with the neutral gases (H, H2, and O) of the Martian exosphere

Lukyanov, Alex

166

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the eleventh quarter, October-December 2002, in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah were aimed at confirming the importance of oxygen injection strategy for different types of burners. CFD modeling at REI was used to better understand the potential for increased corrosion under oxygen enhanced combustion conditions. Data from a full-scale demonstration test in Springfield, MO were analyzed. OTM element development continued with preliminary investigation of an alternative method of fabrication of PSO1d elements. OTM process development continued with long-term testing of a PSO1d element. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. A first commercial proposal has been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-02-01T23:59:59.000Z

167

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the twelfth quarter, January-March 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah explored both the effectiveness of oxygen addition and the best way to add oxygen with a scaled version of Riley Power's newest low NOx burner design. CFD modeling was done to compare the REI's modeling results for James River Unit 3 with the NOx and LOI results obtained during the demonstration program at that facility. Investigation of an alternative method of fabrication of PSO1d elements was conducted. OTM process development work has concluded with the completion of a long-term test of a PSO1d element Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2003-04-01T23:59:59.000Z

168

On the solar nickel and oxygen abundances  

E-Print Network [OSTI]

Determinations of the solar oxygen content relying on the neutral forbidden transition at 630 nm depend upon the nickel abundance, due to a Ni I blend. Here we rederive the solar nickel abundance, using the same ab initio 3D hydrodynamic model of the solar photosphere employed in the recent revision of the abundances of C, N, O and other elements. Using 17 weak, unblended lines of Ni I together with the most accurate atomic and observational data available we find log epsilon_Ni = 6.17 +/- 0.02 (statistical) +/- 0.05 (systematic), a downwards shift of 0.06 to 0.08 dex relative to previous 1D-based abundances. We investigate the implications of the new nickel abundance for studies of the solar oxygen abundance based on the [O I] 630 nm line in the quiet Sun. Furthermore, we demonstrate that the oxygen abundance implied by the recent sunspot spectropolarimetric study of Centeno & Socas-Navarro needs to be revised downwards from log epsilon_O = 8.86 +/- 0.07 to 8.71 +/- 0.10. This revision is based on the new nickel abundance, application of the best available gf-value for the 630 nm forbidden oxygen line, and a more transparent treatment of CO formation. Determinations of the solar oxygen content relying on forbidden lines now appear to converge around log epsilon_O = 8.7.

Pat Scott; Martin Asplund; Nicolas Grevesse; A. Jacques Sauval

2008-11-05T23:59:59.000Z

169

Oxygen abundance of open cluster dwarfs  

E-Print Network [OSTI]

We present oxygen abundances of dwarfs in the young open cluster IC 4665 deduced from the OI $\\lambda$7774 triplet lines and of dwarfs in the open cluster Pleiades derived from the [OI] $\\lambda$6300 forbidden line. Stellar parameters and oxygen abundances were derived using the spectroscopic synthesis tool SME (Spectroscopy Made Easy). We find a dramatic increase in the upper boundary of the OI triplet abundances with decreasing temperature in the dwarfs of IC 4665, consistent with the trend found by Schuler et al. in the open clusters Pleiades and M 34, and to a less extent in the cool dwarfs of Hyades (Schuler et al. 2006a) and UMa (King & Schuler 2005). By contrast, oxygen abundances derived from the [OI] $\\lambda$6300 forbidden line for stars in Pleiades and Hyades (Schuler et al. 2006b) are constant within the errors. Possible mechanisms that may lead a varying oxygen triplet line abundance are examined, including systematic errors in the stellar parameter determinations, the NLTE effects, surface activities and granulation. The age-related effects stellar surface activities (especially the chromospheric activities) are suggested by our analysis to blame for the large spreads of oxygen triplet line abundances.

Z. -X. Shen; X. -W. Liu; H. -W. Zhang; B. Jones; D. N. C. Lin

2007-03-30T23:59:59.000Z

170

Oxygen Hydration Mechanism for the Oxygen Reduction Reaction at Pt and Pd Fuel Cell Catalysts  

Science Journals Connector (OSTI)

Oxygen Hydration Mechanism for the Oxygen Reduction Reaction at Pt and Pd Fuel Cell Catalysts ... Catalytic Reactions on the Open-Edge Sites of Nitrogen-Doped Carbon Nanotubes as Cathode Catalyst for Hydrogen Fuel Cells ... Despite significant progress made the past decade on reducing the platinum catalyst loading in the PEMFC electrodes, further ... ...

Yao Sha; Ted H. Yu; Boris V. Merinov; Pezhman Shirvanian; William A. Goddard; III

2011-02-24T23:59:59.000Z

171

Oxygen: From Environment to Genes. The periodic occurrence of oxygen minima can powerfully influence organisms living in near  

E-Print Network [OSTI]

Oxygen: From Environment to Genes. The periodic occurrence of oxygen minima can powerfully to the winter of 2014. Their scholarly work is presented in this collection. #12;1 Oxygen: From Environment", 2013, 2014 Table of contents Page 2. Laura Lilly - Low-oxygen formation along the California current. 6

172

Photochemical Escape of Oxygen from Early Mars  

E-Print Network [OSTI]

Photochemical escape is an important process for oxygen escape from present Mars. In this work, a 1-D Monte-Carlo Model is developed to calculate escape rates of energetic oxygen atoms produced from O2+ dissociative recombination reactions (DR) under 1, 3, 10, and 20 times present solar XUV fluxes. We found that although the overall DR rates increase with solar XUV flux almost linearly, oxygen escape rate increases from 1 to 10 times present solar XUV conditions but decreases when increasing solar XUV flux further. Analysis shows that atomic species in the upper thermosphere of early Mars increases more rapidly than O2+ when increasing XUV fluxes. While the latter is the source of energetic O atoms, the former increases the collision probability and thus decreases the escape probability of energetic O. Our results suggest that photochemical escape be a less important escape mechanism than previously thought for the loss of water and/or CO2 from early Mars.

Zhao, Jinjin

2015-01-01T23:59:59.000Z

173

Inelastic neutron scattering from confined molecular oxygen  

Science Journals Connector (OSTI)

Inelastic neutron-scattering measurements were carried out on condensed bulk and confined molecular oxygen. The phase transitions of the oxygen confined in cylindrical pores with diameter of ?94?Å are suppressed below their bulk temperatures or in the case of the lowest-temperature transition to the ? phase are suppressed entirely. This last observation is possibly due to the low latent heat of transition for this transition. Both elastic and inelastic neutron-scattering data indicate a mixing of oxygen crystal phases upon confinement. Magnetic ordering fluctuations in the ? phase are found to have similar energy-dependent profiles for confined and bulk excitations showing that the magnetic correlation function decay is unaffected by the finite crystal size in confinement.

Duncan Kilburn; Paul E. Sokol; Craig M. Brown

2008-12-29T23:59:59.000Z

174

Oxygen control in makeup water for PWRs  

SciTech Connect (OSTI)

This study describes the oxygen control program and improvements to the make-up water system components of PWR nuclear plants with the ultimate goal of reducing corrosion related problems in the steam generators and other secondary system components. A PWR plant that has a vacuum degasifier has been selected to establish the basis for the program. Following the investigation of the make-up water system components, the report presents instrumentation developed for the program. Recommendations are provided for improvements to the various make-up water system components to lower the dissolved oxygen levels. 5 refs., 23 figs., 3 tabs.

Silaghy, F. (Burns and Roe, Inc., Oradell, NJ (USA))

1990-08-01T23:59:59.000Z

175

Guidelines Establishing Criteria for Excluding Buildings from the Energy Performance Requirements of Section 543 of the National Energy Conservation Policy Act as Amended by the Energy Policy Act of 2005  

Broader source: Energy.gov [DOE]

This document contains the Guidelines Establishing Criteria for Excluding Buildings from the Energy Performance Requirements of Section 543 of the National Energy Conservation Policy Act as Amended by the Energy Policy Act of 2005

176

Atmospheric Oxygen: Isotopic Composition and Solubility Fractionation  

Science Journals Connector (OSTI)

...where the subscripts aq and gas refer to the aqueous phase and the gas phase, respectively. The single-stage...adsorption and desorp-tion of oxygen gas on type SA molecular sieve...material seems to be debris of the Cyprus-sized planetesimal that produced...

P. Kroopnick; H. Craig

1972-01-07T23:59:59.000Z

177

Oxygen addition to sulfur of metal thiolates  

E-Print Network [OSTI]

, and characterized. Molecular oxygen or hydrogen peroxide reacted with (N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane-nickel(II), (BME-DACO)2Ni3 +2, to produce a trimetallic, (N,N'-bismercaptoethyl-1,5-diazacyclooctane-nickel(II))-nickelate, (BME-DACO)2Ni3 2...

Soma, Takako

2012-06-07T23:59:59.000Z

178

Oxygen Limitation within a Bacterial Aggregate  

Science Journals Connector (OSTI)

...standard deviation of the average of cells exposed to 2...and Doring G. 2002. Effects of reduced mucus oxygen...Lewandowski Z. 1994. Effects of biofilm structures...Dietrich LE , Okegbe C, Price-Whelan A, Sakhtah...capability. Energy Fuels 20 :1565-1571. doi...

Aimee K. Wessel; Talha A. Arshad; Mignon Fitzpatrick; Jodi L. Connell; Roger T. Bonnecaze; Jason B. Shear; Marvin Whiteley

2014-04-01T23:59:59.000Z

179

Oxygen Transport Ceramic Membranes Quarterly Report  

E-Print Network [OSTI]

/Reaction rates in Ion 21 Transport Membranes using Isotope Tracer and Transient Kinetic Techniques CONCLUSIONS 30Oxygen Transport Ceramic Membranes Quarterly Report January 2003 ­ March 2003 Principal Authors on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane

Eagar, Thomas W.

180

Novel Membranes and Processes for Oxygen Enrichment  

SciTech Connect (OSTI)

The overall goal of this project is to develop a membrane process that produces air containing 25-35% oxygen, at a cost of $25-40/ton of equivalent pure oxygen (EPO2). Oxygen-enriched air at such a low cost will allow existing air-fueled furnaces to be converted economically to oxygen-enriched furnaces, which in turn will improve the economic and energy efficiency of combustion processes significantly, and reduce the cost of CO{sub 2} capture and sequestration from flue gases throughout the U.S. manufacturing industries. During the 12-month Concept Definition project: We identified a series of perfluoropolymers (PFPs) with promising oxygen/nitrogen separation properties, which were successfully made into thin film composite membranes. The membranes showed oxygen permeance as high as 1,200 gpu and oxygen/nitrogen selectivity of 3.0, and the permeance and selectivity were stable over the time period tested (60 days). We successfully scaled up the production of high-flux PFP-based membranes, using MTR's commercial coaters. Two bench-scale spiral-wound modules with countercurrent designs were made and parametric tests were performed to understand the effect of feed flow rate and pressure, permeate pressure and sweep flow rate on the membrane module separation properties. At various operating conditions that modeled potential industrial operating conditions, the module separation properties were similar to the pure-gas separation properties in the membrane stamps. We also identified and synthesized new polymers [including polymers of intrinsic microporosity (PIMs) and polyimides] with higher oxygen/nitrogen selectivity (3.5-5.0) than the PFPs, and made these polymers into thin film composite membranes. However, these membranes were susceptible to severe aging; pure-gas permeance decreased nearly six-fold within two weeks, making them impractical for industrial applications of oxygen enrichment. We tested the effect of oxygen-enriched air on NO{sub x} emissions using a Bloom baffle burner at GTI. The results are positive and confirm that oxygen-enriched combustion can be carried out without producing higher levels of NOx than normal air firing, if lancing of combustion air is used and the excess air levels are controlled. A simple economic study shows that the membrane processes can produce O{sub 2} at less than $40/ton EPO{sub 2} and an energy cost of 1.1-1.5 MMBtu/ton EPO{sub 2}, which are very favorable compared with conventional technologies such as cryogenics and vacuum pressure swing adsorption processes. The benefits of integrated membrane processes/combustion process trains have been evaluated, and show good savings in process costs and energy consumption, as well as reduced CO{sub 2} emissions. For example, if air containing 30% oxygen is used in natural gas furnaces, the net natural gas savings are an estimated 18% at a burner temperature of 2,500 F, and 32% at a burner temperature of 3,000 F. With a 20% market penetration of membrane-based oxygen-enriched combustion in all combustion processes by 2020, the energy savings would be 414-736 TBtu/y in the U.S. The comparable net cost savings are estimated at $1.2-2.1 billion per year by 2020, calculated as the value of fuel savings subtracted from the cost of oxygen production. The fuel savings of 18%-32% by the membrane/oxygen-enriched combustion corresponds to an 18%-32% reduction in CO{sub 2} emissions, or 23-40 MM ton/y less CO{sub 2} from natural gas-fired furnaces by 2020. In summary, results from this project (Concept Definition phase) are highly promising and clearly demonstrate that membrane processes can produce oxygen-enriched air in a low cost manner that will lower operating costs and energy consumption in industrial combustion processes. Future work will focus on proof-of-concept bench-scale demonstration in the laboratory.

Lin, Haiqing

2011-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Effects of ethanol content on gasohol PFI engine wide-open-throttle operation  

E-Print Network [OSTI]

The NOx emission and knock characteristics of a PFI engine operating on ethanol/gasoline mixtures were assessed at 1500 and 2000 rpm with ? =1 under Wide-Open-Throttle condition. There was no significant charge cooling due ...

Cheng, Wai K.

182

Hydrocarbon emissions in a homogeneous direct-injection spark engine : gasoline and gasohol  

E-Print Network [OSTI]

In order to better understand the effects on hydrocarbon emissions of loading, engine temperature, fuel type, and injection timing, a series of experiments was performed. The effect of loading was observed by running the ...

Tharp, Ronald S

2008-01-01T23:59:59.000Z

183

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

U.S. Weekly Products Supplied U.S. Weekly Products Supplied Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Distillate Fuel Oil A general classification for one of the petroleum fractions produced in conventional distillation operations. It includes diesel fuels and fuel oils. Products known as No. 1, No. 2, and No. 4 diesel fuel are used in on-highway diesel engines, such as those in trucks and automobiles, as well as off-highway engines, such as those in railroad locomotives and agricultural machinery. Products known as No. 1, No. 2, and No. 4 fuel oils are used primarily for space heating and electric power generation. Finished Motor Gasoline A complex mixture of relatively volatile hydrocarbons with or without small quantities of additives, blended to form a fuel suitable for use in spark-ignition engines. Motor gasoline, as defined in ASTM Specification D 4814 or Federal Specification VV-G-1690C, is characterized as having a boiling range of 122 to 158 degrees Fahrenheit at the 10 percent recovery point to 365 to 374 degrees Fahrenheit at the 90 percent recovery point. Motor Gasoline includes conventional gasoline; all types of oxygenated gasoline, including gasohol; and reformulated gasoline, but excludes aviation gasoline. Note: Volumetric data on blending components, such as oxygenates, are not counted in data on finished motor gasoline until the blending components are blended into the gasoline.

184

Oxygen-producing inert anodes for SOM process  

DOE Patents [OSTI]

An electrolysis system for generating a metal and molecular oxygen includes a container for receiving a metal oxide containing a metallic species to be extracted, a cathode positioned to contact a metal oxide housed within the container; an oxygen-ion-conducting membrane positioned to contact a metal oxide housed within the container; an anode in contact with the oxygen-ion-conducting membrane and spaced apart from a metal oxide housed within the container, said anode selected from the group consisting of liquid metal silver, oxygen stable electronic oxides, oxygen stable crucible cermets, and stabilized zirconia composites with oxygen stable electronic oxides.

Pal, Uday B

2014-02-25T23:59:59.000Z

185

The Economics of Oxygen Enriched Air Production Via Membranes  

E-Print Network [OSTI]

Oxygen enriched air combustion is a recognized approach to energy conservation. Conventional methods of producing oxygen enriched air: Pressure Swing Adsorption and Cryogenics, are energy-intensive and expensive. In this paper the economics of using...

Gollan, A.; Kleper, M. H.

1984-01-01T23:59:59.000Z

186

Breath is a mixture of nitrogen, oxygen, carbon dioxide, water  

E-Print Network [OSTI]

12 SCIENCE Breath is a mixture of nitrogen, oxygen, carbon dioxide, water vapour, inert gases. On the basis of proton affinity, the major constituents of air and breath (nitrogen, oxygen, carbon dioxide

187

Dopant Distribution, Oxygen Stoichiometry and Magnetism of Nanoscale...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dopant Distribution, Oxygen Stoichiometry and Magnetism of Nanoscale Sn0.99Co0.01O. Dopant Distribution, Oxygen Stoichiometry and Magnetism of Nanoscale Sn0.99Co0.01O. Abstract: In...

188

Optimization of Oxygen Purity for Coal Conversion Energy Reduction  

E-Print Network [OSTI]

The conversion of coal into gaseous and liquid fuels and chemical feedstock will require large quantities of oxygen. This oxygen will be produced in large multi-train air separation plants which will consume about 350 kilowatt hours of energy...

Baker, C. R.; Pike, R. A.

1982-01-01T23:59:59.000Z

189

Transient Mobility of Oxygen Adatoms upon O2 Dissociation on...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transient Mobility of Oxygen Adatoms upon O2 Dissociation on Reduced TiO2 (110). Transient Mobility of Oxygen Adatoms upon O2 Dissociation on Reduced TiO2 (110). Abstract: Tracking...

190

Methane Adsorption and Dissociation and Oxygen Adsorption and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methane Adsorption and Dissociation and Oxygen Adsorption and Reaction with CO on Pd Nanoparticles on MgO(100) and on Pd(111). Methane Adsorption and Dissociation and Oxygen...

191

Inhibitive Influence of Oxygen Vacancies for Photoactivity on...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Inhibitive Influence of Oxygen Vacancies for Photoactivity on TiO2(110). Inhibitive Influence of Oxygen Vacancies for Photoactivity on TiO2(110). Abstract: Scanning tunneling...

192

Oxygen-induced magnetic properties and metallic behavior of a...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen-induced magnetic properties and metallic behavior of a BN sheet. Oxygen-induced magnetic properties and metallic behavior of a BN sheet. Abstract: In this paper, ab initio...

193

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the second quarter July--September 2000 in the following task areas: Task 1-Oxygen Enhanced Combustion, Task 2-Oxygen Transport Membranes and Task 4-Program Management. The program is proceeding in accordance with the objectives for the first year. OTM tube characterization is well underway, the design and assembly of the high pressure permeation test facility is complete and the facility will be in full operation during the next quarter. Combustion testing has been initiated at both the University of Arizona and Praxair. Testing at the University of Arizona has experienced some delays; steps have been take to get the test work back on schedule. Completion of the first phase of the testing is expected in next quarter. Combustion modeling has been started at both REI and Praxair, preliminary results are expected in the next quarter.

Lawrence E. Bool; Jack C. Chen; David R. Thompson

2000-10-01T23:59:59.000Z

194

Photosynthesis and the dynamics of oxygen consumption in a ...  

Science Journals Connector (OSTI)

photosynthesis minus oxygen consumption), and gross photosynthesis at high ... The depth distribution of gross photosynthesis, as obtained by the cycling ...

1999-11-15T23:59:59.000Z

195

Oxygen-Enriched Combustion for Military Diesel Engine Generators  

Broader source: Energy.gov [DOE]

Substantial increases in brake power and considerably lower peak pressure can result from oxygen-enriched diesel combustion

196

OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL  

SciTech Connect (OSTI)

This quarterly technical progress report will summarize work accomplished for the Program through the ninth quarter April-June 2002 in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Full-scale testing using the Industrial Boiler Simulation Facility (ISBF) at Alstom Power was completed. The pilot scale experiments to evaluate the effect of air preheat and transport air stoichiometric ratio (SR) on NOx emissions were conducted at the University of Utah. Combustion modeling activities continued with full-scale combustion test furnace simulations. An OTM element was tested in Praxair's single tube high-pressure test facility and two thermal cycles were completed. PSO1d elements of new dimension were tested resulting in a lower flux than previous PSO1d elements of different dimensions, however, no element deformation was observed. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Two potential host beta sites have been identified and proposals submitted.

David R. Thompson; Lawrence E. Bool; Jack C. Chen

2002-08-01T23:59:59.000Z

197

DME-to-oxygenates process studies  

SciTech Connect (OSTI)

The feasibility of the production of hydrocarbons from dimethyl ether (DNM) has been illustrated in a fixed bed micro-reactor as well as a bench scale fluidized bed reactor by the University of Akron/EPRI DME-to-Hydrocarbon (DTG) Process. The DTG process has distinct advantages over its methanol based counterpart. Specifically, the DTG process excels in the area of higher productivity, higher per-pass conversion, and lower heat duties than the MTG process. Also of special importance is the production of oxygenates -- including MTBE, ETBE, and TAME. DME may be reacted with isobutylene to produce a mixture of MTBE and ETBE. The properties of ETBE excel over MTBE in the areas of lower RVP and higher RON. According to industrial reports, MTBE is the fastest growing chemical (1992 US capacity 135,350 BPD, with expected growth of 34%/year to 1997). Also, recent renewed interest as an octane-enhancer and as a source of oxygen has spurred a growing interest in nonrefinery synthesis routes to ETBE. TAME, with its lower RVP and higher RON has proven useful as a gasoline blending agent and octane enhancer and may also be produced directly from DME. DME, therefore, serves as a valuable feedstock in the conversion of may oxygenates with wide-scale industrial importance. It should be also noted that the interest in the utilization of DME as process feedstock is based on the favorable process economics of EPRI/UA`s liquid phase DME process.

Tartamella, T.L.; Sardesai, A.; Lee, S. [Univ. of Akron, OH (United States); Kulik, C.J. [Electric Power Research Inst., Palo Alto, CA (United States)

1994-12-31T23:59:59.000Z

198

Bridge-bonded atomic oxygen on Pt(110)  

Science Journals Connector (OSTI)

We use hybrid density-functional theory (DFT) and scanning tunneling microscopy (STM) to study oxygen adsorption on the Pt(110) surface. In the STM images oxygen appear as bright protrusions on the ridges of the “missing row” reconstructed surface. DFT calculations of binding energies for atomic oxygen on a bridge site shows a clear preference over hollow sites.

E. Janin; H. von Schenck; M. Göthelid; U. O. Karlsson; M. Svensson

2000-05-15T23:59:59.000Z

199

Oxygen Consumption Rates of Bacteria under Nutrient-Limited Conditions  

Science Journals Connector (OSTI)

...research-article Environmental Microbiology Oxygen Consumption Rates of Bacteria under Nutrient-Limited...heterotrophic bacteria was measured. The oxygen consumption and population density of batch cultures...tracked for up to 200 days. The oxygen consumption per CFU (QO2) declined by more than...

Timothy E. Riedel; William M. Berelson; Kenneth H. Nealson; Steven E. Finkel

2013-06-14T23:59:59.000Z

200

IMPROVEMENTS IN MODELLING DISSOLVED OXYGEN IN ACTIVATED SLUDGE SYSTEMS  

E-Print Network [OSTI]

1 IMPROVEMENTS IN MODELLING DISSOLVED OXYGEN IN ACTIVATED SLUDGE SYSTEMS Jacek Makinia*, Scott A in a full-scale activated sludge reactor. The Activated Sludge Model No. 1 was used to describe for dissolved oxygen. KEYWORDS Activated sludge; dispersion; dissolved oxygen dynamics; mass transfer

Wells, Scott A.

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Oceanic oxygen changes as a bellwether of climate change  

E-Print Network [OSTI]

Oceanic oxygen changes as a bellwether of climate change Term paper in Biogeochemistry@ethz.ch] Tutor: Prof. Dr. Nicholas Gruber [nicholas.gruber@env.ethz.ch] Abstract The response of oceanic oxygen of climate change. Recent publications indicate that the oceanic oxygen outgassing is substaintially larger

Fischlin, Andreas

202

Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence  

E-Print Network [OSTI]

Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence Ruby N. Ghosh,a) Gregory L on a reflection-mode fiber-optic oxygen sensor based on the 3 O2 quenching of the red emission from hexanuclear molybdenum chloride clusters. Measurements of the probe operating in a 0%­21% gaseous oxygen environment have

Ghosh, Ruby N.

203

THE OXYGEN REQUIREMENTS OF SHELLFISH By Philip H. Mitchell  

E-Print Network [OSTI]

THE OXYGEN REQUIREMENTS OF SHELLFISH ~ By Philip H. Mitchell 2°7 #12;Blank page retained for pagination #12;THE OXYGEN REQUIREMENTS OF SHELLFISH. By PHILIP H. MITCHELL. J1, The respiratory exchanges to temperature changes, a smaller utili- zation of oxygen in proportion to the body weight with increase in size

204

E-Print Network 3.0 - ameliorating reactive oxygen Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

structure and surface relaxation Summary: reactivity of each type of oxygen the adsorption of hydrogen over different oxygen sites is studied. Full... oxygen is the reactive...

205

E-Print Network 3.0 - acute oxygen sensing Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dissolved oxygen with global warming. In coastal regimes oxygen deficits represent acute ecosystem... Ocean oxygen minima expansions and their biological impacts Lothar Stramma...

206

Oxygen-driven relaxation processes in pre-irradiated Ar cryocrystals  

E-Print Network [OSTI]

Excitations of Solid Oxygen ?in Russian?, B. I. Verkin andNUMBER 11 NOVEMBER 2006 Oxygen-driven relaxation processes? Relaxation processes in oxygen-containing Ar cryocrystals

Savchenko, E. V; Belov, A. G; Gumenchuk, G. B; Ponomaryov, A. N; Bondybey, V. E

2006-01-01T23:59:59.000Z

207

OXYGEN REDUCTION WITH CARBON SUPPORTED METALLIC CLUSTER CATALYSTS IN ALKALINE ELECTROLYTE  

E-Print Network [OSTI]

be published in the Proceedings OXYGEN REDUCTION WITH CARBONof California. LBL-11891 Oxygen Reduction with Carbonof Pt interacts with both oxygen and water more strongly

Ross Jr., Philip N.

2013-01-01T23:59:59.000Z

208

Oxygen isotope fractionation in the vacuum ultraviolet photodissociation of carbon monoxide: Wavelength, pressure and temperature dependency.  

E-Print Network [OSTI]

Oxygen isotope fractionation in the vacuum ultravioletmeasurement of the associated oxygen isotopic composition ofwavelength dependency of the oxygen isotopic composition in

Chakraborty, Subrata

2013-01-01T23:59:59.000Z

209

Field test of two high-pressure direct-contact downhole steam generators. Volume II. Oxygen/diesel system  

SciTech Connect (OSTI)

A field test of an oxygen/diesel fuel, direct contact steam generator has been completed. The field test, which was a part of Project DEEP STEAM and was sponsored by the US Department of Energy, involved the thermal stimulation of a well pattern in the Tar Zone of the Wilmington Oil Field. The activity was carried out in cooperation with the City of Long Beach and the Long Beach Oil Development Company. The steam generator was operated at ground level, with the steam and combustion products delivered to the reservoir through 2022 feet of calcium-silicate insulated tubing. The objectives of the test included demonstrations of safety, operational ease, reliability and lifetime; investigations of reservoir response, environmental impact, and economics; and comparison of those points with a second generator that used air rather than oxygen. The test was extensively instrumented to provide the required data. Excluding interruptions not attributable to the oxygen/diesel system, steam was injected 78% of the time. System lifetime was limited by the combustor, which required some parts replacement every 2 to 3 weeks. For the conditions of this particular test, the use of trucked-in LOX resulted in liess expense than did the production of the equivalent amount of high pressure air using on site compressors. No statistically significant production change in the eight-acre oxygen system well pattern occurred during the test, nor were any adverse effects on the reservoir character detected. Gas analyses during the field test showed very low levels of SOX (less than or equal to 1 ppM) in the generator gaseous effluent. The SOX and NOX data did not permit any conclusion to be drawn regarding reservoir scrubbing. Appreciable levels of CO (less than or equal to 5%) were measured at the generator, and in this case produced-gas analyses showed evidence of significant gas scrubbing. 64 figures, 10 tables.

Moreno, J.B.

1983-07-01T23:59:59.000Z

210

Dilute Oxygen Combustion Phase IV Final Report  

SciTech Connect (OSTI)

Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the cost of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space limitations are critical. DOC technology will continue to have a highly competitive role in retrofit applications requiring increases in furnace productivity.

Riley, M.F.

2003-04-30T23:59:59.000Z

211

NETL: Gasification - Development of Ion-Transport Membrane Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Presentations, Papers, and Publications Presentations, Papers, and Publications ITM Oxygen Development for Advanced Oxygen Supply (Oct 2011) Ted Foster, Air Products & Chemicals, Inc. presented at the Gasification Technologies Conference, San Francisco, CA Oct 9-12, 2011. ASU/IGCC Integration Strategies (Oct 2009), David McCarthy, Air Products & Chemicals, Inc., 2009 Gasification Technologies Conference, Colorado Springs, CO. ITM Oxygen: Taking the Next Step (Oct 2009), VanEric Stein, Air Products & Chemicals, Inc., 2009 Gasification Technologies Conference, Colorado Springs, CO. ITM Oxygen: Scaling Up a Low-Cost Oxygen Supply Technology (Oct 2006) Philip Armstrong, Air Products & Chemicals, Inc., 2006 Gasification Technologies Conference, Washington, D.C. ITM Oxygen: The New Oxygen Supply for the New IGCC Market (Oct 2005)

212

Dissolved Oxygen in Allen CreekDissolved Oxygen in Allen Creek Dissolved oxygen (DO) enters the water by diffusion from air, as a by-product of photosynthesis and  

E-Print Network [OSTI]

Dissolved Oxygen in Allen CreekDissolved Oxygen in Allen Creek Dissolved oxygen (DO) enters and rapids. There is an inverse relationship between temperature and DO, i.e. colder water holds more oxygen it supplies oxygen to aquatic organisms. Higher DO levels also give the water a better taste. Figure 2. During

Tyler, Christy

213

The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries  

SciTech Connect (OSTI)

The oxygen reduction/evolution reaction (ORR/OER) mechanisms in nonaqueous Li-O2 batteries have been investigated by using electron paramagnetic resonance spectroscopy in this work. We identified the superoxide radical anion (O2•-) as an intermediate in the ORR process using 5,5-dimethyl-pyrroline N-oxide as a spin trap, while no O2•- in OER was detected during the charge process. These findings provide insightful understanding on the fundamental oxygen reaction mechanisms in rechargeable nonaqueous Li-O2 batteries.

Cao, Ruiguo; Walter, Eric D.; Xu, Wu; Nasybulin, Eduard N.; Bhattacharya, Priyanka; Bowden, Mark E.; Engelhard, Mark H.; Zhang, Jiguang

2014-09-30T23:59:59.000Z

214

SUPPORTED DENSE CERAMIC MEMBRANES FOR OXYGEN SEPARATION  

SciTech Connect (OSTI)

Mixed-conducting membranes have the ability to conduct oxygen with perfect selectivity at elevated temperatures, which makes them an extremely attractive alternative for oxygen separation and membrane reactor applications. The ability to reliably fabricate these membranes in thin or thick films would enable solid-state divisional limitations to be minimized, thus providing higher oxygen flux. Based on that motivation, the overall objective for this project is to develop and demonstrate a strategy for the fabrication of supported Wick film ceramic mixed conducting membranes, and improve the understanding of the fundamental issues associated with reliable fabrication of these membranes. The project has focused on the mixed-conducting ceramic composition SrCo{sub 0.5}FeO{sub x} because of its superior permeability and stability in reducing atmospheres. The fabrication strategy employed involves the deposition of SrCo{sub 0.5}FeO{sub x} thick films onto porous supports of the same composition. In the second year of this project, we completed characterization of the sintering and phase behavior of the porous SrCo{sub 0.5}FeO{sub x} supports, leading to a standard support fabrication methodology. Using a doctor blade method, pastes made from aerosol-derived SrCo{sub 0.5}FeO{sub x} powder dispersed with polyethylene glycol were applied to the supports, and the sintering behavior of the thick film membranes was examined in air and nitrogen atmospheres. It has been demonstrated that the desired crystalline phase content can be produced in the membranes, and that the material in the membrane layer can be highly densified without densifying the underlying support. However, considerable cracking and opening of the film occurred when films densified to a high extent. The addition of MgO into the SrCo{sub 0.5}FeO{sub x} supports was shown to inhibit support sintering so that temperatures up to 1300 C, where significant liquid formation occurs, could be used for film sintering. This successfully reduced cracking, however the films retained open porosity. The investigation of this concept will be continued in the final year of the project. Investigation of a metal organic chemical vapor deposition (MOCVD) method for defect mending in dense membranes was also initiated. An appropriate metal organic precursor (iron tetramethylheptanedionate) was identified whose deposition can be controlled by access to oxygen at temperatures in the 280-300 C range. Initial experiments have deposited iron oxide, but only on the membrane surface; thus refinement of this method will continue.

Timothy L. Ward

2000-06-30T23:59:59.000Z

215

Foam insulation for a liquid oxygen densifier  

Science Journals Connector (OSTI)

Analyses indicated that it would not be cost effective to vacuum insulate a 7 foot diameter by 30 foot long liquid nitrogen vessel for a launch facility liquid oxygen densifier. Foam insulation appeared to be the logical choice for this infrequently used ground support equipment but the history of foam problems due to cracking, adhesive failure and internal shearing weighed against the use of commercial spray-on material. These problems were solved with a system consisting of alternate sealing and flexible foam layers: (1) an inner membrane sealed to itself but not attached to the cold shell or pipe; (2) a flexible foam insulation layer; (3) a vapor-tight sealing membrane; (4) a second flexible foam insulation layer and (5) an outer aluminized sealing membrane. The second and subsequent layers are sealed to each underlying layer by flexible foam contact adhesive. The inner sealing membrane is particularly vital in that it allows the first foam layer to expand and contract as the tank temperature changes and it also protects the tank from chloride corrosion from the foam. This paper describes preliminary testing to prove out the system and the steps taken to install flexible foam insulation on the oxygen densifier vessel.

G.E. McIntosh; R. Stuckenschmidt

2012-01-01T23:59:59.000Z

216

Oxidation Kinetics of Cu2O in Oxygen Carriers for Chemical Looping with Oxygen Uncoupling  

Science Journals Connector (OSTI)

(7) Application to CLC was first demonstrated by Mattisson et al.,(8) who showed that the release of oxygen allows conversion of petcoke by CLOU to be as much as 50 times faster than conversion by conventional CLC with an iron-based carrier, which requires in situ conversion of petcoke to syngas by relatively slow gasification reactions. ...

Christopher K. Clayton; H. Y. Sohn; Kevin J. Whitty

2014-01-28T23:59:59.000Z

217

Comparison of the Impact of Intake Oxygen Enrichment and Fuel Oxygenation on Diesel Combustion and Emissions  

Science Journals Connector (OSTI)

turbocharged, Intercooler?(air-air), electronically?controlled?EGR with?actuator ... Fumigation into the intake surge tank was chosen to allow thorough mixing of the oxygen?air mixture through the subsequent components of the intake system, such as the air filter, turbocharger, and intercooler, before entering the intake manifold. ...

Juhun Song; Vince Zello; André L. Boehman; Francis J. Waller

2004-07-10T23:59:59.000Z

218

Dilute Oxygen Combustion Phase I Final Report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300°F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

Ryan, H.M.; Riley, M.F.; Kobayashi, H.

1997-10-31T23:59:59.000Z

219

Dilute Oxygen Combustion Phase 2 Final Report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300?F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

Ryan, H.M.; Riley, M.F.; Kobayashi, H.

2005-09-30T23:59:59.000Z

220

Dilute oxygen combustion. Phase I report  

SciTech Connect (OSTI)

A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NO{sub x}) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NO{sub x} through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NO{sub x} production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature ({approximately}1366 K) oxidant (7-27% O{sub 2} vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d{sup +} scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d{sup +} scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW ({approximately}0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NO{sub x} emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NO{sub x} emissions below 5{times}10{sup -3} g/MJ (10 ppm-air equivalent at 3% O{sub 2} dry) were obtained for furnace temperatures below 1533 K (2300{degree}F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in- furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, with increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, requires additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

NONE

1997-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Electrochemical oxygen pumps. Final CRADA report.  

SciTech Connect (OSTI)

All tasks of the Work Plan of ISTC Project 2277p have been completed, thus: (1) techniques of chemical synthesis were developed for more than ten recipes of electrolyte based on cerium oxide doped with 20 mole% of gadolinium (CeGd)O{sub 2}, doped by more than 10 oxide systems including 6 recipes in addition to the Work Plan; (2) electric conductivity and mechanical strength of CeGd specimens with additions of oxide systems were performed, two candidate materials for the electrolyte of electrochemical oxygen pump (pure CeGd and CeGd doped by 0.2 wt% of a transition metal) were chosen; (3) extended studies of mechanical strength of candidate material specimens were performed at room temperature and at 400, 600, 800 C; (4) fixtures for determination of mechanical strength of tubes by external pressure above 40 atmospheres at temperature up to 700 C were developed and fabricated; and (5) technology of slip casting of tubes from pure (Ce,Gd)O{sub 2} and of (Ce,Gd)O{sub 2} doped by 0.2 wt% of a transition metal, withstanding external pressure of minimum 40 atmospheres at temperature up to 700 C was developed, a batch of tubes was sent for testing to Argonne National Laboratory; (6) technology of making nanopowder from pure (Ce,Gd)O{sub 2} was developed based on chemical synthesis and laser ablation techniques, a batch of nanopowder with the weight 1 kg was sent for testing to Argonne National Laboratory; (7) a business plan for establishing a company for making powders of materials for electrochemical oxygen pump was developed; and (8) major results obtained within the Project were reported at international conferences and published in the Russian journal Electrochemistry. In accordance with the Work Plan a business trip of the following project participants was scheduled for April 22-29, 2006, to Tonawanda, NY, USA: Manager Victor Borisov; Leader of technology development Gennady Studenikin; Leader of business planning Elena Zadorozhnaya; Leader of production Vasily Lepalovsky; and Translator Vladimir Litvinov. During this trip project participants were to discuss with the project Technical Monitor J.D. Carter and representative of Praxair Inc. J. Chen the results of project activities (prospects of transition metal-doped material application in oxygen pumps), as well as the prospects of cooperation with Praxair at the meeting with the company management in the following fields: (1) Deposition of thin films of oxide materials of complex composition on support by magnetron and ion sputtering, research of coatings properties; (2) Development of block-type structure technology (made of porous and dense ceramics) for oxygen pump. The block-type structure is promising because when the size of electrolyte block is 2 x 2 inches and assembly height is 10 inches (5 blocks connected together) the area of active surface is ca. 290 square inches (in case of 8 slots), that roughly corresponds to one tube with diameter 1 inch and height 100 inches. So performance of the system made of such blocks may be by a factor of two or three higher than that of tube-based system. However one month before the visit, J. Chen notified us of internal changes at Praxair and the cancellation of the visit to Tonawanda, NY. During consultations with the project Technical Monitor J.D. Carter and Senior Project Manager A. Taylor a decision was made to extend the project term by 2 quarters to prepare proposals for follow-on activities during this extension (development of block-type structures made of dense and porous oxide ceramics for electrochemical oxygen pumps) using the funds that were not used for the trip to the US.

Carter, J. D.

2009-10-01T23:59:59.000Z

222

the International Civil Aviation Organization (ICAO) adopted a resolution that not only accepted a long-term strat-egy for reducing emissions but also excluded language intended to prevent unilateral application of EU legislation  

E-Print Network [OSTI]

of atmospheric pollution, airliners cross many borders and fly through many regula- tory jurisdictions a long-term strat- egy for reducing emissions but also excluded language intended to prevent unilateral-standing disagreement between in- dustrialized and developing countries about preventing climate change. Secondly

Sibille, Etienne

223

Oxygen Atoms Display Novel Behavior on Common Catalyst  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

11, 2008 11, 2008 Oxygen Atoms Display Novel Behavior on Common Catalyst Like waltzing dancers, the two atoms of an oxygen molecule usually behave identically when they separate on the surface of a catalyst. However, new research from the Environmental Molecular Sciences Laboratory reveals that on a particular catalyst, the oxygen atoms act like a couple dancing the tango: one oxygen atom plants itself while the other shimmies away, probably with energy partially stolen from the stationary one. Scientists from EMSL and Pacific Northwest National Laboratory discovered this unanticipated behavior while studying how oxygen interacts with reduced titanium oxide, a popular catalyst and a model oxide. Their research began with a slice of titanium oxide crystal, oriented so that titanium and oxygen

224

Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mixed Copper-Iron-Inert Support Oxygen Carriers Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Contact NETL Technology Transfer Group techtransfer@netl.doe.gov December 2012 This patent-pending technology, "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process," provides a metal-oxide oxygen carrier for application in fuel combustion processes that use oxygen. This technology is available for licensing and/or further collaborative research with the U.S. Department of Energy's National Energy Technology Laboratory. Overview Patent Details U.S. Non-Provisional Patent Application No. 13/159,553; titled "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid

225

New Oxygen-Production Technology Proving Successful | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Oxygen-Production Technology Proving Successful Oxygen-Production Technology Proving Successful New Oxygen-Production Technology Proving Successful April 22, 2009 - 1:00pm Addthis Washington, DC -- The Office of Fossil Energy's National Energy Technology Laboratory (NETL) has partnered with Air Products and Chemicals Inc. of Allentown, Penn. to develop the Ion Transport Membrane (ITM) Oxygen, a revolutionary new oxygen-production technology that requires less energy and offers lower capital costs than conventional technologies. ITM Oxygen will enhance the performance of integrated gasification combined cycle (IGCC) power plants, as well as other gasification-based processes. The technology will also enhance the economics of oxy-fired combustion technologies, making it an attractive option for the capture of carbon

226

NETL: Gasification - Development of Ion-Transport Membrane Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Feed Systems Feed Systems Recovery Act: Development of Ion-Transport Membrane Oxygen Technology for Integration in IGCC and Other Advanced Power Generation Systems Air Products and Chemicals, Inc. Project Number: FC26-98FT40343 Project Description Air Products and Chemicals, Inc. is developing, scaling-up, and demonstrating a novel air separation technology for large-scale production of oxygen (O2) at costs that are approximately one-third lower than conventional cryogenic plants. An Ion Transport Membrane (ITM) Oxygen plant co-produces power and oxygen. A phased technology RD&D effort is underway to demonstrate all necessary technical and economic requirements for scale-up and industrial commercialization. The ITM Oxygen production technology is a radically different approach to producing high-quality tonnage oxygen and to enhance the performance of integrated gasification combined cycle and other advanced power generation systems. Instead of cooling air to cryogenic temperatures, oxygen is extracted from air at temperatures synergistic with power production operations. Process engineering and economic evaluations of integrated gasification combined cycle (IGCC) power plants comparing ITM Oxygen with a state-of-the-art cryogenic air separation unit are aimed to show that the installed capital cost of the air separation unit and the installed capital of IGCC facility are significantly lower compared to conventional technologies, while improving power plant output and efficiency. The use of low-cost oxygen in combustion processes would provide cost-effective emission reduction and carbon management opportunities. ITM Oxygen is an enabling module for future plants for producing coal derived shifted synthesis gas (a mixture of hydrogen [H2] and carbon dioxide [CO2]) ultimately for producing clean energy and fuels. Oxygen-intensive industries such as steel, glass, non-ferrous metallurgy, refineries, and pulp and paper may also realize cost and productivity benefits as a result of employing ITM Oxygen.

227

Electrons, life and the evolution of Earth's oxygen cycle  

Science Journals Connector (OSTI)

...efficiency of organic matter and...increased production of oxygen...eukaryotic host cells, allowing...outside of our Solar System...efficiency of organic matter and...increased production of oxygen...eukaryotic host cells, allowing...outside of our Solar System...efficiency of organic matter and...increased production of oxygen...eukaryotic host cells, allowing...outside of our Solar System...

2008-01-01T23:59:59.000Z

228

Molecular oxygen sensors based on photoluminescent silica aerogels  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Molecular oxygen sensors based on photoluminescent silica aerogels Molecular oxygen sensors based on photoluminescent silica aerogels Title Molecular oxygen sensors based on photoluminescent silica aerogels Publication Type Journal Article Year of Publication 1998 Authors Ayers, Michael R., and Arlon J. Hunt Journal Journal of Non-Crystalline Solids Volume 225 Pagination 343-347 Keywords aerogel, air pressure, oxygen concentration, oxygen molecules, photoluminescence Abstract Photoluminescent silica aerogel acts as the active element of an optical sensor for molecular oxygen. The luminescent aerogel is prepared by the action of energized reducing gases on a standard silica aerogel. Intensity of aerogel photoluminescence decreases as the collision frequency between oxygen molecules and the luminescent carriers in the aerogel matrix increases. This behavior is a characteristic of many photoluminescent materials and arises from a transfer of energy from the aerogel to surrounding oxygen molecules. A sensor for oxygen concentration or air pressure can therefore be simply constructed utilizing an ultraviolet source for excitation and a suitable detector for the emitted visible signal. Stern-Volmer quenching constants for the aerogel sensing element are 1.55×10-2 Torr-1 for hydrophilic aerogel and 2.4×10-3 Torr-1 for hydrophobic aerogel.

229

Effect of feedwater oxygen control at the Vermont Yankee BWR  

SciTech Connect (OSTI)

Results of a test program to evaluate the impact of oxygen injection on the release and transport of iron, nickel, cobalt, copper and zinc in the feedwater system at the Vermont Yankee boiling water reactor (BWR) are presented. Design and operation of the oxygen injection system are discussed. Conclusions and recommendations relative to generic application of oxygen injection for corrosion product control in BWRs during normal operation are presented. Application of oxygen injection to assist in feedwater system materials passivation after an extended outage also is discussed. 12 refs., 16 figs., 5 tabs.

Hobart, R.L.; Palino, G.F.

1985-07-01T23:59:59.000Z

230

OXYGEN CONSUMPTION BY THE SEABED IV. SHIPBOARD AND ...  

Science Journals Connector (OSTI)

respiratory consumption; in these experiments the rate of chemical oxidation decreases with decreasing oxygen tension, whiIe the rate of respiration is relatively.

Orcas

2000-02-13T23:59:59.000Z

231

Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

We discovered that the electronic structure and valence state of transition metal ions show significant variations, which have been identified to be attributed to the oxygen...

232

Geothermal reservoir temperatures estimated from the oxygen isotope...  

Open Energy Info (EERE)

temperatures estimated from the oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes Jump to: navigation, search GEOTHERMAL...

233

Microbial metatranscriptomics in a permanent marine oxygen minimum zone  

E-Print Network [OSTI]

Simultaneous characterization of taxonomic composition, metabolic gene content and gene expression in marine oxygen minimum zones (OMZs) has potential to broaden perspectives on the microbial and biogeochemical dynamics ...

Stewart, Frank J.

234

Oxygen-Enriched Combustion for Military Diesel Engine Generators...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion for Military Diesel Engine Generators Oxygen-Enriched Combustion for Military Diesel Engine Generators Substantial increases in brake power and considerably lower peak...

235

Oxygen Coverage Dependence of NO Oxidation on Pt(111). | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Dependence of NO Oxidation on Pt(111). Abstract: The interaction of NO with adsorbed atomic oxygen on Pt(111) was studied with temperature programmed desorption (TPD),...

236

Optical dissolved oxygen sensor utilizing molybdenum chloride cluster phosphorescence  

E-Print Network [OSTI]

in oxygen atmospheres 0%­21% were obtained with a signal to noise ratio better than 150. Photobleaching physical principles, electrochemistry or luminescence. Electrochemical devices result in analyte

Ghosh, Ruby N.

237

Oxygen-nutrient relationships in the Pacific Ocean  

Science Journals Connector (OSTI)

Aug 18, 1972 ... In the northeastern Pacific Ocean the oxygen-phosphate ... different stations in the Pacific and Indian Oceans to study their water masses.

2000-01-04T23:59:59.000Z

238

Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...  

Broader source: Energy.gov (indexed) [DOE]

2009 - Poster Session August 3 rd , Hyatt Regency Dearborn Hotel Virtual Oxygen Sensor Innovative NOx and PM Emission Control Technologies J. Seebode, E. Stlting,...

239

Modeling Oxygen Transport in Three-Dimensional Capillary Networks.  

E-Print Network [OSTI]

??The purpose of this thesis was to examine how the use of real 3-dimensional (3D) capillary network geometries affect models of oxygen transport to tissue.… (more)

Fraser, Graham M

2012-01-01T23:59:59.000Z

240

Electron-Stimulated Production of Molecular Oxygen in Amorphous...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Precursor Transport Through the Hydrogen Electron-Stimulated Production of Molecular Oxygen in Amorphous Solid Water on Pt(111): Precursor Transport Through the Hydrogen...

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...  

Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

- - - - - - - - - - - - See footnotes at end of table. 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 116 Energy Information...

242

Hydrogen (H2) Production by Oxygenic Phototrophs  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Production by Oxygenic Phototrophs Eric L. Hegg Michigan State University Great Lakes Bioenergy Research Center Bioresour. Technol. 2011, 102, 8589-8604 Major Challenges to H 2 Photoproduction Biological Challenges * Poor efficiency of H 2 production * Poor heterologous expression of H 2 -forming enzymes * Low quantum yields * Competition for reducing equivalents; poor electron coupling * Sensitivity of H 2 -forming enzymes to O 2 M. Ghirardi, Abstract #1751, Honolulu PRiME 2012 Technical Challenges * Mixture of H 2 and O 2 ; H 2 separation and storage * CO 2 addition and overall reactor design Overcoming Low Efficiency: Improving ET * Eliminate or down-regulate pathways competing for ele * Production of organic acids * Formation of NADPH/carbon fixation

243

It's Elemental - Isotopes of the Element Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nitrogen Nitrogen Previous Element (Nitrogen) The Periodic Table of Elements Next Element (Fluorine) Fluorine Isotopes of the Element Oxygen [Click for Main Data] Most of the isotope data on this site has been obtained from the National Nuclear Data Center. Please visit their site for more information. Naturally Occurring Isotopes Mass Number Natural Abundance Half-life 16 99.757% STABLE 17 0.038% STABLE 18 0.205% STABLE Known Isotopes Mass Number Half-life Decay Mode Branching Percentage 12 1.139×10-21 seconds Proton Emission No Data Available 13 8.58 milliseconds Electron Capture 100.00% Electron Capture with delayed Proton Emission 100.00% 14 70.620 seconds Electron Capture 100.00% 15 122.24 seconds Electron Capture 100.00% 16 STABLE - - 17 STABLE - - 18 STABLE - - 19 26.88 seconds Beta-minus Decay 100.00%

244

Dilute Oxygen Combustion - Phase 3 Report  

SciTech Connect (OSTI)

Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good, and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel's standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion on furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

Riley, Michael F.

2000-05-31T23:59:59.000Z

245

Dilute Oxygen Combustion Phase 3 Final Report  

SciTech Connect (OSTI)

Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel?s standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion of furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

Riley, M.F.; Ryan, H.M.

2000-05-31T23:59:59.000Z

246

Use of Oxygen Isotopic Exchange to Explore Catalytic Activity and the Mechanism of Oxygen Reduction on Oxides.  

E-Print Network [OSTI]

??The electrochemical performance of intermediate temperature solid oxide fuel cells is limited by high polarization losses incurred from the oxygen reduction reaction at the cathode.… (more)

Kan, Cynthia

2009-01-01T23:59:59.000Z

247

The generation of singlet Delta oxygen - A technology overview. [For use in chemical oxygen iodine lasers  

SciTech Connect (OSTI)

The rate of generation of O2(1Delta g) using the chlorine-basic-hydrogen-peroxide reaction is a key element to predict the performance of the chemical oxygen iodine laser. O2(1Delta g) carries the energy in the laser, and thus is one of the prime determinants of power in the flow. To predict the performance of O2(1Delta g) generators requires the prediction of the utilization of chlorine, the yield of excited oxygen, and the concentration of potential contaminants in the chemical exhaust of the generator. This paper describes an approach to the analysis of O2(1Delta g) generators. 6 refs.

Mcdermott, W.E. (Rockwell International Corp., Rocketdyne Div., Canoga Park, CA (United States))

1992-07-01T23:59:59.000Z

248

Research on Temperature Field Measuring of Oxygen Propane  

Science Journals Connector (OSTI)

By substituting alumina particles for soot created in burning flame and using the three-color method, the temperature field of the oxygen propane is calculated based on the image taken by CCD and digital image processing technology. The results show ... Keywords: CCD, oxygen propane flame, temperature field, image processing

Zhang Rui-ping

2010-09-01T23:59:59.000Z

249

Unexpected Nondissociative Binding of N2O on Oxygen Vacancies...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Nondissociative Binding of N2O on Oxygen Vacancies on a Rutile TiO2(110)-1×1 . Unexpected Nondissociative Binding of N2O on Oxygen Vacancies on a Rutile TiO2(110)-1×1 ....

250

INVESTIGATION OF OXYGEN REDUCTION MECHANISMS USING CATHODE MICROELECTRODES, PART II  

E-Print Network [OSTI]

of elementary oxygen reduc- tion reaction steps. This discrepancy indicates to a lack of fundamental understanding of oxygen reduction process(es) at the LSM/YSZ interface at the molecular level. #12;Electrical resistances and capacitances in the SOFC behavior. All implications presented in Refs. 2-7 have been based

Yildiz, Bilge

251

Dissecting Oxygenic Photosynthesis: The Evolution of the "Z"-Scheme  

E-Print Network [OSTI]

11CHAPTER Dissecting Oxygenic Photosynthesis: The Evolution of the "Z"-Scheme for Thylakoid and two photosystems are involved in oxygenic photosynthesis. This is then followed by the discovery Drop in Photosynthesis; Two Light Reactions; Two Photosystems; Z-Scheme of Photosynthesis #12

Govindjee

252

Anoxygenic photosynthesis modulated Proterozoic oxygen and sustained Earth's middle age  

E-Print Network [OSTI]

Anoxygenic photosynthesis modulated Proterozoic oxygen and sustained Earth's middle age D. T photosynthesis to overall primary production would have influ- enced oceanic redox and the Proterozoic O2 budget time in Earth's history, complete dominance of oxygenic photosynthesis in the oceans. This paved

Macalady, Jenn

253

NETL: News Release - New Oxygen-Production Technology Proving Successful  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

22, 2009 22, 2009 New Oxygen-Production Technology Proving Successful Ceramic Membrane Enables Efficient, Cost-Effective Co-Production of Power and Oxygen Washington, D.C. -The Office of Fossil Energy's National Energy Technology Laboratory (NETL) has partnered with Air Products and Chemicals Inc. of Allentown, Penn. to develop the Ion Transport Membrane (ITM) Oxygen, a revolutionary new oxygen-production technology that requires less energy and offers lower capital costs than conventional technologies. ITM Oxygen will enhance the performance of integrated gasification combined cycle (IGCC) power plants, as well as other gasification-based processes. The technology will also enhance the economics of oxy-fired combustion technologies, making it an attractive option for the capture of carbon dioxide from existing coal-fired power plants.

254

Direct tuyere injection of oxygen for enhanced coal combustion  

SciTech Connect (OSTI)

Injecting oxygen directly into the tuyere blowpipe can enhance the ignition and combustion of injected pulverized coal, allowing the efficient use of higher coal rates at high furnace production levels. The effects of direct oxygen injection have been estimated from an analysis of the factors controlling the dispersion, heating, ignition, and combustion of injected coal. Injecting ambient temperature oxygen offers mechanical improvements in the dispersion of coal but provides little thermochemical benefit over increased blast enrichment. Injecting hot oxygen through a novel, patented thermal nozzle lance offers both mechanical and thermochemical benefits over increased enrichment or ambient oxygen injection. Plans for pilot-scale and commercial-scale testing of this new lance are described.

Riley, M.F. [Praxair, Inc., Tarrytown, NY (United States)

1996-12-31T23:59:59.000Z

255

Guidelines Establishing Criteria for Excluding Buildings from the Energy Performance Requirements of Section 543 of the National Energy Conservation Policy Act as Amended by the Energy Policy Act of 2005  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Guidelines Establishing Criteria for Excluding Buildings Guidelines Establishing Criteria for Excluding Buildings from the Energy Performance Requirements of Section 543 of the National Energy Conservation Policy Act as Amended by the Energy Policy Act of 2005 January 27, 2006 These guidelines and accompanying criteria fulfill the requirement under Section 543(c)(3) of the National Energy Conservation Policy Act (NECPA) as amended by the Energy Policy Act of 2005 (EPACT). Section 543(c)(3) states that the Secretary of Energy shall issue guidelines that establish criteria for exclusions from the energy performance requirement for a fiscal year, any Federal building or collection of Federal buildings, within the statutory framework provided by the law. The purpose of these guidelines is to clarify and explicate, as necessary, the statutory

256

Guidelines Establishing Criteria for Excluding Buildings from the Energy Performance Requirements of Section 543 of the National Energy Conservation Policy Act as Amended by the Energy Policy Act of 2005  

Broader source: Energy.gov (indexed) [DOE]

Guidelines Establishing Criteria for Excluding Buildings Guidelines Establishing Criteria for Excluding Buildings from the Energy Performance Requirements of Section 543 of the National Energy Conservation Policy Act as Amended by the Energy Policy Act of 2005 January 27, 2006 These guidelines and accompanying criteria fulfill the requirement under Section 543(c)(3) of the National Energy Conservation Policy Act (NECPA) as amended by the Energy Policy Act of 2005 (EPACT). Section 543(c)(3) states that the Secretary of Energy shall issue guidelines that establish criteria for exclusions from the energy performance requirement for a fiscal year, any Federal building or collection of Federal buildings, within the statutory framework provided by the law. The purpose of these guidelines is to clarify and explicate, as necessary, the statutory

257

Oxygen supply for oxyfuel CO2 capture  

Science Journals Connector (OSTI)

This paper presents the results of a study to develop Air Products’ air separation unit (ASU) offerings for oxyfuel coal CO2 capture projects. A scalable “reference plant” concept is described to match particular sizes of power generation equipment, taking into account factors such as safety, reliability, operating flexibility, efficiency, and low capital cost. We describe the selection of a process cycle to exploit the low purity requirements, as well as the options for compression machinery and drivers as the scale of the plant increases and the sizes of referenced equipment limit the possibilities. We also explore integration with other elements of the system, such as preheating condensate or heating and expanding pressurised nitrogen. In addition, we consider how the ASU affects the flexibility of the oxyfuel system and discuss how its power consumption can be reduced during periods of high power demand. Finally, the advantages and disadvantages of different execution strategies for air separation unit projects are discussed, as well as alternative commercial models for the supply of oxygen.

Paul Higginbotham; Vince White; Kevin Fogash; Galip Guvelioglu

2011-01-01T23:59:59.000Z

258

Relaxation behavior of oxygen deficient strontium manganite  

SciTech Connect (OSTI)

Conduction behavior of nanocrystalline oxygen deficient ceramic-SrMnO{sub 3–?}(??0.14) has been studied. The structural analysis of nano-SrMnO{sub 2.86} follows hexagonal unit cell structure with P6{sub 3}/mmc (194) space group belonging to 6/mmm point group with 4H – layered type hexagonal-cubic layers. The system have lattice parameters; a = 5.437(92) Å, c = 9.072(92) Å, c/a?1.66 (85) with ? =90° ?= 120° and cell volume, V= 232.35(18). The relaxation times estimated from complex impedance and modulus relaxation spectrum, show the thermally activated system with corresponding activation energies as 0.66 eV and 0.51 eV The stretching factor ‘?’ from the scaled modulus spectrum shows the poly-dispersive non-Debye nature of the system. The hopping number ‘n’ shows the influence of ionic charge carriers which controls the conduction mechanism of nano-SrMnO{sub 2.86}.

Pandey, Namita, E-mail: namita205@gmail.com; Thakur, Awalendra Kumar, E-mail: namita205@gmail.com [Department of Physics, Indian Institute of Technology-Patna, Patna- 800013 (India)

2014-04-24T23:59:59.000Z

259

Faraday Discuss., 1997, 108, 115130 Excited state dynamics in clusters of oxygen  

E-Print Network [OSTI]

Faraday Discuss., 1997, 108, 115�130 Excited state dynamics in clusters of oxygen Runjun Li, Karl A clusters of oxygen. Oxygen clusters and liquid oxygen have a com- plicated chemistry due to numerous low) dynamics of small anionic clusters of oxygen. We Ðnd that the dynamics of the neutral DPD pathway

Continetti, Robert E.

260

Oxygen diffusion, surface exchange and oxygen semi-permeation performances of Ln2NiO4+ membranes (Ln = La, Pr and Nd)  

E-Print Network [OSTI]

Oxygen diffusion, surface exchange and oxygen semi-permeation performances of Ln2NiO4+ membranes the rate determining step (rds) in oxygen semi-permeation of dense Ln2NiO4+ membranes (with Ln = La, Pr and Nd), a specific setup has been designed, which allowed measuring the oxygen semi-permeation flux

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Oxygen Modulation via Microfluidic Devices Oxygen is a key but under-studied metabolic variable. It influences biological phenomena as diverse as  

E-Print Network [OSTI]

Oxygen Modulation via Microfluidic Devices Oxygen is a key but under-studied metabolic variable methods to modulate oxygen are crude and inefficient. Our lab has developed a suite of devices which can rapidly alter oxygen conditions surrounding cells in both position and time.[1-3]. Moreover, because

Ben-Arie, Jezekiel

262

Increased intrapulmonary retention of radiolabeled neutrophils in early oxygen toxicity  

SciTech Connect (OSTI)

Sequential lung injuries, such as oxygen toxicity followed by septicemia, are common during the adult respiratory distress syndrome (ARDS). As these forms of vascular injury may be mediated in part by polymorphonuclear leukocytes (PMN), aberrant interactions between PMN and previously injured pulmonary endothelium are of both theoretical interest and clinical importance. The present study was undertaken to test the hypothesis that early oxygen toxicity at a dose that injuries pulmonary endothelium relatively selectively alters intrapulmonary neutrophil kinetics. Unanesthetized rats breathing 1.0 atmospheres oxygen for 36 h showed ultrastructural endothelial damage but no edema, injury, or neutrophilic inflammation by histologic criteria. However, in these oxygen-toxic animals, whereas initial accumulation of radiolabeled PMN in lungs was normal, washout of PMN was abnormal at 120 min after infusion, at which point the pulmonary retention of radiolabeled PMN in the lungs of oxygen-treated animals was significantly higher than in control animals (139% of control, p less than 0.0096). Features of our methodology, including avoidance of osmotic stress and use of paired control animals, appear to have greatly enhanced the sensitivity of radiolabeled neutrophils for detecting a subtle abnormality of neutrophil-endothelial interactions. Our studies in the oxygen toxicity model provide the first demonstration in vivo of abnormal intrapulmonary neutrophil kinetics in early oxygen toxicity prior to the onset of histologic evidence of lung injury or inflammation.

Rinaldo, J.E.; English, D.; Levine, J.; Stiller, R.; Henson, J.

1988-02-01T23:59:59.000Z

263

Flammability of selected heat resistant alloys in oxygen gas mixtures  

SciTech Connect (OSTI)

Within recent years, the use of oxygen has increased in applications where elevated temperatures and corrosion may be significant factors. In such situations, traditional alloys used in oxygen systems will not be adequate. Where alternative alloys must be utilized, based upon environmental requirements, it is essential that they may be characterized with respect to their ignition and combustion resistance in oxygen. Promoted ignition and promoted ignition-combustion are terms which have been used to describe a situation where a substance with low oxygen supports the combustion of a compatibility ignites and more ignition resistant material. In this paper, data will be presented on the promoted ignition-combustion behavior of selected heat resistant engineering alloys that may be considered for gaseous oxygen applications in severe environments. In this investigation, alloys have been evaluated via both flowing and static (fixed volume) approaches using a rod configuration. Oxygen-nitrogen gas mixtures with compositions ranging from approximately 40 to 99.7% oxygen at pressures of 3.55 to 34.6 MPa were used in the comparative studies.

Zawierucha, R.; McIlroy, K.; Million, J.F. [Praxair, Inc., Tonawanda, NY (United States)

1995-12-31T23:59:59.000Z

264

Measuring oxygen reduction/evolution reactions on the nanoscale  

SciTech Connect (OSTI)

The efficiency of fuel cells and metal-air batteries is significantly limited by the activation of oxygen reduction and evolution reactions (ORR/OER). Despite the well-recognized role of oxygen reaction kinetics on the viability of energy technologies, the governing mechanisms remain elusive and until now addressable only by macroscopic studies. This lack of nanoscale understanding precludes optimization of material architecture. Here we report direct measurements of oxygen reduction/evolution reactions and oxygen vacancy diffusion on oxygen-ion conductive solid surfaces with sub-10 nanometer resolution. In electrochemical strain microscopy (ESM), the biased scanning probe microscopy tip acts as a moving, electrocatalytically active probe exploring local electrochemical activity. The probe concentrates an electric field in a nanometer-scale volume of material, and bias-induced, picometer-level surface displacements provide information on local electrochemical processes. Systematic mapping of oxygen activity on bare and Pt-functionalized yttria-stabilized zirconia (YSZ) surfaces is demonstrated. This approach allows directly visualization of ORR/OER activation process at the triple-phase boundary, and can be extended to broad spectrum of oxygen-conductive and electrocatalytic materials.

Kalinin, Sergei V [ORNL; Jesse, Stephen [ORNL; Kumar, Amit [ORNL; Morozovska, A. N. [National Academy of Science of Ukraine, Kiev, Ukraine; Ciucci, Francesco [Harvard-Smithsonian Center for Astrophysics

2011-01-01T23:59:59.000Z

265

Boron nitride nanosheets as oxygen-atom corrosion protective coatings  

SciTech Connect (OSTI)

The research of two-dimensional nanomaterials for anticorrosion applications is just recently burgeoning. Herein, we demonstrate the boron nitride nanosheets (BNNSs) coatings for protecting polymer from oxygen-atom corrosion. High-quality BNNSs, which are produced by an effective fluid dynamics method with multiple exfoliation mechanisms, can be assembled into coatings with controlled thickness by vacuum filtration. After exposed in atom oxygen, the naked polymer is severely corroded with remarkable mass loss, while the BNNSs-coated polymer remains intact. Barrier and bonding effects of the BNNSs are responsible for the coating's protective performance. These preliminary yet reproducible results pave a way for resisting oxygen-atom corrosion.

Yi, Min [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Plasma Laboratory, Ministry-of-Education Key Laboratory of Fluid Mechanics, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Shen, Zhigang, E-mail: shenzhg@buaa.edu.cn [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Plasma Laboratory, Ministry-of-Education Key Laboratory of Fluid Mechanics, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); School of Material Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Zhao, Xiaohu [Plasma Laboratory, Ministry-of-Education Key Laboratory of Fluid Mechanics, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Liang, Shuaishuai [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Liu, Lei [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); School of Material Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China)

2014-04-07T23:59:59.000Z

266

The Solubility of Oxygen and Ozone in Liquids  

Science Journals Connector (OSTI)

This review covers the solubility of oxygen and ozone in liquids as a function of temperature and pressure. Solubility data for individual systems were critically evaluated and recommended or tentative values presented in many cases. The trend of solubilities in homologous series or related solvents is discussed. Liquids include water;seawater; aqueous salt solutions; mixed solvents; hydrocarbons; organic compounds containing oxygen halogen sulfur nitrogen or silicon; olive oil; and human blood. For ozone only its solubility in water is presented. Key words: aqueous solutions; biological fluids; gas solubility; hydrocarbons; mixed solvents; organic solvents; oxygen; ozone;seawater;water.

Rubin Battino; Timothy R. Rettich; Toshihiro Tominaga

1983-01-01T23:59:59.000Z

267

Solid phases of spatially nanoconfined oxygen: A neutron scattering study  

SciTech Connect (OSTI)

We present a comprehensive neutron scattering study on solid oxygen spatially confined in 12 nm wide alumina nanochannels. Elastic scattering experiments reveal a structural phase sequence known from bulk oxygen. With decreasing temperature cubic ?-, orthorhombic ?- and monoclinic ?-phases are unambiguously identified in confinement. Weak antiferromagnetic ordering is observed in the confined monoclinic ?-phase. Rocking scans reveal that oxygen nanocrystals inside the tubular channels do not form an isotropic powder. Rather, they exhibit preferred orientations depending on thermal history and the very mechanisms, which guide the structural transitions.

Kojda, Danny [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany) [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany); Freie Universität Berlin, 14195 Berlin (Germany); Wallacher, Dirk; Hofmann, Tommy, E-mail: tommy.hofmann@helmholtz-berlin.de [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany)] [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany); Baudoin, Simon; Hansen, Thomas [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France)] [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France); Huber, Patrick [Technische Universität Hamburg-Harburg, 21073 Hamburg (Germany)] [Technische Universität Hamburg-Harburg, 21073 Hamburg (Germany)

2014-01-14T23:59:59.000Z

268

Production of Ultra-Cold-Neutrons in Solid ?-Oxygen  

E-Print Network [OSTI]

Our recent neutron scattering measurements of phonons and magnons in solid \\alpha-oxygen have led us to a new understanding of the production mechanismen of ultra-cold-neutrons (UCN) in this super-thermal converter. The UCN production in solid \\alpha-oxygen is dominated by the excitation of phonons. The contribution of magnons to UCN production becomes only slightly important above E >10 meV and at E >4 meV. Solid \\alpha-oxygen is in comparison to solid deuterium less effcient in the down-scattering of thermal or cold neutrons into the UCN energy regime.

E. Gutsmiedl; A. Frei; F. Boehle; A. Maier; S. Paul; H. Schober; A. Orecchini

2009-11-23T23:59:59.000Z

269

Magnetic resonance imaging of the cerebral metabolic rate of oxygen (CMRO?)  

E-Print Network [OSTI]

Oxygen consumption is an essential process of the functioning brain. The rate at which the brain consumes oxygen is known as the cerebral metabolic rate of oxygen (CMRO?). CMRO? is intimately related to brain health and ...

Bolar, Divya Sanam

2010-01-01T23:59:59.000Z

270

Atomic oxygen flux determined by mixed-phase Ag/Ag2O deposition...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

oxygen flux determined by mixed-phase AgAg2O deposition. Atomic oxygen flux determined by mixed-phase AgAg2O deposition. Abstract: The flux of atomic oxygen generated in a...

271

Triple Oxygen Isotope Measurement of Nitrate to Analyze Impact of Aircraft Emissions  

E-Print Network [OSTI]

P. ; Craig, H. Atmospheric oxygen: isotopic composition andM.H. 1986. A non-mass-dependent oxygen isotope effect in theof ozone from molecular oxygen: the role of symmetry in

Chan, Sharleen

272

Advances in studying bioinorganic reaction mechanisms: isotopic probes of activated oxygen  

E-Print Network [OSTI]

Advances in studying bioinorganic reaction mechanisms: isotopic probes of activated oxygen intermediates in metalloenzymes Justine P Roth Metalloenzymes catalyze reactions of molecular oxygen and its reduced forms through the controlled formation of metal- bound, activated oxygen intermediates

Roth, Justine P.

273

Oxygen Loss from Venus and the Influence of Extreme Solar Wind Conditions  

E-Print Network [OSTI]

and I. Sillanpää (2009), Oxygen ion escape from Venus in aobservations of atmospheric oxygen escape during the passageI. F. Stewart (1981), Hot oxygen BIBLIOGRAPHY atoms in the

McEnulty, Tess

2012-01-01T23:59:59.000Z

274

High-Velocity Oxygen Fuel Thermal Spray of Fe-Based Amorphous Alloy: a Numerical and Experimental Study  

E-Print Network [OSTI]

High-Velocity Oxygen Fuel Thermal Spray of Fe-Basedusing a high velocity oxygen fuel (HVOF) spray processstructure. [12] High velocity oxygen fuel (HVOF) thermal

Ajdelsztajn, L.; Dannenberg, J.; Lopez, J.; Yang, N.; Farmer, J.; Lavernia, E. J.

2009-01-01T23:59:59.000Z

275

Oxygen enriched combustion system performance study. Phase 2: 100 percent oxygen enriched combustion in regenerative glass melters, Final report  

SciTech Connect (OSTI)

The field test project described in this report was conducted to evaluate the energy and environmental performance of 100% oxygen enriched combustion (100% OEC) in regenerative glass melters. Additional objectives were to determine other impacts of 100% OEC on melter operation and glass quality, and to verify on a commercial scale that an on-site Pressure Swing Adsorption oxygen plant can reliably supply oxygen for glass melting with low electrical power consumption. The tests constituted Phase 2 of a cooperative project between the United States Department of Energy, and Praxair, Inc. Phase 1 of the project involved market and technical feasibility assessments of oxygen enriched combustion for a range of high temperature industrial heating applications. An assessment of oxygen supply options for these applications was also performed during Phase 1, which included performance evaluation of a pilot scale 1 ton per day PSA oxygen plant. Two regenerative container glass melters were converted to 100% OEC operation and served as host sites for Phase 2. A 75 ton per day end-fired melter at Carr-Lowrey Glass Company in Baltimore, Maryland, was temporarily converted to 100% OEC in mid- 1990. A 350 tpd cross-fired melter at Gallo Glass Company in Modesto, California was rebuilt for permanent commercial operation with 100% OEC in mid-1991. Initially, both of these melters were supplied with oxygen from liquid storage. Subsequently, in late 1992, a Pressure Swing Adsorption oxygen plant was installed at Gallo to supply oxygen for 100% OEC glass melting. The particular PSA plant design used at Gallo achieves maximum efficiency by cycling the adsorbent beds between pressurized and evacuated states, and is therefore referred to as a Vacuum/Pressure Swing Adsorption (VPSA) plant.

Tuson, G.B.; Kobayashi, H.; Campbell, M.J.

1994-08-01T23:59:59.000Z

276

E-Print Network 3.0 - activity peak oxygen Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Yttria-stabilized zirconia, a well known oxygen ion... including fuel cells, oxygen pumps, and chemical gas sensors because of a number of superior properties... such as heat...

277

E-Print Network 3.0 - adjuvant hyperbaric oxygen Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ph.D., Editor Summary: . Hyperbaric oxygen is the definitive treat- ment for carbon monoxide poisoning.47 However, pro- ponents... III, Putnam RW, Dean JB: Hyperbaric oxygen and...

278

Microfluidic advantage : novel techniques for protein folding and oxygen control in cell cultures  

E-Print Network [OSTI]

Novel Techniques for Protein Folding and Oxygen Control inTemperature Jump System to Study Fast Protein FoldingNovel Techniques for Protein Folding and Oxygen Control in

Polinkovsky, Mark E.; Polinkovsky, Mark E.

2012-01-01T23:59:59.000Z

279

Impact of ethanol and butanol as oxygenates on SIDI engine efficiency...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

as oxygenates on SIDI engine efficiency and emissions using steady-state and transient test procedures Impact of ethanol and butanol as oxygenates on SIDI engine efficiency and...

280

E-Print Network 3.0 - active oxygen probe Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

OXYGEN PROBES FOR RESPIROMETRY S. Marsili Libelli *, C. Barresi... oxygen, ideally the measuring probe should be able to follow DO variations without introducing any... by...

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference...

282

Aging Enhances the Production of Reactive Oxygen Species andBactericid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enhances the Production of Reactive Oxygen Species andBactericidal Activity in Peritoneal Macrophages by Aging Enhances the Production of Reactive Oxygen Species andBactericidal...

283

Low-Oxygen Induction of Normally Cryptic psbA Genes in Cyanobacteria...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen Induction of Normally Cryptic psbA Genes in Cyanobacteria. Low-Oxygen Induction of Normally Cryptic psbA Genes in Cyanobacteria. Abstract: Microarray analysis indicated...

284

E-Print Network 3.0 - achieving fast oxygen Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Bulletin Collection: Environmental Sciences and Ecology 51 Oxygen diffusion in titanite: Lattice diffusion and fast-path diffusion in single crystals Summary: Oxygen...

285

Geothermal reservoir temperatures estimated from the oxygen isotope  

Open Energy Info (EERE)

reservoir temperatures estimated from the oxygen isotope reservoir temperatures estimated from the oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Geothermal reservoir temperatures estimated from the oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes Details Activities (3) Areas (3) Regions (0) Abstract: The oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes have been tested as a geothermometer in three areas of the western United States. Limited analyses of spring and borehole fluids and existing experimental rate studies suggest that dissolved sulfate and water are probably in isotopic equilibrium in all reservoirs of significant size with temperatures above

286

Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone  

Open Energy Info (EERE)

Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone Drill Cores Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone Drill Cores Details Activities (3) Areas (1) Regions (0) Abstract: Oxygen and carbon isotope ratios were measured for hydrothermal minerals (silica, clay and calcite) from fractures and vugs in altered rhyolite, located between 28 and 129 m below surface (in situ temperatures ranging from 81 to 199°C) in Yellowstone drill holes. The purpose of this study was to investigate the mechanism of formation of these minerals. The Δ18O values of the thirty-two analyzed silica samples (quartz, chalcedony, α-cristobalite, and β-cristobalite) range from -7.5 to +2.8‰. About one

287

Oxygen detected in atmosphere of Saturn's moon Dione  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of molecular oxygen ions in the upper-most atmosphere of Dione. March 3, 2012 Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials. Los Alamos National Laboratory sits on top of a once-remote mesa in northern New Mexico with the Jemez mountains as a backdrop to research and innovation covering multi-disciplines from bioscience, sustainable energy sources, to plasma physics and new materials.

288

Polymer/Silica Composite Films as Luminescent Oxygen Sensors  

Science Journals Connector (OSTI)

10-14 In this technique, an object (a model airplane or wing, a turbine blade, or an automobile) coated with an oxygen-sensing polymer coating (“pressure-sensitive paint,” PSP) is examined in a wind tunnel. ... To examine the influence of the silica particles on oxygen diffusion and oxygen permeation in these films, we carried out both time-scan and pulsed-laser experiments as a function of silica content on films containing PtOEP. ... We rationalize this result by imagining that oxygen adsorption onto the silica surface is diffusion-controlled. Fickian diffusion through the PDMS matrix controls the rate of quenching of dye molecules bound to the silica particles. ...

Xin Lu; Ian Manners; Mitchell A. Winnik

2001-03-06T23:59:59.000Z

289

Mechanisms of Photochemistry and Reactive Oxygen Production by  

E-Print Network [OSTI]

photosensitizer that produces reactive oxygen species (ROS) in the presence of light; however, its properties medical and environmental contexts as well as the potential applications implied for industrial or water of transferring light energy to chemical oxidation potential in theformof

Alvarez, Pedro J.

290

Oxygenated fuels for clean heavy-duty diesel engines  

Science Journals Connector (OSTI)

For diesel engines, changing the fuel composition is an alternative route towards achieving lower emission levels. The potential of oxygenated fuels to significantly reduce particulate matter emissions has already been demonstrated earlier. In this study, this research has been extrapolated towards lower emission levels. Exhaust gas recirculation (EGR) was applied to a modern EURO-3-type HD diesel engine. Tests were done at different engine working points, with EGR-levels and start of fuel delivery timings set to give NOx emissions between 3.5 and 2.0 g/kWh with regular diesel fuel. Fourteen blends of a low-sulphur diesel fuel respectively of a gas-to-liquid synthetic diesel fuel with different oxygenates were tested. The corresponding fuel matrix covers a range of fuel oxygen mass fractions up to 15%. Results are presented and the impact of fuel oxygen mass fraction and Cetane Number are analysed and compared with results from previous research.

P.J.M. Frijters; R.S.G. Baert

2006-01-01T23:59:59.000Z

291

Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen Sensor  

Broader source: Energy.gov [DOE]

Presentation given by Robert Bosch at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensors.

292

Modeling Terrestrial Biogenic Sources of Oxygenated Organic Emissions  

Science Journals Connector (OSTI)

In recent years, oxygenated volatile organic chemicals (OVOCs) likeacetone have been recognized as important atmospheric constituents due to their ability to sequester reactive nitrogen in the form peroxyacetyl nitrate (PAN) and to be a source ...

Christopher Potter; Steven Klooster; David Bubenheim; Hanwant B. Singh; Ranga Myneni

2003-07-01T23:59:59.000Z

293

Reaction of adsorption substitution of oxygen on a cracking catalyst  

SciTech Connect (OSTI)

In an investigation of catalysts for methanol synthesis and carbon monoxide conversion, the authors have observed, for the first time, the reaction of adsorption substitution of strongly bound oxygen on catalysts containing zeolites and compounds of lanthanum and cerium.

Vishnetskaya, M.V.; Takhtarova, G.N.; Topchieva, K.V.

1986-04-01T23:59:59.000Z

294

GARCÍA, HERNÁN E., AND LOUIS I. GORDON. Oxygen solubility in ...  

Science Journals Connector (OSTI)

bility (C,,*) at 1 atm total pressure in pure water and seawater in ... mulae expressing C,* (at STP, real gas) in cm3 dm-3 and ..... The solubility of nitrogen, oxygen.

2000-03-18T23:59:59.000Z

295

Nano- sized strontium titanate metal oxide semiconductor oxygen gas sensors.  

E-Print Network [OSTI]

??The project focuses on strontium titanate (SrTiO3> material, a very important material for oxygen sensors. The advantages of the material are low cost and stability… (more)

Hu, Ying.

2008-01-01T23:59:59.000Z

296

Hydrogen, Oxygen and Silicon Isotope Systematics in Lunar Material  

Science Journals Connector (OSTI)

31 March 1977 research-article Hydrogen, Oxygen and Silicon Isotope Systematics...are supported: (1) The bulk of the hydrogen in the lunar soils represents protons...samples of relatively detuerium rich hydrogen are found, probably resulting from in...

1977-01-01T23:59:59.000Z

297

Characterization of oxygen ion beams emitted from plasma focus  

Science Journals Connector (OSTI)

Abstract The Lee model is modified to include oxygen in addition to other gases. It is then applied to characterize the ion beams emitted from the low energy plasma focus PF 1 kJ device operated with oxygen gas. The numerical experiments give the following results: ion fluence- 3 × 1018 ions m?2, ion flux- 2.4 × 1026 ions m?2 s?1, ion energy- 261 keV, ion number- 3.5 × 1013, ion current- 3.5 kA, and damage factor- 1.12 × 109 Wm?2 s0.5. Numerical experiments are systematically carried out on other plasma focus devices of various energies. Scaling trends are suggested for oxygen ion beam characteristics. These results provide much needed benchmark reference values and scaling trends for ion beams of a plasma focus operated in oxygen gas.

Mohamad Akel; Sami Alsheikh Salo; Sor Heoh Saw; Sing Lee

2014-01-01T23:59:59.000Z

298

Oxygen Vacancies and Ferromagnetism in CoxTi–x–y...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Vacancies and Ferromagnetism in CoxTi–x–y. Oxygen Vacancies and Ferromagnetism in CoxTi–x–y. Abstract: Abstract: Cobalt-doped titanium dioxide, or CTO, has...

299

STUDY OF USING OXYGEN-ENRICHED COMBUSTION AIR FOR LOCOMOTIVE...  

Office of Scientific and Technical Information (OSTI)

and J.G. Whipple, Test and Evaluation o f Polymeric Membranes for Oxygen-Enrichment of Air, DOEAD- 127 10- 1, U S . Department of Energy, 1989. Sawyer, R.F., N.P. Cemansky, and...

300

Sunlight creates oxygenated species in water-soluble fractions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a t Sunlight creates oxygenated species in water-soluble fractions of Deepwater horizon oil Phoebe Z. Ray a , Huan Chen b , David C. Podgorski b,c , Amy M. McKenna b , Matthew A....

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Oxygen isotope records of carboniferous seasonality on the Russian platform  

E-Print Network [OSTI]

OXYGEN ISOTOPE RECORDS OF CARBONIFEROUS SEASONALITY ON THE RUSSIAN PLATFORM A Thesis by HUAYU WANG Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE May 1998 Major Subject: Geology OXYGEN ISOTOPE RECORDS OF CARBONIFFROUS SEASONALITY ON THE RUSSIAN PLATFORM A Thesis by HUAYU WANG Submitted to Texas ARM University in partial fulfillment of the requirements for the degree of MASTER...

Wang, Huayu

2012-06-07T23:59:59.000Z

302

Oxygenation cost estimates for Cherokee, Douglas, and Norris reservoirs  

SciTech Connect (OSTI)

The capital and annual costs associated with reoxygenation of the turbine releases at Cherokee, Douglas and Norris Reservoirs using the small bubble injection technique developed for Ft. Patrick Henry Dam were computed. The weekly average dissolved oxygen (DO) deficits were computed for each reservoir for an average year (based on 16 years of records). The total annual cost of an oxygen supply and injection system for each reservoir is presented. 5 refs., 6 figs., 5 tabs.

Fain, T.G.

1980-10-01T23:59:59.000Z

303

Determination of carbon, nitrogen, and oxygen in high purity magnesium  

E-Print Network [OSTI]

DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Submitted to the Graduate College of Texas A8cM University in partial i'ulfillment of the requirement for the degree of MASTER OF SCIENCE... December 1981 Major Subject: Chemistry DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Approved as to style and content by: E. A. Schweikert (Chairman of Committee) G. J. Bastiaans (Member) L...

Roche, Neil Gerard

2012-06-07T23:59:59.000Z

304

Oxygen consumption by asphalt films and resulting viscosity changes  

E-Print Network [OSTI]

OXYGEN CONSUMPTION BY ASPHALT FILNS AND RESULTING VISCOSITY CHANGES A Thesis by FRANK LEE CARTER, JR. Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... Nay 1965 Major Subject: Chemistry OXYGEN CONSUMPTION BY ASPHALT FILMS AND RESULTING VISCOSITY CHANGES A Thesis by FRANK LEE CARTER, JR. Approved as to style and content by: (Chairm of Committee) (H o Depa ( mb ) (Membe May 1965...

Carter, Frank Lee

2012-06-07T23:59:59.000Z

305

A ligand field chemistry of oxygen generation by the oxygen-evolving complex and synthetic active sites  

Science Journals Connector (OSTI)

...Department of Chemistry, Massachusetts Institute of Technology77 Massachusetts Avenue, 6-335, Cambridge...oxygen-evolving complex|catalysis|solar energy| 1. The nature...Department of Chemistry, Massachusetts Institute of Technology...

2008-01-01T23:59:59.000Z

306

Reduced metabolic rate and oxygen radicals production in stored insect sperm  

Science Journals Connector (OSTI)

...stored sperm. Our method of simultaneously measuring ROS production and metabolic...proteins. Our method also excludes...to accumulated hydrogen peroxide. Our...measuring ROS production and metabolic...proteins. Our method also excludes...to accumulated hydrogen peroxide. Our...

2012-01-01T23:59:59.000Z

307

Frequency effects on the production of reactive oxygen species in atmospheric radio frequency helium-oxygen discharges  

SciTech Connect (OSTI)

Several experimental and computational studies have shown that increasing frequency can effectively enhance the discharge stability in atmospheric radio-frequency (rf) discharges, but the frequency effects on the reactivity of rf discharges, represented by the densities of reactive oxygen species (ROS), are still far from fully understood. In this paper, a one-dimensional fluid model with 17 species and 65 reactions taken into account is used to explore the influences of the driving frequency on the production and destruction of ROS in atmospheric rf helium-oxygen discharges. From the computational results, with an increase in the frequency the densities of ROS decrease always at a constant power density, however, in the relatively higher frequency discharges the densities of ROS can be effectively improved by increasing the input power density with an expanded oxygen admixture range, while the discharges operate in the {alpha} mode, and the numerical data also show the optimal oxygen admixture for ground state atomic oxygen, at which the peak atomic oxygen density can be obtained, increases with the driving frequency.

Zhang, Yuantao T.; He Jin [Shandong Provincial Key Lab of UHV Technology and Gas Discharge Physics, School of Electrical Engineering, Shandong University, Jinan, Shandong Province 250061 (China)

2013-01-15T23:59:59.000Z

308

MEASUREMENT OF OXYGEN CONSUMPTION AND DIFFUSION IN EXPOSED AND COVERED REACTIVE MINE TAILINGS1  

E-Print Network [OSTI]

MEASUREMENT OF OXYGEN CONSUMPTION AND DIFFUSION IN EXPOSED AND COVERED REACTIVE MINE TAILINGS1 the in situ oxygen diffusion and consumption in tailings. It provides measured values for the oxygen reaction rate Kr and the effective diffusion De coefficients based on oxygen consumption and diffusion tests

Aubertin, Michel

309

E-Print Network 3.0 - atomic oxygen beams Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

beams Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic oxygen beams...

310

Oxygen Reduction Catalyzed by Platinum Nanoparticles Supported on Graphene Quantum Dots  

Science Journals Connector (OSTI)

graphene quantum dot; platinum nanoparticle; oxygen reduction; defect; X-ray diffraction; XPS; Tafel plot ...

Guoqiang He; Yang Song; Ke Liu; Andrew Walter; Sophie Chen; Shaowei Chen

2013-03-19T23:59:59.000Z

311

Dissolved Oxygen Sensing in a Flow Stream using Molybdenum Chloride Optical Indicators  

E-Print Network [OSTI]

Dissolved Oxygen Sensing in a Flow Stream using Molybdenum Chloride Optical Indicators Reza Loloee1@msu.edu Abstract--Dissolved oxygen concentration is considered the most important water quality variable in fish culture. Reliable and continuous (24/7) oxygen monitoring of dissolved oxygen (DO) in the 1 ­ 11 mg

Ghosh, Ruby N.

312

Oxygen Consumption by Germinating Seeds Advisor: Dr. Neil Budko (n.v.budko@tudelft.nl)  

E-Print Network [OSTI]

Oxygen Consumption by Germinating Seeds Advisor: Dr. Neil Budko (n.v.budko@tudelft.nl) Problem) by the Fytagoras B.V. (Leiden): "Seed germination in most seeds depends on the availability of oxygen. Living seeds commences. The availability of oxygen to the embryo in the seed depends on the oxygen concentration around

Vuik, Kees

313

Controlled oxygen doping of GaN using plasma assisted molecular-beam epitaxy  

E-Print Network [OSTI]

Controlled oxygen doping of GaN using plasma assisted molecular-beam epitaxy A. J. Ptak, L. J-assisted molecular-beam epitaxy to study the dependence of oxygen incorporation on polarity and oxygen partial pressure. Oxygen incorporates at a rate ten times faster on nitrogen-polar GaN than on the Ga polarity

Myers, Tom

314

E-Print Network 3.0 - atomic oxygen beam Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

beam Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic oxygen beam...

315

E-Print Network 3.0 - atomic oxygen interactions Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

interactions Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic oxygen interactions...

316

Ocean oxygen minima expansions and their biological impacts Lothar Stramma a,, Sunke Schmidtko a,b  

E-Print Network [OSTI]

Ocean oxygen minima expansions and their biological impacts Lothar Stramma a,Ã?, Sunke Schmidtko a Keywords: Deoxygenation Oxygen minimum zones Ecosystem changes Hypoxia Tropical ocean Tropical Atlantic dissolved oxygen with global warming. In coastal regimes oxygen deficits represent acute ecosystem

Levin, Lisa

317

E-Print Network 3.0 - atomic oxygen densities Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

densities Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic oxygen densities...

318

Turbulent Oxygen Flames in Type Ia Supernovae A. J. Aspden1  

E-Print Network [OSTI]

Turbulent Oxygen Flames in Type Ia Supernovae A. J. Aspden1 , J. B. Bell1 , and S. E. Woosley2 oxygen flames. The two aims of the paper are to examine the response of the inductive oxygen flame to intense levels of turbulence, and to explore the possibility of transition to detonation in the oxygen

319

E-Print Network 3.0 - atomic oxygen interaction Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

interaction Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic oxygen interaction...

320

E-Print Network 3.0 - artificial oxygen carrier Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

carrier Search Powered by Explorit Topic List Advanced Search Sample search results for: artificial oxygen carrier...

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Oxygen sublattice defect in cobalt oxide : formation, migration, charge localization and thermodynamic processes  

E-Print Network [OSTI]

643 Oxygen sublattice defect in cobalt oxide : formation, migration, charge localization of oxygen defects in CoO using classical simulations. The charge localization in the oxygen vacancy has]. The defect concentration in the oxygen sublattice is several orders of magnitude smaller, but never- theless

Paris-Sud XI, Université de

322

E-Print Network 3.0 - artificial oxygen carriers Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

carriers Search Powered by Explorit Topic List Advanced Search Sample search results for: artificial oxygen carriers...

323

Competitive oxygen-18 kinetic isotope effects expose OO bond formation in water oxidation  

E-Print Network [OSTI]

Competitive oxygen-18 kinetic isotope effects expose O­O bond formation in water oxidation. Roth*a Competitive oxygen kinetic isotope effects (18 O KIEs) on water oxidation initiated by ruthenium during oxygenic photo- synthesis.1 Formation of the O­O bond in molecular oxygen has been proposed

Roth, Justine P.

324

Deep-Sea Research II 47 (2000) 227}257 Variations in bioturbation across the oxygen  

E-Print Network [OSTI]

Deep-Sea Research II 47 (2000) 227}257 Variations in bioturbation across the oxygen minimum zone 1999; received in revised form 25 March 1999; accepted 30 March 1999 Abstract Oxygen minimum zones) along a transect across the oxygen minimum zone (OMZ) on the Oman margin. Bottom-water oxygen

Levin, Lisa

325

E-Print Network 3.0 - atomic oxygen density Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

density Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic oxygen density...

326

An Application of the Electric Resistance Furnace to the Determination of Oxygen in Iron and Steel.  

Science Journals Connector (OSTI)

An Application of the Electric Resistance Furnace to the Determination of Oxygen in Iron and Steel. ...

R. H. McMillen

1913-01-01T23:59:59.000Z

327

Natural Ores as Oxygen Carriers in Chemical Looping Combustion  

SciTech Connect (OSTI)

Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. The use of natural minerals as oxygen carriers has advantages, such as lower cost and availability. Eight materials, based on copper or iron oxides, were selected for screening tests of CLC processes using coal and methane as fuels. Thermogravimetric experiments and bench-scale fixed-bed reactor tests were conducted to investigate the oxygen transfer capacity, reaction kinetics, and stability during cyclic reduction/oxidation reaction. Most natural minerals showed lower combustion capacity than pure CuO/Fe{sub 2}O{sub 3} due to low-concentrations of active oxide species in minerals. In coal CLC, chryscolla (Cu-based), magnetite, and limonite (Fe-based) demonstrated better reaction performances than other materials. The addition of steam improved the coal CLC performance when using natural ores because of the steam gasification of coal and the subsequent reaction of gaseous fuels with active oxide species in the natural ores. In methane CLC, chryscolla, hematite, and limonite demonstrated excellent reactivity and stability in 50-cycle thermogravimetric analysis tests. Fe{sub 2}O{sub 3}-based ores possess greater oxygen utilization but require an activation period before achieving full performance in methane CLC. Particle agglomeration issues associated with the application of natural ores in CLC processes were also studied by scanning electron microscopy (SEM).

Tian, Hanjing; Siriwardane, Ranjani; Simonyi, Thomas; Poston, James

2013-08-01T23:59:59.000Z

328

Oxygen electrode reaction in molten carbonate fuel cells  

SciTech Connect (OSTI)

Molten carbonate fuel cell system is a leading candidate for the utility power generation because of its high efficiency for fuel to AC power conversion, capability for an internal reforming, and a very low environmental impact. However, the performance of the molten carbonate fuel cell is limited by the oxygen reduction reaction and the cell life time is limited by the stability of the cathode material. An elucidation of oxygen reduction reaction in molten alkali carbonate is essential because overpotential losses in the molten carbonate fuel cell are considerably greater at the oxygen cathode than at the fuel anode. Oxygen reduction on a fully-immersed gold electrode in a lithium carbonate melt was investigated by electrochemical impedance spectroscopy and cyclic voltammetry to determine electrode kinetic and mass transfer parameters. The dependences of electrode kinetic and mass transfer parameters on gas composition and temperature were examined to determine the reaction orders and the activation energies. The results showed that oxygen reduction in a pure lithium carbonate melt occurs via the peroxide mechanism. A mass transfer parameter, D{sub O}{sup 1/2}C{sub O}, estimated by the cyclic voltammetry concurred with that calculated by the EIS technique. The temperature dependence of the exchange current density and the product D{sub O}{sup 1/2}C{sub O} were examined and the apparent activation energies were determined to be about 122 and 175 kJ/ mol, respectively.

Appleby, A.J.; White, R.E.

1992-07-07T23:59:59.000Z

329

Oxygen abundance in the Sloan Digital Sky Survey  

E-Print Network [OSTI]

We present two samples of $\\hii$ galaxies from the Sloan Digital Sky Survey (SDSS) spectroscopic observations data release 3. The electron temperatures($T_e$) of 225 galaxies are calculated with the photoionized $\\hii$ model and $T_e$ of 3997 galaxies are calculated with an empirical method. The oxygen abundances from the $T_e$ methods of the two samples are determined reliably. The oxygen abundances from a strong line metallicity indicator, such as $R_{23}$, $P$, $N2$, and $O3N2$, are also calculated. We compared oxygen abundances of $\\hii$ galaxies obtained with the $T_e$ method, $R_{23}$ method, $P$ method, $N2$ method, and $O3N2$method. The oxygen abundances derived with the $T_e$ method are systematically lower by $\\sim$0.2 dex than those derived with the $R_{23}$ method, consistent with previous studies based on $\\hii$ region samples. No clear offset for oxygen abundance was found between $T_e$ metallicity and $P$, $N2$ and $O3N2$ metallicity. When we studied the relation between N/O and O/H, we found that in the metallicity regime of $\\zoh > 7.95$, the large scatter of the relation can be explained by the contribution of small mass stars to the production of nitrogen. In the high metallicity regime, $\\zoh > 8.2$, nitrogen is primarily a secondary element produced by stars of all masses.

F. Shi; X. Kong; F. Z. Cheng

2006-03-10T23:59:59.000Z

330

CRADA Final Report: Ionically Conductive Membranes Oxygen Separation  

SciTech Connect (OSTI)

Scientists at the Lawrence Berkeley National Laboratory (LBNL) in a collaborative effort with Praxair Corporation developed a bench-top oxygen separation unit capable of producing ultra-high purity oxygen from air. The device is based on thin-film electrolyte technology developed at LBNL as part of a solid oxide fuel cell program. The two teams first demonstrated the concept using planar ceramic disks followed by the development of tubular ceramic structures for the bench-top unit. The highly successful CRADA met all technical milestones on time and on budget. Due to the success of this program the industrial partner and the team at LBNL submitted a grant proposal for further development of the unit to the Advanced Technology Program administered by the National Institute of Standar~s. This proposal was selected for funding, and now the two teams are developing a precommercial oxygen separation unit under a 3-year, $6 million dollar program.

Visco, Steven J.

2001-10-29T23:59:59.000Z

331

Transition metal-promoted oxygen ion conductors as oxidation catalyst  

SciTech Connect (OSTI)

A novel metal oxide composite catalyst for the complete oxidation of carbon monoxide and hydrocarbons was prepared by combining oxygen ion conducting materials with active transition metals. The oxygen ion conductors used were typical fluorite-type oxides, such as ceria, zirconia, and others. Active base metal catalysts, such as copper, were used as additives to promote the catalytic properties of oxygen ion conductors. The intimate contact of the two kinds of materials gave rise to a highly active oxidation catalyst. On Cu-Ce-O composite catalysts, 95% of carbon monoxide was oxidized by air at {approximately} 100 C. Complete methane oxidation on the same catalyst took place at {approximately} 550 C. When the stoichiometric amount of sulfur dioxide was sued to oxidize carbon monoxide, 96% of sulfur dioxide was reduced to elemental sulfur at temperatures above 460 C with 99% of sulfur dioxide conversion. This type of composite catalyst also showed excellent resistance to water poisoning.

Liu, W.; Sarofim, A. [Massachusetts Inst. of Tech., Cambridge, MA (United States). Dept. of Chemical Engineering; Flytzani-Stephanopoulos, M. [Tufts Univ., Medford, MA (United States). Dept. of Chemical Engineering

1994-12-31T23:59:59.000Z

332

Method and apparatus for producing oxygenates from hydrocarbons  

DOE Patents [OSTI]

A chemical reactor for oxygenating hydrocarbons includes: (a) a dielectric barrier discharge plasma cell, the plasma cell comprising a pair of electrodes having a dielectric material and void therebetween, the plasma cell comprising a hydrocarbon gas inlet feeding to the void; (b) a solid oxide electrochemical cell, the electrochemical cell comprising a solid oxide electrolyte positioned between a porous cathode and a porous anode, an oxygen containing gas inlet stream feeding to the porous cathode side of the electrochemical cell; (c) a first gas passageway feeding from the void to the anode side of the electrochemical cell; and (d) a gas outlet feeding from the anode side of the electrochemical cell to expel reaction products from the chemical reactor. A method of oxygenating hydrocarbons is also disclosed. 4 figs.

Kong, P.C.; Lessing, P.A.

1995-06-27T23:59:59.000Z

333

Evolution of Photosynthesis and Biospheric Oxygenation Contingent Upon Nitrogen Fixation?  

E-Print Network [OSTI]

How photosynthesis by Precambrian cyanobacteria oxygenated Earth's biosphere remains incompletely understood. Here it is argued that the oxic transition, which took place between approximately 2.3 and 0.5 Gyr ago, required a great proliferation of cyanobacteria, and this in turn depended on their ability to fix nitrogen via the nitrogenase enzyme system. However, the ability to fix nitrogen was not a panacea, and the rate of biospheric oxygenation may still have been affected by nitrogen constraints on cyanobacterial expansion. Evidence is presented for why cyanobacteria probably have a great need for fixed nitrogen than other prokaryotes, underscoring the importance of their ability to fix nitrogen. The connection between nitrogen fixation and the evolution of photosynthesis is demonstrated by the similarities between nitrogenase and enzymes critical for the biosynthesis of (bacterio)chlorophyll. It is hypothesized that biospheric oxygenation would not have occurred if the emergence of cyanobacteria had not ...

Grula, J W

2006-01-01T23:59:59.000Z

334

Properties of Reactive Oxygen Species by Quantum Monte Carlo  

E-Print Network [OSTI]

The electronic properties of the oxygen molecule, in its singlet and triplet states, and of many small oxygen-containing radicals and anions have important roles in different fields of Chemistry, Biology and Atmospheric Science. Nevertheless, the electronic structure of such species is a challenge for ab-initio computational approaches because of the difficulties to correctly describe the statical and dynamical correlation effects in presence of one or more unpaired electrons. Only the highest-level quantum chemical approaches can yield reliable characterizations of their molecular properties, such as binding energies, equilibrium structures, molecular vibrations, charge distribution and polarizabilities. In this work we use the variational Monte Carlo (VMC) and the lattice regularized Monte Carlo (LRDMC) methods to investigate the equilibrium geometries and molecular properties of oxygen and oxygen reactive species. Quantum Monte Carlo methods are used in combination with the Jastrow Antisymmetrized Geminal Power (JAGP) wave function ansatz, which has been recently shown to effectively describe the statical and dynamical correlation of different molecular systems. In particular we have studied the oxygen molecule, the superoxide anion, the nitric oxide radical and anion, the hydroxyl and hydroperoxyl radicals and their corresponding anions, and the hydrotrioxyl radical. Overall, the methodology was able to correctly describe the geometrical and electronic properties of these systems, through compact but fully-optimised basis sets and with a computational cost which scales as $N^3-N^4$, where $N$ is the number of electrons. This work is therefore opening the way to the accurate study of the energetics and of the reactivity of large and complex oxygen species by first principles.

Andrea Zen; Bernhardt L. Trout; Leonardo Guidoni

2014-03-11T23:59:59.000Z

335

Epitaxial oxygen sponges as low temperature catalysts | ornl.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Functional Materials for Energy Functional Materials for Energy Epitaxial oxygen sponges as low temperature catalysts September 10, 2013 Crystal structure of SrCoO2.5 superimposed on a scanning transmission electron microscopy image of an epitaxially stabilized oxygen sponge. Fast and reversible redox reactions at considerably reduced temperatures are achieved by epitaxial stabilization of multivalent transition metal oxides. This illustrates the unprecedented potential of complex oxides for oxide-ionics, where oxidation state changes are used for energy generation, storage and electrochemical sensing. Thermomechanical degradation reduces the overall performance and lifetime of many perovskite oxides undergoing reversible redox reactions, such as those found in solid oxide fuel cells, rechargeable batteries,

336

Surface wettability of oxygen plasma treated porous silicon  

Science Journals Connector (OSTI)

Oxygen plasma treatment on porous silicon (p-Si) surfaces was studied as a practical and effective means to modify wetting properties of as-fabricated p-Si surfaces, that is, contact angles of the p-Si materials. P-Si samples spanning a wide range of ...

Lei Jiang, Songyan Li, Jiqian Wang, Limin Yang, Qian Sun, Zhaomin Li

2014-01-01T23:59:59.000Z

337

Characteristics of Exhaust Diesel Particles from Different Oxygenated Fuels  

Science Journals Connector (OSTI)

Characteristics of Exhaust Diesel Particles from Different Oxygenated Fuels ... The characteristic variations of exhaust particles were investigated on a light-duty diesel engine. ... This study was conducted on a 2005 model-year light-duty diesel engine that meets Chinese national stage III emission standards (equivalent to Euro III emission standards) without any exhaust control device. ...

Zhen Xu; Xinling Li; Chun Guan; Zhen Huang

2013-12-02T23:59:59.000Z

338

Oxygen and nitrogen diffusion in ?-hafnium from first principles  

SciTech Connect (OSTI)

We use a combination of density functional theory and multistate diffusion formalism to analyze the diffusion of oxygen and nitrogen in technologically important hafnium metal. Comparing the local density approximation and the Perdew-Burke-Ernzerhof version of the generalized gradient approximation, we find that a better description of the hafnium lattice in the latter results in the correct sequence of stable and transition states for oxygen interstitials leading to essentially quantitative agreement with experiment. For oxygen diffusion, we find an isotropic temperature-dependent diffusion coefficient of D=0.082e{sup ?2.04/k{sub B}T}cm{sup 2}s{sup ?1} utilizing interstitial sites with hexahedral and octahedral coordination. For the diffusivity of nitrogen, we find that an additional stable interstitial site, the crowdion site, exists and that the diffusion coefficient is D=0.15e{sup ?2.68/k{sub B}T}cm{sup 2}s{sup ?1}. Our results also reproduce the experimental observation that nitrogen diffusivity is lower than that of oxygen in hafnium.

O'Hara, Andrew; Demkov, Alexander A., E-mail: demkov@physics.utexas.edu [Department of Physics, The University of Texas at Austin, Austin, Texas 78712 (United States)

2014-05-26T23:59:59.000Z

339

Electrons, life and the evolution of Earth's oxygen cycle  

E-Print Network [OSTI]

, Rutgers University, New Brunswick, NJ 08901, USA The biogeochemical cycles of H, C, N, O and S are coupled-compete denitrification, a new stable electron `market' emerged in which oxygenic photosynthesis and aerobic respiration of energy. The hallmark of biological energy transduction is non-equilibrium redox chemi- stry. Indeed

340

Fault Tolerant Oxygen Control of a Diesel Engine Air System  

E-Print Network [OSTI]

Fault Tolerant Oxygen Control of a Diesel Engine Air System Rainer Nitsche Matthias Bitzer control problem of a Diesel engine air system having a jammed Exhaust Gas Recirculation (EGR) valve of the air system. Keywords: Fault tolerant control, Diesel engine, Air system, Model-based trajectory

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Catalytic ignition of fuel/oxygen/nitrogen mixtures over platinum  

SciTech Connect (OSTI)

Ignition of fuel/oxygen/nitrogen mixtures over platinum wire is experimentally studied by using microcalorimetry and by restricting the flow to the low Reynolds number range so that axisymmetry prevails. The fuels studied are propane, butane, propylene, ethylene, carbon monoxide, and hydrogen. Parameters investigated include flow velocity, fuel type and concentration, and oxygen concentration. The catalytic ignition temperatures of the various fuels are accurately determined over extensive ranges of fuel/oxygen/nitrogen concentrations. Results show two distinctly opposite ignition trends depending on the nature of the fuel. That is, the ignition temperature of lean propane/air and butane/air mixtures decreases as their fuel concentration is increased, while the reverse trend is observed for lean mixtures of propylene, ethylene, carbon monoxide, and hydrogen with air. Furthermore, the ignition of propane depends primarily on fuel concentration, while the ignition of carbon monoxide depends on fuel and oxygen concentrations to a comparable extent. These results are explained on the basis of hierarchical surface adsorption strengths of the different reactants in effecting catalytic ignition. Additional phenomena of interest are observed and discussed.

Cho, P.; Law, C.K.

1986-11-01T23:59:59.000Z

342

Exploring Neutron-Rich Oxygen Isotopes with MoNA  

E-Print Network [OSTI]

The Modular Neutron Array (MoNA) was used in conjunction with a large-gap dipole magnet (Sweeper) to measure neutron-unbound states in oxygen isotopes close to the neutron dripline. While no excited states were observed in 24O, a resonance at 45(2) keV above the neutron separation energy was observed in 23O.

N. Frank; T. Baumann; D. Bazin; J. Brown; P. A. DeYoung; J. E. Finck; A. Gade; J. Hinnefeld; R. Howes; J. -L. Lecouey; B. Luther; W. A. Peters; H. Scheit; A. Schiller; M. Thoennessen

2007-08-20T23:59:59.000Z

343

ChemicalChemical StratigraphyStratigraphy Oxygen, Carbon, Strontium,  

E-Print Network [OSTI]

2/25/2009 1 ChemicalChemical StratigraphyStratigraphy Oxygen, Carbon, Strontium, Sulphur Isotopes Change. Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S. Department evolves over time, with the geological time line running from right to left in this graph. The increased

Miami, University of

344

Characteristics of Knock in Hydrogen-Oxygen-Argon SI Engine  

SciTech Connect (OSTI)

A promising approach for improving the efficiency of internal combustion engines is to employ a working fluid with a high specific heat ratio such as the noble gas argon. Moreover, all harmful emissions are eliminated when the intake charge is composed of oxygen, nonreactive argon, and hydrogen fuel. Previous research demonstrated indicated thermal efficiencies greater than 45% at 5.5 compression ratio in engines operating with hydrogen, oxygen, and argon. However, knock limits spark advance and increasing the efficiency further. Conditions under which knock occurs in such engines differs from typical gasoline fueled engines. In-cylinder temperatures using hydrogen-oxygen-argon are higher due to the high specific heat ratio and pressures are lower because of the low compression ratio. Better understanding of knock under these conditions can lead to operating strategies that inhibit knock and allow operation closer to the knock limit. In this work we compare knock with a hydrogen, oxygen, and argon mixture to that of air-gasoline mixtures in a variable compression ratio cooperative fuels research (CFR) engine. The focus is on stability of knocking phenomena, as well as, amplitude and frequency of the resulting pressure waves.

Killingsworth, N; Rapp, V; Flowers, D; Aceves, S; Chen, J; Dibble, R

2010-02-23T23:59:59.000Z

345

Elevated Production of Active Oxygen in Bloom's Syndrome Cell Lines  

Science Journals Connector (OSTI)

...A23187, active oxygen production was elevated in BS cell...formylmethionylleucylphenylalanine, active oxy gen production was found to be increased...through their excessive production (6) or through a deficiency...result in high levels of hydrogen peroxide. Without a...cells. Materials and Methods Cell Lines. The EBV-transformed...

Thomas Nicotera; Kuldip Thusu; and Paresh Dandona

1993-11-01T23:59:59.000Z

346

ORIGINAL PAPER Sex differences in circulatory oxygen transport parameters  

E-Print Network [OSTI]

aerobic energy demands, and suggests that the higher [Hb] of female fish may com- pensate for the smaller has commenced, and so their stored energy reserves must satisfy the energetic demands of the migra rMV. These findings reject the hypothesis that all aspects of the circulatory oxygen trans- port

Hinch, Scott G.

347

RESPONSE TO OXYGEN DEFICIENCY SENSING EQUIPMENT IN LABORATORIES  

E-Print Network [OSTI]

/or lights to warn both the room occupants and those outside the room of the hazard within. 2. Equipment: Vacuum flask that holds liquid air or helium for scientific experiments. Hazardous Atmosphere. Type and location of oxygen deficiency monitoring equipment. When New York Fire Department (FDNY

Jia, Songtao

348

Subtask 3.12 - Oxygen-Fired CFBC  

SciTech Connect (OSTI)

Traditionally, air is used as the source of oxygen for firing a combustion system. A fully oxygen-fired circulating fluidized-bed combustion (CFBC) system would result in the production of a flue gas stream consisting of mostly carbon dioxide and water. The concentrated carbon dioxide stream would be available for sequestering or other purposes. Temperatures in an oxygen-blown CFBC system would be controlled by a combination of flue gas recycle, solids recirculation, and by appropriately sizing and locating the amount of heat-transfer surface required. Flue gas recycle provides the additional gas required for adequate fluidization and circulation of solids replacing the nitrogen that would be present in an air-blown system. The amount of flue gas recycle will determine how much of the remaining heat from the coal combustion will have to be removed. If the amount of flue gas recycle required by increasing solids recirculation and oxygen staging is limited, introducing the pure oxygen at multiple locations in the combustor to result in a more even temperature profile should result in a more compact system, thus reducing initial capital costs for construction. The overall efficiency of the process should be greater than that of an air-blown system since less fuel is required for the creation of the same amount of energy. The Energy & Environmental Research Center (EERC) is in a unique position to advance this technology. It has a world-class CFBC pilot plant, has experience with firing a wide range of fuels in our air-fired CFBC pilot plant, has prior experience with oxygen-firing a slagging furnace system in a pulverized coal-fired mode with a bituminous coal, and has all of the components required for oxygen-firing right next to the CFBC pilot plant already in place. An engineering study was performed to identify methods, an overall appropriate configuration, and an operating strategy for a fully oxygen-fired CFBC pilot plant by: (1) developing a plan to optimize the amount of flue gas recycle required to control bed temperature; (2) determining how to best utilize the heat-transfer surfaces in a CFBC pilot plant, such as increased external bed surface, to more beneficially use increased solids recycle; (3) identifying appropriate methods for staged addition of the oxygen/recycled flue gas streams to maintain a good temperature profile in the combustor; and (4) determining the level of effort required to convert the EERC CFBC pilot plant to one that is oxygen-blown. The EERC additionally used its experience to consider what would be required for firing a wide range of fuels from biomass to low-rank coals to high-rank coals and petroleum cokes. These proposed modifications will be performed based upon obtaining the required funding.

Douglas Hajicek; Mark Musich; Ann Henderson

2007-02-28T23:59:59.000Z

349

working lunch menus prices excludes VAT  

E-Print Network [OSTI]

person +2 items £12.50 per person +3 items £15.00 per person +4 items £17.50 per person meat » mini pie with a coconut dipping sauce » all butter pastry mini sausage roll » traditional melton mowbray pork pie » scotch

350

Electrocatalysis of anodic and cathodic oxygen-transfer reactions  

SciTech Connect (OSTI)

The electrocatalysis of oxygen-transfer reactions is discussed in two parts. In Part I, the reduction of iodate (IO{sub 3}{sup {minus}}) is examined as an example of cathodic oxygen transfer. On oxide-covered Pt electrodes (PtO), a large cathodic current is observed in the presence of IO{sub 3}{sup {minus}} to coincide with the reduction of PtO. The total cathodic charge exceeds the amount required for reduction of PtO and IO{sub 3}{sup {minus}} to produce an adsorbed product. An electrocatalytic link between reduction of IO{sub 3}{sup {minus}} and reduction of PtO is indicated. In addition, on oxide-free Pt electrodes, the reduction of IO{sub 3}{sup {minus}} is determined to be sensitive to surface treatment. The electrocatalytic oxidation of CN{sup {minus}} is presented as an example of anodic oxygen transfer in Part II. The voltametric response of CN{sup {minus}} is virtually nonexistent at PbO{sub 2} electrodes. The response is significantly improved by doping PbO{sub 2} with Cu. Cyanide is also oxidized effectively at CuO-film electrodes. Copper is concluded to serve as an adsorption site for CN{sup {minus}}. It is proposed that an oxygen tunneling mechanism comparable to electron tunneling does not occur at the electrode-solution interface. The adsorption of CN{sup {minus}} is therefore considered to be a necessary prerequisite for oxygen transfer. 201 refs., 23 figs., 2 tabs.

Wels, B.R.

1990-09-21T23:59:59.000Z

351

Oxygen and Nitrogen in Isolated Dwarf Irregular Galaxies  

E-Print Network [OSTI]

We present long slit optical spectroscopy of 67 HII regions in 21 dwarf irregular galaxies to investigate the enrichment of oxygen, nitrogen, neon, sulfur, and argon in low mass galaxies. Oxygen abundances are obtained via direct detection of the temperature sensitive emission lines for 25 HII regions; for the remainder of the sample, oxygen abundances are estimated from strong line calibrations. The direct abundance determinations are compared to the strong-line abundance calibrations of both McGaugh (1991) and Pilyugin (2000). Global oxygen and nitrogen abundances for this sample of dwarf irregular galaxies are examined in the context of open and closed box chemical evolution models. While several galaxies are consistent with closed box chemical evolution, the majority of this sample have an effective yield ~1/4 of the expected yield for a constant star formation rate and Salpeter IMF, indicating that either outflow of enriched gas or inflow of pristine gas has occurred. The effective yield strongly correlates with M_H/L_B in the sense that gas-rich galaxies are more likely to be closed systems. However, the effective yield does not appear to correlate with other global parameters such as dynamical mass, absolute magnitude, star formation rate or surface brightness. A correlation is found between the observed nitrogen-to-oxygen ratio and the color of the underlying stellar population; redder dwarf irregular galaxies have higher N/O ratios than blue dwarf irregular galaxies. The relative abundance ratios are interpreted in the context of delayed release of nitrogen and varied star formation histories.

L. van Zee; M. P. Haynes

2005-09-22T23:59:59.000Z

352

Normal muscle oxygen consumption and fatigability in sickle cell patients despite reduced microvascular oxygenation and hemorheological abnormalities  

E-Print Network [OSTI]

1 Normal muscle oxygen consumption and fatigability in sickle cell patients despite reduced hypothesized that muscle metabolism and fatigability could be impaired in sickle cell patients, no study has profile at rest between 16 healthy subjects (AA), 20 sickle cell-hemoglobin C disease (SC) patients and 16

Paris-Sud XI, Université de

353

IMPACT OF OXYGENATED FUEL ON DIESEL ENGINE PERFORMANCE AND EMISSIONS  

SciTech Connect (OSTI)

As evidenced by recent lawsuits brought against operators of large diesel truck fleets [1] and by the Consent Decree brought against the heavy-duty diesel manufacturers [2], the environmental and health effects of diesel engine emissions continue to be a significant concern. Reduction of diesel engine emissions has traditionally been achieved through a combination of fuel system, combustion chamber, and engine control modifications [3]. Catalytic aftertreatment has become common on modern diesel vehicles, with the predominant device being the diesel oxidation catalytic converter [3]. To enable advanced after-treatment devices and to directly reduce emissions, significant recent interest has focused on reformulation of diesel fuel, particularly the reduction of sulfur content. The EPA has man-dated that diesel fuel will have only 15 ppm sulfur content by 2007, with current diesel specifications requiring around 300 ppm [4]. Reduction of sulfur will permit sulfur-sensitive aftertreatment devices, continuously regenerating particulate traps, NOx control catalysts, and plasma assisted catalysts to be implemented on diesel vehicles [4]. Another method of reformulating diesel fuel to reduce emissions is to incorporate oxygen in the fuel, as was done in the reformulation of gasoline. The use of methyl tertiary butyl ether (MTBE) in reformulated gasoline has resulted in contamination of water resources across the country [5]. Nonetheless, by relying on the lessons learned from MTBE, oxygenation of diesel fuel may be accomplished without compromising water quality. Oxygenation of diesel fuel offers the possibility of reducing particulate matter emissions significantly, even for the current fleet of diesel vehicles. The mechanism by which oxygen content leads to particulate matter reductions is still under debate, but recent evidence shows clearly that ''smokeless'' engine operation is possible when the oxygen content of diesel fuel reaches roughly 38% by weight [6]. The potential improvements in energy efficiency within the transportation section, particularly in sport utility vehicles and light-duty trucks, that can be provided by deployment of diesel engines in passenger cars and trucks is a strong incentive to develop cleaner burning diesel engines and cleaner burning fuels for diesel engines. Thus, serious consideration of oxygenated diesel fuels is of significant practical interest and value to society. In the present work, a diesel fuel reformulating agent, CETANERTM, has been examined in a popular light-medium duty turbodiesel engine over a range of blending ratios. This additive is a mixture of glycol ethers and can be produced from dimethyl ether, which itself can be manufactured from synthesis gas using Air Products' Liquid Phase Dimethyl Ether (LPDME TM) technology. CETANERTM is a liquid, has an oxygen content of 36 wt.%, has a cetane number over 100 and is highly miscible in diesel fuel. This combination of physical and chemical properties makes CETANERTM an attractive agent for oxygenating diesel fuel. The present study considered CETANERTM ratios from 0 to 40 wt.% in a California Air Resources Board (CARB) specification diesel fuel. Particulate matter emissions, gaseous emissions and in-cylinder pressure traces were monitored over the AVL 8-Mode engine test protocol [7]. This paper presents the results from these measurements and discusses the implications of using high cetane number oxygenates in diesel fuel reformulation.

Boehman, Andre L.

2000-08-20T23:59:59.000Z

354

OXYGEN CONSUMPTION OF NORMAL AND GREEN OYSTERS 1 PAUL S. GALTSOFF, Ph. D., In Charge, Oyster Fishery Investigations  

E-Print Network [OSTI]

OXYGEN CONSUMPTION OF NORMAL AND GREEN OYSTERS 1 $ By PAUL S. GALTSOFF, Ph. D., In Charge, Oyster _ ~ethod _ Oxygen consumption of normal oyster _ Effect of oxygen tension on oxygen con- sumption _ Page 489 Increased rate of metabolism _ 490 Experiments with green oysters _ 493 Oxygen consumption

355

Preparation of copper-based oxygen carrier supported by titanium dioxide  

Science Journals Connector (OSTI)

Chemical-looping combustion (CLC) is an indirect oxygen combustion strategy, considered to be the most cost...2...) inherently concentrated. The oxygen carriers in the combustion process are subjected to severe e...

Yaowen Cui; Yan Cao; Wei-ping Pan

2013-12-01T23:59:59.000Z

356

Effects of Hydration and Oxygen Vacancy on CO2 Adsorption and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hydration and Oxygen Vacancy on CO2 Adsorption and Activation on ?-Ga2O3(100). Effects of Hydration and Oxygen Vacancy on CO2 Adsorption and Activation on ?-Ga2O3(100)....

357

Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenati...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on In2O3(110): A DFT Study. Active Oxygen Vacancy Site for Methanol Synthesis from CO2 Hydrogenation on...

358

Denitrification Rates in the Low-Oxygen Waters of the Stratified Baltic Proper  

Science Journals Connector (OSTI)

...F. 1970. The solubility of nitrogen, oxygen and argon in water and sea water. Deep-Sea Res...tion of dissolved nitrogen, oxygen, argon...inorganic carbon by gas chromatography...Nitrous oxide solubility in water and sea water...

Ulf Rönner; Fred Sörensson

1985-10-01T23:59:59.000Z

359

A Mechanism of Photo-Induced Desorption of Oxygen Atoms From...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Photo-Induced Desorption of Oxygen Atoms From MgO Nano-Crystals. A Mechanism of Photo-Induced Desorption of Oxygen Atoms From MgO Nano-Crystals. Abstract: In a series of recent...

360

Hydrous oxide species as inhibitors of oxygen reduction at platinum activated fuel cell cathodes  

Science Journals Connector (OSTI)

The successful development of a methanol/air fuel cell requires optimum performance of the air/ oxygen cathode at about 0.8 V vs RHE. ... oxygen gas reduction on platinum (the best electrocatalyst for this reacti...

L. D. Burke; J. K. Casey; J. A. Morrissey…

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

In Situ Ambient Pressure X-ray Photoelectron Spectroscopy Studies of Lithium-Oxygen Redox Reactions  

E-Print Network [OSTI]

The lack of fundamental understanding of the oxygen reduction and oxygen evolution in nonaqueous electrolytes significantly hinders the development of rechargeable lithium-air batteries. Here we employ a solid-state ...

Lu, Yi-chun

362

Fundamental studies of heterostructured oxide thin film electrocatalysts for oxygen reduction at high temperatures  

E-Print Network [OSTI]

Searching for active and cost-effective catalysts for oxygen electrocatalysis is essential for the development of efficient clean electrochemical energy technologies. Perovskite oxides are active for surface oxygen exchange ...

Crumlin, Ethan J

2012-01-01T23:59:59.000Z

363

Assessment of Tumor Energy and Oxygenation Status by Bioluminescence, Nuclear Magnetic Resonance Spectroscopy, and Cryospectrophotometry  

Science Journals Connector (OSTI)

...Assessment of Tumor Energy and Oxygenation Status...Bioluminescence, Nuclear Magnetic Resonance...Assessment of tumor energy and oxygenation status...bioluminescence, nuclear magnetic resonance...Assessment of Tumor Energy and Oxyg nationStatus by Bioluminescence, Nuclear Magnetic Resonance...

W. Mueller-Klieser; C. Schaefer; S. Walenta; E. K. Rofstad; B. M. Fenton; and R. M. Sutherland

1990-03-15T23:59:59.000Z

364

Electronic structure of perovskite oxide surfaces at elevated temperatures and its correlation with oxygen reduction reactivity  

E-Print Network [OSTI]

The objective is to understand the origin of the local oxygen reduction reaction (ORR) activity on the basis of the local electronic structure at the surface of transition metal oxides at elevated temperatures and in oxygen ...

Chen, Yan, Ph. D. Massachusetts Institute of Technology

2014-01-01T23:59:59.000Z

365

Combined SIMS, AES, and XPS Investigations of Oxygen-Covered 3d Transition Metal Surfaces  

Science Journals Connector (OSTI)

The interaction of some 3d metals with oxygen in the monolayer range under UHV conditions has been investigated by quasisimultaneous static SIMS, static AES, and XPS. The combination ... metal-oxygen interaction ...

O. Ganschow; L. Wiedmann; A. Benninghoven

1979-01-01T23:59:59.000Z

366

Strain aging and strain rate sensitivity of oxygen-enriched (? + ?) Zircaloy-2  

Science Journals Connector (OSTI)

The flow behavior of oxygen-enriched Zircaloy-2, with oxygen concentrations ranging from 1260 to 12360 ppm, was investigated over the (? +?) phase field and parts of the adjacent ? and? phase regions. The flow cu...

R. Choubey; J. J. Jonas; B. A. Cheadle

1982-11-01T23:59:59.000Z

367

Surface structure of ?-Cr2O3(0001) after activated oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Surface structure of ?-Cr2O3(0001) after activated oxygen exposure. Surface structure of ?-Cr2O3(0001) after activated oxygen exposure. Abstract: The surface structure...

368

Stability and Migration of Charged Oxygen Interstitials in ThO2...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Stability and Migration of Charged Oxygen Interstitials in ThO2 and CeO2. Stability and Migration of Charged Oxygen Interstitials in ThO2 and CeO2. Abstract: Density functional...

369

Growth of Epitaxial Thin Pd(111) Films on Pt(111) and Oxygen...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Growth of Epitaxial Thin Pd(111) Films on Pt(111) and Oxygen-Terminated FeO(111) Surfaces . Growth of Epitaxial Thin Pd(111) Films on Pt(111) and Oxygen-Terminated FeO(111)...

370

Development, testing, and application of quantitative oxygenation imaging from magnetic susceptibility by MRI  

E-Print Network [OSTI]

The healthy brain consumes 20% of total oxygen used by the body under normal conditions. Continuous oxygen delivery to neural tissue is needed to maintain normal brain function and viability. Reliable measurements of brain ...

Fan, Audrey Peiwen

2014-01-01T23:59:59.000Z

371

Weird Oxygen Bonding under Pressure | Advanced Photon Source  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Breakthrough in Improving Osteoporosis Drug Design A Breakthrough in Improving Osteoporosis Drug Design Allaying Structural-Alloy Corrosion Putting the Pressure on MOFs Newly Described "Dragon" Protein Could Be Key to Bird Flu Cure Hearing the Highest Pitches Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed Weird Oxygen Bonding under Pressure AUGUST 8, 2008 Bookmark and Share Schematic shows the topology of π* orbital interactions in the (O2)4 cluster. (Image copyright National Academy of Sciences, PNAS.) Oxygen, the third most abundant element in the cosmos and essential to life on Earth, changes its forms dramatically under pressure, transforming to a solid with spectacular colors. Eventually it becomes metallic and a

372

Bimetallic Fe-Ni Oxygen Carriers for Chemical Looping Combustion  

SciTech Connect (OSTI)

The relative abundance, low cost, and low toxicity of iron make Fe-based oxygen carriers of great interest for chemical looping combustion (CLC), an emerging technology for clean and efficient combustion of fossil and renewable fuels. However, Fe also shows much lower reactivity than other metals (such as Ni and Cu). Here, we demonstrate strong improvement of Fe-based carriers by alloying the metal phase with Ni. Through a combination of carrier synthesis and characterization with thermogravimetric and fixed-bed reactor studies, we demonstrate that the addition of Ni results in a significant enhancement in activity as well as an increase in selectivity for total oxidation. Furthermore, comparing alumina and ceria as support materials highlights the fact that reducible supports can result in a strong increase in oxygen carrier utilization.

Bhavsar, Saurabh; Veser, Goetz

2013-11-06T23:59:59.000Z

373

The oxygen emission lines in Wolf-Rayet spectra  

SciTech Connect (OSTI)

The statistical equilibrium of oxygen in the line-emitting regions of WR stars is studied using the one-representative point theory of Castor and van Blerkom (1970) for a wider range of the radiation temperature, electron temperature, and electron density. Radiative processes, collisional processes, and electronic recombination are studied for a 59-level model atom. The level populations depart by large factors from those expected for LTE at the electron temperature and electron density. When the parameters have the values found previously by Bhatia and Underhill to be representative for WR stars, the oxygen atoms are strongly concentrated in the lower levels of O(2+), O(3+), and O(4+). The predicted relative energies in typical lines of O III, O IV, and O V for a solar abundance ratio of O to H are compatible with what is observed in WC and WN spectra. 47 refs.

Bhatia, A.K.; Underhill, A.B. (NASA, Goddard Space Flight Center, Greenbelt, MD (USA) British Columbia Univ., Vancouver (Canada))

1990-07-01T23:59:59.000Z

374

Novel New Oxygen Carriers for Chemical Looping Combustion of Solid Fuels  

Science Journals Connector (OSTI)

Novel New Oxygen Carriers for Chemical Looping Combustion of Solid Fuels ... A loop of chem. ... Energy Combust. ...

Yueying Fan; Ranjani Siriwardane

2014-02-21T23:59:59.000Z

375

Oxygen Release and Oxidation Rates of MgAl2O4-Supported CuO Oxygen Carrier for Chemical-Looping Combustion with Oxygen Uncoupling (CLOU)  

Science Journals Connector (OSTI)

The choice of wood char was made after comparing the oxygen concentration in the reactor’s exit stream, using different solid fuels and taking advantage of the high reactivity of the wood char, compared to other available fuels (e.g., coal or petcoke). ... The required solids inventory in the fuel reactor obtained here is lower than a previously reported investigation for a 40 wt?% CuO on ZrO2 support using petcoke as fuel (120–200 kg MWth–1)(34) and a recent study of continuous operation using a spray-dried 60 wt?% CuO on MgAl2O4 support (235 kg MWth–1 at 960 °C),(22) but is in close agreement with the values obtained by Adánez-Rubio et al.(48) for the spray-dried 60 wt?% CuO on MgAl2O4 support (39 kg MWth–1 at 930 °C). ... data of Mexican petcoke particles by a CuO/ZrO2 oxygen carrier. ...

Mehdi Arjmand; Martin Keller; Henrik Leion; Tobias Mattisson; Anders Lyngfelt

2012-10-03T23:59:59.000Z

376

Examination of oxygen uncoupling behaviour and reactivity towards methane for manganese silicate oxygen carriers in chemical-looping combustion  

Science Journals Connector (OSTI)

Abstract Cheap and environmental friendly Mn–Si oxygen carriers manufactured from Mn3O4 and SiO2 by spray-drying have been investigated with respect to properties for chemical-looping combustion (CLC) and chemical-looping with oxygen uncoupling (CLOU). Fifteen oxygen carriers with SiO2 content varying from 2 wt% to 75 wt% were prepared and calcined at 1050 °C and 1150 °C. The ability of material to release O2 and their reactivity towards CH4 were examined in the temperature range 900–1100 °C. Particles with a SiO2 content of more than 45 wt% and calcined at 1150 °C showed limited CLOU behaviour and poor reactivity towards CH4 at all temperatures investigated. The rest of the materials had significant CLOU properties and provided high conversion of CH4 under the experimental conditions chosen. Increasing the temperature of operation enhanced the CLOU behaviour and reactivity towards CH4. At temperatures above 950 °C, the CH4 conversion was 90–100% for these materials. Crystalline phases identified by XRD in the oxidized samples with more than 45 wt% SiO2 and calcined at 1150 °C were mainly rhodonite MnSiO3. For materials with SiO2 content below 45 wt%, braunite Mn7SiO12 was detected as the main phase in most of the samples after oxidation. This indicates that braunite Mn7SiO12 is the main active phase for oxygen transfer in CLC and CLOU, which is supported by thermodynamic calculations. The reactivity of all of the materials were also studied with syngas (50% CO and 50% H2), showing complete gas conversion at 950 °C, except for materials with a SiO2 content of more than 45 wt% and calcined at 1150 °C. The mechanical integrity and attrition resistance of the oxygen carriers were examined in a jet-cup attrition rig, and although the attrition rates varied, some reactive material showed low rates of attrition, making them very promising oxygen carrier materials for applications related to CLC and CLOU. However, measures should probably be taken to improve the crushing strength to some extent.

Dazheng Jing; Mehdi Arjmand; Tobias Mattisson; Magnus Rydén; Frans Snijkers; Henrik Leion; Anders Lyngfelt

2014-01-01T23:59:59.000Z

377

INCOMPLETE CARBON-OXYGEN DETONATION IN TYPE Ia SUPERNOVAE  

SciTech Connect (OSTI)

Incomplete carbon-oxygen detonation with reactions terminating after burning of C{sup 12} in the leading C{sup 12} + C{sup 12} reaction (C-detonation) may occur in the low-density outer layers of white dwarfs exploding as Type Ia supernovae (SNe Ia). Previous studies of carbon-oxygen detonation structure and stability at low densities were performed under the assumption that the velocity of a detonation wave is derived from complete burning of carbon and oxygen to iron. In fact, at densities {rho} {<=} 10{sup 6} g cm{sup -3} the detonation in SNe Ia may release less than a half of the available nuclear energy. In this paper, we study basic properties of such detonations. We find that the length of an unsupported steady-state C-detonation is {approx_equal}30-100 times greater than previously estimated and that the decreased energy has a drastic effect on the detonation stability. In contrast to complete detonations which are one-dimensionally stable, C-detonations may be one-dimensionally unstable and propagate by periodically re-igniting themselves via spontaneous burning. The re-ignition period at {rho} {<=} 10{sup 6} g cm{sup -3} is estimated to be greater than the timescale of an SN Ia explosion. This suggests that propagation and quenching of C-detonations at these densities could be affected by the instability. Potential observational implications of this effect are discussed.

Dominguez, Inma [Departamento de Fisica Teorica y del Cosmos, University of Granada, 18071 Granada (Spain); Khokhlov, Alexei [Department of Astronomy and Astrophysics and the Enrico Fermi Institute, University of Chicago, Chicago, IL 60637 (United States)

2011-04-01T23:59:59.000Z

378

Interaction of oxygen with sodium at 80 and 20 K  

Science Journals Connector (OSTI)

We have studied the interaction of oxygen with evaporated Na films at 80 and 20 K, by means of core-level and valence photoemission spectroscopy and photoexcited Auger spectroscopy, as well as plasmon loss structures associated with core-level emission. The initial oxidation at 80 and 20 K is characterized by an oxygen 2p resonance at about -3.4 eV with respect to the Fermi level, increasing intensity in the Na-O interatomic Auger transition, increasing width and intensity of the Na 2p core level, and changes in the surface-plasmon loss region which might be interpreted as a decreasing ‘‘free-electron’’ density. Further oxidation leads to oxygen valence emission at -7.4 and -8.4 eV, which may be due to O-O interaction. Larger O2 exposures yield a valence band with structure at -3.2, -5.3, -7.2, and -9.5 eV.

M. L. Shek; Xiaohe Pan; Myron Strongin; M. W. Ruckman

1986-09-15T23:59:59.000Z

379

Spectroscopic study of the ? phase of solid oxygen  

Science Journals Connector (OSTI)

The infrared spectrum of the ? phase of solid oxygen has been studied between room temperature and 20 K as a function of pressure up to 63 GPa. Besides the strong absorption in the fundamental O2 vibron mode and the broad doublet in the overtone region, another peak is detected in the far infrared region. The analysis of the overtone bands allows the determination of the density of states of the O2 vibron region which consists of two separated energy regions, including one the infrared and the other the Raman bands observed in the 1500–1650?cm-1 range. This result, consistent with the analysis of the other Raman and infrared bands at lower frequency, is interpreted on the basis of a crystal composed by a molecular unit formed by four oxygen atoms. This hypothesis explains the strong infrared absorption which is in contrast with the model of a crystal composed by diatomic oxygen molecules. Very thin crystalline slabs (measure the intensity of the strong infrared absorption at 1500–1550?cm-1. The measurement of the Raman spectrum as a function of the incident power and of the laser excitation frequency shows how the intensity and the frequency of the Raman lines are affected by the experimental conditions. Finally, a simple chain model provides indirect proof of our assignment of the low-frequency infrared mode and allows to rule out an association in polymeric units formed by more than four atoms even at pressures close to the insulator-metal transition.

Federico A. Gorelli; Lorenzo Ulivi; Mario Santoro; Roberto Bini

2001-02-20T23:59:59.000Z

380

Oxygen abundance methods in the SDSS: view from modern statistics  

E-Print Network [OSTI]

Our purpose is to find which is the most reliable one among various oxygen abundance determination methods. We will test the validity of several different oxygen abundance determination methods using methods of modern statistics. These methods include Bayesian analysis and information scoring. We will analyze a sample of $\\sim$6000 $\\hii$ galaxies from the Sloan Digital Sky Survey (SDSS) spectroscopic observations data release four. All methods that we used drew the same conclusion that the $T_e$ method is a more reliable oxygen abundance determination methods than the Bayesian metallcity method under the existing telescope ability. The ratios of the likelihoods between the different kinds of methods tell us that the $T_e$, $P$, and $O3N2$ methods are consistent with each other because the $P$ and $O3N2$ method are calibrated by $T_e$-method. The Bayesian and $R_{23}$ method are consistent with each other because both are calibrated by a galaxy model. In either case, the $N2$ method is an {\\it unreliable} method.

F. Shi; G. Zhao; James Wicker

2007-10-24T23:59:59.000Z

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

The solar oxygen crisis: Probably not the last word  

E-Print Network [OSTI]

In this work we present support for recent claims that advocate a downward revision of the solar oxygen abundance. Our analysis employs spatially-resolved spectro-polarimetric observations including the \\FeI lines at 6302 \\AA and the \\OI infrared triplet around 7774 \\AA in the quiet Sun. We used the \\FeI lines to reconstruct the three-dimensional thermal and magnetic structure of the atmosphere. The simultaneous \\OI observations were then employed to determine the abundance of oxygen at each pixel, using both LTE and non-LTE (NLTE) approaches to the radiative transfer. In this manner, we obtain values of \\lgEO=8.63 (NLTE) and 8.93 (LTE) dex. We find an unsettling fluctuation of the oxygen abundance over the field of view. This is likely an artifact indicating that, even with this relatively refined strategy, important physical ingredients are still missing in the picture. By examining the spatial distribution of the abundance, we estimate realistic confidence limits of approximately 0.1 dex.

H. Socas-Navarro A. A. Norton

2007-02-06T23:59:59.000Z

382

Evolution of Photosynthesis and Biospheric Oxygenation Contingent Upon Nitrogen Fixation?  

E-Print Network [OSTI]

How photosynthesis by Precambrian cyanobacteria oxygenated Earth's biosphere remains incompletely understood. Here it is argued that the oxic transition, which took place between approximately 2.3 and 0.5 Gyr ago, required a great proliferation of cyanobacteria, and this in turn depended on their ability to fix nitrogen via the nitrogenase enzyme system. However, the ability to fix nitrogen was not a panacea, and the rate of biospheric oxygenation may still have been affected by nitrogen constraints on cyanobacterial expansion. Evidence is presented for why cyanobacteria probably have a great need for fixed nitrogen than other prokaryotes, underscoring the importance of their ability to fix nitrogen. The connection between nitrogen fixation and the evolution of photosynthesis is demonstrated by the similarities between nitrogenase and enzymes critical for the biosynthesis of (bacterio)chlorophyll. It is hypothesized that biospheric oxygenation would not have occurred if the emergence of cyanobacteria had not been preceded by the evolution of nitrogen fixation, and if these organisms had not also acquired the ability to fix nitrogen at the beginning of or very early in their history. The evolution of nitrogen fixation also appears to have been a precondition for the evolution of (bacterio)chlorophyll-based photosynthesis. Given that some form of chlorophyll is obligatory for true photosynthesis, and its light absorption and chemical properties make it a "universal pigment," it may be predicted that the evolution of nitrogen fixation and photosynthesis are also closely linked on other Earth- like planets.

John W. Grula

2006-05-12T23:59:59.000Z

383

Oxygen production and carbon sequestration in an upwelling coastal Burke Hales,1  

E-Print Network [OSTI]

Oxygen production and carbon sequestration in an upwelling coastal margin Burke Hales,1 Lee Karp), Oxygen production and carbon sequestration in an upwelling coastal margin, Global Biogeochem. Cycles, 20 of particulate organic carbon (POC) and dissolved O2 during the upwelling season off the Oregon coast. Oxygen

Pierce, Stephen

384

Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles  

DOE Patents [OSTI]

A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs.

Cassano, Anthony A. (Allentown, PA)

1985-01-01T23:59:59.000Z

385

Interaction of CO2 with Oxygen Adatoms on Rutile TiO2(110). ...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CO2 with Oxygen Adatoms on Rutile TiO2(110). Interaction of CO2 with Oxygen Adatoms on Rutile TiO2(110). Abstract: The interactions of CO2 with oxygen adatoms (Oa’s) on...

386

INTERNATIONAL CONGRESS OF THE AERONAUTICAL SCIENCES Hypersonic flows of argon, nitrogen, oxygen,  

E-Print Network [OSTI]

, nitrogen, oxygen, and carbon dioxide near a toroidal ballute have been investigated numerically using of nitrogen, dissociating oxygen, argon, and carbon dioxide at 8R H 2R and the Knudsen number Kn D from 02G code [12]. Collisions in nitrogen, argon, oxygen, and carbon dioxide are modeled using

Riabov, Vladimir V.

387

The Effect of Bicarbonate on Photosynthetic Oxygen Evolution in Flashing Light in Chloroplast Fragments  

E-Print Network [OSTI]

been resupplied. However, the final oxygen-evolving reac- tion after the accumulation of four positive of HCO3- in the Hill reaction indicates that this ion plays a critical role in the oxygen- evolving mechanism (1-3). Evidence is available that strongly suggests that HC03- acts on the oxygen-evolving side

Govindjee

388

J. theor. Biol. (1972) 36,427-446 JCinetic Models of Oxygen Evolution in Photosydhesis~  

E-Print Network [OSTI]

reaction center, but in it, each oxygen evolving site has two bound reaction centers II. This alternate that involve the accumulation of two or four positive charges before oxygen is evolved. In order to explain models have been proposed here that equally well explain the data. In the 6rst one, oxygen can be evolved

Govindjee

389

Oxygen production by molten alkali metal salts using multiple absorption-desorption cycles  

DOE Patents [OSTI]

A continuous chemical air separation is performed wherein oxygen is recovered with a molten alkali metal salt oxygen acceptor in a series of absorption zones which are connected to a plurality of desorption zones operated in separate parallel cycles with the absorption zones. A greater recovery of high pressure oxygen is achieved at reduced power requirements and capital costs. 3 figs.

Cassano, A.A.

1985-07-02T23:59:59.000Z

390

Oxygen Transport from the Outer Boundary of a Pulsating Arteriole Wall to the  

E-Print Network [OSTI]

Oxygen Transport from the Outer Boundary of a Pulsating Arteriole Wall to the Surrounding Tissue In all living organisms, oxygen transport from arterioles to the surrounding tissue is critical for survival. However, the exact nature of the transport of oxygen from the arteriole to the surrounding tissue

Salamon, Peter

391

The Rise of Oxygen over the Past 205 Million Years and the Evolution  

E-Print Network [OSTI]

The Rise of Oxygen over the Past 205 Million Years and the Evolution of Large Placental Mammals to the present, we modeled oxygen concentrations over the past 205 million years. Our analysis indicates that atmospheric oxygen approximately doubled over this period, with rela- tively rapid increases in the early

392

Surface Science 425 (1999) 114 Non-adiabatic charge transfer process of oxygen on  

E-Print Network [OSTI]

Surface Science 425 (1999) 1­14 Non-adiabatic charge transfer process of oxygen on metal surfaces November 1998 Abstract The dynamics of charge transfer processes of oxygen on metal surfaces a different charged oxygen species. Empirical universal potential energy functions have been constructed

Zeiri, Yehuda

393

Chemical oxygen diffusion coefficient measurement by conductivity relaxation--correlation between tracer diffusion  

E-Print Network [OSTI]

Chemical oxygen diffusion coefficient measurement by conductivity relaxation--correlation between J. P., Grenier J. C., Loup J. P. ABSTRACT Chemical oxygen diusion coecient ¯(D)was measured the oxygen partial pressure in the surrounding atmosphere of the sample. The consequent evolution

Paris-Sud XI, Université de

394

Oxygen diffusion and reactions in Hf-based dielectrics L. V. Goncharova,a  

E-Print Network [OSTI]

Oxygen diffusion and reactions in Hf-based dielectrics L. V. Goncharova,a M. Dalponte, D. G Oxygen transport in and reactions with thin hafnium oxide and hafnium silicate films have been. The exchange rate is faster for pure hafnium oxides than for silicates. The amount of exchanged oxygen

Gustafsson, Torgny

395

INTRODUCTION A general problem for all animals is the supply of oxygen to  

E-Print Network [OSTI]

INTRODUCTION A general problem for all animals is the supply of oxygen to internal tissues. The common structural solution is formation of a branched tubular network that transports air or oxygenated (respiratory) system, fine branches ramify on or near the oxygen-requiring tissues, with the extent

Krasnow, Mark A.

396

Oxygen and Nitroaen Contamination During Submerged Arc Wel ding of Titanium  

E-Print Network [OSTI]

) ) ) ··- -~ Oxygen and Nitroaen Contamination During Submerged Arc Wel ding of Titanium T· \\v· Eagar* The oxygen content of ti tanium submerged arc wel ~ metal is primaril y derendent uron the purity of the fluo1~ ide fluxes, but it is shown here that the oxygen content of the weld metal may be affected

Eagar, Thomas W.

397

Oxygen: A Fundamental Property Regulating Pelagic Ecosystem Structure in the Coastal Southeastern Tropical  

E-Print Network [OSTI]

Oxygen: A Fundamental Property Regulating Pelagic Ecosystem Structure in the Coastal Southeastern questions about the role of temperature. Here we investigate the role of oxygen in structuring fish that the distribution of oxygen in the ocean is changing with uncertain consequences. Methodology/Principal Findings

398

Supplemental Oxygen and Mountaineer Death Rates on Everest and K2  

E-Print Network [OSTI]

Supplemental Oxygen and Mountaineer Death Rates on Everest and K2 To the Editor: The use of supplemental oxygen by Hima- layan mountaineers has been debated for more than 8 de- cades.1 Although sometimes viewed as unsporting, supplemen- tal-oxygen use may improve survival rates by increasing performance

Huey, Raymond B.

399

Atomic oxygen in solid deuterium A. V. Danilychev and V. A. Apkarian*  

E-Print Network [OSTI]

Atomic oxygen in solid deuterium A. V. Danilychev and V. A. Apkarian* Department of Chemistry 113, Japan Submitted June 8, 2000 Fiz. Nizk. Temp. 26, 909­917 September­October 2000 Atomic oxygen is photogenerated in solid D2 by 193 nm irradiation of samples initially doped with molecular oxygen. The atoms

Apkarian, V. Ara

400

Oxygen as a control on seafloor biological communities and their roles in sedimentary carbon cycling  

E-Print Network [OSTI]

Oxygen as a control on seafloor biological communities and their roles in sedimentary carbon experiments were conducted at sites spanning the steep oxygen, organic matter, and biological community gradients across the Arabian Sea oxygen minimum zone, in order to quantify the role that fauna play

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Dissolved oxygen stratification in two micro-tidal partially-mixed estuaries  

E-Print Network [OSTI]

Dissolved oxygen stratification in two micro-tidal partially-mixed estuaries Jing Lin a,*, Lian Xie online 21 August 2006 Abstract The controlling physical factors for vertical oxygen stratification that vertical stratification of dissolved oxygen (DO) concentration can be explained by the extended Hansen

Mallin, Michael

402

Oxygen driven reconstruction dynamics of Ni,,977... measured by time-lapse scanning tunneling microscopy  

E-Print Network [OSTI]

Oxygen driven reconstruction dynamics of Ni,,977... measured by time-lapse scanning tunneling-lapse scanning tunneling microscopy STM has been used to observe the oxygen induced reconstruction behavior of Ni for the merging of steps in the presence of small amounts of adsorbed oxygen, less than 2% of a monolayer. Point

Sibener, Steven

403

Oxygen chemisorption on Au nanoparticles A. Franceschetti a,b,*, S.J. Pennycook b  

E-Print Network [OSTI]

Oxygen chemisorption on Au nanoparticles A. Franceschetti a,b,*, S.J. Pennycook b , S.T. Pantelides; in final form 11 March 2003 Abstract Oxygen molecules do not adsorb on flat gold surfaces at room temperature, but recent experimental results have demonstrated adsorption of oxygen on small, negatively

Pennycook, Steve

404

Oxygen isotopic disequilibrium in plagioclasecorundumhercynite xenoliths from the Voisey's Bay Intrusion, Labrador, Canada  

E-Print Network [OSTI]

Oxygen isotopic disequilibrium in plagioclase­corundum­hercynite xenoliths from the Voisey's Bay to skeletal. Ion microprobe analyses indicate that oxygen isotopic equilibrium was neither established during corundum is characterized by 18 O values between 2.5 and 7.6. Oxygen isotopic equilibration with mantle

405

OXYGEN GAS-PHASE ABUNDANCE REVISITED M. K. Andre,1,2  

E-Print Network [OSTI]

OXYGEN GAS-PHASE ABUNDANCE REVISITED M. K. Andre´,1,2 C. M. Oliveira,2 J. C. Howk,2 R. Ferlet,1 J gas-phase oxygen abundance along the sight lines toward 19 early-type Galactic stars at an average mag�1 with a standard deviation of 15% is consistent with previous surveys. The mean oxygen abundance

Howk, Jay Christopher

406

Oxygen Isotope Effects as Probes of Electron Transfer Mechanisms and Structures of  

E-Print Network [OSTI]

Oxygen Isotope Effects as Probes of Electron Transfer Mechanisms and Structures of Activated O2, Maryland 21218 RECEIVED ON JULY 26, 2008 C O N S P E C T U S Competitively determined oxygen (18 O) isotope effects can be power- ful probes of chemical and biological transformations involving molec- ular oxygen

Roth, Justine P.

407

Movement of oxygen vacancies in oxide film during annealing observed by an optical reflectivity difference technique  

E-Print Network [OSTI]

Movement of oxygen vacancies in oxide film during annealing observed by an optical reflectivity. The growth and annealing of the film in vacuum and in oxygen ambient are monitored in real time by an oblique tell whether the oxygen vacancies are moving into or moving out of the film during the annealing

Zhu, Xiangdong

408

Movement of oxygen from the atmosphere to the mitochondria occurs via several convective and diffusive steps  

E-Print Network [OSTI]

4111 Movement of oxygen from the atmosphere to the mitochondria occurs via several convective and diffusive steps (Weibel et al., 1981). In mammals, maximal rate of oxygen consumption (VOmax) is not limited by any one step of the oxygen cascade; rather limitations to VOmax are distributed across all steps

Bennett, Albert F.

409

Singlet oxygen generation using iodinated squaraine and squaraine-rotaxane dyesw  

E-Print Network [OSTI]

Singlet oxygen generation using iodinated squaraine and squaraine-rotaxane dyesw Easwaran Arunkumar-rotaxanes to generate singlet oxygen for potential application in photodynamic therapy (PDT). Specifically, we compare-to-face orientations in the solid state. Singlet oxygen generation efficiency was measured by trapping with 1

Smith, Bradley D.

410

The impact of oxygen on the transcriptome of recombinant S. cerevisiae and P. pastoris - a comparative analysis  

E-Print Network [OSTI]

wise comparisons between oxygen set-points, considering a p-= hypoxic vs. normoxic; HvL = hypoxic vs. oxygen-limited;LvN = oxygen-limited vs. normoxic; Cont = control strain;

2011-01-01T23:59:59.000Z

411

Evaluating low oxygen and pH variation and its effects on invertebrate early life stages on upwelling margins /  

E-Print Network [OSTI]

variability of dissolved oxygen and pH in a nearshoreSAN DIEGO Evaluating low oxygen and pH variation and itsof carbonate chemistry, oxygen saturation, and temperature.

Frieder, Christina A.

2013-01-01T23:59:59.000Z

412

Ambiguities of the Rate of Oxygen Formation During Stellar Helium Burning in the 12C(a,g) Reaction  

E-Print Network [OSTI]

The rate of oxygen formation determines the C/O ratio during stellar helium burning. It is the single most important nuclear input of stellar evolution theory including the evolution of Type II and Type Ia supernova. Yet the low energy cross section of the fusion of 4He + 12C denoted as the 12C(a,g)16O reaction still remains uncertain after forty years of extensive work. We analyze and critically review the most recent measurements of complete angular distributions of the outgoing gamma-rays at very low energies (Ecm > 1.0 MeV). Our analysis of the angular distribution measured with the EUROGAM/GANDI arrays lead us to conclude considerably larger error bars than published hence they are excluded from the current sample of "world data". We show that the current sample of "world data" of the measured E2 cross section factors below 1.7 MeV cluster to two distinct groups that lead to two distinct extrapolations of SE2(300) ~ 60 or ~ 154 keVb. We point to a much neglected discrepancy between the measured E1-E2 phase difference (phi_12) and unitarity as required by the Watson theorem, suggesting systematic problem(s) of some of the measured gamma-ray angular distributions. The ambiguity of the extrapolated SE2(300) together with a previously observed ambiguity of SE1(300) represent the current state of the art of the field and they must be resolved by future measurements of complete and detailed angular distributions of the 12C(a,g) reaction at very low energies (Ecm < 1.0 MeV).

Moshe Gai

2013-11-05T23:59:59.000Z

413

Thermochemical Modeling of the Uranium-Cerium-Oxygen System  

SciTech Connect (OSTI)

The objective of the Fuel Cycle R&D Program, Advanced Fuels campaign is to provide the research and development necessary to develop low loss, high quality nuclear fuels for ultra-high burnup reactor operation. Primary work in this area will be focused on the ceramic and metallic fuel systems. The goal of the current work is to enhance the understanding of ceramic nuclear fuel thermochemistry to support fuel research and development efforts. The thermochemical behavior of oxide nuclear fuel under irradiation is dependent on the oxygen to metal ratio (O:M). In fluorite-structured fuel, the actinide metal cation is bonded with {approx}2 oxygen atoms on a crystal lattice and as the metal atoms fission, fission fragments and free oxygen are created. The resulting fission fragments will contain some oxide forming elements, however these are insufficient to bind to all the liberated oxygen and therefore, there is an average increase in O:M with fuel burnup. Some of the fission products also form species that will migrate to and react with the cladding surface in a phenomenon known as Fuel Clad Chemical Interaction (FCCI). Cladding corrosion is life-limiting so it is desirable to understand influencing factors, such as oxide thermochemistry, which can be used to guide the design and fabrication of higher burn up fuel. A phased oxide fuel thermochemical model development effort is underway within the Advanced Fuels Campaign. First models of binary oxide systems are developed. For nuclear fuel system this means U-O and transuranic systems such as Pu-O, Np-O and Am-O. Next, the binary systems will be combined to form pseudobinary systems such as U-Pu-O, etc. The model development effort requires the use of data to allow optimization based on known thermochemical parameters as a function of composition and temperature. Available data is mined from the literature and supplemented by experimental work as needed. Due to the difficulty of performing fuel fabrication development with actinide materials, fundamental studies with uranium are performed using surrogate materials as stand-ins for transuranic elements. In most cases, cerium can be used as a suitable substitute for plutonium when performing O:M and sintering kinetics studies because of identical valence states. Differences exist between the magnitude of reported thermodynamic data of (U,Pu)O{sub x} and (U,Ce)O{sub x}, however the change in oxygen potential versus O:M follows the same trend for both systems. Cerium is also a major fission product element, and thus understanding its behavior in fuel is an important issue as well.

Voit, Stewart L [ORNL; Besmann, Theodore M [ORNL

2010-10-01T23:59:59.000Z

414

Oxygen and Nitrogen in Leo A and GR 8  

E-Print Network [OSTI]

We present elemental abundances for multiple HII regions in Leo A and GR 8 obtained from long slit optical spectroscopy of these two nearby low luminosity dwarf irregular galaxies. As expected from their luminosities, and in agreement with previous observations, the derived oxygen abundances are extremely low in both galaxies. High signal-to-noise ratio observations of a planetary nebula in Leo A yield 12 + log(O/H) = 7.30 +/- 0.05; "semi-empirical" calculations of the oxygen abundance in four HII regions in Leo A indicate 12 + log(O/H) = 7.38 +/- 0.10. These results confirm that Leo A has one of the lowest ISM metal abundances of known nearby galaxies. Based on results from two HII regions with high signal-to-noise measurements of the weak [O III] 4363 line, the mean oxygen abundance of GR 8 is 12 + log(O/H) = 7.65 +/- 0.06; using "empirical" and "semi-empirical" methods, similar abundances are derived for 6 other GR 8 HII regions. Similar to previous results in other low metallicity galaxies, the mean log(N/O) = -1.53 +/- 0.09 for Leo A and -1.51 +/- 0.07 for GR 8. There is no evidence of significant variations in either O/H or N/O in the HII regions. The metallicity-luminosity relation for nearby (D oxygen abundances has a mean correlation of 12 + log(O/H) = 5.67 - 0.151 M_B with a dispersion in oxygen about the relationship of 0.21. These observations confirm that gas-rich low luminosity galaxies have extremely low elemental abundances in the ionized gas-phase of their interstellar media. Although Leo A has one of the lowest metal abundances of known nearby galaxies, detection of tracers of an older stellar population indicate that it is not a newly formed galaxy as has been proposed for some other similarly low metallicity star forming galaxies.

L. van Zee; E. D. Skillman; M. P. Haynes

2005-09-22T23:59:59.000Z

415

The photospheric solar oxygen project: II. Non-concordance of the oxygen abundance derived from two forbidden lines  

E-Print Network [OSTI]

In the Sun, the two forbidden [OI] lines at 630 and 636 nm were previously found to provide discrepant oxygen abundances. aims: We investigate whether this discrepancy is peculiar to the Sun or whether it is also observed in other stars. method: We make use of high-resolution, high signal-to-noise ratio spectra of four dwarf to turn-off stars, five giant stars, and one sub-giant star observed with THEMIS, HARPS, and UVES to investigate the coherence of the two lines. results: The two lines provide oxygen abundances that are consistent, within observational errors, in all the giant stars examined by us. On the other hand, for the two dwarf stars for which a measurement was possible, for Procyon, and for the sub-giant star Capella, the 636 nm line provides systematically higher oxygen abundances, as already seen for the Sun. conclusions: The only two possible reasons for the discrepancy are a serious error in the oscillator strength of the NiI line blending the 630 nm line or the presence of an unknown blend in...

Caffau, Elisabetta; Malherbe, Jean-M; Bonifacio, Piercarlo; Steffen, Matthias; Monaco, Lorenzo

2013-01-01T23:59:59.000Z

416

Oxygen-Consuming Chlor-Alkali Cell Configured To Minimize Peroxide  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen-Consuming Chlor-Alkali Cell Oxygen-Consuming Chlor-Alkali Cell Oxygen-Consuming Chlor-Alkali Cell Configured To Minimize Peroxide Formation Oxygen-consuming zero gap chlor-alkali cell was configured to minimize peroxide formation. Available for thumbnail of Feynman Center (505) 665-9090 Email Oxygen-Consuming Chlor-Alkali Cell Configured To Minimize Peroxide Formation Oxygen-consuming zero gap chlor-alkali cell was configured to minimize peroxide formation. The cell included an ion-exchange membrane that divided the cell into an anode chamber including an anode and a cathode chamber including an oxygen gas diffusion cathode. The cathode included a single-piece of electrically conducting graphitized carbon cloth. Catalyst and polytetrafluoroethylene were attached to only one side of the cloth.

417

Oxygen transport membrane system and method for transferring heat to catalytic/process reactors  

DOE Patents [OSTI]

A method and apparatus for producing heat used in a synthesis gas production is provided. The disclosed method and apparatus include a plurality of tubular oxygen transport membrane elements adapted to separate oxygen from an oxygen containing stream contacting the retentate side of the membrane elements. The permeated oxygen is combusted with a hydrogen containing synthesis gas stream contacting the permeate side of the tubular oxygen transport membrane elements thereby generating a reaction product stream and radiant heat. The present method and apparatus also includes at least one catalytic reactor containing a catalyst to promote the stream reforming reaction wherein the catalytic reactor is surrounded by the plurality of tubular oxygen transport membrane elements. The view factor between the catalytic reactor and the plurality of tubular oxygen transport membrane elements radiating heat to the catalytic reactor is greater than or equal to 0.5.

Kelly, Sean M; Kromer, Brian R; Litwin, Michael M; Rosen, Lee J; Christie, Gervase Maxwell; Wilson, Jamie R; Kosowski, Lawrence W; Robinson, Charles

2014-01-07T23:59:59.000Z

418

Interaction of mineral matter of coal with oxygen carriers in chemical-looping combustion (CLC)  

Science Journals Connector (OSTI)

Abstract The chemical-looping combustion (CLC) and chemical-looping with oxygen uncoupling (CLOU) processes are novel solutions for efficient combustion with direct separation of carbon dioxide. These processes use a metal oxide as an oxygen carrier to transfer oxygen from an air to a fuel reactor, where the fuel reacts with the solid oxygen carrier. When utilizing coal in CLC, the oxygen carrier particles could be affected through interaction with the ash-forming mineral matter found in coal, causing deactivation and/or agglomeration. In this work, possible interactions between minerals commonly encountered in coal and several promising oxygen carriers that are currently under investigation for their use in CLC are studied by both experiment and thermodynamic equilibrium calculations. Possible interaction was studied for both highly reducing and oxidizing conditions at 900 °C. Under highly reducing conditions pyrite was found to have by far the most deteriorating effect on the oxygen carrier particles, as the sulfur in the pyrite reacted with the oxygen carrier to form sulfides. Quartz and clay minerals were found to have a rather low influence on the oxygen carriers. Out of the oxygen carriers investigated, CuO/MgAl2O4 and the Mn3O4/ZrO2 oxygen carriers tended to be quite reactive towards mineral matter whereas ilmenite has been shown to be the most robust oxygen carrier. Although sulfur can clearly deactivate Ni, Cu and Mn based oxygen carriers under sub-stoichiometric conditions, when the fuel is converted fully to CO2 and H2O, sulfides are only expected for Ni-based oxygen carriers.

Martin Keller; Mehdi Arjmand; Henrik Leion; Tobias Mattisson

2014-01-01T23:59:59.000Z

419

Bimetallic Fe–Ni Oxygen Carriers for Chemical Looping Combustion  

Science Journals Connector (OSTI)

(2-4) In CLC (schematic in Figure 1), a fuel is combusted in a fuel reactor (“reducer”) in contact with an oxygen carrier (typically a metal oxide). ... After combustion of the fuel, the reduced metal is then transferred to the air reactor (“oxidizer”) where it is reoxidized by air, and then circulated back to the reducer to close the material “loop”. ... Son, S. R.; Kim, S. D.Chemical-looping combustion with NiO and Fe2O3 in a thermobalance and circulating fluidized bed reactor with double loops Ind. Eng. ...

Saurabh Bhavsar; Götz Veser

2013-05-20T23:59:59.000Z

420

Method for providing oxygen ion vacancies in lanthanide oxides  

DOE Patents [OSTI]

A method for desulfurization of fuel gases resulting from the incomplete combustion of sulfur containing hydrocarbons whereby the gases are treated with lanthanide oxides containing large numbers of oxygen-ion vacancies providing ionic porosity which enhances the ability of the lanthanide oxides to react more rapidly and completely with the sulfur in the fuel gases whereby the sulfur in such gases is reduced to low levels suitable for fuels for firing into boilers of power plants generating electricity with steam turbine driven generators, gas turbines, fuel cells and precursors for liquid fuels such as methanol and the like.

Kay, D. Alan R. (4305 Lakeshore Rd., Burlington, CA); Wilson, William G. (820 Harden Dr., Pittsburgh, PA 15229)

1989-12-05T23:59:59.000Z

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Active Oxygen on Au/TiO2 Catalysts DOI: 10.1002/anie.201102062 Active oxygen on a Au/TiO2 catalyst Formation, stability and CO  

E-Print Network [OSTI]

1 Active Oxygen on Au/TiO2 Catalysts DOI: 10.1002/anie.201102062 Active oxygen on a Au/TiO2 are the activation of molecular oxygen, the active site for this reaction step, and the nature of the catalytically active oxygen species present under working conditions.[3;9-15] Stiehl et al. had shown that molecularly

Pfeifer, Holger

422

IN-SITU STUDY OF OXYGEN ISOTOPES IN GRAPHITE FROM L3 CHONDRITES: INDICATIONS FOR OXYGEN ISOTOPIC HETEROGENEITY. S. Mostefaoui1, FJ. Stadermann2, and A. El Goresy1. !Max-  

E-Print Network [OSTI]

IN-SITU STUDY OF OXYGEN ISOTOPES IN GRAPHITE FROM L3 CHONDRITES: INDICATIONS FOR OXYGEN ISOTOPIC in-situ measurements of oxygen isotopes in graphite from the Khohar and Mez6-Madaras (L3) chondrites. Oxygen isotopic measurements were conducted with the Washington University ion microprobe (a modified

423

The Combination of Hydrogen and Oxygen by Electric Discharges  

Science Journals Connector (OSTI)

Combination of hydrogen and oxygen in the Geissler discharge, low-voltage arc and electrodeless discharge.—It was noted that combination ceased to be explosive in equivalent volumes of the two gases at pressures below 3 cm. Logarithmic decrease in pressure was obtained in equivalent volumes in the Geissler discharge for constant current, whereas excess oxygen increased and excess hydrogen decreased the rate of combination, a similar change in rate having been noted by Lind in his alpha-ray experiments.Number of water molecules formed per pair of ions, as function of pressure.—From a consideration of the number of ions present in the Geissler discharge it appears that the number, k, of water molecules formed per pair of ions at the lower pressures is much less than unity, but that it increases with increasing pressure and may approach the value obtained by Lind at somewhat higher pressures. The pressure at which k approximates unity is such that the time between molecular collisions is of the order of magnitude of the life of an excited hydrogen atom. This is consistent with the view that combination may be due to some similar type of excitation produced by a process secondary to ionization.

Rogers D. Rusk

1928-08-01T23:59:59.000Z

424

Commercialization Development of Oxygen Fired CFB for Greenhouse Gas Control  

SciTech Connect (OSTI)

Given that fossil fuel fired power plants are among the largest and most concentrated producers of CO{sub 2} emissions, recovery and sequestration of CO{sub 2} from the flue gas of such plants has been identified as one of the primary means for reducing anthropogenic (i.e., man-made) CO{sub 2} emissions. In 2001, ALSTOM Power Inc. (ALSTOM) began a two-phase program to investigate the feasibility of various carbon capture technologies. This program was sponsored under a Cooperative Agreement from the US Department of Energy's National Energy Technology Laboratory (DOE). The first phase entailed a comprehensive study evaluating the technical feasibility and economics of alternate CO{sub 2} capture technologies applied to Greenfield US coal-fired electric generation power plants. Thirteen cases, representing various levels of technology development, were evaluated. Seven cases represented coal combustion in CFB type equipment. Four cases represented Integrated Gasification Combined Cycle (IGCC) systems. Two cases represented advanced Chemical Looping Combined Cycle systems. Marion, et al. reported the details of this work in 2003. One of the thirteen cases studied utilized an oxygen-fired circulating fluidized bed (CFB) boiler. In this concept, the fuel is fired with a mixture of oxygen and recirculated flue gas (mainly CO{sub 2}). This combustion process yields a flue gas containing over 80 percent (by volume) CO{sub 2}. This flue gas can be processed relatively easily to enrich the CO{sub 2} content to over 96 percent for use in enhanced oil or gas recovery (EOR or EGR) or simply dried for sequestration. The Phase I study identified the O{sub 2}-fired CFB as having a near term development potential, because it uses conventional commercial CFB technology and commercially available CO{sub 2} capture enabling technologies such as cryogenic air separation and simple rectification or distillation gas processing systems. In the long term, air separation technology advancements offer significant reductions in power requirements, which would improve plant efficiency and economics for the oxygen-fired technology. The second phase consisted of pilot-scale testing followed by a refined performance and economic evaluation of the O{sub 2} fired CFB concept. As a part of this workscope, ALSTOM modified its 3 MW{sub th} (9.9 MMBtu/hr) Multiuse Test Facility (MTF) pilot plant to operate with O{sub 2}/CO{sub 2} mixtures of up to 70 percent O{sub 2} by volume. Tests were conducted with coal and petroleum coke. The test objectives were to determine the impacts of oxygen firing on heat transfer, bed dynamics, potential agglomeration, and gaseous and particulate emissions. The test data results were used to refine the design, performance, costs, and economic models developed in Phase-I for the O{sub 2}-fired CFB with CO{sub 2} capture. Nsakala, Liljedahl, and Turek reported results from this study in 2004. ALSTOM identified several items needing further investigation in preparation for large scale demonstration of the oxygen-fired CFB concept, namely: (1) Operation and performance of the moving bed heat exchanger (MBHE) to avoid recarbonation and also for cost savings compared to the standard bubbling fluid bed heat exchanger (FBHE); (2) Performance of the back-end flash dryer absorber (FDA) for sulfur capture under high CO{sub 2}/high moisture flue gas environment using calcined limestone in the fly ash and using fresh commercial lime directly in the FDA; (3) Determination of the effect of recarbonation on fouling in the convective pass; (4) Assessment of the impact of oxygen firing on the mercury, other trace elements, and volatile organic compound (VOC) emissions; and (5) Develop a proposal-level oxygen-fired retrofit design for a relatively small existing CFB steam power plant in preparation for a large-scale demonstration of the O{sub 2} fired CFB concept. Hence, ALSTOM responded to a DOE Solicitation to address all these issues with further O{sub 2} fired MTF pilot testing and a subsequent retrofit design study of oxygen firing and CO{s

Nsakala ya Nsakala; Gregory N. Liljedahl; David G. Turek

2007-03-31T23:59:59.000Z

425

Donor levels of the divacancy-oxygen defect in silicon  

SciTech Connect (OSTI)

The elimination of divacancies (V{sub 2}) upon isochronal and isothermal annealing has been studied in oxygen-rich p-type silicon by means of deep level transient spectroscopy (DLTS) and high resolution Laplace DLTS. Divacancies were introduced into the crystals by irradiation with 4 or 6?MeV electrons. The temperature range of the divacancy disappearance was found to be 225-300?°C upon 30 min isochronal annealing in the samples studied. A clear anti-correlation between the disappearance of V{sub 2} and the appearance of two hole traps with activation energies for hole emission of 0.23?eV and 0.08?eV was observed. It is argued that these traps are related to the first and second donor levels of the divacancy-oxygen (V{sub 2}O) complex, respectively. Significant electric field enhancement of the hole emission from the second donor level of the V{sub 2}O center occurred in the diodes studied. It is shown that in the range of electric field from 4?×?10{sup 3} to 1.2?×?10{sup 4}?V/cm the emission enhancement is associated with phonon-assisted tunnelling.

Markevich, V. P., E-mail: V.Markevich@manchester.ac.uk; Peaker, A. R.; Hamilton, B. [Photon Science Institute, the University of Manchester, Manchester M13 9PL (United Kingdom); Lastovskii, S. B.; Murin, L. I. [Scientific-Practical Materials Research Center of NAS of Belarus, Minsk 220072 (Belarus)

2014-01-07T23:59:59.000Z

426

DIRECT OXYGEN ABUNDANCES FOR LOW-LUMINOSITY LVL GALAXIES  

SciTech Connect (OSTI)

We present MMT spectroscopic observations of H II regions in 42 low luminosity galaxies in the Spitzer Local Volume Legacy survey. For 31 of the 42 galaxies in our sample, we were able to measure the temperature sensitive [O III] {lambda}4363 line at a strength of 4{sigma} or greater, and thus determine oxygen abundances using the 'direct' method. Our results provide the first 'direct' estimates of oxygen abundance for 19 of these galaxies. 'Direct' oxygen abundances were compared to B-band luminosities, 4.5 {mu}m luminosities, and stellar masses in order to characterize the luminosity-metallicity and mass-metallicity relationships at low luminosity. We present and analyze a 'Combined Select' sample composed of 38 objects (drawn from a sub-set of our parent sample and the literature) with 'direct' oxygen abundances and reliable distance determinations (based on the tip of the red giant branch or Cepheid variables). Consistent with previous studies, the B band and 4.5 {mu}m luminosity-metallicity relationships for the 38 objects were found to be 12 + log(O/H) = (6.27 {+-} 0.21) + (- 0.11 {+-} 0.01)M{sub B} and 12 + log(O/H) = (6.10 {+-} 0.21) + (- 0.10 {+-} 0.01)M{sub [4.5]} with dispersions of {sigma} = 0.15 and 0.14, respectively. The slopes of the optical and near-IR L-Z relationships have been reported to be different for galaxies with luminosities greater than that of the LMC. However, the similarity of the slopes of the optical and near-IR L-Z relationships for our sample probably reflects little influence by dust extinction in the low luminosity galaxies. For this sample, we derive a mass-metallicity relationship of 12 + log(O/H) = (5.61 {+-} 0.24) + (0.29 {+-} 0.03)log (M{sub *}), which agrees with previous studies; however, the dispersion ({sigma} = 0.15) is not significantly lower than that of the L-Z relationships. Because of the low dispersions in these relationships, if an accurate distance is available, the luminosity of a low luminosity galaxy is often a better indicator of metallicity than that derived using certain 'strong-line' methods, so significant departures from the L-Z relationships may indicate that caution is prudent in such cases. With these new 'direct' metallicities we also revisit the 70/160 {mu}m color metallicity relationship. Additionally, we examine N/O abundance trends with respect to oxygen abundance and B - V color. We find a positive correlation between N/O ratio and B - V color for 0.05 {approx}< B - V {approx}< 0.75: log (N/O) = (1.18 {+-} 0.9) Multiplication-Sign (B - V) + (- 1.92 {+-} 0.08), with a dispersion of {sigma} = 0.14, which is in agreement with previous studies.

Berg, Danielle A.; Skillman, Evan D. [Institute for Astrophysics, University of Minnesota, 116 Church St. SE, Minneapolis, MN 55455 (United States); Marble, Andrew R.; Engelbracht, Charles W. [Steward Observatory, University of Arizona, 933 N Cherry Ave., Tucson, AZ 85721 (United States); Van Zee, Liese [Astronomy Department, Indiana University, 727 East 3rd Street, Bloomington, IN 47405 (United States); Lee, Janice C. [STScI, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Kennicutt, Robert C. Jr. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom); Calzetti, Daniela [Department of Astronomy, University of Massachusetts, 710 North Pleasant Street, Amherst, MA 01003 (United States); Dale, Daniel A. [Department of Physics and Astronomy, University of Wyoming, 1000 E. University, Laramie, WY 82071 (United States); Johnson, Benjamin D., E-mail: berg@astro.umn.edu, E-mail: skillman@astro.umn.edu, E-mail: cengelbracht@as.arizona.edu, E-mail: amarble@nso.edu, E-mail: vanzee@astro.indiana.edu, E-mail: jlee@stsci.edu, E-mail: calzetti@astro.umass.edu, E-mail: ddale@uwyo.edu, E-mail: johnson@iap.fr [Institut d'Astrophysique de Paris, UMR 7095, 98 bis Bvd Arago, 75014 Paris (France)

2012-08-01T23:59:59.000Z

427

Mycobacterium tuberculosis Lsr2 Is a Global Transcriptional Regulator Required for Adaptation to Changing Oxygen Levels and Virulence  

Science Journals Connector (OSTI)

...containing ambient atmospheric oxygen or in an...However, under atmospheric oxygen, the mutant...oxygen (A), under atmospheric oxygen (~18...were exposed to water, 5-mM H2O2...is critical for recovery from anaerobiosis...to indicate DNA condensation. If Lsr2 was involved...

I. L. Bartek; L. K. Woolhiser; A. D. Baughn; R. J. Basaraba; W. R. Jacobs; Jr.; A. J. Lenaerts; M. I. Voskuil

2014-06-01T23:59:59.000Z

428

Declining Oxygen in the Northeast Pacific* STEPHEN D. PIERCE, JOHN A. BARTH, R. KIPP SHEARMAN, AND ANATOLI Y. EROFEEV  

E-Print Network [OSTI]

Declining Oxygen in the Northeast Pacific* STEPHEN D. PIERCE, JOHN A. BARTH, R. KIPP SHEARMAN a decrease in oceanic dissolved oxygen and a thickening of the oxygen minimum zone, associated with global warming. Comprehensive observational analyses of oxygen decline are chal- lenging, given generally sparse

Pierce, Stephen

429

Influence of oxygen on the interfacial stability of Cu on Co,,0001... thin films Hongmei Wen,1 Matthew Neurock,1,  

E-Print Network [OSTI]

Influence of oxygen on the interfacial stability of Cu on Co,,0001... thin films Hongmei Wen,1 of oxygen, which can impact the quality of film and its properties. Previously we found that oxygen to examine the effects of surface atomic oxygen on the stability of the Cu 111 /Co 0001 interface

Wadley, Haydn

430

Modern Records of Atmospheric Oxygen (O2) from Scripps Institution of  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atmospheric Trace Gases » Oxygen » Modern Records of Atmospheric Oxygen Atmospheric Trace Gases » Oxygen » Modern Records of Atmospheric Oxygen (O2) from Scripps Institution of Oceanography Modern Records of Atmospheric Oxygen (O2) from Scripps Institution of Oceanography Introduction This page provides an introduction and links to records of atmospheric oxygen (O2) concentrations at nine currently active stations. Records since 1989 are available from Scripps Pier and Alert, Alaska, although these are not continuous. Continuous records from seven stations extend back to 1993, and data for the other two stations (Cold Bay, Alaska and Palmer Station, Antarctica) are available back to the mid 1990s. These data are from remote locations or other locations situated so that they represent averages over large portions of the globe rather than local background sources.

431

In situ global method for measurement of oxygen demand and mass transfer  

SciTech Connect (OSTI)

Two aerobic microorganisms, Saccharomycopsis lipolytica and Brevibacterium lactofermentum, have been used in a study of mass transfer and oxygen uptake from a global perspective using a closed gas system. Oxygen concentrations in the gas and liquid were followed using oxygen electrodes, and the results allowed for easy calculation of in situ oxygen transport. The cell yields on oxygen for S. lipolytica and B. lactofermentum were 1.01 and 1.53 g/g respectively. The mass transfer coefficient was estimated as 10 h{sup {minus}1} at 500 rpm for both fermentations. The advantages with this method are noticeable since the use of model systems may be avoided, and the in situ measurements of oxygen demand assure reliable data for scale-up.

Klasson, K.T. [Oak Ridge National Lab., TN (United States). Chemical Technology Div.; Lundbaeck, K.M.O.; Clausen, E.C.; Gaddy, J.L. [Univ. of Arkansas, Fayetteville, AR (United States). Dept. of Chemical Engineering

1997-05-01T23:59:59.000Z

432

Origin of deep subgap states in amorphous indium gallium zinc oxide: Chemically disordered coordination of oxygen  

SciTech Connect (OSTI)

The origin of the deep subgap states in amorphous indium gallium zinc oxide (a-IGZO), whether intrinsic to the amorphous structure or not, has serious implications for the development of p-type transparent amorphous oxide semiconductors. We report that the deep subgap feature in a-IGZO originates from local variations in the oxygen coordination and not from oxygen vacancies. This is shown by the positive correlation between oxygen composition and subgap intensity as observed with X-ray photoelectron spectroscopy. We also demonstrate that the subgap feature is not intrinsic to the amorphous phase because the deep subgap feature can be removed by low-temperature annealing in a reducing environment. Atomistic calculations of a-IGZO reveal that the subgap state originates from certain oxygen environments associated with the disorder. Specifically, the subgap states originate from oxygen environments with a lower coordination number and/or a larger metal-oxygen separation.

Sallis, S.; Williams, D. S. [Materials Science and Engineering, Binghamton University, Binghamton, New York 13902 (United States); Butler, K. T.; Walsh, A. [Center for Sustainable Technologies and Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY (United Kingdom); Quackenbush, N. F. [Department of Physics, Applied Physics, and Astronomy, Binghamton University, Binghamton, New York 13902 (United States); Junda, M.; Podraza, N. J. [Department of Physics and Astronomy, University of Toledo, Toledo, Ohio 43606 (United States); Fischer, D. A.; Woicik, J. C. [Materials Science and Engineering Laboratory, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); White, B. E.; Piper, L. F. J., E-mail: lpiper@binghamton.edu [Department of Physics, Applied Physics, and Astronomy, Binghamton University, Binghamton, New York 13902 (United States); Materials Science and Engineering, Binghamton University, Binghamton, New York 13902 (United States)

2014-06-09T23:59:59.000Z

433

Cerium Oxide Promoted Iron-based Oxygen Carrier for Chemical Looping Combustion  

Science Journals Connector (OSTI)

Cerium Oxide Promoted Iron-based Oxygen Carrier for Chemical Looping Combustion ... It entails the use of an oxygen carrier (OC), usually a metal oxide, to provide oxygen for combusting fuels in a fuel reactor (FR) and then the reoxidization of the OC in a separate air reactor (AR). ... Preprints of Symposia - American Chemical Society, Division of Fuel Chemistry (2004), 49 (2), 815-816 CODEN: PSADFZ; ISSN:1521-4648. ...

Fang Liu; Liangyong Chen; James K. Neathery; Kozo Saito; Kunlei Liu

2014-10-01T23:59:59.000Z

434

Oxygen impurity and microalloying effect in a Zr-based bulk metallic glass alloy  

E-Print Network [OSTI]

Oxygen impurity and microalloying effect in a Zr-based bulk metallic glass alloy C.T. Liu*, M composition Zr­10 at.%Al­5% Ti­17.9% Cu­14.6% Ni (BAM-11) was used to study the effects of oxygen impurities and microalloying on the microstructure and mechanical properties. Oxygen impurity at a level of 3000 appm

Pennycook, Steve

435

E-Print Network 3.0 - accumulate reactive oxygen Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sciences, University of Manitoba Collection: Geosciences 90 Transient Studies of Oxygen Removal Pathways and Catalytic Redox Cycles during NO Decomposition on Cu-ZSM5 Summary: ....

436

Oxygen-Isotope Exchange between CO2 and Solid Ti18O2  

Science Journals Connector (OSTI)

Oxygen-Isotope Exchange between CO2 and Solid Ti18O2 ... Analysis of the isotopic composition of the gases produced has revealed ... ...

Svatopluk Civis?; Martin Ferus; Pavel Kuba?t; Marke?ta Zukalova?; Ladislav Kavan

2011-05-17T23:59:59.000Z

437

Reducible Supports for Ni-based Oxygen Carriers in Chemical Looping Combustion  

Science Journals Connector (OSTI)

Reducible Supports for Ni-based Oxygen Carriers in Chemical Looping Combustion ... Industrial & Engineering Chemistry Research2014 53 (42), 16341-16348 ...

Saurabh Bhavsar; Götz Veser

2013-03-29T23:59:59.000Z

438

Investigation of Chemical Looping Combustion of Coal with CuFe2O4 Oxygen Carrier  

Science Journals Connector (OSTI)

Investigation of Chemical Looping Combustion of Coal with CuFe2O4 Oxygen Carrier ... Industrial & Engineering Chemistry Research2013 52 (5), 1795-1805 ...

Baowen Wang; Rong Yan; Haibo Zhao; Ying Zheng; Zhaohui Liu; Chuguang Zheng

2011-06-15T23:59:59.000Z

439

Nanostructured Oxygen Carriers for Chemical Looping Combustion and Chemical Looping Hydrogen Production.  

E-Print Network [OSTI]

??Chemical looping combustion (CLC) is an emerging technology for clean energy-production. In CLC, an oxygen carrier is periodically oxidized with air and then reduced in… (more)

Solunke, Rahul Dushyantrao

2011-01-01T23:59:59.000Z

440

Radio-frequency induction plasmas at atmospheric pressure: Mixtures of hydrogen, nitrogen, and oxygen with argon  

Science Journals Connector (OSTI)

Numerical calculations are reported which simulate atmospheric-pressure radiofrequency induction plasmas consisting of either pure argon or mixtures of argon with hydrogen, nitrogen, or oxygen. These calculati...

S. L. Girshick; W. Yu

1990-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

More on the solar oxygen abundance Hans-Gunter Ludwig1  

E-Print Network [OSTI]

abundance is "high" or "low", we derived the oxygen solar abundance using 1D as well as 3D CO5BOLD solar

442

Towards forming-free resistive switching in oxygen engineered HfO{sub 2?x}  

SciTech Connect (OSTI)

We have investigated the resistive switching behavior in stoichiometric HfO{sub 2} and oxygen-deficient HfO{sub 2?x} thin films grown on TiN electrodes using reactive molecular beam epitaxy. Oxygen defect states were controlled by the flow of oxygen radicals during thin film growth. Hard X-ray photoelectron spectroscopy confirmed the presence of sub-stoichiometric hafnium oxide and defect states near the Fermi level. The oxygen deficient HfO{sub 2?x} thin films show bipolar switching with an electroforming occurring at low voltages and low operating currents, paving the way for almost forming-free devices for low-power applications.

Sharath, S. U., E-mail: sharath@oxide.tu-darmstadt.de; Kurian, J.; Hildebrandt, E.; Alff, L. [Institute of Materials Science, Technische Universität Darmstadt, Alarich-Weiss-Strasse 2, 64287 Darmstadt (Germany); Bertaud, T.; Walczyk, C.; Calka, P.; Zaumseil, P.; Sowinska, M.; Walczyk, D. [IHP, Im Technologiepark 25, 15236 Frankfurt Oder (Germany); Gloskovskii, A. [Deutsches Elektronen-Synchrotron DESY, Notkestrasse 85, 22607 Hamburg (Germany); Schroeder, T. [IHP, Im Technologiepark 25, 15236 Frankfurt Oder (Germany); Brandenburgische Technische Universität, Konrad-Zuse-Strasse 1, 03046 Cottbus (Germany)

2014-02-10T23:59:59.000Z

443

Impact of ethanol and butanol as oxygenates on SIDI engine efficiency...  

Broader source: Energy.gov (indexed) [DOE]

as oxygenates on SIDI engine efficiency and emissions using steady-state and transient test procedures Thomas Wallner, Neeraj Shidore, Andrew Ickes Argonne National Laboratory 16...

444

Oxygen-resistant hydrogenases and methods for designing and making same  

DOE Patents [OSTI]

The invention provides oxygen-resistant iron-hydrogenases ([Fe]-hydrogenases) for use in the production of H.sub.2. Methods used in the design and engineering of the oxygen-resistant [Fe]-hydrogenases are disclosed, as are the methods of transforming and culturing appropriate host cells with the oxygen-resistant [Fe]-hydrogenases. Finally, the invention provides methods for utilizing the transformed, oxygen insensitive, host cells in the bulk production of H.sub.2 in a light catalyzed reaction having water as the reactant.

King, Paul; Ghirardi, Maria Lucia; Seibert, Michael

2014-03-04T23:59:59.000Z

445

Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique  

Broader source: Energy.gov [DOE]

Presentation slides from the Fuel Cell Technologies Office webinar, Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique, held March 12, 2013.

446

Oxygen-Dependent Morphogenesis of Modern Clumped Photosynthetic Mats and Implications for the Archean Stromatolite Record  

E-Print Network [OSTI]

Some modern filamentous oxygenic photosynthetic bacteria (cyanobacteria) form macroscopic tufts, laminated cones and ridges that are very similar to some Archean and Proterozoic stromatolites. However, it remains unclear ...

Sim, Min Sub

447

E-Print Network 3.0 - arterial blood oxygen Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

are blood vessels (thick, muscular tubes) that carry oxygen-rich blood from the heart... to the rest of the body. Blood pressure (BP) has two measurements: top...

448

E-Print Network 3.0 - anodic oxygen-transfer reactions Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Conversion and Utilization ; Chemistry 7 Electrochimica Acta 52 (2007) 61256140 A two-dimensional, two-phase mass transport model Summary: resistance of oxygen from gas pores...

449

E-Print Network 3.0 - atmospheric pressure helium-oxygen Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Copyright permission to reproduce figures andor text from this article 12;Remote Atmospheric-Pressure... ) were treated with an atmospheric-pressure oxygen and...

450

Effect of oxygen on the high temperature flow and aging behaviour of Zircaloy-2.  

E-Print Network [OSTI]

??The solute strengthening due to oxygen in Zircaloy-2 was investigated over the temperature range 1023 to 1873 K. The flow stress was determined in constant… (more)

Choubey, Rameshwar.

1981-01-01T23:59:59.000Z

451

Kinetics of oxygen reduction at IrO{sub 2}-coated titanium electrode in alkaline solution  

SciTech Connect (OSTI)

Oxygen reduction is an industrially important electrochemical reaction, for fuel cells, electrochemical caustic concentrators, air depolarized cathodes, metal-air batteries, and oxidant production. Oxygen reduction at IrO{sub 2}-coated titanium electrodes fabricated by thermal decomposition was investigated by employing cyclic voltammetry and rotating-disk electrode techniques. Cyclic voltammetric results indicated that oxygen reduction begins during the Ir(III)/Ir(IV) transition on an IrO{sub 2} electrode. On the basis of measurements using a rotating disk electrode together with polarization curves, Tafel slopes, and stoichiometric number determinations, a mechanism for oxygen reduction on an IrO{sub 2}-coated titanium electrode is proposed.

Chang, C.C.; Wen, T.C. [National Cheng Kung Univ., Tainan (Taiwan, Province of China). Dept. of Chemical Engineering

1996-05-01T23:59:59.000Z

452

Webinar: Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique  

Broader source: Energy.gov [DOE]

Video recording of the Fuel Cell Technologies Office webinar, Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique, originally presented on March 12, 2013.

453

Silicon-on-glass pore network micromodels with oxygen-sensing...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Silicon-on-glass pore network micromodels with oxygen-sensing fluorophore films for chemical imaging and defined spatial Silicon-on-glass pore network micromodels with...

454

Oxygen-resistant hydrogenases and methods for designing and making same  

DOE Patents [OSTI]

The invention provides oxygen- resistant iron-hydrogenases ([Fe]-hydrogenases) for use in the production of H2. Methods used in the design and engineering of the oxygen-resistant [Fe]-hydrogenases are disclosed, as are the methods of transforming and culturing appropriate host cells with the oxygen-resistant [Fe]-hydrogenases. Finally, the invention provides methods for utilizing the transformed, oxygen insensitive, host cells in the bulk production of H.sub.2 in a light catalyzed reaction having water as the reactant.

King, Paul (Golden, CO); Ghirardi, Maria L (Lakewood, CO); Seibert, Michael (Lakewood, CO)

2009-03-10T23:59:59.000Z

455

Low oxygen biomass-derived pyrolysis oils and methods for producing the same  

DOE Patents [OSTI]

Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal-based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

Marinangeli, Richard; Brandvold, Timothy A; Kocal, Joseph A

2013-08-27T23:59:59.000Z

456

Detonation engine fed by acetylene–oxygen mixture  

Science Journals Connector (OSTI)

Abstract The advantages of a constant volume combustion cycle as compared to constant pressure combustion in terms of thermodynamic efficiency has focused the search for advanced propulsion on detonation engines. Detonation of acetylene mixed with oxygen in various proportions is studied using mathematical modeling. Simplified kinetics of acetylene burning includes 11 reactions with 9 components. Deflagration to detonation transition (DDT) is obtained in a cylindrical tube with a section of obstacles modeling a Shchelkin spiral; the DDT takes place in this section for a wide range of initial mixture compositions. A modified ka-omega turbulence model is used to simulate flame acceleration in the Shchelkin spiral section of the system. The results of numerical simulations were compared with experiments, which had been performed in the same size detonation chamber and turbulent spiral ring section, and with theoretical data on the Chapman–Jouguet detonation parameters.

N.N. Smirnov; V.B. Betelin; V.F. Nikitin; Yu.G. Phylippov; Jaye Koo

2014-01-01T23:59:59.000Z

457

Oxygen-stabilized zirconium-vanadium-iron alloy  

DOE Patents [OSTI]

An oxygen stabilized intermetallic compound is described which has the formula (Zr/sub 1-x/Ti/sub x/)/sub 2-u/(V/sub 1-y/Fe/sub y/)O/sub z/ where x = 0.0 to 0.9, y = 0.01 to 0.9, z = 0.25 to 0.5 and u = 0 to 1. The compound is capable of reversibly sorbing hydrogen at temperatures from -196/sup 0/C to 200/sup 0/C at pressures down to 10/sup -6/ torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

Mendelsohn, M.H.; Gruen, D.M.

1981-06-16T23:59:59.000Z

458

Oxygen isotope analysis of multiple, single ostracod valves as a proxy for combined variability in seasonal temperature and lake water oxygen isotopes  

Science Journals Connector (OSTI)

Paleoclimate studies in lakes typically use oxygen isotopic ratios in samples that consist of multiple ostracod specimens, to obtain an average ?18O value that reflects the mean temperature and ?18O of lake water...

Yama Dixit; David A. Hodell; Rajiv Sinha; Cameron A. Petrie

2014-10-01T23:59:59.000Z

459

Calorimetric studies of oxygen adsorption on silver powder and of CO and CO/sub 2/ interactions with preadsorbed oxygen on silver  

SciTech Connect (OSTI)

The initial rapid oxygen adsorption on powdered silver ethylene oxidation catalyst had a heat of adsorption that decreased from 70 to 40 kcal/mole as the adsorbed amount increased from 2 to 20 jmole/sq m. The rapid oxygen adsorption covered about one-fourth of the silver surface. Carbon monoxide adsorbed on the oxygen-covered silver with an initial heat of adsorption of 90 kcal/mole which decreased after 0.6 jmole/sq m CO were adsorbed and was approx. 70 kcal/mole at 2 jmole/sq m CO. Carbon dioxide adsorbed on the oxygen-covered surface with 38 kcal/mole heat of adsorption that was independent of coverage. The adsorption study provided evidence for the formation of adsorbed carbonate (CO/sub 3/) surface complexes.

Vass, M.I.; Budrugeac, P.

1980-07-01T23:59:59.000Z

460

Oxygen reduction at the platinum/Nafion{reg_sign} interface: Electrode kinetics and mass transport  

SciTech Connect (OSTI)

Research in solid polymer electrolyte fuel cells is gaining momentum because of the prospects of attaining high energy efficiencies and power densities, essential for transportation and space applications. The most advanced solid polymer electrolytes for these fuel cells are the perfluorosulfonate ionomers (PFSIs) such as duPont`s Naflon and the Dow PFSIs. The high oxygen solubility, chemical stability, proton conductivity and permselectivity exhibited by Naflon and the Dow PFSI`s make them ideal candidates as electrolytes for fuel cells. Furthermore, the minimal anion adsorption on electrodes from fluorinated acids enhances oxygen reduction kinetics. The primary objectives of this work were to determine the concentration and diffusion coefficient of oxygen in Naflon, and the electrode kinetic parameters for the reduction of oxygen at the Pt/Nafion interface under totally solid-state conditions. Cyclic voltammetric and potentiostatic transient measurements were made at the Pt/Nafion interface. Slow sweep voltammograms yielded Tafel parameters for oxygen reduction. From the two-section Tafel, plot, the calculated exchange current densities were found to be higher than those obtained at any other Pt/acid interface. From an analysis of the transients, the values of oxygen solubility and diffusion coefficient in Naflon were determined. Electrochemical impedance spectroscopic (EIS) investigations were then used to study oxygen reduction under lower humidfication conditions. EIS clearly permits the discrimination of electrode kinetics, mass transport of O{sub 2} and the electrical characteristics of the membrane. A temperature-dependence study in the range of 30{degrees}C to 80{degrees}C yielded the activation energy for oxygen reduction at the Pt/Naflon interface. The diffusion coefficient of oxygen in Nafion increases with temperature while its solubility decreases. the pressure-dependence of oxygen reduction kinetics shows that the reaction order of oxygen is unity.

Parthasarathy, A.

1992-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Mercury methylation in oxygen deficient zones of the oceans: No evidence for the predominance of anaerobes  

E-Print Network [OSTI]

Mercury methylation in oxygen deficient zones of the oceans: No evidence for the predominance Keywords: Methylmercury Oxygen minimum zone Arabian Sea Equatorial Eastern Pacific Mercury methylation Although a large fraction of the world's population is exposed to mercury through consumption of marine

Morel, François M. M.

462

Dynamic Model for an Oxygen-Staged Slagging Entrained Flow Gasifier  

Science Journals Connector (OSTI)

The temperature distribution simulation results also showed that staged oxygen feeding can reduce the temperature near the main burner significantly, therefore extending the lifetime of the burner compared with that of without staged oxygen feed. ... Problems such as a short lifetime of burners and refractory walls and fouling and corrosion in syngas coolers have to be addressed in order to further improve the technology. ...

Zhiwei Yang; Zhe Wang; Yuxin Wu; Jihong Wang; Junfu Lu; Zheng Li; Weidou Ni

2011-07-05T23:59:59.000Z

463

Semi-insulating crystalline silicon formed by oxygen doping during low-temperature chemical vapor deposition  

E-Print Network [OSTI]

Semi-insulating crystalline silicon formed by oxygen doping during low-temperature chemical vapor) In this letter we demonstrate the use of oxygen as a dopant in silicon to create semi-insulating, crystalline of the films exhibit classical characteristics of space-charge-limited current associated with insulators

464

Holocene Paleohydrology and Paleoclimate at Treeline, North-Central Russia, Inferred from Oxygen Isotope  

E-Print Network [OSTI]

Holocene Paleohydrology and Paleoclimate at Treeline, North-Central Russia, Inferred from Oxygen Institute for Geography, Russian Academy of Sciences, Staromonetny Pereulok 29, Moscow 109017, Russia, 1998 Lake-water oxygen-isotope histories for three lakes in northern Russia, derived from the cellulose

Edwards, Thomas W.D.

465

Heart Rate and Oxygen Consumption of Northern Elephant Seals during Diving in the Laboratory  

E-Print Network [OSTI]

116 Heart Rate and Oxygen Consumption of Northern Elephant Seals during Diving in the Laboratory Paul M. Webb1 heart rate over the entire dive cycle increased with increasing oxygen consumption in all, which casts some doubt on the usefulness of heart rate as an indicator of metabolicBurney J. Le Boeuf1 1

Webb, Paul M.

466

Evaluation of Novel Ceria-Supported Metal Oxides As Oxygen Carriers for Chemical-Looping Combustion  

E-Print Network [OSTI]

Evaluation of Novel Ceria-Supported Metal Oxides As Oxygen Carriers for Chemical-Looping Combustion and examined as oxygen carrier materials for chemical-looping combustion (CLC). Unlike conventional support agglomeration. 1. INTRODUCTION 1.1. Chemical-Looping Combustion. Chemical-looping combustion (CLC

Azad, Abdul-Majeed

467

Reduction Kinetics of a CasO4 Based Oxygen Carrier for Chemical-Looping Combustion  

Science Journals Connector (OSTI)

The CaSO4...based oxygen carrier has been proposed as an alternative low cost oxygen carrier for Chemical-looping combustion (CLC) of coal. The reduction of...4 to CaS is an important step for the cyclic process ...

R. Xiao; Q. L. Song; W. G. Zheng; Z. Y. Deng…

2010-01-01T23:59:59.000Z

468

Reduction Kinetics of Perovskite-Based Oxygen Carriers for Chemical Looping Combustion  

Science Journals Connector (OSTI)

Reduction Kinetics of Perovskite-Based Oxygen Carriers for Chemical Looping Combustion ... Industrial & Engineering Chemistry Research (1996), 35 (7), 2469-2472 CODEN: IECRED; ISSN:0888-5885. ... NiO particles mixed with yttria-stabilized zirconia have very good properties for the oxygen carrier in the loop with respect to the reaction rate, conversion, and phys. ...

Zahra Sarshar; Serge Kaliaguine

2013-04-25T23:59:59.000Z

469

Regional groundwater flow paths in Trans-Pecos, Texas inferred from oxygen,  

E-Print Network [OSTI]

and hydrogen, oxygen, and strontium isotopes. dD and d18 O values fall close to the global meteoric water lineRegional groundwater flow paths in Trans-Pecos, Texas inferred from oxygen, hydrogen, and strontium isotopes, and major ion chemistry are used to con- strain flow paths in a fracture-controlled regional

Banner, Jay L.

470

Low energy consumption method for separating gaseous mixtures and in particular for medium purity oxygen production  

DOE Patents [OSTI]

A method for the separation of gaseous mixtures such as air and for producing medium purity oxygen, comprising compressing the gaseous mixture in a first compressor to about 3.9-4.1 atmospheres pressure, passing said compressed gaseous mixture in heat exchange relationship with sub-ambient temperature gaseous nitrogen, dividing the cooled, pressurized gaseous mixture into first and second streams, introducing the first stream into the high pressure chamber of a double rectification column, separating the gaseous mixture in the rectification column into a liquid oxygen-enriched stream and a gaseous nitrogen stream and supplying the gaseous nitrogen stream for cooling the compressed gaseous mixture, removing the liquid oxygen-enriched stream from the low pressure chamber of the rectification column and pumping the liquid, oxygen-enriched steam to a predetermined pressure, cooling the second stream, condensing the cooled second stream and evaporating the oxygen-enriched stream in an evaporator-condenser, delivering the condensed second stream to the high pressure chamber of the rectification column, and heating the oxygen-enriched stream and blending the oxygen-enriched stream with a compressed blend-air stream to the desired oxygen concentration.

Jujasz, Albert J. (North Olmsted, OH); Burkhart, James A. (Olmsted Falls, OH); Greenberg, Ralph (New York, NY)

1988-01-01T23:59:59.000Z

471

Reduction Kinetics of Cu-Based Oxygen Carriers for Chemical Looping Air Separation  

Science Journals Connector (OSTI)

Only Sahir et al. performed a rate analysis from the reported batch fluidized bed CLOU experimental data of Mexican petcoke particles by a CuO/ZrO2 oxygen carrier. ... data of Mexican petcoke particles by a CuO/ZrO2 oxygen carrier. ...

Kun Wang; Qingbo Yu; Qin Qin

2013-08-02T23:59:59.000Z

472

Chromatographic and UV-Spectroscopic Properties of Solvated Oxygen in Mixtures of Acetonitrile and Water  

Science Journals Connector (OSTI)

......responds to the solubility of oxygen in toluene...limit, as oxygen solubility decreases with...caused by solvent-gas interactions...are valid for water a n d are in accordance...absorbance of water and acetonitrile...c system, the gas b u b b l e will...volumes of helium or nitrogen are not Figure......

Jo Doehl

1988-01-01T23:59:59.000Z

473

Oxygen affinity and amino acid sequence of myoglobins from endothermic and ectothermic fish  

E-Print Network [OSTI]

that Mb oxygen affinity has evolved such that it is conserved when adjusted for body temperature amongOxygen affinity and amino acid sequence of myoglobins from endothermic and ectothermic fish DAVID J and Conservation Center and Hopkins Marine Station, Stanford University, Pacific Grove, California 93950; 2 Duke

Block, Barbara A.

474

Calculations of Oxygen Stability in Lithium-Rich Layered Cathodes Penghao Xiao,  

E-Print Network [OSTI]

Calculations of Oxygen Stability in Lithium-Rich Layered Cathodes Penghao Xiao, Z. Q. Deng, A ABSTRACT: Oxygen loss can lead to high-capacity Li2MnO3-based lithium- rich layered cathodes. Substitution The stabilized compounds have a similar structure as LiMO2 except that excess Li populates the transition

Henkelman, Graeme

475

Studies of the Di-iron(VI) Intermediate in Ferrate-Dependent Oxygen Evolution from Water  

E-Print Network [OSTI]

Information ABSTRACT: Molecular oxygen is produced from water via the following reaction of potassium ferrateStudies of the Di-iron(VI) Intermediate in Ferrate-Dependent Oxygen Evolution from Water Rupam consumption of natural abundance water. The derived 18 O KIEs provide insights concerning the identity

Roth, Justine P.

476

Coastal Upwelling Supplies Oxygen-Depleted Water to the Columbia River Estuary  

E-Print Network [OSTI]

extent and duration of exposure to low DO water. Strong upwelling during neap tides produced the largestCoastal Upwelling Supplies Oxygen-Depleted Water to the Columbia River Estuary G. Curtis Roegner1 States of America Abstract Low dissolved oxygen (DO) is a common feature of many estuarine and shallow-water

477

Home Monitoring of Oxygen Saturation and Symptoms for Sickle Cell Disease  

E-Print Network [OSTI]

Home Monitoring of Oxygen Saturation and Symptoms for Sickle Cell Disease Introduction and Aims There is evidence that the vaso-occlusive crises and other complications associated with sickle cell disease (SCD oxygen levels and the onset of sickle cell crises. A secondary objective of the study is to investigate

Oakley, Jeremy

478

Ice-free conditions in Sweden during Marine Oxygen Isotope Stage 3? BARBARA WOHLFARTH  

E-Print Network [OSTI]

Ice-free conditions in Sweden during Marine Oxygen Isotope Stage 3? BARBARA WOHLFARTH BOREAS Wohlfarth, B. 2010 (April): Ice-free conditions in Sweden during Marine Oxygen Isotope Stage 3? Boreas, Vol dates for Sweden older than the Last Glacial Maximum ice advance were eval- uated. Acceptable 14 C dates

Wohlfarth, Barbara

479

Oxygen tolerance of an in silico-designed bioinspired hydrogen-evolving catalyst in water  

Science Journals Connector (OSTI)

...highly exothermic. The overall free-energy reduction is 113.9 kcal/mol for the combined O 2...overpotential for oxygen reduction at a fuel-cell cathode . J Phys Chem B 108 : 17886...Overpotential for Oxygen Reduction at a Fuel-Cell cathode. J. Phys Chem B 108...

Patrick H.-L. Sit; Roberto Car; Morrel H. Cohen; Annabella Selloni

2013-01-01T23:59:59.000Z

480

Assessment of Tumor Energy and Oxygenation Status by Bioluminescence, Nuclear Magnetic Resonance Spectroscopy, and Cryospectrophotometry  

Science Journals Connector (OSTI)

...research-article Assessment of Tumor Energy and Oxygenation Status by Bioluminescence...Montebello, 0310 Oslo 3, Norway [E. K. R.]; Experimental...Federal Republic of Germany. The energy and oxygenation status of tumors...independent techniques. Tumor energy metabolism was investigated...

W. Mueller-Klieser; C. Schaefer; S. Walenta; E. K. Rofstad; B. M. Fenton; and R. M. Sutherland

1990-03-15T23:59:59.000Z

Note: This page contains sample records for the topic "gasohol excludes oxygenates" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Chemical looping gasification of solid fuels using bimetallic oxygen carrier particles – Feasibility assessment and process simulations  

Science Journals Connector (OSTI)

Abstract The chemical looping gasification (CLG) process utilizes an iron-based oxygen carrier to convert carbonaceous fuels into hydrogen and electricity while capturing CO2. Although the process has the potential to be efficient and environmentally friendly, the activity of the iron-based oxygen carrier is relatively low, especially for solid fuel conversion. In the present study, we propose to incorporate a secondary oxygen carrying metal oxide, i.e. CuO, to the iron-based oxygen carrier. Using the “oxygen-uncoupling” characteristics of CuO, gaseous oxygen is released at a high temperature to promote the conversion of both Fe2O3 and coal. Experiments carried out using a Thermal-Gravimetric Analyzer (TGA) indicate that a bimetallic oxygen carrier consisting of a small amount (5% by weight) of CuO is more effective for coal char conversion when compared to oxygen carrier without copper addition. ASPEN Plus® simulations and mathematical modeling of the process indicate that the incorporation of a small amount of copper leads to increased hydrogen yield and process efficiency.

Feng He; Nathan Galinsky; Fanxing Li

2013-01-01T23:59:59.000Z

482

A UV light enhanced TiO2/graphene device for oxygen sensing at room temperature  

E-Print Network [OSTI]

A UV light enhanced TiO2/graphene device for oxygen sensing at room temperature Jia Zhang,ab Chao temperature oxygen sensor based on TiO2/graphene device was developed with an enhanced sensing performance­hole pairs in the TiO2 film and the photogenerated electrons were scavenged by graphene and percolated

Cao, Wenwu

483

Hydrogen absorption characteristics of oxygen-stabilized rare-earth iron intermetallic compounds  

E-Print Network [OSTI]

Hydrogen absorption characteristics of oxygen-stabilized rare-earth iron intermetallic compounds M Abstract. -- The thermal behavior of oxygen-stabilized RjFegO^-hydrogen (R = Y, Dy, Ho) systems was studied decade to the study of the hydrogenation characte- ristics of a variety of intermetallic compounds, our

Paris-Sud XI, Université de

484

The performance of PEM fuel cells fed with oxygen through the free-convection mode  

E-Print Network [OSTI]

The performance of PEM fuel cells fed with oxygen through the free-convection mode Pei-Wen Li; accepted 27 September 2002 Abstract The feasibility and restrictions of feeding oxygen to a PEM fuel cell in the fuel cell. Experimental tests were conducted for one PEM fuel cell stack and two single PEM fuel cell

485

The effect of topological defects and oxygen adsorption on the electronic transport properties of  

E-Print Network [OSTI]

The effect of topological defects and oxygen adsorption on the electronic transport properties theory (DFT) calculations of the interactions between isolated infinitely-long semiconducting zig- zag-oxygen adsorption and its effect on electronic transport properties of these SWCNTs. A Green's function method

Grujicic, Mica

486

Dissolved Oxygen for Fish Production1 Ruth Francis-Floyd2  

E-Print Network [OSTI]

be caused by an over-abundance of aquatic plants or algae in the ecosystem, "turnover" of a body of water, political opinions or affiliations. U.S. Department of Agriculture, Cooperative Extension Service) refers to oxygen gas that is dis- solved in water. Fish "breathe" oxygen just as land animals do. However

Watson, Craig A.

487

Flow stress of oxygen-enriched Zircaloy-2 between 1023 and 1873 K  

SciTech Connect (OSTI)

The solute strengthening effect of oxygen in commercial-purity Zircaloy-2 was investigated over the temperature range 1023 to 1873 K, strain rate range 10/sup -4/ to 10/sup -1/s/sup -1/ , and oxygen concentration range 1260 to 12,360 ppm.

Choubey, R.; Holt, R.A.; Ells, C.E.; Jonas, J.J.

1982-01-01T23:59:59.000Z

488

Formation and stability of oxygen-rich bubbles that shape photosynthetic mats  

E-Print Network [OSTI]

Formation and stability of oxygen-rich bubbles that shape photosynthetic mats T. BOSAK,1 J. W. M and stability of oxygen-rich bubbles enmeshed by filamentous cyanobacteria. Sub-millimetric and millimetric bubbles can be stable for weeks and even months. During this time, lithifying organic-rich lami- nae

Bush, John W.M.

489

Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform  

E-Print Network [OSTI]

Alkaline Microfluidic Hydrogen-Oxygen Fuel Cell as a Cathode Characterization Platform Fikile R of hydrogen H2 and oxygen O2 . Operating fuel cells in alkaline media, as opposed to acidic media, has on an alkaline microfluidic fuel cell for catalyst and electrode characterization. Its constantly refreshing

Kenis, Paul J. A.

490

Doped Graphene as a Material for Oxygen Reduction Reaction in Hydrogen Fuel Cells: A Computational Study  

E-Print Network [OSTI]

Doped Graphene as a Material for Oxygen Reduction Reaction in Hydrogen Fuel Cells: A Computational be used to make an efficient and relatively inexpensive graphene-based material for hydrogen fuel cells fuel cells for oxygen reduction at the cathode. In an attempt to find a cheap yet efficient catalyst

Krasheninnikov, Arkady V.

491

Oxygen Plasma Activation of Cr(CO)(6) on ?-Fe2O3(0001)...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oxygen Plasma Activation of Cr(CO)(6) on ?-Fe2O3(0001). Oxygen Plasma Activation of Cr(CO)(6) on ?-Fe2O3(0001). Abstract: The chemistry of Cr(CO)6 on the Fe3O4(111)...

492

15N2 formation and fast oxygen isotope exchange during pulsed...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

N2 formation and fast oxygen isotope exchange during pulsed 15N18O exposure of MnOxCeO2. 15N2 formation and fast oxygen isotope exchange during pulsed 15N18O exposure of MnOx...

493

Oxygen diffusion in titanite: Lattice diffusion and fast-path diffusion in single crystals  

E-Print Network [OSTI]

Oxygen diffusion in titanite: Lattice diffusion and fast-path diffusion in single crystals X June 2006 Editor: P. Deines Abstract Oxygen diffusion in natural and synthetic single-crystal titanite was characterized under both dry and water-present conditions. For the dry experiments, pre-polished titanite

Watson, E. Bruce

494

FISHERY WASTE EFFLUENTS: A METHOD TO DETERMINE RELATIONSHIPS BETWEEN CHEMICAL OXYGEN DEMAND AND RESIDUE  

E-Print Network [OSTI]

FISHERY WASTE EFFLUENTS: A METHOD TO DETERMINE RELATIONSHIPS BETWEEN CHEMICAL OXYGEN DEMAND effluents, especially for total suspended and settleable solids, and oil and grease. The relationship between chemical oxygen demand and residue was determined on a limited number of samples from four types

495

The Paleoproterozoic snowball Earth: A climate disaster triggered by the evolution of oxygenic photosynthesis  

E-Print Network [OSTI]

photosynthesis Robert E. Kopp*, Joseph L. Kirschvink, Isaac A. Hilburn, and Cody Z. Nash Division of Geological biomarker, trace element, and isotopic evidence have been used to claim that oxygenic photosynthesis evolved phases. First, oxygenic photosynthesis evolved and brought into the world locally oxic environments

496

Krypton for Multi-Pane Windows: Selective Absorption of Krypton from Oxygen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Krypton for Multi-Pane Windows: Selective Absorption of Krypton from Oxygen Krypton for Multi-Pane Windows: Selective Absorption of Krypton from Oxygen in an Ionic Liquid Speaker(s): John Prausnitz Waheed Afzal Date: September 18, 2012 - 12:00pm Location: 90-3122 Seminar Host/Point of Contact: Robert Hart Because of its low thermal conductivity, krypton is a useful gas for the vapor space of double- (or triple-) pane windows. However krypton is more expensive than argon, currently used for most of multi-pane windows. The high price of krypton is due to the energy-intensive cryogenic process for its recovery from oxygen that is obtained from air. Ionic liquids may provide a cost-effective absorption process for separation of krypton from the oxygen stream of a liquid-air plant. The polarizability of krypton is higher than that of oxygen; therefore, krypton solubility may be

497

Prolonged cold storage of red blood cells by oxygen removal and additive usage  

DOE Patents [OSTI]

Prolonged cold storage of red blood cells by oxygen removal and additive usage. A cost-effective, 4 C storage procedure that preserves red cell quality and prolongs post-transfusion in vivo survival is described. The improved in vivo survival and the preservation of adenosine triphosphate levels, along with reduction in hemolysis and membrane vesicle production of red blood cells stored at 4 C for prolonged periods of time, is achieved by reducing the oxygen level therein at the time of storage; in particular, by flushing the cells with an inert gas, and storing them in an aqueous solution which includes adenine, dextrose, mannitol, citrate ion, and dihydrogen phosphate ion, but no sodium chloride, in an oxygen-permeable container which is located in an oxygen-free environment containing oxygen-scavenging materials. 8 figs.

Bitensky, M.W.; Yoshida, Tatsuro

1998-08-04T23:59:59.000Z

498

Structure Evolution of Graphene Oxide during Thermally Driven Phase Transformation: Is the Oxygen Content Really Preserved?  

E-Print Network [OSTI]

A mild annealing procedure was recently proposed for the scalable enhancement of graphene oxide (GO) properties with the oxygen content preserved, which was demonstrated to be attributed to the thermally driven phase separation. In this work, the structure evolution of GO with mild annealing is closely investigated. It reveals that in addition to phase separation, the transformation of oxygen functionalities also occurs, which leads to the slight reduction of GO membranes and further the enhancement of GO properties. These results are further supported by the density functional theory based calculations. The results also show that the amount of chemically bonded oxygen atoms on graphene decreases gradually and we propose that the strongly physisorbed oxygen species constrained in the holes and vacancies on GO lattice might be responsible for the preserved oxygen content during the mild annealing procedure. The present experimental results and calculations indicate that both the diffusion and transformation of...

Sun, Pengzhan; Liu, He; Wang, Kunlin; Wu, Dehai; Xu, Zhiping; Zhu, Hongwei

2014-01-01T23:59:59.000Z

499

Oxygen-ion-beam-driven electrostatic ion cyclotron instability of hydrogen plasma  

SciTech Connect (OSTI)

The electrostatic ion cyclotron instability of hydrogen plasma driven by an oxygen ion beam and resulting turbulent heating of both ion species is investigated. The instability growth rate exceeds the oxygen ion gyrofrequency, so that the oxygen ions may be considered as unmagnetized during the process of waves growth. As a result the instability is developed due to inverse Landau damping of the ion cyclotron waves caused by thermal motion of oxygen ions across the magnetic field. The quasilinear analysis of the turbulent heating of both ion species resulted from their interactions with ion cyclotron turbulence indicates that this instability may be responsible for the observed anisotropic heating of auroral outflowing oxygen O{sup +} ions in the ionosphere.

Chibisov, D. V.; Mikhailenko, V. S.; Stepanov, K. N. [Kharkov National University, 61108 Kharkov (Ukraine)

2009-07-15T23:59:59.000Z

500

NETL: IEP – Oxy-Combustion CO2 Emissions Control - Oxygen-Based PC Boiler  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

– Oxy-Combustion CO2 Emissions Control – Oxy-Combustion CO2 Emissions Control Oxygen-Based PC Boiler Project No.: FC26-04NT42207 & FC26-03NT41736 Spatial Comparison of an Air-Fired Furnace versus an Oxygen-Fired Furnace. Spatial Comparison of an Air-Fired Furnace versus an Oxygen-Fired Furnace. Foster Wheeler North America Corporation will conduct to two projects to improve carbon dioxide (CO2) capture technology by developing a conceptual pulverized coal-fired boiler system design using oxygen as the combustion medium. Using oxygen instead of air produces a flue gas with a high CO2 concentration, which will facilitate CO2 capture for subsequent sequestration. The first project will develop modeling simulations that will lead to a conceptual design that addresses costs, performance, and emissions, and