Sample records for gasification trig system

  1. Gasification system

    DOE Patents [OSTI]

    Haldipur, Gaurang B. (Hempfield, PA); Anderson, Richard G. (Penn Hills, PA); Cherish, Peter (Bethel Park, PA)

    1983-01-01T23:59:59.000Z

    A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

  2. Gasification system

    DOE Patents [OSTI]

    Haldipur, Gaurang B. (Hempfield, PA); Anderson, Richard G. (Penn Hills, PA); Cherish, Peter (Bethel Park, PA)

    1985-01-01T23:59:59.000Z

    A method and system for injecting coal and process fluids into a fluidized bed gasification reactor. Three concentric tubes extend vertically upward into the fluidized bed. Coal particulates in a transport gas are injected through an inner tube, and an oxygen rich mixture of oxygen and steam are injected through an inner annulus about the inner tube. A gaseous medium relatively lean in oxygen content, such as steam, is injected through an annulus surrounding the inner annulus.

  3. Gasification Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SYSTEMS Gasi cation Systems Advanced Combustion Systems Advanced Turbines Solid Oxide Fuel Cells Plant Optimization Coal Utilization Sciences University Training and Research...

  4. Gasification Systems Portfolio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist.Newof EnergyFunding OpportunityF2015 Gasification Systems

  5. Gasification Systems Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist.Newof EnergyFunding OpportunityF2015 GasificationGasification

  6. Gasification Systems Project Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist.Newof EnergyFunding OpportunityF2015 Gasification

  7. Coal Integrated Gasification Fuel Cell System Study

    SciTech Connect (OSTI)

    Gregory Wotzak; Chellappa Balan; Faress Rahman; Nguyen Minh

    2003-08-01T23:59:59.000Z

    The pre-baseline configuration for an Integrated Gasification Fuel Cell (IGFC) system has been developed. This case uses current gasification, clean-up, gas turbine, and bottoming cycle technologies together with projected large planar Solid Oxide Fuel Cell (SOFC) technology. This pre-baseline case will be used as a basis for identifying the critical factors impacting system performance and the major technical challenges in implementing such systems. Top-level system requirements were used as the criteria to evaluate and down select alternative sub-systems. The top choice subsystems were subsequently integrated to form the pre-baseline case. The down-selected pre-baseline case includes a British Gas Lurgi (BGL) gasification and cleanup sub-system integrated with a GE Power Systems 6FA+e gas turbine and the Hybrid Power Generation Systems planar Solid Oxide Fuel Cell (SOFC) sub-system. The overall efficiency of this system is estimated to be 43.0%. The system efficiency of the pre-baseline system provides a benchmark level for further optimization efforts in this program.

  8. Coal Integrated Gasification Fuel Cell System Study

    SciTech Connect (OSTI)

    Chellappa Balan; Debashis Dey; Sukru-Alper Eker; Max Peter; Pavel Sokolov; Greg Wotzak

    2004-01-31T23:59:59.000Z

    This study analyzes the performance and economics of power generation systems based on Solid Oxide Fuel Cell (SOFC) technology and fueled by gasified coal. System concepts that integrate a coal gasifier with a SOFC, a gas turbine, and a steam turbine were developed and analyzed for plant sizes in excess of 200 MW. Two alternative integration configurations were selected with projected system efficiency of over 53% on a HHV basis, or about 10 percentage points higher than that of the state-of-the-art Integrated Gasification Combined Cycle (IGCC) systems. The initial cost of both selected configurations was found to be comparable with the IGCC system costs at approximately $1700/kW. An absorption-based CO2 isolation scheme was developed, and its penalty on the system performance and cost was estimated to be less approximately 2.7% and $370/kW. Technology gaps and required engineering development efforts were identified and evaluated.

  9. Techniques for Mercury Control and Measurement in Gasification Systems

    SciTech Connect (OSTI)

    Granite, E.J.; King, W.P.; Pennline, H.W.

    2002-09-20T23:59:59.000Z

    A major concern for power systems that use coal as an energy source is the air emissions from the plant. Although certain air emissions are currently regulated, the emergence of new regulations for other pollutants are on the horizon. Gasification is an important strategy for increasing the utilization of abundant domestic coal reserves. The Department of Energy envisions increased use of gasification in the United States during the next twenty years. As such, the DOE Gasification Technologies Program will strive to approach a near-zero emissions goal with respect to pollutants. The mercury research detailed in this proposal addresses the Gas Cleaning and Conditioning program technology area.

  10. Power Systems Development Facility Gasification Test Campaign TC22

    SciTech Connect (OSTI)

    Southern Company Services

    2008-11-01T23:59:59.000Z

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of TC22, the first test campaign using a high moisture lignite from Mississippi as the feedstock in the modified Transport Gasifier configuration. TC22 was conducted from March 24 to April 17, 2007. The gasification process was operated for 543 hours, increasing the total gasification operation at the PSDF to over 10,000 hours. The PSDF gasification process was operated in air-blown mode with a total of about 1,080 tons of coal. Coal feeder operation was challenging due to the high as-received moisture content of the lignite, but adjustments to the feeder operating parameters reduced the frequency of coal feeder trips. Gasifier operation was stable, and carbon conversions as high as 98.9 percent were demonstrated. Operation of the PCD and other support equipment such as the recycle gas compressor and ash removal systems operated reliably.

  11. Power Systems Development Facility Gasification Test Campaign TC16

    SciTech Connect (OSTI)

    Southern Company Services

    2004-08-24T23:59:59.000Z

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR (formerly Kellogg Brown & Root) Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report discusses Test Campaign TC16 of the PSDF gasification process. TC16 began on July 14, 2004, lasting until August 24, 2004, for a total of 835 hours of gasification operation. The test campaign consisted of operation using Powder River Basin (PRB) subbituminous coal and high sodium lignite from the North Dakota Freedom mine. The highest gasifier operating temperature mostly varied from 1,760 to 1,850 F with PRB and 1,500 to 1,600 F with lignite. Typically, during PRB operations, the gasifier exit pressure was maintained between 215 and 225 psig using air as the gasification oxidant and between 145 and 190 psig while using oxygen as the oxidant. With lignite, the gasifier operated only in air-blown mode, and the gasifier outlet pressure ranged from 150 to 160 psig.

  12. Fluidized bed gasification ash reduction and removal system

    DOE Patents [OSTI]

    Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

    1984-02-28T23:59:59.000Z

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  13. Power Systems Development Facility Gasification Test Campaing TC14

    SciTech Connect (OSTI)

    Southern Company Services

    2004-02-28T23:59:59.000Z

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device (PCD), advanced syngas cleanup systems, and high pressure solids handling systems. This report details test campaign TC14 of the PSDF gasification process. TC14 began on February 16, 2004, and lasted until February 28, 2004, accumulating 214 hours of operation using Powder River Basin (PRB) subbituminous coal. The gasifier operating temperatures varied from 1760 to 1810 F at pressures from 188 to 212 psig during steady air blown operations and approximately 160 psig during oxygen blown operations.

  14. Power Systems Development Facility Gasification Test Campaign TC17

    SciTech Connect (OSTI)

    Southern Company Services

    2004-11-30T23:59:59.000Z

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR (formerly Kellogg Brown & Root) Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results gasification operation with Illinois Basin bituminous coal in PSDF test campaign TC17. The test campaign was completed from October 25, 2004, to November 18, 2004. System startup and initial operation was accomplished with Powder River Basin (PRB) subbituminous coal, and then the system was transitioned to Illinois Basin coal operation. The major objective for this test was to evaluate the PSDF gasification process operational stability and performance using the Illinois Basin coal. The Transport Gasifier train was operated for 92 hours using PRB coal and for 221 hours using Illinois Basin coal.

  15. Power Systems Development Facility Gasification Test Campaing TC18

    SciTech Connect (OSTI)

    Southern Company Services

    2005-08-31T23:59:59.000Z

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device (PCD), advanced syngas cleanup systems, and high pressure solids handling systems. This report details Test Campaign TC18 of the PSDF gasification process. Test campaign TC18 began on June 23, 2005, and ended on August 22, 2005, with the gasifier train accumulating 1,342 hours of operation using Powder River Basin (PRB) subbituminous coal. Some of the testing conducted included commissioning of a new recycle syngas compressor for gasifier aeration, evaluation of PCD filter elements and failsafes, testing of gas cleanup technologies, and further evaluation of solids handling equipment. At the conclusion of TC18, the PSDF gasification process had been operated for more than 7,750 hours.

  16. Power Systems Development Facility Gasification Test Campaign TC25

    SciTech Connect (OSTI)

    Southern Company Services

    2008-12-01T23:59:59.000Z

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, routinely demonstrates gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a KBR Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This report summarizes the results of TC25, the second test campaign using a high moisture lignite coal from the Red Hills mine in Mississippi as the feedstock in the modified Transport Gasifier configuration. TC25 was conducted from July 4, 2008, through August 12, 2008. During TC25, the PSDF gasification process operated for 742 hours in air-blown gasification mode. Operation with the Mississippi lignite was significantly improved in TC25 compared to the previous test (TC22) with this fuel due to the addition of a fluid bed coal dryer. The new dryer was installed to dry coals with very high moisture contents for reliable coal feeding. The TC25 test campaign demonstrated steady operation with high carbon conversion and optimized performance of the coal handling and gasifier systems. Operation during TC25 provided the opportunity for further testing of instrumentation enhancements, hot gas filter materials, and advanced syngas cleanup technologies. The PSDF site was also made available for testing of the National Energy Technology Laboratory's fuel cell module and Media Process Technology's hydrogen selective membrane with syngas from the Transport Gasifier.

  17. BIOMASS GASIFICATION AND POWER GENERATION USING ADVANCED GAS TURBINE SYSTEMS

    SciTech Connect (OSTI)

    David Liscinsky

    2002-10-20T23:59:59.000Z

    A multidisciplined team led by the United Technologies Research Center (UTRC) and consisting of Pratt & Whitney Power Systems (PWPS), the University of North Dakota Energy & Environmental Research Center (EERC), KraftWork Systems, Inc. (kWS), and the Connecticut Resource Recovery Authority (CRRA) has evaluated a variety of gasified biomass fuels, integrated into advanced gas turbine-based power systems. The team has concluded that a biomass integrated gasification combined-cycle (BIGCC) plant with an overall integrated system efficiency of 45% (HHV) at emission levels of less than half of New Source Performance Standards (NSPS) is technically and economically feasible. The higher process efficiency in itself reduces consumption of premium fuels currently used for power generation including those from foreign sources. In addition, the advanced gasification process can be used to generate fuels and chemicals, such as low-cost hydrogen and syngas for chemical synthesis, as well as baseload power. The conceptual design of the plant consists of an air-blown circulating fluidized-bed Advanced Transport Gasifier and a PWPS FT8 TwinPac{trademark} aeroderivative gas turbine operated in combined cycle to produce {approx}80 MWe. This system uses advanced technology commercial products in combination with components in advanced development or demonstration stages, thereby maximizing the opportunity for early implementation. The biofueled power system was found to have a levelized cost of electricity competitive with other new power system alternatives including larger scale natural gas combined cycles. The key elements are: (1) An Advanced Transport Gasifier (ATG) circulating fluid-bed gasifier having wide fuel flexibility and high gasification efficiency; (2) An FT8 TwinPac{trademark}-based combined cycle of approximately 80 MWe; (3) Sustainable biomass primary fuel source at low cost and potentially widespread availability-refuse-derived fuel (RDF); (4) An overall integrated system that exceeds the U.S. Department of Energy (DOE) goal of 40% (HHV) efficiency at emission levels well below the DOE suggested limits; and (5) An advanced biofueled power system whose levelized cost of electricity can be competitive with other new power system alternatives.

  18. Coal properties and system operating parameters for underground coal gasification

    SciTech Connect (OSTI)

    Yang, L. [China University of Mining & Technology, Xuzhou (China)

    2008-07-01T23:59:59.000Z

    Through the model experiment for underground coal gasification, the influence of the properties for gasification agent and gasification methods on underground coal gasifier performance were studied. The results showed that pulsating gasification, to some extent, could improve gas quality, whereas steam gasification led to the production of high heating value gas. Oxygen-enriched air and backflow gasification failed to improve the quality of the outlet gas remarkably, but they could heighten the temperature of the gasifier quickly. According to the experiment data, the longitudinal average gasification rate along the direction of the channel in the gasifying seams was 1.212 m/d, with transverse average gasification rate 0.069 m/d. Experiment indicated that, for the oxygen-enriched steam gasification, when the steam/oxygen ratio was 2:1, gas compositions remained stable, with H{sub 2} + CO content virtually standing between 60% and 70% and O{sub 2} content below 0.5%. The general regularities of the development of the temperature field within the underground gasifier and the reasons for the changes of gas quality were also analyzed. The 'autopneumatolysis' and methanization reaction existing in the underground gasification process were first proposed.

  19. Co-gasification of municipal solid waste and material recovery in a large-scale gasification and melting system

    SciTech Connect (OSTI)

    Tanigaki, Nobuhiro, E-mail: tanigaki.nobuhiro@nsc-eng.co.jp [Nippon Steel Engineering Co., Ltd. (Head Office), Osaki Center Building 1-5-1, Osaki, Shinagawa-ku, Tokyo 141-8604 (Japan); Manako, Kazutaka [Nippon Steel Engineering Co., Ltd., 46-59, Nakabaru, Tobata-ku, Kitakyushu, Fukuoka 804-8505 (Japan); Osada, Morihiro [Nippon Steel Engineering Co., Ltd. (Head Office), Osaki Center Building 1-5-1, Osaki, Shinagawa-ku, Tokyo 141-8604 (Japan)

    2012-04-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer This study evaluates the effects of co-gasification of MSW with MSW bottom ash. Black-Right-Pointing-Pointer No significant difference between MSW treatment with and without MSW bottom ash. Black-Right-Pointing-Pointer PCDD/DFs yields are significantly low because of the high carbon conversion ratio. Black-Right-Pointing-Pointer Slag quality is significantly stable and slag contains few hazardous heavy metals. Black-Right-Pointing-Pointer The final landfill amount is reduced and materials are recovered by DMS process. - Abstract: This study evaluates the effects of co-gasification of municipal solid waste with and without the municipal solid waste bottom ash using two large-scale commercial operation plants. From the viewpoint of operation data, there is no significant difference between municipal solid waste treatment with and without the bottom ash. The carbon conversion ratios are as high as 91.7% and 95.3%, respectively and this leads to significantly low PCDD/DFs yields via complete syngas combustion. The gross power generation efficiencies are 18.9% with the bottom ash and 23.0% without municipal solid waste bottom ash, respectively. The effects of the equivalence ratio are also evaluated. With the equivalence ratio increasing, carbon monoxide concentration is decreased, and carbon dioxide and the syngas temperature (top gas temperature) are increased. The carbon conversion ratio is also increased. These tendencies are seen in both modes. Co-gasification using the gasification and melting system (Direct Melting System) has a possibility to recover materials effectively. More than 90% of chlorine is distributed in fly ash. Low-boiling-point heavy metals, such as lead and zinc, are distributed in fly ash at rates of 95.2% and 92.0%, respectively. Most of high-boiling-point heavy metals, such as iron and copper, are distributed in metal. It is also clarified that slag is stable and contains few harmful heavy metals such as lead. Compared with the conventional waste management framework, 85% of the final landfill amount reduction is achieved by co-gasification of municipal solid waste with bottom ash and incombustible residues. These results indicate that the combined production of slag with co-gasification of municipal solid waste with the bottom ash constitutes an ideal approach to environmental conservation and resource recycling.

  20. Development of a Segregated Municipal Solid Waste Gasification System for Electrical Power Generation

    E-Print Network [OSTI]

    Maglinao, Amado Latayan

    2013-04-11T23:59:59.000Z

    ) gasification for electrical power generation was conducted in a fluidized bed gasifier and the feasibility of using a control system was evaluated to facilitate its management and operation. The performance of an engine using the gas produced was evaluated. A...

  1. Case-study of a coal gasification-based energy supply system for China

    E-Print Network [OSTI]

    Engineering, Tsinghua University, 100084 Beijing, China ``Syngas city'' (SC) is a concept for a coal. Introduction ``Syngas city'' (SC) is a concept for coal gasification- based energy supply systems that deploy

  2. Diffusion Coatings for Corrosion Resistant Components in Coal Gasification Systems

    SciTech Connect (OSTI)

    Gopala N. Krishnan; Ripudaman Malhotra; Esperanza Alvarez; Kai-Hung Lau; Angel Sanjurjo

    2005-01-01T23:59:59.000Z

    Heat-exchangers, particle filters, turbines, and other components in integrated coal gasification combined cycle system must withstand the highly sulfiding conditions of the high temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high alloy materials are used. Deposition of a suitable coating on a low cost alloy may improve its resistance to such sulfidation attack and decrease capital and operating costs. The alloys used in the gasifier service include austenitic and ferritic stainless steels, nickel-chromium-iron alloys, and expensive nickel-cobalt alloys. During this reporting period we focused on getting a bench-scale test system to expose alloy coupons to simulated gasifier environment. The test facility was designed to allow about 20 specimen coupons to be exposed simultaneously for an extend period to a simulated coal gas stream at temperatures up to 1000 C. The simulated gas stream contained about 26%H{sub 2}, 39%CO, 17%CO{sub 2}, 1.4% H{sub 2}S and balance steam. We successfully ran a 100+h test with coated and uncoated stainless steel coupons. The tested alloys include SS304, SS316, SS405, SS409, SS410, and IN800. The main finding is that Ti/Ta coating provides excellent protection to SS405 under conditions where uncoated austenitic and ferritic stainless steel alloy coupons are badly corroded. Cr coatings also appear to afford some protection against corrosion.

  3. Technical analysis of advanced wastewater-treatment systems for coal-gasification plants

    SciTech Connect (OSTI)

    Not Available

    1981-03-31T23:59:59.000Z

    This analysis of advanced wastewater treatment systems for coal gasification plants highlights the three coal gasification demonstration plants proposed by the US Department of Energy: The Memphis Light, Gas and Water Division Industrial Fuel Gas Demonstration Plant, the Illinois Coal Gasification Group Pipeline Gas Demonstration Plant, and the CONOCO Pipeline Gas Demonstration Plant. Technical risks exist for coal gasification wastewater treatment systems, in general, and for the three DOE demonstration plants (as designed), in particular, because of key data gaps. The quantities and compositions of coal gasification wastewaters are not well known; the treatability of coal gasification wastewaters by various technologies has not been adequately studied; the dynamic interactions of sequential wastewater treatment processes and upstream wastewater sources has not been tested at demonstration scale. This report identifies key data gaps and recommends that demonstration-size and commercial-size plants be used for coal gasification wastewater treatment data base development. While certain advanced treatment technologies can benefit from additional bench-scale studies, bench-scale and pilot plant scale operations are not representative of commercial-size facility operation. It is recommended that coal gasification demonstration plants, and other commercial-size facilities that generate similar wastewaters, be used to test advanced wastewater treatment technologies during operation by using sidestreams or collected wastewater samples in addition to the plant's own primary treatment system. Advanced wastewater treatment processes are needed to degrade refractory organics and to concentrate and remove dissolved solids to allow for wastewater reuse. Further study of reverse osmosis, evaporation, electrodialysis, ozonation, activated carbon, and ultrafiltration should take place at bench-scale.

  4. DIFFUSION COATINGS FOR CORROSION RESISTANT COMPONENTS IN COAL GASIFICATION SYSTEMS

    SciTech Connect (OSTI)

    Gopala N. Krishnan; Ripudaman Malhotra; Esperanza Alvarez; Kai-Hung Lau; Angel Sanjurjo

    2005-01-01T23:59:59.000Z

    Heat-exchangers, particle filters, turbines, and other components in integrated coal gasification combined cycle system must withstand the highly sulfiding conditions of the high temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high alloy materials are used. Deposition of a suitable coating on a low cost alloy may improve is resistance to such sulfidation attack and decrease capital and operating costs. The alloys used in the gasifier service include austenitic and ferritic stainless steels, nickel-chromium-iron alloys, and expensive nickel-cobalt alloys. During this reporting period we coated coupons of selected alloy steels with diffusion coatings of Cr and Al, as well as with titanium and tantalum nitrides. The coated samples were analyzed for their surface composition. In several instances, the samples were also cut to determine the depth profile of the coating. Several of the early runs did not yield uniform or deep enough coatings and hence a significant portion of the effort in this period was devoted fixing the problems with our fluidized bed reactor. Before the end of the quarter we had prepared a number of samples, many of them in duplicates, and sent one set to Wabash River Energy Laboratory for them to install in their gasifier. The gasifier was undergoing a scheduled maintenance and thus presented an opportunity to place some of our coupons in the stream of an operating gasifier. The samples submitted included coated and uncoated pairs of different alloys.

  5. Power Systems Development Facility Gasification Test Run TC08

    SciTech Connect (OSTI)

    Southern Company Services

    2002-06-30T23:59:59.000Z

    This report discusses Test Campaign TC08 of the Kellogg Brown & Root, Inc. (KBR) Transport Gasifier train with a Siemens Westinghouse Power Corporation (Siemens Westinghouse) particle filter system at the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama. The Transport Gasifier is an advanced circulating fluidized-bed gasifier designed to operate as either a combustor or a gasifier in air- or oxygen-blown mode using a particulate control device (PCD). The Transport Gasifier was operated as a pressurized gasifier in air- and oxygen-blown modes during TC08. Test Run TC08 was started on June 9, 2002 and completed on June 29. Both gasifier and PCD operations were stable during the test run with a stable baseline pressure drop. The oxygen feed supply system worked well and the transition from air to oxygen blown was smooth. The gasifier temperature was varied between 1,710 and 1,770 F at pressures from 125 to 240 psig. The gasifier operates at lower pressure during oxygen-blown mode due to the supply pressure of the oxygen system. In TC08, 476 hours of solid circulation and 364 hours of coal feed were attained with 153 hours of pure oxygen feed. The gasifier and PCD operations were stable in both enriched air and 100 percent oxygen blown modes. The oxygen concentration was slowly increased during the first transition to full oxygen-blown operations. Subsequent transitions from air to oxygen blown could be completed in less than 15 minutes. Oxygen-blown operations produced the highest synthesis gas heating value to date, with a projected synthesis gas heating value averaging 175 Btu/scf. Carbon conversions averaged 93 percent, slightly lower than carbon conversions achieved during air-blown gasification.

  6. history gasification | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    gasification is first conceived when Philippe Lebon led efforts to gasify wood. 1. Coal Energy Systems, Bruce G. Miller, pg 247 Gasification Background Markets for...

  7. Proceedings of the seventh annual gasification and gas stream cleanup systems contractors review meeting: Volume 2

    SciTech Connect (OSTI)

    Ghate, M.R.; Markel, K.E. Jr.; Jarr, L.A.; Bossart, S.J. (eds.)

    1987-08-01T23:59:59.000Z

    On June 16 through 19, 1987, METC sponsored the Seventh Annual Gasification and Gas Stream Cleanup Systems Contractors Review Meeting which was held at the Sheraton Lakeview Conference Center in Morgantown, West Virginia. The primary purpose of the meeting was threefold: to review the technical progress and current status of the gasification and gas stream cleanup projects sponsored by the Department of Energy; to foster technology exchange among participating researchers and other technical communities; to facilitate interactive dialogues which would identify research needs that would make coal-based gasification systems more attractive economically and environmentally. More than 310 representatives of Government, academia, industry, and foreign energy research organizations attended the 4-day meeting. Fifty-three papers and thirty poster dsplays were presented summarizing recent developments in the gasification and gas stream cleanup programs. Volume II covers papers presented at sessions 5 and 6 on system for the production of synthesis gas, and on system for the production of power. All papers have been processed for inclusion in the Energy Data Base.

  8. EIS-0428: Mississippi Gasification, LLC, Industrial Gasification...

    Broader source: Energy.gov (indexed) [DOE]

    8: Mississippi Gasification, LLC, Industrial Gasification Facility in Moss Point, MS EIS-0428: Mississippi Gasification, LLC, Industrial Gasification Facility in Moss Point, MS...

  9. EIS-0429: Indiana Gasification, LLC, Industrial Gasification...

    Office of Environmental Management (EM)

    9: Indiana Gasification, LLC, Industrial Gasification Facility in Rockport, IN and CO2 Pipeline EIS-0429: Indiana Gasification, LLC, Industrial Gasification Facility in Rockport,...

  10. Proceedings of the seventh annual gasification and gas stream cleanup systems contractors review meeting: Volume 1

    SciTech Connect (OSTI)

    Ghate, M.R.; Markel, K.E. Jr.; Jarr, L.A.; Bossart, S.J. (eds.)

    1987-08-01T23:59:59.000Z

    On June 16 through 19, 1987, METC sponsored the Seventh Annual Gasification and Gas Stream Cleanup Systems Contractors Review Meeting which was held at the Sheraton Lakeview Conference Center in Morgantown, West Virginia. The primary purpose of the meeting was threefold: to review the technical progress and current status of the gasification and gas stream cleanup projects sponsored by the Department of Energy; to foster technology exchange among participating researchers and other technical communities; to facilitate interactive dialogues which would identify research needs that would make coal-based gasification systems more attractive economically and environmentally. More than 310 representatives of Government, academia, industry, and foreign energy research organizations attended the 4-day meeting. Fifty-three papers and thirty poster displays were presented summarizing recent developments in the gasification and gas stream cleanup programs. Volume I covers information presented at sessions 1 through 4 on systems for the production of Co-products and industrial fuel gas, environmental projects, and components and materials. Individual papers have been processed for the Energy Data Base.

  11. ADVANCED GASIFICATION-BASED FUEL CONVERSION AND ELECTRIC ENERGY PRODUCTION SYSTEM

    SciTech Connect (OSTI)

    Joseph Rabovitser; Bruce Bryan

    2002-10-01T23:59:59.000Z

    Boise Paper Solutions and the Gas Technology Institute (GTI) are cooperating to develop, demonstrate and place in continuous operation an advanced biomass gasification-based power generation system suitable for near-term commercial deployment in the Forest Products Industry. The system will be used in conjunction with, rather than in place of, existing wood waste fired boilers and flue gas cleanup systems. The novel system will include three advanced technological components based on GTI's RENUGAS{reg_sign} and three-stage stoker combustion technologies, and a gas turbine-based power generation concept developed in DOE's High Performance Power System (HIPPS) program. The system has, as its objective, to avoid the major hurdles of high-pressure gasification, i.e., high-pressure fuel feeding and ash removal, and hot gas cleaning that are typical for conventional IGCC power generation. It aims to also minimize capital intensity and technology risks. The system is intended to meet the immediate needs of the forest products industry for highly efficient and environmentally friendly electricity and steam generation systems utilizing existing wood waste as fuel resources. The overall objective of this project is to demonstrate the commercial applicability of an advanced biomass gasification-based power generation system at Boise Paper Solutions' pulp and paper mill located at DeRidder, Louisiana.

  12. ADVANCED GASIFICATION-BASED FUEL CONVERSION AND ELECTRIC ENERGY PRODUCTION SYSTEM

    SciTech Connect (OSTI)

    Joseph Rabovitser; Bruce Bryan

    2002-07-01T23:59:59.000Z

    Boise Cascade Corporation and the Gas Technology Institute (GTI) are cooperating to develop, demonstrate and place in continuous operation an advanced biomass gasification-based power generation system suitable for near-term commercial deployment in the Forest Products Industry. The system will be used in conjunction with, rather than in place of, existing wood waste fired boilers and flue gas cleanup systems. The novel system will include three advanced technological components based on GTI's RENUGAS{reg_sign} and three-stage stoker combustion technologies, and a gas turbine-based power generation concept developed in DOE's High Performance Power System (HIPPS) program. The system has, as its objective, to avoid the major hurdles of high-pressure gasification, i.e., high-pressure fuel feeding and ash removal, and hot gas cleaning that are typical for conventional IGCC power generation. It aims to also minimize capital intensity and technology risks. The system is intended to meet the immediate needs of the forest products industry for highly efficient and environmentally friendly electricity and steam generation systems utilizing existing wood waste as fuel resources.

  13. Evaluation of a Combined Cyclone and Gas Filtration System for Particulate Removal in the Gasification Process

    SciTech Connect (OSTI)

    Rizzo, Jeffrey J. [Phillips66 Company, West Terre Haute, IN (United States)

    2010-04-30T23:59:59.000Z

    The Wabash gasification facility, owned and operated by sgSolutions LLC, is one of the largest single train solid fuel gasification facilities in the world capable of transforming 2,000 tons per day of petroleum coke or 2,600 tons per day of bituminous coal into synthetic gas for electrical power generation. The Wabash plant utilizes Phillips66 proprietary E-Gas (TM) Gasification Process to convert solid fuels such as petroleum coke or coal into synthetic gas that is fed to a combined cycle combustion turbine power generation facility. During plant startup in 1995, reliability issues were realized in the gas filtration portion of the gasification process. To address these issues, a slipstream test unit was constructed at the Wabash facility to test various filter designs, materials and process conditions for potential reliability improvement. The char filtration slipstream unit provided a way of testing new materials, maintenance procedures, and process changes without the risk of stopping commercial production in the facility. It also greatly reduced maintenance expenditures associated with full scale testing in the commercial plant. This char filtration slipstream unit was installed with assistance from the United States Department of Energy (built under DOE Contract No. DE-FC26-97FT34158) and began initial testing in November of 1997. It has proven to be extremely beneficial in the advancement of the E-Gas (TM) char removal technology by accurately predicting filter behavior and potential failure mechanisms that would occur in the commercial process. After completing four (4) years of testing various filter types and configurations on numerous gasification feed stocks, a decision was made to investigate the economic and reliability effects of using a particulate removal gas cyclone upstream of the current gas filtration unit. A paper study had indicated that there was a real potential to lower both installed capital and operating costs by implementing a char cyclonefiltration hybrid unit in the E-Gas (TM) gasification process. These reductions would help to keep the E-Gas (TM) technology competitive among other coal-fired power generation technologies. The Wabash combined cyclone and gas filtration slipstream test program was developed to provide design information, equipment specification and process control parameters of a hybrid cyclone and candle filter particulate removal system in the E-Gas (TM) gasification process that would provide the optimum performance and reliability for future commercial use. The test program objectives were as follows: 1. Evaluate the use of various cyclone materials of construction; 2. Establish the optimal cyclone efficiency that provides stable long term gas filter operation; 3. Determine the particle size distribution of the char separated by both the cyclone and candle filters. This will provide insight into cyclone efficiency and potential future plant design; 4. Determine the optimum filter media size requirements for the cyclone-filtration hybrid unit; 5. Determine the appropriate char transfer rates for both the cyclone and filtration portions of the hybrid unit; 6. Develop operating procedures for the cyclone-filtration hybrid unit; and, 7. Compare the installed capital cost of a scaled-up commercial cyclone-filtration hybrid unit to the current gas filtration design without a cyclone unit, such as currently exists at the Wabash facility.

  14. Development of a Segregated Municipal Solid Waste Gasification System for Electrical Power Generation 

    E-Print Network [OSTI]

    Maglinao, Amado Latayan

    2013-04-11T23:59:59.000Z

    index for coals. ............................................................ 110 Table 21. Utimate analysis of different biomass ............................................................ 114 Table 22. Analysis of the ash from MSW, DM and CGT... impact on the design, performance, maintenance and cost of gasification (Consonni and Vigan?, 2012). [3] 9 Biomass gasification has trailed coal gasification due to technical differences in the characteristics of the feedstock and the typical...

  15. Carbonate fuel cell system with thermally integrated gasification

    DOE Patents [OSTI]

    Steinfeld, George (Southbury, CT); Meyers, Steven J. (Huntington Beach, CA); Lee, Arthur (Fishkill, NY)

    1996-01-01T23:59:59.000Z

    A fuel cell system employing a gasifier for generating fuel gas for the fuel cell of the fuel cell system and in which heat for the gasifier is derived from the anode exhaust gas of the fuel cell.

  16. Carbonate fuel cell system with thermally integrated gasification

    DOE Patents [OSTI]

    Steinfeld, G.; Meyers, S.J.; Lee, A.

    1996-09-10T23:59:59.000Z

    A fuel cell system is described which employs a gasifier for generating fuel gas for the fuel cell of the fuel cell system and in which heat for the gasifier is derived from the anode exhaust gas of the fuel cell. 2 figs.

  17. FEED SYSTEM INNOVATION FOR GASIFICATION OF LOCALLY ECONOMICAL ALTERNATIVE FUELS (FIGLEAF)

    SciTech Connect (OSTI)

    Michael L. Swanson; Mark A. Musich; Darren D. Schmidt; Joseph K. Schultz

    2003-02-01T23:59:59.000Z

    The Feed System Innovation for Gasification of Locally Economical Alternative Fuels (FIGLEAF) project was conducted by the Energy & Environmental Research Center and Gasification Engineering Corporation of Houston, Texas (a subsidiary of Global Energy Inc., Cincinnati, Ohio), with 80% cofunding from the U.S. Department of Energy (DOE). The goal of the project was to identify and evaluate low-value fuels that could serve as alternative feedstocks and to develop a feed system to facilitate their use in integrated gasification combined-cycle and gasification coproduction facilities. The long-term goal, to be accomplished in a subsequent project, is to install a feed system for the selected fuel(s) at Global Energy's commercial-scale 262-MW Wabash River Coal Gasification Facility in West Terre Haute, Indiana. The feasibility study undertaken for the project consisted of identifying and evaluating the economic feasibility of potential fuel sources, developing a feed system design capable of providing a fuel at 400 psig to the second stage of the E-Gas (Destec) gasifier to be cogasified with coal, performing bench- and pilot-scale testing to verify concepts and clarify decision-based options, reviewing information on high-pressure feed system designs, and determining the economics of cofeeding alternative feedstocks with the conceptual feed system design. A preliminary assessment of feedstock availability within Indiana and Illinois was conducted. Feedstocks evaluated included those with potential tipping fees to offset processing cost: sewage sludge, municipal solid waste, used railroad ties, urban wood waste (UWW), and used tires/tire-derived fuel. Agricultural residues and dedicated energy crop fuels were not considered since they would have a net positive cost to the plant. Based on the feedstock assessment, sewage sludge was selected as the primary feedstock for consideration at the Wabash River Plant. Because of the limited waste heat available for drying and the ability of the gasifier to operate with alternative feedstocks at up to 80% moisture, a decision was made to investigate a pumping system for delivering the as-received fuel across the pressure boundary into the second stage of the gasifier. A high-pressure feed pump and fuel dispersion nozzles were tested for their ability to cross the pressure boundary and adequately disperse the sludge into the second stage of the gasifier. These results suggest that it is technically feasible to get the sludge dispersed to an appropriate size into the second stage of the gasifier although the recycle syngas pressure needed to disperse the sludge would be higher than originally desired. A preliminary design was prepared for a sludge-receiving, storage, and high-pressure feeding system at the Wabash River Plant. The installed capital costs were estimated at approximately $9.7 million, within an accuracy of {+-}10%. An economic analysis using DOE's IGCC Model, Version 3 spreadsheet indicates that in order to justify the additional capital cost of the system, Global Energy would have to receive a tipping fee of $12.40 per wet ton of municipal sludge delivered. This is based on operation with petroleum coke as the primary fuel. Similarly, with coal as the primary fuel, a minimum tipping of $16.70 would be required. The availability of delivered sludge from Indianapolis, Indiana, in this tipping-fee range is unlikely; however, given the higher treatment costs associated with sludge treatment in Chicago, Illinois, delivery of sludge from Chicago, given adequate rail access, might be economically viable.

  18. Power Systems Development Facility Gasification Test Run TC09

    SciTech Connect (OSTI)

    Southern Company Services

    2002-09-30T23:59:59.000Z

    This report discusses Test Campaign TC09 of the Kellogg Brown & Root, Inc. (KBR) Transport Gasifier train with a Siemens Westinghouse Power Corporation (Siemens Westinghouse) particle filter system at the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama. The Transport Gasifier is an advanced circulating fluidized-bed gasifier designed to operate as either a combustor or a gasifier in air- or oxygen-blown mode of operation using a particulate control device (PCD). The Transport Gasifier was operated as a pressurized gasifier during TC09 in air- and oxygen-blown modes. Test Run TC09 was started on September 3, 2002, and completed on September 26, 2002. Both gasifier and PCD operations were stable during the test run, with a stable baseline pressure drop. The oxygen feed supply system worked well and the transition from air to oxygen was smooth. The gasifier temperature varied between 1,725 and 1,825 F at pressures from 125 to 270 psig. The gasifier operates at lower pressure during oxygen-blown mode due to the supply pressure of the oxygen system. In TC09, 414 hours of solid circulation and over 300 hours of coal feed were attained with almost 80 hours of pure oxygen feed.

  19. FEED SYSTEM INNOVATION FOR GASIFICATION OF LOCALLY ECONOMICAL ALTERNATIVE FUELS (FIGLEAF)

    SciTech Connect (OSTI)

    Michael L. Swanson; Mark A. Musich; Darren D. Schmidt

    2001-11-01T23:59:59.000Z

    The Feed System Innovation for Gasification of Locally Economical Alternative Fuels (FIGLEAF) project is being conducted by the Energy and Environmental Research Center and Gasification Engineering Corporation of Houston, Texas (a subsidiary of Global Energy Inc., Cincinnati, Ohio), with 80% cofunding from the U.S. Department of Energy. The goal of the project is to identify and evaluate low-value fuels that could serve as alternative feedstocks and to develop a feed system to facilitate their use in integrated gasification combined cycle and gasification coproduction facilities. The long-term goal, to be accomplished in a subsequent project, is to install a feed system for the selected fuels at Global Energy's commercial-scale 262-MW Wabash River Coal Gasification Facility in West Terre Haute, Indiana. The feasibility study undertaken for the project consists of identifying and evaluating the economic feasibility of potential fuel sources, developing a feed system design capable of providing a fuel at 400 psig to the second stage of the E-Gas (Destec) gasifier to be cogasified with coal at up to 30% on a Btu basis, performing bench- and pilot-scale testing to verify concepts and clarify decision-based options, reviewing prior art with respect to high-pressure feed system designs, and determining the economics of cofeeding alternative feedstocks with the conceptual feed system design. Activities and results thus far include the following. Several potential alternative fuels have been obtained for evaluation and testing as potential feedstocks, including sewage sludge, used railroad ties, urban wood waste, municipal solid waste, and used waste tires/tire-derived fuel. Only fuels with potential tipping fees were considered; potential energy crop fuels were not considered since they would have a net positive cost to the plant. Based on the feedstock assessment, sewage sludge has been selected as one of the primary feedstocks for consideration at the Wabash plant. Because of the limited waste heat available for drying and the ability of the gasifier to operate with alternative feedstocks at up to 80% moisture, a decision was made to investigate a pumping system for delivering the as-received fuel across the pressure boundary. High-temperature drop-tube furnace tests were conducted to determine if explosive fragmentation of high-moisture sludge droplets could be expected, but showed that these droplets underwent a shrinking and densification process that implies that the sludge will have to be well dispersed when injected into the gasifier. Fuel dispersion nozzles have been obtained for measuring how well the sludge can be dispersed in the second stage of the gasifier. Future work will include leasing a Schwing America pump to test pumping sewage sludge against 400 psig. In addition, sludge dispersion testing will be completed using two different dispersion nozzles to determine their ability to generate sludge particles small enough to be entrained out of the E-Gas entrained-flow gasifier.

  20. Power Systems Development Facility Gasification Test Run TC11

    SciTech Connect (OSTI)

    Southern Company Services

    2003-04-30T23:59:59.000Z

    This report discusses Test Campaign TC11 of the Kellogg Brown & Root, Inc. (KBR) Transport Gasifier train with a Siemens Westinghouse Power Corporation (Siemens Westinghouse) particle filter system at the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama. The Transport Gasifier is an advanced circulating fluidized-bed gasifier designed to operate as either a combustor or a gasifier in air- or oxygen-blown mode of operation using a particulate control device (PCD). Test run TC11 began on April 7, 2003, with startup of the main air compressor and the lighting of the gasifier start-up burner. The Transport Gasifier operated until April 18, 2003, when a gasifier upset forced the termination of the test run. Over the course of the entire test run, gasifier temperatures varied between 1,650 and 1,800 F at pressures from 160 to 200 psig during air-blown operations and around 135 psig during enriched-air operations. Due to a restriction in the oxygen-fed lower mixing zone (LMZ), the majority of the test run featured air-blown operations.

  1. Power Systems Development Facility Gasification Test Run TC07

    SciTech Connect (OSTI)

    Southern Company Services

    2002-04-05T23:59:59.000Z

    This report discusses Test Campaign TC07 of the Kellogg Brown & Root, Inc. (KBR) Transport Reactor train with a Siemens Westinghouse Power Corporation (Siemens Westinghouse) particle filter system at the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama. The Transport Reactor is an advanced circulating fluidized-bed reactor designed to operate as either a combustor or a gasifier using a particulate control device (PCD). The Transport Reactor was operated as a pressurized gasifier during TC07. Prior to TC07, the Transport Reactor was modified to allow operations as an oxygen-blown gasifier. Test Run TC07 was started on December 11, 2001, and the sand circulation tests (TC07A) were completed on December 14, 2001. The coal-feed tests (TC07B-D) were started on January 17, 2002 and completed on April 5, 2002. Due to operational difficulties with the reactor, the unit was taken offline several times. The reactor temperature was varied between 1,700 and 1,780 F at pressures from 200 to 240 psig. In TC07, 679 hours of solid circulation and 442 hours of coal feed, 398 hours with PRB coal and 44 hours with coal from the Calumet mine, and 33 hours of coke breeze feed were attained. Reactor operations were problematic due to instrumentation problems in the LMZ resulting in much higher than desired operating temperatures in the reactor. Both reactor and PCD operations were stable and the modifications to the lower part of the gasifier performed well while testing the gasifier with PRB coal feed.

  2. Power Systems Development Facility Gasification Test Run TC10

    SciTech Connect (OSTI)

    Southern Company Services

    2002-12-30T23:59:59.000Z

    This report discusses Test Campaign TC10 of the Kellogg Brown & Root, Inc. (KBR) Transport Gasifier train with a Siemens Westinghouse Power Corporation (Siemens Westinghouse) particle filter system at the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama. The Transport Gasifier is an advanced circulating fluidized-bed gasifier designed to operate as either a combustor or a gasifier in air- or oxygen-blown mode of operation using a particulate control device (PCD). The Transport Gasifier was operated as a pressurized gasifier during TC10 in air- (mainly for transitions and problematic operations) and oxygen-blown mode. Test Run TC10 was started on November 16, 2002, and completed on December 18, 2002. During oxygen-blown operations, gasifier temperatures varied between 1,675 and 1,825 F at pressures from 150 to 180 psig. After initial adjustments were made to reduce the feed rate, operations with the new fluidized coal feeder were stable with about half of the total coalfeed rate through the new feeder. However, the new fluidized-bed coal feeder proved to be difficult to control at low feed rates. Later the coal mills and original coal feeder experienced difficulties due to a high moisture content in the coal from heavy rains. Additional operational difficulties were experienced when several of the pressure sensing taps in the gasifier plugged. As the run progressed, modifications to the mills (to address processing the wet coal) resulted in a much larger feed size. This eventually resulted in the accumulation of large particles in the circulating solids causing operational instabilities in the standpipe and loop seal. Despite problems with the coal mills, coal feeder, pressure tap nozzles and the standpipe, the gasifier did experience short periods of stability during oxygenblown operations. During these periods, the syngas quality was high. During TC10, the gasifier gasified over 609 tons of Powder River Basin subbituminous coal and accumulated a total of 416 hours of coal feed, over 293 hours of which were in oxygen-blown operation. No sorbent was used during the run.

  3. Sorbents for mercury capture from fuel gas with application to gasification systems

    SciTech Connect (OSTI)

    Granite, E.J.; Myers, C.R.; King, W.P.; Stanko, D.C.; Pennline, H.W. [US DOE, Pittsburgh, PA (United States)

    2006-06-21T23:59:59.000Z

    In regard to gasification for power generation, the removal of mercury by sorbents at elevated temperatures preserves the higher thermal efficiency of the integrated gasification combined cycle system. Unfortunately, most sorbents display poor capacity for elemental mercury at elevated temperatures. Previous experience with sorbents in flue gas has allowed for judicious selection of potential high-temperature candidate sorbents. The capacities of many sorbents for elemental mercury from nitrogen, as well as from four different simulated fuel gases at temperatures of 204-371{sup o}C, have been determined. The simulated fuel gas compositions contain varying concentrations of carbon monoxide, hydrogen, carbon dioxide, moisture, and hydrogen sulfide. Promising high-temperature sorbent candidates have been identified. Palladium sorbents seem to be the most promising for high-temperature capture of mercury and other trace elements from fuel gases. A collaborative research and development agreement has been initiated between the Department of Energy's National Energy Technology Laboratory (NETL) and Johnson Matthey for optimization of the sorbents for trace element capture from high-temperature fuel gas. Future directions for mercury sorbent development for fuel gas application will be discussed.

  4. Gasification Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist.Newof EnergyFunding OpportunityF

  5. Model predictive control system and method for integrated gasification combined cycle power generation

    DOE Patents [OSTI]

    Kumar, Aditya; Shi, Ruijie; Kumar, Rajeeva; Dokucu, Mustafa

    2013-04-09T23:59:59.000Z

    Control system and method for controlling an integrated gasification combined cycle (IGCC) plant are provided. The system may include a controller coupled to a dynamic model of the plant to process a prediction of plant performance and determine a control strategy for the IGCC plant over a time horizon subject to plant constraints. The control strategy may include control functionality to meet a tracking objective and control functionality to meet an optimization objective. The control strategy may be configured to prioritize the tracking objective over the optimization objective based on a coordinate transformation, such as an orthogonal or quasi-orthogonal projection. A plurality of plant control knobs may be set in accordance with the control strategy to generate a sequence of coordinated multivariable control inputs to meet the tracking objective and the optimization objective subject to the prioritization resulting from the coordinate transformation.

  6. Method and system to estimate variables in an integrated gasification combined cycle (IGCC) plant

    DOE Patents [OSTI]

    Kumar, Aditya; Shi, Ruijie; Dokucu, Mustafa

    2013-09-17T23:59:59.000Z

    System and method to estimate variables in an integrated gasification combined cycle (IGCC) plant are provided. The system includes a sensor suite to measure respective plant input and output variables. An extended Kalman filter (EKF) receives sensed plant input variables and includes a dynamic model to generate a plurality of plant state estimates and a covariance matrix for the state estimates. A preemptive-constraining processor is configured to preemptively constrain the state estimates and covariance matrix to be free of constraint violations. A measurement-correction processor may be configured to correct constrained state estimates and a constrained covariance matrix based on processing of sensed plant output variables. The measurement-correction processor is coupled to update the dynamic model with corrected state estimates and a corrected covariance matrix. The updated dynamic model may be configured to estimate values for at least one plant variable not originally sensed by the sensor suite.

  7. Damage monitoring of refractory wall in a generic entrained-bed slagging gasification system

    E-Print Network [OSTI]

    Ray, Asok

    INTRODUCTION Modern day gasification plants offer a versatile and clean way to convert coal and other that gasification will be a major source of clean-fuel technology (e.g. US Department of Energy's Future- Gen.Forexample,a carbon-based feedstock (e.g. coal) is typically exposed to hot steam and carefully controlled amounts

  8. Modeling the Performance, Emissions, and Cost of an Entrained-Flow Gasification Combined Cycle System Using

    E-Print Network [OSTI]

    Frey, H. Christopher

    1 Modeling the Performance, Emissions, and Cost of an Entrained-Flow Gasification Combined Cycle Carolina State University ABSTRACT Gasification is a globally emerging technology in commercial markets for the conversion of a variety of feedstocks, including coal, heavy residue oil, biomass, solid waste, and others

  9. Instrumentation and Evaluation of a Pilot Scale Fluidized Bed Biomass Gasification System

    E-Print Network [OSTI]

    Maglinao, Amado L

    2009-12-04T23:59:59.000Z

    A pilot scale fluidized bed biomass gasifier developed at Texas A&M University in College Station, Texas was instrumented with thermocouples, pressure transducers and motor controllers for monitoring gasification temperature and pressure, air flow...

  10. Instrumentation and Evaluation of a Pilot Scale Fluidized Bed Biomass Gasification System 

    E-Print Network [OSTI]

    Maglinao, Amado L

    2009-12-04T23:59:59.000Z

    A pilot scale fluidized bed biomass gasifier developed at Texas A&M University in College Station, Texas was instrumented with thermocouples, pressure transducers and motor controllers for monitoring gasification temperature and pressure, air flow...

  11. Assessment of coal gasification/hot gas cleanup based advanced gas turbine systems

    SciTech Connect (OSTI)

    Not Available

    1990-12-01T23:59:59.000Z

    The major objectives of the joint SCS/DOE study of air-blown gasification power plants with hot gas cleanup are to: (1) Evaluate various power plant configurations to determine if an air-blown gasification-based power plant with hot gas cleanup can compete against pulverized coal with flue gas desulfurization for baseload expansion at Georgia Power Company's Plant Wansley; (2) determine if air-blown gasification with hot gas cleanup is more cost effective than oxygen-blown IGCC with cold gas cleanup; (3) perform Second-Law/Thermoeconomic Analysis of air-blown IGCC with hot gas cleanup and oxygen-blown IGCC with cold gas cleanup; (4) compare cost, performance, and reliability of IGCC based on industrial gas turbines and ISTIG power island configurations based on aeroderivative gas turbines; (5) compare cost, performance, and reliability of large (400 MW) and small (100 to 200 MW) gasification power plants; and (6) compare cost, performance, and reliability of air-blown gasification power plants using fluidized-bed gasifiers to air-blown IGCC using transport gasification and pressurized combustion.

  12. Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems

    SciTech Connect (OSTI)

    Gopala N. Krishnan; Ripudaman Malhotra; Esperanza Alvarez; Kai-Hung Lau; Angel Sanjurjo

    2006-06-01T23:59:59.000Z

    Heat-exchangers, particle filters, turbines, and other components in integrated coal gasification combined cycle system must withstand the highly sulfiding conditions of the high-temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high alloy materials are used. Deposition of a suitable coating on a low-cost alloy may improve its resistance to such sulfidation attack, and decrease capital and operating costs. The alloys used in the gasifier service include austenitic and ferritic stainless steels, nickel-chromium-iron alloys, and expensive nickel-cobalt alloys. In previous tests, we had frequently encountered problems with our steam generator that were exacerbated by the very low flow rates that we needed. During this period we installed a new computer-controlled system for injecting water into the steam generator that eliminated this problem. We also tested alloy coupons coated by using the improved procedures described in our last quarterly report. Most of these coatings were nitrided Ti and Ta coatings, either by themselves, or sometimes with barrier layers of Al and Si nitrides. The samples were tested for 300 h at 900 C in a gas stream designed to mimic the environment in the high temperature heat recovery unit (HTHRU). Three samples that showed least corrosion were exposed for an additional 100 h.

  13. Coal Gasification for Power Generation, 3. edition

    SciTech Connect (OSTI)

    NONE

    2007-11-15T23:59:59.000Z

    The report provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered include: an overview of Coal Generation including its history, the current market environment, and the status of coal gasification; a description of gasification technology including processes and systems; an analysis of the key business factors that are driving increased interest in coal gasification; an analysis of the barriers that are hindering the implementation of coal gasification projects; a discussion of Integrated Gasification Combined Cycle (IGCC) technology; an evaluation of IGCC versus other generation technologies; a discussion of IGCC project development options; a discussion of the key government initiatives supporting IGCC development; profiles of the key gasification technology companies participating in the IGCC market; and, a detailed description of existing and planned coal IGCC projects.

  14. Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems

    SciTech Connect (OSTI)

    Gopala N. Krishnan; Ripudaman Malhotra; Esperanza Alvarez; Kai-Hung Lau; Angel Sanjurjo

    2005-12-01T23:59:59.000Z

    Heat exchangers, particle filters, turbines, and other components in an integrated coal gasification combined cycle system must withstand the highly sulfiding conditions of the high-temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high-alloy materials are used. Deposition of a suitable coating on a low-cost alloy may improve its resistance to such sulfidation attack, and decrease capital and operating costs. The alloys used in the gasifier service include austenitic and ferritic stainless steels, nickel-chromium-iron alloys, and expensive nickel-cobalt alloys. During this reporting period, we conducted a simulated gasifier test primarily with TiN-coated steel samples. Although the test showed these coatings to offer significant protection against corrosion, they also revealed a lack of uniformity in the coatings. We spent a considerable amount of effort improving our coatings procedure as well as the fluidized bed reactor and its heater. Based on the results collected thus far, we selected 12 samples and sent them to ConocoPhillips for testing in their gasifier at the Wabash River Energy plant.

  15. GASIFICATION FOR DISTRIBUTED GENERATION

    SciTech Connect (OSTI)

    Ronald C. Timpe; Michael D. Mann; Darren D. Schmidt

    2000-05-01T23:59:59.000Z

    A recent emphasis in gasification technology development has been directed toward reduced-scale gasifier systems for distributed generation at remote sites. The domestic distributed power generation market over the next decade is expected to be 5-6 gigawatts per year. The global increase is expected at 20 gigawatts over the next decade. The economics of gasification for distributed power generation are significantly improved when fuel transport is minimized. Until recently, gasification technology has been synonymous with coal conversion. Presently, however, interest centers on providing clean-burning fuel to remote sites that are not necessarily near coal supplies but have sufficient alternative carbonaceous material to feed a small gasifier. Gasifiers up to 50 MW are of current interest, with emphasis on those of 5-MW generating capacity. Internal combustion engines offer a more robust system for utilizing the fuel gas, while fuel cells and microturbines offer higher electric conversion efficiencies. The initial focus of this multiyear effort was on internal combustion engines and microturbines as more realistic near-term options for distributed generation. In this project, we studied emerging gasification technologies that can provide gas from regionally available feedstock as fuel to power generators under 30 MW in a distributed generation setting. Larger-scale gasification, primarily coal-fed, has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries. Commercial-scale gasification activities are under way at 113 sites in 22 countries in North and South America, Europe, Asia, Africa, and Australia, according to the Gasification Technologies Council. Gasification studies were carried out on alfalfa, black liquor (a high-sodium waste from the pulp industry), cow manure, and willow on the laboratory scale and on alfalfa, black liquor, and willow on the bench scale. Initial parametric tests evaluated through reactivity and product composition were carried out on thermogravimetric analysis (TGA) equipment. These tests were evaluated and then followed by bench-scale studies at 1123 K using an integrated bench-scale fluidized-bed gasifier (IBG) which can be operated in the semicontinuous batch mode. Products from tests were solid (ash), liquid (tar), and gas. Tar was separated on an open chromatographic column. Analysis of the gas product was carried out using on-line Fourier transform infrared spectroscopy (FT-IR). For selected tests, gas was collected periodically and analyzed using a refinery gas analyzer GC (gas chromatograph). The solid product was not extensively analyzed. This report is a part of a search into emerging gasification technologies that can provide power under 30 MW in a distributed generation setting. Larger-scale gasification has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries, and it is probable that scaled-down applications for use in remote areas will become viable. The appendix to this report contains a list, description, and sources of currently available gasification technologies that could be or are being commercially applied for distributed generation. This list was gathered from current sources and provides information about the supplier, the relative size range, and the status of the technology.

  16. Life cycle assessment of a biomass gasification combined-cycle power system

    SciTech Connect (OSTI)

    Mann, M.K.; Spath, P.L.

    1997-12-01T23:59:59.000Z

    The potential environmental benefits from biomass power are numerous. However, biomass power may also have some negative effects on the environment. Although the environmental benefits and drawbacks of biomass power have been debated for some time, the total significance has not been assessed. This study serves to answer some of the questions most often raised in regard to biomass power: What are the net CO{sub 2} emissions? What is the energy balance of the integrated system? Which substances are emitted at the highest rates? What parts of the system are responsible for these emissions? To provide answers to these questions, a life cycle assessment (LCA) of a hypothetical biomass power plant located in the Midwest United States was performed. LCA is an analytical tool for quantifying the emissions, resource consumption, and energy use, collectively known as environmental stressors, that are associated with converting a raw material to a final product. Performed in conjunction with a technoeconomic feasibility study, the total economic and environmental benefits and drawbacks of a process can be quantified. This study complements a technoeconomic analysis of the same process, reported in Craig and Mann (1996) and updated here. The process studied is based on the concept of power Generation in a biomass integrated gasification combined cycle (BIGCC) plant. Broadly speaking, the overall system consists of biomass production, its transportation to the power plant, electricity generation, and any upstream processes required for system operation. The biomass is assumed to be supplied to the plant as wood chips from a biomass plantation, which would produce energy crops in a manner similar to the way food and fiber crops are produced today. Transportation of the biomass and other materials is by both rail and truck. The IGCC plant is sized at 113 MW, and integrates an indirectly-heated gasifier with an industrial gas turbine and steam cycle. 63 refs., 34 figs., 32 tabs.

  17. The Mansfield Two-Stage, Low BTU Gasification System: Report of Operations 

    E-Print Network [OSTI]

    Blackwell, L. T.; Crowder, J. T.

    1983-01-01T23:59:59.000Z

    The least expensive way to produce gas from coal is by low Btu gasification, a process by which coal is converted to carbon monoxide and hydrogen by reacting it with air and steam. Low Btu gas, which is used near its point of production, eliminates...

  18. Diffusion Coatings for Corrosion-Resistant Components in Coal Gasification Systems

    SciTech Connect (OSTI)

    Gopala N. Krishnan; Ripudaman Malhotra; Esperanza Alvarez; Kai-Hung Lau; Angel Sanjurjo

    2006-01-01T23:59:59.000Z

    Heat-exchangers, particle filters, turbines, and other components in integrated coal gasification combined cycle system must withstand the highly sulfiding conditions of the high-temperature coal gas over an extended period of time. The performance of components degrades significantly with time unless expensive high alloy materials are used. Deposition of a suitable coating on a low-cost alloy may improve its resistance to such sulfidation attack, and decrease capital and operating costs. The alloys used in the gasifier service include austenitic and ferritic stainless steels, nickel-chromium-iron alloys, and expensive nickel-cobalt alloys. During this period we tested coated alloy coupons under conditions designed to mimic the conditions in the filter unit after the high-temperature heat recovery unit (HTHRU). The filter unit is another important area where corrosion has caused unscheduled downtime, and the remedy has been the use of sintered metal tubes made of expensive alloys such as inconel. The objective of our test was to determine if those coatings on 400-series steel that were not able to withstand the harsher conditions of the HTHRU, may be sufficiently resistant for use in the filter unit, at the reduced temperatures. Indeed, most of our coatings survived well; the exceptions were the coated porous samples of SS316. We continued making improvements to our coatings apparatus and the procedure began during the last quarter. As a result of these modifications, the coupons we are now producing are uniform. We describe the improved procedure for preparing diffusion coatings. Finally, because porous samples of steel in grades other than SS316 are not readily available, we also decided to procure SS409 powder and fabricate our own sintered porous coupons.

  19. 2007 gasification technologies conference papers

    SciTech Connect (OSTI)

    NONE

    2007-07-01T23:59:59.000Z

    Sessions covered: gasification industry roundtable; the gasification market in China; gasification for power generation; the gasification challenge: carbon capture and use storage; industrial and polygeneration applications; gasification advantage in refinery applications; addressing plant performance; reliability and availability; gasification's contribution to supplementing gaseous and liquid fuels supplies; biomass gasification for fuel and power markets; and advances in technology-research and development

  20. Fluidized bed gasification of agricultural residue 

    E-Print Network [OSTI]

    Groves, John David

    1979-01-01T23:59:59.000Z

    is the only energy derived from such a system. The biomass energy project, of' which this re- search into gasification is a part, was designed to investi- gate both combustion and gasification as means to recover energy from agricultural wastes...FLUIDIZED BED GASIFICATION OF AGRICULTURAL RESIDUES A Thesis by JOHN DAVID GROVES Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May 1979 Major...

  1. Analysis of integrating compressed air energy storage concepts with coal gasification/combined-cycle systems for continuous power production

    SciTech Connect (OSTI)

    Nakhamkin, M.; Patel, M.; Andersson, L. (Energy Storage and Power Consultants, Inc., Mountainside, NJ (United States))

    1992-12-01T23:59:59.000Z

    A previous study sponsored by EPRI concluded that integrating a compressed-air energy storage (CAES) plant with a coal-gasification system (CGS) can reduce the required capacity and cost of the expensive gasification system. The results showed that when compared at an equal plant capacity, the capital cost of the CGS portion of the integrated CAES/CGS plant can be reduced by as much as 30% relative to the same portion of an integrated gasification combined cycle (IGCC) plant. Furthermore, the capital cost of the CAES/CGS.plant, configured as a peaking unit, was found to be slightly lower than that of the base-load IGCC plant. However, the overall economics of the CAES/CGS plant were adversely affected by the low capacity factor of the peak-load service, and ultimately, were found to be less attractive than the IGCC plant. The main objective of this study was to develop and analyze integrated CAES/CGS power plant concepts which provide for continuous (around-the-clock) operation of both the CAES reheat turboexpander train and the CGS facility. The developed concepts also provide utility-load management functions by driving the CAES compressor trains with off-peak electricity supplied through the grid. EPRI contracted with Energy Storage Power Consultants, Inc. (ESPC) to develop conceptual designs, optimized performance characteristics, and preliminary cost data for these CAES/CGS concepts, and to provide a technical and cost comparison to the IGCC plant. The CAES/CGS concepts developed by ESPC for the current study contrast from those of Reference 1.

  2. Gasification Research BIOENERGY PROGRAM

    E-Print Network [OSTI]

    Gasification Research BIOENERGY PROGRAM Description Researchers inthe@tamu.edu Skid-mounted gasifier: 1.8 tons-per-day pilot unit Gasification of cotton gin trash The new Texas A

  3. Gasification: redefining clean energy

    SciTech Connect (OSTI)

    NONE

    2008-05-15T23:59:59.000Z

    This booklet gives a comprehensive overview of how gasification is redefining clean energy, now and in the future. It informs the general public about gasification in a straight-forward, non-technical manner.

  4. Autothermal coal gasification

    SciTech Connect (OSTI)

    Konkol. W.; Ruprecht, P.; Cornils, B.; Duerrfeld, R.; Langhoff, J.

    1982-03-01T23:59:59.000Z

    Test data from the Ruhrchemie/Ruhrkohle Texaco coal gasification demonstration plant at Oberhausen are reported. (5 refs.)

  5. 2010 Worldwide Gasification Database

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The 2010 Worldwide Gasification Database describes the current world gasification industry and identifies near-term planned capacity additions. The database lists gasification projects and includes information (e.g., plant location, number and type of gasifiers, syngas capacity, feedstock, and products). The database reveals that the worldwide gasification capacity has continued to grow for the past several decades and is now at 70,817 megawatts thermal (MWth) of syngas output at 144 operating plants with a total of 412 gasifiers.

  6. PNNL Coal Gasification Research

    SciTech Connect (OSTI)

    Reid, Douglas J.; Cabe, James E.; Bearden, Mark D.

    2010-07-28T23:59:59.000Z

    This report explains the goals of PNNL in relation to coal gasification research. The long-term intent of this effort is to produce a syngas product for use by internal Pacific Northwest National Laboratory (PNNL) researchers in materials, catalysts, and instrumentation development. Future work on the project will focus on improving the reliability and performance of the gasifier, with a goal of continuous operation for 4 hours using coal feedstock. In addition, system modifications to increase operational flexibility and reliability or accommodate other fuel sources that can be used for syngas production could be useful.

  7. Coal gasification system with a modulated on/off control system

    DOE Patents [OSTI]

    Fasching, George E. (Morgantown, WV)

    1984-01-01T23:59:59.000Z

    A modulated control system is provided for improving regulation of the bed level in a fixed-bed coal gasifier into which coal is fed from a rotary coal feeder. A nuclear bed level gauge using a cobalt source and an ion chamber detector is used to detect the coal bed level in the gasifier. The detector signal is compared to a bed level set point signal in a primary controller which operates in proportional/integral modes to produce an error signal. The error signal is modulated by the injection of a triangular wave signal of a frequency of about 0.0004 Hz and an amplitude of about 80% of the primary deadband. The modulated error signal is fed to a triple-deadband secondary controller which jogs the coal feeder speed up or down by on/off control of a feeder speed change driver such that the gasifier bed level is driven toward the set point while preventing excessive cycling (oscillation) common in on/off mode automatic controllers of this type. Regulation of the bed level is achieved without excessive feeder speed control jogging.

  8. Desulfurization of fuel gases in fluidized bed gasification and hot fuel gas cleanup systems

    DOE Patents [OSTI]

    Steinberg, M.; Farber, G.; Pruzansky, J.; Yoo, H.J.; McGauley, P.

    1983-08-26T23:59:59.000Z

    A problem with the commercialization of fluidized bed gasification is that vast amounts of spent sorbent are generated if the sorbent is used on a once-through basis, especially if high sulfur coals are burned. The requirements of a sorbent for regenerative service in the FBG process are: (1) it must be capable of reducing the sulfur containing gas concentration of the FBG flue gas to within acceptable environmental standards; (2) it must not lose its reactivity on cyclic sulfidation and regeneration; (3) it must be capable of regeneration with elimination of substantially all of its sulfur content; (4) it must have good attrition resistance; and, (5) its cost must not be prohibitive. It has now been discovered that calcium silicate pellets, e.g., Portland cement type III pellets meet the criteria aforesaid. Calcium silicate removes COS and H/sub 2/S according to the reactions given to produce calcium sulfide silicate. The sulfur containing product can be regenerated using CO/sub 2/ as the regenerant. The sulfur dioxide can be conveniently reduced to sulfur with hydrogen or carbon for market or storage. The basic reactions in the process of this invention are the reactions with calcium silicate given in the patent. A convenient and inexpensive source of calcium silicate is Portland cement. Portland cement is a readily available, widely used construction meterial.

  9. Integrated supercritical water gasification combined cycle (IGCC) systems for improved performance and reduced operating costs in existing plants

    SciTech Connect (OSTI)

    Tolman, R.; Parkinson, W.J.

    1999-07-01T23:59:59.000Z

    A revolutionary hydrothermal heat recovery steam generator (HRSG) is being developed to produce clean fuels for gas turbines from slurries and emulsions of opportunity fuels. Water can be above 80% by weight and solids below 20%, including coal fines, coal water fuels, biomass, composted municipal refuse, sewage sludge and bitumen/Orimulsion. The patented HRSG tubes use a commercial method of particle scrubbing to improve heat transfer and prevent corrosion and deposition on heat transfer surfaces. A continuous-flow pilot plant is planned to test the HRSG over a wide range of operating conditions, including the supercritical conditions of water, above 221 bar (3,205 psia) and 374 C (705 F). Bench scale data shows, that supercritical water gasification below 580 C (1,076 F) and low residence time without catalysts or an oxidizer can produce a char product that can contain carbon up to the amount of fixed carbon in the proximate analysis of the solids in the feed. This char can be burned with coal in an existing combustion system to provide the heat required for gasification. The new HRSG tubes can be retrofitted into existing power plant boilers for repowering of existing plants for improved performance and reduced costs. A special condensing turbine allows final low-temperature cleaning and maintains quality and combustibility of the fuel vapor for modern gas turbine in the new Vapor Transmission Cycle (VTC). Increased power output and efficiency can be provided for existing plants, while reducing fuel costs. A preliminary computer-based process simulation model has been prepared that includes material and energy balances that simulate commercial-scale operations of the VTC on sewage sludge and coal. Results predict over 40% HHV thermal efficiency to electric power from sewage sludge at more than 83% water by weight. The system appears to become autothermal (no supplemental fuel required) at about 35% fixed carbon in the feed. Thus, bituminous and lignite coal slurries could be gasified at less than 25% coal and more than 75% water. Preliminary life cycle cost analyses indicate that disposal fees for sewage sludge improve operating economics over fuel that must be purchased, the cost and schedule advantages of natural gas-fired combined cycle systems are preserved. Sensitivity analyses show that increasing capital costs by 50% can be offset by an increase in sewage sludge disposal fees of $10/metric ton.

  10. 2007 gasification technologies workshop papers

    SciTech Connect (OSTI)

    NONE

    2007-03-15T23:59:59.000Z

    Topics covered in this workshop are fundamentals of gasification, carbon capture, reviews of financial and regulatory incentives, coal to liquids, and focus on gasification in the Western US.

  11. NETL F 451.1-1/1 Categorical Exclusion (CX) Designation Form

    Broader source: Energy.gov (indexed) [DOE]

    4.5 months Grand Forks, ND Testing of Indian Coal in a Transport Reactor Integrated Gasification (TRIG) System Conduct a 200-hr oxygen-blown gasification test on two different...

  12. Development of an Integrated Multi-Contaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems

    SciTech Connect (OSTI)

    Howard Meyer

    2010-11-30T23:59:59.000Z

    This project met the objective to further the development of an integrated multi-contaminant removal process in which H2S, NH3, HCl and heavy metals including Hg, As, Se and Cd present in the coal-derived syngas can be removed to specified levels in a single/integrated process step. The process supports the mission and goals of the Department of Energyâ??s Gasification Technologies Program, namely to enhance the performance of gasification systems, thus enabling U.S. industry to improve the competitiveness of gasification-based processes. The gasification program will reduce equipment costs, improve process environmental performance, and increase process reliability and flexibility. Two sulfur conversion concepts were tested in the laboratory under this project, i.e., the solventbased, high-pressure University of California Sulfur Recovery Process â?? High Pressure (UCSRP-HP) and the catalytic-based, direct oxidation (DO) section of the CrystaSulf-DO process. Each process required a polishing unit to meet the ultra-clean sulfur content goals of <50 ppbv (parts per billion by volume) as may be necessary for fuel cells or chemical production applications. UCSRP-HP was also tested for the removal of trace, non-sulfur contaminants, including ammonia, hydrogen chloride, and heavy metals. A bench-scale unit was commissioned and limited testing was performed with simulated syngas. Aspen-Plus®-based computer simulation models were prepared and the economics of the UCSRP-HP and CrystaSulf-DO processes were evaluated for a nominal 500 MWe, coal-based, IGCC power plant with carbon capture. This report covers the progress on the UCSRP-HP technology development and the CrystaSulf-DO technology.

  13. Gasification: A Cornerstone Technology

    SciTech Connect (OSTI)

    Gary Stiegel

    2008-03-26T23:59:59.000Z

    NETL is a leader in the science and technology of gasification - a process for the conversion of carbon-based materials such as coal into synthesis gas (syngas) that can be used to produce clean electrical energy, transportation fuels, and chemicals efficiently and cost-effectively using domestic fuel resources. Gasification is a cornerstone technology of 21st century zero emissions powerplants

  14. Gasification: A Cornerstone Technology

    ScienceCinema (OSTI)

    Gary Stiegel

    2010-01-08T23:59:59.000Z

    NETL is a leader in the science and technology of gasification - a process for the conversion of carbon-based materials such as coal into synthesis gas (syngas) that can be used to produce clean electrical energy, transportation fuels, and chemicals efficiently and cost-effectively using domestic fuel resources. Gasification is a cornerstone technology of 21st century zero emissions powerplants

  15. Autothermal coal gasification

    SciTech Connect (OSTI)

    Konkol, W.; Ruprecht, P.; Cornils, B.; Duerrfeld, R.; Langhoff, J.

    1982-03-01T23:59:59.000Z

    This paper presents test results of a pilot plant study of coal gasification system based on the process developed by Texaco. This process has been improved by the project partners Ruhrchenie A.G. and Ruhrkohle A.C. in West Germany and tested in a demonstration plant that operated for more than 10,000 hours, converting over 50,000 tons of coal into gas. The aim was to develop a process that would be sufficiently flexible when used at the commercial level to incorporate all of the advantages inherent in the diverse processes of the 'first generation' - fixed bed, fluidized bed and entrained bed processes - but would be free of the disadvantages of these processes. Extensive test results are tabulated and evaluated. Forecast for future development is included. 5 refs.

  16. Coal gasification vessel

    DOE Patents [OSTI]

    Loo, Billy W. (Oakland, CA)

    1982-01-01T23:59:59.000Z

    A vessel system (10) comprises an outer shell (14) of carbon fibers held in a binder, a coolant circulation mechanism (16) and control mechanism (42) and an inner shell (46) comprised of a refractory material and is of light weight and capable of withstanding the extreme temperature and pressure environment of, for example, a coal gasification process. The control mechanism (42) can be computer controlled and can be used to monitor and modulate the coolant which is provided through the circulation mechanism (16) for cooling and protecting the carbon fiber and outer shell (14). The control mechanism (42) is also used to locate any isolated hot spots which may occur through the local disintegration of the inner refractory shell (46).

  17. Gasification Technologie: Opportunities & Challenges

    SciTech Connect (OSTI)

    Breault, R.

    2012-01-01T23:59:59.000Z

    This course has been put together to provide a single source document that not only reviews the historical development of gasification but also compares the process to combustion. It also provides a short discussion on integrated gasification and combined cycle processes. The major focus of the course is to describe the twelve major gasifiers being developed today. The hydrodynamics and kinetics of each are reviewed along with the most likely gas composition from each of the technologies when using a variety of fuels under different conditions from air blown to oxygen blown and atmospheric pressure to several atmospheres. If time permits, a more detailed discussion of low temperature gasification will be included.

  18. Overview of peat gasification

    SciTech Connect (OSTI)

    Punwani, D.V.

    1981-01-01T23:59:59.000Z

    The results of recent research show that peat is an excellent raw material for making synthetic fuels. Therefore, the objective of most of the recent efforts in various countries is to produce synthetic fuels from peat. This paper presents an overview of the worldwide activity relating to research and development for peat gasification. The review includes thermal as well as biological peat gasification processes. 21 refs.

  19. ANG coal gasification project management control system report. [Great Plains project

    SciTech Connect (OSTI)

    Not Available

    1981-01-01T23:59:59.000Z

    Much time, money and effort has been spent in the forefront of this project for project controls. The work breakdown structure for the systems has been custom designed. The systems, both manual and computerized, have been well scrutinized and chosen by ANG to represent the most cost effective and efficient way of controlling a project the magnitude of $1.5 billion. These systems have been developed in a manner so that information can be gathered as detailed or as summarized as necessary, and in the most timely and expeditious ways.

  20. Fixed-bed gasification research using US coals. Volume 7. Gasification of Piney Tipple bituminous coal

    SciTech Connect (OSTI)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01T23:59:59.000Z

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report is the seventh volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Piney Tipple bituminous coal. The period of the gasification test was July 18-24, 1983. 6 refs., 20 figs., 17 tabs.

  1. Biomass Gasification Technology Assessment: Consolidated Report

    SciTech Connect (OSTI)

    Worley, M.; Yale, J.

    2012-11-01T23:59:59.000Z

    Harris Group Inc. (HGI) was commissioned by the National Renewable Energy Laboratory to assess gasification and tar reforming technologies. Specifically, the assessments focused on gasification and tar reforming technologies that are capable of producing a syngas suitable for further treatment and conversion to liquid fuels. HGI gathered sufficient information to analyze three gasification and tar reforming systems. This report summarizes the equipment, general arrangement of the equipment, operating characteristics, and operating severity for each technology. The order of magnitude capital cost estimates are supported by a basis-of-estimate write-up, which is also included in this report. The report also includes Microsoft Excel workbook models, which can be used to design and price the systems. The models can be used to analyze various operating capacities and pressures. Each model produces a material balance, equipment list, capital cost estimate, equipment drawings and preliminary general arrangement drawings. Example outputs of each model are included in the Appendices.

  2. The Caterpillar Coal Gasification Facility 

    E-Print Network [OSTI]

    Welsh, J.; Coffeen, W. G., III

    1983-01-01T23:59:59.000Z

    This paper is a review of one of America's premier coal gasification installations. The caterpillar coal gasification facility located in York, Pennsylvania is an award winning facility. The plant was recognized as the 'pace setter plant of the year...

  3. Sorption Mechanisms for Mercury Capture in Warm Post-Gasification Gas Clean-Up Systems

    SciTech Connect (OSTI)

    Jost Wendt; Sung Jun Lee; Paul Blowers

    2008-09-30T23:59:59.000Z

    The research was directed towards a sorbent injection/particle removal process where a sorbent may be injected upstream of the warm gas cleanup system to scavenge Hg and other trace metals, and removed (with the metals) within the warm gas cleanup process. The specific objectives of this project were to understand and quantify, through fundamentally based models, mechanisms of interaction between mercury vapor compounds and novel paper waste derived (kaolinite + calcium based) sorbents (currently marketed under the trade name MinPlus). The portion of the research described first is the experimental portion, in which sorbent effectiveness to scavenge metallic mercury (Hg{sup 0}) at high temperatures (>600 C) is determined as a function of temperature, sorbent loading, gas composition, and other important parameters. Levels of Hg{sup 0} investigated were in an industrially relevant range ({approx} 25 {micro}g/m{sup 3}) although contaminants were contained in synthetic gases and not in actual flue gases. A later section of this report contains the results of the complementary computational results.

  4. Biothermal gasification of biomass

    SciTech Connect (OSTI)

    Chynoweth, D.P.; Srivastava, V.J.; Henry, M.P.; Tarman, P.B.

    1980-01-01T23:59:59.000Z

    The BIOTHERMGAS Process is described for conversion of biomass, organic residues, and peat to substitute natural gas (SNG). This new process, under development at IGT, combines biological and thermal processes for total conversion of a broad variety of organic feeds (regardless of water or nutrient content). The process employs thermal gasification for conversion of refractory digester residues. Ammonia and other inorganic nutrients are recycled from the thermal process effluent to the bioconversion unit. Biomethanation and catalytic methanation are presented as alternative processes for methanation of thermal conversion product gases. Waste heat from the thermal component is used to supply the digester heat requirements of the bioconversion component. The results of a preliminary systems analysis of three possible applications of this process are presented: (1) 10,000 ton/day Bermuda grass plant with catalytic methanation; (2) 10,000 ton/day Bermuda grass plant with biomethanation; and (3) 1000 ton/day municipal solid waste (MSW) sewage sludge plant with biomethanation. The results indicate that for these examples, performance is superior to that expected for biological or thermal processes used separately. The results of laboratory studies presented suggest that effective conversion of thermal product gases can be accomplished by biomethanation.

  5. Coal gasification for power generation. 2nd ed.

    SciTech Connect (OSTI)

    NONE

    2006-10-15T23:59:59.000Z

    The report gives an overview of the opportunities for coal gasification in the power generation industry. It provides a concise look at the challenges faced by coal-fired generation, the ability of coal gasification to address these challenges, and the current state of IGCC power generation. Topics covered in the report include: An overview of coal generation including its history, the current market environment, and the status of coal gasification; A description of gasification technology including processes and systems; An analysis of the key business factors that are driving increased interest in coal gasification; An analysis of the barriers that are hindering the implementation of coal gasification projects; A discussion of Integrated Gasification Combined Cycle (IGCC) technology; An evaluation of IGCC versus other generation technologies; A discussion of IGCC project development options; A discussion of the key government initiatives supporting IGCC development; Profiles of the key gasification technology companies participating in the IGCC market; and A description of existing and planned coal IGCC projects.

  6. Production of Hydrogen from Underground Coal Gasification

    DOE Patents [OSTI]

    Upadhye, Ravindra S. (Pleasanton, CA)

    2008-10-07T23:59:59.000Z

    A system of obtaining hydrogen from a coal seam by providing a production well that extends into the coal seam; positioning a conduit in the production well leaving an annulus between the conduit and the coal gasification production well, the conduit having a wall; closing the annulus at the lower end to seal it from the coal gasification cavity and the syngas; providing at least a portion of the wall with a bifunctional membrane that serves the dual purpose of providing a catalyzing reaction and selectively allowing hydrogen to pass through the wall and into the annulus; and producing the hydrogen through the annulus.

  7. NETL: Coal Gasification Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |IsLoveReferenceAgenda Workshop AgendaGraphic of a

  8. Underground coal gasification. Presentations

    SciTech Connect (OSTI)

    NONE

    2007-07-01T23:59:59.000Z

    The 8 presentations are: underground coal gasification (UCG) and the possibilities for carbon management (J. Friedmann); comparing the economics of UCG with surface gasification technologies (E. Redman); Eskom develops UCG technology project (C. Gross); development and future of UCG in the Asian region (L. Walker); economically developing vast deep Powder River Basin coals with UCG (S. Morzenti); effectively managing UCG environmental issues (E. Burton); demonstrating modelling complexity of environmental risk management; and UCG research at the University of Queensland, Australia (A.Y. Klimenko).

  9. Optimum Design of Coal Gasification Plants

    E-Print Network [OSTI]

    Pohani, B. P.; Ray, H. P.; Wen, H.

    1982-01-01T23:59:59.000Z

    This paper deals with the optimum design of heat recovery systems using the Texaco Coal Gasification Process (TCGP). TCGP uses an entrained type gasifier and produces hot gases at approximately 2500oF with high heat flux. This heat is removed...

  10. Optimum Design of Coal Gasification Plants 

    E-Print Network [OSTI]

    Pohani, B. P.; Ray, H. P.; Wen, H.

    1982-01-01T23:59:59.000Z

    This paper deals with the optimum design of heat recovery systems using the Texaco Coal Gasification Process (TCGP). TCGP uses an entrained type gasifier and produces hot gases at approximately 2500oF with high heat flux. This heat is removed...

  11. Gasification of black liquor

    DOE Patents [OSTI]

    Kohl, Arthur L. (Woodland Hills, CA)

    1987-07-28T23:59:59.000Z

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediatley above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone.

  12. Gasification of black liquor

    DOE Patents [OSTI]

    Kohl, A.L.

    1987-07-28T23:59:59.000Z

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediately above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone. 2 figs.

  13. Environmental Permitting of a Low-BTU Coal Gasification Facility

    E-Print Network [OSTI]

    Murawczyk, C.; Stewart, J. T.

    1983-01-01T23:59:59.000Z

    that merits serious consideration since only relatively small modifications to the existing oil or gas burner system may be required, and boiler derating can be minimized. The environmental permitting and planning process for a low-Btu coal gasification...

  14. Environmental Permitting of a Low-BTU Coal Gasification Facility 

    E-Print Network [OSTI]

    Murawczyk, C.; Stewart, J. T.

    1983-01-01T23:59:59.000Z

    that merits serious consideration since only relatively small modifications to the existing oil or gas burner system may be required, and boiler derating can be minimized. The environmental permitting and planning process for a low-Btu coal gasification...

  15. Gasification Product Improvement Facility status

    SciTech Connect (OSTI)

    Carson, R.D.; Dixit, V.B.; Sadowski, R.S.; Thamaraichelvan, P.; Culberson, H.

    1995-11-01T23:59:59.000Z

    Department of Energy (DOE) has awarded a two phase contract for the construction of a Gasification Product Improvement Facility (GPIF) to develop an innovative air blown, dry bottom, pressurized fixed bed gasifier based on the patented PyGas{trademark} fixed bed process. The objective of the project is to provide a test site to support early commercialization of the Integrated Gasification Combined Cycle (IGCC) technology. The GPIF will be capable of processing run of mine high swelling coals that comprise 87% of all Eastern US coals. This program will generate useful scale up data that will be utilized to develop commercial size designs. The project will also support the development of a hot gas clean up subsystem and the gasifier infrastructure consisting of controls, special instrumentation and interconnects with Allegheny Power System`s host power plant, Fort Martin Station in Maidesville, West Virginia. This paper presents the status of the GPIF project. It describes the work performed in the past year on the PyGas process development, gasifier design, plant engineering/layout, tie in with the existing Fort Martin facility, procurement, site permitting and project scheduling.

  16. Advanced development of a pressurized ash agglomerating fluidized-bed coal gasification system. Quarterly progress report, April 1-June 30, 1982

    SciTech Connect (OSTI)

    None

    1982-10-21T23:59:59.000Z

    The overall objective of the Westinghouse coal gasification program is to demonstrate the viability of the Westinghouse pressurized, fluidized bed, gasification system for the production of medium-Btu fuel gas for syngas, electrical power generation, chemical feedstocks, or industrial fuels and to obtain performance and scaleup data for the process and hardware. Progress reports are presented for the following tasks: (1) operation and maintenance of the process development unit (PDU); (2) process analysis; (3) cold flow scaleup facility; (4) process and component engineering and design; and (5) laboratory support studies. Some of the highlights for this period are: TP-032-1, a single stage, oxygen-steam blown gasifier test was conducted in three operational phases from March 30, 1982 through May 2, 1982; TP-032-2 was conducted in two operational phases from May 20, 1982 through May 27, 1982; TP-032-1 and TP-032-2 successfully served as shakedown and demonstrations of the full cyclone cold wall; no visible deposits were found on the cold wall after processing highly fouling coals; samples of product gas produced during TP-032-1, were passed through four different scrubbing solutions and analyzed for 78 EPA primary organic pollutants, all of which were found to be below detection limits; TP-M004, a CO/sub 2/ tracer gas test, was initiated and completed; data analysis of test TP-M002-2 was completed and conclusions are summarized in this report; design, procurement and fabrication of the solids injection device were completed; laboratory studies involved gas-solids flow modeling and coal/ash behavior. 2 references, 11 figures, 39 tables.

  17. Opportunities in underground coal gasification

    SciTech Connect (OSTI)

    Bloomstran, M.A.; Davis, B.E.

    1984-06-01T23:59:59.000Z

    A review is presented of the results obtained on DOE-sponsored field tests of underground coal gasification in steeply-dipping beds at Rawlins, Wyoming. The coal gas composition, process parameters, and process economics are described. Steeply-dipping coal resources, which are not economically mineable using conventional coal mining methods, are identified and potential markets for underground coal gasification products are discussed. It is concluded that in-situ gasification in steeply-dipping deposits should be considered for commercialization.

  18. CATALYTIC GASIFICATION OF COAL USING EUTECTIC SALT MIXTURES

    SciTech Connect (OSTI)

    Dr. Yaw D. Yeboah; Dr. Yong Xu; Dr. Atul Sheth; Dr. Pradeep Agrawal

    2001-12-01T23:59:59.000Z

    The Gas Research Institute (GRI) estimates that by the year 2010, 40% or more of U.S. gas supply will be provided by supplements including substitute natural gas (SNG) from coal. These supplements must be cost competitive with other energy sources. The first generation technologies for coal gasification e.g. the Lurgi Pressure Gasification Process and the relatively newer technologies e.g. the KBW (Westinghouse) Ash Agglomerating Fluidized-Bed, U-Gas Ash Agglomerating Fluidized-Bed, British Gas Corporation/Lurgi Slagging Gasifier, Texaco Moving-Bed Gasifier, and Dow and Shell Gasification Processes, have several disadvantages. These disadvantages include high severities of gasification conditions, low methane production, high oxygen consumption, inability to handle caking coals, and unattractive economics. Another problem encountered in catalytic coal gasification is deactivation of hydroxide forms of alkali and alkaline earth metal catalysts by oxides of carbon (CO{sub x}). To seek solutions to these problems, a team consisting of Clark Atlanta University (CAU, a Historically Black College and University, HBCU), the University of Tennessee Space Institute (UTSI) and Georgia Institute of Technology (Georgia Tech) proposed to identify suitable low melting eutectic salt mixtures for improved coal gasification. The research objectives of this project were to: Identify appropriate eutectic salt mixture catalysts for coal gasification; Assess agglomeration tendency of catalyzed coal; Evaluate various catalyst impregnation techniques to improve initial catalyst dispersion; Determine catalyst dispersion at high carbon conversion levels; Evaluate effects of major process variables (such as temperature, system pressure, etc.) on coal gasification; Evaluate the recovery, regeneration and recycle of the spent catalysts; and Conduct an analysis and modeling of the gasification process to provide better understanding of the fundamental mechanisms and kinetics of the process.

  19. Pioneering Gasification Plants | Department of Energy

    Energy Savers [EERE]

    lighting street lights fueled by "town gas," frequently the product of early forms of coal gasification. Gasification of fuel also provided fuel for steel mills, and toward the...

  20. Hydrogen Production Cost Estimate Using Biomass Gasification...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cost Estimate Using Biomass Gasification: Independent Review Hydrogen Production Cost Estimate Using Biomass Gasification: Independent Review This independent review is the...

  1. Coal-Biomass Feed and Gasification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal-Biomass Feed and Gasification The Coal-Biomass Feed and Gasification Key Technology is advancing scientific knowledge of the production of liquid hydrocarbon fuels from coal...

  2. Hydrogen Production Cost Estimate Using Biomass Gasification

    E-Print Network [OSTI]

    Hydrogen Production Cost Estimate Using Biomass Gasification National Renewable Energy Laboratory Panel, Hydrogen Production Cost Estimate Using Biomass Gasification To: Mr. Mark Ruth, NREL, DOE

  3. Coal Gasification and Transportation Fuels Magazine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gasification and Transportation Fuels Magazine Current Edition: Coal Gasification and Transportation Fuels Quarterly News, Vol.1, Issue 3 (Apr 2015) Archived Editions: Coal...

  4. intro to gasification | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gasifier Gasification Introduction Gasification is a technological process that can convert any carbonaceous (carbon-based) raw material such as coal into fuel gas, also known as...

  5. Market Assessment of Biomass Gasification and Combustion Technology for Small- and Medium-Scale Applications

    SciTech Connect (OSTI)

    Peterson, D.; Haase, S.

    2009-07-01T23:59:59.000Z

    This report provides a market assessment of gasification and direct combustion technologies that use wood and agricultural resources to generate heat, power, or combined heat and power (CHP) for small- to medium-scale applications. It contains a brief overview of wood and agricultural resources in the U.S.; a description and discussion of gasification and combustion conversion technologies that utilize solid biomass to generate heat, power, and CHP; an assessment of the commercial status of gasification and combustion technologies; a summary of gasification and combustion system economics; a discussion of the market potential for small- to medium-scale gasification and combustion systems; and an inventory of direct combustion system suppliers and gasification technology companies. The report indicates that while direct combustion and close-coupled gasification boiler systems used to generate heat, power, or CHP are commercially available from a number of manufacturers, two-stage gasification systems are largely in development, with a number of technologies currently in demonstration. The report also cites the need for a searchable, comprehensive database of operating combustion and gasification systems that generate heat, power, or CHP built in the U.S., as well as a national assessment of the market potential for the systems.

  6. Fixed-bed gasification research using US coals. Volume 9. Gasification of Elkhorn bituminous coal

    SciTech Connect (OSTI)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-05-01T23:59:59.000Z

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) group. This report is the ninth volume in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This specific report describes the gasification of Elkhorn bituminous coal. The period of gasificastion test was September 13 to October 12, 1983. 9 refs., 24 figs., 35 tabs.

  7. Simultaneous high-temperature removal of alkali and particulates in a pressurized gasification system. Final technical progress report, April 1981-July 1983

    SciTech Connect (OSTI)

    Mulik, P.R.; Alvin, M.A.; Bachovchin, D.M.

    1983-09-01T23:59:59.000Z

    This program is directed at performing experimental and analytical investigations, deriving system designs, and estimating costs to ascertain the feasibility of using aluminosilicate-based getters for controlling alkali in pressurized gasification systems. Its overall objective is to develop a plan for evaluating a scaled-up version of the gettering process as a unit operation or as an integral part of a particulate removal device. This report describes work completed on the four technical program tasks: Thermodynamic projections; Getter Selection and Qualification; System Performance Projections; and Program Definition for Concept Scale-up during the 27-month contract performance period. Work completed on the thermodynamic projections includes a data base update, development of alkali phase diagrams, and system performance projections. Getter selection and qualification efforts involved over 70 kinetic studies in which a leading candidate getter - emathlite - was selected and characterized. System performance projections identified a packed-bed configuration containing relatively large getter pellets as the preferred contacting device for a full-scale unit. For emathlite, we concluded that full-scale unit bed heights of 2 m or less would be required if we assume annual replacement on the basis of bed saturation capacity. Concept scale-up work involved defining the hardware and test program requirements for further development of the emathlite packed-bed system. 56 references, 80 figures, 74 tables.

  8. Biomass Gasification | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    gasification involve reducing costs associated with capital equipment and biomass feedstocks. Research to lower capital costs: If oxygen is used in the gasifier, capital...

  9. Gasification of black liquor

    SciTech Connect (OSTI)

    Kohl, A.L.

    1987-07-28T23:59:59.000Z

    A process is described for treating a concentrated aqueous black liquor carbonaceous material and alkali metal sulfur compounds to form a combustible gas and a sulfide-rich melt comprising: (a) providing a gasifier vessel maintained at a pressure of from about 1 to 50 atmospheres and containing a relatively shallow molten salt pool at its bottom within a sump equipped with an overflow discharge; (b) introducing into the top of the drying zone the concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds; (c) evaporating water from the concentrated aqueous black liquor in the drying zone by direct contact of the aqueous black liquor with the hot gas rising from the gasification zone to produce dried black liquor solids; (d) introducing a first portion of an oxygen-containing gas into the gas space in the gasification zone located below the drying zone immediately above the molten salt pool to partially oxidize and gasify a fraction of the carbonaceous material in the dried black liquor solids falling through the zone to form a hot combustible gas; (e) introducing a second portion of the oxygen-containing gas beneath the surface of the molten salt pool in an amount sufficient to cause gasification of essentially all carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool; (f) withdrawing the cooled combustible gas having a higher heating value of at least about 90 Btu/scf (dry basis) from an upper portion of the drying zone; and (g) withdrawing from the overflow discharge in the molten salt reduction zone a melt in which the sulfur content is predominantly in the form of alkali metal sulfide.

  10. Biomass Gasification Combined Cycle

    SciTech Connect (OSTI)

    Judith A. Kieffer

    2000-07-01T23:59:59.000Z

    Gasification combined cycle continues to represent an important defining technology area for the forest products industry. The ''Forest Products Gasification Initiative'', organized under the Industry's Agenda 2020 technology vision and supported by the DOE ''Industries of the Future'' program, is well positioned to guide these technologies to commercial success within a five-to ten-year timeframe given supportive federal budgets and public policy. Commercial success will result in significant environmental and renewable energy goals that are shared by the Industry and the Nation. The Battelle/FERCO LIVG technology, which is the technology of choice for the application reported here, remains of high interest due to characteristics that make it well suited for integration with the infrastructure of a pulp production facility. The capital cost, operating economics and long-term demonstration of this technology area key input to future economically sustainable projects and must be verified by the 200 BDT/day demonstration facility currently operating in Burlington, Vermont. The New Bern application that was the initial objective of this project is not currently economically viable and will not be implemented at this time due to several changes at and around the mill which have occurred since the inception of the project in 1995. The analysis shows that for this technology, and likely other gasification technologies as well, the first few installations will require unique circumstances, or supportive public policies, or both to attract host sites and investors.

  11. Conceptual design of a black liquor gasification pilot plant

    SciTech Connect (OSTI)

    Kelleher, E. G.

    1987-08-01T23:59:59.000Z

    In July 1985, Champion International completed a study of kraft black liquor gasification and use of the product gases in a combined cycle cogeneration system based on gas turbines. That study indicated that gasification had high potential as an alternative to recovery boiler technology and offered many advantages. This paper describes the design of the plant, the construction of the pilot plant, and finally presents data from operation of the plant.

  12. Fluidized bed gasification of agricultural residue

    E-Print Network [OSTI]

    Groves, John David

    1979-01-01T23:59:59.000Z

    and Kinetics Development of Gasification Systems Fixed Bed Gasifiers Fluidized Bed Gasifiers Fluidization 6 7 12 12 13 16 III DEVELOPMENT OF EXPERIMENTAL SYSTEM . . . 20 IV Feed Preparation and Analysis Experimental Apparatus Experimental Method..., wheat, and rice in Texas were produced at an average rate of 20 million tons (18 Tg) per year (LePori and Lacewell, 1977). The main impetus of the project being implemented is to design and build a fluidized bed combustion prototype with subsequent...

  13. GASIFICATION BASED BIOMASS CO-FIRING - PHASE I

    SciTech Connect (OSTI)

    Babul Patel; Kevin McQuigg; Robert F. Toerne

    2001-12-01T23:59:59.000Z

    Biomass gasification offers a practical way to use this locally available fuel source for co-firing traditional large utility boilers. The gasification process converts biomass into a low Btu producer gas that can be fed directly into the boiler. This strategy of co-firing is compatible with variety of conventional boilers including natural gas fired boilers as well as pulverized coal fired and cyclone boilers. Gasification has the potential to address all problems associated with the other types of co-firing with minimum modifications to the existing boiler systems. Gasification can also utilize biomass sources that have been previously unsuitable due to size or processing requirements, facilitating a reduction in the primary fossil fuel consumption in the boiler and thereby reducing the greenhouse gas emissions to the atmosphere.

  14. Gasification Plant Cost and Performance Optimization

    SciTech Connect (OSTI)

    Samuel Tam; Alan Nizamoff; Sheldon Kramer; Scott Olson; Francis Lau; Mike Roberts; David Stopek; Robert Zabransky; Jeffrey Hoffmann; Erik Shuster; Nelson Zhan

    2005-05-01T23:59:59.000Z

    As part of an ongoing effort of the U.S. Department of Energy (DOE) to investigate the feasibility of gasification on a broader level, Nexant, Inc. was contracted to perform a comprehensive study to provide a set of gasification alternatives for consideration by the DOE. Nexant completed the first two tasks (Tasks 1 and 2) of the ''Gasification Plant Cost and Performance Optimization Study'' for the DOE's National Energy Technology Laboratory (NETL) in 2003. These tasks evaluated the use of the E-GAS{trademark} gasification technology (now owned by ConocoPhillips) for the production of power either alone or with polygeneration of industrial grade steam, fuel gas, hydrocarbon liquids, or hydrogen. NETL expanded this effort in Task 3 to evaluate Gas Technology Institute's (GTI) fluidized bed U-GAS{reg_sign} gasifier. The Task 3 study had three main objectives. The first was to examine the application of the gasifier at an industrial application in upstate New York using a Southeastern Ohio coal. The second was to investigate the GTI gasifier in a stand-alone lignite-fueled IGCC power plant application, sited in North Dakota. The final goal was to train NETL personnel in the methods of process design and systems analysis. These objectives were divided into five subtasks. Subtasks 3.2 through 3.4 covered the technical analyses for the different design cases. Subtask 3.1 covered management activities, and Subtask 3.5 covered reporting. Conceptual designs were developed for several coal gasification facilities based on the fluidized bed U-GAS{reg_sign} gasifier. Subtask 3.2 developed two base case designs for industrial combined heat and power facilities using Southeastern Ohio coal that will be located at an upstate New York location. One base case design used an air-blown gasifier, and the other used an oxygen-blown gasifier in order to evaluate their relative economics. Subtask 3.3 developed an advanced design for an air-blown gasification combined heat and power facility based on the Subtask 3.2 design. The air-blown case was chosen since it was less costly and had a better return on investment than the oxygen-blown gasifier case. Under appropriate conditions, this study showed a combined heat and power air-blown gasification facility could be an attractive option for upgrading or expanding the utilities area of industrial facilities. Subtask 3.4 developed a base case design for a large lignite-fueled IGCC power plant that uses the advanced GE 7FB combustion turbine to be located at a generic North Dakota site. This plant uses low-level waste heat to dry the lignite that otherwise would be rejected to the atmosphere. Although this base case plant design is economically attractive, further enhancements should be investigated. Furthermore, since this is an oxygen-blown facility, it has the potential for capture and sequestration of CO{sub 2}. The third objective for Task 3 was accomplished by having NETL personnel working closely with Nexant and Gas Technology Institute personnel during execution of this project. Technology development will be the key to the long-term commercialization of gasification technologies. This will be important to the integration of this environmentally superior solid fuel technology into the existing mix of power plants and industrial facilities. As a result of this study, several areas have been identified in which research and development will further advance gasification technology. Such areas include improved system availability, development of warm-gas clean up technologies, and improved subsystem designs.

  15. Fluidized bed injection assembly for coal gasification

    DOE Patents [OSTI]

    Cherish, Peter (Bethel Park, PA); Salvador, Louis A. (Hempfield Township, Westmoreland County, PA)

    1981-01-01T23:59:59.000Z

    A coaxial feed system for fluidized bed coal gasification processes including an inner tube for injecting particulate combustibles into a transport gas, an inner annulus about the inner tube for injecting an oxidizing gas, and an outer annulus about the inner annulus for transporting a fluidizing and cooling gas. The combustibles and oxidizing gas are discharged vertically upward directly into the combustion jet, and the fluidizing and cooling gas is discharged in a downward radial direction into the bed below the combustion jet.

  16. Characterizing a lignite formation before and after an underground coal gasification experiment 

    E-Print Network [OSTI]

    Ahmed, Usman

    1981-01-01T23:59:59.000Z

    ) . Grid Break Up System for the Areal Model Pressure Drawdown (Semi-log Plot) on Well 9 (Post-Gasification). 24 25 27 31 16 Ei-Function Plot. Drawdown on Well 9 and Inter- ference on Wells 10, 13 and 18 (Post-Gasification) . . 32 17 Pressure... Drawdown (Semi-log Plot) on Well 10 (Post-Gasification). 34 18 Ei-Function Plot. Drawdown on Well 10 and Inter- ference on Wells 9, 13 and 18 (Post-Gasification). . . 35 ~Fi ure 19 LIST OF FIGURES (Continued) Pressure Drawdown (Semi-log Plot) on Well...

  17. Conceptual design report -- Gasification Product Improvement Facility (GPIF)

    SciTech Connect (OSTI)

    Sadowski, R.S.; Skinner, W.H.; House, L.S.; Duck, R.R. [CRS Sirrine Engineers, Inc., Greenville, SC (United States); Lisauskas, R.A.; Dixit, V.J. [Riley Stoker Corp., Worcester, MA (United States); Morgan, M.E.; Johnson, S.A. [PSI Technology Co., Andover, MA (United States). PowerServe Div.; Boni, A.A. [PSI-Environmental Instruments Corp., Andover, MA (United States)

    1994-09-01T23:59:59.000Z

    The problems heretofore with coal gasification and IGCC concepts have been their high cost and historical poor performance of fixed-bed gasifiers, particularly on caking coals. The Gasification Product Improvement Facility (GPIF) project is being developed to solve these problems through the development of a novel coal gasification invention which incorporates pyrolysis (carbonization) with gasification (fixed-bed). It employs a pyrolyzer (carbonizer) to avoid sticky coal agglomeration caused in the conventional process of gradually heating coal through the 400 F to 900 F range. In so doing, the coal is rapidly heated sufficiently such that the coal tar exists in gaseous form rather than as a liquid. Gaseous tars are then thermally cracked prior to the completion of the gasification process. During the subsequent endothermic gasification reactions, volatilized alkali can become chemically bound to aluminosilicates in (or added to) the ash. To reduce NH{sub 3} and HCN from fuel born nitrogen, steam injection is minimized, and residual nitrogen compounds are partially chemically reduced in the cracking stage in the upper gasifier region. Assuming testing confirms successful deployment of all these integrated processes, future IGCC applications will be much simplified, require significantly less mechanical components, and will likely achieve the $1,000/kWe commercialized system cost goal of the GPIF project. This report describes the process and its operation, design of the plant and equipment, site requirements, and the cost and schedule. 23 refs., 45 figs., 23 tabs.

  18. The reemergence of medium scale gasifications technology

    SciTech Connect (OSTI)

    Reindl, W.J.

    1982-06-01T23:59:59.000Z

    Gasification of solid material is a well proven field, but the introduction of abundant and cheap petroleum fuels after WW II caused the technology to be neglected. There are three types of reactors: the fixed fuel bed, the fluidized bed, and the entrained fuel reactor. The advantages, but more to the point, the drawbacks of each system are reviewed. In order for gasification to fill modern industrial needs the advantages of the three types must be combined without their drawbacks. A reactor needs to be tar-free, have a high volume gas output relative to reactor size, accept a wide range of fuels, and have a comparable Btu production level of fuel gas. These specifications are met by the Series 8000 gas generator manufactured by Enerdyne Corporation.

  19. CX-004662: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Exclusion Determination Testing of Chinese Coal in a Transport Reactor Integrated Gasification (TRIG) System CX(s) Applied: B3.6 Date: 12092010 Location(s): Grand Forks, North...

  20. CX-004476: Categorical Exclusion Determination | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Exclusion Determination Testing of Indian Coal in a Transport Reactor Integrated Gasification (TRIG) System CX(s) Applied: B3.6 Date: 11182010 Location(s): Grand Forks, North...

  1. Gasification Product Improvement Facility (GPIF). Final report

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    The gasifier selected for development under this contract is an innovative and patented hybrid technology which combines the best features of both fixed-bed and fluidized-bed types. PyGas{trademark}, meaning Pyrolysis Gasification, is well suited for integration into advanced power cycles such as IGCC. It is also well matched to hot gas clean-up technologies currently in development. Unlike other gasification technologies, PyGas can be designed into both large and small scale systems. It is expected that partial repowering with PyGas could be done at a cost of electricity of only 2.78 cents/kWh, more economical than natural gas repowering. It is extremely unfortunate that Government funding for such a noble cause is becoming reduced to the point where current contracts must be canceled. The Gasification Product Improvement Facility (GPIF) project was initiated to provide a test facility to support early commercialization of advanced fixed-bed coal gasification technology at a cost approaching $1,000 per kilowatt for electric power generation applications. The project was to include an innovative, advanced, air-blown, pressurized, fixed-bed, dry-bottom gasifier and a follow-on hot metal oxide gas desulfurization sub-system. To help defray the cost of testing materials, the facility was to be located at a nearby utility coal fired generating site. The patented PyGas{trademark} technology was selected via a competitive bidding process as the candidate which best fit overall DOE objectives. The paper describes the accomplishments to date.

  2. RESULTS OF THE TECHNICAL AND ECONOMIC FEASIBILITY ANALYSIS FOR A NOVEL BIOMASS GASIFICATION-BASED POWER GENERATION SYSTEM FOR THE FOREST PRODUCTS INDUSTRY

    SciTech Connect (OSTI)

    Bruce Bryan; Joseph Rabovitser; Sunil Ghose; Jim Patel

    2003-11-01T23:59:59.000Z

    In 2001, the Gas Technology Institute (GTI) entered into Cooperative Agreement DE-FC26-01NT41108 with the U.S. Department of Energy (DOE) for an Agenda 2020 project to develop an advanced biomass gasification-based power generation system for near-term deployment in the Forest Products Industry (FPI). The advanced power system combines three advanced components, including biomass gasification, 3-stage stoker-fired combustion for biomass conversion, and externally recuperated gas turbines (ERGTs) for power generation. The primary performance goals for the advanced power system are to provide increased self-generated power production for the mill and to increase wastewood utilization while decreasing fossil fuel use. Additional goals are to reduce boiler NOx and CO{sub 2} emissions. The current study was conducted to determine the technical and economic feasibility of an Advanced Power Generation System capable of meeting these goals so that a capital investment decision can be made regarding its implementation at a paper mill demonstration site in DeRidder, LA. Preliminary designs and cost estimates were developed for all major equipment, boiler modifications and balance of plant requirements including all utilities required for the project. A three-step implementation plan was developed to reduce technology risk. The plant design was found to meet the primary objectives of the project for increased bark utilization, decreased fossil fuel use, and increased self-generated power in the mill. Bark utilization for the modified plant is significantly higher (90-130%) than current operation compared to the 50% design goal. For equivalent steam production, the total gas usage for the fully implemented plant is 29% lower than current operation. While the current average steam production from No.2 Boiler is about 213,000 lb/h, the total steam production from the modified plant is 379,000 lb/h. This steam production increase will be accomplished at a grate heat release rate (GHRR) equal to the original boiler design. Boiler efficiencies (cogeneration-steam plus air) is increased from the original design value of 70% to 78.9% due to a combination of improved burnout, operation with lower excess air, and drier fuel. For the fully implemented plant, the thermal efficiency of fuel to electricity conversion is 79.8% in the cogeneration mode, 5% above the design goal. Finally, self-generated electricity will be increased from the 10.8 MW currently attributable to No.2 Boiler to 46.7MW, an increase of 332%. Environmental benefits derived from the system include a reduction in NOx emissions from the boiler of about 30-50% (90-130 tons/year) through syngas reburning, improved carbon burnout and lower excess air. This does not count NOx reduction that may be associated with replacement of purchased electricity. The project would reduce CO{sub 2} emissions from the generation of electricity to meet the mill's power requirements, including 50,000 tons/yr from a net reduction in gas usage in the mill and an additional 410,000 tons/yr reduction in CO{sub 2} emissions due to a 34 MW reduction of purchased electricity. The total CO{sub 2} reduction amounts to about 33% of the CO{sub 2} currently generated to meet the mills electricity requirement. The overall conclusion of the study is that while significant engineering challenges are presented by the proposed system, they can be met with operationally acceptable and cost effective solutions. The benefits of the system can be realized in an economic manner, with a simple payback period on the order of 6 years. The results of the study are applicable to many paper mills in the U.S. firing woodwastes and other solid fuels for steam and power production.

  3. Surface Gasification Materials Program. Semiannual progress report for the period ending September 30, 1982

    SciTech Connect (OSTI)

    Not Available

    1982-12-01T23:59:59.000Z

    The objective of the Surface Gasification Materials Program is to conduct research and development on materials for application to the specific needs of coal gasification systems. The Program is divided into two subprograms: (1) the Gasification Systems Fabrication Technology Program and (2) the Materials Application and Development Program. The purpose of the Gasification Systems Fabrication Technology Program is to evaluate innovative fabrication methods which have the potential to lower costs and improve reliability and safety for gasifier vessels and components. The purpose of the Materials Application and Development Program is to conduct engineering-scale development and application of materials for coal gasification systems to ensure that the materials of construction for pilot plants and future large-scale plants can be properly selected and specified. The Morgantown Energy Technology Center (METC), in its lead role for gasification projects, is responsible for ensuring that the Surface Gasification Materials Program is responsive to the needs for gasification systems. Under its lead role for fossil energy materials, the Oak Ridge Operations Office (ORO), is responsible for the planning, implementation, and management of the program in accordance with guidance received from METC. The ORNL Fossil Energy Materials Program Office compiles and issues this combined semiannual progress report from camera-ready copies submitted by each of the participating organizations.

  4. MODELLING THE LOW-TAR BIG GASIFICATION CONCEPT Lars Andersen, Brian Elmegaard, Bjrn Qvale, Ulrik Henriksen

    E-Print Network [OSTI]

    and gasification chamber are bubbling fluid beds, fluidised with steam. For moist fuels, the gasifier can be integrated with a steam drying process, where the produced steam is used in the pyrolysis plant systems: Gas engine, Simple cycle gas turbine, Recuperated gas turbine and Integrated Gasification

  5. GASIFICATION BASED BIOMASS CO-FIRING

    SciTech Connect (OSTI)

    Babul Patel; Kevin McQuigg; Robert Toerne; John Bick

    2003-01-01T23:59:59.000Z

    Biomass gasification offers a practical way to use this widespread fuel source for co-firing traditional large utility boilers. The gasification process converts biomass into a low Btu producer gas that can be used as a supplemental fuel in an existing utility boiler. This strategy of co-firing is compatible with a variety of conventional boilers including natural gas and oil fired boilers, pulverized coal fired conventional and cyclone boilers. Gasification has the potential to address all problems associated with the other types of co-firing with minimum modifications to the existing boiler systems. Gasification can also utilize biomass sources that have been previously unsuitable due to size or processing requirements, facilitating a wider selection of biomass as fuel and providing opportunity in reduction of carbon dioxide emissions to the atmosphere through the commercialization of this technology. This study evaluated two plants: Wester Kentucky Energy Corporation's (WKE's) Reid Plant and TXU Energy's Monticello Plant for technical and economical feasibility. These plants were selected for their proximity to large supply of poultry litter in the area. The Reid plant is located in Henderson County in southwest Kentucky, with a large poultry processing facility nearby. Within a fifty-mile radius of the Reid plant, there are large-scale poultry farms that generate over 75,000 tons/year of poultry litter. The local poultry farmers are actively seeking environmentally more benign alternatives to the current use of the litter as landfill or as a farm spread as fertilizer. The Monticello plant is located in Titus County, TX near the town of Pittsburgh, TX, where again a large poultry processor and poultry farmers in the area generate over 110,000 tons/year of poultry litter. Disposal of this litter in the area is also a concern. This project offers a model opportunity to demonstrate the feasibility of biomass co-firing and at the same time eliminate poultry litter disposal problems for the area's poultry farmers.

  6. The Caterpillar Coal Gasification Facility

    E-Print Network [OSTI]

    Welsh, J.; Coffeen, W. G., III

    1983-01-01T23:59:59.000Z

    ' in 1981 and won the 'energy conservation award' for 1983. The decision to install and operate a coal gasification plant was based on severe natural gas curtailments at York with continuing supply interruptions. This paper will present a detailed...

  7. GRI highlights underground gasification effort

    SciTech Connect (OSTI)

    Not Available

    1987-03-01T23:59:59.000Z

    A consortium headed by the Gas Research Institute is supporting major underground coal gasification tests to take place over the next two years at a site near Hanna, Wyoming. About 200 tons of coal will be gasified per day. Directional drilling will be used to form the horizontal gasification pathways linking the injection and production wells. The objectives of the program include a further evaluation of the controlled-retracting-injection-point technology. The technology involves the use of a device that is capable of igniting successive coal zones as it is retracted through a borehole in the coal seam. Comparable data will also be obtained during the test in sections where a linked-vertical-well concept will be used instead of the retracting-injection method. The linked-vertical-well concept, which has been used in most coal gasification tests, involves drilling a series of vertical wells into the coal seam gasification pathway for the ignition of successive coal zones. A parallel program will be conducted to evaluate environmental control technology applicable to underground coal gasification and to define the process requirements that must be satisfied to meet environmental quality standards. The results of these combined programs will provide the process and environmental data bases necessary to assess the economic potential of underground coal gasification from various US locations for a variety of end-product applications.

  8. Integrated Coal Gasification Power Plant Credit (Kansas)

    Broader source: Energy.gov [DOE]

    Integrated Coal Gasification Power Plant Credit states that an income taxpayer that makes a qualified investment in a new integrated coal gasification power plant or in the expansion of an existing...

  9. June 2007 gasification technologies workshop papers

    SciTech Connect (OSTI)

    NONE

    2007-06-15T23:59:59.000Z

    Topics covered in this workshop are fundamentals of gasification, carbon capture and sequestration, reviews of financial and regulatory incentives, co-production, and focus on gasification in the Western US.

  10. Survey of biomass gasification. Volume III. Current technology and research

    SciTech Connect (OSTI)

    None

    1980-04-01T23:59:59.000Z

    This survey of biomass gasification was written to aid the Department of Energy and the Solar Energy Research Institute Biological and Chemical Conversion Branch in determining the areas of gasification that are ready for commercialization now and those areas in which further research and development will be most productive. Chapter 8 is a survey of gasifier types. Chapter 9 consists of a directory of current manufacturers of gasifiers and gasifier development programs. Chapter 10 is a sampling of current gasification R and D programs and their unique features. Chapter 11 compares air gasification for the conversion of existing gas/oil boiler systems to biomass feedstocks with the price of installing new biomass combustion equipment. Chapter 12 treats gas conditioning as a necessary adjunct to all but close-coupled gasifiers, in which the product is promptly burned. Chapter 13 evaluates, technically and economically, synthesis-gas processes for conversion to methanol, ammonia, gasoline, or methane. Chapter 14 compiles a number of comments that have been assembled from various members of the gasifier community as to possible roles of the government in accelerating the development of gasifier technology and commercialization. Chapter 15 includes recommendations for future gasification research and development.

  11. Gasification behavior of carbon residue in bed solids of black liquor gasifier

    SciTech Connect (OSTI)

    Preto, Fernando; Zhang, Xiaojie (Frank); Wang, Jinsheng [CANMET Energy Technology Centre, Natural Resources (Canada)

    2008-07-15T23:59:59.000Z

    Steam gasification of carbon residue in bed solids of a low-temperature black liquor gasifier was studied using a thermogravimetric system at 3 bar. Complete gasification of the carbon residue, which remained unreactive at 600 C, was achieved in about 10 min as the temperature increased to 800 C. The rate of gasification and its temperature dependence were evaluated from the non-isothermal experiment results. Effects of particle size and adding H{sub 2} and CO to the gasification agent were also studied. The rate of steam gasification could be taken as zero order in carbon until 80% of carbon was gasified, and for the rest of the gasification process the rate appeared to be first order in carbon. The maximum rate of carbon conversion was around 0.003/s and the activation energy was estimated to be in the range of 230-300 kJ/mol. The particle size did not show significant effect on the rate of gasification. Hydrogen and carbon monoxide appeared to retard the onset of the gasification process. (author)

  12. Rocky mountain 1: Underground coal-gasification test, Hanna, Wyoming. Summary report, Volume 1. Appendix. Final report

    SciTech Connect (OSTI)

    Vardaman, M.H.

    1989-02-01T23:59:59.000Z

    The Rocky Mountain 1 underground coal gasification test was conducted near Hanna, Wyoming during the period January 1986 through March 1988. These appendixes include information supporting Volume I as well as complete data for certain aspects of the gasification phase. These aspects include daily operations reports, raw and corrected process data, thermocouple and Time Domain Reflectometer results, and monitoring well pressure and level data obtained during the gasification phase. Piping and instrumentation diagrams and supplemental informations on the data acquisition system are included.

  13. Beluga Coal Gasification - ISER

    SciTech Connect (OSTI)

    Steve Colt

    2008-12-31T23:59:59.000Z

    ISER was requested to conduct an economic analysis of a possible 'Cook Inlet Syngas Pipeline'. The economic analysis was incorporated as section 7.4 of the larger report titled: 'Beluga Coal Gasification Feasibility Study, DOE/NETL-2006/1248, Phase 2 Final Report, October 2006, for Subtask 41817.333.01.01'. The pipeline would carry CO{sub 2} and N{sub 2}-H{sub 2} from a synthetic gas plant on the western side of Cook Inlet to Agrium's facility. The economic analysis determined that the net present value of the total capital and operating lifecycle costs for the pipeline ranges from $318 to $588 million. The greatest contributor to this spread is the cost of electricity, which ranges from $0.05 to $0.10/kWh in this analysis. The financial analysis shows that the delivery cost of gas may range from $0.33 to $0.55/Mcf in the first year depending primarily on the price for electricity.

  14. Fixed-bed gasification research using US coals. Volume 2. Gasification of Jetson bituminous coal

    SciTech Connect (OSTI)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-03-31T23:59:59.000Z

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and governmental agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) Group. This report describes the gasification testing of Jetson bituminous coal. This Western Kentucky coal was gasified during an initial 8-day and subsequent 5-day period. Material flows and compositions are reported along with material and energy balances. Operational experience is also described. 4 refs., 24 figs., 17 tabs.

  15. JV Task 46 - Development and Testing of a Thermally Integrated SOFC-Gasification System for Biomass Power Generation

    SciTech Connect (OSTI)

    Phillip Hutton; Nikhil Patel; Kyle Martin; Devinder Singh

    2008-02-01T23:59:59.000Z

    The Energy & Environmental Research Center has designed a biomass power system using a solid oxide fuel cell (SOFC) thermally integrated with a downdraft gasifier. In this system, the high-temperature effluent from the SOFC enables the operation of a substoichiometric air downdraft gasifier at an elevated temperature (1000 C). At this temperature, moisture in the biomass acts as an essential carbon-gasifying medium, reducing the equivalence ratio at which the gasifier can operate with complete carbon conversion. Calculations show gross conversion efficiencies up to 45% (higher heating value) for biomass moisture levels up to 40% (wt basis). Experimental work on a bench-scale gasifier demonstrated increased tar cracking within the gasifier and increased energy density of the resultant syngas. A series of experiments on wood chips demonstrated tar output in the range of 9.9 and 234 mg/m{sup 3}. Both button cells and a 100-watt stack was tested on syngas from the gasifier. Both achieved steady-state operation with a 22% and 15% drop in performance, respectively, relative to pure hydrogen. In addition, tar tolerance testing on button cells demonstrated an upper limit of tar tolerance of approximately 1%, well above the tar output of the gasifier. The predicted system efficiency was revised down to 33% gross and 27% net system efficiency because of the results of the gasifier and fuel cell experiments. These results demonstrate the feasibility and benefits of thermally integrating a gasifier and a high-temperature fuel cell in small distributed power systems.

  16. Fixed-bed gasification research using US coals. Volume 17. Gasification and liquids recovery of four US coals

    SciTech Connect (OSTI)

    Thimsen, D.; Maurer, R.E.; Pooler, A.R.; Pui, D.; Liu, B.; Kittelson, D.

    1985-12-01T23:59:59.000Z

    A single-staged, fixed-bed Wellman-Galusha gasifier coupled with a hot, raw gas combustion system and scrubber has been used to gasify numerous coals from throughout the United States. The gasification test program is organized as a cooperative effort by private industrial participants and government agencies. The consortium of participants is organized under the Mining and Industrial Fuel Gas (MIFGa) group. This report is the seventeenth in a series of reports describing the atmospheric pressure, fixed-bed gasification of US coals. This report describes the gasification and pyrolysis liquids recovery test for four different coals: Illinois No. 6, SUFCO, Indianhead lignite, and Hiawatha. This test series spanned from July 15, 1985, through July 28, 1985. 4 refs., 16 figs., 19 tabs.

  17. Surface-gasification materials program. Semiannual progress report for the period ending March 31, 1982

    SciTech Connect (OSTI)

    Not Available

    1982-08-01T23:59:59.000Z

    The objective of the Surface Gasification Materials Program is to conduct research and development on materials for application to the specific needs of coal gasification systems. The Program is divided into two subprograms: (1) the Gasification Systems Fabrication Technology Program and (2) the Materials Application and Development Program. The purpose of the Gasification Systems Fabrication Technology Program is to evaluate innovative fabrication methods which have the potential to lower costs and improve reliability and safety for gasifier vessels and components. The purpose of the Materials Application and Development Program is to conduct engineering-scale development and application of materials for coal gasification systems to ensure that the materials of construction for pilot plants and future large-scale plants can be properly selected and specified. The management of materials projects in support of surface gasification sponsored by the Headquarters DOE Gasification Division has been defined in an April 16, 1982 METC-sponsored agreement transmitted to DOE field offices and performing contractors. This agreement recognizes the lead role in fossil energy materials delegated by METC to the DOE Oak Ridge Operations Office and the Oak Ridge National Laboratory. The ORNL Fossil Energy Materials Program Office compiles and issues this combined semiannual progress report from camera-ready copies submitted by each of the participating organizations. Distribution is as shown on pages 59 to 63. Future reports will be issued on a semiannual basis to a similar distribution.

  18. Coal gasification 2006: roadmap to commercialization

    SciTech Connect (OSTI)

    NONE

    2006-05-15T23:59:59.000Z

    Surging oil and gas prices, combined with supply security and environmental concerns, are prompting power generators and industrial firms to further develop coal gasification technologies. Coal gasification, the process of breaking down coal into its constituent chemical components prior to combustion, will permit the US to more effectively utilize its enormous, low cost coal reserves. The process facilitates lower environmental impact power generation and is becoming an increasingly attractive alternative to traditional generation techniques. The study is designed to inform the reader as to this rapidly evolving technology, its market penetration prospects and likely development. Contents include: Clear explanations of different coal gasification technologies; Emissions and efficiency comparisons with other fuels and technologies; Examples of US and global gasification projects - successes and failures; Commercial development and forecast data; Gasification projects by syngas output; Recommendations for greater market penetration and commercialization; Current and projected gasification technology market shares; and Recent developments including proposals for underground gasification process. 1 app.

  19. Hybrid Combustion-Gasification Chemical Looping

    SciTech Connect (OSTI)

    Herbert Andrus; Gregory Burns; John Chiu; Gregory Lijedahl; Peter Stromberg; Paul Thibeault

    2009-01-07T23:59:59.000Z

    For the past several years Alstom Power Inc. (Alstom), a leading world-wide power system manufacturer and supplier, has been in the initial stages of developing an entirely new, ultra-clean, low cost, high efficiency power plant for the global power market. This new power plant concept is based on a hybrid combustion-gasification process utilizing high temperature chemical and thermal looping technology The process consists of the oxidation, reduction, carbonation, and calcination of calcium-based compounds, which chemically react with coal, biomass, or opportunity fuels in two chemical loops and one thermal loop. The chemical and thermal looping technology can be alternatively configured as (i) a combustion-based steam power plant with CO{sub 2} capture, (ii) a hybrid combustion-gasification process producing a syngas for gas turbines or fuel cells, or (iii) an integrated hybrid combustion-gasification process producing hydrogen for gas turbines, fuel cells or other hydrogen based applications while also producing a separate stream of CO{sub 2} for use or sequestration. In its most advanced configuration, this new concept offers the promise to become the technology link from today's Rankine cycle steam power plants to tomorrow's advanced energy plants. The objective of this work is to develop and verify the high temperature chemical and thermal looping process concept at a small-scale pilot facility in order to enable AL to design, construct and demonstrate a pre-commercial, prototype version of this advanced system. In support of this objective, Alstom and DOE started a multi-year program, under this contract. Before the contract started, in a preliminary phase (Phase 0) Alstom funded and built the required small-scale pilot facility (Process Development Unit, PDU) at its Power Plant Laboratories in Windsor, Connecticut. Construction was completed in calendar year 2003. The objective for Phase I was to develop the indirect combustion loop with CO{sub 2} separation, and also syngas production from coal with the calcium sulfide (CaS)/calcium sulfate (CaSO{sub 4}) loop utilizing the PDU facility. The results of Phase I were reported in Reference 1, 'Hybrid Combustion-Gasification Chemical Looping Coal Power Development Technology Development Phase I Report' The objective for Phase II was to develop the carbonate loop--lime (CaO)/calcium carbonate (CaCO{sub 3}) loop, integrate it with the gasification loop from Phase I, and ultimately demonstrate the feasibility of hydrogen production from the combined loops. The results of this program were reported in Reference 3, 'Hybrid Combustion-Gasification Chemical Looping Coal Power Development Technology Development Phase II Report'. The objective of Phase III is to operate the pilot plant to obtain enough engineering information to design a prototype of the commercial Chemical Looping concept. The activities include modifications to the Phase II Chemical Looping PDU, solids transportation studies, control and instrumentation studies and additional cold flow modeling. The deliverable is a report making recommendations for preliminary design guidelines for the prototype plant, results from the pilot plant testing and an update of the commercial plant economic estimates.

  20. Underground coal gasification: environmental update

    SciTech Connect (OSTI)

    Dockter, L.; Mcternan, E.M.

    1985-01-01T23:59:59.000Z

    To evaluate the potential for ground water contamination by underground coal gasification, extensive postburn groundwater monitoring programs are being continued at two test sites in Wyoming. An overview of the environmental concerns related to UCG and some results to date on the two field sites are presented in this report.

  1. Fluidized bed gasification ash reduction and removal process

    DOE Patents [OSTI]

    Schenone, Carl E. (Madison, PA); Rosinski, Joseph (Vanderbilt, PA)

    1984-12-04T23:59:59.000Z

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  2. Economic Analysis of a 3MW Biomass Gasification Power Plant

    E-Print Network [OSTI]

    Cattolica, Robert; Lin, Kathy

    2009-01-01T23:59:59.000Z

    Collaborative, Biomass gasification / power generationANALYSIS OF A 3MW BIOMASS GASIFICATION POWER PLANT R obert Cas a feedstock for gasification for a 3 MW power plant was

  3. Gasification world database 2007. Current industry status

    SciTech Connect (OSTI)

    NONE

    2007-10-15T23:59:59.000Z

    Information on trends and drivers affecting the growth of the gasification industry is provided based on information in the USDOE NETL world gasification database (available on the www.netl.doe.gov website). Sectors cover syngas production in 2007, growth planned through 2010, recent industry changes, and beyond 2010 - strong growth anticipated in the United States. A list of gasification-based power plant projects, coal-to-liquid projects and coal-to-SNG projects under consideration in the USA is given.

  4. Wet Gasification of Ethanol Residue: A Preliminary Assessment

    SciTech Connect (OSTI)

    Brown, Michael D.; Elliott, Douglas C.

    2008-09-22T23:59:59.000Z

    A preliminary technoeconomic assessment has been made of several options for the application of catalytic hydrothermal gasification (wet gasification) to ethanol processing residues.

  5. EIS-0412: TX Energy, LLC, Industrial Gasification Facility Near...

    Broader source: Energy.gov (indexed) [DOE]

    2: TX Energy, LLC, Industrial Gasification Facility Near Beaumont, TX EIS-0412: TX Energy, LLC, Industrial Gasification Facility Near Beaumont, TX February 18, 2009 EIS-0412:...

  6. gasification index | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and capture are also required. The National Energy Technology Laboratory (NETL) Gasification Team and members of the NETL-Regional University Alliance (NETL-RUA) are taking an...

  7. Methods and apparatus for catalytic hydrothermal gasification...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methods and apparatus for catalytic hydrothermal gasification of biomass Re-direct Destination: Continuous processing of wet biomass feedstock by catalytic hydrothermal...

  8. Plasma gasification of coal in different oxidants

    SciTech Connect (OSTI)

    Matveev, I.B.; Messerle, V.E.; Ustimenko, A.B. [Applied Plasma Technology, Mclean, VA (USA)

    2008-12-15T23:59:59.000Z

    Oxidant selection is the highest priority for advanced coal gasification-process development. This paper presents comparative analysis of the Powder River Basin bituminous-coal gasification processes for entrained-flow plasma gasifier. Several oxidants, which might be employed for perspective commercial applications, have been chosen, including air, steam/carbon-dioxide blend, carbon dioxide, steam, steam/air, steam/oxygen, and oxygen. Synthesis gas composition, carbon gasification degree, specific power consumptions, and power efficiency for these processes were determined. The influence of the selected oxidant composition on the gasification-process main characteristics have been investigated.

  9. Underground coal gasification using oxygen and steam

    SciTech Connect (OSTI)

    Yang, L.H.; Zhang, X.; Liu, S. [China University of Mining & Technology, Xuzhou (China)

    2009-07-01T23:59:59.000Z

    In this paper, through model experiment of the underground coal gasification, the effects of pure oxygen gasification, oxygen-steam gasification, and moving-point gasification methods on the underground gasification process and gas quality were studied. Experiments showed that H{sub 2} and CO volume fraction in product gas during the pure oxygen gasification was 23.63-30.24% and 35.22-46.32%, respectively, with the gas heating value exceeding 11.00 MJ/m{sup 3}; under the oxygen-steam gasification, when the steam/oxygen ratio stood at 2: 1, gas compositions remained virtually stable and CO + H{sub 2} was basically between 61.66 and 71.29%. Moving-point gasification could effectively improve the changes in the cavity in the coal seams or the effects of roof inbreak on gas quality; the ratio of gas flowing quantity to oxygen supplying quantity was between 3.1:1 and 3.5:1 and took on the linear changes; on the basis of the test data, the reasons for gas quality changes under different gasification conditions were analyzed.

  10. Biomass Gasification at The Evergreen State College

    E-Print Network [OSTI]

    Natural Gas vs. Biomass Gasification...................................................................33..........................................................................................23 Transportation Impacts and Methods of Mitigation...................................24 Biochar, the Bad, and the Slash..........................................................................31 Natural

  11. Plasma-enhanced gasification of low-grade coals for compact power plants

    SciTech Connect (OSTI)

    Uhm, Han S. [Department of Electrophysics, Kwangwoon University, 447-1 Wolgye-Dong, Nowon-Gu, Seoul 139-701 (Korea, Republic of); Hong, Yong C.; Shin, Dong H.; Lee, Bong J. [Convergence Plasma Research Center, National Fusion Research Institute, 113 Gwahangno, Yuseong-Gu, Daejeon 305-333 (Korea, Republic of)

    2011-10-15T23:59:59.000Z

    A high temperature of a steam torch ensures an efficient gasification of low-grade coals, which is comparable to that of high-grade coals. Therefore, the coal gasification system energized by microwaves can serve as a moderately sized power plant due to its compact and lightweight design. This plasma power plant of low-grade coals would be useful in rural or sparsely populated areas without access to a national power grid.

  12. Heat exchanger for coal gasification process

    DOE Patents [OSTI]

    Blasiole, George A. (Greensburg, PA)

    1984-06-19T23:59:59.000Z

    This invention provides a heat exchanger, particularly useful for systems requiring cooling of hot particulate solids, such as the separated fines from the product gas of a carbonaceous material gasification system. The invention allows effective cooling of a hot particulate in a particle stream (made up of hot particulate and a gas), using gravity as the motive source of the hot particulate. In a preferred form, the invention substitutes a tube structure for the single wall tube of a heat exchanger. The tube structure comprises a tube with a core disposed within, forming a cavity between the tube and the core, and vanes in the cavity which form a flow path through which the hot particulate falls. The outside of the tube is in contact with the cooling fluid of the heat exchanger.

  13. Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2: Gas Cleanup Design and Cost Estimates -- Black Liquor Gasification

    SciTech Connect (OSTI)

    Nexant Inc.

    2006-05-01T23:59:59.000Z

    As part of Task 2, Gas Cleanup and Cost Estimates, Nexant investigated the appropriate process scheme for removal of acid gases from black liquor-derived syngas for use in both power and liquid fuels synthesis. Two 3,200 metric tonne per day gasification schemes, both low-temperature/low-pressure (1100 deg F, 40 psi) and high-temperature/high-pressure (1800 deg F, 500 psi) were used for syngas production. Initial syngas conditions from each of the gasifiers was provided to the team by the National Renewable Energy Laboratory and Princeton University. Nexant was the prime contractor and principal investigator during this task; technical assistance was provided by both GTI and Emery Energy.

  14. Development of an advanced, continuous mild gasification process for the production of co-products (Task 1), Volume 1

    SciTech Connect (OSTI)

    Knight, R.A.; Gissy, J.L.; Onischak, M.; Babu, S.P.; Carty, R.H. (Institute of Gas Technology, Chicago, IL (United States)); Duthie, R.G. (Bechtel Group, Inc., San Francisco, CA (United States)); Wootten, J.M. (Peabody Holding Co., Inc., St. Louis, MO (United States))

    1991-09-01T23:59:59.000Z

    Under US DOE sponsorship, a project team consisting of the Institute of Gas Technology, Peabody Holding Company, and Bechtel Group, Inc. has been developing an advanced, mild gasification process to process all types of coal and to produce solid and condensable liquid co-products that can open new markets for coal. The three and a half year program (September 1987 to June 1991) consisted of investigations in four main areas. These areas are: (1) Literature Survey of Mild Gasification Processes, Co-Product Upgrading and Utilization, and Market Assessment; (2) Mild Gasification Technology Development: Process Research Unit Tests Using Slipstream Sampling; (3) Bench-Scale Char Upgrading Study; (4) Mild Gasification Technology Development: System Integration Studies. In this report, the literature and market assessment of mild gasification processes are discussed.

  15. Underground coal gasification simulation. Final report

    SciTech Connect (OSTI)

    Gunn, R.D.

    1984-07-01T23:59:59.000Z

    The underground coal gasification (UCG) process - both forward gasification and reverse combustion linkage - was mathematically modeled. The models were validated with field and laboratory data. They were then used to explain some important UCG phenomena that had not been predictable with other methods. Some views on the UCG technology status are also presented. 3 references, 25 figures, 10 tables.

  16. Improved catalysts for carbon and coal gasification

    DOE Patents [OSTI]

    McKee, D.W.; Spiro, C.L.; Kosky, P.G.

    1984-05-25T23:59:59.000Z

    This invention relates to improved catalysts for carbon and coal gasification and improved processes for catalytic coal gasification for the production of methane. The catalyst is composed of at least two alkali metal salts and a particulate carbonaceous substrate or carrier is used. 10 figures, 2 tables.

  17. Methanol from biomass via steam gasification

    SciTech Connect (OSTI)

    Coffman, J.A. [Wright-Malta Corp., Ballston Spa, NY (United States)

    1995-12-31T23:59:59.000Z

    R&D at Wright-Malta on gasification of biomass, and use of this gas in methanol synthesis, has now reached the stage where a demonstration plant is feasible. The gasifier has evolved into a long, slender, slightly declined, graded temperature stationary kiln, with a box beam rotor and twin piston feed. The methanol reactor is envisioned as a smaller, more declined, graded temperature, water-filled kiln, with a multi-pipe rotor. Input to the demo plant will be 100 tons/day of green (45% water) wood chips; output will be 11,000 gal/day of methanol and 7500 lbs/hr of steam. The over-all biomass to methanol system is tightly integrated in its mechanical design to take full advantage of the reactivity of biomass under a slow, steady, steamy pressurized cook, and the biomass pyrolysis and methanol synthesis exotherms. This is expected to yield good energy efficiency, environmental attractiveness, and economical operation.

  18. Treatment of Mixed Wastes via Fixed Bed Gasification

    SciTech Connect (OSTI)

    None

    1998-10-28T23:59:59.000Z

    This report outlines the details of research performed under USDOE Cooperative Agreement DE-FC21-96MC33258 to evaluate the ChemChar hazardous waste system for the destruction of mixed wastes, defined as those that contain both RCRA-regulated haz- ardous constituents and radionuclides. The ChemChar gasification system uses a granular carbonaceous char matrix to immobilize wastes and feed them into the gasifier. In the gasifier wastes are subjected to high temperature reducing conditions, which destroy the organic constituents and immobilize radionuclides on the regenerated char. Only about 10 percent of the char is consumed on each pass through the gasifier, and the regenerated char can be used to treat additional wastes. When tested on a 4-inch diameter scale with a continuous feed unit as part of this research, the ChemChar gasification system was found to be effective in destroying RCRA surrogate organic wastes (chlorobenzene, dichloroben- zene, and napht.halene) while retaining on the char RCRA heavy metals (chromium, nickel, lead, and cadmium) as well as a fission product surrogate (cesium) and a plutonium surrogate (cerium). No generation of harmful byproducts was observed. This report describes the design and testing of the ChemChar gasification system and gives the operating procedures to be followed in using the system safely and effectively for mixed waste treatment.

  19. Techno Economic Analysis of Hydrogen Production by gasification of biomass

    SciTech Connect (OSTI)

    Francis Lau

    2002-12-01T23:59:59.000Z

    Biomass represents a large potential feedstock resource for environmentally clean processes that produce power or chemicals. It lends itself to both biological and thermal conversion processes and both options are currently being explored. Hydrogen can be produced in a variety of ways. The majority of the hydrogen produced in this country is produced through natural gas reforming and is used as chemical feedstock in refinery operations. In this report we will examine the production of hydrogen by gasification of biomass. Biomass is defined as organic matter that is available on a renewable basis through natural processes or as a by-product of processes that use renewable resources. The majority of biomass is used in combustion processes, in mills that use the renewable resources, to produce electricity for end-use product generation. This report will explore the use of hydrogen as a fuel derived from gasification of three candidate biomass feedstocks: bagasse, switchgrass, and a nutshell mix that consists of 40% almond nutshell, 40% almond prunings, and 20% walnut shell. In this report, an assessment of the technical and economic potential of producing hydrogen from biomass gasification is analyzed. The resource base was assessed to determine a process scale from feedstock costs and availability. Solids handling systems were researched. A GTI proprietary gasifier model was used in combination with a Hysys(reg. sign) design and simulation program to determine the amount of hydrogen that can be produced from each candidate biomass feed. Cost estimations were developed and government programs and incentives were analyzed. Finally, the barriers to the production and commercialization of hydrogen from biomass were determined. The end-use of the hydrogen produced from this system is small PEM fuel cells for automobiles. Pyrolysis of biomass was also considered. Pyrolysis is a reaction in which biomass or coal is partially vaporized by heating. Gasification is a more general term, and includes heating as well as the injection of other ''ingredients'' such as oxygen and water. Pyrolysis alone is a useful first step in creating vapors from coal or biomass that can then be processed in subsequent steps to make liquid fuels. Such products are not the objective of this project. Therefore pyrolysis was not included in the process design or in the economic analysis. High-pressure, fluidized bed gasification is best known to GTI through 30 years of experience. Entrained flow, in contrast to fluidized bed, is a gasification technology applied at much larger unit sizes than employed here. Coal gasification and residual oil gasifiers in refineries are the places where such designs have found application, at sizes on the order of 5 to 10 times larger than what has been determined for this study. Atmospheric pressure gasification is also not discussed. Atmospheric gasification has been the choice of all power system pilot plants built for biomass to date, except for the Varnamo plant in Sweden, which used the Ahlstrom (now Foster Wheeler) pressurized gasifier. However, for fuel production, the disadvantage of the large volumetric flows at low pressure leads to the pressurized gasifier being more economical.

  20. NETL, USDA design coal-stabilized biomass gasification unit

    SciTech Connect (OSTI)

    NONE

    2008-09-30T23:59:59.000Z

    Coal, poultry litter, contaminated corn, rice hulls, moldly hay, manure sludge - these are representative materials that could be tested as fuel feedstocks in a hybrid gasification/combustion concept studied in a recent US Department of Energy (DOE) design project. DOE's National Energy Technology Laboratory (NETL) and the US Department of Agriculture (USDA) collaborated to develop a design concept of a power system that incorporates Hybrid Biomass Gasification. This system would explore the use of a wide range of biomass and agricultural waste products as gasifier feedstocks. The plant, if built, would supply one-third of electrical and steam heating needs at the USDA's Beltsville (Maryland) Agricultural Research Center. 1 fig., 1 photo.

  1. A Generalized Pyrolysis Model for Simulating Charring, Intumescent, Smoldering, and Noncharring Gasification

    E-Print Network [OSTI]

    Lautenberger, Chris; Fernandez-Pello, Carlos

    2006-01-01T23:59:59.000Z

    on Nonflaming Transient Gasification of PMMA and PE duringT. , & Werner, K. , “Wood Gasification at Fire Level HeatConcentration on Nonflaming Gasification Rates and Evolved

  2. The Development of a Hydrothermal Method for Slurry Feedstock Preparation for Gasification Technology

    E-Print Network [OSTI]

    He, Wei

    2011-01-01T23:59:59.000Z

    Higman, C. and M. Burgt, Gasification . 2003: Elsevier/Gulfand N.P. Cheremisinoff, Gasification technologies: a primerbiomass (part 3): gasification technologies. Bioresource

  3. The Development of a Hydrothermal Method for Slurry Feedstock Preparation for Gasification Technology

    E-Print Network [OSTI]

    He, Wei

    2011-01-01T23:59:59.000Z

    Affairs, Carbon and coal gasification: science andand B.F. Towler, Coal Gasification and Its Applications .Coal Chars , in Coal Gasification . 1974, AMERICAN CHEMICAL

  4. Integrated gasification combined-cycle research development and demonstration activities

    SciTech Connect (OSTI)

    Ness, H.M.; Reuther, R.B.

    1995-12-01T23:59:59.000Z

    The United States Department of Energy (DOE) has selected six integrated gasification combined-cycle (IGCC) advanced power systems for demonstration in the Clean Coal Technology (CCT) Program. DOE`s Office of Fossil Energy, Morgantown Energy Technology Center, is managing a research development and demonstration (RD&D) program that supports the CCT program, and addresses long-term improvements in support of IGCC technology. This overview briefly describes the CCT projects and the supporting RD&D activities.

  5. ENCOAL Mild Coal Gasification Project

    SciTech Connect (OSTI)

    Not Available

    1992-02-01T23:59:59.000Z

    ENCOAL Corporation, a wholly-owned subsidiary of Shell Mining Company, is constructing a mild gasification demonstration plant at Triton Coal Company's Buckskin Mine near Gillette, Wyoming. The process, using Liquids From Coal (LFC) technology developed by Shell and SGI International, utilizes low-sulfur Powder River Basin Coal to produce two new fuels, Process Derived Fuel (PDF) and Coal Derived Liquids (CDL). The products, as alternative fuels sources, are expected to significantly reduce current sulfur emissions at industrial and utility boiler sites throughout the nation, thereby reducing pollutants causing acid rain.

  6. Gasification Studies Task 4 Topical Report

    SciTech Connect (OSTI)

    Whitty, Kevin; Fletcher, Thomas; Pugmire, Ronald; Smith, Philip; Sutherland, James; Thornock, Jeremy; Boshayeshi, Babak; Hunsacker, Isaac; Lewis, Aaron; Waind, Travis; Kelly, Kerry

    2014-02-01T23:59:59.000Z

    A key objective of the Task 4 activities has been to develop simulation tools to support development, troubleshooting and optimization of pressurized entrained-flow coal gasifiers. The overall gasifier models (Subtask 4.1) combine submodels for fluid flow (Subtask 4.2) and heat transfer (Subtask 4.3) with fundamental understanding of the chemical processes (Subtask 4.4) processes that take place as coal particles are converted to synthesis gas and slag. However, it is important to be able to compare predictions from the models against data obtained from actual operating coal gasifiers, and Subtask 4.6 aims to provide an accessible, non-proprietary system, which can be operated over a wide range of conditions to provide well-characterized data for model validation. Highlights of this work include: • Verification and validation activities performed with the Arches coal gasification simulation tool on experimental data from the CANMET gasifier (Subtask 4.1). • The simulation of multiphase reacting flows with coal particles including detailed gas-phase chemistry calculations using an extension of the one-dimensional turbulence model’s capability (Subtask 4.2). • The demonstration and implementation of the Reverse Monte Carlo ray tracing (RMCRT) radiation algorithm in the ARCHES code (Subtask 4.3). • Determination of steam and CO{sub 2} gasification kinetics of bituminous coal chars at high temperature and elevated pressure under entrained-flow conditions (Subtask 4.4). In addition, attempts were made to gain insight into the chemical structure differences between young and mature coal soot, but both NMR and TEM characterization efforts were hampered by the highly reacted nature of the soot. • The development, operation, and demonstration of in-situ gas phase measurements from the University of Utah’s pilot-scale entrained-flow coal gasifier (EFG) (Subtask 4.6). This subtask aimed at acquiring predictable, consistent performance and characterizing the environment within the gasifier.

  7. Apparatus for solar coal gasification

    DOE Patents [OSTI]

    Gregg, D.W.

    1980-08-04T23:59:59.000Z

    Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials is described. Incident solar radiation is focused from an array of heliostats through a window onto the surface of a moving bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called synthesis gas, which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam in one embodiment at the rear surface of a secondary mirror used to redirect the focused sunlight. Another novel feature of the invention is the location and arrangement of the array of mirrors on an inclined surface (e.g., a hillside) to provide for direct optical communication of said mirrors and the carbonaceous feed without a secondary redirecting mirror.

  8. Steam gasification of carbon: Catalyst properties

    SciTech Connect (OSTI)

    Falconer, J.L.

    1993-01-10T23:59:59.000Z

    Coal gasification by steam is of critical importance in converting coal to gaseous products (CO, H[sub 2], CO[sub 2], CH[sub 4]) that can then be further converted to synthetic natural gas and higher hydrocarbon fuels. Alkali and alkaline earth metals (present as oxides) catalyze coal gasification reactions and cause them to occur at significantly lower temperatures. A more fundamental understanding of the mechanism of the steam gasification reaction and catalyst utilization may well lead to better production techniques, increased gasification rates, greater yields, and less waste. We are studying the gasification of carbon by steam in the presence of alkali and alkaline earth oxides, using carbonates as the starting materials. Carbon dioxide gasification (CO[sub 2] + C --> 2CO) has been studied in some detail recently, but much less has been done on the actual steam gasification reaction, which is the main thrust of our work. In particular, the form of the active catalyst compound during reaction is still questioned and the dependence of the concentration of active sites on reaction parameters is not known. Until recently, no measurements of active site concentrations during reaction had been made. We have recently used transient isotope tracing to determine active site concentration during CO[sub 2] gasification. We are investigating the mechanism and the concentration of active sites for steam gasification with transient isotopic tracing. For this technique, the reactant feed is switched from H[sub 2]0 to isotopically-labeled water at the same concentration and tow rate. We can then directly measure, at reaction the concentration of active catalytic sites, their kinetic rate constants, and the presence of more than one rate constant. This procedure allows us to obtain transient kinetic data without perturbing the steady-state surface reactions.

  9. Water pollution control for underground coal gasification

    SciTech Connect (OSTI)

    Humenick, M.J.

    1984-06-01T23:59:59.000Z

    Water pollution arising from underground gasification of coal is one of the important considerations in the eventual commercialization of the process. Because many coal seams which are amenable to in situ gasification are also ground-water aquifers, contaminants may be released to these ground waters during and after gasification. Also, when product gas is processed above ground for use, wastewater streams are generated which are too polluted to be discharged. The purpose of this paper is to characterize the nature of the groundwater and above-ground pollutants, discuss the potential long and short-term effects on ground water, propose control and restoration strategies, and to identify potential wastewater treatment schemes.

  10. Fluidized bed catalytic coal gasification process

    DOE Patents [OSTI]

    Euker, Jr., Charles A. (15163 Dianna La., Houston, TX 77062); Wesselhoft, Robert D. (120 Caldwell, Baytown, TX 77520); Dunkleman, John J. (3704 Autumn La., Baytown, TX 77520); Aquino, Dolores C. (15142 McConn, Webster, TX 77598); Gouker, Toby R. (5413 Rocksprings Dr., LaPorte, TX 77571)

    1984-01-01T23:59:59.000Z

    Coal or similar carbonaceous solids impregnated with gasification catalyst constituents (16) are oxidized by contact with a gas containing between 2 volume percent and 21 volume percent oxygen at a temperature between 50.degree. C. and 250.degree. C. in an oxidation zone (24) and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone (44) at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

  11. Development of biomass gasification to produce substitute fuels

    SciTech Connect (OSTI)

    Evans, R.J.; Knight, R.A.; Onischak, M.; Babu, S.P.

    1988-03-01T23:59:59.000Z

    The development of an efficient pressurized, medium-Btu steam-oxygen-blown fluidized-bed biomass gasification process was conducted. The overall program included initial stages of design-support research before the 12-ton-per-day (TPD) process research unit (PRU) was built. These stages involved the characterization of test-specific biomass species and the characteristics and limits of fluidization control. Also obtained for the design of the adiabatic PRU was information from studies with bench-scale equipment on the rapid rates of biomass devolatilization and on kinetics of the rate-controlling step of biomass char and steam gasification. The development program culminated with the sucessful operation of the PRU through 19 parametric-variation tests and extended steady-state process-proving tests. the program investigated the effect of gasifier temperature, pressure, biomass throughput rate, steam-to-biomass ratio, type of feedstock, feedstock moisture, and fludized-bed height on gasification performance. A long-duration gasification test of 3 days steady-state operation was conducted with the whole tree chips to indentify long-term effects of fluidized process conditions; to establish gasifier material and energy balances; to determine the possible breakthrough of low concentration organic species; and to evaluate the mechanical performance of the system components. Results indicate that the pressurized fludizied-bed process, can achieve carbon conversions of about 95% with cold gas thermal efficiences about 75% and with low and tar production. New information was collected on the oil and tar fraction, which relate to the process operating conditions and feedstock type. The different feedstocks studied were very similar in elemental compositions, and produced similar product gas compositions, but each has a different distribution and character of the oil and tar fractions. 11 refs., 45 figs., 18 tabs.

  12. Underground Coal Gasification at Tennessee Colony 

    E-Print Network [OSTI]

    Garrard, C. W.

    1979-01-01T23:59:59.000Z

    The Tennessee Colony In Situ Coal Gasification Project conducted by Basic Resources Inc. is the most recent step in Texas Utilities Company's ongoing research into the utilization of Texas lignite. The project, an application of the Soviet...

  13. The Role of Oxygen in Coal Gasification 

    E-Print Network [OSTI]

    Klosek, J.; Smith, A. R.; Solomon, J.

    1986-01-01T23:59:59.000Z

    Air Products supplies oxygen to a number of coal gasification and partial oxidation facilities worldwide. At the high operating pressures of these processes, economics favor the use of 90% and higher oxygen purities. The effect of inerts...

  14. Underground Coal Gasification at Tennessee Colony

    E-Print Network [OSTI]

    Garrard, C. W.

    1979-01-01T23:59:59.000Z

    The Tennessee Colony In Situ Coal Gasification Project conducted by Basic Resources Inc. is the most recent step in Texas Utilities Company's ongoing research into the utilization of Texas lignite. The project, an application of the Soviet...

  15. Catalysts for carbon and coal gasification

    DOE Patents [OSTI]

    McKee, Douglas W. (Burnt Hills, NY); Spiro, Clifford L. (Scotia, NY); Kosky, Philip G. (Schenectady, NY)

    1985-01-01T23:59:59.000Z

    Catalyst for the production of methane from carbon and/or coal by means of catalytic gasification. The catalyst compostion containing at least two alkali metal salts. A particulate carbonaceous substrate or carrier is used.

  16. Investigation of a sulfur reduction technique for mild gasification char

    SciTech Connect (OSTI)

    Knight, R.A.

    1991-01-01T23:59:59.000Z

    The object of this program is to investigate the desulfurization of mild gasification char using hydrogen/methane mixtures in a laboratory-scale experimental study. In the first year of the two- year program, char is being treated with mixtures of H{sub 2} and CH{sub 4} at temperatures of 1100{degrees}C to 1550{degrees}F and pressures of 50 to 100 psig. The effects of temperature, pressure, residence time, gas velocity, and gas composition on sulfur removal and carbon gasification are being determined. The batch experiments are being performed in a nominal 2-inch-ID stainless-steel, batch, fluidized-bed reactor. The char to be desulfurized was produced by the IGT mild gasification process research unit (PRU) in a recently completed DOE/METC-sponsored technology development program. The parent coal was Illinois No. 6 from a preparation plant, and the char from the selected test contains 4.58 wt% sulfur. In the first quarter, we have obtained and prepared a char for the desulfurization tests. Ultimate and proximate analyses were performed on this char, and its pore size distribution and surface area were determined. Also this quarter, the fluidized-bed reactor system was constructed and equipped with high pressure mass flow controllers and a high pressure sintered metal filter to remove fines from the effluent gas stream.

  17. Method for using fast fluidized bed dry bottom coal gasification

    DOE Patents [OSTI]

    Snell, George J. (Fords, NJ); Kydd, Paul H. (Lawrenceville, NJ)

    1983-01-01T23:59:59.000Z

    Carbonaceous solid material such as coal is gasified in a fast fluidized bed gasification system utilizing dual fluidized beds of hot char. The coal in particulate form is introduced along with oxygen-containing gas and steam into the fast fluidized bed gasification zone of a gasifier assembly wherein the upward superficial gas velocity exceeds about 5.0 ft/sec and temperature is 1500.degree.-1850.degree. F. The resulting effluent gas and substantial char are passed through a primary cyclone separator, from which char solids are returned to the fluidized bed. Gas from the primary cyclone separator is passed to a secondary cyclone separator, from which remaining fine char solids are returned through an injection nozzle together with additional steam and oxygen-containing gas to an oxidation zone located at the bottom of the gasifier, wherein the upward gas velocity ranges from about 3-15 ft/sec and is maintained at 1600.degree.-200.degree. F. temperature. This gasification arrangement provides for increased utilization of the secondary char material to produce higher overall carbon conversion and product yields in the process.

  18. Satisfying winter peak-power demand with phased gasification

    SciTech Connect (OSTI)

    Hall, E.H.; Moss, T.E.; Ravikumar, R.

    1987-01-01T23:59:59.000Z

    The purpose of this study, commissioned by the Bonneville Power Administration, was to investigate application of this concept to the Pacific Northwest. Coal gasification combined-cycle (GCC) plants are receiving serious attention from eastern utilities. Potomac Electric (PEPCO) has engaged Fluor Technology to perform conceptual and preliminary engineering for a nominal 375-MW coal GCC power generation facility to be located in northern Montgomery County, Maryland. Other eastern utilities are engaged in site-specific investigations of satisfying future power requirements employing this alternative, which involves an environmentally superior method of using coal. Coal is combined with oxygen to produce a medium-heating-value fuel gas as an alternative to natural gas. The fuel gas, cleaned to remove sulfur compounds, is burned in gas turbine-generator sets. The hot exhaust gas is used to generate steam for additional power generation. The gasification combined cycle plant is highly efficient and has a high level of flexibility to meet power demands. This study provided background for consideration of one alternative for satisfying winter peak-load demand. The concept is feasible, depending on the timing of the installation of the gasification system, projections of the cost and the availability of natural gas, and restrictions on the use of natural gas. It has the advantage of deferring capacity addition and capital outlay until power is needed and economics are favorable.

  19. Integrated Biomass Gasification with Catalytic Partial Oxidation for Selective Tar Conversion

    SciTech Connect (OSTI)

    Zhang, Lingzhi; Wei, Wei; Manke, Jeff; Vazquez, Arturo; Thompson, Jeff; Thompson, Mark

    2011-05-28T23:59:59.000Z

    Biomass gasification is a flexible and efficient way of utilizing widely available domestic renewable resources. Syngas from biomass has the potential for biofuels production, which will enhance energy security and environmental benefits. Additionally, with the successful development of low Btu fuel engines (e.g. GE Jenbacher engines), syngas from biomass can be efficiently used for power/heat co-generation. However, biomass gasification has not been widely commercialized because of a number of technical/economic issues related to gasifier design and syngas cleanup. Biomass gasification, due to its scale limitation, cannot afford to use pure oxygen as the gasification agent that used in coal gasification. Because, it uses air instead of oxygen, the biomass gasification temperature is much lower than well-understood coal gasification. The low temperature leads to a lot of tar formation and the tar can gum up the downstream equipment. Thus, the biomass gasification tar removal is a critical technology challenge for all types of biomass gasifiers. This USDA/DOE funded program (award number: DE-FG36-O8GO18085) aims to develop an advanced catalytic tar conversion system that can economically and efficiently convert tar into useful light gases (such as syngas) for downstream fuel synthesis or power generation. This program has been executed by GE Global Research in Irvine, CA, in collaboration with Professor Lanny Schmidt's group at the University of Minnesota (UoMn). Biomass gasification produces a raw syngas stream containing H2, CO, CO2, H2O, CH4 and other hydrocarbons, tars, char, and ash. Tars are defined as organic compounds that are condensable at room temperature and are assumed to be largely aromatic. Downstream units in biomass gasification such as gas engine, turbine or fuel synthesis reactors require stringent control in syngas quality, especially tar content to avoid plugging (gum) of downstream equipment. Tar- and ash-free syngas streams are a critical requirement for commercial deployment of biomass-based power/heat co-generation and biofuels production. There are several commonly used syngas clean-up technologies: (1) Syngas cooling and water scrubbing has been commercially proven but efficiency is low and it is only effective at small scales. This route is accompanied with troublesome wastewater treatment. (2) The tar filtration method requires frequent filter replacement and solid residue treatment, leading to high operation and capital costs. (3) Thermal destruction typically operates at temperatures higher than 1000oC. It has slow kinetics and potential soot formation issues. The system is expensive and materials are not reliable at high temperatures. (4) In-bed cracking catalysts show rapid deactivation, with durability to be demonstrated. (5) External catalytic cracking or steam reforming has low thermal efficiency and is faced with problematic catalyst coking. Under this program, catalytic partial oxidation (CPO) is being evaluated for syngas tar clean-up in biomass gasification. The CPO reaction is exothermic, implying that no external heat is needed and the system is of high thermal efficiency. CPO is capable of processing large gas volume, indicating a very compact catalyst bed and a low reactor cost. Instead of traditional physical removal of tar, the CPO concept converts tar into useful light gases (eg. CO, H2, CH4). This eliminates waste treatment and disposal requirements. All those advantages make the CPO catalytic tar conversion system a viable solution for biomass gasification downstream gas clean-up. This program was conducted from October 1 2008 to February 28 2011 and divided into five major tasks. - Task A: Perform conceptual design and conduct preliminary system and economic analysis (Q1 2009 ~ Q2 2009) - Task B: Biomass gasification tests, product characterization, and CPO tar conversion catalyst preparation. This task will be conducted after completing process design and system economics analysis. Major milestones include identification of syngas cleaning requirements for proposed system

  20. Investigation of plasma-aided bituminous coal gasification

    SciTech Connect (OSTI)

    Matveev, I.B.; Messerle, V.E.; Ustimenko, A.B. [Applied Plasma Technology, Mclean, VA (United States)

    2009-04-15T23:59:59.000Z

    This paper presents thermodynamic and kinetic modeling of plasma-aided bituminous coal gasification. Distributions of concentrations, temperatures, and velocities of the gasification products along the gasifier are calculated. Carbon gasification degree, specific power consumptions, and heat engineering characteristics of synthesis gas at the outlet of the gasifier are determined at plasma air/steam and oxygen/steam gasification of Powder River Basin bituminous coal. Numerical simulation showed that the plasma oxygen/steam gasification of coal is a more preferable process in comparison with the plasma air/steam coal gasification. On the numerical experiments, a plasma vortex fuel reformer is designed.

  1. Pulsed combustion process for black liquor gasification

    SciTech Connect (OSTI)

    Durai-Swamy, K.; Mansour, M.N.; Warren, D.W.

    1991-02-01T23:59:59.000Z

    The objective of this project is to test an energy efficient, innovative black liquor recovery system on an industrial scale. In the MTCI recovery process, black liquor is sprayed directly onto a bed of sodium carbonate solids which is fluidized by steam. Direct contact of the black liquor with hot bed solids promotes high rates of heating and pyrolysis. Residual carbon, which forms as a deposit on the particle surface, is then gasified by reaction with steam. Heat is supplied from pulse combustor resonance tubes which are immersed within the fluid bed. A portion of the gasifier product gas is returned to the pulse combustors to provide the energy requirements of the reactor. Oxidized sulfur species are partially reduced by reaction with the gasifier products, principally carbon monoxide and hydrogen. The reduced sulfur decomposed to solid sodium carbonate and gaseous hydrogen sulfide (H{sub 2}S). Sodium values are recovered by discharging a dry sodium carbonate product from the gasifier. MTCI's indirectly heated gasification technology for black liquor recovery also relies on the scrubbing of H{sub 2}S for product gases to regenerate green liquor for reuse in the mill circuit. Due to concerns relative to the efficiency of sulfur recovery in the MTCI integrated process, an experimental investigation was undertaken to establish performance and design data for this portion of the system.

  2. Steam tracer experiment at the Hoe Creek No. 3 underground coal gasification field test

    SciTech Connect (OSTI)

    Thorsness, C.B.

    1980-11-26T23:59:59.000Z

    Water plays an important role in in-situ coal gasification. To better understand this role, we conducted a steam tracer test during the later stages of the Hoe Creek No. 3 underground coal gasification field test. Deuterium oxide was used as the tracer. This report describes the tracer test and the analysis of the data obtained. The analysis indicates that at Hoe Creek the injected steam interacts with a large volume of water as it passes through the underground system. We hypothesize that this water is undergoing continual reflux in the underground system, resulting in a tracer response typical of a well-stirred tank.

  3. WABASH RIVER COAL GASIFICATION REPOWERING PROJECT

    SciTech Connect (OSTI)

    Unknown

    2000-09-01T23:59:59.000Z

    The close of 1999 marked the completion of the Demonstration Period of the Wabash River Coal Gasification Repowering Project. This Final Report summarizes the engineering and construction phases and details the learning experiences from the first four years of commercial operation that made up the Demonstration Period under Department of Energy (DOE) Cooperative Agreement DE-FC21-92MC29310. This 262 MWe project is a joint venture of Global Energy Inc. (Global acquired Destec Energy's gasification assets from Dynegy in 1999) and PSI Energy, a part of Cinergy Corp. The Joint Venture was formed to participate in the Department of Energy's Clean Coal Technology (CCT) program and to demonstrate coal gasification repowering of an existing generating unit impacted by the Clean Air Act Amendments. The participants jointly developed, separately designed, constructed, own, and are now operating an integrated coal gasification combined-cycle power plant, using Global Energy's E-Gas{trademark} technology (E-Gas{trademark} is the name given to the former Destec technology developed by Dow, Destec, and Dynegy). The E-Gas{trademark} process is integrated with a new General Electric 7FA combustion turbine generator and a heat recovery steam generator in the repowering of a 1950's-vintage Westinghouse steam turbine generator using some pre-existing coal handling facilities, interconnections, and other auxiliaries. The gasification facility utilizes local high sulfur coals (up to 5.9% sulfur) and produces synthetic gas (syngas), sulfur and slag by-products. The Project has the distinction of being the largest single train coal gasification combined-cycle plant in the Western Hemisphere and is the cleanest coal-fired plant of any type in the world. The Project was the first of the CCT integrated gasification combined-cycle (IGCC) projects to achieve commercial operation.

  4. Mississippi Ethanol Gasification Project, Final Scientific / Technical Report

    SciTech Connect (OSTI)

    Pearson, Larry, E.

    2007-04-30T23:59:59.000Z

    The Mississippi Ethanol (ME) Project is a comprehensive effort to develop the conversion of biomass to ethanol utilizing a proprietary gasification reactor technology developed by Mississippi Ethanol, LLC. Tasks were split between operation of a 1/10 scale unit at the Diagnostic Instrumentation and Analysis Laboratory (DIAL) of Mississippi State University (MSU) and the construction, development, and operation of a full scale pilot unit located at the ME facility in Winona, Mississippi. In addition to characterization of the ME reactor gasification system, other areas considered critical to the operational and economic viability of the overall ME concept were evaluated. These areas include syngas cleanup, biological conversion of syngas to alcohol, and effects of gasification scale factors. Characterization of run data from the Pre-Pilot and Pilot Units has allowed development of the factors necessary for scale-up from the small unit to the larger unit. This scale range is approximately a factor of 10. Particulate and tar sampling gave order of magnitude values for preliminary design calculations. In addition, sampling values collected downstream of the ash removal system show significant reductions in observed loadings. These loading values indicate that acceptable particulate and tar loading rates could be attained with standard equipment additions to the existing configurations. Overall operation both the Pre-Pilot and Pilot Units proceeded very well. The Pilot Unit was operated as a system, from wood receiving to gas flaring, several times and these runs were used to address possible production-scale concerns. Among these, a pressure feed system was developed to allow feed of material against gasifier system pressure with little or no purge requirements. Similarly, a water wash system, with continuous ash collection, was developed, installed, and tested. Development of a biological system for alcohol production was conducted at Mississippi State University with much progress. However, the current state of biological technology is not deemed to be ready commercially. A preliminary estimate of capital and operating costs of a 12000 gallon per day gasification/biological facility was developed for comparison purposes. In addition, during the biological organism screening and testing, some possible alternative products were identified. One such possibility is the biological production of bio-diesel. Additional research is necessary for further evaluation of all of the biological concepts.

  5. Thermochemical Conversion Research and Development: Gasification and Pyrolysis (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2009-09-01T23:59:59.000Z

    Biomass gasification and pyrolysis research and development activities at the National Renewable Energy Laboratory and Pacific Northwest National Laboratory.

  6. Biomass Anaerobic Digestion Facilities and Biomass Gasification Facilities (Indiana)

    Broader source: Energy.gov [DOE]

    The Indiana Department of Environmental Management requires permits before the construction or expansion of biomass anaerobic digestion or gasification facilities.

  7. Methanol from biomass via steam gasification

    SciTech Connect (OSTI)

    Coffman, J.A. [Wright-Malta Corp., Ballston Spa, NY (United States)

    1995-12-31T23:59:59.000Z

    R & D at Wright-Malta on gasification of biomass, and use of this gas in methanol synthesis, has now reached the stage where a demonstration plant is feasible. The gasifier has evolved into a long, slender, slightly declined, graded temperature series of stationary kiln sections, with box beam rotors and twin piston feed. The methanol reactor is envisioned as a smaller, more declined, graded temperature, water-filled stationary kiln, with a multi-pipe rotor. Input to the demo plant will be 100 tons/day of green (45% water) wood chips; output is projected at 11,000 gal/day of methanol and 7500 lbs/hr of steam. The over-all biomass to methanol system is tightly integrated in its mechanical design to take full advantage of the reactivity of biomass under a slow, steady, steamy pressurized cook, and the biomass pyrolysis and methanol synthesis exotherms. This is expected to yield good energy efficiency, environmental attractiveness, and economical operation.

  8. Development of an advanced, continuous mild gasification process for the production of co-products (Task 1), Volume 1. Final report

    SciTech Connect (OSTI)

    Knight, R.A.; Gissy, J.L.; Onischak, M.; Babu, S.P.; Carty, R.H. [Institute of Gas Technology, Chicago, IL (United States); Duthie, R.G. [Bechtel Group, Inc., San Francisco, CA (United States); Wootten, J.M. [Peabody Holding Co., Inc., St. Louis, MO (United States)

    1991-09-01T23:59:59.000Z

    Under US DOE sponsorship, a project team consisting of the Institute of Gas Technology, Peabody Holding Company, and Bechtel Group, Inc. has been developing an advanced, mild gasification process to process all types of coal and to produce solid and condensable liquid co-products that can open new markets for coal. The three and a half year program (September 1987 to June 1991) consisted of investigations in four main areas. These areas are: (1) Literature Survey of Mild Gasification Processes, Co-Product Upgrading and Utilization, and Market Assessment; (2) Mild Gasification Technology Development: Process Research Unit Tests Using Slipstream Sampling; (3) Bench-Scale Char Upgrading Study; (4) Mild Gasification Technology Development: System Integration Studies. In this report, the literature and market assessment of mild gasification processes are discussed.

  9. Short Communication Catalytic coal gasification: use of calcium versus potassium*

    E-Print Network [OSTI]

    Short Communication Catalytic coal gasification: use of calcium versus potassium* Ljubisa R of calcium is related to its sintering via crystallite growth. (Keywords: coal; gasification; catalysis was to study the relative merits (or liabilities) of these two catalysts in coal char gasification. This work

  10. The Public Perceptions of Underground Coal Gasification (UCG)

    E-Print Network [OSTI]

    Watson, Andrew

    The Public Perceptions of Underground Coal Gasification (UCG): A Pilot Study Simon Shackley #12;The Public Perceptions of Underground Coal Gasification (UCG): A Pilot Study Dr Simon Shackley of Underground Coal Gasification (UCG) in the United Kingdom. The objectives were to identify the main dangers

  11. Apparatus for fixed bed coal gasification

    DOE Patents [OSTI]

    Sadowski, Richard S. (Greenville, SC)

    1992-01-01T23:59:59.000Z

    An apparatus for fixed-bed coal gasification is described in which coal such as caking coal is continuously pyrolyzed with clump formation inhibited, by combining the coal with a combustible gas and an oxidant, and then continually feeding the pyrolyzed coal under pressure and elevated temperature into the gasification region of a pressure vessel. The materials in the pressure vessel are allowed to react with the gasifying agents in order to allow the carbon contents of the pyrolyzed coal to be completely oxidized. The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  12. Air-blown Integrated Gasification Combined Cycle demonstration project

    SciTech Connect (OSTI)

    Not Available

    1991-01-01T23:59:59.000Z

    Clean Power Cogeneration, Inc. (CPC) has requested financial assistance from DOE for the design construction, and operation of a normal 1270 ton-per-day (120-MWe), air-blown integrated gasification combined-cycle (IGCC) demonstration plant. The demonstration plant would produce both power for the utility grid and steam for a nearby industrial user. The objective of the proposed project is to demonstrate air-blown, fixed-bed Integrated Gasification Combined Cycle (IGCC) technology. The integrated performance to be demonstrated will involve all the subsystems in the air-blown IGCC system to include coal feeding; a pressurized air-blown, fixed-bed gasifier capable of utilizing caking coal; a hot gas conditioning systems for removing sulfur compounds, particulates, and other contaminants as necessary to meet environmental and combustion turbine fuel requirements; a conventional combustion turbine appropriately modified to utilize low-Btu coal gas as fuel; a briquetting system for improved coal feed performance; the heat recovery steam generation system appropriately modified to accept a NO{sub x} reduction system such as the selective catalytic reduction process; the steam cycle; the IGCC control systems; and the balance of plant. The base feed stock for the project is an Illinois Basin bituminous high-sulfur coal, which is a moderately caking coal. 5 figs., 1 tab.

  13. Tampa Electric Company`s Polk Power Station Integrated Gasification Combined Cycle Project

    SciTech Connect (OSTI)

    Jenkins, S.D.; Shafer, J.R.

    1994-12-31T23:59:59.000Z

    Tampa Electric Company (TEC) is in the construction phase for the new Polk Power Station, Unit {number_sign}1. This will be the first unit at a new site and will use Integrated Gasification Combined Cycle (IGCC) technology for power generation. The unit will utilize oxygen-blown entrained-flow coal gasification, along with combined cycle technology, to provide nominal net 26OMW of generation. As part of the environmental features of this process, the sulfur species in the coal will be recovered as a commercial grade sulfuric acid by-product. The sulfur will be removed from the synthesis gas utilizing a cold gas clean-up system (CGCU).

  14. Process for fixed bed coal gasification

    DOE Patents [OSTI]

    Sadowski, Richard S. (Greenville, SC)

    1992-01-01T23:59:59.000Z

    The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  15. ADVANCED GASIFICATION BY-PRODUCT UTILIZATION

    SciTech Connect (OSTI)

    Rodney Andrews; Aurora Rubel; Jack Groppo; Ari Geertsema; M. Mercedes Maroto-Valer; Zhe Lu; Harold Schobert

    2005-04-01T23:59:59.000Z

    The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported for the period September 1, 2003 to August 31, 2004. This contract is with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involves the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, and characterization of these materials for use as polymer fillers.

  16. Underground coal gasification product quality parameters

    SciTech Connect (OSTI)

    Bruggink, P.R.; Davis, B.E.

    1981-01-01T23:59:59.000Z

    A simplified model is described which will indicate the economic value of the raw product gas from an experimental underground coal gasification test on a real-time basis in order to aid in the optimization of the process during the course of the test. The model relates the properties of the product gas and the injection gas to the cost of producing each of five potential commercial products. This model was utilized to evaluate data during the Gulf-DOE underground coal gasification test at Rawlins, Wyoming in the fall of 1981. 6 refs.

  17. Materials performance in coal gasification pilot plants

    SciTech Connect (OSTI)

    Judkins, R.R.; Bradley, R.A.

    1987-10-15T23:59:59.000Z

    This paper presents the results of several materials testing projects which were conducted in operating coal gasification pilot plants in the United States. These projects were designed to test potential materials of construction for commercial plants under actual operating conditions. Pilot plants included in the overall test program included the Hygas, Conoco Coal, Synthane, Bi-Gas, Peatgas (Hygas operating with peat), Battelle, U-Gas, Westinghouse (now KRW), General Electric (Gegas), and Mountain Fuel Resources plants. Test results for a large variety of alloys are discussed and conclusions regarding applicability of these materials in coal gasification environments are presented. 14 refs., 2 tabs.

  18. Geosphere in underground coal gasification

    SciTech Connect (OSTI)

    Daly, D.J.; Groenewold, G.H.; Schmit, C.R.; Evans, J.M.

    1988-07-01T23:59:59.000Z

    The feasibility of underground coal gasification (UCG), the in-situ conversion of coal to natural gas, has been demonstrated through 28 tests in the US alone, mainly in low-rank coals, since the early 1970s. Further, UCG is currently entering the commercial phase in the US with a planned facility in Wyoming for the production of ammonia-urea from UCG-generated natural gas. Although the UCG process both affects and is affected by the natural setting, the majority of the test efforts have historically been focused on characterizing those aspects of the natural setting with the potential to affect the burn. With the advent of environmental legislation, this focus broadened to include the potential impacts of the process on the environment (e.g., subsidence, degradation of ground water quality). Experience to date has resulted in the growing recognition that consideration of the geosphere is fundamental to the design of efficient, economical, and environmentally acceptable UCG facilities. The ongoing RM-1 test program near Hanna, Wyoming, sponsored by the US Department of Energy and an industry consortium led by the Gas Research Institute, reflects this growing awareness through a multidisciplinary research effort, involving geoscientists and engineers, which includes (1) detailed geological site characterization, (2) geotechnical, hydrogeological, and geochemical characterization and predictive modeling, and (3) a strategy for ground water protection. Continued progress toward commercialization of the UCG process requires the integration of geological and process-test information in order to identify and address the potentially adverse environmental ramifications of the process, while identifying and using site characteristics that have the potential to benefit the process and minimize adverse impacts.

  19. Peat-Gasification Pilot-Plant Program. Final report, April 9, 1980-March 31, 1983

    SciTech Connect (OSTI)

    Not Available

    1983-03-01T23:59:59.000Z

    The objective of this program was twofold: (1) to modify an existing pilot plant and (2) to operate the pilot plant with peat to produce substitute natural gas (SNG). Activities included the design, procurement, and installation of peat drying, grinding, screening, and lockhopper feed systems. Equipment installed for the program complements the existing pilot plant facility. After shakedown of the new feed preparation equipment (drying, screening, and crushing) was successfully completed, the first integrated pilot plant test was conducted in April 1981 to provide solids flow data and operating experience with the new PEATGAS gasifier configuration. Three gasification tests were subsequently conducted using the existing slurry feed system. The lockhopper feed system, capable of providing a continuous, measured flow of 1 to 4 tons of dry feed at pressures up to 500 psig, was then successfully integrated with the gasifier. Two gasification tests were conducted, expanding the data to more economical operating conditions. The operation of the PEATGAS pilot plant has confirmed that peat is an excellent raw material for SNG production. Peat conversions over 90% were consistently achieved at moderate gasification temperatures and at sinter-free conditions. A large data base was established for Minnesota peat at pressure 1.0. The technical feasibility of the PEATGAS process has been successfully demonstrated. However, an economic assessment of the peat gasification process indicates that the cost of the peat feedstock delivered to a plant site has a significant effect on the cost of the product SNG. 28 figures, 36 tables.

  20. Improved refractories for IGCC power systems

    SciTech Connect (OSTI)

    Dogan, Cynthia P.; Kwong, Kyei-Sing; Bennet, James P.; Chinn, Richard E.; Dahlin, Cheryl L.

    2002-09-01T23:59:59.000Z

    Certain advantages make coal gasification a key element in the US Department of Energy's Vision 21 power system. However, issues of reliability and gasifier operation economics need to be resolved before gasification is widely adopted by the power generation industry.

  1. Coalbed methane production enhancement by underground coal gasification

    SciTech Connect (OSTI)

    Hettema, M.H.H.; Wolf, K.H.A.A.; Neumann, B.V.

    1997-12-31T23:59:59.000Z

    The sub-surface of the Netherlands is generally underlain by coal-bearing Carboniferous strata at greater depths (at many places over 1,500 m). These coal seams are generally thinner than 3 meter, occur in groups (5--15) within several hundred meters and are often fairly continuous over many square kilometers. In many cases they have endured complex burial history, influencing their methane saturation. In certain particular geological settings, a high, maximum coalbed methane saturation, may be expected. Carboniferous/Permian coals in the Tianjin-region (China) show many similarities concerning geological settings, rank and composition. Economical coalbed methane production at greater depths is often obstructed by the (very) low permeabilities of the coal seams as with increasing depth the deformation of the coal reduces both its macro-porosity (the cleat system) and microporosity. Experiments in abandoned underground mines, as well as after underground coal gasification tests indicate ways to improve the prospects for coalbed methane production in originally tight coal reservoirs. High permeability areas can be created by the application of underground coal gasification of one of the coal seams of a multi-seam cycle with some 200 meter of coal bearing strata. The gasification of one of the coal seams transforms that seam over a certain area into a highly permeable bed, consisting of coal residues, ash and (thermally altered) roof rubble. Additionally, roof collapse and subsidence will destabilize the overburden. In conjunction this will permit a better coalbed methane production from the remaining surrounding parts of the coal seams. Moreover, the effects of subsidence will influence the stress patterns around the gasified seam and this improves the permeability over certain distances in the coal seams above and below. In this paper the effects of the combined underground coal gasification and coalbed methane production technique are regarded for a single injection well. Known geotechnical aspects are combined with results from laboratory experiments on compaction of thermally treated rubble. An axi-symmetric numerical model is used to determine the effects induced by the gasified coal seam. The calculation includes the rubble formation, rubble compaction and induced stress effects in the overlying strata. Subsequently the stress effects are related to changes in coal permeability, based on experimental results of McKee et al.

  2. Clean heat, steam, and electricity from rice hull gasification

    SciTech Connect (OSTI)

    Bailey, R.W.; Bailey, R. Jr. [PRM Energy Systems, Inc., Hot Springs, AR (United States)

    1996-12-31T23:59:59.000Z

    PRM Energy Systems, Inc., (PRME) has completed the installation of a 330 ton/day biomass gasification system for Cargill Rice Milling of Greenville, Mississippi. The system was activated on November 1, 1995. Using the information and experience gained from the operation of previous installations, PRME scaled up its already proven technology by a factor of four and designed the model KC-218 to meet the needs of this particular facility. The PRME model KC-218 system converts unground rice hulls/straw and other biomass fuels to combustible gas which is burned in the boiler furnace delivering 115 million Btus/hr to an existing boiler/power island 5.0 MW of electricity and 15,000 pounds per hour of process steam for this rice parboiling facility.

  3. Fixed Bed Counter Current Gasification of Mesquite and Juniper Biomass Using Air-steam as Oxidizer 

    E-Print Network [OSTI]

    Chen, Wei 1981-

    2012-11-27T23:59:59.000Z

    Thermal gasification of biomass is being considered as one of the most promising technologies for converting biomass into gaseous fuel. Here we present results of gasification, using an adiabatic bed gasifier with air, steam as gasification medium...

  4. ASME PTC 47, gasification combined cycle performance -- Uncertainty

    SciTech Connect (OSTI)

    Archer, D.H.; Horazak, D.A.; Bannister, R.L.

    1998-07-01T23:59:59.000Z

    Determining the uncertainty of measured calculated performance parameters is required in all Performance Test Codes of the ASME. This determination begins with the equations defining the performance parameters of the equipment or system--input, useful output, and effectiveness (an input/output ratio). The variables in these equations are: plant operating conditions measured throughout a test; corrections that compensate for deviations of other significant measured plant and ambient operating conditions from their values specified for the test. PTC47, Gasification Combined Cycle Plant Performance, will define procedures for the performance testing of overall gasification combined cycle plants and for each of three major sections that may comprise such a plant. The Committee is now defining the performance parameters for these tests. Performance factor computations include uncertainty calculations in order to provide preliminary estimates of the accuracy expected from the test methods proposed in this Code. Uncertainty calculations will also be used to explore energy balance methods for calculating the energy input to various gasifiers--entrained flow, fluidized bed, and moving bed. Such methods would be important as possible alternatives to direct measurements of flows and heating values of the various fuels fed to the gasifiers. Uncertainty calculations will also be used to assist in identifying those measurements of ambient, imposed, and controlled operating conditions that significantly affect test results and for which correction factors should be determined.

  5. Analysis of forward combustion underground coal gasification models

    SciTech Connect (OSTI)

    Fausett, L.K.; Fausett, D.W.

    1984-01-01T23:59:59.000Z

    A survey has been made of forward combustion gasification models that are available in the public domain. The six models obtained for study have been mathematically analyzed to determine their conceptual completeness and computational complexity. The models range in scope of generality from a simple constrained mass balance model to a two-dimensional unsteady-state model. The computer code for each model has been implemented on the University of Wyoming CDC CYBER 730/760 computer system. Computed analyses with each of the programs are compared using data (taken primarily from the Lawrence Livermore National Laboratory (LLNL) Underground Coal Gasification (UCG) Data Base) corresponding to six representative DOE sponsored field experiments at Hanna, Hoe Creek, Rawlins, and Pricetown. Four of the field tests were air injection experiments and two were oxygen/steam injection experiments. This study provides a direct comparison of input data requirements and computer resource requirements of the six computer codes. It furnishes an indication of the applicability of each model to the various operating conditions in the different field tests. Computational capabilities and limitations of each model are discussed in detail. 20 references, 47 figures, 13 tables.

  6. Control methods and valve arrangement for start-up and shutdown of pressurized combustion and gasification systems integrated with a gas turbine

    DOE Patents [OSTI]

    Provol, Steve J. (Carlsbad, CA); Russell, David B. (San Diego, CA); Isaksson, Matti J. (Karhula, FI)

    1994-01-01T23:59:59.000Z

    A power plant having a system for converting coal to power in a gas turbine comprises a coal fed pressurized circulating bed for converting coal to pressurized gases, a gas turbine having a compressor for pressurizing air for the pressurized circulating bed and expander for receiving and expanding hot combustion gases for powering a generator, a first fast acting valve for controlling the pressurized air, a second fast acting valve means for controlling pressurized gas from the compressor to the expander.

  7. Development and application of optimal design capability for coal gasification systems - Task 1 (Volume 1, 2 and 3). Topical report, July 1995

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    Selective catalytic reduction (SCR) is a process for the post-combustion removal of NO{sub x} from the flue gas of fossil-fuel-fired power plants. SCR is capable of NO{sub x} reduction efficiencies of up to 80 or 90 percent. SCR technology has been applied for treatment of flue gases from a variety of emission sources, including natural gas- and oil-fired gas turbines, process steam boilers in refineries, and coal-fired power plants. SCR applications to coal-fired power plants have occurred in Japan and Germany. Full-scale SCR systems have not been applied to coal-fired power plants in the U.S., although there have been small-scale demonstration projects. SCR has become increasingly widely applied in the U.S. to natural-gas fired gas turbine combined cycle systems. In the remainder of this section, we review the applicability of SCR, as well as the need for post-combustion NO{sub x} control, for several power generation systems.

  8. Hanna, Wyoming underground coal gasification data base. Volume 3. The Hanna II, Phase I field test

    SciTech Connect (OSTI)

    Bartke, T.C.; Fischer, D.D.; King, S.B.; Boyd, R.M.; Humphrey, A.E.

    1985-08-01T23:59:59.000Z

    This report is part of a seven-volume series on the Hanna, Wyoming, underground coal gasification field tests. Volume 1 is a summary of the project, and each of Volumes 2 through 6 describes a particular test. Volume 7 is a compilation of all the data for the tests in Volumes 2 through 6. Hanna II, Phase I was conducted during the spring and summer of 1975, at a site about 700 feet up dip (to the southwest) of the Hanna I test. The test was conducted in two stages - Phase IA and IB. Phase IA consisted of linking and gasification operations between Wells 1 and 3 and Phase IB of linking from the 1-3 gasification zone to Well 2, followed by a short period of gasification from Well 2 to Well 3 over a broad range of air injection rates, in order to determine system turndown capabilities and response times. This report covers: (1) site selection and characteristics; (2) test objectives; (3) facilities description; (4) pre-operational testing; (5) test operations summary; and (6) post-test activity. 7 refs., 11 figs., 8 tabs.

  9. Markets for low- and medium-Btu coal gasification: an analysis of 13 site specific studies

    SciTech Connect (OSTI)

    Not Available

    1981-09-01T23:59:59.000Z

    In 1978 the US Department of Energy (DOE), through its Office of Resource Applications, developed a commercialization plan for low- and medium-Btu coal gasification. Several initial steps have been taken in that process, including a comprehensive study of industrial markets, issuance of a Notice of Program Interest, and funding of proposals under the Alternate Fuels Legislation (P.L. 96-126). To assist it in the further development and administration of the commercialization plan, the Office of Resource Applications has asked Booz, Allen and Hamilton to assess the market prospects for low- and medium-Btu coal gasification. This report covers the detailed findings of the study. Following the introduction which discusses the purpose of the study, approach used for the assignment and current market attitudes on coal gasification, there are three chapters on: systems configurations and applications; economic and finanical attractiveness; and summary of management decisions based on feasibility study results. The final chapter briefly assesses the management decisions. The general consensus seems to be that coal gasification is a technology that will be attractive in the future but is marginal now. 6 figures, 5 tables.

  10. Method for increasing steam decomposition in a coal gasification process

    DOE Patents [OSTI]

    Wilson, M.W.

    1987-03-23T23:59:59.000Z

    The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water- splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

  11. Method for increasing steam decomposition in a coal gasification process

    DOE Patents [OSTI]

    Wilson, Marvin W. (Fairview, WV)

    1988-01-01T23:59:59.000Z

    The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water-splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

  12. Fixed-bed gasification research using US coals. Volume 1. Program and facility description

    SciTech Connect (OSTI)

    Thimsen, D.; Maurer, R.E.; Poole, A.R.; Pui, D.; Liu, B.; Kittleson, D.

    1984-10-01T23:59:59.000Z

    The United States Department of Interior, Bureau of Mines, Twin Cities Research Center, Minneapolis, Minnesota is the site of a 6.5 foot diameter Wellman-Galusha gasifier, installed in 1977-1978. This gasifier, combustor/incinerator, and flue gas scrubber system in the past had been operated jointly by Bureau of Mines personnel, personnel from member companies of the Mining and Industrial Fuel Gas Group, and United States Department of Energy personnel-consultants. Numerous tests using a variety of coals have to date been performed. In May of 1982, Black, Sivalls and Bryson, Incorporated (BS and B) was awarded the contract to plan, execute, and report gasification test performance data from this small industrial fixed-bed gasification test facility. BS and B is responsible for program administration, test planning, test execution, and all documentation of program activities and test reports. The University of Minnesota, Particle Technology Laboratory (UMPTL) is subcontractor to BS and B to monitor process parameters, and provide analysis for material inputs and outputs. This report is the initial volume in a series of reports describing the fixed-bed gasification of US coals at the Bureau of Mines, Twin Cities Research Center. A history of the program is given in Section 1 and a thorough description of the facility in Section 2. The operation of the facility is described in Section 3. Monitoring systems and procedures are described in Sections 4 and 5. Data reduction tools are outlined in Section 6. There is no executive summary or conclusions as this volume serves only to describe the research program. Subsequent volumes will detail each gasification test and other pertinent results of the gasification program. 32 references, 23 figures, 15 tables.

  13. Gasification performance of switchgrass pretreated with torrefaction and densification

    SciTech Connect (OSTI)

    Jaya Shankar Tumuluru; Various

    2014-08-01T23:59:59.000Z

    The purpose of this study was to investigate gasification performance of four switchgrass pretreatments (torrefaction at 230 and 270 °C, densification, and combined torrefaction and densification) and three gasification temperatures (700, 800 and 900 °C). Gasification was performed in a fixed-bed externally heated reactor with air as an oxidizing agent. Switchgrass pretreatment and gasification temperature had significant effects on gasification performance such as gas yields, syngas lower heating value (LHV), and carbon conversion and cold gas efficiencies. With an increase in the gasification temperature, yields of H2 and CO, syngas LHV, and gasifier efficiencies increased whereas CH4, CO2 and N2 yields decreased. Among all switchgrass pretreatments, gasification performance of switchgrass with combined torrefaction and densification was the best followed by that of densified, raw and torrefied switchgrass. Gasification of combined torrefied and densified switchgrass resulted in the highest yields of H2 (0.03 kg/kg biomass) and CO (0.72 kg/kg biomass), highest syngas LHV (5.08 MJ m-3), CCE (92.53%), and CGE (68.40%) at the gasification temperature of 900 °C.

  14. Enabling Small-Scale Biomass Gasification for Liquid Fuel Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, and Refinery Co-Processing Enabling Small-Scale Biomass Gasification for Liquid Fuel Production...

  15. EIS-0383: Southern Company's Orlando Gasification Project, Orlando, FL

    Broader source: Energy.gov [DOE]

    This EIS analyzes DOE's decision to provide cost-shared funding for construction, design, and operation of a new gasification plant in Orlando, Florida.

  16. agricultural residues gasification: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    program considerably facilitated its operation which can now be remotely done. The gasification of sorghum, CGT and manure showed that they contained high amounts of...

  17. agglomerating burner gasification process: Topics by E-print...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    program considerably facilitated its operation which can now be remotely done. The gasification of sorghum, CGT and manure showed that they contained high amounts of...

  18. advanced integrated gasification: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    program considerably facilitated its operation which can now be remotely done. The gasification of sorghum, CGT and manure showed that they contained high amounts of...

  19. allothermal gasification gas: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    program considerably facilitated its operation which can now be remotely done. The gasification of sorghum, CGT and manure showed that they contained high amounts of...

  20. allothermal steam gasification: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    program considerably facilitated its operation which can now be remotely done. The gasification of sorghum, CGT and manure showed that they contained high amounts of...

  1. The ENCOAL Mild Gasification Demonstration Project

    SciTech Connect (OSTI)

    Not Available

    1990-07-01T23:59:59.000Z

    The DOE plans to enter into a Cooperative Agreement with ENCOAL Corporation, a wholly owned subsidiary of Shell Mining Company, for the cost-shared design, construction and operation of a mild gasification facility based on Liquids-from-Coal (LFC) technology. The facility is planned to be located at the Triton Coal Company's Buckskin Mine near Gillette, Wyoming. The mild gasification process to be demonstrated will produce two new, low-sulfur fuel forms (a solid and a liquid) from subbituminous coal. The new fuel forms would be suitable for combustion in commercial, industrial, and utility boilers. This environmental assessment has been prepared by the DOE to comply with the requirements of the NEPA. Pollutant emissions, land use, water, and waste management are briefly discussed. 3 figs., 5 tabs.

  2. Apparatus and method for solar coal gasification

    DOE Patents [OSTI]

    Gregg, David W. (Moraga, CA)

    1980-01-01T23:59:59.000Z

    Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials. Incident solar radiation is focused from an array of heliostats onto a tower-mounted secondary mirror which redirects the focused solar radiation down through a window onto the surface of a vertically-moving bed of coal, or a fluidized bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called "synthesis gas", which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam at the rear surface of the secondary mirror.

  3. Fluidized bed gasification of extracted coal

    DOE Patents [OSTI]

    Aquino, D.C.; DaPrato, P.L.; Gouker, T.R.; Knoer, P.

    1984-07-06T23:59:59.000Z

    Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone with an aqueous solution having a pH above 12.0 at a temperature between 65/sup 0/C and 110/sup 0/C for a period of time sufficient to remove bitumens from the coal into said aqueous solution, and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m/sup 3/. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step. 2 figs., 1 tab.

  4. Fluidized bed gasification of extracted coal

    DOE Patents [OSTI]

    Aquino, Dolores C. (Houston, TX); DaPrato, Philip L. (Westfield, NJ); Gouker, Toby R. (Baton Rouge, LA); Knoer, Peter (Houston, TX)

    1986-01-01T23:59:59.000Z

    Coal or similar carbonaceous solids are extracted by contacting the solids in an extraction zone (12) with an aqueous solution having a pH above 12.0 at a temperature between 65.degree. C. and 110.degree. C. for a period of time sufficient to remove bitumens from the coal into said aqueous solution and the extracted solids are then gasified at an elevated pressure and temperature in a fluidized bed gasification zone (60) wherein the density of the fluidized bed is maintained at a value above 160 kg/m.sup.3. In a preferred embodiment of the invention, water is removed from the aqueous solution in order to redeposit the extracted bitumens onto the solids prior to the gasification step.

  5. Environmental effects of in situ coal gasification

    SciTech Connect (OSTI)

    Humenick, M.J.; Edgar, T.F.; Charbeneau, R.J.

    1983-01-01T23:59:59.000Z

    An assessment of avialable engineering, geological and operating data on underground coal gasification indicates that this process can cause significant air and water pollution and land subsidence. Of the possible impacts, groundwater pollution is the most serious. Modeling studies and large-scale field tests are needed to determine the long-term fate of pollutants and the degree of restoration required before UCG can become a commercial process.

  6. Imperium/Lanzatech Syngas Fermentation Project - Biomass Gasification and Syngas Conditioning for Fermentation Evaluation: Cooperative Research and Development Final Report, CRADA Number CRD-12-474

    SciTech Connect (OSTI)

    Wilcox, E.

    2014-09-01T23:59:59.000Z

    LanzaTech and NREL will investigate the integration between biomass gasification and LanzaTech's proprietary gas fermentation process to produce ethanol and 2,3-butanediol. Using three feed materials (woody biomass, agricultural residue and herbaceous grass) NREL will produce syngas via steam indirect gasification and syngas conditioning over a range of process relevant operating conditions. The gasification temperature, steam-to-biomass ratio of the biomass feed into the gasifier, and several levels of syngas conditioning (based on temperature) will be varied to produce multiple syngas streams that will be fed directly to 10 liter seed fermenters operating with the Lanzatech organism. The NREL gasification system will then be integrated with LanzaTech's laboratory pilot unit to produce large-scale samples of ethanol and 2,3-butanediol for conversion to fuels and chemicals.

  7. Product Characterization for Entrained Flow Coal/Biomass Co-Gasification

    SciTech Connect (OSTI)

    Shawn Maghzi; Ramanathan Subramanian; George Rizeq; Surinder Singh; John McDermott; Boris Eiteneer; David Ladd; Arturo Vazquez; Denise Anderson; Noel Bates

    2011-09-30T23:59:59.000Z

    The U.S. Department of Energyâ??s National Energy Technology Laboratory (DOE NETL) is exploring affordable technologies and processes to convert domestic coal and biomass resources to high-quality liquid hydrocarbon fuels. This interest is primarily motivated by the need to increase energy security and reduce greenhouse gas emissions in the United States. Gasification technologies represent clean, flexible and efficient conversion pathways to utilize coal and biomass resources. Substantial experience and knowledge had been developed worldwide on gasification of either coal or biomass. However, reliable data on effects of blending various biomass fuels with coal during gasification process and resulting syngas composition are lacking. In this project, GE Global Research performed a complete characterization of the gas, liquid and solid products that result from the co-gasification of coal/biomass mixtures. This work was performed using a bench-scale gasifier (BSG) and a pilot-scale entrained flow gasifier (EFG). This project focused on comprehensive characterization of the products from gasifying coal/biomass mixtures in a high-temperature, high-pressure entrained flow gasifier. Results from this project provide guidance on appropriate gas clean-up systems and optimization of operating parameters needed to develop and commercialize gasification technologies. GEâ??s bench-scale test facility provided the bulk of high-fidelity quantitative data under temperature, heating rate, and residence time conditions closely matching those of commercial oxygen-blown entrained flow gasifiers. Energy and Environmental Research Center (EERC) pilot-scale test facility provided focused high temperature and pressure tests at entrained flow gasifier conditions. Accurate matching of syngas time-temperature history during cooling ensured that complex species interactions including homogeneous and heterogeneous processes such as particle nucleation, coagulation, surface condensation, and gas-phase reactions were properly reproduced and lead to representative syngas composition at the syngas cooler outlet. The experimental work leveraged other ongoing GE R&D efforts such as biomass gasification and dry feeding systems projects. Experimental data obtained under this project were used to provide guidance on the appropriate clean-up system(s) and operating parameters to coal and biomass combinations beyond those evaluated under this project.

  8. Product Characterization for Entrained Flow Coal/Biomass Co-Gasification

    SciTech Connect (OSTI)

    Maghzi, Shawn; Subramanian, Ramanathan; Rizeq, George; Singh, Surinder; McDermott, John; Eiteneer, Boris; Ladd, David; Vazquez, Arturo; Anderson, Denise; Bates, Noel

    2011-09-30T23:59:59.000Z

    The U.S. Department of Energy‘s National Energy Technology Laboratory (DOE NETL) is exploring affordable technologies and processes to convert domestic coal and biomass resources to high-quality liquid hydrocarbon fuels. This interest is primarily motivated by the need to increase energy security and reduce greenhouse gas emissions in the United States. Gasification technologies represent clean, flexible and efficient conversion pathways to utilize coal and biomass resources. Substantial experience and knowledge had been developed worldwide on gasification of either coal or biomass. However, reliable data on effects of blending various biomass fuels with coal during gasification process and resulting syngas composition are lacking. In this project, GE Global Research performed a complete characterization of the gas, liquid and solid products that result from the co-gasification of coal/biomass mixtures. This work was performed using a bench-scale gasifier (BSG) and a pilot-scale entrained flow gasifier (EFG). This project focused on comprehensive characterization of the products from gasifying coal/biomass mixtures in a high-temperature, high-pressure entrained flow gasifier. Results from this project provide guidance on appropriate gas clean-up systems and optimization of operating parameters needed to develop and commercialize gasification technologies. GE‘s bench-scale test facility provided the bulk of high-fidelity quantitative data under temperature, heating rate, and residence time conditions closely matching those of commercial oxygen-blown entrained flow gasifiers. Energy and Environmental Research Center (EERC) pilot-scale test facility provided focused high temperature and pressure tests at entrained flow gasifier conditions. Accurate matching of syngas time-temperature history during cooling ensured that complex species interactions including homogeneous and heterogeneous processes such as particle nucleation, coagulation, surface condensation, and gas-phase reactions were properly reproduced and lead to representative syngas composition at the syngas cooler outlet. The experimental work leveraged other ongoing GE R&D efforts such as biomass gasification and dry feeding systems projects. Experimental data obtained under this project were used to provide guidance on the appropriate clean-up system(s) and operating parameters to coal and biomass combinations beyond those evaluated under this project.

  9. Hanna, Wyoming underground coal gasification field test series

    SciTech Connect (OSTI)

    Bartke, T.C.; Gunn, R.D.

    1983-01-01T23:59:59.000Z

    The six in situ coal gasification field tests conducted by LETC near Hanna, WY, demonstrated typical gasification rates of 100 tons/day for continuous operation of about 30 days. Featuring high coal recovery and high product-gas calorific values, the underground process proved to be simple, reliable, and potentially controllable.

  10. The Hanna, Wyoming, underground coal gasification field test series

    SciTech Connect (OSTI)

    Bartke, T.C.; Gunn, R.D.

    1983-01-01T23:59:59.000Z

    Six field tests of in-situ coal gasification have been conducted by the Department of Energy's Laramie Energy Technology Center Near Hanna, Wyoming with typical gasification rates of 100 tons of coal per day for continuous operation of about 30 days. This paper presents an overview of the Hanna field tests.

  11. Methods for sequestering carbon dioxide into alcohols via gasification fermentation

    DOE Patents [OSTI]

    Gaddy, James L; Ko, Ching-Whan; Phillips, J. Randy; Slape, M. Sean

    2013-11-26T23:59:59.000Z

    The present invention is directed to improvements in gasification for use with synthesis gas fermentation. Further, the present invention is directed to improvements in gasification for the production of alcohols from a gaseous substrate containing at least one reducing gas containing at least one microorganism.

  12. Low-temperature catalytic gasification of wet industrial wastes. FY 1991--1992 interim report

    SciTech Connect (OSTI)

    Elliott, D.C.; Neuenschwander, G.G.; Hart, T.R.; Phelps, M.R.; Sealock, L.J. Jr.

    1993-07-01T23:59:59.000Z

    A catalytic gasification system operating in a pressurized water environment has been developed and refined at Pacific Northwest Laboratory (PNL) for over 12 years. Initial experiments were aimed at developing kinetics information for steam gasification of biomass in the presence of catalysts. The combined use of alkali and metal catalysts was reported for gasification of biomass and its components at low temperatures (350{degrees}C to 450{degrees}C). From the fundamental research evolved the concept of a pressurized, catalytic gasification system for converting wet biomass feedstocks to fuel gas. Extensive batch reactor testing and limited continuous reactor system (CRS) testing were undertaken in the development of this system under sponsorship of the US Department of Energy. A wide range of biomass feedstocks were tested, and the importance of the nickel metal catalyst was identified. Specific use of this process for treating food processing wastes was also studied. The concept application was further expanded to encompass cleanup of hazardous wastewater streams, and results were reported for batch reactor tests and continuous reactor tests. Ongoing work at PNL focuses on refining the catalyst and scaling the system to long-term industrial needs. The process is licensed as the Thermochemical Environmental Energy System (TEES{reg_sign}) to Onsite*Ofsite, Inc., of Duarte, California. This report is a follow-on to the 1989--90 interim report [Elliott et al. 1991], which reviewed the results of the studies conducted with a fixed-bed, continuous-feed, tubular reactor. The discussion here provides an overview of experiments on the wide range of potential feedstock materials conducted in a batch reactor; development of new catalyst materials; and tests performed in continuous-flow reactors at three scales. The appendices contain the history and background of the process development, as well as more detailed descriptions and results of the recent studies.

  13. A Texas project illustrates the benefits of integrated gasification

    SciTech Connect (OSTI)

    Philcox, J. [Praxair Inc., Houston, TX (United States); Fenner, G.W. [Praxair Inc., Tonawanda, NY (United States)

    1997-07-14T23:59:59.000Z

    Gasification can be an attractive option for converting a variety of petroleum feedstocks to chemicals. Natural gas is commonly sued to produce acetic acid, isocyanates, plastics, and fibers. But low-cost, bottom-of-the-barrel feeds, such as vacuum resid, petroleum coke, and asphaltenes, also can be used. In any case, gasification products include synthesis gas, carbon monoxide, hydrogen, steam, carbon dioxide, and power. The more a gasification facility is integrated with utilities and other non-core operations of a production complex, the more economical the products are for all consumers. The paper discusses gasification of natural gas, light hydrocarbons (ethane, propanes, and butanes), and heavy hydrocarbons (distillates, heavy residues, asphalts, coals, petroleum coke). The paper then describes a Texas City Gasification Project, which gasifies methane to produce carbon monoxide, hydrogen, and alcohol. The plant is integrated with a cogeneration plant. Economics are discussed.

  14. Commercial demonstration of biomass gasification the Vermont project

    SciTech Connect (OSTI)

    Farris, S.G.; Weeks, S.T. [Ruture Energy Resources Corp., Atlanta, GA (United States)

    1996-12-31T23:59:59.000Z

    Thermal gasification of biomass for use in gas turbine combined cycle plants will improve efficiencies and reduce capital intensity in the forest and paper industry. One such technology has over 20,000 successful hours of operation at Battelle Columbus Labs (BCL) process research unit (PRU), including the first U.S. demonstration of a gas turbine operating on fuel gas produced by the thermal gasification biomass. A commercial scale demo of the technology (rated at 200 dry tons per day) will be constructed and put into operation during the first quarter of 1997. The initial project phase will provide fuel gas to McNeil`s power boiler. A subsequent phase will utilize the fuel gas in a combustion gas turbine. The technology utilizes an extremely high throughput circulating fluid bed (CFB) gasifier in which biomass (which typically contains 85 percent to 90 percent volatiles) is fully devolatilized with hot sand from a CFB char combustor. The fuel gas is then cooled and conditioned by a conventional scrubbing system to remove particulate, condensable organics, ammonia and metal aerosols which could otherwise cause turbine emission and blade fouling problems. Alternate hot gas conditioning systems are also being developed for final gas clean-up. The fuel gas heating value is 450 to 500 Btus per standard cubic foot. A mid size gas turbine combined cycle plant utilizing the technology will have an approximate net cycle efficiency of 35-40 percent. This compares to a conventional biomass plant with an overall net cycle efficiency of 20-25 percent. Capital costs are expected to be low as the process operates at low pressures without the requirement of an oxygen plant.

  15. Environmental report for the Gasification Product Improvement Facility (GPIF)

    SciTech Connect (OSTI)

    Sadowski, R.S.; Skinner, W.H.; Norris, E.S.; Duck, R.R.; Hass, R.B.; Morgan, M.E.; Helble, J.J.; Johnson, S.A.

    1993-01-01T23:59:59.000Z

    The Fossil Energy Program has a mission to develop energy systems that utilize national coal resources in power systems with increased efficiency and environmental compatibility. Coal gasification technology is a versatile candidate that meets this goal. This two phased project consists primarily of the design, construction and operation of a 5-foot inside diameter (minimum) fixed-bed gasifier called PyGas{trademark} and supporting infrastructure (Phase I), and an additional follow on phase consisting of the design, construction and operation of a hot fuel gas cleanup unit (Phase II). Issues expected to be successfully overcome by PyGas{trademark} through its application in this test facility include the processing of high-swelling coals, which causes agglomeration in conventional fixed-bed gasifiers. Such coals comprise 87% of all eastern coals. Other issues expected to be eliminated or significantly reduced include: production of ash clinkers, production of ammonia, the presence of significant tars and fines, and the volatilization of alkalinity in the product fuel gas. A second portion of the NEPA report is concerned with the emission of toxic metal compounds by the gasification process improvement facility (GPIF). The GPIF facility will be located on site at the Fort Martin facility of Allegheny Power Company, and the energy produced (steam) will be directly used by Fort Martin to produce electricity. The coal used at the GPIF facility will be the same coal used by the utility. Therefore, the emissions of the GPIF will be put in context of the entire facility. The GPIF assessment will be divided into four sections: Estimation of the toxic metals content of the raw coal; calculation of the emissions from Fort Martin normally; an estimate of the emission from the GPIF; and a comparison of the two flows.

  16. Biomass Gasification Research Facility Final Report

    SciTech Connect (OSTI)

    Snyder, Todd R.; Bush, Vann; Felix, Larry G.; Farthing, William E.; Irvin, James H.

    2007-09-30T23:59:59.000Z

    While thermochemical syngas production facilities for biomass utilization are already employed worldwide, exploitation of their potential has been inhibited by technical limitations encountered when attempting to obtain real-time syngas compositional data required for process optimization, reliability, and syngas quality assurance. To address these limitations, the Gas Technology Institute (GTI) carried out two companion projects (under US DOE Cooperative Agreements DE-FC36-02GO12024 and DE-FC36-03GO13175) to develop and demonstrate the equipment and methods required to reliably and continuously obtain accurate and representative on-line syngas compositional data. These objectives were proven through a stepwise series of field tests of biomass and coal gasification process streams. GTI developed the methods and hardware for extractive syngas sample stream delivery and distribution, necessary to make use of state-of-the-art on-line analyzers to evaluate and optimize syngas cleanup and conditioning. The primary objectives of Cooperative Agreement DE-FC36-02GO12024 were the selection, acquisition, and application of a suite of gas analyzers capable of providing near real-time gas analyses to suitably conditioned syngas streams. A review was conducted of sampling options, available analysis technologies, and commercially available analyzers, that could be successfully applied to the challenging task of on-line syngas characterization. The majority of thermochemical process streams comprise multicomponent gas mixtures that, prior to crucial, sequential cleanup procedures, include high concentrations of condensable species, multiple contaminants, and are often produced at high temperatures and pressures. Consequently, GTI engaged in a concurrent effort under Cooperative Agreement DE-FC36-03GO13175 to develop the means to deliver suitably prepared, continuous streams of extracted syngas to a variety of on-line gas analyzers. The review of candidate analysis technology also addressed safety concerns associated with thermochemical process operation that constrain the location and configuration of potential gas analysis equipment. Initial analyzer costs, reliability, accuracy, and operating and maintenance costs were also considered prior to the assembly of suitable analyzers for this work. Initial tests at GTI’s Flex-Fuel Test Facility (FFTF) in late 2004 and early 2005 successfully demonstrated the transport and subsequent analysis of a single depressurized, heat-traced syngas stream to a single analyzer (an Industrial Machine and Control Corporation (IMACC) Fourier-transform infrared spectrometer (FT-IR)) provided by GTI. In March 2005, our sampling approach was significantly expanded when this project participated in the U.S. DOE’s Novel Gas Cleaning (NGC) project. Syngas sample streams from three process locations were transported to a distribution manifold for selectable analysis by the IMACC FT-IR, a Stanford Research Systems QMS300 Mass Spectrometer (SRS MS) obtained under this Cooperative Agreement, and a Varian micro gas chromatograph with thermal conductivity detector (?GC) provided by GTI. A syngas stream from a fourth process location was transported to an Agilent Model 5890 Series II gas chromatograph for highly sensitive gas analyses. The on-line analyses made possible by this sampling system verified the syngas cleaning achieved by the NGC process. In June 2005, GTI collaborated with Weyerhaeuser to characterize the ChemrecTM black liquor gasifier at Weyerhaeuser’s New Bern, North Carolina pulp mill. Over a ten-day period, a broad range of process operating conditions were characterized with the IMACC FT-IR, the SRS MS, the Varian ?GC, and an integrated Gas Chromatograph, Mass Selective Detector, Flame Ionization Detector and Sulfur Chemiluminescence Detector (GC/MSD/FID/SCD) system acquired under this Cooperative Agreement from Wasson-ECE. In this field application, a single sample stream was extracted from this low-pressure, low-temperature process and successfully analyzed by these devices. In late 2005,

  17. Advanced Gasification By-Product Utilization

    SciTech Connect (OSTI)

    Rodney Andrews; Aurora Rubel; Jack Groppo; Ari Geertsema; Frank Huggins; M. Mercedes Maroto-Valer; Brandie M. Markley; Harold Schobert

    2006-02-01T23:59:59.000Z

    With the recent passing of new legislation designed to permanently cap and reduce mercury emissions from coal-fired utilities, it is more important than ever to develop and improve upon methods of controlling mercury emissions. One promising technique is carbon sorbent injection into the flue gas of the coal-fired power plant. Currently, this technology is very expensive as costly commercially activated carbons are used as sorbents. There is also a significant lack of understanding of the interaction between mercury vapor and the carbon sorbent, which adds to the difficulty of predicting the amount of sorbent needed for specific plant configurations. Due to its inherent porosity and adsorption properties as well as on-site availability, carbons derived from gasifiers are potential mercury sorbent candidates. Furthermore, because of the increasing restricted use of landfilling, the coal industry is very interested in finding uses for these materials as an alternative to the current disposal practice. The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported for the period September 1, 2004 to August 31, 2005. This contract is with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involves the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, and characterization of these materials for use as polymer fillers.

  18. Integrated gasification combined-cycle research development and demonstration activities in the US

    SciTech Connect (OSTI)

    Ness, H.M.; Brdar, R.D.

    1996-09-01T23:59:59.000Z

    The United States Department of Energy (DOE)`s Office of Fossil Energy, Morgantown Energy Technology Center, is managing a research development and demonstration (RD&D) program that supports the commercialization of integrated gasification combined-cycle (IGCC) advanced power systems. This overview briefly describes the supporting RD&D activities and the IGCC projects selected for demonstration in the Clean Coal Technology (CCT) Program.

  19. Integrated gasification combined-cycle research development and demonstration activities in the U.S.

    SciTech Connect (OSTI)

    Ness, H.M.

    1994-12-31T23:59:59.000Z

    The United States Department of Energy (DOE) has selected seven integrated gasification combined-cycle (IGCC) advanced power systems for demonstration in the Clean Coal Technology (CCT) Program. DOE`s Office of Fossil Energy, Morgantown Energy Technology Center, is managing a research development and demonstration (RD&D)program that supports the CCT program, and addresses long-term improvements in support of IGCC technology. This overview briefly describes the CCT projects and the supporting RD&D activities.

  20. Flow characteristics in underground coal gasification

    SciTech Connect (OSTI)

    Chang, H.L.; Himmelblau, D.M.; Edgar, T.F.

    1982-01-01T23:59:59.000Z

    During the underground coal gasification field test at the Hoe Creek site No. 2, Wyoming, helium pulses were introduced to develop information to characterize the flow field, and to estimate the coefficients in dispersion models of the flow. Quantitative analysis of the tracer response curves shows an increasing departure from a plug flow regime with time because of the combined effects of the free and forced convection in addition to the complex non-uniformity of the flow field. The Peclet number was a function of temperature, pressure, gas recovery and characteristic velocity, as well as the split of the gas between the parallel streams in the model. 17 refs.

  1. Hydrogen Production: Coal Gasification | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of Blythe SolarContamination Detectorof EnergyCoal Gasification Hydrogen

  2. Comparative analysis of peat gasification reactor configuration. Final report

    SciTech Connect (OSTI)

    Not Available

    1981-07-01T23:59:59.000Z

    This report summarizes the comparative analysis of two generic gasifiers (fluidized bed and entrained bed) and two specific hydrogasifiers (IGT's Peat-gas and Rockwell International's hydrogasifier). The objective is to establish a basis for recommending a peat gasification reactor configuration for testing in a DOE peat gasification pilot plant project. The approach involved the following four steps: data base evaluation, regression analysis, a chemical engineering evaluation of upstream and downstream equipment requirement, and computer simulation. Mathematical models and computer programs were developed to simulate the entrained-bed and fluidized-bed reactors. Parametric analyses were made, using these computer programs, to test the sensitivity and effects of significant operating variables (temperature, pressure and feed gas composition, for instance) on the product gas composition in the IGT gasifier and Rockwell International gasifier. This review and analysis concentrates primarily upon the Peatgas process of the Institute of Gas Technology and the Rockwell International Hydrogasification Process. The two-stage Peatgas process appears to have advantages in higher thermal efficiency, smaller capital investment, and its application of existing commercial operations and proven design practices from other types of fluidized solids processing units. There are two problems concerning operability of the Peatgas process: (1) the design of a fluidized solids unit for quite low standpipe densities (approximately 11 to 15 pounds per cubic foot), which may become even lower upon operating upsets, and (2) the potential problem of ash sintering in the very hot combustion zone of the steam-oxygen gasifier. On a relative time scale of development, the Peatgas would seem to be much closer to possible early commercialization than is the Rockwell system.

  3. Chemical Processing in High-Pressure Aqueous Environments. 7. Process Development for Catalytic Gasification of Wet Biomass

    E-Print Network [OSTI]

    Gasification of Wet Biomass Feedstocks Douglas C. Elliott,* Gary G. Neuenschwander, Todd R. Hart, R. Scott the preliminary results of continuous-flow reactor studies with wet biomass feedstocks using new catalyst systems of con- tinuous reactor tests with biomass feedstocks provide preliminary short-term processing results,8

  4. Wabash River coal gasification repowering project: Public design report

    SciTech Connect (OSTI)

    NONE

    1995-07-01T23:59:59.000Z

    The Wabash River Coal Gasification Repowering Project (the Project), conceived in October of 1990 and selected by the US Department of Energy as a Clean Coal IV demonstration project in September 1991, is expected to begin commercial operations in August of 1995. The Participants, Destec Energy, Inc., (Destec) of Houston, Texas and PSI Energy, Inc., (PSI) of Plainfield, Indiana, formed the Wabash River Coal Gasification Repowering Project Joint Venture (the JV) to participate in the DOE`s Clean Coal Technology (CCT) program by demonstrating the coal gasification repowering of an existing 1950`s vintage generating unit affected by the Clean Air Act Amendments (CAAA). The Participants, acting through the JV, signed the Cooperative Agreement with the DOE in July 1992. The Participants jointly developed, and separately designed, constructed, own, and will operate an integrated coal gasification combined cycle (CGCC) power plant using Destec`s coal gasification technology to repower Unit {number_sign}1 at PSI`s Wabash River Generating Station located in Terre Haute, Indiana. PSI is responsible for the new power generation facilities and modification of the existing unit, while Destec is responsible for the coal gasification plant. The Project demonstrates integration of the pre-existing steam turbine generator, auxiliaries, and coal handling facilities with a new combustion turbine generator/heat recovery steam generator tandem and the coal gasification facilities.

  5. ENCOAL mild coal gasification project. Annual report

    SciTech Connect (OSTI)

    Not Available

    1993-10-01T23:59:59.000Z

    This document is the combination of the fourth quarter report (July--September 1993) and the 1993 annual report for the ENCOAL project. The following pages include the background and process description for the project, brief summaries of the accomplishments for the first three quarters, and a detailed fourth quarter report. Its purpose is to convey the accomplishments and current progress of the project. ENCOAL Corporation, has completed the construction of a mild gasification demonstration plant at Triton Coal Company`s Buckskin Mine near Gillette, Wyoming. The process, using Liquids From Coal (LFC) technology developed by SMC and SGI International, utilizes low-sulfur Powder River Basin coal to produce two new fuels, Process Derived Fuel (PDF) and Coal Derived Liquids (CDL). ENCOAL submitted an application to the US Department of Energy (DOE) in August 1989, soliciting joint funding of the project in the third round of the Clean Coal Technology Program. The project was selected by DOE in December, 1989 and the Cooperative Agreement approved in September, 1990. Construction, commissioning, and start-up of the ENCOAL mild coal gasification facility was completed in June of 1992, and the project is currently in the operations phase. Some plant modifications have been required and are discussed in this report.

  6. In Situ Causticizing for Black Liquor Gasification

    SciTech Connect (OSTI)

    Scott Alan Sinquefield

    2005-10-01T23:59:59.000Z

    Black liquor gasification offers a number of attractive incentives to replace Tomlinson boilers but it also leads to an increase in the causticizing load. Reasons for this have been described in previous reports (FY04 ERC, et.al.). The chemistries have also been covered but will be reviewed here briefly. Experimental results of the causticizing reactions with black liquor are presented here. Results of the modeling work were presented in detail in the Phase 1 report. They are included in Table 2 for comparison but will not be discussed in detail. The causticizing agents were added to black liquor in the ratios shown in Table 1, mixed, and then spray-dried. The mixture ratios (doping levels) reflect amount calculated from the stoichiometry above to achieve specified conversions shown in the table. The solids were sieved to 63-90 microns for use in the entrained flow reactors. The firing conditions are shown in Table 2. Pictures and descriptions of the reactors can be found in the Phase 1 annual report. Following gasification, the solids (char) was collected and analyzed by coulometric titration (for carbonate and total carbon), and by inductively coupled plasma emission spectroscopy (ICP) for a wide array of metals.

  7. Research on chemical factors in underground coal gasification. Final technical report

    SciTech Connect (OSTI)

    Edgar, T.F.

    1985-09-01T23:59:59.000Z

    The goal of this research has been to acquire experimental data and develop mathematical models in order to analyze results from laboratory-scale and field-scale experiments on underground coal gasification (UCG), especially for low-rank coals such as Texas lignite. Experimental data for water injection in a combustion tube, coal core combustion, and coal block gasification are reported; in parallel, a mathematical model for the combustion tube temperature profile and gas composition was developed which compared favorably with experimental data. A mathematical model for predicting gas composition and coal recovery in the Hoe Creek field experiment has been completed and verified with field data. Two experiments have been constructed to obtain data on reactions of interest to UCG; these include an apparatus for determining the kinetics of tar cracking and a microreactor for analyzing the process dynamics of the water gas shift reaction carried out in a fixed bed catalytic system. 44 refs., 60 figs., 22 tabs.

  8. GASIFICATION TEST RUN TC06

    SciTech Connect (OSTI)

    Southern Company Services, Inc.

    2003-08-01T23:59:59.000Z

    This report discusses test campaign TC06 of the Kellogg Brown & Root, Inc. (KBR) Transport Reactor train with a Siemens Westinghouse Power Corporation (Siemens Westinghouse) particle filter system at the Power Systems Development Facility (PSDF) located in Wilsonville, Alabama. The Transport Reactor is an advanced circulating fluidized-bed reactor designed to operate as either a combustor or a gasifier using a particulate control device (PCD). The Transport Reactor was operated as a pressurized gasifier during TC06. Test run TC06 was started on July 4, 2001, and completed on September 24, 2001, with an interruption in service between July 25, 2001, and August 19, 2001, due to a filter element failure in the PCD caused by abnormal operating conditions while tuning the main air compressor. The reactor temperature was varied between 1,725 and 1,825 F at pressures from 190 to 230 psig. In TC06, 1,214 hours of solid circulation and 1,025 hours of coal feed were attained with 797 hours of coal feed after the filter element failure. Both reactor and PCD operations were stable during the test run with a stable baseline pressure drop. Due to its length and stability, the TC06 test run provided valuable data necessary to analyze long-term reactor operations and to identify necessary modifications to improve equipment and process performance as well as progressing the goal of many thousands of hours of filter element exposure.

  9. GASIFICATION PLANT COST AND PERFORMANCE OPTIMIZATION

    SciTech Connect (OSTI)

    Samuel S. Tam

    2002-05-01T23:59:59.000Z

    The goal of this series of design and estimating efforts was to start from the as-built design and actual operating data from the DOE sponsored Wabash River Coal Gasification Repowering Project and to develop optimized designs for several coal and petroleum coke IGCC power and coproduction projects. First, the team developed a design for a grass-roots plant equivalent to the Wabash River Coal Gasification Repowering Project to provide a starting point and a detailed mid-year 2000 cost estimate based on the actual as-built plant design and subsequent modifications (Subtask 1.1). This unoptimized plant has a thermal efficiency of 38.3% (HHV) and a mid-year 2000 EPC cost of 1,681 $/kW. This design was enlarged and modified to become a Petroleum Coke IGCC Coproduction Plant (Subtask 1.2) that produces hydrogen, industrial grade steam, and fuel gas for an adjacent Gulf Coast petroleum refinery in addition to export power. A structured Value Improving Practices (VIP) approach was applied to reduce costs and improve performance. The base case (Subtask 1.3) Optimized Petroleum Coke IGCC Coproduction Plant increased the power output by 16% and reduced the plant cost by 23%. The study looked at several options for gasifier sparing to enhance availability. Subtask 1.9 produced a detailed report on this availability analyses study. The Subtask 1.3 Next Plant, which retains the preferred spare gasification train approach, only reduced the cost by about 21%, but it has the highest availability (94.6%) and produces power at 30 $/MW-hr (at a 12% ROI). Thus, such a coke-fueled IGCC coproduction plant could fill a near term niche market. In all cases, the emissions performance of these plants is superior to the Wabash River project. Subtasks 1.5A and B developed designs for single-train coal and coke-fueled power plants. This side-by-side comparison of these plants, which contain the Subtask 1.3 VIP enhancements, showed their similarity both in design and cost (1,318 $/kW for the coal plant and 1,260 $/kW for the coke plant). Therefore, in the near term, a coke IGCC power plant could penetrate the market and provide a foundation for future coal-fueled facilities. Subtask 1.6 generated a design, cost estimate and economics for a multiple train coal-fueled IGCC powerplant, also based on the Subtaks 1.3 cases. The Subtask 1.6 four gasification train plant has a thermal efficiency of 40.6% (HHV) and cost 1,066 $/kW. The single-train advanced Subtask 1.4 plant, which uses an advanced ''G/H-class'' combustion turbine, can have a thermal efficiency of 45.4% (HHV) and a plant cost of 1,096 $/kW. Multi-train plants will further reduce the cost. Again, all these plants have superior emissions performance. Subtask 1.7 developed an optimized design for a coal to hydrogen plant. At current natural gas prices, this facility is not competitive with hydrogen produced from natural gas. The preferred scenario is to coproduce hydrogen in a plant similar to Subtask 1.3, as described above. Subtask 1.8 evaluated the potential merits of warm gas cleanup technology. This study showed that selective catalytic oxidation of hydrogen sulfide (SCOHS) is promising. As gasification technology matures, SCOHS and other improvements identified in this study will lead to further cost reductions and efficiency improvements.

  10. Advanced High-Temperature, High-Pressure Transport Reactor Gasification

    SciTech Connect (OSTI)

    Michael Swanson; Daniel Laudal

    2008-03-31T23:59:59.000Z

    The U.S. Department of Energy (DOE) National Energy Technology Laboratory Office of Coal and Environmental Systems has as its mission to develop advanced gasification-based technologies for affordable, efficient, zero-emission power generation. These advanced power systems, which are expected to produce near-zero pollutants, are an integral part of DOE's Vision 21 Program. DOE has also been developing advanced gasification systems that lower the capital and operating costs of producing syngas for chemical production. A transport reactor has shown potential to be a low-cost syngas producer compared to other gasification systems since its high-throughput-per-unit cross-sectional area reduces capital costs. This work directly supports the Power Systems Development Facility utilizing the KBR transport reactor located at the Southern Company Services Wilsonville, Alabama, site. Over 2800 hours of operation on 11 different coals ranging from bituminous to lignite along with a petroleum coke has been completed to date in the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center (EERC). The EERC has established an extensive database on the operation of these various fuels in both air-blown and oxygen-blown modes utilizing a pilot-scale transport reactor gasifier. This database has been useful in determining the effectiveness of design changes on an advanced transport reactor gasifier and for determining the performance of various feedstocks in a transport reactor. The effects of different fuel types on both gasifier performance and the operation of the hot-gas filter system have been determined. It has been demonstrated that corrected fuel gas heating values ranging from 90 to 130 Btu/scf have been achieved in air-blown mode, while heating values up to 230 Btu/scf on a dry basis have been achieved in oxygen-blown mode. Carbon conversions up to 95% have also been obtained and are highly dependent on the oxygen-coal ratio. Higher-reactivity (low-rank) coals appear to perform better in a transport reactor than the less reactive bituminous coals. Factors that affect TRDU product gas quality appear to be coal type, temperature, and air/coal ratios. Testing with a higher-ash, high-moisture, low-rank coal from the Red Hills Mine of the Mississippi Lignite Mining Company has recently been completed. Testing with the lignite coal generated a fuel gas with acceptable heating value and a high carbon conversion, although some drying of the high-moisture lignite was required before coal-feeding problems were resolved. No ash deposition or bed material agglomeration issues were encountered with this fuel. In order to better understand the coal devolatilization and cracking chemistry occurring in the riser of the transport reactor, gas and solid sampling directly from the riser and the filter outlet has been accomplished. This was done using a baseline Powder River Basin subbituminous coal from the Peabody Energy North Antelope Rochelle Mine near Gillette, Wyoming.

  11. Model Predictive Control of Integrated Gasification Combined Cycle Power Plants

    SciTech Connect (OSTI)

    B. Wayne Bequette; Priyadarshi Mahapatra

    2010-08-31T23:59:59.000Z

    The primary project objectives were to understand how the process design of an integrated gasification combined cycle (IGCC) power plant affects the dynamic operability and controllability of the process. Steady-state and dynamic simulation models were developed to predict the process behavior during typical transients that occur in plant operation. Advanced control strategies were developed to improve the ability of the process to follow changes in the power load demand, and to improve performance during transitions between power levels. Another objective of the proposed work was to educate graduate and undergraduate students in the application of process systems and control to coal technology. Educational materials were developed for use in engineering courses to further broaden this exposure to many students. ASPENTECH software was used to perform steady-state and dynamic simulations of an IGCC power plant. Linear systems analysis techniques were used to assess the steady-state and dynamic operability of the power plant under various plant operating conditions. Model predictive control (MPC) strategies were developed to improve the dynamic operation of the power plants. MATLAB and SIMULINK software were used for systems analysis and control system design, and the SIMULINK functionality in ASPEN DYNAMICS was used to test the control strategies on the simulated process. Project funds were used to support a Ph.D. student to receive education and training in coal technology and the application of modeling and simulation techniques.

  12. Experimental program for the development of peat gasification. Monthly status report, February 1-February 28, 1981

    SciTech Connect (OSTI)

    Not Available

    1981-03-01T23:59:59.000Z

    In Task 1 (Single-Stage Fluidized-Bed Gasification Tests), one test was conducted with Minnesota peat in the process development unit (PDU), using steam and oxygen. The test was performed at a pressure of 268 psia, a fluidization velocity of 1.0 ft/s, and an average bed temperature of 1680/sup 0/F. The objective was to determine the effects of high feed moisture content (22-weight-percent moisture) and low gasification pressure on the gasification characteristics of peat. Most of the previous tests had been conducted at a nominal pressure of 500 psia. The test was successful; about 1 hour of steady-state operation was achieved before sintering began and the test was ended. The results of a test conducted previously with Minnesota peat containing about 8-weight-percent moisture were analyzed and are presented this month. The test was conducted at an average bed temperature of 1700/sup 0/F, a pressure of 522 psia, and a steam-to-carbon feed ratio of 1.1 mol/mol; it achieved a carbon conversion of about 84%. In Task 2 (Wet-Carbonization PDU-Scale Tests), orders were placed for long-lead-time equipment for the PDU. The design and specifications for the slurry heater/cooler system and the shell-and-tube heat exchangers have been finalized. The installation of the instrumentation and the control panel for the PDU is continuing. In Task 3 (Kinetic Data on Alaska and Florida Peats), efforts were made to obtain representative samples of peats from Alaska and Florida. A sample of Florida reed-sedge peat has been obtained and is being analyzed. Samples of Alaskan peat have been taken by the company conducting the US Department of Energy (DOE) peat resource assessment work; however, they have not yet been received. In Task 4 (Effect of Dewatering Methodology on Peat Gasification), efforts to obtain peat dewatered by various methods were continued.

  13. Wood Gasification: Where It's At, Where It's Going

    E-Print Network [OSTI]

    Murphy, M. L.

    1981-01-01T23:59:59.000Z

    This paper discusses the principles and practice of various designs of biomass/wood gasifiers. In general, the basic principle of gasification is reviewed. A look at existing gasifier schemes, including packed bed updraft, downdraft, and fluidized...

  14. Black Liquor Gasification Process Review and Status Update 

    E-Print Network [OSTI]

    Brown, C.

    1993-01-01T23:59:59.000Z

    After more than two decades of research and development, black liquor gasification is poised to become a commercial reality in the 90's. Several promising developments are underway in North America and Europe. In fact, all major recovery boiler...

  15. Wood Gasification: Where It's At, Where It's Going 

    E-Print Network [OSTI]

    Murphy, M. L.

    1981-01-01T23:59:59.000Z

    This paper discusses the principles and practice of various designs of biomass/wood gasifiers. In general, the basic principle of gasification is reviewed. A look at existing gasifier schemes, including packed bed updraft, downdraft, and fluidized...

  16. Gasification and combustion modeling for porous char particles

    E-Print Network [OSTI]

    Singer, Simcha Lev

    2012-01-01T23:59:59.000Z

    Gasification and combustion of porous char particles occurs in many industrial applications. Reactor-scale outputs of importance depend critically on processes that occur at the particle-scale. Because char particles often ...

  17. Energy Optimization of Bioethanol Production via Gasification of Switchgrass

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    1 Energy Optimization of Bioethanol Production via Gasification of Switchgrass Mariano Martín Abstract. In this paper, we address the conceptual design of the bioethanol process from switchgrass via of $0.41/gal Keywords: Energy; Biofuels; Bioethanol; Process synthesis

  18. The suitability of coal gasification in India's energy sector

    E-Print Network [OSTI]

    Simpson, Lori Allison

    2006-01-01T23:59:59.000Z

    Integrated Gasification Combined Cycle (IGCC), an advanced coal-based power generation technology, may be an important technology to help India meet its future power needs. It has the potential to provide higher generating ...

  19. Coal gasification-based integrated coproduction energy facilities

    SciTech Connect (OSTI)

    Baumann, P.D. (InterFact, Inc., Dallas, TX (US)); Epstein, M. (Electric Power Research Inst., Palo Alto, CA (United States)); Kern, E.E. (Houston Lighting and Power Co., TX (United States))

    1992-01-01T23:59:59.000Z

    Coal gasification has been a technological reality for over a half century, being first used in great detail in Europe as an alternative to petroleum. Several projects in the US in the last decade have led to the commercial demonstration and verification of the coal gasification process. This paper reports that, in an effort to reduce the cost of electricity from an Integrated Gasification Combined Cycle Plant, the Electric Power Research Institute embarked in a program to research, evaluate and potentially demonstrate a coal gasification-based integrated coproduction energy facility, and release an RFP in mid 1990 as Phase I of that program. Houston Lighting and Power Company responded with a proposal in its ongoing effort to study emerging technologies for electricity production. HL and P recognized the opportunities available to them in coproduction because of their close proximity to the world's largest petrochemical complex located on the Houston Ship Channel.

  20. Modeling, Optimization and Economic Evaluation of Residual Biomass Gasification 

    E-Print Network [OSTI]

    Georgeson, Adam

    2012-02-14T23:59:59.000Z

    Gasification is a thermo-chemical process which transforms biomass into valuable synthesis gas. Integrated with a biorefinery it can address the facility’s residue handling challenges and input demands. A number of feedstock, technology, oxidizer...

  1. Kinetics of gasification of black liquor char by steam

    SciTech Connect (OSTI)

    Li, J.; van Heiningen, A.R.P. (Dept. of Chemical Engineering, McGill Univ., Pulp and Paper Research Inst. of Canada, Montreal, Quebec (CA))

    1991-07-01T23:59:59.000Z

    This paper reports on the steam gasification kinetics of kraft black liquor char that were studied in a thermogravimetric analysis reactor. The effect of steam and hydrogen concentration on gasification rate can be described by Langmuir-Hinshelwood type kinetics. An activation energy of 210 kJ/mol was obtained. Methane formation was negligible, and H{sub 2}S was the major gaseous sulfur-containing product obtained over the temperature range studied, 873-973 K. The CO{sub 2} concentration was higher than calculated for the water-shift reaction at equilibrium. A gasification mechanism is proposed whereby CO{sub 2} is one of the primary gasification products.

  2. Demonstration of Black Liquor Gasification at Big Island

    SciTech Connect (OSTI)

    Robert DeCarrera

    2007-04-14T23:59:59.000Z

    This Final Technical Report provides an account of the project for the demonstration of Black Liquor Gasification at Georgia-Pacific LLC's Big Island, VA facility. This report covers the period from May 5, 2000 through November 30, 2006.

  3. October 2005 Gasification-Based Fuels and Electricity Production from

    E-Print Network [OSTI]

    ................................................. 15 3.2.1 Synthesis of Fischer-Tropsch Fuels.4 FISCHER-TROPSCH FUELS PRODUCTION, and production cost estimates for gasification-based thermochemical conversion of switchgrass into Fischer-Tropsch

  4. Underground coal gasification: a brief review of current status

    SciTech Connect (OSTI)

    Shafirovich, E.; Varma, A. [Purdue University, West Lafayette, IN (United States). School of Chemical Engineering

    2009-09-15T23:59:59.000Z

    Coal gasification is a promising option for the future use of coal. Similarly to gasification in industrial reactors, underground coal gasification (UCG) produces syngas, which can be used for power generation or for the production of liquid hydrocarbon fuels and other valuable chemical products. As compared with conventional mining and surface gasification, UCG promises lower capital/operating costs and also has other advantages, such as no human labor underground. In addition, UCG has the potential to be linked with carbon capture and sequestration. The increasing demand for energy, depletion of oil and gas resources, and threat of global climate change lead to growing interest in UCG throughout the world. In this article, we review the current status of this technology, focusing on recent developments in various countries.

  5. ECONOMIC EVALUATION OF CO2 SEQUESTRATION TECHNOLOGIES TASK 4, BIOMASS GASIFICATION-BASED PROCESSING

    SciTech Connect (OSTI)

    Martha L. Rollins; Les Reardon; David Nichols; Patrick Lee; Millicent Moore; Mike Crim; Robert Luttrell; Evan Hughes

    2002-04-01T23:59:59.000Z

    Biomass derived energy currently accounts for about 3 quads of total primary energy use in the United States. Of this amount, about 0.8 quads are used for power generation. Several biomass energy production technologies exist today which contribute to this energy mix. Biomass combustion technologies have been the dominant source of biomass energy production, both historically and during the past two decades of expansion of modern biomass energy in the U. S. and Europe. As a research and development activity, biomass gasification has usually been the major emphasis as a method of more efficiently utilizing the energy potential of biomass, particularly wood. Numerous biomass gasification technologies exist today in various stages of development. Some are simple systems, while others employ a high degree of integration for maximum energy utilization. The purpose of this study is to conduct a technical and economic comparison of up to three biomass gasification technologies, including the carbon dioxide emissions reduction potential of each. To accomplish this, a literature search was first conducted to determine which technologies were most promising based on a specific set of criteria. During this reporting period, the technical and economic performances of the selected processes were evaluated using computer models and available literature. The results of these evaluations are summarized in this report.

  6. ECONOMIC EVALUATION OF CO2 SEQUESTRATION TECHNOLOGIES TASK 4, BIOMASS GASIFICATION-BASED PROCESSING

    SciTech Connect (OSTI)

    Martha L. Rollins; Les Reardon; David Nichols; Patrick Lee; Millicent Moore; Mike Crim; Robert Luttrell; Evan Hughes

    2002-06-01T23:59:59.000Z

    Biomass derived energy currently accounts for about 3 quads of total primary energy use in the United States. Of this amount, about 0.8 quads are used for power generation. Several biomass energy production technologies exist today which contribute to this energy mix. Biomass combustion technologies have been the dominant source of biomass energy production, both historically and during the past two decades of expansion of modern biomass energy in the U. S. and Europe. As a research and development activity, biomass gasification has usually been the major emphasis as a method of more efficiently utilizing the energy potential of biomass, particularly wood. Numerous biomass gasification technologies exist today in various stages of development. Some are simple systems, while others employ a high degree of integration for maximum energy utilization. The purpose of this study is to conduct a technical and economic comparison of up to three biomass gasification technologies, including the carbon dioxide emissions reduction potential of each. To accomplish this, a literature search was first conducted to determine which technologies were most promising based on a specific set of criteria. The technical and economic performances of the selected processes were evaluated using computer models and available literature. Using these results, the carbon sequestration potential of the three technologies was then evaluated. The results of these evaluations are given in this final report.

  7. Mathematical model of the pyrolysis and gasification of coal

    SciTech Connect (OSTI)

    Kalinenko, R.A.; Levitskii, A.A.; Mirokhin, Yu.A.; Polak, L.S.

    1987-12-01T23:59:59.000Z

    A kinetic model of the pyrolysis and gasification of coal at moderate (1100-1300 K) and high (2000-3000 K) temperatures, which includes reactions resulting in the release of volatile substances and their further conversions and takes into account the processes of heat and mass transfer, has been developed. A calculation of the composition of the gasification products of brown coals on the basis of the model has displayed good agreement with experimental data.

  8. Biological treatment of underground coal gasification wastewaters

    SciTech Connect (OSTI)

    Bryant, C.W. Jr.; Humenick, M.J.; Cawein, C.C.; Nolan, B.T. III

    1985-05-01T23:59:59.000Z

    Biotreatability studies using underground coal gasification (UCG) wastewaters were performed by the University of Arizona and the University of Wyoming. The University of Arizona researchers found that UCG condensate could be effectively treated by activated sludge, using feed wastewaters of up to 50% strength. Total organic carbon (TOC) and chemical oxygen demand (COD) removals approached 90% during this research. The University of Wyoming researchers found that solvent extraction and hot-gas stripping were effective pretreatments for undiluted UCG condensate and that addition of powdered activated carbon enhanced the biotreatment process. TOC and COD removals resulting from the combination of pretreatments and biotreatment were 91% and 95%, respectively. The yield, decay, and substrate removal rate coefficients were greater in the University of Wyoming study than in the University of Arizona study. This was possibly caused by removing bioinhibitory substances, such as ammonia, with pretreatment. 18 refs., 25 figs., 6 tabs.

  9. Rocky Mountain 1 Underground Coal Gasification Project

    SciTech Connect (OSTI)

    Not Available

    1992-03-01T23:59:59.000Z

    The Rocky Mountain 1 Underground Coal Gasification Test or Burn was conducted from approximately mid-November, 1987 through February, 1988. After the burn the project began proceeding with the following overall tasks: venting, flushing and cooling of the cavities; subsurface or groundwater cleanup; post-burn coring and drilling; groundwater monitoring, and site restoration/reclamation. By the beginning of 1991 field activities associated with venting, flushing and cooling of the cavities and post-burn coring and drilling had been completed. However, data analysis continued including the University of North Dakota analyzing drilling and coring data, and the US Department of Energy (DOE)/EG G developing a chronological listing of project events.

  10. Advanced Gasification By-Product Utilization

    SciTech Connect (OSTI)

    Rodney Andrews; Aurora Rubel; Jack Groppo; Brock Marrs; Ari Geertsema; Frank Huggins; M. Mercedes Maroto-Valer; Brandie M. Markley; Zhe Lu; Harold Schobert

    2006-08-31T23:59:59.000Z

    With the passing of legislation designed to permanently cap and reduce mercury emissions from coal-fired utilities, it is more important than ever to develop and improve upon methods of controlling mercury emissions. One promising technique is carbon sorbent injection into the flue gas of the coal-fired power plant. Currently, this technology is very expensive as costly commercially activated carbons are used as sorbents. There is also a significant lack of understanding of the interaction between mercury vapor and the carbon sorbent, which adds to the difficulty of predicting the amount of sorbent needed for specific plant configurations. Due to its inherent porosity and adsorption properties as well as on-site availability, carbons derived from gasifiers are potential mercury sorbent candidates. Furthermore, because of the increasing restricted use of landfilling, the coal industry is very interested in finding uses for these materials as an alternative to the current disposal practice. The results of laboratory investigations and supporting technical assessments conducted under DOE Subcontract No. DE-FG26-03NT41795 are reported. This contract was with the University of Kentucky Research Foundation, which supports work with the University of Kentucky Center for Applied Energy Research and The Pennsylvania State University Energy Institute. The worked described was part of a project entitled ''Advanced Gasification By-Product Utilization''. This work involved the development of technologies for the separation and characterization of coal gasification slags from operating gasification units, activation of these materials to increase mercury and nitrogen oxide capture efficiency, assessment of these materials as sorbents for mercury and nitrogen oxides, assessment of the potential for leaching of Hg captured by the carbons, analysis of the slags for cement applications, and characterization of these materials for use as polymer fillers. The objectives of this collaborative effort between the University of Kentucky Center for Applied Energy Research (CAER), The Pennsylvania State University Energy Institute, and industry collaborators supplying gasifier char samples were to investigate the potential use of gasifier slag carbons as a source of low cost sorbent for Hg and NOX capture from combustion flue gas, concrete applications, polymer fillers and as a source of activated carbons. Primary objectives were to determine the relationship of surface area, pore size, pore size distribution, and mineral content on Hg storage of gasifier carbons and to define the site of Hg capture. The ability of gasifier slag carbon to capture NOX and the effect of NOX on Hg adsorption were goals. Secondary goals were the determination of the potential for use of the slags for cement and filler applications. Since gasifier chars have already gone through a devolatilization process in a reducing atmosphere in the gasifier, they only required to be activated to be used as activated carbons. Therefore, the principal objective of the work at PSU was to characterize and utilize gasification slag carbons for the production of activated carbons and other carbon fillers. Tests for the Hg and NOX adsorption potential of these activated gasifier carbons were performed at the CAER. During the course of this project, gasifier slag samples chemically and physically characterized at UK were supplied to PSU who also characterized the samples for sorption characteristics and independently tested for Hg-capture. At the CAER as-received slags were tested for Hg and NOX adsorption. The most promising of these were activated chemically. The PSU group applied thermal and steam activation to a representative group of the gasifier slag samples separated by particle sizes. The activated samples were tested at UK for Hg-sorption and NOX capture and the most promising Hg adsorbers were tested for Hg capture in a simulated flue gas. Both UK and PSU tested the use of the gasifier slag samples as fillers. The CAER analyzed the slags for possible use in cement applications

  11. Biomass Gasification Research Facility Final Report

    SciTech Connect (OSTI)

    Snyder, Todd R.; Bush, Vann; Felix, Larry G.; Farthing, William E.; Irvin, James H.

    2007-09-30T23:59:59.000Z

    While thermochemical syngas production facilities for biomass utilization are already employed worldwide, exploitation of their potential has been inhibited by technical limitations encountered when attempting to obtain real-time syngas compositional data required for process optimization, reliability, and syngas quality assurance. To address these limitations, the Gas Technology Institute (GTI) carried out two companion projects (under US DOE Cooperative Agreements DE-FC36-03GO13175 and DE-FC36-02GO12024) to develop and demonstrate the equipment and methods required to reliably and continuously obtain accurate and representative on-line syngas compositional data. These objectives were proven through a stepwise series of field tests of biomass and coal gasification process streams. GTI developed the methods and hardware for extractive syngas sample stream delivery and distribution, necessary to make use of state-of-the-art on-line analyzers to evaluate and optimize syngas cleanup and conditioning. This multi-year effort to develop methods to effectively monitor gaseous species produced in thermochemical process streams resulted in a sampling and analysis approach that is continuous, sensitive, comprehensive, accurate, reliable, economical, and safe. The improved approach for sampling thermochemical processes that GTI developed and demonstrated in its series of field demonstrations successfully provides continuous transport of vapor-phase syngas streams extracted from the main gasification process stream to multiple, commercially available analyzers. The syngas stream is carefully managed through multiple steps to successfully convey it to the analyzers, while at the same time bringing the stream to temperature and pressure conditions that are compatible with the analyzers. The primary principle that guides the sample transport is that throughout the entire sampling train, the temperature of the syngas stream is maintained above the maximum condensation temperature of the vapor phase components of the conveyed sample gas. In addition, to minimize adsorption or chemical changes in the syngas components prior to analysis, the temperature of the transported stream is maintained as hot as is practical, while still being cooled only as much necessary prior to entering the analyzer(s). The successful transport of the sample gas stream to the analyzer(s) is accomplished through the managed combination of four basic gas conditioning methods that are applied as specifically called for by the process conditions, the gas constituent concentrations, the analyzer requirements, and the objectives of the syngas analyses: 1) removing entrained particulate matter from the sample stream; 2) maintaining the temperature of the sample gas stream; 3) lowering the pressure of the sample gas stream to decrease the vapor pressures of all the component vapor species in the sample stream; and 4) diluting the gas stream with a metered, inert gas, such as nitrogen. Proof-of-concept field demonstrations of the sampling approach were conducted for gasification process streams from a black liquor gasifier, and from the gasification of biomass and coal feedstocks at GTI’s Flex-Fuel Test Facility. In addition to the descriptions and data included in this Final Report, GTI produced a Special Topical Report, Design and Protocol for Monitoring Gaseous Species in Thermochemical Processes, that explains and describes in detail the objectives, principles, design, hardware, installation, operation and representative data produced during this successful developmental effort. Although the specific analyzers used under Cooperative Agreement DE-FC36-02GO12024 were referenced in the Topical Report and this Final Report, the sampling interface design they present is generic enough to adapt to other analyzers that may be more appropriate to alternate process streams or facilities.

  12. Flow characteristics in underground coal gasification

    SciTech Connect (OSTI)

    Chang, H.L.; Himmelblau, D.M.; Edgar, T.F.

    1982-01-01T23:59:59.000Z

    During the Hoe Creek No. 2 (Wyoming) underground-coal-gasification field test, researchers introduced helium pulses to characterize the flow field and to estimate the coefficients in dispersion models of the flow. Flow models such as the axial-dispersion and parallel tanks-in-series models allowed interpretation of the in situ combustion flow field from the residence time distribution of the tracer gas. A quantitative analysis of the Hoe Creek tracer response curves revealed an increasing departure from a plug-flow regime with time, which was due to the combined effects of the free and forced convection in addition to the complex nonuniformity of the flow field. The Peclet number was a function of temperature, pressure, gas recovery, and characteristic velocity, as well as the split of the gas between the parallel streams in the model.

  13. Program for large-scale underground-coal-gasification tests

    SciTech Connect (OSTI)

    Hammesfahr, F.W.; Winter, P.L.

    1982-11-01T23:59:59.000Z

    The continuing development of underground coal gasification technology requires extended multi-module field programs in which the output gas is linked to surface usage. This effort was to appraise whether existing surface facilities in the utility, petroleum refinery, or natural gas industries could be used to reduce the cost of such an extended multi-module test and whether regional demand in areas having underground coal gasification coal resources could support the manufacture of transportation fuels from underground coal gasification gases. To limit the effort to a reasonable level but yet to permit a fair test of the concept, effort was focused on five states, Illinois, New Mexico, Texas, Washington, and Wyoming, which have good underground coal gasification reserves. Studies of plant distribution located 25 potential sites within 3 miles of the underground coal gasification amenable reserves in the five states. Distribution was 44% to utilities, 44% to refineries, and 12% to gas processing facilities. The concept that existing surface facilities, currently or potentially gas-capable, might contribute to the development of underground coal gasification technology by providing a low cost industrial application for the gas produced in a multi-module test appears valid. To further test the concept, three industries were reviewed in depth. These were the electric utility, natural gas, and petroleum industries. When looking at a fuel substitution of the type proposed, each industry had its special perspective. These are discussed in detail in the report.

  14. Subtask 4.2 - Coal Gasification Short Course

    SciTech Connect (OSTI)

    Kevin Galbreath

    2009-06-30T23:59:59.000Z

    Major utilities, independent power producers, and petroleum and chemical companies are intent on developing a fleet of gasification plants primarily because of high natural gas prices and the implementation of state carbon standards, with federal standards looming. Currently, many projects are being proposed to utilize gasification technologies to produce a synthesis gas or fuel gas stream for the production of hydrogen, liquid fuels, chemicals, and electricity. Financing these projects is challenging because of the complexity, diverse nature of gasification technologies, and the risk associated with certain applications of the technology. The Energy & Environmental Research Center has developed a gasification short course that is designed to provide technical personnel with a broad understanding of gasification technologies and issues, thus mitigating the real or perceived risk associated with the technology. Based on a review of research literature, tutorial presentations, and Web sites on gasification, a short course presentation was prepared. The presentation, consisting of about 500 PowerPoint slides, provides at least 7 hours of instruction tailored to an audience's interests and needs. The initial short course is scheduled to be presented September 9 and 10, 2009, in Grand Forks, North Dakota.

  15. Modeling of contaminant transport in underground coal gasification

    SciTech Connect (OSTI)

    Lanhe Yang; Xing Zhang [China University of Mining and Technology, Xuzhou (China). College of Resources and Geosciences

    2009-01-15T23:59:59.000Z

    In order to study and discuss the impact of contaminants produced from underground coal gasification on groundwater, a coupled seepage-thermodynamics-transport model for underground gasification was developed on the basis of mass and energy conservation and pollutant-transport mechanisms, the mathematical model was solved by the upstream weighted multisell balance method, and the model was calibrated and verified against the experimental site data. The experiment showed that because of the effects of temperature on the surrounding rock of the gasification panel the measured pore-water-pressure was higher than the simulated one; except for in the high temperature zone where the simulation errors of temperature, pore water pressure, and contaminant concentration were relatively high, the simulation values of the overall gasification panel were well fitted with the measured values. As the gasification experiment progressed, the influence range of temperature field expanded, the gradient of groundwater pressure decreased, and the migration velocity of pollutant increased. Eleven months and twenty months after the test, the differences between maximum and minimum water pressure were 2.4 and 1.8 MPa, respectively, and the migration velocities of contaminants were 0.24-0.38 m/d and 0.27-0.46 m/d, respectively. It was concluded that the numerical simulation of the transport process for pollutants from underground coal gasification was valid. 42 refs., 13 figs., 1 tab.

  16. Solar coal gasification reactor with pyrolysis gas recycle

    DOE Patents [OSTI]

    Aiman, William R. (Livermore, CA); Gregg, David W. (Morago, CA)

    1983-01-01T23:59:59.000Z

    Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas (14) is withdrawn from a region of the reactor between the gasification zone (32) and the pyrolysis zone (34). The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

  17. Low-temperature catalytic gasification of wet industrial wastes

    SciTech Connect (OSTI)

    Elliott, D C; Neuenschwander, G G; Baker, E G; Sealock, Jr, L J; Butner, R S

    1991-04-01T23:59:59.000Z

    Bench-scale reactor tests are in progress at Pacific Northwest Laboratory to develop a low-temperature, catalytic gasification system. The system, licensed under the trade name Thermochemical Environmental Energy System (TEES{reg sign}), is designed for treating a wide variety of feedstocks ranging from dilute organics in water to waste sludges from food processing. This report describes a test program which used a continuous-feed tubular reactor. This test program is an intermediate stage in the process development. The reactor is a laboratory-scale version of the commercial concept as currently envisioned by the process developers. An energy benefit and economic analysis was also completed on the process. Four conceptual commercial installations of the TEES process were evaluated for three food processing applications and one organic chemical manufacturing application. Net energy production (medium-Btu gas) was achieved in all four cases. The organic chemical application was found to be economically attractive in the present situation. Based on sensitivity studies included in the analysis, the three food processing cases will likely become attractive in the near future as waste disposal regulations tighten and disposal costs increase. 21 refs., 2 figs., 9 tabs.

  18. DEMONSTRATION OF BLACK LIQUOR GASIFICATION AT BIG ISLAND

    SciTech Connect (OSTI)

    Robert DeCarrera

    2003-10-20T23:59:59.000Z

    This Technical Progress Report provides an account of the status of the project for the demonstration of Black Liquor Gasification at Georgia-Pacific Corporation's Big Island, VA facility. The report also includes budget information and a milestone schedule. The project to be conducted by G-P is a comprehensive, complete commercial-scale demonstration that is divided into two phases. Phase I is the validation of the project scope and cost estimate. Phase II is project execution, data acquisition and reporting, and consists of procurement of major equipment, construction and start-up of the new system. Phase II also includes operation of the system for a period of time to demonstrate the safe operation and full integration of the energy and chemical recovery systems in a commercial environment. The objective of Phase I is to validate the process design and to engineer viable solutions to any technology gaps. This phase includes engineering and planning for the integration of the full-scale MTCI/StoneChem PulseEnhanced{trademark} black liquor steam-reformer chemical recovery system into G-P's operating pulp and paper mill at Big Island, Virginia. During this phase, the scope and cost estimate will be finalized to confirm the cost of the project and its integration into the existing system at the mill. The objective of Phase II of the project is the successful and safe completion of the engineering, construction and functional operation of the fully integrated full-scale steam reformer process system. This phase includes installation of all associated support systems and equipment required for the enhanced recovery of both energy and chemicals from all of the black liquor generated from the pulping process at the Big Island Mill. The objective also includes operation of the steam reformer system to demonstrate the ability of the system to operate reliably and achieve designed levels of energy and chemical recovery while maintaining environmental emissions at or below the limits set by the environmental permits.

  19. Assessment of advanced coal-gasification processes. [AVCO high throughput gasification in process; Bell High Mass Flux process; CS-R process; and Exxon Gasification process

    SciTech Connect (OSTI)

    McCarthy, J.; Ferrall, J.; Charng, T.; Houseman, J.

    1981-06-01T23:59:59.000Z

    This report represents a technical assessment of the following advanced coal gasification processes: AVCO High Throughput Gasification (HTG) Process, Bell Single - Stage High Mass Flux (HMF) Process, Cities Service/Rockwell (CS/R) Hydrogasification Process, and the Exxon Catalytic Coal Gasification (CCG) Process. Each process is evaluated for its potential to produce SNG from a bituminous coal. In addition to identifying the new technology these processes represent, key similarities/differences, strengths/weaknesses, and potential improvements to each process are identified. The AVCO HTG and the Bell HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging and syngas as the initial raw product gas. The CS/R Hydrogasifier is also SRT but is non-slagging and produces a raw gas high in methane content. The Exxon CCG gasifier is a long residence time, catalytic fluidbed reactor producing all of the raw product methane in the gasifier.

  20. INTEGRATED GASIFICATION COMBINED CYCLE PROJECT 2 MW FUEL CELL DEMONSTRATION

    SciTech Connect (OSTI)

    FuelCell Energy

    2005-05-16T23:59:59.000Z

    With about 50% of power generation in the United States derived from coal and projections indicating that coal will continue to be the primary fuel for power generation in the next two decades, the Department of Energy (DOE) Clean Coal Technology Demonstration Program (CCTDP) has been conducted since 1985 to develop innovative, environmentally friendly processes for the world energy market place. The 2 MW Fuel Cell Demonstration was part of the Kentucky Pioneer Energy (KPE) Integrated Gasification Combined Cycle (IGCC) project selected by DOE under Round Five of the Clean Coal Technology Demonstration Program. The participant in the CCTDP V Project was Kentucky Pioneer Energy for the IGCC plant. FuelCell Energy, Inc. (FCE), under subcontract to KPE, was responsible for the design, construction and operation of the 2 MW fuel cell power plant. Duke Fluor Daniel provided engineering design and procurement support for the balance-of-plant skids. Colt Engineering Corporation provided engineering design, fabrication and procurement of the syngas processing skids. Jacobs Applied Technology provided the fabrication of the fuel cell module vessels. Wabash River Energy Ltd (WREL) provided the test site. The 2 MW fuel cell power plant utilizes FuelCell Energy's Direct Fuel Cell (DFC) technology, which is based on the internally reforming carbonate fuel cell. This plant is capable of operating on coal-derived syngas as well as natural gas. Prior testing (1992) of a subscale 20 kW carbonate fuel cell stack at the Louisiana Gasification Technology Inc. (LGTI) site using the Dow/Destec gasification plant indicated that operation on coal derived gas provided normal performance and stable operation. Duke Fluor Daniel and FuelCell Energy developed a commercial plant design for the 2 MW fuel cell. The plant was designed to be modular, factory assembled and truck shippable to the site. Five balance-of-plant skids incorporating fuel processing, anode gas oxidation, heat recovery, water treatment/instrument air, and power conditioning/controls were built and shipped to the site. The two fuel cell modules, each rated at 1 MW on natural gas, were fabricated by FuelCell Energy in its Torrington, CT manufacturing facility. The fuel cell modules were conditioned and tested at FuelCell Energy in Danbury and shipped to the site. Installation of the power plant and connection to all required utilities and syngas was completed. Pre-operation checkout of the entire power plant was conducted and the plant was ready to operate in July 2004. However, fuel gas (natural gas or syngas) was not available at the WREL site due to technical difficulties with the gasifier and other issues. The fuel cell power plant was therefore not operated, and subsequently removed by October of 2005. The WREL fuel cell site was restored to the satisfaction of WREL. FuelCell Energy continues to market carbonate fuel cells for natural gas and digester gas applications. A fuel cell/turbine hybrid is being developed and tested that provides higher efficiency with potential to reach the DOE goal of 60% HHV on coal gas. A system study was conducted for a 40 MW direct fuel cell/turbine hybrid (DFC/T) with potential for future coal gas applications. In addition, FCE is developing Solid Oxide Fuel Cell (SOFC) power plants with Versa Power Systems (VPS) as part of the Solid State Energy Conversion Alliance (SECA) program and has an on-going program for co-production of hydrogen. Future development in these technologies can lead to future coal gas fuel cell applications.

  1. Effect of pulsation on black liquor gasification. Final report

    SciTech Connect (OSTI)

    Zinn, B.T.; Jagoda, J.; Jeong, H.; Kushari, A.; Rosen, L.J.

    1998-12-01T23:59:59.000Z

    Pyrolysis is an endothermic process. The heat of reaction is provided either by partial combustion of the waste or by heat transfer from an external combustion process. In one proposed system black liquor is pyrolized in a fluidized bed to which heat is added through a series of pulse combustor tail pipes submerged in the bed material. This system appears promising because of the relatively high heat transfer in pulse combustors and in fluidized beds. Other advantages of pulse combustors are discussed elsewhere. The process is, however, only economically viable if a part of the pyrolysis products can be used to fire the pulse combustors. The overall goals of this study were to determine: (1) which is the limiting heat transfer rate in the process of transferring heat from the hot combustion products to the pipe, through the pipe, from the tail pipe to the bed and through the bed; i.e., whether increased heat transfer within the pulse combustor will significantly increase the overall heat transfer rate; (2) whether the heat transfer benefits of the pulse combustor can be utilized while maintaining the temperature in the bed within the narrow temperature range required by the process without generating hot spots in the bed; and (3) whether the fuel gas produced during the gasification process can be used to efficiently fire the pulse combustor.

  2. Instrumentation and process control development for in situ coal gasification. Seventeenth, eighteenth, and nineteenth quarterly reports, December 1978 through August 1979

    SciTech Connect (OSTI)

    Glass, R.E. (ed.)

    1980-02-01T23:59:59.000Z

    The second phase of the Hanna IV In Situ Coal Gasification Test, Hanna IV-B, was initiated on April 20, 1979. The reverse combustion linking process was completed July 13, 1979, and gasification began July 28, 1979. Sandia Laboratories is providing support by fielding and monitoring diagnostic and remote monitoring instrumentation techniques. All techniques are supported by a minicomputer-based, field data acquisition system developed for this application which provides on-site, real-time reduction, analysis and display of the experimental data. Results to date show the development of at least three links, and the progress of the gasification front is being monitored. There have also been developments in hardware for use in the planned Hoe Creek III experiment, notably an inverted thermocouple string with a lateral transmission device. To support all field activities an in-house computing system with complete data base storage capability has been assembled.

  3. Techniques and equipment used in contaminant detection at Hoe Creek underground coal gasification experimental site

    SciTech Connect (OSTI)

    Davidson, S.C.

    1984-01-01T23:59:59.000Z

    Data obtained from existing monitoring wells at an experimental coal gasification site indicated that local groundwater supplies were under risk from organic contaminants, particularly phenols. A more extensive monitoring system was installed. A drilling and open-hole sampling programme was devised to locate the edge of the contaminated area and indicate where additional monitoring wells were required. Geophysical logging was employed to determine the optimal position of gas-driven groundwater samplers/piezometers. The system successfully delineated the extent of the contaminant plume on 3 sides, but further work is required on the fourth side.

  4. Influence of pressure on coal pyrolysis and char gasification

    SciTech Connect (OSTI)

    Haiping Yang; Hanping Chen; Fudong Ju; Rong Yan; Shihong Zhang [Huazhong University of Science and Technology, Wuhan (China). State Key Laboratory of Coal Combustion

    2007-12-15T23:59:59.000Z

    Coal char structure varied greatly with pyrolysis pressure, which has a significant influence on the gasification reactivity. In this study, the influence of pressure on the behavior of coal pyrolysis and physicochemical structure and gasification characteristics of the resultant coal char was investigated using a pressurized thermogravimetric analyzer combined with an ambient thermogravimetric analyzer. First, the pyrolysis of Shenfu (SF) bituminous coal was performed in a pressurized thermogravimetric analyzer (TGA) at different pressures (0.1, 0.8, 1.5, 3, and 5 MPa). The volatile mainly evolved out at 400-800{sup o}C. The gas products are mainly CO{sub 2}, CO, CH{sub 4}, and light aliphatics with some water. It was observed that the pyrolysis of coal was shifted to lower temperature (50{sup o}C) with pressure increasing from ambient to 5 MPa, and the devolatilization rate of coal pyrolysis was decreased and the coal char yield was increased slightly. The structure of solid coal char was analyzed using FTIR, ASAP2020, and CNHS. In the solid char, the main organic functional groups are mainly CO, C-C (alkane), C-H ar, C-O-C, and C=C ar. The carbon content was increased while H content decreased. Finally, the gasification of the solid char was preformed at ambient pressure with CO{sub 2} as gasify agent. The gasification process of coal char can be divided into postpyrolysis and char gasification. Higher pressure accelerated the initial stage of char gasification, and higher gasification reactivity was observed for char derived at 5 MPa. 23 refs., 8 figs., 5 tabs.

  5. The Development of a Hydrothermal Method for Slurry Feedstock Preparation for Gasification Technology

    E-Print Network [OSTI]

    He, Wei

    2011-01-01T23:59:59.000Z

    M.J. Keyser, and M. Coertzen, Syngas production from SouthExperimental study on syngas production by co- gasificationTropsch synthesis of the syngas produced in gasification or

  6. The Development of a Hydrothermal Method for Slurry Feedstock Preparation for Gasification Technology

    E-Print Network [OSTI]

    He, Wei

    2011-01-01T23:59:59.000Z

    feedstocks at a dual fluidised bed gasifier: Impacts ofThe ash chemistry in fluidised bed gasification of biomass

  7. Fixed Bed Counter Current Gasification of Mesquite and Juniper Biomass Using Air-steam as Oxidizer

    E-Print Network [OSTI]

    Chen, Wei 1981-

    2012-11-27T23:59:59.000Z

    contains high percentage of Nitrogen, the heating value of the gasification gas is very low. The oxygen-blow gasification produce a syngas with medium heating value and steam blow gasification lead to the production of a syngas with an acceptable HHV... schematic flow diagram of an integrated Gasification Combined Cycle (IGCC) plan. Coal, heavy petroleum residues, or biomass is gasified in the gasifier using air or steam media to generate syngas under high temperature and pressure. The syngas was first...

  8. Two-stage coal gasification and desulfurization apparatus

    DOE Patents [OSTI]

    Bissett, Larry A. (Morgantown, WV); Strickland, Larry D. (Morgantown, WV)

    1991-01-01T23:59:59.000Z

    The present invention is directed to a system which effectively integrates a two-stage, fixed-bed coal gasification arrangement with hot fuel gas desulfurization of a first stream of fuel gas from a lower stage of the two-stage gasifier and the removal of sulfur from the sulfur sorbent regeneration gas utilized in the fuel-gas desulfurization process by burning a second stream of fuel gas from the upper stage of the gasifier in a combustion device in the presence of calcium-containing material. The second stream of fuel gas is taken from above the fixed bed in the coal gasifier and is laden with ammonia, tar and sulfur values. This second stream of fuel gas is burned in the presence of excess air to provide heat energy sufficient to effect a calcium-sulfur compound forming reaction between the calcium-containing material and sulfur values carried by the regeneration gas and the second stream of fuel gas. Any ammonia values present in the fuel gas are decomposed during the combustion of the fuel gas in the combustion chamber. The substantially sulfur-free products of combustion may then be combined with the desulfurized fuel gas for providing a combustible fluid utilized for driving a prime mover.

  9. Analysis of mathematical models of underground coal gasification

    SciTech Connect (OSTI)

    Fausett, L.V.

    1984-01-01T23:59:59.000Z

    Results are reported of a survey and comparison of forward combustion underground coal gasification (UCG) models that are available in the public domain. The six models obtained for study were mathematically analyzed to determine their conceptual completeness and computational complexity. The computer code for each model was implemented on the University of Wyoming CDC CYBER 730/760 computer system. Computed analyses were made with each of the programs using data to simulate six representative UCG field tests. Four of the field tests were air injection experiments and two were oxygen/steam. Modifications were necessary to two models in order for them to simulate oxygen/steam injection experiments. A mistake in the computer code for one model was discovered and corrected; this enabled the code to execute with data from one field test for which the original version had failed. An alternate numerical solution technique for one mdoel was studied, and improved correlations for the model were developed. An approximate analytical solution to the model was obtained that is valid over the region where difficulties were encountered, using both multiple shooting and collocation numerical solutions. The applicability of each model to the various conditions occurring in the different field tests was determined.

  10. Fate of trace elements in UK coals during gasification processes

    SciTech Connect (OSTI)

    Bushell, A.J.; Williamson, J. [Imperial College of Science, Technology and Medicine, London (United Kingdom)

    1996-12-31T23:59:59.000Z

    Five UK coals were selected to cover the range of mineral matter and ash contents typically encountered in UK bituminous coals. Trace element analysis was performed on both the whole coals and size separated fractions using ICP analysis for 21 trace elements, including Be, Cr, Co, Ni, As, Cd, Sb, Hg, and Pb, elements deemed to be the most environmentally hazardous. Small quantities of each coal were gasified in a laboratory gasifier in an atmosphere of N{sub 2} containing 15% O{sub 2}. Samples of bed ash, cyclone ash, and a fine gas-filtered ash were collected and analyzed to determine the partition of the trace elements between the gasification products. Mass balance calculations showed that the recovery of the trace elements varied from 20 to 97%; the low recovery of some trace elements highlighting the difficulties of collecting representative samples from a laboratory system. A parallel study on samples taken from a pilot plant gasifier showed significantly higher recovery rates, indicating the value of larger scale trials.

  11. Formation of CO precursors during char gasification with O2, CO2 and H2O

    E-Print Network [OSTI]

    Truong, Thanh N.

    Formation of CO precursors during char gasification with O2, CO2 and H2O Alejandro Montoya a are presented to get insight into an unified mechanism of uncatalyzed carbon gasification. D 2002 Elsevier Science B.V. All rights reserved. Keywords: Gasification; Chemisorption; Molecular simulation; Surface

  12. Biomass Gasification using Solar Thermal Energy M. Munzinger and K. Lovegrove

    E-Print Network [OSTI]

    Biomass Gasification using Solar Thermal Energy M. Munzinger and K. Lovegrove Solar Thermal Group technical pathways for biomass gasification and shows their advantages and disadvantages especially in connection with the use of solar heat as energy source for the conversion reaction. Biomass gasification

  13. LLNL Capabilities in Underground Coal Gasification

    SciTech Connect (OSTI)

    Friedmann, S J; Burton, E; Upadhye, R

    2006-06-07T23:59:59.000Z

    Underground coal gasification (UCG) has received renewed interest as a potential technology for producing hydrogen at a competitive price particularly in Europe and China. The Lawrence Livermore National Laboratory (LLNL) played a leading role in this field and continues to do so. It conducted UCG field tests in the nineteen-seventies and -eighties resulting in a number of publications culminating in a UCG model published in 1989. LLNL successfully employed the ''Controlled Retraction Injection Point'' (CRIP) method in some of the Rocky Mountain field tests near Hanna, Wyoming. This method, shown schematically in Fig.1, uses a horizontally-drilled lined injection well where the lining can be penetrated at different locations for injection of the O{sub 2}/steam mixture. The cavity in the coal seam therefore gets longer as the injection point is retracted as well as wider due to reaction of the coal wall with the hot gases. Rubble generated from the collapsing wall is an important mechanism studied by Britten and Thorsness.

  14. Gasification Characteristics of Coal/Biomass Mixed Fuels

    SciTech Connect (OSTI)

    Mitchell, Reginald

    2013-09-30T23:59:59.000Z

    A research project was undertaken that had the overall objective of developing the models needed to accurately predict conversion rates of coal/biomass mixtures to synthesis gas under conditions relevant to a commercially-available coal gasification system configured to co- produce electric power as well as chemicals and liquid fuels. In our efforts to accomplish this goal, experiments were performed in an entrained flow reactor in order to produce coal and biomass chars at high heating rates and temperatures, typical of the heating rates and temperatures fuel particles experience in real systems. Mixed chars derived from coal/biomass mixtures containing up to 50% biomass and the chars of the pure coal and biomass components were subjected to a matrix of reactivity tests in a pressurized thermogravimetric analyzer (TGA) in order to obtain data on mass loss rates as functions of gas temperature, pressure and composition as well as to obtain information on the variations in mass specific surface area during char conversion under kinetically-limited conditions. The experimental data were used as targets when determining the unknown parameters in the chemical reactivity and specific surface area models developed. These parameters included rate coefficients for the reactions in the reaction mechanism, enthalpies of formation and absolute entropies of adsorbed species formed on the carbonaceous surfaces, and pore structure coefficients in the model used to describe how the mass specific surface area of the char varies with conversion. So that the reactivity models can be used at high temperatures when mass transport processes impact char conversion rates, Thiele modulus – effectiveness factor relations were also derived for the reaction mechanisms developed. In addition, the reactivity model and a mode of conversion model were combined in a char-particle gasification model that includes the effects of chemical reaction and diffusion of reactive gases through particle pores and energy exchange between the particle and its environment. This char-particle gasification model is capable of predicting the average mass loss rates, sizes, apparent densities, specific surface areas, and temperatures of the char particles produced when co-firing coal and biomass to the type environments established in entrained flow gasifiers operating at high temperatures and elevated pressures. A key result of this work is the finding that the reactivities of the mixed chars were not always in between the reactivities of the pure component chars at comparable gasification conditions. Mixed char reactivity to CO{sub 2} was lower than the reactivities of both the pure Wyodak coal and pure corn stover chars to CO{sub 2}. In contrast, mixed char reactivity to H{sub 2}O was higher than the reactivities of both the pure Wyodak coal and pure corn stover chars to H{sub 2}O. This was found to be in part, a consequence of the reduced mass specific surface areas of the coal char particles formed during devolatilization when the coal and biomass particles are co-fired. The biomass particles devolatilize prior to the coal particles, impacting the temperature and the composition of the environment in which the coal particles devolatilize. This situation results in coal char particles within the mixed char that differ in specific surface area and reactivity from the coal char particles produced in the absence of the devolatilizing biomass particles. Due to presence of this “affected” coal char, it was not possible to develop a mixed char reactivity model that uses linear mixing rules to determine the reactivity of a mixed char from only the reactivities of the pure mixture components. However, it was possible to predict both mixed char specific surface area and reactivity for a wide range of fuel mixture rat os provided the specific surface area and reactivity of the affected coal char particles are known. Using the kinetic parameters determined for the Wyodak coal and corn stover chars, the model was found to adequately predict the observed conversion times a

  15. Multiphysics modeling of carbon gasification processes in a well-stirred reactor with detailed gas-phase chemistry

    E-Print Network [OSTI]

    Qiao, Li

    : Coal gasification Carbon gasification Detailed chemistry Heterogeneous surface reactions Radiation Multi-physics numerical modeling a b s t r a c t Fuel synthesis through coal and biomass gasification Fuel synthesis through coal gasification offers a potential solu- tion to the problem of increasing

  16. Underground coal gasification: A near-term alternate fuel

    SciTech Connect (OSTI)

    Avasthi, J.; Singleton, A.M.

    1984-06-01T23:59:59.000Z

    Since the beginning of this century underground coal gasification has been considered as an alternative to mining as a means of utilizing the coal resources not recoverable by conventional methods. The energy crunch of the seventies gave a new impetus to it, and several tests were conducted in the U.S. to demonstrate the feasibility of this method in both horizontal and steeply dipping coal resources. Gulf Research and Development Company has conducted two successful underground coal gasification tests near Rawlins, Wyoming, in steeply dipping coal beds. The results of these tests indicate that the present state of the art is advanced enough for utilization of this technique for commercial purposes. A right combination of resource, consumer, and economic factors will dictate future commercialization of underground coal gasification for the U.S. coal resources.

  17. Separating hydrogen from coal gasification gases with alumina membranes

    SciTech Connect (OSTI)

    Egan, B.Z. (Oak Ridge National Lab., TN (USA)); Fain, D.E.; Roettger, G.E.; White, D.E. (Oak Ridge K-25 Site, TN (USA))

    1991-01-01T23:59:59.000Z

    Synthesis gas produced in coal gasification processes contains hydrogen, along with carbon monoxide, carbon dioxide, hydrogen sulfide, water, nitrogen, and other gases, depending on the particular gasification process. Development of membrane technology to separate the hydrogen from the raw gas at the high operating temperatures and pressures near exit gas conditions would improve the efficiency of the process. Tubular porous alumina membranes with mean pore radii ranging from about 9 to 22 {Angstrom} have been fabricated and characterized. Based on hydrostatic tests, the burst strength of the membranes ranged from 800 to 1600 psig, with a mean value of about 1300 psig. These membranes were evaluated for separating hydrogen and other gases. Tests of membrane permeabilities were made with helium, nitrogen, and carbon dioxide. Measurements were made at room temperature in the pressure range of 15 to 589 psi. Selected membranes were tested further with mixed gases simulating a coal gasification product gas. 5 refs., 7 figs.

  18. Thermophysical models of underground coal gasification and FEM analysis

    SciTech Connect (OSTI)

    Yang, L.H. [China University of Mining & Technology, Xuzhou (China)

    2007-11-15T23:59:59.000Z

    In this study, mathematical models of the coupled thermohydromechanical process of coal rock mass in an underground coal gasification panel are established. Combined with the calculation example, the influence of heating effects on the observed values and simulated values for pore water pressure, stress, and displacement in the gasification panel are fully discussed and analyzed. Calculation results indicate that 38, 62, and 96 days after the experiment, the average relative errors for the calculated values and measured values for the temperature and water pressure were between 8.51-11.14% and 3-10%, respectively; with the passage of gasification time, the calculated errors for the vertical stress and horizontal stress gradually declined, but the simulated errors for the horizontal and vertical displacements both showed a rising trend. On the basis of the research results, the calculated values and the measured values agree with each other very well.

  19. A sweep efficiency model for underground coal gasification

    SciTech Connect (OSTI)

    Chang, H.L.; Edgar, T.F.; Himmelblau, D.M.

    1985-01-01T23:59:59.000Z

    A new model to predict sweep efficiency for underground coal gasification (UCG) has been developed. The model is based on flow through rubble in the cavity as well as through the open channel and uses a tanks-in-series model for the flow characteristics. The model can predict cavity growth and product gas composition given the rate of water influx, roof collapse, and spalling. Self-gasification of coal is taken into account in the model, and the coal consumption rate and the location of the flame front are determined by material and energy balances at the char surface. The model has been used to predict the results of the Hoe Creek III field tests (for the air gasification period). Predictions made by the model such as cavity shape, product gas composition, temperature profile, and overall reaction stoichiometry between the injected oxygen and the coal show reasonable agreement with the field test results.

  20. Advances in the development of wire mesh reactor for coal gasification studies - article no. 084102

    SciTech Connect (OSTI)

    Zeng, C.; Chen, L.; Liu, G.; Li, W.H.; Huang, B.M.; Zhu, H.D.; Zhang, B.; Zamansky, V. [GE Global Research Shanghai, Shanghai (China)

    2008-08-15T23:59:59.000Z

    In an effort to further understand the coal gasification behavior in entrained-flow gasifiers, a high pressure and high temperature wire mesh reactor with new features was recently built. An advanced LABVIEW-based temperature measurement and control system were adapted. Molybdenum wire mesh with aperture smaller than 70 {mu} m and type D thermocouple were used to enable high carbon conversion ({gt}90%) at temperatures {gt}1000 {sup o}C. Gaseous species from wire mesh reactor were quantified using a high sensitivity gas chromatography. The material balance of coal pyrolysis in wire mesh reactor was demonstrated for the first time by improving the volatile's quantification techniques.

  1. Biomass gasification project gets funding to solve black liquor safety and landfill problems

    SciTech Connect (OSTI)

    Black, N.P.

    1991-02-01T23:59:59.000Z

    This paper reports on biomass gasifications. The main by-product in pulp making is black liquor from virgin fiber; the main by-product in paper recycling is fiber residue. Although the black liquor is recycled for chemical and energy recovery, safety problems plague the boilers currently used to do this. The fiber residue is usually transported to a landfill. The system being developed by MTCI will convert black liquor and fiber residue into a combustible gas, which can then be used for a wide variety of thermal or power generation applications.

  2. Characterization of cellulosic wastes and gasification products from chicken farms

    SciTech Connect (OSTI)

    Joseph, Paul, E-mail: p.joseph@ulster.ac.uk [School of the Built Environment and the Built Environment Research Institute, University of Ulster, Newtownabbey BT37 0QB, County Antrim, Northern Ireland (United Kingdom); Tretsiakova-McNally, Svetlana; McKenna, Siobhan [School of the Built Environment and the Built Environment Research Institute, University of Ulster, Newtownabbey BT37 0QB, County Antrim, Northern Ireland (United Kingdom)

    2012-04-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer The gas chromatography indicated the variable quality of the producer gas. Black-Right-Pointing-Pointer The char had appreciable NPK values, and can be used as a fertiliser. Black-Right-Pointing-Pointer The bio-oil produced was of poor quality, having high moisture content and low pH. Black-Right-Pointing-Pointer Mass and energy balances showed inadequate level energy recovery from the process. Black-Right-Pointing-Pointer Future work includes changing the operating parameters of the gasification unit. - Abstract: The current article focuses on gasification as a primary disposal solution for cellulosic wastes derived from chicken farms, and the possibility to recover energy from this process. Wood shavings and chicken litter were characterized with a view to establishing their thermal parameters, compositional natures and calorific values. The main products obtained from the gasification of chicken litter, namely, producer gas, bio-oil and char, were also analysed in order to establish their potential as energy sources. The experimental protocol included bomb calorimetry, pyrolysis combustion flow calorimetry (PCFC), thermo-gravimetric analyses (TGA), differential scanning calorimetry (DSC), Fourier transform infrared (FT-IR) spectroscopy, Raman spectroscopy, elemental analyses, X-ray diffraction (XRD), mineral content analyses and gas chromatography. The mass and energy balances of the gasification unit were also estimated. The results obtained confirmed that gasification is a viable method of chicken litter disposal. In addition to this, it is also possible to recover some energy from the process. However, energy content in the gas-phase was relatively low. This might be due to the low energy efficiency (19.6%) of the gasification unit, which could be improved by changing the operation parameters.

  3. High-pressure gasification of Montana subbituminous coal

    SciTech Connect (OSTI)

    Goyal, A.; Bryan, B.; Rehmat, A.

    1991-01-01T23:59:59.000Z

    A data base for the fluidized-bed gasification of different coals at elevated pressures has been developed at the Institute of Gas Technology (IGT) with different ranks of coal at pressures up to 450 psig and at temperatures dictated by the individual coals. Adequate data have been obtained to characterize the effect of pressure on the gasification of Montana Rosebud subbituminous coal and North Dakota lignite. The results obtained with Montana Rosebud subbituminous coal are presented here. This program was funded by the Gas Research Institute. 9 refs., 10 figs., 3 tabs.

  4. Hydrogen Production Cost Estimate Using Biomass Gasification: Independent Review

    SciTech Connect (OSTI)

    Ruth, M.

    2011-10-01T23:59:59.000Z

    This independent review is the conclusion arrived at from data collection, document reviews, interviews and deliberation from December 2010 through April 2011 and the technical potential of Hydrogen Production Cost Estimate Using Biomass Gasification. The Panel reviewed the current H2A case (Version 2.12, Case 01D) for hydrogen production via biomass gasification and identified four principal components of hydrogen levelized cost: CapEx; feedstock costs; project financing structure; efficiency/hydrogen yield. The panel reexamined the assumptions around these components and arrived at new estimates and approaches that better reflect the current technology and business environments.

  5. Pyrolysis and gasification of meat-and-bone-meal: Energy balance and GHG accounting

    SciTech Connect (OSTI)

    Cascarosa, Esther [Thermochemical Processes Group, Aragón Institute for Engineering Research (I3A), Universidad de Zaragoza (Spain); Boldrin, Alessio, E-mail: aleb@env.dtu.dk [Department of Environmental Engineering. Technical University of Denmark, Kongens Lyngby (Denmark); Astrup, Thomas [Department of Environmental Engineering. Technical University of Denmark, Kongens Lyngby (Denmark)

    2013-11-15T23:59:59.000Z

    Highlights: • GHG savings are in the order of 600–1000 kg CO{sub 2}-eq. per Mg of MBM treated. • Energy recovery differed in terms of energy products and efficiencies. • The results were largely determined by use of the products for energy purposes. - Abstract: Meat-and-bone-meal (MBM) produced from animal waste has become an increasingly important residual fraction needing management. As biodegradable waste is routed away from landfills, thermo-chemical treatments of MBM are considered promising solution for the future. Pyrolysis and gasification of MBM were assessed based on data from three experimental lab and pilot-scale plants. Energy balances were established for the three technologies, providing different outcomes for energy recovery: bio-oil was the main product for the pyrolysis system, while syngas and a solid fraction of biochar were the main products in the gasification system. These products can be used – eventually after upgrading – for energy production, thereby offsetting energy production elsewhere in the system. Greenhouse gases (GHG) accounting of the technologies showed that all three options provided overall GHG savings in the order of 600–1000 kg CO{sub 2}-eq. per Mg of MBM treated, mainly as a consequence of avoided fossil fuel consumption in the energy sector. Local conditions influencing the environmental performance of the three systems were identified, together with critical factors to be considered during decision-making regarding MBM management.

  6. Mass transfer effects in a gasification riser

    SciTech Connect (OSTI)

    Breault, Ronald W [U.S. DOE; Li, Tingwen [URS; Nicoletti, Phillip [URS

    2013-01-01T23:59:59.000Z

    In the development of multiphase reacting computational fluid dynamics (CFD) codes, a number of simplifications were incorporated into the codes and models. One of these simplifications was the use of a simplistic mass transfer correlation for the faster reactions and omission of mass transfer effects completely on the moderate speed and slow speed reactions such as those in a fluidized bed gasifier. Another problem that has propagated is that the mass transfer correlation used in the codes is not universal and is being used far from its developed bubbling fluidized bed regime when applied to circulating fluidized bed (CFB) riser reactors. These problems are true for the major CFD codes. To alleviate this problem, a mechanistic based mass transfer coefficient algorithm has been developed based upon an earlier work by Breault et al. This fundamental approach uses the local hydrodynamics to predict a local, time varying mass transfer coefficient. The predicted mass transfer coefficients and the corresponding Sherwood numbers agree well with literature data and are typically about an order of magnitude lower than the correlation noted above. The incorporation of the new mass transfer model gives the expected behavior for all the gasification reactions evaluated in the paper. At the expected and typical design values for the solid flow rate in a CFB riser gasifier an ANOVA analysis has shown the predictions from the new code to be significantly different from the original code predictions. The new algorithm should be used such that the conversions are not over predicted. Additionally, its behaviors with changes in solid flow rate are consistent with the changes in the hydrodynamics.

  7. GASIFICATION PLANT COST AND PERFORMANCE OPTIMIZATION

    SciTech Connect (OSTI)

    Sheldon Kramer

    2003-09-01T23:59:59.000Z

    This project developed optimized designs and cost estimates for several coal and petroleum coke IGCC coproduction projects that produced hydrogen, industrial grade steam, and hydrocarbon liquid fuel precursors in addition to power. The as-built design and actual operating data from the DOE sponsored Wabash River Coal Gasification Repowering Project was the starting point for this study that was performed by Bechtel, Global Energy and Nexant under Department of Energy contract DE-AC26-99FT40342. First, the team developed a design for a grass-roots plant equivalent to the Wabash River Coal Gasification Repowering Project to provide a starting point and a detailed mid-year 2000 cost estimate based on the actual as-built plant design and subsequent modifications (Subtask 1.1). This non-optimized plant has a thermal efficiency to power of 38.3% (HHV) and a mid-year 2000 EPC cost of 1,681 $/kW.1 This design was enlarged and modified to become a Petroleum Coke IGCC Coproduction Plant (Subtask 1.2) that produces hydrogen, industrial grade steam, and fuel gas for an adjacent Gulf Coast petroleum refinery in addition to export power. A structured Value Improving Practices (VIP) approach was applied to reduce costs and improve performance. The base case (Subtask 1.3) Optimized Petroleum Coke IGCC Coproduction Plant increased the power output by 16% and reduced the plant cost by 23%. The study looked at several options for gasifier sparing to enhance availability. Subtask 1.9 produced a detailed report on this availability analyses study. The Subtask 1.3 Next Plant, which retains the preferred spare gasification train approach, only reduced the cost by about 21%, but it has the highest availability (94.6%) and produces power at 30 $/MW-hr (at a 12% ROI). Thus, such a coke-fueled IGCC coproduction plant could fill a near term niche market. In all cases, the emissions performance of these plants is superior to the Wabash River project. Subtasks 1.5A and B developed designs for single-train coal- and coke-fueled IGCC power plants. A side-by-side comparison of these plants, which contain the Subtask 1.3 VIP enhancements, shows their similarity both in design and cost (1,318 $/kW for the coal plant and 1,260 $/kW for the coke plant). Therefore, in the near term, a coke IGCC power plant could penetrate the market and provide a foundation for future coal-fueled facilities. Subtask 1.6 generated a design, cost estimate and economics for a four-train coal-fueled IGCC power plant, also based on the Subtask 1.3 cases. This plant has a thermal efficiency to power of 40.6% (HHV) and cost 1,066 $/kW. The single-train advanced Subtask 1.4 plant, which uses an advanced ''G/H-class'' combustion turbine, can have a thermal efficiency to power of 44.5% (HHV) and a plant cost of 1,116 $/kW. Multi-train plants will further reduce the cost. Again, all these plants have superior emissions performance. Subtask 1.7 developed an optimized design for a coal to hydrogen plant. At current natural gas prices, this facility is not competitive with hydrogen produced from natural gas. The preferred scenario is to co-produce hydrogen in a plant similar to Subtask 1.3, as described above. Subtask 1.8 evaluated the potential merits of warm gas cleanup technology. This study showed that selective catalytic oxidation of hydrogen sulfide (SCOHS) is promising. Subtask 2.1 developed a petroleum coke IGCC power plant with the coproduction of liquid fuel precursors from the Subtask 1.3 Next Plant by eliminating the export steam and hydrogen production and replacing it with a Fischer-Tropsch hydrocarbon synthesis facility that produced 4,125 bpd of liquid fuel precursors. By maximizing liquids production at the expense of power generation, Subtask 2.2 developed an optimized design that produces 10,450 bpd of liquid fuel precursors and 617 MW of export power from 5,417 tpd of dry petroleum coke. With 27 $/MW-hr power and 30 $/bbl liquids, the Subtask 2.2 plant can have a return on investment of 18%. Subtask 2.3 converted the Subtask 1.6 four-train coal fueled IGCC power plant

  8. Burn cavity growth during the Hoe Creek No. 3 underground coal gasification experiment

    SciTech Connect (OSTI)

    Hill, R.W.

    1981-01-14T23:59:59.000Z

    A detailed history is given of the growth of the burn cavity during the first month of the Hoe Creek No. 3 underground coal gasification experiment near Gillette, Wyoming, in 1979. The changing shape of the cavity with time is inferred from data from three types of instruments installed throughout the experimental zone: (1) thermocouples at various levels in a number of holes, to map temperatures; (2) extensometers at various levels in other holes, to detect motions of the overburden material; and (3) high-frequency electromagnetic (HFEM) scans made between various pairs of holes, to detect cavities and zones of burning coal. Additional data on the final shape of the underground cavity are derived from the results of a core drilling program carried out from the surface after the burn had ended. This study of cavity growth history has contributed significantly to our understanding of how the in situ coal gasification process operates in sites like Hoe Creek. The diagnostic system provided invaluable information on cavity growth and on the interaction between the two coal seams. Some new problems with injection well survival and slag production in oxygen-steam burns were brought out, and the importance of understanding and controlling heat loss mechanisms was amply demonstrated. Although no one system of underground diagnostics can give all of the information needed to fully describe the in situ process, a combination of several diagnostic systems can be used to deduce a self-consistent description.

  9. Burn cavity growth during the Hoe Creek No. 3 underground-coal-gasification experiment

    SciTech Connect (OSTI)

    Hill, R.W.

    1981-06-08T23:59:59.000Z

    A detailed history is given of the growth of the burn cavity during the first month of the Hoe Creek No. 3 underground coal gasification experiment near Gillette, Wyoming, in 1979. The changing shape of the cavity with time is inferred from data from three types of instruments installed throughout the experimental zone: (1) thermocouples at various levels in a number of holes, to map temperatures; (2) extensometers at various levels in other holes, to detect motions of the overburden material; and (3) high-frequency electromagnetic scans made between various pairs of holes, to detect cavities and zones of burning coal. Additional data on the final shape of the underground cavity is derived from the results of a core drilling program carried out from the surface after the burn had ended. This study of cavity growth history has contributed significantly to our understanding of how the in-situ coal gasification process operates in sites like Hoe Creek. The diagnostic system provided invaluable information on cavity growth and on the interaction between the two coal seams. Some new problems with injection well survival and slag production in oxygen-steam burns were brought out, and the importance of understanding and controlling heat loss mechanisms was amply demonstrated. Although no one system of underground diagnostics can give all of the information needed to fully describe the in-situ process, a combination of several diagnostic systems can be used to deduce a self-consistent description.

  10. Progress in carbon dioxide capture and separation research for gasification-based power generation point sources

    SciTech Connect (OSTI)

    Pennline, H.; Luebke, D.; Jones, K.; Myers, C.; Morsi, B.; Heintz, Y.; Ilconich, J.

    2008-01-01T23:59:59.000Z

    The purpose of the present work is to investigate novel approaches, materials, and molecules for the abatement of carbon dioxide (CO2) at the pre-combustion stage of gasification-based power generation point sources. The capture/separation step for CO2 from large point sources is a critical one with respect to the technical feasibility and cost of the overall carbon sequestration scenario. For large point sources, such as those found in power generation, the carbon dioxide capture techniques being investigated by the Office of Research and Development of the National Energy Technology Laboratory possess the potential for improved efficiency and reduced costs as compared to more conventional technologies. The investigated techniques can have wide applications, but the present research is focused on the capture/separation of carbon dioxide from fuel gas (precombustion gas) from processes such as the Integrated Gasification Combined Cycle (IGCC) process. For such applications, novel concepts are being developed in wet scrubbing with physical sorption, chemical sorption with solid sorbents, and separation by membranes. In one concept, a wet scrubbing technique is being investigated that uses a physical solvent process to remove CO2 from fuel gas of an IGCC system at elevated temperature and pressure. The need to define an “ideal” solvent has led to the study of the solubility and mass transfer properties of various solvents. Pertaining to another separation technology, fabrication techniques and mechanistic studies for membranes separating CO2 from the fuel gas produced by coal gasification are also being performed. Membranes that consist of CO2-philic ionic liquids encapsulated into a polymeric substrate have been investigated for permeability and selectivity. Finally, processes based on dry, regenerable sorbents are additional techniques for CO2 capture from fuel gas. An overview of these novel techniques is presented along with a research progress status of technologies related to membranes and physical solvents.

  11. LLNL underground coal gasification project. Quarterly progress report, October-December 1980

    SciTech Connect (OSTI)

    Olness, D.U. (ed.)

    1981-01-26T23:59:59.000Z

    We have continued laboratory studies of forward gasification through drilled holes in small blocks of coal (approx. 30 cm on a side). Such studies give insight into cavity growth mechanisms and particulate production. In addition, we have been developing a mathematical model for these experiments in order to further our understanding of the physical and chemical processes governing the burning of the coal and the growth of the cavity within the block. This model will be adapted, later, to larger-scale coal-block experiments, and finally to full-scale field exoperiments. We hope to obtain scaling laws and other insights from the model. The small-block experiments are beginning to provide information relevant to the early-time cavity growth. The natural extension of these experiments to larger blocks, perhaps 10ft or more on a side, is presently being planned. The large-block tests will be conducted at a mine, where blocks of coal will be isolated by the experimenter; the objective will be to quantify early-time cavity growth. We completed planning for the directionally drilled injection well for DOE Experiment No. 1. Assessment of the data obtained during the various underground coal gasification tests is continuing. Results from the four different diagnostic systems have been combined to produce a description of the shape of the burn cavity as a function of time during the Hoe Creek No. 3 experiment. Groundwater samples from wells located at distances of a few feet to several hundred feet from the gasification cavities have been collected before, during, and after each of the Hoe Creek tests. The analysis of the groundwater contamination data pertinent to the Hoe Creek No. 2 test was completed.

  12. Prospects for the Gasification of Refuse-Derived Fuel (RDF)

    E-Print Network [OSTI]

    Woodruff, K. L.; Guard, R. F. W.

    1983-01-01T23:59:59.000Z

    Fluidized-bed gasification of wood waste is now a commercially proven technology. An Omnifuel gasifier in Hearst, Ontario, has been in operation since early 1981. It produces a low-BTU gas which is used to displace natural gas in existing boilers...

  13. Gasification of woody biomass Tessa Jansen (s0140600)

    E-Print Network [OSTI]

    Luding, Stefan

    which I was a (small) part of is GasBio (gasification for biofuels). The main objectives of this project are to develop Norwegian competence in the biofuels area and to contribute to the reduction of biofuel production emission, as an important greenhouse gas, have been recognized by large parts of the world. The security

  14. Prospects for the Gasification of Refuse-Derived Fuel (RDF) 

    E-Print Network [OSTI]

    Woodruff, K. L.; Guard, R. F. W.

    1983-01-01T23:59:59.000Z

    Fluidized-bed gasification of wood waste is now a commercially proven technology. An Omnifuel gasifier in Hearst, Ontario, has been in operation since early 1981. It produces a low-BTU gas which is used to displace natural gas in existing boilers...

  15. EIS-0007: Low Btu Coal Gasification Facility and Industrial Park

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy prepared this environmental impact statement which evaluates the potential environmental impacts that may be associated with the construction and operation of a low-Btu coal gasification facility and the attendant industrial park in Georgetown, Scott County, Kentucky.

  16. EIS-0072: Great Plains Gasification Project, Mercer County, North Dakota

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy prepared this EIS to evaluate the impacts of a project to construct a 125 million cubic feet per day coal gasification facility located in Mercer County, North Dakota. The Office of Fossil Energy adopted three environmental impact evaluation documents prepared by other Federal agencies to develop this EIS.

  17. EIS-0409: Kemper County Integrated Gasification Combined Cycle Project, Mississippi

    Broader source: Energy.gov [DOE]

    This EIS analyzes DOE's decision to provide funding for the Kemper County Integrated Gasification Combined Cycle Project in Kemper County, Mississippi to assess the potential environmental impacts associated with the construction and operation of a project proposed by Southern Power Company, through its affiliate Mississippi Power Company, which has been selected by DOE for consideration under the Clean Coal Power Initiative (CCPI) program.

  18. Utilization of char from biomass gasification in catalytic applications

    E-Print Network [OSTI]

    temperature or time. In addition, micropores were observed in char that was made in CO2, but not in char, but sintering was not observed during gasification with CO2. This showed that the properties of char depend catalytically or thermally. However, thermal decomposition requires high temperatures, and catalyst deactivation

  19. Process analysis and simulation of underground coal gasification

    SciTech Connect (OSTI)

    Chang, H.L.

    1984-01-01T23:59:59.000Z

    This investigation pertains to the prediction of cavity growth and the prediction of product gas composition in underground coal gasification (ICG) via mathematical model. The large-scale simulation model of the UCG process is comprised of a number of sub-models, each describing definable phenomena in the process. Considerable effort has been required in developing these sub-models, which are described in this work. In the first phase of the investigation, the flow field in field experiments was analyzed using five selected flow models and a combined model was developed based on the Hoe Creek II field experimental observations. The combined model was a modified tanks-in-series mode, and each tank consisted of a void space and a rubble zone. In the second phase of this work, a sub-model for self-gasification of coal was developed and simulated to determine the effect of water influx on the consumption of coal and whether self-gasification of coal alone was shown to be insufficient to explain the observed cavity growth. In the third phase of this work, a new sweep efficiency model was developed and coded to predict the cavity growth and product gas composition. Self-gasification of coal, water influx, and roof collapse and spalling were taken into account in the model. Predictions made by the model showed reasonable agreement with the experimental observations and calculations.

  20. In-situ coal-gasification data look promising

    SciTech Connect (OSTI)

    Not Available

    1980-07-21T23:59:59.000Z

    According to a report given at the 6th Underground Coal Conversion Symposium (Afton, Oklahoma 1980), the Hoe Creek No. 3 underground coal-gasification experiments Oil Gas J. 77 sponsored by the U.S. Department of Energy and the Gas Research Institute and directed by the University of California Lawrence Livermore Laboratory demonstrated the feasibility of in-situ coal conversion and featured the use of a directionally drilled channel to connect the injection and production wells rather than the reverse-burn ordinarily used to produce the connecting channel. In the test, 2816 cu m of coal weighing (APPROX) 4200 tons was consumed, with (APPROX) 18% of the product gas escaping through the overburden or elsewhere. When air injection was used, the average heating value was 217 Btu/std cu ft. The average thermal efficiency of the burn was 65%, and the average gas composition was 35% hydrogen, 5% methane, 11% carbon monoxide, and 44% carbon dioxide. Subsidence occurred after completion of the test. The Uniwell gasification method, scheduled for use in the final experiment in the Deep-1 series of underground coal-gasification tests in Wyoming, seeks to prevent subsidence by use of concentric pipes which are inserted into the vertical well to control the combustion zone. Underground coal-gasification prospects and the mechanics of subsidence are discussed.

  1. Modeling, Optimization and Economic Evaluation of Residual Biomass Gasification

    E-Print Network [OSTI]

    Georgeson, Adam

    2012-02-14T23:59:59.000Z

    . .............................................................................. 7 Table 2. Components Used in Simulation. ...................................................................... 20 Table 3. Composition of Biomass Feedstock to Biorefinery. ......................................... 43 Table 4. Operating... for optimizing gasification plant design from an economic perspective. Specifically, the problem addressed in this work is stated as follows: Given are: ? A set of biomass feedstocks {i|i = 1,2,?,I } which includes fresh as well as residue biomass ? A set...

  2. Feasibility of black liquor gasification in combined cycle cogeneration. Final report, Phase I

    SciTech Connect (OSTI)

    Kelleher, E.G.

    1983-06-30T23:59:59.000Z

    A small-scale test program of 65% solids black liquor gasification was conducted in the bench-scale molten salt gasifier. Nine tests were performed using both air and oxygen as the oxidant. The black liquor gasified readily and the product gas had a dry-basis heating value of 70 Btu/scf with air and about 250 Btu/scf with oxygen. These values were almost identical to values predicted on the basis of thermodynamic equilibrium in the gas phase, indicating that the system had achieved near-equilibrium. However, the reduction of the melt to sodium sulfide was generally low. An independent research program aimed at improving the performance of air-blown black liquor gasification was conducted. That work resulted in a modified gasifier system design which increased the off-gas heating value to 120 Btu/scf and the reduction of the melt to over 95%. This was an improvement that would potentially allow use of the scrubbed product gas as a feed to a combustion gas turbine without prior enrichment.

  3. Investigation of an integrated switchgrass gasification/fuel cell power plant. Final report for Phase 1 of the Chariton Valley Biomass Power Project

    SciTech Connect (OSTI)

    Brown, R.C.; Smeenk, J. [Iowa State Univ., Ames, IA (United States); Steinfeld, G. [Energy Research Corp., Danbury, CT (United States)

    1998-09-30T23:59:59.000Z

    The Chariton Valley Biomass Power Project, sponsored by the US Department of Energy Biomass Power Program, has the goal of converting switchgrass grown on marginal farmland in southern Iowa into electric power. Two energy conversion options are under evaluation: co-firing switchgrass with coal in an existing utility boiler and gasification of switchgrass for use in a carbonate fuel cell. This paper describes the second option under investigation. The gasification study includes both experimental testing in a pilot-scale gasifier and computer simulation of carbonate fuel cell performance when operated on gas derived from switchgrass. Options for comprehensive system integration between a carbonate fuel cell and the gasification system are being evaluated. Use of waste heat from the carbonate fuel cell to maximize overall integrated plant efficiency is being examined. Existing fuel cell power plant design elements will be used, as appropriate, in the integration of the gasifier and fuel cell power plant to minimize cost complexity and risk. The gasification experiments are being performed by Iowa State University and the fuel cell evaluations are being performed by Energy Research Corporation.

  4. Integrated Sensing and Controls for Coal Gasification - Development of Model-Based Controls for GE's Gasifier and Syngas Cooler

    SciTech Connect (OSTI)

    Aditya Kumar

    2010-12-30T23:59:59.000Z

    This report summarizes the achievements and final results of this program. The objective of this program is to develop a comprehensive systems approach to integrated design of sensing and control systems for an Integrated Gasification Combined Cycle (IGCC) plant, using advanced model-based techniques. In particular, this program is focused on the model-based sensing and control system design for the core gasification section of an IGCC plant. The overall approach consists of (i) developing a first-principles physics-based dynamic model of the gasification section, (ii) performing model-reduction where needed to derive low-order models suitable for controls analysis and design, (iii) developing a sensing system solution combining online sensors with model-based estimation for important process variables not measured directly, and (iv) optimizing the steady-state and transient operation of the plant for normal operation as well as for startup using model predictive controls (MPC). Initially, available process unit models were implemented in a common platform using Matlab/Simulink{reg_sign}, and appropriate model reduction and model updates were performed to obtain the overall gasification section dynamic model. Also, a set of sensor packages were developed through extensive lab testing and implemented in the Tampa Electric Company IGCC plant at Polk power station in 2009, to measure temperature and strain in the radiant syngas cooler (RSC). Plant operation data was also used to validate the overall gasification section model. The overall dynamic model was then used to develop a sensing solution including a set of online sensors coupled with model-based estimation using nonlinear extended Kalman filter (EKF). Its performance in terms of estimating key unmeasured variables like gasifier temperature, carbon conversion, etc., was studied through extensive simulations in the presence sensing errors (noise and bias) and modeling errors (e.g. unknown gasifier kinetics, RSC fouling). In parallel, an MPC solution was initially developed using ideal sensing to optimize the plant operation during startup pre-heating as well as steady state and transient operation under normal high-pressure conditions, e.g. part-load, base-load, load transition and fuel changes. The MPC simulation studies showed significant improvements both for startup pre-heating and for normal operation. Finally, the EKF and MPC solutions were coupled to achieve the integrated sensing and control solution and its performance was studied through extensive steady state and transient simulations in the presence of sensor and modeling errors. The results of each task in the program and overall conclusions are summarized in this final report.

  5. Investigation of a sulfur reduction technique for mild gasification char. Technical report, September 1, 1991--November 30, 1991

    SciTech Connect (OSTI)

    Knight, R.A.

    1991-12-31T23:59:59.000Z

    The object of this program is to investigate the desulfurization of mild gasification char using hydrogen/methane mixtures in a laboratory-scale experimental study. In the first year of the two- year program, char is being treated with mixtures of H{sub 2} and CH{sub 4} at temperatures of 1100{degrees}C to 1550{degrees}F and pressures of 50 to 100 psig. The effects of temperature, pressure, residence time, gas velocity, and gas composition on sulfur removal and carbon gasification are being determined. The batch experiments are being performed in a nominal 2-inch-ID stainless-steel, batch, fluidized-bed reactor. The char to be desulfurized was produced by the IGT mild gasification process research unit (PRU) in a recently completed DOE/METC-sponsored technology development program. The parent coal was Illinois No. 6 from a preparation plant, and the char from the selected test contains 4.58 wt% sulfur. In the first quarter, we have obtained and prepared a char for the desulfurization tests. Ultimate and proximate analyses were performed on this char, and its pore size distribution and surface area were determined. Also this quarter, the fluidized-bed reactor system was constructed and equipped with high pressure mass flow controllers and a high pressure sintered metal filter to remove fines from the effluent gas stream.

  6. Role of hydrogeology in Rocky Mountain 1 underground coal gasification test, Hanna basin, Wyoming

    SciTech Connect (OSTI)

    Daly, D.J.; Schmit, C.R.; Beaver, F.W.; Evans, J.M. (North Dakota Mining and Mineral Resources Research Institute, Grand Forks (USA))

    1989-09-01T23:59:59.000Z

    Experience has shown that the designs and implementation of Underground Coal Gasification (UCG) operations that are technically sound and environmentally safe require a thorough understanding of the hydrogeology of the UCG site, complemented by an understanding of the potential interactions between the elements of the hydrogeologic system and UCG process. This is significant because UCG is conducted in the saturated zone, consumes large volumes of ground water, and has the potential to adversely affect ground water quality and flow. The textural, mineralogical, chemical, and structural character of the geologic materials constituting the UCG reactor, as well as the occurrence, flow, and quality of fluids moving through that three-dimensional matrix of geologic materials, must be understood. The US Department of Energy and an industry consortium led by the Gas Research Institute recently conducted the Rocky Mountain 1 Test in the Hanna basin of Wyoming. For this test, the hydrogeologic aspects of the site were characterized to an extent unprecedented in UCG testing. This information was then used to develop and evaluate operating strategies intended to prevent or minimize contamination. Such strategies included gasifying at less than hydrostatic pressure to enhance ground water flow toward the gasification modules and to restrict contamination to the module area. Hydrogeologic information also allowed a more complete evaluation of process-setting interactions. For example, a substantial and widespread drop in elevation heat noted for the ground water in the target coal emphasized the importance of an adequate water supply for UCG, particularly in a long-term commercial operation.

  7. High resolution seismic survey of the Hanna, Wyoming underground coal gasification area

    SciTech Connect (OSTI)

    Not Available

    1983-08-01T23:59:59.000Z

    In June 1983 a high resolution seismic survey was conducted at the Department of Energy, Laramie Energy Technology Center's underground coal gasification test site near Hanna, Wyoming. The objectives of the survey were to locate and characterize underground burn zones and to identify shallow geologic faults at the test site. Seismic data acquisition and processing parameters were based upon prior work in the area, and were specifically designed to emphasize reflections at the shallow, 61 to 91 meter (200 to 300 ft) depths of interest. Data were obtained on two north-south lines along the test site boundary in addition to a three-dimensional grid over the Hanna IV experiment area. Processing included time varying filters, deconvolution, trace composition, and three-dimensional areal stacking of the data in order to identify burn zone anomalies. Anomalies were discernable resulting from the rubble-collapse void above the burn zones in the vicinity of the injection wells at the Hanna IV experiment area. The fault studies disclosed faults at the Hanna IV experiment area which may be responsible for the unexpected problems experienced in the early in-site gasification tests. For the test site the fault system was found to be a generally arcuate east-west trending graben complex with numerous antithetic faults. 15 references, 33 figures, 6 tables.

  8. Material Characterization and Analysis for Selection of Refractories Used In Black Liquor Gasification

    SciTech Connect (OSTI)

    Hemrick, James Gordon [ORNL; Keiser, James R [ORNL; Meisner, Roberta Ann [ORNL; Gorog, John Peter [ORNL

    2008-01-01T23:59:59.000Z

    Black liquor gasification provides the pulp and paper industry with a technology which could potentially replace recovery boilers with equipment that could reduce emissions and, if used in a combined cycle system, increase the power production of the mill allowing it to be a net exporter of electrical power. In addition, rather than burning the syngas produced in a gasifier, this syngas could be used to produce higher value chemicals or fuels. However, problems with structural materials, and particularly the refractory lining of the reactor vessel, have caused unplanned shutdowns and resulted in component replacement much sooner than originally planned. Through examination of exposed materials, laboratory corrosion tests and cooperative efforts with refractory manufacturers, many refractory materials issues in high-temperature black liquor gasification have been addressed and optimized materials have been selected for this application. In this paper, the characterization and analysis techniques used for refractory screening and selection will be discussed along with characteristic results from these methods which have led to the selection of optimized materials for this application.

  9. Material Characterization and Analysis for Selection of Refractories Used in Black Liquor Gasification

    SciTech Connect (OSTI)

    Hemrick, James Gordon [ORNL; Keiser, James R [ORNL; Meisner, Roberta A [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL)

    2010-01-01T23:59:59.000Z

    Black liquor gasification provides the pulp and paper industry with a technology which could potentially replace recovery boilers with equipment that could reduce emissions and, if used in a combined cycle system, increase the power production of the mill allowing it to be a net exporter of electrical power. In addition, rather than burning the syngas produced in a gasifier, this syngas could be used to produce higher value chemicals or fuels. However, problems with structural materials such as the refractory lining of the reactor vessel have caused unplanned shutdowns and resulted in component replacement much sooner than originally planned. Through examination of exposed materials, laboratory corrosion tests and cooperative efforts with refractory manufacturers, many refractory materials issues in high-temperature black liquor gasification have been addressed and optimized materials have been selected for this application. In this paper, an updated summary of the characterization and analysis techniques used for refractory screening and selection will be discussed along with characteristic results from these methods which have led to the selection of optimized materials for both the hot-face and back-up linings used in this application.

  10. FUNDAMENTAL INVESTIGATION OF FUEL TRANSFORMATIONS IN PULVERIZED COAL COMBUSTION AND GASIFICATION TECHNOLOGIES

    SciTech Connect (OSTI)

    Robert Hurt; Joseph Calo; Thomas H. Fletcher; Alan Sayre

    2005-04-29T23:59:59.000Z

    The goal of this project was to carry out the necessary experiments and analyses to extend current capabilities for modeling fuel transformations to the new conditions anticipated in next-generation coal-based, fuel-flexible combustion and gasification processes. This multi-organization, multi-investigator project has produced data, correlations, and submodels that extend present capabilities in pressure, temperature, and fuel type. The combined experimental and theoretical/computational results are documented in detail in Chapters 1-8 of this report, with Chapter 9 serving as a brief summary of the main conclusions. Chapters 1-3 deal with the effect of elevated pressure on devolatilization, char formation, and char properties. Chapters 4 and 5 deal with advanced combustion kinetic models needed to cover the extended ranges of pressure and temperature expected in next-generation furnaces. Chapter 6 deals with the extension of kinetic data to a variety of alternative solid fuels. Chapter 7 focuses on the kinetics of gasification (rather than combustion) at elevated pressure. Finally, Chapter 8 describes the integration, testing, and use of new fuel transformation submodels into a comprehensive CFD framework. Overall, the effects of elevated pressure, temperature, heating rate, and alternative fuel use are all complex and much more work could be further undertaken in this area. Nevertheless, the current project with its new data, correlations, and computer models provides a much improved basis for model-based design of next generation systems operating under these new conditions.

  11. Groundwater restoration field test at the Hoe Creek underground coal gasification site

    SciTech Connect (OSTI)

    Nordin, J.S.; Barrash, W.; Nolan, B.T.

    1988-02-01T23:59:59.000Z

    Three underground coal gasification burns were conducted at the Hoe Creek Site in the Powder River Basin. Some contaminants were released in the groundwater. The Department of Energy (DOE) analyzed the water from a network of wells. Two million gallons of groundwater were pumped from wells adjacent to the Hoe Creek II underground coal gasification cavity, passed through filters and carbon adsorbers, and reinjected into the cavity. Phenol was the target compound of the water treatment system. The phenol concentration pumped from well WS-10 decreased from 974 parts per billion (ppB) when treatment began on July 2, 1987, to about 200 ppB when treatment ceased on August 29, 1987. Phenol concentrations pumped from well WS-22 fluctuated during the tests, but they decreased to the 150 to 200 ppB range by the time treatment was terminated. The phenol concentration of treated water reinjected into the Hoe Creek II cavity was below detectable limits (less than 20 ppB). Pumping rates were about 18 gallons per minute (gpm) from well WS-10 and 6 to 8 gpm from well WS-22. Hoe Creek is located approximately 20 miles southwest of Gillette, Wyoming. 12 refs., 5 figs., 8 tabs.

  12. Assessment of the SRI Gasification Process for Syngas Generation with HTGR Integration -- White Paper

    SciTech Connect (OSTI)

    A.M. Gandrik

    2012-04-01T23:59:59.000Z

    This white paper is intended to compare the technical and economic feasibility of syngas generation using the SRI gasification process coupled to several high-temperature gas-cooled reactors (HTGRs) with more traditional HTGR-integrated syngas generation techniques, including: (1) Gasification with high-temperature steam electrolysis (HTSE); (2) Steam methane reforming (SMR); and (3) Gasification with SMR with and without CO2 sequestration.

  13. Hydrogen Production from Biomass via Indirect Gasification: The Impact of NREL Process Development Unit Gasifier Correlations

    SciTech Connect (OSTI)

    Kinchin, C. M.; Bain, R. L.

    2009-05-01T23:59:59.000Z

    This report describes a set of updated gasifier correlations developed by NREL to predict biomass gasification products and Minimum Hydrogen Selling Price.

  14. Proceedings of the eleventh annual underground coal gasification symposium

    SciTech Connect (OSTI)

    Not Available

    1985-12-01T23:59:59.000Z

    The Eleventh Annual Underground Coal Gasification Symposium was sponsored by the Laramie Project Office of the Morgantown Energy Technology Center, US Department of Energy, and hosted by the Western Research Institute, University of Wyoming research Corporation, in Denver, Colorado, on August 11 to 14, 1985. The five-session symposium included 37 presentations describing research on underground coal gasification (UCG) being performed throughout the world. Eleven of the presentations were from foreign countries developing UCG technology for their coal resources. The papers printed in the proceedings have been reproduced from camera-ready manuscripts furnished by the authors. The papers have not been refereed, nor have they been edited extensively. All papers have been processed for inclusion in the Energy Data Base.

  15. Methods and apparatus for catalytic hydrothermal gasification of biomass

    DOE Patents [OSTI]

    Elliott, Douglas C.; Butner, Robert Scott; Neuenschwander, Gary G.; Zacher, Alan H.; Hart, Todd R.

    2012-08-14T23:59:59.000Z

    Continuous processing of wet biomass feedstock by catalytic hydrothermal gasification must address catalyst fouling and poisoning. One solution can involve heating the wet biomass with a heating unit to a temperature sufficient for organic constituents in the feedstock to decompose, for precipitates of inorganic wastes to form, for preheating the wet feedstock in preparation for subsequent separation of sulfur contaminants, or combinations thereof. Treatment further includes separating the precipitates out of the wet feedstock, removing sulfur contaminants, or both using a solids separation unit and a sulfur separation unit, respectively. Having removed much of the inorganic wastes and the sulfur that can cause poisoning and fouling, the wet biomass feedstock can be exposed to the heterogeneous catalyst for gasification.

  16. Large-block experiments in underground coal gasification

    SciTech Connect (OSTI)

    Not Available

    1982-11-01T23:59:59.000Z

    A major objective of the nation's energy program is to develop processes for cleanly producing fuels from coal. One of the more promising of these is underground coal gasification (UCG). If successful, UCG would quadruple recoverable U.S. coal reserves. Under the sponsorship of the Department of Energy (DOE), Lawrence Livermore National Laboratory (LLNL) performed an early series of UCG field experiments from 1976 through 1979. The Hoe Creek series of tests were designed to develop the basic technology of UCG at low cost. The experiments were conducted in a 7.6-m thick subbituminous coal seam at a relatively shallow depth of 48 m at a site near Gillette, Wyoming. On the basis of the Hoe Creek results, more extensive field experiments were designed to establish the feasibility of UCG for commercial gas production under a variety of gasification conditions. Concepts and practices in UCG are described, and results of the field tests are summarized.

  17. UTILIZATION OF LIGHTWEIGHT MATERIALS MADE FROM COAL GASIFICATION SLAGS

    SciTech Connect (OSTI)

    Vas Choudhry; Stephen Kwan; Steven R. Hadley

    2001-07-01T23:59:59.000Z

    The objective of the project entitled ''Utilization of Lightweight Materials Made from Coal Gasification Slags'' was to demonstrate the technical and economic viability of manufacturing low-unit-weight products from coal gasification slags which can be used as substitutes for conventional lightweight and ultra-lightweight aggregates. In Phase I, the technology developed by Praxis to produce lightweight aggregates from slag (termed SLA) was applied to produce a large batch (10 tons) of expanded slag using pilot direct-fired rotary kilns and a fluidized bed calciner. The expanded products were characterized using basic characterization and application-oriented tests. Phase II involved the demonstration and evaluation of the use of expanded slag aggregates to produce a number of end-use applications including lightweight roof tiles, lightweight precast products (e.g., masonry blocks), structural concrete, insulating concrete, loose fill insulation, and as a substitute for expanded perlite and vermiculite in horticultural applications. Prototypes of these end-use applications were made and tested with the assistance of commercial manufacturers. Finally, the economics of expanded slag production was determined and compared with the alternative of slag disposal. Production of value-added products from SLA has a significant potential to enhance the overall gasification process economics, especially when the avoided costs of disposal are considered.

  18. Pressurized pyrolysis and gasification of Chinese typical coal samples

    SciTech Connect (OSTI)

    Hanping Chen; Zhiwu Luo; Haiping Yang; Fudong Ju; Shihong Zhang [Huazhong University of Science and Technology, Wuhan (China). State Key Laboratory of Coal Combustion

    2008-03-15T23:59:59.000Z

    This paper aims to understand the pyrolysis and gasification behavior of different Chinese coal samples at different pressures. First, the pyrolysis of four typical Chinese coals samples (Xiaolongtan brown coal, Shenfu bituminous coal, Pingzhai anthracite coal, and Heshan lean coal) were carried out using a pressurized thermogravimetric analyzer at ambient pressure and 3 MPa, respectively. The surface structure and elemental component of the resultant char were measured with an automated gas adsorption apparatus and element analyzer. It was observed that higher pressure suppressed the primary pyrolysis, while the secondary pyrolysis of coal particles was promoted. With respect to the resultant solid char, the carbon content increased while H content decreased; however, the pore structure varied greatly with increasing pressure for different coal samples. For Xiaolongtan brown coal (XLT) char, it decreased greatly, while it increased obviously for the other three char types. Then, the isothermal gasification behavior of solid char particles was investigated using an ambient thermal analyzer with CO{sub 2} as the gasifying agent at 1000{sup o}C. The gasification reactivity of solid char was decreased greatly with increasing pyrolysis pressure. However, the extent of change displayed a vital relation with the characteristics of the original coal sample. 26 refs., 5 figs., 5 tabs.

  19. High frequency electromagnetic burn monitoring for underground coal gasification

    SciTech Connect (OSTI)

    Deadrick, F.J.; Hill, R.W.; Laine, E.F.

    1981-06-17T23:59:59.000Z

    This paper describes the use of high frequency electromagnetic waves to monitor an in-situ coal gasification burn process, and presents some recent results obtained with the method. Both the technique, called HFEM (high frequency electromagnetic) probing, the HFEM hardware used are described, and some of the data obtained from the LLNL Hoe Creek No. 3 underground coal gasification experiment conducted near Gillette, Wyoming are presented. HFEM was found to be very useful for monitoring the burn activity found in underground coal gasification. The technique, being a remote sensing method which does not require direct physical contact, does not suffer from burnout problems as found with thermocouples, and can continue to function even as the burn progresses on through the region of interest. While HFEM does not replace more conventional instrumentation such as thermocouples, the method does serve to provide data which is unobtainable by other means, and in so doing it complements the other data to help form a picture of what cannot be seen underground.

  20. Power Systems Development Facility

    SciTech Connect (OSTI)

    Southern Company Services

    2009-01-31T23:59:59.000Z

    In support of technology development to utilize coal for efficient, affordable, and environmentally clean power generation, the Power Systems Development Facility (PSDF), located in Wilsonville, Alabama, has routinely demonstrated gasification technologies using various types of coals. The PSDF is an engineering scale demonstration of key features of advanced coal-fired power systems, including a Transport Gasifier, a hot gas particulate control device, advanced syngas cleanup systems, and high-pressure solids handling systems. This final report summarizes the results of the technology development work conducted at the PSDF through January 31, 2009. Twenty-one major gasification test campaigns were completed, for a total of more than 11,000 hours of gasification operation. This operational experience has led to significant advancements in gasification technologies.

  1. Study of JET Soft Housekeeping Waste Volume Reduction by Plasma Arc Centrifuge and Gasification in Countercurrent Regime Methods

    E-Print Network [OSTI]

    Study of JET Soft Housekeeping Waste Volume Reduction by Plasma Arc Centrifuge and Gasification in Countercurrent Regime Methods

  2. Improved Materials for High-Temperature Black Liquor Gasification

    SciTech Connect (OSTI)

    Keiser, J.R.; Hemrick, J.G.; Gorog, J.P.; Leary, R.

    2006-06-29T23:59:59.000Z

    The laboratory immersion test system built and operated at ORNL was found to successfully screen samples from numerous refractory suppliers, including both commercially available and experimental materials. This system was found to provide an accurate prediction of how these materials would perform in the actual gasifier environment. Test materials included mullites, alumino-silicate bricks, fusion-cast aluminas, alumina-based and chrome-containing mortars, phosphate-bonded mortars, coated samples provided under an MPLUS-funded project, bonded spinels, different fusion-cast magnesia-alumina spinels with magnesia content ranging from 2.5% to about 60%, high-MgO castable and brick materials, spinel castables, and alkali-aluminate materials. This testing identified several candidate material systems that perform well in the New Bern gasifier. Fusion-cast aluminas were found to survive for nearly one year, and magnesia-alumina spinels have operated successfully for 18 months and are expected to survive for two years. Alkali-aluminates and high-MgO-content materials have also been identified for backup lining applications. No other material with a similar structure and chemical composition to that of the fusion-cast magnesium-aluminum spinel brick currently being used for the hot-face lining is commercially available. Other materials used for this application have been found to have inferior service lives, as previously discussed. Further, over 100 laboratory immersion tests have been performed on other materials (both commercial and experimental), but none to date has performed as well as the material currently being used for the hot-face lining. Operating experience accumulated with the high-temperature gasifier at New Bern, North Carolina, has confirmed that the molten alkali salts degrade many types of refractories. Fusion-cast alumina materials were shown to provide a great improvement in lifetime over materials used previously. Further improvement was realized with fusion-cast magnesia-alumina spinel refractory, which appears to be the most resistant to degradation found to date, exhibiting over a year of service life and expected to be capable of over two years of service life. Regarding the use of refractory mortar, it was found that expansion of the current chrome-alumina mortar when subjected to black liquor smelt is likely contributing to the strains seen on the vessel shell. Additionally, the candidate high-alumina mortar that was originally proposed as a replacement for the current chrome-alumina mortar also showed a large amount of expansion when subjected to molten smelt. A UMR experimental mortar, composed of a phosphate bonded system specifically designed for use with fusion-cast magnesium-aluminum spinel, was found to perform well in the molten smelt environment. Strain gauges installed on the gasifier vessel shell provided valuable information about the expansion of the refractory, and a new set of strain gauges and thermocouples has been installed in order to monitor the loading caused by the currently installed spinel refractory. These results provide information for a direct comparison of the expansion of the two refractories. Measurements to date suggest that the fusion-cast magnesia-alumina spinel is expanding less than the fusion-cast {alpha}/{beta}-alumina used previously. A modified liquor nozzle was designed and constructed to test a number of materials that should be more resistant to erosion and corrosion than the material currently used. Inserts made of three erosion-resistant metallic materials were fabricated, along with inserts made of three ceramic materials. The assembled system was sent to the New Bern mill for installation in the gasifer in 2005. Following operation of the gasifier using the modified nozzle, inserts should be removed and analyzed for wear by erosion/corrosion. Although no materials have been directly identified for sensor/thermocouple protection tubes, several of the refractory material systems identified for lining material applications may be applicable for use in this

  3. Development of an advanced, continuous mild gasification process for the production of co-products: Topical report

    SciTech Connect (OSTI)

    Cha, C.Y.; Merriam, N.W.; Jha, M.C.; Breault, R.W.

    1988-06-01T23:59:59.000Z

    Research on mild gasification is discussed. The report is divided into three sections: literature survey of mild gasification processes; literature survey of char, condensibles, and gas upgrading and utilization methods; and industrial market assessment of products of mild gasification. Recommendations are included in each section. (CBS) 248 refs., 58 figs., 62 tabs.

  4. Mar., 1955 GASIFICATIONOF CARBONRODSWITH CARBONDIOXIDE 241 GASIFICATION OF CARBON RODS WITH CARBON DIOXIDE1*2

    E-Print Network [OSTI]

    commercial carbons and their gasification rates with carbon dioxide at a series of temperatures between 900 and 1300" has been investigated. The following properties of the carbons have been determined: yantitative. No general correlation between these properties and the carbon gasification rates was found. Introduction

  5. Current Gasification Research | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    At the Power Systems Development Facility (PSDF) in Wilsonville, Alabama, (a DOEindustry partnership project to develop clean, economical and reliable processes for power and...

  6. The Hanna and Hoe Creek underground coal gasification test sites: Status report, (June 1986-June 1987)

    SciTech Connect (OSTI)

    Berdan, G.L.; Nolan, B.T.; Barteaux, W.L.; Barrash, W.

    1987-06-01T23:59:59.000Z

    To comply with a cooperative agreement with the U.S. Department of Energy (DOE), the Western Research Institute (WRI) is required to submit an annual report summarizing the status of environmentally related work performed by WRI at the Hanna and Hoe Creek underground coal gasification (UCG) sites. The following is a summary of work performed at these two sites from June 1986 to June 1987. Several tasks for restoring the water quailty at Hoe Creek were: (1) groundwater treatment demonstration (1986); (2) bench-scale carbon adsorption experiments (1987); (3) design of the scaled-up treatment system (1987); (4) well-pumping test (1987). A summary of the results of each task is presented. 6 refs., 8 figs., 4 tabs.

  7. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems

    SciTech Connect (OSTI)

    Sadowski, R.S.; Brown, M.J.; Hester, J.C.; Harriz, J.T.; Ritz, G.J.

    1991-02-01T23:59:59.000Z

    The objective of this study is to develop standardized air blown fixed bed gasification hot gas cleanup integrated gasifier combined cycle (IGCC) systems.

  8. Computational fluid dynamics modeling of coal gasification in a pressurized spout-fluid bed

    SciTech Connect (OSTI)

    Zhongyi Deng; Rui Xiao; Baosheng Jin; He Huang; Laihong Shen; Qilei Song; Qianjun Li [Southeast University, Nanjing (China). Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education

    2008-05-15T23:59:59.000Z

    Computational fluid dynamics (CFD) modeling, which has recently proven to be an effective means of analysis and optimization of energy-conversion processes, has been extended to coal gasification in this paper. A 3D mathematical model has been developed to simulate the coal gasification process in a pressurized spout-fluid bed. This CFD model is composed of gas-solid hydrodynamics, coal pyrolysis, char gasification, and gas phase reaction submodels. The rates of heterogeneous reactions are determined by combining Arrhenius rate and diffusion rate. The homogeneous reactions of gas phase can be treated as secondary reactions. A comparison of the calculated and experimental data shows that most gasification performance parameters can be predicted accurately. This good agreement indicates that CFD modeling can be used for complex fluidized beds coal gasification processes. 37 refs., 7 figs., 5 tabs.

  9. Development of an advanced, continuous mild gasification process for the production of co-products

    SciTech Connect (OSTI)

    Knight, R.A.; Gissy, J.; Kline, S.; Onischak, M.; Babu, S.P. (Institute of Gas Technology, Chicago, IL (USA)); Duthie, R.G. (Bechtel National, Inc., San Francisco, CA (USA))

    1990-04-01T23:59:59.000Z

    A project team consisting of the Institute of Gas Technology, Peabody Holding Company, Inc., and Bechtel National, Inc., is developing a mild gasification process that uses a fluidized/entrained-bed reactor. This reactor is designed to process caking bituminous coals over a wide range of particle sizes without oxidative pretreatment, and also without the use of oxygen or air as reactants. The co-product streams, consisting of char, fuel gas, water, and condensables, would be separated by conventional means such as cyclone, staged condensers, and recycle-oil scrubbers. An isothermal process research unit (PRU) has been built at IGT, consisting of an 8-inch-I.D., 8-foot-long fluidized-bed section and a 4-inch-I.D., 13-foot-long entrained flow section, externally heated by electrical heaters. This quarter, eleven mild gasification tests were conducted in the PRU. Illinois No. 6 coal was used in nine of the tests and a West Virginia metallurgical grade of coal was used in the last two tests. The tests conducted in the PRU this quarter were operated with feed rates about three times higher than those used in the last quarter. Results show the effect of process temperature on the shields of char, oils/tars, and gases. Various compositional effects on the oils/tars were also discovered. Char upgrading studies were completed for the char co-product options of smokeless fuel and adsorbent char. A total condensate collection system was designed for the PRU system. 18 figs., 22 tabs.

  10. Hydrogen production by supercritical water gasification of biomass. Phase 1 -- Technical and business feasibility study, technical progress report

    SciTech Connect (OSTI)

    NONE

    1997-12-01T23:59:59.000Z

    The nine-month Phase 1 feasibility study was directed toward the application of supercritical water gasification (SCWG) for the economical production and end use of hydrogen from renewable energy sources such as sewage sludge, pulp waste, agricultural wastes, and ultimately the combustible portion of municipal solid waste. Unique in comparison to other gasifier systems, the properties of supercritical water (SCW) are ideal for processing biowastes with high moisture content or contain toxic or hazardous contaminants. During Phase I, an end-to-end SCWG system was evaluated. A range of process options was initially considered for each of the key subsystems. This was followed by tests of sewage sludge feed preparation, pumping and gasification in the SCW pilot plant facility. Based on the initial process review and successful pilot-scale testing, engineering evaluations were performed that defined a baseline system for the production, storage and end use of hydrogen. The results compare favorably with alternative biomass gasifiers currently being developed. The results were then discussed with regional wastewater treatment facility operators to gain their perspective on the proposed commercial SCWG systems and to help define the potential market. Finally, the technical and business plans were developed based on perceived market needs and the projected capital and operating costs of SCWG units. The result is a three-year plan for further development, culminating in a follow-on demonstration test of a 5 MT/day system at a local wastewater treatment plant.

  11. Parametric Gasification of Oak and Pine Feedstocks Using the TCPDU and Slipstream Water-Gas Shift Catalysis

    SciTech Connect (OSTI)

    Hrdlicka, J.; Feik, C.; Carpenter, D.; Pomeroy, M.

    2008-12-01T23:59:59.000Z

    With oak and pine feedstocks, the Gasification of Biomass to Hydrogen project maximizes hydrogen production using the Full Stream Reformer during water-gas shift fixed-bed reactor testing. Results indicate that higher steam-to-biomass ratio and higher thermal cracker temperature yield higher hydrogen concentration. NREL's techno-economic models and analyses indicate hydrogen production from biomass may be viable at an estimated cost of $1.77/kg (current) and $1.47/kg (advanced in 2015). To verify these estimates, NREL used the Thermochemical Process Development Unit (TCPDU), an integrated system of unit operations that investigates biomass thermochemical conversion to gaseous and liquid fuels and chemicals.

  12. Integrated coal cleaning, liquefaction, and gasification process

    DOE Patents [OSTI]

    Chervenak, Michael C. (Pennington, NJ)

    1980-01-01T23:59:59.000Z

    Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

  13. Advancement of High Temperature Black Liquor Gasification Technology

    SciTech Connect (OSTI)

    Craig Brown; Ingvar Landalv; Ragnar Stare; Jerry Yuan; Nikolai DeMartini; Nasser Ashgriz

    2008-03-31T23:59:59.000Z

    Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the design, specification and procurement of facility upgrades. Chemrec AB is also operating a pressurized, O2-blown gasifier pilot facility in Piteaa, Sweden. There was an exchange of knowledge with the pressurized projects including utilization of the experimental results from facilities in Piteaa, Sweden. Resources at the Georgia Tech Research Corporation (GTRC, a.k.a., the Institute of Paper Science and Technology) were employed primarily to conduct the fundamental investigations on scaling and plugging mechanisms and characterization of green liquor dregs. The project also tapped GTRC expertise in the development of the critical underlying black liquor gasification rate subroutines employed in the CFD code. The actual CFD code development and application was undertaken by Process Simulation, Ltd (PSL) and Simulent, Ltd. PSL focused on the overall integrated gasifier CFD code, while Simulent focused on modeling the black liquor nozzle and description of the black liquor spray. For nozzle development and testing Chemrec collaborated with ETC (Energy Technology Centre) in Piteae utilizing their test facility for nozzle spray investigation. GTI (Gas Technology Institute), Des Plains, IL supported the team with advanced gas analysis equipment during the gasifier test period in June 2005.

  14. Catalytic gasification studies in a pressurized fluid-bed unit

    SciTech Connect (OSTI)

    Mudge, L.K.; Baker, E.G.; Mitchell, D.H.; Robertus, R.J.; Brown, M.D.

    1983-07-01T23:59:59.000Z

    The purpose of the project is to evaluate the technical and economic feasibility of producing specific gas products via the catalytic gasification of biomass. This report presents the results of research conducted from October 1980 to November 1982. In the laboratory scale studis, active catalysts were developed for generation of synthesis gases from wood by steam gasification. A trimetallic catalyst, Ni-Co-Mo on silica-alumina doped with 2 wt % Na, was found to retain activity indefinitely for generation of a methanol synthesis gas from wood at 1380/sup 0/F (750/sup 0/C) and 1 atm (100 kPa) absolute pressure. Catalysts for generation of a methane-rich gas were deactivated rapidly and could not be regenerated as required for economic application. Sodium carbonate and potassium carbonate were effective as catalysts for conversion of wood to synthesis gases and methane-rich gas and should be economically viable. Catalytic gasification conditions were found to be suitable for processing of alternative feedstocks: bagasse, alfalfa, rice hulls, and almond hulls. The PDU was operated successfully at absolute pressures of up to 10 atm (1000 kPa) and temperatures of up to 1380/sup 0/F (750/sup 0/C). Yields of synthesis gases at elevated pressure were greater than those used for previous economic evaluations. A trimetallic catalyst, Ni-Cu-Mo on silica-alumina, did not display a long life as did the doped trimetallic catalyst used in laboratory studies. A computer program for a Radio Shack TRS-80 Model I microcomputer was developed to evaluate rapidly the economics of producing either methane or methanol from wood. The program is based on economic evaluations reported in previous studies. Improved yields from the PDU studies were found to result in a reduction of about 9 cents/gal in methanol cost.

  15. Mass balances for underground coal gasification in steeply dipping beds

    SciTech Connect (OSTI)

    Lindeman, R.; Ahner, P.; Davis, B.E.

    1980-01-01T23:59:59.000Z

    Two different mass balances were used during the recent underground coal gasification tests conducted in steeply dipping coal beds at Rawlins, Wyoming. The combination of both mass balances proved extremely useful in interpreting the test results. One mass balance which assumed char could be formed underground required the solution of 3 simultaneous equations. The assumption of no char decouples the 3 equations in the other mass balance. Both mass balance results are compared to the test data to provide an interpretation of the underground process.

  16. Black liquor gasification phase 2D final report

    SciTech Connect (OSTI)

    Kohl, A.L.; Stewart, A.E.

    1988-06-01T23:59:59.000Z

    This report covers work conducted by Rockwell International under Amendment 5 to Subcontract STR/DOE-12 of Cooperative Agreement DE-AC-05-80CS40341 between St. Regis Corporation (now Champion International) and the Department of Energy (DOE). The work has been designated Phase 2D of the overall program to differentiate it from prior work under the same subcontract. The overall program is aimed at demonstrating the feasibility of and providing design data for the Rockwell process for gasifying Kraft black liquor. In this process, concentrated black liquor is converted into low-Btu fuel gas and reduced melt by reaction with air in a specially designed gasification reactor.

  17. Carbon Dioxide Capture and Separation Techniques for Gasification-based Power Generation Point Sources

    SciTech Connect (OSTI)

    Pennline, H.W.; Luebke, D.R.; Jones, K.L.; Morsi, B.I. (Univ. of Pittsburgh, PA); Heintz, Y.J. (Univ. of Pittsburgh, PA); Ilconich, J.B. (Parsons)

    2007-06-01T23:59:59.000Z

    The capture/separation step for carbon dioxide (CO2) from large-point sources is a critical one with respect to the technical feasibility and cost of the overall carbon sequestration scenario. For large-point sources, such as those found in power generation, the carbon dioxide capture techniques being investigated by the in-house research area of the National Energy Technology Laboratory possess the potential for improved efficiency and reduced costs as compared to more conventional technologies. The investigated techniques can have wide applications, but the research has focused on capture/separation of carbon dioxide from flue gas (post-combustion from fossil fuel-fired combustors) and from fuel gas (precombustion, such as integrated gasification combined cycle or IGCC). With respect to fuel gas applications, novel concepts are being developed in wet scrubbing with physical absorption; chemical absorption with solid sorbents; and separation by membranes. In one concept, a wet scrubbing technique is being investigated that uses a physical solvent process to remove CO2 from fuel gas of an IGCC system at elevated temperature and pressure. The need to define an ideal solvent has led to the study of the solubility and mass transfer properties of various solvents. Pertaining to another separation technology, fabrication techniques and mechanistic studies for membranes separating CO2 from the fuel gas produced by coal gasification are also being performed. Membranes that consist of CO2-philic ionic liquids encapsulated into a polymeric substrate have been investigated for permeability and selectivity. Finally, dry, regenerable processes based on sorbents are additional techniques for CO2 capture from fuel gas. An overview of these novel techniques is presented along with a research progress status of technologies related to membranes and physical solvents.

  18. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems. Volume 1, Final report

    SciTech Connect (OSTI)

    Sadowski, R.S.; Brown, M.J.; Hester, J.C.; Harriz, J.T.; Ritz, G.J.

    1991-02-01T23:59:59.000Z

    The objective of this study is to develop standardized air blown fixed bed gasification hot gas cleanup integrated gasifier combined cycle (IGCC) systems.

  19. Direct Causticizing for Black Liquor Gasification in a Circulating Fluidized Bed

    SciTech Connect (OSTI)

    Scott Sinquefield; Xiaoyan Zeng, Alan Ball

    2010-03-02T23:59:59.000Z

    Gasification of black liquor (BLG) has distinct advantages over direct combustion in Tomlinson recovery boilers. In this project we seek to resolve causticizing issues in order to make pressurized BLG even more efficient and cost-effective. One advantage of BLG is that the inherent partial separation of sulfur and sodium during gasification lends itself to the use of proven high yield variants to conventional kraft pulping which require just such a separation. Processes such as polysulfide, split sulfidity, ASAQ, and MSSAQ can increase pulp yield from 1% to 10% over conventional kraft but require varying degrees of sulfur/sodium separation, which requires additional [and costly] processing in a conventional Tomlinson recovery process. However during gasification, the sulfur is partitioned between the gas and smelt phases, while the sodium all leaves in the smelt; thus creating the opportunity to produce sulfur-rich and sulfur-lean white liquors for specialty pulping processes. A second major incentive of BLG is the production of a combustible product gas, rich in H2 and CO. This product gas (a.k.a. “syngas”) can be used in gas turbines for combined cycle power generation (which is twice as efficient as the steam cycle alone), or it can be used as a precursor to form liquid fuels, such as dimethyl ether or Fischer Tropsh diesel. There is drawback to BLG, which has the potential to become a third major incentive if this work is successful. The causticizing load is greater for gasification of black liquor than for combustion in a Tomlinson boiler. So implementing BLG in an existing mill would require costly increases to the causticizing capacity. In situ causticizing [within the gasifier] would handle the entire causticizing load and therefore eliminate the lime cycle entirely. Previous work by the author and others has shown that titanate direct causticizing (i.e. in situ) works quite well for high-temperature BLG (950°C), but was limited to pressures below about 5 bar. It is desirable however to operate BLG at 20-30 bar for efficiency reasons related to either firing the syngas in a turbine, or catalytically forming liquid fuels. This work focused on achieving high direct causticizing yields at 20 bars pressure. The titanate direct causticizing reactions are inhibited by CO2. Previous work has shown that the partial pressure of CO2 should be kept below about 0.5 bar in order for the process to work. This translates to a total reactor pressure limit of about 5 bar for airblown BLG, and only 2 bar for O2-blown BLG. In this work a process was developed in which the CO2 partial pressure could be manipulated to a level under 0.5 bar with the total system pressure at 10 bar during O2-blown BLG. This fell short of our 20 bar goal but still represents a substantial increase in the pressure limit. A material and energy balance was performed, as well as first-pass economics based on capital and utilities costs. Compared to a reference case of using BLG with a conventional lime cycle [Larson, 2003], the IRR and NVP were estimated for further replacing the lime kiln with direct causticizing. The economics are strongly dependent on the price of lime kiln fuel. At $6/mmBTU the lime cycle is the clear choice. At $8/mmBTU the NPV is $10M with IRR of 17%. At $12/mmBTU the NPV is $45M with IRR of 36%. To further increase the total allowable pressure, the CO2 could be further decreased by further decreasing the temperature. Testing should be done at 750C. Also a small pilot should be built.

  20. Fossil fuel gasification technical evaluation services. Final report 1978-83

    SciTech Connect (OSTI)

    Johnson, C.D.

    1983-05-01T23:59:59.000Z

    Technical evaluations performed prior to 1981 were published as a separate document, Topical Reports 1978-1980, by C F Braun and Co, November 1982, Report No. GRI-80/0168. These evaluations include the Cities Service-Rockwell, Exxon Catalytic, Mountain Fuels, Slagging Lurgi, U-Gas, and Westinghouse processes for coal gasification, the Peatgas process for peat gasification, the GE Membrane process for acid gas removal, and an integrated test facility for use in the development of gasification processes. Evaluations performed in the 1981 to 1983 period are included in the present document, the Final Report. These evaluations include the Westinghouse process for coal gasification, the Engelhard, Stone and Webster and Texaco processes for gasification of coal derived liquids, the Catalysis Research Corporation (CRC) process for direct methanation of raw gas streams, and the CNG Research Company process for removal of acid gases from coal gasification process streams. Other recent investigations include the evaluation of materials of construction, fundamental design data, and heat recovery technology for coal gasification processes.

  1. Rawlins UCG (underground coal gasification) Demonstration Project site characterization report

    SciTech Connect (OSTI)

    Not Available

    1989-04-01T23:59:59.000Z

    The United States Department of Energy and Energy International, Inc. have entered into a Cooperative Agreement to conduct a cost-shared UCG field test demonstrating the operation of commercial scale Underground Coal Gasification (UCG) on steeply dipping bed modules to provide synthesis gas for a small scale commercial ammonia plant. The field test and the commercial ammonia plant will be located at the North Knobs site near Rawlins, Wyoming. During this demonstration test, two or more UCG modules will be operated simultaneously until one module is completely consumed and an additional module is brought on line. During this period, the average coal gasification rate will be between 500 and 1200 tons per day. A portion of the raw UCG product gas will be cleaned and converted into a synthesis gas, which will be used as feedstock to a 400--500 ton per day ammonia plant. The UCG facility will continue to operate subsequent to the test demonstration to provide feedstock for the commercial plant. The objective of the hydrologic site characterization program is to provide an accurate representation of the hydrologic environment within the area to be gasified. This information will aid in the placement and operation of the process wells in relation to the ground water source. 21 refs., 14 figs., 6 tabs.

  2. Rawlins UCG (underground coal gasification) Demonstration Project site characterization report

    SciTech Connect (OSTI)

    Not Available

    1989-04-01T23:59:59.000Z

    The US Department of Energy and Energy International, Inc. have entered into a Cooperative Agreement to conduct a cost-shared UCG field test demonstrating the operation of commercial scale underground coal gasification (UCG) on steeply dipping bed modules to provide synthesis gas for a small scale commercial ammonia plant. The field test and the commercial ammonia plant will be located at the North Knobs site near Rawlins, Wyoming. During this demonstration test, two or more UCG modules will be operated simultaneously until one module is completely consumed and an additional module is brought on line. During this period, the average coal gasification rate will be between 500 and 1200 tons per day. A portion of the raw UCG product gas will be cleaned and converted into a synthesis gas, which will be used as feedstock to a 400--500 ton per day ammonia plant. The UCG facility will continue to operate subsequent to the test demonstration to provide feedstock for the commercial plant. The objective of the geologic site characterization program is to provide a descriptive model that accurately represents the geologic environment of the coal resource that is to be gasified. This model is to be used as an aid in understanding the hydrology of the coal bearing sequence, as a framework for installation of the process wells and the subsequent exploitation of the coal resources. 3 figs., 3 tabs.

  3. Lawrence Livermore National Laboratory Underground Coal Gasification project

    SciTech Connect (OSTI)

    Thorsness, C.B.; Britten, J.A.

    1989-10-15T23:59:59.000Z

    The Lawrence Livermore National Laboratory (LLNL) has been actively developing Underground Coal Gasification (UCG) technology for 15 years. The goal of the project has been to develop a fundamental technological understanding of UCG and foster the commercialization of the process. In striving to achieve this goal the LLNL project has carried out laboratory experiments, developed mathematical models, actively participated in technology transfer programs, and conducted field test experiments. As a result of this work the Controlled Retracting Injection Point (CRIP) concept was developed which helps insure optimum performance of an underground gasifier in a flat seam, and provides a means to produce multiple gasification cavities. The LLNL field work culminated in the Rocky Mountain I field test in which a gasifier using the CRIP technology generated gas of a quality equal to that of surface gasifiers. This last test and others preceding it have demonstrated beyond any reasonable doubt, that UCG is technically feasible in moderately thick coal seams at modest depths. 2 refs., 2 tabs.

  4. Pyrolysis and gasification of coal at high temperatures

    SciTech Connect (OSTI)

    Zygourakis, K.

    1988-01-01T23:59:59.000Z

    Coals of different ranks will be pyrolyzed in a microscope hot-stage reactor using inert and reacting atmospheres. The macropore structure of the produced chars will be characterized using video microscopy and digital image processing techniques to obtain pore size distributions. Comparative studies will quantify the effect of pyrolysis conditions (heating rates, final heat treatment temperatures, particle size and inert or reacting atmosphere) on the pore structure of the devolatilized chars. The devolatilized chars will be gasified in the regime of strong intraparticle diffusional limitations using O{sub 2}/N{sub 2} and O{sub 2}/H{sub 2}O/N{sub 2}2 mixtures. Constant temperature and programmed-temperature experiments in a TGA will be used for these studies. Additional gasification experiments performed in the hot-stage reactor will be videotaped and selected images will be analyzed to obtain quantitative data on particle shrinkage and fragmentation. Discrete mathematical models will be developed and validated using the experimental gasification data.

  5. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect (OSTI)

    Archie Robertson

    2002-07-10T23:59:59.000Z

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the April 1--June 30, 2002 time period.

  6. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect (OSTI)

    Unknown

    2003-01-30T23:59:59.000Z

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the October 1--December 31, 2002 time period.

  7. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect (OSTI)

    Archie Robertson

    2003-07-23T23:59:59.000Z

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the April 1--June 30, 2003 time period.

  8. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect (OSTI)

    Archie Robertson

    2003-10-29T23:59:59.000Z

    Foster Wheeler Power Group, Inc. is working under US Department of Energy contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. This report describes the work performed during the July 1--September 30, 2003 time period.

  9. Pricetown I underground coal gasification field test: operations report

    SciTech Connect (OSTI)

    Agarwal, A.K.; Seabaugh, P.W.; Zielinski, R.E.

    1981-01-01T23:59:59.000Z

    An Underground Coal Gasification (UCG) field test in bituminous coal was successfully completed near Pricetown, West Virginia. The primary objective of this field test was to determine the viability of the linked vertical well (LVV) technology to recover the 900 foot deep, 6 foot thick coal seam. A methane rich product gas with an average heating value of approximately 250 Btu/SCF was produced at low air injection flow rates during the reverse combustion linkage phase. Heating value of the gas produced during the linkage enhancement phase was 221 Btu/SCF with air injection. The high methane formation has been attributed to the thermal and hydrocracking of tars and oils along with hydropyrolysis and hydrogasification of coal char. The high heating value of the gas was the combined effect of residence time, flow pattern, injection flow rate, injection pressure, and back pressure. During the gasification phase, a gas with an average heating value of 125 Btu/SCF was produced with only air injection, which resulted in an average energy production of 362 MMBtu/day.

  10. Pioneering Gasification Plants | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO Overview OCHCO Overview OCHCO OCHCOControlGuide to aEnergy LivingSystemPilot

  11. Steam gasification of carbon: Catalyst properties. Final report, September 15, 1988--October 31, 1992

    SciTech Connect (OSTI)

    Falconer, J.L.

    1993-01-10T23:59:59.000Z

    Coal gasification by steam is of critical importance in converting coal to gaseous products (CO, H{sub 2}, CO{sub 2}, CH{sub 4}) that can then be further converted to synthetic natural gas and higher hydrocarbon fuels. Alkali and alkaline earth metals (present as oxides) catalyze coal gasification reactions and cause them to occur at significantly lower temperatures. A more fundamental understanding of the mechanism of the steam gasification reaction and catalyst utilization may well lead to better production techniques, increased gasification rates, greater yields, and less waste. We are studying the gasification of carbon by steam in the presence of alkali and alkaline earth oxides, using carbonates as the starting materials. Carbon dioxide gasification (CO{sub 2} + C --> 2CO) has been studied in some detail recently, but much less has been done on the actual steam gasification reaction, which is the main thrust of our work. In particular, the form of the active catalyst compound during reaction is still questioned and the dependence of the concentration of active sites on reaction parameters is not known. Until recently, no measurements of active site concentrations during reaction had been made. We have recently used transient isotope tracing to determine active site concentration during CO{sub 2} gasification. We are investigating the mechanism and the concentration of active sites for steam gasification with transient isotopic tracing. For this technique, the reactant feed is switched from H{sub 2}0 to isotopically-labeled water at the same concentration and tow rate. We can then directly measure, at reaction the concentration of active catalytic sites, their kinetic rate constants, and the presence of more than one rate constant. This procedure allows us to obtain transient kinetic data without perturbing the steady-state surface reactions.

  12. Modeling and comparative assessment of municipal solid waste gasification for energy production

    SciTech Connect (OSTI)

    Arafat, Hassan A., E-mail: harafat@masdar.ac.ae; Jijakli, Kenan

    2013-08-15T23:59:59.000Z

    Highlights: • Study developed a methodology for the evaluation of gasification for MSW treatment. • Study was conducted comparatively for USA, UAE, and Thailand. • Study applies a thermodynamic model (Gibbs free energy minimization) using the Gasify software. • The energy efficiency of the process and the compatibility with different waste streams was studied. - Abstract: Gasification is the thermochemical conversion of organic feedstocks mainly into combustible syngas (CO and H{sub 2}) along with other constituents. It has been widely used to convert coal into gaseous energy carriers but only has been recently looked at as a process for producing energy from biomass. This study explores the potential of gasification for energy production and treatment of municipal solid waste (MSW). It relies on adapting the theory governing the chemistry and kinetics of the gasification process to the use of MSW as a feedstock to the process. It also relies on an equilibrium kinetics and thermodynamics solver tool (Gasify®) in the process of modeling gasification of MSW. The effect of process temperature variation on gasifying MSW was explored and the results were compared to incineration as an alternative to gasification of MSW. Also, the assessment was performed comparatively for gasification of MSW in the United Arab Emirates, USA, and Thailand, presenting a spectrum of socioeconomic settings with varying MSW compositions in order to explore the effect of MSW composition variance on the products of gasification. All in all, this study provides an insight into the potential of gasification for the treatment of MSW and as a waste to energy alternative to incineration.

  13. Peat gasification pilot plant program. Project 70105 quarterly report No. 2, September 1-November 30, 1981

    SciTech Connect (OSTI)

    Not Available

    1982-09-01T23:59:59.000Z

    The objective of this program is twofold: (1) to modify an existing pilot plant; and (2) to operate the pilot plant with peat to produce substitute natural gas (SNG). Activities include the design, procurement, and installation of peat drying, grinding, screening, and lockhopper feed systems. Equipment installed for the program complements the existing pilot plant facility. Drying, grinding, and screening equipment for peat was installed and operated during the previous reporting periods. Three gasification tests (PT-1 through PT-3) had also been conducted using the toluene slurry feed system. Installation of the lockhopper dry feed system was completed on schedule. Shakedown of the system has begun. Operation of the modified 400-ton storage and transport system was successfully demonstrated with peat containing 10% moisture. Preparations for Test PT-4 are currently underway. Data analyses for Test PT-2 were completed and are presented. The low-pressure Plexiglas unit was modified to investigate the use of a downflowing pneumatic feed system for the dryer bed. Initial testing was begun.

  14. Rocky Mountain 1: Underground coal gasification test, Hanna, Wyoming. Volume 1. Operations. Summary report

    SciTech Connect (OSTI)

    Not Available

    1989-03-01T23:59:59.000Z

    The Rocky Mountain 1 underground coal gasification (UCG) test was conducted near Hanna, Wyoming during the period January 1986 through March 1988. The report focuses on operations phases that included site selection, facility design, facility construction, well drilling, gasification and environmental monitoring. Two technologies were evaluated as separate modules: the Extended Linked Well (ELW) and the Controlled Retracting Injection Point (CRIP) processes. The test results, along with a discussion of the key test parameters and conclusions of the gasification phase, are provided. A bibliography and schematics are included.

  15. Fundamental investigations of underground coal gasification. Final report, March 1982-December 1986

    SciTech Connect (OSTI)

    Gunn, R.D.

    1987-08-01T23:59:59.000Z

    The report presents several mathematical models of underground coal-gasification processes. Through these models, a much better theoretical understanding of underground coal gasification becomes possible. Specific phenomena studied were the effects of high-amplitude pressure oscillation, reverse combustion, spontaneous ignition at high pressures, an analytical model of reverse-combustion channeling, an exploratory study of electrolinking, cavity-growth behavior, and a technical evaluation of the Forestburg underground coal-gasification field test at Forestburg, Alberta. This test is especially interesting because the site was escavated after completion of the experiment.

  16. Synthesis Gas Production by Rapid Solar Thermal Gasification of Corn Stover

    SciTech Connect (OSTI)

    Perkins, C. M.; Woodruff, B.; Andrews, L.; Lichty, P.; Lancaster, B.; Weimer, A. W.; Bingham, C.

    2008-03-01T23:59:59.000Z

    Biomass resources hold great promise as renewable fuel sources for the future, and there exists great interest in thermochemical methods of converting these resources into useful fuels. The novel approach taken by the authors uses concentrated solar energy to efficiently achieve temperatures where conversion and selectivity of gasification are high. Use of solar energy removes the need for a combustion fuel and upgrades the heating value of the biomass products. The syngas product of the gasification can be transformed into a variety of fuels useable with today?s infrastructure. Gasification in an aerosol reactor allows for rapid kinetics, allowing efficient utilization of the incident solar radiation and high solar efficiency.

  17. Integration of stripping of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1980-01-01T23:59:59.000Z

    In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

  18. Status of health and environmental research relative to coal gasification 1976 to the present

    SciTech Connect (OSTI)

    Wilzbach, K.E.; Reilly, C.A. Jr. (comps.)

    1982-10-01T23:59:59.000Z

    Health and environmental research relative to coal gasification conducted by Argonne National Laboratory, the Inhalation Toxicology Research Institute, and Oak Ridge National Laboratory under DOE sponsorship is summarized. The studies have focused on the chemical and toxicological characterization of materials from a range of process streams in five bench-scale, pilot-plant and industrial gasifiers. They also address ecological effects, industrial hygiene, environmental control technology performance, and risk assessment. Following an overview of coal gasification technology and related environmental concerns, integrated summaries of the studies and results in each area are presented and conclusions are drawn. Needed health and environmental research relative to coal gasification is identified.

  19. Fluidized-bed catalytic coal-gasification process. [US patent; pretreatment to minimize agglomeration

    DOE Patents [OSTI]

    Euker, C.A. Jr.; Wesselhoft, R.D.; Dunkleman, J.J.; Aquino, D.C.; Gouker, T.R.

    1981-09-14T23:59:59.000Z

    Coal or similar carbonaceous solids impregnated with gasification catalyst constituents are oxidized by contact with a gas containing between 2 vol % and 21 vol % oxygen at a temperature between 50 and 250/sup 0/C in an oxidation zone and the resultant oxidized, catalyst impregnated solids are then gasified in a fluidized bed gasification zone at an elevated pressure. The oxidation of the catalyst impregnated solids under these conditions insures that the bed density in the fluidized bed gasification zone will be relatively high even though the solids are gasified at elevated pressure and temperature.

  20. Mutagenic and toxic activity of environmental effluents from underground coal gasification experiments

    SciTech Connect (OSTI)

    Timourian, H.

    1982-05-01T23:59:59.000Z

    Using bacterial bioassays, the authors have screened for the presence of mutagens and toxins in extracts from groundwater, and in tar from product gas, at the Hoe Creek II and III in situ coal gasification sites. The sites exhibited different potential biological hazards, suggesting that different gasification processes may represent different human health concerns. It was found that mutagens are present in groundwater, they persist for at least 2 years after gasification has been terminated, and they show a change in activity with time, possibly in parallel with changes in chemical composition. The tar may represent a disposal problem, since it is mutagenic, but with a low level of activity.

  1. Assessment of underground coal gasification in bituminous coals: potential UCG products and markets. Final report, Phase I

    SciTech Connect (OSTI)

    None

    1982-01-31T23:59:59.000Z

    The following conclusions were drawn from the study: (1) The US will continue to require new sources of energy fuels and substitutes for petrochemical feedstocks into the foreseeable future. Most of this requirement will be met using coal. However, the cost of mining, transporting, cleaning, and preparing coal, disposing of ash or slag and scrubbing stack gases continues to rise; particularly, in the Eastern US where the need is greatest. UCG avoids these pitfalls and, as such, should be considered a viable alternative to the mining of deeper coals. (2) Of the two possible product gases LBG and MBG, MBG is the most versatile. (3) The most logical use for UCG product in the Eastern US is to generate power on-site using a combined-cycle or co-generation system. Either low or medium Btu gas (LBG or MBG) can be used. (4) UCG should be an option whenever surface gasification is considered; particularly, in areas where deeper, higher sulfur coal is located. (5) There are environmental and social benefits to use of UCG over surface gasification in the Eastern US. (6) A site could be chosen almost anywhere in the Illinois and Ohio area where amenable UCG coal has been determined due to the existence of existing transportation or transmission systems. (7) The technology needs to be demonstrated and the potential economic viability determined at a site in the East-North-Central US which has commercial quantities of amenable bituminous coal before utilities will show significant interest.

  2. Control of bed height in a fluidized bed gasification system

    DOE Patents [OSTI]

    Mehta, Gautam I. (Greensburg, PA); Rogers, Lynn M. (Export, PA)

    1983-12-20T23:59:59.000Z

    In a fluidized bed apparatus a method for controlling the height of the fdized bed, taking into account variations in the density of the bed. The method comprises taking simultaneous differential pressure measurements at different vertical elevations within the vessel, averaging the differential pressures, determining an average fluidized bed density, then periodically calculating a weighting factor. The weighting factor is used in the determination of the actual bed height which is used in controlling the fluidizing means.

  3. Gasification Systems 2013 Project Selections | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic2 OPAM Flash2011-12 OPAM RevisedFundingEnergyAPPLICATION OFGas

  4. The ENCOAL Mild Coal Gasification Project, A DOE Assessment

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2002-03-15T23:59:59.000Z

    This report is a post-project assessment of the ENCOAL{reg_sign} Mild Coal Gasification Project, which was selected under Round III of the U.S. Department of Energy (DOE) Clean Coal Technology (CCT) Demonstration Program. The CCT Demonstration Program is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of commercial-scale facilities. The ENCOAL{reg_sign} Corporation, a wholly-owned subsidiary of Bluegrass Coal Development Company (formerly SMC Mining Company), which is a subsidiary of Ziegler Coal Holding Company, submitted an application to the DOE in August 1989, soliciting joint funding of the project in the third round of the CCT Program. The project was selected by DOE in December 1989, and the Cooperative Agreement (CA) was approved in September 1990. Construction, commissioning, and start-up of the ENCOAL{reg_sign} mild coal gasification facility was completed in June 1992. In October 1994, ENCOAL{reg_sign} was granted a two-year extension of the CA with the DOE, that carried through to September 17, 1996. ENCOAL{reg_sign} was then granted a six-month, no-cost extension through March 17, 1997. Overall, DOE provided 50 percent of the total project cost of $90,664,000. ENCOAL{reg_sign} operated the 1,000-ton-per-day mild gasification demonstration plant at Triton Coal Company's Buckskin Mine near Gillette, Wyoming, for over four years. The process, using Liquids From Coal (LFC{trademark}) technology originally developed by SMC Mining Company and SGI International, utilizes low-sulfur Powder River Basin (PRB) coal to produce two new fuels, Process-Derived Fuel (PDF{trademark}) and Coal-Derived Liquids (CDL{trademark}). The products, as alternative fuel sources, are capable of significantly lowering current sulfur emissions at industrial and utility boiler sites throughout the nation thus reducing pollutants causing acid rain. In support of this overall objective, the following goals were established for the ENCOAL{reg_sign} Project: Provide sufficient quantity of products for full-scale test burns; Develop data for the design of future commercial plants; Demonstrate plant and process performance; Provide capital and O&M cost data; and Support future LFC{trademark} technology licensing efforts. Each of these goals has been met and exceeded. The plant has been in operation for nearly 5 years, during which the LFC{trademark} process has been demonstrated and refined. Fuels were made, successfully burned, and a commercial-scale plant is now under contract for design and construction.

  5. Refractory Materials based on Magnesia-Alumina Spinel for Improved Performance in Coal Gasification Environments

    SciTech Connect (OSTI)

    Hemrick, James Gordon [ORNL; Armstrong, Beth L [ORNL; Rodrigues-Schroer, Angela [Minteq International, Inc.; Colavito, [Minteq International, Inc.; Smith, Jeffrey D [ORNL; O'Hara, Kelley [University of Missouri, Rolla

    2013-01-01T23:59:59.000Z

    As part of a larger project to develop novel refractory systems and techniques to reduce energy consumption of refractory lined vessels, a team composed of Oak Ridge National Laboratory, refractory manufacturer Minteq International, Inc., and academic partner Missouri University of Science and Technology have developed new refractory materials and coating systems specifically for application in coal gasification environments. Materials were developed under this U.S. DOE funded project to address the need for innovative refractory compositions by developing MgO-Al2O3 spinel gunnable refractory compositions utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques. Work was conducted to develop and deploy these new materials and to develop and apply low cost coatings using a colloidal approach for protection against attack of the refractory brick by the serviced environment. Additionally, a light-weight back-up refractory system was developed to help offset the high thermal conductivity inherent in spinel materials. This paper discusses the efforts involved in the development of these materials, along with the laboratory testing and evaluation of these materials leading to relevant results achieved toward the reduction of chemical reactions and mechanical degradation by the service environment though compositional and processing modifications.

  6. Gasification of Low Ash Partially Composted Dairy Biomass with Enriched Air Mixture

    E-Print Network [OSTI]

    Thanapal, Siva Sankar

    2012-02-14T23:59:59.000Z

    within the bed increases with increase in oxygen concentration in the gasification medium. Also carbon dioxide concentration in the mixture increases with corresponding decrease in carbon monoxide with increase in oxygen concentration of the incoming...

  7. Production of Medium BTU Gas by In Situ Gasification of Texas Lignite 

    E-Print Network [OSTI]

    Edgar, T. F.

    1979-01-01T23:59:59.000Z

    The necessity of providing clean, combustible fuels for use in Gulf Coast industries is well established; one possible source of such a fuel is to perform in situ gasification of Texas lignite which lies below stripping depths. If oxygen (rather...

  8. Methodology for technology evaluation under uncertainty and its application in advanced coal gasification processes

    E-Print Network [OSTI]

    Gong, Bo, Ph. D. Massachusetts Institute of Technology

    2011-01-01T23:59:59.000Z

    Integrated gasification combined cycle (IGCC) technology has attracted interest as a cleaner alternative to conventional coal-fired power generation processes. While a number of pilot projects have been launched to ...

  9. Biomass characterization and reduced order modeling of mixed-feedstock gasification

    E-Print Network [OSTI]

    Chapman, Alex J. (Alex Jacob)

    2011-01-01T23:59:59.000Z

    There has been much effort to characterize and model coal for use in combustion and gasification. This work seeks to delineate the differences and similarities between biomass and coal, with emphasis on the state of the ...

  10. ASME PTC 47 - IGCC performance testing: Gasification island thermal performance testing

    SciTech Connect (OSTI)

    Mirolli, M.D.; Doering, E.L.

    1998-07-01T23:59:59.000Z

    In the past several years, Integrated Gasification Combined Cycle (IGCC) power plants have been introduced in a number of competitive markets. Most of the demonstration projects have been subsidized. However, as the technology is further developed, its versatility will lead to its application in a variety of market segments. This leads to the need of the user to evaluate the performance of the gasification process within the IGCC power plant through field testing. This paper deals with an approach to measuring the gasification island thermal performance. A thermal efficiency term based upon an input/output test approach is introduced. Measured parameters and pre-test planning are discussed. Computational procedures for determining the thermal efficiency of the gasification island are described including an uncertainty analysis for the performance test.

  11. Production of Medium BTU Gas by In Situ Gasification of Texas Lignite

    E-Print Network [OSTI]

    Edgar, T. F.

    1979-01-01T23:59:59.000Z

    The necessity of providing clean, combustible fuels for use in Gulf Coast industries is well established; one possible source of such a fuel is to perform in situ gasification of Texas lignite which lies below stripping depths. If oxygen (rather...

  12. Recent regulatory experience of low-Btu coal gasification. Volume III. Supporting case studies

    SciTech Connect (OSTI)

    Ackerman, E.; Hart, D.; Lethi, M.; Park, W.; Rifkin, S.

    1980-02-01T23:59:59.000Z

    The MITRE Corporation conducted a five-month study for the Office of Resource Applications in the Department of Energy on the regulatory requirements of low-Btu coal gasification. During this study, MITRE interviewed representatives of five current low-Btu coal gasification projects and regulatory agencies in five states. From these interviews, MITRE has sought the experience of current low-Btu coal gasification users in order to recommend actions to improve the regulatory process. This report is the third of three volumes. It contains the results of interviews conducted for each of the case studies. Volume 1 of the report contains the analysis of the case studies and recommendations to potential industrial users of low-Btu coal gasification. Volume 2 contains recommendations to regulatory agencies.

  13. adiabatic fixed-bed gasification: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    TxSpace Summary: was obtained at 700?C (Figure 4.) Elbaba et al. (2011) utilized waste tires for hydrogen production using pyrolysis-gasification with nickelcerium catalyst. The...

  14. 10January 1998 Small-Scale Gasification-Based Biomass Power Generation

    E-Print Network [OSTI]

    are the technologies of choice today for gasification-based power generationfrom biomass(Fig. I). Fuel cells and micro-gas turbines coupled with biomassgasifiers will offer considerably higher efficiencies at small

  15. Thermochemical Ethanol via Direct Gasification and Mixed Alcohol Synthesis of Lignocellulosic Biomass

    SciTech Connect (OSTI)

    Dutta, A.; Phillips, S. D.

    2009-07-01T23:59:59.000Z

    This report evaluates process design and technoeconomic criteria for a direct gasification process for conversion of biomass to ethanol. Follow-up to NREL/TP-510-41168.

  16. EA-1219: Hoe Creek Underground Coal Gasification Test Site Remediation, Campbell County, Wyoming

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts for the proposed Hoe Creek Underground Coal Gasification Test Site Remediation that would be performed at the Hoe Creek site in Campbell County, Wyoming.

  17. Chemical Looping Gasification for Hydrogen Enhanced Syngas Production with In-Situ CO2 Capture

    SciTech Connect (OSTI)

    Kathe, Mandar; Xu, Dikai; Hsieh, Tien-Lin; Simpson, James; Statnick, Robert; Tong, Andrew; Fan, Liang-Shih

    2014-12-31T23:59:59.000Z

    This document is the final report for the project titled “Chemical Looping Gasification for Hydrogen Enhanced Syngas Production with In-Situ CO2 Capture” under award number FE0012136 for the performance period 10/01/2013 to 12/31/2014.This project investigates the novel Ohio State chemical looping gasification technology for high efficiency, cost efficiency coal gasification for IGCC and methanol production application. The project developed an optimized oxygen carrier composition, demonstrated the feasibility of the concept and completed cold-flow model studies. WorleyParsons completed a techno-economic analysis which showed that for a coal only feed with carbon capture, the OSU CLG technology reduced the methanol required selling price by 21%, lowered the capital costs by 28%, increased coal consumption efficiency by 14%. Further, using the Ohio State Chemical Looping Gasification technology resulted in a methanol required selling price which was lower than the reference non-capture case.

  18. Underground coal gasification field experiment in the high-dipping coal seams

    SciTech Connect (OSTI)

    Yang, L.H.; Liu, S.Q.; Yu, L.; Zhang, W. [China University of Mining & Technology, Xuzhou (China). College of Resources & Geoscience

    2009-07-01T23:59:59.000Z

    In this article the experimental conditions and process of the underground gasification in the Woniushan Mine, Xuzhou, Jiangsu Province are introduced, and the experimental results are analyzed. By adopting the new method of long-channel, big-section, and two-stage underground coal gasification, the daily gas production reaches about 36,000 m{sup 3}, with the maximum output of 103,700 m{sup 3}. The daily average heating value of air gas is 5.04 MJ/m{sup 3}, with 13.57 MJ/m{sup 3} for water gas. In combustible compositions of water gas, H{sub 2} contents stand at over 50%, with both CO and CH{sub 4} contents over 6%. Experimental results show that the counter gasification can form new temperature conditions and increase the gasification efficiency of coal seams.

  19. Hanna, Wyoming underground coal gasification data base. Volume 1. General information and executive summary

    SciTech Connect (OSTI)

    Bartke, T.C.; Fischer, D.D.; King, S.B.; Boyd, R.M.; Humphrey, A.E.

    1985-08-01T23:59:59.000Z

    This report is part of a seven-volume series on the Hanna, Wyoming, underground coal gasification field tests. Volume 1 is a summary of the project and each of Volumes 2 through 6 describes a particular test. Volume 7 is a compilation. This report covers: (1) history of underground coal gasification leading to the Hanna tests; (2) area characteristics (basic meteorological and socioeconomic data); (3) site selection history; (4) site characteristics; (5) permitting; and (6) executive summary. 5 figs., 15 tabs.

  20. Summary report: Trace substance emissions from a coal-fired gasification plant

    SciTech Connect (OSTI)

    Williams, A.; Wetherold, B.; Maxwell, D.

    1996-10-16T23:59:59.000Z

    The U.S. Department of Energy (DOE), the Electric Power Research Institute (EPRI), and Louisiana Gasification Technology Inc. (LGTI) sponsored field sampling and analyses to characterize emissions of trace substances from LGTI`s integrated gasification combined cycle (IGCC) power plant at Plaquemine, Louisiana. The results indicate that emissions from the LGTI facility were quite low, often in the ppb levels, and comparable to a well-controlled pulverized coal-fired power plant.

  1. Fossil fuel gasification technical evaluation services. Topical report 1978-80

    SciTech Connect (OSTI)

    Detman, R.F.

    1982-12-30T23:59:59.000Z

    The Exxon, Mountain Fuel, Cities Service/Rockwell, Westinghouse, BGC slagging Lurgi and Peatgas processes for fossil fuel gasification were evaluated. The Lurgi and HYGAS processes had been evaluated in earlier studies. For producing SNG from coal, only the Westinghouse conceptual design appeared competitive with HYGAS on eastern coal. All coal gasification processes were competitive with or better than Lurgi on eastern coal. The Mountain Fuel process was more costly than Lurgi or HYGAS on a western coal.

  2. Scale-up of mild gasification to a process development unit. Quarterly report, May 21--August 20, 1993

    SciTech Connect (OSTI)

    Campbell, J.A.L.; Carty, R.H.; Foster, H.

    1993-09-01T23:59:59.000Z

    The work performed during the seventh quarterly reporting period on the research program, ``Scale-up of Mild Gasification to a Process Development Unit`` is presented in this report. The overall objective of this project is to develop the IGT Mild-Gasification (MILDGAS) process for near-term commercialization. The specific objectives of the program are to: (1) design, construct, and operate a 24-tons/day adiabatic process development unit (PDU) to obtain process performance data suitable for further design scaleup. (2) Obtain large batches of coal-derived co-products for industrial evaluation. (3) Prepare a detailed design of a demonstration unit. And (4) develop technical and economic plans for commercialization of the MILDGAS process. The MILDGAS process is a continuous closed system for producing liquid and solid (char) co-products at mild operating conditions up to 50 psig and 1300{degree}F. It is capable of processing a wide range of both eastern caking and western noncaking coals. The 1 ton/hr PDU facility is comprised of a 2.5-ft ID adiabatic gasifier for the production of gases, coal liquids, and char; a thermal cracker for upgrading of the coal liquids; a three-stage condensation train to condense and store the liquid products; and coal feeding and char handling equipment. The facility will also incorporate support equipment for environmentally acceptable disposal of process waste.

  3. Revised users manual, Pulverized Coal Gasification or Combustion: 2-dimensional (87-PCGC-2): Final report, Volume 2. [87-PCGC-2

    SciTech Connect (OSTI)

    Smith, P.J.; Smoot, L.D.; Brewster, B.S.

    1987-12-01T23:59:59.000Z

    A two-dimensional, steady-state model for describing a variety of reactive and non-reactive flows, including pulverized coal combustion and gasification, is presented. Recent code revisions and additions are described. The model, referred to as 87-PCGC-2, is applicable to cylindrical axi-symmetric systems. Turbulence is accounted for in both the fluid mechanics equations and the combustion scheme. Radiation from gases, walls, and particles is taken into account using either a flux method or discrete ordinates method. The particle phase is modeled in a Lagrangian framework, such that mean paths of particle groups are followed. Several multi-step coal devolatilization schemes are included along with a heterogeneous reaction scheme that allows for both diffusion and chemical reaction. Major gas-phase reactions are modeled assuming local instantaneous equilibrium, and thus the reaction rates are limited by the turbulent rate mixing. A NO/sub x/ finite rate chemistry submodel is included which integrates chemical kinetics and the statistics of the turbulence. The gas phase is described by elliptic partial differential equations that are solved by an iterative line-by-line technique. Under-relaxation is used to achieve numerical stability. The generalized nature of the model allows for calculation of isothermal fluid mechanicsgaseous combustion, droplet combustion, particulate combustion and various mixtures of the above, including combustion of coal-water and coal-oil slurries. Both combustion and gasification environments are permissible. User information and theory are presented, along with sample problems. 106 refs.

  4. Comparative assessment of municipal sewage sludge incineration, gasification and pyrolysis for a sustainable sludge-to-energy management in Greece

    SciTech Connect (OSTI)

    Samolada, M.C. [Dept. Secretariat of Environmental and Urban Planning – Decentralized Area Macedonian Thrace, Taki Oikonomidi 1, 54008 Thessaloniki (Greece); Zabaniotou, A.A., E-mail: azampani@auth.gr [Aristotle University of Thessaloniki, Dept. of Chemical Engineering, University Box 455, University Campus, 541 24 Thessaloniki (Greece)

    2014-02-15T23:59:59.000Z

    Highlights: • The high output of MSS highlights the need for alternative routes of valorization. • Evaluation of 3 sludge-to-energy valorisation methods through SWOT analysis. • Pyrolysis is an energy and material recovery process resulting to ‘zero waste’. • Identification of challenges and barriers for MSS pyrolysis in Greece was investigated. • Adopters of pyrolysis systems face the challenge of finding new product markets. - Abstract: For a sustainable municipal sewage sludge management, not only the available technology, but also other parameters, such as policy regulations and socio-economic issues should be taken in account. In this study, the current status of both European and Greek Legislation on waste management, with a special insight in municipal sewage sludge, is presented. A SWOT analysis was further developed for comparison of pyrolysis with incineration and gasification and results are presented. Pyrolysis seems to be the optimal thermochemical treatment option compared to incineration and gasification. Sewage sludge pyrolysis is favorable for energy savings, material recovery and high added materials production, providing a ‘zero waste’ solution. Finally, identification of challenges and barriers for sewage sludge pyrolysis deployment in Greece was investigated.

  5. Arco's research and development efforts in underground coal gasification

    SciTech Connect (OSTI)

    Bell, G.J.; Bailey, D.W.; Brandenburg, C.F.

    1983-01-01T23:59:59.000Z

    Arco has studied underground coal gasification (UCG) since the mid-1970's in an attempt to advance the technology. This paper is a review of past and present UCG research and development efforts, starting with Arco's Rocky Hill No. 1 test. Although this first experiment gave Arco invaluable experience for conducting UCG in the deep, wet, thick coal resources of the Powder River Basin in Wyoming, many formidable questions remain to be addressed with the operation of a larger-scale, multi-well test. Unresolved issues include such items as site selection, well design, well linking, overburden subsidence, ground water protection, surface treatment of product gas, and the interaction of simultaneously operating modules.

  6. Encoal mild coal gasification project: Commercial plant feasibility study

    SciTech Connect (OSTI)

    NONE

    1997-07-01T23:59:59.000Z

    In order to determine the viability of any Liquids from Coal (LFC) commercial venture, TEK-KOL and its partner, Mitsubishi Heavy Industries (MHI), have put together a technical and economic feasibility study for a commercial-size LFC Plant located at Zeigler Coal Holding Company`s North Rochelle Mine site. This resulting document, the ENCOAL Mild Coal Gasification Plant: Commercial Plant Feasibility Study, includes basic plant design, capital estimates, market assessment for coproducts, operating cost assessments, and overall financial evaluation for a generic Powder River Basin based plant. This document and format closely resembles a typical Phase II study as assembled by the TEK-KOL Partnership to evaluate potential sites for LFC commercial facilities around the world.

  7. Method for gasification of deep, thin coal seams

    DOE Patents [OSTI]

    Gregg, David W. (Moraga, CA)

    1982-01-01T23:59:59.000Z

    A method of gasification of coal in deep, thin seams by using controlled bending subsidence to confine gas flow to a region close to the unconsumed coal face. The injection point is moved sequentially around the perimeter of a coal removal area from a production well to sweep out the area to cause the controlled bending subsidence. The injection holes are drilled vertically into the coal seam through the overburden or horizontally into the seam from an exposed coal face. The method is particularly applicable to deep, thin seams found in the eastern United States and at abandoned strip mines where thin seams were surface mined into a hillside or down a modest dip until the overburden became too thick for further mining.

  8. Method for gasification of deep, thin coal seams. [DOE patent

    DOE Patents [OSTI]

    Gregg, D.W.

    1980-08-29T23:59:59.000Z

    A method of gasification of coal in deep, thin seams by using controlled bending subsidence to confine gas flow to a region close to the unconsumed coal face is given. The injection point is moved sequentially around the perimeter of a coal removal area from a production well to sweep out the area to cause the controlled bending subsidence. The injection holes are drilled vertically into the coal seam through the overburden or horizontally into the seam from an exposed coal face. The method is particularly applicable to deep, thin seams found in the eastern United States and at abandoned strip mines where thin seams were surface mined into a hillside or down a modest dip until the overburden became too thick for further mining.

  9. Gasification CFD Modeling for Advanced Power Plant Simulations

    SciTech Connect (OSTI)

    Zitney, S.E.; Guenther, C.P.

    2005-09-01T23:59:59.000Z

    In this paper we have described recent progress on developing CFD models for two commercial-scale gasifiers, including a two-stage, coal slurry-fed, oxygen-blown, pressurized, entrained-flow gasifier and a scaled-up design of the PSDF transport gasifier. Also highlighted was NETL’s Advanced Process Engineering Co-Simulator for coupling high-fidelity equipment models with process simulation for the design, analysis, and optimization of advanced power plants. Using APECS, we have coupled the entrained-flow gasifier CFD model into a coal-fired, gasification-based FutureGen power and hydrogen production plant. The results for the FutureGen co-simulation illustrate how the APECS technology can help engineers better understand and optimize gasifier fluid dynamics and related phenomena that impact overall power plant performance.

  10. Proceedings of the ninth annual underground coal gasification symposium

    SciTech Connect (OSTI)

    Wieber, P.R.; Martin, J.W.; Byrer, C.W. (eds.)

    1983-12-01T23:59:59.000Z

    The Ninth Underground Coal Gasification Symposium was held August 7 to 10, 1983 at the Indian Lakes Resort and Conference Center in Bloomingdale, Illinois. Over one-hundred attendees from industry, academia, National Laboratories, State Government, and the US Government participated in the exchange of ideas, results and future research plans. Representatives from six countries including France, Belgium, United Kingdom, The Netherlands, West Germany, and Brazil also participated by presenting papers. Fifty papers were presented and discussed in four formal sessions and two informal poster sessions. The presentations described current and future field testing plans, interpretation of field test data, environmental research, laboratory studies, modeling, and economics. All papers were processed for inclusion in the Energy Data Base.

  11. Encoal mild coal gasification project: Final design modifications report

    SciTech Connect (OSTI)

    NONE

    1997-07-01T23:59:59.000Z

    The design, construction and operation Phases of the Encoal Mild Coal Gasification Project have been completed. The plant, designed to process 1,000 ton/day of subbituminous Power River Basin (PRB) low-sulfur coal feed and to produce two environmentally friendly products, a solid fuel and a liquid fuel, has been operational for nearly five years. The solid product, Process Derived Fuel (PDF), is a stable, low-sulfur, high-Btu fuel similar in composition and handling properties to bituminous coal. The liquid product, Coal Derived Liquid (CDL), is a heavy, low-sulfur, liquid fuel similar in properties to heavy industrial fuel oil. Opportunities for upgrading the CDL to higher value chemicals and fuels have been identified. Significant quantities of both PDF and CDL have been delivered and successfully burned in utility and industrial boilers. A summary of the Project is given.

  12. Review of underground coal gasification field experiments at Hoe Creek

    SciTech Connect (OSTI)

    Thorsness, C.B.; Creighton, J.R.

    1983-01-01T23:59:59.000Z

    LLNL has conducted three underground coal gasification experiments at the Hoe Creek site near Gillette, WY. Three different linking methods were used: explosive fracturing, reverse burning and directional drilling. Air was injected on all three experiments and a steam/oxygen mixture during 2 days of the second and most of the third experiment. Comparison of results show that the linking method didn't influence gas quality. The heat of combustion of the product gas was higher with steam/oxygen injection, mainly because of reduced inert diluent. Gas quality was generally independent of other operating parameters, but declined from its initial value over a period of time. This was due to heat loss to the wet overburden and extensive roof collapse in the second and third experiments.

  13. Review of underground coal gasification field experiments at Hoe Creek

    SciTech Connect (OSTI)

    Thorsness, C.B.; Creighton, J.R.

    1983-01-01T23:59:59.000Z

    In three underground coal gasification experiments at the Hoe Creek site near Gillette, WY, LLNL applied three different linking methods: explosive fracture, reverse burning, and directional drilling. Air was injected in all three experiments; a steam/oxygen mixture, during 2 days of the second and most of the third experiment. Comparison of results show that the type of linking method did not influence gas quality. The heat of combustion of the product gas was higher with steam/oxygen injection, mainly because of reduced inert diluent. Gas quality was generally independent of other operating parameters but declined from its initial value over a period of time because of heat loss to the wet overburden and extensive roof collapse in the second and third experiments.

  14. In-situ coal gasification: a new technology

    SciTech Connect (OSTI)

    Agarwal, A.K.; Zielinski, R.E.; Seabaugh, P.W.; Liberatore, A.J.; Martin, J.W.

    1982-01-01T23:59:59.000Z

    While the technology for underground gasification of Western US subbituminous coals is advancing through efforts at the Hanna and Hoe Creek test sites, the development of an Eastern bituminous coal technology has only begun. The Pricetown 1 field test proved the feasibility of gasifying the thin-seam, swelling bituminous coal resources. Key issues remaining to be demonstrated include an effective linkage method, means of controlling gas production and composition, and scale-up. A major field-test program could entail three phases: (1) resolving the linkage and process control problems in the Appalachian basin, (2) assessing the technology in the untested Illinois basin, and (3) testing a multimodule commercial-scale prototype.

  15. Effect of steam partial pressure on gasification rate and gas composition of product gas from catalytic steam gasification of HyperCoal

    SciTech Connect (OSTI)

    Atul Sharma; Ikuo Saito; Toshimasa Takanohashi [National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan). Advanced Fuel Group

    2009-09-15T23:59:59.000Z

    HyperCoal was produced from coal by a solvent extraction method. The effect of the partial pressure of steam on the gasification rate and gas composition at temperatures of 600, 650, 700, and 750{sup o}C was examined. The gasification rate decreased with decreasing steam partial pressure. The reaction order with respect to steam partial pressure was between 0.2 and 0.5. The activation energy for the K{sub 2}CO{sub 3}-catalyzed HyperCoal gasification was independent of the steam partial pressure and was about 108 kJ/mol. The gas composition changed with steam partial pressure and H{sub 2} and CO{sub 2} decreased and CO increased with decreasing steam partial pressure. By changing the partial pressure of the steam, the H{sub 2}/CO ratio of the synthesis gas can be controlled. 18 refs., 7 figs., 2 tabs.

  16. Catalytic gasification of bagasse for the production of methanol

    SciTech Connect (OSTI)

    Baker, E.G.; Brown, M.D.; Robertus, R.J.

    1985-10-01T23:59:59.000Z

    The purpose of the study was to evaluate the technical and economic feasibility of catalytic gasification of bagasse to produce methanol. In previous studies, a catalytic steam gasification process was developed which converted wood to methanol synthesis gas in one step using nickel based catalysts in a fluid-bed gasifier. Tests in a nominal 1 ton/day process development unit (PDU) gasifier with these same catalysts showed bagasse to be a good feedstock for fluid-bed gasifiers, but the catalysts deactivated quite rapidly in the presence of bagasse. Laboratory catalyst screening tests showed K/sub 2/CO/sub 3/ doped on the bagasse to be a promising catalyst for converting bagasse to methanol synthesis gas. PDU tests with 10 wt % K/sub 2/CO/sub 3/ doped on bagasse showed the technical feasibility of this type of catalyst on a larger scale. A high quality synthesis gas was produced and carbon conversion to gas was high. The gasifier was successfully operated without forming agglomerates of catalyst, ash, and char in the gasifier. There was no loss of activity throughout the runs because catalysts is continually added with the bagasse. Laboratory tests showed about 80% of the potassium carbonate could be recovered and recycled with a simple water wash. An economic evaluation of the process for converting bagasse to methanol showed the required selling price of methanol to be significantly higher than the current market price of methanol. Several factors make this current evaluaton using bagasse as a feedstock less favorable: (1) capital costs are higher due to inflation and some extra costs required to use bagasse, (2) smaller plant sizes were considered so economies of scale are lost, and (3) the market price of methanol in the US has fallen 44% in the last six months. 24 refs., 14 figs., 16 tabs.

  17. DEVELOPMENT OF PRESSURIZED CIRCULATING FLUIDIZED BED PARTIAL GASIFICATION MODULE (PGM)

    SciTech Connect (OSTI)

    Archie Robertson

    2004-07-01T23:59:59.000Z

    Foster Wheeler Power Group, Inc. is working under US Department of Energy Contract No. DE-FC26-00NT40972 to develop a partial gasification module (PGM) that represents a critical element of several potential coal-fired Vision 21 plants. When utilized for electrical power generation, these plants will operate with efficiencies greater than 60% and produce near zero emissions of traditional stack gas pollutants. The new process partially gasifies coal at elevated pressure producing a coal-derived syngas and a char residue. The syngas can be used to fuel the most advanced power producing equipment such as solid oxide fuel cells or gas turbines, or processed to produce clean liquid fuels or chemicals for industrial users. The char residue is not wasted; it can also be used to generate electricity by fueling boilers that drive the most advanced ultra-supercritical pressure steam turbines. The amount of syngas and char produced by the PGM can be tailored to fit the production objectives of the overall plant, i.e., power generation, clean liquid fuel production, chemicals production, etc. Hence, PGM is a robust building bock that offers all the advantages of coal gasification but in a more user-friendly form; it is also fuel flexible in that it can use alternative fuels such as biomass, sewerage sludge, etc. Under this contract a series of pilot plant tests are being conducted to ascertain PGM performance with a variety of fuels. The performance and economics of a PGM based plant designed for the co-production of hydrogen and electricity will also be determined. This report describes the work performed during the April-June 30, 2004 time period.

  18. LLNL Underground Coal Gasification Project annual report - fiscal year 1984

    SciTech Connect (OSTI)

    Stephens, D.R.; O'Neal, E.M. (eds.)

    1985-06-15T23:59:59.000Z

    The Laboratory has been conducting an interdisciplinary underground coal gasification program since 1974 under the sponsorship of DOE and its predecessors. We completed three UCG tests at the Hoe Creek site near Gillette, Wyoming, during the period 1975 to 1979. Five small field experiments, the large-block tests, were completed from 1981 to 1982 at the exposed coal face in the WIDCO coal mine near Centralia, Washington. A larger test at the same location, the partial-seam CRIP test, was completed during fiscal year 1984. In conjunction with the DOE and an industrial group lead by the Gas Research Institute, we have prepared a preliminary design for a large-scale test at the WIDCO site. The planned test features dual injection and production wells, module interaction, and consumption of 20,000 tons of coal during a hundred-day steam-oxygen gasification. During fiscal year 1984, we documented the large-block excavations. The cavities were elongated, the cavity cross sections were elliptical, and the cavities contained ash and slag at the bottom, char and dried coal above that, and a void at the top. The results from the large-block tests provided enough data to allow us to construct a composite model, CAVSM. Preliminary results from the model agree well with the product-gas chemistry and cavity shape observed in the large-block tests. Other models and techniques developed during the year include a transient, moving-front code, a two-dimensional, reactive-flow code using the method of lines, and a wall-recession-rate model. In addition, we measured the rate of methane decomposition in the hot char bed and developed an engineering rate expression to estimate the magnitude of the methane-decomposition reaction. 16 refs., 30 figs., 1 tab.

  19. Wabash River Coal Gasification Repowering Project. Topical report, July 1992--December 1993

    SciTech Connect (OSTI)

    Not Available

    1994-01-01T23:59:59.000Z

    The Wabash River Coal Gasification Repowering Project (WRCGRP, or Wabash Project) is a joint venture of Destec Energy, Inc. of Houston, Texas and PSI Energy, Inc. of Plainfield, Indiana, who will jointly repower an existing 1950 vintage coal-fired steam generating plant with coal gasification combined cycle technology. The Project is located in West Terre Haute, Indiana at PSI`s existing Wabash River Generating Station. The Project will process locally-mined Indiana high-sulfur coal to produce 262 megawatts of electricity. PSI and Destec are participating in the Department of Energy Clean Coal Technology Program to demonstrate coal gasification repowering of an existing generating unit affected by the Clean Air Act Amendments. As a Clean Coal Round IV selection, the project will demonstrate integration of an existing PSI steam turbine generator and auxiliaries, a new combustion turbine generator, heat recovery steam generator tandem, and a coal gasification facility to achieve improved efficiency, reduced emissions, and reduced installation costs. Upon completion in 1995, the Project will not only represent the largest coal gasification combined cycle power plant in the United States, but will also emit lower emissions than other high sulfur coal-fired power plants and will result in a heat rate improvement of approximately 20% over the existing plant configuration. As of the end of December 1993, construction work is approximately 20% complete for the gasification portion of the Project and 25% complete for the power generation portion.

  20. SPINEL-BASED REFRACTORIES FOR IMPROVED PERFORMANCE IN COAL GASIFICATION ENVIRONMENTS

    SciTech Connect (OSTI)

    Hemrick, James Gordon [ORNL; Armstrong, Beth L [ORNL; Rodrigues-Schroer, Angela [Minteq International, Inc.; Colavito, [Minteq International, Inc.; Smith, Jeffrey D [ORNL; O'Hara, Kelley [University of Missouri, Rolla

    2013-01-01T23:59:59.000Z

    Oak Ridge National Laboratory, in collaboration with refractory manufacturer Minteq International, Inc., academic partner Missouri University of Science and Technology and refractory end users have developed novel refractory systems and techniques to reduce energy consumption of refractory lined vessels. The objective of this U.S. DOE funded project was to address the need for innovative refractory compositions by developing MgO-Al 2O3 spinel gunnable refractory compositions utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques. Materials have been developed specifically for coal gasification environments and work has been performed to develop and apply low cost coatings using a colloidal approach for protection against attack of the refractory brick by the service environment and to develop a light-weight back-up refractory system to help offset the high thermal conductivity inherent in spinel materials. This paper discusses the systematic development of these materials, laboratory testing and evaluation of these materials, and relevant results achieved toward the reduction of chemical reactions and mechanical degradation by the service environment though compositional and processing modifications.

  1. DEVELOPMENT OF NOVEL SPINEL REFRACTORIES FOR USE IN COAL GASIFICATION ENVIRONMENTS

    SciTech Connect (OSTI)

    Hemrick, James Gordon [ORNL; Armstrong, Beth L [ORNL; Rodrigues-Schroer, Angela [Minteq International, Inc.; Colavito, [Minteq International, Inc.; Smith, Jeffrey D [ORNL; O'Hara, Kelley [University of Missouri, Rolla

    2011-01-01T23:59:59.000Z

    Work has been performed by Oak Ridge National Laboratory (ORNL), in collaboration with industrial refractory manufacturer (Minteq International, Inc.), academic research partner (Missouri University of Science and Technology) and end users to employ novel refractory systems and techniques to reduce energy consumption of refractory lined vessels found in industries such as aluminum, chemical, glass, and pulp and paper. The objective of the project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al 2O3 spinel structured unshaped refractory compositions (castables, gunnables, shotcretes, etc) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques. As part of the four-year project funded by the U.S. Department of Energy (DOE), materials have been developed specifically for coal gasification environments. Additionally, work has been performed to develop and apply low cost coatings using a colloidal approach for protection against corrosion attack of the refractory brick and to develop a light-weight back-up refractory system to help offset the high thermal conductivity inherent in spinel materials. This paper discusses the development of these materials, along with preliminary results achieved toward the reduction of chemical reactions and mechanical degradation by the service environment.

  2. NOVEL COMPOSITE MEMBRANES FOR HYDROGEN SEPARATION IN GASIFICATION PROCESSES IN VISION 21 ENERGY PLANTS

    SciTech Connect (OSTI)

    Michael Schwartz

    2004-12-01T23:59:59.000Z

    This report describes the work performed, accomplishments and conclusion obtained from the project entitled ''Novel Composite Membranes for Hydrogen Separation in Gasification Processes in Vision 21 Energy Plants'' under the United States Department of Energy Contract DE-FC26-01NT40973. ITN Energy Systems was the prime contractor. Team members included: the Idaho National Engineering and Environmental Laboratory; Nexant Consulting; Argonne National Laboratory and Praxair. The objective of the program was to develop a novel composite membrane structure for hydrogen separation as a key technology module within the future ''Vision 21'' fossil fuel plants. The separation technology module is targeted for use within the gasification module of the ''Vision 21'' fossil fuel plant. The high performance and low-cost manufacturing of the proposed technology will benefit the deployment of ''Vision 21'' fossil fuel plant processes by improving the energy efficiency, flexibility and environmental performance of these plants. Of particular importance is that this technology will also produce a stream of pure carbon dioxide. This allows facile sequestration or other use of this greenhouse gas. These features will benefit the U.S. in allowing for the continued use of domestic fossil fuels in a more energy efficient and environmentally acceptable manner. The program developed and evaluated composite membranes and catalysts for hydrogen separation. Components of the monolithic modules were fabricated by plasma spray processing. The engineering and economic characteristics of the proposed Ion Conducting Ceramic Membrane (ICCM) approach, including system integration issues, were also assessed. This resulted in a comprehensive evaluation of the technical and economic feasibility of integration schemes of ICCM hydrogen separation technology within Vision 21 fossil fuel plants. Several results and conclusion were obtained during this program. In the area of materials synthesis, novel pyrochlore-based proton conductors were identified, synthesized and characterized. They exhibited conductivity as high as 0.03 S/cm at 900 C. Long-term stability under CO{sub 2} and H{sub 2} atmospheres was also demonstrated. In the area of membrane fabrication by plasma spray processing, the initial results showed that the pyrochlore materials could be processed in a spray torch. Although leak-tight membranes were obtained, cracking, most likely due to differences in thermal expansion, remained a problem. More modeling and experimental work can be used to solve this problem. Finally the techno-economic analyses showed that the ITN ICCM approach for separating H{sub 2} is comparable to conventional pressure swing adsorption (PSA) technology in efficiency and economics. Enhanced membrane flux and lower operating temperatures may make the ICCM approach superior to PSA.

  3. [Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion]. Quarterly technical progress report, October 1--December 31, 1993

    SciTech Connect (OSTI)

    Not Available

    1993-12-31T23:59:59.000Z

    This quarterly technical progress report summarizes work completed during the Second Quarter of the Second Budget Period, October 1 through December 31, 1993, under the Department of Energy (DOE) Cooperative Agreement No. DE-FC21-90MC25140 entitled ``Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.`` The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scaleup of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the existing Transport Reactor gas source and Hot Gas Cleanup Units: (1) Carbonizer/pressurized circulating fluidized bed gas source; (2) hot gas cleanup units to mate to all gas streams; (3) combustion gas turbine; (4) fuel cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF).

  4. Modeling of the coal gasification processes in a hybrid plasma torch

    SciTech Connect (OSTI)

    Matveev, I.B.; Serbin, S.I. [Applied Plasma Technology, Mclean, VA (USA)

    2007-12-15T23:59:59.000Z

    The major advantages of plasma treatment systems are cost effectiveness and technical efficiency. A new efficient electrodeless 1-MW hybrid plasma torch for waste disposal and coal gasification is proposed. This product merges several solutions such as the known inductive-type plasma torch, innovative reverse-vortex (RV) reactor and the recently developed nonequilibrium plasma pilot and plasma chemical reactor. With the use of the computational-fluid-dynamics-computational method, preliminary 3-D calculations of heat exchange in a 1-MW plasma generator operating with direct vortex and RV have been conducted at the air flow rate of 100 g/s. For the investigated mode and designed parameters, reduction of the total wall heat transfer for the reverse scheme is about 65 kW, which corresponds to an increase of the plasma generator efficiency by approximately 6.5%. This new hybrid plasma torch operates as a multimode, high power plasma system with a wide range of plasma feedstock gases and turn down ratio, and offers convenient and simultaneous feeding of several additional reagents into the discharge zone.

  5. Characterizing and modeling combustion of mild-gasification chars in pressurized fluidized beds

    SciTech Connect (OSTI)

    Daw, C.S.

    1993-03-01T23:59:59.000Z

    Performance estimates for the UCC2, IGTP1, and IGTP2 chars were made for a typical utility PFBC boiler having nominal characteristics similar to those of the American Electric Power 75 MW(e) Tidd PFBC demonstration facility. Table 2 summarizes the assumed boiler operating conditions input to the PFBC simulation code. Input fuel parameters for the chars and reference fuels were determined from their standard ASTM analyses (Table 1) and the results of the bench-scale characterization tests at B&W`s Alliance Research Center. The required characterization information for the reference fuels was available from the B&W data base, and the combustion reactivity information for the mild-gasification chars was generated in the pressurized bench-scale reactor as described earlier. Note that the combustion reactivity parameters for Beulah lignite are those previously measured at low-pressure conditions. It was necessary to use the previous values as the new parameters could not be accurately measured in the pressurized bench-scale facility. Based on very limited measurements of particle size attrition in paste-type feed systems, it was assumed that all of the fuels (including the chars) would have a very small (essentially negligible) degree of attrition in the feed system. Char devolatilization parameters were assumed to be equal to those of anthracite because of the very low levels of volatiles present in UCC2, IGTP1, and IGTP2. Major fuel input parameters and higher heating values are summarized in Table 3.

  6. Characterizing and modeling combustion of mild-gasification chars in pressurized fluidized beds

    SciTech Connect (OSTI)

    Daw, C.S.

    1993-01-01T23:59:59.000Z

    Performance estimates for the UCC2, IGTP1, and IGTP2 chars were made for a typical utility PFBC boiler having nominal characteristics similar to those of the American Electric Power 75 MW(e) Tidd PFBC demonstration facility. Table 2 summarizes the assumed boiler operating conditions input to the PFBC simulation code. Input fuel parameters for the chars and reference fuels were determined from their standard ASTM analyses (Table 1) and the results of the bench-scale characterization tests at B W's Alliance Research Center. The required characterization information for the reference fuels was available from the B W data base, and the combustion reactivity information for the mild-gasification chars was generated in the pressurized bench-scale reactor as described earlier. Note that the combustion reactivity parameters for Beulah lignite are those previously measured at low-pressure conditions. It was necessary to use the previous values as the new parameters could not be accurately measured in the pressurized bench-scale facility. Based on very limited measurements of particle size attrition in paste-type feed systems, it was assumed that all of the fuels (including the chars) would have a very small (essentially negligible) degree of attrition in the feed system. Char devolatilization parameters were assumed to be equal to those of anthracite because of the very low levels of volatiles present in UCC2, IGTP1, and IGTP2. Major fuel input parameters and higher heating values are summarized in Table 3.

  7. Analysis and comparison of biomass pyrolysis/gasification condensates: an interim report

    SciTech Connect (OSTI)

    Elliott, D.C.

    1985-09-01T23:59:59.000Z

    This report provides results of chemical and physical analysis of condensates from eleven biomass gasification and pyrolysis systems. The analyses were performed in order to provide more detailed data concerning these condensates for the different process research groups and to allow a determination of the differences in properties of the condensates as a function of reactor environment. The samples were representative of the various reactor configurations being researched within the Department of Energy, Biomass Thermochemical Conversion program. The condensates included tar phases, aqueous phases and, in some cases, both phases depending on the output of the particular reactor system. The analyses included gross compositional analysis (elemental analysis, ash, moisture), physical characterization (pour point, viscosity, density, heat of combustion, distillation), specific chemical analysis (gas chromatography/mass spectrometry, infrared spectrophotometry, proton and carbon-13 nuclear magnetic resonance spectrometry) and biological activity (Ames assay). The analytical data demonstrate the wide range of chemical composition of the organics recovered in the condensates and suggests a direct relationship between operating temperature and chemical composition of the condensates. A continuous pathway of thermal degradation of the tar components as a function of temperature is proposed. Variations in the chemical composition of the organic components in the tars are reflected in the physical properties of tars and phase stability in relation to water in the condensate. The biological activity appears to be limited to the tars produced at high temperatures as a result of formation of polycyclic aromatic hydrocarbons in high concentrations. 55 refs., 13 figs., 6 tabs.

  8. Design of gasifiers to optimize fuel cell systems

    SciTech Connect (OSTI)

    Not Available

    1992-02-01T23:59:59.000Z

    The objective of this project is to configure coal gasification/carbonate fuel cell systems that can significantly improve the economics, performance, and efficiency of electric power generation systems. (VC)

  9. Gasification of kraft black liquor and use of the products in combined cycle cogeneration. Final report, Phase II

    SciTech Connect (OSTI)

    Kelleher, E.G.

    1985-07-01T23:59:59.000Z

    This Phase II study of kraft black liquor gasification and use of the product gases in combined cycle cogeneration based on combustion gas turbines was motivated by the very promising results of the Phase I feasibility study. The Phase I study indicated that the alternative technology to the Tomlinson recovery furnace had the potential of improving the energy efficiency and safety of combusting black liquor, reducing the capital and operating costs, increasing the electric power output, and providing an economical system for incremental kraft capacity additions. During Phase II, additional bench-scale experiments were run, pilot-scale experiments were conducted, equipment systems were investigated, and performance and economics were reanalyzed. All of the objectives of the Phase II project were met. Recommendations are summarized.

  10. Chemical Processing in High-Pressure Aqueous Environments. 7. Process Development for Catalytic Gasification of Wet Biomass Feedstocks

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.; Butner, Scott S.; Zacher, Alan H.; Engelhard, Mark H.; Young, James S.; McCready, David E.

    2004-07-01T23:59:59.000Z

    Through the use of a metal catalyst, gasification of wet biomass can be accomplished with high levels of carbon conversion to gas at relatively low temperature (350 C). In the pressurized-water environment (20 MPa) near-total conversion of the organic structure of biomass to gases has been accomplished in the presence of a ruthenium metal catalyst. The process is essentially steam reforming as there is no added oxidizer or reagent other than water. In addition, the gas produced is a medium-heating value gas due to the synthesis of high-levels of methane, as dictated by thermodynamic equilibrium. Biomass trace components cause processing difficulties using the fixed catalyst bed tubular reactor system. Results are described for both bench-scale and scaled-up reactor systems.

  11. Energy, Environmental, and Economic Analyses of Design Concepts for the Co-Production of Fuels and Chemicals with Electricity via Co-Gasification of Coal and Biomass

    SciTech Connect (OSTI)

    Eric Larson; Robert Williams; Thomas Kreutz; Ilkka Hannula; Andrea Lanzini; Guangjian Liu

    2012-03-11T23:59:59.000Z

    The overall objective of this project was to quantify the energy, environmental, and economic performance of industrial facilities that would coproduce electricity and transportation fuels or chemicals from a mixture of coal and biomass via co-gasification in a single pressurized, oxygen-blown, entrained-flow gasifier, with capture and storage of CO{sub 2} (CCS). The work sought to identify plant designs with promising (Nth plant) economics, superior environmental footprints, and the potential to be deployed at scale as a means for simultaneously achieving enhanced energy security and deep reductions in U.S. GHG emissions in the coming decades. Designs included systems using primarily already-commercialized component technologies, which may have the potential for near-term deployment at scale, as well as systems incorporating some advanced technologies at various stages of R&D. All of the coproduction designs have the common attribute of producing some electricity and also of capturing CO{sub 2} for storage. For each of the co-product pairs detailed process mass and energy simulations (using Aspen Plus software) were developed for a set of alternative process configurations, on the basis of which lifecycle greenhouse gas emissions, Nth plant economic performance, and other characteristics were evaluated for each configuration. In developing each set of process configurations, focused attention was given to understanding the influence of biomass input fraction and electricity output fraction. Self-consistent evaluations were also carried out for gasification-based reference systems producing only electricity from coal, including integrated gasification combined cycle (IGCC) and integrated gasification solid-oxide fuel cell (IGFC) systems. The reason biomass is considered as a co-feed with coal in cases when gasoline or olefins are co-produced with electricity is to help reduce lifecycle greenhouse gas (GHG) emissions for these systems. Storing biomass-derived CO{sub 2} underground represents negative CO{sub 2} emissions if the biomass is grown sustainably (i.e., if one ton of new biomass growth replaces each ton consumed), and this offsets positive CO{sub 2} emissions associated with the coal used in these systems. Different coal:biomass input ratios will produce different net lifecycle greenhouse gas (GHG) emissions for these systems, which is the reason that attention in our analysis was given to the impact of the biomass input fraction. In the case of systems that produce only products with no carbon content, namely electricity, ammonia and hydrogen, only coal was considered as a feedstock because it is possible in theory to essentially fully decarbonize such products by capturing all of the coal-derived CO{sub 2} during the production process.

  12. Hydrogen production by high-temperature steam gasification of biomass and coal

    SciTech Connect (OSTI)

    Kriengsak, S.N.; Buczynski, R.; Gmurczyk, J.; Gupta, A.K. [University of Maryland, College Park, MD (United States). Dept. of Mechanical Engineering

    2009-04-15T23:59:59.000Z

    High-temperature steam gasification of paper, yellow pine woodchips, and Pittsburgh bituminous coal was investigated in a batch-type flow reactor at temperatures in the range of 700 to 1,200{sup o}C at two different ratios of steam to feedstock molar ratios. Hydrogen yield of 54.7% for paper, 60.2% for woodchips, and 57.8% for coal was achieved on a dry basis, with a steam flow rate of 6.3 g/min at steam temperature of 1,200{sup o}C. Yield of both the hydrogen and carbon monoxide increased while carbon dioxide and methane decreased with the increase in gasification temperature. A 10-fold reduction in tar residue was obtained at high-temperature steam gasification, compared to low temperatures. Steam and gasification temperature affects the composition of the syngas produced. Higher steam-to-feedstock molar ratio had negligible effect on the amount of hydrogen produced in the syngas in the fixed-batch type of reactor. Gasification temperature can be used to control the amounts of hydrogen or methane produced from the gasification process. This also provides mean to control the ratio of hydrogen to CO in the syngas, which can then be processed to produce liquid hydrocarbon fuel since the liquid fuel production requires an optimum ratio between hydrogen and CO. The syngas produced can be further processed to produce pure hydrogen. Biomass fuels are good source of renewable fuels to produce hydrogen or liquid fuels using controlled steam gasification.

  13. Advanced High-Temperature, High-Pressure Transport Reactor Gasification

    SciTech Connect (OSTI)

    Michael L. Swanson

    2005-08-30T23:59:59.000Z

    The transport reactor development unit (TRDU) was modified to accommodate oxygen-blown operation in support of a Vision 21-type energy plex that could produce power, chemicals, and fuel. These modifications consisted of changing the loop seal design from a J-leg to an L-valve configuration, thereby increasing the mixing zone length and residence time. In addition, the standpipe, dipleg, and L-valve diameters were increased to reduce slugging caused by bubble formation in the lightly fluidized sections of the solid return legs. A seal pot was added to the bottom of the dipleg so that the level of solids in the standpipe could be operated independently of the dipleg return leg. A separate coal feed nozzle was added that could inject the coal upward into the outlet of the mixing zone, thereby precluding any chance of the fresh coal feed back-mixing into the oxidizing zone of the mixing zone; however, difficulties with this coal feed configuration led to a switch back to the original downward configuration. Instrumentation to measure and control the flow of oxygen and steam to the burner and mix zone ports was added to allow the TRDU to be operated under full oxygen-blown conditions. In total, ten test campaigns have been conducted under enriched-air or full oxygen-blown conditions. During these tests, 1515 hours of coal feed with 660 hours of air-blown gasification and 720 hours of enriched-air or oxygen-blown coal gasification were completed under this particular contract. During these tests, approximately 366 hours of operation with Wyodak, 123 hours with Navajo sub-bituminous coal, 143 hours with Illinois No. 6, 106 hours with SUFCo, 110 hours with Prater Creek, 48 hours with Calumet, and 134 hours with a Pittsburgh No. 8 bituminous coal were completed. In addition, 331 hours of operation on low-rank coals such as North Dakota lignite, Australian brown coal, and a 90:10 wt% mixture of lignite and wood waste were completed. Also included in these test campaigns was 50 hours of gasification on a petroleum coke from the Hunt Oil Refinery and an additional 73 hours of operation on a high-ash coal from India. Data from these tests indicate that while acceptable fuel gas heating value was achieved with these fuels, the transport gasifier performs better on the lower-rank feedstocks because of their higher char reactivity. Comparable carbon conversions have been achieved at similar oxygen/coal ratios for both air-blown and oxygen-blown operation for each fuel; however, carbon conversion was lower for the less reactive feedstocks. While separation of fines from the feed coals is not needed with this technology, some testing has suggested that feedstocks with higher levels of fines have resulted in reduced carbon conversion, presumably due to the inability of the finer carbon particles to be captured by the cyclones. These data show that these low-rank feedstocks provided similar fuel gas heating values; however, even among the high-reactivity low-rank coals, the carbon conversion did appear to be lower for the fuels (brown coal in particular) that contained a significant amount of fines. The fuel gas under oxygen-blown operation has been higher in hydrogen and carbon dioxide concentration since the higher steam injection rate promotes the water-gas shift reaction to produce more CO{sub 2} and H{sub 2} at the expense of the CO and water vapor. However, the high water and CO{sub 2} partial pressures have also significantly reduced the reaction of (Abstract truncated)

  14. Polk power station syngas cooling system

    SciTech Connect (OSTI)

    Jenkins, S.D.

    1995-01-01T23:59:59.000Z

    Tampa Electric Company (TEC) is in the site development and construction phase of the new Polk Power Station Unit No. 1. This will be the first unit at a new site and will use Integrated Gasification Combined Cycle (IGCC) Technology. The unit will utilize Texaco`s oxygen-blown, entrained-flow coal gasification, along with combined cycle power generation, to produce nominal 260MW. Integral to the gasification process is the syngas cooling system. The design, integration, fabrication, transportation, and erection of this equipment have provided and continue to provide major challenges for this project.

  15. Numerical study on convection diffusion for gasification agent in underground coal gasification. Part I: establishment of mathematical models and solving method

    SciTech Connect (OSTI)

    Yang, L.H.; Ding, Y.M. [China University of Mining & Technology, Xuzhou (China). College of Resources and Geoscience

    2009-07-01T23:59:59.000Z

    The aim of this article is to discuss the distribution law of the gasification agent concentration in a deep-going way during underground coal gasification and the new method of solving the problem for the convection diffusion of the gas. In this paper, the basic features of convection diffusion for the gas produced in underground coal gasification are studied. On the basis of the model experiment, through the analysis of the distribution and patterns of variation for the fluid concentration field in the process of the combustion and gasification of the coal seams within the gasifier, the 3-D non-linear unstable mathematical models on the convection diffusion for oxygen are established. In order to curb such pseudo-physical effects as numerical oscillation and surfeit which frequently occurred in the solution of the complex mathematical models, the novel finite unit algorithm, the upstream weighted multi-cell balance method is advanced in this article, and its main derivation process is introduced.

  16. Assessment of underground coal gasification in bituminous coals. Volume I. Executive summary. Final report

    SciTech Connect (OSTI)

    None

    1981-01-01T23:59:59.000Z

    This report describes the bituminous coal resources of the United States, identifies those resources which are potentially amenable to Underground Coal Gasification (UCG), identifies products and markets in the vicinity of selected target areas, identifies UCG concepts, describes the state of the art of UCG in bituminous coal, and presents three R and D programs for development of the technology to the point of commercial viability. Of the 670 billion tons of bituminous coal remaining in-place as identified by the National Coal Data System, 32.2 billion tons or 4.8% of the total are potentially amenable to UCG technology. The identified amenable resource was located in ten states: Alabama, Colorado, Illinois, Kentucky, New Mexico, Ohio, Oklahoma, Utah, Virginia, and West Virginia. The principal criteria which eliminated 87.3% of the resource was the minimum thickness (42 inches). Three R and D programs were developed using three different concepts at two different sites. Open Borehole, Hydraulic Fracture, and Electrolinking concepts were developed. The total program costs for each concept were not significantly different. The study concludes that much of the historical information based on UCG in bituminous coals is not usable due to the poor siting of the early field tests and a lack of adequate diagnostic equipment. This information gap requires that much of the early work be redone in view of the much improved understanding of the role of geology and hydrology in the process and the recent development of analytical tools and methods.

  17. Combined Air Sparge and Bioremediation of an Underground Coal Gasification Site

    SciTech Connect (OSTI)

    Covell, J.R.; Thomas, M.H.

    1996-12-01T23:59:59.000Z

    EG&G Technical Services of West Virginia (TSWV) Inc. is successfully remediating a former underground coal gasification (UCG) test site in northeastern Wyoming. EG&G is demonstrating the effectiveness of combined air sparge and biostimulation technology. This project is being conducted for the U.S. Department of Energy (DOE ) - Morgantown Energy Technology Center (METC), the lease holder of the site. UCG testing from 1976 through 1979 contaminated three water-bearing units at the site with benzene. Previous pump and treat operations at the site showed the presence of a persistent non-dissolved benzene source material. The Felix I coal seam is the most contaminated unit at the site and was the target unit for the initial demonstration. Air sparging was selected to strip dissolved benzene, volatilize the non- dissolved benzene source material, and to provide oxygen for increasing aerobic bacteria populations. Indigenous bacteria populations were stimulated with ammonium phosphate addition. EG&G designed the remediation system to take advantage of the hydrogeologic environment to produce a cost-effective approach to the groundwater remediation. Groundwater pumping was used to manipulate subsurface air flow, nutrient transport, and biomass management. Demonstration operations began on September 29, 1995, and were suspended on April 30, 1996 to begin demonstration expansion. Initial results of the demonstration show substantial reduction in benzene concentrations across the demonstration area. Benzene concentration reductions greater than 80% were observed two months after demonstration operations were suspended.

  18. Plasma Treatments and Biomass Gasification This article has been downloaded from IOPscience. Please scroll down to see the full text article.

    E-Print Network [OSTI]

    Boyer, Edmond

    Plasma Treatments and Biomass Gasification This article has been downloaded from IOPscience. Please Treatments and Biomass Gasification J Luche1 , Q Falcoz2 , T Bastien2 , J P Leninger2 , K Arabi1 , O Aubry1 various methods of biomass processing. Gasification is one of the ways to recover energy from biomass

  19. Fundamental research on novel process alternatives for coal gasification: Final report

    SciTech Connect (OSTI)

    Hill, A H; Knight, R A; Anderson, G L; Feldkirchner, H L; Babu, S P

    1986-10-01T23:59:59.000Z

    The Institute of Gas Technology has conducted a fundamental research program to determine the technical feasibility of and to prepare preliminary process evaluations for two new approaches to coal gasification. These two concepts were assessed under two major project tasks: Task 1. CO/sub 2/-Coal Gasification Process Concept; Task 2. Internal Recirculation Catalysts Coal Gasification Process Concept. The first process concept involves CO/sub 2/-O/sub 2/ gasification of coal followed by CO/sub 2/ removal from the hot product gas by a solid MgO-containing sorbent. The sorbent is regenerated by either a thermal- or a pressure-swing step and the CO/sub 2/ released is recycled back to the gasifier. The product is a medium-Btu gas. The second process concept involves the use of novel ''semivolatile'' materials as internal recirculating catalysts for coal gasification. These materials remain in the gasifier because their vapor pressure-temperature behavior is such that they will be in the vapor state at the hotter, char exit part of the reactor and will condense in the colder, coal-inlet part of the reactor. 21 refs., 43 figs., 43 tabs.

  20. Coke gasification: the influence and behavior of inherent catalytic mineral matter

    SciTech Connect (OSTI)

    Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Bangor, NSW (Australia)

    2009-04-15T23:59:59.000Z

    Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

  1. A review of the factors influencing the physicochemical characteristics of underground coal gasification

    SciTech Connect (OSTI)

    Yang, L.H. [China University of Mining and Technology, Jiangsu (China)

    2008-07-01T23:59:59.000Z

    In this article, the physicochemical characteristics of the oxidation zone, the reduction zone, and the destructive distillation and dry zone in the process of underground coal gasification (UCG) were explained. The effect of such major factors as temperature, coal type, water-inrush or -intake rate, the quantity and quality of wind blasting, the thickness of coal seams, operational pressure, the length, and the section of gasification gallery on the quality of the underground gas and their interrelationship were discussed. Research showed that the temperature conditions determined the underground gas compositions; the appropriate water-inrush or -intake rate was conducive to the improvement in gas heat value; the properties of the gasification agent had an obvious effect on the compositions and heat value of the product gas. Under the cyclically changing pressure, heat losses decreased by 60%, with the heat efficiency and gasification efficiency being 1.4 times and 2 times those of constant pressure, respectively. The test research further proved that the underground gasifier with a long channel and a big cross-section, to a large extent, improved the combustion-gasification conditions.

  2. Results from the third LLL underground coal gasification experiment at Hoe Creek

    SciTech Connect (OSTI)

    Hill, R.W.; Thorsness, C.B.; Cena, R.J.; Aiman, W.R.; Stephens, D.R.

    1980-05-20T23:59:59.000Z

    A major objective of the US Energy Program is the development of processes to produce clean fuels from coal. Underground coal gasification is one of the most promising of these processes. If successful, underground coal gasification (UCG) would quadruple the proven reserves of the US coal. Cost for products produced from UCG are projected to be 65 to 75% of those from conventional coal conversion. Finally, UCG appears to possess environmental advantages since no mining is involved and there are less solid wastes produced. In this paper we describe results from the Hoe Creek No. 3 underground coal gasification test. The experiment employed a drilled channel between process wells spaced 130' apart. The drilled channel was enlarged by reverse combustion prior to forward gasification. The first week of forward gasification was carried out using air injection, during which 250 tons of coal were consumed yielding an average dry product gas heating value of 114 Btu/scf. Following this phase, steam and oxygen were injected (generally a 50-50 mixture) for 47 days, during which 3945 tons of coal were consumed at an average rate of 84 tons of coal per day and an average dry gas heating value of 217 Btu/scf. The average gas composition during the steam-oxygen phase was 37% H/sub 2/, 5% CH/sub 4/, 11% CO, and 44% CO/sub 2/. Gas recovery was approximately 82% during the test, and the average thermochemical efficiency was near 65%.

  3. Corrosion and mechanical behavior of materials for coal gasification applications

    SciTech Connect (OSTI)

    Natesan, K.

    1980-05-01T23:59:59.000Z

    A state-of-the-art review is presented on the corrosion and mechanical behavior of materials at elevated temperatures in coal-gasification environments. The gas atmosphere in coal-conversion processes are, in general, complex mixtures which contain sulfur-bearing components (H/sub 2/S, SO/sub 2/, and COS) as well as oxidants (CO/sub 2//CO and H/sub 2/O/H/sub 2/). The information developed over the last five years clearly shows sulfidation to be the major mode of material degradation in these environments. The corrosion behavior of structural materials in complex gas environments is examined to evaluate the interrelationships between gas chemistry, alloy chemistry, temperature, and pressure. Thermodynamic aspects of high-temperature corrosion processes that pertain to coal conversion are discussed, and kinetic data are used to compare the behavior of different commercial materials of interest. The influence of complex gas environments on the mechanical properties such as tensile, stress-rupture, and impact on selected alloys is presented. The data have been analyzed, wherever possible, to examine the role of environment on the property variation. The results from ongoing programs on char effects on corrosion and on alloy protection via coatings, cladding, and weld overlay are presented. Areas of additional research with particular emphasis on the development of a better understanding of corrosion processes in complex environments and on alloy design for improved corrosion resistance are discussed. 54 references, 65 figures, 24 tables.

  4. Role of site characteristics in coal gasification. [Hanna, Wyoming

    SciTech Connect (OSTI)

    Bader, B.E.; Glass, R.E.

    1981-12-01T23:59:59.000Z

    Field test data for a series of four underground coal gasification tests (UCG) at a site near Hanna, Wyoming are presented. Results of these field tests were combined with modeling efforts to identify site selective parameters broadly identified as the flow and mechanical properties of a coal seam that can help determine the degree to which any UCG test would be successful. Specifically, the characteristics shown to be important are concluded to be: (1) permeability structure and mobile water, which play a crucial role in determining air flow paths; (2) high permeability zones at midstream and above to act as the primary air flow path; (3) spacing of injection and production wells can be varied to enhance the chance of keeping the air flow paths low in the coal seam; (4) completion of the process wells in a manner that minimizes neighboring permeability inhibits the chance of override; (5) the orthotropic permeability of coal improve UCG results; (6) thermochemical properties of coal are important with respect to the manner of combustion front propogation; and (7) heating will result in stress dependent anisotropic strength characteristics of the coal. Other properties characteristic of a given coal, petrographic constitutents of a coal, chemistry of combustion and the in situ stress distribution are also pointed out as significant factors to be considered in the most efficient use of UCG technique. 14 references, (BLM)

  5. Effects of aquifer interconnection resulting from underground coal gasification

    SciTech Connect (OSTI)

    Stone, R.

    1983-09-01T23:59:59.000Z

    Lawrence Livermore National Laboratory evaluated the effects of aquifer interconnection caused by the collapse of cavities formed in coal seams by two small underground coal gasification experiments in the Powder River Basin, Wyoming. Flow models and field measurements were used to show that the water from one or both of the upper aquifers enters the collapse, rubble and flows down to the lowest aquifer (the gasified coal seam) where it flows away from the collapse zones. The investigations showed that the hydraulic conductivity of the collapse rubble is less than that of the aquifers and provides only a moderately permeable interconnection between them, a marked reduction in hydraulic conductivity of the gasified coal seam near the collapse zones restricts the flow in the seam, away from them; changes in the hydraulic head and flow patterns caused by aquifer interconnection extend generally only 60-90 m away from the experiment sites, whereas flow in the uppermost aquifer at one of the sites may be influenced as far away as 122 m. At both sites, the aquifer interconnection allows water from the uppermost (sand) aquifer, which contains the poorest quality water of the 3 aquifers, to enter one or both of the underlying aquifers.

  6. Proceedings of the thirteenth annual underground coal gasification symposium

    SciTech Connect (OSTI)

    Martin, J.W.; Barone, S.P. (eds.)

    1987-08-01T23:59:59.000Z

    The Thirteenth Annual Underground Coal Gasification Symposium was cosponsored by the Morgantown Energy Technology Center's Laramie Projects Office and Gas Research Institute of Chicago, Illinois, and hosted by the Western Research Institute of Laramie, Wyoming. The symposium was held in Laramie, Wyoming, during the period, August 24 to 26, 1987. Papers printed in these Proceedings were reproduced from camera-ready manuscripts furnished by the authors. They have not been refereed nor have they been edited after receipt for publishing. The purpose for this annual meeting is to provide an opportunity for scientists working in the technology to present their research results, exchange ideas, and discuss their future plans. Nearly 100 attendees from industry, academia, Government, and eight countries, including Belgium, Brazil, France, the Netherlands, Japan, West Germany, India, and Yugoslavia participated. Forty-seven papers were presented in five formal sessions covering Technology, International, Environmental, and General Topics and one informal poster session dominantly covering laboratory and modeling studies. Industrial papers have been processed for inclusion in the Energy Data Base.

  7. Techno-Economic Analysis of Biofuels Production Based on Gasification

    SciTech Connect (OSTI)

    Swanson, R. M.; Platon, A.; Satrio, J. A.; Brown, R. C.; Hsu, D. D.

    2010-11-01T23:59:59.000Z

    This study compares capital and production costs of two biomass-to-liquid production plants based on gasification. The first biorefinery scenario is an oxygen-fed, low-temperature (870?C), non-slagging, fluidized bed gasifier. The second scenario is an oxygen-fed, high-temperature (1,300?C), slagging, entrained flow gasifier. Both are followed by catalytic Fischer-Tropsch synthesis and hydroprocessing to naphtha-range (gasoline blend stock) and distillate-range (diesel blend stock) liquid fractions. Process modeling software (Aspen Plus) is utilized to organize the mass and energy streams and cost estimation software is used to generate equipment costs. Economic analysis is performed to estimate the capital investment and operating costs. Results show that the total capital investment required for nth plant scenarios is $610 million and $500 million for high-temperature and low-temperature scenarios, respectively. Product value (PV) for the high-temperature and low-temperature scenarios is estimated to be $4.30 and $4.80 per gallon of gasoline equivalent (GGE), respectively, based on a feedstock cost of $75 per dry short ton. Sensitivity analysis is also performed on process and economic parameters. This analysis shows that total capital investment and feedstock cost are among the most influential parameters affecting the PV.

  8. Catalytic combustor for integrated gasification combined cycle power plant

    DOE Patents [OSTI]

    Bachovchin, Dennis M. (Mauldin, SC); Lippert, Thomas E. (Murrysville, PA)

    2008-12-16T23:59:59.000Z

    A gasification power plant 10 includes a compressor 32 producing a compressed air flow 36, an air separation unit 22 producing a nitrogen flow 44, a gasifier 14 producing a primary fuel flow 28 and a secondary fuel source 60 providing a secondary fuel flow 62 The plant also includes a catalytic combustor 12 combining the nitrogen flow and a combustor portion 38 of the compressed air flow to form a diluted air flow 39 and combining at least one of the primary fuel flow and secondary fuel flow and a mixer portion 78 of the diluted air flow to produce a combustible mixture 80. A catalytic element 64 of the combustor 12 separately receives the combustible mixture and a backside cooling portion 84 of the diluted air flow and allows the mixture and the heated flow to produce a hot combustion gas 46 provided to a turbine 48. When fueled with the secondary fuel flow, nitrogen is not combined with the combustor portion.

  9. ENCOAL mild coal gasification project public design and construction report

    SciTech Connect (OSTI)

    NONE

    1994-12-01T23:59:59.000Z

    This Public Design Report describes the 1000 ton per day ENCOAL mild coal gasification demonstration plant now in operation at the Buckskin Mine near Gillette, Wyoming. The objective of the project is to demonstrate that the proprietary Liquids From Coal (LFC) technology can reliably and economically convert low Btu PRB coal into a superior, high-Btu solid fuel (PDF), and an environmentally attractive low-sulfur liquid fuel (CDL). The Project`s plans also call for the production of sufficient quantities of PDF and CDL to permit utility companies to carry out full scale burn tests. While some process as well as mechanical design was done in 1988, the continuous design effort was started in July 1990. Civil construction was started in October 1990; mechanical erection began in May 1991. Virtually all of the planned design work was completed by July 1991. Most major construction was complete by April 1992 followed by plant testing and commissioning. Plant operation began in late May 1992. This report covers both the detailed design and initial construction aspects of the Project.

  10. Steam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture

    E-Print Network [OSTI]

    Litster, Shawn

    Steam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture Nicholas S. Siefert Virginia 26507, United States ABSTRACT: We present experimental results of coal gasification. Using two different coal types and temperatures between 700 and 900 °C, we studied the effect

  11. Integrated Gasification Combined Cycle (IGCC) demonstration project, Polk Power Station -- Unit No. 1. Annual report, October 1993--September 1994

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    This describes the Tampa Electric Company`s Polk Power Station Unit 1 (PPS-1) Integrated Gasification Combined Cycle (IGCC) demonstration project which will use a Texaco pressurized, oxygen-blown, entrained-flow coal gasifier to convert approximately 2,300 tons per day of coal (dry basis) coupled with a combined cycle power block to produce a net 250 MW electrical power output. Coal is slurried in water, combined with 95% pure oxygen from an air separation unit, and sent to the gasifier to produce a high temperature, high pressure, medium-Btu syngas with a heat content of about 250 Btu/scf (LHV). The syngas then flows through a high temperature heat recovery unit which cools the syngas prior to its entering the cleanup systems. Molten coal ash flows from the bottom of the high temperature heat recovery unit into a water-filled quench chamber where it solidifies into a marketable slag by-product.

  12. Hot Gas Cleanup Test Facility for gasification and pressurized combustion. Quarterly report, October--December 1994

    SciTech Connect (OSTI)

    NONE

    1995-02-01T23:59:59.000Z

    The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The major particulate control device issues to be addressed include the integration of the particulate control devices into coal utilization systems, on-line cleaning techniques, chemical and thermal degradation of components, fatigue or structural failures, blinding, collection efficiency as a function of particle size, and scale-up of particulate control systems to commercial size. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: carbonizer/pressurized circulating fluidized bed gas source; hot gas cleanup units to mate to all gas streams; combustion gas turbine; and fuel cell and associated gas treatment. The major emphasis during this reporting period was continuing the detailed design of the facility and integrating the particulate control devices (PCDs) into structural and process designs. Substantial progress in underground construction activities was achieved during the quarter. Delivery and construction of coal handling and process structural steel began during the quarter. Delivery and construction of coal handling and process structural steel began during the quarter. MWK equipment at the grade level and the first tier are being set in the structure.

  13. Fundamental investigations of underground coal gasification. Annual report Mar 82-Mar 83

    SciTech Connect (OSTI)

    Dunn, R.D.

    1983-03-01T23:59:59.000Z

    Coal deposits in the Appalachian and Midwest Coal Regions consist primarily of thin relatively deep seams of swelling bituminous coal, but little scientific effort in the United States has been directed toward underground coal gasification in these important industrial areas. In Europe, however, major work is under way on underground coal gasification in thin, deep seams of swelling coal. The principal investigator and a graduate student are participating in field tests in Belgium and supporting laboratory experiments in Germany. Mathematical models are being developed to interpret these experimental data, and a better understanding of the underground coal gasification process is emerging. This understanding is essential for evaluating potential problems, for devising solutions to such problems and for designing field tests.

  14. Water assessment report: Section 13 (c); Great Plains gasification project, Mercer County, ND

    SciTech Connect (OSTI)

    None

    1980-12-01T23:59:59.000Z

    The Water Resources Council is completing a water assessment of synfuels development in the Upper Missouri River Basin. This is being done under Section 13(a) of the Federal Nonnuclear Energy Research and Development Act. The assessment area includes the coal deposits in the Mercer County project site. Levels of North Dakota coal gasification development that are several times the production level of the Great Plains gasification project are being examined. This report assesses: (1) the availability of adequate water supplies to meet the water requirements of the project, supporting activities, and other development induced by the project; and (2) the changes in the water resources that will result from the project. Findings of the 13(a) assessment show that water supplies are physically available within the mainstem of the Missouri River in North Dakota to supply the requirements of the gasification facilities and the supporting activities - mining and reclamation, electricity, and project-induced population increases.

  15. Utilization of solid wastes from the gasification of coal-water slurries

    SciTech Connect (OSTI)

    M.Y. Shpirt; N.P. Goryunova [Institute for Fossil Fuels, Moscow (Russian Federation)

    2009-07-01T23:59:59.000Z

    It was found that only fly and bottom ashes are the solid wastes of water-coal slurry gasification in a direct-flow gasifier. The yields and chemical compositions of fly and bottom ashes obtained after the gasification of water-coal slurries prepared using brown (B) and long-flame (D) coals from the Berezovskii and Mokhovskii strip mines (Kansk-Achinsk and Kuznetsk Basins, respectively) were characterized. Based on an analysis of currently available information, the areas of utilization of fly and bottom ashes after water-coal slurry gasification with dry ash removal were summarized. The use of these wastes in the construction of high-ways and earthwork structures (for the parent coals of B and D grades) and in the manufacture of ash concrete (for the parent coal of D grade) is most promising.

  16. Transformation of alkali metals during pyrolysis and gasification of a lignite

    SciTech Connect (OSTI)

    Xiaofang Wei; Jiejie Huang; Tiefeng Liu; Yitian Fang; Yang Wang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

    2008-05-15T23:59:59.000Z

    Transformation of Na and K in a lignite was investigated during pyrolysis and gasification in a fixed-bed by using a serial dissolution method with H{sub 2}O, CH{sub 3}COONH{sub 4}, and HCl solutions. The evolution of the fractions of four forms in solid and alkali volatilization during pyrolysis and gasification was determined. The results show that a different mode of occurrence between Na and of K in coal existed. Na in coal can be nearly completely dissolved by H{sub 2}O, CH{sub 3}COONH{sub 4}, and HCl solution. However, K in coal exists almost in the stable forms. Both H{sub 2}O soluble and CH{sub 3}COONH{sub 4} soluble Na and K fractions decline during pyrolysis and early gasification stage and increase a little with the process of char gasification. The stable form Na in the char produced during pyrolysis is transferred to other forms during char gasification via the pore opening and a series of chemical reactions. Na{sub 2}SO{sub 4} (K{sub 2}SO{sub 4}) may play an important role in producing stable forms such as Na{sub 2}O.Al{sub 2}O{sub 3}2SiO{sub 2} and K{sub 2}O.Al{sub 2}O{sub 3}.2SiO{sub 2} during pyrolysis. The fraction of HCl soluble K increases during pyrolysis but decreases markedly during the early gasification stage. 20 refs., 7 figs., 1 tabs.

  17. Development of an advanced, continuous mild gasification process for the production of co-products

    SciTech Connect (OSTI)

    Ness, R.O. Jr.; Li, Y.; Heidt, M.

    1992-09-01T23:59:59.000Z

    Prior to disassembly of the CFBR, accumulated tar residue must be removed from the reactor, piping and tubing lines, and the condenser vessels. Based on experience from the CFBR mild gasification tests, lacquer thinner must be pumped through the unit for at least one hour to remove the residual tar. The lacquer thinner wash may be followed by a water wash. The CFBR will be disassembled after the system has been thoroughly flushed out. The following equipment must be disassembled and removed for storage: Superheater; Water supply pump; Coal feed system (hopper, auger, ball feeder, valves); Reactor; Cyclone and fines catch pot; Condensers (water lines, glycol bath, condenser pots, valves); and Gas meter. After the process piping and reactor have been disassembled, the equipment will be inspected for tar residues and flushed again with acetone or lacquer thinner, if necessary. All solvent used for cleaning the system will be collected for recycle or proper disposal. Handling and disposal of the solvent will be properly documented. The equipment will be removed and stored for future use. Equipment contaminated externally with tar (Level 4) will be washed piece by piece with lacquer thinner after disassembly of the PRU. Proper health and safety practices must be followed by the personnel involved in the cleanup operation. Care must be taken to avoid ingestion, inhalation, or prolonged skin contact of the coal tars and lacquer thinner. Equipment contaminated internally by accumulation of residual tar or oil (Level 5) will be flushed section by section with lacquer thinner. The equipment will be washed with solvent both before and after disassembly to ensure that all tar has been removed from the piping, pumps, gas quench condensers, light tar condensers, and drain lines. The coal tars wig be separated from the solvent and incinerated.

  18. The particulate and vapor phase components of airborne polyaromatic hydrocarbons (PAHs) in coal gasification pilot plants 

    E-Print Network [OSTI]

    Brink, Eric Jon

    1980-01-01T23:59:59.000Z

    , the hot gases flow into a condenser where they are (1-3, 7) cooled and the liquid sulfur 1s removed. The final steps 1n the gasif1cation process are to compr ess the methanated gas from appr oximately 140 psig to pipel1ne pr essure of 1000 psig...THE PARTICULATE AND VAPOR PHASE COMPONENTS OF AIRBORNE POLYAROMATIC HYDROCARBONS(PAHs) IN COAL GASIFICATION PILOT PLANTS A Thesis by ERIC JON BRINK Submitted to the Graduate College of Texas A & M University in partial fulfillment...

  19. Characterization of Texas lignite and numerical modeling of its in-situ gasification 

    E-Print Network [OSTI]

    Wang, Yih-Jy

    1983-01-01T23:59:59.000Z

    Modeling Site selection for in-situ gasification projects normally involves application of site screen1ng criteria. Some of these cr1teria were discussed by Russell et al. (1983). Numerical simulation may play an important role in s1te selection...CHARACTERIZATION OF TEXAS LIGNITE AND NUMERICAL MODELING OF ITS IN-SITU GASIFICATION A Thesis by YIH-JY WANG Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER...

  20. Oil shale, tar sands, and underground coal gasification. Quarterly progress report, July-September, 1983

    SciTech Connect (OSTI)

    Not Available

    1983-10-28T23:59:59.000Z

    Technical progress made for the second quarter, July 1, 1983 through September 30, 1983 are described for three areas, oil shale, tar sand and underground gasification of coal. The oil shale program is divided into the following tasks: chemistry and physics; retort bed analysis; novel processing methods; and environmental impact mitigation. The tar sand investigation covers: recovery processes; preparation; novel processing methods; and environmental impact mitigation. Underground coal gasification covers: recovery processes; field project evaluation; novel processing methods; and environmental impact mitigation. An executive summary is provided for the three programs. 19 figures, 23 tables.

  1. Energy considerations for steam plasma gasification of black liquor and chemical recovery

    SciTech Connect (OSTI)

    Grandy, J.D.; Kong, P.C.

    1995-10-01T23:59:59.000Z

    This paper investigates the energy economics of using a hybrid steam plasma process to gasify black liquor. In the pulp and paper industry, gasification is gaining credibility as an incremental method to supplement the standard Kraft process, which bums the black liquor in large furnaces to recover energy and inorganic chemicals (sodium and sulfur) that are recycled back into the wood pulping process. This paper shows that despite the energy intensive nature of steam plasma processing, several fortuitous conditions arise that make it a viable technology for the gasification of black liquor.

  2. Energy considerations for steam plasma gasification of black liquor and chemical recovery

    SciTech Connect (OSTI)

    Grandy, J.D.; Kong, P.C. [Idaho National Engineering Lab., Idaho Falls, ID (United States)

    1995-07-01T23:59:59.000Z

    This paper investigates the energy economics of using a hybrid steam plasma process to gasify black liquor. In the pulp and paper industry, gasification is gaining credibility as an incremental method to supplement the standard Kraft process, which burns the black liquor in large furnaces to recover energy and inorganic chemicals (sodium and sulfur) that are recycled back into the wood pulping process. This paper shows that despite the energy intensive nature of steam plasma processing, several fortuitous conditions arise that make it a viable technology for the gasification of black liquor.

  3. Modelling Rates of Gasification of a Char Particle in Chemical Looping Combustion

    E-Print Network [OSTI]

    Saucedo, Marco A.; Dennis, John S.; Scott, Stuart A.

    2014-07-15T23:59:59.000Z

    with that in the initial particle. Keywords Chemical-looping combustion; gasification; coal; CO2 separation; fluidisation 3 Nomenclature 12ckA Pre-exponential factor for the rate constant 2ck1, mol s -1 g-1 bar-1 12ckA Pre-exponential factor for the rate constant 2ck2... 1 Modelling Rates of Gasification of a Char Particle in Chemical Looping Combustion Marco A. Saucedoa*, John S. Dennisa, Stuart A. Scottb aDepartment of Chemical Engineering and Biotechnology, University of Cambridge, Pembroke Street, Cambridge...

  4. Changes in major organic contaminants in the groundwater at the Hoe Creek underground coal gasification site

    SciTech Connect (OSTI)

    Wang, F.; Mead, W.

    1985-08-01T23:59:59.000Z

    The results of groundwater analysis at the Hoe Creek underground coal gasification (UCG) site have indicated that, after gasification, the phenolic compounds and neutral aromatic hydrocarbons decrease more slowly than expected on the basis of our laboratory studies. The field data also fail to confirm the expected inverse relationship between a contaminant's water solubility and the extent to which it is sorbed by surrounding coal. The authors described a mechanism for the deposition of coal pyrolysis products that may help to elucidate the observed behavior of these organic contaminants. 7 refs., 7 figs.

  5. Economic development through biomass system integration. Volumes 2--4

    SciTech Connect (OSTI)

    DeLong, M.M.

    1995-10-01T23:59:59.000Z

    Report documents a feasibility study for an integrated biomass power system, where an energy crop (alfalfa) is the feedstock for a processing plant and a power plant (integrated gasification combined cycle) in a way that benefits the facility owners.

  6. Simulation of blast-furnace tuyere and raceway conditions in a wire mesh reactor: extents of combustion and gasification

    SciTech Connect (OSTI)

    Long Wu; N. Paterson; D.R. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

    2007-08-15T23:59:59.000Z

    A wire mesh reactor has been modified to investigate reactions of coal particles in the tuyeres and raceways of blast furnaces. At temperatures above 1000{sup o}C, pyrolysis reactions are completed within 1 s. The release of organic volatiles is probably completed by 1500{sup o}C, but the volatile yield shows a small increase up to 2000{sup o}C. The additional weight loss at the higher temperature may be due to weight loss from inorganic material. The residence time in the raceway is typically 20 ms, so it is likely that pyrolysis of the coal will continue throughout the passage along the raceway and into the base of the furnace shaft. Combustion reactions were investigated using a trapped air injection system, which admitted a short pulse of air into the wire mesh reactor sweep gas stream. In these experiments, the temperature and partial pressure of O{sub 2} were limited by the oxidation of the molybdenum mesh. However, the tests have provided valid insight into the extent of this reaction at conditions close to those experienced in the raceway. Extents of combustion of the char were low (mostly, less than 5%, daf basis). The work indicates that the extent of this reaction is limited in the raceway by the low residence time and by the effect of released volatiles, which scavenge the O{sub 2} and prevent access to the char. CO{sub 2} gasification has also been studied and high conversions achieved within a residence time of 5-10 s. The latter residence time is far longer than that in the raceway and more typical of small particles travelling upward in the furnace shaft. The results indicate that this reaction is capable of destroying most of the char. However, the extent of the gasification reaction appears limited by the decrease in temperature as the material moves up through the furnace. 44 refs., 12 figs., 6 tabs.

  7. LLNL underground coal gasification project. Quarterly progress report, July-Sep 1980. [Hoe Creek and Gorgas, Alabama tests

    SciTech Connect (OSTI)

    Olness, D.U. (ed.)

    1980-10-14T23:59:59.000Z

    Laboratory studies of forward gasification through drilled holes in blocks of coal have continued. Such studies give insight into cavity growth mechanisms and particulate production. In addition to obtaining a qualitative comparison of the forward burn characteristics of two coals, we obtained information on the influence of bedding plane/cleat structure orientation on the early-time shape of the burn cavity in the Roland coal. We have improved our model of the coal drying rate during underground coal gasification (UCG) by adding refinements to the model. To aid in analyzing and predicting the performance of UCG tests, we have developed a simple gas-compositional model. When the model was tested against experimental data from the three Hoe Creek experiments, it was able to match very closely the observed gas compositions, energy fractions, and water influxes. This model can be used to make performance predictions consistent with the material and energy balance constraints of the underground system. A postburn coring and wireline-logging study is under way at the Hoe Creek No. 3 site to investigate the overall effect of the directionally-drilled, horizontal linking hole to better estimate the amount of coal gasified and the shape of the combustion front, and to provide additional information on subsurface deformation and thermal effects. The site reclamation work was completed, including the dismantling of all surface equipment and piping and the plugging and sealing of process and diagnostics wells. Final grading of the reclaimed land has been completed, and the area is ready for disk-seeding. Our survey of the UCG literature has continued with a review of the extensive tests at Gorgas, Alabama, carried on by the US Bureau of Mines from 1947 to 1959.

  8. KRW oxygen-blown gasification combined cycle: Carbon dioxide recovery, transport, and disposal

    SciTech Connect (OSTI)

    Doctor, R.D.; Molburg, J.C.; Thimmapuram, P.R.

    1996-08-01T23:59:59.000Z

    This project emphasizes CO{sub 2}-capture technologies combined with integrated gasification combined-cycle (IGCC) power systems. Complementary evaluations address CO{sub 2} transportation, CO{sub 2} use, and options for the long-term sequestration of unused CO{sub 2}. The intent is to provide the CO{sub 2} budget, or an equivalent CO{sub 2} budget, associated with each of the individual energy-cycle steps, in addition to process design capital and operating costs. The base case is a 458-MW (gross generation) IGCC system that uses an oxygen-blown Kellogg-Rust-Westinghouse agglomerating fluidized-bed gasifier, Illinois No. 6 bituminous coal feed, and low-pressure glycol sulfur removal followed by Claus/SCOT treatment to produce a saleable product. Mining, feed preparation, and conversion result in a net electric power production for the entire energy cycle of 411 MW, with a CO{sub 2} release rate of 0.801 kg/k Whe. For comparison, in two cases, the gasifier output was taken through water-gas shift and then to low-pressure glycol H{sub 2}S recovery, followed by either low-pressure glycol or membrane CO{sub 2} recovery and then by a combustion turbine being fed a high-hydrogen-content fuel. Two additional cases employed chilled methanol for H{sub 2}S recovery and a fuel cell as the topping cycle with no shift stages. From the IGCC plant, a 500-km pipeline took the CO{sub 2} to geological sequestering. In a comparison of air-blown and oxygen-blown CO{sub 2}-release base cases, the cost of electricity for the air-blown IGCC was 56.86 mills/kWh, and the cost of oxygen-blown IGCC was 58.29 mills/kWh.

  9. Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment

    SciTech Connect (OSTI)

    Kevin Whitty

    2008-06-30T23:59:59.000Z

    The University of Utah's project 'Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment' (U.S. DOE Cooperative Agreement DE-FC26-04NT42261) was a response to U.S. DOE/NETL solicitation DE-PS36-04GO94002, 'Biomass Research and Development Initiative' Topical Area 4-Kraft Black Liquor Gasification. The project began September 30, 2004. The objective of the project was to improve the understanding of black liquor conversion in high pressure, high temperature reactors that gasify liquor through partial oxidation with either air or oxygen. The physical and chemical characteristics of both the gas and condensed phase were to be studied over the entire range of liquor conversion, and the rates and mechanisms of processes responsible for converting the liquor to its final smelt and syngas products were to be investigated. This would be accomplished by combining fundamental, lab-scale experiments with measurements taken using a new semi-pilot scale pressurized entrained-flow gasifier. As a result of insufficient availability of funds and changes in priority within the Office of Biomass Programs of the U.S. Department of Energy, the research program was terminated in its second year. In total, only half of the budgeted funding was made available for the program, and most of this was used during the first year for construction of the experimental systems to be used in the program. This had a severe impact on the program. As a consequence, most of the planned research was unable to be performed. Only studies that relied on computational modeling or existing experimental facilities started early enough to deliver useful results by the time to program was terminated Over the course of the program, small scale (approx. 1 ton/day) entrained-flow gasifier was designed and installed at the University of Utah's off-campus Industrial Combustion and Gasification Research Facility. The system is designed to operate at pressures as high as 32 atmospheres, and at temperatures as high as 1500 C (2730 F). Total black liquor processing capacity under pressurized, oxygen-blown conditions should be in excess of 1 ton black liquor solids per day. Many sampling ports along the conversion section of the system will allow detailed analysis of the environment in the gasifier under industrially representative conditions. Construction was mostly completed before the program was terminated, but resources were insufficient to operate the system. A system for characterizing black liquor sprays in hot environments was designed and constructed. Silhouettes of black liquor sprays formed by injection of black liquor through a twin fluid (liquor and atomizing air) nozzle were videoed with a high-speed camera, and the resulting images were analyzed to identify overall characteristics of the spray and droplet formation mechanisms. The efficiency of liquor atomization was better when the liquor was injected through the center channel of the nozzle, with atomizing air being introduced in the annulus around the center channel, than when the liquor and air feed channels were reversed. Atomizing efficiency and spray angle increased with atomizing air pressure up to a point, beyond which additional atomizing air pressure had little effect. Analysis of the spray patterns indicates that two classifications of droplets are present, a finely dispersed 'mist' of very small droplets and much larger ligaments of liquor that form at the injector tip and form one or more relatively large droplets. This ligament and subsequent large droplet formation suggests that it will be challenging to obtain a narrow distribution of droplet sizes when using an injector of this design. A model for simulating liquor spray and droplet formation was developed by Simulent, Inc. of Toronto. The model was able to predict performance when spraying water that closely matched the vendor specifications. Simulation of liquor spray indicates that droplets on the order 200-300 microns can be expected, and that higher liquor flow will result in be

  10. EARLY ENTRANCE CO-PRODUCTION PLANT - DECENTRALIZED GASIFICATION COGENERATION TRANSPORTATION FUELS AND STEAM FROM AVAILABLE FEEDSTOCKS

    SciTech Connect (OSTI)

    Unknown

    2003-01-01T23:59:59.000Z

    Waste Processors Management, Inc. (WMPI), along with its subcontractors Texaco Power & Gasification (now ChevronTexaco), SASOL Technology Ltd., and Nexant Inc. entered into a Cooperative Agreement DE-FC26-00NT40693 with the U. S. Department of Energy (DOE), National Energy Technology Laboratory (NETL) to assess the technoeconomic viability of building an Early Entrance Co-Production Plant (EECP) in the United States to produce ultra clean Fischer-Tropsch (FT) transportation fuels with either power or steam as the major co-product. The EECP design includes recovery and gasification of low-cost coal waste (culm) from physical coal cleaning operations and will assess blends of the culm with coal or petroleum coke. The project has three phases. Phase I is the concept definition and engineering feasibility study to identify areas of technical, environmental and financial risk. Phase II is an experimental testing program designed to validate the coal waste mixture gasification performance. Phase III updates the original EECP design based on results from Phase II, to prepare a preliminary engineering design package and financial plan for obtaining private funding to build a 5,000 barrel per day (BPD) coal gasification/liquefaction plant next to an existing co-generation plant in Gilberton, Schuylkill County, Pennsylvania. The current report covers the period performance from July 1, 2002 through September 30, 2002.

  11. Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs 

    E-Print Network [OSTI]

    Patel, S. S.

    1982-01-01T23:59:59.000Z

    effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per...

  12. Oil shale, tar sands, and underground coal gasification. Quarterly progress report, April-June 1984

    SciTech Connect (OSTI)

    Not Available

    1984-08-15T23:59:59.000Z

    Highlights of progress achieved during the quarter ending June 30, 1984 are summarized. This research involves three resource areas: oil shale, tar sands, and underground gasification of coal. Separate abstracts have been prepared for each section for inclusion in the Energy Database. (DMC)

  13. Gasification of low-grade fuels in a spouted bed for power generation

    SciTech Connect (OSTI)

    A.A. Belyaev [Institute for Fossil Fuels, Moscow (Russian Federation)

    2008-12-15T23:59:59.000Z

    Experimental data on the autothermal gasification of wastes from the flotation of Kuzbass coal of grade Zh and low-ash coal from the Kansk-Achinsk Basin in a spouted bed of an inert material at atmospheric pressure are presented. Capabilities for the development and use of this process for power generation based on closed-cycle gas turbine plants are analyzed.

  14. EIS-0429: Department of Energy Loan Guarantee for Indiana Integrated Gasification Combined Cycle, Rockport, IN

    Broader source: Energy.gov [DOE]

    This EIS evaluates the environmental impacts of a coal-to-substitute natural gas facility proposed to be built in Rockport, IN by Indiana Gasification. The facility would utilize Illinois Basin coal. Other products would be marketable sulfuric acid, argon, and electric power.

  15. EIS-0428: Department of Energy Loan Guarantee for Mississippi Integrated Gasification Combined Cycle, Moss Point, Mississippi

    Broader source: Energy.gov [DOE]

    This EIS evaluates the environmental impacts of a petroleum coke-to-substitute natural gas facility proposed to be built by Mississippi Gasification. The facility would be designed to produce 120 million standard cubic feet of gas per day. Other products would be marketable sulfuric acid, carbon dioxide, argon, and electric power.

  16. Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs

    E-Print Network [OSTI]

    Patel, S. S.

    1982-01-01T23:59:59.000Z

    effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per...

  17. Differences in gasification behaviors and related properties between entrained gasifier fly ash and coal char

    SciTech Connect (OSTI)

    Jing Gu; Shiyong Wu; Youqing Wu; Ye Li; Jinsheng Gao [East China University of Science and Technology, Shanghai (China). Department of Chemical Engineering for Energy Resources and Key Laboratory of Coal Gasification of Ministry of Education

    2008-11-15T23:59:59.000Z

    In the study, two fly ash samples from Texaco gasifiers were compared to coal char and the physical and chemical properties and reactivity of samples were investigated by scanning electron microscopy (SEM), SEM-energy-dispersive spectrometry (EDS), X-ray diffraction (XRD), N{sub 2} and CO{sub 2} adsorption method, and isothermal thermogravimetric analysis. The main results were obtained. The carbon content of gasified fly ashes exhibited 31-37%, which was less than the carbon content of 58-59% in the feed coal. The fly ashes exhibited higher Brunauer-Emmett-Teller (BET) surface area, richer meso- and micropores, more disordered carbon crystalline structure, and better CO{sub 2} gasification reactivity than coal char. Ashes in fly ashes occurred to agglomerate into larger spherical grains, while those in coal char do not agglomerate. The minerals in fly ashes, especial alkali and alkaline-earth metals, had a catalytic effect on gasification reactivity of fly ash carbon. In the low-temperature range, the gasification process of fly ashes is mainly in chemical control, while in the high-temperature range, it is mainly in gas diffusion control, which was similar to coal char. In addition, the carbon in fly ashes was partially gasified and activated by water vapor and exhibited higher BET surface area and better gasification activity. Consequently, the fact that these carbons in fly ashes from entrained flow gasifiers are reclaimed and reused will be considered to be feasible. 15 refs., 7 figs., 5 tabs.

  18. Bench-scale development of mild gasification char desulfurization. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Knight, R.A. [Inst. of Gas Technology, Chicago, IL (United States)

    1994-09-01T23:59:59.000Z

    The goal of this project is to scale up a process, developed under a previous ICCI grant, for desulfurization of mild gasification char by treatment with hydrogen-rich process-derived fuel gas at 650--760 C and 7--15 atm. The char can be converted into a low-sulfur metallurgical form coke. In the prior study, IBC-105 coal with 4.0 wt% sulfur was converted to chars with less than 1.0 wt% sulfur in a laboratory-scale batch reactor. The susceptibility of the char to desulfurization was correlated with physicochemical char properties and mild gasification conditions. Acid pretreatment of the coal prior to mild gasification was also shown to significantly enhance subsequent sulfur removal. In this study, IGT is conducting continuous bench-scale tests in a 1-lb/h fluidized-bed reactor to determine the preferred process conditions and obtain steady-state data necessary for process design and scale-up. The desulfurized chars are to be used to produce low-sulfur form coke, which will be evaluated for density, reactivity, and strength properties relevant to utilization in blast furnaces. This quarter, 2,500 g of mild gasification char was produced from untreated IBC-105 coal in the bench-scale reactor. Half of this char will be subjected to sulfuric acid treatment to enhance subsequent desulfurization. Char-producing runs were also initiated with acid-pretreated coal, which will produce about 1,250 g of char.

  19. LLNL Underground-Coal-Gasification Project. Quarterly progress report, July-September 1981

    SciTech Connect (OSTI)

    Stephens, D.R.; Clements, W. (eds.) [eds.

    1981-11-09T23:59:59.000Z

    We have continued our laboratory studies of forward gasification in small blocks of coal mounted in 55-gal drums. A steam/oxygen mixture is fed into a small hole drilled longitudinally through the center of the block, the coal is ignited near the inlet and burns toward the outlet, and the product gases come off at the outlet. Various diagnostic measurements are made during the course of the burn, and afterward the coal block is split open so that the cavity can be examined. Development work continues on our mathematical model for the small coal block experiments. Preparations for the large block experiments at a coal outcrop in the Tono Basin of Washington State have required steadily increasing effort with the approach of the scheduled starting time for the experiments (Fall 1981). Also in preparation is the deep gasification experiment, Tono 1, planned for another site in the Tono Basin after the large block experiments have been completed. Wrap-up work continues on our previous gasification experiments in Wyoming. Results of the postburn core-drilling program Hoe Creek 3 are presented here. Since 1976 the Soviets have been granted four US patents on various aspects of the underground coal gasification process. These patents are described here, and techniques of special interest are noted. Finally, we include ten abstracts of pertinent LLNL reports and papers completed during the quarter.

  20. Performance of solid oxide fuel cells operated with coal syngas provided directly from a gasification process

    SciTech Connect (OSTI)

    Hackett, Gregory A.; Gerdes, Kirk R.; Song, Xueyan; Chen, Yun; Shutthanandan, V.; Engelhard, Mark H.; Zhu, Zihua; Thevuthasan, Suntharampillai; Gemmen, Randall

    2012-09-15T23:59:59.000Z

    Solid oxide fuel cells (SOFCs) are presently being developed for gasification integrated power plants that generate electricity from coal at 50+% efficiency. The interaction of trace metals in coal syngas with the Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but direct test data from coal syngas exposure are sparsely available. This research effort evaluates the significance of SOFC performance losses associated with exposure of a SOFC anode to direct coal syngas. SOFC specimen of industrially relevant composition are operated in a unique mobile test skid that was deployed to the research gasifier at the National Carbon Capture Center (NCCC) in Wilsonville, AL. The mobile test skid interfaces with a gasifier slipstream to deliver hot syngas (up to 300°C) directly to a parallel array of 12 button cell specimen, each of which possesses an active area of approximately 2 cm2. During the 500 hour test period, all twelve cells were monitored for performance at four discrete operating current densities, and all cells maintained contact with a data acquisition system. Of these twelve, nine demonstrated good performance throughout the test, while three of the cells were partially compromised. Degradation associated with the properly functioning cells was attributed to syngas exposure and trace material attack on the anode structure that was accelerated at increasing current densities. Cells that were operated at 0 and 125 mA/cm² degraded at 9.1 and 10.7% per 1000 hours, respectively, while cells operated at 250 and 375 mA/cm² degraded at 18.9 and 16.2% per 1000 hours, respectively. Post-trial spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

  1. Thermal-Hydrological Sensitivity Analysis of Underground Coal Gasification

    SciTech Connect (OSTI)

    Buscheck, T A; Hao, Y; Morris, J P; Burton, E A

    2009-10-05T23:59:59.000Z

    This paper presents recent work from an ongoing project at Lawrence Livermore National Laboratory (LLNL) to develop a set of predictive tools for cavity/combustion-zone growth and to gain quantitative understanding of the processes and conditions (natural and engineered) affecting underground coal gasification (UCG). We discuss the application of coupled thermal-hydrologic simulation capabilities required for predicting UCG cavity growth, as well as for predicting potential environmental consequences of UCG operations. Simulation of UCG cavity evolution involves coupled thermal-hydrological-chemical-mechanical (THCM) processes in the host coal and adjoining rockmass (cap and bedrock). To represent these processes, the NUFT (Nonisothermal Unsaturated-saturated Flow and Transport) code is being customized to address the influence of coal combustion on the heating of the host coal and adjoining rock mass, and the resulting thermal-hydrological response in the host coal/rock. As described in a companion paper (Morris et al. 2009), the ability to model the influence of mechanical processes (spallation and cavity collapse) on UCG cavity evolution is being developed at LLNL with the use of the LDEC (Livermore Distinct Element Code) code. A methodology is also being developed (Morris et al. 2009) to interface the results of the NUFT and LDEC codes to simulate the interaction of mechanical and thermal-hydrological behavior in the host coal/rock, which influences UCG cavity growth. Conditions in the UCG cavity and combustion zone are strongly influenced by water influx, which is controlled by permeability of the host coal/rock and the difference between hydrostatic and cavity pressure. In this paper, we focus on thermal-hydrological processes, examining the relationship between combustion-driven heat generation, convective and conductive heat flow, and water influx, and examine how the thermal and hydrologic properties of the host coal/rock influence those relationships. Specifically, we conducted a parameter sensitivity analysis of the influence of thermal and hydrological properties of the host coal, caprock, and bedrock on cavity temperature and steam production.

  2. Characterizing and modeling combustion of mild-gasification chars in pressurized fluidized beds

    SciTech Connect (OSTI)

    Daw, C.S.

    1995-10-01T23:59:59.000Z

    Oak Ridge National Laboratory (ORNL) is supported by the Morgantown Energy Technology Center (METC) of the Department of Energy (DOE) under FWP-FEAA310 to characterize the fuel properties of liquid and char coproducts from the mild gasification of coal, Because most of the energy content of coals subjected to mild gasification is retained in the byproduct char, efficient and cost-effective utilization of the char is essential in insuring that candidate gasification processes are commercially viable. One potential use for char of particular interest to DOE is pressurized fluidized bed combustion (PFBC). PFBC is of particular interest because it has the potential for 10 to 30 percent greater overall energy efficiency than atmospheric fluidized bed combustion (AFBC), While bench-scale tools and analytical procedures for characterizing fuels for AFBC have been recently demonstrated, no such tools have been reliably demonstrated for PFBC. This report summarizes the results of joint research collaboration between ORNL and B&W that has been directed at modifying the previously developed AFBC fuel characterization procedures to be applicable for mild-gasification chars and PFBC conditions. The specific objectives were to: (1) characterize the combustion reactivity of a selected set of candidate mild- gasification chars at PFB conditions; (2) compare the measured char characteristics with those of more conventional PFBC fuels; (3) modify an AFBC computer code previously developed by B&W and ORNL for the Electric Power Research Institute (EPRI) to predict PFBC performance; and (4) apply the modified code and measured char combustion characteristics to make performance predictions for the candidate chars relative to more conventional fuels.

  3. Improving process performances in coal gasification for power and synfuel production

    SciTech Connect (OSTI)

    M. Sudiro; A. Bertucco; F. Ruggeri; M. Fontana [University of Padova, Milan (Italy). Italy and Foster Wheeler Italiana Spa

    2008-11-15T23:59:59.000Z

    This paper is aimed at developing process alternatives of conventional coal gasification. A number of possibilities are presented, simulated, and discussed in order to improve the process performances, to avoid the use of pure oxygen, and to reduce the overall CO{sub 2} emissions. The different process configurations considered include both power production, by means of an integrated gasification combined cycle (IGCC) plant, and synfuel production, by means of Fischer-Tropsch (FT) synthesis. The basic idea is to thermally couple a gasifier, fed with coal and steam, and a combustor where coal is burnt with air, thus overcoming the need of expensive pure oxygen as a feedstock. As a result, no or little nitrogen is present in the syngas produced by the gasifier; the required heat is transferred by using an inert solid as the carrier, which is circulated between the two modules. First, a thermodynamic study of the dual-bed gasification is carried out. Then a dual-bed gasification process is simulated by Aspen Plus, and the efficiency and overall CO{sub 2} emissions of the process are calculated and compared with a conventional gasification with oxygen. Eventually, the scheme with two reactors (gasifier-combustor) is coupled with an IGCC process. The simulation of this plant is compared with that of a conventional IGCC, where the gasifier is fed by high purity oxygen. According to the newly proposed configuration, the global plant efficiency increases by 27.9% and the CO{sub 2} emissions decrease by 21.8%, with respect to the performances of a conventional IGCC process. 29 refs., 7 figs., 5 tabs.

  4. The U.S. Department of Energy`s integrated gasification combined cycle research, development and demonstration program

    SciTech Connect (OSTI)

    Brdar, R.D.; Cicero, D.C.

    1996-07-01T23:59:59.000Z

    Historically, coal has played a major role as a fuel source for power generation both domestically and abroad. Despite increasingly stringent environmental constraints and affordable natural gas, coal will remain one of the primary fuels for producing electricity. This is due to its abundance throughout the world, low price, ease of transport an export, decreasing capital cost for coal-based systems, and the need to maintain fuel diversity. Recognizing the role coal will continue to play, the US Department of Energy (DOE) is working in partnership with industry to develop ways to use this abundant fuel resource in a manner that is more economical, more efficient and environmentally superior to conventional means to burn coal. The most promising of these technologies is integrated gasification combined cycle (IGCC) systems. Although IGCC systems offer many advantages, there are still several hurdles that must be overcome before the technology achieves widespread commercial acceptance. The major hurdles to commercialization include reducing capital and operating costs, reducing technical risk, demonstrating environmental and technical performance at commercial scale, and demonstrating system reliability and operability. Overcoming these hurdles, as well as continued progress in improving system efficiency, are the goals of the DOE IGCC research, development and demonstrate (RD and D) program. This paper provides an overview of this integrated RD and D program and describes fundamental areas of technology development, key research projects and their related demonstration scale activities.

  5. Behavior of chars from Bursa Mustafa Kemal Pasa Alpagut and Balkesir Dursunbey Cakiirca Lignite (Turkey) during non-catalytic and catalytic gasification

    SciTech Connect (OSTI)

    Bozkurt, Y.; Misirlioglu, Z.; Sinag, A.; Tekes, A.T.; Canel, M. [Ankara University, Ankara (Turkey). Dept. of Chemistry

    2008-07-01T23:59:59.000Z

    The reactivities of chars obtained by pyrolysis of Bursa Mustafa Kemal Pasa Alpagut lignite and Balkesir Dursunbey Cakiirca lignite (Turkey) at different temperatures were determined by CO{sub 2} gasification and by combustion with O{sub 2}. Catalytic effect of Na{sub 2}CO{sub 3} on the CO{sub 2} and O{sub 2} gasification reactivity of chars was investigated. Gasification tests were performed in the fixed bed reactors operating at ambient pressure. Reactivity of chars during the CO{sub 2} gasification reactions was determined by calculating the reaction rate constants and reactivity of chars during the O{sub 2} gasification was determined by using ignition temperatures of the samples. Activation energies and Arrhenius constants of the chars on the CO{sub 2} gasification reactions were also calculated by the help of Arrhenius curves. The activation energy for CO{sub 2} gasification was generally decreased with pyrolysis temperature, due to the different surface characteristics and different nature of carbon atoms gasified as the gasification reactions proceed. Generally, the increase in pyrolysis temperature leads to an increase in gasification reactivity with CO{sub 2}. The reactivity of chars in catalytic gasification was higher than the corresponding non-catalytic reactivity of the same chars. Ignition temperature increased with increasing pyrolysis temperature.

  6. Hot gas cleanup test facility for gasification and pressurized combustion. Quarterly technical progress report, January 1--March 31, 1992

    SciTech Connect (OSTI)

    Not Available

    1992-12-01T23:59:59.000Z

    This quarterly technical progress report summarizes work completed during the Sixth Quarter of the First Budget Period, January 1 through March 31, 1992, under the Department of Energy (DOE) Cooperative Agreement No. DE-FC21-90MC25140 entitled ``Hot Gas Cleanup Test Facility for Gasification and Pressurized Combustion.`` The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. The major emphasis during this reporting period was expanding the test facility to address system integration issues of hot particulate removal in advanced power generation systems. The conceptual design of the facility was extended to include additional modules for the expansion of the test facility, which is referred to as the Power Systems Development Facility (PSOF). A letter agreement was negotiated between Southern Company Services (SCS) and Foster Wheeler (FW) for the conceptual design of the Advanced Pressurized Fluid-Bed Combustion (APFBC)/Topping Combustor/Gas Turbine System to be added to the facility. The expanded conceptual design also included modifications to the existing conceptual design for the Hot Gas Cleanup Test Facility (HGCTF), facility layout and balance of plant design for the PSOF. Southern Research Institute (SRI) began investigating the sampling requirements for the expanded facility and assisted SCS in contacting Particulate Control Device (PCD) vendors for additional information. SCS also contacted the Electric Power Research Institute (EPRI) and two molten carbonate fuel cell vendors for input on the fuel cell module for the PSDF.

  7. Fluid-Bed Testing of Greatpoint Energy's Direct Oxygen Injection Catalytic Gasification Process for Synthetic Natural Gas and Hydrogen Coproduction Year 6 - Activity 1.14 - Development of a National Center for Hydrogen Technology

    SciTech Connect (OSTI)

    Swanson, Michael; Henderson, Ann

    2012-04-01T23:59:59.000Z

    The GreatPoint Energy (GPE) concept for producing synthetic natural gas and hydrogen from coal involves the catalytic gasification of coal and carbon. GPE’s technology “refines” coal by employing a novel catalyst to “crack” the carbon bonds and transform the coal into cleanburning methane (natural gas) and hydrogen. The GPE mild “catalytic” gasifier design and operating conditions result in reactor components that are less expensive and produce pipeline-grade methane and relatively high purity hydrogen. The system operates extremely efficiently on very low cost carbon sources such as lignites, subbituminous coals, tar sands, petcoke, and petroleum residual oil. In addition, GPE’s catalytic coal gasification process eliminates troublesome ash removal and slagging problems, reduces maintenance requirements, and increases thermal efficiency, significantly reducing the size of the air separation plant (a system that alone accounts for 20% of the capital cost of most gasification systems) in the catalytic gasification process. Energy & Environmental Research Center (EERC) pilot-scale gasification facilities were used to demonstrate how coal and catalyst are fed into a fluid-bed reactor with pressurized steam and a small amount of oxygen to “fluidize” the mixture and ensure constant contact between the catalyst and the carbon particles. In this environment, the catalyst facilitates multiple chemical reactions between the carbon and the steam on the surface of the coal. These reactions generate a mixture of predominantly methane, hydrogen, and carbon dioxide. Product gases from the process are sent to a gas-cleaning system where CO{sub 2} and other contaminants are removed. In a full-scale system, catalyst would be recovered from the bottom of the gasifier and recycled back into the fluid-bed reactor. The by-products (such as sulfur, nitrogen, and CO{sub 2}) would be captured and could be sold to the chemicals and petroleum industries, resulting in near-zero hazardous air or water pollution. This technology would also be conducive to the efficient coproduction of methane and hydrogen while also generating a relatively pure CO{sub 2} stream suitable for enhanced oil recovery (EOR) or sequestration. Specific results of bench-scale testing in the 4- to 38-lb/hr range in the EERC pilot system demonstrated high methane yields approaching 15 mol%, with high hydrogen yields approaching 50%. This was compared to an existing catalytic gasification model developed by GPE for its process. Long-term operation was demonstrated on both Powder River Basin subbituminous coal and on petcoke feedstocks utilizing oxygen injection without creating significant bed agglomeration. Carbon conversion was greater than 80% while operating at temperatures less than 1400°F, even with the shorter-than-desired reactor height. Initial designs for the GPE gasification concept called for a height that could not be accommodated by the EERC pilot facility. More gas-phase residence time should allow the syngas to be converted even more to methane. Another goal of producing significant quantities of highly concentrated catalyzed char for catalyst recovery and material handling studies was also successful. A Pd–Cu membrane was also successfully tested and demonstrated to produce 2.54 lb/day of hydrogen permeate, exceeding the desired hydrogen permeate production rate of 2.0 lb/day while being tested on actual coal-derived syngas that had been cleaned with advanced warm-gas cleanup systems. The membranes did not appear to suffer any performance degradation after exposure to the cleaned, warm syngas over a nominal 100-hour test.

  8. Experimental program for the development of peat gasification. Final report for Project No. 65003, February 10, 1976-January 3, 1983. [Contains list of 15 interim reports and brief summaries of each

    SciTech Connect (OSTI)

    Not Available

    1983-07-01T23:59:59.000Z

    The results of the program have demonstrated that, on the basis of chemistry and kinetics, peat is an excellent feedstock for the production of SNG and other gaseous and liquid fuels. Peat gasifies at a much faster rate than does lignite or other coals, and high carbon conversions can be achieved with peat at relatively low severity conditions. In hydrogasification, the product mix (gases and liquids) can be varied over a much greater range than that of lignite or other coals, to satisfy seasonally changing consumer demands. Over 200 tests were conducted in laboratory- and PDU-scale equipment with different peats to determine the effects of temperature, pressure, feedstock, feed gas composition, residence time, and other operating parameters on the gasification of peat. A mathematical model was developed that closely describes the effects of operating conditions on peat gasification. These results formed the data base for the PEATGAS process development at the pilot-plant scale. Tests with peats from different geographic locations showed the effect of feedstock source on gasification. The effect of peat dewatering methodologies (including harvesting techniques and mechanical and thermal dewatering methods) on gasification was also studied. Wet carbonization tests were conducted. Wet carbonization is a thermochemical beneficiation process that improves the heating value and dewaterability of peat. The laboratory test program was the first systemic study of the effects of wet carbonization on the carbon and oxygen conversions and heating value enhancements of peat to appear in the open literature. The PDU-test program included the design, construction, and operation of an integrated computer-controlled wet carbonization unit.

  9. LLL in situ coal gasification project. Quarterly progress report, October-December 1979. [Hoe Creek No. 3 and planning

    SciTech Connect (OSTI)

    Cena, R.J.; Strack, B.S. (eds.)

    1980-04-23T23:59:59.000Z

    The major effort this quarter has been postexperiment analysis of Hoe Creek No. 3 and planning for future gasification experiments. Hoe Creek No. 3: Thermal data have been analyzed to determine the performance of the drilled horizontal channel during forward gasification. Thermal and material balance data are combined to determine late-time burn boundaries for the experiment. Surface subsidence after the experiment was completed is described. Process wells were inspected to determine failure characteristics and pinpoint late-time injection location. Ground-water quality before and after Hoe Creek No. 3 and the effects of aquifer interconnection on hydraulic measurements at the Hoe Creek No. 2 and No. 3 sites are discussed. Future experiments: Potential UCG sites are being characterized for future tests. Two sites in the Powder River Basin near Gillette, Wyoming are discussed. Preliminary plans for a deep site gasification experiment and a new method for in situ gasification of thick seams are presented.

  10. An investigation of changes in groundwater quality caused by in-situ gasification of East Texas lignite 

    E-Print Network [OSTI]

    Leach, Kimberly Sue

    1988-01-01T23:59:59.000Z

    AN INVESTIGATION OF CHANGES IN GROUNDWATER QUALITY CAUSED BY IN-SITU GASIFICATION OF EAST TEXAS LIGNITE A Thesis by KIMBERLY SUE LEACH Submitted to the Graduate College of Texas AGM University in Partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1988 Major Subject: Petroleum Engineering AN INVESTIGATION OF CHANGES IN GROUNDWATER QUALITY CAUSED BY IN-SITU GASIFICATION OF EAST TEXAS LIGNITE A Thesis by KIMBERLY SUE LEACH Approved as to style and content by...

  11. An investigation of changes in groundwater quality caused by in-situ gasification of East Texas lignite

    E-Print Network [OSTI]

    Leach, Kimberly Sue

    1988-01-01T23:59:59.000Z

    to lignite gasification at the Hoe Creek site were determined not to be a serious groundwater quality problem, similar work needs to be done at the Rockdale site due to varying geological controls. LIGNITE Lignite is a low grade coal intermediate between...AN INVESTIGATION OF CHANGES IN GROUNDWATER QUALITY CAUSED BY IN-SITU GASIFICATION OF EAST TEXAS LIGNITE A Thesis by KIMBERLY SUE LEACH Submitted to the Graduate College of Texas AGM University in Partial fulfillment of the requirements...

  12. Fundamental Study of Black Liquor Gasification Kinetics. Quarterly progress report for the period October 1999 to December 1999

    SciTech Connect (OSTI)

    NONE

    2000-01-31T23:59:59.000Z

    The overall objective of this research is to evaluate the kinetics of gasification of kraft black liquor under laboratory conditions simulating pressurized, oxygen-blown gasification. The significant independent variables are gasifier temperature, black liquor composition particle size, and particle residence time. The authors will quantify their impact on the concentration of major and trace gas phase species, as well as the composition of condensed phase inorganic products, including specification of the Na- and S-containing compounds and overall carbon conversion.

  13. TVA coal-gasification commercial demonstration plant project. Volume 5. Plant based on Koppers-Totzek gasifier. Final report

    SciTech Connect (OSTI)

    Not Available

    1980-11-01T23:59:59.000Z

    This volume presents a technical description of a coal gasification plant, based on Koppers-Totzek gasifiers, producing a medium Btu fuel gas product. Foster Wheeler carried out a conceptual design and cost estimate of a nominal 20,000 TPSD plant based on TVA design criteria and information supplied by Krupp-Koppers concerning the Koppers-Totzek coal gasification process. Technical description of the design is given in this volume.

  14. Combined cycle power plant of SVZ Schwarze Pumpe GmbH operating experience gained with low calorific value fuel resulting from gasification processes

    SciTech Connect (OSTI)

    Kotschenreuther, H.; Hauptmann, W.

    1998-07-01T23:59:59.000Z

    Supported by experience gained over many years, Schwarze Pumpe GmbH (SVZ), the secondary raw material recycling centre, operates autothermal compression-type gasification plants with oxygen according to the fixed-bed and the entrained flow process, in which apart from lignite as the fuel to be gasified, residues containing C/H of varying consistency are gasified in an environmentally friendly manner. The purified gas acquired after scrubbing, partial conversion and desulfurization is mainly used as a synthesis gas for methanol synthesis and thus provided with a material use. For covering auxiliary requirements in electrical and process power, a combined-cycle power plant is operated, the main fuel of which is a low calorific value dual-process gas, primarily consisting of purified and purge gas. The volumes of purified and purge gases available to the combined-cycle power plant from the SVZ process equipment and their grades cannot be influenced by the combined-cycle power plant. It is shown that from a targeted modification of the dual-process gas temperature the Wobbe Index of dual-process gases with considerably varying parameters (calorific value, density) can be brought into the range required for running the gas turbine. Furthermore what is also shown is the operating strategy and control concept by which the combined-cycle power plant can maintain the pressure in the SVZ purified gas system and thus ultimately the gasification reactor operating pressure.

  15. Peat gasification pilot plant program. Project 70105 quarterly report No. 1, October 1, 1980-August 31, 1981

    SciTech Connect (OSTI)

    Not Available

    1982-09-01T23:59:59.000Z

    Over 200 peat gasification tests were conducted in laboratory-scale and PDU-scale (process development unit) equipment since 1976. A kinetic model for peat gasification was developed from laboratory and PDU data. The encouraging results of these tests and the model projections show that on the basis of its chemistry and kinetics, peat is an excellent raw material for commercial synthetic natural gas (SNG) production. To further advance peat gasification technology, DOE and GRI initiated a pilot-plant-scale program using an existing coal gasification pilot plant. This facility was adapted to peat processing and can convert 50 tons of peat to about 0.5 million standard cubic feet of SNG daily. The pilot plant is described in Appendix A. Only three major pieces of equipment - a peat dryer, a grinder, and a screener - were required to prepare the pilot plant for peat processing. This modification phase was completed in the winter of 1980-1981. After a number of drying, grinding, and screening tests, peat was first fed to the gasifier in April 1981, initiating the pilot plant studies to develop the PEATGAS process. Since that time, the gasification of Minnesota peat by the PEATGAS process has been successfully demonstrated in a series of gasification tests. This report covers the work done between October 1, 1980, and August 31, 1981, under DOE Contract No. AC01-80ET14688.

  16. Hot gas cleanup test facility for gasification and pressurized combustion project. Quarterly report, October--December 1995

    SciTech Connect (OSTI)

    NONE

    1996-02-01T23:59:59.000Z

    The objective of this project is to evaluate hot gas particle control technologies using coal-derived gas streams. This will entail the design, construction, installation, and use of a flexible test facility which can operate under realistic gasification and combustion conditions. The conceptual design of the facility was extended to include a within scope, phased expansion of the existing Hot Gas Cleanup Test Facility Cooperative Agreement to also address systems integration issues of hot particulate removal in advanced coal-based power generation systems. This expansion included the consideration of the following modules at the test facility in addition to the original Transport Reactor gas source and Hot Gas Cleanup Units: Carbonizer/pressurized circulating fluidized bed gas source; hot gas cleanup units to mate to all gas streams; combustion gas turbine; and fuel cell and associated gas treatment. This expansion to the Hot Gas Cleanup Test Facility is herein referred to as the Power Systems Development Facility (PSDF). The major emphasis during this reporting period was continuing the detailed design of the facility towards completion and integrating the balance-of-plant processes and particulate control devices (PCDs) into the structural and process designs. Substantial progress in construction activities was achieved during this quarter.

  17. NOVEL COMPOSITE MEMBRANES FOR HYDROGEN SEPARATION IN GASIFICATION PROCESSES IN VISION 21 ENERGY PLANTS

    SciTech Connect (OSTI)

    Michael Schwartz

    2004-01-01T23:59:59.000Z

    ITN Energy Systems, along with its team members, the Idaho National Engineering and Environmental Laboratory, Nexant Consulting, Argonne National Laboratory and Praxair, propose to develop a novel composite membrane structure for hydrogen separation as a key technology module within the future ''Vision 21'' fossil fuel plants. The ITN team is taking a novel approach to hydrogen separation membrane technology where fundamental engineering material development is fully integrated into fabrication designs; combining functionally graded materials, monolithic module concept and plasma spray manufacturing techniques. The technology is based on the use of Ion Conducting Ceramic Membranes (ICCM) for the selective transport of hydrogen. The membranes are comprised of composites consisting of a proton conducting ceramic and a second metallic phase to promote electrical conductivity. Functional grading of the membrane components allows the fabrication of individual membrane layers of different materials, microstructures and functions directly into a monolithic module. Plasma spray techniques, common in industrial manufacturing, are well suited for fabricating ICCM hydrogen separation modules inexpensively, yielding compact membrane modules that are amenable to large scale, continuous manufacturing with low costs. This program will develop and evaluate composite membranes and catalysts for hydrogen separation. Components of the monolithic modules will be fabricated by plasma spray processing. The engineering and economic characteristics of the proposed ICCM approach, including system integration issues, will also be assessed. This will result in a complete evaluation of the technical and economic feasibility of ICCM hydrogen separation for implementation within the ''Vision 21'' fossil fuel plant. The ICCM hydrogen separation technology is targeted for use within the gasification module of the ''Vision 21'' fossil fuel plant. The high performance and low-cost manufacturing of the proposed technology will benefit the deployment of ''Vision 21'' fossil fuel plant processes by improving the energy efficiency, flexibility and environmental performance of these plants. Of particular importance is that this technology will also produce a stream of pure carbon dioxide. This allows facile sequestration or other use of this greenhouse gas. These features will benefit the U.S. in allowing for the continued use of domestic fossil fuels in a more energy efficient and environmentally acceptable manner.

  18. Novel Composite Membranes for Hydrogen Separation in Gasification Processes in Vision 21 Energy Plants

    SciTech Connect (OSTI)

    Schwartz, Michael

    2001-11-06T23:59:59.000Z

    ITN Energy Systems, Inc. (ITN) and its partners, the Idaho National Engineering and Environmental Laboratory, Argonne National Laboratory, Nexant Consulting, LLC and Praxair, Inc. are developing composite membranes for hydrogen separation as a key technology module within the future ''Vision 21'' fossil fuel plants. The ITN team is pursuing a novel approach to hydrogen separation membrane technology where fundamental engineering material development is fully integrated into module fabrication designs; combining functionally-graded materials, monolithic module concept and thermal spray manufacturing techniques. The technology is based on the use of Ion Conducting Ceramic Membranes (ICCM) for the selective transport of hydrogen. The membranes are comprised of composites consisting of a proton conducting ceramic and a second metallic phase to promote electrical conductivity. Functional grading of the membrane components allows for the fabrication of individual membrane layers of different materials, microstructures and functions directly into a monolithic module. Plasma spray techniques, common in industrial manufacturing, are well suited for fabricating ICCM hydrogen separation modules inexpensively, yielding compact membrane modules that are amenable to large scale, continuous manufacturing techniques with low costs. The engineering and economic characteristics of the proposed ICCM approach, including system integration issues, are being assessed. This will result in an evaluation of the technical and economic feasibility of the proposed ICCM hydrogen separation approach for implementation within the ''Vision 21'' fossil fuel plant. The ICCM hydrogen separation technology is targeted for use within the gasification module of the ''Vision 21'' fossil fuel plant. The high performance and low-cost manufacturing of the proposed technology will benefit the deployment of ''Vision 21'' fossil fuel plant processes by improving the energy efficiency, flexibility and environmental performance of such plants. Of particular importance is that the proposed technology also results in a stream of pure carbon dioxide. This allows for the facile sequestration or other use of this greenhouse gas. These features will benefit the U.S. in allowing for the continued use of domestic fossil fuels in a more energy efficient and environmentally acceptable manner.

  19. NOVEL COMPOSITE MEMBRANES FOR HYDROGEN SEPARATION IN GASIFICATION PROCESSES IN VISION 21 ENERGY PLANTS

    SciTech Connect (OSTI)

    Michael Schwartz

    2003-07-01T23:59:59.000Z

    ITN Energy Systems, along with its team members, the Idaho National Engineering and Environmental Laboratory, Nexant Consulting, Argonne National Laboratory and Praxair, propose to develop a novel composite membrane structure for hydrogen separation as a key technology module within the future ''Vision 21'' fossil fuel plants. The ITN team is taking a novel approach to hydrogen separation membrane technology where fundamental engineering material development is fully integrated into fabrication designs; combining functionally graded materials, monolithic module concept and plasma spray manufacturing techniques. The technology is based on the use of Ion Conducting Ceramic Membranes (ICCM) for the selective transport of hydrogen. The membranes are comprised of composites consisting of a proton conducting ceramic and a second metallic phase to promote electrical conductivity. Functional grading of the membrane components allows the fabrication of individual membrane layers of different materials, microstructures and functions directly into a monolithic module. Plasma spray techniques, common in industrial manufacturing, are well suited for fabricating ICCM hydrogen separation modules inexpensively, yielding compact membrane modules that are amenable to large scale, continuous manufacturing with low costs. This program will develop and evaluate composite membranes and catalysts for hydrogen separation. Components of the monolithic modules will be fabricated by plasma spray processing. The engineering and economic characteristics of the proposed ICCM approach, including system integration issues, will also be assessed. This will result in a complete evaluation of the technical and economic feasibility of ICCM hydrogen separation for implementation within the ''Vision 21'' fossil fuel plant. The ICCM hydrogen separation technology is targeted for use within the gasification module of the ''Vision 21'' fossil fuel plant. The high performance and low-cost manufacturing of the proposed technology will benefit the deployment of ''Vision 21'' fossil fuel plant processes by improving the energy efficiency, flexibility and environmental performance of these plants. Of particular importance is that this technology will also produce a stream of pure carbon dioxide. This allows facile sequestration or other use of this greenhouse gas. These features will benefit the U.S. in allowing for the continued use of domestic fossil fuels in a more energy efficient and environmentally acceptable manner.

  20. NOVEL COMPOSITE MEMBRANES FOR HYDROGEN SEPARATION IN GASIFICATION PROCESSES IN VISION 21 ENERGY PLANTS

    SciTech Connect (OSTI)

    Michael Schwartz

    2003-10-01T23:59:59.000Z

    ITN Energy Systems, along with its team members, the Idaho National Engineering and Environmental Laboratory, Nexant Consulting, Argonne National Laboratory and Praxair, propose to develop a novel composite membrane structure for hydrogen separation as a key technology module within the future ''Vision 21'' fossil fuel plants. The ITN team is taking a novel approach to hydrogen separation membrane technology where fundamental engineering material development is fully integrated into fabrication designs; combining functionally graded materials, monolithic module concept and plasma spray manufacturing techniques. The technology is based on the use of Ion Conducting Ceramic Membranes (ICCM) for the selective transport of hydrogen. The membranes are comprised of composites consisting of a proton conducting ceramic and a second metallic phase to promote electrical conductivity. Functional grading of the membrane components allows the fabrication of individual membrane layers of different materials, microstructures and functions directly into a monolithic module. Plasma spray techniques, common in industrial manufacturing, are well suited for fabricating ICCM hydrogen separation modules inexpensively, yielding compact membrane modules that are amenable to large scale, continuous manufacturing with low costs. This program will develop and evaluate composite membranes and catalysts for hydrogen separation. Components of the monolithic modules will be fabricated by plasma spray processing. The engineering and economic characteristics of the proposed ICCM approach, including system integration issues, will also be assessed. This will result in a complete evaluation of the technical and economic feasibility of ICCM hydrogen separation for implementation within the ''Vision 21'' fossil fuel plant. The ICCM hydrogen separation technology is targeted for use within the gasification module of the ''Vision 21'' fossil fuel plant. The high performance and low-cost manufacturing of the proposed technology will benefit the deployment of ''Vision 21'' fossil fuel plant processes by improving the energy efficiency, flexibility and environmental performance of these plants. Of particular importance is that this technology will also produce a stream of pure carbon dioxide. This allows facile sequestration or other use of this greenhouse gas. These features will benefit the U.S. in allowing for the continued use of domestic fossil fuels in a more energy efficient and environmentally acceptable manner.