Sample records for gases regulated emissions

  1. The greenhouse gases HFCs, PFCs Danish consumption and emissions, 2007

    E-Print Network [OSTI]

    The greenhouse gases HFCs, PFCs and SF6 Danish consumption and emissions, 2007 Tomas Sander Poulsen AND EMISSION OF F-GASES 7 1.1.1 Consumption 7 1.1.2 Emission 7 1.1.3 Trends in total GWP contribution from F 21 4 EMISSION OF F-GASES 23 4.1.1 Emissions of HFCs from refrigerants 23 4.1.2 Emissions of HFCs from

  2. Emissions Of Greenhouse Gases From Rice Agriculture

    SciTech Connect (OSTI)

    M. Aslam K. Khalil

    2009-07-16T23:59:59.000Z

    This project produced detailed data on the processes that affect methane and nitrous oxide emissions from rice agriculture and their inter-relationships. It defines the shifting roles and potential future of these gases in causing global warming and the benefits and tradeoffs of reducing emissions. The major results include: 1). Mechanisms and Processes Leading to Methane Emissions are Delineated. Our experiments have tested the standard model of methane emissions from rice fields and found new results on the processes that control the flux. A mathematical mass balance model was used to unravel the production, oxidation and transport of methane from rice. The results suggested that when large amounts of organic matter are applied, the additional flux that is observed is due to both greater production and reduced oxidation of methane. 2). Methane Emissions From China Have Been Decreasing Over the Last Two Decades. We have calculated that methane emissions from rice fields have been falling in recent decades. This decrease is particularly large in China. While some of this is due to reduced area of rice agriculture, the bigger effect is from the reduction in the emission factor which is the annual amount of methane emitted per hectare of rice. The two most important changes that cause this decreasing emission from China are the reduced use of organic amendments which have been replaced by commercial nitrogen fertilizers, and the increased practice of intermittent flooding as greater demands are placed on water resources. 3). Global Methane Emissions Have Been Constant For More Than 20 Years. While the concentrations of methane in the atmosphere have been leveling off in recent years, our studies show that this is caused by a near constant total global source of methane for the last 20 years or more. This is probably because as some anthropogenic sources have increased, others, such as the rice agriculture source, have fallen. Changes in natural emissions appear small. 4). Nitrous Oxide Emissions From Rice Fields Increase as Methane Emissions Drop. Inundated conditions favor anaerobic methane production with high emission rates and de-nitrification resulting in modest nitrous oxide emissions. Under drier conditions such as intermittent flooding, methane emissions fall and nitrous oxide emissions increase. Increased nitrogen fertilizer use increases nitrous oxide emissions and is usually accompanied by reduced organic matter applications which decreases methane emissions. These mechanisms cause a generally inverse relationship between methane and nitrous oxide emissions. Reduction of methane from rice agriculture to control global warming comes with tradeoffs with increased nitrous oxide emissions. 5). High Spatial Resolution Maps of Emissions Produced. Maps of methane and nitrous oxide emissions at a resolution of 5 min × 5 min have been produced based on the composite results of this research. These maps are necessary for both scientific and policy uses.

  3. Emissions of greenhouse gases in the United States 1997

    SciTech Connect (OSTI)

    NONE

    1998-10-01T23:59:59.000Z

    This is the sixth annual report on aggregate US national emissions of greenhouse gases. It covers emissions over the period 1990--1996, with preliminary estimates of emissions for 1997. Chapter one summarizes some background information about global climate change and the greenhouse effect. Important recent developments in global climate change activities are discussed, especially the third Conference of the Parties to the Framework Convention on Climate Change, which was held in December of 1997 in Kyoto, Japan. Chapters two through five cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons and related gases, respectively. Chapter six describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Six appendices are included in the report. 96 refs., 38 tabs.

  4. Emissions of greenhouse gases in the United States 1995

    SciTech Connect (OSTI)

    NONE

    1996-10-01T23:59:59.000Z

    This is the fourth Energy Information Administration (EIA) annual report on US emissions of greenhouse gases. This report presents estimates of US anthropogenic (human-caused) emissions of carbon dioxide, methane, nitrous oxide, and several other greenhouse gases for 1988 through 1994. Estimates of 1995 carbon dioxide, nitrous oxide, and halocarbon emissions are also provided, although complete 1995 estimates for methane are not yet available. Emissions of carbon dioxide increased by 1.9% from 1993 to 1994 and by an additional 0.8% from 1994 to 1995. Most carbon dioxide emissions are caused by the burning of fossil fuels for energy consumption, which is strongly related to economic growth, energy prices, and weather. The US economy grew rapidly in 1994 and slowed in 1995. Estimated emissions of methane increased slightly in 1994, as a result of a rise in emissions from energy and agricultural sources. Estimated nitrous oxide emissions increased by 1.8% in 1995, primarily due to increased use of nitrogen fertilizers and higher output of chemicals linked to nitrous oxide emissions. Estimated emissions of hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs), which are known to contribute to global warming, increased by nearly 11% in 1995, primarily as a result of increasing substitution for chlorofluorocarbons (CFCs). With the exception of methane, the historical emissions estimates presented in this report are only slightly revised from those in last year`s report.

  5. Emissions of greenhouse gases in the United States 1996

    SciTech Connect (OSTI)

    NONE

    1997-10-01T23:59:59.000Z

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1990, with annual updates thereafter. This report is the fifth annual update, covering national emissions over the period 1989--1995, with preliminary estimates of emissions for 1996. The estimates contained in this report have been revised from those in last year`s report. Emissions estimates for carbon dioxide are reported in metric tons of carbon; estimates for other gases are reported in metric tons of gas. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapter 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Five appendixes are included with this report. 216 refs., 11 figs., 38 tabs.

  6. Comparing Emissions Benefits from Regulating Heavy Vehicle Idling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from Regulating Heavy Vehicle Idling Comparing Emissions Benefits from Regulating Heavy Vehicle Idling 2005 Diesel Engine Emissions Reduction (DEER) Conference...

  7. Advanced Clean Cars Zero Emission Vehicle Regulation

    E-Print Network [OSTI]

    California at Davis, University of

    Advanced Clean Cars Zero Emission Vehicle Regulation ZEV #12;Advanced Clean Cars ZEV Program 2020 2021 2022 2023 2024 2025 Current Regulation -ZEVs Current Regulation -PHEVs Projected: PHEVs 15 infrastructure, the cars won't come · Complementary Policies to support ZEV regulation ­ Clean Fuels Outlet

  8. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    EMISSIONS OF NON-CO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITYEMISSIONS OF NON-CO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITY

  9. Regulations for Air Quality (Quebec, Canada)

    Broader source: Energy.gov [DOE]

    This Regulation establishes emission standards for particulates and gases, emission opacity standards, standards of air quality and control measures to prevent, eliminate or reduce the emission of...

  10. Technical Demonstration of 2010 Emissions Regulations over Transient...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Demonstration of 2010 Emissions Regulations over Transient Operation Technical Demonstration of 2010 Emissions Regulations over Transient Operation Presentation given at DEER 2006,...

  11. Update on Diesel Exhaust Emission Control Technology and Regulations...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control Technology and Regulations Update on Diesel Exhaust Emission Control Technology and Regulations 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation:...

  12. Emissions of greenhouse gases in the United States, 1987--1994

    SciTech Connect (OSTI)

    NONE

    1995-09-25T23:59:59.000Z

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1992, with annual updates thereafter. This is the third annual update report,covering national emissions over the period 1987--1993, with preliminary estimates of US carbon dioxide and halocarbon emissions for 1994. Calculating national aggregate emissions(or ``national inventories``) of greenhouse gases is a recently developed form of intellectual endeavor. Greenhouse gas emissions are rarely measured directly or reported to statistical agencies. Thus, to prepare emissions inventories usually requires inferring emissions indirectly from information collected for other purposes. Both the available information and the inferences drawn may be of varying reliability. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapters 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes.

  13. Abstract--Energy consumption and the concomitant Green House Gases (GHG) emissions of network infrastructures are

    E-Print Network [OSTI]

    Politčcnica de Catalunya, Universitat

    Abstract--Energy consumption and the concomitant Green House Gases (GHG) emissions of network as for their energy consumption. Renewable energy sources (e.g. solar, wind, tide, etc.) are emerging as a promising and the comparison of several energy-aware static routing and wavelength assignment (RWA) strategies for wavelength

  14. Regulated Emissions from Diesel and Compressed Natural Gas Transit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions from Diesel and Compressed Natural Gas Transit Buses Regulated Emissions from Diesel and Compressed Natural Gas Transit Buses Poster presentaiton at the 2007 Diesel...

  15. Air Pollution Control Regulations: No. 13 - Particulate Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    Environmental Regulations Provider Department of Environmental Management The purpose of this regulation is to limit emissions of particulate matter from fossil fuel fired and...

  16. Air Emissions Operating Permit Regulations for the Purposes of...

    Broader source: Energy.gov (indexed) [DOE]

    Environmental Regulations Provider Department of Environmental Quality The Air Emissions Operating Permit Regulations for the Purpose of Title V of the Federal Clean Air Act...

  17. The Greenhouse Gases, Regulated Emissions, and Energy Use in...

    Open Energy Info (EERE)

    Model (GREET Fleet) An easy-to-use tool that allows quick comparison of a variety of vehicle, fuel, and technology choices. Overview Measures the petroleum displacement and...

  18. Greenhouse Gases, Regulated Emissions, and Energy Use in Transportatio...

    Open Energy Info (EERE)

    and Energy Use in Transportation (GREET) Model AgencyCompany Organization: Argonne National Laboratory Focus Area: GHG Inventory Development Topics: Analysis Tools...

  19. The Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty Edit with formSoutheasternInformationPolicy |EnvironmentalInformation TheModel

  20. Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual SiteofEvaluating AGeothermal/ExplorationGoods | Open Energy Information ImpactsOpen(GREET)

  1. Emission factors for particles, elemental carbon, and trace gases from the Kuwait oil fires

    SciTech Connect (OSTI)

    Laursen, K.K.; Ferek, R.J.; Hobbs, P.V. [Univ. of Washington, Seattle, WA (United States); Rasmussen, R.A. [Oregon Graduate Institute of Science and Technology, Beaverton, OR (United States)

    1992-09-20T23:59:59.000Z

    Emission factors are presented for particles, elemental carbon (i.e., soot), total organic carbon in particles and vapor, and for various trace gases from the 1991 Kuwait oil fires. Particle emissions accounted for {approximately} 2% of the fuel burned. In general, soot emission factors were substantially lower than those used in recent {open_quotes}nuclear winter{close_quotes} calculations. Differences in the emissions and appearances of some of the individual fires are discussed. Carbon budget data for the composite plumes from the Kuwait fires are summarized; most of the burned carbon in the plumes was in the form of CO{sub 2}. Fluxes are presented for several combustion products. 26 refs., 1 fig., 5 tabs.

  2. An analytical inversion method for determining regional and global emissions of greenhouse gases: Sensitivity studies and application to halocarbons

    E-Print Network [OSTI]

    Stohl, A.

    A new analytical inversion method has been developed to determine the regional and global emissions of long-lived atmospheric trace gases. It exploits in situ measurement data from three global networks and builds on ...

  3. Emissions of greenhouse gases from the use of transportation fuels and electricity. Volume 2: Appendixes A--S

    SciTech Connect (OSTI)

    DeLuchi, M.A. [Argonne National Lab., IL (United States); [Univ. of California, Davis, CA (United States). Inst. of Transportation Studies

    1993-11-01T23:59:59.000Z

    This volume contains the appendices to the report on Emission of Greenhouse Gases from the Use of Transportation Fuels and Electricity. Emissions of methane, nitrous oxide, carbon monoxide, and other greenhouse gases are discussed. Sources of emission including vehicles, natural gas operations, oil production, coal mines, and power plants are covered. The various energy industries are examined in terms of greenhouse gas production and emissions. Those industries include electricity generation, transport of goods via trains, trucks, ships and pipelines, coal, natural gas and natural gas liquids, petroleum, nuclear energy, and biofuels.

  4. The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions

    E-Print Network [OSTI]

    Guenther, A. B.

    The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1) is a modeling framework for estimating fluxes of biogenic compounds between terrestrial ecosystems and the atmosphere using simple mechanistic ...

  5. Emissions of greenhouse gases from the use of transportation fuels and electricity. Volume 1, Main text

    SciTech Connect (OSTI)

    DeLuchi, M.A. [California Univ., Davis, CA (United States)

    1991-11-01T23:59:59.000Z

    This report presents estimates of full fuel-cycle emissions of greenhouse gases from using transportation fuels and electricity. The data cover emissions of carbon dioxide (CO{sub 2}), methane, carbon monoxide, nitrous oxide, nitrogen oxides, and nonmethane organic compounds resulting from the end use of fuels, compression or liquefaction of gaseous transportation fuels, fuel distribution, fuel production, feedstock transport, feedstock recovery, manufacture of motor vehicles, maintenance of transportation systems, manufacture of materials used in major energy facilities, and changes in land use that result from using biomass-derived fuels. The results for electricity use are in grams of CO{sub 2}-equivalent emissions per kilowatt-hour of electricity delivered to end users and cover generating plants powered by coal, oil, natural gas, methanol, biomass, and nuclear energy. The transportation analysis compares CO{sub 2}-equivalent emissions, in grams per mile, from base-case gasoline and diesel fuel cycles with emissions from these alternative- fuel cycles: methanol from coal, natural gas, or wood; compressed or liquefied natural gas; synthetic natural gas from wood; ethanol from corn or wood; liquefied petroleum gas from oil or natural gas; hydrogen from nuclear or solar power; electricity from coal, uranium, oil, natural gas, biomass, or solar energy, used in battery-powered electric vehicles; and hydrogen and methanol used in fuel-cell vehicles.

  6. Abstract--Limiting the emissions of greenhouse gases from power generation will depend, among other things, on the

    E-Print Network [OSTI]

    Harrison, Gareth

    other things, on the continuing and increased use of hydroelectric power. However, climate change itself provision of hydropower. Index Terms-- hydroelectric power generation, hydrology, meteorology, finance, risk1 Abstract-- Limiting the emissions of greenhouse gases from power generation will depend, among

  7. Market-Based Emissions Regulation and Industry Dynamics

    E-Print Network [OSTI]

    Fowlie, Meredith

    . Examples include the Emissions Trading Scheme (ETS) in the European Union and California's greenhouse gas (GHG) emissions trading program. In these "cap-and-trade" (CAT) programs, regulators impose a cap- sions is that, provided a series of conditions are met, an emissions trading program designed to equate

  8. An assessment of the health implications of aviation emissions regulations

    E-Print Network [OSTI]

    Sequeira, Christopher J

    2008-01-01T23:59:59.000Z

    An exploration of the health implications of aviation emissions regulations is made by assessing the results of a study of aviation's effects on United States air quality mandated by the Energy Policy Act of 2005. The ...

  9. Market-Based Emissions Regulation and Industry Dynamics

    E-Print Network [OSTI]

    Fowlie, Meredith

    We assess the long-run dynamic implications of market-based regulation of carbon dioxide emissions in the US Portland cement industry. We consider several alternative policy designs, including mechanisms that use production ...

  10. Greenhouse Gases | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Greenhouse Gases Greenhouse Gases Executive Order 13514 requires Federal agencies to inventory and manage greenhouse gas (GHG) emissions to meet Federal goals and mitigate climate...

  11. Setup for in situ investigation of gases and gas/solid interfaces by soft x-ray emission and absorption spectroscopy

    SciTech Connect (OSTI)

    Benkert, A., E-mail: andreas.benkert@kit.edu, E-mail: l.weinhardt@kit.edu [Institute for Photon Science and Synchrotron Radiation, Karlsruhe Institute of Technology (KIT), Hermann-v.-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany); Universität Würzburg, Experimentelle Physik VII, Am Hubland, 97074 Würzburg (Germany); Gemeinschaftslabor für Nanoanalytik, Karlsruhe Institute of Technology (KIT), 76021 Karlsruhe (Germany); Blum, M. [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States) [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States); Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States); Meyer, F. [Universität Würzburg, Experimentelle Physik VII, Am Hubland, 97074 Würzburg (Germany)] [Universität Würzburg, Experimentelle Physik VII, Am Hubland, 97074 Würzburg (Germany); Wilks, R. G. [Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany)] [Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Yang, W. [Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States)] [Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States); Bär, M. [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States) [Department of Chemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Nevada 89154-4003 (United States); Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin (Germany); Insitut für Physik und Chemie, Brandenburgische Technische Universität Cottbus-Senftenberg, Konrad-Wachsmann-Allee 1, 03046 Cottbus (Germany); and others

    2014-01-15T23:59:59.000Z

    We present a novel gas cell designed to study the electronic structure of gases and gas/solid interfaces using soft x-ray emission and absorption spectroscopies. In this cell, the sample gas is separated from the vacuum of the analysis chamber by a thin window membrane, allowing in situ measurements under atmospheric pressure. The temperature of the gas can be regulated from room temperature up to approximately 600?°C. To avoid beam damage, a constant mass flow can be maintained to continuously refresh the gaseous sample. Furthermore, the gas cell provides space for solid-state samples, allowing to study the gas/solid interface for surface catalytic reactions at elevated temperatures. To demonstrate the capabilities of the cell, we have investigated a TiO{sub 2} sample behind a mixture of N{sub 2} and He gas at atmospheric pressure.

  12. The new air emission regulations for gas turbine

    SciTech Connect (OSTI)

    Solt, C.

    1998-07-01T23:59:59.000Z

    In the US, there are three new regulations now in development that will lower the limits for NO{sub x} emissions from gas turbines: (1) New National Ambient Air Quality Standards (NAAQS) for Particulate Matter, and Possibly revision to the Ozone standard (both of these new programs will target NO{sub x} emissions); (2) New regulations stemming from the Ozone Transport Assessment Group (OTAG) recommendations (again, NO{sub x} is the primary focus); (3) Revision of the New Source Performance Standard (NSPS) for gas turbines and a new rule that will impose new toxic emission requirements, (the Industrial Combustion Coordinated Rulemaking, stemming from revisions to Title III of the Clean Sir Act Amendments of 1990). The toxic rule should be of particular concern to the gas turbine industry in that it may impose the use of expensive toxic emission control techniques that may not provide any significant health benefits to the public. In addition, the European Community is currently drafting a new regulation for combustion sources that will require gas turbines to meet levels that are lower than any in Europe today. This paper will consider all 5 of these regulatory actions and will: review the proposed regulations; discuss timing for regulation development and implementation; assess the probable impact of each regulation; and provide opinions on the fate of each regulation. Both manufacturers and users of gas turbines should be aware of these proceedings and take an active role in the rule development.

  13. A game of climate chicken : can EPA regulate greenhouse gases before the U.S. Senate ratifies the Kyoto Protocol?

    E-Print Network [OSTI]

    Bugnion, Véronique.; Reiner, David M.

    EPA's legal authority to regulate greenhouse gas emissions under the Clean Air Act is reviewed. While EPA clearly does not have the authority to implement the precise terms of the Kyoto Protocol, arguments could be put ...

  14. Quantifying emissions of greenhouse gases from South Asia through a targeted measurement campaign

    E-Print Network [OSTI]

    Ganesan, Anita Lakshmi

    2013-01-01T23:59:59.000Z

    Methane (CH 4 ), nitrous oxide (N20) and sulfur hexafluoride (SF6) are powerful greenhouse gases with global budgets that are well-known but regional distributions that are not adequately constrained for the purposes of ...

  15. Rethinking Downstream Regulation: California's Opportunity to Engage Households in Reducing Greenhouse Gases

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    D. , et al. , Rethinking downstream regulation: California’sD. , et al. , Rethinking downstream regulation: California’slocate/enpol Rethinking downstream regulation: California’s

  16. Regulation of GHG emissions from transportation fuels: Emission quota versus emission intensity standard

    E-Print Network [OSTI]

    Rajagopal, Deepak

    2010-01-01T23:59:59.000Z

    Derivation of average cost of emission reduction by blending?) and ? respectively. GHG emissions per unit of blend is, ?+ ?? i Reduction in GHG emissions with respect to unblended

  17. Truck Stop Electrification as a Strategy To Reduce Greenhouse Gases, Fuel Consumption and Pollutant Emissions

    E-Print Network [OSTI]

    Truck Stop Electrification as a Strategy To Reduce Greenhouse Gases, Fuel Consumption and Pollutant, Schneider, Lee, Bubbosh 2 ABSTRACT Extended truck idling is a very large source of fuel wastage, greenhouse, most long-haul truck drivers idle their vehicles for close to 10 hours per day to operate heating

  18. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    CO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITYCO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITY

  19. State Air Emission Regulations That Affect Electric Power Producers (Update) (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01T23:59:59.000Z

    Several states have recently enacted air emission regulations that will affect the electricity generation sector. The regulations govern emissions of NOx, SO2, CO2, and mercury from power plants.

  20. Emissions of trace gases and aerosols during the open combustion of biomass in the laboratory

    E-Print Network [OSTI]

    McMeeking, Gavin R.

    2009-01-01T23:59:59.000Z

    Emissions from laboratory combustion of wildland fuels:range transport of combustion-derived aerosols, Science,from the laboratory combustion of wildland fuels: Particle

  1. Emissions of trace gases and aerosols during the open combustion of biomass in the laboratory

    E-Print Network [OSTI]

    McMeeking, Gavin R.

    2009-01-01T23:59:59.000Z

    primarily focused on agricultural waste [Jenkins et al. ,emissions from these agricultural wastes have attractedpectinata). Two agricultural waste products that are burned

  2. A methodology to estimate greenhouse gases emissions in Life Cycle Inventories of wastewater treatment plants

    SciTech Connect (OSTI)

    Rodriguez-Garcia, G., E-mail: gonzalo.rodriguez.garcia@usc.es [Department of Chemical Engineering, University of Santiago de Compostela, Rua Lope Gomez de Marzoa, S/N, 15782, Santiago de Compostela (Spain); Hospido, A., E-mail: almudena.hospido@usc.es [Department of Chemical Engineering, University of Santiago de Compostela, Rua Lope Gomez de Marzoa, S/N, 15782, Santiago de Compostela (Spain); Bagley, D.M., E-mail: bagley@uwyo.edu [Department of Chemical and Petroleum Engineering, University of Wyoming, 82072 Laramie, WY (United States); Moreira, M.T., E-mail: maite.moreira@usc.es [Department of Chemical Engineering, University of Santiago de Compostela, Rua Lope Gomez de Marzoa, S/N, 15782, Santiago de Compostela (Spain); Feijoo, G., E-mail: gumersindo.feijoo@usc.es [Department of Chemical Engineering, University of Santiago de Compostela, Rua Lope Gomez de Marzoa, S/N, 15782, Santiago de Compostela (Spain)

    2012-11-15T23:59:59.000Z

    The main objective of this paper is to present the Direct Emissions Estimation Model (DEEM), a model for the estimation of CO{sub 2} and N{sub 2}O emissions from a wastewater treatment plant (WWTP). This model is consistent with non-specific but widely used models such as AS/AD and ASM no. 1 and presents the benefits of simplicity and application over a common WWTP simulation platform, BioWin Registered-Sign , making it suitable for Life Cycle Assessment and Carbon Footprint studies. Its application in a Spanish WWTP indicates direct N{sub 2}O emissions to be 8 times larger than those associated with electricity use and thus relevant for LCA. CO{sub 2} emissions can be of similar importance to electricity-associated ones provided that 20% of them are of non-biogenic origin. - Highlights: Black-Right-Pointing-Pointer A model has been developed for the estimation of GHG emissions in WWTP. Black-Right-Pointing-Pointer Model was consistent with both ASM no. 1 and AS/AD. Black-Right-Pointing-Pointer N{sub 2}O emissions are 8 times more relevant than the one associated with electricity. Black-Right-Pointing-Pointer CO{sub 2} emissions are as important as electricity if 20% of it is non-biogenic.

  3. Quantifying Emissions of Greenhouse Gases from South Asia Through a Targeted Measurement

    E-Print Network [OSTI]

    of Philosophy in Climate Physics and Chemistry Abstract Methane (CH4), nitrous oxide (N2O) and sulfur in India and are used for measurement- based assessment of emissions. Several features are identified are investigated to better quantify some of the uncertainties associated with this chemical transport model

  4. Emissions of trace gases and aerosols during the open combustion of biomass in the laboratory

    SciTech Connect (OSTI)

    McMeeking, Gavin R.; Kreidenweis, Sonia M.; Baker, Stephen; Carrico, Christian M.; Chow, Judith C.; Collett, Jr., Jeffrey L.; Hao, Wei Min; Holden, Amanda S.; Kirchstetter, Thomas W.; Malm, William C.; Moosmuller, Hans; Sullivan, Amy P.; Wold, Cyle E.

    2009-05-15T23:59:59.000Z

    We characterized the gas- and speciated aerosol-phase emissions from the open combustion of 33 different plant species during a series of 255 controlled laboratory burns during the Fire Laboratory at Missoula Experiments (FLAME). The plant species we tested were chosen to improve the existing database for U.S. domestic fuels: laboratory-based emission factors have not previously been reported for many commonly-burned species that are frequently consumed by fires near populated regions and protected scenic areas. The plants we tested included the chaparral species chamise, manzanita, and ceanothus, and species common to the southeastern US (common reed, hickory, kudzu, needlegrass rush, rhododendron, cord grass, sawgrass, titi, and wax myrtle). Fire-integrated emission factors for gas-phase CO{sub 2}, CO, CH{sub 4}, C{sub 2-4} hydrocarbons, NH{sub 3}, SO{sub 2}, NO, NO{sub 2}, HNO{sub 3} and particle-phase organic carbon (OC), elemental carbon (EC), SO{sub 4}{sup 2-}, NO{sub 3}{sup -}, Cl{sup -}, Na{sup +}, K{sup +}, and NH{sub 4}{sup +} generally varied with both fuel type and with the fire-integrated modified combustion efficiency (MCE), a measure of the relative importance of flaming- and smoldering-phase combustion to the total emissions during the burn. Chaparral fuels tended to emit less particulate OC per unit mass of dry fuel than did other fuel types, whereas southeastern species had some of the largest observed EF for total fine particulate matter. Our measurements often spanned a larger range of MCE than prior studies, and thus help to improve estimates for individual fuels of the variation of emissions with combustion conditions.

  5. Updated cost estimates of meeting geothermal hydrogen sulfide emission regulations

    SciTech Connect (OSTI)

    Wells, K.D.; Currie, J.W.; Weakley, S.A.; Ballinger, M.Y.

    1981-08-01T23:59:59.000Z

    A means of estimating the cost of hydrogen sulfide (H/sub 2/S) emission control was investigated. This study was designed to derive H/sub 2/S emission abatement cost functions and illustrate the cost of H/sub 2/S emission abatement at a hydrothermal site. Four tasks were undertaken: document the release of H/sub 2/S associated with geothermal development; review H/sub 2/S environmental standards; develop functional relationships that may be used to estimate the most cose-effective available H/sub 2/S abatement process; and use the cost functions to generate abatement cost estimates for a specific site. The conclusions and recommendations derived from the research are presented. The definition of the term impacts as used in this research is discussed and current estimates of the highest expected H/sub 2/S concentrations of in geothermal reservoirs are provided. Regulations governing H/sub 2/S emissions are reviewed and a review of H/sub 2/S control technology and a summary of the control cost functions are included. A case study is presented to illustrate H/sub 2/S abatement costs at the Baca KGRA in New Mexico.

  6. Emissions Trading and Air Toxics Emissions: RECLAIM and Toxics Regulation in the South Coast Air Basin

    E-Print Network [OSTI]

    Cohen, Nancy J.

    1993-01-01T23:59:59.000Z

    Emissions Trading and Air Toxics Emissions: RECLAIM anda mar- ket-based emissions trading program called theimpacts cre- ated by emissions trading programs that affect

  7. Regulated Emissions from Biodiesel Tested in Heavy-Duty Engines Meeting 2004 Emission Standards

    SciTech Connect (OSTI)

    McCormick, R. L.; Tennant, C. J.; Hayes, R. R.; Black, S.; Ireland, J.; McDaniel, T.; Williams, A.; Frailey, M.; Sharp, C. A.

    2005-11-01T23:59:59.000Z

    Biodiesel produced from soybean oil, canola oil, yellow grease, and beef tallow was tested in two heavy-duty engines. The biodiesels were tested neat and as 20% by volume blends with a 15 ppm sulfur petroleum-derived diesel fuel. The test engines were the following: 2002 Cummins ISB and 2003 DDC Series 60. Both engines met the 2004 U.S. emission standard of 2.5 g/bhp-h NO{sub x}+HC (3.35 g/kW-h) and utilized exhaust gas recirculation (EGR). All emission tests employed the heavy-duty transient procedure as specified in the U.S. Code of Federal Regulations. Reduction in PM emissions and increase in NO{sub x} emissions were observed for all biodiesels in all engines, confirming observations made in older engines. On average PM was reduced by 25% and NO{sub x} increased by 3% for the two engines tested for a variety of B20 blends. These changes are slightly larger in magnitude, but in the same range as observed in older engines. The cetane improver 2-ethyl hexyl nitrate was shown to have no measurable effect on NO{sub x} emissions from B20 in these engines, in contrast to observations reported for older engines. The effect of intake air humidity on NO{sub x} emissions from the Cummins ISB was quantified. The CFR NO{sub x}/humidity correction factor was shown to be valid for an engine equipped with EGR, operating at 1700 m above sea level, and operating on conventional or biodiesel.

  8. Federal Air Emissions Regulations (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01T23:59:59.000Z

    In 2005, the Environmental Protection Agency (EPA) finalized two regulations, the Clean Air Interstate Rule (CAIR) and the Clean Air Mercury Rule CAMR, that would reduce emissions from coal-fired power plants in the United States. Both CAIR and CAMR are included in the Annual Energy Outlook 2006 reference case. The EPA has received 11 petitions for reconsideration of CAIR and has provided an opportunity for public comment on reconsidering certain aspects of CAIR. Public comments were accepted until January 13, 2006. The EPA has also received 14 petitions for reconsideration of CAMR and is willing to reconsider certain aspects of the rule. Public comments were accepted for 45 days after publication of the reconsideration notice in the Federal Register. Several states and organizations have filed lawsuits against CAMR. The ultimate decision of the courts will have a significant impact on the implementation of CAMR.

  9. Emissions of Criteria Pollutants, Toxic Air Pollutants, and Greenhouse Gases, From the Use of Alternative Transportation Modes and Fuels

    E-Print Network [OSTI]

    Delucchi, Mark

    1996-01-01T23:59:59.000Z

    evaporative, refueling, and running loss emissions fromis turned off; iii) running loss emissions from the fuel= temperature-corrected running-loss evaporative emissions (

  10. Greenhouse Gases, Regulated Emissions, and Energy use in Transportation (GREET) Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdf Flash2006-52.pdf0.pdfDepartmentCounselGlassGreenHunter Biodiesel RefineryGreenhouse

  11. Incomplete Environmental Regulation, Imperfect Competition, and Emissions Leakage

    E-Print Network [OSTI]

    Fowlie, Meredith

    2007-01-01T23:59:59.000Z

    D. (2005), ‘ Allocation of CO2 emission allowances in the2005), ‘ Evaluation of CO2 emissions allocations as a partcorresponding, unit-speci…c CO2 emissions rate (measured in

  12. ENVIRON SCIENCE AND TECHNOLOGY IN ROMANIA--ESTROM PROJECT Sources and emission of greenhouse gases in Danube

    E-Print Network [OSTI]

    Wehrli, Bernhard

    gases in Danube Delta lakes Alina Pavel & Edith Durisch-Kaiser & Sorin Balan & Silviu Radan & Sebastian. Radan GeoEcoMar, National Institute for Marine Geology and Geoecology, 024053 Bucharest, Romania E

  13. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    per kWh), but that CO2 emissions from hydropower plantswill be less than CO2 emissions from fossil-fuel plants.kg/ha) 2. Difference in CO2 emissions vs. control plot (kg/

  14. Improving UK greenhouse gas emission estimates using tall tower observations 

    E-Print Network [OSTI]

    Howie, James Edward

    2014-06-30T23:59:59.000Z

    Greenhouse gases in the Earth’s atmosphere play an important role in regulating surface temperatures. The UK is signatory to international agreements that legally commit the UK to reduce its greenhouse gas emissions, and ...

  15. Market-Based Emissions Regulation and Industry Dynamics

    E-Print Network [OSTI]

    Fowlie, Meredith

    . The authors gratefully acknowledge the support of NSF grant SES-0922401. 1 #12;Emissions Trading Scheme (ETS) in the European Union and California's greenhouse gas (GHG) emissions trading program. In these "cap is that, provided a series of conditions are met, an emissions trading program designed to equate marginal

  16. Air Pollution Control Regulations: No. 3- Particulate Emissions from Industrial Processes (Rhode Island)

    Broader source: Energy.gov [DOE]

    These regulations limit particulate emissions into the atmosphere by process weight per hour, where process weight is the total weight of all materials introduced into any specific process which...

  17. Volunteering for market-based environmental regulation : the substitution provision of the SO? emissions trading program

    E-Print Network [OSTI]

    Montero, Juan Pablo

    In this paper we explore the practical and welfare implications of a system of voluntary compliance within a market-based environmental regulation. The Substitution Provision of the SO2 emissions trading program allows the ...

  18. Analysis of potential for reducing emissions of greenhouse gases in municipal solid waste in Brazil, in the state and city of Rio de Janeiro

    SciTech Connect (OSTI)

    Loureiro, S.M., E-mail: saulo@lima.coppe.ufrj.br [Department of Energy Planning, Federal University of Rio de Janeiro, C.P. 68565, CEP 21949-972 Rio de Janeiro, RJ (Brazil); Rovere, E.L.L., E-mail: emilio@ppe.ufrj.br [Department of Energy Planning, Federal University of Rio de Janeiro, C.P. 68565, CEP 21949-972 Rio de Janeiro, RJ (Brazil); Mahler, C.F., E-mail: mahler0503@yahoo.com [Department of Civil Engineering, Federal University of Rio de Janeiro, C.P. 68506, CEP 21945-970, Rio de Janeiro, RJ (Brazil)

    2013-05-15T23:59:59.000Z

    Highlights: ? We constructed future scenarios of emissions of greenhouse gases in waste. ? Was used the IPCC methodology for calculating emission inventories. ? We calculated the costs of abatement for emissions reduction in landfill waste. ? The results were compared to Brazil, state and city of Rio de Janeiro. ? The higher the environmental passive, the greater the possibility of use of biogas. - Abstract: This paper examines potential changes in solid waste policies for the reduction in GHG for the country of Brazil and one of its major states and cities, Rio de Janeiro, from 2005 to 2030. To examine these policy options, trends in solid waste quantities and associated GHG emissions are derived. Three alternative policy scenarios are evaluated in terms of effectiveness, technology, and economics and conclusions posited regarding optimal strategies for Brazil to implement. These scenarios are been building on the guidelines for national inventories of GHG emissions (IPCC, 2006) and adapted to Brazilian states and municipalities’ boundaries. Based on the results, it is possible to say that the potential revenue from products of solid waste management is more than sufficient to transform the current scenario in this country into one of financial and environmental gains, where the negative impacts of climate change have created a huge opportunity to expand infrastructure for waste management.

  19. Air Pollution Control Regulations: No. 6 - Continuous Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    Management Stationary sources, including fossil fuel fired steam or hot water generating units, may be required to install and operate a continuous emissions monitoring system...

  20. Air Pollution Control Regulations: No. 7 - Emission of Air Contaminant...

    Broader source: Energy.gov (indexed) [DOE]

    with the enjoyment of life and property. The criteria for determining compliance is listed in the regulations, and is based on other air pollution and ambient air standards...

  1. Market-based emissions regulation when damages vary across sources: What are the gains from differentiation?

    E-Print Network [OSTI]

    Fowlie, Meredith

    For much of the air pollution currently regulated under U.S. emissions trading programs, health pernicious air quality problems in the United States involve non-uniformly mixed pollutants. Examples include policies can accommodate non-uniformly mixed pollution by using emissions penalties that vary with damages

  2. Update on State Air Emission Regulations That Affect Electric Power Producers (released in AEO2005)

    Reports and Publications (EIA)

    2005-01-01T23:59:59.000Z

    Several states have recently enacted air emission regulations that will affect the electricity generation sector. The regulations are intended to improve air quality in the states and assist them in complying with the revised 1997 National Ambient Air Quality Standards (NAAQS) for ground-level ozone and fine particulates. The affected states include Connecticut, Massachusetts, Maine, Missouri, New Hampshire, New Jersey, New York, North Carolina, Oregon, Texas, and Washington. The regulations govern emissions of NOx, SO2, CO2, and mercury from power plants.

  3. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    combustion (N2O emissions peak with particle sizes of about 1 mm), and gas residence time within and after the fixed bed (

  4. Air Emission Regulations for the Prevention, Abatement, and Control...

    Broader source: Energy.gov (indexed) [DOE]

    BTU per hour heat. For installations equal or greater than 10 million BTU per hour heat input shall not exceed the rate of E 0.8808 * I-0.1667 where E is the emission rate...

  5. Air Pollution Control Regulations: No. 1- Visible Emissions (Rhode Island)

    Broader source: Energy.gov [DOE]

    The regulations state that no person shall emit into the atmosphere from any source any air contaminant for a period or periods aggregating more than three minutes in any one hour which is greater...

  6. Control of pollutants in flue gases and fuel gases

    E-Print Network [OSTI]

    Laughlin, Robert B.

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1 2.2 Flue gases and fuel gases: combustion, gasification, pyrolysis, incineration and other and gasification technologies for heat and power . . . . . . . . 2-3 2.4 Waste incineration and waste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-3 3.3 Formation of sulphur compounds during combustion and gasification . 3-5 3.4 Emission

  7. Voluntary Reporting of Greenhouse Gases

    Reports and Publications (EIA)

    2011-01-01T23:59:59.000Z

    The Voluntary Reporting of Greenhouse Gases Program was suspended May 2011. It was a mechanism by which corporations, government agencies, individuals, voluntary organizations, etc., could report to the Energy Information Administration, any actions taken that have or are expected to reduce/avoid emissions of greenhouse gases or sequester carbon.

  8. Emissions of Criteria Pollutants, Toxic Air Pollutants, and Greenhouse Gases, From the Use of Alternative Transportation Modes and Fuels

    E-Print Network [OSTI]

    Delucchi, Mark

    1996-01-01T23:59:59.000Z

    compressed natural gas; E85 = 85% ethanol and 15% gasoline;compressed natural gas; E85 = 85% ethanol and 15% gasoline;for E85 is based on only 8 emissions tests of 2 ethanol

  9. Emissions of Criteria Pollutants, Toxic Air Pollutants, and Greenhouse Gases, From the Use of Alternative Transportation Modes and Fuels

    E-Print Network [OSTI]

    Delucchi, Mark

    1996-01-01T23:59:59.000Z

    fleet- average mpg in 1987. bWe assume that electricity ands (1993) road classification. bWe use FHWA (1993) data toin note b of Table 2. bWe estimated total emissions from the

  10. Air Pollution Control Regulations: No. 13- Particulate Emissions from Fossil Fuel Fired Steam or Hot Water Generating Units (Rhode Island)

    Broader source: Energy.gov [DOE]

    The purpose of this regulation is to limit emissions of particulate matter from fossil fuel fired and wood-fired steam or hot water generating units.

  11. Updated State Air Emissions Regulations (released in AEO2010)

    Reports and Publications (EIA)

    2010-01-01T23:59:59.000Z

    The Regional Greenhouse Gas Initiative (RGGI) is a program that includes 10 Northeast states that have agreed to curtail and reverse growth in their carbon dioxide (CO2) emissions. The RGGI program includes all electricity generating units with a capacity of at least 25 megawatts and requires an allowance for each ton of CO2 emitted. The first year of mandatory compliance was in 2009.

  12. Guidance Document CompressedGases

    E-Print Network [OSTI]

    electricity. Oxygen by itself does not burn, but it will support or accelerate combustion of flammable the regulator is completely closed. 3. When possible use flammable and reactive gases in a fume hood. Certain

  13. The emissions of gases from abandoned mines: role of atmospheric pressure changes and air temperature on the surface

    E-Print Network [OSTI]

    Boyer, Edmond

    pressure were monitored. Gas flow can be influenced mainly by the temperature difference between external pressure influences gas flow in the coal mines, which can be considered as closed systems. Modelling has confirmed the differential pressure value measured that exceeds friction losses. Key words Mine gas emission

  14. Emission Regulations Reduced Impact of Climate Change in CA

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisitingContractElectron-State HybridizationSecurity / EmergencyResearchEmission

  15. Regulation of Emissions from Stationary Diesel Engines (released in AEO2007)

    Reports and Publications (EIA)

    2007-01-01T23:59:59.000Z

    On July 11, 2006, the Environmental Protection Agency (EPA) issued regulations covering emissions from stationary diesel engines New Source Performance Standards that limit emissions of NOx, particulate matter, SO2, carbon monoxide, and hydrocarbons to the same levels required for nonroad diesel engines. The regulation affects new, modified, and reconstructed diesel engines. Beginning with model year 2007, engine manufacturers must specify that new engines less than 3,000 horsepower meet the same emissions standard as nonroad diesel engines. For engines greater than 3,000 horsepower, the standard will be fully effective in 2011. Stationary diesel engine fuel will also be subject to the same standard as nonroad diesel engine fuel, which reduces the sulfur content of the fuel to 500 parts per million by mid-2007 and 15 parts per million by mid-2010.

  16. Coupling field and laboratory measurements to estimate the emission factors of identified and unidentified trace gases for prescribed fires

    SciTech Connect (OSTI)

    Yokelson, Robert J.; Burling, Ian R.; Gilman, Jessica; Warneke, Carsten; Stockwell, Chelsea E.; de Gouw, Joost A.; Akagi, Sheryl; Urbanski, Shawn; Veres, Patrick; Roberts, James M.; Kuster, W. C.; Reardon, James; Griffith, David WT; Johnson, Timothy J.; Hosseini, SeyedEhsan; Miller, J. Wayne; Cocker, David R.; Jung, H.; Weise, David

    2013-01-07T23:59:59.000Z

    Vegetative fuels commonly consumed in prescribed fires were collected from five locations in the southeastern and southwestern U.S. and burned in a series of 77 fires at the U.S. Forest Service Fire Sciences Laboratory in Missoula, Montana. The particulate matter (PM2.5) emissions were measured by gravimetric filter sampling with subsequent analysis for elemental carbon (EC), organic carbon (OC), and 38 elements. The trace gas emissions were measured with a large suite of state-of-the-art instrumentation including an open-path Fourier transform infrared (OP FTIR) spectrometer, proton-transfer-reaction mass spectrometry (PTR-MS), proton-transfer ion-trap mass spectrometry (PIT-MS), negative-ion proton-transfer chemical-ionization mass spectrometry (NI-PT-CIMS), and gas chromatography with MS detection (GC-MS). 204 trace gas species (mostly non-methane organic compounds (NMOC)) were identified and quantified with the above instruments. An additional 152 significant peaks in the unit mass resolution mass spectra were quantified, but either could not be identified or most of the signal at that molecular mass was unaccounted for by identifiable species. As phase II of this study, we conducted airborne and ground-based sampling of the emissions from real prescribed fires mostly in the same land management units where the fuels for the lab fires were collected. A broad variety, but smaller number of species (21 trace gas species and PM2.5) was measured on 14 fires in chaparral and oak savanna in the southwestern US, as well as pine forest understory in the southeastern US and Sierra Nevada mountains of California. These extensive field measurements of emission factors (EF) for temperate biomass burning are useful both for modeling and to examine the representativeness of our lab fire EF. The lab/field EF ratio for the pine understory fuels was not statistically different from one, on average. However, our lab EF for “smoldering compounds” emitted by burning the semi-arid SW fuels should likely be increased by about a factor of 2.7 to better represent field fires. Based on the lab/field comparison, we present a table with emission factors for 365 pyrogenic species (including unidentified species) for 4 broad fuel types: pine understory, semi-arid shrublands, evergreen canopy, and duff. To our knowledge this is the most complete measurement of biomass burning emissions to date and it should enable improved representation of smoke in atmospheric models. The results provide important insights into the nature of smoke. For example, ~35% (range from 16-71%) of the mass of gas-phase NMOC species was attributed to the species that we could not identify. These unidentified species are likely not represented in most models, but some provision should be made for the fact that they will react in the atmosphere. In addition, the total mass of gas-phase NMOC divided by the mass of co-emitted PM2.5 averaged ~2.6 for the main fire types with a range from ~1.8-8.8. About 36-63% of the NMOC were likely semivolatile or of intermediate volatility. Thus, the gas-phase NMOC represent a large reservoir of potential precursors for secondary formation of organic aerosol. For the one fire in organic soil (Alaskan duff) about 28% of the emitted carbon was present as gas-phase NMOC in contrast to the other fuels for which NMOC accounted for only ~1-3% of emitted carbon. 71% of the mass of NMOC emitted by the smoldering duff was un-identified. The duff results highlight the need to learn more about the emissions from smoldering organic soils. The ?NMOC/“NOx-as-NO” ratio was consistently about ten for the main fire types when accounting for all NMOC, indicating strongly NOx-limited O3 production conditions. Finally, the fuel consumption per unit area was measured on 6 of the 14 prescribed fires and averaged 7.08 ± 2.09 (1?) Mg ha-1.

  17. Greenhouse Gases

    Broader source: Energy.gov [DOE]

    Federal agencies are required to inventory and manage greenhouse gas (GHG) emissions to meet Federal goals and mitigate climate change.

  18. New Automobile Regulations: Double the Fuel Economy, Half the CO2 Emissions, and Even Automakers Like It

    E-Print Network [OSTI]

    Lutsey, Nic

    2012-01-01T23:59:59.000Z

    Lead-Time: The Case of US Automobile Greenhouse Gas EmissionNew Automobile Regulations Double the Fuel Economy, Half thephysics of the modern automobile involve an uphill battle to

  19. HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Greenhouse gases andGreenhouse gases and

    E-Print Network [OSTI]

    Zevenhoven, Ron

    in gas turbinecombustion in gas turbine HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Effect of COEffect-depleting gases ·· COCO22 removal for gas purificationremoval for gas purification ·· COCO22 removal for greenhouse gas emissions reductionremoval for greenhouse gas emissions reduction ·· Other greenhouse gases

  20. Compliance Costs, Regulation, and Environmental Performance: Controlling Truck Emissions in the United States

    E-Print Network [OSTI]

    Thornton, Dorothy; Kagan, Robert A.; Gunningham, Neil

    2008-01-01T23:59:59.000Z

    Performance: Controlling Truck Emissions in the Unitedthe major source of truck emissions – the thousands of over-to high levels of truck emissions – have been forced to

  1. Shaping the terms of competition : environmental regulation and corporate strategies to reduce diesel vehicle emissions

    E-Print Network [OSTI]

    Ng, Christine Bik-Kay, 1979-

    2006-01-01T23:59:59.000Z

    Environmental regulations are typically portrayed as an outside force stimulating development of environmental technologies in regulated industries. In reality, firms influence regulation by communicating their technological ...

  2. Voluntary reporting of greenhouse gases, 1995

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    The Voluntary Reporting Program for greenhouse gases is part of an attempt by the U.S. Government to develop innovative, low-cost, and nonregulatory approaches to limit emissions of greenhouse gases. It is one element in an array of such programs introduced in recent years as part of the effort being made by the United States to comply with its national commitment to stabilize emissions of greenhouse gases under the Framework Convention on Climate Change. The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report to the Energy Information Administration (EIA) on actions taken that have reduced or avoided emissions of greenhouse gases.

  3. Where do California's greenhouse gases come from?

    ScienceCinema (OSTI)

    Fischer, Marc

    2013-05-29T23:59:59.000Z

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  4. Wildland fire emissions, carbon, and climate: Emission factors Shawn Urbanski

    E-Print Network [OSTI]

    Wildland fire emissions, carbon, and climate: Emission factors Shawn Urbanski Missoula Fire burning Greenhouse gases Emission factors a b s t r a c t While the vast majority of carbon emitted mixture of gases and aerosols. Primary emissions include sig- nificant amounts of CH4 and aerosol (organic

  5. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi (Hoffman Estates, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL)

    1986-01-01T23:59:59.000Z

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  6. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.

    1986-08-19T23:59:59.000Z

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  7. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi (Hoffman Estates, IL)

    1986-01-01T23:59:59.000Z

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  8. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.; Kulkarni, S.S.

    1986-08-26T23:59:59.000Z

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  9. Air Pollution Control Regulations: No.27- Control of Nitrogen Oxide Emissions (Rhode Island)

    Broader source: Energy.gov [DOE]

    These regulations apply to stationary sources with the potential to emit 50 tons of nitrogen oxides (NOx) per year from all pollutant-emitting equipment or activities. The regulations describe...

  10. State Regulations on Airborne Emissions: Update Through 2006 (Update) (released in AEO2007)

    Reports and Publications (EIA)

    2007-01-01T23:59:59.000Z

    In May 2005, the Environmental Protection Agency published two final rules aimed at reducing emissions from coal-fired power plants. The Clean Air Interstate Rule (CAIR) requires 28 states and the District of Columbia to reduce emissions of SO2 and/or NOx. The Clean Air Mercury Rule (CAMR) requires the states to reduce emissions of mercury from new and existing coal-fired plants.

  11. Multi-objective regulations on transportation fuels: Comparing renewable fuel mandates and emission standards

    E-Print Network [OSTI]

    Rajagopal, D; Rajagopal, D; Plevin, R; Hochman, G; Zilberman, D

    2015-01-01T23:59:59.000Z

    greenhouse gas emissions. Energy Policy 390 (9), 5509–5518.United States Energy Information Administration, 2014.Annual Energy Outlook. Venkatesh, A. , Jaramillo, P. , Grif?

  12. Shaping the Terms of Competition: Environmental Regulation and Corporate Strategies to Reduce Diesel Vehicle Emissions

    E-Print Network [OSTI]

    de Weck, Olivier L.

    Diesel Vehicle Emissions by Christine Bik-Kay Ng B.S., Civil and Environmental Engineering University Strategies to Reduce Diesel Vehicle Emissions by Christine Bik-Kay Ng Submitted to the Engineering Systems. This research explains the conditions under which competitive regulatory strategies are pursued in the diesel

  13. Air Pollution Control Regulations: No. 6- Continuous Emissions Monitors and Opacity Monitors (Rhode Island)

    Broader source: Energy.gov [DOE]

    Stationary sources, including fossil fuel fired steam or hot water generating units, may be required to install and operate a continuous emissions monitoring system equipped with an opacity monitor...

  14. Permit Regulations for the Construction and, or Operation of Air Emissions Equipment (Mississippi)

    Broader source: Energy.gov [DOE]

    The Permit Board will issue two types of air pollution control permits, a permit to construct air emissions equipment and a State Permit to Operate such equipment. A State Permit to Operate is...

  15. Voluntary reporting of greenhouse gases 1997

    SciTech Connect (OSTI)

    NONE

    1999-05-01T23:59:59.000Z

    The Voluntary Reporting of Greenhouse Gases Program, required by Section 1605(b) of the Energy Policy Act of 1992, records the results of voluntary measures to reduce, avoid, or sequester greenhouse gas emissions. In 1998, 156 US companies and other organizations reported to the Energy information Administration that, during 1997, they had achieved greenhouse gas emission reductions and carbon sequestration equivalent to 166 million tons of carbon dioxide, or about 2.5% of total US emissions for the year. For the 1,229 emission reduction projects reported, reductions usually were measured by comparing an estimate of actual emissions with an estimate of what emissions would have been had the project not been implemented.

  16. Combustion System Development for Medium-Sized Industrial Gas Turbines: Meeting Tight Emission Regulations while Using

    E-Print Network [OSTI]

    Ponce, V. Miguel

    Combustion System Development for Medium-Sized Industrial Gas Turbines: Meeting Tight Emission and the oil & gas industries. The combustion system used in Solar's products are discussed along- bility for the introduction of new combustion systems for gas turbine products to enhance fuel

  17. Emission Standards for Contaminants (Iowa)

    Broader source: Energy.gov [DOE]

    These regulations list emissions standards for various contaminants, and contain special requirements for anaerobic lagoons. These regulations also describe alternative emissions limits, which may...

  18. New Automobile Regulations: Double the Fuel Economy, Half the CO2 Emissions, and Even Automakers Like It

    E-Print Network [OSTI]

    Lutsey, Nic

    2012-01-01T23:59:59.000Z

    ever taken to reduce oil consumption and carbon emissions inever taken to reduce oil consumption and carbon emissions in

  19. CleanFleet. Final report: Volume 7, vehicle emissions

    SciTech Connect (OSTI)

    NONE

    1995-12-01T23:59:59.000Z

    Measurements of exhaust and evaporative emissions from Clean Fleet vans running on M-85, compressed natural gas (CNG), California Phase 2 reformulated gasoline (RFG), propane gas, and a control gasoline (RF-A) are presented. Three vans from each combination of vehicle manufacturer and fuel were tested at the California Air Resources Board (ARB) as they accumulated mileage in the demonstration. Data are presented on regulated emissions, ozone precursors, air toxics, and greenhouse gases. The emissions tests provide information on in-use emissions. That is, the vans were taken directly from daily commercial service and tested at the ARB. The differences in alternative fuel technology provide the basis for a range of technology options. The emissions data reflect these differences, with classes of vehicle/fuels producing either more or less emissions for various compounds relative to the control gasoline.

  20. atmospheric aerosol emissions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    gases, and sulfate aerosols are predicted to raise global temperatures via the "greenhouse effect" (IPCC, 1996), growing emissions of SO2Interactions Among Emissions, Atmospheric...

  1. State Regulations on Airborne Emissions: Update Through 2007 (Update) (released in AEO2008)

    Reports and Publications (EIA)

    2008-01-01T23:59:59.000Z

    States are moving forward with implementation plans for the Clean Air Interstate Rule (CAIR). The program, promulgated by the EPA in March 2005, is a cap-and-trade system designed to reduce emissions of SO2 and NOx. States originally had until March 2007 to submit implementation plans, but the deadline has been extended by another year. CAIR covers 28 eastern states and the District of Columbia. States have the option to participate in the cap-and trade plan or devise their own plans, which can be more stringent than the federal requirements. To date, no state has indicated an intent to form NOx and SO2 programs with emissions limits stricter than those in CAIR, and it is expected that all states will participate in the Environmental Protection Agency administered cap-and-trade program. CAIR remains on schedule for implementation, and Annual Energy Outlook 2008 includes CAIR by assuming that all required states will meet only the federal requirement and will trade credits.

  2. Chapter 46. Ultracold Quantum Gases Ultracold Quantum Gases

    E-Print Network [OSTI]

    of strongly interacting Fermi gases is important for the modeling of neutron stars. Cold atomic gases allow potential of the gas. Away from resonance another length scale comes into play, the scattering length a

  3. Cryogenic method for measuring nuclides and fission gases

    DOE Patents [OSTI]

    Perdue, P.T.; Haywood, F.F.

    1980-05-02T23:59:59.000Z

    A cryogenic method is provided for determining airborne gases and particulates from which gamma rays are emitted. A special dewar counting vessel is filled with the contents of the sampling flask which is immersed in liquid nitrogen. A vertically placed sodium-iodide or germanium-lithium gamma-ray detector is used. The device and method are of particular use in measuring and identifying the radioactive noble gases including emissions from coal-fired power plants, as well as fission gases released or escaping from nuclear power plants.

  4. Global fire emissions and the contribution of deforestation, savanna, forest, agricultural, and peat fires (1997-2009)

    E-Print Network [OSTI]

    2010-01-01T23:59:59.000Z

    K. G. : Direct carbon emissions from Canadian forest fires,O. , and Merlet, P. : Emission of trace gases and aerosolsEstimating direct carbon emissions from Canadian wildland

  5. Using hydroponic biomass to regulate NOx emissions in long range space travel

    SciTech Connect (OSTI)

    Xu, X.H.; Shi, Y.; Chang, S.G.; Fisher, J.; Pisharody, S.; Moran, M.; Wignarajah, K.

    2002-02-01T23:59:59.000Z

    The incineration of wastes is one of the most promising reclamation technologies being developed for life support in long range space travel. However, incineration in a closed environment will build up hazardous NOx if not regulated. A technology that can remove NOx under microgravity conditions without the need of expendables is required. Activated carbon prepared from inedible wheat straw and sweet potato stalk that were grown under hydroponic conditions has been demonstrated to be able to adsorb NO and reduce it to N{sub 2}. The high mineral content in the activated carbon prepared from hydroponic biomass prohibits high surface area production and results in inferior NO adsorption capacity. The removal of mineral from the carbon circumvents the aforementioned negative effect. The optimal production conditions to obtain maximum yield and surface area for the activated carbon have been determined. A parametric study on the NO removal efficiency by the activated carbon has been done. The presence of oxygen in flue gas is essential for effective adsorption of NO by the activated carbon. On the contrary, water vapor inhibits the adsorption efficiency of NO. The NO adsorption capacity and the duration before it exceeds the Space Maximum Allowable Concentration were determined. After the adsorption of NO, the activated carbon can be regenerated for reuse by heating the carbon bed under anaerobic conditions to above 500 C, when the adsorbed NO is reduced to N{sub 2}. The regenerated activated carbon exhibits improved NO adsorption efficiency. However, regeneration had burned off a small percentage of the activated carbon.

  6. Wildland fire emissions, carbon, and climate: U.S. emissions inventories Narasimhan K. Larkin a,

    E-Print Network [OSTI]

    Wildland fire emissions, carbon, and climate: U.S. emissions inventories Narasimhan K. Larkin a: Fire emissions Emissions inventories Greenhouse gases a b s t r a c t Emissions from wildland fire fire emissions change considerably due to fluctuations from year to year with overall fire season

  7. Regulated and Unregulated Exhaust Emissions Comparison for Three Tier II Non-Road Diesel Engines Operating on Ethanol-Diesel Blends

    SciTech Connect (OSTI)

    Merritt, P. M.; Ulmet, V.; McCormick, R. L.; Mitchell, W. E.; Baumgard, K. J.

    2005-11-01T23:59:59.000Z

    Regulated and unregulated emissions (individual hydrocarbons, ethanol, aldehydes and ketones, polynuclear aromatic hydrocarbons (PAH), nitro-PAH, and soluble organic fraction of particulate matter) were characterized in engines utilizing duplicate ISO 8178-C1 eight-mode tests and FTP smoke tests. Certification No. 2 diesel (400 ppm sulfur) and three ethanol/diesel blends, containing 7.7 percent, 10 percent, and 15 percent ethanol, respectively, were used. The three, Tier II, off-road engines were 6.8-L, 8.1-L, and 12.5-L in displacement and each had differing fuel injection system designs. It was found that smoke and particulate matter emissions decreased with increasing ethanol content. Changes to the emissions of carbon monoxide and oxides of nitrogen varied with engine design, with some increases and some decreases. As expected, increasing ethanol concentration led to higher emissions of acetaldehyde (increases ranging from 27 to 139 percent). Benzene emissions were reduced by up to 50 percent with the ethanol-blended fuels. Emissions of 1,3-butadiene were also substantially decreased, with reductions ranging from 24 to 82 percent. Isolated trends were noted for certain PAHs. There was a decrease in 1-nitropyrene with use of ethanol in all cases. Particulate phase 1-nitropyrene was reduced from 18 to 62 percent. There was also a general increase in the proportion of heavy PAHs in the particulate phase with ethanol use, and although less pronounced, a general decrease in light PAHs in the particulate phase.

  8. Spatio-temporal theory of lasing action in optically-pumped rotationally excited molecular gases

    E-Print Network [OSTI]

    Chua, Song-Liang

    We investigate laser emission from optically-pumped rotationally excited molecular gases confined in a metallic cavity. To this end, we have developed a theoretical framework able to accurately describe, both in the spatial ...

  9. Eddy covariance flux measurements of pollutant gases in urban Mexico City

    E-Print Network [OSTI]

    Velasco, Erik

    Eddy covariance (EC) flux measurements of the atmosphere/surface exchange of gases over an urban area are a direct way to improve and evaluate emissions inventories, and, in turn, to better understand urban atmospheric ...

  10. Welcome to Greenhouse Gases: Science and Technology: Editorial

    SciTech Connect (OSTI)

    Oldenburg, C.M.; Maroto-Valer, M.M.

    2011-02-01T23:59:59.000Z

    This editorial introduces readers and contributors to a new online journal. Through the publication of articles ranging from peer-reviewed research papers and short communications, to editorials and interviews on greenhouse gas emissions science and technology, this journal will disseminate research results and information that address the global crisis of anthropogenic climate change. The scope of the journal includes the full spectrum of research areas from capture and separation of greenhouse gases from flue gases and ambient air, to beneficial utilization, and to sequestration in deep geologic formations and terrestrial (plant and soil) systems, as well as policy and technoeconomic analyses of these approaches.

  11. Air Pollution Control Regulations: No. 7- Emission of Air Contaminants Detrimental to Person or Property (Rhode Island)

    Broader source: Energy.gov [DOE]

    No person shall emit any contaminant which either alone or in connection with other emissions, by reason of their concentration or duration, may be injurious to human, plant or animal life, or...

  12. `Capture ready' regulation of fossil fuel power plants Betting the UK's carbon emissions on promises of future technology

    E-Print Network [OSTI]

    Haszeldine, Stuart

    -linked UK energy and climate change policies. Current climate change targets include 20% reduction of national green house gas emissions by 2010 and 80% reduction by 2050 from a 1990 baseline. However, only

  13. Novel Application of Air Separation Membranes Reduces NOx Emissions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    permeation of gases using an air separation membrane. Can be retrofitted to existing engines Significantly reduces NOx emissions (as much as 70%) with just a 2% nitrogen...

  14. Improved correlations for retrograde gases 

    E-Print Network [OSTI]

    Crogh, Arne

    1996-01-01T23:59:59.000Z

    Three correlations for retrograde gases have been developed. First, a correlation was developed that relates the composition of a retrograde gas-condensate mixture at any depletion stage to the composition at its dew point ...

  15. Curbing Greenhouse Gases: Agriculture's Role

    E-Print Network [OSTI]

    McCarl, Bruce A.

    the Kyoto results in more detail elsewhere in this issue. Emissions trading - Creating a market for emission rights Importantly, the Protocol encourages emissions trading. Emissions are limited by country emissions trading system, much like the trading scheme used in the U.S. acid #12;3 rain program. The total

  16. Excess Emissions (New Mexico)

    Broader source: Energy.gov [DOE]

    This regulation establishes requirements for a source whose operation results in an excess emission and to establish criteria for a source whose operation results in an excess emission to claim an...

  17. Kolstad: EKC Dec 2005 Interpreting Estimated Environmental Kuznets Curves for Greenhouse Gases

    E-Print Network [OSTI]

    Kolstad, Charles

    Kolstad: EKC Dec 2005 Interpreting Estimated Environmental Kuznets Curves for Greenhouse Gases to interpret a relationship between income and carbon emissions in a country (the environmental Kuznets curve), it was primarily concerned with Environmental Kuznets Curves (EKC) for greenhouse gas emissions. The EKC literature

  18. Effects of Biochar and Basalt Additions on Carbon Sequestration and Fluxes of Greenhouse Gases in Soils

    E-Print Network [OSTI]

    Vallino, Joseph J.

    Effects of Biochar and Basalt Additions on Carbon Sequestration and Fluxes of Greenhouse Gases Emissions--Carbon Dioxide Emissions--Sequestration and Storage--Biochar--Basalt--Organic Fertilizers, this investigation focuses on the range of potential of different soil additives to enhance sequestration and storage

  19. Closed loop engine control for regulating NOx emissions, using a two-dimensional fuel-air curve

    DOE Patents [OSTI]

    Bourn, Gary D.; Smith, Jack A.; Gingrich, Jess W.

    2007-01-30T23:59:59.000Z

    An engine control strategy that ensures that NOx emissions from the engine will be maintained at an acceptable level. The control strategy is based on a two-dimensional fuel-air curve, in which air manifold pressure (AMP) is a function of fuel header pressure and engine speed. The control strategy provides for closed loop NOx adjustment to a base AMP value derived from the fuel-air curve.

  20. Cost of Ownership and Well-to-Wheels Carbon Emissions/Oil Use of Alternative Fuels and Advanced Light-Duty Vehicle Technologies

    SciTech Connect (OSTI)

    Elgowainy, Mr. Amgad [Argonne National Laboratory (ANL); Rousseau, Mr. Aymeric [Argonne National Laboratory (ANL); Wang, Mr. Michael [Argonne National Laboratory (ANL); Ruth, Mr. Mark [National Renewable Energy Laboratory (NREL); Andress, Mr. David [David Andress & Associates, Inc.; Ward, Jacob [U.S. Department of Energy; Joseck, Fred [U.S. Department of Energy; Nguyen, Tien [U.S. Department of Energy; Das, Sujit [ORNL

    2013-01-01T23:59:59.000Z

    The U.S. Department of Energy (DOE), Argonne National Laboratory (Argonne), and the National Renewable Energy Laboratory (NREL) updated their analysis of the well-to-wheels (WTW) greenhouse gases (GHG) emissions, petroleum use, and the cost of ownership (excluding insurance, maintenance, and miscellaneous fees) of vehicle technologies that have the potential to significantly reduce GHG emissions and petroleum consumption. The analyses focused on advanced light-duty vehicle (LDV) technologies such as plug-in hybrid, battery electric, and fuel cell electric vehicles. Besides gasoline and diesel, alternative fuels considered include natural gas, advanced biofuels, electricity, and hydrogen. The Argonne Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) and Autonomie models were used along with the Argonne and NREL H2A models.

  1. Sulfur Dioxide Regulations (Ohio)

    Broader source: Energy.gov [DOE]

    This chapter of the law establishes that the Ohio Environmental Protection Agency provides sulfur dioxide emission limits for every county, as well as regulations for the emission, monitoring and...

  2. Kansas Air Quality Regulations (Kansas)

    Broader source: Energy.gov [DOE]

    All new air contaminant emission sources or alterations to emission sources that are required to be reported shall be in compliance with all applicable emission control regulations at the time that...

  3. The use of onboard diagnostics to reduce emissions in automobiles

    E-Print Network [OSTI]

    Perez, Alberto, Jr

    2009-01-01T23:59:59.000Z

    The emissions from automobiles are very harmful and include gases such as Carbon Dioxide, Nitrous Oxide, and Sulfur Dioxide. One of the main reasons OBD was created was to control emissions however it currently only monitors ...

  4. An Analysis of the European Emission Trading Scheme

    E-Print Network [OSTI]

    Reilly, John M.

    An international emissions trading system is a featured instrument in the Kyoto Protocol to the Framework Convention on Climate Change, designed to reduce emissions of greenhouse gases among major industrial countries. The ...

  5. atmospheric pb emissions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    emission of greenhouse gases into the atmosphere such as CO2, CH4, N2O and CFCs. The CO2 emissions Montes-Hernandez, German 19 Measurement of the Cross Section for...

  6. Coal-Fired Power Plants, Greenhouse Gases, and State Statutory Substantial Endangerment Provisions: Climate Change Comes to Kansas

    E-Print Network [OSTI]

    Glicksman, Robert L.

    2008-04-01T23:59:59.000Z

    economy standards on motor vehicles by states such as California. But the states have also targeted stationary sources of greenhouse gases. In particular, they have sought to minimize carbon dioxide emissions from coal-fired power plants. States have used...

  7. Emissions of volatile organic compounds inferred from airborne flux measurements over a megacity

    E-Print Network [OSTI]

    Karl, T.; Apel, E.; Hodzic, A.; Riemer, D. D; Blake, D. R; Wiedinmyer, C.

    2009-01-01T23:59:59.000Z

    P. R. , and Hao, W. M. : Emissions from forest fires nearM. O. and Merlet, P. : Emission of trace gases and aerosolsW. : Automo- bile Emissions of Acetonitrile: Assessment of

  8. Air Pollution Emissions and Abatement (Minnesota) | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Environmental Regulations A person who controls the source of an emission must notify the Pollution Control Agency immediately of excessive or abnormal unpermitted emissions, and...

  9. become more important as countries agree to emission reduction targets

    E-Print Network [OSTI]

    Constable, Steve

    : immediate stabilization of carbon dioxide emissions, regulation of air pollution that balances removal

  10. Greenhouse gas emissions of biofuels, Improving Life Cycle Assessments by taking into

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Greenhouse gas emissions of biofuels, Improving Life Cycle Assessments by taking into account local.......................................................................................................................................................14 Chapter 1 Biofuels, greenhouse gases and climate change 1 Introduction

  11. Voluntary reporting of greenhouse gases under Section 1605(b) of the Energy Policy Act of 1992: General Guidelines

    SciTech Connect (OSTI)

    Not Available

    1994-10-01T23:59:59.000Z

    Because of concerns with the growing threat of global climate change from increasing emissions of greenhouse gases, Congress authorized a voluntary program for the public to report achievements in reducing those gases. This document offers guidance on recording historic and current greenhouse gas emissions, emissions reductions, and carbon sequestration. Under the Energy Policy Act (EPAct) reporters will have the opportunity to highlight specific achievements. If you have taken actions to lessen the greenhouse gas effect, either by decreasing greenhouse gas emissions or by sequestering carbon, the Department of Energy (DOE) encourages you to report your achievements under this program. The program has two related, but distinct parts. First, the program offers you an opportunity to report your annual emissions of greenhouse gases. Second, the program records your specific projects to reduce greenhouse gas emissions and increase carbon sequestration. Although participants in the program are strongly encouraged to submit reports on both, reports on either annual emissions or emissions reductions and carbon sequestration projects will be accepted. These guidelines and the supporting technical documents outline the rationale for the program and approaches to analyzing emissions and emissions reduction projects. Your annual emissions and emissions reductions achievements will be reported.

  12. Development and use of the GREET model to estimate fuel-cycle energy use and emissions of various transportation technologies and fuels

    SciTech Connect (OSTI)

    Wang, M.Q.

    1996-03-01T23:59:59.000Z

    This report documents the development and use of the Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model. The model, developed in a spreadsheet format, estimates the full fuel- cycle emissions and energy use associated with various transportation fuels for light-duty vehicles. The model calculates fuel-cycle emissions of five criteria pollutants (volatile organic compounds, carbon monoxide, nitrogen oxides, sulfur oxides, and particulate matter measuring 10 microns or less) and three greenhouse gases (carbon dioxide, methane, and nitrous oxide). The model also calculates the total fuel-cycle energy consumption, fossil fuel consumption, and petroleum consumption using various transportation fuels. The GREET model includes 17 fuel cycles: petroleum to conventional gasoline, reformulated gasoline, clean diesel, liquefied petroleum gas, and electricity via residual oil; natural gas to compressed natural gas, liquefied petroleum gas, methanol, hydrogen, and electricity; coal to electricity; uranium to electricity; renewable energy (hydrogen, solar energy, and wind) to electricity; corn, woody biomass, and herbaceous biomass to ethanol; and landfill gases to methanol. This report presents fuel-cycle energy use and emissions for a 2000 model-year car powered by each of the fuels that are produced from the primary energy sources considered in the study.

  13. Industrial Gases as a Vehicle for Competitiveness

    E-Print Network [OSTI]

    Dale, J. R.

    -based separation technology was developing to offer an alternative to cryogenic separation for those instances when neither high purity or cryogenic properties were required by the application. It resulted in gas of lower than 99.9995%, "five-nines", purity...INDUSTRIAL GASES AS A VEHICLE FOR COMPETITIVENESS James R. Dale, Director, Technology Programs, Airco Industrial Gases Division, The BOC Group, Inc., Murray Hill, New Jersey ABSTRACT Industrial gases are produced using compressed air...

  14. An Analysis of the Effectiveness and Impact of Mandatory Company Greenhouse Gas Emission Reporting Under The Companies Act 2006 (Strategic Report and Directors’ Report) Regulations 2013 

    E-Print Network [OSTI]

    Plaza, Celina

    2014-11-22T23:59:59.000Z

    The intent of this research is to examine the effectiveness and impact of the UK’s mandatory reporting of company greenhouse gas emissions, otherwise known as carbon dioxide equivalent (CO2e) emissions, in accordance to ...

  15. EIA - Greenhouse Gas Emissions - High-GWP gases

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688 760,877 951,322 1,381,127byForms What'sAnnual2 EIA372.5.

  16. EIA - Emissions of Greenhouse Gases in the United States 2009

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001)gasoline353/06) 2YonthlyEnergy Markets 9,Analysis‹

  17. Anode supported single chamber solid oxide fuel cells operating in exhaust gases of thermal engine

    E-Print Network [OSTI]

    Boyer, Edmond

    Anode supported single chamber solid oxide fuel cells operating in exhaust gases of thermal engine. Conventional solid oxide fuel cells are separated into two compartments containing each electrode split hydrocarbons, pollutant emissions reduction hal-01056363,version1-21Aug2014 #12;1. Introduction Solid oxide

  18. Internal structure and expansion dynamics of laser ablation plumes into ambient gases

    E-Print Network [OSTI]

    Harilal, S. S.

    Internal structure and expansion dynamics of laser ablation plumes into ambient gases S. S. Harilal 13 December 2002 The effect of ambient gas on the expansion dynamics of the plasma generated by laser together with time resolved emission diagnostics, a triple structure of the plume was observed

  19. Preferences for change: Do individuals prefer voluntary actions, soft regulations, or hard regulations to

    E-Print Network [OSTI]

    Indiana University

    ' environmental attitudes (as assessed using the New Ecological Paradigm scale) had a strong positive relationship states sued the EPA to force the agency to regulate carbon dioxide and other green- house gases (GHGs

  20. Particle entanglement in rotating gases

    SciTech Connect (OSTI)

    Liu Zhao; Fan Heng [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

    2010-06-15T23:59:59.000Z

    In this paper, we investigate the particle entanglement in two-dimensional (2D) weakly interacting rotating Bose and Fermi gases. We find that both particle localization and vortex localization can be indicated by particle entanglement. We also use particle entanglement to show the occurrence of edge reconstruction of rotating fermions. The different properties of condensate phase and vortex liquid phase of bosons can be reflected by particle entanglement and in vortex liquid phase we construct the same trial wave function with that in [Phys. Rev. Lett. 87, 120405 (2001)] from the viewpoint of entanglement to relate the ground state with quantum Hall state. Finally, the relation between particle entanglement and interaction strength is studied.

  1. Granular gases under extreme driving

    E-Print Network [OSTI]

    W. Kang; J. Machta; E. Ben-Naim

    2010-08-06T23:59:59.000Z

    We study inelastic gases in two dimensions using event-driven molecular dynamics simulations. Our focus is the nature of the stationary state attained by rare injection of large amounts of energy to balance the dissipation due to collisions. We find that under such extreme driving, with the injection rate much smaller than the collision rate, the velocity distribution has a power-law high energy tail. The numerically measured exponent characterizing this tail is in excellent agreement with predictions of kinetic theory over a wide range of system parameters. We conclude that driving by rare but powerful energy injection leads to a well-mixed gas and constitutes an alternative mechanism for agitating granular matter. In this distinct nonequilibrium steady-state, energy cascades from large to small scales. Our simulations also show that when the injection rate is comparable with the collision rate, the velocity distribution has a stretched exponential tail.

  2. Nebraska Air Quality Regulations (Nebraska)

    Broader source: Energy.gov [DOE]

    These regulations, promulgated by the Department of Environmental Quality, contain provisions pertaining to ambient air quality standards, pollution source operating permits, emissions reporting,...

  3. Identifying Options for Deep Reductions in Greenhouse Gas Emissions from California Transportation: Meeting an 80% Reduction Goal in 2050

    E-Print Network [OSTI]

    Yang, Christopher; McCollum, David L; McCarthy, Ryan; Leighty, Wayne

    2008-01-01T23:59:59.000Z

    of U.S. Croplands for Biofuels Increases Greenhouse GasesGHG Emissions from Biofuels . in STEPS Research Symposium .NRDC, Growing Energy: How Biofuels Can Help End America's

  4. Synthesis and development of processes for the recovery of sulfur from acid gases. Part 1, Development of a high-temperature process for removal of H{sub 2}S from coal gas using limestone -- thermodynamic and kinetic considerations; Part 2, Development of a zero-emissions process for recovery of sulfur from acid gas streams

    SciTech Connect (OSTI)

    Towler, G.P.; Lynn, S.

    1993-05-01T23:59:59.000Z

    Limestone can be used more effectively as a sorbent for H{sub 2}S in high-temperature gas-cleaning applications if it is prevented from undergoing calcination. Sorption of H{sub 2}S by limestone is impeded by sintering of the product CaS layer. Sintering of CaS is catalyzed by CO{sub 2}, but is not affected by N{sub 2} or H{sub 2}. The kinetics of CaS sintering was determined for the temperature range 750--900{degrees}C. When hydrogen sulfide is heated above 600{degrees}C in the presence of carbon dioxide elemental sulfur is formed. The rate-limiting step of elemental sulfur formation is thermal decomposition of H{sub 2}S. Part of the hydrogen thereby produced reacts with CO{sub 2}, forming CO via the water-gas-shift reaction. The equilibrium of H{sub 2}S decomposition is therefore shifted to favor the formation of elemental sulfur. The main byproduct is COS, formed by a reaction between CO{sub 2} and H{sub 2}S that is analogous to the water-gas-shift reaction. Smaller amounts of SO{sub 2} and CS{sub 2} also form. Molybdenum disulfide is a strong catalyst for H{sub 2}S decomposition in the presence of CO{sub 2}. A process for recovery of sulfur from H{sub 2}S using this chemistry is as follows: Hydrogen sulfide is heated in a high-temperature reactor in the presence of CO{sub 2} and a suitable catalyst. The primary products of the overall reaction are S{sub 2}, CO, H{sub 2} and H{sub 2}O. Rapid quenching of the reaction mixture to roughly 600{degrees}C prevents loss Of S{sub 2} during cooling. Carbonyl sulfide is removed from the product gas by hydrolysis back to CO{sub 2} and H{sub 2}S. Unreacted CO{sub 2} and H{sub 2}S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H{sub 2} and CO, which recovers the hydrogen value from the H{sub 2}S. This process is economically favorable compared to the existing sulfur-recovery technology and allows emissions of sulfur-containing gases to be controlled to very low levels.

  5. An Infrared Spectral Database for Detection of Gases Emitted...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Database for Detection of Gases Emitted by Biomass Burning. An Infrared Spectral Database for Detection of Gases Emitted by Biomass Burning. Abstract: We report the construction of...

  6. atmospheric greenhouse gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GASES BACKGROUND CiteSeer Summary: The Earths climate depends on the amount of solar radiation received and the atmospheric abundance of clouds and greenhouse gases. The...

  7. aerosol precursor gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sunlight 11 GREENHOUSE GASES GREENHOUSE GASES BACKGROUND CiteSeer Summary: The Earths climate depends on the amount of solar radiation received and the atmospheric abundance of...

  8. Energy Efficiency and Greenhouse Gases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency and Greenhouse Gases Energy Efficiency and Greenhouse Gases Mission The team establishes an energy conservation program, as deemed appropriate for LM operations...

  9. Library Regulations Library Regulations

    E-Print Network [OSTI]

    Birmingham, University of

    Library Regulations 2012-13 Library Regulations UNIVERSITY OF BIRMINGHAM REGULATIONS LIBRARY REGULATIONS Preamble: The Library Regulations apply to all users of library facilities managed on behalf of the University by Library Services, and thus there are sections that apply also to non- members of the University

  10. Light Collection in Liquid Noble Gases

    SciTech Connect (OSTI)

    McKinsey, Dan [Yale University

    2013-05-29T23:59:59.000Z

    Liquid noble gases are increasingly used as active detector materials in particle and nuclear physics. Applications include calorimeters and neutrino oscillation experiments as well as searches for neutrinoless double beta decay, direct dark matter, muon electron conversion, and the neutron electric dipole moment. One of the great advantages of liquid noble gases is their copious production of ultraviolet scintillation light, which contains information about event energy and particle type. I will review the scintillation properties of the various liquid noble gases and the means used to collect their scintillation light, including recent advances in photomultiplier technology and wavelength shifters.

  11. Estimating Policy-Driven Greenhouse Gas Emissions Trajectories in California

    E-Print Network [OSTI]

    , such as high global warming potential gases, waste treatment, agriculture and forestry) in varying degrees and gaseous hydrocarbon fuels, electricity and hydrogen), and finally calculated emissions of GHGs and three

  12. Persistent sensitivity of Asian aerosol to emissions of nitrogen oxides

    E-Print Network [OSTI]

    Kharol, S. K.

    We use a chemical transport model and its adjoint to examine the sensitivity of secondary inorganic aerosol formation to emissions of precursor trace gases from Asia. Sensitivity simulations indicate that secondary inorganic ...

  13. Synthetic Assessment of Historical Anthropogenic Sulfur Dioxide (SO2) Emissions

    E-Print Network [OSTI]

    activities (Smith et al., 2011) · The following 100 years emissions had rapidly increased by use of coal, and by anthropogenic sources, such as burning of coal, oil and gases. SO2 as a pollutant not only changes the climate

  14. Comparing the effects of greenhouse gas emissions on global warming

    E-Print Network [OSTI]

    Eckaus, Richard S.

    1990-01-01T23:59:59.000Z

    Policies dealing with global warming require a measure of the effects of the emissions of greenhouse gases that create different magnitudes of instantaneous radiative forcing and have different lifetimes. The Global Warming ...

  15. Analytical Framework to Evaluate Emission Control Systems for Marine Engines

    E-Print Network [OSTI]

    Jayaram, Varalakshmi

    2010-01-01T23:59:59.000Z

    Ignition Engine Fueled with Biodiesel Blends. Society ofRegulated emissions from biodiesel fuels from on/ off-roadEffects of Methyl Ester Biodiesel Blends on NOx Emissions.

  16. Emission estimates for air pollution transport models.

    SciTech Connect (OSTI)

    Streets, D. G.

    1998-10-09T23:59:59.000Z

    The results of studies of energy consumption and emission inventories in Asia are discussed. These data primarily reflect emissions from fuel combustion (both biofuels and fossil fuels) and were collected to determine emissions of acid-deposition precursors (SO{sub 2} and NO{sub x}) and greenhouse gases (CO{sub 2} CO, CH{sub 4}, and NMHC) appropriate to RAINS-Asia regions. Current work is focusing on black carbon (soot), volatile organic compounds, and ammonia.

  17. Impacts of ethanol fuel level on emissions of regulated and unregulated pollutants from a fleet of gasoline light-duty vehicles

    SciTech Connect (OSTI)

    Karavalakis, Georgios; Durbin, Thomas; Shrivastava, ManishKumar B.; Zheng, Zhongqing; Villella, Phillip M.; Jung, Hee-Jung

    2012-03-30T23:59:59.000Z

    The study investigated the impact of ethanol blends on criteria emissions (THC, NMHC, CO, NOx), greenhouse gas (CO2), and a suite of unregulated pollutants in a fleet of gasoline-powered light-duty vehicles. The vehicles ranged in model year from 1984 to 2007 and included one Flexible Fuel Vehicle (FFV). Emission and fuel consumption measurements were performed in duplicate or triplicate over the Federal Test Procedure (FTP) driving cycle using a chassis dynamometer for four fuels in each of seven vehicles. The test fuels included a CARB phase 2 certification fuel with 11% MTBE content, a CARB phase 3 certification fuel with a 5.7% ethanol content, and E10, E20, E50, and E85 fuels. In most cases, THC and NMHC emissions were lower with the ethanol blends, while the use of E85 resulted in increases of THC and NMHC for the FFV. CO emissions were lower with ethanol blends for all vehicles and significantly decreased for earlier model vehicles. Results for NOx emissions were mixed, with some older vehicles showing increases with increasing ethanol level, while other vehicles showed either no impact or a slight, but not statistically significant, decrease. CO2 emissions did not show any significant trends. Fuel economy showed decreasing trends with increasing ethanol content in later model vehicles. There was also a consistent trend of increasing acetaldehyde emissions with increasing ethanol level, but other carbonyls did not show strong trends. The use of E85 resulted in significantly higher formaldehyde and acetaldehyde emissions than the specification fuels or other ethanol blends. BTEX and 1,3-butadiene emissions were lower with ethanol blends compared to the CARB 2 fuel, and were almost undetectable from the E85 fuel. The largest contribution to total carbonyls and other toxics was during the cold-start phase of FTP.

  18. Denitrification of combustion gases. [Patent application

    DOE Patents [OSTI]

    Yang, R.T.

    1980-10-09T23:59:59.000Z

    A method for treating waste combustion gas to remove the nitrogen oxygen gases therefrom is disclosed wherein the waste gas is first contacted with calcium oxide which absorbs and chemically reacts with the nitrogen oxide gases therein at a temperature from about 100/sup 0/ to 430/sup 0/C. The thus reacted calcium oxide (now calcium nitrate) is then heated at a temperature range between about 430/sup 0/ and 900/sup 0/C, resulting in regeneration of the calcium oxide and production of the decomposition gas composed of nitrogen and nitrogen oxide gas. The decomposition gases can be recycled to the calcium oxide contacting step to minimize the amount of nitrogen oxide gases in the final product gas.

  19. Biological production of products from waste gases

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    2002-01-22T23:59:59.000Z

    A method and apparatus are designed for converting waste gases from industrial processes such as oil refining, and carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various products, such as organic acids, alcohols, hydrogen, single cell protein, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  20. Trend analysis from 1970 to 2008 and model evaluation of EDGARv4 global gridded anthropogenic mercury emissions

    E-Print Network [OSTI]

    Muntean, Marilena

    The Emission Database for Global Atmospheric Research (EDGAR) provides a time-series of man-made emissions of greenhouse gases and short-lived atmospheric pollutants from 1970 to 2008. Mercury is included in EDGARv4.tox1, ...

  1. Air Pollution Control Regulations: No. 9- Air Pollution Control Permits (Rhode Island)

    Broader source: Energy.gov [DOE]

    These regulations describe permitting procedures and requirements for minor and major sources of emissions.

  2. An investigation of the sub-grid variability of trace gases and aerosols for global climate modeling

    SciTech Connect (OSTI)

    Qian, Yun; Gustafson, William I.; Fast, Jerome D.

    2010-07-29T23:59:59.000Z

    One fundamental property and limitation of grid based models is their inability to identify spatial details smaller than the grid cell size. While decades of work have gone into developing sub-grid treatments for clouds and land surface processes in climate models, the quantitative understanding of sub-grid processes and variability for aerosols and their precursors is much poorer. In this study, WRF-Chem is used to simulate the trace gases and aerosols over central Mexico during the 2006 MILAGRO field campaign, with multiple spatial resolutions and emission/terrain scenarios. Our analysis focuses on quantifying the sub-grid variability (SGV) of trace gases and aerosols within a typical global climate model grid cell, i.e. 75x75 km2. Our results suggest that a simulation with 3-km horizontal grid spacing adequately reproduces the overall transport and mixing of trace gases and aerosols downwind of Mexico City, while 75-km horizontal grid spacing is insufficient to represent local emission and terrain-induced flows along the mountain ridge, subsequently affecting the transport and mixing of plumes from nearby sources. Therefore, the coarse model grid cell average may not correctly represent aerosol properties measured over polluted areas. Probability density functions (PDFs) for trace gases and aerosols show that secondary trace gases and aerosols, such as O3, sulfate, ammonium, and nitrate, are more likely to have a relatively uniform probability distribution (i.e. smaller SGV) over a narrow range of concentration values. Mostly inert and long-lived trace gases and aerosols, such as CO and BC, are more likely to have broad and skewed distributions (i.e. larger SGV) over polluted regions. Over remote areas, all trace gases and aerosols are more uniformly distributed compared to polluted areas. Both CO and O3 SGV vertical profiles are nearly constant within the PBL during daytime, indicating that trace gases are very efficiently transported and mixed vertically by turbulence. But, simulated horizontal variability indicates that trace gases and aerosols are not well mixed horizontally in the PBL. During nighttime the SGV for trace gases is maximum at the surface, and quickly decreases with height. Unlike the trace gases, the SGV of BC and secondary aerosols reaches a maximum at the PBL top during the day. The SGV decreases with distance away from the polluted urban area, has a more rapid decrease for long-lived trace gases and aerosols than for secondary ones, and is greater during daytime than nighttime. The SGV of trace gases and aerosols is generally larger than for meteorological quantities. Emissions can account for up to 50% of the SGV over urban areas such as Mexico City during daytime for less-reactive trace gases and aerosols, such as CO and BC. The impact of emission spatial variability on SGV decays with altitude in the PBL and is insignificant in the free troposphere. The emission variability affects SGV more significantly during daytime (rather than nighttime) and over urban (rather than rural or remote) areas. The terrain, through its impact on meteorological fields such as wind and the PBL structure, affects dispersion and transport of trace gases and aerosols and their SGV.

  3. Greenhouse gases accounting and reporting for waste management - A South African perspective

    SciTech Connect (OSTI)

    Friedrich, Elena, E-mail: Friedriche@ukzn.ac.z [University of KwaZulu-Natal, CRECHE, School of Civil Engineering, Surveying and Construction, Howard College Campus, Durban (South Africa); Trois, Cristina [University of KwaZulu-Natal, CRECHE, School of Civil Engineering, Surveying and Construction, Howard College Campus, Durban (South Africa)

    2010-11-15T23:59:59.000Z

    This paper investigates how greenhouse gases are accounted and reported in the waste sector in South Africa. Developing countries (including South Africa) do not have binding emission reduction targets, but many of them publish different greenhouse gas emissions data which have been accounted and reported in different ways. Results show that for South Africa, inventories at national and municipal level are the most important tools in the process of accounting and reporting greenhouse gases from waste. For the development of these inventories international initiatives were important catalysts at national and municipal levels, and assisted in developing local expertise, resulting in increased output quality. However, discrepancies in the methodology used to account greenhouse gases from waste between inventories still remain a concern. This is a challenging issue for developing countries, especially African ones, since higher accuracy methods are more data intensive. Analysis of the South African inventories shows that results from the recent inventories can not be compared with older ones due to the use of different accounting methodologies. More recently the use of Clean Development Mechanism (CDM) procedures in Africa, geared towards direct measurements of greenhouse gases from landfill sites, has increased and resulted in an improvement of the quality of greenhouse gas inventories at municipal level.

  4. Method for determining the concentration of atomic species in gases and solids

    DOE Patents [OSTI]

    Loge, Gary W. (304 Cheryl Ave., Los Alamos, NM 87544)

    1998-01-01T23:59:59.000Z

    Method for determining the concentration of atomic species in gases and solids. Measurement of at least two emission intensities from a species in a sample that is excited by incident laser radiation. Which generates a plasma therein after a sufficient time period has elapsed and during a second time period, permits an instantaneous temperature to be established within the sample. The concentration of the atomic species to be determined is then derived from the known emission intensity of a predetermined concentration of that species in the sample at the measured temperature, a quantity which is measured prior to the determination of the unknown concentration, and the actual measured emission from the unknown species, or by this latter emission and the emission intensity of a species having known concentration within the sample such as nitrogen for gaseous air samples.

  5. Method for determining the concentration of atomic species in gases and solids

    DOE Patents [OSTI]

    Loge, Gary W. (2998 Plaza Blanca, Santa Fe, NM 87505)

    1999-01-01T23:59:59.000Z

    Method for determining the concentration of atomic species in gases and solids. Measurement of at least two emission intensities from a species in a plasma containing the species after a sufficient time period has elapsed after the generation of the plasma and during a second time period, permits an instantaneous temperature to be established within the sample. The concentration of the atomic species to be determined is then derived from the known emission intensity of a predetermined concentration of that species in the sample at the measured temperature, a quantity which is measured prior to the determination of the unknown concentration, and the actual measured emission from the unknown species, or by this latter emission and the emission intensity of a species having known concentration within the sample.

  6. 6, 57735796, 2006 Vehicular emissions

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    be partly responsible for lower CO2 and higher CO and NO emission factors. Also, a fast reduction the emission (in g/km) of key and non-regulated pollutants, such as CO2, CO, NO, SO2, NH3, HCHO, NMHC, dur-10 of pollutants, even from a super ultra-low emission vehicle (SULEV). The emissions of HC's, NOx, CO20 and CO2

  7. Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas emissions into the atmosphere

    E-Print Network [OSTI]

    Montes-Hernandez, German

    Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas emissions into the atmosphere of anthropogenic emission of greenhouse gases into the atmosphere such as CO2, CH4, N2O and CFCs. The CO2 emissions to reflect, adsorb and emit the solar energy. However, the continuous emissions of CO2 into the atmosphere

  8. Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN

    E-Print Network [OSTI]

    2011-01-01T23:59:59.000Z

    and Fehsenfeld, F. C. : Emission sources and ocean uptake ofand No- vakov, T. : Emissions of trace gases and particlesGroot, W. J. : Future emissions from Canadian boreal forest

  9. Pollution markets with imperfectly observed emissions

    E-Print Network [OSTI]

    Montero, Juan-Pablo

    2004-01-01T23:59:59.000Z

    I study the advantages of pollution permit markets over traditional standard regulations when the regulator has incomplete information on firms? emissions and costs of production and abatement (e.g., air pollution in large ...

  10. Pollution Markets with Imperfectly Observed Emissions

    E-Print Network [OSTI]

    Montero, Juan-Pablo

    2006-03-14T23:59:59.000Z

    I study the advantages of pollution permit markets over traditional standard regulations when the regulator has incomplete information on firms’ emissions and costs of production and abatement (e.g., air pollution in large cities). Because...

  11. Evaluation of Corona Reactors of Several Geometries for a Plasma Assisted Nitrogen Oxide Emission Reduction Device

    SciTech Connect (OSTI)

    Herling, Darrell R.; Smith, Monty R.; Hemingway, Mark D.; Goulette, David; Silvis, Thomas W.

    2000-08-09T23:59:59.000Z

    Proposed vehicle emissions regulations for the near future have prompted automotive manufactures and component suppliers to focus heavily on developing more efficient exhaust aftertreatment devices to lower emissions from spark and compression ignition engines. One of the primary pollutants from lean-burn engines, especially from diesels, are oxides of nitrogen (NOx). Current three-way catalytic converters will not have adequate performance to meet future emission reduction requirements. Therefore, there is a need for researchers and engineers to develop efficient exhaust aftertreatment devices that will reduce NOx emissions from lean-burn engines. These devices must have very high conversion of NOx gases, be unaffected by exhaust-gas impurity such as sulfur, and have minimal impact on vehicle operations and fuel economy. An effective technology for NOx control that is currently receiving a lot of attention is a non-thermal plasma system. This system is comprised of a two-stage corona generation device (plasma reactor) and reduction catalyst that reduces nitric oxide and nitrogen dioxide emissions to nitrogen.

  12. Investigation of feasibility of injecting power plant waste gases for enhanced coalbed methane recovery from low rank coals in Texas 

    E-Print Network [OSTI]

    Saugier, Luke Duncan

    2004-09-30T23:59:59.000Z

    Greenhouse gases such as carbon dioxide (CO2) may be to blame for a gradual rise in the average global temperature. The state of Texas emits more CO2 than any other state in the U.S., and a large fraction of emissions are ...

  13. Stationary light in cold atomic gases

    E-Print Network [OSTI]

    Gor Nikoghosyan; Michael Fleischhauer

    2009-09-16T23:59:59.000Z

    We discuss stationary light created by a pair of counter-propagating control fields in Lambda-type atomic gases with electromagnetically induced transparency for the case of negligible Doppler broadening. In this case the secular approximation used in the discussion of stationary light in hot vapors is no longer valid. We discuss the quality of the effective light-trapping system and show that in contrast to previous claims it is finite even for vanishing ground-state dephasing. The dynamics of the photon loss is in general non exponential and can be faster or slower than in hot gases.

  14. 2010 LANL radionuclide air emissions report /

    SciTech Connect (OSTI)

    Fuehne, David P.

    2011-06-01T23:59:59.000Z

    The emissions of radionuclides from Department of Energy Facilities such as Los Alamos National Laboratory (LANL) are regulated by the Amendments to the Clean Air Act of 1990, National Emissions Standards for Hazardous Air Pollutants (40 CFR 61 Subpart H). These regulations established an annual dose limit of 10 mrem to the maximally exposed member of the public attributable to emissions of radionuclides. This document describes the emissions of radionuclides from LANL and the dose calculations resulting from these emissions for calendar year 2010. This report meets the reporting requirements established in the regulations.

  15. Fluidized bed controls refinery emissions

    SciTech Connect (OSTI)

    Abdulally, I.F.; Kersey, B.R.

    1986-05-01T23:59:59.000Z

    In early 1983, two fluidized bed, waste heat boilers entered into service at the Ashland Petroleum Company refinery site in Ashland, Kentucky. These fluidized bed units are coupled to the regeneration end of a newly developed reduced crude conversion (RCC) process and served the purpose of reducing CO, SO/sub 2/ and NO/sub x/ emissions while recuperating waste heat from the regenerator process off gases.

  16. Trading quasi-emission permits

    E-Print Network [OSTI]

    Montero, Juan-Pablo

    2002-01-01T23:59:59.000Z

    I study the design of environmental policies for a regulator that has incomplete information on firms' emissions and costs of production and abatement (e.g., air pollution in cities with numerous small polluting sources). ...

  17. Updated greenhouse gas and criteria air pollutant emission factors and their probability distribution functions for electricity generating units

    SciTech Connect (OSTI)

    Cai, H.; Wang, M.; Elgowainy, A.; Han, J. (Energy Systems)

    2012-07-06T23:59:59.000Z

    Greenhouse gas (CO{sub 2}, CH{sub 4} and N{sub 2}O, hereinafter GHG) and criteria air pollutant (CO, NO{sub x}, VOC, PM{sub 10}, PM{sub 2.5} and SO{sub x}, hereinafter CAP) emission factors for various types of power plants burning various fuels with different technologies are important upstream parameters for estimating life-cycle emissions associated with alternative vehicle/fuel systems in the transportation sector, especially electric vehicles. The emission factors are typically expressed in grams of GHG or CAP per kWh of electricity generated by a specific power generation technology. This document describes our approach for updating and expanding GHG and CAP emission factors in the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model developed at Argonne National Laboratory (see Wang 1999 and the GREET website at http://greet.es.anl.gov/main) for various power generation technologies. These GHG and CAP emissions are used to estimate the impact of electricity use by stationary and transportation applications on their fuel-cycle emissions. The electricity generation mixes and the fuel shares attributable to various combustion technologies at the national, regional and state levels are also updated in this document. The energy conversion efficiencies of electric generating units (EGUs) by fuel type and combustion technology are calculated on the basis of the lower heating values of each fuel, to be consistent with the basis used in GREET for transportation fuels. On the basis of the updated GHG and CAP emission factors and energy efficiencies of EGUs, the probability distribution functions (PDFs), which are functions that describe the relative likelihood for the emission factors and energy efficiencies as random variables to take on a given value by the integral of their own probability distributions, are updated using best-fit statistical curves to characterize the uncertainties associated with GHG and CAP emissions in life-cycle modeling with GREET.

  18. Regulation XVI: GENERAL UNIVERSITY REGULATIONS

    E-Print Network [OSTI]

    Regulation XVI: GENERAL UNIVERSITY REGULATIONS APPLICATION AND INTERPRETATION 1. Unless stated otherwise, these and the following Regulations apply to students in all Faculties, including the International Faculty: General Regulations for First Degrees; General Regulations for Higher Degrees

  19. Optimal Production Policy under the Carbon Emission Market

    E-Print Network [OSTI]

    Touzi, Nizar

    with the reduction of the green- house gases including CO2 and is accepted by several countries e.g. Euro- pean Union Scheme (EU ETS) which provides a way to control the emission of CO2 within carbon polluters throughOptimal Production Policy under the Carbon Emission Market Redouane Belaouar Arash Fahim Nizar

  20. Emissions of air pollutants and greenhouse gases over1 Asian regions during 20002008: Regional Emission2

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    -3-9 Toranomon, Minato-ku, Tokyo, 105-0001, Japan}12 [5]{Ocean Policy Research Foundation, 3-4-10 Toranomon Singapore SGP Thailand THA Vietnam VNM Bangladesh OSA BGD Bhutan BTN India/Andhra Pradesh IND ANPR India/Bihar, Jharkhand BIHA India/Assam, Manipur, Meghalaya, Mizoram, Nagaland, Sikkim, Tripura EHIM India/Gujarat GUJA

  1. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOE Patents [OSTI]

    Turick, Charles E. (Idaho Falls, ID)

    1997-01-01T23:59:59.000Z

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases.

  2. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOE Patents [OSTI]

    Turick, C.E.

    1997-06-10T23:59:59.000Z

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases. 3 figs.

  3. Remote Sensing of Mobile Source Air Pollutant Emissions: Variability and Uncertainty in On-Road Emissions

    E-Print Network [OSTI]

    Frey, H. Christopher

    Remote Sensing of Mobile Source Air Pollutant Emissions: Variability and Uncertainty in On.0 INTRODUCTION 1 1.1 Mobile Source Emissions 2 1.2 Emission Regulations 2 1.3 Emissions Contributions of "Non Estimates 70 6.3 Fuel Economy Data for School Buses Observed at the Rock Quarry Road Site 75 6.4 Diesel

  4. The safe use of low temperature liquefied gases 1. Introduction

    E-Print Network [OSTI]

    Martin, Ralph R.

    dioxide TABLE 1 Property Oxygen (O2) Nitrogen (N2) Argon (Ar) Helium (He) Carbon dioxide (CO2) Molecular.1 Objective 1.2 Gases considered and typical uses 2. Properties of low temperature liquefied atmospheric gases of BOC low temperature liquefied gases information on their properties, the hazards associated

  5. Greenhouse gases in the corn-to-fuel ethanol pathway.

    SciTech Connect (OSTI)

    Wang, M. Q.

    1998-06-18T23:59:59.000Z

    Argonne National Laboratory (ANL) has applied its Greenhouse gas, Regulated Emissions and Energy in Transportation (GREET) full-fuel-cycle analysis model to examine greenhouse gas (GHG) emissions of corn-feedstock ethanol, given present and near-future production technology and practice. On the basis of updated information appropriate to corn farming and processing operations in the four principal corn- and ethanol-producing states (Illinois, Iowa, Minnesota, and Nebraska), the model was used to estimate energy requirements and GHG emissions of corn farming; the manufacture, transportation to farms, and field application of fertilizer and pesticide; transportation of harvested corn to ethanol plants; nitrous oxide emissions from cultivated cornfields; ethanol production in current average and future technology wet and dry mills; and operation of cars and light trucks using ethanol fuels. For all cases examined on the basis of mass emissions per travel mile, the corn-to-ethanol fuel cycle for Midwest-produced ethanol used in both E85 and E10 blends with gasoline outperforms conventional (current) and reformulated (future) gasoline with respect to energy use and GHG production. Also, GHG reductions (but not energy use) appear surprisingly sensitive to the value chosen for combined soil and leached N-fertilizer conversion to nitrous oxide. Co-product energy-use attribution remains the single key factor in estimating ethanol's relative benefits because this value can range from 0 to 50%, depending on the attribution method chosen.

  6. Survey and assessment of the effects of nonconventional gases on gas distribution equipment

    SciTech Connect (OSTI)

    Jasionowski, W.J.; Scott, M.I.; Gracey, W.C.

    1982-10-01T23:59:59.000Z

    A literature search and a survey of the gas industry were conducted to assess potential problems in the distribution of nonconventional gases. Available literature did not uncover data that would describe potential problems or substantiate the presence of harmful trace elements in final gas compositions produced from various SNG processes. Information from the survey indicates that some companies have encountered problems with nonconventional gases and extraneous additives such as landfill gas, refinery off-gases, oil gas, carbureted water gas, coke-oven gas, propane-air, and compressor lubricant oils. These nonconventional gases and compressor oils may 1) cause pipeline corrosion, 2) degrade some elastomeric materials and greases and affect the integrity of seals, gaskets, O-rings, and meter and regulator diaphragms, and 3) cause operational and safety problems. The survey indicated that 62% of the responding companies plan to use supplemental gas, with most planning on more than one type. Distribution companies intend to significantly increase their use of polyethylene piping from 11.6% in 1980 to 22.4% in 2000 for gas mains and from 33.4% to 50.3% in 2000 for gas service lines.

  7. Radiative precursors driven by converging blast waves in noble gases

    SciTech Connect (OSTI)

    Burdiak, G. C.; Lebedev, S. V.; Harvey-Thompson, A. J.; Swadling, G. F.; Suzuki-Vidal, F.; Hall, G. N.; Khoory, E.; Pickworth, L.; Bland, S. N.; Grouchy, P. de; Skidmore, J.; Suttle, L.; Bennett, M.; Niasse, N. P. L. [Blackett Laboratory, Imperial College London SW7 2BW (United Kingdom)] [Blackett Laboratory, Imperial College London SW7 2BW (United Kingdom); Williams, R. J. R. [Atomic Weapons Establishment, Aldermaston RG7 4PR (United Kingdom)] [Atomic Weapons Establishment, Aldermaston RG7 4PR (United Kingdom); Blesener, K.; Atoyan, L.; Cahill, A.; Hoyt, C.; Potter, W. [Laboratory of Plasma Studies, Cornell University, Ithaca, New York 14853 (United States)] [Laboratory of Plasma Studies, Cornell University, Ithaca, New York 14853 (United States); and others

    2014-03-15T23:59:59.000Z

    A detailed study of the radiative precursor that develops ahead of converging blast waves in gas-filled cylindrical liner z-pinch experiments is presented. The experiment is capable of magnetically driving 20?km s{sup ?1} blast waves through gases of densities of the order 10{sup ?5} g cm{sup ?3} (see Burdiak et al. [High Energy Density Phys. 9(1), 52–62 (2013)] for a thorough description). Data were collected for Ne, Ar, and Xe gas-fills. The geometry of the setup allows a determination of the plasma parameters both in the precursor and across the shock, along a nominally uniform line of sight that is perpendicular to the propagation of the shock waves. Radiation from the shock was able to excite NeI, ArII, and XeII/XeIII precursor spectral features. It is shown that the combination of interferometry and optical spectroscopy data is inconsistent with upstream plasmas being in LTE. Specifically, electron density gradients do not correspond to any apparent temperature change in the emission spectra. Experimental data are compared to 1D radiation hydrodynamics HELIOS-CR simulations and to PrismSPECT atomic physics calculations to assist in a physical interpretation of the observations. We show that upstream plasma is likely in the process of being radiatively heated and that the emission from a small percentage of ionised atoms within a cool background plasma dominates the emission spectra. Experiments were carried out on the MAGPIE and COBRA pulsed-power facilities at Imperial College London and Cornell University, respectively.

  8. New fluorescence techniques for detecting noble gases

    SciTech Connect (OSTI)

    Whitaker, T.J.; Cannon, B.D.; Bushaw, B.A.

    1986-10-01T23:59:59.000Z

    Two new concepts for detecting noble gases are reported. Both techniques involve formation of the long-lived 1s/sup 5/ metastable state of noble gases. The first technique utilizes the photon-burst method and should be capable of isotopically selective detection at extremely small relative abundances. The second concept incorporates a shelving technique that stores noble gas atoms in the metastable state and then pumps these atoms to a higher excited state that radiatively cascades to the ground state, emitting vacuum ultraviolet (vuv) photons. A significant advantage is that AlGaAs diode lasers can be used for the techniques rather than continuous wave cw dye lasers. 5 refs., 1 fig.

  9. Glass Membrane For Controlled Diffusion Of Gases

    DOE Patents [OSTI]

    Shelby, James E. (Alfred Station, NY); Kenyon, Brian E. (Pittsburgh, PA)

    2001-05-15T23:59:59.000Z

    A glass structure for controlled permeability of gases includes a glass vessel. The glass vessel has walls and a hollow center for receiving a gas. The glass vessel contains a metal oxide dopant formed with at least one metal selected from the group consisting of transition metals and rare earth metals for controlling diffusion of the gas through the walls of the glass vessel. The vessel releases the gas through its walls upon exposure to a radiation source.

  10. Scanning electron microscopy of cold gases

    E-Print Network [OSTI]

    Santra, Bodhaditya

    2015-01-01T23:59:59.000Z

    Ultracold quantum gases offer unique possibilities to study interacting many-body quantum systems. Probing and manipulating such systems with ever increasing degree of control requires novel experimental techniques. Scanning electron microscopy is a high resolution technique which can be used for in situ imaging, single site addressing in optical lattices and precision density engineering. Here, we review recent advances and achievements obtained with this technique and discuss future perspectives.

  11. Method for introduction of gases into microspheres

    DOE Patents [OSTI]

    Hendricks, Charles D. (Livermore, CA); Koo, Jackson C. (San Ramon, CA); Rosencwaig, Allan (Danville, CA)

    1981-01-01T23:59:59.000Z

    A method for producing small hollow glass spheres filled with a gas by introduction of the gas during formation of the hollow glass spheres. Hollow glass microspheres having a diameter up to about 500.mu. with both thin walls (0.5 to 4.mu.) and thick walls (5 to 20.mu.) that contain various fill gases, such as Ar, Kr, Xe, Br, DT, H.sub.2, D.sub.2, He, N.sub.2, Ne, CO.sub.2, etc. in the interior thereof, can be produced by the diffusion of the fill gas or gases into the microsphere during the formation thereof from a liquid droplet of glass-forming solution. This is accomplished by filling at least a portion of the multiple-zone drop-furnace used in producing hollow microspheres with the gas or gases of interest, and then taking advantage of the high rate of gaseous diffusion of the fill gas through the wall of the gel membrane before it transforms into a glass microsphere as it is processed in the multiple-zone furnace. Almost any gas can be introduced into the inner cavity of a glass microsphere by this method during the formation of the microsphere provided that the gas is diffused into the gel membrane or microsphere prior to its transformation into glass. The process of this invention provides a significant savings of time and related expense of filling glass microspheres with various gases. For example, the time for filling a glass microballoon with 1 atmosphere of DT is reduced from about two hours to a few seconds.

  12. Seeded optical breakdown of molecular and noble gases

    SciTech Connect (OSTI)

    Polynkin, Pavel; Scheller, Maik; Moloney, Jerome V. [College of Optical Sciences, University of Arizona 1630 E. University Blvd., Tucson, Arizona 85721 (United States)

    2012-07-30T23:59:59.000Z

    We report experimental results on the dual laser-pulse plasma excitation in various gases at atmospheric pressure. Dilute plasma channels generated through filamentation of ultraintense femtosecond laser pulses in air, argon, and helium are densified through the application of multi-Joule nanosecond heater pulses. Optical breakdown in atomic gases can be achieved for considerably longer delays between femtosecond and nanosecond pulses compared to that in molecular gases. The densification of the seed channel in molecular gases is always accompanied by its fragmentation into discrete bubbles, while in atomic gases the densified channel remains smooth and continuous.

  13. The EU’s Emissions Trading Scheme: A Proto-Type Global System?

    E-Print Network [OSTI]

    Ellerman, A. Denny

    2008-01-01T23:59:59.000Z

    The European Union's Emission Trading Scheme (EU ETS) is the world's first multinational cap-and-trade system for greenhouse gases. As an agreement between sovereign nations with diverse historical, institutional, and ...

  14. The EU’s Emissions Trading Scheme: A Prototype Global System?

    E-Print Network [OSTI]

    Ellerman, A. Denny

    The European Union's Emission Trading Scheme (EU ETS) is the world's first multinational cap-and-trade system for greenhouse gases. As an agreement between sovereign nations with diverse historical, institutional, and ...

  15. Estimating the benefits of greenhouse gas emission reduction from agricultural policy reform

    SciTech Connect (OSTI)

    Adger, W.N. (Univ. of East Anglia, Norwich (United Kingdom). Centre for Social and Economic Research on the Global Environment); Moran, D.C. (Univ. College, London (United Kingdom). Centre for Social and Economic Research on the Global Environment)

    1993-09-01T23:59:59.000Z

    Land use and agricultural activities contribute directly to the increased concentrations of atmospheric greenhouse gases. Economic support in industrialized countries generally increases agriculture's contribution to global greenhouse gas concentrations through fluxes associated with land use change and other sources. Changes in economic support offers opportunities to reduce net emissions, through this so far has gone unaccounted. Estimates are presented here of emissions of methane from livestock in the UK and show that, in monetary terms, when compared to the costs of reducing support, greenhouse gases are a significant factor. As signatory parties to the Climate Change Convection are required to stabilize emissions of all greenhouse gases, options for reduction of emissions of methane and other trace gases from the agricultural sector should form part of these strategies.

  16. Abatement of Air Pollution: Control of Particulate Matter and Visible Emissions (Connecticut)

    Broader source: Energy.gov [DOE]

    These regulations set emissions opacity standards for stationary sources with opacity continuous emissions monitoring equipment, stationary sources without such equipment, and mobile sources. The...

  17. Air Pollution Control Regulations: No. 41- Nox Budget Trading Program (Rhode Island)

    Broader source: Energy.gov [DOE]

    These regulations establish a budget trading program for nitrogen oxide emissions, setting NOx budget units for generators and an NOx Allowance Tracking System to account for emissions. These...

  18. Toward Verifying Fossil Fuel CO2 Emissions with the CMAQ Model: Motivation, Model Description and Initial Simulation

    SciTech Connect (OSTI)

    Liu, Zhen; Bambha, Ray P.; Pinto, Joseph P.; Zeng, Tao; Boylan, Jim; Huang, Maoyi; Lei, Huimin; Zhao, Chun; Liu, Shishi; Mao, Jiafu; Schwalm, Christopher R.; Shi, Xiaoying; Wei, Yaxing; Michelsen, Hope A.

    2014-03-14T23:59:59.000Z

    Motivated by the urgent need for emission verification of CO2 and other greenhouse gases, we have developed regional CO2 simulation with CMAQ over the contiguous U.S. Model sensitivity experiments have been performed using three different sets of inputs for net ecosystem exchange (NEE) and two fossil fuel emission inventories, to understand the roles of fossil fuel emissions, atmosphere-biosphere exchange and transport in regulating the spatial and diurnal variability of CO2 near the surface, and to characterize the well-known ‘signal-to-noise’ problem, i.e. the interference from the biosphere on the interpretation of atmospheric CO2 observations. It is found that differences in the meteorological conditions for different urban areas strongly contribute to the contrast in concentrations. The uncertainty of NEE, as measured by the difference among the three different NEE inputs, has notable impact on regional distribution of CO2 simulated by CMAQ. Larger NEE uncertainty and impact are found over eastern U.S. urban areas than along the western coast. A comparison with tower CO2 measurements at Boulder Atmospheric Observatory (BAO) shows that the CMAQ model using hourly varied and high-resolution CO2 emission from the Vulcan inventory and CarbonTracker optimized NEE reasonably reproduce the observed diurnal profile, whereas switching to different NEE inputs significantly degrades the model performance. Spatial distribution of CO2 is found to correlate with NOx, SO2 and CO, due to their similarity in emission sources and transport processes. These initial results from CMAQ demonstrate the power of a state-of-the art CTM in helping interpret CO2 observations and verify fossil fuel emissions. The ability to simulate CO2 in CMAQ will also facilitate investigations of the utility of traditionally regulated pollutants and other species as tracers to CO2 source attribution.

  19. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)IntegratedSpeedingTechnicalPurchase, Delivery, and Storage of Gases Print ALS users

  20. The Marginal Damage Costs of Different Greenhouse Gases: An Application of FUND

    SciTech Connect (OSTI)

    Waldhoff, Stephanie T.; Anthoff, David; Rose, Steven K.; Tol, Richard

    2014-10-01T23:59:59.000Z

    We use FUND 3.8 to estimate the social cost of four greenhouse gases: carbon dioxide, methane, nitrous oxide, and sulphur hexafluoride emissions. The damage potential for each gas—the ratio of the social cost of the non-carbon dioxide greenhouse gas to the social cost of carbon dioxide—is also estimated. The damage potentials are compared to several metrics, focusing in particular on the global warming potentials, which are frequently used to measure the trade-off between gases in the form of carbon dioxide equivalents. We find that damage potentials could be significantly higher than global warming potentials. This finding implies that previous papers have underestimated the relative importance of reducing non-carbon dioxide greenhouse gas emissions from an economic damage perspective. We show results for a range of sensitivity analyses: carbon dioxide fertilization on agriculture productivity, terrestrial feedbacks, climate sensitivity, discounting, equity weighting, and socioeconomic and emissions scenarios. The sensitivity of the results to carbon dioxide fertilization is a primary focus as it is an important element of climate change that has not been considered in much of the previous literature. We estimate that carbon dioxide fertilization has a large positive impact that reduces the social cost of carbon dioxide with a much smaller effect on the other greenhouse gases. As a result, our estimates of the damage potentials of methane and nitrous oxide are much higher compared to estimates that ignore carbon dioxide fertilization. As a result, our base estimates of the damage potential for methane and nitrous oxide that include carbon dioxide fertilization are twice their respective global warming potentials. Our base estimate of the damage potential of sulphur hexafluoride is similar to the one previous estimate, both almost three times the global warming potential.

  1. Annual Survey of Biological and Chemical Agents regulated by Homeland Security

    E-Print Network [OSTI]

    Portman, Douglas

    is different than dinitrobenze, which is not regulated) Nitrogen mustard hydrochloride [Bis(2-chloroethyl)methylamine hydrochloride] Nitrogen trioxide Phosphorus oxychloride Phosphorus trichloride Propylphosphonothioic dichloride Thiodiglycol [Bis(2- hydroxyethyl)sulfide] Titanium tetrachloride Triethyl phosphite Trimethyl phosphite Gases

  2. Emissions of polychlorinated dibenzo-p-dioxins and dibenzofurans from various industrial sources

    SciTech Connect (OSTI)

    Long-Full Lin; Wen-Jhy Lee; Guo-Ping Chang-Chien [National Cheng Kung University, Tainan (Taiwan). Department of Environmental Engineering, and Sustainable Environment Research Center

    2006-12-15T23:59:59.000Z

    This study characterized the emissions of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) from the stack flue gases of 17 industrial sources, which were classified into 10 categories. The results show that the mean PCDD/PCDF concentration of secondary zinc smelter (Zn-S) and secondary copper smelter (Cu-S) is 2.44 ng international toxic equivalent (I-TEQ)/Nm{sup 3} (N represents normal conditions at 0{sup o}C, 760 mmHg), which was found to be significantly greater than that of industrial waste incinerators (mean concentration = 0.15 ng I-TEQ/Nm{sup 3}). These results imply that the controlling of secondary metallurgical melting processes is more important than industrial waste incineration for the reduction of PCDD/PCDF emissions. The mean emission factors of cement production, Zn-S and Cu-S, are 0.052, 1.99, and 1.73 {mu}g I-TEQ/t product, respectively. The cement plant uses bituminous coal as fuel. For industrial waste incineration, the mean emission factors of waste rubber, waste liquor, waste sludge, industrial waste solid (IWI)-1, IWI-2, IWI-3, and IWI-4 are 0.752, 0.435, 0.760, 6.64, 1.67, 2.38, and 0.094 {mu}g I-TEQ/t feed, respectively. Most of the PCDD/PCDF emission factors established in this study are less than those reported in previous studies, which could be because of the more stringent regulations for PCDD/PCDF emissions in recent years. 20 refs., 1 fig., 7 tabs.

  3. Method for controlling corrosion in thermal vapor injection gases

    DOE Patents [OSTI]

    Sperry, John S. (Houston, TX); Krajicek, Richard W. (Houston, TX)

    1981-01-01T23:59:59.000Z

    An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

  4. Theory of ultracold atomic Fermi gases

    SciTech Connect (OSTI)

    Giorgini, Stefano; Pitaevskii, Lev P.; Stringari, Sandro [Dipartimento di Fisica, Universita di Trento and CNR-INFM BEC Center, I-38050 Povo, Trento (Italy); Dipartimento di Fisica, Universita di Trento and CNR-INFM BEC Center, I-38050 Povo, Trento, Italy and Kapitza Institute for Physical Problems, ul. Kosygina 2, 117334 Moscow (Russian Federation); Dipartimento di Fisica, Universita di Trento and CNR-INFM BEC Center, I-38050 Povo, Trento (Italy)

    2008-10-15T23:59:59.000Z

    The physics of quantum degenerate atomic Fermi gases in uniform as well as in harmonically trapped configurations is reviewed from a theoretical perspective. Emphasis is given to the effect of interactions that play a crucial role, bringing the gas into a superfluid phase at low temperature. In these dilute systems, interactions are characterized by a single parameter, the s-wave scattering length, whose value can be tuned using an external magnetic field near a broad Feshbach resonance. The BCS limit of ordinary Fermi superfluidity, the Bose-Einstein condensation (BEC) of dimers, and the unitary limit of large scattering length are important regimes exhibited by interacting Fermi gases. In particular, the BEC and the unitary regimes are characterized by a high value of the superfluid critical temperature, on the order of the Fermi temperature. Different physical properties are discussed, including the density profiles and the energy of the ground-state configurations, the momentum distribution, the fraction of condensed pairs, collective oscillations and pair-breaking effects, the expansion of the gas, the main thermodynamic properties, the behavior in the presence of optical lattices, and the signatures of superfluidity, such as the existence of quantized vortices, the quenching of the moment of inertia, and the consequences of spin polarization. Various theoretical approaches are considered, ranging from the mean-field description of the BCS-BEC crossover to nonperturbative methods based on quantum Monte Carlo techniques. A major goal of the review is to compare theoretical predictions with available experimental results.

  5. Treatment of PDMS surfaces using pulsed DBD plasmas: comparing the use of different gases and its influence on adhesion

    E-Print Network [OSTI]

    Nascimento, Fellype do; Machida, Munemasa; Parada, Sergio

    2015-01-01T23:59:59.000Z

    In this work we present some results of the treatment of polydimethylsiloxane (PDMS) surfaces using pulsed dielectric barrier discharge plasmas. The results of plasma treatment using different gases to produce the plasmas (argon, argon plus water, helium, helium plus water, nitrogen and nitrogen plus water) were compared testing the adhesion between two PDMS samples for each kind of plasma. We also studied the water contact angle in function of plasma process time of PDMS surfaces with each kind of plasma. The plasmas were characterized by optical emission spectroscopy to identify the emitting species and determine plasma temperatures through comparison with emission spectra simulations. Measurements of power delivered to the plasmas were also performed. Plasmas of all gases are good enough for surface treatment with long exposure time. But when only a few discharges are applied the best choice is the helium plasma.

  6. New Materials for Capturing Carbon Dioxide from Combustion Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to APS Science Highlights rss feed New Materials for Capturing Carbon Dioxide from Combustion Gases April 9, 2014 Bookmark and Share The SIFSIX materials in order of increasing...

  7. adjacente dos gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nature Le Roy, Robert J. 437 Classical disordered ground states: Super-ideal gases and stealth and equi-luminous materials Chemistry Websites Summary: Classical disordered...

  8. Finalize Historic National Program to Reduce Greenhouse Gases...

    Open Energy Info (EERE)

    Finalize Historic National Program to Reduce Greenhouse Gases and Improve Fuel Economy for Cars and Trucks Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Finalize...

  9. Mitigating greenhouse gas emissions: Voluntary reporting

    SciTech Connect (OSTI)

    NONE

    1997-10-01T23:59:59.000Z

    The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report on their emissions of greenhouse gases, and on actions taken that have reduced or avoided emissions or sequestered carbon, to the Energy Information Administration (EIA). This, the second annual report of the Voluntary Reporting Program, describes information provided by the participating organizations on their aggregate emissions and emissions reductions, as well as their emissions reduction or avoidance projects, through 1995. This information has been compiled into a database that includes reports from 142 organizations and descriptions of 967 projects that either reduced greenhouse gas emissions or sequestered carbon. Fifty-one reporters also provided estimates of emissions, and emissions reductions achieved, for their entire organizations. The projects described actions taken to reduce emissions of carbon dioxide from energy production and use; to reduce methane and nitrous oxide emissions from energy use, waste management, and agricultural processes; to reduce emissions of halocarbons, such as CFCs and their replacements; and to increase carbon sequestration.

  10. Modeling non-CO? greenhouse gases

    E-Print Network [OSTI]

    Hyman, Robert C.

    Although emissions of CO? are the largest anthropogenic contributor to the risks of climate change, other substances are important in the formulation of a cost-effective response. To provide improved facilities for addressing ...

  11. Fuel Flexible, Low Emission Catalytic Combustor for Opportunity Fuel Applications

    SciTech Connect (OSTI)

    Eteman, Shahrokh

    2013-06-30T23:59:59.000Z

    Limited fuel resources, increasing energy demand and stringent emission regulations are drivers to evaluate process off-gases or process waste streams as fuels for power generation. Often these process waste streams have low energy content and/or highly reactive components. Operability of low energy content fuels in gas turbines leads to issues such as unstable and incomplete combustion. On the other hand, fuels containing higher-order hydrocarbons lead to flashback and auto-ignition issues. Due to above reasons, these fuels cannot be used directly without modifications or efficiency penalties in gas turbine engines. To enable the use of these wide variety of fuels in gas turbine engines a rich catalytic lean burn (RCL®) combustion system was developed and tested in a subscale high pressure (10 atm.) rig. The RCL® injector provided stability and extended turndown to low Btu fuels due to catalytic pre-reaction. Previous work has shown promise with fuels such as blast furnace gas (BFG) with LHV of 85 Btu/ft3 successfully combusted. This program extends on this work by further modifying the combustor to achieve greater catalytic stability enhancement. Fuels containing low energy content such as weak natural gas with a Lower Heating Value (LHV) of 6.5 MJ/m3 (180 Btu/ft3 to natural gas fuels containing higher hydrocarbon (e.g ethane) with LHV of 37.6 MJ/m3 (1010 Btu/ft3) were demonstrated with improved combustion stability; an extended turndown (defined as the difference between catalytic and non-catalytic lean blow out) of greater than 250oF was achieved with CO and NOx emissions lower than 5 ppm corrected to 15% O2. In addition, for highly reactive fuels the catalytic region preferentially pre-reacted the higher order hydrocarbons with no events of flashback or auto-ignition allowing a stable and safe operation with low NOx and CO emissions.

  12. Executive Summary An emissions inventory that identifies and quantifies a country's primary anthropogenic1 sources and sinks of

    E-Print Network [OSTI]

    Little, John B.

    Executive Summary An emissions inventory that identifies and quantifies a country's primary emission sources and greenhouse gases to climate change. In 1992, the United States signed and ratified and make available...national inventories of anthropogenic emissions by sources and removals by sinks

  13. Understanding the catalytic conversion of automobile exhaust emissions using model catalysts: CO+NO reaction on Pd(111)

    E-Print Network [OSTI]

    Goodman, Wayne

    Understanding the catalytic conversion of automobile exhaust emissions using model catalysts: CO and the quantity of the exhaust gases originating from mobile sources such as automobile emissions by the automobile industry for emission control purposes due to its technical and economical advantages [2

  14. Finite Temperature Gases of Fermionic Strings

    E-Print Network [OSTI]

    Shyamoli Chaudhuri

    2005-09-12T23:59:59.000Z

    We show that in the absence of a Ramond-Ramond sector both the type IIA and type IIB free string gases have a thermal instability due to low temperature tachyon modes. The gas of free IIA strings undergoes a thermal duality transition into a gas of free IIB strings at the self-dual temperature. The free heterotic string gas is a tachyon-free ensemble with gauge symmetry SO(16)$\\times$SO(16) in the presence of a timelike Wilson line background. It exhibits a holographic duality relation undergoing a self-dual phase transition with positive free energy and positive specific heat. The type IB open and closed string ensemble is related by thermal duality to the type I' string ensemble. We identify the order parameter for the Kosterlitz-Thouless phase transition from a low temperature gas of short open strings to a high temperature long string phase at or below T_C. Note Added (Sep 2005).

  15. A Fuel-Based Inventory for Heavy-Duty Diesel Truck Emissions

    E-Print Network [OSTI]

    Dreher, David B.; Harley, Robert A.

    1998-01-01T23:59:59.000Z

    for Heavy-Duty Diesel Truck Emissions David B. Dreher andheavy-duty diesel truck emissions is described. In thisheavy-duty diesel truck emissions are regulated per unit of

  16. The next restructuring: Environmental regulation

    SciTech Connect (OSTI)

    Ellerman, A.D. (Massachusetts Inst. of Tech., Cambridge, MA (United States). Center for Energy and Environmental Policy Research)

    1999-01-01T23:59:59.000Z

    From oil, to natural gas, and now electricity, the regulation of energy markets has been successively restructured to allow greater scope to market forces. The likely next domain for restructuring, environmental regulation, may seem far-fetched now, but it is no more so than the restructuring of electric utility regulation would have seemed to be twenty years ago. The grand experiment with emissions trading under the US acid rain program has set a propitious example by showing that markets in environmental goods can be constructed and that the explicit recognition of property rights in the use of the environment is compatible with effective and non-intrusive environmental regulation.

  17. Continuous cryopump with a method for removal of solidified gases

    DOE Patents [OSTI]

    Carlson, L.W.; Herman, H.

    1988-05-05T23:59:59.000Z

    An improved cryopump for the removal of gases from a high vacuum, comprising a cryopanel incorporating honeycomb structure, refrigerant means thermally connected to the cryopanel, and a rotatable channel moving azimuthally around an axis located near the center of the cryopanel, removing gases adsorbed within the honeycomb structure by subliming them and conducting them outside the vacuum vessel. 4 figs.

  18. AMIII Termodinamica dos Gases Ideais 17 de Janeiro de 2002

    E-Print Network [OSTI]

    Natário, José

    AMIII ­ Termodinâ??amica dos Gases Ideais 17 de Janeiro de 2002 N moles de um gâ??as ideal em equil dos gases ideais). A Primeira Lei da Termodinâ??amica afirma que existe uma funâ?şcâ?ťao E : M # R, dita pela Segunda Lei da Termodinâ??amica. 2 #12;

  19. Biological Removal of Siloxanes from Landfill and Digester Gases

    E-Print Network [OSTI]

    Biological Removal of Siloxanes from Landfill and Digester Gases: Opportunities and Challenges S U) presents challenges for using landfill and digester gases as energy fuels because of the formation volatilize from waste at landfills and wastewater treatment plants (1). As a result, biogas produced

  20. Measurement of transient nonlinear refractive index in gases using xenon

    E-Print Network [OSTI]

    Milchberg, Howard

    Measurement of transient nonlinear refractive index in gases using xenon supercontinuum single measurement of ultrafast high field processes using modest energy lasers, with pump and probe pulses totaling) and instrument resolution. The ultrafast nonlinear Kerr effect in glass, and in Ar, N2, and N2O gases is measured

  1. Trace gas and particle emissions from domestic and industrial biofuel use and garbage burning in central Mexico

    E-Print Network [OSTI]

    Christian, T. J.

    In central Mexico during the spring of 2007 we measured the initial emissions of 12 gases and the aerosol speciation for elemental and organic carbon (EC, OC), anhydrosugars, Cl?, NO[subscript 3]?, and 20 metals from 10 ...

  2. Air Emission Inventory for the Idaho National Engineering Laboratory, 1993 emissions report

    SciTech Connect (OSTI)

    Not Available

    1994-06-01T23:59:59.000Z

    This report presents the 1993 update of the Air Emission Inventory for the Idaho National Engineering Laboratory (INEL). The purpose of the Air Emission Inventory is to commence the preparation of the permit to operate application for the INEL, as required by the recently promulgated Title V regulations of the Clean Air Act. The report describes the emission inventory process and all of the sources at the INEL and provides emissions estimates for both mobile and stationary sources.

  3. The Sweet Taste of Defeat: American Electric Power Co v. Connecticut and Federal Greenhouse Gas Regulation

    E-Print Network [OSTI]

    Trisolini, Katherine A.

    2012-01-01T23:59:59.000Z

    as held in Massachusetts v. EPA, EPA's regulation of GHGsstood Massachusetts v. EPA, and that its GHG regulationsMassachusetts made plain that emissions of carbon dioxide qualify as air pollution subject to regulation

  4. Site-selected luminescence of atomic europium in the solid rare gases

    SciTech Connect (OSTI)

    Byrne, Owen; McCaffrey, John G. [Department of Chemistry, National University of Ireland - Maynooth, Maynooth, County Kildare (Ireland)

    2011-07-14T23:59:59.000Z

    Site-selective excitation has been used to simplify complex emission recorded in the visible spectral region for atomic europium isolated in the solid rare gases. In addition to y{sup 8}P resonance fluorescence, excitation of the y{sup 8}P state produces emission from the z{sup 6}P state and the metastable a{sup 10}D state. Very weak emission at 690 nm is tentatively assigned to the J = 9/2 level of the z{sup 10}P state. Eu atoms isolated in the red and blue sites exhibit very different temperature dependence both spectrally and temporally. For the y{sup 8}P state emission the red site atoms exhibit small Stokes shifts and yield radiative lifetimes while the emission from the blue site loses intensity and the temporal profiles shorten dramatically between 10 and 16 K indicating very efficient non-radiative relaxation in this site. An analysis of the Stokes shifts exhibited for the y{sup 8}P state in each site supports the attributions made in a previous publication [O. Byrne and J.G. McCaffrey, J. Chem. Phys. 134, 124501 (2011)] that the smaller blue tetravacancy site has a greater repulsive interaction with the guest. With the exception of the y{sup 8}P state resonance fluorescence, the recorded decay profiles of all the other emissions exhibit multiple components. This behaviour has been attributed to the existence of multiple crystal field levels arising from the splitting of the distinct spin-orbit levels from which emission occurs.

  5. Measuring non-condensable gases in steam

    SciTech Connect (OSTI)

    Doornmalen, J. P. C. M. van; Kopinga, K., E-mail: k.kopinga@tue.nl [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)

    2013-11-15T23:59:59.000Z

    In surgery, medical devices that are used should be sterilized. To obtain surface steam sterilization conditions, not only in the sterilizer chamber itself but also in the loads to be sterilized, the amount of non-condensable gases (NCGs), for instance air, should be very low. Even rather small fractions of NCGs (below 1 %) seriously hamper steam penetration in porous materials or devices with hollow channels (e.g., endoscopes). A recently developed instrument which might detect the presence of residual NCGs in a reliable and reproducible way is the 3M{sup TM} Electronic Test System (ETS). In this paper, a physical model is presented that describes the behavior of this instrument. This model has been validated by experiments in which known fractions of NCGs were introduced in a sterilizer chamber in which an ETS was placed. Despite several approximations made in the model, a good agreement is found between the model predictions and the experimental results. The basic principle of the ETS, measuring the heat transfer by condensation on a cooled surface, permits a very sensitive detection of NCGs in harsh environments like water vapor at high temperatures and pressures. Our model may serve to develop adapted and optimized versions of this instrument for use outside the field of sterilization, e.g., in heat exchangers based on steam condensation.

  6. Development of Diesel Exhaust Aftertreatment System for Tier II Emissions

    SciTech Connect (OSTI)

    Yu, R. C.; Cole, A. S., Stroia, B. J.; Huang, S. C. (Cummins, Inc.); Howden, Kenneth C.; Chalk, Steven (U.S. Dept. of Energy)

    2002-06-01T23:59:59.000Z

    Due to their excellent fuel efficiency, reliability, and durability, compression ignition direct injection (CIDI) engines have been used extensively to power almost all highway trucks, urban buses, off-road vehicles, marine carriers, and industrial equipment. CIDI engines burn 35 to 50% less fuel than gasoline engines of comparable size, and they emit far less greenhouse gases (Carbon Dioxides), which have been implicated in global warming. Although the emissions of CIDI engines have been reduced significantly over the last decade, there remains concern with the Nitrogen Oxides (NOX) and Particulate Matter (PM) emission levels. In 2000, the US EPA proposed very stringent emissions standards to be introduced in 2007 along with low sulfur (< 15ppm) diesel fuel. The California Air Resource Board (CARB) has also established the principle that future diesel fueled vehicles should meet the same emissions standards as gasoline fueled vehicles and the EPA followed suit with its Tier II emissions regulations. Meeting the Tier II standards requires NOX and PM emissions to be reduced dramatically. Achieving such low emissions while minimizing fuel economy penalty cannot be done through engine development and fuel reformulation alone, and requires application of NOX and PM aftertreatment control devices. A joint effort was made between Cummins Inc. and the Department of Energy to develop the generic aftertreatment subsystem technologies applicable for Light-Duty Vehicle (LDV) and Light-Duty Truck (LDT) engines. This paper provides an update on the progress of this joint development program. Three NOX reduction technologies including plasmaassisted catalytic NOX reduction (PACR), active lean NOX catalyst (LNC), and adsorber catalyst (AC) technology using intermittent rich conditions for NOX reduction were investigated in parallel in an attempt to select the best NOX control approach for light-duty aftertreatment subsystem integration and development. Investigations included system design and analysis, critical lab/engine experiments, and ranking then selection of NOX control technologies against reliability, up-front cost, fuel economy, service interval/serviceability, and size/weight. The results of the investigations indicate that the best NOX control approach for LDV and LDT applications is a NOX adsorber system. A greater than 83% NOX reduction efficiency is required to achieve 0.07g/mile NOX Tier II vehicle-out emissions. Both active lean NOX and PACR technology are currently not capable of achieving the high conversion efficiency required for Tier II, Bin 5 emissions standards. In this paper, the NOX technology assessment and selection is first reviewed and discussed. Development of the selected NOX technology (NOX adsorber) and PM control are then discussed in more detail. Discussion includes exhaust sulfur management, further adsorber formulation development, reductant screening, diesel particulate filter development & active regeneration, and preliminary test results on the selected integrated SOX trap, NOX adsorber, and diesel particulate filter system over an FTP-75 emissions cycle, and its impact on fuel economy. Finally, the direction of future work for continued advanced aftertreatment technology development is discussed. (SAE Paper SAE-2002-01-1867 © 2002 SAE International. This paper is published on this website with permission from SAE International. As a user of this website, you are permitted to view this paper on-line, download this pdf file and print one copy of this paper at no cost for your use only. The downloaded pdf file and printout of this SAE paper may not be copied, distributed or forwarded to others or for the use of others.)

  7. Viscosities of natural gases at high pressures and high temperatures

    E-Print Network [OSTI]

    Viswanathan, Anup

    2007-09-17T23:59:59.000Z

    Estimation of viscosities of naturally occurring petroleum gases provides the information needed to accurately work out reservoir-engineering problems. Existing models for viscosity prediction are limited by data, especially at high pressures...

  8. Studying coherence in ultra-cold atomic gases

    E-Print Network [OSTI]

    Miller, Daniel E. (Daniel Edward)

    2007-01-01T23:59:59.000Z

    This thesis will discuss the study of coherence properties of ultra-cold atomic gases. The atomic systems investigated include a thermal cloud of atoms, a Bose-Einstein condensate and a fermion pair condensate. In each ...

  9. The Release of Trapped Gases from Amorphous Solid Water Films...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    I. Top-Down" Crystallization-Induced Crack Propagation Probed The Release of Trapped Gases from Amorphous Solid Water Films: I. Top-Down" Crystallization-Induced Crack Propagation...

  10. Low-Value Waste Gases as an Energy Source 

    E-Print Network [OSTI]

    Waibel, R. T.

    1996-01-01T23:59:59.000Z

    Waste gases with potentially useful fuel value are generated at any number of points in refineries, chemical plants and other industrial and commercial sites. The higher quality streams have been utilized successfully in fuel systems for years...

  11. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, C.R.; Ernstberger, E.G.

    1985-07-03T23:59:59.000Z

    A method for monitoring the stack gases of a purge cascade of gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases. 1 fig.

  12. Helium Isotopes in Geothermal and Volcanic Gases of the Western...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Helium Isotopes in Geothermal and Volcanic Gases of the Western United States, II. Long...

  13. Helium Isotopes In Geothermal And Volcanic Gases Of The Western...

    Open Energy Info (EERE)

    Helium Isotopes In Geothermal And Volcanic Gases Of The Western United States, I, Regional Variability And Magmatic Origin Jump to: navigation, search OpenEI Reference LibraryAdd...

  14. Geochemical Data on Waters, Gases, Scales, and Rocks from the...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999)...

  15. Low-Value Waste Gases as an Energy Source

    E-Print Network [OSTI]

    Waibel, R. T.

    Waste gases with potentially useful fuel value are generated at any number of points in refineries, chemical plants and other industrial and commercial sites. The higher quality streams have been utilized successfully in fuel systems for years...

  16. Radio-frequency spectroscopy of ultracold atomic Fermi gases

    E-Print Network [OSTI]

    Schirotzek, Andre

    2010-01-01T23:59:59.000Z

    This thesis presents experiments investigating the phase diagram of ultracold atomic Fermi gases using radio-frequency spectroscopy. The tunability of many experimental parameters including the temperature, the interparticle ...

  17. Method of producing pyrolysis gases from carbon-containing materials

    DOE Patents [OSTI]

    Mudge, Lyle K. (Richland, WA); Brown, Michael D. (West Richland, WA); Wilcox, Wayne A. (Kennewick, WA); Baker, Eddie G. (Richland, WA)

    1989-01-01T23:59:59.000Z

    A gasification process of improved efficiency is disclosed. A dual bed reactor system is used in which carbon-containing feedstock materials are first treated in a gasification reactor to form pyrolysis gases. The pyrolysis gases are then directed into a catalytic reactor for the destruction of residual tars/oils in the gases. Temperatures are maintained within the catalytic reactor at a level sufficient to crack the tars/oils in the gases, while avoiding thermal breakdown of the catalysts. In order to minimize problems associated with the deposition of carbon-containing materials on the catalysts during cracking, a gaseous oxidizing agent preferably consisting of air, oxygen, steam, and/or mixtures thereof is introduced into the catalytic reactor at a high flow rate in a direction perpendicular to the longitudinal axis of the reactor. This oxidizes any carbon deposits on the catalysts, which would normally cause catalyst deactivation.

  18. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, Claude R. (Paducah, KY); Ernstberger, Harold G. (Paducah, KY)

    1988-01-01T23:59:59.000Z

    A method for monitoring the stack gases of a purge cascade of a gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases.

  19. active trace gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OF GEOPHYSICAL RESEARCH, VOL. 94, NO. D13, PAGES 16,417-16,421,NOVEMBER 20, 1989 Greenhouse Effect of Chlorofluorocarbons and Other Trace Gases Environmental Sciences and Ecology...

  20. Process for the removal of acid forming gases from exhaust gases

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (San Pablo, CA)

    1992-01-01T23:59:59.000Z

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. are attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO and SO.sub.2 can be removed in an economic fashion.

  1. Process for the removal of acid forming gases from exhaust gases

    DOE Patents [OSTI]

    Chang, S.G.; Liu, D.K.

    1992-11-17T23:59:59.000Z

    Exhaust gases are treated to remove NO or NO[sub x] and SO[sub 2] by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50 C is attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO[sub x] and SO[sub 2], alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO[sub x] and SO[sub 2] can be removed in an economic fashion. 9 figs.

  2. Chapter 4 The Gaseous State Chemistry of Gases

    E-Print Network [OSTI]

    Ihee, Hyotcherl

    .15 V = V0[1+(t/273.15oC)] Kelvin T = 273.15 + t(Celsius) #12;Boyle's Law · The stirling engine, a heatChapter 4 The Gaseous State NO2 #12;AIR #12;Chemistry of Gases SO3 .. corrosive gas SO2...burning) ~1760 Charle The definition of the Temperature All gases expand with increasing temperature by the same

  3. Biological production of ethanol from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    2000-01-01T23:59:59.000Z

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products is disclosed. The method includes introducing the waste gases into a bioreactor where they are fermented to various product, such as organic acids, alcohols H.sub.2, SCP, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  4. Fiber optics spectrochemical emission sensors

    DOE Patents [OSTI]

    Griffin, J.W.; Olsen, K.B.

    1992-02-04T23:59:59.000Z

    A method is described of in situ monitoring of a body of a fluid stored in a tank or groundwater or vadose zone gases in a well for the presence of selected chemical species. The method uses a probe insertable into the well or tank via a cable and having an electrical apparatus for exciting selected chemical species in the body of fluid. The probe can have a pair of electrodes for initiating a spark or a plasma cell for maintaining a plasma to excite the selected chemical species. The probe also has an optical apparatus for receiving optical emissions emitted by the excited species and optically transmitting the emissions via the cable to an analysis location outside the well. The analysis includes detecting a selected wavelength in the emissions indicative of the presence of the selected chemical species. A plurality of probes can be suspended at an end of a respective cable, with the transmitting and analyzing steps for each probe being synchronized sequentially for one set of support equipment and instrumentation to monitor at multiple test points. The optical apparatus is arranged about the light guide axis so that the selected chemical species are excited in the fluid in alignment with the light guide axis. Optical emissions are received from the excited chemical species along such axis. 18 figs.

  5. Fiber optics spectrochemical emission sensors

    DOE Patents [OSTI]

    Griffin, Jeffrey W. (Kennewick, WA); Olsen, Khris B. (West Richland, WA)

    1992-01-01T23:59:59.000Z

    A method of in situ monitoring of a body of a fluid stored in a tank or groundwater or vadose zone gases in a well for the presence of selected chemical species uses a probe insertable into the well or tank via a cable and having electrical apparatus for exciting selected chemical species in the body of fluid. The probe can have a pair of electrodes for initiating a spark or a plasma cell for maintaining a plasma to excite the selected chemical species. The probe also has optical apparatus for receiving optical emissions emitted by the excited species and optically transmitting the emissions via the cable to an analysis location outside the well. The analysis includes detecting a selected wavelength in the emissions indicative of the presence of the selected chemical species. A plurality of probes can be suspended at an end of a respective cable, with the transmitting and analyzing steps for each probe being synchronized sequentially for one set of support equipment and instrumentation to monitor at multiple test points. The optical apparatus is arranged about the light guide axis so that the selected chemical species are excited the fluid in alignment with the light guide axis and optical emissions are received from the excited chemical species along such axis.

  6. Assessment of fuel-cycle energy use and greenhouse gas emissions for Fischer-Tropsch diesel from coal and cellulosic biomass.

    SciTech Connect (OSTI)

    Xie, X.; Wang, M.; Han, J. (Energy Systems)

    2011-04-01T23:59:59.000Z

    This study expands and uses the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model to assess the effects of carbon capture and storage (CCS) technology and cellulosic biomass and coal cofeeding in Fischer-Tropsch (FT) plants on energy use and greenhouse gas (GHG) emissions of FT diesel (FTD). To demonstrate the influence of the coproduct credit methods on FTD life-cycle analysis (LCA) results, two allocation methods based on the energy value and the market revenue of different products and a hybrid method are employed. With the energy-based allocation method, fossil energy use of FTD is less than that of petroleum diesel, and GHG emissions of FTD could be close to zero or even less than zero with CCS when forest residue accounts for 55% or more of the total dry mass input to FTD plants. Without CCS, GHG emissions are reduced to a level equivalent to that from petroleum diesel plants when forest residue accounts for 61% of the total dry mass input. Moreover, we show that coproduct method selection is crucial for LCA results of FTD when a large amount of coproducts is produced.

  7. Charge-exchange EUV spectroscopy in collisions of Xe{sup q+} (q=7-9) with rare gases

    SciTech Connect (OSTI)

    Tanuma, H.; Ohashi, H.; Yamamoto, N.; Kato, D.; Murakami, I.; Fujioka, S.; Nishimura, H.; Nishihara, K. [Department of Physics, Tokyo Metropolitan University, 1-1 Minami-Ohsawa, Hachioji, Tokyo 192-0397 (Japan); National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan); Institute of Laser Engineering, Osaka University, 2-6 Yamada-oka, Suita, Osaka 565-0871 (Japan)

    2011-10-15T23:59:59.000Z

    Extreme ultraviolet (EUV) emission spectra have been measured in charge exchange collisions between Xe{sup q+} (q=7--9) and rare gases at an energy of 20 q keV. We have observed 4, 22, and 39 lines in collisions of Xe{sup 7+}, Xe{sup 8+}, and Xe{sup 9+}. Of these emission lines, four lines of Xe vii, eight lines of Xe viii, and nine lines of Xe ix correspond to newly observed transitions. The identification procedure is described in detail. The aim of this work is to obtain spectroscopic data for multiply charged Xe ions. In addition, the electron capture mechanism is also discussed using the crude classical over-the-barrier model to understand the target dependence of the emission spectra.

  8. Using Section 111 of the Clean Air Act for Cap-and-Trade of Greenhouse Gas Emissions: Obstacles and Solutions

    E-Print Network [OSTI]

    Enion, Rhead M.

    2012-01-01T23:59:59.000Z

    focused nitro- gen oxide emissions-trading program for largeNSPS program could use emissions trading, including cap-and-regulations that allow emissions trading, to achieve GHG

  9. Tier 2 Useful Life (120,000 miles) Exhaust Emission Results for a NOx Adsorber and Diesel Particle Filter Equipped Light-Duty Diesel Vehicle

    SciTech Connect (OSTI)

    Tatur, M.; Tomazic, D.; Thornton, M.; Orban, J.; Slone, E.

    2006-05-01T23:59:59.000Z

    Investigates the emission control system performance and system desulfurization effects on regulated and unregulated emissions in a light-duty diesel engine.

  10. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, Kenneth C. (Bolingbrook, IL); Markun, Francis (Joliet, IL); Zawadzki, Mary T. (South Bend, IN)

    1998-01-01T23:59:59.000Z

    An apparatus and method for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir.

  11. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, K.C.; Markun, F.; Zawadzki, M.T.

    1998-04-28T23:59:59.000Z

    An apparatus and method are disclosed for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir. 6 figs.

  12. Realization of effective super Tonks-Girardeau gases via strongly attractive one-dimensional Fermi gases

    SciTech Connect (OSTI)

    Chen Shu; Yin Xiangguo; Guan Liming [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Guan Xiwen [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Batchelor, M. T. [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Mathematical Sciences Institute, Australian National University, Canberra ACT 0200 (Australia)

    2010-03-15T23:59:59.000Z

    A significant feature of the one-dimensional super Tonks-Girardeau gas is its metastable gas-like state with a stronger Fermi-like pressure than for free fermions which prevents a collapse of atoms. This naturally suggests a way to search for such strongly correlated behavior in systems of interacting fermions in one dimension. We thus show that the strongly attractive Fermi gas without polarization can be effectively described by a super Tonks-Girardeau gas composed of bosonic Fermi pairs with attractive pair-pair interaction. A natural description of such super Tonks-Girardeau gases is provided by Haldane generalized exclusion statistics. In particular, they are equivalent to ideal particles obeying more exclusive statistics than Fermi-Dirac statistics.

  13. Process for removing hydrogen sulfide from gases particularly coal pyrolysis gases

    SciTech Connect (OSTI)

    Ritter, H.; Herpers, E.T.

    1985-02-12T23:59:59.000Z

    Hydrogen sulfide is first removed by ammoniacal liquor from coke oven gas in the bottom part of a gas scrubber. In the top part of the scrubber, two consecutively-arranged fine scrubbing stages remove hydrogen sulfide by treating the gases, in the upper stage, with a caustic soda solution or a caustic potash solution. Beneath the upper scrubbing stage is the second fine scrubbing stage fed with a subflow of an aqueous carbonate solution collecting at the outlet of the upper fine scrubbing stage and a subflow of cooled, regenerated carbonate solution discharged from the hydrogen-sulfide/hydrogen-cyanide stripper. From the hydrogen-sulfide/hydrogen-cyanide stripper, a second subflow is admixed with coal liquor for removing fixed ammonia therefrom in a separator. The separator produces water vapor with carbon dioxide vapors that are delivered to the hydrogen-sulfide/hydrogen-cyanide stripper for regenerating the aqueous carbonate washing solution.

  14. Climate Change Technology Scenarios: Energy, Emissions, and Economic Implications

    SciTech Connect (OSTI)

    Placet, Marylynn; Humphreys, Kenneth K.; Mahasenan, N Maha

    2004-08-15T23:59:59.000Z

    This report describes three advanced technology scenarios and various illustrative cases developed by staff of Pacific Northwest National Laboratory (PNNL) for the U.S. Climate Change Technology Program. These scenarios and illustrative cases explore the energy, emissions and economic implications of using advanced energy technologies and other climate change related technologies to reduce future emissions of greenhouse gases (GHGs). The cases were modeled using the Mini Climate Assessment Model (MiniCAM) developed by PNNL. The report describes the scenarios, the specifications for the cases, and the results. The report also provides background information on current emissions of GHGs and issues associated with stabilizing GHG concentrations.

  15. Process for the removal of acid forming gases from exhaust gases and production of phosphoric acid

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (San Pablo, CA)

    1992-01-01T23:59:59.000Z

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorous preferably in a wet scrubber. The addition of yellow phosphorous in the system induces the production of O.sub.3 which subsequently oxidizes NO to NO.sub.2. The resulting NO.sub.2 dissolves readily and can be reduced to form ammonium ions by dissolved SO.sub.2 under appropriate conditions. In a 20 acfm system, yellow phosphorous is oxidized to yield P.sub.2 O.sub.5 which picks up water to form H.sub.3 PO.sub.4 mists and can be collected as a valuable product. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, better than 90% of SO.sub.2 and NO in simulated flue gas can be removed. Stoichiometric ratios (P/NO) ranging between 0.6 and 1.5 were obtained.

  16. Simulations of greenhouse trace gases using the Los Alamos chemical tracer model

    SciTech Connect (OSTI)

    Kao, C.Y.J.; Morz, E. (Los Alamos National Lab., NM (United States)); Tie, X. (Scripps Institution of Oceanography, San Diego, CA (United States))

    1991-11-01T23:59:59.000Z

    Through three-dimensional global model studies on atmospheric composition and transport, we are improving our quantitative understanding of the origins and behavior of trace gases that affect Earth's radiative energy balance and climate. We will focus, in this paper, on the simulations of three individual trace gases including CFC-11, methyl chloroform, and methane. We first used our chemical tracer model to study the global distribution and trend of chemically inert CFC-11 observed by the Atmospheric Lifetime Experiment. The results show that the model has the ability to reproduce the time-series of the observations. The purpose of this CFC-11 simulation was to test the transport of the model. We then used to model introduce methyl chloroform into the atmosphere according to the known emission patterns and iteratively varied OH fields so that the observed concentrations of methyl chloroform from the observations could be simulated well. The rationale behind this approach is that the reaction with OH is the dominant sink for metyl chloroform and the transport of the model has been tested in the previous CFC-11 study. Finally, using the inferred OH distributions, we conducted a steady-state simulation to reproduce the current methane distribution. The general agreement between the modeled an observed methane surface concentrations has laid a foundation for the simulation of the transient increase of methane.

  17. Simulations of greenhouse trace gases using the Los Alamos chemical tracer model

    SciTech Connect (OSTI)

    Kao, C.Y.J.; Morz, E. [Los Alamos National Lab., NM (United States); Tie, X. [Scripps Institution of Oceanography, San Diego, CA (United States)

    1991-11-01T23:59:59.000Z

    Through three-dimensional global model studies on atmospheric composition and transport, we are improving our quantitative understanding of the origins and behavior of trace gases that affect Earth`s radiative energy balance and climate. We will focus, in this paper, on the simulations of three individual trace gases including CFC-11, methyl chloroform, and methane. We first used our chemical tracer model to study the global distribution and trend of chemically inert CFC-11 observed by the Atmospheric Lifetime Experiment. The results show that the model has the ability to reproduce the time-series of the observations. The purpose of this CFC-11 simulation was to test the transport of the model. We then used to model introduce methyl chloroform into the atmosphere according to the known emission patterns and iteratively varied OH fields so that the observed concentrations of methyl chloroform from the observations could be simulated well. The rationale behind this approach is that the reaction with OH is the dominant sink for metyl chloroform and the transport of the model has been tested in the previous CFC-11 study. Finally, using the inferred OH distributions, we conducted a steady-state simulation to reproduce the current methane distribution. The general agreement between the modeled an observed methane surface concentrations has laid a foundation for the simulation of the transient increase of methane.

  18. Key words. Emissions markets, Cap-and-trade schemes, Equilibrium models, Environmental MARKET DESIGN FOR EMISSION TRADING SCHEMES

    E-Print Network [OSTI]

    Carmona, Rene

    Key words. Emissions markets, Cap-and-trade schemes, Equilibrium models, Environmental Finance. MARKET DESIGN FOR EMISSION TRADING SCHEMES REN´E CARMONA , MAX FEHR , JURI HINZ , AND ARNAUD PORCHET to help policy makers and regulators understand the pros and the cons of the emissions markets. We propose

  19. Evaluation of exposures of hospital employees to anesthetic gases

    SciTech Connect (OSTI)

    Lambeth, J.D.

    1988-01-01T23:59:59.000Z

    Hospital employees who work in hospital operating and recovery rooms are often exposed to a number of anesthetic gases. There is evidence to support the belief that such exposures have led to higher rates of miscarriages and spontaneous abortions of pregnancies among women directly exposed to these gases than among women not exposed. Most of the studies assessing exposure levels were conducted prior to the widespread use of scavenging systems. Air sampling was conducted in hospital operatories and recovery rooms of three large hospitals to assess the current exposure levels in these areas and determine the effectiveness of these systems in reducing exposures to fluoride-containing anesthetic gases. It was determined that recovery-room personnel are exposed to levels of anesthesia gases that often approach and exceed the recommended Threshold Limit Value-Time Weighted Average (TLV-TWA) of 2.0 ppm. Recovery-room personnel do not have the protection from exposure provided by scavenging systems in operating rooms. Operating-room personnel were exposed to anesthesia gas levels above the TLV-TWA only when patients were masked, or connected and disconnected from the scavenging systems. Recovery-room personnel also need to be protected from exposure to anesthesia gases by a scavenging system.

  20. Biogenic greenhouse gas emissions linked to the life cycles of biodiesel derived from European rapeseed and Brazilian soybeans

    E-Print Network [OSTI]

    Biogenic greenhouse gas emissions linked to the life cycles of biodiesel derived from European determinants of life cycle emissions of greenhouse gases linked to the life cycle of biodiesel from European rapeseed and Brazilian soybeans. For biodiesel from European rapeseed and for biodiesel from Brazilian

  1. Method for removing acid gases from a gaseous stream

    DOE Patents [OSTI]

    Gorin, Everett (San Rafael, CA); Zielke, Clyde W. (McMurray, PA)

    1981-01-01T23:59:59.000Z

    In a process for hydrocracking a heavy aromatic polynuclear carbonaceous feedstock containing reactive alkaline constituents to produce liquid hydrocarbon fuels boiling below about 475.degree. C. at atmospheric pressure by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, thereafter separating a gaseous stream containing hydrogen, at least a portion of the hydrocarbon fuels and acid gases from the molten metal halide and regenerating the molten metal halide, thereby producing a purified molten metal halide stream for recycle to the hydrocracking zone, an improvement comprising; contacting the gaseous acid gas, hydrogen and hydrocarbon fuels-containing stream with the feedstock containing reactive alkaline constituents to remove acid gases from the acid gas containing stream. Optionally at least a portion of the hydrocarbon fuels are separated from gaseous stream containing hydrogen, hydrocarbon fuels and acid gases prior to contacting the gaseous stream with the feedstock.

  2. Separating hydrogen from coal gasification gases with alumina membranes

    SciTech Connect (OSTI)

    Egan, B.Z. (Oak Ridge National Lab., TN (USA)); Fain, D.E.; Roettger, G.E.; White, D.E. (Oak Ridge K-25 Site, TN (USA))

    1991-01-01T23:59:59.000Z

    Synthesis gas produced in coal gasification processes contains hydrogen, along with carbon monoxide, carbon dioxide, hydrogen sulfide, water, nitrogen, and other gases, depending on the particular gasification process. Development of membrane technology to separate the hydrogen from the raw gas at the high operating temperatures and pressures near exit gas conditions would improve the efficiency of the process. Tubular porous alumina membranes with mean pore radii ranging from about 9 to 22 {Angstrom} have been fabricated and characterized. Based on hydrostatic tests, the burst strength of the membranes ranged from 800 to 1600 psig, with a mean value of about 1300 psig. These membranes were evaluated for separating hydrogen and other gases. Tests of membrane permeabilities were made with helium, nitrogen, and carbon dioxide. Measurements were made at room temperature in the pressure range of 15 to 589 psi. Selected membranes were tested further with mixed gases simulating a coal gasification product gas. 5 refs., 7 figs.

  3. “Hard probes” of strongly-interacting atomic gases

    SciTech Connect (OSTI)

    Nishida, Yusuke [Los Alamos National Laboratory

    2012-06-18T23:59:59.000Z

    We investigate properties of an energetic atom propagating through strongly interacting atomic gases. The operator product expansion is used to systematically compute a quasiparticle energy and its scattering rate both in a spin-1/2 Fermi gas and in a spinless Bose gas. Reasonable agreement with recent quantum Monte Carlo simulations even at a relatively small momentum k/kF > 1.5 indicates that our large-momentum expansions are valid in a wide range of momentum. We also study a differential scattering rate when a probe atom is shot into atomic gases. Because the number density and current density of the target atomic gas contribute to the forward scattering only, its contact density (measure of short-range pair correlation) gives the leading contribution to the backward scattering. Therefore, such an experiment can be used to measure the contact density and thus provides a new local probe of strongly interacting atomic gases.

  4. Regulation XVII: GENERAL REGULATIONS FOR FIRST DEGREES

    E-Print Network [OSTI]

    Regulation XVII: GENERAL REGULATIONS FOR FIRST DEGREES SCOPE OF THESE REGULATIONS4 1. These Regulations apply, subject to any different provision in the Regulations for a particular programme of study programme of study is designated as a non-modular programme, Regulation 14 and subsequent Regulations

  5. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, G.I.; Dietz, R.N.

    1994-04-05T23:59:59.000Z

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

  6. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

    1994-01-01T23:59:59.000Z

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

  7. Removal of sulfur and nitrogen containing pollutants from discharge gases

    DOE Patents [OSTI]

    Joubert, James I. (Pittsburgh, PA)

    1986-01-01T23:59:59.000Z

    Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

  8. Methods, systems, and devices for deep desulfurization of fuel gases

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA); Liu, Jun (Richland, WA); Huo, Qisheng (Richland, WA)

    2012-04-17T23:59:59.000Z

    A highly effective and regenerable method, system and device that enables the desulfurization of warm fuel gases by passing these warm gasses over metal-based sorbents arranged in a mesoporous substrate. This technology will protect Fischer-Tropsch synthesis catalysts and other sulfur sensitive catalysts, without drastic cooling of the fuel gases. This invention can be utilized in a process either alone or alongside other separation processes, and allows the total sulfur in such a gas to be reduced to less than 500 ppb and in some instances as low as 50 ppb.

  9. Light duty vehicle full fuel cycle emissions analysis. Topical report, April 1993-April 1994

    SciTech Connect (OSTI)

    Darrow, K.G.

    1994-04-01T23:59:59.000Z

    The report provides a methodology for analyzing full fuel cycle emissions of alternative fuels for vehicles. Included in this analysis is an assessment of the following fuel cycles relevant to vehicle use: gasoline, reformulated gasoline, natural gas, liquefied petroleum gas, electric power (with onboard battery storage), ethanol, and methanol fuels. The analysis focuses on basic criteria pollutants (reactive organic gases, nitrous oxides, carbon monoxide, sulfurous oxides, and particulates less than 10 microns (PM10)). Emissions of greenhouse gases (carbon dioxide, methane, and nitrous oxide) are also defined. The analysis was conducted for two cases, United States and the State of California and two time frames, current and year 2000.

  10. Alternative Regulation (Vermont)

    Broader source: Energy.gov [DOE]

    Utility regulators, including the Public Service Board, have applied a new type of regulation, often called "alternative regulation" or "incentive regulation." There are many variants of this type...

  11. Electrochemical NOx Sensor for Monitoring Diesel Emissions

    SciTech Connect (OSTI)

    Woo, L Y; Glass, R S

    2008-11-14T23:59:59.000Z

    Increasingly stringent emissions regulations will require the development of advanced gas sensors for a variety of applications. For example, compact, inexpensive sensors are needed for detection of regulated pollutants, including hydrocarbons (HCs), CO, and NO{sub x}, in automotive exhaust. Of particular importance will be a sensor for NO{sub x} to ensure the proper operation of the catalyst system in the next generation of diesel (CIDI) automobiles. Because many emerging applications, particularly monitoring of automotive exhaust, involve operation in harsh, high-temperature environments, robust ceramic-oxide-based electrochemical sensors are a promising technology. Sensors using yttria-stabilized zirconia (YSZ) as an oxygen-ion-conducting electrolyte have been widely reported for both amperometric and potentiometric modes of operation. These include the well-known exhaust gas oxygen (EGO) sensor. More recently, ac impedance-based (i.e., impedance-metric) sensing techniques using YSZ have been reported for sensing water vapor, hydrocarbons, CO, and NO{sub x}. Typically small-amplitude alternating signal is applied, and the sensor response is measured at a specified frequency. Most impedance-metric techniques have used the modulus (or magnitude) at low frequencies (< 1 Hz) as the sensing signal and attribute the measured response to interfacial phenomena. Work by our group has also investigated using phase angle as the sensing signal at somewhat higher frequencies (10 Hz). The higher frequency measurements would potentially allow for reduced sampling times during sensor operation. Another potential advantage of impedance-metric NO{sub x} sensing is the similarity in response to NO and NO{sub 2} (i.e., total-NO{sub x} sensing). Potentiometric NO{sub x} sensors typically show higher sensitivity to NO2 than NO, and responses that are opposite in sign. However, NO is more stable than NO{sub 2} at temperatures > 600 C, and thermodynamic calculations predict {approx}90% NO, balance NO{sub 2}. Since automotive exhaust sensors will probably be required to operate at temperatures > 600 C, NO is the dominant component in thermodynamic equilibrium and the target NOx species. Also, the use of upstream catalysts could further promote the conversion of NO{sub x} species to NO. Therefore, the focus of current work is to investigate the response to NO. Nevertheless, minimizing the sensitivity to a variety of competing species is important in order to obtain the accuracy necessary for achieving the emission limits. Mitigating the effect of interfering gases (e.g., O{sub 2}, water vapor, HCs, etc.) is an area of current study. For impedance metric NO{sub x} sensors, our previous work has demonstrated that the cross-sensitivity to O{sub 2} may be accounted for by comparing measurements at multiple frequencies. Other strategies for compensation are also being explored, including calibration using data from existing sensors located nearby. Our current work has made significant advances in terms of developing prototype sensors more suitable for commercialization. Also, dynamometer testing has provided real-world sensor performance data that will be useful in approaching potential suppliers to whom we can transfer the technology for commercialization. The advances are a direct result of understanding the sensing mechanisms responsible for impedance-based NO{sub x} sensing and the effect of materials choice and sensor design/geometry.

  12. Sensitive Multi-Species Emissions Monitoring: Infrared Laser-Based Detection of Trace-Level Contaminants.

    SciTech Connect (OSTI)

    Steill, Jeffrey D

    2015-01-01T23:59:59.000Z

    This report summarizes our development of spectroscopic chemical analysis techniques and spectral modeling for trace-gas measurements of highly-regulated low-concentration species present in flue gas emissions from utility coal boilers such as HCl under conditions of high humidity. Detailed spectral modeling of the spectroscopy of HCl and other important combustion and atmospheric species such as H 2 O, CO 2 , N 2 O, NO 2 , SO 2 , and CH 4 demonstrates that IR-laser spectroscopy is a sensitive multi-component analysis strategy. Experimental measurements from techniques based on IR laser spectroscopy are presented that demonstrate sub-ppm sensitivity levels to these species. Photoacoustic infrared spectroscopy is used to detect and quantify HCl at ppm levels with extremely high signal-to-noise even under conditions of high relative humidity. Additionally, cavity ring-down IR spectroscopy is used to achieve an extremely high sensitivity to combustion trace gases in this spectral region; ppm level CH 4 is one demonstrated example. The importance of spectral resolution in the sensitivity of a trace-gas measurement is examined by spectral modeling in the mid- and near-IR, and efforts to improve measurement resolution through novel instrument development are described. While previous project reports focused on benefits and complexities of the dual-etalon cavity ring-down infrared spectrometer, here details on steps taken to implement this unique and potentially revolutionary instrument are described. This report also illustrates and critiques the general strategy of IR- laser photodetection of trace gases leading to the conclusion that mid-IR laser spectroscopy techniques provide a promising basis for further instrument development and implementation that will enable cost-effective sensitive detection of multiple key contaminant species simultaneously.

  13. Government Regulation

    E-Print Network [OSTI]

    Ashford, Nicholas

    2005-01-01T23:59:59.000Z

    Abstract. Interest in the use of so-called voluntary approaches to supplement or replace formal environmental regulation is on the rise, both in Europe and in the United States. These approaches fall into two general ...

  14. Saving Fuel, Reducing Emissions

    E-Print Network [OSTI]

    Kammen, Daniel M.; Arons, Samuel M.; Lemoine, Derek M.; Hummel, Holmes

    2009-01-01T23:59:59.000Z

    lower greenhouse gas emissions from electricity productionAssessment of Greenhouse Gas Emissions from Plug-in Hybridof national greenhouse gas emissions. Both motor vehicle

  15. Emissions of trace gases and aerosols during the open combustion of biomass in the laboratory

    E-Print Network [OSTI]

    McMeeking, Gavin R.

    2009-01-01T23:59:59.000Z

    roemerianus). We also burned kudzu (Pueraria lobata), ancommon reed, hickory, kudzu, needlegrass rush, rhododendron,included ‘leafy’ fuels such as kudzu, turkey oak, sagebrush,

  16. GASES EMISSION MONITORING IN A POST-MINING CONTEXT BESNARD Katia1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    to the surface through existing aerodynamic links like abandoned shaft or galleries and fissures in rock; abandoned mines; monitoring; in-situ measurements. RESUME : Les mines abandonnées sont fréquemment le lieu reservoirs formed by residual voids left by the mining activity. It can migrate to surface under the effect

  17. EIA-Voluntary Reporting of Greenhouse Gases Program - Emission Factors and

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688 760,877SouthwestWisconsin profileDatabase Form914

  18. Emissions of Greenhouse Gases in the United States 2009, DOE/EIA-0573(2009)

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688Electricity Use as an Indicator of U.S. Economic Activity1

  19. AER1301: KINETIC THEORY OF GASES Assignment #1

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    AER1301: KINETIC THEORY OF GASES Assignment #1 1. A hypersonic wind tunnel is contructed so such that the mean free path, , is given by the expression = 16µ 5 1 2RT , where R is the ideal gas constant and p space and the length of each side of the cube is 4v. (a) Obtain an expression for the normalized

  20. AER1301: KINETIC THEORY OF GASES Assignment #1

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    AER1301: KINETIC THEORY OF GASES Assignment #1 1. A hypersonic wind tunnel is contructed so spheres during collisions such that the mean free path, #21;, is given by the expression #21; = 16#22; 5 of the cube is 4v Ć . (a) Obtain an expression for the normalized velocity distribution function, f(v). (b

  1. AER1301: KINETIC THEORY OF GASES Assignment #4

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    - equilibrium cases, up to second order. (b) Derive an expression for the non-conservative form of the kineticAER1301: KINETIC THEORY OF GASES Assignment #4 1. Consider a monatomic gas with one translational by the relaxation time approx- imation. Neglecting external forces, the conserved form of the kinetic equation

  2. AER1301: KINETIC THEORY OF GASES Assignment #4

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    AER1301: KINETIC THEORY OF GASES Assignment #4 1. Consider a monatomic gas with one translational by the relaxation time approx- imation. Neglecting external forces, the conserved form of the kinetic equation function, in both the equilibrium and non- equilibrium cases, up to second order. (b) Derive an expression

  3. Ozone-depleting substances and the greenhouse gases HFCs, PFCs

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 19 3.1 IMPORTS AND EXPORTS 19 3.1.1 CFCs 19 3.1.2 Tetrachloromethane 19 3

  4. Nature of superfluidity in ultracold Fermi gases near Feshbach resonances

    SciTech Connect (OSTI)

    Stajic, Jelena; Levin, K. [James Franck Institute and Department of Physics, University of Chicago, Chicago, Illinois 60637 (United States); Milstein, J.N.; Holland, M.J. [JILA, University of Colorado and National Institute of Standards and Technology, Boulder, Colorado 80309 (United States); Chen Qijin [Department of Physics and Astronomy, Johns Hopkins University, Baltimore, Maryland 21218 (United States); Chiofalo, M.L. [Classe di Scienze and INFM, Scuola Normale Superiore, Piazza dei Cavelieri 7, I-56126 Pisa (Italy)

    2004-06-01T23:59:59.000Z

    We study the superfluid state of atomic Fermi gases using a BCS-Bose-Einstein-condensation crossover theory. Our approach emphasizes noncondensed fermion pairs which strongly hybridize with their (Feshbach-induced) molecular boson counterparts. These pairs lead to pseudogap effects above T{sub c} and non-BCS characteristics below. We discuss how these effects influence the experimental signatures of superfluidity.

  5. INTRODUCTION Insects exchange respiratory gases through a complex network of

    E-Print Network [OSTI]

    Socha, Jake

    3409 INTRODUCTION Insects exchange respiratory gases through a complex network of tracheal tubes through the tracheal system using diffusion alone (Krogh, 1920a; Weis-Fogh, 1964), many species are known to augment gas exchange using convection (Buck, 1962; Miller, 1966a). Two general mechanisms are recognized

  6. Higher Dimensional Coulomb Gases and Renormalized Energy Functionals

    E-Print Network [OSTI]

    -Louis Lions, Paris, F-75005 France & Courant Institute, New York University, 251 Mercer st, NY NY 10012, USAHigher Dimensional Coulomb Gases and Renormalized Energy Functionals N. Rougerie and S. Serfaty extract the next to leading order term in the ground state energy, beyond the mean-field limit. We show

  7. Use of low temperature blowers for recirculation of hot gases

    DOE Patents [OSTI]

    Maru, H.C.; Forooque, M.

    1982-08-19T23:59:59.000Z

    An apparatus is described for maintaining motors at low operating temperatures during recirculation of hot gases in fuel cell operations and chemical processes such as fluidized bed coal gasification. The apparatus includes a means for separating the hot process gas from the motor using a secondary lower temperature gas, thereby minimizing the temperature increase of the motor and associated accessories.

  8. Noble gases and radiocarbon in natural gas hydrates Gisela Winckler

    E-Print Network [OSTI]

    Aeschbach-Hertig, Werner

    Noble gases and radiocarbon in natural gas hydrates Gisela Winckler Lamont-Doherty Earth 2001; published 24 May 2002. [1] In samples of pure natural gas hydrates from Hydrate Ridge, Cascadia ones preferentially incorporated into the gas hydrate structure. The hydrate methane is devoid of 14 C

  9. Volcanic gas emissions and their effect on ambient air character

    SciTech Connect (OSTI)

    Sutton, A.J. [Geological Survey, Menlo Park, CA (United States); Elias, T. [Geological Survey, Hawaii National Park, HI (United States). Hawaiian Volcano Observatory

    1994-01-01T23:59:59.000Z

    This bibliography was assembled to service an agreement between Department of Energy and the USGS to provide a body of references and useful annotations for understanding background gas emissions from Kilauea volcano. The current East Rift Zone (ERZ) eruption of Kilauea releases as much as 500,000 metric tonnes of SO{sub 2} annually, along with lesser amounts of other chemically and radiatively active species including H{sub 2}S, HCl, and HF. Primary degassing locations on Kilauea are located in the summit caldera and along the middle ERZ. The effects of these emissions on ambient air character are a complex function of chemical reactivity, source geometry and effusivity, and local meteorology. Because of this complexity, we organized the bibliography into three main sections: (1) characterizing gases as they leave the edifice; (2) characterizing gases and chemical reaction products away from degassing sources; and (3) Hawaii Island meteorology.

  10. Fact #771: March 18, 2013 California Zero-Emission Vehicle Mandate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    December 27, 2012, allowed the Amendments to the California Zero Emission Vehicle (ZEV) Regulation to become effective immediately. California had passed the law in early 2012,...

  11. Strongly interacting Fermi gases : non-equilibrium dynamics and dimensional crossover

    E-Print Network [OSTI]

    Sommer, Ariel T. (Ariel Tjodolv)

    2013-01-01T23:59:59.000Z

    Experiments using ultracold atomic gases address fundamental problems in many-body physics. This thesis describes experiments on strongly-interacting gases of fermionic atoms, with a focus on non-equilibrium physics and ...

  12. Steam Production from Waste Stack Gases in a Carbon Black Plant

    E-Print Network [OSTI]

    Istre, R. I.

    1981-01-01T23:59:59.000Z

    gases to produce steam has two very important rewards - energy conservation and pollution abatement. Energy conservation is achieved by using waste gases in place of fuel oil to produce the steam required by the various plants. Pollution abatement is due...

  13. Rethinking Downstream Regulation: California's Opportunity to Engage Households in Reducing Greenhouse Gases

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    in the winter months when hydroelectric power generation isare located and hydroelectric power generation is naturally

  14. Production of ethanol from refinery waste gases. Phase 2, technology development, annual report

    SciTech Connect (OSTI)

    Arora, D.; Basu, R.; Phillips, J.R.; Wikstrom, C.V.; Clausen, E.C.; Gaddy, J.L.

    1995-07-01T23:59:59.000Z

    Oil refineries discharge large volumes of H{sub 2}, CO, and CO{sub 2} from cracking, coking, and hydrotreating operations. This program seeks to develop a biological process for converting these waste gases into ethanol, which can be blended with gasoline to reduce emissions. Production of ethanol from all 194 US refineries would save 450 billion BTU annually, would reduce crude oil imports by 110 million barrels/year and emissions by 19 million tons/year. Phase II efforts has yielded at least 3 cultures (Clostridium ljungdahlii, Isolate O-52, Isolate C-01) which are able to produce commercially viable concentrations of ethanol from CO, CO{sub 2}, and H{sub 2} in petroleum waste gas. Single continuous stirred tank reactor studies have shown that 15-20 g/L of ethanol can be produced, with less than 5 g/L acetic acid byproduct. Culture and reactor optimization in Phase III should yield even higher ethanol concentrations and minimal acetic acid. Product recovery studies showed that ethanol is best recovered in a multi-step process involving solvent extraction/distillation to azeotrope/azeotropic distillation or pervaporation, or direct distillation to the azeotrope/azeotropic distillation or pervaporation. Projections show that the ethanol facility for a typical refinery would require an investment of about $30 million, which would be returned in less than 2 years.

  15. Key statistics related to CO/sub 2/ emissions: Significant contributing countries

    SciTech Connect (OSTI)

    Kellogg, M.A.; Edmonds, J.A.; Scott, M.J.; Pomykala, J.S.

    1987-07-01T23:59:59.000Z

    This country selection task report describes and applies a methodology for identifying a set of countries responsible for significant present and anticipated future emissions of CO/sub 2/ and other radiatively important gases (RIGs). The identification of countries responsible for CO/sub 2/ and other RIGs emissions will help determine to what extent a select number of countries might be capable of influencing future emissions. Once identified, those countries could potentially exercise cooperative collective control of global emissions and thus mitigate the associated adverse affects of those emissions. The methodology developed consists of two approaches: the resource approach and the emissions approach. While conceptually very different, both approaches yield the same fundamental conclusion. The core of any international initiative to control global emissions must include three key countries: the US, USSR, and the People's Republic of China. It was also determined that broader control can be achieved through the inclusion of sixteen additional countries with significant contributions to worldwide emissions.

  16. Saving Fuel, Reducing Emissions

    E-Print Network [OSTI]

    Kammen, Daniel M.; Arons, Samuel M.; Lemoine, Derek M.; Hummel, Holmes

    2009-01-01T23:59:59.000Z

    COMPACT EMISSIONS HEV PHEV marginal power plant is a coalpower uses relatively little coal, but in other cases emissions

  17. Technology Opportunities to Reduce U.S. Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    National Lab Directors, . .

    2001-04-05T23:59:59.000Z

    The rise in greenhouse gas emissions from fossil fuel combustion and industrial and agricultural activities has aroused international concern about the possible impacts of these emissions on climate. Greenhouse gases--mostly carbon dioxide, some methane, nitrous oxide and other trace gases--are emitted to the atmosphere, enhancing an effect in which heat reflected from the earth's surface is kept from escaping into space, as in a greenhouse. Thus, there is concern that the earth's surface temperature may rise enough to cause global climate change. Approximately 90% of U.S. greenhouse gas emissions from anthropogenic sources come from energy production and use, most of which are a byproduct of the combustion of fossil fuels. On a per capita basis, the United States is one of the world's largest sources of greenhouse gas emissions, comprising 4% of the world's population, yet emitting 23% of the world's greenhouse gases. Emissions in the United States are increasing at around 1.2% annually, and the Energy Information Administration forecasts that emissions levels will continue to increase at this rate in the years ahead if we proceed down the business-as-usual path. President Clinton has presented a two-part challenge for the United States: reduce greenhouse gas emissions and grow the economy. Meeting the challenge will mean that in doing tomorrow's work, we must use energy more efficiently and emit less carbon for the energy expended than we do today. To accomplish these goals, President Clinton proposed on June 26, 1997, that the United States ''invest more in the technologies of the future''. In this report to Secretary of Energy Pena, 47 technology pathways are described that have significant potential to reduce carbon dioxide emissions. The present study was completed before the December 1997 United Nations Framework Convention on Climate Change and is intended to provide a basis to evaluate technology feasibility and options to reduce greenhouse gas emissions. These technology pathways (which are described in greater detail in Appendix B, Technology Pathways) address three areas: energy efficiency, clean energy, and carbon sequestration (removing carbon from emissions and enhancing carbon storage). Based on an assessment of each of these technology pathways over a 30-year planning horizon, the directors of the Department of Energy's (DOE's) national laboratories conclude that success will require pursuit of multiple technology pathways to provide choices and flexibility for reducing greenhouse gas emissions. Advances in science and technology are necessary to reduce greenhouse gas emissions from the United States while sustaining economic growth and providing collateral benefits to the nation.

  18. Regulation 29: Other Regulations concerning the University site and buildings, Computing Regulations and Miscellaneous Administrative Regulations

    E-Print Network [OSTI]

    Sussex, University of

    Regulations and Miscellaneous Administrative Regulations 190 nuisance to occupants, except in designated (Vehicle Operators and Penalty Notices) Regulations; (iii) allow smoking in designated study bedroomsRegulation 29: Other Regulations concerning the University site and buildings, Computing

  19. System for trapping and storing gases for subsequent chemical reduction to solids

    DOE Patents [OSTI]

    Vogel, John S. (San Jose, CA); Ognibene, Ted J. (Oakland, CA); Bench, Graham S. (Livermore, CA); Peaslee, Graham F. (Holland, MI)

    2009-11-03T23:59:59.000Z

    A system for quantitatively reducing oxide gases. A pre-selected amount of zinc is provided in a vial. A tube is provided in the vial. The zinc and the tube are separated. A pre-selected amount of a catalyst is provided in the tube. Oxide gases are injected into the vial. The vial, tube, zinc, catalyst, and the oxide gases are cryogenically cooled. At least a portion of the vial, tube, zinc, catalyst, and oxide gases are heated.

  20. Title of Document: INTERACTION OF INTENSE SHORT LASER PULSES WITH GASES OF NANOSCALE

    E-Print Network [OSTI]

    Anlage, Steven

    ABSTRACT Title of Document: INTERACTION OF INTENSE SHORT LASER PULSES WITH GASES OF NANOSCALE-cluster interaction. #12;INTERACTION OF INTENSE SHORT LASER PULSES WITH GASES OF NANOSCALE ATOMIC AND MOLECULAR., Department of Electrical and Computer Engineering We study the interaction of intense laser pulses with gases

  1. Process for separation of CO/sub 2/ from CO/sub 2/-containing gases

    SciTech Connect (OSTI)

    Linde, G.

    1985-07-09T23:59:59.000Z

    For separating CO/sub 2/ from CO/sub 2/-containing gases, especially stack gases and/or blast furnace gases, dimethylformamide is employed as a physical scrubbing medium to ensure high CO/sub 2/ purity. After absorption of CO/sub 2/, the DMF is regenerated and returned into the scrubbing stage. Dimethylformamide is utilized as the scrubbing medium.

  2. NARUC: Regulation at the crossroads

    SciTech Connect (OSTI)

    Not Available

    1990-01-04T23:59:59.000Z

    This article reports on the review of changes during the last decade of the regulation of industries by the federal government. The state commissioners that make up the National Association of Regulatory Utility Commissioners discuss the changing regulatory climate for a competitive industry, changes in the federal-state relationship, proposed changes in jurisdictional boundaries, acid rain legislation and emissions trading, and Senator J. Bennet Johnson's amendment to the Public Utilities Holding Company Act.

  3. Greenhouse Gas Dissonance: The History of EPA's Regulations and the Incongruity of Recent Legal Challenges

    E-Print Network [OSTI]

    Moreno, Robert B.; Zalzal, Peter

    2012-01-01T23:59:59.000Z

    denial of the scientific data underpinning climate change.denial notice asserted that not regulating GHG emissions from motor vehicles dovetailed with President Bush's "comprehensive global climate change

  4. Sacred Cars? Optimal Regulation of Stationary and Non-stationary Pollution Sources

    E-Print Network [OSTI]

    Fowlie, Meredith; Knittel, Christopher R; Wolfram, Catherine D

    2008-01-01T23:59:59.000Z

    Mendelsohn. 2008. "E˘ cient Pollution Regulation: Gettingthe damages of air pollution in the United States. ” JournalMendelsohn. 2006. “The Air Pollution Emission Experiments

  5. Towards an Emissions Trading Scheme for Air Pollutants in India

    E-Print Network [OSTI]

    Duflo, Esther

    Emissions trading schemes have great potential to lower pollution while minimizing compliance costs for firms in many areas now subject to traditional command-and-control regulation. This paper connects experience with ...

  6. Power plant emissions verified remotely at Four Corners sites

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    measurements can support Clean Air Act regulations LOS ALAMOS, N.M., May 19, 2014-Air pollution and greenhouse gas emissions from two coal-fired power plants in the Four...

  7. Modeling of Particulate Matter Emissions from Agricultural Operations

    E-Print Network [OSTI]

    Bairy, Jnana 1988-

    2013-01-02T23:59:59.000Z

    State Air Pollution Regulation Agencies (SAPRAs) issue and enforce permits that limit particulate matter emissions from all sources including layer and broiler facilities, cattle feedyards, dairies, cotton gins, and grain elevators...

  8. Clostridium stain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, James L. (2207 Tall Oaks Dr., Fayetteville, AR 72703)

    1997-01-01T23:59:59.000Z

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

  9. The extreme nonlinear optics of gases and femtosecond optical filamentation

    SciTech Connect (OSTI)

    Milchberg, H. M.; Chen, Y.-H.; Cheng, Y.-H.; Jhajj, N.; Palastro, J. P.; Rosenthal, E. W.; Varma, S.; Wahlstrand, J. K.; Zahedpour, S. [Institute for Research in Electronics and Applied Physics, University of Maryland, College Park, Maryland 20742 (United States)

    2014-10-15T23:59:59.000Z

    Under certain conditions, powerful ultrashort laser pulses can form greatly extended, propagating filaments of concentrated high intensity in gases, leaving behind a very long trail of plasma. Such filaments can be much longer than the longitudinal scale over which a laser beam typically diverges by diffraction, with possible applications ranging from laser-guided electrical discharges to high power laser propagation in the atmosphere. Understanding in detail the microscopic processes leading to filamentation requires ultrafast measurements of the strong field nonlinear response of gas phase atoms and molecules, including absolute measurements of nonlinear laser-induced polarization and high field ionization. Such measurements enable the assessment of filamentation models and make possible the design of experiments pursuing applications. In this paper, we review filamentation in gases and some applications, and discuss results from diagnostics developed at Maryland for ultrafast measurements of laser-gas interactions.

  10. Apparatus for the plasma destruction of hazardous gases

    DOE Patents [OSTI]

    Kang, Michael (Los Alamos, NM)

    1995-01-01T23:59:59.000Z

    A plasma cell for destroying hazardous gases. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required.

  11. Apparatus for the plasma destruction of hazardous gases

    DOE Patents [OSTI]

    Kang, M.

    1995-02-07T23:59:59.000Z

    A plasma cell for destroying hazardous gases is described. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required. 4 figs.

  12. Clostridium strain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, J.L.

    1997-01-14T23:59:59.000Z

    A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 4 figs.

  13. Decontamination of combustion gases in fluidized bed incinerators

    DOE Patents [OSTI]

    Leon, Albert M. (Mamaroneck, NY)

    1982-01-01T23:59:59.000Z

    Sulfur-containing atmospheric pollutants are effectively removed from exit gas streams produced in a fluidized bed combustion system by providing a fluidized bed of particulate material, i.e. limestone and/or dolomite wherein a concentration gradient is maintained in the vertical direction. Countercurrent contacting between upwardly directed sulfur containing combustion gases and descending sorbent particulate material creates a concentration gradient across the vertical extent of the bed characterized in progressively decreasing concentration of sulfur, sulfur dioxide and like contaminants upwardly and decreasing concentration of e.g. calcium oxide, downwardly. In this manner, gases having progressively decreasing sulfur contents contact correspondingly atmospheres having progressively increasing concentrations of calcium oxide thus assuring optimum sulfur removal.

  14. Vapor canister heater for evaporative emissions systems

    SciTech Connect (OSTI)

    Bishop, R.P.; Berg, P.G.

    1987-01-01T23:59:59.000Z

    Automotive evaporative emissions systems use a charcoal canister to store evaporative hydrocarobn emissions. These stored vapors are later purged and burned during engine operation. Under certain conditions the engine cannot completely purge the canister of the stored fuel vapors, which results in a decreased vapor storage capacity in the canister. A self-regulating PTC (Positive Temperature Coefficient) heater has been developed to warm the purge air as it enters the canister, in order to provide thermal energy for increased release of the vapors from charcoal sites. This paper describes the construction and operation of the vapor canister heater as it relates to improved evaporative emission system performance.

  15. Wave Speed in the Macroscopic Extended Model for Ultrarelativistic Gases

    E-Print Network [OSTI]

    F. Borghero; F. Demontis; S. Pennisi

    2010-12-07T23:59:59.000Z

    An exact macroscopic extended model for ultrarelativistic gases, with an arbitrary number of moments, is present in the literature. Here we exploit equations determining wave speeds for that model. We find interesting results; for example, the whole system for their determination can be divided into independent subsystems and some, but not all, wave speeds are expressed by rational numbers. Moreover, the extraordinary property that these wave speeds for the macroscopic model are the same of those in the kinetic model, is proved.

  16. Pulse Radiolysis of Gases H atom yields, OH reactions,

    E-Print Network [OSTI]

    PULSE RADIOLYSIS OP GASES H atom yields, OH reactions, and kinetics of H2S systems Ole John Nielsen, M, in the reaction OH + OH + M · H2O2 + M. 3) In the H2S systems the HS extinction coefficient determined: k(H + H2S · H2 + HS) = 4-6 x 108 M ^ s " 1 k(HS + HS · products) = (1.9 ± 0.1) x io1 0 M ^ s " 1

  17. Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases

    SciTech Connect (OSTI)

    Carlsbad Field Office

    2006-04-01T23:59:59.000Z

    The Performance Demonstration Program (PDP) for headspace gases distributes sample gases of volatile organic compounds (VOCs) for analysis. Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facility’s compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.

  18. Regulation XVIII: GENERAL REGULATIONS FOR HIGHER DEGREES,

    E-Print Network [OSTI]

    Regulation XVIII: GENERAL REGULATIONS FOR HIGHER DEGREES, POSTGRADUATE DIPLOMAS AND POSTGRADUATE CERTIFICATES SCOPE OF THESE REGULATIONS 1. These Regulations apply to the Degree of PhD in all Faculties in all Faculties Postgraduate Certificates in all Faculties. 2. These Regulations are subject

  19. Regulation 28: Library REGULATION 28: LIBRARY

    E-Print Network [OSTI]

    Sussex, University of

    Regulation 28: Library 180 REGULATION 28: LIBRARY The purpose of this Regulation is to safeguard the common interests of all Library users. All persons are admitted on the understanding that they have read and agreed to observe the Library Regulations. Breach of this Regulation could result in membership being

  20. Chemical production from industrial by-product gases: Final report

    SciTech Connect (OSTI)

    Lyke, S.E.; Moore, R.H.

    1981-04-01T23:59:59.000Z

    The potential for conservation of natural gas is studied and the technical and economic feasibility and the implementation of ventures to produce such chemicals using carbon monoxide and hydrogen from byproduct gases are determined. A survey was performed of potential chemical products and byproduct gas sources. Byproduct gases from the elemental phosphorus and the iron and steel industries were selected for detailed study. Gas sampling, preliminary design, market surveys, and economic analyses were performed for specific sources in the selected industries. The study showed that production of methanol or ammonia from byproduct gas at the sites studied in the elemental phosphorus and the iron and steel industries is technically feasible but not economically viable under current conditions. Several other applications are identified as having the potential for better economics. The survey performed identified a need for an improved method of recovering carbon monoxide from dilute gases. A modest experimental program was directed toward the development of a permselective membrane to fulfill that need. A practical membrane was not developed but further investigation along the same lines is recommended. (MCW)

  1. Air Emission Inventory for the Idaho National Engineering Laboratory: 1992 emissions report

    SciTech Connect (OSTI)

    Stirrup, T.S.

    1993-06-01T23:59:59.000Z

    This report presents the 1992 Air Emission Inventory for the Idaho National Engineering Laboratory. Originally, this report was in response to the Environmental Oversight and Monitoring Agreement in 1989 between the State of Idaho and the Department of Energy Idaho Field Office, and a request from the Idaho Air Quality Bureau. The current purpose of the Air Emission Inventory is to provide the basis for the preparation of the INEL Permit-to-Operate (PTO) an Air Emission Source Application, as required by the recently promulgated Title V regulations of the Clean Air Act. This report includes emissions calculations from 1989 to 1992. The Air Emission Inventory System, an ORACLE-based database system, maintains the emissions inventory.

  2. Limiting net greenhouse gas emissions in the United States

    SciTech Connect (OSTI)

    Bradley, R A; Watts, E C; Williams, E R [eds.] [eds.

    1991-09-01T23:59:59.000Z

    In 2988 the Congress requested DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. This report presents the results of that study. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity), and the relationship between energy production and use and the emission of radiactively important gases. Topics discussed include: energy and environmental technology to reduce greenhouse gas emissions, fossil energy production and electricity generation technologies, nuclear energy technology, renewable energy technologies, energy storage, transmission, and distribution technology, transportation, technology, industrial technology, residential and commercial building technology, greenhouse gas removal technology, approaches to restructuring the demand for energy.

  3. Reduce emissions and operating costs with appropriate glycol selection

    SciTech Connect (OSTI)

    Covington, K.; Lyddon, L. [Bryan Research and Engineering, Inc., TX (United States); Ebeling, H. [Latoka Engineering L.L.C., Tulsa, OK (United States)

    1998-12-31T23:59:59.000Z

    Benzene, toluene, ethylbenzene and xylene (BTEX) emissions from glycol dehydration units have become a major concern and some form of control is necessary in many cases. One method of reducing BTEX emissions that is often overlooked is in the selection of the proper dehydrating agent. BTEX compounds are less soluble in diethylene glycol (DEG) than triethylene glycol (TEG) and considerably less soluble in ethylene glycol (EG). If the use of DEG or EG achieves the required gas dew point in cases where BTEX emissions are a concern, a significant savings in both operating costs and the cost of treating still vent gases may be achieved. This paper compares plant operations using TEG, DEG and EG from the viewpoint of BTEX emissions, circulating rates, utilities and dehydration capabilities.

  4. Thermodynamics of sustaining gases in the roughness of submerged superhydrophobic surfaces

    E-Print Network [OSTI]

    Neelesh A. Patankar

    2015-05-22T23:59:59.000Z

    Rough surfaces submerged in a liquid can remain almost dry if the liquid does not fully wet the roughness and gases are sustained in roughness grooves. Such partially dry surfaces can help reduce drag or enhance boiling. Gases sustained in roughness grooves would be composed of air and the vapor phase of the liquid itself. The thermodynamics of sustaining vapor was considered in a prior work [Patankar, Soft Matter, 2010, 6:1613]. Here, the thermodynamics of sustaining gases (e.g. air) is considered. Governing equations are presented along with a solution methodology to determine a critical condition to sustain gases. The critical roughness scale to sustain gases is estimated for different degrees of saturation of gases dissolved in the liquid. It is shown that roughness spacings of less than a micron are essential to sustain gases on surfaces submerged in water at atmospheric pressure. This is consistent with prior empirical data.

  5. Radionuclide Air Emission Report for 2007

    SciTech Connect (OSTI)

    Wahl, Linnea; Wahl, Linnea

    2008-06-13T23:59:59.000Z

    Berkeley Lab operates facilities where radionuclides are handled and stored. These facilities are subject to the U.S. Environmental Protection Agency (EPA) radioactive air emission regulations in Code of Federal Regulations (CFR) Title 40, Part 61, Subpart H (EPA 1989). The EPA regulates radionuclide emissions that may be released from stacks or vents on buildings where radionuclide production or use is authorized or that may be emitted as diffuse sources. In 2007, all Berkeley Lab sources were minor stack or building emissions sources of radionuclides (sources resulting in a potential dose of less than 0.1 mrem/yr [0.001 mSv/yr]), there were no diffuse emissions, and there were no unplanned emissions. Emissions from minor sources either were measured by sampling or monitoring or were calculated based on quantities received for use or produced during the year. Using measured and calculated emissions, and building-specific and common parameters, Laboratory personnel applied the EPA-approved computer code, CAP88-PC, Version 3.0, to calculate the effective dose equivalent to the maximally exposed individual (MEI). The effective dose equivalent from all sources at Berkeley Lab in 2007 is 1.2 x 10{sup -2} mrem/yr (1.2 x 10{sup -4} mSv/yr) to the MEI, well below the 10 mrem/yr (0.1 mSv/yr) EPA dose standard. The location of the MEI is at the University of California (UC) Lawrence Hall of Science, a public science museum about 1500 ft (460 m) east of Berkeley Lab's Building 56. The estimated collective effective dose equivalent to persons living within 50 mi (80 km) of Berkeley Lab is 3.1 x 10{sup -1} person-rem (3.1 x 10{sup -3} person-Sv) attributable to the Lab's airborne emissions in 2007.

  6. Microscopic description of neutron emission rates in compound nuclei

    E-Print Network [OSTI]

    Yi Zhu; Junchen Pei

    2014-11-02T23:59:59.000Z

    The neutron emission rates in thermal excited nuclei are conventionally described by statistical models with a phenomenological level density parameter that depends on excitation energies, deformations and mass regions. In the microscopic view of hot nuclei, the neutron emission rates can be determined by the external neutron gas densities without any free parameters. Therefore the microscopic description of thermal neutron emissions is desirable that can impact several understandings such as survival probabilities of superheavy compound nuclei and neutron emissivity in reactors. To describe the neutron emission rates microscopically, the external thermal neutron gases are self-consistently obtained based on the Finite-Temperature Hartree-Fock-Bogoliubov (FT-HFB) approach. The results are compared with the statistical model to explore the connections between the FT-HFB approach and the statistical model. The Skyrme FT-HFB equation is solved by HFB-AX in deformed coordinate spaces. Based on the FT-HFB approach, the thermal properties and external neutron gas are properly described with the self-consistent gas substraction procedure. Then neutron emission rates can be obtained based on the densities of external neutron gases. The thermal statistical properties of $^{238}$U and $^{258}$U are studied in detail in terms of excitation energies. The thermal neutron emission rates in $^{238, 258}$U and superheavy compound nuclei $_{112}^{278}$Cn and $_{114}^{292}$Fl are calculated, which agree well with the statistical model by adopting an excitation-energy-dependent level density parameter. The coordinate-space FT-HFB approach can provide reliable microscopic descriptions of neutron emission rates in hot nuclei, as well as microscopic constraints on the excitation energy dependence of level density parameters for statistical models.

  7. Stock prices and the cost of environmental regulation

    E-Print Network [OSTI]

    Linn, Joshua

    2006-01-01T23:59:59.000Z

    Recent environmental regulations have used market incentives to reduce compliance costs and improve efficiency. In most cases, the Environmental Protection Agency (EPA) selects an emissions cap using the predicted costs ...

  8. automotive exhaust gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the environment and legislation introduced to reduce greenhouse gas emissions and improve resource efficiency, eco product design and manufacturing strategies have to be developed...

  9. Air Quality: Air Pollutants, SLAC Emissions Sources, and Regulatory Reference

    E-Print Network [OSTI]

    Wechsler, Risa H.

    Air Quality: Air Pollutants, SLAC Emissions Sources, and Regulatory Reference Department: Chemical and General Safety Program: Air Quality Owner: Program Manager Authority: ES&H Manual, Chapter 30, Air Quality1 SLAC's air emissions are regulated through a federally mandated site-wide permit as well

  10. Emissions Reductions as a Result of Automobile Improvement

    E-Print Network [OSTI]

    Denver, University of

    continually less polluting independent of measurement location. Improving emissions control technology spurred by federal regulations is thought to have brought about these trends. Introduction The U.S. Environmental Protection Agency (EPA) estimates on-road motor vehicle emissions to be the single largest contributor

  11. Charge regulation circuit

    DOE Patents [OSTI]

    Ball, Don G. (Livermore, CA)

    1992-01-01T23:59:59.000Z

    A charge regulation circuit provides regulation of an unregulated voltage supply in the range of 0.01%. The charge regulation circuit is utilized in a preferred embodiment in providing regulated voltage for controlling the operation of a laser.

  12. Driving Down Diesel Emissions

    E-Print Network [OSTI]

    Harley, Robert

    2013-01-01T23:59:59.000Z

    Turnover on Drayage Truck Emissions at the Port of Oakland,”actions to clean up port truck emissions in Oakland serve asTurnover on Drayage Truck Emissions at the Port of Oakland,”

  13. Characterization of Fine Particulate Matter (PM) and Secondary PM Precursor Gases in Mexico City

    SciTech Connect (OSTI)

    Dr. Charles E. Kolb

    2008-03-31T23:59:59.000Z

    This project was one of three collaborating grants designed to understand the atmospheric chemistry and aerosol particle microphysics impacting air quality in the Mexico City Metropolitan Area (MCMA) and its urban plume. The overall effort, titled MCMA- 2006, focused on: 1) the primary emissions of fine particles and precursor gases leading to photochemical production of atmospheric oxidants and secondary aerosol particles and 2) the measurement and analysis of secondary oxidants and secondary fine particular matter (PM) production, with particular emphasis on secondary organic aerosol (SOA). MCAM-2006 pursued it goals through three main activities: 1) performance and publication of detailed analyses of extensive MCMA trace gas and fine PM measurements made by the collaborating groups and others during earlier MCMA field campaigns in 2002 and 2003; 2) deployment and utilization of extensive real-time trace gas and fine PM instrumentation at urban and downwind MCMA sites in support of the MAX-Mex/MILAGRO field measurements in March, 2006; and, 3) analyses of the 2006 MCMA data sets leading to further publications that are based on new data as well as insights from analysis and publication of the 2002/2003 field data. Thirteen archival publications were coauthored with other MCMA-2003 participants. Documented findings included a significantly improved speciated emissions inventory from on-road vehicles, a greatly enhanced understanding of the sources and atmospheric loadings of volatile organic compounds, a unique analysis of the high fraction of ambient formaldehyde from primary emission sources, a much more extensive knowledge of the composition, size distributions and atmospheric mass loadings of both primary and secondary fine PM, including the fact that the rate of MCMA SOA production greatly exceeded that predicted by current atmospheric models, and evaluations of significant errors that can arise from standard air quality monitors for ozone and nitrogen dioxide. Deployment of the Aerodyne mobile laboratory, equipped with instruments from five collaborating laboratories, at the T0 urban supersite, four downwind sites and the Tula industrial area yielded unique trace gas and fine PM data sets during the March 2006 MAXMex/MILAGRO campaign. In addition, on-road measurements as the mobile laboratory moved between sites provided extensive data on 2006 MCMA fleet averaged vehicle emissions. Analyses of 2006 data sets have yielded the identification of a close correlation between the rate of production of SOA and “Odd Oxygen” (O3 + NO2) and primary organic PM with CO in the MCMA urban plume, a more sophisticated understanding of the interplay between nitrogen oxide speciation and ozone production, the identification of significant vehicular emission sources of HCN and CH3CN (usually associated with biomass burning), characterization of the aging of primary carbonaceous PM, and updated 2006 MCMA fleet on-road trace gas and fine PM emissions. Results from analyses of 2002/2003 and 2006 emissions and ambient measurements have conveyed to Mexican air quality managers who are using these data to devise and assess air quality management strategies. All data sets and published analyses are available to DOE/ASP researchers evaluating the impact of urban emissions on regional climate.

  14. Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases

    SciTech Connect (OSTI)

    Carlsbad Field Office

    2007-11-13T23:59:59.000Z

    The Performance Demonstration Program (PDP) for headspace gases distributes blind audit samples in a gas matrix for analysis of volatile organic compounds (VOCs). Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facility’s compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.

  15. Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases

    SciTech Connect (OSTI)

    Carlsbad Field Office

    2007-11-19T23:59:59.000Z

    The Performance Demonstration Program (PDP) for headspace gases distributes blind audit samples in a gas matrix for analysis of volatile organic compounds (VOCs). Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facility’s compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.

  16. Direct conversion of light hydrocarbon gases to liquid fuel

    SciTech Connect (OSTI)

    Kaplan, R.D.; Foral, M.J.

    1992-05-16T23:59:59.000Z

    Amoco oil Company, has investigated the direct, non-catalytic conversion of light hydrocarbon gases to liquid fuels (particularly methanol) via partial oxidation. The primary hydrocarbon feed used in these studies was natural gas. This report describes work completed in the course of our two-year project. In general we determined that the methanol yields delivered by this system were not high enough to make it economically attractive. Process variables studied included hydrocarbon feed composition, oxygen concentration, temperature and pressure effects, residence time, reactor design, and reactor recycle.

  17. Prospecting by sampling and analysis of airborne particulates and gases

    DOE Patents [OSTI]

    Sehmel, G.A.

    1984-05-01T23:59:59.000Z

    A method is claimed for prospecting by sampling airborne particulates or gases at a ground position and recording wind direction values at the time of sampling. The samples are subsequently analyzed to determine the concentrations of a desired material or the ratios of the desired material to other identifiable materials in the collected samples. By comparing the measured concentrations or ratios to expected background data in the vicinity sampled, one can select recorded wind directions indicative of the upwind position of the land-based source of the desired material.

  18. Two-phase compressibility factors for retrograde gases 

    E-Print Network [OSTI]

    Rayes, Daniel George

    1989-01-01T23:59:59.000Z

    . K. , M Cain, W. D. , Jr. and Jennings, J. W. : "An Improved Method for the Determination of the Reservoir Specific Gravity for Retrograde Gases, " JPT (July 1989) 747-752. 7. Craft, B. C. and Hawkins, M. F. : A li P 1 m R rv ir En ine rin...). Variable Mean Standard Deviation Minimum Maximum H2S CO2 N2 CI C2 C3 IC4 NC4 IC5 NC5 C6 C7+ M. W. C7+ S. G. C7+ 1, 01840 0. 00997 0. 02545 0. 01840 0. 73233 0. 07584 0. 03948 0. 00859 0. 01482 0. 00611 0. 00637 0. 00857 0. 05404...

  19. Separation of gases through gas enrichment membrane composites

    DOE Patents [OSTI]

    Swedo, R.J.; Kurek, P.R.

    1988-07-19T23:59:59.000Z

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  20. Separation of gases through gas enrichment membrane composites

    DOE Patents [OSTI]

    Swedo, Raymond J. (Mt. Prospect, IL); Kurek, Paul R. (Schaumburg, IL)

    1988-01-01T23:59:59.000Z

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  1. EIA-Voluntary Reporting of Greenhouse Gases Program

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells, Wisconsin:DeploymentSite Name: Email: Terminal2,7,7,of Greenhouse Gases

  2. Modelling regulations Completing an incomplete regulation

    E-Print Network [OSTI]

    van der Torre, Leon

    Objectives Modelling regulations Completing an incomplete regulation Examples Discussion Consistency and Completeness of Regulations Laurence Cholvy1 St´ephanie Roussel1,2 1ONERA Centre de Toulouse 2ISAE, Toulouse NorMAS 2008, Luxembourg, July 2008 cholvy Consistency and Completeness of Regulations

  3. Managing CO{sub 2} emissions in Nigeria

    SciTech Connect (OSTI)

    Obioh, I.B.; Oluwole, A.F.; Akeredolu, F.A. [Obafemi Awolowo Univ., Ile-Ife (Nigeria)

    1994-12-31T23:59:59.000Z

    The energy resources in Nigeria are nearly equally divided between fossil fuels and biofuels. The increasing pressure on them, following expected increased population growth, may lead to substantial emissions of carbon into the atmosphere. Additionally agricultural and forestry management practices in vogue are those related to savannah burning and rotational bush fallow systems, which have been clearly implicated as important sources of CO{sub 2} and trace gases. An integrated model for the prediction of future CO{sub 2} emissions based on fossil fuels and biomass fuels requirements, rates of deforestation and other land-use indices is presented. This is further based on trends in population and economic growth up to the year 2025, with a base year in 1988. A coupled carbon cycle-climate model based on the contribution of CO{sub 2} and other trace gases is established from the proportions of integrated global warming effects for a 20-year averaging time using the product of global warming potential (GWP) and total emissions. An energy-technology inventory approach to optimal resources management is used as a tool for establishing the future scope of reducing the CO{sub 2} emissions through improved fossil fuel energy efficiencies. Scenarios for reduction based on gradual to swift shifts from biomass to fossil and renewable fuels are presented together with expected policy options required to effect them.

  4. Instantaneous and efficient surface wave excitation of a low pressure gas or gases

    DOE Patents [OSTI]

    Levy, Donald J. (Berkeley, CA); Berman, Samuel M. (San Francisco, CA)

    1988-01-01T23:59:59.000Z

    A system for instantaneously ionizing and continuously delivering energy in the form of surface waves to a low pressure gas or mixture of low pressure gases, comprising a source of rf energy, a discharge container, (such as a fluorescent lamp discharge tube), an rf shield, and a coupling device responsive to rf energy from the source to couple rf energy directly and efficiently to the gas or mixture of gases to ionize at least a portion of the gas or gases and to provide energy to the gas or gases in the form of surface waves. The majority of the rf power is transferred to the gas or gases near the inner surface of the discharge container to efficiently transfer rf energy as excitation energy for at least one of the gases. The most important use of the invention is to provide more efficient fluorescent and/or ultraviolet lamps.

  5. Continuous Emissions Monitoring System Monitoring Plan for the Y-12 Steam Plant

    SciTech Connect (OSTI)

    None

    2003-02-28T23:59:59.000Z

    The Oak Ridge Y-12 National Security Complex (Y-12), managed by BWXT, is submitting this Continuous Emissions Monitoring System (CEMS) Monitoring Plan in conformance with the requirements of Title 40 of the U.S. Code of Federal Regulations (CFR) Part 75. The state of Tennessee identified the Y-12 Steam Plant in Oak Ridge, Tennessee, as a non-electrical generation unit (EGU) nitrogen oxides (NO{sub x}) budget source as a result of the NO{sub x} State Implementation Plan (SIP) under the Tennessee Department of Environment and Conservation (TDEC) Rule 1200-3-27. Following this introduction, the monitoring plan contains the following sections: CEMS details, NO{sub x} emissions, and quality assurance (QA)/quality control (QC). The following information is included in the attachments: fuel and flue gas diagram, system layout, data flow diagrams, Electronic Monitoring Plan printouts, vendor information on coal and natural gas feed systems, and the Certification Test Protocol. The Y-12 Steam Plant consists of four Wickes boilers. Each is rated at a maximum heat input capacity of 296.8 MMBtu/hour or 250,000 lb/hour of 250-psig steam. Although pulverized coal is the principal fuel, each of the units can fire natural gas or a combination of coal and gas. Each unit is equipped with a Joy Manufacturing Company reverse air baghouse to control particulate emissions. Flue gases travel out of the baghouse, through an induced draft fan, then to one of two stacks. Boilers 1 and 2 exhaust through Stack 1. Boilers 3 and 4 exhaust through Stack 2. A dedicated CEMS will be installed in the ductwork of each boiler, downstream of the baghouse. The CEMS will be designed, built, installed, and started up by URS Group, Inc. (URS). Data acquisition and handling will be accomplished using a data acquisition and handling system (DAHS) designed, built, and programmed by Environmental Systems Corporation (ESC). The installed CEMS will continuously monitor NO{sub x}, flue gas flowrate, and carbon dioxide (CO{sub 2}). The CEMS will be utilized to report emissions from each unit for each ozone season starting May 1, 2003. Each boiler has independent coal and natural gas metering systems. Coal is fed to each boiler by belt-type coal feeders. Each boiler has two dedicated coal feeders. Natural gas may be burned along with coal for flame stability. The boilers may also be fired on natural gas alone. Orifice meters measure the natural gas flow to each boiler.

  6. Process for recovery of sulfur from acid gases

    DOE Patents [OSTI]

    Towler, Gavin P. (Kirkbymoorside, GB2); Lynn, Scott (Pleasant Hill, CA)

    1995-01-01T23:59:59.000Z

    Elemental sulfur is recovered from the H.sub.2 S present in gases derived from fossil fuels by heating the H.sub.2 S with CO.sub.2 in a high-temperature reactor in the presence of a catalyst selected as one which enhances the thermal dissociation of H.sub.2 S to H.sub.2 and S.sub.2. The equilibrium of the thermal decomposition of H.sub.2 S is shifted by the equilibration of the water-gas-shift reaction so as to favor elemental sulfur formation. The primary products of the overall reaction are S.sub.2, CO, H.sub.2 and H.sub.2 O. Small amounts of COS, SO.sub.2 and CS.sub.2 may also form. Rapid quenching of the reaction mixture results in a substantial increase in the efficiency of the conversion of H.sub.2 S to elemental sulfur. Plant economy is further advanced by treating the product gases to remove byproduct carbonyl sulfide by hydrolysis, which converts the COS back to CO.sub.2 and H.sub.2 S. Unreacted CO.sub.2 and H.sub.2 S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H.sub.2 and CO, which has value either as a fuel or as a chemical feedstock and recovers the hydrogen value from the H.sub.2 S.

  7. Self-pulsing of hollow cathode discharge in various gases

    SciTech Connect (OSTI)

    Qin, Y.; He, F., E-mail: hefeng@bit.edu.cn; Jiang, X. X.; Ouyang, J. T., E-mail: jtouyang@bit.edu.cn [School of Physics, Beijing Institute of Technology, Beijing 100081 (China); Xie, K. [School of Aerospace Engineering, Beijing Institute of Technology, Beijing 100081 (China)

    2014-07-15T23:59:59.000Z

    In this paper, we investigate the self-pulsing phenomenon of cavity discharge in a cylindrical hollow cathode in various gases including argon, helium, nitrogen, oxygen, and air. The current-voltage characteristics of the cavity discharge, the waveforms of the self-pulsing current and voltage as well as the repetition frequency were measured. The results show that the pulsing frequency ranges from a few to tens kilohertz and depends on the averaged current and the pressure in all gases. The pulsing frequency will increase with the averaged current and decrease with the pressure. The rising time of the current pulse is nearly constant in a given gas or mixture. The self-pulsing does not depend on the external ballast but is affected significantly by the external capacitor in parallel with the discharge cell. The low-current self-pulsing in hollow cathode discharge is the mode transition between Townsend and glow discharges. It can be described by the charging-discharging process of an equivalent circuit consisting of capacitors and resistors.

  8. Dark resonances for ground state transfer of molecular quantum gases

    E-Print Network [OSTI]

    Manfred J. Mark; Johann G. Danzl; Elmar Haller; Mattias Gustavsson; Nadia Bouloufa; Olivier Dulieu; Houssam Salami; Tom Bergeman; Helmut Ritsch; Russell Hart; Hanns-Christoph Nägerl

    2008-11-05T23:59:59.000Z

    One possible way to produce ultracold, high-phase-space-density quantum gases of molecules in the rovibronic ground state is given by molecule association from quantum-degenerate atomic gases on a Feshbach resonance and subsequent coherent optical multi-photon transfer into the rovibronic ground state. In ultracold samples of Cs_2 molecules, we observe two-photon dark resonances that connect the intermediate rovibrational level |v=73,J=2> with the rovibrational ground state |v=0,J=0> of the singlet $X^1\\Sigma_g^+$ ground state potential. For precise dark resonance spectroscopy we exploit the fact that it is possible to efficiently populate the level |v=73,J=2> by two-photon transfer from the dissociation threshold with the stimulated Raman adiabatic passage (STIRAP) technique. We find that at least one of the two-photon resonances is sufficiently strong to allow future implementation of coherent STIRAP transfer of a molecular quantum gas to the rovibrational ground state |v=0,J=0>.

  9. Glass science tutorial: Lecture No. 4, commercial glass melting and associated air emission issues

    SciTech Connect (OSTI)

    Kruger, A.A.

    1995-01-01T23:59:59.000Z

    This document serves as a manual for a workshop on commercial glass melting and associated air emission issues. Areas covered include: An overview of the glass industry; Furnace design and construction practices; Melting furnace operation; Energy input methods and controls; Air legislation and regulations; Soda lime emission mechanisms; and, Post furnace emission controls. Supporting papers are also included.

  10. The Effects of Climate and Electricity Emissions on Air Quality in the United States

    E-Print Network [OSTI]

    Wisconsin at Madison, University of

    , and both are regulated under the U.S. Clean Air Act. While emissions from fossil fuel combustion suggests that air quality co-benefits associated with CO2 emission reductions could be significantThe Effects of Climate and Electricity Emissions on Air Quality in the United States by Steven D

  11. Emissions of Transport Refrigeration Units with CARB Diesel, Gas-to-Liquid Diesel, and Emissions Control Devices

    SciTech Connect (OSTI)

    Barnitt, R. A.; Chernich, D.; Burnitzki, M.; Oshinuga, A.; Miyasato, M.; Lucht, E.; van der Merwe, D.; Schaberg, P.

    2010-05-01T23:59:59.000Z

    A novel in situ method was used to measure emissions and fuel consumption of transport refrigeration units (TRUs). The test matrix included two fuels, two exhaust configurations, and two TRU engine operating speeds. Test fuels were California ultra low sulfur diesel and gas-to-liquid (GTL) diesel. Exhaust configurations were a stock muffler and a Thermo King pDPF diesel particulate filter. The TRU engine operating speeds were high and low, controlled by the TRU user interface. Results indicate that GTL diesel fuel reduces all regulated emissions at high and low engine speeds. Application of a Thermo King pDPF reduced regulated emissions, sometimes almost entirely. The application of both GTL diesel and a Thermo King pDPF reduced regulated emissions at high engine speed, but showed an increase in oxides of nitrogen at low engine speed.

  12. Multiwavelength Thermal Emission

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    Multiwavelength Astronomy NASA #12;Thermal Emission #12;Thermal Emission Non-thermal p-p collisions Optical IR Radio/ Microwave sources of emission massive stars, WHIM, Ly many dust, cool objects-ray ~GeV Gamma-ray ~TeV sources of emission AGN, clusters, SNR, binaries, stars AGN (obscured), shocks

  13. Sensitivity of Multi-gas Climate Policy to Emission Metrics

    SciTech Connect (OSTI)

    Smith, Steven J.; Karas, Joseph F.; Edmonds, James A.; Eom, Jiyong; Mizrahi, Andrew H.

    2013-04-01T23:59:59.000Z

    Multi-gas greenhouse emission targets require that different emissions be combined into an aggregate total. The Global Warming Potential (GWP) index is currently used for this purpose, despite various criticisms of the underlying concept. It is not possible to uniquely define a single metric that perfectly captures the different impacts of emissions of substances with widely disparate atmospheric lifetimes, which leads to a wide range of possible index values. We examine the sensitivity of emissions and climate outcomes to the value of the index used to aggregate methane emissions using a technologically detailed integrated assessment model. We find that the sensitivity to index value is of order 4-14% in terms of methane emissions and 2% in terms of total radiative forcing, using index values between 4 and 70 for methane, with larger regional differences in some cases. The sensitivity to index value is much higher in economic terms, with total 2-gas mitigation cost decreasing 4-5% for a lower index and increasing 10-13% for a larger index, with even larger changes if the emissions reduction targets are small. The sensitivity to index value also depends on the assumed maximum amount of mitigation available in each sector. Evaluation of the maximum mitigation potential for major sources of non-CO2 greenhouse gases would greatly aid analysis

  14. The sources of emission reductions : evidence from U.S. SO? emissions from 1985-2002

    E-Print Network [OSTI]

    Ellerman, A. Denny

    2004-01-01T23:59:59.000Z

    An enduring issue in environmental regulation is whether to clean up existing "old" plants or in some manner to bring in new ?clean? plants to replace the old. In this paper, a unit-level data base of emissions by nearly ...

  15. State environmental law and carbon emissions: Do public utility commissions use environmental statutes to fight global warming?

    SciTech Connect (OSTI)

    Sautter, John A.

    2010-10-15T23:59:59.000Z

    In many states environmental statutes provide the authority for public utility commissioners to make decisions to reduce greenhouse gases from electricity generation. This article looks at six such laws and how the presence of these laws affected CO{sub 2} emissions during a nine-year period from 1997 to 2005. (author)

  16. Loschmidt echo in one-dimensional interacting Bose gases

    SciTech Connect (OSTI)

    Lelas, K.; Seva, T.; Buljan, H. [Faculty of Electrical Engineering Mechanical Engineering and Naval Architecture, University of Split, Rudjera Boskovica BB, 21000 Split (Croatia); Department of Physics, University of Zagreb, Bijenicka c. 32, 10000 Zagreb (Croatia)

    2011-12-15T23:59:59.000Z

    We explore Loschmidt echo in two regimes of one-dimensional interacting Bose gases: the strongly interacting Tonks-Girardeau (TG) regime, and the weakly interacting mean-field regime. We find that the Loschmidt echo of a TG gas decays as a Gaussian when small (random and time independent) perturbations are added to the Hamiltonian. The exponent is proportional to the number of particles and the magnitude of a small perturbation squared. In the mean-field regime the Loschmidt echo shows richer behavior: it decays faster for larger nonlinearity, and the decay becomes more abrupt as the nonlinearity increases; it can be very sensitive to the particular realization of the noise potential, especially for relatively small nonlinearities.

  17. Photolysis of water for production of fuel gases

    SciTech Connect (OSTI)

    Eror, N.G.; Blakemore, J.S.

    1981-12-01T23:59:59.000Z

    To better understand the role of the semiconductor electrode in the photocatalytic decomposition of water to form hydrogen and other fuel gases, researchers characterized the defect structure of a number of large-band-gap semiconductor electrode materials. The defect structure of SrTiO/sub 3/ samples has been related to photoelectrochemical cell response, leading to a signficant improvement in the understanding of how electrode properties influence cell performance. Although the large band gap of these materials severely restricts their ability to use the solar spectrum, they are more resistant to photocorrosion than lower-band-gap materials. This band gap has been reduced somewhat in lanthanum-doped SrTiO/sub 3/ samples without compromising photostability or requiring a bias voltage for water decomposition.

  18. Finite-size energy of non-interacting Fermi gases

    E-Print Network [OSTI]

    Martin Gebert

    2014-06-14T23:59:59.000Z

    We prove the asymptotics of the difference of the ground-state energies of two non-interacting $N$-particle Fermi gases on the half line of length $L$ in the thermodynamic limit up to order $1/L$. We are particularly interested in subdominant terms proportional to $1/L$, called finite-size energy. In the nineties Affleck and co-authors [Aff97, ZA97, AL94] claimed that the finite-size energy equals the decay exponent occuring in Anderson's orthogonality catastrophe. It turns out that the finite-size energy depends on the details of the thermodynamic limit and typically also includes a linear term in the scattering phase shift.

  19. Free Energies of Dilute Bose gases: upper bound

    E-Print Network [OSTI]

    Jun Yin

    2010-12-19T23:59:59.000Z

    We derive a upper bound on the free energy of a Bose gas system at density $\\rho$ and temperature $T$. In combination with the lower bound derived previously by Seiringer \\cite{RS1}, our result proves that in the low density limit, i.e., when $a^3\\rho\\ll 1$, where $a$ denotes the scattering length of the pair-interaction potential, the leading term of $\\Delta f$ the free energy difference per volume between interacting and ideal Bose gases is equal to $4\\pi a (2\\rho^2-[\\rho-\\rhoc]^2_+)$. Here, $\\rhoc(T)$ denotes the critical density for Bose-Einstein condensation (for the ideal gas), and $[\\cdot ]_+$ $=$ $\\max\\{\\cdot, 0\\}$ denotes the positive part.

  20. Elliptic flow and nearly perfect fluidity in dilute Fermi gases

    E-Print Network [OSTI]

    Thomas Schaefer

    2010-12-16T23:59:59.000Z

    In this contribution we summarize recent progress in understanding the shear viscosity of strongly correlated dilute Fermi gases. We discuss predictions from kinetic theory, and show how these predictions can be tested using recent experimental data on elliptic flow. We find agreement between theory and experiments in the high temperature regime $T\\gg T_F$, where $T_F$ is the the temperature where quantum degeneracy effects become important. In the low temperature regime, $T\\sim T_F$, the strongest constraints on the shear viscosity come from experimental studies of the damping of collective modes. These experiments indicate that $\\eta/s\\lsim 0.5\\hbar/k_B$, where $\\eta$ is the shear viscosity and $s$ is the entropy density.

  1. Light pulse in {Lambda}-type cold-atom gases

    SciTech Connect (OSTI)

    Wei Ran; Deng Youjin; Chen Shuai; Chen Zengbing; Pan Jianwei [Hefei National Laboratory for Physical Sciences at Microscale and Department of Modern Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); Zhao Bo [Institute for Theoretical physics, University of Innsbruck, A-6020 Innsbruck (Austria); Institute for Quantum Optics and Quantum Information of the Austrian Academy of Science, A-6020 Innsbruck (Austria)

    2010-04-15T23:59:59.000Z

    We investigate the behavior of the light pulse in {Lambda}-type cold-atom gases with two counter-propagating control lights with equal strength by directly simulating the dynamic equations and exploring the dispersion relation. Our analysis shows that, depending on the length L{sub 0} of the stored wave packet and the decay rate {gamma} of ground-spin coherence, the recreated light can behave differently. For long L{sub 0} and/or large {gamma}, a stationary light pulse is produced, while two propagating light pulses appear for short L{sub 0} and/or small {gamma}. In the {gamma}{yields}0 limit, the light always splits into two propagating pulses for a sufficiently long time. This scenario agrees with a recent experiment [Y.-W. Lin et al., Phys. Rev. Lett. 102, 213601 (2009)] where two propagating light pulses are generated in laser-cooled cold-atom ensembles.

  2. Fuel cell stack with internal manifolds for reactant gases

    DOE Patents [OSTI]

    Schnacke, Arthur W. (Schenectady, NY)

    1985-01-01T23:59:59.000Z

    A fuel cell stack includes a plurality of plate-like fuel cells arranged along an axis generally parallel to cell thickness with electrically conductive separator plates between each pair of cells. A plurality of axial manifolds are provided at opposite sides of the stack in outer marginal portions beyond the edges of electrodes and electrolyte tiles. Sealing rings prevent cross-leakage of oxidant fuel gases through use of pairs of outwardly extending lips from opposite tile surfaces bonded to first and second electrode frames respectively. The frames provide transition between electrode edges and manifold perimeters. The pairs of extension lips are sealingly bonded together through an electrically insulative sealing ring with wedge shaped fastening members.

  3. Fuel cell stack with internal manifolds for reactant gases

    DOE Patents [OSTI]

    Schnacke, A.W.

    1983-10-12T23:59:59.000Z

    A fuel cell stack includes a plurality of plate-like fuel cells arranged along an axis generally parallel to cell thickness with electrically conductive separator plates between each pair of cells. A plurality of axial manifolds are provided at opposite sides of the stack in outer marginal portions beyond the edges of electrodes and electrolyte tiles. Sealing rings prevent cross-leakage of oxidant fuel gases through use of pairs of outwardly extending lips from opposite tile surfaces bonded to first and second electrode frames respectively. The frames provide transition between electrode edges and manifold perimeters. The pairs of extension lips are sealingly bonded together through an electrically insulative sealing ring with wedge shaped fastening members.

  4. California Energy Commission REGULATIONS

    E-Print Network [OSTI]

    California Energy Commission REGULATIONS FINAL STATEMENT OF REASONS ENFORCEMENT PROCEDURES by Government Code section 11346.9(a) for the California Energy Commission (Energy Commission) regulations 399.30 (l) directs the Energy Commission to adopt regulations specifying procedures

  5. California Energy Commission REGULATIONS

    E-Print Network [OSTI]

    California Energy Commission REGULATIONS NONRESIDENTIAL BUILDING ENERGY Disclosure Program California Code of Regulations Title 20. Public Utilities and Energy Division 2. State USE DISCLOSURE PROGRAM California Code of Regulations, Title 20, Division 2

  6. Title of Dissertation: HIGH POWER NONLINEAR PROPAGATION OF LASER PULSES IN TENUOUS GASES

    E-Print Network [OSTI]

    Anlage, Steven

    ABSTRACT Title of Dissertation: HIGH POWER NONLINEAR PROPAGATION OF LASER PULSES IN TENUOUS GASES AND PLASMA CHANNELS Jianzhou Wu, Doctor of Philosophy, 2005 Dissertation Directed By: Professor Thomas M PROPAGATION OF LASER PULSES IN TENUOUS GASES AND PLASMA CHANNELS By Jianzhou Wu Dissertation submitted

  7. Monte Carlo Simulation of Radiation in Gases with a NarrowBand Model

    E-Print Network [OSTI]

    Dufresne, Jean-Louis

    , France (\\Phi) now at the Institute of Energy and Power Plant Technology, TH Darmstadt, 64287 DarmstadtMonte Carlo Simulation of Radiation in Gases with a Narrow­Band Model and a Net is used for simulation of radiative heat transfers in non­gray gases. The proposed procedure is based

  8. Abstract--Airborne pollution and explosive gases threaten human health and occupational safety, therefore generating high

    E-Print Network [OSTI]

    Mason, Andrew

    Abstract--Airborne pollution and explosive gases threaten human health and occupational safety and a thumb-drive sized prototype system. I. INTRODUCTION xposure to air pollution consistently ranks among to occupational safety as energy demands rise. Airborne pollutants and explosive gases vary in both time and space

  9. Permeation of Gases in Polymers: Parameter Identification and Nonlinear Regression Analysis

    E-Print Network [OSTI]

    Scheichl, Robert

    Permeation of Gases in Polymers: Parameter Identification and Nonlinear Regression Analysis Robert at PARAOPE, Heidelberg, June 30th, 2004 #12;Overview · Permeation of gases in polymers ­ Application areas for diffusion in polymers ­ Description of the experimental device ­ Mathematical model · Parameter

  10. Heavy noble gases in solar wind delivered by Genesis mission Alex Meshik a,

    E-Print Network [OSTI]

    measured in the Genesis solar wind collectors generally agree with the less precise values obtained fromHeavy noble gases in solar wind delivered by Genesis mission Alex Meshik a, , Charles Hohenberg knowledge of the isotopic composition of the heavy noble gases in solar wind and, by inference, the Sun

  11. Preserving noble gases in a convecting mantle Helge M. Gonnermann1

    E-Print Network [OSTI]

    Mukhopadhyay, Sujoy

    of a processed and out- gassed lower-mantle source, residues of mantle melting10,11 , depleted in uranium and mixing of noble-gas-depleted slabs dilutes the concentrations of noble gases in the mantle, thereby melt, which forms the ocean crust and leaves the residual mantle severely depleted of noble gases

  12. Bose-Einstein condensates in 85 Rb gases at higher densities

    E-Print Network [OSTI]

    Glyde, Henry R.

    Bose-Einstein condensates in 85 Rb gases at higher densities A. R. Sakhel, J. L. DuBois, and H. R August 2002; published 31 December 2002 The Bose-Einstein condensation in trapped gases of 85 Rb find that there is a significant depletion of the condensate at T 0 K, for example, 25% at na3 10 2

  13. Localization of Bogoliubov quasiparticles in interacting Bose gases with correlated disorder P. Lugan1,2

    E-Print Network [OSTI]

    Boyer, Edmond

    ) in a weakly interacting Bose gas of chemical potential µ subjected to a disordered potential V . We introduce-Einstein condensates [40­48], interacting Bose gases at equilibrium [26, 49­72], strongly interacting Fermi gases [73 behaviors can be found in various situa- tions. For instance, weak repulsive interactions in a Bose gas

  14. Polices for Controlling Groundwater Pollution from Concentrated Animal Feeding Operations

    E-Print Network [OSTI]

    Wang, Jingjing

    2012-01-01T23:59:59.000Z

    1.1.2.1 Water Pollution . . . . . . . . . . . . . . . . . .1.1.2.2 Air Pollution and Greenhouse Gases Emissions 1.1.3Regulating nonpoint source pollution under heterogeneous

  15. Microsoft Word - ANL-ESD-10-1_AErev.doc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    gases, Regulated Emissions, and Energy use in Transportation GT gas turbine GTMax Generation and Transmission Maximization GUI graphical user interface xiv GVW gross...

  16. Forest Road Building Regulations

    Broader source: Energy.gov [DOE]

    The Wisconsin Department of Natural Resources has regulations for building a forest road, if development requires one. Regulations include zoning ordinances and permits for stream crossing, grading...

  17. BP's Perspective on Emissions Purdue Emissions Trading Workshop

    E-Print Network [OSTI]

    BP's Perspective on Emissions Trading Purdue Emissions Trading Workshop April 30, 2010 Mark - Government policies can create a carbon price via three primary mechanisms: - Emissions trading (BP's strong

  18. Radionuclide Air Emission Report for 2008

    SciTech Connect (OSTI)

    Wahl, Linnea

    2009-05-21T23:59:59.000Z

    Berkeley Lab operates facilities where radionuclides are handled and stored. These facilities are subject to the U.S. Environmental Protection Agency (EPA) radioactive air emission regulations in Code of Federal Regulations (CFR) Title 40, Part 61, Subpart H (EPA 1989). Radionuclides may be emitted from stacks or vents on buildings where radionuclide production or use is authorized or they may be emitted as diffuse sources. In 2008, all Berkeley Lab sources were minor sources of radionuclides (sources resulting in a potential dose of less than 0.1 mrem/yr [0.001 mSv/yr]). These minor sources include more than 100 stack sources and one source of diffuse emissions. There were no unplanned emissions from the Berkeley Lab site. Emissions from minor sources (stacks and diffuse emissions) either were measured by sampling or monitoring or were calculated based on quantities used, received for use, or produced during the year. Using measured and calculated emissions, and building-specific and common parameters, Laboratory personnel applied the EPA-approved computer code, CAP88-PC, to calculate the effective dose equivalent to the maximally exposed individual (MEI). The effective dose equivalent from all sources at Berkeley Lab in 2008 is 5.2 x 10{sup -3} mrem/yr (5.2 x 10{sup -5} mSv/yr) to the MEI, well below the 10 mrem/yr (0.1 mSv/yr) dose standard. The location of the MEI is at the University of California (UC) Lawrence Hall of Science, a public science museum about 1500 ft (460 m) east of Berkeley Lab's Building 56. The estimated collective effective dose equivalent to persons living within 50 mi (80 km) of Berkeley Lab is 1.1 x 10{sup -1} person-rem (1.1 x 10{sup -3} person-Sv) attributable to the Lab's airborne emissions in 2008.

  19. Method of recovering sulfur from the hydrogen sulfide contained in coke oven gases

    SciTech Connect (OSTI)

    Laufhutte, D.

    1985-04-30T23:59:59.000Z

    Ammonia and hydrogen sulfide are washed out of the coke oven gas and stripped from the wash liquor in the form of gases and fumes or vapors. The ammonia is decomposed in a nickel catalyzer and a small part of the decomposition gases is supplied directly to a combustion furnace, while the larger part of the combustion gases is first cooled and freed from condensate, and only then supplied to the combustion furnace. In the combustion furnace, the proportion of H/sub 2/S/SO/sub 2/ needed for the Claus process is adjusted by a partial combustion of the decomposition gases. The gases from the combustion furnace are then processed in the Claus plant to sulfur.

  20. Radionuclide air emissions report for the Hanford site, Calendar year 1994

    SciTech Connect (OSTI)

    Gleckler, B.P.; Diediker, L.P. [Westinghouse Hanford Co., Richland, WA (United States); Jette, S.J.; Rhoads, K.; Soldat, S.K. [Pacific Northwest Lab., Richland, WA (United States)

    1995-06-01T23:59:59.000Z

    This report documents radionuclide air emissions from the Hanford Site in 1994, and the resulting effective dose equivalent to the maximally exposed member of the public, referred to as the ``MEI.`` The report has been prepared and will be submitted in accordance with reporting requirements in the Code of Federal Regulations, title 40, Protection of the Environment, Part 61, ``National Emissions Standards for Hazardous Air Pollutants,`` Subpart H, ``National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities.``

  1. Radionuclide air emissions report for the Hanford Site, calendar year 1992

    SciTech Connect (OSTI)

    Diediker, L.P.; Johnson, A.R. [Westinghouse Hanford Co., Richland, WA (United States); Rhoads, K.; Klages, D.L.; Soldat, J.K. [Pacific Northwest Lab., Richland, WA (United States); Rokkan, D.J. [Science Applications International Corp., Richland, WA (United States)

    1993-06-01T23:59:59.000Z

    This report documents radionuclide air emissions from the Hanford Site in 1992 and the resulting effective dose equivalent to an member of the public. The report has been prepared and will be submitted in accordance with reporting requirements in the Code of Federal Regulations, Title 40, Protection of the Environment, Part 61, ``National Emissions Standards for Hazardous Air Pollutants,`` Subpart H, ``National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities.``

  2. National Emission Standards for Hazardous Air Pollutants—Calendar Year 2010 INL Report for Radionuclides (2011)

    SciTech Connect (OSTI)

    Mark Verdoorn; Tom Haney

    2011-06-01T23:59:59.000Z

    This report documents the calendar Year 2010 radionuclide air emissions and resulting effective dose equivalent to the maximally exposed individual member of the public from operations at the Department of Energy's Idaho National Laboratory Site. This report was prepared in accordance with the Code of Federal Regulations, Title 40, 'Protection of the Environment,' Part 61, 'National Emission Standards for Hazardous Air Pollutants,' Subpart H, 'National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities.'

  3. Emissions Trading and Social Justice

    E-Print Network [OSTI]

    Farber, Daniel A

    2011-01-01T23:59:59.000Z

    David  M.  Driesen,  Does  Emissions  Trading  Encourage  Jason  Coburn,  Emissions  Trading   and   Environmental  Szambelan,  U.S.  Emissions  Trading  Markets  for  SO 2  

  4. Modeling of shippingModeling of shipping NONOxx emissions in globalemissions in global GeertGeert VinkenVinken11,, FolkertFolkert BoersmaBoersma22, and Daniel J. Jacob, and Daniel J. Jacob33

    E-Print Network [OSTI]

    Haak, Hein

    ) emissions 5-7% of global sulfur dioxide (SO2) emissions 3-4% of global carbon dioxide (CO2) emissions ShipModeling of shippingModeling of shipping NONOxx emissions in globalemissions in global CTMs 70% of the ship emissions occur within 400 km of land Only industrial sector not regulated under

  5. Feasibility of reconstructing paleoatmospheric records of selected alkanes, methyl halides, and sulfur gases from Greenland ice cores

    E-Print Network [OSTI]

    Aydin, M.; Williams, M. B; Saltzman, E. S

    2007-01-01T23:59:59.000Z

    firn and ice at Summit, Greenland, J. Geophys. Res. , 98,AL. : TRACE GASES IN GREENLAND ICE CORE ¨ . Andreae Kettle,and sulfur gases from Greenland ice cores M. Aydin, 1 M. B.

  6. How accurate are your reported emissions measurements?

    SciTech Connect (OSTI)

    Macak J.J. III [Mostardi Platt Environmental (United States)

    2006-09-15T23:59:59.000Z

    Complying with permitted emissions limits may be the most significant operations risk for a power plant. As limits are slowly ratcheted downward, understanding the accuracy and variation of measured pollutant levels becomes even more important. To avoid misunderstandings, regulators and plant owners should factor measurement uncertainty into air quality permit numbers both as the permit is formulated and preceding any subsequent modifications. 4 figs., 2 tabs.

  7. Satellite Measurements of Trace Gases or Air Pollutants

    E-Print Network [OSTI]

    Dickerson, Russell R.

    #12;ACTIVE VS. PASSIVE REMOTE SENSING Passive Remote Sensing: Natural sources of radiation-located with receiver #12;Thermal Emission Measurements (IR, microwave) EARTH SURFACE I(To) Absorbing gas, HIRDLS Pros: · versa4lity (many species) · small field of view (nadir) · ver4

  8. Characterization of lagoon gases by an electronic nose

    E-Print Network [OSTI]

    Woodcock, Jane Catherine

    1997-01-01T23:59:59.000Z

    in the decomposition of livestock wastes, the need for accurate and reliable devices for field monitoring of emissions exists. Studies were undertaken into the use of an array of chemical gas sensors for the detection and characterization of lagoon biogas. The sensors...

  9. UNIVERSITY STANDARDS AND REGULATIONS

    E-Print Network [OSTI]

    Royer, Dana

    2014­2015 UNIVERSITY STANDARDS AND REGULATIONS #12;Wesleyan University does not discriminate STANDARDS OF CONDUCT

  10. UNIVERSITY STANDARDS AND REGULATIONS

    E-Print Network [OSTI]

    Royer, Dana

    2013­2014 UNIVERSITY STANDARDS AND REGULATIONS #12;Wesleyan University does not discriminate STANDARDS OF CONDUCT

  11. Oxygen buffering of Kilauea volcanic gases and the oxygen fugacity of Kilauea basalt

    SciTech Connect (OSTI)

    Gerlach, T.M. (Geological Survey, Vancouver, WA (United States))

    1993-02-01T23:59:59.000Z

    Volcanic gases collected during episode 1 of the Puu Oo eruption along the east rift zone of Kilauea Volcano, Hawaii, have uniform C-O-H-S-Cl-F compositions that are sharply depleted in CO[sub 2]. The CO[sub 2]-poor gases are typical of Type II volcanic gases (GERLACH and GRAEBER, 1985) and were emitted from evolved magma stored for a prolonged period of time in the east rift zone after releasing CO[sub 2]-rich gases during an earlier period of temporary residence in the summit magma chamber. The samples are remarkably free of contamination by atmospheric gases and meteoric water. Thermodynamic evaluation of the analytical data shows that the episode 1 gases have equilibrium compositions appropriate for temperatures between 935 and 1032[degrees]C. Open- and closed-system equilibrium models of species distributions for the episode 1 gases show unequivocally that coexisting lavas buffered the gas oxygen fugacities during cooling. These models indicate that the F[sub o[sub 2

  12. Study Pinpoints Sources of Polluting Vehicle Emissions (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-03-01T23:59:59.000Z

    Unburned lubricant produces 60%-90% of organic carbon emissions. While diesel fuel is often viewed as the most polluting of conventional petroleum-based fuels, emissions from gasoline engines can more significantly degrade air quality. Gasoline exhaust is at least as toxic on a per-unit-mass basis as diesel exhaust, and contributes up to 10 times more particulate matter (PM) to the emission inventory. Because emissions from both fuels can gravely impact health and the environment, researchers at the National Renewable Energy Laboratory (NREL) launched a study to understand how these pollutants relate to fuels, lubricants, and engine operating conditions. NREL's Collaborative Lubricating Oil Study on Emissions (CLOSE) project tested a variety of vehicles over different drive cycles at moderate (72 F) and cold (20 F) temperatures. Testing included: (1) Normal and high-emitting light-, medium-, and heavy-duty vehicles; (2) Gasoline, diesel, and compressed natural gas (CNG)-powered vehicles; (3) New and aged lubricants representative of those currently on the market; and (4) Gasoline containing no ethanol, E10, Texas-mandated low-emission diesel fuel, biodiesel, and CNG. The study confirmed that normally functioning emission control systems for gasoline light-duty vehicles are very effective at controlling organic carbon (OC) emissions. Diesel vehicles without aftertreatment emission control systems exhibited OC emissions approximately one order of magnitude higher than gasoline vehicles. High-emitter gasoline vehicles produced OC emissions similar to diesel vehicles without exhaust aftertreatment emission control. Exhaust catalysts combusted or converted more than 75% of lubricating oil components in the exhaust gases. Unburned crankcase lubricant made up 60%-90% of OC emissions. This OC represented 20%-50% of emitted PM in all but two of the vehicles. Three-way catalysts proved effective at reducing most of the OC. With high PM emitters or vehicles with deteriorated aftertreatment, high-molecular-weight fuel components and unburned lubricant were emitted at higher rates than in vehicles in good repair, with functioning emissions systems. Light-duty gasoline, medium-duty diesel, and heavy-duty natural gas vehicles produced more particles with fresh oil than with aged oil. The opposite trend was observed in light- and medium-duty high PM emitters. This effect was not readily apparent with heavy-duty diesel vehicles, perhaps because the lubricant represented a much smaller fraction of the total PM in those trucks.

  13. Sequim Site Radionuclide Air Emissions Report for Calendar Year 2012

    SciTech Connect (OSTI)

    Snyder, Sandra F.; Barnett, J. M.; Gervais, Todd L.

    2013-04-01T23:59:59.000Z

    This report is prepared to document compliance with the Code of Federal Regulations (CFR), Title 40, Protection of the Environment, Part 61, National Emission Standards for Hazardous Air Pollutants (NESHAP), Subpart H, National Emission Standards for Emissions of Radionuclides Other than Radon from Department of Energy Facilities and ashington Administrative Code (WAC) Chapter 246-247, Radiation Protection Air Emissions. This report meets the calendar year 2012 Sequim Site annual reporting requirement for its operations as a privately-owned facility as well as its federally-contracted status that began in October 2012. Compliance is indicated by comparing the estimated dose to the maximally exposed individual (MEI) with the 10 mrem/yr Environmental Protection Agency (EPA) standard. The MSL contains only sources classified as fugitive emissions. Despite the fact that the regulations are intended for application to point source emissions, fugitive emissions are included with regard to complying with the EPA standard. The dose to the Sequim Site MEI due to routine operations in 2012 was 9E-06 mrem (9E-08 mSv). No non-routine emissions occurred in 2012. The MSL is in compliance with the federal and state 10 mrem/yr standard.

  14. Developing the model of laser ablation by considering the interplay between emission and expansion of aluminum plasma

    SciTech Connect (OSTI)

    Rezaei, F.; Tavassoli, S. H. [Laser and Plasma Research Institute, ShahidBeheshti University, 19396 4716, G. C., Evin, Tehran (Iran, Islamic Republic of)

    2013-01-15T23:59:59.000Z

    In the present study, the ablation behavior of aluminum target and its plasma radiation in noble ambient gases by a laser pulse with wavelength of 266 nm and pulse duration of 10 ns are numerically studied. A thermal model of laser ablation considering heat conduction, Euler equations, Saha-Eggert equations, Knudsen layer, mass and energy balance relations and optical shielding effects are used for calculation of plasma parameters. Effects of excitation energy on plasma expansion and its emissivity are investigated. Time and spatial-resolved plasma emission including bremsstrahlung, recombination and spectral emission at early delay times after laser irradiation is obtained. Effects of two ambient gases (He and Ar) as well as different gas pressures of 100, 300, 500, and 760 Torr on plasma expansion and its spectrum are studied. Results illustrate that at initial delay times, especially at high noble gas pressures, ionic lines have the maximum intensities, while at later times neutral lines dominate. When the pressure of ambient gas increases, a confinement of the plasma plume is predicted and the intensity of neutral lines decreases. Continuous emission increases with wavelength in both ambient gases. Spatially resolved analysis shows that an intense continuous emission is predicted next to the sample surface decreasing with distance from the latter.

  15. 2D Coulomb Gases and the Renormalized Energy

    E-Print Network [OSTI]

    Sandier, Etienne

    2012-01-01T23:59:59.000Z

    We study the statistical mechanics of classical two-dimensional "Coulomb gases" with general potential and arbitrary \\beta, the inverse of the temperature. Such ensembles also correspond to random matrix models in some particular cases. The formal limit case \\beta=\\infty corresponds to "weighted Fekete sets" and also falls within our analysis. It is known that in such a system points should be asymptotically distributed according to a macroscopic "equilibrium measure," and that a large deviations principle holds for this, as proven by Ben Arous and Zeitouni. By a suitable splitting of the Hamiltonian, we connect the problem to the "renormalized energy" W, a Coulombian interaction for points in the plane introduced in our prior work, which is expected to be a good way of measuring the disorder of an infinite configuration of points in the plane. By so doing, we are able to examine the situation at the microscopic scale, and obtain several new results: a next order asymptotic expansion of the partition function...

  16. Noble gases in the howardites Bholghati and Kapoeta

    SciTech Connect (OSTI)

    Swindle, T.D. (Univ. of Arizona, Tucson (USA)); Garrison, D.H.; Hohenberg, C.M.; Nichols, R.H.; Olinger, C.T. (Washington Univ., St. Louis, MO (USA)); Goswami, J.N. (Physical Research Laboratory, Ahmedabad (India))

    1990-08-01T23:59:59.000Z

    Analyses of noble gases in whole rock samples of the howardites Bholghati and Kapoeta and grain-size separates of Kapoeta yield evidence for excesses of the Xe isotopes {sup 129}Xe, {sup 131}Xe, {sup 132}Xe, {sup 134}Xe, and {sup 136}Xe in a low-temperature component, similar to lunar excess fission Xe. Such a component may be able to provide chronometric information if the relative abundances of radioactive progenitors ({sup 129}I, {sup 244}Pu, and {sup 238}U) can be determined, but the isotopic spectra we obtain are not sufficiently precise to do so. Eucritic clast BH-5 in Bholghati contains Xe produced in situ by the decay of {sup 244}Pu. Calculated fission Xe retention ages are 30-70 Ma after the formation of the solar system, consistent with the apparent presence of {sup 146}Sm decay products. Both the clast and the matrix of Bholghati have K-Ar ages of about 2 Ga, suggesting a common thermal event at least that recently.

  17. In-Situ Microbial Conversion of Sequestered Greenhouse Gases

    SciTech Connect (OSTI)

    Scott, A R; Mukhopadhyay, M; Balin, D F

    2012-09-06T23:59:59.000Z

    The objectives of the project are to use microbiological in situ bioconversion technology to convert sequestered or naturally-occurring greenhouse gases, including carbon dioxide and carbon monoxide, into methane and other useful organic compounds. The key factors affecting coal bioconversion identified in this research include (1) coal properties, (2) thermal maturation and coalification process, (3) microbial population dynamics, (4) hydrodynamics (5) reservoir conditions, and (6) the methodology of getting the nutrients into the coal seams. While nearly all cultures produced methane, we were unable to confirm sustained methane production from the enrichments. We believe that the methane generation may have been derived from readily metabolized organic matter in the coal samples and/or biosoluble organic material in the coal formation water. This raises the intriguing possibility that pretreatment of the coal in the subsurface to bioactivate the coal prior to the injection of microbes and nutrients might be possible. We determined that it would be more cost effective to inject nutrients into coal seams to stimulate indigenous microbes in the coal seams, than to grow microbes in fermentation vats and transport them to the well site. If the coal bioconversion process can be developed on a larger scale, then the cost to generate methane could be less than $1 per Mcf

  18. Future Sulfur Dioxide Emissions

    SciTech Connect (OSTI)

    Smith, Steven J.; Pitcher, Hugh M.; Wigley, Tom M.

    2005-12-01T23:59:59.000Z

    The importance of sulfur dioxide emissions for climate change is now established, although substantial uncertainties remain. This paper presents projections for future sulfur dioxide emissions using the MiniCAM integrated assessment model. A new income-based parameterization for future sulfur dioxide emissions controls is developed based on purchasing power parity (PPP) income estimates and historical trends related to the implementation of sulfur emissions limitations. This parameterization is then used to produce sulfur dioxide emissions trajectories for the set of scenarios developed for the Special Report on Emission Scenarios (SRES). We use the SRES methodology to produce harmonized SRES scenarios using the latest version of the MiniCAM model. The implications, and requirements, for IA modeling of sulfur dioxide emissions are discussed. We find that sulfur emissions eventually decline over the next century under a wide set of assumptions. These emission reductions result from a combination of emission controls, the adoption of advanced electric technologies, and a shift away from the direct end use of coal with increasing income levels. Only under a scenario where incomes in developing regions increase slowly do global emission levels remain at close to present levels over the next century. Under a climate policy that limits emissions of carbon dioxide, sulfur dioxide emissions fall in a relatively narrow range. In all cases, the relative climatic effect of sulfur dioxide emissions decreases dramatically to a point where sulfur dioxide is only a minor component of climate forcing by the end of the century. Ecological effects of sulfur dioxide, however, could be significant in some developing regions for many decades to come.

  19. Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.

  20. Semi-continuous detection of mercury in gases

    DOE Patents [OSTI]

    Granite, Evan J. (Wexford, PA); Pennline, Henry W. (Bethel Park, PA)

    2011-12-06T23:59:59.000Z

    A new method for the semi-continuous detection of heavy metals and metalloids including mercury in gaseous streams. The method entails mass measurement of heavy metal oxides and metalloid oxides with a surface acoustic wave (SAW) sensor having an uncoated substrate. An array of surface acoustic wave (SAW) sensors can be used where each sensor is for the semi-continuous emission monitoring of a particular heavy metal or metalloid.

  1. Heavy-Duty Truck Emissions in the South Coast Air Basin of Gary A. Bishop,* Brent G. Schuchmann,

    E-Print Network [OSTI]

    Denver, University of

    Heavy-Duty Truck Emissions in the South Coast Air Basin of California Gary A. Bishop,* Brent G, Colorado 80208, United States ABSTRACT: California and Federal emissions regulations for 2007 and newer of nitrogen spurring the introduction of new aftertreatment systems. Since 2008, four emission measurement

  2. Abstract--Historic data shows an increase in carbon dioxide (CO2) emissions at airports caused by an increase

    E-Print Network [OSTI]

    design alternatives provides reduction of CO2 emission levels such that the CO2 emissions for 2050 meet Abstract-- Historic data shows an increase in carbon dioxide (CO2) emissions at airports caused regulations at airports through reduction of CO2 for all components of flight operations. The purpose

  3. Limiting net greenhouse gas emissions in the United States

    SciTech Connect (OSTI)

    Bradley, R A; Watts, E C; Williams, E R [eds.

    1991-09-01T23:59:59.000Z

    In 1988, Congress requested that DOE produce a study on carbon dioxide inventory and policy to provide an inventory of emissions sources and to analyze policies to achieve a 20% reduction in carbon dioxide emissions in 5 to 10 years and a 50% reduction in 15 to 20 years. Energy and environmental technology data were analyzed using computational analysis models. This information was then evaluated, drawing on current scientific understanding of global climate change, the possible consequences of anthropogenic climate change (change caused by human activity) and the relationship between energy production and use and the emission of radiatively important gases. Topics discussed include: state of the science in estimating atmosphere/climate change relationships, the potential consequences of atmosphere/climate change, us greenhouse emissions past and present, an approach to analyzing the technical potential and cost of reducing US energy-related greenhouse gas emissions, current policy base and National Energy Strategy actions, fiscal instruments, regulatory instruments, combined strategies and instruments, macroeconomic impacts, carbon taxation and international trade, a comparison to other studies.

  4. Air Pollution Control Regulations: No. 3 - Particulate Emissions...

    Broader source: Energy.gov (indexed) [DOE]

    Agricultural Commercial Construction Fed. Government Fuel Distributor General PublicConsumer Industrial InstallerContractor Institutional Investor-Owned Utility Local Government...

  5. Emission Regulations Reduced Impact of Climate Change in CA

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    black carbon on California. In conducting the study, scientists used computer models and air pollution data collected by aircraft, satellite and ground monitors. The study's...

  6. Biomass Boiler and Furnace Emissions and Safety Regulations in...

    Open Energy Info (EERE)

    Air Use Management (NESCAUM) Sector: Energy Focus Area: Biomass, - Biomass Combustion, - Biomass Gasification, - Biomass Pyrolysis, - Biofuels, Economic Development...

  7. Climate regulation of fire emissions and deforestation in equatorial Asia

    E-Print Network [OSTI]

    2008-01-01T23:59:59.000Z

    different types of fire, with peat fires emitting up to fourof carbon released from peat and forest fires in IndonesiaM, Wo¨sten H, Page S (2006) PEAT-CO2: assessment of CO2

  8. Online Appendix: Market-based Emissions Regulation and the Evolution

    E-Print Network [OSTI]

    Fowlie, Meredith

    i makes entry, exit, production, and investment decisions, collec- tively denoted by ai. Since represents the firm's private information about the cost of entry, exit, investment, and divestment, investment, entry, and exit behavior as a function of the present state vector. In a Markovian setting

  9. Online Appendix: Market-based Emissions Regulation and the Evolution

    E-Print Network [OSTI]

    Fowlie, Meredith

    , firm i makes entry, exit, production, and investment decisions, collectively denoted by ai. Since represents the firm's private information about the cost of entry, exit, investment, and divestment, investment, entry, and exit behavior as a function of the present state vector. In a Markovian setting

  10. Update on Diesel Exhaust Emission Control Technology and Regulations

    Broader source: Energy.gov (indexed) [DOE]

    diesel out of the PM inventory * Technology is the state of optimization and cost reduction - Regeneration * LDD and MDD: engine management * HDD: auxiliary exhaust injection -...

  11. Comparing Emissions Benefits from Regulating Heavy Vehicle Idling |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof"Wave the WhiteNational| DepartmentCommunitiesDepartment of Energy

  12. Update on Diesel Exhaust Emission Control Technology and Regulations |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your DensityEnergy U.S.-China Electric Vehicle and03/02 TUE 08:59 FAX 423 241UpcomingASHRAEDepartment of

  13. Biomass Boiler and Furnace Emissions and Safety Regulations in the

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnualProperty EditCalifornia: EnergyAvignon,Belcher HomesLyons BiomassBiofuels) Jump

  14. Technical Demonstration of 2010 Emissions Regulations over Transient

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideoStrategic| Department ofGeneralWind »Assistance:Technical Demonstration

  15. Regulated Emissions from Diesel and Compressed Natural Gas Transit Buses |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of ContaminationHubs+18,new2004_v1.3_5.0.zipFlorida4Visitors Can Register forDepartment

  16. Timelines for mitigating methane emissions from energy technologies

    E-Print Network [OSTI]

    Roy, Mandira; Trancik, Jessika E

    2015-01-01T23:59:59.000Z

    Energy technologies emitting differing proportions of methane and carbon dioxide vary in their relative climate impacts over time, due to the different atmospheric lifetimes of the two gases. Standard technology comparisons using the global warming potential (GWP) emissions equivalency metric do not reveal these dynamic impacts, and may not provide the information needed to assess technologies and emissions mitigation opportunities in the context of broader climate policy goals. Here we formulate a portfolio optimization model that incorporates changes in technology impacts as a radiative forcing (RF) stabilization target is approached. An optimal portfolio, maximizing allowed energy consumption while meeting the RF target, is obtained by year-wise minimization of the marginal RF impact in an intended stabilization year. The optimal portfolio calls for using certain higher methane-emitting technologies prior to an optimal switching year, followed by methane-light technologies as the stabilization year approac...

  17. Field-driven dynamics of dilute gases, viscous liquids and polymer chains

    E-Print Network [OSTI]

    Mohan, Aruna, 1981-

    2007-01-01T23:59:59.000Z

    This thesis is concerned with the exploration of field-induced dynamical phenomena arising in dilute gases, viscous liquids and polymer chains. The problems considered herein pertain to the slip-induced motion of a rigid, ...

  18. Fact #825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus...

    Broader source: Energy.gov (indexed) [DOE]

    organic gases (NMOG) and nitrogen oxides (NOx) that new light vehicles with gasoline engines are allowed to produce for model years 2017 to 2025. These standards apply to a...

  19. Evolution and stability of shock waves in dissipative gases characterized by activated inelastic collisions

    E-Print Network [OSTI]

    Sirmas, Nick

    2015-01-01T23:59:59.000Z

    Previous experiments have revealed that shock waves driven through dissipative gases may become unstable, for example, in granular gases, and in molecular gases undergoing strong relaxation effects. The mechanisms controlling these instabilities are not well understood. We successfully isolated and investigated this instability in the canonical problem of piston driven shock waves propagating into a medium characterized by inelastic collision processes. We treat the standard model of granular gases, where particle collisions are taken as inelastic with constant coefficient of restitution. The inelasticity is activated for sufficiently strong collisions. Molecular dynamic simulations were performed for 30,000 particles. We find that all shock waves investigated become unstable, with density non-uniformities forming in the relaxation region. The wavelength of these fingers is found comparable to the characteristic relaxation thickness. Shock Hugoniot curves for both elastic and inelastic collisions were obtaine...

  20. Biological sweetening of energy gases mimics in biotrickling filters Marc Fortuny a,c

    E-Print Network [OSTI]

    in energy-rich gases such as biogas from anaerobic digesters which may contain H2S concentrations exceeding: Hydrogen sulfide; Gas sweetening; Biotrickling filter; Desulfurization; Fuel gas; Biogas 1. Introduction

  1. Method and apparatus for separating mixtures of gases using an acoustic wave

    DOE Patents [OSTI]

    Geller, Drew A.; Swift, Gregory W.; Backhaus, Scott N.

    2004-05-11T23:59:59.000Z

    A thermoacoustic device separates a mixture of gases. An elongated duct is provided with first and second ends and has a length that is greater than the wavelength of sound in the mixture of gases at a selected frequency, and a diameter that is greater than a thermal penetration depth in the mixture of gases. A first acoustic source is located at the first end of the duct to generate acoustic power at the selected frequency. A plurality of side branch acoustic sources are spaced along the length of the duct and are configured to introduce acoustic power into the mixture of gases so that a first gas is concentrated at the first end of the duct and a second gas is concentrated at the second end of the duct.

  2. What are greenhouse gases? Many chemical compounds in the atmosphere act as

    E-Print Network [OSTI]

    , Michigan State University, 2 Michigan State University Extension Climate Change and Agriculture Fact Sheet greenhouse gases carbon dioxide, methane, and nitrous oxide over the past 2000 years. Data are from ice core

  3. Quantum Cattaneo wave equation for ultra-short laser pulses interaction with electron and nucleon gases

    E-Print Network [OSTI]

    Marciak-Kozlowska, J

    2011-01-01T23:59:59.000Z

    In this paper the quantum Cattaneo wave equation for ultra-short laser pulses interaction with medium is obtained . The explicit formulae for electron and nucleon gases are presented

  4. Quantum coherence and magnetism in bosonic and fermionic gases of ultracold atoms

    E-Print Network [OSTI]

    Jo, Gyu-Boong

    2010-01-01T23:59:59.000Z

    In this thesis, two sets of experimental studies in bosonic and fermionic gases are described. In the first part of the thesis, itinerant ferromagnetism was studied in a strongly interacting Fermi gas of ultracold atoms. ...

  5. Quantum Cattaneo wave equation for ultra-short laser pulses interaction with electron and nucleon gases

    E-Print Network [OSTI]

    J Marciak-Kozlowska; Miroslaw Kozlowski

    2011-10-21T23:59:59.000Z

    In this paper the quantum Cattaneo wave equation for ultra-short laser pulses interaction with medium is obtained . The explicit formulae for electron and nucleon gases are presented

  6. Surface interactions involved in flashover with high density electronegative gases.

    SciTech Connect (OSTI)

    Hodge, Keith Conquest; Warne, Larry Kevin; Jorgenson, Roy Eberhardt; Wallace, Zachariah Red; Lehr, Jane Marie

    2010-01-01T23:59:59.000Z

    This report examines the interactions involved with flashover along a surface in high density electronegative gases. The focus is on fast ionization processes rather than the later time ionic drift or thermalization of the discharge. A kinetic simulation of the gas and surface is used to examine electron multiplication and includes gas collision, excitation and ionization, and attachment processes, gas photoionization and surface photoemission processes, as well as surface attachment. These rates are then used in a 1.5D fluid ionization wave (streamer) model to study streamer propagation with and without the surface in air and in SF6. The 1.5D model therefore includes rates for all these processes. To get a better estimate for the behavior of the radius we have studied radial expansion of the streamer in air and in SF6. The focus of the modeling is on voltage and field level changes (with and without a surface) rather than secondary effects, such as, velocities or changes in discharge path. An experiment has been set up to carry out measurements of threshold voltages, streamer velocities, and other discharge characteristics. This setup includes both electrical and photographic diagnostics (streak and framing cameras). We have observed little change in critical field levels (where avalanche multiplication sets in) in the gas alone versus with the surface. Comparisons between model calculations and experimental measurements are in agreement with this. We have examined streamer sustaining fields (field which maintains ionization wave propagation) in the gas and on the surface. Agreement of the gas levels with available literature is good and agreement between experiment and calculation is good also. Model calculations do not indicate much difference between the gas alone versus the surface levels. Experiments have identified differences in velocity between streamers on the surface and in the gas alone (the surface values being larger).

  7. ACID GASES IN CO2-RICH SUBSURFACE GEOLOGIC ENVIRONMENTS

    SciTech Connect (OSTI)

    Chialvo, Ariel A [ORNL] [ORNL; Vlcek, Lukas [ORNL] [ORNL; Cole, David [Ohio State University] [Ohio State University

    2013-01-01T23:59:59.000Z

    The analysis of species behavior involving dilute fluid environments has been crucial for the advance of modern solvation thermodynamics through molecular-based formalisms to guide the development of macroscopic regression tools in the description of fluid behavior and correlation of experimental data (Chialvo 2013). Dilute fluid environments involving geologic formations are of great theoretical and practical relevance regardless of the thermodynamic state conditions. The most challenging systems are those involving highly compressible and reactive confined environments, i.e., where small perturbations of pressure and/or temperature can trigger considerable density changes. This in turn can alter significantly the species solvation, their preferential solvation, and consequently, their reactivity with one another and with the surrounding mineral surfaces whose outcome is the modification of the substrate porosity and permeability, and ultimately, the integrity of the mineral substrates. Considering that changes in porosity and permeability resulting from dissolution and precipitation phenomena in confined environments are at the core of the aqueous CO2-mineral interactions, and that caprock integrity (e.g., sealing capacity) depends on these key parameters, it is imperative to gain fundamental understanding of the mineral-fluid interfacial phenomena and fluid-fluid equilibria under mineral confinement at subsurface conditions. In order to undertand the potential effects of acid gases as contaminants of supercritical CO2 streams, in the next section we will discuss the thermodynamic behavior of CO2 fluid systems by addressing two crucial issues in the context of carbon capture, utilization and sequestration (CCUS) technologies: (i) Why should we consider (acid gas) CO2 impurities? and (ii) Why are CO2 fluid - mineral interactions of paramount relevance?

  8. Methods for separating oxygen from oxygen-containing gases

    DOE Patents [OSTI]

    Mackay, Richard (Lafayette, CO); Schwartz, Michael (Boulder, CO); Sammells, Anthony F. (Boulder, CO)

    2000-01-01T23:59:59.000Z

    This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula: A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ; where x and x' are greater than 0; y and y' are greater than 0; x+x' is less than or equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; and B' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements. The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane include A.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z, where x is about 0.3 to about 0.5, x' is about 1.5 to about 1.7, y is 0.6, y' is between about 1.0 and 1.4 and B is Ga or Al.

  9. Nitrogen and sulfur emissions from the burning of forest products near large urban areas

    SciTech Connect (OSTI)

    Hegg, D.A.; Radke, L.F.; Hobbs, P.V.; Brock, C.A.; Riggan, P.J.

    1987-12-20T23:59:59.000Z

    Airborne measurements of trace gases and particles in the smoke from a prescribed burn of forest products in the Los Angeles basin show significantly higher emissions of NO/sub X/, SO/sub 2/, and particulate NO/sub 3//sup -/ than do measurements in smokes from the burning of biomass in rural areas. It is postulated that the high emissions are due to the revolatilization of previoulsy deposited pollutants. Implications for pollutant source inventories and the nuclear winter hypothesis are briefly discussed.

  10. Optimal design of a phase-in emissions trading program with voluntary compliance options

    E-Print Network [OSTI]

    Montero, Juan Pablo

    In this paper we explore the welfare implications of voluntary compliance within an emissions trading program and derive optimal permits allocations to affected and opti-in sources when the environmental regulator has ...

  11. Nitrogen oxides emission control through reburning with biomass in coal-fired power plants 

    E-Print Network [OSTI]

    Arumugam, Senthilvasan

    2005-02-17T23:59:59.000Z

    Oxides of nitrogen from coal-fired power stations are considered to be major pollutants, and there is increasing concern for regulating air quality and offsetting the emissions generated from the use of energy. Reburning ...

  12. A Strategy for a Global Observing System for Verification of National Greenhouse Gas Emissions

    E-Print Network [OSTI]

    Prinn, Ronald G.

    With the risks of climate change becoming increasingly evident, there is growing discussion regarding international treaties and national regulations to lower greenhouse gas (GHG) emissions. Enforcement of such agreements ...

  13. Forecasting and Capturing Emission Reductions Using Industrial Energy Management and Reporting Systems

    E-Print Network [OSTI]

    Robinson, J.

    2010-01-01T23:59:59.000Z

    The Mandatory 2010 Green House Gas (GHG) Reporting Regulations and pending climate change legislation has increased interest in Energy Management and Reporting Systems (EMRS) as a means of both reducing and reporting GHG emissions. This paper...

  14. Characterization of Fine Particulate Matter (PM) and Secondary PM Precursor Gases in the Mexico City Metropolitan Area

    SciTech Connect (OSTI)

    Luisa T. Molina, Rainer Volkamer, Benjamin de Foy, Wenfang Lei, Miguel Zavala, Erik Velasco; Mario J. Molina

    2008-10-31T23:59:59.000Z

    This project was one of three collaborating grants funded by DOE/ASP to characterize the fine particulate matter (PM) and secondary PM precursors in the Mexico City Metropolitan Area (MCMA) during the MILAGRO Campaign. The overall effort of MCMA-2006, one of the four components, focused on i) examination of the primary emissions of fine particles and precursor gases leading to photochemical production of atmospheric oxidants and secondary aerosol particles; ii) measurement and analysis of secondary oxidants and secondary fine PM production, with particular emphasis on secondary organic aerosol (SOA), and iii) evaluation of the photochemical and meteorological processes characteristic of the Mexico City Basin. The collaborative teams pursued the goals through three main tasks: i) analyses of fine PM and secondary PM precursor gaseous species data taken during the MCMA-2002/2003 campaigns and preparation of publications; ii) planning of the MILAGRO Campaign and deployment of the instrument around the MCMA; and iii) analysis of MCMA-2006 data and publication preparation. The measurement phase of the MILAGRO Campaign was successfully completed in March 2006 with excellent participation from the international scientific community and outstanding cooperation from the Mexican government agencies and institutions. The project reported here was led by the Massachusetts Institute of Technology/Molina Center for Energy and the Environment (MIT/MCE2) team and coordinated with DOE/ASP-funded collaborators at Aerodyne Research Inc., University of Colorado at Boulder and Montana State University. Currently 24 papers documenting the findings from this project have been published. The results from the project have improved significantly our understanding of the meteorological and photochemical processes contributing to the formation of ozone, secondary aerosols and other pollutants. Key findings from the MCMA-2003 include a vastly improved speciated emissions inventory from on-road vehicles: the MCMA motor vehicles produce abundant amounts of primary PM, elemental carbon, particle-bound polycyclic aromatic hydrocarbons, carbon monoxide and a wide range of air toxics; the feasibility of using eddy covariance techniques to measure fluxes of volatile organic compounds in an urban core and a valuable tool for validating local emissions inventory; a much better understanding of the sources and atmospheric loadings of volatile organic compounds; the first spectroscopic detection of glyoxal in the atmosphere; a unique analysis of the high fraction of ambient formaldehyde from primary emission sources; characterization of ozone formation and its sensitivity to VOCs and NOx; a much more extensive knowledge of the composition, size distribution and atmospheric mass loadings of both primary and secondary fine PM, including the fact that the rate of MCMA SOA production greatly exceeded that predicted by current atmospheric models; evaluations of significant errors that can arise from standard air quality monitors for O3 and NO2; and the implementation of an innovative Markov Chain Monte Carlo method for inorganic aerosol modeling as a powerful tool to analyze aerosol data and predict gas phase concentrations where these are unavailable. During the MILAGRO Campaign the collaborative team utilized a combination of central fixed sites and a mobile laboratory deployed throughout the MCMA to representative urban and boundary sites to measure trace gases and fine particles. Analysis of the extensive 2006 data sets has confirmed the key findings from MCMA-2002/2003; additionally MCMA-2006 provided more detailed gas and aerosol chemistry and wider regional scale coverage. Key results include an updated 2006 emissions inventory; extension of the flux system to measure fluxes of fine particles; better understanding of the sources and apportionment of aerosols, including contribution from biomass burning and industrial sources; a comprehensive evaluation of metal containing particles in a complex urban environment; identification of a close correlation between

  15. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOE Patents [OSTI]

    Natesan, K.

    1992-11-17T23:59:59.000Z

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9--30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000--1100 C. 7 figs.

  16. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOE Patents [OSTI]

    Natesan, Krishnamurti (Naperville, IL)

    1992-01-01T23:59:59.000Z

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9-30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000.degree.-1100.degree. C.

  17. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08T23:59:59.000Z

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  18. Field emission chemical sensor

    DOE Patents [OSTI]

    Panitz, J.A.

    1983-11-22T23:59:59.000Z

    A field emission chemical sensor for specific detection of a chemical entity in a sample includes a closed chamber enclosing two field emission electrode sets, each field emission electrode set comprising (a) an electron emitter electrode from which field emission electrons can be emitted when an effective voltage is connected to the electrode set; and (b) a collector electrode which will capture said electrons emitted from said emitter electrode. One of the electrode sets is passive to the chemical entity and the other is active thereto and has an active emitter electrode which will bind the chemical entity when contacted therewith.

  19. Modeling Traffic Flow Emissions

    E-Print Network [OSTI]

    Cappiello, Alessandra

    2002-09-17T23:59:59.000Z

    The main topic of this thesis is the development of light-duty vehicle dynamic emission models and their integration with dynamic traffic models. Combined, these models

  20. Saving Fuel, Reducing Emissions

    E-Print Network [OSTI]

    Kammen, Daniel M.; Arons, Samuel M.; Lemoine, Derek M.; Hummel, Holmes

    2009-01-01T23:59:59.000Z

    would in turn lower PHEV fuel costs and make them morestretches from fossil-fuel- powered conventional vehiclesbraking, as do Saving Fuel, Reducing Emissions Making Plug-

  1. Vehicle Emissions Review - 2011

    Broader source: Energy.gov (indexed) [DOE]

    mass, membrane effects, fundamentals on permeability * DOC Pd:Pt ratios allow optimization * Gasoline emission control is amazing - Zone coating - Lower PGM with better...

  2. Well-to-wheels energy use and greenhouse gas emissions analysis of plug-in hybrid electric vehicles.

    SciTech Connect (OSTI)

    Elgowainy, A.; Burnham, A.; Wang, M.; Molburg, J.; Rousseau, A.; Energy Systems

    2009-03-31T23:59:59.000Z

    Researchers at Argonne National Laboratory expanded the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model and incorporated the fuel economy and electricity use of alternative fuel/vehicle systems simulated by the Powertrain System Analysis Toolkit (PSAT) to conduct a well-to-wheels (WTW) analysis of energy use and greenhouse gas (GHG) emissions of plug-in hybrid electric vehicles (PHEVs). The WTW results were separately calculated for the blended charge-depleting (CD) and charge-sustaining (CS) modes of PHEV operation and then combined by using a weighting factor that represented the CD vehicle-miles-traveled (VMT) share. As indicated by PSAT simulations of the CD operation, grid electricity accounted for a share of the vehicle's total energy use, ranging from 6% for a PHEV 10 to 24% for a PHEV 40, based on CD VMT shares of 23% and 63%, respectively. In addition to the PHEV's fuel economy and type of on-board fuel, the marginal electricity generation mix used to charge the vehicle impacted the WTW results, especially GHG emissions. Three North American Electric Reliability Corporation regions (4, 6, and 13) were selected for this analysis, because they encompassed large metropolitan areas (Illinois, New York, and California, respectively) and provided a significant variation of marginal generation mixes. The WTW results were also reported for the U.S. generation mix and renewable electricity to examine cases of average and clean mixes, respectively. For an all-electric range (AER) between 10 mi and 40 mi, PHEVs that employed petroleum fuels (gasoline and diesel), a blend of 85% ethanol and 15% gasoline (E85), and hydrogen were shown to offer a 40-60%, 70-90%, and more than 90% reduction in petroleum energy use and a 30-60%, 40-80%, and 10-100% reduction in GHG emissions, respectively, relative to an internal combustion engine vehicle that used gasoline. The spread of WTW GHG emissions among the different fuel production technologies and grid generation mixes was wider than the spread of petroleum energy use, mainly due to the diverse fuel production technologies and feedstock sources for the fuels considered in this analysis. The PHEVs offered reductions in petroleum energy use as compared with regular hybrid electric vehicles (HEVs). More petroleum energy savings were realized as the AER increased, except when the marginal grid mix was dominated by oil-fired power generation. Similarly, more GHG emissions reductions were realized at higher AERs, except when the marginal grid generation mix was dominated by oil or coal. Electricity from renewable sources realized the largest reductions in petroleum energy use and GHG emissions for all PHEVs as the AER increased. The PHEVs that employ biomass-based fuels (e.g., biomass-E85 and -hydrogen) may not realize GHG emissions benefits over regular HEVs if the marginal generation mix is dominated by fossil sources. Uncertainties are associated with the adopted PHEV fuel consumption and marginal generation mix simulation results, which impact the WTW results and require further research. More disaggregate marginal generation data within control areas (where the actual dispatching occurs) and an improved dispatch modeling are needed to accurately assess the impact of PHEV electrification. The market penetration of the PHEVs, their total electric load, and their role as complements rather than replacements of regular HEVs are also uncertain. The effects of the number of daily charges, the time of charging, and the charging capacity have not been evaluated in this study. A more robust analysis of the VMT share of the CD operation is also needed.

  3. Molecular extended thermodynamics of rarefied polyatomic gases and wave velocities for increasing number of moments

    SciTech Connect (OSTI)

    Arima, Takashi, E-mail: tks@stat.nitech.ac.jp [Center for Social Contribution and Collaboration, Nagoya Institute of Technology (Japan); Mentrelli, Andrea, E-mail: andrea.mentrelli@unibo.it [Department of Mathematics and Research Center of Applied Mathematics (CIRAM), University of Bologna (Italy); Ruggeri, Tommaso, E-mail: tommaso.ruggeri@unibo.it [Department of Mathematics and Research Center of Applied Mathematics (CIRAM), University of Bologna (Italy)

    2014-06-15T23:59:59.000Z

    Molecular extended thermodynamics of rarefied polyatomic gases is characterized by two hierarchies of equations for moments of a suitable distribution function in which the internal degrees of freedom of a molecule is taken into account. On the basis of physical relevance the truncation orders of the two hierarchies are proven to be not independent on each other, and the closure procedures based on the maximum entropy principle (MEP) and on the entropy principle (EP) are proven to be equivalent. The characteristic velocities of the emerging hyperbolic system of differential equations are compared to those obtained for monatomic gases and the lower bound estimate for the maximum equilibrium characteristic velocity established for monatomic gases (characterized by only one hierarchy for moments with truncation order of moments N) by Boillat and Ruggeri (1997) (?{sub (N)}{sup E,max})/(c{sub 0}) ??(6/5 (N?1/2 )),(c{sub 0}=?(5/3 k/m T)) is proven to hold also for rarefied polyatomic gases independently from the degrees of freedom of a molecule. -- Highlights: •Molecular extended thermodynamics of rarefied polyatomic gases is studied. •The relation between two hierarchies of equations for moments is derived. •The equivalence of maximum entropy principle and entropy principle is proven. •The characteristic velocities are compared to those of monatomic gases. •The lower bound of the maximum characteristic velocity is estimated.

  4. Small-Chamber Measurements of Chemical-Specific Emission Factors for Drywall

    SciTech Connect (OSTI)

    Maddalena, Randy; Russell, Marion; Apte, Michael G.

    2010-06-01T23:59:59.000Z

    Imported drywall installed in U.S. homes is suspected of being a source of odorous and potentially corrosive indoor pollutants. To support an investigation of those building materials by the Consumer Products Safety Commission (CPSC), Lawrence Berkeley National Laboratory (LBNL) measured chemical-specific emission factors for 30 samples of drywall materials. Emission factors are reported for 75 chemicals and 30 different drywall samples encompassing both domestic and imported stock and incorporating natural, synthetic, or mixed gypsum core material. CPSC supplied all drywall materials. First the drywall samples were isolated and conditioned in dedicated chambers, then they were transferred to small chambers where emission testing was performed. Four sampling and analysis methods were utilized to assess (1) volatile organic compounds, (2) low molecular weight carbonyls, (3) volatile sulfur compounds, and (4) reactive sulfur gases. LBNL developed a new method that combines the use of solid phase microextraction (SPME) with small emission chambers to measure the reactive sulfur gases, then extended that technique to measure the full suite of volatile sulfur compounds. The testing procedure and analysis methods are described in detail herein. Emission factors were measured under a single set of controlled environmental conditions. The results are compared graphically for each method and in detailed tables for use in estimating indoor exposure concentrations.

  5. Natural Gas Regulations (Kentucky)

    Broader source: Energy.gov [DOE]

    Kentucky Administrative Regulation title 805 promulgates the rules and regulations pertaining to natural gas production in Kentucky. In addition to KAR title 405, chapter 30, which pertains to any...

  6. Radionuclide Air Emission Report for 2009

    SciTech Connect (OSTI)

    Wahl, Linnea

    2010-06-01T23:59:59.000Z

    Berkeley Lab operates facilities where radionuclides are handled and stored. These facilities are subject to the EPA radioactive air emission regulations in 40CFR61, Subpart H (EPA 1989). Radionuclides may be emitted from stacks or vents on buildings where radionuclide production or use is authorized or they may be emitted as diffuse sources. In 2009, all Berkeley Lab sources were minor sources of radionuclides (sources resulting in a potential dose of less than 0.1 mrem/yr [0.001 mSv/yr]). These minor sources included more than 100 stack sources and one source of diffuse emissions. There were no unplanned emissions from the Berkeley Lab site. Emissions from minor sources (stacks and diffuse emissions) either were measured by sampling or monitoring or were calculated based on quantities used, received for use, or produced during the year. Using measured and calculated emissions, and building-specific and common parameters, Laboratory personnel applied the EPA-approved computer code, CAP88-PC, to calculate the effective dose equivalent to the maximally exposed individual (MEI). The effective dose equivalent from all sources at Berkeley Lab in 2009 is 7.0 x 10{sup -3} mrem/yr (7.0 x 10{sup -5} mSv/yr) to the MEI, well below the 10 mrem/yr (0.1 mSv/yr) dose standard. The location of the MEI is at the University of California (UC) Lawrence Hall of Science, a public science museum about 1500 ft (460 m) east of Berkeley Lab's Building 56. The estimated collective effective dose equivalent to persons living within 50 mi (80 km) of Berkeley Lab is 1.5 x 10{sup -1} person-rem (1.5 x 10{sup -3} person-Sv) attributable to the Lab's airborne emissions in 2009.

  7. Air Emission Inventory for the INEEL -- 1999 Emission Report

    SciTech Connect (OSTI)

    Zohner, Steven K

    2000-05-01T23:59:59.000Z

    This report presents the 1999 calendar year update of the Air Emission Inventory for the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL Air Emission Inventory documents sources and emissions of nonradionuclide pollutants from operations at the INEEL. The report describes the emission inventory process and all of the sources at the INEEL, and provides nonradionuclide emissions estimates for stationary sources.

  8. Global Emissions of Terpenoid VOCs from Terrestrial Vegetation in the Last Millennium

    SciTech Connect (OSTI)

    Acosta Navarro, J. C.; Smolander, S.; Struthers, H.; Zorita, E.; Ekman, A. M.; Kaplan, J. O.; Guenther, Alex B.; Arneth, A.; Riipinen, I.

    2014-06-16T23:59:59.000Z

    We investigated the millennial variability of global BVOC emissions by using two independent numerical models: The Model of Emissions of Gases and Aerosols from Nature (MEGAN), for isoprene, monoterpene and sesquiterpene and Lund-Potsdam-Jena General Ecosystem Simulator (LPJ8 GUESS), for isoprene and monoterpenes. We found the millennial trends of global isoprene emissions to be mostly affected by land cover and atmospheric carbon dioxide changes, whereas monoterpene and sesquiterpene emission were dominated by temperature change. Isoprene emissions declined substantially in regions with large and rapid land cover change. In addition, isoprene emission sensitivity to drought proved to have signicant short term global effects. By the end of the past millennium MEGAN isoprene emissions were 634 TgC yr-1 (13% and 19% less than during during 1750-1850 and 1000- 15 1200, respectively) and LPJ-GUESS emissions were 323 TgC yr-1 (15% and 20% less than during 1750-1850 and 1000-1200, respectively). Monoterpene emissions were 89 TgC yr-1 (10% and 6% higher than during 1750-1850 and 1000-1200, respectively) in MEGAN, and 24 TgC yr-1 (2% higher and 5% 19 20 less than during 1750-1850 and 1000-1200, respectively) in LPJ-GUESS. MEGAN sesquiterpene emissions were 36 TgC yr-1 (10% and 4% higher than during1750-1850 and 1000-1200, respectively). Although both models capture similar We investigated the millennial variability of global BVOC emissions by using two independent numerical models: The Model of Emissions of Gases and Aerosols from Nature (MEGAN), for isoprene, monoterpene and sesquiterpene and Lund-Potsdam-Jena General Ecosystem Simulator (LPJ8GUESS), for isoprene and monoterpenes. We found the millennial trends ofglobal isoprene emissions to be mostly a*ected by land cover and atmospheric carbon dioxide changes, whereas monoterpene and sesquiterpene emission were dominated by temperature change. Isoprene emissions declined substantially in regions with large and rapid land cover change. In addition, isoprene emission sensitivity to drought proved to have signifcant short term global effects. By the end of the past millennium MEGAN isoprene emissions were 634 TgC yr-1 (13% and 19% less than during during 1750-1850 and 1000- 1200, respectively) and LPJ-GUESS emissions were 323 TgC yr-1 (15% and 16 17 20% less than during 1750-1850 and 1000-1200, respectively). Monoterpene emissions were 89 TgC yr-1 (10% and 6% higher than during 1750-1850 and 18 1000-1200, respectively) in MEGAN, and 24 TgC yr-1 (2% higher and 5% less than during 1750-1850 and 1000-1200, respectively) in LPJ-GUESS. MEGAN sesquiterpene emissions were 36 TgC yr-1 (10% and 4% higher than during1750-1850 and 1000-1200, respectively). Although both models capture similar emission trends, the magnitude of the emissions are different. This highlights the importance of building better constraints on VOC emissions from terrestrial vegetation.emission trends, the magnitude of the emissions are different. This highlights the importance of building better constraints on VOC emissions from terrestrial vegetation.

  9. Development of an ammonia emission protocol and preliminary emission factor for a central Texas dairy

    E-Print Network [OSTI]

    Rose, Adam Joseph

    2004-09-30T23:59:59.000Z

    dairies. The Texas Commission on Environmental Quality (TCEQ), the Texas SAPRA, does not currently use an emission factor to permit or regulate emitted ammonia for the dairy industry. ________________________ This thesis follows the style..., and is subject to gas-phase reaction with photochemically produced hydroxyl (-OH) radicals, reaction with gaseous nitric acid (to form particulate ammonium nitrate), and with aerosols to form ammonium salts (Singh et al., 2001). Ammonia that does not react...

  10. Computer Use Regulation Introduction

    E-Print Network [OSTI]

    Liu, Paul

    Computer Use Regulation #12;Introduction · The following training materials will reference the contents of the Computer Use Regulations, but should not serve as a substitute for reading the actual responsibilities NCSU employees have under the regulations. · North Carolina State University's computer networks

  11. Emotion Regulation CONCEPTUAL FOUNDATIONS

    E-Print Network [OSTI]

    Gross, James J.

    CHAPTER 1 Emotion Regulation CONCEPTUAL FOUNDATIONS JAMES J. GROSS ROSS A. THOMPSON Standing, paper or plastic are made. Quotidian acts of emotion regulation such as this constitute one important- changes that require us to regulate how emotions are experienced and expressed. But what do people do

  12. 3 Library Regulations Definitions

    E-Print Network [OSTI]

    Mottram, Nigel

    3 Library Regulations Definitions In Regulation 3: 'Library' means the University Library as defined in Regulation 3.1; 'Library staff' means the staff of the University Library; 'Librarian' means the University Librarian and Head of Information Resources Directorate or nominee; `Library Committee' means

  13. Emissions of Criteria Pollutants, Toxic Air Pollutants, and Greenhouse Gases, From the Use of Alternative Transportation Modes and Fuels

    E-Print Network [OSTI]

    Delucchi, Mark

    1996-01-01T23:59:59.000Z

    Administration, Annual Energy Outlook 1994, DOE/EIA-0383(Supplement to the Annual Energy Outlook 1994, DOE/EIA-0554(Supplement to the Annual Energy Outlook 1994, DOE/EIA-0554(

  14. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    T. L. e. a. Cottengim, Unaccounted-for Gas Project, Pacific1995). Determination of Unaccounted-for-Gas Distribution,publishes estimates of "unaccounted for" gas, but this is an

  15. Emissions of Criteria Pollutants, Toxic Air Pollutants, and Greenhouse Gases, From the Use of Alternative Transportation Modes and Fuels

    E-Print Network [OSTI]

    Delucchi, Mark

    1996-01-01T23:59:59.000Z

    plants, petroleum bulk terminals, gasoline service stations,terminals Petrol products, n.e.c. New & used car dealers Used car dealers Gasoline

  16. Emissions of Criteria Pollutants, Toxic Air Pollutants, and Greenhouse Gases, From the Use of Alternative Transportation Modes and Fuels

    E-Print Network [OSTI]

    Delucchi, Mark

    1996-01-01T23:59:59.000Z

    methanol made from coal, natural gas, or biomass, and used in internal- combustion-engine vehicles (ICEVs) or fuel-cell electric vehicles (

  17. Intrinsically Disordered Proteins: Regulation and Disease Regulation of IDPs

    E-Print Network [OSTI]

    Babu, M. Madan

    31st Jan 2011 Intrinsically Disordered Proteins: Regulation and Disease Regulation of IDPs M. Madan ...........................................................................................................................................................................1 2. The need for regulating IDPs.................................................................................................................................................1 3. General principles of IDP regulation

  18. The Effects of Environmental Regulation on the Competitiveness of U.S. Manufacturing

    E-Print Network [OSTI]

    Greenstone, Michael

    2012-09-10T23:59:59.000Z

    The economic costs of environmental regulations have been widely debated since the U.S. began to restrict pollution emissions more than four decades ago. Using detailed production data from nearly 1.2 million plant ...

  19. The Effects of Environmental Regulation on the Competitiveness of U.S. Manufacturing

    E-Print Network [OSTI]

    Greenstone, Michael

    The economic costs of environmental regulations have been widely debated since the U.S. began to restrict pollution emissions more than four decades ago. Using detailed production data from nearly 1.2 million plant ...

  20. The Clean Air Act's Impact on Environmental Regulation and Electric Power Conservation and Production

    E-Print Network [OSTI]

    Ashley, H.

    stringent environmental regulations force utilities to reconsider how best to meet the power demand. The new Clean Air Act permits utilities to use a market driven system of allowances to comply with sulfur dioxide emission limits. This paper discusses some...

  1. Graphene field emission devices

    SciTech Connect (OSTI)

    Kumar, S., E-mail: shishirk@gmail.com; Raghavan, S. [Centre for Nanoscience and Engineering, Indian Institute of Science, Bengaluru (India); Duesberg, G. S. [Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN) and School of Chemistry, Trinity College Dublin, Dublin, D2 (Ireland); Pratap, R. [Centre for Nanoscience and Engineering, Indian Institute of Science, Bengaluru (India); Department of Mechanical Engineering, Indian Institute of Science, Bengaluru (India)

    2014-09-08T23:59:59.000Z

    Graphene field emission devices are fabricated using a scalable process. The field enhancement factors, determined from the Fowler-Nordheim plots, are within few hundreds and match the theoretical predictions. The devices show high emission current density of ?10?nA ?m{sup ?1} at modest voltages of tens of volts. The emission is stable with time and repeatable over long term, whereas the noise in the emission current is comparable to that from individual carbon nanotubes emitting under similar conditions. We demonstrate a power law dependence of emission current on pressure which can be utilized for sensing. The excellent characteristics and relative ease of making the devices promise their great potential for sensing and electronic applications.

  2. Load regulating expansion fixture

    DOE Patents [OSTI]

    Wagner, Lawrence M. (San Jose, CA); Strum, Michael J. (San Jose, CA)

    1998-01-01T23:59:59.000Z

    A free standing self contained device for bonding ultra thin metallic films, such as 0.001 inch beryllium foils. The device will regulate to a predetermined load for solid state bonding when heated to a bonding temperature. The device includes a load regulating feature, whereby the expansion stresses generated for bonding are regulated and self adjusting. The load regulator comprises a pair of friction isolators with a plurality of annealed copper members located therebetween. The device, with the load regulator, will adjust to and maintain a stress level needed to successfully and economically complete a leak tight bond without damaging thin foils or other delicate components.

  3. Load regulating expansion fixture

    DOE Patents [OSTI]

    Wagner, L.M.; Strum, M.J.

    1998-12-15T23:59:59.000Z

    A free standing self contained device for bonding ultra thin metallic films, such as 0.001 inch beryllium foils is disclosed. The device will regulate to a predetermined load for solid state bonding when heated to a bonding temperature. The device includes a load regulating feature, whereby the expansion stresses generated for bonding are regulated and self adjusting. The load regulator comprises a pair of friction isolators with a plurality of annealed copper members located therebetween. The device, with the load regulator, will adjust to and maintain a stress level needed to successfully and economically complete a leak tight bond without damaging thin foils or other delicate components. 1 fig.

  4. Harvesting the Greenhouse: Comparing Biological Sequestration with Emissions Offsets

    E-Print Network [OSTI]

    McCarl, Bruce A.

    is principally stimulated by the link between GHGs and projected global warming (Intergovernmental Panel.g., carbon emission taxes in Norway or potential multi pollutant electric utility regulation in the U of the emitting activity (e.g. reducing the production of emitting products) or by altering the mix of fuel inputs

  5. Future Emissions Impact On Off-Road Vehicles

    SciTech Connect (OSTI)

    Kirby Baumgard; Steve Ephraim

    2001-04-18T23:59:59.000Z

    Summaries of paper: Emission requirements dictate vehicle update cycles; Packaging, performance and cost impacted; Styling updates can be integrated; Opportunity to integrate features and performance; Non-uniform regulations challenge resources; and Customers won't expect to pay more or receive less.

  6. Quality Assurance Program Plan for radionuclide airborne emissions monitoring

    SciTech Connect (OSTI)

    Vance, L.M.

    1993-07-01T23:59:59.000Z

    This Quality Assurance Program Plan (QAPP) describes the quality assurance requirements and responsibilities for radioactive airborne emissions measurements activities from regulated stacks are controlled at the Hanford Site. Detailed monitoring requirements apply to stacks exceeding 1% of the standard of 10 mrem annual effective dose equivalent to the maximally exposed individual from operations of the Hanford Site.

  7. THE VALUATION OF CLEAN SPREAD OPTIONS: LINKING ELECTRICITY, EMISSIONS RENE CARMONA, MICHAEL COULON, AND DANIEL SCHWARZ

    E-Print Network [OSTI]

    Carmona, Rene

    for the latter than the former. In this paper we concentrate on the production of electricity and CO2 emissions and the resulting dependence structure between prices. Market mechanisms aimed at controlling CO2 emissions have on CO2 by the regulation should be included in the costs of production to set the price of electricity

  8. Waste Heat Recovery from High Temperature Off-Gases from Electric Arc Furnace

    SciTech Connect (OSTI)

    Nimbalkar, Sachin U [ORNL; Thekdi, Arvind [E3M Inc; Keiser, James R [ORNL; Storey, John Morse [ORNL

    2014-01-01T23:59:59.000Z

    This article presents a study and review of available waste heat in high temperature Electric Arc Furnace (EAF) off gases and heat recovery techniques/methods from these gases. It gives details of the quality and quantity of the sensible and chemical waste heat in typical EAF off gases, energy savings potential by recovering part of this heat, a comprehensive review of currently used waste heat recovery methods and potential for use of advanced designs to achieve a much higher level of heat recovery including scrap preheating, steam production and electric power generation. Based on our preliminary analysis, currently, for all electric arc furnaces used in the US steel industry, the energy savings potential is equivalent to approximately 31 trillion Btu per year or 32.7 peta Joules per year (approximately $182 million US dollars/year). This article describes the EAF off-gas enthalpy model developed at Oak Ridge National Laboratory (ORNL) to calculate available and recoverable heat energy for a given stream of exhaust gases coming out of one or multiple EAF furnaces. This Excel based model calculates sensible and chemical enthalpy of the EAF off-gases during tap to tap time accounting for variation in quantity and quality of off gases. The model can be used to estimate energy saved through scrap preheating and other possible uses such as steam generation and electric power generation using off gas waste heat. This article includes a review of the historical development of existing waste heat recovery methods, their operations, and advantages/limitations of these methods. This paper also describes a program to develop and test advanced concepts for scrap preheating, steam production and electricity generation through use of waste heat recovery from the chemical and sensible heat contained in the EAF off gases with addition of minimum amount of dilution or cooling air upstream of pollution control equipment such as bag houses.

  9. Final report on activities and findings under DOE grant “Interactive Photochemistry in Earth System Models to Assess Uncertainty in Ozone and Greenhouse Gases

    SciTech Connect (OSTI)

    Prather, Michael J. [UCI

    2014-11-07T23:59:59.000Z

    Atmospheric chemistry controls the abundances and hence climate forcing of important greenhouse gases including N2O, CH4, HFCs, CFCs, and O3. Attributing climate change to human activities requires, at a minimum, accurate models of the chemistry and circulation of the atmosphere that relate emissions to abundances. This DOE-funded research provided realistic, yet computationally optimized and affordable, photochemical modules to the Community Earth System Model (CESM) that augment the CESM capability to explore the uncertainty in future stratospheric-tropospheric ozone, stratospheric circulation, and thus the lifetimes of chemically controlled greenhouse gases from climate simulations. To this end, we have successfully implemented Fast-J (radiation algorithm determining key chemical photolysis rates) and Linoz v3.0 (linearized photochemistry for interactive O3, N2O, NOy and CH4) packages in LLNL-CESM and for the first time demonstrated how change in O2 photolysis rate within its uncertainty range can significantly impact on the stratospheric climate and ozone abundances. From the UCI side, this proposal also helped LLNL develop a CAM-Superfast Chemistry model that was implemented for the IPCC AR5 and contributed chemical-climate simulations to CMIP5.

  10. Spontaneous Emission Rate Enhancement Using Optical Antennas

    E-Print Network [OSTI]

    Kumar, Nikhil

    2013-01-01T23:59:59.000Z

    of  Spontaneous  Emission  in  a  Semiconductor  nanoLED,”  emission  rate  enhancement  using  the  Fluorescent  Emission  by  Lattice   Resonances  in  

  11. EMISSION AND TRANSMISSION NOISE PROPAGATION IN POSITRON EMISSION COMPUTED TOMOGRAPHY

    E-Print Network [OSTI]

    Gullberg, G.T.

    2010-01-01T23:59:59.000Z

    High Resolution Computed Tomography of Positron Emitters,"of Dynamic Emission Computed Tomography," J. Nucl. Med. ~:IN POSITRON EMISSION COMPUTED TOMOGRAPHY RECEIVED lAWRENCE

  12. Proving Environmental Discretion: An Argument for Regulating Greenhouse Gases from Motor Vehicles under the Clean Air Act

    E-Print Network [OSTI]

    Jackson, Omari

    2006-01-01T23:59:59.000Z

    of sea level increases as a result of global warming thatglobal warming, it stated that an increase in carbon dioxide levels

  13. Stable field emission from W tips in poor vacuum conditions V. N. Tondare,a)

    E-Print Network [OSTI]

    van Druten, Klaasjan

    to the emission current measured. Without a current regulator circuit, an uncleaned W tip in unbaked 6 10 7 mbar system pressure cannot emit stable FE current and short-term fluctuations at a few nA current were found to be more than 300%. The current regulator circuit improves the FE current stability dramatically

  14. Contraction & Convergence: UK carbon emissions and the

    E-Print Network [OSTI]

    Watson, Andrew

    the EU's emissions trading scheme will do little to mitigate carbon emissions 4) Aviation growth must emissions. Keywords Contraction & Convergence; aviation; emissions trading; passengers; carbon dioxide #12

  15. Emission Abatement System

    DOE Patents [OSTI]

    Bromberg, Leslie (Sharon, MA); Cohn, Daniel R. (Chestnut Hill, MA); Rabinovich, Alexander (Swampscott, MA)

    2003-05-13T23:59:59.000Z

    Emission abatement system. The system includes a source of emissions and a catalyst for receiving the emissions. Suitable catalysts are absorber catalysts and selective catalytic reduction catalysts. A plasma fuel converter generates a reducing gas from a fuel source and is connected to deliver the reducing gas into contact with the absorber catalyst for regenerating the catalyst. A preferred reducing gas is a hydrogen rich gas and a preferred plasma fuel converter is a plasmatron. It is also preferred that the absorber catalyst be adapted for absorbing NO.sub.x.

  16. Phase Behavior of Light Gases in Hydrocarbon and Aqueous Solvents

    SciTech Connect (OSTI)

    Gasem, K.A.M.; Robinson, R.L., Jr.; Trvedi, N.J., Gao, W.

    1997-09-01T23:59:59.000Z

    Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, our solubility apparatus was refurbished and restored to full service. To test the experimental apparatus and procedures used, measurements were obtained for the solubility Of C0{sub 2} in benzene at 160{degrees}F. Having confirmed the accuracy of the newly acquired data in comparison with our previous measurements and data reported in the literature for this test system, we have begun to measure the solubility of hydrogen in hexane. The measurements for this system will cover the temperature range from 160 to 280{degrees}F at pressures to 2,500 psia. As part of our model evaluation efforts, we examined the predictive abilities of an alternative approach we have proposed for calculating the phase behavior properties of highly non-ideal systems. Using this approach, the liquid phase fugacities generated from an equation of state (EOS) are augmented by a fugacity deviation function correction. The correlative abilities of this approach are compared with those of an EOS equipped with the recently introduced Wong-Sandler (MWS) mixing rules. These two approaches are compared with the current methods for vapor-liquid equilibrium (VLE) calculations, i.e., the EOS (0/0) approach with the van der Waals mixing rules and the split (y/0) approach. The evaluations were conducted on a database comprised of non-ideal low pressure binary systems as well as asymmetric high pressure binary systems. These systems are of interest in the coal liquefaction and utilization processes. The Peng-Robinson EOS was selected for the purposes of this evaluation.

  17. Observation of CH4 and other Non-CO2 Green House Gas Emissions from California

    SciTech Connect (OSTI)

    Fischer, Marc L.; Zhao, Chuanfeng; Riley, William J.; Andrews, Arlyn C.

    2009-01-09T23:59:59.000Z

    In 2006, California passed the landmark assembly bill AB-32 to reduce California's emissions of greenhouse gases (GHGs) that contribute to global climate change. AB-32 commits California to reduce total GHG emissions to 1990 levels by 2020, a reduction of 25 percent from current levels. To verify that GHG emission reductions are actually taking place, it will be necessary to measure emissions. We describe atmospheric inverse model estimates of GHG emissions obtained from the California Greenhouse Gas Emissions Measurement (CALGEM) project. In collaboration with NOAA, we are measuring the dominant long-lived GHGs at two tall-towers in central California. Here, we present estimates of CH{sub 4} emissions obtained by statistical comparison of measured and predicted atmospheric mixing ratios. The predicted mixing ratios are calculated using spatially resolved a priori CH{sub 4} emissions and surface footprints, that provide a proportional relationship between the surface emissions and the mixing ratio signal at tower locations. The footprints are computed using the Weather Research and Forecast (WRF) coupled to the Stochastic Time-Inverted Lagrangian Transport (STILT) model. Integral to the inverse estimates, we perform a quantitative analysis of errors in atmospheric transport and other factors to provide quantitative uncertainties in estimated emissions. Regressions of modeled and measured mixing ratios suggest that total CH{sub 4} emissions are within 25% of the inventory estimates. A Bayesian source sector analysis obtains posterior scaling factors for CH{sub 4} emissions, indicating that emissions from several of the sources (e.g., landfills, natural gas use, petroleum production, crops, and wetlands) are roughly consistent with inventory estimates, but livestock emissions are significantly higher than the inventory. A Bayesian 'region' analysis is used to identify spatial variations in CH{sub 4} emissions from 13 sub-regions within California. Although, only regions near the tower are significantly constrained by the tower measurements, CH{sub 4} emissions from the south Central Valley appear to be underestimated in a manner consistent with the under-prediction of livestock emissions. Finally, we describe a pseudo-experiment using predicted CH{sub 4} signals to explore the uncertainty reductions that might be obtained if additional measurements were made by a future network of tall-tower stations spread over California. These results show that it should be possible to provide high-accuracy estimates of surface CH{sub 4} emissions for multiple regions as a means to verify future emissions reductions.

  18. Physical and chemical properties of the regional mixed layer of Mexico's Megapolis – Part II: Evaluation of measured and modeled trace gases and particle size distributions

    SciTech Connect (OSTI)

    Ochoa, Carlos; Baumgardner, Darrel; Grutter, M.; Allan, James D.; Fast, Jerome D.; Rappengluck, B.

    2012-10-31T23:59:59.000Z

    This study extends the work of Baumgardner et al. (2009) in which measurements of trace gases and particles at a remote, high-altitude mountain site 60 km from Mexico City were analyzed with respect to the origin of air masses. In the current evaluation, the temperature, water vapor, ozone (O3), carbon monoxide (CO), acyl peroxy nitrate (APN) and particle size distributions (PSDs) of the mass concentrations of sulfate, nitrate, ammonium and organic mass (OM) were simulated with the WRF-Chem chemical transport model and compared with the measurements at the mountain site. The model prediction of the diurnal trends of the gases were well correlated with the measurements before the regional boundary layer reached the measurement site but underestimated the concentrations after that time. The differences are caused by an overly rapid growth of the boundary layer by the model with too much dilution. There also appears to be more O3 produced by photochemical production, downwind of the emission sources, than predicted by the model. The measured and modeled PSDs compare very well with respect to their general shape and diameter of the peak concentrations. The spectra are log normally distributed with most of the mass in the accumulation mode and the geometric diameter centered at 200 ±20 nm, with little observed or predicted change with respect to the origin of the air mass or the time when the RBL is above the Altzomoni research. Only the total mass changed with time and air mass origin. The invariability of the average diameter of the accumulation mode suggests that there is very little growth of the particles by condensation or coagulation after six hours of aging downwind of the major sources of anthropogenic emissions in Mexico’s Megapolis.

  19. Applying guidance for methane emission estimation for landfills

    SciTech Connect (OSTI)

    Scharff, Heijo [NV Afvalzorg, Postbus 2, 1566 ZG Assendelft (Netherlands)]. E-mail: h.scharff@afvalzorg.nl; Jacobs, Joeri [NV Afvalzorg, Postbus 2, 1566 ZG Assendelft (Netherlands)]. E-mail: j.jacobs@afvalzorg.nl

    2006-07-01T23:59:59.000Z

    Quantification of methane emission from landfills is important to evaluate measures for reduction of greenhouse gas emissions. Both the United Nations and the European Union have adopted protocols to ensure quantification of methane emission from individual landfills. The purpose of these protocols is to disclose emission data to regulators and the general public. Criteria such as timeliness, completeness, certainty, comparability, consistency and transparency are set for inclusion of emission data in a publicly accessible database. All methods given as guidance to landfill operators to estimate landfill methane emissions are based on models. In this paper the consequences of applying six different models for estimates of three landfills are explored. It is not the intention of this paper to criticise or validate models. The modelling results are compared with whole site methane emission measurements. A huge difference in results is observed. This raises doubts about the accuracy of the models. It also indicates that at least some of the criteria previously mentioned are not met for the tools currently available to estimate methane emissions from individual landfills. This will inevitably lead to compiling and comparing data with an incomparable origin. Harmonisation of models is recommended. This may not necessarily reduce uncertainty, but it will at least result in comparable, consistent and transparent data.

  20. Emission control cost-effectiveness of alternative-fuel vehicles

    SciTech Connect (OSTI)

    Wang, Q. [Argonne National Lab., IL (United States); Sperling, D.; Olmstead, J. [California Univ., Davis, CA (United States). Inst. of Transportation Studies

    1993-06-14T23:59:59.000Z

    Although various legislation and regulations have been adopted to promote the use of alternative-fuel vehicles for curbing urban air pollution problems, there is a lack of systematic comparisons of emission control cost-effectiveness among various alternative-fuel vehicle types. In this paper, life-cycle emission reductions and life-cycle costs were estimated for passenger cars fueled with methanol, ethanol, liquefied petroleum gas, compressed natural gas, and electricity. Vehicle emission estimates included both exhaust and evaporative emissions for air pollutants of hydrocarbon, carbon monoxide, nitrogen oxides, and air-toxic pollutants of benzene, formaldehyde, 1,3-butadiene, and acetaldehyde. Vehicle life-cycle cost estimates accounted for vehicle purchase prices, vehicle life, fuel costs, and vehicle maintenance costs. Emission control cost-effectiveness presented in dollars per ton of emission reduction was calculated for each alternative-fuel vehicle types from the estimated vehicle life-cycle emission reductions and costs. Among various alternative-fuel vehicle types, compressed natural gas vehicles are the most cost-effective vehicle type in controlling vehicle emissions. Dedicated methanol vehicles are the next most cost-effective vehicle type. The cost-effectiveness of electric vehicles depends on improvements in electric vehicle battery technology. With low-cost, high-performance batteries, electric vehicles are more cost-effective than methanol, ethanol, and liquified petroleum gas vehicles.

  1. Growing consumption of petroleum products worldwide has resulted in the proliferation of vessels carrying oil, chemicals, and gases

    E-Print Network [OSTI]

    Neimark, Alexander V.

    Growing consumption of petroleum products worldwide has resulted in the proliferation of vessels carrying oil, chemicals, and gases into our harbors. Meeting our society's surging demand for commodities

  2. Greenhouse Gas Emissions (Minnesota)

    Broader source: Energy.gov [DOE]

    This statute sets goals for the reduction of statewide greenhouse gas emissions by at least 15 percent by 2015, 30 percent by 2025, and 80 percent by 2050, calculated relative to 2005 levels. These...

  3. Photon enhanced thermionic emission

    DOE Patents [OSTI]

    Schwede, Jared; Melosh, Nicholas; Shen, Zhixun

    2014-10-07T23:59:59.000Z

    Photon Enhanced Thermionic Emission (PETE) is exploited to provide improved efficiency for radiant energy conversion. A hot (greater than 200.degree. C.) semiconductor cathode is illuminated such that it emits electrons. Because the cathode is hot, significantly more electrons are emitted than would be emitted from a room temperature (or colder) cathode under the same illumination conditions. As a result of this increased electron emission, the energy conversion efficiency can be significantly increased relative to a conventional photovoltaic device. In PETE, the cathode electrons can be (and typically are) thermalized with respect to the cathode. As a result, PETE does not rely on emission of non-thermalized electrons, and is significantly easier to implement than hot-carrier emission approaches.

  4. Field emission electron source

    DOE Patents [OSTI]

    Zettl, Alexander Karlwalter (Kensington, CA); Cohen, Marvin Lou (Berkeley, CA)

    2000-01-01T23:59:59.000Z

    A novel field emitter material, field emission electron source, and commercially feasible fabrication method is described. The inventive field emission electron source produces reliable electron currents of up to 400 mA/cm.sup.2 at 200 volts. The emitter is robust and the current it produces is not sensitive to variability of vacuum or the distance between the emitter tip and the cathode. The novel emitter has a sharp turn-on near 100 volts.

  5. Dynamics of a geothermal field traced by noble gases: Cerro Prieto, Mexico

    SciTech Connect (OSTI)

    Mazor, E. (Weizmann Inst. of Science, Rehovot, Israel); Truesdell, A.H.

    1981-01-01T23:59:59.000Z

    Noble gases have been measured mass spectrometrically in samples collected during 1977 from producing wells at Cerro Prieto. Positive correlations between concentrations of radiogenic (He, /sup 40/Ar) and atmospheric noble gases (Ne, Ar, and Kr) suggest the following dynamic model: the geothermal fluids originated from meteoric water penetrated to more than 2500 m depth (below the level of first boiling) and mixed with radiogenic helium and argon-40 formed in the aquifer rocks. Subsequently, small amounts of steam were lost by a Raleigh process (0 to 3%) and mixing with shallow cold water occurred (0 to 30%). Noble gases are sensitive tracers of boiling in the initial stages of 0 to 3% steam separation and complement other tracers, such as Cl or temperature, which are effective only beyond this range.

  6. The Spectral Backbone of Excitation Transport in Ultra-Cold Rydberg Gases

    E-Print Network [OSTI]

    Scholak, Torsten; Buchleitner, Andreas

    2014-01-01T23:59:59.000Z

    The spectral structure underlying excitonic energy transfer in ultra-cold Rydberg gases is studied numerically, in the framework of random matrix theory, and via self-consistent diagrammatic techniques. Rydberg gases are made up of randomly distributed, highly polarizable atoms that interact via strong dipolar forces. Dynamics in such a system is fundamentally different from cases in which the interactions are of short range, and is ultimately determined by the spectral and eigenvector structure. In the energy levels' spacing statistics, we find evidence for a critical energy that separates delocalized eigenstates from states that are localized at pairs or clusters of atoms separated by less than the typical nearest-neighbor distance. We argue that the dipole blockade effect in Rydberg gases can be leveraged to manipulate this transition across a wide range: As the blockade radius increases, the relative weight of localized states is reduced. At the same time, the spectral statistics -- in particular, the den...

  7. Coal Mining Regulations (Kentucky)

    Broader source: Energy.gov [DOE]

    Kentucky Administrative Regulation Title 405 chapters 1, 2, 3, 5, 7, 8, 10, 12, 16, 18 and 20 establish the laws governing coal mining in the state.

  8. Regulation of natural monopolies

    E-Print Network [OSTI]

    Joskow, Paul L.

    2005-01-01T23:59:59.000Z

    This chapter provides a comprehensive overview of the theoretical and empirical literature on the regulation of natural monopolies. It covers alternative definitions of natural monopoly, regulatory goals, alternative ...

  9. Regulations of Wells (Florida)

    Broader source: Energy.gov [DOE]

    The Department of Environmental Protection regulates the construction, repair, and abandonment of wells, as well as the persons and businesses undertaking such practices. Governing boards of water...

  10. Tidal Wetlands Regulations (Connecticut)

    Broader source: Energy.gov [DOE]

    Most activities occurring in or near tidal wetlands are regulated, and this section contains information on such activities and required permit applications for proposed activities. Applications...

  11. Utility Regulation (Indiana)

    Broader source: Energy.gov [DOE]

    The Indiana Utility Regulatory Commission enforces regulations in this legislation that apply to all individuals, corporations, companies, and partnerships that may own, operate, manage, or control...

  12. Control technology of vinyl chloride in EDC-VCM and PVC plants at main source points and fugitive emissions

    E-Print Network [OSTI]

    Parra, Dario Antonio

    1983-01-01T23:59:59.000Z

    in a boiler and the combustion gases scrubbed with water or a caustic solution to remove the hydrogen chloride to form hydrochloric acid or sodium chloride. According to the Trane Thermal Company, thermal incineration is a basic proven process... and fugitive emissions, (b) collection of data by using a questionaire ? survey from industries located in the United States, and (c) a statistical analysis of the data. It was found that thermal incineration is considered the best approach to control...

  13. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

    1984-01-01T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  14. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1984-06-19T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  15. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1982-07-07T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  16. Diesel Emission Control in Review

    Broader source: Energy.gov (indexed) [DOE]

    in Review Dept. of Energy DEER Conference Tim Johnson August 2007 Summary * Regulations - European LDD regulations have implications to the US approach - Europe is formally...

  17. New environmental regulation for the aerospace industry: The aerospace NESHAP

    SciTech Connect (OSTI)

    Bauer, J.P.; Gampper, B.P. [Brusn and McDonnell Waste Consultants, Inc., Kansas City, MO (United States); Baker, J.M. [Raytheon Aircraft Co., Wichita, KS (United States)

    1997-12-31T23:59:59.000Z

    40 CFR Part 63, Subpart GG, the National Emission Standard for Hazardous Air Pollutants for Aerospace Manufacturing and Rework Facilities, commonly referred to as the Aerospace NESHAP, was issued on September 1, 1995 and requires compliance by September 1, 1998. The regulation affects any facility that manufactures or reworks commercial, civil, or military aircraft vehicles or components and is a major source of Hazardous Air Pollutants (HAPs). The regulation targets reducing Volatile Organic Compound (VOC) and Hazardous Air Pollutant (HAP) emissions to the atmosphere. Processes affected by the new regulation include aircraft painting, paint stripping, chemical milling masking, solvent cleaning, and spray gun cleaning. Regulatory requirements affecting these processes are summarized, and different compliance options compared in terms of cost-effectiveness and industry acceptance. Strategies to reduce compliance costs and minimize recordkeeping burdens are also presented.

  18. Climate Protection and Green Economy Act, Global Warming Solutions Act (Massachusetts)

    Broader source: Energy.gov [DOE]

    This Act requires the Department of Natural Resources to monitor and regulate the emissions of greenhouse gases in the Commonwealth of Massachusetts, to require emissions reporting and to establish...

  19. REGULATION I: Responsibility for Creation and Amendment of Regulations

    E-Print Network [OSTI]

    REGULATION I: Responsibility for Creation and Amendment of Regulations 1. In accordance with Article 14 of the Charter, the Council shall have the power to make, amend or repeal Regulations. 2 of the Regulations and the delegation of such power pursuant to Regulation II (7.2) by the Council to Senate

  20. Workshop in Regulation &

    E-Print Network [OSTI]

    Lin, Xiaodong

    Smart Grid and Regulatory Issues April 1, 2011 K&L Gates LLP, 1601 K Street, NW, Washington, DC Viable Regulation." Victor Glass, NECA, Comments January 14, 2011 Smart Grid and Regulatory Issues Location: Rutgers, The Brattle Group, "Smart Grid/Smart Regulation" John Caldwell, EEI, "Economic Efficiency and the Smart Grid