Sample records for gases ethane propane

  1. Effect of catalyst structure on oxidative dehydrogenation of ethane and propane on alumina-supported vanadia

    E-Print Network [OSTI]

    Argyle, Morris D.; Chen, Kaidong; Bell, Alexis T.; Iglesia, Enrique

    2001-01-01T23:59:59.000Z

    catalysts: (a) ethane ODH, (b) propane ODH (663 K, 14 kPa CDehydrogenation of Ethane and Propane on Alumina-Supporteddehydrogenation of ethane and propane. UV-visible and Raman

  2. Author's personal copy Unified behaviour of maximum soot yields of methane, ethane and propane

    E-Print Network [OSTI]

    Gülder, Ömer L.

    Author's personal copy Unified behaviour of maximum soot yields of methane, ethane and propane the current study and the previous measurements in similar flames with methane, ethane, and propane flames

  3. Selective adsorption of ethylene over ethane and propylene over propane in the metalorganic

    E-Print Network [OSTI]

    Selective adsorption of ethylene over ethane and propylene over propane in the metal in the energy costs associated with the cryogenic separation of ethylene­ethane and propylene­propane mixtures adsorption data for ethylene, ethane, propylene, and propane at 45, 60, and 80 C for the entire series

  4. Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing

    E-Print Network [OSTI]

    Sessions, Alex L.

    Novel Methane, Ethane, and Propane Oxidizing Bacteria at Marine Hydrocarbon Seeps Identified by Stable Isotope Probing Running Title: Novel Methane, Ethane, and Propane Oxidizing Bacteria Section incubating sediment with 13 C-labeled methane, ethane, or propane, we5 confirmed the incorporation of 13 C

  5. Novel Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation Pingping Sun a

    E-Print Network [OSTI]

    Iglesia, Enrique

    Novel Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation Pingping Sun a , Georges and propane dehydrogenation reactions are strongly dependent on the bulk In/Pt ratio. For both reactants to alkene was nearly 100%. Coke deposition was observed after catalyst use for either ethane or propane

  6. Molecular Properties of the "Ideal" Inhaled Anesthetic: Studies of Fluorinated Methanes, Ethanes, Propanes,

    E-Print Network [OSTI]

    Hudlicky, Tomas

    , Propanes, and Butanes E. 1Eger, 11, MD*, J. Liu, MD*, D. D. Koblin, PhD, MDt, M. J. Laster, DVM*, S. Taheri unfluorinated, partially fluorinated, and perfluorinated methanes, ethanes, propanes, and butanes to define fluorinated methanes, ethanes, propanes, and butanes, also obtaining limited data on longer- chained alkanes

  7. J. Am. Chem. SOC.1988, 110, 8305-8319 8305 Hydrogenolysis of Ethane, Propane, n-Butane, and Neopentane

    E-Print Network [OSTI]

    Goodman, Wayne

    J. Am. Chem. SOC.1988, 110, 8305-8319 8305 Hydrogenolysis of Ethane, Propane, n, Pasadena, California 91125. Received February I, 1988 Abstract: The hydrogenolysisof ethane, propane, n for ethane, propane, and neopentane involvesthe cleavage of a single carbon-carbon bond, resulting

  8. Novel Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation

    SciTech Connect (OSTI)

    Sun, Pingping; Siddiqi, Georges; Vining, William C.; Chi, Miaofang; Bell, Alexis T. (UCB); (ORNL)

    2011-10-28T23:59:59.000Z

    Catalysts for the dehydrogenation of light alkanes were prepared by dispersing Pt on the surface of a calcined hydrotalcite-like support containing indium, Mg(In)(Al)O. Upon reduction in H{sub 2} at temperatures above 673 K, bimetallic particles of PtIn are observed by TEM, which have an average diameter of 1 nm. Analysis of Pt LIII-edge extended X-ray absorption fine structure (EXAFS) data shows that the In content of the bimetallic particles increases with increasing bulk In/Pt ratio and reduction temperature. Pt LIII-edge X-ray absorption near edge structure (XANES) indicates that an increasing donation of electronic charge from In to Pt occurs with increasing In content in the PtIn particles. The activity and selectivity of the Pt/Mg(In)(Al)O catalysts for ethane and propane dehydrogenation reactions are strongly dependent on the bulk In/Pt ratio. For both reactants, maximum activity was achieved for a bulk In/Pt ratio of 0.48, and at this In/Pt ratio, the selectivity to alkene was nearly 100%. Coke deposition was observed after catalyst use for either ethane or propane dehydrogenation, and it was observed that the alloying of Pt with In greatly reduced the amount of coke deposited. Characterization of the deposit by Raman spectroscopy indicates that the coke is present as highly disordered graphite particles <30 nm in diameter. While the amount of coke deposited during ethane and propane dehydrogenation are comparable, the effects on activity are dependent on reactant composition. Coke deposition had no effect on ethane dehydrogenation activity, but caused a loss in propane dehydrogenation activity. This difference is attributed to the greater ease with which coke produced on the surface of PtIn nanoparticles migrates to the support during ethane dehydrogenation versus propane dehydrogenation.

  9. Effect of catalyst structure on oxidative dehydrogenation of ethane and propane on alumina-supported vanadia

    SciTech Connect (OSTI)

    Argyle, Morris D.; Chen, Kaidong; Bell, Alexis T.; Iglesia, Enrique

    2001-09-11T23:59:59.000Z

    The catalytic properties of Al2O3-supported vanadia with a wide range of VOx surface density (1.4-34.2 V/nm2) and structure were examined for the oxidative dehydrogenation of ethane and propane. UV-visible and Raman spectra showed that vanadia is dispersed predominantly as isolated monovanadate species below {approx}2.3 V/nm2. As surface densities increase, two-dimensional polyvanadates appear (2.3-7.0 V/nm2) along with increasing amounts of V2O5 crystallites at surface densities above 7.0 V/nm2. The rate constant for oxidative dehydrogenation (k1) and its ratio with alkane and alkene combustion (k2/k1 and k3/k1, respectively) were compared for both alkane reactants as a function of vanadia surface density. Propene formation rates (per V-atom) are {approx}8 times higher than ethene formation rates at a given reaction temperature, but the apparent ODH activation energies (E1) are similar for the two reactants and relatively insensitive to vanadia surface density. Ethene and propene formation rates (per V-atom) are strongly influenced by vanadia surface density and reach a maximum value at intermediate surface densities ({approx}8 V/nm2). The ratio of k2/k1 depends weakly on reaction temperature, indicating that activation energies for alkane combustion and ODH reactions are similar. The ratio of k2/k1 is independent of surface density for ethane, but increase slightly with vanadia surface density for propane, suggesting that isolated structures prevalent at low surface densities are slightly more selective for alkane dehydrogenation reactions. The ratio of k3/k1 decreases markedly with increasing reaction temperature for both ethane and propane ODH. Thus, the apparent activation energy for alkene combustion (E3) is much lower than that for alkane dehydrogenation (E1) and the difference between these two activation energies decreases with increasing surface density. The lower alkene selectivities observed at high vanadia surface densities are attributed to an increase in alkene adsorption enthalpies with increasing vanadia surface density. The highest yield of alkene is obtained for catalysts containing predominantly isolated monovanadate species and operated at high temperatures that avoid homogeneous reactions (< {approx} 800 K).

  10. Synergistic effect of mixing dimethyl ether with methane, ethane, propane, and ethylene fuels on polycyclic aromatic hydrocarbon and soot formation

    SciTech Connect (OSTI)

    Yoon, S.S. [Corporate Research and Development Division, Hyundai-Kia Motors, Gyeonggi-do 445-706 (Korea); Anh, D.H. [Korea Electric Power Research Institute, Daejeon 305-380 (Korea); Chung, S.H. [School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-742 (Korea)

    2008-08-15T23:59:59.000Z

    Characteristics of polycyclic aromatic hydrocarbon (PAH) and soot formation in counterflow diffusion flames of methane, ethane, propane, and ethylene fuels mixed with dimethyl ether (DME) have been investigated. Planar laser-induced incandescence and fluorescence techniques were employed to measure relative soot volume fractions and PAH concentrations, respectively. Results showed that even though DME is known to be a clean fuel in terms of soot formation, DME mixture with ethylene fuel increases PAH and soot formation significantly as compared to the pure ethylene case, while the mixture of DME with methane, ethane, and propane decreases PAH and soot formation. Numerical calculations adopting a detailed kinetics showed that DME can be decomposed to produce a relatively large number of methyl radicals in the low-temperature region where PAH forms and grows; thus the mixture of DME with ethylene increases CH{sub 3} radicals significantly in the PAH formation region. Considering that the increase in the concentration of O radicals is minimal in the PAH formation region with DME mixture, the enhancement of PAH and soot formation in the mixture flames of DME and ethylene can be explained based on the role of methyl radicals in PAH and soot formation. Methyl radicals can increase the concentration of propargyls, which could enhance incipient benzene ring formation through the propargyl recombination reaction and subsequent PAH growth. Thus, the result substantiates the importance of methyl radicals in PAH and soot formation, especially in the PAH formation region of diffusion flames. (author)

  11. Experimental and kinetic study of autoignition in methane/ethane/air and methane/propane/air mixtures under engine-relevant conditions

    SciTech Connect (OSTI)

    Huang, J.; Bushe, W.K. [Department of Mechanical Engineering, University of British Columbia, 6950 Applied Science Lane, Vancouver, British Columbia (Canada V6T 1Z4)

    2006-01-01T23:59:59.000Z

    The ignition delay of homogeneous methane/air mixtures enriched with small fractions of ethane/propane was measured using the reflected-shock technique at temperatures from 900 to 1400 K and pressures from 16 to 40 bar. The results show complex effects of ethane/propane on the ignition of methane, but a common trend observed with both hydrocarbons is an increased promotion effect for temperatures below 1100 K. A detailed kinetic mechanism was used to investigate the interaction between ethane/propane and the ignition chemistry of methane under the above conditions. It was found that at relatively low temperatures, the reactions between ethane/propane and methylperoxy (CH{sub 3}O{sub 2}) lead to an enhanced rate of formation of OH radicals in the initiation phase of the ignition. By systematically applying the quasi-steady-state assumptions to the intermediate species involved in the main reaction path identified, we have achieved an analytical description of the ignition process in the transitional temperature regime. The analytical solutions agree reasonably well with the detailed kinetic model and the experimental results for both ignition delay and concentrations of major intermediate species.

  12. Feasibility of reconstructing paleoatmospheric records of selected alkanes, methyl halides, and sulfur gases from Greenland ice cores

    E-Print Network [OSTI]

    Aydin, M.; Williams, M. B; Saltzman, E. S

    2007-01-01T23:59:59.000Z

    study of ethane and propane oxidation in the tropo- sphere,alkanes (ethane, C 2 H 6 ; propane, C 3 H 8 ; n-butane, n-Cfluid contamination. 4.1.2. Propane [ 24 ] Propane levels in

  13. Ethane enrichment and propane depletion in subsurface gases indicate gas hydrate occurrence in marine sediments at southern Hydrate Ridge offshore Oregon

    SciTech Connect (OSTI)

    Milkov, Alexei V.; Claypool, G E.; Lee, Young-Joo; Torres, Marta E.; Borowski, W S.; Tomaru, H; Sassen, Roger; Long, Philip E.

    2004-07-02T23:59:59.000Z

    The recognition of finely disseminated gas hydrate in deep marine sediments heavily depends on various indirect techniques because this mineral quickly decomposes upon recovery from in situ pressure and temperature conditions. Here, we discuss molecular properties of closely spaced gas voids (formed as a result of core recovery) and gas hydrates from an area of relatively low gas flux at the flanks of the southern Hydrate Ridge Offshore Oregon (ODP Sites 1244, 1245 and 1247).

  14. Airborne measurement of OH reactivity during INTEX-B

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    plus OH sign), reactiv- propane ing different gases gases atisoprene (plus sign), propane (star) and propene (triangle).NMHC includes ethane, ethene, propane, propene, i-butane, n-

  15. 9118 J. Am. Chem. SOC.1992, 114, 9118-9122 Propane Buwe

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    9118 J. Am. Chem. SOC.1992, 114, 9118-9122 Scheme 111 Propane Buwe X =CHI and Y = H lossofH2 Z = H-82-8; ethane, 74- 84-0; propane, 74-98-6;butane, 106-97-8. (28) The heats of formation for C3H2are the scaled

  16. Selective dehydrogenation of propane over novel catalytic materials

    SciTech Connect (OSTI)

    Sault, A.G.; Boespflug, E.P.; Martino, A.; Kawola, J.S.

    1998-02-01T23:59:59.000Z

    The conversion of small alkanes into alkenes represents an important chemical processing area; ethylene and propylene are the two most important organic chemicals manufactured in the U.S. These chemicals are currently manufactured by steam cracking of ethane and propane, an extremely energy intensive, nonselective process. The development of catalytic technologies (e.g., selective dehydrogenation) that can be used to produce ethylene and propylene from ethane and propane with greater selectivity and lower energy consumption than steam cracking will have a major impact on the chemical processing industry. This report details a study of two novel catalytic materials for the selective dehydrogenation of propane: Cr supported on hydrous titanium oxide ion-exchangers, and Pt nanoparticles encapsulated in silica and alumina aerogel and xerogel matrices.

  17. Propane on Titan

    E-Print Network [OSTI]

    H. G. Roe; T. K. Greathouse; M. J. Richter; J. H. Lacy

    2003-09-23T23:59:59.000Z

    We present the first observations of propane (C$_3$H$_8$) on Titan that unambiguously resolve propane features from other numerous stratospheric emissions. This is accomplished using a $R=\\lambda/\\delta\\lambda\\approx10^5$ spectrometer (TEXES) to observe propane's $\

  18. Nationwide: Southeast Propane Autogas Development Program Brings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Southeast Propane Autogas Development Program Brings 1200 Propane Vehicles to the Road Nationwide: Southeast Propane Autogas Development Program Brings 1200 Propane Vehicles to the...

  19. Boreal forest fire emissions in fresh Canadian smoke plumes: C1-C10 volatile organic compounds (VOCs), CO2, CO, NO2, NO, HCN and CH3CN

    E-Print Network [OSTI]

    2011-01-01T23:59:59.000Z

    propene, acetone, benzene, propane and ?-pinene (Table 1).cyanide Acetonitrile Ethane Propane i-Butane n-Butane i-= Ethane Ethane Ethane Ethane Propane Propane Propane ARCTAS

  20. Propane Vehicle Demonstration Grant Program

    SciTech Connect (OSTI)

    Jack Mallinger

    2004-08-27T23:59:59.000Z

    Project Description: Propane Vehicle Demonstration Grants The Propane Vehicle Demonstration Grants was established to demonstrate the benefits of new propane equipment. The US Department of Energy, the Propane Education & Research Council (PERC) and the Propane Vehicle Council (PVC) partnered in this program. The project impacted ten different states, 179 vehicles, and 15 new propane fueling facilities. Based on estimates provided, this project generated a minimum of 1,441,000 new gallons of propane sold for the vehicle market annually. Additionally, two new off-road engines were brought to the market. Projects originally funded under this project were the City of Portland, Colorado, Kansas City, Impco Technologies, Jasper Engines, Maricopa County, New Jersey State, Port of Houston, Salt Lake City Newspaper, Suburban Propane, Mutual Liquid Propane and Ted Johnson.

  1. The catalytic oxidation of propane 

    E-Print Network [OSTI]

    Sanderson, Charles Frederick

    1949-01-01T23:59:59.000Z

    THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

  2. The catalytic oxidation of propane

    E-Print Network [OSTI]

    Sanderson, Charles Frederick

    1949-01-01T23:59:59.000Z

    THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

  3. Residential propane price increases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05, 2014propane

  4. Residential propane prices available

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05,propane prices

  5. Residential propane prices decreases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05,propane prices5, 2014

  6. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05,propane prices5,

  7. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05,propane

  8. 2013 Propane Market Outlook

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032) -Less isNFebruary 2004AugustApril 20133 Audit2013 NUFOPlasma Propane

  9. NREL: Energy Analysis - Ethan Warner

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Saleshttp://www.fnal.gov/directorate/nalcal/nalcal02_07_05_files/nalcal.gifNRELPower SystemsDebbie Brodt-Giles PhotoEllaEricEthan

  10. Working Draft

    Office of Environmental Management (EM)

    gases-including nitrogen, carbon dioxide, hydrogen sulfide, methane, ethane, and propane-and butanes and other volatile liquids) composition, and flash gas composition....

  11. Quantum cascade laser investigations of CH4 and C2H2 interconversion in hydrocarbon/H2 gas mixtures during microwave plasma

    E-Print Network [OSTI]

    Bristol, University of

    described in Mankelevich et al. J. Appl. Phys. 104, 113304 2008 . The gas temperature distribution within source gases investigated methane, acetylene, ethane, propyne, propane, and butane are converted

  12. Liquid Propane Injection Technology Conductive to Today's North...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Conductive to Today's North American Specification Liquid Propane Injection Technology Conductive to Today's North American Specification Liquid propane injection...

  13. Propane - A Mid-Heating Season Assessment

    Reports and Publications (EIA)

    2001-01-01T23:59:59.000Z

    This report will analyze some of the factors leading up to the rapid increase in propane demand and subsequent deterioration in supply that propelled propane prices to record high levels during December and early January.

  14. Costs Associated With Propane Vehicle Fueling Infrastructure

    SciTech Connect (OSTI)

    Smith, M.; Gonzales, J.

    2014-08-01T23:59:59.000Z

    This document is designed to help fleets understand the cost factors associated with propane vehicle fueling infrastructure. It provides an overview of the equipment and processes necessary to develop a propane fueling station and offers estimated cost ranges.

  15. 1, 2341, 2001 OH + propane and

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 1, 23­41, 2001 OH + propane and iodopropanes S. A. Carl and J. N. Crowley Title Page Abstract + propane and iodopropanes S. A. Carl and J. N. Crowley Title Page Abstract Introduction Conclusions #12;ACPD 1, 23­41, 2001 OH + propane and iodopropanes S. A. Carl and J. N. Crowley Title Page Abstract

  16. Fuels outlook for oil/propane

    SciTech Connect (OSTI)

    Weigand, P.

    1995-09-01T23:59:59.000Z

    The outlook for using oil and propane as fuels is outlined. The following topics are discussed: factors affecting price of the burner tip, supply and demand forecast, distribution costs and availability, alternate fuels economics, propane prices, No. 2 oil prices, natural gas vs. 1% residual HP prices, and future for industrial oil and propane consumers.

  17. New thermodynamic diagrams developed for methane and ethane

    SciTech Connect (OSTI)

    Yaws, C.L.; Sheth, S.D.; Han, M. [Lamar Univ., Beaumont, TX (United States)

    1995-12-04T23:59:59.000Z

    Thermodynamic diagrams have been developed for methane and ethane. The diagrams determine volume and enthalpy as a function of pressure and temperature. The diagrams cover a wide range of conditions and are designed for ease of use. The enthalpy diagrams also contain constant-entropy lines, which allow engineers to solve second-law problems such as adiabatic expansion and fluid compression. Each diagram includes: a two-phase region for saturated liquid and vapor; a superheated gas region for gases at temperatures above the saturation temperature; a subcooled liquid region for liquids at temperatures below the saturation temperature; and a supercritical region for temperatures and pressures above the critical point. Representative engineering uses are illustrated in three examples.

  18. Selective adsorption of ethylene over ethane and propylene over propane in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch > TheNuclearHomeland ScienceInnovationScienceMaterials Centerthe

  19. Propane Market Model documentation report

    SciTech Connect (OSTI)

    Not Available

    1993-12-01T23:59:59.000Z

    The purpose of this report is to define the objectives of the Propane Market Model (PMM), describe its basic approach, and to provide details on model functions. This report is intended as a reference document for model analysts, users, and the general public. Documentation of the model is in accordance with EIA`s legal obligation to provide adequate documentation in support of its models. The PMM performs a short-term (6- to 9-months) forecast of demand and price for consumer-grad propane in the national US market; it also calculates the end-of-month stock level during the term of the forecast. Another part of the model allows for short-term demand forecasts for certain individual Petroleum Administration for Defense (PAD) districts. The model is used to analyze market behavior assumptions or shocks and to determine the effect on market price, demand, and stock level.

  20. Silane-propane ignitor/burner

    DOE Patents [OSTI]

    Hill, Richard W. (Livermore, CA); Skinner, Dewey F. (Livermore, CA); Thorsness, Charles B. (Livermore, CA)

    1985-01-01T23:59:59.000Z

    A silane propane burner for an underground coal gasification process which is used to ignite the coal and to controllably retract the injection point by cutting the injection pipe. A narrow tube with a burner tip is positioned in the injection pipe through which an oxidant (oxygen or air) is flowed. A charge of silane followed by a supply of fuel, such as propane, is flowed through the tube. The silane spontaneously ignites on contact with oxygen and burns the propane fuel.

  1. Silane-propane ignitor/burner

    DOE Patents [OSTI]

    Hill, R.W.; Skinner, D.F. Jr.; Thorsness, C.B.

    1983-05-26T23:59:59.000Z

    A silane propane burner for an underground coal gasification process which is used to ignite the coal and to controllably retract the injection point by cutting the injection pipe. A narrow tube with a burner tip is positioned in the injection pipe through which an oxidant (oxygen or air) is flowed. A charge of silane followed by a supply of fuel, such as propane, is flowed through the tube. The silane spontaneously ignites on contact with oxygen and burns the propane fuel.

  2. Comparison of Hydrogen and Propane Fuels (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2008-10-01T23:59:59.000Z

    Factsheet comparing the chemical, physical, and thermal properties of hydrogen and propane, designed to facilitate an understanding of the differences and similarites of the two fuels

  3. Comparison of Hydrogen and Propane Fuels (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2009-04-01T23:59:59.000Z

    Factsheet comparing the chemical, physical, and thermal properties of hydrogen and propane, designed to facilitate an understanding of the differences and similarites of the two fuels.

  4. Residential propane price decreases slightly

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05, 2014propane price

  5. Heating Oil and Propane Update - Energy Information Administration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Petroleum Reports Heating Oil and Propane Update Weekly heating oil and propane prices are only collected during the heating season, which extends from October through March....

  6. 29Counting Atoms in a Molecule The complex molecule Propanal

    E-Print Network [OSTI]

    29Counting Atoms in a Molecule The complex molecule Propanal was discovered in a dense interstellar is the ratio of carbon atoms to hydrogen atoms in propanal? Problem 4 - If the mass of a hydrogen atom of a propanal molecule in AMUs? Problem 5 - What is the complete chemical formula for propanal? C3 H __ O

  7. Alternative Fuel Tool Kit How to Implement: Propane

    E-Print Network [OSTI]

    1 08/2014 Alternative Fuel Tool Kit How to Implement: Propane Contents Introduction to Propane (LPG...........................................................................................................2 Benefits of Using Propane (LPG) for Transportation of Energy under Award Number DE-EE0006083. #12;2 08/2014 Introduction to Propane (LPG) for Transportation

  8. Evolutionary History of a Specialized P450 Propane Monooxygenase

    E-Print Network [OSTI]

    Arnold, Frances H.

    Evolutionary History of a Specialized P450 Propane Monooxygenase Rudi Fasan1 , Yergalem T-evolved P450 propane mono- oxygenase (P450PMO) having 20 heme domain substitutions compared to P450BM3 of propane activity. In contrast, refinement of the enzyme catalytic efficiency for propane oxidation (9000

  9. Propane vehicles : status, challenges, and opportunities.

    SciTech Connect (OSTI)

    Rood Werpy, M.; Burnham, A.; Bertram, K.; Energy Systems

    2010-06-17T23:59:59.000Z

    Propane as an auto fuel has a high octane value and has key properties required for spark-ignited internal combustion engines. To operate a vehicle on propane as either a dedicated fuel or bi-fuel (i.e., switching between gasoline and propane) vehicle, only a few modifications must be made to the engine. Until recently propane vehicles have commonly used a vapor pressure system that was somewhat similar to a carburetion system, wherein the propane would be vaporized and mixed with combustion air in the intake plenum of the engine. This leads to lower efficiency as more air, rather than fuel, is inducted into the cylinder for combustion (Myers 2009). A newer liquid injection system has become available that injects propane directly into the cylinder, resulting in no mixing penalty because air is not diluted with the gaseous fuel in the intake manifold. Use of a direct propane injection system will improve engine efficiency (Gupta 2009). Other systems include the sequential multi-port fuel injection system and a bi-fuel 'hybrid' sequential propane injection system. Carbureted systems remain in use but mostly for non-road applications. In the United States a closed-loop system is used in after-market conversions. This system incorporates an electronic sensor that provides constant feedback to the fuel controller to allow it to measure precisely the proper air/fuel ratio. A complete conversion system includes a fuel controller, pressure regulator valves, fuel injectors, electronics, fuel tank, and software. A slight power loss is expected in conversion to a vapor pressure system, but power can still be optimized with vehicle modifications of such items as the air/fuel mixture and compression ratios. Cold start issues are eliminated for vapor pressure systems since the air/fuel mixture is gaseous. In light-duty propane vehicles, the fuel tank is typically mounted in the trunk; for medium- and heavy-duty vans and trucks, the tank is located under the body of the vehicle. Propane tanks add weight to a vehicle and can slightly increase the consumption of fuel. On a gallon-to-gallon basis, the energy content of propane is 73% that of gasoline, thus requiring more propane fuel to travel an equivalent distance, even in an optimized engine (EERE 2009b).

  10. QER- Comment of National Propane Gas Association

    Broader source: Energy.gov [DOE]

    Ladies and Gentlemen: Please find attached the QER comments of the National Propane Gas Association. Please feel to contact us if we can provide further information. Thank you for your attention to our submission.

  11. Knoxville Area Transit: Propane Hybrid Electric Trolleys

    SciTech Connect (OSTI)

    Not Available

    2005-04-01T23:59:59.000Z

    A 2-page fact sheet summarizing the evaluation done by the U.S. Department of Energy's Advanced Vehicle Testing Activity on the Knoxville Area Transit's use of propane hybrid electric trolleys.

  12. QER- Comment of Propane Education & Research Council

    Broader source: Energy.gov [DOE]

    I plan to attend and ask a question of the Secretary regarding propane supply for the upcoming winter. Please do not hesitate to call or email if you have questions. Tucker Perkins

  13. Adsorption and Separation of Light Gases on an Amino-Functionalized Metal–Organic Framework: An Adsorption and In Situ XRD Study

    SciTech Connect (OSTI)

    Couck S.; Stavitski E.; Gobehiya, E.; Kirschhock, C.E.A.; Serra-Crespo, P.; Juan-Alcaniz, J.; Martinez Joaristi, A.; Gascon, J.; Kapteijn, F.; Baron, G. V.; Denayer J.F.M.

    2012-02-29T23:59:59.000Z

    The NH{sub 2}-MIL-53(Al) metal-organic framework was studied for its use in the separation of CO{sub 2} from CH{sub 4}, H{sub 2}, N{sub 2} C{sub 2}H{sub 6} and C{sub 3}H{sub 8} mixtures. Isotherms of methane, ethane, propane, hydrogen, nitrogen, and CO{sub 2} were measured. The atypical shape of these isotherms is attributed to the breathing properties of the material, in which a transition from a very narrow pore form to a narrow pore form and from a narrow pore form to a large pore form occurs, depending on the total pressure and the nature of the adsorbate, as demonstrated by in-situ XRD patterns measured during adsorption. Apart from CO{sub 2}, all tested gases interacted weakly with the adsorbent. As a result, they are excluded from adsorption in the narrow pore form of the material at low pressure. CO{sub 2} interacted much more strongly and was adsorbed in significant amounts at low pressure. This gives the material excellent properties to separate CO{sub 2} from other gases. The separation of CO{sub 2} from methane, nitrogen, hydrogen, or a combination of these gases has been demonstrated by breakthrough experiments using pellets of NH{sub 2}-MIL-53(Al). The effect of total pressure (1-30 bar), gas composition, temperature (303-403 K) and contact time has been examined. In all cases, CO{sub 2} was selectively adsorbed, whereas methane, nitrogen, and hydrogen nearly did not adsorb at all. Regeneration of the adsorbent by thermal treatment, inert purge gas stripping, and pressure swing has been demonstrated. The NH{sub 2}-MIL-53(Al) pellets retained their selectivity and capacity for more than two years.

  14. Hydrogen Safety Issues Compared to Safety Issues with Methane and Propane

    E-Print Network [OSTI]

    Green, Michael A.

    2005-01-01T23:59:59.000Z

    Issues with Methane and Propane Michael A. Green LawrenceSAFETY ISSUES WITH METHANE AND PROPANE M. A. Green Lawrencehydrogen. Methane and propane are commonly used by ordinary

  15. Propane Vehicle and Infrastructure Codes and Standards Citations (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2010-07-01T23:59:59.000Z

    This document lists codes and standards typically used for U.S. propane vehicle and infrastructure projects.

  16. Correlation between homogeneous propane pyrolysis and pyrocarbon deposition

    E-Print Network [OSTI]

    Boyer, Edmond

    Correlation between homogeneous propane pyrolysis and pyrocarbon deposition C´edric Descamps, G propane pyrolysis is studied in a 1-D hot-wall CVD furnace. The gas-phase pyrolysis is modelled in previous reports [6]: total pressure equal to 2 kPa, temperature between 900 K and 1400 K, and pure propane

  17. Study of the Low Temperature Oxidation of Propane Maximilien Cord

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Study of the Low Temperature Oxidation of Propane Maximilien Cord , Benoit Husson , Juan of China, Hefei, Anhui 230029, P. R. China Abstract The lowtemperature oxidation of propane oxidation of propane in the gas phase has been the subject of very few experimental studies, mainly

  18. Evolutionary History of a Specialized P450 Propane Monooxygenase

    E-Print Network [OSTI]

    Arnold, Frances H.

    Evolutionary History of a Specialized P450 Propane Monooxygenase Rudi Fasan1 , Yergalem T hydroxylase (P450BM3) to a laboratory-evolved P450 propane mono- oxygenase (P450PMO) having 20 heme domain substrate range and the emergence of propane activity. In contrast, refinement of the enzyme catalytic

  19. Portland Public School Children Move with Propane

    SciTech Connect (OSTI)

    Not Available

    2004-04-01T23:59:59.000Z

    This 2-page Clean Cities fact sheet describes the use of propane as a fuel source for Portland Public Schools' fleet of buses. It includes information on the history of the program, along with contact information for the local Clean Cities Coordinator and Portland Public Schools.

  20. The oxidative dehydrogenation of ethane with nitrous oxide by molybdenum oxide supported on silica gel

    E-Print Network [OSTI]

    Yang, Tsong-Jen

    1979-01-01T23:59:59.000Z

    pmole/min/g Ho for the formation of ethylene corresponds to a conversion of 0. 6% based on ethane. The steady state rates were low at temperatures less than 350 C, wnereas tne selectivity to ethylene (defined as mole ethylene/mole ethylene + 1/2 mole.... The rates of formation for C284 ( ~ ) and CO& (& ) as a function of temperature. Flow rates of gases: C~H8, 8. 4 ml/min; N~Q, 48. 8 ml/min. 15 g 12 0 0) c g 0 E ~6 300 325 350 375 400 425 450 T ('~) TABLE 1 Reactions of C 2H6 with N20 at Different...

  1. Titan's Prolific Propane: The Cassini CIRS Perspective

    E-Print Network [OSTI]

    Nixon, C A; Flaud, J -M; Bezard, B; Teanby, N A; Irwin, P G J; Ansty, T M; Coustenis, A; Vinatier, S; Flasar, F M; 10.1016/j.pss.2009.06.021

    2009-01-01T23:59:59.000Z

    In this paper we select large spectral averages of data from the Cassini Composite Infrared Spectrometer (CIRS) obtained in limb-viewing mode at low latitudes (30S--30N), greatly increasing the path length and hence signal-to-noise ratio for optically thin trace species such as propane. By modeling and subtracting the emissions of other gas species, we demonstrate that at least six infrared bands of propane are detected by CIRS, including two not previously identified in Titan spectra. Using a new line list for the range 1300-1400cm -1, along with an existing GEISA list, we retrieve propane abundances from two bands at 748 and 1376 cm-1. At 748 cm-1 we retrieve 4.2 +/- 0.5 x 10(-7) (1-sigma error) at 2 mbar, in good agreement with previous studies, although lack of hotbands in the present spectral atlas remains a problem. We also determine 5.7 +/- 0.8 x 10(-7) at 2 mbar from the 1376 cm-1 band - a value that is probably affected by systematic errors including continuum gradients due to haze and also an imperf...

  2. Electron attenuation in free, neutral ethane clusters

    SciTech Connect (OSTI)

    Winkler, M.; Harnes, J.; Børve, K. J., E-mail: Knut.Borve@kj.uib.no [Department of Chemistry, University of Bergen, NO-5007 Bergen (Norway); Myrseth, V. [Department of Physics and Technology, University of Bergen, NO-5007 Bergen (Norway)

    2014-10-28T23:59:59.000Z

    The electron effective attenuation length (EAL) in free, neutral ethane clusters has been determined at 40 eV kinetic energy by combining carbon 1s x-ray photoelectron spectroscopy and theoretical lineshape modeling. More specifically, theory is employed to form model spectra on a grid in cluster size (N) and EAL (?), allowing N and ? to be determined by optimizing the goodness-of-fit ?{sup 2}(N, ?) between model and observed spectra. Experimentally, the clusters were produced in an adiabatic-expansion setup using helium as the driving gas, spanning a range of 100–600 molecules in mean cluster size. The effective attenuation length was determined to be 8.4?±?1.9 Å, in good agreement with an independent estimate of 10 Å formed on the basis of molecular electron-scattering data and Monte Carlo simulations. The aggregation state of the clusters as well as the cluster temperature and its importance to the derived EAL value are discussed in some depth.

  3. Atmospheric Environment 39 (2005) 28292838 Diurnal and seasonal cycles of ozone precursors observed from

    E-Print Network [OSTI]

    Wingenter, Oliver W.

    characteristics. Ethane and propane, largely originated from leakage of natural gas or liquefied petroleum gases) and nitrogen oxides (NO+NO2 ¼ NOx), ozone is photochemically pro- duced and can accumulate to hazardous levels

  4. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1999 Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State (Thousand Gallons per Day) -...

  5. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    See footnotes at end of table. 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State 386 Energy Information...

  6. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1995 Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State (Thousand Gallons per Day) -...

  7. Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1998 Table 49. Prime Supplier Sales Volumes of Aviation Fuels, Propane, and Residual Fuel Oil by PAD District and State (Thousand Gallons per Day) -...

  8. Microsoft Word - Joe Rose - Providence remarks.propane.JUR -...

    Broader source: Energy.gov (indexed) [DOE]

    for propane consumers in acquiring adequate supply at affordable prices. Crop drying demand of 500% of last year's demand combined with heating demand of 20% above the...

  9. New insights into microbial responses to oil spills from the Deepwater Horizon incident

    E-Print Network [OSTI]

    Mason, O.U.

    2012-01-01T23:59:59.000Z

    C. J. Villanueva (2010). "Propane respiration jump-startsin samples that exhibited propane and ethane anomalies (loss of both ethane and propane relative to methane

  10. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, G.I.; Dietz, R.N.

    1994-04-05T23:59:59.000Z

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

  11. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

    1994-01-01T23:59:59.000Z

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

  12. Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum, and Tungsten Oxides

    E-Print Network [OSTI]

    Iglesia, Enrique

    Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum catalysts confirmed that oxidative dehydrogenation of propane occurs via similar pathways, which involve for propane dehydrogenation and for propene combustion increase in the sequence VOx/ZrO2

  13. CONTRIBUTION A L'TUDE DES FLAMMES D'HYDROCARBURES. PROPANE ET ACTYLNE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    CONTRIBUTION A L'ÉTUDE DES FLAMMES D'HYDROCARBURES. PROPANE ET ACÉTYLÈNE Par MM. JEAN VAN DER POLL du propane et de l'acétylène qui ont montré que, dans certains cas, les flammes oxy-propane et oxy

  14. Chemical evolution of volatile organic compounds in the outflow of the Mexico City Metropolitan area

    E-Print Network [OSTI]

    2010-01-01T23:59:59.000Z

    C-130 T0 T1 G1 Ethane Propane i-Butane n-Butane i-Pentane n-ppbv) Ethane Ethene Ethyne Propane Propene i-Butane n-Butanee.g. , ethane, ethene, propane, propane, methanol, ethanol,

  15. Finding the missing stratospheric Bry: a global modeling study of CHBr3 and CH2Br2

    E-Print Network [OSTI]

    2010-01-01T23:59:59.000Z

    C-130 T0 T1 G1 Ethane Propane i-Butane n-Butane i-Pentane n-ppbv) Ethane Ethene Ethyne Propane Propene i-Butane n-Butanee.g. , ethane, ethene, propane, propane, methanol, ethanol,

  16. Liquid Propane Injection Applications | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment ofLetterEconomy and EmissionsDepartment of EnergyLiquid propane

  17. Residential propane price decreases slightly decreases slightly

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05, 2014propane price7,

  18. Alternative Fuels Data Center: Propane Related Links

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNewPropane Printable Version Share this

  19. National propane safety week caps fifth anniversary of GAS Check

    SciTech Connect (OSTI)

    Prowler, S.

    1990-09-01T23:59:59.000Z

    This paper reports on National Propane Safety Week. The publicity encompassed everything from preventative maintenance to safe winter storage of cylinders. This campaign focused much of its attention on GAS (gas appliance system) Check, the propane industry's most well-known safety program.

  20. Safety evaluation for packaging (onsite) nitrogen trailers propane tanks

    SciTech Connect (OSTI)

    Ferrell, P.C.

    1998-01-28T23:59:59.000Z

    The purpose of the Safety Evaluation for Packaging (SEP) is the evaluation and authorization of the onsite transport of propane tanks that are mounted on the Lockheed Martin Hanford Corporation Characterization Project`s nitrogen trailers. This SEP authorizes onsite transport of the nitrogen trailers, including the propane tanks, until May 31, 1998. The three nitrogen trailers (HO-64-4966, HO-64-4968, and HO-64-5170) are rated for 1,361 kg (30,000 lb) and are equipped with tandem axles and pintel hitches. Permanently mounted on each trailer is a 5,678 L (1,500 gal) cryogenic dewar that is filled with nitrogen, and a propane fired water bath vaporizer system, and a 454 L (1 20 gal) propane tank. The nitrogen trailer system is operated only when it is disconnected from the tow vehicle and is leveled and stabilized. When the trailers are transported, the propane tanks are isolated via closed supply valves.

  1. High ethylene to ethane processes for oxidative coupling

    DOE Patents [OSTI]

    Chafin, Richard B. (Hurricane, WV); Warren, Barbara K. (Charleston, WV)

    1991-01-01T23:59:59.000Z

    Oxidative coupling of lower alkane to higher hydrocarbon is conducted using catalyst comprising barium and/or strontium component and a metal oxide combustion promoter in the presence of vapor phase halogen component. High ethylene to ethane mole ratios in the product can be obtained over extended operating periods.

  2. High ethylene to ethane processes for oxidative coupling

    DOE Patents [OSTI]

    Chafin, R.B.; Warren, B.K.

    1991-12-17T23:59:59.000Z

    Oxidative coupling of lower alkane to higher hydrocarbon is conducted using a catalyst comprising barium and/or strontium component and a metal oxide combustion promoter in the presence of vapor phase halogen component. High ethylene to ethane mole ratios in the product can be obtained over extended operating periods.

  3. Why Study Mineralogy? Perspective from Prof. Ethan Baxter on

    E-Print Network [OSTI]

    Baxter, Ethan F.

    Why Study Mineralogy? Perspective from Prof. Ethan Baxter on CAS ES 222 "Mineralogy" offered IN GEOSCIENCES · Mineralogy is a foundational course for students with broad geosciences interests. · Mineralogy is a recommended prerequisite for ES301 (Structural Geology) and ES424 (Petrology). · Mineralogy

  4. Sequestration of ethane in the cryovolcanic subsurface of Titan

    E-Print Network [OSTI]

    Olivier Mousis; Bernard Schmitt

    2008-02-07T23:59:59.000Z

    Saturn's largest satellite, Titan, has a thick atmosphere dominated by nitrogen and methane. The dense orange-brown smog hiding the satellite's surface is produced by photochemical reactions of methane, nitrogen and their dissociation products with solar ultraviolet, which lead primarily to the formation of ethane and heavier hydrocarbons. In the years prior to the exploration of Titan's surface by the Cassini-Huygens spacecraft, the production and condensation of ethane was expected to have formed a satellite-wide ocean one kilometer in depth, assuming that it was generated over the Solar system's lifetime. However, Cassini-Huygens observations failed to find any evidence of such an ocean. Here we describe the main cause of the ethane deficiency on Titan: cryovolcanic lavas regularly cover its surface, leading to the percolation of the liquid hydrocarbons through this porous material and its accumulation in subsurface layers built up during successive methane outgassing events. The liquid stored in the pores may, combined with the ice layers, form a stable ethane-rich clathrate reservoir, potentially isolated from the surface. Even with a low open porosity of 10% for the subsurface layers, a cryovolcanic icy crust less than 2300 m thick is required to bury all the liquid hydrocarbons generated over the Solar system's lifetime.

  5. LIQUID PROPANE GAS (LPG) STORAGE AREA BOILING LIQUID EXPANDING VAPOR EXPLOSION (BLEVE) ANALYSIS

    SciTech Connect (OSTI)

    PACE, M.E.

    2004-01-13T23:59:59.000Z

    The PHA and the FHAs for the SWOC MDSA (HNF-14741) identified multiple accident scenarios in which vehicles powered by flammable gases (e.g., propane), or combustible or flammable liquids (e.g., gasoline, LPG) are involved in accidents that result in an unconfined vapor cloud explosion (UVCE) or in a boiling liquid expanding vapor explosion (BLEVE), respectively. These accident scenarios are binned in the Bridge document as FIR-9 scenarios. They are postulated to occur in any of the MDSA facilities. The LPG storage area will be in the southeast corner of CWC that is relatively remote from store distaged MAR. The location is approximately 30 feet south of MO-289 and 250 feet east of 2401-W by CWC Gate 10 in a large staging area for unused pallets and equipment.

  6. Can propane school buses save money and provide other benefits...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Can propane school buses save money and provide other benefits? October 1, 2014 Tweet EmailPrint School districts across the country are looking for ways to save money and be more...

  7. VEE-0040- In the Matter of Western Star Propane, Inc.

    Broader source: Energy.gov [DOE]

    On February 18, 1997, Western Star Propane, Inc. (Western) filed an Application for Exception with the Office of Hearings and Appeals (OHA) of the Department of Energy (DOE). In its application,...

  8. VEE-0060- In the Matter of Blakeman Propane, Inc.

    Broader source: Energy.gov [DOE]

    On May 11, 1999, Blakeman Propane, Inc. (Blakeman) of Moorcroft, Wyoming, filed an Application for Exception with the Office of Hearings and Appeals (OHA) of the Department of Energy (DOE). In its...

  9. Residential home heating oil and propane survey, 1991--1992

    SciTech Connect (OSTI)

    Not Available

    1992-05-01T23:59:59.000Z

    This report contains pricing and consumption data on heating oils and propane for the Maine residential sector during the heating season 1991--1992. The information was gathered by survey. (VC)

  10. Dynamics of Propane in Silica Mesopores Formed upon Propylene Hydrogenation over Pt Nanoparticles by Time-Resolved FT-IR Spectroscopy

    E-Print Network [OSTI]

    Waslylenko, Walter; Frei, Heinz

    2008-01-01T23:59:59.000Z

    A steady state distribution of propane between gas andK). A steady state distribution of propane between gas phasesteady state distribution between propane inside and outside

  11. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi (Hoffman Estates, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL)

    1986-01-01T23:59:59.000Z

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  12. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.

    1986-08-19T23:59:59.000Z

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  13. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi (Hoffman Estates, IL)

    1986-01-01T23:59:59.000Z

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  14. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.; Kulkarni, S.S.

    1986-08-26T23:59:59.000Z

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  15. MOLECULAR SIMULATION OF PHASE EQUILIBRIA FOR WATER -METHANE AND WATER -ETHANE MIXTURES

    E-Print Network [OSTI]

    1 MOLECULAR SIMULATION OF PHASE EQUILIBRIA FOR WATER - METHANE AND WATER - ETHANE MIXTURES Jeffrey were used to calculate water - methane and water - ethane phase equilibria over a wide range and petrochemical industry, natural and petroleum gas production, and environmental control. For many

  16. Experimental studies of steam-propane injection for the Duri intermediate crude oil 

    E-Print Network [OSTI]

    Hendroyono, Arief

    2003-01-01T23:59:59.000Z

    Laboratory experimental studies were carried out to better understand production mechanisms involved in steam-propane injection and to investigate effects of expected field pressure and temperature conditions on steam-propane injection...

  17. Emissions from In-Use NG, Propane, and Diesel Fueled Heavy Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In-Use NG, Propane, and Diesel Fueled Heavy Duty Vehicles Emissions from In-Use NG, Propane, and Diesel Fueled Heavy Duty Vehicles Emissions tests of in-use heavy-duty vehicles...

  18. Consequences of propene and propane on plasma remediation of NOx Rajesh Doraia)

    E-Print Network [OSTI]

    Kushner, Mark

    Consequences of propene and propane on plasma remediation of NOx Rajesh Doraia) Department exhausts with hydrocarbons propane (C3H8) and propene (C3H6) has been investigated. In general

  19. Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and David H. Olson,

    E-Print Network [OSTI]

    Li, Jing

    Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene Kunhao Li, David H the first examples of MMOFs that are capable of kinetic separation of propane and propene (propylene), which

  20. Experimental studies of steam-propane injection for the Duri intermediate crude oil

    E-Print Network [OSTI]

    Hendroyono, Arief

    2003-01-01T23:59:59.000Z

    Laboratory experimental studies were carried out to better understand production mechanisms involved in steam-propane injection and to investigate effects of expected field pressure and temperature conditions on steam-propane injection...

  1. Alternative Fuels Data Center: Propane Powers Airport Shuttles in New

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropaneOrleans Propane

  2. Propane Vehicle and Infrastructure Codes and Standards Chart (Revised) (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-02-01T23:59:59.000Z

    This chart shows the SDOs responsible for leading the support and development of key codes and standards for propane.

  3. A KINETIC STUDY OF AEROBIC PROPANE UPTAKE AND COMETABOLIC DEGRADATION OF CHLOROFORM,

    E-Print Network [OSTI]

    Semprini, Lewis

    A KINETIC STUDY OF AEROBIC PROPANE UPTAKE AND COMETABOLIC DEGRADATION OF CHLOROFORM, CIS the behavior of different consortiums of aerobic propane-utilizing microorganisms, with respect to both the lag time for growth after exposure to propane, and their ability to transform three chlorinated aliphatic

  4. Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum Oxide Catalysts

    E-Print Network [OSTI]

    Iglesia, Enrique

    Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum of propane over ZrO2-supported MoOx catalysts. Competitive reactions of C3H6 and CH3 13 CH2CH3 showed combustion of propene, or by direct combustion of propane. A mixture of C3H8 and C3D8 undergoes oxidative

  5. Functional Characterization of Propane-Enhanced N-Nitrosodimethylamine Degradation by

    E-Print Network [OSTI]

    Alvarez-Cohen, Lisa

    ARTICLE Functional Characterization of Propane-Enhanced N-Nitrosodimethylamine Degradation by Two: Propane-induced cometabolic degradation of n-nitrosodimethylamine (NDMA) by two propanotrophs is characterized through kinetic, gene presence, and expression studies. After growth on propane, resting cells

  6. Ceramic microreactors for on-site hydrogen production from high temperature steam reforming of propane{

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    of propane{ Christian, Michael Mitchell and Paul J. A. Kenis* Received 31st May 2006, Accepted 10th August of propane into hydrogen at temperatures between 800 and 1000 uC. We characterized these microreactors. Kinetic analysis using a power law model showed reaction orders of 0.50 and 20.23 with respect to propane

  7. Fourier transform microwave spectrum of the propane-water complex: A prototypical water-hydrophobe system

    E-Print Network [OSTI]

    Cohen, Ronald C.

    Fourier transform microwave spectrum of the propane-water complex: A prototypical water) The Fourier transform microwave spectrum of the propane-water complex (C3H,-H,O) has been observed and analyzed. This spectrum includes transitions assigned to propane complexed with both the ortho and para

  8. Improved Product-Per-Glucose Yields in P450-Dependent Propane Biotransformations

    E-Print Network [OSTI]

    Arnold, Frances H.

    ARTICLE Improved Product-Per-Glucose Yields in P450-Dependent Propane Biotransformations Using propane monooxygenase prepared by directed evolu- tion [P450PMOR2; Fasan et al. (2007); Angew Chem Int Ed of the energy source (glucose) in the propane biotransformation com- pared to the native E. coli strain. Using

  9. Catalytic Properties of Supported MoO3 Catalysts for Oxidative Dehydrogenation of Propane

    E-Print Network [OSTI]

    Iglesia, Enrique

    Catalytic Properties of Supported MoO3 Catalysts for Oxidative Dehydrogenation of Propane Kaidong The effects of MoOx structure on propane oxidative dehydrogenation (ODH) rates and selectivity were examined with those obtained on MoOx/ZrO2. On MoOx/Al2O3 catalysts, propane turnover rate increased with increasing Mo

  10. High propylene/propane adsorption selectivity in a copper(catecholate)-decorated porous organic

    E-Print Network [OSTI]

    High propylene/propane adsorption selectivity in a copper(catecholate)-decorated porous organic and propane isotherms measured at ambient temperatures and ideal adsorption solution theory (IAST) calculations revealed increasing propylene/propane selectivities with increasing pressures. The eld of highly

  11. Layering and orientational ordering of propane on graphite: An experimental and simulation study

    E-Print Network [OSTI]

    Borguet, Eric

    Layering and orientational ordering of propane on graphite: An experimental and simulation study 2002; accepted 30 July 2002 We report the results of an experimental and theoretical study of propane and experiments show that propane adsorbs in a layer-by-layer fashion and exhibits continuous growth beyond

  12. Experimental Study of Propane-Fueled Pulsed Detonation Rocket Frank K. Lu,* Jason M. Meyers,

    E-Print Network [OSTI]

    Texas at Arlington, University of

    1 Experimental Study of Propane-Fueled Pulsed Detonation Rocket Frank K. Lu,* Jason M. Meyers in comparison to cases without the spiral. Tests through a range of cycle frequencies up to 20 Hz in oxygen-propane spiral in a pulsed detonation engine operating with propane and oxygen. A high-energy igniter is used

  13. Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation

    E-Print Network [OSTI]

    Jones, William D.

    Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation between] in interaction with propane. Two complexes have been found as minima coordinated through either a methyl the methylene complex of propane into a methyl complex of pro- pane. This latter reaction has a much lower

  14. Ionization Spectroscopy of Conformational Isomers of Propanal: The Origin of the Conformational Preference

    E-Print Network [OSTI]

    Kim, Sang Kyu

    Ionization Spectroscopy of Conformational Isomers of Propanal: The Origin of the Conformational conformational isomers of propanal, cis and gauche, are investigated by the vacuum-UV mass- analyzed thresholdV and 9.9516 ( 0.0006 eV, respectively. cis-Propanal, which is the more stable conformer in the neutral

  15. PROPANE -C3H8 MSDS (Document # 001045) PAGE 1 OF 8 MATERIAL SAFETY DATA SHEET

    E-Print Network [OSTI]

    Choi, Kyu Yong

    PROPANE - C3H8 MSDS (Document # 001045) PAGE 1 OF 8 MATERIAL SAFETY DATA SHEET Prepared to U in an emergency? 1. PRODUCT IDENTIFICATION CHEMICAL NAME; CLASS: PROPANE - C3H8 Document Number: 001045 PRODUCT IN AIR ACGIH OSHA TLV STEL PEL STEL IDLH OTHER ppm ppm ppm ppm ppm Propane 74-98-6 > 96.0 Simple

  16. Coleman Two Burner Stove The Coleman Matchlight 2-Burner Propane Stove is especially designed for outdoor

    E-Print Network [OSTI]

    Walker, Lawrence R.

    Coleman Two Burner Stove The Coleman Matchlight 2-Burner Propane Stove is especially designed-burner propane stove has a high-pressure regulator that ensures a constant flame regardless of weather propane stove has a removable nickel-chrome-plated grate that makes for easy cleaning. The aluminized

  17. Absorption du rayonnement 12 et 8 millimtres par les vapeurs de propane sous pression

    E-Print Network [OSTI]

    Boyer, Edmond

    Absorption du rayonnement 12 et 8 millimètres par les vapeurs de propane sous pression A. Battaglia des pertes diélectriques (03B5") présentées par le propane gazeux aux fréquences de 24 et 36 GHz, à la Birnbaum. Abstract. 2014 Experimental study of dielectric losses (03B5") presented by gaseous propane

  18. Dehydrogenation of Propane to Propylene over Supported Model NiAu Catalysts

    E-Print Network [OSTI]

    Goodman, Wayne

    Dehydrogenation of Propane to Propylene over Supported Model Ni­Au Catalysts Zhen Yan · Yunxi Yao 2012 Ó Springer Science+Business Media, LLC 2012 Abstract Hydrogenolysis and dehydrogenation of propane. For the conversionofpropane in the presence of hydrogen, the dehydrogenation of propane to propylene was observed onthe Ni

  19. Zeolitic imidazolate frameworks for kinetic separation of propane and propene

    SciTech Connect (OSTI)

    Li, Jing; Li, Kunhao; Olson, David H.

    2014-08-05T23:59:59.000Z

    Zeolitic Imidazolate Frameworks (ZIFs) characterized by organic ligands consisting of imidazole ligands that are either essentially all 2-chloroimidazole ligands or essentially all 2-bromoimidazole ligands are disclosed. Methods for separating propane and propene with the ZIFs of the present invention, as well as other ZIFs, are also disclosed.

  20. Experimental comparison of hot water/propane injection to steam/propane injection for recovery of heavy oil 

    E-Print Network [OSTI]

    Nesse, Thomas

    2005-02-17T23:59:59.000Z

    , attempts have been made to inject hot water instead of steam. The results have all been rather poor, the major problem being low sweep efficiency. The hot water just doesn?t enhance oil recovery enough. Adding propane to the steam injected in the reservoir...

  1. Experimental comparison of hot water/propane injection to steam/propane injection for recovery of heavy oil

    E-Print Network [OSTI]

    Nesse, Thomas

    2005-02-17T23:59:59.000Z

    , attempts have been made to inject hot water instead of steam. The results have all been rather poor, the major problem being low sweep efficiency. The hot water just doesn?t enhance oil recovery enough. Adding propane to the steam injected in the reservoir...

  2. Effect of a current polarisation on BIMEVOX membranes for oxidation of propane in a Catalytic Dense Membrane

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Effect of a current polarisation on BIMEVOX membranes for oxidation of propane in a Catalytic Dense of propane under OCV and under electrical bias. The propane conversion remained constantly equal to 12 by partial oxidation and oxidative dehydrogenation of propane, respectively. An anodic polarisation led

  3. Isotopic Tracer Studies of Propane Reactions on H-ZSM5 Zeolite Joseph A. Biscardi and Enrique Iglesia*

    E-Print Network [OSTI]

    Iglesia, Enrique

    Isotopic Tracer Studies of Propane Reactions on H-ZSM5 Zeolite Joseph A. Biscardi and Enrique unlabeled products from mixtures of propene and propane-2-13C reactants. Aromatic products of propane-2-13C-Parmer) that allowed differential reactor operation (propane reactions were

  4. Dead poets' society New England, the 1950s. Todd Anderson (Ethan Hawke), a lonely and painfully

    E-Print Network [OSTI]

    Schenato, Luca

    Dead poets' society New England, the 1950s. Todd Anderson (Ethan Hawke), a lonely and painfully shy in it. After seeing that Mr. Keating listed "Dead Poets Society" as one of his activities at the school

  5. Evaluation of ethane as a power conversion system working fluid for fast reactors

    E-Print Network [OSTI]

    Perez, Jeffrey A

    2008-01-01T23:59:59.000Z

    A supercritical ethane working fluid Brayton power conversion system is evaluated as an alternative to carbon dioxide. The HSC® chemical kinetics code was used to study thermal dissociation and chemical interactions for ...

  6. Greenhouse Gases | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Greenhouse Gases Greenhouse Gases Executive Order 13514 requires Federal agencies to inventory and manage greenhouse gas (GHG) emissions to meet Federal goals and mitigate climate...

  7. Experimental study on transmission of an overdriven detonation wave from propane/oxygen to propane/air

    SciTech Connect (OSTI)

    Li, J.; Lai, W.H. [National Cheng Kung University, Institute of Aeronautics and Astronautics, Tainan (China); Chung, K. [National Cheng Kung University, Aerospace Science and Technology Research Center, Tainan (China); Lu, F.K. [University of Texas at Arlington, Mechanical and Aerospace Engineering Department, Aerodynamics Research Center, TX 76019 (United States)

    2008-08-15T23:59:59.000Z

    Two sets of experiments were performed to achieve a strong overdriven state in a weaker mixture by propagating an overdriven detonation wave via a deflagration-to-detonation transition (DDT) process. First, preliminary experiments with a propane/oxygen mixture were used to evaluate the attenuation of the overdriven detonation wave in the DDT process. Next, experiments were performed wherein a propane/oxygen mixture was separated from a propane/air mixture by a thin diaphragm to observe the transmission of an overdriven detonation wave. Based on the characteristic relations, a simple wave intersection model was used to calculate the state of the transmitted detonation wave. The results showed that a rarefaction effect must be included to ensure that there is no overestimate of the post-transmission wave properties when the incident detonation wave is overdriven. The strength of the incident overdriven detonation wave plays an important role in the wave transmission process. The experimental results showed that a transmitted overdriven detonation wave occurs instantaneously with a strong incident overdriven detonation wave. The near-CJ state of the incident wave leads to a transmitted shock wave, and then the transition to the overdriven detonation wave occurs downstream. The attenuation process for the overdriven detonation wave decaying to a near-CJ state occurs in all tests. After the attenuation process, an unstable detonation wave was observed in most tests. This may be attributed to the increase in the cell width in the attenuation process that exceeds the detonability cell width limit. (author)

  8. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1999 421 Table A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) -...

  9. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1995 467 Table A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) -...

  10. Table 14. U.S. Propane (Consumer Grade) Prices by Sales Type

    U.S. Energy Information Administration (EIA) Indexed Site

    and EIA-782B, "Resellers'Retailers' Monthly Petroleum Product Sales Report." 14. U.S. Propane (Consumer Grade) Prices by Sales Type 28 Energy Information Administration ...

  11. Microsoft PowerPoint - Joe Rose.Providence.Propane Supply Infrastruct...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from the Gulf Coast. * Growth in Canadian demand for diluent (Pentanes+) demand for the oil sands industry. American Shale Production In 2013, U.S. Propane Production Increased...

  12. Dynamics of Propane in Silica Mesopores Formed upon Propylene Hydrogenation over Pt Nanoparticles by Time-Resolved FT-IR Spectroscopy

    E-Print Network [OSTI]

    Waslylenko, Walter; Frei, Heinz

    2008-01-01T23:59:59.000Z

    state distribution of propane between gas and mesopore phaseWavenumber (cm ) B Gas Phase Propane 2968 cm k 1 = 3.1 ± 0.4slices showing the gas phase propane component at 216, 648,

  13. Propane cold neutron source: creation and operation experience

    SciTech Connect (OSTI)

    Zemlyanov, M. G.

    1997-09-01T23:59:59.000Z

    In most cold neutron sources, utilized until recently, liquid hydrogen, liquid deuterium and their mixtures were used as a moderating medium. The sources with the liquid hydrogen moderator offer the most specific effectiveness of cold neutron generation. But they are complicated in design, require special safety measures in the course of operation and are very expensive. In this connection, it is of undoubted interest to create a source which, although it yields the specific generation of cold neutrons comparable to the liquid hydrogen one, is safer in operation and simple in design. We assume such a source may be one which uses as a moderator liquid propane cooled to liquid nitrogen temperature.

  14. Alternative Fuels Data Center: Michigan Converts Vehicles to Propane,

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduce OperatingPropane in OhioReducing

  15. Alternative Fuels Data Center: Propane Buses Shuttle Visitors in Maine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropane Buses Shuttle

  16. Alternative Fuels Data Center: Propane Fueling Infrastructure Development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropane Buses

  17. Alternative Fuels Data Center: Propane Fueling Station Locations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropane BusesStation

  18. Alternative Fuels Data Center: Propane Mowers Help National Park Cut

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropane

  19. Alternative Fuels Data Center: Propane Powers Fleets Across the Nation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNew HampshirePropaneOrleans

  20. Alternative Fuels Data Center: Propane School Buses Launched in Gloucester

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNewPropane Printable Version Share

  1. Alternative Fuels Data Center: Propane Tank Overfill Safety Advisory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNewPropane Printable Version

  2. Alternative Fuels Data Center: Propane Vans Keep Kansas City Transportation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNewPropane Printable VersionCompany

  3. Alternative Fuels Data Center: Renzenberger Inc Saves Money With Propane

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduceNewPropane PrintableTools

  4. Final report of the Rhode Island State Energy Office on residential no. 2 heating oil and propane prices [SHOPP

    SciTech Connect (OSTI)

    McClanahan, Janice

    2001-04-01T23:59:59.000Z

    Summary report on residential No.2 heating oil and propane prepared under grant. Summarizes the monitoring and analysis of heating oil and propane prices from October 2000 through March 2001.

  5. Experimental studies of steam-propane and enriched gas injection for the Minas light crude oil 

    E-Print Network [OSTI]

    Yudishtira, Wan Dedi

    2003-01-01T23:59:59.000Z

    Experimental studies were carried out to compare the benefits of propane as an additive in steam injection and in lean gas injection to enhance production for the Minas light crude oil (34?API). The studies on steam-propane were specifically...

  6. Further experimental studies of steam-propane injection to enhance recovery of Morichal oil 

    E-Print Network [OSTI]

    Ferguson,Mark Anthony

    2000-01-01T23:59:59.000Z

    In 1998-1999, experimental research was conducted by Goite at Texas A&M University into steam-propane injection to enhance oil recovery from the Morichal field, Venezuela. Goite's results showed that, compared with steam injection alone, steam-propane...

  7. Experimental studies of steam-propane injection to enhance recovery of an intermediate crude oil 

    E-Print Network [OSTI]

    Tinss, Judicael Christopher

    2001-01-01T23:59:59.000Z

    In the past few years, research has been conducted at Texas A&M University on steam-propane injection to enhance oil recovery from the Morichal field, Venezuela, which contains 13.5 ?API gravity oil. Experimental results show that a 5:100 propane...

  8. Experimental studies of steam-propane injection to enhance recovery of an intermediate crude oil

    E-Print Network [OSTI]

    Tinss, Judicael Christopher

    2001-01-01T23:59:59.000Z

    In the past few years, research has been conducted at Texas A&M University on steam-propane injection to enhance oil recovery from the Morichal field, Venezuela, which contains 13.5 ?API gravity oil. Experimental results show that a 5:100 propane...

  9. Further experimental studies of steam-propane injection to enhance recovery of Morichal oil

    E-Print Network [OSTI]

    Ferguson,Mark Anthony

    2000-01-01T23:59:59.000Z

    In 1998-1999, experimental research was conducted by Goite at Texas A&M University into steam-propane injection to enhance oil recovery from the Morichal field, Venezuela. Goite's results showed that, compared with steam injection alone, steam-propane...

  10. Experimental studies of steam-propane and enriched gas injection for the Minas light crude oil

    E-Print Network [OSTI]

    Yudishtira, Wan Dedi

    2003-01-01T23:59:59.000Z

    Experimental studies were carried out to compare the benefits of propane as an additive in steam injection and in lean gas injection to enhance production for the Minas light crude oil (34?API). The studies on steam-propane were specifically...

  11. State heating oil and propane program, 1994--1995 heating season. Final technical report

    SciTech Connect (OSTI)

    NONE

    1995-05-09T23:59:59.000Z

    Propane prices and No. 2 fuel prices during the 1994-1995 heating season are tabulated for the state of Ohio. Nineteen companies were included in the telephone survey of propane prices, and twenty two companies for the fuel oil prices. A bar graph is also presented for average residential prices of No. 2 heating oil.

  12. Chapter 46. Ultracold Quantum Gases Ultracold Quantum Gases

    E-Print Network [OSTI]

    of strongly interacting Fermi gases is important for the modeling of neutron stars. Cold atomic gases allow potential of the gas. Away from resonance another length scale comes into play, the scattering length a

  13. Syngas Production from Propane Using Atmospheric Non-thermal Plasma

    E-Print Network [OSTI]

    Ouni, Fakhreddine; Cormier, Jean Marie; 10.1007/s11090-009-9166-2

    2009-01-01T23:59:59.000Z

    Propane steam reforming using a sliding discharge reactor was investigated under atmospheric pressure and low temperature (420 K). Non-thermal plasma steam reforming proceeded efficiently and hydrogen was formed as a main product (H2 concentration up to 50%). By-products (C2-hydrocarbons, methane, carbon dioxide) were measured with concentrations lower than 6%. The mean electrical power injected in the discharge is less than 2 kW. The process efficiency is described in terms of propane conversion rate, steam reforming and cracking selectivity, as well as by-products production. Chemical processes modelling based on classical thermodynamic equilibrium reactor is also proposed. Calculated data fit quiet well experimental results and indicate that the improvement of C3H8 conversion and then H2 production can be achieved by increasing the gas fraction through the discharge. By improving the reactor design, the non-thermal plasma has a potential for being an effective way for supplying hydrogen or synthesis gas.

  14. Investigation of the flame speeds of propane/methanol gas mixtures

    SciTech Connect (OSTI)

    Foote, K.L.; Villareal, J.

    1985-05-02T23:59:59.000Z

    A series of tests was conducted in an acoustically tuned flame tube in order to determine the laminar burning velocities in air of various propane/methanol gas mixtures. The experimental method is explained in detail, along with the tabular results. A 90% propane, 10% methanol mixture is shown to have a maximum burning velocity of 40.8 cm/s. A 65% propane, 35% methanol mixture has a maximum velocity of 41.8 cm/s. These maximum flame speeds are shown to be about the same as that of pure propane by the same method. Gulder has found evidence that the presence of methanol in some hydrocarbon fuels may actually inhibit combustion, but we see no apparent modifications in the combustion of propane when mixed with methanol.

  15. Far-infrared laser vibration-rotation-tunneling spectroscopy of the propane-water compkx: Torsional dynamics of the hydrogen

    E-Print Network [OSTI]

    Cohen, Ronald C.

    Far-infrared laser vibration-rotation-tunneling spectroscopy of the propane-water compkx: Torsional 1993) The far-infrared laservibration-rotation-tunneling (FIR-VRT) spectrumof the propane-water complex calculations. In the present paper and in its counterpart,13we present our results for the water-propane

  16. Non-oxidative reactions of propane on Zn/Na-ZSM5 Joseph A. Biscardi and Enrique Iglesia*

    E-Print Network [OSTI]

    Iglesia, Enrique

    Non-oxidative reactions of propane on Zn/Na-ZSM5 Joseph A. Biscardi and Enrique Iglesia* Department rates during propane conversion at 773 K on Zn/Na-ZSM5 are about ten times higher than on Zn/H-ZSM5 catalysts with similar Zn content. The total rate of propane conversion is also higher on Zn/Na-ZSM5

  17. Modeling of the formation of short-chain acids in propane flames F. Battin-Leclerc , 1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Modeling of the formation of short-chain acids in propane flames F. Battin-Leclerc , 1 , A. Simulations of lean (equivalence ratios from 0.9 to 0.48) laminar premixed flames of propane stabilized in a combustion apparatus which can easily be modeled, a laminar premixed flame of propane at atmospheric pressure

  18. Kinetics and Reaction Pathways for Propane Dehydrogenation and Aromatization on Co/H-ZSM5 and H-ZSM5

    E-Print Network [OSTI]

    Iglesia, Enrique

    Kinetics and Reaction Pathways for Propane Dehydrogenation and Aromatization on Co/H-ZSM5 and H Co/H-ZSM5 catalyzes propane dehydrogenation and aromatization reactions. Initial product selectivities, product site-yields, and the 13C content and distribution in the products of 2-13C-propane show

  19. SURVEY OF THE LITERATURE ON THE CARBON-HYDROGEN SYSTEM

    E-Print Network [OSTI]

    Krakowski, R.A.

    2010-01-01T23:59:59.000Z

    one temperature and analyzed for propane for corr- osion-ratThe pyrolysis of ethane and propane at 2000 to 5000 0 K wasproduct was methane. Propane and The tempera- ethane

  20. Simulation of hydrogen and hydrogen-assisted propane ignition in Pt catalyzed microchannel

    SciTech Connect (OSTI)

    Seshadri, Vikram; Kaisare, Niket S. [Department of Chemical Engineering, Indian Institute of Technology - Madras, Chennai 600 036 (India)

    2010-11-15T23:59:59.000Z

    This paper deals with self-ignition of catalytic microburners from ambient cold-start conditions. First, reaction kinetics for hydrogen combustion is validated with experimental results from the literature, followed by validation of a simplified pseudo-2D microburner model. The model is then used to study the self-ignition behavior of lean hydrogen/air mixtures in a Platinum-catalyzed microburner. Hydrogen combustion on Pt is a very fast reaction. During cold start ignition, hydrogen conversion reaches 100% within the first few seconds and the reactor dynamics are governed by the ''thermal inertia'' of the microburner wall structure. The self-ignition property of hydrogen can be used to provide the energy required for propane ignition. Two different modes of hydrogen-assisted propane ignition are considered: co-feed mode, where the microburner inlet consists of premixed hydrogen/propane/air mixtures; and sequential feed mode, where the inlet feed is switched from hydrogen/air to propane/air mixtures after the microburner reaches propane ignition temperature. We show that hydrogen-assisted ignition is equivalent to selectively preheating the inlet section of the microburner. The time to reach steady state is lower at higher equivalence ratio, lower wall thermal conductivity, and higher inlet velocity for both the ignition modes. The ignition times and propane emissions are compared. Although the sequential feed mode requires slightly higher amount of hydrogen, the propane emissions are at least an order of magnitude lower than the other ignition modes. (author)

  1. An analysis of US propane markets, winter 1996-1997

    SciTech Connect (OSTI)

    NONE

    1997-06-01T23:59:59.000Z

    In late summer 1996, in response to relatively low inventory levels and tight world oil markets, prices for crude oil, natural gas, and products derived from both began to increase rapidly ahead of the winter heating season. Various government and private sector forecasts indicated the potential for supply shortfalls and sharp price increases, especially in the event of unusually severe winter weather. Following a rapid runup in gasoline prices in the spring of 1996, public concerns were mounting about a possibly similar situation in heating fuels, with potentially more serious consequences. In response to these concerns, the Energy Information Administration (EIA) participated in numerous briefings and meetings with Executive Branch officials, Congressional committee members and staff, State Energy Offices, and consumers. EIA instituted a coordinated series of actions to closely monitor the situation and inform the public. This study constitutes one of those actions: an examination of propane supply, demand, and price developments and trends.

  2. Absorption Equilibrium and Kinetics for Ethylene-Ethane Separation with a Novel Solvent

    E-Print Network [OSTI]

    Eldridge, R. Bruce

    mixture of ethylene/ethane, distillation towers with an enormous number of trays are operated at high integration present in a modern ethylene unit, the energy expen- diture is enormous, making up 6.2% of the total yearly energy requirement of all distillation processes.2 Despite the high capital and energy

  3. Reactor simulation of benzene ethylation and ethane dehydrogenation catalyzed by ZSM-5: A multiscale approach

    E-Print Network [OSTI]

    Bell, Alexis

    Reactor simulation of benzene ethylation and ethane dehydrogenation catalyzed by ZSM-5 Dehydrogenation a b s t r a c t Rate expressions are vital for analysis, design and operation of chemical reactors used the extended continuum model in the design equation of a fixed bed reactor and simulated

  4. Effect of temperature and pressure on the dynamics of nanoconfined propane

    SciTech Connect (OSTI)

    Gautam, Siddharth, E-mail: gautam.25@osu.edu; Liu, Tingting, E-mail: gautam.25@osu.edu; Welch, Susan; Cole, David [School of Earth Sciences, The Ohio State University, 275 Mendenhall Laboratory, 125 S Oval Mall, Columbus, OH 43210 (United States); Rother, Gernot [Geochemistry and Interfacial Science Group, Chemical Science Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Jalarvo, Niina [Jülich Center for Neutron Sciences (JCNS-1), Forschungszentrum Jülich Outstation at Spallation Neutron Source(SNS), Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Mamontov, Eugene [Spallation Neutron Source (SNS), Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States)

    2014-04-24T23:59:59.000Z

    We report the effect of temperature and pressure on the dynamical properties of propane confined in nanoporous silica aerogel studied using quasielastic neutron scattering (QENS). Our results demonstrate that the effect of a change in the pressure dominates over the effect of temperature variation on the dynamics of propane nano-confined in silica aerogel. At low pressures, most of the propane molecules are strongly bound to the pore walls, only a small fraction is mobile. As the pressure is increased, the fraction of mobile molecules increases. A change in the mechanism of motion, from continuous diffusion at low pressures to jump diffusion at higher pressures has also been observed.

  5. State heating oil and propane program: Final report. Survey of No.2 heating oil and propane prices at the retail level, October 1997 through March 1998

    SciTech Connect (OSTI)

    NONE

    1998-11-01T23:59:59.000Z

    The Energy Efficiency Division of the Vermont Department of Public Service (DPS) monitored the price and inventory of residential heating oil and propane during the 1997--98 heating season under a grant from the US Department of Energy`s Energy Information Administration (EIA). DPS staff collected data biweekly between October 5, 1997 and March 16, 1998 on the retail price of {number_sign}2 home heating oil and propane by telephone survey. Propane price quoted was based on the rate for a residential home heating customer using 1,000+ per year. The survey included a sample of fuel dealers selected by the EIA, plus additional dealers and fuels selected by the DPS. The EIA weighted, analyzed, and reported the data collected from their sample.

  6. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation 

    E-Print Network [OSTI]

    Jaiswal, Namit

    2007-09-17T23:59:59.000Z

    Simulation study has shown oil production is accelerated when propane is used as an additive during steam injection. To better understand this phenomenon, distillation experiments were performed using San Ardo crude oil (12oAPI). For comparison...

  7. Experimental study of Morichal heavy oil recovery using combined steam and propane injection 

    E-Print Network [OSTI]

    Goite Marcano, Jose Gregorio

    1999-01-01T23:59:59.000Z

    with steam (for the purpose of increasing steam recovery efficiency) are being evaluated. An experimental study has been performed to investigate the effect of combined steam and propane injection on recovery of heavy oil from the Morichal field, Venezuela...

  8. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam with propane-distillation 

    E-Print Network [OSTI]

    Ramirez Garnica, Marco Antonio

    2004-09-30T23:59:59.000Z

    Recent experimental and simulation studies -conducted at the Department of Petroleum Engineering at Texas A&M University - confirm oil production is accelerated when propane is used as an additive during steam injection. To better understand...

  9. Experimental study of Morichal heavy oil recovery using combined steam and propane injection

    E-Print Network [OSTI]

    Goite Marcano, Jose Gregorio

    1999-01-01T23:59:59.000Z

    with steam (for the purpose of increasing steam recovery efficiency) are being evaluated. An experimental study has been performed to investigate the effect of combined steam and propane injection on recovery of heavy oil from the Morichal field, Venezuela...

  10. Table A2. Refiner/Reseller Prices of Aviation Fuels, Propane...

    U.S. Energy Information Administration (EIA) Indexed Site

    - W 73.5 See footnotes at end of table. A2. RefinerReseller Prices of Aviation Fuels, Propane, and Kerosene, by PAD District, 1983-Present Energy Information Administration ...

  11. Analysis of tank deformation from fire induced ruptures and BLEVEs of 400 l propane tanks

    SciTech Connect (OSTI)

    Kielec, D.J.; Birk, A.M. [Queen`s Univ., Kingston, Ontario (Canada). Dept. of Mechanical Engineering

    1996-12-01T23:59:59.000Z

    A series of fire tests were conducted to study the thermal rupture of propane tanks. The tests involved 400 liter ASME automotive propane tanks filled to 80% capacity with commercial propane. The tanks were brought to failure using torches and pool fires. the resulting thermal ruptures varied in severity from minor fissures, measuring a few centimeters in length, to catastrophic failures where the tank was flattened on the ground. The catastrophic failures would typically be called Boiling Liquid Expanding Vapour Explosions (BLEVE). The objective of this work was to develop a correlation between the failure severity and the tank condition at failure. The deformed propane tanks were measured in detail and the extent of deformation was quantified. The tank failure severity was found to be a complex function of a number of tank and lading properties at failure. this paper presents the measured data from the tanks and a step by step description of how the correlation was determined.

  12. Analysis of fire-induced ruptures of 400-L propane tanks

    SciTech Connect (OSTI)

    Kielec, D.J.; Birk, A.M. [Queen`s Univ., Kingston, Ontario (Canada). Dept. of Mechanical Engineering

    1997-08-01T23:59:59.000Z

    A series of fire tests were conducted to study the thermal rupture of propane tanks. The tests involved 400-L ASME automotive propane tanks filled to 80% capacity with commercial propane. The tanks were brought to failure using torches and pool fires. The resulting thermal ruptures varied in severity from minor fissures, measuring a few centimeters in length, to catastrophic failures where the tank was flattened on the ground. The catastrophic failures would typically be called boiling liquid expanding vapor explosions (BLEVEs). The objective of this work was to develop a correlation between the failure severity and the tank condition at failure. The deformed propane tanks were measured in detail and the extent of deformation was quantified. The tank failure severity was found to be a complex function of a number of tank and lading properties at failure. This paper presents the measured data from the tanks and a step-by-step description of how the correlation was determined.

  13. Emissions from In-Use NG, Propane, and Diesel Fueled Heavy Duty...

    Broader source: Energy.gov (indexed) [DOE]

    Emissions from In-Use NG, Propane, and Diesel Fueled Heavy Duty Vehicles 2011 Directions in Engine-Efficiency and Emissions Research (DEER) October 3-6, 2011 Presented By: Kent...

  14. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation

    E-Print Network [OSTI]

    Jaiswal, Namit

    2007-09-17T23:59:59.000Z

    EXPERIMENTAL AND ANALYTICAL STUDIES OF HYDROCARBON YIELDS UNDER DRY-, STEAM-, AND STEAM-WITH- PROPANE DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University...-WITH- PROPANE-DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved...

  15. Etude cin\\'etique de CVD de pyrocarbone obtenu par pyrolyse de propane

    E-Print Network [OSTI]

    Ziegler-Devin, Isabelle; Marquaire, Paul-Marie

    2009-01-01T23:59:59.000Z

    High temeperature (900-1000\\degree C) low pressure (propane yields a pyrocarbon deposit, but also mainly hydrogen and hydrocarbons from methane to polyaromatics. 30 reaction products were exeperimentally quantified at different operating conditions. A detailed kinetic pyrolysis model (600 reactions) has been developed and validated based on the totality of experiments. This model includes a homogeneous model (describing the gas phase pyrolysis of propane) coupled with a heterogeneous model describing the pyrocarbon deposit.

  16. Control of pollutants in flue gases and fuel gases

    E-Print Network [OSTI]

    Laughlin, Robert B.

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1 2.2 Flue gases and fuel gases: combustion, gasification, pyrolysis, incineration and other and gasification technologies for heat and power . . . . . . . . 2-3 2.4 Waste incineration and waste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-3 3.3 Formation of sulphur compounds during combustion and gasification . 3-5 3.4 Emission

  17. DOI: 10.1002/cbic.200500261 Direct Conversion of Ethane to

    E-Print Network [OSTI]

    Arnold, Frances H.

    by a variety of transition metal catalysts, but these sys- tems produce mixtures containing significant amounts dioxygen from the air as the oxidant, and produce little or no hazardous waste. Biological systems have as propane.[8­10] Communication between the heme and reduc- tase domains of BM-3 is substrate

  18. Heat transfer coefficients for propane (R-290), isobutane (R-600a), and 50/50 mixture of propane and isobutane

    SciTech Connect (OSTI)

    Mathur, G.D. [Zexel USA Corp., Decatur, IL (United States)

    1998-12-31T23:59:59.000Z

    Tube-side heat transfer coefficients for single-phase flow, evaporation, and condensation are presented for propane (R-290), isobutane (R-600a), and a 50/50 mixture (by weight) of propane and isobutane. Heat transfer coefficients have been presented for smooth tubes based on the standard correlations available in the literature for pure refrigerants. The correlations for evaporation and condensation have previously been verified for R-12 and other refrigerants. The correlations for evaporation and condensation have previously been verified for R-12 and other refrigerants. The mass flux of the refrigerant is varied over a wide range that is typically encountered in residential, commercial, and automotive applications. Evaporation temperatures of {minus}6.7 C (20 F) and 4.4 C (40 F) and condensation temperatures of 37.8 C (100 F) and 48.9 C (120 F) have been used for this investigation. The heat transfer coefficients for hydrocarbons (R-290, R-600a, R-290/R-600a) have been compared with R-12 and R-134a. The REFPROP computer program developed by the National Institute of Standards and Technology (NIST) has been used to determine the thermodynamic properties for R-290, R-600a, and R-290/R-600a. This study shows that the heat transfer coefficients for hydrocarbons are significantly higher than those for both R-12 and R-134a. For the range of refrigerant temperatures and mass flux studied, single-phase vapor heat transfer coefficients for hydrocarbons are greater by 234% to 259% in comparison to R-12 and are greater by 167% to 181% in comparison to R-134a. The single-phase liquid heat transfer coefficients for hydrocarbons are greater by 193% to 245% in comparison to R-12; and are greater by 155% to 198% in comparison to R-134a. Average evaporative heat transfer coefficients for hydrocarbons are greater by 194% to 238% in comparison to R-12 and are greater by 157% to 192% in comparison to R-134a. Finally, average condensing coefficients are greater by 220% to 233% in comparison to R-12 and are greater by 177% to 187% in comparison to R-134a. Tables 3 through 6 show a summary of the heat transfer coefficient enhancement of the hydrocarbons in comparison to both R-12 and R-134a.

  19. AIRBORNE, OPTICAL REMOTE SENSNG OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2005-04-15T23:59:59.000Z

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. The scope of the work involved designing and developing an airborne, optical remote sensor capable of sensing methane and, if possible, ethane for the detection of natural gas pipeline leaks. Flight testing using a custom dual wavelength, high power fiber amplifier was initiated in February 2005. Ophir successfully demonstrated the airborne system, showing that it was capable of discerning small amounts of methane from a simulated pipeline leak. Leak rates as low as 150 standard cubic feet per hour (scf/h) were detected by the airborne sensor.

  20. Voluntary Reporting of Greenhouse Gases

    Reports and Publications (EIA)

    2011-01-01T23:59:59.000Z

    The Voluntary Reporting of Greenhouse Gases Program was suspended May 2011. It was a mechanism by which corporations, government agencies, individuals, voluntary organizations, etc., could report to the Energy Information Administration, any actions taken that have or are expected to reduce/avoid emissions of greenhouse gases or sequester carbon.

  1. Assessment of the risk of transporting propane by truck and train

    SciTech Connect (OSTI)

    Geffen, C.A.

    1980-03-01T23:59:59.000Z

    The risk of shipping propane is discussed and the risk assessment methodology is summarized. The risk assessment model has been constructed as a series of separate analysis steps to allow the risk to be readily reevaluated as additional data becomes available or as postulated system characteristics change. The transportation system and accident environment, the responses of the shipping system to forces in transportation accidents, and release sequences are evaluated to determine both the likelihood and possible consequences of a release. Supportive data and analyses are given in the appendices. The risk assessment results are related to the year 1985 to allow a comparison with other reports in this series. Based on the information presented, accidents involving tank truck shipments of propane will be expected to occur at a rate of 320 every year; accidents involving bobtails would be expected at a rate of 250 every year. Train accidents involving propane shipments would be expected to occur at a rate of about 60 every year. A release of any amount of material from propane trucks, under both normal transportation and transport accident conditions, is to be expected at a rate of about 110 per year. Releases from propane rail tank cars would occur about 40 times a year. However, only those releases that occur during a transportation accident or involve a major tank defect will include sufficient propane to present the potential for danger to the public. These significant releases can be expected at the lower rate of about fourteen events per year for truck transport and about one event every two years for rail tank car transport. The estimated number of public fatalities resulting from these significant releases in 1985 is fifteen. About eleven fatalities per year result from tank truck operation, and approximately half a death per year stems from the movement of propane in rail tank cars.

  2. Survey and assessment of the effects of nonconventional gases on gas distribution equipment

    SciTech Connect (OSTI)

    Jasionowski, W.J.; Scott, M.I.; Gracey, W.C.

    1982-10-01T23:59:59.000Z

    A literature search and a survey of the gas industry were conducted to assess potential problems in the distribution of nonconventional gases. Available literature did not uncover data that would describe potential problems or substantiate the presence of harmful trace elements in final gas compositions produced from various SNG processes. Information from the survey indicates that some companies have encountered problems with nonconventional gases and extraneous additives such as landfill gas, refinery off-gases, oil gas, carbureted water gas, coke-oven gas, propane-air, and compressor lubricant oils. These nonconventional gases and compressor oils may 1) cause pipeline corrosion, 2) degrade some elastomeric materials and greases and affect the integrity of seals, gaskets, O-rings, and meter and regulator diaphragms, and 3) cause operational and safety problems. The survey indicated that 62% of the responding companies plan to use supplemental gas, with most planning on more than one type. Distribution companies intend to significantly increase their use of polyethylene piping from 11.6% in 1980 to 22.4% in 2000 for gas mains and from 33.4% to 50.3% in 2000 for gas service lines.

  3. Lean and ultralean stretched propane-air counterflow flames

    SciTech Connect (OSTI)

    Cheng, Zhongxian; Pitz, Robert W. [Mechanical Engineering Department, Vanderbilt University, Box 1592, Station B, Nashville, TN 37235 (United States); Wehrmeyer, Joseph A. [Aerospace Testing Alliance, Building 1099, Avenue C, Arnold Air Force Base, TN 37389 (United States)

    2006-06-15T23:59:59.000Z

    Stretched laminar flame structures for a wide range of C{sub 3}H{sub 8}-air mixtures vs hot products are investigated by laser-based diagnostics and numerical simulation. The hot products are produced by a lean H{sub 2}-air premixed flame. The effect of stretch rate and equivalence ratio on four groups of C{sub 3}H{sub 8}-air flame structures is studied in detail by Raman scattering measurements and by numerical calculations of the major species concentration and temperature profiles. The equivalence ratio, f, is varied from a near-stoichiometric condition (f=0.86) to the sublean limit (f=0.44) and the stretch rate varies from 90 s{sup -1} to near extinction. For most of these C{sub 3}H{sub 8}-air lean mixtures, hot products are needed to maintain the flame. The significant feature of these flames is the relatively low flame temperatures (1200-1800 K). For this temperature range, the predicted C{sub 3}H{sub 8}-air flame structure is sensitive to the specific chemical kinetic mechanism. Two types of flame structures (a lean self-propagating flame and a lean diffusion-controlled flame) are obtained based on the combined effect of stretch and equivalence ratio. Three different mechanisms, the M5 mechanism, the Optimized mechanism, and the San Diego mechanism, are chosen for the numerical simulations. None of the propane chemical mechanisms give good agreement with the data over the entire range of flame conditions. (author)

  4. No. 2 heating oil/propane program 1994--1995. Final report

    SciTech Connect (OSTI)

    McBrien, J.

    1995-05-01T23:59:59.000Z

    During the 1994--95 heating season, the Massachusetts Division of Energy Resources (DOER) participated in a joint data collection program between several state energy offices and the federal Department of Energy`s (DOE) Energy Information Administration (EIA). The purpose of the program was to collect and monitor retail and wholesale heating oil and propane prices and inventories from October 1994 through March 1995. This program augmented the existing Massachusetts data collection system and served several important functions. The information helped the federal and state governments respond to consumer, congressional and media inquiries regarding No. 2 oil and propane. The information also provided policy decision-makers with timely, accurate and consistent data to monitor current heating oil and propane markets and develop appropriate state responses when necessary. In addition, the communication network between states and the DOE was strengthened through this program. This final report begins with an overview of the unique events that had an impact on the petroleum markets prior to and during the reporting period. Next, the report summarizes the results from residential heating oil and propane price surveys conducted by DOER over the 1994--95 heating season. The report also incorporates the wholesale heating oil and propane prices and inventories collected by EIA and distributed to the states. Finally, the report outlines DOER`s use of the data.

  5. State Heating Oil & Propane Program. Final report 1997/98 heating season

    SciTech Connect (OSTI)

    Hunton, G.

    1998-06-01T23:59:59.000Z

    The following is a summary report of the New Hampshire Governor`s Office of Energy and Community Services (ECS) participation in the State Heating Oil and Propane Program (SHOPP) for the 1997/98 heating season. SHOPP is a cooperative effort, linking energy offices in East Coast and Midwest states, with the Department of Energy (DOE), Energy Information Administration (EIA) for the purpose of collecting retail price data for heating oil and propane. The program is funded by the participating state with a matching grant from DOE. SHOPP was initiated in response to congressional inquires into supply difficulties and price spikes of heating oil and propane associated with the winter of 1989/90. This is important to New Hampshire because heating oil controls over 55% of the residential heating market statewide. Propane controls 10% of the heating market statewide and is widely used for water heating and cooking in areas of the state where natural gas is not available. Lower installation cost, convenience, lower operating costs compared to electricity, and its perception as a clean heating fuel have all worked to increase the popularity of propane in New Hampshire and should continue to do so in the future. Any disruption in supply of these heating fuels to New Hampshire could cause prices to skyrocket and leave many residents in the cold.

  6. Improved correlations for retrograde gases 

    E-Print Network [OSTI]

    Crogh, Arne

    1996-01-01T23:59:59.000Z

    Three correlations for retrograde gases have been developed. First, a correlation was developed that relates the composition of a retrograde gas-condensate mixture at any depletion stage to the composition at its dew point ...

  7. Guidance Document CompressedGases

    E-Print Network [OSTI]

    electricity. Oxygen by itself does not burn, but it will support or accelerate combustion of flammable the regulator is completely closed. 3. When possible use flammable and reactive gases in a fume hood. Certain

  8. No. 2 heating oil/propane program. Final report, 1992/93

    SciTech Connect (OSTI)

    McBrien, J.

    1993-05-01T23:59:59.000Z

    During the 1992--93 heating season, the Massachusetts Division Energy Resources (DOER) participated in a joint data collection program between several state energy offices and the federal Department of Energy`s (DOE) Energy Information Administration (EIA). The purpose of the program was to collect and monitor retail and wholesale heating oil and propane prices and inventories from October, 1992 through March, 1993. This final report begins with an overview of the unique events which had an impact on the petroleum markets prior to and during the reporting period. Next, the report summarizes the results from residential heating oil and propane price surveys conducted by DOER over the 1992--93 heating season. The report also incorporates the wholesale heating oil and propane prices and inventories collected by the EIA and distributed to the states. Finally, the report outlines DOER`s use of the data.

  9. Clean Fuel Advanced Technology Public Education Campaign: Billboards According to the U.S. Department of Energy's July 2013 alternative fuel price report, the price of propane

    E-Print Network [OSTI]

    .S. Department of Energy's July 2013 alternative fuel price report, the price of propane (LPG) in North Carolina at least $1,000 in yearly fuel costs by driving on natural gas or propane. · According to the U

  10. Performance analysis of a series of hermetic reciprocating compressors working with R290 (propane) and R407C

    E-Print Network [OSTI]

    Fernández de Córdoba, Pedro

    Performance analysis of a series of hermetic reciprocating compressors working with R290 (propane Abstract In this paper, a series of compressors with different capacities and geometries working with propane as refrigerant are analyzed in terms of the compressor model developed by [E. Navarro, E. Granryd

  11. The determination of compressibility factors of gaseous propane-nitrogen mixtures 

    E-Print Network [OSTI]

    Hodges, Don

    1952-01-01T23:59:59.000Z

    of thc Beg;voc cf kBSTBACT The propane-nitrogen system has been investigated in the gaseous phase at a temperature of 300 F. and at pressures up to 4/0 atmospheres. Compressibility curves for three mixtures of this system have been determined. A... the pressure corresponding to the "n " expansion ? th? the partial pressure of nitrogen the partial pressure oi' propane the total pressure of a gaseous system the universal gas constant (0. 08206 liter-atmosphere/ gram mole - oK) the absolute...

  12. The determination of compressibility factors of gaseous propane-nitrogen mixtures 

    E-Print Network [OSTI]

    Dickson, Cecil Herman

    1955-01-01T23:59:59.000Z

    LIBRARY A A N O'iLLEOE OF 1EXAS THE DETERMINATION OF COMPRESSIBILITY FACTORS OF GASEOUS PROPANE-NITROGEIN MIXTURES A Thesis Cecil Herman Dickson Submitted to the Graduate School of the Agricultural and Mechanical College of' Texas in partial... f'ulf'illment of the requirements for the de~ree of MASTER OF SCIENCE Ma]or GubjectI Chemistry May I&55 THE DETERMINATION OF COMPRESSIBILITY FACTORS OF GASEOUS PROPANE-NITROGEN MIXTURES A Thesis Cecil Herman Dickson Approved as to style...

  13. The determination of compressibility factors of gaseous propane-nitrogen mixtures

    E-Print Network [OSTI]

    Dickson, Cecil Herman

    1955-01-01T23:59:59.000Z

    LIBRARY A A N O'iLLEOE OF 1EXAS THE DETERMINATION OF COMPRESSIBILITY FACTORS OF GASEOUS PROPANE-NITROGEIN MIXTURES A Thesis Cecil Herman Dickson Submitted to the Graduate School of the Agricultural and Mechanical College of' Texas in partial... f'ulf'illment of the requirements for the de~ree of MASTER OF SCIENCE Ma]or GubjectI Chemistry May I&55 THE DETERMINATION OF COMPRESSIBILITY FACTORS OF GASEOUS PROPANE-NITROGEN MIXTURES A Thesis Cecil Herman Dickson Approved as to style...

  14. The determination of compressibility factors of gaseous propane-nitrogen mixtures

    E-Print Network [OSTI]

    Hodges, Don

    1952-01-01T23:59:59.000Z

    of thc Beg;voc cf kBSTBACT The propane-nitrogen system has been investigated in the gaseous phase at a temperature of 300 F. and at pressures up to 4/0 atmospheres. Compressibility curves for three mixtures of this system have been determined. A... the pressure corresponding to the "n " expansion ? th? the partial pressure of nitrogen the partial pressure oi' propane the total pressure of a gaseous system the universal gas constant (0. 08206 liter-atmosphere/ gram mole - oK) the absolute...

  15. SUR LA POSSIBILIT D'UTILISATION D'UNE CHAMBRE A BULLES A PROPANE POUR L'TUDE DES RACTIONS NUCLAIRES

    E-Print Network [OSTI]

    Boyer, Edmond

    175 A. SUR LA POSSIBILITÉ D'UTILISATION D'UNE CHAMBRE A BULLES A PROPANE POUR L'ÉTUDE DES RÉACTIONS. - Mise au point et étude des caractéristiques du fonctionnement d'une chambre à bulles à propane de 6 135 MeV. Abstract. 2014 Adjustment and studies of some characteristics of a 6 litre propane bubble

  16. Single-Site Vanadyl Activation, Functionalization, and Reoxidation Reaction Mechanism for Propane Oxidative Dehydrogenation on the Cubic V4O10 Cluster

    E-Print Network [OSTI]

    Goddard III, William A.

    Single-Site Vanadyl Activation, Functionalization, and Reoxidation Reaction Mechanism for Propane of density functional theory) to examine the detailed mechanism for propane reacting with a V4O10 cluster to model the catalytic oxidative dehydrogenation (ODH) of propane on the V2O5(001) surface. We here report

  17. Structure and critical function of Fe and acid sites in Fe-ZSM-5 in propane oxidative dehydrogenation with N2O and N2O decomposition

    E-Print Network [OSTI]

    Sklenak, Stepan

    Structure and critical function of Fe and acid sites in Fe-ZSM-5 in propane oxidative species Steamed Fe-zeolites Mössbauer spectroscopy UV­Vis FTIR H2-TPR N2O decomposition Propane oxidative of propane to propene with N2O. The evacuated non-steamed FeH-ZSM-5 contained high concentration of Brønsted

  18. Simulation studies of steam-propane injection for the Hamaca heavy oil field 

    E-Print Network [OSTI]

    Venturini, Gilberto Jose

    2002-01-01T23:59:59.000Z

    Simulation studies were performed to evaluate a novel technology, steam-propane injection, for the heavy Hamaca crude oil. The oil has a gravity of 9.3?API and a viscosity of 25,000 cp at 50?C. Two types of simulation studies were performed: a...

  19. Metallurgical failure analysis of a propane tank boiling liquid expanding vapor explosion (BLEVE).

    SciTech Connect (OSTI)

    Kilgo, Alice C.; Eckelmeyer, Kenneth Hall; Susan, Donald Francis

    2005-01-01T23:59:59.000Z

    A severe fire and explosion occurred at a propane storage yard in Truth or Consequences, N.M., when a truck ran into the pumping and plumbing system beneath a large propane tank. The storage tank emptied when the liquid-phase excess flow valve tore out of the tank. The ensuing fire engulfed several propane delivery trucks, causing one of them to explode. A series of elevated-temperature stress-rupture tears developed along the top of a 9800 L (2600 gal) truck-mounted tank as it was heated by the fire. Unstable fracture then occurred suddenly along the length of the tank and around both end caps, along the girth welds connecting the end caps to the center portion of the tank. The remaining contents of the tank were suddenly released, aerosolized, and combusted, creating a powerful boiling liquid expanding vapor explosion (BLEVE). Based on metallography of the tank pieces, the approximate tank temperature at the onset of the BLEVE was determined. Metallurgical analysis of the ruptured tank also permitted several hypotheses regarding BLEVE mechanisms to be evaluated. Suggestions are made for additional work that could provide improved predictive capabilities regarding BLEVEs and for methods to decrease the susceptibility of propane tanks to BLEVEs.

  20. Simulation studies of steam-propane injection for the Hamaca heavy oil field

    E-Print Network [OSTI]

    Venturini, Gilberto Jose

    2002-01-01T23:59:59.000Z

    Simulation studies were performed to evaluate a novel technology, steam-propane injection, for the heavy Hamaca crude oil. The oil has a gravity of 9.3?API and a viscosity of 25,000 cp at 50?C. Two types of simulation studies were performed: a...

  1. Syngas Production from Propane using Atmospheric Non-Thermal Plasma F. Ouni, A. Khacef*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Syngas Production from Propane using Atmospheric Non-Thermal Plasma F. Ouni, A. Khacef* and J. M applications (1, 2) . Synthesis gas or syngas (mixture of hydrogen and carbon monoxide) are used as a major. The conventional reformers allowing syngas production are based on steam reforming of hydrocarbons (3) following

  2. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2003-11-12T23:59:59.000Z

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. This second six-month technical report summarizes the progress made towards defining, designing, and developing the hardware and software segments of the airborne, optical remote methane and ethane sensor. The most challenging task to date has been to identify a vendor capable of designing and developing a light source with the appropriate output wavelength and power. This report will document the work that has been done to identify design requirements, and potential vendors for the light source. Significant progress has also been made in characterizing the amount of light return available from a remote target at various distances from the light source. A great deal of time has been spent conducting laboratory and long-optical path target reflectance measurements. This is important since it helps to establish the overall optical output requirements for the sensor. It also reduces the relative uncertainty and risk associated with developing a custom light source. The data gathered from the optical path testing has been translated to the airborne transceiver design in such areas as: fiber coupling, optical detector selection, gas filters, and software analysis. Ophir will next, summarize the design progress of the transceiver hardware and software development. Finally, Ophir will discuss remaining project issues that may impact the success of the project.

  3. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPLINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2004-05-12T23:59:59.000Z

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. The third six-month technical report contains a summary of the progress made towards finalizing the design and assembling the airborne, remote methane and ethane sensor. The vendor has been chosen and is on contract to develop the light source with the appropriate linewidth and spectral shape to best utilize the Ophir gas correlation software. Ophir has expanded upon the target reflectance testing begun in the previous performance period by replacing the experimental receiving optics with the proposed airborne large aperture telescope, which is theoretically capable of capturing many times more signal return. The data gathered from these tests has shown the importance of optimizing the fiber optic receiving fiber to the receiving optic and has helped Ophir to optimize the design of the gas cells and narrowband optical filters. Finally, Ophir will discuss remaining project issues that may impact the success of the project.

  4. A Minimum Free Energy Reaction Path for the E2 Reaction between Fluoro Ethane and a Fluoride Ion

    E-Print Network [OSTI]

    Nielsen, Steven O.

    A Minimum Free Energy Reaction Path for the E2 Reaction between Fluoro Ethane and a Fluoride Ion, such as the mechanism and the free-energy profile, remains an important challenge not only for enzyme catalysis1 of the reaction free-energy profile is very cumbersome with constrained molecular dynamics (MD) and umbrella

  5. Ethan Frome

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells, Wisconsin:DeploymentSite Name: Email: Terminal2,7,7,of2014

  6. AIRBORNE, OPTICAL REMOTE SENSING OF METHANE AND ETHANE FOR NATURAL GAS PIPELINE LEAK DETECTION

    SciTech Connect (OSTI)

    Jerry Myers

    2003-05-13T23:59:59.000Z

    Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. This six-month technical report summarizes the progress for each of the proposed tasks, discusses project concerns, and outlines near-term goals. Ophir has completed a data survey of two major natural gas pipeline companies on the design requirements for an airborne, optical remote sensor. The results of this survey are disclosed in this report. A substantial amount of time was spent on modeling the expected optical signal at the receiver at different absorption wavelengths, and determining the impact of noise sources such as solar background, signal shot noise, and electronic noise on methane and ethane gas detection. Based upon the signal to noise modeling and industry input, Ophir finalized the design requirements for the airborne sensor, and released the critical sensor light source design requirements to qualified vendors. Responses from the vendors indicated that the light source was not commercially available, and will require a research and development effort to produce. Three vendors have responded positively with proposed design solutions. Ophir has decided to conduct short path optical laboratory experiments to verify the existence of methane and absorption at the specified wavelength, prior to proceeding with the light source selection. Techniques to eliminate common mode noise were also evaluated during the laboratory tests. Finally, Ophir has included a summary of the potential concerns for project success and has established future goals.

  7. Thermophysical property predictions of propane, propylene and their mixtures by Benedict-Webb-Rubin type equations of state 

    E-Print Network [OSTI]

    Bengani, Pramod Kumar

    1990-01-01T23:59:59.000Z

    THERMOPHYSICAL PROPERTY PREDICTIONS OF PROPANE, PROPYLENE AND THEIR MIXTURES BY BENEDICT-WEBB-RUBIN TYPE EQUATIONS OF STATE A Thesis by PRAMOD KUMAR BENGANI Submitted to the Office of Graduate Studies of Texas A & M University in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1990 Major Subject: Chemical Engineering THERMOPHYSICAL PROPERTY PREDICTIONS OF PROPANE, PROPYLENE AND THEIR MIXTURES BY BENEDICT-WEBB-RUBIN TYPE EQUATIONS OF STATE A Thesis...

  8. SCADA system aids BGE`s Notch Cliff propane-air facility

    SciTech Connect (OSTI)

    Miller, B.A. [Baltimore Gas and Electric Co., MD (United States)

    1997-02-01T23:59:59.000Z

    SCADA systems in the natural gas industry are commonly associated with distribution networks and transmission pipelines. There is however, another application for SCADA technology that is increasingly being utilized in the industry. By implementing automation technology and process control concepts more typically associated with industrial and petrochemical process facilities, Baltimore Gas and Electric Co. (BGE) has significantly improved the efficiency, performance, and safety at its Notch Cliff Propane-Air peak shaving facility. These results have contributed to BGE`s ongoing efforts to effectively operate in the competitive energy marketplace. When the Notch Cliff plant was built in the early 1960s, it was a state-of-the-art facility. The plant blends propane vapor and compressed air to create a supplement to the natural gas supply during peak demand periods.

  9. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam with propane-distillation

    E-Print Network [OSTI]

    Ramirez Garnica, Marco Antonio

    2004-09-30T23:59:59.000Z

    from Instituto Mexicano del Petróleo (IMP), Dr. Fernando Rodriguez de la Garza, and Dr. Jose Luis Sanchez Bujanos from Petróleos Mexicanos (PEMEX), and Lawyer Rolando Rueda de Leon from Diario de Mexico, for their help and valuable advice. I would...-, and Steam with Propane-Distillation. (May 2004) Marco Antonio Ramírez-Garnica, B.S., Instituto Politécnico Nacional; M.S., Instituto Politécnico Nacional, México Chair of Advisory Committee: Dr. Daulat D. Mamora Recent experimental and simulation...

  10. Michigan residential heating oil and propane price survey: 1995--1996 heating season. Final report

    SciTech Connect (OSTI)

    Moriarty, C.

    1996-05-01T23:59:59.000Z

    This report summarizes the results of a survey of residential No. 2 distillate fuel (home heating oil) and liquefied petroleum gas (propane) prices over the 1995--1996 heating season in Michigan. The Michigan`s Public Service Commission (MPSC) conducted the survey under a cooperative agreement with the US Department of Energy`s (DOE) Energy Information Administration (EIA). This survey was funded in part by a grant from the DOE. From October 1995 through March 1996, the MPSC surveyed participating distributors by telephone for current residential retail home heating oil and propane prices. The MPSC transmitted the data via a computer modem to the EIA using the Petroleum Electronic Data Reporting Option (PEDRO). Survey results were published in aggregate on the MPSC World Wide Web site at http://ermisweb.state.mi.us/shopp. The page was updated with both residential and wholesale prices immediately following the transmission of the data to the EIA. The EIA constructed the survey using a sample of Michigan home heating oil and propane retailers. The sample accounts for different sales volumes, geographic location, and sources of primary supply.

  11. Industrial Gases as a Vehicle for Competitiveness

    E-Print Network [OSTI]

    Dale, J. R.

    -based separation technology was developing to offer an alternative to cryogenic separation for those instances when neither high purity or cryogenic properties were required by the application. It resulted in gas of lower than 99.9995%, "five-nines", purity...INDUSTRIAL GASES AS A VEHICLE FOR COMPETITIVENESS James R. Dale, Director, Technology Programs, Airco Industrial Gases Division, The BOC Group, Inc., Murray Hill, New Jersey ABSTRACT Industrial gases are produced using compressed air...

  12. "Nanocrystal bilayer for tandem catalysis"

    E-Print Network [OSTI]

    Yamada, Yusuke

    2012-01-01T23:59:59.000Z

    Hydrogenolysis of Ethane, Propane, n-Butane and iso-Butanethe Hydroformylation of Propane over Silica-supported Groupproduct and small amount of propane, which is likely to be

  13. Detecting Volatile Organic Compounds from Orbit J. J. Harrison & P. F. Bernath

    E-Print Network [OSTI]

    ethane retrievals are currently being optimised by updating and improving the microwindow set. Propane cross sections have also been determined from spectra recorded at the MSF. Propane 215 K Propane Q

  14. THE FURNACE COMBUSTION AND RADIATION CHARACTERISTICS OF METHANOL AND A METHANOL/COAL SLURRY

    E-Print Network [OSTI]

    Grosshandler, W.L.

    2010-01-01T23:59:59.000Z

    of NO and N02 in a Turbulent Propane/Air Di fusion Flame,"Fuel Methanol Ethanol Ethane Propane i so Octane n - Cetanestage of the secondary Propane, at A spark air line contains

  15. Series 50 propane-fueled Nova bus: Engine development, installation, and field trials

    SciTech Connect (OSTI)

    Smith, B.

    1999-01-01T23:59:59.000Z

    The report describes a project to develop the Detroit Diesel series 50 liquefied propane gas (LPG) heavy-duty engine and to conduct demonstrations of LPG-fuelled buses at selected sites (Halifax Regional Municipality and three sites in the United States). The project included five main elements: Engine development and certification, chassis re-engineering and engine installation, field demonstration, LPG fuel testing, and LPG fuel variability testing. Lessons learned with regard to engine design and other issues are discussed, and recommendations are made for further development and testing.

  16. U.S. Natural Gas Supplemental Gas - Propane Air (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40 Buildingto17 34 44Year Jan Feb MarDecade Year-0 Year-1 Year-2 Year-3OtherPropane

  17. Alternative Fuels Data Center: Michigan School Buses Get Rolling on Propane

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProductsAlternative Fuels CleanReduce OperatingPropane inMichigan School

  18. Alternative Fuels Data Center: Propane Rolls on as Reliable Fleet Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWP RelatedCellulaseFuels andConversionsAssumptionsBenefitsPropane

  19. Particle entanglement in rotating gases

    SciTech Connect (OSTI)

    Liu Zhao; Fan Heng [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

    2010-06-15T23:59:59.000Z

    In this paper, we investigate the particle entanglement in two-dimensional (2D) weakly interacting rotating Bose and Fermi gases. We find that both particle localization and vortex localization can be indicated by particle entanglement. We also use particle entanglement to show the occurrence of edge reconstruction of rotating fermions. The different properties of condensate phase and vortex liquid phase of bosons can be reflected by particle entanglement and in vortex liquid phase we construct the same trial wave function with that in [Phys. Rev. Lett. 87, 120405 (2001)] from the viewpoint of entanglement to relate the ground state with quantum Hall state. Finally, the relation between particle entanglement and interaction strength is studied.

  20. Granular gases under extreme driving

    E-Print Network [OSTI]

    W. Kang; J. Machta; E. Ben-Naim

    2010-08-06T23:59:59.000Z

    We study inelastic gases in two dimensions using event-driven molecular dynamics simulations. Our focus is the nature of the stationary state attained by rare injection of large amounts of energy to balance the dissipation due to collisions. We find that under such extreme driving, with the injection rate much smaller than the collision rate, the velocity distribution has a power-law high energy tail. The numerically measured exponent characterizing this tail is in excellent agreement with predictions of kinetic theory over a wide range of system parameters. We conclude that driving by rare but powerful energy injection leads to a well-mixed gas and constitutes an alternative mechanism for agitating granular matter. In this distinct nonequilibrium steady-state, energy cascades from large to small scales. Our simulations also show that when the injection rate is comparable with the collision rate, the velocity distribution has a stretched exponential tail.

  1. Winter fuels report, week ending February 12, 1993. [Contains Glossary and feature article on Midwest Propane Markets

    SciTech Connect (OSTI)

    Not Available

    1993-02-18T23:59:59.000Z

    The Winter Fuels Report is intended to provide concise, timely information to the industry, the press, policymakers, consumers, analysts, and State and local governments on the following topics: Distillate fuel oil net production, imports and stocks on a US level and for all Petroleum Administration for Defense Districts (PADD) and product supplied on a US level; propane net production, imports and stocks on a US level and for PADD's 1, II, and III; natural gas supply and disposition and underground storage for the US and consumption for all PADD'S; as well as selected National average prices. Residential and wholesale pricing data for heating oil and propane for those States participating in the joint Energy Information Administration (EIA)/State Heating Oil and Propane Program; selected cities; and a 6--10 Day, 30-Day, and 90-Day outlook for temperature and precipitation and US total heating degree-days by city.

  2. Combustion: What is the Lower Heating Value (LHV) of Propane? Before we start: how reasonable is the use of the LHV? What is the dewpoint of the reaction products?

    E-Print Network [OSTI]

    Combustion: What is the Lower Heating Value (LHV) of Propane? Before we start: how reasonable temperature we can achieve with a propane-and-air blowtorch? We repeat this calculation for several different

  3. Analysis of ignition behavior in a turbocharged direct injection dual fuel engine using propane and methane as primary fuels

    SciTech Connect (OSTI)

    Polk, A. C.; Gibson, C. M.; Shoemaker, N. T.; Srinivasan, K. K.; Krishnan, S. R.

    2011-10-05T23:59:59.000Z

    This paper presents experimental analyses of the ignition delay (ID) behavior for diesel-ignited propane and diesel-ignited methane dual fuel combustion. Two sets of experiments were performed at a constant speed (1800 rev/min) using a 4-cylinder direct injection diesel engine with the stock ECU and a wastegated turbocharger. First, the effects of fuel-air equivalence ratios (���© pilot �¢���¼ 0.2-0.6 and ���© overall �¢���¼ 0.2-0.9) on IDs were quantified. Second, the effects of gaseous fuel percent energy substitution (PES) and brake mean effective pressure (BMEP) (from 2.5 to 10 bar) on IDs were investigated. With constant ���© pilot (> 0.5), increasing ���© overall with propane initially decreased ID but eventually led to premature propane autoignition; however, the corresponding effects with methane were relatively minor. Cyclic variations in the start of combustion (SOC) increased with increasing ���© overall (at constant ���© pilot), more significantly for propane than for methane. With increasing PES at constant BMEP, the ID showed a nonlinear (initially increasing and later decreasing) trend at low BMEPs for propane but a linearly decreasing trend at high BMEPs. For methane, increasing PES only increased IDs at all BMEPs. At low BMEPs, increasing PES led to significantly higher cyclic SOC variations and SOC advancement for both propane and methane. Finally, the engine ignition delay (EID) was also shown to be a useful metric to understand the influence of ID on dual fuel combustion.

  4. The catalytic oxidation of propane and propylene with air: total aldehyde production and selectivity at low conversions. 

    E-Print Network [OSTI]

    Looney, Franklin Sittig

    1950-01-01T23:59:59.000Z

    ~ Ths writer is izntebteg to pr, P G~ ~och Tor his assistance azsi guidance in this work aC to Br~ J+ 9 Kinds Tor his aery. suggestions eel Succor~ a The oxidation cf propane~ propylene and prcya~cregyimm mbetccres ctver a ~ aiucdna ~st in a flew... formation of aldehyde fran pure grade propane The ~ce of Within the range of variables of this investigation and with propylene ~& aldehyde pr~cn was f'ennd to bs independent of" residence Qorrcgations relating aldehyde pressure to ~ and cncygsn pressure...

  5. State Heating Oil and Propane Program, 1990--1991 heating season. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1991-06-06T23:59:59.000Z

    The following discussion summarizes the survey approach and results of the Department of Public Service`s survey of retail fuel oil and propane prices during the 1990--91 heating season. The semi-monthly phone surveys were conducted in cooperation with the US Department of Energy`s State Fuel Oil and Propane Program, which coordinated surveys of heating fuel prices by 25 eastern and midwest states. This federal/state program serves as a method for fast collection, analysis, and dissemination of information on current residential prices. No other information source meets needs for timely retail price information over the course of the heating season. For the 1990--91 heating season, the Minnesota Department of Public Service (MN/DPS) expanded the scope of its survey effort to include regional price data. Surveys were conducted with 160 retailers, including 59 respondents from the DOE samples, to provide a reasonable sample size for each region. Fuel oil retailers were also asked for updates on their secondary inventory levels.

  6. State Heating Oil and Propane Program, 1990--1991 heating season

    SciTech Connect (OSTI)

    Not Available

    1991-06-06T23:59:59.000Z

    The following discussion summarizes the survey approach and results of the Department of Public Service's survey of retail fuel oil and propane prices during the 1990--91 heating season. The semi-monthly phone surveys were conducted in cooperation with the US Department of Energy's State Fuel Oil and Propane Program, which coordinated surveys of heating fuel prices by 25 eastern and midwest states. This federal/state program serves as a method for fast collection, analysis, and dissemination of information on current residential prices. No other information source meets needs for timely retail price information over the course of the heating season. For the 1990--91 heating season, the Minnesota Department of Public Service (MN/DPS) expanded the scope of its survey effort to include regional price data. Surveys were conducted with 160 retailers, including 59 respondents from the DOE samples, to provide a reasonable sample size for each region. Fuel oil retailers were also asked for updates on their secondary inventory levels.

  7. Effects of Propane/Natural Gas Blended Fuels on Gas Turbine Pollutant Emissions

    SciTech Connect (OSTI)

    Straub, D.L.; Ferguson, D.H.; Casleton, K.H.; Richards, G.A.

    2007-03-01T23:59:59.000Z

    Liquefied natural gas (LNG) imports to the U.S. are expected to grow significantly over the next 10-15 years. Likewise, it is expected that changes to the domestic gas supply may also introduce changes in natural gas composition. As a result of these anticipated changes, the composition of fuel sources may vary significantly from conventional domestic natural gas supplies. This paper will examine the effects of fuel variability on pollutant emissions for premixed gas turbine conditions. The experimental data presented in this paper have been collected from a pressurized single injector combustion test rig at the National Energy Technology Laboratory (NETL). The tests are conducted at 7.5 atm with a 588 K air preheat. A propane blending facility is used to vary the Wobbe Index of the site natural gas. The results indicate that propane addition of about five (vol.) percent does not lead to a significant change in the observed NOx or CO emissions. These results are different from data collected on some engine applications and potential reasons for these differences will be described.

  8. Comparison of propane and methane performance and emissions in a turbocharged direct injection dual fuel engine

    SciTech Connect (OSTI)

    Gibson, C. M.; Polk, A. C.; Shoemaker, N. T.; Srinivasan, K. K.; Krishnan, S. R.

    2011-04-20T23:59:59.000Z

    With increasingly restrictive NO x and particulate matter emissions standards, the recent discovery of new natural gas reserves, and the possibility of producing propane efficiently from biomass sources, dual fueling strategies have become more attractive. This paper presents experimental results from dual fuel operation of a four-cylinder turbocharged direct injection (DI) diesel engine with propane or methane (a natural gas surrogate) as the primary fuel and diesel as the ignition source. Experiments were performed with the stock engine control unit at a constant speed of 1800 rpm, and a wide range of brake mean effective pressures (BMEPs) (2.7-11.6 bars) and percent energy substitutions (PESs) of C 3 H 8 and CH 4. Brake thermal efficiencies (BTEs) and emissions (NO x, smoke, total hydrocarbons (THCs), CO, and CO 2) were measured. Maximum PES levels of about 80-95% with CH 4 and 40-92% with C 3 H 8 were achieved. Maximum PES was limited by poor combustion efficiencies and engine misfire at low loads for both C 3 H 8 and CH 4, and the onset of knock above 9 bar BMEP for C 3 H 8. While dual fuel BTEs were lower than straight diesel BTEs at low loads, they approached diesel BTE values at high loads. For dual fuel operation, NO x and smoke reductions (from diesel values) were as high as 66-68% and 97%, respectively, but CO and THC emissions were significantly higher with increasing PES at all engine loads

  9. Production of olefins by oxidative dehydrogenation of propane and butane over monoliths at short contact times

    SciTech Connect (OSTI)

    Huff, M.; Schmidt, L.D. [Univ. of Minnesota, Minneapolis, MN (United States)] [Univ. of Minnesota, Minneapolis, MN (United States)

    1994-09-01T23:59:59.000Z

    The autothermal production of olefins from propane or n-butane by oxidative dehydrogenation and cracking in air or oxygen at atmospheric pressure over noble metal coated ceramic foam monoliths at contact times of {approximately}5 milliseconds has been studied. On Pt, synthesis gas (CO and H{sub 2}) dominates near its stoichiometry, while olefin production dominates at higher fuel-to-oxygen ratios. No carbon buildup is observed, and catalysts exhibit no deactivation over at least several days. On Rh, primarily synthesis gas is produced under these conditions, while on Pd, carbon deposition rapidly deactivates the catalyst. The authors observed up to 65% selectivity to olefins at nearly 100% conversion of propane or n-butane with a catalyst contact time of 5 ms. Ethylene selectivity is maximized by increasing the reaction temperature, either by preheating the reactants or by using oxygen enriched air. Propylene selectivity is maximized by lower temperature and shorter catalyst contact time. Very small amounts alkanes and higher molecular weight species are obtained, suggesting that a homogeneous pyrolysis mechanism is not occurring. A very simple reaction mechanism appears to explain the observed product distribution. Reactions are initiated by oxidative dehydrogenation of the alkane by adsorbed oxygen to form a surface alkyl. On Pt, {beta}-hydrogen and {beta}-alkyl elimination reactions of adsorbed alkyl dominate which lead to olefin production rather than cracking to C{sub s} and H{sub s}. 24 refs., 14 figs., 4 tabs.

  10. Published in Journal de Physique IV, vol 11, pp. Pr3-101 ---Pr3-108 Kinetic modelling of gas-phase decomposition of propane : correlation with pyrocarbon deposition

    E-Print Network [OSTI]

    Boyer, Edmond

    -phase decomposition of propane : correlation with pyrocarbon deposition Cédric Descamps, Gerard L. Vignoles , Olivier : A chemical kinetic model for gas-phase pyrolysis of propane has been set up, partially reduced, and validated the notion of "maturation" from propane to lighter hydrocarbons, then to aromatic compounds and PAHs. The gas

  11. An Infrared Spectral Database for Detection of Gases Emitted...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Database for Detection of Gases Emitted by Biomass Burning. An Infrared Spectral Database for Detection of Gases Emitted by Biomass Burning. Abstract: We report the construction of...

  12. atmospheric greenhouse gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GASES BACKGROUND CiteSeer Summary: The Earths climate depends on the amount of solar radiation received and the atmospheric abundance of clouds and greenhouse gases. The...

  13. aerosol precursor gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sunlight 11 GREENHOUSE GASES GREENHOUSE GASES BACKGROUND CiteSeer Summary: The Earths climate depends on the amount of solar radiation received and the atmospheric abundance of...

  14. Energy Efficiency and Greenhouse Gases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency and Greenhouse Gases Energy Efficiency and Greenhouse Gases Mission The team establishes an energy conservation program, as deemed appropriate for LM operations...

  15. Light Collection in Liquid Noble Gases

    SciTech Connect (OSTI)

    McKinsey, Dan [Yale University

    2013-05-29T23:59:59.000Z

    Liquid noble gases are increasingly used as active detector materials in particle and nuclear physics. Applications include calorimeters and neutrino oscillation experiments as well as searches for neutrinoless double beta decay, direct dark matter, muon electron conversion, and the neutron electric dipole moment. One of the great advantages of liquid noble gases is their copious production of ultraviolet scintillation light, which contains information about event energy and particle type. I will review the scintillation properties of the various liquid noble gases and the means used to collect their scintillation light, including recent advances in photomultiplier technology and wavelength shifters.

  16. SOLAR HEATING OF TANK BOTTOMS Application of Solar Heating to Asphaltic and Parrafinic Oils Reducing Fuel Costs and Greenhouse Gases Due to Use of Natural Gas and Propane

    SciTech Connect (OSTI)

    Eugene A. Fritzler

    2005-09-01T23:59:59.000Z

    The sale of crude oil requires that the crude meet product specifications for BS&W, temperature, pour point and API gravity. The physical characteristics of the crude such as pour point and viscosity effect the efficient loading, transport, and unloading of the crude oil. In many cases, the crude oil has either a very high paraffin content or asphalt content which will require either hot oiling or the addition of diluents to the crude oil to reduce the viscosity and the pour point of the oil allowing the crude oil to be readily loaded on to the transport. Marginal wells are significantly impacted by the cost of preheating the oil to an appropriate temperature to allow for ease of transport. Highly paraffinic and asphaltic oils exist throughout the D-J basin and generally require pretreatment during cold months prior to sales. The current study addresses the use of solar energy to heat tank bottoms and improves the overall efficiency and operational reliability of stripper wells.

  17. A simulation study of steam and steam-propane injection using a novel smart horizontal producer to enhance oil production 

    E-Print Network [OSTI]

    Sandoval Munoz, Jorge Eduardo

    2004-11-15T23:59:59.000Z

    A 3D 8-component thermal compositional simulation study has been performed to evaluate the merits of steam-propane injection and a novel vertical-smart horizontal well system for the Lombardi reservoir in the San Ardo field, California. The novel...

  18. High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling

    SciTech Connect (OSTI)

    Gray, J.A. (Sandia National Labs., Livermore, CA (United States)); Westbrook, C.K. (Lawrence Livermore National Lab., CA (United States))

    1991-01-01T23:59:59.000Z

    Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added in amounts up to 25% of the fuel to propane-oxygen-argon mixtures in shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenius parameters of E{sub a}{approximately}40 kcal/mol and log (A){approximately} 9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified.

  19. High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling. Revision 1

    SciTech Connect (OSTI)

    Gray, J.A. [Sandia National Labs., Livermore, CA (United States); Westbrook, C.K. [Lawrence Livermore National Lab., CA (United States)

    1991-12-01T23:59:59.000Z

    Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added to amounts up to 25% of the fuel to propane-oxygen-argon mixtures to shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenium parameters of E{sub a}{sup {minus}}40 kcal/mol and log(A) {sup {minus}}9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified. 19 refs., 1 fig., 3 tabs.

  20. High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling

    SciTech Connect (OSTI)

    Gray, J.A. [Sandia National Labs., Livermore, CA (United States); Westbrook, C.K. [Lawrence Livermore National Lab., CA (United States)

    1991-12-31T23:59:59.000Z

    Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added in amounts up to 25% of the fuel to propane-oxygen-argon mixtures in shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenius parameters of E{sub a}{approximately}40 kcal/mol and log (A){approximately} 9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified.

  1. High-temperature ignition of propane with MTBE as an additive: Shock-tube experiments and modeling

    SciTech Connect (OSTI)

    Gray, J.A. (Sandia National Labs., Livermore, CA (United States)); Westbrook, C.K. (Lawrence Livermore National Lab., CA (United States))

    1991-12-01T23:59:59.000Z

    Ignition of propane has been studied in a shock tube and by computational modeling to determine the effect of methyl tert-butyl ether (MTBE) as a fuel additive. MTBE and isobutene were added to amounts up to 25% of the fuel to propane-oxygen-argon mixtures to shock-tube experiments covering a range of temperatures between 1450 and 1800 K. Ignition delays were measured from chemiluminescence at 432 nm due to excited CH radicals. The temperature dependence of the ignition rates was analyzed to yield Arrhenium parameters of E{sub a}{sup {minus}}40 kcal/mol and log(A) {sup {minus}}9.0 sec{sup {minus}1} for the overall reaction. Reactions involving MTBE and its decomposition products were combined with an established propane mechanism in a numerical model to describe the kinetic interaction of this additive with a typical hydrocarbon fuel. The experiments and the kinetic model both show that MTBE and isobutene retard propane ignition with nearly equal efficiency. The kinetic model demonstrates that isobutene kinetics are responsible for inhibition by both MTBE and isobutene, and the specific elementary reactions which produce this behavior are identified. 19 refs., 1 fig., 3 tabs.

  2. Optimized design of a heat exchanger for an air-to-water reversible heat pump working with propane (R290)

    E-Print Network [OSTI]

    Fernández de Córdoba, Pedro

    Optimized design of a heat exchanger for an air-to-water reversible heat pump working with propane-to-water reversible heat pump unit was carried out using two different fin-and-tube heat exchanger ``coil'' designs concepts. The performance of the heat pump was evaluated for each coil design at different superheat

  3. Effect of propane-air on NGVs and vehicle fueling stations. Topical report, January 1-October 1, 1993

    SciTech Connect (OSTI)

    Liss, W.E.; Moulton, D.S.

    1994-06-01T23:59:59.000Z

    Propane-air (P/A) peakshaving is an important element of peak-load management for some U.S. gas utilities. P/A is used as a supplemental energy medium with natural gas and has been shown to operate satisfactorily in most natural gas applications. The propane levels injected are compatible with the pressures (under 200 psig) and temperatures (over 40 F) found in utility distribution networks. However, P/A can create problems for natural gas vehicles (NGVs) operating on compressed gas as well as NGV fueling stations. This report contains information on P/A peakshaving and its compatibility with NGVs by documenting condensation impacts at nine conditions--i.e., three propane levels and three temperatures. These data portray the depressurization of a vehicle tank, an area selected because it illustrates NGV operation and can discriminate between acceptable and potentially non-acceptable operating points. These analyses show, not surprisingly, a correlation exists between propane level, ambient temperature, and condensation.

  4. Studies of n-Propanol, iso-Propanol, and Propane Flames

    SciTech Connect (OSTI)

    Veloo, Peter S.; Egolfopoulos, Fokion N.

    2011-01-01T23:59:59.000Z

    The phenomena of propagation and extinction of flames of saturated C{sub 3} alcohols and propane were studied experimentally and numerically in order to assess the effects of the presence and location of the hydroxyl radical in the fuel molecular structure. The experiments were carried out in the counterflow configuration under atmospheric pressure and for unreacted fuel-carrying stream temperature of 343 K. The simulations included detailed descriptions of molecular transport and chemical kinetics using a recently developed kinetic model for C{sub 3} alcohols. The experimental results revealed that the laminar flame speeds and extinction strain rates of n-propanol/air and propane/air flames are close to each other whereas those of iso-propanol/air flames are consistently lower. Similar behavior was observed also for the extinction strain rates of non-premixed n-propanol and iso-propanol flames. It was shown through sensitivity and reaction path analyses that there are two major differences between the intermediates of n-propanol/air and iso-propanol/air flames. In iso-propanol/air flames there are notably higher concentrations of propene whose consumption pathway results in the relatively unreactive allyl radicals, retarding thus the overall reactivity. In n-propanol/air flames there are notably higher concentrations of formaldehyde that reacts readily to form formyl radicals whose subsequent reactions enhance the overall reactivity. The kinetic model used in this study was found to overpredict the experimental results for rich n-propanol/air and propane/air flames. Analysis revealed that those discrepancies are most likely caused by deficiencies in the C{sub 3} alkane kinetics. Through sensitivity analysis, it was determined also that the propagation and extinction of n-propanol/air and iso-propanol/air flames are sensitive largely to hydrogen, carbon monoxide, and C{sub 1}–C{sub 3} kinetics and not to fuel-specific reactions. Finally, the relative sooting propensities of flames of these three fuels were assessed computationally.

  5. Denitrification of combustion gases. [Patent application

    DOE Patents [OSTI]

    Yang, R.T.

    1980-10-09T23:59:59.000Z

    A method for treating waste combustion gas to remove the nitrogen oxygen gases therefrom is disclosed wherein the waste gas is first contacted with calcium oxide which absorbs and chemically reacts with the nitrogen oxide gases therein at a temperature from about 100/sup 0/ to 430/sup 0/C. The thus reacted calcium oxide (now calcium nitrate) is then heated at a temperature range between about 430/sup 0/ and 900/sup 0/C, resulting in regeneration of the calcium oxide and production of the decomposition gas composed of nitrogen and nitrogen oxide gas. The decomposition gases can be recycled to the calcium oxide contacting step to minimize the amount of nitrogen oxide gases in the final product gas.

  6. Voluntary reporting of greenhouse gases, 1995

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    The Voluntary Reporting Program for greenhouse gases is part of an attempt by the U.S. Government to develop innovative, low-cost, and nonregulatory approaches to limit emissions of greenhouse gases. It is one element in an array of such programs introduced in recent years as part of the effort being made by the United States to comply with its national commitment to stabilize emissions of greenhouse gases under the Framework Convention on Climate Change. The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report to the Energy Information Administration (EIA) on actions taken that have reduced or avoided emissions of greenhouse gases.

  7. Biological production of products from waste gases

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    2002-01-22T23:59:59.000Z

    A method and apparatus are designed for converting waste gases from industrial processes such as oil refining, and carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various products, such as organic acids, alcohols, hydrogen, single cell protein, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  8. Cross sections for electron scattering by propane in the low- and intermediate-energy ranges

    SciTech Connect (OSTI)

    Souza, G. L. C. de; Lee, M.-T.; Sanches, I. P.; Rawat, P.; Iga, I.; Santos, A. S. dos; Machado, L. E.; Sugohara, R. T.; Brescansin, L. M.; Homem, M. G. P.; Lucchese, R. R. [Departamento de Quimica, UFSCar, 13565-905 Sao Carlos, SP (Brazil); Departamento de Fisica, UFSCar, 13565-905 Sao Carlos, SP (Brazil); Instituto de Fisica 'Gleb Wataghin', UNICAMP, 13083-970 Campinas, SP (Brazil); Departamento de Fisica, UFSC, 88010-970 Florianopolis, SC (Brazil); Department of Chemistry, Texas A and M University, College Station, Texas 7784-3255 (United States)

    2010-07-15T23:59:59.000Z

    We present a joint theoretical-experimental study on electron scattering by propane (C{sub 3}H{sub 8}) in the low- and intermediate-energy ranges. Calculated elastic differential, integral, and momentum transfer as well as total (elastic + inelastic) and total absorption cross sections are reported for impact energies ranging from 2 to 500 eV. Also, experimental absolute elastic cross sections are reported in the 40- to 500-eV energy range. A complex optical potential is used to represent the electron-molecule interaction dynamics. A theoretical method based on the single-center-expansion close-coupling framework and corrected by the Pade approximant is used to solve the scattering equations. The experimental angular distributions of the scattered electrons are converted to absolute cross sections using the relative flow technique. The comparison of our calculated with our measured results, as well as with other experimental and theoretical data available in the literature, is encouraging.

  9. Synthesis and Characterization of Gold Clusters Ligated with 1,3-Bis(dicyclohexylphosphino)propane

    SciTech Connect (OSTI)

    Johnson, Grant E.; Priest, Thomas A.; Laskin, Julia

    2013-09-01T23:59:59.000Z

    In this multidisciplinary study we combine chemical reduction synthesis of novel gold clusters in solution with high-resolution analytical mass spectrometry (MS) to gain insight into the composition of the gold clusters and how their size, ionic charge state and ligand substitution influences their gas-phase fragmentation pathways. Ultra small cationic gold clusters ligated with 1,3-bis(dicyclohexylphosphino)propane (DCPP) were synthesized for the first time and introduced into the gas phase using electrospray ionization (ESI). Mass-selected cluster ions were fragmented employing collision induced dissociation (CID) and the product ions were analysed using MS. The solutions were found to contain the multiply charged cationic gold clusters Au9L43+, Au13L53+, Au6L32+, Au8L32+ and Au10L42+ (L = DCPP). The gas-phase fragmentation pathways of these cluster ions were examined systematically employing CID combined with MS. In addition, CID experiments were performed on related gold clusters of the same size and ionic charge state but capped with 1,3-bis(diphenylphosphino)propane (DPPP) ligands containing phenyl functional groups at the two phosphine centers instead of cyclohexane rings. It is shown that this relatively small change in the molecular substitution of the two phosphine centers in diphosphine ligands (C6H11 versus C6H5) exerts a pronounced influence on the size of the species that are preferentially formed in solution during reduction synthesis as well as the gas-phase fragmentation channels of otherwise identical gold cluster ions. The mass spectrometry results indicate that in addition to the length of the alkyl chain between the two phosphine centers, the substituents at the phosphine centers also play a crucial role in determining the composition, size and stability of diphosphine ligated gold clusters synthesized in solution.

  10. 4-70C Propane (molar mass = 44.1 kg/kmol) poses a greater fire danger than methane (molar mass = 16 kg/kmol) since propane is heavier than air (molar mass = 29 kg/kmol), and it will settle near the floor.

    E-Print Network [OSTI]

    Bahrami, Majid

    4-36 Ideal Gas 4-70C Propane (molar mass = 44.1 kg/kmol) poses a greater fire danger than methane (molar mass = 16 kg/kmol) since propane is heavier than air (molar mass = 29 kg/kmol), and it will settle MATERIAL. © 2008 The McGraw-Hill Companies, Inc. Limited distribution permitted only to teachers

  11. HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Greenhouse gases andGreenhouse gases and

    E-Print Network [OSTI]

    Zevenhoven, Ron

    in gas turbinecombustion in gas turbine HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Effect of COEffect-depleting gases ·· COCO22 removal for gas purificationremoval for gas purification ·· COCO22 removal for greenhouse gas emissions reductionremoval for greenhouse gas emissions reduction ·· Other greenhouse gases

  12. Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O-and OH,,,O-Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate

    E-Print Network [OSTI]

    Goddard III, William A.

    Intramolecular Hydrogen Bonding in Disubstituted Ethanes. A Comparison of NH,,,O- and OH,,,O- Hydrogen Bonding through Conformational Analysis of 4-Amino-4-oxobutanoate (succinamate) and Monohydrogen 1 of amide NH,,,O- and carboxyl OH,,,O- hydrogen bonds were investigated via conformational analysis

  13. Experimental study of enhancement of injectivity and in-situ oil upgrading by steam-propane injection for the Hamaca heavy oil field 

    E-Print Network [OSTI]

    Rivero Diaz, Jose Antonio

    2002-01-01T23:59:59.000Z

    Experiments were conducted to study the feasibility of using propane as a steam additive to accelerate oil production and improve steam injectivity in the Hamaca field, Venezuela. The experiments utilized a vertical injection cell into which a...

  14. Use of a thermodynamic cycle simulation to determine the difference between a propane-fuelled engine and an iso-octane-fuelled engine 

    E-Print Network [OSTI]

    Pathak, Dushyant

    2006-04-12T23:59:59.000Z

    the engine cycle simulation to determine the difference between a propane-fuelled and an iso-octane-fuelled engine for the same operating conditions and engine specifications. A comprehensive parametric investigation was conducted to examine the effects...

  15. Experimental study of enhancement of injectivity and in-situ oil upgrading by steam-propane injection for the Hamaca heavy oil field

    E-Print Network [OSTI]

    Rivero Diaz, Jose Antonio

    2002-01-01T23:59:59.000Z

    Experiments were conducted to study the feasibility of using propane as a steam additive to accelerate oil production and improve steam injectivity in the Hamaca field, Venezuela. The experiments utilized a vertical injection cell into which a...

  16. Use of a thermodynamic cycle simulation to determine the difference between a propane-fuelled engine and an iso-octane-fuelled engine

    E-Print Network [OSTI]

    Pathak, Dushyant

    2006-04-12T23:59:59.000Z

    the engine cycle simulation to determine the difference between a propane-fuelled and an iso-octane-fuelled engine for the same operating conditions and engine specifications. A comprehensive parametric investigation was conducted to examine the effects...

  17. Where do California's greenhouse gases come from?

    ScienceCinema (OSTI)

    Fischer, Marc

    2013-05-29T23:59:59.000Z

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  18. Propane tank explosion (2 deaths, 7 injuries) at Herrig Brothers Feather Creek Farm, Albert City, Iowa, April 9, 1998. Investigation report

    SciTech Connect (OSTI)

    NONE

    1999-09-01T23:59:59.000Z

    This report explains the explosion/BLEVE that took place on April 9, 1998, at the Herrig Brothers Feather Creek Farm, located in Albert City, Iowa. Two volunteer fire fighters were killed and seven other emergency response personnel were injured. Safety issues covered in the report include protection of propane storage tanks and piping, state regulatory oversight of such installations, and fire fighter response to propane storage tank fires.

  19. Phase Behavior of Light Gases in Hydrocarbon and Aqueous Solvents

    SciTech Connect (OSTI)

    Gasem, K.A.M.; Robinson, R.L., Jr.; Trvedi, N.J., Gao, W.

    1997-09-01T23:59:59.000Z

    Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, our solubility apparatus was refurbished and restored to full service. To test the experimental apparatus and procedures used, measurements were obtained for the solubility Of C0{sub 2} in benzene at 160{degrees}F. Having confirmed the accuracy of the newly acquired data in comparison with our previous measurements and data reported in the literature for this test system, we have begun to measure the solubility of hydrogen in hexane. The measurements for this system will cover the temperature range from 160 to 280{degrees}F at pressures to 2,500 psia. As part of our model evaluation efforts, we examined the predictive abilities of an alternative approach we have proposed for calculating the phase behavior properties of highly non-ideal systems. Using this approach, the liquid phase fugacities generated from an equation of state (EOS) are augmented by a fugacity deviation function correction. The correlative abilities of this approach are compared with those of an EOS equipped with the recently introduced Wong-Sandler (MWS) mixing rules. These two approaches are compared with the current methods for vapor-liquid equilibrium (VLE) calculations, i.e., the EOS (0/0) approach with the van der Waals mixing rules and the split (y/0) approach. The evaluations were conducted on a database comprised of non-ideal low pressure binary systems as well as asymmetric high pressure binary systems. These systems are of interest in the coal liquefaction and utilization processes. The Peng-Robinson EOS was selected for the purposes of this evaluation.

  20. Stationary light in cold atomic gases

    E-Print Network [OSTI]

    Gor Nikoghosyan; Michael Fleischhauer

    2009-09-16T23:59:59.000Z

    We discuss stationary light created by a pair of counter-propagating control fields in Lambda-type atomic gases with electromagnetically induced transparency for the case of negligible Doppler broadening. In this case the secular approximation used in the discussion of stationary light in hot vapors is no longer valid. We discuss the quality of the effective light-trapping system and show that in contrast to previous claims it is finite even for vanishing ground-state dephasing. The dynamics of the photon loss is in general non exponential and can be faster or slower than in hot gases.

  1. Adsorption of propane, isopropyl, and hydrogen on cluster models of the M1 phase of Mo-V-Te-Nb-O mixed metal oxide catalyst

    SciTech Connect (OSTI)

    Govindasamy, Agalya [University of Cincinnati; Muthukumar, Kaliappan [University of Cincinnati; Yu, Junjun [University of Cincinnati; Xu, Ye [ORNL; Guliants, Vadim V. [University of Cincinnati

    2010-01-01T23:59:59.000Z

    The Mo-V-Te-Nb-O mixed metal oxide catalyst possessing the M1 phase structure is uniquely capable of directly converting propane into acrylonitrile. However, the mechanism of this complex eight-electron transformation, which includes a series of oxidative H-abstraction and N-insertion steps, remains poorly understood. We have conducted a density functional theory study of cluster models of the proposed active and selective site for propane ammoxidation, including the adsorption of propane, isopropyl (CH{sub 3}CHCH{sub 3}), and H which are involved in the first step of this transformation, that is, the methylene C-H bond scission in propane, on these active site models. Among the surface oxygen species, the telluryl oxo (Te=O) is found to be the most nucleophilic. Whereas the adsorption of propane is weak regardless of the MO{sub x} species involved, isopropyl and H adsorption exhibits strong preference in the order of Te=O > V=O > bridging oxygens > empty Mo apical site, suggesting the importance of TeO{sub x} species for H abstraction. The adsorption energies of isopropyl and H and consequently the reaction energy of the initial dehydrogenation of propane are strongly dependent on the number of ab planes included in the cluster, which points to the need to employ multilayer cluster models to correctly capture the energetics of surface chemistry on this mixed metal oxide catalyst.

  2. Michigan residential No. 2 fuel oil and propane price survey for the 1990/91 heating season. Final report

    SciTech Connect (OSTI)

    Not Available

    1991-10-01T23:59:59.000Z

    This report summarizes the results of a survey of home heating oil and propane prices over the 1990/1991 heating season in Michigan. The survey was conducted under a cooperative agreement between the State of Michigan, Michigan Public Service Commission and the US Department of Energy (DOE), Energy Information Administration (EIA), and was funded by a grant from EIA. From October 1990 through May 1991, participating dealers/distributions were called and asked for their current residential retail prices of No. 2 home heating oil and propane. This information was then transmitted to the EIA, bi-monthly using an electronic reporting system called Petroleum Data Reporting Option (PEDRO). The survey was conducted using a sample provided by EIA of home heating oil and propane retailers which supply Michigan households. These retailers were contacted the first and third Mondays of each month. The sample was designed to account for distributors with different sales volumes, geographic distributions and sources of primary supply. It should be noted that this simple is different from the sample used in prior year surveys.

  3. Michigan residential No. 2 fuel oil and propane price survey for the 1990/91 heating season

    SciTech Connect (OSTI)

    Not Available

    1991-10-01T23:59:59.000Z

    This report summarizes the results of a survey of home heating oil and propane prices over the 1990/1991 heating season in Michigan. The survey was conducted under a cooperative agreement between the State of Michigan, Michigan Public Service Commission and the US Department of Energy (DOE), Energy Information Administration (EIA), and was funded by a grant from EIA. From October 1990 through May 1991, participating dealers/distributions were called and asked for their current residential retail prices of No. 2 home heating oil and propane. This information was then transmitted to the EIA, bi-monthly using an electronic reporting system called Petroleum Data Reporting Option (PEDRO). The survey was conducted using a sample provided by EIA of home heating oil and propane retailers which supply Michigan households. These retailers were contacted the first and third Mondays of each month. The sample was designed to account for distributors with different sales volumes, geographic distributions and sources of primary supply. It should be noted that this simple is different from the sample used in prior year surveys.

  4. Super critical fluid extraction of a crude oil bitumen-derived liquid and bitumen by carbon dioxide and propane

    SciTech Connect (OSTI)

    Deo, M.D.; Hwang, J.; Hanson, F.V.

    1991-01-01T23:59:59.000Z

    Supercritical fluid extraction of complex hydrocarbon mixtures is important in separation processes, petroleum upgrading and enhanced oil recovery. In this study, a paraffinic crude oil, a bitumen- derived liquid and bitumen were extracted at several temperatures and pressures with carbon dioxide and propane to assess the effect of the size and type of compounds that makeup the feedstock on the extraction process. It was observed that the pure solvent density at the extraction conditions was not the sole variable governing extraction, and that the proximity of the extraction conditions to the pure solvent critical point affected the extraction yields and the compositions of the extracts. Heavier compounds reported to the extract phase as the extraction time increased at constant temperature and pressure and as the extraction pressure increased at constant temperature and extraction time for both the paraffin crude-propane and the bitumen-propane systems. This preferential extraction was not observed for the bitumen-derived liquid. The non-discriminatory extraction behavior of the bitumen-derived liquid was attributed to its thermal history and to the presence of the olefins and aromatics in the liquid. Phase behavior calculations using the Peng-Robinson equation of state and component lumping procedures provided reasonable agreement between calculated and experimental results for the crude oil and bitumen extractions, but failed in the prediction of the phase compositions for the bitumen-derived liquid extractions.

  5. Super critical fluid extraction of a crude oil bitumen-derived liquid and bitumen by carbon dioxide and propane

    SciTech Connect (OSTI)

    Deo, M.D.; Hwang, J.; Hanson, F.V.

    1991-12-31T23:59:59.000Z

    Supercritical fluid extraction of complex hydrocarbon mixtures is important in separation processes, petroleum upgrading and enhanced oil recovery. In this study, a paraffinic crude oil, a bitumen- derived liquid and bitumen were extracted at several temperatures and pressures with carbon dioxide and propane to assess the effect of the size and type of compounds that makeup the feedstock on the extraction process. It was observed that the pure solvent density at the extraction conditions was not the sole variable governing extraction, and that the proximity of the extraction conditions to the pure solvent critical point affected the extraction yields and the compositions of the extracts. Heavier compounds reported to the extract phase as the extraction time increased at constant temperature and pressure and as the extraction pressure increased at constant temperature and extraction time for both the paraffin crude-propane and the bitumen-propane systems. This preferential extraction was not observed for the bitumen-derived liquid. The non-discriminatory extraction behavior of the bitumen-derived liquid was attributed to its thermal history and to the presence of the olefins and aromatics in the liquid. Phase behavior calculations using the Peng-Robinson equation of state and component lumping procedures provided reasonable agreement between calculated and experimental results for the crude oil and bitumen extractions, but failed in the prediction of the phase compositions for the bitumen-derived liquid extractions.

  6. Modeling of the formation of short-chain acids in propane flames

    E-Print Network [OSTI]

    Battin-Leclerc, Frédérique; Jaffrezo, J L; Legrand, M

    2009-01-01T23:59:59.000Z

    In order to better understand their potential formation in combustion systems, a detailed kinetic mechanism for the formation of short-chain monocarboxylic acids, formic (HCOOH), acetic (CH3COOH), propionic (C2H5COOH) and propenic (C2H3COOH)) acids, has been developed. Simulations of lean (equivalence ratios from 0.9 to 0.48) laminar premixed flames of propane stabilized at atmospheric pressure with nitrogen as diluent have been performed. It was found that amounts up to 25 ppm of acetic acid, 15 ppm of formic acid and 1 ppm of C3 acid can be formed for some positions in the flames. Simulations showed that the more abundant C3 acid formed is propenic acid. A quite acceptable agreement has been obtained with the scarce results from the literature concerning oxygenated compounds, including aldehydes (CH2O, CH3CHO) and acids. A reaction pathways analysis demonstrated that each acid is mainly derived from the aldehyde of similar structure.

  7. Subnanometer platinum clusters highly active and selective catalysts for the oxidative dehydrogenation of propane.

    SciTech Connect (OSTI)

    Vajda, S; Pellin, M. J.; Greeley, J. P.; Marshall, C. L.; Curtiss, L. A.; Ballentine, G. A.; Elam, J. W.; Catillon-Mucherie, S.; Redfern, P. C.; Mehmood, F.; Zapol, P.; Yale Univ.

    2009-03-01T23:59:59.000Z

    Small clusters are known to possess reactivity not observed in their bulk analogues, which can make them attractive for catalysis. Their distinct catalytic properties are often hypothesized to result from the large fraction of under-coordinated surface atoms. Here, we show that size-preselected Pt{sub 8-10} clusters stabilized on high-surface-area supports are 40-100 times more active for the oxidative dehydrogenation of propane than previously studied platinum and vanadia catalysts, while at the same time maintaining high selectivity towards formation of propylene over by-products. Quantum chemical calculations indicate that under-coordination of the Pt atoms in the clusters is responsible for the surprisingly high reactivity compared with extended surfaces. We anticipate that these results will form the basis for development of a new class of catalysts by providing a route to bond-specific chemistry, ranging from energy-efficient and environmentally friendly synthesis strategies to the replacement of petrochemical feedstocks by abundant small alkanes.

  8. Autoignited laminar lifted flames of propane in coflow jets with tribrachial edge and mild combustion

    SciTech Connect (OSTI)

    Choi, B.C.; Kim, K.N.; Chung, S.H. [School of Mechanical and Aerospace Engineering, Seoul National University, Seoul 151-744 (Korea)

    2009-02-15T23:59:59.000Z

    Characteristics of laminar lifted flames have been investigated experimentally by varying the initial temperature of coflow air over 800 K in the non-premixed jets of propane diluted with nitrogen. The result showed that the lifted flame with the initial temperature below 860 K maintained the typical tribrachial structure at the leading edge, which was stabilized by the balance mechanism between the propagation speed of tribrachial flame and the local flow velocity. For the temperature above 860 K, the flame was autoignited without having any external ignition source. The autoignited lifted flames were categorized in two regimes. In the case with tribrachial edge structure, the liftoff height increased nonlinearly with jet velocity. Especially, for the critical condition near blowout, the lifted flame showed a repetitive behavior of extinction and reignition. In such a case, the autoignition was controlled by the non-adiabatic ignition delay time considering heat loss such that the autoignition height was correlated with the square of the adiabatic ignition delay time. In the case with mild combustion regime at excessively diluted conditions, the liftoff height increased linearly with jet velocity and was correlated well with the square of the adiabatic ignition delay time. (author)

  9. A rapid compression machine study of the oxidation of propane in the negative temperature coefficient regime

    SciTech Connect (OSTI)

    Gallagher, S.M.; Curran, H.J.; Metcalfe, W.K.; Healy, D.; Simmie, J.M. [Combustion Chemistry Centre, National University of Ireland, Galway (Ireland); Bourque, G. [Rolls-Royce Canada, Montreal (Canada)

    2008-04-15T23:59:59.000Z

    The oxidation of propane has been studied in the temperature range 680-970 K at compressed gas pressures of 21, 27, and 37 atm and at varying equivalence ratios of 0.5, 1.0, and 2.0. These data are consistent with other experiments presented in the literature for alkane fuels in that, when ignition delay times are plotted as a function of temperature, a characteristic negative coefficient behavior is observed. In addition, these data were simulated using a detailed chemical kinetic model. It was found that qualitatively the model correctly simulated the effect of change in equivalence ratio and pressure, predicting that fuel-rich, high-pressure mixtures ignite fastest, while fuel-lean, low-pressure mixtures ignite slowest. Moreover, reactivity as a function of temperature is well captured, with the model predicting negative temperature coefficient behavior similar to the experiments. Quantitatively the model is faster than experiment for all mixtures at the lowest temperatures (650-750 K) and is also faster than experiment throughout the entire temperature range for fuel-lean mixtures. (author)

  10. Soot formation and temperature field structure in laminar propane-air diffusion flames at elevated pressures

    SciTech Connect (OSTI)

    Bento, Decio S.; Guelder, OEmer L. [Institute for Aerospace Studies, University of Toronto, 4925 Dufferin Street, Toronto, ON M3H 5T6 (Canada); Thomson, Kevin A. [National Research Council, ICPET Combustion Technology, 1200 Montreal Road M-9, Ontario K1A 0R6 (Canada)

    2006-06-15T23:59:59.000Z

    The effect of pressure on soot formation and the structure of the temperature field was studied in coflow propane-air laminar diffusion flames over the pressure range of 0.1 to 0.73 MPa in a high-pressure combustion chamber. The fuel flow rate was selected so that the soot was completely oxidized within the visible flame and the flame was stable at all pressures. Spectral soot emission was used to measure radially resolved soot volume fraction and soot temperature as a function of pressure. Additional soot volume fraction measurements were made at selected heights using line-of-sight light attenuation. Soot concentration values from these two techniques agreed to within 30% and both methods exhibited similar trends in the spatial distribution of soot concentration. Maximum line-of-sight soot concentration along the flame centerline scaled with pressure; the pressure exponent was about 1.4 for pressures between 0.2 and 0.73 MPa. Peak carbon conversion to soot, defined as the percentage of fuel carbon content converted to soot, also followed a power-law dependence on pressure, where the pressure exponent was near to unity for pressures between 0.2 and 0.73 MPa. Soot temperature measurements indicated that the overall temperatures decreased with increasing pressure; however, the temperature gradients increased with increasing pressure. (author)

  11. Operation of a Four-Cylinder 1.9L Propane Fueled HCCI Engine

    SciTech Connect (OSTI)

    Flowers, D; Aceves, S M; Martinez-Frias, J; Smith, J R; Au, M; Girard, J; Dibble, R

    2001-03-15T23:59:59.000Z

    A four-cylinder 1.9 Volkswagen TDI Engine has been converted to run in Homogeneous Charge Compression Ignition (HCCI) mode. The stock configuration is a turbocharged direct injection Diesel engine. The combustion chamber has been modified by discarding the in-cylinder Diesel fuel injectors and replacing them with blank inserts (which contain pressure transducers). The stock pistons contain a reentrant bowl and have been retained for the tests reported here. The intake and exhaust manifolds have also been retained, but the turbocharger has been removed. A heater has been installed upstream of the intake manifold and fuel is added just downstream of this heater. The performance of this engine in naturally aspirated HCCI operation, subject to variable intake temperature and fuel flow rate, has been studied. The engine has been run with propane fuel at a constant speed of 1800 rpm. This work is intended to characterize the HCCI operation of the engine in this configuration that has been minimally modified from the base Diesel engine. The performance (BMEP, IMEP, efficiency, etc) and emissions (THC, CO, NOx) of the engine are presented, as are combustion process results based on heat release analysis of the pressure traces from each cylinder.

  12. Oxidative Dehydrogenation of Propane over V2O5/MoO3/Al2O3 and V2O5/Cr2O3/Al2O3: Structural Characterization and Catalytic Function

    E-Print Network [OSTI]

    Bell, Alexis T.

    Oxidative Dehydrogenation of Propane over V2O5/MoO3/Al2O3 and V2O5/Cr2O3/Al2O3: Structural of stoichiometric reduction in H2, and the oxidative dehydrogenation of propane. VOx domains on Al2O3 modified The oxidative dehydrogenation (ODH) of propane provides an attractive route for the synthesis of propene.1

  13. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOE Patents [OSTI]

    Turick, Charles E. (Idaho Falls, ID)

    1997-01-01T23:59:59.000Z

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases.

  14. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOE Patents [OSTI]

    Turick, C.E.

    1997-06-10T23:59:59.000Z

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases. 3 figs.

  15. The safe use of low temperature liquefied gases 1. Introduction

    E-Print Network [OSTI]

    Martin, Ralph R.

    dioxide TABLE 1 Property Oxygen (O2) Nitrogen (N2) Argon (Ar) Helium (He) Carbon dioxide (CO2) Molecular.1 Objective 1.2 Gases considered and typical uses 2. Properties of low temperature liquefied atmospheric gases of BOC low temperature liquefied gases information on their properties, the hazards associated

  16. Hydrogen Storage -Overview George Thomas, Hydrogen Consultant to SNL*

    E-Print Network [OSTI]

    aspects of hydrogen utilization. production distribution utilization How do we achieve safe, efficient Forecourt storage (refueling stations) requirements being developed (IHIG) Distribution storage (delivery 75 100 125 hydrogen m ethane ethane propane butane pentane hexane heptane octane (gasoline) cetane

  17. Hydronic Heating Coil Versus Propane Furnace, Rehoboth Beach, Delaware (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-01-01T23:59:59.000Z

    Insight Homes constructed two houses in Rehoboth Beach, Delaware, with identical floor plans and thermal envelopes but different heating and domestic hot water (DHW) systems. Each house is 1,715-ft2 with a single story, three bedrooms, two bathrooms, and the heating, ventilation, and air conditioning (HVAC) systems and ductwork located in conditioned crawlspaces. The standard house, which the builder offers as its standard production house, uses an air source heat pump (ASHP) with supplemental propane furnace heating. The Building America test house uses the same ASHP unit with supplemental heat provided by the DHW heater (a combined DHW and hydronic heating system, where the hydronic heating element is in the air handler). Both houses were occupied during the test period. Results indicate that efficiency of the two heating systems was not significantly different. Three issues dominate these results; lower system design performance resulting from the indoor refrigerant coil selected for the standard house, an incorrectly functioning defrost cycle in the standard house, and the low resolution of the natural gas monitoring equipment. The thermal comfort of both houses fell outside the ASHRAE Standard 55 heating range but was within the ACCA room-to-room temperature range when compared to the thermostat temperature. The monitored DHW draw schedules were input into EnergyPlus to evaluate the efficiency of the tankless hot water heater model using the two monitored profiles and the Building America House Simulation Protocols. The results indicate that the simulation is not significantly impacted by the draw profiles.

  18. New fluorescence techniques for detecting noble gases

    SciTech Connect (OSTI)

    Whitaker, T.J.; Cannon, B.D.; Bushaw, B.A.

    1986-10-01T23:59:59.000Z

    Two new concepts for detecting noble gases are reported. Both techniques involve formation of the long-lived 1s/sup 5/ metastable state of noble gases. The first technique utilizes the photon-burst method and should be capable of isotopically selective detection at extremely small relative abundances. The second concept incorporates a shelving technique that stores noble gas atoms in the metastable state and then pumps these atoms to a higher excited state that radiatively cascades to the ground state, emitting vacuum ultraviolet (vuv) photons. A significant advantage is that AlGaAs diode lasers can be used for the techniques rather than continuous wave cw dye lasers. 5 refs., 1 fig.

  19. Glass Membrane For Controlled Diffusion Of Gases

    DOE Patents [OSTI]

    Shelby, James E. (Alfred Station, NY); Kenyon, Brian E. (Pittsburgh, PA)

    2001-05-15T23:59:59.000Z

    A glass structure for controlled permeability of gases includes a glass vessel. The glass vessel has walls and a hollow center for receiving a gas. The glass vessel contains a metal oxide dopant formed with at least one metal selected from the group consisting of transition metals and rare earth metals for controlling diffusion of the gas through the walls of the glass vessel. The vessel releases the gas through its walls upon exposure to a radiation source.

  20. Scanning electron microscopy of cold gases

    E-Print Network [OSTI]

    Santra, Bodhaditya

    2015-01-01T23:59:59.000Z

    Ultracold quantum gases offer unique possibilities to study interacting many-body quantum systems. Probing and manipulating such systems with ever increasing degree of control requires novel experimental techniques. Scanning electron microscopy is a high resolution technique which can be used for in situ imaging, single site addressing in optical lattices and precision density engineering. Here, we review recent advances and achievements obtained with this technique and discuss future perspectives.

  1. Method for introduction of gases into microspheres

    DOE Patents [OSTI]

    Hendricks, Charles D. (Livermore, CA); Koo, Jackson C. (San Ramon, CA); Rosencwaig, Allan (Danville, CA)

    1981-01-01T23:59:59.000Z

    A method for producing small hollow glass spheres filled with a gas by introduction of the gas during formation of the hollow glass spheres. Hollow glass microspheres having a diameter up to about 500.mu. with both thin walls (0.5 to 4.mu.) and thick walls (5 to 20.mu.) that contain various fill gases, such as Ar, Kr, Xe, Br, DT, H.sub.2, D.sub.2, He, N.sub.2, Ne, CO.sub.2, etc. in the interior thereof, can be produced by the diffusion of the fill gas or gases into the microsphere during the formation thereof from a liquid droplet of glass-forming solution. This is accomplished by filling at least a portion of the multiple-zone drop-furnace used in producing hollow microspheres with the gas or gases of interest, and then taking advantage of the high rate of gaseous diffusion of the fill gas through the wall of the gel membrane before it transforms into a glass microsphere as it is processed in the multiple-zone furnace. Almost any gas can be introduced into the inner cavity of a glass microsphere by this method during the formation of the microsphere provided that the gas is diffused into the gel membrane or microsphere prior to its transformation into glass. The process of this invention provides a significant savings of time and related expense of filling glass microspheres with various gases. For example, the time for filling a glass microballoon with 1 atmosphere of DT is reduced from about two hours to a few seconds.

  2. Seeded optical breakdown of molecular and noble gases

    SciTech Connect (OSTI)

    Polynkin, Pavel; Scheller, Maik; Moloney, Jerome V. [College of Optical Sciences, University of Arizona 1630 E. University Blvd., Tucson, Arizona 85721 (United States)

    2012-07-30T23:59:59.000Z

    We report experimental results on the dual laser-pulse plasma excitation in various gases at atmospheric pressure. Dilute plasma channels generated through filamentation of ultraintense femtosecond laser pulses in air, argon, and helium are densified through the application of multi-Joule nanosecond heater pulses. Optical breakdown in atomic gases can be achieved for considerably longer delays between femtosecond and nanosecond pulses compared to that in molecular gases. The densification of the seed channel in molecular gases is always accompanied by its fragmentation into discrete bubbles, while in atomic gases the densified channel remains smooth and continuous.

  3. ED-XAS Data Reveal In-situ Time-Resolved Adsorbate Coverage on Supported Molybdenum Oxide Catalysts during Propane Dehydrogenation

    SciTech Connect (OSTI)

    Ramaker, David; Gatewood, Daniel [Department of Chemistry, George Washington University, Washington D.C. 20052 (United States); Beale, Andrew M.; Weckhuysen, Bert M. [Inorganic Chemistry and Catalysis, Dept. of Chem., Utrecht University, Sorbonnelaan 16, 3584 CA Utrecht (Netherlands)

    2007-02-02T23:59:59.000Z

    Energy-Dispersive X-ray Absorption Spectroscopy (ED-XAS) data combined with UV/Vis, Raman, and mass spectrometry data on alumina- and silica-supported molybdenum oxide catalysts under propane dehydrogenation conditions have been previously reported. A novel {delta}{mu} adsorbate isolation technique was applied here to the time-resolved (0.1 min) Mo K-edge ED-XAS data by taking the difference of absorption, {mu}, at t>1 against the initial time, t=0. Further, full multiple scattering calculations using the FEFF 8.0 code are performed to interpret the {delta}{mu} signatures. The resulting difference spectra and interpretation provide real time propane coverage and O depletion at the MoOn surface. The propane coverage is seen to correlate with the propene and/or coke production, with the maximum coke formation occurring when the propane coverage is the largest. Combined, these data give unprecedented insight into the complicated dynamics for propane dehydrogenation.

  4. State heating oil & propane program. Final report for the Commonwealth of Pennsylvania 1994--1995 heating season

    SciTech Connect (OSTI)

    NONE

    1995-05-18T23:59:59.000Z

    This report has been prepared by the Pennsylvania Energy Office (PEO) to summarize its activities under the State Heating Oil and Propane Program (SHOPP) for the 1994-95 heating season. The PEO is under a cooperative agreement, Agreement DE-7C01-91E122784, Amendment No. 3, with the U.S. Department of Energy, Energy Information Administration (DOE/EIA) to conduct these activities. The objective of the SHOPP program was to collect Pennsylvania-specific price information for residential No. 2 heating oil and propane and transmit this information to DOE/EIA for compilation into its various reports and publications. Under the PEO`s cooperative agreement with DOE/EIA, prices were collected on the first and third Mondays of each month, starting on October 3, 1994, and extending through March 20, 1995. Prices were obtained via telephone calls made by PEO staff. For each heating oil distributor in the survey sample, the PEO collected charge prices for a standard delivery quantity of No. 2 heating oil. For propane, dealers were requested to provide the price for a customer using between one thousand and fifteen hundred gallons of fuel during the heating season. The PEO agreed to forward the survey results to the DOE/EIA within three days of the date of each survey. DOE/EIA`s responsibility was to compile the data from all states and distribute a bi-weekly report. In addition, DOE/EIA took responsibility for the collection of primary stock information for No. 2 heating oil.

  5. The catalytic oxidation of propane and propylene with air: total aldehyde production and selectivity at low conversions.

    E-Print Network [OSTI]

    Looney, Franklin Sittig

    1950-01-01T23:59:59.000Z

    ~ Ths writer is izntebteg to pr, P G~ ~och Tor his assistance azsi guidance in this work aC to Br~ J+ 9 Kinds Tor his aery. suggestions eel Succor~ a The oxidation cf propane~ propylene and prcya~cregyimm mbetccres ctver a ~ aiucdna ~st in a flew... vere developed for rms with Iow propylene pressers Froa ths recncits of this study it, appears that the reaction yieldiccg aldehyde occurs in the fere part af the reactec bed Increased oxidation br' about by tunreased residence tins causes eccidation...

  6. NOAA Data Report ERL PMEL-2 LOW MOLECULAR WEIGHT HYDROCARBON CONCENTRATIONS (C1 -c4),

    E-Print Network [OSTI]

    or imply that the NOAA Environ- mental Research Laboratories approves, recommends, or endorses any pro) variations in the dissolved gaseous hydrocarbon fraction composed of methane, ethane, ethene, propane

  7. High-Pressure Micellar Solutions of Polystyrene-block-Polybutadiene and Polystyrene-block-Polyisoprene Solutions in Propane Exhibit Cloud-Pressure Reduction and Distinct Micellization End Points

    SciTech Connect (OSTI)

    Winoto, Winoto [University of Wyoming, Laramie; Radosz, Maciej [University of Wyoming, Laramie; Tan, Sugata [University of Wyoming, Laramie; Hong, Kunlun [ORNL; Mays, Jimmy [ORNL

    2009-01-01T23:59:59.000Z

    Micellar solutions of polystyrene-block-polybutadiene and polystyrene-block-polyisoprene in propane are found to exhibit significantly lower cloud pressures than the corresponding hypothetical non-micellar solutions. Such a cloud-pressure reduction indicates the extent to which micelle formation enhances the apparent diblock solubility in near-critical and hence compressible propane. Pressure-temperature points beyond which no micelles can be formed, referred to as the micellization end points, are found to depend on the block type, size and ratio, and on the polymer concentration. For a given pressure, the micellization end-point temperature corresponds to the "critical micelle temperature." The cloud-pressure reduction and the micellization end point measured for styrene-diene diblocks in propane should be characteristic of all amphiphilic diblock copolymer solutions that form micelles in compressible solvents.

  8. Supplement of "Inversion of and emissions

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    ¦&¡ ¤¢' ethane ¦&¡ ¤ ethylene ¦( ¤¢) propane ¦( ¤¢' propylene 0 ¨1 234¦&# ¤¢) $ isoprene 5 2 06£ 4¦ 768 ¤ 7 propylene ¦ ¤ %¦§ S © ¤ peracetic acid ¦( ¤©a © ¤ peroxide from propane 5 ¦!b!@ © ¤ 4¦ ¤ %¦§ S ¦ ¤ % ©¡ methylperoxy radical 2& ¢¡4¦( ¤¢' ¤ ¢¡%$ peroxy radical from propylene 5 ¦!b!@ ¢¡4¦ ¤ ¥¦§ S

  9. Photophysics and Luminescence Spectroelectrochemistry of [Tc(dmpe)3]+/2+ (dmpe = 1,2-bis(dimethylphosphino)ethane)

    SciTech Connect (OSTI)

    Chatterjee, Sayandev; Del Negro, Andrew S.; Smith, Frances N.; Wang, Zheming; Hightower, Sean E.; Sullivan, Brian P.; Heineman, William R.; Seliskar, Carl J.; Bryan, Samuel A.

    2013-12-05T23:59:59.000Z

    The ligand-to-metal charge transfer (LMCT) excited state luminescence of [Tc(dmpe)3]2+ (dmpe is 1,2-bis-(dimethylphosphino)ethane) has been measured in solution at room temperature, and is compared to its Re analogue. Surprisingly, both [M(dmpe)3]2+* (M = Re, Tc) species have extremely large excited-state potentials (ESPs) as oxidants - the highest for any simple coordination complex of a transition metal. Furthermore, this potential is available using a photon of visible light (calculated for M = Re(Tc); E1/2* = +2.61(2.48) V versus SCE; ?max = 526(585) nm). Open shell TDDFT calculations support the assignment of the lowest energy transition in both the technetium and rhenium complexes to be a doublet-doublet process that involve predominantly LMCT (dmpe-to-metal) character and is in agreement with past assignments for the Re system. As expected for highly oxidizing excited state potentials, quenching is observed for the excited states by both the rhenium and technetium complexes. Stern-Volmer analysis resulted in quenching parameters for both the rhenium and technetium complexes under identical conditions, and are compared using Rehm-Weller analysis. Of particular interest is the fact that both benzene and toluene are oxidized by both the Re and Tc systems.

  10. CHARACTERIZATION STUDIES OF THE SELECTIVE REDUCTION OF NO by NH3

    E-Print Network [OSTI]

    Brown, N.J.

    2013-01-01T23:59:59.000Z

    post combustion gases of propane/air in a laboratory scalepost combustion gases of propane/air in a laboratory scaleThe combustion products of propane and air are diluted by

  11. A Sequential Fluid-mechanic Chemical-kinetic Model of Propane HCCI Combustion

    SciTech Connect (OSTI)

    Aceves, S M; Flowers, D L; Martinez-Frias, J; Smith, J R; Westbrook, C; Pitz, W; Dibble, R; Wright, J F; Akinyemi, W C; Hessel, R P

    2000-11-29T23:59:59.000Z

    We have developed a methodology for predicting combustion and emissions in a Homogeneous Charge Compression Ignition (HCCI) Engine. This methodology combines a detailed fluid mechanics code with a detailed chemical kinetics code. Instead of directly linking the two codes, which would require an extremely long computational time, the methodology consists of first running the fluid mechanics code to obtain temperature profiles as a function of time. These temperature profiles are then used as input to a multi-zone chemical kinetics code. The advantage of this procedure is that a small number of zones (10) is enough to obtain accurate results. This procedure achieves the benefits of linking the fluid mechanics and the chemical kinetics codes with a great reduction in the computational effort, to a level that can be handled with current computers. The success of this procedure is in large part a consequence of the fact that for much of the compression stroke the chemistry is inactive and thus has little influence on fluid mechanics and heat transfer. Then, when chemistry is active, combustion is rather sudden, leaving little time for interaction between chemistry and fluid mixing and heat transfer. This sequential methodology has been capable of explaining the main characteristics of HCCI combustion that have been observed in experiments. In this paper, we use our model to explore an HCCI engine running on propane. The paper compares experimental and numerical pressure traces, heat release rates, and hydrocarbon and carbon monoxide emissions. The results show an excellent agreement, even in parameters that are difficult to predict, such as chemical heat release rates. Carbon monoxide emissions are reasonably well predicted, even though it is intrinsically difficult to make good predictions of CO emissions in HCCI engines. The paper includes a sensitivity study on the effect of the heat transfer correlation on the results of the analysis. Importantly, the paper also shows a numerical study on how parameters such as swirl rate, crevices and ceramic walls could help in reducing HC and CO emissions from HCCI engines.

  12. United States Department of Energy New Jersey Department of Environmental Protection and Energy. 1991--1992 Heating Oil and Propane Price Monitoring Program

    SciTech Connect (OSTI)

    NONE

    1998-12-31T23:59:59.000Z

    In cooperation with the United States Department of Energy (USDOE), Energy Information Administration (EIA) the New Jersey Department of Environmental Protection and Energy (DEPE), Office of Energy participated in a program to monitor retail prices of no. 2 heating oil and propane in New Jersey. According to program instructions, we conducted price surveys on a semi-monthly basis to obtain the necessary information from retail fuel merchants and propane dealers identified by the EIA. The period of the surveys was October 7, 1991 to March 16 1992. We submitted data collected as of specified reference dates to the EIA, within two working days of those dates.

  13. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)IntegratedSpeedingTechnicalPurchase, Delivery, and Storage of Gases Print ALS users

  14. Method for controlling corrosion in thermal vapor injection gases

    DOE Patents [OSTI]

    Sperry, John S. (Houston, TX); Krajicek, Richard W. (Houston, TX)

    1981-01-01T23:59:59.000Z

    An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

  15. The greenhouse gases HFCs, PFCs Danish consumption and emissions, 2007

    E-Print Network [OSTI]

    The greenhouse gases HFCs, PFCs and SF6 Danish consumption and emissions, 2007 Tomas Sander Poulsen AND EMISSION OF F-GASES 7 1.1.1 Consumption 7 1.1.2 Emission 7 1.1.3 Trends in total GWP contribution from F 21 4 EMISSION OF F-GASES 23 4.1.1 Emissions of HFCs from refrigerants 23 4.1.2 Emissions of HFCs from

  16. Theory of ultracold atomic Fermi gases

    SciTech Connect (OSTI)

    Giorgini, Stefano; Pitaevskii, Lev P.; Stringari, Sandro [Dipartimento di Fisica, Universita di Trento and CNR-INFM BEC Center, I-38050 Povo, Trento (Italy); Dipartimento di Fisica, Universita di Trento and CNR-INFM BEC Center, I-38050 Povo, Trento, Italy and Kapitza Institute for Physical Problems, ul. Kosygina 2, 117334 Moscow (Russian Federation); Dipartimento di Fisica, Universita di Trento and CNR-INFM BEC Center, I-38050 Povo, Trento (Italy)

    2008-10-15T23:59:59.000Z

    The physics of quantum degenerate atomic Fermi gases in uniform as well as in harmonically trapped configurations is reviewed from a theoretical perspective. Emphasis is given to the effect of interactions that play a crucial role, bringing the gas into a superfluid phase at low temperature. In these dilute systems, interactions are characterized by a single parameter, the s-wave scattering length, whose value can be tuned using an external magnetic field near a broad Feshbach resonance. The BCS limit of ordinary Fermi superfluidity, the Bose-Einstein condensation (BEC) of dimers, and the unitary limit of large scattering length are important regimes exhibited by interacting Fermi gases. In particular, the BEC and the unitary regimes are characterized by a high value of the superfluid critical temperature, on the order of the Fermi temperature. Different physical properties are discussed, including the density profiles and the energy of the ground-state configurations, the momentum distribution, the fraction of condensed pairs, collective oscillations and pair-breaking effects, the expansion of the gas, the main thermodynamic properties, the behavior in the presence of optical lattices, and the signatures of superfluidity, such as the existence of quantized vortices, the quenching of the moment of inertia, and the consequences of spin polarization. Various theoretical approaches are considered, ranging from the mean-field description of the BCS-BEC crossover to nonperturbative methods based on quantum Monte Carlo techniques. A major goal of the review is to compare theoretical predictions with available experimental results.

  17. New Materials for Capturing Carbon Dioxide from Combustion Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to APS Science Highlights rss feed New Materials for Capturing Carbon Dioxide from Combustion Gases April 9, 2014 Bookmark and Share The SIFSIX materials in order of increasing...

  18. adjacente dos gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nature Le Roy, Robert J. 437 Classical disordered ground states: Super-ideal gases and stealth and equi-luminous materials Chemistry Websites Summary: Classical disordered...

  19. Finalize Historic National Program to Reduce Greenhouse Gases...

    Open Energy Info (EERE)

    Finalize Historic National Program to Reduce Greenhouse Gases and Improve Fuel Economy for Cars and Trucks Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Finalize...

  20. Experimental studies of steam and steam-propane injection using a novel smart horizontal producer to enhance oil production in the San Ardo field 

    E-Print Network [OSTI]

    Rivero Diaz, Jose Antonio

    2007-09-17T23:59:59.000Z

    is the use of propane as a steam additive with the purpose of increasing recovery and accelerating oil production. The second process involves the use of a novel production configuration that makes use of a vertical injector and a smart horizontal producer...

  1. Experimental study of oil yields and properties of light and medium Venezuelan crude oils under steam and steam-propane distillation 

    E-Print Network [OSTI]

    Plazas Garcia, Joyce Vivia

    2002-01-01T23:59:59.000Z

    Six experimental runs were carried out to study the yields for a light crude oil (34.2°API) and an intermediate crude oil (25.1°API) under steam distillation and steam-propane distillation. Yields, were measured at five temperatures, 110, 150, 200...

  2. An In-Situ XAS Study of the Structural Changes in a CuO-CeO2/Al2O3 Catalyst during Total Oxidation of Propane

    SciTech Connect (OSTI)

    Silversmith, Geert; Poelman, Hilde; Poelman, Dirk; Gryse, Roger de [Ghent University, Department of Solid State Sciences, Krijgslaan 281 S1, B-9000 Gent (Belgium); Olea, Maria; Balcaen, Veerle; Heynderickx, Philippe; Marin, Guy B. [Ghent University, Laboratorium voor Petrochemische Techniek, Krijgslaan 281 S5, B-9000 Gent (Belgium)

    2007-02-02T23:59:59.000Z

    A CuOx-CeOx/Al2O3 catalyst was studied with in-situ transmission Cu K XAS for the total oxidation of propane as model reaction for the catalytic elimination of volatile organic compounds. The local Cu structure was determined for the catalyst as such, after pre-oxidation and after reduction with propane. The catalyst as such has a local CuO structure. No structural effect was observed upon heating in He up to 600 deg. C or after pre-oxidation at 150 deg. C. A full reduction of the Cu2+ towards metallic Cu0 occurred, when propane was fed to the catalyst. The change in local Cu structure during propane reduction was followed with a time resolution of 1 min. The {chi}(k) scans appeared as linear combinations of start and end spectra, CuO and Cu structure, respectively. However, careful examination of the XANES edge spectra indicates the presence of a small amount of additional Cu1+ species.

  3. Experimental study of oil yields and properties of light and medium Venezuelan crude oils under steam and steam-propane distillation

    E-Print Network [OSTI]

    Plazas Garcia, Joyce Vivia

    2002-01-01T23:59:59.000Z

    Six experimental runs were carried out to study the yields for a light crude oil (34.2°API) and an intermediate crude oil (25.1°API) under steam distillation and steam-propane distillation. Yields, were measured at five temperatures, 110, 150, 200...

  4. Influence of low and high temperature coking of H-GaMFI propane aromatization catalyst on its surface and catalytic properties

    SciTech Connect (OSTI)

    Choudhary, V.R.; Kinage, A.K.; Devadas, P. [National Chemical Lab., Pune (India)] [and others] [National Chemical Lab., Pune (India); and others

    1997-03-01T23:59:59.000Z

    H-Gallosilicate (MFI) (i.e., H-GaMFI) zeolite shows high activity/selectivity in the aromatization of lower alkanes, which is processes of treat practical importance. The high aromatization activity of this catalyst is attributed to its high dehydrogenation activity due to the presence of high dispersed nonframework Ga-oxide species (which are formed during hydrothermal synthesis and/or pretreatments to the zeolite) along with the zeolitic acid sites (or framework Ga), resulting in a bifunctional catalyst. However, this zeolite undergoes fast catalyst deactivation in the propane aromatization. The catalyst deactivation is attributed mainly to the coke formation on the zeolite. Earlier, a few studies have been reported on the deactivation of H-GaMFI zeolite in the propane aromatization. The catalyst deactivation is attributed mainly to the coke formation on the zeolite. Earlier, a few studies have been reported on the deactivation of H-GaMFI zeolite in the propane aromatization at 500-550{degrees}C for a short time-on-stream (10 h). It is interesting to know the effect of catalyst deactivation due to coking in the propane aromatization for much longer periods both at low (at 400{degrees}C) and high (at 550{degrees}C) temperatures on the product selectivity and also on the surface (viz., sorption capacity, acidity/acid strength distribution) and catalytic properties of the zeolite. The present investigation was undertaken for this purpose. 16 refs., 1 fig., 3 tabs.

  5. Bench-Scale Synthetic Optimization of 1,2-bis(2-aminophenylthio)ethane (APO-Link) Used in the Production of APO-BMI Resin

    SciTech Connect (OSTI)

    Hilary Wheeler; Crystal Densmore

    2007-07-31T23:59:59.000Z

    The diamine reagent 1,2-bis(2-aminophenylthio)ethane is no longer commercially available but still required for the synthesis of the bismaleimide resin, APO-BMI, used in syntactic foams. In this work, we examined the hydrolysis of benzothiazole followed the by reaction with dichloroethane or dibromoethane. We also studied the deprotonation of 2-aminothiophenol followed by the reaction with dibromoethane. We optimized the latter for scale-up by scrutinizing all aspects of the reaction conditions, work-up and recrystallization. On bench-scale, our optimized procedure consistently produced a 75-80% overall yield of finely divided, high purity product (>95%).

  6. Finite Temperature Gases of Fermionic Strings

    E-Print Network [OSTI]

    Shyamoli Chaudhuri

    2005-09-12T23:59:59.000Z

    We show that in the absence of a Ramond-Ramond sector both the type IIA and type IIB free string gases have a thermal instability due to low temperature tachyon modes. The gas of free IIA strings undergoes a thermal duality transition into a gas of free IIB strings at the self-dual temperature. The free heterotic string gas is a tachyon-free ensemble with gauge symmetry SO(16)$\\times$SO(16) in the presence of a timelike Wilson line background. It exhibits a holographic duality relation undergoing a self-dual phase transition with positive free energy and positive specific heat. The type IB open and closed string ensemble is related by thermal duality to the type I' string ensemble. We identify the order parameter for the Kosterlitz-Thouless phase transition from a low temperature gas of short open strings to a high temperature long string phase at or below T_C. Note Added (Sep 2005).

  7. Voluntary reporting of greenhouse gases 1997

    SciTech Connect (OSTI)

    NONE

    1999-05-01T23:59:59.000Z

    The Voluntary Reporting of Greenhouse Gases Program, required by Section 1605(b) of the Energy Policy Act of 1992, records the results of voluntary measures to reduce, avoid, or sequester greenhouse gas emissions. In 1998, 156 US companies and other organizations reported to the Energy information Administration that, during 1997, they had achieved greenhouse gas emission reductions and carbon sequestration equivalent to 166 million tons of carbon dioxide, or about 2.5% of total US emissions for the year. For the 1,229 emission reduction projects reported, reductions usually were measured by comparing an estimate of actual emissions with an estimate of what emissions would have been had the project not been implemented.

  8. The preliminary result from spectra of $K^0_s ?^-$ in reaction p+propane at 10 GeV/c

    E-Print Network [OSTI]

    P. Zh. Aslanyan

    2006-05-04T23:59:59.000Z

    The experimental data from 2m propane bubble chamber have been analyzed to search for scalar meson $\\kappa(800)$ in a $K^0_s\\pi$ decay mode for the reaction p+$C_3H_8$ at 10 GeV/c. The $K^0_s\\pi^-$ invariant mass spectrum has shown resonant structures with $M_{K^0_s\\pi^-}$=730, 900 and $\\Gamma$=143, 48 MeV/$c^2$, respectively. The statistical significance are estimated to be of 14.2$\\sigma$ and 4.2$\\sigma$, respectively. The peak in M(900) is identified as reflection from the well known resonance with mass of 892 MeV/c$^2$.

  9. Continuous cryopump with a method for removal of solidified gases

    DOE Patents [OSTI]

    Carlson, L.W.; Herman, H.

    1988-05-05T23:59:59.000Z

    An improved cryopump for the removal of gases from a high vacuum, comprising a cryopanel incorporating honeycomb structure, refrigerant means thermally connected to the cryopanel, and a rotatable channel moving azimuthally around an axis located near the center of the cryopanel, removing gases adsorbed within the honeycomb structure by subliming them and conducting them outside the vacuum vessel. 4 figs.

  10. AMIII Termodinamica dos Gases Ideais 17 de Janeiro de 2002

    E-Print Network [OSTI]

    Natário, José

    AMIII ­ Termodinâ??amica dos Gases Ideais 17 de Janeiro de 2002 N moles de um gâ??as ideal em equil dos gases ideais). A Primeira Lei da Termodinâ??amica afirma que existe uma funâ?ºcâ?ao E : M # R, dita pela Segunda Lei da Termodinâ??amica. 2 #12;

  11. Biological Removal of Siloxanes from Landfill and Digester Gases

    E-Print Network [OSTI]

    Biological Removal of Siloxanes from Landfill and Digester Gases: Opportunities and Challenges S U) presents challenges for using landfill and digester gases as energy fuels because of the formation volatilize from waste at landfills and wastewater treatment plants (1). As a result, biogas produced

  12. Measurement of transient nonlinear refractive index in gases using xenon

    E-Print Network [OSTI]

    Milchberg, Howard

    Measurement of transient nonlinear refractive index in gases using xenon supercontinuum single measurement of ultrafast high field processes using modest energy lasers, with pump and probe pulses totaling) and instrument resolution. The ultrafast nonlinear Kerr effect in glass, and in Ar, N2, and N2O gases is measured

  13. TIME-VARYING FLAME IONIZATION SENSING APPLIED TO NATURAL GAS AND PROPANE BLENDS IN A PRESSURIZED LEAN PREMIXED (LPM) COMBUSTOR

    SciTech Connect (OSTI)

    D. L. Straub; B. T. Chorpening; E. D. Huckaby; J. D. Thornton; W. L. Fincham

    2008-06-13T23:59:59.000Z

    In-situ monitoring of combustion phenomena is a critical need for optimal operation and control of advanced gas turbine combustion systems. The concept described in this paper is based on naturally occurring flame ionization processes that accompany the combustion of hydrocarbon fuels. Previous work has shown that flame ionization techniques may be applied to detect flashback, lean blowout, and some aspects of thermo-acoustic combustion instabilities. Previous work has focused on application of DC electric fields. By application of time-varying electric fields, significant improvements to sensor capabilities have been observed. These data have been collected in a lean premixed combustion test rig operating at 0.51-0.76 MPa (5-7.5 atm) with air preheated to 588 K (600°F). Five percent of the total fuel flow is injected through the centerbody tip as a diffusion pilot. The fuel composition is varied independently by blending approximately 5% (volume) propane with the pipeline natural gas. The reference velocity through the premixing annulus is kept constant for all conditions at a nominal value of 70 m/s. The fuel-air equivalence ratio is varied independently from 0.46 – 0.58. Relative to the DC field version, the time-varying combustion control and diagnostic sensor (TV-CCADS) shows a significant improvement in the correlation between the measured flame ionization current and local fuel-air equivalence ratio. In testing with different fuel compositions, the triangle wave data show the most distinct change in flame ionization current in response to an increase in propane content. Continued development of this sensor technology will improve the capability to control advanced gas turbine combustion systems, and help address issues associated with variations in fuel supplies.

  14. Compressible Solution Properties of Amorphous Polystyrene-block-Polybutadiene, Crystalline Polystyrene-block-Poly(Hydrogenated Polybutadiene) and Their Corresponding Homopolymers: Fluid-Fluid, Fluid-Solid and Fluid-Micelle Phase Transitions in Propane and Propylene

    SciTech Connect (OSTI)

    Hong, Kunlun [ORNL; Mays, Jimmy [ORNL; Winoto, Winoto [University of Wyoming, Laramie; Radosz, Maciej [University of Wyoming, Laramie

    2009-01-01T23:59:59.000Z

    Abstract Polystyrene, polybutadiene, hydrogenated polybutadiene, and styrene diblock copolymers of these homopolymers can form homogenous solutions in compressible solvents, such as propane and propylene, which separate into two bulk phases upon reducing pressure. The cloud and micellization pressures for homopolymer and diblock copolymers are generally found to be higher in propane than in propylene, except for hydrogenated polybutadiene and polystyrene-block-(hydrogenated polybutadiene). Hydrogenated polybutadiene homopolymers and copolymers exhibit relatively pressure-independent crystallization and melting observed in both propane and propylene solutions.

  15. Biodegradation of ddt (1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane) by the white rot fungus phanerochaete chrysosporium

    SciTech Connect (OSTI)

    Bumpus, J.A.; Aust, S.D.

    1987-01-01T23:59:59.000Z

    Extensive biodegradation of 1,1,1-trichloro-2,2bis(4-chlorophenyl)ethane (DDT) by the white rot fungus Phanerochaete chrysosporium was demonstrated by disappearance and mineralization of (14C) DDT in nutrient nitrogen-deficient cultures. Mass balance studies demonstrated the formation of polar and water-soluble metabolites during degradation. Hexane-extractable metabolites identified by gas chromatography-mass spectrometry included 1,1-dichloro-2,2-bis(4-chlorophenyl)ethane(DDD), 2,2,2-trichloro-1,1-bis(4-chlorophenyl)ethanol (dicofol), 2,2-dichloro-1,1-bis(4-chlorophenyl) ethanol (FW-152), and 4,4'-dichlorobenzophenone (DBP). DDD was the first metabolite observed; it appeared after 3 days of incubation and disappeared from culture upon continued incubation. This, as well as the fact that ((14)C) dicofol was mineralized, demonstrates that intermediates formed during DDT degradation are also metabolized. These results demonstrate that the pathway for DDT degradation in P. chrysosporium is clearly different from the major pathway proposed for microbial or environmental degradation of DDT. Like P. chrysosporium ME-446 and BKM-F-1767, the white rot fungi Pleurotus ostreatus, Phellinus weirii, and Polyporus versicolor also mineralized DDT.

  16. Measuring non-condensable gases in steam

    SciTech Connect (OSTI)

    Doornmalen, J. P. C. M. van; Kopinga, K., E-mail: k.kopinga@tue.nl [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)

    2013-11-15T23:59:59.000Z

    In surgery, medical devices that are used should be sterilized. To obtain surface steam sterilization conditions, not only in the sterilizer chamber itself but also in the loads to be sterilized, the amount of non-condensable gases (NCGs), for instance air, should be very low. Even rather small fractions of NCGs (below 1 %) seriously hamper steam penetration in porous materials or devices with hollow channels (e.g., endoscopes). A recently developed instrument which might detect the presence of residual NCGs in a reliable and reproducible way is the 3M{sup TM} Electronic Test System (ETS). In this paper, a physical model is presented that describes the behavior of this instrument. This model has been validated by experiments in which known fractions of NCGs were introduced in a sterilizer chamber in which an ETS was placed. Despite several approximations made in the model, a good agreement is found between the model predictions and the experimental results. The basic principle of the ETS, measuring the heat transfer by condensation on a cooled surface, permits a very sensitive detection of NCGs in harsh environments like water vapor at high temperatures and pressures. Our model may serve to develop adapted and optimized versions of this instrument for use outside the field of sterilization, e.g., in heat exchangers based on steam condensation.

  17. High-precision optical measurements of 13 isotope ratios in organic compounds at

    E-Print Network [OSTI]

    Zare, Richard N.

    range with an average precision of 0.95 and 0.67 for ethane and propane, respec- tively. The calibrated accuracy for methane, ethane, and propane is within 3 of the values determined using isotope ratio mass place in chemistry, especially in geochemistry, for determining reaction mechanisms and pro- viding

  18. DOI: 10.1126/science.1194777 , 211 (2010);330Science

    E-Print Network [OSTI]

    Fineberg, Jay

    2010-01-01T23:59:59.000Z

    .colleagues, clients, or customers by , you can order high-quality copies for yourIf you wish to distribute hydrocarbon plumes is delayed with respect to that of ethane-, propane-, and butane-consuming communities. To identify potential propane- and ethane- consuming bacteria active in the deep plumes, we collected cells

  19. ORIGINAL RESEARCH ARTICLE published: 14 May 2013

    E-Print Network [OSTI]

    Girguis, Peter R.

    examined the metabolism of ethane (C2), propane (C3), and butane (C4) in anoxic sediments in contrast-chain alkanes, sulfate reduction INTRODUCTION Hydrocarbongases,includingmethane(C1),ethane(C2),propane (C3, ecological physiology, and diversity of microorganisms mediating this process and the global distribution

  20. 396 J. Phys. Chem. 1990, 94, 396-409 Reaction of Cyclopropane, Methylcyclopropane, and Propylene with Hydrogen on the

    E-Print Network [OSTI]

    Goodman, Wayne

    . Consequently, from an exam- ination of a relatively simple product distribution (methane, ethane, and propane hydrogenation to propane and the hydrogenolysis to methane and ethane, with the hydrogenation channel dominating the two surfaces for hydrogenolysis,the product distributions for the major reaction channels were CH4+ C

  1. Measurements of Laminar Flame Velocity for Components of Natural Gas

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    flame velocity of components of natural gas, methane, ethane, propane, and nbutane as well as of binary% by volume (1). The laminar flame velocities of methane/air, ethane/air, and propane/air mixtures have on a plenum chamber with the radial temperature distribution measurement made by a series of thermocouples

  2. Experimental and artificial neural network modeling study on soot formation in premixed hydrocarbon flamesq

    E-Print Network [OSTI]

    Senkan, Selim M.

    The formation of soot in premixed flames of methane, ethane, propane, and butane was studied at three different particle diameters at higher distances above the burner surface and propane, ethane, and butane flames came conditions in humans. Polycyclic aromatic hydro- carbons (PAH), the largest class of chemical carcinogens

  3. Cryogenic method for measuring nuclides and fission gases

    DOE Patents [OSTI]

    Perdue, P.T.; Haywood, F.F.

    1980-05-02T23:59:59.000Z

    A cryogenic method is provided for determining airborne gases and particulates from which gamma rays are emitted. A special dewar counting vessel is filled with the contents of the sampling flask which is immersed in liquid nitrogen. A vertically placed sodium-iodide or germanium-lithium gamma-ray detector is used. The device and method are of particular use in measuring and identifying the radioactive noble gases including emissions from coal-fired power plants, as well as fission gases released or escaping from nuclear power plants.

  4. INVESTIGATION ON THE FLAME EXTINCTION LIMIT OF FUEL BLENDS

    SciTech Connect (OSTI)

    Ahsan R. Choudhuri

    2005-02-01T23:59:59.000Z

    Lean flame extinction limits of binary fuel mixtures of methane (CH{sub 4}), propane (C{sub 3}H{sub 8}), and ethane (C{sub 2}H{sub 6}) were measured using a twin-flame counter-flow burner. Experiments were conducted to generate an extinction equivalence ratio vs. global stretch rate plot and an extrapolation method was used to calculate the equivalence ratio corresponding to an experimentally unattainable zero-stretch condition. The foregoing gases were selected because they are the primary constitutes of natural gas, which is the primary focus of the present study. To validate the experimental setup and methodology, the flame extinction limit of pure fuels at zero stretch conditions were also estimated and compared with published values. The lean flame extinction limits of methane (f{sub ext} = 4.6%) and propane (f{sub ext} = 2.25%) flames measured in the present study agreed with the values reported in the literature. It was observed that the flame extinction limit of fuel blends have a polynomial relation with the concentration of component fuels in the mixture. This behavior contradicts with the commonly used linear Le Chatelier's approximation. The experimentally determined polynomial relations between the flame extinction limits of fuel blends (i.e. methane-propane and methane-ethane) and methane concentration are as follows: (1) Methane-Propane--%f{sub ext} = (1.05 x 10{sup -9}) f{sup 5}-(1.3644 x 10{sup -7}) f{sup 4}+(6.40299 x 10{sup -6}) f{sup 3}-(1.2108459 x 10{sup -4}) f{sup 2}+(2.87305329 x 10{sup -3}) f+2.2483; (2) Methane-Ethane--%f{sub ext} = (2.1 x 10{sup -9})f{sup 5}-(3.5752 x 10{sup -7}) f{sup 4}+(2.095425 x 10{sup -5}) f{sup 3}-(5.037353 x 10{sup -4}) f{sup 2} + 6.08980409 f + 2.8923. Where f{sub ext} is the extinction limits of methane-propane and methane-ethane fuel blends, and f is the concentration (% volume) of methane in the fuel mixture. The relations were obtained by fitting fifth order curve (polynomial regression) to experimentally measured extinction limits at different mixture conditions. To extend the study to a commercial fuel, the flame extinction limit for Birmingham natural gas (a blend of 95% methane, 5% ethane and 5% nitrogen) was experimentally determined and was found to be 3.62% fuel in the air-fuel mixture.

  5. Reading Out Visual Information from Populations of Neurons in ITC and PFC Ethan Meyers1,2, David Freedman3,4, Earl Miller1,3, Gabriel Kreiman2,5, Tomaso Poggio1,2

    E-Print Network [OSTI]

    Kreiman, Gabriel

    Reading Out Visual Information from Populations of Neurons in ITC and PFC Ethan Meyers1,2, David were trained on the firing rates of 256 randomly chosen neurons from either ITC or PFC (only neurons/trial choice) is the main statistic we report. 443 ITC, 525 PFC neurons were recording from two rhesus macaque

  6. Catalytic dehydrogenation of ethane

    E-Print Network [OSTI]

    Place, Harold Glenn

    1955-01-01T23:59:59.000Z

    -Grew-Hill Pub. Co? 1950 ' Frey, F. E. and Huppke, W. F. , Ind. Ehg. Chem. , 25, 54 (1933). Burgin& J. , Gr oil& H. , and Roberts& R M & Nat'1. Petr. News, 30, R 432 (1938). Grosse, A. V. and Ipatieff, V. N. , Ind. ~En . Chem. , 32, (19) Riess, C. H...) Brooks, F. R. , et al. , Anal. Chem. , 21, 1105 (1949). (26) Johanson, L. N. and Watson, K. M , Nat'1. Petr. Neve, 1946. For Runs 1, 2, 3, and Composite Sample, conditions were the same, as follows: Flow rate - 0. 0515 cfm, mass of catalyst - 33. 5...

  7. Ethane/Ethylene Exports

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40Coal Stocks at1,066,688Electricity Use as an IndicatorNatural GasRevenueMay9 70

  8. Direct growth of few-layer graphene on 6H-SiC and 3C-SiC/Si via propane chemical vapor deposition

    SciTech Connect (OSTI)

    Michon, A.; Vezian, S.; Portail, M. [CNRS-CRHEA, Rue Bernard Gregory, 06560 Valbonne (France); Ouerghi, A. [CNRS-LPN, Route de Nozay, 91460 Marcoussis (France); Zielinski, M.; Chassagne, T. [NOVASiC, Savoie Technolac, Arche Bat 4, BP267, 73375 Le Bourget du Lac (France)

    2010-10-25T23:59:59.000Z

    We propose to grow graphene on SiC by a direct carbon feeding through propane flow in a chemical vapor deposition reactor. X-ray photoemission and low energy electron diffraction show that propane allows to grow few-layer graphene (FLG) on 6H-SiC(0001). Surprisingly, FLG grown on (0001) face presents a rotational disorder similar to that observed for FLG obtained by annealing on (000-1) face. Thanks to a reduced growth temperature with respect to the classical SiC annealing method, we have also grown FLG/3C-SiC/Si(111) in a single growth sequence. This opens the way for large-scale production of graphene-based devices on silicon substrate.

  9. Nanostructure of Solid Precipitates Obtained by Expansion of Polystyrene-block-Polybutadiene Solutions in Near Critical Propane: Block Ratio and Micellar Solution Effects

    SciTech Connect (OSTI)

    Green, Jade [University of Wyoming, Laramie; Tyrrell, Zachary [University of Wyoming, Laramie; Radosz, Maciej [University of Wyoming, Laramie; Hong, Kunlun [ORNL; Mays, Jimmy [ORNL

    2011-01-01T23:59:59.000Z

    In contrast to incompressible liquid solutions, compressible near-critical solutions of block copolymers allow for controlling rapid structure transformations with pressure alone. For example, when dissolved in near-critical propane, polystyrene-block-polybutadiene can form a random molecular solution at high pressures, a micellar solution at moderate pressures, and a solvent-free precipitate at low pressures. In contrast to the unstructured virgin copolymer, such a propane-treated precipitate rapidly self-assembles toward structures characteristic of equilibrated block copolymers, such as lamellae, spheres, or cylinders, which depend on the block ratio rather than on the decompression rate or temperature, at least within the rate and temperature ranges investigated in this work. At lower temperatures, however, say below 40 C, glass transition of the styrene-butadiene diblocks can inhibit independent structure formation, while crystallization of their hydrogenated-butadiene analogues can preserve the micellar-solution structure.

  10. Deuteration Can Impact Micellization Pressure and Cloud Pressure of Polystyrene-block-polybutadiene and Polystyrene-block-polyisoprene in Compressible Propane

    SciTech Connect (OSTI)

    Winoto, Winoto [University of Wyoming, Laramie; Shen, Youqin [University of Wyoming, Laramie; Radosz, Maciej [University of Wyoming, Laramie; Hong, Kunlun [ORNL; Mays, Jimmy [ORNL

    2009-01-01T23:59:59.000Z

    The deuterated homopolymers and their corresponding polystyrene-block-polybutadiene and polystyrene-block-polyisoprene copolymers require lower cloud pressures than their hydrogenous analogues to dissolve in a compressible alkane solvent, such as propane. For symmetric diblocks, deuteration reduces the micellization pressure. By contrast, for asymmetric diblocks with a long diene block relative to the styrene block, deuteration can increase the micellization pressure. All in all, however, the deuteration effects, while measurable, do not qualitatively change the principal diblock properties in compressible propane solutions, such as pressure-induced micelle decomposition, micelle formation and micelle size, and their temperature dependence. Therefore, isotope labeling should be a useful approach to neutron-scattering characterization for styrene-diene block copolymers in compressible alkane systems.

  11. H-gallosilicate (MFI) propane aromatization catalyst: Influence of Si/Ga ratio on acidity, activity and deactivation due to coking

    SciTech Connect (OSTI)

    Choudhary, V.R.; Kinage, A.K.; Sivadinarayana, C. [National Chemical Lab., Pune (India)] [and others] [National Chemical Lab., Pune (India); and others

    1996-01-01T23:59:59.000Z

    Influence of bulk Si/Ga ratio of H-gallosilicate (MFI) on its degalliation (during calcination for removal of template and deammoniation of NH{sub 4} form), acidity/acid strength distribution (measured by stepwise thermal desorption and chemisorption of pyridine at 50-400{degrees}C using GC techniques and also by acid catalyzed model reactions viz. iso-octane cracking and toluene disproportionation) and initial activity/product selectivity and catalyst deactivation in propane aromatization (at 550{degrees}C) has been investigated. Framework Si/Ga ratio was measured by {sup 29}Si MAS NMR. Information on the external acid sites is obtained by isooctane cracking. The influence of poisoning of strong acid sites (by pyridine) on acid catalyzed model reactions and the effect of deactivation on the product distribution in the propane aromatization have also been studied. 21 refs., 19 figs., 3 tabs.

  12. Viscosities of natural gases at high pressures and high temperatures

    E-Print Network [OSTI]

    Viswanathan, Anup

    2007-09-17T23:59:59.000Z

    Estimation of viscosities of naturally occurring petroleum gases provides the information needed to accurately work out reservoir-engineering problems. Existing models for viscosity prediction are limited by data, especially at high pressures...

  13. Studying coherence in ultra-cold atomic gases

    E-Print Network [OSTI]

    Miller, Daniel E. (Daniel Edward)

    2007-01-01T23:59:59.000Z

    This thesis will discuss the study of coherence properties of ultra-cold atomic gases. The atomic systems investigated include a thermal cloud of atoms, a Bose-Einstein condensate and a fermion pair condensate. In each ...

  14. The Release of Trapped Gases from Amorphous Solid Water Films...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    I. Top-Down" Crystallization-Induced Crack Propagation Probed The Release of Trapped Gases from Amorphous Solid Water Films: I. Top-Down" Crystallization-Induced Crack Propagation...

  15. Low-Value Waste Gases as an Energy Source 

    E-Print Network [OSTI]

    Waibel, R. T.

    1996-01-01T23:59:59.000Z

    Waste gases with potentially useful fuel value are generated at any number of points in refineries, chemical plants and other industrial and commercial sites. The higher quality streams have been utilized successfully in fuel systems for years...

  16. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, C.R.; Ernstberger, E.G.

    1985-07-03T23:59:59.000Z

    A method for monitoring the stack gases of a purge cascade of gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases. 1 fig.

  17. Helium Isotopes in Geothermal and Volcanic Gases of the Western...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Helium Isotopes in Geothermal and Volcanic Gases of the Western United States, II. Long...

  18. Helium Isotopes In Geothermal And Volcanic Gases Of The Western...

    Open Energy Info (EERE)

    Helium Isotopes In Geothermal And Volcanic Gases Of The Western United States, I, Regional Variability And Magmatic Origin Jump to: navigation, search OpenEI Reference LibraryAdd...

  19. Geochemical Data on Waters, Gases, Scales, and Rocks from the...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999)...

  20. Low-Value Waste Gases as an Energy Source

    E-Print Network [OSTI]

    Waibel, R. T.

    Waste gases with potentially useful fuel value are generated at any number of points in refineries, chemical plants and other industrial and commercial sites. The higher quality streams have been utilized successfully in fuel systems for years...

  1. Radio-frequency spectroscopy of ultracold atomic Fermi gases

    E-Print Network [OSTI]

    Schirotzek, Andre

    2010-01-01T23:59:59.000Z

    This thesis presents experiments investigating the phase diagram of ultracold atomic Fermi gases using radio-frequency spectroscopy. The tunability of many experimental parameters including the temperature, the interparticle ...

  2. Method of producing pyrolysis gases from carbon-containing materials

    DOE Patents [OSTI]

    Mudge, Lyle K. (Richland, WA); Brown, Michael D. (West Richland, WA); Wilcox, Wayne A. (Kennewick, WA); Baker, Eddie G. (Richland, WA)

    1989-01-01T23:59:59.000Z

    A gasification process of improved efficiency is disclosed. A dual bed reactor system is used in which carbon-containing feedstock materials are first treated in a gasification reactor to form pyrolysis gases. The pyrolysis gases are then directed into a catalytic reactor for the destruction of residual tars/oils in the gases. Temperatures are maintained within the catalytic reactor at a level sufficient to crack the tars/oils in the gases, while avoiding thermal breakdown of the catalysts. In order to minimize problems associated with the deposition of carbon-containing materials on the catalysts during cracking, a gaseous oxidizing agent preferably consisting of air, oxygen, steam, and/or mixtures thereof is introduced into the catalytic reactor at a high flow rate in a direction perpendicular to the longitudinal axis of the reactor. This oxidizes any carbon deposits on the catalysts, which would normally cause catalyst deactivation.

  3. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, Claude R. (Paducah, KY); Ernstberger, Harold G. (Paducah, KY)

    1988-01-01T23:59:59.000Z

    A method for monitoring the stack gases of a purge cascade of a gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases.

  4. active trace gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OF GEOPHYSICAL RESEARCH, VOL. 94, NO. D13, PAGES 16,417-16,421,NOVEMBER 20, 1989 Greenhouse Effect of Chlorofluorocarbons and Other Trace Gases Environmental Sciences and Ecology...

  5. Acid strength of support materials as a factor controlling oxidation state of palladium catalyst for propane combustion

    SciTech Connect (OSTI)

    Yazawa, Yoshiteru; Yoshida, Hisao; Takagi, Nobuyuki; Komai, Shinichi; Satsuma, Atsushi; Hattori, Tadashi

    1999-10-01T23:59:59.000Z

    The support effect on the low temperature catalytic combustion of propane over palladium catalyst was studied by using a series of metal oxides as support materials: MgO, ZrO{sub 2}, Al{sub 2}O{sub 3}, SiO{sub 2}, SiO{sub 2}-ZrO{sub 2}, SiO{sub 2}-Al{sub 2}O{sub 3}, and SO{sub 4}{sup 2{minus}}-ZrO{sub 2}. The catalytic activity varied with the kind of support materials; a support material with moderate acid strength gave maximum conversion. In order to discuss more details, 5 wt% Pd/ZrO{sub 2}, Pd/Al{sub 2}O{sub 3}, and Pd/SiO{sub 2}-Al{sub 2}O{sub 3} were subjected to catalytic testing under the various conditions, and the catalysts after the test were characterized by XRD and XPS. The activity changed with the oxygen concentration, and the concentration providing the maximum activity depended on the support material. The maximum activity was obtained at high concentration on Pd/SiO{sub 2}-Al{sub 2}O{sub 3}, at moderate concentration on Pd/Al{sub 2}O{sub 3}, and at low concentration on Pd/ZrO{sub 2}. This sequence corresponded to that of acid strength of the support materials measured by Hammett indicators. The relation between the oxidation state of palladium and its catalytic activity under the various mixtures indicated that the catalytic activity on each catalyst depends on the oxidation state of palladium, and that partially oxidized palladium is effective for propane combustion. Moreover, palladium on acidic support kept the metallic state even under high oxygen concentration, indicating that acidic support gives palladium the resistibility against oxidation. These results suggest one guideline for the design of active palladium catalyst; an acidic support must be chosen under the mixture of the higher oxygen concentration and vice versa.

  6. TECHNICAL JUSTIFICATION FOR CHOOSING PROPANE AS A CALIBRATION AGENT FOR TOTAL FLAMMABLE VOLATILE ORGANIC COMPOUND (VOC) DETERMINATIONS

    SciTech Connect (OSTI)

    DOUGLAS, J.G.

    2006-07-06T23:59:59.000Z

    This document presents the technical justification for choosing and using propane as a calibration standard for estimating total flammable volatile organic compounds (VOCs) in an air matrix. A propane-in-nitrogen standard was selected based on a number of criteria: (1) has an analytical response similar to the VOCs of interest, (2) can be made with known accuracy and traceability, (3) is available with good purity, (4) has a matrix similar to the sample matrix, (5) is stable during storage and use, (6) is relatively non-hazardous, and (7) is a recognized standard for similar analytical applications. The Waste Retrieval Project (WRP) desires a fast, reliable, and inexpensive method for screening the flammable VOC content in the vapor-phase headspace of waste containers. Table 1 lists the flammable VOCs of interest to the WRP. The current method used to determine the VOC content of a container is to sample the container's headspace and submit the sample for gas chromatography--mass spectrometry (GC-MS) analysis. The driver for the VOC measurement requirement is safety: potentially flammable atmospheres in the waste containers must be allowed to diffuse prior to processing the container. The proposed flammable VOC screening method is to inject an aliquot of the headspace sample into an argon-doped pulsed-discharge helium ionization detector (Ar-PDHID) contained within a gas chromatograph. No actual chromatography is performed; the sample is transferred directly from a sample loop to the detector through a short, inert transfer line. The peak area resulting from the injected sample is proportional to the flammable VOC content of the sample. However, because the Ar-PDHID has different response factors for different flammable VOCs, a fundamental assumption must be made that the agent used to calibrate the detector is representative of the flammable VOCs of interest that may be in the headspace samples. At worst, we desire that calibration with the selected calibrating agent overestimate the value of the VOCs in a sample. By overestimating the VOC content of a sample, we want to minimize false negatives. A false negative is defined as incorrectly estimating the VOC content of the sample to be below programmatic action limits when, in fact, the sample,exceeds the action limits. The disadvantage of overestimating the flammable VOC content of a sample is that additional cost may be incurred because additional sampling and GC-MS analysis may be required to confirm results over programmatic action limits. Therefore, choosing an appropriate calibration standard for the Ar-PDHID is critical to avoid false negatives and to minimize additional analytical costs.

  7. Vanadium oxide based nanostructured materials for catalytic oxidative dehydrogenation of propane : effect of heterometallic centers on the catalyst performance.

    SciTech Connect (OSTI)

    Khan, M. I.; Deb, S.; Aydemir, K.; Alwarthan, A. A.; Chattopadhyay, S.; Miller, J. T.; Marshall, C. L. (Chemical Sciences and Engineering Division); (Illinois Inst. of Tech.); (King Saud Univ.)

    2010-01-01T23:59:59.000Z

    Catalytic properties of a series of new class of catalysts materials-[Co{sub 3}(H{sub 2}O){sub 12}V{sub 18}O{sub 42} (XO{sub 4})].24H{sub 2}O (VNM-Co), [Fe{sub 3}(H{sub 2}O){sub 12}V{sub 18}O{sub 42}(XO{sub 4})].24H{sub 2}O (VNM-Fe) (X = V, S) and [H{sub 6}Mn{sub 3}(H{sub 2}O){sub 12}V{sub 18}O{sub 42}(VO{sub 4})].30H{sub 2}O for the oxidative dehydrogenation of propane is studied. The open-framework nanostructures in these novel materials consist of three-dimensional arrays of {l_brace}V{sub 18}O{sub 42}(XO{sub 4}){r_brace} (X = V, S) clusters interconnected by {l_brace}-O-M-O-{r_brace} (M = Mn, Fe, Co) linkers. The effect of change in the heterometallic center M (M = Mn, Co, Fe) of the linkers on the catalyst performance was studied. The catalyst material with Co in the linker showed the best performance in terms of propane conversion and selectivity at 350 C. The material containing Fe was most active but least selective and Mn containing catalyst was least active. The catalysts were characterized by Temperature Programmed Reduction (TPR), BET surface area measurement, Diffuse Reflectance Infrared Fourier Transform Spectroscopy, and X-ray Absorption Spectroscopy. TPR results show that all three catalysts are easily reducible and therefore are active at relatively low temperature. In situ X-ray absorption near edge spectroscopy (XANES) and extended X-ray absorption fine structure spectroscopy (EXAFS) studies revealed that the oxidation state of Co(II) remained unchanged up to 425 C (even after pretreatment). The reduction of Co(II) into metallic form starts at 425 C and this process is completed at 600 C.

  8. Performance and Emissions Characteristics of Bio-Diesel (B100)-Ignited Methane and Propane Combustion in a Four Cylinder Turbocharged Compression Ignition Engine

    SciTech Connect (OSTI)

    Shoemaker, N. T.; Gibson, C. M.; Polk, A. C.; Krishnan, S. R.; Srinivasan, K. K.

    2011-10-05T23:59:59.000Z

    Different combustion strategies and fuel sources are needed to deal with increasing fuel efficiency demands and emission restrictions. One possible strategy is dual fueling using readily available resources. Propane and natural gas are readily available with the current infrastructure and biodiesel is growing in popularity as a renewable fuel. This paper presents experimental results from dual fuel combustion of methane (as a surrogate for natural gas) and propane as primary fuels with biodiesel pilots in a 1.9 liter, turbocharged, 4 cylinder diesel engine at 1800 rev/min. Experiments were performed with different percentage energy substitutions (PES) of propane and methane and at different brake mean effective pressures (BMEP/bmep). Brake thermal efficiency (BTE) and emissions (NOx, HC, CO, CO2, O2 and smoke) were also measured. Maximum PES levels for B100-methane dual fuelling were limited to 70% at 2.5 bar bmep and 48% at 10 bar bmep, and corresponding values for B100-propane dual fuelling were 64% and 43%, respectively. Maximum PES was limited by misfire at 2.5 bar bmep and the onset of engine knock at 10 bar bmep. Dual fuel BTEs approached straight B100 values at 10 bar bmep while they were significantly lower than B100 values at 2.5 bar bmep. In general dual fuelling was beneficial in reducing NOx and smoke emissions by 33% and 50%, respectively from baseline B100 levels; however, both CO and THC emissions were significantly higher than baseline B100 levels at all PES and loads.

  9. Process for the removal of acid forming gases from exhaust gases

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (San Pablo, CA)

    1992-01-01T23:59:59.000Z

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. are attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO and SO.sub.2 can be removed in an economic fashion.

  10. Process for the removal of acid forming gases from exhaust gases

    DOE Patents [OSTI]

    Chang, S.G.; Liu, D.K.

    1992-11-17T23:59:59.000Z

    Exhaust gases are treated to remove NO or NO[sub x] and SO[sub 2] by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50 C is attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO[sub x] and SO[sub 2], alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO[sub x] and SO[sub 2] can be removed in an economic fashion. 9 figs.

  11. Chapter 4 The Gaseous State Chemistry of Gases

    E-Print Network [OSTI]

    Ihee, Hyotcherl

    .15 V = V0[1+(t/273.15oC)] Kelvin T = 273.15 + t(Celsius) #12;Boyle's Law · The stirling engine, a heatChapter 4 The Gaseous State NO2 #12;AIR #12;Chemistry of Gases SO3 .. corrosive gas SO2...burning) ~1760 Charle The definition of the Temperature All gases expand with increasing temperature by the same

  12. Biological production of ethanol from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    2000-01-01T23:59:59.000Z

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products is disclosed. The method includes introducing the waste gases into a bioreactor where they are fermented to various product, such as organic acids, alcohols H.sub.2, SCP, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  13. Effects of pressure, temperature, and hydrogen during graphene growth on SiC(0001) using propane-hydrogen chemical vapor deposition

    SciTech Connect (OSTI)

    Michon, A.; Vezian, S.; Roudon, E.; Lefebvre, D.; Portail, M. [CNRS-CRHEA, Rue Bernard Gregory, 06560 Valbonne (France)] [CNRS-CRHEA, Rue Bernard Gregory, 06560 Valbonne (France); Zielinski, M.; Chassagne, T. [NOVASiC, Savoie Technolac, Arche Bat 4, BP267, 73375 Le Bourget du Lac (France)] [NOVASiC, Savoie Technolac, Arche Bat 4, BP267, 73375 Le Bourget du Lac (France)

    2013-05-28T23:59:59.000Z

    Graphene growth from a propane flow in a hydrogen environment (propane-hydrogen chemical vapor deposition (CVD)) on SiC differentiates from other growth methods in that it offers the possibility to obtain various graphene structures on the Si-face depending on growth conditions. The different structures include the (6{radical}3 Multiplication-Sign 6{radical}3)-R30 Degree-Sign reconstruction of the graphene/SiC interface, which is commonly observed on the Si-face, but also the rotational disorder which is generally observed on the C-face. In this work, growth mechanisms leading to the formation of the different structures are studied and discussed. For that purpose, we have grown graphene on SiC(0001) (Si-face) using propane-hydrogen CVD at various pressure and temperature and studied these samples extensively by means of low energy electron diffraction and atomic force microscopy. Pressure and temperature conditions leading to the formation of the different structures are identified and plotted in a pressure-temperature diagram. This diagram, together with other characterizations (X-ray photoemission and scanning tunneling microscopy), is the basis of further discussions on the carbon supply mechanisms and on the kinetics effects. The entire work underlines the important role of hydrogen during growth and its effects on the final graphene structure.

  14. Effect of heat recirculation on the self-sustained catalytic combustion of propane/air mixtures in a quartz reactor

    SciTech Connect (OSTI)

    Scarpa, A. [Dipartimento di Ingegneria Chimica, Universita degli Studi di Napoli ''Federico II'', P.le V. Tecchio 80, 80125 Naples (Italy); Department of Chemical Engineering, Center for Catalytic Science and Technology (CCST), and Center for Composite Materials (CCM), University of Delaware, 150 Academy Street, Newark, DE 19716 (United States); Pirone, R. [Istituto di Ricerche sulla Combustione-CNR, P.le V. Tecchio 80, 80125 Naples (Italy); Russo, G. [Dipartimento di Ingegneria Chimica, Universita degli Studi di Napoli ''Federico II'', P.le V. Tecchio 80, 80125 Naples (Italy); Vlachos, D.G. [Department of Chemical Engineering, Center for Catalytic Science and Technology (CCST), and Center for Composite Materials (CCM), University of Delaware, 150 Academy Street, Newark, DE 19716 (United States)

    2009-05-15T23:59:59.000Z

    The self-sustained catalytic combustion of propane is experimentally studied in a two-pass, quartz heat-recirculation reactor (HRR) and compared to that in a no (heat) recirculation reactor (NRR). Structured monolithic reactors with Pt/{gamma}-Al{sub 2}O{sub 3}, LaMnO{sub 3}/{gamma}-Al{sub 2}O{sub 3}, and Pt doped perovskite catalysts have been compared in the HRR and NRR configurations. Heat recirculation enhances combustion stability, by widening the operating window of self-sustained operation, and changes the mode of stability loss from blowout to extinction. It is found that thermal shields (upstream and downstream of the monolith) play no role in the stability of a HRR but increase the stability of a NRR. The stability of a HRR follows this trend: Pt/{gamma}-Al{sub 2}O{sub 3} > doped perovskite > LaMnO{sub 3}/{gamma}-Al{sub 2}O{sub 3}. Finally, a higher cell density monolith enlarges the operating window of self-sustained combustion, and allows further increase of the power density of the process. (author)

  15. Synthesis of Pt?Pd Core?Shell Nanostructures by Atomic Layer Deposition: Application in Propane Oxidative Dehydrogenation to Propylene

    SciTech Connect (OSTI)

    Lei, Y.; Liu, Bin; Lu, Junling; Lobo-Lapidus, Rodrigo J.; Wu, Tianpin; Feng, Hao; Xia, Xiaoxing; Mane, Anil U.; Libera, Joseph A.; Greeley, Jeffrey P.; Miller, Jeffrey T.; Elam, J. W.

    2012-08-20T23:59:59.000Z

    Atomic layer deposition (ALD) was employed to synthesize supported Pt?Pd bimetallic particles in the 1 to 2 nm range. The metal loading and composition of the supported Pt?Pd nanoparticles were controlled by varying the deposition temperature and by applying ALD metal oxide coatings to modify the support surface chemistry. Highresolution scanning transmission electron microscopy images showed monodispersed Pt?Pd nanoparticles on ALD Al2O3 - and TiO2 -modi?ed SiO2 gel. X-ray absorption spectroscopy revealed that the bimetallic nanoparticles have a stable Pt-core, Pd-shell nanostructure. Density functional theory calculations revealed that the most stable surface con?guration for the Pt? Pd alloys in an H2 environment has a Pt-core, Pd-shell nanostructure. In comparison to their monometallic counterparts, the small Pt?Pd bimetallic core?shell nanoparticles exhibited higher activity in propane oxidative dehydrogenation as compared to their physical mixture.

  16. Dynamic light scattering in sooting premixed atmospheric-pressure methane-, propane-, ethene-, and propene-oxygen flames

    SciTech Connect (OSTI)

    Lamprecht, A.; Eimer, W.; Kohse-Hoeinghaus, K. [Univ. Bielefeld (Germany)] [Univ. Bielefeld (Germany)

    1999-07-01T23:59:59.000Z

    In a systematic investigation under well-defined flame conditions, dynamic light scattering (DLS) was applied to the determination of soot particle radii with the aim of examining the suitability of this technique for accurate soot particle sizing. In particular, flat premixed methane-, propane-, ethene-, and propene-oxygen flames at atmospheric pressure were investigated, and particle sizes were obtained as a function of stoichiometry and height above the burner surface. In combination with absorption measurements, soot volume fraction and particle number density were determined; also, the temperature was measured at each flame condition. In comparison to absorption techniques, attractive features of DLS are its independence of the particle refractive index and its insensitivity to fluorescence interference; also, it offers spatial resolution. In principle, additional information on the particle size distribution as well as on the global shape of the particles may be obtained from DLS experiments. This study is therefore an evaluation of the potential of DLS as a complement to other soot diagnostic techniques.

  17. Propane ammoxidation over the Mo-V-Te-Nb-O M1 phase: Reactivity of surface cations in hydrogen abstraction steps

    SciTech Connect (OSTI)

    Muthukumar, Kaliappan [University of Cincinnati; Yu, Junjun [University of Cincinnati; Xu, Ye [ORNL; Guliants, Vadim V. [University of Cincinnati

    2011-01-01T23:59:59.000Z

    Density functional theory calculations (GGA-PBE) have been performed to investigate the adsorption of C3 (propane, isopropyl, propene, and allyl) and H species on the proposed active center present in the surface ab planes of the bulk Mo-V-Te-Nb-O M1 phase in order to better understand the roles of the different surface cations in propane ammoxidation. Modified cluster models were employed to isolate the closely spaced V=O and Te=O from each other and to vary the oxidation state of the V cation. While propane and propene adsorb with nearly zero adsorption energy, the isopropyl and allyl radicals bind strongly to V=O and Te=O with adsorption energies, {Delta}E, being {le} -1.75 eV, but appreciably more weakly on other sites, such as Mo=O, bridging oxygen (Mo-O-V and Mo-O-Mo), and empty metal apical sites ({Delta}E > -1 eV). Atomic H binds more strongly to Te = O ({Delta}E {le} -3 eV) than to all the other sites, including V = O ({Delta}E = -2.59 eV). The reduction of surface oxo groups by dissociated H and their removal as water are thermodynamically favorable except when both H atoms are bonded to the same Te=O. Consistent with the strong binding of H, Te=O is markedly more active at abstracting the methylene H from propane (E{sub a} {le} 1.01 eV) than V = O (E{sub a} = 1.70 eV on V{sup 5+} = O and 2.13 eV on V{sup 4+} = O). The higher-than-observed activity and the loose binding of Te = O moieties to the mixed metal oxide lattice of M1 raise the question of whether active Te = O groups are in fact present in the surface ab planes of the M1 phase under propane ammoxidation conditions.

  18. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, Kenneth C. (Bolingbrook, IL); Markun, Francis (Joliet, IL); Zawadzki, Mary T. (South Bend, IN)

    1998-01-01T23:59:59.000Z

    An apparatus and method for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir.

  19. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, K.C.; Markun, F.; Zawadzki, M.T.

    1998-04-28T23:59:59.000Z

    An apparatus and method are disclosed for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir. 6 figs.

  20. Realization of effective super Tonks-Girardeau gases via strongly attractive one-dimensional Fermi gases

    SciTech Connect (OSTI)

    Chen Shu; Yin Xiangguo; Guan Liming [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Guan Xiwen [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Batchelor, M. T. [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Mathematical Sciences Institute, Australian National University, Canberra ACT 0200 (Australia)

    2010-03-15T23:59:59.000Z

    A significant feature of the one-dimensional super Tonks-Girardeau gas is its metastable gas-like state with a stronger Fermi-like pressure than for free fermions which prevents a collapse of atoms. This naturally suggests a way to search for such strongly correlated behavior in systems of interacting fermions in one dimension. We thus show that the strongly attractive Fermi gas without polarization can be effectively described by a super Tonks-Girardeau gas composed of bosonic Fermi pairs with attractive pair-pair interaction. A natural description of such super Tonks-Girardeau gases is provided by Haldane generalized exclusion statistics. In particular, they are equivalent to ideal particles obeying more exclusive statistics than Fermi-Dirac statistics.

  1. Process for removing hydrogen sulfide from gases particularly coal pyrolysis gases

    SciTech Connect (OSTI)

    Ritter, H.; Herpers, E.T.

    1985-02-12T23:59:59.000Z

    Hydrogen sulfide is first removed by ammoniacal liquor from coke oven gas in the bottom part of a gas scrubber. In the top part of the scrubber, two consecutively-arranged fine scrubbing stages remove hydrogen sulfide by treating the gases, in the upper stage, with a caustic soda solution or a caustic potash solution. Beneath the upper scrubbing stage is the second fine scrubbing stage fed with a subflow of an aqueous carbonate solution collecting at the outlet of the upper fine scrubbing stage and a subflow of cooled, regenerated carbonate solution discharged from the hydrogen-sulfide/hydrogen-cyanide stripper. From the hydrogen-sulfide/hydrogen-cyanide stripper, a second subflow is admixed with coal liquor for removing fixed ammonia therefrom in a separator. The separator produces water vapor with carbon dioxide vapors that are delivered to the hydrogen-sulfide/hydrogen-cyanide stripper for regenerating the aqueous carbonate washing solution.

  2. Process for the removal of acid forming gases from exhaust gases and production of phosphoric acid

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (San Pablo, CA)

    1992-01-01T23:59:59.000Z

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorous preferably in a wet scrubber. The addition of yellow phosphorous in the system induces the production of O.sub.3 which subsequently oxidizes NO to NO.sub.2. The resulting NO.sub.2 dissolves readily and can be reduced to form ammonium ions by dissolved SO.sub.2 under appropriate conditions. In a 20 acfm system, yellow phosphorous is oxidized to yield P.sub.2 O.sub.5 which picks up water to form H.sub.3 PO.sub.4 mists and can be collected as a valuable product. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, better than 90% of SO.sub.2 and NO in simulated flue gas can be removed. Stoichiometric ratios (P/NO) ranging between 0.6 and 1.5 were obtained.

  3. Emissions Of Greenhouse Gases From Rice Agriculture

    SciTech Connect (OSTI)

    M. Aslam K. Khalil

    2009-07-16T23:59:59.000Z

    This project produced detailed data on the processes that affect methane and nitrous oxide emissions from rice agriculture and their inter-relationships. It defines the shifting roles and potential future of these gases in causing global warming and the benefits and tradeoffs of reducing emissions. The major results include: 1). Mechanisms and Processes Leading to Methane Emissions are Delineated. Our experiments have tested the standard model of methane emissions from rice fields and found new results on the processes that control the flux. A mathematical mass balance model was used to unravel the production, oxidation and transport of methane from rice. The results suggested that when large amounts of organic matter are applied, the additional flux that is observed is due to both greater production and reduced oxidation of methane. 2). Methane Emissions From China Have Been Decreasing Over the Last Two Decades. We have calculated that methane emissions from rice fields have been falling in recent decades. This decrease is particularly large in China. While some of this is due to reduced area of rice agriculture, the bigger effect is from the reduction in the emission factor which is the annual amount of methane emitted per hectare of rice. The two most important changes that cause this decreasing emission from China are the reduced use of organic amendments which have been replaced by commercial nitrogen fertilizers, and the increased practice of intermittent flooding as greater demands are placed on water resources. 3). Global Methane Emissions Have Been Constant For More Than 20 Years. While the concentrations of methane in the atmosphere have been leveling off in recent years, our studies show that this is caused by a near constant total global source of methane for the last 20 years or more. This is probably because as some anthropogenic sources have increased, others, such as the rice agriculture source, have fallen. Changes in natural emissions appear small. 4). Nitrous Oxide Emissions From Rice Fields Increase as Methane Emissions Drop. Inundated conditions favor anaerobic methane production with high emission rates and de-nitrification resulting in modest nitrous oxide emissions. Under drier conditions such as intermittent flooding, methane emissions fall and nitrous oxide emissions increase. Increased nitrogen fertilizer use increases nitrous oxide emissions and is usually accompanied by reduced organic matter applications which decreases methane emissions. These mechanisms cause a generally inverse relationship between methane and nitrous oxide emissions. Reduction of methane from rice agriculture to control global warming comes with tradeoffs with increased nitrous oxide emissions. 5). High Spatial Resolution Maps of Emissions Produced. Maps of methane and nitrous oxide emissions at a resolution of 5 min × 5 min have been produced based on the composite results of this research. These maps are necessary for both scientific and policy uses.

  4. Evaluation of exposures of hospital employees to anesthetic gases

    SciTech Connect (OSTI)

    Lambeth, J.D.

    1988-01-01T23:59:59.000Z

    Hospital employees who work in hospital operating and recovery rooms are often exposed to a number of anesthetic gases. There is evidence to support the belief that such exposures have led to higher rates of miscarriages and spontaneous abortions of pregnancies among women directly exposed to these gases than among women not exposed. Most of the studies assessing exposure levels were conducted prior to the widespread use of scavenging systems. Air sampling was conducted in hospital operatories and recovery rooms of three large hospitals to assess the current exposure levels in these areas and determine the effectiveness of these systems in reducing exposures to fluoride-containing anesthetic gases. It was determined that recovery-room personnel are exposed to levels of anesthesia gases that often approach and exceed the recommended Threshold Limit Value-Time Weighted Average (TLV-TWA) of 2.0 ppm. Recovery-room personnel do not have the protection from exposure provided by scavenging systems in operating rooms. Operating-room personnel were exposed to anesthesia gas levels above the TLV-TWA only when patients were masked, or connected and disconnected from the scavenging systems. Recovery-room personnel also need to be protected from exposure to anesthesia gases by a scavenging system.

  5. Shock tube and theoretical studies on the thermal decomposition of propane : evidence for a roaming radical channel.

    SciTech Connect (OSTI)

    Sivaramakrishnan, R.; Su, M.-C.; Michael, J. V.; Klippenstein, S. J.; Harding, L. B.; Ruscic, B. (Chemical Sciences and Engineering Division)

    2011-04-21T23:59:59.000Z

    The thermal decomposition of propane has been studied using both shock tube experiments and ab initio transition state theory-based master equation calculations. Dissociation rate constants for propane have been measured at high temperatures behind reflected shock waves using high-sensitivity H-ARAS detection and CH{sub 3} optical absorption. The two major dissociation channels at high temperature are C{sub 3}H{sub 8} {yields} CH{sub 3} + C{sub 2}H{sub 5} (eq 1a) and C{sub 3}H{sub 8} {yields} CH{sub 4} + C{sub 2}H{sub 4} (eq 1b). Ultra high-sensitivity ARAS detection of H-atoms produced from the decomposition of the product, C{sub 2}H{sub 5}, in (1a), allowed measurements of both the total decomposition rate constants, k{sub total}, and the branching to radical products, k{sub 1a}/k{sub total}. Theoretical analyses indicate that the molecular products are formed exclusively through the roaming radical mechanism and that radical products are formed exclusively through channel 1a. The experiments were performed over the temperature range 1417-1819 K and gave a minor contribution of (10 {+-} 8%) due to roaming. A multipass CH{sub 3} absorption diagnostic using a Zn resonance lamp was also developed and characterized in this work using the thermal decomposition of CH{sub 3}I as a reference reaction. The measured rate constants for CH{sub 3}I decomposition agreed with earlier determinations from this laboratory that were based on I-atom ARAS measurements. This CH{sub 3} diagnostic was then used to detect radicals from channel 1a allowing lower temperature (1202-1543 K) measurements of k1a to be determined. Variable reaction coordinate-transition state theory was used to predict the high pressure limits for channel (1a) and other bond fission reactions in C{sub 3}H{sub 8}. Conventional transition state theory calculations were also used to estimate rate constants for other tight transition state processes. These calculations predict a negligible contribution (<1%) from all other bond fission and tight transition state processes, indicating that the bond fission channel (1a) and the roaming channel (1b) are indeed the only active channels at the temperature and pressure ranges of the present experiments. The predicted reaction exo- and endothermicities are in excellent agreement with the current version of the Active Thermochemical Tables. Master equation calculations incorporating these transition state theory results yield predictions for the temperature and pressure dependence of the dissociation rate constants for channel 1a. The final theoretical results reliably reproduce the measured dissociation rate constants that are reported here and in the literature. The experimental data are well reproduced over the 500-2500 K and 1 x 10{sup -4} to 100 bar range (errors of {approx}15% or less) by the following Troe parameters for Ar as the bath gas: k{sub {infinity}} = 1.55 x 10{sup 24}T{sup -2.034} exp(-45490/T) s{sup -1}, k{sub 0} = 7.92 x 10{sup 53}T{sup -16.67} exp(-50380/T) cm{sup 3} s{sup -1}, and F{sub c} = 0.190 exp(-T/3091) + 0.810 exp(-T/128) + exp(-8829/T).

  6. Method for removing acid gases from a gaseous stream

    DOE Patents [OSTI]

    Gorin, Everett (San Rafael, CA); Zielke, Clyde W. (McMurray, PA)

    1981-01-01T23:59:59.000Z

    In a process for hydrocracking a heavy aromatic polynuclear carbonaceous feedstock containing reactive alkaline constituents to produce liquid hydrocarbon fuels boiling below about 475.degree. C. at atmospheric pressure by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, thereafter separating a gaseous stream containing hydrogen, at least a portion of the hydrocarbon fuels and acid gases from the molten metal halide and regenerating the molten metal halide, thereby producing a purified molten metal halide stream for recycle to the hydrocracking zone, an improvement comprising; contacting the gaseous acid gas, hydrogen and hydrocarbon fuels-containing stream with the feedstock containing reactive alkaline constituents to remove acid gases from the acid gas containing stream. Optionally at least a portion of the hydrocarbon fuels are separated from gaseous stream containing hydrogen, hydrocarbon fuels and acid gases prior to contacting the gaseous stream with the feedstock.

  7. Separating hydrogen from coal gasification gases with alumina membranes

    SciTech Connect (OSTI)

    Egan, B.Z. (Oak Ridge National Lab., TN (USA)); Fain, D.E.; Roettger, G.E.; White, D.E. (Oak Ridge K-25 Site, TN (USA))

    1991-01-01T23:59:59.000Z

    Synthesis gas produced in coal gasification processes contains hydrogen, along with carbon monoxide, carbon dioxide, hydrogen sulfide, water, nitrogen, and other gases, depending on the particular gasification process. Development of membrane technology to separate the hydrogen from the raw gas at the high operating temperatures and pressures near exit gas conditions would improve the efficiency of the process. Tubular porous alumina membranes with mean pore radii ranging from about 9 to 22 {Angstrom} have been fabricated and characterized. Based on hydrostatic tests, the burst strength of the membranes ranged from 800 to 1600 psig, with a mean value of about 1300 psig. These membranes were evaluated for separating hydrogen and other gases. Tests of membrane permeabilities were made with helium, nitrogen, and carbon dioxide. Measurements were made at room temperature in the pressure range of 15 to 589 psi. Selected membranes were tested further with mixed gases simulating a coal gasification product gas. 5 refs., 7 figs.

  8. Emissions of greenhouse gases in the United States 1997

    SciTech Connect (OSTI)

    NONE

    1998-10-01T23:59:59.000Z

    This is the sixth annual report on aggregate US national emissions of greenhouse gases. It covers emissions over the period 1990--1996, with preliminary estimates of emissions for 1997. Chapter one summarizes some background information about global climate change and the greenhouse effect. Important recent developments in global climate change activities are discussed, especially the third Conference of the Parties to the Framework Convention on Climate Change, which was held in December of 1997 in Kyoto, Japan. Chapters two through five cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons and related gases, respectively. Chapter six describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Six appendices are included in the report. 96 refs., 38 tabs.

  9. “Hard probes” of strongly-interacting atomic gases

    SciTech Connect (OSTI)

    Nishida, Yusuke [Los Alamos National Laboratory

    2012-06-18T23:59:59.000Z

    We investigate properties of an energetic atom propagating through strongly interacting atomic gases. The operator product expansion is used to systematically compute a quasiparticle energy and its scattering rate both in a spin-1/2 Fermi gas and in a spinless Bose gas. Reasonable agreement with recent quantum Monte Carlo simulations even at a relatively small momentum k/kF > 1.5 indicates that our large-momentum expansions are valid in a wide range of momentum. We also study a differential scattering rate when a probe atom is shot into atomic gases. Because the number density and current density of the target atomic gas contribute to the forward scattering only, its contact density (measure of short-range pair correlation) gives the leading contribution to the backward scattering. Therefore, such an experiment can be used to measure the contact density and thus provides a new local probe of strongly interacting atomic gases.

  10. Removal of sulfur and nitrogen containing pollutants from discharge gases

    DOE Patents [OSTI]

    Joubert, James I. (Pittsburgh, PA)

    1986-01-01T23:59:59.000Z

    Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

  11. Methods, systems, and devices for deep desulfurization of fuel gases

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA); Liu, Jun (Richland, WA); Huo, Qisheng (Richland, WA)

    2012-04-17T23:59:59.000Z

    A highly effective and regenerable method, system and device that enables the desulfurization of warm fuel gases by passing these warm gasses over metal-based sorbents arranged in a mesoporous substrate. This technology will protect Fischer-Tropsch synthesis catalysts and other sulfur sensitive catalysts, without drastic cooling of the fuel gases. This invention can be utilized in a process either alone or alongside other separation processes, and allows the total sulfur in such a gas to be reduced to less than 500 ppb and in some instances as low as 50 ppb.

  12. Welcome to Greenhouse Gases: Science and Technology: Editorial

    SciTech Connect (OSTI)

    Oldenburg, C.M.; Maroto-Valer, M.M.

    2011-02-01T23:59:59.000Z

    This editorial introduces readers and contributors to a new online journal. Through the publication of articles ranging from peer-reviewed research papers and short communications, to editorials and interviews on greenhouse gas emissions science and technology, this journal will disseminate research results and information that address the global crisis of anthropogenic climate change. The scope of the journal includes the full spectrum of research areas from capture and separation of greenhouse gases from flue gases and ambient air, to beneficial utilization, and to sequestration in deep geologic formations and terrestrial (plant and soil) systems, as well as policy and technoeconomic analyses of these approaches.

  13. A practical grinding-assisted dry synthesis of nanocrystalline NiMoO{sub 4} polymorphs for oxidative dehydrogenation of propane

    SciTech Connect (OSTI)

    Chen Miao, E-mail: chenmiao@sinochem.com [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); Wu Jialing; Liu Yongmei [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Cao Yong, E-mail: yongcao@fudan.edu.cn [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China); Guo Li [Zhejiang Chemical Industry Research Institute, Hangzhou 310023 (China); He Heyong; Fan Kangnian [Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai 200433 (China)

    2011-12-15T23:59:59.000Z

    A practical two-stage reactive grinding-assisted pathway waste-free and cost-effective for the synthesis of NiMoO{sub 4} has been successfully developed. It was demonstrated that proper design in synthetic strategy for grinding plays a crucial role in determining the ultimate polymorph of NiMoO{sub 4}. Specifically, direct grinding (DG) of MoO{sub 3} and NiO rendered {alpha}-NiMoO{sub 4} after annealing, whereas sequential grinding (SG) of the two independently pre-ground oxides followed by annealing generated {beta}-NiMoO{sub 4} solid solution. Characterizations in terms of Raman and X-ray diffraction suggest the creation of {beta}-NiMoO{sub 4} precursor in the latter alternative is the key aspect for the formation of {beta}-NiMoO{sub 4}. The DG-derived {alpha}-NiMoO{sub 4} tested by oxidative dehydrogenation of propane exhibited superior activity in contrast to its analog synthesized via conventional coprecipitation. It is suggested that the favorable chemical composition facilely obtained via grinding in contrast to that by coprecipitation was essential for achieving a more selective production of propylene. - Graphical Abstract: Grinding-assisted synthesis of NiMoO{sub 4} offers higher and more reproducible activities in contrast to coprecipitation for oxidative dehydrogenation of propane, and both {alpha}- and {beta}-NiMoO{sub 4} can be synthesized. Highlights: Black-Right-Pointing-Pointer NiMoO{sub 4} was prepared through grinding-assisted pathway. Black-Right-Pointing-Pointer Direct/sequential grinding rendered {alpha}-, {beta}-NiMoO{sub 4}, respectively. Black-Right-Pointing-Pointer Grinding-derived {alpha}-NiMoO{sub 4} showed high and reproducible activity for oxidative dehydrogenation of propane.

  14. AER1301: KINETIC THEORY OF GASES Assignment #1

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    AER1301: KINETIC THEORY OF GASES Assignment #1 1. A hypersonic wind tunnel is contructed so such that the mean free path, , is given by the expression = 16µ 5 1 2RT , where R is the ideal gas constant and p space and the length of each side of the cube is 4v. (a) Obtain an expression for the normalized

  15. AER1301: KINETIC THEORY OF GASES Assignment #1

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    AER1301: KINETIC THEORY OF GASES Assignment #1 1. A hypersonic wind tunnel is contructed so spheres during collisions such that the mean free path, #21;, is given by the expression #21; = 16#22; 5 of the cube is 4v Æ . (a) Obtain an expression for the normalized velocity distribution function, f(v). (b

  16. AER1301: KINETIC THEORY OF GASES Assignment #4

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    - equilibrium cases, up to second order. (b) Derive an expression for the non-conservative form of the kineticAER1301: KINETIC THEORY OF GASES Assignment #4 1. Consider a monatomic gas with one translational by the relaxation time approx- imation. Neglecting external forces, the conserved form of the kinetic equation

  17. AER1301: KINETIC THEORY OF GASES Assignment #4

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    AER1301: KINETIC THEORY OF GASES Assignment #4 1. Consider a monatomic gas with one translational by the relaxation time approx- imation. Neglecting external forces, the conserved form of the kinetic equation function, in both the equilibrium and non- equilibrium cases, up to second order. (b) Derive an expression

  18. Ozone-depleting substances and the greenhouse gases HFCs, PFCs

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 19 3.1 IMPORTS AND EXPORTS 19 3.1.1 CFCs 19 3.1.2 Tetrachloromethane 19 3

  19. Nature of superfluidity in ultracold Fermi gases near Feshbach resonances

    SciTech Connect (OSTI)

    Stajic, Jelena; Levin, K. [James Franck Institute and Department of Physics, University of Chicago, Chicago, Illinois 60637 (United States); Milstein, J.N.; Holland, M.J. [JILA, University of Colorado and National Institute of Standards and Technology, Boulder, Colorado 80309 (United States); Chen Qijin [Department of Physics and Astronomy, Johns Hopkins University, Baltimore, Maryland 21218 (United States); Chiofalo, M.L. [Classe di Scienze and INFM, Scuola Normale Superiore, Piazza dei Cavelieri 7, I-56126 Pisa (Italy)

    2004-06-01T23:59:59.000Z

    We study the superfluid state of atomic Fermi gases using a BCS-Bose-Einstein-condensation crossover theory. Our approach emphasizes noncondensed fermion pairs which strongly hybridize with their (Feshbach-induced) molecular boson counterparts. These pairs lead to pseudogap effects above T{sub c} and non-BCS characteristics below. We discuss how these effects influence the experimental signatures of superfluidity.

  20. INTRODUCTION Insects exchange respiratory gases through a complex network of

    E-Print Network [OSTI]

    Socha, Jake

    3409 INTRODUCTION Insects exchange respiratory gases through a complex network of tracheal tubes through the tracheal system using diffusion alone (Krogh, 1920a; Weis-Fogh, 1964), many species are known to augment gas exchange using convection (Buck, 1962; Miller, 1966a). Two general mechanisms are recognized

  1. Higher Dimensional Coulomb Gases and Renormalized Energy Functionals

    E-Print Network [OSTI]

    -Louis Lions, Paris, F-75005 France & Courant Institute, New York University, 251 Mercer st, NY NY 10012, USAHigher Dimensional Coulomb Gases and Renormalized Energy Functionals N. Rougerie and S. Serfaty extract the next to leading order term in the ground state energy, beyond the mean-field limit. We show

  2. Use of low temperature blowers for recirculation of hot gases

    DOE Patents [OSTI]

    Maru, H.C.; Forooque, M.

    1982-08-19T23:59:59.000Z

    An apparatus is described for maintaining motors at low operating temperatures during recirculation of hot gases in fuel cell operations and chemical processes such as fluidized bed coal gasification. The apparatus includes a means for separating the hot process gas from the motor using a secondary lower temperature gas, thereby minimizing the temperature increase of the motor and associated accessories.

  3. Noble gases and radiocarbon in natural gas hydrates Gisela Winckler

    E-Print Network [OSTI]

    Aeschbach-Hertig, Werner

    Noble gases and radiocarbon in natural gas hydrates Gisela Winckler Lamont-Doherty Earth 2001; published 24 May 2002. [1] In samples of pure natural gas hydrates from Hydrate Ridge, Cascadia ones preferentially incorporated into the gas hydrate structure. The hydrate methane is devoid of 14 C

  4. SaltRx HT -Scoring Sheet A1. 0.1 M Bis-Tris Propane pH 7.0, 1.8 M Sodium Acetate pH 7.0

    E-Print Network [OSTI]

    Hill, Chris

    SaltRx HT - Scoring Sheet A1. 0.1 M Bis-Tris Propane pH 7.0, 1.8 M Sodium Acetate pH 7.0 A2. 0.1 M Bis-Tris Propane pH 7.0, 2.8 M Sodium Acetate pH 7.0 A3. 0.1 M Sodium Acetate pH 4.6, 1.5 M Ammonium Chloride A4. 0.1 M Bis-Tris Propane pH 7.0, 1.5 M Ammonium Chloride A5. 0.1 M Tris pH 8.5, 1.5 M Ammonium

  5. Acoustic method for measuring the sound speed of gases over small path lengths

    E-Print Network [OSTI]

    and the quality of gaseous fuels for alternative fueled vehicles such as hydrogen, natural gas, and propane hydrogen in air with a response time on the order of 1­2 s. An acoustic phase shift method is a very, to accurately measure the composition of binary gas mixtures. More recently, Huang et al.11 used this method

  6. Strongly interacting Fermi gases : non-equilibrium dynamics and dimensional crossover

    E-Print Network [OSTI]

    Sommer, Ariel T. (Ariel Tjodolv)

    2013-01-01T23:59:59.000Z

    Experiments using ultracold atomic gases address fundamental problems in many-body physics. This thesis describes experiments on strongly-interacting gases of fermionic atoms, with a focus on non-equilibrium physics and ...

  7. Steam Production from Waste Stack Gases in a Carbon Black Plant

    E-Print Network [OSTI]

    Istre, R. I.

    1981-01-01T23:59:59.000Z

    gases to produce steam has two very important rewards - energy conservation and pollution abatement. Energy conservation is achieved by using waste gases in place of fuel oil to produce the steam required by the various plants. Pollution abatement is due...

  8. Structures, Mechanisms, and Kinetics of Ammoxidation and Selective Oxidation of Propane Over the M2 Phase of MoVNbTeO Catalysts

    SciTech Connect (OSTI)

    Goddard, William A. [California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center; Liu, Lianchi [California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center; Mueller, Jonathan E. [California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center; Pudar, Sanja [California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center; Nielsen, Robert J. [California Inst. of Technology (CalTech), Pasadena, CA (United States). Materials and Process Simulation Center

    2011-07-01T23:59:59.000Z

    We report here first-principles-based predictions of the structures, mechanisms, and activation barriers for propane activation by the M2 phase of the MoVNbTeO multi-metal oxide catalysts capable of the direct conversion of propane to acrylonitrile. Our approach is to combine extensive quantum mechanical (QM) calculations to establish the mechanisms for idealized representations of the surfaces for these catalytic systems and then to modify the parameters in the ReaxFF reactive force field for molecular dynamics (MD) calculations to describe accurately the activation barriers and reaction mechanisms of the chemical reactions over complex mixed metal oxides. The parameters for ReaxFF are derived entirely from QM without the use of empirical data so that it can be applied to novel systems on which there is little or no data. To understand the catalysis in these systems it is essential to determine the surface structures that control the surface chemistry. High quality three-dimensional (3D) Rietveld structures are now available for the M1 and M2 phases of the MoVNbTeO catalysts.

  9. Dynamics of Propane in Silica Mesopores Formed upon PropyleneHydrogenation over Pt Nanoparticles by Time-Resolved FT-IRSpectroscopy

    SciTech Connect (OSTI)

    Waslylenko, Walter; Frei, Heinz

    2007-01-31T23:59:59.000Z

    Propylene hydrogenation over Pt nanoparticles supported onmesoporous silica type SBA-15 was monitored by time-resolved FT-IRspectroscopy at 23 ms resolution using short propylene gas pulses thatjoined a continuous flow of hydrogen in N2 (1 atm total pressure).Experiments were conducted in the temperature range 323-413 K. Propanewas formed within 100 milliseconds or faster. The CH stretching regionrevealed distinct bands for propane molecules emerging inside thenanoscale channels of the silica support. Spectral analysis gave thedistribution of the propane product between support and surrounding gasphase as function of time. Kinetic analysis showed that the escape ofpropane molecules from the channels occurred within hundreds ofmilliseconds (3.1 + 0.4 s-1 at 383 K). A steady state distribution ofpropane between gas phase and mesoporous support is established as theproduct is swept from the catalyst zone by the continuous flow ofhydrogen co-reactant. This is the first direct spectroscopic observationof emerging products of heterogeneous catalysis on nanoporous supportsunder reaction conditions.

  10. System for trapping and storing gases for subsequent chemical reduction to solids

    DOE Patents [OSTI]

    Vogel, John S. (San Jose, CA); Ognibene, Ted J. (Oakland, CA); Bench, Graham S. (Livermore, CA); Peaslee, Graham F. (Holland, MI)

    2009-11-03T23:59:59.000Z

    A system for quantitatively reducing oxide gases. A pre-selected amount of zinc is provided in a vial. A tube is provided in the vial. The zinc and the tube are separated. A pre-selected amount of a catalyst is provided in the tube. Oxide gases are injected into the vial. The vial, tube, zinc, catalyst, and the oxide gases are cryogenically cooled. At least a portion of the vial, tube, zinc, catalyst, and oxide gases are heated.

  11. Title of Document: INTERACTION OF INTENSE SHORT LASER PULSES WITH GASES OF NANOSCALE

    E-Print Network [OSTI]

    Anlage, Steven

    ABSTRACT Title of Document: INTERACTION OF INTENSE SHORT LASER PULSES WITH GASES OF NANOSCALE-cluster interaction. #12;INTERACTION OF INTENSE SHORT LASER PULSES WITH GASES OF NANOSCALE ATOMIC AND MOLECULAR., Department of Electrical and Computer Engineering We study the interaction of intense laser pulses with gases

  12. Process for separation of CO/sub 2/ from CO/sub 2/-containing gases

    SciTech Connect (OSTI)

    Linde, G.

    1985-07-09T23:59:59.000Z

    For separating CO/sub 2/ from CO/sub 2/-containing gases, especially stack gases and/or blast furnace gases, dimethylformamide is employed as a physical scrubbing medium to ensure high CO/sub 2/ purity. After absorption of CO/sub 2/, the DMF is regenerated and returned into the scrubbing stage. Dimethylformamide is utilized as the scrubbing medium.

  13. Propane/Propylene Exports

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade1 Source:Additions to Capacity onThousand(Dollars2009 2010698 1.87324

  14. Residential propane price

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil price decreasesheatingheating oil

  15. Residential propane price

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil price decreasesheatingheating oilpropane

  16. Residential propane price

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil price decreasesheatingheating

  17. Residential propane price

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil price decreasesheatingheatingpropane price

  18. Residential propane price

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil price decreasesheatingheatingpropane

  19. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil price

  20. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price decreases The average

  1. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price decreases The

  2. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price decreases Thepropane

  3. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price decreases

  4. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price decreasespropane price

  5. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price decreasespropane

  6. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price decreasespropanepropane

  7. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price

  8. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05, 2014 Residential

  9. Residential propane price decreases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05, 2014

  10. Residential propane price increases

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05, 2014propanepropane

  11. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05,propanepropane prices

  12. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05,propanepropane

  13. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane price05,propanepropanepropane

  14. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropane

  15. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropanepropane prices increase The

  16. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropanepropane prices increase

  17. Residential propane prices increase

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropanepropane prices increasepropane

  18. Residential propane prices stable

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropanepropane prices

  19. Residential propane prices stable

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropanepropane pricespropane price

  20. Residential propane prices surges

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropanepropane pricespropane

  1. Residential propane prices surges

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropanepropane pricespropane5, 2014

  2. Residential propane prices surges

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropanepropane pricespropane5, 20142,

  3. Residential propane prices surges

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropanepropane pricespropane5,

  4. Residential propane prices surges

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade Year-0E (2001) -heating oil pricepropanepropane pricespropane5,Midwest

  5. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    CO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITYCO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITY

  6. Clostridium stain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, James L. (2207 Tall Oaks Dr., Fayetteville, AR 72703)

    1997-01-01T23:59:59.000Z

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

  7. The extreme nonlinear optics of gases and femtosecond optical filamentation

    SciTech Connect (OSTI)

    Milchberg, H. M.; Chen, Y.-H.; Cheng, Y.-H.; Jhajj, N.; Palastro, J. P.; Rosenthal, E. W.; Varma, S.; Wahlstrand, J. K.; Zahedpour, S. [Institute for Research in Electronics and Applied Physics, University of Maryland, College Park, Maryland 20742 (United States)

    2014-10-15T23:59:59.000Z

    Under certain conditions, powerful ultrashort laser pulses can form greatly extended, propagating filaments of concentrated high intensity in gases, leaving behind a very long trail of plasma. Such filaments can be much longer than the longitudinal scale over which a laser beam typically diverges by diffraction, with possible applications ranging from laser-guided electrical discharges to high power laser propagation in the atmosphere. Understanding in detail the microscopic processes leading to filamentation requires ultrafast measurements of the strong field nonlinear response of gas phase atoms and molecules, including absolute measurements of nonlinear laser-induced polarization and high field ionization. Such measurements enable the assessment of filamentation models and make possible the design of experiments pursuing applications. In this paper, we review filamentation in gases and some applications, and discuss results from diagnostics developed at Maryland for ultrafast measurements of laser-gas interactions.

  8. Apparatus for the plasma destruction of hazardous gases

    DOE Patents [OSTI]

    Kang, Michael (Los Alamos, NM)

    1995-01-01T23:59:59.000Z

    A plasma cell for destroying hazardous gases. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required.

  9. Apparatus for the plasma destruction of hazardous gases

    DOE Patents [OSTI]

    Kang, M.

    1995-02-07T23:59:59.000Z

    A plasma cell for destroying hazardous gases is described. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required. 4 figs.

  10. Clostridium strain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, J.L.

    1997-01-14T23:59:59.000Z

    A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 4 figs.

  11. Decontamination of combustion gases in fluidized bed incinerators

    DOE Patents [OSTI]

    Leon, Albert M. (Mamaroneck, NY)

    1982-01-01T23:59:59.000Z

    Sulfur-containing atmospheric pollutants are effectively removed from exit gas streams produced in a fluidized bed combustion system by providing a fluidized bed of particulate material, i.e. limestone and/or dolomite wherein a concentration gradient is maintained in the vertical direction. Countercurrent contacting between upwardly directed sulfur containing combustion gases and descending sorbent particulate material creates a concentration gradient across the vertical extent of the bed characterized in progressively decreasing concentration of sulfur, sulfur dioxide and like contaminants upwardly and decreasing concentration of e.g. calcium oxide, downwardly. In this manner, gases having progressively decreasing sulfur contents contact correspondingly atmospheres having progressively increasing concentrations of calcium oxide thus assuring optimum sulfur removal.

  12. Wave Speed in the Macroscopic Extended Model for Ultrarelativistic Gases

    E-Print Network [OSTI]

    F. Borghero; F. Demontis; S. Pennisi

    2010-12-07T23:59:59.000Z

    An exact macroscopic extended model for ultrarelativistic gases, with an arbitrary number of moments, is present in the literature. Here we exploit equations determining wave speeds for that model. We find interesting results; for example, the whole system for their determination can be divided into independent subsystems and some, but not all, wave speeds are expressed by rational numbers. Moreover, the extraordinary property that these wave speeds for the macroscopic model are the same of those in the kinetic model, is proved.

  13. Pulse Radiolysis of Gases H atom yields, OH reactions,

    E-Print Network [OSTI]

    PULSE RADIOLYSIS OP GASES H atom yields, OH reactions, and kinetics of H2S systems Ole John Nielsen, M, in the reaction OH + OH + M · H2O2 + M. 3) In the H2S systems the HS extinction coefficient determined: k(H + H2S · H2 + HS) = 4-6 x 108 M ^ s " 1 k(HS + HS · products) = (1.9 ± 0.1) x io1 0 M ^ s " 1

  14. Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases

    SciTech Connect (OSTI)

    Carlsbad Field Office

    2006-04-01T23:59:59.000Z

    The Performance Demonstration Program (PDP) for headspace gases distributes sample gases of volatile organic compounds (VOCs) for analysis. Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facility’s compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.

  15. Chemical production from industrial by-product gases: Final report

    SciTech Connect (OSTI)

    Lyke, S.E.; Moore, R.H.

    1981-04-01T23:59:59.000Z

    The potential for conservation of natural gas is studied and the technical and economic feasibility and the implementation of ventures to produce such chemicals using carbon monoxide and hydrogen from byproduct gases are determined. A survey was performed of potential chemical products and byproduct gas sources. Byproduct gases from the elemental phosphorus and the iron and steel industries were selected for detailed study. Gas sampling, preliminary design, market surveys, and economic analyses were performed for specific sources in the selected industries. The study showed that production of methanol or ammonia from byproduct gas at the sites studied in the elemental phosphorus and the iron and steel industries is technically feasible but not economically viable under current conditions. Several other applications are identified as having the potential for better economics. The survey performed identified a need for an improved method of recovering carbon monoxide from dilute gases. A modest experimental program was directed toward the development of a permselective membrane to fulfill that need. A practical membrane was not developed but further investigation along the same lines is recommended. (MCW)

  16. Emissions of greenhouse gases in the United States 1996

    SciTech Connect (OSTI)

    NONE

    1997-10-01T23:59:59.000Z

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1990, with annual updates thereafter. This report is the fifth annual update, covering national emissions over the period 1989--1995, with preliminary estimates of emissions for 1996. The estimates contained in this report have been revised from those in last year`s report. Emissions estimates for carbon dioxide are reported in metric tons of carbon; estimates for other gases are reported in metric tons of gas. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapter 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Five appendixes are included with this report. 216 refs., 11 figs., 38 tabs.

  17. Thermodynamics of sustaining gases in the roughness of submerged superhydrophobic surfaces

    E-Print Network [OSTI]

    Neelesh A. Patankar

    2015-05-22T23:59:59.000Z

    Rough surfaces submerged in a liquid can remain almost dry if the liquid does not fully wet the roughness and gases are sustained in roughness grooves. Such partially dry surfaces can help reduce drag or enhance boiling. Gases sustained in roughness grooves would be composed of air and the vapor phase of the liquid itself. The thermodynamics of sustaining vapor was considered in a prior work [Patankar, Soft Matter, 2010, 6:1613]. Here, the thermodynamics of sustaining gases (e.g. air) is considered. Governing equations are presented along with a solution methodology to determine a critical condition to sustain gases. The critical roughness scale to sustain gases is estimated for different degrees of saturation of gases dissolved in the liquid. It is shown that roughness spacings of less than a micron are essential to sustain gases on surfaces submerged in water at atmospheric pressure. This is consistent with prior empirical data.

  18. All-optical remote monitoring of propane gas using a 5-km-long, low-loss optical fiber link and an InGaP light-emitting diode in the 1. 68-. mu. m region

    SciTech Connect (OSTI)

    Chan, K.; Ito, H.; Inaba, H.

    1984-08-01T23:59:59.000Z

    We report the fully optical remote detection of low-level propane (C/sub 3/H/sub 8/) gas realized by the scheme based on a long distance, very low-loss silica optical fiber link connected to a compact absorption cell in conjunction with a high radiant InGaP light-emitting diode at 1.68 ..mu..m. For this application, the near-infrared absorption spectrum of propane was measured and studied to find very complicated bands around 1.69, 1.53, and 1.38 ..mu..m. This simple system, employing a 5-km-long silica optical fiber link, was demonstrated to be capable of achieving reproducibly the detection sensitivity less than 2.4 Torr for propane gas in air, i.e., about 14% of the lower explosion limit of propane density. This result verifies a large capability for major applications to various strategic points within the environment, such as industrial complexes as well as urban and residential areas, with considerably increased reliability and safety over the existing techniques.

  19. Exotic narrow resonance searches in the system Lambda K0s in p+propane collisions at 10 GeV/c

    E-Print Network [OSTI]

    P. Zh. Aslanyan; V. N. Emelyanenko; G. G. Rikhkvitzkaya

    2005-04-15T23:59:59.000Z

    Experimental data from the 2m propane bubble chamber have been analyzed to search for an exotic baryon states, in the $\\Lambda K^0_s$ decay mode for the reaction p+$C_3H_8$ at 10 GeV/c. The invariant mass spectrum $\\Lambda K^0_s$ observe a narrow peaks at 1750$\\pm$18, 1795$\\pm$18,1850$\\pm19$ MeV/$c^2$ and full widths of $\\Gamma_{exp.}$= 32$\\pm$6, 44$\\pm$15, 29.0$\\pm$8 MeV/$c^2$. The statistical significance of these peaks has been estimated as 5.6, 3.3 and 3.0 S.D., respectively. There are the small enhancements in mass regions of (1650-1675) and (1925-1950) ???/?$^2$. These would be candidates for the $N^0$ or the $\\Xi^0$ pentaquark states. The investigation has been performed at the Veksler and Baldin Laboratory of High Energies, JINR.

  20. The preliminary result from spectra of $K^0_s \\pi^-$ in reaction p+propane at 10 GeV/c

    E-Print Network [OSTI]

    Aslanyan, P Z

    2006-01-01T23:59:59.000Z

    The experimental data from 2m propane bubble chamber have been analyzed to search for scalar meson $\\kappa(800)$ in a $K^0_s\\pi$ decay mode for the reaction p+$C_3H_8$ at 10 GeV/c. The $K^0_s\\pi^-$ invariant mass spectrum has shown resonant structures with $M_{K^0_s\\pi^-}$=730, 900 and $\\Gamma$=143, 48 MeV/$c^2$, respectively. The statistical significance are estimated to be of 14.2$\\sigma$ and 4.2$\\sigma$, respectively. The peak in M(900) is identified as reflection from the well known resonance with mass of 892 MeV/c$^2$.

  1. Exotic narrow resonance searches in the system Lambda K0s in p+propane collisions at 10 GeV/c

    E-Print Network [OSTI]

    Aslanyan, P Z; Rikhkvitzkaya, G G

    2005-01-01T23:59:59.000Z

    Experimental data from the 2m propane bubble chamber have been analyzed to search for an exotic baryon states, in the $\\Lambda K^0_s$ decay mode for the reaction p+$C_3H_8$ at 10 GeV/c. The invariant mass spectrum $\\Lambda K^0_s$ observe a narrow peaks at 1750$\\pm$18, 1795$\\pm$18,1850$\\pm19$ MeV/$c^2$ and full widths of $\\Gamma_{exp.}$= 32$\\pm$6, 44$\\pm$15, 29.0$\\pm$8 MeV/$c^2$. The statistical significance of these peaks has been estimated as 5.6, 3.3 and 3.0 S.D., respectively. There are the small enhancements in mass regions of (1650-1675) and (1925-1950) ???/?$^2$. These would be candidates for the $N^0$ or the $\\Xi^0$ pentaquark states. The investigation has been performed at the Veksler and Baldin Laboratory of High Energies, JINR.

  2. STEM HAADF Image Simulation of the Orthorhombic M1 Phase in the Mo-V-Nb-Te-O Propane Oxidation Catalyst

    SciTech Connect (OSTI)

    D Blom; X Li; S Mitra; T Vogt; D Buttrey

    2011-12-31T23:59:59.000Z

    A full frozen phonon multislice simulation of high angle annular dark field scanning transmission electron microscopy (HAADF STEM) images from the M1 phase of the Mo-V-Nb-Te-O propane oxidation catalyst has been performed by using the latest structural model obtained using the Rietveld method. Simulated contrast results are compared with experimental HAADF images. Good agreement is observed at ring sites, however significant thickness dependence is noticed at the linking sites. The remaining discrepancies between the model based on Rietveld refinement and image simulations indicate that the sampling of a small volume element in HAADF STEM and averaging elemental contributions of a disordered site in a crystal slab by using the virtual crystal approximation might be problematic, especially if there is preferential Mo/V ordering near the (001) surface.

  3. Direct observation of surface ethyl to ethane interconversion uponC2H4 hydrogenation over Pt/Al2O3 catalyst by time-resolved FT-IRspectroscopy

    SciTech Connect (OSTI)

    Wasylenko, Walter; Frei, Heinz

    2004-12-10T23:59:59.000Z

    Time-resolved FT-IR spectra of ethylene hydrogenation over alumina-supported Pt catalyst were recorded at 25 ms resolution in the temperature range 323 to 473 K using various H2 flow rates (1 atm total gas pressure). Surface ethyl species (2870 and 1200 cm-1) were detected at all temperatures along with the gas phase ethane product (2954 and 2893 cm-1). The CH3CH2Pt growth was instantaneous on the time scale of 25ms under all experimental conditions. At 323 K, the decay time of surface ethyl (122 + 10 ms) coincides with the rise time of C2H6 (144 + 14 ms).This establishes direct kinetic evidence for surface ethyl as the kinetically relevant intermediate. Such a direct link between the temporal behavior of an observed intermediate and the final product growth in a heterogeneous catalytic system has not been demonstrated before to our knowledge. A fraction (10 percent) of the asymptotic ethane growth at 323 K is prompt, indicating that there are surface ethyl species that react much faster than the majority of the CH3CH2Pt intermediates. The dispersive kinetics is attributed to the varying strength of interaction of the ethyl species with the Pt surface caused by heterogeneity of the surface environment. At 473 K, the majority of ethyl intermediates are hydrogenated prior to the recording of the first time slice (24 ms), and a correspondingly large prompt growth of ethane is observed. The yield and kinetics of the surface ethylidyne are in agreement with the known spectator nature of this species.

  4. Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases

    SciTech Connect (OSTI)

    Carlsbad Field Office

    2007-11-13T23:59:59.000Z

    The Performance Demonstration Program (PDP) for headspace gases distributes blind audit samples in a gas matrix for analysis of volatile organic compounds (VOCs). Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facility’s compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.

  5. Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases

    SciTech Connect (OSTI)

    Carlsbad Field Office

    2007-11-19T23:59:59.000Z

    The Performance Demonstration Program (PDP) for headspace gases distributes blind audit samples in a gas matrix for analysis of volatile organic compounds (VOCs). Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facility’s compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.

  6. Direct conversion of light hydrocarbon gases to liquid fuel

    SciTech Connect (OSTI)

    Kaplan, R.D.; Foral, M.J.

    1992-05-16T23:59:59.000Z

    Amoco oil Company, has investigated the direct, non-catalytic conversion of light hydrocarbon gases to liquid fuels (particularly methanol) via partial oxidation. The primary hydrocarbon feed used in these studies was natural gas. This report describes work completed in the course of our two-year project. In general we determined that the methanol yields delivered by this system were not high enough to make it economically attractive. Process variables studied included hydrocarbon feed composition, oxygen concentration, temperature and pressure effects, residence time, reactor design, and reactor recycle.

  7. Prospecting by sampling and analysis of airborne particulates and gases

    DOE Patents [OSTI]

    Sehmel, G.A.

    1984-05-01T23:59:59.000Z

    A method is claimed for prospecting by sampling airborne particulates or gases at a ground position and recording wind direction values at the time of sampling. The samples are subsequently analyzed to determine the concentrations of a desired material or the ratios of the desired material to other identifiable materials in the collected samples. By comparing the measured concentrations or ratios to expected background data in the vicinity sampled, one can select recorded wind directions indicative of the upwind position of the land-based source of the desired material.

  8. Two-phase compressibility factors for retrograde gases 

    E-Print Network [OSTI]

    Rayes, Daniel George

    1989-01-01T23:59:59.000Z

    . K. , M Cain, W. D. , Jr. and Jennings, J. W. : "An Improved Method for the Determination of the Reservoir Specific Gravity for Retrograde Gases, " JPT (July 1989) 747-752. 7. Craft, B. C. and Hawkins, M. F. : A li P 1 m R rv ir En ine rin...). Variable Mean Standard Deviation Minimum Maximum H2S CO2 N2 CI C2 C3 IC4 NC4 IC5 NC5 C6 C7+ M. W. C7+ S. G. C7+ 1, 01840 0. 00997 0. 02545 0. 01840 0. 73233 0. 07584 0. 03948 0. 00859 0. 01482 0. 00611 0. 00637 0. 00857 0. 05404...

  9. Separation of gases through gas enrichment membrane composites

    DOE Patents [OSTI]

    Swedo, R.J.; Kurek, P.R.

    1988-07-19T23:59:59.000Z

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  10. Separation of gases through gas enrichment membrane composites

    DOE Patents [OSTI]

    Swedo, Raymond J. (Mt. Prospect, IL); Kurek, Paul R. (Schaumburg, IL)

    1988-01-01T23:59:59.000Z

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  11. EIA-Voluntary Reporting of Greenhouse Gases Program

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells, Wisconsin:DeploymentSite Name: Email: Terminal2,7,7,of Greenhouse Gases

  12. Instantaneous and efficient surface wave excitation of a low pressure gas or gases

    DOE Patents [OSTI]

    Levy, Donald J. (Berkeley, CA); Berman, Samuel M. (San Francisco, CA)

    1988-01-01T23:59:59.000Z

    A system for instantaneously ionizing and continuously delivering energy in the form of surface waves to a low pressure gas or mixture of low pressure gases, comprising a source of rf energy, a discharge container, (such as a fluorescent lamp discharge tube), an rf shield, and a coupling device responsive to rf energy from the source to couple rf energy directly and efficiently to the gas or mixture of gases to ionize at least a portion of the gas or gases and to provide energy to the gas or gases in the form of surface waves. The majority of the rf power is transferred to the gas or gases near the inner surface of the discharge container to efficiently transfer rf energy as excitation energy for at least one of the gases. The most important use of the invention is to provide more efficient fluorescent and/or ultraviolet lamps.

  13. Process for recovery of sulfur from acid gases

    DOE Patents [OSTI]

    Towler, Gavin P. (Kirkbymoorside, GB2); Lynn, Scott (Pleasant Hill, CA)

    1995-01-01T23:59:59.000Z

    Elemental sulfur is recovered from the H.sub.2 S present in gases derived from fossil fuels by heating the H.sub.2 S with CO.sub.2 in a high-temperature reactor in the presence of a catalyst selected as one which enhances the thermal dissociation of H.sub.2 S to H.sub.2 and S.sub.2. The equilibrium of the thermal decomposition of H.sub.2 S is shifted by the equilibration of the water-gas-shift reaction so as to favor elemental sulfur formation. The primary products of the overall reaction are S.sub.2, CO, H.sub.2 and H.sub.2 O. Small amounts of COS, SO.sub.2 and CS.sub.2 may also form. Rapid quenching of the reaction mixture results in a substantial increase in the efficiency of the conversion of H.sub.2 S to elemental sulfur. Plant economy is further advanced by treating the product gases to remove byproduct carbonyl sulfide by hydrolysis, which converts the COS back to CO.sub.2 and H.sub.2 S. Unreacted CO.sub.2 and H.sub.2 S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H.sub.2 and CO, which has value either as a fuel or as a chemical feedstock and recovers the hydrogen value from the H.sub.2 S.

  14. Self-pulsing of hollow cathode discharge in various gases

    SciTech Connect (OSTI)

    Qin, Y.; He, F., E-mail: hefeng@bit.edu.cn; Jiang, X. X.; Ouyang, J. T., E-mail: jtouyang@bit.edu.cn [School of Physics, Beijing Institute of Technology, Beijing 100081 (China); Xie, K. [School of Aerospace Engineering, Beijing Institute of Technology, Beijing 100081 (China)

    2014-07-15T23:59:59.000Z

    In this paper, we investigate the self-pulsing phenomenon of cavity discharge in a cylindrical hollow cathode in various gases including argon, helium, nitrogen, oxygen, and air. The current-voltage characteristics of the cavity discharge, the waveforms of the self-pulsing current and voltage as well as the repetition frequency were measured. The results show that the pulsing frequency ranges from a few to tens kilohertz and depends on the averaged current and the pressure in all gases. The pulsing frequency will increase with the averaged current and decrease with the pressure. The rising time of the current pulse is nearly constant in a given gas or mixture. The self-pulsing does not depend on the external ballast but is affected significantly by the external capacitor in parallel with the discharge cell. The low-current self-pulsing in hollow cathode discharge is the mode transition between Townsend and glow discharges. It can be described by the charging-discharging process of an equivalent circuit consisting of capacitors and resistors.

  15. Dark resonances for ground state transfer of molecular quantum gases

    E-Print Network [OSTI]

    Manfred J. Mark; Johann G. Danzl; Elmar Haller; Mattias Gustavsson; Nadia Bouloufa; Olivier Dulieu; Houssam Salami; Tom Bergeman; Helmut Ritsch; Russell Hart; Hanns-Christoph Nägerl

    2008-11-05T23:59:59.000Z

    One possible way to produce ultracold, high-phase-space-density quantum gases of molecules in the rovibronic ground state is given by molecule association from quantum-degenerate atomic gases on a Feshbach resonance and subsequent coherent optical multi-photon transfer into the rovibronic ground state. In ultracold samples of Cs_2 molecules, we observe two-photon dark resonances that connect the intermediate rovibrational level |v=73,J=2> with the rovibrational ground state |v=0,J=0> of the singlet $X^1\\Sigma_g^+$ ground state potential. For precise dark resonance spectroscopy we exploit the fact that it is possible to efficiently populate the level |v=73,J=2> by two-photon transfer from the dissociation threshold with the stimulated Raman adiabatic passage (STIRAP) technique. We find that at least one of the two-photon resonances is sufficiently strong to allow future implementation of coherent STIRAP transfer of a molecular quantum gas to the rovibrational ground state |v=0,J=0>.

  16. Emissions of greenhouse gases in the United States 1995

    SciTech Connect (OSTI)

    NONE

    1996-10-01T23:59:59.000Z

    This is the fourth Energy Information Administration (EIA) annual report on US emissions of greenhouse gases. This report presents estimates of US anthropogenic (human-caused) emissions of carbon dioxide, methane, nitrous oxide, and several other greenhouse gases for 1988 through 1994. Estimates of 1995 carbon dioxide, nitrous oxide, and halocarbon emissions are also provided, although complete 1995 estimates for methane are not yet available. Emissions of carbon dioxide increased by 1.9% from 1993 to 1994 and by an additional 0.8% from 1994 to 1995. Most carbon dioxide emissions are caused by the burning of fossil fuels for energy consumption, which is strongly related to economic growth, energy prices, and weather. The US economy grew rapidly in 1994 and slowed in 1995. Estimated emissions of methane increased slightly in 1994, as a result of a rise in emissions from energy and agricultural sources. Estimated nitrous oxide emissions increased by 1.8% in 1995, primarily due to increased use of nitrogen fertilizers and higher output of chemicals linked to nitrous oxide emissions. Estimated emissions of hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs), which are known to contribute to global warming, increased by nearly 11% in 1995, primarily as a result of increasing substitution for chlorofluorocarbons (CFCs). With the exception of methane, the historical emissions estimates presented in this report are only slightly revised from those in last year`s report.

  17. David Chandler ater and oil famously don't mix: the

    E-Print Network [OSTI]

    Chandler, David

    to this volume. The solvation free energies of ethane, propane and other similar molecules indi- cate,thefreeenergyofalargesolute withanextendedhydrophobicsurfaceispro- portional to the surface area of the interface between the solute and water. Here, the pro

  18. Atmos. Chem. Phys., 11, 503518, 2011 www.atmos-chem-phys.net/11/503/2011/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    southwestern Asia during the monsoon, some- times more than double their spring and fall means, pro- vides of biofuel burning to NMHC emis- sions in this region. Conversely, the ratios of ethane and propane to carbon

  19. Gas Content of Gladys McCall Reservoir Brine A Topical Report

    Office of Scientific and Technical Information (OSTI)

    gas t o brine ratio. This w i l l result i n cubic feet of methane, ethane, propane, etc. per barrel of brine, Then, the contributions from sample points are added until...

  20. This article appeared in a journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research

    E-Print Network [OSTI]

    Wooldridge, Margaret S.

    institution and sharing with colleagues. Other uses, including reproduction and distribution, or selling. Quantitative measurements of mole fraction time-histories of meth- ane, ethane, propane, ethene, propene, and 1

  1. Embedding parameters in ab initio theory to develop well-controlled approximations based on molecular similarity

    E-Print Network [OSTI]

    Yaron, David

    is explored by training such a model on data for ethane and testing the resulting model on methane, propane and butane. The electronic distribution of the molecules is varied by placing them in strong electrostatic

  2. T h e o p e n a c c e s s j o u r n a l f o r p h y s i c s New Journal of Physics

    E-Print Network [OSTI]

    Gribakin, Gleb

    methane and its fluoro-substitutes, ethane, propane, butane and benzene are presented. The annihilation -spectra characterise the momentum distribution of the electron­positron pair at the instant

  3. Reply to Saba and Orzechowski and Schon: Methane contamination of

    E-Print Network [OSTI]

    Jackson, Robert B.

    , and that the ratios of methane to ethane and propane were different [figure 4b (3)]. Furthermore, the methane present underground gas storage, leading to documented leaks into well water (5). The DEP correspondence they cite

  4. Loschmidt echo in one-dimensional interacting Bose gases

    SciTech Connect (OSTI)

    Lelas, K.; Seva, T.; Buljan, H. [Faculty of Electrical Engineering Mechanical Engineering and Naval Architecture, University of Split, Rudjera Boskovica BB, 21000 Split (Croatia); Department of Physics, University of Zagreb, Bijenicka c. 32, 10000 Zagreb (Croatia)

    2011-12-15T23:59:59.000Z

    We explore Loschmidt echo in two regimes of one-dimensional interacting Bose gases: the strongly interacting Tonks-Girardeau (TG) regime, and the weakly interacting mean-field regime. We find that the Loschmidt echo of a TG gas decays as a Gaussian when small (random and time independent) perturbations are added to the Hamiltonian. The exponent is proportional to the number of particles and the magnitude of a small perturbation squared. In the mean-field regime the Loschmidt echo shows richer behavior: it decays faster for larger nonlinearity, and the decay becomes more abrupt as the nonlinearity increases; it can be very sensitive to the particular realization of the noise potential, especially for relatively small nonlinearities.

  5. Photolysis of water for production of fuel gases

    SciTech Connect (OSTI)

    Eror, N.G.; Blakemore, J.S.

    1981-12-01T23:59:59.000Z

    To better understand the role of the semiconductor electrode in the photocatalytic decomposition of water to form hydrogen and other fuel gases, researchers characterized the defect structure of a number of large-band-gap semiconductor electrode materials. The defect structure of SrTiO/sub 3/ samples has been related to photoelectrochemical cell response, leading to a signficant improvement in the understanding of how electrode properties influence cell performance. Although the large band gap of these materials severely restricts their ability to use the solar spectrum, they are more resistant to photocorrosion than lower-band-gap materials. This band gap has been reduced somewhat in lanthanum-doped SrTiO/sub 3/ samples without compromising photostability or requiring a bias voltage for water decomposition.

  6. Finite-size energy of non-interacting Fermi gases

    E-Print Network [OSTI]

    Martin Gebert

    2014-06-14T23:59:59.000Z

    We prove the asymptotics of the difference of the ground-state energies of two non-interacting $N$-particle Fermi gases on the half line of length $L$ in the thermodynamic limit up to order $1/L$. We are particularly interested in subdominant terms proportional to $1/L$, called finite-size energy. In the nineties Affleck and co-authors [Aff97, ZA97, AL94] claimed that the finite-size energy equals the decay exponent occuring in Anderson's orthogonality catastrophe. It turns out that the finite-size energy depends on the details of the thermodynamic limit and typically also includes a linear term in the scattering phase shift.

  7. Free Energies of Dilute Bose gases: upper bound

    E-Print Network [OSTI]

    Jun Yin

    2010-12-19T23:59:59.000Z

    We derive a upper bound on the free energy of a Bose gas system at density $\\rho$ and temperature $T$. In combination with the lower bound derived previously by Seiringer \\cite{RS1}, our result proves that in the low density limit, i.e., when $a^3\\rho\\ll 1$, where $a$ denotes the scattering length of the pair-interaction potential, the leading term of $\\Delta f$ the free energy difference per volume between interacting and ideal Bose gases is equal to $4\\pi a (2\\rho^2-[\\rho-\\rhoc]^2_+)$. Here, $\\rhoc(T)$ denotes the critical density for Bose-Einstein condensation (for the ideal gas), and $[\\cdot ]_+$ $=$ $\\max\\{\\cdot, 0\\}$ denotes the positive part.

  8. Elliptic flow and nearly perfect fluidity in dilute Fermi gases

    E-Print Network [OSTI]

    Thomas Schaefer

    2010-12-16T23:59:59.000Z

    In this contribution we summarize recent progress in understanding the shear viscosity of strongly correlated dilute Fermi gases. We discuss predictions from kinetic theory, and show how these predictions can be tested using recent experimental data on elliptic flow. We find agreement between theory and experiments in the high temperature regime $T\\gg T_F$, where $T_F$ is the the temperature where quantum degeneracy effects become important. In the low temperature regime, $T\\sim T_F$, the strongest constraints on the shear viscosity come from experimental studies of the damping of collective modes. These experiments indicate that $\\eta/s\\lsim 0.5\\hbar/k_B$, where $\\eta$ is the shear viscosity and $s$ is the entropy density.

  9. Light pulse in {Lambda}-type cold-atom gases

    SciTech Connect (OSTI)

    Wei Ran; Deng Youjin; Chen Shuai; Chen Zengbing; Pan Jianwei [Hefei National Laboratory for Physical Sciences at Microscale and Department of Modern Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); Zhao Bo [Institute for Theoretical physics, University of Innsbruck, A-6020 Innsbruck (Austria); Institute for Quantum Optics and Quantum Information of the Austrian Academy of Science, A-6020 Innsbruck (Austria)

    2010-04-15T23:59:59.000Z

    We investigate the behavior of the light pulse in {Lambda}-type cold-atom gases with two counter-propagating control lights with equal strength by directly simulating the dynamic equations and exploring the dispersion relation. Our analysis shows that, depending on the length L{sub 0} of the stored wave packet and the decay rate {gamma} of ground-spin coherence, the recreated light can behave differently. For long L{sub 0} and/or large {gamma}, a stationary light pulse is produced, while two propagating light pulses appear for short L{sub 0} and/or small {gamma}. In the {gamma}{yields}0 limit, the light always splits into two propagating pulses for a sufficiently long time. This scenario agrees with a recent experiment [Y.-W. Lin et al., Phys. Rev. Lett. 102, 213601 (2009)] where two propagating light pulses are generated in laser-cooled cold-atom ensembles.

  10. Fuel cell stack with internal manifolds for reactant gases

    DOE Patents [OSTI]

    Schnacke, Arthur W. (Schenectady, NY)

    1985-01-01T23:59:59.000Z

    A fuel cell stack includes a plurality of plate-like fuel cells arranged along an axis generally parallel to cell thickness with electrically conductive separator plates between each pair of cells. A plurality of axial manifolds are provided at opposite sides of the stack in outer marginal portions beyond the edges of electrodes and electrolyte tiles. Sealing rings prevent cross-leakage of oxidant fuel gases through use of pairs of outwardly extending lips from opposite tile surfaces bonded to first and second electrode frames respectively. The frames provide transition between electrode edges and manifold perimeters. The pairs of extension lips are sealingly bonded together through an electrically insulative sealing ring with wedge shaped fastening members.

  11. Fuel cell stack with internal manifolds for reactant gases

    DOE Patents [OSTI]

    Schnacke, A.W.

    1983-10-12T23:59:59.000Z

    A fuel cell stack includes a plurality of plate-like fuel cells arranged along an axis generally parallel to cell thickness with electrically conductive separator plates between each pair of cells. A plurality of axial manifolds are provided at opposite sides of the stack in outer marginal portions beyond the edges of electrodes and electrolyte tiles. Sealing rings prevent cross-leakage of oxidant fuel gases through use of pairs of outwardly extending lips from opposite tile surfaces bonded to first and second electrode frames respectively. The frames provide transition between electrode edges and manifold perimeters. The pairs of extension lips are sealingly bonded together through an electrically insulative sealing ring with wedge shaped fastening members.

  12. Title of Dissertation: HIGH POWER NONLINEAR PROPAGATION OF LASER PULSES IN TENUOUS GASES

    E-Print Network [OSTI]

    Anlage, Steven

    ABSTRACT Title of Dissertation: HIGH POWER NONLINEAR PROPAGATION OF LASER PULSES IN TENUOUS GASES AND PLASMA CHANNELS Jianzhou Wu, Doctor of Philosophy, 2005 Dissertation Directed By: Professor Thomas M PROPAGATION OF LASER PULSES IN TENUOUS GASES AND PLASMA CHANNELS By Jianzhou Wu Dissertation submitted

  13. Monte Carlo Simulation of Radiation in Gases with a NarrowBand Model

    E-Print Network [OSTI]

    Dufresne, Jean-Louis

    , France (\\Phi) now at the Institute of Energy and Power Plant Technology, TH Darmstadt, 64287 DarmstadtMonte Carlo Simulation of Radiation in Gases with a Narrow­Band Model and a Net is used for simulation of radiative heat transfers in non­gray gases. The proposed procedure is based

  14. Abstract--Airborne pollution and explosive gases threaten human health and occupational safety, therefore generating high

    E-Print Network [OSTI]

    Mason, Andrew

    Abstract--Airborne pollution and explosive gases threaten human health and occupational safety and a thumb-drive sized prototype system. I. INTRODUCTION xposure to air pollution consistently ranks among to occupational safety as energy demands rise. Airborne pollutants and explosive gases vary in both time and space

  15. Permeation of Gases in Polymers: Parameter Identification and Nonlinear Regression Analysis

    E-Print Network [OSTI]

    Scheichl, Robert

    Permeation of Gases in Polymers: Parameter Identification and Nonlinear Regression Analysis Robert at PARAOPE, Heidelberg, June 30th, 2004 #12;Overview · Permeation of gases in polymers ­ Application areas for diffusion in polymers ­ Description of the experimental device ­ Mathematical model · Parameter

  16. Heavy noble gases in solar wind delivered by Genesis mission Alex Meshik a,

    E-Print Network [OSTI]

    measured in the Genesis solar wind collectors generally agree with the less precise values obtained fromHeavy noble gases in solar wind delivered by Genesis mission Alex Meshik a, , Charles Hohenberg knowledge of the isotopic composition of the heavy noble gases in solar wind and, by inference, the Sun

  17. Preserving noble gases in a convecting mantle Helge M. Gonnermann1

    E-Print Network [OSTI]

    Mukhopadhyay, Sujoy

    of a processed and out- gassed lower-mantle source, residues of mantle melting10,11 , depleted in uranium and mixing of noble-gas-depleted slabs dilutes the concentrations of noble gases in the mantle, thereby melt, which forms the ocean crust and leaves the residual mantle severely depleted of noble gases

  18. Bose-Einstein condensates in 85 Rb gases at higher densities

    E-Print Network [OSTI]

    Glyde, Henry R.

    Bose-Einstein condensates in 85 Rb gases at higher densities A. R. Sakhel, J. L. DuBois, and H. R August 2002; published 31 December 2002 The Bose-Einstein condensation in trapped gases of 85 Rb find that there is a significant depletion of the condensate at T 0 K, for example, 25% at na3 10 2

  19. Localization of Bogoliubov quasiparticles in interacting Bose gases with correlated disorder P. Lugan1,2

    E-Print Network [OSTI]

    Boyer, Edmond

    ) in a weakly interacting Bose gas of chemical potential µ subjected to a disordered potential V . We introduce-Einstein condensates [40­48], interacting Bose gases at equilibrium [26, 49­72], strongly interacting Fermi gases [73 behaviors can be found in various situa- tions. For instance, weak repulsive interactions in a Bose gas

  20. Method of recovering sulfur from the hydrogen sulfide contained in coke oven gases

    SciTech Connect (OSTI)

    Laufhutte, D.

    1985-04-30T23:59:59.000Z

    Ammonia and hydrogen sulfide are washed out of the coke oven gas and stripped from the wash liquor in the form of gases and fumes or vapors. The ammonia is decomposed in a nickel catalyzer and a small part of the decomposition gases is supplied directly to a combustion furnace, while the larger part of the combustion gases is first cooled and freed from condensate, and only then supplied to the combustion furnace. In the combustion furnace, the proportion of H/sub 2/S/SO/sub 2/ needed for the Claus process is adjusted by a partial combustion of the decomposition gases. The gases from the combustion furnace are then processed in the Claus plant to sulfur.

  1. Operation of a Four-Cylinder 1.9L Propane Fueled Homogeneous Charge Compression Ignition Engine: Basic Operating Characteristics and Cylinder-to-Cylinder Effects

    SciTech Connect (OSTI)

    Flowers, D; Aceves, S M; Martinez-Frias, J; Smith, J R; Au, M; Girard, J; Dibble, R

    2001-03-12T23:59:59.000Z

    A four-cylinder 1.9 Volkswagen TDI Engine has been converted to run in Homogeneous Charge Compression Ignition (HCCI) mode. The stock configuration is a turbocharged direct injection Diesel engine. The combustion chamber has been modified by discarding the in-cylinder Diesel fuel injectors and replacing them with blank inserts (which contain pressure transducers). The stock pistons contain a reentrant bowl and have been retained for the tests reported here. The intake and exhaust manifolds have also been retained, but the turbocharger has been removed. A heater has been installed upstream of the intake manifold and fuel is added just downstream of this heater. The performance of this engine in naturally aspirated HCCI operation, subject to variable intake temperature and fuel flow rate, has been studied. The engine has been run with propane fuel at a constant speed of 1800 rpm. This work is intended to characterize the HCCI operation of the engine in this configuration that has been minimally modified from the base Diesel engine. The performance (BMEP, IMEP, efficiency, etc) and emissions (THC, CO, NOx) of the engine are presented, as are combustion process results based on heat release analysis of the pressure traces from each cylinder.

  2. Feasibility of reconstructing paleoatmospheric records of selected alkanes, methyl halides, and sulfur gases from Greenland ice cores

    E-Print Network [OSTI]

    Aydin, M.; Williams, M. B; Saltzman, E. S

    2007-01-01T23:59:59.000Z

    firn and ice at Summit, Greenland, J. Geophys. Res. , 98,AL. : TRACE GASES IN GREENLAND ICE CORE ¨ . Andreae Kettle,and sulfur gases from Greenland ice cores M. Aydin, 1 M. B.

  3. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    EMISSIONS OF NON-CO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITYEMISSIONS OF NON-CO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITY

  4. Oxygen buffering of Kilauea volcanic gases and the oxygen fugacity of Kilauea basalt

    SciTech Connect (OSTI)

    Gerlach, T.M. (Geological Survey, Vancouver, WA (United States))

    1993-02-01T23:59:59.000Z

    Volcanic gases collected during episode 1 of the Puu Oo eruption along the east rift zone of Kilauea Volcano, Hawaii, have uniform C-O-H-S-Cl-F compositions that are sharply depleted in CO[sub 2]. The CO[sub 2]-poor gases are typical of Type II volcanic gases (GERLACH and GRAEBER, 1985) and were emitted from evolved magma stored for a prolonged period of time in the east rift zone after releasing CO[sub 2]-rich gases during an earlier period of temporary residence in the summit magma chamber. The samples are remarkably free of contamination by atmospheric gases and meteoric water. Thermodynamic evaluation of the analytical data shows that the episode 1 gases have equilibrium compositions appropriate for temperatures between 935 and 1032[degrees]C. Open- and closed-system equilibrium models of species distributions for the episode 1 gases show unequivocally that coexisting lavas buffered the gas oxygen fugacities during cooling. These models indicate that the F[sub o[sub 2

  5. 2D Coulomb Gases and the Renormalized Energy

    E-Print Network [OSTI]

    Sandier, Etienne

    2012-01-01T23:59:59.000Z

    We study the statistical mechanics of classical two-dimensional "Coulomb gases" with general potential and arbitrary \\beta, the inverse of the temperature. Such ensembles also correspond to random matrix models in some particular cases. The formal limit case \\beta=\\infty corresponds to "weighted Fekete sets" and also falls within our analysis. It is known that in such a system points should be asymptotically distributed according to a macroscopic "equilibrium measure," and that a large deviations principle holds for this, as proven by Ben Arous and Zeitouni. By a suitable splitting of the Hamiltonian, we connect the problem to the "renormalized energy" W, a Coulombian interaction for points in the plane introduced in our prior work, which is expected to be a good way of measuring the disorder of an infinite configuration of points in the plane. By so doing, we are able to examine the situation at the microscopic scale, and obtain several new results: a next order asymptotic expansion of the partition function...

  6. Noble gases in the howardites Bholghati and Kapoeta

    SciTech Connect (OSTI)

    Swindle, T.D. (Univ. of Arizona, Tucson (USA)); Garrison, D.H.; Hohenberg, C.M.; Nichols, R.H.; Olinger, C.T. (Washington Univ., St. Louis, MO (USA)); Goswami, J.N. (Physical Research Laboratory, Ahmedabad (India))

    1990-08-01T23:59:59.000Z

    Analyses of noble gases in whole rock samples of the howardites Bholghati and Kapoeta and grain-size separates of Kapoeta yield evidence for excesses of the Xe isotopes {sup 129}Xe, {sup 131}Xe, {sup 132}Xe, {sup 134}Xe, and {sup 136}Xe in a low-temperature component, similar to lunar excess fission Xe. Such a component may be able to provide chronometric information if the relative abundances of radioactive progenitors ({sup 129}I, {sup 244}Pu, and {sup 238}U) can be determined, but the isotopic spectra we obtain are not sufficiently precise to do so. Eucritic clast BH-5 in Bholghati contains Xe produced in situ by the decay of {sup 244}Pu. Calculated fission Xe retention ages are 30-70 Ma after the formation of the solar system, consistent with the apparent presence of {sup 146}Sm decay products. Both the clast and the matrix of Bholghati have K-Ar ages of about 2 Ga, suggesting a common thermal event at least that recently.

  7. In-Situ Microbial Conversion of Sequestered Greenhouse Gases

    SciTech Connect (OSTI)

    Scott, A R; Mukhopadhyay, M; Balin, D F

    2012-09-06T23:59:59.000Z

    The objectives of the project are to use microbiological in situ bioconversion technology to convert sequestered or naturally-occurring greenhouse gases, including carbon dioxide and carbon monoxide, into methane and other useful organic compounds. The key factors affecting coal bioconversion identified in this research include (1) coal properties, (2) thermal maturation and coalification process, (3) microbial population dynamics, (4) hydrodynamics (5) reservoir conditions, and (6) the methodology of getting the nutrients into the coal seams. While nearly all cultures produced methane, we were unable to confirm sustained methane production from the enrichments. We believe that the methane generation may have been derived from readily metabolized organic matter in the coal samples and/or biosoluble organic material in the coal formation water. This raises the intriguing possibility that pretreatment of the coal in the subsurface to bioactivate the coal prior to the injection of microbes and nutrients might be possible. We determined that it would be more cost effective to inject nutrients into coal seams to stimulate indigenous microbes in the coal seams, than to grow microbes in fermentation vats and transport them to the well site. If the coal bioconversion process can be developed on a larger scale, then the cost to generate methane could be less than $1 per Mcf

  8. Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.

  9. International Journal of Mass Spectrometry 248 (2006) 18 Molecular hydrogen ion elimination from alkyl iodides

    E-Print Network [OSTI]

    Strathclyde, University of

    reported on many occasions [1­7]. Recently, we have studied the ionization/dissociation pro- cesses of some 26510 98695. E-mail address: kkosmid@cc.uoi.gr (C. Kosmidis). ethane, propane, etc.) has been studied of propane, Tonokura et al. [13] have shown that the atomic hydrogen elim- ination channel exhibits a site

  10. Quantifying emissions of greenhouse gases from South Asia through a targeted measurement campaign

    E-Print Network [OSTI]

    Ganesan, Anita Lakshmi

    2013-01-01T23:59:59.000Z

    Methane (CH 4 ), nitrous oxide (N20) and sulfur hexafluoride (SF6) are powerful greenhouse gases with global budgets that are well-known but regional distributions that are not adequately constrained for the purposes of ...

  11. Spatio-temporal theory of lasing action in optically-pumped rotationally excited molecular gases

    E-Print Network [OSTI]

    Chua, Song-Liang

    We investigate laser emission from optically-pumped rotationally excited molecular gases confined in a metallic cavity. To this end, we have developed a theoretical framework able to accurately describe, both in the spatial ...

  12. Field-driven dynamics of dilute gases, viscous liquids and polymer chains

    E-Print Network [OSTI]

    Mohan, Aruna, 1981-

    2007-01-01T23:59:59.000Z

    This thesis is concerned with the exploration of field-induced dynamical phenomena arising in dilute gases, viscous liquids and polymer chains. The problems considered herein pertain to the slip-induced motion of a rigid, ...

  13. Eddy covariance flux measurements of pollutant gases in urban Mexico City

    E-Print Network [OSTI]

    Velasco, Erik

    Eddy covariance (EC) flux measurements of the atmosphere/surface exchange of gases over an urban area are a direct way to improve and evaluate emissions inventories, and, in turn, to better understand urban atmospheric ...

  14. Fact #825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus...

    Broader source: Energy.gov (indexed) [DOE]

    organic gases (NMOG) and nitrogen oxides (NOx) that new light vehicles with gasoline engines are allowed to produce for model years 2017 to 2025. These standards apply to a...

  15. Evolution and stability of shock waves in dissipative gases characterized by activated inelastic collisions

    E-Print Network [OSTI]

    Sirmas, Nick

    2015-01-01T23:59:59.000Z

    Previous experiments have revealed that shock waves driven through dissipative gases may become unstable, for example, in granular gases, and in molecular gases undergoing strong relaxation effects. The mechanisms controlling these instabilities are not well understood. We successfully isolated and investigated this instability in the canonical problem of piston driven shock waves propagating into a medium characterized by inelastic collision processes. We treat the standard model of granular gases, where particle collisions are taken as inelastic with constant coefficient of restitution. The inelasticity is activated for sufficiently strong collisions. Molecular dynamic simulations were performed for 30,000 particles. We find that all shock waves investigated become unstable, with density non-uniformities forming in the relaxation region. The wavelength of these fingers is found comparable to the characteristic relaxation thickness. Shock Hugoniot curves for both elastic and inelastic collisions were obtaine...

  16. Biological sweetening of energy gases mimics in biotrickling filters Marc Fortuny a,c

    E-Print Network [OSTI]

    in energy-rich gases such as biogas from anaerobic digesters which may contain H2S concentrations exceeding: Hydrogen sulfide; Gas sweetening; Biotrickling filter; Desulfurization; Fuel gas; Biogas 1. Introduction

  17. Method and apparatus for separating mixtures of gases using an acoustic wave

    DOE Patents [OSTI]

    Geller, Drew A.; Swift, Gregory W.; Backhaus, Scott N.

    2004-05-11T23:59:59.000Z

    A thermoacoustic device separates a mixture of gases. An elongated duct is provided with first and second ends and has a length that is greater than the wavelength of sound in the mixture of gases at a selected frequency, and a diameter that is greater than a thermal penetration depth in the mixture of gases. A first acoustic source is located at the first end of the duct to generate acoustic power at the selected frequency. A plurality of side branch acoustic sources are spaced along the length of the duct and are configured to introduce acoustic power into the mixture of gases so that a first gas is concentrated at the first end of the duct and a second gas is concentrated at the second end of the duct.

  18. What are greenhouse gases? Many chemical compounds in the atmosphere act as

    E-Print Network [OSTI]

    , Michigan State University, 2 Michigan State University Extension Climate Change and Agriculture Fact Sheet greenhouse gases carbon dioxide, methane, and nitrous oxide over the past 2000 years. Data are from ice core

  19. Quantum Cattaneo wave equation for ultra-short laser pulses interaction with electron and nucleon gases

    E-Print Network [OSTI]

    Marciak-Kozlowska, J

    2011-01-01T23:59:59.000Z

    In this paper the quantum Cattaneo wave equation for ultra-short laser pulses interaction with medium is obtained . The explicit formulae for electron and nucleon gases are presented

  20. Quantum coherence and magnetism in bosonic and fermionic gases of ultracold atoms

    E-Print Network [OSTI]

    Jo, Gyu-Boong

    2010-01-01T23:59:59.000Z

    In this thesis, two sets of experimental studies in bosonic and fermionic gases are described. In the first part of the thesis, itinerant ferromagnetism was studied in a strongly interacting Fermi gas of ultracold atoms. ...