Sample records for gases coke oven

  1. Method of recovering sulfur from the hydrogen sulfide contained in coke oven gases

    SciTech Connect (OSTI)

    Laufhutte, D.

    1985-04-30T23:59:59.000Z

    Ammonia and hydrogen sulfide are washed out of the coke oven gas and stripped from the wash liquor in the form of gases and fumes or vapors. The ammonia is decomposed in a nickel catalyzer and a small part of the decomposition gases is supplied directly to a combustion furnace, while the larger part of the combustion gases is first cooled and freed from condensate, and only then supplied to the combustion furnace. In the combustion furnace, the proportion of H/sub 2/S/SO/sub 2/ needed for the Claus process is adjusted by a partial combustion of the decomposition gases. The gases from the combustion furnace are then processed in the Claus plant to sulfur.

  2. Innovative coke oven gas cleaning system for retrofit applications

    SciTech Connect (OSTI)

    Not Available

    1992-08-24T23:59:59.000Z

    The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the final coolers, hydrogen sulfide removal system and the sulfur recovery system. The existing wastewater treatment, tar recovery and one of the three light oil recovery systems will continue to be used to support the new innovative combination of COG treatment technologies.

  3. Method for processing coke oven gas

    SciTech Connect (OSTI)

    Flockenhaus, C.; Meckel, J.F.; Wagener, D.

    1980-11-25T23:59:59.000Z

    Coke oven gas is subjected, immediately after the discharge thereof from coke ovens, and without any preliminary cooling operation or any purification operation other than desulfurization, to a catalytic cracking operation to form a hot cracked gas which is rich in hydrogen and carbon monoxide. The catalytic cracking reaction is carried out in the presence of a hydrogen-containing and/or CO2-containing gas, with a steam reforming catalyst.

  4. Coke oven gas injection to blast furnaces

    SciTech Connect (OSTI)

    Maddalena, F.L.; Terza, R.R.; Sobek, T.F.; Myklebust, K.L. [U.S. Steel, Clairton, PA (United States)

    1995-12-01T23:59:59.000Z

    U.S. Steel has three major facilities remaining in Pennsylvania`s Mon Valley near Pittsburgh. The Clairton Coke Works operates 12 batteries which produce 4.7 million tons of coke annually. The Edgar Thomson Works in Braddock is a 2.7 million ton per year steel plant. Irvin Works in Dravosburg has a hot strip mill and a range of finishing facilities. The coke works produces 120 mmscfd of coke oven gas in excess of the battery heating requirements. This surplus gas is used primarily in steel re-heating furnaces and for boiler fuel to produce steam for plant use. In conjunction with blast furnace gas, it is also used for power generation of up to 90 MW. However, matching the consumption with the production of gas has proved to be difficult. Consequently, surplus gas has been flared at rates of up to 50 mmscfd, totaling 400 mmscf in several months. By 1993, several changes in key conditions provided the impetus to install equipment to inject coke oven gas into the blast furnaces. This paper describes the planning and implementation of a project to replace natural gas in the furnaces with coke oven gas. It involved replacement of 7 miles of pipeline between the coking plants and the blast furnaces, equipment capable of compressing coke oven gas from 10 to 50 psig, and installation of electrical and control systems to deliver gas as demanded.

  5. New process to avoid emissions: Constant pressure in coke ovens

    SciTech Connect (OSTI)

    Giertz, J.; Huhn, F. [DMT-Gesellschaft fuer Forschung und Pruefung mbH, Essen (Germany). Inst. for Cokemaking and Fuel Technology; Hofherr, K. [Thyssen Stahl AG, Duisburg (Germany)

    1995-12-01T23:59:59.000Z

    A chamber pressure regulation (PROven), especially effective in regard to emission control problems of coke ovens is introduced for the first time. Because of the partial vacuum in the collecting main system, it is possible to keep the oven`s raw gas pressure constant on a low level over the full coking time. The individual pressure control for each chamber is assured directly as a function of the oven pressure by an immersion system controlling the flow resistance of the collecting main valve. The latter is a fixed-position design (system name ``FixCup``). By doing away with the interdependence of collecting main pressure and chamber pressure, a parameter seen as a coking constant could not be made variable. This opens a new way to reduce coke oven emissions and simultaneously to prevent the ovens from damage caused by air ingress into the oven.

  6. Factors affecting coking pressures in tall coke ovens

    SciTech Connect (OSTI)

    Grimley, J.J.; Radley, C.E. [British Steel plc, Scunthorpe (United Kingdom). Scunthorpe Works

    1995-12-01T23:59:59.000Z

    The detrimental effects of excessive coking pressures, resulting in the permanent deformation of coke oven walls, have been recognized for many years. Considerable research has been undertaken worldwide in attempts to define the limits within which a plant may safely operate and to quantify the factors which influence these pressures. Few full scale techniques are available for assessing the potential of a coal blend for causing wall damage. Inference of dangerous swelling pressures may be made however by the measurement of the peak gas pressure which is generated as the plastic layers meet and coalesce at the center of the oven. This pressure is referred to in this report as the carbonizing pressure. At the Dawes Lane cokemaking plant of British Steel`s Scunthorpe Works, a large database has been compiled over several years from the regulator measurement of this pressure. This data has been statistically analyzed to provide a mathematical model for predicting the carbonizing pressure from the properties of the component coals, the results of this analysis are presented in this report.

  7. Process for separating, especially in multiple stages, acid components such as CO/sub 2/, HCN and specifically H/sub 2/S, from gases, especially from coke oven gases, by means of ammonia recirculation scrubbing

    SciTech Connect (OSTI)

    Bauer, H.K.; Otte, E.A.W.

    1984-10-16T23:59:59.000Z

    A process of separating in multiple stages acid components in coke oven gas such as CO/sub 2/, HCN and particularly H/sub 2/S by ammonia scrubbing wherein the ammonia used in scrubbing is deacidified to remove the acid components and is recirculated to the scrubbing process at least in part as substantially pure liquid ammonia.

  8. Problem of improving coke oven gas purification systems

    SciTech Connect (OSTI)

    Goldin, I.A.

    1982-01-01T23:59:59.000Z

    A discussion of the problems of improving desulfurization processes of coke oven gas was presented. Of particular interest were control systems and increasing capacity of the coke ovens. Included in the discussion were the vacuum-carbonate and arsenic-soda sulfur removal systems. Problems involved with these systems were the number of treatment operations, the volume of the reagents used, and the operation of equipment for naphthalene and cyanide removal.

  9. Method for removing hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Ritter, H.

    1982-08-03T23:59:59.000Z

    An improved sulfur-ammonia process is disclosed for removing hydrogen sulfide from coke oven gases. In the improved process, a concentrator formerly used for standby operation is used at all normal times as an ammonia scrubber to improve the efficiency of gas separation during normal operation and is used as a concentrator for its intended standby functions during the alternative operations. In its normal function, the concentrator/scrubber functions as a scrubber to strip ammonia gas from recirculating liquid streams and to permit introduction of an ammonia-rich gas into a hydrogen sulfide scrubber to increase the separation efficiency of that unit. In the standby operation, the same concentrator/scrubber serves as a concentrator to concentrate hydrogen sulfide in a ''strong liquor'' stream for separate recovery as a strong liquor.

  10. Mathematical modeling of clearance between wall of coke oven and coke cake

    SciTech Connect (OSTI)

    Nushiro, K.; Matsui, T.; Hanaoka, K.; Igawa, K.; Sorimachi, K.

    1995-12-01T23:59:59.000Z

    A mathematical model was developed for estimating the clearance between the wall of the coke oven and the coke cake. The prediction model is based on the balance between the contractile force and the coking pressure. A clearance forms when the contractile force exceeds the coking pressure in this model. The contractile force is calculated in consideration of the visco-elastic behavior of the thermal shrinkage of the coke. The coking pressure is calculated considering the generation and dispersion of gas in the melting layer. The relaxation time off coke used in this model was obtained with a dilatometer under the load application. The clearance was measured by the laser sensor, and the internal gas pressure was measured in a test oven. The clearance calculated during the coking process were in good agreement with the experimental results, which supported the validity of the mathematical model.

  11. New process for coke-oven gas desulfurization

    SciTech Connect (OSTI)

    Currey, J.H. [Citizens Gas and Coke Utility, Indianapolis, IN (United States)

    1995-10-01T23:59:59.000Z

    With the EPA reclassifying spent iron oxide as a hazardous waste material in 1990, an alternative technology was sought for desulfurizing coke-oven gas. Vacasulf technology was adopted for reasons that included: producing of coke battery heating gas without further polishing and high-quality elemental sulfur; lowest operating cost in comparison with other methods; no waste products; and integrates with existing ammonia destruction facility. Vacasulf requires a single purchased material, potassium hydroxide, that reacts with carbon dioxide in coke-oven gas to form potassium carbonate which, in turn, absorbs hydrogen sulfide. Operation of the system has been successful following the resolution of relatively minor start-up problems.

  12. Coke oven gas desulfurization: at Republic Steel's New Coking Facility, Warren, OH

    SciTech Connect (OSTI)

    Boak, S.C.; Prucha, D.G.; Turic, H.L.

    1981-01-01T23:59:59.000Z

    Our performance test indicates that the Sulfiban process is an effective method for removing H/sub 2/S from coke-oven gas. The process is able to handle variations in coke-oven gas flow and composition. Continuing efforts are underway to maintain optimum desulfurization conditions while trying to reduce waste production and MEA consumption. The problems which have prevented us from operating continuously have given us a better understanding of the process. This has contributed to better plant operations and greater equipment reliability for us to obtain continuous coke-oven gas desulfurization. 2 figures, 1 table.

  13. Pipeline charging of coke ovens with a preheated charge

    SciTech Connect (OSTI)

    Karpov, A.V.; Khadzhioglo, A.V.; Kuznichenko, V.M.

    1983-01-01T23:59:59.000Z

    Work to test a pipeline charging method was conducted at the Konetsk Coke Works (a PK-2K coke oven system with a single gas main, oven width 407 mm, height 4300 mm, effective column 20.0 cm/sub 3/). This method consists of transporting the heated coal charge to the ovens through a pipe by means of steam. the charge is transported by high pressure chamber groups, and loaded by means of systems equipped with devices for separation, withdrawal and treatment of the spent steam. The principal goal of the present investigation was to test technical advances in the emission-free charging of preheated charges. The problem was, first, to create a reliable technology for separation of the steam from the charge immediately before loading it into the oven and, second, to provide a total elimination of emissions, thereby protecting the environment against toxic substances.

  14. New packing in absorption systems for trapping benzene from coke-oven gas

    SciTech Connect (OSTI)

    V.V. Grabko; V.M. Li; T.A. Shevchenko; M.A. Solov'ev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The efficiency of benzene removal from coke-oven gas in absorption units OAO Alchevskkoks with new packing is assessed.

  15. A coke oven model including thermal decomposition kinetics of tar

    SciTech Connect (OSTI)

    Munekane, Fuminori; Yamaguchi, Yukio [Mitsubishi Chemical Corp., Yokohama (Japan); Tanioka, Seiichi [Mitsubishi Chemical Corp., Sakaide (Japan)

    1997-12-31T23:59:59.000Z

    A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

  16. Development of advanced technology of coke oven gas drainage treatment

    SciTech Connect (OSTI)

    Higashi, Tadayuki; Yamaguchi, Akikazu; Ikai, Kyozou; Kamiyama, Hisarou; Muto, Hiroshi

    1996-12-31T23:59:59.000Z

    In April 1994, commercial-scale application of ozone oxidation to ammonia liquor (which is primarily the water condensing from coke oven gas) to reduce its chemical oxygen demand (COD) was started at the Nagoya Works of Nippon Steel Corporation. This paper deals with the results of technical studies on the optimization of process operating conditions and the enlargement of equipment size and the operating purification system.

  17. Design and operation of the coke-oven gas sulfur removal facility at Geneva Steel

    SciTech Connect (OSTI)

    Havili, M.U.; Fraser-Smyth, L.L.; Wood, B.W. [Geneva Steel, Provo, UT (United States)

    1996-02-01T23:59:59.000Z

    The coke-oven gas sulfur removal facility at Geneva Steel utilizes a combination of two technologies which had never been used together. These two technologies had proven effective separately and now in combination. However, it brought unique operational considerations which has never been considered previously. The front end of the facility is a Sulfiban process. This monoethanolamine (MEA) process effectively absorbs hydrogen sulfide and other acid gases from coke-oven gas. The final step in sulfur removal uses a Lo-Cat II. The Lo-Cat process absorbs and subsequently oxidizes H{sub 2}S to elemental sulfur. These two processes have been effective in reducing sulfur dioxide emissions from coke-oven gas by 95%. Since the end of the start-up and optimization phase, emission rate has stayed below the 104.5 lb/hr limit of equivalent SO{sub 2} (based on a 24-hr average). In Jan. 1995, the emission rate from the sulfur removal facility averaged 86.7 lb/hr with less than 20 lb/hr from the Econobator exhaust. The challenges yet to be met are decreasing the operating expenses of the sulfur removal facility, notably chemical costs, and minimizing the impact of the heating system on unit reliability.

  18. X-ray evaluation of coke-oven gas line deposits

    SciTech Connect (OSTI)

    Swain, Y.T.

    1983-08-01T23:59:59.000Z

    Control of coke-oven gas pipeline deposits has been facilitated through the use of an X-ray technique that provides quantitative data without disrupting plant operations.

  19. Coke oven gas desulphurization by the Carl Still process

    SciTech Connect (OSTI)

    Knight, R.E.

    1981-01-01T23:59:59.000Z

    The Steubenville East Coke Plant need a desulfurization process that would desulfurize an eventual 95 million standard cubic feet per day of coke oven gas from an inlet of 450 gr/DSCF to an outlet of 45 gr/DSCF of hydrogen sulfide. The Dravo/Still plant process was selected, due to the use of ammonia which was available in the gas, as the absorbing agent. It was also a proven process. Dravo/Still also was capable of building a sulfuric acid plant. The desulfurization efficiency of the plant has consistently provided an average final gas sulfur loading below the guaranteed 45 gr/DSCF. This removal efficiency has enabled production of an average of 4615 tons per day of 66/sup 0/Be acid. Also SO/sub 2/ to SO/sub 3/ conversion has averaged 98%. 3 figures. (DP)

  20. Takahax-Hirohax process for coke oven gas desulfurization

    SciTech Connect (OSTI)

    Gastwirth, H.; Miner, R.; Stengle, W.

    1981-01-01T23:59:59.000Z

    This paper describes the Takahax-Hirohax process to desulfurize coke oven gas and to produce an ammonium sulfate end product. A review is also made of current operating experience and recent technical developments. The Takahax-Hirohax process is extremely useful when the COG contains a suitable ammonia to sulfur ratio and when ammonium sulfate is a desirable end product. No contaminated effluent streams are emitted from the process. The process is simple, reliable, flexible, and responds easily to COG variations. 4 figures, 3 tables. (DP)

  1. Process for dissolving coke oven deposits comprising atomizing a composition containing N-methyl-2-pyrrolidone into the gas lines

    SciTech Connect (OSTI)

    Stafford, M.L.; Nicholson, G.M.

    1993-07-06T23:59:59.000Z

    A method is described for cleaning gas lines in coke oven batteries comprising atomizing a composition into the gas lines of coke oven batteries, where the composition comprises N-methyl-2-pyrrolidone.

  2. Desulphurization of coke oven gas by the Stretford Process

    SciTech Connect (OSTI)

    Plenderleith, J.

    1981-01-01T23:59:59.000Z

    The Stretford process is probably the most effective means available for removing hydrogen sulphide from gas streams. For streams which do not contain hydrogen cyanide or excessive oxygen it should be nearly ideal. However, the large volume of waste liquor generated by fixation of hydrogen cyanide has prevented its widespread adoption for coke oven gas treatment. Investigations of various proposals for treating the waste liquor indicate that the only practicable way of dealing with it is by reductive incineration. Although attempts to apply the Peabody-Holmes reductive incineration process have been disappointing, significant progress in overcoming some of its deficiencies has been made. The Zimpro wet oxidation process will provide a convenient method of treating the HCN scrubber effluent at No. 1 Plant. However, it will not treat the sodium based liquor from the Stretford plant. Its application to Stretford waste treatment is limited to situations where ammonium liquors and ammonium sulphate recovery facilities are available. Commissioning of this plant has been delayed while a defect in the air compressor supplied for the plant is being remedied. When the problem of liquid effluent disposal has been overcome, and if reagent chemicals continue to be available at reasonable prices, the Stretford process will be a good choice for coke oven gas desulphurization. 8 figures.

  3. Innovative coke oven gas cleaning system for retrofit applications

    SciTech Connect (OSTI)

    Not Available

    1992-10-16T23:59:59.000Z

    Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

  4. Heating control methodology in coke oven battery at Rourkela Steel Plant

    SciTech Connect (OSTI)

    Bandyopadhyay, S.S.; Parthasarathy, L.; Gupta, A.; Bose, P.R.; Mishra, U.

    1996-12-31T23:59:59.000Z

    A methodology of heating control was evolved incorporating temperature data generated through infra-red sensor at quenching station and thermocouples specially installed in the gooseneck of coke oven battery No. 3 of RSP. Average temperature of the red-hot coke as pushed helps in diagnosis of the abnormal ovens and in setting the targeted battery temperature. A concept of coke readiness factor (Q) was introduced which on optimization resulted in lowering the specific heat consumption by 30 KCal/Kg.

  5. Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau (CPM)

    E-Print Network [OSTI]

    Boyer, Edmond

    - 1 - Modelling of a coke oven heating wall M. Landreau, D. Isler, Centre de Pyrolyse de Marienau with thermomechanical modelling of a coke oven heating wall. The objective is to define the safe limits of coke oven of walls, roof and larry car, pre-stresses (anchoring system), lateral pressure due to coal pushing A 3D

  6. The Videofil probe, a novel instrument to extend the coke oven service life

    SciTech Connect (OSTI)

    Gaillet, J.P.; Isler, D. [Centre de Pyrolyse de Marienau, Forbach (France)

    1997-12-31T23:59:59.000Z

    To prolong the service life of coke oven batteries, the Centre de Pyrolyse de Marienau developed the Videofil probe, a novel instrument to conduct diagnoses and to help repair operations of coke ovens. The Videofil probe is a flexible non-water-cooled endoscope which is used to locate flue wall damage and estimate its importance, to define the oven zones to repair and guide the repair work and to control the quality of the repair work and its durability.

  7. Bethlehem Steel announces plans to control coke oven air and water pollution

    SciTech Connect (OSTI)

    Not Available

    1989-08-01T23:59:59.000Z

    Bethlehem Steel Corporation and the Maryland Department of the Environment have announced an agreement under which Bethlehem will spend an estimated $92-million at its Sparrows Points, Md., plant for technologically-advanced controls to further reduce air and water pollution, mainly from the plant's coke ovens. The two major systems include one to treat by-product coke oven gas and chemicals, and another to upgrade existing pushing emission controls on two older coke oven batteries. One of the new systems will replace most of the existing equipment that cleans gas and treats chemicals created by the coking process at the plant's three coke oven batteries. Because this system has the potential to greatly reduce sulfur dioxide and other pollutants, the United States Department of Energy (DOE) in September announced that its installation qualified for funding as part of the nationwide Innovative Clean Coal Technology Program.

  8. Automatic coke oven heating control system at Burns Harbor for normal and repair operation

    SciTech Connect (OSTI)

    Battle, E.T.; Chen, K.L. [Bethlehem Steel Corp., Burns Harbor, IN (United States); [Bethlehem Steel Corp., PA (United States)

    1997-12-31T23:59:59.000Z

    An automatic heating control system for coke oven batteries was developed in 1985 for the Burns Harbor No. 1 battery and reported in the 1989 Ironmaking Conference Proceedings. The original system was designed to maintain a target coke temperature at a given production level under normal operating conditions. Since 1989, enhancements have been made to this control system so that it can also control the battery heating when the battery is under repair. The new control system has improved heating control capability because it adjusts the heat input to the battery in response to anticipated changes in the production schedule. During a recent repair of this 82 oven battery, the pushing schedule changed from 102 ovens/day to 88 ovens/day, then back to 102 ovens/day, then to 107 ovens/day. During this repair, the control system was able to maintain the coke temperature average standard deviation at 44 F, with a maximum 75 F.

  9. Development of automatic operation system for coke oven machines at Yawata Works of Nippon Steel Corporation

    SciTech Connect (OSTI)

    Matsunaga, Masao; Uematsu, Hiroshi; Nakagawa, Yoji; Ishiharaguchi, Yuji

    1995-12-01T23:59:59.000Z

    The coke plant is a working environment involving heavy dust emissions, high heat and demanding physical labor. The labor-saving operation of the coke plant is an essential issue from the standpoints of not only improvement in working environment, but also reduction in fixed cost by enhancement of labor productivity. Under these circumstances, Nippon Steel has implemented the automation of coke oven machines. The first automatic operation system for coke oven machinery entered service at Oita Works in 1992, followed by the second system at the No. 5 coke oven battery of the coke plant at Yawata Works. The Yawata automatic operation system is characterized by the installation of coke oven machinery to push as many as 140 ovens per day within a short cycle time, such as a preliminary ascension pipe cap opening car and cycle time simulator by the manned operation of the pusher, which is advantageous from the standpoint of investment efficiency, and by the monitoring of other oven machines by the pusher. These measures helped to reduce the manpower requirement to 2 persons per shift from 4 persons per shift. The system entered commercial operation in March, 1994 and has been smoothly working with an average total automatic rate of 97%. Results from the startup to recent operation of the system are reported below.

  10. Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 1, January 1, 1991--June 30, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-08-24T23:59:59.000Z

    The coke plant at the Sparrows Point Plant consist of three coke oven batteries and two coal chemical plants. The by-product coke oven gas (COG) consists primarily of hydrogen, methane, carbon monoxide, nitrogen and contaminants consisting of tars, light oils (benzene, toluene, and xylene) hydrogen sulfide, ammonia, water vapor and other hydrocarbons. This raw coke oven gas needs to be cleaned of most of its contaminants before it can be used as a fuel at other operations at the Sparrows Point Plant. In response to environmental concerns, BSC decided to replace much of the existing coke oven gas treatment facilities in the two coal chemical Plants (A and B) with a group of technologies consisting of: Secondary Cooling of the Coke oven Gas; Hydrogen Sulfide Removal; Ammonia Removal; Deacification of Acid Gases Removed; Ammonia Distillation and Destruction; and, Sulfur Recovery. This combination of technologies will replace the existing ammonia removal system, the final coolers, hydrogen sulfide removal system and the sulfur recovery system. The existing wastewater treatment, tar recovery and one of the three light oil recovery systems will continue to be used to support the new innovative combination of COG treatment technologies.

  11. Hydrogen production from steam reforming of coke oven gas and its utility for indirect reduction of iron oxides in blast

    E-Print Network [OSTI]

    Leu, Tzong-Shyng "Jeremy"

    of coal and coke are consumed for heating and reducing iron oxides [2,3]. As a result, BFs have becomeHydrogen production from steam reforming of coke oven gas and its utility for indirect reduction 2012 Available online 18 June 2012 Keywords: Steam reforming Hydrogen and syngas production Coke oven

  12. Operational improvements at Jewell Coal and Coke Company`s non-recovery ovens

    SciTech Connect (OSTI)

    Ellis, C.E.; Pruitt, C.W.

    1995-12-01T23:59:59.000Z

    Operational improvements at Jewell Coal and Coke Company over the past five years includes safety and environmental concerns, product quality, equipment availability, manpower utilization, and productivity. These improvements with Jewell`s unique process has allowed Jewell Coal and Coke Company to be a consistent, high quality coke producer. The paper briefly explains Jewell`s unique ovens, their operating mode, improved process control, their maintenance management program, and their increase in productivity.

  13. Use of ethylenediamine to remove hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Marakhovskii, L.F.; Popov, A.A.; Rezunenko, Yu.I.

    1983-01-01T23:59:59.000Z

    The investigations of the equilibrium absorption of H/sub 2/S by an EDA solution which show that the solubility of hydrogen sulfide in ethylenediamine solutions is almost twice that in monoethanolamine solutions. Ethylenediamine may be used as an absorber for thorough removal of H/sub 2/S from coke oven gas in the presence of CO/sub 2/ and HCN. The hydrogen cyanide of coke oven gas, having practically no effect on the equilibrium absorption of H/sub 2/S and CO/sub 2/, may in this case be recovered in the form of ethylenethiourea - a marketable byproduct.

  14. The use of ethylenediamine to remove hydrogen sulfide from coke oven gas

    SciTech Connect (OSTI)

    Marakhovskii, L.F.; Rezunenko, Y.I.; Popov, A.A.

    1983-01-01T23:59:59.000Z

    The investigations of the equilibrium absorption of H/sub 2/S by an EDA solution showed the solubility of hydrogen sulfide in ethylenediamine solutions is almost twice that in monoethanolamine solutions. Ethylenediamine may be used as an absorber for thorough removal of H/sub 2/S from coke oven gas in the presence of CO/sub 2/ and HCN. The hydrogen cyanide of coke oven gas, having practically no effect on the equilibrium absorption of H/sub 2/S and CO/sub 2/, may in this case be used in the form of ethylenethiourea - a marketable byproduct.

  15. Innovative coke oven gas cleaning system for retrofit applications. Volume 1, Public design report

    SciTech Connect (OSTI)

    Not Available

    1994-05-24T23:59:59.000Z

    This Public Design Report provides, in a single document, available nonproprietary design -information for the ``Innovative Coke Oven Gas Cleaning System for Retrofit Applications`` Demonstration Project at Bethlehem Steel Corporation`s Sparrows Point, Maryland coke oven by-product facilities. This project demonstrates, for the first time in the United States, the feasibility of integrating four commercially available technologies (processes) for cleaning coke oven gas. The four technologies are: Secondary Gas Cooling, Hydrogen Sulfide and Ammonia Removal, Hydrogen Sulfide and Ammonia Recovery, and Ammonia Destruction and Sulfur Recovery. In addition to the design aspects, the history of the project and the role of the US Department of,Energy are briefly discussed. Actual plant capital and projected operating costs are also presented. An overview of the integration (retrofit) of the processes into the existing plant is presented and is followed by detailed non-proprietary descriptions of the four technologies and their overall effect on reducing the emissions of ammonia, sulfur, and other pollutants from coke oven gas. Narrative process descriptions, simplified process flow diagrams, input/output stream data, operating conditions, catalyst and chemical requirements, and utility requirements are given for each unit. Plant startup provisions, environmental considerations and control monitoring, and safety considerations are also addressed for each process.

  16. SOLOX coke-oven gas desulfurization ppm levels -- No toxic waste

    SciTech Connect (OSTI)

    Platts, M. (Thyssen Still Otto Technical Services, Pittsburgh, PA (United States)); Tippmer, K. (Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany))

    1994-09-01T23:59:59.000Z

    For sulfur removal from coke-oven gas, the reduction/oxidation processes such as Stretford are the most effective, capable of removing the H[sub 2]S down to ppm levels. However, these processes have, in the past, suffered from ecological problems with secondary pollutant formation resulting from side reactions with HCN and O[sub 2]. The SOLOX gas desulfurization system is a development of the Stretford process in which the toxic effluent problems are eliminated by installing a salt decomposition process operating according to the liquid-phase hydrolysis principle. In this process, the gaseous hydrolysis products H[sub 2]S, NH[sub 3] and CO[sub 2] are returned to the untreated gas, and the regenerated solution is recycled to the absorption process. The blowdown from the absorption circuit is fed into a tube reactor where the hydrolysis process takes place. The toxic salts react with water, producing as reaction products the gases H[sub 2]S, NH[sub 3] and CO[sub 2], and the nontoxic salt Na[sub 2]SO[sub 4]. From the hydrolysis reactor the liquid stream flows into a fractionating crystallization plant. This plant produces a recycle stream of regenerated absorption solution and a second stream containing most of the Na[sub 2]SO[sub 4]. This second stream comprises the net plant waste and can be disposed of with the excess ammonia liquor or sprayed onto the coal.

  17. Utilizing secondary heat to heat wash oil in the coke-oven gas desulfurization division

    SciTech Connect (OSTI)

    Volkov, E.L.

    1981-01-01T23:59:59.000Z

    Removal of hydrogen sulfide from the coke-oven gas by the vacuum-carbonate method involves significant energy costs, comprising about 47% of the total costs of the process. This is explained by the significant demand of steam for regeneration of the wash oil, the cost of which exceeds 30% of the total operating costs. The boiling point of the saturated wash oil under vacuum does not exceed 70/sup 0/C, thus the wash oil entering the regenerator can be heated either by the direct coke-oven gas or by the tar supernatant from the gas collection cycle. Utilizing the secondary heat of the direct coke-oven gas and the tar supernatant liquor (the thermal effect is approximately the same) to heat the wash oil from the gas desulfurization shops significantly improves the industrial economic indices. Heating the wash oil from gas desulfurization shops using the vacuum-carbonate method by the heat of the tar supernatant liquor may be adopted at a number of coking plants which have a scarcity of thermal resources and which have primary coolers with vertical tubes.

  18. Final environmental information volume for the coke oven gas cleaning project at the Bethlehem Steel Corporation Sparrows Point Plant

    SciTech Connect (OSTI)

    Not Available

    1990-04-24T23:59:59.000Z

    Bethelehem Steel Corporation (BSC) is planning to conduct a demonstration project involving an integrated system that can be retrofitted into coke oven gas handling systems to address a variety of environmental and operational factors in a more cost-effective manner. Successful application of this technology to existing US coke plants could: (1) reduce emissions of sulfur dioxide, cyanide, and volatile organic compounds (including benzene) (2) reduce the cost and handling of processing feed chemicals, (3) disposal costs of nuisance by-products and (4) increase reliability and reduce operation/maintenance requirements for coke oven gas desulfurization systems. The proposed system will remove sulfur from the coke oven gas in the form of hydrogen sulfide using the ammonia indigenous to the gas as the primary reactive chemical. Ammonia and hydrogen cyanide are also removed in this process. The hydrogen sulfide removed from the coke oven gas in routed to a modified Claus plant for conversion to a saleable sulfur by-product. Ammonia and hydrogen cyanide will be catalytically converted to hydrogen, nitrogen, carbon dioxide, and carbon monoxide. The tail gas from the sulfur recovery unit is recycled to the coke oven gas stream, upstream of the new gas cleaning system. The proposed demonstration project will be installed at the existing coke oven facilities at BSC's Sparrows Point Plant. This volume describes the proposed actions and the resulting environmental impacts. 21 refs., 19 figs., 9 tabs.

  19. Coke oven doors: Historical methods of emission control and evaluation of current designs

    SciTech Connect (OSTI)

    Pettrey, J.O.; Greene, D.E. (Armco Steel Co., Middletown, OH (United States))

    1993-01-01T23:59:59.000Z

    The containment of oven door leakage has presented challenges to coke producers for many years as the requirements of environmental regulatory agencies have become increasingly stringent. A description and evaluation of past door modifications, leakage control methodologies and luting practices on Armco Steel Company, L.P.'s Ashland No. 4 Battery is detailed to provide a background for recent work, and to expand the industry's technology base. The strict door leakage standards of the 1990 amendments to the USA Clean Air Act has prompted additional technical studies. Both a joint Armco committee's evaluation of successful systems world wide and test door installations at Ashland were incorporated to determine compliance strategy. The eventual installation of Ikio Model II coke oven doors, along with modifications to ancillary equipment, has resulted in door leakage rates approaching zero. Associated methods, problems, results and evaluations are discussed.

  20. Choosing a coke-oven gas desulfurization system: a review of current technology

    SciTech Connect (OSTI)

    Lynch, P.A.

    1982-12-01T23:59:59.000Z

    Installation of coke-oven gas desulphurizing systems is primarily the result of air pollution control regulations. Although not currently profitable, operating costs can be minimized by choosing the technology most suited to the particular application. The Stretford Holmes, Takahax/Hirohax, Koppers Vacuum Carbonate, Sulfiban and Dravo/Still processes are discussed, together with criteria for economic analysis based on technical and by-product market evaluations.

  1. Method of washing hydrogen sulfide from coke oven gas by the ammonium sulfide method

    SciTech Connect (OSTI)

    Ritter, H.

    1985-05-21T23:59:59.000Z

    An improved coke oven gas washing process for removing hydrogen sulfide is proposed wherein the coke oven gas is treated in a hydrogen sulfide scrubber by counterflow with an aqueous ammonia wash water. A stream of aqueous weak ammonia liquor is cooled and sprayed through nozzles in the mid-region of the hydrogen sulfide scrubber. A quantity of aqueous ammonia liquor, corresponding to the quantity which is sprayed through the said nozzles, is withdrawn from the hydrogen sulfide scrubber at a level below the nozzles and is introduced into the top of the said hydrogen sulfide scrubber. Ammonia vapor released at the nozzles has a higher partial pressure than the ammonia partial pressure of the coke oven gas in the region of the nozzle. The aqueous ammonia liquor from the deacidifier is the source of the cooled aqueous ammonia liquor which is introduced through the nozzles. A portion of the aqueous ammonia liquor from the deacidifier is introduced directly into the top of the hydrogen sulfide scrubber as a portion of the required aqueous ammonia wash water.

  2. Health-hazard evaluation report No. HETA-88-377-2120, Armco Coke Oven, Ashland Kentucky

    SciTech Connect (OSTI)

    Kinnes, G.M.; Fleeger, A.K.; Baron, S.L.

    1991-06-01T23:59:59.000Z

    In response to a request from the Oil, Chemical and Atomic Workers International Union, a study was made of possible hazardous working conditions at ARMCO Coke Oven (SIC-3312), Ashland, Kentucky. The facility produces about 1,000,000 tons of coke annually. Of the approximately 400 total employees at the coke oven site, 55 work in the by products area. Air quality sampling results indicated overexposure to both benzene (71432) and coal tar pitch volatiles (CTPVs). Airborne levels of benzene ranged as high as 117 parts per million (ppm) with three of 17 samples being above the OSHA limit of 1ppm. Airborne concentrations of CTPVs ranged as high as 0.38mg/cu m with two of six readings being above OSHA limit of 0.2mg/cu m. Several polynuclear aromatic hydrocarbons were also detected. The authors conclude that by products area workers are potentially overexposed to carcinogens, including benzene, CTPVs, and polynuclear aromatic hydrocarbons. An epidemiologic study is considered unlikely to yield meaningful information at this time, due to the small number of workers and the short follow up period. The authors recommend specific measures for reducing potential employee exposures, including an environmental sampling program, a preventive maintenance program, improved housekeeping procedures, and reducing exposure in operators' booths.

  3. A mathematical model for the estimation of flue temperature in a coke oven

    SciTech Connect (OSTI)

    Choi, K.I.; Kim, S.Y.; Suo, J.S.; Hur, N.S.; Kang, I.S.; Lee, W.J.

    1997-12-31T23:59:59.000Z

    The coke plants at the Kwangyang works has adopted an Automatic Battery Control (ABC) system which consists of four main parts, battery heating control, underfiring heat and waste gas oxygen control, pushing and charging schedule and Autotherm-S that measures heating wall temperature during pushing. The measured heating wall temperature is used for calculating Mean Battery Temperature (MBT) which is average temperature of flues for a battery, but the Autotherm-S system can not provide the flue temperatures of an oven. This work attempted to develop mathematical models for the estimation of the flue temperature using the measured heating wall temperature and to examine fitness of the mathematical model for the coke plant operation by analysis of raw gas temperature at the stand pipe. Through this work it is possible to reflect heating wall temperature in calculating MBT for battery heating control without the interruption caused by a maintenance break.

  4. Reduction of NO[sub x] emissions coke oven gas combustion process

    SciTech Connect (OSTI)

    Terza, R.R. (USS Clairton Works, PA (United States)); Sardesai, U.V. (Westfield Engineering and Services, Inc., Houston, TX (United States))

    1993-01-01T23:59:59.000Z

    The paper describes by-product processing at Clairton Works which uses a unique cryogenic technology. Modifications to the desulfurization facility, nitrogen oxide formation in combustion processes (both thermal and fuel NO[sub x]), and the boilers plants are described. Boilers were used to study the contribution of fuel NO[sub x] formation during the combustion of coke oven gas. Results are summarized. The modifications made to the desulfurization facility resulted in the overall H[sub 2]S emission being reduced by 2-4 grains/100scf and the NO[sub x] emission being reduced by 21-42% in the boiler stacks.

  5. Coke oven gas treatment and by-product plant of Magnitogorsk Integrated Iron and Steel Works

    SciTech Connect (OSTI)

    Egorov, V.N.; Anikin, G.J. [Magnitogorsk Integrated Iron and Steel Works, (Russian Federation); Gross, M. [Krupp Koppers GmbH, Essen (Germany)

    1995-12-01T23:59:59.000Z

    Magnitogorsk Integrated Iron and Steel Works, Russia, decided to erect a new coke oven gas treatment and by-product plant to replace the existing obsolete units and to improve the environmental conditions of the area. The paper deals with the technological concept and the design requirements. Commissioning is scheduled at the beginning of 1996. The paper describes H{sub 2}S and NH{sub 3} removal, sulfur recovery and ammonia destruction, primary gas cooling and electrostatic tar precipitation, and the distributed control system that will be installed.

  6. Experience and results of new heating control system of coke oven batteries at Rautaruukki Oy Raahe Steel

    SciTech Connect (OSTI)

    Swanljung, J.; Palmu, P. [Rautaruukki Oy Raahe Steel (Finland)

    1997-12-31T23:59:59.000Z

    The latest development and results of the heating control system at Raahe Steel are presented in this paper. From the beginning of coke production in Rautaruukki Oy Raahe Steel (October 1987) the heating control systems have been developed. During the first stage of development work at the coking plant (from year 1987 to 1992), when only the first coke oven battery consisting of 35 ovens was in production, the main progress was in the field of process monitoring. After commissioning of the second stage of the coking plant (November 1992), the development of the new heating control model was started. Target of the project was to develop a dynamic control system which guides the heating of batteries through the various process conditions. Development work took three years and the heating control system was commissioned in the year 1995. Principle of the second generation system is an energy balance calculation, coke end temperature determination and dynamic oven scheduling system. The control is based on simultaneous feedforward and feedback control. The fuzzy logic components were added after about one year experience.

  7. Summing up of discussion on improvement trends in coke-oven gas purification flowsheets

    SciTech Connect (OSTI)

    Zemblevskii, K.K.

    1983-01-01T23:59:59.000Z

    Reference is made to a previously published article that included flowsheets for purification of coke-oven gas. It is concluded that the flowsheets for a process using arsenic-soda and vacuum-carbonate methods of sulfur removal in which the gas is cooled to 303-308/sup 0/K are seriously in error. Schemes involving minor refrigeration, sulfur removal by the circulating ammonia method and ammonia recovery as ammonia liquor are seen as promising but in need of further improvement. One scheme discussed (the VUKhIN scheme) involves ammonia recovery by the circulating phosphate method and sulfur removal by the circulating ammonia method is seen as a replacement for the minor refrigeration method. Since liquid ammonia consumption in agriculture is continually increasing, schemes that result in production of liquid ammonia rather than ammonia liquor should be seriously considered.

  8. Innovative coke oven gas cleaning system for retrofit applications. Environmental Monitoring program. Volume 1 - sampling progrom report. Baseline Sampling Program report

    SciTech Connect (OSTI)

    Stuart, L.M.

    1994-05-27T23:59:59.000Z

    Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This innovative coke oven gas cleaning system combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE provided cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct and Environmental Monitoring Plan for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. It also requires the preparation of a final report on the results of the Baseline Compliance and Supplemental Sampling Programs that are part of the EMP and which were conducted prior to the startup of the innovative coke oven gas cleaning system. This report is the Baseline Sampling Program report.

  9. Method and apparatus for quenching coke

    SciTech Connect (OSTI)

    Calderon, A.

    1980-07-22T23:59:59.000Z

    A method is described for controlling pollutions during the discharge of coke from a coke oven having a pusher side and a coke discharge opening. The method comprises the steps of moving a carriage into alignment with the coke discharge opening, pushing a body of hot coke out of the discharge opening of the oven, guiding the coke pushed from the oven into a chamber supported on said carriage, quenching the coke by directing liquid at coke which is pushed into said chamber for dropping the temperature of the coke, confining steam and vapor generated during the dropping of the temperature of the coke in the chamber for building a positive pressure within the chamber, forcing the steam and vapors generated from the quenching of the coke out of the chamber through a venturi-like opening by means of the positive pressure built up in the chamber, and spraying liquid at the gases forced through said venturi-like opening by the positive pressure in the chamber for cleaning the gases.

  10. Urinary 1-hydroxypyrene concentrations in Chinese coke oven workers relative to job category, respirator usage, and cigarette smoking

    SciTech Connect (OSTI)

    Bo Chen; Yunping Hu; Lixing Zheng; Qiangyi Wang; Yuanfen Zhou; Taiyi Jin [Fudan University, Shanghai (China). School of Public Health

    2007-09-15T23:59:59.000Z

    1-Hydroxypyrene (1-OHP) is a biomarker of recent exposure to polycyclic aromatic hydrocarbons (PAHs). We investigated whether urinary 1-OHP concentrations in Chinese coke oven workers (COWs) are modulated by job category, respirator usage, and cigarette smoking. The present cross-sectional study measured urinary 1-OHP concentrations in 197 COWs from Coking plant I and 250 COWs from Coking plant II, as well as 220 unexposed referents from Control plant I and 56 referents from Control plant II. Urinary 1-OHP concentrations (geometric mean, {mu}mol/mol creatinine) were 5.18 and 4.21 in workers from Coking plants I and II, respectively. The highest 1-OHP levels in urine were found among topside workers including lidmen, tar chasers, and whistlers. Benchmen had higher 1-OHP levels than other workers at the sideoven. Above 75% of the COWs exceeded the recommended occupational exposure limit of 2.3 {mu}mol/mol creatinine. Respirator usage and increased body mass index (BMI) slightly reduced 1-OHP levels in COWs. Cigarette smoking significantly increased urinary 1-OHP levels in unexposed referents but had no effect in COWs. Chinese COWs, especially topside workers and benchmen, are exposed to high levels of PAHs. Urinary 1-OHP concentrations appear to be modulated by respirator usage and BMI in COWs, as well as by smoking in unexposed referents.

  11. Development and introduction of methods for extracting hydrogen sulfide and hydrogen cyanide from coke-oven gas

    SciTech Connect (OSTI)

    Litvinenko, M.S.; Zaichenko, V.M.

    1980-01-01T23:59:59.000Z

    The progress between 1933 and the present in desulfurizing coal gas from coke ovens and making use of the by-products to produce sulfuric acid, thioyanates, etc. is described. The vacuum carbonate process and the monoethanolamine method are apparently now preferred, but some plants are still using modified arsenic-soda processes. More recently additional by-products have been thiocyanates (for producing acrylonitrile fiber) and hydrogen xanthanates. The production of other organic sulfur and cyanide compounds has been investigated for use as herbicides, corrosion inhibitors, etc. (LTN)

  12. Glass-coating and cleaning system to prevent carbon deposition on coke oven walls

    SciTech Connect (OSTI)

    Takahira, Takuya; Ando, Takeshi; Kasaoka, Shizuki; Yamauchi, Yutaka [Kawasaki Steel Corp., Mizushima, Kurashiki (Japan). Mizushima Works

    1997-12-31T23:59:59.000Z

    The new technology for protecting the coking chamber bricks from damage by hard-pushing is described. The technology consists of the glass coating on the wall bricks and a wall cleaner to blow deposited carbon. For the glass coating, a specially developed glaze is sprayed onto the wall bricks by a spraying device developed to completely spray one coking chamber in a few minutes. The wall cleaner is installed on a pusher ram in the facility to automatically blow air at a sonic speed during coke pushing. The life of the glazed layer is estimated to be over two years.

  13. Innovative coke oven gas cleaning system for retrofit applications. Quarterly technical progress report No. 4, October 1, 1990 to December 31, 1990

    SciTech Connect (OSTI)

    Kwasnoski, D.

    1993-10-22T23:59:59.000Z

    Work on this coke oven gas cleaning demonstration project (CCT-II) this quarter has been focused on Phase IIB tasks, and include engineering, procurement, construction, and training. Additionally, plans for changes in the operating schedule of the coke plant that affect the demonstration project are described. Engineering efforts are nearly complete. Remaining to be finalized is an assessment of electrical heat tracing/insulation needs for pipe lines, assessment of fire protection requirements, and instrument modifications. Procurement of all major equipment items is complete, except for possible additions to fire fighting capabilities. Major focus is on expediting pipe and structural steel to the project site. Civil construction is complete except for minor pads and bases as required for pipe supports, etc. Erection of the hydrogen sulfide and ammonia scrubber vessels is complete. Installation of scrubber vessel internals is underway. A subcontractor has been retained to develop a computerized program for operations and maintenance training for the coke oven gas treatment plant. Recent developments in the coke plant operating plans will result in reductions in the rate of production of coke oven gas to be processed in the demonstration project.

  14. Influence of technological factors on statics of hydrogen sulfide absorption from coke-oven gas by the ammonia process

    SciTech Connect (OSTI)

    Nazarov, V.G.; Kamennykh, B.M.; Rus'yanov, N.D.

    1983-01-01T23:59:59.000Z

    The basic technological factors that determine the effectiveness of hydrogen sulfide absorption from coke-oven gas by the cyclic ammonia process are the initial H/sub 2/S content of the gas, the degree of purification, the absorption temperature and the NH/sub 3/ and CO/sub 2/ contents of the absorbent solution. The effects of these factors on the statics of hydrogen sulfide absorption are studied. The investigation is based on the phase-equilibrium distributions of components in the absorption-desorption gas-cleaning cycle. The mathematical model is presented which includes the solution of a system of chemical equilibrium equations for reactions in the solution, material balances, and electrical neutrality. 4 references, 5 figures, 1 table.

  15. Startup and initial operation of a DFGD and pulse jet fabric filter system on Cokenergy's Indiana Harbor coke oven off gas system

    SciTech Connect (OSTI)

    Morris, W.J.; Gansley, R.R.; Schaddell, J.G.

    1999-07-01T23:59:59.000Z

    This paper describes the design, initial operation and performance testing of a Dry Flue Gas Desulfurization (DFGD) and Modular Pulse Jet Fabric Filter (MPJFF) system installed at Cokenergy's site in East Chicago, Indiana. The combined flue gas from the sixteen (16) waste heat recovery boilers is processed by the system to control emissions of sulfur dioxide and particulates. These boilers recover energy from coke oven off gas from Indiana Harbor Coke Company's coke batteries. The DFGD system consists of two 100% capacity absorbers. Each absorber vessel uses a single direct drive rotary atomizer to disperse the lime slurry for SO{sub 2} control. The MPJFF consists of thirty two (32) modules arranged in twin sixteen-compartment (16) units. The initial start up of the DFGD/MPJFF posed special operational issues due to the low initial gas flows through the system as the four coke oven batteries were cured and put in service for the first time. This occurred at approximately monthly intervals beginning in March 1998. A plan was implemented to perform a staged startup of the DFGD and MPJFF to coincide with the staged start up of the coke batteries and waste heat boilers. Operational issues that are currently being addressed include reliability of byproduct removal. Performance testing was conducted in August and September 1998 at the inlet of the system and the outlet stack. During these tests, particulate, SO{sub 2}, SO{sub 3}, and HCI emissions were measured simultaneously at the common DFGD inlet duct and the outlet stack. Measurements were also taken for average lime, water, and power consumption during the tests as well as system pressure losses. These results showed that all guarantee parameters were achieved during the test periods. The initial operation and performance testing are described in this paper.

  16. Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 3, January 1, 1991--December 31, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-10-16T23:59:59.000Z

    Bethlehem Steel Corporation (BSC), in conjunction with the Department of Energy (DOE) is conducting a Clean Coal Technology (CCT) project at its Sparrows Point, Maryland Coke Oven Plant. This project combines several existing technologies into an integrated system for removing impurities from Coke Oven Gas (COG) to make it an acceptable fuel. DOE is providing cost-sharing under a Cooperative Agreement with BSC. This Cooperative Agreement requires BSC to develop and conduct an Environmental Monitoring Plan (EMP) for the Clean Coal Technology project and to report the status of the EMP on a quarterly basis. This report is the third quarterly status report of the EMP. It covers the Environmental Monitoring Plan activities for the full year of 1991 from January 1, 1991 through December 31, 1991, including the forth quarter. See Sections 2, 3 and 4 for status reports of the Project Installation and Commissioning, the Environmental Monitoring activities and the Compliance Monitoring results for the period. Section 5 contains a list of Compliance Reports submitted to regulatory agencies during the period. The EMP describes in detail the environmental monitoring activities to be performed during the project execution. The purpose of the EMP is to: (1) document the extent of compliance of monitoring activities, i.e. those monitoring required to meet permit requirements, (2) confirm the specific impacts predicted in the National Environmental Policy Act documentation, and (3) establish an information base for the assessment of the environmental performance of the technology demonstrated by the project.

  17. Process for the elimination of waste water produced upon the desulfurization of coking oven gas by means of wash solution containing organic oxygen-carrier, with simultaneous recovery of elemental sulfur

    SciTech Connect (OSTI)

    Diemer, P.; Brake, W.; Dittmer, R.

    1985-04-16T23:59:59.000Z

    A process is disclosed for the elimination of waste water falling out with the desulfurization of coking oven gas by means of an organic oxygen carrier-containing washing solution with simultaneous recovery of elemental sulfur. The waste water is decomposed in a combustion chamber in a reducing atmosphere at temperatures between about 1000/sup 0/ and 1100/sup 0/ C. under such conditions that the mole ratio of H/sub 2/S:SO/sub 2/ in the exhaust gas of the combustion chamber amounts to at least 2:1. Sulfur falling out is separated and the sensible heat of the exhaust gas is utilized for steam generation. The cooled and desulfurized exhaust gas is added to the coking oven gas before the pre-cooling. Sulfur falling out from the washing solution in the oxidizer is separated out and lead into the combustion chamber together with the part of the washing solution discharged as waste water from the washing solution circulation. Preferred embodiments include that the sulfur loading of the waste water can amount to up to about 370 kg sulfur per m/sup 3/ waste water; having the cooling of sulfur-containing exhaust gas leaving the combustion chamber follow in a waste heat boiler and a sulfur condenser heated by pre-heated boiler feed water, from which condenser sulfur is discharged in liquid state.

  18. Prolongation technologies for campaign life of tall oven

    SciTech Connect (OSTI)

    Doko, Yoshiji; Saji, Takafumi; Kitayama, Yoshiteru; Yoshida, Shuhei [Sumitomo Metal Industries, Ltd., Kashima, Ibaraki (Japan). Kashima Steel Works

    1997-12-31T23:59:59.000Z

    In Kashima Steel Works, 25-year-old 7-meter-high coke ovens have damage on their walls. However, by using new methods of internal in-situ investigation, ceramic welding for the extended central and upper portions of coke ovens has prolonged the campaign life for over 40 years without large-scale hot repair. In this paper, introduction of these new methods, its application in Kashima and the policy of repairing the tall coke oven are reported.

  19. Coke oven air and water pollution. 1970-June, 1981 (citations from the Engineering Index Data Base). Report for 1970-Jun 81

    SciTech Connect (OSTI)

    Not Available

    1981-07-01T23:59:59.000Z

    Monitoring, sampling, analyzing, transport properties, and control of emissions and effluents are cited in this compilation from worldwide journals. Pollutants described are sulfur dioxide, hydrogen sulfide, ammonia, phenols, benzopyrene, particulates and other trace elements and compounds. Process and equipment modifications, such as pipeline charging, wet and dry quenching, retrofitting, and oven leakage preventives are included. (This updated bibliography contains 210 citations, 9 of which are new entries to the previous edition.)

  20. Simulation of industrial coking -- Phase 1

    SciTech Connect (OSTI)

    Todoschuk, T.W.; Price, J.T.; Gransden, J.F.

    1997-12-31T23:59:59.000Z

    Two statistically designed experimental programs using an Appalachian and a Western Canadian coal blend were run in CANMET`s 460mm (18 inch) movable wall oven. Factors included coal grind, moisture, oil addition, carbonization rate and final coke temperature. Coke quality parameters including CSR, coal charge characteristics and pressure generation were analyzed.

  1. Clean Production of Coke from Carbonaceous Fines

    SciTech Connect (OSTI)

    Craig N. Eatough

    2004-11-16T23:59:59.000Z

    In order to produce steel (a necessary commodity in developed nations) using conventional technologies, you must have metallurgical coke. Current coke-making technology pyrolyzes high-quality coking coals in a slot oven, but prime coking coals are becoming more expensive and slot ovens are being shut-down because of age and environmental problems. The United States typically imports about 4 million tons of coke per year, but because of a world-wide coke scarcity, metallurgical coke costs have risen from about $77 per tonne to more than $225. This coke shortage is a long-term challenge driving up the price of steel and is forcing steel makers to search for alternatives. Combustion Resources (CR) has developed a technology to produce metallurgical coke from alternative feedstocks in an environmentally clean manner. The purpose of the current project was to refine material and process requirements in order to achieve improved economic benefits and to expand upon prior work on the proposed technology through successful prototype testing of coke products. The ultimate objective of this project is commercialization of the proposed technology. During this project period, CR developed coke from over thirty different formulations that meet the strength and reactivity requirements for use as metallurgical coke. The technology has been termed CR Clean Coke because it utilizes waste materials as feedstocks and is produced in a continuous process where pollutant emissions can be significantly reduced compared to current practice. The proposed feed material and operating costs for a CR Clean Coke plant are significantly less than conventional coke plants. Even the capital costs for the proposed coke plant are about half that of current plants. The remaining barrier for CR Clean Coke to overcome prior to commercialization is full-scale testing in a blast furnace. These tests will require a significant quantity of product (tens of thousands of tons) necessitating the construction of a demonstration facility. Talks are currently underway with potential partners and investors to build a demonstration facility that will generate enough coke for meaningful blast furnace evaluation tests. If the testing is successful, CR Clean Coke could potentially eliminate the need for the United States to import any coke, effectively decreasing US Steel industry dependence on foreign nations and reducing the price of domestic steel.

  2. Collector main replacement at Indianapolis Coke

    SciTech Connect (OSTI)

    Sickle, R.R. Van

    1997-12-31T23:59:59.000Z

    Indianapolis Coke is a merchant coke producer, supplying both foundry and blast furnace coke to the industry. The facility has three coke batteries: two 3 meter batteries, one Wilputte four divided and one Koppers Becker. Both batteries are underjet batteries and are producing 100% foundry coke at a net coking time of 30.6 hours. This paper deals with the No. 1 coke battery, which is a 72 oven, gun fired, 5 meter Still battery. No. 1 battery produces both foundry and blast furnace coke at a net coking rate of 25.4 hours. No. 1 battery was commissioned in 1979. The battery is equipped with a double collector main. Although many renovations have been completed to the battery, oven machinery and heating system, to date no major construction projects have taken place. Deterioration of the collector main was caused in part from elevated levels of chlorides in the flushing liquor, and temperature fluctuations within the collector main. The repair procedures are discussed.

  3. Method of operating a coal predrying and heating plant in connection with a coking plant

    SciTech Connect (OSTI)

    Bocsanczy, J.; Knappstein, J.; Stalherm, D.

    1981-01-27T23:59:59.000Z

    A method of preparing and delivering coal to a coking plant comprises conveying the coal to the plant on a moving conveyor while an inert combustion gas is directed over the coal being conveyed. The combustion gas is generated by burning a fuel with air to produce a substantially inert combustion gas which is passed over the coal during its conveying and, thereafter, passed through a cooler for removing the moisture which has been picked up from the coal by the gas. The heating and predrying inert gases are advantageously generated by the direct combustion of air and fuel which are passed through flash dryer tubes and one or more separate separator systems and then delivered into a conveyor pipeline through which the coal is conveyed. A portion of the gases which are generated are also directed with a return gas to a filter for removal of any coal therefrom and to a cooler for removing the moisture picked up from the coal and then back into the stream for delivery to the conveyor for the coal. The inert gas may also be a gas which is circulated in heat exchange relationship with combustion gases which are generated by a combustion of the coal itself. In such a system, a portion of the combustion gases generated are also passed through a condenser or cooler and the cooled and dried waste gases are circulated over the coal being conveyed to the coking oven or its bunkers.

  4. Unmanned operation of the coke guides at Hoogovens IJmuiden Coke Plant 1

    SciTech Connect (OSTI)

    Vos, D.; Mannes, N.; Poppema, B. [Hoogovens IJmuiden B.V. (Netherlands)

    1995-12-01T23:59:59.000Z

    Due to the bad condition of batteries and many ovens under repair, Hoogovens was forced to partially repair and rebuild the Coke plant No. 1. The production of coke at Coke plant No. 1 is realized in 3 production blocks subdivided in 6 batteries. Besides a renovated installation, all coke oven machines were renewed. A total of five identical machine sets are available. Each consists of a pusher machine, larry car, coke guide and quench car with diesel locomotive. A complete automated control system was implemented. The main objectives were a highly regular coking and pushing process, automated traveling and positioning and a centrally coordinated interlocking of machine functions. On each operational machine however an operator performed the supervisory control of the automated machine functions. After years of good experience with the automated system, economical reasons urged further personnel reduction from 1994 on. Totally 375 people were involved, including the maintenance department. To reduce the occupation at coke plant No. 1, the coke guide was the first machine to be fully automated because of the isolated and uncomfortable working place.

  5. VACASULF operation at Citizens Gas and Coke Utility

    SciTech Connect (OSTI)

    Currey, J.H. [Citizens Gas and Coke Utility, Indianapolis, IN (United States)

    1995-12-01T23:59:59.000Z

    Citizens Gas and Coke Utility is a Public Charitable Trust which operates as the Department of Utilities of the City of Indianapolis, Indiana. Indianapolis Coke, the trade name for the Manufacturing Division of the Utility, operates a by-products coke plant in Indianapolis, Indiana. The facility produces both foundry and blast furnace coke. Surplus Coke Oven gas, generated by the process, is mixed with Natural Gas for sale to industrial and residential customers. In anticipation of regulatory developments, beginning in 1990, Indianapolis Coke undertook the task to develop an alternate Coke Oven Gas desulfurization technology for its facility. The new system was intended to perform primary desulfurization of the gas, dramatically extending the oxide bed life, thus reducing disposal liabilities. Citizens Gas chose the VACASULF technology for its primary desulfurization system. VACASULF requires a single purchased material, Potassium Hydroxide (KOH). The KOH reacts with Carbon Dioxide in the coke Oven Gas to form Potassium Carbonate (potash) which in turn absorbs the Hydrogen Sulfide. The rich solution releases the absorbed sulfide under strong vacuum in the desorber column. Operating costs are reduced through utilization of an inherent heat source which is transferred indirectly via attendant reboilers. The Hydrogen Sulfide is transported by the vacuum pumps to the Claus Kiln and Reactor for combustion, reaction, and elemental Sulfur recovery. Regenerated potash solution is returned to the Scrubber.

  6. The waste water free coke plant

    SciTech Connect (OSTI)

    Schuepphaus, K.; Brink, N. [Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany)

    1995-12-01T23:59:59.000Z

    Apart from coke which is the actual valuable material a coke oven plant also produces a substantial volume of waste water. These effluent water streams are burdened with organic components (e.g. phenols) and inorganic salts (e.g. NH{sub 4}Cl); due to the concentration of the constituents contained therein these effluent waters must be subjected to a specific treatment before they can be introduced into public waters. For some years a lot of separation tasks have been solved successfully by applying the membrane technology. It was especially the growing number of membrane facilities for cleaning of landfill leakage water whose composition can in fact be compared with that of coking plant waste waters (organic constituents, high salt fright, ammonium compounds) which gave Thyssen Still Otto Anlagentechnik the idea for developing a process for coke plant effluent treatment which contains the membrane technology as an essential component.

  7. Priorities in the design of chemical shops at coke plants

    SciTech Connect (OSTI)

    V.I. Rudyka; Y.E. Zingerman; V.V. Grabko; L.A. Kazak [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Recent trends in the design of chemical equipment at coke plants are described, through the lens of experience at Giprokoks. The main priorities were to improve the removal of impurities from coke oven gas; to improve equipment design on the basis of new materials; to reduce reagent consumption; to reduce the materials and energy consumed in the construction of new equipment; and to minimize impacts on the environment and worker health. Some technological equipment is briefly characterized.

  8. Coke battery with 51-m{sup 3} furnace chambers and lateral supply of mixed gas

    SciTech Connect (OSTI)

    V.I. Rudyka; N.Y. Chebotarev; O.N. Surenskii; V.V. Derevich [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The basic approaches employed in the construction of coke battery 11A at OAO Magnitogorskii Metallurgicheskii Kombinat are outlined. This battery includes 51.0-m{sup 3} furnaces and a dust-free coke-supply system designed by Giprokoks with lateral gas supply; it is heated exclusively by low-calorific mixed gas consisting of blast-furnace gas with added coke-oven gas. The 82 furnaces in the coke battery are divided into two blocks of 41. The gross coke output of the battery (6% moisture content) is 1140000 t/yr.

  9. Cyanide treatment options in coke plants

    SciTech Connect (OSTI)

    Minak, H.P.; Lepke, P. [Krupp Uhde GmbH, Dortmund (Germany)

    1997-12-31T23:59:59.000Z

    The paper discusses the formation of cyanides in coke oven gas and describes and compares waste processing options. These include desulfurization by aqueous ammonia solution, desulfurization using potash solution, desulfurization in oxide boxes, decomposition of NH{sub 3} and HCN for gas scrubbing. Waste water treatment methods include chemical oxidation, precipitation, ion exchange, reverse osmosis, and biological treatment. It is concluded that biological treatment is the most economical process, safe in operation and requires a minimum of manpower.

  10. The new Kaiserstuhl coking plant: The heating system -- Design, construction and initial operating experience

    SciTech Connect (OSTI)

    Strunk, J.

    1996-12-31T23:59:59.000Z

    At the end of 1992 the new coke plant Kaiserstuhl in Dortmund/Germany with presently the largest coke ovens world-wide started its production operation in close linkage to the Krupp-Hoesch Metallurgical Works after about 35 months construction time. This plant incorporating comprehensive equipment geared to improve environmental protection is also considered as the most modern coke plant of the world. The heating-system and first results of operation will be presented.

  11. Process for removing hydrogen sulfide from gases particularly coal pyrolysis gases

    SciTech Connect (OSTI)

    Ritter, H.; Herpers, E.T.

    1985-02-12T23:59:59.000Z

    Hydrogen sulfide is first removed by ammoniacal liquor from coke oven gas in the bottom part of a gas scrubber. In the top part of the scrubber, two consecutively-arranged fine scrubbing stages remove hydrogen sulfide by treating the gases, in the upper stage, with a caustic soda solution or a caustic potash solution. Beneath the upper scrubbing stage is the second fine scrubbing stage fed with a subflow of an aqueous carbonate solution collecting at the outlet of the upper fine scrubbing stage and a subflow of cooled, regenerated carbonate solution discharged from the hydrogen-sulfide/hydrogen-cyanide stripper. From the hydrogen-sulfide/hydrogen-cyanide stripper, a second subflow is admixed with coal liquor for removing fixed ammonia therefrom in a separator. The separator produces water vapor with carbon dioxide vapors that are delivered to the hydrogen-sulfide/hydrogen-cyanide stripper for regenerating the aqueous carbonate washing solution.

  12. Gas treatment and by-products recovery of Thailand`s first coke plant

    SciTech Connect (OSTI)

    Diemer, P.E.; Seyfferth, W. [Krupp Uhde GmbH, Dortmund (Germany)

    1997-12-31T23:59:59.000Z

    Coke is needed in the blast furnace as the main fuel and chemical reactant and the main product of a coke plant. The second main product of the coke plant is coke oven gas. During treatment of the coke oven gas some coal chemicals like tar, ammonia, sulphur and benzole can be recovered as by-products. Since the market prices for these by-products are rather low and often erratic it does not in most cases justify the investment to recover these products. This is the reason why modern gas treatment plants only remove those impurities from the crude gas which must be removed for technical and environmental reasons. The cleaned gas, however, is a very valuable product as it replaces natural gas in steel work furnaces and can be used by other consumers. The surplus can be combusted in the boiler of a power plant. A good example for an optimal plant layout is the new coke oven facility of Thai Special Steel Industry (TSSI) in Rayong. The paper describes the TSSI`s coke oven gas treatment plant.

  13. Operating and maintenance benefits of automated oven wall temperature measurement

    SciTech Connect (OSTI)

    Leuchtmann, K.P. [Thyssen Still Otto Anlagentechnik GmbH, Bochum (Germany); Hinz, D.; Bergbau, D. [Ruhrkohle Bergbau AG, Bottrop (Germany). Prosper Coking Plant; Platts, M. [Thyssen Still Otto Technical Services, Pittsburgh, PA (United States)

    1997-12-31T23:59:59.000Z

    For a very long time and regardless of all shortcomings associated with it, the manual measurement of the heating flue temperature has been the only method of monitoring the temperature prevailing in a coke oven battery and discovering weak points in the heating system. In the course of the last few years a number of automated temperature measuring systems have been developed that are intended to replace or supplement the manual heating flue measurement system. These measuring systems and their advantages/disadvantages are briefly described in this paper. Additionally, operational experience gathered with the oven chamber wall temperature measuring system is discussed in detail.

  14. Innovative coke oven gas cleaning system for retrofit applications

    SciTech Connect (OSTI)

    Not Available

    1992-09-21T23:59:59.000Z

    The EMP consists of a Compliance Monitoring Sampling Program and a Supplemental monitoring Sampling Program. The Compliance Monitoring Sampling Program will be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Project and during a summer and a winter period following the successful Startup and Operational phase of the completed Project. compliance monitoring consist of conducting all the sampling and observation programs associated with existing required Federal, State, and Local Regulations, Permits and Orders. These include air, water, and waste monitoring and OSHA and NESHAP monitoring. The Supplemental Monitoring Program will also be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Demonstration Facility and during a summer and a winter period following the successful startup and Operational phase of the completed Facility. Supplemental Monitoring includes sampling of 27 additional streams that are important to measure operational or environmental performance and impacts of the installation of the new COG treatment facilities.

  15. Innovative coke oven gas cleaning system for retrofit applications

    SciTech Connect (OSTI)

    Not Available

    1990-09-10T23:59:59.000Z

    All of the project work since the previous report has been on Phase 2B tasks. Therefore, this quarterly progress report summarizes the period's activities in Engineering, Procurement and Civil Construction. Engineering is 95% complete, but revisions and changes are still being incorporated particularly in the Instrument and Electrical areas. Procurement has only valves 4 in. and above yet to order to complete all major items purchased. The scheduled material curve was based on the original estimate of the job. The projected curve reflects the previous month's estimate. Construction of civil work is proceeding according to schedule in the field. The initial bid packages for the Mechanical General Contractor portion of the work have been reviewed and evaluated. Order placement is scheduled for the end of July. The Electrical package is due back from the bidders on July 6. It requires additional evaluation by BSC and DSO and will not be placed until late August. The cost of the project is ahead of the cost or spending plan because of the accelerated progress in the field and early delivery of equipment. However, there are some concerns that the mechanical and electrical bid packages are higher than planned. Although we plan to determine the causes of the increases, we do not intend to let it effect the progress of the project. 7 figs.

  16. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2004-09-26T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  17. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk; Keith Wisecarver

    2003-09-26T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking.

  18. Design, construction and start-up of a modern coke plant

    SciTech Connect (OSTI)

    Williams, A.E.

    1983-05-01T23:59:59.000Z

    The planning and design of a 60-oven, 6m replacement coke battery and associated by-products plant for Republic Steel Corp, Chicago, are described together with the constructional methods used and problems experienced through start-up of the facility. Pushing emission control is achieved with a Mitsubishi-type land-based system and changing emission control with a Nippon Steel combination car and land-based system. A Takahax-Hirohax coke-oven gas desulphurization unit is included in the by-product plant. Construction began in March 1979 with the first push in December 1981.

  19. Blast furnace coke quality in relation to petroleum coke addition

    SciTech Connect (OSTI)

    Alvarez, R.; Diez, M.A.; Menendez, J.A.; Barriocanal, C.; Pis, J.J. [CSIC, Oviedo (Spain). Inst. Nacional del Carbon; Sirgado, M. [ENSIDESA, Aviles (Spain)

    1995-12-01T23:59:59.000Z

    The incorporation of petroleum coke as an additive in industrial coking coal blends is a practice often used by steel companies. A suitable blast furnace coke produced by replacing part of the coking coal blend with a suitable petroleum coke (addition of 5 to 15%), was made by Great Lakes Carbon Corporation and successfully tested at several blast furnaces. This coke had lower reactivity, less ash and slightly higher sulfur content than coke made without the addition of petroleum coke. In contrast with these results, it has been reported in a BCRA study that additions of petroleum coke to a strong coking coal, above 5 wt%, increased coke reactivity. These differences may be explained on the basis of the coal or blend characteristics to which petroleum coke is added. Petroleum coke addition seems to give better results if the coal/blend has high fluidity. The present situation in Spain is favorable for the use of petroleum coke. So, a study of laboratory and semi-industrial scale was made to assess the possibility of using petroleum coke as an additive to the typical industrial coal blend coked by the Spanish Steel Company, ENSIDESA. The influence of the petroleum coke particle size was also studied to semi-industrial scale.

  20. Western Canadian coking coals -- Thermal rheology and coking quality

    SciTech Connect (OSTI)

    Leeder, W.R. [Teck Corp. (Canada); Price, J.T.; Gransden, J.F. [CANMET Energy Technology Centre, Ottawa, Ontario (Canada)

    1997-12-31T23:59:59.000Z

    Methods of predicting coke strength developed from the thermal rheological properties of Carboniferous coals frequently indicate that Cretaceous coals would not make high quality coke -- yet both types of coals produce coke suitable for the iron blast furnace. This paper will discuss the reasons why Western Canadian coals exhibit lower rheological values and how to predict the strength of coke produced from them.

  1. Integration of stripping of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1980-01-01T23:59:59.000Z

    In an integrated fluid coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a wet scrubbing process and wherein the resulting solids-liquid slurry is stripped to remove acidic gases, the stripped vapors of the stripping zone are sent to the gas cleanup stage of the gasification product gas. The improved stripping integration is particularly useful in the combination coal liquefaction process, fluid coking of bottoms of the coal liquefaction zone and gasification of the product coke.

  2. Met coke world summit 2005

    SciTech Connect (OSTI)

    NONE

    2005-07-01T23:59:59.000Z

    Papers are presented under the following session headings: industry overview and market outlook; coke in the Americas; the global coke industry; and new developments. All the papers (except one) only consist of a copy of the overheads/viewgraphs.

  3. Coking and gasification process

    DOE Patents [OSTI]

    Billimoria, Rustom M. (Houston, TX); Tao, Frank F. (Baytown, TX)

    1986-01-01T23:59:59.000Z

    An improved coking process for normally solid carbonaceous materials wherein the yield of liquid product from the coker is increased by adding ammonia or an ammonia precursor to the coker. The invention is particularly useful in a process wherein coal liquefaction bottoms are coked to produce both a liquid and a gaseous product. Broadly, ammonia or an ammonia precursor is added to the coker ranging from about 1 to about 60 weight percent based on normally solid carbonaceous material and is preferably added in an amount from about 2 to about 15 weight percent.

  4. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Michael Volk Jr; Keith Wisecarver

    2005-10-01T23:59:59.000Z

    Delayed coking evolved steadily over the early to mid 1900s to enable refiners to convert high boiling, residual petroleum fractions to light products such as gasoline. Pound for pound, coking is the most energy intensive of any operation in a modern refinery. Large amounts of energy are required to heat the thick, poor-quality petroleum residuum to the 900 to 950 degrees F required to crack the heavy hydrocarbon molecules into lighter, more valuable products. One common misconception of delayed coking is that the product coke is a disadvantage. Although coke is a low valued (near zero economic value) byproduct, compared to transportation fuels, there is a significant worldwide trade and demand for coke as it is an economical fuel. Coke production has increased steadily over the last ten years, with further increases forecast for the foreseeable future. Current domestic production is near 111,000 tons per day. A major driving force behind this increase is the steady decline in crude quality available to refiners. Crude slates are expected to grow heavier with higher sulfur contents while environmental restrictions are expected to significantly reduce the demand for high-sulfur residual fuel oil. Light sweet crudes will continue to be available and in even greater demand than they are today. Refiners will be faced with the choice of purchasing light sweet crudes at a premium price, or adding bottom of the barrel upgrading capability, through additional new investments, to reduce the production of high-sulfur residual fuel oil and increase the production of low-sulfur distillate fuels. A second disadvantage is that liquid products from cokers frequently are unstable, i.e., they rapidly form gum and sediments. Because of intermediate investment and operating costs, delayed coking has increased in popularity among refiners worldwide. Based on the 2000 Worldwide Refining Survey published in the Oil and Gas, the delayed coking capacity for 101 refineries around the world is 2,937,439 barrels/calendar day. These cokers produce 154,607 tons of coke per day and delayed coking accounts for 88% of the world capacity. The delayed coking charge capacity in the United States is 1,787,860 b/cd. Despite its wide commercial use, only relatively few contractors and refiners are truly knowledgeable in delayed-coking design, so that this process carries with it a ''black art'' connotation. Until recently, the expected yield from cokers was determined by a simple laboratory test on the feedstock. As a result of Tulsa University's prior related research, a process model was developed that with additional work could be used to optimize existing delayed cokers over a wide range of potential feedstocks and operating conditions. The objectives of this research program are to: utilize the current micro, batch and pilot unit facilities at The University of Tulsa to enhance the understanding of the coking process; conduct additional micro and pilot unit tests with new and in-house resids and recycles to make current optimization models more robust; conduct focused kinetic experiments to enhance the furnace tube model and to enhance liquid production while minimizing sulfur in the products; conduct detailed foaming studies to optimize the process and minimize process upsets; quantify the parameters that affect coke morphology; and to utilize the knowledge gained from the experimental and modeling studies to enhance the computer programs developed in the previous JIP for optimization of the coking process. These refined computer models will then be tested against refinery data provided by the member companies. Novel concepts will also be explored for hydrogen sulfide removal of furnace gases as well as gas injection studies to reduce over-cracking. The following deliverables are scheduled from the two projects of the three-year JIP: (1) A novel method for enhancing liquid yields from delayed cokers and data that provide insight as to the optimum temperature to remove hydrogen sulfide from furnace gases. (2) An understanding of what causes foaming in c

  5. Survey and assessment of the effects of nonconventional gases on gas distribution equipment

    SciTech Connect (OSTI)

    Jasionowski, W.J.; Scott, M.I.; Gracey, W.C.

    1982-10-01T23:59:59.000Z

    A literature search and a survey of the gas industry were conducted to assess potential problems in the distribution of nonconventional gases. Available literature did not uncover data that would describe potential problems or substantiate the presence of harmful trace elements in final gas compositions produced from various SNG processes. Information from the survey indicates that some companies have encountered problems with nonconventional gases and extraneous additives such as landfill gas, refinery off-gases, oil gas, carbureted water gas, coke-oven gas, propane-air, and compressor lubricant oils. These nonconventional gases and compressor oils may 1) cause pipeline corrosion, 2) degrade some elastomeric materials and greases and affect the integrity of seals, gaskets, O-rings, and meter and regulator diaphragms, and 3) cause operational and safety problems. The survey indicated that 62% of the responding companies plan to use supplemental gas, with most planning on more than one type. Distribution companies intend to significantly increase their use of polyethylene piping from 11.6% in 1980 to 22.4% in 2000 for gas mains and from 33.4% to 50.3% in 2000 for gas service lines.

  6. High coking value pitch

    SciTech Connect (OSTI)

    Miller, Douglas J.; Chang, Ching-Feng; Lewis, Irwin C.; Lewis, Richard T.

    2014-06-10T23:59:59.000Z

    A high coking value pitch prepared from coal tar distillate and has a low softening point and a high carbon value while containing substantially no quinoline insolubles is disclosed. The pitch can be used as an impregnant or binder for producing carbon and graphite articles.

  7. Oven wall panel construction

    DOE Patents [OSTI]

    Ellison, Kenneth (20 Avondale Cres., Markham, CA); Whike, Alan S. (R.R. #1, Caledon East, both of Ontario, CA)

    1980-04-22T23:59:59.000Z

    An oven roof or wall is formed from modular panels, each of which comprises an inner fabric and an outer fabric. Each such fabric is formed with an angle iron framework and somewhat resilient tie-bars or welded at their ends to flanges of the angle irons to maintain the inner and outer frameworks in spaced disposition while minimizing heat transfer by conduction and permitting some degree of relative movement on expansion and contraction of the module components. Suitable thermal insulation is provided within the module. Panels or skins are secured to the fabric frameworks and each such skin is secured to a framework and projects laterally so as slidingly to overlie the adjacent frame member of an adjacent panel in turn to permit relative movement during expansion and contraction.

  8. Design and construction of coke battery 1A at Radlin coke plant, Poland

    SciTech Connect (OSTI)

    A.M. Kravchenko; D.P. Yarmoshik; V.B. Kamenyuka; G.E. Kos'kova; N.I. Shkol'naya; V.V. Derevich; A.S. Grankin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    In the design and construction of coke battery 1A at Radlin coke plant (Poland), coking of rammed coke with a stationary system was employed for the first time. The coke batteries are grouped in blocks. Safety railings are provided on the coke and machine sides of the maintenance areas.

  9. Light oil yield improvement project at Granite City Division Coke/By-Product Plant

    SciTech Connect (OSTI)

    Holloran, R.A. [National Steel Corp., Granite City, IL (United States). Granite City Div.

    1995-12-01T23:59:59.000Z

    Light oil removal from coke oven gas is a process that has long been proven and utilized throughout many North American Coke/By-Products Plants. The procedures, processes, and equipment requirements to maximize light oil recovery at the Granite City By-Products Plant will be discussed. The Light Oil Yield Improvement Project initially began in July, 1993 and was well into the final phase by February, 1994. Problem solving techniques, along with utilizing proven theoretical recovery standards were applied in this project. Process equipment improvements and implementation of Operator/Maintenance Standard Practices resulted in an average yield increase of 0.4 Gals./NTDC by the end of 1993.

  10. COKEMASTER: Coke plant management system

    SciTech Connect (OSTI)

    Johanning, J.; Reinke, M. [Krupp Koppers GmbH, Essen (Germany)

    1996-12-31T23:59:59.000Z

    To keep coke utilization in ironmaking as competitive as possible, the potential to improve the economics of coke production has to be utilized. As one measure to meet this need of its customers, Krupp Koppers has expanded its existing ECOTROL computer system for battery heating control to a comprehensive Coke Plant Management System. Increased capacity utilization, lower energy consumption, stabilization of plant operation and ease of operation are the main targets.

  11. Ovenized microelectromechanical system (MEMS) resonator

    DOE Patents [OSTI]

    Olsson, Roy H; Wojciechowski, Kenneth; Kim, Bongsang

    2014-03-11T23:59:59.000Z

    An ovenized micro-electro-mechanical system (MEMS) resonator including: a substantially thermally isolated mechanical resonator cavity; a mechanical oscillator coupled to the mechanical resonator cavity; and a heating element formed on the mechanical resonator cavity.

  12. Cryogenic fractionator gas as stripping gas of fines slurry in a coking and gasification process

    DOE Patents [OSTI]

    DeGeorge, Charles W. (Chester, NJ)

    1981-01-01T23:59:59.000Z

    In an integrated coking and gasification process wherein a stream of fluidized solids is passed from a fluidized bed coking zone to a second fluidized bed and wherein entrained solid fines are recovered by a scrubbing process and wherein the resulting solids-liquid slurry is stripped with a stripping gas to remove acidic gases, at least a portion of the stripping gas comprises a gas comprising hydrogen, nitrogen and methane separated from the coker products.

  13. Coke from coal and petroleum

    DOE Patents [OSTI]

    Wynne, Jr., Francis E. (Allison Park, PA); Lopez, Jaime (Pittsburgh, PA); Zaborowsky, Edward J. (Harwick, PA)

    1981-01-01T23:59:59.000Z

    A carbonaceous coke is manufactured by the delayed coking of a slurry mixture of from about 10 to about 30 weight percent of caking or non-caking coal and the remainder a petroleum resid blended at below 50.degree. C.

  14. Convection automated logic oven control

    SciTech Connect (OSTI)

    Boyer, M.A.; Eke, K.I. [Apollo U.S.A. Inc., Orlando, FL (United States)] [Apollo U.S.A. Inc., Orlando, FL (United States)

    1998-03-01T23:59:59.000Z

    For the past few years, there has been a greater push to bring more automation to the cooling process. There have been attempts at automated cooking using a wide range of sensors and procedures, but with limited success. The authors have the answer to the automated cooking process; this patented technology is called Convection AutoLogic (CAL). The beauty of the technology is that it requires no extra hardware for the existing oven system. They use the existing temperature probe, whether it is an RTD, thermocouple, or thermistor. This means that the manufacturer does not have to be burdened with extra costs associated with automated cooking in comparison to standard ovens. The only change to the oven is the program in the central processing unit (CPU) on the board. As for its operation, when the user places the food into the oven, he or she is required to select a category (e.g., beef, poultry, or casseroles) and then simply press the start button. The CAL program then begins its cooking program. It first looks at the ambient oven temperature to see if it is a cold, warm, or hot start. CAL stores this data and then begins to look at the food`s thermal footprint. After CAL has properly detected this thermal footprint, it can calculate the time and temperature at which the food needs to be cooked. CAL then sets up these factors for the cooking stage of the program and, when the food has finished cooking, the oven is turned off automatically. The total time for this entire process is the same as the standard cooking time the user would normally set. The CAL program can also compensate for varying line voltages and detect when the oven door is opened. With all of these varying factors being monitored, CAL can produce a perfectly cooked item with minimal user input.

  15. Solar Oven, Take One: FAIL | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Solar Oven, Take One: FAIL Solar Oven, Take One: FAIL June 15, 2011 - 11:56am Addthis Our homemade solar oven. | Courtesy of Moon Choe Our homemade solar oven. | Courtesy of Moon...

  16. New coke-sorting system at OAO Koks

    SciTech Connect (OSTI)

    B.Kh. Bulaevskii; V.S. Shved; Yu.V. Kalimin; S.D. Filippov [OAO Koks, Kemerovo (Russian Federation)

    2009-05-15T23:59:59.000Z

    A new coke-sorting system has been introduced at OAO Koks. It differs from the existing system in that it has no bunkers for all-purpose coke but only bunkers for commercial coke. In using this system with coke from battery 4, the crushing of the coke on conveyer belts, at roller screens, and in the commercial-coke bunkers is studied. After installing braking elements in the coke path, their effectiveness in reducing coke disintegration and improving coke screening is investigated. The granulometric composition and strength of the commercial coke from coke battery 3, with the new coke-sorting system, is evaluated.

  17. Proposal of a novel multifunctional energy system for cogeneration of coke, hydrogen, and power - article no. 052001

    SciTech Connect (OSTI)

    Jin, H.G.; Sun, S.; Han, W.; Gao, L. [Chinese Academy of Sciences, Beijing (China)

    2009-09-15T23:59:59.000Z

    This paper proposes a novel multifunctional energy system (MES), which cogenerates coke, hydrogen, and power, through the use of coal and coke oven gas (COG). In this system, a new type of coke oven, firing coal instead of COG as heating resource for coking, is adopted. The COG rich in H{sub 2} is sent to a pressure swing adsorption (PSA) unit to separate about 80% of hydrogen first, and then the PSA purge gas is fed to a combined cycle as fuel. The new system combines the chemical processes and power generation system, along with the integration of chemical conversion and thermal energy utilization. In this manner, both the chemical energy of fuel and thermal energy can be used more effectively. With the same inputs of fuel and the same output of coking heat, the new system can produce about 65% more hydrogen than that of individual systems. As a result, the thermal efficiency of the new system is about 70%, and the exergy efficiency is about 66%. Compared with individual systems, the primary energy saving ratio can reach as high as 12.5%. Based on the graphical exergy analyses, we disclose that the integration of synthetic utilization of COG and coal plays a significant role in decreasing the exergy destruction of the MES system. The promising results obtained may lead to a clean coal technology that will utilize COG and coal more efficiently and economically.

  18. Biological production of products from waste gases

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    2002-01-22T23:59:59.000Z

    A method and apparatus are designed for converting waste gases from industrial processes such as oil refining, and carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various products, such as organic acids, alcohols, hydrogen, single cell protein, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  19. Trends in the automation of coke production

    SciTech Connect (OSTI)

    R.I. Rudyka; Y.E. Zingerman; K.G. Lavrov [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Up-to-date mathematical methods, such as correlation analysis and expert systems, are employed in creating a model of the coking process. Automatic coking-control systems developed by Giprokoks rule out human error. At an existing coke battery, after introducing automatic control, the heating-gas consumption is reduced by {>=}5%.

  20. Ammonia removal process upgrade to the Acme Steel Coke Plant

    SciTech Connect (OSTI)

    Harris, J.L. [Acme Steel Co., Chicago, IL (United States). Chicago Coke Plant

    1995-12-01T23:59:59.000Z

    The need to upgrade the ammonia removal process at the Acme Steel Coke Plant developed with the installation of the benzene NESHAP (National Emission Standard for Hazardous Air Pollutants) equipment, specifically the replacement of the final cooler. At Acme Steel it was decided to replace the existing open cooling tower type final cooler with a closed loop direct spray tar/water final cooler. This new cooler has greatly reduced the emissions of benzene, ammonia, hydrogen sulfide and hydrogen cyanide to the atmosphere, bringing them into environmental compliance. At the time of its installation it was not fully recognized as to the effect this would have on the coke oven gas composition. In the late seventies the decision had been made at Acme Steel to stop the production of ammonia sulfate salt crystals. The direction chosen was to make a liquid ammonia sulfate solution. This product was used as a pickle liquor at first and then as a liquid fertilizer as more markets were developed. In the fall of 1986 the ammonia still was brought on line. The vapors generated from the operation of the stripping still are directed to the inlet of the ammonia absorber. At that point in time it was decided that an improvement to the cyclical ammonia removal process was needed. The improvements made were minimal yet allowed the circulation of solution through the ammonia absorber on a continuous basis. The paper describes the original batch process and the modifications made which allowed continuous removal.

  1. China's Industrial Carbon Dioxide Emissions in Manufacturing Subsectors and in Selected Provinces

    E-Print Network [OSTI]

    Lu, Hongyou

    2013-01-01T23:59:59.000Z

    Coal Washed Coal Coke Coke Oven Gas Other Gas Other CokingTJ) Coal Coke Coke Oven Gas Other Gas Other Coking Products

  2. Ovens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for RenewableSpeedingBiomass and Biofuels BiomassOutstanding-Long-Term-Liabilities

  3. Use of resin-bearing wastes from coke and coal chemicals production at the Novokuznetsk Metallurgical Combine

    SciTech Connect (OSTI)

    Kul'kova, T.N.; Yablochkin, N.V.; Gal'chenko, A.I.; Karyakina, E.A.; Litvinova, V.A.; Gorbach, D.A.

    2007-03-15T23:59:59.000Z

    The coke and coal chemicals plant at the Novokuznetsk Metallurgical Combine is making trial use of a technology that recycles waste products in 'tar ponds.' Specialists from the Ekomash company have installed a recycling unit in one area of the plant's dump, the unit including an inclined conveyor with a steam heater and a receiving hopper The coal preparation shop receives the wastes in a heated bin, where a screw mixes the wastes with pail of the charge for the coking ovens. The mixture subsequently travels along a moving conveyor belt together with the rest of the charge materials. The addition of up to 2% resin-bearing waste materials to the coal charge has not had any significant effect on the strength properties of the coke.

  4. Cleaning method for removing sulfur containing deposits from coke oven gas lines

    SciTech Connect (OSTI)

    Sumansky, L.W.

    1985-04-09T23:59:59.000Z

    Process for removing hard to remove deposits containing elemental sulfur and multivalent compounds from a surface comprising contacting the deposits with a cleaning composition comprising (a) a major portion of aliphatic amine, (b) water, and (c) an oxidizing or reducing agent, allowing the cleaning composition to remain in contact with the deposits for sufficient time to allow sufficient dissolution of said solid to take place to allow removal of the deposits to take place, and applying such force as is necessary to remove these partially dissolved deposits from the surface. A preferred cleaning composition comprises from about 60 to about 90 volume percent aliphatic amine, from about 10 to about 40 volume percent water, and from about 1 to about 3 weight percent of a moderate oxidizing or reducing agent, such percentages based on the total composition.

  5. Coke cake behavior under compressive forces

    SciTech Connect (OSTI)

    Watakabe, S.; Takeda, T.; Itaya, H.; Suginobe, H.

    1997-12-31T23:59:59.000Z

    The deformation of the coke cake and load on the side wall during pushing were studied using an electric furnace equipped with a movable wall. Coke cake was found to deform in three stages under compressive forces. The coke cake was shortened in the pushing direction in the cake deformation stage, and load was generated on the side walls in the high wall load stage. Secondary cracks in the coke cake were found to prevent load transmission on the wall. The maximum load transmission rate was controlled by adjusting the maximum fluidity and mean reflectance of the blended coal.

  6. Estimating Coke and Pepsi's price and advertising strategies

    E-Print Network [OSTI]

    Golan, Amos; Karp, Larry; Perloff, Jeffrey M.

    1999-01-01T23:59:59.000Z

    No. 789 ESTIMATING COKE AND PEPSI’ PRICE S AND ADVERTISINGAdvertising Strategies: Coke and Pepsi) by Amos Golan, LarryMarch 1999 Estimating Coke and Pepsi’s Price and Advertising

  7. New designs in the reconstruction of coke-sorting systems

    SciTech Connect (OSTI)

    A.S. Larin; V.V. Demenko; V.L. Voitanik [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    In recent Giprokoks designs for the reconstruction of coke-sorting systems, high-productivity vibrational-inertial screens have been employed. This permits single-stage screening and reduction in capital and especially operating expenditures, without loss of coke quality. In two-stage screening, >80 mm coke (for foundry needs) is additionally separated, with significant improvement in quality of the metallurgical coke (25-80 mm). New designs for the reconstruction of coke-sorting systems employ mechanical treatment of the coke outside the furnace, which offers new scope for stabilization of coke quality and permits considerable improvement in mechanical strength and granulometric composition of the coke by mechanical crushing.

  8. Rapid baking characteristics and energy efficiency of an impingement air oven compared to a reel oven

    E-Print Network [OSTI]

    Smith, Lloyd Hobart

    1983-01-01T23:59:59.000Z

    those baked in the reel oven. Buna baked in t h e im pi ngement ove n wer e a pp rex imately 10X smaller in volume. Instron shear force measurements o f the change i n f i rmnes s t h a t r el a te to sta ling showed that the impingement baked buna... isture leve 1 s with in the oven. Modern reel ovens can be heated quickly, have easily adjustable temperature control and have high heat ing e ff ic iency. In 1 975, Smi t h was granted a patent for the "Jet Sweep" air impingement oven in which jets...

  9. Biological production of ethanol from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    2000-01-01T23:59:59.000Z

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products is disclosed. The method includes introducing the waste gases into a bioreactor where they are fermented to various product, such as organic acids, alcohols H.sub.2, SCP, and salts of organic acids by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified.

  10. Heat treatment of exchangers to remove coke

    SciTech Connect (OSTI)

    Turner, J.D.

    1990-02-20T23:59:59.000Z

    This patent describes a process for preparing furfural coke for removal from metallic surfaces. It comprises: heating the furfural coke without causing an evolution of heat capable of undesirably altering metallurgical properties of the surfaces in the presence of a gas containing molecular oxygen at a sufficient temperature below 800{degrees}F (427{degrees}C) for a sufficient time to change the crush strength of the coke so as to permit removal with a water jet at a pressure of five thousand pounds per square inch.

  11. Delayed coking of decant oil and coal in a laboratory-scale coking unit

    SciTech Connect (OSTI)

    Oemer Guel; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University Park, PA (United States). Energy Institute, C205 Coal Utilization Laboratory

    2006-08-15T23:59:59.000Z

    In this paper, we describe the development of a laboratory-scale delayed coker and present results of an investigation on the recovered liquid from the coking of decant oil and decant oil/coal mixtures. Using quantitative gas chromatography/mass spectroscopy (GC/MS) and {sup 1}H and {sup 13}C NMR, a study was made of the chemical composition of the distillate liquids isolated from the overheads collected during the coking and co-coking process. {sup 1}H and {sup 13}C NMR analyses of combined liquids from coking and co-coking did not show any substantial differences. These NMR results of coking and co-coking liquids agree with those of GC/MS. In these studies, it was observed that co-coking with coal resulted in a decrease in the paraffins contents of the liquid. The percentage of cycloparaffins, indenes, naphthalenes, and tetralins did not change significantly. In contrast, alkyl benzenes and polycyclic aromatic hydrocarbons in the distillate were higher in the co-coking experiments which may have resulted from the distillation of thermally cracked coal macromolecules and the contribution of these molecules to the overall liquid composition. 40 refs., 3 figs., 13 tabs.

  12. An example of alkalization of SiO{sub 2} in a blast furnace coke

    SciTech Connect (OSTI)

    S.S. Gornostayev; P.A. Tanskanen; E.-P. Heikkinen; O. Kerkkonen; J.J. Haerkki [University of Oulu, Oulu (Finland). Laboratory of Process Metallurgy

    2007-09-15T23:59:59.000Z

    Scanning electron microscopy and an electron-microprobe analysis of a sample of blast furnace (BF) coke have revealed alkalization (5.64 wt % Na{sub 2}O + K{sub 2}O) and Al saturation (17.28 wt % Al{sub 2}O{sub 3}) of SiO{sub 2} by BF gases. The K/Na{sub at} value of 1.15 in the new phase (alteration zone) reflects close atomic proportions of the elements and suggests that the abilities to incorporate K and Na during the process are almost equal. This Al saturation and alkalization of SiO{sub 2} indicates an active role for Al along with alkali metals in BF gases. The average width of the altered area in the SiO{sub 2} grain is about 10 m, which suggests that SiO{sub 2} particles of that size can be transformed fully to the new phase, provided that at least one of their faces is open to an external pore (surface of the coke) or internal pore with circulating BF gases. The grains that exceed 10 {mu}m can only be partly altered, which means that smaller SiO{sub 2} grains can incorporate more alkali metals and Al (during their transformation to the Al and alkali-bearing phase) than a similar volume of SiO{sub 2} concentrated in larger grains. Thermodynamic calculations for 100 g{sub solid}/100 g{sub gas} and temperatures 800-1800{sup o}C have shown that the BF gases have very little or no effect on the alkalization of SiO{sub 2}. If the alteration process described in this paper proves to be a generalized phenomenon in blast furnace cokes, then the addition of fine-grained quartz to the surface of the coke before charging a BF can be useful for removing of some of the Al and alkali from the BF gases and reduce coke degradation by alkalis, or at least improve its properties until the temperature reaches approximately 2000{sup o}C. 22 refs., 5 figs., 1 tab.

  13. New and revised standards for coke production

    SciTech Connect (OSTI)

    G.A. Kotsyuba; M.I. Alpatov; Y.G. Shapoval [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    The need for new and revised standards for coke production in Ukraine and Russia is outlined. Such standards should address improvements in plant operation, working conditions, environmental protection, energy conservation, fire and explosion safety, and economic indices.

  14. Mozambique becomes a major coking coal exporter?

    SciTech Connect (OSTI)

    Ruffini, A.

    2008-06-15T23:59:59.000Z

    In addition to its potential role as a major international supplier of coking coal, Mozambique will also become a major source of power generation for southern Africa. 3 figs.

  15. Process for treatment of residual gas

    SciTech Connect (OSTI)

    Nolden, K.

    1980-01-01T23:59:59.000Z

    A process is disclosed for the treatment of the residual gases which are produced when hydrogen sulfide is reduced, by combustion, to elementary sulfur by the Claus process. The residual gases are fed through a heated conduit and gas scrubber, wherein the temperature of those residual gases are maintained above the melting point of sulfur. A portion of the raw coke oven gas condensate is admitted to the gas scrubber to be returned to the coke oven battery main from the flushing liquid separator as flushing liquor. The residual gases are then conducted through the coke oven gas purification process equipment along with the raw coke oven gas where the residual gases are intermixed with the raw coke oven gas prior to tar separation.

  16. Giprokoks proposals for improvement in air quality at coke battery 1A of Radlin coke plant

    SciTech Connect (OSTI)

    T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke battery 1A, which uses rammed batch, has gone into production at Radlin coke plant (Poland), on the basis of Giprokoks designs. Up-to-date dust-trapping methods are used for the first time within the aspiration systems in the coal-preparation shop and in improving dust collection within the production buildings.

  17. Development and Testing of the Advanced CHP System Utilizing the Off-Gas from the Innovative Green Coke Calcining Process in Fluidized Bed

    SciTech Connect (OSTI)

    Chudnovsky, Yaroslav; Kozlov, Aleksandr

    2013-08-15T23:59:59.000Z

    Green petroleum coke (GPC) is an oil refining byproduct that can be used directly as a solid fuel or as a feedstock for the production of calcined petroleum coke. GPC contains a high amount of volatiles and sulfur. During the calcination process, the GPC is heated to remove the volatiles and sulfur to produce purified calcined coke, which is used in the production of graphite, electrodes, metal carburizers, and other carbon products. Currently, more than 80% of calcined coke is produced in rotary kilns or rotary hearth furnaces. These technologies provide partial heat utilization of the calcined coke to increase efficiency of the calcination process, but they also share some operating disadvantages. However, coke calcination in an electrothermal fluidized bed (EFB) opens up a number of potential benefits for the production enhancement, while reducing the capital and operating costs. The increased usage of heavy crude oil in recent years has resulted in higher sulfur content in green coke produced by oil refinery process, which requires a significant increase in the calcinations temperature and in residence time. The calorific value of the process off-gas is quite substantial and can be effectively utilized as an “opportunity fuel” for combined heat and power (CHP) production to complement the energy demand. Heat recovered from the product cooling can also contribute to the overall economics of the calcination process. Preliminary estimates indicated the decrease in energy consumption by 35-50% as well as a proportional decrease in greenhouse gas emissions. As such, the efficiency improvement of the coke calcinations systems is attracting close attention of the researchers and engineers throughout the world. The developed technology is intended to accomplish the following objectives: - Reduce the energy and carbon intensity of the calcined coke production process. - Increase utilization of opportunity fuels such as industrial waste off-gas from the novel petroleum coke calcination process. - Increase the opportunity of heat (chemical and physical) utilization from process off-gases and solid product. - Develop a design of advanced CHP system utilizing off-gases as an “opportunity fuel” for petroleum coke calcinations and sensible heat of calcined coke. A successful accomplishment of the aforementioned objectives will contribute toward the following U.S. DOE programmatic goals: - Drive a 25% reduction in U. S. industrial energy intensity by 2017 in support of EPAct 2005; - Contribute to an 18% reduction in U.S. carbon intensity by 2012 as established by the Administration’s “National Goal to Reduce Emissions Intensity.” 8

  18. Investigation of bonding mechanism of coking on semi-coke from lignite with pitch and tar

    SciTech Connect (OSTI)

    Vedat Arslan [Dokuz Eylul University, Izmir (Turkey). Engineering Faculty

    2006-10-15T23:59:59.000Z

    In coking, the bonding ability of inert macerals by reactive macerals is dependent on various parameters and also is related to the wettability of the inert macerals. In this study, the effect of carbonization temperature on the wettability of semi-cokes produced at various temperatures has been investigated. Soma and Yatagan semicokes represent inert macerals, and pitch was used as a reactive structure in the experiments. The briquetted pitch blocks were located on the semi-cokes and heated from the softening temperature of pitch (60{sup o}C) to 140{sup o}C to observe the wettability. In addition, liquid tar was also used to determine the wettability of semi-cokes. From the standpoint of wettability, the temperature of 900{sup o}C was determined to be the critical point for coke produced from sub-bituminous coals. 15 refs., 6 figs., 2 tabs.

  19. Working Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE

    E-Print Network [OSTI]

    Karp, Larry S.

    Working Paper No. 789 ESTIMATING COKE AND PEPSI'S PRICE AND ADVERTISING STRATEGIES (formerly Estimating Firms'Mixed Price and Advertising Strategies: Coke and Pepsi) by Amos Golan, Larry S. Karp. #12;Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan* Larry S. Karp** Jeffrey M

  20. Fundamentals of Delayed Coking Joint Industry Project

    SciTech Connect (OSTI)

    Volk Jr., Michael; Wisecarver, Keith D.; Sheppard, Charles M.

    2003-02-07T23:59:59.000Z

    The coking test facilities include three reactors (or cokers) and ten utilities. Experiments were conducted using the micro-coker, pilot-coker, and stirred-batch coker. Gas products were analyzed using an on-line gas chromatograph. Liquid properties were analyzed in-house using simulated distillation (HP 5880a), high temperature gas chromatography (6890a), detailed hydrocarbon analysis, and ASTM fractionation. Coke analyses as well as feedstock analyses and some additional liquid analyses (including elemental analyses) were done off-site.

  1. Multiple delivery cesium oven system for negative ion sources

    SciTech Connect (OSTI)

    Bansal, G.; Bhartiya, S.; Pandya, K.; Bandyopadhyay, M.; Singh, M. J.; Soni, J.; Gahlaut, A.; Parmar, K. G.; Chakraborty, A. [Institute for Plasma Research, Bhat, Gandhinagar, Gujarat 382428 (India)

    2012-02-15T23:59:59.000Z

    Distribution of cesium in large negative ion beam sources to be operational in ITER, is presently based on the use of three or more cesium ovens, which operate simultaneously and are controlled remotely. However, use of multiple Cs ovens simultaneously is likely to pose difficulties in operation and maintenance of the ovens. An alternate method of Cs delivery, based on a single oven distribution system is proposed as one which could reduce the need of simultaneous operation of many ovens. A proof of principle experiment verifying the concept of a multinozzle distributor based Cs oven has been carried out at Institute for Plasma Research. It is also observed that the Cs flux is not controlled by Cs reservoir temperature after few hours of operation but by the temperature of the distributor which starts behaving as a Cs reservoir.

  2. Reducing dust emissions at OAO Alchevskkoks coke battery 10A

    SciTech Connect (OSTI)

    T.F. Trembach; E.N. Lanina [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke battery 10A with rammed batch is under construction at OAO Alchevskkoks. The design documentation developed by Giprokoks includes measures for reducing dust emissions to the atmosphere. Aspiration systems with dry dust trapping are employed in the new components of coke battery 10A and in the existing coke-sorting equipment. Two-stage purification of dusty air in cyclones and bag filters is employed for the coke-sorting equipment. This system considerably reduces coke-dust emissions to the atmosphere.

  3. Water protection in coke-plant design

    SciTech Connect (OSTI)

    G.I. Alekseev [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Wastewater generation, water consumption, and water management at coke plants are considered. Measures to create runoff-free water-supply and sewer systems are discussed. Filters for water purification, corrosion inhibitors, and biocides are described. An integrated single-phase technology for the removal of phenols, thiocyanides, and ammoniacal nitrogen is outlined.

  4. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: COKE FORMATION PREDICTABILITY MAPS

    SciTech Connect (OSTI)

    John F. Schabron; A. Troy Pauli; Joseph F. Rovani Jr.

    2002-05-01T23:59:59.000Z

    The dispersed particle solution model of petroleum residua structure was used to develop predictors for pyrolytic coke formation. Coking Indexes were developed in prior years that measure how near a pyrolysis system is to coke formation during the coke formation induction period. These have been demonstrated to be universally applicable for residua regardless of the source of the material. Coking onset is coincidental with the destruction of the ordered structure and the formation of a multiphase system. The amount of coke initially formed appears to be a function of the free solvent volume of the original residua. In the current work, three-dimensional coke make predictability maps were developed at 400 C, 450 C, and 500 C (752 F, 842 F, and 932 F). These relate residence time and free solvent volume to the amount of coke formed at a particular pyrolysis temperature. Activation energies for two apparent types of zero-order coke formation reactions were estimated. The results provide a new tool for ranking residua, gauging proximity to coke formation, and predicting initial coke make tendencies.

  5. REDUCING POWER PRODUCTION COSTS BY UTILIZING PETROLEUM COKE

    SciTech Connect (OSTI)

    NONE

    1998-09-01T23:59:59.000Z

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance. Although the blending of petroleum coke with coal may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  6. Coking properties of perhydrous low-rank vitrains. Influence of pyrolysis conditions

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    generally lead to increased coking potential of coals characterised in the resulting cokes by large sizes equivalent to natural coking coals, since the cokes from these residues are always made of smaller MOD than those obtained for coking coals. For comparison, a similar characterisation, carried out

  7. Model based control of a coke battery

    SciTech Connect (OSTI)

    Stone, P.M.; Srour, J.M.; Zulli, P. [BHP Research, Mulgrave (Australia). Melbourne Labs.; Cunningham, R.; Hockings, K. [BHP Steel, Pt Kembla, New South Wales (Australia). Coal and Coke Technical Development Group

    1997-12-31T23:59:59.000Z

    This paper describes a model-based strategy for coke battery control at BHP Steel`s operations in Pt Kembla, Australia. The strategy uses several models describing the battery thermal and coking behavior. A prototype controller has been installed on the Pt Kembla No. 6 Battery (PK6CO). In trials, the new controller has been well accepted by operators and has resulted in a clear improvement in battery thermal stability, with a halving of the standard deviation of average battery temperature. Along with other improvements to that battery`s operations, this implementation has contributed to a 10% decrease in specific battery energy consumption. A number of enhancements to the low level control systems on that battery are currently being undertaken in order to realize further benefits.

  8. Reducing power production costs by utilizing petroleum coke. Annual report

    SciTech Connect (OSTI)

    Galbreath, K.C.

    1998-07-01T23:59:59.000Z

    A Powder River Basin subbituminous coal from the North Antelope mine and a petroleum shot coke were received from Northern States Power Company (NSP) for testing the effects of parent fuel properties on coal-coke blend grindability and evaluating the utility of petroleum coke blending as a strategy for improving electrostatic precipitator (ESP) particulate collection efficiency. Petroleum cokes are generally harder than coals, as indicated by Hardgrove grindability tests. Therefore, the weaker coal component may concentrate in the finer size fractions during the pulverizing of coal-coke blends. The possibility of a coal-coke size fractionation effect is being investigated because it may adversely affect combustion performance, it may enhance ESP particulate collection efficiency. Petroleum cokes contain much higher concentrations of V relative to coals. Consequently, coke blending can significantly increase the V content of fly ash resulting from coal-coke combustion. Pentavalent vanadium oxide (V{sub 2}O{sub 5}) is a known catalyst for transforming gaseous sulfur dioxide (SO{sub 2}[g]) to gaseous sulfur trioxide (SO{sub 3}[g]). The presence of SO{sub 3}(g) strongly affects fly ash resistivity and, thus, ESP performance.

  9. The methods of steam coals usage for coke production

    SciTech Connect (OSTI)

    Korobetskii, I.A.; Ismagilov, M.S.; Nazimov, S.A.; Sladkova, I.L.; Shudrikov, E.S.

    1998-07-01T23:59:59.000Z

    Nowadays, high volatile bituminous coals are broadly used for metallurgical coke production in Russia. The share of such coals in the coking blend is variable from 20 to 40% by weight. There are some large coal deposits in Kuznetskii basin which have coals with low caking tendency. The low caking properties of such coals limit of its application in the coking process. At the same time the usage of low caking coals for coke production would allow flexibility of the feedstock for coke production. Preliminary tests, carried out in COAL-C's lab has shown some differences in coal properties with dependence on the size distribution. That is why the separation of the well-caking fraction from petrographically heterogeneous coals and its further usage in coking process may be promising. Another way for low caking coals application in the coke industry is briquettes production from such coals. This method has been known for a very long time. It may be divided into two possible directions. First is a direct coking of briquettes from the low caking coals. Another way is by adding briquettes to coal blends in defined proportion and combined coking. The possibility of application of coal beneficiation methods mentioned above was investigated in present work.

  10. Development of an Advanced Combined Heat and Power (CHP) System Utilizing Off-Gas from Coke Calcination

    Broader source: Energy.gov [DOE]

    Coke calcination is a process that involves the heating of green petroleum coke in order to remove volatile material and purify the coke for further processing. Calcined coke is vital to the...

  11. Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs 

    E-Print Network [OSTI]

    Patel, S. S.

    1982-01-01T23:59:59.000Z

    effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per...

  12. Dry purification of aspirational air in coke-sorting systems with wet slaking of coke

    SciTech Connect (OSTI)

    T.F. Trembach; A.G. Klimenko [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Coke transportation after wet slaking is accompanied by the release of dust in the production building and in the surrounding atmosphere. Wet methods are traditionally used to purify very humid air. Giprokoks has developed designs for highly efficient dry dust-removal methods in such conditions.

  13. Coke Gasification - A Solution to Excess Coke Capacity and High Energy Costs

    E-Print Network [OSTI]

    Patel, S. S.

    1982-01-01T23:59:59.000Z

    effectively to produce medium-Btu (300 Btu/scf) gas which, in turn, can fuel the refinery furnaces to replace natural gas. Coke gasification should prove economical with natural gas price decontrol and the average price projected to rise to over $14.0 per...

  14. The Problem of Second-Hand Industrial Equipment: Reclaiming a Missed Opportunity

    E-Print Network [OSTI]

    Kelly-Detwiler, P.; Opheim, K.

    furnaces, preheating combustion air, high-efficiency burners, use of coke oven gas compressors, heat recovery of coke oven gases, and dry coke quenching. In addition, high efficiency motor retrofits and installation of adjustable speed drives are less... country industries are likely to experience growing difficulties in their ability to profitably service the domestic markets for which they were designed, let alone potential export markets, if they are dependent on outdated, inefficient industrial...

  15. Syncrude coke burned in bubbling fluidized bed

    SciTech Connect (OSTI)

    Not Available

    1987-03-01T23:59:59.000Z

    Syncrude Canada Ltd.'s byproduct coke is high in sulfur (7%) and vanadium (0.2%), and moderate in ash (5.9%). It contains a high proportion of unreactive forms of carbon and is low in volatiles, 6.6%. It is unsuitable for combustion by established technologies, and at present the entire production of over 2000 tons per day is being stockpiled. Experiments with atmospheric fluidized bed combustion (AFBC) are described. The AFBC provides abatement of SO/sub 2/ emissions by means of limestone sorbent fed to the combustor together with the fuel. The pilot plant, combustion efficiency, and sulfur capture are discussed. 3 figures.

  16. Building Energy Supply Infrastructures and Urban Sustained Development of Shenyang 

    E-Print Network [OSTI]

    Feng, G.; Wang, Y.; Gao, Y.

    2006-01-01T23:59:59.000Z

    store 300-thousand-cubemeter gases. The compressor is designed to distribute 63? 000m3/h gas. At present, in Shenyang there are oil gases, coal seam gases, mine gases, coke oven gases, liquefied petroleum gases with air, liquefied petroleum gases... Supply Selling Supply Selling kJ/Nm3 Oil gas 3507 2793 403 21767 Coke oven gas 5267 5323 4989 5039 5582 18487 Produced gas 857 7470 297 5870 3824 3592 4475 4916 Oil field gas 7986 6899 7249 6268 7008 6048 7758 6679 6938...

  17. Grass roots technology and energy policy: Solar ovens and wind turbines in Kenya

    SciTech Connect (OSTI)

    Kammen, D.M. [Harvard Univ., Cambridge, MA (United States). Dept. of Physics

    1992-12-31T23:59:59.000Z

    Kenya is said to be an ideal site for projects that promote renewable energy sources since it devotes over forty percent of its GNP to the purchase of imported coal and oil. The author presents a chronology of solar oven projects in Kenya and suggests that success of the program will be measured by the number of people who move on to wind turbine use. He discusses the role of renewable energy technology in reducing greenhouse gases and closes by recommending that industrialized nations that produce large amounts of carbon dioxide provide aid to develop projects that reduce carbon dioxide elsewhere in the world. At the same time they would receive credit towards their carbon dioxide quotas.

  18. Method for removal of furfural coke from metal surfaces

    SciTech Connect (OSTI)

    Turner, J.D.

    1990-02-27T23:59:59.000Z

    This patent describes a process for preparing furfural coke for removal from metallic surfaces. It comprises: heating ship furfural coke without causing an evolution of heat capable of undesirably altering metallurgical properties of the surfaces in the presence of a gas with a total pressure of less than 100 psig containing molecular oxygen. The gas being at a sufficient temperature below 800{degrees}F. (427{degrees}C.) for a sufficient time to change the crush strength of the coke so as to permit removal with a water jet at a pressure of about 5000 psi.

  19. Coke profile and effect on methane/ethylene conversion process

    E-Print Network [OSTI]

    Al-Solami, Bandar

    2002-01-01T23:59:59.000Z

    with distance along the reactor, and therefore the coke distribution should follow a similar pattern. A distribution of coke deposits along the reactor was also observed by Noda er al. (1974) in a study of iso-pentane isomerization. In this case the coke..., methane, ethane, ethylene, propane, iso-butane, butane, iso-pentane, pentane and hexanes. Also, the flow rate of the effluent stream is measured using the bubble meter. The mole percentages of methane and ethylene are subtracted of the effluent stream...

  20. A container for heat treating materials in microwave ovens

    DOE Patents [OSTI]

    Holcombe, C.E.; Dykes, N.L.; Kimrey, H.D. Jr.; Mills, J.E.

    1988-01-26T23:59:59.000Z

    The efficiency of a microwave oven of a conventional two-source configuration and energy level is increased by providing the oven with a container for housing a refractory material to be treated. The container is formed to top and bottom walls transparent to microwaves while the sidewalls, in a circular configuration, are formed of a nonmetallic material opaque to microwave radiation for reflecting the radiation penetrating the top and bottom walls radially inwardly into the center of the container wherein a casket of heat-insulating material is provided for housing the material to be heat treated. The reflection of the microwave radiation from the sidewalls increases the concentration of the microwaves upon the material being heat treated while the concentration of the microwaves upon the material being heat treated while the casket retains the heat to permit the heating of the material to a substantially higher temperature than achievable in the oven without the container.

  1. RESIDUA UPGRADING EFFICIENCY IMPROVEMENT MODELS: WRI COKING INDEXES

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani, Jr.; Francis P. Miknis; Thomas F. Turner

    2003-06-01T23:59:59.000Z

    Pyrolysis experiments were conducted with three residua at 400 C (752 F) at various residence times. The wt % coke and gaseous products were measured for the product oils. The Western Research Institute (WRI) Coking Indexes were determined for the product oils. Measurements were made using techniques that might correlate with the Coking Indexes. These included spin-echo proton nuclear magnetic resonance spectroscopy, heat capacity measurements at 280 C (536 F), and ultrasonic attenuation. The two immiscible liquid phases that form once coke formation begins were isolated and characterized for a Boscan residuum pyrolyzed at 400 C (752 F) for 55 minutes. These materials were analyzed for elemental composition (CHNS), porphyrins, and metals (Ni,V) content.

  2. Estimating Coke and Pepsi's Price and Advertising Strategies

    E-Print Network [OSTI]

    Golan, Amos; Karp, Larry S.; Perloff, Jeffrey M.

    1998-01-01T23:59:59.000Z

    2b: GME-Nash Estimates of Pepsi’s Strategies (First QuarterStrategy Distributions for Pepsi (First Quarter 1977) a)789 ESTIMATING COKE AND PEPSI'S PRICE ADVERTISING STRATEGIES

  3. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi (Hoffman Estates, IL); Kulkarni, Sudhir S. (Hoffman Estates, IL)

    1986-01-01T23:59:59.000Z

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  4. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.

    1986-08-19T23:59:59.000Z

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  5. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, Santi (Hoffman Estates, IL)

    1986-01-01T23:59:59.000Z

    The separation of polar gases from nonpolar gases may be effected by passing a mixture of nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The porous support is pretreated prior to casting of the mixture thereon by contact with a polyhydric alcohol whereby the pores of the support are altered, thus adding to the increased permeability of the polar gas.

  6. Separation of polar gases from nonpolar gases

    DOE Patents [OSTI]

    Kulprathipanja, S.; Kulkarni, S.S.

    1986-08-26T23:59:59.000Z

    Polar gases such as hydrogen sulfide, sulfur dioxide and ammonia may be separated from nonpolar gases such as methane, nitrogen, hydrogen or carbon dioxide by passing a mixture of polar and nonpolar gases over the face of a multicomponent membrane at separation conditions. The multicomponent membrane which is used to effect the separation will comprise a mixture of a glycol plasticizer having a molecular weight of from about 200 to about 600 and an organic polymer cast on a porous support. The use of such membranes as exemplified by polyethylene glycol and silicon rubber composited on polysulfone will permit greater selectivity accompanied by a high flux rate in the separation process.

  7. Prediction of metallurgical coke strength from the petrographic composition of coal blends

    SciTech Connect (OSTI)

    Sutcu, H.; Toroglu, I.; Piskin, S. [Zonguldak Karaelmas University, Zonguldak (Turkey)

    2009-07-01T23:59:59.000Z

    Turkey, especially Zonguldak on the West Coast of Black Sea region, has large reserves of bituminous coal that can be used either directly or in blends with other coals for metallurgical coke production. It is possible to predict the coking properties of these coals by petrographic analysis. In this study, semi- and non-coking coals were blended with coking bituminous coals in varying proportions and an estimation was made as to their stability factors through petrographic techniques. It was established that semi- and non-coking bituminous coals could be used in the production of metallurgical coke.

  8. Clostridium stain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, James L. (2207 Tall Oaks Dr., Fayetteville, AR 72703)

    1997-01-01T23:59:59.000Z

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

  9. Clostridium strain which produces acetic acid from waste gases

    DOE Patents [OSTI]

    Gaddy, J.L.

    1997-01-14T23:59:59.000Z

    A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 4 figs.

  10. Role of hydrogen in blast furnaces to improve productivity and decrease coke consumption

    SciTech Connect (OSTI)

    Agarwal, J.C.; Brown, F.C.; Chin, D.L.; Stevens, G.; Clark, R.; Smith, D.

    1995-12-01T23:59:59.000Z

    The hydrogen contained in blast furnace gases exerts a variety of physical, thermochemical, and kinetic effects as the gases pass through the various zones. The hydrogen is derived from two sources: (1) the dissociation of moisture in the blast air (ambient and injected with hot blast), and (2) the release from partial combustion of supplemental fuels (including moisture in atomizing water, steam, or transport air, if any). With each atom of oxygen (or carbon), the molar amounts of hydrogen released are more than six times higher for natural gas than for coal, and two times higher for natural gas than for oil. Injection of natural gas in a blast furnace is not a new process. Small amounts of natural gas--about 50--80 lb or 1,100--1,700 SCF/ton of hot metal--have been injected in many of the North American blast furnaces since the early 1960s, with excellent operating results. What is new, however, is a batter understanding of how natural gas reacts in the blast furnace and how natural gas and appropriate quantities of oxygen can be used to increase the driving rate or combustion rate of carbon (coke) in the blast furnace without causing hanging furnace and operating problems. The paper discusses the factors limiting blast furnace productivity and how H{sub 2} and O{sub 2} can increase productivity.

  11. Energy conservation and efficiency in Giprokoks designs at Ukrainian ferrous-metallurgical enterprises

    SciTech Connect (OSTI)

    M.I. Fal'kov [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Energy conditions at Ukrainian ferrous-metallurgical enterprises are analyzed. Measures to boost energy conservation and energy efficiency are proposed: specifically, the introduction of systems for dry slaking of coke; and steam-gas turbines that employ coke-oven gas or a mixture of gases produced at metallurgical enterprises. Such turbines may be built from Ukrainian components.

  12. Process for converting coal into liquid fuel and metallurgical coke

    DOE Patents [OSTI]

    Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

    1994-01-01T23:59:59.000Z

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  13. Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan*

    E-Print Network [OSTI]

    Lansky, Joshua

    Estimating Coke and Pepsi's Price and Advertising Strategies Amos Golan* Larry S. Karp** Jeffrey M strategies in prices and advertising for Coca-Cola and Pepsi-Cola. Separate strategies for each firm theory. We use these methods to estimate the pricing and adver- tising strategies of Coca-Cola and Pepsi

  14. Coke profile and effect on methane/ethylene conversion process 

    E-Print Network [OSTI]

    Al-Solami, Bandar

    2002-01-01T23:59:59.000Z

    The objective of this study was to investigate the coke profile with respect to time on stream and the change of product distribution due to catalyst deactivation. A fixed bed reactor was used to conduct this investigation. A series of runs were...

  15. Greenhouse Gases | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Greenhouse Gases Greenhouse Gases Executive Order 13514 requires Federal agencies to inventory and manage greenhouse gas (GHG) emissions to meet Federal goals and mitigate climate...

  16. An overview of crisis management in the coke industry

    SciTech Connect (OSTI)

    Saunders, D.A.

    1995-12-01T23:59:59.000Z

    Members of the American Coke and Coal Chemicals Institute (ACCCI), as responsible corporate citizens, have embraced the concepts of crisis management and progress down the various paths of planning and preparation, monitoring, media communications, community outreach, emergency response, and recovery. Many of the concepts outlined here reflect elements of crisis management guidelines developed by the Chemical Manufacturers Association (CMA). At a coke plant, crises can take the form of fires, chemical releases, labor strikes, feedstock supply disruptions, and excessive snowfall, just to name a few. The CMA defines a crisis as: ``an unplanned event that has the potential to significantly impact a company`s operability or credibility, or to pose a significant environment, economic or legal liability``; and crisis management as: ``those activities undertaken to anticipate or prevent, prepare for, respond to and recover from any incident that has the potential to greatly affect the way a company conducts its business.

  17. Integrated coke, asphalt and jet fuel production process and apparatus

    DOE Patents [OSTI]

    Shang, Jer Y. (McLean, VA)

    1991-01-01T23:59:59.000Z

    A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

  18. New environmental concepts in the chemical and coke industries

    SciTech Connect (OSTI)

    A.Yu. Naletov; V.A. Naletov [Mendeleev Russian Chemical-Engineering University (Russian Federation)

    2007-05-15T23:59:59.000Z

    We know that environmentally pure technologies do not exist. Coke production is no exception to the rule. The article considers the logic of environmental decision making. Attention focuses on a new bank of ecologically appropriate materials whose release to the biosphere must be considered solely in quantititative terms. Qualitativily all these materials are familiar; they are assimilated by populations of microorganisms and tar thus compatible with the biosphere.

  19. How to implement a quality program in a coking plant. The AHMSA experience

    SciTech Connect (OSTI)

    Reyes M, M.A.; Perez, J.L.; Garza, C. de la; Morales, M.

    1995-12-01T23:59:59.000Z

    AHMSA (Altos Hornos de Mexico) is the largest integrated Steel Plant in Mexico, with its 3.1 MMMT of Liquid Steel production program for 1995. AHMSA operates two coke plants which began operations in 1955 and 1976. Total coke monthly production capacity amounts to as much as 106,000 Metric Tons (MT). The coke plants working philosophy was discussed and established in 1986 as part of the Quality Improvement Program, where its ultimate goal is to give the best possible coke quality to its main client--the blast furnaces. With this goal in mind, a planned joint effort with their own coal mines was initiated. This paper deals with the implementation process of the Quality Program, and the results of this commitment at the coal mines, coke plants and blast furnaces. The coke quality improvement is shown since 1985 to 1994, as well as the impact on the blast furnace operation.

  20. Low-coke rate operation under high PCI at Kobe No. 3 BF

    SciTech Connect (OSTI)

    Matsuo, Tadasu; Kanazuka, Yasuo; Hoshino, Koichi; Yoshida, Yasuo; Kitayama, Syuji; Ishiwaki, Shiro [Kobe Steel Ltd. (Japan). Kobe Works

    1997-12-31T23:59:59.000Z

    Kobe No. 3 blast furnace (BF) suffered tremendous damage when the Great Hanshin-Awaji Earthquake rocked the area on January 17, 1995. However, working as quickly as possible to dig out of the burden and rehabilitate various facilities, the company managed to restart the No. 3 BF on April 2. After the restart, which went smoothly, production was shifted into the low coke rate operation which was being promoted before the disaster. In October, 1995, only seven months after the restart, the nation record of 296 kg/t low coke rate could be achieved. Subsequently, in January, 1996, coke rate reached 290 kg/t and the low coke rate operation was renewed. Since that time the same level of coke rate has been maintained. The paper discusses how low coke rate operation was achieved.

  1. Process Parameters and Energy Use of Gas and Electric Ovens in Industrial Applications 

    E-Print Network [OSTI]

    Kosanovic, D.; Ambs, L.

    2000-01-01T23:59:59.000Z

    The study was conducted to evaluate the energy use of natural gas and electric ovens in the production of polymer bearings and components. Tests were conducted to evaluate and compare the performance of natural gas and electric ovens in the process...

  2. Process Parameters and Energy Use of Gas and Electric Ovens in Industrial Applications

    E-Print Network [OSTI]

    Kosanovic, D.; Ambs, L.

    The study was conducted to evaluate the energy use of natural gas and electric ovens in the production of polymer bearings and components. Tests were conducted to evaluate and compare the performance of natural gas and electric ovens in the process...

  3. The effects of ash and maceral composition of Azdavay and Kurucasile (Turkey) coals on coking properties

    SciTech Connect (OSTI)

    Toroglu, I. [Zonguldak Karaelmas University, Zonguldak (Turkey). Faculty of Engineering

    2006-07-01T23:59:59.000Z

    In this study, investigations were made as to the effect of the maceral compositions and mineral matter content of Azdavay and Kurucasile coals on the coking property. Chemical and maceral analyses and coking properties were determined for the products of the float-sink procedure. The coking properties were established on the basis of free swelling index and Ruhr dilatometer tests. Maceral analyses showed that as the ash content of a coal containing both high and medium volatile matter increases, its effective maceral proportion decreases, and the coking property is affected in an unfavorable way.

  4. Chapter 46. Ultracold Quantum Gases Ultracold Quantum Gases

    E-Print Network [OSTI]

    of strongly interacting Fermi gases is important for the modeling of neutron stars. Cold atomic gases allow potential of the gas. Away from resonance another length scale comes into play, the scattering length a

  5. Innovative coke oven gas cleaning system for retrofit applications: Environmental Monitoring Program. Baseline sampling program report: Volume 2, Appendix sections 1--7

    SciTech Connect (OSTI)

    Stuart, L.M.

    1994-05-27T23:59:59.000Z

    This report contains no text. It consist entirely of results monitoring stack opacity, benzene surveys, chemical effluent in wastewater, etc.

  6. Innovative coke oven gas cleaning system for retrofit applications. Quarterly environmental monitoring report No. 2, July 1, 1991--September 30, 1991

    SciTech Connect (OSTI)

    Not Available

    1992-09-21T23:59:59.000Z

    The EMP consists of a Compliance Monitoring Sampling Program and a Supplemental monitoring Sampling Program. The Compliance Monitoring Sampling Program will be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Project and during a summer and a winter period following the successful Startup and Operational phase of the completed Project. compliance monitoring consist of conducting all the sampling and observation programs associated with existing required Federal, State, and Local Regulations, Permits and Orders. These include air, water, and waste monitoring and OSHA and NESHAP monitoring. The Supplemental Monitoring Program will also be conducted during a summer and a winter Baseline periods during the Pre-Construction/Construction phases of the Demonstration Facility and during a summer and a winter period following the successful startup and Operational phase of the completed Facility. Supplemental Monitoring includes sampling of 27 additional streams that are important to measure operational or environmental performance and impacts of the installation of the new COG treatment facilities.

  7. Progressive Powder Coating: New Infrared Curing Oven at Metal Finishing Plant Increases Production by 50%

    SciTech Connect (OSTI)

    Not Available

    2003-05-01T23:59:59.000Z

    Progressive Powder Coating in Mentor, Ohio, is a metal finishing plant that uses a convection oven in its manufacturing process. In an effort to save energy and improve production, the company installed an infrared oven in between the powder coating booth and the convection oven on its production line. This installation allowed the plant to increase its conveyor line speed and increase production by 50 percent. In addition, the plant reduced its natural gas consumption, yielding annual energy savings of approximately$54,000. With a total project cost of$136,000, the simple payback is 2.5 years.

  8. Influence of coal on coke properties and blast-furnace operation

    SciTech Connect (OSTI)

    G.R. Gainieva; L.D. Nikitin [OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (Russian Federation)

    2007-07-01T23:59:59.000Z

    With unstable coal supplies and properties and a fluctuating content of coking coal in the batch at OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (ZSMK) and of bituminous coal at Kuznetskaya enrichment facility, it is important to optimize the rank composition of the batch for coke production.

  9. Analytical input-output and supply chain study of China's coke and steel sectors

    E-Print Network [OSTI]

    Li, Yu, 1976-

    2004-01-01T23:59:59.000Z

    I design an input-output model to investigate the energy supply chain of coal-coke-steel in China. To study the demand, supply, and energy-intensity issues for coal and coke from a macroeconomic perspective, I apply the ...

  10. Teamwork in planning and carrying out the first inspection of the coke dry quenching (CDQ) plant of the Kaiserstuhl Coking Facility

    SciTech Connect (OSTI)

    Burchardt, G.

    1996-12-31T23:59:59.000Z

    The coke plant Kaiserstuhl operates a coke dry quenching (CDQ) plant with a downstream installed waste heat boiler to satisfy statutory pollution control rules and requirements. This CDQ which went on stream in March 1993 cools the whole coke production output from the Kaiserstuhl coke plant in counterflow to an inert cooling gas. This brief overview on the whole CDQ plant should elucidate the complex of problems posed when trying to make an exact plant revision plan. After all it was impossible to evaluate or to assess all the interior process technology relevant components during the planning stage as the plant was in operation. The revision data for the first interior check was determined and fixed by the statutory rule for steam boilers and pressure vessels. The relevant terms for this check are mandatorily prescribed. In liaison with the testing agency (RW TUEV) the date for the first revision was fixed for April 1995, that means two years after the first commissioning.

  11. Additional Steam Traps Increase Production of a Drum Oven at a Petroleum Jelly Plant

    SciTech Connect (OSTI)

    Not Available

    2002-03-01T23:59:59.000Z

    Additional steam traps were installed on the drum oven at a petroleum jelly production facility at an ExxonMobil plant in Nigeria. The installation improved heat transfer and saved energy.

  12. Acoustic emission feedback control for control of boiling in a microwave oven

    DOE Patents [OSTI]

    White, Terry L. (Oak Ridge, TN)

    1991-01-01T23:59:59.000Z

    An acoustic emission based feedback system for controlling the boiling level of a liquid medium in a microwave oven is provided. The acoustic emissions from the medium correlated with surface boiling is used to generate a feedback control signal proportional to the level of boiling of the medium. This signal is applied to a power controller to automatically and continuoulsly vary the power applied to the oven to control the boiling at a selected level.

  13. Biological production of acetic acid from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, James L. (Fayetteville, AR)

    1998-01-01T23:59:59.000Z

    A method and apparatus for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration.

  14. Biological production of acetic acid from waste gases with Clostridium ljungdahlii

    DOE Patents [OSTI]

    Gaddy, J.L.

    1998-09-15T23:59:59.000Z

    A method and apparatus are disclosed for converting waste gases from industrial processes such as oil refining, carbon black, coke, ammonia, and methanol production, into useful products. The method includes introducing the waste gases into a bioreactor where they are fermented to various organic acids or alcohols by anaerobic bacteria within the bioreactor. These valuable end products are then recovered, separated and purified. In an exemplary recovery process, the bioreactor raffinate is passed through an extraction chamber into which one or more non-inhibitory solvents are simultaneously introduced to extract the product. Then, the product is separated from the solvent by distillation. Gas conversion rates can be maximized by use of centrifuges, hollow fiber membranes, or other means of ultrafiltration to return entrained anaerobic bacteria from the bioreactor raffinate to the bioreactor itself, thus insuring the highest possible cell concentration. 5 figs.

  15. Demineralization of petroleum cokes and fly ash samples obtained from the upgrading of Athabasca oil sands bitumen

    SciTech Connect (OSTI)

    Majid, A.; Ratcliffe, C.I.; Ripmeester, J.A. (National Research Council of Canada, Ottawa, ON (Canada). Div. of Chemistry)

    1989-01-01T23:59:59.000Z

    Ash reduction of the cokes and fly ash samples derived from the Athabasca oil sands bitumen was attempted by dissolving the mineral matter in acids. The samples used for this investigation included Syncrude fluid coking coke, Suncor delayed coking coke and the two fly ash samples obtained from the combustion of these cokes. All samples were analyzed for C,H,N,O, and S before and after acid demineralization and the analyses results compared. Further, the ash from the samples before and after acid demineralization was analyzed for silica, alumina, iron titanium, nickel and vanadium to assess the acid leaching of these elements. CP/MAS, /sup 13/C NMR spectroscopic study of the demineralized coke and fly ash samples was also attempted.

  16. Characterization of liquids derived from laboratory coking of decant oil and co-coking of Pittsburgh seam bituminous coal with decant oil

    SciTech Connect (OSTI)

    Omer Gul; Caroline Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States)

    2009-05-15T23:59:59.000Z

    In this study, decant oil and a blend of Pittsburgh seam bituminous coal with decant oil were subjected to coking and co-coking in a laboratory-scale delayed coker. Higher yields of coke and gas were obtained from co-coking than from coking. Coal addition into the feedstock resulted in lighter overhead liquid. GC/MS analyses of gasoline, jet fuel, and diesel show that co-coking of coal/decant oil gave higher quantity aromatic components than that of coking of decant oil alone. Simulated distillation gas chromatography analyses of overhead liquids and GC/MS analyses of vacuum fractions show that when coal was reacted with a decant oil, the coal constituents contributed to the distillable liquids. To address the reproducibility of the liquid products, overhead liquid samples collected at the first, third, and fifth hours of experiments of 6 h duration were evaluated using simulated distillation gas chromatography and {sup 1}H and {sup 13}C NMR. NMR analyses of the liquid products showed that, even though there were slight changes in the {sup 1}H and {sup 13}C spectra, the standard deviation was low for the time-dependent samples. Simulated distillation gas chromatography showed that the yields of refinery boiling range materials (i.e., gasoline, jet fuel, diesel, and fuel oil cuts) were reproducible between runs. Fractionation of the overhead liquids into refinery boiling range materials (gasoline, jet fuel, diesel, fuel oil fractions) showed that the boiling range materials and chemical compositions of fractions were found to be reproducible. 54 refs., 17 tabs.

  17. A Comparison of Iron and Steel Production Energy Use and Energy Intensity in China and the U.S.

    E-Print Network [OSTI]

    Hasanbeigi, Ali

    2012-01-01T23:59:59.000Z

    other bituminous coal and coking coal. Small differences incoal (used as fuel) Coking coal Coke oven coke Natural gasrange for typical NCVs of coking coal of 26.6 to 29.8Mj/kg.

  18. Energy efficiency of alternative coke-free metallurgical technologies

    SciTech Connect (OSTI)

    V.G. Lisienko; A.V. Lapteva; A.E. Paren'kov [Ural State Technical University - Ural Polytechnic Institute, Yekaterinburg (Russian Federation)

    2009-02-15T23:59:59.000Z

    Energy analysis is undertaken for the blast-furnace process, for liquid-phase processes (Corex, Hismelt, Romelt), for solid-phase pellet reduction (Midrex, HYL III, LP-V in a shaft furnace), for steel production in systems consisting of a blast furnace and a converter, a Midrex unit and an arc furnace, or a Romelt unit and an arc furnace, and for scrap processing in an arc furnace or in an LP-V shaft furnace. Three blast-furnace processes with sinter and coke are adopted as the basis of comparison, as in: the standard blast-furnace process used in Russia; the improved blast-furnace process with coal-dust injection; and the production of vanadium hot metal from vanadium-bearing titanomagnetite ore (with a subsequent duplex process, ferrovanadium production, and its use in the arc furnace).

  19. Control of pollutants in flue gases and fuel gases

    E-Print Network [OSTI]

    Laughlin, Robert B.

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-1 2.2 Flue gases and fuel gases: combustion, gasification, pyrolysis, incineration and other and gasification technologies for heat and power . . . . . . . . 2-3 2.4 Waste incineration and waste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3-3 3.3 Formation of sulphur compounds during combustion and gasification . 3-5 3.4 Emission

  20. Producing and controlling of the pollutant in the coal`s coking process

    SciTech Connect (OSTI)

    Li, S. [Shanxi Environmental Protection Bureau (China); Fan, Z. [Shanxi Central Environmental Monitoring Station (China)

    1997-12-31T23:59:59.000Z

    In the process of heating and coke shaping, different pollutants and polluting factors will be produced and lost to the environment due to the different coking methods. The paper analyzes the production mechanism, type, emission, average quantity, and damage to the environment of the major pollutants and polluting factors produced in several kinds of coking processes in China at the present. Then, the paper concludes that an assessment for any coking method should include a comprehensive beneficial assessment of economical benefit, environmental benefit and social benefit. The items in the evaluation should consist of infrastructure investment, which includes production equipment and pollution control equipment, production cost, benefit and profit produced by one ton coal, whether the pollution complies with the environmental requirement, extent of the damage, influence to the social development, and etc.

  1. Current developments at Giprokoks for coke-battery construction and reconstruction

    SciTech Connect (OSTI)

    V.I. Rudyka; Y.E. Zingerman; V.B. Kamenyuka; O.N. Surenskii; G.E. Kos'kova; V.V. Derevich; V.A. Gushchin [Giprokoks, the State Institute for the Design of Coke-Industry Enterprises, Kharkov (Ukraine)

    2009-07-15T23:59:59.000Z

    Approaches developed at Giprokoks for coke-battery construction and reconstruction are considered. Recommendations regarding furnace construction and reconstruction are made on the basis of Ukrainian and world experience.

  2. Voluntary Reporting of Greenhouse Gases

    Reports and Publications (EIA)

    2011-01-01T23:59:59.000Z

    The Voluntary Reporting of Greenhouse Gases Program was suspended May 2011. It was a mechanism by which corporations, government agencies, individuals, voluntary organizations, etc., could report to the Energy Information Administration, any actions taken that have or are expected to reduce/avoid emissions of greenhouse gases or sequester carbon.

  3. Development of a high-temperature oven for the 28 GHz electron cyclotron resonance ion source

    SciTech Connect (OSTI)

    Ohnishi, J., E-mail: ohnishi@riken.jp; Higurashi, Y.; Kidera, M.; Ozeki, K.; Nakagawa, T. [RIKEN Nishina Center, Wako, Saitama 351-0198 (Japan)] [RIKEN Nishina Center, Wako, Saitama 351-0198 (Japan)

    2014-02-15T23:59:59.000Z

    We have been developing the 28 GHz ECR ion source in order to accelerate high-intensity uranium beams at the RIKEN RI-beam Factory. Although we have generated U{sup 35+} beams by the sputtering method thus far, we began developing a high-temperature oven with the aim of increasing and stabilizing the beams. Because the oven method uses UO{sub 2}, a crucible must be heated to a temperature higher than 2000?°C to supply an appropriate amount of UO{sub 2} vapor to the ECR plasma. Our high-temperature oven uses a tungsten crucible joule-heated with DC current of approximately 450 A. Its inside dimensions are ?11 mm × 13.5 mm. Since the crucible is placed in a magnetic field of approximately 3 T, it is subject to a magnetic force of approximately 40 N. Therefore, we used ANSYS to carefully design the crucible, which was manufactured by machining a tungsten rod. We could raise the oven up to 1900?°C in the first off-line test. Subsequently, UO{sub 2} was loaded into the crucible, and the oven was installed in the 28 GHz ECR ion source and was tested. As a result, a U{sup 35+} beam current of 150 ?A was extracted successfully at a RF power of approximately 3 kW.

  4. The nature and formation of coke in the reaction of methanol to hydrocarbons over chabazite 

    E-Print Network [OSTI]

    McLaughlin, Kenneth Woot

    1983-01-01T23:59:59.000Z

    45 Figure 9. Relationship between enhanced coke formation with increasing yields of paraffins and diminishing yields of olefins 46 Figure 10. Gas chromatogram of the concentrated carbon tetrachloride extract of spent catalyst pellets . . . 49...THE NATURE ABD FORMATION OF COKE IB THE REACTIOB OF METHANOL TO HIDROCARBOBS OVER CHABAZITE A Thesis KENNETH WOOT MCLAUGHLLN Submitted to the Graduate College of Texas AAM Univers ty partial. fulfillment nf the req~nt fo~he degree of MASTER...

  5. Effect of thermal treatment on coke reactivity and catalytic iron mineralogy

    SciTech Connect (OSTI)

    Byong-chul Kim; Sushil Gupta; David French; Richard Sakurovs; Veena Sahajwalla [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research and Technology

    2009-07-15T23:59:59.000Z

    Iron minerals in coke can catalyze its gasification and may affect coke behavior in the blast furnace. The catalytic behavior of iron depends largely upon the nature of the iron-bearing minerals. To determine the mineralogical changes that iron could undergo in the blast furnace, cokes made from three coals containing iron present in different mineral forms (clays, carbonates, and pyrite) were examined. All coke samples were heat-treated in a horizontal furnace at 1373, 1573, and 1773 K and then gasified with CO{sub 2} at 1173 K in a fixed bed reactor (FBR). Coke mineralogy was characterized using quantitative X-ray diffraction (XRD) analysis of coke mineral matter prepared by low-temperature ashing (LTA) and field emission scanning electron microscopy combined with energy dispersive X-ray analysis (FESEM/EDS). The mineralogy of the three cokes was most notably distinguished by differing proportions of iron-bearing phases. During heat treatment and subsequent gasification, iron-containing minerals transformed to a range of minerals but predominantly iron-silicides and iron oxides, the relative amounts of which varied with heat treatment temperature and gasification conditions. The relationship between initial apparent reaction rate and the amount of catalytic iron minerals - pyrrhotite, metallic iron, and iron oxides - was linear and independent of heat treatment temperature at total catalyst levels below 1 wt %. The study showed that the coke reactivity decreased with increasing temperature of heat treatment due to decreased levels of catalytic iron minerals (largely due to formation of iron silicides) as well as increased ordering of the carbon structure. The study also showed that the importance of catalytic mineral matter in determining reactivity declines as gasification proceeds. 37 refs., 13 figs., 7 tabs.

  6. Coke gasification: the influence and behavior of inherent catalytic mineral matter

    SciTech Connect (OSTI)

    Mihaela Grigore; Richard Sakurovs; David French; Veena Sahajwalla [Commonwealth Scientific and Industrial Research Organisation (CSIRO), Bangor, NSW (Australia)

    2009-04-15T23:59:59.000Z

    Gasification of coke contributes to its degradation in the blast furnace. In this study, the effect of gasification on the inherent catalytic minerals in cokes and their reciprocal influence on gasification are investigated. The catalytic mineral phases identified in the cokes used in this study were metallic iron, iron sulfides, and iron oxides. Metallic iron and pyrrhotite were rapidly oxidized during gasification to iron oxide. The catalysts had a strong influence on the apparent rates at the initial stages of reaction. As gasification proceeds, their effect on the reaction rate diminishes as a result of reducing the surface contact between catalyst and carbon matrix because of carbon consumption around the catalyst particles; with extended burnout the reactivity of the coke becomes increasingly dependent on surface area. The reaction rate in the initial stages was also influenced by the particle size of the catalytic minerals; for a given catalytic iron level, the cokes whose catalytic minerals were more finely dispersed had a higher apparent reaction rate than cokes containing larger catalytic particles. Iron, sodium, and potassium in the amorphous phase did not appear to affect the reaction rate. 40 refs., 16 figs., 6 tabs.

  7. Improved correlations for retrograde gases 

    E-Print Network [OSTI]

    Crogh, Arne

    1996-01-01T23:59:59.000Z

    Three correlations for retrograde gases have been developed. First, a correlation was developed that relates the composition of a retrograde gas-condensate mixture at any depletion stage to the composition at its dew point ...

  8. Guidance Document CompressedGases

    E-Print Network [OSTI]

    electricity. Oxygen by itself does not burn, but it will support or accelerate combustion of flammable the regulator is completely closed. 3. When possible use flammable and reactive gases in a fume hood. Certain

  9. Extra Crispy OvenFried Drumsticks 3 cups cornflake cereal, crushed

    E-Print Network [OSTI]

    Jawitz, James W.

    Extra Crispy OvenFried Drumsticks 3 cups cornflake cereal, crushed 1/3 cup grated Parmesan pepper sauce 8 chicken drumsticks, skinned Vegetable cooking spray 1. Combine buttermilk and hot pepper sauce in an extralarge ziptop freezer bag. Add chicken drumsticks, turning to coat. Place bag

  10. PROCESS PARAMETERS AND ENERGY USE OF GAS AND ELECTRIC OVENS IN INDUSTRIAL APPLICATIONS

    E-Print Network [OSTI]

    Massachusetts at Amherst, University of

    . BACKGROUND This paper will evaluate current practices of clients in the New England/New York whichPROCESS PARAMETERS AND ENERGY USE OF GAS AND ELECTRIC OVENS IN INDUSTRIAL APPLICATIONS Dr for Energy Efficiency and Renewable Energy Department of Mechanical and Industrial Engineering University

  11. Effect of coal and coke qualities on blast furnace injection and productivity at Taranto

    SciTech Connect (OSTI)

    Salvatore, E.; Calcagni, M. [ILVA, Taranto (Italy); Eichinger, F.; Rafi, M.

    1995-12-01T23:59:59.000Z

    Injection rates at Taranto blast furnaces Nos. 2 and 4, for more than 16 months, was maintained above 175 kg/thm. Monthly average injection rate for two months stabilized above 190 kg/thm. This performance was possible due to the very high combined availabilities of Taranto blast furnaces and the KST injection system. Based upon this experience the quantitative relationships between coke/coal and blast furnace operational parameters were studied and are shown graphically. During this period due to coke quality changes, injection rate had to be reduced. The effect of using coke breeze in coke/ferrous charge as well as coal blend was also evaluated. Permeability of the furnace was found to be directly affected by O{sub 2} enrichment level, while at a high PCI rate no correlation between actual change in coke quality and permeability could be established. The future of PCI technology lies in better understanding of relationships between material specifications and blast furnace parameters of which permeability is of prime importance.

  12. Dale Coke: Coke Farm

    E-Print Network [OSTI]

    Farmer, Ellen

    2010-01-01T23:59:59.000Z

    the right place to get compost, or how you get the beststerilized or pasteurized our compost before we put it out.

  13. Coal flow aids reduce coke plant operating costs and improve production rates

    SciTech Connect (OSTI)

    Bedard, R.A.; Bradacs, D.J.; Kluck, R.W.; Roe, D.C.; Ventresca, B.P.

    2005-06-01T23:59:59.000Z

    Chemical coal flow aids can provide many benefits to coke plants, including improved production rates, reduced maintenance and lower cleaning costs. This article discusses the mechanisms by which coal flow aids function and analyzes several successful case histories. 2 refs., 10 figs., 1 tab.

  14. Simulation of diffusion and trapping in digitized heterogeneous media David A. Coke@ and Salvatore Torquatob)

    E-Print Network [OSTI]

    Torquato, Salvatore

    Simulation of diffusion and trapping in digitized heterogeneous media David A. Coke@ and Salvatore of a Brownian particle diffusing among a, digitized lattice-based domain of traps. Following the first, the inverse of the trapping rate, is obtained for a variety of configurations involving digitized spheres

  15. Recycling of rubber tires in electric arc furnace steelmaking: simultaneous combustion of metallurgical coke and rubber tyres blends

    SciTech Connect (OSTI)

    Magdalena Zaharia; Veena Sahajwalla; Byong-Chul Kim; Rita Khanna; N. Saha-Chaudhury; Paul O'Kane; Jonathan Dicker; Catherine Skidmore; David Knights [University of New South Wales, Sydney, NSW (Australia). School of Materials Science and Engineering

    2009-05-15T23:59:59.000Z

    The present study investigates the effect of addition of waste rubber tires on the combustion behavior of its blends with coke for carbon injection in electric arc furnace steelmaking. Waste rubber tires were mixed in different proportions with metallurgical coke (MC) (10:90, 20:80, 30:70) for combustion and pyrolysis at 1473 K in a drop tube furnace (DTF) and thermogravimetric analyzer (TGA), respectively. Under experimental conditions most of the rubber blends indicated higher combustion efficiencies compared to those of the constituent coke. In the early stage of combustion the weight loss rate of the blends is much faster compared to that of the raw coke due to the higher volatile yield of rubber. The presence of rubber in the blends may have had an impact upon the structure during the release and combustion of their high volatile matter (VM) and hence increased char burnout. Measurements of micropore surface area and bulk density of the chars collected after combustion support the higher combustion efficiency of the blends in comparison to coke alone. The surface morphology of the 30% rubber blend revealed pores in the residual char that might be attributed to volatile evolution during high temperature reaction in oxygen atmosphere. Physical properties and VM appear to have a major effect upon the measured combustion efficiency of rubber blends. The study demonstrates that waste rubber tires can be successfully co-injected with metallurgical coke in electric arc furnace steelmaking process to provide additional energy from combustion. 44 refs., 11 figs., 2 tabs.

  16. National Level Co-Control Study of the Targets for Energy Intensity and Sulfur Dioxide in China

    E-Print Network [OSTI]

    Zhou, Nan

    2013-01-01T23:59:59.000Z

    Increasing bed depth Improve ignition oven efficiency Emission Optimized Sintering (EOS ® ) Other measures Coke Making Coal moisture control Coke dry quenching (

  17. Industrial Gases as a Vehicle for Competitiveness

    E-Print Network [OSTI]

    Dale, J. R.

    -based separation technology was developing to offer an alternative to cryogenic separation for those instances when neither high purity or cryogenic properties were required by the application. It resulted in gas of lower than 99.9995%, "five-nines", purity...INDUSTRIAL GASES AS A VEHICLE FOR COMPETITIVENESS James R. Dale, Director, Technology Programs, Airco Industrial Gases Division, The BOC Group, Inc., Murray Hill, New Jersey ABSTRACT Industrial gases are produced using compressed air...

  18. Usiing NovoCOS cleaning equipment in repairing the furnace-chamber lining in coke batteries 4 & 5 at OAO Koks

    SciTech Connect (OSTI)

    S.G. Protasov; R. Linden; A. Gross [OAO Koks, Kemerovo (Russian Federation)

    2009-05-15T23:59:59.000Z

    Experience with a new surface-preparation technology for the ceramic resurfacing of the refractory furnace-chamber lining in coke batteries is described.

  19. Initial coke deposition on a NiMo/{gamma}-Al{sub 2}O{sub 3} bitumen hydroprocessing catalyst

    SciTech Connect (OSTI)

    Richardson, S.M.; Nagaishi, Hiroshi; Gray, M.R. [Univ. of Alberta, Edmonton (Canada). Dept. of Chemical Engineering] [Univ. of Alberta, Edmonton (Canada). Dept. of Chemical Engineering

    1996-11-01T23:59:59.000Z

    Athabasca bitumen was hydrocracked over a commercial NiMo/{gamma}-Al{sub 2}O{sub 3} catalyst in two reactors, a microbatch reactor and a 1-L continuous stirred tank reactor (CSTR). Coke deposition on catalyst was measured as a function of hydrogen pressure, time on stream, and liquid composition by measuring the carbon content of the cleaned spent catalyst. The carbon content ranged from 11.3% to 17.6% over the pressure range 6.9--15.2 MPa in CSTR experiments. Batch and CSTR experiments showed a rapid approach to a constant coke content with increasing oil/catalyst ratio. Coke deposition was independent of product composition for residue concentrations ranging from 8% to 32% by weight. Removal of the coke by tetralin at reaction conditions suggested reversible adsorption of residue components on the catalyst surface. A physical model based on clearance of coke by hydrogen in the vicinity of metal crystallites is presented for the coke deposition behavior during the first several hours of hydrocracking use. This model gives good agreement with experimental data, including the effect of reaction time, the ratio of total feed weight to catalyst weight, hydrogen pressure, and feed composition, and it agrees with general observations from industrial usage. The model implies that except at the highest coke levels, the active surfaces of the metal crystallites remain exposed. Severe mass-transfer limitations are caused by the overall narrowing of the pore structure, which in {gamma}-Al{sub 2}O{sub 3} would give very low effective diffusivity for residuum molecules in micropores.

  20. March 1980 / Vol. 5, No. 3 / OPTICS LETTERS 117 Disk-shaped heat-pipe oven used for lithium excited-state

    E-Print Network [OSTI]

    Stroud, Carlos R.

    March 1980 / Vol. 5, No. 3 / OPTICS LETTERS 117 Disk-shaped heat-pipe oven used for lithium excited success- fully operated using both sodium and lithium as the working fluid. The lithium 4s 2 S 112 and 5s whosepressure is easily measured externally, the heat-pipe oven isolates the often corrosive vapor from windows

  1. Particle entanglement in rotating gases

    SciTech Connect (OSTI)

    Liu Zhao; Fan Heng [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

    2010-06-15T23:59:59.000Z

    In this paper, we investigate the particle entanglement in two-dimensional (2D) weakly interacting rotating Bose and Fermi gases. We find that both particle localization and vortex localization can be indicated by particle entanglement. We also use particle entanglement to show the occurrence of edge reconstruction of rotating fermions. The different properties of condensate phase and vortex liquid phase of bosons can be reflected by particle entanglement and in vortex liquid phase we construct the same trial wave function with that in [Phys. Rev. Lett. 87, 120405 (2001)] from the viewpoint of entanglement to relate the ground state with quantum Hall state. Finally, the relation between particle entanglement and interaction strength is studied.

  2. Granular gases under extreme driving

    E-Print Network [OSTI]

    W. Kang; J. Machta; E. Ben-Naim

    2010-08-06T23:59:59.000Z

    We study inelastic gases in two dimensions using event-driven molecular dynamics simulations. Our focus is the nature of the stationary state attained by rare injection of large amounts of energy to balance the dissipation due to collisions. We find that under such extreme driving, with the injection rate much smaller than the collision rate, the velocity distribution has a power-law high energy tail. The numerically measured exponent characterizing this tail is in excellent agreement with predictions of kinetic theory over a wide range of system parameters. We conclude that driving by rare but powerful energy injection leads to a well-mixed gas and constitutes an alternative mechanism for agitating granular matter. In this distinct nonequilibrium steady-state, energy cascades from large to small scales. Our simulations also show that when the injection rate is comparable with the collision rate, the velocity distribution has a stretched exponential tail.

  3. Demineralization of petroleum cokes and fly ash samples obtained from the upgrading of Athabasca oil sands bitumen

    SciTech Connect (OSTI)

    Majid, A.; Ratcliffe, C.I.; Ripmeester, J.A.

    1988-06-01T23:59:59.000Z

    Today's commercially proved technology to recover oil from the Athabasca oil sands, as practiced by Suncor and Syncrude, involves two major operations, namely: separation of the bitumen from the sand and upgrading of the bitumen to refinery oil. Significant amounts of petroleum coke are produced during the bitumen upgrading process. Suncor burns the bulk of its petroleum coke in boilers to fulfill the energy requirements of the entire operation, still meeting government regulations restricting the amount of sulfur dioxide that can be released to the environment. In contrast, Syncrude is able to burn only 20% of its coke production because of high sulphur dioxide emissions from elsewhere in its operations. The boiler ash (Fly ash) which contains appreciable amounts of metals, such as vanadium, nickel, titianium, iron, aluminum and other elements, is collected in the boiler hoppers and cyclones of the petroleum coke fired steam generation plants. There has been relatively little effort made towards the understanding of the chemical or physical nature of these materials. Knowledge of the physico-chemical properties of these materials will be helpful in assessing their beneficiation and potential use as fuel or metallurigcal coke and the feasibility of extracting some metals, especially Ni and V. In this communication the authors report studies of acid demineralization as a means of reducing ash content of these materials for /sup 13/C NMR spectroscopic investigations.

  4. Abstract--The paper reviews solutions being explored to face the supply problems faced in the Chilean electricity market oven

    E-Print Network [OSTI]

    Catholic University of Chile (Universidad Católica de Chile)

    and transportation of natural gas. Private investors were strongly behind the process, and invested heavily in the Chilean electricity market oven recent years, given unexpected restrictions in natural gas transfers from Argentina. Investment in generation came to a stall, given uncertainties in natural gas supply and the risk

  5. Improved wastewater treatment at Wheeling-Pittsburgh Steel Corporations`s Steubenville East Coke Plant

    SciTech Connect (OSTI)

    Goshe, A.J.; Nodianos, M.J. [Wheeling-Pittsburgh Steel Corp., Follansbee, WV (United States)

    1995-12-01T23:59:59.000Z

    Wheeling-Pittsburgh Steel Corporation recently improved its wastewater treatment at it`s by-products coke plant. This has led to greatly improved effluent quality. Excess ammonia liquor, along with wastewater from the light oil recovery plant, desulfurization facility, and coal pile runoff, must be treated prior to being discharged into the Ohio River. This is accomplished using a biological wastewater treatment plant to remove 99.99% of the organic contaminants and ammonia. Biologically treated, clarified wastewater is now polished in the newly constructed tertiary treatment plant.

  6. Operating temperature effects on nozzle coking in a cottonseed oil fueled diesel engine

    E-Print Network [OSTI]

    Yarbrough, Charles Michael

    1984-01-01T23:59:59.000Z

    J/'CA] volume rate of change [m /'CA) ? apparent rate of heat release [kJ/'CA] fuel air ratio [kg/kg] heat transfer coefficient [kJ/m 'K sec] ratio of specific heats connecting rod length [m] fuel lower heating value [kJ/kg] total mass of combustion gas...OPERATING TEMPERATURE EFFECTS ON NOZZLE COKING IN A COTTONSEED OIL FUELED DIESEL ENGINE A Thesis CHARLES MICHAEL YARBROUGH Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirements for the degree cf...

  7. An Infrared Spectral Database for Detection of Gases Emitted...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Database for Detection of Gases Emitted by Biomass Burning. An Infrared Spectral Database for Detection of Gases Emitted by Biomass Burning. Abstract: We report the construction of...

  8. atmospheric greenhouse gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GASES BACKGROUND CiteSeer Summary: The Earths climate depends on the amount of solar radiation received and the atmospheric abundance of clouds and greenhouse gases. The...

  9. aerosol precursor gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sunlight 11 GREENHOUSE GASES GREENHOUSE GASES BACKGROUND CiteSeer Summary: The Earths climate depends on the amount of solar radiation received and the atmospheric abundance of...

  10. Energy Efficiency and Greenhouse Gases | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Efficiency and Greenhouse Gases Energy Efficiency and Greenhouse Gases Mission The team establishes an energy conservation program, as deemed appropriate for LM operations...

  11. Light Collection in Liquid Noble Gases

    SciTech Connect (OSTI)

    McKinsey, Dan [Yale University

    2013-05-29T23:59:59.000Z

    Liquid noble gases are increasingly used as active detector materials in particle and nuclear physics. Applications include calorimeters and neutrino oscillation experiments as well as searches for neutrinoless double beta decay, direct dark matter, muon electron conversion, and the neutron electric dipole moment. One of the great advantages of liquid noble gases is their copious production of ultraviolet scintillation light, which contains information about event energy and particle type. I will review the scintillation properties of the various liquid noble gases and the means used to collect their scintillation light, including recent advances in photomultiplier technology and wavelength shifters.

  12. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

    2008-03-15T23:59:59.000Z

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  13. Denitrification of combustion gases. [Patent application

    DOE Patents [OSTI]

    Yang, R.T.

    1980-10-09T23:59:59.000Z

    A method for treating waste combustion gas to remove the nitrogen oxygen gases therefrom is disclosed wherein the waste gas is first contacted with calcium oxide which absorbs and chemically reacts with the nitrogen oxide gases therein at a temperature from about 100/sup 0/ to 430/sup 0/C. The thus reacted calcium oxide (now calcium nitrate) is then heated at a temperature range between about 430/sup 0/ and 900/sup 0/C, resulting in regeneration of the calcium oxide and production of the decomposition gas composed of nitrogen and nitrogen oxide gas. The decomposition gases can be recycled to the calcium oxide contacting step to minimize the amount of nitrogen oxide gases in the final product gas.

  14. Voluntary reporting of greenhouse gases, 1995

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    The Voluntary Reporting Program for greenhouse gases is part of an attempt by the U.S. Government to develop innovative, low-cost, and nonregulatory approaches to limit emissions of greenhouse gases. It is one element in an array of such programs introduced in recent years as part of the effort being made by the United States to comply with its national commitment to stabilize emissions of greenhouse gases under the Framework Convention on Climate Change. The Voluntary Reporting Program, developed pursuant to Section 1605(b) of the Energy Policy Act of 1992, permits corporations, government agencies, households, and voluntary organizations to report to the Energy Information Administration (EIA) on actions taken that have reduced or avoided emissions of greenhouse gases.

  15. Production of ethanol from refinery waste gases. Phase 2, technology development, annual report

    SciTech Connect (OSTI)

    Arora, D.; Basu, R.; Phillips, J.R.; Wikstrom, C.V.; Clausen, E.C.; Gaddy, J.L.

    1995-07-01T23:59:59.000Z

    Oil refineries discharge large volumes of H{sub 2}, CO, and CO{sub 2} from cracking, coking, and hydrotreating operations. This program seeks to develop a biological process for converting these waste gases into ethanol, which can be blended with gasoline to reduce emissions. Production of ethanol from all 194 US refineries would save 450 billion BTU annually, would reduce crude oil imports by 110 million barrels/year and emissions by 19 million tons/year. Phase II efforts has yielded at least 3 cultures (Clostridium ljungdahlii, Isolate O-52, Isolate C-01) which are able to produce commercially viable concentrations of ethanol from CO, CO{sub 2}, and H{sub 2} in petroleum waste gas. Single continuous stirred tank reactor studies have shown that 15-20 g/L of ethanol can be produced, with less than 5 g/L acetic acid byproduct. Culture and reactor optimization in Phase III should yield even higher ethanol concentrations and minimal acetic acid. Product recovery studies showed that ethanol is best recovered in a multi-step process involving solvent extraction/distillation to azeotrope/azeotropic distillation or pervaporation, or direct distillation to the azeotrope/azeotropic distillation or pervaporation. Projections show that the ethanol facility for a typical refinery would require an investment of about $30 million, which would be returned in less than 2 years.

  16. Petroleum Coke

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghurajiConventionalMississippi"site. IfProved(MillionPrice (Percent)82,516 82,971 84,053 85,190

  17. Petroleum Coke

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for On-Highway4,1,50022,3,,,,6,1,9,1,50022,3,,,,6,1,Decade1 Source: Office(BillionYearPricePrice (Percent)theCity

  18. HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Greenhouse gases andGreenhouse gases and

    E-Print Network [OSTI]

    Zevenhoven, Ron

    in gas turbinecombustion in gas turbine HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Effect of COEffect-depleting gases ·· COCO22 removal for gas purificationremoval for gas purification ·· COCO22 removal for greenhouse gas emissions reductionremoval for greenhouse gas emissions reduction ·· Other greenhouse gases

  19. Cyanide leaching from soil developed from coking plant purifier waste as influenced by citrate

    SciTech Connect (OSTI)

    Tim Mansfeldt; Heike Leyer; Kurt Barmettler; Ruben Kretzschmar [Ruhr-University Bochum, Bochum (Germany). Soil Science and Soil Ecology Group, Faculty of Geosciences

    2004-07-01T23:59:59.000Z

    Soils in the vicinity of manufactured gas plants and coal coking plants are often highly contaminated with cyanides in the form of the compound Prussian blue. The objective of this study was to investigate the influence of citrate on the leaching of iron-cyanide complexes from an extremely acidic soil (pH 2.3) developed from gas purifier waste near a former coking plant. The soil contained 63 g kg{sup -1} CN, 148 g kg{sup -1} Fe, 123 g kg{sup -1} S, and 222 g kg{sup -1} total C. Analysis of the soil by X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectroscopy revealed the presence of Prussian blue, gypsum, elemental sulfur, jarosite, and hematite. For column leaching experiments, air-dried soil was mixed with purified cristabolite sand at a ratio of 1:3 and packed into chromatography columns. The soil was leached with dilute (0.1 or 1 mM) CaCl{sub 2} solutions and the effluent was collected and analyzed for total and dissolved CN, Ca, Fe, SO{sub 4}, pH, and pe. In the absence of citrate, the total dissolved CN concentration in the effluent was always below current drinking water limits (< 1.92 {mu}M), indicating low leaching potential. Adding citrate at a concentration of 1 mM had little effect on the CN concentrations in the column effluent. Addition of 10 or 100 mM citrate to the influent solution resulted in strong increases in dissolved and colloidal CN concentrations in the effluent.

  20. Where do California's greenhouse gases come from?

    ScienceCinema (OSTI)

    Fischer, Marc

    2013-05-29T23:59:59.000Z

    Last March, more than two years after California passed legislation to slash greenhouse gas emissions 25 percent by 2020, Lawrence Berkeley National Laboratory scientist Marc Fischer boarded a Cessna loaded with air monitoring equipment and crisscrossed the skies above Sacramento and the Bay Area. Instruments aboard the aircraft measured a cocktail of greenhouse gases: carbon dioxide from fossil fuel use, methane from livestock and landfills, CO2 from refineries and power plants, traces of nitrous oxide from agriculture and fuel use, and industrially produced other gases like refrigerants. The flight was part of the Airborne Greenhouse Gas Emissions Survey, a collaboration between Berkeley Lab, the National Oceanic and Atmospheric Administration, and the University of California, and UC Davis to pinpoint the sources of greenhouse gases in central California. The survey is intended to improve inventories of the states greenhouse gas emissions, which in turn will help scientists verify the emission reductions mandated by AB-32, the legislation enacted by California in 2006.

  1. Stationary light in cold atomic gases

    E-Print Network [OSTI]

    Gor Nikoghosyan; Michael Fleischhauer

    2009-09-16T23:59:59.000Z

    We discuss stationary light created by a pair of counter-propagating control fields in Lambda-type atomic gases with electromagnetically induced transparency for the case of negligible Doppler broadening. In this case the secular approximation used in the discussion of stationary light in hot vapors is no longer valid. We discuss the quality of the effective light-trapping system and show that in contrast to previous claims it is finite even for vanishing ground-state dephasing. The dynamics of the photon loss is in general non exponential and can be faster or slower than in hot gases.

  2. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOE Patents [OSTI]

    Turick, Charles E. (Idaho Falls, ID)

    1997-01-01T23:59:59.000Z

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases.

  3. Method for enhancing microbial utilization rates of gases using perfluorocarbons

    DOE Patents [OSTI]

    Turick, C.E.

    1997-06-10T23:59:59.000Z

    A method of enhancing the bacterial reduction of industrial gases using perfluorocarbons (PFCs) is disclosed. Because perfluorocarbons (PFCs) allow for a much greater solubility of gases than water does, PFCs have the potential to deliver gases in higher concentrations to microorganisms when used as an additive to microbial growth media thereby increasing the rate of the industrial gas conversion to economically viable chemicals and gases. 3 figs.

  4. The safe use of low temperature liquefied gases 1. Introduction

    E-Print Network [OSTI]

    Martin, Ralph R.

    dioxide TABLE 1 Property Oxygen (O2) Nitrogen (N2) Argon (Ar) Helium (He) Carbon dioxide (CO2) Molecular.1 Objective 1.2 Gases considered and typical uses 2. Properties of low temperature liquefied atmospheric gases of BOC low temperature liquefied gases information on their properties, the hazards associated

  5. New fluorescence techniques for detecting noble gases

    SciTech Connect (OSTI)

    Whitaker, T.J.; Cannon, B.D.; Bushaw, B.A.

    1986-10-01T23:59:59.000Z

    Two new concepts for detecting noble gases are reported. Both techniques involve formation of the long-lived 1s/sup 5/ metastable state of noble gases. The first technique utilizes the photon-burst method and should be capable of isotopically selective detection at extremely small relative abundances. The second concept incorporates a shelving technique that stores noble gas atoms in the metastable state and then pumps these atoms to a higher excited state that radiatively cascades to the ground state, emitting vacuum ultraviolet (vuv) photons. A significant advantage is that AlGaAs diode lasers can be used for the techniques rather than continuous wave cw dye lasers. 5 refs., 1 fig.

  6. Effects of HyperCoal addition on coke strength and thermoplasticity of coal blends

    SciTech Connect (OSTI)

    Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito [National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan). Energy Technology Research Institute

    2008-05-15T23:59:59.000Z

    Ashless coal, also known as HyperCoal (HPC), was produced by thermal extraction of three coals of different ranks (Gregory caking coal, Warkworth steam coal, and Pasir subbituminous coal) with 1-methylnaphthalene (1-MN) at 360, 380, and 400{sup o}C. The effects of blending these HPCs into standard coal blends were investigated. Blending HPCs as 5-10% of a standard blend (Kouryusho:Goonyella:K9) enhanced the thermoplasticity over a wide temperature range. For blends made with the Pasir-HPC, produced from a noncaking coal, increasing the extraction temperature from 360 to 400{sup o}C increased the thermoplasticity significantly. Blends containing Warkworth-HPC, produced from a slightly caking coal, had a higher tensile strength than the standard blend in semicoke strength tests. The addition of 10% Pasir-HPC, extracted at 400{sup o}C, increased the tensile strength of the semicokes to the same degree as those made with Gregory-HPC. Furthermore, all HPC blends had a higher tensile strength and smaller weight loss during carbonization. These results suggest that the HPC became integrated into the coke matrix, interacting strongly with the other raw coals. 14 refs., 11 figs., 1 tab.

  7. Glass Membrane For Controlled Diffusion Of Gases

    DOE Patents [OSTI]

    Shelby, James E. (Alfred Station, NY); Kenyon, Brian E. (Pittsburgh, PA)

    2001-05-15T23:59:59.000Z

    A glass structure for controlled permeability of gases includes a glass vessel. The glass vessel has walls and a hollow center for receiving a gas. The glass vessel contains a metal oxide dopant formed with at least one metal selected from the group consisting of transition metals and rare earth metals for controlling diffusion of the gas through the walls of the glass vessel. The vessel releases the gas through its walls upon exposure to a radiation source.

  8. Scanning electron microscopy of cold gases

    E-Print Network [OSTI]

    Santra, Bodhaditya

    2015-01-01T23:59:59.000Z

    Ultracold quantum gases offer unique possibilities to study interacting many-body quantum systems. Probing and manipulating such systems with ever increasing degree of control requires novel experimental techniques. Scanning electron microscopy is a high resolution technique which can be used for in situ imaging, single site addressing in optical lattices and precision density engineering. Here, we review recent advances and achievements obtained with this technique and discuss future perspectives.

  9. Method for introduction of gases into microspheres

    DOE Patents [OSTI]

    Hendricks, Charles D. (Livermore, CA); Koo, Jackson C. (San Ramon, CA); Rosencwaig, Allan (Danville, CA)

    1981-01-01T23:59:59.000Z

    A method for producing small hollow glass spheres filled with a gas by introduction of the gas during formation of the hollow glass spheres. Hollow glass microspheres having a diameter up to about 500.mu. with both thin walls (0.5 to 4.mu.) and thick walls (5 to 20.mu.) that contain various fill gases, such as Ar, Kr, Xe, Br, DT, H.sub.2, D.sub.2, He, N.sub.2, Ne, CO.sub.2, etc. in the interior thereof, can be produced by the diffusion of the fill gas or gases into the microsphere during the formation thereof from a liquid droplet of glass-forming solution. This is accomplished by filling at least a portion of the multiple-zone drop-furnace used in producing hollow microspheres with the gas or gases of interest, and then taking advantage of the high rate of gaseous diffusion of the fill gas through the wall of the gel membrane before it transforms into a glass microsphere as it is processed in the multiple-zone furnace. Almost any gas can be introduced into the inner cavity of a glass microsphere by this method during the formation of the microsphere provided that the gas is diffused into the gel membrane or microsphere prior to its transformation into glass. The process of this invention provides a significant savings of time and related expense of filling glass microspheres with various gases. For example, the time for filling a glass microballoon with 1 atmosphere of DT is reduced from about two hours to a few seconds.

  10. Seeded optical breakdown of molecular and noble gases

    SciTech Connect (OSTI)

    Polynkin, Pavel; Scheller, Maik; Moloney, Jerome V. [College of Optical Sciences, University of Arizona 1630 E. University Blvd., Tucson, Arizona 85721 (United States)

    2012-07-30T23:59:59.000Z

    We report experimental results on the dual laser-pulse plasma excitation in various gases at atmospheric pressure. Dilute plasma channels generated through filamentation of ultraintense femtosecond laser pulses in air, argon, and helium are densified through the application of multi-Joule nanosecond heater pulses. Optical breakdown in atomic gases can be achieved for considerably longer delays between femtosecond and nanosecond pulses compared to that in molecular gases. The densification of the seed channel in molecular gases is always accompanied by its fragmentation into discrete bubbles, while in atomic gases the densified channel remains smooth and continuous.

  11. "Diffusion of Innovation: Solar Oven Use in Lesotho (Africa)." Grundy, William and Roy Grundy. Advances in Solar Cooking: Proceedings of the 2nd International Conference on Solar Cooker Use and Technology. Shyam S. Nandwani, ed. July 12-15, 1994.

    E-Print Network [OSTI]

    Noble, William Stafford

    "Diffusion of Innovation: Solar Oven Use in Lesotho (Africa)." Grundy, William and Roy Grundy. Advances in Solar Cooking: Proceedings of the 2nd International Conference on Solar Cooker Use and Technology. Shyam S. Nandwani, ed. July 12-15, 1994. pp. 240-247. 1 DIFFUSION OF INNOVATION: SOLAR OVEN USE

  12. Purchase, Delivery, and Storage of Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)IntegratedSpeedingTechnicalPurchase, Delivery, and Storage of Gases Print ALS users

  13. Method for controlling corrosion in thermal vapor injection gases

    DOE Patents [OSTI]

    Sperry, John S. (Houston, TX); Krajicek, Richard W. (Houston, TX)

    1981-01-01T23:59:59.000Z

    An improvement in the method for producing high pressure thermal vapor streams from combustion gases for injection into subterranean oil producing formations to stimulate the production of viscous minerals is described. The improvement involves controlling corrosion in such thermal vapor gases by injecting water near the flame in the combustion zone and injecting ammonia into a vapor producing vessel to contact the combustion gases exiting the combustion chamber.

  14. The greenhouse gases HFCs, PFCs Danish consumption and emissions, 2007

    E-Print Network [OSTI]

    The greenhouse gases HFCs, PFCs and SF6 Danish consumption and emissions, 2007 Tomas Sander Poulsen AND EMISSION OF F-GASES 7 1.1.1 Consumption 7 1.1.2 Emission 7 1.1.3 Trends in total GWP contribution from F 21 4 EMISSION OF F-GASES 23 4.1.1 Emissions of HFCs from refrigerants 23 4.1.2 Emissions of HFCs from

  15. Theory of ultracold atomic Fermi gases

    SciTech Connect (OSTI)

    Giorgini, Stefano; Pitaevskii, Lev P.; Stringari, Sandro [Dipartimento di Fisica, Universita di Trento and CNR-INFM BEC Center, I-38050 Povo, Trento (Italy); Dipartimento di Fisica, Universita di Trento and CNR-INFM BEC Center, I-38050 Povo, Trento, Italy and Kapitza Institute for Physical Problems, ul. Kosygina 2, 117334 Moscow (Russian Federation); Dipartimento di Fisica, Universita di Trento and CNR-INFM BEC Center, I-38050 Povo, Trento (Italy)

    2008-10-15T23:59:59.000Z

    The physics of quantum degenerate atomic Fermi gases in uniform as well as in harmonically trapped configurations is reviewed from a theoretical perspective. Emphasis is given to the effect of interactions that play a crucial role, bringing the gas into a superfluid phase at low temperature. In these dilute systems, interactions are characterized by a single parameter, the s-wave scattering length, whose value can be tuned using an external magnetic field near a broad Feshbach resonance. The BCS limit of ordinary Fermi superfluidity, the Bose-Einstein condensation (BEC) of dimers, and the unitary limit of large scattering length are important regimes exhibited by interacting Fermi gases. In particular, the BEC and the unitary regimes are characterized by a high value of the superfluid critical temperature, on the order of the Fermi temperature. Different physical properties are discussed, including the density profiles and the energy of the ground-state configurations, the momentum distribution, the fraction of condensed pairs, collective oscillations and pair-breaking effects, the expansion of the gas, the main thermodynamic properties, the behavior in the presence of optical lattices, and the signatures of superfluidity, such as the existence of quantized vortices, the quenching of the moment of inertia, and the consequences of spin polarization. Various theoretical approaches are considered, ranging from the mean-field description of the BCS-BEC crossover to nonperturbative methods based on quantum Monte Carlo techniques. A major goal of the review is to compare theoretical predictions with available experimental results.

  16. New Materials for Capturing Carbon Dioxide from Combustion Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to APS Science Highlights rss feed New Materials for Capturing Carbon Dioxide from Combustion Gases April 9, 2014 Bookmark and Share The SIFSIX materials in order of increasing...

  17. adjacente dos gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nature Le Roy, Robert J. 437 Classical disordered ground states: Super-ideal gases and stealth and equi-luminous materials Chemistry Websites Summary: Classical disordered...

  18. Finalize Historic National Program to Reduce Greenhouse Gases...

    Open Energy Info (EERE)

    Finalize Historic National Program to Reduce Greenhouse Gases and Improve Fuel Economy for Cars and Trucks Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Finalize...

  19. Dispersion modeling of polycyclic aromatic hydrocarbons from combustion of biomass and fossil fuels and production of coke in Tianjin, China

    SciTech Connect (OSTI)

    Shu Tao; Xinrong Li; Yu Yang; Raymond M. Coveney, Jr.; Xiaoxia Lu; Haitao Chen; Weiran Shen [Peking University, Beijing (China). Laboratory for Earth Surface Processes, College of Environmental Sciences

    2006-08-01T23:59:59.000Z

    A USEPA procedure, ISCLT3 (Industrial Source Complex Long-Term), was applied to model the spatial distribution of polycyclic aromatic hydrocarbons (PAHs) emitted from various sources including coal, petroleum, natural gas, and biomass into the atmosphere of Tianjin, China. Benzo(a)pyrene equivalent concentrations (BaPeq) were calculated for risk assessment. Model results were provisionally validated for concentrations and profiles based on the observed data at two monitoring stations. The dominant emission sources in the area were domestic coal combustion, coke production, and biomass burning. Mainly because of the difference in the emission heights, the contributions of various sources to the average concentrations at receptors differ from proportions emitted. The shares of domestic coal increased from {approximately} 43% at the sources to 56% at the receptors, while the contributions of coking industry decreased from {approximately} 23% at the sources to 7% at the receptors. The spatial distributions of gaseous and particulate PAHs were similar, with higher concentrations occurring within urban districts because of domestic coal combustion. With relatively smaller contributions, the other minor sources had limited influences on the overall spatial distribution. The calculated average BaPeq value in air was 2.54 {+-} 2.87 ng/m{sup 3} on an annual basis. Although only 2.3% of the area in Tianjin exceeded the national standard of 10 ng/m{sup 3}, 41% of the entire population lives within this area. 37 refs., 9 figs.

  20. Finite Temperature Gases of Fermionic Strings

    E-Print Network [OSTI]

    Shyamoli Chaudhuri

    2005-09-12T23:59:59.000Z

    We show that in the absence of a Ramond-Ramond sector both the type IIA and type IIB free string gases have a thermal instability due to low temperature tachyon modes. The gas of free IIA strings undergoes a thermal duality transition into a gas of free IIB strings at the self-dual temperature. The free heterotic string gas is a tachyon-free ensemble with gauge symmetry SO(16)$\\times$SO(16) in the presence of a timelike Wilson line background. It exhibits a holographic duality relation undergoing a self-dual phase transition with positive free energy and positive specific heat. The type IB open and closed string ensemble is related by thermal duality to the type I' string ensemble. We identify the order parameter for the Kosterlitz-Thouless phase transition from a low temperature gas of short open strings to a high temperature long string phase at or below T_C. Note Added (Sep 2005).

  1. Voluntary reporting of greenhouse gases 1997

    SciTech Connect (OSTI)

    NONE

    1999-05-01T23:59:59.000Z

    The Voluntary Reporting of Greenhouse Gases Program, required by Section 1605(b) of the Energy Policy Act of 1992, records the results of voluntary measures to reduce, avoid, or sequester greenhouse gas emissions. In 1998, 156 US companies and other organizations reported to the Energy information Administration that, during 1997, they had achieved greenhouse gas emission reductions and carbon sequestration equivalent to 166 million tons of carbon dioxide, or about 2.5% of total US emissions for the year. For the 1,229 emission reduction projects reported, reductions usually were measured by comparing an estimate of actual emissions with an estimate of what emissions would have been had the project not been implemented.

  2. Continuous cryopump with a method for removal of solidified gases

    DOE Patents [OSTI]

    Carlson, L.W.; Herman, H.

    1988-05-05T23:59:59.000Z

    An improved cryopump for the removal of gases from a high vacuum, comprising a cryopanel incorporating honeycomb structure, refrigerant means thermally connected to the cryopanel, and a rotatable channel moving azimuthally around an axis located near the center of the cryopanel, removing gases adsorbed within the honeycomb structure by subliming them and conducting them outside the vacuum vessel. 4 figs.

  3. AMIII Termodinamica dos Gases Ideais 17 de Janeiro de 2002

    E-Print Network [OSTI]

    Natário, José

    AMIII ­ Termodinâ??amica dos Gases Ideais 17 de Janeiro de 2002 N moles de um gâ??as ideal em equil dos gases ideais). A Primeira Lei da Termodinâ??amica afirma que existe uma funâ?şcâ?ťao E : M # R, dita pela Segunda Lei da Termodinâ??amica. 2 #12;

  4. Biological Removal of Siloxanes from Landfill and Digester Gases

    E-Print Network [OSTI]

    Biological Removal of Siloxanes from Landfill and Digester Gases: Opportunities and Challenges S U) presents challenges for using landfill and digester gases as energy fuels because of the formation volatilize from waste at landfills and wastewater treatment plants (1). As a result, biogas produced

  5. Measurement of transient nonlinear refractive index in gases using xenon

    E-Print Network [OSTI]

    Milchberg, Howard

    Measurement of transient nonlinear refractive index in gases using xenon supercontinuum single measurement of ultrafast high field processes using modest energy lasers, with pump and probe pulses totaling) and instrument resolution. The ultrafast nonlinear Kerr effect in glass, and in Ar, N2, and N2O gases is measured

  6. Study on the effect of heat treatment and gasification on the carbon structure of coal chars and metallurgical cokes using fourier transform Raman spectroscopy

    SciTech Connect (OSTI)

    S. Dong; P. Alvarez; N. Paterson; D.R. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

    2009-03-15T23:59:59.000Z

    Differences in the development of carbon structures between coal chars and metallurgical cokes during high-temperature reactions have been investigated using Raman spectroscopy. These are important to differentiate between different types of carbons in dust recovered from the top gas of the blast furnace. Coal chars have been prepared from a typical injectant coal under different heat-treatment conditions. These chars reflected the effect of peak temperature, residence time at peak temperature, heating rate and pressure on the evolution of their carbon structures. The independent effect of gasification on the development of the carbon structure of a representative coal char has also been studied. A similar investigation has also been carried out to study the effect of heat-treatment temperature (from 1300 to 2000{sup o}C) and gasification on the carbon structure of a typical metallurgical coke. Two Raman spectral parameters, the intensity ratio of the D band to the G band (I{sub D}/I{sub G}) and the intensity ratio of the valley between D and G bands to the G band (I{sub V}/I{sub G}), have been found useful in assessing changes in carbon structure. An increase in I{sub D}/I{sub G} indicates the growth of basic graphene structural units across the temperature range studied. A decrease in I{sub V}/I{sub G} appears to suggest the elimination of amorphous carbonaceous materials and ordering of the overall carbon structure. The Raman spectral differences observed between coal chars and metallurgical cokes are considered to result from the difference in the time-temperature history between the raw injectant coal and the metallurgical coke and may lay the basis for differentiation between metallurgical coke fines and coal char residues present in the dust carried over the top of the blast furnace. 41 refs., 17 figs., 3 tabs.

  7. Measuring non-condensable gases in steam

    SciTech Connect (OSTI)

    Doornmalen, J. P. C. M. van; Kopinga, K., E-mail: k.kopinga@tue.nl [Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven (Netherlands)

    2013-11-15T23:59:59.000Z

    In surgery, medical devices that are used should be sterilized. To obtain surface steam sterilization conditions, not only in the sterilizer chamber itself but also in the loads to be sterilized, the amount of non-condensable gases (NCGs), for instance air, should be very low. Even rather small fractions of NCGs (below 1 %) seriously hamper steam penetration in porous materials or devices with hollow channels (e.g., endoscopes). A recently developed instrument which might detect the presence of residual NCGs in a reliable and reproducible way is the 3M{sup TM} Electronic Test System (ETS). In this paper, a physical model is presented that describes the behavior of this instrument. This model has been validated by experiments in which known fractions of NCGs were introduced in a sterilizer chamber in which an ETS was placed. Despite several approximations made in the model, a good agreement is found between the model predictions and the experimental results. The basic principle of the ETS, measuring the heat transfer by condensation on a cooled surface, permits a very sensitive detection of NCGs in harsh environments like water vapor at high temperatures and pressures. Our model may serve to develop adapted and optimized versions of this instrument for use outside the field of sterilization, e.g., in heat exchangers based on steam condensation.

  8. Supplement of Atmos. Chem. Phys., 14, 65716603, 2014 http://www.atmos-chem-phys.net/14/6571/2014/

    E-Print Network [OSTI]

    Pierce, Jeffrey

    for coal-charging process 0 0 0 0 10 10 0 FGD for coke oven gas 0 0 0 0 10 10 0 Combination[1] BAU[2]/PC[2] 2005 2010 2020 2030 2020 2030 2030 Sintering FGD 0 10 20 40 95 100 100 Coke oven FGD 100 Hot rolling ESP 0 0 0 0 70 95 100 Cold rolling HED 0 0 0 0 70 95 100 Coke oven WET 100 100 100 100

  9. 7, 14791506, 2007 apportionment of the

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , coal residential, coke oven, coal power plant, biomass burning, natural gas (NG) combustion. The major showed distinct seasonal variations. High contributions of biomass burning and coal (residential and coke is the world's largest coal consumption region (IEA, 2006). Thu

  10. Cryogenic method for measuring nuclides and fission gases

    DOE Patents [OSTI]

    Perdue, P.T.; Haywood, F.F.

    1980-05-02T23:59:59.000Z

    A cryogenic method is provided for determining airborne gases and particulates from which gamma rays are emitted. A special dewar counting vessel is filled with the contents of the sampling flask which is immersed in liquid nitrogen. A vertically placed sodium-iodide or germanium-lithium gamma-ray detector is used. The device and method are of particular use in measuring and identifying the radioactive noble gases including emissions from coal-fired power plants, as well as fission gases released or escaping from nuclear power plants.

  11. EA-0404: Finding of No Significant Impact

    Broader source: Energy.gov [DOE]

    Innovative Clean Coal Technology Program - Coke Oven Gas Cleaning Demonstration Project at the Bethlehem Steel Corp. Sparrows Point Plant, Baltimore County, Maryland

  12. brwtp-icoke | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Dec 1989) Comprehensive Report to Congress Comprehensive Report to Congress on the Clean Coal Technology Program: Innovative Coke Oven Gas Cleaning System for Retrofit...

  13. Viscosities of natural gases at high pressures and high temperatures

    E-Print Network [OSTI]

    Viswanathan, Anup

    2007-09-17T23:59:59.000Z

    Estimation of viscosities of naturally occurring petroleum gases provides the information needed to accurately work out reservoir-engineering problems. Existing models for viscosity prediction are limited by data, especially at high pressures...

  14. Studying coherence in ultra-cold atomic gases

    E-Print Network [OSTI]

    Miller, Daniel E. (Daniel Edward)

    2007-01-01T23:59:59.000Z

    This thesis will discuss the study of coherence properties of ultra-cold atomic gases. The atomic systems investigated include a thermal cloud of atoms, a Bose-Einstein condensate and a fermion pair condensate. In each ...

  15. The Release of Trapped Gases from Amorphous Solid Water Films...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    I. Top-Down" Crystallization-Induced Crack Propagation Probed The Release of Trapped Gases from Amorphous Solid Water Films: I. Top-Down" Crystallization-Induced Crack Propagation...

  16. Low-Value Waste Gases as an Energy Source 

    E-Print Network [OSTI]

    Waibel, R. T.

    1996-01-01T23:59:59.000Z

    Waste gases with potentially useful fuel value are generated at any number of points in refineries, chemical plants and other industrial and commercial sites. The higher quality streams have been utilized successfully in fuel systems for years...

  17. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, C.R.; Ernstberger, E.G.

    1985-07-03T23:59:59.000Z

    A method for monitoring the stack gases of a purge cascade of gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases. 1 fig.

  18. Helium Isotopes in Geothermal and Volcanic Gases of the Western...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Helium Isotopes in Geothermal and Volcanic Gases of the Western United States, II. Long...

  19. Helium Isotopes In Geothermal And Volcanic Gases Of The Western...

    Open Energy Info (EERE)

    Helium Isotopes In Geothermal And Volcanic Gases Of The Western United States, I, Regional Variability And Magmatic Origin Jump to: navigation, search OpenEI Reference LibraryAdd...

  20. Geochemical Data on Waters, Gases, Scales, and Rocks from the...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Geochemical Data on Waters, Gases, Scales, and Rocks from the Dixie Valley Region, Nevada (1996-1999)...

  1. Low-Value Waste Gases as an Energy Source

    E-Print Network [OSTI]

    Waibel, R. T.

    Waste gases with potentially useful fuel value are generated at any number of points in refineries, chemical plants and other industrial and commercial sites. The higher quality streams have been utilized successfully in fuel systems for years...

  2. Radio-frequency spectroscopy of ultracold atomic Fermi gases

    E-Print Network [OSTI]

    Schirotzek, Andre

    2010-01-01T23:59:59.000Z

    This thesis presents experiments investigating the phase diagram of ultracold atomic Fermi gases using radio-frequency spectroscopy. The tunability of many experimental parameters including the temperature, the interparticle ...

  3. Method of producing pyrolysis gases from carbon-containing materials

    DOE Patents [OSTI]

    Mudge, Lyle K. (Richland, WA); Brown, Michael D. (West Richland, WA); Wilcox, Wayne A. (Kennewick, WA); Baker, Eddie G. (Richland, WA)

    1989-01-01T23:59:59.000Z

    A gasification process of improved efficiency is disclosed. A dual bed reactor system is used in which carbon-containing feedstock materials are first treated in a gasification reactor to form pyrolysis gases. The pyrolysis gases are then directed into a catalytic reactor for the destruction of residual tars/oils in the gases. Temperatures are maintained within the catalytic reactor at a level sufficient to crack the tars/oils in the gases, while avoiding thermal breakdown of the catalysts. In order to minimize problems associated with the deposition of carbon-containing materials on the catalysts during cracking, a gaseous oxidizing agent preferably consisting of air, oxygen, steam, and/or mixtures thereof is introduced into the catalytic reactor at a high flow rate in a direction perpendicular to the longitudinal axis of the reactor. This oxidizes any carbon deposits on the catalysts, which would normally cause catalyst deactivation.

  4. Method for monitoring stack gases for uranium activity

    DOE Patents [OSTI]

    Beverly, Claude R. (Paducah, KY); Ernstberger, Harold G. (Paducah, KY)

    1988-01-01T23:59:59.000Z

    A method for monitoring the stack gases of a purge cascade of a gaseous diffusion plant for uranium activity. A sample stream is taken from the stack gases and contacted with a volume of moisture-laden air for converting trace levels of uranium hexafluoride, if any, in the stack gases into particulate uranyl fluoride. A continuous strip of filter paper from a supply roll is passed through this sampling stream to intercept and gather any uranyl fluoride in the sampling stream. This filter paper is then passed by an alpha scintillation counting device where any radioactivity on the filter paper is sensed so as to provide a continuous monitoring of the gas stream for activity indicative of the uranium content in the stack gases.

  5. active trace gases: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OF GEOPHYSICAL RESEARCH, VOL. 94, NO. D13, PAGES 16,417-16,421,NOVEMBER 20, 1989 Greenhouse Effect of Chlorofluorocarbons and Other Trace Gases Environmental Sciences and Ecology...

  6. Production of ethanol from refinery waste gases. Phase 3. Engineering development. Annual report, April 1, 1995--May 15, 1996

    SciTech Connect (OSTI)

    Arora, D.; Basu, R.; Phillips, J.R.; Wikstrom, C.V.; Clausen, E.C; Gaddy, J.L.

    1996-11-01T23:59:59.000Z

    Refineries discharge large volumes of H2, CO, and CO 2 from cracking, coking, and hydrotreating operations. This R&D program seeks to develop, demonstrate, and commercialize a biological process for converting these waste gases into ethanol for blending with gasoline. A 200,000 BPD refinery could produce up to 38 million gallons ethanol per year. The program is being conducted in 3 phases: II, technology development; III, engineering development; and IV, demonstration. Phase I, exploratory development, has been completed. The research effort has yielded two strains (Isolates O-52 and C-01) which are to be used in the pilot studies to produce ethanol from CO, CO2, and H2 in petroleum waste gas. Results from single continuous stirred tank reactor (CSTR) laboratory tests have shown that 20-25 g/L ethanol can be produced with < 5 g/L acetic acid byproduct. Laboratory studies with two CSTRs in series have yielded ethanol concentrations of 30-35 g/L with 2-4 g/L acetic acid byproduct. Water recycle from distillation back to the fermenter shows that filtration of the water before distillation eliminates the recycle of toxic materials back to the fermenter. Product recovery in the process will use direct distillation to the azeotrope, followed by adsorption to produce neat ethanol. This is less energy intensive than e.g. solvent extraction, azeotropic distillation, or pervaporation. Economic projections are quite attractive; the economics are refinery stream dependent and thus vary depending on refinery location and operation.

  7. Process for the removal of acid forming gases from exhaust gases

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (San Pablo, CA)

    1992-01-01T23:59:59.000Z

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. are attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO and SO.sub.2 can be removed in an economic fashion.

  8. Process for the removal of acid forming gases from exhaust gases

    DOE Patents [OSTI]

    Chang, S.G.; Liu, D.K.

    1992-11-17T23:59:59.000Z

    Exhaust gases are treated to remove NO or NO[sub x] and SO[sub 2] by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50 C is attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO[sub x] and SO[sub 2], alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO[sub x] and SO[sub 2] can be removed in an economic fashion. 9 figs.

  9. Chapter 4 The Gaseous State Chemistry of Gases

    E-Print Network [OSTI]

    Ihee, Hyotcherl

    .15 V = V0[1+(t/273.15oC)] Kelvin T = 273.15 + t(Celsius) #12;Boyle's Law · The stirling engine, a heatChapter 4 The Gaseous State NO2 #12;AIR #12;Chemistry of Gases SO3 .. corrosive gas SO2...burning) ~1760 Charle The definition of the Temperature All gases expand with increasing temperature by the same

  10. Further investigation of the impact of the co-combustion of tire-derived fuel and petroleum coke on the petrology and chemistry of coal combustion products

    SciTech Connect (OSTI)

    Hower, J.C.; Robertson, J.D.; Elswick, E.R.; Roberts, J.M.; Brandsteder, K.; Trimble, A.S.; Mardon, S.M. [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    2007-07-01T23:59:59.000Z

    A Kentucky cyclone-fired unit burns coal and tire-derived fuel, sometimes in combination with petroleum coke. A parallel pulverized combustion (pc) unit at the same plant burns the same coal, without the added fuels. The petrology, chemistry, and sulfur isotope distribution in the fuel and resulting combustion products was investigated for several configurations of the fuel blend. Zinc and Cd in the combustion products are primarily contributed from the tire-derived fuel, the V and Ni are primarily from the petroleum coke, and the As and Hg are probably largely from the coal. The sulfur isotope distribution in the cyclone unit is complicated due to the varying fuel sources. The electrostatic precipitator (ESP) array in the pc unit shows a subtle trend towards heavier S isotopic ratios in the cooler end of the ESP.

  11. Determination of the effect of different additives in coking blends using a combination of in situ high-temperature {sup 1}H NMR and rheometry

    SciTech Connect (OSTI)

    Miguel C. Diaz; Karen M. Steel; Trevor C. Drage; John W. Patrick; Colin E. Snape [Nottingham University, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

    2005-12-01T23:59:59.000Z

    High-temperature {sup 1}H NMR and rheometry measurements were carried out on 4:1 wt/wt blends of a medium volatile bituminous coal with two anthracites, two petroleum cokes, charcoal, wood, a low-temperature coke breeze, tyre crumb, and active carbon to determine the effects on fluidity development to identify the parameters responsible for these effects during pyrolysis and to study possible relationships among the parameters derived from these techniques. Positive, negative, and neutral effects were identified on the concentration of fluid material. Small positive effects (ca. 5-6%) were caused by blending the coal with petroleum cokes. Charcoal, wood, and active carbon all exerted negative effects on concentration (18-27% reduction) and mobility (12-25% reduction in T2) of the fluid phase, which have been associated with the inert character and high surface areas of these additives that adsorb the fluid phase of the coal. One of the anthracites and the low-temperature coke breeze caused deleterious effects to a lesser extent on the concentration (7-12%) and mobility (13-17%) of the fluid material, possibly due to the high concentration of metals in these additives (ca. 11% ash). Despite the high fluid character of tyre crumb at the temperature of maximum fluidity of the coal (73%), the mobility of the fluid phase of the blend was lower than expected. The comparison of {sup 1}H NMR and rheometry results indicated that to account for the variations in minimum complex viscosity for all the blends, both the maximum concentration of fluid phase and the maximum mobility of the fluid material had to be considered. For individual blends, two exponential relationships have been found between the complex viscosity and the concentration of solid phase in both the softening and resolidification stages but the parameters are different for each blend. 30 refs., 8 figs., 5 tabs.

  12. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, Kenneth C. (Bolingbrook, IL); Markun, Francis (Joliet, IL); Zawadzki, Mary T. (South Bend, IN)

    1998-01-01T23:59:59.000Z

    An apparatus and method for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir.

  13. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, K.C.; Markun, F.; Zawadzki, M.T.

    1998-04-28T23:59:59.000Z

    An apparatus and method are disclosed for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir. 6 figs.

  14. Realization of effective super Tonks-Girardeau gases via strongly attractive one-dimensional Fermi gases

    SciTech Connect (OSTI)

    Chen Shu; Yin Xiangguo; Guan Liming [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Guan Xiwen [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Batchelor, M. T. [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Mathematical Sciences Institute, Australian National University, Canberra ACT 0200 (Australia)

    2010-03-15T23:59:59.000Z

    A significant feature of the one-dimensional super Tonks-Girardeau gas is its metastable gas-like state with a stronger Fermi-like pressure than for free fermions which prevents a collapse of atoms. This naturally suggests a way to search for such strongly correlated behavior in systems of interacting fermions in one dimension. We thus show that the strongly attractive Fermi gas without polarization can be effectively described by a super Tonks-Girardeau gas composed of bosonic Fermi pairs with attractive pair-pair interaction. A natural description of such super Tonks-Girardeau gases is provided by Haldane generalized exclusion statistics. In particular, they are equivalent to ideal particles obeying more exclusive statistics than Fermi-Dirac statistics.

  15. Process for the removal of acid forming gases from exhaust gases and production of phosphoric acid

    DOE Patents [OSTI]

    Chang, Shih-Ger (El Cerrito, CA); Liu, David K. (San Pablo, CA)

    1992-01-01T23:59:59.000Z

    Exhaust gases are treated to remove NO or NO.sub.x and SO.sub.2 by contacting the gases with an aqueous emulsion or suspension of yellow phosphorous preferably in a wet scrubber. The addition of yellow phosphorous in the system induces the production of O.sub.3 which subsequently oxidizes NO to NO.sub.2. The resulting NO.sub.2 dissolves readily and can be reduced to form ammonium ions by dissolved SO.sub.2 under appropriate conditions. In a 20 acfm system, yellow phosphorous is oxidized to yield P.sub.2 O.sub.5 which picks up water to form H.sub.3 PO.sub.4 mists and can be collected as a valuable product. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50.degree. C. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO.sub.x and SO.sub.2, alkalis that are used for flue gas desulfurization are preferred. With this process, better than 90% of SO.sub.2 and NO in simulated flue gas can be removed. Stoichiometric ratios (P/NO) ranging between 0.6 and 1.5 were obtained.

  16. Influence of low and high temperature coking of H-GaMFI propane aromatization catalyst on its surface and catalytic properties

    SciTech Connect (OSTI)

    Choudhary, V.R.; Kinage, A.K.; Devadas, P. [National Chemical Lab., Pune (India)] [and others] [National Chemical Lab., Pune (India); and others

    1997-03-01T23:59:59.000Z

    H-Gallosilicate (MFI) (i.e., H-GaMFI) zeolite shows high activity/selectivity in the aromatization of lower alkanes, which is processes of treat practical importance. The high aromatization activity of this catalyst is attributed to its high dehydrogenation activity due to the presence of high dispersed nonframework Ga-oxide species (which are formed during hydrothermal synthesis and/or pretreatments to the zeolite) along with the zeolitic acid sites (or framework Ga), resulting in a bifunctional catalyst. However, this zeolite undergoes fast catalyst deactivation in the propane aromatization. The catalyst deactivation is attributed mainly to the coke formation on the zeolite. Earlier, a few studies have been reported on the deactivation of H-GaMFI zeolite in the propane aromatization. The catalyst deactivation is attributed mainly to the coke formation on the zeolite. Earlier, a few studies have been reported on the deactivation of H-GaMFI zeolite in the propane aromatization at 500-550{degrees}C for a short time-on-stream (10 h). It is interesting to know the effect of catalyst deactivation due to coking in the propane aromatization for much longer periods both at low (at 400{degrees}C) and high (at 550{degrees}C) temperatures on the product selectivity and also on the surface (viz., sorption capacity, acidity/acid strength distribution) and catalytic properties of the zeolite. The present investigation was undertaken for this purpose. 16 refs., 1 fig., 3 tabs.

  17. Emissions Of Greenhouse Gases From Rice Agriculture

    SciTech Connect (OSTI)

    M. Aslam K. Khalil

    2009-07-16T23:59:59.000Z

    This project produced detailed data on the processes that affect methane and nitrous oxide emissions from rice agriculture and their inter-relationships. It defines the shifting roles and potential future of these gases in causing global warming and the benefits and tradeoffs of reducing emissions. The major results include: 1). Mechanisms and Processes Leading to Methane Emissions are Delineated. Our experiments have tested the standard model of methane emissions from rice fields and found new results on the processes that control the flux. A mathematical mass balance model was used to unravel the production, oxidation and transport of methane from rice. The results suggested that when large amounts of organic matter are applied, the additional flux that is observed is due to both greater production and reduced oxidation of methane. 2). Methane Emissions From China Have Been Decreasing Over the Last Two Decades. We have calculated that methane emissions from rice fields have been falling in recent decades. This decrease is particularly large in China. While some of this is due to reduced area of rice agriculture, the bigger effect is from the reduction in the emission factor which is the annual amount of methane emitted per hectare of rice. The two most important changes that cause this decreasing emission from China are the reduced use of organic amendments which have been replaced by commercial nitrogen fertilizers, and the increased practice of intermittent flooding as greater demands are placed on water resources. 3). Global Methane Emissions Have Been Constant For More Than 20 Years. While the concentrations of methane in the atmosphere have been leveling off in recent years, our studies show that this is caused by a near constant total global source of methane for the last 20 years or more. This is probably because as some anthropogenic sources have increased, others, such as the rice agriculture source, have fallen. Changes in natural emissions appear small. 4). Nitrous Oxide Emissions From Rice Fields Increase as Methane Emissions Drop. Inundated conditions favor anaerobic methane production with high emission rates and de-nitrification resulting in modest nitrous oxide emissions. Under drier conditions such as intermittent flooding, methane emissions fall and nitrous oxide emissions increase. Increased nitrogen fertilizer use increases nitrous oxide emissions and is usually accompanied by reduced organic matter applications which decreases methane emissions. These mechanisms cause a generally inverse relationship between methane and nitrous oxide emissions. Reduction of methane from rice agriculture to control global warming comes with tradeoffs with increased nitrous oxide emissions. 5). High Spatial Resolution Maps of Emissions Produced. Maps of methane and nitrous oxide emissions at a resolution of 5 min × 5 min have been produced based on the composite results of this research. These maps are necessary for both scientific and policy uses.

  18. Evaluation of exposures of hospital employees to anesthetic gases

    SciTech Connect (OSTI)

    Lambeth, J.D.

    1988-01-01T23:59:59.000Z

    Hospital employees who work in hospital operating and recovery rooms are often exposed to a number of anesthetic gases. There is evidence to support the belief that such exposures have led to higher rates of miscarriages and spontaneous abortions of pregnancies among women directly exposed to these gases than among women not exposed. Most of the studies assessing exposure levels were conducted prior to the widespread use of scavenging systems. Air sampling was conducted in hospital operatories and recovery rooms of three large hospitals to assess the current exposure levels in these areas and determine the effectiveness of these systems in reducing exposures to fluoride-containing anesthetic gases. It was determined that recovery-room personnel are exposed to levels of anesthesia gases that often approach and exceed the recommended Threshold Limit Value-Time Weighted Average (TLV-TWA) of 2.0 ppm. Recovery-room personnel do not have the protection from exposure provided by scavenging systems in operating rooms. Operating-room personnel were exposed to anesthesia gas levels above the TLV-TWA only when patients were masked, or connected and disconnected from the scavenging systems. Recovery-room personnel also need to be protected from exposure to anesthesia gases by a scavenging system.

  19. Lesson 9 - Solar Ovens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12electron 9 5 -ofLearningLensless4 Lensless Lesson 16 -

  20. Reduction of COD in leachate from a hazardous waste landfill adjacent to a coke-making facility

    SciTech Connect (OSTI)

    Banerjee, K.; O`Toole, T.J. [Chester Environmental, Moon Township, PA (United States)

    1995-12-01T23:59:59.000Z

    A hazardous waste landfill adjacent to a coke manufacturing facility was in operation between July 1990 and December 1991. A system was constructed to collect and treat the leachate from the landfill prior to discharge to the river. Occasionally, the discharge from the treatment facility exceeded the permit limitations for Chemical Oxygen Demand (COD), Biochemical Oxygen Demand (BOD), and Total Organic Carbon (TOC). The objectives of this study were to determine treatment methods which would enable compliance with the applicable discharge limits; to establish the desired operating conditions of the process; and to investigate the effect of various parameters such as pH, catalyst dosage, and reaction time on the COD destruction efficiency. The characteristics of the landfill leachate in question were significantly variable in terms of chemical composition. A review of the influent quality data suggests that the COD concentration ranges between 80 and 390 mg/l. The oxidation processes using Fenton`s reagent or a combination of UV/hydrogen peroxide/catalyst are capable of reducing the COD concentration of the leachate below the discharge limitation of 35 mg/l. The estimated capital cost associated with the Fenton`s reagent process is approximately $525,000, and the annual operating and maintenance cost is $560,000. The estimated capital cost for the UV/hydrogen peroxide/catalyst treatment system is $565,000. The annual operating and maintenance cost of this process would be approximately $430,000.

  1. Method for removing acid gases from a gaseous stream

    DOE Patents [OSTI]

    Gorin, Everett (San Rafael, CA); Zielke, Clyde W. (McMurray, PA)

    1981-01-01T23:59:59.000Z

    In a process for hydrocracking a heavy aromatic polynuclear carbonaceous feedstock containing reactive alkaline constituents to produce liquid hydrocarbon fuels boiling below about 475.degree. C. at atmospheric pressure by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, thereafter separating a gaseous stream containing hydrogen, at least a portion of the hydrocarbon fuels and acid gases from the molten metal halide and regenerating the molten metal halide, thereby producing a purified molten metal halide stream for recycle to the hydrocracking zone, an improvement comprising; contacting the gaseous acid gas, hydrogen and hydrocarbon fuels-containing stream with the feedstock containing reactive alkaline constituents to remove acid gases from the acid gas containing stream. Optionally at least a portion of the hydrocarbon fuels are separated from gaseous stream containing hydrogen, hydrocarbon fuels and acid gases prior to contacting the gaseous stream with the feedstock.

  2. Separating hydrogen from coal gasification gases with alumina membranes

    SciTech Connect (OSTI)

    Egan, B.Z. (Oak Ridge National Lab., TN (USA)); Fain, D.E.; Roettger, G.E.; White, D.E. (Oak Ridge K-25 Site, TN (USA))

    1991-01-01T23:59:59.000Z

    Synthesis gas produced in coal gasification processes contains hydrogen, along with carbon monoxide, carbon dioxide, hydrogen sulfide, water, nitrogen, and other gases, depending on the particular gasification process. Development of membrane technology to separate the hydrogen from the raw gas at the high operating temperatures and pressures near exit gas conditions would improve the efficiency of the process. Tubular porous alumina membranes with mean pore radii ranging from about 9 to 22 {Angstrom} have been fabricated and characterized. Based on hydrostatic tests, the burst strength of the membranes ranged from 800 to 1600 psig, with a mean value of about 1300 psig. These membranes were evaluated for separating hydrogen and other gases. Tests of membrane permeabilities were made with helium, nitrogen, and carbon dioxide. Measurements were made at room temperature in the pressure range of 15 to 589 psi. Selected membranes were tested further with mixed gases simulating a coal gasification product gas. 5 refs., 7 figs.

  3. Emissions of greenhouse gases in the United States 1997

    SciTech Connect (OSTI)

    NONE

    1998-10-01T23:59:59.000Z

    This is the sixth annual report on aggregate US national emissions of greenhouse gases. It covers emissions over the period 1990--1996, with preliminary estimates of emissions for 1997. Chapter one summarizes some background information about global climate change and the greenhouse effect. Important recent developments in global climate change activities are discussed, especially the third Conference of the Parties to the Framework Convention on Climate Change, which was held in December of 1997 in Kyoto, Japan. Chapters two through five cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons and related gases, respectively. Chapter six describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Six appendices are included in the report. 96 refs., 38 tabs.

  4. “Hard probes” of strongly-interacting atomic gases

    SciTech Connect (OSTI)

    Nishida, Yusuke [Los Alamos National Laboratory

    2012-06-18T23:59:59.000Z

    We investigate properties of an energetic atom propagating through strongly interacting atomic gases. The operator product expansion is used to systematically compute a quasiparticle energy and its scattering rate both in a spin-1/2 Fermi gas and in a spinless Bose gas. Reasonable agreement with recent quantum Monte Carlo simulations even at a relatively small momentum k/kF > 1.5 indicates that our large-momentum expansions are valid in a wide range of momentum. We also study a differential scattering rate when a probe atom is shot into atomic gases. Because the number density and current density of the target atomic gas contribute to the forward scattering only, its contact density (measure of short-range pair correlation) gives the leading contribution to the backward scattering. Therefore, such an experiment can be used to measure the contact density and thus provides a new local probe of strongly interacting atomic gases.

  5. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, G.I.; Dietz, R.N.

    1994-04-05T23:59:59.000Z

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

  6. Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases

    DOE Patents [OSTI]

    Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

    1994-01-01T23:59:59.000Z

    This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

  7. Removal of sulfur and nitrogen containing pollutants from discharge gases

    DOE Patents [OSTI]

    Joubert, James I. (Pittsburgh, PA)

    1986-01-01T23:59:59.000Z

    Oxides of sulfur and of nitrogen are removed from waste gases by reaction with an unsupported copper oxide powder to form copper sulfate. The resulting copper sulfate is dissolved in water to effect separation from insoluble mineral ash and dried to form solid copper sulfate pentahydrate. This solid sulfate is thermally decomposed to finely divided copper oxide powder with high specific surface area. The copper oxide powder is recycled into contact with the waste gases requiring cleanup. A reducing gas can be introduced to convert the oxide of nitrogen pollutants to nitrogen.

  8. Methods, systems, and devices for deep desulfurization of fuel gases

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA); Liu, Jun (Richland, WA); Huo, Qisheng (Richland, WA)

    2012-04-17T23:59:59.000Z

    A highly effective and regenerable method, system and device that enables the desulfurization of warm fuel gases by passing these warm gasses over metal-based sorbents arranged in a mesoporous substrate. This technology will protect Fischer-Tropsch synthesis catalysts and other sulfur sensitive catalysts, without drastic cooling of the fuel gases. This invention can be utilized in a process either alone or alongside other separation processes, and allows the total sulfur in such a gas to be reduced to less than 500 ppb and in some instances as low as 50 ppb.

  9. Welcome to Greenhouse Gases: Science and Technology: Editorial

    SciTech Connect (OSTI)

    Oldenburg, C.M.; Maroto-Valer, M.M.

    2011-02-01T23:59:59.000Z

    This editorial introduces readers and contributors to a new online journal. Through the publication of articles ranging from peer-reviewed research papers and short communications, to editorials and interviews on greenhouse gas emissions science and technology, this journal will disseminate research results and information that address the global crisis of anthropogenic climate change. The scope of the journal includes the full spectrum of research areas from capture and separation of greenhouse gases from flue gases and ambient air, to beneficial utilization, and to sequestration in deep geologic formations and terrestrial (plant and soil) systems, as well as policy and technoeconomic analyses of these approaches.

  10. AER1301: KINETIC THEORY OF GASES Assignment #1

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    AER1301: KINETIC THEORY OF GASES Assignment #1 1. A hypersonic wind tunnel is contructed so such that the mean free path, , is given by the expression = 16µ 5 1 2RT , where R is the ideal gas constant and p space and the length of each side of the cube is 4v. (a) Obtain an expression for the normalized

  11. AER1301: KINETIC THEORY OF GASES Assignment #1

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    AER1301: KINETIC THEORY OF GASES Assignment #1 1. A hypersonic wind tunnel is contructed so spheres during collisions such that the mean free path, #21;, is given by the expression #21; = 16#22; 5 of the cube is 4v Ć . (a) Obtain an expression for the normalized velocity distribution function, f(v). (b

  12. AER1301: KINETIC THEORY OF GASES Assignment #4

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    - equilibrium cases, up to second order. (b) Derive an expression for the non-conservative form of the kineticAER1301: KINETIC THEORY OF GASES Assignment #4 1. Consider a monatomic gas with one translational by the relaxation time approx- imation. Neglecting external forces, the conserved form of the kinetic equation

  13. AER1301: KINETIC THEORY OF GASES Assignment #4

    E-Print Network [OSTI]

    Groth, Clinton P. T.

    AER1301: KINETIC THEORY OF GASES Assignment #4 1. Consider a monatomic gas with one translational by the relaxation time approx- imation. Neglecting external forces, the conserved form of the kinetic equation function, in both the equilibrium and non- equilibrium cases, up to second order. (b) Derive an expression

  14. Ozone-depleting substances and the greenhouse gases HFCs, PFCs

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 19 3.1 IMPORTS AND EXPORTS 19 3.1.1 CFCs 19 3.1.2 Tetrachloromethane 19 3

  15. Nature of superfluidity in ultracold Fermi gases near Feshbach resonances

    SciTech Connect (OSTI)

    Stajic, Jelena; Levin, K. [James Franck Institute and Department of Physics, University of Chicago, Chicago, Illinois 60637 (United States); Milstein, J.N.; Holland, M.J. [JILA, University of Colorado and National Institute of Standards and Technology, Boulder, Colorado 80309 (United States); Chen Qijin [Department of Physics and Astronomy, Johns Hopkins University, Baltimore, Maryland 21218 (United States); Chiofalo, M.L. [Classe di Scienze and INFM, Scuola Normale Superiore, Piazza dei Cavelieri 7, I-56126 Pisa (Italy)

    2004-06-01T23:59:59.000Z

    We study the superfluid state of atomic Fermi gases using a BCS-Bose-Einstein-condensation crossover theory. Our approach emphasizes noncondensed fermion pairs which strongly hybridize with their (Feshbach-induced) molecular boson counterparts. These pairs lead to pseudogap effects above T{sub c} and non-BCS characteristics below. We discuss how these effects influence the experimental signatures of superfluidity.

  16. INTRODUCTION Insects exchange respiratory gases through a complex network of

    E-Print Network [OSTI]

    Socha, Jake

    3409 INTRODUCTION Insects exchange respiratory gases through a complex network of tracheal tubes through the tracheal system using diffusion alone (Krogh, 1920a; Weis-Fogh, 1964), many species are known to augment gas exchange using convection (Buck, 1962; Miller, 1966a). Two general mechanisms are recognized

  17. Higher Dimensional Coulomb Gases and Renormalized Energy Functionals

    E-Print Network [OSTI]

    -Louis Lions, Paris, F-75005 France & Courant Institute, New York University, 251 Mercer st, NY NY 10012, USAHigher Dimensional Coulomb Gases and Renormalized Energy Functionals N. Rougerie and S. Serfaty extract the next to leading order term in the ground state energy, beyond the mean-field limit. We show

  18. Use of low temperature blowers for recirculation of hot gases

    DOE Patents [OSTI]

    Maru, H.C.; Forooque, M.

    1982-08-19T23:59:59.000Z

    An apparatus is described for maintaining motors at low operating temperatures during recirculation of hot gases in fuel cell operations and chemical processes such as fluidized bed coal gasification. The apparatus includes a means for separating the hot process gas from the motor using a secondary lower temperature gas, thereby minimizing the temperature increase of the motor and associated accessories.

  19. Noble gases and radiocarbon in natural gas hydrates Gisela Winckler

    E-Print Network [OSTI]

    Aeschbach-Hertig, Werner

    Noble gases and radiocarbon in natural gas hydrates Gisela Winckler Lamont-Doherty Earth 2001; published 24 May 2002. [1] In samples of pure natural gas hydrates from Hydrate Ridge, Cascadia ones preferentially incorporated into the gas hydrate structure. The hydrate methane is devoid of 14 C

  20. Strongly interacting Fermi gases : non-equilibrium dynamics and dimensional crossover

    E-Print Network [OSTI]

    Sommer, Ariel T. (Ariel Tjodolv)

    2013-01-01T23:59:59.000Z

    Experiments using ultracold atomic gases address fundamental problems in many-body physics. This thesis describes experiments on strongly-interacting gases of fermionic atoms, with a focus on non-equilibrium physics and ...

  1. Steam Production from Waste Stack Gases in a Carbon Black Plant

    E-Print Network [OSTI]

    Istre, R. I.

    1981-01-01T23:59:59.000Z

    gases to produce steam has two very important rewards - energy conservation and pollution abatement. Energy conservation is achieved by using waste gases in place of fuel oil to produce the steam required by the various plants. Pollution abatement is due...

  2. Atmos. Chem. Phys., 7, 35873596, 2007 www.atmos-chem-phys.net/7/3587/2007/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    on the emis- sion data in Seoul and Northeast Asia: Gasoline and diesel vehicles, residential coal use, coke daily and seasonal variations. High contributions of biomass burning and coal (residential and coke oven ovens, coal power plants, biomass burning, and natural gas (NG) combustion. The ma- jor sources

  3. System for trapping and storing gases for subsequent chemical reduction to solids

    DOE Patents [OSTI]

    Vogel, John S. (San Jose, CA); Ognibene, Ted J. (Oakland, CA); Bench, Graham S. (Livermore, CA); Peaslee, Graham F. (Holland, MI)

    2009-11-03T23:59:59.000Z

    A system for quantitatively reducing oxide gases. A pre-selected amount of zinc is provided in a vial. A tube is provided in the vial. The zinc and the tube are separated. A pre-selected amount of a catalyst is provided in the tube. Oxide gases are injected into the vial. The vial, tube, zinc, catalyst, and the oxide gases are cryogenically cooled. At least a portion of the vial, tube, zinc, catalyst, and oxide gases are heated.

  4. Title of Document: INTERACTION OF INTENSE SHORT LASER PULSES WITH GASES OF NANOSCALE

    E-Print Network [OSTI]

    Anlage, Steven

    ABSTRACT Title of Document: INTERACTION OF INTENSE SHORT LASER PULSES WITH GASES OF NANOSCALE-cluster interaction. #12;INTERACTION OF INTENSE SHORT LASER PULSES WITH GASES OF NANOSCALE ATOMIC AND MOLECULAR., Department of Electrical and Computer Engineering We study the interaction of intense laser pulses with gases

  5. Process for separation of CO/sub 2/ from CO/sub 2/-containing gases

    SciTech Connect (OSTI)

    Linde, G.

    1985-07-09T23:59:59.000Z

    For separating CO/sub 2/ from CO/sub 2/-containing gases, especially stack gases and/or blast furnace gases, dimethylformamide is employed as a physical scrubbing medium to ensure high CO/sub 2/ purity. After absorption of CO/sub 2/, the DMF is regenerated and returned into the scrubbing stage. Dimethylformamide is utilized as the scrubbing medium.

  6. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K. C. Kwon

    2007-09-30T23:59:59.000Z

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

  7. Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts

    SciTech Connect (OSTI)

    K.C. Kwon

    2009-09-30T23:59:59.000Z

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

  8. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    CO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITYCO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITY

  9. The extreme nonlinear optics of gases and femtosecond optical filamentation

    SciTech Connect (OSTI)

    Milchberg, H. M.; Chen, Y.-H.; Cheng, Y.-H.; Jhajj, N.; Palastro, J. P.; Rosenthal, E. W.; Varma, S.; Wahlstrand, J. K.; Zahedpour, S. [Institute for Research in Electronics and Applied Physics, University of Maryland, College Park, Maryland 20742 (United States)

    2014-10-15T23:59:59.000Z

    Under certain conditions, powerful ultrashort laser pulses can form greatly extended, propagating filaments of concentrated high intensity in gases, leaving behind a very long trail of plasma. Such filaments can be much longer than the longitudinal scale over which a laser beam typically diverges by diffraction, with possible applications ranging from laser-guided electrical discharges to high power laser propagation in the atmosphere. Understanding in detail the microscopic processes leading to filamentation requires ultrafast measurements of the strong field nonlinear response of gas phase atoms and molecules, including absolute measurements of nonlinear laser-induced polarization and high field ionization. Such measurements enable the assessment of filamentation models and make possible the design of experiments pursuing applications. In this paper, we review filamentation in gases and some applications, and discuss results from diagnostics developed at Maryland for ultrafast measurements of laser-gas interactions.

  10. Apparatus for the plasma destruction of hazardous gases

    DOE Patents [OSTI]

    Kang, Michael (Los Alamos, NM)

    1995-01-01T23:59:59.000Z

    A plasma cell for destroying hazardous gases. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required.

  11. Apparatus for the plasma destruction of hazardous gases

    DOE Patents [OSTI]

    Kang, M.

    1995-02-07T23:59:59.000Z

    A plasma cell for destroying hazardous gases is described. An electric-discharge cell having an electrically conducting electrode onto which an alternating high-voltage waveform is impressed and a dielectric barrier adjacent thereto, together forming a high-voltage electrode, generates self-terminating discharges throughout a volume formed between this electrode and a grounded conducting liquid electrode. The gas to be transformed is passed through this volume. The liquid may be flowed, generating thereby a renewable surface. Moreover, since hydrochloric and hydrofluoric acids may be formed from destruction of various chlorofluorocarbons in the presence of water, a conducting liquid may be selected which will neutralize these corrosive compounds. The gases exiting the discharge region may be further scrubbed if additional purification is required. 4 figs.

  12. Decontamination of combustion gases in fluidized bed incinerators

    DOE Patents [OSTI]

    Leon, Albert M. (Mamaroneck, NY)

    1982-01-01T23:59:59.000Z

    Sulfur-containing atmospheric pollutants are effectively removed from exit gas streams produced in a fluidized bed combustion system by providing a fluidized bed of particulate material, i.e. limestone and/or dolomite wherein a concentration gradient is maintained in the vertical direction. Countercurrent contacting between upwardly directed sulfur containing combustion gases and descending sorbent particulate material creates a concentration gradient across the vertical extent of the bed characterized in progressively decreasing concentration of sulfur, sulfur dioxide and like contaminants upwardly and decreasing concentration of e.g. calcium oxide, downwardly. In this manner, gases having progressively decreasing sulfur contents contact correspondingly atmospheres having progressively increasing concentrations of calcium oxide thus assuring optimum sulfur removal.

  13. Wave Speed in the Macroscopic Extended Model for Ultrarelativistic Gases

    E-Print Network [OSTI]

    F. Borghero; F. Demontis; S. Pennisi

    2010-12-07T23:59:59.000Z

    An exact macroscopic extended model for ultrarelativistic gases, with an arbitrary number of moments, is present in the literature. Here we exploit equations determining wave speeds for that model. We find interesting results; for example, the whole system for their determination can be divided into independent subsystems and some, but not all, wave speeds are expressed by rational numbers. Moreover, the extraordinary property that these wave speeds for the macroscopic model are the same of those in the kinetic model, is proved.

  14. Pulse Radiolysis of Gases H atom yields, OH reactions,

    E-Print Network [OSTI]

    PULSE RADIOLYSIS OP GASES H atom yields, OH reactions, and kinetics of H2S systems Ole John Nielsen, M, in the reaction OH + OH + M · H2O2 + M. 3) In the H2S systems the HS extinction coefficient determined: k(H + H2S · H2 + HS) = 4-6 x 108 M ^ s " 1 k(HS + HS · products) = (1.9 ± 0.1) x io1 0 M ^ s " 1

  15. Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases

    SciTech Connect (OSTI)

    Carlsbad Field Office

    2006-04-01T23:59:59.000Z

    The Performance Demonstration Program (PDP) for headspace gases distributes sample gases of volatile organic compounds (VOCs) for analysis. Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facility’s compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.

  16. Chemical production from industrial by-product gases: Final report

    SciTech Connect (OSTI)

    Lyke, S.E.; Moore, R.H.

    1981-04-01T23:59:59.000Z

    The potential for conservation of natural gas is studied and the technical and economic feasibility and the implementation of ventures to produce such chemicals using carbon monoxide and hydrogen from byproduct gases are determined. A survey was performed of potential chemical products and byproduct gas sources. Byproduct gases from the elemental phosphorus and the iron and steel industries were selected for detailed study. Gas sampling, preliminary design, market surveys, and economic analyses were performed for specific sources in the selected industries. The study showed that production of methanol or ammonia from byproduct gas at the sites studied in the elemental phosphorus and the iron and steel industries is technically feasible but not economically viable under current conditions. Several other applications are identified as having the potential for better economics. The survey performed identified a need for an improved method of recovering carbon monoxide from dilute gases. A modest experimental program was directed toward the development of a permselective membrane to fulfill that need. A practical membrane was not developed but further investigation along the same lines is recommended. (MCW)

  17. Emissions of greenhouse gases in the United States 1996

    SciTech Connect (OSTI)

    NONE

    1997-10-01T23:59:59.000Z

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1990, with annual updates thereafter. This report is the fifth annual update, covering national emissions over the period 1989--1995, with preliminary estimates of emissions for 1996. The estimates contained in this report have been revised from those in last year`s report. Emissions estimates for carbon dioxide are reported in metric tons of carbon; estimates for other gases are reported in metric tons of gas. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapter 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes. Five appendixes are included with this report. 216 refs., 11 figs., 38 tabs.

  18. Thermodynamics of sustaining gases in the roughness of submerged superhydrophobic surfaces

    E-Print Network [OSTI]

    Neelesh A. Patankar

    2015-05-22T23:59:59.000Z

    Rough surfaces submerged in a liquid can remain almost dry if the liquid does not fully wet the roughness and gases are sustained in roughness grooves. Such partially dry surfaces can help reduce drag or enhance boiling. Gases sustained in roughness grooves would be composed of air and the vapor phase of the liquid itself. The thermodynamics of sustaining vapor was considered in a prior work [Patankar, Soft Matter, 2010, 6:1613]. Here, the thermodynamics of sustaining gases (e.g. air) is considered. Governing equations are presented along with a solution methodology to determine a critical condition to sustain gases. The critical roughness scale to sustain gases is estimated for different degrees of saturation of gases dissolved in the liquid. It is shown that roughness spacings of less than a micron are essential to sustain gases on surfaces submerged in water at atmospheric pressure. This is consistent with prior empirical data.

  19. National Environmental Research Institute University of Aarhus . Denmark

    E-Print Network [OSTI]

    .2 Coal, other plants 99 1.3 Brown coal briquettes and Coke oven coke 100 1.4 Petroleum coke 100 1.5 Wood correspondence list 94 Appendix 4 Emission factors, references 96 1 SO2 97 1.1 Coal, large power plants 97 1

  20. Pushing schedule derivation method

    SciTech Connect (OSTI)

    Henriquez, B. [Compania Siderurgica Huachipato S.A., Talcahuano (Chile)

    1996-12-31T23:59:59.000Z

    The development of a Pushing Schedule Derivation Method has allowed the company to sustain the maximum production rate at CSH`s Coke Oven Battery, in spite of having single set oven machinery with a high failure index as well as a heat top tendency. The stated method provides for scheduled downtime of up to two hours for machinery maintenance purposes, periods of empty ovens for decarbonization and production loss recovery capability, while observing lower limits and uniformity of coking time.

  1. Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases

    SciTech Connect (OSTI)

    Carlsbad Field Office

    2007-11-13T23:59:59.000Z

    The Performance Demonstration Program (PDP) for headspace gases distributes blind audit samples in a gas matrix for analysis of volatile organic compounds (VOCs). Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facility’s compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.

  2. Performance Demonstration Program Plan for Analysis of Simulated Headspace Gases

    SciTech Connect (OSTI)

    Carlsbad Field Office

    2007-11-19T23:59:59.000Z

    The Performance Demonstration Program (PDP) for headspace gases distributes blind audit samples in a gas matrix for analysis of volatile organic compounds (VOCs). Participating measurement facilities (i.e., fixed laboratories, mobile analysis systems, and on-line analytical systems) are located across the United States. Each sample distribution is termed a PDP cycle. These evaluation cycles provide an objective measure of the reliability of measurements performed for transuranic (TRU) waste characterization. The primary documents governing the conduct of the PDP are the Quality Assurance Program Document (QAPD) (DOE/CBFO-94-1012) and the Waste Isolation Pilot Plant (WIPP) Waste Analysis Plan (WAP) contained in the Hazardous Waste Facility Permit (NM4890139088-TSDF) issued by the New Mexico Environment Department (NMED). The WAP requires participation in the PDP; the PDP must comply with the QAPD and the WAP. This plan implements the general requirements of the QAPD and the applicable requirements of the WAP for the Headspace Gas (HSG) PDP. Participating measurement facilities analyze blind audit samples of simulated TRU waste package headspace gases according to the criteria set by this PDP Plan. Blind audit samples (hereafter referred to as PDP samples) are used as an independent means to assess each measurement facility’s compliance with the WAP quality assurance objectives (QAOs). To the extent possible, the concentrations of VOC analytes in the PDP samples encompass the range of concentrations anticipated in actual TRU waste package headspace gas samples. Analyses of headspace gases are required by the WIPP to demonstrate compliance with regulatory requirements. These analyses must be performed by measurement facilities that have demonstrated acceptable performance in this PDP. These analyses are referred to as WIPP analyses and the TRU waste package headspace gas samples on which they are performed are referred to as WIPP samples in this document. Participating measurement facilities must analyze PDP samples using the same procedures used for routine waste characterization analyses of WIPP samples.

  3. Direct conversion of light hydrocarbon gases to liquid fuel

    SciTech Connect (OSTI)

    Kaplan, R.D.; Foral, M.J.

    1992-05-16T23:59:59.000Z

    Amoco oil Company, has investigated the direct, non-catalytic conversion of light hydrocarbon gases to liquid fuels (particularly methanol) via partial oxidation. The primary hydrocarbon feed used in these studies was natural gas. This report describes work completed in the course of our two-year project. In general we determined that the methanol yields delivered by this system were not high enough to make it economically attractive. Process variables studied included hydrocarbon feed composition, oxygen concentration, temperature and pressure effects, residence time, reactor design, and reactor recycle.

  4. Prospecting by sampling and analysis of airborne particulates and gases

    DOE Patents [OSTI]

    Sehmel, G.A.

    1984-05-01T23:59:59.000Z

    A method is claimed for prospecting by sampling airborne particulates or gases at a ground position and recording wind direction values at the time of sampling. The samples are subsequently analyzed to determine the concentrations of a desired material or the ratios of the desired material to other identifiable materials in the collected samples. By comparing the measured concentrations or ratios to expected background data in the vicinity sampled, one can select recorded wind directions indicative of the upwind position of the land-based source of the desired material.

  5. Two-phase compressibility factors for retrograde gases 

    E-Print Network [OSTI]

    Rayes, Daniel George

    1989-01-01T23:59:59.000Z

    . K. , M Cain, W. D. , Jr. and Jennings, J. W. : "An Improved Method for the Determination of the Reservoir Specific Gravity for Retrograde Gases, " JPT (July 1989) 747-752. 7. Craft, B. C. and Hawkins, M. F. : A li P 1 m R rv ir En ine rin...). Variable Mean Standard Deviation Minimum Maximum H2S CO2 N2 CI C2 C3 IC4 NC4 IC5 NC5 C6 C7+ M. W. C7+ S. G. C7+ 1, 01840 0. 00997 0. 02545 0. 01840 0. 73233 0. 07584 0. 03948 0. 00859 0. 01482 0. 00611 0. 00637 0. 00857 0. 05404...

  6. Separation of gases through gas enrichment membrane composites

    DOE Patents [OSTI]

    Swedo, R.J.; Kurek, P.R.

    1988-07-19T23:59:59.000Z

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  7. Separation of gases through gas enrichment membrane composites

    DOE Patents [OSTI]

    Swedo, Raymond J. (Mt. Prospect, IL); Kurek, Paul R. (Schaumburg, IL)

    1988-01-01T23:59:59.000Z

    Thin film composite membranes having as a permselective layer a film of a homopolymer of certain vinyl alkyl ethers are useful in the separation of various gases. Such homopolymers have a molecular weight of greater than 30,000 and the alkyl group of the vinyl alkyl monomer has from 4 to 20 carbon atoms with branching within the alkyl moiety at least at the carbon atom bonded to the ether oxygen or at the next adjacent carbon atom. These membranes show excellent hydrolytic stability, especially in the presence of acidic or basic gaseous components.

  8. EIA-Voluntary Reporting of Greenhouse Gases Program

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells, Wisconsin:DeploymentSite Name: Email: Terminal2,7,7,of Greenhouse Gases

  9. Instantaneous and efficient surface wave excitation of a low pressure gas or gases

    DOE Patents [OSTI]

    Levy, Donald J. (Berkeley, CA); Berman, Samuel M. (San Francisco, CA)

    1988-01-01T23:59:59.000Z

    A system for instantaneously ionizing and continuously delivering energy in the form of surface waves to a low pressure gas or mixture of low pressure gases, comprising a source of rf energy, a discharge container, (such as a fluorescent lamp discharge tube), an rf shield, and a coupling device responsive to rf energy from the source to couple rf energy directly and efficiently to the gas or mixture of gases to ionize at least a portion of the gas or gases and to provide energy to the gas or gases in the form of surface waves. The majority of the rf power is transferred to the gas or gases near the inner surface of the discharge container to efficiently transfer rf energy as excitation energy for at least one of the gases. The most important use of the invention is to provide more efficient fluorescent and/or ultraviolet lamps.

  10. Process for recovery of sulfur from acid gases

    DOE Patents [OSTI]

    Towler, Gavin P. (Kirkbymoorside, GB2); Lynn, Scott (Pleasant Hill, CA)

    1995-01-01T23:59:59.000Z

    Elemental sulfur is recovered from the H.sub.2 S present in gases derived from fossil fuels by heating the H.sub.2 S with CO.sub.2 in a high-temperature reactor in the presence of a catalyst selected as one which enhances the thermal dissociation of H.sub.2 S to H.sub.2 and S.sub.2. The equilibrium of the thermal decomposition of H.sub.2 S is shifted by the equilibration of the water-gas-shift reaction so as to favor elemental sulfur formation. The primary products of the overall reaction are S.sub.2, CO, H.sub.2 and H.sub.2 O. Small amounts of COS, SO.sub.2 and CS.sub.2 may also form. Rapid quenching of the reaction mixture results in a substantial increase in the efficiency of the conversion of H.sub.2 S to elemental sulfur. Plant economy is further advanced by treating the product gases to remove byproduct carbonyl sulfide by hydrolysis, which converts the COS back to CO.sub.2 and H.sub.2 S. Unreacted CO.sub.2 and H.sub.2 S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H.sub.2 and CO, which has value either as a fuel or as a chemical feedstock and recovers the hydrogen value from the H.sub.2 S.

  11. Self-pulsing of hollow cathode discharge in various gases

    SciTech Connect (OSTI)

    Qin, Y.; He, F., E-mail: hefeng@bit.edu.cn; Jiang, X. X.; Ouyang, J. T., E-mail: jtouyang@bit.edu.cn [School of Physics, Beijing Institute of Technology, Beijing 100081 (China); Xie, K. [School of Aerospace Engineering, Beijing Institute of Technology, Beijing 100081 (China)

    2014-07-15T23:59:59.000Z

    In this paper, we investigate the self-pulsing phenomenon of cavity discharge in a cylindrical hollow cathode in various gases including argon, helium, nitrogen, oxygen, and air. The current-voltage characteristics of the cavity discharge, the waveforms of the self-pulsing current and voltage as well as the repetition frequency were measured. The results show that the pulsing frequency ranges from a few to tens kilohertz and depends on the averaged current and the pressure in all gases. The pulsing frequency will increase with the averaged current and decrease with the pressure. The rising time of the current pulse is nearly constant in a given gas or mixture. The self-pulsing does not depend on the external ballast but is affected significantly by the external capacitor in parallel with the discharge cell. The low-current self-pulsing in hollow cathode discharge is the mode transition between Townsend and glow discharges. It can be described by the charging-discharging process of an equivalent circuit consisting of capacitors and resistors.

  12. Dark resonances for ground state transfer of molecular quantum gases

    E-Print Network [OSTI]

    Manfred J. Mark; Johann G. Danzl; Elmar Haller; Mattias Gustavsson; Nadia Bouloufa; Olivier Dulieu; Houssam Salami; Tom Bergeman; Helmut Ritsch; Russell Hart; Hanns-Christoph Nägerl

    2008-11-05T23:59:59.000Z

    One possible way to produce ultracold, high-phase-space-density quantum gases of molecules in the rovibronic ground state is given by molecule association from quantum-degenerate atomic gases on a Feshbach resonance and subsequent coherent optical multi-photon transfer into the rovibronic ground state. In ultracold samples of Cs_2 molecules, we observe two-photon dark resonances that connect the intermediate rovibrational level |v=73,J=2> with the rovibrational ground state |v=0,J=0> of the singlet $X^1\\Sigma_g^+$ ground state potential. For precise dark resonance spectroscopy we exploit the fact that it is possible to efficiently populate the level |v=73,J=2> by two-photon transfer from the dissociation threshold with the stimulated Raman adiabatic passage (STIRAP) technique. We find that at least one of the two-photon resonances is sufficiently strong to allow future implementation of coherent STIRAP transfer of a molecular quantum gas to the rovibrational ground state |v=0,J=0>.

  13. Emissions of greenhouse gases in the United States 1995

    SciTech Connect (OSTI)

    NONE

    1996-10-01T23:59:59.000Z

    This is the fourth Energy Information Administration (EIA) annual report on US emissions of greenhouse gases. This report presents estimates of US anthropogenic (human-caused) emissions of carbon dioxide, methane, nitrous oxide, and several other greenhouse gases for 1988 through 1994. Estimates of 1995 carbon dioxide, nitrous oxide, and halocarbon emissions are also provided, although complete 1995 estimates for methane are not yet available. Emissions of carbon dioxide increased by 1.9% from 1993 to 1994 and by an additional 0.8% from 1994 to 1995. Most carbon dioxide emissions are caused by the burning of fossil fuels for energy consumption, which is strongly related to economic growth, energy prices, and weather. The US economy grew rapidly in 1994 and slowed in 1995. Estimated emissions of methane increased slightly in 1994, as a result of a rise in emissions from energy and agricultural sources. Estimated nitrous oxide emissions increased by 1.8% in 1995, primarily due to increased use of nitrogen fertilizers and higher output of chemicals linked to nitrous oxide emissions. Estimated emissions of hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs), which are known to contribute to global warming, increased by nearly 11% in 1995, primarily as a result of increasing substitution for chlorofluorocarbons (CFCs). With the exception of methane, the historical emissions estimates presented in this report are only slightly revised from those in last year`s report.

  14. Technical support document: Energy efficiency standards for consumer products: Room air conditioners, water heaters, direct heating equipment, mobile home furnaces, kitchen ranges and ovens, pool heaters, fluorescent lamp ballasts and television sets. Volume 1, Methodology

    SciTech Connect (OSTI)

    Not Available

    1993-11-01T23:59:59.000Z

    The Energy Policy and Conservation Act (P.L. 94-163), as amended, establishes energy conservation standards for 12 of the 13 types of consumer products specifically covered by the Act. The legislation requires the Department of Energy (DOE) to consider new or amended standards for these and other types of products at specified times. DOE is currently considering amending standards for seven types of products: water heaters, direct heating equipment, mobile home furnaces, pool heaters, room air conditioners, kitchen ranges and ovens (including microwave ovens), and fluorescent light ballasts and is considering establishing standards for television sets. This Technical Support Document presents the methodology, data, and results from the analysis of the energy and economic impacts of the proposed standards. This volume presents a general description of the analytic approach, including the structure of the major models.

  15. Process for releasing ammonia bound in coal water

    SciTech Connect (OSTI)

    Laufhutte, D.; Weber, H.

    1981-11-24T23:59:59.000Z

    A process for releasing ammonia which is bound in coal water using a pre-desulfurization plant having ammonia and hydrogen sulfide scrubbers through which crude coking plant gas is passed comprises circulating the crude coke oven gases through the hydrogen sulfide scrubber and the ammonia scrubber in succession, directing the coal water first through the ammonia scrubber while the crude coking plant gases are being also circulated therethrough after passing it first through the hydrogen sulfide scrubber. An alkali solution is also circulated through the ammonia scrubber to enrich the solution with acid components and to liberate ammonia bound in the coal water directing the coal water which has been enriched from the ammonia scrubber into the hydrogen sulfide scrubber. The process is characterized by the fact that the alkali solution which has first served for the hydrogen sulfide scrubber is added to the ammonia hydrogen sulfide scrubber. 80 to 90% of the total alkali solution is charged to the hydrogen sulfide after-washery and then on the hydrogen sulfide pre-washery and the rest is charged to an ammonia expulsion apparatus.

  16. Loschmidt echo in one-dimensional interacting Bose gases

    SciTech Connect (OSTI)

    Lelas, K.; Seva, T.; Buljan, H. [Faculty of Electrical Engineering Mechanical Engineering and Naval Architecture, University of Split, Rudjera Boskovica BB, 21000 Split (Croatia); Department of Physics, University of Zagreb, Bijenicka c. 32, 10000 Zagreb (Croatia)

    2011-12-15T23:59:59.000Z

    We explore Loschmidt echo in two regimes of one-dimensional interacting Bose gases: the strongly interacting Tonks-Girardeau (TG) regime, and the weakly interacting mean-field regime. We find that the Loschmidt echo of a TG gas decays as a Gaussian when small (random and time independent) perturbations are added to the Hamiltonian. The exponent is proportional to the number of particles and the magnitude of a small perturbation squared. In the mean-field regime the Loschmidt echo shows richer behavior: it decays faster for larger nonlinearity, and the decay becomes more abrupt as the nonlinearity increases; it can be very sensitive to the particular realization of the noise potential, especially for relatively small nonlinearities.

  17. Photolysis of water for production of fuel gases

    SciTech Connect (OSTI)

    Eror, N.G.; Blakemore, J.S.

    1981-12-01T23:59:59.000Z

    To better understand the role of the semiconductor electrode in the photocatalytic decomposition of water to form hydrogen and other fuel gases, researchers characterized the defect structure of a number of large-band-gap semiconductor electrode materials. The defect structure of SrTiO/sub 3/ samples has been related to photoelectrochemical cell response, leading to a signficant improvement in the understanding of how electrode properties influence cell performance. Although the large band gap of these materials severely restricts their ability to use the solar spectrum, they are more resistant to photocorrosion than lower-band-gap materials. This band gap has been reduced somewhat in lanthanum-doped SrTiO/sub 3/ samples without compromising photostability or requiring a bias voltage for water decomposition.

  18. Finite-size energy of non-interacting Fermi gases

    E-Print Network [OSTI]

    Martin Gebert

    2014-06-14T23:59:59.000Z

    We prove the asymptotics of the difference of the ground-state energies of two non-interacting $N$-particle Fermi gases on the half line of length $L$ in the thermodynamic limit up to order $1/L$. We are particularly interested in subdominant terms proportional to $1/L$, called finite-size energy. In the nineties Affleck and co-authors [Aff97, ZA97, AL94] claimed that the finite-size energy equals the decay exponent occuring in Anderson's orthogonality catastrophe. It turns out that the finite-size energy depends on the details of the thermodynamic limit and typically also includes a linear term in the scattering phase shift.

  19. Free Energies of Dilute Bose gases: upper bound

    E-Print Network [OSTI]

    Jun Yin

    2010-12-19T23:59:59.000Z

    We derive a upper bound on the free energy of a Bose gas system at density $\\rho$ and temperature $T$. In combination with the lower bound derived previously by Seiringer \\cite{RS1}, our result proves that in the low density limit, i.e., when $a^3\\rho\\ll 1$, where $a$ denotes the scattering length of the pair-interaction potential, the leading term of $\\Delta f$ the free energy difference per volume between interacting and ideal Bose gases is equal to $4\\pi a (2\\rho^2-[\\rho-\\rhoc]^2_+)$. Here, $\\rhoc(T)$ denotes the critical density for Bose-Einstein condensation (for the ideal gas), and $[\\cdot ]_+$ $=$ $\\max\\{\\cdot, 0\\}$ denotes the positive part.

  20. Elliptic flow and nearly perfect fluidity in dilute Fermi gases

    E-Print Network [OSTI]

    Thomas Schaefer

    2010-12-16T23:59:59.000Z

    In this contribution we summarize recent progress in understanding the shear viscosity of strongly correlated dilute Fermi gases. We discuss predictions from kinetic theory, and show how these predictions can be tested using recent experimental data on elliptic flow. We find agreement between theory and experiments in the high temperature regime $T\\gg T_F$, where $T_F$ is the the temperature where quantum degeneracy effects become important. In the low temperature regime, $T\\sim T_F$, the strongest constraints on the shear viscosity come from experimental studies of the damping of collective modes. These experiments indicate that $\\eta/s\\lsim 0.5\\hbar/k_B$, where $\\eta$ is the shear viscosity and $s$ is the entropy density.

  1. Light pulse in {Lambda}-type cold-atom gases

    SciTech Connect (OSTI)

    Wei Ran; Deng Youjin; Chen Shuai; Chen Zengbing; Pan Jianwei [Hefei National Laboratory for Physical Sciences at Microscale and Department of Modern Physics, University of Science and Technology of China, Hefei, Anhui 230026 (China); Zhao Bo [Institute for Theoretical physics, University of Innsbruck, A-6020 Innsbruck (Austria); Institute for Quantum Optics and Quantum Information of the Austrian Academy of Science, A-6020 Innsbruck (Austria)

    2010-04-15T23:59:59.000Z

    We investigate the behavior of the light pulse in {Lambda}-type cold-atom gases with two counter-propagating control lights with equal strength by directly simulating the dynamic equations and exploring the dispersion relation. Our analysis shows that, depending on the length L{sub 0} of the stored wave packet and the decay rate {gamma} of ground-spin coherence, the recreated light can behave differently. For long L{sub 0} and/or large {gamma}, a stationary light pulse is produced, while two propagating light pulses appear for short L{sub 0} and/or small {gamma}. In the {gamma}{yields}0 limit, the light always splits into two propagating pulses for a sufficiently long time. This scenario agrees with a recent experiment [Y.-W. Lin et al., Phys. Rev. Lett. 102, 213601 (2009)] where two propagating light pulses are generated in laser-cooled cold-atom ensembles.

  2. Fuel cell stack with internal manifolds for reactant gases

    DOE Patents [OSTI]

    Schnacke, Arthur W. (Schenectady, NY)

    1985-01-01T23:59:59.000Z

    A fuel cell stack includes a plurality of plate-like fuel cells arranged along an axis generally parallel to cell thickness with electrically conductive separator plates between each pair of cells. A plurality of axial manifolds are provided at opposite sides of the stack in outer marginal portions beyond the edges of electrodes and electrolyte tiles. Sealing rings prevent cross-leakage of oxidant fuel gases through use of pairs of outwardly extending lips from opposite tile surfaces bonded to first and second electrode frames respectively. The frames provide transition between electrode edges and manifold perimeters. The pairs of extension lips are sealingly bonded together through an electrically insulative sealing ring with wedge shaped fastening members.

  3. Fuel cell stack with internal manifolds for reactant gases

    DOE Patents [OSTI]

    Schnacke, A.W.

    1983-10-12T23:59:59.000Z

    A fuel cell stack includes a plurality of plate-like fuel cells arranged along an axis generally parallel to cell thickness with electrically conductive separator plates between each pair of cells. A plurality of axial manifolds are provided at opposite sides of the stack in outer marginal portions beyond the edges of electrodes and electrolyte tiles. Sealing rings prevent cross-leakage of oxidant fuel gases through use of pairs of outwardly extending lips from opposite tile surfaces bonded to first and second electrode frames respectively. The frames provide transition between electrode edges and manifold perimeters. The pairs of extension lips are sealingly bonded together through an electrically insulative sealing ring with wedge shaped fastening members.

  4. Title of Dissertation: HIGH POWER NONLINEAR PROPAGATION OF LASER PULSES IN TENUOUS GASES

    E-Print Network [OSTI]

    Anlage, Steven

    ABSTRACT Title of Dissertation: HIGH POWER NONLINEAR PROPAGATION OF LASER PULSES IN TENUOUS GASES AND PLASMA CHANNELS Jianzhou Wu, Doctor of Philosophy, 2005 Dissertation Directed By: Professor Thomas M PROPAGATION OF LASER PULSES IN TENUOUS GASES AND PLASMA CHANNELS By Jianzhou Wu Dissertation submitted

  5. Monte Carlo Simulation of Radiation in Gases with a NarrowBand Model

    E-Print Network [OSTI]

    Dufresne, Jean-Louis

    , France (\\Phi) now at the Institute of Energy and Power Plant Technology, TH Darmstadt, 64287 DarmstadtMonte Carlo Simulation of Radiation in Gases with a Narrow­Band Model and a Net is used for simulation of radiative heat transfers in non­gray gases. The proposed procedure is based

  6. Abstract--Airborne pollution and explosive gases threaten human health and occupational safety, therefore generating high

    E-Print Network [OSTI]

    Mason, Andrew

    Abstract--Airborne pollution and explosive gases threaten human health and occupational safety and a thumb-drive sized prototype system. I. INTRODUCTION xposure to air pollution consistently ranks among to occupational safety as energy demands rise. Airborne pollutants and explosive gases vary in both time and space

  7. Permeation of Gases in Polymers: Parameter Identification and Nonlinear Regression Analysis

    E-Print Network [OSTI]

    Scheichl, Robert

    Permeation of Gases in Polymers: Parameter Identification and Nonlinear Regression Analysis Robert at PARAOPE, Heidelberg, June 30th, 2004 #12;Overview · Permeation of gases in polymers ­ Application areas for diffusion in polymers ­ Description of the experimental device ­ Mathematical model · Parameter

  8. Heavy noble gases in solar wind delivered by Genesis mission Alex Meshik a,

    E-Print Network [OSTI]

    measured in the Genesis solar wind collectors generally agree with the less precise values obtained fromHeavy noble gases in solar wind delivered by Genesis mission Alex Meshik a, , Charles Hohenberg knowledge of the isotopic composition of the heavy noble gases in solar wind and, by inference, the Sun

  9. Preserving noble gases in a convecting mantle Helge M. Gonnermann1

    E-Print Network [OSTI]

    Mukhopadhyay, Sujoy

    of a processed and out- gassed lower-mantle source, residues of mantle melting10,11 , depleted in uranium and mixing of noble-gas-depleted slabs dilutes the concentrations of noble gases in the mantle, thereby melt, which forms the ocean crust and leaves the residual mantle severely depleted of noble gases

  10. Bose-Einstein condensates in 85 Rb gases at higher densities

    E-Print Network [OSTI]

    Glyde, Henry R.

    Bose-Einstein condensates in 85 Rb gases at higher densities A. R. Sakhel, J. L. DuBois, and H. R August 2002; published 31 December 2002 The Bose-Einstein condensation in trapped gases of 85 Rb find that there is a significant depletion of the condensate at T 0 K, for example, 25% at na3 10 2

  11. Localization of Bogoliubov quasiparticles in interacting Bose gases with correlated disorder P. Lugan1,2

    E-Print Network [OSTI]

    Boyer, Edmond

    ) in a weakly interacting Bose gas of chemical potential µ subjected to a disordered potential V . We introduce-Einstein condensates [40­48], interacting Bose gases at equilibrium [26, 49­72], strongly interacting Fermi gases [73 behaviors can be found in various situa- tions. For instance, weak repulsive interactions in a Bose gas

  12. Feasibility of reconstructing paleoatmospheric records of selected alkanes, methyl halides, and sulfur gases from Greenland ice cores

    E-Print Network [OSTI]

    Aydin, M.; Williams, M. B; Saltzman, E. S

    2007-01-01T23:59:59.000Z

    firn and ice at Summit, Greenland, J. Geophys. Res. , 98,AL. : TRACE GASES IN GREENLAND ICE CORE ¨ . Andreae Kettle,and sulfur gases from Greenland ice cores M. Aydin, 1 M. B.

  13. Emissions of Non-CO2 Greenhouse Gases From the Production and Use of Transportation Fuels and Electricity

    E-Print Network [OSTI]

    Delucchi, Mark

    1997-01-01T23:59:59.000Z

    EMISSIONS OF NON-CO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITYEMISSIONS OF NON-CO2 GREENHOUSE GASES FROM THE PRODUCTION AND USE OF TRANSPORTATION FUELS AND ELECTRICITY

  14. Oxygen buffering of Kilauea volcanic gases and the oxygen fugacity of Kilauea basalt

    SciTech Connect (OSTI)

    Gerlach, T.M. (Geological Survey, Vancouver, WA (United States))

    1993-02-01T23:59:59.000Z

    Volcanic gases collected during episode 1 of the Puu Oo eruption along the east rift zone of Kilauea Volcano, Hawaii, have uniform C-O-H-S-Cl-F compositions that are sharply depleted in CO[sub 2]. The CO[sub 2]-poor gases are typical of Type II volcanic gases (GERLACH and GRAEBER, 1985) and were emitted from evolved magma stored for a prolonged period of time in the east rift zone after releasing CO[sub 2]-rich gases during an earlier period of temporary residence in the summit magma chamber. The samples are remarkably free of contamination by atmospheric gases and meteoric water. Thermodynamic evaluation of the analytical data shows that the episode 1 gases have equilibrium compositions appropriate for temperatures between 935 and 1032[degrees]C. Open- and closed-system equilibrium models of species distributions for the episode 1 gases show unequivocally that coexisting lavas buffered the gas oxygen fugacities during cooling. These models indicate that the F[sub o[sub 2

  15. 2D Coulomb Gases and the Renormalized Energy

    E-Print Network [OSTI]

    Sandier, Etienne

    2012-01-01T23:59:59.000Z

    We study the statistical mechanics of classical two-dimensional "Coulomb gases" with general potential and arbitrary \\beta, the inverse of the temperature. Such ensembles also correspond to random matrix models in some particular cases. The formal limit case \\beta=\\infty corresponds to "weighted Fekete sets" and also falls within our analysis. It is known that in such a system points should be asymptotically distributed according to a macroscopic "equilibrium measure," and that a large deviations principle holds for this, as proven by Ben Arous and Zeitouni. By a suitable splitting of the Hamiltonian, we connect the problem to the "renormalized energy" W, a Coulombian interaction for points in the plane introduced in our prior work, which is expected to be a good way of measuring the disorder of an infinite configuration of points in the plane. By so doing, we are able to examine the situation at the microscopic scale, and obtain several new results: a next order asymptotic expansion of the partition function...

  16. Noble gases in the howardites Bholghati and Kapoeta

    SciTech Connect (OSTI)

    Swindle, T.D. (Univ. of Arizona, Tucson (USA)); Garrison, D.H.; Hohenberg, C.M.; Nichols, R.H.; Olinger, C.T. (Washington Univ., St. Louis, MO (USA)); Goswami, J.N. (Physical Research Laboratory, Ahmedabad (India))

    1990-08-01T23:59:59.000Z

    Analyses of noble gases in whole rock samples of the howardites Bholghati and Kapoeta and grain-size separates of Kapoeta yield evidence for excesses of the Xe isotopes {sup 129}Xe, {sup 131}Xe, {sup 132}Xe, {sup 134}Xe, and {sup 136}Xe in a low-temperature component, similar to lunar excess fission Xe. Such a component may be able to provide chronometric information if the relative abundances of radioactive progenitors ({sup 129}I, {sup 244}Pu, and {sup 238}U) can be determined, but the isotopic spectra we obtain are not sufficiently precise to do so. Eucritic clast BH-5 in Bholghati contains Xe produced in situ by the decay of {sup 244}Pu. Calculated fission Xe retention ages are 30-70 Ma after the formation of the solar system, consistent with the apparent presence of {sup 146}Sm decay products. Both the clast and the matrix of Bholghati have K-Ar ages of about 2 Ga, suggesting a common thermal event at least that recently.

  17. In-Situ Microbial Conversion of Sequestered Greenhouse Gases

    SciTech Connect (OSTI)

    Scott, A R; Mukhopadhyay, M; Balin, D F

    2012-09-06T23:59:59.000Z

    The objectives of the project are to use microbiological in situ bioconversion technology to convert sequestered or naturally-occurring greenhouse gases, including carbon dioxide and carbon monoxide, into methane and other useful organic compounds. The key factors affecting coal bioconversion identified in this research include (1) coal properties, (2) thermal maturation and coalification process, (3) microbial population dynamics, (4) hydrodynamics (5) reservoir conditions, and (6) the methodology of getting the nutrients into the coal seams. While nearly all cultures produced methane, we were unable to confirm sustained methane production from the enrichments. We believe that the methane generation may have been derived from readily metabolized organic matter in the coal samples and/or biosoluble organic material in the coal formation water. This raises the intriguing possibility that pretreatment of the coal in the subsurface to bioactivate the coal prior to the injection of microbes and nutrients might be possible. We determined that it would be more cost effective to inject nutrients into coal seams to stimulate indigenous microbes in the coal seams, than to grow microbes in fermentation vats and transport them to the well site. If the coal bioconversion process can be developed on a larger scale, then the cost to generate methane could be less than $1 per Mcf

  18. Energy Consumption and Potential for Energy Conservation in the Steel Industry 

    E-Print Network [OSTI]

    Hughes, M. L.

    1979-01-01T23:59:59.000Z

    percent (weight basis) of the input coal is converted to blast furnace coke and coke breeze and the remaining 30 percent is converted to coke oven gas, tar and li~t oils. A number of chemicals are extracted from these streams, and in at least two... in the world are identical. In the iron-ore reduction process there are three separate operations: blast furnaces, ore agglomerating facilities other than the mine-site preparation previously mentioned, and coke ovens -- the blast furnaces being the central...

  19. Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.

  20. Vacuum carbonate desulfurization and claus sulfur recovery system at No. 11 battery

    SciTech Connect (OSTI)

    Ellis, A.

    1981-01-01T23:59:59.000Z

    The vacuum carbonate process functions above 90% efficiency and satisfactorily removes the HCN and sulfur compounds from the coke oven gas generated at No. 11 Battery. It has been noted that a large quantity of energy is required for the operation of the vacuum carbonate system. Normally 544,617 kg (1.2 million lbs of steam) and 5.4 thousand kWh of electricity are used per day to maintain the system's temperatures and pressures. The processed coke oven gases from the system satisfy industrial and environmental standards as a combustible fuel. The HCN destruction unit reduces the corrosive HCN to concentrations below .07% of the acid gas stream and offers the necessary protection to the downstream modified Claus unit. The Claus unit at No. 11 Battery operates at 98% efficiency and produces 5896 kg (6.5 tons) of sulfur per day. The liquid sulfur generated in the Claus unit is a high quality product of 99% purity. 7 figures, 3 tables.

  1. Quantifying emissions of greenhouse gases from South Asia through a targeted measurement campaign

    E-Print Network [OSTI]

    Ganesan, Anita Lakshmi

    2013-01-01T23:59:59.000Z

    Methane (CH 4 ), nitrous oxide (N20) and sulfur hexafluoride (SF6) are powerful greenhouse gases with global budgets that are well-known but regional distributions that are not adequately constrained for the purposes of ...

  2. Spatio-temporal theory of lasing action in optically-pumped rotationally excited molecular gases

    E-Print Network [OSTI]

    Chua, Song-Liang

    We investigate laser emission from optically-pumped rotationally excited molecular gases confined in a metallic cavity. To this end, we have developed a theoretical framework able to accurately describe, both in the spatial ...

  3. Field-driven dynamics of dilute gases, viscous liquids and polymer chains

    E-Print Network [OSTI]

    Mohan, Aruna, 1981-

    2007-01-01T23:59:59.000Z

    This thesis is concerned with the exploration of field-induced dynamical phenomena arising in dilute gases, viscous liquids and polymer chains. The problems considered herein pertain to the slip-induced motion of a rigid, ...

  4. Eddy covariance flux measurements of pollutant gases in urban Mexico City

    E-Print Network [OSTI]

    Velasco, Erik

    Eddy covariance (EC) flux measurements of the atmosphere/surface exchange of gases over an urban area are a direct way to improve and evaluate emissions inventories, and, in turn, to better understand urban atmospheric ...

  5. Fact #825: June 16, 2014 Tier 3 Non-Methane Organic Gases Plus...

    Broader source: Energy.gov (indexed) [DOE]

    organic gases (NMOG) and nitrogen oxides (NOx) that new light vehicles with gasoline engines are allowed to produce for model years 2017 to 2025. These standards apply to a...

  6. Evolution and stability of shock waves in dissipative gases characterized by activated inelastic collisions

    E-Print Network [OSTI]

    Sirmas, Nick

    2015-01-01T23:59:59.000Z

    Previous experiments have revealed that shock waves driven through dissipative gases may become unstable, for example, in granular gases, and in molecular gases undergoing strong relaxation effects. The mechanisms controlling these instabilities are not well understood. We successfully isolated and investigated this instability in the canonical problem of piston driven shock waves propagating into a medium characterized by inelastic collision processes. We treat the standard model of granular gases, where particle collisions are taken as inelastic with constant coefficient of restitution. The inelasticity is activated for sufficiently strong collisions. Molecular dynamic simulations were performed for 30,000 particles. We find that all shock waves investigated become unstable, with density non-uniformities forming in the relaxation region. The wavelength of these fingers is found comparable to the characteristic relaxation thickness. Shock Hugoniot curves for both elastic and inelastic collisions were obtaine...

  7. Biological sweetening of energy gases mimics in biotrickling filters Marc Fortuny a,c

    E-Print Network [OSTI]

    in energy-rich gases such as biogas from anaerobic digesters which may contain H2S concentrations exceeding: Hydrogen sulfide; Gas sweetening; Biotrickling filter; Desulfurization; Fuel gas; Biogas 1. Introduction

  8. Method and apparatus for separating mixtures of gases using an acoustic wave

    DOE Patents [OSTI]

    Geller, Drew A.; Swift, Gregory W.; Backhaus, Scott N.

    2004-05-11T23:59:59.000Z

    A thermoacoustic device separates a mixture of gases. An elongated duct is provided with first and second ends and has a length that is greater than the wavelength of sound in the mixture of gases at a selected frequency, and a diameter that is greater than a thermal penetration depth in the mixture of gases. A first acoustic source is located at the first end of the duct to generate acoustic power at the selected frequency. A plurality of side branch acoustic sources are spaced along the length of the duct and are configured to introduce acoustic power into the mixture of gases so that a first gas is concentrated at the first end of the duct and a second gas is concentrated at the second end of the duct.

  9. What are greenhouse gases? Many chemical compounds in the atmosphere act as

    E-Print Network [OSTI]

    , Michigan State University, 2 Michigan State University Extension Climate Change and Agriculture Fact Sheet greenhouse gases carbon dioxide, methane, and nitrous oxide over the past 2000 years. Data are from ice core

  10. Quantum Cattaneo wave equation for ultra-short laser pulses interaction with electron and nucleon gases

    E-Print Network [OSTI]

    Marciak-Kozlowska, J

    2011-01-01T23:59:59.000Z

    In this paper the quantum Cattaneo wave equation for ultra-short laser pulses interaction with medium is obtained . The explicit formulae for electron and nucleon gases are presented

  11. Quantum coherence and magnetism in bosonic and fermionic gases of ultracold atoms

    E-Print Network [OSTI]

    Jo, Gyu-Boong

    2010-01-01T23:59:59.000Z

    In this thesis, two sets of experimental studies in bosonic and fermionic gases are described. In the first part of the thesis, itinerant ferromagnetism was studied in a strongly interacting Fermi gas of ultracold atoms. ...

  12. Quantum Cattaneo wave equation for ultra-short laser pulses interaction with electron and nucleon gases

    E-Print Network [OSTI]

    J Marciak-Kozlowska; Miroslaw Kozlowski

    2011-10-21T23:59:59.000Z

    In this paper the quantum Cattaneo wave equation for ultra-short laser pulses interaction with medium is obtained . The explicit formulae for electron and nucleon gases are presented

  13. Surface interactions involved in flashover with high density electronegative gases.

    SciTech Connect (OSTI)

    Hodge, Keith Conquest; Warne, Larry Kevin; Jorgenson, Roy Eberhardt; Wallace, Zachariah Red; Lehr, Jane Marie

    2010-01-01T23:59:59.000Z

    This report examines the interactions involved with flashover along a surface in high density electronegative gases. The focus is on fast ionization processes rather than the later time ionic drift or thermalization of the discharge. A kinetic simulation of the gas and surface is used to examine electron multiplication and includes gas collision, excitation and ionization, and attachment processes, gas photoionization and surface photoemission processes, as well as surface attachment. These rates are then used in a 1.5D fluid ionization wave (streamer) model to study streamer propagation with and without the surface in air and in SF6. The 1.5D model therefore includes rates for all these processes. To get a better estimate for the behavior of the radius we have studied radial expansion of the streamer in air and in SF6. The focus of the modeling is on voltage and field level changes (with and without a surface) rather than secondary effects, such as, velocities or changes in discharge path. An experiment has been set up to carry out measurements of threshold voltages, streamer velocities, and other discharge characteristics. This setup includes both electrical and photographic diagnostics (streak and framing cameras). We have observed little change in critical field levels (where avalanche multiplication sets in) in the gas alone versus with the surface. Comparisons between model calculations and experimental measurements are in agreement with this. We have examined streamer sustaining fields (field which maintains ionization wave propagation) in the gas and on the surface. Agreement of the gas levels with available literature is good and agreement between experiment and calculation is good also. Model calculations do not indicate much difference between the gas alone versus the surface levels. Experiments have identified differences in velocity between streamers on the surface and in the gas alone (the surface values being larger).

  14. ACID GASES IN CO2-RICH SUBSURFACE GEOLOGIC ENVIRONMENTS

    SciTech Connect (OSTI)

    Chialvo, Ariel A [ORNL] [ORNL; Vlcek, Lukas [ORNL] [ORNL; Cole, David [Ohio State University] [Ohio State University

    2013-01-01T23:59:59.000Z

    The analysis of species behavior involving dilute fluid environments has been crucial for the advance of modern solvation thermodynamics through molecular-based formalisms to guide the development of macroscopic regression tools in the description of fluid behavior and correlation of experimental data (Chialvo 2013). Dilute fluid environments involving geologic formations are of great theoretical and practical relevance regardless of the thermodynamic state conditions. The most challenging systems are those involving highly compressible and reactive confined environments, i.e., where small perturbations of pressure and/or temperature can trigger considerable density changes. This in turn can alter significantly the species solvation, their preferential solvation, and consequently, their reactivity with one another and with the surrounding mineral surfaces whose outcome is the modification of the substrate porosity and permeability, and ultimately, the integrity of the mineral substrates. Considering that changes in porosity and permeability resulting from dissolution and precipitation phenomena in confined environments are at the core of the aqueous CO2-mineral interactions, and that caprock integrity (e.g., sealing capacity) depends on these key parameters, it is imperative to gain fundamental understanding of the mineral-fluid interfacial phenomena and fluid-fluid equilibria under mineral confinement at subsurface conditions. In order to undertand the potential effects of acid gases as contaminants of supercritical CO2 streams, in the next section we will discuss the thermodynamic behavior of CO2 fluid systems by addressing two crucial issues in the context of carbon capture, utilization and sequestration (CCUS) technologies: (i) Why should we consider (acid gas) CO2 impurities? and (ii) Why are CO2 fluid - mineral interactions of paramount relevance?

  15. Radiative precursors driven by converging blast waves in noble gases

    SciTech Connect (OSTI)

    Burdiak, G. C.; Lebedev, S. V.; Harvey-Thompson, A. J.; Swadling, G. F.; Suzuki-Vidal, F.; Hall, G. N.; Khoory, E.; Pickworth, L.; Bland, S. N.; Grouchy, P. de; Skidmore, J.; Suttle, L.; Bennett, M.; Niasse, N. P. L. [Blackett Laboratory, Imperial College London SW7 2BW (United Kingdom)] [Blackett Laboratory, Imperial College London SW7 2BW (United Kingdom); Williams, R. J. R. [Atomic Weapons Establishment, Aldermaston RG7 4PR (United Kingdom)] [Atomic Weapons Establishment, Aldermaston RG7 4PR (United Kingdom); Blesener, K.; Atoyan, L.; Cahill, A.; Hoyt, C.; Potter, W. [Laboratory of Plasma Studies, Cornell University, Ithaca, New York 14853 (United States)] [Laboratory of Plasma Studies, Cornell University, Ithaca, New York 14853 (United States); and others

    2014-03-15T23:59:59.000Z

    A detailed study of the radiative precursor that develops ahead of converging blast waves in gas-filled cylindrical liner z-pinch experiments is presented. The experiment is capable of magnetically driving 20?km s{sup ?1} blast waves through gases of densities of the order 10{sup ?5} g cm{sup ?3} (see Burdiak et al. [High Energy Density Phys. 9(1), 52–62 (2013)] for a thorough description). Data were collected for Ne, Ar, and Xe gas-fills. The geometry of the setup allows a determination of the plasma parameters both in the precursor and across the shock, along a nominally uniform line of sight that is perpendicular to the propagation of the shock waves. Radiation from the shock was able to excite NeI, ArII, and XeII/XeIII precursor spectral features. It is shown that the combination of interferometry and optical spectroscopy data is inconsistent with upstream plasmas being in LTE. Specifically, electron density gradients do not correspond to any apparent temperature change in the emission spectra. Experimental data are compared to 1D radiation hydrodynamics HELIOS-CR simulations and to PrismSPECT atomic physics calculations to assist in a physical interpretation of the observations. We show that upstream plasma is likely in the process of being radiatively heated and that the emission from a small percentage of ionised atoms within a cool background plasma dominates the emission spectra. Experiments were carried out on the MAGPIE and COBRA pulsed-power facilities at Imperial College London and Cornell University, respectively.

  16. Methods for separating oxygen from oxygen-containing gases

    DOE Patents [OSTI]

    Mackay, Richard (Lafayette, CO); Schwartz, Michael (Boulder, CO); Sammells, Anthony F. (Boulder, CO)

    2000-01-01T23:59:59.000Z

    This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula: A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ; where x and x' are greater than 0; y and y' are greater than 0; x+x' is less than or equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; and B' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements. The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane include A.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z, where x is about 0.3 to about 0.5, x' is about 1.5 to about 1.7, y is 0.6, y' is between about 1.0 and 1.4 and B is Ga or Al.

  17. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOE Patents [OSTI]

    Natesan, K.

    1992-11-17T23:59:59.000Z

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9--30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000--1100 C. 7 figs.

  18. Iron-based alloys with corrosion resistance to oxygen-sulfur mixed gases

    DOE Patents [OSTI]

    Natesan, Krishnamurti (Naperville, IL)

    1992-01-01T23:59:59.000Z

    An iron-based alloy with improved performance with exposure to oxygen-sulfur mixed gases with the alloy containing about 9-30 wt. % Cr and a small amount of Nb and/or Zr implanted on the surface of the alloy to diffuse a depth into the surface portion, with the alloy exhibiting corrosion resistance to the corrosive gases without bulk addition of Nb and/or Zr and without heat treatment at temperatures of 1000.degree.-1100.degree. C.

  19. Method of removing and recovering elemental sulfur from highly reducing gas streams containing sulfur gases

    DOE Patents [OSTI]

    Gangwal, Santosh K.; Nikolopoulos, Apostolos A.; Dorchak, Thomas P.; Dorchak, Mary Anne

    2005-11-08T23:59:59.000Z

    A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

  20. Molecular extended thermodynamics of rarefied polyatomic gases and wave velocities for increasing number of moments

    SciTech Connect (OSTI)

    Arima, Takashi, E-mail: tks@stat.nitech.ac.jp [Center for Social Contribution and Collaboration, Nagoya Institute of Technology (Japan); Mentrelli, Andrea, E-mail: andrea.mentrelli@unibo.it [Department of Mathematics and Research Center of Applied Mathematics (CIRAM), University of Bologna (Italy); Ruggeri, Tommaso, E-mail: tommaso.ruggeri@unibo.it [Department of Mathematics and Research Center of Applied Mathematics (CIRAM), University of Bologna (Italy)

    2014-06-15T23:59:59.000Z

    Molecular extended thermodynamics of rarefied polyatomic gases is characterized by two hierarchies of equations for moments of a suitable distribution function in which the internal degrees of freedom of a molecule is taken into account. On the basis of physical relevance the truncation orders of the two hierarchies are proven to be not independent on each other, and the closure procedures based on the maximum entropy principle (MEP) and on the entropy principle (EP) are proven to be equivalent. The characteristic velocities of the emerging hyperbolic system of differential equations are compared to those obtained for monatomic gases and the lower bound estimate for the maximum equilibrium characteristic velocity established for monatomic gases (characterized by only one hierarchy for moments with truncation order of moments N) by Boillat and Ruggeri (1997) (?{sub (N)}{sup E,max})/(c{sub 0}) ??(6/5 (N?1/2 )),(c{sub 0}=?(5/3 k/m T)) is proven to hold also for rarefied polyatomic gases independently from the degrees of freedom of a molecule. -- Highlights: •Molecular extended thermodynamics of rarefied polyatomic gases is studied. •The relation between two hierarchies of equations for moments is derived. •The equivalence of maximum entropy principle and entropy principle is proven. •The characteristic velocities are compared to those of monatomic gases. •The lower bound of the maximum characteristic velocity is estimated.

  1. Adsorption of Hydrogen Sulfide onto Activated Carbon Fibers: Effect of

    E-Print Network [OSTI]

    Borguet, Eric

    . These processes include natural gas processing, petroleum refining, petrochemical plants, Kraft mills, coke ovens, and coal gasifiers. H2S concentrations in these processes vary from 0 to 60 vol % (6). The Claus process

  2. HOW TO LIVE (almost) FOREVER Justyna Derkach, UG Lab/Research

    E-Print Network [OSTI]

    Thompson, Michael

    before you work with these. acrylonitrile arsenic asbestos benzene coke oven emissions ethylene from ABB Scientific Stores or Justyna ­ JHE-A106) #12;NASTIES (designated substances) More paperwork

  3. 1 novembre 8, 2011 Title: The Employment Potential of Site Remediation Policies: a Micro-

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , the first gathering gasworks and coke ovens and the other dealing with petrol filling stations. As regards are only beginning to design a policy. It is very likely that this will become a major policy issue

  4. EAST CAROLINA UNIVERSITY HAZARDOUS CHEMICAL USE GRANT REVIEW FORM ECU policy requires that all grant proposals involving the use of hazardous chemicals be reviewed by an institutional review committee or

    E-Print Network [OSTI]

    -benezene 4-Aminodiphenyl Asbestos Coal tar pitch volatiles Methyl chloromethyl ether Formaldehyde Vinyl chloride Coke oven emissions 1,2-dibromo-3-chloropropane Lead Cadmium Benzene Cotton dust Chromium VI

  5. Waste Heat Recovery from High Temperature Off-Gases from Electric Arc Furnace

    SciTech Connect (OSTI)

    Nimbalkar, Sachin U [ORNL; Thekdi, Arvind [E3M Inc; Keiser, James R [ORNL; Storey, John Morse [ORNL

    2014-01-01T23:59:59.000Z

    This article presents a study and review of available waste heat in high temperature Electric Arc Furnace (EAF) off gases and heat recovery techniques/methods from these gases. It gives details of the quality and quantity of the sensible and chemical waste heat in typical EAF off gases, energy savings potential by recovering part of this heat, a comprehensive review of currently used waste heat recovery methods and potential for use of advanced designs to achieve a much higher level of heat recovery including scrap preheating, steam production and electric power generation. Based on our preliminary analysis, currently, for all electric arc furnaces used in the US steel industry, the energy savings potential is equivalent to approximately 31 trillion Btu per year or 32.7 peta Joules per year (approximately $182 million US dollars/year). This article describes the EAF off-gas enthalpy model developed at Oak Ridge National Laboratory (ORNL) to calculate available and recoverable heat energy for a given stream of exhaust gases coming out of one or multiple EAF furnaces. This Excel based model calculates sensible and chemical enthalpy of the EAF off-gases during tap to tap time accounting for variation in quantity and quality of off gases. The model can be used to estimate energy saved through scrap preheating and other possible uses such as steam generation and electric power generation using off gas waste heat. This article includes a review of the historical development of existing waste heat recovery methods, their operations, and advantages/limitations of these methods. This paper also describes a program to develop and test advanced concepts for scrap preheating, steam production and electricity generation through use of waste heat recovery from the chemical and sensible heat contained in the EAF off gases with addition of minimum amount of dilution or cooling air upstream of pollution control equipment such as bag houses.

  6. Phase Behavior of Light Gases in Hydrocarbon and Aqueous Solvents

    SciTech Connect (OSTI)

    Gasem, K.A.M.; Robinson, R.L., Jr.; Trvedi, N.J., Gao, W.

    1997-09-01T23:59:59.000Z

    Under previous support from the Department of Energy, an experimental facility has been established and operated to measure valuable vapor-liquid equilibrium data for systems of interest in the production and processing of coal fluids. To facilitate the development and testing of models for prediction of the phase behavior for such systems, we have acquired substantial amounts of data on the equilibrium phase compositions for binary mixtures of heavy hydrocarbon solvents with a variety of supercritical solutes, including hydrogen, methane, ethane, carbon monoxide, and carbon dioxide. The present project focuses on measuring the phase behavior of light gases and water in Fischer-Tropsch (F-T) type solvents at conditions encountered in indirect liquefaction processes and evaluating and developing theoretically-based correlating frameworks to predict the phase behavior of such systems. Specific goals of the proposed work include (a) developing a state-of-the-art experimental facility to permit highly accurate measurements of equilibrium phase compositions (solubilities) of challenging F-T systems, (b) measuring these properties for systematically-selected binary, ternary and molten F-T wax mixtures to provide critically needed input data for correlation development, (c) developing and testing models suitable for describing the phase behavior of such mixtures, and (d) presenting the modeling results in generalized, practical formats suitable for use in process engineering calculations. During the present reporting period, our solubility apparatus was refurbished and restored to full service. To test the experimental apparatus and procedures used, measurements were obtained for the solubility Of C0{sub 2} in benzene at 160{degrees}F. Having confirmed the accuracy of the newly acquired data in comparison with our previous measurements and data reported in the literature for this test system, we have begun to measure the solubility of hydrogen in hexane. The measurements for this system will cover the temperature range from 160 to 280{degrees}F at pressures to 2,500 psia. As part of our model evaluation efforts, we examined the predictive abilities of an alternative approach we have proposed for calculating the phase behavior properties of highly non-ideal systems. Using this approach, the liquid phase fugacities generated from an equation of state (EOS) are augmented by a fugacity deviation function correction. The correlative abilities of this approach are compared with those of an EOS equipped with the recently introduced Wong-Sandler (MWS) mixing rules. These two approaches are compared with the current methods for vapor-liquid equilibrium (VLE) calculations, i.e., the EOS (0/0) approach with the van der Waals mixing rules and the split (y/0) approach. The evaluations were conducted on a database comprised of non-ideal low pressure binary systems as well as asymmetric high pressure binary systems. These systems are of interest in the coal liquefaction and utilization processes. The Peng-Robinson EOS was selected for the purposes of this evaluation.

  7. Growing consumption of petroleum products worldwide has resulted in the proliferation of vessels carrying oil, chemicals, and gases

    E-Print Network [OSTI]

    Neimark, Alexander V.

    Growing consumption of petroleum products worldwide has resulted in the proliferation of vessels carrying oil, chemicals, and gases into our harbors. Meeting our society's surging demand for commodities

  8. Dynamics of a geothermal field traced by noble gases: Cerro Prieto, Mexico

    SciTech Connect (OSTI)

    Mazor, E. (Weizmann Inst. of Science, Rehovot, Israel); Truesdell, A.H.

    1981-01-01T23:59:59.000Z

    Noble gases have been measured mass spectrometrically in samples collected during 1977 from producing wells at Cerro Prieto. Positive correlations between concentrations of radiogenic (He, /sup 40/Ar) and atmospheric noble gases (Ne, Ar, and Kr) suggest the following dynamic model: the geothermal fluids originated from meteoric water penetrated to more than 2500 m depth (below the level of first boiling) and mixed with radiogenic helium and argon-40 formed in the aquifer rocks. Subsequently, small amounts of steam were lost by a Raleigh process (0 to 3%) and mixing with shallow cold water occurred (0 to 30%). Noble gases are sensitive tracers of boiling in the initial stages of 0 to 3% steam separation and complement other tracers, such as Cl or temperature, which are effective only beyond this range.

  9. The Spectral Backbone of Excitation Transport in Ultra-Cold Rydberg Gases

    E-Print Network [OSTI]

    Scholak, Torsten; Buchleitner, Andreas

    2014-01-01T23:59:59.000Z

    The spectral structure underlying excitonic energy transfer in ultra-cold Rydberg gases is studied numerically, in the framework of random matrix theory, and via self-consistent diagrammatic techniques. Rydberg gases are made up of randomly distributed, highly polarizable atoms that interact via strong dipolar forces. Dynamics in such a system is fundamentally different from cases in which the interactions are of short range, and is ultimately determined by the spectral and eigenvector structure. In the energy levels' spacing statistics, we find evidence for a critical energy that separates delocalized eigenstates from states that are localized at pairs or clusters of atoms separated by less than the typical nearest-neighbor distance. We argue that the dipole blockade effect in Rydberg gases can be leveraged to manipulate this transition across a wide range: As the blockade radius increases, the relative weight of localized states is reduced. At the same time, the spectral statistics -- in particular, the den...

  10. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

    1984-01-01T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  11. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1984-06-19T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  12. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1982-07-07T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  13. Method and apparatus for separating gases based on electrically and magnetically enhanced monolithic carbon fiber composite sorbents

    DOE Patents [OSTI]

    Judkins, Roddie R. (9917 Rainbow Dr., Knoxville, TN 37922); Burchell, Timothy D. (109 Greywood Pl., Oak Ridge, TN 37830)

    1999-01-01T23:59:59.000Z

    A method for separating gases or other fluids involves placing a magnetic field on a monolithic carbon fiber composite sorption material to more preferentially attract certain gases or other fluids to the sorption material to which a magnetic field is applied. This technique may be combined with the known "pressure swing adsorption" technique utilizing the same sorption material.

  14. Method and apparatus for separating gases based on electrically and magnetically enhanced monolithic carbon fiber composite sorbents

    DOE Patents [OSTI]

    Judkins, R.R.; Burchell, T.D.

    1999-07-20T23:59:59.000Z

    A method for separating gases or other fluids involves placing a magnetic field on a monolithic carbon fiber composite sorption material to more preferentially attract certain gases or other fluids to the sorption material to which a magnetic field is applied. This technique may be combined with the known pressure swing adsorption'' technique utilizing the same sorption material. 1 fig.

  15. Feasibility of reconstructing paleoatmospheric records of selected alkanes, methyl halides, and sulfur gases from Greenland ice cores

    E-Print Network [OSTI]

    Saltzman, Eric

    , and sulfur gases from Greenland ice cores M. Aydin,1 M. B. Williams,1 and E. S. Saltzman1 Received 7-lived atmospheric trace gases were measured in 25 ice core samples from Summit, Greenland. Samples were selected. The CH3Br results are consistent with previous observations of ``excess'' CH3Br in Greenland firn air

  16. A conceptual design of a Reactive Ion Etch back end system for the direct reuse of process gases

    E-Print Network [OSTI]

    Tiner, Paul Alan

    1994-01-01T23:59:59.000Z

    of these gases have proven to be detrimental to the environment. Because of the low percentage of utilization of the gas in a plasma process, these effects are a major concern. Few methods exist in industry today to dispose of unused gases, and all of the known...

  17. Kinetic theory for dilute cohesive granular gases with a square well potential

    E-Print Network [OSTI]

    Satoshi Takada; Kuniyasu Saitoh; Hisao Hayakawa

    2015-06-15T23:59:59.000Z

    We develop the kinetic theory of dilute cohesive granular gases in which the attractive part is described by a square well potential. We derive the hydrodynamic equations from the kinetic theory with the microscopic expressions for the dissipation rate and the transport coefficients. We check the validity of our theory by performing the direct simulation Monte Carlo.

  18. ESTABoues, a decision tool to assess greenhouse gases of sewage sludge treatment and di

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ORBIT2012 G ESTABoues, a decision tool to assess greenhouse gases of sewage sludge treatment and di-laure.reverdy@irstea.fr EXECUTIVE SUMMARY Sewage sludge production increases continuously reaching almost 20% (946 700 t 1 118 795% was incinerated (with or without household wastes) or landfilled. Nowadays, sludge reduction is a major concern

  19. Operational aspects of the desulfurization process of energy gases mimics in biotrickling filters5

    E-Print Network [OSTI]

    . Introduction Energy rich off-gases such as biogas are sometimes not used for electric power generation due impurities. H2S concentrations in biogas can range from 0.1 to 5 We dedicate this article to the memory/v (1000e20,000 ppmv), whereas the specifications for the maximum content of H2S in typical biogas

  20. Heat and Mass Transfer Modeling of Dry Gases in the Cathode of PEM Fuel Cells

    E-Print Network [OSTI]

    Stockie, John

    Heat and Mass Transfer Modeling of Dry Gases in the Cathode of PEM Fuel Cells M.J. Kermani1 J and N2, through the cathode of a proton exchange membrane (PEM) fuel cell is studied numerically) an energy equation, written in a form that has enthalpy as the dependent variable. Keywords: PEM fuel cells

  1. Diffusion of gases in air and its affect on oxygen deficiency hazard abatement

    SciTech Connect (OSTI)

    Theilacker, J.C.; White, M.J.; /Fermilab

    2005-09-01T23:59:59.000Z

    Density differences between air and released gases of cryogenic systems have been used to either require special oxygen deficiency hazard (ODH) control measures, or as a means of abatement. For example, it is not uncommon to assume that helium spills will quickly collect at the ceiling of a building or enclosure and will efficiently exit at the nearest vertical penetration or vent. Oxygen concentration reduction was found to be detectable during a localized helium spill throughout the entire 6.3 km Tevatron tunnel. This prompted us to perform diffusion tests in air with common gases used at Fermilab. The tests showed that gases, more readily than expected, diffused through an air column in the direction opposing buoyancy. Test results for helium and sulfur hexafluoride are presented. A system of tests were performed to better understand how easily released gases would fully mix with air and whether they remained fully mixed. The test results have been applied to a new system at Fermilab for ODH abatement.

  2. Ozone-depleting substances and the greenhouse gases HFCs, PFCs and

    E-Print Network [OSTI]

    Ozone-depleting substances and the greenhouse gases HFCs, PFCs and SF6 Danish consumption contribution to the debate on environmental policy in Denmark. #12;3 Contents 1 SUMMARY 5 1.1 OZONE OZONE-DEPLETING SUBSTANCES 18 3.1 IMPORTS AND EXPORTS 18 3.1.1 CFCs 18 3.1.2 Tetrachloromethane 19 3

  3. Anode supported single chamber solid oxide fuel cells operating in exhaust gases of thermal engine

    E-Print Network [OSTI]

    Boyer, Edmond

    Anode supported single chamber solid oxide fuel cells operating in exhaust gases of thermal engine. Conventional solid oxide fuel cells are separated into two compartments containing each electrode split hydrocarbons, pollutant emissions reduction hal-01056363,version1-21Aug2014 #12;1. Introduction Solid oxide

  4. A Biomass-based Model to Estimate the Plausibility of Exoplanet Biosignature Gases

    E-Print Network [OSTI]

    Seager, S; Hu, R

    2013-01-01T23:59:59.000Z

    Biosignature gas detection is one of the ultimate future goals for exoplanet atmosphere studies. We have created a framework for linking biosignature gas detectability to biomass estimates, including atmospheric photochemistry and biological thermodynamics. The new framework is intended to liberate predictive atmosphere models from requiring fixed, Earth-like biosignature gas source fluxes. New biosignature gases can be considered with a check that the biomass estimate is physically plausible. We have validated the models on terrestrial production of NO, H2S, CH4, CH3Cl, and DMS. We have applied the models to propose NH3 as a biosignature gas on a "cold Haber World," a planet with a N2-H2 atmosphere, and to demonstrate why gases such as CH3Cl must have too large of a biomass to be a plausible biosignature gas on planets with Earth or early-Earth-like atmospheres orbiting a Sun-like star. To construct the biomass models, we developed a functional classification of biosignature gases, and found that gases (such...

  5. The origins and concentrations of water, carbon, nitrogen and noble gases on Earth

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 The origins and concentrations of water, carbon, nitrogen and noble gases on Earth Bernard Marty (PSN) are still present in the mantle, presumably signing the sequestration of PSN gas at an early), and up to ~500 ppm C, both largely sequestrated in the solid Earth. This volatile content is equivalent

  6. Kolstad: EKC Dec 2005 Interpreting Estimated Environmental Kuznets Curves for Greenhouse Gases

    E-Print Network [OSTI]

    Kolstad, Charles

    Kolstad: EKC Dec 2005 Interpreting Estimated Environmental Kuznets Curves for Greenhouse Gases to interpret a relationship between income and carbon emissions in a country (the environmental Kuznets curve), it was primarily concerned with Environmental Kuznets Curves (EKC) for greenhouse gas emissions. The EKC literature

  7. Greenhouse gases accounting and reporting for waste management - A South African perspective

    SciTech Connect (OSTI)

    Friedrich, Elena, E-mail: Friedriche@ukzn.ac.z [University of KwaZulu-Natal, CRECHE, School of Civil Engineering, Surveying and Construction, Howard College Campus, Durban (South Africa); Trois, Cristina [University of KwaZulu-Natal, CRECHE, School of Civil Engineering, Surveying and Construction, Howard College Campus, Durban (South Africa)

    2010-11-15T23:59:59.000Z

    This paper investigates how greenhouse gases are accounted and reported in the waste sector in South Africa. Developing countries (including South Africa) do not have binding emission reduction targets, but many of them publish different greenhouse gas emissions data which have been accounted and reported in different ways. Results show that for South Africa, inventories at national and municipal level are the most important tools in the process of accounting and reporting greenhouse gases from waste. For the development of these inventories international initiatives were important catalysts at national and municipal levels, and assisted in developing local expertise, resulting in increased output quality. However, discrepancies in the methodology used to account greenhouse gases from waste between inventories still remain a concern. This is a challenging issue for developing countries, especially African ones, since higher accuracy methods are more data intensive. Analysis of the South African inventories shows that results from the recent inventories can not be compared with older ones due to the use of different accounting methodologies. More recently the use of Clean Development Mechanism (CDM) procedures in Africa, geared towards direct measurements of greenhouse gases from landfill sites, has increased and resulted in an improvement of the quality of greenhouse gas inventories at municipal level.

  8. Analise Matematica III Turma Especial Ficha Extra 2 Termodinamica dos Gases Ideais

    E-Print Network [OSTI]

    Natário, José

    Anâ??alise Matemâ??atica III ­ Turma Especial Ficha Extra 2 ­ Termodinâ??amica dos Gases Ideais N Termodinâ??amica afirma que existe uma funâ?şcâ?ťao E : M # R, dita a energia interna do gâ??as, cuja derivadaâ??amicos gerais pela Segunda Lei da Termodinâ??amica. 2 #12;

  9. Abstract--Energy consumption and the concomitant Green House Gases (GHG) emissions of network infrastructures are

    E-Print Network [OSTI]

    Politčcnica de Catalunya, Universitat

    Abstract--Energy consumption and the concomitant Green House Gases (GHG) emissions of network as for their energy consumption. Renewable energy sources (e.g. solar, wind, tide, etc.) are emerging as a promising and the comparison of several energy-aware static routing and wavelength assignment (RWA) strategies for wavelength

  10. Effects of Biochar and Basalt Additions on Carbon Sequestration and Fluxes of Greenhouse Gases in Soils

    E-Print Network [OSTI]

    Vallino, Joseph J.

    Effects of Biochar and Basalt Additions on Carbon Sequestration and Fluxes of Greenhouse Gases Emissions--Carbon Dioxide Emissions--Sequestration and Storage--Biochar--Basalt--Organic Fertilizers, this investigation focuses on the range of potential of different soil additives to enhance sequestration and storage

  11. Simultaneous gas-chromatographic determination of four toxic gases generally present in combustion atmospheres. Final report

    SciTech Connect (OSTI)

    Endecott, B.R.; Sanders, D.C.; Chaturvedi, A.K.

    1994-09-01T23:59:59.000Z

    Measurement of combustion gases produced by burning aircraft cabin materials poses a continuing limitation for smoke toxicity research. Since toxic effects of gases depend on both their concentrations and duration of exposures, frequent atmosphere sampling is necessary to define the concentration-time curve. A gas chromatographic method was developed for the simultaneous analyses of carbon monoxide (CO), hydrogen sulfide (H2S), sulfur dioxide (SO2), and hydrogen cyanide (HCN). The method utilized an MTI M200 dual-column gas chromatograph (GC) equipped with 4-m molecular sieve-5A and 8-m PoraPlot-U capillary columns and two low-volume, high-sensitivity thermal conductivity detectors. Detectability (ppm)/retention times (seconds) for the gases were: CO (100/28); H2S (50/26); SO2 (125/76); HCN (60/108). The method was effective for determining these gases in mixtures and in the combustion atmospheres generated by burning wool (CO, HCN, and H2S) and modacrylic (CO and HCN) fabrics. Common atmospheric gaseous or combustion products (oxygen, carbon dioxide, nitrogen, water vapor, and other volatiles) did not interfere with the analyses. However, filtration of the combustion atmospheres was necessary to prevent restriction of the GC sampling inlet by smoke particulates. The speed, sensitivity, and selectivity of this method make it suitable for smoke toxicity research and for evaluating performance of passenger protective breathing equipment.

  12. Classical disordered ground states: Super-ideal gases and stealth and equi-luminous materials

    E-Print Network [OSTI]

    Torquato, Salvatore

    Classical disordered ground states: Super-ideal gases and stealth and equi-luminous materials of Materials, Princeton University, Princeton, New Jersey 08544, USA 4 Program in Applied and Computational focus on three classes of configurations with unique radiation scattering characteristics: i "stealth

  13. Centre for Business History to study development of industrial gases industry

    E-Print Network [OSTI]

    Guo, Zaoyang

    be overestimated and the study - funded by German-based gas and engineering company, the Linde Group - aims to give. Wolfgang Reitzle, Chief Executive Officer of Linde AG said: "Over time, industrial gases have changed fellow, also funded by Linde AG, and co-ordinating the project board monitoring progress on the project

  14. Nuclear fusion in gases of deuterium clusters heated with a femtosecond T. Ditmire,

    E-Print Network [OSTI]

    Ditmire, Todd

    Nuclear fusion in gases of deuterium clusters heated with a femtosecond laser* T. Ditmire, J deuterium­deuterium DD nuclear fusion. By diagnosing the fusion yield through measurements of 2.45 Me release of kinetic energy in fast ions can be harnessed to drive nuclear fusion between deuterium ions

  15. Experimental observation of a traveling plasma grating formed by two crossing filaments in gases

    SciTech Connect (OSTI)

    Durand, Magali [Laboratoire d'Optique Appliquee, ENSTA ParisTech-Ecole Polytechnique-CNRS, 91761 Palaiseau (France); ONERA, Chemin de la Huniere, 91761 Palaiseau (France); Liu Yi; Forestier, Benjamin; Houard, Aurelien; Mysyrowicz, Andre [Laboratoire d'Optique Appliquee, ENSTA ParisTech-Ecole Polytechnique-CNRS, 91761 Palaiseau (France)

    2011-03-21T23:59:59.000Z

    The spatial motion and effective duration of a traveling plasma grating formed by two interfering femtosecond laser filaments in gases is characterized by its Doppler effect imparted on a probe pulse. The shift velocity determined experimentally agrees with the theoretical calculations.

  16. Intercomparison of tritium and noble gases analyses, 3 and derived parameters excess air and recharge temperature

    E-Print Network [OSTI]

    Intercomparison of tritium and noble gases analyses, 3 H/3 He ages and derived parameters excess with the tritium­helium (3 H/3 He) method has become a powerful tool for hydrogeologists. The uncertainty in the inter- comparison for tritium analyses and ten laboratories participated in the noble gas

  17. PHYSICAL REVIEW A 81, 023611 (2010) Critical temperature of dilute Bose gases

    E-Print Network [OSTI]

    Ueltschi, Daniel

    2010-01-01T23:59:59.000Z

    and Daniel Ueltschi* Department of Mathematics, University of Warwick, Coventry CV4 7AL, United Kingdom quantum particles become winding Brownian bridges in one more dimension [1,16]. For dilute gases, Bose method to a test by computing the free energy of the effective model. As it turns out, it is equal

  18. On the Critical Temperature of Dilute Bose Gases Volker Betz and Daniel Ueltschi

    E-Print Network [OSTI]

    Betz, Volker

    of Mathematics, University of Warwick, Coventry, CV4 7AL, United Kingdom We compute the critical temperature quantum particles become winding Brownian bridges in one more dimension [1, 16]. For dilute gases, Bose responsible. Finally, we put our method to a test by computing the free energy of the effective model

  19. Internal structure and expansion dynamics of laser ablation plumes into ambient gases

    E-Print Network [OSTI]

    Harilal, S. S.

    Internal structure and expansion dynamics of laser ablation plumes into ambient gases S. S. Harilal 13 December 2002 The effect of ambient gas on the expansion dynamics of the plasma generated by laser together with time resolved emission diagnostics, a triple structure of the plume was observed

  20. Measurement and Analysis of the Relationship between Ammonia, Acid Gases, and Fine Particles in Eastern North

    E-Print Network [OSTI]

    Aneja, Viney P.

    ).2­4 Gas-to-particle conversion can be accomplished by condensation, which adds mass onto preMeasurement and Analysis of the Relationship between Ammonia, Acid Gases, and Fine Particles acid gas con- centrations of 0.23 g/m3 hydrochloric acid (standard deviation [SD] 0.2 g/m3 ); 1.14 g/m3

  1. Atmospheric Environment 42 (2008) 30763086 Scavenging of soluble gases by evaporating and growing cloud

    E-Print Network [OSTI]

    Elperin, Tov

    and condensation of a cloud droplet in the presence of soluble gases. It is assumed that gas absorption we performed numerical analysis of simultaneous heat and mass transfer during evaporation into account thermal effect of gas absorption. It was shown that nonlinear behavior of different parameters

  2. Truck Stop Electrification as a Strategy To Reduce Greenhouse Gases, Fuel Consumption and Pollutant Emissions

    E-Print Network [OSTI]

    Truck Stop Electrification as a Strategy To Reduce Greenhouse Gases, Fuel Consumption and Pollutant, Schneider, Lee, Bubbosh 2 ABSTRACT Extended truck idling is a very large source of fuel wastage, greenhouse, most long-haul truck drivers idle their vehicles for close to 10 hours per day to operate heating

  3. Theoretical Gas Phase Mass Transfer Coefficients for Endogenous Gases in the Lungs

    E-Print Network [OSTI]

    George, Steven C.

    Theoretical Gas Phase Mass Transfer Coefficients for Endogenous Gases in the Lungs PETER CONDORELLI, is produced within the tissue of the airways of the lungs.16 As an intercellular messenger, NO is involved is available regarding the basic gas exchange dynamics of NO in the lungs. Ingested ethanol EtOH is transported

  4. Coking Coal Import Costs - EIA

    Gasoline and Diesel Fuel Update (EIA)

    Import Costs for Selected Countries U.S. Dollars per Metric Ton1 (Average Unit Value, CIF2) Country 2001 2002 2003 2004 2005 2006 2007 2008 2009 Belgium 48.67 46.59 49.25 78.98...

  5. Converting Petroleum Coke to Electricity 

    E-Print Network [OSTI]

    Pavone, A.

    1992-01-01T23:59:59.000Z

    will compete economically with conventional coal and nature gas, both of which are currently experiencing low prices. Pipeline quality natural gas at the well is selling on average for $1.50 IM- Btu, while cleaned coal at the mine is under $1.00/M... pneumatically into the firebox. Supplementary fuel (10%) would be necessary to ignite the process. and be required continuously to maintain flame stability Firebox temperatues would average 2000-2500 degF. Air would be introduced at several different stages...

  6. Converting Petroleum Coke to Electricity

    E-Print Network [OSTI]

    Pavone, A.

    Changes in oil refining technology and economics are driving refiners to utilize thermal processes to maximize the conversion of heavy crude oil components to clean products. Since the primary unit operation to accomplish this objective...

  7. Thermal Plasma Systems for Industrial Processes 

    E-Print Network [OSTI]

    Fey, M. G.; Meyer, T. N.; Reed, W. H.; Philbrook, W. O.

    1982-01-01T23:59:59.000Z

    required to produce hot metal. To plasma superheat wind. energy is transferred to the air stream via a plasma torch. To maximize the coke reduction due to wind superheating. other fuels such as oil. natural gas. coke oven gas. and coal can be considered... tuyere injections of steam. oxygen, methane. natural gas. coke-oven gas. coal gas. fuel oils. or coals of various ranks is a two-stage blast furnace mass and heat balance developed by Rist and Meysson [12.13J and others at IRSID. A constraint...

  8. Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases

    DOE Patents [OSTI]

    Ayala, Raul E. (Clifton Park, NY)

    1993-01-01T23:59:59.000Z

    This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

  9. Modification of environmental control of cokemaking plant

    SciTech Connect (OSTI)

    Katoh, H.; Yasuno, M.; Gotch, T.; Yoshida, F.

    1993-01-01T23:59:59.000Z

    Recently, global environmental protection has been a great concern in the world. In the United States of America, the Clean Air Act (CAA) has been revised to control emissions strictly. Especially in the field of cokemaking, the restriction of fume emission from a coke oven is so severe that old coke ovens will stop operation with the application of CAA. In Japan, it is expected that more severe protection measures are going to be requested for keeping environmental quality. In this situation, it is indispensable to strengthen environmental protection measures for cokemaking plants to continue coke production in the 21st century. In Chiba Works, Kawasaki Steep Corp., the Ironmaking Department has been struggling for the improvement of environmental measures for. These activities for coke ovens are described in this report. The paper describes fume emission control from the coke oven door and dust emission control measures, including the dust monitoring system, prevention of secondary dust scattering from coke ovens, replacement of dedusters, and fume and dust control of stack emission.

  10. This article appeared in a journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research

    E-Print Network [OSTI]

    Leu, Tzong-Shyng "Jeremy"

    -scale reactor for producing hot metal where coke and coal are consumed as reducing agent and fuel, respectively]. In addition to coke, coal has also been extensively consumed in BFs for supplying heat through pulverized coal. At the same time, the consumptions of coal and coke will liberate a large amount of greenhouse gases

  11. Interaction with thermal radiation in the free expansion and mixing of ideal gases and Gibbs' paradox in classical thermodynamics

    E-Print Network [OSTI]

    A. Paglietti

    2009-04-26T23:59:59.000Z

    The standard theory of ideal gases ignores the interaction of the gas particles with the thermal radiation (photon gas) that fills the otherwise vacuum space between them. This is an unphysical feature of the theory since every material in this universe, and hence also the particles of a gas, absorbs and radiates thermal energy. The interaction with the thermal radiation that is contained within the volume of the body may be important in gases since the latter, unlike solids and liquids, are capable of undergoing conspicuous volume changes. Taking this interaction into account makes the behaviour of the ideal gases more realistic and removes Gibbs' paradox.

  12. Removal of oxides of nitrogen from gases in multi-stage coal combustion

    DOE Patents [OSTI]

    Mollot, D.J.; Bonk, D.L.; Dowdy, T.E.

    1998-01-13T23:59:59.000Z

    Polluting NO{sub x} gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO{sub x} gases are removed is directed to introducing NO{sub x}-free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor. 2 figs.

  13. Removal of oxides of nitrogen from gases in multi-stage coal combustion

    DOE Patents [OSTI]

    Mollot, Darren J. (Morgantown, WV); Bonk, Donald L. (Louisville, OH); Dowdy, Thomas E. (Orlando, FL)

    1998-01-01T23:59:59.000Z

    Polluting NO.sub.x gas values are removed from off-gas of a multi-stage coal combustion process which includes an initial carbonizing reaction, firing of char from this reaction in a fluidized bed reactor, and burning of gases from the carbonizing and fluidized bed reactions in a topping combustor having a first, fuel-rich zone and a second, fuel-lean zone. The improvement by means of which NO.sub.x gases are removed is directed to introducing NO.sub.x -free oxidizing gas such as compressor air into the second, fuel-lean zone and completing combustion with this source of oxidizing gas. Excess air fed to the fluidized bed reactor is also controlled to obtain desired stoichiometry in the first, fuel-rich zone of the topping combustor.

  14. Nuclear magnetic resonance of laser-polarized noble gases in molecules, materials and organisms

    SciTech Connect (OSTI)

    Goodson, Boyd M.

    1999-12-01T23:59:59.000Z

    Conventional nuclear magnetic resonance (NMR) spectroscopy and magnetic resonance imaging (MRI) are fundamentally challenged by the insensitivity that stems from the ordinarily low spin polarization achievable in even the strongest NMR magnets. However, by transferring angular momentum from laser light to electronic and nuclear spins, optical pumping methods can increase the nuclear spin polarization of noble gases by several orders of magnitude, thereby greatly enhancing their NMR sensitivity. This dissertation is primarily concerned with the principles and practice of optically pumped nuclear magnetic resonance (OPNMR). The enormous sensitivity enhancement afforded by optical pumping noble gases can be exploited to permit a variety of novel NMR experiments across many disciplines. Many such experiments are reviewed, including the void-space imaging of organisms and materials, NMR and MRI of living tissues, probing structure and dynamics of molecules in solution and on surfaces, and zero-field NMR and MRI.

  15. Free cooling and high-energy tails of granular gases with variable restitution coefficient

    E-Print Network [OSTI]

    Ricardo J. Alonso; Bertrand Lods

    2010-05-31T23:59:59.000Z

    We prove the so-called generalized Haff's law yielding the optimal algebraic cooling rate of the temperature of a granular gas described by the homogeneous Boltzmann equation for inelastic interactions with non constant restitution coefficient. Our analysis is carried through a careful study of the infinite system of moments of the solution to the Boltzmann equation for granular gases and precise Lp estimates in the selfsimilar variables. In the process, we generalize several results on the Boltzmann collision operator obtained recently for homogeneous granular gases with constant restitution coefficient to a broader class of physical restitution coefficients that depend on the collision impact velocity. This generalization leads to the so-called L1-exponential tails theorem. for this model.

  16. Radiolytic and radiolytically induced generation of gases in simulated waste solutions

    SciTech Connect (OSTI)

    Meisel, D.; Sauer, M.C. Jr.; Jonah, C.D.; Diamond, H.; Matheson, M.S.; Barnabas, F.; Cerny, E.; Cheng, Y.

    1990-12-31T23:59:59.000Z

    The radiolytic generation of gases in simulated mixed waste solutions was studied. Computer modeling of the non-homogeneous kinetic processes in these highly concentrated homogeneous solutions was attempted. The predictions of the modeling simulations were verified experimentally. Two sources for the radiolytic generation of H{sub 2} are identified: direct dissociation of highly energetic water molecules and hydrogen abstraction from the organic molecules by hydrogen atoms. Computer simulation of the homogeneous kinetics of the NO{sub X} system indicate that no N{sub 2}O will be produced in the absence of organic solutes and none was experimentally detected. It was also found that long term pre-irradiation of the simulated waste solutions leads to enhanced thermal production of these two gases. 22 refs., 5 figs., 3 tabs.

  17. Radiolytic and radiolytically induced generation of gases in simulated waste solutions

    SciTech Connect (OSTI)

    Meisel, D.; Sauer, M.C. Jr.; Jonah, C.D.; Diamond, H.; Matheson, M.S.; Barnabas, F.; Cerny, E.; Cheng, Y.

    1990-01-01T23:59:59.000Z

    The radiolytic generation of gases in simulated mixed waste solutions was studied. Computer modeling of the non-homogeneous kinetic processes in these highly concentrated homogeneous solutions was attempted. The predictions of the modeling simulations were verified experimentally. Two sources for the radiolytic generation of H{sub 2} are identified: direct dissociation of highly energetic water molecules and hydrogen abstraction from the organic molecules by hydrogen atoms. Computer simulation of the homogeneous kinetics of the NO{sub X} system indicate that no N{sub 2}O will be produced in the absence of organic solutes and none was experimentally detected. It was also found that long term pre-irradiation of the simulated waste solutions leads to enhanced thermal production of these two gases. 22 refs., 5 figs., 3 tabs.

  18. Process for removal of ammonia and acid gases from contaminated waters

    DOE Patents [OSTI]

    King, C.J.; Mackenzie, P.D.

    1982-09-03T23:59:59.000Z

    Contaminating basic gases, i.e., ammonia and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with stream, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  19. Process for removal of ammonia and acid gases from contaminated waters

    DOE Patents [OSTI]

    King, C. Judson (Kensington, CA); MacKenzie, Patricia D. (Berkeley, CA)

    1985-01-01T23:59:59.000Z

    Contaminating basic gases, i.e., ammonia, and acid gases, e.g., carbon dioxide, are removed from process waters or waste waters in a combined extraction and stripping process. Ammonia in the form of ammonium ion is extracted by an immiscible organic phase comprising a liquid cation exchange component, especially an organic phosphoric acid derivative, and preferably di-2-ethyl hexyl phosphoric acid, dissolved in an alkyl hydrocarbon, aryl hydrocarbon, higher alcohol, oxygenated hydrocarbon, halogenated hydrocarbon, and mixtures thereof. Concurrently, the acidic gaseous contaminants are stripped from the process or waste waters by stripping with steam, air, nitrogen, or the like. The liquid cation exchange component has the ammonia stripped therefrom by heating, and the component may be recycled to extract additional amounts of ammonia.

  20. A simple method to estimate entropy of atmospheric gases from their action

    E-Print Network [OSTI]

    Kennedy, Ivan R; Rose, Michael T; Crossan, Angus N

    2015-01-01T23:59:59.000Z

    A convenient model for estimating the total entropy ({\\Sigma}Si) of atmospheric gases based on physical action is proposed. This realistic approach is fully consistent with statistical mechanics, but uses the properties of translational, rotational and vibrational action to partition the entropy. When all sources of action are computed as appropriate non-linear functions, the total input of thermal energy ({\\Sigma}SiT) required to sustain a chemical system at specific temperatures (T) and pressures (p) can be estimated, yielding results in close agreement with published experimental third law values. Thermodynamic properties of gases including enthalpy, Gibbs energy and Helmholtz energy can be easily calculated from simple molecular and physical properties. We propose that these values for entropy are employed both chemically for reactions and physically for computing atmospheric profiles, the latter based on steady state heat flow equilibrating thermodynamics with gravity. We also predict that this applicati...

  1. Membranes, methods of making membranes, and methods of separating gases using membranes

    DOE Patents [OSTI]

    Ho, W. S. Winston

    2012-10-02T23:59:59.000Z

    Membranes, methods of making membranes, and methods of separating gases using membranes are provided. The membranes can include at least one hydrophilic polymer, at least one cross-linking agent, at least one base, and at least one amino compound. The methods of separating gases using membranes can include contacting a gas stream containing at least one of CO.sub.2, H.sub.2S, and HCl with one side of a nonporous and at least one of CO.sub.2, H.sub.2S, and HCl selectively permeable membrane such that at least one of CO.sub.2, H.sub.2S, and HCl is selectively transported through the membrane.

  2. Isotopic measurements of solar noble gases in individual micrometeorites from Greenland and Antarctica

    SciTech Connect (OSTI)

    Olinger, C.T.

    1990-01-01T23:59:59.000Z

    Noble gases are studied in individual 100 micron-size particles selected from Greenland and Antarctic glacial sediments. Noble gas isotopic and elemental patterns confirm the extraterrestrial origin of 81 out of 302 particles studied. Micrometeorites in this size range are particularly interesting because they correspond to the peak of the meteoritic mass flux distribution. Many particles studied are compositionally and morphologically similar to known meteoritic materials.

  3. Evolution and stability of shock waves in dissipative gases characterized by activated inelastic collisions

    E-Print Network [OSTI]

    Nick Sirmas; Matei I. Radulescu

    2015-01-14T23:59:59.000Z

    Previous experiments have revealed that shock waves driven through dissipative gases may become unstable, for example, in granular gases, and in molecular gases undergoing strong relaxation effects. The mechanisms controlling these instabilities are not well understood. We successfully isolated and investigated this instability in the canonical problem of piston driven shock waves propagating into a medium characterized by inelastic collision processes. We treat the standard model of granular gases, where particle collisions are taken as inelastic with constant coefficient of restitution. The inelasticity is activated for sufficiently strong collisions. Molecular dynamic simulations were performed for 30,000 particles. We find that all shock waves investigated become unstable, with density non-uniformities forming in the relaxation region. The wavelength of these fingers is found comparable to the characteristic relaxation thickness. Shock Hugoniot curves for both elastic and inelastic collisions were obtained analytically and numerically. Analysis of these curves indicate that the instability is not of the Bethe-Zeldovich-Thompson or Dyakov-Kontorovich types. Analysis of the shock relaxation rates and rates for clustering in a convected fluid element with the same thermodynamic history outruled the clustering instability of a homogeneous granular gas. Instead, wave reconstruction of the early transient evolution indicates that the onset of instability occurs during the re-pressurization of the gas following the initial relaxation of the medium behind the lead shock. This re-pressurization gives rise to internal pressure waves in the presence of strong density gradients. This indicates that the mechanism of instability is more likely of the vorticity-generating Richtmyer-Meshkov type, relying on the action of the inner pressure waves development during the transient relaxation.

  4. The origin of hydrothermal and other gases in the Kenya Rift Valley

    SciTech Connect (OSTI)

    Darling, W.G. [British Geological Survey, Wallingford (United Kingdom)] [British Geological Survey, Wallingford (United Kingdom); Griesshaber, E. [Max-Planck Institut fuer Chemie, Mainz (Germany)] [Max-Planck Institut fuer Chemie, Mainz (Germany); Andrews, J.N. [Univ. of Reading (United Kingdom)] [and others] [Univ. of Reading (United Kingdom); and others

    1995-06-01T23:59:59.000Z

    The Kenya Rift Valley (KRV) is part of a major continental rift system from which much outgassing is presently occurring. Previous research on gases in the KRV has tended to concentrate on their geothermal implications; the present paper is an attempt to broaden the interpretation by consideration of new data including helium and carbon isotope analyses from a wide cross-section of sites. In order to do this, gases have been divided into categories dependent on origin. N{sub 2} and noble gases are for the most part atmospherically derived, although their relative concentrations may be altered from ASW ratios by various physical processes. Reduced carbon (CH{sub 4} and homologues) appears to be exclusively derived from the shallow crust, with thermogenic {delta}{sup 13}C values averaging -25{per_thousand} PDB for CH{sub 4}. H{sub 2} is likely also to be crustally formed. CO{sub 2}, generally a dominant constituent, has a narrow {delta}{sup 13}C range averaging -3.7{per_thousand} PDB, and is likely to be derived with little modification from the upper mantle. Consideration of the ratio C/{sup 3}He supports this view in most cases. Sulphur probably also originates there. Ratios of {sup 3}He/{sup 4}He reach a MORB-like maximum of 8.0 R/R{sub A} and provide the best indication of an upper mantle source of gases beneath the KRV. A correlation between {sup 3}He/{sup 4}He and the hydrocarbon parameter log (C{sub 1}/{Sigma}C{sub 2-4}) appears to be primarily temperature related. The highest {sup 3}He/{sup 4}He ratios in spring waters are associated with basalts, perhaps because of the leaching of basalt glasses. There may be a structural control on {sup 3}He/{sup 4}He ratios in the KRV as a whole.

  5. Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases

    SciTech Connect (OSTI)

    Gardner, Todd H.; Berry, David A.; Lyons, K. David; Beer, Stephen K.; Monahan, Michael J.

    2001-11-06T23:59:59.000Z

    The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for Vision 21 integrated gasification combined cycle (IGCC) power generation plants. In this plan, the U. S. Department of Energy will construct ultra-clean, modular, co-production IGCC power plants each with chemical products tailored to meet the demands of specific regional markets. The catalysts employed in these co-production modules, for example water-gas-shift and Fischer-Tropsch catalysts, are readily poisoned by hydrogen sulfide (H{sub 2}S), a sulfur contaminant, present in the coal-derived fuel gases. To prevent poisoning of these catalysts, the removal of H{sub 2}S down to the parts-per-billion level is necessary. Historically, research into the purification of coal-derived fuel gases has focused on dry technologies that offer the prospect of higher combined cycle efficiencies as well as improved thermal integration with co-production modules. Primarily, these concepts rely on a highly selective process separation step to remove low concentrations of H{sub 2}S present in the fuel gases and produce a concentrated stream of sulfur bearing effluent. This effluent must then undergo further processing to be converted to its final form, usually elemental sulfur. Ultimately, desulfurization of coal-derived fuel gases may cost as much as 15% of the total fixed capital investment (Chen et al., 1992). It is, therefore, desirable to develop new technology that can accomplish H{sub 2}S separation and direct conversion to elemental sulfur more efficiently and with a lower initial fixed capital investment.

  6. One-dimensional ultracold atomic gases: impact of the effective range on integrability

    E-Print Network [OSTI]

    Tom Kristensen; Ludovic Pricoupenko

    2015-06-12T23:59:59.000Z

    The one-dimensional one-component Bose and Fermi gases are considered in a regime of large effective range. We focus our study on the three-body problem, which is at the heart of the integra-bility issue. For fermions, the vicinity of the integrability is characterized by large deviations with respect to the predictions of the Bethe ansatz. For the consistency of the contact model, it appears essential to take into account the contact of three particles.

  7. Temperature jump in degenerate quantum gases in the presence of a Bose - Einstein condensate

    E-Print Network [OSTI]

    A. V. Latyshev; A. A. Yushkanov

    2010-01-04T23:59:59.000Z

    We construct a kinetic equation modeling the behavior of degenerate quantum Bose gases whose collision rate depends on the momentum of elementary excitations. We consider the case where the phonon component is the decisive factor in the elementary excitations. We analytically solve the half-space boundary value problem of the temperature jump at the boundary of the degenerate Bose gas in the presence of a Bose -- Einstein condensate.

  8. New York Nonhydrocarbon Gases Removed from Natural Gas (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office ofthrough 1996) inThousandWithdrawals (Million CubicYearNonhydrocarbon Gases

  9. Trace water vapor determination in nitrogen and corrosive gases using infrared spectroscopy

    SciTech Connect (OSTI)

    Espinoza, L.H.; Niemczyk, T.M. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Chemistry; Stallard, B.R.; Garcia, M.J. [Sandia National Labs., Albuquerque, NM (United States)

    1997-06-01T23:59:59.000Z

    The generation of particles in gas handling systems as a result of corrosion is a major concern in the microelectronics industry. The corrosion can be caused by the presence of trace quantities of water in corrosive gases such as HCl or HBr. FTIR spectroscopy has been shown to be a method that can be made compatible with corrosive gases and is capable of detecting low ppb levels of water vapor. In this report, the application of FTIR spectroscopy combined with classical least squares multivariate calibration to detect trace H{sub 2}O in N{sub 2}, HCl and HBr is discussed. Chapter 2 discusses the gas handling system and instrumentation required to handle corrosive gases. A method of generating a background spectrum useful to the measurements discussed in this report, as well as in other application areas such as gas phase environmental monitoring, is discussed in Chapter 3. Experimental results obtained with the first system are presented in Chapter 4. Those results made it possible to optimize the design options for the construction of a dedicate system for low ppb water vapor determination. These designs options are discussed in Chapter 5. An FTIR prototype accessory was built. In addition, a commercially available evacuable FTIR system was obtained for evaluation. Test results obtained with both systems are discussed in Chapter 6. Experiments dealing with the interaction between H{sub 2}O-HCl and potential improvements to the detection system are discussed in Chapter 7.

  10. The Spectral Backbone of Excitation Transport in Ultra-Cold Rydberg Gases

    E-Print Network [OSTI]

    Torsten Scholak; Thomas Wellens; Andreas Buchleitner

    2014-11-26T23:59:59.000Z

    The spectral structure underlying excitonic energy transfer in ultra-cold Rydberg gases is studied numerically, in the framework of random matrix theory, and via self-consistent diagrammatic techniques. Rydberg gases are made up of randomly distributed, highly polarizable atoms that interact via strong dipolar forces. Dynamics in such a system is fundamentally different from cases in which the interactions are of short range, and is ultimately determined by the spectral and eigenvector structure. In the energy levels' spacing statistics, we find evidence for a critical energy that separates delocalized eigenstates from states that are localized at pairs or clusters of atoms separated by less than the typical nearest-neighbor distance. We argue that the dipole blockade effect in Rydberg gases can be leveraged to manipulate this transition across a wide range: As the blockade radius increases, the relative weight of localized states is reduced. At the same time, the spectral statistics -- in particular, the density of states and the nearest neighbor level spacing statistics -- exhibits a transition from approximately a 1-stable L\\'evy to a Gaussian orthogonal ensemble. Deviations from random matrix statistics are shown to stem from correlations between interatomic interaction strengths that lead to an asymmetry of the spectral density and profoundly affect localization properties. We discuss approximations to the self-consistent Matsubara-Toyozawa locator expansion that incorporate these effects.

  11. Emissions of greenhouse gases in the United States, 1987--1994

    SciTech Connect (OSTI)

    NONE

    1995-09-25T23:59:59.000Z

    The Energy Information Administration (EIA) is required by the Energy Policy Act of 1992 to prepare a report on aggregate US national emissions of greenhouse gases for the period 1987--1992, with annual updates thereafter. This is the third annual update report,covering national emissions over the period 1987--1993, with preliminary estimates of US carbon dioxide and halocarbon emissions for 1994. Calculating national aggregate emissions(or ``national inventories``) of greenhouse gases is a recently developed form of intellectual endeavor. Greenhouse gas emissions are rarely measured directly or reported to statistical agencies. Thus, to prepare emissions inventories usually requires inferring emissions indirectly from information collected for other purposes. Both the available information and the inferences drawn may be of varying reliability. Chapter 1 of this report briefly recapitulates some background information about global climate change and the greenhouse effect and discusses important recent developments in global climate change activities. Chapters 2 through 6 cover emissions of carbon dioxide, methane, nitrous oxide, halocarbons, and criteria pollutants, respectively. Chapter 7 describes potential sequestration and emissions of greenhouse gases as a result of land use changes.

  12. High-Pressure Phase Equilibria of Ionic Liquids and Compressed Gases for Applications in Reactions and Absorption Refrigeration

    E-Print Network [OSTI]

    Ren, Wei

    2009-12-29T23:59:59.000Z

    for reactions and separations. However, without understanding the phase equilibrium, the kinetics results cannot be properly interpreted. This work also demonstrates that the absorption refrigeration system using ionic liquids and compressed gases in vehicles...

  13. ENVIRON SCIENCE AND TECHNOLOGY IN ROMANIA--ESTROM PROJECT Sources and emission of greenhouse gases in Danube

    E-Print Network [OSTI]

    Wehrli, Bernhard

    gases in Danube Delta lakes Alina Pavel & Edith Durisch-Kaiser & Sorin Balan & Silviu Radan & Sebastian. Radan GeoEcoMar, National Institute for Marine Geology and Geoecology, 024053 Bucharest, Romania E

  14. Coal-Fired Power Plants, Greenhouse Gases, and State Statutory Substantial Endangerment Provisions: Climate Change Comes to Kansas

    E-Print Network [OSTI]

    Glicksman, Robert L.

    2008-04-01T23:59:59.000Z

    economy standards on motor vehicles by states such as California. But the states have also targeted stationary sources of greenhouse gases. In particular, they have sought to minimize carbon dioxide emissions from coal-fired power plants. States have used...

  15. An analytical inversion method for determining regional and global emissions of greenhouse gases: Sensitivity studies and application to halocarbons

    E-Print Network [OSTI]

    Stohl, A.

    A new analytical inversion method has been developed to determine the regional and global emissions of long-lived atmospheric trace gases. It exploits in situ measurement data from three global networks and builds on ...

  16. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    1999-09-22T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (1) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (2) providing proof that such process is continuous and environmentally closed to prevent emissions; (3) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; (4) conducting a blast furnace test to demonstrate the compatibility of the coke produced; and (5) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter were focused on the following: Detailed workings of the team; Proposal to FETC for Phase II; Permitting and Environmental Work; and Engineering Progress.

  17. CALDERON COKEMAKING PROCESS/DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Albert Calderon

    1999-06-23T23:59:59.000Z

    This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (1) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (2) providing proof that such process is continuous and environmentally closed to prevent emissions; (3) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by-product coke ovens can be used in the Calderon process; (4) conducting a blast furnace test to demonstrate the compatibility of the coke produced; and (5) demonstrating that coke can be produced economically, at a level competitive with coke imports. The activities of the past quarter were focused on the following: Detailed studies of LTV's site for the installation of the commercial Demonstration Unit with site specific layouts; Environmental Work; Firm commitments for funding from the private sector; and Federal funding to complement the private contribution.

  18. Calderon cokemaking process/demonstration project

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    The Clean Air Act Amendments of 1990 set new emission standards for hazardous air pollutants from coke ovens. Congress, recognizing that the coke industry faces technological and financial difficulties in meeting these new, stringent emission standards, required the U.S. Environmental Protection Agency and DOE to conduct a joint six-year research and development program to assist the industry in developing and commercializing new technologies and work practices that would significantly reduce hazardous coke oven emissions. DOE`s purpose for sponsoring the proposed demonstration project is to provide the coke industry with a new option for the economical production of high quality coke that significantly reduces the quantity of pollutants entering the environment.

  19. Greenhouse Gases

    Broader source: Energy.gov [DOE]

    Federal agencies are required to inventory and manage greenhouse gas (GHG) emissions to meet Federal goals and mitigate climate change.

  20. An investigation of the sub-grid variability of trace gases and aerosols for global climate modeling

    SciTech Connect (OSTI)

    Qian, Yun; Gustafson, William I.; Fast, Jerome D.

    2010-07-29T23:59:59.000Z

    One fundamental property and limitation of grid based models is their inability to identify spatial details smaller than the grid cell size. While decades of work have gone into developing sub-grid treatments for clouds and land surface processes in climate models, the quantitative understanding of sub-grid processes and variability for aerosols and their precursors is much poorer. In this study, WRF-Chem is used to simulate the trace gases and aerosols over central Mexico during the 2006 MILAGRO field campaign, with multiple spatial resolutions and emission/terrain scenarios. Our analysis focuses on quantifying the sub-grid variability (SGV) of trace gases and aerosols within a typical global climate model grid cell, i.e. 75x75 km2. Our results suggest that a simulation with 3-km horizontal grid spacing adequately reproduces the overall transport and mixing of trace gases and aerosols downwind of Mexico City, while 75-km horizontal grid spacing is insufficient to represent local emission and terrain-induced flows along the mountain ridge, subsequently affecting the transport and mixing of plumes from nearby sources. Therefore, the coarse model grid cell average may not correctly represent aerosol properties measured over polluted areas. Probability density functions (PDFs) for trace gases and aerosols show that secondary trace gases and aerosols, such as O3, sulfate, ammonium, and nitrate, are more likely to have a relatively uniform probability distribution (i.e. smaller SGV) over a narrow range of concentration values. Mostly inert and long-lived trace gases and aerosols, such as CO and BC, are more likely to have broad and skewed distributions (i.e. larger SGV) over polluted regions. Over remote areas, all trace gases and aerosols are more uniformly distributed compared to polluted areas. Both CO and O3 SGV vertical profiles are nearly constant within the PBL during daytime, indicating that trace gases are very efficiently transported and mixed vertically by turbulence. But, simulated horizontal variability indicates that trace gases and aerosols are not well mixed horizontally in the PBL. During nighttime the SGV for trace gases is maximum at the surface, and quickly decreases with height. Unlike the trace gases, the SGV of BC and secondary aerosols reaches a maximum at the PBL top during the day. The SGV decreases with distance away from the polluted urban area, has a more rapid decrease for long-lived trace gases and aerosols than for secondary ones, and is greater during daytime than nighttime. The SGV of trace gases and aerosols is generally larger than for meteorological quantities. Emissions can account for up to 50% of the SGV over urban areas such as Mexico City during daytime for less-reactive trace gases and aerosols, such as CO and BC. The impact of emission spatial variability on SGV decays with altitude in the PBL and is insignificant in the free troposphere. The emission variability affects SGV more significantly during daytime (rather than nighttime) and over urban (rather than rural or remote) areas. The terrain, through its impact on meteorological fields such as wind and the PBL structure, affects dispersion and transport of trace gases and aerosols and their SGV.

  1. Battery operation experience at SSAB, Luleaa six years after rehabilitation

    SciTech Connect (OSTI)

    Petrini, H.; Sundgren, M. [SSAB Tunnplaat, Luleaa (Sweden); Meyer, G. [Krupp Koppers GmbH, Essen (Germany)

    1995-12-01T23:59:59.000Z

    SSAB operates a coke oven plant in Luleaa, Sweden, consisting of one 7 m battery. Pushing the first coke in 1975, the battery encountered over the years more and more difficulties in keeping coking time and operation level at the design rate. In order to improve the coke supply a major repair of the battery was made. In 1989 the battery was fully rehabilitated by Krupp Koppers. The experience made during the years before and during repair contributed to a new policy for the operation of the plant. The policy has led to considerable improvements. It is clear that it is possible to successfully operate a rehabilitated battery.

  2. Technical basis for storage of Zircaloy-clad spent fuel in inert gases

    SciTech Connect (OSTI)

    Johnson, A.B. Jr.; Gilbert, E.R.

    1983-09-01T23:59:59.000Z

    This report summarizes the technical bases to establish safe conditions for dry storage of Zircaloy-clad fuel. Dry storage of fuel with zirconium alloy cladding has been licensed in Canada, the Federal Republic of Germany, and Switzerland. In addition, dry storage demonstrations, hot cell tests, and modeling have been conducted using Zircaloy-clad fuel. The demonstrations have included irradiated boiling water reactor, pressurized heavy-water reactor, and pressurized water reactor (PWR) fuel assemblies. Irradiated fuel has been emplaced in and retrieved from metal casks, dry wells, silos, and a vault. Dry storage tests and demonstrations have involved {similar_to}5,000 fuel rods, and {similar_to}600 rods have been monitored during dry storage in inert gases with maximum cladding temperatures ranging from 50 to 570{sup 0}C. Although some tests and demonstrations are still in progress, there is currently no evidence that any rods exposed to inert gases have failed (one PWR rod exposed to an air cover gas failed at {similar_to}70{sup 0}C). Based on this favorable experience, it is concluded that there is sufficient information on fuel rod behavior, storage conditions, and potential cladding failure mechanisms to support licensing of dry storage in the United States. This licensing position includes a requirement for inert cover gases and a maximum cladding temperature guideline of 380{sup 0}C for Zircaloy-clad fuel. Using an inert cover gas assures that even if fuel with cladding defects were placed in dry storage, or if defects develop during storage, the defects would not propagate. Tests and demonstrations involving Zircaloy-clad rods and assemblies with maximum cladding temperatures above 400{sup 0}C are in progress. When the results from these tests have been evaluated, the viability of higher temperature limits should be examined. Acceptable conditions for storage in air and dry storage of consolidated fuel are issues yet to be resolved.

  3. Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moskovitz, Yevgeny [Department of Chemistry, Middle Tennessee State University; Yang, Hui [Department of Chemistry, Middle Tennessee State University

    2015-01-01T23:59:59.000Z

    Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distribution functions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the ‘critical volume’ hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.

  4. The Marginal Damage Costs of Different Greenhouse Gases: An Application of FUND

    SciTech Connect (OSTI)

    Waldhoff, Stephanie T.; Anthoff, David; Rose, Steven K.; Tol, Richard

    2014-10-01T23:59:59.000Z

    We use FUND 3.8 to estimate the social cost of four greenhouse gases: carbon dioxide, methane, nitrous oxide, and sulphur hexafluoride emissions. The damage potential for each gas—the ratio of the social cost of the non-carbon dioxide greenhouse gas to the social cost of carbon dioxide—is also estimated. The damage potentials are compared to several metrics, focusing in particular on the global warming potentials, which are frequently used to measure the trade-off between gases in the form of carbon dioxide equivalents. We find that damage potentials could be significantly higher than global warming potentials. This finding implies that previous papers have underestimated the relative importance of reducing non-carbon dioxide greenhouse gas emissions from an economic damage perspective. We show results for a range of sensitivity analyses: carbon dioxide fertilization on agriculture productivity, terrestrial feedbacks, climate sensitivity, discounting, equity weighting, and socioeconomic and emissions scenarios. The sensitivity of the results to carbon dioxide fertilization is a primary focus as it is an important element of climate change that has not been considered in much of the previous literature. We estimate that carbon dioxide fertilization has a large positive impact that reduces the social cost of carbon dioxide with a much smaller effect on the other greenhouse gases. As a result, our estimates of the damage potentials of methane and nitrous oxide are much higher compared to estimates that ignore carbon dioxide fertilization. As a result, our base estimates of the damage potential for methane and nitrous oxide that include carbon dioxide fertilization are twice their respective global warming potentials. Our base estimate of the damage potential of sulphur hexafluoride is similar to the one previous estimate, both almost three times the global warming potential.

  5. Modelling of noble anaesthetic gases and high hydrostatic pressure effects in lipid bilayers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moskovitz, Yevgeny; Yang, Hui

    2015-01-01T23:59:59.000Z

    Our objective was to study molecular processes that might be responsible for inert gas narcosis and high-pressure nervous syndrome. The classical molecular dynamics trajectories (200 ns-long) of dioleoylphosphatidylcholine (DOPC) bilayers simulated by the Berger force field were evaluated for water and the atomic distribution of noble gases around DOPC molecules at a pressure range of 1 - 1000 bar and temperature of 310 Kelvin. Xenon and argon have been tested as model gases for general anesthetics, and neon has been investigated for distortions that are potentially responsible for neurological tremor at hyperbaric conditions. The analysis of stacked radial pair distributionmore »functions of DOPC headgroup atoms revealed the explicit solvation potential of gas molecules, which correlates with their dimensions. The orientational dynamics of water molecules at the biomolecular interface should be considered as an influential factor; while excessive solvation effects appearing in the lumen of membrane-embedded ion channels could be a possible cause of inert gas narcosis. All the noble gases tested exhibit similar patterns of the order parameter for both DOPC acyl chains, which is opposite to the patterns found for the order parameter curve at high hydrostatic pressures in intact bilayers. This finding supports the ‘critical volume’ hypothesis of anesthesia pressure reversal. The irregular lipid headgroup-water boundary observed in DOPC bilayers saturated with neon in the pressure range of 1 - 100 bar could be associated with the possible manifestation of neurological tremor at the atomic scale. The non-immobilizer neon also demonstrated the highest momentum impact on the normal component of the DOPC diffusion coefficient representing monolayers undulations rate, which indicates enhanced diffusivity, rather than atom size, as the key factor.« less

  6. Sequestration of noble gases by H3+ in protoplanetary disks and outer solar system composition

    E-Print Network [OSTI]

    Olivier Mousis; Francoise Pauzat; Yves Ellinger; Cecilia Ceccarelli

    2007-09-23T23:59:59.000Z

    We study the efficiency of the noble gases sequestration by the ion H3+ in the form of XH3+ complexes (with X = argon, krypton or xenon) in gas phase conditions similar to those encountered during the cooling of protoplanetary disks, at the epoch of icy planetesimals formation. We show that XH3+ complexes form very stable structures in the gas phase and that their binding energies are much higher than those involved in the structures of X-H2O hydrates or pure X-X condensates. This implies that, in presence of H3+ ions, argon, krypton or xenon are likely to remain sequestrated in the form of XH3+ complexes embedded in the gas phase rather than forming ices during the cooling of protoplanetary disks. The amount of the deficiency depends on how much H3+ is available and efficient in capturing noble gases. In the dense gas of the mid-plane of solar nebula, H3+ is formed by the ionization of H2 from energetic particles, as those in cosmic rays or those ejected by the young Sun. Even using the largest estimate of the cosmic rays ionization rate, we compute that the H3+ abundance is two and three orders of magnitude lower than the xenon and krypton abundance, respectively. Estimating the ionization induced by the young Sun, on the other hand, is very uncertain but leaves the possibility to have enough H3+ to make krypton and xenon trapping efficent. Finally, additional source of H3+ formation may be provided by the presence of a nearby supernova, as discussed in the literature. Recent solar system observations show a deficiency of Ar, and, even more, of Kr and Xe in Titan and in comets. In this article, we consider the possibility that this deficiency is caused by the afore-mentioned process, namely trapping of those noble gases by H3+ ions in the solar nebula.

  7. Coherent spin mixing dynamics in thermal $^{87}$Rb spin-1 and spin-2 gases

    E-Print Network [OSTI]

    He, Xiaodong; Li, Xiaoke; Wang, Fudong; Xu, Zhifang; Wang, Dajun

    2015-01-01T23:59:59.000Z

    We study the non-equilibrium coherent spin mixing dynamics in ferromagnetic spin-1 and antiferromagnetic spin-2 thermal gases of ultracold $^{87}$Rb atoms. Long lasting spin population oscillations with magnetic field dependent resonances are observed in both cases. Our observations are well reproduced by Boltzmann equations of the Wigner distribution function. Compared to the equation of motion of spinor Bose-Einstein condensates, the only difference here is a factor of two increase in the spin-dependent interaction, which is confirmed directly in the spin-2 case by measuring the relation between the oscillation amplitude and the sample's density.

  8. Effective super Tonks-Girardeau gases as ground states of strongly attractive multicomponent fermions

    SciTech Connect (OSTI)

    Yin Xiangguo; Chen Shu [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Guan Xiwen [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Batchelor, M. T. [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Mathematical Sciences Institute, Australian National University, Canberra ACT 0200 (Australia)

    2011-01-15T23:59:59.000Z

    In the strong interaction limit, attractive fermions with N-component hyperfine states in a one-dimensional waveguide form unbreakable bound cluster states. We demonstrate that the ground state of strongly attractive SU(N) Fermi gases can be effectively described by a super Tonks-Girardeau gaslike state composed of bosonic cluster states with strongly attractive cluster-cluster interaction for even N and a Fermi duality of a super Tonks-Girardeau gaslike state composed of fermionic cluster states with weakly interacting cluster-cluster p-wave interaction for odd N.

  9. Overview of the Flammability of Gases Generated in Hanford Waste Tanks

    SciTech Connect (OSTI)

    Mahoney, Lenna A.; Huckaby, James L.; Bryan, Samuel A.; Johnson, Gerald D.

    2000-07-19T23:59:59.000Z

    This report presents an overview of what is known about the flammability of the gases generated and retained in Hanford waste tanks in terms of the gas composition, flammability and detonability limits of the gas constituents, and availability of ignition sources. The intrinsic flammability (or non-flammability) of waste gas mixtures is one major determinant of whether a flammable region develops in the tank headspace; other factors are the rate, surface area, and volume of the release and the tank ventilation rate, which are not covered in this report.

  10. Monte Carlo simulation of the nuclear medium: Fermi gases, nuclei and the role of Pauli potentials

    E-Print Network [OSTI]

    M. A. Perez-Garcia

    2007-08-26T23:59:59.000Z

    The role of Pauli potentials in the semiclassical simulation of Fermi gases at low temperatures is investigated. An alternative Pauli potential to the usual bivariate Gaussian form by Dorso et al. is proposed. This new Pauli potential allows for a simultaneous good reproduction of not only the kinetic energy per particle but also the momentum distribution and the two-body correlation function. The reproduction of the binding energies in finite nuclei in the low and medium mass range is also analyzed. What is found is that given a reasonable short-range atractive nuclear interaction one can include correlation effects in a suitable chosen density dependent Pauli potential.

  11. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S. (North Canton, OH); Downs, William (Alliance, OH); Bailey, Ralph T. (Uniontown, OH); Vecci, Stanley J. (Alliance, OH)

    2003-01-01T23:59:59.000Z

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  12. Separation of rare gases and chiral molecules by selective binding in porous organic cages

    SciTech Connect (OSTI)

    Chen, Linjiang; Reiss, Paul S.; Chong, Samantha Y.; Holden, Daniel; Jelfs, Kim E.; Hasell, Tom; Little, Marc A.; Kewley, Adam; Briggs, Michael E.; Stephenson, Andrew; Thomas, K. M.; Armstrong, Jayne A.; Bell, Jon; Busto, Jose; Noel, Raymond; Liu, Jian; Strachan, Denis M.; Thallapally, Praveen K.; Cooper, Andrew I.

    2014-10-31T23:59:59.000Z

    Abstract: The rare gases krypton, xenon, and radon pose both an economic opportunity and a potential environmental hazard. Xenon is used in commercial lighting, medical imaging, and anesthesia, and can sell for $5,000 per kilogram. Radon, by contrast, Is naturally radioactive and the second largest cause of lung cancer, and radioactive xenon, 133Xe, was a major pollutant released In the Fukushima Daiichi Nuclear Power Plant disaster. We describe an organic cage molecule that can capture xenon and radon with unprecedented selectivity, suggesting new technologies for environmental monitoring, removal of pollutants, or the recovery of rare, valuable elements from air.

  13. Enhancement of NMR and MRI in the presence of hyperpolarized noble gases

    DOE Patents [OSTI]

    Pines, Alexander; Budinger, Thomas; Navon, Gil; Song, Yi-Qiao; Appelt, Stephan; Bifone, Angelo; Taylor, Rebecca; Goodson, Boyd; Seydoux, Roberto; Room, Toomas; Pietrass, Tanja

    2004-11-16T23:59:59.000Z

    The present invention relates generally to nuclear magnetic resonance (NMR) techniques for both spectroscopy and imaging. More particularly, the present invention relates to methods in which hyperpolarized noble gases (e.g., Xe and He) are used to enhance and improve NMR and MRI. Additionally, the hyperpolarized gas solutions of the invention are useful both in vitro and in vivo to study the dynamics or structure of a system. When used with biological systems, either in vivo or in vitro, it is within the scope of the invention to target the hyperpolarized gas and deliver it to specific regions within the system.

  14. Direct conversion of light hydrocarbon gases to liquid fuel. Final report No. 33

    SciTech Connect (OSTI)

    Kaplan, R.D.; Foral, M.J.

    1992-05-16T23:59:59.000Z

    Amoco oil Company, has investigated the direct, non-catalytic conversion of light hydrocarbon gases to liquid fuels (particularly methanol) via partial oxidation. The primary hydrocarbon feed used in these studies was natural gas. This report describes work completed in the course of our two-year project. In general we determined that the methanol yields delivered by this system were not high enough to make it economically attractive. Process variables studied included hydrocarbon feed composition, oxygen concentration, temperature and pressure effects, residence time, reactor design, and reactor recycle.

  15. Overview of the Flammability of Gases Generated in Hanford Waste Tanks

    SciTech Connect (OSTI)

    LA Mahoney; JL Huckaby; SA Bryan; GD Johnson

    2000-07-21T23:59:59.000Z

    This report presents an overview of what is known about the flammability of the gases generated and retained in Hanford waste tanks in terms of the gas composition, the flammability and detonability limits of the gas constituents, and the availability of ignition sources. The intrinsic flammability (or nonflammability) of waste gas mixtures is one major determinant of whether a flammable region develops in the tank headspace; other factors are the rate, surface area, volume of the release, and the tank ventilation rate, which are not covered in this report.

  16. Pressurized release of liquefied fuel gases (LNG and LPG). Topical report, May 1993-February 1996

    SciTech Connect (OSTI)

    Atallah, S.; Janardhan, A.

    1996-02-01T23:59:59.000Z

    This report is an important contribution to the behavior of pressurized liquefied gases when accidentally released into the atmosphere. LNG vehicle fueling stations and LPG storage facilities operate at elevated pressures. Accidental releases could result in rainout and the formation of an aerosol in the vapor cloud. These factors must be considered when estimating the extent of the hazard zone of the vapor cloud using a heavier-than-air gas dispersion model such as DEGADIS (or its Windows equivalent DEGATEC). The DOS program PREL has been incorporated in the Windows program LFGRISK.

  17. Changes in atmospheric gases during isobaric storage of beef packaged pre- and post-rigor

    E-Print Network [OSTI]

    Hoermann, Karen Lee

    1980-01-01T23:59:59.000Z

    of C mmittee o-Chairman o Committee !, ' '2s r Mem er Member H d fop t ~t August 1980 ABSTRACT Changes in Atmospheric Gases During Isobaric Storage of Beef Packaged Pre- and Post-Rigor. (August 1980) Karen Lee Hoermann, B. S. , Texas ASM... and support. Thanks are g1ven to Don Bernard, David Hill, Karen Tanksley, and Julie Vrana for the1r assistance 1n the analysis of the samples. For his statist1cal expertise, the author thanks Dr. Iti. C. Parr for h1s help in analysis of variance and covari...

  18. Use of sulfide-containing liquors for removing mercury from flue gases

    DOE Patents [OSTI]

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2006-05-02T23:59:59.000Z

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  19. Co-production of electricity and alternate fuels from coal. Final report, August 1995

    SciTech Connect (OSTI)

    NONE

    1995-12-31T23:59:59.000Z

    The Calderon process and its process development unit, PDU, were originally conceived to produce two useful products from a bituminous coal: a desulfurized medium BTU gas containing primarily CO, H{sub 2}, CH{sub 4}, CO{sub 2}, and H{sub 2}O; and a desulfurized low BTU gas containing these same constituents plus N{sub 2} from the air used to provide heat for the process through the combustion of a portion of the fuel. The process was viewed as a means for providing both a synthesis gas for liquid fuel production (perhaps CH{sub 3}OH, alternatively CH{sub 4} or NH{sub 3}) and a pressurized, low BTU fuel gas, for gas turbine based power generation. The Calderon coal process comprises three principle sections which perform the following functions: coal pyrolysis in a continuous, steady flow unit based on coke oven technology; air blown, slagging, coke gasification in a moving bed unit based on a blast furnace technology; and a novel, lime pebble based, product gas processing in which a variety of functions are accomplished including the cracking of hydrocarbons and the removal of sulfur, H{sub 2}S, and of particulates from both the medium and low BTU gases. The product gas processing unit, based on multiple moving beds, has also been conceived to regenerate the lime pebbles and recover sulfur as elemental S.

  20. Sequestration of noble gases by H3+ in protoplanetary disks and outer solar system composition

    E-Print Network [OSTI]

    Mousis, Olivier; Ellinger, Yves; Ceccarelli, Cecilia

    2007-01-01T23:59:59.000Z

    We study the efficiency of the noble gases sequestration by the ion H3+ in the form of XH3+ complexes (with X = argon, krypton or xenon) in gas phase conditions similar to those encountered during the cooling of protoplanetary disks, at the epoch of icy planetesimals formation. We show that XH3+ complexes form very stable structures in the gas phase and that their binding energies are much higher than those involved in the structures of X-H2O hydrates or pure X-X condensates. This implies that, in presence of H3+ ions, argon, krypton or xenon are likely to remain sequestrated in the form of XH3+ complexes embedded in the gas phase rather than forming ices during the cooling of protoplanetary disks. The amount of the deficiency depends on how much H3+ is available and efficient in capturing noble gases. In the dense gas of the mid-plane of solar nebula, H3+ is formed by the ionization of H2 from energetic particles, as those in cosmic rays or those ejected by the young Sun. Even using the largest estimate of t...

  1. Characterization of particles entrained in the effluent gases of an 18-inch AFBC

    SciTech Connect (OSTI)

    Anderson, R.J.; Childers, E.E.; Chidester, G.E.

    1983-02-01T23:59:59.000Z

    This experimental investigation was directed at measurements of the mass loading and size distribution of the particles entrained in the effluent gases of the Morgantown Energy Technology Center (METC) 18-inch, atmospheric pressure fluidized-bed combustor (AFBC). This information was required to aid in the continuing characterization of the AFBC, and to assess the efficiency or performance of an associated cleanup device. The particle-laden flow from the AFBC was introduced into a prototype granular-bed filter (GBF) designed for hot gas cleanup. In order to assess the efficiency of the GBF for particle removal, the mass loading and size distribution of particles contained in the cleaned gas emerging from the GBF were also determined. The effluent gases exit the AFBC at a nominal 1500/sup 0/F and a heavy particle loading (>1 g/scm). These conditions represent a harsh sampling environment. Filter samples obtained by extractive sampling formed the basis of the experimental information. Gravimetric and Coulter counter analyses were performed on each sample to provide mass loading and particle size data, respectively. Mass loadings of particles, as determined from filter samples collected at the inlet and outlet of the GBF, indicated particle removal efficiencies of about 80%. No significant variation in the particle removal efficiency was observed. Analysis of collected particulate samples showed no significant preferential removal of particles as a function of particle size. 2 figs., 1 tab.

  2. Particulate removal from high-temperature, high-pressure combustion gases

    SciTech Connect (OSTI)

    Henry, R.F.; Saxena, S.C.; Podolski, W.F.

    1983-10-01T23:59:59.000Z

    The adoption by utilities of coal-fired pressurized fluidized-bed/combined cycle combustion systems for electric power generation depends to a large extent on the development of an efficient and economic cleanup system for the high-temperature, high-pressure combustion gases. For adequate turbine protection, these gases must be sufficiently cleaned to bring particulate erosion and alkali vapor corrosion to a level acceptable to gas turbine manufacturers. At the same time, the total particulate content of the flue gas must be reduced to the limit set by the Environmental Protection Agency. To accomplish particulate removal from a dust-laden gas stream, a number of separation devices have been developed. These include conventional and augmented cyclones; porous metal, fiber, fabric, and ceramic filters, as well as fixed, moving, and fluidized-bed granular filters; and electrostatic precipitators. Several other novel separation devices have been proposed and developed to different degrees such as: contactors using molten salt, metal, or glass, dry scrubbers, acoustic agglomerators, as well as cyclones and granular-bed filters with external electrostatic or magnetic fields. Some of these separation devices in various combinations have been tested in process development units or in hot gas simulators by ANL, CPC, CURL, C-W, Exxon, GE, Westinghouse, etc. The results are discussed and evaluated for PFBC applications.

  3. JV Task 125-Mercury Measurement in Combustion Flue Gases Short Course

    SciTech Connect (OSTI)

    Dennis Laudal

    2008-09-30T23:59:59.000Z

    The short course, designed to train personnel who have an interest in measuring mercury in combustion flue gases, was held twice at the Drury Inn in Marion, Illinois. The short course helped to provide attendees with the knowledge necessary to avoid the many pitfalls that can and do occur when measuring mercury in combustion flue gases. The first short course, May 5-8, 2008, included both a classroom-type session and hands-on demonstration of mercury-sampling equipment. The hands-on demonstration of equipment was staged at Southern Illinois Power Cooperative. Not including the Illinois Clean Coal Institute and the U.S. Department of Energy project managers, there were 12 attendees. The second short course was conducted September 16-17, 2008, but only included the classroom portion of the course; 14 people attended. In both cases, lectures were provided on the various mercury measurement methods, and interaction between attendees and EERC research personnel to discuss specific mercury measurement problems was promoted. Overall, the response to the course was excellent.

  4. Simulations of greenhouse trace gases using the Los Alamos chemical tracer model

    SciTech Connect (OSTI)

    Kao, C.Y.J.; Morz, E. (Los Alamos National Lab., NM (United States)); Tie, X. (Scripps Institution of Oceanography, San Diego, CA (United States))

    1991-11-01T23:59:59.000Z

    Through three-dimensional global model studies on atmospheric composition and transport, we are improving our quantitative understanding of the origins and behavior of trace gases that affect Earth's radiative energy balance and climate. We will focus, in this paper, on the simulations of three individual trace gases including CFC-11, methyl chloroform, and methane. We first used our chemical tracer model to study the global distribution and trend of chemically inert CFC-11 observed by the Atmospheric Lifetime Experiment. The results show that the model has the ability to reproduce the time-series of the observations. The purpose of this CFC-11 simulation was to test the transport of the model. We then used to model introduce methyl chloroform into the atmosphere according to the known emission patterns and iteratively varied OH fields so that the observed concentrations of methyl chloroform from the observations could be simulated well. The rationale behind this approach is that the reaction with OH is the dominant sink for metyl chloroform and the transport of the model has been tested in the previous CFC-11 study. Finally, using the inferred OH distributions, we conducted a steady-state simulation to reproduce the current methane distribution. The general agreement between the modeled an observed methane surface concentrations has laid a foundation for the simulation of the transient increase of methane.

  5. Simulations of greenhouse trace gases using the Los Alamos chemical tracer model

    SciTech Connect (OSTI)

    Kao, C.Y.J.; Morz, E. [Los Alamos National Lab., NM (United States); Tie, X. [Scripps Institution of Oceanography, San Diego, CA (United States)

    1991-11-01T23:59:59.000Z

    Through three-dimensional global model studies on atmospheric composition and transport, we are improving our quantitative understanding of the origins and behavior of trace gases that affect Earth`s radiative energy balance and climate. We will focus, in this paper, on the simulations of three individual trace gases including CFC-11, methyl chloroform, and methane. We first used our chemical tracer model to study the global distribution and trend of chemically inert CFC-11 observed by the Atmospheric Lifetime Experiment. The results show that the model has the ability to reproduce the time-series of the observations. The purpose of this CFC-11 simulation was to test the transport of the model. We then used to model introduce methyl chloroform into the atmosphere according to the known emission patterns and iteratively varied OH fields so that the observed concentrations of methyl chloroform from the observations could be simulated well. The rationale behind this approach is that the reaction with OH is the dominant sink for metyl chloroform and the transport of the model has been tested in the previous CFC-11 study. Finally, using the inferred OH distributions, we conducted a steady-state simulation to reproduce the current methane distribution. The general agreement between the modeled an observed methane surface concentrations has laid a foundation for the simulation of the transient increase of methane.

  6. Molecular formations in ultracold mixtures of interacting and noninteracting atomic gases

    E-Print Network [OSTI]

    T. Nishimura; A. Matsumoto; H. Yabu

    2008-08-06T23:59:59.000Z

    Atom-molecule equilibrium for molecular formation processes is discussed for boson-fermion, fermion-fermion, and boson-boson mixtures of ultracold atomic gases in the framework of quasichemical equilibrium theory. After presentation of the general formulation, zero-temperature phase diagrams of the atom-molecule equilibrium states are calculated analytically; molecular, mixed, and dissociated phases are shown to appear for the change of the binding energy of the molecules. The temperature dependences of the atom or molecule densities are calculated numerically, and finite-temperature phase structures are obtained of the atom-molecule equilibrium in the mixtures. The transition temperatures of the atom or molecule Bose-Einstein condensations are also evaluated from these results. Quantum-statistical deviations of the law of mass action in atom-molecule equilibrium, which should be satisfied in mixtures of classical Maxwell-Boltzmann gases, are calculated, and the difference in the different types of quantum-statistical effects is clarified. Mean-field calculations with interparticle interactions (atom-atom, atom-molecule, and molecule-molecule) are formulated, where interaction effects are found to give the linear density-dependent term in the effective molecular binding energies. This method is applied to calculations of zero-temperature phase diagrams, where new phases with coexisting local-equilibrium states are shown to appear in the case of strongly repulsive interactions.

  7. Quantum criticality and universal scaling of strongly attractive spin-imbalanced Fermi gases in a one-dimensional harmonic trap

    SciTech Connect (OSTI)

    Yin Xiangguo; Chen Shu [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Guan Xiwen [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Batchelor, Murray T. [Department of Theoretical Physics, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Mathematical Sciences Institute, Australian National University, Canberra ACT 0200 (Australia)

    2011-07-15T23:59:59.000Z

    We investigate quantum criticality and universal scaling of strongly attractive Fermi gases confined in a one-dimensional harmonic trap. We demonstrate from the power-law scaling of the thermodynamic properties that current experiments on this system are capable of measuring universal features at quantum criticality, such as universal scaling and Tomonaga-Luttinger liquid physics. The results also provide insights on recent measurements of key features of the phase diagram of a spin-imbalanced atomic Fermi gas [Y. Liao et al., Nature (London) 467, 567 (2010)] and point to further study of quantum critical phenomena in ultracold atomic Fermi gases.

  8. Production of stable, non-thermal atmospheric pressure rf capacitive plasmas using gases other than helium or neon

    DOE Patents [OSTI]

    Park, Jaeyoung; Henins, Ivars

    2005-06-21T23:59:59.000Z

    The present invention enables the production of stable, steady state, non-thermal atmospheric pressure rf capacitive .alpha.-mode plasmas using gases other than helium and neon. In particular, the current invention generates and maintains stable, steady-state, non-thermal atmospheric pressure rf .alpha.-mode plasmas using pure argon or argon with reactive gas mixtures, pure oxygen or air. By replacing rare and expensive helium with more readily available gases, this invention makes it more economical to use atmospheric pressure rf .alpha.-mode plasmas for various materials processing applications.

  9. Emissions of greenhouse gases from the use of transportation fuels and electricity. Volume 2: Appendixes A--S

    SciTech Connect (OSTI)

    DeLuchi, M.A. [Argonne National Lab., IL (United States); [Univ. of California, Davis, CA (United States). Inst. of Transportation Studies

    1993-11-01T23:59:59.000Z

    This volume contains the appendices to the report on Emission of Greenhouse Gases from the Use of Transportation Fuels and Electricity. Emissions of methane, nitrous oxide, carbon monoxide, and other greenhouse gases are discussed. Sources of emission including vehicles, natural gas operations, oil production, coal mines, and power plants are covered. The various energy industries are examined in terms of greenhouse gas production and emissions. Those industries include electricity generation, transport of goods via trains, trucks, ships and pipelines, coal, natural gas and natural gas liquids, petroleum, nuclear energy, and biofuels.

  10. Radiolytic and radiolytically induced generation of gases from synthetic wastes. Final report

    SciTech Connect (OSTI)

    Meisel, D.; Jonah, C.D.; Kapoor, S.; Matheson, M.S.; Sauer, M.C. Jr.

    1993-10-01T23:59:59.000Z

    To better understand the processes leading to the generation and release of gases from waste tanks, the authors studied the radiolytic and thermal generation of H{sub 2}, N{sub 2}O, N{sub 2}, O{sub 2}, and NH{sub 3} in nonradioactive waste simulant solutions and slurries. The radiolytic sources for H{sub 2} are e{sub aq}{sup {minus}} and its predecessors and H atoms. Radiolysis of the water generates some H{sub 2} and an additional amount comes from the hydrogen abstraction reaction H + RH{yields}H{sub 2}+R{center_dot}. Nitrate scavenges e{sub aq}{sup {minus}} and its predecessors whereas nitrite is the major H-atom scavenger. Computer modeling shows that if [NO{sub 3}{sup {minus}}] is above 0.5 M, and [NO{sub 2}{sup {minus}}] is above 2M, the addition of other scavengers will have little effect on the yield of H{sub 2}. In the presence of organic molecules O{sub 2} is efficiently destroyed. Small yields of ammonia were measured and the yields increase linearly with dose. The nitrogen in NH{sub 3} comes from organic chelators. The yields of gases in solution depend only weakly on temperature. The rate of thermal generation of gases increases upon preirradiation, reaches a maximum, and then declines. The known radiolytic degradation products of chelators, NTA, IDA, glycolate, glyoxylate, formaldehyde, formate, oxalate, and hydroxylainine were examined for their roles in the thermal generation of H{sub 2} and N{sub 2}O at 60{degrees}C. In solution or slurry only radiolytically produced Pd intermediate strongly retains H{sub 2}. Radiolytic yields of N{sub 2}O are strongly reduced by Cr(III). In irradiated slurry, loose and tight gas were found. The loose gas could be removed by bubbling from the slurry, but the tight gas could be released only by dissolution of the slurry.

  11. Supercomputers Take a Cue From Microwave Ovens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    many different licenses for different applications," says Shalf. "Just as the consumer electronics chip designers choose a set of processor characteristics appropriate to the...

  12. Solar Pizza Oven Box k - 6

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33Frequently AskedEnergyIssues DOE's Nuclear EnergySmart Metersof Energy LEDMarketReady to

  13. Supercomputers Take a Cue From Microwave Ovens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over Our InstagramStructure of All-Polymer. .Energy8 CareerSupercomputerSupercomputers

  14. Making a Solar Oven | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment ofLetterEconomyDr.Energy Maine

  15. Process for coal liquefaction by separation of entrained gases from slurry exiting staged dissolvers

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA); Ying, David H. S. (Macungie, PA)

    1983-01-01T23:59:59.000Z

    There is described an improved liquefaction process by which coal is converted to a low ash and low sulfur carbonaceous material that can be used as a fuel in an environmentally acceptable manner without costly gas scrubbing equipment. In the process, coal is slurried with a solvent, passed through a preheater and at least two dissolvers in series in the presence of hydrogen-rich gases at elevated temperatures and pressures. Solids, including mineral ash and unconverted coal macerals are separated from the condensed dissolver effluent. In accordance with the improved process, fresh hydrogen is fed to each dissolver and the entrained gas from each dissolver is separated from the slurry phase and removed from the reactor system before the condensed phase is passed to the next dissolver in the series. In accordance with another process, the feeds to the dissolvers are such that the top of each downstream dissolver is used as a gas-liquid separator.

  16. New equation calculates thermal conductivities of C[sub 1]-C[sub 4] gases

    SciTech Connect (OSTI)

    Yaws, C.L.; Lin, X.; Bu, L.; Nijhawan, S. (Lamar Univ., Beaumont, TX (United States))

    1994-04-18T23:59:59.000Z

    In the design of heat exchangers, heat-transfer coefficients are commonly calculated for individual items. These calculations require knowledge of the thermal conductivities of the species involved. The calculation require knowledge of the thermal conductivities of the species involved. The calculation of the overall heat-transfer coefficient for a heat exchanger also requires thermal conductivity data for the individual species. In fact, thermal conductivity is the fundamental property involved in heat transfer. Ordinarily, thermal conductivities are either measured experimentally or estimated using complex correlations and models. Engineers must search existing literature for the values needed. Here, a compilation of thermal conductivity data for gases is presented for a wide temperature range. Using these data with the accompanying equation will enable engineers to quickly determine values at the desired temperatures. The results are provided in an easy-to-use tabular format, which is especially helpful for rapid calculations using a personal computer or hand-held calculator.

  17. Uniform electron gases. II. The generalized local density approximation in one dimension

    SciTech Connect (OSTI)

    Loos, Pierre-François, E-mail: pf.loos@anu.edu.au; Ball, Caleb J.; Gill, Peter M. W., E-mail: peter.gill@anu.edu.au [Research School of Chemistry, Australian National University, Canberra ACT 0200 (Australia)] [Research School of Chemistry, Australian National University, Canberra ACT 0200 (Australia)

    2014-05-14T23:59:59.000Z

    We introduce a generalization (gLDA) of the traditional Local Density Approximation (LDA) within density functional theory. The gLDA uses both the one-electron Seitz radius r{sub s} and a two-electron hole curvature parameter ? at each point in space. The gLDA reduces to the LDA when applied to the infinite homogeneous electron gas but, unlike the LDA, it is also exact for finite uniform electron gases on spheres. We present an explicit gLDA functional for the correlation energy of electrons that are confined to a one-dimensional space and compare its accuracy with LDA, second- and third-order Mřller-Plesset perturbation energies, and exact calculations for a variety of inhomogeneous systems.

  18. Clathrate hydrates as a sink of noble gases in Titan's atmosphere

    E-Print Network [OSTI]

    Thomas, C; Ballenegger, V; Picaud, Sylvain

    2007-01-01T23:59:59.000Z

    We use a statistical thermodynamic approach to determine the composition of clathrate hydrates which may form from a multiple compound gas whose composition is similar to that of Titan's atmosphere. Assuming that noble gases are initially present in this gas phase, we calculate the ratios of xenon, krypton and argon to species trapped in clathrate hydrates. We find that these ratios calculated for xenon and krypton are several orders of magnitude higher than in the coexisting gas at temperature and pressure conditions close to those of Titan's present atmosphere at ground level. Furthermore we show that, by contrast, argon is poorly trapped in these ices. This trapping mechanism implies that the gas-phase is progressively depleted in xenon and krypton when the coexisting clathrate hydrates form whereas the initial abundance of argon remains almost constant. Our results are thus compatible with the deficiency of Titan's atmosphere in xenon and krypton measured by the {\\it Huygens} probe during its descent on J...

  19. Electrochemical separation and concentration of sulfur containing gases from gas mixtures

    DOE Patents [OSTI]

    Winnick, Jack (3805 Woodrail-on-the-Green, Columbia, MO 65201)

    1981-01-01T23:59:59.000Z

    A method of removing sulfur oxides of H.sub.2 S from high temperature gas mixtures (150.degree.-1000.degree. C.) is the subject of the present invention. An electrochemical cell is employed. The cell is provided with inert electrodes and an electrolyte which will provide anions compatible with the sulfur containing anions formed at the anode. The electrolyte is also selected to provide inert stable cations at the temperatures encountered. The gas mixture is passed by the cathode where the sulfur gases are converted to SO.sub.4.sup.= or, in the case of H.sub.2 S, to S.sup.=. The anions migrate to the anode where they are converted to a stable gaseous form at much greater concentration levels (>10X). Current flow may be effected by utilizing an external source of electrical energy or by passing a reducing gas such as hydrogen past the anode.

  20. Recent Progress in the Research on Ion and Electron Transport in Gases at Swarm Energies

    SciTech Connect (OSTI)

    Urquijo, Jaime de [Centro de Ciencias Fisicas, Universidad Nacional Autonoma de Mexico, P.O. Box 48-3, 62251, Cuernavaca, Mor. (Mexico)

    2004-12-01T23:59:59.000Z

    This paper deals with the presentation and discussion of recent research on the transport of electrons and ions in gases at low energies. Particular emphasis is placed on electron swarm experiments related with the negative differential conductivity of electrons in some gas mixtures, and with secondary ionisation processes due to the impact of metastables with neutrals (Penning ionisation). Ion transport is firstly addressed through some recent measurements on atomic and molecular systems for which both theory and experiment have reached a high degree of agreement, and also on those in which the ranges of the density-normalized electric field intensity E/N have been increased substantiality. Also, the recent advances on the application of transport theories dealing with inelastic collisions are presented, as well as some recent measurements of negative ions and charged clusters in gaseous mixtures, leading to the successful test of Blanc's law at low fields, to the experimental mobilities.