National Library of Energy BETA

Sample records for gaseous straight-chain hydrocar

  1. Polyethylene composites containing a phase change material having a C14 straight chain hydrocarbon

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1987-01-01

    A composite useful in thermal energy storage, said composite being formed of a polyethylene matrix having a straight chain alkyl hydrocarbon incorporated therein, said polyethylene being crosslinked to such a degree that said polyethylene matrix is form stable and said polyethylene matrix is capable of absorbing at least 10% by weight of said straight chain alkyl hydrocarbon; the composite is useful in forming pellets or sheets having thermal energy storage characteristics.

  2. Gaseous Hydrogen Delivery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gaseous Hydrogen Delivery Gaseous Hydrogen Delivery Gaseous hydrogen is most commonly delivered either by trucks or through pipelines. Because gaseous hydrogen is typically...

  3. NGPL Production, Gaseous Equivalent

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYear Jan Feb MarNGPL Production, Gaseous

  4. NGPL Production, Gaseous Equivalent

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYear Jan Feb MarNGPL Production, Gaseous

  5. Fuel Cells and Renewable Gaseous Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cell Technologies Office | 1 7142015 Fuel Cells and Renewable Gaseous Fuels Bioenergy 2015: Renewable Gaseous Fuels Breakout Session Sarah Studer, PhD ORISE Fellow Fuel Cell...

  6. School science project 'demystifies' Portsmouth Gaseous Diffusion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    School science project 'demystifies' Portsmouth Gaseous Diffusion Plant Site School science project 'demystifies' Portsmouth Gaseous Diffusion Plant Site June 2, 2015 - 10:40am...

  7. Independent Oversight Review, Portsmouth Gaseous Diffusion Plant...

    Office of Environmental Management (EM)

    January 2013 Independent Oversight Review, Portsmouth Gaseous Diffusion Plant - January 2013 January 2013 Review of the Portsmouth Gaseous Diffusion Plant Work Planning and Control...

  8. Independent Activity Report, Portsmouth Gaseous Diffusion Plant...

    Office of Environmental Management (EM)

    Portsmouth Gaseous Diffusion Plant - August 2011 Independent Activity Report, Portsmouth Gaseous Diffusion Plant - August 2011 August 2011 Orientation Visit to the Portsmouth...

  9. Gaseous-fuel engine technology

    SciTech Connect (OSTI)

    1995-12-31

    This publication contains three distinct groups of papers covering gaseous-fuel injection and control, gaseous-fuel engine projects, and gaseous-fuel engine/vehicle applications. Contents include: ultra rapid natural gas port injection; a CNG specific fuel injector using latching solenoid technology; development of an electronically-controlled natural gas-fueled John Deere PowerTech 8.1L engine; adapting a Geo Metro to run on natural gas using fuel-injection technology; behavior of a closed loop controlled air valve type mixer on a natural gas fueled engine under transient operation; and a turbocharged lean-burn 4.3 liter natural gas engine.

  10. The Promise of Renewable Gaseous Fuels

    Broader source: Energy.gov [DOE]

    Breakout Session 3-C: Renewable Gaseous FuelsThe Promise of Renewable Gaseous FuelsJeffrey Reed, Director of Business Strategy and Development, Southern California Gas Company/San Diego Gas &...

  11. Hydrogen and Gaseous Fuel Safety and Toxicity

    SciTech Connect (OSTI)

    Lee C. Cadwallader; J. Sephen Herring

    2007-06-01

    Non-traditional motor fuels are receiving increased attention and use. This paper examines the safety of three alternative gaseous fuels plus gasoline and the advantages and disadvantages of each. The gaseous fuels are hydrogen, methane (natural gas), and propane. Qualitatively, the overall risks of the four fuels should be close. Gasoline is the most toxic. For small leaks, hydrogen has the highest ignition probability and the gaseous fuels have the highest risk of a burning jet or cloud.

  12. Portsmouth Gaseous Diffusion Plant Director's Final Findings...

    Office of Environmental Management (EM)

    Portsmouth Gaseous Diffusion Plant Director's Final Findings and Orders, October 4, 1995 State Ohio Agreement Type Federal Facility Agreement Legal Driver(s) FFCAct Scope Summary...

  13. Independent Oversight Review, Portsmouth Gaseous Diffusion Plant...

    Office of Environmental Management (EM)

    April 2013 Independent Oversight Review, Portsmouth Gaseous Diffusion Plant - April 2013 April 2013 Review of the Integrated Safety Management System Phase I Verification Review at...

  14. Process for exchanging hydrogen isotopes between gaseous hydrogen and water

    DOE Patents [OSTI]

    Hindin, Saul G. (Mendham, NJ); Roberts, George W. (Westfield, NJ)

    1980-08-12

    A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

  15. Portsmouth Gaseous Diffusion Plant - Quadrant I Groundwater Investigat...

    Office of Environmental Management (EM)

    Portsmouth Gaseous Diffusion Plant - Quadrant I Groundwater Investigative (5-Unit) Area Plume Portsmouth Gaseous Diffusion Plant - Quadrant I Groundwater Investigative (5-Unit)...

  16. DOE Issues Final Request for Proposal for Portsmouth Gaseous...

    Office of Environmental Management (EM)

    Portsmouth Gaseous Diffusion Plant Support Services DOE Issues Final Request for Proposal for Portsmouth Gaseous Diffusion Plant Support Services December 9, 2014 - 3:37pm Addthis...

  17. DOE Seeks Small Businesses for Paducah Gaseous Diffusion Plant...

    Office of Environmental Management (EM)

    Paducah Gaseous Diffusion Plant Infrastructure Support Services DOE Seeks Small Businesses for Paducah Gaseous Diffusion Plant Infrastructure Support Services June 10, 2014 -...

  18. DOE Issues Final Request for Proposal for Paducah Gaseous Diffusion...

    Energy Savers [EERE]

    Paducah Gaseous Diffusion Plant Support Services DOE Issues Final Request for Proposal for Paducah Gaseous Diffusion Plant Support Services October 6, 2014 - 4:13pm Addthis Media...

  19. DOE Issues Final Request for Proposal for Portsmouth Gaseous...

    Energy Savers [EERE]

    DOE Issues Final Request for Proposal for Portsmouth Gaseous Diffusion Plant Support Services DOE Issues Final Request for Proposal for Portsmouth Gaseous Diffusion Plant Support...

  20. DOE Awards Contract for Paducah Gaseous Diffusion Plant Infrastructure...

    Office of Environmental Management (EM)

    Paducah Gaseous Diffusion Plant Infrastructure Support Services DOE Awards Contract for Paducah Gaseous Diffusion Plant Infrastructure Support Services June 17, 2015 - 5:45pm...

  1. Combination free electron and gaseous laser

    DOE Patents [OSTI]

    Brau, Charles A. (Los Alamos, NM); Rockwood, Stephen D. (Los Alamos, NM); Stein, William E. (Los Alamos, NM)

    1980-01-01

    A multiple laser having one or more gaseous laser stages and one or more free electron stages. Each of the free electron laser stages is sequentially pumped by a microwave linear accelerator. Subsequently, the electron beam is directed through a gaseous laser, in the preferred embodiment, and in an alternative embodiment, through a microwave accelerator to lower the energy level of the electron beam to pump one or more gaseous lasers. The combination laser provides high pulse repetition frequencies, on the order of 1 kHz or greater, high power capability, high efficiency, and tunability in the synchronous production of multiple beams of coherent optical radiation.

  2. Process for removing metal carbonyls from gaseous streams

    SciTech Connect (OSTI)

    Heyd, R.L.; Pignet, T.P.

    1988-04-26

    A process for removing metal carbonyl contaminates from a gaseous stream is described containing such contaminates and which is free from sulfur contaminates, which process comprises contacting the gaseous stream with a zinc sulfide absorbent to thereby remove metal carbonyl contaminates from the gaseous stream, and separating the gaseous stream from the zinc sulfide absorbent.

  3. Methods and systems for deacidizing gaseous mixtures

    DOE Patents [OSTI]

    Hu, Liang

    2010-05-18

    An improved process for deacidizing a gaseous mixture using phase enhanced gas-liquid absorption is described. The process utilizes a multiphasic absorbent that absorbs an acid gas at increased rate and leads to reduced overall energy costs for the deacidizing operation.

  4. Gaseous Hydrogen Delivery Breakout- Strategic Directions for Hydrogen Delivery Workshop

    Broader source: Energy.gov [DOE]

    Targets, barriers and research and development priorities for gaseous delivery of hydrogen through hydrogen and natural gas pipelines.

  5. Gaseous modification of MCrAlY coatings

    DOE Patents [OSTI]

    Vance, Steven J. (Orlando, FL); Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL)

    2000-01-01

    The present invention generally describes methods for modifying MCrAlY coatings by using gaseous carburization, gaseous nitriding or gaseous carbonitriding. The modified MCrAlY coatings are useful in thermal barrier coating systems, which may be used in gas turbine engines.

  6. Band Formation during Gaseous Diffusion in Aerogels

    E-Print Network [OSTI]

    M. A. Einarsrud; F. A. Maao; A. Hansen; M. Kirkedelen; J. Samseth

    1997-06-18

    We study experimentally how gaseous HCl and NH_3 diffuse from opposite sides of and react in silica aerogel rods with porosity of 92 % and average pore size of about 50 nm. The reaction leads to solid NH_4Cl, which is deposited in thin sheet-like structures. We present a numerical study of the phenomenon. Due to the difference in boundary conditions between this system and those usually studied, we find the sheet-like structures in the aerogel to differ significantly from older studies. The influence of random nucleation centers and inhomogeneities in the aerogel is studied numerically.

  7. NGPL Production, Gaseous Equivalent at Processing Plants

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYear Jan Feb MarNGPL Production, GaseousNGPL

  8. Sandia Energy - Particulate and Gaseous Emissions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II)Geothermal Energy &WaterNew CREWOnlineParticulate and Gaseous

  9. untitled

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    barrels or more andor receives petroleum products by tanker, barge, or pipeline. Butane (C 4 H 10 ). A normally gaseous straight-chain or branch-chain hydrocarbon extracted...

  10. Non-Destructive Analysis Calibration Standards for Gaseous Diffusion...

    Energy Savers [EERE]

    surrogates are required to verify and validate NDA methods used to support characterization of gaseous diffusion equipment within the D&D project. Because working reference...

  11. Gaseous Emissions From Steamboat Springs, Brady'S Hot Springs...

    Open Energy Info (EERE)

    systems, characterize their lateral extent, or map the trends of concealed geologic structures that may provide important reservoir permeability at depth. Gaseous geochemical...

  12. EM Begins Demolishing K-31 Gaseous Diffusion Building | Department...

    Office of Environmental Management (EM)

    East Tennessee Technology Park (ETTP) began Wednesday, marking the removal of the fourth of five gaseous diffusion buildings at the former uranium enrichment site. The...

  13. The Thermodynamics of Gaseous, Cuprous Chloride Monomer and Trimer

    E-Print Network [OSTI]

    Brewer, Leo

    2010-01-01

    No.W-7405-eng~48B TIiE THERMODYNAMICS OF GASEOUS" CUPROUSCu(s) + HCl::= I Thermodynamics of Vaporization to Monomeric

  14. Paducah Gaseous Diffusion Plant - GW OU Northwest Plume | Department...

    Office of Environmental Management (EM)

    - GW OU Northwest Plume January 1, 2014 - 12:00pm Addthis US Department of Energy Groundwater Database Groundwater Master Report InstallationName, State: Paducah Gaseous...

  15. Paducah Gaseous Diffusion Plant - GW OU Northeast Plume | Department...

    Office of Environmental Management (EM)

    - GW OU Northeast Plume January 1, 2014 - 12:00pm Addthis US Department of Energy Groundwater Database Groundwater Master Report InstallationName, State: Paducah Gaseous...

  16. Federal Facility Agreement for the Paducah Gaseous Diffusion...

    Office of Environmental Management (EM)

    Federal Facility Agreement for the Paducah Gaseous Diffusion Plant State Kentucky Agreement Type Federal Facility Agreement Legal Driver(s) CERCLARCRA Scope Summary Ensure that...

  17. Gaseous Detonation-Driven Fracture of Tubes Tong Wa Chao

    E-Print Network [OSTI]

    Barr, Al

    Gaseous Detonation-Driven Fracture of Tubes Thesis by Tong Wa Chao In Partial Fulfillment An experimental investigation of fracture response of aluminum 6061-T6 tubes under internal gaseous detonation of this particular traveling load and tube geometry produced fracture data not available before in the open

  18. 2011 GASEOUS IONS GORDON RESEARCH CONFERENCE

    SciTech Connect (OSTI)

    Scott Anderson

    2011-03-04

    The Gaseous Ions: Structures, Energetics and Reactions Gordon Research Conference will focus on ions and their interactions with molecules, surfaces, electrons, and light. The conference will cover theory and experiments, and systems ranging from molecular to biological to clusters to materials. The meeting goal continues to be bringing together scientists interested in fundamentals, with those applying fundamental phenomena to a wide range of practical problems. Each of the ten conference sessions will focus on a topic within this spectrum, and there will also be poster sessions for contributed papers, with sufficient space and time to allow all participants to present their latest results. To encourage active participation by young investigators, about ten of the poster abstracts will be selected for 15 minute 'hot topic' talks during the conference sessions. Hot topic selection will be done about a month before the meeting. Funds should be available to offset the participation cost for young investigators.

  19. Growth of graphene films from non-gaseous carbon sources

    DOE Patents [OSTI]

    Tour, James; Sun, Zhengzong; Yan, Zheng; Ruan, Gedeng; Peng, Zhiwei

    2015-08-04

    In various embodiments, the present disclosure provides methods of forming graphene films by: (1) depositing a non-gaseous carbon source onto a catalyst surface; (2) exposing the non-gaseous carbon source to at least one gas with a flow rate; and (3) initiating the conversion of the non-gaseous carbon source to the graphene film, where the thickness of the graphene film is controllable by the gas flow rate. Additional embodiments of the present disclosure pertain to graphene films made in accordance with the methods of the present disclosure.

  20. Combustion characteristics of alternative gaseous fuels

    SciTech Connect (OSTI)

    Park, O.; Veloo, Peter S.; Liu, N.; Egolfopoulos, Fokion N.

    2011-01-01

    Fundamental flame properties of mixtures of air with hydrogen, carbon monoxide, and C{sub 1}–C{sub 4} saturated hydrocarbons were studied both experimentally and numerically. The fuel mixtures were chosen in order to simulate alternative gaseous fuels and to gain insight into potential kinetic couplings during the oxidation of fuel mixtures. The studies included the use of the counterflow configuration for the determination of laminar flame speeds, as well as extinction and ignition limits of premixed flames. The experiments were modeled using the USC Mech II kinetic model. It was determined that when hydrocarbons are added to hydrogen flames as additives, flame ignition, propagation, and extinction are affected in a counterintuitive manner. More specifically, it was found that by substituting methane by propane or n-butane in hydrogen flames, the reactivity of the mixture is reduced both under pre-ignition and vigorous burning conditions. This behavior stems from the fact that propane and n-butane produce higher amounts of methyl radicals that can readily recombine with atomic hydrogen and reduce thus the rate of the H + O{sub 2} ? O + OH branching reaction. The kinetic model predicts closely the experimental data for flame propagation and extinction for various fuel mixtures and pressures, and for various amounts of carbon dioxide in the fuel blend. On the other hand, it underpredicts, in general, the ignition temperatures.

  1. Demolition of K-31 gaseous diffusion building begins | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    OREM began demolition of the 750,000 sq. ft. K-31 Building, marking the removal of the fourth of five gaseous diffusion buildings at the former uranium enrichment site. OREM began...

  2. Method for removing acid gases from a gaseous stream

    DOE Patents [OSTI]

    Gorin, Everett (San Rafael, CA); Zielke, Clyde W. (McMurray, PA)

    1981-01-01

    In a process for hydrocracking a heavy aromatic polynuclear carbonaceous feedstock containing reactive alkaline constituents to produce liquid hydrocarbon fuels boiling below about 475.degree. C. at atmospheric pressure by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, thereafter separating a gaseous stream containing hydrogen, at least a portion of the hydrocarbon fuels and acid gases from the molten metal halide and regenerating the molten metal halide, thereby producing a purified molten metal halide stream for recycle to the hydrocracking zone, an improvement comprising; contacting the gaseous acid gas, hydrogen and hydrocarbon fuels-containing stream with the feedstock containing reactive alkaline constituents to remove acid gases from the acid gas containing stream. Optionally at least a portion of the hydrocarbon fuels are separated from gaseous stream containing hydrogen, hydrocarbon fuels and acid gases prior to contacting the gaseous stream with the feedstock.

  3. Feasibility of gas-phase decontamination of gaseous diffusion equipment

    SciTech Connect (OSTI)

    Munday, E.B.; Simmons, D.W.

    1993-02-01

    The five buildings at the K-25 Site formerly involved in the gaseous diffusion process contain 5000 gaseous diffusion stages as well as support facilities that are internally contaminated with uranium deposits. The gaseous diffusion facilities located at the Portsmouth Gaseous Diffusion Plant and the Paducah Gaseous Diffusion Plant also contain similar equipment and will eventually close. The decontamination of these facilities will require the most cost-effective technology consistent with the criticality, health physics, industrial hygiene, and environmental concerns; the technology must keep exposures to hazardous substances to levels as low as reasonably achievable (ALARA). This report documents recent laboratory experiments that were conducted to determine the feasibility of gas-phase decontamination of the internal surfaces of the gaseous diffusion equipment that is contaminated with uranium deposits. A gaseous fluorinating agent is used to fluorinate the solid uranium deposits to gaseous uranium hexafluoride (UF[sub 6]), which can be recovered by chemical trapping or freezing. The lab results regarding the feasibility of the gas-phase process are encouraging. These results especially showed promise for a novel decontamination approach called the long-term, low-temperature (LTLT) process. In the LTLT process: The equipment is rendered leak tight, evacuated, leak tested, and pretreated, charged with chlorine trifluoride (ClF[sub 3]) to subatmospheric pressure, left for an extended period, possibly > 4 months, while processing other items. Then the UF[sub 6] and other gases are evacuated. The UF[sub 6] is recovered by chemical trapping. The lab results demonstrated that ClF[sub 3] gas at subatmospheric pressure and at [approx] 75[degree]F is capable of volatilizing heavy deposits of uranyl fluoride from copper metal surfaces sufficiently that the remaining radioactive emissions are below limits.

  4. Feasibility of gas-phase decontamination of gaseous diffusion equipment

    SciTech Connect (OSTI)

    Munday, E.B.; Simmons, D.W.

    1993-02-01

    The five buildings at the K-25 Site formerly involved in the gaseous diffusion process contain 5000 gaseous diffusion stages as well as support facilities that are internally contaminated with uranium deposits. The gaseous diffusion facilities located at the Portsmouth Gaseous Diffusion Plant and the Paducah Gaseous Diffusion Plant also contain similar equipment and will eventually close. The decontamination of these facilities will require the most cost-effective technology consistent with the criticality, health physics, industrial hygiene, and environmental concerns; the technology must keep exposures to hazardous substances to levels as low as reasonably achievable (ALARA). This report documents recent laboratory experiments that were conducted to determine the feasibility of gas-phase decontamination of the internal surfaces of the gaseous diffusion equipment that is contaminated with uranium deposits. A gaseous fluorinating agent is used to fluorinate the solid uranium deposits to gaseous uranium hexafluoride (UF{sub 6}), which can be recovered by chemical trapping or freezing. The lab results regarding the feasibility of the gas-phase process are encouraging. These results especially showed promise for a novel decontamination approach called the long-term, low-temperature (LTLT) process. In the LTLT process: The equipment is rendered leak tight, evacuated, leak tested, and pretreated, charged with chlorine trifluoride (ClF{sub 3}) to subatmospheric pressure, left for an extended period, possibly > 4 months, while processing other items. Then the UF{sub 6} and other gases are evacuated. The UF{sub 6} is recovered by chemical trapping. The lab results demonstrated that ClF{sub 3} gas at subatmospheric pressure and at {approx} 75{degree}F is capable of volatilizing heavy deposits of uranyl fluoride from copper metal surfaces sufficiently that the remaining radioactive emissions are below limits.

  5. Portsmouth Gaseous Diffusion Plant- Quadrant I Groundwater Investigative (5-Unit) Area Plume

    Broader source: Energy.gov [DOE]

    Groundwater Database Report - Portsmouth Gaseous Diffusion Plant - Quadrant I Groundwater Investigative (5-Unit) Area Plume

  6. Process for removing carbonyl sulfide from gaseous streams

    SciTech Connect (OSTI)

    Tellis, C.

    1981-11-10

    This invention relates to a process for reducing the carbonyl sulfide content of a gaseous stream which has a concentration of carbonyl sulfide of from at least 1 to about 100 parts per million, by volume, which comprises providing an absorbent bed wherein the absorbent comprises zinc oxide and contains no more than 5%, by weight, of an oxide of an alkli or alkaline earth metal, and contacting said process stream with said adsorbent bed at a temperature of from about ambient to 250/sup 0/ C. For a period of time sufficient to remove at least 90% of the carbonyl sulfide content of said gaseous stream.

  7. Turbulent Wind Fields for Gaseous Phenomena Eugene Fiume 0

    E-Print Network [OSTI]

    Toronto, University of

    Turbulent Wind Fields for Gaseous Phenomena Jos Stam Eugene Fiume 0 Department of Computer Science of smoke, steam, mist and water re­ acting to a turbulent field such as wind is an attractive, and realistic illumina­ tion. We present a model for turbulent wind flow having a deterministic component

  8. Atmospheric escape by magnetically driven wind from gaseous planets

    SciTech Connect (OSTI)

    Tanaka, Yuki A.; Suzuki, Takeru K.; Inutsuka, Shu-ichiro

    2014-09-01

    We calculate the mass loss driven by magnetohydrodynamic (MHD) waves from hot Jupiters by using MHD simulations in one-dimensional flux tubes. If a gaseous planet has a magnetic field, MHD waves are excited by turbulence at the surface, dissipate in the upper atmosphere, and drive gas outflows. Our calculation shows that mass-loss rates are comparable to the observed mass-loss rates of hot Jupiters; therefore, it is suggested that gas flow driven by MHD waves can play an important role in the mass loss from gaseous planets. The mass-loss rate varies dramatically with the radius and mass of a planet: a gaseous planet with a small mass but an inflated radius produces a very large mass-loss rate. We also derive an analytical expression for the dependence of mass-loss rate on planet radius and mass that is in good agreement with the numerical calculation. The mass-loss rate also depends on the amplitude of the velocity dispersion at the surface of a planet. Thus, we expect to infer the condition of the surface and the internal structure of a gaseous planet from future observations of mass-loss rate from various exoplanets.

  9. Methods for deacidizing gaseous mixtures by phase enhanced absorption

    DOE Patents [OSTI]

    Hu, Liang

    2012-11-27

    An improved process for deacidizing a gaseous mixture using phase enhanced gas-liquid absorption is described. The process utilizes a multiphasic absorbent that absorbs an acid gas at increased rate and leads to reduced overall energy costs for the deacidizing operation.

  10. An introduction to technetium in the gaseous diffusion cascades

    SciTech Connect (OSTI)

    Simmons, D.W.

    1996-09-01

    The radioisotope technetium-99 ({sup 99}Tc) was introduced into the gaseous diffusion plants (GDP) as a contaminant in uranium that had been reprocessed from spent nuclear reactor fuel. {sup 99}Tc is a product of the nuclear fission of uranium-235 ({sup 235}U). The significantly higher emitted radioactivity of {sup 99}Tc generates concern in the enrichment complex and warrants increased attention (1) to the control of all site emissions, (2) to worker exposures and contamination control when process equipment requires disassembly and decontamination, and (3) to product purity when the enriched uranium hexafluoride (UF{sub 6}) product is marketed to the private sector. A total of 101,268 metric tons of RU ({approximately}96% of the total) was fed at the Paducah Gaseous Diffusion Plant (PGDP) between FY1953 and FY1976. An additional 5600 metric tons of RU from the government reactors were fed at the Oak Ridge Gaseous Diffusion Plant (ORGDP), plus an approximate 500 tons of foreign reactor returns. Only a small amount of RU was fed directly at the Portsmouth Gaseous Diffusion Plant (PORTS). The slightly enriched PGDP product was then fed to either the ORGDP or PORTS cascades for final enrichment. Bailey estimated in 1988 that of the 606 kg of Tc received at PGDP from RU, 121 kg was subsequently re-fed to ORGDP and 85 kg re-fed to PORTS.

  11. THE POSSIBILITY OF PRODUCING THERMONUCLEAR REACTIONS IN A GASEOUS DISCHARGE*

    E-Print Network [OSTI]

    THE POSSIBILITY OF PRODUCING THERMONUCLEAR REACTIONS IN A GASEOUS DISCHARGE* I.V. Kurchatov of the energy of thermonuclear reactions. Physicists the world over are attracted by the extraordinarily interest- ing and very difficult task of controlling thermonuclear reactiom. Investigations in this field

  12. MEASURING GASEOUS EMISSIONS FROM STORED PIG SLURRY S. Espagnol1

    E-Print Network [OSTI]

    Boyer, Edmond

    2 MEASURING GASEOUS EMISSIONS FROM STORED PIG SLURRY S. Espagnol1 , L. Loyon2 , F. Guiziou2 , P to measure emissions factors of ammonia (NH3), nitrous oxide (N2O) methane (CH4) and carbon dioxide (CO2) from stored pig slurry and measured the variations of the emissions in time and space. In 2006, dynamic

  13. Coated photocathodes for visible photon imaging with gaseous photomultipliers

    E-Print Network [OSTI]

    Coated photocathodes for visible photon imaging with gaseous photomultipliers E. Shefer*, A photocathodes, coated with thin CsI and CsBr protective "lms, for applications within gas avalanche., Jerusalem, Israel. achieved, though at the expense of some reduction in the quantum e$ciency, by coating

  14. Paducah Gaseous Diffusion Plant environmental report for 1992

    SciTech Connect (OSTI)

    Horak, C.M. [ed.] [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States)

    1993-09-01

    This two-part report, Paducah Gaseous Diffusion Plant Environmental Report for 1992, is published annually. It reflects the results of an environmental monitoring program designed to quantify potential increases in the concentration of contaminants and potential doses to the resident human population. The Paducah Gaseous Diffusion Plant (PGDP) overall goal for environmental management is to protect the environment and PGDP`s neighbors and to maintain full compliance with all current regulations. The current environmental strategy is to identify any deficiencies and to develop a system to resolve them. The long-range goal of environmental management is to minimize the source of pollutants, reduce the generation of waste, and minimize hazardous waste by substitution of materials.

  15. Paducah Gaseous Diffusion Plant Environmental report for 1990

    SciTech Connect (OSTI)

    Counce-Brown, D. (ed.)

    1991-09-01

    This two-part report, Paducah Gaseous Diffusion Plant Site Environmental Report for 1990, is published annually. It reflects the results of a comprehensive, year-round program to monitor the impact of operations at Paducah Gaseous Diffusion Plant (PGDP) on the area's groundwater and surface waters, soil, air quality, vegetation, and wildlife. In addition, an assessment of the effect of PGDP effluents on the resident human population is made. PGDP's overall goal for environmental management is to protect the environment and PGDP's neighbors and to maintain full compliance with all current regulations. The current environmental strategy is to identify any deficiencies and to develop a system to resolve them. The long-range goal of environmental management is to minimize the source of pollutants, to reduce the formation of waste, and to minimize hazardous waste by substitution of materials.

  16. Paducah Gaseous Diffusion Plant Annual Site Environmental Report for 1993

    SciTech Connect (OSTI)

    Not Available

    1994-10-01

    The purpose of this document is to summarize effluent monitoring and environmental surveillance results and compliance with environmental laws, regulations, and orders at the Paducah Gaseous Diffusion Plant (PGDP). Environmental monitoring at PGDP consists of two major activities: effluent monitoring and environmental surveillance. Effluent monitoring is direct measurement or the collection and analysis of samples of liquid and gaseous discharges to the environment. Environmental surveillance is direct measurement or the collection and analysis of samples of air, water, soil, foodstuff, biota, and other media. Environmental monitoring is performed to characterize and quantify contaminants, assess radiation exposures of members of the public, demonstrate compliance with applicable standards and permit requirements, and detect and assess the effects (if any) on the local environment. Multiple samples are collected throughout the year and are analyzed for radioactivity, chemical content, and various physical attributes.

  17. Method of producing gaseous products using a downflow reactor

    DOE Patents [OSTI]

    Cortright, Randy D; Rozmiarek, Robert T; Hornemann, Charles C

    2014-09-16

    Reactor systems and methods are provided for the catalytic conversion of liquid feedstocks to synthesis gases and other noncondensable gaseous products. The reactor systems include a heat exchange reactor configured to allow the liquid feedstock and gas product to flow concurrently in a downflow direction. The reactor systems and methods are particularly useful for producing hydrogen and light hydrocarbons from biomass-derived oxygenated hydrocarbons using aqueous phase reforming. The generated gases may find used as a fuel source for energy generation via PEM fuel cells, solid-oxide fuel cells, internal combustion engines, or gas turbine gensets, or used in other chemical processes to produce additional products. The gaseous products may also be collected for later use or distribution.

  18. Method and apparatus for analyzing particle-containing gaseous suspensions

    DOE Patents [OSTI]

    Solomon, P.R.; Carangelo, R.M.; Best, P.E.

    1987-03-24

    The method and apparatus permit analyses, by optical means, of properties of gaseous suspensions of particles, by measuring radiation that is emitted, transmitted or scattered by the particles. Determinations of composition, size, temperature and spectral emittance can be performed either in-situ or by sampling, and Fourier-transform infrared spectrometric techniques are most effectively used. Apparatus specifically adapted for performing radiation scattering analyses, and for collecting radiation from different sources, are provided. 51 figs.

  19. Method and apparatus for analyzing particle-containing gaseous suspensions

    DOE Patents [OSTI]

    Solomon, Peter R. (West Hartford, CT); Carangelo, Robert M. (Coventry, CT); Best, Philip E. (Mansfield, CT)

    1987-01-01

    The method and apparatus permit analyses, by optical means, of properties of gaseous suspensions of particles, by measuring radiation that is emitted, transmitted or scattered by the particles. Determinations of composition, size, temperature and spectral emittance can be performed either in-situ or by sampling, and Fourier-transform infrared spectrometric techniques are most effectively used. Apparatus specifically adapted for performing radiation scattering analyses, and for collecting radiation from different sources, are provided.

  20. Overview of seismic considerations at the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Hunt, R.J.; Stoddart, W.C.; Burnett, W.A.; Beavers, J.E.

    1992-10-01

    This paper presents an overview of seismic considerations at the Paducah Gaseous Diffusion Plant (PGDP), which is managed by Martin Marietta Energy Systems, Inc., for the Department of Energy (DOE). The overview describes the original design, the seismic evaluations performed for the Safety Analysis Report (SAR) issued in 1985, and current evaluations and designs to address revised DOE requirements. Future plans to ensure changes in requirements and knowledge are addressed.

  1. Stellar and Gaseous Disk Structures in Cosmological Galaxy Equilibrium Models

    E-Print Network [OSTI]

    Rathaus, Ben

    2015-01-01

    We present "radially-resolved-equilibrium-models" for the growth of stellar and gaseous disks in cosmologically accreting massive halos. Our focus is on objects that evolve to redshifts $z\\sim 2$. We solve the time-dependent equations that govern the radially dependent star-formation rates, inflows and outflows from and to the inter- and circum-galactic medium, and inward radial gas flows within the disks. The stellar and gaseous disks reach equilibrium configurations on dynamical time scales much shorter than variations in the cosmological dark matter halo growth and baryonic accretions rates. We show analytically that mass and global angular momentum conservation naturally give rise to exponential gas and stellar disks over many radial length scales. The gaseous disks are more extended as set by the condition Toomre $Q<1$ for star-formation. The disks rapidly become baryon dominated. For massive, $5\\times 10^{12}M_\\odot$ halos at redshift $z=2$, we reproduced the typical observed star-formation rates of ...

  2. Onsite Gaseous Centrifuge Enrichment Plant UF6 Cylinder Destructive Analysis

    SciTech Connect (OSTI)

    Anheier, Norman C.; Cannon, Bret D.; Qiao, Hong; Carter, Jennifer C.; McNamara, Bruce K.; O'Hara, Matthew J.; Phillips, Jon R.; Curtis, Michael M.

    2012-07-17

    The IAEA safeguards approach for gaseous centrifuge enrichment plants (GCEPs) includes measurements of gross, partial, and bias defects in a statistical sampling plan. These safeguard methods consist principally of mass and enrichment nondestructive assay (NDA) verification. Destructive assay (DA) samples are collected from a limited number of cylinders for high precision offsite mass spectrometer analysis. DA is typically used to quantify bias defects in the GCEP material balance. Under current safeguards measures, the operator collects a DA sample from a sample tap following homogenization. The sample is collected in a small UF6 sample bottle, then sealed and shipped under IAEA chain of custody to an offsite analytical laboratory. Current practice is expensive and resource intensive. We propose a new and novel approach for performing onsite gaseous UF6 DA analysis that provides rapid and accurate assessment of enrichment bias defects. DA samples are collected using a custom sampling device attached to a conventional sample tap. A few micrograms of gaseous UF6 is chemically adsorbed onto a sampling coupon in a matter of minutes. The collected DA sample is then analyzed onsite using Laser Ablation Absorption Ratio Spectrometry-Destructive Assay (LAARS-DA). DA results are determined in a matter of minutes at sufficient accuracy to support reliable bias defect conclusions, while greatly reducing DA sample volume, analysis time, and cost.

  3. Gas phase decontamination of gaseous diffusion process equipment

    SciTech Connect (OSTI)

    Bundy, R.D.; Munday, E.B.; Simmons, D.W.; Neiswander, D.W.

    1994-03-01

    D&D of the process facilities at the gaseous diffusion plants (GDPs) will be an enormous task. The EBASCO estimate places the cost of D&D of the GDP at the K-25 Site at approximately $7.5 billion. Of this sum, nearly $4 billion is associated with the construction and operation of decontamination facilities and the dismantlement and transport of contaminated process equipment to these facilities. In situ long-term low-temperature (LTLT) gas phase decontamination is being developed and demonstrated at the K-25 site as a technology that has the potential to substantially lower these costs while reducing criticality and safeguards concerns and worker exposure to hazardous and radioactive materials. The objective of gas phase decontamination is to employ a gaseous reagent to fluorinate nonvolatile uranium deposits to form volatile LJF6, which can be recovered by chemical trapping or freezing. The LTLT process permits the decontamination of the inside of gas-tight GDP process equipment at room temperature by substituting a long exposure to subatmospheric C1F for higher reaction rates at higher temperatures. This paper outlines the concept for applying LTLT gas phase decontamination, reports encouraging laboratory experiments, and presents the status of the design of a prototype mobile system. Plans for demonstrating the LTLT process on full-size gaseous diffusion equipment are also outlined briefly.

  4. Diffusive Evolution of Gaseous and Diffusive Evolution of Gaseous and Hydrate Horizons of Methane in SeabedHydrate Horizons of Methane in Seabed

    E-Print Network [OSTI]

    Banaji,. Murad

    Diffusive Evolution of Gaseous and Diffusive Evolution of Gaseous and Hydrate Horizons of Methane in SeabedHydrate Horizons of Methane in Seabed Denis S. Goldobin (University of Leicester),Denis S. Goldobin"")) MethaneNetMethaneNet Early Career Workshop Early Career Workshop MiltonMilton KeynesKeynes 2929

  5. Portsmouth Gaseous Diffusion Plant Environmental report for 1990

    SciTech Connect (OSTI)

    Counce-Brown, D.

    1991-09-01

    This calendar year 1990 annual report on environmental surveillance of the US Department of Energy's (DOE's) Portsmouth Gaseous Diffusion Plant (PORTS) and its environs consists of two parts: the summary, discussion, and conclusions (Part 1) and the data presentation (Part 2). The objectives of this report are as follows: report 1990 monitoring data for the installation and its environs that may have been affected by operations on the plant site, provide reasonably detailed information about the plant site and plant operations, provide detailed information on input and assumptions used in all calculations, provide trend analyses (when appropriate) to indicate increases and decreases in environmental impact, and provide general information on plant quality assurance.

  6. Modified gaseous atmospheres for storage of beef, lamb and pork 

    E-Print Network [OSTI]

    Davis, George Theodore

    1979-01-01

    MODIFIED G'~. ' . . OUS ATMOSPHERI. S FOR STORAGE OI REEF, I. PMB AND PORK A Thesis by GEORGE THEODORE DAVIS I II Submitted to thc. graduate college of Texas AsM University in partial fulfillment of the rec, u. 'rement fox the degree... of MASTER OF SCIENCE December ' 1979 Major Subject: Animal "" ience MODIF1ED GASEOUS ATMOSPHERES FOR STORAGE OF BEEFi LAMB AND PORK A Thesis GEORGE THEODORE DAVIS III Approved as to style and content. by (Co Chairman of ommittee) (Member) (Member...

  7. Ionization and scintillation of nuclear recoils in gaseous xenon

    E-Print Network [OSTI]

    J. Renner; V. M. Gehman; A. Goldschmidt; H. S. Matis; T. Miller; Y. Nakajima; D. Nygren; C. A. B. Oliveira; D. Shuman; V. Álvarez; F. I. G. Borges; S. Cárcel; J. Castel; S. Cebrián; A. Cervera; C. A. N. Conde; T. Dafni; T. H. V. T. Dias; J. Díaz; R. Esteve; P. Evtoukhovitch; L. M. P. Fernandes; P. Ferrario; A. L. Ferreira; E. D. C. Freitas; A. Gil; H. Gómez; J. J. Gómez-Cadenas; D. González-Díaz; R. M. Gutiérrez; J. Hauptman; J. A. Hernando Morata; D. C. Herrera; F. J. Iguaz; I. G. Irastorza; M. A. Jinete; L. Labarga; A. Laing; I. Liubarsky; J. A. M. Lopes; D. Lorca; M. Losada; G. Luzón; A. Marí; J. Martín-Albo; A. Martínez; A. Moiseenko; F. Monrabal; M. Monserrate; C. M. B. Monteiro; F. J. Mora; L. M. Moutinho; J. Muñoz Vidal; H. Natal da Luz; G. Navarro; M. Nebot-Guinot; R. Palma; J. Pérez; J. L. Pérez Aparicio; L. Ripoll; A. Rodríguez; J. Rodríguez; F. P. Santos; J. M. F. dos Santos; L. Seguí; L. Serra; A. Simón; C. Sofka; M. Sorel; J. F. Toledo; A. Tomás; J. Torrent; Z. Tsamalaidze; J. F. C. A. Veloso; J. A. Villar; R. C. Webb; J. White; N. Yahlali

    2014-09-09

    Ionization and scintillation produced by nuclear recoils in gaseous xenon at approximately 14 bar have been simultaneously observed in an electroluminescent time projection chamber. Neutrons from radioisotope $\\alpha$-Be neutron sources were used to induce xenon nuclear recoils, and the observed recoil spectra were compared to a detailed Monte Carlo employing estimated ionization and scintillation yields for nuclear recoils. The ability to discriminate between electronic and nuclear recoils using the ratio of ionization to primary scintillation is demonstrated. These results encourage further investigation on the use of xenon in the gas phase as a detector medium in dark matter direct detection experiments.

  8. Process for obtaining gaseous streams rich in ethene

    SciTech Connect (OSTI)

    Cabral, J.A.; Coutinho, P.H.

    1981-02-17

    This invention relates to the production of ethene with a highly profitable yield by means of fluidized bed catalytic cracking of a mixture containing 0.13 to 50 parts by weight of ethanol to 100 parts by weight of hydrocarbons blend at a temperature between 430/sup 0/C and 550/sup 0/C., and pressure between 0 and 5.0kg/cm2 ga in such way that the final gaseous product resulting therefrom has an ethene content between 18.8% and 64% by volume.

  9. K-25 Gaseous Diffusion Process Building | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOE Safety Standards Implementation July 17,76 I Street, NWK-25 Gaseous

  10. Low energy consumption method for separating gaseous mixtures and in particular for medium purity oxygen production

    DOE Patents [OSTI]

    Jujasz, Albert J. (North Olmsted, OH); Burkhart, James A. (Olmsted Falls, OH); Greenberg, Ralph (New York, NY)

    1988-01-01

    A method for the separation of gaseous mixtures such as air and for producing medium purity oxygen, comprising compressing the gaseous mixture in a first compressor to about 3.9-4.1 atmospheres pressure, passing said compressed gaseous mixture in heat exchange relationship with sub-ambient temperature gaseous nitrogen, dividing the cooled, pressurized gaseous mixture into first and second streams, introducing the first stream into the high pressure chamber of a double rectification column, separating the gaseous mixture in the rectification column into a liquid oxygen-enriched stream and a gaseous nitrogen stream and supplying the gaseous nitrogen stream for cooling the compressed gaseous mixture, removing the liquid oxygen-enriched stream from the low pressure chamber of the rectification column and pumping the liquid, oxygen-enriched steam to a predetermined pressure, cooling the second stream, condensing the cooled second stream and evaporating the oxygen-enriched stream in an evaporator-condenser, delivering the condensed second stream to the high pressure chamber of the rectification column, and heating the oxygen-enriched stream and blending the oxygen-enriched stream with a compressed blend-air stream to the desired oxygen concentration.

  11. Regenerable sorbent and method for removing hydrogen sulfide from hot gaseous mixtures

    DOE Patents [OSTI]

    Farrior, Jr., William L. (Morgantown, WV)

    1978-01-01

    Hydrogen sulfide is effectively removed from hot gaseous mixtures useful for industrial purposes by employing a solid absorbent consisting of silica-supported iron oxide in pellet form.

  12. Characterization of the Installed Costs of Prime Movers Using Gaseous Opportunity Fuels, September 2007

    Office of Energy Efficiency and Renewable Energy (EERE)

    A report addendum and final white paper for the Characterization of the Installed Costs of Prime Movers Using Gaseous Opportunity Fuels

  13. Non-Destructive Analysis Calibration Standards for Gaseous Diffusion Plant (GDP) Decommissioning

    Broader source: Energy.gov [DOE]

    The decommissioning of Gaseous Diffusion Plant facilities requires accurate, non-destructive assay (NDA) of residual enriched uranium in facility components for safeguards and nuclear criticality...

  14. Voluntary Protection Program Onsite Review, Infrastructure Support Contract Paducah Gaseous Diffusion Plant- March 2012

    Broader source: Energy.gov [DOE]

    Evaluation to determine whether the Infrastructure Support Contract Paducah Gaseous Diffusion Plant is continuing to perform at a level deserving DOE-VPP Star recognition.

  15. Voluntary Protection Program Onsite Review, Infrastructure Support Contract Paducah Gaseous Diffusion Plant- May 2013

    Broader source: Energy.gov [DOE]

    Evaluation to determine whether Infrastructure Support Contract Paducah Gaseous Diffusion Plant is continuing to perform at a level deserving DOE-VPP Star recognition.

  16. Fixed bed trapping for gaseous fluoride effluent control

    SciTech Connect (OSTI)

    Otey, M.G.; Bayne, C.K.

    1980-06-14

    To comply with future air quality standards for gaseous fluoride emissions at the PGDP, studies are being made to evaluate the most feasible and efficient method of trapping fluorides from the effluents of the different processes. Although this work is in direct support of environmental projects, its results are applicable in other areas. Throughout the diffusion plants there are several areas where fluorides, either single or multiple species, are controlled and/or processed. The solid sorbent studies represent new, promising technology which could have significant impact on the gaseous diffusion plants. Scoping studies of solid sorbents and reaction conditions have been conducted. In a series of statistically designed experiments, the effects of total gas flow, temperature, and fluoride gas flow were studied for eight dry chemicals in a 1-in. diameter fixed bed designed to remove three separate fluoride gas species (hydrogen fluoride (HF), fluorine (F/sub 2/), and chlorine trifluoride (ClF/sub 3/)) from an air stream. The trapping materials selected for the test include two brands of four different material types: soda lime, oolitic calcium carbonate (CaCO/sub 3/), calcium oxide (CaO), and activated alumina (Al/sub 2/O/sub 3/). Additionally, loading factors and material utilization were determined to allow an economic comparison to be made between bed materials.

  17. Spectral modeling of gaseous metal disks around DAZ white dwarfs

    E-Print Network [OSTI]

    K. Werner; T. Nagel; T. Rauch

    2008-09-30

    We report on our attempt for the first non-LTE modeling of gaseous metal disks around single DAZ white dwarfs recently discovered by Gaensicke et al. and thought to originate from a disrupted asteroid. We assume a Keplerian rotating viscous disk ring composed of calcium and hydrogen and compute the detailed vertical structure and emergent spectrum. We find that the observed infrared CaII emission triplet can be modeled with a hydrogen-deficient gas ring located at R=1.2 R_sun, inside of the tidal disruption radius, with Teff about 6000 K and a low surface mass density of about 0.3 g/cm**2. A disk having this density and reaching from the central white dwarf out to R=1.2 R_sun would have a total mass of 7 10**21 g, corresponding to an asteroid with about 160 km diameter.

  18. Portsmouth Gaseous Diffusion Plant annual site environmental report for 1993

    SciTech Connect (OSTI)

    Horak, C.M.

    1994-11-01

    This calendar year (CY) 1993 annual report on environmental monitoring of the US Department of Energy`s (DOE`s) Portsmouth Gaseous Diffusion Plant (Portsmouth) and its environs consists of three separate documents: a summary pamphlet for the general public; a more detail discussion and of compliance status, data, and environmental impacts (this document); and a volume of detailed data that is available on request. The objectives of this report are to report compliance status during 1993; provide information about the plant site and plant operations; report 1993 monitoring data for the installation and its environs that may have been affected by operations on the plant site; document information on input and assumptions used in calculations; provide trend analyses (where appropriate) to indicate increases and decreases in environmental impact, and provide general information on quality assurance for the environmental monitoring program.

  19. Paducah Gaseous Diffusion Plant environmental report for 1991

    SciTech Connect (OSTI)

    Williams, M.F. (ed.) (Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States))

    1992-10-01

    This two-part report is published annually. It reflects the results of an environmental monitoring program designed to quantify potential increases in the concentration of contaminants and potential doses to the resident human population from the Paducah Gaseous Diffusion Plant (PGDP). PGDP's overall goal for environmental management is to protect the environment and PGDP's neighbors and to maintain full compliance with all current regulations. The current environmental strategy is to identify any deficiencies and to develop a system to resolve them. The long-range goal of environmental management is to minimize the source of pollutants, to reduce the generation of waste, and to minimize hazardous waste by substitution of materials. Environmental-monitoring systems at PGDP include emission-monitoring networks for airborne and aqueous discharges, groundwater monitoring, solid waste characterization, and ambient-sampling networks for air, surface water, groundwater, vegetation, food crops, fish, wildlife, soil, and surface stream sediments.

  20. Tiger Team Assessment of the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Not Available

    1990-07-01

    This document contains findings and concerns identified during the Tiger Team Assessment of the Department of Energy's (DOE's) Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky. The assessment was directed by the Department's Office of Environment, Safety and Health (ES H) and was conducted from June 18 to July 20, 1990. The PGDP Tiger Team Assessment is comprehensive in scope. It covers the Environmental, Safety and Health (including OSHA Compliance), and Management areas and determines the site's compliance with applicable federal (including DOE), state, and local regulations and requirements. The objective of the assessment program is to provide the Secretary with information on the current ES H compliance status of DOE facilities, root causation for noncompliance, adequacy of DOE and site contractor ES H management programs, response actions to address the identified problem areas, and DOE-wide ES H compliance trends and root causes. This volume contains appendices.

  1. Seismic issues at the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Fricke, K.E. (Martin Marietta Energy Systems, Inc., Oak Ridge, TN (USA))

    1989-11-01

    A seismic expert workshop was held at the Paducah Gaseous Diffusion Plant (PGDP) on March 13--15, 1989. the PGDP is operated by Martin Marietta Energy Systems, Inc. for the United States Department of Energy (DOE). During the last twenty years the design criteria for natural phenomenon hazards has steadily become more demanding at all of the DOE Oak Ridge Operations (ORO) sites. The purpose of the two-day workshop was to review the seismic vulnerability issues of the PGDP facilities. Participants to the workshop included recognized experts in the fields of seismic engineering, seismology and geosciences, and probabilistic analysis, along with engineers and other personnel from Energy Systems. A complete list of the workshop participants is included in the front of this report. 29 refs.

  2. Gaseous diffusion plant transition from DOE to external regulation

    SciTech Connect (OSTI)

    Dann, R.K.; Crites, T.R.; Rahm-Crites, L.K. [Lawrence Livermore National Lab., CA (United States)

    1997-12-01

    After many years of operation as government-owned/contractor-operated facilities, large portions of the gaseous diffusion plants (GDPs) at Portsmouth, Ohio, and Paducah, Kentucky, were leased to the United States Enrichment Corporation (USEC). These facilities are now certified by the U.S. Nuclear Regulatory Commission (NRC) and subject to oversight by the Occupational Safety and Health Administration (OSHA). The transition from DOE to NRC regulation was more difficult than expected. The original commitment was to achieve NRC certification in October 1995; however, considerably more time was required and transition-related costs escalated. The Oak Ridge Operations Office originally estimated the cost of transition at $60 million; $240 million has been spent to date. The DOE`s experience in transitioning the GDPs to USEC operation with NRC oversight provides valuable lessons (both positive and negative) that could be applied to future transitions.

  3. Paducah Gaseous Diffusion Plant environmental report for 1991. Volume 3

    SciTech Connect (OSTI)

    Williams, M.F. [ed.] [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States)

    1992-10-01

    This two-part report is published annually. It reflects the results of an environmental monitoring program designed to quantify potential increases in the concentration of contaminants and potential doses to the resident human population from the Paducah Gaseous Diffusion Plant (PGDP). PGDP`s overall goal for environmental management is to protect the environment and PGDP`s neighbors and to maintain full compliance with all current regulations. The current environmental strategy is to identify any deficiencies and to develop a system to resolve them. The long-range goal of environmental management is to minimize the source of pollutants, to reduce the generation of waste, and to minimize hazardous waste by substitution of materials. Environmental-monitoring systems at PGDP include emission-monitoring networks for airborne and aqueous discharges, groundwater monitoring, solid waste characterization, and ambient-sampling networks for air, surface water, groundwater, vegetation, food crops, fish, wildlife, soil, and surface stream sediments.

  4. Paducah Gaseous Diffusion Plant environmental report for 1989

    SciTech Connect (OSTI)

    Turner, J.W. )

    1990-10-01

    This two-part environmental report is published annually. It reflects the results of a comprehensive, year-round program to monitor the impact of operations at Paducah Gaseous Diffusion Plant (PGDP) on the area's groundwater and surface waters, soil, air quality, vegetation, and wildlife. In addition, an assessment of the effect of PGDP effluents on the resident human population is made. PGDP's overall goal for environmental management is to protect the environment and PGDP's neighbors and to maintain full compliance with all current regulations. The current environmental strategy is to identify any deficiencies and to develop a system to resolve them. The long-range goal of environmental management is to minimize the source of pollutants, to reduce the formation of waste, and to minimize hazardous waste by substitution of materials. 36 refs.

  5. Gaseous and particulate emissions from a DC arc melter

    SciTech Connect (OSTI)

    Overcamp, T.J.; Speer, M.P.; Griner, S.J.; Cash, D.M. [Clemson Univ., Anderson, SC (United States)

    1997-12-31

    This paper presents the results of the gaseous and particulate emissions from eight experimental tests of a DC arc melter to treat simulated Savannah River soils contaminated with metals, surrogates for radionuclides, and organic debris. The gaseous analyses reported on the concentrations of oxygen, hydrogen, carbon monoxide, carbon dioxide, hydrogen, methane, nitric oxide, and nitrogen dioxide. The carbon dioxide concentration was high for all runs. For the runs with an air purge, the carbon monoxide concentration ranged up to 10% in the runs with the debris and 2% in the runs without debris. Hydrogen ranged up to 5% by with debris and up to 1% without debris. The methane concentration ranged up to 7,000 ppm{sub v} for the runs with debris and 2,000 ppm for the runs without debris. With a nitrogen purge, oxygen concentrations were less than 1%. The carbon dioxide concentrations ranged from 3 to 15%. Much of this carbon dioxide was probably due the carbonates added to the feed material. The carbon monoxide concentration ranged up to 20% with the debris and 7% without debris. Hydrogen was above 6% in with debris and up to 6% without debris. The methane concentration ranged up to 10,000 ppm{sub v} with debris and 4,000 ppm{sub v} without debris. The particulate concentrations exiting ranged from 32 to 145 g/m{sup 3}. From the chemical analyses, the primary elements were silicon and calcium. The CHN analyses indicated that carbon, probably as carbonates, are an additional component in the particulate matter. The estimated emissions were at a level of 3% or less for cerium, up to 7% for nickel, and 11 to 30% for cesium.

  6. Application of Gaseous Sphere Injection Method for Modeling Under-expanded H2 Injection

    SciTech Connect (OSTI)

    Whitesides, R; Hessel, R P; Flowers, D L; Aceves, S M

    2010-12-03

    A methodology for modeling gaseous injection has been refined and applied to recent experimental data from the literature. This approach uses a discrete phase analogy to handle gaseous injection, allowing for addition of gaseous injection to a CFD grid without needing to resolve the injector nozzle. This paper focuses on model testing to provide the basis for simulation of hydrogen direct injected internal combustion engines. The model has been updated to be more applicable to full engine simulations, and shows good agreement with experiments for jet penetration and time-dependent axial mass fraction, while available radial mass fraction data is less well predicted.

  7. Portsmouth Gaseous Diffusion Plant environmental report for 1989

    SciTech Connect (OSTI)

    Turner, J.W. )

    1990-10-01

    This calendar year 1989 annual report on environmental surveillance of the US Department of Energy's (DOE) Portsmouth Gaseous Diffusion Plant (PORTS) and its environs consists of two parts: the Summary, Discussion, and Conclusions (Part 1) and the Data Presentation (Part 2). The objectives of this report are the following: report 1989 monitoring data for the installation and its environs that may have been affected by operations on the plant site, provide reasonably detailed information about the plant site and plant operations, provide detailed information on input and assumptions used in all calculations, provide trend analyses (where appropriate) to indicate increases and decreases in environmental impact, and provide general information on plant quality assurance. Routine monitoring and sampling for radiation, radioactive materials, and chemical substances on and off the DOE site are used to document compliance with appropriate standards, to identify trends, to provide information for the public, and to contribute to general environmental knowledge. The surveillance program assists in fulfilling the DOE policy of protecting the public, employees, and environment from harm that could be caused by its activities and reducing negative environmental impacts to the greatest degree practicable. Environmental-monitoring information complements data on specific releases, trends, and summaries. 26 refs.

  8. Radiation Tests for a Single-GEM Loaded Gaseous Detector

    E-Print Network [OSTI]

    Lee, Kyong Sei; Kim, Sang Yeol; Park, Sung Keun

    2014-01-01

    We report on the systematic study of a single-gas-electron-multiplication (GEM) loaded gaseous detector developed for precision measurements of high-energy particle beams and dose-verification measurements. In the present study, a 256-channel prototype detector with an active area of 16$\\times$16 cm$^{2}$, operated in a continuous current-integration-mode signal-processing method, was manufactured and tested with x rays emitted from a 70-kV x-ray generator and 43-MeV protons provided by the MC50 proton cyclotron at the Korea Institute of Radiological and Medical Science (KIRAMS). The amplified detector response was measured for the x rays with an intensity of about 5$\\times$10$^{6}$ Hz cm$^{-2}$. The linearity of the detector response to the particle flux was examined and validated by using 43-MeV proton beams. The non-uniform development of the amplification for the gas electrons in space was corrected by applying proper calibration to the channel responses of the measured beam-profile data. We concluded fro...

  9. Gaseous fueled vehicles: A role for natural gas and hydrogen

    SciTech Connect (OSTI)

    Blazek, C.F.; Jasionowski, W.J.

    1991-01-01

    The commercialization of gaseous hydrogen fueled vehicles requires both the development of hydrogen fueled vehicles and the establishment of a hydrogen fueling infrastructure. These requirements create a classic chicken and egg scenario in that manufacturers will not build and consumers will not buy vehicles without an adequate refueling infrastructure and potential refueling station operators will not invest the needed capital without an adequate market to serve. One solution to this dilemma is to create a bridging strategy whereby hydrogen is introduced gradually via another carrier. The only contending alternative fuel that can act as a bridge to hydrogen fueled vehicles is natural gas. To explore this possibility, IGT is conducting emission tests on its dedicated natural gas vehicle (NGV) test platform to determine what, if any, effects small quantities of hydrogen have on emissions and performance. Furthermore, IGT is actively developing an adsorbent based low-pressure natural gas storage system for NGV applications. This system has also shown promise as a storage media for hydrogen. A discussion of our research results in this area will be presented. Finally, a review of IGT's testing facility will be presented to indicate our capabilities in conducted natural gas/hydrogen vehicle (NGHV) research. 3 refs., 10 figs.

  10. Partnering efforts at the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Warren, C.B. [Environmental Protection Agency, Atlanta, GA (United States)

    1995-12-31

    Before individuals or agencies can effectively work together to solve common problems, they must first agree on exactly what those problems are and establish common goals and methods that will lead to mutually acceptable solutions. Then, they must make a conscientious effort to form a cohesive team that focuses on the established goals and deemphasize traditional roles, which may in some instances be considered adversarial. This kind of teamwork/partnering process can be more difficult, though not impossible, to achieve in cases where there are traditional (real or imagined) adversarial relationships between the parties, i.e. regulator vs. regulated. The US Department of Energy Site Office (DOE) at Paducah, Kentucky, the Kentucky Department of Environmental Protection (KDEP) and the US Environmental Protection Agency, Region IV (EPA) have made t strides toward teamwork and partnering at DOE`s Paducah Gaseous Diffusion Plant. They have accomplished this in a number of ways, which will be discussed in greater detail but first and foremost, the agencies agreed up front that they had mutual goals and interests. These goals are to protect public health and the environment in a cost-effective and timely manner, taking care to make the wisest use of public resources (tax dollars); to evaluate and minimize risks, and to achieve ``Win-Win`` for all parties concerned.

  11. Bioavailability study for the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Phipps, T.L.; Kszos, L.A.

    1996-08-01

    The overall purpose of this plan is to assess the bioavailability of metals in the continuous and intermittent outfalls. The results may be used to determine alternative metal limits that more appropriately measure the portion of metal present necessary for toxicity to aquatic life. These limits must remain protective of in-stream aquatic life; thus, the highest concentration of metal in the water will be determined concurrently with an assessment of acute or chronic toxicity on laboratory tests. Using the method developed by the Kentucky Division of Water (KDOW), biomonitoring results and chemical data will be used to recommend alternative metal limits for the outfalls of concern. The data will be used to meet the objectives of the study: (1) evaluate the toxicity of continuous outfalls and intermittent outfalls at Paducah Gaseous Diffusion Plant; (2) determine the mean ratio of dissolved to Total Recoverable metal for Cd, Cr, Cu, Pb, Ni, and Zn in the continuous and intermittent outfalls; (3) determine whether the concentration of total recoverable metal discharged causes toxicity to fathead minnows and /or Ceriodaphnia; and (4) determine alternative metal limits for each metal of concern (Cd, Cr, Cu, Pb, Ni, and Zn).

  12. Radiation monitoring during criticality at a gaseous diffusion plant

    SciTech Connect (OSTI)

    Goebel, G.R.; Hines, T.W.; Carver, A.M.

    1994-12-31

    The Paducah gaseous diffusion plant (PGDP) has two systems of radiation detection units that monitor radiation associated with a nuclear criticality accident (NCA). The primary system, the criticality accident alarm system (CAAS), is composed of several detection units that alarm when gamma-radiation levels exceed 10 mR/h. The CAAS provides the means to initiate emergency-evacuation procedures in the event of an NCA. This system is augmented with a second system of radiation detectors, which is referred to as the argon gamma graph (AGG) system. The AGG system is utilized specifically for the remote monitoring of radiation during an NCA and is a primary tool used by emergency response personnel. The remote radiation readings supplied by the AGG system provide the means to quickly locate and characterize an NCA. The centralized remote monitoring of radiation during an NCA permits important data to be collected efficiently without subjecting personnel to unknown and unquantified radiation fields. Calculations of the expected radiation readings on the AGG system were performed for a postulated NCA at four different locations at PGDP.

  13. Paducah Gaseous Diffusion Plant Northwest Plume interceptor system evaluation

    SciTech Connect (OSTI)

    Laase, A.D.; Clausen, J.L.

    1998-07-01

    The Paducah Gaseous Diffusion Plant (PGDP) recently installed an interceptor system consisting of four wells, evenly divided between two well fields, to contain the Northwest Plume. As stated in the Northwest Plume Record of Decision (ROD), groundwater will be pumped at a rate to reduce further contamination and initiate control of the northwest contaminant plume. The objective of this evaluation was to determine the optimum (minimal) well field pumping rates required for plume hotspot containment. Plume hotspot, as defined in the Northwest Plume ROD and throughout this report, is that portion of the plume with trichloroethene (TCE) concentrations greater than 1,000 {micro}g/L. An existing 3-dimensional groundwater model was modified and used to perform capture zone analyses of the north and south interceptor system well fields. Model results suggest that the plume hotspot is not contained at the system design pumping rate of 100 gallons per minute (gal/min) per well field. Rather, the modeling determined that north and south well field pumping rates of 400 and 150 gal/min, respectively, are necessary for plume hotspot containment. The difference between the design and optimal pumping rates required for containment can be attributed to the discovery of a highly transmissive zone in the vicinity of the two well fields.

  14. Effect of gaseous inhibitors on PCDD/F formation

    SciTech Connect (OSTI)

    Ruokojaervi, P.H.; Halonen, I.A.; Tuppurainen, K.A.; Tarhanen, J.; Ruuskanen, J.

    1998-10-15

    Emissions of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) from municipal waste incineration are currently a subject of considerable public concern because of their extreme toxicity. PCDD/F formation in incineration processes is being studied widely, but studies on inhibition are quite sparse, especially in a pilot-plant scale. In this work, the effect of four gaseous inhibitors (sulfur dioxide, ammonia, dimethylamine, and methyl mercaptan) on PCDD/PCDF formation in the combustion of liquid fuel was studied using a pilot-scale plant. The inhibitors were injected into the flue gas stream after the first economizer at a temperature of 670 C and just before the second economizer at 410 C. Both the chlorophenol and PCDD and PCDF concentrations decreased when inhibitors were added. Particle-phase PCDD/F concentrations in particular decreased by up to 98%. The results suggest that the formation of PCDD/Fs is hindered in the particle phase at the early stages of the PCDD/F formation chain, probably even before precursors such as chlorophenols have been formed.

  15. Photoelectron spectroscopy of wet and gaseous samples through graphene membranes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kraus, Jürgen; Reichelt, Robert; Günther, Sebastian; Gregoratti, Luca; Amati, Matteo; Kiskinova, Maya; Yulaev, Alexander; Vlassiouk, Ivan V.; Kolmakov, Andrei

    2014-09-21

    Photoelectron spectroscopy (PES) and microscopy are highly important for exploring morphologically and chemically complex liquid–gas, solid–liquid and solid–gas interfaces under realistic conditions, but the very small electron mean free path inside dense media imposes serious experimental challenges. Currently, near ambient pressure PES is conducted using dexterously designed electron energy analyzers coupled with differentially pumped electron lenses which make it possible to conduct PES measurements at a few hPa. This report proposes an alternative ambient pressure approach that can be applied to a broad class of samples and be implemented in conventional PES instruments. It uses ultrathin electron transparent but molecularmore »impermeable membranes to isolate the high pressure sample environment from the high vacuum PES detection system. We show that the separating graphene membrane windows are both mechanically robust and sufficiently transparent for electrons in a wide energy range to allow soft X-ray PES of liquid and gaseous water. The performed proof-of-principle experiments confirm the possibility to probe vacuum-incompatible toxic or reactive samples placed inside such hermetic, gas flow or fluidic environmental cells.« less

  16. Numerical assessment of stability criteria from disturbance energies in gaseous combustion

    E-Print Network [OSTI]

    Nicoud, Franck

    Numerical assessment of stability criteria from disturbance energies in gaseous combustion A, which corresponds to a ducted, laminar premixed propane-air flame, is used to assess the different terms

  17. Biomaterials 24 (2003) 37573764 Cell adhesion on gaseous plasma modified poly-(l-lactide) surface

    E-Print Network [OSTI]

    Yang, Jian

    2003-01-01

    Biomaterials 24 (2003) 3757­3764 Cell adhesion on gaseous plasma modified poly-(l-lactide) surface properties of biomaterials. It is commonly accepted that the adhesion of cells to solid substrata

  18. Mixed waste storage facility CDR review, Paducah Gaseous Diffusion Plant; Solid waste landfill CDR review, Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    NONE

    1998-08-01

    This report consists of two papers reviewing the waste storage facility and the landfill projects proposed for the Paducah Gaseous Diffusion Plant complex. The first paper is a review of DOE`s conceptual design report for a mixed waste storage facility. This evaluation is to review the necessity of constructing a separate mixed waste storage facility. The structure is to be capable of receiving, weighing, sampling and the interim storage of wastes for a five year period beginning in 1996. The estimated cost is assessed at approximately $18 million. The review is to help comprehend and decide whether a new storage building is a feasible approach to the PGDP mixed waste storage problem or should some alternate approach be considered. The second paper reviews DOE`s conceptual design report for a solid waste landfill. This solid waste landfill evaluation is to compare costs and the necessity to provide a new landfill that would meet State of Kentucky regulations. The assessment considered funding for a ten year storage facility, but includes a review of other facility needs such as a radiation detection building, compactor/baler machinery, material handling equipment, along with other personnel and equipment storage buildings at a cost of approximately $4.1 million. The review is to help discern whether a landfill only or the addition of compaction equipment is prudent.

  19. Stratified charge combustion system and method for gaseous fuel internal combustion engines

    SciTech Connect (OSTI)

    Rhoades, W.A. Jr.

    1986-03-11

    This patent describes a stratified charge combustion system for use in a gaseous fuel internal combustion engine. This system consists of: (a) a combustion chamber; (b) an ignition; (c) a gaseous fuel injection valve assembly in communication with the combustion chamber and in spaced relationship from the ignition source with a portion of the inside surfaces extending between the fuel injection valve assembly and the ignition source. The fuel valve assembly defines an entry port for the entrance of gaseous fuel, the entry port is recessed outside of a fixed inside surface. (d) means for pressuring the gaseous fuel prior to injection; and (e) a curved transitional surface extending from the entry port toward the portion of the inside surfaces extending between the fuel injection valve assembly and the ignition source. The curved transitional surface curves away from the direction of the entry port. The curved transitional surface has a curvature for the particular direction and configuration of the entry port. The particular configuration of the portion of the inside surfaces extends between the injection valve assembly and the ignition source. The particular arrangment of the fuel injection valve assembly in the combustion chamber, and for the particular pressure of the gaseous fuel is to produce the Coanda Effect in the injected gaseous fuel flow after it passes through the entry port and follows the curved transitional surface under the Coanda Effect. As the curved transitional surface curves away from the direction of the entry port, a flow is produced of the gaseous fuel that clings to and follows the particular configuration of the inside surfaces to the ignition source.

  20. The Effects of Gaseous Ozone and Nitric Acid Deposition on two Crustose Lichen Species From Joshua Tree National Park

    E-Print Network [OSTI]

    Hessom, Elizabeth Curie

    2012-01-01

    photosynthetic rate responses to ozone in some foliose andof gaseous nitric acid and ozone on lichens. Dissertations &with nitric acid and ozone. Environmental Pollution, In

  1. EA-1856: Conveyance of Land and Facilities at the Portsmouth Gaseous Diffusion Plant for Economic Development Purposes, Piketon, Ohio

    Broader source: Energy.gov [DOE]

    This EA will evaluate the environmental impacts of conveyance of land and facilities at the Portsmouth Gaseous Diffusion Plant, in Piketon, Ohio, for economic development purposes.

  2. Oak Ridge National Lebroatory Liquid&Gaseous Waste Treatment System Strategic Plan

    SciTech Connect (OSTI)

    Van Hoesen, S.D.

    2003-09-09

    Excellence in Laboratory operations is one of the three key goals of the Oak Ridge National Laboratory (ORNL) Agenda. That goal will be met through comprehensive upgrades of facilities and operational approaches over the next few years. Many of ORNL's physical facilities, including the liquid and gaseous waste collection and treatment systems, are quite old, and are reaching the end of their safe operating life. The condition of research facilities and supporting infrastructure, including the waste handling facilities, is a key environmental, safety and health (ES&H) concern. The existing infrastructure will add considerably to the overhead costs of research due to increased maintenance and operating costs as these facilities continue to age. The Liquid Gaseous Waste Treatment System (LGWTS) Reengineering Project is a UT-Battelle, LLC (UT-B) Operations Improvement Program (OIP) project that was undertaken to develop a plan for upgrading the ORNL liquid and gaseous waste systems to support ORNL's research mission.

  3. Transient model of an intermediate surge system for the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Beard, B.; Blankenship, J.G.; McGrady, P.W.

    1989-09-01

    Engineering design work (Reference 1) is underway for intermediate surge systems to be added to the Paducah Gaseous Diffusion Plant (PGDP) cascade as part of the Process Inventory Control System (PICS) project. These systems would be located between 000 buildings and lower half 00 buildings and would remove or add inventory during cascade transients in order to protect cascade compressors from overload and surge. Similar systems were operated in the Oak Ridge Gaseous Diffusion Plant cascade and are operated in the Portsmouth Gaseous Diffusion Plant cascade. A steady state flow analysis of the system to be installed at the PGDP has been made. The flow analysis did not address response of the surge system to the cascade transients, nor did it address automatic control of the system. The need to address these issues prompted development of the transient model described in this report. 2 refs., 8 figs., 2 tabs.

  4. On-line vibration and analysis system at the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Herricks, D.M.; Strunk, W.D.

    1988-02-01

    The enrichment facility in Paducah, KY uses a unique hard-wired vibration monitoring and analysis system for gaseous diffusion equipment. The axial flow and centrifugal flow compressors used in uranium enrichment range in size from 6 feet in diameter to less than one foot in diameter. These compressors must operate smoothly and safely, without breech of containment, since the working fluid of gaseous diffusion is gaseous UF/sub 6/. The condition of 1925 compressors is monitored by use of the 2500 point vibration analysis system. Since the failure mechanisms of the compressors are well known and documented, only one accelerometer per machine is needed for most machines. The system is completely automated and can generate spectra or broadband levels in either acceleration or velocity units. Levels are stored for historical review. The analyst can, via a custom telecommunications link, view and analyze data from all monitored points with an office PC. 4 figs.

  5. Impacts of a Nanosized Ceria Additive on Diesel Engine Emissions of Particulate and Gaseous Pollutants

    E-Print Network [OSTI]

    Garfunkel, Eric

    Impacts of a Nanosized Ceria Additive on Diesel Engine Emissions of Particulate and Gaseous incorporating nanosized ceria have been increasingly used in diesel engines as combustion promoters. However- cylinder, four-cycle diesel engine using fuel mixes containing nanoceria of varying concentrations

  6. Gaseous 3,4-Pyridyne and the Formation of Diazabiphenylene Jerry Kramer and R. Stephen Berry*

    E-Print Network [OSTI]

    Berry, R. Stephen

    8336 Gaseous 3,4-Pyridyne and the Formation of Diazabiphenylene Jerry Kramer and R. Stephen Berry, Illinois 60637. Received March 15, 1972 Abstract: Flash photolysis of pyridine-3-diazonium-4 The analogous reaction of 3,4-pyridyne leads to the formation of 2,6- and/or 2,7-diazabiphenylene, one member

  7. D&D of the French High Enrichment Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    BEHAR, Christophe; GUIBERTEAU, Philippe; DUPERRET, Bernard; TAUZIN, Claude

    2003-02-27

    This paper describes the D&D program that is being implemented at France's High Enrichment Gaseous Diffusion Plant, which was designed to supply France's Military with Highly Enriched Uranium. This plant was definitively shut down in June 1996, following French President Jacques Chirac's decision to end production of Highly Enriched Uranium and dismantle the corresponding facilities.

  8. Nonlinear signal contamination effects for gaseous plume detection in hyperspectral imagery

    E-Print Network [OSTI]

    Theiler, James

    Nonlinear signal contamination effects for gaseous plume detection in hyperspectral imagery James-plume pixels are inadvertently included, then that background characterization will be contaminated. In broad in the scene are off- plume, so some contamination is inevitable. In general, the contaminated background

  9. Environmental Restoration Site-Specific Plan for the Portsmouth Gaseous Diffusion Plant, FY 93

    SciTech Connect (OSTI)

    Not Available

    1993-01-15

    The purpose of this Site-Specific Plan (SSP) is to describe past, present, and future activities undertaken to implement Environmental Restoration and Waste Management goals at the Portsmouth Gaseous Diffusion Plant (PORTS). The SSP is presented in sections emphasizing Environmental Restoration description of activities, resources, and milestones.

  10. Emission and Long-Range Transport of Gaseous Mercury from a

    E-Print Network [OSTI]

    Lee, Xuhui

    Emission and Long-Range Transport of Gaseous Mercury from a Large-Scale Canadian Boreal Forest FireQuebec.Thesemeasurementsindicated significant and highly correlated increases in Hg and CO during the plume event. The Hg:CO emissions ratio emissions and biomass burned to determine a mean area-based Hg emission flux density for boreal forest fires

  11. Apparatus for the production of heavier hydrocarbons from gaseous light hydrocarbons

    SciTech Connect (OSTI)

    Agee, K.L.

    1990-11-27

    This patent describes apparatus for producing heavier hydrocarbons from one or more gaseous light hydrocarbons. It comprises a partial oxidation burner means; a synthesis gas generation vessel; a hydrocarbon synthesis reactor; first conduit means; separating means; second conduit means; catalytic combustion means; third conduit means; carbon dioxide separating means; fourth conduit means; and fifth conduit means.

  12. Fracture response of externally flawed aluminum cylindrical shells under internal gaseous detonation loading

    E-Print Network [OSTI]

    Barr, Al

    Fracture response of externally flawed aluminum cylindrical shells under internal gaseous. Experiments were performed to observe the fracture behavior of thin- wall and initially-flawed aluminum tubes to different fracture events are analyzed. Keywords: tube fracture, detonation, crack branching, crack curving

  13. A Simple and Highly Sensitive Colorimetric Detection Method for Gaseous Formaldehyde

    E-Print Network [OSTI]

    Suslick, Kenneth S.

    A Simple and Highly Sensitive Colorimetric Detection Method for Gaseous Formaldehyde Liang Feng 116023, P. R. China Received December 8, 2009; E-mail: ksuslick@illinois.edu Formaldehyde is widely used of such materials, however, occurs surprisingly readily from urea-formaldehyde foam insulation, particle board

  14. Superfund record of decision (EPA Region 4): Paducah Gaseous Diffusion Plant Site, Paducah, KY, March 1994

    SciTech Connect (OSTI)

    Not Available

    1994-07-01

    The decision document presents the selected interim action for the North-South Diversion Ditch (NSDD) at the Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky. The primary objective of this interim remedial action is to initiate control of the source of continued contaminant releases into the NSDD and mitigate the spread of contamination from the NSDD.

  15. Process and system for removing sulfur from sulfur-containing gaseous streams

    DOE Patents [OSTI]

    Basu, Arunabha (Aurora, IL); Meyer, Howard S. (Hoffman Estates, IL); Lynn, Scott (Pleasant Hill, CA); Leppin, Dennis (Chicago, IL); Wangerow, James R. (Medinah, IL)

    2012-08-14

    A multi-stage UCSRP process and system for removal of sulfur from a gaseous stream in which the gaseous stream, which contains a first amount of H.sub.2S, is provided to a first stage UCSRP reactor vessel operating in an excess SO.sub.2 mode at a first amount of SO.sub.2, producing an effluent gas having a reduced amount of SO.sub.2, and in which the effluent gas is provided to a second stage UCSRP reactor vessel operating in an excess H.sub.2S mode, producing a product gas having an amount of H.sub.2S less than said first amount of H.sub.2S.

  16. Measurements of uranium holdup in an operating gaseous diffusion enrichment plant

    SciTech Connect (OSTI)

    Augustson, R.H.; Walton, R.B.; Harris, R.; Harbarger, W.; Hicks, J.; Timmons, G.; Shissler, D.; Tayloe, R.; Jones, S.; Fields, L.

    1983-01-01

    Holdup of nuclear material in process equipment is one of the major sources of uncertainty in materials balances, particularly for high-throughput facilities with large equipment and extensive piping, such as gaseous diffusion uranium-enrichment plants. Locating and measuring the holdup while the plant is operating is a challenging problem because of background from the process material and the neighboring equipment. This paper reports NDA measurements performed at the Goodyear Atomic Gaseous Diffusion Plant, Portsmouth, Ohio, on enrichment equipment at the higher enrichment and (>10% /sup 235/U isotopic abundance) of the cascade. Both neutron and gamma-ray measurements were made to locate anomalously large deposits in converters and compressors and, within the limitations of the techniques, to quantify the amount of the deposit.

  17. A gaseous proportional counter built from a conventional aluminium beverage can

    E-Print Network [OSTI]

    Winkler, Alexander; Hildén, Timo; Garcia, Francisco; Fedi, Giacomo; Devoto, Francesco; Brücken, Erik J

    2015-01-01

    The gaseous proportional counter is a device that can be used to detect ionizing radiation. These devices can be as simple as a cylindrical cathode and a very thin anode wire centered along its axis. By applying a high voltage, a strong electric field is generated close to the anode wire. Ion-pairs, generated by passing ionizing radiation, create avalanches once they drift into the strong electric field region near the anode. The electrical charges created by the avalanche generate an observable signal which is proportional to the energy loss of the incoming radiation. We discuss the construction of such a device. Our detector was built from an ordinary aluminium beverage can and uses a common electric wire strand as the anode. The construction of this detector offers students at universities or technically oriented high schools a detailed understanding of the design and operation of gaseous radiation detectors. The equipment required to complete the project should be available at most institutions.

  18. Energy and materials flows in the production of liquid and gaseous oxygen

    SciTech Connect (OSTI)

    Shen, S.; Wolsky, A.M.

    1980-08-01

    Liquid and gaseous oxygen is produced in an energy-intensive air separation processo that also generates nitrogen. More than 65% of the cost of oxygen is attributable to energy costs. Energy use and materials flows are analyzed for various air separation methods. Effective approaches to energy and material conservation in air separation plants include efficient removal of contaminants (carbon dioxide and water), centralization of air products user-industries so that large air separation plants are cost-effective and the energy use in transportation is minimized, and increased production of nitrogen. Air separation plants can produce more than three times more nitrogen than oxygen, but present markets demand, at most, only 1.5 times more. Full utlization of liquid and gaseous nitrogen should be encouraged, so that the wasted separation energy is minimized. There are potential markets for nitrogen in, for example, cryogenic separation of metallic and plastic wastes, cryogenic particle size reduction, and production of ammonia for fertilizer.

  19. Natural phenomena hazards evaluation of equipment and piping of Gaseous Diffusion Plant Uranium Enrichment Facility

    SciTech Connect (OSTI)

    Singhal, M.K.; Kincaid, J.H.; Hammond, C.R.; Stockdale, B.I.; Walls, J.C. [Oak Ridge National Lab., TN (United States). Technical Programs and Services; Brock, W.R.; Denton, D.R. [Lockheed Martin Energy Systems, Inc., Oak Ridge, TN (United States)

    1995-12-31

    In support of the Gaseous Diffusion Plant Safety Analysis Report Upgrade program (GDP SARUP), a natural phenomena hazards evaluation was performed for the main process equipment and piping in the uranium enrichment buildings at Paducah and Portsmouth gaseous diffusion plants. In order to reduce the cost of rigorous analyses, the evaluation methodology utilized a graded approach based on an experience data base collected by SQUG/EPRI that contains information on the performance of industrial equipment and piping during past earthquakes. This method consisted of a screening walkthrough of the facility in combination with the use of engineering judgment and simple calculations. By using these screenings combined with evaluations that contain decreasing conservatism, reductions in the time and cost of the analyses were significant. A team of experienced seismic engineers who were trained in the use of the DOE SQUG/EPRI Walkdown Screening Material was essential to the success of this natural phenomena hazards evaluation.

  20. Long-range global warming impact of gaseous diffusion plant operation

    SciTech Connect (OSTI)

    Trowbridge, L.D.

    1992-09-01

    The DOE gaseous diffusion plant complex makes extensive use of CFC-114 as a primary coolant. As this material is on the Montreal Protocol list of materials scheduled for production curtailment, a substitute must be found. In addition to physical cooling properties, the gaseous diffusion application imposes the unique requirement of chemical inertness to fluorinating agents. This has narrowed the selection of a near-term substitute to two fully fluorinated material, FC-318 and FC-3110, which are likely to be strong, long-lived greenhouse gases. In this document, calculations are presented showing, for a number of plausible scenarios of diffusion plant operation and coolant replacement strategy, the future course of coolant use, greenhouse gas emissions (including coolant and power-related indirect CO{sub 2} emissions), and the consequent global temperature impacts of these scenarios.

  1. Introduction to the nuclear criticality safety evaluation of facility X-705, Portsmouth Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Sheaffer, M.K.; Keeton, S.C.

    1993-08-16

    This report is the first in a series of documents that will evaluate nuclear criticality safety in the Decontamination and Recovery Facility, X-705, Portsmouth Gaseous Diffusion Plant. It provides an overview of the facility, categorizes its functions for future analysis, reviews existing NCS documentation, and explains the follow-on effort planned for X-705. A detailed breakdown of systems, subsystems, and operational areas is presented and cross-referenced to existing NCS documentation.

  2. Nuclear criticality safety evaluation of Spray Booth Operations in X-705, Portsmouth Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Sheaffer, M.K.; Keeton, S.C.

    1993-09-20

    This report evaluates nuclear criticality safety for Spray Booth Operations in the Decontamination and Recovery Facility, X-705, at the Portsmouth Gaseous Diffusion Plant. A general description of current procedures and related hardware/equipment is presented. Control parameters relevant to nuclear criticality safety are explained, and a consolidated listing of administrative controls and safety systems is developed. Based on compliance with DOE Orders and MMES practices, the overall operation is evaluated, and recommendations for enhanced safety are suggested.

  3. Environmental Restoration Site-Specific Plan for the Paducah Gaseous Diffusion Plant, FY 93

    SciTech Connect (OSTI)

    Not Available

    1993-01-15

    This report provides an overview of the major Environmental Restoration (ER) concerns at Paducah Gaseous Diffusion Plant (PGDP). The identified solid waste management units at PGDP are listed. In the Department of Energy (DOE) Five Year Plan development process, one or more waste management units are addressed in a series of activity data sheets (ADSs) which identify planned scope, schedule, and cost objectives that are representative of the current state of planned technical development for individual or multiple sites.

  4. Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption

    DOE Patents [OSTI]

    Ghate, Madhav R. (Morgantown, WV); Yang, Ralph T. (Williamsville, NY)

    1987-01-01

    Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon, zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high parity hydrogen from gaseous products of coal gasification and as an acid gas scrubber.

  5. Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption

    DOE Patents [OSTI]

    Ghate, M.R.; Yang, R.T.

    1985-10-03

    Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high purity hydrogen from gaseous products of coal gasification and as an acid gas scrubber. 2 figs., 2 tabs.

  6. Laser acceleration of protons using multi-ion plasma gaseous targets

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Tung -Chang; Shao, Xi; Liu, Chuan -Sheng; Eliasson, Bengt; Strathclyde Univ., Glasgow; Hill, III, W. T.; Wang, Jyhpyng; National Central Univ., Taoyuan; Chen, Shih -Hung

    2015-02-01

    We present a theoretical and numerical study of a novel acceleration scheme by applying a combination of laser radiation pressure and shielded Coulomb repulsion in laser acceleration of protons in multi-species gaseous targets. By using a circularly polarized CO? laser pulse with a wavelength of 10 ?m—much greater than that of a Ti: Sapphire laser—the critical density is significantly reduced, and a high-pressure gaseous target can be used to achieve an overdense plasma. This gives us a larger degree of freedom in selecting the target compounds or mixtures, as well as their density and thickness profiles. By impinging such amore »laser beam on a carbon–hydrogen target, the gaseous target is first compressed and accelerated by radiation pressure until the electron layer disrupts, after which the protons are further accelerated by the electron-shielded carbon ion layer. An 80 MeV quasi-monoenergetic proton beam can be generated using a half-sine shaped laser beam with a peak power of 70 TW and a pulse duration of 150 wave periods.« less

  7. United States Department of Energy Paducah Gaseous Diffusion Plant. Environmental monitoring report, calendar year 1984

    SciTech Connect (OSTI)

    Not Available

    1985-07-01

    Air, water, soil, sediments, grass, and groundwater in the vicinity of the Paducah Gaseous Diffusion Plant were continuously or periodically sampled during 1984. Analyses for materials known to be in plant effluents were made to provide effluent control information and to determine compliance with applicable environmental standards. Low sulfur coal is burned in the steam plant to meet Kentucky emission limits for sulfur dioxide. Air analyses for radioactivity indicated concentrations at each off-site sampling station averaged less than 1% of the DOE Radioactivity Concentration Guide (RCG). Offsite analyses for fluorides in grass met the Kentucky Air Quality Requirements. All onsite and offsite airborne fluoride samples met the Kentucky one-week and one-month standards for gaseous HF. Soil samples were analyzed for uranium and showed no significant deviation from normal background concentrations. There was no detectable change in chemical, physical, or radioactive characteristics of the Ohio River attributable to Paducah Gaseous Diffusion Plant operations. The results of water sample analyses of the Ohio River show the chromium and fluoride concentrations to be in compliance with the requirements of the applicable Kentucky regulations. 7 figs., 26 tabs.

  8. EA-0767: Construction and Experiment of an Industrial Solid Waste Landfill at Portsmouth Gaseous Diffusion Plant, Piketon, Ohio

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to construct and operate a solid waste landfill within the boundary at the U.S. Department of Energy's Portsmouth Gaseous Diffusion plant...

  9. Interactions of gaseous HNO3 and water with individual and mixed alkyl self-assembled monolayers at room temperature.

    E-Print Network [OSTI]

    Nishino, Noriko; Hollingsworth, Scott A; Stern, Abraham C; Roeselová, Martina; Tobias, Douglas J; Finlayson-Pitts, Barbara J

    2014-01-01

    of gaseous HNO 3 and water with individual and mixed alkylon all SAM surfaces when water is removed. Results ofof gas-phase HNO 3 and water on organic films using a C8

  10. Gas separation process using membranes with permeate sweep to remove CO.sub.2 from gaseous fuel combustion exhaust

    DOE Patents [OSTI]

    Wijmans Johannes G. (Menlo Park, CA); Merkel, Timothy C. (Menlo Park, CA); Baker, Richard W. (Palo Alto, CA)

    2012-05-15

    A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.

  11. STAR FORMATION IN THE EXTENDED GASEOUS DISK OF THE ISOLATED GALAXY CIG 96

    SciTech Connect (OSTI)

    Espada, D.; Sabater, J.; Verdes-Montenegro, L.; Sulentic, J.; Munoz-Mateos, J. C.; Gil de Paz, A.; Verley, S.; Leon, S.

    2011-07-20

    We study the Kennicutt-Schmidt star formation law and efficiency in the gaseous disk of the isolated galaxy CIG 96 (NGC 864), with special emphasis on its unusually large atomic gas (H I) disk (r{sub Hmathsci}/r{sub 25} = 3.5, r{sub 25} = 1.'85). We present deep Galaxy Evolution Explorer near- and far-UV observations, used as a recent star formation tracer, and we compare them with new, high-resolution (16''or 1.6 kpc) Very Large Array H I observations. The UV and H I maps show good spatial correlation outside the inner 1', where the H I phase dominates over H{sub 2}. Star-forming regions in the extended gaseous disk are mainly located along the enhanced H I emission within two (relatively) symmetric, giant gaseous spiral arm-like features, which emulate an H I pseudo-ring at r {approx_equal} 3'. Inside this structure, two smaller gaseous spiral arms extend from the northeast and southwest of the optical disk and connect to the previously mentioned H I pseudo-ring. Interestingly, we find that the (atomic) Kennicutt-Schmidt power-law index systematically decreases with radius, from N {approx_equal} 3.0 {+-} 0.3 in the inner disk (0.'8-1.'7) to N = 1.6 {+-} 0.5 in the outskirts of the gaseous disk (3.'3-4.'2). Although the star formation efficiency (SFE), the star formation rate per unit of gas, decreases with radius where the H I component dominates as is common in galaxies, we find that there is a break of the correlation at r = 1.5r{sub 25}. At radii 1.5r{sub 25} < r < 3.5r{sub 25}, mostly within the H I pseudo-ring structure, regions exist whose SFE remains nearly constant, SFE {approx_equal} 10{sup -11} yr{sup -1}. We discuss possible mechanisms that might be triggering the star formation in the outskirts of this galaxy, and we suggest that the constant SFE for such large radii (r > 2r{sub 25}) and at such low surface densities might be a common characteristic in extended UV disk galaxies.

  12. MICROSTRUCTURE AND MECHANICAL PROPERTY PERFORMANCE OF COMMERCIAL GRADE API PIPELINE STEELS IN HIGH PRESSURE GASEOUS HYDROGEN

    SciTech Connect (OSTI)

    Stalheim, Mr. Douglas; Boggess, Todd; San Marchi, Chris; Jansto, Steven; Somerday, Dr. B; Muralidharan, Govindarajan; Sofronis, Prof. Petros

    2010-01-01

    The continued growth of the world s developing countries has placed an ever increasing demand on traditional fossil fuel energy sources. This development has lead to increasing research and development of alternative energy sources. Hydrogen gas is one of the potential alternative energy sources under development. Currently the most economical method of transporting large quantities of hydrogen gas is through steel pipelines. It is well known that hydrogen embrittlement has the potential to degrade steel s mechanical properties when hydrogen migrates into the steel matrix. Consequently, the current pipeline infrastructure used in hydrogen transport is typically operated in a conservative fashion. This operational practice is not conducive to economical movement of significant volumes of hydrogen gas as an alternative to fossil fuels. The degradation of the mechanical properties of steels in hydrogen service is known to depend on the microstructure of the steel. Understanding the levels of mechanical property degradation of a given microstructure when exposed to hydrogen gas under pressure can be used to evaluate the suitability of the existing pipeline infrastructure for hydrogen service and guide alloy and microstructure design for new hydrogen pipeline infrastructure. To this end, the 2 Copyright 2010 by ASME microstructures of relevant steels and their mechanical properties in relevant gaseous hydrogen environments must be fully characterized to establish suitability for transporting hydrogen. A project to evaluate four commercially available pipeline steels alloy/microstructure performance in the presences of gaseous hydrogen has been funded by the US Department of Energy along with the private sector. The microstructures of four pipeline steels were characterized and then tensile testing was conducted in gaseous hydrogen and helium at pressures of 800, 1600 and 3000 psi. Based on measurements of reduction of area, two of the four steels that performed the best across the pressure range were selected for evaluation of fracture and fatigue performance in gaseous hydrogen at 800 and 3000 psi. This paper will describe the work performed on four commercially available pipeline steels in the presence of gaseous hydrogen at pressures relevant for transport in pipelines. Microstructures and mechanical property performances will be compared. In addition, recommendations for future work related to gaining a better understanding of steel pipeline performance in hydrogen service will be discussed.

  13. Design considerations for instrumentation to monitor the enrichment of gaseous UF{sub 6}

    SciTech Connect (OSTI)

    Close, D.A.

    1999-07-01

    The measurement of the enrichment of gaseous UF{sub 6} presents unique measurement problems. The well-known uranium enrichment meter is not applicable. For solid samples of uranium, including metal, and oxide and fluoride compounds, the infinite thickness is {approximately}1 cm. Gaseous UF{sub 6}, at a pressure of tens of Torr, has an infinite thickness on the order of 350 m. This is a physically and operationally unrealistic situation for an operating facility. Pipe dimensions and composition also strongly influence the applicable measurement technique. Fundamentally, the definition of enrichment is the ratio of {sup 235}U to total uranium. The amount of {sup 235}U is determined by measuring the intensity of the 185.7-keV gamma ray from the decay of {sup 235}U. There are two methods that have been implemented to determine the amount of total uranium in the gas: X-ray fluorescence (XRF) and gamma-ray transmission. The technique used to measure the amount of total uranium is dependent on the pressure of the gas in the header pipe. The transmission measurement is applicable for higher pressures, generally pressures {lt}40 Torr. The XRF measurement can be used for pressures greater than a few Torr. An XRF measurement at pressures lower than a few Torr becomes very difficult. Two other constraints strongly influence the implementation of the measurement technique--pipe diameter and material composition. These two techniques have been implemented. The XRF technique is an approved measurement by the International Atomic Energy Agency (IAEA) for inspections at gaseous centrifuge facilities. The XRF technique has also been implemented at the Portsmouth Gaseous Diffusion Plant for the IAEA verification experiment during the period December 1997 to October 1998 to verify the downblending of US highly enriched uranium (HEU) to low-enriched uranium (LEU). The transmission technique was originally developed to verify the downblending of Russian HEU to LEU. This instrument was demonstrated at the Paducah Gaseous Diffusion Plant from April 1998 to July 1998 and installed at the Urals Electrochemical Integrated Plant, Novouralsk, Russia, during January 1999.

  14. Investigation of gas-phase decontamination of internally radioactively contaminated gaseous diffusion process equipment and piping

    SciTech Connect (OSTI)

    Bundy, R.D.; Munday, E.B.

    1991-01-01

    Construction of the gaseous diffusion plants (GDPs) was begun during World War 2 to produce enriched uranium for defense purposes. These plants, which utilized UF{sub 6} gas, were used primarily for this purpose through 1964. From 1959 through 1968, production shifted primarily to uranium enrichment to supply the nuclear power industry. Additional UF{sub 6}-handling facilities were built in feed and fuel-processing plants associated with the uranium enrichment process. Two of the five process buildings at Oak ridge were shut down in 1964. Uranium enrichment activities at Oak Ridge were discontinued altogether in 1985. In 1987, the Department of Energy (DOE) decided to proceed with a permanent shutdown of the Oak Ridge Gaseous Diffusion Plant (ORGDP). DOE intends to begin decommissioning and decontamination (D D) of ORGDP early in the next century. The remaining two GDPs are expected to be shut down during the next 10 to 40 years and will also require D D, as will the other UF{sub 6}-handling facilities. This paper presents an investigation of gas- phase decontamination of internally radioactively contaminated gaseous diffusion process equipment and piping using powerful fluorinating reagents that convert nonvolatile uranium compounds to volatile UF{sub 6}. These reagents include ClF{sub 3}, F{sub 2}, and other compounds. The scope of D D at the GDPs, previous work of gas-phase decontamination, four concepts for using gas-phase decontamination, plans for further study of gas-phase decontamination, and the current status of this work are discussed. 13 refs., 15 figs.

  15. Mechanistic study of the isotopic-exchange reaction between gaseous hydrogen and palladium hydride powder

    SciTech Connect (OSTI)

    Outka, D.A.; Foltz, G.W. (Sandia National Labs., Livermore, CA (USA))

    1991-07-01

    A detailed mechanism for the isotopic-exchange reaction between gaseous hydrogen and solid palladium hydride is developed which extends previous model for this reaction by specifically including surface reactions. The modeling indicates that there are two surface-related processes that contribute to the overall rate of exchange: the desorption of hydrogen from the surface and the exchange between surface hydrogen and bulk hydrogen. This conclusion is based upon measurements examining the effect of small concentrations of carbon monoxide were helpful in elucidating the mechanism. Carbon monoxide reversibly inhibits certain steps in the exchange; this slows the overall rate of exchange and changes the distribution of products from the reactor.

  16. Liquefied Gaseous Fuels Safety and Environmental Control Assessment Program: second status report

    SciTech Connect (OSTI)

    1980-10-01

    This document is arranged in three volumes and reports on progress in the Liquefied Gaseous Fuels (LGF) Safety and Environmental Control Assessment Program made in fiscal Year (FY)-1979 and early FY-1980. Volume 3 contains reports from 6 government contractors on LPG, anhydrous ammonia, and hydrogen energy systems. Report subjects include: simultaneous boiling and spreading of liquefied petroleum gas (LPG) on water; LPG safety research; state-of-the-art of release prevention and control technology in the LPG industry; ammonia: an introductory assessment of safety and environmental control information; ammonia as a fuel, and hydrogen safety and environmental control assessment.

  17. 2013 GASEOUS IONS GORDON RESEARCH CONFERENCE, FEBRUARY 24 - MARCH 1, 2013

    SciTech Connect (OSTI)

    Williams, Evan

    2013-03-01

    The Gaseous Ions: Structures, Energetics and Reactions Gordon Research Conference will focus on ions and their interactions with molecules, surfaces, electrons, and light. The long-standing goal of our community is to develop new strategies for capturing complex molecular architectures as gas phase ions where they can be isolated, characterized and manipulated with great sensitivity. Emergent areas of interest include catalytic mechanisms, cryogenic processing of ions extracted from solution, ion fragmentation mechanisms, and new methods for ion formation and structural characterization. The conference will cover theoretical and experimental advances on systems ranging from model studies at the molecular scale to preparation of nanomaterials and characterization of large biological molecules.

  18. Measurement of the electron antineutrino mass from the beta spectrum of gaseous tritium

    SciTech Connect (OSTI)

    Knapp, D.A.

    1986-12-01

    A measurement has been made of the mass of the electron antineutrino using the beta spectrum from a source of gaseous molecular tritium, and an upper limit of 36 eV/c/sup 2/ has been set on this mass. This measurement is the first upper limit on neutrino mass that does not rely on assumptions about the atomic configuration after the beta decay, and it has significantly smaller systematic errors associated with it than do previous measurements. 130 refs., 83 figs., 8 tabs.

  19. Nuclear criticality safety evaluation of large cylinder cleaning operations in X-705, Portsmouth Gaseous diffusion Plant

    SciTech Connect (OSTI)

    Sheaffer, M.K.; Keeton, S.C.; Lutz, H.F.

    1995-06-01

    This report evaluates nuclear criticality safety for large cylinder cleaning operations in the Decontamination and Recovery Facility, X-705, at the Portsmouth Gaseous Diffusion Plant. A general description of current cleaning procedures and required hardware/equipment is presented, and documentation for large cylinder cleaning operations is identified and described. Control parameters, design features, administrative controls, and safety systems relevant to nuclear criticality are discussed individually, followed by an overall assessment based on the Double Contingency Principle. Recommendations for enhanced safety are suggested, and issues for increased efficiency are presented.

  20. Fire protection review revisit No. 2, Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    Dobson, P.H.; Keller, D.R.; Treece, S.D.

    1990-02-01

    A fire protection survey was conducted for the Department of Energy at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky, from October 30--November 4, November 6--10, and December 4--8, 1989. The purpose of the survey was to review the facility fire protection program and to make recommendations. Surveys of other facilities resulted in a classification system for buildings which provide an indication of the importance of the building to the fulfillment of the mission of the facility. Recommendations in this report reflect to some degree the relative importance of the facility and the time to restore it to useful condition in the event a loss were to occur.

  1. Construction and operation of an industrial solid waste landfill at Portsmouth Gaseous Diffusion Plant, Piketon, Ohio

    SciTech Connect (OSTI)

    1995-10-01

    The US Department of Energy (DOE), Office of Waste Management, proposes to construct and operate a solid waste landfill within the boundary of the Portsmouth Gaseous Diffusion Plant (PORTS), Piketon, Ohio. The purpose of the proposed action is to provide PORTS with additional landfill capacity for non-hazardous and asbestos wastes. The proposed action is needed to support continued operation of PORTS, which generates non-hazardous wastes on a daily basis and asbestos wastes intermittently. Three alternatives are evaluated in this environmental assessment (EA): the proposed action (construction and operation of the X-737 landfill), no-action, and offsite shipment of industrial solid wastes for disposal.

  2. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1984-06-19

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  3. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1982-07-07

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  4. U.S. Natural Gas Plant Liquids Production, Gaseous Equivalent (Billion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With WIPP UPDATE: AprilCubic Feet) Production, Gaseous Equivalent

  5. Liquefied Gaseous Fuels Safety and Environmental Control Assessment Program: second status report

    SciTech Connect (OSTI)

    Not Available

    1980-10-01

    The Assistant Secretary for Environment has responsibility for identifying, characterizing, and ameliorating the environmental, health, and safety issues and public concerns associated with commercial operation of specific energy systems. The need for developing a safety and environmental control assessment for liquefied gaseous fuels was identified by the Environmental and Safety Engineering Division as a result of discussions with various governmental, industry, and academic persons having expertise with respect to the particular materials involved: liquefied natural gas, liquefied petroleum gas, hydrogen, and anhydrous ammonia. This document is arranged in three volumes and reports on progress in the Liquefied Gaseous Fuels (LGF) Safety and Environmental Control Assessment Program made in Fiscal Year (FY)-1979 and early FY-1980. Volume 1 (Executive Summary) describes the background, purpose and organization of the LGF Program and contains summaries of the 25 reports presented in Volumes 2 and 3. Annotated bibliographies on Liquefied Natural Gas (LNG) Safety and Environmental Control Research and on Fire Safety and Hazards of Liquefied Petroleum Gas (LPG) are included in Volume 1.

  6. The Blend Down Monitoring System Demonstration at the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Benton, J.; Close, D.; Johnson, W., Jr.; Kerr, P.; March-Leuba, J.; Mastal, E.; Moss, C.; Powell, D.; Sumner, J.; Uckan, T.; Vines, R.; Wright, P.D.

    1999-07-25

    Agreements between the governments of the US and the Russian Federation for the US purchase of low enriched uranium (LEU) derived from highly enriched uranium (HEU) from dismantled Russian nuclear weapons calls for the establishment of transparency measures to provide confidence that nuclear nonproliferation goals are being met. To meet these transparency goals, the agreements call for the installation of nonintrusive US instruments to monitor the down blending of HEU to LEU. The Blend Down Monitoring System (BDMS) has been jointly developed by the Los Alamos National Laboratory (LANL) and the Oak Ridge National Laboratory (ORNL) to continuously monitor {sup 235}U enrichments and mass flow rates at Russian blending facilities. Prior to its installation in Russian facilities, the BDMS was installed and operated in a UF{sub 6} flow loop in the Paducah Gaseous Diffusion Plant simulating flow and enrichment conditions expected in a typical down-blending facility. A Russian delegation to the US witnessed the equipment demonstration in June, 1998. To conduct the demonstration in the Paducah Gaseous Diffusion Plant (PGDP), the BDMS was required to meet stringent Nuclear Regulatory Commission licensing, safety and operational requirements. The Paducah demonstration was an important milestone in achieving the operational certification for the BDMS use in Russian facilities.

  7. Development of NF3 Deposit Removal Technology for the Portsmouth Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Scheele, R.D.; McNamara, B.K.; Rapko, B.M.; Edwards, M.K.; Kozelisky, A.E.; Daniel, R.C. [Battelle Pacific Northwest Division, PO Box 999, Battelle Blvd, Richland, Washington 99352 (United States); McSweeney, T.I.; Maharas, S.J.; Weaver, P.J.; Iwamasa, K.J. [Battelle Columbus Operations, 505 King Avenue, Columbus, Ohio 43201 (United States); Kefgen, R.B. [WASTREN, Inc., 1864 Shyville Road, Piketon, Ohio 45661 (United States)

    2006-07-01

    This paper summarizes the Battelle, Stoller, and WASTREN (BSW) team's efforts, to date, in support of the United States Department of Energy's plans to remove uranium and technetium deposits before decommissioning the Portsmouth Gaseous Diffusion Plant. The BSW team investigated nitrogen trifluoride (NF{sub 3}) as a safer yet effective alternative gaseous treatment to the chlorine trifluoride (ClF{sub 3})-elemental fluorine (F{sub 2}) treatment currently used to remove uranium and technetium deposits from the uranium enrichment cascade. Both ClF{sub 3} and F{sub 2} are highly reactive, toxic, and hazardous gases, while NF{sub 3}, although toxic [1], is no more harmful than moth balls [2]. BSW's laboratory thermo-analytical and laboratory-scale prototype studies with NF{sub 3} established that thermal NF{sub 3} can effectively remove likely and potential uranium (UO{sub 2}F{sub 2} and UF{sub 4}) and technetium deposits (a surrogate deposit material, TcO{sub 2}, and pertechnetates) by conversion to volatile compounds. Our engineering evaluations suggest that NF{sub 3}'s effectiveness could be enhanced by combining with a lesser concentration of ClF{sub 3}. BSW's and other's studies indicate compatibility with Portsmouth materials of construction (aluminum, copper, and nickel). (authors)

  8. Project plan for the background soils project for the Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    NONE

    1995-09-01

    The Background Soils Project for the Paducah Gaseous Diffusion Plant (BSPP) will determine the background concentration levels of selected naturally occurring metals, other inorganics, and radionuclides in soils from uncontaminated areas in proximity to the Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky. The data will be used for comparison with characterization and compliance data for soils, with significant differences being indicative of contamination. All data collected as part of this project will be in addition to other background databases established for the PGDP. The BSPP will address the variability of surface and near-surface concentration levels with respect to (1) soil taxonomical types (series) and (2) soil sampling depths within a specific soil profile. The BSPP will also address the variability of concentration levels in deeper geologic formations by collecting samples of geologic materials. The BSPP will establish a database, with recommendations on how to use the data for contaminated site assessment, and provide data to estimate the potential human and health and ecological risk associated with background level concentrations of potentially hazardous constituents. BSPP data will be used or applied as follows.

  9. Site-specific earthquake response analysis for Paducah Gaseous Diffusion Plant, Paducah, Kentucky. Final report

    SciTech Connect (OSTI)

    Sykora, D.W.; Davis, J.J.

    1993-08-01

    The Paducah Gaseous Diffusion Plant (PGDP), owned by the US Department of Energy (DOE) and operated under contract by Martin Marietta Energy systems, Inc., is located southwest of Paducah, Kentucky. An aerial photograph and an oblique sketch of the plant are shown in Figures 1 and 2, respectively. The fenced portion of the plant consists of 748 acres. This plant was constructed in the 1950`s and is one of only two gaseous diffusion plants in operation in the United States; the other is located near Portsmouth, Ohio. The facilities at PGDP are currently being evaluated for safety in response to natural seismic hazards. Design and evaluation guidelines to evaluate the effects of earthquakes and other natural hazards on DOE facilities follow probabilistic hazard models that have been outlined by Kennedy et al. (1990). Criteria also established by Kennedy et al. (1990) classify diffusion plants as ``moderate hazard`` facilities. The US Army Engineer Waterways Experiment Station (WES) was tasked to calculate the site response using site-specific design earthquake records developed by others and the results of previous geotechnical investigations. In all, six earthquake records at three hazard levels and four individual and one average soil columns were used.

  10. A multispectral scanner survey of the United States Department of Energy's Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Not Available

    1991-06-01

    Airborne multispectral scanner data of the Paducah Gaseous Diffusion Plant (PGDP) and surrounding area were acquired during late spring 1990. This survey was conducted by the Remote Sensing Laboratory (RSL) which is operated by EG G Energy Measurements (EG G/EM) for the US Department of Energy (DOE) Nevada Operations Office. It was requested by the US Department of Energy (DOE) Environmental Audit Team which was reviewing environmental conditions at the facility. The objectives of this survey were to: (1) Acquire 12-channel, multispectral scanner data of the PGDP from an altitude of 3000 feet above ground level (AGL); (2) Acquire predawn, digital thermal infrared (TIR) data of the site from the same altitude; (3) Collect color and color-infrared (CIR) aerial photographs over the facilities; and (4) Illustrate how the analyses of these data could benefit environmental monitoring at the PGDP. This report summarizes the two multispectral scanner and aerial photographic missions at the Paducah Gaseous Diffusion Plant. Selected examples of the multispectral data are presented to illustrate its potential for aiding environmental management at the site. 4 refs., 1 fig., 2 tabs.

  11. Photoionization Models of the Inner Gaseous Disk of the Herbig Be Star BD+65 1637

    E-Print Network [OSTI]

    Patel, P; Landstreet, J D

    2015-01-01

    We attempt to constrain the physical properties of the inner, gaseous disk of the Herbig Be star BD+65 1637 using non-LTE, circumstellar disk codes and observed spectra (3700 to 10,500 \\r{A}) from the ESPaDOnS instrument on CFHT. The photoionizing radiation of the central star is assumed to be the sole source of input energy for the disk. We model optical and near-infrared emission lines that are thought to form in this region using standard techniques that have been successful in modeling the spectra of Classical Be stars. By comparing synthetic line profiles of hydrogen, helium, iron and calcium with the observed line profiles, we try to constrain the geometry, density structure, and kinematics of the gaseous disk. Reasonable matches have been found for all line profiles individually; however, no disk density model based on a single power-law for the equatorial density was able to simultaneously fit all of the observed emission lines. Amongst the emission lines, the metal lines, especially the Ca II IR trip...

  12. The lattice Boltzmann method for isothermal micro-gaseous flow and its application in shale gas flow: a review

    E-Print Network [OSTI]

    Wang, Junjian; Kang, Qinjun; Rahman, Sheik S

    2015-01-01

    The lattice Boltzmann method (LBM) has experienced tremendous advances and been well accepted as a popular method of simulation of various fluid flow mechanisms on pore scale in tight formations. With the introduction of an effective relaxation time and slip boundary conditions, the LBM has been successfully extended to solve micro-gaseous related transport and phenomena. As gas flow in shale matrix is mostly in the slip flow and transition flow regimes, given the difficulties of experimental techniques to determine extremely low permeability, it appears that the computational methods especially the LBM can be an attractive choice for simulation of these micro-gaseous flows. In this paper an extensive overview on a number of relaxation time and boundary conditions used in LBM-like models for micro-gaseous flow are carried out and their advantages and disadvantages are discussed. Furthermore, potential application of the LBM in flow simulation in shale gas reservoirs on pore scale and representative elementary...

  13. Method and system for low-NO.sub.x dual-fuel combustion of liquid and/or gaseous fuels

    DOE Patents [OSTI]

    Gard, Vincent; Chojnacki, Dennis A; Rabovitser, Ioseph K

    2014-12-02

    A method and apparatus for combustion in which a pressurized preheated liquid fuel is atomized and a portion thereof flash vaporized, creating a mixture of fuel vapor and liquid droplets. The mixture is mixed with primary combustion oxidant, producing a fuel/primary oxidant mixture which is then injected into a primary combustion chamber in which the fuel/primary oxidant mixture is partially combusted, producing a secondary gaseous fuel containing hydrogen and carbon oxides. The secondary gaseous fuel is mixed with a secondary combustion oxidant and injected into the second combustion chamber wherein complete combustion of the secondary gaseous fuel is carried out. The resulting second stage flue gas containing very low amounts of NO.sub.x is then vented from the second combustion chamber.

  14. Reassessment of liquefaction potential and estimation of earthquake- induced settlements at Paducah Gaseous Diffusion Plant, Paducah, Kentucky. Final report

    SciTech Connect (OSTI)

    Sykora, D.W.; Yule, D.E.

    1996-04-01

    This report documents a reassessment of liquefaction potential and estimation of earthquake-induced settlements for the U.S. Department of Energy (DOE), Paducah Gaseous Diffusion Plant (PGDP), located southwest of Paducah, KY. The U.S. Army Engineer Waterways Experiment Station (WES) was authorized to conduct this study from FY91 to FY94 by the DOE, Oak Ridge Operations (ORO), Oak Ridge, TN, through Inter- Agency Agreement (IAG) No. DE-AI05-91OR21971. The study was conducted under the Gaseous Diffusion Plant Safety Analysis Report (GDP SAR) Program.

  15. Method and apparatus for removal of gaseous, liquid and particulate contaminants from molten metals

    DOE Patents [OSTI]

    Hobson, David O. (Oak Ridge, TN); Alexeff, Igor (Oak Ridge, TN); Sikka, Vinod K. (Clinton, TN)

    1988-01-01

    Method and apparatus for removal of nonelectrically-conducting gaseous, liquid, and particulate contaminants from molten metal compositions by applying a force thereto. The force (commonly referred to as the Lorentz Force) exerted by simultaneous application of an electric field and a magnetic field on a molten conductor causes an increase, in the same direction as the force, in the apparent specific gravity thereof, but does not affect the nonconducting materials. This difference in apparent densities cause the nonconducting materials to "float" in the opposite direction from the Lorentz Force at a rapid rate. Means are further provided for removal of the contaminants and prevention of stirring due to rotational forces generated by the applied fields.

  16. Gusty, gaseous flows of FIRE: galactic winds in cosmological simulations with explicit stellar feedback

    E-Print Network [OSTI]

    Muratov, Alexander L; Faucher-Giguere, Claude-Andre; Hopkins, Philip F; Quataert, Eliot; Murray, Norman

    2015-01-01

    We present an analysis of the galaxy-scale gaseous outflows from the FIRE (Feedback in Realistic Environments) simulations. This suite of hydrodynamic cosmological zoom simulations provides a sample of halos where star-forming giant molecular clouds are resolved to z=0, and features an explicit stellar feedback model on small scales. In this work, we focus on quantifying the gas mass ejected out of galaxies in winds and how this material travels through the halo. We correlate these quantities to star formation in galaxies throughout cosmic history. Our simulations reveal that a significant portion of every galaxy's evolution, particularly at high redshift, is dominated by bursts of star formation, which are followed by powerful gusts of galactic outflow that sweep up a large fraction of gas in the interstellar medium and send it through the circumgalactic medium. The dynamical effect of these outflows can significantly limit the amount of star formation within the affected galaxy. At low redshift, however, su...

  17. Prograde rotation of protoplanets by accretion of pebbles in a gaseous environment

    E-Print Network [OSTI]

    Johansen, Anders

    2009-01-01

    We perform computer simulations of the accretion of pebbles and rocks onto protoplanets of a few hundred kilometers in radius, including two-way drag force coupling between particles and the protoplanetary disc gas. Particle streams interacting with the gas far out in the Hill sphere of the protoplanet spiral into a prograde circumplanetary disc. Material is accreted onto the protoplanet due to stirring by the turbulent surroundings. We speculate that the trend for prograde rotation among the largest asteroids is primordial and that protoplanets accreted 10%-50% of their mass from pebbles and rocks during the gaseous solar nebula phase. Our model offers an explanation for the narrow range of spin periods observed among the largest bodies in the asteroid and trans-Neptunian belts, and predicts that the 1000 km-scale Kuiper belt objects should preferentially spin in the prograde direction.

  18. Composition, apparatus, and process, for sorption of gaseous compounds of group II-VII elements

    DOE Patents [OSTI]

    Tom, Glenn M. (New Milford, CT); McManus, James V. (Danbury, CT); Luxon, Bruce A. (Stamford, CT)

    1991-08-06

    Scavenger compositions are disclosed, which have utility for effecting the sorptive removal of hazardous gases containing Group II-VII elements of the Periodic Table, such as are widely encountered in the manufacture of semiconducting materials and semiconductor devices. Gas sorption processes including the contacting of Group II-VII gaseous compounds with such scavenger compositions are likewise disclosed, together with critical space velocity contacting conditions pertaining thereto. Further described are gas contacting apparatus, including mesh structures which may be deployed in gas contacting vessels containing such scavenger compositions, to prevent solids from being introduced to or discharged from the contacting vessel in the gas stream undergoing treatment. A reticulate heat transfer structure also is disclosed, for dampening localized exothermic reaction fronts when gas mixtures comprising Group II-VII constituents are contacted with the scavenger compositions in bulk sorption contacting vessels according to the invention.

  19. Study of technetium uptake in vegetation in the vicinity of the Portsmouth Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Acox, T.A.

    1982-01-01

    Technetium-99 was measured in vegetation and soil collected on and near the Portsmouth Gaseous Diffusion Plant to obtain an estimate of the soil-to-vegetation concentration factors. The concentration factors appear to be lognormally distributed with a geometric mean of 3.4 (Bq/kg dry wt. tissue per Bq/kg dry wt. soil) and a geometric standard deviation of 4.7. A dose commitment was calculated using a hypothetical 3.7 x 10/sup 10/ Bq Tc-99/year release and the actual CY-1981 concentration release of Tc-99. The radiological significance of Tc-99 in the terrestial food chain is substantially less than previously believed.

  20. Apparatus and method for operating internal combustion engines from variable mixtures of gaseous fuels

    DOE Patents [OSTI]

    Heffel, James W.; Scott, Paul B.

    2003-09-02

    An apparatus and method for utilizing any arbitrary mixture ratio of multiple fuel gases having differing combustion characteristics, such as natural gas and hydrogen gas, within an internal combustion engine. The gaseous fuel composition ratio is first sensed, such as by thermal conductivity, infrared signature, sound propagation speed, or equivalent mixture differentiation mechanisms and combinations thereof which are utilized as input(s) to a "multiple map" engine control module which modulates selected operating parameters of the engine, such as fuel injection and ignition timing, in response to the proportions of fuel gases available so that the engine operates correctly and at high efficiency irrespective of the gas mixture ratio being utilized. As a result, an engine configured according to the teachings of the present invention may be fueled from at least two different fuel sources without admixing constraints.

  1. Method and apparatus for removal of gaseous, liquid and particulate contaminants from molten metals

    DOE Patents [OSTI]

    Hobson, D.O.; Alexeff, I.; Sikka, V.K.

    1987-08-10

    Method and apparatus for removal of nonelectrically-conducting gaseous, liquid, and particulate contaminants from molten metal compositions by applying a force thereto. The force (commonly referred to as the Lorentz Force) exerted by simultaneous application of an electric field and a magnetic field on a molten conductor causes an increase, in the same direction as the force, in the apparent specific gravity thereof, but does not affect the nonconducting materials. This difference in apparent densities cause the nonconducting materials to ''float'' in the opposite direction from the Lorentz Force at a rapid rate. Means are further provided for removal of the contaminants and prevention of stirring due to rotational forces generated by the applied fields. 6 figs.

  2. The pseudo-photosphere model for the continuum emission of gaseous discs

    E-Print Network [OSTI]

    Vieira, Rodrigo G; Bjorkman, Jon E

    2015-01-01

    We investigate the continuum emission of viscous decretion discs around Be stars in this paper. The results obtained from non-LTE (local thermodynamic equilibrium) radiative transfer models show two regimes in the disc surface brightness profile: an inner optically thick region, which behaves as a pseudo-photosphere with a wavelength-dependent size, and an optically thin tenuous outer part, which contributes with about a third of the total flux. The isophotal shape of the surface brightness is well described by elliptical contours with an axial ratio $b/a=\\cos i$ for inclinations $iemission of gaseous discs. It provides fluxes and spectral slopes at the infrared within an accuracy of $10\\%$ and $5\\%$, respectively, when compared to the numerical results. The model indicates that the infrared spectral slope is mainly determined by both the density radial slope and the disc flaring exponent, being practic...

  3. Apparatus and method for operating internal combustion engines from variable mixtures of gaseous fuels

    DOE Patents [OSTI]

    Heffel, James W. (Lake Matthews, CA); Scott, Paul B. (Northridge, CA); Park, Chan Seung (Yorba Linda, CA)

    2011-11-01

    An apparatus and method for utilizing any arbitrary mixture ratio of multiple fuel gases having differing combustion characteristics, such as natural gas and hydrogen gas, within an internal combustion engine. The gaseous fuel composition ratio is first sensed, such as by thermal conductivity, infrared signature, sound propagation speed, or equivalent mixture differentiation mechanisms and combinations thereof which are utilized as input(s) to a "multiple map" engine control module which modulates selected operating parameters of the engine, such as fuel injection and ignition timing, in response to the proportions of fuel gases available so that the engine operates correctly and at high efficiency irrespective of the gas mixture ratio being utilized. As a result, an engine configured according to the teachings of the present invention may be fueled from at least two different fuel sources without admixing constraints.

  4. Liquefied Gaseous Fuels Safety and Environmental Control Assessment Program: second status report

    SciTech Connect (OSTI)

    1980-10-01

    Volume 2 consists of 19 reports describing technical effort performed by Government Contractors in the area of LNG Safety and Environmental Control. Report topics are: simulation of LNG vapor spread and dispersion by finite element methods; modeling of negatively buoyant vapor cloud dispersion; effect of humidity on the energy budget of a liquefied natural gas (LNG) vapor cloud; LNG fire and explosion phenomena research evaluation; modeling of laminar flames in mixtures of vaporized liquefied natural gas (LNG) and air; chemical kinetics in LNG detonations; effects of cellular structure on the behavior of gaseous detonation waves under transient conditions; computer simulation of combustion and fluid dynamics in two and three dimensions; LNG release prevention and control; the feasibility of methods and systems for reducing LNG tanker fire hazards; safety assessment of gelled LNG; and a four band differential radiometer for monitoring LNG vapors.

  5. A probabilistic safety analysis of UF{sub 6} handling at the Portsmouth Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Boyd, G.J.; Lewis, S.R.; Summitt, R.L. [Safety and Reliability Optimization Services (SAROS), Inc., Knoxville, TN (United States)

    1991-12-31

    A probabilistic safety study of UF{sub 6} handling activities at the Portsmouth Gaseous Diffusion Plant has recently been completed. The analysis provides a unique perspective on the safety of UF{sub 6} handling activities. The estimated release frequencies provide an understanding of current risks, and the examination of individual contributors yields a ranking of important plant features and operations. Aside from the probabilistic results, however, there is an even more important benefit derived from a systematic modeling of all operations. The integrated approach employed in the analysis allows the interrelationships among the equipment and the required operations to be explored in depth. This paper summarizes the methods used in the study and provides an overview of some of the technical insights that were obtained. Specific areas of possible improvement in operations are described.

  6. Local drainage analyses of the Paducah and Portsmouth Gaseous Diffusion Plants during an extreme storm

    SciTech Connect (OSTI)

    Johnson, R.O.; Wang, J.C.; Lee, D.W.

    1993-11-01

    Local drainage analyses have been performed for the Paducah and Portsmouth Gaseous Diffusion Plants during an extreme storm having an approximate 10,000-yr recurrence interval. This review discusses the methods utilized to accomplish the analyses in accordance with US Department of Energy (DOE) design and evaluation guidelines, and summarizes trends, results, generalizations, and uncertainties applicable to other DOE facilities. Results indicate that some culverts may be undersized, and that the storm sewer system cannot drain the influx of precipitation from the base of buildings. Roofs have not been designed to sustain ponding when the primary drainage system is clogged. Some underground tunnels, building entrances, and ground level air intakes may require waterproofing.

  7. Regional flood hazard assessment of the Paducah and Portsmouth Gaseous Diffusion Plants

    SciTech Connect (OSTI)

    Johnson, R.O.; Wang, J.C.; Lee, D.W.

    1991-01-01

    Regional flood-hazard assessments performed for the Paducah and Portsmouth Gaseous Diffusion Plants are reviewed, compared, and contrasted to determine the relationship of probable maximum flood methodology with respect to US Department of Energy design and evaluation guidelines. The Paducah assessment was carried out using probable maximum flood methodology, while the Portsmouth assessment utilized probabilistic techniques. Results indicated that regional flooding along nearby rivers would not inundate either plant, and that the guidelines were satisfied. A comparison of results indicated that the probable maximum flood recurrence interval associated with the Paducah assessment exceeded the 10,000 years depending on the choice of the probabilistic model used to perform the assessment. It was concluded, based on an analysis of two data points, that smaller watersheds driven by single event storms could be assessed using probabilistic techniques, while probable maximum flood methodology could be applied to larger drainage basins flooded by storm sequences. 32 refs., 3 figs.

  8. Report on the biological monitoring program at Paducah Gaseous Diffusion Plant December 1990 to November 1992

    SciTech Connect (OSTI)

    Kszos, L.A. [ed.

    1994-03-01

    On September 23, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous Diffusion Plant (PGDP). Beginning in fall 1991, the Environmental Sciences Division (ESD) at Oak Ridge National Lab (ORNL) added data collection and report preparation to its responsibilities for the PGDP BMP. The BMP has been continued because it has proven to be extremely valuable in identifying those effluents with the potential for adversely affecting instream fauna, assessing the ecological health of receiving streams, guiding plans for remediation, and protecting human health. In September 1992, a renewed permit was issued which requires toxicity monitoring of continuous and intermittent outfalls on a quarterly basis. The BMP for PGDP consists of three major tasks: (1) effluent and ambient toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of stream communities. This report includes ESD/ORNL activities occurring from December 1990 to November 1992.

  9. Privatization of the gaseous diffusion plants and impacts on nuclear criticality safety administration

    SciTech Connect (OSTI)

    D`Aquila, D.M.; Holliday, R.T. [Lockheed Martin Utility Services, Inc., Piketon, OH (United States); Dean, J.C. [Lockheed Martin Utility Services, Inc., Paducah, KY (United States)

    1996-12-31

    The Energy Policy Act of 1992 created the United States Enrichment Corporation (USEC) on July 1, 1993. The USEC is a government-owned business that leases those Gaseous Diffusion Plant (GDP) facilities at the Portsmouth, Ohio, and Paducah, Kentucky, sites from the U.S. Department of Energy (DOE) that are required for enriching uranium. Lockheed Martin Utility Services is the operating contractor for the USEC-leased facilities. The DOE has retained use of, and regulation over, some facilities and areas at the Portsmouth and Paducah sites for managing legacy wastes and environmental restoration activities. The USEC is regulated by the DOE, but is currently changing to regulation under the U.S. Nuclear Regulatory Commission (NRC). The USEC is also preparing for privatization of the uranium enrichment enterprise. These changes have significantly affected the nuclear criticality safety (NCS) programs at the sites.

  10. Paducah Gaseous Diffusion Plant Annual Site Environmental Report summary for 1993

    SciTech Connect (OSTI)

    Not Available

    1994-11-01

    This report contains summaries of the environmental programs at Paducah Gaseous Diffusion Plant, environmental monitoring and the results, and the impact of operations on the environment and the public for 1993. The environmental monitoring program at Paducah includes effluent monitoring and environmental surveillance. Effluent monitoring is measurement of releases as they occur. Contaminants are released through either airborne emissions or liquids discharged from the plant. These releases occur as part of normal site operations, such as cooling water discharged from the uranium enrichment cascade operations or airborne releases from ventilation systems. In the event of system failure, this monitoring provides timely warning so that corrective action can be taken before releases reach an unsafe level. Environmental surveillance tracks the dispersion of materials into the environment after they have been released. This involves the collection of samples from various media, such as water, soil, vegetation, and food crops, and the analysis of these samples for certain radionuclides, chemicals, and metals.

  11. Seismically-induced soil amplification at the DOE Paducah Gaseous Diffusion Plant site

    SciTech Connect (OSTI)

    Sykora, D.W.; Haynes, M.E. (Army Engineer Waterways Experiment Station, Vicksburg, MS (United States). Geotechnical Lab.); Brock, W.R.; Hunt, R.J.; Shaffer, K.E. (Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States))

    1991-01-01

    A site-specific earthquake site response (soil amplification) study is being conducted for the Department of Energy (DOE), Paducah Gaseous Diffusion Plant (PGDP). This study is pursuant to an upgraded Final Safety Analysis Report in accordance with requirements specified by DOE. The seismic hazard at PGDP is dominated by the New Madrid Seismic Zone. Site-specific synthetic earthquake records developed by others were applied independently to four soil columns with heights above baserock of about 325 ft. The results for the 1000-year earthquake event indicate that the site period is between 1.0 and 1.5 sec. Incident shear waves are amplified at periods of motion greater than 0.15 sec. The peak free-field horizontal acceleration, occurring at very low periods, is 0.28 g. 13 refs., 13 figs.

  12. Report on the Biological Monitoring Program at Paducah Gaseous Diffusion Plant December 1992--December 1993

    SciTech Connect (OSTI)

    Kszos, L.A.; Hinzman, R.L.; Peterson, M.J.; Ryon, M.G.; Smith, J.G.; Southworth, G.R.

    1995-06-01

    On September 24, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous Diffusion Plant (PGDP). The goals of BMP are to demonstrate that the effluent limitations established for PGDP protect and maintain the use of Little Bayou and Big Bayou creeks for growth and propagation of fish and other aquatic life, characterize potential health and environmental impacts, document the effects of pollution abatement facilities on stream biota, and recommend any program improvements that would increase effluent treatability. The BMP for PGDP consists of three major tasks: effluent and ambient toxicity monitoring, bioaccumulation studies, and ecological surveys of stream communities (i.e., benthic macroinvertebrates and fish). This report includes ESD activities occurring from December 1992 to December 1993, although activities conducted outside this time period are included as appropriate.

  13. Portsmouth Gaseous Diffusion Plant Annual Site Environmental Report summary for 1993

    SciTech Connect (OSTI)

    Not Available

    1994-11-01

    This report contains summaries of the environmental programs at Paducah Gaseous Diffusion Plant, environmental monitoring and the results, and the impact of operations on the environment and the public for 1993. The environmental monitoring program at Paducah includes effluent monitoring and environmental surveillance. Effluent monitoring is measurement of releases as they occur. Contaminants are released through either airborne emissions or liquids discharged from the plant. These releases occur as part of normal site operations, such as cooling water discharged from the uranium enrichment cascade operations or airborne releases from ventilation systems. In the event of system failure, this monitoring provides timely warning so that corrective action can be taken before releases reach an unsafe level. Environmental surveillance tracks the dispersion of materials into the environment after they have been released. This involves the collection of samples from various media, such as water, soil, vegetation, and food crops, and the analysis of these samples for certain radionuclides, chemicals, and metals.

  14. Liquefied gaseous fuels safety and environmental control assessment program: third status report

    SciTech Connect (OSTI)

    Not Available

    1982-03-01

    This Status Report contains contributions from all contractors currently participating in the DOE Liquefied Gaseous Fuels (LG) Safety and Environmental Control Assessment Program and is presented in two principal sections. Section I is an Executive Summary of work done by all program participants. Section II is a presentation of fourteen individual reports (A through N) on specific LGF Program activities. The emphasis of Section II is on research conducted by Lawrence Livermore National Laboratory (Reports A through M). Report N, an annotated bibliography of literature related to LNG safety and environmental control, was prepared by Pacific Northwest Laboratory (PNL) as part of its LGF Safety Studies Project. Other organizations who contributed to this Status Report are Aerojet Energy Conversion Company; Applied Technology Corporation; Arthur D. Little, Incorporated; C/sub v/ International, Incorporated; Institute of Gas Technology; and Massachusetts Institute of Technology. Separate abstracts have been prepared for Reports A through N for inclusion in the Energy Data Base.

  15. Engine gaseous, aerosol precursor and particulate at simulated flight altitude conditions. Technical memo

    SciTech Connect (OSTI)

    Wey, C.C.

    1998-10-01

    The overall objective of the NASA Atmospheric Effects of Aviation Project (AEAP) is to develop scientific bases for assessing atmospheric impacts of the exhaust emissions by both current and future fleets of subsonic and supersonic aircraft. Among the six primary elements of the AEAP is Emissions Characterization. The objective of the Emission Characterization effort is to determine the exhaust emission constituents and concentrations at the engine exit plane. The specific objective of this engine test is to obtain a database of gaseous and particulate emissions as a function of fuel sulfur and engine operating conditions. The database of the particulate emission properties is to be used as a comparative baseline with subsequent flight measurement. The engine used in this test was a Pratt and Whitney F100-200E turbofan engine. Aviation fuel (Jet A) with a range of fuel sulfur was used. Low and high sulfur values are limited by commercially available fuels and by fuel specification limits of 0.3% by weight. Test matrix was set by parametrically varying the combustor inlet temperature (T3) between idle and maximum power setting at simulated SLS and up to five other altitudes for each fuel. Four diagnostic systems, extractive and non-intrusive, were assembled for the gaseous and particulate emissions characterization measurements study. NASA extractive system includes smoke meter and analyzers for measurement of CO, CO{sub 2}, NO, NOx, O{sub 2}, total unburnt hydrocarbons (THC), and SO{sub 2}. Particulate emissions were characterized by University of Missouri-Rolla Mobile Aerosol Sampling System.

  16. Selective Gaseous Extraction: Research, Development and Training for Isotope Production, Final Technical Report

    SciTech Connect (OSTI)

    Bertch, Timothy C,

    2014-03-31

    General Atomics and the University of Missouri Research Reactor (MURR) completed research and development of selective gaseous extraction of fission products from irradiated fuel, which included training and education of MURR students. The process used porous fuel and after irradiation flowed product gases through the fuel to selectively removed desired fission products with the primary goal of demonstrating the removal of rhodium 105. High removal rates for the ruthenium/rhodium (Ru/Rh), tellurium/iodine (Te/I) and molybdenum/technetium (Mo/Tc) series were demonstrated. The success of this research provides for the reuse of the target for further production, significantly reducing the production of actinide wastes relative to processes that dissolve the target. This effort was conducted under DOE funding (DE-SC0007772). General Atomics objective of the project was to conduct R&D on alternative methods to produce a number of radioactive isotopes currently needed for medical and industry applications to include rhodium-105 and other useful isotopes. Selective gaseous extraction was shown to be effective at removing radioisotopes of the ruthenium/rhodium, tellurium/iodine and molybdenum/technetium decay chains while having trace to no quantities of other fission products or actinides. This adds a new, credible method to the area of certain commercial isotope production beyond current techniques, while providing significant potential reduction of process wastes. Waste reduction, along with reduced processing time/cost provides for superior economic feasibility which may allow domestic production under full cost recovery practices. This provides the potential for improved access to domestically produced isotopes for medical diagnostics and treatment at reduced cost, providing for the public good.

  17. EA-1927: Conveyance of Land and Facilities at the Paducah Gaseous Diffusion Plant for Economic Development Purposes, Paducah, Kentucky

    Broader source: Energy.gov [DOE]

    Draft EA: Public Comment Period Ends 07/27/2015DOE’s Portsmouth/Paducah Project Office has prepared a Draft EA for potential land and facilities transfers at the Paducah Gaseous Diffusion Plant in McCracken County, Kentucky.

  18. New C-H Stretching Vibrational Spectral Features in the Raman Spectra of Gaseous and Liquid Ethanol

    E-Print Network [OSTI]

    Liu, Shilin

    New C-H Stretching Vibrational Spectral Features in the Raman Spectra of Gaseous and Liquid Ethanol Traditionally, the Raman spectrum of ethanol in the C-H vibrational stretching region between 2800 cm-1 and 3100, and the -CH3 antisymmetric stretching. In this report, new Raman spectral features were observed for ethanol

  19. TREATMENT OF GASEOUS EFFLUENTS ISSUED FROM RECYCLING – A REVIEW OF THE CURRENT PRACTICES AND PROSPECTIVE IMPROVEMENTS

    SciTech Connect (OSTI)

    Patricia Paviet-Hartmann; William Kerlin; Steven Bakhtiar

    2010-11-01

    The objectives of gaseous waste management for the recycling of nuclear used fuel is to reduce by best practical means (ALARA) and below regulatory limits, the quantity of activity discharged to the environment. The industrial PUREX process recovers the fissile material U(VI) and Pu(IV) to re-use them for the fabrication of new fuel elements e.g. recycling plutonium as a Mixed Oxide (MOX) fuel or recycling uranium for new enrichment for Pressurized Water Reactor (PWR). Meanwhile the separation of the waste (activation and fission product) is performed as a function of their pollution in order to store and avoid any potential danger and release towards the biosphere. Raffinate, that remains after the extraction step and which contains mostly all fission products and minor actinides is vitrified, the glass package being stored temporarily at the recycling plant site. Hulls and end pieces coming from PWR recycled fuel are compacted by means of a press leading to a volume reduced to 1/5th of initial volume. An organic waste treatment step will recycle the solvent, mainly tri-butyl phosphate (TBP) and some of its hydrolysis and radiolytic degradation products such as dibutyl phosphate (HDPB) and monobutyl phosphate (H2MBP). Although most scientific and technological development work focused on high level waste streams, a considerable effort is still under way in the area of intermediate and low level waste management. Current industrial practices for the treatment of gaseous effluents focusing essentially on Iodine-129 and Krypton-85 will be reviewed along with the development of novel technologies to extract, condition, and store these fission products. As an example, the current industrial practice is to discharge Kr-85, a radioactive gas, entirely to the atmosphere after dilution, but for the large recycling facilities envisioned in the near future, several techniques such as 1) cryogenic distillation and selective absorption in solvents, 2) adsorption on activated charcoal, 3) selective sorption on chemical modified zeolites, or 4) diffusion through membranes with selective permeability are potential technologies to retain the gas.

  20. Replacement of chlorofluorocarbons at the DOE gaseous diffusion plants: An assessment of global impacts

    SciTech Connect (OSTI)

    Socolof, M.L.; McCold, L.N.; Saylor, R.E.

    1997-01-01

    Three gaseous diffusion plants (GDPs) for enriching uranium maintain a large inventory of chlorofluorocarbon-114 (CFC-114) as a coolant. To address the continued use of CFC-114, an ozone-depleting substance, the US Department of Energy (DOE) considered introducing perfluorocarbons (PFCs) by the end of 1995. These PFCs would not contribute to stratospheric ozone depletion but would be larger contributors to global warming than would CFC-114. The paper reports the results of an assessment of the global impacts of four alternatives for modifying GDP coolant system operations over a three-year period beginning in 1996. The overall contribution of GDP coolant releases to impacts on ozone depletion and global warming were quantified by parameters referred to as ozone-depletion impact and global-warming impact. The analysis showed that these parameters could be used as surrogates for predicting global impacts to all resources and could provide a framework for assessing environmental impacts of a permanent coolant replacement, eliminating the need for subsequent resource-specific analyses.

  1. Statistics for the Relative Detectability of Chemicals in Weak Gaseous Plumes in LWIR Hyperspectral Imagery

    SciTech Connect (OSTI)

    Metoyer, Candace N.; Walsh, Stephen J.; Tardiff, Mark F.; Chilton, Lawrence

    2008-10-30

    The detection and identification of weak gaseous plumes using thermal imaging data is complicated by many factors. These include variability due to atmosphere, ground and plume temperature, and background clutter. This paper presents an analysis of one formulation of the physics-based model that describes the at-sensor observed radiance. The motivating question for the analyses performed in this paper is as follows. Given a set of backgrounds, is there a way to predict the background over which the probability of detecting a given chemical will be the highest? Two statistics were developed to address this question. These statistics incorporate data from the long-wave infrared band to predict the background over which chemical detectability will be the highest. These statistics can be computed prior to data collection. As a preliminary exploration into the predictive ability of these statistics, analyses were performed on synthetic hyperspectral images. Each image contained one chemical (either carbon tetrachloride or ammonia) spread across six distinct background types. The statistics were used to generate predictions for the background ranks. Then, the predicted ranks were compared to the empirical ranks obtained from the analyses of the synthetic images. For the simplified images under consideration, the predicted and empirical ranks showed a promising amount of agreement. One statistic accurately predicted the best and worst background for detection in all of the images. Future work may include explorations of more complicated plume ingredients, background types, and noise structures.

  2. Design and reliability optimization of a MEMS micro-hotplate for combustion of gaseous fuel

    SciTech Connect (OSTI)

    Manginell, R. P.

    2012-03-01

    This report will detail the process by which the silicon carbide (SiC) microhotplate devices, manufactured by GE, were imaged using IR microscopy equipment available at Sandia. The images taken were used as inputs to a finite element modeling (FEM) process using the ANSYS software package. The primary goal of this effort was to determine a method to measure the temperature of the microhotplate. Prior attempts to monitor the device's temperature by measuring its resistance had proven to be unreliable due to the nonlinearity of the doped SiC's resistance with temperature. As a result of this thermal modeling and IR imaging, a number of design recommendations were made to facilitate this temperature measurement. The lower heating value (LHV) of gaseous fuels can be measured with a catalyst-coated microhotplate calorimeter. GE created a silicon carbide (SiC) based microhotplate to address high-temperature survivability requirements for the application. The primary goal of this effort was to determine a method to measure the temperature of the microhotplate. Prior attempts to monitor the device's temperature by measuring its resistance had proven to be unreliable due to the non-linearity of the doped SiC's resistance with temperature. In this work, thermal modeling and IR imaging were utilized to determine the operation temperature as a function of parameters such as operation voltage and device sheet resistance. A number of design recommendations were made according to this work.

  3. Environmental Survey preliminary report, Oak Ridge Gaseous Diffusion Plant, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    Not Available

    1989-02-01

    This report presents the preliminary findings from the first phase of the Environmental Survey of the US Department of Energy's (DOE) Oak Ridge Gaseous Diffusion Plant (ORGDP) conducted March 14 through 25, 1988. The Survey is being conducted by an interdisciplinary team of environmental specialists, led and managed by the Office of Environment, Safety and Health's Office of Environmental Audit. Individual team components are being supplied by a private contractor. The objective of the Survey is to identify environmental risk associated with ORGDP. The Survey covers all environmental media and all areas of environmental regulation. It is being performed in accordance with the DOE Environmental Survey Manual. This phase of the Survey involves the review of existing site environmental data, observations of the operations carried on at ORGDP, and interviews with site personnel. The Survey team developed a Sampling and Analysis Plan to assist in further assessing certain of the environmental problems identified during is on-site activities. The Sampling and Analysis Plan will be executed by Idaho National Engineering Laboratory (INEL). When completed, the results will be incorporated into the ORGDP Survey findings for in inclusion into the Environmental Survey Summary Report. 120 refs., 41 figs., 74 tabs.

  4. Safeguards Verification Measurements using Laser Ablation, Absorbance Ratio Spectrometry in Gaseous Centrifuge Enrichment Plants

    SciTech Connect (OSTI)

    Anheier, Norman C.; Cannon, Bret D.; Kulkarni, Gourihar R.; Munley, John T.; Nelson, Danny A.; Qiao, Hong; Phillips, Jon R.

    2012-07-17

    Laser Ablation Absorbance Ratio Spectrometry (LAARS) is a new verification measurement technology under development at the US Department of Energy (DOE) Pacific Northwest National Laboratory (PNNL). LAARS uses three lasers to ablate and then measure the relative isotopic abundance of uranium compounds. An ablation laser is tightly focused on uranium-bearing solids, producing a small atomic uranium vapor plume. Two collinear wavelength-tuned spectrometry lasers transit through the plume and the absorbance of U-235 and U-238 isotopes are measured to determine U-235 enrichment. The measurement is independent of chemical form and degree of dilution with nuisance dust and other materials. LAARS has high relative precision and detection limits approaching the femtogram range for U-235. The sample is scanned and assayed point-by-point at rates reaching 1 million measurements/hour, enabling LAARS to detect and analyze uranium in trace samples. The spectrometer is assembled using primarily commercially available components and features a compact design and automated analysis.Two specific gaseous centrifuge enrichment plant (GCEP) applications of the spectrometer are currently under development: 1) LAARS-Environmental Sampling (ES), which collects and analyzes aerosol particles for GCEP misuse detection and 2) LAARS-Destructive Assay (DA), which enables onsite enrichment DA sample collection and analysis for protracted diversion detection. The two applications propose game-changing technological advances in GCEP safeguards verification.

  5. Gaseous Radiochemical Method for Registration of Ionizing Radiation and Its Possible Applications in Science and Industry

    E-Print Network [OSTI]

    S. G. Lebedev; V. E. Yants

    2005-10-06

    This work presents a new possibility of registration of ionizing radiation by the flowing gaseous radiochemical method (FGRM). The specified method uses the property of some solid crystalline lattice materials for a free emission of radioactive isotopes of inert gas atoms formed as a result of nuclear reactions. Generated in an ampoule of the detector, the radioactive inert gases are transported by a gas-carrier into the proportional gas counter of the flowing type, where the decay rate of the radioactive gas species is measured. This quantity is unequivocally related to the flux of particles (neutrons, protons, light and heavy ions) at the location of the ampoule. The method was used to monitor the neutron flux of the pulsed neutron target "RADEX" driven by the linear proton accelerator of INR RAS. Further progress of the FGRM may give rise to possible applications in nuclear physics, astrophysics and medicine, in the nondestructive control of fissionable materials, diagnostics of thermonuclear plasma, monitoring of fluxes and measurement of spectra of bombarding particles.

  6. Radiation Heat Transfer in Particle-Laden Gaseous Flame: Flame Acceleration and Triggering Detonation

    E-Print Network [OSTI]

    Liberman, M A; Kiverin, A D

    2015-01-01

    In this study we examine influence of the radiation heat transfer on the combustion regimes in the mixture, formed by suspension of fine inert particles in hydrogen gas. The gaseous phase is assumed to be transparent for the thermal radiation, while the radiant heat absorbed by the particles is then lost by conduction to the surrounding gas. The particles and gas ahead of the flame is assumed to be heated by radiation from the original flame. It is shown that the maximum temperature increase due to the radiation preheating becomes larger for a flame with lower velocity. For a flame with small enough velocity temperature of the radiation preheating may exceed the crossover temperature, so that the radiation heat transfer may become a dominant mechanism of the flame propagation. In the case of non-uniform distribution of particles, the temperature gradient formed due to the radiation preheating can initiate either deflagration or detonation ahead of the original flame via the Zel'dovich's gradient mechanism. Th...

  7. Report on the biological monitoring program at Paducah Gaseous Diffusion Plant, January--December 1997

    SciTech Connect (OSTI)

    Kszos, L.A.; Peterson, M.J.; Ryon, M.G.; Smith, J.G.; Southworth, G.R.

    1998-03-01

    On September 24, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous Diffusion Plant (PGDP). A plan for the biological monitoring of the receiving streams was implemented in 1987 and consisted of ecological surveys, toxicity monitoring of effluents and receiving streams, evaluation of bioaccumulation of trace contaminants in biota, and supplemental chemical characterization of effluents. Beginning in fall 1991, the Environmental Sciences Division (ESD) at Oak Ridge National Laboratory added data collection and report preparation to its responsibilities for the PGDP BMP. The BMP has been continued because it has proven to be extremely valuable in (1) identifying those effluents with the potential for adversely affecting instream fauna, (2) assessing the ecological health of receiving streams, and (3) guiding plans for remediation and protecting human health. The BMP for PGDP consists of three major tasks: (1) effluent toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of benthic macroinvertebrate communities and fish. With the exception of the benthic macroinvertebrate community surveys, this report focuses on activities from January to December 1997.

  8. Martin Marietta Paducah Gaseous Diffusion Plant comprehensive earthquake emergency management program

    SciTech Connect (OSTI)

    Not Available

    1990-02-28

    Recognizing the value of a proactive, integrated approach to earthquake preparedness planning, Martin Marietta Energy Systems, Inc. initiated a contract in June 1989 with Murray State University, Murray, Kentucky, to develop a comprehensive earthquake management program for their Gaseous Diffusion Plant in Paducah, Kentucky. The overall purpose of the program is to mitigate the loss of life and property in the event of a major destructive earthquake. The program includes four distinct (yet integrated) components: an emergency management plan, with emphasis on the catastrophic earthquake; an Emergency Operations Center Duty Roster Manual; an Integrated Automated Emergency Management Information System (IAEMIS); and a series of five training program modules. The PLAN itself is comprised of four separate volumes: Volume I -- Chapters 1--3; Volume II -- Chapters 4--6, Volume III -- Chapter 7, and Volume IV -- 23 Appendices. The EOC Manual (which includes 15 mutual aid agreements) is designated as Chapter 7 in the PLAN and is a stand alone'' document numbered as Volume III. This document, Volume I, provides an introduction, summary and recommendations, and the emergency operations center direction and control.

  9. Determination of operating limits for radionuclides for a proposed landfill at Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Wang, J.C.; Lee, D.W.; Ketelle, R.H.; Lee, R.R.; Kocher, D.C.

    1994-05-24

    The operating limits for radionuclides in sanitary and industrial wastes were determined for a proposed landfill at the Paducah Gaseous Diffusion Plant (PGDP), Kentucky. These limits, which may be very small but nonzero, are not mandated by law or regulation but are needed for rational operation. The approach was based on analyses of the potential contamination of groundwater at the plant boundary and the potential exposure to radioactivity of an intruder at the landfill after closure. The groundwater analysis includes (1) a source model describing the disposal of waste and the release of radionuclides from waste to the groundwater, (2) site-specific groundwater flow and contaminant transport calculations, and (3) calculations of operating limits from the dose limit and conversion factors. The intruder analysis includes pathways through ingestion of contaminated vegetables and soil, external exposure to contaminated soil, and inhalation of suspended activity from contaminated soil particles. In both analyses, a limit on annual effective dose equivalent of 4 mrem (0.04 mSv) was adopted. The intended application of the results is to refine the radiological monitoring standards employed by the PGDP Health Physics personnel to determine what constitutes radioactive wastes, with concurrence of the Commonwealth of Kentucky.

  10. Determination of operating limits for radionuclides for a proposed landfill at Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Wang, J.C.; Lee, D.W.; Ketelle, R.H.; Lee, R.R.; Kocher, D.C. [Oak Ridge National Lab., TN (United States)

    1994-12-31

    The operating limits for radionuclides in sanitary and industrial wastes were determined for a proposed landfill at the Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky. These limits, which may be very small but nonzero, are not mandated by law or regulation but are needed for rational operation. The primary advantages of establishing such operating limits include (a) technically defensible screening criteria for landfill-destined solid wastes, (b) significant reductions in the required capacity of radioactive waste storage and disposal facilities, and (c) reductions in costs associated with storage and disposal of radioactive materials. The approach was based on analyses of potential contamination of groundwater at the plant boundary and the potential exposure to radioactivity of an intruder at the landfill after closure. The groundwater analysis includes (a) a source model describing the disposal of waste and the release of radionuclides from waste to groundwater, (b) site-specific groundwater flow and contaminant transport calculations, and (c) calculations of operating limits from the dose objective and conversion factors. The intruder analysis includes pathways through ingestion of contaminated vegetables and soil, external exposure to contaminated soil, and inhalation of suspended activity from contaminated soil particles. In both analyses, a limit on annual effective dose equivalent of 4 mrem (0.04 mSv) was adopted.

  11. Report on the biological monitoring program at Paducah Gaseous Diffusion Plant December 1993 to December 1994

    SciTech Connect (OSTI)

    Kszos, L.A. [ed.

    1996-05-01

    On September 24, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous Diffusion Plant (PGDP). The PGDP BMP was implemented in 1987 by the University of Kentucky. Research staff of the Environmental Sciences Division (ESD) at Oak Ridge National Laboratory (ORNL) served as reviewers and advisers to the University of Kentucky. Beginning in fall 1991, ESD added data collection and report preparation to its responsibilities for the PGDP BMP. The goals of BMP are to (1) demonstrate that the effluent limitations established for PGDP protect and maintain the use of Little Bayou and Big Bayou creeks for growth and propagation of fish and other aquatic life, (2) characterize potential environmental impacts, (3) document the effects of pollution abatement facilities on stream biota, and (4) recommend any program improvements that would increase effluent treatability. In September 1992, a renewed Kentucky Pollutant Discharge Elimination System (KPDES) permit was issued to PGDP. The BMP for PGDP consists of three major tasks: (1) effluent and ambient toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of stream communities (i.e., benthic macroinvertebrates and fish). This report includes ESD activities occurring from December 1993 to December 1994, although activities conducted outside this time period are included as appropriate.

  12. Martin Marietta Paducah Gaseous Diffusion Plant comprehensive earthquake emergency management program

    SciTech Connect (OSTI)

    Not Available

    1990-02-28

    Recognizing the value of a proactive, integrated approach to earthquake preparedness planning, Martin Marietta Energy Systems, Inc. initiated a contract in June 1989 with Murray State University, Murray, Kentucky, to develop a comprehensive earthquake management program for their Gaseous Diffusion Plant in Paducah, Kentucky (PGDP -- Subcontract No. 19P-JV649V). The overall purpose of the program is to mitigate the loss of life and property in the event of a major destructive earthquake. The program includes four distinct (yet integrated) components: an emergency management plan, with emphasis on the catastrophic earthquake; an Emergency Operations Center Duty Roster Manual; an Integrated Automated Emergency Management Information System (IAEMIS); and a series of five training program modules. The PLAN itself is comprised of four separate volumes: Volume I -- Chapters 1--3; Volume II -- Chapters 4--6, Volume III -- Chapter 7, and Volume IV -- 23 Appendices. The EOC Manual (which includes 15 mutual aid agreements) is designated as Chapter 7 in the PLAN and is a stand alone'' document numbered as Volume III. This document, Volume II, discusses methodology, engineering and environmental analyses, and operational procedures.

  13. Report on the biological monitoring program at Paducah Gaseous Diffusion Plant, January--December 1996

    SciTech Connect (OSTI)

    Kszos, L.A. [ed.; Konetsky, B.K.; Peterson, M.J.; Petrie, R.B.; Ryon, M.G.; Smith, J.G.; Southworth, G.R.

    1997-06-01

    On September 24, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous diffusion Plant (PGDP). The PGDP BMP was conducted by the University of Kentucky Between 1987 and 1992 and by staff of the Environmental Sciences Division (ESD) at Oak Ridge National Laboratory (ORNL) from 1991 to present. The goals of BMP are to (1) demonstrate that the effluent limitations established for PGDP protect and maintain the use of Little Bayou and Big Bayou creeks for growth and propagation of fish and other aquatic life, (2) characterize potential environmental impacts, and (3) document the effects of pollution abatement facilities on stream. The BMP for PGDP consists of three major tasks: (1) effluent toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of stream communities (i.e., benthic macroinvertebrates and fish). This report focuses on ESD activities occurring from January 1996 to December 1996, although activities conducted outside this time period are included as appropriate.

  14. Seismic hazard evaluation for the Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    Not Available

    1991-07-01

    The study presents the results of an investigation of seismic hazard at the site of the Paducah Gaseous Diffusion Plant. Paducah is located near the northern end of the Reelfoot Rift -- a large feature of the earth's crust that is believed to be associated with the New Madrid earthquakes of 1811 and 1812. Results from three separate seismic hazard analyses are presented here. The EPRI/SOG analysis uses the input data and methodology developed by the Electric Power Research Institute, under the sponsorship of several electric utilities, for the evaluation of seismic hazard in the central and eastern United States. Section 2 of this report documents the application of the EPRI/SOG methodology to the Paducah site (for both rock and soil conditions). The LLNL analysis uses the input data and methodology developed by the Lawrence Livermore National Laboratory for the Nuclear Regulatory Commission. This analysis was performed by LLNL and results were transmitted to us. Section 3 of this report contains a summary of LLNL inputs and results (for both rock and soil conditions, and considering 4 and 5 LLNL ground motion experts). 29 refs., 118 figs., 24 tabs.

  15. Operating limit study for the proposed solid waste landfill at Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Lee, D.W.; Wang, J.C.; Kocher, D.C.

    1995-06-01

    A proposed solid waste landfill at Paducah Gaseous Diffusion Plant (PGDP) would accept wastes generated during normal operations that are identified as non-radioactive. These wastes may include small amounts of radioactive material from incidental contamination during plant operations. A site-specific analysis of the new solid waste landfill is presented to determine a proposed operating limit that will allow for waste disposal operations to occur such that protection of public health and the environment from the presence of incidentally contaminated waste materials can be assured. Performance objectives for disposal were defined from existing regulatory guidance to establish reasonable dose limits for protection of public health and the environment. Waste concentration limits were determined consistent with these performance objectives for the protection of off-site individuals and inadvertent intruders who might be directly exposed to disposed wastes. Exposures of off-site individuals were estimated using a conservative, site-specific model of the groundwater transport of contamination from the wastes. Direct intrusion was analyzed using an agricultural homesteader scenario. The most limiting concentrations from direct intrusion or groundwater transport were used to establish the concentration limits for radionuclides likely to be present in PGDP wastes.

  16. Martin Marietta Paducah Gaseous Diffusion Plant comprehensive earthquake emergency management program

    SciTech Connect (OSTI)

    Not Available

    1990-02-28

    Recognizing the value of a proactive, integrated approach to earthquake preparedness planning, Martin Marietta Energy Systems, Inc, initiated a contract in June 1989 with Murray State University, Murray, Kentucky, to develop a comprehensive earthquake management program for their Gaseous Diffusion Plant in Paducah, Kentucky (PGDP--Subcontract No. 19P-JV649V). The overall purpose of the program is to mitigate the loss of life and property in the event of a major destructive earthquake. The program includes four distinct (yet integrated) components: (1) an emergency management plan, with emphasis on the catas trophic earthquake, (2) an Emergency Operations Center Duty Roster Manual, (3) an Integrated Automated Emergency Management Information System (IAEMIS), and (4) a series of five training program modules. The PLAN itself is comprised of four separate volumes: Volume I--Chapters 1--3; Volume II--Chapters 4--6, Volume III--Chapter 7, and Volume IV--23 Appendices. The EOC Manual (which includes 15 mutual aid agreements) is designated as Chapter 7 in the PLAN and is a stand alone'' document numbered as Volume III. This document, Volume IV contains the appendices to this report.

  17. Martin Marietta Paducah Gaseous Diffusion Plant comprehensive earthquake emergency management program

    SciTech Connect (OSTI)

    Not Available

    1990-02-28

    Recognizing the value of a proactive, integrated approach to earthquake preparedness planning, Martin Marietta Energy Systems, Inc. initiated a contract in June 1989 with Murray State University, Murray, Kentucky, to develop a comprehensive earthquake management program for their Gaseous Diffusion Plant in Paducah, Kentucky (PGDP -- Subcontract No. 19P-JV649V). The overall purpose of the program is to mitigate the loss of life and property in the event of a major destructive earthquake. The program includes four distinct (yet integrated) components: (1) an emergency management plan with emphasis on the catas trophic earthquake; (2) an Emergency Operations Center Duty Roster Manual; (3) an Integrated Automated Emergency Management Information System (IAEMIS); and (4) a series of five training program modules. The PLAN itself is comprised of four separate volumes: Volume I -- Chapters 1--3; Volume II -- Chapters 4--6; Volume III -- Chapter 7; and Volume IV -- 23 Appendices. The EOC Manual (which includes 15 mutual aid agreements) is designated as Chapter 7 in the PLAN and is this document numbered as Volume III.

  18. Uranium isotope exchange between gaseous UF{sub 6} and solid UF{sub 5}

    SciTech Connect (OSTI)

    Yato, Yumio; Kishimoto, Yoichiro; Sasao, Nobuyuki; Suto, Osamu; Funasaka, Hideyuki

    1996-08-01

    Based on a collision model, a new rate equation is derived for uranium isotope exchange between gaseous UF{sub 6} and solid UF{sub 5} by considering the number of UF{sub 5} molecules on the solid surface to be dependent on time. The reaction parameters included in the equation are determined from the experimental data and compared with the previous ones. A remarkable agreement is found between the particle sizes of UF{sub 5} estimated from the reaction parameter and from the direct observation with an electron microscope. The rate equation given in this work fully satisfies the related mass conservation and furthermore includes explicitly the terms related to the UF{sub 6} density and the mean size of UF{sub 5} particles, both of which are considered to cause an important effect on the reaction. This remarkable feature facilitates the simulation studies on this reaction under various conditions. The long term behavior of a simulated exchange reaction is studied under the condition considered to be close to that in a recovery zone of the MLIS process. The result indicates that the reaction is virtually limited to the solid surface under this conditions and thus the depletion of {sup 235}UF{sub 5} concentration averaged over the whole UF{sub 5} particles is not significant even after 200 h of the exchange reaction.

  19. Modeling of temporal behavior of isotopic exchange between gaseous hydrogen and palladium hydride power

    SciTech Connect (OSTI)

    Melius, C F; Foltz, G W

    1987-01-01

    A parametric rate-equation model is described which depicts the time dependent behavior of the isotopic exchange process occurring between the solid and gas phases in gaseous hydrogen (deuterium) flows through packed-powder palladium deuteride (hydride) beds. The exchange mechanism is assumed to be rate-limited by processes taking place on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with recent experimental measurements of isotope exchange in the ..beta..-phase hydrogen/palladium system and, using a literature value of ..cap alpha.. = 2.4, a good description of the experimental data is obtained for p approx. 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of ..cap alpha.. values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

  20. Environmental restoration and waste management site specific plan for Oak Ridge Operation Office Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Not Available

    1990-07-18

    The Paducah Gaseous Diffusion Plant (PGDP) occupies 748 security-fenced acres located on a 3,400-acre tract in McCracken County, Kentucky, which was previously part of the Kentucky Ordnance Works. The principle objective on-site process at PGDP is the separation of uranium isotopes through gaseous diffusion. The process produces enriched uranium, which is used for nuclear fuel in commercial power plants and for military purposes. This document provides an overview of the major environmental and waste management concerns at PGDP, requirements for implementation, organization/management, corrective activities, environmental restoration, waste management options, compliance with National Environmental Policy Act (NEPA), reporting and data management, quality assurance and federal, state and local interactions. 12 refs., 6 figs., 5 tabs.

  1. The development of a sensitive method to study volatile organic compounds in gaseous emissions of lung cancer cell lines 

    E-Print Network [OSTI]

    Maroly, Anupam

    2005-08-29

    ]. Workers exposed to tar and soot (which contains benzo[a]pyrene), such as coke oven workers, [7, 8] in concentrations exceeding those present in urban air are at increased risk of lung cancer. Occupational exposures to a number of metals, including... detection of lung cancer. Tests involved the quantitation of gaseous metabolic emissions from immortalized lung cancer cell lines in order to correlate the chemical markers to be of cancerous origin. The specific aims of the project were the study of gas...

  2. Chemistry of gaseous lower halides of uranium. Technical progress report, 1 September 1979-1 April 1980

    SciTech Connect (OSTI)

    Hildenbrand, D.L.

    1980-04-15

    The gaseous uranium species UF, UF/sub 2/, UF/sub 3/, and UF/sub 4/ were generated in effusion cell beams by vaporization of UF/sub 4/(s) under reducing conditions, and they were identified and studied by mass spectrometry. From extensive second-law studies of reaction equilibria involving these species and several reaction partners used as reference standards, the individual bond dissociation energies and standard enthalpies of formation of the U-F species were derived. Reaction entropies derived from the slope data indicate that the electronic entropies of the U-F species are substantial, and are comparable to or larger than that of atomic uranium. Additional thermochemical measurements were made to establish the properties of several Ag and Cu monohalides that have been or will be used as reference standards in the uranium halide measurements. From studies of the sublimation and decomposition of uranyl fluoride, UO/sub 2/F/sub 2/(s), the enthalpy of sublimation of UO/sub 2/F/sub 2/(g), has been determined, and another gaseous oxyfluoride, UOF/sub 4/(g), has been tentatively identified. The gaseous products of decomposition of UO/sub 2/F/sub 2/(s) observed by mass spectrometry differ from those postulated by other investigators, indicating that the mechanism of decomposition has not been clearly established. A search of the thermochemical literature on uranium halides has been completed.

  3. Method for selectively removing fluorine and fluorine-containing contaminants from gaseous UF/sub 6/. [ClF/sub 3/

    DOE Patents [OSTI]

    Jones, R.L.; Otey, M.G.; Perkins, R.W.

    1980-11-24

    This invention is a method for effecting preferential removal and immobilization of certain gaseous contaminants from gaseous UF/sub 6/. The contaminants include fluorine and fluorides which are more reactive with CaCO/sub 3/ than is UF/sub 6/. The method comprises contacting the contaminant-carrying UF/sub 6/ with particulate CaCO/sub 3/ at a temperature effecting reaction of the contaminant and the CaCO/sub 3/.

  4. BINARIES MIGRATING IN A GASEOUS DISK: WHERE ARE THE GALACTIC CENTER BINARIES?

    SciTech Connect (OSTI)

    Baruteau, C.; Lin, D. N. C.; Cuadra, J. E-mail: lin@ucolick.org

    2011-01-01

    The massive stars in the Galactic center inner arcsecond share analogous properties with the so-called Hot Jupiters. Most of these young stars have highly eccentric orbits and were probably not formed in situ. It has been proposed that these stars acquired their current orbits from the tidal disruption of compact massive binaries scattered toward the proximity of the central supermassive black hole. Assuming a binary star formed in a thin gaseous disk beyond 0.1 pc from the central object, we investigate the relevance of disk-satellite interactions to harden the binding energy of the binary, and to drive its inward migration. A massive, equal-mass binary star is found to become more tightly wound as it migrates inward toward the central black hole. The migration timescale is very similar to that of a single-star satellite of the same mass. The binary's hardening is caused by the formation of spiral tails lagging the stars inside the binary's Hill radius. We show that the hardening timescale is mostly determined by the mass of gas inside the binary's Hill radius and that it is much shorter than the migration timescale. We discuss some implications of the binary's hardening process. When the more massive (primary) components of close binaries eject most their mass through supernova explosion, their secondary stars may attain a range of eccentricities and inclinations. Such processes may provide an alternative unified scenario for the origin of the kinematic properties of the central cluster and S-stars in the Galactic center as well as the high-velocity stars in the Galactic halo.

  5. Modifying woody plants for efficient conversion to liquid and gaseous fuels

    SciTech Connect (OSTI)

    Dinus, R.J.; Dimmel, D.R.; Feirer, R.P.; Johnson, M.A.; Malcolm, E.W. )

    1990-07-01

    The Short Rotation Woody Crop Program (SRWCP), Department of Energy, is developing woody plant species as sources of renewable energy. Much progress has been made in identifying useful species, and testing site adaptability, stand densities, coppicing abilities, rotation lengths, and harvesting systems. Conventional plant breeding and intensive cultural practices have been used to increase above-ground biomass yields. Given these and foreseeable accomplishments, program leaders are now shifting attention to prospects for altering biomass physical and chemical characteristics, and to ways for improving the efficiency with which biomass can be converted to gaseous and liquid fuels. This report provides a review and synthesis of literature concerning the quantity and quality of such characteristics and constituents, and opportunities for manipulating them via conventional selection and breeding and/or molecular biology. Species now used by SRWCP are emphasized, with supporting information drawn from others as needed. Little information was found on silver maple (Acer saccharinum), but general comparisons (Isenberg 1981) suggest composition and behavior similar to those of the other species. Where possible, conclusions concerning means for and feasibility of manipulation are given, along with expected impacts on conversion efficiency. Information is also provided on relationships to other traits, genotype X environment interactions, and potential trade-offs or limitations. Biomass productivity per se is not addressed, except in terms of effects that may by caused by changes in constituent quality and/or quantity. Such effects are noted to the extent they are known or can be estimated. Likely impacts of changes, however effected, on suitability or other uses, e.g., pulp and paper manufacture, are notes. 311 refs., 4 figs., 9 tabs.

  6. Uranium hexafluoride packaging tiedown systems overview at Portsmouth Gaseous Diffusion Plant, Piketon, Ohio

    SciTech Connect (OSTI)

    Becker, D.L.; Lindquist, M.R.

    1993-03-01

    The Portsmouth Gaseous Diffusion Plant (PORTS) in Piketon, Ohio operated by Martin Marietta Energy Systems, Inc., through the US Department of Energy-Oak Ridge Operations Office (DOE-ORO) for the US Department of Energy Headquarters, Office of Nuclear Energy. The PORTS conducts those operations that are necessary for the production, packaging, and shipment of enriched uranium hexafluoride (UF[sub 6]). Uranium hexafluoride enriched greater than 1.0 wt percent [sup 235]U shall be packaged in accordance with the US Department of Transportation (DOT) regulations of Title 49 CFR Parts 173 (Reference 1) and 178 (Reference 2), or in US Nuclear Regulatory Commission (NRC) or US Department of Energy (DOE) certified package designs. Concerns have been expressed regarding the various tiedown methods and condition of the trailers being used by some shippers/carriers for international transport of the UF[sub 6] cylinders/overpacks (Reference 3). Because of the concerns about international shipments, the US Department of Energy-Headquarters (DOE-HQ) Office of Nuclear Energy, through DOE-HQ Transportation Management Division, requested Westinghouse Hanford Company (Westinghouse Hanford) to review UF[sub 6] packaging tiedown and shipping practices used by PORTS, and where possible and appropriate, provide recommendations for enhancing these practices. Consequently, a tram of two individuals from Westinghouse Hanford visited PORTS on March 5 and 6, 1990, for the purpose of conducting this review. The paper provides a brief discussion of the review activities and a summary of the resulting findings and recommendations. A detailed reporting of the review is documented in Reference 4.

  7. Uranium hexafluoride packaging tiedown systems overview at Portsmouth Gaseous Diffusion Plant, Piketon, Ohio

    SciTech Connect (OSTI)

    Becker, D.L.; Lindquist, M.R.

    1993-03-01

    The Portsmouth Gaseous Diffusion Plant (PORTS) in Piketon, Ohio operated by Martin Marietta Energy Systems, Inc., through the US Department of Energy-Oak Ridge Operations Office (DOE-ORO) for the US Department of Energy Headquarters, Office of Nuclear Energy. The PORTS conducts those operations that are necessary for the production, packaging, and shipment of enriched uranium hexafluoride (UF{sub 6}). Uranium hexafluoride enriched greater than 1.0 wt percent {sup 235}U shall be packaged in accordance with the US Department of Transportation (DOT) regulations of Title 49 CFR Parts 173 (Reference 1) and 178 (Reference 2), or in US Nuclear Regulatory Commission (NRC) or US Department of Energy (DOE) certified package designs. Concerns have been expressed regarding the various tiedown methods and condition of the trailers being used by some shippers/carriers for international transport of the UF{sub 6} cylinders/overpacks (Reference 3). Because of the concerns about international shipments, the US Department of Energy-Headquarters (DOE-HQ) Office of Nuclear Energy, through DOE-HQ Transportation Management Division, requested Westinghouse Hanford Company (Westinghouse Hanford) to review UF{sub 6} packaging tiedown and shipping practices used by PORTS, and where possible and appropriate, provide recommendations for enhancing these practices. Consequently, a tram of two individuals from Westinghouse Hanford visited PORTS on March 5 and 6, 1990, for the purpose of conducting this review. The paper provides a brief discussion of the review activities and a summary of the resulting findings and recommendations. A detailed reporting of the review is documented in Reference 4.

  8. Evaluation of aqueous degreasers versus chlorinated solvents at the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Gunn, D.

    1988-10-31

    Spent chlorinated solvents are produced mainly as a result of degreasing operations at several Paducah Gaseous Diffusion Plant (PGDP) locations. This waste is a listed hazardous waste under Resource Conservation and Recovery Act (RCRA) regulations (40 CFR 261). In addition, some of the solvents become contaminated with uranium which classifies the waste as a mixed waste for which no disposal method is currently available. Due to health and environmental concerns and the desire to minimize mixed and hazardous waste generation, degreasing operations in the plant were delineated and alternate nonhazardous solvents were evaluated for their suitability for replacing the chlorinated solvents. Metal cleanliness testing of eight aqueous degreasers using ultrasonic cleaning and immersion with agitation, and vapor degreasing with trichloroethylene (TCE) and 1,1,1-trichloroethane (TC-ane) was performed. Soils such as dust, fingerprints, lube oil, water-soluble oil, silicone grease, and petroleum-based grease were removed from Monel, copper, mild steel, aluminum, and phosphor bronze. Cleanliness was determined by estimating the surface energy of metal coupons before and after cleaning. A Kepner-Tregoe (KT) decision analysis was utilized to determine the three best multipurpose degreasers for the plant. Additional testing was performed on the top three selected degreasers to evaluate corrosive effects of the cleaning solutions (general surface corrosion and pitting), and to determine the compatability of any residual contamination with process gases. Corrosion testing was performed in an electrochemical corrosion tester. Cleaned coupons were exposed to uranium hexafluoride, fluorine, and chlorine trifluoride. In addition, metal cleanliness testing was conducted to evaluate the cleaning efficiency of parts cleaned in the field.

  9. Ground penetrating radar surveys over an alluvial DNAPL site, Paducah Gaseous Diffusion Plant, Kentucky

    SciTech Connect (OSTI)

    Carpenter, P.J. [Northern Illinois Univ., DeKalb, IL (United States). Dept. of Geology]|[Oak Ridge National Lab., TN (United States); Doll, W.E. [Oak Ridge National Lab., TN (United States); Phillips, B.E. [Paducah Gaseous Diffusion Plant, KY (United States)

    1994-09-01

    Ground penetrating radar (GPR) surveys were used to map shallow sands and gravels which are DNAPL migration pathways at the Paducah Gaseous Diffusion Plant in western Kentucky. The sands and gravels occur as paleochannel deposits, at depths of 17-25 ft, embedded in Pleistocene lacustrine clays. More than 30 GPR profiles were completed over the Drop Test Area (DTA) to map the top and base of the paleochannel deposits, and to assess their lateral continuity. A bistatic radar system was used with antenna frequencies of 25 and 50 MHz. An average velocity of 0.25 ft/ns for silty and clayey materials above the paleochannel deposits was established from radar walkaway tests, profiles over culverts of known depth, and comparison of radar sections with borings. In the south portion of the DTA, strong reflections corresponded to the water table at approximately 9-10 ft, the top of the paleochannel deposits at approximately 18 ft, and to gravel horizons within these deposits. The base of these deposits was not visible on the radar sections. Depth estimates for the top of the paleochannel deposits (from 50 records) were accurate to within 2 ft across the southern portion of the DTA. Continuity of these sands and gravels could not be assessed due to interference from air-wave reflections and lateral changes in signal penetration depth. However, the sands and gravels appear to extend across the entire southern portion of the DTA, at depths as shallow as 17 ft. Ringing, air-wave reflections and diffractions from powerlines, vehicles, well casings, and metal equipment severly degraded GPR profiles in the northern portion of the DTA; depths computed from reflection times (where visible) were accurate to within 4 ft in this area. The paleochannel deposits are deeper to the north and northeast where DNAPL has apparently pooled (DNAPL was not directly imaged by the GPR, however). Existing hydrogeological models of the DTA will be revised.

  10. Inorganic soil and groundwater chemistry near Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    Moore, G.K. [Tennessee Univ., Knoxville, TN (United States)

    1995-03-01

    Near-surface soils, boreholes, and sediments near the Paducah Gaseous Diffusion Plant (PGDP) were sampled in 1989-91 as were monitoring wells, TVA wells, and privately-owned wells. Most wells were sampled two or three times. The resulting chemical analyses have been published in previous reports and have been previously described (CH2M HILL 1991, 1992; Clausen et al. 1992). The two reports by CH2M HILL are controversial, however, because, the concentrations of some constituents were reported to exceed background levels or drinking water standards and because both on-site (within the perimeter fence at PGDP) and off-site pollution was reported to have occurred. The groundwater samples upon which these interpretations were based may not be representative, however. The CH2M HILL findings are discussed in the report. The purpose of this report is to characterize the inorganic chemistry of groundwater and soils near PGDP, using data from the CH2M HILL reports (1991, 1992), and to determine whether or not any contamination has occurred. The scope is limited to analysis and interpretation of data in the CH2M HILL reports because previous interpretations of these data may not be valid, because samples were collected in a relatively short period of time at several hundred locations, and because the chemical analyses are nearly complete. Recent water samples from the same wells were not considered because the characterization of inorganic chemistry for groundwater and soil requirements only one representative sample and an accurate analysis from each location.

  11. Proposed sale of radioactively contaminated nickel ingots located at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    NONE

    1995-10-01

    The U.S. Department of Energy (DOE) proposes to sell 8,500 radioactively contaminated nickel ingots (9.350 short tons), currently in open storage at the Paducah Gaseous Diffusion Plant (PGDP), to Scientific Ecology Group, Inc. (SEG) for decontamination and resale on the international market. SEG would take ownership of the ingots when they are loaded for transport by truck to its facility in Oak Ridge, Tennessee. SEG would receive approximately 200 short tons per month over approximately 48 months (an average of 180 ingots per month). The nickel decontamination process specified in SEG`s technical proposal is considered the best available technology and has been demonstrated in prototype at SEG. The resultant metal for resale would have contamination levels between 0.3 and 20 becquerel per gram (Bq/g). The health hazards associated with release of the decontaminated nickel are minimal. The activity concentration of the end product would be further reduced when the nickel is combined with other metals to make stainless steel. Low-level radioactive waste from the SEG decontamination process, estimated to be approximately 382 m{sup 3} (12,730 ft), would be shipped to a licensed commercial or DOE disposal facility. If the waste were packaged in 0.23 m{sup 3}-(7.5 ft{sup 3}-) capacity drums, approximately 1,500 to 1,900 drums would be transported over the 48-month contract period. Impacts from the construction of decontamination facilities and the selected site are minimal.

  12. Uranium hexafluoride packaging tiedown systems overview at Portsmouth Gaseous Diffusion Plant, Piketon, Ohio. Revision 1

    SciTech Connect (OSTI)

    Becker, D.L.; Green, D.J.; Lindquist, M.R.

    1993-07-01

    The Portsmouth Gaseous Diffusion Plant (PORTS) in Piketon, Ohio, is operated by Martin Marietta Energy Systems, Inc., through the US Department of Energy-Oak Ridge Operations Office (DOE-ORO) for the US Department of Energy-Headquarters, Office of Nuclear Energy. The PORTS conducts those operations that are necessary for the production, packaging, and shipment of uranium hexafluoride (UF{sub 6}). Uranium hexafluoride enriched uranium than 1.0 wt percent {sup 235}U shall be packaged in accordance with the US Department of Transportation (DOT) regulations of Title 49 CFR Parts 173 (Reference 1) and 178 (Reference 2), or in US Nuclear Regulatory Commission (NRC) or US Department of Energy (DOE) certified package designs. Concerns have been expressed regarding the various tiedown methods and condition of the trailers being used by some shippers/carriers for international transport of the UF{sub 6} cylinders/overpacks. Because of the concerns about international shipments, the US Department of Energy-Headquarters (DOE-HQ) Office of Nuclear Energy, through DOE-HQ Transportation Management Division, requested Westinghouse Hanford Company (Westinghouse Hanford) to review UF{sub 6} packaging tiedown and shipping practices used by PORTS, and where possible and appropriate, provide recommendations for enhancing these practices. Consequently, a team of two individuals from Westinghouse Hanford visited PORTS on March 5 and 6, 1990, for the purpose of conducting this review. The paper provides a brief discussion of the review activities and a summary of the resulting findings and recommendations. A detailed reporting of the is documented in Reference 4.

  13. Safeguards Verification Measurements using Laser Ablation, Absorbance Ratio Spectrometry in Gaseous Centrifuge Enrichment Plants

    SciTech Connect (OSTI)

    Anheier, Norman C.; Cannon, Bret D.; Qiao, Hong; Phillips, Jon R.

    2012-07-01

    Laser Ablation Absorbance Ratio Spectrometry (LAARS) is a new verification measurement technology under development at the US Department of Energy’s (DOE) Pacific Northwest National Laboratory (PNNL). LAARS uses three lasers to ablate and then measure the relative isotopic abundance of uranium compounds. An ablation laser is tightly focused on uranium-bearing solids producing a small plume containing uranium atoms. Two collinear wavelength-tuned spectrometry lasers transit through the plume and the absorbance of U-235 and U-238 isotopes are measured to determine U-235 enrichment. The measurement has high relative precision and detection limits approaching the femtogram range for uranium. It is independent of chemical form and degree of dilution with nuisance dust and other materials. High speed sample scanning and pinpoint characterization allow measurements on millions of particles/hour to detect and analyze the enrichment of trace uranium in samples. The spectrometer is assembled using commercially available components at comparatively low cost, and features a compact and low power design. Future designs can be engineered for reliable, autonomous deployment within an industrial plant environment. Two specific applications of the spectrometer are under development: 1) automated unattended aerosol sampling and analysis and 2) on-site small sample destructive assay measurement. The two applications propose game-changing technological advances in gaseous centrifuge enrichment plant (GCEP) safeguards verification. The aerosol measurement instrument, LAARS-environmental sampling (ES), collects aerosol particles from the plant environment in a purpose-built rotating drum impactor and then uses LAARS-ES to quickly scan the surface of the impactor to measure the enrichments of the captured particles. The current approach to plant misuse detection involves swipe sampling and offsite analysis. Though this approach is very robust it generally requires several months to obtain results from a given sample collection. The destructive assay instrument, LAARS-destructive assay (DA), uses a simple purpose-built fixture with a sampling planchet to collect adsorbed UF6 gas from a cylinder valve or from a process line tap or pigtail. A portable LAARS-DA instrument scans the microgram quantity of uranium collected on the planchet and the assay of the uranium is measured to ~0.15% relative precision. Currently, destructive assay samples for bias defect measurements are collected in small sample cylinders for offsite mass spectrometry measurement.

  14. Design of an Unattended Environmental Aerosol Sampling and Analysis System for Gaseous Centrifuge Enrichment Plants

    SciTech Connect (OSTI)

    Anheier, Norman C.; Munley, John T.; Alexander, M. L.

    2011-07-19

    The resources of the IAEA continue to be challenged by the rapid, worldwide expansion of nuclear energy production. Gaseous centrifuge enrichment plants (GCEPs) represent an especially formidable dilemma to the application of safeguard measures, as the size and enrichment capacity of GCEPs continue to escalate. During the early part of the 1990's, the IAEA began to lay the foundation to strengthen and make cost-effective its future safeguard regime. Measures under Part II of 'Programme 93+2' specifically sanctioned access to nuclear fuel production facilities and environmental sampling by IAEA inspectors. Today, the Additional Protocol grants inspection and environmental sample collection authority to IAEA inspectors at GCEPs during announced and low frequency unannounced (LFUA) inspections. During inspections, IAEA inspectors collect environmental swipe samples that are then shipped offsite to an analytical laboratory for enrichment assay. This approach has proven to be an effective deterrence to GCEP misuse, but this method has never achieved the timeliness of detection goals set forth by IAEA. Furthermore it is questionable whether the IAEA will have the resources to even maintain pace with the expansive production capacity of the modern GCEP, let alone improve the timeliness in reaching current safeguards conclusions. New safeguards propositions, outside of familiar mainstream safeguard measures, may therefore be required that counteract the changing landscape of nuclear energy fuel production. A new concept is proposed that offers rapid, cost effective GCEP misuse detection, without increasing LFUA inspection access or introducing intrusive access demands on GCEP operations. Our approach is based on continuous onsite aerosol collection and laser enrichment analysis. This approach mitigates many of the constraints imposed by the LFUA protocol, reduces the demand for onsite sample collection and offsite analysis, and overcomes current limitations associated with the in-facility misuse detection devices. Onsite environmental sample collection offers the ability to collect fleeting uranium hexafluoride emissions before they are lost to the ventilation system or before they disperse throughout the facility, to become deposited onto surfaces that are contaminated with background and historical production material. Onsite aerosol sample collection, combined with enrichment analysis, provides the unique ability to quickly detect stepwise enrichment level changes within the facility, leading to a significant strengthening of facility misuse deterence. We report in this paper our study of several GCEP environmental sample release scenarios and simulation results of a newly designed aerosol collection and particle capture system that is fully integrated with the Laser Ablation, Absorbance Ratio Spectrometry (LAARS) uranium particle enrichment analysis instrument that was developed at the Pacific Northwest National Laboratory.

  15. Gaseous fission product management for molten salt reactors and vented fuel systems

    SciTech Connect (OSTI)

    Messenger, S. J.; Forsberg, C.; Massie, M.

    2012-07-01

    Fission gas disposal is one of the unresolved difficulties for Molten Salt Reactors (MSRs) and advanced reactors with vented fuel systems. As these systems operate, they produce many radioactive isotopes of xenon and krypton (e.g. {sup 135}Xe t{sub 1/2} = 9.14 hours and {sup 85}Kr t{sub 1/2}= 10.73 years). Removing these gases proves vital to the success of such reactor designs for two reasons. First, the gases act as large neutron sinks which decrease reactivity and must be counterbalanced by increasing fuel loading. Second, for MSRs, inert fission product gases naturally separate quickly from high temperature salts, thus creating high vapor pressure which poses safety concerns. For advanced reactors with solid vented fuel, the gases are allowed to escape into an off-gas system and thus must be managed. Because of time delays in transport of fission product gases in vented fuel systems, some of the shorter-lived radionuclides will decay away thereby reducing the fission gas source term relative to an MSR. To calculate the fission gas source term of a typical molten salt reactor, we modeled a 1000 MWe graphite moderated thorium MSR similar to that detailed in Mathieu et al. [1]. The fuel salt used in these calculations was LiF (78 mole percent) - (HN)F 4 (22 mole percent) with a heavy nuclide composition of 3.86% {sup 233}U and 96.14% {sup 232}Th by mass. Before we can remove the fission product gases produced by this reactor configuration, we must first develop an appropriate storage mechanism. The gases could be stored in pressurized containers but then one must be concerned about bottle failure. Methods to trap noble gases in matrices are expensive and complex. Alternatively, there are direct storage/disposal options: direct injection into the Earth or injecting a grout-based product into the Earth. Advances in drilling technologies, hydro fracture technologies, and methods for the sequestration of carbon dioxide from fossil fuel plants are creating new options for disposal of fission gas wastes. In each option, lithostatic pressure, a kilometer or more underground, eliminates the pressure driving force for noble gas release and dissolves any untrapped gas in deep groundwater or into incorporated solid waste forms. The options, challenges, and potential for these methods to dispose of gaseous fission products are described. With this research, we hope to help both MSRs and other advanced reactors come one step closer to commercialization. (authors)

  16. Method of preparing and utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream

    DOE Patents [OSTI]

    Berry, David A; Shekhawat, Dushyant; Smith, Mark; Haynes, Daniel

    2013-07-16

    The disclosure relates to a method of utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream with a mitigation of carbon accumulation. The system is comprised of a catalytically active phase deposited onto an oxygen conducting phase, with or without supplemental support. The catalytically active phase has a specified crystal structure where at least one catalytically active metal is a cation within the crystal structure and coordinated with oxygen atoms within the crystal structure. The catalyst system employs an optimum coverage ratio for a given set of oxidation conditions, based on a specified hydrocarbon conversion and a carbon deposition limit. Specific embodiments of the catalyst system are disclosed.

  17. Health risk from earthquake caused releases of UF{sub 6} at the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Brown, N.W; Lu, S.; Chen, J.C.; Roehnelt, R.; Lombardi, D.

    1998-05-01

    The health risk to the public and workers from potential exposure to the toxic materials from earthquake caused releases of uranium hexafluoride from the Paducah gaseous Diffusion Plant are evaluated. The results of the study show that the health risk from earthquake caused releases is small, and probably less than risks associated with the transportation of hydrogen fluoride and other similar chemicals used by industry. The probability of more than 30 people experiencing health consequences (injuries) from earthquake damage is less than 4xlO{sup 4}/yr.

  18. Superfund record of decision (EPA Region 4): Paducah Gaseous Diffusion Plant, Northwest Plume, Paducah, KY, July 1993

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    This decision document presents the selected remedial action for the Northwest Plume at the Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky. The primary objective of this interim remedial action is to initiate a first phase remedial action, as an interim action to initiate control of the source and mitigate the spread of contamination in the Northwest plume. This operable unit addresses a portion of the contaminated ground water. Additional interim actions associated with this integrator operable unit are being considered, as well as for other areas of contaminated ground water.

  19. Superfund record of decision (EPA Region 4): Paducah Gaseous Diffusion Plant (USDOE), Operable Unit 15, Paducah, KY, August 10, 1998

    SciTech Connect (OSTI)

    NONE

    1998-12-01

    This decision document presents the remedial action for the Solid Waste Management Unit (SWMU) 91 of the Waste Area Group (WAG) 27 at the Paducah Gaseous Diffusion Plant (PGDP) near Paducah, Kentucky. The primary objective of this remedial action is to reduce the level of TCE-contaminated soil thereby reducing the potential future concentrations in ground water that could pose a threat to human health and the environment at the POE (i.e., the DOE property boundary). The potential for migration of the contamination from the soil of the off-site aquifer is the concern associated with the SWMU.

  20. Pattern recognition techniques to reduce backgrounds in the search for the {sup 136}Xe double beta decay with gaseous TPCs

    SciTech Connect (OSTI)

    Iguaz, F. J.; Cebrián, S.; Dafni, T.; Gómez, H.; Herrera, D. C.; Irastorza, I. G.; Luzon, G.; Segui, L.; Tomas, A. [Laboratorio de Física Nuclear y Astropartículas, Universidad de Zaragoza (Spain)] [Laboratorio de Física Nuclear y Astropartículas, Universidad de Zaragoza (Spain)

    2013-08-08

    The observation of the neutrinoless double beta decay may provide essential information on the nature of neutrinos. Among the current experimental approaches, a high pressure gaseous TPC is an attractive option for the search of double beta decay due to its good energy resolution and the detailed topological information of each event. We present in this talk a detailed study of the ionization topology of the {sup 136}Xe double beta decay events in a High Pressure Xenon TPC, as well as that of the typical competing backgrounds. We define some observables based on graph theory concepts to develop automated discrimination algorithms. Our criteria are able to reduce the background level by about three orders of magnitude in the region of interest of the {sup 136}Xe Q{sub ??} for a signal acceptance of 40%. This result provides a quantitative assessment of the benefit of topological information offered by gaseous TPCs for double beta decay search, and proves that it is a promising feature in view of future experiments in the field. Possible ideas for further improvement in the discrimination algorithms and the dependency of these results with the gas diffusion and readout granularity will be also discussed.

  1. APPLICATION OF THE LASAGNA{trademark} SOIL REMEDIATION TECHNOLOGY AT THE DOE PADUCAH GASEOUS DIFFUSION PLANT

    SciTech Connect (OSTI)

    Swift, Barry D.; Tarantino, Joseph J., P. E.

    2003-02-27

    The Paducah Gaseous Diffusion Plant (PGDP), owned by the Department of Energy (DOE), has been enriching uranium since the early 1950s. The enrichment process involves electrical and mechanical components that require periodic cleaning. The primary cleaning agent was trichloroethene (TCE) until the late 1980s. Historical documentation indicates that a mixture of TCE and dry ice were used at PGDP for testing the integrity of steel cylinders, which stored depleted uranium. TCE and dry ice were contained in a below-ground pit and used during the integrity testing. TCE seeped from the pit and contaminated the surrounding soil. The Lasagna{trademark} technology was identified in the Record of Decision (ROD) as the selected alternative for remediation of the cylinder testing site. A public-private consortium formed in 1992 (including DOE, the U.S. Environmental Protection Agency, and the Kentucky Department for Environmental Protection, Monsanto, DuPont, and General Electric) developed the Lasagna{trademark} technology. This innovative technology employs electrokinetics to remediate soil contaminated with organics and is especially suited to sites with low permeability soils. This technology uses direct current to move water through the soil faster and more uniformly than hydraulic methods. Electrokinetics moves contaminants in soil pore water through treatment zones comprised of iron filings, where the contaminants are decomposed to basic chemical compounds such as ethane. After three years of development in the laboratory, the consortium field tested the Lasagna{trademark} process in several phases. CDM installed and operated Phase I, the trial installation and field test of a 150-square-foot area selected for a 120-day run in 1995. Approximately 98 percent of the TCE was removed. CDM then installed and operated the next phase (IIa), a year-long test on a 600-square-foot site. Completed in July 1997, this test removed 75 percent of the total volume of TCE down to a depth of 45 feet. TCE in the test sites. Based on the successful field tests (Phases I and IIa), the ROD was prepared and the Lasagna{trademark} alternative was selected for remediation of TCE contaminated soils at the cylinder testing site Solid Waste Management Unit 91(SWMU 91). Bechtel Jacobs Company LLC contracted CDM to construct and operate a full-scale Lasagna{trademark} remediation system at the site (Phase IIb). Construction began in August 1999 and the operational phase was initiated in December 1999. The Lasagna{trademark} system was operated for two years and reduced the average concentration of TCE in SWMU 91 soil from 84 ppm to less than 5.6 ppm. Verification sampling was conducted during May, 2002. Results of the verification sampling indicated the average concentration of TCE in SWMU 91 soil was 0.38 ppm with a high concentration of 4.5 ppm.

  2. Gamma radiological surveys of the Oak Ridge Reservation, Paducah Gaseous Diffusion Plant, and Portsmouth Gaseous Diffusion Plant, 1990-1993, and overview of data processing and analysis by the Environmental Restoration Remote Sensing Program, Fiscal Year 1995

    SciTech Connect (OSTI)

    Smyre, J.L.; Moll, B.W.; King, A.L.

    1996-06-01

    Three gamma radiological surveys have been conducted under auspices of the ER Remote Sensing Program: (1) Oak Ridge Reservation (ORR) (1992), (2) Clinch River (1992), and (3) Portsmouth Gaseous Diffusion Plant (PORTS) (1993). In addition, the Remote Sensing Program has acquired the results of earlier surveys at Paducah Gaseous Diffusion Plant (PGDP) (1990) and PORTS (1990). These radiological surveys provide data for characterization and long-term monitoring of U.S. Department of Energy (DOE) contamination areas since many of the radioactive materials processed or handled on the ORR, PGDP, and PORTS are direct gamma radiation emitters or have gamma emitting daughter radionuclides. High resolution airborne gamma radiation surveys require a helicopter outfitted with one or two detector pods, a computer-based data acquisition system, and an accurate navigational positioning system for relating collected data to ground location. Sensors measure the ground-level gamma energy spectrum in the 38 to 3,026 KeV range. Analysis can provide gamma emission strength in counts per second for either gross or total man-made gamma emissions. Gross count gamma radiation includes natural background radiation from terrestrial sources (radionuclides present in small amounts in the earth`s soil and bedrock), from radon gas, and from cosmic rays from outer space as well as radiation from man-made radionuclides. Man-made count gamma data include only the portion of the gross count that can be directly attributed to gamma rays from man-made radionuclides. Interpretation of the gamma energy spectra can make possible the determination of which specific radioisotopes contribute to the observed man-made gamma radiation, either as direct or as indirect (i.e., daughter) gamma energy from specific radionuclides (e.g., cesium-137, cobalt-60, uranium-238).

  3. Apparatus and method for generating continuous wave 16 .mu.m laser radiation using gaseous CF.sub.4

    DOE Patents [OSTI]

    Telle, John M. (Los Alamos, NM)

    1986-01-01

    Apparatus and method for generating continuous wave 16 .mu.m laser radiation using gaseous CF.sub.4. Laser radiation at 16 .mu.m has been observed in a cooled static cell containing low pressure CF.sub.4 optically pumped by an approximately 3 W output power cw CO.sub.2 laser. The laser cavity employed was a multiple-pass off-axis-path two spherical mirror ring resonator. Unidirectional CF.sub.4 laser output power at 615 cm.sup.-1 exceeded 2 mW. Computer calculations indicate that for modest pump powers of about 40 W, approximately 1 W of emitted laser radiation at 16 .mu.m might be obtained.

  4. Utilization of 4-Dimensional Data Visualization Modeling to Evaluate Burial Ground Contaminants at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    Brindley, T. L.; Tarantino, J. J.; Locke, A. L. [CDM, 325 Kentucky Ave., Kevil, Kentucky 42053 (United States); Dollins, D. W. [Department of Energy, Paducah Gaseous Diffusion Plant, Paducah Kentucky 42001 (United States)

    2006-07-01

    This paper describes how 4-Dimensional (4D) Data Visualization Modeling was used to evaluate historical data and to help guide the decisions for the sampling necessary to complete a Remedial Investigation/Feasibility Study (RI/FS) for the burial ground sites at the Department of Energy (DOE) Paducah Gaseous Diffusion Plant (PGDP). DOE at the Paducah Site is primarily involved in environmental cleanup and landlord activities. The scope of this project was to prepare a work plan for identifying the data available and the data required to conduct an RI/FS for the Burial Ground Operable Unit (BGOU) located within and near PGDP. The work plan focuses on collecting existing information about contamination in and around the burial grounds and determining what additional data are required to support an assessment of risks to human health and the environment and to support future decisions regarding actions to reduce these risks. (authors)

  5. An interim report to the manager of the Paducah Gaseous Diffusion Plant from the Paducah Environmental Advisory Committee

    SciTech Connect (OSTI)

    Jackson, G.D.

    1987-10-01

    The Paducah Environmental Advisory Committee was formed as: (1) an outgrowth of other Environmental Advisory Committees already in existence at Oak Ridge and other Martin Marietta Energy Systems plants; (2) a result of public concern following significant nuclear incidents at Bhopal and Chernobyl; (3) a result of the new direction and commitment of the management of the Paducah Gaseous Diffusion Plant following contract acquisition by Martin Marietta Energy Systems; and (4) a means of reducing and/or preventing local and/or public concern regarding the activities of and potential risks created by PGDP. This report discusses the following issues and concerns of the Committee arrived at through a series of meetings: (1) groundwater monitoring; (2) long-range tails storage; C-404, scrap yrads, and PCB and TCE cleanup; nuclear criticality plan and alarm systems; documentation of historical data regarding hazardous waste burial grounds; dosimeter badges; and asbestos handling and removal.

  6. The Mailbox Computer System for the IAEA verification experiment on HEU downlending at the Portsmouth Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Aronson, A.L.; Gordon, D.M.

    2000-07-31

    IN APRIL 1996, THE UNITED STATES (US) ADDED THE PORTSMOUTH GASEOUS DIFFUSION PLANT TO THE LIST OF FACILITIES ELIGIBLE FOR THE APPLICATION OF INTERNATIONAL ATOMIC ENERGY AGENCY (IAEA) SAFEGUARDS. AT THAT TIME, THE US PROPOSED THAT THE IAEA CARRY OUT A ''VERIFICATION EXPERIMENT'' AT THE PLANT WITH RESPECT TO DOOWNBLENDING OF ABOUT 13 METRIC TONS OF HIGHLY ENRICHED URANIUM (HEU) IN THE FORM OF URANIUM HEXAFLUROIDE (UF6). DURING THE PERIOD DECEMBER 1997 THROUGH JULY 1998, THE IAEA CARRIED OUT THE REQUESTED VERIFICATION EXPERIMENT. THE VERIFICATION APPROACH USED FOR THIS EXPERIMENT INCLUDED, AMONG OTHER MEASURES, THE ENTRY OF PROCESS-OPERATIONAL DATA BY THE FACILITY OPERATOR ON A NEAR-REAL-TIME BASIS INTO A ''MAILBOX'' COMPUTER LOCATED WITHIN A TAMPER-INDICATING ENCLOSURE SEALED BY THE IAEA.

  7. Detection of illicit HEU production in gaseous centrifuge enrichment plants using neutron counting techniques on product cylinders

    SciTech Connect (OSTI)

    Freeman, Corey R; Geist, William H

    2010-01-01

    Innovative and novel safeguards approaches are needed for nuclear energy to meet global energy needs without the threat of nuclear weapons proliferation. Part of these efforts will include creating verification techniques that can monitor uranium enrichment facilities for illicit production of highly-enriched uranium (HEU). Passive nondestructive assay (NDA) techniques will be critical in preventing illicit HEU production because NDA offers the possibility of continuous and unattended monitoring capabilities with limited impact on facility operations. Gaseous centrifuge enrichment plants (GCEP) are commonly used to produce low-enriched uranium (LEU) for reactor fuel. In a GCEP, gaseous UF{sub 6} spins at high velocities in centrifuges to separate the molecules containing {sup 238}U from those containing the lighter {sup 235}U. Unfortunately, the process for creating LEU is inherently the same as HEU, creating a proliferation concern. Insuring that GCEPs are producing declared enrichments poses many difficult challenges. In a GCEP, large cascade halls operating thousands of centrifuges work together to enrich the uranium which makes effective monitoring of the cascade hall economically prohibitive and invasive to plant operations. However, the enriched uranium exiting the cascade hall fills product cylinders where the UF{sub 6} gas sublimes and condenses for easier storage and transportation. These product cylinders hold large quantities of enriched uranium, offering a strong signal for NDA measurement. Neutrons have a large penetrability through materials making their use advantageous compared to gamma techniques where the signal is easily attenuated. One proposed technique for detecting HEU production in a GCEP is using neutron coincidence counting at the product cylinder take off stations. This paper discusses findings from Monte Carlo N-Particle eXtended (MCNPX) code simulations that examine the feasibility of such a detector.

  8. International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 Ammonia Emissions from Broiler Houses in Pennsylvania

    E-Print Network [OSTI]

    Kentucky, University of

    International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 1 Ammonia Emissions from Broiler Houses in Pennsylvania During Cold of reducing ammonia (NH3) emissions are under study. Ammonia emissions during cold weather conditions from

  9. International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 AMMONIA EMISSIONS FROM LAYER HOUSES IN IOWA

    E-Print Network [OSTI]

    Kentucky, University of

    International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 1 AMMONIA EMISSIONS FROM LAYER HOUSES IN IOWA Y. Liang1 , H. Xin2 , A. Casey10 ABSTRACT An ongoing project of monitoring ammonia (NH3) emissions from U.S. layer houses

  10. International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 Ammonia Emissions from Broiler Houses in Kentucky during Winter

    E-Print Network [OSTI]

    Kentucky, University of

    International Symposium on Gaseous and Odour Emissions from Animal Production Facilities, Horsens, Jutland, Denmark 1-4 June, 2003 Ammonia Emissions from Broiler Houses in Kentucky during Winter Kenneth D a comprehensive database of ammonia emission rates (ER) from US poultry facilities. The influence of common

  11. Dispersion of UO{sub 2}F{sub 2} aerosol and HF vapor in the operating floor during winter ventilation at the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Kim, S.H.; Chen, N.C.J.; Taleyarkhan, R.P.; Keith, K.D.; Schmidt, R.W. [Oak Ridge National Lab., TN (United States); Carter, J.C. [J.C. Carter Associates, Inc., Knoxville, TN (United States)

    1996-12-30

    The gaseous diffusion process is currently employed at two plants in the US: the Paducah Gaseous Diffusion Plant and the Portsmouth Gaseous Diffusion Plant. As part of a facility-wide safety evaluation, a postulated design basis accident involving large line-rupture induced releases of uranium hexafluoride (UF{sub 6}) into the process building of a gaseous diffusion plant (GDP) is evaluated. When UF{sub 6} is released into the atmosphere, it undergoes an exothermic chemical reaction with moisture (H{sub 2}O) in the air to form vaporized hydrogen fluoride (HF) and aerosolized uranyl fluoride (UO{sub 2}F{sub 2}). These reactants disperse in the process building and transport through the building ventilation system. The ventilation system draws outside air into the process building, distributes it evenly throughout the building, and discharges it to the atmosphere at an elevated temperature. Since air is recirculated from the cell floor area to the operating floor, issues concerning in-building worker safety and evacuation need to be addressed. Therefore, the objective of this study is to evaluate the transport of HF vapor and UO{sub 2}F{sub 2} aerosols throughout the operating floor area following B-line break accident in the cell floor area.

  12. Anaerobic Digestion of Algal Biomass Residues with Nutrient Recycle Microalgae are currently considered as a renewable source of liquid and gaseous biofuels and

    E-Print Network [OSTI]

    Collins, Gary S.

    are currently considered as a renewable source of liquid and gaseous biofuels and a practical technology of the most sustainable and promising of biofuel feedstock, demonstrating particularly high growth rates, and their entrained lipids, can offer several different types of biofuel and bioenergy production options including

  13. PGDP (Paducah Gaseous Diffusion Plant)-UF/sub 6/ handling, sampling, analysis and associated QC/QA and safety related procedures

    SciTech Connect (OSTI)

    Harris, R.L. (comp.)

    1987-05-22

    This document is a compilation of Paducah Gaseous Diffusion Plant procedures on UF/sub 6/ handling, sampling, and analysis, along with associated QC/QA and safety related procedures. It was assembled for transmission by the US Department of Energy to the Korean Advanced Energy Institute as a part of the US-Korea technical exchange program.

  14. Type B Accident Investigation of the August 22, 2000, Injury Resulting From Violent Exothermic Chemical Reaction at the Portsmouth Gaseous Diffusion Plant, X-701B Site

    Broader source: Energy.gov [DOE]

    On August 22, 2000, an accident occurred at the U. S. Department of Energy (DOE) Portsmouth Gaseous Diffusion Plant (PORTS) located in Piketon, Ohio. An employee of the IT Corporation (IT) working on an Environmental Management (EM) Technology Deployment Project received serious burns from a violent chemical reaction.

  15. First results of a large-area cryogenic gaseous photomultiplier coupled to a dual-phase liquid xenon TPC

    E-Print Network [OSTI]

    Arazi, L; Erdal, E; Israelashvili, I; Rappaport, M L; Shchemelinin, S; Vartsky, D; Santos, J M F dos; Breskin, A

    2015-01-01

    We discuss recent advances in the development of cryogenic gaseous photomultipliers (GPM), for possible use in dark matter and other rare-event searches using noble-liquid targets. We present results from a 10 cm diameter GPM coupled to a dual-phase liquid xenon (LXe) TPC, demonstrating - for the first time - the feasibility of recording both primary ("S1") and secondary ("S2") scintillation signals. The detector comprised a triple Thick Gas Electron Multiplier (THGEM) structure with cesium iodide photocathode on the first element; it was shown to operate stably at 180 K with gains above 10^5, providing high single-photon detection efficiency even in the presence of large alpha particle-induced S2 signals comprising thousands of photoelectrons. S1 scintillation signals were recorded with a time resolution of 1.2 ns (RMS). The energy resolution ({\\sigma}/E) for S2 electroluminescence of 5.5 MeV alpha particles was ~9%, which is comparable to that obtained in the XENON100 TPC with PMTs. The results are discusse...

  16. Nuclear criticality safety controls for uranium deposits during D and D at the Oak Ridge Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Haire, M.J.; Jordan, W.C. [Oak Ridge National Lab., TN (United States); Jollay, L.J. III; Dahl, T.L. [Oak Ridge K-25 Site, TN (United States)

    1997-02-01

    The US Department of Energy (DOE) Deputy Assistant Secretary of Energy for Environmental Management has issued a challenge to complete DOE environmental cleanup within a decade. The response for Oak Ridge facilities is in accordance with the DOE ten-year plan which calls for completion of > 95% of environmental management work by the year 2006. This will result in a 99% risk reduction and in a significant savings in base line costs in waste management (legacy waste); remedial action (groundwater, soil, etc.); and decontamination and decommissioning (D and D). It is assumed that there will be long-term institutional control of cascade equipment, i.e., there will be no walk away from sites, and that there will be firm radioactivity release limits by 1999 for recycle metals. An integral part of these plants is the removal of uranium deposits which pose nuclear criticality safety concerns in the shut down of the Oak Ridge Gaseous Diffusion Plant. DOE has initiated the Nuclear Criticality Stabilization Program to improve nuclear criticality safety by removing the larger uranium deposits from unfavorable geometry equipment. Nondestructive assay (NDA) measurements have identified the location of these deposits. The objective of the K-25 Site Nuclear Criticality Stabilization Program is to remove and place uranium deposits into safe geometry storage containers to meet the double contingency principle. Each step of the removal process results in safer conditions where multiple controls are present. Upon completion of the Program, nuclear criticality risks will be greatly reduced.

  17. Source term evaluation for UF{sub 6} release event in feed facility at gaseous diffusion plants

    SciTech Connect (OSTI)

    Kim, S.H.; Taleyarkhan, R.P.

    1997-01-30

    An assessment of UF{sub 6} release accidents was conducted for the feed facility of a gaseous diffusion plant (GDP). Release rates from pig-tail connections were estimated from CYLIND code predictions, whereas, MELCOR was utilized for simulating reactions of UF{sub 6} with moisture and consequent transport of UO{sub 2}F{sub 2} aerosols and HF vapor through the building and to the environment. Two wind speeds were utilized. At the high end (Case 1) a wind speed of {approximately} 1 m/s (200 fpm) was assumed to flow parallel to the building length. At the low end (Case 2) to represent stagnant conditions a corresponding wind speed of 1 cm/s (2 fpm) was utilized. A further conservative assumption was made to specify no closure of crane and train doors at either end of the building. Relaxation of this assumption should provide for additional margins. Results indicated that, for the high (200 fpm) wind speed, close to 66% of the UO{sub 2}F{sub 2} aerosols and 100% of the HF gas get released to the environment over a 10-minute period. However, for the low (2 fpm) wind speed, negligible amount ({approximately} 1% UO{sub 2}F{sub 2}) of aerosols get released even over a 2 hour period.

  18. Prediction of external corrosion for steel cylinders at the Paducah Gaseous Diffusion Plant: Application of an empirical method

    SciTech Connect (OSTI)

    Lyon, B.F.

    1996-02-01

    During the summer of 1995, ultrasonic wall thickness data were collected for 100 steel cylinders containing depleted uranium (DU) hexafluoride located at Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky. The cylinders were selected for measurement to assess the condition of the more vulnerable portion of the cylinder inventory at PGDP. The purpose of this report is to apply the method used in Lyon to estimate the effects of corrosion for larger unsampled populations as a function of time. The scope of this report is limited and is not intended to represent the final analyses of available data. Future efforts will include continuing analyses of available data to investigate defensible deviations from the conservative assumptions made to date. For each cylinder population considered, two basic types of analyses were conducted: (1) estimates were made of the number of cylinders as a function of time that will have a minimum wall thickness of either 0 mils (1 mil = 0.00 1 in.) or 250 mils and (2) the current minimum wall thickness distributions across cylinders were estimated for each cylinder population considered. Additional analyses were also performed investigating comparisons of the results for F and G yards with the results presented in Lyon (1995).

  19. Superfund record of decision (EPA Region 4): Paducah Gaseous Diffusion Plant (USDOE) Operable Unit 5, Paducah, KY, August 10, 1998

    SciTech Connect (OSTI)

    NONE

    1998-12-01

    This Record of Decision (ROD) presents the final remedial action decisions selected for soils and sediments in each of the solid waste management units (SWMUs) of Waste Area Groups (WAGs) 1 and 7 at the Paducah Gaseous Diffusion Plant (PGDP) near Paducah, Kentucky. Waste Area Group 1 consists of SWMUs 100 and 136. Waste Area Group 7 consists of SWMUs 8 and 130 through 134. By mutual consent among the United States Environmental Protection Agency (EPA), the Kentucky Department for Environmental Protection (KDEP), the United States Department of Defense (DOD), the United States Army Corps of Engineers (COE), and the DOE, it was agreed that the evaluation and implementation of any remedial actions required for the Kentucky Ordnance Works (KOW) SWMUs (SWMU 94 (KOW Sewage Treatment Plant), SWMU 95 (KOW Burn Area), and SWMU 157 (KOW Toluene Spill Site)), formerly included in WAGs 1 and 7, would be the responsibility of the DOD and conducted on behalf of the DOD by the COE. Due to the agreements reached among these entities, remedial technologies for the KOW SWMUs are not discussed further in this ROD and will be evaluated as part of the WAG 10 investigation by the COE. Additionally, by written mutual consent, the EPA, the DKEP, and the DOE agreed that an evaluation of remedial alternatives for SWMU 38, the C-615 Sewage Treatment Plant, would be deferred until the unit ceases operation. Consequently, no remedial actions are discussed for these SWMUs in this ROD.

  20. Effect of long duration UV irradiation on diamondlike carbon surfaces in the presence of a hydrocarbon gaseous atmosphere

    SciTech Connect (OSTI)

    Riedo, A.; Wahlstroem, P.; Scheer, J. A.; Wurz, P.; Tulej, M.

    2010-12-01

    Measurements of the effect of long duration UV irradiation (up to 2905 min) of flight quality diamondlike carbon charge state conversion surfaces for application in space research in the presence of a hydrocarbon atmosphere were done. An isopropanol atmosphere was used for simulating the hydrocarbon gaseous environment for an instrument on a satellite in space. Charge state conversion surfaces are used in neutral particle sensing instruments where neutral atoms have to be ionized prior to the analysis. A narrow-band (126{+-}5 nm) discharge lamp and a broad-band deuterium lamp (112-370 nm) were used as sources of UV radiation. The UV irradiation of a surface results in the desorption of some volatiles present on the surface and the decomposition of others. Desorption of volatiles, mostly water, is observed for both UV sources. The decomposition of the hydrocarbons and the subsequent build-up of a hydrocarbonaceous layer is only observed for the broad-band UV lamp, which is more representative for the space environment. Unfortunately, the hydrocarbonaceous layer cannot be removed thermally, i.e., it is permanent, and causes a degradation of the performance of the charge state conversion surfaces. With the present measurements we can quantify the UV influence at which the degradation of the conversion surfaces becomes noticeable.

  1. Measurement of scintillation and ionization yield with high-pressure gaseous mixtures of Xe and TMA for improved neutrinoless double beta decay and dark matter searches

    E-Print Network [OSTI]

    Nakajima, Y; Matis, H S; Nygren, D; Oliveira, C; Renner, J

    2015-01-01

    Liquid Xe TPCs are among the most popular choices for double beta decay and WIMP dark matter searches. Gaseous Xe has intrinsic advantages when compared to Liquid Xe, specifically, tracking capability and better energy resolution for double beta decay searches. The performance of gaseous Xe can be further improved by molecular additives such as trimethylamine(TMA), which are expected to (1) cool down the ionization electrons, (2) convert Xe excitation energy to TMA ionizations through Penning transfer, and (3) produce scintillation and electroluminescence light in a more easily detectable wavelength (300 nm). These features may provide better tracking and energy resolution for double-beta decay searches. They are also expected to enhance columnar recombination for nuclear recoils, which can be used for searches for WIMP dark matter with directional sensitivity. We constructed a test ionization chamber and successfully measured scintillation and ionization yields at high precision with various Xe and TMA mixtu...

  2. Unattended Monitoring of HEU Production in Gaseous Centrifuge Enrichment Plants using Automated Aerosol Collection and Laser-based Enrichment Assay

    SciTech Connect (OSTI)

    Anheier, Norman C.; Bushaw, Bruce A.

    2010-08-11

    Nuclear power is enjoying rapid growth as government energy policies and public demand shift toward low carbon energy production. Pivotal to the global nuclear power renaissance is the development and deployment of robust safeguards instrumentation that allows the limited resources of the IAEA to keep pace with the expansion of the nuclear fuel cycle. Undeclared production of highly enriched uranium (HEU) remains a primary proliferation concern for modern gaseous centrifuge enrichment plants (GCEPs), due to their massive separative work unit (SWU) processing power and comparably short cascade equilibrium timescale. The Pacific Northwest National Laboratory is developing an unattended safeguards instrument, combining continuous aerosol particulate collection with uranium isotope assay, to provide timely detection of HEU production within a GCEP. This approach is based on laser vaporization of aerosol particulates, followed by laser spectroscopy to characterize the uranium enrichment level. Our prior investigation demonstrated single-shot detection sensitivity approaching the femtogram range and relative isotope ratio uncertainty better than 10% using gadolinium as a surrogate for uranium. In this paper we present measurement results on standard samples containing traces of depleted, natural, and low enriched uranium, as well as measurements on aerodynamic size uranium particles mixed in background materials (e.g., dust, minerals, soils). Improvements and optimizations in the detection electronics, signal timing, calibration, and laser alignment have lead to significant improvements in detection sensitivity and enrichment accuracy, contributing to an overall reduction in the false alarm probability. The sample substrate media was also found to play a significant role in facilitating laser-induced vaporization and the production of energetic plasma conditions, resulting in ablation optimization and further improvements in the isotope abundance sensitivity.

  3. Photo-oxidation of gaseous ethanol on photocatalyst prepared by acid leaching of titanium oxide/hydroxyapatite composite

    SciTech Connect (OSTI)

    Ono, Y.; Rachi, T.; Yokouchi, M.; Kamimoto, Y.; Nakajima, A.; Okada, K.

    2013-06-01

    Highlights: ? Photocatalyst powder was prepared by acid leaching of TiO{sub 2}/apatite composite. ? The photocatalytic activity was evaluated from in situ FT-IR study using ethanol. ? Apatite in the composite had positive effect for the photo-oxidation of ethanol. ? The enhanced oxidation rate was explained by the difference in deactivation rate. - Abstract: Highly active photocatalysts were synthesized by leaching of heat-treated titanium dioxide (TiO{sub 2})/hydroxyapatite (HAp) powder with hydrochloric acid at 0.25, 0.50, 0.75 mol/l, and their photocatalytic activities were evaluated from in situ Fourier transform infrared (FT-IR) study of photo-oxidation of gaseous ethanol. By changing the acid concentration, the TiO{sub 2}/HAp composite had different atomic ratios of Ca/Ti (0.0–2.8) and P/Ti (0.3–2.1). It was found that phosphate group remained on the surface of TiO{sub 2} particle even in the sample treated with concentrated acid (0.75 mol/l). These acid-treated samples showed higher rates for ethanol photo-oxidation than the commercial TiO{sub 2} powder, Degussa P25. The highest rate was obtained in the TiO{sub 2}/HAp composite treated with the dilute (0.25 mol/l) acid in spite of its low content of TiO{sub 2} photocatalyst. This enhanced photocatalytic activity was attributed to the result that the deactivation with repeated injections of ethanol gas was suppressed in the TiO{sub 2}/HAp composites compared with the TiO{sub 2} powders.

  4. Gaseous dark matter detectors

    E-Print Network [OSTI]

    Martoff, C. J.

    Dark matter (DM) detectors with directional sensitivity have the potential of yielding an unambiguous positive observation of WIMPs as well as discriminating between galactic DM halo models. In this paper, we introduce the ...

  5. Engineering Overview of Gaseous

    E-Print Network [OSTI]

    Siefert, Chris

    .S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. 4.9999% pure hydrogen 11 #12;Safe operations using engineering controls · ASME rated vessel BPVC Sect VIII, Div components. 12 #12;Safe operations during setup and test using administrative controls · Education, training

  6. Gaseous leak detector

    DOE Patents [OSTI]

    Juravic, Jr., Frank E. (Aurora, IL)

    1988-01-01

    In a short path length mass-spectrometer type of helium leak detector wherein the helium trace gas is ionized, accelerated and deflected onto a particle counter, an arrangement is provided for converting the detector to neon leak detection. The magnetic field of the deflection system is lowered so as to bring the non linear fringe area of the magnetic field across the ion path, thereby increasing the amount of deflection of the heavier neon ions.

  7. Improved gaseous leak detector

    DOE Patents [OSTI]

    Juravic, F.E. Jr.

    1983-10-06

    In a short path length mass-spectrometer type of helium leak detector wherein the helium trace gas is ionized, accelerated and deflected onto a particle counter, an arrangement is provided for converting the detector to neon leak detection. The magnetic field of the deflection system is lowered so as to bring the nonlinear fringe area of the magnetic field across the ion path, thereby increasing the amount of deflection of the heavier neon ions.

  8. Fiber Bulk Gaseous Carriers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015Executive Order14,Energy 9, 2013Federal TaxMAYDon Baldwin, Director

  9. Environmental site description for a Uranium Atomic Vapor Laser Isotope Separation (U-AVLIS) production plant at the Portsmouth Gaseous Diffusion Plant site

    SciTech Connect (OSTI)

    Marmer, G.J.; Dunn, C.P.; Filley, T.H.; Moeller, K.L.; Pfingston, J.M.; Policastro, A.J.; Cleland, J.H.

    1991-09-01

    Uranium enrichment in the United States has utilized a diffusion process to preferentially enrich the U-235 isotope in the uranium product. In the 1970s, the US Department of Energy (DOE) began investigating more efficient and cost-effective enrichment technologies. In January 1990, the Secretary of Energy approved a plan for the demonstration and deployment of the Uranium Atomic Vapor Laser isotope Separation (U-AVLIS) technology with the near-term goal to provide the necessary information to make a deployment decision by November 1992. Initial facility operation is anticipated for 1999. A programmatic document for use in screening DOE sites to locate a U-AVLIS production plant was developed and implemented in two parts. The first part consisted of a series of screening analyses, based on exclusionary and other criteria, that identified a reasonable number of candidate sites. The final evaluation, which included sensitivity studies, identified the Oak Ridge Gaseous Diffusion Plant (ORGDP) site, the Paducah Gaseous Diffusion Plant (PGDP) site, and the Portsmouth Gaseous Diffusion Plant (PORTS) site as having significant advantages over the other sites considered. This environmental site description (ESD) provides a detailed description of the PORTS site and vicinity suitable for use in an environmental impact statement (EIS). This report is based on existing literature, data collected at the site, and information collected by Argonne National Laboratory (ANL) staff during site visits. The organization of the ESD is as follows. Topics addressed in Sec. 2 include a general site description and the disciplines of geology, water resources, biotic resources, air resources, noise, cultural resources, land use. Socioeconomics, and waste management. Identification of any additional data that would be required for an EIS is presented in Sec. 3.

  10. Source term evaluation for postulated UF{sub 6} release accidents in gaseous diffusion plants -- Summer ventilation mode (non-seismic cases)

    SciTech Connect (OSTI)

    Kim, S.H.; Chen, N.C.J.; Taleyarkhan, R.P.; Wendel, M.W.; Keith, K.D.; Schmidt, R.W. [Oak Ridge National Lab., TN (United States); Carter, J.C. [J.C. Carter Associates, Inc., Knoxville, TN (United States); Dyer, R.H. [Dyer Enterprises, Harriman, TN (United States)

    1996-12-30

    Computer models have been developed to simulate the transient behavior of aerosols and vapors as a result of a postulated accident involving the release of uranium hexafluoride (UF{sub 6}) into the process building of a gaseous diffusion plant. For the current study, gaseous UF{sub 6} is assumed to get released in the cell housing atmosphere through B-line break at 58.97 kg/s for 10 min and 30 min duration at the Paducah and Portsmouth Gaseous Diffusion Plants. The released UF{sub 6} undergoes an exothermic chemical reaction with moisture (H{sub 2}O) in the air to form hydrogen fluoride (HF) and radioactive uranyl fluoride (UO{sub 2}F{sub 2}) while it disperses throughout the process building. As part of a facility-wide safety evaluation, this study evaluated source terms consisting of UO{sub 2}F{sub 2} as well as HF during a postulated UF{sub 6} release accident in a process building. UO{sub 2}F{sub 2} mainly remains as airborne-solid particles (aerosols), and HF is in a vapor form. Some UO{sub 2}F{sub 2} aerosols are removed from the air flow due to gravitational settling. The HF and the remaining UO{sub 2}F{sub 2} are mixed with air and exhausted through the building ventilation system. The MELCOR computer code was selected for simulating aerosols and vapor transport in the process building. To characterize leakage flow through the cell housing wall, 3-D CFD tool (CFDS-FLOW3D) was used. About 57% of UO{sub 2}F{sub 2} was predicted to be released into the environment. Since HF was treated as vapor, close to 100% was estimated to get released into the environment.

  11. System and process for capture of H.sub.2S from gaseous process streams and process for regeneration of the capture agent

    DOE Patents [OSTI]

    Heldenbrant, David J; Koech, Phillip K; Rainbolt, James E; Bearden, Mark D; Zheng, Feng

    2014-02-18

    A system and process are disclosed for selective removal and recovery of H.sub.2S from a gaseous volume, e.g., from natural gas. Anhydrous organic, sorbents chemically capture H.sub.2S gas to form hydrosulfide salts. Regeneration of the capture solvent involves addition of an anti-solvent that releases the captured H.sub.2S gas from the capture sorbent. The capture sorbent and anti-solvent are reactivated for reuse, e.g., by simple distillation.

  12. Photocatalytic degradation of gaseous toluene over TiO{sub 2}-SiO{sub 2} composite nanotubes synthesized by sol-gel with template technique

    SciTech Connect (OSTI)

    Zou, Xuejun [State Key Laboratory of Fine Chemical and Key Laboratory of Industrial Ecology and Environmental Engineering, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian, 116024 (China)] [State Key Laboratory of Fine Chemical and Key Laboratory of Industrial Ecology and Environmental Engineering, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian, 116024 (China); Li, Xinyong, E-mail: xyli@dlut.edu.cn [State Key Laboratory of Fine Chemical and Key Laboratory of Industrial Ecology and Environmental Engineering, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian, 116024 (China) [State Key Laboratory of Fine Chemical and Key Laboratory of Industrial Ecology and Environmental Engineering, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian, 116024 (China); Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia); Qu, Zhenping; Zhao, Qidong; Shi, Yong; Chen, Yongying [State Key Laboratory of Fine Chemical and Key Laboratory of Industrial Ecology and Environmental Engineering, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian, 116024 (China)] [State Key Laboratory of Fine Chemical and Key Laboratory of Industrial Ecology and Environmental Engineering, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian, 116024 (China); Tade, Moses [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia)] [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia); Liu, Shaomin, E-mail: shaomin.liu@curtin.edu.au [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia)] [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia)

    2012-02-15

    Graphical abstract: TiO{sub 2}-SiO{sub 2} nanotubes (b) were fabricated by sol-gel method using ZnO nanowires (a) as template. Highlights: Black-Right-Pointing-Pointer A simple method to prepare TiO{sub 2}-SiO{sub 2} nanotubes for photocatalytic toluene removal. Black-Right-Pointing-Pointer The TiO{sub 2}-SiO{sub 2} nanotubes have a small blue shift and higher absorption intensity. Black-Right-Pointing-Pointer The TiO{sub 2}-SiO{sub 2} nanotubes have an enhanced photoactivity in degrading gaseous toluene. -- Abstract: TiO{sub 2}-SiO{sub 2} composite nanotubes were successfully synthesized by a facile sol-gel technique utilizing ZnO nanowires as template. The nanotubes were well characterized by transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray diffraction, Fourier transform infrared spectroscopy, N{sub 2} adsorption-desorption analysis and UV-vis diffuse reflectance spectroscopy. The nanotubular TiO{sub 2}-SiO{sub 2} composite photocatalysts showed diameter of 300-325 nm, fine mesoporous structure and high specific surface area. The results indicated that the degradation efficiency of gaseous toluene could get 65% after 4 h reaction using the TiO{sub 2}-SiO{sub 2} composite as the photocatalyst under UV light illumination, which was higher than that of P25.

  13. FTIR study of the photocatalytic degradation of gaseous benzene over UV-irradiated TiO{sub 2} nanoballs synthesized by hydrothermal treatment in alkaline solution

    SciTech Connect (OSTI)

    Zhu, Zhengru [Key Laboratory of Industrial Ecology and Environmental Engineering and State Key Laboratory of Fine Chemical, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian 116024 (China)] [Key Laboratory of Industrial Ecology and Environmental Engineering and State Key Laboratory of Fine Chemical, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian 116024 (China); Li, Xinyong, E-mail: xyli@dlut.edu.cn [Key Laboratory of Industrial Ecology and Environmental Engineering and State Key Laboratory of Fine Chemical, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian 116024 (China)] [Key Laboratory of Industrial Ecology and Environmental Engineering and State Key Laboratory of Fine Chemical, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian 116024 (China); Zhao, Qidong; Qu, Zhenping; Hou, Yang; Zhao, Ling [Key Laboratory of Industrial Ecology and Environmental Engineering and State Key Laboratory of Fine Chemical, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian 116024 (China)] [Key Laboratory of Industrial Ecology and Environmental Engineering and State Key Laboratory of Fine Chemical, School of Environmental Sciences and Technology, Dalian University of Technology, Dalian 116024 (China); Liu, Shaomin [Department of Chemical Engineering, Curtin University of Technology, Perth, WA 6845 (Australia)] [Department of Chemical Engineering, Curtin University of Technology, Perth, WA 6845 (Australia); Chen, Guohua [Department of Chemical and Biomolecular Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)] [Department of Chemical and Biomolecular Engineering, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)

    2010-12-15

    In this study, photocatalysts of TiO{sub 2} nanoballs were obtained via a hydrothermal treating of commercial P25 in alkaline solution, and then characterized with SEM, XRD, BET and surface photovoltage spectroscopy techniques. The UV-assisted photodegradation of gaseous benzene over P25 and the prepared TiO{sub 2} nanoballs was monitored by an in situ infrared technique. The results demonstrated that the prepared TiO{sub 2} nanoballs in anatase form were more active than commercial P25 in photocatalytic oxidation of gaseous benzene. The promoted activity of the hydrothermal-treated TiO{sub 2} is attributed to the increasing specific surface area and larger band gap induced by the reduced crystallite size. The spectra of FTIR indicated that weakly adsorbed phenol was formed as the reaction progress. Hydroxyl groups on the surface of TiO{sub 2} nanoballs are able to react with photo-produced phenol, which is then retained on the catalyst surface leading to the progressive deactivation of the catalyst in the gas-solid system.

  14. TECHNICAL EVALUATION OF TEMPORAL GROUNDWATER MONITORING VARIABILITY IN MW66 AND NEARBY WELLS, PADUCAH GASEOUS DIFFUSION PLANT

    SciTech Connect (OSTI)

    Looney, B.; Eddy-Dilek, C.

    2012-08-28

    Evaluation of disposal records, soil data, and spatial/temporal groundwater data from the Paducah Gaseous Diffusion Plant (PGDP) Solid Waste Management Unit (SWMU) 7 indicate that the peak contaminant concentrations measured in monitoring well (MW) 66 result from the influence of the regional PGDP NW Plume, and does not support the presence of significant vertical transport from local contaminant sources in SWMU 7. This updated evaluation supports the 2006 conceptualization which suggested the high and low concentrations in MW66 represent different flow conditions (i.e., local versus regional influences). Incorporation of the additional lines of evidence from data collected since 2006 provide the basis to link high contaminant concentrations in MW66 (peaks) to the regional 'Northwest Plume' and to the upgradient source, specifically, the C400 Building Area. The conceptual model was further refined to demonstrate that groundwater and the various contaminant plumes respond to complex site conditions in predictable ways. This type of conceptualization bounds the expected system behavior and supports development of environmental cleanup strategies, providing a basis to support decisions even if it is not feasible to completely characterize all of the 'complexities' present in the system. We recommend that the site carefully consider the potential impacts to groundwater and contaminant plume migration as they plan and implement onsite production operations, remediation efforts, and reconfiguration activities. For example, this conceptual model suggests that rerouting drainage water, constructing ponds or basin, reconfiguring cooling water systems, capping sites, decommissioning buildings, fixing (or not fixing) water leaks, and other similar actions will potentially have a 'direct' impact on the groundwater contaminant plumes. Our conclusion that the peak concentrations in MW66 are linked to the regional PGDP NW Plume does not imply that there TCE is not present in SWMU 7. The available soil and groundwater data indicate that the some of the waste disposed in this facility contacted and/or were contaminated by TCE. In our assessment, the relatively small amount of TCE associated with SWMU 7 is not contributing detectable TCE to the groundwater and does not represent a significant threat to the environment, particularly in an area where remediation and/or management of TCE in the NW plume will be required for an extended timeframe. If determined to be necessary by the PGDP team and regulators, additional TCE characterization or cleanup activities could be performed. Consistent with the limited quantity of TCE in SWMU 7, we identify a range of low cost approaches for such activities (e.g., soil gas surveys for characterization or SVE for remediation). We hope that this information is useful to the Paducah team and to their regulators and stakeholders to develop a robust environmental management path to address the groundwater and soil contamination associated with the burial ground areas.

  15. COMBINED GEOPHYSICAL INVESTIGATION TECHNIQUES TO IDENTIFY BURIED WASTE IN AN UNCONTROLLED LANDFILL AT THE PADUCAH GASEOUS DIFFUSION PLANT, KENTUCKY

    SciTech Connect (OSTI)

    Miller, Peter T.; Starmer, R. John

    2003-02-27

    The primary objective of the investigation was to confirm the presence and determine the location of a cache of 30 to 60 buried 55-gallon drums that were allegedly dumped along the course of the pre-existing, northsouth diversion ditch (NSDD) adjacent to permitted landfills at the Paducah Gaseous Diffusion Plant, Kentucky. The ditch had been rerouted and was being filled and re-graded at the time of the alleged dumping. Historic information and interviews with individuals associated with alleged dumping activities indicated that the drums were dumped prior to the addition of other fill materials. In addition, materials alleged to have been dumped in the ditch, such as buried roofing materials, roof flashing, metal pins, tar substances, fly ash, and concrete rubble complicated data interpretation. Some clean fill materials have been placed over the site and graded. This is an environment that is extremely complicated in terms of past waste dumping activities, construction practices and miscellaneous landfill operations. The combination of site knowledge gained from interviews and research of existing site maps, variable frequency EM data, classical total magnetic field data and optimized GPR lead to success where a simpler less focused approach by other investigators using EM-31 and EM-61 electromagnetic methods and unfocused ground penetrating radar (GPR)did not produce results and defined no real anomalies. A variable frequency electromagnetic conductivity unit was used to collect the EM data at 3,030 Hz, 5,070 Hz, 8,430 Hz, and 14,010 Hz. Both in-phase and quadrature components were recorded at each station point. These results provided depth estimates for targets and some information on the subsurface conditions. A standard magnetometer was used to conduct the magnetic survey that showed the locations and extent of buried metal, the approximate volume of ferrous metal present within a particular area, and allowed estimation of approximate target depths. The GPR survey used a 200 megahertz (MHz) antenna to provide the maximum depth penetration and subsurface detail yielding usable signals to a depth of about 6 to 10 feet in this environment and allowed discrimination of objects that were deeper, particularly useful in the southern area of the site where shallow depth metallic debris (primarily roof flashing) complicated interpretation of the EM and magnetic data. Several geophysical anomalies were defined on the contour plots that indicated the presence of buried metal. During the first phase of the project, nine anomalies or anomalous areas were detected. The sizes, shapes, and magnitudes of the anomalies varied considerably, but given the anticipated size of the primary target of the investigation, only the most prominent anomalies were considered as potential caches of 30 to 60 buried drums. After completion of a second phase investigation, only two of the anomalies were of sufficient magnitude, not identifiable with existing known metallic objects such as monitoring wells, and in positions that corresponded to the location of alleged dumping activities and were recommended for further, intrusive investigation. Other important findings, based on the variable frequency EM method and its combination with total field magnetic and GPR data, included the confirmation of the position of the old NSDD, the ability to differentiate between ferrous and non-ferrous anomalies, and the detection of what may be plumes emanating from the landfill cell.

  16. Proceedings of waste stream minimization and utilization innovative concepts: An experimental technology exchange. Volume 2, Industrial liquid waste processing, industrial gaseous waste processing

    SciTech Connect (OSTI)

    Lee, V.E. [ed.; Watts, R.L.

    1993-04-01

    This two-volume proceedings summarize the results of fifteen innovations that were funded through the US Department of Energy`s Innovative Concept Program. The fifteen innovations were presented at the sixth Innovative Concepts Fair, held in Austin, Texas, on April 22--23, 1993. The concepts in this year`s fair address innovations that can substantially reduce or use waste streams. Each paper describes the need for the proposed concept, the concept being proposed, and the concept`s economics and market potential, key experimental results, and future development needs. The papers are divided into two volumes: Volume 1 addresses innovations for industrial solid waste processing and municipal waste reduction/recycling, and Volume 2 addresses industrial liquid waste processing and industrial gaseous waste processing. Individual reports are indexed separately.

  17. Probe into Gaseous Pollution and Assessment of Air Quality Benefit under Sector Dependent Emission Control Strategies over Megacities in Yangtze River Delta, China

    SciTech Connect (OSTI)

    Dong, Xinyi; Gao, Yang; Fu, Joshua S.; Li, Juan; Huang, Kan; Zhuang, G.; Zhou, Ying

    2013-11-01

    On February 29th 2012, China published its new National Ambient Air Quality Standard (CH-NAAQS) aiming at revising the standards and measurements for both gaseous pollutants including ozone (O3), nitrogen dioxide (NO2), and sulfur dioxide (SO2), and also particle pollutants including PM10 and PM2.5. In order to understand the air pollution status regarding this new standard, the integrated MM5/CMAQ modeling system was applied over Yangtze River Delta (YRD) within this study to examine the criteria gaseous pollutants listed in the new CH-NAAQS. Sensitivity simulations were also conducted to assess the responses of gaseous pollutants under 8 different sector-dependent emission reduction scenarios in order to evaluate the potential control strategies. 2006 was selected as the simulation year in order to review the air quality condition at the beginning of China’s 11th Five-Year-Plan (FYP, from 2006 to 2010), and also compared with air quality status in 2010 as the end of 11th FYP to probe into the effectiveness of the national emission control efforts. Base case simulation showed distinct seasonal variation for gaseous pollutants: SO2, and NO2 were found to have higher surface concentrations in winter while O3 was found to have higher concentrations in spring and summer than other seasons. According to the analyses focused on 3 megacities within YRD, Shanghai, Nanjing, and Hangzhou, we found different air quality conditions among the cities: NO2 was the primary pollutant that having the largest number of days exceeding the CH-NAAQS daily standard (80 ?g/m3) in Shanghai (59 days) and Nanjing (27 days); SO2 was the primary pollutant with maximum number of days exceeding daily air quality standard (150 ?g/m3) in Hangzhou (28 days), while O3 exceeding the daily maximum 8-hour standard (160 ?g/m3) for relatively fewer days in all the three cities (9 days in Shanghai, 14 days in Nanjing, and 11 days in Hangzhou). Simulation results from predefined potential applicable emission control scenarios suggested significant air quality improvements from emission reduction: 90% of SO2 emission removed from power plant in YRD would be able to reduce more than 85% of SO2 pollution, 85% NOx emission reduction from power plant would reduce more than 60% of NO2 pollution, in terms of reducing the number of days exceeding daily air quality standard. NOx emission reduction from transportation and industry were also found to effectively reduce NO2 pollution but less efficient than emission control from power plants. We also found that multi-pollutants emission control including both NOx and VOC would be a better strategy than independent NOx control over YRD which is China’s 12th Five-Year-Plan (from 2011 to 2015), because O3 pollution would be increased as a side effect of NOx control and counteract NO2 pollution reduction benefit.

  18. Environmental investigations at the Paducah Gaseous Diffusion Plant and surrounding area, McCracken County, Kentucky: Volume 1 -- Executive summary. Final report

    SciTech Connect (OSTI)

    NONE

    1994-05-01

    This report details the results of four studies into environmental and cultural resources on and near the Department of Energy`s (DOE) Paducah Gaseous Diffusion Plant (PGDP) located in Western Kentucky in McCracken County, approximately 10 miles west of Paducah, KY. The area investigated includes the PGDP facility proper, additional area owned by DOE under use permit to the Western Kentucky Wildlife Management Area (WKWMA), area owned by the Commonwealth of Kentucky that is administered by the WKWMA, area owned by the Tennessee Valley Authority (TVA), the Metropolis Lake State Nature preserve and some privately held land. DOE requested the assistance and support of the US Army Engineer District, Nashville (CEORN) in conducting various environmental investigations of the area. The US Army Engineer Waterways Experiment Station (WES) provided technical support to the CEORN for environmental investigations of (1) wetland resources, (2) threatened or endangered species and habitats, and (3) cultural resources. A floodplain investigation was conducted by CEORN.

  19. Integrated modeling of CO2 storage and leakage scenarios including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO2

    SciTech Connect (OSTI)

    Pruess, K.

    2011-05-15

    Storage of CO{sub 2} in saline aquifers is intended to be at supercritical pressure and temperature conditions, but CO{sub 2} leaking from a geologic storage reservoir and migrating toward the land surface (through faults, fractures, or improperly abandoned wells) would reach subcritical conditions at depths shallower than 500-750 m. At these and shallower depths, subcritical CO{sub 2} can form two-phase mixtures of liquid and gaseous CO{sub 2}, with significant latent heat effects during boiling and condensation. Additional strongly non-isothermal effects can arise from decompression of gas-like subcritical CO{sub 2}, the so-called Joule-Thomson effect. Integrated modeling of CO{sub 2} storage and leakage requires the ability to model non-isothermal flows of brine and CO{sub 2} at conditions that range from supercritical to subcritical, including three-phase flow of aqueous phase, and both liquid and gaseous CO{sub 2}. In this paper, we describe and demonstrate comprehensive simulation capabilities that can cope with all possible phase conditions in brine-CO{sub 2} systems. Our model formulation includes: (1) an accurate description of thermophysical properties of aqueous and CO{sub 2}-rich phases as functions of temperature, pressure, salinity and CO{sub 2} content, including the mutual dissolution of CO{sub 2} and H{sub 2}O; (2) transitions between super- and subcritical conditions, including phase change between liquid and gaseous CO{sub 2}; (3) one-, two-, and three-phase flow of brine-CO{sub 2} mixtures, including heat flow; (4) non-isothermal effects associated with phase change, mutual dissolution of CO{sub 2} and water, and (de-) compression effects; and (5) the effects of dissolved NaCl, and the possibility of precipitating solid halite, with associated porosity and permeability change. Applications to specific leakage scenarios demonstrate that the peculiar thermophysical properties of CO{sub 2} provide a potential for positive as well as negative feedbacks on leakage rates, with a combination of self-enhancing and self-limiting effects. Lower viscosity and density of CO{sub 2} as compared to aqueous fluids provides a potential for self-enhancing effects during leakage, while strong cooling effects from liquid CO{sub 2} boiling into gas, and from expansion of gas rising towards the land surface, act to self-limit discharges. Strong interference between fluid phases under three-phase conditions (aqueous - liquid CO{sub 2} - gaseous CO{sub 2}) also tends to reduce CO{sub 2} fluxes. Feedback on different space and time scales can induce non-monotonic behavior of CO{sub 2} flow rates.

  20. Field evaluation of a horizontal well recirculation system for groundwater treatment: Field demonstration at X-701B Portsmouth Gaseous Diffusion Plant, Piketon, Ohio

    SciTech Connect (OSTI)

    Korte, N.; Muck, M.; Kearl, P.; Siegrist, R.; Schlosser, R.; Zutman, J.; Houk, T.

    1998-08-01

    This report describes the field-scale demonstration performed as part of the project, In Situ Treatment of Mixed Contaminants in Groundwater. This project was a 3{1/2} year effort comprised of laboratory work performed at Oak Ridge National Laboratory and fieldwork performed at the US Department of Energy (DOE) Portsmouth Gaseous Diffusion Plant (PORTS). The overall goal of the project was to evaluate in situ treatment of groundwater using horizontal recirculation coupled with treatment modules. Specifically, horizontal recirculation was tested because of its application to thin, interbedded aquifer zones. Mixed contaminants were targeted because of their prominence at DOE sites and because they cannot be treated with conventional methods. The project involved several research elements, including treatment process evaluation, hydrodynamic flow and transport modeling, pilot testing at an uncontaminated site, and full-scale testing at a contaminated site. This report presents the results of the work at the contaminated site, X-701B at PORTS. Groundwater contamination at X-701B consists of trichloroethene (TCE) (concentrations up to 1800 mg/L) and technetium-998 (Tc{sup 99}) (activities up to 926 pCi/L).

  1. The Case Against Dark Matter and Modified Gravity: Flat Rotation Curves Are a Rigorous Requirement in Rotating Self-Gravitating Newtonian Gaseous Disks

    E-Print Network [OSTI]

    Christodoulou, Dimitris M

    2015-01-01

    By solving analytically the various types of Lane-Emden equations with rotation, we have discovered two new coupled fundamental properties of rotating, self-gravitating, gaseous disks in equilibrium: Isothermal disks must, on average, exhibit strict power-law density profiles in radius $x$ on their equatorial planes of the form $A x^{k-1}$, where $A$ and $k-1$ are the integration constants; and ``flat'' rotation curves precisely such as those observed in spiral galaxy disks. Polytropic disks must, on average, exhibit strict density profiles of the form $\\left[\\ln(A x^k)\\right]^n$, where $n$ is the polytropic index; and ``flat'' rotation curves described by square roots of upper incomplete gamma functions. By ``on average,'' we mean that, irrespective of the chosen boundary conditions, the actual profiles must oscillate around and remain close to the strict mean profiles of the analytic singular equilibrium solutions. We call such singular solutions the ``intrinsic'' solutions of the differential equations bec...

  2. Dual wall reverse circulation drilling with multi-level groundwater sampling for groundwater contaminant plume delineation at Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    Smuin, D.R.; Morti, E.E.; Zutman, J.L.; Pickering, D.A.

    1995-08-01

    Dual wall reverse circulation (DWRC) drilling was used to drill 48 borings during a groundwater contaminant investigation at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky. This method was selected as an alternative to conventional hollow stem auger drilling for a number of reasons, including the expectation of minimizing waste, increasing the drilling rate, and reducing the potential for cross contamination of aquifers. Groundwater samples were collected from several water-bearing zones during drilling of each borehole. The samples were analyzed for volatile organic compounds using a field gas chromatograph. This approach allowed the investigation to be directed using near-real-time data. Use of downhole geophysical logging, in conjunction with lithologic descriptions of borehole cuttings, resulted in excellent correlation of the geology in the vicinity of the contaminant plume. The total volume of cuttings generated using the DWRC drilling method was less than half of what would have been produced by hollow stem augering; however, the cuttings were recovered in slurry form and had to be dewatered prior to disposal. The drilling rate was very rapid, often approaching 10 ft/min; however, frequent breaks to perform groundwater sampling resulted in an average drilling rate of < 1 ft/min. The time required for groundwater sampling could be shortened by changing the sampling methodology. Analytical results indicated that the drilling method successfully isolated the various water bearing zones and no cross contamination resulted from the investigation.

  3. Thermal Discharges from Paducah Gaseous Diffusion Plant Outfalls: Impacts on Stream Temperatures and Fauna of Little Bayou and Big Bayou Creeks

    SciTech Connect (OSTI)

    Roy, W.K.

    1999-01-01

    The development of a biological monitoring plan for the receiving streams of the Paducah Gaseous Diffusion Plant (PGDP) began in the late 1980s, because of an Agreed Order (AO) issued in September 1987 by the Kentucky Division of Water (KDOW). Five years later, in September 1992, more stringent effluent limitations were imposed upon the PGDP operations when the KDOW reissued Kentucky Pollutant Discharge Elimination System permit No. KY 0004049. This action prompted the US Department of Energy (DOE) to request a stay of certain limits contained in the permit. An AO is being negotiated between KDOW, the United States Enrichment Corporation (USEC), and DOE that will require that several studies be conducted, including this stream temperature evaluation study, in an effort to establish permit limitations. All issues associated with this AO have been resolved, and the AO is currently being signed by all parties involved. The proposed effluent temperature limit is 89 F (31.7C) as a mean monthly temperature. In the interim, temperatures are not to exceed 95 F (35 C) as a monthly mean or 100 F (37.8 C) as a daily maximum. This study includes detailed monitoring of instream temperatures, benthic macroinvertebrate communities, fish communities, and a laboratory study of thermal tolerances.

  4. Applicable or relevant and appropriate requirements (ARARs) for remedial actions at the Paducah Gaseous Diffusion Plant: A compendium of environmental laws and guidance

    SciTech Connect (OSTI)

    Etnier, E.L.; Eaton, L.A. (Oak Ridge National Lab., TN (United States))

    1992-03-01

    Section 121 of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) of 1980 specifies that remedial actions for cleanup of hazardous substances found at sites placed on the National Priorities List (NPL) by the US Environmental Protection Agency (EPA) must comply with applicable or relevant and appropriate requirements (ARARs) or standards under federal and state environmental laws. To date, the US Department of Energy (DOE) Paducah Gaseous Diffusion Plant (PGDP) has not been on the NPL. Although DOE and EPA have entered into an Administrative Consent Order (ACO), the prime regulatory authority for cleanup at PGDP will be the Resource Conservation and Recovery Act (RCRA). This report supplies a preliminary list of available federal and state ARARs that might be considered for remedial response at PGDP in the event that the plant becomes included on the NPL or the ACO is modified to include CERCLA cleanup. A description of the terms applicable'' and relevant and appropriate'' is provided, as well as definitions of chemical-, location-, and action-specific ARARS. ARARs promulgated by the federal government and by the state of Kentucky are listed in tables. In addition, the major provisions of RCRA, the Safe Drinking Water Act, the Clean Water Act, the Clean Air Act, and other acts, as they apply to hazardous and radioactive waste cleanup, are discussed.

  5. Thermal discharges from Paducah Gaseous Diffusion Plant outfalls: Impacts on stream temperatures and fauna of Little Bayou and Big Bayou Creeks

    SciTech Connect (OSTI)

    Roy, W.K.; Ryon, M.G.; Hinzman, R.L. [Oak Ridge National Lab., TN (United States). Computer Science and Mathematics Div.

    1996-03-01

    The development of a biological monitoring plan for the receiving streams of the Paducah Gaseous Diffusion Plant (PGDP) began in the late 1980s, because of an Agreed Order (AO) issued in September 1987 by the Kentucky Division of Water (KDOW). Five years later, in September 1992, more stringent effluent limitations were imposed upon the PGDP operations when the KDOW reissued Kentucky Pollutant Discharge Elimination System permit No. KY 0004049. This action prompted the US Department of Energy (DOE) to request a stay of certain limits contained in the permit. An AO is being negotiated between KDOW, the US Enrichment Corporation (USEC), and DOE that will require that several studies be conducted, including this stream temperature evaluation study, in an effort to establish permit limitations. All issues associated with this AO have been resolved, and the AO is currently being signed by all parties involved. The proposed effluent temperature limit is 89 F (31.7 C) as a mean monthly temperature. In the interim, temperatures are not to exceed 95 F (35 C) as a monthly mean or 100 F (37.8 C) as a daily maximum. This study includes detailed monitoring of instream temperatures, benthic macroinvertebrate communities, fish communities, and a laboratory study of thermal tolerances.

  6. Applicable or relevant and appropriate requirements (ARARs) for remedial actions at the Paducah Gaseous Diffusion Plant: A compendium of environmental laws and guidance. Environmental Restoration Program

    SciTech Connect (OSTI)

    Etnier, E.L.; Eaton, L.A. [Oak Ridge National Lab., TN (United States)

    1992-03-01

    Section 121 of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) of 1980 specifies that remedial actions for cleanup of hazardous substances found at sites placed on the National Priorities List (NPL) by the US Environmental Protection Agency (EPA) must comply with applicable or relevant and appropriate requirements (ARARs) or standards under federal and state environmental laws. To date, the US Department of Energy (DOE) Paducah Gaseous Diffusion Plant (PGDP) has not been on the NPL. Although DOE and EPA have entered into an Administrative Consent Order (ACO), the prime regulatory authority for cleanup at PGDP will be the Resource Conservation and Recovery Act (RCRA). This report supplies a preliminary list of available federal and state ARARs that might be considered for remedial response at PGDP in the event that the plant becomes included on the NPL or the ACO is modified to include CERCLA cleanup. A description of the terms ``applicable`` and ``relevant and appropriate`` is provided, as well as definitions of chemical-, location-, and action-specific ARARS. ARARs promulgated by the federal government and by the state of Kentucky are listed in tables. In addition, the major provisions of RCRA, the Safe Drinking Water Act, the Clean Water Act, the Clean Air Act, and other acts, as they apply to hazardous and radioactive waste cleanup, are discussed.

  7. Photocatalytic degradation of gaseous toluene over hollow “spindle-like” ?-Fe{sub 2}O{sub 3} loaded with Ag

    SciTech Connect (OSTI)

    Li, Hong [State Key Laboratory of Fine Chemical, Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China) [State Key Laboratory of Fine Chemical, Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China); Department of Basic, Dalian Naval Academy, Dalian 116018 (China); Zhao, Qidong [State Key Laboratory of Fine Chemical, Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China)] [State Key Laboratory of Fine Chemical, Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China); Li, Xinyong, E-mail: xyli@dlut.edu.cn [State Key Laboratory of Fine Chemical, Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China) [State Key Laboratory of Fine Chemical, Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China); Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia); Shi, Yong [State Key Laboratory of Fine Chemical, Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China)] [State Key Laboratory of Fine Chemical, Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024 (China); Zhu, Zhengru [Research Center of Hydrology and Engineering, Academy of City and Environment, Liaoning Normal University, Dalian 116029 (China)] [Research Center of Hydrology and Engineering, Academy of City and Environment, Liaoning Normal University, Dalian 116029 (China); Tade, Moses [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia)] [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia); Liu, Shaomin, E-mail: shaomin.liu@curtin.edu.au [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia)] [Department of Chemical Engineering, Curtin University, Perth, WA 6845 (Australia)

    2012-06-15

    Highlights: ? Hollow ?-Fe{sub 2}O{sub 3} spindle-shaped microparticles were prepared for Ag support. ? The hollow ?-Fe{sub 2}O{sub 3} and Ag/?-Fe{sub 2}O{sub 3} materials were used to degrade gaseous toluene. ? Complete degradation of toluene occurred on the Ag/?-Fe{sub 2}O{sub 3} surface. -- Abstract: In this work, hollow “spindle-like” ?-Fe{sub 2}O{sub 3} nanoparticles were synthesized by a hydrothermal route. The Ag/?-Fe{sub 2}O{sub 3} catalyst was prepared based on the spindle-shaped ?-Fe{sub 2}O{sub 3} with CTAB as the surfactant, which showed excellent photoelectric property and photocatalytic activity. The structural properties of these samples were systematically investigated by X-ray powder diffraction, scanning electronic microscopy, transmission electronic microscopy, energy-dispersive X-ray spectra, and UV–Vis diffuse reflectance spectroscopy techniques. The photo-induced charge separation in the samples was demonstrated by surface photovoltage measurement. The photocatalytic performances of the Ag/?-Fe{sub 2}O{sub 3} and ?-Fe{sub 2}O{sub 3} samples were comparatively studied in the degradation of toluene under xenon lamp irradiation by in situ FTIR spectroscopy. Benzaldehyde and benzoic acid species could be observed on the ?-Fe{sub 2}O{sub 3} surface rather than Ag/?-Fe{sub 2}O{sub 3} surface. The results indicate that the Ag/?-Fe{sub 2}O{sub 3} sample exhibited higher photocatalytic efficiency.

  8. Assessment of the influences of groundwater colloids on the migration of technetium-99 at the Paducah Gaseous Diffusion Plant Site in Paducah, Kentucky

    SciTech Connect (OSTI)

    Gu, B.; McDonald, J.A.; McCarthy, J.F. [Oak Ridge National Lab., TN (United States); Clausen, J.L. [Paducah Gaseous Diffusion Plant, KY (United States). Environmental Restoration and Waste Management

    1994-07-01

    This short report summarizes the influences of groundwater colloids on the migration/transport of {sup 99}Tc at the Paducah Gaseous Diffusion Plant (PGDP) site in Paducah, Kentucky. Limited data suggest that inorganic colloidal materials (e.g., aluminosilicate clay minerals) may not play a significant role in the retention and transport of Tc. Studies by size fractionation reveal that both Tc and natural organic matter (NOM) are largely present in the <3K fraction. The role of NOM on Tc retention and transport is not conclusive on the basis of this study. However, a literature review suggests that Tc is very likely associated with the groundwater organics. The presence of the organic matter could have increased the solubility and cotransport of Tc at the PGDP site. Further studies, applying such techniques as gel chromatography, size exclusion, and spectroscopy, may be useful to determine the association of organic matter with Tc. If Tc is associated with groundwater organics, appropriate protocols for removal of organic matter associated with Tc may be developed. Time and resources were limited so this study is not comprehensive with respect to the role of mobile organic and inorganic colloidal materials on Tc transport in subsurface soils. The redox conditions (DO) of groundwaters reported may not represent the true groundwater conditions, which could have influenced the association and dissociation of Tc with groundwater colloidal materials. Because Tc concentrations in the groundwater (on the order of nCi/L) at the PGDP site is much lower than the solubility of reduced Tc (IV) (on the order of {approximately}10{sup {minus}8} mol/L or parts per billion), regardless of the redox conditions, Tc will stay in solution phase as TC(IV) or Tc(VII). The mechanisms of adsorption/association vs precipitation must be understood under reduced and low Tc conditions so that strategic plans for remediation of Tc contaminated soils and groundwaters can be developed.

  9. A supercoarsening multigrid method for poroelasticity in 3D coupled ...

    E-Print Network [OSTI]

    2012-06-14

    Jun 14, 2012 ... water. heavy hydrocarbon or oil, and light hydrocar- ... Conservation of mass for water, oil, and ..... problem is closely tied to a real ?eld case.

  10. A TECHNICAL ASSESSMENT OF THE CURRENT WATER POLICY BOUNDARY AT U.S. DEPARTMENT OF ENERGY, PADUCAH GASEOUS DIFFUSION PLANT, PADUCAH, KENTUCKY

    SciTech Connect (OSTI)

    2012-12-13

    In 1988, groundwater contaminated with trichloroethene (TCE) and technetium-99 (Tc-99) was identified in samples collected from residential water wells withdrawing groundwater from the Regional Gravel Aquifer (RGA) north of the Paducah Gaseous Diffusion Plant (PGDP) facility. In response, the U.S. Department of Energy (DOE) provided temporary drinking water supplies to approximately 100 potentially affected residents by initially supplying bottled water, water tanks, and water-treatment systems, and then by extending municipal water lines, all at no cost, to those persons whose wells could be affected by contaminated groundwater. The Water Policy boundary was established in 1993. In the Policy, DOE agreed to pay the reasonable monthly cost of water for homes and businesses and, in exchange, many of the land owners signed license agreements committing to cease using the groundwater via rural water wells. In 2012, DOE requested that Oak Ridge Associated Universities (ORAU), managing contractor of Oak Ridge Institute for Science and Education (ORISE), provide an independent assessment of the quality and quantity of the existing groundwater monitoring data and determine if there is sufficient information to support a modification to the boundary of the current Water Policy. As a result of the assessment, ORAU concludes that sufficient groundwater monitoring data exists to determine that a shrinkage and/or shift of the plume(s) responsible for the initial development of this policy has occurred. Specifically, there is compelling evidence that the TCE plume is undergoing shrinkage due to natural attenuation and associated degradation. The plume shrinkage (and migration) has also been augmented in local areas where large volumes of groundwater were recovered by pump-and treat remedial systems along the eastern and western boundaries of the Northwest Plume, and in other areas where pump-and-treat systems have been deployed by DOE to remove source contaminants. The available evidence supports adjusting the western and northwestern Water Policy boundary. Based on the historical and modeled hydrogeological data reflecting past flow and plume attenuation, along with associated plume migration toward the northeast, the establishment of a new boundary along the westernmost margin of the earliest indication of the TCE plume is proposed and justified on hydrogeological grounds. Approximately 30% of the original area would remain within the adjusted Water Policy area west and northwest of the PGDP facility. This modification would release about 70% of the area, although individual properties would overlap the new boundary.

  11. Dose Modeling Evaluations and Technical Support Document For the Authorized Limits Request for the DOE-Owned Property Outside the Limited Area, Paducah Gaseous Diffusion Plant Paducah, Kentucky

    SciTech Connect (OSTI)

    Boerner, A. J.; Maldonado, D. G.; Hansen, Tom

    2012-09-01

    Environmental assessments and remediation activities are being conducted by the U.S. Department of Energy (DOE) at the Paducah Gaseous Diffusion Plant (PGDP), Paducah, Kentucky. The Oak Ridge Institute for Science and Education (ORISE), a DOE prime contractor, was contracted by the DOE Portsmouth/Paducah Project Office (DOE-PPPO) to conduct radiation dose modeling analyses and derive single radionuclide soil guidelines (soil guidelines) in support of the derivation of Authorized Limits (ALs) for 'DOE-Owned Property Outside the Limited Area' ('Property') at the PGDP. The ORISE evaluation specifically included the area identified by DOE restricted area postings (public use access restrictions) and areas licensed by DOE to the West Kentucky Wildlife Management Area (WKWMA). The licensed areas are available without restriction to the general public for a variety of (primarily) recreational uses. Relevant receptors impacting current and reasonably anticipated future use activities were evaluated. In support of soil guideline derivation, a Conceptual Site Model (CSM) was developed. The CSM listed radiation and contamination sources, release mechanisms, transport media, representative exposure pathways from residual radioactivity, and a total of three receptors (under present and future use scenarios). Plausible receptors included a Resident Farmer, Recreational User, and Wildlife Worker. single radionuclide soil guidelines (outputs specified by the software modeling code) were generated for three receptors and thirteen targeted radionuclides. These soil guidelines were based on satisfying the project dose constraints. For comparison, soil guidelines applicable to the basic radiation public dose limit of 100 mrem/yr were generated. Single radionuclide soil guidelines from the most limiting (restrictive) receptor based on a target dose constraint of 25 mrem/yr were then rounded and identified as the derived soil guidelines. An additional evaluation using the derived soil guidelines as inputs into the code was also performed to determine the maximum (peak) dose for all receptors. This report contains the technical basis in support of the DOE?s derivation of ALs for the 'Property.' A complete description of the methodology, including an assessment of the input parameters, model inputs, and results is provided in this report. This report also provides initial recommendations on applying the derived soil guidelines.

  12. Fissible Deposit Characterization at the Former Oak Ridge K-25 Gaseous Diffusion Plant by {sup 252}CF-Source-Driven Measurements

    SciTech Connect (OSTI)

    Hannon, T.F.; Mihalczo, J.T.; Mullens, J.A.; Uckan, T.; Valentine, T.E.; Wyatt, M.S.

    1998-05-01

    The Deposit Removal Project was undertaken with the support of the U. S. Department of Energy at the East Tennessee Technology Park (ETTP) formerly the Oak Ridge K-25 Site. The project team performed the safe removal of the hydrated uranyl fluoride (UO{sub 2}F{sub 2}) deposits from the K-29 Building of the former Oak Ridge Gaseous Diffusion Plant. The deposits had developed as a result of air leakage into UF{sub 6} gas process pipes; UO{sub 2}F{sub 2} became hydrated by moisture from the air and deposited inside the pipes. The mass, its distribution, and the hydrogen content [that is, the ratio of H to U (H/U)], were the key parameters that controlled the nuclear criticality safety of the deposits. Earlier gamma-ray spectrometry measurements in K-29 had identified the largest deposits in the building. The first and third largest deposits in the building were measured in this program. The first deposit, found in the Unit 2, Cell 7, B-Line Outlet process pipe (called the ''Hockey Stick'') was about 1,300 kg ({+-} 50% uncertainty) at 3.34 wt% {sup 235}U enrichment ({+-}50% uncertainty) and according to the gamma-ray spectroscopy was uniformly distributed. The second deposit (the third-largest deposit in the building), found in the Unit 2, Cell 6, A-Line Outlet process pipe (called the ''Tee-Pipe''), had a uranium deposit estimated to be about 240 kg ({+-} 50% uncertainty) at 3.4 wt % {sup 235}U enrichment ({+-} 20% uncertainty). Before deposit removal activities began, the Deposit Removal Project team needed to survey the inside of the pipes intrusively to assess the nuclear criticality safety of the deposits. Therefore, the spatial distribution of the deposits, the total uranium deposit mass, and the moderation level resulting from hydration of the deposits, all of which affect nuclear criticality safety were required. To perform the task safely and effectively, the Deposit Removal Project team requested that Oak Ridge National Laboratory (ORNL) characterize the two largest deposits with the {sup 252}Cf-source-driven transmission (CFSDT) technique, an active neutron interrogation method developed for use at the Oak Ridge Y-12 Plant to identify nuclear weapons components in containers. The active CFSDT measurement technique uses CFSDT time-of-flight measurements of prompt neutrons and gamma rays from an externally introduced {sup 252}Cf source.

  13. ENZYME ACTIVITY PROBE AND GEOCHEMICAL ASSESSMENT FOR POTENTIAL AEROBIC COMETABOLISM OF TRICHLOROETHENE IN GROUNDWATER OF THE NORTHWEST PLUME, PADUCAH GASEOUS DIFFUSION PLANT, KENTUCKY

    SciTech Connect (OSTI)

    Looney, B; M. Hope Lee, M; S. K. Hampson, S

    2008-06-27

    The overarching objective of the Paducah Gaseous Diffusion Plant (PGDP) enzyme activity probe (EAP) effort is to determine if aerobic cometabolism is contributing to the attenuation of trichloroethene (TCE) and other chlorinated solvents in the contaminated groundwater beneath PGDP. The site-specific objective for the EAP assessment is to identify if key metabolic pathways are present and expressed in the microbial community--namely the pathways that are responsible for degradation of methane and aromatic (e.g. toluene, benzene, phenol) substrates. The enzymes produced to degrade methane and aromatic compounds also break down TCE through a process known as cometabolism. EAPs directly measure if methane and/or aromatic enzyme production pathways are operating and, for the aromatic pathways, provide an estimate of the number of active organisms in the sampled groundwater. This study in the groundwater plumes at PGDP is a major part of a larger scientific effort being conducted by Interstate Technology and Regulatory Council (ITRC), U.S. Department of Energy (DOE) Office of Environmental Management (EM), Savannah River National Laboratory (SRNL), and North Wind Inc. in which EAPs are being applied to contaminated groundwater from diverse hydrogeologic and plume settings throughout the U.S. to help standardize their application as well as their interpretation. While EAP data provide key information to support the site specific objective for PGDP, several additional lines of evidence are being evaluated to increase confidence in the determination of the occurrence of biodegradation and the rate and sustainability of aerobic cometabolism. These complementary efforts include: (1) Examination of plume flowpaths and comparison of TCE behavior to 'conservative' tracers in the plume (e.g., {sup 99}Tc); (2) Evaluation of geochemical conditions throughout the plume; and (3) Evaluation of stable isotopes in the contaminants and their daughter products throughout the plume. If the multiple lines of evidence support the occurrence of cometabolism and the potential for the process to contribute to temporal and spatial attenuation of TCE in PGDP groundwater, then a follow-up enzyme probe microcosm study to better estimate biological degradation rate(s) is warranted.

  14. Process for producing enriched uranium having a {sup 235}U content of at least 4 wt. % via combination of a gaseous diffusion process and an atomic vapor laser isotope separation process to eliminate uranium hexafluoride tails storage

    DOE Patents [OSTI]

    Horton, J.A.; Hayden, H.W. Jr.

    1995-05-30

    An uranium enrichment process capable of producing an enriched uranium, having a {sup 235}U content greater than about 4 wt. %, is disclosed which will consume less energy and produce metallic uranium tails having a lower {sup 235}U content than the tails normally produced in a gaseous diffusion separation process and, therefore, eliminate UF{sub 6} tails storage and sharply reduce fluorine use. The uranium enrichment process comprises feeding metallic uranium into an atomic vapor laser isotope separation process to produce an enriched metallic uranium isotopic mixture having a {sup 235} U content of at least about 2 wt. % and a metallic uranium residue containing from about 0.1 wt. % to about 0.2 wt. % {sup 235} U; fluorinating this enriched metallic uranium isotopic mixture to form UF{sub 6}; processing the resultant isotopic mixture of UF{sub 6} in a gaseous diffusion process to produce a final enriched uranium product having a {sup 235}U content of at least 4 wt. %, and up to 93.5 wt. % or higher, of the total uranium content of the product, and a low {sup 235}U content UF{sub 6} having a {sup 235}U content of about 0.71 wt. % of the total uranium content of the low {sup 235}U content UF{sub 6}; and converting this low {sup 235}U content UF{sub 6} to metallic uranium for recycle to the atomic vapor laser isotope separation process. 4 figs.

  15. Process for producing enriched uranium having a .sup.235 U content of at least 4 wt. % via combination of a gaseous diffusion process and an atomic vapor laser isotope separation process to eliminate uranium hexafluoride tails storage

    DOE Patents [OSTI]

    Horton, James A. (Livermore, CA); Hayden, Jr., Howard W. (Oakridge, TN)

    1995-01-01

    An uranium enrichment process capable of producing an enriched uranium, having a .sup.235 U content greater than about 4 wt. %, is disclosed which will consume less energy and produce metallic uranium tails having a lower .sup.235 U content than the tails normally produced in a gaseous diffusion separation process and, therefore, eliminate UF.sub.6 tails storage and sharply reduce fluorine use. The uranium enrichment process comprises feeding metallic uranium into an atomic vapor laser isotope separation process to produce an enriched metallic uranium isotopic mixture having a .sup.235 U content of at least about 2 wt. % and a metallic uranium residue containing from about 0.1 wt. % to about 0.2 wt. % .sup.235 U; fluorinating this enriched metallic uranium isotopic mixture to form UF.sub.6 ; processing the resultant isotopic mixture of UF.sub.6 in a gaseous diffusion process to produce a final enriched uranium product having a .sup.235 U content of at least 4 wt. %, and up to 93.5 wt. % or higher, of the total uranium content of the product, and a low .sup.235 U content UF.sub.6 having a .sup.235 U content of about 0.71 wt. % of the total uranium content of the low .sup.235 U content UF.sub.6 ; and converting this low .sup.235 U content UF.sub.6 to metallic uranium for recycle to the atomic vapor laser isotope separation process.

  16. Final Environmental Assessment and Finding of No Significant Impact: The Implementation of the Authorized Limits Process for Waste Acceptance at the C-746-U Landfill Paducah Gaseous Diffusion Plant Paducah, Kentucky

    SciTech Connect (OSTI)

    N /A

    2002-08-06

    The US Department of Energy (DOE) has completed an environmental assessment (DOE/EA-1414) for the proposed implementation of the authorized limits process for waste acceptance at the C-746-U Landfill at the Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky. Based on the results of the impact analysis reported in the EA, which is incorporated herein by this reference, DOE has determined that the proposed action is not a major Federal action that would significantly affect the quality of the human environment within the context of the ''National Environmental Policy Act of 1969'' (NEPA). Therefore preparation of an environmental impact statement is not necessary, and DOE is issuing this Finding of No Significant Impact (FONSI).

  17. ECO2M: A TOUGH2 Fluid Property Module for Mixtures of Water, NaCl, and CO2, Including Super- and Sub-Critical Conditions, and Phase Change Between Liquid and Gaseous CO2

    SciTech Connect (OSTI)

    Pruess, K.

    2011-04-01

    ECO2M is a fluid property module for the TOUGH2 simulator (Version 2.0) that was designed for applications to geologic storage of CO{sub 2} in saline aquifers. It includes a comprehensive description of the thermodynamics and thermophysical properties of H{sub 2}O - NaCl - CO{sub 2} mixtures, that reproduces fluid properties largely within experimental error for temperature, pressure and salinity conditions in the range of 10 C {le} T {le} 110 C, P {le} 600 bar, and salinity from zero up to full halite saturation. The fluid property correlations used in ECO2M are identical to the earlier ECO2N fluid property package, but whereas ECO2N could represent only a single CO{sub 2}-rich phase, ECO2M can describe all possible phase conditions for brine-CO{sub 2} mixtures, including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO{sub 2}. This allows for seamless modeling of CO{sub 2} storage and leakage. Flow processes can be modeled isothermally or non-isothermally, and phase conditions represented may include a single (aqueous or CO{sub 2}-rich) phase, as well as two-and three-phase mixtures of aqueous, liquid CO{sub 2} and gaseous CO{sub 2} phases. Fluid phases may appear or disappear in the course of a simulation, and solid salt may precipitate or dissolve. TOUGH2/ECO2M is upwardly compatible with ECO2N and accepts ECO2N-style inputs. This report gives technical specifications of ECO2M and includes instructions for preparing input data. Code applications are illustrated by means of several sample problems, including problems that had been previously solved with TOUGH2/ECO2N.

  18. Lessons-Learned from D and D Activities at the Five Gaseous Diffusion Buildings (K-25, K- 27, K-29, K-31 and K-33) East Tennessee Technology Park, Oak Ridge, TN - 13574

    SciTech Connect (OSTI)

    Kopotic, James D. [United States Department of Energy, Oak Ridge Office, P.O. Box 2001, Oak Ridge, TN 37831 (United States)] [United States Department of Energy, Oak Ridge Office, P.O. Box 2001, Oak Ridge, TN 37831 (United States); Ferri, Mark S.; Buttram, Claude [URS - CH2M Oak Ridge LLC, East Tennessee Technology Park, P. O. Box 4699, Oak Ridge, TN 37831 (United States)] [URS - CH2M Oak Ridge LLC, East Tennessee Technology Park, P. O. Box 4699, Oak Ridge, TN 37831 (United States)

    2013-07-01

    The East Tennessee Technology Park (ETTP) is the site of five former gaseous diffusion plant (GDP) process buildings that were used to enrich uranium from 1945 to 1985. The process equipment in the original two buildings (K-25 and K-27) was used for the production of highly enriched uranium (HEU), while that in the three later buildings (K-29, K-31 and K-33) produced low enriched uranium (LEU). Equipment was contaminated primarily with uranium and to a lesser extent technetium (Tc). Decommissioning of the GDP process buildings has presented several unique challenges and produced many lessons-learned. Among these is the importance of good, up-front characterization in developing the best demolition approach. Also, chemical cleaning of process gas equipment and piping (PGE) prior to shutdown should be considered to minimize the amount of hold-up material that must be removed by demolition crews. Another lesson learned is to maintain shutdown buildings in a dry state to minimize structural degradation which can significantly complicate characterization, deactivation and demolition efforts. Perhaps the most important lesson learned is that decommissioning GDP process buildings is first and foremost a waste logistics challenge. Innovative solutions are required to effectively manage the sheer volume of waste generated from decontamination and demolition (D and D) of these enormous facilities. Finally, close coordination with Security is mandatory to effectively manage Special Nuclear Material (SNM) and classified equipment issues. (authors)

  19. Issues and recommendations related to replacement of CFC-114 at the uranium enrichment gaseous diffusion plant. Task title: Chlorofluorocarbon (CFC) Program Review, Final report, August 1, 1991--October 1, 1992

    SciTech Connect (OSTI)

    Anderson, B.L.; Banaghan, E.

    1993-03-31

    The operating uranium enrichment gaseous diffusion plants (GDPs) in Portsmouth, Ohio and Paducah, Kentucky, which are operated for the United States Department for Energy by Martin Marietta Energy Systems (MMES), currently use a chlorofluorocarbon (CFC-114) as the primary process stream coolant. Due to recent legislation embodied in the Clean Air Act, the production of this and other related chlorofluorocarbons (CFCS) are to be phased out with no production occurring after 1995. Since the plants lose approximately 500,000 pounds per year of this process stream coolant through various leaks, the GDPs are faced with the challenge of identifying a replacement coolant that will allow continued operation of the plants. MMES formed the CFC Task Team to identify and solve the various problems associated with identifying and implementing a replacement coolant. This report includes a review of the work performed by the CFC Task Team, and recommendations that were formulated based on this review and upon original work. The topics covered include; identifying a replacement coolant, coolant leak detection and repair efforts, coolant safety concerns, coolant level sensors, regulatory issues, and an analytical decision analysis.

  20. Refurbishment of uranium hexafluoride cylinder storage yards C-745-K, L, M, N, and P and construction of a new uranium hexafluoride cylinder storage yard (C-745-T) at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    1996-07-01

    The Paducah Gaseous Diffusion Plant (PGDP) is a uranium enrichment facility owned by the US Department of Energy (DOE). A residual of the uranium enrichment process is depleted uranium hexafluoride (UF6). Depleted UF6, a solid at ambient temperature, is stored in 32,200 steel cylinders that hold a maximum of 14 tons each. Storage conditions are suboptimal and have resulted in accelerated corrosion of cylinders, increasing the potential for a release of hazardous substances. Consequently, the DOE is proposing refurbishment of certain existing yards and construction of a new storage yard. This environmental assessment (EA) evaluates the impacts of the proposed action and no action and considers alternate sites for the proposed new storage yard. The proposed action includes (1) renovating five existing cylinder yards; (2) constructing a new UF6 storage yard; handling and onsite transport of cylinders among existing yards to accommodate construction; and (4) after refurbishment and construction, restacking of cylinders to meet spacing and inspection requirements. Based on the results of the analysis reported in the EA, DOE has determined that the proposed action is not a major Federal action that would significantly affect the quality of the human environment within the context of the National Environmental Policy Act of 1969. Therefore, DOE is issuing a Finding of No Significant Impact. Additionally, it is reported in this EA that the loss of less than one acre of wetlands at the proposed project site would not be a significant adverse impact.

  1. INDEPENDENT TECHNICAL REVIEW OF THE FOCUSED FEASIBILITY STUDY AND PROPOSED PLAN FOR DESIGNATED SOLID WASTE MANAGEMENT UNITS CONTRIBUTING TO THE SOUTHWEST GROUNDWATER PLUME AT THE PADUCAH GASEOUS DIFFUSION PLANT

    SciTech Connect (OSTI)

    Looney, B.; Eddy-Dilek, C.; Amidon, M.; Rossabi, J.; Stewart, L.

    2011-05-31

    The U. S. Department of Energy (DOE) is currently developing a Proposed Plan (PP) for remediation of designated sources of chlorinated solvents that contribute contamination to the Southwest (SW) Groundwater Plume at the Paducah Gaseous Diffusion Plant (PGDP), in Paducah, KY. The principal contaminants in the SW Plume are trichloroethene (TCE) and other volatile organic compounds (VOCs); these industrial solvents were used and disposed in various facilities and locations at PGDP. In the SW plume area, residual TCE sources are primarily in the fine-grained sediments of the Upper Continental Recharge System (UCRS), a partially saturated zone that delivers contaminants downward into the coarse-grained Regional Gravel Aquifer (RGA). The RGA serves as the significant lateral groundwater transport pathway for the plume. In the SW Plume area, the four main contributing TCE source units are: (1) Solid Waste Management Unit (SWMU) 1 / Oil Landfarm; (2) C-720 Building TCE Northeast Spill Site (SWMU 211A); (3) C-720 Building TCE Southeast Spill Site (SWMU 211B); and (4) C-747 Contaminated Burial Yard (SWMU 4). The PP presents the Preferred Alternatives for remediation of VOCs in the UCRS at the Oil Landfarm and the C-720 Building spill sites. The basis for the PP is documented in a Focused Feasibility Study (FFS) (DOE, 2011) and a Site Investigation Report (SI) (DOE, 2007). The SW plume is currently within the boundaries of PGDP (i.e., does not extend off-site). Nonetheless, reasonable mitigation of the multiple contaminant sources contributing to the SW plume is one of the necessary components identified in the PGDP End State Vision (DOE, 2005). Because of the importance of the proposed actions DOE assembled an Independent Technical Review (ITR) team to provide input and assistance in finalizing the PP.

  2. Gaseous Hydrogen Compression | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    reactions, metal hydrides, and ionic liquids. Electrochemical compressors use proton exchange membranes flanked by electrodes and an external power source to drive the...

  3. Gaseous Decomposition Products of Safety Powders

    E-Print Network [OSTI]

    Cubbison, C.E.

    1912-01-01

    x i d e 15 D e t e r m i n a t i o n o f Heavy Hydrocarbons — — 16 D e t e r m i n a t i o n o f Oxygen 18 D e t e r m i n a t i o n o f Carbon Monoxide 18 D e t e r m i n a t i o n o f Hydrogen and Methane 19 D e t e r m i n a t i o n o f n i... gases were then drawn o f f from the c y l i n d e r , c o l l e c t e d and the volume measured.A sample o f the gas was then taken and ana l y z ed f o r carbon d i ­ o x i d e , h e a v y hydrocarbons , oxygen, carbon monoxide, me thane...

  4. Sandia Energy - Particulate and Gaseous Emissions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    power generation boilers. The combustor consists of a 4.2 m long, 15 cm diameter silicon carbide reactor tube divided into seven independently heated sections. The MFC has...

  5. NOVEL TECHNOLOGIES FOR GASEOUS CONTAMINANTS CONTROL

    SciTech Connect (OSTI)

    B.S. Turk; T. Merkel; A. Lopez-Ortiz; R.P. Gupta; J.W. Portzer; G.N. Krishnan; B.D. Freeman; G.K. Fleming

    2001-09-30

    The overall objective of this project is to develop technologies for cleaning/conditioning the syngas from an integrated gasification combined cycle (IGCC) system to meet the tolerance limits for contaminants such as H{sub 2}S, COS, NH{sub 3}, HCN, HCl, and alkali for fuel cell and chemical production applications. RTI's approach is to develop a modular system that (1) removes reduced sulfur species to sub-ppm levels using a hybrid process consisting of a polymer membrane and a regenerable ZnO-coated monolith or a mixed metal oxide sorbent; (2) removes hydrogen chloride vapors to sub-ppm levels using an inexpensive, high-surface area material; and (3) removes NH{sub 3} with acidic adsorbents. RTI is working with MEDAL, Inc., and North Carolina State University (NCSU) to develop polymer membrane technology for bulk removal of H{sub 2}S from syngas. These membranes are being engineered to remove the acid gas components (H{sub 2}S, CO{sub 2}, NH{sub 3}, and H{sub 2}O) from syngas by focusing on the ''solubility selectivity'' of the novel polymer compositions. The desirable components of the syngas (H{sub 2} and CO) are maintained at high-pressure conditions as a non-permeate stream while the impurities are transported across the membrane to the low pressure side. RTI tested commercially available and novel materials from MEDAL using a high-temperature, high-pressure (HTHP) permeation apparatus. H{sub 2}S/H{sub 2} selectivities >30 were achieved, although there was a strong negative dependence with temperature. MEDAL believes that all the polymer compositions tested so far can be prepared as hollow fiber membrane modules using the existing manufacturing technology. For fuel cell and chemical applications, additional sulfur removal (beyond that achievable with the membranes) is required. To overcome limitations of conventional ZnO pellets, RTI is testing a monolith with a thin coating of high surface area zinc-oxide based materials. Alternatively, a regenerable sorbent developed by DOE/NETL (RVS-1) is being evaluated for this application. A multi-cycle test of 2-in. (5-cm) diameter monolith samples demonstrated that <0.5 ppm sulfur can be achieved. Removal of HCl vapors is being accomplished by low-cost materials that combine the known effectiveness of sodium carbonate as an active matrix used with enhanced surface area supports for greater reactivity and capacity at the required operating temperatures. RTI is working with SRI International on this task. Sorbents prepared using diatomaceous earth and sepiolite, impregnated with sodium carbonate achieved steady-state HCl level <100 ppb (target is 10 ppb). Research is continuing to optimize the impregnation and calcination procedures to provide an optimum pore size distribution and other properties. RTI and SRI International have established the feasibility of a process to selectively chemisorb NH3 from syngas on high surface area molecular sieve adsorbents at high temperatures by conducting a series of temperature-programmed reactions at 225 C (437 F). Significant levels of NH{sub 3} were adsorbed on highly acidic adsorbents; the adsorbed NH{sub 3} was subsequently recovered by heating the adsorbent and the regenerated adsorbent was reused. A comprehensive technical and economic evaluation of this modular gas cleaning process was conducted by Nexant to compare capital and operating cost with existing amine based processes. Nexant estimated a total installed cost of $42 million for the RTI process for a 500 MWe IGCC plant based on its current state of development. By comparison, Nexant estimated the installed cost for an equivalent sized plant based on the Rectisol process (which would achieve the same sulfur removal specification) to be $75 million. Thus the RTI process is economically competitive with a state-of-the-art process for syngas cleanup.

  6. School science project 'demystifies' Portsmouth Gaseous Diffusion...

    Broader source: Energy.gov (indexed) [DOE]

    plus I learned a lot," Tolle said. "I really enjoyed (Fluor-B&W subject matter expert) Marc Hill who explained all the things that go on for historic preservation. We all learned...

  7. Portsmouth Gaseous Diffusion Plant Director's Final Findings...

    Office of Environmental Management (EM)

    Bechtel Jacobs Company LLC; State of Ohio Environmental Protection Agency Date 3181999 SCOPE * Integrate the on-site closure work required for specific units to avoid...

  8. Portsmouth Gaseous Diffusion Plant Director's Final Findings...

    Office of Environmental Management (EM)

    Protection ("Director") under Chapters 3734. and 3745. of the Ohio Revised Code ("ORC"). Go to Table of Contents II. Parties Bound These Orders shall apply to and be binding...

  9. Gaseous Sulfate Solubility in Glass: Experimental Method

    SciTech Connect (OSTI)

    Bliss, Mary

    2013-11-30

    Sulfate solubility in glass is a key parameter in many commercial glasses and nuclear waste glasses. This report summarizes key publications specific to sulfate solubility experimental methods and the underlying physical chemistry calculations. The published methods and experimental data are used to verify the calculations in this report and are expanded to a range of current technical interest. The calculations and experimental methods described in this report will guide several experiments on sulfate solubility and saturation for the Hanford Waste Treatment Plant Enhanced Waste Glass Models effort. There are several tables of sulfate gas equilibrium values at high temperature to guide experimental gas mixing and to achieve desired SO3 levels. This report also describes the necessary equipment and best practices to perform sulfate saturation experiments for molten glasses. Results and findings will be published when experimental work is finished and this report is validated from the data obtained.

  10. The Promise of Renewable Gaseous Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    drop-in fuel by 2025 16 Opportunity Areas Use of dedicated energy crops to produce methane Co-production of methane and hydrogen with other products Joint deployment...

  11. Observational consequencies of baryonic gaseous dark matter

    E-Print Network [OSTI]

    Shchekinov, Yu A

    1998-01-01

    Possible observational consequencies of dark matter in the Galaxy in the form of dense molecular gas clouds -- clumpuscules of masses $M_c\\sim 10^{-3}~\\msun$ and radii $R_c\\sim 3\\times 10^{13}$ cm -- are considered. Recent models of the extreme scattering events -- refraction of radio-waves from quasars in dense plasma clumps in the Galactic halo -- definitely show on such clouds as possible dark matter candidate. We arugue that collisions of such clumpuscules are quite frequent: around $1-10~\\msun$ a year can be ejected in the intestellar medium due to collisions. Optical continuum and 21 cm emissions from post-collisional gas are found to be observable. We show that clumpuscules can form around O stars HII regions of sizes $R\\sim 30$ pc and emission measure $EM\\simeq 20$ cm$^{-6}$ pc, and can also be observable in $H_\\alpha$ emission. Evaporation of clumpuscules by external ionising radiation can be a substantial mass source. From requirement that the total mass input on the Hubble time cannot exceed the lu...

  12. Observational consequences of baryonic gaseous dark matter

    E-Print Network [OSTI]

    Yu. A. Shchekinov

    1998-12-03

    Possible observational consequences of dark matter in the Galaxy in the form of dense molecular gas clouds - clumpuscules of masses $M_c\\sim 10^{-3} \\msun$ and radii $R_c\\sim 3\\times 10^{13}$ cm - are considered. Recent models of the extreme scattering events - refraction of radio-waves from quasars in dense plasma clumps in the Galactic halo - definitely show on such clouds as possible dark matter candidate. We argue that collisions of such clumpuscules are quite frequent: around $1-10 \\msun$ a year can be ejected in the interstellar medium due to collisions. Optical continuum and 21 cm emissions from post-collisional gas are found to be observable. We show that clumpuscules can form around O stars HII regions of sizes $R\\sim 30$ pc and emission measure $EM\\simeq 20 cm^{-6}$ pc, and can also be observable in $H_\\alpha$ emission. Evaporation of clumpuscules by external ionizing radiation can be a substantial mass source. From requirement that the total mass input on the Hubble time cannot exceed the luminous mass in the Galaxy, typical radius of clouds is constrained as $R_c energy of the gas ejected by such clouds can be an efficient energy source for the Galactic halo.

  13. Independent Oversight Review, Portsmouth Gaseous Diffusion Plant...

    Broader source: Energy.gov (indexed) [DOE]

    Review, Paducah Site - April 2013 Independent Oversight Review, Hanford Site - September 2013 Enterprise Assessments Review, West Valley Demonstration Project - December 2014...

  14. Gaseous and particulate contamination in space 

    E-Print Network [OSTI]

    Yang, Xiaofang

    1989-01-01

    ?w??effect on the NC'Ds is plotted for water at 300 km altitude in Fsgure 7. assuming that the observer is at the coordinates of (rpv, ? 0, rp, ? 1 m). YVhen the parameter Daway value is less than 0. 1 meter, the tangentsal or x-direction distance at which...

  15. Independent Oversight Review, Portsmouth Gaseous Diffusion Plant -

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-inPPLforLDRD Report11,SecurityHomeRemarks As PreparedMembers||November 2013 |

  16. Safetygram Gaseous Hydrogen | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo. 195 -RobSSL IN PRACTICERENEWABLEExample Safetyand

  17. Portsmouth Gaseous Diffusion Plant | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested PartiesBuilding energy codesPhiladelhiaPolicyTechnologies |Department

  18. First gaseous boronization during pulsed discharge cleaning

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journal Article) |Final Reportthe GrowingDirectProofof Energy

  19. Gaseous Hydrogen Compression | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuelsof Energy Services »Information ResourcesHeat &Department of

  20. Gaseous Hydrogen Delivery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuelsof Energy Services »Information ResourcesHeat &Department ofDelivery

  1. Renewable and alteRnative eneRgy Fact Sheet College of Agricultural Sciences Agricultural Research and Cooperative Extension

    E-Print Network [OSTI]

    Boyer, Elizabeth W.

    using ethanol rather than methanol, the resulting molecules are"fatty acid ethyl esters hand, consists of about 95 percent saturated hydrocar- bons and 5 percent aromatic compounds.1

  2. Vanadyl tert-Butoxy Orthosilicate, OV[OSi(OtBu)3]3: A Model for Isolated Vanadyl Sites on Silica and a

    E-Print Network [OSTI]

    Iglesia, Enrique

    performance for propane oxidative dehydrogenation. Introduction The direct oxidation of organic compounds combustion. For this reason, studies on the selective oxidation of hydrocar- bons have focused on metal oxide

  3. Published: October 04, 2011 r 2011 American Chemical Society 23008 dx.doi.org/10.1021/jp207350r |J. Phys. Chem. C 2011, 115, 2300823012

    E-Print Network [OSTI]

    Alavi, Ali

    Information ' INTRODUCTION Adsorbed hydroxyl (OHad) is a key intermediate in many catalytic reactions over transition metals. For Pt, these include oxidations of organic molecules, steam reforming of hydrocar- bons

  4. GEOPHYSICS, VOL. 71, NO. 2 (MARCH-APRIL 2006); P. G43G51, 11 FIGS., 1 TABLE. 10.1190/1.2187748

    E-Print Network [OSTI]

    Constable, Steve

    to assess the resistivity of potential hydrocar- bon reservoirs before drilling. We examine the sensitiv information on the porosity and pore geometry of geologic formations as well as the nature of the fluids

  5. Development of Micro-Encapsulated Phase Change Materials and W. Brownrigg

    E-Print Network [OSTI]

    ) are often used as heat storage media, providing heat buffering to thermal systems. Conventional PCMs have. Paraffins are constructed of a combination of straight chain hydrocarbons. Their chemical inertness

  6. In situ carbonyl extraction of Ni from gaseous diffusion cells

    SciTech Connect (OSTI)

    Visnapuu, A. [USBM Salt Lake Research Center, Salt Lake City, UT (United States); Hollenberg, G.W. [Battelle Pacific Northwest Lab., Richland, WA (United States); Bundy, R.D. [Battelle Memorial Institute, Oak Ridge, TN (United States)

    1995-12-31

    This paper discusses the use of carbonyl processing technology for recovery of nickel from uranium isotope separation diffusion cells, and potential applications to recover nickel, iron, chromium, cobalt, and other carbonyl forming metals from nuclear waste while reducing the volume of the high level residue for more economic disposal. Nickel powder was carbonylated under static and dynamic conditions using only carbon monoxide to determine if the nickel powder would react rapidly enough to require no promoter. Nickel to Ni(CO){sub 4} conversion was realized in all cases and nickel metal was vapor deposited in the thermal decomposer, but the conversion rates in all cases the reaction were too slow for practical recovery. Addition of hydrogen sulfide gas as a promoter increased the conversion rate more than 500-fold over conversion with no promoter. Test summaries are provided in the paper; results indicate that promoter activated carbonylation is a viable approach for recovery of nickel from uranium isotope diffusion cells.

  7. Process for the removal of acid gases from gaseous streams

    SciTech Connect (OSTI)

    Blytas, G.C.; Diaz, Z.

    1982-11-16

    Hydrogen sulfide, carbon dioxide, and carbonyl sulfide are removed from a gas stream in a staged procedure by: absorption of the CO/sub 2/ and COS; conversion of the hydrogen sulfide to produce sulfur in an absorbent mixture; hydrolysis of the carbonyl sulfide to produce a gas stream of hydrogen sulfide and carbon dioxide; and removal of the hydrogen sulfide from the gas stream.

  8. FEDERAL FACILITY AGREEMENT FOR THE PADUCAH GASEOUS DIFFUSION...

    Office of Environmental Management (EM)

    hazardous waste, hazardous constituent or hazardous substance which is not from a solid waste management unit and which poses a current or potential threat to human health or the...

  9. Paducah Gaseous Diffusion Plant - GW OU Southwest Plume | Department...

    Office of Environmental Management (EM)

    soils - 2015 start date). REMEDIAL APPROACH: Record of Decision for Solid Waste Management Units 1, 211-A, 211-B, and Part of 102 Volatile Organic Compound Sources...

  10. Mechanistic Aspects of Pyrite Oxidation in an Oxidizing Gaseous

    E-Print Network [OSTI]

    Sparks, Donald L.

    to molecularoxygenandwaterleadstowidespreadoccurrences of acid wastewaters near coal mines, metal mines, and other areas with pyritic rock exposed. Acid blocking surface sites for O2 adsorption. The extent of oxygen incorporation from either the H2O or the O2 component into the surface-bound sulfur oxyanion product appears to be a strong function of the relative

  11. Dissolved gaseous mercury behavior in shallow water estuaries 

    E-Print Network [OSTI]

    Landin, Charles Melchor

    2009-05-15

    , increased wind speed should enhance air to water transfer of elemental mercury, thus one would expect a negative correlation. DGM co-varied negatively with salinity during the continuous studies, suggesting that the DGM pool is reduced in surface waters...

  12. Supporting Information for Historical gaseous and primary aerosol emissions in

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    External Combustion Boilers Natural Gas - 2103006XXX Stationary Source Fuel Combustion LPG 103010XXX External Combustion Boilers Liquified Petroleum Gas (LPG) - 2103007XXX Stationary Source Fuel Combustion 2104006XXX Natural Gas - LPG 2104007XXX Liquified Petroleum Gas (LPG) - #12;Wood 2104008XXX Wood PM

  13. Detector for flow abnormalities in gaseous diffusion plant compressors

    DOE Patents [OSTI]

    Smith, Stephen F. (Loudon, TN); Castleberry, Kim N. (Harriman, TN)

    1998-01-01

    A detector detects a flow abnormality in a plant compressor which outputs a motor current signal. The detector includes a demodulator/lowpass filter demodulating and filtering the motor current signal producing a demodulated signal, and first, second, third and fourth bandpass filters connected to the demodulator/lowpass filter, and filtering the demodulated signal in accordance with first, second, third and fourth bandpass frequencies generating first, second, third and fourth filtered signals having first, second, third and fourth amplitudes. The detector also includes first, second, third and fourth amplitude detectors connected to the first, second, third and fourth bandpass filters respectively, and detecting the first, second, third and fourth amplitudes, and first and second adders connected to the first and fourth amplitude detectors and the second and third amplitude detectors respectively, and adding the first and fourth amplitudes and the second and third amplitudes respectively generating first and second added signals. Finally, the detector includes a comparator, connected to the first and second adders, and comparing the first and second added signals and detecting the abnormal condition in the plant compressor when the second added signal exceeds the first added signal by a predetermined value.

  14. Detector for flow abnormalities in gaseous diffusion plant compressors

    DOE Patents [OSTI]

    Smith, S.F.; Castleberry, K.N.

    1998-06-16

    A detector detects a flow abnormality in a plant compressor which outputs a motor current signal. The detector includes a demodulator/lowpass filter demodulating and filtering the motor current signal producing a demodulated signal, and first, second, third and fourth bandpass filters connected to the demodulator/lowpass filter, and filtering the demodulated signal in accordance with first, second, third and fourth bandpass frequencies generating first, second, third and fourth filtered signals having first, second, third and fourth amplitudes. The detector also includes first, second, third and fourth amplitude detectors connected to the first, second, third and fourth bandpass filters respectively, and detecting the first, second, third and fourth amplitudes, and first and second adders connected to the first and fourth amplitude detectors and the second and third amplitude detectors respectively, and adding the first and fourth amplitudes and the second and third amplitudes respectively generating first and second added signals. Finally, the detector includes a comparator, connected to the first and second adders, and comparing the first and second added signals and detecting the abnormal condition in the plant compressor when the second added signal exceeds the first added signal by a predetermined value. 6 figs.

  15. Breached cylinder incident at the Portsmouth gaseous diffusion plant

    SciTech Connect (OSTI)

    Boelens, R.A. [Martin Marietta Energy Systems, Inc., Piketon, OH (United States)

    1991-12-31

    On June 16, 1990, during an inspection of valves on partially depleted product storage cylinders, a 14-ton partially depleted product cylinder was discovered breached. The cylinder had been placed in long-term storage in 1977 on the top row of Portsmouth`s (two rows high) storage area. The breach was observed when an inspector noticed a pile of green material along side of the cylinder. The breach was estimated to be approximately 8- inches wide and 16-inches long, and ran under the first stiffening ring of the cylinder. During the continuing inspection of the storage area, a second 14-ton product cylinder was discovered breached. This cylinder was stacked on the bottom row in the storage area in 1986. This breach was also located adjacent to a stiffening ring. This paper will discuss the contributing factors of the breaching of the cylinders, the immediate response, subsequent actions in support of the investigation, and corrective actions.

  16. Synthesis of thin films and materials utilizing a gaseous catalyst

    DOE Patents [OSTI]

    Morse, Daniel E; Schwenzer, Birgit; Gomm, John R; Roth, Kristian M; Heiken, Brandon; Brutchey, Richard

    2013-10-29

    A method for the fabrication of nanostructured semiconducting, photoconductive, photovoltaic, optoelectronic and electrical battery thin films and materials at low temperature, with no molecular template and no organic contaminants. High-quality metal oxide semiconductor, photovoltaic and optoelectronic materials can be fabricated with nanometer-scale dimensions and high dopant densities through the use of low-temperature biologically inspired synthesis routes, without the use of any biological or biochemical templates.

  17. DOE Awards Contract for Paducah Gaseous Diffusion Plant Infrastructure...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    maintenance and repair of facilities; janitorial services; grounds maintenance, snow removal, and pest control; roadwayparking lot maintenance; computing,...

  18. MICROWAVE SPECTROMETER FOR THE DETECTION OF TRANSIENT GASEOUS SPECIES

    E-Print Network [OSTI]

    Kolbe, W.F.

    2011-01-01

    for Computer Control of Microwave Spectrometers, LBL-9276,and H. P. Broida, "Microwave Discharge Cavities Operating atJr. , and C. H. Townes, "Microwave Spectra of the Free

  19. Characterization of Gaseous Effluents from Modeling of LWIR Hyperspectral Measurements*

    E-Print Network [OSTI]

    Kerekes, John

    and geologic conditions over a large region. Volcanic eruptions produce large amounts of SO2, H2O and CO2 which scenes which contain effluent emissions from a stack or other source provides the initial foundation Longwave Infrared (LWIR) radiation comprising atmospheric and surface emissions provides information

  20. Mevva ion source operated in purely gaseous mode

    E-Print Network [OSTI]

    Yushkov, G.Y.; MacGill, R.A.; Brown, I.G.

    2003-01-01

    introduced into the vacuum arc plasma discharge so as toto replace the vacuum arc as plasma formation mechanism by aarc cathode), a hollow cathode glow discharge plasma [10-12

  1. Orientation Visit to the Portsmouth Gaseous Diffusion Plant

    Office of Environmental Management (EM)

    Service Activity (UESA) Storage Building and Associated Outside Storage, and the DUF6 Conversion Facility. The tours gave the site lead the opportunity to interact with...

  2. Origin of gaseous hydrocarbons in east-central Texas groundwaters 

    E-Print Network [OSTI]

    Coffman, Bryan Keith

    1988-01-01

    in flow direction due to pumping at the Bryan well fields (after Follett, 1974). 13 6 Structure map on the top of the Queen City Formation and approximate thickness of sand containing fresh to slightly saline water in Brazos and Burleson Counties... The approximate ' C/ C ratios produced from or associated with different sources (1-4) and sinks (5) of COs . 41 5 Well owners, location of sample outlet, head gas abundance and casing material for wells sampled in this study. 53 6 Hydrocarbon concentration...

  3. Dissolved gaseous mercury behavior in shallow water estuaries 

    E-Print Network [OSTI]

    Landin, Charles Melchor

    2008-10-10

    , Gary A. Gill, for helping me as much as he did with this thesis, both as a mentor and financially. I would also like to thank him for the tremendous amount of patience and understanding he had for me during this long endeavor. I am also grateful... with collecting my data in California. Last but not least, to Peter Santschi, who took the helm as my committee chair when Gary left and whose confidence in me gave me the inspiration and motivation to finish this work. And I would like to thank Robert Duce...

  4. Column Density Profiles of Multi-Phase Gaseous Halos

    E-Print Network [OSTI]

    Liang, Cameron J; Agertz, Oscar

    2015-01-01

    We present a suite of high-resolution cosmological galaxy re-simulations of a Milky-Way size halo with variety of star-formation and feedback models to investigate the effects of the specific details of the star formation-feedback loop modeling on the observable properties of the circumgalactic medium (CGM). We show that properties of the CGM are quite sensitive to the details of star formation-feedback loop. The simulation which produces a very realistic late-type central galaxy fails to reproduce existing observations of CGM. At the same time, variations of parameters of star formation recipe or feedback modeling, such as cosmic rays feedback, brings predicted CGM in better agreement with observations. The simulations show that the column density profiles of ions arising in such gas are well described by an exponential function of the impact parameter. Ions with higher ionization energy have more extended profiles with the scale height of the exponential distribution scaling as a power law of the ionization...

  5. Paducah Gaseous Diffusion Plant Draft Paducah Environmental Assessment...

    Office of Environmental Management (EM)

    the Draft EA. Written comments may submitted by the following methods: By Mail: Robert Smith, Paducah Strategic Planner Department of Energy-Paducah 5501 Hobbs Road C103 Kevil,...

  6. Inorganic Metal Fluorite Materials as Novel Adsorbents for Gaseous...

    Office of Scientific and Technical Information (OSTI)

    Type: Conference Resource Relation: Conference: International high level radioacvtive waste management conference held April 28 - May 2, 2013 in Albuquerque, NM.; Related...

  7. DOE Seeks Small Businesses for Portsmouth Gaseous Diffusion Plant...

    Broader source: Energy.gov (indexed) [DOE]

    , bill.taylor@srs.gov Cincinnati -- The U.S. Department of Energy (DOE) today issued a Draft Request for Proposal (RFP) seeking eligible small businesses under North American...

  8. Fuel age impacts on gaseous fission product capture during separations

    SciTech Connect (OSTI)

    Jubin, Robert T.; Soelberg, Nicolas R.; Strachan, Denis M.; Ilas, G.

    2012-09-21

    As a result of fuel reprocessing, volatile radionuclides will be released from the facility stack if no processes are put in place to remove them. The radionuclides that are of concern in this document are 3H, 14C, 85Kr, and 129 Rosnick 2007 I. The question we attempt to answer is how efficient must this removal process be for each of these radionuclides? To answer this question, we examine the three regulations that may impact the degree to which these radionuclides must be reduced before process gases can be released from the facility. These regulations are 40 CFR 61 (EPA 2010a), 40 CFR 190(EPA 2010b), and 10 CFR 20 (NRC 2012), and they apply to the total radonuclide release and to the dose to a particular organ – the thyroid. Because these doses can be divided amongst all the radionuclides in different ways and even within the four radionuclides in question, several cases are studied. These cases consider for the four analyzed radionuclides inventories produced for three fuel types—pressurized water reactor uranium oxide (PWR UOX), pressurized water reactor mixed oxide (PWR MOX), and advanced high-temperature gascooled reactor (AHTGR)—several burnup values and time out of reactor extending to 200 y. Doses to the maximum exposed individual (MEI) are calculated with the EPA code CAP-88 ( , 1992). Two dose cases are considered. The first case, perhaps unrealistic, assumes that all of the allowable dose is assigned to the volatile radionuclides. In lieu of this, for the second case a value of 10% of the allowable dose is arbitrarily selected to be assigned to the volatile radionuclides. The required decontamination factors (DFs) are calculated for both of these cases, including the case for the thyroid dose for which 14C and 129I are the main contributors. However, for completeness, for one fuel type and burnup, additional cases are provided, allowing 25% and 50% of the allowable dose to be assigned to the volatile radionuclides. Because 3H and 85Kr have relatively short half-lives, 12.3 y and 10.7 y, respectively, the dose decreases with the time from when the fuel is removed from the reactor to the time it is processed (herein “fuel age”). One possible strategy for limiting the discharges of these short halflife radionuclides is to allow the fuel to age to take advantage of radioactive decay. Therefore, the doses and required DFs are calculated as a function of fuel age. Here we calculate, given the above constraints and assumptions, the minimum ages for each fuel type that would not require additional effluent controls for the shorter half-life volatile radionuclides based on dose considerations. With respect to 129I doses, we find that the highest dose is calculated with iodine as a fine particulate. The dose scales as the fraction of the total 129I that is particulate. Therefore, we assume for all of our calculations that 100% of the 129I is particulate and allow the user of the results given here to scale our calculated doses to their needs. To summarize the data given in the body and appendices of this report, we find that the principal isotopes of concern are 3H and 129I, the latter requiring the highest DFs. The maximum DF value for 129I is 8000 for the illustrated cases. The required DF for 3H could be as high as 720, depending on the age of the fuel processed. The DF for 85Kr could be up to ~60, depending on fuel age. The DF for 14C is in many cases 1 (no treatment required) but could be as high as 30. The DFs required are within the range of DFs that are reported for the capture technologies that are available for the volatile radionuclides. Achieving the required 129I and 3H DFs is more challenging. Variations in stack design and other design factors may also significantly impact the DF requirements.

  9. The Thermodynamics of Gaseous, Cuprous Chloride Monomer and Trimer

    E-Print Network [OSTI]

    Brewer, Leo

    2010-01-01

    48B" with the Atomic Energy Commission in connection withDeclassified Atomic Energy Commission raper, CC-358,5,Common Gases" Atomic Energy Commission Declassified Report.

  10. Paducah Gaseous Diffusion Plant Compliance Order, September 10...

    Office of Environmental Management (EM)

    Agreed Order File No. NWM-30039-042 State Kentucky Agreement Type Consent Order Legal Driver(s) FFCAct Scope Summary Require compliance with an approved Site Treatment Plan and...

  11. Paducah Gaseous Diffusion Plant site environmental report for 1988

    SciTech Connect (OSTI)

    Rogers, J.G.; Jett, T.G.

    1989-05-01

    Quantities of nonradiological chemical emissions are not included in this report this year. An addendum that will include the information will be published after the Superfund Amendments Reauthorization Act (SARA) Title III report is issued on July 1, 1989. When the addendum is published, probably in late July, a summary of the SARA Title III 313 report will be included. The SARA report provides the community with the opportunity to lean about estimated quantities of certain toxic chemicals used at a facility that are routinely or accidentally released into the environment. The addendum that will be published after the SARA report will summarize the SARA report and is expected to include some additional large quantity'' chemicals used or stored at the facilities that are not required to be reported by SARA Title III but are known to be emitted from the facilities. The addendum will not be all inclusive but will provide emissions information on the major chemical emissions to the air, water, or land from processes at the facilities.

  12. Development of Compact Gaseous Sensors with Internal Reference...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NOx in Combustion Environments Compact sensors have been developed to allow for real-time monitoring of O2 and NOx during combustion. deer08singh.pdf More Documents & Publications...

  13. Environmental Effects on Gaseous Disks of the Virgo Spiral Galaxies

    E-Print Network [OSTI]

    Hiroyuki Nakanishi; Nario Kuno; Yoshiaki Sofue; Naoko Sato; Naomasa Nakai; Yasuhiro Shioya; Tomoka Tosaki; Sachiko Onodera; Kazuo Sorai; Fumi Egusa; Akihiko Hirota

    2006-10-27

    We found high molecular fractions ($f_{\\rm mol}$; ratio of the molecular to total gas surface densities) in three of five Virgo spiral galaxies in spite of their low total gas column density, based on $^{12}$CO$(J=1-0)$ observations with the Nobeyama 45 m telescope equipped with a multi-beam receiver, BEARS. We interpret this as a result of environmental effects. Combining the CO data with HI data, the relationship between the surface density of the total gas (HI plus H$_2$) and $f_{\\rm mol}$ indicates that the three galaxies near the cluster center have larger $f_{\\rm mol}$ values than expected for field galaxies, while the others show normal $f_{\\rm mol}$. The large $f_{\\rm mol}$ is interpreted as being due either to effective HI gas stripping, even in the inner disks, or to large ISM pressure induced by the high ICM pressure and/or ram pressure, although the possibility of an unusually high metallicity cannot be ruled out.

  14. Chapter 4 The Gaseous State Chemistry of Gases

    E-Print Network [OSTI]

    Ihee, Hyotcherl

    .15 V = V0[1+(t/273.15oC)] Kelvin T = 273.15 + t(Celsius) #12;Boyle's Law · The stirling engine, a heat engine invented by a Scottish minister, has been considered for use in automobile engines because of its efficiency. In such an engine, a gas goes through a four-step cycle of (1) expansion at constant T, (2

  15. Aqueous and gaseous nitrogen losses induced by fertilizer application

    E-Print Network [OSTI]

    Gu, C.

    2009-01-01

    from KNO 3 and the leachate fluxes from CO(NH 2 ) 2 wereB PB concentrations in leachate and surface water can also>KNO 3 (Figure 7 b). The leachate fluxes were B B B B B B B

  16. Continuous Fiber Ceramic Composite (CFCC) Program: Gaseous Nitridation

    SciTech Connect (OSTI)

    R. Suplinskas G. DiBona; W. Grant

    2001-10-29

    Textron has developed a mature process for the fabrication of continuous fiber ceramic composite (CFCC) tubes for application in the aluminum processing and casting industry. The major milestones in this project are System Composition; Matrix Formulation; Preform Fabrication; Nitridation; Material Characterization; Component Evaluation

  17. Gaseous missions rduction from arobic MBT of municipal solid waste

    E-Print Network [OSTI]

    Boyer, Edmond

    recovery (by collecting biogas generated during anaerobic digestion) and/or return of organic matter the composting process, and the sec- ond one focused on the biogas génération from the associated landfill surface fluxes and biogas composition. ineris-00973342,version1-4Apr2014 Author manuscript, published

  18. Method for direct conversion of gaseous hydrocarbons to liquids

    DOE Patents [OSTI]

    Kong, Peter C.; Lessing, Paul A.

    2006-03-07

    A chemical reactor for direct conversion of hydrocarbons includes a dielectric barrier discharge plasma cell and a solid oxide electrochemical cell in fluid communication therewith. The discharge plasma cell comprises a pair of electrodes separated by a dielectric material and passageway therebetween. The electrochemical cell comprises a mixed-conducting solid oxide electrolyte membrane tube positioned between a porous cathode and a porous anode, and a gas inlet tube for feeding oxygen containing gas to the porous cathode. An inlet is provided for feeding hydrocarbons to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a light source for directing ultraviolet light into the discharge plasma cell and the electrochemical cell.

  19. Senior DOE Officials Visit Paducah Gaseous Diffusion Plant Site...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    resistance heating as part of the trichloroethene remediation at the C-400 groundwater contamination source with David Klaus, DOE Deputy Under Secretary for Management...

  20. Independent Activity Report, Portsmouth Gaseous Diffusion Plant - August

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (BillionProvedTravelInformation Resources » GeothermalPerformance withto HuntIanEnergyImproving2011

  1. Bioelectrochemical Treatment of Gaseous By-products - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O OLaura|Bilayer Graphene GetsBiodiesel - SSC Processis

  2. DOE - Office of Legacy Management -- Paducah Gaseous Diffusion Plant - KY

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth Dakota Edgemont,Manufacturing -Nevada TestOxnard Facility -

  3. DOE - Office of Legacy Management -- Portsmouth Gaseous Diffusion Plant -

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth Dakota Edgemont,Manufacturing0-19 Polytechnic Institute

  4. Property:PotentialBiopowerGaseousCapacity | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo,AltFuelVehicle2FlatDemandMonth3 Jump to: navigation, searchPhone Jump to:Plants

  5. Property:PotentialBiopowerGaseousGeneration | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo,AltFuelVehicle2FlatDemandMonth3 Jump to: navigation, searchPhone Jump

  6. Property:PotentialBiopowerGaseousMass | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo,AltFuelVehicle2FlatDemandMonth3 Jump to: navigation, searchPhone

  7. U.S. Supplemental Gaseous Fuels (Billion Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015"Separation, Proved Reserves(Million2009 2010 2011Decade6,015 6,980

  8. Orientation Visit to the Portsmouth Gaseous Diffusion Plant

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann Jackson About1996How to ApplytheExecutive71.1 OMB Field Element0|2008Newberry Volcano |HSS

  9. Paducah Gaseous Diffusion Plant Final Environmental Assessment for

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematics AndBeryllium Disease | DepartmentOLED StakeholderINL E-IDR (InventionOCIO

  10. Deactivation Project Begins at Paducah Gaseous Diffusion Plant | Department

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-in electricLaboratory | version of the1996ofDavid Friedman -LeeCompliance1

  11. EM Begins Demolishing K-31 Gaseous Diffusion Building | Department of

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-inPPL EnergyPlus, LLC to5USC787StatementDepartment's

  12. Energy Department Selects Deactivation Contractor for Paducah Gaseous

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-inPPLfor Innovative Solar Power PlantEnergyLawrence Berkeley, Oak

  13. Paducah Gaseous Diffusion Plant Draft Paducah Environmental Assessment for

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy AEnergyPresidential PermitDAYS - WE NEED A CHANGE OFNovember 2015 < prev

  14. NGPL Production, Gaseous Equivalent at Processing Plants (Summary)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963Residential2, 2014ProvedYear Jan Feb MarNGPL Production,

  15. Alaska--Onshore Natural Gas Plant Liquids Production, Gaseous Equivalent

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948 2,724 2,570Month PreviousDry Production

  16. Alaska--State Offshore Natural Gas Plant Liquids Production, Gaseous

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948 2,724 2,570Month PreviousDry

  17. California--State Offshore Natural Gas Plant Liquids Production, Gaseous

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0ProvedDecade2,948California (Million Cubic513,005

  18. Federal Offshore California Natural Gas Plant Liquids Production, Gaseous

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan Feb Mar Apr May Jun2003 DetailedThousand Cubic2009OverviewNA

  19. Gaseous Emissions From Steamboat Springs, Brady'S Hot Springs, And Desert

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoopButtePowerEdistoWhiskeyFootprintGEXA Corp. (Delaware)GalvestonWindSampling

  20. Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnicalInformation4563AbuseConnectJournal Article:(Journal Article)Article)solid

  1. Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield MunicipalTechnicalInformation4563AbuseConnectJournal Article:(Journal

  2. Lessons Learned from Practical Field Experience with High Pressure Gaseous

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICE INDUSTRIALU.S.Leadership on Clean Energys o u t h e aLessie00Fuels |

  3. DOE Releases Request for Information for Paducah Gaseous Diffusion Plant

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department ofRefrigeratorsDepartmentEP9425 701 9thofStatesDeactivation

  4. DOE Seeks Deactivation Contractor for Paducah Gaseous Diffusion Plant |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department8, 2015 GATEWAY Takes on Another1990,

  5. DOE Seeks Quotes for Paducah Gaseous Diffusion Plant Environmental

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department8, 2015 GATEWAY Takes on Another1990,EnergyProcess

  6. U.S. Supplemental Gaseous Fuels (Billion Cubic Feet)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With WIPP UPDATE: AprilCubicProductionSpent Nuclear Fuel

  7. Energy Department Completes K-25 Gaseous Diffusion Building Demolition |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015 Infographic courtesy of theSolarDepartment ofStorage

  8. Fuel Cells and Renewable Gaseous Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015ExecutiveFluorescentDanKathy LoftusFuel CellFuel Fuelgreen h y dFuel

  9. Senior DOE Officials Visit Paducah Gaseous Diffusion Plant Site |

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OF APPLICABLE DIRECTIVES Pursuant to theDepartment of|New Reports | Department

  10. School science project 'demystifies' Portsmouth Gaseous Diffusion Plant

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterestedReplacement-2-AA-1 SECTION JSTEM-ingEnglish).pdfItalian).pdfPerformance

  11. Independent Oversight Review, Portsmouth Gaseous Diffusion Plant - April

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergy HeadquartersFuelBConservation StandardsEnergy In2008 |of2013 |of Energy2013 |

  12. Independent Oversight Review, Portsmouth Gaseous Diffusion Plant - January

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergy HeadquartersFuelBConservation StandardsEnergy In2008 |of2013 |of Energy2013

  13. DOE Seeks Proposals for Portsmouth Gaseous Diffusion Plant Technical

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment ofOffice of Headquarters AccountingDOEEnergy DOE has

  14. K-25 Gaseous Diffusion Process Building | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuelsof EnergyApril 2014 | International Nuclear EnergyatJobsJointJoyceJune»

  15. DOE Issues Final Request for Proposal for Portsmouth Gaseous Diffusion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergy Webinar:IAbout Us »Buildings DOEDOE FCalculation |

  16. DOE Seeks Small Businesses for Portsmouth Gaseous Diffusion Plant

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergy Webinar:IAbout Us »BuildingsInfrastructure Support Services |

  17. Paducah Gaseous Diffusion Plant Transition | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuelsof EnergyAprilEnergy EEREPlateauFolsomProgress

  18. NGPL Production, Gaseous Equivalent at Processing Plants (Summary)

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,Decade Year-03.82 (MillionandIndustrialYear1371,024,082 1,066,366

  19. Texas--State Offshore Natural Gas Plant Liquids Production, Gaseous

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames5 Tables July 1996 Energy Information Administration Office of Coal, Nuclear,DecadeYearbyWithdrawalsHome6,672(Million Cubic8-2014Equivalent

  20. DOE Awards Contract for Paducah Gaseous Diffusion Plant Infrastructure

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-in electric vehicle10 DOE ASSESSMENTathasBestI) AprilSupport Services |

  1. DOE Seeks Small Businesses for Paducah Gaseous Diffusion Plant

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-in electric vehicle10nominateEnergyThisEnergy RequestInfrastructure

  2. Atmos. Chem. Phys., 9, 52815297, 2009 www.atmos-chem-phys.net/9/5281/2009/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    emissions of CH4, CO and H2 for one year. It is based on an atmospheric chemical transport model and on a simplified scheme for the oxidation chain of hydrocar- bons, including methane, formaldehyde, carbon monoxide that of methane (CH4), which is the second anthropogenic greenhouse gas after car- bon dioxide (CO2). Taking

  3. Atmos. Chem. Phys., 5, 26352656, 2005 www.atmos-chem-phys.org/acp/5/2635/

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of chemically active species, such as methane, re- quires a good knowledge of OH OH space and time varia- tions including methane (CH4), carbon monoxide (CO), Non-Methane Hydrocar- bons, and halogenated species by several authors to infer OH fields based on different methodologies (Krol et al., 2003; Den- tener et al

  4. Control-oriented input-delay model of the distributed temperature of a SI engine exhaust

    E-Print Network [OSTI]

    the combustion: hydrocar- bons HC, carbon monoxide CO and nitrogen oxide NOx. Yet, conversion efficiency Delphine, warm-up strategies are performed by increasing the exhaust gas tem- peratures via combustion timing shifting [8]. This open-loop technique leads to a faster heating of the catalyst but also yields combustion

  5. 4D imaging of fracturing in organic-rich shales during heating Maya Kobchenko,1

    E-Print Network [OSTI]

    Scheibert, Julien

    and pressure rise, and kerogen decomposes into low molecular weight hydrocar- bon fluids (gas and oil), which escape in low permeability rocks, we performed time-resolved in situ X-ray tomography imaging matter. Kerogen decomposition is thought to cause an internal pressure build up sufficient to form cracks

  6. USING A COGENERATION FACILITY ToIllustrateEngineeringPracticetoLower-LevelStudents

    E-Print Network [OSTI]

    Hesketh, Robert

    water-treatment sys- tems that may include membrane devices! The systems are equipped with pumps. Concentration measurements are made using NDIR gas analyzers for CO, C02 and total hydrocar- bons. And oxygen his as, MS, and PhD from Rulgers University. His teaching and research interests are in separation

  7. We present results from a transient electromagnetic exper-iment to detect hydrocarbons and to monitor their move-

    E-Print Network [OSTI]

    water-saturated reservoirs (low resistivity) and hydrocar- bon-saturated reservoirs (high resistivity to calculate the porosity and saturation of reservoir rocks. When the pore fluid within a rock changes from above the reservoir to approximately 400 Ohm-m in the gas-saturated reservoir. The main reason

  8. 2,3,7,8-Tetrachlorodibenzo-p-dioxin Induces Premature Activation of the KLF2 Regulon during

    E-Print Network [OSTI]

    Bradfield, Christopher A.

    2,3,7,8-Tetrachlorodibenzo-p-dioxin Induces Premature Activation of the KLF2 Regulon during, Wisconsin 53706 The environmental pollutant 2,3,7,8-tetrachlorodibenzo-p- dioxin (TCDD, dioxin) causes,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD)2 is the most toxic congener of a family of halogenated aromatic hydrocar- bons

  9. Atmos. Chem. Phys., 15, 30453062, 2015 www.atmos-chem-phys.net/15/3045/2015/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    compounds (OVOCs) are important products of the photo-oxidation of hydrocar- bons. They influence in formaldehyde (HCHO), acetaldehyde (CH3CHO), methyl ethyl ketone (MEK) and methanol were found to be 12.9, 15 Chemical Mechanism version 3.2 (MCM3.2) was applied to evaluate how OVOC production responds to the reduced

  10. Atmos. Chem. Phys., 10, 24132424, 2010 www.atmos-chem-phys.net/10/2413/2010/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    ), a region with a very high density of industrial/petrochemical operations. HCHO levels at the Moody Tower (HSC), which comprises large agglomerations of petrochemical industries (Kleinman et al., 2002; Daum et al., 2003, 2004; Ryerson et al., 2003; Berkowitz et al., 2005); the impact of non methane hydrocar

  11. Highly Selective Condensation of Biomass-Derived Methyl Ketones as a Source of Aviation Fuel

    E-Print Network [OSTI]

    Toste, Dean

    Highly Selective Condensation of Biomass-Derived Methyl Ketones as a Source of Aviation Fuel Eric R,[b] and Alexis T. Bell*[a] Introduction Aviation fuels must meet a number of stringent specifications, the most by branched and cyclic hydrocar- bons, and, consequently, these types of fuels are not likely to be displaced

  12. Phase change compositions

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1989-01-01

    Compositions containing crystalline, straight chain, alkyl hydrocarbons as phase change materials including cementitious compositions containing the alkyl hydrocarbons neat or in pellets or granules formed by incorporating the alkyl hydrocarbons in polymers or rubbers; and polymeric or elastomeric compositions containing alkyl hydrocarbons.

  13. Journal of Chemical Ecology, Vol. 28, No. 5, May 2002 (C 2002) EVALUATION OF SYNTHETIC HYDROCARBONS

    E-Print Network [OSTI]

    Hanks, Lawrence M.

    Journal of Chemical Ecology, Vol. 28, No. 5, May 2002 (C 2002) EVALUATION OF SYNTHETIC HYDROCARBONS of five straight-chain hydrocarbons (C24, C25, C26, C28, C30) to detached elytra of the red milkweed, and placed them in an exposed location outdoors. The amount of hydrocarbons on the elytra did not change over

  14. Method for measuring particulate and gaseous metals in a fluid stream, device for measuring particulate and gaseous metals in a fluid stream

    DOE Patents [OSTI]

    Farber, Paul S. (Willowbrook, IL); Huang, Hann-Shen (Westmont, IL)

    2001-01-01

    A method for analyzing metal in a fluid is provided comprising maintaining a first portion of a continuous filter media substrate at a temperature coinciding with the phase in which the metal is to be analyzed; contacting the fluid to a first portion of said substrate to retain the metal on the first portion of said substrate; preventing further contact of the fluid to the first portion of substrate; and contacting the fluid to a second portion of said substrate to retain metal on the second portion of the said substrate while simultaneously analyzing the first portion for metal. Also provided is a device for the simultaneous monitoring and analysis of metal in a fluid comprising a continuous filter media substrate; means for maintaining a first portion of said filter media substrate at a temperature coinciding with the phase in which the metal is to be analyzed; a means for contacting the fluid to the first portion of said substrate; a means for preventing further contact of the fluid to the first portion of substrate; a means for contacting the fluid to a second portion of said substrate to retain metal on the second portion of the said substrate; and means for analyzing the first portion for metal.

  15. Enterprise Assessments Review of Radioactive Waste Management at the Portsmouth Gaseous Diffusion Plant … December 2015

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergy HeadquartersFuelB IMSof 2005 at Iowa WindEnergy1-03 -1EnergyEAofPlantat the

  16. Proposed On-Site Disposal Facility (OSDF) at the Paducah Gaseous...

    Office of Environmental Management (EM)

    in the vadose zone). These alternatives to conventional ground water monitoring and assessment could persuade the regulatory agency to allow siting in a brownfield area. USACOE...

  17. Integrated Advanced Reciprocating Internal Combustion Engine System for Increased Utilization of Gaseous Opportunity Fuels

    SciTech Connect (OSTI)

    Pratapas, John; Zelepouga, Serguei; Gnatenko, Vitaliy; Saveliev, Alexei; Jangale, Vilas; Li, Hailin; Getz, Timothy; Mather, Daniel

    2013-08-31

    The project is addressing barriers to or opportunities for increasing distributed generation (DG)/combined heat and power (CHP) use in industrial applications using renewable/opportunity fuels. This project brings together novel gas quality sensor (GQS) technology with engine management for opportunity fuels such as landfill gas, digester gas and coal bed methane. By providing the capability for near real-time monitoring of the composition of these opportunity fuels, the GQS output can be used to improve the performance, increase efficiency, raise system reliability, and provide improved project economics and reduced emissions for engines used in distributed generation and combined heat and power.

  18. Atmospheric Escape by Magnetically Driven Wind from Gaseous Planets II --Effects of Magnetic Diffusion--

    E-Print Network [OSTI]

    Tanaka, Yuki A; Inutsuka, Shu-ichiro

    2015-01-01

    We investigate roles of Alfvenic waves in the weakly-ionized atmosphere of hot Jupiters by carrying out non-ideal magnetohydrodynamic (MHD) simulations with Ohmic diffusion in one-dimensional magnetic flux tubes. Turbulence at the surface excites Alfven waves and they propagate upward to drive hot (~ 10^4 K) outflows. The magnetic diffusion plays an important role in the dissipation of the Alfvenic waves in the weakly ionized atmosphere of hot Jupiters. The mass-loss rate of the spontaneously driven planetary wind is considerably reduced, in comparison with that obtained from ideal MHD simulations because the Alfvenic waves are severely damped at low altitudes in the atmosphere, whereas the wave heating is still important in the heating of the upper atmosphere. Dependence on the surface temperature, planetary radius, and velocity dispersion at the surface is also investigated. We find an inversion phenomenon of the transmitted wave energy flux; the energy flux carried by Alfven waves in the upper atmosphere h...

  19. Studies of isotopic exchange between gaseous hydrogen and palladium hydride powder

    SciTech Connect (OSTI)

    Foltz, G.W.; Melius, C.F.

    1987-12-01

    A gas flow apparatus has been constructed and used to study the isotopic exchange reaction occurring between the solid and gas phases in hydrogen (deuterium) gas flows directed through packed-powder beds of ..beta..-phase palladium deuteride (hydride). Spontaneous Raman light scattering is employed to obtain a real-time analysis of the isotopic composition of the gas (H/sub 2/, D/sub 2/, HD) exiting from the bed. A parametric rate-equation model is described which depicts the time-dependent behavior of the isotopic exchange process. The exchange mechanism is assumed to be rate-limited by processes occurring on the surface of the powder. The fundamental kinetic parameter of the model is the isotopic exchange probability, p, which is the probability that an isotopic exchange event occurs during a collision of a gas-phase atom with the surface. Isotope effects between the gas and solid phases are explicitly included in terms of the isotope separation factor, ..cap alpha... Results of the model are compared with the experimental measurements and, using a literature value of ..cap alpha.. = 2.4, good agreement is obtained for p approx. = 10/sup -7/. In view of the importance of the isotope effects in the hydrogen/palladium system and the range of a values reported for the ..beta..-phase in the literature, the sensitivity of the model results to a variation in the value of ..cap alpha.. is examined.

  20. Characterization of atmospheric ammonia near Fort Worth, TX Part I. Dynamics of gaseous ammonia

    E-Print Network [OSTI]

    Hampshire, Durham, NH, USA 7 Earth and Sun Systems Laboratory, Atmospheric Chemistry Division, National of the region. The dynamic behavior of NH319 highlights its importance in atmospheric chemistry and indicates (NH3) plays a significant role in atmospheric2 chemistry. It is emitted into the atmosphere from

  1. Methods and compositions for removing carbon dioxide from a gaseous mixture

    DOE Patents [OSTI]

    Li, Jing; Wu, Haohan

    2014-06-24

    Provided is a method for adsorbing or separating carbon dioxide from a mixture of gases by passing the gas mixture through a porous three-dimensional polymeric coordination compound having a plurality of layers of two-dimensional arrays of repeating structural units, which results in a lower carbon dioxide content in the gas mixture. Thus, this invention provides useful compositions and methods for removal of greenhouse gases, in particular CO.sub.2, from industrial flue gases or from the atmosphere.

  2. The determination of compressibility factors of gaseous butane-nitrogen mixtures in the gas phase 

    E-Print Network [OSTI]

    Evans, Robert Buckner

    1955-01-01

    butane in summer resulting from lowered gasoline volatility and various increasing supply factors will create fuel purchasing opportunities. It was found that in-place propane switching capability among manufacturers could be adapted to absorb all...

  3. Dynamic Chamber System to Measure Gaseous Compounds Emissions and Atmospheric-Biospheric Interactions

    E-Print Network [OSTI]

    Aneja, Viney P.

    : Dynamic chamber, Emissions, Ammonia, Nitrogen oxide, Hydrogen sulphide, Hydrogen peroxide Abstract agricultural soils where nitrogen-rich fertilizers have been applied. Ammonia-nitrogen (NH3-N) and reduced-liquid interface at swine waste treatment anaerobic storage lagoons, and agricultural fields. Similar chamber

  4. An apparatus for laboratory demonstrations of compressibility measurements on gaseous fluids 

    E-Print Network [OSTI]

    Baron, John Daniel

    1952-01-01

    imyarted by weights placed, on. s platform 'z'eating on ths yiston sixish is floating in oil. . Xn this mannex' the ~~ serves as a balance and the yrsssxkpe is msaeursd 'kjg-~s af the weights on the. eakkbraWd'yiston. This tpje Iof . Nxge"is' eayab1s... ~a+ are used with or eithout elestzical indicating contacts, Xn all eases the volume of the fluid is varied by injecting mercury into ths system bg means of a mercux~ yump or othsx suitable device, Xn ths eases shore visual insyeetion oi" the flui...

  5. ELECTRON-DRIVEN REACTIONS IN PROTO-PLANETARY ATMOSPHERES: METASTABLE ANIONS OF GASEOUS o-BENZYNE

    SciTech Connect (OSTI)

    Carelli, F.; Sebastianelli, F.; Baccarelli, I.; Gianturco, F. A.

    2010-03-20

    In this paper, we present an investigation into low-energy electron scattering (E < 15 eV) processes from a specific benzene-like polyatomic target such as ortho-benzyne, o-C{sub 6}H{sub 4}({sup 1}SIGMA), in order to gain a better understanding of the effects that possible low-lying metastable electron-attachment states could have on its nuclear fragmentation dynamics. The current importance of the dynamical evolution of this molecule lies in the fact that o-C{sub 6}H{sub 4} is considered to be relevant for the circumstellar synthesis of large polycyclic aromatic hydrocarbons (PAHs), as a precursor for C{sub 6}H{sub 6} production via ion-based ring closure reaction from C{sub 2}H{sub 2}. Our parameter-free scattering calculations are performed within the molecular reference frame, where we obtain the metastable anionic states for the nuclear equilibrium configuration and further characterize the properties of such transient anions with respect to those found earlier for the benzene molecule. Our quantum studies indicate that o-C{sub 6}H{sub 4} is a more efficient producer of compact, fairly long-lived anionic intermediates than benzene itself; hence, this should more rapidly enter the chemical reaction cycles of PAHs formation, thereby disappearing from possible direct observation as a stable anion.

  6. Calibration Effects for Laser-Induced Breakdown Spectroscopy of Gaseous Sample Streams

    E-Print Network [OSTI]

    Hahn, David W.

    when nebulizing either lead acetate, lead chloride, or lead nitrate. Cadmium revealed a 27% difference in analyte response when comparing nebulized solutions of cadmium nitrate and cadmium chloride. In experi.19 Calibration curves were generated for three analytes, namely, cadmium, lead, and zinc, and were

  7. High-frequency acoustic sensors for operation in a gaseous medium. Final report

    SciTech Connect (OSTI)

    Kino, G.S.

    1990-12-31

    Photothermal microscopy is a technique for measuring thermal properties on a small scale by using focused laser beams as heat sources and as temperature probes. Typically used for nondestructive evaluation (NDE) of materials, its main advantage is its ability to measure types of flaws that are not visible optically or acoustically. Because of the optical nature of photothermal microscopy, sub-micron resolutions can be obtained in many of these thermal measurements. The greatest limitation of these systems is their relatively poor signal-to-noise ratios and, consequently, slow imaging speeds. To circumvent this problem, a variety of approaches to the detection of thermal waves has been pursued in recent years. This thesis compares the relative merits of a common class of techniques that rely on direct observation of physical changes in the heated sample, including a novel approach to interferometric measurement of the thermal expansion. It is found that the optimum approach depends not only on the physical properties of the sample being studies, but also upon the resolution of the experiment and the damage threshold of the specimen. Finally, this dissertation describes the applications of photothermal microscopy to the study of the anisotropic thermal properties of the new high-{Tc} superconductors. By adding a high-vacuum cryostat to the microscope, the authors have been able to study the influence of the superconducting transition on the thermal conductivity. The measurements of the anisotropic thermal conductivity demonstrate that the heat flow along the superconducting planes is enhanced below the transition, and that no such enhancement exists in the non-superconducting direction. Material examined was Bi-Ca-Sr-Cu-O.

  8. Supporting Material for Seasonal Changes in Gaseous Elemental Mercury in Relation to Monsoon

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    determination in natural airs. 1. sampling introduction device; 2. six-way injection valves (injection-V1, -V2) Vent AFS Detection/ Data acquisition 3 4 P Vent P MFC Sample gas Ar gas 2 V2 Pump MFC Preconcentration gas Ar gas 2 V2 Pump MFCMFC Preconcentration/ desorption Sample/analytical trap Two-channel analysis

  9. Origin of gaseous hydrocarbons from Upper Cretaceous and Tertiary strata in the Piceance basin, western Colorado 

    E-Print Network [OSTI]

    Katz, David Jonathan

    1997-01-01

    ), and are chemically distinct and therefore Renetically different from gases between 2450 and 2791 M (513C ci =-37.9 +-O.2%og 813C C2 =-26.4 0?.5%09 CI/Cl-3 = 0.88 0?.01). Gases of the latter group were probably derived from coalbeds that comprise the Cameo Group...

  10. Method and apparatus for treating gaseous effluents from waste treatment systems

    DOE Patents [OSTI]

    Flannery, Philip A. (Ramsey, MT); Kujawa, Stephan T. (Butte, MT)

    2000-01-01

    Effluents from a waste treatment operation are incinerated and oxidized by passing the gases through an inductively coupled plasmas arc torch. The effluents are transformed into plasma within the torch. At extremely high plasma temperatures, the effluents quickly oxidize. The process results in high temperature oxidation of the gases without addition of any mass flow for introduction of energy.

  11. Gaseous and particulate water-soluble organic and inorganic nitrogen in rural air in southern Scotland 

    E-Print Network [OSTI]

    Gonzalez Benitez, Juan M; Cape, J Neil; Heal, Mathew R

    2010-01-01

    Simultaneous daily measurements of water-soluble organic nitrogen (WSON), ammonium and nitrate were made between July and November 2008 at a rural location in south-east Scotland, using a ‘Cofer’ nebulizing sampler for the gas phase and collection...

  12. Characterization of a Compact, High Resolution Readout System for Micro Pattern Gaseous Detectors

    E-Print Network [OSTI]

    Shi, L; Mjörnmark, U

    2013-01-01

    A Linear e^+e^- collider, either ILC or CLIC will be the next platform for high energy physics study to complement the LHC. Results discovered by LHC may need precision measurements before we can get full understanding of the physics. International collaborations are in the process to prepare both for the accelerator and for the experimental setup.

  13. Ab initio modeling of complex aqueous and gaseous systems containing nitrogen

    E-Print Network [OSTI]

    Ashcraft, Robert Wilson

    2008-01-01

    Nitrogen chemistry is ubiquitous in everyday life, from biological processes at ambient conditions to atmospheric chemistry at low pressures and temperatures to high-temperature combustion. Understanding the chemical ...

  14. Source term evaluation during seismic events in the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Kim, S.H.; Chen, N.C.J.; Schmidt, R.W.; Taleyarkhan, R.P.

    1996-12-30

    The 00 buildings are expected to collapse (per guidance from structure evaluation) during a seismic event in which acceleration level exceeds 0.15g. All roof beams may slip off supports, and collapse. Equipment may slip off from supports and fall onto the floor. The cell floor is also supposed to collapse due to structural instability and distortion due to excessive acceleration forces. Following structure collapse, expansion joints in the process piping and joints between the piping and equipment are expected to fail. Preliminary analysis showed that converters are likely to remain intact. The UF{sub 6} gas released from the break will rapidly interact with moisture in the air to produce UO{sub 2}F{sub 2} and HF with exothermic energy released of {approximately}0.32 MJ/kg of UF{sub 6} reacted. Depending on the degree of mixing between UF{sub 6} gas, its reaction products, air and freon (R-114), there may occur a strong buoyancy force to disperse UO{sub 2}F{sub 2} aerosol particles that are subjected to the gravitational force for settling. Such a chemical reaction will also occur inside the converters. A substantial amount of UF{sub 6} must be stagnated at the bottom of the converters. At the interface between this stagnated UF{sub 6} and air, UF{sub 6} gas will diffuse into the air, undergo the chemical reaction with moisture there, and eventually be released through the break. Furthermore, lubricant oil fire in the building, if it occurs, will enhance the UF{sub 6} release into the atmosphere. The purpose of this study is to evaluate source term (UO{sub 2}F{sub 2} and HF) during such a seismic event. This study takes an approach using multiple steps as follows: (1) Source term evaluation at the break due to mixing between UF{sub 6} and air along with thermal buoyancy induced by chemical reaction energy, (2) Evaluation of additional source term from the converters in which a substantial UF{sub 6} vapor remains, and (3) Source term evaluation with lubricant oil fire.

  15. Elucidating the solid, liquid and gaseous products from batch pyrolysis of cotton-gin trash. 

    E-Print Network [OSTI]

    Aquino, Froilan Ludana

    2009-05-15

    and 30 min settings, however, the HV of char was low and almost similar to the HV of CGT. A maximum gas yield of 40 wt.% was measured at 800°C and 60 min and the highest liquid yield of 30 wt.% was determined at 800°C and 30 min. In the modified pyrolysis...

  16. CROSSED BEAM REACTIVE SCATTERING OF OXYGEN ATOMS AND SURFACE SCATTERING STUDIES OF GASEOUS CONDENSATION

    E-Print Network [OSTI]

    Sibener, S.J.

    2010-01-01

    F. 0( D,) Production When dilute oxygen-helium gas mixturesoxygen-helium mixture for maximizing Of D ) production. D Ihelium mixtures (12S torr total pressure, 145 watts I The genera­ and have observed atomic hydrogen production.

  17. Pressure Relief Devices for High-Pressure Gaseous Storage Systems: Applicability to Hydrogen Technology

    SciTech Connect (OSTI)

    Kostival, A.; Rivkin, C.; Buttner, W.; Burgess, R.

    2013-11-01

    Pressure relief devices (PRDs) are viewed as essential safety measures for high-pressure gas storage and distribution systems. These devices are used to prevent the over-pressurization of gas storage vessels and distribution equipment, except in the application of certain toxic gases. PRDs play a critical role in the implementation of most high-pressure gas storage systems and anyone working with these devices should understand their function so they can be designed, installed, and maintained properly to prevent any potentially dangerous or fatal incidents. As such, the intention of this report is to introduce the reader to the function of the common types of PRDs currently used in industry. Since high-pressure hydrogen gas storage systems are being developed to support the growing hydrogen energy infrastructure, several recent failure incidents, specifically involving hydrogen, will be examined to demonstrate the results and possible mechanisms of a device failure. The applicable codes and standards, developed to minimize the risk of failure for PRDs, will also be reviewed. Finally, because PRDs are a critical component for the development of a successful hydrogen energy infrastructure, important considerations for pressure relief devices applied in a hydrogen gas environment will be explored.

  18. Laser utilizing a gaseous lasing medium and method for operating the same

    DOE Patents [OSTI]

    Zerr, B.A.

    1983-10-18

    The invention relates to an improvement in gas lasers and a method of operating the same. In one aspect, the invention is an improved method for operating a high-power gas laser. The improvement comprises introducing the gas lasing medium tangentially to the laser tube at a pressure establishing a forced vortex in the tube. The vortex defines an axially extending core region characterized by a low pressure and temperature relative to the gas inlet and the exterior of the vortex. An electrical discharge is established in the core region to initiate lasing of the gas. The gas discharge from the tube is passed through a diffuser. As in conventional gas lasers, firing results in a very abrupt increase in gas temperature and in severe disruption of the gas. However, the gas vortex, almost immediately restores the gas to its prefiring condition. That is, almost all of the waste heat is transferred radially to the laser wall, and the original gas-flow pattern is restored. As a result, the power output of the laser is increased significantly, and the laser firing repetition rate is markedly increased.

  19. Process and system for producing high-density pellets from a gaseous medium

    DOE Patents [OSTI]

    Foster, Christopher A. (Clinton, TN)

    1999-01-01

    A process and system for producing pellets of high density carbon dioxide or other gases utilize a chamber containing a plurality of cell-like freezing compartments within which ice is to be formed. A gas desired to be frozen into ice is introduced into the chamber while the internal pressure of the chamber is maintained at a level which is below the equilibrium triple pressure of the gas. The temperature of the freezing compartments is lowered to a temperature which is below the equilibrium vapor pressure temperature of the gas at the chamber pressure so that the gas condenses into ice within the compartments. The temperature of the freezing compartments is thereafter raised so that the ice is thereby released from and falls out of the compartments as pellets for collection.

  20. Velocity of sound measurements in gaseous per-fluorocarbons and their custom mixtures

    E-Print Network [OSTI]

    Vacek, V; Lindsay, S

    2000-01-01

    An inexpensive sonar instrument was prepared for measurements of sound velocity in two fluorocarbon vapors; per-fluoro-n-propane (C3F8), per-fluoro-n-butane (C4F10), and their custom mixtures. The apparatus, measurement principle and instrument software are described. All sound velocity measurements in per-fluorocarbons were made in the low pressure range between 0.01 and 0.4 MPa, and at temperatures between 253 and 303 K. The purity of the C3F8 and C4F10 samples was checked using gas chromatography. Uncertainties in the speed of sound measurements were better than ± 0.1 %. Comparisons were made with theoretical predictions of sound velocity for the two individual components. The instrument was then used for concentration monitoring of custom C3F8/C4F10 mixtures.

  1. Membrane loop process for separating carbon dioxide for use in gaseous form from flue gas

    DOE Patents [OSTI]

    Wijmans, Johannes G; Baker, Richard W; Merkel, Timothy C

    2014-10-07

    The invention is a process involving membrane-based gas separation for separating and recovering carbon dioxide emissions from combustion processes in partially concentrated form, and then transporting the carbon dioxide and using or storing it in a confined manner without concentrating it to high purity. The process of the invention involves building up the concentration of carbon dioxide in a gas flow loop between the combustion step and a membrane separation step. A portion of the carbon dioxide-enriched gas can then be withdrawn from this loop and transported, without the need to liquefy the gas or otherwise create a high-purity stream, to a destination where it is used or confined, preferably in an environmentally benign manner.

  2. Computational fluid dynamic simulations of chemical looping fuel reactors utilizing gaseous fuels

    SciTech Connect (OSTI)

    Mahalatkar, K.; Kuhlman, J.; Huckaby, E.D.; O'Brien, T.

    2011-01-01

    A computational fluid dynamic(CFD) model for the fuel reactor of chemical looping combustion technology has been developed,withspecialfocusonaccuratelyrepresentingtheheterogeneous chemicalreactions.Acontinuumtwo-fluidmodelwasusedtodescribeboththegasandsolidphases. Detailedsub-modelstoaccountforfluid–particleandparticle–particleinteractionforceswerealso incorporated.Twoexperimentalcaseswereanalyzedinthisstudy(Son andKim,2006; Mattisonetal., 2001). SimulationswerecarriedouttotestthecapabilityoftheCFDmodeltocapturechangesinoutletgas concentrationswithchangesinnumberofparameterssuchassuperficialvelocity,metaloxide concentration,reactortemperature,etc.Fortheexperimentsof Mattissonetal.(2001), detailedtime varyingoutletconcentrationvalueswerecompared,anditwasfoundthatCFDsimulationsprovideda reasonablematchwiththisdata.

  3. MASSES, RADII, AND ORBITS OF SMALL KEPLER PLANETS: THE TRANSITION FROM GASEOUS TO ROCKY PLANETS

    E-Print Network [OSTI]

    Seager, Sara

    We report on the masses, sizes, and orbits of the planets orbiting 22 Kepler stars. There are 49 planet candidates around these stars, including 42 detected through transits and 7 revealed by precise Doppler measurements ...

  4. Laser utilizing a gaseous lasing medium and method for operating the same

    DOE Patents [OSTI]

    Zerr, Bruce A. (Harriman, TN)

    1986-01-01

    The invention relates to an improvement in gas lasers and a method of operating the same. In one aspect, the invention is an improved method for operating a high-power gas laser. The improvement comprises introducing the gas lasing medium tangentially to the laser tube at a pressure establishing a forced vortex in the tube. The vortex defines an axially extending core region characterized by a low pressure and temperature relative to the gas inlet and the exterior of the vortex. An electrical discharge is established in the core region to initiate lasing of the gas. The gas discharge from the tube is passed through a diffuser. As in conventional gas lasers, firing results in a very abrupt increase in gas temperature and in severe disruption of the gas. However, the gas vortex almost immediately restores the gas to its pre-firing condition. That is, almost all of the waste heat is transferred radially to the laser wall, and the original gas-flow pattern is restored. As a result, the power output of the laser is increased significantly, and the laser firing repetition rate is markedly increased.

  5. Characterizing Rocky and Gaseous Exoplanets with 2-meter Class Space-based Coronagraphs: General Considerations

    E-Print Network [OSTI]

    Robinson, Tyler D; Marley, Mark S

    2015-01-01

    Several concepts now exist for small, space-based missions to directly characterize exoplanets in reflected light. Here, we develop an instrument noise model suitable for studying the spectral characterization potential of a coronagraph-equipped, space-based telescope. We adopt a baseline set of telescope and instrument parameters, including a 2 m diameter primary aperture, an operational wavelength range of 0.4-1.0 um, and an instrument spectral resolution of 70, and apply our baseline model to a variety of spectral models of different planet types, including Earth twins, Jupiter twins, and warm and cool Jupiters and Neptunes. With our exoplanet spectral models, we explore wavelength-dependent planet-star flux ratios for main sequence stars of various effective temperatures, and discuss how coronagraph inner and outer working angle constraints will influence the potential to study different types of planets. For planets most favorable to spectroscopic characterization---cool Jupiters and Neptunes as well as ...

  6. EA-1927: Conveyance of Land and Facilities at the Paducah Gaseous...

    Energy Savers [EERE]

    the Draft EA. Written comments may submitted by the following methods: By Mail: Robert Smith, Paducah Strategic Planner Department of Energy-Paducah 5501 Hobbs Road C103 Kevil,...

  7. Testing and Certification of Gaseous Storage Tanks for Vehicles: The European Commission (EC) Perspective

    Broader source: Energy.gov [DOE]

    These slides were presented at the International Hydrogen Fuel and Pressure Vessel Forum on September 27 – 29, 2010, in Beijing, China.

  8. Generic report on health effects for the US Gaseous Diffusion Plants. Sect. 8, Pt. 1

    SciTech Connect (OSTI)

    Just, R.A.; Emler, V.S.

    1984-06-01

    Toxic substances present in uranium enrichment plants include uranium hexafluoride (UF/sub 6/), hydrogen fluoride (HF), uranyl fluoride (UO/sub 2/F/sub 2/), chlorine (Cl/sub 2/), chlorine trifluoride (ClF/sub 3/), fluorine (F/sub 2/), uranium tetrafluoride (UF/sub 4/), and technetium (Tc). The current knowledge of the expected health effects of acute exposures to these substances is described. 10 references, 2 figures, 6 tables. (ACR)

  9. Report on the Biological Monitoring Program at Paducah Gaseous Diffusion Plant, January--December 1995

    SciTech Connect (OSTI)

    Kszos, L.A. [ed.

    1996-04-01

    The BMP for PGDP consists of three major tasks: (1) effluent and ambient toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of stream communities (benthic macroinvertebrates, fish). This report focuses on ESD activities occurring from Jan. 1995 to Dec. 1995, although activities conducted outside this period are included as appropriate.

  10. Placement of criticality alarms in the Paducah Gaseous Diffusion Plant Laboratory

    SciTech Connect (OSTI)

    Miller, L.F.; Weems, L.D.; Cao, Z. [Univ. of Tennessee, Knoxville, TN (United States)] [and others

    1997-12-01

    The placement of criticality alarms at the Paducah plant has been studied. Four detectors placed in the halls of the first floor will provide double coverage of the first floor and single coverage of the basement, attic, and counting laboratory. Results from MCNP calculations also show that a detector placed in the hall adjacent to room 27 will cover the NDA laboratory.

  11. Environmental program audit, Paducah Gaseous Diffusion Plant, Paducah, Kentucky. Final report

    SciTech Connect (OSTI)

    Not Available

    1985-08-01

    The environmental monitoring program, environmental control equipment and its use, and the facility's compliance with DOE orders, Federal and State laws and regulations were evaluated in this audit. No imminent threat to public health and safety was discovered. A needed quality assurance program is being added. Recommendations are given. (PSB)

  12. Results of Lasagna process field experiment at the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Athmer, C.J.; Ho, S.V. [Monsanto Environmental Sciences Center, St. Louis, MO (United States)

    1995-12-31

    The Lasagna process is being developed to remediate clayey soils in-situ. Lasagna is a combination of electrokinetics and in-situ treatment taking place in installed treatment zones. The zones are formed in either horizontal or vertical orientation using modified existing geoengineering processes. A Lasagna field experiment combining electroosmosis with carbon adsorption in the vertical orientation has been conducted at a TCE contaminated DOE site in Paducah, KY. Carbon adsorption was chosen for this first field test so that a material balance could confirm the movement of TCE from the clay to the treatment zones. The results of this experiment are presented in this paper.

  13. Evaluation of the proposed pilot groundwater pump and treat demonstration for the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Bodenstein, G.W.; Bonczek, R.R.; Early, T.O.; Hale, T.B.; Huff, D.D.; Nickelson, M.D.; Rightmire, C.T.

    1992-11-01

    This report contains the evaluation and recommendations of a Groundwater Corrective Actions Review Team. The primary goal is to evaluate the technical merit of and the need to implement a proposed groundwater pump-and-treat demonstration project for the Northwest contaminant plume at Paducah, Kentucky. A key distinction recognized by the review team is that the proposed project is intended to be a full-scale hydraulic containment of contaminants migrating from the sources of the plume, not plume remediation. The key questions incorporated into this plan are whether (1) dense, nonaqueous-phase liquids (DNAPLS) are present in the Regional Gravel Aquifer (RGA) at the source of the plume and (2) [sup 99]Tc removal must be included as part of any groundwater treatment process. The first question cannot be answered until the contaminant sources are better defined; the second question requires further risk assessment and/or a policy decision by DOE. Technical evaluation by the review team suggests that the recommended course of action be to modify the proposed work plan to include accurate identification of the sources of contaminants and vertical distribution of contaminants within the Northwest plume before a decision is made on the preferred source-control option. If DNAPLs are not present in the RGA, removal or containment of the sources is recommended. If DNAPLs are present, then hydraulic containment will be required. Finally, the review team recognizes that it is necessary to initiate a more comprehensive analysis of sitewide remediation needs to create links between action taken for the Northwest plume and action taken for other contamination sites at PGPD.

  14. Method and apparatus for fast laser-pulse detection using gaseous plasmas

    DOE Patents [OSTI]

    McLellan, E.J.; Webb, J.A.

    1981-06-18

    The method and device of the instant invention is a detector of pulsed laser radiation which utilizes the electromotive force generated by the plasma formed when such radiation is focused onto a surface. Measurements are made with a 10.6 ..mu..m CO/sub 2/ laser capable of producing peak intensities of 10/sup 13/ W/cm/sup 2/ when directed through a converging lens. Evacuated detector response to such laser intensity if 1 kV signal peak amplitude and subnanosecond risetimes into a 50 ..cap omega.. load. Detector performance is found to be greatly altered with the introduction of a background gas. For example, with one atmosphere of air, the detector produces prompt signals of the order of 1 V with subnanosecond response for pulse trains lasting 100 ns. With argon, krypton, or zenon at pressures of the order of 10 torr, the detector generates trigger pulses of about 250 V amplitude and 0.2 ns risetimes. Such detectors are quite robust when irradiated with high intensity laser radiation and are useful for qualitative laser beam monitoring.

  15. CROSSED BEAM REACTIVE SCATTERING OF OXYGEN ATOMS AND SURFACE SCATTERING STUDIES OF GASEOUS CONDENSATION

    E-Print Network [OSTI]

    Sibener, S.J.

    2010-01-01

    angular and velocity distributions of the reaction products.angular and velocity distri­ butions, while reactionand velocity angular distributions of the OH reaction

  16. Development of a test facility for the experimental evaluation of liquid and gaseous automotive engine fuels 

    E-Print Network [OSTI]

    McCanlies, John Michael

    1983-01-01

    Checkout 126 Uncertainty Analysis 131 APPENDIX F: DETAILED PROCEDURES AND ADDITIONAL BASELINE RESULTS 141 F. I F. 2 Test Procedures Additional Baseline Results 141 144 161 LIST OF TAGLES PAGE Table I: Variables to be Investigated in Original...quid methanol as a fuel for multi-cylinder automotive eng1nes. This investigation was conducted in two phases. During the first phase, the experimental test system was designed and constructed, and baseline engine performance with liquid methanol...

  17. The determination of compressibility factors of gaseous propane-nitrogen mixtures 

    E-Print Network [OSTI]

    Dickson, Cecil Herman

    1955-01-01

    100 0 2 000 3000 4000 LEGEND DALTON + BE ATT IE- B RI DGEMAN V AMAGAT ~ EX PER I MENTAL 5000 6000 7000 8000 PR E SSUR E, P SI A 50 GRAPH X COMPA RISON OF EX PER IMENTAL DATA WITH CALCULATED VALUES F OR THE 48. 6I% PROPANE MIXTURE AT 300 F I... Percent Propane Mixture at 300 F. Comparison of Experimental Data wI. th Calculated Values for the 48. 6$ Mole Percent Propane Mixture at 260 F, Comparison of Experimental Data with Calculated Values for the &8. 6$ Mole Percent Propane Mixture st 300...

  18. GASEOUS HYDROGEN EFFECTS ON THE MECHANICAL PROPERTIES OF CARBON AND LOW ALLOY STEELS (U)

    SciTech Connect (OSTI)

    Lam, P

    2006-06-08

    This report is a compendium of sets of mechanical properties of carbon and low alloy steels following the short-term effects of hydrogen exposure. The property sets include the following: Yield Strength; Ultimate Tensile Strength; Uniform Elongation; Reduction of Area; Threshold Cracking, K{sub H} or K{sub th}; Fracture Toughness (K{sub IC}, J{sub IC}, and/or J-R Curve); and Fatigue Crack Growth (da/dN). These properties are drawn from literature sources under a variety of test methods and conditions. However, the collection of literature data is by no means complete, but the diversity of data and dependency of results in test method is sufficient to warrant a design and implementation of a thorough test program. The program would be needed to enable a defensible demonstration of structural integrity of a pressurized hydrogen system. It is essential that the environmental variables be well-defined (e.g., the applicable hydrogen gas pressure range and the test strain rate) and the specimen preparation be realistically consistent (such as the techniques to charge hydrogen and to maintain the hydrogen concentration in the specimens).

  19. LITERATURE SURVEY OF GASEOUS HYDROGEN EFFECTS ON THE MECHANICAL PROPERTIES OF CARBON AND LOW ALLOY STEELS

    SciTech Connect (OSTI)

    Lam, P; Robert Sindelar, R; Thad Adams, T

    2007-04-18

    Literature survey has been performed for a compendium of mechanical properties of carbon and low alloy steels following hydrogen exposure. The property sets include yield strength, ultimate tensile strength, uniform elongation, reduction of area, threshold stress intensity factor, fracture toughness, and fatigue crack growth. These properties are drawn from literature sources under a variety of test methods and conditions. However, the collection of literature data is by no means complete, but the diversity of data and dependency of results in test method is sufficient to warrant a design and implementation of a thorough test program. The program would be needed to enable a defensible demonstration of structural integrity of a pressurized hydrogen system. It is essential that the environmental variables be well-defined (e.g., the applicable hydrogen gas pressure range and the test strain rate) and the specimen preparation be realistically consistent (such as the techniques to charge hydrogen and to maintain the hydrogen concentration in the specimens).

  20. LITERATURE SURVEY OF GASEOUS HYDROGEN EFFECTS ON THE MECHANICAL PROPERTIES OF CARBON AND LOW ALLOY STEELS

    SciTech Connect (OSTI)

    Lam, P; Andrew Duncan, A; Robert Sindelar, R; Thad Adams, T

    2009-04-27

    Literature survey has been performed for a compendium of mechanical properties of carbon and low alloy steels following hydrogen exposure. The property sets include yield strength, ultimate tensile strength, uniform elongation, reduction of area, threshold stress intensity factor, fracture toughness, and fatigue crack growth. These properties are drawn from literature sources under a variety of test methods and conditions. However, the collection of literature data is by no means complete, but the diversity of data and dependency of results in test method is sufficient to warrant a design and implementation of a thorough test program. The program would be needed to enable a defensible demonstration of structural integrity of a pressurized hydrogen system. It is essential that the environmental variables be well-defined (e.g., the applicable hydrogen gas pressure range and the test strain rate) and the specimen preparation be realistically consistent (such as the techniques to charge hydrogen and to maintain the hydrogen concentration in the specimens).

  1. Journal of Low Temperature Physics, Vol. 122, Nos. 12, 2001 Dissipationless Flow and Superfluidity in Gaseous

    E-Print Network [OSTI]

    Department of Physics and Research Laboratory of Electronics, Massachusetts Institute of Technology into an Ioffe-Pritchard magnetic trap. The trap consisted of four Ioffe bars and two elongated pinch coils

  2. The determination of compressibility factors of gaseous propane-nitrogen mixtures 

    E-Print Network [OSTI]

    Hodges, Don

    1952-01-01

    ??IxTURE AS CALO:LATM& "RO? PRE BEAT I. - ~RIl, ), El AN &', gi)ATIOR OR STATE (liters por ~rr I ) RT(1 - o/vT3) (Cr. mole atm ). er liter v Bo(1 - b) (liters per r oIe) Ao(1 - a) vs v (p 8rrrp at?sos tpr ur*, atmos (Pv RT 0 0900 0 1050...

  3. Apparatus and methods for direct conversion of gaseous hydrocarbons to liquids

    DOE Patents [OSTI]

    Kong, Peter C.; Lessing, Paul A.

    2006-04-25

    A chemical reactor for direct conversion of hydrocarbons includes a dielectric barrier discharge plasma cell and a solid oxide electrochemical cell in fluid communication therewith. The discharge plasma cell comprises a pair of electrodes separated by a dielectric material and passageway therebetween. The electrochemical cell comprises a mixed-conducting solid oxide electrolyte membrane tube positioned between a porous cathode and a porous anode, and a gas inlet tube for feeding oxygen containing gas to the porous cathode. An inlet is provided for feeding hydrocarbons to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a light source for directing ultraviolet light into the discharge plasma cell and the electrochemical cell.

  4. An In-Situ Ion Mobility Spectrometer Sensor System for Detecting Gaseous VOCs in Unsaturated Soils

    E-Print Network [OSTI]

    Baker, R. Jacob

    . The IMS system will be packaged in a probe housing for deployment using direct push methods methods for sampling and analyzing soil gas samples fall into two classes: passive sampling and active sampling. Passive sampling methods involve the shallow burial of a sorbent collector, which adsorbs the VOC

  5. International Journal of Thermophysics, Vol. 17, No. 6, 1996 Calculation of Second Virial Coefficients and Gaseous

    E-Print Network [OSTI]

    Lisal, Martin

    /1100-1269509.50/0© 1996PlenumPublishingCorporation #12;1270 Lisal, Watanabe, and Vacek and heat-pumping equipment. HFC-32

  6. DOE - Office of Legacy Management -- Oak Ridge Gaseous Diffusion Plant - TN

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth Dakota Edgemont,Manufacturing -Nevada Test SiteNY

  7. ,"U.S. Natural Gas Plant Liquids Production, Gaseous Equivalent (Bcf)"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015" ,"ReleaseMonthly","10/2015" ,"Release Date:","12/31/2015" ,"Next

  8. ,"U.S. Natural Gas Plant Liquids Production, Gaseous Equivalent (Bcf)"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home PageMonthly","10/2015"4,"Ames City of",6,1,"Omaha Public PowerOECD/IEA -Annual",2014 ,"ReleaseAnnual",2014Annual",2014 ,"Release

  9. U.S. Natural Gas Plant Liquids Production, Gaseous Equivalent (Billion

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: AlternativeMonthly","10/2015"Monthly","10/2015"Separation, Proved Reserves(Million2009 2010 2011 2012DecadeDecade Year-0 Year-1Cubic

  10. Demolition of K-31 gaseous diffusion building begins | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-in electricLaboratory | version ofEnergy This documentOREM began

  11. Stellar and gaseous nuclear disks observed in nearby (U)LIRGs (Journal

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail. (Conference)Feedback System inStatus of the MEIC ion colliderArticle) | SciTech

  12. EA-1856: Conveyance of Land and Facilities at the Portsmouth Gaseous

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|

  13. EA-1927: Conveyance of Land and Facilities at the Paducah Gaseous Diffusion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of Energy 8: DOEFinding ofofFinding5: Finding of NoPlant

  14. U.S., Ohio Approve Portsmouth Gaseous Diffusion Plant Site D&D Plans |

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OF APPLICABLEStatutoryin the Nation's, China Partner to Counter

  15. Proposed On-Site Disposal Facility (OSDF) at the Paducah Gaseous Diffusion

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested PartiesBuildingBudget || Department of EnergyNo. 154 - Aug. 10, 2011

  16. Proposed On-Site Waste Disposal Facility (OSWDF) at the Portsmouth Gaseous

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested PartiesBuildingBudget || Department of EnergyNo. 154 - Aug. 10,

  17. DOE Issues Final Request for Proposal for Paducah Gaseous Diffusion Plant

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergy Webinar:IAbout Us »Buildings DOEDOE FCalculation | DOEDOESupport

  18. DOE completes demolition of K-31 gaseous diffusion building | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergy Webinar:IAbout Us| Department of Energy DOE Windand

  19. RADIOLOGICAL HEALTH AND RELATED STANDARDS FOR NUCLEAR POWER PLANTS. VOLUME 2 OF HEALTH AND SAFETY IMPACTS OF NUCLEAR, GEOTHERMAL, AND FOSSIL-FUEL ELECTRIC GENERATION IN CALIFORNIA

    E-Print Network [OSTI]

    Nero, A.V.

    2010-01-01

    OF RADIOACTIVE MATERIALS IN GASEOUS AND LIQUID EFFLUENTSof radioactive materials in liquid and gaseous effluents to

  20. Explosion bomb measurements of ethanol-air laminar gaseous flame characteristics at pressures up to 1.4 MPa

    SciTech Connect (OSTI)

    Bradley, D.; Lawes, M.; Mansour, M.S. [School of Mechanical Engineering, University of Leeds, Leeds LS2 9JT (United Kingdom)

    2009-07-15

    The principal burning characteristics of a laminar flame comprise the fuel vapour pressure, the laminar burning velocity, ignition delay times, Markstein numbers for strain rate and curvature, the stretch rates for the onset of flame instabilities and of flame extinction for different mixtures. With the exception of ignition delay times, measurements of these are reported and discussed for ethanol-air mixtures. The measurements were in a spherical explosion bomb, with central ignition, in the regime of a developed stable, flame between that of an under or over-driven ignition and that of an unstable flame. Pressures ranged from 0.1 to 1.4 MPa, temperatures from 300 to 393 K, and equivalence ratios were between 0.7 and 1.5. It was important to ensure the relatively large volume of ethanol in rich mixtures at high pressures was fully evaporated. The maximum pressure for the measurements was the highest compatible with the maximum safe working pressure of the bomb. Many of the flames soon became unstable, due to Darrieus-Landau and thermo-diffusive instabilities. This effect increased with pressure and the flame wrinkling arising from the instabilities enhanced the flame speed. Both the critical Peclet number and the, more rational, associated critical Karlovitz stretch factor were evaluated at the onset of the instability. With increasing pressure, the onset of flame instability occurred earlier. The measured values of burning velocity are expressed in terms of their variations with temperature and pressure, and these are compared with those obtained by other researchers. Some comparisons are made with the corresponding properties for iso-octane-air mixtures. (author)

  1. Process for recovering uranium from waste hydrocarbon oils containing the same. [Uranium contaminated lubricating oils from gaseous diffusion compressors

    DOE Patents [OSTI]

    Conrad, M.C.; Getz, P.A.; Hickman, J.E.; Payne, L.D.

    1982-06-29

    The invention is a process for the recovery of uranium from uranium-bearing hydrocarbon oils containing carboxylic acid as a degradation product. In one aspect, the invention comprises providing an emulsion of water and the oil, heating the same to a temperature effecting conversion of the emulsion to an organic phase and to an acidic aqueous phase containing uranium carboxylate, and recovering the uranium from the aqueous phase. The process is effective, simple and comparatively inexpensive. It avoids the use of toxic reagents and the formation of undesirable intermediates.

  2. Abstract--Rain, snow, gaseous, cloud, fog, scintillation and other atmospheric properties can have a distorting effect on

    E-Print Network [OSTI]

    Huang, Changcheng

    -effective attenuation mitigation techniques. It enhances link availability and performance. In view of these analytical conditions can enable mitigation planning by adaptively selecting appropriate modulation, coding, transmitted power level, transmission rate and configured frame size. The aim of this paper is to estimate different

  3. Development of Compact Gaseous Sensors with Internal Reference for Monitoring O2 and NOx in Combustion Environments

    Broader source: Energy.gov [DOE]

    Compact sensors have been developed to allow for real-time monitoring of O2 and NOx during combustion.

  4. Nonlinear polarization response of a gaseous medium in the regime of atom stabilization in a strong radiation field

    SciTech Connect (OSTI)

    Volkova, E. A.; Popov, A. M. Tikhonova, O. V.

    2013-03-15

    The nonlinear polarization response of a quantum system modeling a silver atom in the field of high-intensity radiation in the IR and UV spectral ranges has been studied by direct numerical integration of a nonstationary Schroedinger equation. The domains of applicability of perturbation theory and polarization expansion in powers of the field intensity are determined. The contribution of excited atoms and electrons in a continuum to the atomic polarization response at the field frequency, which arises due to the radiation-induced excitation and photoionization processes, is analyzed. Features of the nonlinear response to an external field under conditions of atom stabilization are considered.

  5. A multi-term solution of the space-time Boltzmann equation for electrons in gaseous and liquid Argon

    E-Print Network [OSTI]

    Boyle, G J; Tattersall, W J; McEachran, R P; White, R D

    2015-01-01

    In a recent paper [1] the scattering and transport of excess electrons in liquid argon in the hydrodynamic regime was investigated, generalizing the seminal works of Lekner and Cohen [2,3] with modern scattering theory techniques and kinetic theory. In this paper, the discussion is extended to the non-hydrodynamic regime through the development of a full multi-term space-time solution of Boltzmann's equation for electron transport in gases and liquids using a novel operator-splitting method. A Green's function formalism is considered that enables flexible adaptation to various experimental systems. The spatio-temporal evolution of electrons in liquids in the hydrodynamic regime is studied for a benchmark model Percus-Yevick liquid as well as for liquid argon. The temporal evolution of Franck-Hertz oscillations are observed for liquids, with striking differences in the spatio-temporal development of the velocity distribution function components between the uncorrelated gas and true liquid approximations in arg...

  6. An evaluation of gaseous sterilants under various conditions and their effect upon the heat resistance of Salmonella 

    E-Print Network [OSTI]

    Ali, Md. Razzak

    1966-01-01

    environment under the conditions of these esperimsnts, SPL and formaldehyde seem to be more effective than Penn Gas under the enperimental conditions used, 6 ~ Penn Das requires a comparatively prolonged-exposure time to accomplish effective sterilisation...

  7. Effect of Gaseous Impurities on Long-Term Thermal Cycling and Aging Properties of Complex Hydrides for Hydrogen Storage

    SciTech Connect (OSTI)

    Chandra, Dhanesh; Lamb, Joshua; Chien, Wen-Ming; Talekar, Anjali; and Pal, Narendra.

    2011-03-28

    This program was dedicated to understanding the effect of impurities on Long-Term Thermal Cycling and aging properties of Complex Hydrides for Hydrogen Storage. At the start of the program we found reversibility between Li2NH+LiH ? LiH+LiNH2 (yielding ~5.8 wt.%H capacity). Then we tested the effect of impurity in H2 gas by pressure cycling at 255oC; first with industrial gas containing ppm levels of O2 and H2O as major impurities. Both these impurities had a significant impact on the reversibility and decreased the capacity by 2.65 wt.%H. Further increase in number of cycles from 500 to 1100 showed only a 0.2 wt%H more weight loss, showing some capacity is still maintained after a significant number of cycles. The loss of capacity is attributed to the formation of ~55 wt% LiH and ~30% Li2O, as major contaminant phases, along with the hydride Li2NH phase; suggesting loss of nitrogen during cycling. The effect of 100 ppm H2O in H2 also showed a decrease of ~2.5 wt.%H (after 560 cycles), and 100ppm O2 in H2; a loss of ~4.1 wt.%. Methane impurity (100 ppm, 100cycles), showed a very small capacity loss of 0.9 wt.%H under similar conditions. However, when Li3N was pressure cycled with 100ppmN2-H2 there were beneficial effects were observed (255oC); the reversible capacity increased to 8.4wt.%H after 853 cycles. Furthermore, with 20 mol.%N2-H2 capacity increased to ~10 wt.%H after 516 cycles. We attribute this enhancement to the reaction of nitrogen with liquid lithium during cycling as the Gibbs free energy of formation of Li3N (?Go = -98.7 kJ/mol) is more negative than that of LiH (?Go = -50.3 kJ/mol). We propose that the mitigation of hydrogen capacity losses is due to the destabilization of the LiH phase that tends to accumulate during cycling. Also more Li2NH phase was found in the cycled product. Mixed Alanates (3LiNH2:Li3AlH6) showed that 7 wt% hydrogen desorbed under dynamic vacuum. Equilibrium experiments (maximum 12 bar H2) showed up to 4wt% hydrogen reversibly stored in the material after the first desorption. The activation energy was found to be 51 kJ/mol, as compared to 81 kJ/mol for pure lithium alanate. It is proposed that based on the data obtained and CALPHAD modeling that the improvement in cycling is due to the formation of pure lithium (liquid at 255oC), which is able to react with nitrogen specifically forming Li3N. The presence of nitrogen in the 80/20 molar mixtures in a hydride bed along with hydrogen causes Li to form Li3N rather than LiH, and subsequently regenerates the Li2NH phase and yields a ~10 wt.%H reversibly.

  8. Interactions of gaseous HNO3 and water with individual and mixed alkyl self-assembled monolayers at room temperature.

    E-Print Network [OSTI]

    Nishino, Noriko; Hollingsworth, Scott A; Stern, Abraham C; Roeselová, Martina; Tobias, Douglas J; Finlayson-Pitts, Barbara J

    2014-01-01

    of even small amounts of water vapor (revised Fig.  of the CI and POZ by water under tropospheric http://mechanism and the effects of water and irradiation remain 

  9. Restoration and repair of 30-year old cooling towers at the Paducah Gaseous Diffusion Plant, Phase I. Draft 1

    SciTech Connect (OSTI)

    Shelton, M.F.

    1985-01-01

    Early in 1980, a comprehensive reliability study was made to ascertain the ability of the present 30-year old recirculating water system to meet the anticipated load demand through the year 2000. The findings and recommendations of this study were used as a guide to schedule uprating and repairs. This paper deals with the underground distribution system and cooling tower repairs.

  10. Northwest Plume Groundwater System Green-sand Media Removal and Waste Packaging Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    Troutman, M.T.; Richards, C.J.; Tarantino, J.J. [CDM Federal Programs Corporation, 325 Kentucky Avenue, Kevil, KY 42053 (United States)

    2006-07-01

    The Northwest Plume Groundwater System (NWPGS) was temporarily shut down due to high differential pressures across the green-sand filters. Increased levels of suspended solids were introduced into the system from monitoring well development water, equipment decontamination water, and secondary containment water. These waters were treated for suspended solids through a groundwater pretreatment system but were suspected of causing the high differential pressures in the green-sand filters. Prior to the system being shutdown, the NWPGS had been experiencing increasingly shorter run times between filter backwashes indicating that the normal backwash cycle was not adequately removing the fines. This condition led to the removal and replacement of green-sand media from two filter vessels. Discussions include problems with the removal process, waste packaging specifications, requirements for the disposition of green-sand media, and lessons learned. (authors)

  11. Evaluation of the proposed pilot groundwater pump and treat demonstration for the Paducah Gaseous Diffusion Plant. Environmental Restoration Program

    SciTech Connect (OSTI)

    Bodenstein, G.W.; Bonczek, R.R.; Early, T.O.; Hale, T.B.; Huff, D.D.; Nickelson, M.D.; Rightmire, C.T.

    1992-11-01

    This report contains the evaluation and recommendations of a Groundwater Corrective Actions Review Team. The primary goal is to evaluate the technical merit of and the need to implement a proposed groundwater pump-and-treat demonstration project for the Northwest contaminant plume at Paducah, Kentucky. A key distinction recognized by the review team is that the proposed project is intended to be a full-scale hydraulic containment of contaminants migrating from the sources of the plume, not plume remediation. The key questions incorporated into this plan are whether (1) dense, nonaqueous-phase liquids (DNAPLS) are present in the Regional Gravel Aquifer (RGA) at the source of the plume and (2) {sup 99}Tc removal must be included as part of any groundwater treatment process. The first question cannot be answered until the contaminant sources are better defined; the second question requires further risk assessment and/or a policy decision by DOE. Technical evaluation by the review team suggests that the recommended course of action be to modify the proposed work plan to include accurate identification of the sources of contaminants and vertical distribution of contaminants within the Northwest plume before a decision is made on the preferred source-control option. If DNAPLs are not present in the RGA, removal or containment of the sources is recommended. If DNAPLs are present, then hydraulic containment will be required. Finally, the review team recognizes that it is necessary to initiate a more comprehensive analysis of sitewide remediation needs to create links between action taken for the Northwest plume and action taken for other contamination sites at PGPD.

  12. Final report. Paducah Gaseous Diffusion Plant PCB sediment survey: Big Bayou Creek and Little Bayou Creek, Paducah, Kentucky

    SciTech Connect (OSTI)

    None

    1996-12-01

    Laboratory analysis of collected samples along drainage features at PGDP. Report documents levels of PCB contamination and considers locations of contamination and known releases to theorize probable sources to further investigate.

  13. Environmental assessment for the construction and operation of waste storage facilities at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    NONE

    1994-06-01

    DOE is proposing to construct and operate 3 waste storage facilities (one 42,000 ft{sup 2} waste storage facility for RCRA waste, one 42,000 ft{sup 2} waste storage facility for toxic waste (TSCA), and one 200,000 ft{sup 2} mixed (hazardous/radioactive) waste storage facility) at Paducah. This environmental assessment compares impacts of this proposed action with those of continuing present practices aof of using alternative locations. It is found that the construction, operation, and ultimate closure of the proposed waste storage facilities would not significantly affect the quality of the human environment within the meaning of NEPA; therefore an environmental impact statement is not required.

  14. Investigation of Particle and Gaseous Emissions from Conventional and Emerging Vehicle Technologies Operating on Bio-Fuels

    E-Print Network [OSTI]

    Short, Daniel

    2014-01-01

    Lippert A.M. 2005. Stratified-charge combustion: modelingeither homogeneous or stratified-charge spray-guided (SG)charge mode only, the greatest fuel economy benefit is achieved with unthrottled lean stratified

  15. Investigation of Particle and Gaseous Emissions from Conventional and Emerging Vehicle Technologies Operating on Bio-Fuels

    E-Print Network [OSTI]

    Short, Daniel

    2014-01-01

    20% when testing a GDI turbocharged vehicle with two enginewhen they tested a turbocharged GDI vehicle over the Federalwhen they tested a GDI turbocharged vehicle with two engine

  16. Voluntary Protection Program Onsite Review, Swift and Staley Team, Infrastructure Support Contract, Paducah Gaseous Diffusion Plant- December 2014

    Broader source: Energy.gov [DOE]

    Annual Merit Review of Swift and Staley Team (SST) for continued participation in the Department of Energy Voluntary Protection Program.

  17. Gaseous Chemistry and Aerosol Mechanism Developments for Version 3.5.1 of the Online Regional Model, WRF-Chem

    SciTech Connect (OSTI)

    Archer-Nicholls, Scott; Lowe, Douglas; Utembe, Steve; Allan, James D.; Zaveri, Rahul A.; Fast, Jerome D.; Hodnebrog, Oivind; Denier van der Gon, Hugo; McFiggans, Gordon

    2014-11-08

    We have made a number of developments in the regional coupled model WRF-Chem, with the aim of making the model more suitable for prediction of atmospheric composition and of interactions between air quality and weather. We have worked on the European domain, with a particular focus on making the model suitable for the study of night time chemistry and oxidation by the nitrate radical in the UK atmosphere. A reduced form of the Common Reactive Intermediates gas-phase chemical mechanism (CRIv2-R5) has been implemented to enable more explicit simulation of VOC degradation. N2O5 heterogeneous chemistry has been added to the existing sectional MOSAIC aerosol module, and coupled to both the CRIv2-R5 and existing CBM-Z gas phase scheme. Modifications have also been made to the sea-spray aerosol emission representation, allowing the inclusion of primary organic material in sea-spray aerosol. Driven by appropriate emissions, wind fields and chemical boundary conditions, implementation of the different developments is illustrated in order to demonstrate the impact that these changes have in the North-West European domain. These developments are now part of the freely available WRF-Chem distribution.

  18. Transforming dielectric coated tungsten and platinum wires to gaseous state using negative nanosecond-pulsed-current in vacuum

    SciTech Connect (OSTI)

    Wu, Jian; Li, Xingwen Wang, Kun; Yang, Zefeng; Shi, Zongqian; Jia, Shenli; Qiu, Aici; Li, Zhenghong

    2014-11-15

    With the help of thin dielectric coatings, corona free explosions were achieved in the region of about half a wire length (2?cm) for tungsten wires and nearly the whole wire length for platinum wires under a fast rising (46–170?A/ns) negative polarity current in vacuum. Expansion velocity of the tungsten gas was over 10?km/s. Current waveforms from exploding coated wires were similar to those from bare wires in the air including a current pause stage. Coated wires with different coating parameters had a similar joule energy deposition before voltage collapsed, but a quite different scenario in the region near the electrodes. The axial field under negative current was the main reason for the axial inhomogeneity of coated tungsten wires. Tungsten or platinum gases in the vaporized region were tightly encompassed by the dielectric coating, while gaps or probably low density gases, were observed between the coating and the edge of the dense wire core in the core-corona structure region.

  19. Investigation of Particle and Gaseous Emissions from Conventional and Emerging Vehicle Technologies Operating on Bio-Fuels

    E-Print Network [OSTI]

    Short, Daniel

    2014-01-01

    D.R. 2009. Real World Vehicle Emissions: A Summary of the 18Research Council On-Road Vehicle Emissions Workshop, JournalAnalysis: Tier 3 Motor Vehicle Emission and Fuel Standards,

  20. Investigation of Particle and Gaseous Emissions from Conventional and Emerging Vehicle Technologies Operating on Bio-Fuels

    E-Print Network [OSTI]

    Short, Daniel

    2014-01-01

    M.Z. 2007. Effects of Ethanol (E85) Versus Gasoline Vehiclesoperating on low blend ethanol gasoline and E85. Atmosphericof Low Blend Ethanol Gasoline and E85, Atomospheric

  1. A look back at Union Carbides [first] 20 Years in Nuclear Energy [The Gaseous Diffusion Plants]

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach HomeA Better Anode Design to Improve Lithium-Ion Batteries PrintA New SolarAComplexAthe[first] 20 Years

  2. Independent Oversight Review of Preparedness for Severe Natural Phenomena Events at the Portsmouth Gaseous Diffusion Plant, November 2013

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nA Guide toIMPROVEMENT OF DESIGNEmergency Preparedness for Severefor Severe

  3. Project House Dedication - 8 

    E-Print Network [OSTI]

    Unknown

    2011-08-17

    ) (11) Burke, N. E., Curtice, S., Little, C.T" and Seibert, A. F" Remoyal of Hydrocar;bons fr;om Oil-Field Brines by Flocculation with Car;bon Dioxide, SPE International Symposium on Oilfield Chemistry, SPE 21046, P 457 (1991). 102 in equilibrium...., Little, C.T., and Seibert, A. F., Remoyal of Hydrocarbons fz;om Oil-Field Brines by Flocculation with Caz;bon Dioxide, SPE International Symposium on Oilfield Chemistry, SPE 21046, P 457 (1991). ESL-IE-91-06-23 Proceedings from the 13th National...

  4. Transportation Energy Futures

    E-Print Network [OSTI]

    DeLuchi, Mark A.

    1989-01-01

    tanks for compressed natural gas (CNG)storage, additional fuel lines for the gaseous fuel, and a gaseous fuel mixer

  5. Use of 2,5-dimethyl-2,5-hexane diamine as a curing agent for epoxy resins

    DOE Patents [OSTI]

    Rinde, J.A.; Newey, H.A.

    1981-02-24

    Primary diamines are disclosed of the formula shown in a diagram wherein R is a straight chain saturated hydrocarbon of 2 to 4 carbons, a disubstituted benzene ring, or disubstituted dibenzomethane for use as a curing agent for epoxy resins. These curing agents can be used to form epoxy resin mixtures useful in filament winding and pre-impregnated fiber molding and in formulating film adhesives, powder coatings and molding powders. The epoxy mixtures form for such uses as room temperature non-reacting, intermediate stable state which has a latent cross-linking capability.

  6. Selective hydrocracking of raffinates

    SciTech Connect (OSTI)

    Shipikin, V.V.; Georgievskii, V.Yu.

    1987-05-01

    The most acceptable method for processing raffinates to improve their antiknock properties is selective hydrocracking. As a result of selective cracking of the straight-chain paraffinic hydrocarbons present in raffinates, an octane number gain of 15-20 may be achieved. The authors list certain process indexes for selective hydrocracking of 62-105/sup 0/C cut (benzene-toluene) and 105-140/sup 0/C cut (xylene). It is shown that the improvement of the antiknock properties of raffinates by selective hydrocracking may change the structure of automotive gasoline production quite substantially.

  7. Use of 2,5-dimethyl-2,5-hexane diamine as a curing agent for epoxy resins

    DOE Patents [OSTI]

    Rinde, James A. [Livermore, CA; Newey, Herbert A. [Lafayette, CA

    1981-02-24

    Primary diamines of the formula ##STR1## wherein R is a straight chain saturated hydrocarbon of 2 to 4 carbons, a disubstituted benzene ring, or disubstituted dibenzo methane for use as a curing agent for epoxy resins. These curing agents can be used to form epoxy resin mixtures useful in filament winding and pre-impregnated fiber molding and in formulating film adhesives, powder coatings and molding powders. The epoxy mixtures form for such uses as room temperature non-reacting, intermediate stable state which has a latent cross-linking capability.

  8. An HST/COS legacy survey of intervening SiIII absorption in the extended gaseous halos of low-redshift galaxies

    E-Print Network [OSTI]

    Richter, P; Fechner, C; Herenz, P; Tepper-Garcia, T; Fox, A J

    2015-01-01

    Doubly ionized silicon (SiIII) is a powerful tracer of diffuse ionized gas inside and outside of galaxies. It can be observed in the local Universe in ultraviolet (UV) absorption against bright extragalactic background sources. We here present an extensive study of intervening SiIII- selected absorbers and their relation to the circumgalactic medium (CGM) of galaxies at low redshift (z12.2. We develop a geometrical model for the absorption-cross section of the CGM around the local galaxy population and find excellent agreement between the model predictions and the observations. We further compare redshifts and positions of the absorbers with that of ~64,000 galaxies using archival galaxy-survey data. For the majority of the absorbers we identify possible L>0.5L* host galaxies within 300 km/s of the absorbers and derive impact parameters rho<200 kpc, demonstrating that the spatial distributions of SiIII absorbers and galaxies are highly correlated. Our study indicates that the majority of SiIII-selected abs...

  9. Dose Modeling Evaluations and Technical Support Document for the Authorized Limits Request for the C-746-U Landfill at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    Boerner, A. J.; Maldonado, D. G.

    2012-06-01

    This report contains the technical basis in support of the DOE?s derivation of Authorized Limits (ALs) for the DOE Paducah C-746-U Landfill. A complete description of the methodology, including an assessment of the input parameters, model inputs, and results is provided in this report. This report also provides initial recommendations on applying the derived soil guidelines. The ORISE-derived soil guidelines are specifically applicable to the Landfill at the end of its operational life. A suggested 'upper bound' multiple of the derived soil guidelines for individual shipments is provided.

  10. Using a Regional Chemical Transport Model for the Analysis of Gaseous and Particulate Air Pollutants in the Mexico City Metropolitan Area 

    E-Print Network [OSTI]

    Ali, Sajjad Ghulam

    2012-02-14

    -Chem). The simulation period was March 2-7, 2006. Hourly species concentrations of O3, NOx, CO, SO2, PM10, and PM2.5 for the period were provided by the Automatic Air Quality Monitoring Network (labeled as RAMA). Preliminary evaluation showed GEOS-Chem and CMAQ being...

  11. Geochemical assessment of gaseous hydrocarbons: mixing of bacterial and thermogenic methane in the deep subsurface petroleum system, Gulf of Mexico continental slope 

    E-Print Network [OSTI]

    Ozgul, Ercin

    2004-09-30

    Mixtures of bacterial and thermogenic methane are found both at vents at the seafloor and in reservoirs in the deep subsurface of the Gulf of Mexico continental slope. The C1-C5 gas that most recently charged reservoirs of Jolliet (GC 184), Genesis...

  12. Environmental site description for a Uranium Atomic Vapor Laser Isotope Separation (U-AVLIS) production plant at the Oak Ridge Gaseous Diffusion Plant Site

    SciTech Connect (OSTI)

    Not Available

    1991-09-01

    In January 1990, the Secretary of Energy approved a plan for the demonstration and deployment of the Uranium Atomic Vapor Laser Isotope Separation (U-AVLIS) technology, with the near-term goal to provide the necessary information to make a deployment decision by November 1992. The U-AVLIS process is based on electrostatic extraction of photoionized U-235 atoms from an atomic vapor stream created by electron-beam vaporization of uranium metal alloy. A programmatic document for use in screening DOE sites to locate the U-AVLIS production plant was developed and implemented in two parts (Wolsko et al. 1991). The first part consisted of a series of screening analyses, based on exclusionary and other criteria, that identified a reasonable number of candidate sites. These sites were then subjected to a more rigorous and detailed comparative analysis for the purpose of developing a short list of reasonable alternative sites for later environmental examination. This environmental site description (ESD) provides a detailed description of the ORGDP site and vicinity suitable for use in an environmental impact statement (EIS). The report is based on existing literature, data collected at the site, and information collected by Argonne National Laboratory (ANL) staff during a site visit. The organization of the ESD is as follows. Topics addressed in Sec. 2 include a general site description and the disciplines of geology, water resources, biotic resources, air resources, noise, cultural resources, land use, socioeconomics, and waste management. Identification of any additional data that would be required for an EIS is presented in Sec. 3. Following the site description and additional data requirements, Sec. 4 provides a short, qualitative assessment of potential environmental issues. 37 refs., 20 figs., 18 tabs.

  13. Investigation of the radiological safety concerns and medical history of the late Joseph T. Harding, former employee of the Paducah Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Vallario, E.J.; Wolfe, H.R.

    1981-03-01

    An ex-employee's claims that inadequate enforcement of radiation safety regulations allowed excess radiation exposure thereby causing his deteriorating health was not substantiated by a thorough investigation.

  14. Analysis of criticality alarm system response to an accidental criticality outside the cascade process buildings at the Portsmouth Gaseous Diffusion Plant

    SciTech Connect (OSTI)

    Negron, S.B.; Tayloe, R.W. Jr.; Dobelbower, M.C. [Battelle, Columbus, OH (United States)

    1994-07-01

    Neutron dose rates at detector positions within the X-326, X-330, and X-333 buildings were evaluated for an accidental criticality outside of each building. As fissile material bearing equipment and containers are moved to and from each building, the possibility exists for a criticality accident to occur. This analysis demonstrates that a criticality accident which occurs at any position on the access roads alongside a process building can be detected. The detectable area includes all points within the access road boundary along each face of each building. This analysis also demonstrates that the criticality alarm systems of the process buildings will respond to criticality events occurring within the tie lines connecting the process buildings. This analysis was performed using the MCNP Monte Carlo neutron-proton transport code. The radiation source is the neutron leakage spectrum of a critical solution of 4.95 percent enriched UO{sub 2}F{sub 2}-H{sub 2}O at a power level corresponding to the ANSI ANS 8.3. Standard minimum accident of concern. The evaluated neutron fluxes were converted to neutron dose rates by use of the Henderson free-in-air response functions. Critical source positions correspond to the farthest source to detector distances on the access roads along each face of the three buildings, and the centerpoint of the building tie lines. This report contains the methodology used for this study, a background on the data used, and a section about the assumptions and limits to all conclusions.

  15. Integrated modeling of CO2 storage and leakage scenarios including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO2

    E-Print Network [OSTI]

    Pruess, K.

    2012-01-01

    corresponding to a geothermal gradient of 30 o C/km andwater in a typical geothermal gradient, as shown in Figs. 1-o C, 1.013x10 5 Pa) in a geothermal gradient of 30 o C/km to

  16. Type B Accident Investigation Board Report on the September 15, 1997, Drum Explosion at Building C-746-Q, Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    Broader source: Energy.gov [DOE]

    This report is an independent product of the Type B Accident Investigation Board (Board) appointed by James C. Hall, Manager, Oak Ridge Operations.

  17. Evaluation of natural attenuation processes for trichloroethylene and technetium-99 in the Northeast and Northwest plumes at the Paducah Gaseous Diffusion Plant, Paducah, Kentucky

    SciTech Connect (OSTI)

    Clausen, J.L.; Sturchio, N.C.; Heraty, L.J.; Huang, L.; Abrajano,T.

    1997-11-25

    NA processes such as biodegradation, sorption, dilution dispersion, advection, and possibly sorption and diffusion are occurring in the Northeast and Northwest plumes. However, the overall biological attenuation rate for TCE within the plumes is not sufficiently rapid to utilize as remedial option. The mobility and toxicity of {sup 99}Tc is not being reduced by attenuating processes within the Northwest Plume. The current EPA position is that NA is not a viable remedial approach unless destructive processes are present or processes are active which reduce the toxicity and mobility of a contaminant. Therefore, active remediation of the dissolved phase plumes will be necessary to reduce contaminant concentrations before an NA approach could be justified at PGDP for either plume. Possible treatment methods for the reduction of dissolved phase concentrations within the plumes are pump-and-treat bioaugmentation, biostimulation, or multiple reactive barriers. Another possibility is the use of a regulatory instrument such as an Alternate Concentration Limit (ACL) petition. Biodegradation of TCE is occurring in both plumes and several hypothesis are possible to explain the apparent conflicts with some of the geochemical data. The first hypothesis is active intrinsic bioremediation is negligible or so slow to be nonmeasurable. In this scenario, the D.O., chloride, TCE, and isotopic results are indicative of past microbiological reactions. It is surmised in this scenario, that when the initial TCE release occurred, sufficient energy sources were available for microorganisms to drive aerobic reduction of TCE, but these energy sources were rapidly depleted. The initial degraded TCE has since migrated to downgradient locations. In the second scenario, TCE anaerobic degradation occurs in organic-rich micro-environments within a generally aerobic aquifer. TCE maybe strongly absorbed to organic-rich materials in the aquifer matrix and degraded by local Immunities of microbes, perhaps even under anaerobic conditions. Chloride, generated by degradation in such microenvironment is released rapidly into the water, as is CO{sub 2}, from respiration of the microorganisms. TCE and its organic degradation products are retained on the aquifer matrix by sorption, and released more slowly into the groundwater. In this process, chloride produced from the microbial reaction may become separated in the plume from the residual TCE. This may explain why the chloride isotope ratio and dissolved TCE do not correlate with the DIC isotope ratio. The relationship between the {delta}{sup 37}Cl values of TCE and dissolved inorganic chloride is consistent with what would be expected from the degradation of TCE, but is complicated by the elevated levels of background chloride, presumably due to agriculture practice, and complex behavior of TCE in the aquifer.

  18. Investigation of the radiological safety concerns and medical history of the late Joseph T. Harding, former employee of the Paducah Gaseous Diffusion Plant

    E-Print Network [OSTI]

    Vallario, E J

    1981-01-01

    An ex-employee's claims that inadequate enforcement of radiation safety regulations allowed excess radiation exposure thereby causing his deteriorating health was not substantiated by a thorough investigation.

  19. Environmental site description for a Uranium Atomic Vapor Laser Isotope Separation (U-AVLIS) production plant at the Paducah Gaseous Diffusion Plant site

    SciTech Connect (OSTI)

    Marmer, G.J.; Dunn, C.P.; Moeller, K.L.; Pfingston, J.M.; Policastro, A.J.; Yuen, C.R.; Cleland, J.H.

    1991-09-01

    Uranium enrichment in the United States has utilized a diffusion process to preferentially enrich the U-235 isotope in the uranium product. The U-AVLIS process is based on electrostatic extraction of photoionized U-235 atoms from an atomic vapor stream created by electron-beam vaporization of uranium metal alloy. The U-235 atoms are ionized when precisely tuned laser light -- of appropriate power, spectral, and temporal characteristics -- illuminates the uranium vapor and selectively photoionizes the U-235 isotope. A programmatic document for use in screening DOE site to locate a U-AVLIS production plant was developed and implemented in two parts. The first part consisted of a series of screening analyses, based on exclusionary and other criteria, that identified a reasonable number of candidate sites. These sites were subjected to a more rigorous and detailed comparative analysis for the purpose of developing a short list of reasonable alternative sites for later environmental examination. This environmental site description (ESD) provides a detailed description of the PGDP site and vicinity suitable for use in an environmental impact statement (EIS). The report is based on existing literature, data collected at the site, and information collected by Argonne National Laboratory (ANL) staff during a site visit. 65 refs., 15 tabs.

  20. Dynamics of the giant planets of the solar system in the gaseous proto-planetary disk and relationship to the current orbital architecture

    E-Print Network [OSTI]

    Alessandro Morbidelli; Kleomenis Tsiganis; Aurelien Crida; Harold F. Levison; Rodney Gomes

    2007-07-17

    We study the orbital evolution of the 4 giant planets of our solar system in a gas disk. Our investigation extends the previous works by Masset and Snellgrove (2001) and Morbidelli and Crida (2007, MC07), which focussed on the dynamics of the Jupiter-Saturn system. The only systems that we found to reach a steady state are those in which the planets are locked in a quadruple mean motion resonance (i.e. each planet is in resonance with its neighbor). In total we found 6 such configurations. For the gas disk parameters found in MC07, these configurations are characterized by a negligible migration rate. After the disappearance of the gas, and in absence of planetesimals, only two of these six configurations (the least compact ones) are stable for a time of hundreds of millions of years or more. The others become unstable on a timescale of a few My. Our preliminary simulations show that, when a planetesimal disk is added beyond the orbit of the outermost planet, the planets can evolve from the most stable of these configurations to their current orbits in a fashion qualitatively similar to that described in Tsiganis et al. (2005).