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Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Model of leaf photosynthesis and the effects of simple gaseous sulfur compounds (H/sub 2/S and SO/sub 2/)  

DOE Green Energy (OSTI)

A theoretical development is presented of a leaf model and the effects of simple sulfur compounds (H{sub 2}S and SO{sub 2}) on photosynthesis based upon biochemical mechanisms. The model is developed to interpret short-term fumigation experiments and to use with season-long fumigation experiments to assess the effects of these compounds on growth. The model is designed as a submodel in a growth-and-allocation model of the plant. Included in this development are an analysis of the diffusion of CO{sub 2} and sulfur compound into the leaf, enzymatic interactions of sulfur in dark and light reactions of photosynthesis, temperature dependence of the kinetics and denaturization of enzymes, metabolism of sulfur compounds, and a hypothesis for the long-term effects of sulfur compounds. Enhanced photosynthesis at low H{sub 2}S levels, depression of photosynthesis at high H/sub 2/S levels, threshold to effects of sulfur pollutants, and the nature of the temperature dependence of photosynthesis are explained. Parameters in the model for sugar beets from data in the literature and from experiments funded through LLL were used. The properties of the model were analyzed. Data and experiments still required, sensitivities of the model to parameters and variables, implications to assessments, and the setting of standards for gaseous pollutants, are discussed.

Kercher, J.R.

1978-08-10T23:59:59.000Z

2

TULSA UNIVERSITY PARAFFIN DEPOSITION PROJECTS  

SciTech Connect

As oil and gas production moves to deeper and colder water, subsea multiphase production systems become critical for economic feasibility. It will also become increasingly imperative to adequately identify the conditions for paraffin precipitation and predict paraffin deposition rates to optimize the design and operation of these multiphase production systems. Although several oil companies have paraffin deposition predictive capabilities for single-phase oil flow, these predictive capabilities are not suitable for the multiphase flow conditions encountered in most flowlines and wellbores. For deepwater applications in the Gulf of Mexico, it is likely that multiphase production streams consisting of crude oil, produced water and gas will be transported in a single multiphase pipeline to minimize capital cost and complexity at the mudline. Existing single-phase (crude oil) paraffin deposition predictive tools are clearly inadequate to accurately design these pipelines because they do not account for the second and third phases, namely, produced water and gas. The objective of this program is to utilize the current test facilities at The University of Tulsa, as well as member company expertise, to accomplish the following: enhance our understanding of paraffin deposition in single and two-phase (gas-oil) flows; conduct focused experiments to better understand various aspects of deposition physics; and, utilize knowledge gained from experimental modeling studies to enhance the computer programs developed in the previous JIP for predicting paraffin deposition in single and two-phase flow environments. These refined computer models will then be tested against field data from member company pipelines. The following deliverables are scheduled during the first three projects of the program: (1) Single-Phase Studies, with three different black oils, which will yield an enhanced computer code for predicting paraffin deposition in deepwater and surface pipelines. (2) Two-Phase Studies, with a focus on heat transfer and paraffin deposition at various pipe inclinations, which will be used to enhance the paraffin deposition code for gas-liquid flow in pipes. (3) Deposition Physics and Water Impact Studies, which will address the aging process, improve our ability to characterize paraffin deposits and enhance our understanding of the role water plays in paraffin deposition in deepwater pipelines. As in the previous two studies, knowledge gained in this suite of studies will be integrated into a state-of-the-art three-phase paraffin deposition computer program.

Michael Volk; Cem Sarica

2003-10-01T23:59:59.000Z

3

TULSA UNIVERSITY PARAFFIN DEPOSITION PROJECTS  

SciTech Connect

As oil and gas production moves to deeper and colder water, subsea multiphase production systems become critical for economic feasibility. It will also become increasingly imperative to adequately identify the conditions for paraffin precipitation and predict paraffin deposition rates to optimize the design and operation of these multi-phase production systems. Although several oil companies have paraffin deposition predictive capabilities for single-phase oil flow, these predictive capabilities are not suitable for the multiphase flow conditions encountered in most flowlines and wellbores. For deepwater applications in the Gulf of Mexico, it is likely that multiphase production streams consisting of crude oil, produced water and gas will be transported in a single multiphase pipeline to minimize capital cost and complexity at the mudline. Existing single-phase (crude oil) paraffin deposition predictive tools are clearly inadequate to accurately design these pipelines, because they do not account for the second and third phases, namely, produced water and gas. The objective of this program is to utilize the current test facilities at The University of Tulsa, as well as member company expertise, to accomplish the following: enhance our understanding of paraffin deposition in single and two-phase (gas-oil) flows; conduct focused experiments to better understand various aspects of deposition physics; and, utilize knowledge gained from experimental modeling studies to enhance the computer programs developed in the previous JIP for predicting paraffin deposition in single and two-phase flow environments. These refined computer models will then be tested against field data from member company pipelines.

Cem Sarica; Michael Volk

2004-06-01T23:59:59.000Z

4

Treating paraffin deposits in producing oil wells  

Science Conference Proceedings (OSTI)

Paraffin deposition has been a problem for operators in many areas since the beginning of petroleum production from wells. An extensive literature search on paraffin problems and methods of control has been carried out, and contact was made with companies which provide chemicals to aid in the treatment of paraffin problems. A discussion of the nature of paraffins and the mechanisms of this deposition is presented. The methods of prevention and treatment of paraffin problems are summarized. Suggested procedures for handling paraffin problems are provided. Suggestions for areas of further research testing are given.

Noll, L.

1992-01-01T23:59:59.000Z

5

Rubidium dimers in paraffin-coated cells  

E-Print Network (OSTI)

Measurements were made to determine the density of rubidium dimer vapor in paraffin-coated cells. The number density of dimers and atoms in similar paraffin-coated and uncoated cells was measured by optical spectroscopy. Due to the relatively low melting point of paraffin, a limited temperature range of 43-80 deg C was explored, with the lower end corresponding to a dimer density of less than 10^7 cm^(-3). With one-minute integration time, a sensitivity to dimer number density of better than 10^6 cm^(-3) was achieved. No significant difference in dimer density was observed between the cells.

V. M. Acosta; A. Jarmola; D. Windes; E. Corsini; M. P. Ledbetter; T. Karaulanov; M. Auzinsh; S. A. Rangwala; D. F. Jackson Kimball; D. Budker

2010-05-03T23:59:59.000Z

6

NGPL Production, Gaseous Equivalent  

U.S. Energy Information Administration (EIA) Indexed Site

NGPL Production, Gaseous Equivalent Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By:...

7

Gaseous insulators for high voltage electrical equipment  

DOE Patents (OSTI)

Gaseous insulators comprise compounds having high attachment cross sections for electrons having energies in the 0-1.3 electron volt range. Multi-component gaseous insulators comprise compounds and mixtures having overall high electron attachment cross sections in the 0-1.3 electron volt range and moderating gases having high cross sections for inelastic interactions with electrons of energies 1-4 electron volts. Suitable electron attachment components include hexafluorobutyne, perfluorobutene-2, perfluorocyclobutane, perfluorodimethylcyclobutane, perfluorocyclohexene, perfluoromethylcyclohexane, hexafluorobutadiene, perfluoroheptene-1 and hexafluoroazomethane. Suitable moderating gases include N.sub.2, CO, CO.sub.2 and H.sub.2. The gaseous insulating mixture can also contain SF.sub.6, perfluoropropane and perfluorobenzene.

Christophorou, Loucas G. (Oak Ridge, TN); James, David R. (Knoxville, TN); Pace, Marshall O. (Knoxville, TN); Pai, Robert Y. (Concord, TN)

1981-01-01T23:59:59.000Z

8

Gaseous insulators for high voltage electrical equipment  

DOE Patents (OSTI)

Gaseous insulators comprise compounds having high attachment cross sections for electrons having energies in the 0-1.3 electron volt range. Multi-component gaseous insulators comprise compounds and mixtures having overall high electron attachment cross sections in the 0-1.3 electron volt range and moderating gases having high cross sections for inelastic interactions with electrons of energies 1-4 electron volts. Suitable electron attachment components include hexafluorobutyne, perfluorobutene-2, perfluorocyclobutane, perfluorodimethylcyclobutane, perfluorocyclohexene, perfluoromethylcyclohexane, hexafluorobutadiene, perfluoroheptene-1 and hexafluoroazomethane. Suitable moderating gases include N.sub.2, CO, CO.sub.2 and H.sub.2. The gaseous insulating mixture can also contain SF.sub.6, perfluoropropane and perfluorobenzene.

Christophorou, Loucas G. (Oak Ridge, TN); James, David R. (Knoxville, TN); Pace, Marshall O. (Knoxville, TN); Pai, Robert Y. (Concord, TN)

1979-01-01T23:59:59.000Z

9

Gaseous Fuel Injection Modeling using a Gaseous Sphere Injection Methodology  

DOE Green Energy (OSTI)

The growing interest in gaseous fuels (hydrogen and natural gas) for internal combustion engines calls for the development of computer models for simulation of gaseous fuel injection, air entrainment and the ensuing combustion. This paper introduces a new method for modeling the injection and air entrainment processes for gaseous fuels. The model uses a gaseous sphere injection methodology, similar to liquid droplet in injection techniques used for liquid fuel injection. In this paper, the model concept is introduced and model results are compared with correctly- and under-expanded experimental data.

Hessel, R P; Aceves, S M; Flowers, D L

2006-03-06T23:59:59.000Z

10

GASEOUS SCINTILLATION COUNTER  

DOE Patents (OSTI)

A gaseous excitation counter for detecting the presence amd measuring the energy of subatomic particles and electromagnetic radiation is described. The counter includes a gas-tight chamber filled with an elemental gas capable of producing ultra-violet excitation quanta when irradiated with subatomic particles and electromagnetic radiation. The gas has less than one in a thousand parts ultra-violet absorbing contamination. When nuclear radiation ps present the ultra-violet light produced by the gas strikes a fluorescent material within the counter, responsive to produce visible excitation quanta, and photo-sensitive counting means detect the visible emission.

Eggler, C.; Huddleston, C.M.

1959-04-28T23:59:59.000Z

11

The Application of Paraffin Deposition Model of Wellbore for Condensate Gas Well  

Science Conference Proceedings (OSTI)

The safety hazard caused by paraffin precipitation to normal oil and gas production cannot be ignored. Therefore, it is necessary to develop the paraffin precipitation, deposition mechanism, and variation discipline of phase state, prediction technology ... Keywords: deposition mechanism, paraffin precipitation, condensate gas reservoir

Xi-an Wang; Min Yang

2011-10-01T23:59:59.000Z

12

Independent Oversight Inspection, Portsmouth Gaseous Diffusion Plant -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth Gaseous Diffusion Portsmouth Gaseous Diffusion Plant - November 2006 Independent Oversight Inspection, Portsmouth Gaseous Diffusion Plant - November 2006 November 2006 Inspection of Emergency Management at the Portsmouth Gaseous Diffusion Plant The Secretary of Energy's Office of Independent Oversight, within the Office of Security and Safety Performance Assurance, conducted an inspection of the emergency management program at the Portsmouth Gaseous Diffusion Plant (PORTS) in August and September 2006. The coordination of emergency plans and procedures among USEC and DOE contractor organizations has successfully integrated the emergency management programs into a single cohesive program for the PORTS site. Other strengths include accurate hazards surveys that identify applicable

13

Gaseous electrode development. Final report  

DOE Green Energy (OSTI)

The purpose of the present study is to optimize the gaseous electrode for use in an MHD generator and to test this optimum configuration in an operating MHD channel. The arc gaseous electrode concept is based on the use of an arc source in the body of the MHD channel electrode, wherein the arc follows a helical path and generates a plasma which flows out of a long, thin slot cut parallel to the cylindrical annulus, to provide a low impedance path for the MHD current through the boundary layer so that electrode erosion due to arcing can be reduced. Bench-scale tests on the arc plasma source were conducted. The effect of the parameters such as magnetic field, yaw angle with respect to the magnetic field, electrode geometry, and arc cathode materials were studied. Based on these studies, an optimum design was selected for testing in the MHD channel. Tests were conducted with the arc gaseous electrode in the cathode wall of a diagonal conducting wall MHD generator at magnetic fields up to 3.83 Tesla, with a supersonic flow of combustion products seeded with 1.0 w/o of potassium. The measured MHD plasma conductivity varied between 12 and 22 S/m. Results are presented and discussed in detail. (WHK)

Jones, M.S. Jr.; Scannell, E.P.; Sathyanarayana, K.; Thiagarajan, V.; Mallavarpu, R.; Armstrong, A.J.

1979-12-01T23:59:59.000Z

14

Hydrogen and Gaseous Fuel Safety and Toxicity  

DOE Green Energy (OSTI)

Non-traditional motor fuels are receiving increased attention and use. This paper examines the safety of three alternative gaseous fuels plus gasoline and the advantages and disadvantages of each. The gaseous fuels are hydrogen, methane (natural gas), and propane. Qualitatively, the overall risks of the four fuels should be close. Gasoline is the most toxic. For small leaks, hydrogen has the highest ignition probability and the gaseous fuels have the highest risk of a burning jet or cloud.

Lee C. Cadwallader; J. Sephen Herring

2007-06-01T23:59:59.000Z

15

Bulk heating cleans paraffinic bottoms from crude tanks  

SciTech Connect

It is often challenging to remove from service crude oil tanks that have been in use for many years. Bulk heating, as opposed to localized heating, has been used to successfully liquefy heavy paraffinic or asphaltic bases in crude oil tanks. The process provides economical product recovery, while minimizing waste production and reducing human exposure to hazardous working conditions. Statia Terminals Point Tupper Inc., Point Tupper, N.S., used bulk heating to remove 2 ft of weathered, paraffinic tank bottoms from six 450,000 bbl tanks that held Cabinda crude from West Africa. Immersion tube heaters were installed through the tank manholes and a diluent was added. Two 10-million BTU/hr propane burners supplied heat, and tank mixers operated continuously to aid in heat transfer. The tank contents were heated to 135 F and the temperature was held constant for 3 days. The resulting hot liquid was a pumpable and recoverable product. About 10 days were required to clean each tank. The paper describes the heating and cleaning operation as well as the economics of the Statia project.

Badrock, J. (Cooperheat Inc., Houston, TX (United States)); Coutu, R. (Cooperheat Inc., Mississauga, Ontario (Canada)); Johnson, N. (Statia Terminals N.V. St. Eustatius (Netherlands)); Martin, A. (Chicago Bridge and Iron Co., Oak Brook, IL (United States))

1995-02-20T23:59:59.000Z

16

Portsmouth Gaseous Diffusion Plant, Former Production Workers...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Plant, Former Production Workers Screening Projects Portsmouth Gaseous Diffusion Plant, Former Production Workers Screening Projects Project Name: Worker Health Protection Program...

17

Portsmouth Gaseous Diffusion Plant - Enforcement Documents  

NLE Websites -- All DOE Office Websites (Extended Search)

Inc. related to Installation and Inspection of Penetration Fire Seals at the DUF6 Conversion Building at the Portsmouth Gaseous Diffusion Plant, March 26, 2010 Consent...

18

Independent Oversight Review, Portsmouth Gaseous Diffusion Plant -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth Gaseous Diffusion Plant Portsmouth Gaseous Diffusion Plant - November 2013 Independent Oversight Review, Portsmouth Gaseous Diffusion Plant - November 2013 November 5, 2013 Review of Preparedness for Severe Natural Phenomena Events at the Portsmouth Gaseous Diffusion Plant This report documents the results of an independent oversight review of the preparedness of the DOE Portsmouth/Paducah Project Office, contractors at the DOE Portsmouth Gaseous Diffusion Plant, and selected non-leased facilities to respond to a severe natural phenomena event (NPE). The review was conducted in July and August 2013 by the U.S. Department of Energy's (DOE) Office of Safety and Emergency Management Evaluations, which is within the DOE Office of Health, Safety and Security (HSS). The HSS Office of Safety and Emergency Management Evaluations performed this

19

Process for exchanging hydrogen isotopes between gaseous hydrogen and water  

DOE Patents (OSTI)

A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

Hindin, Saul G. (Mendham, NJ); Roberts, George W. (Westfield, NJ)

1980-08-12T23:59:59.000Z

20

Illinois Natural Gas Plant Liquids Production, Gaseous Equivalent...  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Illinois Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2...

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Oklahoma Natural Gas Plant Liquids Production, Gaseous Equivalent...  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Oklahoma Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2...

22

Tennessee Natural Gas Plant Liquids Production, Gaseous Equivalent...  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Tennessee Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2...

23

Florida Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Florida Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

24

Ohio Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Ohio Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

25

Wyoming Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Wyoming Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

26

Montana Natural Gas Plant Liquids Production, Gaseous Equivalent...  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Montana Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

27

Nebraska Natural Gas Plant Liquids Production, Gaseous Equivalent...  

Annual Energy Outlook 2012 (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Nebraska Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2...

28

Utah Natural Gas Plant Liquids Production, Gaseous Equivalent...  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Utah Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

29

Indiana Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Indiana Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2...

30

Alaska Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Alaska Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

31

West Virginia Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) West Virginia Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2...

32

Kansas Natural Gas Plant Liquids Production, Gaseous Equivalent...  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Kansas Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

33

Non-Destructive Analysis Calibration Standards for Gaseous Diffusion...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Analysis Calibration Standards for Gaseous Diffusion Plant (GDP) Decommissioning The decommissioning of Gaseous Diffusion Plant facilities requires accurate, non-destructive...

34

Production and Handling Slide 25: The Portsmouth Gaseous Diffusion...  

NLE Websites -- All DOE Office Websites (Extended Search)

Portsmouth Gaseous Diffusion Plant Skip Presentation Navigation First Slide Previous Slide Next Slide Last Presentation Table of Contents The Portsmouth Gaseous Diffusion Plant...

35

Production and Handling Slide 24: The Paducah Gaseous Diffusion...  

NLE Websites -- All DOE Office Websites (Extended Search)

Paducah Gaseous Diffusion Site Skip Presentation Navigation First Slide Previous Slide Next Slide Last Presentation Table of Contents The Paducah Gaseous Diffusion Site Refer to...

36

Combination free electron and gaseous laser  

DOE Patents (OSTI)

A multiple laser having one or more gaseous laser stages and one or more free electron stages. Each of the free electron laser stages is sequentially pumped by a microwave linear accelerator. Subsequently, the electron beam is directed through a gaseous laser, in the preferred embodiment, and in an alternative embodiment, through a microwave accelerator to lower the energy level of the electron beam to pump one or more gaseous lasers. The combination laser provides high pulse repetition frequencies, on the order of 1 kHz or greater, high power capability, high efficiency, and tunability in the synchronous production of multiple beams of coherent optical radiation.

Brau, Charles A. (Los Alamos, NM); Rockwood, Stephen D. (Los Alamos, NM); Stein, William E. (Los Alamos, NM)

1980-01-01T23:59:59.000Z

37

Greenhouse warming potential of candidate gaseous diffusion plant coolants  

SciTech Connect

A preliminary estimate has been made of the greenhouse warming potential (GWP) of coolants under consideration as substitutes for CFC-114 in the gaseous diffusion plants. Coolants are not at present regulated on the basis of GWP, but may well be in the future. Use of c-C{sub 4}F{sub 8} or n-C{sub 4}F{sub 10} is estimated to have three to four times the greenhouse impact of an equivalent use of CFC-114. Neither of the substitutes, of course, would cause any ozone depletion. HCFC-124 (a probable commercial substitute for CFC-114, but not presently under serious consideration due to its relatively high UF{sub 6} reactivity) would have much less greenhouse and ozone depletion impact than CFC-114. The GWP estimates derive from a simple model that approximately reproduces literature values for similar compounds. The major uncertainty in these estimates lies in the atmospheric lifetime, especially of the perfluorocarbon compounds, for which little reliable information exists. In addition to GWP estimates for coolants, the overall greenhouse impact of the gaseous diffusion plants is calculated, including indirect power-related CO{sub 2} emissions. This result is used to compare greenhouse impacts of nuclear- and coal-produced electricity. 11 refs., 2 figs., 5 tabs.

Trowbridge, L.D.

1991-03-01T23:59:59.000Z

38

Manhattan Project: K-25 Gaseous Diffusion Plant  

Office of Scientific and Technical Information (OSTI)

K-25 Gaseous Diffusion Plant, Oak Ridge Events > The Uranium Path to the Bomb, 1942-1944 Events > The Uranium Path to the Bomb, 1942-1944 > Working K-25 into the Mix, Oak Ridge:...

39

Independent Oversight Review, Portsmouth Gaseous Diffusion Plant- January 2013  

Energy.gov (U.S. Department of Energy (DOE))

Review of the Portsmouth Gaseous Diffusion Plant Work Planning and Control Activities Prior to Work Execution

40

Independent Activity Report, Portsmouth Gaseous Diffusion Plant - July 2011  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Activity Report, Portsmouth Gaseous Diffusion Plant - Activity Report, Portsmouth Gaseous Diffusion Plant - July 2011 Independent Activity Report, Portsmouth Gaseous Diffusion Plant - July 2011 July 2011 Orientation Visit to the Portsmouth Gaseous Diffusion Plant [HIAR-PAD-2011-07-27] The purpose of the visit was to discuss the nuclear safety oversight strategy, describe the site lead program, increase HSS personnel's operational awareness of the site's activities, and to determine how HSS can carry out its independent oversight and mission support responsibilities. Independent Activity Report, Portsmouth Gaseous Diffusion Plant - July 2011 More Documents & Publications Independent Activity Report, Portsmouth Gaseous Diffusion Plant - August 2011 Independent Activity Report, Argonne National Laboratory - August 2011

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Independent Oversight Review, Portsmouth Gaseous Diffusion Plant- April 2013  

Energy.gov (U.S. Department of Energy (DOE))

Review of the Integrated Safety Management System Phase I Verification Review at the Portsmouth Gaseous Diffusion Plant

42

Gaseous modification of MCrAlY coatings  

SciTech Connect

The present invention generally describes methods for modifying MCrAlY coatings by using gaseous carburization, gaseous nitriding or gaseous carbonitriding. The modified MCrAlY coatings are useful in thermal barrier coating systems, which may be used in gas turbine engines.

Vance, Steven J. (Orlando, FL); Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL)

2000-01-01T23:59:59.000Z

43

Non-Destructive Analysis Calibration Standards for Gaseous Diffusion Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Non-Destructive Analysis Calibration Standards for Gaseous Non-Destructive Analysis Calibration Standards for Gaseous Diffusion Plant (GDP) Decommissioning Non-Destructive Analysis Calibration Standards for Gaseous Diffusion Plant (GDP) Decommissioning The decommissioning of Gaseous Diffusion Plant facilities requires accurate, non-destructive assay (NDA) of residual enriched uranium in facility components for safeguards and nuclear criticality safety purposes. Current practices used to perform NDA measurements frequently have poorly defined uncertainties due to multiple factors. Working reference material (WRM) standards and container-specific surrogates are required to verify and validate NDA methods used to support characterization of gaseous diffusion equipment within the D&D project. Because working reference

44

Gaseous Diffusion Plant Production Workers Needs Assessment  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Department of Energy Gaseous Diffusion Plants Department of Energy Gaseous Diffusion Plants Phase I: Needs Assessment Robert Wages Oil, Chemical and Atomic Inte national Union Steven Markowitz Mount Sinai School of Medicine Sylvia Kieding Oil, Chemical and Atomic International Union Mark Griffon University of Massachusetts Lowell Elizabeth Averill Samaras Alice Hamilton College October 1, 1997 TABLE OF CONTENTS Page Number Executive Summary 1 J: OVERVIEW 1. Introduction 2-3 2. Methods 3-8 3. Principal Findings 9-16 4. Need for Medical Surveillance and Risk Communication 16-17 PART II: METHODOLOGY AND RESULTS 4. Exposure Assessment Appendix A Appendix B Appendix C 5. Focus Group Results Appendix A Appendix B Appendix C 6. Epidemiology and Other Health Studies EXECUTIVE SUMMARY Purpose We report the results and analysis of a one year needs assessment study evaluating

45

Alternative gaseous-fuels safety assessment  

DOE Green Energy (OSTI)

A relative safety assessment of alternative gaseous and reference liquid fuels utilized for light automotive transportation in the public sector was completed. The specific fuels considered were compressed natural gas (CNG), liquefied natural gas (LNG), liquefied petroleum gas (LPG), and the liquid fuels, gasoline and diesel. The assessment methodology describes and develops the relative hazards of these fuels from an integrated generic physicochemical property and accident scenario point of view. A technique involving a method of eliciting expert judgment combined with a comparative scoring methodology was applied in establishing fuel relative safety rankings. Limitations of this type of assessment are discussed. Selected accident scenarios included fuel leakage in both residential and public garages; fueling line rupture at a refueling station in the presence of user vehicles or delivery vehicles; and vehicle collisions under rural, urban, and vehicular tunnel conditions. Overall, the results obtained demonstrate dependency upon the specific application or scenario. Gaseous fuels have increased relative risks in certain situations and are relatively safe in others. The results suggest that alternative gaseous fuels are not disqualified for public usage. The assessment also provides rationale for the development of selected safe handling criteria and recommendations.

Krupka, M.C.; Peaslee, A.T. Jr.; Laquer, H.L.

1983-01-01T23:59:59.000Z

46

Method for converting asbestos to non-carcinogenic compounds  

DOE Patents (OSTI)

Hazardous and carcinogenic asbestos waste characterized by a crystalline fibrous structure is transformed into non-carcinogenic, relatively nonhazardous, and non-crystalline solid compounds and gaseous compounds which have commercial utilization. The asbestos waste is so transformed by the complete fluorination of the crystalline fibrous silicate mineral defining the asbestos. 7 figs.

Selby, T.W.

1996-08-06T23:59:59.000Z

47

Band Formation during Gaseous Diffusion in Aerogels  

E-Print Network (OSTI)

We study experimentally how gaseous HCl and NH_3 diffuse from opposite sides of and react in silica aerogel rods with porosity of 92 % and average pore size of about 50 nm. The reaction leads to solid NH_4Cl, which is deposited in thin sheet-like structures. We present a numerical study of the phenomenon. Due to the difference in boundary conditions between this system and those usually studied, we find the sheet-like structures in the aerogel to differ significantly from older studies. The influence of random nucleation centers and inhomogeneities in the aerogel is studied numerically.

M. A. Einarsrud; F. A. Maao; A. Hansen; M. Kirkedelen; J. Samseth

1997-06-18T23:59:59.000Z

48

K-25 Gaseous Diffusion Process Building | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Operational Management » History » Manhattan Project » Signature Operational Management » History » Manhattan Project » Signature Facilities » K-25 Gaseous Diffusion Process Building K-25 Gaseous Diffusion Process Building K-25 Gaseous Diffusion Process Building The K-25 plant, located on the southwestern end of the Oak Ridge reservation, used the gaseous diffusion method to separate uranium-235 from uranium-238. Based on the well-known principle that molecules of a lighter isotope would pass through a porous barrier more readily than molecules of a heavier one, gaseous diffusion produced through myriads of repetitions a gas increasingly rich in uranium-235 as the heavier uranium-238 was separated out in a system of cascades. Although producing minute amounts of final product measured in grams, gaseous diffusion required a massive

49

Orientation Visit to the Paducah Gaseous Diffusion Plant  

NLE Websites -- All DOE Office Websites (Extended Search)

PAD-2011-07-27 Site: Paducah Gaseous Diffusion Plant Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for the...

50

,"North Dakota Natural Gas Plant Liquids Production, Gaseous...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","North Dakota Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release...

51

,"Tennessee Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","Tennessee Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet)",1,"Annual",2012...

52

,"U.S. Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Natural Gas Plant Liquids Production, Gaseous Equivalent (Bcf)",1,"Monthly","92013" ,"Release...

53

,"New Mexico Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release...

54

,"Arkansas Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","Arkansas Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release...

55

,"Colorado Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","Colorado Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release...

56

,"Kentucky Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","Kentucky Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release...

57

,"West Virginia Natural Gas Plant Liquids Production, Gaseous...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","West Virginia Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release...

58

Former Worker Medical Screening Program - Paducah Gaseous Diffusion...  

NLE Websites -- All DOE Office Websites (Extended Search)

Paducah Gaseous Diffusion Plant Construction Workers Former Worker Medical Screening Program (FWP) Project Name: Building Trades National Medical Screening Program Covered DOE...

59

The Thermodynamics of Gaseous, Cuprous Chloride Monomer and Trimer  

E-Print Network (OSTI)

No.W-7405-eng~48B TIiE THERMODYNAMICS OF GASEOUS" CUPROUSCu(s) + HCl::= I Thermodynamics of Vaporization to Monomeric

Brewer, Leo

2010-01-01T23:59:59.000Z

60

Virtual Screening of Materials for Gaseous Fuel Storage  

Science Conference Proceedings (OSTI)

Presentation Title, Virtual Screening of Materials for Gaseous Fuel Storage .... Numerical Study on Behavior of Top-Blown Supersonic Jets and Their Interaction ...

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

2011 GASEOUS IONS GORDON RESEARCH CONFERENCE  

DOE Green Energy (OSTI)

The Gaseous Ions: Structures, Energetics and Reactions Gordon Research Conference will focus on ions and their interactions with molecules, surfaces, electrons, and light. The conference will cover theory and experiments, and systems ranging from molecular to biological to clusters to materials. The meeting goal continues to be bringing together scientists interested in fundamentals, with those applying fundamental phenomena to a wide range of practical problems. Each of the ten conference sessions will focus on a topic within this spectrum, and there will also be poster sessions for contributed papers, with sufficient space and time to allow all participants to present their latest results. To encourage active participation by young investigators, about ten of the poster abstracts will be selected for 15 minute 'hot topic' talks during the conference sessions. Hot topic selection will be done about a month before the meeting. Funds should be available to offset the participation cost for young investigators.

Scott Anderson

2011-03-04T23:59:59.000Z

62

2011 GASEOUS IONS GORDON RESEARCH CONFERENCE  

SciTech Connect

The Gaseous Ions: Structures, Energetics and Reactions Gordon Research Conference will focus on ions and their interactions with molecules, surfaces, electrons, and light. The conference will cover theory and experiments, and systems ranging from molecular to biological to clusters to materials. The meeting goal continues to be bringing together scientists interested in fundamentals, with those applying fundamental phenomena to a wide range of practical problems. Each of the ten conference sessions will focus on a topic within this spectrum, and there will also be poster sessions for contributed papers, with sufficient space and time to allow all participants to present their latest results. To encourage active participation by young investigators, about ten of the poster abstracts will be selected for 15 minute 'hot topic' talks during the conference sessions. Hot topic selection will be done about a month before the meeting. Funds should be available to offset the participation cost for young investigators.

Scott Anderson

2011-03-04T23:59:59.000Z

63

Gaseous-fuel safety assessment. Status report  

DOE Green Energy (OSTI)

The Los Alamos National Laboratory, in support of studies sponsored by the Office of Vehicle and Engine Research and Development in the US Department of Energy, has undertaken a safety assessment of selected gaseous fuels for use in light automotive transportation. The purpose is to put into perspective the hazards of these fuels relative to present day fuels and delineated criteria for their safe handling. Fuels include compressed and liquified natural gas (CNG and LNG), liquefied petroleum gas (LPG), and for reference gasoline and diesel. This paper is a program status report. To date, physicochemical property data and general petroleum and transportation information were compiled; basic hazards defined; alternative fuels were safety-ranked based on technical properties alone; safety data and vehicle accident statistics reviewed; and accident scenarios selected for further analysis. Methodology for such analysis is presently under consideration.

Krupka, M.C.; Edeskuty, F.J.; Bartlit, J.R.; Williamson, K.D. Jr.

1982-01-01T23:59:59.000Z

64

DOE - Office of Legacy Management -- Portsmouth Gaseous Diffusion Plant -  

Office of Legacy Management (LM)

Portsmouth Gaseous Diffusion Plant Portsmouth Gaseous Diffusion Plant - 026 FUSRAP Considered Sites Site: Portsmouth Gaseous Diffusion Plant (026 ) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition: Radioactive Materials Handled: Primary Radioactive Materials Handled: Radiological Survey(s): Site Status: The Portsmouth Gaseous Diffusion Plant (PGDP) is located in south central Ohio, approximately 20 miles north of Portsmouth, Ohio and 70 miles south of Columbus, Ohio. Construction of the PGDP began in late 1952 to expand the Federal Government¿s gaseous diffusion program already in place at Oak Ridge, Tennessee and Paducah, Kentucky. The facility was built to increase the production of enriched uranium at rates substantially above the other

65

Enforcement Documents - Portsmouth Gaseous Diffusion Plant | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth Gaseous Diffusion Plant Portsmouth Gaseous Diffusion Plant Enforcement Documents - Portsmouth Gaseous Diffusion Plant March 26, 2010 Enforcement Letter, Intennech, Inc. - March 26, 2010 Enforcement Letter issued to Intermech, Inc. related to Installation and Inspection of Anchor Bolts and Pipe Supports at the DUF6 Conversion Buildings at the Portsmouth and Paducah Gaseous Diffusion Plants March 26, 2010 Enforcement Letter, Geiger Brothers Mechanical Contractors, INC - March 26, 2010 Enforcement Letter issued to Geiger Brothers Mechanical Contractors, Inc. related to Installation and Inspection of Penetration Fire Seals at the DUF6 Conversion Building at the Portsmouth Gaseous Diffusion Plant March 26, 2010 Consent Order, Uranium Disposition Services, LLC - NCO-2010-01 Consent Order issued to Uranium Disposition Services, LLC related to

66

Orientation Visit to the Paducah Gaseous Diffusion Plant, July 2011 |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Orientation Visit to the Paducah Gaseous Diffusion Plant, July 2011 Orientation Visit to the Paducah Gaseous Diffusion Plant, July 2011 Orientation Visit to the Paducah Gaseous Diffusion Plant, July 2011 The U.S. Department of Energy (DOE) Office of Enforcement and Oversight, within the Office of Health, Safety and Security (HSS), conducted an orientation visit to the DOE Paducah Site Office (PAD) from July 25-27, 2011. The purpose of the visit was to discuss the nuclear safety oversight strategy, describe the site lead program, increase HSS personnel's operational awareness of the site's activities, and to determine how HSS can carry out its independent oversight and mission support responsibilities. Orientation Visit to the Paducah Gaseous Diffusion Plant, July 2011 More Documents & Publications Independent Activity Report, Portsmouth Gaseous Diffusion Plant - August

67

Gaseous Emissions From Steamboat Springs, Brady'S Hot Springs, And Desert  

Open Energy Info (EERE)

Gaseous Emissions From Steamboat Springs, Brady'S Hot Springs, And Desert Gaseous Emissions From Steamboat Springs, Brady'S Hot Springs, And Desert Peak Geothermal Systems, Nevada Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Paper: Gaseous Emissions From Steamboat Springs, Brady'S Hot Springs, And Desert Peak Geothermal Systems, Nevada Details Activities (3) Areas (3) Regions (0) Abstract: Gaseous emissions from the landscape can be used to explore for geothermal systems, characterize their lateral extent, or map the trends of concealed geologic structures that may provide important reservoir permeability at depth. Gaseous geochemical signatures vary from system to system and utilization of a multi-gas analytical approach to exploration or characterization should enhance the survey's clarity. This paper describes

68

Property:PotentialBiopowerGaseousGeneration | Open Energy Information  

Open Energy Info (EERE)

PotentialBiopowerGaseousGeneration PotentialBiopowerGaseousGeneration Jump to: navigation, search Property Name PotentialBiopowerGaseousGeneration Property Type Quantity Description The estimated potential energy generation from gaseous biopower for a particular place. Use this type to express a quantity of energy. The default unit for energy on OpenEI is the Kilowatt hour (kWh), which is 3,600,000 Joules. http://en.wikipedia.org/wiki/Unit_of_energy It's possible types are Watt hours - 1000 Wh, Watt hour, Watthour Kilowatt hours - 1 kWh, Kilowatt hour, Kilowatthour Megawatt hours - 0.001 MWh, Megawatt hour, Megawatthour Gigawatt hours - 0.000001 GWh, Gigawatt hour, Gigawatthour Joules - 3600000 J, Joules, joules Pages using the property "PotentialBiopowerGaseousGeneration" Showing 25 pages using this property. (previous 25) (next 25)

69

Property:PotentialBiopowerGaseousMass | Open Energy Information  

Open Energy Info (EERE)

PotentialBiopowerGaseousMass PotentialBiopowerGaseousMass Jump to: navigation, search Property Name PotentialBiopowerGaseousMass Property Type Quantity Description The potential mass of gaseous biopower material for a place. Use this type to express a quantity of magnitude, or an object's resistance to acceleration. The default unit is the kilogram (kg). http://en.wikipedia.org/wiki/Kilogram Acceptable units (and their conversions) are: Kilograms - 1 kg, kilo, kilogram, kilograms, Kilogram, kilogramme, kilos Grams - 1000 g, gram, gramme, grams Tonnes - 0.001 tonnes, metric tons, Tonnes, Metric Tonnes Pounds - 2.205 lbs, pounds, pound, Pounds, Lbs Stone - 0.1575 stones, st, stone Ounces - 35.27 ounces, oz, Ounces, ounce BDT - 0.001 BDT, Bone Dry Tonnes, bdt Pages using the property "PotentialBiopowerGaseousMass"

70

Gaseous Detectors: recent developments and applications  

E-Print Network (OSTI)

Since long time, the compelling scientific goals of future high energy physics experiments were a driving factor in the development of advanced detector technologies. A true innovation in detector instrumentation concepts came in 1968, with the development of a fully parallel readout for a large array of sensing elements - the Multiwire Proportional Chamber (MWPC), which earned Georges Charpak a Nobel prize in physics in 1992. Since that time radiation detection and imaging with fast gaseous detectors, capable of economically covering large detection volume with low mass budget, have been playing an important role in many fields of physics. Advances in photo-lithography and micro-processing techniques in the chip industry during the past decade triggered a major transition in the field of gas detectors from wire structures to Micro-Pattern Gas Detector (MPGD) concepts, revolutionizing cell size limitations for many gas detector applications. The high radiation resistance and excellent spatial and time resolution make them an invaluable tool to confront future detector challenges at the next generation of colliders. The design of the new micro-pattern devices appears suitable for industrial production. Novel structures where MPGDs are directly coupled to the CMOS pixel readout represent an exciting field allowing timing and charge measurements as well as precise spatial information in 3D. Originally developed for the high energy physics, MPGD applications has expanded to nuclear physics, UV and visible photon detection, astroparticle and neutrino physics, neutron detection and medical physics.

Maxim Titov

2010-08-23T23:59:59.000Z

71

Property:PotentialBiopowerGaseousCapacity | Open Energy Information  

Open Energy Info (EERE)

PotentialBiopowerGaseousCapacity PotentialBiopowerGaseousCapacity Jump to: navigation, search Property Name PotentialBiopowerGaseousCapacity Property Type Quantity Description The nameplate capacity technical potential from gaseous biopower for a particular place. Use this property to express potential electric energy generation, such as Nameplate Capacity. The default unit is megawatts (MW). For spatial capacity, use property Volume. Acceptable units (and their conversions) are: 1 MW,MWe,megawatt,Megawatt,MegaWatt,MEGAWATT,megawatts,Megawatt,MegaWatts,MEGAWATT,MEGAWATTS 1000 kW,kWe,KW,kilowatt,KiloWatt,KILOWATT,kilowatts,KiloWatts,KILOWATT,KILOWATTS 1000000 W,We,watt,watts,Watt,Watts,WATT,WATTS 1000000000 mW,milliwatt,milliwatts,MILLIWATT,MILLIWATTS 0.001 GW,gigawatt,gigawatts,Gigawatt,Gigawatts,GigaWatt,GigaWatts,GIGAWATT,GIGAWATTS

72

DOE Seeks Deactivation Contractor for Paducah Gaseous Diffusion Plant  

Energy.gov (U.S. Department of Energy (DOE))

Cincinnati The U.S. Department of Energy (DOE) today issued a Request for Task Proposal (RTP) for deactivation activities at the Paducah Gaseous Diffusion Plant (GDP) in Paducah, Kentucky.

73

Pennsylvania Natural Gas Plant Liquids Production, Gaseous Equivalent  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Pennsylvania Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 121 116 93 1970's 79 55 70 71 75 68 61 45 64 49 1980's 41 29 40 55 61 145 234 318 272 254 1990's 300 395 604 513 513 582 603 734 732 879 2000's 586 691 566 647 634 700 794 859 1,008 1,295 2010's 4,578 8,931 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 12/12/2013 Next Release Date: 1/7/2014 Referring Pages: NGPL Production, Gaseous Equivalent Pennsylvania Natural Gas Plant Processing

74

Energy Department Completes K-25 Gaseous Diffusion Building Demolition |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Energy Department Completes K-25 Gaseous Diffusion Building Energy Department Completes K-25 Gaseous Diffusion Building Demolition Energy Department Completes K-25 Gaseous Diffusion Building Demolition December 19, 2013 - 12:00pm Addthis K-25 Demolition - Oak Ridge 2013 K-25 Demolition - Oak Ridge 2013 Media Contacts Ben Williams, DOE, (865) 574-4912 Wayne McKinney, UCOR, (865) 576-6284 Oak Ridge, Tenn. - Today, the Department of Energy announced that its contractor URS|CH2M Oak Ridge, LLC, or UCOR, has completed demolition of the K-25 gaseous diffusion building, the largest facility in the DOE complex. UCOR took over the project in 2011 and has maintained a strong safety record while completing the demolition over one year ahead of its current schedule and approximately $300 million under the current budget. All debris removal is expected to be completed in spring 2014.

75

Feasibility of gas-phase decontamination of gaseous diffusion equipment  

SciTech Connect

The five buildings at the K-25 Site formerly involved in the gaseous diffusion process contain 5000 gaseous diffusion stages as well as support facilities that are internally contaminated with uranium deposits. The gaseous diffusion facilities located at the Portsmouth Gaseous Diffusion Plant and the Paducah Gaseous Diffusion Plant also contain similar equipment and will eventually close. The decontamination of these facilities will require the most cost-effective technology consistent with the criticality, health physics, industrial hygiene, and environmental concerns; the technology must keep exposures to hazardous substances to levels as low as reasonably achievable (ALARA). This report documents recent laboratory experiments that were conducted to determine the feasibility of gas-phase decontamination of the internal surfaces of the gaseous diffusion equipment that is contaminated with uranium deposits. A gaseous fluorinating agent is used to fluorinate the solid uranium deposits to gaseous uranium hexafluoride (UF{sub 6}), which can be recovered by chemical trapping or freezing. The lab results regarding the feasibility of the gas-phase process are encouraging. These results especially showed promise for a novel decontamination approach called the long-term, low-temperature (LTLT) process. In the LTLT process: The equipment is rendered leak tight, evacuated, leak tested, and pretreated, charged with chlorine trifluoride (ClF{sub 3}) to subatmospheric pressure, left for an extended period, possibly > 4 months, while processing other items. Then the UF{sub 6} and other gases are evacuated. The UF{sub 6} is recovered by chemical trapping. The lab results demonstrated that ClF{sub 3} gas at subatmospheric pressure and at {approx} 75{degree}F is capable of volatilizing heavy deposits of uranyl fluoride from copper metal surfaces sufficiently that the remaining radioactive emissions are below limits.

Munday, E.B.; Simmons, D.W.

1993-02-01T23:59:59.000Z

76

Polybenzimidazole compounds  

SciTech Connect

A PBI compound that includes imidazole nitrogens, at least a portion of which are substituted with an organic-inorganic hybrid moiety. At least 85% of the imidazole nitrogens may be substituted. The organic-inorganic hybrid moiety may be an organosilane moiety, for example, (R)Me.sub.2SiCH.sub.2--, where R is selected from among methyl, phenyl, vinyl, and allyl. The PBI compound may exhibit similar thermal properties in comparison to the unsubstituted PBI. The PBI compound may exhibit a solubility in an organic solvent greater than the solubility of the unsubstituted PBI. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may occur at about room temperature and/or at about atmospheric pressure. Substituting may use at least five equivalents in relation to the imidazole nitrogens to be substituted or, preferably, about fifteen equivalents.

Klaehn, John R. (Idaho Falls, ID); Peterson, Eric S. (Idaho Falls, ID); Wertsching, Alan K. (Idaho Falls, ID); Orme, Christopher J. (Shelley, ID); Luther, Thomas A. (Idaho Falls, ID); Jones, Michael G. (Pocatello, ID)

2010-08-10T23:59:59.000Z

77

Polybenzimidazole compounds  

DOE Patents (OSTI)

A PBI compound includes imidazole nitrogens at least a portion of which are substituted with a moiety containing a carbonyl group, the substituted imidazole nitrogens being bonded to carbon of the carbonyl group. At least 85% of the nitrogens may be substituted. The carbonyl-containing moiety may include RCO--, where R is alkoxy or haloalkyl. The PBI compound may exhibit a first temperature marking an onset of weight loss corresponding to reversion of the substituted PBI that is less than a second temperature marking an onset of decomposition of an otherwise identical PBI compound without the substituted moiety. The PBI compound may be included in separatory media. A substituted PBI synthesis method may include providing a parent PBI in a less than 5 wt % solvent solution. Substituting may use more than 5 equivalents in relation to the imidazole nitrogens to be substituted.

Klaehn, John R. (Idaho Falls, ID); Peterson, Eric S. (Idaho Falls, ID); Orme, Christopher J. (Shelley, ID); Jones, Michael G. (Chubbuck, ID); Wertsching, Alan K. (Idaho Falls, ID); Luther, Thomas A. (Idaho Falls, ID); Trowbridge, Tammy L. (Idaho Falls, ID)

2011-11-22T23:59:59.000Z

78

Syntheses and studies of organosilicon compounds  

SciTech Connect

The syntheses of polycarbosilanes and polysilanes as silicon carbide ceramic precursors have been active research areas in the Barton Research Group. In this thesis, the work is focused on the preparation of polycarbosilanes and polysilanes as stoichiometric silicon carbide precursor polymers. The syntheses of the precursor polymers are discussed and the conversions of these precursors to silicon carbide via pyrolysis are reported. The XRD pattern and elemental analyses of the resulting silicon carbide ceramics are presented. Silicon monoxide is an important intermediate in the production of silicon metal. The existence of silicon monoxide in gap phase has been widely accepted. In the second part of this thesis, the generation of gaseous silicon monoxide in four different reactors and the reactions of gaseous silicon monoxide towards organic compounds are discussed.

Xie, R.

1999-02-12T23:59:59.000Z

79

Independent Oversight Review, Portsmouth Gaseous Diffusion Plant - April  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

April 2013 April 2013 Independent Oversight Review, Portsmouth Gaseous Diffusion Plant - April 2013 April 2013 Review of the Integrated Safety Management System Phase I Verification Review at the Portsmouth Gaseous Diffusion Plant The Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), conducted an independent review of the U.S. Department of Energy (DOE) Portsmouth/Paducah Project Office (PPPO). The objective of the Independent Oversight review was to evaluate PPPO's conduct of the Integrated Safety Management System (ISMS) Phase I verification review at the Portsmouth Gaseous Diffusion Plant (PORTS). The contractor at PORTS is Fluor-Babcock & Wilcox Portsmouth (FBP). The HSS Office of Safety and Emergency Management Evaluations

80

Paducah Gaseous Diffusion Plant, Construction Worker Screening Project |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Paducah Gaseous Diffusion Plant, Construction Worker Screening Paducah Gaseous Diffusion Plant, Construction Worker Screening Project Paducah Gaseous Diffusion Plant, Construction Worker Screening Project Project Name: Building Trades National Medical Screening Program Covered DOE Site: Paducah Worker Population Served: Construction Workers Principal Investigator: Knut Ringen, DrPH, MHA, MPH Toll-free Telephone: (888) 464-0009 Local Outreach Office: Joe Hudson 1930 North 13th Street Paducah, KY 42001 Website: http://www.btmed.org This project is intended to provide free medical screening to former workers in the building trades (construction workers). The screening targets health problems resulting from exposures, including asbestos, beryllium, cadmium, chromium, lead, mercury, noise, radiation, silica and/or solvents. The project is being carried out by a large group led by

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Portsmouth Gaseous Diffusion Plant, Former Production Workers Screening  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth Gaseous Diffusion Plant, Former Production Workers Portsmouth Gaseous Diffusion Plant, Former Production Workers Screening Projects Portsmouth Gaseous Diffusion Plant, Former Production Workers Screening Projects Project Name: Worker Health Protection Program Covered DOE Site: Portsmouth Worker Population Served: Production Workers Principal Investigator: Jim Frederick Co-Principal Investigator: Steven Markowitz, MD Toll-free Telephone: (888) 241-1199 Local Outreach Office: Jeanne Cisco 2288 Wakefield Mound Road Piketon, OH 45661 Website: http://www.worker-health.org/ This project is conducted by the Unitedsteel Workers in conjunction with Queens College of the City University of New York. The program is being offered as a service to both former and current workers. Free of charge, eligible workers can receive a medical exam, including chest X-ray and

82

GROW1: a crop growth model for assessing impacts of gaseous pollutants from geothermal technologies  

DOE Green Energy (OSTI)

A preliminary model of photosynthesis and growth of field crops was developed to assess the effects of gaseous pollutants, particularly airborne sulfur compounds, resulting from energy production from geothermal resources. The model simulates photosynthesis as a function of such variables as irradiance, CO/sub 2/ diffusion resistances, and internal biochemical processes. The model allocates the products of photosynthesis to structural (leaf, stem, root, and fruit) and storage compartments of the plant. The simulations encompass the entire growing season from germination to senescence. The model is described conceptually and mathematically and examples of model output are provided for various levels of pollutant stress. Also, future developments that would improve this preliminary model are outlined and its applications are discussed.

Kercher, J.R.

1977-03-17T23:59:59.000Z

83

Artificial neural network in gaseous emissions prediction with bioreactor usage  

Science Conference Proceedings (OSTI)

The artificial neural network is used more and more often for prediction of processes related with the biowaste management. In this area, composting is one of the most important process of biowaste recycling. However, the gaseous emissions from the composted ... Keywords: composting, data acquisition, emissions, multilayer perceptron, neural modeling, prediction

Piotr Boniecki; Jacek Dach; Krzysztof Pilarski; Aleksander J?dru?; Krzysztof Nowakowski; Hanna Piekarska-Boniecka; Jacek Przyby?

2012-05-01T23:59:59.000Z

84

Methods for deacidizing gaseous mixtures by phase enhanced absorption  

SciTech Connect

An improved process for deacidizing a gaseous mixture using phase enhanced gas-liquid absorption is described. The process utilizes a multiphasic absorbent that absorbs an acid gas at increased rate and leads to reduced overall energy costs for the deacidizing operation.

Hu, Liang

2012-11-27T23:59:59.000Z

85

The real air quality benefits of gaseous-fueled vehicles.  

SciTech Connect

This paper provides a justification for prominent inclusion of currently available gaseous-fueled vehicles (i.e., vehicles powered by propane, sometimes called liquefied petroleum gas [LPG], or natural gas--chiefly, methane--stored onboard the vehicle in gaseous or liquid state but combusted as a gas) in the mix of strategies to (a) reduce public exposure to toxic and fine particulate emissions in the urbanized areas of the developing world and (b) achieve local and regional improvements in ozone air quality. It also presents estimates of associated emission reduction credits into the future. Important considerations discussed are the location of fine particle and toxic emissions in congested urban areas, and the location and timing of ozone precursor emissions, with emphasis on how gaseous-fueled vehicles' role in the relationship among and magnitude of these variables differs from that of their conventionally-fueled counterparts. Efforts to enhance the measurement and quantification of gaseous-fuel benefits are also described.

Saricks, C. L.

2002-03-28T23:59:59.000Z

86

Adaptive high-resolution simulation of realistic gaseous detonation waves  

DOE Green Energy (OSTI)

The numerical approximation of detonation waves in gaseous combustible mixtures is extremely demanding since a wide range of scales needs to be resolved. A dynamically adaptive high-resolution finite volume method is described that has enabled accurately resolved computational investigations of the transient behavior of regularly oscillating detonations in low-pressure hydrogen-oxygen mixtures in realistic two-dimensional geometry.

Deiterding, Ralf [ORNL

2007-01-01T23:59:59.000Z

87

Recent Advances in Laser-based Diagnostics for Gaseous Flows  

Science Conference Proceedings (OSTI)

Laser-based diagnostic techniques offer unique capabilities for experimentation on gaseous flows. In this paper, we overview recent progress of two concepts: spectrally resolved absorption and planar laser-induced fluorescence (PLIF) imaging. The absorption ... Keywords: PLIF, absorption spectroscopy, acetone, combustion control, diode laser, hypersonic, supersonic

R. Hanson; D. Baer; C. Morris; M. Thurber; E. Furlong; S. Wehe

1999-12-01T23:59:59.000Z

88

Estimation of Carbon-14 in Nuclear Power Plant Gaseous Effluents  

Science Conference Proceedings (OSTI)

Nuclear power plants report the amount of radioactivity released through permitted effluent pathways in their plant annual reports. This report provides users with a method for calculating the amount of carbon-14 (14C) generated in a light water reactor (LWR) core and released through plant gaseous effluent pathways.

2010-12-21T23:59:59.000Z

89

Mississippi Natural Gas Plant Liquids Production, Gaseous Equivalent  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Mississippi Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 1,127 971 1,334 1970's 1,270 1,217 1,058 878 679 567 520 367 485 1,146 1980's 553 830 831 633 618 458 463 437 811 380 1990's 445 511 416 395 425 377 340 300 495 5,462 2000's 11,377 15,454 16,477 11,430 13,697 14,308 14,662 13,097 10,846 18,354 2010's 18,405 11,221 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 12/12/2013 Next Release Date: 1/7/2014 Referring Pages: NGPL Production, Gaseous Equivalent

90

Arkansas Natural Gas Plant Liquids Production, Gaseous Equivalent (Million  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Arkansas Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 3,499 3,667 3,475 1970's 3,235 2,563 1,197 1,118 952 899 823 674 883 1,308 1980's 1,351 1,327 1,287 1,258 1,200 1,141 1,318 1,275 1,061 849 1990's 800 290 413 507 553 488 479 554 451 431 2000's 377 408 395 320 254 231 212 162 139 168 2010's 213 268 424 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 12/12/2013 Next Release Date: 1/7/2014 Referring Pages: NGPL Production, Gaseous Equivalent

91

Reactive codoping of GaAlInP compound semiconductors  

DOE Patents (OSTI)

A GaAlInP compound semiconductor and a method of producing a GaAlInP compound semiconductor are provided. The apparatus and method comprises a GaAs crystal substrate in a metal organic vapor deposition reactor. Al, Ga, In vapors are prepared by thermally decomposing organometallic compounds. P vapors are prepared by thermally decomposing phospine gas, group II vapors are prepared by thermally decomposing an organometallic group IIA or IIB compound. Group VIB vapors are prepared by thermally decomposing a gaseous compound of group VIB. The Al, Ga, In, P, group II, and group VIB vapors grow a GaAlInP crystal doped with group IIA or IIB and group VIB elements on the substrate wherein the group IIA or IIB and a group VIB vapors produced a codoped GaAlInP compound semiconductor with a group IIA or IIB element serving as a p-type dopant having low group II atomic diffusion.

Hanna, Mark Cooper (Boulder, CO); Reedy, Robert (Golden, CO)

2008-02-12T23:59:59.000Z

92

Phyto remediation groundwater trends at the DOE portsmouth gaseous  

Science Conference Proceedings (OSTI)

This paper describes the progress of a phyto-remediation action being performed at the Department of Energy (DOE) Portsmouth Gaseous Diffusion Plant (PORTS) X-740 Waste Oil Handling Facility to remediate contaminated groundwater under a Resource Conservation and Recovery Act (RCRA) closure action. This action was effected by an Ohio Environmental Protection Agency (OEPA) decision to use phyto-remediation as the preferred remedy for the X-740 groundwater contamination. This remedy was recognized as a cost-effective, low-maintenance, and promising method to remediate groundwater contaminated with volatile organic compounds (VOCs), primarily trichloroethylene (TCE). During 1999, prior to the tree installation at the X-740 Phyto-remediation Area, water level measurements in the area were collected from 10 monitoring wells completed in the Gallia Formation. The Gallia is the uppermost water-bearing zone and contains most of the groundwater contamination at PORTS. During the tree installation which took place during the summer of 1999, four new Gallia monitoring wells were installed at the X-740 Area in addition to the 10 Gallia wells which had been installed in the same area during the early 1990's. Manual water level measurements were collected quarterly from these 14 Gallia monitoring wells between 1998 and 2001. These manual water level measurements were collected to monitor the combined impact of the trees on the groundwater prior to root development. Beginning in 2001, water level measurements were collected monthly during the growing season (April-September) and quarterly during the dormant season (October-March). A total of eight water level measurements were collected annually to monitor the phyto-remediation system's effect on the groundwater in the X- 740 Area. The primary function of the X-740 Phyto-remediation Area is to hydraulically prevent further spreading of the TCE plume. This process utilizes deep-rooted plants, such as poplar trees, to extract large quantities of water from the saturated zone. The focus of any phyto-remediation system is to develop a cone of depression under the entire plantation area. This cone of depression can halt migration of the contaminant plume and can create a hydraulic barrier, thereby maintaining plume capture. While a cone of depression is not yet evident at the X-740 Phyto-remediation Area, water level measurements in 2004 and 2005 differed from measurements taken in previous years, indicating that the now mature trees are influencing groundwater flow direction and gradient at the site. Water level measurements taken from 2003 through 2005 indicate a trend whereby groundwater elevations steadily decreased in the X-740 Phyto-remediation System. During this time, an average groundwater table drop of 0.30 feet was observed. Although the time for the phyto-remediation system to mature had been estimated at two to three years, these monitoring data indicate a period of four to five years for the trees to reach maturity. Although, these trends are not apparent from analysis of the potentiometric surface contours, it does appear that the head gradient across the site is higher during the spring and lower during the fall. It is not clear, however, whether this trend was initiated by the installation of the phyto-remediation system. This paper will present the groundwater data collected to date to illustrate the effects of the trees on the groundwater table. (authors)

Lewis, A.C.; Baird, D.R. [CDM, Piketon, OH (United States)

2007-07-01T23:59:59.000Z

93

Gaseous Hydrogen Delivery Breakout - Strategic Directions for Hydrogen Delivery Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Gaseous Hydrogen Gaseous Hydrogen Delivery Breakout Strategic Directions for Hydrogen Delivery Workshop May 7-8, 2003 Crystal City, Virginia Breakout Session Name Targets/Objectives More work is needed to better define delivery target metrics Assumptions about targets for costs and energy efficiency need to be qualified Technology improvements likely to lower costs, but may not have major impact on total cost A significant impact on cost would come through permitting policy changes, e.g., use of public land Breakout Session Name Priority Barriers System Issues: need to assess delivery options in context of total system Materials: corrosion, H2 permeability Construction: welding, joining Maintenance and Operation: leak detection Pipeline Safety: odorants, flame visibility

94

Orientation Visit to the Portsmouth Gaseous Diffusion Plant  

NLE Websites -- All DOE Office Websites (Extended Search)

PORTS-2011-08-03 PORTS-2011-08-03 Site: Portsmouth Gaseous Diffusion Plant Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for the Orientation Visit to the Portsmouth Gaseous Diffusion Plant Dates of Activity : 08/01/2011 - 08/03/2011 Report Preparer: Joseph P. Drago Activity Description/Purpose: The U.S. Department of Energy (DOE) Office of Enforcement and Oversight, within the Office of Health, Safety and Security (HSS), conducted an orientation visit to the DOE Portsmouth Site Office (PORTS) and the Portsmouth/Paducah Project Office (PPPO) in Lexington, Kentucky, from August 1-3, 2011. The purpose of the visit was to discuss the nuclear safety oversight strategy, describe the site lead program, increase HSS personnel's operational awareness of the site's

95

Orientation Visit to the Paducah Gaseous Diffusion Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

PAD-2011-07-27 PAD-2011-07-27 Site: Paducah Gaseous Diffusion Plant Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for the Orientation Visit to the Paducah Gaseous Diffusion Plant Dates of Activity : 07/25/2011 - 07/27/2011 Report Preparer: Joseph P. Drago Activity Description/Purpose: The U.S. Department of Energy (DOE) Office of Enforcement and Oversight, within the Office of Health, Safety and Security (HSS), conducted an orientation visit to the DOE Paducah Site Office (PAD) from July 25-27, 2011. The purpose of the visit was to discuss the nuclear safety oversight strategy, describe the site lead program, increase HSS personnel's operational awareness of the site's activities, and to determine how HSS can carry out its independent oversight and mission

96

Orientation Visit to the Paducah Gaseous Diffusion Plant  

NLE Websites -- All DOE Office Websites (Extended Search)

PAD-2011-07-27 PAD-2011-07-27 Site: Paducah Gaseous Diffusion Plant Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for the Orientation Visit to the Paducah Gaseous Diffusion Plant Dates of Activity : 07/25/2011 - 07/27/2011 Report Preparer: Joseph P. Drago Activity Description/Purpose: The U.S. Department of Energy (DOE) Office of Enforcement and Oversight, within the Office of Health, Safety and Security (HSS), conducted an orientation visit to the DOE Paducah Site Office (PAD) from July 25-27, 2011. The purpose of the visit was to discuss the nuclear safety oversight strategy, describe the site lead program, increase HSS personnel's operational awareness of the site's activities, and to determine how HSS can carry out its independent oversight and mission

97

Federal Facility Agreement for the Paducah Gaseous Diffusion Plant Summary  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Federal Facility Agreement for the Paducah Gaseous Federal Facility Agreement for the Paducah Gaseous Diffusion Plant State Kentucky Agreement Type Federal Facility Agreement Legal Driver(s) CERCLA/RCRA Scope Summary Ensure that the environmental impacts of activities at the Site are investigated and appropriate response actions are taken. Parties U.S. DOE; Kentucky Natural Resources and Environmental Protection Cabinet; U.S. EPA Date 2/01/1998 SCOPE * Ensure all releases of hazardous substances, pollutants, or contaminants are addressed to achieve comprehensive remediation of the site. * Establish a procedural framework and schedule for developing, implementing, and monitoring response actions in accordance with CERCLA, RCRA, and Kentucky Law. * Facilitate cooperation, exchange of information, and participation of the Parties and

98

Orientation Visit to the Portsmouth Gaseous Diffusion Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

PORTS-2011-08-03 PORTS-2011-08-03 Site: Portsmouth Gaseous Diffusion Plant Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for the Orientation Visit to the Portsmouth Gaseous Diffusion Plant Dates of Activity : 08/01/2011 - 08/03/2011 Report Preparer: Joseph P. Drago Activity Description/Purpose: The U.S. Department of Energy (DOE) Office of Enforcement and Oversight, within the Office of Health, Safety and Security (HSS), conducted an orientation visit to the DOE Portsmouth Site Office (PORTS) and the Portsmouth/Paducah Project Office (PPPO) in Lexington, Kentucky, from August 1-3, 2011. The purpose of the visit was to discuss the nuclear safety oversight strategy, describe the site lead program, increase HSS personnel's operational awareness of the site's

99

Paducah Gaseous Diffusion Plant Annual Site Environmental Report for 1993  

SciTech Connect

The purpose of this document is to summarize effluent monitoring and environmental surveillance results and compliance with environmental laws, regulations, and orders at the Paducah Gaseous Diffusion Plant (PGDP). Environmental monitoring at PGDP consists of two major activities: effluent monitoring and environmental surveillance. Effluent monitoring is direct measurement or the collection and analysis of samples of liquid and gaseous discharges to the environment. Environmental surveillance is direct measurement or the collection and analysis of samples of air, water, soil, foodstuff, biota, and other media. Environmental monitoring is performed to characterize and quantify contaminants, assess radiation exposures of members of the public, demonstrate compliance with applicable standards and permit requirements, and detect and assess the effects (if any) on the local environment. Multiple samples are collected throughout the year and are analyzed for radioactivity, chemical content, and various physical attributes.

Not Available

1994-10-01T23:59:59.000Z

100

Method for diverting a gaseous sand-consolidating fluid  

SciTech Connect

An unconsolidated gas-producing sand in which the permeability is layered and the productivity can be impaired by liquid blocking can be consolidated by wetting the rock surfaces with a limited amount of water, injecting a smoke which selectively reduces the permeability of the most permeable layers by depositing on their faces unconsolidated masses of substantially inert solid particles and injecting a gaseous silicon polyhalide to convert a significant proportion of the rock surface-wettingwater to a grain bonding silica gel.

Davies, D. R.; Richardson, E. A.

1980-12-30T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Method and apparatus for analyzing particle-containing gaseous suspensions  

DOE Patents (OSTI)

The method and apparatus permit analyses, by optical means, of properties of gaseous suspensions of particles, by measuring radiation that is emitted, transmitted or scattered by the particles. Determinations of composition, size, temperature and spectral emittance can be performed either in-situ or by sampling, and Fourier-transform infrared spectrometric techniques are most effectively used. Apparatus specifically adapted for performing radiation scattering analyses, and for collecting radiation from different sources, are provided. 51 figs.

Solomon, P.R.; Carangelo, R.M.; Best, P.E.

1987-03-24T23:59:59.000Z

102

North Dakota Natural Gas Plant Liquids Production, Gaseous Equivalent  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) North Dakota Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 5,150 5,428 4,707 1970's 4,490 3,592 3,199 2,969 2,571 2,404 2,421 2,257 2,394 2,986 1980's 3,677 5,008 5,602 7,171 7,860 8,420 6,956 7,859 6,945 6,133 1990's 6,444 6,342 6,055 5,924 5,671 5,327 4,937 5,076 5,481 5,804 2000's 6,021 6,168 5,996 5,818 6,233 6,858 7,254 7,438 7,878 10,140 2010's 11,381 14,182 26,156 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 1/7/2014

103

Louisiana Natural Gas Plant Liquids Production, Gaseous Equivalent (Million  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Louisiana Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 115,177 140,290 179,117 1970's 193,209 195,072 197,967 206,833 194,329 189,541 172,584 166,392 161,511 165,515 1980's 142,171 142,423 128,858 124,193 132,501 117,736 115,604 124,890 120,092 121,425 1990's 119,405 129,154 132,656 130,336 128,583 146,048 139,841 150,008 144,609 164,794 2000's 164,908 152,862 152,724 124,955 133,434 103,381 105,236 110,745 94,785 95,359 2010's 102,448 95,630 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data.

104

Michigan Natural Gas Plant Liquids Production, Gaseous Equivalent (Million  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Michigan Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 3,351 3,244 2,705 1970's 2,330 2,013 1,912 1,581 1,921 2,879 6,665 11,494 14,641 15,686 1980's 15,933 14,540 14,182 13,537 12,829 11,129 11,644 10,876 10,483 9,886 1990's 8,317 8,103 8,093 7,012 6,371 6,328 6,399 6,147 5,938 5,945 2000's 5,322 4,502 4,230 3,838 4,199 3,708 3,277 3,094 3,921 2,334 2010's 2,943 2,465 2,480 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 12/12/2013

105

California Natural Gas Plant Liquids Production, Gaseous Equivalent  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) California Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 34,803 32,639 30,334 1970's 29,901 27,585 24,156 17,498 17,201 15,221 14,125 13,567 13,288 10,720 1980's 8,583 7,278 14,113 14,943 15,442 16,973 16,203 15,002 14,892 13,376 1990's 12,424 11,786 12,385 12,053 11,250 11,509 12,169 11,600 10,242 10,762 2000's 11,063 11,060 12,982 13,971 14,061 13,748 14,056 13,521 13,972 13,722 2010's 13,244 12,095 12,755 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data.

106

Kentucky Natural Gas Plant Liquids Production, Gaseous Equivalent (Million  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Kentucky Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 11,500 8,573 8,579 1970's 6,574 6,133 6,063 5,441 5,557 5,454 5,231 4,764 6,192 3,923 1980's 6,845 5,638 6,854 6,213 6,516 6,334 4,466 2,003 2,142 1,444 1990's 1,899 2,181 2,342 2,252 2,024 2,303 2,385 2,404 2,263 2,287 2000's 1,416 1,558 1,836 1,463 2,413 1,716 2,252 1,957 2,401 3,270 2010's 4,576 4,684 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 12/12/2013 Next Release Date: 1/7/2014

107

New Mexico Natural Gas Plant Liquids Production, Gaseous Equivalent  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) New Mexico Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 46,149 48,635 50,484 1970's 52,647 53,810 54,157 55,782 54,986 56,109 61,778 72,484 77,653 62,107 1980's 59,457 60,544 56,857 56,304 58,580 53,953 51,295 65,156 63,355 61,594 1990's 66,626 70,463 75,520 83,193 86,607 85,668 108,341 109,046 106,665 107,850 2000's 110,411 108,958 110,036 111,292 105,412 101,064 99,971 96,250 92,579 94,840 2010's 91,963 90,291 84,562 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data.

108

Colorado Natural Gas Plant Liquids Production, Gaseous Equivalent (Million  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Colorado Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 4,126 4,546 4,058 1970's 3,405 4,152 4,114 4,674 6,210 9,620 11,944 13,507 13,094 12,606 1980's 12,651 13,427 12,962 11,314 10,771 11,913 10,441 10,195 11,589 13,340 1990's 13,178 15,822 18,149 18,658 19,612 25,225 23,362 28,851 24,365 26,423 2000's 29,105 29,195 31,952 33,650 35,821 34,782 36,317 38,180 53,590 67,607 2010's 82,637 90,801 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data.

109

Alabama Natural Gas Plant Liquids Production, Gaseous Equivalent (Million  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Alabama Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 236 1970's 225 281 243 199 501 694 661 933 1,967 4,845 1980's 4,371 4,484 4,727 4,709 5,123 5,236 4,836 4,887 4,774 5,022 1990's 4,939 4,997 5,490 5,589 5,647 5,273 5,361 4,637 4,263 18,079 2000's 24,086 13,754 14,826 11,293 15,133 13,759 21,065 19,831 17,222 17,232 2010's 19,059 17,271 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 12/12/2013 Next Release Date: 1/7/2014 Referring Pages:

110

Texas Natural Gas Plant Liquids Production, Gaseous Equivalent (Million  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Texas Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 433,684 457,117 447,325 1970's 466,016 448,288 470,105 466,143 448,993 435,571 428,635 421,110 393,819 352,650 1980's 350,312 345,262 356,406 375,849 393,873 383,719 384,693 364,477 357,756 343,233 1990's 342,186 353,737 374,126 385,063 381,020 381,712 398,442 391,174 388,011 372,566 2000's 380,535 355,860 360,535 332,405 360,110 355,589 373,350 387,349 401,503 424,042 2010's 433,622 481,308 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data.

111

Bismaleimide compounds  

DOE Patents (OSTI)

Bismaleimides of the formula ##STR1## wherein R.sub.1 and R.sub.2 each independently is H, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, C1 or Br, or R.sub.1 and R.sub.2 together form a fused 6-membered hydrocarbon aromatic ring, with the proviso that R.sub.1 and R.sub.2 are not t-butyl or t-butoxy; X is O, S or Se; n is 1-3; and the alkylene bridging group, optionally, is substituted by 1-3 methyl groups or by fluorine, form polybismaleimide resins which have valuable physical properties. Uniquely, these compounds permit extended cure times, i.e., they remain fluid for a time sufficient to permit the formation of a homogeneous melt prior to curing.

Adams, Johnnie E. (Grandview, MO); Jamieson, Donald R. (Merriam, KS)

1986-01-14T23:59:59.000Z

112

Infrared absorption strengths of potential gaseous diffusion plant coolants and related reaction products  

SciTech Connect

The DOE gaseous diffusion plant complex makes extensive use of CFC-114 as a primary coolant. As this material is scheduled for production curtailment within the next few years, a search for substitutes is underway, and apparently workable alternatives have been found and are under testing. The presently favored substitutes, FC-c3l8 and FC-3110, satisfy ozone depletion and operational chemical compatibility concerns, but will be long-lived greenhouse gases, and thus may be regulated on that basis in the future. A further search is therefore underway for compounds with shorter atmospheric lifetimes which could otherwise satisfy operational physical and chemical requirements. A number of such candidates are in the process of being screened for chemical compatibility in a fluorinating environment. This document presents infrared spectral data developed and used in that study for candidates recently examined, and also for many of their fluorination reaction products. The data include gas-phase infrared spectra, quantitative peak intensities as a function of partial pressure, and integrated absorbance strength in the IR-transparent atmospheric window of interest to global warming modeling. Combining this last property with literature or estimated atmospheric lifetimes, rough estimates of global warming potential for these compounds are also presented.

Trowbridge, L.D.; Angel, E.C.

1993-05-01T23:59:59.000Z

113

Pyrolitic Uranium Compound (PYRUC)  

NLE Websites -- All DOE Office Websites (Extended Search)

Pyrolitic Uranium Compound Pyrolitic Uranium Compound (PYRUC) PYRolitic Uranium Compound (PYRUC) is a shielding material consisting of depleted uranium UO2 or UC in either pellet...

114

Uranium and Its Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

and Its Compounds Uranium and Its Compounds line line What is Uranium? Chemical Forms of Uranium Properties of Uranium Compounds Radioactivity and Radiation Uranium Health Effects...

115

Gaseous divertor simulation in an arc-jet device  

SciTech Connect

The first experimental simulation of the gaseous tokamak divertor is presented. Significant results are: (1) neutral gas at a pressure of a few mTorr is sufficient to absorb the entire localized flux of plasma thermal energy and reidstribute it over a wide area; (2) elastic ion-neutral collisions constitute the main energy absorbing process (at T/sub e,i/ less than or equal to 5 eV), and (3) a large pressure difference between divertor and main plasma chamber is maintained by plasma pumping in the connecting channel.

Hsu, W.L.; Yamada, M.; Barrett, P.J.

1982-12-01T23:59:59.000Z

116

Removing gaseous contaminants in {sup 3}He by cryogenic stripping  

SciTech Connect

The Tritium Operations Group at LLNL, Tritium Facility has recently developed a {sup 3}He recovery system to remove argon, xenon, neon, hydrogen, and all other contaminants from the {sup 3}He stream in an Accelerator Production of Tritium (APT) experimental apparatus. In this paper the authors will describe in detail the background information, technical requirements, the design approach, and the results of their experimental tests. The authors believe this gas purification system may have other applications as it provides at a reasonable cost an efficient method for purification of gaseous helium.

Benapfl, M.; Biltoft, P.; Coombs, A. [Lawrence Livermore National Lab., CA (United States). Tritium Operations Group

1995-08-17T23:59:59.000Z

117

Portsmouth Gaseous Diffusion Plant Environmental report for 1990  

Science Conference Proceedings (OSTI)

This calendar year 1990 annual report on environmental surveillance of the US Department of Energy's (DOE's) Portsmouth Gaseous Diffusion Plant (PORTS) and its environs consists of two parts: the summary, discussion, and conclusions (Part 1) and the data presentation (Part 2). The objectives of this report are as follows: report 1990 monitoring data for the installation and its environs that may have been affected by operations on the plant site, provide reasonably detailed information about the plant site and plant operations, provide detailed information on input and assumptions used in all calculations, provide trend analyses (when appropriate) to indicate increases and decreases in environmental impact, and provide general information on plant quality assurance.

Counce-Brown, D. (ed.)

1991-09-01T23:59:59.000Z

118

DOE Seeks Proposals for Portsmouth Gaseous Diffusion Plant Technical Services Contract  

Energy.gov (U.S. Department of Energy (DOE))

Cincinnati - The Department of Energy today issued a Draft Request for Proposals (RFP) for an Environmental Technical Services acquisition at the Portsmouth Gaseous Diffusion Plant near Piketon, Ohio.

119

Low energy consumption method for separating gaseous mixtures and in particular for medium purity oxygen production  

DOE Patents (OSTI)

A method for the separation of gaseous mixtures such as air and for producing medium purity oxygen, comprising compressing the gaseous mixture in a first compressor to about 3.9-4.1 atmospheres pressure, passing said compressed gaseous mixture in heat exchange relationship with sub-ambient temperature gaseous nitrogen, dividing the cooled, pressurized gaseous mixture into first and second streams, introducing the first stream into the high pressure chamber of a double rectification column, separating the gaseous mixture in the rectification column into a liquid oxygen-enriched stream and a gaseous nitrogen stream and supplying the gaseous nitrogen stream for cooling the compressed gaseous mixture, removing the liquid oxygen-enriched stream from the low pressure chamber of the rectification column and pumping the liquid, oxygen-enriched steam to a predetermined pressure, cooling the second stream, condensing the cooled second stream and evaporating the oxygen-enriched stream in an evaporator-condenser, delivering the condensed second stream to the high pressure chamber of the rectification column, and heating the oxygen-enriched stream and blending the oxygen-enriched stream with a compressed blend-air stream to the desired oxygen concentration.

Jujasz, Albert J. (North Olmsted, OH); Burkhart, James A. (Olmsted Falls, OH); Greenberg, Ralph (New York, NY)

1988-01-01T23:59:59.000Z

120

Liquefied Gaseous Fuels Spill Test Facility: Overview of STF capabilities  

SciTech Connect

The Liquefied Gaseous Fuels Spill Test Facility (STF) constructed at the Department of Energy`s Nevada Test Site is a basic research tool for studying the dynamics of accidental releases of various hazardous liquids. This Facility is designed to (1) discharge, at a controlled rate, a measured volume of hazardous test liquid on a prepared surface of a dry lake bed (Frenchman Lake); (2) monitor and record process operating data, close-in and downwind meteorological data, and downwind gaseous concentration levels; and (3) provide a means to control and monitor these functions from a remote location. The STF will accommodate large and small-scale testing of hazardous test fluid release rates up to 28,000 gallons per minute. Spill volumes up to 52,800 gallons are achievable. Generic categories of fluids that can be tested are cryogenics, isothermals, aerosol-forming materials, and chemically reactive. The phenomena that can be studied include source definition, dispersion, and pool fire/vapor burning. Other capabilities available at the STF include large-scale wind tunnel testing, a small test cell for exposing personnel protective clothing, and an area for developing mitigation techniques.

Gray, H.E.

1993-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Online learning of a neural fuel control system for gaseous fueled si engines  

Science Conference Proceedings (OSTI)

This dissertation presents a new type of fuel control algorithm for gaseous fuelled vehicles. Gaseous fuels such as hydrogen and natural gas have been shown to be less polluting than liquid fuels such as gasoline, both at the tailpipe and on a total ...

Travis Kent Wiens

2008-01-01T23:59:59.000Z

122

Extending the Photon Mapping Method for Realistic Rendering of Hot Gaseous Fluids  

E-Print Network (OSTI)

fluid dynamics have proved very successful. As a result, diverse physically based fluid animation fluids. In addition to the generation of ap- pealing motions of gaseous fluids, several inter- esting, they are gen- erated within the gaseous fluid, but an energy value is assigned to each one according to the to

Texas at Austin, University of

123

Paducah Gaseous Diffusion Plant, Production Workers Screening Projects |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Production Workers Screening Production Workers Screening Projects Paducah Gaseous Diffusion Plant, Production Workers Screening Projects Project Name: Worker Health Protection Program Covered DOE Site: Paducah Worker Population Served: Production Workers Principal Investigator: Jim Frederick Co-Principal Investigator: Steven Markowitz, MD Toll-free Telephone: (888) 241-1199 Local Outreach Office: James Harbison 2525 Cairo Road Paducah, KY 42001 Website: http://www.worker-health.org/ This project is conducted by the United Steelworkers in conjunction with Queens College of the City University of New York. The program is being offered as a service to both former and current workers. Free of charge, eligible workers can receive a medical exam, including chest X-ray and breathing test, and an educational workshop. This program also offers CT

124

Portsmouth Gaseous Diffusion Plant Former Workers, Construction Worker  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Plant Former Workers, Construction Plant Former Workers, Construction Worker Screening Projects Portsmouth Gaseous Diffusion Plant Former Workers, Construction Worker Screening Projects Project Name: Building Trades National Medical Screening Program Covered DOE Site: Portsmouth Worker Population Served: Construction Workers Principal Investigator: Knut Ringen, DrPh, MHA, MPH Toll-free Telephone: (888) 464-0009 Local Outreach Office: Ron Bush 1236 Gallia Street Portsmouth, OH 45662 Website: http://www.btmed.org This project is intended to provide free medical screening to former workers in the building trades (construction workers). The screening targets health problems resulting from exposures, including asbestos, beryllium, cadmium, chromium, lead, mercury, noise, radiation, silica and/or solvents. The project is being carried out by a large group led by

125

Portsmouth Gaseous Diffusion Plant annual site environmental report for 1993  

Science Conference Proceedings (OSTI)

This calendar year (CY) 1993 annual report on environmental monitoring of the US Department of Energy`s (DOE`s) Portsmouth Gaseous Diffusion Plant (Portsmouth) and its environs consists of three separate documents: a summary pamphlet for the general public; a more detail discussion and of compliance status, data, and environmental impacts (this document); and a volume of detailed data that is available on request. The objectives of this report are to report compliance status during 1993; provide information about the plant site and plant operations; report 1993 monitoring data for the installation and its environs that may have been affected by operations on the plant site; document information on input and assumptions used in calculations; provide trend analyses (where appropriate) to indicate increases and decreases in environmental impact, and provide general information on quality assurance for the environmental monitoring program.

Horak, C.M. [ed.

1994-11-01T23:59:59.000Z

126

Gaseous diffusion plant transition from DOE to external regulation  

SciTech Connect

After many years of operation as government-owned/contractor-operated facilities, large portions of the gaseous diffusion plants (GDPs) at Portsmouth, Ohio, and Paducah, Kentucky, were leased to the United States Enrichment Corporation (USEC). These facilities are now certified by the U.S. Nuclear Regulatory Commission (NRC) and subject to oversight by the Occupational Safety and Health Administration (OSHA). The transition from DOE to NRC regulation was more difficult than expected. The original commitment was to achieve NRC certification in October 1995; however, considerably more time was required and transition-related costs escalated. The Oak Ridge Operations Office originally estimated the cost of transition at $60 million; $240 million has been spent to date. The DOE`s experience in transitioning the GDPs to USEC operation with NRC oversight provides valuable lessons (both positive and negative) that could be applied to future transitions.

Dann, R.K.; Crites, T.R.; Rahm-Crites, L.K. [Lawrence Livermore National Lab., CA (United States)

1997-12-01T23:59:59.000Z

127

Gaseous Arginine Conformers and Their Unique Intramolecular Interactions  

DOE Green Energy (OSTI)

Extensive ab initio calculations were employed to characterize stable conformers of gaseous arginine, both canonical and zwitterionic tautomers. Step-by-step geometry optimizations of possible single-bond rotamers at the B3LYP/6-31G(d), B3LYP/6-31++G(d,p) and MP2/6-31++G(d,p) levels yield numerous structures that are more stable than any known ones. The final electronic energies of the conformers were determined at the CCSD/6-31++G(d,p) level. The lowest energies of the canonical and zwitterionic structures are lower than the existing ones by 2.0 and 2.3 kcal/mol, respectively. The relative energies, rotational constants, dipole moments and harmonic frequencies of the stable conformers were given for future experimental verifications. The conformational distributions at various temperatures, estimated based upon the thermodynamic principles, consist almost exclusively of the newly found structures. One striking feature is the occurrence of the blue-shifting hydrogen bonds in all the six most stable conformers. A unique feature of important conformations is the coexistence of dihydrogen, blue- and red-shifting hydrogen bonds. In addition to the hydrogen bonds, the stereoelectronic effects were also found to be important stabilization factors. The calculated and measured proton affinities agree within the theoretical and experimental uncertainties, affirming high quality of our conformational search. The theoretical gas phase basicity of 245.9 kcal/mol is also in good agreement with the experimental value of 240.6 kcal/mol. The extensive searches establish firmly that gaseous arginine exists primarily in the canonical and not the zwitterionic form. Computing resources were available through a Computational Grand Challenge Application grant from the Molecular Sciences Computing Facility in the Environmental Molecular Sciences Laboratory. PNNL is operated by Battelle for the U.S. DOE under Contract DE-AC06-76RLO 1830.

Ling, Sanliang; Yu, Wenbo; Huang, Zhijian; Lin, Zijing; Haranczyk, Maciej; Gutowski, Maciej S.

2006-11-09T23:59:59.000Z

128

Gaseous Arginine Conformers and Their Unique Intramolecular Interactions.  

DOE Green Energy (OSTI)

Extensive ab initio calculations were employed to characterize stable conformers of gaseous arginine, both the canonical and zwitterionic tautomers. Step-by-step geometry optimizations of possible single-bond rotamers at the B3LYP/6-31G(d), B3LYP/6-31++G(d,p), and MP2/6-31++G(d,p) levels yield numerous structures that are more stable than any known ones. The final electronic energies of the conformers were determined at the CCSD/6-31++G(d,p) level. The lowest energies of the canonical and zwitterionic structures are lower than the existing values by 2.0 and 2.3 kcal/mol, respectively. The relative energies, rotational constants, dipole moments, and harmonic frequencies of the stable conformers remain for future experimental verification. The conformational distributions at various temperatures, estimated according to thermodynamic principles, consist almost exclusively of the newly found structures. One striking feature is the occurrence of blueshifting hydrogen bonds in all six of the most stable conformers. A unique feature of important conformations is the coexistence of dihydrogen and blue- and red-shifting hydrogen bonds. In addition to the hydrogen bonds, the stereoelectronic effects were also found to be important stabilization factors. The calculated and measured proton affinities agree within the theoretical and experimental uncertainties, affirming the high quality of our conformational search. The theoretical gas-phase basicity of 245.9 kcal/mol is also in good agreement with the experimental value of 240.6 kcal/mol. The extensive searches establish firmly that gaseous arginine exists primarily in the canonical and not the zwitterionic form.

Ling, Sanliang; Yu, Wenbo; Huang, Zhijian; Lin, Zijing; Haranczyk, Maciej; Gutowski, Maciej S.

2006-11-09T23:59:59.000Z

129

,"Louisiana Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Louisiana Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sla_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sla_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

130

,"Nebraska Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Nebraska Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sne_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sne_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

131

,"Pennsylvania Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Pennsylvania Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_spa_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_spa_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

132

,"South Dakota Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Plant Liquids Production, Gaseous Equivalent (MMcf)" Plant Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","South Dakota Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_ssd_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_ssd_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

133

,"Wyoming Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Wyoming Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_swy_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_swy_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

134

,"Montana Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Montana Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_smt_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_smt_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

135

,"Kansas Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Kansas Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sks_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sks_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

136

,"Alabama Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Alabama Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sal_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sal_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

137

,"California Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sca_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sca_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

138

,"Oklahoma Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Oklahoma Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sok_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sok_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

139

,"Ohio Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Ohio Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_soh_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_soh_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

140

,"Utah Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Utah Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sut_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sut_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

,"Alaska Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Alaska Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sak_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sak_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

142

,"Indiana Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Plant Liquids Production, Gaseous Equivalent (MMcf)" Plant Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Indiana Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sin_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sin_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

143

Application of Gaseous Sphere Injection Method for Modeling Under-expanded H2 Injection  

DOE Green Energy (OSTI)

A methodology for modeling gaseous injection has been refined and applied to recent experimental data from the literature. This approach uses a discrete phase analogy to handle gaseous injection, allowing for addition of gaseous injection to a CFD grid without needing to resolve the injector nozzle. This paper focuses on model testing to provide the basis for simulation of hydrogen direct injected internal combustion engines. The model has been updated to be more applicable to full engine simulations, and shows good agreement with experiments for jet penetration and time-dependent axial mass fraction, while available radial mass fraction data is less well predicted.

Whitesides, R; Hessel, R P; Flowers, D L; Aceves, S M

2010-12-03T23:59:59.000Z

144

,"Michigan Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Michigan Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_smi_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_smi_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

145

,"Florida Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Florida Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sfl_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sfl_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

146

,"Mississippi Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Mississippi Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sms_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sms_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

147

,"Texas Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Texas Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_stx_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_stx_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

148

Dispersing the Gaseous Protoplanetary Disc and Halting Type II Migration  

E-Print Network (OSTI)

More than 30 extra-solar Jupiter-like planets have shorter periods than the planet Mercury. It is generally accepted that they formed further out, past the snow line (?1 AU), and migrated inwards. In order to be driven by tidal torques from the gaseous disc, the disc exterior to the planet had to contain about a planetary mass. The fact that the planets stopped migrating means that their outer disc was removed. We suggest, following the simulation by Bate et al. (2003), that the outer disc was accreted by the planet. This not only halts migration but removes the outer disc for planets interior to about 2 AU. The disc further out could have been removed by photoevaporation (Matsuyama et al. 2003). Furthermore, as also shown by Bate et al. (op cit) this process also provides an upper limit to planetary masses in agreement with the analysis of observed planetary masses by Zucker & Mazeh (2002). In this scenario, the endgame is a race. The central star is accreting the inner disc and the planet, while the planet is accreting the outer disc. The planet survives if it accretes its outer disc before being accreted by the star. The winner is determined solely by the ratio of the mass of the outer disc to the local surface density of the disc. Some planets are certainly eaten by the central star. Subject headings: extrasolar planets, Jupiter 1.

M. Lecar; D. D. Sasselov

2003-01-01T23:59:59.000Z

149

Gaseous fueled vehicles: A role for natural gas and hydrogen  

SciTech Connect

The commercialization of gaseous hydrogen fueled vehicles requires both the development of hydrogen fueled vehicles and the establishment of a hydrogen fueling infrastructure. These requirements create a classic chicken and egg scenario in that manufacturers will not build and consumers will not buy vehicles without an adequate refueling infrastructure and potential refueling station operators will not invest the needed capital without an adequate market to serve. One solution to this dilemma is to create a bridging strategy whereby hydrogen is introduced gradually via another carrier. The only contending alternative fuel that can act as a bridge to hydrogen fueled vehicles is natural gas. To explore this possibility, IGT is conducting emission tests on its dedicated natural gas vehicle (NGV) test platform to determine what, if any, effects small quantities of hydrogen have on emissions and performance. Furthermore, IGT is actively developing an adsorbent based low-pressure natural gas storage system for NGV applications. This system has also shown promise as a storage media for hydrogen. A discussion of our research results in this area will be presented. Finally, a review of IGT's testing facility will be presented to indicate our capabilities in conducted natural gas/hydrogen vehicle (NGHV) research. 3 refs., 10 figs.

Blazek, C.F.; Jasionowski, W.J.

1991-01-01T23:59:59.000Z

150

GASEOUS CO ABUNDANCE-AN EVOLUTIONARY TRACER FOR MOLECULAR CLOUDS  

SciTech Connect

Planck cold clumps are among the most promising objects to investigate the initial conditions of the evolution of molecular clouds. In this work, by combing the dust emission data from the survey of the Planck satellite with the molecular data of {sup 12}CO/{sup 13}CO/C{sup 18}O (1-0) lines from observations with the Purple Mountain Observatory 13.7 m telescope, we investigate the CO abundance, CO depletion, and CO-to-H{sub 2} conversion factor of 674 clumps in the early cold cores sample. The median and mean values of the CO abundance are 0.89 Multiplication-Sign 10{sup -4} and 1.28 Multiplication-Sign 10{sup -4}, respectively. The mean and median of CO depletion factor are 1.7 and 0.9, respectively. The median value of X{sub CO-to-H{sub 2}} for the whole sample is 2.8 Multiplication-Sign 10{sup 20} cm{sup -2} K{sup -1} km{sup -1} s. The CO abundance, CO depletion factor, and CO-to-H{sub 2} conversion factor are strongly (anti-)correlated to other physical parameters (e.g., dust temperature, dust emissivity spectral index, column density, volume density, and luminosity-to-mass ratio). To conclude, the gaseous CO abundance can be used as an evolutionary tracer for molecular clouds.

Liu Tie; Wu Yuefang; Zhang Huawei, E-mail: liutiepku@gmail.com, E-mail: ywu@pku.edu.cn [Department of Astronomy, Peking University, Beijing 100871 (China)

2013-09-20T23:59:59.000Z

151

Portsmouth Gaseous Diffusion Plant environmental report for 1989  

Science Conference Proceedings (OSTI)

This calendar year 1989 annual report on environmental surveillance of the US Department of Energy's (DOE) Portsmouth Gaseous Diffusion Plant (PORTS) and its environs consists of two parts: the Summary, Discussion, and Conclusions (Part 1) and the Data Presentation (Part 2). The objectives of this report are the following: report 1989 monitoring data for the installation and its environs that may have been affected by operations on the plant site, provide reasonably detailed information about the plant site and plant operations, provide detailed information on input and assumptions used in all calculations, provide trend analyses (where appropriate) to indicate increases and decreases in environmental impact, and provide general information on plant quality assurance. Routine monitoring and sampling for radiation, radioactive materials, and chemical substances on and off the DOE site are used to document compliance with appropriate standards, to identify trends, to provide information for the public, and to contribute to general environmental knowledge. The surveillance program assists in fulfilling the DOE policy of protecting the public, employees, and environment from harm that could be caused by its activities and reducing negative environmental impacts to the greatest degree practicable. Environmental-monitoring information complements data on specific releases, trends, and summaries. 26 refs.

Turner, J.W. (ed.) (Martin Marietta Energy Systems, Inc., Oak Ridge, TN (USA))

1990-10-01T23:59:59.000Z

152

Gaseous fueled vehicles: A role for natural gas and hydrogen  

DOE Green Energy (OSTI)

The commercialization of gaseous hydrogen fueled vehicles requires both the development of hydrogen fueled vehicles and the establishment of a hydrogen fueling infrastructure. These requirements create a classic chicken and egg scenario in that manufacturers will not build and consumers will not buy vehicles without an adequate refueling infrastructure and potential refueling station operators will not invest the needed capital without an adequate market to serve. One solution to this dilemma is to create a bridging strategy whereby hydrogen is introduced gradually via another carrier. The only contending alternative fuel that can act as a bridge to hydrogen fueled vehicles is natural gas. To explore this possibility, IGT is conducting emission tests on its dedicated natural gas vehicle (NGV) test platform to determine what, if any, effects small quantities of hydrogen have on emissions and performance. Furthermore, IGT is actively developing an adsorbent based low-pressure natural gas storage system for NGV applications. This system has also shown promise as a storage media for hydrogen. A discussion of our research results in this area will be presented. Finally, a review of IGT's testing facility will be presented to indicate our capabilities in conducted natural gas/hydrogen vehicle (NGHV) research. 3 refs., 10 figs.

Blazek, C.F.; Jasionowski, W.J.

1991-01-01T23:59:59.000Z

153

DOE Seeks Quotes for Paducah Gaseous Diffusion Plant Environmental Technical Services  

Energy.gov (U.S. Department of Energy (DOE))

Cincinnati The Department of Energy (DOE) today issued a Request for Quotation (RFQ) for an Environmental Technical Services acquisition at the Paducah Gaseous Diffusion Plant (GDP) for the Portsmouth Paducah Project Office (PPPO).

154

Early Morning Ventilation of a Gaseous Tracer from a Mountain Valley  

Science Conference Proceedings (OSTI)

An important component of a joint Environmental Protection AgencyDepartment of Energy field experiment in Brush Creek Valley, Colorado in JulyAugust 1982, was an aircraft sampling task to help verify the early morning ventilation of a gaseous ...

Montie M. Orgill

1989-07-01T23:59:59.000Z

155

Interpolation and Profile Correction (IPC) Method for Shortwave Radiative Transfer in Spectral Intervals of Gaseous Absorption  

Science Conference Proceedings (OSTI)

The new interpolation and profile correction (IPC) method for radiance/flux calculations in gaseous absorption bands is presented. The IPC method is designed to allow an arbitrary spectral resolution including monochromatic mode. It features a ...

Alexei I. Lyapustin

2003-03-01T23:59:59.000Z

156

A Relaxed Eddy Accumulation System for Measuring Surface Fluxes of Total Gaseous Mercury  

Science Conference Proceedings (OSTI)

A relaxed eddy accumulation (REA) system was designed to continuously measure total gaseous mercury (TGM) fluxes over a forest canopy. TGM concentration measurements were measured at 5-min intervals with a Tekran model 2537A mercury analyzer ...

Jesse O. Bash; David R. Miller

2008-02-01T23:59:59.000Z

157

INSENSITIVE HIGH-NITROGEN COMPOUNDS  

DOE Green Energy (OSTI)

The conventional approach to developing energetic molecules is to chemically place one or more nitro groups onto a carbon skeleton, which is why the term ''nitration'' is synonymous to explosives preparation. The nitro group carries the oxygen that reacts with the skeletal carbon and hydrogen fuels, which in turn produces the heat and gaseous reaction products necessary for driving an explosive shock. These nitro-containing energetic molecules typically have heats of formation near zero and therefore most of the released energy is derived from the combustion process. Our investigation of the tetrazine, furazan and tetrazole ring systems has offered a different approach to explosives development, where a significant amount of the chemical potential energy is derived from their large positive heats of formation. Because these compounds often contain a large percentage of nitrogen atoms, they are usually regarded as high-nitrogen fuels or explosives. A general artifact of these high-nitrogen compounds is that they are less sensitive to initiation (e.g. by impact) when compared to traditional nitro-containing explosives of similar performances. Using the precursor, 3,6-bis-(3,5-dimethylpyrazol-1-yl)-s-tetrazine, several useful energetic compounds based on the s-tetrazine system have been synthesized and studied. Some of the first compounds are 3,6-diamino-s-tetrazine-1,4-dioxide (LAX-112) and 3,6-dihydrazino-s-tetrazine (DHT). LAX-112 was once extensively studied as an insensitive explosive by Los Alamos; DHT is an example of a high-nitrogen explosive that relies entirely on its heat of formation for sustaining a detonation. Recent synthesis efforts have yielded an azo-s-tetrazine, 3,3'-azobis(6-amino-s-tetrazine) or DAAT, which has a very high positive heat of formation. The compounds, 4,4'-diamino-3,3'-azoxyfurazan (DAAF) and 4,4'-diamino-3,3'-azofurazan (DAAzF), may have important future roles in insensitive explosive applications. Neither DAAF nor DAAzF can be initiated by laboratory impact drop tests, yet both have in some aspects better explosive performances than 1,3,5-triamino-2,4,6-trinitrobenzene TATB--the standard of insensitive high explosives. The thermal stability of DAAzF is equal to that of hexanitrostilbene (HNS), yet it too is a better explosive performer. The recently discovered tetrazol derivative, 3,6-bis-(1H-1,2,3,4-tetrazol-5-ylamino)-s-tetrazine (BTATz) was measured to have exceptional positive heats of formation and to be insensitive to explosive initiation. Because of its high burn rate with low sensitivity to pressure, this material is of great interest to the propellant community.

D. CHAVEZ; ET AL

2001-03-01T23:59:59.000Z

158

Liquid and Gaseous Waste Operations Department Annual Operating Report, CY 1993  

SciTech Connect

This report summarizes the activities of the waste management operations section of the liquid and gaseous waste operations department at ORNL for 1993. The process waste, liquid low-level waste, gaseous waste systems activities are reported, as well as the low-level waste solidification project. Upgrade activities is the various waste processing and treatment systems are summarized. A maintenance activity overview is provided, and program management, training, and other miscellaneous activities are covered.

Maddox, J.J.; Scott, C.B.

1994-02-01T23:59:59.000Z

159

Electron attachment fo halocarbons of interest in gaseous dielectrics  

Science Conference Proceedings (OSTI)

Total electron attachment rate constants and cross sections for halomethane and haloethane (freon) compounds are summarized and new results are reported for haloethylenes. The relationship between the electron attachment cross section and the breakdown strength of dielectric gases reported earlier is further discussed.

McCorkle, D.L.; Christodoulides, A.A.; Christophorou, L.G.

1984-01-01T23:59:59.000Z

160

Infrared Spectroscopy of Atomic Lines in Gaseous Nebulae  

E-Print Network (OSTI)

Spectroscopy in the infrared provides a means to assess important properties of the plasma in gaseous nebulae. We present some of our own work that illustrates the need for interactions between the themes of this conference - astronomical data, atomic data, and plasma simulations. We undertook Infrared Space Observatory (ISO) observations with the intent of better understanding the effects of density variations in nebulae, particularly planetary nebulae (PNs), by determining average electron densities from the flux ratios of several fine-structure, IR emission lines. Instead, we are able to ascertain only minor density information because of several instances of the observed line flux ratios being out of range of the theoretical predictions using current atomic data. In these cases, the ISO data cannot presently be used to derive electron density, but rather provide direction for needed improvements in the atomic collision strengths. We have detected an unidentified (uid) strong emission line in an ISO/SWS spectrum of the Orion Nebula. The line has a rest wavelength 2.89350$\\pm$0.00003 $\\mu$m. A long-slit UKIRT observation confirms the presence of this line and shows that the emission is spatially extended and appears to be coincident with the brightest part of the ionized region. We do not detect the uid line in our SWS02 spectra of any of the several bright PNs which we observed for a comparable time. The need for basic atomic data, in this case wavelengths to aid species identification, is paramount for future progress. We look toward the future with a brief synopsis of upcoming or planned IR missions.

R. H. Rubin; R. J. Dufour; T. R. Geballe; S. W. J. Colgan; J. P. Harrington; S. D. Lord; A. L. Liao; D. A. Levine

2001-09-23T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Dissolved gaseous mercury behavior in shallow water estuaries  

E-Print Network (OSTI)

The formation of dissolved gaseous mercury (DGM) can be an important pathway for mercury removal from an aquatic environment. DGM evasional fluxes from an aquatic system can account for up to 95% of atmospheric Hg and its deposition pathways. While this makes DGM an important species of mercury to investigate, the difficulty of accurately analyzing DGM has prevented many from studying it. In this study, DGM was measured in two different types of estuarine environments and with two different methods, discrete and continuous analysis. The discrete technique works reasonably well and is reproducible, but it does not allow one to observe rapid changes in DGM concentration due to long analysis times (~2 hr per sample). When used in this study, the discrete sampling technique agreed well with the continuous technique for Offatts Bayou, Galveston, Texas, and Georgiana Slough in the California Bay-Delta region. The average DGM concentration during the March continuous study at Offatts Bayou was 25.3 8.8 pg L-1. This is significantly higher than the average DGM concentration from Georgiana Slough during late March 2006 (9.6 6.6 pg L-1). DGM seemed to correlate best with photosynthetically active radiation (PAR) data in every study, suggesting that the primary control of its formation is solar irradiation. Stronger positive correlations with PAR were seen when DGM data was shifted back one hour, indicating that mercury photoreactions take time to complete. DGM also correlated positively with wind speed in most instances. However, increased wind speed should enhance air to water transfer of elemental mercury, thus one would expect a negative correlation. DGM co-varied negatively with salinity during the continuous studies, suggesting that the DGM pool is reduced in surface waters by chloride mediated oxidation. Three predictive flux models were used in the study to assess the potential for DGM water to air transfer. For both the Georgiana Slough and Offatts Bayou studies, the predicted flux dropped to or below zero after sunset. This study does contribute to the understanding of DGM cycling in aquatic environments as there are few studies that have made continuous DGM measurements in estuarine environments.

Landin, Charles Melchor

2007-12-01T23:59:59.000Z

162

Dissolved gaseous mercury behavior in shallow water estuaries  

E-Print Network (OSTI)

The formation of dissolved gaseous mercury (DGM) can be an important pathway for mercury removal from an aquatic environment. DGM evasional fluxes from an aquatic system can account for up to 95% of atmospheric Hg and its deposition pathways. While this makes DGM an important species of mercury to investigate, the difficulty of accurately analyzing DGM has prevented many from studying it. In this study, DGM was measured in two different types of estuarine environments and with two different methods, discrete and continuous analysis. The discrete technique works reasonably well and is reproducible, but it does not allow one to observe rapid changes in DGM concentration due to long analysis times (~2 hr per sample). When used in this study, the discrete sampling technique agreed well with the continuous technique for Offatts Bayou, Galveston, Texas, and Georgiana Slough in the California Bay-Delta region. The average DGM concentration during the March continuous study at Offatts Bayou was 25.3 + 8.8 pg L-1. This is significantly higher than the average DGM concentration from Georgiana Slough during late March 2006 (9.6 + 6.6 pg L-1). DGM seemed to correlate best with photosynthetically active radiation (PAR) data in every study, suggesting that the primary control of its formation is solar irradiation. Stronger positive correlations with PAR were seen when DGM data was shifted back one hour, indicating that mercury photoreactions take time to complete. DGM also correlated positively with wind speed in most instances. However, increased wind speed should enhance air to water transfer of elemental mercury, thus one would expect a negative correlation. DGM co-varied negatively with salinity during the continuous studies, suggesting that the DGM pool is reduced in surface waters by chloride mediated oxidation. Three predictive flux models were used in the study to assess the potential for DGM water to air transfer. For both the Georgiana Slough and Offatts Bayou studies, the predicted flux dropped to or below zero after sunset. This study does contribute to the understanding of DGM cycling in aquatic environments as there are few studies that have made continuous DGM measurements in estuarine environments.

Landin, Charles Melchor

2007-12-01T23:59:59.000Z

163

Carburization of austenitic alloys by gaseous impurities in helium  

SciTech Connect

The carburization behavior of Alloy 800H, Inconel Alloy 617 and Hastelloy Alloy X in helium containing various amounts of H/sub 2/, CO, CH/sub 4/, H/sub 2/O and CO/sub 2/ was studied. Corrosion tests were conducted in a temperature range from 649 to 1000/sup 0/C (1200 to 1832/sup 0/F) for exposure time up to 10,000 h. Four different helium environments, identified as A, B, C, and D, were investigated. Concentrations of gaseous impurities were 1500 ..mu..atm H/sub 2/, 450 ..mu..atm CO, 50 ..mu..atm CH/sub 4/ and 50 ..mu..atm H/sub 2/O for Environment A; 200 ..mu..atm H/sub 2/, 100 ..mu..atm CO, 20 ..mu..atm CH/sub 4/, 50 ..mu..atm H/sub 2/O and 5 ..mu..atm CO/sub 2/ for Environment B; 500 ..mu..atm H/sub 2/, 50 ..mu..atm CO, 50 ..mu..atm CH/sub 4/ and < 0.5 ..mu..atm H/sub 2/O for Environment C; and 500 ..mu..atm H/sub 2/, 50 ..mu..atm CO, 50 ..mu..atm CH/sub 4/ and 1.5 ..mu..atm H/sub 2/O for Environment D. Environments A and B were characteristic of high-oxygen potential, while C and D were characteristic of low-oxygen potential. The results showed that the carburization kinetics in low-oxygen potential environments (C and D) were significantly higher, approximately an order of magnitude higher at high temperatures, than those in high-oxygen potential environments (A and B) for all three alloys. Thermodynamic analyses indicated no significant differences in the thermodynamic carburization potential between low- and high-oxygen potential environments. It is thus believed that the enhanced carburization kinetics observed in the low-oxygen potential environments were related to kinetic effects. A qualitatively mechanistic model was proposed to explain the enhanced kinetics. The present results further suggest that controlling the oxygen potential of the service environment can be an effective means of reducing carburization of alloys.

Lai, G.Y.; Johnson, W.R.

1980-03-01T23:59:59.000Z

164

Method for production of an isotopically enriched compound  

Science Conference Proceedings (OSTI)

A method is presented for producing and isolating an isotopically enriched compound of a desired isotope from a parent radionuclide. The method includes forming, or placing, a precipitate containing a parent radionuclide of the desired daughter isotope in a first reaction zone and allowing sufficient time for the parent to decay into the desired gaseous daughter radioisotope. The method further contemplates collecting the desired daughter isotope as a solid in a second reaction zone through the application of temperatures below the freezing point of the desired isotope to a second reaction zone that is connected to the first reaction zone. Specifically, a method is presented for producing isotopically enriched compounds of xenon, including the radioactive isotope Xe-131m and the stable isotope Xe-131.

Watrous, Matthew G.

2012-12-11T23:59:59.000Z

165

XAFS Model Compound Library  

DOE Data Explorer (OSTI)

The XAFS Model Compound Library contains XAFS data on model compounds. The term "model" compounds refers to compounds of homogeneous and well-known crystallographic or molecular structure. Each data file in this library has an associated atoms.inp file that can be converted to a feff.inp file using the program ATOMS. (See the related Searchable Atoms.inp Archive at http://cars9.uchicago.edu/~newville/adb/) This Library exists because XAFS data on model compounds is useful for several reasons, including comparing to unknown data for "fingerprinting" and testing calculations and analysis methods. The collection here is currently limited, but is growing. The focus to date has been on inorganic compounds and minerals of interest to the geochemical community. [Copied, with editing, from http://cars9.uchicago.edu/~newville/ModelLib/

Newville, Matthew

166

Preparation of uranium compounds  

SciTech Connect

UI.sub.3(1,4-dioxane).sub.1.5 and UI.sub.4(1,4-dioxane).sub.2, were synthesized in high yield by reacting turnings of elemental uranium with iodine dissolved in 1,4-dioxane under mild conditions. These molecular compounds of uranium are thermally stable and excellent precursor materials for synthesizing other molecular compounds of uranium including alkoxide, amide, organometallic, and halide compounds.

Kiplinger, Jaqueline L; Montreal, Marisa J; Thomson, Robert K; Cantat, Thibault; Travia, Nicholas E

2013-02-19T23:59:59.000Z

167

Partially fluorinated ionic compounds  

DOE Patents (OSTI)

Partially fluorinated ionic compounds are prepared. They are useful in the preparation of partially fluorinated dienes, in which the repeat units are cycloaliphatic.

Han, legal representative, Amy Qi (Hockessin, DE); Yang, Zhen-Yu (Hockessin, DE)

2008-11-25T23:59:59.000Z

168

Portsmouth Gaseous Diffusion Plant Director's Final Findings and Orders, October 4, 1995  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth Gaseous Diffusion Plant Director's Final Portsmouth Gaseous Diffusion Plant Director's Final Findings and Orders, October 4, 1995 BEFORE THE OHIO ENVIRONMENTAL PROTECTION AGENCY In the Matter Of: United States Department of Energy : Director's Final Portsmouth Gaseous Diffusion Plant : Findings and Orders P.O. Box 700 : Piketon, Ohio 45661-0700 : Respondent It is hereby agreed by and among the parties hereto as follows: Table of Contents I. Jurisdiction II. Parties Bound III. Definitions IV. Findings of Fact V. Orders VI. Limitations of Director's Approval VII. Notice VIII. Project Managers IX. Dispute Resolution X. Funding XI. Other Applicable Laws XII. Reservation of Rights XIII. Modification XIV. Termination XV. Other Claims XVI. Signatories XVII. Waiver I. Jurisdiction These Director's Final Findings and Orders ("Orders") are issued to the United States

169

Oak Ridge K-25 Gaseous Diffusion Plant, Former Production Workers Screening  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

K-25 Gaseous Diffusion Plant, Former Production Workers K-25 Gaseous Diffusion Plant, Former Production Workers Screening Projects Oak Ridge K-25 Gaseous Diffusion Plant, Former Production Workers Screening Projects Project Name: Worker Health Protection Program Covered DOE Site: K-25 Worker Population Served: Production Workers Principal Investigator: Jim Frederick Co-Principal Investigator: Steven Markowitz, MD Toll-free Telephone: (888) 241-1199 Local Outreach Office: Bruce Lawson 133 Raleigh Road Oak Ridge, TN 37830 Local Medical Clinics: ParkMed 110 S. Illinois Avenue Oak Ridge, TN 37380 Website: http://www.worker-health.org/ This project is conducted by the United Steelworkers in conjunction with Queens College of the City University of New York. The program is being offered as a service to both former and current workers. Free of charge,

170

Simulation of VUV electroluminescence in micropattern gaseous detectors: the case of GEM and MHSP  

E-Print Network (OSTI)

Electroluminescence produced during avalanche development in gaseous avalanche detectors is an useful information for triggering, calorimetry and tracking in gaseous detectors. Noble gases present high electroluminescence yields, emitting mainly in the VUV region. The photons can provide signal readout if appropriate photosensors are used. Micropattern gaseous detectors are good candidates for signal amplification in high background and/or low rate experiments due to their high electroluminescence yields and radiopurity. In this work, the VUV light responses of the Gas Electron Multiplier and of the Micro-Hole Strip Plate, working with pure xenon, are simulated and studied in detail using a new and versatile C++ toolkit. It is shown that the solid angle subtended by a photosensor placed below the microstructures depends on the operating conditions. The obtained absolute EL yields, determined for different gas pressures and as functions of the applied voltage, are compared with those determined experimentally.

C. A. B. Oliveira; P. M. M. Correia; H. Schindler; A. L. Ferreira; C. M. B. Monteiro; J. M. F. dos Santos; S. Biagi; R. Veenhof; J. F. C. A. Veloso

2012-06-08T23:59:59.000Z

171

Quasi-monoenergetic protons accelerated by laser radiation pressure and shocks in thin gaseous targets  

Science Conference Proceedings (OSTI)

Recent experiments and simulations have demonstrated effective CO{sub 2} laser acceleration of quasi-monoenergetic protons from thick gaseous hydrogen target (of thickness tens of laser wavelengths) via hole boring and shock accelerations. We present here an alternative novel acceleration scheme by combining laser radiation pressure acceleration with shock acceleration of protons in a thin gaseous target of thickness several laser wavelengths. The laser pushes the thin gaseous plasma forward while compressing it with protons trapped in it. We demonstrated the combined acceleration with two-dimensional particle-in-cell simulation and obtained quasi-monoenergetic protons {approx}44 MeV in a gas target of thickness twice of the laser wavelength irradiated by circularly polarized CO{sub 2} laser with normalized laser amplitude a{sub 0}=10.

He Minqing; Shao Xi; Liu Chuansheng; Liu Tungchang; Su Jaojang; Dudnikova, Galina; Sagdeev, Roald Z. [East-West Space Science Center, University of Maryland, College Park, Maryland 20742 (United States); Sheng Zhengming [Department of Physics, Shanghai Jiao Tong University, Shanghai 200240 (China); Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, CAS, Beijing 100190 (China)

2012-07-15T23:59:59.000Z

172

Oak Ridge National Lebroatory Liquid&Gaseous Waste Treatment System Strategic Plan  

SciTech Connect

Excellence in Laboratory operations is one of the three key goals of the Oak Ridge National Laboratory (ORNL) Agenda. That goal will be met through comprehensive upgrades of facilities and operational approaches over the next few years. Many of ORNL's physical facilities, including the liquid and gaseous waste collection and treatment systems, are quite old, and are reaching the end of their safe operating life. The condition of research facilities and supporting infrastructure, including the waste handling facilities, is a key environmental, safety and health (ES&H) concern. The existing infrastructure will add considerably to the overhead costs of research due to increased maintenance and operating costs as these facilities continue to age. The Liquid Gaseous Waste Treatment System (LGWTS) Reengineering Project is a UT-Battelle, LLC (UT-B) Operations Improvement Program (OIP) project that was undertaken to develop a plan for upgrading the ORNL liquid and gaseous waste systems to support ORNL's research mission.

Van Hoesen, S.D.

2003-09-09T23:59:59.000Z

173

Safeguards Verification Measurements using Laser Ablation, Absorbance Ratio Spectrometry in Gaseous Centrifuge Enrichment Plants  

Science Conference Proceedings (OSTI)

Laser Ablation Absorbance Ratio Spectrometry (LAARS) is a new verification measurement technology under development at the US Department of Energys (DOE) Pacific Northwest National Laboratory (PNNL). LAARS uses three lasers to ablate and then measure the relative isotopic abundance of uranium compounds. An ablation laser is tightly focused on uranium-bearing solids producing a small plume containing uranium atoms. Two collinear wavelength-tuned spectrometry lasers transit through the plume and the absorbance of U-235 and U-238 isotopes are measured to determine U-235 enrichment. The measurement has high relative precision and detection limits approaching the femtogram range for uranium. It is independent of chemical form and degree of dilution with nuisance dust and other materials. High speed sample scanning and pinpoint characterization allow measurements on millions of particles/hour to detect and analyze the enrichment of trace uranium in samples. The spectrometer is assembled using commercially available components at comparatively low cost, and features a compact and low power design. Future designs can be engineered for reliable, autonomous deployment within an industrial plant environment. Two specific applications of the spectrometer are under development: 1) automated unattended aerosol sampling and analysis and 2) on-site small sample destructive assay measurement. The two applications propose game-changing technological advances in gaseous centrifuge enrichment plant (GCEP) safeguards verification. The aerosol measurement instrument, LAARS-environmental sampling (ES), collects aerosol particles from the plant environment in a purpose-built rotating drum impactor and then uses LAARS-ES to quickly scan the surface of the impactor to measure the enrichments of the captured particles. The current approach to plant misuse detection involves swipe sampling and offsite analysis. Though this approach is very robust it generally requires several months to obtain results from a given sample collection. The destructive assay instrument, LAARS-destructive assay (DA), uses a simple purpose-built fixture with a sampling planchet to collect adsorbed UF6 gas from a cylinder valve or from a process line tap or pigtail. A portable LAARS-DA instrument scans the microgram quantity of uranium collected on the planchet and the assay of the uranium is measured to ~0.15% relative precision. Currently, destructive assay samples for bias defect measurements are collected in small sample cylinders for offsite mass spectrometry measurement.

Anheier, Norman C.; Cannon, Bret D.; Qiao, Hong (Amy); Phillips, Jon R.

2012-07-01T23:59:59.000Z

174

Elucidating the solid, liquid and gaseous products from batch pyrolysis of cotton-gin trash.  

E-Print Network (OSTI)

Cotton-gin trash (CGT) was pyrolyzed at different temperatures and reaction times using an externally-heated batch reactor. The average yields of output products (solid/char, liquid/bio-oil, and gaseous) were determined. The heating value (HV) of CGT was measured to be around 15-16 MJ kg- 1 (6500-7000 Btu lb-1). In the first set of tests, CGT was pyrolyzed at 600, 700, and 800C and at 30, 45, and 60 min reaction period. The maximum char yield of 40% by weight (wt.%) was determined at 600C and 30 min settings, however, the HV of char was low and almost similar to the HV of CGT. A maximum gas yield of 40 wt.% was measured at 800C and 60 min and the highest liquid yield of 30 wt.% was determined at 800C and 30 min. In the modified pyrolysis test, the effects of temperature (500, 600, 700, and 800C) on the product yield and other properties were investigated. The experiment was performed using the same reactor purged with nitrogen at a rate of 1000 cm3 min-1. Gas yield increased as temperature was increased while the effect was opposite on char yield. The maximum char yield of 38 wt.% was determined at 500C and 30 min. The char had the largest fraction in the energy output (70-83%) followed by gas (10-20%) and bio-oil (7- 9%). Maximum gas yield of 35 wt.% was determined at 800C. The average yield of CO, H2 and total hydrocarbons (THC) generally increased with increased temperature but CO2 production decreased. Methane, ethane, and propane dominated the THC. The bio-oil yield at 600C was the highest at about 30 wt.% among the temperature settings. The HV of bio-oil was low (2-5 MJ kg-1) due to minimal non-HC compounds and high moisture content (MC). A simple energy balance of the process was performed. The process was considered energy intensive due to the high amount of energy input (6100 kJ) while generating a maximum energy output of only 10%. After disregarding the energy used for preparation and pyrolysis, the energy losses ranged from 30-46% while the energy of the output represent between 55-70% of the input energy from CGT.

Aquino, Froilan Ludana

2007-12-01T23:59:59.000Z

175

Liquid and Gaseous Waste Operations Department annual operating report CY 1996  

SciTech Connect

This annual report summarizes operating activities dealing with the process waste system, the liquid low-level waste system, and the gaseous waste system. It also describes upgrade activities dealing with the process and liquid low-level waste systems, the cathodic protection system, a stack ventilation system, and configuration control. Maintenance activities are described dealing with nonradiological wastewater treatment plant, process waste treatment plant and collection system, liquid low-level waste system, and gaseous waste system. Miscellaneous activities include training, audits/reviews/tours, and environmental restoration support.

Maddox, J.J.; Scott, C.B.

1997-03-01T23:59:59.000Z

176

A Possible Anisotropy in Blackbody Radiation Viewed through Non-uniform Gaseous Matter  

E-Print Network (OSTI)

A non-local gauge symmetry of a complex scalar field, which can be trivially extended to spinor fields, was demonstrated in a recent paper (Mod.Phys.Lett. A13, 1265 (1998) ; hep-th/9902020). The corresponding covariant Lagrangian density yielded a new, non-local Quantum Electrodynamics. In this letter we show that as a consequence of this new QED, a blackbody radiation viewed through gaseous matter appears to show a slight deviation from the Planck formula, and propose an experimental test to check this effect. We also show that a non-uniformity in this gaseous matter distribution leads to an (apparent) spatial anisotropy in the blackbody radiation.

T K Rai Dastidar

1999-03-12T23:59:59.000Z

177

Investigation of Auxiliary Power Substation 95A4 fault and fire, Portsmouth Gaseous Diffusion Plant, March 24, 1982  

SciTech Connect

On March 24, 1982, an electrical fault and resultant fire in the 480 volt Auxiliary Power Substation 95A4 at the Portsmouth Gaseous Diffusion Plant destroyed that substation. There were no personal injuries, the overall loss was limited to the Substation, and the cost of replacing the Substation with repaired and new components has been estimated at $184,000. At the time of the incident, Goodyear was involved in a project to replace the obsolete 480 volt circuit breaker of the Auxiliary Power System. This project involved the disassembly, refurishing, and reassembly of 480 volt circuit breaker carriages by Goodyear personnel. The fault occurred in a circuit breaker upgraded under this project. The investigation of this accident is reported. The evidence suggests the fault resulted from the improper assembly of an upgraded 480 volt circuit breaker. Compounding the problem and leading to the extensive damage was the failure of the transformer secondary breaker to trip open as designed and interrupt the flow of power to the substation. It is surmised that inadequate testing during preventive maintenance contributed to this condition. Additional factors which may have contributed to the accident included: no requirements for assuring the competence of the electricians who installed the circuit breakers, no specific assembly instructions to the electricians, inadequate procedure instructions, and an inadequate procedure governing operational or load testing of the breaker. (LCL)

1982-06-01T23:59:59.000Z

178

On-Line Measurement of Heat of Combustion of Gaseous Hydrocarbon Fuel Mixtures  

Science Conference Proceedings (OSTI)

A method for the on-line measurement of the heat of combustion of gaseous hydrocarbon fuel mixtures has been developed and tested. The method involves combustion of a test gas with a measured quantity of air to achieve a preset concentration of oxygen ...

Sprinkle Danny R.; Chaturvedi Sushil K.; Kheireddine Ali

1996-03-01T23:59:59.000Z

179

Environmental Restoration Site-Specific Plan for the Portsmouth Gaseous Diffusion Plant, FY 93  

Science Conference Proceedings (OSTI)

The purpose of this Site-Specific Plan (SSP) is to describe past, present, and future activities undertaken to implement Environmental Restoration and Waste Management goals at the Portsmouth Gaseous Diffusion Plant (PORTS). The SSP is presented in sections emphasizing Environmental Restoration description of activities, resources, and milestones.

Not Available

1993-01-15T23:59:59.000Z

180

Recovery of normally gaseous hydrocarbons from net excess hydrogen in a catalytic reforming process  

Science Conference Proceedings (OSTI)

A process is disclosed for the catalytic reforming of hydrocarbons in the presence of hydrogen, preferably to produce high quality gasoline boiling range products. An improved recovery of normally gaseous hydrocarbons from the net excess hydrogen is realized by chilling and contacting said hydrogen with a normally liquid hydrocarbon stream in a plural stage absorption zone at an elevated pressure.

Scheifele, C.A.

1982-06-08T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Method of absorbing UF.sub.6 from gaseous mixtures in alkamine absorbents  

DOE Patents (OSTI)

A method of recovering uranium hexafluoride from gaseous mixtures employing as an absorbent a liquid composition at least one of the components of which is chosen from the group consisting of ethanolamine, diethanolamine, and 3-methyl-3-amino-propane-diol-1,2.

Lafferty, Robert H. (Oak Ridge, TN); Smiley, Seymour H. (Oak Ridge, TN); Radimer, Kenneth J. (Little Falls, NJ)

1976-04-06T23:59:59.000Z

182

Heart testing compound  

DOE Patents (OSTI)

The compound 15-(p-(/sup 125/I)-iodophenyl)-6-tellurapentadecanoic acid is disclosed as a myocardial imaging agent having rapid and pronounced uptake, prolonged myocardial retention, and low in vivo deiodination.

Knapp, F.F. Jr.; Goodman, M.M.

1983-06-29T23:59:59.000Z

183

Heart testing compound  

DOE Patents (OSTI)

The compound 15-(p-[.sup.125 I]-iodophenyl)-6-tellurapentadecanoic acid is disclosed as a myocardial imaging agent having rapid and pronounced uptake, prolonged myocardial retention, and low in vivo deiodination.

Knapp, Jr., Furn F. (Oak Ridge, TN); Goodman, Mark M. (Knoxville, TN)

1985-01-01T23:59:59.000Z

184

Charge Density Wave Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Fisher Research Group Fisher Research Group Layered Chalcogenides 29 February 2008 Controlling the Wave by Brad Plummer, SLAC Communications Stanford University researchers working in part at SSRL have discovered a novel set of properties pertaining to a compound of materials called tritellurides. These compounds, composed of three atoms of tellurium and a single atom of one of the rare earth elements, demonstrate unique electronic properties that can be controlled by altering the temperature of the material. The tritellurides display phenomena known as charge density waves (CDW). In a normal conductive metal, electrons persist in a "sea" wherein they are evenly distributed and equally available, or conductive. A CDW occurs under certain circumstances and causes the electrons to clump together, lowering their availability, and thereby lowering the compound's conductivity. Tellurium, when crystallized into quasi-two-dimensional planes and combined with rare earth elements, produces a material with CDWs that can be manipulated and controlled.

185

8-fluoropurine compounds  

DOE Patents (OSTI)

An efficient, regiocontrolled approach to the synthesis of 8-fluoropurines by direct fluorination of purines with dilute elemental fluorine, or acetyl hypofluorite, is provided. In a preferred embodiment, a purine compound is dissolved in a polar solvent and reacted with a dilute mixture of F.sub.2 in He or other inert gas.

Barrio, Jorge R. (Agoura Hills, CA); Satyamurthy, Nagichettiar (Los Angeles, CA); Namavari, Mohammad (Los Angeles, CA); Phelps, Michael E. (Encino, CA)

2001-01-01T23:59:59.000Z

186

Compound semiconductor MOSFETs  

Science Conference Proceedings (OSTI)

Enhancement mode, high electron mobility MOSFET devices have been fabricated using an oxide high-@k gate dielectric stack developed using molecular beam epitaxy. A template layer of Ga"2O"3, initially deposited on the surface of the III-V device unpins ... Keywords: Compound semiconductors, GaAs gate dielectric, III-V MOSFETs

R. Droopad; K. Rajagopalan; J. Abrokwah; P. Zurcher; M. Passlack

2007-09-01T23:59:59.000Z

187

A compound parabolic concentrator  

SciTech Connect

A compound parabolic concentrator (CPC) for solar energy applications is presented in this work. A prototype was built and its thermal performance was determined. Operating temperatures of the order of 150 /sup 0/C with a reasonable efficiency can be attained by means of a fixed CPC.

Manrique, J.A.

1984-05-01T23:59:59.000Z

188

Long-range global warming impact of gaseous diffusion plant operation  

SciTech Connect

The DOE gaseous diffusion plant complex makes extensive use of CFC-114 as a primary coolant. As this material is on the Montreal Protocol list of materials scheduled for production curtailment, a substitute must be found. In addition to physical cooling properties, the gaseous diffusion application imposes the unique requirement of chemical inertness to fluorinating agents. This has narrowed the selection of a near-term substitute to two fully fluorinated material, FC-318 and FC-3110, which are likely to be strong, long-lived greenhouse gases. In this document, calculations are presented showing, for a number of plausible scenarios of diffusion plant operation and coolant replacement strategy, the future course of coolant use, greenhouse gas emissions (including coolant and power-related indirect CO{sub 2} emissions), and the consequent global temperature impacts of these scenarios.

Trowbridge, L.D.

1992-09-01T23:59:59.000Z

189

Proposed On-Site Waste Disposal Facility (OSWDF) at the Portsmouth Gaseous Diffusion Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

OH OH EM Project: On-Site Disposal Facility ETR Report Date: February 2008 ETR-12 United States Department of Energy Office of Environmental Management (DOE-EM) External Technical Review of the Proposed On-Site Waste Disposal Facility (OSWDF) at the Portsmouth Gaseous Diffusion Plant Why DOE-EM Did This Review The On-Site Waste Disposal Facility (OSWDF) is proposed for long-term containment of contaminated materials from the planned Decontamination and Decommissioning (D&D) activities at the Portsmouth Gaseous Diffusion Plant. Acceptable performance of the proposed OSWDF will depend on interactions between engineered landfill features and operations methods that recognize the unique characteristics of the waste stream and site-

190

Portsmouth Gaseous Diffusion Plant Director's Final Findings and Orders, October 4, 1995 Summary  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth Gaseous Diffusion Plant Director's Final Portsmouth Gaseous Diffusion Plant Director's Final Findings and Orders, October 4, 1995 State Ohio Agreement Type Federal Facility Agreement Legal Driver(s) FFCAct Scope Summary Agreement between the Ohio EPA and DOE approving the STP and setting waste treatment milestones Parties DOE; Ohio Department of Environmental Protection Date 10/4/1995 SCOPE * Approve the Compliance Plan Volume of the amended PSTP submitted to Ohio EPA on October 2, 1995, hereafter referred to as "approved STP." * Set forth guidelines for storage and treatment of mixed wastes at the Facility which are not being stored in accordance with the LDR requirements of OAC rule 3745-59- 50. * Establish milestones and target dates for approved STP. ESTABLISHING MILESTONES

191

Summary - Proposed On-Site Disposal Facility (OSDF) at the Paducah Gaseous Diffusion Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Paducah, KY Paducah, KY EM Project: On-Site Disposal Facility ETR Report Date: August 2008 ETR-16 United States Department of Energy Office of Environmental Management (DOE-EM) External Technical Review of the Proposed On-Site Disposal Facility(OSDF) at the Paducah Gaseous Diffusion Plant Why DOE-EM Did This Review The Paducah Gaseous Diffusion Plant (PGDP) is an active uranium enrichment facility that was placed on the National Priorities List. DOE is required to remediate the PGDP in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). DOE is evaluating alternatives to dispose of waste generated from the remedial activities at the PGDP. One option is to construct an on-site disposal facility (OSDF) meeting the CERCLA requirements.

192

Process and system for removing sulfur from sulfur-containing gaseous streams  

DOE Patents (OSTI)

A multi-stage UCSRP process and system for removal of sulfur from a gaseous stream in which the gaseous stream, which contains a first amount of H.sub.2S, is provided to a first stage UCSRP reactor vessel operating in an excess SO.sub.2 mode at a first amount of SO.sub.2, producing an effluent gas having a reduced amount of SO.sub.2, and in which the effluent gas is provided to a second stage UCSRP reactor vessel operating in an excess H.sub.2S mode, producing a product gas having an amount of H.sub.2S less than said first amount of H.sub.2S.

Basu, Arunabha (Aurora, IL); Meyer, Howard S. (Hoffman Estates, IL); Lynn, Scott (Pleasant Hill, CA); Leppin, Dennis (Chicago, IL); Wangerow, James R. (Medinah, IL)

2012-08-14T23:59:59.000Z

193

Nuclear safety procedure upgrade project at USEC/MMUS gaseous diffusion plants  

SciTech Connect

Martin Marietta Utility Services has embarked on a program to upgrade procedures at both of its Gaseous Diffusion Plant sites. The transition from a U.S. Department of Energy government-operated facility to U.S. Nuclear Regulatory Commission (NRC) regulated has necessitated a complete upgrade of plant operating procedures and practices incorporating human factors as well as a philosophy change in their use. This program is designed to meet the requirements of the newly written 10CFR76, {open_quotes}The Certification of Gaseous Diffusion Plants,{close_quotes} and aid in progression toward NRC certification. A procedures upgrade will help ensure increased nuclear safety, enhance plant operation, and eliminate personnel procedure errors/occurrences.

Kocsis, F.J. III

1994-12-31T23:59:59.000Z

194

D&D of the French High Enrichment Gaseous Diffusion Plant  

SciTech Connect

This paper describes the D&D program that is being implemented at France's High Enrichment Gaseous Diffusion Plant, which was designed to supply France's Military with Highly Enriched Uranium. This plant was definitively shut down in June 1996, following French President Jacques Chirac's decision to end production of Highly Enriched Uranium and dismantle the corresponding facilities.

BEHAR, Christophe; GUIBERTEAU, Philippe; DUPERRET, Bernard; TAUZIN, Claude

2003-02-27T23:59:59.000Z

195

Environmental Restoration Site-Specific Plan for the Paducah Gaseous Diffusion Plant, FY 93  

Science Conference Proceedings (OSTI)

This report provides an overview of the major Environmental Restoration (ER) concerns at Paducah Gaseous Diffusion Plant (PGDP). The identified solid waste management units at PGDP are listed. In the Department of Energy (DOE) Five Year Plan development process, one or more waste management units are addressed in a series of activity data sheets (ADSs) which identify planned scope, schedule, and cost objectives that are representative of the current state of planned technical development for individual or multiple sites.

Not Available

1993-01-15T23:59:59.000Z

196

Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption  

DOE Patents (OSTI)

Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high purity hydrogen from gaseous products of coal gasification and as an acid gas scrubber. 2 figs., 2 tabs.

Ghate, M.R.; Yang, R.T.

1985-10-03T23:59:59.000Z

197

Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption  

DOE Patents (OSTI)

Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon, zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high parity hydrogen from gaseous products of coal gasification and as an acid gas scrubber.

Ghate, Madhav R. (Morgantown, WV); Yang, Ralph T. (Williamsville, NY)

1987-01-01T23:59:59.000Z

198

Environmental effects of the construction and operation of a gaseous diffusion plant  

SciTech Connect

The impacts upon the environment resulting from construction, stert-up, and operation of a gaseous dfffusion plant are described. Some of the impacts are typical regardless of location of the plant. Others are atypical and depend upon location; those are presented, by way of example, as they occur at the Portsmouth Gaseous Diffusion Plant. The various environmental contaminants that may be produced in the operating plant are described. The concentrations of those contaminants are stated; and the adverse biological effects of pertinent conteminants are elucidated. UF/sup 6/ may be enriched in the Portsmouth Gaseous Wffusion Plant to almost any /sup 235/U concentration desired. The environmental impact of the plant varies somewhat according to /sup 235/U concentrations. However, commercial plants are not expected to enrich /sup 235/U in concentrations greater than 4%. for this reason, environmental effects due to Portsmouth operations within that range are emphasized. The study revealed that present discharges from the plants generally have no detrimental effects upon the environment. (auth)

1973-07-26T23:59:59.000Z

199

Oak Ridge National Lebroatory Liquid&Gaseous Waste Treatment System Strategic Plan  

SciTech Connect

Excellence in Laboratory operations is one of the three key goals of the Oak Ridge National Laboratory (ORNL) Agenda. That goal will be met through comprehensive upgrades of facilities and operational approaches over the next few years. Many of ORNL's physical facilities, including the liquid and gaseous waste collection and treatment systems, are quite old, and are reaching the end of their safe operating life. The condition of research facilities and supporting infrastructure, including the waste handling facilities, is a key environmental, safety and health (ES&H) concern. The existing infrastructure will add considerably to the overhead costs of research due to increased maintenance and operating costs as these facilities continue to age. The Liquid Gaseous Waste Treatment System (LGWTS) Reengineering Project is a UT-Battelle, LLC (UT-B) Operations Improvement Program (OIP) project that was undertaken to develop a plan for upgrading the ORNL liquid and gaseous waste systems to support ORNL's research mission.

Van Hoesen, S.D.

2003-09-09T23:59:59.000Z

200

The Use of New Parameterizations for Gaseous Absorption in the CLIRAD-SW Solar Radiation Code for Models  

Science Conference Proceedings (OSTI)

The new gaseous absorption parameterizations are incorporated in the CLIRAD-SW solar radiation code for models, openly distributed for the scientific community. In the new parameterizations, the magnitude of absorption coefficients in each ...

T. A. Tarasova; B. A. Fomin

2007-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Joint Test Plan to Identify the Gaseous By-Products of CH3I Loading on AgZ  

SciTech Connect

The objective of this test plan is to describe research to determine the gaseous by-products of the adsorption of CH3I on hydrogen reduced silver exchanged mordenite (AgZ).

R. T. Jubin; N. R. Soelberg; D. M. Strachan; T. M. Nenoff; B. B. Spencer

2012-12-01T23:59:59.000Z

202

Review of the Portsmouth Gaseous Diffusion Plant Integrated Safety Management System Phase I Verification Review, April 2013  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth Gaseous Diffusion Plant Portsmouth Gaseous Diffusion Plant Integrated Safety Management System Phase I Verification Review April 2013 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose ................................................................................................................................................. 1 2.0 Scope.................................................................................................................................................... 1 3.0 Background........................................................................................................................................... 1 4.0 Methodology......................................................................................................................................... 1

203

Review of the Portsmouth Gaseous Diffusion Plant Integrated Safety Management System Phase I Verification Review, April 2013  

NLE Websites -- All DOE Office Websites (Extended Search)

Portsmouth Gaseous Diffusion Plant Portsmouth Gaseous Diffusion Plant Integrated Safety Management System Phase I Verification Review April 2013 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose ................................................................................................................................................. 1 2.0 Scope.................................................................................................................................................... 1 3.0 Background........................................................................................................................................... 1 4.0 Methodology......................................................................................................................................... 1

204

Gas separation process using membranes with permeate sweep to remove CO.sub.2 from gaseous fuel combustion exhaust  

DOE Patents (OSTI)

A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.

Wijmans Johannes G. (Menlo Park, CA); Merkel, Timothy C. (Menlo Park, CA); Baker, Richard W. (Palo Alto, CA)

2012-05-15T23:59:59.000Z

205

Hydrogen in compound semiconductors  

DOE Green Energy (OSTI)

Progress in the understanding of hydrogen and its interactions in III/V and II/VI compound semiconductors is reviewed. Donor, acceptor and deep level passivation is well established in III/V compounds based on electrical measurements and on spectroscopic studies. The hydrogen donor levels in GaAs and GaP are estimated to lie near E{sub v}+0.5 eV and E{sub v}+0.3 eV, respectively. Arsenic acceptors have been passivated by hydrogen in CdTe and the very first nitrogen-hydrogen local vibrational model spectra in ZnSe have been reported. This long awaited result may lead to an explanation for the poor activation of nitrogen acceptors in ZnSe grown by techniques which involve high concentrations of hydrogen.

Haller, E.E.

1993-05-01T23:59:59.000Z

206

MICROSTRUCTURE AND MECHANICAL PROPERTY PERFORMANCE OF COMMERCIAL GRADE API PIPELINE STEELS IN HIGH PRESSURE GASEOUS HYDROGEN  

Science Conference Proceedings (OSTI)

The continued growth of the world s developing countries has placed an ever increasing demand on traditional fossil fuel energy sources. This development has lead to increasing research and development of alternative energy sources. Hydrogen gas is one of the potential alternative energy sources under development. Currently the most economical method of transporting large quantities of hydrogen gas is through steel pipelines. It is well known that hydrogen embrittlement has the potential to degrade steel s mechanical properties when hydrogen migrates into the steel matrix. Consequently, the current pipeline infrastructure used in hydrogen transport is typically operated in a conservative fashion. This operational practice is not conducive to economical movement of significant volumes of hydrogen gas as an alternative to fossil fuels. The degradation of the mechanical properties of steels in hydrogen service is known to depend on the microstructure of the steel. Understanding the levels of mechanical property degradation of a given microstructure when exposed to hydrogen gas under pressure can be used to evaluate the suitability of the existing pipeline infrastructure for hydrogen service and guide alloy and microstructure design for new hydrogen pipeline infrastructure. To this end, the 2 Copyright 2010 by ASME microstructures of relevant steels and their mechanical properties in relevant gaseous hydrogen environments must be fully characterized to establish suitability for transporting hydrogen. A project to evaluate four commercially available pipeline steels alloy/microstructure performance in the presences of gaseous hydrogen has been funded by the US Department of Energy along with the private sector. The microstructures of four pipeline steels were characterized and then tensile testing was conducted in gaseous hydrogen and helium at pressures of 800, 1600 and 3000 psi. Based on measurements of reduction of area, two of the four steels that performed the best across the pressure range were selected for evaluation of fracture and fatigue performance in gaseous hydrogen at 800 and 3000 psi. This paper will describe the work performed on four commercially available pipeline steels in the presence of gaseous hydrogen at pressures relevant for transport in pipelines. Microstructures and mechanical property performances will be compared. In addition, recommendations for future work related to gaining a better understanding of steel pipeline performance in hydrogen service will be discussed.

Stalheim, Mr. Douglas [DGS Metallurgical Solutions Inc; Boggess, Todd [Secat; San Marchi, Chris [Sandia National Laboratories (SNL); Jansto, Steven [Reference Metals Company; Somerday, Dr. B [Sandia National Laboratories (SNL); Muralidharan, Govindarajan [ORNL; Sofronis, Prof. Petros [University of Illinois

2010-01-01T23:59:59.000Z

207

Injection Molding Compounds  

Science Conference Proceedings (OSTI)

Table 5   Common thermoplastic and thermoset molding compounds...(r) (s) (t) Phenolic Distributor caps, plastic ash trays (a) (b) (g) (h) (i) (j) (k) (l) (m) (n) (o) (q) (r) (s) (t) Urethane Automotive body panels, bumpers (a) (d) (e) (g) (i) (l) (m) (o) (q) (r) (t) Vinyl ester Composite car/truck springs, wheels (b) (d) (e) (g) (i) (j) (k) (l) (m) (n) (o) (p)...

208

Measuring the Effect of Fuel Chemical Structure on Particulate and Gaseous Emissions using Isotope Tracing  

DOE Green Energy (OSTI)

Using accelerator mass spectrometry (AMS), a technique initially developed for radiocarbon dating and recently applied to internal combustion engines, carbon atoms within specific fuel molecules can be labeled and followed in particulate or gaseous emissions. In addition to examining the effect of fuel chemical structure on emissions, the specific source of carbon for PM can be identified if an isotope label exists in the appropriate fuel source. Existing work has focused on diesel engines, but the samples (soot collected on quartz filters or combustion gases captured in bombs or bags) are readily collected from large industrial combustors as well.

Buchholz, B A; Mueller, C J; Martin, G C; Upatnicks, A; Dibble, R W; Cheng, S

2003-09-11T23:59:59.000Z

209

Replacement of chlorofluorocarbons (CFCs) at the DOE gaseous diffusion plants: An assessment of global impacts  

SciTech Connect

The US Department of Energy (DOE) formerly operated two gaseous diffusion plants (GDPs) for enriching uranium and maintained a third shutdown GDP. These plants maintain a large inventory of dichlorotetrafluorethane (CFC-114), a cholorofluorocarbon (CFC), as a coolant. The paper evaluates the global impacts of four alternatives to modify GDP coolant system operations for a three-year period beginning in 1996. Interim modification of GDP coolant system operations has the potential to reduce stratospheric ozone depletion from GDP coolant releases while a permanent solution is studied.

Socolof, M.L.; Saylor, R.E.; McCold, L.N.

1994-06-01T23:59:59.000Z

210

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents (OSTI)

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1984-06-19T23:59:59.000Z

211

(2) Quantities and Prices of Animal Manure and Gaseous Fuels Generated:  

E-Print Network (OSTI)

In this context, we are defining animal manure as the excrement of livestock reared in agricultural operations as well as straw, sawdust, and other residues used as animal bedding. Gaseous fuels may be derived from municipal and industrial landfills (landfill gas) or from animal manure and solid biomass such as crop silage or the organic fraction of MSW (biogas). Both landfill gas and biogas are generated via anaerobic digestion, a multi-stage process whereby bacteria convert carbohydrates, fats, and proteins to methane (Evans 2001). EPA does not consider these materials to be wastes in themselves, when used as fuel, but rather materials derived from wastes.

unknown authors

2010-01-01T23:59:59.000Z

212

Liquefied Gaseous Fuels Safety and Environmental Control Assessment Program: second status report  

SciTech Connect

This document is arranged in three volumes and reports on progress in the Liquefied Gaseous Fuels (LGF) Safety and Environmental Control Assessment Program made in fiscal Year (FY)-1979 and early FY-1980. Volume 3 contains reports from 6 government contractors on LPG, anhydrous ammonia, and hydrogen energy systems. Report subjects include: simultaneous boiling and spreading of liquefied petroleum gas (LPG) on water; LPG safety research; state-of-the-art of release prevention and control technology in the LPG industry; ammonia: an introductory assessment of safety and environmental control information; ammonia as a fuel, and hydrogen safety and environmental control assessment.

1980-10-01T23:59:59.000Z

213

2013 GASEOUS IONS GORDON RESEARCH CONFERENCE, FEBRUARY 24 - MARCH 1, 2013  

Science Conference Proceedings (OSTI)

The Gaseous Ions: Structures, Energetics and Reactions Gordon Research Conference will focus on ions and their interactions with molecules, surfaces, electrons, and light. The long-standing goal of our community is to develop new strategies for capturing complex molecular architectures as gas phase ions where they can be isolated, characterized and manipulated with great sensitivity. Emergent areas of interest include catalytic mechanisms, cryogenic processing of ions extracted from solution, ion fragmentation mechanisms, and new methods for ion formation and structural characterization. The conference will cover theoretical and experimental advances on systems ranging from model studies at the molecular scale to preparation of nanomaterials and characterization of large biological molecules.

Williams, Evan

2013-03-01T23:59:59.000Z

214

Separation of normally gaseous hydrocarbons from a catalytic reforming effluent and recovery of purified hydrogen  

Science Conference Proceedings (OSTI)

A process for the catalytic reforming of a hydrocarbonaceous feedstock, preferably to produce high quality gasoline boiling range products, is disclosed. Relatively impure hydrogen is separated from the reforming zone effluent, compressed, and recontacted with at least a portion of the liquid reformate product to provide relatively pure hydrogen, a portion of which is recycled to the reforming zone. The balance is further compressed and recontacted with at least a portion of the liquid reformate product to provide an improved recovery of normally gaseous hydrocarbons as well as an improved recovery of purified hydrogen at a pressure suitable for use in the relatively high pressure hydrotreating of sulfur-containing feedstocks.

Coste, A.C.

1982-06-08T23:59:59.000Z

215

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents (OSTI)

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

1984-01-01T23:59:59.000Z

216

Linking the gaseous and the condensed phases of matter: The slow electron and its interactions  

SciTech Connect

The interfacing of the gaseous and the condensed phases of matter as effected by interphase and cluster studies on the behavior of key reactions involving slow electrons either as reacting initial particles or as products of the reactions themselves is discussed. Emphasis is placed on the measurement of both the cross sections and the energetics involved, although most of the available information to date is on the latter. The discussion is selectively focussed on electron scattering (especially the role of negative ion states in gases, clusters, and dense matter), ionization, electron attachment and photodetachment. The dominant role of the electric polarization of the medium is emphasized.

Christophorou, L.G.

1993-12-31T23:59:59.000Z

217

Heat-pipe effect on the transport of gaseous radionuclides released from a nuclear waste container  

SciTech Connect

When an unsaturated porous medium is subjected to a temperature gradient and the temperature is sufficiently high, vadose water is heated and vaporizes. Vapor flows under its pressure gradient towards colder regions where it condenses. Vaporization and condensation produce a liquid saturation gradient, creating a capillary pressure gradient inside the porous medium. Condensate flows towards the hot end under the influence of a capillary pressure gradient. This is a heat pipe in an unsaturated porous medium. We study analytically the transport of gaseous species released from a spent-fuel waste package, as affected by a time-dependent heat pipe in an unsaturated rock. For parameter values typical of a potential repository in partially saturated fractured tuff at Yucca Mountain, we found that a heat pipe develops shortly after waste is buried, and the heat-pipe`s spatial extent is time-dependent. Water vapor movements produced by the heat pipe can significantly affect the migration of gaseous radionuclides. 12 refs., 6 figs., 1 tab.

Zhou, W.; Chambre, P.L.; Pigford, T.H.; Lee, W.W.L.

1990-11-01T23:59:59.000Z

218

Project plan for the background soils project for the Paducah Gaseous Diffusion Plant, Paducah, Kentucky  

SciTech Connect

The Background Soils Project for the Paducah Gaseous Diffusion Plant (BSPP) will determine the background concentration levels of selected naturally occurring metals, other inorganics, and radionuclides in soils from uncontaminated areas in proximity to the Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky. The data will be used for comparison with characterization and compliance data for soils, with significant differences being indicative of contamination. All data collected as part of this project will be in addition to other background databases established for the PGDP. The BSPP will address the variability of surface and near-surface concentration levels with respect to (1) soil taxonomical types (series) and (2) soil sampling depths within a specific soil profile. The BSPP will also address the variability of concentration levels in deeper geologic formations by collecting samples of geologic materials. The BSPP will establish a database, with recommendations on how to use the data for contaminated site assessment, and provide data to estimate the potential human and health and ecological risk associated with background level concentrations of potentially hazardous constituents. BSPP data will be used or applied as follows.

NONE

1995-09-01T23:59:59.000Z

219

The Radiochemical Analysis of Gaseous Samples (RAGS) Apparatus for Nuclear Diagnostics at the National Ignition Facility  

SciTech Connect

The RAGS (Radiochemical Analysis of Gaseous Samples) diagnostic apparatus was recently installed at the National Ignition Facility. Following a NIF shot, RAGS is used to pump the gas load from the NIF chamber for purification and isolation of the noble gases. After collection, the activated gaseous species are counted via gamma spectroscopy for measurement of the capsule areal density and fuel-ablator mix. Collection efficiency was determined by injecting a known amount of {sup 135}Xe into the NIF chamber, which was then collected with RAGS. Commissioning was performed with an exploding pusher capsule filled with isotopically enriched {sup 124}Xe and {sup 126}Xe added to the DT gas fill. Activated xenon species were recovered post-shot and counted via gamma spectroscopy. Results from the collection and commissioning tests are presented. The performance of RAGS allows us to establish a noble gas collection method for measurement of noble gas species produced via neutron and charged particle reactions in a NIF capsule.

Shaughnessy, D A; Velsko, C A; Jedlovec, D R; Yeamans, C B; Moody, K J; Tereshatov, E; Stoeffl, W; Riddle, A

2012-05-11T23:59:59.000Z

220

Anisotropic gaseous models of tidally limited star clusters -- comparison with other methods  

E-Print Network (OSTI)

We present new models of the evolution and dissolution of star clusters evolving under the combined influence of internal relaxation and external tidal fields, using the anisotropic gaseous model based on the Fokker-Planck approximation, and a new escaper loss cone model. This model borrows ideas from loss cones of stellar distributions near massive black holes, and describes physical processes related to escaping stars by a simple model based on two timescales and a diffusion process. We compare our results with those of direct $N$-body models and of direct numerical solutions of the orbit-averaged Fokker-Planck equation. For this comparative study we limit ourselves to idealized single point mass star clusters, in order to present a detailed study of the physical processes determining the rate of mass loss, core collapse and other features of the system's evolution. With the positive results of our study the path is now open in the future to use the computationally efficient gaseous models for future studies with more realism (mass spectrum, stellar evolution).

R. Spurzem; M. Giersz; K. Takahashi; A. Ernst

2004-12-30T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Liquefied Gaseous Fuels Safety and Environmental Control Assessment Program: second status report  

DOE Green Energy (OSTI)

The Assistant Secretary for Environment has responsibility for identifying, characterizing, and ameliorating the environmental, health, and safety issues and public concerns associated with commercial operation of specific energy systems. The need for developing a safety and environmental control assessment for liquefied gaseous fuels was identified by the Environmental and Safety Engineering Division as a result of discussions with various governmental, industry, and academic persons having expertise with respect to the particular materials involved: liquefied natural gas, liquefied petroleum gas, hydrogen, and anhydrous ammonia. This document is arranged in three volumes and reports on progress in the Liquefied Gaseous Fuels (LGF) Safety and Environmental Control Assessment Program made in Fiscal Year (FY)-1979 and early FY-1980. Volume 1 (Executive Summary) describes the background, purpose and organization of the LGF Program and contains summaries of the 25 reports presented in Volumes 2 and 3. Annotated bibliographies on Liquefied Natural Gas (LNG) Safety and Environmental Control Research and on Fire Safety and Hazards of Liquefied Petroleum Gas (LPG) are included in Volume 1.

Not Available

1980-10-01T23:59:59.000Z

222

Mixture of micronized coal powder with gaseous fuels for use in internal combustion engines  

DOE Patents (OSTI)

An improved fuel mixture for use in internal combustion engines is described. This fuel is an intimate mixture of micronized coal, having an average particle size of less than 100 microns, with a gaseous fuel selected from natural gas and coal-derived. The coal can be present from more than 0 percent to less than 100 percent, with generally the lower percentages being preferred. The addition of the coal to the gaseous fuel improves engine efficiency and power rating, and also decreases peak engine pressure allowing for higher compression ratios. An increase in the amount of the coal increases the oxides of sulfur while reducing the oxides of nitrogen in the exhaust. An increase in the amount of gas, on the other hand, increases the oxides of nitrogen but lowers oxides of sulfur. Accordingly, a preferred mixture will depend upon a particular application for the coal/gas fuel and thereby increases user fuel flexibility considerations. Modeling of the fuel mixture for use in a diesel engine is described. 3 figs., 3 tabs.

Carpenter, L.K.

1990-01-03T23:59:59.000Z

223

Sandia National Labs: PCNSC: Research: Compound Semiconductor...  

NLE Websites -- All DOE Office Websites (Extended Search)

Compound Semiconductor Science and Technology Thrust The Physical, Chemical, and Nano Sciences Center's vision for Compound Semiconductors is to develop the science of compound...

224

High-Value Fluorine Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Compounds Baseline plans call for production of anhydrous or aqueous Hydrogen Fluoride (HF) from the DU hexafluoride conversion plant and subsequent recycle of these...

225

Potential Signatures of Semi-volatile Compounds Associated With Nuclear Processing  

SciTech Connect

Semi-volatile chemicals associated with nuclear processes (e.g., the reprocessing of uranium to produce plutonium for nuclear weapons, or the separation of actinides from processing waste streams), can provide sticky residues or signatures that will attach to piping, ducting, soil, water, or other surface media. Volatile compounds, that are more suitable for electro-optical sensing, have been well studied. However, the semi-volatile compounds have not been well documented or studied. A majority of these semi-volatile chemicals are more robust than typical gaseous or liquid chemicals and can have lifetimes of several weeks, months, or years in the environment. However, large data gaps exist concerning these potential signature compounds and more research is needed to fill these data gaps so that important signature information is not overlooked or discarded. This report investigates key semi-volatile compounds associated with nuclear separations, identifies available chemical and physical properties, and discusses the degradation products that would result from hydrolysis, radiolysis and oxidation reactions on these compounds.

Probasco, Kathleen M.; Birnbaum, Jerome C.; Maughan, A. D.

2002-06-01T23:59:59.000Z

226

Indirect NMR detection of 235U in gaseous uranium hexafluoride National Center for Physics, P.O. Box MG-6, Bucharest, Romania  

E-Print Network (OSTI)

L-493 Indirect NMR detection of 235U in gaseous uranium hexafluoride I. Ursu National Center- vation of235 U NMR signal in liquid UF6 at B = 11.747 T has been recently reported [7]. The aim of this Letter is to investigate the effect of the 23 5U enrichment on the 19F NMR spectra in gaseous UF6. Using

Paris-Sud XI, Université de

227

Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents (OSTI)

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

228

Apparatus and method for operating internal combustion engines from variable mixtures of gaseous fuels  

DOE Patents (OSTI)

An apparatus and method for utilizing any arbitrary mixture ratio of multiple fuel gases having differing combustion characteristics, such as natural gas and hydrogen gas, within an internal combustion engine. The gaseous fuel composition ratio is first sensed, such as by thermal conductivity, infrared signature, sound propagation speed, or equivalent mixture differentiation mechanisms and combinations thereof which are utilized as input(s) to a "multiple map" engine control module which modulates selected operating parameters of the engine, such as fuel injection and ignition timing, in response to the proportions of fuel gases available so that the engine operates correctly and at high efficiency irrespective of the gas mixture ratio being utilized. As a result, an engine configured according to the teachings of the present invention may be fueled from at least two different fuel sources without admixing constraints.

Heffel, James W. (Lake Matthews, CA); Scott, Paul B. (Northridge, CA); Park, Chan Seung (Yorba Linda, CA)

2011-11-01T23:59:59.000Z

229

Proposed On-Site Disposal Facility (OSDF) at the Paducah Gaseous Diffusion Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

i i TABLE OF CONTENTS 1. INTRODUCTION 1 2. LINE OF INQUIRY NO. 1 - Future Uses of the Subtitle D Landfill 2 3. LINE OF INQUIRY NO. 2 - OSDF Siting in a Brownfield Area 3 4. LINE OF INQUIRY NO. 3 - Seismic Issues 4 5. LINE OF INQUIRY NO. 4 - Post-Closure Public Use of the OSDF 5 6. LINE OF INQUIRY NO. 5 - Public Communication Plan 7 7. LINE OF INQUIRY NO. 6 - Baseline Schedule 8 8. RECOMMENDATIONS 8 9. ACKNOWLEDGEMENT 10 10. REFERENCES 10 APPENDIX 11 1 1. INTRODUCTION The Paducah Gaseous Diffusion Plant (PGDP) is an active uranium enrichment facility that is owned by the US Department of Energy (DOE). Uranium enrichment facilities at PGDP are leased to and operated by the United States Enrichment Corporation. In 1994, PGDP was placed

230

Lessons Learned from Practical Field Experience with High Pressure Gaseous Fuels  

NLE Websites -- All DOE Office Websites (Extended Search)

5/2010 5/2010 www.cleanvehicle.org 1 Lessons Learned from Practical Field Experience with High Pressure Gaseous Fuels DOE - DOT CNG - H 2 Workshop December 10, 2009 Douglas Horne, PE - CVEF President Rob Adams, P.Eng. - Marathon Technical Services The Facts  NGVs have been used in North America for over 30 years  Codes and Standards (C&S) provide opportunity for safe reliable operation of NGVs  C&S evolve with new technology and field experience  People make mistakes, continuous training is critical for safe operations  Cylinders have a limited life -track your cylinders! 2/25/2010 www.cleanvehicle.org 2 Incidents in North America  Since 1984 CVEF has recorded 97 incidents of which 67 involved CNG vehicles - 37 incidents involve either a CNG leak (15) or a

231

Assessment of methods for analyzing gaseous mixtures of hydrogen isotopes and helium  

DOE Green Energy (OSTI)

Mass spectrographic methods have served well in the past to analyze gaseous mixtures of the hydrogen isotopes. Alternate methods of analyses are reviewed which offer wider ranges and variety of isotopic determinations. This report describes possible improvements of the mass spectrographic determinations, gas chromatography, anti-Stokes Raman spectroscopy, microwave-induced optical emission spectroscopy, and methods of measuring tritium using radiation detection devices. Precision, accuracy, limitations, and costs are included for some of the methods mentioned. Costs range from $70,000 for the anti-Stokes Raman spectroscopy equipment, which can determine hydrogen isotopes but not helium, to less than $10,000 for the gas chromatographic equipment, which can determine hydrogen isotopes and helium with precision and accuracy comparable to those of the mass spectrometer.

Attalla, A.; Bishop, C.T.; Bohl, D.R.; Buxton, T.L.; Sprague, R.E.; Warner, D.K.

1976-10-20T23:59:59.000Z

232

Preliminary assessment of the gaseous fuels aftermarket conversion industry. Final report  

Science Conference Proceedings (OSTI)

The purpose of the report is to provide information to be used in assessing the potential impacts of EPA's proposed Gaseous Fuels and Clean Fuel Fleet rulemakings on the aftermarket conversion industry. Therefore, the report will focus on issues germane to determining these impacts (such as financial profiles of companies involved, future trends in industry development and sales, and costs of complying with conversion requirements) rather than assessing the viability of current technologies or the emissions benefits of alternative fuels. Moreover, the report focuses on conversions to CNG and LPG as conversions to these fuels are most viable at this time, even though EPA's proposed conversion regulations could potentially apply to any fuel (e.g., liquid natural gas).

Not Available

1992-09-28T23:59:59.000Z

233

Method and apparatus for removal of gaseous, liquid and particulate contaminants from molten metals  

DOE Patents (OSTI)

Method and apparatus for removal of nonelectrically-conducting gaseous, liquid, and particulate contaminants from molten metal compositions by applying a force thereto. The force (commonly referred to as the Lorentz Force) exerted by simultaneous application of an electric field and a magnetic field on a molten conductor causes an increase, in the same direction as the force, in the apparent specific gravity thereof, but does not affect the nonconducting materials. This difference in apparent densities cause the nonconducting materials to "float" in the opposite direction from the Lorentz Force at a rapid rate. Means are further provided for removal of the contaminants and prevention of stirring due to rotational forces generated by the applied fields.

Hobson, David O. (Oak Ridge, TN); Alexeff, Igor (Oak Ridge, TN); Sikka, Vinod K. (Clinton, TN)

1988-01-01T23:59:59.000Z

234

Report on the biological monitoring program at Paducah Gaseous Diffusion Plant December 1990 to November 1992  

Science Conference Proceedings (OSTI)

On September 23, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous Diffusion Plant (PGDP). Beginning in fall 1991, the Environmental Sciences Division (ESD) at Oak Ridge National Lab (ORNL) added data collection and report preparation to its responsibilities for the PGDP BMP. The BMP has been continued because it has proven to be extremely valuable in identifying those effluents with the potential for adversely affecting instream fauna, assessing the ecological health of receiving streams, guiding plans for remediation, and protecting human health. In September 1992, a renewed permit was issued which requires toxicity monitoring of continuous and intermittent outfalls on a quarterly basis. The BMP for PGDP consists of three major tasks: (1) effluent and ambient toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of stream communities. This report includes ESD/ORNL activities occurring from December 1990 to November 1992.

Kszos, L.A. [ed.

1994-03-01T23:59:59.000Z

235

Report on the Biological Monitoring Program at Paducah Gaseous Diffusion Plant December 1992--December 1993  

SciTech Connect

On September 24, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous Diffusion Plant (PGDP). The goals of BMP are to demonstrate that the effluent limitations established for PGDP protect and maintain the use of Little Bayou and Big Bayou creeks for growth and propagation of fish and other aquatic life, characterize potential health and environmental impacts, document the effects of pollution abatement facilities on stream biota, and recommend any program improvements that would increase effluent treatability. The BMP for PGDP consists of three major tasks: effluent and ambient toxicity monitoring, bioaccumulation studies, and ecological surveys of stream communities (i.e., benthic macroinvertebrates and fish). This report includes ESD activities occurring from December 1992 to December 1993, although activities conducted outside this time period are included as appropriate.

Kszos, L.A.; Hinzman, R.L.; Peterson, M.J.; Ryon, M.G.; Smith, J.G.; Southworth, G.R.

1995-06-01T23:59:59.000Z

236

Method and apparatus for removal of gaseous, liquid and particulate contaminants from molten metals  

DOE Patents (OSTI)

Method and apparatus for removal of nonelectrically-conducting gaseous, liquid, and particulate contaminants from molten metal compositions by applying a force thereto. The force (commonly referred to as the Lorentz Force) exerted by simultaneous application of an electric field and a magnetic field on a molten conductor causes an increase, in the same direction as the force, in the apparent specific gravity thereof, but does not affect the nonconducting materials. This difference in apparent densities cause the nonconducting materials to ''float'' in the opposite direction from the Lorentz Force at a rapid rate. Means are further provided for removal of the contaminants and prevention of stirring due to rotational forces generated by the applied fields. 6 figs.

Hobson, D.O.; Alexeff, I.; Sikka, V.K.

1987-08-10T23:59:59.000Z

237

Liquefied gaseous fuels safety and environmental control assessment program: third status report  

Science Conference Proceedings (OSTI)

This Status Report contains contributions from all contractors currently participating in the DOE Liquefied Gaseous Fuels (LG) Safety and Environmental Control Assessment Program and is presented in two principal sections. Section I is an Executive Summary of work done by all program participants. Section II is a presentation of fourteen individual reports (A through N) on specific LGF Program activities. The emphasis of Section II is on research conducted by Lawrence Livermore National Laboratory (Reports A through M). Report N, an annotated bibliography of literature related to LNG safety and environmental control, was prepared by Pacific Northwest Laboratory (PNL) as part of its LGF Safety Studies Project. Other organizations who contributed to this Status Report are Aerojet Energy Conversion Company; Applied Technology Corporation; Arthur D. Little, Incorporated; C/sub v/ International, Incorporated; Institute of Gas Technology; and Massachusetts Institute of Technology. Separate abstracts have been prepared for Reports A through N for inclusion in the Energy Data Base.

Not Available

1982-03-01T23:59:59.000Z

238

Separation of normally gaseous hydrocarbons from a catalytic reforming effluent and recovery of purified hydrogen  

Science Conference Proceedings (OSTI)

A process for the catalytic reforming of a hydrocarbonaceous feedstock, preferably to produce high quality gasoline boiling range products, is disclosed. Relatively impure hydrogen is separated from the reforming zone effluent, compressed, and recontacted with at least a portion of the liquid reformate product to provide relatively pure hydrogen, a portion of which is recycled to the reforming zone. The balance is further compressed and recontacted with at least a portion of the liquid reformate product in a plural stage absorption zone to provide an improved recovery of normally gaseous hydrocarbons as well as an improved recovery of purified hydrogen at a pressure suitable, for example, the relatively high pressure hydrotreating of sulfur-containing feedstocks.

O'brien, D.E.

1982-06-08T23:59:59.000Z

239

Privatization of the gaseous diffusion plants and impacts on nuclear criticality safety administration  

SciTech Connect

The Energy Policy Act of 1992 created the United States Enrichment Corporation (USEC) on July 1, 1993. The USEC is a government-owned business that leases those Gaseous Diffusion Plant (GDP) facilities at the Portsmouth, Ohio, and Paducah, Kentucky, sites from the U.S. Department of Energy (DOE) that are required for enriching uranium. Lockheed Martin Utility Services is the operating contractor for the USEC-leased facilities. The DOE has retained use of, and regulation over, some facilities and areas at the Portsmouth and Paducah sites for managing legacy wastes and environmental restoration activities. The USEC is regulated by the DOE, but is currently changing to regulation under the U.S. Nuclear Regulatory Commission (NRC). The USEC is also preparing for privatization of the uranium enrichment enterprise. These changes have significantly affected the nuclear criticality safety (NCS) programs at the sites.

D`Aquila, D.M.; Holliday, R.T. [Lockheed Martin Utility Services, Inc., Piketon, OH (United States); Dean, J.C. [Lockheed Martin Utility Services, Inc., Paducah, KY (United States)

1996-12-31T23:59:59.000Z

240

METHOD OF REDUCING PLUTONIUM COMPOUNDS  

DOE Patents (OSTI)

A method is described for reducing plutonium compounds in aqueous solution from a higher to a lower valence state. This reduction of valence is achieved by treating the aqueous solution of higher valence plutonium compounds with hydrogen in contact with an activated platinum catalyst.

Johns, I.B.

1958-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Rate of Contamination Removal of Two Phyto-remediation Sites at the DOE Portsmouth Gaseous Diffusion Plant  

SciTech Connect

This paper describes applications of phyto-remediation at the Portsmouth Gaseous Diffusion Plant (PORTS), a Department of Energy (DOE) Facility that enriched uranium from the early 1950's until 2000. Phyto-remediation has been implemented to assist in the removal of TCE (trichloroethylene) in the groundwater at two locations at the PORTS facility: the X-740 area and the X-749/X-120 area. Phyto-remediation technology is based on the ability of certain plants species (in this case hybrid poplar trees) and their associated rhizo-spheric microorganisms to remove, degrade, or contain chemical contaminants located in the soil, sediment, surface water, groundwater, and possibly even the atmosphere. Phyto-remediation technology is a promising clean-up solution for a wide variety of pollutants and sites. Mature trees, such as the hybrid poplar, can consume up to 3,000 gallons of groundwater per acre per day. Organic compounds are captured in the trees' root systems. These organic compounds are degraded by ultraviolet light as they are transpired along with the water vapor through the leaves of the trees. The phyto-remediation system at the X-740 area encompasses 766 one-year old hybrid poplar trees (Populus nigra x nigra, Populus nigra x maximowiczii, and Populus deltoides x nigra) that were planted 10 feet apart in rows 10 feet to 20 feet apart, over an area of 2.6 acres. The system was installed to manage the VOC contaminant plume. At the X749/X-120 area, a phyto-remediation system of 2,640 hybrid poplar trees (Populus nigra x maximowiczii) was planted in seven areas/zones to manage the VOC contaminant plume. The objectives of these systems are to remove contamination from the groundwater and to prevent further migration of contaminants. The goal of these remediation procedures is to achieve completely mature and functional phyto-remediation systems within two years of the initial planting of the hybrid poplar trees at each planting location. There is a direct relationship between plant transpiration, soil moisture, and groundwater flow in a phyto-remediation system. The existing monitoring program was expanded in 2004 in order to evaluate the interactions among these processes. The purpose of this monitoring program was to determine the rate of contaminant removal and to more accurately predict the amount of time needed to remediate the contaminated groundwater. Initial planting occurred in 1999 at the X-740 area, with additional replanting in 2001 and 2002. In 2003, coring of selected trees and chemical analyses illustrated the presence of TCE; however, little impact was observed in groundwater levels, analytical monitoring, and periodic tree diameter monitoring at the X-740 area. To provide better understanding of how these phyto-remediation systems work, a portable weather station was installed at the X-740 area to provide data for estimating transpiration and two different systems for measuring sap flow and sap velocity were outfitted to numerous trees. After evaluating and refining the groundwater flow and contaminant transport models, the data gathered by these two inventive methods can be used to establish a rate of contaminant removal and to better predict the time required in order to meet remediation goals for the phyto-remediation systems located at the PORTS site. (authors)

Lewis, A.C.; Baird, D.R. [CDM Federal Services, P.O. Box 789, Piketon, OH 45661 (United States)

2006-07-01T23:59:59.000Z

242

Devices for collecting chemical compounds  

SciTech Connect

A device for sampling chemical compounds from fixed surfaces and related methods are disclosed. The device may include a vacuum source, a chamber and a sorbent material. The device may utilize vacuum extraction to volatilize the chemical compounds from a fixed surface so that they may be sorbed by the sorbent material. The sorbent material may then be analyzed using conventional thermal desorption/gas chromatography/mass spectrometry (TD/GC/MS) instrumentation to determine presence of the chemical compounds. The methods may include detecting release and presence of one or more chemical compounds and determining the efficacy of decontamination. The device may be useful in collection and analysis of a variety of chemical compounds, such as residual chemical warfare agents, chemical attribution signatures and toxic industrial chemicals.

Scott, Jill R; Groenewold, Gary S

2013-12-24T23:59:59.000Z

243

Review of the Portsmouth Gaseous Diffusion Plant Work Planning and Control Activities Prior to Work Execution, January 2013  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Review of the Review of the Portsmouth Gaseous Diffusion Plant Work Planning and Control Activities Prior to Work Execution January 2013 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose ................................................................................................................................................. 1 2.0 Scope.................................................................................................................................................... 1 3.0 Background........................................................................................................................................... 1

244

Analytical risk-based model of gaseous and liquid-phase radon transport in landfills with radium sources  

Science Conference Proceedings (OSTI)

An analytical model of gaseous and liquid-phase radon transport through soils is derived for environmental modeling of landfills containing uranium mill tailings or Ra-226 sources. Processes include radon diffusion in both the gas and liquid phases, ... Keywords: Landfill, Multiphase, Performance assessment, Probabilistic modeling, Radium, Radon, Transport

Clifford K. Ho

2008-09-01T23:59:59.000Z

245

Int. J. Environment and Pollution, Vol. 8, Nos. 3-6, 1997 727 Gaseous pollutant dispersion around urban-canopy  

E-Print Network (OSTI)

. Meroney, 1983: Gas dispersion near a cubical model building. Part I. Mean concentration measurements. JInt. J. Environment and Pollution, Vol. 8, Nos. 3-6, 1997 727 Gaseous pollutant dispersion around numerical predictions of atmospheric dispersion in the urban environment on sub-meso scales. Wind

Fedorovich, Evgeni

246

Tests of Micro-Pattern Gaseous Detectors for Active1 Target Time Projection Chambers in nuclear physics2  

E-Print Network (OSTI)

Tests of Micro-Pattern Gaseous Detectors for Active1 Target Time Projection Chambers in nuclear the gas used as the detection medium10 is also a target for nuclear reactions, have been used for a wide variety of11 nuclear physics applications since the eighties. Improvements in MPGD (Mi-12 cro Pattern

Recanati, Catherine

247

Separation and recovery of hydrogen and normally gaseous hydrocarbons from net excess hydrogen from a catalytic reforming process  

Science Conference Proceedings (OSTI)

A process is disclosed for the catalytic reforming of hydrocarbons in the presence of hydrogen, preferably to produce high quality gasoline boiling range products. An improved recovery of normally gaseous hydrocarbons from the net excess hydrogen is realized by chilling and contacting said hydrogen with a normally liquid hydrocarbon stream in a plural stage absorption zone at an elevated pressure.

Scheifele, C.A.

1982-06-08T23:59:59.000Z

248

Polishing compound for plastic surfaces  

DOE Patents (OSTI)

A polishing compound for plastic surfaces. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains fine particles silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS.TM., LEXAN.TM., LUCITE.TM., polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired.

Stowell, Michael S. (New Ellenton, SC)

1995-01-01T23:59:59.000Z

249

Polishing compound for plastic surfaces  

DOE Patents (OSTI)

A polishing compound for plastic surfaces is disclosed. The compound contains by weight approximately 4 to 17 parts at least one petroleum distillate lubricant, 1 to 6 parts mineral spirits, 2.5 to 15 parts abrasive particles, and 2.5 to 10 parts water. The abrasive is tripoli or a similar material that contains colloidal silica. Preferably, most of the abrasive particles are less than approximately 10 microns, more preferably less than approximately 5 microns in size. The compound is used on PLEXIGLAS{sup TM}, LEXAN{sup TM}, LUCITE{sup TM}, polyvinyl chloride (PVC) and similar plastic materials whenever a smooth, clear polished surface is desired.

Stowell, M.S.

1993-01-01T23:59:59.000Z

250

Detection of chlorinated aromatic compounds  

SciTech Connect

A method for making a composition for measuring the concentration of chloated aromatic compounds in aqueous fluids, and an optical probe for use with the method. The composition comprises a hydrophobic polymer matrix, preferably polyamide, with a fluorescent indicator uniformly dispersed therein. The indicator fluoresces in the presence of the chlorinated aromatic compounds with an intensity dependent on the concentration of these compounds in the fluid of interest, such as 8-amino-2-naphthalene sulfonate. The probe includes a hollow cylindrical housing that contains the composition in its distal end. The probe admits an aqueous fluid to the probe interior for exposure to the composition. An optical fiber transmits excitation light from a remote source to the composition while the indicator reacts with chlorinated aromatic compounds present in the fluid. The resulting fluorescence light signal is reflected to a second optical fiber that transmits the light to a spectrophotometer for analysis.

Ekechukwu, Amy A. (Augusta, GA)

1996-01-01T23:59:59.000Z

251

COMBUSTION SOURCES OF NITROGEN COMPOUNDS  

E-Print Network (OSTI)

Rasmussen, R.A. (1976). Combustion as a source of nitrousx control for stationary combustion sources. Prog. Energy,CA, March 3-4, 1977 COMBUSTION SOURCES OF NITROGEN COMPOUNDS

Brown, Nancy J.

2011-01-01T23:59:59.000Z

252

Polishing compound for plastic surfaces  

DOE Patents (OSTI)

This invention is comprised of a polishing compound for plastic materials. The compound includes approximately by approximately by weight 25 to 80 parts at least one petroleum distillate lubricant, 1 to 12 parts mineral spirits, 50 to 155 parts abrasive paste, and 15 to 60 parts water. Preferably, the compound includes approximately 37 to 42 parts at least one petroleum distillate lubricant, up to 8 parts mineral spirits, 95 to 110 parts abrasive paste, and 50 to 55 parts water. The proportions of the ingredients are varied in accordance with the particular application. The compound is used on PLEXIGLAS{trademark}, LEXAN{trademark}, LUCITE{trademark}, polyvinyl chloride (PVC), and similar plastic materials whenever a smooth, clear polished surface is desired.

Stowell, M.S.

1991-01-01T23:59:59.000Z

253

Detection of chlorinated aromatic compounds  

DOE Patents (OSTI)

A method for making a composition for measuring the concentration of chlorinated aromatic compounds in aqueous fluids, and an optical probe for use with the method are disclosed. The composition comprises a hydrophobic polymer matrix, preferably polyamide, with a fluorescent indicator uniformly dispersed therein. The indicator fluoresces in the presence of the chlorinated aromatic compounds with an intensity dependent on the concentration of these compounds in the fluid of interest, such as 8-amino-2-naphthalene sulfonate. The probe includes a hollow cylindrical housing that contains the composition in its distal end. The probe admits an aqueous fluid to the probe interior for exposure to the composition. An optical fiber transmits excitation light from a remote source to the composition while the indicator reacts with chlorinated aromatic compounds present in the fluid. The resulting fluorescence light signal is reflected to a second optical fiber that transmits the light to a spectrophotometer for analysis. 5 figs.

Ekechukwu, A.A.

1996-02-06T23:59:59.000Z

254

Aza compounds as anion receptors  

SciTech Connect

A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of Li.sup.+ ion in alkali metal batteries.

Lee, Hung Sui (East Setauket, NY); Yang, Xiao-Qing (Port Jefferson Station, NY); McBreen, James (Bellport, NY)

1998-01-06T23:59:59.000Z

255

TREATMENT OF GASEOUS EFFLUENTS ISSUED FROM RECYCLING A REVIEW OF THE CURRENT PRACTICES AND PROSPECTIVE IMPROVEMENTS  

Science Conference Proceedings (OSTI)

The objectives of gaseous waste management for the recycling of nuclear used fuel is to reduce by best practical means (ALARA) and below regulatory limits, the quantity of activity discharged to the environment. The industrial PUREX process recovers the fissile material U(VI) and Pu(IV) to re-use them for the fabrication of new fuel elements e.g. recycling plutonium as a Mixed Oxide (MOX) fuel or recycling uranium for new enrichment for Pressurized Water Reactor (PWR). Meanwhile the separation of the waste (activation and fission product) is performed as a function of their pollution in order to store and avoid any potential danger and release towards the biosphere. Raffinate, that remains after the extraction step and which contains mostly all fission products and minor actinides is vitrified, the glass package being stored temporarily at the recycling plant site. Hulls and end pieces coming from PWR recycled fuel are compacted by means of a press leading to a volume reduced to 1/5th of initial volume. An organic waste treatment step will recycle the solvent, mainly tri-butyl phosphate (TBP) and some of its hydrolysis and radiolytic degradation products such as dibutyl phosphate (HDPB) and monobutyl phosphate (H2MBP). Although most scientific and technological development work focused on high level waste streams, a considerable effort is still under way in the area of intermediate and low level waste management. Current industrial practices for the treatment of gaseous effluents focusing essentially on Iodine-129 and Krypton-85 will be reviewed along with the development of novel technologies to extract, condition, and store these fission products. As an example, the current industrial practice is to discharge Kr-85, a radioactive gas, entirely to the atmosphere after dilution, but for the large recycling facilities envisioned in the near future, several techniques such as 1) cryogenic distillation and selective absorption in solvents, 2) adsorption on activated charcoal, 3) selective sorption on chemical modified zeolites, or 4) diffusion through membranes with selective permeability are potential technologies to retain the gas.

Patricia Paviet-Hartmann; William Kerlin; Steven Bakhtiar

2010-11-01T23:59:59.000Z

256

Impact of nitrate-enhanced leachate recirculation on gaseous releases from a landfill bioreactor cell  

SciTech Connect

This study evaluates the impact of nitrate injection on a full scale landfill bioreactor through the monitoring of gaseous releases and particularly N{sub 2}O emissions. During several weeks, we monitored gas concentrations in the landfill gas collection system as well as surface gas releases with a series of seven static chambers. These devices were directly connected to a gas chromatograph coupled to a flame ionisation detector and an electron capture detector (GC-FID/ECD) placed directly on the field. Measurements were performed before, during and after recirculation of raw leachate and nitrate-enhanced leachate. Raw leachate recirculation did not have a significant effect on the biogas concentrations (CO{sub 2}, CH{sub 4} and N{sub 2}O) in the gas extraction network. However, nitrate-enhanced leachate recirculation induced a marked increase of the N{sub 2}O concentrations in the gas collected from the recirculation trench (100-fold increase from 0.2 ppm to 23 ppm). In the common gas collection system however, this N{sub 2}O increase was no more detectable because of dilution by gas coming from other cells or ambient air intrusion. Surface releases through the temporary cover were characterized by a large spatial and temporal variability. One automated chamber gave limited standard errors over each experimental period for N{sub 2}O releases: 8.1 {+-} 0.16 mg m{sup -2} d{sup -1} (n = 384), 4.2 {+-} 0.14 mg m{sup -2} d{sup -1} (n = 132) and 1.9 {+-} 0.10 mg m{sup -2} d{sup -1} (n = 49), during, after raw leachate and nitrate-enhanced leachate recirculation, respectively. No clear correlation between N{sub 2}O gaseous surface releases and recirculation events were evidenced. Estimated N{sub 2}O fluxes remained in the lower range of what is reported in the literature for landfill covers, even after nitrate injection.

Tallec, G.; Bureau, C. [Cemagref, UR HBAN, Parc de Tourvoie, BP44, F-92163 Antony (France); Peu, P.; Benoist, J.C. [Cemagref, UR GERE, 17 Avenue de Cucille, CS 64427, F-35044 Rennes (France); Lemunier, M. [Suez-Environnement, CIRADE, 38 Av. Jean Jaures, 78440 Gargenville (France); Budka, A.; Presse, D. [SITA France, 132 Rue des 3 Fontanot, 92000 Nanterre Cedex (France); Bouchez, T. [Cemagref, UR HBAN, Parc de Tourvoie, BP44, F-92163 Antony (France)], E-mail: theodore.bouchez@cemagref.fr

2009-07-15T23:59:59.000Z

257

Calculation of releases of radioactive materials in gaseous and liquid effluents from pressurized water reactors (PWR-GALE Code). Revision 1  

SciTech Connect

This report revises the original issuance of NUREG-0017, ''Calculation of Releases of Radioactive Materials in Gaseous and Liquid Effluents from Pressurized Water Reactors (PWR-GALE-Code)'' (April 1976), to incorporate more recent operating data now available as well as the results of a number of in-plant measurement programs at operating pressurized water reactors. The PWR-GALE Code is a computerized mathematical model for calculating the releases of radioactive material in gaseous and liquid effluents (i.e., the gaseous and liquid source terms). The US Nuclear Regulatory Commission uses the PWR-GALE Code to determine conformance with the requirements of Appendix I to 10 CFR Part 50.

Chandrasekaran, T.; Lee, J.Y.; Willis, C.A.

1985-04-01T23:59:59.000Z

258

Mass transport of volatile organic compounds between the saturated and vadose zones. Master`s thesis  

Science Conference Proceedings (OSTI)

Volatile organic compounds (VOCs) dissolved in the saturated zone are transported into the vadose zone primarily by gaseous phase diffusion. If the saturated zone is remediated, VOCs present in the vadose zone may become a secondary source of contamination for the groundwater. The amount of VOCs that remain in the vadose zone is dependent on site hydrology, soil properties, and the chemical properties of the contaminants. The purpose of this study was to determine what conditions caused VOC concentrations in the vadose zone to significantly recontaminate the saturated zone. A one-dimensional numerical model was developed to investigate the transport of a VOC, trichioroethylene, between the saturated and vadose zones under a variety of conditions. The model featured steady-state unsaturated water flow and transient contaminant transport. Transport mechanisms included aqueous phase advection-dispersion and gaseous phase diffusion. Partitioning between the water, gas, and soil compartments were modeled as equilibrium processes. Sensitivity analyses were performed on several variables including soil type (homogeneous and heterogeneous profiles), water infiltration rate and vadose zone depth. Results indicated that recontamination was most significant rate, and vadose zone depth. Results indicated that recontamination was most significant in the presence of heterogeneous soils, low infiltration rates and deep vadose zones.

Harner, M.S.

1996-12-01T23:59:59.000Z

259

Method for purifying bidentate organophosphorus compounds  

DOE Patents (OSTI)

Bidentate organophosphorus compounds useful for extracting actinide elements from acidic nuclear waste solutions are purified of undesirable acidic impurities by contacting the compounds with ethylene glycol which preferentially extracts the impurities found in technical grade bidentate compounds.

Schulz, Wallace W. (Richland, WA)

1977-01-01T23:59:59.000Z

260

Six-dimensional muon beam cooling in a continuous, homogeneous, gaseous hydrogen absorber  

DOE Green Energy (OSTI)

The fast reduction of the six-dimensional phase space of muon beams is required for muon colliders and is also of great importance for neutrino factories based on accelerated muon beams. Ionization cooling, where all momentum components are degraded by an energy absorbing material and only the longitudinal momentum is restored by RF cavities, provides a means to quickly reduce transverse beam sizes. However, the beam momentum spread cannot be reduced by this method unless the longitudinal emittance can be transformed or exchanged into the transverse emittance. The best emittance exchange plans up to now have been accomplished by using magnets to disperse the beam along the face of a wedge-shaped absorber such that higher momentum particles pass through thicker parts of the absorber and thus suffer larger ionization energy loss. In the scheme advocated in this paper, it is noted that one can generate a magnetic channel filled with absorber where higher momentum corresponds to a longer path length and therefore larger ionization energy loss. Thus a homogeneous absorber, without any special edge shaping, can provide the desired emittance exchange. An attractive example of a cooling channel based on this principle involves the use of RF cavities filled with a continuous gaseous hydrogen absorber in a magnetic channel composed of a solenoidal field with superimposed helical transverse dipole, quadrupole, and octupole fields. The theory of this helical channel is described to support the analytical prediction of a million-fold reduction in phase space volume in a channel 150 m long.

Yaroslav Derbenev; Rolland P. Johnson

2004-10-01T23:59:59.000Z

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261

Environmental Survey preliminary report, Oak Ridge Gaseous Diffusion Plant, Oak Ridge, Tennessee  

SciTech Connect

This report presents the preliminary findings from the first phase of the Environmental Survey of the US Department of Energy's (DOE) Oak Ridge Gaseous Diffusion Plant (ORGDP) conducted March 14 through 25, 1988. The Survey is being conducted by an interdisciplinary team of environmental specialists, led and managed by the Office of Environment, Safety and Health's Office of Environmental Audit. Individual team components are being supplied by a private contractor. The objective of the Survey is to identify environmental risk associated with ORGDP. The Survey covers all environmental media and all areas of environmental regulation. It is being performed in accordance with the DOE Environmental Survey Manual. This phase of the Survey involves the review of existing site environmental data, observations of the operations carried on at ORGDP, and interviews with site personnel. The Survey team developed a Sampling and Analysis Plan to assist in further assessing certain of the environmental problems identified during is on-site activities. The Sampling and Analysis Plan will be executed by Idaho National Engineering Laboratory (INEL). When completed, the results will be incorporated into the ORGDP Survey findings for in inclusion into the Environmental Survey Summary Report. 120 refs., 41 figs., 74 tabs.

Not Available

1989-02-01T23:59:59.000Z

262

Corrosion behavior of stainless steel in solid oxide fuel cell simulated gaseous environment  

DOE Green Energy (OSTI)

Significant progress in reducing the operating temperature of solid oxide fuel cells (SOFC) from {approx}1000 C to {approx} 750 C may permit the replacement of currently used ceramic interconnects by metallic interconnects in planar SOFCs (PSOFC). The use of metallic interconnects will result in a substantial cost reduction of PSOFCs. The interconnects operate in severe gaseous environments, in which one side of the interconnect can be exposed to hydrogen and the other side to air or oxygen at temperatures up to 800 C. Similar environmental conditions can exist in devices used for separating hydrogen from CO after reforming methane and steam. Type 304 stainless steel was selected for this base line study aimed at understanding corrosion processes in dual gas environments. This paper discusses the oxidation resistance of 304 stainless steel exposed to a dual environment gas at 800 C. The dual environment consisted of air on one side of the specimen and 1% hydrogen in nitrogen on the other side. The surface characterization techniques used in this study were optical and scanning electron microscopy, as well as various x-ray techniques.

Ziomek-Moroz, M.; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Cramer, Stephen D.; Matthes, Steven A.; Bullard, Sophie J.; Dunning, John S.; Alman, David E.; Wilson, Rick D.; Singh, P.

2003-01-01T23:59:59.000Z

263

Gaseous Radiochemical Method for Registration of Ionizing Radiation and Its Possible Applications in Science and Industry  

E-Print Network (OSTI)

This work presents a new possibility of registration of ionizing radiation by the flowing gaseous radiochemical method (FGRM). The specified method uses the property of some solid crystalline lattice materials for a free emission of radioactive isotopes of inert gas atoms formed as a result of nuclear reactions. Generated in an ampoule of the detector, the radioactive inert gases are transported by a gas-carrier into the proportional gas counter of the flowing type, where the decay rate of the radioactive gas species is measured. This quantity is unequivocally related to the flux of particles (neutrons, protons, light and heavy ions) at the location of the ampoule. The method was used to monitor the neutron flux of the pulsed neutron target "RADEX" driven by the linear proton accelerator of INR RAS. Further progress of the FGRM may give rise to possible applications in nuclear physics, astrophysics and medicine, in the nondestructive control of fissionable materials, diagnostics of thermonuclear plasma, monitoring of fluxes and measurement of spectra of bombarding particles.

S. G. Lebedev; V. E. Yants

2005-10-06T23:59:59.000Z

264

Report on the biological monitoring program at Paducah Gaseous Diffusion Plant December 1993 to December 1994  

SciTech Connect

On September 24, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous Diffusion Plant (PGDP). The PGDP BMP was implemented in 1987 by the University of Kentucky. Research staff of the Environmental Sciences Division (ESD) at Oak Ridge National Laboratory (ORNL) served as reviewers and advisers to the University of Kentucky. Beginning in fall 1991, ESD added data collection and report preparation to its responsibilities for the PGDP BMP. The goals of BMP are to (1) demonstrate that the effluent limitations established for PGDP protect and maintain the use of Little Bayou and Big Bayou creeks for growth and propagation of fish and other aquatic life, (2) characterize potential environmental impacts, (3) document the effects of pollution abatement facilities on stream biota, and (4) recommend any program improvements that would increase effluent treatability. In September 1992, a renewed Kentucky Pollutant Discharge Elimination System (KPDES) permit was issued to PGDP. The BMP for PGDP consists of three major tasks: (1) effluent and ambient toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of stream communities (i.e., benthic macroinvertebrates and fish). This report includes ESD activities occurring from December 1993 to December 1994, although activities conducted outside this time period are included as appropriate.

Kszos, L.A. [ed.

1996-05-01T23:59:59.000Z

265

Report on the biological monitoring program at Paducah Gaseous Diffusion Plant, January--December 1996  

Science Conference Proceedings (OSTI)

On September 24, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous diffusion Plant (PGDP). The PGDP BMP was conducted by the University of Kentucky Between 1987 and 1992 and by staff of the Environmental Sciences Division (ESD) at Oak Ridge National Laboratory (ORNL) from 1991 to present. The goals of BMP are to (1) demonstrate that the effluent limitations established for PGDP protect and maintain the use of Little Bayou and Big Bayou creeks for growth and propagation of fish and other aquatic life, (2) characterize potential environmental impacts, and (3) document the effects of pollution abatement facilities on stream. The BMP for PGDP consists of three major tasks: (1) effluent toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of stream communities (i.e., benthic macroinvertebrates and fish). This report focuses on ESD activities occurring from January 1996 to December 1996, although activities conducted outside this time period are included as appropriate.

Kszos, L.A. [ed.; Konetsky, B.K.; Peterson, M.J.; Petrie, R.B.; Ryon, M.G.; Smith, J.G.; Southworth, G.R.

1997-06-01T23:59:59.000Z

266

IAEA Verification Experiment at the Portsmouth Gaseous Diffusion Plant: Report on the Cascade Header Enrichment Monitor  

SciTech Connect

The authors describe the Cascade Header Enrichment Monitor (CHEM) for the Portsmouth Gaseous Diffusion Plant at Piketon, Ohio, and present the calibration and measurement results. The US government has offered excess fissile material that is no longer needed for defense purposes for International Atomic Energy Agency (IAEA) inspection. Measurement results provided by the CHEM were used by the IAEA in a verification experiment to provide confidence that the US successfully blended excess highly enriched uranium (HEU) down to low enriched uranium (LEU). The CHEM measured the uranium enrichment in two cascade header pipes, a 20.32-cm HEU pipe and a 7.62-cm product LEU pipe. The CHEM determines the amount of {sup 235}U from the 185.7-keV gamma-ray photopeak and the amount of total uranium by x-ray fluorescence (XRF) of the 98.4-keV x-ray from uranium with a {sup 57}Co XRF source. The ratio yields the enrichment. The CHEM consists of a collimator assembly, an electromechanically cooled germanium detector, and a rack-mounted personal computer running commercial and custom software. The CHEM was installed in December 1997 and was used by the IAEA inspectors for announced and unannounced inspections on the HEU and LEU header pipes through October 1998. The equipment was sealed with tamper-indicating enclosures when the inspectors were not present.

P. L. Kerr; D. A. Close; W. S. Johnson; R. M. Kandarian; C. E. Moss; C. D. Romero

1999-03-01T23:59:59.000Z

267

Radioactivity discharged in gaseous wastes from separations facilities 200 Area stacks during 1970  

SciTech Connect

This document summarizes by stack number the amount of radioactivity discharged from the facilities of Chemical Processing Division, Atlantic Richfield Hanford Company. Emission data for 231-Z Building and 2724-W, Laundry Building, which are operated by other AEC Contractors are not available for this report. Total beta, alpha and I{sup l3l} radioactive emissions from the stacks for 1970 were as follows: alpha (Pu, assumed) 1.59 {times} 10{sup {minus}1} C, alpha (U, assumed) 1.44 {times} 10{sup {minus}3} C, beta 1.93C, and I{sup 131} 4.92 {times} 10{sup {minus}1} C. Air samples taken continuously from gaseous release facilities were analyzed for total beta and alpha activity (and iodine activity, where applicable). Where sample data were not available, the total radioactive emission was adjusted by using the average emission rate prior to the subject period; or where activity was near constant, by using the daily average as a base. A gamma scan of the 291-S stack is included in the report.

Maxfield, H.L.

1971-03-29T23:59:59.000Z

268

Design and reliability optimization of a MEMS micro-hotplate for combustion of gaseous fuel  

SciTech Connect

This report will detail the process by which the silicon carbide (SiC) microhotplate devices, manufactured by GE, were imaged using IR microscopy equipment available at Sandia. The images taken were used as inputs to a finite element modeling (FEM) process using the ANSYS software package. The primary goal of this effort was to determine a method to measure the temperature of the microhotplate. Prior attempts to monitor the device's temperature by measuring its resistance had proven to be unreliable due to the nonlinearity of the doped SiC's resistance with temperature. As a result of this thermal modeling and IR imaging, a number of design recommendations were made to facilitate this temperature measurement. The lower heating value (LHV) of gaseous fuels can be measured with a catalyst-coated microhotplate calorimeter. GE created a silicon carbide (SiC) based microhotplate to address high-temperature survivability requirements for the application. The primary goal of this effort was to determine a method to measure the temperature of the microhotplate. Prior attempts to monitor the device's temperature by measuring its resistance had proven to be unreliable due to the non-linearity of the doped SiC's resistance with temperature. In this work, thermal modeling and IR imaging were utilized to determine the operation temperature as a function of parameters such as operation voltage and device sheet resistance. A number of design recommendations were made according to this work.

Manginell, R. P.

2012-03-01T23:59:59.000Z

269

An Aerial Radiological Survey of the Portsmouth Gaseous Diffusion Plant and Surrounding Area, Portsmouth, Ohio  

SciTech Connect

An aerial radiological survey was conducted over the 16 square-mile (~41 square-kilometer) area surrounding the Portsmouth Gaseous Diffusion Plant. The survey was performed in August 2007 utilizing a large array of helicopter mounted sodium iodide detectors. The purpose of the survey was to update the previous radiological survey levels of the environment and surrounding areas of the plant. A search for a missing radium-226 source was also performed. Implied exposure rates, man-made activity, and excess bismuth-214 activity, as calculated from the aerial data are presented in the form of isopleth maps superimposed on imagery of the surveyed area. Ground level and implied aerial exposure rates for nine specific locations are compared. Detected radioisotopes and their associated gamma ray exposure rates were consistent with those expected from normal background emitters. At specific plant locations described in the report, man-made activity was consistent with the operational histories of the location. There was no spectral activity that would indicate the presence of the lost source.

Namdoo Moon

2007-12-01T23:59:59.000Z

270

Uranium Compounds and Other Natural Radioactivities  

NLE Websites -- All DOE Office Websites (Extended Search)

X-ray Science Division XSD Groups Industry Argonne Home Advanced Photon Source Uranium Compounds and Other Natural Radioactivities Uranium containing compounds and other...

271

compound queries | OpenEI Community  

Open Energy Info (EERE)

- 15:22 Multicolor Maps from Compound Queries ask queries compound queries developer Google maps maps multicolor result formats results Semantic Mediawiki Hi all, Recently, a...

272

Independent Oversight Review of Preparedness for Severe Natural Phenomena Events at the Portsmouth Gaseous Diffusion Plant, November 2013  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

of of Preparedness for Severe Natural Phenomena Events at the Portsmouth Gaseous Diffusion Plant May 2011 November 2013 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose................................................................................................................................................ 1 2.0 Scope................................................................................................................................................... 1 3.0 Background ......................................................................................................................................... 1 4.0 Methodology ....................................................................................................................................... 2

273

Gaseous dry deposition of atmospheric mercury: A comparison of two surface resistance models for deposition to semiarid vegetation  

Science Conference Proceedings (OSTI)

In the United States, atmospheric mercury (Hg) deposition, from regional and international sources, is the largest contributor to increased Hg concentrations in bodies of water leading to bioaccumulation of methyl mercury in fish. In this work, modeled dry deposition velocities (vd) for gaseous Hg are calculated using two surface resistance parameterizations found in the literature. The flux is then estimated as the product of the species concentration and modeled vd. The calculations utilize speciated atmospheric mercury concentrations measured during an annual monitoring campaign in southern Idaho. Gaseous elemental mercury (GEM) and reactive gaseous mercury (RGM) were monitored with Tekran models 2537A and 1130, respectively. Two anemometers collected meteorological data, including one fast-response three-dimensional sonic anemometer to measure turbulence parameters. For the flux calculation, three resistances are required to model the mechanisms that transport gaseous Hg from the atmosphere to the surface, with the surface resistance being the largest source of error. Results from two surface resistance models are presented. In particular, the downward flux is sensitive to the choice of model and input parameters such as seasonal category and mesophyll resistance. A comparison of annual GEM and RGM fluxes calculated using the two models shows good agreement for RGM (3.2% difference for annual deposition); however, for the low-solubility species of GEM, the models show a 64% difference in annual fluxes, with a range of 32% to 200% in seasonal fluxes. Results indicate the importance of understanding the diurnal variation of the physical processes modeled in the surface resistance parameterization for vd.

Heather A. Holmes; Eric R. Pardyjak; Kevin D. Perry; Michael L. Abbott

2011-07-01T23:59:59.000Z

274

Review of the Portsmouth Gaseous Diffusion Plant Work Planning and Control Activities Prior to Work Execution, January 2013  

NLE Websites -- All DOE Office Websites (Extended Search)

Independent Oversight Review of the Independent Oversight Review of the Portsmouth Gaseous Diffusion Plant Work Planning and Control Activities Prior to Work Execution January 2013 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose ................................................................................................................................................. 1 2.0 Scope.................................................................................................................................................... 1 3.0 Background........................................................................................................................................... 1

275

PAndAS IN THE MIST: THE STELLAR AND GASEOUS MASS WITHIN THE HALOS OF M31 AND M33  

SciTech Connect

Large-scale surveys of the prominent members of the Local Group have provided compelling evidence for the hierarchical formation of massive galaxies, revealing a wealth of substructure that is thought to be the debris from ancient and ongoing accretion events. In this paper, we compare two extant surveys of the M31-M33 subgroup of galaxies: the Pan-Andromeda Archaeological Survey of the stellar structure, and a combination of observations of the H I gaseous content, detected at 21 cm. Our key finding is a marked lack of spatial correlation between these two components on all scales, with only a few potential overlaps between stars and gas. The paucity of spatial correlation significantly restricts the analysis of kinematic correlations, although there does appear to be H I kinematically associated with the Giant Stellar Stream where it passes the disk of M31. These results demonstrate that different processes must significantly influence the dynamical evolution of the stellar and H I components of substructures, such as ram pressure driving gas away from a purely gravitational path. Detailed modeling of the offset between the stellar and gaseous substructures will provide a determination of the properties of the gaseous halos of M31 and M33.

Lewis, Geraint F. [Sydney Institute for Astronomy, School of Physics A28, The University of Sydney, NSW 2006 (Australia)] [Sydney Institute for Astronomy, School of Physics A28, The University of Sydney, NSW 2006 (Australia); Braun, Robert [CSIRO Astronomy and Space Science, P.O. Box 76, Epping, NSW 1710 (Australia)] [CSIRO Astronomy and Space Science, P.O. Box 76, Epping, NSW 1710 (Australia); McConnachie, Alan W. [Dominion Astrophysical Observatory, 5071 West Saanich Road, Victoria, BC V9E 2E7 (Canada)] [Dominion Astrophysical Observatory, 5071 West Saanich Road, Victoria, BC V9E 2E7 (Canada); Irwin, Michael J.; Chapman, Scott C. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom)] [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom); Ibata, Rodrigo A.; Martin, Nicolas F. [Observatoire de Strasbourg, 11, rue de l'Universite, F-67000 Strasbourg (France)] [Observatoire de Strasbourg, 11, rue de l'Universite, F-67000 Strasbourg (France); Ferguson, Annette M. N. [Institute for Astronomy, University of Edinburgh, Blackford Hill, Edinburgh EH9 3HJ (United Kingdom)] [Institute for Astronomy, University of Edinburgh, Blackford Hill, Edinburgh EH9 3HJ (United Kingdom); Fardal, Mark [Department of Astronomy, University of Massachusetts, Amherst, MA 01003-9305 (United States)] [Department of Astronomy, University of Massachusetts, Amherst, MA 01003-9305 (United States); Dubinski, John [Department of Astronomy and Astrophysics, 50 St. George Street, University of Toronto, ON M5S 3H4 (Canada)] [Department of Astronomy and Astrophysics, 50 St. George Street, University of Toronto, ON M5S 3H4 (Canada); Widrow, Larry [Department of Physics, Queen's University, 99 University Avenue, Kingston, ON K7L 3N6 (Canada)] [Department of Physics, Queen's University, 99 University Avenue, Kingston, ON K7L 3N6 (Canada); Mackey, A. Dougal [Research School of Astronomy and Astrophysics, Mount Stromlo Observatory, Cotter Road, Weston Creek, ACT 2611 (Australia)] [Research School of Astronomy and Astrophysics, Mount Stromlo Observatory, Cotter Road, Weston Creek, ACT 2611 (Australia); Babul, Arif [Department of Physics and Astronomy, University of Victoria, Victoria, BC V8W 3P6 (Canada)] [Department of Physics and Astronomy, University of Victoria, Victoria, BC V8W 3P6 (Canada); Tanvir, Nial R. [Department of Physics and Astronomy, University of Leicester, Leicester LE1 7RH (United Kingdom)] [Department of Physics and Astronomy, University of Leicester, Leicester LE1 7RH (United Kingdom); Rich, Michael, E-mail: geraint.lewis@sydney.edu.au [Division of Astronomy, University of California, 8979 Math Sciences, Los Angeles, CA 90095-1562 (United States)] [Division of Astronomy, University of California, 8979 Math Sciences, Los Angeles, CA 90095-1562 (United States)

2013-01-20T23:59:59.000Z

276

Summary and Outlook of the International Workshop on Aging Phenomena in Gaseous Detectors (DESY, Hamburg, October, 2001)  

E-Print Network (OSTI)

High Energy Physics experiments are currently entering a new era which requires the operation of gaseous particle detectors at unprecedented high rates and integrated particle fluxes. Full functionality of such detectors over the lifetime of an experiment in a harsh radiation environment is of prime concern to the involved experimenters. New classes of gaseous detectors such as large-scale straw-type detectors, Micro-pattern Gas Detectors and related detector types with their own specific aging effects have evolved since the first workshop on wire chamber aging was held at LBL, Berkeley in 1986. In light of these developments and as detector aging is a notoriously complex field, the goal of the workshop was to provide a forum for interested experimentalists to review the progress in understanding of aging effects and to exchange recent experiences. A brief summary of the main results and experiences reported at the 2001 workshop is presented, with the goal of providing a systematic review of aging effects in state-of-the-art and future gaseous detectors.

M. Titov; M. Hohlmann; C. Padilla; N. Tesch

2002-04-04T23:59:59.000Z

277

Long-Term Behavior of the Tritides Formed by Nickel-Based Intermetallic Compounds  

SciTech Connect

Some properties of the tritide phases formed by the intermetallic compounds Mg2Ni, ZrNi, and LaNi5 have been studied. Whereas ZrNiT3 will retain its stoichiometry indefinitely when sufficient gaseous tritium is available, the stoichiometries of Mg2NiT4 and LaNi5T6.9 decrease with time. Although all three intermetallic tritides can retain large quantities of the helium-3 tritium decay daughter product in the solid phase, irreversible release of helium begins after several hundred days for ZrNiTx and Mg2NiTx. However, LaNi5Tx retains all of the helium generated in the solid for at least 2400 days. NMR measurements for ZrNiTx and Mg2NiTx imply that helium is retained in microscopic bubbles as previously observed in several binary metal tritides.

Bowman, Jr., R. C.; Steinmeyer, R. H.; Matson, L. K.; Attalla, A.; Craft, B. D.

1985-04-01T23:59:59.000Z

278

Method for selectively removing fluorine and fluorine-containing contaminants from gaseous UF/sub 6/. [ClF/sub 3/  

DOE Patents (OSTI)

This invention is a method for effecting preferential removal and immobilization of certain gaseous contaminants from gaseous UF/sub 6/. The contaminants include fluorine and fluorides which are more reactive with CaCO/sub 3/ than is UF/sub 6/. The method comprises contacting the contaminant-carrying UF/sub 6/ with particulate CaCO/sub 3/ at a temperature effecting reaction of the contaminant and the CaCO/sub 3/.

Jones, R.L.; Otey, M.G.; Perkins, R.W.

1980-11-24T23:59:59.000Z

279

Prioritizing and scheduling Portsmouth Gaseous Diffusion Plant safeguards upgrades. Final report  

Science Conference Proceedings (OSTI)

As part of the Site Safeguards and Security Plan (SSSP), facilities are required to develop a Resource Plan (RP). The Resource Plan provides documentation and justification for the facility`s planned upgrades, including the schedule, priority, and cost estimates for the safeguards and security upgrades. Portsmouth Gaseous Diffusion Plant (PORTS) management has identified and obtained funding approval for a number of safeguards and security upgrades, including line-item construction projects. These upgrade projects were selected to address a variety of concerns identified in the PORTS vulnerability assessments and other reviews performed in support of the SSSP process. However, budgeting and scheduling constraints do not make it possible to simultaneously begin implementation of all of the upgrade projects. A formal methodology and analysis are needed to explicitly address the trade-offs between competing safeguards objectives, and to prioritize and schedule the upgrade projects to ensure that the maximum benefit can be realized in the shortest possible time frame. The purpose of this report is to describe the methodology developed to support these upgrade project scheduling decisions. The report also presents the results obtained from applying the methodology to a set of the upgrade projects selected by PORTS S&S management. Data for the analysis are based on discussions with personnel familiar with the PORTS safeguards and security needs, the requirements for implementing these upgrades, and upgrade funding limitations. The analysis results presented here assume continued highly enriched uranium (HEU) operations at PORTS. However, the methodology developed is readily adaptable for the evaluation of other operational scenarios and other resource allocation issues relevant to PORTS.

Edmunds, T.; Saleh, R.; Zevanove, S.

1992-02-01T23:59:59.000Z

280

Uranium hexafluoride packaging tiedown systems overview at Portsmouth Gaseous Diffusion Plant, Piketon, Ohio. Revision 1  

SciTech Connect

The Portsmouth Gaseous Diffusion Plant (PORTS) in Piketon, Ohio, is operated by Martin Marietta Energy Systems, Inc., through the US Department of Energy-Oak Ridge Operations Office (DOE-ORO) for the US Department of Energy-Headquarters, Office of Nuclear Energy. The PORTS conducts those operations that are necessary for the production, packaging, and shipment of uranium hexafluoride (UF{sub 6}). Uranium hexafluoride enriched uranium than 1.0 wt percent {sup 235}U shall be packaged in accordance with the US Department of Transportation (DOT) regulations of Title 49 CFR Parts 173 (Reference 1) and 178 (Reference 2), or in US Nuclear Regulatory Commission (NRC) or US Department of Energy (DOE) certified package designs. Concerns have been expressed regarding the various tiedown methods and condition of the trailers being used by some shippers/carriers for international transport of the UF{sub 6} cylinders/overpacks. Because of the concerns about international shipments, the US Department of Energy-Headquarters (DOE-HQ) Office of Nuclear Energy, through DOE-HQ Transportation Management Division, requested Westinghouse Hanford Company (Westinghouse Hanford) to review UF{sub 6} packaging tiedown and shipping practices used by PORTS, and where possible and appropriate, provide recommendations for enhancing these practices. Consequently, a team of two individuals from Westinghouse Hanford visited PORTS on March 5 and 6, 1990, for the purpose of conducting this review. The paper provides a brief discussion of the review activities and a summary of the resulting findings and recommendations. A detailed reporting of the is documented in Reference 4.

Becker, D.L.; Green, D.J.; Lindquist, M.R.

1993-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Modifying woody plants for efficient conversion to liquid and gaseous fuels  

DOE Green Energy (OSTI)

The Short Rotation Woody Crop Program (SRWCP), Department of Energy, is developing woody plant species as sources of renewable energy. Much progress has been made in identifying useful species, and testing site adaptability, stand densities, coppicing abilities, rotation lengths, and harvesting systems. Conventional plant breeding and intensive cultural practices have been used to increase above-ground biomass yields. Given these and foreseeable accomplishments, program leaders are now shifting attention to prospects for altering biomass physical and chemical characteristics, and to ways for improving the efficiency with which biomass can be converted to gaseous and liquid fuels. This report provides a review and synthesis of literature concerning the quantity and quality of such characteristics and constituents, and opportunities for manipulating them via conventional selection and breeding and/or molecular biology. Species now used by SRWCP are emphasized, with supporting information drawn from others as needed. Little information was found on silver maple (Acer saccharinum), but general comparisons (Isenberg 1981) suggest composition and behavior similar to those of the other species. Where possible, conclusions concerning means for and feasibility of manipulation are given, along with expected impacts on conversion efficiency. Information is also provided on relationships to other traits, genotype X environment interactions, and potential trade-offs or limitations. Biomass productivity per se is not addressed, except in terms of effects that may by caused by changes in constituent quality and/or quantity. Such effects are noted to the extent they are known or can be estimated. Likely impacts of changes, however effected, on suitability or other uses, e.g., pulp and paper manufacture, are notes. 311 refs., 4 figs., 9 tabs.

Dinus, R.J.; Dimmel, D.R.; Feirer, R.P.; Johnson, M.A.; Malcolm, E.W. (Institute of Paper Science and Technology, Atlanta, GA (USA))

1990-07-01T23:59:59.000Z

282

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 figures.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1993-09-07T23:59:59.000Z

283

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a molecular sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1994-06-14T23:59:59.000Z

284

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C[sub 2] to C[sub 10] olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80 C to 500 C, using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms. 1 fig.

Smith, L.A. Jr.

1989-07-18T23:59:59.000Z

285

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene to about the mid point of the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1993-01-01T23:59:59.000Z

286

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1994-01-01T23:59:59.000Z

287

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a catalytic distillation, wherein the catalyst structure also serves as a distillation component by contacting the aromatic compound with a C.sub.2 to C.sub.10 olefin in the catalyst bed under 0.25 to 50 atmospheres of pressure and at temperatures in the range of 80.degree. C. to 500.degree. C., using as the catalyst a mole sieve characterized as acidic or an acidic cation exchange resin. For example, ethyl benzene is produced by feeding ethylene below the catalyst bed while benzene is conveniently added through the reflux in molar excess to that required to react with ethylene, thereby reacting substantially all of the ethylene and recovering benzene as the principal overhead and ethyl benzene in the bottoms.

Smith, Jr., Lawrence A. (Houston, TX)

1989-01-01T23:59:59.000Z

288

Design of an Unattended Environmental Aerosol Sampling and Analysis System for Gaseous Centrifuge Enrichment Plants  

Science Conference Proceedings (OSTI)

The resources of the IAEA continue to be challenged by the rapid, worldwide expansion of nuclear energy production. Gaseous centrifuge enrichment plants (GCEPs) represent an especially formidable dilemma to the application of safeguard measures, as the size and enrichment capacity of GCEPs continue to escalate. During the early part of the 1990's, the IAEA began to lay the foundation to strengthen and make cost-effective its future safeguard regime. Measures under Part II of 'Programme 93+2' specifically sanctioned access to nuclear fuel production facilities and environmental sampling by IAEA inspectors. Today, the Additional Protocol grants inspection and environmental sample collection authority to IAEA inspectors at GCEPs during announced and low frequency unannounced (LFUA) inspections. During inspections, IAEA inspectors collect environmental swipe samples that are then shipped offsite to an analytical laboratory for enrichment assay. This approach has proven to be an effective deterrence to GCEP misuse, but this method has never achieved the timeliness of detection goals set forth by IAEA. Furthermore it is questionable whether the IAEA will have the resources to even maintain pace with the expansive production capacity of the modern GCEP, let alone improve the timeliness in reaching current safeguards conclusions. New safeguards propositions, outside of familiar mainstream safeguard measures, may therefore be required that counteract the changing landscape of nuclear energy fuel production. A new concept is proposed that offers rapid, cost effective GCEP misuse detection, without increasing LFUA inspection access or introducing intrusive access demands on GCEP operations. Our approach is based on continuous onsite aerosol collection and laser enrichment analysis. This approach mitigates many of the constraints imposed by the LFUA protocol, reduces the demand for onsite sample collection and offsite analysis, and overcomes current limitations associated with the in-facility misuse detection devices. Onsite environmental sample collection offers the ability to collect fleeting uranium hexafluoride emissions before they are lost to the ventilation system or before they disperse throughout the facility, to become deposited onto surfaces that are contaminated with background and historical production material. Onsite aerosol sample collection, combined with enrichment analysis, provides the unique ability to quickly detect stepwise enrichment level changes within the facility, leading to a significant strengthening of facility misuse deterence. We report in this paper our study of several GCEP environmental sample release scenarios and simulation results of a newly designed aerosol collection and particle capture system that is fully integrated with the Laser Ablation, Absorbance Ratio Spectrometry (LAARS) uranium particle enrichment analysis instrument that was developed at the Pacific Northwest National Laboratory.

Anheier, Norman C.; Munley, John T.; Alexander, M. L.

2011-07-19T23:59:59.000Z

289

Advanced Laser Diagnostics Development for the Characterization of Gaseous High Speed Flows  

E-Print Network (OSTI)

The study of high-speed flows represents a challenging problem in the fluid dynamics field due to the presence of chemical reactions and non-equilibrium effects. Hypersonic flights, where speeds reach Mach 5 and above, are particularly influenced by these effects, resulting in a direct impact on the flow and consequently on the aerodynamic performance of a vehicle traveling at these speeds. The study of hypersonic flow conditions requires the experimental capability of determining local temperatures, pressures and velocities using non-intrusive techniques. Furthermore, the simultaneous measurement of two or more variables in a complex flow boosts the amount of information that is obtained since valuable correlations can be established. This research includes the design, construction and characterization of a hypersonic flow apparatus explicitly intended as a tool for advanced laser diagnostics development. This apparatus is characterized by its pulsed operation mode that translates into a significant reduction in mass flow rates and can be operated for long periods at Mach numbers ranging from 2.8 to 6.2. The flow conditions during the uniform flow time interval of each pulse vary by less than 1%, generating a flow of sufficient quality for quantitative measurements. The development of a laser diagnostic technique, the VENOM technique, which is a non-intrusive method to provide simultaneous 2-D measurements of the mean and instantaneous fluctuations in two-component velocity and temperature is also presented. This technique represents the first single diagnostic capable of instantaneous two-component velocimetry and thermometry in a gaseous flow field by combining two Nitric Oxide Planar Laser Induced Fluorescence methods: two-component Molecular Tagging Velocimetry and two-line thermometry, employing the nascent NO(v"=1) arising from the NO2 photodissociation as a molecular tracer. The VENOM technique is expected to be not only applicable to cold high-speed flows, which is the focus of the present work, but also to combustion and other reactive or high-enthalpy flow fields.

Sanchez-Gonzalez, Rodrigo

2012-05-01T23:59:59.000Z

290

Potential Hazards Relating to Pyrolysis of c-C{sub 4}F{sub 8}O, n-C{sub 4}F{sub 10}, and c-C{sub 4}F{sub 8} in Selected Gaseous Diffusion Plant Operations  

SciTech Connect

As part of a program intended to replace the present evaporative coolant at the gaseous diffusion plants (GDPs) with a non-ozone-depleting alternate, a series of investigations of the suitability of candidate substitutes is under way. This report summarizes studies directed at estimating the chemical and thermal stability of three candidate coolants, c-C{sub 4}F{sub 8}, n-C{sub 4}F{sub 10}, and c-C{sub 4}F{sub 8}O, in a few specific environments to be found in gaseous diffusion plant operations. One issue concerning the new coolants is the possibility that they might produce the highly toxic compound perfluoroisobutylene (PFIB) in high-temperature environments. Two specific high-temperature thermal environments are examined, namely the use of a flame test for the presence of coolant vapors and welding in the presence of coolant vapors. A second issue relates to the thermal or chemical decomposition of the coolants in the gaseous diffusion process environment. The primary purpose of the study was to develop and evaluate available data to provide information that will allow the technical and industrial hygiene staff at the GDPs to perform appropriate safety evaluations and to determine the need for field testing or experimental work. The scope of this study included a literature search and an evaluation of the information developed therefrom. Part of that evaluation consists of chemical kinetics modeling of coolant decomposition in the two operational environments. The general conclusions are that PFIB formation is unlikely in either situation but that it cannot be ruled out completely under extreme conditions. The presence of oxygen, moisture, and combustion products will tend to lead to the formation of CF{sub 4} and oxidation products (COF{sub 2}, CO, CO{sub 2}, and HF) rather than PFIB.

Trowbridge, L.D.

2000-03-29T23:59:59.000Z

291

Feedback Capacity of the Compound Channel  

E-Print Network (OSTI)

In this work, we find the capacity of a compound finite-state channel (FSC) with time-invariant deterministic feedback. We consider the use of fixed length block codes over the compound channel. Our achievability result ...

Shrader, Brooke E.

292

The Radiochemical Analysis of Gaseous Samples (RAGS) apparatus for nuclear diagnostics at the National Ignition Facility (invited)  

SciTech Connect

The Radiochemical Analysis of Gaseous Samples (RAGS) diagnostic apparatus was recently installed at the National Ignition Facility (NIF). Following a NIF shot, RAGS is used to pump the gas load from the NIF chamber for purification and isolation of the noble gases. After collection, the activated gaseous species are counted via gamma spectroscopy for measurement of the capsule areal density and fuel-ablator mix. Collection efficiency was determined by injecting a known amount of {sup 135}Xe into the NIF chamber, which was then collected with RAGS. Commissioning was performed with an exploding pusher capsule filled with isotopically enriched {sup 124}Xe and {sup 126}Xe added to the DT gas fill. Activated xenon species were recovered post-shot and counted via gamma spectroscopy. Results from the collection and commissioning tests are presented. The performance of RAGS allows us to establish a noble gas collection method for measurement of noble gas species produced via neutron and charged particle reactions in a NIF capsule.

Shaughnessy, D. A.; Velsko, C. A.; Jedlovec, D. R.; Yeamans, C. B.; Moody, K. J.; Tereshatov, E.; Stoeffl, W.; Riddle, A. [Lawrence Livermore National Laboratory, PO Box 808, L-236, Livermore, California 94551 (United States)

2012-10-15T23:59:59.000Z

293

The Compound Capacity of Polar Codes  

E-Print Network (OSTI)

We consider the compound capacity of polar codes under successive cancellation decoding for a collection of binary-input memoryless output-symmetric channels. By deriving a sequence of upper and lower bounds, we show that in general the compound capacity under successive decoding is strictly smaller than the unrestricted compound capacity.

Hassani, S Hamed; Urbanke, Ruediger

2009-01-01T23:59:59.000Z

294

Thin films of mixed metal compounds  

DOE Patents (OSTI)

A compositionally uniform thin film of a mixed metal compound is formed by simultaneously evaporating a first metal compound and a second metal compound from independent sources. The mean free path between the vapor particles is reduced by a gas and the mixed vapors are deposited uniformly. The invention finds particular utility in forming thin film heterojunction solar cells.

Mickelsen, Reid A. (Bellevue, WA); Chen, Wen S. (Seattle, WA)

1985-01-01T23:59:59.000Z

295

ENZYME ACTIVITY PROBE AND GEOCHEMICAL ASSESSMENT FOR POTENTIAL AEROBIC COMETABOLISM OF TRICHLOROETHENE IN GROUNDWATER OF THE NORTHWEST PLUME, PADUCAH GASEOUS DIFFUSION PLANT, KENTUCKY  

Science Conference Proceedings (OSTI)

The overarching objective of the Paducah Gaseous Diffusion Plant (PGDP) enzyme activity probe (EAP) effort is to determine if aerobic cometabolism is contributing to the attenuation of trichloroethene (TCE) and other chlorinated solvents in the contaminated groundwater beneath PGDP. The site-specific objective for the EAP assessment is to identify if key metabolic pathways are present and expressed in the microbial community--namely the pathways that are responsible for degradation of methane and aromatic (e.g. toluene, benzene, phenol) substrates. The enzymes produced to degrade methane and aromatic compounds also break down TCE through a process known as cometabolism. EAPs directly measure if methane and/or aromatic enzyme production pathways are operating and, for the aromatic pathways, provide an estimate of the number of active organisms in the sampled groundwater. This study in the groundwater plumes at PGDP is a major part of a larger scientific effort being conducted by Interstate Technology and Regulatory Council (ITRC), U.S. Department of Energy (DOE) Office of Environmental Management (EM), Savannah River National Laboratory (SRNL), and North Wind Inc. in which EAPs are being applied to contaminated groundwater from diverse hydrogeologic and plume settings throughout the U.S. to help standardize their application as well as their interpretation. While EAP data provide key information to support the site specific objective for PGDP, several additional lines of evidence are being evaluated to increase confidence in the determination of the occurrence of biodegradation and the rate and sustainability of aerobic cometabolism. These complementary efforts include: (1) Examination of plume flowpaths and comparison of TCE behavior to 'conservative' tracers in the plume (e.g., {sup 99}Tc); (2) Evaluation of geochemical conditions throughout the plume; and (3) Evaluation of stable isotopes in the contaminants and their daughter products throughout the plume. If the multiple lines of evidence support the occurrence of cometabolism and the potential for the process to contribute to temporal and spatial attenuation of TCE in PGDP groundwater, then a follow-up enzyme probe microcosm study to better estimate biological degradation rate(s) is warranted.

Looney, B; M. Hope Lee, M; S. K. Hampson, S

2008-06-27T23:59:59.000Z

296

Thin films of mixed metal compounds  

DOE Patents (OSTI)

Disclosed is a thin film heterojunction solar cell, said heterojunction comprising a p-type I-III-IV[sub 2] chalcopyrite substrate and an overlying layer of an n-type ternary mixed metal compound wherein said ternary mixed metal compound is applied to said substrate by introducing the vapor of a first metal compound to a vessel containing said substrate from a first vapor source while simultaneously introducing a vapor of a second metal compound from a second vapor source of said vessel, said first and second metals comprising the metal components of said mixed metal compound; independently controlling the vaporization rate of said first and second vapor sources; reducing the mean free path between vapor particles in said vessel, said gas being present in an amount sufficient to induce homogeneity of said vapor mixture; and depositing said mixed metal compound on said substrate in the form of a uniform composition polycrystalline mixed metal compound. 5 figs.

Mickelsen, R.A.; Chen, W.S.

1985-06-11T23:59:59.000Z

297

An automatic analysis of Norwegian compounds  

E-Print Network (OSTI)

Introduction The University of Oslo is currently developing an automatic morphosyntactic tagger for Norwegian. 2 A very important module is one which can analyse compounds. Compounding is extremely productive in Norwegian, and it is futile to ever hope for a lexicon (dictionary) that will contain all or even most of the compounds that occr in actual texts. Since the tagger we are developing is based on the possibility of recognising words by the help of a lexicon, it is of great importance to have a module that recognises new compounds. According to Munthe (1972), 10.4 per cent of all words in running text are compounds. Any text sample will contain a greatnumber of compounds. This statistics is true even for small samples. I took an arbitrary 440-word article from the newspaper Aftenposten from September this year, Full penhet om passunion (Full openness on passport union), and I quickly counted 47 compounds. Many of them a

Janne Bondi Johannessen; Helge Hauglin

1996-01-01T23:59:59.000Z

298

METHOD OF RECOVERING URANIUM COMPOUNDS  

DOE Patents (OSTI)

S>The recovery of uranium compounds which have been adsorbed on anion exchange resins is discussed. The uranium and thorium-containing residues from monazite processed by alkali hydroxide are separated from solution, and leached with an alkali metal carbonate solution, whereby the uranium and thorium hydrorides are dissolved. The carbonate solution is then passed over an anion exchange resin causing the uranium to be adsorbed while the thorium remains in solution. The uranium may be recovered by contacting the uranium-holding resin with an aqueous ammonium carbonate solution whereby the uranium values are eluted from the resin and then heating the eluate whereby carbon dioxide and ammonia are given off, the pH value of the solution is lowered, and the uranium is precipitated.

Poirier, R.H.

1957-10-29T23:59:59.000Z

299

Volatile organic compound sensing devices  

DOE Patents (OSTI)

Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs.

Lancaster, Gregory D. (Idaho Falls, ID); Moore, Glenn A. (Idaho Falls, ID); Stone, Mark L. (Idaho Falls, ID); Reagen, William K. (Stillwater, MN)

1995-01-01T23:59:59.000Z

300

Volatile organic compound sensing devices  

DOE Patents (OSTI)

Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs. 15 figs.

Lancaster, G.D.; Moore, G.A.; Stone, M.L.; Reagen, W.K.

1995-08-29T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Volatile organic compound sensing devices  

DOE Patents (OSTI)

Apparatus employing vapochromic materials in the form of inorganic double complex salts which change color reversibly when exposed to volatile organic compound (VOC) vapors is adapted for VOC vapor detection, VOC aqueous matrix detection, and selective VOC vapor detection. The basic VOC vapochromic sensor is incorporated in various devices such as a ground probe sensor, a wristband sensor, a periodic sampling monitor, a soil/water penetrometer, an evaporative purge sensor, and various vacuum-based sensors which are particularly adapted for reversible/reusable detection, remote detection, continuous monitoring, or rapid screening of environmental remediation and waste management sites. The vapochromic sensor is used in combination with various fiber optic arrangements to provide a calibrated qualitative and/or quantitative indication of the presence of VOCs.

Lancaster, G.D.; Moore, G.A.; Stone, M.L.; Regen, W.K.

1993-12-31T23:59:59.000Z

302

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70 C and 500 C and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

Smith, L.A. Jr.; Arganbright, R.P.; Hearn, D.

1993-01-05T23:59:59.000Z

303

Alkylation of organic aromatic compounds  

DOE Patents (OSTI)

Aromatic compounds are alkylated in a combination reactor/distillation column comprising a vessel suitable for operating between 70.degree. C. and 500.degree. C. and from 0.5 to 20 atmospheres pressure; an inert distillation packing in the lower one-third of said vessel; solid acidic catalytic material such as zeolites or an acidic cation exchange resin supported in the middle one-third of said vessel; and inert distillation packing in the upper one-third of said vessel. A benzene inlet is located near the upper end of the vessel; an olefin inlet is juxtaposed with said solid acidic catalytic material; a bottoms outlet is positioned near the bottom of said vessel for removing said cumene and ethyl benzene; and an overhead outlet is placed at the top of said vessel for removing any unreacted benzene and olefin.

Smith, Jr., Lawrence A. (Bellaire, TX); Arganbright, Robert P. (Seabrook, TX); Hearn, Dennis (Houston, TX)

1993-01-01T23:59:59.000Z

304

Apparatus and method for generating continuous wave 16. mu. m laser radiation using gaseous CF/sub 4/  

DOE Patents (OSTI)

Apparatus and method for generating continuous wave 16 ..mu..m laser radiation using gaseous CF/sub 4/. Laser radiation at 16 ..mu..m has been observed in a cooled static cell containing low pressure CF/sub 4/ optically pumped by an approximately 3 W output power c-w CO/sub 2/ laser. The laser cavity employed was a multiple-pass off-axis-path two spherical mirror ring resonator. Unidirectional CF/sub 4/ laser output power at 615 cm/sup -1/ exceeded 2 mW. Computer calculations indicate that for modest pump powers of about 40 W, approximately 1 W of emitted laser radiation at 16 ..mu..m might be obtained.

Telle, J.M.

1984-05-01T23:59:59.000Z

305

Apparatus and method for generating continuous wave 16 .mu.m laser radiation using gaseous CF.sub.4  

DOE Patents (OSTI)

Apparatus and method for generating continuous wave 16 .mu.m laser radiation using gaseous CF.sub.4. Laser radiation at 16 .mu.m has been observed in a cooled static cell containing low pressure CF.sub.4 optically pumped by an approximately 3 W output power cw CO.sub.2 laser. The laser cavity employed was a multiple-pass off-axis-path two spherical mirror ring resonator. Unidirectional CF.sub.4 laser output power at 615 cm.sup.-1 exceeded 2 mW. Computer calculations indicate that for modest pump powers of about 40 W, approximately 1 W of emitted laser radiation at 16 .mu.m might be obtained.

Telle, John M. (Los Alamos, NM)

1986-01-01T23:59:59.000Z

306

The Mailbox Computer System for the IAEA verification experiment on HEU downlending at the Portsmouth Gaseous Diffusion Plant  

SciTech Connect

IN APRIL 1996, THE UNITED STATES (US) ADDED THE PORTSMOUTH GASEOUS DIFFUSION PLANT TO THE LIST OF FACILITIES ELIGIBLE FOR THE APPLICATION OF INTERNATIONAL ATOMIC ENERGY AGENCY (IAEA) SAFEGUARDS. AT THAT TIME, THE US PROPOSED THAT THE IAEA CARRY OUT A ''VERIFICATION EXPERIMENT'' AT THE PLANT WITH RESPECT TO DOOWNBLENDING OF ABOUT 13 METRIC TONS OF HIGHLY ENRICHED URANIUM (HEU) IN THE FORM OF URANIUM HEXAFLUROIDE (UF6). DURING THE PERIOD DECEMBER 1997 THROUGH JULY 1998, THE IAEA CARRIED OUT THE REQUESTED VERIFICATION EXPERIMENT. THE VERIFICATION APPROACH USED FOR THIS EXPERIMENT INCLUDED, AMONG OTHER MEASURES, THE ENTRY OF PROCESS-OPERATIONAL DATA BY THE FACILITY OPERATOR ON A NEAR-REAL-TIME BASIS INTO A ''MAILBOX'' COMPUTER LOCATED WITHIN A TAMPER-INDICATING ENCLOSURE SEALED BY THE IAEA.

Aronson, A.L.; Gordon, D.M.

2000-07-31T23:59:59.000Z

307

Detection of illicit HEU production in gaseous centrifuge enrichment plants using neutron counting techniques on product cylinders  

SciTech Connect

Innovative and novel safeguards approaches are needed for nuclear energy to meet global energy needs without the threat of nuclear weapons proliferation. Part of these efforts will include creating verification techniques that can monitor uranium enrichment facilities for illicit production of highly-enriched uranium (HEU). Passive nondestructive assay (NDA) techniques will be critical in preventing illicit HEU production because NDA offers the possibility of continuous and unattended monitoring capabilities with limited impact on facility operations. Gaseous centrifuge enrichment plants (GCEP) are commonly used to produce low-enriched uranium (LEU) for reactor fuel. In a GCEP, gaseous UF{sub 6} spins at high velocities in centrifuges to separate the molecules containing {sup 238}U from those containing the lighter {sup 235}U. Unfortunately, the process for creating LEU is inherently the same as HEU, creating a proliferation concern. Insuring that GCEPs are producing declared enrichments poses many difficult challenges. In a GCEP, large cascade halls operating thousands of centrifuges work together to enrich the uranium which makes effective monitoring of the cascade hall economically prohibitive and invasive to plant operations. However, the enriched uranium exiting the cascade hall fills product cylinders where the UF{sub 6} gas sublimes and condenses for easier storage and transportation. These product cylinders hold large quantities of enriched uranium, offering a strong signal for NDA measurement. Neutrons have a large penetrability through materials making their use advantageous compared to gamma techniques where the signal is easily attenuated. One proposed technique for detecting HEU production in a GCEP is using neutron coincidence counting at the product cylinder take off stations. This paper discusses findings from Monte Carlo N-Particle eXtended (MCNPX) code simulations that examine the feasibility of such a detector.

Freeman, Corey R [Los Alamos National Laboratory; Geist, William H [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

308

Compound cryopump for fusion reactors  

E-Print Network (OSTI)

We reconsider an old idea: a three-stage compound cryopump for use in fusion reactors such as DEMO. The helium "ash" is adsorbed on a 4.5 K charcoal-coated surface, while deuterium and tritium are adsorbed at 15-22 K on a second charcoal-coated surface. The helium is released by raising the first surface to ~30 K. In a separate regeneration step, deuterium and tritium are released at ~110 K. In this way, the helium can be pre-separated from other species. In the simplest design, all three stages are in the same vessel, with a single valve to close the pump off from the tokamak during regeneration. In an alternative design, the three stages are in separate vessels, connected by valves, allowing the stages to regenerate without interfering with each other. The inclusion of the intermediate stage would not affect the overall pumping speed significantly. The downstream exhaust processing system could be scaled down, as much of the deuterium and tritium could be returned directly to the reactor. This could reduce ...

Kovari, M; Shephard, T

2013-01-01T23:59:59.000Z

309

High voltage research (breakdown strengths of gaseous and liquid insulators) and environmental effects of dielectric gases. Semiannual report, October 1, 1979-March 31, 1980  

Science Conference Proceedings (OSTI)

Topics covered include basic studies of gaseous dielectrics, direct current breakdown strengths of gases/mixtures, environmental effects studies and decomposition analyses, impulse studies, breakdown strengths of binary mixtures with concentric cylinder geometry, and a discussion of the experimental apparatus. (GHT)

Christophorou, L.G.; James, D.R.; Pai, R.Y.

1980-08-01T23:59:59.000Z

310

The importance of SO{sub 2} and SO{sub 3} for sulphation of gaseous KCl - An experimental investigation in a biomass fired CFB boiler  

Science Conference Proceedings (OSTI)

This paper is based on results obtained during co-combustion of wood pellets and straw in a 12 MW circulating fluidised bed (CFB) boiler. Elemental sulphur (S) and ammonium sulphate ((NH{sub 4}){sub 2}SO{sub 4}) were used as additives to convert the alkali chlorides (mainly KCl) to less corrosive alkali sulphates. Their performance was then evaluated using several measurement tools including, IACM (on-line measurements of gaseous alkali chlorides), a low-pressure impactor (particle size distribution and chemical composition of extracted fly ash particles), and deposit probes (chemical composition in deposits collected). The importance of the presence of either SO{sub 2} or SO{sub 3} for gas phase sulphation of KCl is also discussed. Ammonium sulphate performed significantly better than elemental sulphur. A more efficient sulphation of gaseous KCl was achieved with (NH{sub 4}){sub 2}SO{sub 4} even when the S/Cl molar ratio was less than half compared to sulphur. Thus the presence of gaseous SO{sub 3} is of greater importance than that of SO{sub 2} for the sulphation of gaseous KCl. (author)

Kassman, Haakan [Vattenfall Power Consultant AB, Nykoeping (Sweden); Chalmers University of Technology, Department of Energy and Environment, Division of Energy Technology, Gothenburg (Sweden); Baefver, Linda [Technical Research Institute of Sweden, Energy Technology, Boraas (Sweden); Aamand, Lars-Erik [Chalmers University of Technology, Department of Energy and Environment, Division of Energy Technology, Gothenburg (Sweden)

2010-09-15T23:59:59.000Z

311

Annual book of ASTM Standards 2008. Section Five. Petroleum products, lubricants, and fossil fuels. Volume 05.06. Gaseous fuels; coal and coke  

SciTech Connect

The first part covers standards for gaseous fuels. The second part covers standards on coal and coke including the classification of coals, determination of major elements in coal ash and trace elements in coal, metallurgical properties of coal and coke, methods of analysis of coal and coke, petrogrpahic analysis of coal and coke, physical characteristics of coal, quality assurance and sampling.

NONE

2008-09-15T23:59:59.000Z

312

Reading Comprehension - Dissecting and Compound Microscopes  

NLE Websites -- All DOE Office Websites (Extended Search)

Dissecting and Compound Microscopes Two types of microscopes. _________ Dissecting and Compound Microscopes Two types of microscopes. _________ Dissecting Microscope Compound Microscope _________ eyepiece focus knob light light switch objective stage _________ eyepiece focus knob light light switch objective stage _________ eyepiece focus knob light light switch objective stage _________ eyepiece focus knob light light switch objective stage _________ eyepiece focus knob light light switch objective stage _________ eyepiece focus knob light light switch objective stage _________ Dissecting Microscope Compound Microscope _________ eyepieces focus knob light light switch objective stage _________ eyepieces focus knob light light switch objective stage _________ eyepieces focus knob light light switch objective stage _________ eyepieces focus knob light

313

Volatile organic compound emissions from composting.  

E-Print Network (OSTI)

??This paper is a review of the aerobic composting process and the emissions of volatile organic compounds (VOCs) from this process. To understand why and (more)

Harris, Stephanie Rose Rene

2013-01-01T23:59:59.000Z

314

Modern Records of Radiatively Important Halogenated Compounds...  

NLE Websites -- All DOE Office Websites (Extended Search)

at CDIAC sites: Methane, Nonmethane Hydrocarbons, Alkyl Nitrates, and Chlorinated Carbon Compounds including three Chlorofluorocarbons (CFC-11, CFC-12, and CFC-113) in...

315

Hydrodesulfurization catalysis by Chevrel phase compounds  

DOE Patents (OSTI)

A process is disclosed for the hydrodesulfurization of sulfur-containing hydrocarbon fuel with reduced ternary molybdenum sulfides, known as Chevrel phase compounds. Chevrel phase compounds of the general composition M.sub.x Mo.sub.6 S.sub.8, with M being Ho, Pb, Sn, Ag, In, Cu, Fe, Ni, or Co, were found to have hydrodesulfurization activities comparable to model unpromoted and cobalt-promoted MoS.sub.2 catalysts. The most active catalysts were the "large" cation compounds (Ho, Pb, Sn), and the least active catalysts were the "small" cation compounds (Cu, Fe, Ni, Co.).

McCarty, Kevin F. (Livermore, CA); Schrader, Glenn L. (Ames, IA)

1985-12-24T23:59:59.000Z

316

Why Sequence Bacteria That Reduce Sulfur Compounds?  

NLE Websites -- All DOE Office Websites (Extended Search)

Bacteria That Reduce Sulfur Compounds? Combustion of sulfur-containing fuels, such as coal, oil, and natural gas, contributes significantly to global environmental problems, such...

317

PLUTONIUM COMPOUNDS AND PROCESS FOR THEIR PREPARATION  

DOE Patents (OSTI)

This patent relates to certain new compounds of plutonium, and to the utilization of these compounds to effect purification or separation of the plutonium. The compounds are organic chelate compounds consisting of tetravalent plutonium together with a di(salicylal) alkylenediimine. These chelates are soluble in various organic solvents, but not in water. Use is made of this property in extracting the plutonium by contacting an aqueous solution thereof with an organic solution of the diimine. The plutonium is chelated, extracted and effectively separated from any impurities accompaying it in the aqueous phase.

Wolter, F.J.; Diehl, H.C. Jr.

1958-01-01T23:59:59.000Z

318

Process for synthesizing compounds from elemental powders  

DOE Patents (OSTI)

A process for synthesizing intermetallic compounds from elemental powders. The elemental powders are initially combined in ratio a which approximates the stoichiometric composition of the intermetallic compound. The mixed powders are then formed into a compact which is heat treated at a controlled rate of heating such that an exothermic reaction between the elements is initiated. The heat treatment may be performed under controlled conditions ranging from a vacuum (pressureless sintering) to compression (hot pressing) to produce a desired densification of the intermetallic compound. In a preferred form of the invention, elemental powders of Fe and Al are combined to form aluminide compounds of Fe{sub 3}Al and FeAl.

Rabin, B.H.; Wright, R.N.

1990-01-01T23:59:59.000Z

319

Alloys and Compounds for Thermoelectric and Solar Cell Applications  

Science Conference Proceedings (OSTI)

Alloys and Compounds for Thermoelectric and Solar Cell Applications II: Alloys and Compounds for Thermoelectric and Solar Cell Applications: Thermoelectric...

320

On Quantum Capacity of Compound Channels  

E-Print Network (OSTI)

In this paper we address the issue of universal or robust communication over quantum channels. Specifically, we consider memoryless communication scenario with channel uncertainty which is an analog of compound channel in classical information theory. We determine the quantum capacity of finite compound channels and arbitrary compound channels with informed decoder. Our approach in the finite case is based on the observation that perfect channel knowledge at the decoder does not increase the capacity of finite quantum compound channels. As a consequence we obtain coding theorem for finite quantum averaged channels, the simplest class of channels with long-term memory. The extension of these results to quantum compound channels with uninformed encoder and decoder, and infinitely many constituents remains an open problem.

I. Bjelakovic; H. Boche; J. Noetzel

2008-08-07T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
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321

Towards Heavy Fermions in Europium Intermetallic Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Towards Heavy Fermions in Europium Intermetallic Compounds Print Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass) have provided the clearest evidence for these continuous phase transitions, which are controlled by such parameters as chemical composition, magnetic field, and pressure, rather than temperature. A new study of a europium-based compound by an international team led by researchers from the Technische Universität Dresden in Germany hints that this compound could join well-known compounds of cerium, ytterbium, and uranium as a new material suitable for research on quantum critical transitions. This finding is exciting, since physicists hope that the use of a new material will give an additional degree of freedom for researching quantum critical behavior.

322

Towards Heavy Fermions in Europium Intermetallic Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Towards Heavy Fermions in Europium Intermetallic Compounds Print Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass) have provided the clearest evidence for these continuous phase transitions, which are controlled by such parameters as chemical composition, magnetic field, and pressure, rather than temperature. A new study of a europium-based compound by an international team led by researchers from the Technische Universität Dresden in Germany hints that this compound could join well-known compounds of cerium, ytterbium, and uranium as a new material suitable for research on quantum critical transitions. This finding is exciting, since physicists hope that the use of a new material will give an additional degree of freedom for researching quantum critical behavior.

323

Towards Heavy Fermions in Europium Intermetallic Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Towards Heavy Fermions in Towards Heavy Fermions in Europium Intermetallic Compounds Towards Heavy Fermions in Europium Intermetallic Compounds Print Wednesday, 29 July 2009 00:00 For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass) have provided the clearest evidence for these continuous phase transitions, which are controlled by such parameters as chemical composition, magnetic field, and pressure, rather than temperature. A new study of a europium-based compound by an international team led by researchers from the Technische Universität Dresden in Germany hints that this compound could join well-known compounds of cerium, ytterbium, and uranium as a new material suitable for research on quantum critical transitions. This finding is exciting, since physicists hope that the use of a new material will give an additional degree of freedom for researching quantum critical behavior.

324

Towards Heavy Fermions in Europium Intermetallic Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Towards Heavy Fermions in Europium Intermetallic Compounds Print Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass) have provided the clearest evidence for these continuous phase transitions, which are controlled by such parameters as chemical composition, magnetic field, and pressure, rather than temperature. A new study of a europium-based compound by an international team led by researchers from the Technische Universität Dresden in Germany hints that this compound could join well-known compounds of cerium, ytterbium, and uranium as a new material suitable for research on quantum critical transitions. This finding is exciting, since physicists hope that the use of a new material will give an additional degree of freedom for researching quantum critical behavior.

325

Towards Heavy Fermions in Europium Intermetallic Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Towards Heavy Fermions in Europium Intermetallic Compounds Print Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass) have provided the clearest evidence for these continuous phase transitions, which are controlled by such parameters as chemical composition, magnetic field, and pressure, rather than temperature. A new study of a europium-based compound by an international team led by researchers from the Technische Universität Dresden in Germany hints that this compound could join well-known compounds of cerium, ytterbium, and uranium as a new material suitable for research on quantum critical transitions. This finding is exciting, since physicists hope that the use of a new material will give an additional degree of freedom for researching quantum critical behavior.

326

Towards Heavy Fermions in Europium Intermetallic Compounds  

NLE Websites -- All DOE Office Websites (Extended Search)

Towards Heavy Fermions in Europium Intermetallic Compounds Print Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass) have provided the clearest evidence for these continuous phase transitions, which are controlled by such parameters as chemical composition, magnetic field, and pressure, rather than temperature. A new study of a europium-based compound by an international team led by researchers from the Technische Universität Dresden in Germany hints that this compound could join well-known compounds of cerium, ytterbium, and uranium as a new material suitable for research on quantum critical transitions. This finding is exciting, since physicists hope that the use of a new material will give an additional degree of freedom for researching quantum critical behavior.

327

Double-pulse and single-pulse laser-induced breakdown spectroscopy for distinguishing between gaseous and particulate phase analytes  

SciTech Connect

We explore the use of a combination of double-pulse and single-pulse laser-induced breakdown spectroscopy (LIBS) methodologies as a means of differentiating between solid-phase and gaseous-phase analytes (namely, carbon) in an aerosol stream. A range of spectral data was recorded for double-pulse and single-pulse configurations, including both ns and fs prepulse widths, while varying the gas-phase mass percentage of the carbon from about 10% to 90% for various fixed carbon concentrations. The carbon emission response, as measured by the peak-to-continuum ratio, was greater for the double-pulse configuration as compared with the single-pulse response and was also enhanced as the percentage of solid-phase carbon was increased. Using a combination of the double-pulse and single-pulse emission signals, a monotonically increasing response function was found to correlate with the percentage of gas-phase analyte. However, individual data points at the measured gas-phase percentages reveal considerable scatter from the predicted trend. Furthermore, the double-pulse to single-pulse ratio was only pronounced with the ns-ns configuration as compared with the fs-ns scheme. Overall, the LIBS methodology has been demonstrated as a potential means to discriminate between gas-phase and particulate-phase fractions of the same elemental species in an aerosol, although future optimization of the temporal parameters should be explored to improve the precision and accuracy of this approach.

Asgill, Michael E.; Brown, Michael S.; Frische, Kyle; Roquemore, William M.; Hahn, David W.

2010-05-01T23:59:59.000Z

328

Effect of gaseous corrosion on the strength of SiC and Si sub 3 N sub 4  

DOE Green Energy (OSTI)

The effects of gaseous corrosion on the room-temperature flexural strength of SiC and Si{sub 3}N{sub 4} were investigated. Sintered {alpha}-SiC and hot-pressed Si{sub 3}N{sub 4} were exposed to flowing H{sub 2} or Ar at 1400{degrees}C for 10 h. The explored variables, water vapor pressure in the H{sub 2} or oxygen partial pressure in the Ar, were found to significantly affect the corrosion of these materials. Reductions in room-temperature strength were observed when weight loss resulted from active oxidation, except for the Si{sub 3}N{sub 4} exposed in Ar containing O{sub 2}. Large pits that formed during exposure were responsible for the strength reductions. When the P{sub H{sub 2}O} in H{sub 2} or P{sub O{sub 2}} in Ar was high enough to form a thin oxide layer on the sample surface, the observed strength increased, ultimately to values greater than that of the as-polished material. However, under conditions in which a much thicker oxide layer was formed, the strengths were unaffected or decreased slightly, the latter being attributed to the generation of new flaws such as bubbles or cracks in the oxide layer. 34 refs., 8 figs.

Kim, Hyoun-Ee; Moorhead, A.J.

1989-01-01T23:59:59.000Z

329

Prediction of external corrosion for steel cylinders at the Paducah Gaseous Diffusion Plant: Application of an empirical method  

Science Conference Proceedings (OSTI)

During the summer of 1995, ultrasonic wall thickness data were collected for 100 steel cylinders containing depleted uranium (DU) hexafluoride located at Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky. The cylinders were selected for measurement to assess the condition of the more vulnerable portion of the cylinder inventory at PGDP. The purpose of this report is to apply the method used in Lyon to estimate the effects of corrosion for larger unsampled populations as a function of time. The scope of this report is limited and is not intended to represent the final analyses of available data. Future efforts will include continuing analyses of available data to investigate defensible deviations from the conservative assumptions made to date. For each cylinder population considered, two basic types of analyses were conducted: (1) estimates were made of the number of cylinders as a function of time that will have a minimum wall thickness of either 0 mils (1 mil = 0.00 1 in.) or 250 mils and (2) the current minimum wall thickness distributions across cylinders were estimated for each cylinder population considered. Additional analyses were also performed investigating comparisons of the results for F and G yards with the results presented in Lyon (1995).

Lyon, B.F.

1996-02-01T23:59:59.000Z

330

Nuclear criticality safety controls for uranium deposits during D and D at the Oak Ridge Gaseous Diffusion Plant  

SciTech Connect

The US Department of Energy (DOE) Deputy Assistant Secretary of Energy for Environmental Management has issued a challenge to complete DOE environmental cleanup within a decade. The response for Oak Ridge facilities is in accordance with the DOE ten-year plan which calls for completion of > 95% of environmental management work by the year 2006. This will result in a 99% risk reduction and in a significant savings in base line costs in waste management (legacy waste); remedial action (groundwater, soil, etc.); and decontamination and decommissioning (D and D). It is assumed that there will be long-term institutional control of cascade equipment, i.e., there will be no walk away from sites, and that there will be firm radioactivity release limits by 1999 for recycle metals. An integral part of these plants is the removal of uranium deposits which pose nuclear criticality safety concerns in the shut down of the Oak Ridge Gaseous Diffusion Plant. DOE has initiated the Nuclear Criticality Stabilization Program to improve nuclear criticality safety by removing the larger uranium deposits from unfavorable geometry equipment. Nondestructive assay (NDA) measurements have identified the location of these deposits. The objective of the K-25 Site Nuclear Criticality Stabilization Program is to remove and place uranium deposits into safe geometry storage containers to meet the double contingency principle. Each step of the removal process results in safer conditions where multiple controls are present. Upon completion of the Program, nuclear criticality risks will be greatly reduced.

Haire, M.J.; Jordan, W.C. [Oak Ridge National Lab., TN (United States); Jollay, L.J. III; Dahl, T.L. [Oak Ridge K-25 Site, TN (United States)

1997-02-01T23:59:59.000Z

331

Novel mass spectrometric instrument for gaseous and particulate characterization and monitoring. Technical progress report, July 1, 1993--September 30, 1993  

SciTech Connect

The goals of the Office of Technology Development as outlined by the director of the Environmental Restoration and Waste Management Program (EM), Leo Duffy, in 1991 appropriations hearings include conducting an aggressive technology development program for waste management, waste minimization, waste treatment, storage and disposal of waste. This will be done through the development of more effective remediation technology to reduce occupational and public exposure. We are developing a method to monitor airborne emissions from the TSCA plant at Oak Ridge which will provide real-time, accurate, and inexpensive data on the emission of hazardous organic and inorganic chemicals in both gaseous and particulate form, and to assist DOE in maintaining its ambitious schedules and overcoming significant scientific limitations of its current monitoring technologies. In May 1988 under the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), Oak Ridge National Laboratory (ORNL) established a timetable remedial investigation/feasibility study, and a Federal Facility Agreement is being negotiated with the Environmental Protection Agency and the Tennessee Department of Health and Environment. As a result, work has begun on inactive waste sites at ORNL to excavate and isolate wastes in compliance with current standards. In addition, ORNL must comply with the Resource Conservation and Recovery Act (RCRA), which regulates generation, transportation, treatment, storage, and disposal of hazardous wastes and corrective action of releases to the environment of hazardous wastes from active facilities.

Coggiola, M.J.

1993-11-01T23:59:59.000Z

332

Characterization Activities Conducted at the 183-DR Site in Support of an In Situ Gaseous Reduction Demonstration  

Science Conference Proceedings (OSTI)

In Situ Gaseous Reduction (ISGR) is a technology developed by DOE for the remediation of soil waste sites contaminated with hexavalent chromium. This document presents information associated with characterization activities conducted at the 183-DR site at Hanford, which is associated with a significant groundwater contaminant plume and was formerly a water treatment facility that utilized chromate as a corrosion inhibitor. Geotechnical and chemical data were collected during the excavation of trenches and the drilling of two vadose zone boreholes to support a possible ISGR demonstration at 183-DR. Although elevated total chromium and trace levels of hexavalent chromium were identified from one of the trenches and one of the boreholes, it appears that the boreholes missed the vadose zone contaminant source responsible for the chromium groundwater plume located downgradient of the 183-DR site. Recommendations are provided, however, for future work at 183-DR that may serve to identify the source for the groundwater plume and possibly provide an opportunity for an ISGR demonstration.

Thornton, Edward C.; Gilmore, Tyler J.; Olsen, Khris B.; Schalla, Ronald; Cantrell, Kirk J.

2001-03-30T23:59:59.000Z

333

Compound and Elemental Analysis | Open Energy Information  

Open Energy Info (EERE)

Compound and Elemental Analysis Compound and Elemental Analysis Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: Compound and Elemental Analysis Details Activities (104) Areas (69) Regions (6) NEPA(0) Exploration Technique Information Exploration Group: Lab Analysis Techniques Exploration Sub Group: Fluid Lab Analysis Parent Exploration Technique: Fluid Lab Analysis Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Results can aid in the determination of fluid source regions and circulation pathways. Thermal: Certain elements exhibit high spatial correlation with high-temperature geothermal systems. Cost Information Low-End Estimate (USD): 15.001,500 centUSD 0.015 kUSD 1.5e-5 MUSD 1.5e-8 TUSD / compound Median Estimate (USD): 30.003,000 centUSD

334

Fission Barriers of Compound Superheavy Nuclei  

E-Print Network (OSTI)

The dependence of fission barriers on the excitation energy of the compound nucleus impacts the survival probability of superheavy nuclei synthesized in heavy-ion fusion reactions. In this work, we investigate the isentropic ...

Sheikh, J. A.

335

Production method for making rare earth compounds  

DOE Patents (OSTI)

A method of making a rare earth compound, such as a earth-transition metal permanent magnet compound, without the need for producing rare earth metal as a process step, comprises carbothermically reacting a rare earth oxide to form a rare earth carbide and heating the rare earth carbide, a compound-forming reactant (e.g. a transition metal and optional boron), and a carbide-forming element (e.g. a refractory metal) that forms a carbide that is more thermodynamically favorable than the rare earth carbide whereby the rare earth compound (e.g. Nd.sub.2 Fe.sub.14 B or LaNi.sub.5) and a carbide of the carbide-forming element are formed.

McCallum, R. William (Ames, IA); Ellis, Timothy W. (Ames, IA); Dennis, Kevin W. (Ames, IA); Hofer, Robert J. (Ames, IA); Branagan, Daniel J. (Ames, IA)

1997-11-25T23:59:59.000Z

336

Aza crown ether compounds as anion receptors  

DOE Patents (OSTI)

A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the new family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of LI{sup +} ion in alkali metal batteries. 3 figs.

Lee, H.S.; Yang, X.O.; McBreen, J.

1998-08-04T23:59:59.000Z

337

Aza crown ether compounds as anion receptors  

SciTech Connect

A family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the new family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of LI.sup.+ ion in alkali metal batteries.

Lee, Hung Sui (East Setauket, NY); Yang, Xiao-Oing (Port Jefferson Station, NY); McBreen, James (Bellport, NY)

1998-08-04T23:59:59.000Z

338

INDEPENDENT TECHNICAL REVIEW OF THE FOCUSED FEASIBILITY STUDY AND PROPOSED PLAN FOR DESIGNATED SOLID WASTE MANAGEMENT UNITS CONTRIBUTING TO THE SOUTHWEST GROUNDWATER PLUME AT THE PADUCAH GASEOUS DIFFUSION PLANT  

SciTech Connect

The U. S. Department of Energy (DOE) is currently developing a Proposed Plan (PP) for remediation of designated sources of chlorinated solvents that contribute contamination to the Southwest (SW) Groundwater Plume at the Paducah Gaseous Diffusion Plant (PGDP), in Paducah, KY. The principal contaminants in the SW Plume are trichloroethene (TCE) and other volatile organic compounds (VOCs); these industrial solvents were used and disposed in various facilities and locations at PGDP. In the SW plume area, residual TCE sources are primarily in the fine-grained sediments of the Upper Continental Recharge System (UCRS), a partially saturated zone that delivers contaminants downward into the coarse-grained Regional Gravel Aquifer (RGA). The RGA serves as the significant lateral groundwater transport pathway for the plume. In the SW Plume area, the four main contributing TCE source units are: (1) Solid Waste Management Unit (SWMU) 1 / Oil Landfarm; (2) C-720 Building TCE Northeast Spill Site (SWMU 211A); (3) C-720 Building TCE Southeast Spill Site (SWMU 211B); and (4) C-747 Contaminated Burial Yard (SWMU 4). The PP presents the Preferred Alternatives for remediation of VOCs in the UCRS at the Oil Landfarm and the C-720 Building spill sites. The basis for the PP is documented in a Focused Feasibility Study (FFS) (DOE, 2011) and a Site Investigation Report (SI) (DOE, 2007). The SW plume is currently within the boundaries of PGDP (i.e., does not extend off-site). Nonetheless, reasonable mitigation of the multiple contaminant sources contributing to the SW plume is one of the necessary components identified in the PGDP End State Vision (DOE, 2005). Because of the importance of the proposed actions DOE assembled an Independent Technical Review (ITR) team to provide input and assistance in finalizing the PP.

Looney, B.; Eddy-Dilek, C.; Amidon, M.; Rossabi, J.; Stewart, L.

2011-05-31T23:59:59.000Z

339

Polymers containing borane or carborane cage compounds and related applications  

DOE Patents (OSTI)

Polymers comprising residues of cage compound monomers having at least one polyalkoxy silyl substituent are provided. The cage compound monomers are selected from borane cage compound monomers comprising at least 7 cage atoms and/or carborane cage compound monomers comprising 7 to 11 cage compound monomers. Such polymers can further comprise one or more reactive matrices and/or co-monomers covalently bound with the cage compound monomer residues. Articles of manufacture comprising such polymers are also disclosed.

Bowen, III, Daniel E; Eastwood, Eric A

2013-04-23T23:59:59.000Z

340

Gaseous mercury release during steam curing of aerated concretes that contain fly ash and activated carbon sorbent  

Science Conference Proceedings (OSTI)

Gaseous mercury released from aerated concrete during both presteam curing at 25{sup o}C and steam curing at 80{sup o}C was measured in controlled laboratory experiments. Mercury release originated from two major components in the concrete mixture: (1) class F coal fly ash and (2) a mixture of the fly ash and powdered activated carbon onto which elemental mercury was adsorbed. Mercury emitted during each curing cycle was collected on iodated carbon traps in a purge-and-trap arrangement and subsequently measured by cold-vapor atomic fluorescence spectrometry. Through 3 h of presteam curing, the release of mercury from the freshly prepared mixture was less than 0.03 ng/kg of concrete. Releases of total mercury over the 21 h steam curing process ranged from 0.4 to 5.8 ng of mercury/kg of concrete and depended upon mercury concentrations in the concrete. The steam-cured concrete had a higher mercury release rate (ng kg{sup -1} h{sup -1}) compared to air-cured concrete containing fly ash, but the shorter curing interval resulted in less total release of mercury from the steam-cured concrete. The mercury flux from exposed concrete surfaces to mercury-free air ranged from 0.77 to 11.1 ng m{sup -2} h{sup -1}, which was similar to mercury fluxes for natural soils to ambient air of 4.2 ng m{sup -2} h{sup -1} reported by others. Less than 0.022% of the total quantity of mercury present from all mercury sources in the concrete was released during the curing process, and therefore, nearly all of the mercury was retained in the concrete. 31 refs., 4 figs., 2 tabs.

Danold W. Golightly; Chin-Min Cheng; Ping Sun; Linda K. Weavers; Harold W. Walker; Panuwat Taerakul; William E. Wolfe [Ohio State University, Columbus, OH (United States). Department of Civil and Environmental Engineering and Geodetic Science

2008-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Unattended Monitoring of HEU Production in Gaseous Centrifuge Enrichment Plants using Automated Aerosol Collection and Laser-based Enrichment Assay  

Science Conference Proceedings (OSTI)

Nuclear power is enjoying rapid growth as government energy policies and public demand shift toward low carbon energy production. Pivotal to the global nuclear power renaissance is the development and deployment of robust safeguards instrumentation that allows the limited resources of the IAEA to keep pace with the expansion of the nuclear fuel cycle. Undeclared production of highly enriched uranium (HEU) remains a primary proliferation concern for modern gaseous centrifuge enrichment plants (GCEPs), due to their massive separative work unit (SWU) processing power and comparably short cascade equilibrium timescale. The Pacific Northwest National Laboratory is developing an unattended safeguards instrument, combining continuous aerosol particulate collection with uranium isotope assay, to provide timely detection of HEU production within a GCEP. This approach is based on laser vaporization of aerosol particulates, followed by laser spectroscopy to characterize the uranium enrichment level. Our prior investigation demonstrated single-shot detection sensitivity approaching the femtogram range and relative isotope ratio uncertainty better than 10% using gadolinium as a surrogate for uranium. In this paper we present measurement results on standard samples containing traces of depleted, natural, and low enriched uranium, as well as measurements on aerodynamic size uranium particles mixed in background materials (e.g., dust, minerals, soils). Improvements and optimizations in the detection electronics, signal timing, calibration, and laser alignment have lead to significant improvements in detection sensitivity and enrichment accuracy, contributing to an overall reduction in the false alarm probability. The sample substrate media was also found to play a significant role in facilitating laser-induced vaporization and the production of energetic plasma conditions, resulting in ablation optimization and further improvements in the isotope abundance sensitivity.

Anheier, Norman C.; Bushaw, Bruce A.

2010-08-11T23:59:59.000Z

342

Compound and Elemental Analysis At Salt Wells Area (Shevenell...  

Open Energy Info (EERE)

Compound and Elemental Analysis At Salt Wells Area (Shevenell & Garside, 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and...

343

Alloys and Compounds for Thermoelectric and Solar Cell Applications  

Science Conference Proceedings (OSTI)

Alloys and Compounds for Thermoelectric and Solar Cell Applications II: Alloys and Compounds for Thermoelectric and Solar Cell Applications: Thermoelectric I

344

Energy-efficient indoor volatile organic compound air cleaning...  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy-efficient indoor volatile organic compound air cleaning using activated carbon fiber media with nightly regeneration Title Energy-efficient indoor volatile organic compound...

345

Compound and Elemental Analysis At Black Warrior Area (DOE GTP...  

Open Energy Info (EERE)

Compound and Elemental Analysis At Black Warrior Area (DOE GTP) Exploration Activity Details Location Black Warrior Area Exploration Technique Compound and Elemental Analysis...

346

Compound and Elemental Analysis At Wister Area (DOE GTP) | Open...  

Open Energy Info (EERE)

Compound and Elemental Analysis At Wister Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At...

347

SEPARATION PROCESS FOR ZIRCONIUM AND COMPOUNDS THEREOF  

DOE Patents (OSTI)

The separation of zirconium from columbium, rare earths, yttrium and the alkaline earth metals, such mixtures of elements occurring in zirconium ores or neutron irradiated uranium is described. According to the invention a suitable separation of zirconium from a one normal acidic aqueous solution containing salts, nitrates for example, of tetravalent zirconium, pentavalent columbium, yttrium, rare earths in the trivalent state and alkaline earths can be obtained by contacting the aqueous solution with a fluorinated beta diketonc alone or in an organic solvent solution, such as benzene, to form a zirconium chelate compound. When the organic solvent is present the zirconium chelate compound is directly extracted; otherwise it is separated by filtration. The zirconium may be recovered from contacting the organic solvent solution containing the chelated compound by back extraction with either an aqueous hydrofluoric acid or an oxalic acid solution.

Crandall, H.W.; Thomas, J.R.

1959-06-30T23:59:59.000Z

348

Inelastic neutron scattering in valence fluctuation compounds  

SciTech Connect

The valence fluctuation compounds are rare earth intermetallics where hybridization of the nearly-localized 4f electrons with the conduction electrons leads to incorporation of the 4f's into the itinerant states. This hybridization slows down the conduction electrons and hence gives them a heavy effective mass, justifying application of the term 'heavy Fermion' (HF) to these materials. During the project period, we grew large single crystals of several such compounds and measured their properties using both standard thermodynamic probes and state-of-the-art inelastic neutron scattering. We obtained three main results. For the intermediate valence compounds CePd{sub 3} and YbAl{sub 3}, we showed that the scattering of neutrons by the fluctuations of the 4f magnetic moment does not have the momentum dependence expected for the itinerant heavy mass state; rather, the scattering is more typical of a localized spin fluctuation. We believe that incoherent scattering localizes the excitation. For the heavy Fermion compound Ce(Ni{sub 0.935}Pd{sub 0.065}){sub 2}Ge{sub 2}, which sits at a T = 0 critical point for transformation into an antiferromagnetic (AF) phase, we showed that the scattering from the AF fluctuations does not exhibit any of the divergences that are expected at a phase transition. We speculate that alloy disorder profoundly suppresses the growth of the fluctuating AF regions, leading to short range clusters rather than regions of infinite size. Finally, we explored the applicability of key concepts used to describe the behavior of rare earth heavy Fermions to uranium based HF compounds where the 5f electrons are itinerant as opposed to localized. We found that scaling laws relating the spin fluctuation energy measured in neutron scattering to the low temperature specific heat and susceptibility are valid for the uranium compounds, once corrections are made for AF fluctuations; however, the degeneracy of the high temperature moment is smaller than expected for rare-earth-like Hund's rule behavior, essentially because the orbital moment is suppressed for itinerant 5f electrons. We also found that the standard local-moment-based theory of the temperature dependence of the specific heat, susceptibility and neutron scattering fails badly for URu{sub 2}Zn{sub 20} and UCo{sub 2}Zn{sub 20}, even though the theory is phenomenally successful for the closely related rare earth compound YbFe{sub 2}Zn{sub 20}. Both these results highlight the distinction between the itineracy of the 5f's and the localization of the 4f's. It is our hope that these results are sufficiently significant as to stimulate deeper investigation of these compounds.

Jon M Lawrence

2011-02-15T23:59:59.000Z

349

Process for producing phenolic compounds from lignins  

DOE Patents (OSTI)

A process is described for the production of low molecular weight phenolic compounds from lignins through the pyrolysis of the lignins in the presence of a strong base. In a preferred embodiment, potassium hydroxide is present in an amount of from about 0.1% to about 5% by weight, the pyrolysis temperature is from about 400 C to about 600 C at atmospheric pressure, and the time period for substantial completion of the reaction is from about 1--3 minutes. Examples of low molecular weight phenolic compounds produced include methoxyphenols, non-methoxylated phenols, and mixtures thereof. 16 figs.

Agblevor, F.A.

1998-09-15T23:59:59.000Z

350

Organic photosensitive devices using subphthalocyanine compounds  

DOE Patents (OSTI)

An organic photosensitive optoelectronic device, having a donor-acceptor heterojunction of a donor-like material and an acceptor-like material and methods of making such devices is provided. At least one of the donor-like material and the acceptor-like material includes a subphthalocyanine, a subporphyrin, and/or a subporphyrazine compound; and/or the device optionally has at least one of a blocking layer or a charge transport layer, where the blocking layer and/or the charge transport layer includes a subphthalocyanine, a subporphyrin, and/or a subporphyrazine compound.

Rand, Barry (Princeton, NJ); Forrest, Stephen R. (Ann Arbor, MI); Mutolo, Kristin L. (Hollywood, CA); Mayo, Elizabeth (Alhambra, CA); Thompson, Mark E. (Anaheim Hills, CA)

2011-07-05T23:59:59.000Z

351

Process for producing phenolic compounds from lignins  

DOE Patents (OSTI)

A process for the production of low molecular weight phenolic compounds from lignins through the pyrolysis of the lignins in the presence of a strong base. In a preferred embodiment, potassium hydroxide is present in an amount of from about 0.1% to about 5% by weight, the pyrolysis temperature is from about 400.degree. C. to about 600.degree. C. at atmospheric pressure, and the time period for substantial completion of the reaction is from about 1-3 minutes. Examples of low molecular weight phenolic compounds produced include methoxyphenols, non-methoxylated phenols, and mixtures thereof.

Agblevor, Foster A. (Lakewood, CO)

1998-01-01T23:59:59.000Z

352

Paraffin Polydispersity Facilitates Mechanical Gelation Kristofer Paso,  

E-Print Network (OSTI)

climates or subsea producing fields. When the temperature of a crude oil or gas condensate fluid drops. Sastry, and H. Scott Fogler*, Department of Chemical Engineering, University of Michigan, Ann Arbor, Michigan 48109, and Department of Mechanical Engineering, University of Michigan, Ann Arbor, Michigan 48109

Sastry, Ann Marie

353

NGPL Production, Gaseous Equivalent  

U.S. Energy Information Administration (EIA) Indexed Site

Monthly Annual Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Data Series Area 2007 2008 2009 2010 2011 2012 View History U.S. 930,320 953,451 1,024,082 1,066,366 1,134,473 1,250,340 1930-2012 Federal Offshore Gulf of Mexico 0 0 0 0 0 2007-2011 Alabama 19,831 17,222 17,232 19,059 17,271 1969-2011 Alaska 26,332 24,337 22,925 20,835 21,554 21,470 1969-2012 Arkansas 162 139 168 213 268 424 1967-2012 California 13,521 13,972 13,722 13,244 12,095 12,755 1967-2012 Colorado 38,180 53,590 67,607 82,637 90,801 1967-2011 Florida 132 22 0 0 0 0 1968-2012 Illinois 48 42 31 345 1,043 0 1967-2012 Indiana 0 0 0 0 0 0 1979-2012

354

Portsmouth Gaseous Diffusion Plant  

NLE Websites -- All DOE Office Websites (Extended Search)

implement Cold Shutdown requirements; disposition of depleted uranium hexafluoride cylinders; and perform Decontamination and Decommissioning. Portsmouth D&D Project Portsmouth...

355

Gaseous Hydrogen Delivery Breakout  

E-Print Network (OSTI)

natural gas pipelines can be used for H2 without total loss of natural gas flow capability #12;Breakout technology #12;Breakout Session Name R&D Needs Advanced Compressors Survey existing and emerging compression, `invisible' flame Role of federal gov't vs industry for H2 research to address market failures #12;

356

Fluorescent compounds for plastic scintillation applications  

SciTech Connect

Several 2-(2{prime}-hydroxyphenyl)benzothiazole, -benzoxazole, and -benzimidazole derivatives have been prepared. Transmittance, fluorescence, light yield, and decay time characteristics of these compounds have been studied in a polystyrene matrix and evaluated for use in plastic scintillation detectors. Radiation damage studies utilizing a {sup 60}C source have also been performed.

Pla-Dalmau, A.; Bross, A.D.

1994-04-01T23:59:59.000Z

357

Pyrolysis mechanisms of lignin model compounds  

DOE Green Energy (OSTI)

The flash vacuum pyrolysis of lignin model compounds was studied under conditions optimized for the production of liquid products to provide mechanistic insight into the reaction pathways that lead to product formation. The major reaction products can be explained by cleavage of the C-O either linkage by a free radial or concerted 1,2-elimination.

Britt, P.F.; Buchanan, A.C. III; Cooney, M.J.

1997-06-01T23:59:59.000Z

358

Compound nucleus studies withy reverse kinematics  

SciTech Connect

Reverse kinematics reactions are used to demonstrate the compound nucleus origin of intermediate mass particles at low energies and the extension of the same mechanism at higher energies. No evidence has appeared in our energy range for liquid-vapor equilibrium or cold fragmentation mechanisms. 11 refs., 12 figs.

Moretto, L.G.

1985-06-01T23:59:59.000Z

359

PRODUCTION OF URANIUM AND THORIUM COMPOUNDS  

DOE Patents (OSTI)

Compounds of Th and U are extracted with an organic solvent in the presence of an adsorbent substance which has greater retentivity for impurities present than for the uranium and/or thorium. The preferred adsorbent material is noted as being cellulose. The uranium and thoriumcontaining substances treated are preferably in the form of dissolved nitrates, and the preferred organic solvent is diethyl ether.

Arden, T.V.; Burstall, F.H.; Linstead, R.P.; Wells, R.A.

1955-12-27T23:59:59.000Z

360

Stable surface passivation process for compound semiconductors  

DOE Patents (OSTI)

A passivation process for a previously sulfided, selenided or tellurated III-V compound semiconductor surface. The concentration of undesired mid-gap surface states on a compound semiconductor surface is reduced by the formation of a near-monolayer of metal-(sulfur and/or selenium and/or tellurium)-semiconductor that is effective for long term passivation of the underlying semiconductor surface. Starting with the III-V compound semiconductor surface, any oxidation present thereon is substantially removed and the surface is then treated with sulfur, selenium or tellurium to form a near-monolayer of chalcogen-semiconductor of the surface in an oxygen-free atmosphere. This chalcogenated surface is then contacted with a solution of a metal that will form a low solubility chalcogenide to form a near-monolayer of metal-chalcogen-semiconductor. The resulting passivating layer provides long term protection for the underlying surface at or above the level achieved by a freshly chalcogenated compound semiconductor surface in an oxygen free atmosphere.

Ashby, Carol I. H. (Edgewood, NM)

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Tritium labeling of organic compounds deposited on porous structures  

DOE Patents (OSTI)

An improved process for labeling organic compounds with tritium is carried out by depositing the selected compound on the extensive surface of a porous structure such as a membrane filter and exposing the membrane containing the compound to tritium gas activated by the microwave discharge technique. The labeled compound is then recovered from the porous structure.

Ehrenkaufer, Richard L. E. (Speonk, NY); Wolf, Alfred P. (Setauket, NY); Hembree, Wylie C. (Woodcliff Lake, NJ)

1979-01-01T23:59:59.000Z

362

Compositions containing borane or carborane cage compounds and related applications  

DOE Patents (OSTI)

Compositions comprising a polymer-containing matrix and a filler comprising a cage compound selected from borane cage compounds, carborane cage compounds, metal complexes thereof, residues thereof, mixtures thereof, and/or agglomerations thereof, where the cage compound is not covalently bound to the matrix polymer. Methods of making and applications for using such compositions are also disclosed.

Bowen, III, Daniel E; Eastwood, Eric A

2013-05-28T23:59:59.000Z

363

Hydromechanical transmission with compound planetary assembly  

DOE Patents (OSTI)

A power transmission having three distinct ranges: (1) hydrostatic, (2) simple power-split hydromechanical, and (3) compound power-split hydromechanical. A single compound planetary assembly has two sun gears, two ring gears, and a single carrier with two sets of elongated planet gears. The two sun gears may be identical in size, and the two ring gears may be identical in size. A speed-varying module in driving relationship to the first sun gear is clutchable, in turn, to (1) the input shaft and (2) the second sun gear. The speed-varying means may comprise a pair of hydraulic units hydraulically interconnected so that one serves as a pump while the other serves as a motor and vice versa, one of the units having a variable stroke and being the one clutchable to either the input shaft or to the second sun gear. The other unit, which may have a fixed stroke, is connected in driving relation to the first sun gear. A brake grounds the carrier in the first range and in reverse and causes drive to be delivered to the output shaft through the first ring gear in a hydrostatic mode, the first ring gear being rigidly connected to the output shaft. The input shaft is also clutchable to the second ring gear of the compound planetary assembly.

Orshansky, Jr., deceased, Elias (late of San Francisco, CA); Weseloh, William E. (San Diego, CA)

1980-01-01T23:59:59.000Z

364

TECHNICAL EVALUATION OF TEMPORAL GROUNDWATER MONITORING VARIABILITY IN MW66 AND NEARBY WELLS, PADUCAH GASEOUS DIFFUSION PLANT  

SciTech Connect

Evaluation of disposal records, soil data, and spatial/temporal groundwater data from the Paducah Gaseous Diffusion Plant (PGDP) Solid Waste Management Unit (SWMU) 7 indicate that the peak contaminant concentrations measured in monitoring well (MW) 66 result from the influence of the regional PGDP NW Plume, and does not support the presence of significant vertical transport from local contaminant sources in SWMU 7. This updated evaluation supports the 2006 conceptualization which suggested the high and low concentrations in MW66 represent different flow conditions (i.e., local versus regional influences). Incorporation of the additional lines of evidence from data collected since 2006 provide the basis to link high contaminant concentrations in MW66 (peaks) to the regional 'Northwest Plume' and to the upgradient source, specifically, the C400 Building Area. The conceptual model was further refined to demonstrate that groundwater and the various contaminant plumes respond to complex site conditions in predictable ways. This type of conceptualization bounds the expected system behavior and supports development of environmental cleanup strategies, providing a basis to support decisions even if it is not feasible to completely characterize all of the 'complexities' present in the system. We recommend that the site carefully consider the potential impacts to groundwater and contaminant plume migration as they plan and implement onsite production operations, remediation efforts, and reconfiguration activities. For example, this conceptual model suggests that rerouting drainage water, constructing ponds or basin, reconfiguring cooling water systems, capping sites, decommissioning buildings, fixing (or not fixing) water leaks, and other similar actions will potentially have a 'direct' impact on the groundwater contaminant plumes. Our conclusion that the peak concentrations in MW66 are linked to the regional PGDP NW Plume does not imply that there TCE is not present in SWMU 7. The available soil and groundwater data indicate that the some of the waste disposed in this facility contacted and/or were contaminated by TCE. In our assessment, the relatively small amount of TCE associated with SWMU 7 is not contributing detectable TCE to the groundwater and does not represent a significant threat to the environment, particularly in an area where remediation and/or management of TCE in the NW plume will be required for an extended timeframe. If determined to be necessary by the PGDP team and regulators, additional TCE characterization or cleanup activities could be performed. Consistent with the limited quantity of TCE in SWMU 7, we identify a range of low cost approaches for such activities (e.g., soil gas surveys for characterization or SVE for remediation). We hope that this information is useful to the Paducah team and to their regulators and stakeholders to develop a robust environmental management path to address the groundwater and soil contamination associated with the burial ground areas.

Looney, B.; Eddy-Dilek, C.

2012-08-28T23:59:59.000Z

365

Ternary compound electrode for lithium cells  

DOE Patents (OSTI)

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and of light weight. One type of lithium-based cell utilizes a molten salt electrolyte and normally is operated in the temperature range of about 350 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems. The present invention provides an electrochemical cell in which lithium is the electroactive species. The cell has a positive electrode which includes a ternary compound generally represented as Li-M-O, wherein M is a transition metal. Corrosion of the inventive cell is considerably reduced.

Raistrick, I.D.; Godshall, N.A.; Huggins, R.A.

1980-07-30T23:59:59.000Z

366

Ternary compound electrode for lithium cells  

DOE Patents (OSTI)

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and of light weight. One type of lithium-based cell utilizes a molten salt electrolyte and normally is operated in the temperature range of about 350.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems. The present invention provides an electrochemical cell in which lithium is the electroactive species. The cell has a positive electrode which includes a ternary compound generally represented as Li-M-O, wherein M is a transition metal. Corrosion of the inventive cell is considerably reduced.

Raistrick, Ian D. (Menlo Park, CA); Godshall, Ned A. (Stanford, CA); Huggins, Robert A. (Stanford, CA)

1982-01-01T23:59:59.000Z

367

Palladium catalyzed hydrogenation of bio-oils and organic compounds  

DOE Patents (OSTI)

The invention provides palladium-catalyzed hydrogenations of bio-oils and certain organic compounds. Experimental results have shown unexpected and superior results for palladium-catalyzed hydrogenations of organic compounds typically found in bio-oils.

Elliott, Douglas C [Kennewick, WA; Hu, Jianli [Richland, WA; Hart,; Todd, R [Kennewick, WA; Neuenschwander, Gary G [Burbank, WA

2011-06-07T23:59:59.000Z

368

Palladium catalyzed hydrogenation of bio-oils and organic compounds  

DOE Patents (OSTI)

The invention provides palladium-catalyzed hydrogenations of bio-oils and certain organic compounds. Experimental results have shown unexpected and superior results for palladium-catalyzed hydrogenations of organic compounds typically found in bio-oils.

Elliott, Douglas C. (Richland, WA); Hu, Jianli (Kennewick, WA); Hart, Todd R. (Kennewick, WA); Neuenschwander, Gary G. (Burbank, WA)

2008-09-16T23:59:59.000Z

369

Surface passivation process of compound semiconductor material using UV photosulfidation  

DOE Patents (OSTI)

A method for passivating compound semiconductor surfaces by photolytically disrupting molecular sulfur vapor with ultraviolet radiation to form reactive sulfur which then reacts with and passivates the surface of compound semiconductors.

Ashby, Carol I. H. (Edgewood, NM)

1995-01-01T23:59:59.000Z

370

Hydroxyalkyl phosphine compounds for use as diagnostic and therapeutic pharmaceuticals  

DOE Patents (OSTI)

This research discloses a compound and method of making a compound for use as a diagnostic or therapeutic pharmaceutical comprises a functionalized hydroxyalkyl phosphine ligand and a metal combined with the ligand. 16 figs.

Katti, K.V.; Singh, P.R.; Reddy, V.S.; Katti, K.K.; Volkert, W.A.; Ketring, A.R.

1999-03-02T23:59:59.000Z

371

Compound and Elemental Analysis At International Geothermal Area...  

Open Energy Info (EERE)

Indonesia (Laney, 2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At International Geothermal Area...

372

Alloys and Compounds for Thermoelectric and Solar Cell ...  

Science Conference Proceedings (OSTI)

About this Symposium. Meeting, 2014 TMS Annual Meeting & Exhibition. Symposium, Alloys and Compounds for Thermoelectric and Solar Cell Applications II.

373

Method for conversion of .beta.-hydroxy carbonyl compounds  

DOE Patents (OSTI)

A process is disclosed for conversion of salts of .beta.-hydroxy carbonyl compounds forming useful conversion products including, e.g., .alpha.,.beta.-unsaturated carbonyl compounds and/or salts of .alpha.,.beta.-unsaturated carbonyl compounds. Conversion products find use, e.g., as feedstock and/or end-use chemicals.

Lilga, Michael A. (Richland, WA); White, James F. (Richland, WA); Holladay, Johnathan E. (Kennewick, WA); Zacher, Alan H. (Kennewick, WA); Muzatko, Danielle S. (Kennewick, WA); Orth, Rick J. (Kennewick, WA)

2010-03-30T23:59:59.000Z

374

Boron containing amino acid compounds and methods for their use  

DOE Patents (OSTI)

The present invention provides new boron containing amino acid compounds and methods for making these compounds by contacting melphalan or another nitrogen mustard derivative and sodium borocaptate. The present invention also provides a method of treating a mammal having a tumor by administering to the mammal a therapeutically effective amount of the new boron containing amino acid compounds.

Glass, John D. (Shoreham, NY); Coderre, Jeffrey A. (Wading River, NY)

2000-01-01T23:59:59.000Z

375

Catalytic Esterification of Model Compounds of Biomass Pyrolysis Oil  

Science Conference Proceedings (OSTI)

Biomass pyrolysis oil is a complex mixture containing a wide variety of oxygenated compounds, which results in difficulties in bio-oil upgrading. To gain a clearer understanding of the reaction pathways, seven compounds were chosen to represent biomass ... Keywords: pyrolysis oil, model compounds, catalytic esterification

Zuo-gang Guo; Shu-rong Wang; Ying-ying Zhu

2009-10-01T23:59:59.000Z

376

Novel amine-based presursor compounds and composite membranes thereof  

DOE Patents (OSTI)

Novel amine-based precursor compounds comprising the condensation products of dialkylenetriamine and alpha, beta-unsaturated acid halides are disclosed, as well as composite membranes containing such compounds, the membranes being useful in RO-type processes for desalination and the removal of low molecular weight organic compounds such as phenols and carboxylic acids.

Lee, Eric K. L. (Wilmington, DE); Tuttle, Mark E. (Bend, OR)

1989-01-01T23:59:59.000Z

377

Compound parabolic concentrators for narrowband wireless infrared receivers  

E-Print Network (OSTI)

Compound parabolic concentrators for narrowband wireless infrared receivers Keang-Po Ho Joseph M and hollow compound parabolic concentrators (CPCs), for use in free-space infrared communication receivers terms: compound parabolic concentrators (CPCs); optical bandpass fil- ters; Monte Carlo ray tracing

Kahn, Joseph M.

378

Compound Refractive Lenses for Thermal Neutron Applications  

SciTech Connect

This project designed and built compound refractive lenses (CRLs) that are able to focus, collimate and image using thermal neutrons. Neutrons are difficult to manipulate compared to visible light or even x rays; however, CRLs can provide a powerful tool for focusing, collimating and imaging neutrons. Previous neutron CRLs were limited to long focal lengths, small fields of view and poor resolution due to the materials available and manufacturing techniques. By demonstrating a fabrication method that can produce accurate, small features, we have already dramatically improved the focal length of thermal neutron CRLs, and the manufacture of Fresnel lens CRLs that greatly increases the collection area, and thus efficiency, of neutron CRLs. Unlike a single lens, a compound lens is a row of N lenslets that combine to produce an N-fold increase in the refraction of neutrons. While CRLs can be made from a variety of materials, we have chosen to mold Teflon lenses. Teflon has excellent neutron refraction, yet can be molded into nearly arbitrary shapes. We designed, fabricated and tested Teflon CRLs for neutrons. We demonstrated imaging at wavelengths as short as 1.26 ? with large fields of view and achieved resolution finer than 250 ?m which is better than has been previously shown. We have also determined designs for Fresnel CRLs that will greatly improve performance.

Gary, Charles K.

2013-11-12T23:59:59.000Z

379

Development of a complex compound chill storage system  

DOE Green Energy (OSTI)

A thermal energy storage system applicable to industrial refrigeration needs at temperatures as low as {minus}28{degree}C has been developed. The system is based on the chemical bonding between a gaseous refrigerant and a solid salt. The system has been tested successfully in the laboratory and a small unit capable of holding 4 ton-h has been constructed in a factory environment. Much of the development efforts have centered on designing the reactor/heat exchanger where the salt and the refrigerant are combined. Economic evaluations have been made and show an estimated simple rate of return between 30 and 50%. 6 refs., 30 figs.

Rockenfelleer, U.; Kirol, L.

1991-08-01T23:59:59.000Z

380

Determination of total gas in lithium tritide-deuteride compounds  

DOE Green Energy (OSTI)

Lithium tritide--deuteride samples are enclosed in a copper foil and decomposed by heating to 850/sup 0/C in a copper reaction tube in vacuum. The temperature and pressure of the evolved gas, collected in a measured volume using a Toepler pump, are measured to determine the total moles of gas released from the sample. The gas is transferred to a removable sample bulb and, if required, analyzed for gaseous constituents by mass spectrometry. Based on 14 total gas determinations for a lithium deuteride sample, the calculated relative standard deviation was 1.0% and the estimated bias was <2.5%.

Smith, M.E.; Koski, N.L.; Waterbury, G.R.

1979-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Three-electrode low pressure discharge apparatus and method for uniform ionization of gaseous media. [CO/sub 2/ laser oscillator and pulse smoother  

DOE Patents (OSTI)

Uniform, transverse electrical discharges are produced in gaseous media without the necessity of switching the main discharge voltage with an external device which carries the entire discharge current. A three-electrode low pressure discharge tube is charged across its anode and cathode to below breakdown voltage using a dc voltage source. An array of resistors or capacitors can be made to discharge to the wire screen anode by means of a low energy high voltage pulse circuit producing sufficient preionization in the region between the anode and cathode to initiate and control the main discharge. The invention has been demonstrated to be useful as a CO/sub 2/ laser oscillator and pulse-smoother. It can be reliably operated in the sealed-off mode.

McLellan, E.J.

1980-10-17T23:59:59.000Z

382

Integrated modeling of CO2 storage and leakage scenarios including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO2  

SciTech Connect

Storage of CO{sub 2} in saline aquifers is intended to be at supercritical pressure and temperature conditions, but CO{sub 2} leaking from a geologic storage reservoir and migrating toward the land surface (through faults, fractures, or improperly abandoned wells) would reach subcritical conditions at depths shallower than 500-750 m. At these and shallower depths, subcritical CO{sub 2} can form two-phase mixtures of liquid and gaseous CO{sub 2}, with significant latent heat effects during boiling and condensation. Additional strongly non-isothermal effects can arise from decompression of gas-like subcritical CO{sub 2}, the so-called Joule-Thomson effect. Integrated modeling of CO{sub 2} storage and leakage requires the ability to model non-isothermal flows of brine and CO{sub 2} at conditions that range from supercritical to subcritical, including three-phase flow of aqueous phase, and both liquid and gaseous CO{sub 2}. In this paper, we describe and demonstrate comprehensive simulation capabilities that can cope with all possible phase conditions in brine-CO{sub 2} systems. Our model formulation includes: (1) an accurate description of thermophysical properties of aqueous and CO{sub 2}-rich phases as functions of temperature, pressure, salinity and CO{sub 2} content, including the mutual dissolution of CO{sub 2} and H{sub 2}O; (2) transitions between super- and subcritical conditions, including phase change between liquid and gaseous CO{sub 2}; (3) one-, two-, and three-phase flow of brine-CO{sub 2} mixtures, including heat flow; (4) non-isothermal effects associated with phase change, mutual dissolution of CO{sub 2} and water, and (de-) compression effects; and (5) the effects of dissolved NaCl, and the possibility of precipitating solid halite, with associated porosity and permeability change. Applications to specific leakage scenarios demonstrate that the peculiar thermophysical properties of CO{sub 2} provide a potential for positive as well as negative feedbacks on leakage rates, with a combination of self-enhancing and self-limiting effects. Lower viscosity and density of CO{sub 2} as compared to aqueous fluids provides a potential for self-enhancing effects during leakage, while strong cooling effects from liquid CO{sub 2} boiling into gas, and from expansion of gas rising towards the land surface, act to self-limit discharges. Strong interference between fluid phases under three-phase conditions (aqueous - liquid CO{sub 2} - gaseous CO{sub 2}) also tends to reduce CO{sub 2} fluxes. Feedback on different space and time scales can induce non-monotonic behavior of CO{sub 2} flow rates.

Pruess, K.

2011-05-15T23:59:59.000Z

383

Superconducting phases of f-electron compounds  

E-Print Network (OSTI)

Superconductivity was discovered almost a century ago. Yet, unexpected and fascinating new variants of this same old theme are being found at an increasing pace. This is due to great technical advances in materials preparation and an increasingly more systematic screening of new compounds. Prior to the late 1970s all known superconductors could be accounted for in terms of a condensate of Cooper pairs, where the Cooper pairs form due to electron-phonon interactions. With the discovery of the superfluid phases of 3He this understanding began to change in two ways (Osheroff et al., 1972; Vollhardt and Wlfle, 1990). First, 3He provided an example of non-electron-phonon mediated pairing. Second, it provided an example of a superfluid condensate that breaks additional symmetries. The discovery of heavy-fermion superconductivity as a prime candidate for complex order parameter symmetries and non-electron-phonon mediated pairing in f-electron compounds nearly three decades ago was long recognized as an important turning point in the history of superconductivity. However, progress in heavy fermion superconductivity until not long ago seemed to have been slow. In recent years especially the superconductivity in the cuprates, ruthenates, cobaltates, pyrochlores and ironpnictides received great attention. However, a spectacular series of discoveries and developments in f-electron superconductors took place at the same time. While in the first twelve years following the discovery of heavyfermion superconductivity in CeCu2Si2 only five more heavy fermion superconductors could be identified, over twenty five additional systems have been found in the past fifteen years (see Fig. 1). By now over thirty systems are known, about half of which were discovered in the past five years alone. This illustrates the speed of development the field of f-electron superconductivity has picked up despite its long tradition. As a result there is growing appreciation that superconducting phases of f-electron compounds frequently exist at the border of competing and coexisting forms of electronic order. For the majority of systems, including the original heavy-fermion superconductors, an inarXiv:0905.2625v1

Christian Pfleiderer

2009-01-01T23:59:59.000Z

384

Standard test method for the analysis of refrigerant 114, plus other carbon-containing and fluorine-containing compounds in uranium hexafluoride via fourier-transform infrared (FTIR) spectroscopy  

E-Print Network (OSTI)

1.1 This test method covers determining the concentrations of refrigerant-114, other carbon-containing and fluorine-containing compounds, hydrocarbons, and partially or completely substituted halohydrocarbons that may be impurities in uranium hexafluoride. The two options are outlined for this test method. They are designated as Part A and Part B. 1.1.1 To provide instructions for performing Fourier-Transform Infrared (FTIR) spectroscopic analysis for the possible presence of Refrigerant-114 impurity in a gaseous sample of uranium hexafluoride, collected in a "2S" container or equivalent at room temperature. The all gas procedure applies to the analysis of possible Refrigerant-114 impurity in uranium hexafluoride, and to the gas manifold system used for FTIR applications. The pressure and temperatures must be controlled to maintain a gaseous sample. The concentration units are in mole percent. This is Part A. 1.2 Part B involves a high pressure liquid sample of uranium hexafluoride. This method can be appli...

American Society for Testing and Materials. Philadelphia

2004-01-01T23:59:59.000Z

385

Influences of gaseous environment on low growth-rate fatigue crack propagation in steels. Annual report No. 1, January 1980. Report No. FPL/R/80/1030  

DOE Green Energy (OSTI)

The influence of gaseous environment is examined on fatigue crack propagation behavior in steels. Specifically, a fully martensitic 300-M ultrahigh strength steel and a fully bainitic 2-1/4Cr-1Mo lower strength steel are investigated in environments of ambient temperature moist air and low pressure dehumidified hydrogen and argon gases over a wide range of growth rates from 10/sup -8/ to 10/sup -2/ mm/cycle, with particular emphasis given to behavior near the crack propagation threshold ..delta..K/sub 0/. It is found that two distinct growth rate regimes exist where hydrogen can markedly accelerate crack propagation rates compared to air, (1) at near-threshold levels below (5 x 10/sup -6/ mm/cycle) and (2) at higher growth rates, typically around 10/sup -5/ mm/cycle above a critical maximum stress intensity K/sub max//sup T/. Hydrogen-assisted crack propagation at higher growth rates is attributed to a hydrogen embrittlement mechanism, with K/sub max//sup T/ nominally equal to K/sub Iscc/ (the sustained load stress corrosion threshold) in high strength steels, and far below K/sub Iscc/ in the strain-rate sensitive lower strength steels. Hydrogen-assisted crack propagation at near-threshold levels is attributed to a new mechanism involving fretting-oxide-induced crack closure generated in moist (or oxygenated) environments. The absence of hydrogen embrittlement mechanisms at near-threshold levels is supported by tests showing that ..delta..K/sub 0/ values in dry gaseous argon are similar to ..delta..K/sub 0/ values in hydrogen. The potential ramifications of these results are examined in detail.

Ritchie, R.O.; Suresh, S.; Toplosky, J.

1980-01-01T23:59:59.000Z

386

Radiological Control Programs for Special Tritium Compounds  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

84-2004 84-2004 SEPTEMBER 2004 CHANGE NOTICE NO. 1 Date June 2006 DOE HANDBOOK RADIOLOGICAL CONTROL PROGRAMS FOR SPECIAL TRITIUM COMPOUNDS U.S. Department of Energy AREA OCSH Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. NOT MEASUREMENT SENSITIVE ii Table of Changes Page Change 67 (near bottom) In row 1, column 2 of the table titled "dosimetric properties" 6 mrem was changed to 6 x 10 -2 mrem Available on the Department of Energy Technical Standards Program Web site at http://tis.eh.doe.gov/techstds/ DOE-HDBK-1184-2004 iii Foreword The Department of Energy (DOE) and its predecessor agencies have undertaken a wide variety

387

Radiological Control Programs for Special Tritium Compounds  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

F 1325.8 F 1325.8 (08-93) United States Government Department of Energy memorandum DATE: May 11, 2006 REPLY TO EH-52:JRabovsky:3-2 135 ATTN OF: APPROVAL OF CHANGE NOTICE 1 TO DEPARTMENT OF ENERGY (DOE) SUBJECT. HANDBOOK 1184-2004, RADIOLOGICAL CONTROL PROGRAMS FOR SPECIAL TRITIUM COMPOUNDS TO: Dennis Kubicki, EH-24 Technical Standards Manager This memorandum forwards the subject Change Notice 1 to DOE Handbook, DOE- HDBK- 1184-2004, which has approved for publication and distribution. The change to this handbook consists of a correction to the rule of thumb, listed in Appendix A, for converting the uptake of tritium oxide into radiation dose. A factor of 1/100 was inadvertently omitted from this rule of thumb when this DOE Handbook was originally published. This change does not affect the references, is not of a technical nature, and

388

Clathrate compounds and method of manufacturing  

DOE Patents (OSTI)

The present invention comprises new materials, material structures, and processes of fabrication of such that may be used in technologies involving the conversion of light to electricity and/or heat to electricity, and in optoelectronics technologies. The present invention provide for the fabrication of a clathrate compound comprising a type II clathrate lattice with atoms of silicon and germanium as a main framework forming lattice spacings within the framework, wherein the clathrate lattice follows the general formula Si.sub.136-yGe.sub.y, where y indicates the number of Ge atoms present in the main framework and 136-y indicates the number of Si atoms present in the main framework, and wherein y>0.

Nolas, George S. (Tampa, FL); Witanachchi, Sarath (Tampa, FL); Mukherjee, Pritish (Tampa, FL)

2009-05-19T23:59:59.000Z

389

IRRADIATION METHOD OF CONVERTING ORGANIC COMPOUNDS  

DOE Patents (OSTI)

A method is given for changing the distribution of organic compounds from that produced by the irradiation of bulk alkane hydrocarbons. This method consists of depositing an alkane hydrocarbon on the surface of a substrate material and irradiating with gamma radiation at a dose rate of more than 100,000 rads. The substrate material may be a metal, metal salts, metal oxides, or carbons having a surface area in excess of 1 m/sup 2//g. The hydrocarbons are deposited in layers of from 0.1 to 10 monolayers on the surfaces of these substrates and irradiated. The product yields are found to vary from those which result from the irradiation of bulk hydrocarbons in that there is an increase in the quantity of branched hydrocarbons.

Allen, A.O.; Caffrey, J.M. Jr.

1960-10-11T23:59:59.000Z

390

Fission Barriers of Compound Superheavy Nuclei  

E-Print Network (OSTI)

The dependence of fission barriers on the excitation energy of the compound nucleus impacts the survival probability of superheavy nuclei synthesized in heavy-ion fusion reactions. In this work, we investigate the isentropic fission barriers by means of the self-consistent nuclear density functional theory. The relationship between isothermal and isentropic descriptions is demonstrated. Calculations have been carried out for $^{264}$Fm, $^{272}$Ds, $^{278}$112, $^{292}$114, and $^{312}$124. For nuclei around $^{278}$112 produced in "cold fusion" reactions, we predict a more rapid decrease of fission barriers with excitation energy as compared to the nuclei around $^{292}$114 synthesized in "hot fusion" experiments. This is explained in terms of the difference between the ground-state and saddle-point temperatures. The effect of the particle gas is found to be negligible in the range of temperatures studied.

J. C. Pei; W. Nazarewicz; J. A. Sheikh; A. K. Kerman

2009-01-07T23:59:59.000Z

391

Steam generation in compound parabolic concentrator collectors  

SciTech Connect

This report describes the advantages of generating steam directly in a nonimaging compound parabolic concentrator (CPC) collector rather than using a heat-transfer fluid and a secondary heat exchanger. The predicted performance advantages from generating steam directly in CPC collectors are significant, and that performance has ben verified using a collector built and tested at Argonne National Laboratory. The collector and the method used to test its operation in a steam-generating mode are described. Test results are included for a 6.4-m/sup 2/ array of evacuated tube collectors with an advanced absorber coating, silver reflectors, and tubes oriented in a north-south configuration. Also described are the test methods and results for indoor testing for heat loss by the collectors and outdoor testing of their instantaneous optical efficiency.

Allen, J.W.; Schertz, W.W.; Wantroba, A.S.

1985-08-01T23:59:59.000Z

392

Separation of polar shale oil compounds using high-speed liquid chromatography. [Compounds known to exist in shale oil  

DOE Green Energy (OSTI)

Methods for separation of potentially toxic compounds from shale oil and its waste products by high-speed liquid chromatography (HSLC) are discussed. The following classes of compounds were selected for study: aromatic and polynuclear aromatic hydrocarbons, thiophenes, and indoles. No attempt was made to identify or quantitate compounds in shale oil, but it was demonstrated that HSLC can be a rapid and sensitive method for the separation of polar compounds from classes recognized to be present in shale oil and its waste products. Specific compounds studied were: phenanthrene, naphthalene, anthracene, pyrene, triphenylene, chrysene, benzo(a)pyrene, 1,2,3,4-dibenzanthracene, and 1,2,5,6-dibenzanthracene. (JGB)

Riley, R.G.

1976-11-01T23:59:59.000Z

393

Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds  

E-Print Network (OSTI)

efficiency by sulfur and/or chlorine containing compounds atfired Flue Gas by Sulfur-chlorine Compounds Nai-Qiang Yanremoval. Two sulfur-chlorine compounds, sulfur dichloride (

Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

2008-01-01T23:59:59.000Z

394

THE PREPARATION OF RHENIUM FROM IODO COMPOUNDS  

SciTech Connect

Potassium hexaiodorhenate (IV) decomposes in vacuo at 500 maiinly to potassium iodide, rhenium and iodine. At 700 potassium iodide sublimes off to leave an iodinefree product, but analyses showed retention of potassium. This cannot be ascribed to the retention of alkali as in the hydrogen reduction of potassium perrhenate, and it indicates that an unsolvated potassium rhenide is stable at high temperatures. Ammonium hexaiodorhenate (IV) prepared quaatitatively from rhenium heptoxide decomposes quantitatively to rhenium at 700 in vacuo. A compound approximating to rhenium tri-iodide was prepared by evaporating the eluate, obtained by passing potassium hexachlororhenate in hydrochloric acid through a cation exchange column, to dryness with hydriodic acid. This iodide also decomposed to rhenium in vacuo. We have confirmed and extended the observations thai rhenium iodides cannot be prepared by direct combination alone or in complexing and non-complexing solvents for iodine. The hexaiodorhenates can be prepared quantitatively from the corresponding chlorides. It has been shown that the series K/sub 2/ReCl/sub 6/, K/sub 2/ReBrI/sub 6/ can be interconvented in either direction with the appropriate halogen acids but with greater difficulty to the left. The hexachloro salt is converted to potassium perrhenate and bifiuoride with hydrofluoric acid and not to the hexafluoro salt. The last resembles the hexaffluoro iridate and not osmate or platinate. (auth)

Woolf, A.A.

1958-10-01T23:59:59.000Z

395

Flash vacuum pyrolysis of lignin model compounds  

DOE Green Energy (OSTI)

Despite the extensive research into the pyrolysis of lignin, the underlying chemical reactions that lead to product formation are poorly understood. Detailed mechanistic studies on the pyrolysis of biomass and lignin under conditions relevant to current process conditions could provide insight into utilizing this renewable resource for the production of chemicals and fuel. Currently, flash or fast pyrolysis is the most promising process to maximize the yields of liquid products (up to 80 wt %) from biomass by rapidly heating the substrate to moderate temperatures, typically 500{degrees}C, for short residence times, typically less than two seconds. To provide mechanistic insight into the primary reaction pathways under process relevant conditions, we are investigating the flash vacuum pyrolysis (FVP) of lignin model compounds that contain a {beta}-ether. linkage and {alpha}- or {gamma}-alcohol, which are key structural elements in lignin. The dominant products from the FVP of PhCH{sub 2}CH{sub 2}OPh (PPE), PhC(OH)HCH{sub 2}OPh, and PhCH{sub 2}CH(CH{sub 2}OH)OPh at 500{degrees}C can be attributed to homolysis of the weakest bond in the molecule (C-O bond) or 1,2-elimination. Surprisingly, the hydroxy-substituent dramatically increases the decomposition of PPE. It is proposed that internal hydrogen bonding is accelerating the reaction.

Cooney, M.J.; Britt, P.F.; Buchanan, A.C. III

1997-03-01T23:59:59.000Z

396

Volatile organic compound remedial action project  

SciTech Connect

This Environmental Assessment (EA) reviews a proposed project that is planned to reduce the levels of volatile organic compound (VOC) contaminants present in the Mound domestic water supply. The potable and industrial process water supply for Mound is presently obtained from a shallow aquifer via on-site production wells. The present levels of VOCs in the water supply drawn from the on-site wells are below the maximum contaminant levels (MCLs) permissible for drinking water under Safe Drinking Water Act (SDWA; 40 CFR 141); however, Mound has determined that remedial measures should be taken to further reduce the VOC levels. The proposed project action is the reduction of the VOC levels in the water supply using packed tower aeration (PTA). This document is intended to satisfy the requirements of the National Environmental Policy Act (NEPA) of 1969 and associated Council on Environmental Quality regulations (40 CFR parts 1500 through 1508) as implemented through U.S. Department of Energy (DOE) Order 5440.1D and supporting DOE NEPA Guidelines (52 FR 47662), as amended (54 FR 12474; 55 FR 37174), and as modified by the Secretary of Energy Notice (SEN) 15-90 and associated guidance. As required, this EA provides sufficient information on the probable environmental impacts of the proposed action and alternatives to support a DOE decision either to prepare an Environmental Impact Statement (EIS) or issue a Finding of No Significant Impact (FONSI).

NONE

1991-12-01T23:59:59.000Z

397

Chemical and Radiological Toxicity of Uranium and Its Compounds  

SciTech Connect

The concentration of uranyl nitrate required to deliver the radiation dose limit for soluble uranium compounds is larger than the toxicity-based concentration limits. Therefore, for soluble uranium compounds, health consequences of exposure are primarily due to their chemical toxicity. For insoluble compounds of uranium, health consequences (e.g., fibrosis and/or carcinogenesis of the lung) are primarily due to irradiation of pulmonary tissues from inhaled respirable particles.

Tansky, R.R.

2001-07-26T23:59:59.000Z

398

Boron compounds as anion binding agents for nonaqueous battery electrolytes  

DOE Patents (OSTI)

Novel fluorinated boron-based compounds which act as anion receptors in non-aqueous battery electrolytes are provided. When added to non-aqueous battery electrolytes, the fluorinated boron-based compounds of the invention enhance ionic conductivity and cation transference number of non-aqueous electrolytes. The fluorinated boron-based anion receptors include borane and borate compounds bearing different fluorinated alkyl and aryl groups.

Lee, Hung Sui (East Setauket, NY); Yang, Xia-Oing (Port Jefferson Station, NY); McBreen, James (Bellport, NY); Xiang, Caili (Upton, NY)

2000-02-08T23:59:59.000Z

399

Compound and Elemental Analysis At Salt Wells Area (Coolbaugh...  

Open Energy Info (EERE)

Technique Compound and Elemental Analysis Activity Date 2005 - 2005 Usefulness useful DOE-funding Unknown Exploration Basis Geochemical water sampling, mineral distribution...

400

Method for conversion of .beta.-hydroxy carbonyl compounds ...  

A process is disclosed for conversion of salts of .beta.-hydroxy carbonyl compounds forming useful conversion products including, e.g., .alpha.,.beta.-unsaturated ...

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Process for preparing a chemical compound enriched in isotope content  

DOE Patents (OSTI)

A process to prepare a chemical enriched in isotope content which includes: (a) A chemical exchange reaction between a first and second compound which yields an isotopically enriched first compound and an isotopically depleted second compound; (b) the removal of a portion of the first compound as product and the removal of a portion of the second compound as spent material; (c) the conversion of the remainder of the first compound to the second compound for reflux at the product end of the chemical exchange reaction region; (d) the conversion of the remainder of the second compound to the first compound for reflux at the spent material end of the chemical exchange region; and the cycling of the additional chemicals produced by one conversion reaction to the other conversion reaction, for consumption therein. One of the conversion reactions is an oxidation reaction, and the energy that it yields is used to drive the other conversion reaction, a reduction. The reduction reaction is carried out in a solid polymer electrolyte electrolytic reactor. The overall process is energy efficient and yields no waste by-products.

Michaels, Edward D. (Spring Valley, OH)

1982-01-01T23:59:59.000Z

402

Compound and Elemental Analysis At Fish Lake Valley Area (Deymonaz...  

Open Energy Info (EERE)

ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Fish Lake Valley Area (Deymonaz, Et Al., 2008) Exploration Activity Details Location Fish...

403

Compound and Elemental Analysis At Fish Lake Valley Area (DOE...  

Open Energy Info (EERE)

ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Fish Lake Valley Area (DOE GTP) Exploration Activity Details Location Fish Lake Valley Area...

404

Testing of Selected Self-Leveling Compounds for Floors  

Science Conference Proceedings (OSTI)

... was not attempted, because the rank would depend on the tight given to each ... The mixes were neat self-leveling compounds without added sand. ...

1997-09-03T23:59:59.000Z

405

Supercritical Water Gasification of Biomass & Biomass Model Compounds.  

E-Print Network (OSTI)

??Supercritical water gasification (SCWG) is an innovative, modern, and effective destruction process for the treatment of organic compounds. Hydrogen production using SCWG of biomass or (more)

Youssef, Emhemmed A.E.A

2011-01-01T23:59:59.000Z

406

Technologies for Extracting Valuable Metals and Compounds from...  

Open Energy Info (EERE)

Project Jump to: navigation, search Last modified on July 22, 2011. Project Title Technologies for Extracting Valuable Metals and Compounds from Geothermal Fluids Project...

407

Recovery of mercury from mercury compounds via electrolytic methods  

DOE Patents (OSTI)

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

1988-01-01T23:59:59.000Z

408

Recovery of mercury from mercury compounds via electrolytic methods  

DOE Patents (OSTI)

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg[sub 2]Cl[sub 2] employing as the electrolyte solution a mixture of HCl and H[sub 2]O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H[sub 2]O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds. 3 figs.

Grossman, M.W.; George, W.A.

1989-11-07T23:59:59.000Z

409

Recovery of mercury from mercury compounds via electrolytic methods  

DOE Patents (OSTI)

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

1989-01-01T23:59:59.000Z

410

Recovery of mercury from mercury compounds via electrolytic methods  

DOE Patents (OSTI)

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg.sub.2 Cl.sub.2 employing as the electrolyte solution a mixture of HCl and H.sub.2 O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H.sub.2 O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds.

Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

1991-01-01T23:59:59.000Z

411

Recovery of mercury from mercury compounds via electrolytic methods  

DOE Patents (OSTI)

A process for electrolytically recovering mercury from mercury compounds is provided. In one embodiment, Hg is recovered from Hg[sub 2]Cl[sub 2] employing as the electrolyte solution a mixture of HCl and H[sub 2]O. In another embodiment, Hg is electrolytically recovered from HgO wherein the electrolyte solution is comprised of glacial acetic acid and H[sub 2]O. Also provided is an apparatus for producing isotopically enriched mercury compounds in a reactor and then transporting the dissolved compounds into an electrolytic cell where mercury ions are electrolytically reduced and elemental mercury recovered from the mercury compounds. 3 figures.

Grossman, M.W.; George, W.A.

1991-06-18T23:59:59.000Z

412

Compound and Elemental Analysis At Flint Geothermal Area (DOE...  

Open Energy Info (EERE)

Geothermal Area (DOE GTP) Exploration Activity Details Location Flint Geothermal Area Exploration Technique Compound and Elemental Analysis Activity Date Usefulness not indicated...

413

Compound and Elemental Analysis At Little Valley Area (Wood,...  

Open Energy Info (EERE)

Area (Wood, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Little Valley Area (Wood, 2002) Exploration...

414

Alloys and Compounds for Thermoelectric and Solar Cell Applications  

Science Conference Proceedings (OSTI)

Jul 31, 2012 ... TMS: Energy Conversion and Storage Committee ... of the alloys and compounds used in the thermoelectric and solar cell devices. Materials of...

415

Process for synthesizing compounds from elemental powders and product  

DOE Patents (OSTI)

A process for synthesizing intermetallic compounds from elemental powders. The elemental powders are initially combined in a ratio which approximates the stoichiometric composition of the intermetallic compound. The mixed powders are then formed into a compact which is heat treated at a controlled rate of heating such that an exothermic reaction between the elements is initiated. The heat treatment may be performed under controlled conditions ranging from a vacuum (pressureless sintering) to compression (hot pressing) to produce a desired densification of the intermetallic compound. In a preferred form of the invention, elemental powders of Fe and Al are combined to form aluminide compounds of Fe.sub.3 Al and FeAl.

Rabin, Barry H. (Idaho Falls, ID); Wright, Richard N. (Idaho Falls, ID)

1993-01-01T23:59:59.000Z

416

Compound and Elemental Analysis At International Geothermal Area...  

Open Energy Info (EERE)

Mexico (Norman & Moore, 2004) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At International Geothermal Area...

417

Effects of gaseous NH{sub 3} and SO{sub 2} on the concentration profiles of PCDD/F in flyash under post-combustion zone conditions  

Science Conference Proceedings (OSTI)

Highlights: Black-Right-Pointing-Pointer Influence of NH{sub 3} and SO{sub 2} on 2378-PCDD/F in flyash and flue gases was investigated. Black-Right-Pointing-Pointer NH{sub 3} decreased the concentration of PCDD and PCDF by 34-75% in the flyash. Black-Right-Pointing-Pointer NH{sub 3} decreased the concentration of PCDD and PCDF by 21-40% from the flue gases. Black-Right-Pointing-Pointer SO{sub 2} led to 99% PCDD and 93% PCDF reductions in the flyash. Black-Right-Pointing-Pointer SO{sub 2} led to 89% PCDD and 76% PCDF reductions in the flue gases. - Abstract: The influence of gaseous ammonia and sulphur dioxide on the formation of 2378-substituted PCDD/F on a reference flyash from a municipal waste incinerator has been investigated using a laboratory scale fixed-bed reactor. The reference flyash samples (BCR-490) was reacted under a simulated flue gas stream at temperatures of 225 and 375 Degree-Sign C for 96 h. The experiments were carried out in two series: first with simulated flue gas alone, and then with injection of NH{sub 3} or SO{sub 2} gas into the flue gas just before the reactor inlet. It was found that the injection of gaseous ammonia into the flue gas could decrease the concentration of both PCDD and PCDF by 34-75% from the solid phase and by 21-40% from the gas phase. Converting the results to I-TEQ values, it could reduce the total I-TEQ values of PCDD and PCDF in the sum of the flyash and exhaust flue gas by 42-75% and 24-57% respectively. The application of SO{sub 2} led to 99% and 93% reductions in the PCDD and PCDF average congener concentrations, respectively in the solid phase. In the gas phase, the total reductions were 89% and 76% for PCDD and PCDF, respectively. Moreover, addition of SO{sub 2} reduced the total I-TEQ value of PCDD and PCDF in the flyash and exhaust flue gas together by 60-86% and 72-82% respectively. Sulphur dioxide was more effective than ammonia in suppressing PCDD/F formation in flyash under the conditions investigated.

Hajizadeh, Yaghoub; Onwudili, Jude A. [Energy Research Institute, University of Leeds, Leeds LS2 9JT (United Kingdom); Williams, Paul T., E-mail: p.t.williams@leeds.ac.uk [Energy Research Institute, University of Leeds, Leeds LS2 9JT (United Kingdom)

2012-07-15T23:59:59.000Z

418

Polymers containing borane or carborane cage compounds and related applications  

DOE Patents (OSTI)

Polymers comprising residues of borane and/or carborane cage compound monomers having at least one polyalkoxy silyl substituent. Such polymers can further comprise one or more reactive matrices and/or co-monomers covalently bound with the cage compound monomer residues. Methods of making and applications for using such polymers are also disclosed.

Bowen, III, Daniel E. (Olathe, KS); Eastwood, Eric A. (Raymore, MO)

2012-06-05T23:59:59.000Z

419

Process for reducing aromatic compounds in ethylenediamine with calcium  

DOE Patents (OSTI)

Olefins are produced by containing an organic compound having at least one benzene ring with ethylenediamine and calcium metal, the calcium metal being used in large excess or alternatively in conjunction with an inert abrasive particulate substance. Substantially all of the organic compounds are converted to corresponding cyclic olefins, largely mono-olefins.

Benkeser, R.A.; Laugal, J.A.; Rappa, A.

1985-08-06T23:59:59.000Z

420

Process for reducing aromatic compounds in ethylenediamine with calcium  

DOE Patents (OSTI)

Olefins are produced by containing an organic compound having at least one benzene ring with ethylenediamine and calcium metal, the calcium metal being used in large excess or alternatively in conjunction with an inert abrasive particulate substance. Substantially all of the organic compounds are converted to corresponding cyclic olefins, largely mono-olefins.

Benkeser, Robert A. (West Lafayette, IN); Laugal, James A. (Lostant, IL); Rappa, Angela (Baltimore, MD)

1985-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Redox chromophore compounds and electrodes of metal containing substituted bipyridines  

DOE Patents (OSTI)

Chromophoric compounds, each having a wide range of distinct color changes in response to changes in the oxidation states thereof, are provided in the form of polymerizable monomers, and polymers thereof, of certain metal containing, and electron group substituted, 2,2'-bipyridine compounds.

Elliott, Cecil M. (Fort Collins, CO); Redepenning, Jody G. (Fort Collins, CO)

1986-01-01T23:59:59.000Z

422

Semantic interpretation of noun compounds using verbal and other paraphrases  

Science Conference Proceedings (OSTI)

We study the problem of semantic interpretation of noun compounds such as bee honey, malaria mosquito, apple cake, and stem cell. In particular, we explore the potential of using predicates that make explicit the hidden relation ... Keywords: Lexical semantics, Web as a corpus, machine translation, multiword expressions, noun compounds, paraphrases

Preslav I. Nakov; Marti A. Hearst

2013-07-01T23:59:59.000Z

423

Multicolor Maps from Compound Queries | OpenEI Community  

Open Energy Info (EERE)

Multicolor Maps from Compound Queries Multicolor Maps from Compound Queries Home > Groups > OpenEI Community Central Jweers's picture Submitted by Jweers(83) Contributor 16 May, 2013 - 14:22 ask queries compound queries developer Google maps maps multicolor result formats results Semantic Mediawiki Hi all, Recently, a couple of people on OpenEI have asked me how to do compound (or multicolor) maps like this one: Thanks to the new Google Maps v3 API, this is really easy. I put together a quick sample of how this is done, complete with code snippits, here: http://en.openei.org/wiki/User:Jweers/Test5. First, create a compound query, then atttribute a custom marker icon to each query using the ;param=value syntax. The new OpenEI maps extension will take care of the rest. Here is an example of it in use on OpenEI by NREL's Geothermal team:

424

Compound and Elemental Analysis At Fenton Hill Hdr Geothermal Area  

Open Energy Info (EERE)

Compound and Elemental Analysis At Fenton Hill Hdr Geothermal Area Compound and Elemental Analysis At Fenton Hill Hdr Geothermal Area (Brookins & Laughlin, 1983) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Fenton Hill Hdr Geothermal Area (Brookins & Laughlin, 1983) Exploration Activity Details Location Fenton Hill Hdr Geothermal Area Exploration Technique Compound and Elemental Analysis Activity Date Usefulness not indicated DOE-funding Unknown Notes Fenton Hill HDR Site References D. G. Brookins, A. W. Laughlin (1983) Rb-Sr Geochronologic Investigation Of Precambrian Samples From Deep Geothermal Drill Holes, Fenton Hill, New Mexico Retrieved from "http://en.openei.org/w/index.php?title=Compound_and_Elemental_Analysis_At_Fenton_Hill_Hdr_Geothermal_Area_(Brookins_%26_Laughlin,_1983)&oldid=511281"

425

Definition: Compound and Elemental Analysis | Open Energy Information  

Open Energy Info (EERE)

Definition Definition Edit with form History Facebook icon Twitter icon » Definition: Compound and Elemental Analysis Jump to: navigation, search Dictionary.png Compound and Elemental Analysis Compound and elemental analysis is a process where a sample of some material (e.g., soil, waste or drinking water, bodily fluids, minerals, chemical compounds) is analyzed for its elements and compounds and sometimes its isotopic composition. Elemental analysis can be qualitative (determining what elements are present), and it can also be quantitative (determining how much of each type are present).[1] View on Wikipedia Wikipedia Definition References ↑ http://en.wikipedia.org/wiki/Elemental_analysis Ret Like Like You like this.Sign Up to see what your friends like. rieved from

426

Corona method and apparatus for altering carbon containing compounds  

DOE Patents (OSTI)

The present invention is a method and apparatus for altering a carbon containing compound in an aqueous mixture. According to a first aspect of the present invention, it has been discovered that for an aqueous mixture having a carbon containing compound with an ozone reaction rate less than the ozone reaction rate of pentachlorophenol, use of corona discharge in a low or non-oxidizing atmosphere increases the rate of destruction of the carbon containing compound compared to corona discharge an oxidizing atmosphere. For an aqueous mixture containing pentachlorphenol, there was essentially no difference in destruction between atmospheres. According to a second aspect of the present invention, it has been further discovered that an aqueous mixture having a carbon containing compound in the presence of a catalyst and oxygen resulted in an increased destruction rate of the carbon containing compound compared to no catalyst.

Sharma, Amit K. (Richland, WA); Camaioni, Donald M. (Richland, WA); Josephson, Gary B. (Richland, WA)

1999-01-01T23:59:59.000Z

427

Device for collecting chemical compounds and related methods  

SciTech Connect

A device for sampling chemical compounds from fixed surfaces and related methods are disclosed. The device may include a vacuum source, a chamber and a sorbent material. The device may utilize vacuum extraction to volatilize the chemical compounds from the fixed surfaces so that they may be sorbed by the sorbent material. The sorbent material may then be analyzed using conventional thermal desorption/gas chromatography/mass spectrometry (TD/GC/MS) instrumentation to determine presence of the chemical compounds. The methods may include detecting release and presence of one or more chemical compounds and determining the efficacy of decontamination. The device may be useful in collection and analysis of a variety of chemical compounds, such as residual chemical warfare agents, chemical attribution signatures and toxic industrial chemicals.

Scott, Jill R.; Groenewold, Gary S.; Rae, Catherine

2013-01-01T23:59:59.000Z

428

Corona Method And Apparatus For Altering Carbon Containing Compounds  

DOE Patents (OSTI)

The present invention is a method and apparatus for altering a carbon-containing compound in an aqueous mixture. According to a first aspect of the present invention, it has been discovered that for an aqueous mixture having a carbon containing compound with an ozone reaction rate less than the ozone reaction rate of pentachlorophenol, use of corona discharge in a low or non-oxidizing atmosphere increases the rate of destruction of the carbon containing compound compared to corona discharge an oxidizing atmosphere. For an aqueous mixture containing pentachlorphenol, there was essentially no difference in destruction between atmospheres. According to a second aspect of the present invention, it has been further discovered that an aqueous mixture having a carbon-containing compound in the presence of a catalyst and oxygen resulted in an increased destruction rate of the carbon containing compound compared to no catalyst.

Sharma, Amit K. (Plainsboro, NJ); Camaioni, Donald M. (Richland, WA); Josephson; Gary B. (Richland, WA)

2004-05-04T23:59:59.000Z

429

Improved estimates of separation distances to prevent unacceptable damage to nuclear power plant structures from hydrogen detonation for gaseous hydrogen storage. Technical report  

DOE Green Energy (OSTI)

This report provides new estimates of separation distances for nuclear power plant gaseous hydrogen storage facilities. Unacceptable damage to plant structures from hydrogen detonations will be prevented by having hydrogen storage facilities meet separation distance criteria recommended in this report. The revised standoff distances are based on improved calculations on hydrogen gas cloud detonations and structural analysis of reinforced concrete structures. Also, the results presented in this study do not depend upon equivalencing a hydrogen detonation to an equivalent TNT detonation. The static and stagnation pressures, wave velocity, and the shock wave impulse delivered to wall surfaces were computed for several different size hydrogen explosions. Separation distance equations were developed and were used to compute the minimum separation distance for six different wall cases and for seven detonating volumes (from 1.59 to 79.67 lbm of hydrogen). These improved calculation results were compared to previous calculations. The ratio between the separation distance predicted in this report versus that predicted for hydrogen detonation in previous calculations varies from 0 to approximately 4. Thus, the separation distances results from the previous calculations can be either overconservative or unconservative depending upon the set of hydrogen detonation parameters that are used. Consequently, it is concluded that the hydrogen-to-TNT detonation equivalency utilized in previous calculations should no longer be used.

Not Available

1994-05-01T23:59:59.000Z

430

Thermal discharges from Paducah Gaseous Diffusion Plant outfalls: Impacts on stream temperatures and fauna of Little Bayou and Big Bayou Creeks  

SciTech Connect

The development of a biological monitoring plan for the receiving streams of the Paducah Gaseous Diffusion Plant (PGDP) began in the late 1980s, because of an Agreed Order (AO) issued in September 1987 by the Kentucky Division of Water (KDOW). Five years later, in September 1992, more stringent effluent limitations were imposed upon the PGDP operations when the KDOW reissued Kentucky Pollutant Discharge Elimination System permit No. KY 0004049. This action prompted the US Department of Energy (DOE) to request a stay of certain limits contained in the permit. An AO is being negotiated between KDOW, the US Enrichment Corporation (USEC), and DOE that will require that several studies be conducted, including this stream temperature evaluation study, in an effort to establish permit limitations. All issues associated with this AO have been resolved, and the AO is currently being signed by all parties involved. The proposed effluent temperature limit is 89 F (31.7 C) as a mean monthly temperature. In the interim, temperatures are not to exceed 95 F (35 C) as a monthly mean or 100 F (37.8 C) as a daily maximum. This study includes detailed monitoring of instream temperatures, benthic macroinvertebrate communities, fish communities, and a laboratory study of thermal tolerances.

Roy, W.K.; Ryon, M.G.; Hinzman, R.L. [Oak Ridge National Lab., TN (United States). Computer Science and Mathematics Div.

1996-03-01T23:59:59.000Z

431

A 40 Myr OLD GASEOUS CIRCUMSTELLAR DISK AT 49 CETI: MASSIVE CO-RICH COMET CLOUDS AT YOUNG A-TYPE STARS  

Science Conference Proceedings (OSTI)

The gaseous molecular disk that orbits the main-sequence A-type star 49 Ceti has been known since 1995, but the stellar age and the origin of the observed carbon monoxide molecules have been unknown. We now identify 49 Ceti as a member of the 40 Myr old Argus Association and present a colliding comet model to explain the high CO concentrations seen at 49 Ceti and the 30 Myr old A-type star HD 21997. The model suggests that massive-400 Earth mass-analogs of the Sun's Kuiper Belt are in orbit around some A-type stars, that these large masses are composed primarily of comet-like objects, and that these objects are rich in CO and perhaps also CO{sub 2}. We identify additional early-type members of the Argus Association and the Tucana/Horologium and Columba Associations; some of these stars display excess mid-infrared emission as measured with the Widefield Infrared Survey Explorer.

Zuckerman, B. [Department of Physics and Astronomy, University of California, Los Angeles, CA 90095 (United States); Song, Inseok, E-mail: ben@astro.ucla.edu, E-mail: song@physast.uga.edu [Department of Physics and Astronomy, University of Georgia, Athens, GA 30602-2451 (United States)

2012-10-20T23:59:59.000Z

432

Potential Hazards Relating to Pyrolysis of c-C{sub 4}F{sub 8} in Selected Gaseous Diffusion Plant Operations  

SciTech Connect

As part of a program intended to replace the present evaporative coolant at the gaseous diffusion plants (GDPs) with a non-ozone-depleting alternate, a series of investigations of the suitability of candidate substitutes in under way. One issue concerning a primary candidate, c-C4F8, is the possibility that it might produce the highly toxic perfluoroisobutylene (PFIB) in high temperature environments. This study was commissioned to determine the likelihood and severity of decomposition under two specific high temperature thermal environments, namely the use of a flame test for the presence of coolant vapors and welding in the presence of coolant vapors. The purpose of the study was to develop and evaluate available data to provide information that will allow the technical and industrial hygiene staff at the GDPs to perform appropriate safety evaluations and to determine the need for field testing or experimental work. The scope of this study included a literature search and an evaluation of the information developed therefrom. Part of that evaluation consists of chemical kinetics modeling of coolant decomposition in the two operational environments. The general conclusions are that PFIB formation is unlikely in either situation but that it cannot be ruled out completely under extreme conditions. The presence of oxygen, moisture, and combustion products will tend to lead to formation of oxidation products (COF2, CO, CO2, and HF) rather than PFIB.

Trowbridge, L.D.

1999-03-01T23:59:59.000Z

433

Verification experiment on the downblending of high enriched uranium (HEU) at the Portsmouth Gaseous Diffusion Plant. Digital video surveillance of the HEU feed stations  

SciTech Connect

As part of a Safeguards Agreement between the US and the International Atomic Energy Agency (IAEA), the Portsmouth Gaseous Diffusion Plant, Piketon, Ohio, was added to the list of facilities eligible for the application of IAEA safeguards. Currently, the facility is in the process of downblending excess inventory of HEU to low enriched uranium (LEU) from US defense related programs for commercial use. An agreement was reached between the US and the IAEA that would allow the IAEA to conduct an independent verification experiment at the Portsmouth facility, resulting in the confirmation that the HEU was in fact downblended. The experiment provided an opportunity for the DOE laboratories to recommend solutions/measures for new IAEA safeguards applications. One of the measures recommended by Sandia National Laboratories (SNL), and selected by the IAEA, was a digital video surveillance system for monitoring activity at the HEU feed stations. This paper describes the SNL implementation of the digital video system and its integration with the Load Cell Based Weighing System (LCBWS) from Oak Ridge National Laboratory (ORNL). The implementation was based on commercially available technology that also satisfied IAEA criteria for tamper protection and data authentication. The core of the Portsmouth digital video surveillance system was based on two Digital Camera Modules (DMC-14) from Neumann Consultants, Germany.

Martinez, R.L.; Tolk, K. [Sandia National Labs., Albuquerque, NM (United States); Whiting, N. [International Atomic Energy Agency, Vienna (Austria); Castleberry, K.; Lenarduzzi, R. [Oak Ridge National Lab., TN (United States)

1998-08-01T23:59:59.000Z

434

Applicable or relevant and appropriate requirements (ARARs) for remedial actions at the Paducah Gaseous Diffusion Plant: A compendium of environmental laws and guidance  

Science Conference Proceedings (OSTI)

Section 121 of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) of 1980 specifies that remedial actions for cleanup of hazardous substances found at sites placed on the National Priorities List (NPL) by the US Environmental Protection Agency (EPA) must comply with applicable or relevant and appropriate requirements (ARARs) or standards under federal and state environmental laws. To date, the US Department of Energy (DOE) Paducah Gaseous Diffusion Plant (PGDP) has not been on the NPL. Although DOE and EPA have entered into an Administrative Consent Order (ACO), the prime regulatory authority for cleanup at PGDP will be the Resource Conservation and Recovery Act (RCRA). This report supplies a preliminary list of available federal and state ARARs that might be considered for remedial response at PGDP in the event that the plant becomes included on the NPL or the ACO is modified to include CERCLA cleanup. A description of the terms applicable'' and relevant and appropriate'' is provided, as well as definitions of chemical-, location-, and action-specific ARARS. ARARs promulgated by the federal government and by the state of Kentucky are listed in tables. In addition, the major provisions of RCRA, the Safe Drinking Water Act, the Clean Water Act, the Clean Air Act, and other acts, as they apply to hazardous and radioactive waste cleanup, are discussed.

Etnier, E.L.; Eaton, L.A. (Oak Ridge National Lab., TN (United States))

1992-03-01T23:59:59.000Z

435

Applicable or relevant and appropriate requirements (ARARs) for remedial actions at the Paducah Gaseous Diffusion Plant: A compendium of environmental laws and guidance. Environmental Restoration Program  

Science Conference Proceedings (OSTI)

Section 121 of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) of 1980 specifies that remedial actions for cleanup of hazardous substances found at sites placed on the National Priorities List (NPL) by the US Environmental Protection Agency (EPA) must comply with applicable or relevant and appropriate requirements (ARARs) or standards under federal and state environmental laws. To date, the US Department of Energy (DOE) Paducah Gaseous Diffusion Plant (PGDP) has not been on the NPL. Although DOE and EPA have entered into an Administrative Consent Order (ACO), the prime regulatory authority for cleanup at PGDP will be the Resource Conservation and Recovery Act (RCRA). This report supplies a preliminary list of available federal and state ARARs that might be considered for remedial response at PGDP in the event that the plant becomes included on the NPL or the ACO is modified to include CERCLA cleanup. A description of the terms ``applicable`` and ``relevant and appropriate`` is provided, as well as definitions of chemical-, location-, and action-specific ARARS. ARARs promulgated by the federal government and by the state of Kentucky are listed in tables. In addition, the major provisions of RCRA, the Safe Drinking Water Act, the Clean Water Act, the Clean Air Act, and other acts, as they apply to hazardous and radioactive waste cleanup, are discussed.

Etnier, E.L.; Eaton, L.A. [Oak Ridge National Lab., TN (United States)

1992-03-01T23:59:59.000Z

436

Thermal Discharges from Paducah Gaseous Diffusion Plant Outfalls: Impacts on Stream Temperatures and Fauna of Little Bayou and Big Bayou Creeks  

SciTech Connect

The development of a biological monitoring plan for the receiving streams of the Paducah Gaseous Diffusion Plant (PGDP) began in the late 1980s, because of an Agreed Order (AO) issued in September 1987 by the Kentucky Division of Water (KDOW). Five years later, in September 1992, more stringent effluent limitations were imposed upon the PGDP operations when the KDOW reissued Kentucky Pollutant Discharge Elimination System permit No. KY 0004049. This action prompted the US Department of Energy (DOE) to request a stay of certain limits contained in the permit. An AO is being negotiated between KDOW, the United States Enrichment Corporation (USEC), and DOE that will require that several studies be conducted, including this stream temperature evaluation study, in an effort to establish permit limitations. All issues associated with this AO have been resolved, and the AO is currently being signed by all parties involved. The proposed effluent temperature limit is 89 F (31.7C) as a mean monthly temperature. In the interim, temperatures are not to exceed 95 F (35 C) as a monthly mean or 100 F (37.8 C) as a daily maximum. This study includes detailed monitoring of instream temperatures, benthic macroinvertebrate communities, fish communities, and a laboratory study of thermal tolerances.

Roy, W.K.

1999-01-01T23:59:59.000Z

437

Atmospheric mercury in Changbai Mountain area, northeastern China I. The seasonal distribution pattern of total gaseous mercury and its potential sources  

SciTech Connect

An intensive field campaign for the measurement of total gaseous mercury (TGM) concentrations in ambient air was conducted in Changbai Mountain area from 5 August 2005 to 5 July 2006 using an automatic atmospheric mercury analyzer (Tekran 2537A), which was the first time TGM was monitored at a remote area in northeastern China. 99% of the hourly TGM concentrations fell between 1.28 and 9.49 ng m{sup -3} with an annual arithmetic mean of 3.58{+-}1.78 ng m{sup -3}, which was significantly elevated compared to values obtained in remote areas of Europe and North America. Seasonal mean TGM concentrations displayed a descending trend as follows: winter, spring, fall, and summer. Compared to spring/winter, TGM concentrations were lower in the summer/fall but the standard deviation (SD) of TGM levels was higher and indicated a correlation with anthropogenic emissions. TGM concentrations showed seasonal differences with respect to meteorological parameters: TGM levels in spring/winter were most correlated with wind speed, and correlated with solar radiation only in the winter, while TGM levels in summer/fall periods were most correlated with air temperature. There was a strong diurnal variation of seasonal TGM with significantly higher concentrations in daytime/nighttime compared to the early morning. The seasonal diel TGM pattern indicated regional biofuel and coal combustion were the primary mercury sources.

Wan Qi [State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002 (China); Graduate University of Chinese Academy of Sciences, Beijing 100049 (China); Feng Xinbin [State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002 (China)], E-mail: fengxinbin@vip.skleg.cn; Lu, Julia [Department of Chemistry and Biology, Ryerson University, Toronto, Ont., M5B 2K3 (Canada)], E-mail: Julialu@ryerson.ca; Zheng Wei [State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002 (China); Graduate University of Chinese Academy of Sciences, Beijing 100049 (China); Song Xinjie [Department of Chemistry and Biology, Ryerson University, Toronto, Ont., M5B 2K3 (Canada); Han Shijie; Xu Hao [Open Research Station of Changbai Mountain Forest Ecosystems, Chinese Academy of Sciences, Yanbian 133613 (China)

2009-04-15T23:59:59.000Z

438

Compound cast product and method for producing a compound cast product  

DOE Patents (OSTI)

A compound cast product is formed in a casting mold (14) having a mold cavity (16) sized and shaped to form the cast product. A plurality of injectors (24) is supported from a bottom side (26) of the casting mold (14). The injectors (24) are in fluid communication with the mold cavity (16) through the bottom side (26) of the casting mold (14). A molten material holder furnace (12) is located beneath the casting mold (14). The holder furnace (12) defines molten material receiving chambers (36) configured to separately contain supplies of two different molten materials (37, 38). The holder furnace (12) is positioned such that the injectors (24) extend downward into the receiving chamber (36). The receiving chamber (36) is separated into at least two different flow circuits (51, 52). A first molten material (37) is received in a first flow circuit (51), and a second molten material (38) is received into a second flow circuit (52). The first and second molten materials (37, 38) are injected into the mold cavity (16) by the injectors (24) acting against the force of gravity. The injectors (24) are positioned such that the first and second molten materials (37, 38) are injected into different areas of the mold cavity (16). The molten materials (37, 38) are allowed to solidify and the resulting compound cast product is removed from the mold cavity (16).

Meyer, Thomas N. (3987 Murray Highlands Cir., Murrysville, PA 15668-1747); Viswanathan, Srinath (1104 Albermarle La., Knoxville, TN 37923)

2002-09-17T23:59:59.000Z

439

Review of the Department of Energy Office of Environmental Management Assessment of the Portsmouth/Paducah Project Office Oversight of the Portsmouth Gaseous Diffusion Plant Criticality Safety Program, May 2012  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Department of Energy Department of Energy Office of Environmental Management Assessment of the Portsmouth/Paducah Project Office Oversight of the Portsmouth Gaseous Diffusion Plant Criticality Safety Program May 2012 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy i Table of Contents 1.0 Purpose ................................................................................................................................................... 1 2.0 Background ............................................................................................................................................ 1 3.0 Scope ...................................................................................................................................................... 2

440

Mechanistic Study of Oxygen Atom Transfer Catalyzed by Rhenium Compounds  

SciTech Connect

Two ionic and one neutral methyl(oxo)rhenium(V) compounds were synthesized and structurally characterized. They were compared in reactivity towards the ligands triphenylphosphane, pyridines, pyridine N-oxides. Assistance from Broensted bases was found on ligand displacement of ionic rhenium compounds as well as nucleophile assistance on oxidation of all compounds. From the kinetic data, crystal structures, and an analysis of the intermediates, a structural formula of PicH{sup +}3{sup -} and mechanisms of ligand displacement and oxidation were proposed.

Xiaopeng Shan

2003-08-05T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous paraffinic compound" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Dosimeter for monitoring vapors and aerosols of organic compounds  

DOE Patents (OSTI)

A dosimeter is provided for collecting and detecting vapors and aerosols of organic compounds. The dosimeter comprises a lightweight, passive device that can be conveniently worn by a person as a badge or placed at a stationary location. The dosimeter includes a sample collector comprising a porous web treated with a chemical for inducing molecular displacement and enhancing phosphorescence. Compounds are collected onto the web by molecular diffusion. The web also serves as the sample medium for detecting the compounds by a room temperature phosphorescence technique.

Vo-Dinh, Tuan (625 Gulfwood Rd., Knoxville, TN 37923)

1987-01-01T23:59:59.000Z

442

Dosimeter for monitoring vapors and aerosols of organic compounds  

DOE Patents (OSTI)

A dosimeter is provided for collecting and detecting vapors and aerosols of organic compounds. The dosimeter comprises a lightweight, passive device that can be conveniently worn by a person as a badge or placed at a stationary location. The dosimeter includes a sample collector comprising a porous web treated with a chemical for inducing molecular displacement and enhancing phosphorescence. Compounds are collected onto the web by molecular diffusion. The web also serves as the sample medium for detecting the compounds by a room temperature phosphorescence technique. 7 figs.

Vo-Dinh, T.

1987-07-14T23:59:59.000Z

443

Characterization of nitrogen compound types in hydrotreated Paraho shale oil  

DOE Green Energy (OSTI)

Results from the separation and characterization of nitrogen compound types in hydrotreated Paraho shale oil samples were obtained. Two samples of Paraho shale oil were hydrotreated by Chevron Research Company such that one sample contained about 0.05 wt. percent nitrogen and the other sample contained about 0.10 wt. percent nitrogen. A separation method concentrate specific nitrogen compound types was developed. Characterization of the nitrogen types was accomplished by infrared spectroscopy, mass spectrometry, potentiometric titration, and elemental analysis. The distribution of nitrogen compound types in both samples and in the Paraho crude shale oil is compared.

Holmes, S.A.; Latham, D.R.

1980-10-01T23:59:59.000Z

444

Abatement of Air Pollution: Control of Sulfur Compound Emissions  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Abatement of Air Pollution: Control of Sulfur Compound Emissions Abatement of Air Pollution: Control of Sulfur Compound Emissions (Connecticut) Abatement of Air Pollution: Control of Sulfur Compound Emissions (Connecticut) < Back Eligibility Agricultural Commercial Construction Fed. Government Fuel Distributor General Public/Consumer Industrial Installer/Contractor Institutional Investor-Owned Utility Local Government Low-Income Residential Multi-Family Residential Municipal/Public Utility Nonprofit Residential Retail Supplier Rural Electric Cooperative Schools State/Provincial Govt Systems Integrator Transportation Tribal Government Utility Program Info State Connecticut Program Type Environmental Regulations Provider Department of Energy and Environmental Protection These regulations set limits on the sulfur content of allowable fuels (1.0%

445

Process and apparatus for formation of photovoltaic compounds  

DOE Patents (OSTI)

The invention relates to a process and apparatus for formation and deposition of thin films on a substrate, in a vacuum, by evaporation of the elements to form a Zn.sub.x Cd.sub.1-x S compound having a preselected fixed ratio of cadmium to zinc, characterized by the evaporation of cadmium and zinc at a rate the ratio of which is proportional to the stoichiometric ratio of those elements in the intended compound and evaporation of sulfur at a rate at least twice the combined rates of cadmium and zinc, and at least twice that required by the stoichiometry of the intended compound.

Hall, Robert B. (Newark, DE); Rocheleau, Richard E. (Wilmington, DE)

1985-01-01T23:59:59.000Z

446

Removal of basic nitrogen compounds from hydrocarbon liquids  

DOE Patents (OSTI)

A method is provided for reducing the concentration of basic nitrogen compounds in hydrocarbonaceous feedstock fluids used in the refining industry by providing a solid particulate carbonaceous adsorbent/fuel material such as coal having active basic nitrogen complexing sites on the surface thereof and the coal with a hydrocarbonaceous feedstock containing basic nitrogen compounds to facilitate attraction of the basic nitrogen compounds to the complexing sites and the formation of complexes thereof on the surface of the coal. The adsorbent coal material and the complexes formed thereon are from the feedstock fluid to provide a hydrocarbonaceous fluid of reduced basic nitrogen compound concentration. The coal can then be used as fuel for boilers and the like.

Givens, Edwin N. (Bethlehem, PA); Hoover, David S. (New Tripoli, PA)

1985-01-01T23:59:59.000Z

447

Cocoa Butter and Related CompoundsChapter 3 Cocoa Polyphenols  

Science Conference Proceedings (OSTI)

Cocoa Butter and Related Compounds Chapter 3 Cocoa Polyphenols Food Science Health Nutrition eChapters Food Science & Technology Health - Nutrition - Biochemistry 58E85136211F4F2A1FF657252FD1866B AOCS Press Downloadab

448

EVect of aromatic compounds on the production of laccase and ...  

J Ind Microbiol Biotechnol (2010) 37:10911096 DOI 10.1007/s10295-010-0757-y 123 ORIGINAL PAPER EVect of aromatic compounds on the production of ...

449

Electrochemically driven phase transformation in energy storage compounds  

E-Print Network (OSTI)

Nanoscale lithium transition metal phosphate olivines have become commercially important as positive electrode materials in a new generation of lithium-ion batteries. Not surprisingly, many energy storage compounds undergo ...

Gao, Yuhua

2011-01-01T23:59:59.000Z

450

Low-Cost Phosphate Compounds Enhance Lithium Battery Performance  

Argonne National Laboratory has developed a series of inexpensive, electrochemically active phosphate compounds that are highly functional when used in high-power and high-energy lithium batteries.

451

Compound Solar Technology CompSolar | Open Energy Information  

Open Energy Info (EERE)

Solar Technology CompSolar Jump to: navigation, search Name Compound Solar Technology (CompSolar) Place Jhunan, Taiwan Zip 350 Sector Solar Product Producer of glass-based...

452

Metastable, Single Crystalline Nanopillar Growth of III-V Compounds...  

NLE Websites -- All DOE Office Websites (Extended Search)

Metastable, Single Crystalline Nanopillar Growth of III-V Compounds on Lattice-Mismatched Substrates Speaker(s): Connie Chang-Hasnain Date: February 28, 2012 - 12:00pm Location:...

453

Lattice mismatched compound semiconductors and devices on silicon  

E-Print Network (OSTI)

III-V compound semiconductors, due to their superior electron mobility, are promising candidates for n-type metal-oxide-semiconductor field effect transistors (MOSFETs). However, the limited size of III-V substrates and ...

Yang, Li, Ph. D. Massachusetts Institute of Technology

2011-01-01T23:59:59.000Z

454

Microfluidic in vivo screen identifies compounds enhancing neuronal  

E-Print Network (OSTI)

Compound screening is a powerful tool to identify new therapeutic targets, drug leads, and elucidate the fundamental mechanisms of biological processes. We report here the results of the first in vivo small-molecule screens ...

Haggarty, Stephen

455

Compound and Elemental Analysis At Yellowstone Region (Hurwitz, Et Al.,  

Open Energy Info (EERE)

Compound and Elemental Analysis At Yellowstone Region (Hurwitz, Et Al., Compound and Elemental Analysis At Yellowstone Region (Hurwitz, Et Al., 2007) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Compound and Elemental Analysis At Yellowstone Region (Hurwitz, Et Al., 2007) Exploration Activity Details Location Yellowstone Caldera Geothermal Region Exploration Technique Compound and Elemental Analysis Activity Date Usefulness not indicated DOE-funding Unknown Notes In this paper, we present and evaluate a chemical dataset that includes the concentrations and fluxes of HCO3_, SO42_, Cl_, and F_ in rivers draining YNP for the 2002-2004 water years (1 October 2001 - 30 September 2004). These solutes were chosen because they are likely derived in part, from the magmatic volatiles CO2, SO2, H2S, HCl, HF (Symonds et al., 2001). Weekly to

456

Process for synthesizing compounds from elemental powders and product  

DOE Patents (OSTI)

A process for synthesizing intermetallic compounds from elemental powders is described. The elemental powders are initially combined in a ratio which approximates the stoichiometric composition of the intermetallic compound. The mixed powders are then formed into a compact which is heat treated at a controlled rate of heating such that an exothermic reaction between the elements is initiated. The heat treatment may be performed under controlled conditions ranging from a vacuum (pressureless sintering) to compression (hot pressing) to produce a desired densification of the intermetallic compound. In a preferred form of the invention, elemental powders of Fe and Al are combined to form aluminide compounds of Fe[sub 3] Al and FeAl. 25 figures.

Rabin, B.H.; Wright, R.N.

1993-12-14T23:59:59.000Z

457

Device for aqueous detection of nitro-aromatic compounds  

DOE Patents (OSTI)

This invention relates to a compact and portable detection apparatus for nitro-aromatic based chemical compounds, such as nitrotoluenes, dinitrotoluenes, and trinitrotoluene (TNT). The apparatus is based upon the use of fiber optics using filtered light. The preferred process of the invention relies upon a reflective chemical sensor and optical and electronic components to monitor a decrease in fluorescence when the nitro-aromatic molecules in aqueous solution combine and react with a fluorescent polycyclic aromatic compound. 4 figures.

Reagen, W.K.; Schulz, A.L.; Ingram, J.C.; Lancaster, G.D.; Grey, A.E.

1994-04-26T23:59:59.000Z

458

Process for reducing organic compounds with calcium, amine, and alcohol  

DOE Patents (OSTI)

Olefins are produced by contacting an organic compound having at least one benzene ring with calcium metal, ethylenediamine, a low molecular weight aliphatic alcohol, and optionally a low molecular weight aliphatic primary amine, and/or an inert, abrasive particulate substance. The reduction is conducted at temperatures ranging from about -10.degree. C. to about 30.degree. C. or somewhat higher. Substantially all of the organic compounds are converted to corresponding cyclic olefins, primarily diolefins.

Benkeser, Robert A. (West Lafayette, IN); Laugal, James A. (Lostant, IL); Rappa, Angela (Baltimore, MD)

1985-01-01T23:59:59.000Z

459

Process for reducing organic compounds with calcium, amine, and alcohol  

DOE Patents (OSTI)

Olefins are produced by contacting an organic compound having at least one benzene ring with calcium metal, ethylenediamine, a low molecular weight aliphatic alcohol, and optionally a low molecular weight aliphatic primary amine, and/or an inert, abrasive particulate substance. The reduction is conducted at temperatures ranging from about [minus]10 C to about 30 C or somewhat higher. Substantially all of the organic compounds are converted to corresponding cyclic olefins, primarily diolefins.

Benkeser, R.A.; Laugal, J.A.; Rappa, A.

1985-08-06T23:59:59.000Z

460

Anion receptor compounds for non-aqueous electrolytes  

SciTech Connect

A new family of aza-ether based compounds including linear, multi-branched and aza-crown ethers is provided. When added to non-aqueous battery electrolytes, the new family of aza-ether based compounds acts as neutral receptors to complex the anion moiety of the electrolyte salt thereby increasing the conductivity and the transference number of LI.sup.+ ion in alkali metal batteries.

Lee, Hung Sui (East Setauket, NY); Yang, Xiao-Oing (Port Jefferson Station, NY); McBreen, James (Bellport, NY)

2000-09-19T23:59:59.000Z

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461

Chromium (V) compounds as cathode material in electrochemical power sources  

SciTech Connect

A cathode for use in a thermal battery, comprising a chromium (V) compound. The preferred materials for this use are Ca.sub.5 (CrO.sub.4).sub.3 Cl, Ca.sub.5 (CrO.sub.4).sub.3 OH, and Cr.sub.2 O.sub.5. The chromium (V) compound can be employed as a cathode material in ambient temperature batteries when blended with a suitably conductive filler, preferably carbon black.

Delnick, Frank M. (Albuquerque, NM); Guidotti, Ronald A. (Albuquerque, NM); McCarthy, David K. (Albuquerque, NM)

1985-01-01T23:59:59.000Z

462

Emissions of volatile and potentially toxic organic compounds from waste-water treatment plants and collection systems (Phase 2). Volume 1. Project summaries. Final report  

SciTech Connect

The objectives of the Phase II research project on emission of potentially toxic organic compounds (PTOCs) from wastewater treatment plants were fivefold: (1) assessment of the importance of gaseous emissions from municipal wastewater collection systems; (2) resolution of the discrepancy between the measured and estimated emissions (Phase I), from the Joint Water Pollution Control Plant (JWPCP) operated by the County Sanitation Districts of Los Angeles County (CSDLAC); (3) determination of airborne concentrations of PTOCS immediately downwind of an activated sludge aeration process at the City of Los Angeles' Hyperion Treatment Plant (HTP); (4) a modeling assessment of the effects of transient loading on emissions during preliminary and primary treatment at a typical municipal wastewater treatment plant (MWTP); (5) a preliminary investigation of effects of chlorination practices on haloform production. Volume 1, for which the abstract was prepared, contains a summary of results from each project; Volume 2 contains the discussion regarding the modeling of collection system emissions; Volume 3 addresses methods development and field sampling efforts at the JWPCP and HTP, data on emissions from a mechanically ventilated sewer and results of some preliminary haloform formation studies in wastewaters; and Volume 4 discusses aspects of the emissions modeling problem.

Chang, D.P.Y.; Schroeder, E.D.; Corsi, R.L.; Guensler, R.; Meyerhofer, J.A.

1991-08-01T23:59:59.000Z

463

PUMP FOR GASEOUS WORKING FLUIDS  

DOE Patents (OSTI)

A gas pump having a substantially constant rate of flow and a relatively efficient punnping action is described. A number of flexible plates disposed longitudinally in and in contact with a duct are caus