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Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Apparatus for recovering gaseous hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents (OSTI)

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1984-01-01T23:59:59.000Z

2

Recovery of normally gaseous hydrocarbons from net excess hydrogen in a catalytic reforming process  

Science Conference Proceedings (OSTI)

A process is disclosed for the catalytic reforming of hydrocarbons in the presence of hydrogen, preferably to produce high quality gasoline boiling range products. An improved recovery of normally gaseous hydrocarbons from the net excess hydrogen is realized by chilling and contacting said hydrogen with a normally liquid hydrocarbon stream in a plural stage absorption zone at an elevated pressure.

Scheifele, C.A.

1982-06-08T23:59:59.000Z

3

On-Line Measurement of Heat of Combustion of Gaseous Hydrocarbon Fuel Mixtures  

Science Conference Proceedings (OSTI)

A method for the on-line measurement of the heat of combustion of gaseous hydrocarbon fuel mixtures has been developed and tested. The method involves combustion of a test gas with a measured quantity of air to achieve a preset concentration of oxygen ...

Sprinkle Danny R.; Chaturvedi Sushil K.; Kheireddine Ali

1996-03-01T23:59:59.000Z

4

Separation and recovery of hydrogen and normally gaseous hydrocarbons from net excess hydrogen from a catalytic reforming process  

Science Conference Proceedings (OSTI)

A process is disclosed for the catalytic reforming of hydrocarbons in the presence of hydrogen, preferably to produce high quality gasoline boiling range products. An improved recovery of normally gaseous hydrocarbons from the net excess hydrogen is realized by chilling and contacting said hydrogen with a normally liquid hydrocarbon stream in a plural stage absorption zone at an elevated pressure.

Scheifele, C.A.

1982-06-08T23:59:59.000Z

5

Catalytic Cracking of Gaseous Heavy Hydrocarbons by Ceramic Filters  

DOE Green Energy (OSTI)

The use of syngas from waste or biomass gasification to generate electricity is a way which is attracting increasing attention especially with regard to the demands of regenerable energy consumption and to the reduction of waste disposal. In order to feed the syngas to a gas motor or a gas turbine the gas has to be cleaned. In future also the coupling of biomass gasification with a fuel cell will be applied, which needs a very efficient gas cleaning. The decomposition of tars and the removal of particles from the gas are the key issues of gas cleaning. Up to now these two steps are performed in two separate units. Normally, the tars are decomposed in catalytic beds or honeycomb structures. The catalytic decomposition is achieved at temperatures between 750 C and 900 C depending on the catalyst used. Particles are removed by filtration of the hot gas. Filtration at high temperatures and with high efficiencies is possible when using ceramic filter elements. Ceramic hot gas filters are well established in advanced coal gasification, such as the integrated gasification combined cycle process, as well as in waste and biomass gasification and pyrolysis processes. Since the catalytic reaction requires high temperatures the gas has to be reheated after the particles are removed in the filter or the hot unfiltered gas has to flow through the catalytic unit. If the gas is filtered first, reheating of the gas stream is an additional cost factor. Furthermore, pipes downstream of the filter can be plugged, if the temperature of the gas falls below the condensation temperature of the heavy hydrocarbons. Using the second way of hot unfiltered gas flows through the catalytic unit, there is the problem of deactivation of the catalyst by deposition of dust at higher dust concentrations. At worst the catalytic unit can be plugged by dust deposition.

Heidenreich, S.; Nacken, M.; Walch, A.; Chudzinski, S.

2002-09-19T23:59:59.000Z

6

Separation of normally gaseous hydrocarbons from a catalytic reforming effluent and recovery of purified hydrogen  

Science Conference Proceedings (OSTI)

A process for the catalytic reforming of a hydrocarbonaceous feedstock, preferably to produce high quality gasoline boiling range products, is disclosed. Relatively impure hydrogen is separated from the reforming zone effluent, compressed, and recontacted with at least a portion of the liquid reformate product to provide relatively pure hydrogen, a portion of which is recycled to the reforming zone. The balance is further compressed and recontacted with at least a portion of the liquid reformate product to provide an improved recovery of normally gaseous hydrocarbons as well as an improved recovery of purified hydrogen at a pressure suitable for use in the relatively high pressure hydrotreating of sulfur-containing feedstocks.

Coste, A.C.

1982-06-08T23:59:59.000Z

7

Separation of normally gaseous hydrocarbons from a catalytic reforming effluent and recovery of purified hydrogen  

Science Conference Proceedings (OSTI)

A process for the catalytic reforming of a hydrocarbonaceous feedstock, preferably to produce high quality gasoline boiling range products, is disclosed. Relatively impure hydrogen is separated from the reforming zone effluent, compressed, and recontacted with at least a portion of the liquid reformate product to provide relatively pure hydrogen, a portion of which is recycled to the reforming zone. The balance is further compressed and recontacted with at least a portion of the liquid reformate product in a plural stage absorption zone to provide an improved recovery of normally gaseous hydrocarbons as well as an improved recovery of purified hydrogen at a pressure suitable, for example, the relatively high pressure hydrotreating of sulfur-containing feedstocks.

O'brien, D.E.

1982-06-08T23:59:59.000Z

8

Characterization and analysis of Devonian shales as related to release of gaseous hydrocarbons. Well R-109, Washington County, Ohio  

DOE Green Energy (OSTI)

Coring of Well R-109 (Washington County, Ohio) was accomplished in August 1976. A total of 25 samples were collected. Hydrocarbon gas analyses indicate that higher chain hydrocarbon gases (C/sub 2/-C/sub 5/) make up a significant portion of total hydrocarbons in the shales, but methane is still the dominant single gas. Distinct relationships exist between the carbon and hydrocarbon gas contents, showing increase in hydrocarbon gas contents with increasing carbon. Similar relationships between hydrogen and hydrocarbon gas contents exist, though they are not as pronounced. Gas contents appear not to be related to the bulk densities in any quantitative manner, though organic contents (carbon and hydrogen) seem to be related to bulk density values much more clearly. R-109 shales are virtually impermeable to gases and other fluids, as attempted helium gas permeability measurements indicated extremely small (< 10/sup -12/ Darcy) permeability values.

Kalyoncu, R.S.; Boyer, J.P.; Snyder, M.J.

1979-06-20T23:59:59.000Z

9

Characterization and analysis of Devonian shales as related to release of gaseous hydrocarbons. Quarterly technical progress report, April--June 1978  

DOE Green Energy (OSTI)

Objective is to determine the relationships between the shale characteristics, hydrocarbon gas contents, and well location, for assessing the productive capacity of the Eastern Devonian Gas Shale deposits and guiding research, development, and demonstration projects to enhance the recovery of natural gas from the shale deposits. One well was sampled during this reporting period. Another well from Monongalia County, WV (M-1) was cored in April. 31 samples were obtained for Battelle with additional 55 samples canned for other DOE contractors. Characterization tasks on shale samples from R-146 (Mason County, WV.) and M-1 wells (Monongalia) have been completed. In the preliminary analysis correlations were observed between the hydrocarbon gas contents and can pressure, propane content, well location, oxygen content CO/sub 2/ content, bulk density and carbon contents. Higher pressures are attributed to higher hydrocarbon gas contents. For high gas pressures, propane content is an important indication of hydrocarbon gas content. At low gas pressure, butane contents more accurately predict the hydrocarbon gas contents. High CO/sub 2/ and carbon contents indicate high hydrocarbon gas values, whereas oxygen contents are inversely related to hydrocarbon gas contents. Analysis of the limited wire-line log data shows that correlations between the laboratory and well log data can be utilized to predict potential hydrocarbon gas contents of the wells. 15 tables, 27 figures.

Kalyoncu, R.S.; Snyder, M.J.

1978-08-08T23:59:59.000Z

10

Geochemical assessment of gaseous hydrocarbons: mixing of bacterial and thermogenic methane in the deep subsurface petroleum system, Gulf of Mexico continental slope  

E-Print Network (OSTI)

Mixtures of bacterial and thermogenic methane are found both at vents at the seafloor and in reservoirs in the deep subsurface of the Gulf of Mexico continental slope. The C1-C5 gas that most recently charged reservoirs of Jolliet (GC 184), Genesis (GC 160/161) and Petronius (VK 786) fields is estimated to include 17%-28%, 31%-51%, 31%-49% bacterial methane, respectively. Geochemical assessment of the reservoir gas in the fields show that the gas may be the product of thermal cracking of Upper Jurassic crude oil before final migration to the reservoirs. The gas from three different fields is of similar thermal maturity levels. In contrast to oil in reservoirs in the fields, which shows biodegradation effects, the C1-C5 reservoir gas is unaltered by biodegradation. Late gas migration may have occurred at or near present burial depth and flushed the reservoir system of previously biodegraded hydrocarbon gas to include any previous bacterial methane. Molecular and isotopic properties of reservoir gas and oil suggest that bacterial methane mixed with thermogenic hydrocarbon gas before entering the reservoirs. Thus the source of the bacterial methane is logically deeper than the present depth (>~4 km) and temperatures of the reservoirs. High sedimentation rate and low geothermal gradient may offer conditions favorable for generation and preservation of bacterial methane in deep subsurface petroleum system of the Gulf slope. Bacterial methane dispersed across the large drainage areas of the deep subsurface petroleum system may have been swept by migrating fluids at >4 km, and then charged both vents (GC 185, GC 233 and GC 286) at the seafloor and reservoirs in the deep subsurface. The volume of bacterial methane from geologically significant depth in rapidly subsiding basins may be underestimated.

Ozgul, Ercin

2002-08-01T23:59:59.000Z

11

Conversion of organic solids to hydrocarbons  

DOE Patents (OSTI)

A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon.

Greenbaum, Elias (Oak Ridge, TN)

1995-01-01T23:59:59.000Z

12

Conversion of organic solids to hydrocarbons  

DOE Patents (OSTI)

A method of converting organic solids to liquid and gaseous hydrocarbons includes impregnating an organic solid with photosensitizing ions and exposing the impregnated solid to light in a non-oxidizing atmosphere for a time sufficient to photocatalytically reduce the solid to at least one of a liquid and a gaseous hydrocarbon. 5 Figs.

Greenbaum, E.

1995-05-23T23:59:59.000Z

13

NGPL Production, Gaseous Equivalent  

U.S. Energy Information Administration (EIA) Indexed Site

NGPL Production, Gaseous Equivalent Period: Monthly Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By:...

14

Gaseous Fuel Injection Modeling using a Gaseous Sphere Injection Methodology  

DOE Green Energy (OSTI)

The growing interest in gaseous fuels (hydrogen and natural gas) for internal combustion engines calls for the development of computer models for simulation of gaseous fuel injection, air entrainment and the ensuing combustion. This paper introduces a new method for modeling the injection and air entrainment processes for gaseous fuels. The model uses a gaseous sphere injection methodology, similar to liquid droplet in injection techniques used for liquid fuel injection. In this paper, the model concept is introduced and model results are compared with correctly- and under-expanded experimental data.

Hessel, R P; Aceves, S M; Flowers, D L

2006-03-06T23:59:59.000Z

15

Method for recovery of hydrocarbon material from hydrocarbon material-bearing formations  

SciTech Connect

A method is disclosed for heating a hydrocarbon material contained in a recovery zone in an underground hydrocarbon material-bearing formation to reduce the viscosity thereof for facilitating recovery of the hydrocarbon material. A gaseous penetration medium comprising a gaseous working fluid and a carrier gas, is fed into the formation at a penetration pressure sufficient for penetration of the recovery zone, the working fluid being a water soluble gas which generates heat of solution upon absorption in an aqueous medium, and in which the partial pressure of the working fluid in relation to the penetration pressure and the temperature prevailing in the recovery zone is controlled to inhibit working fluid condensation but to provide for absorption of working fluid by water present in the formation to release heat for heating the hydrocarbon material in the recovery zone.

Kalina, A.I.

1982-05-25T23:59:59.000Z

16

GASEOUS SCINTILLATION COUNTER  

DOE Patents (OSTI)

A gaseous excitation counter for detecting the presence amd measuring the energy of subatomic particles and electromagnetic radiation is described. The counter includes a gas-tight chamber filled with an elemental gas capable of producing ultra-violet excitation quanta when irradiated with subatomic particles and electromagnetic radiation. The gas has less than one in a thousand parts ultra-violet absorbing contamination. When nuclear radiation ps present the ultra-violet light produced by the gas strikes a fluorescent material within the counter, responsive to produce visible excitation quanta, and photo-sensitive counting means detect the visible emission.

Eggler, C.; Huddleston, C.M.

1959-04-28T23:59:59.000Z

17

Plasma-assisted conversion of solid hydrocarbon to diamond  

DOE Patents (OSTI)

A process of preparing diamond, e.g., diamond fiber, by subjecting a hydrocarbon material, e.g., a hydrocarbon fiber, to a plasma treatment in a gaseous feedstream for a sufficient period of time to form diamond, e.g., a diamond fiber is disclosed. The method generally further involves pretreating the hydrocarbon material prior to treatment with the plasma by heating within an oxygen-containing atmosphere at temperatures sufficient to increase crosslinking within said hydrocarbon material, but at temperatures insufficient to melt or decompose said hydrocarbon material, followed by heating at temperatures sufficient to promote outgassing of said crosslinked hydrocarbon material, but at temperatures insufficient to convert said hydrocarbon material to carbon.

Valone, Steven M. (Santa Fe, NM); Pattillo, Stevan G. (Los Alamos, NM); Trkula, Mitchell (Los Alamos, NM); Coates, Don M. (Santa Fe, NM); Shah, S. Ismat (Wilmington, DE)

1996-01-01T23:59:59.000Z

18

Getter pump for hydrogen and hydrocarbon gases  

DOE Patents (OSTI)

A gettering device for hydrogen isotopes and gaseous hydrocarbons based on the interaction of a plasma and graphite used as cathodic material. The plasma is maintained at a current density within the range of about 1 to about 1000 mA/cm.sup.2. The graphite may be heated to a temperature greater than 1000.degree. C. The new device offers high capacity, low noise, and gas species selectivity.

Hsu, Wen L. (Danville, CA)

1989-01-01T23:59:59.000Z

19

: Plasma-Hydrocarbon conversion  

crude oil and hydrocarbon gases like natural gas, into lighter hydrocarbon materials (e.g. synthetic light oil).

20

Recovery of C/sub 3/. sqrt. hydrocarbon conversion products and net excess hydrogen in a catalytic reforming process  

Science Conference Proceedings (OSTI)

This invention relates to a hydrocarbon conversion process effected in the presence of hydrogen, especially a hydrogenproducing hydrocarbon conversion process. More particularly, this invention relates to the catalytic reforming of a naphtha feedstock, and is especially directed to an improved recovery of the net excess hydrogen, and to an improved recovery of a C/sub 3/..sqrt.. normally gaseous hydrocarbon conversion product and a C/sub 5/..sqrt.. hydrocarbon conversion product boiling in the gasoline range.

Degraff, R.R.; Peters, K.D.

1982-12-21T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Apparatus for hydrocarbon extraction  

DOE Patents (OSTI)

Systems and methods for hydrocarbon extraction from hydrocarbon-containing material. Such systems and methods relate to extracting hydrocarbon from hydrocarbon-containing material employing a non-aqueous extractant. Additionally, such systems and methods relate to recovering and reusing non-aqueous extractant employed for extracting hydrocarbon from hydrocarbon-containing material.

Bohnert, George W.; Verhulst, Galen G.

2013-03-19T23:59:59.000Z

22

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents (OSTI)

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus, carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, Guy R. B. (Los Alamos, NM); Barraclough, Bruce L. (Santa Fe, NM); Vanderborgh, Nicholas E. (Los Alamos, NM)

1983-01-01T23:59:59.000Z

23

Substantially self-powered method and apparatus for recovering hydrocarbons from hydrocarbon-containing solid hydrates  

DOE Patents (OSTI)

A method and apparatus are provided for producing gaseous hydrocarbons from formations comprising solid hydrocarbon hydrates located under either a body of land or a body of water. The vast natural resources of such hydrocarbon hydrates can thus now be economically mined. Relatively warm brine or water is brought down from an elevation above that of the hydrates through a portion of the apparatus, and passes in contact with the hydrates, thus melting them. The liquid then continues up another portion of the apparatus carrying entrained hydrocarbon vapors in the form of bubbles, which can easily be separated from the liquid. After a short startup procedure, the process and apparatus are substantially self-powered.

Elliott, G.R.B.; Barraclough, B.L.; Vanderborgh, N.E.

1981-02-19T23:59:59.000Z

24

Independent Oversight Inspection, Portsmouth Gaseous Diffusion Plant -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth Gaseous Diffusion Portsmouth Gaseous Diffusion Plant - November 2006 Independent Oversight Inspection, Portsmouth Gaseous Diffusion Plant - November 2006 November 2006 Inspection of Emergency Management at the Portsmouth Gaseous Diffusion Plant The Secretary of Energy's Office of Independent Oversight, within the Office of Security and Safety Performance Assurance, conducted an inspection of the emergency management program at the Portsmouth Gaseous Diffusion Plant (PORTS) in August and September 2006. The coordination of emergency plans and procedures among USEC and DOE contractor organizations has successfully integrated the emergency management programs into a single cohesive program for the PORTS site. Other strengths include accurate hazards surveys that identify applicable

25

Gaseous electrode development. Final report  

DOE Green Energy (OSTI)

The purpose of the present study is to optimize the gaseous electrode for use in an MHD generator and to test this optimum configuration in an operating MHD channel. The arc gaseous electrode concept is based on the use of an arc source in the body of the MHD channel electrode, wherein the arc follows a helical path and generates a plasma which flows out of a long, thin slot cut parallel to the cylindrical annulus, to provide a low impedance path for the MHD current through the boundary layer so that electrode erosion due to arcing can be reduced. Bench-scale tests on the arc plasma source were conducted. The effect of the parameters such as magnetic field, yaw angle with respect to the magnetic field, electrode geometry, and arc cathode materials were studied. Based on these studies, an optimum design was selected for testing in the MHD channel. Tests were conducted with the arc gaseous electrode in the cathode wall of a diagonal conducting wall MHD generator at magnetic fields up to 3.83 Tesla, with a supersonic flow of combustion products seeded with 1.0 w/o of potassium. The measured MHD plasma conductivity varied between 12 and 22 S/m. Results are presented and discussed in detail. (WHK)

Jones, M.S. Jr.; Scannell, E.P.; Sathyanarayana, K.; Thiagarajan, V.; Mallavarpu, R.; Armstrong, A.J.

1979-12-01T23:59:59.000Z

26

Carbon K-shell excitation of gaseous and condensed cyclic hydrocarbons: C/sub 3/H/sub 6/, C/sub 4/H/sub 8/, C/sub 5/H/sub 8/, C/sub 5/H/sub 10/, C/sub 6/H/sub 10/, C/sub 6/H/sub 12/, and C/sub 8/H/sub 8/  

SciTech Connect

The carbon K-shell excitation spectra of gaseous cyclic hydrocarbons, both saturated (cyclopropane, cyclobutane, cyclopentane, cyclohexane) and unsaturated (cyclopentene, cyclohexene, and cyclooctatetraene), have been recorded by electron energy loss spectroscopy under dipole-dominated conditions. These are compared to the NEXAFS spectra of multilayers and monolayers of C/sub 4/H/sub 8/, C/sub 5/H/sub 8/, C/sub 6/H/sub 12/, and C/sub 8/H/sub 8/ on Pt(111). Multiple scattering X..cap alpha.. calculations of the spectra of cyclopropane, cyclobutane, and cyclohexane are also reported. In most cases the gas and solid spectra are essentially the same indicating that intramolecular transitions dominate in the condensed phase. The NEXAFS polarization dependence of the condensed phases has assisted spectral assignments and the determination of the molecular orientation in the monolayer phase. In the saturated species a sharp feature about 3 eV below the carbon 1s ionization threshold is identified as a transition to a state of mixed Rydberg/valence character with the ..pi..*(CH/sub 2/) valence component dominating. Except for cyclopropane the positions of the main sigma * resonances correlate with the C-C bond lengths in a manner similar to that reported previously for noncyclic aliphatic molecules. In the spectra of monolayer C/sub 6/H/sub 12/, C/sub 5/H/sub 8/, and C/sub 8/H/sub 8/ spectral broadening and weak additional features are observed which are attributed to molecule-surface interactions.

Hitchcock, A.P.; Newbury, D.C.; Ishii, I.; Stoehr, J.; Horsley, J.A.; Redwing, R.D.; Johnson, A.L.; Sette, F.

1986-11-01T23:59:59.000Z

27

Removing the Hydrocarbon from Hydrocarbon Flow ...  

Science Conference Proceedings (OSTI)

... gas and petroleum products. Therefore is important to have primary calibration standards with low uncertainty. NIST has several hydrocarbon liquid ...

2014-01-03T23:59:59.000Z

28

Hydrogen and Gaseous Fuel Safety and Toxicity  

DOE Green Energy (OSTI)

Non-traditional motor fuels are receiving increased attention and use. This paper examines the safety of three alternative gaseous fuels plus gasoline and the advantages and disadvantages of each. The gaseous fuels are hydrogen, methane (natural gas), and propane. Qualitatively, the overall risks of the four fuels should be close. Gasoline is the most toxic. For small leaks, hydrogen has the highest ignition probability and the gaseous fuels have the highest risk of a burning jet or cloud.

Lee C. Cadwallader; J. Sephen Herring

2007-06-01T23:59:59.000Z

29

Portsmouth Gaseous Diffusion Plant, Former Production Workers...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Plant, Former Production Workers Screening Projects Portsmouth Gaseous Diffusion Plant, Former Production Workers Screening Projects Project Name: Worker Health Protection Program...

30

Portsmouth Gaseous Diffusion Plant - Enforcement Documents  

NLE Websites -- All DOE Office Websites (Extended Search)

Inc. related to Installation and Inspection of Penetration Fire Seals at the DUF6 Conversion Building at the Portsmouth Gaseous Diffusion Plant, March 26, 2010 Consent...

31

Hydrocarbon synthesis catalyst and method of preparation  

DOE Patents (OSTI)

A catalyst for the synthesis of hydrocarbons from carbon monoxide and hydrogen composed of palladium or platinum and cobalt supported on a solid phase is disclosed. The catalyst is prepared by heating a heterogeneous component of the palladium or platinum deposited on the solid support in a solution of cobalt carbonyl or precursors thereof. The catalyst exhibits excellent activity, stability in air, and produces highly desirable product fractions even with dilute gaseous reactants. The catalyst is preferably used in dilute slurry form, which is desirable from a heat transfer standpoint.

Sapienza, Richard S. (Shoreham, NY); Sansone, Michael J. (Summit, NJ); Slegeir, William A. R. (Hampton Bays, NY)

1983-08-02T23:59:59.000Z

32

Process for converting light alkanes to higher hydrocarbons  

DOE Patents (OSTI)

A process is disclosed for the production of aromatic-rich, gasoline boiling range hydrocarbons from the lower alkanes, particularly from methane. The process is carried out in two stages. In the first, alkane is reacted with oxygen and hydrogen chloride over an oxyhydrochlorination catalyst such as copper chloride with minor proportions of potassium chloride and rare earth chloride. This produces an intermediate gaseous mixture containing water and chlorinated alkanes. The chlorinated alkanes are contacted with a crystalline aluminosilicate catalyst in the hydrogen or metal promoted form to produce gasoline range hydrocarbons with a high proportion of aromatics and a small percentage of light hydrocarbons (C.sub.2 -C.sub.4). The light hydrocarbons can be recycled for further processing over the oxyhydrochlorination catalyst.

Noceti, Richard P. (Pittsburgh, PA); Taylor, Charles E. (Pittsburgh, PA)

1988-01-01T23:59:59.000Z

33

Independent Oversight Review, Portsmouth Gaseous Diffusion Plant -  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth Gaseous Diffusion Plant Portsmouth Gaseous Diffusion Plant - November 2013 Independent Oversight Review, Portsmouth Gaseous Diffusion Plant - November 2013 November 5, 2013 Review of Preparedness for Severe Natural Phenomena Events at the Portsmouth Gaseous Diffusion Plant This report documents the results of an independent oversight review of the preparedness of the DOE Portsmouth/Paducah Project Office, contractors at the DOE Portsmouth Gaseous Diffusion Plant, and selected non-leased facilities to respond to a severe natural phenomena event (NPE). The review was conducted in July and August 2013 by the U.S. Department of Energy's (DOE) Office of Safety and Emergency Management Evaluations, which is within the DOE Office of Health, Safety and Security (HSS). The HSS Office of Safety and Emergency Management Evaluations performed this

34

Process for exchanging hydrogen isotopes between gaseous hydrogen and water  

DOE Patents (OSTI)

A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

Hindin, Saul G. (Mendham, NJ); Roberts, George W. (Westfield, NJ)

1980-08-12T23:59:59.000Z

35

Illinois Natural Gas Plant Liquids Production, Gaseous Equivalent...  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Illinois Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2...

36

Oklahoma Natural Gas Plant Liquids Production, Gaseous Equivalent...  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Oklahoma Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2...

37

Tennessee Natural Gas Plant Liquids Production, Gaseous Equivalent...  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Tennessee Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2...

38

Florida Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Florida Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

39

Ohio Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Ohio Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

40

Wyoming Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Wyoming Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Montana Natural Gas Plant Liquids Production, Gaseous Equivalent...  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Montana Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

42

Nebraska Natural Gas Plant Liquids Production, Gaseous Equivalent...  

Annual Energy Outlook 2012 (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Nebraska Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2...

43

Utah Natural Gas Plant Liquids Production, Gaseous Equivalent...  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Utah Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

44

Indiana Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Indiana Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2...

45

Alaska Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Alaska Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

46

West Virginia Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) West Virginia Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2...

47

Kansas Natural Gas Plant Liquids Production, Gaseous Equivalent...  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Kansas Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3...

48

Non-Destructive Analysis Calibration Standards for Gaseous Diffusion...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Analysis Calibration Standards for Gaseous Diffusion Plant (GDP) Decommissioning The decommissioning of Gaseous Diffusion Plant facilities requires accurate, non-destructive...

49

Production and Handling Slide 25: The Portsmouth Gaseous Diffusion...  

NLE Websites -- All DOE Office Websites (Extended Search)

Portsmouth Gaseous Diffusion Plant Skip Presentation Navigation First Slide Previous Slide Next Slide Last Presentation Table of Contents The Portsmouth Gaseous Diffusion Plant...

50

Production and Handling Slide 24: The Paducah Gaseous Diffusion...  

NLE Websites -- All DOE Office Websites (Extended Search)

Paducah Gaseous Diffusion Site Skip Presentation Navigation First Slide Previous Slide Next Slide Last Presentation Table of Contents The Paducah Gaseous Diffusion Site Refer to...

51

Combination free electron and gaseous laser  

DOE Patents (OSTI)

A multiple laser having one or more gaseous laser stages and one or more free electron stages. Each of the free electron laser stages is sequentially pumped by a microwave linear accelerator. Subsequently, the electron beam is directed through a gaseous laser, in the preferred embodiment, and in an alternative embodiment, through a microwave accelerator to lower the energy level of the electron beam to pump one or more gaseous lasers. The combination laser provides high pulse repetition frequencies, on the order of 1 kHz or greater, high power capability, high efficiency, and tunability in the synchronous production of multiple beams of coherent optical radiation.

Brau, Charles A. (Los Alamos, NM); Rockwood, Stephen D. (Los Alamos, NM); Stein, William E. (Los Alamos, NM)

1980-01-01T23:59:59.000Z

52

Manhattan Project: K-25 Gaseous Diffusion Plant  

Office of Scientific and Technical Information (OSTI)

K-25 Gaseous Diffusion Plant, Oak Ridge Events > The Uranium Path to the Bomb, 1942-1944 Events > The Uranium Path to the Bomb, 1942-1944 > Working K-25 into the Mix, Oak Ridge:...

53

Independent Oversight Review, Portsmouth Gaseous Diffusion Plant- January 2013  

Energy.gov (U.S. Department of Energy (DOE))

Review of the Portsmouth Gaseous Diffusion Plant Work Planning and Control Activities Prior to Work Execution

54

Gaseous insulators for high voltage electrical equipment  

DOE Patents (OSTI)

Gaseous insulators comprise compounds having high attachment cross sections for electrons having energies in the 0-1.3 electron volt range. Multi-component gaseous insulators comprise compounds and mixtures having overall high electron attachment cross sections in the 0-1.3 electron volt range and moderating gases having high cross sections for inelastic interactions with electrons of energies 1-4 electron volts. Suitable electron attachment components include hexafluorobutyne, perfluorobutene-2, perfluorocyclobutane, perfluorodimethylcyclobutane, perfluorocyclohexene, perfluoromethylcyclohexane, hexafluorobutadiene, perfluoroheptene-1 and hexafluoroazomethane. Suitable moderating gases include N.sub.2, CO, CO.sub.2 and H.sub.2. The gaseous insulating mixture can also contain SF.sub.6, perfluoropropane and perfluorobenzene.

Christophorou, Loucas G. (Oak Ridge, TN); James, David R. (Knoxville, TN); Pace, Marshall O. (Knoxville, TN); Pai, Robert Y. (Concord, TN)

1981-01-01T23:59:59.000Z

55

Gaseous insulators for high voltage electrical equipment  

DOE Patents (OSTI)

Gaseous insulators comprise compounds having high attachment cross sections for electrons having energies in the 0-1.3 electron volt range. Multi-component gaseous insulators comprise compounds and mixtures having overall high electron attachment cross sections in the 0-1.3 electron volt range and moderating gases having high cross sections for inelastic interactions with electrons of energies 1-4 electron volts. Suitable electron attachment components include hexafluorobutyne, perfluorobutene-2, perfluorocyclobutane, perfluorodimethylcyclobutane, perfluorocyclohexene, perfluoromethylcyclohexane, hexafluorobutadiene, perfluoroheptene-1 and hexafluoroazomethane. Suitable moderating gases include N.sub.2, CO, CO.sub.2 and H.sub.2. The gaseous insulating mixture can also contain SF.sub.6, perfluoropropane and perfluorobenzene.

Christophorou, Loucas G. (Oak Ridge, TN); James, David R. (Knoxville, TN); Pace, Marshall O. (Knoxville, TN); Pai, Robert Y. (Concord, TN)

1979-01-01T23:59:59.000Z

56

Glossary - U.S. Energy Information Administration (EIA)  

U.S. Energy Information Administration (EIA)

Sales, revenue and prices, power plants, fuel use, stocks, generation, trade, demand & emissions. ... Isopentane: A saturated branched-chain hydrocarbon ...

57

Independent Activity Report, Portsmouth Gaseous Diffusion Plant - July 2011  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Activity Report, Portsmouth Gaseous Diffusion Plant - Activity Report, Portsmouth Gaseous Diffusion Plant - July 2011 Independent Activity Report, Portsmouth Gaseous Diffusion Plant - July 2011 July 2011 Orientation Visit to the Portsmouth Gaseous Diffusion Plant [HIAR-PAD-2011-07-27] The purpose of the visit was to discuss the nuclear safety oversight strategy, describe the site lead program, increase HSS personnel's operational awareness of the site's activities, and to determine how HSS can carry out its independent oversight and mission support responsibilities. Independent Activity Report, Portsmouth Gaseous Diffusion Plant - July 2011 More Documents & Publications Independent Activity Report, Portsmouth Gaseous Diffusion Plant - August 2011 Independent Activity Report, Argonne National Laboratory - August 2011

58

Independent Oversight Review, Portsmouth Gaseous Diffusion Plant- April 2013  

Energy.gov (U.S. Department of Energy (DOE))

Review of the Integrated Safety Management System Phase I Verification Review at the Portsmouth Gaseous Diffusion Plant

59

Gaseous modification of MCrAlY coatings  

SciTech Connect

The present invention generally describes methods for modifying MCrAlY coatings by using gaseous carburization, gaseous nitriding or gaseous carbonitriding. The modified MCrAlY coatings are useful in thermal barrier coating systems, which may be used in gas turbine engines.

Vance, Steven J. (Orlando, FL); Goedjen, John G. (Oviedo, FL); Sabol, Stephen M. (Orlando, FL); Sloan, Kelly M. (Longwood, FL)

2000-01-01T23:59:59.000Z

60

Plasma Processing Of Hydrocarbon  

SciTech Connect

The Idaho National Laboratory (INL) developed several patented plasma technologies for hydrocarbon processing. The INL patents include nonthermal and thermal plasma technologies for direct natural gas to liquid conversion, upgrading low value heavy oil to synthetic light crude, and to convert refinery bottom heavy streams directly to transportation fuel products. Proof of concepts has been demonstrated with bench scale plasma processes and systems to convert heavy and light hydrocarbons to higher market value products. This paper provides an overview of three selected INL patented plasma technologies for hydrocarbon conversion or upgrade.

Grandy, Jon D; Peter C. Kong; Brent A. Detering; Larry D. Zuck

2007-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Non-Destructive Analysis Calibration Standards for Gaseous Diffusion Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Non-Destructive Analysis Calibration Standards for Gaseous Non-Destructive Analysis Calibration Standards for Gaseous Diffusion Plant (GDP) Decommissioning Non-Destructive Analysis Calibration Standards for Gaseous Diffusion Plant (GDP) Decommissioning The decommissioning of Gaseous Diffusion Plant facilities requires accurate, non-destructive assay (NDA) of residual enriched uranium in facility components for safeguards and nuclear criticality safety purposes. Current practices used to perform NDA measurements frequently have poorly defined uncertainties due to multiple factors. Working reference material (WRM) standards and container-specific surrogates are required to verify and validate NDA methods used to support characterization of gaseous diffusion equipment within the D&D project. Because working reference

62

Gaseous Diffusion Plant Production Workers Needs Assessment  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Department of Energy Gaseous Diffusion Plants Department of Energy Gaseous Diffusion Plants Phase I: Needs Assessment Robert Wages Oil, Chemical and Atomic Inte national Union Steven Markowitz Mount Sinai School of Medicine Sylvia Kieding Oil, Chemical and Atomic International Union Mark Griffon University of Massachusetts Lowell Elizabeth Averill Samaras Alice Hamilton College October 1, 1997 TABLE OF CONTENTS Page Number Executive Summary 1 J: OVERVIEW 1. Introduction 2-3 2. Methods 3-8 3. Principal Findings 9-16 4. Need for Medical Surveillance and Risk Communication 16-17 PART II: METHODOLOGY AND RESULTS 4. Exposure Assessment Appendix A Appendix B Appendix C 5. Focus Group Results Appendix A Appendix B Appendix C 6. Epidemiology and Other Health Studies EXECUTIVE SUMMARY Purpose We report the results and analysis of a one year needs assessment study evaluating

63

Direct conversion of light hydrocarbon gases to liquid fuel  

DOE Green Energy (OSTI)

The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

Foral, M.J.

1991-01-01T23:59:59.000Z

64

Direct conversion of light hydrocarbon gases to liquid fuel  

DOE Green Energy (OSTI)

The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

Foral, M.J.

1990-01-01T23:59:59.000Z

65

Alternative gaseous-fuels safety assessment  

DOE Green Energy (OSTI)

A relative safety assessment of alternative gaseous and reference liquid fuels utilized for light automotive transportation in the public sector was completed. The specific fuels considered were compressed natural gas (CNG), liquefied natural gas (LNG), liquefied petroleum gas (LPG), and the liquid fuels, gasoline and diesel. The assessment methodology describes and develops the relative hazards of these fuels from an integrated generic physicochemical property and accident scenario point of view. A technique involving a method of eliciting expert judgment combined with a comparative scoring methodology was applied in establishing fuel relative safety rankings. Limitations of this type of assessment are discussed. Selected accident scenarios included fuel leakage in both residential and public garages; fueling line rupture at a refueling station in the presence of user vehicles or delivery vehicles; and vehicle collisions under rural, urban, and vehicular tunnel conditions. Overall, the results obtained demonstrate dependency upon the specific application or scenario. Gaseous fuels have increased relative risks in certain situations and are relatively safe in others. The results suggest that alternative gaseous fuels are not disqualified for public usage. The assessment also provides rationale for the development of selected safe handling criteria and recommendations.

Krupka, M.C.; Peaslee, A.T. Jr.; Laquer, H.L.

1983-01-01T23:59:59.000Z

66

Hydrocarbon adsorption system  

SciTech Connect

In a solid adsorbent hydrocarbon recovery system for processing natural gas, towers adapted for performing adsorbing, cooling, and regenerating functions are used. It is recommended that a regeneration gas be used of substantially uniform richness in hydrocarbons in the closed-cycle regeneration system. The natural gas stream is flowed through an adsorbent bed to remove liquid hydrocarbons. A portion of the stripped gas stream is flowed through a second adsorbent bed for cooling purposes. A heated, rich, regeneration gas is circulated through a closed-cycle regeneration system that includes a third adsorbent bed. This rich regeneration gas is combined with the stripped gas stream. These steps are repeated in a cyclic operation. (10 claims)

Humphries, C.L.

1966-11-29T23:59:59.000Z

67

K-25 Gaseous Diffusion Process Building | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Operational Management » History » Manhattan Project » Signature Operational Management » History » Manhattan Project » Signature Facilities » K-25 Gaseous Diffusion Process Building K-25 Gaseous Diffusion Process Building K-25 Gaseous Diffusion Process Building The K-25 plant, located on the southwestern end of the Oak Ridge reservation, used the gaseous diffusion method to separate uranium-235 from uranium-238. Based on the well-known principle that molecules of a lighter isotope would pass through a porous barrier more readily than molecules of a heavier one, gaseous diffusion produced through myriads of repetitions a gas increasingly rich in uranium-235 as the heavier uranium-238 was separated out in a system of cascades. Although producing minute amounts of final product measured in grams, gaseous diffusion required a massive

68

Band Formation during Gaseous Diffusion in Aerogels  

E-Print Network (OSTI)

We study experimentally how gaseous HCl and NH_3 diffuse from opposite sides of and react in silica aerogel rods with porosity of 92 % and average pore size of about 50 nm. The reaction leads to solid NH_4Cl, which is deposited in thin sheet-like structures. We present a numerical study of the phenomenon. Due to the difference in boundary conditions between this system and those usually studied, we find the sheet-like structures in the aerogel to differ significantly from older studies. The influence of random nucleation centers and inhomogeneities in the aerogel is studied numerically.

M. A. Einarsrud; F. A. Maao; A. Hansen; M. Kirkedelen; J. Samseth

1997-06-18T23:59:59.000Z

69

Hydrocarbon/Total Combustibles Sensor  

the invention is an electrochemical hydrocarbon sensor that is more reliable and reproducible than any other hydrocarbon sensor on the market today. The patented method for producing the sensor ensures reproducibility and reduces the need for ...

70

Origin of gaseous hydrocarbons from Upper Cretaceous and Tertiary strata in the Piceance basin, western Colorado  

E-Print Network (OSTI)

Natural gas samples were collected for geochemical analyses from Upper Cretaceous and Tertiary strata of the Piceance basin in western Colorado to: 1) determine the origin of gases (i.e., microbial versus thermogenic), 2) determine the thermogenic source rock(s) for the gas-rich Williams Fork Formation, and 3) assess the nature of gas migration. Mud logging gases were sampled approximately every 60 m between 350 and 2800 m and analyzed for "C compositions and CI/C,-3 ratios. Samples collected from low gas content intervals above 1950 m define two parallel trends of increasing "Cc, content with depth. Data from the first trend are based on eighteen analyses and range from-69.9 to-38.3%o (R 2 = 0.92). These data suggest a microbial and mixed microbial/thermogenic origin for methane. Only one sample from above 1950 m contained sufficient amounts of C2for isotopic analysis (813 CC2 =-27.0%o at 1718 m). Data from the second trend are based on seven analyses and are offset by approximately +20%o compared with the primary trend at comparable depths. These data range from-65.0 to-38.5%0 (R' = 0.84). 813c ci and C,/CI-3data from both trends are similar when viewed on a crossplot, thus suggesting that large-scale, vertical gas migration has occurred. Migration was probably aided by fractures that formed during maximum burial and peak gas generation. Except for one sample collected at 1718 m, "CC2compositions above 1950 m were not determined due to insufficient sample sizes. Below 1950 m, gas contents abruptly increase and approach 10-4' gas units. These gases have "C compositions indicative of thermogenic origin. Gases between 1950 and 2450 m have relatively uniform geochemistries (8"Cc, =-39.9 0?.3%ol 613C C2 =-27.4 I?.i%ol CI/Cl-3 = 0-91 0?.03), and are chemically distinct and therefore Renetically different from gases between 2450 and 2791 M (513C ci =-37.9 +-O.2%og 813C C2 =-26.4 0?.5%09 CI/Cl-3 = 0.88 0?.01). Gases of the latter group were probably derived from coalbeds that comprise the Cameo Group, as abundant coals are found between 2450 and 2630 m. Only three thin coalbeds occur within the Coal Ridge Group between 1950 and 2450 m, so gases from this interval were probably derived from interbedded shales. Core and cuttings samples were also collected and sealed in cans from several intervals for geochemical analyses. Canned methanes at or above 858 m are "C-enriched by 13 to 33%o compared with logging methanes at equivalent intervals. Below 1934 m, however, 813C ci values for core and cuttings are comparable to logging gas values. This observation suggests that 813 Cc, discrepancies above 858 m are related to low gas contents in the core and cutting samples. Therefore, geochemical data from core and cuttings were not used to assess migration or to interpret gas origin.

Katz, David Jonathan

1997-01-01T23:59:59.000Z

71

Orientation Visit to the Paducah Gaseous Diffusion Plant  

NLE Websites -- All DOE Office Websites (Extended Search)

PAD-2011-07-27 Site: Paducah Gaseous Diffusion Plant Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for the...

72

,"North Dakota Natural Gas Plant Liquids Production, Gaseous...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","North Dakota Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release...

73

,"Tennessee Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","Tennessee Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet)",1,"Annual",2012...

74

,"U.S. Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","U.S. Natural Gas Plant Liquids Production, Gaseous Equivalent (Bcf)",1,"Monthly","92013" ,"Release...

75

,"New Mexico Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release...

76

,"Arkansas Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","Arkansas Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release...

77

,"Colorado Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","Colorado Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release...

78

,"Kentucky Natural Gas Plant Liquids Production, Gaseous Equivalent...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","Kentucky Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release...

79

,"West Virginia Natural Gas Plant Liquids Production, Gaseous...  

U.S. Energy Information Administration (EIA) Indexed Site

Of Series","Frequency","Latest Data for" ,"Data 1","West Virginia Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release...

80

Former Worker Medical Screening Program - Paducah Gaseous Diffusion...  

NLE Websites -- All DOE Office Websites (Extended Search)

Paducah Gaseous Diffusion Plant Construction Workers Former Worker Medical Screening Program (FWP) Project Name: Building Trades National Medical Screening Program Covered DOE...

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

The Thermodynamics of Gaseous, Cuprous Chloride Monomer and Trimer  

E-Print Network (OSTI)

No.W-7405-eng~48B TIiE THERMODYNAMICS OF GASEOUS" CUPROUSCu(s) + HCl::= I Thermodynamics of Vaporization to Monomeric

Brewer, Leo

2010-01-01T23:59:59.000Z

82

Virtual Screening of Materials for Gaseous Fuel Storage  

Science Conference Proceedings (OSTI)

Presentation Title, Virtual Screening of Materials for Gaseous Fuel Storage .... Numerical Study on Behavior of Top-Blown Supersonic Jets and Their Interaction ...

83

Dispersant solutions for dispersing hydrocarbons  

DOE Patents (OSTI)

A dispersant solution includes a hydrocarbon dispersing solution derived from a bacterium from ATCC 75527, ATCC 75529, or ATCC 55638.

Tyndall, Richard L. (Clinton, TN)

1997-01-01T23:59:59.000Z

84

Catalysts for hydrocarbon conversion  

Science Conference Proceedings (OSTI)

Catalyst, particularly useful in catalytic reforming and for producing highly pure aromatic hydrocarbons, comprising an alumina carrier and containing, expressed in proportion of the weight of the alumina carrier: 005 to 1% of platinum 01 to 4% of gallium, indium or thallium 01 to 2% of tungsten, and 1 to 10% of halogen.

Le P. J.; Malmaison, R.; Marcilly, C.; Martino, G.; Miquel, J.

1980-08-12T23:59:59.000Z

85

Thermal device and method for production of carbon monoxide and hydrogen by thermal dissociation of hydrocarbon gases  

DOE Patents (OSTI)

Carbon monoxide is produced in a fast quench reactor. The production of carbon monoxide includes injecting carbon dioxide and some air into a reactor chamber having a high temperature at its inlet and a rapidly expanding a reactant stream, such as a restrictive convergent-divergent nozzle at its outlet end. Carbon dioxide and other reactants such as methane and other low molecular weight hydrocarbons are injected into the reactor chamber. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The resulting heated gaseous stream is then rapidly cooled by expansion of the gaseous stream.

Detering, Brent A. (Idaho Falls, ID); Kong, Peter C. (Idaho Falls, ID)

2001-01-01T23:59:59.000Z

86

2011 GASEOUS IONS GORDON RESEARCH CONFERENCE  

DOE Green Energy (OSTI)

The Gaseous Ions: Structures, Energetics and Reactions Gordon Research Conference will focus on ions and their interactions with molecules, surfaces, electrons, and light. The conference will cover theory and experiments, and systems ranging from molecular to biological to clusters to materials. The meeting goal continues to be bringing together scientists interested in fundamentals, with those applying fundamental phenomena to a wide range of practical problems. Each of the ten conference sessions will focus on a topic within this spectrum, and there will also be poster sessions for contributed papers, with sufficient space and time to allow all participants to present their latest results. To encourage active participation by young investigators, about ten of the poster abstracts will be selected for 15 minute 'hot topic' talks during the conference sessions. Hot topic selection will be done about a month before the meeting. Funds should be available to offset the participation cost for young investigators.

Scott Anderson

2011-03-04T23:59:59.000Z

87

2011 GASEOUS IONS GORDON RESEARCH CONFERENCE  

SciTech Connect

The Gaseous Ions: Structures, Energetics and Reactions Gordon Research Conference will focus on ions and their interactions with molecules, surfaces, electrons, and light. The conference will cover theory and experiments, and systems ranging from molecular to biological to clusters to materials. The meeting goal continues to be bringing together scientists interested in fundamentals, with those applying fundamental phenomena to a wide range of practical problems. Each of the ten conference sessions will focus on a topic within this spectrum, and there will also be poster sessions for contributed papers, with sufficient space and time to allow all participants to present their latest results. To encourage active participation by young investigators, about ten of the poster abstracts will be selected for 15 minute 'hot topic' talks during the conference sessions. Hot topic selection will be done about a month before the meeting. Funds should be available to offset the participation cost for young investigators.

Scott Anderson

2011-03-04T23:59:59.000Z

88

Gaseous-fuel safety assessment. Status report  

DOE Green Energy (OSTI)

The Los Alamos National Laboratory, in support of studies sponsored by the Office of Vehicle and Engine Research and Development in the US Department of Energy, has undertaken a safety assessment of selected gaseous fuels for use in light automotive transportation. The purpose is to put into perspective the hazards of these fuels relative to present day fuels and delineated criteria for their safe handling. Fuels include compressed and liquified natural gas (CNG and LNG), liquefied petroleum gas (LPG), and for reference gasoline and diesel. This paper is a program status report. To date, physicochemical property data and general petroleum and transportation information were compiled; basic hazards defined; alternative fuels were safety-ranked based on technical properties alone; safety data and vehicle accident statistics reviewed; and accident scenarios selected for further analysis. Methodology for such analysis is presently under consideration.

Krupka, M.C.; Edeskuty, F.J.; Bartlit, J.R.; Williamson, K.D. Jr.

1982-01-01T23:59:59.000Z

89

DOE - Office of Legacy Management -- Portsmouth Gaseous Diffusion Plant -  

Office of Legacy Management (LM)

Portsmouth Gaseous Diffusion Plant Portsmouth Gaseous Diffusion Plant - 026 FUSRAP Considered Sites Site: Portsmouth Gaseous Diffusion Plant (026 ) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition: Radioactive Materials Handled: Primary Radioactive Materials Handled: Radiological Survey(s): Site Status: The Portsmouth Gaseous Diffusion Plant (PGDP) is located in south central Ohio, approximately 20 miles north of Portsmouth, Ohio and 70 miles south of Columbus, Ohio. Construction of the PGDP began in late 1952 to expand the Federal Government¿s gaseous diffusion program already in place at Oak Ridge, Tennessee and Paducah, Kentucky. The facility was built to increase the production of enriched uranium at rates substantially above the other

90

Property:PotentialBiopowerGaseousGeneration | Open Energy Information  

Open Energy Info (EERE)

PotentialBiopowerGaseousGeneration PotentialBiopowerGaseousGeneration Jump to: navigation, search Property Name PotentialBiopowerGaseousGeneration Property Type Quantity Description The estimated potential energy generation from gaseous biopower for a particular place. Use this type to express a quantity of energy. The default unit for energy on OpenEI is the Kilowatt hour (kWh), which is 3,600,000 Joules. http://en.wikipedia.org/wiki/Unit_of_energy It's possible types are Watt hours - 1000 Wh, Watt hour, Watthour Kilowatt hours - 1 kWh, Kilowatt hour, Kilowatthour Megawatt hours - 0.001 MWh, Megawatt hour, Megawatthour Gigawatt hours - 0.000001 GWh, Gigawatt hour, Gigawatthour Joules - 3600000 J, Joules, joules Pages using the property "PotentialBiopowerGaseousGeneration" Showing 25 pages using this property. (previous 25) (next 25)

91

Property:PotentialBiopowerGaseousMass | Open Energy Information  

Open Energy Info (EERE)

PotentialBiopowerGaseousMass PotentialBiopowerGaseousMass Jump to: navigation, search Property Name PotentialBiopowerGaseousMass Property Type Quantity Description The potential mass of gaseous biopower material for a place. Use this type to express a quantity of magnitude, or an object's resistance to acceleration. The default unit is the kilogram (kg). http://en.wikipedia.org/wiki/Kilogram Acceptable units (and their conversions) are: Kilograms - 1 kg, kilo, kilogram, kilograms, Kilogram, kilogramme, kilos Grams - 1000 g, gram, gramme, grams Tonnes - 0.001 tonnes, metric tons, Tonnes, Metric Tonnes Pounds - 2.205 lbs, pounds, pound, Pounds, Lbs Stone - 0.1575 stones, st, stone Ounces - 35.27 ounces, oz, Ounces, ounce BDT - 0.001 BDT, Bone Dry Tonnes, bdt Pages using the property "PotentialBiopowerGaseousMass"

92

Enforcement Documents - Portsmouth Gaseous Diffusion Plant | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth Gaseous Diffusion Plant Portsmouth Gaseous Diffusion Plant Enforcement Documents - Portsmouth Gaseous Diffusion Plant March 26, 2010 Enforcement Letter, Intennech, Inc. - March 26, 2010 Enforcement Letter issued to Intermech, Inc. related to Installation and Inspection of Anchor Bolts and Pipe Supports at the DUF6 Conversion Buildings at the Portsmouth and Paducah Gaseous Diffusion Plants March 26, 2010 Enforcement Letter, Geiger Brothers Mechanical Contractors, INC - March 26, 2010 Enforcement Letter issued to Geiger Brothers Mechanical Contractors, Inc. related to Installation and Inspection of Penetration Fire Seals at the DUF6 Conversion Building at the Portsmouth Gaseous Diffusion Plant March 26, 2010 Consent Order, Uranium Disposition Services, LLC - NCO-2010-01 Consent Order issued to Uranium Disposition Services, LLC related to

93

Orientation Visit to the Paducah Gaseous Diffusion Plant, July 2011 |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Orientation Visit to the Paducah Gaseous Diffusion Plant, July 2011 Orientation Visit to the Paducah Gaseous Diffusion Plant, July 2011 Orientation Visit to the Paducah Gaseous Diffusion Plant, July 2011 The U.S. Department of Energy (DOE) Office of Enforcement and Oversight, within the Office of Health, Safety and Security (HSS), conducted an orientation visit to the DOE Paducah Site Office (PAD) from July 25-27, 2011. The purpose of the visit was to discuss the nuclear safety oversight strategy, describe the site lead program, increase HSS personnel's operational awareness of the site's activities, and to determine how HSS can carry out its independent oversight and mission support responsibilities. Orientation Visit to the Paducah Gaseous Diffusion Plant, July 2011 More Documents & Publications Independent Activity Report, Portsmouth Gaseous Diffusion Plant - August

94

Gaseous Emissions From Steamboat Springs, Brady'S Hot Springs, And Desert  

Open Energy Info (EERE)

Gaseous Emissions From Steamboat Springs, Brady'S Hot Springs, And Desert Gaseous Emissions From Steamboat Springs, Brady'S Hot Springs, And Desert Peak Geothermal Systems, Nevada Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Conference Paper: Gaseous Emissions From Steamboat Springs, Brady'S Hot Springs, And Desert Peak Geothermal Systems, Nevada Details Activities (3) Areas (3) Regions (0) Abstract: Gaseous emissions from the landscape can be used to explore for geothermal systems, characterize their lateral extent, or map the trends of concealed geologic structures that may provide important reservoir permeability at depth. Gaseous geochemical signatures vary from system to system and utilization of a multi-gas analytical approach to exploration or characterization should enhance the survey's clarity. This paper describes

95

Hydrocarbon reclaimer system  

SciTech Connect

This patent describes a filtering process for filtering sludge from a finished product oil storage tank and thereby separating solids from oil and hydrocarbon. The process requires no added water, solvents or diluents. It comprises: pumping a volume sludge from a finished product oil storage tank to a mixing tank; mixing the sludge; sampling the sludge to determine solid content; adding filter aid comprising diatomaceous earth to the mixing tank; mixing the filter aid with the sludge in the mixing tank; enclosing and sealing a plurality of filter plates inside a horizontal plate filter; pressurizing the horizontal plate filter by operation of pump means; pumping the sludge from the mixing tank through the horizontal plate filter to filter out solids; recirculating the sludge from the horizontal plate filter back through the mixing tank; and pumping a purified hydrocarbon and water filtrate from the horizontal plate filter.

Uremovich, M.J.

1990-09-04T23:59:59.000Z

96

FROZEN HYDROCARBONS IN COMETS  

SciTech Connect

Recent investigations of the luminescence of frozen hydrocarbon particles of icy cometary halos have been carried out. The process of luminescence of organic icy particles in a short-wavelength solar radiation field is considered. A comparative analysis of observed and laboratory data leads to 72 luminescent emission lines in the spectrum of the comet 153P/Ikeya-Zhang. The concept of cometary relict matter is presented, and the creation of a database of unidentified cometary emission lines is proposed.

Simonia, Irakli, E-mail: irakli.simonia@jcu.edu.au [School of Graduate Studies, Ilia State University, 3/5 Cholokashvili Street, Tbilisi, 0162 (Georgia); Center for Astronomy, James Cook University, Townsville QLD 4811 (Australia)

2011-02-15T23:59:59.000Z

97

THERMOCHEMISTRY OF HYDROCARBON RADICALS  

DOE Green Energy (OSTI)

Gas phase negative ion chemistry methods are employed to determine enthalpies of formation of hydrocarbon radicals that are important in combustion processes and to investigate the dynamics of ion-molecule reactions. Using guided ion beam tandem mass spectrometry, we measure collisional threshold energies of endoergic proton transfer and hydrogen atom transfer reactions of hydrocarbon molecules with negative reagent ions. The measured reaction threshold energies for proton transfer yield the relative gas phase acidities. In an alternative methodology, competitive collision-induced dissociation of proton-bound ion-molecule complexes provides accurate gas phase acidities relative to a reference acid. Combined with the electron affinity of the R {center_dot} radical, the gas phase acidity yields the RH bond dissociation energy of the corresponding neutral molecule, or equivalently the enthalpy of formation of the R{center_dot} organic radical, using equation: D(R-H) = {Delta}{sub acid}H(RH) + EA(R) - IE(H). The threshold energy for hydrogen abstraction from a hydrocarbon molecule yields its hydrogen atom affinity relative to the reagent anion, providing the RH bond dissociation energy directly. Electronic structure calculations are used to evaluate the possibility of potential energy barriers or dynamical constrictions along the reaction path, and as input for RRKM and phase space theory calculations. In newer experiments, we have measured the product velocity distributions to obtain additional information on the energetics and dynamics of the reactions.

Kent M. Ervin, Principal Investigator

2004-08-17T23:59:59.000Z

98

HYDROCARBON LIQUID FLOW CALIBRATION SERVICE ...  

Science Conference Proceedings (OSTI)

... and is the cross correlation coefficient ... a NIST Hydrocarbon Liquid Flow Calibration Facility ... FED2004-56790, 2004 Heat Transfer/Fluids Engineering ...

2012-05-21T23:59:59.000Z

99

HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS  

E-Print Network (OSTI)

or natural gas or even oil shale (which represents anotherto transform the coal or oil shale or gaseous, fuel. There

Calvin, Melvin

2013-01-01T23:59:59.000Z

100

Gaseous Detectors: recent developments and applications  

E-Print Network (OSTI)

Since long time, the compelling scientific goals of future high energy physics experiments were a driving factor in the development of advanced detector technologies. A true innovation in detector instrumentation concepts came in 1968, with the development of a fully parallel readout for a large array of sensing elements - the Multiwire Proportional Chamber (MWPC), which earned Georges Charpak a Nobel prize in physics in 1992. Since that time radiation detection and imaging with fast gaseous detectors, capable of economically covering large detection volume with low mass budget, have been playing an important role in many fields of physics. Advances in photo-lithography and micro-processing techniques in the chip industry during the past decade triggered a major transition in the field of gas detectors from wire structures to Micro-Pattern Gas Detector (MPGD) concepts, revolutionizing cell size limitations for many gas detector applications. The high radiation resistance and excellent spatial and time resolution make them an invaluable tool to confront future detector challenges at the next generation of colliders. The design of the new micro-pattern devices appears suitable for industrial production. Novel structures where MPGDs are directly coupled to the CMOS pixel readout represent an exciting field allowing timing and charge measurements as well as precise spatial information in 3D. Originally developed for the high energy physics, MPGD applications has expanded to nuclear physics, UV and visible photon detection, astroparticle and neutrino physics, neutron detection and medical physics.

Maxim Titov

2010-08-23T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Natural Gas Plant Net Stocks Natural Gas Plant Net Stocks Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Butylene (C4H8) An olefinic hydrocarbon recovered from refinery processes. Ethane (C2H6) A normally gaseous straight-chain hydrocarbon. It is a colorless paraffinic gas that boils at a temperature of -127.48º F. It is extracted from natural gas and refinery gas streams. Isobutane (C4H10) A normally gaseous branch-chain hydrocarbon. It is a colorless paraffinic gas that boils at a temperature of 10.9º F. It is extracted from natural gas or refinery gas streams. Liquefied Petroleum Gases (LPG) A group of hydrocarbon-based gases derived from crude oil refining or nautral gas fractionation. They include: ethane, ethylene, propane, propylene, normal butane, butylene, isobutane, and isobutylene. For convenience of transportation, these gases are liquefied through pressurization.

102

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Plant Field Production Plant Field Production Definitions Key Terms Definition Barrel A unit of volume equal to 42 U.S. gallons. Butylene (C4H8) An olefinic hydrocarbon recovered from refinery processes. Ethane (C2H6) A normally gaseous straight-chain hydrocarbon. It is a colorless paraffinic gas that boils at a temperature of -127.48º F. It is extracted from natural gas and refinery gas streams. Field Production Represents crude oil production on leases, natural gas liquids production at natural gas processing plants, new supply of other hydrocarbons/oxygenates and motor gasoline blending components, and fuel ethanol blended into finished motor gasoline. Isobutane (C4H10) A normally gaseous branch-chain hydrocarbon. It is a colorless paraffinic gas that boils at a temperature of 10.9º F. It is extracted from natural gas or refinery gas streams.

103

Pennsylvania Natural Gas Plant Liquids Production, Gaseous Equivalent  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Pennsylvania Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 121 116 93 1970's 79 55 70 71 75 68 61 45 64 49 1980's 41 29 40 55 61 145 234 318 272 254 1990's 300 395 604 513 513 582 603 734 732 879 2000's 586 691 566 647 634 700 794 859 1,008 1,295 2010's 4,578 8,931 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 12/12/2013 Next Release Date: 1/7/2014 Referring Pages: NGPL Production, Gaseous Equivalent Pennsylvania Natural Gas Plant Processing

104

Energy Department Completes K-25 Gaseous Diffusion Building Demolition |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Energy Department Completes K-25 Gaseous Diffusion Building Energy Department Completes K-25 Gaseous Diffusion Building Demolition Energy Department Completes K-25 Gaseous Diffusion Building Demolition December 19, 2013 - 12:00pm Addthis K-25 Demolition - Oak Ridge 2013 K-25 Demolition - Oak Ridge 2013 Media Contacts Ben Williams, DOE, (865) 574-4912 Wayne McKinney, UCOR, (865) 576-6284 Oak Ridge, Tenn. - Today, the Department of Energy announced that its contractor URS|CH2M Oak Ridge, LLC, or UCOR, has completed demolition of the K-25 gaseous diffusion building, the largest facility in the DOE complex. UCOR took over the project in 2011 and has maintained a strong safety record while completing the demolition over one year ahead of its current schedule and approximately $300 million under the current budget. All debris removal is expected to be completed in spring 2014.

105

Property:PotentialBiopowerGaseousCapacity | Open Energy Information  

Open Energy Info (EERE)

PotentialBiopowerGaseousCapacity PotentialBiopowerGaseousCapacity Jump to: navigation, search Property Name PotentialBiopowerGaseousCapacity Property Type Quantity Description The nameplate capacity technical potential from gaseous biopower for a particular place. Use this property to express potential electric energy generation, such as Nameplate Capacity. The default unit is megawatts (MW). For spatial capacity, use property Volume. Acceptable units (and their conversions) are: 1 MW,MWe,megawatt,Megawatt,MegaWatt,MEGAWATT,megawatts,Megawatt,MegaWatts,MEGAWATT,MEGAWATTS 1000 kW,kWe,KW,kilowatt,KiloWatt,KILOWATT,kilowatts,KiloWatts,KILOWATT,KILOWATTS 1000000 W,We,watt,watts,Watt,Watts,WATT,WATTS 1000000000 mW,milliwatt,milliwatts,MILLIWATT,MILLIWATTS 0.001 GW,gigawatt,gigawatts,Gigawatt,Gigawatts,GigaWatt,GigaWatts,GIGAWATT,GIGAWATTS

106

DOE Seeks Deactivation Contractor for Paducah Gaseous Diffusion Plant  

Energy.gov (U.S. Department of Energy (DOE))

Cincinnati The U.S. Department of Energy (DOE) today issued a Request for Task Proposal (RTP) for deactivation activities at the Paducah Gaseous Diffusion Plant (GDP) in Paducah, Kentucky.

107

Feasibility of gas-phase decontamination of gaseous diffusion equipment  

SciTech Connect

The five buildings at the K-25 Site formerly involved in the gaseous diffusion process contain 5000 gaseous diffusion stages as well as support facilities that are internally contaminated with uranium deposits. The gaseous diffusion facilities located at the Portsmouth Gaseous Diffusion Plant and the Paducah Gaseous Diffusion Plant also contain similar equipment and will eventually close. The decontamination of these facilities will require the most cost-effective technology consistent with the criticality, health physics, industrial hygiene, and environmental concerns; the technology must keep exposures to hazardous substances to levels as low as reasonably achievable (ALARA). This report documents recent laboratory experiments that were conducted to determine the feasibility of gas-phase decontamination of the internal surfaces of the gaseous diffusion equipment that is contaminated with uranium deposits. A gaseous fluorinating agent is used to fluorinate the solid uranium deposits to gaseous uranium hexafluoride (UF{sub 6}), which can be recovered by chemical trapping or freezing. The lab results regarding the feasibility of the gas-phase process are encouraging. These results especially showed promise for a novel decontamination approach called the long-term, low-temperature (LTLT) process. In the LTLT process: The equipment is rendered leak tight, evacuated, leak tested, and pretreated, charged with chlorine trifluoride (ClF{sub 3}) to subatmospheric pressure, left for an extended period, possibly > 4 months, while processing other items. Then the UF{sub 6} and other gases are evacuated. The UF{sub 6} is recovered by chemical trapping. The lab results demonstrated that ClF{sub 3} gas at subatmospheric pressure and at {approx} 75{degree}F is capable of volatilizing heavy deposits of uranyl fluoride from copper metal surfaces sufficiently that the remaining radioactive emissions are below limits.

Munday, E.B.; Simmons, D.W.

1993-02-01T23:59:59.000Z

108

Hydrocarbons in the deep earth  

NLE Websites -- All DOE Office Websites (Extended Search)

composed of the elements hydrogen and carbon) are the main building block of crude oil and natural gas. Hydrocarbons contribute to the global carbon cycle (one of the most...

109

Hydrocarbon adsorption apparatus and process  

SciTech Connect

A method of recovering hydrocarbons from natural gas by the use of solid adsorbents consists of 3 steps. The main flow stream of natural gas is passed through a first and only bed of solid adsorbent so that at least a portion of the hydrocarbons present is adsorbed in the bed. A heated regeneration gas is next passed through a second bed of solid adsorbent so that at least a portion of the hydrocarbons is desorbed from the bed. The main flow of natural gas is passed through the second and only bed when in a heated condition after regeneration and the flow of heated regeneration gas is passed through the first bed. The hydrocarbons desorbed from the first and second beds from the regeneration gas are recovered while the previous 3 steps are repeated. (6 claims)

Humphries, C.L.

1966-12-06T23:59:59.000Z

110

Hydrocarbon synthesis catalyst and method of preparation and use thereof. [DOE patent application  

DOE Patents (OSTI)

A catalyst for the synthesis of hydrocarbons from carbon monoxide and hydrogen composed of palladium or platinum and cobalt supported on a solid phase is disclosed. The catalyst is prepared by heating a heterogeneous component of the palladium or platinum deposited on the solid support in a solution of cobalt carbonyl or precursors thereof. The catalyst exhibits excellent activity, stability in air, and produces highly desirable product fractions even with dilute gaseous reactants. The catalyst is preferably used in dilute slurry form, which is desirable from a heat transfer standpoint.

Sapienza, R.S.; Sansone, M.J.; Slegeir, W.A.R.

1981-08-14T23:59:59.000Z

111

Independent Oversight Review, Portsmouth Gaseous Diffusion Plant - April  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

April 2013 April 2013 Independent Oversight Review, Portsmouth Gaseous Diffusion Plant - April 2013 April 2013 Review of the Integrated Safety Management System Phase I Verification Review at the Portsmouth Gaseous Diffusion Plant The Office of Enforcement and Oversight (Independent Oversight), within the Office of Health, Safety and Security (HSS), conducted an independent review of the U.S. Department of Energy (DOE) Portsmouth/Paducah Project Office (PPPO). The objective of the Independent Oversight review was to evaluate PPPO's conduct of the Integrated Safety Management System (ISMS) Phase I verification review at the Portsmouth Gaseous Diffusion Plant (PORTS). The contractor at PORTS is Fluor-Babcock & Wilcox Portsmouth (FBP). The HSS Office of Safety and Emergency Management Evaluations

112

Paducah Gaseous Diffusion Plant, Construction Worker Screening Project |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Paducah Gaseous Diffusion Plant, Construction Worker Screening Paducah Gaseous Diffusion Plant, Construction Worker Screening Project Paducah Gaseous Diffusion Plant, Construction Worker Screening Project Project Name: Building Trades National Medical Screening Program Covered DOE Site: Paducah Worker Population Served: Construction Workers Principal Investigator: Knut Ringen, DrPH, MHA, MPH Toll-free Telephone: (888) 464-0009 Local Outreach Office: Joe Hudson 1930 North 13th Street Paducah, KY 42001 Website: http://www.btmed.org This project is intended to provide free medical screening to former workers in the building trades (construction workers). The screening targets health problems resulting from exposures, including asbestos, beryllium, cadmium, chromium, lead, mercury, noise, radiation, silica and/or solvents. The project is being carried out by a large group led by

113

Portsmouth Gaseous Diffusion Plant, Former Production Workers Screening  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth Gaseous Diffusion Plant, Former Production Workers Portsmouth Gaseous Diffusion Plant, Former Production Workers Screening Projects Portsmouth Gaseous Diffusion Plant, Former Production Workers Screening Projects Project Name: Worker Health Protection Program Covered DOE Site: Portsmouth Worker Population Served: Production Workers Principal Investigator: Jim Frederick Co-Principal Investigator: Steven Markowitz, MD Toll-free Telephone: (888) 241-1199 Local Outreach Office: Jeanne Cisco 2288 Wakefield Mound Road Piketon, OH 45661 Website: http://www.worker-health.org/ This project is conducted by the Unitedsteel Workers in conjunction with Queens College of the City University of New York. The program is being offered as a service to both former and current workers. Free of charge, eligible workers can receive a medical exam, including chest X-ray and

114

A role of hydrocarbon reaction for NO{sub x} formation and reduction in fuel-rich pulverized coal combustion  

Science Conference Proceedings (OSTI)

We have investigated an index for modeling a NO{sub x} reaction mechanism of pulverized coal combustion. The reaction mechanism of coal nitrogen was examined by drop-tube furnace experiments under various burning conditions. We proposed the gas phase stoichiometric ratio (SRgas) as a key index to evaluate NO{sub x} concentration in fuel-rich flames. The SRgas was defined as: SRgas {identical_to} amount of fuel required for stoichiometry combustion/amount of gasified fuel where, the amount of gasified fuel was defined as the amount of fuel which had been released to the gas phase by pyrolysis, oxidation and gasification reactions. When SRgas estimate the total concentration of hydrocarbons in coal flame. The reaction of heavy hydrocarbons which had plural aromatic rings was very important to analyze the reaction mechanism of hydrocarbons for coal combustion in detail. When burning temperature and SRgas were the same, total hydrocarbon concentration in a coal flame was larger than that of a light gaseous hydrocarbon flame. Total hydrocarbon concentration in oxy-fuel combustion was lower than that in air combustion. We verified the proposed model by experimental results obtained for a drop-tube furnace and a laboratory-scale furnace that had an installed low-NO{sub x} burner. (author)

Taniguchi, Masayuki; Kamikawa, Yuki; Okazaki, Teruyuki; Yamamoto, Kenji; Orita, Hisayuki [Energy and Environmental Systems Laboratory, Hitachi, Ltd. Power Systems Company, 7-2-1 Omika-cho, Hitachi-shi, Ibaraki-ken 319-1292 (Japan)

2010-08-15T23:59:59.000Z

115

Artificial neural network in gaseous emissions prediction with bioreactor usage  

Science Conference Proceedings (OSTI)

The artificial neural network is used more and more often for prediction of processes related with the biowaste management. In this area, composting is one of the most important process of biowaste recycling. However, the gaseous emissions from the composted ... Keywords: composting, data acquisition, emissions, multilayer perceptron, neural modeling, prediction

Piotr Boniecki; Jacek Dach; Krzysztof Pilarski; Aleksander J?dru?; Krzysztof Nowakowski; Hanna Piekarska-Boniecka; Jacek Przyby?

2012-05-01T23:59:59.000Z

116

Mississippi Natural Gas Plant Liquids Production, Gaseous Equivalent  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Mississippi Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 1,127 971 1,334 1970's 1,270 1,217 1,058 878 679 567 520 367 485 1,146 1980's 553 830 831 633 618 458 463 437 811 380 1990's 445 511 416 395 425 377 340 300 495 5,462 2000's 11,377 15,454 16,477 11,430 13,697 14,308 14,662 13,097 10,846 18,354 2010's 18,405 11,221 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 12/12/2013 Next Release Date: 1/7/2014 Referring Pages: NGPL Production, Gaseous Equivalent

117

Arkansas Natural Gas Plant Liquids Production, Gaseous Equivalent (Million  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Arkansas Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 3,499 3,667 3,475 1970's 3,235 2,563 1,197 1,118 952 899 823 674 883 1,308 1980's 1,351 1,327 1,287 1,258 1,200 1,141 1,318 1,275 1,061 849 1990's 800 290 413 507 553 488 479 554 451 431 2000's 377 408 395 320 254 231 212 162 139 168 2010's 213 268 424 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 12/12/2013 Next Release Date: 1/7/2014 Referring Pages: NGPL Production, Gaseous Equivalent

118

Methods for deacidizing gaseous mixtures by phase enhanced absorption  

SciTech Connect

An improved process for deacidizing a gaseous mixture using phase enhanced gas-liquid absorption is described. The process utilizes a multiphasic absorbent that absorbs an acid gas at increased rate and leads to reduced overall energy costs for the deacidizing operation.

Hu, Liang

2012-11-27T23:59:59.000Z

119

The real air quality benefits of gaseous-fueled vehicles.  

SciTech Connect

This paper provides a justification for prominent inclusion of currently available gaseous-fueled vehicles (i.e., vehicles powered by propane, sometimes called liquefied petroleum gas [LPG], or natural gas--chiefly, methane--stored onboard the vehicle in gaseous or liquid state but combusted as a gas) in the mix of strategies to (a) reduce public exposure to toxic and fine particulate emissions in the urbanized areas of the developing world and (b) achieve local and regional improvements in ozone air quality. It also presents estimates of associated emission reduction credits into the future. Important considerations discussed are the location of fine particle and toxic emissions in congested urban areas, and the location and timing of ozone precursor emissions, with emphasis on how gaseous-fueled vehicles' role in the relationship among and magnitude of these variables differs from that of their conventionally-fueled counterparts. Efforts to enhance the measurement and quantification of gaseous-fuel benefits are also described.

Saricks, C. L.

2002-03-28T23:59:59.000Z

120

Adaptive high-resolution simulation of realistic gaseous detonation waves  

DOE Green Energy (OSTI)

The numerical approximation of detonation waves in gaseous combustible mixtures is extremely demanding since a wide range of scales needs to be resolved. A dynamically adaptive high-resolution finite volume method is described that has enabled accurately resolved computational investigations of the transient behavior of regularly oscillating detonations in low-pressure hydrogen-oxygen mixtures in realistic two-dimensional geometry.

Deiterding, Ralf [ORNL

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Recent Advances in Laser-based Diagnostics for Gaseous Flows  

Science Conference Proceedings (OSTI)

Laser-based diagnostic techniques offer unique capabilities for experimentation on gaseous flows. In this paper, we overview recent progress of two concepts: spectrally resolved absorption and planar laser-induced fluorescence (PLIF) imaging. The absorption ... Keywords: PLIF, absorption spectroscopy, acetone, combustion control, diode laser, hypersonic, supersonic

R. Hanson; D. Baer; C. Morris; M. Thurber; E. Furlong; S. Wehe

1999-12-01T23:59:59.000Z

122

Estimation of Carbon-14 in Nuclear Power Plant Gaseous Effluents  

Science Conference Proceedings (OSTI)

Nuclear power plants report the amount of radioactivity released through permitted effluent pathways in their plant annual reports. This report provides users with a method for calculating the amount of carbon-14 (14C) generated in a light water reactor (LWR) core and released through plant gaseous effluent pathways.

2010-12-21T23:59:59.000Z

123

Cleanup of hydrocarbon conversion system  

Science Conference Proceedings (OSTI)

This patent describes a process for the catalytic reforming of a substantially contaminant-free second hydrocarbon feed using a second reforming catalyst, in a catalytic-reforming system having equipment contaminated through contact with a contaminant-containing prior feed. It comprises: contacting the first hydrocarbon feed in the catalytic-reforming system at first reforming conditions with a first reforming catalyst until contaminant removal from the conversion system is substantially completed and the system is contaminant-free; thereafter replacing the first reforming catalyst in the contaminant-free catalytic-reforming system with a second reforming catalyst; and thereafter contacting the second hydrocarbon feed in the contaminant-free catalytic-reforming system with the second reforming catalyst at second reforming conditions.

Peer, R.L.; Russ, M.B.

1990-07-10T23:59:59.000Z

124

Enrichment of light hydrocarbon mixture  

Science Conference Proceedings (OSTI)

Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

Yang, Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

2011-11-29T23:59:59.000Z

125

Enrichment of light hydrocarbon mixture  

DOE Patents (OSTI)

Light hydrocarbon enrichment is accomplished using a vertically oriented distillation column having a plurality of vertically oriented, nonselective micro/mesoporous hollow fibers. Vapor having, for example, both propylene and propane is sent upward through the distillation column in between the hollow fibers. Vapor exits neat the top of the column and is condensed to form a liquid phase that is directed back downward through the lumen of the hollow fibers. As vapor continues to ascend and liquid continues to countercurrently descend, the liquid at the bottom of the column becomes enriched in a higher boiling point, light hydrocarbon (propane, for example) and the vapor at the top becomes enriched in a lower boiling point light hydrocarbon (propylene, for example). The hollow fiber becomes wetted with liquid during the process.

Yang; Dali (Los Alamos, NM); Devlin, David (Santa Fe, NM); Barbero, Robert S. (Santa Cruz, NM); Carrera, Martin E. (Naperville, IL); Colling, Craig W. (Warrenville, IL)

2010-08-10T23:59:59.000Z

126

Biological enhancement of hydrocarbon extraction  

SciTech Connect

A method of microbial enhanced oil recovery for recovering oil from an oil-bearing rock formation is provided. The methodology uses a consortium of bacteria including a mixture of surfactant producing bacteria and non-surfactant enzyme producing bacteria which may release hydrocarbons from bitumen containing sands. The described bioprocess can work with existing petroleum recovery protocols. The consortium microorganisms are also useful for treatment of above oil sands, ground waste tailings, subsurface oil recovery, and similar materials to enhance remediation and/or recovery of additional hydrocarbons from the materials.

Brigmon, Robin L. (North Augusta, SC); Berry, Christopher J. (Aiken, SC)

2009-01-06T23:59:59.000Z

127

Catalytic Conversion of Bioethanol to Hydrocarbons ...  

Conventional biomass to hydrocarbon conversion is generally not commercially feasible, due to costs of the conversion process.

128

Hydrocarbons from plants and trees  

DOE Green Energy (OSTI)

The way energy was used in the US in 1980 was examined. A diagram shows the development of energy from its source to its end use. The following are described: the carbon dioxide problem - the greenhouse effect, sugar cane as an energy source, hydrocarbon-producing plants and trees, and isoprenoids from plants and trees. (MHR)

Calvin, M.

1982-07-01T23:59:59.000Z

129

Gaseous Hydrogen Delivery Breakout - Strategic Directions for Hydrogen Delivery Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Gaseous Hydrogen Gaseous Hydrogen Delivery Breakout Strategic Directions for Hydrogen Delivery Workshop May 7-8, 2003 Crystal City, Virginia Breakout Session Name Targets/Objectives More work is needed to better define delivery target metrics Assumptions about targets for costs and energy efficiency need to be qualified Technology improvements likely to lower costs, but may not have major impact on total cost A significant impact on cost would come through permitting policy changes, e.g., use of public land Breakout Session Name Priority Barriers System Issues: need to assess delivery options in context of total system Materials: corrosion, H2 permeability Construction: welding, joining Maintenance and Operation: leak detection Pipeline Safety: odorants, flame visibility

130

Orientation Visit to the Portsmouth Gaseous Diffusion Plant  

NLE Websites -- All DOE Office Websites (Extended Search)

PORTS-2011-08-03 PORTS-2011-08-03 Site: Portsmouth Gaseous Diffusion Plant Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for the Orientation Visit to the Portsmouth Gaseous Diffusion Plant Dates of Activity : 08/01/2011 - 08/03/2011 Report Preparer: Joseph P. Drago Activity Description/Purpose: The U.S. Department of Energy (DOE) Office of Enforcement and Oversight, within the Office of Health, Safety and Security (HSS), conducted an orientation visit to the DOE Portsmouth Site Office (PORTS) and the Portsmouth/Paducah Project Office (PPPO) in Lexington, Kentucky, from August 1-3, 2011. The purpose of the visit was to discuss the nuclear safety oversight strategy, describe the site lead program, increase HSS personnel's operational awareness of the site's

131

Orientation Visit to the Paducah Gaseous Diffusion Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

PAD-2011-07-27 PAD-2011-07-27 Site: Paducah Gaseous Diffusion Plant Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for the Orientation Visit to the Paducah Gaseous Diffusion Plant Dates of Activity : 07/25/2011 - 07/27/2011 Report Preparer: Joseph P. Drago Activity Description/Purpose: The U.S. Department of Energy (DOE) Office of Enforcement and Oversight, within the Office of Health, Safety and Security (HSS), conducted an orientation visit to the DOE Paducah Site Office (PAD) from July 25-27, 2011. The purpose of the visit was to discuss the nuclear safety oversight strategy, describe the site lead program, increase HSS personnel's operational awareness of the site's activities, and to determine how HSS can carry out its independent oversight and mission

132

Orientation Visit to the Paducah Gaseous Diffusion Plant  

NLE Websites -- All DOE Office Websites (Extended Search)

PAD-2011-07-27 PAD-2011-07-27 Site: Paducah Gaseous Diffusion Plant Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for the Orientation Visit to the Paducah Gaseous Diffusion Plant Dates of Activity : 07/25/2011 - 07/27/2011 Report Preparer: Joseph P. Drago Activity Description/Purpose: The U.S. Department of Energy (DOE) Office of Enforcement and Oversight, within the Office of Health, Safety and Security (HSS), conducted an orientation visit to the DOE Paducah Site Office (PAD) from July 25-27, 2011. The purpose of the visit was to discuss the nuclear safety oversight strategy, describe the site lead program, increase HSS personnel's operational awareness of the site's activities, and to determine how HSS can carry out its independent oversight and mission

133

Federal Facility Agreement for the Paducah Gaseous Diffusion Plant Summary  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Federal Facility Agreement for the Paducah Gaseous Federal Facility Agreement for the Paducah Gaseous Diffusion Plant State Kentucky Agreement Type Federal Facility Agreement Legal Driver(s) CERCLA/RCRA Scope Summary Ensure that the environmental impacts of activities at the Site are investigated and appropriate response actions are taken. Parties U.S. DOE; Kentucky Natural Resources and Environmental Protection Cabinet; U.S. EPA Date 2/01/1998 SCOPE * Ensure all releases of hazardous substances, pollutants, or contaminants are addressed to achieve comprehensive remediation of the site. * Establish a procedural framework and schedule for developing, implementing, and monitoring response actions in accordance with CERCLA, RCRA, and Kentucky Law. * Facilitate cooperation, exchange of information, and participation of the Parties and

134

Orientation Visit to the Portsmouth Gaseous Diffusion Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

PORTS-2011-08-03 PORTS-2011-08-03 Site: Portsmouth Gaseous Diffusion Plant Subject: Office of Enforcement and Oversight's Office of Safety and Emergency Management Evaluations Activity Report for the Orientation Visit to the Portsmouth Gaseous Diffusion Plant Dates of Activity : 08/01/2011 - 08/03/2011 Report Preparer: Joseph P. Drago Activity Description/Purpose: The U.S. Department of Energy (DOE) Office of Enforcement and Oversight, within the Office of Health, Safety and Security (HSS), conducted an orientation visit to the DOE Portsmouth Site Office (PORTS) and the Portsmouth/Paducah Project Office (PPPO) in Lexington, Kentucky, from August 1-3, 2011. The purpose of the visit was to discuss the nuclear safety oversight strategy, describe the site lead program, increase HSS personnel's operational awareness of the site's

135

Paducah Gaseous Diffusion Plant Annual Site Environmental Report for 1993  

SciTech Connect

The purpose of this document is to summarize effluent monitoring and environmental surveillance results and compliance with environmental laws, regulations, and orders at the Paducah Gaseous Diffusion Plant (PGDP). Environmental monitoring at PGDP consists of two major activities: effluent monitoring and environmental surveillance. Effluent monitoring is direct measurement or the collection and analysis of samples of liquid and gaseous discharges to the environment. Environmental surveillance is direct measurement or the collection and analysis of samples of air, water, soil, foodstuff, biota, and other media. Environmental monitoring is performed to characterize and quantify contaminants, assess radiation exposures of members of the public, demonstrate compliance with applicable standards and permit requirements, and detect and assess the effects (if any) on the local environment. Multiple samples are collected throughout the year and are analyzed for radioactivity, chemical content, and various physical attributes.

Not Available

1994-10-01T23:59:59.000Z

136

Method for diverting a gaseous sand-consolidating fluid  

SciTech Connect

An unconsolidated gas-producing sand in which the permeability is layered and the productivity can be impaired by liquid blocking can be consolidated by wetting the rock surfaces with a limited amount of water, injecting a smoke which selectively reduces the permeability of the most permeable layers by depositing on their faces unconsolidated masses of substantially inert solid particles and injecting a gaseous silicon polyhalide to convert a significant proportion of the rock surface-wettingwater to a grain bonding silica gel.

Davies, D. R.; Richardson, E. A.

1980-12-30T23:59:59.000Z

137

Method and apparatus for analyzing particle-containing gaseous suspensions  

DOE Patents (OSTI)

The method and apparatus permit analyses, by optical means, of properties of gaseous suspensions of particles, by measuring radiation that is emitted, transmitted or scattered by the particles. Determinations of composition, size, temperature and spectral emittance can be performed either in-situ or by sampling, and Fourier-transform infrared spectrometric techniques are most effectively used. Apparatus specifically adapted for performing radiation scattering analyses, and for collecting radiation from different sources, are provided. 51 figs.

Solomon, P.R.; Carangelo, R.M.; Best, P.E.

1987-03-24T23:59:59.000Z

138

Syngas Upgrading to Hydrocarbon Fuels Technology Pathway  

DOE Green Energy (OSTI)

This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and lowest risk conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas-to-hydrocarbon pathway to be competitive with petroleum-derived gasoline-, diesel- and jet-range hydrocarbon blendstocks.

Talmadge, M.; Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

2013-03-01T23:59:59.000Z

139

North Dakota Natural Gas Plant Liquids Production, Gaseous Equivalent  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) North Dakota Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 5,150 5,428 4,707 1970's 4,490 3,592 3,199 2,969 2,571 2,404 2,421 2,257 2,394 2,986 1980's 3,677 5,008 5,602 7,171 7,860 8,420 6,956 7,859 6,945 6,133 1990's 6,444 6,342 6,055 5,924 5,671 5,327 4,937 5,076 5,481 5,804 2000's 6,021 6,168 5,996 5,818 6,233 6,858 7,254 7,438 7,878 10,140 2010's 11,381 14,182 26,156 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 1/7/2014

140

Texas Natural Gas Plant Liquids Production, Gaseous Equivalent (Million  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Texas Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 433,684 457,117 447,325 1970's 466,016 448,288 470,105 466,143 448,993 435,571 428,635 421,110 393,819 352,650 1980's 350,312 345,262 356,406 375,849 393,873 383,719 384,693 364,477 357,756 343,233 1990's 342,186 353,737 374,126 385,063 381,020 381,712 398,442 391,174 388,011 372,566 2000's 380,535 355,860 360,535 332,405 360,110 355,589 373,350 387,349 401,503 424,042 2010's 433,622 481,308 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data.

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Louisiana Natural Gas Plant Liquids Production, Gaseous Equivalent (Million  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Louisiana Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 115,177 140,290 179,117 1970's 193,209 195,072 197,967 206,833 194,329 189,541 172,584 166,392 161,511 165,515 1980's 142,171 142,423 128,858 124,193 132,501 117,736 115,604 124,890 120,092 121,425 1990's 119,405 129,154 132,656 130,336 128,583 146,048 139,841 150,008 144,609 164,794 2000's 164,908 152,862 152,724 124,955 133,434 103,381 105,236 110,745 94,785 95,359 2010's 102,448 95,630 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data.

142

Michigan Natural Gas Plant Liquids Production, Gaseous Equivalent (Million  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Michigan Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 3,351 3,244 2,705 1970's 2,330 2,013 1,912 1,581 1,921 2,879 6,665 11,494 14,641 15,686 1980's 15,933 14,540 14,182 13,537 12,829 11,129 11,644 10,876 10,483 9,886 1990's 8,317 8,103 8,093 7,012 6,371 6,328 6,399 6,147 5,938 5,945 2000's 5,322 4,502 4,230 3,838 4,199 3,708 3,277 3,094 3,921 2,334 2010's 2,943 2,465 2,480 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 12/12/2013

143

California Natural Gas Plant Liquids Production, Gaseous Equivalent  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) California Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 34,803 32,639 30,334 1970's 29,901 27,585 24,156 17,498 17,201 15,221 14,125 13,567 13,288 10,720 1980's 8,583 7,278 14,113 14,943 15,442 16,973 16,203 15,002 14,892 13,376 1990's 12,424 11,786 12,385 12,053 11,250 11,509 12,169 11,600 10,242 10,762 2000's 11,063 11,060 12,982 13,971 14,061 13,748 14,056 13,521 13,972 13,722 2010's 13,244 12,095 12,755 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data.

144

Kentucky Natural Gas Plant Liquids Production, Gaseous Equivalent (Million  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Kentucky Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 11,500 8,573 8,579 1970's 6,574 6,133 6,063 5,441 5,557 5,454 5,231 4,764 6,192 3,923 1980's 6,845 5,638 6,854 6,213 6,516 6,334 4,466 2,003 2,142 1,444 1990's 1,899 2,181 2,342 2,252 2,024 2,303 2,385 2,404 2,263 2,287 2000's 1,416 1,558 1,836 1,463 2,413 1,716 2,252 1,957 2,401 3,270 2010's 4,576 4,684 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 12/12/2013 Next Release Date: 1/7/2014

145

New Mexico Natural Gas Plant Liquids Production, Gaseous Equivalent  

Gasoline and Diesel Fuel Update (EIA)

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) New Mexico Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 46,149 48,635 50,484 1970's 52,647 53,810 54,157 55,782 54,986 56,109 61,778 72,484 77,653 62,107 1980's 59,457 60,544 56,857 56,304 58,580 53,953 51,295 65,156 63,355 61,594 1990's 66,626 70,463 75,520 83,193 86,607 85,668 108,341 109,046 106,665 107,850 2000's 110,411 108,958 110,036 111,292 105,412 101,064 99,971 96,250 92,579 94,840 2010's 91,963 90,291 84,562 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data.

146

Colorado Natural Gas Plant Liquids Production, Gaseous Equivalent (Million  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Colorado Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 4,126 4,546 4,058 1970's 3,405 4,152 4,114 4,674 6,210 9,620 11,944 13,507 13,094 12,606 1980's 12,651 13,427 12,962 11,314 10,771 11,913 10,441 10,195 11,589 13,340 1990's 13,178 15,822 18,149 18,658 19,612 25,225 23,362 28,851 24,365 26,423 2000's 29,105 29,195 31,952 33,650 35,821 34,782 36,317 38,180 53,590 67,607 2010's 82,637 90,801 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data.

147

Alabama Natural Gas Plant Liquids Production, Gaseous Equivalent (Million  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (Million Cubic Feet) Liquids Production, Gaseous Equivalent (Million Cubic Feet) Alabama Natural Gas Plant Liquids Production, Gaseous Equivalent (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1960's 236 1970's 225 281 243 199 501 694 661 933 1,967 4,845 1980's 4,371 4,484 4,727 4,709 5,123 5,236 4,836 4,887 4,774 5,022 1990's 4,939 4,997 5,490 5,589 5,647 5,273 5,361 4,637 4,263 18,079 2000's 24,086 13,754 14,826 11,293 15,133 13,759 21,065 19,831 17,222 17,232 2010's 19,059 17,271 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 12/12/2013 Next Release Date: 1/7/2014 Referring Pages:

148

Hydrocarbon Technologies | Open Energy Information  

Open Energy Info (EERE)

Hydrocarbon Technologies Hydrocarbon Technologies Place Lawrenceville, New Jersey Zip 8648 Sector Efficiency Product String representation "Technology-base ... onmental risks." is too long. Coordinates 36.761678°, -77.845048° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":36.761678,"lon":-77.845048,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

149

Deep desulfurization of hydrocarbon fuels  

SciTech Connect

The invention relates to processes for reducing the sulfur content in hydrocarbon fuels such as gasoline, diesel fuel and jet fuel. The invention provides a method and materials for producing ultra low sulfur content transportation fuels for motor vehicles as well as for applications such as fuel cells. The materials and method of the invention may be used at ambient or elevated temperatures and at ambient or elevated pressures without the need for hydrogen.

Song, Chunshan (State College, PA); Ma, Xiaoliang (State College, PA); Sprague, Michael J. (Calgary, CA); Subramani, Velu (State College, PA)

2012-04-17T23:59:59.000Z

150

Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 11 for thrid quarter FY 1990  

DOE Green Energy (OSTI)

The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of the various options will be performed as experimental data become available.

Foral, M.J.

1990-12-31T23:59:59.000Z

151

Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 15 fourth quarter FY 1990  

DOE Green Energy (OSTI)

The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

Foral, M.J.

1990-12-31T23:59:59.000Z

152

Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 23 for second quarter FY 1991  

DOE Green Energy (OSTI)

The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

Foral, M.J.

1991-12-31T23:59:59.000Z

153

Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 19 for first quarter FY 1991  

DOE Green Energy (OSTI)

The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

Foral, M.J.

1991-12-31T23:59:59.000Z

154

Direct conversion of light hydrocarbon gases to liquid fuel  

DOE Green Energy (OSTI)

The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons to liquid transportation fuels via a partial oxidation process. The process will be tested in existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various option will be performed as experimental data become available. The project is of two year's duration and contains three major tasks: Project Management Plan, Pilot Plant Modification, and Comparison of Preliminary Data With Los Alamos Model: We will determine if the kinetic model developed by Los Alamos National Laboratory can be used to guide our experimental effort. Other subtasks under Task 3 include: Pressure/Temperature/Reaction Time Effects; Study of Different Injection Systems: Different schemes for introducing and mixing reactants before or within the reactor will be evaluated theoretically and/or experimentally; Study of Different Quench Systems; Effect of Reactor Geometry; Effect of Reactor Recycle; and Enhanced-Yield Catalyst Study. 5 refs., 12 figs., 4 tabs.

Foral, M.J.

1990-01-01T23:59:59.000Z

155

Gaseous divertor simulation in an arc-jet device  

SciTech Connect

The first experimental simulation of the gaseous tokamak divertor is presented. Significant results are: (1) neutral gas at a pressure of a few mTorr is sufficient to absorb the entire localized flux of plasma thermal energy and reidstribute it over a wide area; (2) elastic ion-neutral collisions constitute the main energy absorbing process (at T/sub e,i/ less than or equal to 5 eV), and (3) a large pressure difference between divertor and main plasma chamber is maintained by plasma pumping in the connecting channel.

Hsu, W.L.; Yamada, M.; Barrett, P.J.

1982-12-01T23:59:59.000Z

156

Removing gaseous contaminants in {sup 3}He by cryogenic stripping  

SciTech Connect

The Tritium Operations Group at LLNL, Tritium Facility has recently developed a {sup 3}He recovery system to remove argon, xenon, neon, hydrogen, and all other contaminants from the {sup 3}He stream in an Accelerator Production of Tritium (APT) experimental apparatus. In this paper the authors will describe in detail the background information, technical requirements, the design approach, and the results of their experimental tests. The authors believe this gas purification system may have other applications as it provides at a reasonable cost an efficient method for purification of gaseous helium.

Benapfl, M.; Biltoft, P.; Coombs, A. [Lawrence Livermore National Lab., CA (United States). Tritium Operations Group

1995-08-17T23:59:59.000Z

157

Portsmouth Gaseous Diffusion Plant Environmental report for 1990  

Science Conference Proceedings (OSTI)

This calendar year 1990 annual report on environmental surveillance of the US Department of Energy's (DOE's) Portsmouth Gaseous Diffusion Plant (PORTS) and its environs consists of two parts: the summary, discussion, and conclusions (Part 1) and the data presentation (Part 2). The objectives of this report are as follows: report 1990 monitoring data for the installation and its environs that may have been affected by operations on the plant site, provide reasonably detailed information about the plant site and plant operations, provide detailed information on input and assumptions used in all calculations, provide trend analyses (when appropriate) to indicate increases and decreases in environmental impact, and provide general information on plant quality assurance.

Counce-Brown, D. (ed.)

1991-09-01T23:59:59.000Z

158

HYDROCARBON AND SULFUR SENSORS FOR SOFC SYSTEMS  

DOE Green Energy (OSTI)

The following report summarizes work conducted during the Phase I program Hydrocarbon and Sulfur Sensors for SOFC Systems under contract No. DE-FC26-02NT41576. For the SOFC application, sensors are required to monitor hydrocarbons and sulfur in order to increase the operation life of SOFC components. This report discusses the development of two such sensors, one based on thick film approach for sulfur monitoring and the second galvanic based for hydrocarbon monitoring.

A.M. Azad; Chris Holt; Todd Lesousky; Scott Swartz

2003-11-01T23:59:59.000Z

159

Catalytic Conversion of Bioethanol to Hydrocarbons  

ORNL 2011-G00219/jcn UT-B ID 201002414 08.2011 Catalytic Conversion of Bioethanol to Hydrocarbons Technology Summary A method for catalytically converting an alcohol ...

160

Membrane separation of hydrocarbons using cycloparaffinic solvents  

DOE Patents (OSTI)

Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

Kulkarni, Sudhir S. (Hoffman Estates, IL); Chang, Y. Alice (Westmont, IL); Gatsis, John G. (Des Plaines, IL); Funk, Edward W. (Highland Park, IL)

1988-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Catalytic Conversion of Bioethanol to Hydrocarbons  

ORNL 2011-G00219/jcn UT-B ID 201002414 08.2011 Catalytic Conversion of Bioethanol to Hydrocarbons Technology Summary A method for catalytically ...

162

Nox reduction system utilizing pulsed hydrocarbon injection  

DOE Patents (OSTI)

Hydrocarbon co-reductants, such as diesel fuel, are added by pulsed injection to internal combustion engine exhaust to reduce exhaust NO.sub.x to N.sub.2 in the presence of a catalyst. Exhaust NO.sub.x reduction of at least 50% in the emissions is achieved with the addition of less than 5% fuel as a source of the hydrocarbon co-reductants. By means of pulsing the hydrocarbon flow, the amount of pulsed hydrocarbon vapor (itself a pollutant) can be minimized relative to the amount of NO.sub.x species removed.

Brusasco, Raymond M. (Livermore, CA); Penetrante, Bernardino M. (San Ramon, CA); Vogtlin, George E. (Fremont, CA); Merritt, Bernard T. (Livermore, CA)

2001-01-01T23:59:59.000Z

163

Membrane separation of hydrocarbons using cycloparaffinic solvents  

DOE Patents (OSTI)

Heavy crude oils which contain metal contaminants such as nickel, vanadium and iron may be separated from light hydrocarbon oils by passing a solution of the crude oil dissolved in a cycloparaffinic hydrocarbon solvent containing from about 5 to about 8 carbon atoms by passing through a polymeric membrane which is capable of maintaining its integrity in the presence of hydrocarbon compounds. The light hydrocarbon oils which possess relatively low molecular weights will be recovered as the permeate while the heavy oils which possess relatively high molecular weights as well as the metal contaminants will be recovered as the retentate.

Kulkarni, S.S.; Chang, Y.A.; Gatsis, J.G.; Funk, E.W.

1988-06-14T23:59:59.000Z

164

DOE Seeks Proposals for Portsmouth Gaseous Diffusion Plant Technical Services Contract  

Energy.gov (U.S. Department of Energy (DOE))

Cincinnati - The Department of Energy today issued a Draft Request for Proposals (RFP) for an Environmental Technical Services acquisition at the Portsmouth Gaseous Diffusion Plant near Piketon, Ohio.

165

Low energy consumption method for separating gaseous mixtures and in particular for medium purity oxygen production  

DOE Patents (OSTI)

A method for the separation of gaseous mixtures such as air and for producing medium purity oxygen, comprising compressing the gaseous mixture in a first compressor to about 3.9-4.1 atmospheres pressure, passing said compressed gaseous mixture in heat exchange relationship with sub-ambient temperature gaseous nitrogen, dividing the cooled, pressurized gaseous mixture into first and second streams, introducing the first stream into the high pressure chamber of a double rectification column, separating the gaseous mixture in the rectification column into a liquid oxygen-enriched stream and a gaseous nitrogen stream and supplying the gaseous nitrogen stream for cooling the compressed gaseous mixture, removing the liquid oxygen-enriched stream from the low pressure chamber of the rectification column and pumping the liquid, oxygen-enriched steam to a predetermined pressure, cooling the second stream, condensing the cooled second stream and evaporating the oxygen-enriched stream in an evaporator-condenser, delivering the condensed second stream to the high pressure chamber of the rectification column, and heating the oxygen-enriched stream and blending the oxygen-enriched stream with a compressed blend-air stream to the desired oxygen concentration.

Jujasz, Albert J. (North Olmsted, OH); Burkhart, James A. (Olmsted Falls, OH); Greenberg, Ralph (New York, NY)

1988-01-01T23:59:59.000Z

166

Liquefied Gaseous Fuels Spill Test Facility: Overview of STF capabilities  

SciTech Connect

The Liquefied Gaseous Fuels Spill Test Facility (STF) constructed at the Department of Energy`s Nevada Test Site is a basic research tool for studying the dynamics of accidental releases of various hazardous liquids. This Facility is designed to (1) discharge, at a controlled rate, a measured volume of hazardous test liquid on a prepared surface of a dry lake bed (Frenchman Lake); (2) monitor and record process operating data, close-in and downwind meteorological data, and downwind gaseous concentration levels; and (3) provide a means to control and monitor these functions from a remote location. The STF will accommodate large and small-scale testing of hazardous test fluid release rates up to 28,000 gallons per minute. Spill volumes up to 52,800 gallons are achievable. Generic categories of fluids that can be tested are cryogenics, isothermals, aerosol-forming materials, and chemically reactive. The phenomena that can be studied include source definition, dispersion, and pool fire/vapor burning. Other capabilities available at the STF include large-scale wind tunnel testing, a small test cell for exposing personnel protective clothing, and an area for developing mitigation techniques.

Gray, H.E.

1993-09-01T23:59:59.000Z

167

Greenhouse warming potential of candidate gaseous diffusion plant coolants  

SciTech Connect

A preliminary estimate has been made of the greenhouse warming potential (GWP) of coolants under consideration as substitutes for CFC-114 in the gaseous diffusion plants. Coolants are not at present regulated on the basis of GWP, but may well be in the future. Use of c-C{sub 4}F{sub 8} or n-C{sub 4}F{sub 10} is estimated to have three to four times the greenhouse impact of an equivalent use of CFC-114. Neither of the substitutes, of course, would cause any ozone depletion. HCFC-124 (a probable commercial substitute for CFC-114, but not presently under serious consideration due to its relatively high UF{sub 6} reactivity) would have much less greenhouse and ozone depletion impact than CFC-114. The GWP estimates derive from a simple model that approximately reproduces literature values for similar compounds. The major uncertainty in these estimates lies in the atmospheric lifetime, especially of the perfluorocarbon compounds, for which little reliable information exists. In addition to GWP estimates for coolants, the overall greenhouse impact of the gaseous diffusion plants is calculated, including indirect power-related CO{sub 2} emissions. This result is used to compare greenhouse impacts of nuclear- and coal-produced electricity. 11 refs., 2 figs., 5 tabs.

Trowbridge, L.D.

1991-03-01T23:59:59.000Z

168

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission...

169

Underground storage of natural gas, liquid hydrocarbons, and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana)...

170

Biogeochemistry of Isoprenoid Production and Anaerobic Hydrocarbon Biodgeradation.  

E-Print Network (OSTI)

??This dissertation is an exploration of microbial isoprenoid production and destruction by anaerobic hydrocarbon biodegradation. Isoprenoids are methyl-branched hydrocarbons, and include biomarkers from all three (more)

Dawson, Katherine

2011-01-01T23:59:59.000Z

171

Air pollution from a large steel factory: polycyclic aromatic hydrocarbon emissions from coke-oven batteries  

SciTech Connect

A systematic investigation of solid and gaseous atmospheric emissions from some coke-oven batteries of one of Europe's largest integrated steel factory (Taranto, Italy) has been carried out. These emissions, predominantly diffuse, originate from oven leakages, as well as from cyclic operations of coal loading and coke unloading. In air monitoring samples, polycyclic aromatic hydrocarbons (PAHs) were consistently detected at concentrations largely exceeding threshold limit values. By means of PAHs speciation profile and benzo-(a)pyrene (BaP) equivalent dispersion modeling from diffuse sources, the study indicated that serious health risks exist not only in working areas, but also in a densely populated residential district near the factory. 30 refs., 5 figs., 3 tabs.

Lorenzo Liberti; Michele Notarnicola; Roberto Primerano; Paolo Zannetti [Technical University of Bari, Bari (Italy). Department of Environmental Engineering and Sustainable Development

2006-03-15T23:59:59.000Z

172

Online learning of a neural fuel control system for gaseous fueled si engines  

Science Conference Proceedings (OSTI)

This dissertation presents a new type of fuel control algorithm for gaseous fuelled vehicles. Gaseous fuels such as hydrogen and natural gas have been shown to be less polluting than liquid fuels such as gasoline, both at the tailpipe and on a total ...

Travis Kent Wiens

2008-01-01T23:59:59.000Z

173

Extending the Photon Mapping Method for Realistic Rendering of Hot Gaseous Fluids  

E-Print Network (OSTI)

fluid dynamics have proved very successful. As a result, diverse physically based fluid animation fluids. In addition to the generation of ap- pealing motions of gaseous fluids, several inter- esting, they are gen- erated within the gaseous fluid, but an energy value is assigned to each one according to the to

Texas at Austin, University of

174

Paducah Gaseous Diffusion Plant, Production Workers Screening Projects |  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Production Workers Screening Production Workers Screening Projects Paducah Gaseous Diffusion Plant, Production Workers Screening Projects Project Name: Worker Health Protection Program Covered DOE Site: Paducah Worker Population Served: Production Workers Principal Investigator: Jim Frederick Co-Principal Investigator: Steven Markowitz, MD Toll-free Telephone: (888) 241-1199 Local Outreach Office: James Harbison 2525 Cairo Road Paducah, KY 42001 Website: http://www.worker-health.org/ This project is conducted by the United Steelworkers in conjunction with Queens College of the City University of New York. The program is being offered as a service to both former and current workers. Free of charge, eligible workers can receive a medical exam, including chest X-ray and breathing test, and an educational workshop. This program also offers CT

175

Portsmouth Gaseous Diffusion Plant Former Workers, Construction Worker  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Plant Former Workers, Construction Plant Former Workers, Construction Worker Screening Projects Portsmouth Gaseous Diffusion Plant Former Workers, Construction Worker Screening Projects Project Name: Building Trades National Medical Screening Program Covered DOE Site: Portsmouth Worker Population Served: Construction Workers Principal Investigator: Knut Ringen, DrPh, MHA, MPH Toll-free Telephone: (888) 464-0009 Local Outreach Office: Ron Bush 1236 Gallia Street Portsmouth, OH 45662 Website: http://www.btmed.org This project is intended to provide free medical screening to former workers in the building trades (construction workers). The screening targets health problems resulting from exposures, including asbestos, beryllium, cadmium, chromium, lead, mercury, noise, radiation, silica and/or solvents. The project is being carried out by a large group led by

176

Portsmouth Gaseous Diffusion Plant annual site environmental report for 1993  

Science Conference Proceedings (OSTI)

This calendar year (CY) 1993 annual report on environmental monitoring of the US Department of Energy`s (DOE`s) Portsmouth Gaseous Diffusion Plant (Portsmouth) and its environs consists of three separate documents: a summary pamphlet for the general public; a more detail discussion and of compliance status, data, and environmental impacts (this document); and a volume of detailed data that is available on request. The objectives of this report are to report compliance status during 1993; provide information about the plant site and plant operations; report 1993 monitoring data for the installation and its environs that may have been affected by operations on the plant site; document information on input and assumptions used in calculations; provide trend analyses (where appropriate) to indicate increases and decreases in environmental impact, and provide general information on quality assurance for the environmental monitoring program.

Horak, C.M. [ed.

1994-11-01T23:59:59.000Z

177

Gaseous diffusion plant transition from DOE to external regulation  

SciTech Connect

After many years of operation as government-owned/contractor-operated facilities, large portions of the gaseous diffusion plants (GDPs) at Portsmouth, Ohio, and Paducah, Kentucky, were leased to the United States Enrichment Corporation (USEC). These facilities are now certified by the U.S. Nuclear Regulatory Commission (NRC) and subject to oversight by the Occupational Safety and Health Administration (OSHA). The transition from DOE to NRC regulation was more difficult than expected. The original commitment was to achieve NRC certification in October 1995; however, considerably more time was required and transition-related costs escalated. The Oak Ridge Operations Office originally estimated the cost of transition at $60 million; $240 million has been spent to date. The DOE`s experience in transitioning the GDPs to USEC operation with NRC oversight provides valuable lessons (both positive and negative) that could be applied to future transitions.

Dann, R.K.; Crites, T.R.; Rahm-Crites, L.K. [Lawrence Livermore National Lab., CA (United States)

1997-12-01T23:59:59.000Z

178

Gaseous Arginine Conformers and Their Unique Intramolecular Interactions  

DOE Green Energy (OSTI)

Extensive ab initio calculations were employed to characterize stable conformers of gaseous arginine, both canonical and zwitterionic tautomers. Step-by-step geometry optimizations of possible single-bond rotamers at the B3LYP/6-31G(d), B3LYP/6-31++G(d,p) and MP2/6-31++G(d,p) levels yield numerous structures that are more stable than any known ones. The final electronic energies of the conformers were determined at the CCSD/6-31++G(d,p) level. The lowest energies of the canonical and zwitterionic structures are lower than the existing ones by 2.0 and 2.3 kcal/mol, respectively. The relative energies, rotational constants, dipole moments and harmonic frequencies of the stable conformers were given for future experimental verifications. The conformational distributions at various temperatures, estimated based upon the thermodynamic principles, consist almost exclusively of the newly found structures. One striking feature is the occurrence of the blue-shifting hydrogen bonds in all the six most stable conformers. A unique feature of important conformations is the coexistence of dihydrogen, blue- and red-shifting hydrogen bonds. In addition to the hydrogen bonds, the stereoelectronic effects were also found to be important stabilization factors. The calculated and measured proton affinities agree within the theoretical and experimental uncertainties, affirming high quality of our conformational search. The theoretical gas phase basicity of 245.9 kcal/mol is also in good agreement with the experimental value of 240.6 kcal/mol. The extensive searches establish firmly that gaseous arginine exists primarily in the canonical and not the zwitterionic form. Computing resources were available through a Computational Grand Challenge Application grant from the Molecular Sciences Computing Facility in the Environmental Molecular Sciences Laboratory. PNNL is operated by Battelle for the U.S. DOE under Contract DE-AC06-76RLO 1830.

Ling, Sanliang; Yu, Wenbo; Huang, Zhijian; Lin, Zijing; Haranczyk, Maciej; Gutowski, Maciej S.

2006-11-09T23:59:59.000Z

179

Gaseous Arginine Conformers and Their Unique Intramolecular Interactions.  

DOE Green Energy (OSTI)

Extensive ab initio calculations were employed to characterize stable conformers of gaseous arginine, both the canonical and zwitterionic tautomers. Step-by-step geometry optimizations of possible single-bond rotamers at the B3LYP/6-31G(d), B3LYP/6-31++G(d,p), and MP2/6-31++G(d,p) levels yield numerous structures that are more stable than any known ones. The final electronic energies of the conformers were determined at the CCSD/6-31++G(d,p) level. The lowest energies of the canonical and zwitterionic structures are lower than the existing values by 2.0 and 2.3 kcal/mol, respectively. The relative energies, rotational constants, dipole moments, and harmonic frequencies of the stable conformers remain for future experimental verification. The conformational distributions at various temperatures, estimated according to thermodynamic principles, consist almost exclusively of the newly found structures. One striking feature is the occurrence of blueshifting hydrogen bonds in all six of the most stable conformers. A unique feature of important conformations is the coexistence of dihydrogen and blue- and red-shifting hydrogen bonds. In addition to the hydrogen bonds, the stereoelectronic effects were also found to be important stabilization factors. The calculated and measured proton affinities agree within the theoretical and experimental uncertainties, affirming the high quality of our conformational search. The theoretical gas-phase basicity of 245.9 kcal/mol is also in good agreement with the experimental value of 240.6 kcal/mol. The extensive searches establish firmly that gaseous arginine exists primarily in the canonical and not the zwitterionic form.

Ling, Sanliang; Yu, Wenbo; Huang, Zhijian; Lin, Zijing; Haranczyk, Maciej; Gutowski, Maciej S.

2006-11-09T23:59:59.000Z

180

A mathematical model for the branched chain amino acid biosynthetic pathways of Escherichia coli K12  

E-Print Network (OSTI)

Biotechnol 19, 125-130 Herring, P. A. , McKnight, B. L. ,1257-1265 Jackson, J. H. , Herring, P. A. , Patterson, E.250: 4477-85, 1975 17 Herring P.A. et al. Biochem. Biophy.

Yang, C R; Shapiro, B E; Hung, S P; Mjolsness, E D; Hatfield, G W

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Molecular Plant Pages 110, 2011 RESEARCH ARTICLE Catabolism of Branched Chain Amino Acids  

E-Print Network (OSTI)

de Biologia Vegetal, Universidade Federal de Vicxosa, 36570­000 Vicxosa, Minas Gerais, Brazil c; tomato. INTRODUCTION Due to their branched carbon skeletons, the amino acids va- line, leucine

Klee, Harry J.

182

Process for recovery of liquid hydrocarbons  

SciTech Connect

Methane is recovered as a gas for discharge to a pipeline from a gas stream containing methane and heavier hydrocarbons, principally ethane and propane. Separation is accomplished by condensing the heavier hydrocarbons and distilling the methane therefrom. A liquid product (LPG) comprising the heavier hydrocarbons is subsequently recovered and transferred to storage. Prior to being discharged to a pipeline, the recovered methane gas is compressed and in undergoing compression the gas is heated. The heat content of the gas is employed to reboil the refrigerant in an absorption refrigeration unit. The refrigeration unit is used to cool the LPG prior to its storage.

Millar, J.F.; Cockshott, J.E.

1978-04-11T23:59:59.000Z

183

Elucidating the solid, liquid and gaseous products from batch pyrolysis of cotton-gin trash.  

E-Print Network (OSTI)

Cotton-gin trash (CGT) was pyrolyzed at different temperatures and reaction times using an externally-heated batch reactor. The average yields of output products (solid/char, liquid/bio-oil, and gaseous) were determined. The heating value (HV) of CGT was measured to be around 15-16 MJ kg- 1 (6500-7000 Btu lb-1). In the first set of tests, CGT was pyrolyzed at 600, 700, and 800C and at 30, 45, and 60 min reaction period. The maximum char yield of 40% by weight (wt.%) was determined at 600C and 30 min settings, however, the HV of char was low and almost similar to the HV of CGT. A maximum gas yield of 40 wt.% was measured at 800C and 60 min and the highest liquid yield of 30 wt.% was determined at 800C and 30 min. In the modified pyrolysis test, the effects of temperature (500, 600, 700, and 800C) on the product yield and other properties were investigated. The experiment was performed using the same reactor purged with nitrogen at a rate of 1000 cm3 min-1. Gas yield increased as temperature was increased while the effect was opposite on char yield. The maximum char yield of 38 wt.% was determined at 500C and 30 min. The char had the largest fraction in the energy output (70-83%) followed by gas (10-20%) and bio-oil (7- 9%). Maximum gas yield of 35 wt.% was determined at 800C. The average yield of CO, H2 and total hydrocarbons (THC) generally increased with increased temperature but CO2 production decreased. Methane, ethane, and propane dominated the THC. The bio-oil yield at 600C was the highest at about 30 wt.% among the temperature settings. The HV of bio-oil was low (2-5 MJ kg-1) due to minimal non-HC compounds and high moisture content (MC). A simple energy balance of the process was performed. The process was considered energy intensive due to the high amount of energy input (6100 kJ) while generating a maximum energy output of only 10%. After disregarding the energy used for preparation and pyrolysis, the energy losses ranged from 30-46% while the energy of the output represent between 55-70% of the input energy from CGT.

Aquino, Froilan Ludana

2007-12-01T23:59:59.000Z

184

Selective photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A selective photooxidation process for the conversion of hydrocarbon molecules to partially oxygenated derivatives, which comprises the steps of adsorbing a hydrocarbon and oxygen onto a dehydrated zeolite support matrix to form a hydrocarbon-oxygen contact pair, and subsequently exposing the hydrocarbon-oxygen contact pair to visible light, thereby forming a partially oxygenated derivative.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Berkeley, CA); Sun, Hai (Berkeley, CA)

1998-01-01T23:59:59.000Z

185

HYDROCARBONS FROM PLANTS: ANALYTICAL METHODS AND OBSERVATIONS  

E-Print Network (OSTI)

W. and Calvin, M. J. Amer. Oil Chern. Assoc. Science, 208,of the production of oil and alcohol from hydrocarbon-Figure 1 Cumulative U.S. crude oil discoveries as a function

Calvin, Melvin

2013-01-01T23:59:59.000Z

186

Thermodynamic Properties of Acetic Acid + Hydrocarbons ...  

Science Conference Proceedings (OSTI)

Thermodynamic Properties of Acetic Acid + Hydrocarbons Mixtures L. Negadi1,C,S, N. Ainous2, A. Negadi1, I. Mokbel2, A. Kaci3 and J. Jose2 ...

2006-07-20T23:59:59.000Z

187

,"Louisiana Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Louisiana Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sla_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sla_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

188

,"Nebraska Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Nebraska Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sne_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sne_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

189

,"Pennsylvania Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Pennsylvania Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_spa_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_spa_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

190

,"South Dakota Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Plant Liquids Production, Gaseous Equivalent (MMcf)" Plant Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","South Dakota Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_ssd_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_ssd_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

191

,"Wyoming Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Wyoming Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_swy_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_swy_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

192

,"Michigan Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Michigan Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_smi_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_smi_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

193

,"Florida Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Florida Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sfl_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sfl_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

194

,"Mississippi Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Mississippi Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sms_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sms_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

195

,"Texas Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Texas Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_stx_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_stx_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

196

,"Montana Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Montana Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_smt_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_smt_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

197

,"Kansas Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Kansas Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sks_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sks_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

198

,"Alabama Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Alabama Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sal_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sal_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

199

,"California Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","California Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sca_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sca_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

200

,"Oklahoma Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Oklahoma Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sok_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sok_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

,"Ohio Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Ohio Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_soh_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_soh_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

202

,"Utah Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Utah Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2011 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sut_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sut_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

203

,"Alaska Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Liquids Production, Gaseous Equivalent (MMcf)" Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Alaska Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sak_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sak_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

204

,"Indiana Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)"  

U.S. Energy Information Administration (EIA) Indexed Site

Plant Liquids Production, Gaseous Equivalent (MMcf)" Plant Liquids Production, Gaseous Equivalent (MMcf)" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Indiana Natural Gas Plant Liquids Production, Gaseous Equivalent (MMcf)",1,"Annual",2012 ,"Release Date:","12/12/2013" ,"Next Release Date:","1/7/2014" ,"Excel File Name:","na1150_sin_2a.xls" ,"Available from Web Page:","http://tonto.eia.gov/dnav/ng/hist/na1150_sin_2a.htm" ,"Source:","Energy Information Administration" ,"For Help, Contact:","infoctr@eia.doe.gov"

205

Application of Gaseous Sphere Injection Method for Modeling Under-expanded H2 Injection  

DOE Green Energy (OSTI)

A methodology for modeling gaseous injection has been refined and applied to recent experimental data from the literature. This approach uses a discrete phase analogy to handle gaseous injection, allowing for addition of gaseous injection to a CFD grid without needing to resolve the injector nozzle. This paper focuses on model testing to provide the basis for simulation of hydrogen direct injected internal combustion engines. The model has been updated to be more applicable to full engine simulations, and shows good agreement with experiments for jet penetration and time-dependent axial mass fraction, while available radial mass fraction data is less well predicted.

Whitesides, R; Hessel, R P; Flowers, D L; Aceves, S M

2010-12-03T23:59:59.000Z

206

Process for Photochemical Chlorination of Hydrocarbons  

DOE Patents (OSTI)

A process for chlorination of a major portion of the hydrogen atoms of paraffinic hydrocarbons of five or more carbon atoms may be replaced by subjecting the hydrocarbon to the action of chlorine under active light. The initial chlorination is begun at 25 to 30 deg C with the chlorine diluted with HCl. The later stages may be carried out with undiluted chlorine and the temperature gradually raised to about 129 deg C.

Beanblossom, W.S.

1950-10-31T23:59:59.000Z

207

Formation of hydrocarbons by bacteria and algae  

SciTech Connect

A literature review has been performed summarizing studies on hydrocarbon synthesis by microorganisms. Certain algal and bacterial species produce hydrocarbons in large quantities, 70 to 80% of dry cell mass, when in a controlled environment. The nutritional requirements of these organisms are simple: CO/sub 2/ and mineral salts. The studies were initiated to determine whether or not microorganisms played a role in petroleum formation. 90 references. (DMC)

Tornabene, T.G.

1980-12-01T23:59:59.000Z

208

Clean, economical, underwater (hydrocarbon) storage  

SciTech Connect

A consortium consisting of Howaldtswerke-Deutsche Werft A.G., Phoenix Gummiwerke A.G., Strabag Bau-A.G., and Bugsier Reederei und Bergungs-A.G. offers a plausible solution to the large-scale underwater storage of hydrocarbons. Up to 20 storage compartments of 8000 cu m capacity can be assembled for a capacity of 160,000 cu m. Each compartment is divided in half by a nylon-reinforced polyurethane diaphragm which isolates oil or other products on one side from sea-water ballast on the other side. As oil is pumped into storage on one side of the diaphragm, the diaphragm moves and ballast on the other side is displaced to the sea. Ballast re-enters the compartment during unloading. The system can enable small offshore platforms to produce more economically. Cargo tankers load at 8000 cu m/hr. The tanks will be used in 200 m or greater water depths. The loading station is installed in a buoy 30 m below the water surface.

1978-08-01T23:59:59.000Z

209

Dispersing the Gaseous Protoplanetary Disc and Halting Type II Migration  

E-Print Network (OSTI)

More than 30 extra-solar Jupiter-like planets have shorter periods than the planet Mercury. It is generally accepted that they formed further out, past the snow line (?1 AU), and migrated inwards. In order to be driven by tidal torques from the gaseous disc, the disc exterior to the planet had to contain about a planetary mass. The fact that the planets stopped migrating means that their outer disc was removed. We suggest, following the simulation by Bate et al. (2003), that the outer disc was accreted by the planet. This not only halts migration but removes the outer disc for planets interior to about 2 AU. The disc further out could have been removed by photoevaporation (Matsuyama et al. 2003). Furthermore, as also shown by Bate et al. (op cit) this process also provides an upper limit to planetary masses in agreement with the analysis of observed planetary masses by Zucker & Mazeh (2002). In this scenario, the endgame is a race. The central star is accreting the inner disc and the planet, while the planet is accreting the outer disc. The planet survives if it accretes its outer disc before being accreted by the star. The winner is determined solely by the ratio of the mass of the outer disc to the local surface density of the disc. Some planets are certainly eaten by the central star. Subject headings: extrasolar planets, Jupiter 1.

M. Lecar; D. D. Sasselov

2003-01-01T23:59:59.000Z

210

Gaseous fueled vehicles: A role for natural gas and hydrogen  

SciTech Connect

The commercialization of gaseous hydrogen fueled vehicles requires both the development of hydrogen fueled vehicles and the establishment of a hydrogen fueling infrastructure. These requirements create a classic chicken and egg scenario in that manufacturers will not build and consumers will not buy vehicles without an adequate refueling infrastructure and potential refueling station operators will not invest the needed capital without an adequate market to serve. One solution to this dilemma is to create a bridging strategy whereby hydrogen is introduced gradually via another carrier. The only contending alternative fuel that can act as a bridge to hydrogen fueled vehicles is natural gas. To explore this possibility, IGT is conducting emission tests on its dedicated natural gas vehicle (NGV) test platform to determine what, if any, effects small quantities of hydrogen have on emissions and performance. Furthermore, IGT is actively developing an adsorbent based low-pressure natural gas storage system for NGV applications. This system has also shown promise as a storage media for hydrogen. A discussion of our research results in this area will be presented. Finally, a review of IGT's testing facility will be presented to indicate our capabilities in conducted natural gas/hydrogen vehicle (NGHV) research. 3 refs., 10 figs.

Blazek, C.F.; Jasionowski, W.J.

1991-01-01T23:59:59.000Z

211

GASEOUS CO ABUNDANCE-AN EVOLUTIONARY TRACER FOR MOLECULAR CLOUDS  

SciTech Connect

Planck cold clumps are among the most promising objects to investigate the initial conditions of the evolution of molecular clouds. In this work, by combing the dust emission data from the survey of the Planck satellite with the molecular data of {sup 12}CO/{sup 13}CO/C{sup 18}O (1-0) lines from observations with the Purple Mountain Observatory 13.7 m telescope, we investigate the CO abundance, CO depletion, and CO-to-H{sub 2} conversion factor of 674 clumps in the early cold cores sample. The median and mean values of the CO abundance are 0.89 Multiplication-Sign 10{sup -4} and 1.28 Multiplication-Sign 10{sup -4}, respectively. The mean and median of CO depletion factor are 1.7 and 0.9, respectively. The median value of X{sub CO-to-H{sub 2}} for the whole sample is 2.8 Multiplication-Sign 10{sup 20} cm{sup -2} K{sup -1} km{sup -1} s. The CO abundance, CO depletion factor, and CO-to-H{sub 2} conversion factor are strongly (anti-)correlated to other physical parameters (e.g., dust temperature, dust emissivity spectral index, column density, volume density, and luminosity-to-mass ratio). To conclude, the gaseous CO abundance can be used as an evolutionary tracer for molecular clouds.

Liu Tie; Wu Yuefang; Zhang Huawei, E-mail: liutiepku@gmail.com, E-mail: ywu@pku.edu.cn [Department of Astronomy, Peking University, Beijing 100871 (China)

2013-09-20T23:59:59.000Z

212

Portsmouth Gaseous Diffusion Plant environmental report for 1989  

Science Conference Proceedings (OSTI)

This calendar year 1989 annual report on environmental surveillance of the US Department of Energy's (DOE) Portsmouth Gaseous Diffusion Plant (PORTS) and its environs consists of two parts: the Summary, Discussion, and Conclusions (Part 1) and the Data Presentation (Part 2). The objectives of this report are the following: report 1989 monitoring data for the installation and its environs that may have been affected by operations on the plant site, provide reasonably detailed information about the plant site and plant operations, provide detailed information on input and assumptions used in all calculations, provide trend analyses (where appropriate) to indicate increases and decreases in environmental impact, and provide general information on plant quality assurance. Routine monitoring and sampling for radiation, radioactive materials, and chemical substances on and off the DOE site are used to document compliance with appropriate standards, to identify trends, to provide information for the public, and to contribute to general environmental knowledge. The surveillance program assists in fulfilling the DOE policy of protecting the public, employees, and environment from harm that could be caused by its activities and reducing negative environmental impacts to the greatest degree practicable. Environmental-monitoring information complements data on specific releases, trends, and summaries. 26 refs.

Turner, J.W. (ed.) (Martin Marietta Energy Systems, Inc., Oak Ridge, TN (USA))

1990-10-01T23:59:59.000Z

213

Gaseous fueled vehicles: A role for natural gas and hydrogen  

DOE Green Energy (OSTI)

The commercialization of gaseous hydrogen fueled vehicles requires both the development of hydrogen fueled vehicles and the establishment of a hydrogen fueling infrastructure. These requirements create a classic chicken and egg scenario in that manufacturers will not build and consumers will not buy vehicles without an adequate refueling infrastructure and potential refueling station operators will not invest the needed capital without an adequate market to serve. One solution to this dilemma is to create a bridging strategy whereby hydrogen is introduced gradually via another carrier. The only contending alternative fuel that can act as a bridge to hydrogen fueled vehicles is natural gas. To explore this possibility, IGT is conducting emission tests on its dedicated natural gas vehicle (NGV) test platform to determine what, if any, effects small quantities of hydrogen have on emissions and performance. Furthermore, IGT is actively developing an adsorbent based low-pressure natural gas storage system for NGV applications. This system has also shown promise as a storage media for hydrogen. A discussion of our research results in this area will be presented. Finally, a review of IGT's testing facility will be presented to indicate our capabilities in conducted natural gas/hydrogen vehicle (NGHV) research. 3 refs., 10 figs.

Blazek, C.F.; Jasionowski, W.J.

1991-01-01T23:59:59.000Z

214

DOE Seeks Quotes for Paducah Gaseous Diffusion Plant Environmental Technical Services  

Energy.gov (U.S. Department of Energy (DOE))

Cincinnati The Department of Energy (DOE) today issued a Request for Quotation (RFQ) for an Environmental Technical Services acquisition at the Paducah Gaseous Diffusion Plant (GDP) for the Portsmouth Paducah Project Office (PPPO).

215

Early Morning Ventilation of a Gaseous Tracer from a Mountain Valley  

Science Conference Proceedings (OSTI)

An important component of a joint Environmental Protection AgencyDepartment of Energy field experiment in Brush Creek Valley, Colorado in JulyAugust 1982, was an aircraft sampling task to help verify the early morning ventilation of a gaseous ...

Montie M. Orgill

1989-07-01T23:59:59.000Z

216

Interpolation and Profile Correction (IPC) Method for Shortwave Radiative Transfer in Spectral Intervals of Gaseous Absorption  

Science Conference Proceedings (OSTI)

The new interpolation and profile correction (IPC) method for radiance/flux calculations in gaseous absorption bands is presented. The IPC method is designed to allow an arbitrary spectral resolution including monochromatic mode. It features a ...

Alexei I. Lyapustin

2003-03-01T23:59:59.000Z

217

A Relaxed Eddy Accumulation System for Measuring Surface Fluxes of Total Gaseous Mercury  

Science Conference Proceedings (OSTI)

A relaxed eddy accumulation (REA) system was designed to continuously measure total gaseous mercury (TGM) fluxes over a forest canopy. TGM concentration measurements were measured at 5-min intervals with a Tekran model 2537A mercury analyzer ...

Jesse O. Bash; David R. Miller

2008-02-01T23:59:59.000Z

218

UV Irradiation of Polycyclic Aromatic Hydrocarbons in Ices  

E-Print Network (OSTI)

abundant and widespread class of carbon-car- rying gaseous species is believed to be PAHs (3­5). In dense divided between the hydro

219

Liquid and Gaseous Waste Operations Department Annual Operating Report, CY 1993  

SciTech Connect

This report summarizes the activities of the waste management operations section of the liquid and gaseous waste operations department at ORNL for 1993. The process waste, liquid low-level waste, gaseous waste systems activities are reported, as well as the low-level waste solidification project. Upgrade activities is the various waste processing and treatment systems are summarized. A maintenance activity overview is provided, and program management, training, and other miscellaneous activities are covered.

Maddox, J.J.; Scott, C.B.

1994-02-01T23:59:59.000Z

220

Infrared Spectroscopy of Atomic Lines in Gaseous Nebulae  

E-Print Network (OSTI)

Spectroscopy in the infrared provides a means to assess important properties of the plasma in gaseous nebulae. We present some of our own work that illustrates the need for interactions between the themes of this conference - astronomical data, atomic data, and plasma simulations. We undertook Infrared Space Observatory (ISO) observations with the intent of better understanding the effects of density variations in nebulae, particularly planetary nebulae (PNs), by determining average electron densities from the flux ratios of several fine-structure, IR emission lines. Instead, we are able to ascertain only minor density information because of several instances of the observed line flux ratios being out of range of the theoretical predictions using current atomic data. In these cases, the ISO data cannot presently be used to derive electron density, but rather provide direction for needed improvements in the atomic collision strengths. We have detected an unidentified (uid) strong emission line in an ISO/SWS spectrum of the Orion Nebula. The line has a rest wavelength 2.89350$\\pm$0.00003 $\\mu$m. A long-slit UKIRT observation confirms the presence of this line and shows that the emission is spatially extended and appears to be coincident with the brightest part of the ionized region. We do not detect the uid line in our SWS02 spectra of any of the several bright PNs which we observed for a comparable time. The need for basic atomic data, in this case wavelengths to aid species identification, is paramount for future progress. We look toward the future with a brief synopsis of upcoming or planned IR missions.

R. H. Rubin; R. J. Dufour; T. R. Geballe; S. W. J. Colgan; J. P. Harrington; S. D. Lord; A. L. Liao; D. A. Levine

2001-09-23T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Syngas Upgrading to Hydrocarbon Fuels Technology Pathway  

SciTech Connect

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the upgrading of biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and risk adverse conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas to hydrocarbon pathway to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

Talmadge, M.; Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

2013-03-31T23:59:59.000Z

222

George A. Olah, Carbocation and Hydrocarbon Chemistry  

Office of Scientific and Technical Information (OSTI)

George A. Olah, Carbocation and Hydrocarbon Chemistry George A. Olah, Carbocation and Hydrocarbon Chemistry Resources with Additional Information · Patents George A. Olah Courtesy Rand Larson, Morningstar Productions George Olah received the 1994 Nobel Prize in Chemistry "for his contribution to carbocation chemistry" and his 'role in the chemistry of hydrocarbons. In particular, he developed superacids ... that are much stronger than ordinary acids, are non-nucleophilic, and are fluid at low temperatures. In such media ... carbocations are stable and their physical properties ... can be observed, thus allowing details of their structures to be determined. Besides trivalent ions ... Olah demonstrated the existence of higher coordinate carbocations ... . These species do not violate the octet rule, but involve 2-electron 3-center bonding. '1

223

Gulf Hydrocarbon Inc | Open Energy Information  

Open Energy Info (EERE)

Hydrocarbon Inc Hydrocarbon Inc Jump to: navigation, search Name Gulf Hydrocarbon Inc Address 2016 Main St Place Houston, Texas Zip 77002 Sector Biofuels Product Wholesale marketing of biodiesel and ethanol to refiners, blenders and petroleum distributors Website http://www.gulfhydrocarbon.com Coordinates 29.749227°, -95.371693° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":29.749227,"lon":-95.371693,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

224

Catalysts for synthesizing various short chain hydrocarbons  

DOE Green Energy (OSTI)

Method and apparatus (10), including novel photocatalysts, are disclosed for the synthesis of various short chain hydrocarbons. Light-transparent SiO.sub.2 aerogels doped with photochemically active uranyl ions (18) are fluidized in a fluidized-bed reactor (12) having a transparent window (16), by hydrogen and CO, C.sub.2 H.sub.4 or C.sub.2 H.sub.6 gas mixtures (20), and exposed to radiation (34) from a light source (32) external to the reactor (12), to produce the short chain hydrocarbons (36).

Colmenares, Carlos (Alamo, CA)

1991-01-01T23:59:59.000Z

225

Dissolved gaseous mercury behavior in shallow water estuaries  

E-Print Network (OSTI)

The formation of dissolved gaseous mercury (DGM) can be an important pathway for mercury removal from an aquatic environment. DGM evasional fluxes from an aquatic system can account for up to 95% of atmospheric Hg and its deposition pathways. While this makes DGM an important species of mercury to investigate, the difficulty of accurately analyzing DGM has prevented many from studying it. In this study, DGM was measured in two different types of estuarine environments and with two different methods, discrete and continuous analysis. The discrete technique works reasonably well and is reproducible, but it does not allow one to observe rapid changes in DGM concentration due to long analysis times (~2 hr per sample). When used in this study, the discrete sampling technique agreed well with the continuous technique for Offatts Bayou, Galveston, Texas, and Georgiana Slough in the California Bay-Delta region. The average DGM concentration during the March continuous study at Offatts Bayou was 25.3 8.8 pg L-1. This is significantly higher than the average DGM concentration from Georgiana Slough during late March 2006 (9.6 6.6 pg L-1). DGM seemed to correlate best with photosynthetically active radiation (PAR) data in every study, suggesting that the primary control of its formation is solar irradiation. Stronger positive correlations with PAR were seen when DGM data was shifted back one hour, indicating that mercury photoreactions take time to complete. DGM also correlated positively with wind speed in most instances. However, increased wind speed should enhance air to water transfer of elemental mercury, thus one would expect a negative correlation. DGM co-varied negatively with salinity during the continuous studies, suggesting that the DGM pool is reduced in surface waters by chloride mediated oxidation. Three predictive flux models were used in the study to assess the potential for DGM water to air transfer. For both the Georgiana Slough and Offatts Bayou studies, the predicted flux dropped to or below zero after sunset. This study does contribute to the understanding of DGM cycling in aquatic environments as there are few studies that have made continuous DGM measurements in estuarine environments.

Landin, Charles Melchor

2007-12-01T23:59:59.000Z

226

Dissolved gaseous mercury behavior in shallow water estuaries  

E-Print Network (OSTI)

The formation of dissolved gaseous mercury (DGM) can be an important pathway for mercury removal from an aquatic environment. DGM evasional fluxes from an aquatic system can account for up to 95% of atmospheric Hg and its deposition pathways. While this makes DGM an important species of mercury to investigate, the difficulty of accurately analyzing DGM has prevented many from studying it. In this study, DGM was measured in two different types of estuarine environments and with two different methods, discrete and continuous analysis. The discrete technique works reasonably well and is reproducible, but it does not allow one to observe rapid changes in DGM concentration due to long analysis times (~2 hr per sample). When used in this study, the discrete sampling technique agreed well with the continuous technique for Offatts Bayou, Galveston, Texas, and Georgiana Slough in the California Bay-Delta region. The average DGM concentration during the March continuous study at Offatts Bayou was 25.3 + 8.8 pg L-1. This is significantly higher than the average DGM concentration from Georgiana Slough during late March 2006 (9.6 + 6.6 pg L-1). DGM seemed to correlate best with photosynthetically active radiation (PAR) data in every study, suggesting that the primary control of its formation is solar irradiation. Stronger positive correlations with PAR were seen when DGM data was shifted back one hour, indicating that mercury photoreactions take time to complete. DGM also correlated positively with wind speed in most instances. However, increased wind speed should enhance air to water transfer of elemental mercury, thus one would expect a negative correlation. DGM co-varied negatively with salinity during the continuous studies, suggesting that the DGM pool is reduced in surface waters by chloride mediated oxidation. Three predictive flux models were used in the study to assess the potential for DGM water to air transfer. For both the Georgiana Slough and Offatts Bayou studies, the predicted flux dropped to or below zero after sunset. This study does contribute to the understanding of DGM cycling in aquatic environments as there are few studies that have made continuous DGM measurements in estuarine environments.

Landin, Charles Melchor

2007-12-01T23:59:59.000Z

227

Carburization of austenitic alloys by gaseous impurities in helium  

SciTech Connect

The carburization behavior of Alloy 800H, Inconel Alloy 617 and Hastelloy Alloy X in helium containing various amounts of H/sub 2/, CO, CH/sub 4/, H/sub 2/O and CO/sub 2/ was studied. Corrosion tests were conducted in a temperature range from 649 to 1000/sup 0/C (1200 to 1832/sup 0/F) for exposure time up to 10,000 h. Four different helium environments, identified as A, B, C, and D, were investigated. Concentrations of gaseous impurities were 1500 ..mu..atm H/sub 2/, 450 ..mu..atm CO, 50 ..mu..atm CH/sub 4/ and 50 ..mu..atm H/sub 2/O for Environment A; 200 ..mu..atm H/sub 2/, 100 ..mu..atm CO, 20 ..mu..atm CH/sub 4/, 50 ..mu..atm H/sub 2/O and 5 ..mu..atm CO/sub 2/ for Environment B; 500 ..mu..atm H/sub 2/, 50 ..mu..atm CO, 50 ..mu..atm CH/sub 4/ and < 0.5 ..mu..atm H/sub 2/O for Environment C; and 500 ..mu..atm H/sub 2/, 50 ..mu..atm CO, 50 ..mu..atm CH/sub 4/ and 1.5 ..mu..atm H/sub 2/O for Environment D. Environments A and B were characteristic of high-oxygen potential, while C and D were characteristic of low-oxygen potential. The results showed that the carburization kinetics in low-oxygen potential environments (C and D) were significantly higher, approximately an order of magnitude higher at high temperatures, than those in high-oxygen potential environments (A and B) for all three alloys. Thermodynamic analyses indicated no significant differences in the thermodynamic carburization potential between low- and high-oxygen potential environments. It is thus believed that the enhanced carburization kinetics observed in the low-oxygen potential environments were related to kinetic effects. A qualitatively mechanistic model was proposed to explain the enhanced kinetics. The present results further suggest that controlling the oxygen potential of the service environment can be an effective means of reducing carburization of alloys.

Lai, G.Y.; Johnson, W.R.

1980-03-01T23:59:59.000Z

228

Biogenic Hydrocarbons in the Atmospheric Boundary Layer: A Review  

Science Conference Proceedings (OSTI)

Nonmethane hydrocarbons are ubiquitous trace atmospheric constituents yet they control the oxidation capacity of the atmosphere. Both anthropogenic and biogenic processes contribute to the release of hydrocarbons to the atmosphere. In this ...

J. D. Fuentes; L. Gu; M. Lerdau; R. Atkinson; D. Baldocchi; J. W. Bottenheim; P. Ciccioli; B. Lamb; C. Geron; A. Guenther; T. D. Sharkey; W. Stockwell

2000-07-01T23:59:59.000Z

229

Co-cultured Synechococcus and Shewanella Produce Hydrocarbons ...  

... microbes has been developed. These hydrocarbons may be further processed into vehicle fuels using traditional oil refining techniques.

230

Method for removing chlorine compounds from hydrocarbon mixtures  

DOE Patents (OSTI)

A process for removing halide ions from a hydrocarbon feedstream containing halogenated hydrocarbons wherein the contaminated feedstock is contacted with a solution of a suitable oxidizing acid containing a lanthanide oxide, the acid being present in a concentration of at least about 50 weight percent for a time sufficient to remove substantially all of the halide ion from the hydrocarbon feedstock.

Janoski, Edward J. (Havertown, PA); Hollstein, Elmer J. (Wilmington, DE)

1985-12-31T23:59:59.000Z

231

Production of hydrocarbons from hydrates. [DOE patent application  

DOE Patents (OSTI)

An economical and safe method of producing hydrocarbons (or natural gas) from in situ hydrocarbon-containing hydrates is given. Once started, the method will be self-driven and will continue producing hydrocarbons over an extended period of time (i.e., many days).

McGuire, P.L.

1981-09-08T23:59:59.000Z

232

Method for removing chlorine compounds from hydrocarbon mixtures  

DOE Patents (OSTI)

A process for removing halide ions from a hydrocarbon feedstream containing halogenated hydrocarbons wherein the contaminated feedstock is contacted with a solution of a suitable oxidizing acid containing a lanthanide oxide, the acid being present in a concentration of at least about 50 weight percent for a time sufficient to remove substantially all of the halide ion from the hydrocarbon feedstock.

Janoski, E.J.; Hollstein, E.J.

1984-09-29T23:59:59.000Z

233

Method of dispersing a hydrocarbon using bacteria  

DOE Patents (OSTI)

New protozoan derived microbial consortia and method for their isolation are provided. Consortia and bacteria isolated therefrom are useful for treating wastes such as trichloroethylene and trinitrotoluene. Consortia, bacteria isolated therefrom, and dispersants isolated therefrom are useful for dispersing hydrocarbons such as oil, creosote, wax, and grease.

Tyndall, Richard L. (Clinton, TN)

1996-01-01T23:59:59.000Z

234

Trace elements and Polycyclic Aromatic Hydrocarbons (PAHs)  

E-Print Network (OSTI)

.2.2 Anthropogenic emissions 28 2.3 Polycyclic Aromatic Hydrocarbons 30 2.3.1 Sources of PAHs 30 2.3.2 Gas to particle distribution in atmosphere 32 2.3.3 Gas to particle distribution in atmosphere 32 CHAPTER THREE

Paris-Sud XI, Université de

235

Phyto remediation groundwater trends at the DOE portsmouth gaseous  

Science Conference Proceedings (OSTI)

This paper describes the progress of a phyto-remediation action being performed at the Department of Energy (DOE) Portsmouth Gaseous Diffusion Plant (PORTS) X-740 Waste Oil Handling Facility to remediate contaminated groundwater under a Resource Conservation and Recovery Act (RCRA) closure action. This action was effected by an Ohio Environmental Protection Agency (OEPA) decision to use phyto-remediation as the preferred remedy for the X-740 groundwater contamination. This remedy was recognized as a cost-effective, low-maintenance, and promising method to remediate groundwater contaminated with volatile organic compounds (VOCs), primarily trichloroethylene (TCE). During 1999, prior to the tree installation at the X-740 Phyto-remediation Area, water level measurements in the area were collected from 10 monitoring wells completed in the Gallia Formation. The Gallia is the uppermost water-bearing zone and contains most of the groundwater contamination at PORTS. During the tree installation which took place during the summer of 1999, four new Gallia monitoring wells were installed at the X-740 Area in addition to the 10 Gallia wells which had been installed in the same area during the early 1990's. Manual water level measurements were collected quarterly from these 14 Gallia monitoring wells between 1998 and 2001. These manual water level measurements were collected to monitor the combined impact of the trees on the groundwater prior to root development. Beginning in 2001, water level measurements were collected monthly during the growing season (April-September) and quarterly during the dormant season (October-March). A total of eight water level measurements were collected annually to monitor the phyto-remediation system's effect on the groundwater in the X- 740 Area. The primary function of the X-740 Phyto-remediation Area is to hydraulically prevent further spreading of the TCE plume. This process utilizes deep-rooted plants, such as poplar trees, to extract large quantities of water from the saturated zone. The focus of any phyto-remediation system is to develop a cone of depression under the entire plantation area. This cone of depression can halt migration of the contaminant plume and can create a hydraulic barrier, thereby maintaining plume capture. While a cone of depression is not yet evident at the X-740 Phyto-remediation Area, water level measurements in 2004 and 2005 differed from measurements taken in previous years, indicating that the now mature trees are influencing groundwater flow direction and gradient at the site. Water level measurements taken from 2003 through 2005 indicate a trend whereby groundwater elevations steadily decreased in the X-740 Phyto-remediation System. During this time, an average groundwater table drop of 0.30 feet was observed. Although the time for the phyto-remediation system to mature had been estimated at two to three years, these monitoring data indicate a period of four to five years for the trees to reach maturity. Although, these trends are not apparent from analysis of the potentiometric surface contours, it does appear that the head gradient across the site is higher during the spring and lower during the fall. It is not clear, however, whether this trend was initiated by the installation of the phyto-remediation system. This paper will present the groundwater data collected to date to illustrate the effects of the trees on the groundwater table. (authors)

Lewis, A.C.; Baird, D.R. [CDM, Piketon, OH (United States)

2007-07-01T23:59:59.000Z

236

Portsmouth Gaseous Diffusion Plant Director's Final Findings and Orders, October 4, 1995  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth Gaseous Diffusion Plant Director's Final Portsmouth Gaseous Diffusion Plant Director's Final Findings and Orders, October 4, 1995 BEFORE THE OHIO ENVIRONMENTAL PROTECTION AGENCY In the Matter Of: United States Department of Energy : Director's Final Portsmouth Gaseous Diffusion Plant : Findings and Orders P.O. Box 700 : Piketon, Ohio 45661-0700 : Respondent It is hereby agreed by and among the parties hereto as follows: Table of Contents I. Jurisdiction II. Parties Bound III. Definitions IV. Findings of Fact V. Orders VI. Limitations of Director's Approval VII. Notice VIII. Project Managers IX. Dispute Resolution X. Funding XI. Other Applicable Laws XII. Reservation of Rights XIII. Modification XIV. Termination XV. Other Claims XVI. Signatories XVII. Waiver I. Jurisdiction These Director's Final Findings and Orders ("Orders") are issued to the United States

237

Oak Ridge K-25 Gaseous Diffusion Plant, Former Production Workers Screening  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

K-25 Gaseous Diffusion Plant, Former Production Workers K-25 Gaseous Diffusion Plant, Former Production Workers Screening Projects Oak Ridge K-25 Gaseous Diffusion Plant, Former Production Workers Screening Projects Project Name: Worker Health Protection Program Covered DOE Site: K-25 Worker Population Served: Production Workers Principal Investigator: Jim Frederick Co-Principal Investigator: Steven Markowitz, MD Toll-free Telephone: (888) 241-1199 Local Outreach Office: Bruce Lawson 133 Raleigh Road Oak Ridge, TN 37830 Local Medical Clinics: ParkMed 110 S. Illinois Avenue Oak Ridge, TN 37380 Website: http://www.worker-health.org/ This project is conducted by the United Steelworkers in conjunction with Queens College of the City University of New York. The program is being offered as a service to both former and current workers. Free of charge,

238

Simulation of VUV electroluminescence in micropattern gaseous detectors: the case of GEM and MHSP  

E-Print Network (OSTI)

Electroluminescence produced during avalanche development in gaseous avalanche detectors is an useful information for triggering, calorimetry and tracking in gaseous detectors. Noble gases present high electroluminescence yields, emitting mainly in the VUV region. The photons can provide signal readout if appropriate photosensors are used. Micropattern gaseous detectors are good candidates for signal amplification in high background and/or low rate experiments due to their high electroluminescence yields and radiopurity. In this work, the VUV light responses of the Gas Electron Multiplier and of the Micro-Hole Strip Plate, working with pure xenon, are simulated and studied in detail using a new and versatile C++ toolkit. It is shown that the solid angle subtended by a photosensor placed below the microstructures depends on the operating conditions. The obtained absolute EL yields, determined for different gas pressures and as functions of the applied voltage, are compared with those determined experimentally.

C. A. B. Oliveira; P. M. M. Correia; H. Schindler; A. L. Ferreira; C. M. B. Monteiro; J. M. F. dos Santos; S. Biagi; R. Veenhof; J. F. C. A. Veloso

2012-06-08T23:59:59.000Z

239

Quasi-monoenergetic protons accelerated by laser radiation pressure and shocks in thin gaseous targets  

Science Conference Proceedings (OSTI)

Recent experiments and simulations have demonstrated effective CO{sub 2} laser acceleration of quasi-monoenergetic protons from thick gaseous hydrogen target (of thickness tens of laser wavelengths) via hole boring and shock accelerations. We present here an alternative novel acceleration scheme by combining laser radiation pressure acceleration with shock acceleration of protons in a thin gaseous target of thickness several laser wavelengths. The laser pushes the thin gaseous plasma forward while compressing it with protons trapped in it. We demonstrated the combined acceleration with two-dimensional particle-in-cell simulation and obtained quasi-monoenergetic protons {approx}44 MeV in a gas target of thickness twice of the laser wavelength irradiated by circularly polarized CO{sub 2} laser with normalized laser amplitude a{sub 0}=10.

He Minqing; Shao Xi; Liu Chuansheng; Liu Tungchang; Su Jaojang; Dudnikova, Galina; Sagdeev, Roald Z. [East-West Space Science Center, University of Maryland, College Park, Maryland 20742 (United States); Sheng Zhengming [Department of Physics, Shanghai Jiao Tong University, Shanghai 200240 (China); Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, CAS, Beijing 100190 (China)

2012-07-15T23:59:59.000Z

240

Oak Ridge National Lebroatory Liquid&Gaseous Waste Treatment System Strategic Plan  

SciTech Connect

Excellence in Laboratory operations is one of the three key goals of the Oak Ridge National Laboratory (ORNL) Agenda. That goal will be met through comprehensive upgrades of facilities and operational approaches over the next few years. Many of ORNL's physical facilities, including the liquid and gaseous waste collection and treatment systems, are quite old, and are reaching the end of their safe operating life. The condition of research facilities and supporting infrastructure, including the waste handling facilities, is a key environmental, safety and health (ES&H) concern. The existing infrastructure will add considerably to the overhead costs of research due to increased maintenance and operating costs as these facilities continue to age. The Liquid Gaseous Waste Treatment System (LGWTS) Reengineering Project is a UT-Battelle, LLC (UT-B) Operations Improvement Program (OIP) project that was undertaken to develop a plan for upgrading the ORNL liquid and gaseous waste systems to support ORNL's research mission.

Van Hoesen, S.D.

2003-09-09T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Liquid and Gaseous Waste Operations Department annual operating report CY 1996  

SciTech Connect

This annual report summarizes operating activities dealing with the process waste system, the liquid low-level waste system, and the gaseous waste system. It also describes upgrade activities dealing with the process and liquid low-level waste systems, the cathodic protection system, a stack ventilation system, and configuration control. Maintenance activities are described dealing with nonradiological wastewater treatment plant, process waste treatment plant and collection system, liquid low-level waste system, and gaseous waste system. Miscellaneous activities include training, audits/reviews/tours, and environmental restoration support.

Maddox, J.J.; Scott, C.B.

1997-03-01T23:59:59.000Z

242

A Possible Anisotropy in Blackbody Radiation Viewed through Non-uniform Gaseous Matter  

E-Print Network (OSTI)

A non-local gauge symmetry of a complex scalar field, which can be trivially extended to spinor fields, was demonstrated in a recent paper (Mod.Phys.Lett. A13, 1265 (1998) ; hep-th/9902020). The corresponding covariant Lagrangian density yielded a new, non-local Quantum Electrodynamics. In this letter we show that as a consequence of this new QED, a blackbody radiation viewed through gaseous matter appears to show a slight deviation from the Planck formula, and propose an experimental test to check this effect. We also show that a non-uniformity in this gaseous matter distribution leads to an (apparent) spatial anisotropy in the blackbody radiation.

T K Rai Dastidar

1999-03-12T23:59:59.000Z

243

Hydrous pyrolysis/oxidation process for in situ destruction of chlorinated hydrocarbon and fuel hydrocarbon contaminants in water and soil  

DOE Patents (OSTI)

In situ hydrous pyrolysis/oxidation process is useful for in situ degradation of hydrocarbon water and soil contaminants. Fuel hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, petroleum distillates and other organic contaminants present in the soil and water are degraded by the process involving hydrous pyrolysis/oxidation into non-toxic products of the degradation. The process uses heat which is distributed through soils and water, optionally combined with oxygen and/or hydrocarbon degradation catalysts, and is particularly useful for remediation of solvent, fuel or other industrially contaminated sites.

Knauss, Kevin G. (Livermore, CA); Copenhaver, Sally C. (Livermore, CA); Aines, Roger D. (Livermore, CA)

2000-01-01T23:59:59.000Z

244

Hydrocarbon autothermal performing program annual report  

DOE Green Energy (OSTI)

A goal of the national molten carbonate fuel cells program is to develop the capability to use heavy fuel oil or coal liquids as feed stock for fuel cell power plants. These liquid fuels must be reformed to gaseous fuels which are composed mainly of CO, H/sub 2/, CO/sub 2/, and H/sub 2/O (and N/sub 2/) for use by the fuel cell. The goal of this program is to understand the mechanism for the formation of soot under conditions relevant to autothermal reformers and to translate this understanding to recommendations for modification of autothermal design. This goal is to be accomplished by a combination of experimental and theoretical tasks. The experimental tasks are to study the mechanisms of soot formation under controlled conditions with gaseous fuels, O/sub 2/ and H/sub 2/O, both premixed, and with well-described mixing, with and without catalysts. The theoretical tasks will develop models to describe the experimental data first by detailed chemical and fluid mechanical processes, second by quasiequilibrium models, and finally by scaling laws. These scaling laws will then be utilized in recommending reformer design modifications. The first year's work of the two year program is described. (WHK)

Lewis, P.F.; Kothandaraman, G.; Pugh, E.; Lord, G.; Yarrington, R.; Hwang, H.S.

1980-10-01T23:59:59.000Z

245

Method and apparatus for synthesizing hydrocarbons  

DOE Patents (OSTI)

A method and apparatus for synthesizing a mixture of hydrocarbons having five carbons or less is disclosed. An equal molar ratio of CO and H/sub 2/ gases is caused to pass through a ThO/sub 2/ catalyst having a surface area of about 80 to 125 m/sup 2//g. The catalyst further includes Na present as a substitutional cation in an amount of about 5 to 10 atom %. At a temperature of about 340 to 360/sup 0/C, and at pressures of about 20 to 50 atm, CH/sub 3/OH is produced in an amount of about 90 wt % of the total hydrocarbon mixture, and comprised 1 mole % of the effluent gas.

Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

1983-06-21T23:59:59.000Z

246

Chemical kinetic modelling of hydrocarbon ignition  

DOE Green Energy (OSTI)

Chemical kinetic modeling of hydrocarbon ignition is discussed with reference to a range of experimental configurations, including shock tubes, detonations, pulse combustors, static reactors, stirred reactors and internal combustion engines. Important conditions of temperature, pressure or other factors are examined to determine the main chemical reaction sequences responsible for chain branching and ignition, and kinetic factors which can alter the rate of ignition are identified. Hydrocarbon ignition usually involves complex interactions between physical and chemical factors, and it therefore is a suitable and often productive subject for computer simulations. In most of the studies to be discussed below, the focus of the attention is placed on the chemical features of the system. The other physical parts of each application are generally included in the form of initial or boundary conditions to the chemical kinetic parts of the problem, as appropriate for each type of application being addressed.

Westbrook, C.K.; Pitz, W.J.; Curran, H.J.; Gaffuri, P.; Marinov, N.M.

1995-08-25T23:59:59.000Z

247

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons  

DOE Patents (OSTI)

Oxidative dehydrogenation of alkanes to unsaturated hydrocarbons is carried out over metal vanadate catalysts under oxidizing conditions. The vanadate catalysts are represented by the formulas M[sub 3](VO[sub 4])[sub 2] and MV[sub 2]O[sub 6], M representing Mg, Zn, Ca, Pb, or Cd. The reaction is carried out in the presence of oxygen, but the formation of oxygenate by-products is suppressed.

Kung, H.H.; Chaar, M.A.

1988-10-11T23:59:59.000Z

248

HYDROCARBON FORMATION ON POLYMER-SUPPORTED COBALT  

SciTech Connect

In this report we detail the synthesis catalytic chemistry of polystyrene supported {eta}{sup 5} ~cyclopentadienyl- dicarbonyl cobalt, CpCo(CO){sub 2}. This material is active in the hydrogenation of CO to saturated linear hydrocarbons and appears to retain its "homogeneous", mononuclear character during the course of its catalysis, During the course of our work 18% and 20% crosslinked analogs of polystyrene supported CpCo(CO){sub 2} were shown to exhibit limited catalytic activity and no CO activation.

Benner, Linda S.; Perkins, Patrick; Vollhardt, K.Peter C.

1980-10-01T23:59:59.000Z

249

A Review of World Hydrocarbon Resource Assessments  

Science Conference Proceedings (OSTI)

This study reviews assessments of world oil, natural gas, and oil shale resources made between the end of World War II and the end of 1980. Details are provided on the methods used in developing these assessments, geographic coverage, time horizons, and major assumptions (e.g., about discovery rates and recovery factor). Conclusions on the current state of knowledge concerning each of these hydrocarbon resources are presented.

1982-11-01T23:59:59.000Z

250

Literature Review of Background Polycyclic Aromatic Hydrocarbons  

Science Conference Proceedings (OSTI)

Polycyclic aromatic hydrocarbons (PAHs) continuously move through the environment, often via atmospheric transport. The subsequent deposition of particulates containing PAHs along with other sources of PAHs, such as natural vegetative decay, result in "background" PAHs in surficial soils. Even in pristine areas, surface and near surface soils can contain detectable levels of PAHs. This study provides data on the concentrations and distributions of background PAHs observed in environmental media. Such inf...

2000-03-20T23:59:59.000Z

251

Hydrocarbon content of geopressured brines. Final report  

DOE Green Energy (OSTI)

Design Well data (bottomhole pressure minus wellhead pressure, GWR, and hydrocarbon composition) is presented as a function of producing conditions. These are examined in conjunction with the following models to attempt to deduce the reservoir brine saturation level: (1) reservoir contains gas dispersed in the pores and the gas saturation is greater than critical; (2) reservoir brine is gas-saturated; (3) bubble point below hydrostatic pressure; and (4) bubble point between hydrostatic pressure and reservoir pressure. 24 figs., 10 tabs. (ACR)

Osif, T.L.

1985-08-01T23:59:59.000Z

252

Hydrocarbon Fouling of SCR during PCCI combustion  

SciTech Connect

The combination of advanced combustion with advanced selective catalytic reduction (SCR) catalyst formulations was studied in the work presented here to determine the impact of the unique hydrocarbon (HC) emissions from premixed charge compression ignition (PCCI) combustion on SCR performance. Catalyst core samples cut from full size commercial Fe- and Cu-zeolite SCR catalysts were exposed to a slipstream of raw engine exhaust from a 1.9-liter 4-cylinder diesel engine operating in conventional and PCCI combustion modes. The zeolites which form the basis of these catalysts are different with the Cu-based catalyst made on a chabazite zeolite which las smaller pore structures relative to the Fe-based catalyst. Subsequent to exposure, bench flow reactor characterization of performance and hydrocarbon release and oxidation enabled evaluation of overall impacts from the engine exhaust. The Fe-zeolite NOX conversion efficiency was significantly degraded, especially at low temperatures (<250 C), after the catalyst was exposed to the raw engine exhaust. The degradation of the Fe-zeolite performance was similar for both combustion modes. The Cu-zeolite showed better tolerance to HC fouling at low temperatures compared to the Fe-zeolite but PCCI exhaust had a more significant impact than the exhaust from conventional combustion on the NOX conversion efficiency. Furthermore, chemical analysis of the hydrocarbons trapped on the SCR cores was conducted to better determine chemistry specific effects.

Prikhodko, Vitaly Y [ORNL; Pihl, Josh A [ORNL; Lewis Sr, Samuel Arthur [ORNL; Parks, II, James E [ORNL

2012-01-01T23:59:59.000Z

253

Environmental Restoration Site-Specific Plan for the Portsmouth Gaseous Diffusion Plant, FY 93  

Science Conference Proceedings (OSTI)

The purpose of this Site-Specific Plan (SSP) is to describe past, present, and future activities undertaken to implement Environmental Restoration and Waste Management goals at the Portsmouth Gaseous Diffusion Plant (PORTS). The SSP is presented in sections emphasizing Environmental Restoration description of activities, resources, and milestones.

Not Available

1993-01-15T23:59:59.000Z

254

Method of absorbing UF.sub.6 from gaseous mixtures in alkamine absorbents  

DOE Patents (OSTI)

A method of recovering uranium hexafluoride from gaseous mixtures employing as an absorbent a liquid composition at least one of the components of which is chosen from the group consisting of ethanolamine, diethanolamine, and 3-methyl-3-amino-propane-diol-1,2.

Lafferty, Robert H. (Oak Ridge, TN); Smiley, Seymour H. (Oak Ridge, TN); Radimer, Kenneth J. (Little Falls, NJ)

1976-04-06T23:59:59.000Z

255

Transition metal ion-assisted photochemical generation of alkyl halides and hydrocarbons from carboxylic acids  

Science Conference Proceedings (OSTI)

Near-UV photolysis of aqueous solutions of propionic acid and aqueous Fe3+ in the absence of oxygen generates a mixture of hydrocarbons (ethane, ethylene and butane), carbon dioxide, and Fe2+. The reaction becomes mildly catalytic (about five turnovers) in the presence of oxygen which converts a portion of alkyl radicals to oxidizing intermediates that reoxidize Fe2+. The photochemistry in the presence of halide ions (X? = Cl?, Br?) generates ethyl halides via halogen atom abstraction from FeXn3?n by ethyl radicals. Near-quantitative yields of C2H5X are obtained at ?0.05 M X?. Competition experiments with Co(NH3)5Br2+ provided kinetic data for the reaction of ethyl radicals with FeCl2+ (k = (4.0 0.5) 106 M?1 s?1) and with FeBr2+ (k = (3.0 0.5) 107 M?1 s?1). Photochemical decarboxylation of propionic acid in the presence of Cu2+ generates ethylene and Cu+. Longer-chain acids also yield alpha olefins as exclusive products. These reactions become catalytic under constant purge with oxygen which plays a dual role. It reoxidizes Cu+ to Cu2+, and removes gaseous olefins to prevent accumulation of Cu+(olefin) complexes and depletion of Cu2+. The results underscore the profound effect that the choice of metal ions, the medium, and reaction conditions exert on the photochemistry of carboxylic acids.

Carraher, Jack; Pestovsky, Oleg; Bakac, Andreja

2012-03-14T23:59:59.000Z

256

Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts  

NLE Websites -- All DOE Office Websites (Extended Search)

of Reforming Hydrocarbon Fuels Using of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts Contact NETL Technology Transfer Group techtransfer@netl.doe.gov May 2012 Opportunity Research is currently active on the technology "Methods of Reforming Hydrocarbon Fuels Using Hexaaluminate Catalysts." The technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory. Overview This invention discloses a method to reform hydrocarbon fuels using hexa- aluminate catalysts. In general, the method successfully disrupts the forma- tion of carbon that leads to the deactivation of the catalyst, a key element in the reforming of hydrocarbon fuels. When researchers are designing catalysts to reform hydrocarbon fuels, one

257

Method for producing hydrocarbon and alcohol mixtures. [Patent application  

DOE Patents (OSTI)

It is an object of this invention to provide an efficient process for extracting alcohols and ketones from an aqueous solution containing the same into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. Another object of the invention is to provide a mixture consisting of hydrocarbon, alcohols or ketones, polyoxyalkylene polymer and water which can be directly added to fuels or further purified. The above stated objects are achieved in accordance with a preferred embodiment of the invention by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5 to 18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is mixed in the presence or one or more of a group of polyoxyalkylene polymers described in detail hereinafter; the fermentation alcohol being extracted into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

Compere, A.L.; Googin, J.M.; Griffith, W.L.

1980-12-01T23:59:59.000Z

258

Harvester ants utilize cuticular hydrocarbons in nestmate recognition  

E-Print Network (OSTI)

AbstractCuticular hydrocarbons appear to play a role in ant nestmate recognition, but few studies have tested this hypothesis experimentally with purified hydrocarbon extracts. We exposed captive colonies of the harvester ant Pogonomyrmex barbatus to small glass blocks coated with whole cuticular lipid extracts and the purified hydrocarbon portion of extracts from nestmate and nonnestmate workers. As an estimate of agonistic behavior, we measured the proportion of ants in contact with blocks that flared their mandibles. Blocks coated with cuticular extracts from nonnestmates were contacted by more workers in one of two experiments and elicited higher levels of aggression in both experiments than blocks bearing extracts from nestmates. The cuticular hydrocarbon fraction of extracts alone was sufficient to elicit agonistic behavior toward nonnestmates. The results demonstrate that harvester ants can perceive differences in cuticular hydrocarbon composition, and can use those differences in nestmate recognition. Key WordsCuticular hydrocarbons, Formicidae, Nestmate recognition, Pogonomyrmex barbatus.

Diane Wagner; Madeleine Tissot; William Cuevas; Deborah M. Gordon

2000-01-01T23:59:59.000Z

259

Catalytic conversion of cellulose to liquid hydrocarbon fuels ...  

Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities

260

Novel catalyst for selective NOx reduction using hydrocarbons ...  

This invention discloses a catalyst and process for removing nitrogen oxides from exhaust streams under lean burn conditions using hydrocarbons as the reductant.

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

ORGANIC GEOCHEMICAL STUDIES. I. MOLECULAR CRITERIA FOR HYDROCARBON GENESIS  

E-Print Network (OSTI)

isoprenoid hydrocarbons in crude oils and sediments must beisomers (up to C ) in crude oil and those characterised inarc found ubiqubtously in crude oils and shalt extracts as

McCarthy, Eugene D.; Calvin, Kevin

2008-01-01T23:59:59.000Z

262

Methods for natural gas and heavy hydrocarbon co-conversion  

DOE Patents (OSTI)

A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.

Kong, Peter C. (Idaho Falls, ID); Nelson, Lee O. (Idaho Falls, ID); Detering, Brent A. (Idaho Falls, ID)

2009-02-24T23:59:59.000Z

263

Recovery of nitrogen and light hydrocarbons from polyalkene ...  

Recovery of nitrogen and light hydrocarbons from polyalkene purge gas United States Patent. Patent Number: 6,576,043: Issued: June 10, 2003: Official Filing:

264

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents (OSTI)

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons.

Senum, Gunnar I. (Patchogue, NY); Dietz, Russell N. (Patchogue, NY)

1994-01-01T23:59:59.000Z

265

Carbonaceous adsorbent regeneration and halocarbon displacement by hydrocarbon gases  

DOE Patents (OSTI)

This invention describes a process for regeneration of halocarbon bearing carbonaceous adsorbents through which a carbonaceous adsorbent is contacted with hydrocarbon gases, preferably propane, butane and pentane at near room temperatures and at atmospheric pressure. As the hydrocarbon gases come in contact with the adsorbent, the hydrocarbons displace the halocarbons by physical adsorption. As a result of using this process, the halocarbon concentration and the hydrocarbon eluant is increased thereby allowing for an easier recovery of pure halocarbons. By using the process of this invention, carbonaceous adsorbents can be regenerated by an inexpensive process which also allows for subsequent re-use of the recovered halocarbons. 8 figures.

Senum, G.I.; Dietz, R.N.

1994-04-05T23:59:59.000Z

266

Multi-step catalytic hydroprocessing to produce hydrocarbon fuels ...  

Multi-step catalytic hydroprocessing to produce hydrocarbon fuels from biomass pyrolysis bio-oil (PNNL IPID 16665) Pacific Northwest National Laboratory

267

Systems and methods for producing hydrocarbons from tar sands formations  

DOE Patents (OSTI)

A system for treating a tar sands formation is disclosed. A plurality of heaters are located in the formation. The heaters include at least partially horizontal heating sections at least partially in a hydrocarbon layer of the formation. The heating sections are at least partially arranged in a pattern in the hydrocarbon layer. The heaters are configured to provide heat to the hydrocarbon layer. The provided heat creates a plurality of drainage paths for mobilized fluids. At least two of the drainage paths converge. A production well is located to collect and produce mobilized fluids from at least one of the converged drainage paths in the hydrocarbon layer.

Li, Ruijian (Katy, TX); Karanikas, John Michael (Houston, TX)

2009-07-21T23:59:59.000Z

268

Polycyclic Aromatic Hydrocarbon Exposure in German Coke Oven Workers.  

E-Print Network (OSTI)

??Polycyclic aromatic hydrocarbons (PAHs) are formed whenever there is incomplete combustion of carbonaceous material. They are ubiquitous in the environment and background levels are found (more)

Thoroman, Jeffrey S.

2010-01-01T23:59:59.000Z

269

Enhanced solubility of petroleum hydrocarbons using biosurfactants  

E-Print Network (OSTI)

This research investigation included two similarly-designed experiments. In the first, a biological surfactant produced by Rhodococcus strain H13-A and a commonly-used synthetic surfactant, Tween-80 (polyoxyethylene sorbitan monooleate), were compared for their effectiveness in enhancing the transport of polycyclic aromatic hydrocarbons from a complex organic phase into aqueous solution. In the batch-reactor experiment, each reactor contained a surfactant solution and West Texas Crude oil, while the control reactors contained distilled-deionized water and the crude oil. Using a temporal-monitoring scheme, the reactors were sacrificially sampled to determine the water-accommodated fraction (WAF). The phenanthrenes, fluorenes, pyrenes, and chrysenes showed significant increases in their aqueous-plus-micellar-phase concentrations in the presence of surfactants; the increase was greater for the biosurfactant compared to the synthetic surfactant. The enhancement in "solubility" was also more significant for the highly-substituted aromatics, when compared to their parent compounds. In the second study, the effects of four biosurfactants on the solubility of petroleum saturated hydrocarbons were compared. Rhodococcus species H13-A (glycolipid-producing), Pseudomonas aeruginosa ATCC 9027 (rhamnolipid-producing), Candida bombicola ATCC 22214 (sophorolipid-producing), and Bacillus subtilis ATCC 21332 (surfactin-producing) were compared to a control of distilled-deionized water. The experimental design was similar that of the first study. The Pseudomonas aeruginosa treatment significantly enhanced the solubility of the lower-weight, higher-weight and branched saturated hydrocarbons. The Rhodococcus treatment significantly enhanced the solubility of the low-molecular-weight compounds, but only moderately increased the solubilities of the other saturates. Neither the Candida nor the Bacillus solutions produced any negligible increase in solubility under these laboratory conditions.

Page, Cheryl Ann

1997-01-01T23:59:59.000Z

270

Collisional processes of hydrocarbons in hydrogen plasmas  

DOE Green Energy (OSTI)

We have investigated the reactions of methane and its derivatives with hydrogen plasmas for use in modelling carbon and hydrocarbon transport in hydrogen plasmas. We provide quantitative information over the temperature range from 0.1 eV to 2 keV for the most significant reactions of methane and methane fragments with electrons and protons. We review the properties of each reaction, present graphs of the cross section and reaction rate coefficient, and give analytical fits for sigma and (sigmav). 34 refs.

Ehrhardt, A.B.; Langer, W.D.

1987-09-01T23:59:59.000Z

271

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Production Production Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per short ton. Barrel A unit of volume equal to 42 U.S. gallons. Butane (C4H10) A normally gaseous straight-chain or branch-chain hydrocarbon extracted from natural gas or refinery gas streams. It includes isobutane and normal butane and is designated in ASTM Specification D1835 and Gas Processors Association Specifications for commercial butane.

272

Table Definitions, Sources, and Explanatory Notes  

Gasoline and Diesel Fuel Update (EIA)

Receipts by Pipeline, Tanker, and Barge Between PAD Districts Receipts by Pipeline, Tanker, and Barge Between PAD Districts Definitions Key Terms Definition Asphalt A dark-brown-to-black cement-like material containing bitumens as the predominant constituent obtained by petroleum processing; used primarily for road construction. It includes crude asphalt as well as the following finished products: cements, fluxes, the asphalt content of emulsions (exclusive of water), and petroleum distillates blended with asphalt to make cutback asphalts. Note: The conversion factor for asphalt is 5.5 barrels per short ton. Barrel A unit of volume equal to 42 U.S. gallons. Butane (C4H10) A normally gaseous straight-chain or branch-chain hydrocarbon extracted from natural gas or refinery gas streams. It includes isobutane and normal butane and is designated in ASTM Specification D1835 and Gas Processors Association Specifications for commercial butane.

273

Preliminary Geospatial Analysis of Arctic Ocean Hydrocarbon Resources  

SciTech Connect

Ice coverage of the Arctic Ocean is predicted to become thinner and to cover less area with time. The combination of more ice-free waters for exploration and navigation, along with increasing demand for hydrocarbons and improvements in technologies for the discovery and exploitation of new hydrocarbon resources have focused attention on the hydrocarbon potential of the Arctic Basin and its margins. The purpose of this document is to 1) summarize results of a review of published hydrocarbon resources in the Arctic, including both conventional oil and gas and methane hydrates and 2) develop a set of digital maps of the hydrocarbon potential of the Arctic Ocean. These maps can be combined with predictions of ice-free areas to enable estimates of the likely regions and sequence of hydrocarbon production development in the Arctic. In this report, conventional oil and gas resources are explicitly linked with potential gas hydrate resources. This has not been attempted previously and is particularly powerful as the likelihood of gas production from marine gas hydrates increases. Available or planned infrastructure, such as pipelines, combined with the geospatial distribution of hydrocarbons is a very strong determinant of the temporal-spatial development of Arctic hydrocarbon resources. Significant unknowns decrease the certainty of predictions for development of hydrocarbon resources. These include: 1) Areas in the Russian Arctic that are poorly mapped, 2) Disputed ownership: primarily the Lomonosov Ridge, 3) Lack of detailed information on gas hydrate distribution, and 4) Technical risk associated with the ability to extract methane gas from gas hydrates. Logistics may control areas of exploration more than hydrocarbon potential. Accessibility, established ownership, and leasing of exploration blocks may trump quality of source rock, reservoir, and size of target. With this in mind, the main areas that are likely to be explored first are the Bering Strait and Chukchi Sea, in spite of the fact that these areas do not have highest potential for future hydrocarbon reserves. Opportunities for improving the mapping and assessment of Arctic hydrocarbon resources include: 1) Refining hydrocarbon potential on a basin-by-basin basis, 2) Developing more realistic and detailed distribution of gas hydrate, and 3) Assessing the likely future scenarios for development of infrastructure and their interaction with hydrocarbon potential. It would also be useful to develop a more sophisticated approach to merging conventional and gas hydrate resource potential that considers the technical uncertainty associated with exploitation of gas hydrate resources. Taken together, additional work in these areas could significantly improve our understanding of the exploitation of Arctic hydrocarbons as ice-free areas increase in the future.

Long, Philip E.; Wurstner, Signe K.; Sullivan, E. C.; Schaef, Herbert T.; Bradley, Donald J.

2008-10-01T23:59:59.000Z

274

Long-range global warming impact of gaseous diffusion plant operation  

SciTech Connect

The DOE gaseous diffusion plant complex makes extensive use of CFC-114 as a primary coolant. As this material is on the Montreal Protocol list of materials scheduled for production curtailment, a substitute must be found. In addition to physical cooling properties, the gaseous diffusion application imposes the unique requirement of chemical inertness to fluorinating agents. This has narrowed the selection of a near-term substitute to two fully fluorinated material, FC-318 and FC-3110, which are likely to be strong, long-lived greenhouse gases. In this document, calculations are presented showing, for a number of plausible scenarios of diffusion plant operation and coolant replacement strategy, the future course of coolant use, greenhouse gas emissions (including coolant and power-related indirect CO{sub 2} emissions), and the consequent global temperature impacts of these scenarios.

Trowbridge, L.D.

1992-09-01T23:59:59.000Z

275

Proposed On-Site Waste Disposal Facility (OSWDF) at the Portsmouth Gaseous Diffusion Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

OH OH EM Project: On-Site Disposal Facility ETR Report Date: February 2008 ETR-12 United States Department of Energy Office of Environmental Management (DOE-EM) External Technical Review of the Proposed On-Site Waste Disposal Facility (OSWDF) at the Portsmouth Gaseous Diffusion Plant Why DOE-EM Did This Review The On-Site Waste Disposal Facility (OSWDF) is proposed for long-term containment of contaminated materials from the planned Decontamination and Decommissioning (D&D) activities at the Portsmouth Gaseous Diffusion Plant. Acceptable performance of the proposed OSWDF will depend on interactions between engineered landfill features and operations methods that recognize the unique characteristics of the waste stream and site-

276

Portsmouth Gaseous Diffusion Plant Director's Final Findings and Orders, October 4, 1995 Summary  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth Gaseous Diffusion Plant Director's Final Portsmouth Gaseous Diffusion Plant Director's Final Findings and Orders, October 4, 1995 State Ohio Agreement Type Federal Facility Agreement Legal Driver(s) FFCAct Scope Summary Agreement between the Ohio EPA and DOE approving the STP and setting waste treatment milestones Parties DOE; Ohio Department of Environmental Protection Date 10/4/1995 SCOPE * Approve the Compliance Plan Volume of the amended PSTP submitted to Ohio EPA on October 2, 1995, hereafter referred to as "approved STP." * Set forth guidelines for storage and treatment of mixed wastes at the Facility which are not being stored in accordance with the LDR requirements of OAC rule 3745-59- 50. * Establish milestones and target dates for approved STP. ESTABLISHING MILESTONES

277

Summary - Proposed On-Site Disposal Facility (OSDF) at the Paducah Gaseous Diffusion Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Paducah, KY Paducah, KY EM Project: On-Site Disposal Facility ETR Report Date: August 2008 ETR-16 United States Department of Energy Office of Environmental Management (DOE-EM) External Technical Review of the Proposed On-Site Disposal Facility(OSDF) at the Paducah Gaseous Diffusion Plant Why DOE-EM Did This Review The Paducah Gaseous Diffusion Plant (PGDP) is an active uranium enrichment facility that was placed on the National Priorities List. DOE is required to remediate the PGDP in accordance with the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA). DOE is evaluating alternatives to dispose of waste generated from the remedial activities at the PGDP. One option is to construct an on-site disposal facility (OSDF) meeting the CERCLA requirements.

278

Process and system for removing sulfur from sulfur-containing gaseous streams  

DOE Patents (OSTI)

A multi-stage UCSRP process and system for removal of sulfur from a gaseous stream in which the gaseous stream, which contains a first amount of H.sub.2S, is provided to a first stage UCSRP reactor vessel operating in an excess SO.sub.2 mode at a first amount of SO.sub.2, producing an effluent gas having a reduced amount of SO.sub.2, and in which the effluent gas is provided to a second stage UCSRP reactor vessel operating in an excess H.sub.2S mode, producing a product gas having an amount of H.sub.2S less than said first amount of H.sub.2S.

Basu, Arunabha (Aurora, IL); Meyer, Howard S. (Hoffman Estates, IL); Lynn, Scott (Pleasant Hill, CA); Leppin, Dennis (Chicago, IL); Wangerow, James R. (Medinah, IL)

2012-08-14T23:59:59.000Z

279

Nuclear safety procedure upgrade project at USEC/MMUS gaseous diffusion plants  

SciTech Connect

Martin Marietta Utility Services has embarked on a program to upgrade procedures at both of its Gaseous Diffusion Plant sites. The transition from a U.S. Department of Energy government-operated facility to U.S. Nuclear Regulatory Commission (NRC) regulated has necessitated a complete upgrade of plant operating procedures and practices incorporating human factors as well as a philosophy change in their use. This program is designed to meet the requirements of the newly written 10CFR76, {open_quotes}The Certification of Gaseous Diffusion Plants,{close_quotes} and aid in progression toward NRC certification. A procedures upgrade will help ensure increased nuclear safety, enhance plant operation, and eliminate personnel procedure errors/occurrences.

Kocsis, F.J. III

1994-12-31T23:59:59.000Z

280

Geology and hydrocarbon potentials of Arafura Sea  

Science Conference Proceedings (OSTI)

The Arafura Sea is a continental-shelf sea located between Irian Jaya (western New Guinea) and the northern part of the Australian continent. On the south it adjoins the stable Australian craton, and on the north it is bordered by the Tertiary collision zone between the Australian craton and the northern Irian Jaya island arc. On the west and northwest it is bounded by the active Banda arc collision zone, whereas on the east it is bordered by the northern extension of the Gulf of Carpentaria that also forms the western limit of the zone of late Paleozoic granites. Shelf sediments, ranging in age from late Paleozoic to Cenozoic, predominate in the Arafura Sea continental shelf, and are underlain by granitic basement. Gas shows have been reported from Jurassic to Cretaceous fine-grained marine limestones and sandstones, and gas and condensate also are present in Cretaceous sediments and Middle Jurassic fine-grained sandstones. At the north, the most prospective area seems to be the hinge zone of the Aru high, where a combination of traps and reservoir rocks presumably exists. On the south, the Money Shoal area is considered a significant prospect. In the Arafura basin, stratigraphic traps seem to be the most promising target for hydrocarbon exploration as tectonics seems not to have played an important role in the area. The sedimentary area occupied by the eastern extension of the Tarera-Aiduna wrench fault should also be investigated in detail for its hydrocarbon potential.

Katili, J.A.

1984-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Lubricant formulation for lower unburnt hydrocarbon emissions  

Science Conference Proceedings (OSTI)

Engine-out emissions of unburnt hydrocabons from spark ignition engines are attributable to a number of mechanisms, occurring during the engine cycle, by which fuel escapes combustion. These include absorption of fuel components into the bore lubricating oil film during compression, and subsequent desorption into hot combustion gases throughout expansion. A proportion of the hydrocarbons desorbed will then be emitted, either as unburnt or partially oxidised fuel. This mechanism has been studied by a number of workers, and estimates of its importance vary from 10 to 30% of total hydrocarbons being related to the absorption/desorption process. A novel lubricant additive has been formulated for the purpose of reducing the quantity of fuel which is absorbed into the bore lubricant film, and hence the quantity of fuel subsequently desorbed. This paper describes a programme to evaluate the effect that this lubricant additive can have on engine-out emissions from a single cylinder research engine, together with results from current technology, low-emitting US and European vehicles, tested over FTP and ECE drive cycles. 11 refs., 9 figs., 3 tabs.

Beckwith, P.; Cooper, J.H.

1994-10-01T23:59:59.000Z

282

D&D of the French High Enrichment Gaseous Diffusion Plant  

SciTech Connect

This paper describes the D&D program that is being implemented at France's High Enrichment Gaseous Diffusion Plant, which was designed to supply France's Military with Highly Enriched Uranium. This plant was definitively shut down in June 1996, following French President Jacques Chirac's decision to end production of Highly Enriched Uranium and dismantle the corresponding facilities.

BEHAR, Christophe; GUIBERTEAU, Philippe; DUPERRET, Bernard; TAUZIN, Claude

2003-02-27T23:59:59.000Z

283

Environmental Restoration Site-Specific Plan for the Paducah Gaseous Diffusion Plant, FY 93  

Science Conference Proceedings (OSTI)

This report provides an overview of the major Environmental Restoration (ER) concerns at Paducah Gaseous Diffusion Plant (PGDP). The identified solid waste management units at PGDP are listed. In the Department of Energy (DOE) Five Year Plan development process, one or more waste management units are addressed in a series of activity data sheets (ADSs) which identify planned scope, schedule, and cost objectives that are representative of the current state of planned technical development for individual or multiple sites.

Not Available

1993-01-15T23:59:59.000Z

284

Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption  

DOE Patents (OSTI)

Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high purity hydrogen from gaseous products of coal gasification and as an acid gas scrubber. 2 figs., 2 tabs.

Ghate, M.R.; Yang, R.T.

1985-10-03T23:59:59.000Z

285

Method and apparatus for the selective separation of gaseous coal gasification products by pressure swing adsorption  

DOE Patents (OSTI)

Bulk separation of the gaseous components of multi-component gases provided by the gasification of coal including hydrogen, carbon monoxide, methane, and acid gases (carbon dioxide plus hydrogen sulfide) are selectively adsorbed by a pressure swing adsorption technique using activated carbon, zeolite or a combination thereof as the adsorbent. By charging a column containing the adsorbent with a gas mixture and pressurizing the column to a pressure sufficient to cause the adsorption of the gases and then reducing the partial pressure of the contents of the column, the gases are selectively and sequentially desorbed. Hydrogen, the least absorbable gas of the gaseous mixture, is the first gas to be desorbed and is removed from the column in a co-current direction followed by the carbon monoxide, hydrogen and methane. With the pressure in the column reduced to about atmospheric pressure the column is evacuated in a countercurrent direction to remove the acid gases from the column. The present invention is particularly advantageous as a producer of high parity hydrogen from gaseous products of coal gasification and as an acid gas scrubber.

Ghate, Madhav R. (Morgantown, WV); Yang, Ralph T. (Williamsville, NY)

1987-01-01T23:59:59.000Z

286

Environmental effects of the construction and operation of a gaseous diffusion plant  

SciTech Connect

The impacts upon the environment resulting from construction, stert-up, and operation of a gaseous dfffusion plant are described. Some of the impacts are typical regardless of location of the plant. Others are atypical and depend upon location; those are presented, by way of example, as they occur at the Portsmouth Gaseous Diffusion Plant. The various environmental contaminants that may be produced in the operating plant are described. The concentrations of those contaminants are stated; and the adverse biological effects of pertinent conteminants are elucidated. UF/sup 6/ may be enriched in the Portsmouth Gaseous Wffusion Plant to almost any /sup 235/U concentration desired. The environmental impact of the plant varies somewhat according to /sup 235/U concentrations. However, commercial plants are not expected to enrich /sup 235/U in concentrations greater than 4%. for this reason, environmental effects due to Portsmouth operations within that range are emphasized. The study revealed that present discharges from the plants generally have no detrimental effects upon the environment. (auth)

1973-07-26T23:59:59.000Z

287

Oak Ridge National Lebroatory Liquid&Gaseous Waste Treatment System Strategic Plan  

SciTech Connect

Excellence in Laboratory operations is one of the three key goals of the Oak Ridge National Laboratory (ORNL) Agenda. That goal will be met through comprehensive upgrades of facilities and operational approaches over the next few years. Many of ORNL's physical facilities, including the liquid and gaseous waste collection and treatment systems, are quite old, and are reaching the end of their safe operating life. The condition of research facilities and supporting infrastructure, including the waste handling facilities, is a key environmental, safety and health (ES&H) concern. The existing infrastructure will add considerably to the overhead costs of research due to increased maintenance and operating costs as these facilities continue to age. The Liquid Gaseous Waste Treatment System (LGWTS) Reengineering Project is a UT-Battelle, LLC (UT-B) Operations Improvement Program (OIP) project that was undertaken to develop a plan for upgrading the ORNL liquid and gaseous waste systems to support ORNL's research mission.

Van Hoesen, S.D.

2003-09-09T23:59:59.000Z

288

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A process for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

1999-01-01T23:59:59.000Z

289

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A process for a combined selective thermal oxidation and photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly combined selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

2001-01-01T23:59:59.000Z

290

Selective thermal oxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A process for selective thermal oxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls is carried out in solvent free zeolites under dark thermal conditions. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts.

Frei, Heinz (Berkeley, CA); Blatter, Fritz (Basel, CH); Sun, Hai (Saint Charles, MO)

2000-01-01T23:59:59.000Z

291

Algal Lipid Extraction and Upgrading to Hydrocarbons Technology Pathway  

DOE Green Energy (OSTI)

This technology pathway case investigates the cultivation of algal biomass followed by further lipid extraction and upgrading to hydrocarbon biofuels. Technical barriers and key research needs have been assessed in order for the algal lipid extraction and upgrading pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

Davis, R.; Biddy, M.; Jones, S.

2013-03-01T23:59:59.000Z

292

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

DOE Green Energy (OSTI)

This technology pathway case investigates the biological conversion of biomass-derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot-scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks.

Davis, R.; Biddy, M.; Tan, E.; Tao, L.; Jones, S.

2013-03-01T23:59:59.000Z

293

Selective thermal and photooxidation of hydrocarbons in zeolites by oxygen  

DOE Patents (OSTI)

A process is described for selective thermal oxidation or photooxidation of hydrocarbons adsorbed onto zeolite matrices. A highly selective thermal oxidation and photooxidation of unsubstituted or alkyl substituted alkanes, alkenes, aromatics and cycloalkyls in solvent free zeolites under dark thermal conditions or under irradiation with visible light. The process oxidizes hydrocarbons almost completely selectively without substantial production of byproducts. 19 figs.

Frei, H.; Blatter, F.; Sun, H.

1999-06-22T23:59:59.000Z

294

The Use of New Parameterizations for Gaseous Absorption in the CLIRAD-SW Solar Radiation Code for Models  

Science Conference Proceedings (OSTI)

The new gaseous absorption parameterizations are incorporated in the CLIRAD-SW solar radiation code for models, openly distributed for the scientific community. In the new parameterizations, the magnitude of absorption coefficients in each ...

T. A. Tarasova; B. A. Fomin

2007-06-01T23:59:59.000Z

295

Joint Test Plan to Identify the Gaseous By-Products of CH3I Loading on AgZ  

SciTech Connect

The objective of this test plan is to describe research to determine the gaseous by-products of the adsorption of CH3I on hydrogen reduced silver exchanged mordenite (AgZ).

R. T. Jubin; N. R. Soelberg; D. M. Strachan; T. M. Nenoff; B. B. Spencer

2012-12-01T23:59:59.000Z

296

Geologic control of natural marine hydrocarbon seep emissions, Coal Oil Point seep field, California  

E-Print Network (OSTI)

Formation, the primary source of petroleum hydrocarbons inPetroleum Geologists, Tulsa Clark JF, Washburn L, Hornafius JS, Luyendyk BP (2000) Natural marine hydrocarbon seep source

Leifer, Ira; Kamerling, Marc J.; Luyendyk, Bruce P.; Wilson, Douglas S.

2010-01-01T23:59:59.000Z

297

The Spatial Scales, Distribution, and Intensity of Natural Marine Hydrocarbon Seeps near Coal Oil Point, California  

E-Print Network (OSTI)

marine hydrocarbon seeps (Coal Oil Point, Santa Barbara,marine hydrocarbon seepage near Coal Oil Point, California,associated with offshore oil production", Geology, 27(11),

Washburn, Libe; Clark, Jordan F.; Kyriakidis, Phaedon

2004-01-01T23:59:59.000Z

298

The Spatial Scales, Distribution, and Intensity of Natural Marine Hydrocarbon Seeps near Coal Oil Point, California  

E-Print Network (OSTI)

marine hydrocarbon seeps (Coal Oil Point, Santa Barbara,marine hydrocarbon seepage near Coal Oil Point, California,source areas such as near Coal Oil Point. Furthermore,

Washburn, Libe; Clark, Jordan F.; Kyriakidis, Phaedon

2004-01-01T23:59:59.000Z

299

Cogeneration systems and processes for treating hydrocarbon containing formations  

Science Conference Proceedings (OSTI)

A system for treating a hydrocarbon containing formation includes a steam and electricity cogeneration facility. At least one injection well is located in a first portion of the formation. The injection well provides steam from the steam and electricity cogeneration facility to the first portion of the formation. At least one production well is located in the first portion of the formation. The production well in the first portion produces first hydrocarbons. At least one electrical heater is located in a second portion of the formation. At least one of the electrical heaters is powered by electricity from the steam and electricity cogeneration facility. At least one production well is located in the second portion of the formation. The production well in the second portion produces second hydrocarbons. The steam and electricity cogeneration facility uses the first hydrocarbons and/or the second hydrocarbons to generate electricity.

Vinegar, Harold J. (Bellaire, TX); Fowler, Thomas David (Houston, TX); Karanikas, John Michael (Houston, TX)

2009-12-29T23:59:59.000Z

300

Heating hydrocarbon containing formations in a line drive staged process  

DOE Patents (OSTI)

Method for treating a hydrocarbon containing formation are described herein. Methods may include providing heat to a first section of the formation with one or more first heaters in the first section. First hydrocarbons may be heated in the first section such that at least some of the first hydrocarbons are mobilized. At least some of the mobilized first hydrocarbons may be produced through a production well located in a second section of the formation. The second section may be located substantially adjacent to the first section. A portion of the second section may be provided some heat from the mobilized first hydrocarbons, but is not conductively heated by heat from the first heaters. Heat may be provided to the second section with one or more second heaters in the second section to further heat the second section.

Miller, David Scott (Katy, TX)

2009-07-21T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Review of the Portsmouth Gaseous Diffusion Plant Integrated Safety Management System Phase I Verification Review, April 2013  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Portsmouth Gaseous Diffusion Plant Portsmouth Gaseous Diffusion Plant Integrated Safety Management System Phase I Verification Review April 2013 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose ................................................................................................................................................. 1 2.0 Scope.................................................................................................................................................... 1 3.0 Background........................................................................................................................................... 1 4.0 Methodology......................................................................................................................................... 1

302

Review of the Portsmouth Gaseous Diffusion Plant Integrated Safety Management System Phase I Verification Review, April 2013  

NLE Websites -- All DOE Office Websites (Extended Search)

Portsmouth Gaseous Diffusion Plant Portsmouth Gaseous Diffusion Plant Integrated Safety Management System Phase I Verification Review April 2013 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose ................................................................................................................................................. 1 2.0 Scope.................................................................................................................................................... 1 3.0 Background........................................................................................................................................... 1 4.0 Methodology......................................................................................................................................... 1

303

Gas separation process using membranes with permeate sweep to remove CO.sub.2 from gaseous fuel combustion exhaust  

DOE Patents (OSTI)

A gas separation process for treating exhaust gases from the combustion of gaseous fuels, and gaseous fuel combustion processes including such gas separation. The invention involves routing a first portion of the exhaust stream to a carbon dioxide capture step, while simultaneously flowing a second portion of the exhaust gas stream across the feed side of a membrane, flowing a sweep gas stream, usually air, across the permeate side, then passing the permeate/sweep gas back to the combustor.

Wijmans Johannes G. (Menlo Park, CA); Merkel, Timothy C. (Menlo Park, CA); Baker, Richard W. (Palo Alto, CA)

2012-05-15T23:59:59.000Z

304

MICROSTRUCTURE AND MECHANICAL PROPERTY PERFORMANCE OF COMMERCIAL GRADE API PIPELINE STEELS IN HIGH PRESSURE GASEOUS HYDROGEN  

Science Conference Proceedings (OSTI)

The continued growth of the world s developing countries has placed an ever increasing demand on traditional fossil fuel energy sources. This development has lead to increasing research and development of alternative energy sources. Hydrogen gas is one of the potential alternative energy sources under development. Currently the most economical method of transporting large quantities of hydrogen gas is through steel pipelines. It is well known that hydrogen embrittlement has the potential to degrade steel s mechanical properties when hydrogen migrates into the steel matrix. Consequently, the current pipeline infrastructure used in hydrogen transport is typically operated in a conservative fashion. This operational practice is not conducive to economical movement of significant volumes of hydrogen gas as an alternative to fossil fuels. The degradation of the mechanical properties of steels in hydrogen service is known to depend on the microstructure of the steel. Understanding the levels of mechanical property degradation of a given microstructure when exposed to hydrogen gas under pressure can be used to evaluate the suitability of the existing pipeline infrastructure for hydrogen service and guide alloy and microstructure design for new hydrogen pipeline infrastructure. To this end, the 2 Copyright 2010 by ASME microstructures of relevant steels and their mechanical properties in relevant gaseous hydrogen environments must be fully characterized to establish suitability for transporting hydrogen. A project to evaluate four commercially available pipeline steels alloy/microstructure performance in the presences of gaseous hydrogen has been funded by the US Department of Energy along with the private sector. The microstructures of four pipeline steels were characterized and then tensile testing was conducted in gaseous hydrogen and helium at pressures of 800, 1600 and 3000 psi. Based on measurements of reduction of area, two of the four steels that performed the best across the pressure range were selected for evaluation of fracture and fatigue performance in gaseous hydrogen at 800 and 3000 psi. This paper will describe the work performed on four commercially available pipeline steels in the presence of gaseous hydrogen at pressures relevant for transport in pipelines. Microstructures and mechanical property performances will be compared. In addition, recommendations for future work related to gaining a better understanding of steel pipeline performance in hydrogen service will be discussed.

Stalheim, Mr. Douglas [DGS Metallurgical Solutions Inc; Boggess, Todd [Secat; San Marchi, Chris [Sandia National Laboratories (SNL); Jansto, Steven [Reference Metals Company; Somerday, Dr. B [Sandia National Laboratories (SNL); Muralidharan, Govindarajan [ORNL; Sofronis, Prof. Petros [University of Illinois

2010-01-01T23:59:59.000Z

305

Stable isotope investigations of chlorinated aliphatic hydrocarbons.  

Science Conference Proceedings (OSTI)

Stable isotope ratio measurements for carbon (C) and chlorine (Cl) can be used to elucidate the processes affecting transformation and transportation of chlorinated aliphatic hydrocarbons (CAHs) in the environment. Methods recently developed in our laboratory for isotopic analysis of CAHs have been applied to laboratory measurements of the kinetic isotope effects associated with aerobic degradation of dichloromethane (DCM) and with both anaerobic and aerobic cometabolic degradation of trichlomethene (TCE) in batch and column microbial cultures. These experimental determinations of fractionation factors are crucial for understanding the behavior of CAHs in complex natural systems, where the extent of biotransformation can be masked by dispersion and volatilization. We have also performed laboratory investigations of kinetic isotope effects accompanying evaporation of CAHs, as well as field investigations of natural attenuation and in situ remediation of CAHs in a number of contaminated shallow aquifers at sites operated by the federal government and the private sector.

Abrajano, T.; Heraty, L. J.; Holt, B. D.; Huang, L.; Sturchio, N. C.

1999-06-01T23:59:59.000Z

306

Microbial hydrocarbons: back to the future  

Science Conference Proceedings (OSTI)

The defining challenge of energy research in the 21st century is the development and deployment of technologies for large-scale reconfiguration of global energy infrastructure. Modern society is built upon a concentrated yet finite reservoir of diverse hydrocarbons formed through the photosynthetic transformation of several hundred million years of solar energy. In human history, the fossil energy era will be short lived and never repeated. Although the timing of peak oil is extensively debated, it is an eventuality. It is, therefore, imperative that projections for both when it will occur and the degree to which supply will fall short of demand be taken into serious consideration, especially in the sectors of energy technology development, political and economic decision making, and societal energy usage. The requirement for renewable energy systems is no longer a point for discussion, and swift advances on many fronts are vital to counteract current and impending crises in both energy and the environment.

Work, Victoria H.; Beliaev, Alex S.; Konopka, Allan; Posewitz, Matthew C.

2012-03-01T23:59:59.000Z

307

Method and apparatus for synthesizing hydrocarbons  

DOE Patents (OSTI)

A method and apparatus for synthesizing a mixture of aliphatic alcohols having five carbons or less is disclosed. An equal molar ratio of CO and H/sub 2/ gases is caused to pass through a ThO/sub 2/ catalyst having a surface area of about 80 to 125 m/sup 2//g. The catalyst further optionally includes Na ions present as substitutional cations in an amount of about 5 to 10 atom %. At a temperature of about 570 to 630/sup 0/K, and at pressures of about 20 to 50 atm, methanol and isobutanol are the predominant products and are produced in amounts of about 90 wt % of the total hydrocarbon mixture. 6 figs.

Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

1985-04-16T23:59:59.000Z

308

Preignition oxidation characteristics of hydrocarbon fuels  

SciTech Connect

Experimental results obtained from a static reactor are presented for the oxidation of a variety of fuels. Pressure and temperature histories of the reacting fuel/oxidizer mixtures were obtained. Measurements of the stable reaction intermediate and product species were made using gas chromatographic analysis. One aspect of this work involved detailed studies of the oxidation chemistry of relatively low molecular weight aliphatic hydrocarbons: propane, propene, and n-butane. The oxidation chemistry of these fuels was examined at temperatures in the range 550-750 K, equivalence ratios ranging from 0.8 to 4.0 and at subatmospheric pressures. The main characteristics and features of the oxidation mechanisms were determined for each fuel in each temperature regime. The experimental results from propene and propane were used to develop a low and intermediate temperature kinetic mechanism for these fuels based on a low temperature acetaldehyde mechanism of Kaiser et al. and a high temperature propene/propane mechanism of Westbrook and Pitz. General preignition characteristics of higher molecular weight hydrocarbons and binary mixtures of these fuels were also studied. The low temperature/cool flame ignition characteristics of dodecane were investigated at temperatures in the range 523-623 K, equivalence s ranging from 0.8 to 1.0 and at subatmospheric pressures. The preignition characteristics of binary mixtures of dodecane and the aromatic component tetralin were examined. The addition of the tetralin had the overall effect of decreasing the ignition tendency of the mixture, although this effect was nonlinear with respect to the amount of tetralin added.

Wilk, R.D.

1986-01-01T23:59:59.000Z

309

Solubilization of petroleum hydrocarbons using biosurfactants  

E-Print Network (OSTI)

Low solubility of petroleum hydrocarbons in water is the major factor limiting the degradation rates of these compounds (Zhang and Miller, 1994). The fraction that is more soluble in the aqueous phase is degraded at higher rates, while less soluble or insoluble compounds have lower degradation rates due to limited bioavailability to the microbial community. A recent study in our lab found no significant degradation of weathered petroleum at a Texas petrochemical plant site. It was concluded that bioavailability of the crude oil to the microorganisms limited the degradation rates (Mills, 1994). Preliminary experiments at our laboratories have also indicated enhanced solubilities of petroleum hydrocarbons due to the effects of biosurfactants (Kanga et al., 1994). This research focused on biosurfactants because they have been shown to be as effective as chemical surfactants and, most importantly, they enhance biodegradation. Glycolipid biosurfactants are produced by Rhodococcus species HI 3-A to enhance substrate solubility and promote bioavailability for degradation. The work proceeded in two stages. The initial stage involved production and characterization of extracellular biosurfactants by HI 3-A when grown on minimal salts media with hexadecane as the carbon source. The second stage evaluated the performance of the biosurfactants in enhancing the aqueous solubility of weathered West Texas Crude. Initial results indicated production of the biosurfactants by Rhodococcus species H13-A during the stationary growth stage. Biosurfactants lowered the surface tension from 72 to-30 dynes/cm and interfacial tension to below 5 dynes/cm. The two-, three-, and four-ring aromatic compounds showed substantial increase in their aqueous phase concentrations in the presence of biosurfactants. The enhancement was more dramatic with the larger aromatics and also the highly substituted-compounds. Preliminary experiments on toxicity and biodegradation indicated higher levels of toxicity in the surfactant/aqueous mixtures due to increased PAH partitioning (Lambert, 1995), and increased degradation rates for the target PAH compounds.

Kanga, Shahrukh

1995-01-01T23:59:59.000Z

310

Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) Carbon Monoxide, Ozone, Hydrocarbon Air Quality Standards, and Related Emission Requirements (Ohio) < Back Eligibility Agricultural Commercial Construction Fuel Distributor Industrial Institutional Investor-Owned Utility Local Government Municipal/Public Utility Rural Electric Cooperative State/Provincial Govt Transportation Tribal Government Utility Savings Category Buying & Making Electricity Program Info State Ohio Program Type Environmental Regulations Provider Ohio Environmental Protection Agency This chapter defining the roles of the Ohio Environmental Protection Agency gives specific detail on the regulation point-source air pollution for a variety of industries and pollutants.

311

Thermal conversion of oil shale into recoverable hydrocarbons  

SciTech Connect

The production of hydrocarbons is accomplished by pyrolysis of oil shale with controlled removal of the resulting layer of spent oil-shale residue. A procedure is described for the in situ thermal conversion of oil shale wherein fluidized abrasive particles are employed to foster improved hydrocarbon production, in amount and kind, by a controlled partial removal of the layer of spent oil shale which results from application of flowing fluids to heat exposed surfaces of the oil shale to release hydrocarbons. (5 claims)

Slusser, M.L.; Bramhall, W.E.

1969-09-23T23:59:59.000Z

312

Analysis of the behavior of ternary hydrocarbon mixture as substitutes of the CFC-12  

Science Conference Proceedings (OSTI)

Hydrocarbons are stratospheric ozone friendly and have good heat transfer properties. The use of hydrocarbons (HCs) or their blend as refrigerant is extending in these days. This paper deals with the search of the best ternary hydrocarbons mixture of ... Keywords: CFC-12, LB-12, cub, hydrocarbon, ozone, refrigerant, ternary mixture

Rafael Quintero Ricardo

2007-05-01T23:59:59.000Z

313

Measuring the Effect of Fuel Chemical Structure on Particulate and Gaseous Emissions using Isotope Tracing  

DOE Green Energy (OSTI)

Using accelerator mass spectrometry (AMS), a technique initially developed for radiocarbon dating and recently applied to internal combustion engines, carbon atoms within specific fuel molecules can be labeled and followed in particulate or gaseous emissions. In addition to examining the effect of fuel chemical structure on emissions, the specific source of carbon for PM can be identified if an isotope label exists in the appropriate fuel source. Existing work has focused on diesel engines, but the samples (soot collected on quartz filters or combustion gases captured in bombs or bags) are readily collected from large industrial combustors as well.

Buchholz, B A; Mueller, C J; Martin, G C; Upatnicks, A; Dibble, R W; Cheng, S

2003-09-11T23:59:59.000Z

314

Replacement of chlorofluorocarbons (CFCs) at the DOE gaseous diffusion plants: An assessment of global impacts  

SciTech Connect

The US Department of Energy (DOE) formerly operated two gaseous diffusion plants (GDPs) for enriching uranium and maintained a third shutdown GDP. These plants maintain a large inventory of dichlorotetrafluorethane (CFC-114), a cholorofluorocarbon (CFC), as a coolant. The paper evaluates the global impacts of four alternatives to modify GDP coolant system operations for a three-year period beginning in 1996. Interim modification of GDP coolant system operations has the potential to reduce stratospheric ozone depletion from GDP coolant releases while a permanent solution is studied.

Socolof, M.L.; Saylor, R.E.; McCold, L.N.

1994-06-01T23:59:59.000Z

315

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents (OSTI)

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1984-06-19T23:59:59.000Z

316

(2) Quantities and Prices of Animal Manure and Gaseous Fuels Generated:  

E-Print Network (OSTI)

In this context, we are defining animal manure as the excrement of livestock reared in agricultural operations as well as straw, sawdust, and other residues used as animal bedding. Gaseous fuels may be derived from municipal and industrial landfills (landfill gas) or from animal manure and solid biomass such as crop silage or the organic fraction of MSW (biogas). Both landfill gas and biogas are generated via anaerobic digestion, a multi-stage process whereby bacteria convert carbohydrates, fats, and proteins to methane (Evans 2001). EPA does not consider these materials to be wastes in themselves, when used as fuel, but rather materials derived from wastes.

unknown authors

2010-01-01T23:59:59.000Z

317

Liquefied Gaseous Fuels Safety and Environmental Control Assessment Program: second status report  

SciTech Connect

This document is arranged in three volumes and reports on progress in the Liquefied Gaseous Fuels (LGF) Safety and Environmental Control Assessment Program made in fiscal Year (FY)-1979 and early FY-1980. Volume 3 contains reports from 6 government contractors on LPG, anhydrous ammonia, and hydrogen energy systems. Report subjects include: simultaneous boiling and spreading of liquefied petroleum gas (LPG) on water; LPG safety research; state-of-the-art of release prevention and control technology in the LPG industry; ammonia: an introductory assessment of safety and environmental control information; ammonia as a fuel, and hydrogen safety and environmental control assessment.

1980-10-01T23:59:59.000Z

318

2013 GASEOUS IONS GORDON RESEARCH CONFERENCE, FEBRUARY 24 - MARCH 1, 2013  

Science Conference Proceedings (OSTI)

The Gaseous Ions: Structures, Energetics and Reactions Gordon Research Conference will focus on ions and their interactions with molecules, surfaces, electrons, and light. The long-standing goal of our community is to develop new strategies for capturing complex molecular architectures as gas phase ions where they can be isolated, characterized and manipulated with great sensitivity. Emergent areas of interest include catalytic mechanisms, cryogenic processing of ions extracted from solution, ion fragmentation mechanisms, and new methods for ion formation and structural characterization. The conference will cover theoretical and experimental advances on systems ranging from model studies at the molecular scale to preparation of nanomaterials and characterization of large biological molecules.

Williams, Evan

2013-03-01T23:59:59.000Z

319

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents (OSTI)

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

1984-01-01T23:59:59.000Z

320

Linking the gaseous and the condensed phases of matter: The slow electron and its interactions  

SciTech Connect

The interfacing of the gaseous and the condensed phases of matter as effected by interphase and cluster studies on the behavior of key reactions involving slow electrons either as reacting initial particles or as products of the reactions themselves is discussed. Emphasis is placed on the measurement of both the cross sections and the energetics involved, although most of the available information to date is on the latter. The discussion is selectively focussed on electron scattering (especially the role of negative ion states in gases, clusters, and dense matter), ionization, electron attachment and photodetachment. The dominant role of the electric polarization of the medium is emphasized.

Christophorou, L.G.

1993-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream  

DOE Patents (OSTI)

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced. 3 figs.

Kansa, E.J.; Anderson, B.L.; Wijesinghe, A.M.; Viani, B.E.

1999-05-25T23:59:59.000Z

322

Separation of toxic metal ions, hydrophilic hydrocarbons, hydrophobic fuel and halogenated hydrocarbons and recovery of ethanol from a process stream  

DOE Patents (OSTI)

This invention provides a process to tremendously reduce the bulk volume of contaminants obtained from an effluent stream produced subsurface remediation. The chemicals used for the subsurface remediation are reclaimed for recycling to the remediation process. Additional reductions in contaminant bulk volume are achieved by the ultra-violet light destruction of halogenated hydrocarbons, and the complete oxidation of hydrophobic fuel hydrocarbons and hydrophilic hydrocarbons. The contaminated bulk volume will arise primarily from the disposal of the toxic metal ions. The entire process is modular, so if there are any technological breakthroughs in one or more of the component process modules, such modules can be readily replaced.

Kansa, Edward J. (Livermore, CA); Anderson, Brian L. (Lodi, CA); Wijesinghe, Ananda M. (Tracy, CA); Viani, Brian E. (Oakland, CA)

1999-01-01T23:59:59.000Z

323

Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

storage of natural gas, liquid hydrocarbons, and carbon storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) Underground storage of natural gas, liquid hydrocarbons, and carbon dioxide (Louisiana) < Back Eligibility Commercial Construction Industrial Investor-Owned Utility Municipal/Public Utility Utility Program Info State Louisiana Program Type Environmental Regulations Siting and Permitting The Louisiana Department of Environmental Quality regulates the underground storage of natural gas or liquid hydrocarbons and carbon dioxide. Prior to the use of any underground reservoir for the storage of natural gas and prior to the exercise of eminent domain by any person, firm, or corporation having such right under laws of the state of Louisiana, the commissioner, shall have found all of the following:

324

Process for conversion of lignin to reformulated hydrocarbon gasoline  

DOE Patents (OSTI)

A process for converting lignin into high-quality reformulated hydrocarbon gasoline compositions in high yields is disclosed. The process is a two-stage, catalytic reaction process that produces a reformulated hydrocarbon gasoline product with a controlled amount of aromatics. In the first stage, a lignin material is subjected to a base-catalyzed depolymerization reaction in the presence of a supercritical alcohol as a reaction medium, to thereby produce a depolymerized lignin product. In the second stage, the depolymerized lignin product is subjected to a sequential two-step hydroprocessing reaction to produce a reformulated hydrocarbon gasoline product. In the first hydroprocessing step, the depolymerized lignin is contacted with a hydrodeoxygenation catalyst to produce a hydrodeoxygenated intermediate product. In the second hydroprocessing step, the hydrodeoxygenated intermediate product is contacted with a hydrocracking/ring hydrogenation catalyst to produce the reformulated hydrocarbon gasoline product which includes various desirable naphthenic and paraffinic compounds.

Shabtai, Joseph S. (Salt Lake City, UT); Zmierczak, Wlodzimierz W. (Salt Lake City, UT); Chornet, Esteban (Golden, CO)

1999-09-28T23:59:59.000Z

325

Determination of Total Petroleum Hydrocarbons (TPH) Using Total Carbon Analysis  

SciTech Connect

Several methods have been proposed to replace the Freon(TM)-extraction method to determine total petroleum hydrocarbon (TPH) content. For reasons of cost, sensitivity, precision, or simplicity, none of the replacement methods are feasible for analysis of radioactive samples at our facility. We have developed a method to measure total petroleum hydrocarbon content in aqueous sample matrixes using total organic carbon (total carbon) determination. The total carbon content (TC1) of the sample is measured using a total organic carbon analyzer. The sample is then contacted with a small volume of non-pokar solvent to extract the total petroleum hydrocarbons. The total carbon content of the resultant aqueous phase of the extracted sample (TC2) is measured. Total petroleum hydrocarbon content is calculated (TPH = TC1-TC2). The resultant data are consistent with results obtained using Freon(TM) extraction followed by infrared absorbance.

Ekechukwu, A.A.

2002-05-10T23:59:59.000Z

326

Mathematical modeling of solid oxide fuel cells using hydrocarbon fuels  

E-Print Network (OSTI)

Solid oxide fuel cells (SOFCs) are high efficiency conversion devices that use hydrogen or light hydrocarbon (HC) fuels in stationary applications to produce quiet and clean power. While successful, HC-fueled SOFCs face ...

Lee, Won Yong, Ph. D. Massachusetts Institute of Technology

2012-01-01T23:59:59.000Z

327

Trend Analysis for Atmospheric Hydrocarbon Partitioning Using Continuous Thermodynamics  

Science Conference Proceedings (OSTI)

The partitioning of atmospheric hydrocarbons into vapor and condensed phases when the species count is large is considered using the formalism of continuous thermodynamics. The vapor saturation pressures and condensate species distribution are ...

K. Harstad

2005-08-01T23:59:59.000Z

328

Biodegradation and phytoremediation of polycyclic aromatic hydrocarbons using mushroom compost.  

E-Print Network (OSTI)

??Soils contaminated with Polycyclic Aromatic Hydrocarbons (PAHs) are commonly found in petroleum, gas-work and wood-impregnation sites. Interest in the biodegradation and environmental fate of PAHs (more)

Kodjo-Wayo, Lina Korkor

2006-01-01T23:59:59.000Z

329

Assessment of plant-derived hydrocarbons. Final report  

DOE Green Energy (OSTI)

A number of hydrocarbon producing plants are evaluated as possible sources of rubber, liquid fuels, and industrial lubricants. The plants considered are Euphorbia lathyris or gopher plant, milkweeds, guayule, rabbit brush, jojoba, and meadow foam. (ACR)

McFadden, K.; Nelson, S.H.

1981-09-30T23:59:59.000Z

330

Computer program for determining the thermodynamic properties of light hydrocarbons  

DOE Green Energy (OSTI)

This program was written to be used as a subroutine. The program determines the thermodynamics of light hydrocarbons. The following light hydrocarbons can be analyzed: butane, ethane, ethylene, heptane, hexane, isobutane, isopentane, methane, octane, pentane, propane and propylene. The subroutine can evaluate a thermodynamic state for the light hydrocarbons given any of the following pairs of state quantities: pressure and quality, pressure and enthalpy, pressure and entropy, temperature and pressure, temperature and quality and temperature and specific volume. These six pairs of knowns allow the user to analyze any thermodynamic cycle utilizing a light hydrocarbon as the working fluid. The Starling--Benedict--Webb--Rubin equation of state was used. A brief description, flowchart, listing and required equations for each subroutine are included.

Riemer, D.H.; Jacobs, H.R.; Boehm, R.F.; Cook, D.S.

1976-01-01T23:59:59.000Z

331

Computer program for determining the thermodynamic properties of light hydrocarbons  

DOE Green Energy (OSTI)

This program was written to be used as a subroutine. The program determines the thermodynamics of light hydrocarbons. The following light hydrocarbons can be analyzed: butane, ethane, ethylene, heptane, hexane, isobutane, isopentane, methane, octane, pentane, propane and propylene. The subroutine can evaluate a thermodynamic state for the light hydrocarbons given any of the following pairs of state quantities: pressure and quality, pressure and enthalpy, pressure and entropy, temperature and pressure, temperature and quality and temperature and specific volume. These six pairs of knowns allow the user to analyze any thermodynamic cycle utilizing a light hydrocarbon as the working fluid. The Starling-Benedict-Webb-Rubin equation of state was used. This report contains a brief description, flowchart, listing and required equations for each subroutine.

Riemer, D.H.; Jacobs, H.R.; Boehm, R.F.; Cook, D.S.

1976-07-01T23:59:59.000Z

332

Conversion of Pentose-Derived Furans into Hydrocarbon Fuels  

Science Conference Proceedings (OSTI)

We are interested in the conversion of biomass-derived hemicellulose into hydrocarbon molecules that can be used in the formulation of 'drop-in' fuels such as gasoline (C5-12), diesel (C10-20) and jet fuel (C9-16). Our focus lies on the use of furfuryl alcohol as a starting material since that is already produced commercially from hemicellulose-derived pentoses. The steps required to convert the latter into hydrocarbons are 1) oligomerization of furfuryl alcohol to form dimers (C10) and trimers (C15), and 2) hydrotreatment of the dimers and trimers to produce a mixture of linear hydrocarbons with carbon chain lengths in the range of diesel and jet fuels. However, furfuryl alcohol readily polymerizes to form resins in the presence of an acid catalyst, and the exothermic oligomerization must be carried out under reaction control. This presentation will discuss our progress in the development of this sugar-to-hydrocarbon pathway.

Moens, L.; Johnson, D. K.

2012-01-01T23:59:59.000Z

333

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway  

DOE Green Energy (OSTI)

This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline-, diesel-, and jet-range hydrocarbon blendstocks have been identified.

Biddy, M.; Jones, S.

2013-03-01T23:59:59.000Z

334

Hydrocarbon-enhanced particulate filter regeneration via microwave ignition  

DOE Patents (OSTI)

A regeneration method for a particulate filter includes estimating a quantity of particulate matter trapped within the particulate filter, comparing the quantity of particulate matter to a predetermined quantity, heating at least a portion of the particulate filter to a combustion temperature of the particulate matter, and introducing hydrocarbon fuel to the particulate filter. The hydrocarbon fuel facilitates combustion of the particulate matter to regenerate the particulate filter.

Gonze, Eugene V. (Pinckney, MI); Brown, David B. (Brighton, MI)

2010-02-02T23:59:59.000Z

335

Cooling and solidification of heavy hydrocarbon liquid streams  

DOE Patents (OSTI)

A process and apparatus for cooling and solidifying a stream of heavy hydrocarbon material normally boiling above about 850.degree. F., such as vacuum bottoms material from a coal liquefaction process. The hydrocarbon stream is dropped into a liquid bath, preferably water, which contains a screw conveyor device and the stream is rapidly cooled, solidified and broken therein to form discrete elongated particles. The solid extrudates or prills are then dried separately to remove substantially all surface moisture, and passed to further usage.

Antieri, Salvatore J. (Trenton, NJ); Comolli, Alfred G. (Yardley, PA)

1983-01-01T23:59:59.000Z

336

Method for producing hydrocarbon fuels from heavy polynuclear hydrocarbons by use of molten metal halide catalyst  

DOE Patents (OSTI)

In a process for hydrocracking heavy polynuclear carbonaceous feedstocks to produce lighter hydrocarbon fuels by contacting the heavy feedstocks with hydrogen in the presence of a molten metal halide catalyst, thereafter separating at least a substantial portion of the carbonaceous material associated with the reaction mixture from the spent molten metal halide and thereafter regenerating the metal halide catalyst, an improvement comprising contacting the spent molten metal halide catalyst after removal of a major portion of the carbonaceous material therefrom with an additional quantity of hydrogen is disclosed.

Gorin, Everett (San Rafael, CA)

1979-01-01T23:59:59.000Z

337

Catalytic partial oxidation reforming of hydrocarbon fuels.  

DOE Green Energy (OSTI)

The polymer electrolyte fuel cell (PEFC) is the primary candidate as the power source for light-duty transportation systems. On-board conversion of fuels (reforming) to supply the required hydrogen has the potential to provide the driving range that is typical of today's automobiles. Petroleum-derived fuels, gasoline or some distillate similar to it, are attractive because of their existing production, distribution, and retailing infrastructure. The fuel may be either petroleum-derived or other alternative fuels such as methanol, ethanol, natural gas, etc. [1]. The ability to use a variety of fuels is also attractive for stationary distributed power generation [2], such as in buildings, or for portable power in remote locations. Argonne National Laboratory has developed a catalytic reactor based on partial oxidation reforming that is suitable for use in light-duty vehicles powered by fuel cells. The reactor has shown the ability to convert a wide variety of fuels to a hydrogen-rich gas at less than 800 C, temperatures that are several hundreds of degrees lower than alternative noncatalytic processes. The fuel may be methanol, ethanol, natural gas, or petroleum-derived fuels that are blends of various hydrocarbons such as paraffins, olefins, aromatics, etc., as in gasoline. This paper will discuss the results obtained from a bench-scale (3-kWe) reactor., where the reforming of gasoline and natural gas generated a product gas that contained 38% and 42% hydrogen on a dry basis at the reformer exit, respectively.

Ahmed, S.

1998-09-21T23:59:59.000Z

338

Heat-pipe effect on the transport of gaseous radionuclides released from a nuclear waste container  

SciTech Connect

When an unsaturated porous medium is subjected to a temperature gradient and the temperature is sufficiently high, vadose water is heated and vaporizes. Vapor flows under its pressure gradient towards colder regions where it condenses. Vaporization and condensation produce a liquid saturation gradient, creating a capillary pressure gradient inside the porous medium. Condensate flows towards the hot end under the influence of a capillary pressure gradient. This is a heat pipe in an unsaturated porous medium. We study analytically the transport of gaseous species released from a spent-fuel waste package, as affected by a time-dependent heat pipe in an unsaturated rock. For parameter values typical of a potential repository in partially saturated fractured tuff at Yucca Mountain, we found that a heat pipe develops shortly after waste is buried, and the heat-pipe`s spatial extent is time-dependent. Water vapor movements produced by the heat pipe can significantly affect the migration of gaseous radionuclides. 12 refs., 6 figs., 1 tab.

Zhou, W.; Chambre, P.L.; Pigford, T.H.; Lee, W.W.L.

1990-11-01T23:59:59.000Z

339

Project plan for the background soils project for the Paducah Gaseous Diffusion Plant, Paducah, Kentucky  

SciTech Connect

The Background Soils Project for the Paducah Gaseous Diffusion Plant (BSPP) will determine the background concentration levels of selected naturally occurring metals, other inorganics, and radionuclides in soils from uncontaminated areas in proximity to the Paducah Gaseous Diffusion Plant (PGDP) in Paducah, Kentucky. The data will be used for comparison with characterization and compliance data for soils, with significant differences being indicative of contamination. All data collected as part of this project will be in addition to other background databases established for the PGDP. The BSPP will address the variability of surface and near-surface concentration levels with respect to (1) soil taxonomical types (series) and (2) soil sampling depths within a specific soil profile. The BSPP will also address the variability of concentration levels in deeper geologic formations by collecting samples of geologic materials. The BSPP will establish a database, with recommendations on how to use the data for contaminated site assessment, and provide data to estimate the potential human and health and ecological risk associated with background level concentrations of potentially hazardous constituents. BSPP data will be used or applied as follows.

NONE

1995-09-01T23:59:59.000Z

340

The Radiochemical Analysis of Gaseous Samples (RAGS) Apparatus for Nuclear Diagnostics at the National Ignition Facility  

SciTech Connect

The RAGS (Radiochemical Analysis of Gaseous Samples) diagnostic apparatus was recently installed at the National Ignition Facility. Following a NIF shot, RAGS is used to pump the gas load from the NIF chamber for purification and isolation of the noble gases. After collection, the activated gaseous species are counted via gamma spectroscopy for measurement of the capsule areal density and fuel-ablator mix. Collection efficiency was determined by injecting a known amount of {sup 135}Xe into the NIF chamber, which was then collected with RAGS. Commissioning was performed with an exploding pusher capsule filled with isotopically enriched {sup 124}Xe and {sup 126}Xe added to the DT gas fill. Activated xenon species were recovered post-shot and counted via gamma spectroscopy. Results from the collection and commissioning tests are presented. The performance of RAGS allows us to establish a noble gas collection method for measurement of noble gas species produced via neutron and charged particle reactions in a NIF capsule.

Shaughnessy, D A; Velsko, C A; Jedlovec, D R; Yeamans, C B; Moody, K J; Tereshatov, E; Stoeffl, W; Riddle, A

2012-05-11T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Anisotropic gaseous models of tidally limited star clusters -- comparison with other methods  

E-Print Network (OSTI)

We present new models of the evolution and dissolution of star clusters evolving under the combined influence of internal relaxation and external tidal fields, using the anisotropic gaseous model based on the Fokker-Planck approximation, and a new escaper loss cone model. This model borrows ideas from loss cones of stellar distributions near massive black holes, and describes physical processes related to escaping stars by a simple model based on two timescales and a diffusion process. We compare our results with those of direct $N$-body models and of direct numerical solutions of the orbit-averaged Fokker-Planck equation. For this comparative study we limit ourselves to idealized single point mass star clusters, in order to present a detailed study of the physical processes determining the rate of mass loss, core collapse and other features of the system's evolution. With the positive results of our study the path is now open in the future to use the computationally efficient gaseous models for future studies with more realism (mass spectrum, stellar evolution).

R. Spurzem; M. Giersz; K. Takahashi; A. Ernst

2004-12-30T23:59:59.000Z

342

Liquefied Gaseous Fuels Safety and Environmental Control Assessment Program: second status report  

DOE Green Energy (OSTI)

The Assistant Secretary for Environment has responsibility for identifying, characterizing, and ameliorating the environmental, health, and safety issues and public concerns associated with commercial operation of specific energy systems. The need for developing a safety and environmental control assessment for liquefied gaseous fuels was identified by the Environmental and Safety Engineering Division as a result of discussions with various governmental, industry, and academic persons having expertise with respect to the particular materials involved: liquefied natural gas, liquefied petroleum gas, hydrogen, and anhydrous ammonia. This document is arranged in three volumes and reports on progress in the Liquefied Gaseous Fuels (LGF) Safety and Environmental Control Assessment Program made in Fiscal Year (FY)-1979 and early FY-1980. Volume 1 (Executive Summary) describes the background, purpose and organization of the LGF Program and contains summaries of the 25 reports presented in Volumes 2 and 3. Annotated bibliographies on Liquefied Natural Gas (LNG) Safety and Environmental Control Research and on Fire Safety and Hazards of Liquefied Petroleum Gas (LPG) are included in Volume 1.

Not Available

1980-10-01T23:59:59.000Z

343

Mixture of micronized coal powder with gaseous fuels for use in internal combustion engines  

DOE Patents (OSTI)

An improved fuel mixture for use in internal combustion engines is described. This fuel is an intimate mixture of micronized coal, having an average particle size of less than 100 microns, with a gaseous fuel selected from natural gas and coal-derived. The coal can be present from more than 0 percent to less than 100 percent, with generally the lower percentages being preferred. The addition of the coal to the gaseous fuel improves engine efficiency and power rating, and also decreases peak engine pressure allowing for higher compression ratios. An increase in the amount of the coal increases the oxides of sulfur while reducing the oxides of nitrogen in the exhaust. An increase in the amount of gas, on the other hand, increases the oxides of nitrogen but lowers oxides of sulfur. Accordingly, a preferred mixture will depend upon a particular application for the coal/gas fuel and thereby increases user fuel flexibility considerations. Modeling of the fuel mixture for use in a diesel engine is described. 3 figs., 3 tabs.

Carpenter, L.K.

1990-01-03T23:59:59.000Z

344

Indirect NMR detection of 235U in gaseous uranium hexafluoride National Center for Physics, P.O. Box MG-6, Bucharest, Romania  

E-Print Network (OSTI)

L-493 Indirect NMR detection of 235U in gaseous uranium hexafluoride I. Ursu National Center- vation of235 U NMR signal in liquid UF6 at B = 11.747 T has been recently reported [7]. The aim of this Letter is to investigate the effect of the 23 5U enrichment on the 19F NMR spectra in gaseous UF6. Using

Paris-Sud XI, Université de

345

Review of current research on hydrocarbon production by plants  

DOE Green Energy (OSTI)

This review assesses the status of research and development in the area of plants that produce hydrocarbons as a possible replacement for traditional fossil fuels. The information is meant to be used as a basis for determining the scope of a possible R and D program by DOE/FFB. Except in the case of guayule (Parthenium argentatum Gray), research on hydrocarbon species generally has not advanced beyond preliminary screening, extraction, and growth studies. Virtually no field studies have been initiated; hydrocarbon component extraction, separation, identification, and characterization have been only timidly approached; the biochemistry of hydrocarbon formation remains virtually untouched; and potential market analysis has been based on insufficient data. Research interest is increasing in this area, however. Industrial interest understandably centers about guayule prospects and is supplemented by NSF and DOE research funds. Additional support for other research topics has been supplied by DOE and USDA and by certain university systems. Due to the infant state of technology in this area of energy research, it is not possible to predict or satisfactorily assess at this time the potential contribution that plant hydrocarbons might make toward decreasing the nation's dependence upon petroleum. However, the general impression received from experts interviewed during this review was that the major thrust of research should be directed toward the manufacture of petrochemical substitutes rather than fuel production.

Benedict, H. M.; Inman, B.

1979-01-01T23:59:59.000Z

346

Methane-derived hydrocarbons produced under upper-mantle conditions  

SciTech Connect

There is widespread evidence that petroleum originates from biological processes. Whether hydrocarbons can also be produced from abiogenic precursor molecules under the high-pressure, high-temperature conditions characteristic of the upper mantle remains an open question. It has been proposed that hydrocarbons generated in the upper mantle could be transported through deep faults to shallower regions in the Earth's crust, and contribute to petroleum reserves. Here we use in situ Raman spectroscopy in laser-heated diamond anvil cells to monitor the chemical reactivity of methane and ethane under upper-mantle conditions. We show that when methane is exposed to pressures higher than 2 GPa, and to temperatures in the range of 1,000-1,500 K, it partially reacts to form saturated hydrocarbons containing 2-4 carbons (ethane, propane and butane) and molecular hydrogen and graphite. Conversely, exposure of ethane to similar conditions results in the production of methane, suggesting that the synthesis of saturated hydrocarbons is reversible. Our results support the suggestion that hydrocarbons heavier than methane can be produced by abiogenic processes in the upper mantle.

Kolesnikov, Anton; Kutcherov, Vladimir G.; Goncharov, Alexander F.; (CIW); (RITS)

2009-08-13T23:59:59.000Z

347

Apparatus and method for operating internal combustion engines from variable mixtures of gaseous fuels  

DOE Patents (OSTI)

An apparatus and method for utilizing any arbitrary mixture ratio of multiple fuel gases having differing combustion characteristics, such as natural gas and hydrogen gas, within an internal combustion engine. The gaseous fuel composition ratio is first sensed, such as by thermal conductivity, infrared signature, sound propagation speed, or equivalent mixture differentiation mechanisms and combinations thereof which are utilized as input(s) to a "multiple map" engine control module which modulates selected operating parameters of the engine, such as fuel injection and ignition timing, in response to the proportions of fuel gases available so that the engine operates correctly and at high efficiency irrespective of the gas mixture ratio being utilized. As a result, an engine configured according to the teachings of the present invention may be fueled from at least two different fuel sources without admixing constraints.

Heffel, James W. (Lake Matthews, CA); Scott, Paul B. (Northridge, CA); Park, Chan Seung (Yorba Linda, CA)

2011-11-01T23:59:59.000Z

348

Proposed On-Site Disposal Facility (OSDF) at the Paducah Gaseous Diffusion Plant  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

i i TABLE OF CONTENTS 1. INTRODUCTION 1 2. LINE OF INQUIRY NO. 1 - Future Uses of the Subtitle D Landfill 2 3. LINE OF INQUIRY NO. 2 - OSDF Siting in a Brownfield Area 3 4. LINE OF INQUIRY NO. 3 - Seismic Issues 4 5. LINE OF INQUIRY NO. 4 - Post-Closure Public Use of the OSDF 5 6. LINE OF INQUIRY NO. 5 - Public Communication Plan 7 7. LINE OF INQUIRY NO. 6 - Baseline Schedule 8 8. RECOMMENDATIONS 8 9. ACKNOWLEDGEMENT 10 10. REFERENCES 10 APPENDIX 11 1 1. INTRODUCTION The Paducah Gaseous Diffusion Plant (PGDP) is an active uranium enrichment facility that is owned by the US Department of Energy (DOE). Uranium enrichment facilities at PGDP are leased to and operated by the United States Enrichment Corporation. In 1994, PGDP was placed

349

Lessons Learned from Practical Field Experience with High Pressure Gaseous Fuels  

NLE Websites -- All DOE Office Websites (Extended Search)

5/2010 5/2010 www.cleanvehicle.org 1 Lessons Learned from Practical Field Experience with High Pressure Gaseous Fuels DOE - DOT CNG - H 2 Workshop December 10, 2009 Douglas Horne, PE - CVEF President Rob Adams, P.Eng. - Marathon Technical Services The Facts  NGVs have been used in North America for over 30 years  Codes and Standards (C&S) provide opportunity for safe reliable operation of NGVs  C&S evolve with new technology and field experience  People make mistakes, continuous training is critical for safe operations  Cylinders have a limited life -track your cylinders! 2/25/2010 www.cleanvehicle.org 2 Incidents in North America  Since 1984 CVEF has recorded 97 incidents of which 67 involved CNG vehicles - 37 incidents involve either a CNG leak (15) or a

350

Assessment of methods for analyzing gaseous mixtures of hydrogen isotopes and helium  

DOE Green Energy (OSTI)

Mass spectrographic methods have served well in the past to analyze gaseous mixtures of the hydrogen isotopes. Alternate methods of analyses are reviewed which offer wider ranges and variety of isotopic determinations. This report describes possible improvements of the mass spectrographic determinations, gas chromatography, anti-Stokes Raman spectroscopy, microwave-induced optical emission spectroscopy, and methods of measuring tritium using radiation detection devices. Precision, accuracy, limitations, and costs are included for some of the methods mentioned. Costs range from $70,000 for the anti-Stokes Raman spectroscopy equipment, which can determine hydrogen isotopes but not helium, to less than $10,000 for the gas chromatographic equipment, which can determine hydrogen isotopes and helium with precision and accuracy comparable to those of the mass spectrometer.

Attalla, A.; Bishop, C.T.; Bohl, D.R.; Buxton, T.L.; Sprague, R.E.; Warner, D.K.

1976-10-20T23:59:59.000Z

351

Preliminary assessment of the gaseous fuels aftermarket conversion industry. Final report  

Science Conference Proceedings (OSTI)

The purpose of the report is to provide information to be used in assessing the potential impacts of EPA's proposed Gaseous Fuels and Clean Fuel Fleet rulemakings on the aftermarket conversion industry. Therefore, the report will focus on issues germane to determining these impacts (such as financial profiles of companies involved, future trends in industry development and sales, and costs of complying with conversion requirements) rather than assessing the viability of current technologies or the emissions benefits of alternative fuels. Moreover, the report focuses on conversions to CNG and LPG as conversions to these fuels are most viable at this time, even though EPA's proposed conversion regulations could potentially apply to any fuel (e.g., liquid natural gas).

Not Available

1992-09-28T23:59:59.000Z

352

Method and apparatus for removal of gaseous, liquid and particulate contaminants from molten metals  

DOE Patents (OSTI)

Method and apparatus for removal of nonelectrically-conducting gaseous, liquid, and particulate contaminants from molten metal compositions by applying a force thereto. The force (commonly referred to as the Lorentz Force) exerted by simultaneous application of an electric field and a magnetic field on a molten conductor causes an increase, in the same direction as the force, in the apparent specific gravity thereof, but does not affect the nonconducting materials. This difference in apparent densities cause the nonconducting materials to "float" in the opposite direction from the Lorentz Force at a rapid rate. Means are further provided for removal of the contaminants and prevention of stirring due to rotational forces generated by the applied fields.

Hobson, David O. (Oak Ridge, TN); Alexeff, Igor (Oak Ridge, TN); Sikka, Vinod K. (Clinton, TN)

1988-01-01T23:59:59.000Z

353

Report on the biological monitoring program at Paducah Gaseous Diffusion Plant December 1990 to November 1992  

Science Conference Proceedings (OSTI)

On September 23, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous Diffusion Plant (PGDP). Beginning in fall 1991, the Environmental Sciences Division (ESD) at Oak Ridge National Lab (ORNL) added data collection and report preparation to its responsibilities for the PGDP BMP. The BMP has been continued because it has proven to be extremely valuable in identifying those effluents with the potential for adversely affecting instream fauna, assessing the ecological health of receiving streams, guiding plans for remediation, and protecting human health. In September 1992, a renewed permit was issued which requires toxicity monitoring of continuous and intermittent outfalls on a quarterly basis. The BMP for PGDP consists of three major tasks: (1) effluent and ambient toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of stream communities. This report includes ESD/ORNL activities occurring from December 1990 to November 1992.

Kszos, L.A. [ed.

1994-03-01T23:59:59.000Z

354

Report on the Biological Monitoring Program at Paducah Gaseous Diffusion Plant December 1992--December 1993  

SciTech Connect

On September 24, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous Diffusion Plant (PGDP). The goals of BMP are to demonstrate that the effluent limitations established for PGDP protect and maintain the use of Little Bayou and Big Bayou creeks for growth and propagation of fish and other aquatic life, characterize potential health and environmental impacts, document the effects of pollution abatement facilities on stream biota, and recommend any program improvements that would increase effluent treatability. The BMP for PGDP consists of three major tasks: effluent and ambient toxicity monitoring, bioaccumulation studies, and ecological surveys of stream communities (i.e., benthic macroinvertebrates and fish). This report includes ESD activities occurring from December 1992 to December 1993, although activities conducted outside this time period are included as appropriate.

Kszos, L.A.; Hinzman, R.L.; Peterson, M.J.; Ryon, M.G.; Smith, J.G.; Southworth, G.R.

1995-06-01T23:59:59.000Z

355

Method and apparatus for removal of gaseous, liquid and particulate contaminants from molten metals  

DOE Patents (OSTI)

Method and apparatus for removal of nonelectrically-conducting gaseous, liquid, and particulate contaminants from molten metal compositions by applying a force thereto. The force (commonly referred to as the Lorentz Force) exerted by simultaneous application of an electric field and a magnetic field on a molten conductor causes an increase, in the same direction as the force, in the apparent specific gravity thereof, but does not affect the nonconducting materials. This difference in apparent densities cause the nonconducting materials to ''float'' in the opposite direction from the Lorentz Force at a rapid rate. Means are further provided for removal of the contaminants and prevention of stirring due to rotational forces generated by the applied fields. 6 figs.

Hobson, D.O.; Alexeff, I.; Sikka, V.K.

1987-08-10T23:59:59.000Z

356

Liquefied gaseous fuels safety and environmental control assessment program: third status report  

Science Conference Proceedings (OSTI)

This Status Report contains contributions from all contractors currently participating in the DOE Liquefied Gaseous Fuels (LG) Safety and Environmental Control Assessment Program and is presented in two principal sections. Section I is an Executive Summary of work done by all program participants. Section II is a presentation of fourteen individual reports (A through N) on specific LGF Program activities. The emphasis of Section II is on research conducted by Lawrence Livermore National Laboratory (Reports A through M). Report N, an annotated bibliography of literature related to LNG safety and environmental control, was prepared by Pacific Northwest Laboratory (PNL) as part of its LGF Safety Studies Project. Other organizations who contributed to this Status Report are Aerojet Energy Conversion Company; Applied Technology Corporation; Arthur D. Little, Incorporated; C/sub v/ International, Incorporated; Institute of Gas Technology; and Massachusetts Institute of Technology. Separate abstracts have been prepared for Reports A through N for inclusion in the Energy Data Base.

Not Available

1982-03-01T23:59:59.000Z

357

GROW1: a crop growth model for assessing impacts of gaseous pollutants from geothermal technologies  

DOE Green Energy (OSTI)

A preliminary model of photosynthesis and growth of field crops was developed to assess the effects of gaseous pollutants, particularly airborne sulfur compounds, resulting from energy production from geothermal resources. The model simulates photosynthesis as a function of such variables as irradiance, CO/sub 2/ diffusion resistances, and internal biochemical processes. The model allocates the products of photosynthesis to structural (leaf, stem, root, and fruit) and storage compartments of the plant. The simulations encompass the entire growing season from germination to senescence. The model is described conceptually and mathematically and examples of model output are provided for various levels of pollutant stress. Also, future developments that would improve this preliminary model are outlined and its applications are discussed.

Kercher, J.R.

1977-03-17T23:59:59.000Z

358

Privatization of the gaseous diffusion plants and impacts on nuclear criticality safety administration  

SciTech Connect

The Energy Policy Act of 1992 created the United States Enrichment Corporation (USEC) on July 1, 1993. The USEC is a government-owned business that leases those Gaseous Diffusion Plant (GDP) facilities at the Portsmouth, Ohio, and Paducah, Kentucky, sites from the U.S. Department of Energy (DOE) that are required for enriching uranium. Lockheed Martin Utility Services is the operating contractor for the USEC-leased facilities. The DOE has retained use of, and regulation over, some facilities and areas at the Portsmouth and Paducah sites for managing legacy wastes and environmental restoration activities. The USEC is regulated by the DOE, but is currently changing to regulation under the U.S. Nuclear Regulatory Commission (NRC). The USEC is also preparing for privatization of the uranium enrichment enterprise. These changes have significantly affected the nuclear criticality safety (NCS) programs at the sites.

D`Aquila, D.M.; Holliday, R.T. [Lockheed Martin Utility Services, Inc., Piketon, OH (United States); Dean, J.C. [Lockheed Martin Utility Services, Inc., Paducah, KY (United States)

1996-12-31T23:59:59.000Z

359

Toxicity Analysis of Polycyclic Aromatic Hydrocarbon Mixtures  

E-Print Network (OSTI)

Polycyclic aromatic hydrocarbons (PAHs) are widely distributed in the environment and are generated by many sources. Though the potential of PAH-rich mixtures to cause health effects has been known for almost a century, there are still unanswered questions about the levels of PAHs in the environment, the potential for human exposure to PAHs, the health effects associated with exposure, and how genetic susceptibility influences the extent of health effects in individuals. The first objective of this research was to quantify concentrations of PAHs in samples of settled house dust collected from homes in Azerbaijan, China, and Texas. The trends of PAH surface loadings and percentage of carcinogenic PAHs were China > Azerbaijan > Texas, indicating that the risk of health effects from exposure to PAHs in house dust is highest in the Chinese population and lowest in the Texas population. PAHs in China and Azerbaijan were derived mainly from combustion sources; Texas PAHs were derived from unburned fossil fuels such as petroleum. The second objective of this research was to investigate the effect of pregnane X receptor (PXR) on the genotoxicity of benzo[a]pyrene (BaP). BaP treatment resulted in significantly lower DNA adduct levels in PXR-transfected HepG2 cells than in parental HepG2 cells. Total GST enzymatic activity and mRNA levels of several metabolizing enyzmes were significantly higher in cells overexpressing PXR. These results suggest that PXR protects cells against DNA damage by PAHs such as BaP, possibly through a coordinated regulation of genes involved in xenobiotic metabolism. The third objective of this research was to investigate biomarkers of exposure in house mice (Mus musculus) exposed to PAH mixtures in situ. Mice and soil were collected near homes in Sumgayit and Khizi, Azerbaijan. Mean liver adduct levels were significantly higher in Khizi than in Sumgayit. Mean lung and kidney adduct levels were similar in the two regions. The DNA lesions detected may be a combination of environmentally-induced DNA adducts and naturally-occurring I-compounds. PAHs were present at background levels in soils from both Khizi and Sumgayit. It appears that health risks posed to rodents by soil-borne PAHs are low in these two areas.

Naspinski, Christine S.

2009-05-01T23:59:59.000Z

360

Review of the Portsmouth Gaseous Diffusion Plant Work Planning and Control Activities Prior to Work Execution, January 2013  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Review of the Review of the Portsmouth Gaseous Diffusion Plant Work Planning and Control Activities Prior to Work Execution January 2013 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose ................................................................................................................................................. 1 2.0 Scope.................................................................................................................................................... 1 3.0 Background........................................................................................................................................... 1

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Analytical risk-based model of gaseous and liquid-phase radon transport in landfills with radium sources  

Science Conference Proceedings (OSTI)

An analytical model of gaseous and liquid-phase radon transport through soils is derived for environmental modeling of landfills containing uranium mill tailings or Ra-226 sources. Processes include radon diffusion in both the gas and liquid phases, ... Keywords: Landfill, Multiphase, Performance assessment, Probabilistic modeling, Radium, Radon, Transport

Clifford K. Ho

2008-09-01T23:59:59.000Z

362

Int. J. Environment and Pollution, Vol. 8, Nos. 3-6, 1997 727 Gaseous pollutant dispersion around urban-canopy  

E-Print Network (OSTI)

. Meroney, 1983: Gas dispersion near a cubical model building. Part I. Mean concentration measurements. JInt. J. Environment and Pollution, Vol. 8, Nos. 3-6, 1997 727 Gaseous pollutant dispersion around numerical predictions of atmospheric dispersion in the urban environment on sub-meso scales. Wind

Fedorovich, Evgeni

363

Tests of Micro-Pattern Gaseous Detectors for Active1 Target Time Projection Chambers in nuclear physics2  

E-Print Network (OSTI)

Tests of Micro-Pattern Gaseous Detectors for Active1 Target Time Projection Chambers in nuclear the gas used as the detection medium10 is also a target for nuclear reactions, have been used for a wide variety of11 nuclear physics applications since the eighties. Improvements in MPGD (Mi-12 cro Pattern

Recanati, Catherine

364

Catalytic Upgrading of Sugars to Hydrocarbons Technology Pathway  

Science Conference Proceedings (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the catalytic conversion of solubilized carbohydrate streams to hydrocarbon biofuels, utilizing data from recent efforts within the National Advanced Biofuels Consortium (NABC) in collaboration with Virent, Inc.. Technical barriers and key research needs that should be pursued for the catalytic conversion of sugars pathway to be competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks have been identified.

Biddy, Mary J.; Jones, Susanne B.

2013-03-31T23:59:59.000Z

365

Method and apparatus for producing oxygenates from hydrocarbons  

DOE Patents (OSTI)

A chemical reactor for oxygenating hydrocarbons includes: a) a dielectric barrier discharge plasma cell, the plasma cell comprising a pair of electrodes having a dielectric material and void therebetween, the plasma cell comprising a hydrocarbon gas inlet feeding to the void; b) a solid oxide electrochemical cell, the electrochemical cell comprising a solid oxide electrolyte positioned between a porous cathode and a porous anode, an oxygen containing gas inlet stream feeding to the porous cathode side of the electrochemical cell; c) a first gas passageway feeding from the void to the anode side of the electrochemical cell; and d) a gas outlet feeding from the anode side of the electrochemical cell to expel reaction products from the chemical reactor. A method of oxygenating hydrocarbons is also disclosed.

Kong, Peter C. (Idaho Falls, ID); Lessing, Paul A. (Idaho Falls, ID)

1995-01-01T23:59:59.000Z

366

Catalytic Fast Pyrolysis for the Production of the Hydrocarbon Biofuels  

SciTech Connect

Catalytic fast pyrolysis is a promising technique for conversion of biomass into hydrocarbons for use as transportation fuels. For over 30 years this process has been studied and it has been demonstrated that oils can be produced with high concentrations of hydrocarbons and low levels of oxygen. However, the yields from this type of conversion are typically low and the catalysts, which are often zeolites, are quickly deactivated through coking. In addition, the hydrocarbons produced are primarily aromatic molecules (benzene, toluene, xylene) that not desirable for petroleum refineries and are not well suited for diesel or jet engines. The goals of our research are to develop new multifunction catalysts for the production of gasoline, diesel and jet fuel range molecules and to improve process conditions for higher yields and low coking rates. We are investigating filtration and the use of hydrogen donor molecules to improve catalyst performance.

Nimlos, M. R.; Robichaud, D. J.; Mukaratate, C.; Donohoe, B. S.; Iisa, K.

2013-01-01T23:59:59.000Z

367

Process for light-driven hydrocarbon oxidation at ambient temperatures  

DOE Patents (OSTI)

A photochemical reaction for the oxidation of hydrocarbons uses molecular oxygen as the oxidant. A reductive photoredox cycle that uses a tin(IV)- or antimony(V)-porphyrin photosensitizer generates the reducing equivalents required to activate oxygen. This artificial photosynthesis system drives a catalytic cycle, which mimics the cytochrome P{sub 450} reaction, to oxidize hydrocarbons. An iron(III)- or manganese(III)-porphyrin is used as the hydrocarbon-oxidation catalyst. Methylviologen can be used as a redox relay molecule to provide for electron-transfer from the reduced photosensitizer to the Fe or Mn porphyrin. The system is long-lived and may be used in photo-initiated spectroscopic studies of the reaction to determine reaction rates and intermediates. 1 fig. 2 tab.

Shelnutt, J.A.

1989-09-26T23:59:59.000Z

368

Process for light-driven hydrocarbon oxidation at ambient temperatures  

DOE Patents (OSTI)

A photochemical reaction for the oxidation of hydrocarbons uses molecular oxygen as the oxidant. A reductive photoredox cycle that uses a tin(IV)- or antimony(V)-porphyrin photosensitizer generates the reducing equivalents required to activate oxygen. This artificial photosynthesis system drives a catalytic cycle, which mimics the cytochrome P.sub.450 reaction, to oxidize hydrocarbons. An iron(III)- or manganese(III)-porphyrin is used as the hydrocarbon-oxidation catalyst. Methylviologen can be used as a redox relay molecule to provide for electron-transfer from the reduced photosensitizer to the Fe or Mn porphyrin. The system is long-lived and may be used in photo-initiated spectroscopic studies of the reaction to determine reaction rates and intermediates.

Shelnutt, John A. (Tijeras, NM)

1990-01-01T23:59:59.000Z

369

Reclamation and reuse of Freon in total petroleum hydrocarbon analyses  

Science Conference Proceedings (OSTI)

At the Savannah River Technology Center (SRTC), we have successfully demonstrated the use of a solvent recycling system to reclaim spent Freon solvent in total petroleum hydrocarbon (TPH) analyses of radioactive samples. A wide variety of sample types including ground water, organics, laboratory waste, process control, sludge, soils, and others are received by our lab for total petroleum hydrocarbon analysis. This paper demonstrates the successful use of a commercially available carbon bed recycle system which we modified to enable the recovery of 95-98 percent of the radioactive contaminated Freon. This system has been used successfully in our lab for the past three years.

Ekechukwu, A.A.; Young, J.E.

1997-12-31T23:59:59.000Z

370

Method and apparatus for synthesizing various short chain hydrocarbons  

DOE Patents (OSTI)

A method and apparatus, including novel photocatalysts, are disclosed for the synthesis of various short chain hydrocarbons. Light-transparent SiO{sub 2} aerogels doped with photochemically active uranyl ions are fluidized in a fluidized-bed reactor having a transparent window, by hydrogen and CO, C{sub 2}H{sub 4} or C{sub 2}H{sub 6} gas mixtures, and exposed to radiation from a light source external to the reactor, to produce the short chain hydrocarbons. 1 fig., 1 tab.

Colmenares, C.

1989-05-05T23:59:59.000Z

371

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents (OSTI)

A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external flotation tanks located below the water surface. The surface buoy is secured to the sea bed by one or more tendons which are anchored to a foundation with piles imbedded in the sea bed. The system accommodates multiple versions on the surface buoy configuration. 20 figures.

Blandford, J.W.

1995-01-17T23:59:59.000Z

372

Method for recovering light hydrocarbons from coal agglomerates  

DOE Patents (OSTI)

A method and apparatus for removing light hydrocarbons, such as heptane, from coal agglomerates includes an enclosed chamber having a substantially horizontal perforate surface therein. The coal agglomerates are introduced into a water bath within the chamber. The agglomerates are advanced over the surface while steam is substantially continuously introduced through the surface into the water bath. Steam heats the water and causes volatilization of the light hydrocarbons, which may be collected from the overhead of the chamber. The resulting agglomerates may be collected at the opposite end from the surface and subjected to final draining processes prior to transportation or use.

Huettenhain, Horst (Benicia, CA); Benz, August D. (Hillsborough, CA); Getsoian, John (Ann Arbor, MI)

1991-01-01T23:59:59.000Z

373

Preliminary investigation of the nature of hydrocarbon migration and entrapment  

E-Print Network (OSTI)

Numerical simulations indicate that hydrocarbon migration and entrapment in stacked fault-bounded reservoirs are mainly affected by the following factors: charge time, faults, pressure and geological structures. The charge time for commercial hydrocarbon accumulation is much longer in oil-water systems than in oil-gas-water systems. Faults are classified into charging faults and 'back doors' faults other than charging faults in stacked fault-bounded reservoirs. The lower the displacement pressure of a fault, the higher its updip oil transportation ability. The downdip oil transportation ability of a fault is usually low and cannot cause commercial downdip oil accumulation. Back doors affect both hydrocarbon percent charge and hydrocarbon migration pathways. Updip back doors improve updip oil charge. The lower the displacement pressure of an updip back door, the more efficient the updip oil charge before 3,000 years. Back doors whose displacement pressure is equal to or higher than 28.76 psi are effective in sealing faults in oil-water systems. On the contrary, only sealing faults result in commercial gas accumulations in stacked fault-compartmentalized reservoirs. Otherwise gas is found over oil. Downdip back doors generally have few effects on downdip hydrocarbon charge. Geopressure enhances the updip oil transportation of a fault and improves the positive effects of updip back doors during updip oil charge. Geopressure and updip back doors result in more efficient updip oil charge. A physical barrier is not necessarily a barrier to oil migration with the aid of geopressure and updip back doors. The chance for hydrocarbon charge into reservoirs along growth faults is not equal. Any one of the above controlling factors can change the patterns of hydrocarbon charge and distribution in such complex geological structures. Generally, lower reservoirs and updip reservoirs are favored. Reservoirs along low-permeability charging faults may be bypassed. Gas can only charge the updip reservoirs. Both updip and downdip back doors can facilitate oil penetrating a barrier fault to charge reservoirs offset by the barrier fault. Interreservoir migration among stacked fault-compartmentalized reservoirs is an important mechanism for hydrocarbon accumulation and trap identification. The interreservoir migration is a very slow process, even though the displacement pressures of bounding faults may be very low.

Bai, Jianyong

2005-05-01T23:59:59.000Z

374

Process of producing liquid hydrocarbon fuels from biomass  

DOE Patents (OSTI)

A continuous thermochemical indirect liquefaction process to convert various biomass materials into diesel-type transportation fuels which fuels are compatible with current engine designs and distribution systems comprising feeding said biomass into a circulating solid fluidized bed gasification system to produce a synthesis gas containing olefins, hydrogen and carbon monoxide and thereafter introducing the synthesis gas into a catalytic liquefaction system to convert the synthesis gas into liquid hydrocarbon fuel consisting essentially of C.sub.7 -C.sub.17 paraffinic hydrocarbons having cetane indices of 50+.

Kuester, James L. (Scottsdale, AZ)

1987-07-07T23:59:59.000Z

375

Process of producing liquid hydrocarbon fuels from biomass  

DOE Patents (OSTI)

A continuous thermochemical indirect liquefaction process is described to convert various biomass materials into diesel-type transportation fuels which fuels are compatible with current engine designs and distribution systems comprising feeding said biomass into a circulating solid fluidized bed gasification system to produce a synthesis gas containing olefins, hydrogen and carbon monoxide and thereafter introducing the synthesis gas into a catalytic liquefaction system to convert the synthesis gas into liquid hydrocarbon fuel consisting essentially of C[sub 7]-C[sub 17] paraffinic hydrocarbons having cetane indices of 50+. 1 fig.

Kuester, J.L.

1987-07-07T23:59:59.000Z

376

Method and apparatus for production of subsea hydrocarbon formations  

DOE Patents (OSTI)

A system for controlling, separating, processing and exporting well fluids produced from subsea hydrocarbon formations is disclosed. The subsea well tender system includes a surface buoy supporting one or more decks above the water surface for accommodating equipment to process oil, gas and water recovered from the subsea hydrocarbon formation. The surface buoy includes a surface-piercing central flotation column connected to one or more external floatation tanks located below the water surface. The surface buoy is secured to the seabed by one or more tendons which are anchored to a foundation with piles imbedded in the seabed. The system accommodates multiple versions on the surface buoy configuration.

Blandford, Joseph W. (15 Mott La., Houston, TX 77024)

1995-01-01T23:59:59.000Z

377

Low-Temperature Catalytic Process To Produce Hydrocarbons From Sugars  

DOE Patents (OSTI)

Disclosed is a method of producing hydrogen from oxygenated hydrocarbon reactants, such as methanol, glycerol, sugars (e.g. glucose and xylose), or sugar alcohols (e.g. sorbitol). The method takes place in the condensed liquid phase. The method includes the steps of reacting water and a water-soluble oxygenated hydrocarbon in the presence of a metal-containing catalyst. The catalyst contains a metal selected from the group consisting of Group VIIIB transitional metals, alloys thereof, and mixtures thereof. The disclosed method can be run at lower temperatures than those used in the conventional steam reforming of alkanes.

Cortright, Randy D. (Madison, WI); Dumesic, James A. (Verona, WI)

2005-11-15T23:59:59.000Z

378

Variability of Gas Composition and Flux Intensity in Natural Marine Hydrocarbon Seeps  

E-Print Network (OSTI)

Energy Development and Technology 008 "Variability of gas composition and flux intensity in natural marine hydrocarbon seeps" Jordan

Clark, J F; Schwager, Katherine; Washburn, Libe

2005-01-01T23:59:59.000Z

379

Hydrocarbon compositions of high elongational viscosity and process for making the same  

SciTech Connect

A hydrocarbon composition is described consisting essentially of a hydrocarbon liquid and an ionic-association or coordination-complex polymer in an amount sufficient to increase and maintain the elongational viscosity of the composition at a level greater than that of the hydrocarbon alone. The polymer is capable of dissociation upon application of the high shear regime to which the hydrocarbon is subjected, and reassociation upon withdrawal of the high shear.

Hamil, H.F.; Weatherford, W.D. Jr.; Fodor, G.E.

1988-03-15T23:59:59.000Z

380

U.S. Product Supplied of Other Hydrocarbons/Oxygenates (Thousand ...  

U.S. Energy Information Administration (EIA)

Product Supplied for Hydrogen/Oxygenates/Renewables/Other Hydrocarbons ; U.S. Product Supplied for Crude Oil and Petroleum Products ...

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

U.S. Exports of Other Hydrocarbons/Oxygenates (Thousand Barrels ...  

U.S. Energy Information Administration (EIA)

Hydrogen/Oxygenates/Renewables/Other Hydrocarbons Supply and Disposition; U.S. Exports of Crude Oil and Petroleum Products ...

382

THERMOCATALYTIC CO2-FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS  

E-Print Network (OSTI)

, preferential oxidation) and gas separation stages required by conventional technologies (e.g., steam reforming and carbon via sustainable catalytic decomposition of methane or other hydrocarbons using inexpensive-situ generation of catalytically active carbon species produced by co-decomposition of methane and unsaturated and

383

Conversion of methane and acetylene into gasoline range hydrocarbons  

E-Print Network (OSTI)

Conversion of methane and acetylene to higher molecular weight hydrocarbons over zeolite catalyst (HZSM-5) was studied The reaction between methane and acetylene successfully produced high molecular weight hydrocarbons, such as naphthalene, benzene, indene, azulene, fluorene, and biphenyl substituted compounds. Also, lighter hydrocarbons, such as ethylene and isobutene were produced. The reaction was conducted at different operating temperatures and different molar feed composition. The results showed that the conversion of both reactants increased with increasing the operating temperature; for example a conversion of 95.1% was achieved for acetylene at 350C and 98.6% at 412C. In addition, the conversion of both reactants decreased with increasing the molar feed ratio of methane to acetylene. A conversion of 96.4% for acetylene was achieved at a molar feed ratio of 6 to 1 (methane to acetylene) and 80.9% at a molar feed ration of 20 to 1 (methane to acetylene). The reaction of methane and ethane over HZSM-5 catalyst also led to the production of high molecular weight hydrocarbons, mainly aromatics, and some lighter products such as propane, and ethylene. Also methane by itself showed the ability to react over HZSM-5 to produce a small amount of aromatics, and ethylene.

Alkhawaldeh, Ammar

2000-01-01T23:59:59.000Z

384

TREATMENT OF GASEOUS EFFLUENTS ISSUED FROM RECYCLING A REVIEW OF THE CURRENT PRACTICES AND PROSPECTIVE IMPROVEMENTS  

Science Conference Proceedings (OSTI)

The objectives of gaseous waste management for the recycling of nuclear used fuel is to reduce by best practical means (ALARA) and below regulatory limits, the quantity of activity discharged to the environment. The industrial PUREX process recovers the fissile material U(VI) and Pu(IV) to re-use them for the fabrication of new fuel elements e.g. recycling plutonium as a Mixed Oxide (MOX) fuel or recycling uranium for new enrichment for Pressurized Water Reactor (PWR). Meanwhile the separation of the waste (activation and fission product) is performed as a function of their pollution in order to store and avoid any potential danger and release towards the biosphere. Raffinate, that remains after the extraction step and which contains mostly all fission products and minor actinides is vitrified, the glass package being stored temporarily at the recycling plant site. Hulls and end pieces coming from PWR recycled fuel are compacted by means of a press leading to a volume reduced to 1/5th of initial volume. An organic waste treatment step will recycle the solvent, mainly tri-butyl phosphate (TBP) and some of its hydrolysis and radiolytic degradation products such as dibutyl phosphate (HDPB) and monobutyl phosphate (H2MBP). Although most scientific and technological development work focused on high level waste streams, a considerable effort is still under way in the area of intermediate and low level waste management. Current industrial practices for the treatment of gaseous effluents focusing essentially on Iodine-129 and Krypton-85 will be reviewed along with the development of novel technologies to extract, condition, and store these fission products. As an example, the current industrial practice is to discharge Kr-85, a radioactive gas, entirely to the atmosphere after dilution, but for the large recycling facilities envisioned in the near future, several techniques such as 1) cryogenic distillation and selective absorption in solvents, 2) adsorption on activated charcoal, 3) selective sorption on chemical modified zeolites, or 4) diffusion through membranes with selective permeability are potential technologies to retain the gas.

Patricia Paviet-Hartmann; William Kerlin; Steven Bakhtiar

2010-11-01T23:59:59.000Z

385

Impact of nitrate-enhanced leachate recirculation on gaseous releases from a landfill bioreactor cell  

SciTech Connect

This study evaluates the impact of nitrate injection on a full scale landfill bioreactor through the monitoring of gaseous releases and particularly N{sub 2}O emissions. During several weeks, we monitored gas concentrations in the landfill gas collection system as well as surface gas releases with a series of seven static chambers. These devices were directly connected to a gas chromatograph coupled to a flame ionisation detector and an electron capture detector (GC-FID/ECD) placed directly on the field. Measurements were performed before, during and after recirculation of raw leachate and nitrate-enhanced leachate. Raw leachate recirculation did not have a significant effect on the biogas concentrations (CO{sub 2}, CH{sub 4} and N{sub 2}O) in the gas extraction network. However, nitrate-enhanced leachate recirculation induced a marked increase of the N{sub 2}O concentrations in the gas collected from the recirculation trench (100-fold increase from 0.2 ppm to 23 ppm). In the common gas collection system however, this N{sub 2}O increase was no more detectable because of dilution by gas coming from other cells or ambient air intrusion. Surface releases through the temporary cover were characterized by a large spatial and temporal variability. One automated chamber gave limited standard errors over each experimental period for N{sub 2}O releases: 8.1 {+-} 0.16 mg m{sup -2} d{sup -1} (n = 384), 4.2 {+-} 0.14 mg m{sup -2} d{sup -1} (n = 132) and 1.9 {+-} 0.10 mg m{sup -2} d{sup -1} (n = 49), during, after raw leachate and nitrate-enhanced leachate recirculation, respectively. No clear correlation between N{sub 2}O gaseous surface releases and recirculation events were evidenced. Estimated N{sub 2}O fluxes remained in the lower range of what is reported in the literature for landfill covers, even after nitrate injection.

Tallec, G.; Bureau, C. [Cemagref, UR HBAN, Parc de Tourvoie, BP44, F-92163 Antony (France); Peu, P.; Benoist, J.C. [Cemagref, UR GERE, 17 Avenue de Cucille, CS 64427, F-35044 Rennes (France); Lemunier, M. [Suez-Environnement, CIRADE, 38 Av. Jean Jaures, 78440 Gargenville (France); Budka, A.; Presse, D. [SITA France, 132 Rue des 3 Fontanot, 92000 Nanterre Cedex (France); Bouchez, T. [Cemagref, UR HBAN, Parc de Tourvoie, BP44, F-92163 Antony (France)], E-mail: theodore.bouchez@cemagref.fr

2009-07-15T23:59:59.000Z

386

Calculation of releases of radioactive materials in gaseous and liquid effluents from pressurized water reactors (PWR-GALE Code). Revision 1  

SciTech Connect

This report revises the original issuance of NUREG-0017, ''Calculation of Releases of Radioactive Materials in Gaseous and Liquid Effluents from Pressurized Water Reactors (PWR-GALE-Code)'' (April 1976), to incorporate more recent operating data now available as well as the results of a number of in-plant measurement programs at operating pressurized water reactors. The PWR-GALE Code is a computerized mathematical model for calculating the releases of radioactive material in gaseous and liquid effluents (i.e., the gaseous and liquid source terms). The US Nuclear Regulatory Commission uses the PWR-GALE Code to determine conformance with the requirements of Appendix I to 10 CFR Part 50.

Chandrasekaran, T.; Lee, J.Y.; Willis, C.A.

1985-04-01T23:59:59.000Z

387

Reclamation and reuse of freon in total petroleum hydrocarbon analyses  

SciTech Connect

ADS is using a commercially available solvent reclamation system to recycle 95-97 percent of the Freon used in total petroleum hydrocarbon analyses. ADS has further developed the commercially available solvent reclamation system to accommodate radioactive contaminated Freon. This report establishes the following: validity of the method; success of recycling; and effect of radionuclides in recycling radioactive contaminated Freon. The standard analysis method for determining total petroleum hydrocarbons (commonly known as oil and grease determination) involves solvent extraction of the hydrocarbons using Freon followed by quantitation using infrared detection. This has been the method of choice because it is simple, rugged, inexpensive, and applicable to both solid and liquid samples and to radioactive samples. Due to its deleterious effect on the ozone layer, the use of Freon and other chloro-fluorocarbons (CFCs) has been greatly restricted. Freon has become very expensive (800$/liter) and will soon be unavailable entirely. Several methods have been proposed to replace the Freon extraction method. These methods include solid-phase extraction, solvent extraction, and supercritical fluid extraction all of which use gravimetric determination or infrared analysis of the extracted hydrocarbons. These methods are not as precise or as sensitive as the Freon extraction method, and a larger amount of sample is therefore required due to the decreased sensitivity. The solid phase extraction method cannot accommodate solid samples. Supercritical fluid extraction requires expensive instrumentation. ADS opted to keep the existing Freon method and recycle the solvent. An inexpensive solvent reclamation system was procured to reclaim the spent Freon. This reclaimer removes hydrocarbons from the Freon solvent by passage through an activated carbon bed.

Ekechukwu, A.A.; Peterson, S.F.

1996-04-01T23:59:59.000Z

388

Method for producing hydrocarbon fuels and fuel gas from heavy polynuclear hydrocarbons by the use of molten metal halide catalysts  

DOE Patents (OSTI)

In a process for hydrocracking heavy polynuclear carbonaceous feedstocks to produce lighter hydrocarbon fuels by contacting the heavy feedstocks with hydrogen in the presence of a molten metal halide catalyst in a hydrocracking zone, thereafter separating at least a major portion of the lighter hydrocarbon fuels from the spent molten metal halide and thereafter regenerating the spent molten metal halide by incinerating the spent molten metal halide by combustion of carbon and sulfur compounds in the spent molten metal halide in an incineration zone, the improvement comprising: (a) contacting the heavy feedstocks and hydrogen in the presence of the molten metal halide in the hydrocracking zone at reaction conditions effective to convert from about 60 to about 90 weight percent of the feedstock to lighter hydrocarbon fuels; (b) separating at least a major portion of the lighter hydrocarbon fuels from the spent molten metal halide; (c) contacting the spent molten metal halide with oxygen in a liquid phase gasification zone at a temperature and pressure sufficient to vaporize from about 25 to about 75 weight percent of the spent metal halide, the oxygen being introduced in an amount sufficient to remove from about 60 to about 90 weight percent of the carbon contained in the spent molten metal halide to produce a fuel gas and regenerated metal halide; and (d) incinerating the spent molten metal halide by combusting carbon and sulfur compounds contained therein.

Gorin, Everett (San Rafael, CA)

1979-01-01T23:59:59.000Z

389

Six-dimensional muon beam cooling in a continuous, homogeneous, gaseous hydrogen absorber  

DOE Green Energy (OSTI)

The fast reduction of the six-dimensional phase space of muon beams is required for muon colliders and is also of great importance for neutrino factories based on accelerated muon beams. Ionization cooling, where all momentum components are degraded by an energy absorbing material and only the longitudinal momentum is restored by RF cavities, provides a means to quickly reduce transverse beam sizes. However, the beam momentum spread cannot be reduced by this method unless the longitudinal emittance can be transformed or exchanged into the transverse emittance. The best emittance exchange plans up to now have been accomplished by using magnets to disperse the beam along the face of a wedge-shaped absorber such that higher momentum particles pass through thicker parts of the absorber and thus suffer larger ionization energy loss. In the scheme advocated in this paper, it is noted that one can generate a magnetic channel filled with absorber where higher momentum corresponds to a longer path length and therefore larger ionization energy loss. Thus a homogeneous absorber, without any special edge shaping, can provide the desired emittance exchange. An attractive example of a cooling channel based on this principle involves the use of RF cavities filled with a continuous gaseous hydrogen absorber in a magnetic channel composed of a solenoidal field with superimposed helical transverse dipole, quadrupole, and octupole fields. The theory of this helical channel is described to support the analytical prediction of a million-fold reduction in phase space volume in a channel 150 m long.

Yaroslav Derbenev; Rolland P. Johnson

2004-10-01T23:59:59.000Z

390

Infrared absorption strengths of potential gaseous diffusion plant coolants and related reaction products  

SciTech Connect

The DOE gaseous diffusion plant complex makes extensive use of CFC-114 as a primary coolant. As this material is scheduled for production curtailment within the next few years, a search for substitutes is underway, and apparently workable alternatives have been found and are under testing. The presently favored substitutes, FC-c3l8 and FC-3110, satisfy ozone depletion and operational chemical compatibility concerns, but will be long-lived greenhouse gases, and thus may be regulated on that basis in the future. A further search is therefore underway for compounds with shorter atmospheric lifetimes which could otherwise satisfy operational physical and chemical requirements. A number of such candidates are in the process of being screened for chemical compatibility in a fluorinating environment. This document presents infrared spectral data developed and used in that study for candidates recently examined, and also for many of their fluorination reaction products. The data include gas-phase infrared spectra, quantitative peak intensities as a function of partial pressure, and integrated absorbance strength in the IR-transparent atmospheric window of interest to global warming modeling. Combining this last property with literature or estimated atmospheric lifetimes, rough estimates of global warming potential for these compounds are also presented.

Trowbridge, L.D.; Angel, E.C.

1993-05-01T23:59:59.000Z

391

Environmental Survey preliminary report, Oak Ridge Gaseous Diffusion Plant, Oak Ridge, Tennessee  

SciTech Connect

This report presents the preliminary findings from the first phase of the Environmental Survey of the US Department of Energy's (DOE) Oak Ridge Gaseous Diffusion Plant (ORGDP) conducted March 14 through 25, 1988. The Survey is being conducted by an interdisciplinary team of environmental specialists, led and managed by the Office of Environment, Safety and Health's Office of Environmental Audit. Individual team components are being supplied by a private contractor. The objective of the Survey is to identify environmental risk associated with ORGDP. The Survey covers all environmental media and all areas of environmental regulation. It is being performed in accordance with the DOE Environmental Survey Manual. This phase of the Survey involves the review of existing site environmental data, observations of the operations carried on at ORGDP, and interviews with site personnel. The Survey team developed a Sampling and Analysis Plan to assist in further assessing certain of the environmental problems identified during is on-site activities. The Sampling and Analysis Plan will be executed by Idaho National Engineering Laboratory (INEL). When completed, the results will be incorporated into the ORGDP Survey findings for in inclusion into the Environmental Survey Summary Report. 120 refs., 41 figs., 74 tabs.

Not Available

1989-02-01T23:59:59.000Z

392

Corrosion behavior of stainless steel in solid oxide fuel cell simulated gaseous environment  

DOE Green Energy (OSTI)

Significant progress in reducing the operating temperature of solid oxide fuel cells (SOFC) from {approx}1000 C to {approx} 750 C may permit the replacement of currently used ceramic interconnects by metallic interconnects in planar SOFCs (PSOFC). The use of metallic interconnects will result in a substantial cost reduction of PSOFCs. The interconnects operate in severe gaseous environments, in which one side of the interconnect can be exposed to hydrogen and the other side to air or oxygen at temperatures up to 800 C. Similar environmental conditions can exist in devices used for separating hydrogen from CO after reforming methane and steam. Type 304 stainless steel was selected for this base line study aimed at understanding corrosion processes in dual gas environments. This paper discusses the oxidation resistance of 304 stainless steel exposed to a dual environment gas at 800 C. The dual environment consisted of air on one side of the specimen and 1% hydrogen in nitrogen on the other side. The surface characterization techniques used in this study were optical and scanning electron microscopy, as well as various x-ray techniques.

Ziomek-Moroz, M.; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Cramer, Stephen D.; Matthes, Steven A.; Bullard, Sophie J.; Dunning, John S.; Alman, David E.; Wilson, Rick D.; Singh, P.

2003-01-01T23:59:59.000Z

393

Gaseous Radiochemical Method for Registration of Ionizing Radiation and Its Possible Applications in Science and Industry  

E-Print Network (OSTI)

This work presents a new possibility of registration of ionizing radiation by the flowing gaseous radiochemical method (FGRM). The specified method uses the property of some solid crystalline lattice materials for a free emission of radioactive isotopes of inert gas atoms formed as a result of nuclear reactions. Generated in an ampoule of the detector, the radioactive inert gases are transported by a gas-carrier into the proportional gas counter of the flowing type, where the decay rate of the radioactive gas species is measured. This quantity is unequivocally related to the flux of particles (neutrons, protons, light and heavy ions) at the location of the ampoule. The method was used to monitor the neutron flux of the pulsed neutron target "RADEX" driven by the linear proton accelerator of INR RAS. Further progress of the FGRM may give rise to possible applications in nuclear physics, astrophysics and medicine, in the nondestructive control of fissionable materials, diagnostics of thermonuclear plasma, monitoring of fluxes and measurement of spectra of bombarding particles.

S. G. Lebedev; V. E. Yants

2005-10-06T23:59:59.000Z

394

Report on the biological monitoring program at Paducah Gaseous Diffusion Plant December 1993 to December 1994  

SciTech Connect

On September 24, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous Diffusion Plant (PGDP). The PGDP BMP was implemented in 1987 by the University of Kentucky. Research staff of the Environmental Sciences Division (ESD) at Oak Ridge National Laboratory (ORNL) served as reviewers and advisers to the University of Kentucky. Beginning in fall 1991, ESD added data collection and report preparation to its responsibilities for the PGDP BMP. The goals of BMP are to (1) demonstrate that the effluent limitations established for PGDP protect and maintain the use of Little Bayou and Big Bayou creeks for growth and propagation of fish and other aquatic life, (2) characterize potential environmental impacts, (3) document the effects of pollution abatement facilities on stream biota, and (4) recommend any program improvements that would increase effluent treatability. In September 1992, a renewed Kentucky Pollutant Discharge Elimination System (KPDES) permit was issued to PGDP. The BMP for PGDP consists of three major tasks: (1) effluent and ambient toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of stream communities (i.e., benthic macroinvertebrates and fish). This report includes ESD activities occurring from December 1993 to December 1994, although activities conducted outside this time period are included as appropriate.

Kszos, L.A. [ed.

1996-05-01T23:59:59.000Z

395

Report on the biological monitoring program at Paducah Gaseous Diffusion Plant, January--December 1996  

Science Conference Proceedings (OSTI)

On September 24, 1987, the Commonwealth of Kentucky Natural Resources and Environmental Protection Cabinet issued an Agreed Order that required the development of a Biological Monitoring Program (BMP) for the Paducah Gaseous diffusion Plant (PGDP). The PGDP BMP was conducted by the University of Kentucky Between 1987 and 1992 and by staff of the Environmental Sciences Division (ESD) at Oak Ridge National Laboratory (ORNL) from 1991 to present. The goals of BMP are to (1) demonstrate that the effluent limitations established for PGDP protect and maintain the use of Little Bayou and Big Bayou creeks for growth and propagation of fish and other aquatic life, (2) characterize potential environmental impacts, and (3) document the effects of pollution abatement facilities on stream. The BMP for PGDP consists of three major tasks: (1) effluent toxicity monitoring, (2) bioaccumulation studies, and (3) ecological surveys of stream communities (i.e., benthic macroinvertebrates and fish). This report focuses on ESD activities occurring from January 1996 to December 1996, although activities conducted outside this time period are included as appropriate.

Kszos, L.A. [ed.; Konetsky, B.K.; Peterson, M.J.; Petrie, R.B.; Ryon, M.G.; Smith, J.G.; Southworth, G.R.

1997-06-01T23:59:59.000Z

396

IAEA Verification Experiment at the Portsmouth Gaseous Diffusion Plant: Report on the Cascade Header Enrichment Monitor  

SciTech Connect

The authors describe the Cascade Header Enrichment Monitor (CHEM) for the Portsmouth Gaseous Diffusion Plant at Piketon, Ohio, and present the calibration and measurement results. The US government has offered excess fissile material that is no longer needed for defense purposes for International Atomic Energy Agency (IAEA) inspection. Measurement results provided by the CHEM were used by the IAEA in a verification experiment to provide confidence that the US successfully blended excess highly enriched uranium (HEU) down to low enriched uranium (LEU). The CHEM measured the uranium enrichment in two cascade header pipes, a 20.32-cm HEU pipe and a 7.62-cm product LEU pipe. The CHEM determines the amount of {sup 235}U from the 185.7-keV gamma-ray photopeak and the amount of total uranium by x-ray fluorescence (XRF) of the 98.4-keV x-ray from uranium with a {sup 57}Co XRF source. The ratio yields the enrichment. The CHEM consists of a collimator assembly, an electromechanically cooled germanium detector, and a rack-mounted personal computer running commercial and custom software. The CHEM was installed in December 1997 and was used by the IAEA inspectors for announced and unannounced inspections on the HEU and LEU header pipes through October 1998. The equipment was sealed with tamper-indicating enclosures when the inspectors were not present.

P. L. Kerr; D. A. Close; W. S. Johnson; R. M. Kandarian; C. E. Moss; C. D. Romero

1999-03-01T23:59:59.000Z

397

Radioactivity discharged in gaseous wastes from separations facilities 200 Area stacks during 1970  

SciTech Connect

This document summarizes by stack number the amount of radioactivity discharged from the facilities of Chemical Processing Division, Atlantic Richfield Hanford Company. Emission data for 231-Z Building and 2724-W, Laundry Building, which are operated by other AEC Contractors are not available for this report. Total beta, alpha and I{sup l3l} radioactive emissions from the stacks for 1970 were as follows: alpha (Pu, assumed) 1.59 {times} 10{sup {minus}1} C, alpha (U, assumed) 1.44 {times} 10{sup {minus}3} C, beta 1.93C, and I{sup 131} 4.92 {times} 10{sup {minus}1} C. Air samples taken continuously from gaseous release facilities were analyzed for total beta and alpha activity (and iodine activity, where applicable). Where sample data were not available, the total radioactive emission was adjusted by using the average emission rate prior to the subject period; or where activity was near constant, by using the daily average as a base. A gamma scan of the 291-S stack is included in the report.

Maxfield, H.L.

1971-03-29T23:59:59.000Z

398

Design and reliability optimization of a MEMS micro-hotplate for combustion of gaseous fuel  

SciTech Connect

This report will detail the process by which the silicon carbide (SiC) microhotplate devices, manufactured by GE, were imaged using IR microscopy equipment available at Sandia. The images taken were used as inputs to a finite element modeling (FEM) process using the ANSYS software package. The primary goal of this effort was to determine a method to measure the temperature of the microhotplate. Prior attempts to monitor the device's temperature by measuring its resistance had proven to be unreliable due to the nonlinearity of the doped SiC's resistance with temperature. As a result of this thermal modeling and IR imaging, a number of design recommendations were made to facilitate this temperature measurement. The lower heating value (LHV) of gaseous fuels can be measured with a catalyst-coated microhotplate calorimeter. GE created a silicon carbide (SiC) based microhotplate to address high-temperature survivability requirements for the application. The primary goal of this effort was to determine a method to measure the temperature of the microhotplate. Prior attempts to monitor the device's temperature by measuring its resistance had proven to be unreliable due to the non-linearity of the doped SiC's resistance with temperature. In this work, thermal modeling and IR imaging were utilized to determine the operation temperature as a function of parameters such as operation voltage and device sheet resistance. A number of design recommendations were made according to this work.

Manginell, R. P.

2012-03-01T23:59:59.000Z

399

An Aerial Radiological Survey of the Portsmouth Gaseous Diffusion Plant and Surrounding Area, Portsmouth, Ohio  

SciTech Connect

An aerial radiological survey was conducted over the 16 square-mile (~41 square-kilometer) area surrounding the Portsmouth Gaseous Diffusion Plant. The survey was performed in August 2007 utilizing a large array of helicopter mounted sodium iodide detectors. The purpose of the survey was to update the previous radiological survey levels of the environment and surrounding areas of the plant. A search for a missing radium-226 source was also performed. Implied exposure rates, man-made activity, and excess bismuth-214 activity, as calculated from the aerial data are presented in the form of isopleth maps superimposed on imagery of the surveyed area. Ground level and implied aerial exposure rates for nine specific locations are compared. Detected radioisotopes and their associated gamma ray exposure rates were consistent with those expected from normal background emitters. At specific plant locations described in the report, man-made activity was consistent with the operational histories of the location. There was no spectral activity that would indicate the presence of the lost source.

Namdoo Moon

2007-12-01T23:59:59.000Z

400

RADIOLYSIS OF ORGANIC COMPOUNDS IN THE ADSORBED STATE  

DOE Patents (OSTI)

>A method of forming branch chained hydrocarbons by means of energetic penetrating radiation is described. A solid zeolite substrate is admixed with a cobalt ion and is irradiated with a hydrocarbon adsorbed therein. Upon irradiation with gamma rays, there is an increased yield of branched and lower molecular straight chain compounds. (AEC)

Sutherland, J.W.; Allen, A.O.

1961-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Independent Oversight Review of Preparedness for Severe Natural Phenomena Events at the Portsmouth Gaseous Diffusion Plant, November 2013  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

of of Preparedness for Severe Natural Phenomena Events at the Portsmouth Gaseous Diffusion Plant May 2011 November 2013 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose................................................................................................................................................ 1 2.0 Scope................................................................................................................................................... 1 3.0 Background ......................................................................................................................................... 1 4.0 Methodology ....................................................................................................................................... 2

402

Gaseous dry deposition of atmospheric mercury: A comparison of two surface resistance models for deposition to semiarid vegetation  

Science Conference Proceedings (OSTI)

In the United States, atmospheric mercury (Hg) deposition, from regional and international sources, is the largest contributor to increased Hg concentrations in bodies of water leading to bioaccumulation of methyl mercury in fish. In this work, modeled dry deposition velocities (vd) for gaseous Hg are calculated using two surface resistance parameterizations found in the literature. The flux is then estimated as the product of the species concentration and modeled vd. The calculations utilize speciated atmospheric mercury concentrations measured during an annual monitoring campaign in southern Idaho. Gaseous elemental mercury (GEM) and reactive gaseous mercury (RGM) were monitored with Tekran models 2537A and 1130, respectively. Two anemometers collected meteorological data, including one fast-response three-dimensional sonic anemometer to measure turbulence parameters. For the flux calculation, three resistances are required to model the mechanisms that transport gaseous Hg from the atmosphere to the surface, with the surface resistance being the largest source of error. Results from two surface resistance models are presented. In particular, the downward flux is sensitive to the choice of model and input parameters such as seasonal category and mesophyll resistance. A comparison of annual GEM and RGM fluxes calculated using the two models shows good agreement for RGM (3.2% difference for annual deposition); however, for the low-solubility species of GEM, the models show a 64% difference in annual fluxes, with a range of 32% to 200% in seasonal fluxes. Results indicate the importance of understanding the diurnal variation of the physical processes modeled in the surface resistance parameterization for vd.

Heather A. Holmes; Eric R. Pardyjak; Kevin D. Perry; Michael L. Abbott

2011-07-01T23:59:59.000Z

403

Review of the Portsmouth Gaseous Diffusion Plant Work Planning and Control Activities Prior to Work Execution, January 2013  

NLE Websites -- All DOE Office Websites (Extended Search)

Independent Oversight Review of the Independent Oversight Review of the Portsmouth Gaseous Diffusion Plant Work Planning and Control Activities Prior to Work Execution January 2013 Office of Safety and Emergency Management Evaluations Office of Enforcement and Oversight Office of Health, Safety and Security U.S. Department of Energy Table of Contents 1.0 Purpose ................................................................................................................................................. 1 2.0 Scope.................................................................................................................................................... 1 3.0 Background........................................................................................................................................... 1

404

PAndAS IN THE MIST: THE STELLAR AND GASEOUS MASS WITHIN THE HALOS OF M31 AND M33  

SciTech Connect

Large-scale surveys of the prominent members of the Local Group have provided compelling evidence for the hierarchical formation of massive galaxies, revealing a wealth of substructure that is thought to be the debris from ancient and ongoing accretion events. In this paper, we compare two extant surveys of the M31-M33 subgroup of galaxies: the Pan-Andromeda Archaeological Survey of the stellar structure, and a combination of observations of the H I gaseous content, detected at 21 cm. Our key finding is a marked lack of spatial correlation between these two components on all scales, with only a few potential overlaps between stars and gas. The paucity of spatial correlation significantly restricts the analysis of kinematic correlations, although there does appear to be H I kinematically associated with the Giant Stellar Stream where it passes the disk of M31. These results demonstrate that different processes must significantly influence the dynamical evolution of the stellar and H I components of substructures, such as ram pressure driving gas away from a purely gravitational path. Detailed modeling of the offset between the stellar and gaseous substructures will provide a determination of the properties of the gaseous halos of M31 and M33.

Lewis, Geraint F. [Sydney Institute for Astronomy, School of Physics A28, The University of Sydney, NSW 2006 (Australia)] [Sydney Institute for Astronomy, School of Physics A28, The University of Sydney, NSW 2006 (Australia); Braun, Robert [CSIRO Astronomy and Space Science, P.O. Box 76, Epping, NSW 1710 (Australia)] [CSIRO Astronomy and Space Science, P.O. Box 76, Epping, NSW 1710 (Australia); McConnachie, Alan W. [Dominion Astrophysical Observatory, 5071 West Saanich Road, Victoria, BC V9E 2E7 (Canada)] [Dominion Astrophysical Observatory, 5071 West Saanich Road, Victoria, BC V9E 2E7 (Canada); Irwin, Michael J.; Chapman, Scott C. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom)] [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom); Ibata, Rodrigo A.; Martin, Nicolas F. [Observatoire de Strasbourg, 11, rue de l'Universite, F-67000 Strasbourg (France)] [Observatoire de Strasbourg, 11, rue de l'Universite, F-67000 Strasbourg (France); Ferguson, Annette M. N. [Institute for Astronomy, University of Edinburgh, Blackford Hill, Edinburgh EH9 3HJ (United Kingdom)] [Institute for Astronomy, University of Edinburgh, Blackford Hill, Edinburgh EH9 3HJ (United Kingdom); Fardal, Mark [Department of Astronomy, University of Massachusetts, Amherst, MA 01003-9305 (United States)] [Department of Astronomy, University of Massachusetts, Amherst, MA 01003-9305 (United States); Dubinski, John [Department of Astronomy and Astrophysics, 50 St. George Street, University of Toronto, ON M5S 3H4 (Canada)] [Department of Astronomy and Astrophysics, 50 St. George Street, University of Toronto, ON M5S 3H4 (Canada); Widrow, Larry [Department of Physics, Queen's University, 99 University Avenue, Kingston, ON K7L 3N6 (Canada)] [Department of Physics, Queen's University, 99 University Avenue, Kingston, ON K7L 3N6 (Canada); Mackey, A. Dougal [Research School of Astronomy and Astrophysics, Mount Stromlo Observatory, Cotter Road, Weston Creek, ACT 2611 (Australia)] [Research School of Astronomy and Astrophysics, Mount Stromlo Observatory, Cotter Road, Weston Creek, ACT 2611 (Australia); Babul, Arif [Department of Physics and Astronomy, University of Victoria, Victoria, BC V8W 3P6 (Canada)] [Department of Physics and Astronomy, University of Victoria, Victoria, BC V8W 3P6 (Canada); Tanvir, Nial R. [Department of Physics and Astronomy, University of Leicester, Leicester LE1 7RH (United Kingdom)] [Department of Physics and Astronomy, University of Leicester, Leicester LE1 7RH (United Kingdom); Rich, Michael, E-mail: geraint.lewis@sydney.edu.au [Division of Astronomy, University of California, 8979 Math Sciences, Los Angeles, CA 90095-1562 (United States)] [Division of Astronomy, University of California, 8979 Math Sciences, Los Angeles, CA 90095-1562 (United States)

2013-01-20T23:59:59.000Z

405

Summary and Outlook of the International Workshop on Aging Phenomena in Gaseous Detectors (DESY, Hamburg, October, 2001)  

E-Print Network (OSTI)

High Energy Physics experiments are currently entering a new era which requires the operation of gaseous particle detectors at unprecedented high rates and integrated particle fluxes. Full functionality of such detectors over the lifetime of an experiment in a harsh radiation environment is of prime concern to the involved experimenters. New classes of gaseous detectors such as large-scale straw-type detectors, Micro-pattern Gas Detectors and related detector types with their own specific aging effects have evolved since the first workshop on wire chamber aging was held at LBL, Berkeley in 1986. In light of these developments and as detector aging is a notoriously complex field, the goal of the workshop was to provide a forum for interested experimentalists to review the progress in understanding of aging effects and to exchange recent experiences. A brief summary of the main results and experiences reported at the 2001 workshop is presented, with the goal of providing a systematic review of aging effects in state-of-the-art and future gaseous detectors.

M. Titov; M. Hohlmann; C. Padilla; N. Tesch

2002-04-04T23:59:59.000Z

406

Method for selectively removing fluorine and fluorine-containing contaminants from gaseous UF/sub 6/. [ClF/sub 3/  

DOE Patents (OSTI)

This invention is a method for effecting preferential removal and immobilization of certain gaseous contaminants from gaseous UF/sub 6/. The contaminants include fluorine and fluorides which are more reactive with CaCO/sub 3/ than is UF/sub 6/. The method comprises contacting the contaminant-carrying UF/sub 6/ with particulate CaCO/sub 3/ at a temperature effecting reaction of the contaminant and the CaCO/sub 3/.

Jones, R.L.; Otey, M.G.; Perkins, R.W.

1980-11-24T23:59:59.000Z

407

Algal Lipid Extraction and Upgrading to Hydrocarbons Technology Pathway  

Science Conference Proceedings (OSTI)

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the cultivation of algal biomass followed by further lipid extraction and upgrading to hydrocarbon biofuels. Technical barriers and key research needs have been assessed in order for the algal lipid extraction and upgrading pathway to be competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks.

Davis, Ryan; Biddy, Mary J.; Jones, Susanne B.

2013-03-31T23:59:59.000Z

408

Biological Conversion of Sugars to Hydrocarbons Technology Pathway  

SciTech Connect

In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This technology pathway case investigates the biological conversion of biomass derived sugars to hydrocarbon biofuels, utilizing data from recent literature references and information consistent with recent pilot scale demonstrations at NREL. Technical barriers and key research needs have been identified that should be pursued for the pathway to become competitive with petroleum-derived gasoline, diesel and jet range hydrocarbon blendstocks.

Davis, Ryan; Biddy, Mary J.; Tan, Eric; Tao, Ling; Jones, Susanne B.

2013-03-31T23:59:59.000Z

409

Plasma-induced conversion of surface-adsorbed hydrocarbons  

DOE Green Energy (OSTI)

Experimental results are reported for an electrical device for direct conversion of methane into higher hydrocarbons. A microchannel plate is excited with electrons from a photoemissive source, and electron impact ionization of methane on the inner surfaces of the microchannels creates an ion feedback process. The resulting low-density plasma creates higher hydrocarbons when charged particles impact the surfaces at grazing incidence. The production Of C{sub 2} to C{sub 8}-containing gases was noted, with a selectivity for C{sub 2} of 39% in one case. The proportions of converted products and the conversion rates depend upon the electrical voltage, the microchannel geometry, and the operating pressure. Conversion rates increase with operating pressure.

Sackinger, W.M.

1992-07-01T23:59:59.000Z

410

Plasma-induced conversion of surface-adsorbed hydrocarbons  

DOE Green Energy (OSTI)

Experimental results are reported for an electrical device for direct conversion of methane into higher hydrocarbons. A microchannel plate is excited with electrons from a photoemissive source, and electron impact ionization of methane on the inner surfaces of the microchannels creates an ion feedback process. The resulting low-density plasma creates higher hydrocarbons when charged particles impact the surfaces at grazing incidence. The production Of C{sub 2} to C{sub 8}-containing gases was noted, with a selectivity for C{sub 2} of 39% in one case. The proportions of converted products and the conversion rates depend upon the electrical voltage, the microchannel geometry, and the operating pressure. Conversion rates increase with operating pressure.

Sackinger, W.M.

1992-01-01T23:59:59.000Z

411

Catalysts for conversion of methane to higher hydrocarbons  

DOE Patents (OSTI)

Catalysts for converting methane to higher hydrocarbons such as ethane and ethylene in the presence of oxygen at temperatures in the range of about 700.degree. to 900.degree. C. are described. These catalysts comprise calcium oxide or gadolinium oxide respectively promoted with about 0.025-0.4 mole and about 0.1-0.7 mole sodium pyrophosphate. A preferred reaction temperature in a range of about 800.degree. to 850.degree. C. with a preferred oxygen-to-methane ratio of about 2:1 provides an essentially constant C.sub.2 hydrocarbon yield in the range of about 12 to 19 percent over a period of time greater than about 20 hours.

Siriwardane, Ranjani V. (Morgantown, WV)

1993-01-01T23:59:59.000Z

412

Aryl hydrocarbon mono-oxygenase activity in human lymphocytes  

SciTech Connect

Aryl hydrocarbon mono-oxygenase (AHM), an enzyme of key importance in metabolism of xenobiotic chemicals such as polynuclear aromatic hydrocarbons (PNA), is present in human lymphocytes. Studies investing the relation of activity of AHM in human lymphocytes to parameters such as disease state, PNA exposure, in vitro mitogen stimulation, etc. have been summarized in this report. Some studies have demonstrated increased AHM activity in lymphocytes from cigarette smokers (compared to nonsmokers), and in lung cancer patients when compared to appropriate control groups. These observations are confused by extreme variability in human lymphocyte AHM activities, such variability arising from factors such as genetic variation in AHM activity, variation in in vitro culture conditions which affect AHM activity, and the problematical relationship of common AHM assays to actual PNA metabolism taking place in lymphocytes. If some of the foregoing problems can be adequately addressed, lymphocyte AHM activity could hold the promise of being a useful biomarker system for human PNA exposure.

Griffin, G.D.; Schuresko, D.D.

1981-06-01T23:59:59.000Z

413

Catalysts for conversion of methane to higher hydrocarbons  

DOE Patents (OSTI)

Catalysts for converting methane to higher hydrocarbons such as ethane and ethylene in the presence of oxygen at temperatures in the range of about 700 to 900{degrees}C are described. These catalysts comprise calcium oxide or gadolinium oxide respectively promoted with about 0.025--0.4 mole and about 0.1--0.7 mole sodium pyrophosphate. A preferred reaction temperature in a range of about 800 to 850{degrees}C with a preferred oxygen-to-methane ratio of about 2:1 provides an essentially constant C{sub 2} hydrocarbon yield in the range of about 12 to 19 percent over a period of time greater than about 20 hours.

Siriwardane, R.V.

1991-05-15T23:59:59.000Z

414

Environmental Distribution of Petroleum Hydrocarbons at a Utility Service Center  

Science Conference Proceedings (OSTI)

This report presents the results of a field study at a utility service center located in western New York where a petroleum product had leaked into the subsurface over a number of years. The study was a tailored collaboration effort between the Electric Power Research Institute (EPRI) and the Niagara Mohawk Power Corporation, aimed at delineating the nature and extent of migration of the dissolved hydrocarbons. The information is of interest to many utilities as they develop and implement management prac...

1999-06-30T23:59:59.000Z

415

Production of valuable hydrocarbons by flash pyrolysis of oil shale  

DOE Patents (OSTI)

A process for the production of gas and liquid hydrocarbons from particulated oil shale by reaction with a pyrolysis gas at a temperature of from about 700/sup 0/C to about 1100/sup 0/C, at a pressure of from about 400 psi to about 600 psi, for a period of about 0.2 second to about 20 seconds. Such a pyrolysis gas includes methane, helium, or hydrogen. 3 figs., 3 tabs.

Steinberg, M.; Fallon, P.T.

1985-04-01T23:59:59.000Z

416

Determining Polycyclic Aromatic Hydrocarbon (PAH) Background in Sediments  

Science Conference Proceedings (OSTI)

Sediment remediation challenges at former manufactured gas plant (MGP) sites include defining sediment remedial zones, establishing risk-based remedial goals for specific polycyclic aromatic hydrocarbons (PAHs), and determining background conditions in what are often highly industrialized waterways. This technical update describes the various tools and approaches developed over approximately the past decade to determine site-specific background PAH concentrations in sediments attributable to ...

2012-11-14T23:59:59.000Z

417

Irregular spacing of heat sources for treating hydrocarbon containing formations  

SciTech Connect

A method for treating a hydrocarbon containing formation includes providing heat input to a first section of the formation from one or more heat sources located in the first section. Fluids are produced from the first section through a production well located at or near the center of the first section. The heat sources are configured such that the average heat input per volume of formation in the first section increases with distance from the production well.

Miller, David Scott (Katy, TX); Uwechue, Uzo Philip (Houston, TX)

2012-06-12T23:59:59.000Z

418

Conversion of ethane and of propane to higher olefin hydrocarbons  

DOE Green Energy (OSTI)

It has become apparent during the past few months that results obtained in the oxidative coupling of methane cannot be extended to ethane and propane. Good selectivities and yields for the oxydehydrogenation to olefins can be obtained but production of higher hydrocarbons is small. The present report summarizes results of experiments using zeolite based catalysts and compares these with basic oxide catalysts. The oxydehydrogenation of ethane over zeolite based catalysts (H[sup [minus plus

Heinemann, H.; Somorjai, G.A.

1992-09-01T23:59:59.000Z

419

Aerobic microorganism for the degradation of chlorinated aliphatic hydrocarbons  

DOE Patents (OSTI)

A chlorinated aliphatic hydrocarbon-degrading microorganism, having American Type Culture Collection accession numbers ATCC 53570 and 53571, in a biologically pure culture aseptically collected from a deep subsurface habitat and enhanced, mineralizes trichloroethylene and tetrachloroethylene to HCl, H.sub.2 O and Co.sub.2 under aerobic conditions stimulated by methane, acetate, methanol, tryptone-yeast extract, propane and propane-methane.

Fliermans, Carl B. (Augusta, GA)

1989-01-01T23:59:59.000Z

420

Aerobic microorganism for the degradation of chlorinated aliphatic hydrocarbons  

DOE Patents (OSTI)

This invention pertains to a chlorinated aliphatic hydrocarbon-degrading microorganism, having American Type Culture Collection accession numbers ATCC 53570 and 53571, in a biologically pure culture aseptically collected from a deep subsurface habitat and enhanced, mineralizes trichloroethylene and tetrachloroethylene to HCl, H{sub 2}O and CO{sub 2} under aerobic conditions stimulated by methane, acetate, methanol, tryptone-yeast extract, propane and propane-methane.

Fliermans, C.B.

1988-10-12T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Prioritizing and scheduling Portsmouth Gaseous Diffusion Plant safeguards upgrades. Final report  

Science Conference Proceedings (OSTI)

As part of the Site Safeguards and Security Plan (SSSP), facilities are required to develop a Resource Plan (RP). The Resource Plan provides documentation and justification for the facility`s planned upgrades, including the schedule, priority, and cost estimates for the safeguards and security upgrades. Portsmouth Gaseous Diffusion Plant (PORTS) management has identified and obtained funding approval for a number of safeguards and security upgrades, including line-item construction projects. These upgrade projects were selected to address a variety of concerns identified in the PORTS vulnerability assessments and other reviews performed in support of the SSSP process. However, budgeting and scheduling constraints do not make it possible to simultaneously begin implementation of all of the upgrade projects. A formal methodology and analysis are needed to explicitly address the trade-offs between competing safeguards objectives, and to prioritize and schedule the upgrade projects to ensure that the maximum benefit can be realized in the shortest possible time frame. The purpose of this report is to describe the methodology developed to support these upgrade project scheduling decisions. The report also presents the results obtained from applying the methodology to a set of the upgrade projects selected by PORTS S&S management. Data for the analysis are based on discussions with personnel familiar with the PORTS safeguards and security needs, the requirements for implementing these upgrades, and upgrade funding limitations. The analysis results presented here assume continued highly enriched uranium (HEU) operations at PORTS. However, the methodology developed is readily adaptable for the evaluation of other operational scenarios and other resource allocation issues relevant to PORTS.

Edmunds, T.; Saleh, R.; Zevanove, S.

1992-02-01T23:59:59.000Z

422

Uranium hexafluoride packaging tiedown systems overview at Portsmouth Gaseous Diffusion Plant, Piketon, Ohio. Revision 1  

SciTech Connect

The Portsmouth Gaseous Diffusion Plant (PORTS) in Piketon, Ohio, is operated by Martin Marietta Energy Systems, Inc., through the US Department of Energy-Oak Ridge Operations Office (DOE-ORO) for the US Department of Energy-Headquarters, Office of Nuclear Energy. The PORTS conducts those operations that are necessary for the production, packaging, and shipment of uranium hexafluoride (UF{sub 6}). Uranium hexafluoride enriched uranium than 1.0 wt percent {sup 235}U shall be packaged in accordance with the US Department of Transportation (DOT) regulations of Title 49 CFR Parts 173 (Reference 1) and 178 (Reference 2), or in US Nuclear Regulatory Commission (NRC) or US Department of Energy (DOE) certified package designs. Concerns have been expressed regarding the various tiedown methods and condition of the trailers being used by some shippers/carriers for international transport of the UF{sub 6} cylinders/overpacks. Because of the concerns about international shipments, the US Department of Energy-Headquarters (DOE-HQ) Office of Nuclear Energy, through DOE-HQ Transportation Management Division, requested Westinghouse Hanford Company (Westinghouse Hanford) to review UF{sub 6} packaging tiedown and shipping practices used by PORTS, and where possible and appropriate, provide recommendations for enhancing these practices. Consequently, a team of two individuals from Westinghouse Hanford visited PORTS on March 5 and 6, 1990, for the purpose of conducting this review. The paper provides a brief discussion of the review activities and a summary of the resulting findings and recommendations. A detailed reporting of the is documented in Reference 4.

Becker, D.L.; Green, D.J.; Lindquist, M.R.

1993-07-01T23:59:59.000Z

423

Modifying woody plants for efficient conversion to liquid and gaseous fuels  

DOE Green Energy (OSTI)

The Short Rotation Woody Crop Program (SRWCP), Department of Energy, is developing woody plant species as sources of renewable energy. Much progress has been made in identifying useful species, and testing site adaptability, stand densities, coppicing abilities, rotation lengths, and harvesting systems. Conventional plant breeding and intensive cultural practices have been used to increase above-ground biomass yields. Given these and foreseeable accomplishments, program leaders are now shifting attention to prospects for altering biomass physical and chemical characteristics, and to ways for improving the efficiency with which biomass can be converted to gaseous and liquid fuels. This report provides a review and synthesis of literature concerning the quantity and quality of such characteristics and constituents, and opportunities for manipulating them via conventional selection and breeding and/or molecular biology. Species now used by SRWCP are emphasized, with supporting information drawn from others as needed. Little information was found on silver maple (Acer saccharinum), but general comparisons (Isenberg 1981) suggest composition and behavior similar to those of the other species. Where possible, conclusions concerning means for and feasibility of manipulation are given, along with expected impacts on conversion efficiency. Information is also provided on relationships to other traits, genotype X environment interactions, and potential trade-offs or limitations. Biomass productivity per se is not addressed, except in terms of effects that may by caused by changes in constituent quality and/or quantity. Such effects are noted to the extent they are known or can be estimated. Likely impacts of changes, however effected, on suitability or other uses, e.g., pulp and paper manufacture, are notes. 311 refs., 4 figs., 9 tabs.

Dinus, R.J.; Dimmel, D.R.; Feirer, R.P.; Johnson, M.A.; Malcolm, E.W. (Institute of Paper Science and Technology, Atlanta, GA (USA))

1990-07-01T23:59:59.000Z

424

Challenge for Mesozoic hydrocarbon exploration in the Eastern Indonesia  

Science Conference Proceedings (OSTI)

The eastern part of Indonesia covers approximately 3 million square kilometers, 35 percent being landmass and 65 percent covered by ocean. Only three of 38 sedimentary basins are producing hydrocarbon (Salawati, Bintuni, and Seram Basins). Oil and gas have discovered in the Lariang, Bone, Timor, Banggai, Sula and Biak Basins, however the discoveries have not developed yet. Hydrocarbon systems in Northern Australia and Papua New Guinea give the major contributions to the geological idea of Pre-Tertiary section in the less explored area in the Eastern Indonesia. The Triassic-Middle Jurassic marine carbonaceous shale sequences are the main hydrocarbon source rock in the Irian Jaya and surrounding area (Buton, gula and Seram basins). The main Mesozoic reservoir are the Kembelangan Formation in the Bintuni Basin of Irian Jaya and Bobong Formation in the North Sula Region. Exploration play types in the Eastern Indonesia can be divided into five types: 1 - Peri Cratonic, 2 - Marginal Rift Graben, 3 - Thrust Fold Belt Island Arc, 4 - Early Collision and 5 -Microcontinental Block - Advanced Collision. Recent discoveries through Mesozoic section in Eastern Indonesia are: Roabiba-1 (1990) in Bintuni Basin-Irian Jaya (Kambelangan Formation); Loku- 1 (1990) in North Sula region (Pre-Tertiary sediments); Oseil-1 (1993/94) in Bula-Seram Basin (Jurassic Manusela Formation); Elang-1 (1 994); Kakaktua-1 (1994) and Laminaria-1 in North Bonaparte Basin (Upper Jurassic Sands).

Abdullah, S.; Rukmiati, M.G.; Sitompul, N. (Pertamina Exploration and Production, Jakarta (Indonesia))

1996-01-01T23:59:59.000Z

425

Method for production of hydrocarbon diluent from heavy crude oil  

Science Conference Proceedings (OSTI)

This patent describes a method of producing a hydrocarbon diluent from a heavy crude oil extracted from an underground petroleum formation via a production well. It comprises: preheating a quantity of heavy crude oil extracted from the production well to yield a heated crude oil; separating in a separator vessel by flashing the heated crude oil to produce a first vapor fraction and a first liquid fraction; thermally cracking in a cracking unit at least a portion of the first liquid fraction to produce a first liquid effluent; quenching the first liquid effluent; introducing at least a portion of the quenched fist liquid effluent into a separator; condensing the first vapor fraction; separating in a separator vessel the condensed vapor fraction to produce a liquid hydrocarbon diluent middle fraction characterized in having a boiling range between about 400{degrees}-700{degrees}F. and a gas; and, directing the liquid hydrocarbon diluent into the formation via an injection well for enhancing production of petroleum from the formation via the production well.

McCants, M.F.

1992-05-05T23:59:59.000Z

426

Hydrocarbon reforming catalyst material and configuration of the same  

DOE Patents (OSTI)

A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall. 5 figs.

Singh, P.; Shockling, L.A.; George, R.A.; Basel, R.A.

1996-06-18T23:59:59.000Z

427

Hydrocarbon reforming catalyst material and configuration of the same  

DOE Patents (OSTI)

A hydrocarbon reforming catalyst material comprising a catalyst support impregnated with catalyst is provided for reforming hydrocarbon fuel gases in an electrochemical generator. Elongated electrochemical cells convert the fuel to electrical power in the presence of an oxidant, after which the spent fuel is recirculated and combined with a fresh hydrocarbon feed fuel forming the reformable gas mixture which is fed to a reforming chamber containing a reforming catalyst material, where the reforming catalyst material includes discrete passageways integrally formed along the length of the catalyst support in the direction of reformable gas flow. The spent fuel and/or combusted exhaust gases discharged from the generator chamber transfer heat to the catalyst support, which in turn transfers heat to the reformable gas and to the catalyst, preferably via a number of discrete passageways disposed adjacent one another in the reforming catalyst support. The passageways can be slots extending inwardly from an outer surface of the support body, which slots are partly defined by an exterior confining wall. According to a preferred embodiment, the catalyst support is non-rigid, porous, fibrous alumina, wherein the fibers are substantially unsintered and compressible, and the reforming catalyst support is impregnated, at least in the discrete passageways with Ni and MgO, and has a number of internal slot passageways for reformable gas, the slot passageways being partly closed by a containing outer wall.

Singh, Prabhakar (Export, PA); Shockling, Larry A. (Plum Borough, PA); George, Raymond A. (Pittsburgh, PA); Basel, Richard A. (Plub Borough, PA)

1996-01-01T23:59:59.000Z

428

Thermocatalytic CO2-Free Production of Hydrogen from Hydrocarbon Fuels  

DOE Green Energy (OSTI)

The main objective of this project is the development of an economically viable thermocatalytic process for production of hydrogen and carbon from natural gas or other hydrocarbon fuels with minimal environmental impact. The three major technical goals of this project are: (1) to accomplish efficient production of hydrogen and carbon via sustainable catalytic decomposition of methane or other hydrocarbons using inexpensive and durable carbon catalysts, (2) to obviate the concurrent production of CO/CO{sub 2} byproducts and drastically reduce CO{sub 2} emissions from the process, and (3) to produce valuable carbon products in order to reduce the cost of hydrogen production The important feature of the process is that the reaction is catalyzed by carbon particulates produced in the process, so no external catalyst is required (except for the start-up operation). This results in the following advantages: (1) no CO/CO{sub 2} byproducts are generated during hydrocarbon decomposition stage, (2) no expensive catalysts are used in the process, (3) several valuable forms of carbon can be produced in the process depending on the process conditions (e.g., turbostratic carbon, pyrolytic graphite, spherical carbon particles, carbon filaments etc.), and (4) CO{sub 2} emissions could be drastically reduced (compared to conventional processes).

University of Central Florida

2004-01-30T23:59:59.000Z

429

Conversion of Biomass-Derived Furans into Hydrocarbon Fuels  

Science Conference Proceedings (OSTI)

One of the most studied chemical transformations of carbohydrates is their thermocatalytic dehydration to form furans. Cellulose-derived glucose is thereby converted into 5-hydroxymethylfurfuraldehyde (5-HMF), while the hemicellulose-derived pentoses (e.g., xylose, arabinose) form furfuraldehyde. Our objective is to identify new pathways to convert furfuryl alcohol into a mixture of aliphatic hydrocarbons that can be used as drop-in fuels for diesel (C10-20) and jet fuel (C9-16) blends. Furfuryl alcohol is produced commercially through hydrogenation of furfuraldehyde that is derived from hemicellulose-derived pentoses via acid-catalyzed dehydration. The steps that we are currently pursuing to convert furfuryl alcohol into hydrocarbons are 1) oligomerization of furfuryl alcohol to form dimers (C10) and trimers (C15), and 2) hydrotreatment of the dimers and trimers to produce a mixture of linear hydrocarbons with carbon chain lengths in the range of diesel and jet fuels. This presentation will discuss our progress in the development of this pathway.

Moens, L.; Johnson, D. K.

2013-01-01T23:59:59.000Z

430

Microphysical modeling of ultrane hydrocarbon-containing aerosols in aircraft emissions  

E-Print Network (OSTI)

Combustion engines emit precursors of ne particulate matter (PM) into the atmosphere. Numerous gaseous species, soot particles, and liquid aerosols in the aircraft exhaust are involved in PM formation, and these very ne, ...

Jun, Mina

2011-01-01T23:59:59.000Z

431

Seismic Evaluation of Hydrocarbon Saturation in Deep-Water Reservoirs  

SciTech Connect

During this last period of the ''Seismic Evaluation of Hydrocarbon Saturation in Deep-Water Reservoirs'' project (Grant/Cooperative Agreement DE-FC26-02NT15342), we finalized integration of rock physics, well log analysis, seismic processing, and forward modeling techniques. Most of the last quarter was spent combining the results from the principal investigators and come to some final conclusions about the project. Also much of the effort was directed towards technology transfer through the Direct Hydrocarbon Indicators mini-symposium at UH and through publications. As a result we have: (1) Tested a new method to directly invert reservoir properties, water saturation, Sw, and porosity from seismic AVO attributes; (2) Constrained the seismic response based on fluid and rock property correlations; (3) Reprocessed seismic data from Ursa field; (4) Compared thin layer property distributions and averaging on AVO response; (5) Related pressures and sorting effects on porosity and their influence on DHI's; (6) Examined and compared gas saturation effects for deep and shallow reservoirs; (7) Performed forward modeling using geobodies from deepwater outcrops; (8) Documented velocities for deepwater sediments; (9) Continued incorporating outcrop descriptive models in seismic forward models; (10) Held an open DHI symposium to present the final results of the project; (11) Relations between Sw, porosity, and AVO attributes; (12) Models of Complex, Layered Reservoirs; and (14) Technology transfer Several factors can contribute to limit our ability to extract accurate hydrocarbon saturations in deep water environments. Rock and fluid properties are one factor, since, for example, hydrocarbon properties will be considerably different with great depths (high pressure) when compared to shallow properties. Significant over pressure, on the other hand will make the rocks behave as if they were shallower. In addition to the physical properties, the scale and tuning will alter our hydrocarbon indicators. Gas saturated reservoirs change reflection amplitudes significantly. The goal for the final project period was to systematically combine and document these various effects for use in deep water exploration and transfer this knowledge as clearly and effectively as possible.

Michael Batzle

2006-04-30T23:59:59.000Z

432

Safeguards Verification Measurements using Laser Ablation, Absorbance Ratio Spectrometry in Gaseous Centrifuge Enrichment Plants  

Science Conference Proceedings (OSTI)

Laser Ablation Absorbance Ratio Spectrometry (LAARS) is a new verification measurement technology under development at the US Department of Energys (DOE) Pacific Northwest National Laboratory (PNNL). LAARS uses three lasers to ablate and then measure the relative isotopic abundance of uranium compounds. An ablation laser is tightly focused on uranium-bearing solids producing a small plume containing uranium atoms. Two collinear wavelength-tuned spectrometry lasers transit through the plume and the absorbance of U-235 and U-238 isotopes are measured to determine U-235 enrichment. The measurement has high relative precision and detection limits approaching the femtogram range for uranium. It is independent of chemical form and degree of dilution with nuisance dust and other materials. High speed sample scanning and pinpoint characterization allow measurements on millions of particles/hour to detect and analyze the enrichment of trace uranium in samples. The spectrometer is assembled using commercially available components at comparatively low cost, and features a compact and low power design. Future designs can be engineered for reliable, autonomous deployment within an industrial plant environment. Two specific applications of the spectrometer are under development: 1) automated unattended aerosol sampling and analysis and 2) on-site small sample destructive assay measurement. The two applications propose game-changing technological advances in gaseous centrifuge enrichment plant (GCEP) safeguards verification. The aerosol measurement instrument, LAARS-environmental sampling (ES), collects aerosol particles from the plant environment in a purpose-built rotating drum impactor and then uses LAARS-ES to quickly scan the surface of the impactor to measure the enrichments of the captured particles. The current approach to plant misuse detection involves swipe sampling and offsite analysis. Though this approach is very robust it generally requires several months to obtain results from a given sample collection. The destructive assay instrument, LAARS-destructive assay (DA), uses a simple purpose-built fixture with a sampling planchet to collect adsorbed UF6 gas from a cylinder valve or from a process line tap or pigtail. A portable LAARS-DA instrument scans the microgram quantity of uranium collected on the planchet and the assay of the uranium is measured to ~0.15% relative precision. Currently, destructive assay samples for bias defect measurements are collected in small sample cylinders for offsite mass spectrometry measurement.

Anheier, Norman C.; Cannon, Bret D.; Qiao, Hong (Amy); Phillips, Jon R.

2012-07-01T23:59:59.000Z

433

Design of an Unattended Environmental Aerosol Sampling and Analysis System for Gaseous Centrifuge Enrichment Plants  

Science Conference Proceedings (OSTI)

The resources of the IAEA continue to be challenged by the rapid, worldwide expansion of nuclear energy production. Gaseous centrifuge enrichment plants (GCEPs) represent an especially formidable dilemma to the application of safeguard measures, as the size and enrichment capacity of GCEPs continue to escalate. During the early part of the 1990's, the IAEA began to lay the foundation to strengthen and make cost-effective its future safeguard regime. Measures under Part II of 'Programme 93+2' specifically sanctioned access to nuclear fuel production facilities and environmental sampling by IAEA inspectors. Today, the Additional Protocol grants inspection and environmental sample collection authority to IAEA inspectors at GCEPs during announced and low frequency unannounced (LFUA) inspections. During inspections, IAEA inspectors collect environmental swipe samples that are then shipped offsite to an analytical laboratory for enrichment assay. This approach has proven to be an effective deterrence to GCEP misuse, but this method has never achieved the timeliness of detection goals set forth by IAEA. Furthermore it is questionable whether the IAEA will have the resources to even maintain pace with the expansive production capacity of the modern GCEP, let alone improve the timeliness in reaching current safeguards conclusions. New safeguards propositions, outside of familiar mainstream safeguard measures, may therefore be required that counteract the changing landscape of nuclear energy fuel production. A new concept is proposed that offers rapid, cost effective GCEP misuse detection, without increasing LFUA inspection access or introducing intrusive access demands on GCEP operations. Our approach is based on continuous onsite aerosol collection and laser enrichment analysis. This approach mitigates many of the constraints imposed by the LFUA protocol, reduces the demand for onsite sample collection and offsite analysis, and overcomes current limitations associated with the in-facility misuse detection devices. Onsite environmental sample collection offers the ability to collect fleeting uranium hexafluoride emissions before they are lost to the ventilation system or before they disperse throughout the facility, to become deposited onto surfaces that are contaminated with background and historical production material. Onsite aerosol sample collection, combined with enrichment analysis, provides the unique ability to quickly detect stepwise enrichment level changes within the facility, leading to a significant strengthening of facility misuse deterence. We report in this paper our study of several GCEP environmental sample release scenarios and simulation results of a newly designed aerosol collection and particle capture system that is fully integrated with the Laser Ablation, Absorbance Ratio Spectrometry (LAARS) uranium particle enrichment analysis instrument that was developed at the Pacific Northwest National Laboratory.

Anheier, Norman C.; Munley, John T.; Alexander, M. L.

2011-07-19T23:59:59.000Z

434

Advanced Laser Diagnostics Development for the Characterization of Gaseous High Speed Flows  

E-Print Network (OSTI)

The study of high-speed flows represents a challenging problem in the fluid dynamics field due to the presence of chemical reactions and non-equilibrium effects. Hypersonic flights, where speeds reach Mach 5 and above, are particularly influenced by these effects, resulting in a direct impact on the flow and consequently on the aerodynamic performance of a vehicle traveling at these speeds. The study of hypersonic flow conditions requires the experimental capability of determining local temperatures, pressures and velocities using non-intrusive techniques. Furthermore, the simultaneous measurement of two or more variables in a complex flow boosts the amount of information that is obtained since valuable correlations can be established. This research includes the design, construction and characterization of a hypersonic flow apparatus explicitly intended as a tool for advanced laser diagnostics development. This apparatus is characterized by its pulsed operation mode that translates into a significant reduction in mass flow rates and can be operated for long periods at Mach numbers ranging from 2.8 to 6.2. The flow conditions during the uniform flow time interval of each pulse vary by less than 1%, generating a flow of sufficient quality for quantitative measurements. The development of a laser diagnostic technique, the VENOM technique, which is a non-intrusive method to provide simultaneous 2-D measurements of the mean and instantaneous fluctuations in two-component velocity and temperature is also presented. This technique represents the first single diagnostic capable of instantaneous two-component velocimetry and thermometry in a gaseous flow field by combining two Nitric Oxide Planar Laser Induced Fluorescence methods: two-component Molecular Tagging Velocimetry and two-line thermometry, employing the nascent NO(v"=1) arising from the NO2 photodissociation as a molecular tracer. The VENOM technique is expected to be not only applicable to cold high-speed flows, which is the focus of the present work, but also to combustion and other reactive or high-enthalpy flow fields.

Sanchez-Gonzalez, Rodrigo

2012-05-01T23:59:59.000Z

435

Method for direct production of carbon disulfide and hydrogen from hydrocarbons and hydrogen sulfide feedstock  

DOE Patents (OSTI)

A method for converting hydrocarbons and hydrogen sulfide to carbon disulfide and hydrogen is provided comprising contacting the hydrocarbons and hydrogen sulfide to a bi-functional catalyst residing in a controlled atmosphere for a time and at a temperature sufficient to produce carbon disulfide and hydrogen. Also provided is a catalyst for converting carbon sulfides and hydrogen sulfides to gasoline range hydrocarbons comprising a mixture containing a zeolite catalyst and a hydrogenating catalyst.

Miao, Frank Q.; Erekson, Erek James

1998-12-01T23:59:59.000Z

436

Effect of temperature on wave velocities in sands and sandstones with heavy hydrocarbons  

SciTech Connect

A laboratory investigation was made of the effects of temperature on wave velocities in well cemented Massillon and Boise sandstones and unconsolidated Ottawa sand saturated with heavy hydrocarbons, as well as the dependence of compressional velocities in the hydrocarbons themselves as a function of temperature. The hydrocarbons selected as pore saturants were a commercial paraffin wax, 1-Eicosene, natural heavy crude, and natural tar. The experimental results show that the compressional wave velocities in the hydrocarbons decrease markedly with increasing temperature. In contrast wave velocities in the Massillon and Boise sandstones and unconsolidated Ottawa sand saturated with air or water decrease only little with increasing temperatures. The main reason for the large decreases in rocks with hydrocarbons is the melting of solid hydrocarbons, and high pore pressure. Thermal expansion of the saturants, and possibly thermal cracking of the heavy fractions and vaporization of the light fractions of the hydrocarbons may also contribute. The large decreases of the compressional and shear wave velocities in the hydrocarbon-saturated rocks and sands with temperature, suggest that seismic measurements such as used in seismology or borehole tomography may be very useful in detecting steam fronts in heavy hydrocarbon reservoirs undergoing steam flooding.

Wang, Z.; Nur, A.M.

1986-01-01T23:59:59.000Z

437

Catalytic conversion of C3+ alcohols to hydrocarbon blend-stock  

Catalytic conversion of C3+ alcohols to hydrocarbon blend-stock Note: The technology described above is an early stage opportunity. Licensing rights to this ...

438

Rare earth elements (REE) as geochemical clues to reconstruct hydrocarbon generation history.  

E-Print Network (OSTI)

??The REE distribution patterns and total concentrations of the organic matter of the Woodford shale reveal a potential avenue to investigate hydrocarbon maturation processes in (more)

Ramirez-Caro, Daniel

2013-01-01T23:59:59.000Z

439

Hydrocarbon solubility and its migration processes: a look at the present status  

DOE Green Energy (OSTI)

In this study we review the present status of knowledge of solubility of hydrocarbons and its implications on primary migration processes. The intent is to examine the solubility and the transportation mechanisms relevant to geopressured-geothermal reservoirs, although the discussion included here accommodates a wide range of related aspects. Influences of parameters associated with hydrocarbon (especially methane) solubility have been studied. We have sought to evaluate several primary hydrocarbon migration processes and to point out their attractive features as well as their limitations. A brief discussion of hydrocarbon generation processes is also included.

Mamun, C.K.; Ohkuma, H.; Sepehrnoori, K.

1985-12-01T23:59:59.000Z

440

Two decades of hydrocarbon exploration activity in Indonesia  

SciTech Connect

During the past two decades, hydrocarbon exploration activity within Indonesia has been based on the Indonesian Energy Policy, aims of which include intensifying and expanding hydrocarbon exploration programs. Expansion into the offshore regions of the nation has resulted in the discovery of petroliferous basins. The first offshore oil production came on stream in 1971. Since then, significant achievements have been made in developing these resources. Intensified onshore exploration has resulted in additional oil fields being discovered in these more mature areas. Among the significant gas fields discovered during the past 20 years, Arun and Badak both supply major LNG projects. Oil fields have been found in the onshore areas of Sumatra, Kalimantan, Java, and Irian Jaya, and in the offshore areas around West Java, Madura, Natuna, and East Kalimantan. The exploration drilling success during this time has been approximately 32%. In addition, the ratio of oil field development to these discoveries is about 54%. For technical and economic reasons, not all discoveries can be developed into oil fields. Recently, Pertamina's Research and Development Division organized the study of data contributed by Pertamina exploration, foreign contractors, and science institutes. This study reveals that 60 basins are spread throughout the onshore and offshore areas of the nation. Using PAUS (plan and analysis of uncertainty situation), a Monte Carolo simulation program, the hydrocarbon potential of each basin has been estimated. These estimates will be continually revised as more data are made available to the study, as the geology of Indonesia is better understood in terms of plate tectonic theory, and as computing techniques improve.

Suardy, A.; Taruno, J.; Simbolon, P.H.; Simbolon, B.

1986-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Novel metalloporphyrin catalysts for the oxidation of hydrocarbons  

DOE Green Energy (OSTI)

Work was done for developing biomimetic oxidation catalysts. Two classes of metalloporphyrin catalysts were studied. The first class of catalysts studied were a novel series of highly substituted metalloporphyrins, the fluorinated iron dodecaphenylporphyrins. These homogeneous metalloporphyrin catalysts were screened for activity as catalysts in the oxidation of hydrocarbons by dioxygen. Results are discussed with respect to catalyst structural features. The second type of catalysts studied were heterogeneous catalysts consisting of metalloporphyrins applied to inorganic supports. Preliminary catalytic testing results with these materials are presented.

Showalter, M.C.; Nenoff, T.M.; Shelnutt, J.A.

1996-11-01T23:59:59.000Z

442

Polycyclic Aromatic Hydrocarbons (PAHS) in Surface Soil in Illinois  

Science Conference Proceedings (OSTI)

One hundred sixty soil samples were collected and analyzed from sites in the State of Illinois as part of EPRI's nationwide study of polycyclic aromatic hydrocarbons (PAHs) in surface soil. The samples were collected from 10 pseudo-randomly selected locations in 16 pseudo-randomly selected populated areas throughout the State, excluding the City of Chicago. At each location, the soils were logged and samples were collected from 0 to 15 cm below ground surface. At the laboratory, the soil samples were ana...

2004-12-27T23:59:59.000Z

443

The Radiochemical Analysis of Gaseous Samples (RAGS) apparatus for nuclear diagnostics at the National Ignition Facility (invited)  

SciTech Connect

The Radiochemical Analysis of Gaseous Samples (RAGS) diagnostic apparatus was recently installed at the National Ignition Facility (NIF). Following a NIF shot, RAGS is used to pump the gas load from the NIF chamber for purification and isolation of the noble gases. After collection, the activated gaseous species are counted via gamma spectroscopy for measurement of the capsule areal density and fuel-ablator mix. Collection efficiency was determined by injecting a known amount of {sup 135}Xe into the NIF chamber, which was then collected with RAGS. Commissioning was performed with an exploding pusher capsule filled with isotopically enriched {sup 124}Xe and {sup 126}Xe added to the DT gas fill. Activated xenon species were recovered post-shot and counted via gamma spectroscopy. Results from the collection and commissioning tests are presented. The performance of RAGS allows us to establish a noble gas collection method for measurement of noble gas species produced via neutron and charged particle reactions in a NIF capsule.

Shaughnessy, D. A.; Velsko, C. A.; Jedlovec, D. R.; Yeamans, C. B.; Moody, K. J.; Tereshatov, E.; Stoeffl, W.; Riddle, A. [Lawrence Livermore National Laboratory, PO Box 808, L-236, Livermore, California 94551 (United States)

2012-10-15T23:59:59.000Z

444

Hydrous metal oxide catalysts for oxidation of hydrocarbons  

DOE Green Energy (OSTI)

This report describes work performed at Sandia under a CRADA with Shell Development of Houston, Texas aimed at developing hydrous metal oxide (HMO) catalysts for oxidation of hydrocarbons. Autoxidation as well as selective oxidation of 1-octene was studied in the presence of HMO catalysts based on known oxidation catalysts. The desired reactions were the conversion of olefin to epoxides, alcohols, and ketones, HMOs seem to inhibit autoxidation reactions, perhaps by reacting with peroxides or radicals. Attempts to use HMOs and metal loaded HMOs as epoxidation catalysts were unsuccessful, although their utility for this reaction was not entirely ruled out. Likewise, alcohol formation from olefins in the presence of HMO catalysts was not achieved. However, this work led to the discovery that acidified HMOs can lead to carbocation reactions of hydrocarbons such as cracking. An HMO catalyst containing Rh and Cu that promotes the reaction of {alpha}-olefins with oxygen to form methyl ketones was identified. Although the activity of the catalyst is relatively low and isomerization reactions of the olefin simultaneously occur, results indicate that these problems may be addressed by eliminating mass transfer limitations. Other suggestions for improving the catalyst are also made. 57 refs.

Miller, J.E.; Dosch, R.G.; McLaughlin, L.I. [Sandia National Labs., Albuquerque, NM (United States). Process Research Dept.

1993-07-01T23:59:59.000Z

445

Energy Conservation Opportunities in Hydrocarbon Resin Manufacturing Facilities  

E-Print Network (OSTI)

"The results of a plant-wide assessment of the manufacturing facilities of Neville Chemical Company, a manufacturer of hydrocarbon resins will be presented in this paper. The project was co-funded by US Department of Energy under its Plant-Wide Opportunity Assessment Program. Resin manufacturing is a highly energy intensive process. The process needs extensive heating accomplished through steam boilers and thermal oil heaters, and cooling which is accomplished through refrigeration as well as process cooling water systems. Detailed energy assessment of Neville Chemical plants has shown significant energy conservation opportunities. For the less capital-intensive measures, energy cost savings of 20% to 30% with paybacks of less than two years were identified. The identified measures can be easily replicated in similar facilities. In this paper, details of the processes in hydrocarbon resin production from an energy consumption viewpoint will be discussed, current prevalent practices in the industry will be elaborated, and potential measures for energy use and cost savings will be outlined."

Ganji, A. R.

2003-05-01T23:59:59.000Z

446

Flexible hydrogen plant utilizing multiple refinery hydrocarbon streams  

Science Conference Proceedings (OSTI)

Numerous processes are available to produce hydrogen, however, steam reforming is still the dominant and currently preferred process because it can economically process a variety of refinery feedstocks into hydrogen. This paper discusses the Air Products 88 MMSCFD hydrogen plant built by KTI, adjacent to Shell`s Martinez refinery, which utilizes up to eight separate refinery hydrocarbon streams as feed and fuel for the production of hydrogen in the steam reforming unit. The integration of refinery hydrocarbon purge streams, normally sent to fuel, allows greater flexibility in refinery operations and increases the overall refinery fuel efficiencies. The hydrogen plant also incorporates a number of process control design features to enhance reliability, such as two out of three voting systems, in-line sparing, and reduced bed PSA operation. The final section of the paper describes the environmental features of the plant required for operation in the Bay Area Air Quality Management District (BAAQMD). Air Products and KTI designed BACT features into the hydrogen plant to minimize emissions from the facility.

Kramer, K.A.; Patel, N.M. [Air Products and Chemicals Inc., Allentown, PA (United States); Sekhri, S. [Kinetics Technology International Corp., San Dimas, CA (United States); Brown, M.G. [Shell Oil Products Co., Martinez, CA (United States)

1996-12-01T23:59:59.000Z

447

Oxygen sensor for monitoring gas mixtures containing hydrocarbons  

DOE Patents (OSTI)

A gas sensor measures O.sub.2 content of a reformable monitored gas containing hydrocarbons H.sub.2 O and/or CO.sub.2, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system.

Ruka, Roswell J. (Pittsburgh, PA); Basel, Richard A. (Pittsburgh, PA)

1996-01-01T23:59:59.000Z

448

Mineralization of hydrocarbons in soils under decreasing oxygen availability  

SciTech Connect

Techniques for remediation of soils contaminated with hydrocarbons (HCs) can be improved when the factors that control the decomposition rate are identified. In this study, the effect of O{sub 2} availability on the decomposition rate of hydrocarbons in soils is examined. A kinetic second-order model with the O{sub 2} concentration and biomass concentration as rate-controlling variables is used to quantify HC decomposition, O{sub 2} consumption, and CO{sub 2} production. Concentrations O{sub 2} and CO{sub 2} are calculated analytically as a function of time in a three-phase closed system. These calculations are compared with measurements of repetitive O{sub 2}-depletion experiments in closed jars containing a layer of soil contaminated with HCs. About 80% of the HC decrease could be attributed to mineralization, while the other 20% was assumed to be converted into biomass and metabolites. After calibration, model calculations agree with the experimental results, which makes the concept of O{sub 2} concentration and biomass concentration as rate-controlling variables plausible. The parameter values that are obtained by calibration have a clear biochemical significance. It is concluded that attention has to be paid to the O{sub 2} supply in closed-jar experiments to avoid erroneous interpretation of the results. 34 refs., 5 figs., 4 tabs.

Freijer, J.I. [Univ. of Amsterdam (Netherlands)

1996-03-01T23:59:59.000Z

449

Reaction of Si(111) Surface with Saturated Hydrocarbon  

SciTech Connect

Reaction of Si(111) surface with saturated hydrocarbon such as methane (CH{sub 4}) and ethane (C{sub 2}H{sub 6}) was carried out in a gas source molecular beam epitaxy (GSMBE). After carbonization, structures formed on the surface were observed by in situ reflection high-energy electron diffraction (RHEED). Structures transition formed on the surface were 7x7, {delta}-7x7, 1x1, and SiC structures. In the case of CH{sub 4}, the Si surfaces were carbonized at 800 deg. C for 120 min (7.2x10{sup 4} L) with a W-filament of 2800 deg. C, and SiC layers were obtained. In the case of C{sub 2}H{sub 6}, the mixture of 7x7 and SiC structure was observed. Decomposition of hydrocarbon was characterized in quadrupole mass spectroscopy (QMS) measurements. An atomic force microscopy (AFM) image of the mixture of 7x7 and SiC shows a wandering shape. Whereas, the SiC layer shows a regular step. This result seems to be related to the different in the amount of CH{sub 3} molecules on the surface.

Suryana, Risa [Department of Physics, Faculty of Mathematics and Natural Sciences, Sebelas Maret University Jl. Ir. Sutami 36A Kentingan Surakarta 57126 (Indonesia); Nakahara, Hitoshi; Saito, Yahachi [Department of Quantum Engineering, Graduate School of Engineering, Nagoya University Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Ichimiya, Ayahiko [Department of Mathematical and Physical Science, Faculty of Science, Japan Women's University Mejirodai 2-8-1, Tokyo 112-8681 (Japan)

2011-12-10T23:59:59.000Z

450

Remedial evaluation of a UST site impacted with chlorinated hydrocarbons  

Science Conference Proceedings (OSTI)

During assessment and remedial planning of an underground storage tank (UST) site, it was discovered that chlorinated hydrocarbons were present. A network of selected wells were sampled for analysis of halogenated volatile organics and volatile organic compounds to determine the extent of constituents not traditionally associated with refined petroleum motor fuel products. The constituents detected included vinyl chloride, tetrachloroethylene (PCE), bromodichloromethane, and 2-chloroethylvinyl ether. These analytical data were evaluated as to what effect the nonpetroleum hydrocarbon constituents may have on the remedial approach utilized the site hydrogeologic properties to its advantage and took into consideration the residential nature of the impacted area. The geometry of the dissolved plume is very flat and broad, emanating from the site and extending downgradient under a residential area situated in a transmissive sand unit. Ground-water pumping was proposed from two areas of the dissolved plume including five wells pumping at a combined rate of 55 gallons per minute (gpm) at a downgradient position, and two wells on-site to remove free product and highly impacted ground water. Also, to assist in remediation of the dissolved plume and to control vapors, a bioventing system was proposed throughout the plume area.

Ilgner, B.; Rainey, E. (Geraghty and Miller, Inc., Oak Ridge, TN (United States)); Ball, M.; Schutt, M.

1993-10-01T23:59:59.000Z

451

Southern Mozambique basin: most promising hydrocarbon province offshore eat Africa  

Science Conference Proceedings (OSTI)

Recent offshore acquisition of 12,800 km (8,000 mi) of seismic reflection data, with gravity and magnetic profiles encompassing the southern half of the Mozambique basin, reveals new facets of the subsurface geology. Integrated interpretation of these new geophysical data with old well information results in the development of depositional and tectonic models that positively establish the hydrocarbon potential of the basin. The recent comprehensive interpretation affords the following conclusions. (1) Significant oil shows accompany wet gas discoveries suggest that the South Mozambique basin is a mature province, as the hydrocarbon associations imply thermogenic processes. (2) Super-Karoo marine Jurassic sequences have been encountered in Nhamura-1 well onshore from the application of seismic stratigraphy and well correlation. (3) Steeply dipping reflectors truncated by the pre-Cretaceous unconformity testify to significant tectonic activity preceding the breakup of Gondwanaland. Hence, preconceived ideas about the depth of the economic basement and the absence of mature source rocks of pre-Cretaceous age should be revised. (4) Wildcats in the vicinity of ample structural closures have not been, in retrospect, optimally positioned nor drilled to sufficient depth to test the viability of prospects mapped along a major offshore extension of the East African rift system delineated by this new survey.

De Buyl, M.; Flores, G.

1984-09-01T23:59:59.000Z

452

Catalytic autothermal reforming of hydrocarbon fuels for fuel cells.  

DOE Green Energy (OSTI)

Fuel cell development has seen remarkable progress in the past decade because of an increasing need to improve energy efficiency as well as to address concerns about the environmental consequences of using fossil fuel for producing electricity and for propulsion of vehicles [1]. The lack of an infrastructure for producing and distributing H{sub 2} has led to a research effort to develop on-board fuel processing technology for reforming hydrocarbon fuels to generate H{sub 2} [2]. The primary focus is on reforming gasoline, because a production and distribution infrastructure for gasoline already exists to supply internal combustion engines [3]. Existing reforming technology for the production of H{sub 2} from hydrocarbon feedstocks used in large-scale manufacturing processes, such as ammonia synthesis, is cost prohibitive when scaled down to the size of the fuel processor required for transportation applications (50-80 kWe) nor is it designed to meet the varying power demands and frequent shutoffs and restarts that will be experienced during normal drive cycles. To meet the performance targets required of a fuel processor for transportation applications will require new reforming reactor technology developed to meet the volume, weight, cost, and operational characteristics for transportation applications and the development of new reforming catalysts that exhibit a higher activity and better thermal and mechanical stability than reforming catalysts currently used in the production of H{sub 2} for large-scale manufacturing processes.

Krumpelt, M.; Krause, T.; Kopasz, J.; Carter, D.; Ahmed, S.

2002-01-11T23:59:59.000Z

453

Oxygen sensor for monitoring gas mixtures containing hydrocarbons  

DOE Patents (OSTI)

A gas sensor measures O{sub 2} content of a reformable monitored gas containing hydrocarbons, H{sub 2}O and/or CO{sub 2}, preferably in association with an electrochemical power generation system. The gas sensor has a housing communicating with the monitored gas environment and carries the monitored gas through an integral catalytic hydrocarbon reforming chamber containing a reforming catalyst, and over a solid electrolyte electrochemical cell used for sensing purposes. The electrochemical cell includes a solid electrolyte between a sensor electrode that is exposed to the monitored gas, and a reference electrode that is isolated in the housing from the monitored gas and is exposed to a reference gas environment. A heating element is also provided in heat transfer communication with the gas sensor. A circuit that can include controls operable to adjust operations via valves or the like is connected between the sensor electrode and the reference electrode to process the electrical signal developed by the electrochemical cell. The electrical signal varies as a measure of the equilibrium oxygen partial pressure of the monitored gas. Signal noise is effectively reduced by maintaining a constant temperature in the area of the electrochemical cell and providing a monitored gas at chemical equilibria when contacting the electrochemical cell. The output gas from the electrochemical cell of the sensor is fed back into the conduits of the power generating system. 4 figs.

Ruka, R.J.; Basel, R.A.

1996-03-12T23:59:59.000Z

454

Effect of temperature on wave velocities in sands and sandstones with heavy hydrocarbons  

SciTech Connect

A laboratory investigation was made of the effects of temperature on wave velocities in sandstones and unconsolidated sand saturated with heavy hydrocarbons. The large decreases of the compressional and shear velocities in such sandstones and sand with increasing temperature suggest that seismic methods may be very useful in detecting heat fronts in heavy hydrocarbon reservoirs undergoing steamflooding or in-situ combustion.

Wang, Z.; Nur, A.

1988-02-01T23:59:59.000Z

455

Process And Apparatus For Producing A Stream Of Inert Gases From A Hydrocarbon Fuel Source  

Science Conference Proceedings (OSTI)

An experimental research study involving an unconventional method of producing a stream of inert gases from common hydrocarbon fuel sources has been described. Design and processing science elements from several different scientific, engineering, and ... Keywords: design, engine, fuel, hydrocarbon, inert gas, process, production, system

F. W. Giacobbe

2004-08-01T23:59:59.000Z

456

The spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil Point, California  

E-Print Network (OSTI)

The spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil pollution sources. A field of strong hydrocarbon seepage offshore of Coal Oil Point near Santa Barbara in the Coal Oil Point field to measure directly the atmospheric gas flux from three seeps of varying size

California at Santa Barbara, University of

457

Massively-parallel electrical-conductivity imaging of hydrocarbons using the Blue Gene/L supercomputer  

E-Print Network (OSTI)

hydrocarbon, i.e. oil and gas, exploration, and are provenoil and gas reservoirs at the highest resolution possible, and on time scales acceptable to the explorationexploration in basin hydrocarbon systems including the subsurface visualization of earth resistivity volumes applied to oil and gas

2008-01-01T23:59:59.000Z

458

Evaluation of In Situ Remedial Technologies for Sites Contaminated With Hydrocarbons  

Science Conference Proceedings (OSTI)

Utility managers are faced at times with decision making regarding remediation of sites contaminated with petroleum hydrocarbons. This report, which presents the results of a survey of the literature on established and emerging technologies for in situ remediation of petroleum hydrocarbons, is intended to support such decision making.

1998-04-20T23:59:59.000Z

459

A study of hydrocarbons associated with brines from DOE geopressured wells  

DOE Green Energy (OSTI)

Accomplishments are summarized on the following tasks: distribution coefficients and solubilities, DOE design well sampling, analysis of well samples, review of theoretical models of geopressured reservoir hydrocarbons, monitor for aliphatic hydrocarbons, development of a ph meter probe, DOE design well scrubber analysis, removal and disposition of gas scrubber equipment at Pleasant Bayou Well, and disposition of archived brines.

Keeley, D.F.

1993-01-01T23:59:59.000Z

460

A study of hydrocarbons associated with brines from DOE geopressured wells. Final report  

DOE Green Energy (OSTI)

Accomplishments are summarized on the following tasks: distribution coefficients and solubilities, DOE design well sampling, analysis of well samples, review of theoretical models of geopressured reservoir hydrocarbons, monitor for aliphatic hydrocarbons, development of a ph meter probe, DOE design well scrubber analysis, removal and disposition of gas scrubber equipment at Pleasant Bayou Well, and disposition of archived brines.

Keeley, D.F.

1993-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "gaseous branch-chain hydrocarbon" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Numerical Simulation of Polycyclic Aromatic Hydrocarbon Formation in n-Heptane HCCI Combustion  

Science Conference Proceedings (OSTI)

By modifying the SENKIN code of CHEMKIN chemical kinetics package, the combustion processes and the characteristics of hydrocarbon (HC) and carbon monoxide(CO) emissions of a HCCI engine were simulated. Furthermore, the formation of benzene (A1) and ... Keywords: n-neptane, HCCI, multi-zone model, polycyclic aromatic hydrocarbons

Zeng Wen; Ma Hong-an

2011-02-01T23:59:59.000Z

462

Curvature analysis applied to the Cantarell structure, southern Gulf of Mexico: implications for hydrocarbon exploration  

Science Conference Proceedings (OSTI)

The middle Miocene Cantarell structure is host to the largest hydrocarbon field in Mexico. It has been variously interpreted as a fold-and-thrust or a dextral transpressional structure and the hydrocarbons are generally located in fold culminations adjacent ... Keywords: Folds, Geological algorithm, Geological surfaces, Petroleum, Structural geology, Transpressional structure

J. J. Mandujano; R. V. Khachaturov; G. Tolson; J. Duncan Keppie

2005-06-01T23:59:59.000Z

463

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents (OSTI)

A method for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap therebetween. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition.

Kong, Peter C. (Idaho Falls, ID)

1997-01-01T23:59:59.000Z

464

Method for cracking hydrocarbon compositions using a submerged reactive plasma system  

DOE Patents (OSTI)

A method is described for cracking a liquid hydrocarbon composition (e.g. crude oil) to produce a cracked hydrocarbon product. A liquid hydrocarbon composition is initially provided. An electrical arc is generated directly within the hydrocarbon composition so that the arc is entirely submerged in the composition. Arc generation is preferably accomplished using a primary and secondary electrode each having a first end submerged in the composition. The first ends of the electrodes are separated from each other to form a gap there between. An electrical potential is then applied to the electrodes to generate the arc within the gap. A reactive gas is thereafter delivered to the arc which forms a bubble around the arc. Gas delivery may be accomplished by providing a passageway through each electrode and delivering the gas through the passageways. The arc and gas cooperate to produce a plasma which efficiently cracks the hydrocarbon composition. 6 figs.

Kong, P.C.

1997-05-06T23:59:59.000Z

465

Biofuel from Bacteria and Sunlight: Shewanella as an Ideal Platform for Producing Hydrocarbons  

SciTech Connect

Broad Funding Opportunity Announcement Project: The University of Minnesota is developing clean-burning, liquid hydrocarbon fuels from bacteria. The University is finding ways to continuously harvest hydrocarbons from a type of bacteria called Shewanella by using a photosynthetic organism to constantly feed Shewanella the sugar it needs for energy and hydrocarbon production. The two organisms live and work together as a system. Using Shewanella to produce hydrocarbon fuels offers several advantages over traditional biofuel production methods. First, it eliminates many of the time-consuming and costly steps involved in growing plants and harvesting biomass. Second, hydrocarbon biofuels resemble current petroleum-based fuels and would therefore require few changes to the existing fuel refining and distribution infrastructure in the U.S.

None

2010-01-01T23:59:59.000Z