National Library of Energy BETA

Sample records for gas supplants coal

  1. Supplanting ecosystem services provided by scavengers raises greenhouse gas

    E-Print Network [OSTI]

    Richner, Heinz

    Supplanting ecosystem services provided by scavengers raises greenhouse gas emissions Zebensui to human-induced increments in atmospheric concentrations of greenhouse gases (GHG) is one of the most concentrations of some gases such as carbon dioxide, methane or nitrous oxide (globally called greenhouse gases

  2. Coal beneficiation by gas agglomeration

    DOE Patents [OSTI]

    Wheelock, Thomas D.; Meiyu, Shen

    2003-10-14

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  3. Coal Beneficiation by Gas Agglomeration

    SciTech Connect (OSTI)

    Thomas D. Wheelock; Meiyu Shen

    2000-03-15

    Coal beneficiation is achieved by suspending coal fines in a colloidal suspension of microscopic gas bubbles in water under atmospheric conditions to form small agglomerates of the fines adhered by the gas bubbles. The agglomerates are separated, recovered and resuspended in water. Thereafter, the pressure on the suspension is increased above atmospheric to deagglomerate, since the gas bubbles are then re-dissolved in the water. During the deagglomeration step, the mineral matter is dispersed, and when the pressure is released, the coal portion of the deagglomerated gas-saturated water mixture reagglomerates, with the small bubbles now coming out of the solution. The reagglomerate can then be separated to provide purified coal fines without the mineral matter.

  4. COAL CLEANING BY GAS AGGLOMERATION

    SciTech Connect (OSTI)

    T.D. Wheelock

    1999-03-01

    The technical feasibility of a gas agglomeration method for cleaning coal was demonstrated by means of bench-scale tests conducted with a mixing system which enabled the treatment of ultra-fine coal particles with a colloidal suspension of microscopic gas bubbles in water. A suitable suspension of microbubbles was prepared by first saturating water with air or carbon dioxide under pressure then reducing the pressure to release the dissolved gas. The formation of microbubbles was facilitated by agitation and a small amount of i-octane. When the suspension of microbubbles and coal particles was mixed, agglomeration was rapid and small spherical agglomerates were produced. Since the agglomerates floated, they were separated from the nonfloating tailings in a settling chamber. By employing this process in numerous agglomeration tests of moderately hydrophobic coals with 26 wt.% ash, it was shown that the ash content would be reduced to 6--7 wt.% while achieving a coal recovery of 75 to 85% on a dry, ash-free basis. This was accomplished by employing a solids concentration of 3 to 5 w/w%, an air saturation pressure of 136 to 205 kPa (5 to 15 psig), and an i-octane concentration of 1.0 v/w% based on the weight of coal.

  5. Gas distributor for fluidized bed coal gasifier

    DOE Patents [OSTI]

    Worley, Arthur C. (Mt. Tabor, NJ); Zboray, James A. (Irvine, CA)

    1980-01-01

    A gas distributor for distributing high temperature reaction gases to a fluidized bed of coal particles in a coal gasification process. The distributor includes a pipe with a refractory reinforced lining and a plurality of openings in the lining through which gas is fed into the bed. These feed openings have an expanding tapered shape in the downstream or exhaust direction which aids in reducing the velocity of the gas jets as they enter the bed.

  6. Demonstration of a Carbonate Fuel Cell on Coal Derived Gas 

    E-Print Network [OSTI]

    Rastler, D. M.; Keeler, C. G.; Chi, C. V.

    1993-01-01

    Several studies indicate that carbonate fuel cell systems have the potential to offer efficient, cost competitive, and environmentally preferred power plants operating on natural gas or coal derived gas (“syn-gas”). To date, however, no fuel cell...

  7. Advanced coal-fueled gas turbine systems

    SciTech Connect (OSTI)

    Not Available

    1992-09-01

    Westinghouse's Advanced Coal-Fueled Gas Turbine System Program (DE-AC2l-86MC23167) was originally split into two major phases - a Basic Program and an Option. The Basic Program also contained two phases. The development of a 6 atm, 7 lb/s, 12 MMBtu/hr slagging combustor with an extended period of testing of the subscale combustor, was the first part of the Basic Program. In the second phase of the Basic Program, the combustor was to be operated over a 3-month period with a stationary cascade to study the effect of deposition, erosion and corrosion on combustion turbine components. The testing of the concept, in subscale, has demonstrated its ability to handle high- and low-sulfur bituminous coals, and low-sulfur subbituminous coal. Feeding the fuel in the form of PC has proven to be superior to CWM type feed. The program objectives relative to combustion efficiency, combustor exit temperature, NO[sub x] emissions, carbon burnout, and slag rejection have been met. Objectives for alkali, particulate, and SO[sub x] levels leaving the combustor were not met by the conclusion of testing at Textron. It is planned to continue this testing, to achieve all desired emission levels, as part of the W/NSP program to commercialize the slagging combustor technology.

  8. Gas Permeability of Fractured Sandstone/Coal Samples under Variable Confining Pressure

    E-Print Network [OSTI]

    Liu, Weiqun; Li, Yushou; Wang, Bo

    2010-01-01

    Permeability of Fractured Sandstone/Coal Samples Smeulders,8 Gas Permeability of Fractured Sandstone/Coal Samples underthe fractured samples of sandstone and coal and obtain their

  9. Production of Substitute Natural Gas from Coal

    SciTech Connect (OSTI)

    Andrew Lucero

    2009-01-31

    The goal of this research program was to develop and demonstrate a novel gasification technology to produce substitute natural gas (SNG) from coal. The technology relies on a continuous sequential processing method that differs substantially from the historic methanation or hydro-gasification processing technologies. The thermo-chemistry relies on all the same reactions, but the processing sequences are different. The proposed concept is appropriate for western sub-bituminous coals, which tend to be composed of about half fixed carbon and about half volatile matter (dry ash-free basis). In the most general terms the process requires four steps (1) separating the fixed carbon from the volatile matter (pyrolysis); (2) converting the volatile fraction into syngas (reforming); (3) reacting the syngas with heated carbon to make methane-rich fuel gas (methanation and hydro-gasification); and (4) generating process heat by combusting residual char (combustion). A key feature of this technology is that no oxygen plant is needed for char combustion.

  10. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    O. A. Marina; L. R. Pederson; R. Gemmen; K. Gerdes; H. Finklea; I. B. Celik

    2010-03-01

    An overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic and actual coal gas for periods greater than 1000 hours. Post-test analyses were performed to identify reaction products formed and their distribution, and compared to phases expected from thermochemical modeling. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  11. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Gemmen, Randall; Gerdes, Kirk; Finklea, Harry; Celik, Ismail B.

    2010-05-01

    An overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic and actual coal gas for periods greater than 1000 hours. Post-test analyses were performed to identify reaction products formed and their distribution, and compared to phases expected from thermochemical modeling. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  12. Testing for market integration crude oil, coal, and natural gas

    SciTech Connect (OSTI)

    Bachmeier, L.J.; Griffin, J.M.

    2006-07-01

    Prompted by the contemporaneous spike in coal, oil, and natural gas prices, this paper evaluates the degree of market integration both within and between crude oil, coal, and natural gas markets. Our approach yields parameters that can be readily tested against a priori conjectures. Using daily price data for five very different crude oils, we conclude that the world oil market is a single, highly integrated economic market. On the other hand, coal prices at five trading locations across the United States are cointegrated, but the degree of market integration is much weaker, particularly between Western and Eastern coals. Finally, we show that crude oil, coal, and natural gas markets are only very weakly integrated. Our results indicate that there is not a primary energy market. Despite current price peaks, it is not useful to think of a primary energy market, except in a very long run context.

  13. Coal liquefaction and gas conversion: Proceedings. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1993-12-31

    Volume I contains papers presented at the following sessions: AR-Coal Liquefaction; Gas to Liquids; and Direct Liquefaction. Selected papers have been processed separately for inclusion in the Energy Science and Technology Database.

  14. An Evaluation of Low-BTU Gas from Coal as an Alternate Fuel for Process Heaters 

    E-Print Network [OSTI]

    Nebeker, C. J.

    1982-01-01

    considerations including: coal vs. natural gas prices, economic life of the gas-consuming facility, quantity of gas required, need for desulfurization, location of gasifiers in relation to gas users, existence of coal unloading and storage facilities, etc. Two...

  15. Two-stage coal liquefaction without gas-phase hydrogen

    DOE Patents [OSTI]

    Stephens, H.P.

    1986-06-05

    A process is provided for the production of a hydrogen-donor solvent useful in the liquefaction of coal, wherein the water-gas shift reaction is used to produce hydrogen while simultaneously hydrogenating a donor solvent. A process for the liquefaction of coal using said solvent is also provided. The process enables avoiding the use of a separate water-gas shift reactor as well as high pressure equipment for liquefaction. 3 tabs.

  16. Overview of SOFC Anode Interactions with Coal Gas Impurities

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Gemmen, Randall; Gerdes, Kirk; Finklea, Harry; Celik, Ismail B.

    2009-08-11

    Efficiencies greater than 50 percent (higher heating value) have been projected for solid oxide fuel cell (SOFC) systems fueled with gasified coal, even with carbon sequestration. Multiple minor and trace components are present in coal that could affect fuel cell performance, however, which vary widely depending on coal origin and type. Minor and trace components have been classified into three groups: elements with low volatility that are likely to remain in the ash, elements that will partition between solid and gas phases, and highly volatile elements that are unlikely to condense. Those in the second group are of most concern. In the following, an overview of the results of SOFC anode interactions with phosphorus, arsenic, selenium, sulfur, antimony, and hydrogen chloride as single contaminants or in combinations is discussed. Tests were performed using both anode- and electrolyte-supported cells in synthetic coal gas. The ultimate purpose of this work is to establish maximum permissible concentrations for impurities in coal gas, to aid in the selection of appropriate coal gas clean-up technologies.

  17. Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds

    E-Print Network [OSTI]

    Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

    2008-01-01

    removal from flue gas of coal-fired power plants. Environ.Speciation in a 100-MW Coal-Fired Boiler with Low-NOxControl Technologies for Coal-Fired Power Plants, DOE/NETL

  18. Solar coal gasification reactor with pyrolysis gas recycle

    DOE Patents [OSTI]

    Aiman, William R. (Livermore, CA); Gregg, David W. (Morago, CA)

    1983-01-01

    Coal (or other carbonaceous matter, such as biomass) is converted into a duct gas that is substantially free from hydrocarbons. The coal is fed into a solar reactor (10), and solar energy (20) is directed into the reactor onto coal char, creating a gasification front (16) and a pyrolysis front (12). A gasification zone (32) is produced well above the coal level within the reactor. A pyrolysis zone (34) is produced immediately above the coal level. Steam (18), injected into the reactor adjacent to the gasification zone (32), reacts with char to generate product gases. Solar energy supplies the energy for the endothermic steam-char reaction. The hot product gases (38) flow from the gasification zone (32) to the pyrolysis zone (34) to generate hot char. Gases (38) are withdrawn from the pyrolysis zone (34) and reinjected into the region of the reactor adjacent the gasification zone (32). This eliminates hydrocarbons in the gas by steam reformation on the hot char. The product gas (14) is withdrawn from a region of the reactor between the gasification zone (32) and the pyrolysis zone (34). The product gas will be free of tar and other hydrocarbons, and thus be suitable for use in many processes.

  19. Petroleum Data, Natural Gas Data, Coal Data, Macroeconomic Data, Petroleum Import Data

    SciTech Connect (OSTI)

    2009-01-18

    Supplemental tables to the Annual Energy Outlook (AEO) 2006 for petroleum, natural gas, coal, macroeconomic, and import data

  20. Method for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, Thomas (Morgantown, WV)

    1989-01-01

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600.degree. to 1800.degree. F. and are partially quenched with water to 1000.degree. to 1200.degree. F. before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime/limestone.

  1. Optimal transition from coal to gas and renewable power under capacity constraints and adjustment costs

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Optimal transition from coal to gas and renewable power under capacity constraints and adjustment existing coal power plants to gas and renewable power under a carbon budget. It solves a model of polluting, exhaustible resources with capacity constraints and adjustment costs (to build coal, gas, and renewable power

  2. Slag processing system for direct coal-fired gas turbines

    DOE Patents [OSTI]

    Pillsbury, Paul W. (Winter Springs, FL)

    1990-01-01

    Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The gas turbine system includes a primary zone for burning coal in the presence of compressed air to produce hot combustion gases and debris, such as molten slag. The turbine system further includes a secondary combustion zone for the lean combustion of the hot combustion gases. The operation of the system is improved by the addition of a cyclone separator for removing debris from the hot combustion gases. The cyclone separator is disposed between the primary and secondary combustion zones and is in pressurized communication with these zones. In a novel aspect of the invention, the cyclone separator includes an integrally disposed impact separator for at least separating a portion of the molten slag from the hot combustion gases.

  3. Gas Migration from Closed Coal Mines to the Surface RISK ASSESSMENT METHODOLOGY AND PREVENTION MEANS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Gas Migration from Closed Coal Mines to the Surface RISK ASSESSMENT METHODOLOGY AND PREVENTION to the surface is especially significant in the context of coal mines. This is because mine gas can migrate of the scheduled closure of all coal mining operations in France, INERIS has drawn up, at the request of national

  4. Durable zinc ferrite sorbent pellets for hot coal gas desulfurization

    DOE Patents [OSTI]

    Jha, Mahesh C. (Arvada, CO); Blandon, Antonio E. (Thornton, CO); Hepworth, Malcolm T. (Edina, MN)

    1988-01-01

    Durable, porous sulfur sorbents useful in removing hydrogen sulfide from hot coal gas are prepared by water pelletizing a mixture of fine zinc oxide and fine iron oxide with inorganic and organic binders and small amounts of activators such as sodium carbonate and molybdenite; the pellets are dried and then indurated at a high temperature, e.g., 1800.degree. C., for a time sufficient to produce crush-resistant pellets.

  5. Slag processing system for direct coal-fired gas turbines

    DOE Patents [OSTI]

    Pillsbury, Paul W. (Winter Springs, FL)

    1990-01-01

    Direct coal-fired gas turbine systems and methods for their operation are provided by this invention. The systems include a primary combustion compartment coupled to an impact separator for removing molten slag from hot combustion gases. Quenching means are provided for solidifying the molten slag removed by the impact separator, and processing means are provided forming a slurry from the solidified slag for facilitating removal of the solidified slag from the system. The released hot combustion gases, substantially free of molten slag, are then ducted to a lean combustion compartment and then to an expander section of a gas turbine.

  6. Ni/YSZ Anode Interactions with Impurities in Coal Gas

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Thomsen, Edwin C.; Coffey, Greg W.

    2009-10-16

    Performance of solid oxide fuel cell (SOFC) with nickel/zirconia anodes on synthetic coal gas in the presence of low levels of phosphorus, arsenic, selenium, sulfur, hydrogen chloride, and antimony impurities were evaluated. The presence of phosphorus and arsenic led to the slow and irreversible SOFC degradation due to the formation of secondary phases with nickel, particularly close to the gas inlet. Phosphorus and antimony surface adsorption layers were identified as well. Hydrogen chloride and sulfur interactions with the nickel were limited to the surface adsorption only, whereas selenium exposure also led to the formation of nickel selenide for highly polarized cells.

  7. Scaling control during membrane distillation of coal seam gas reverse osmosis brine

    E-Print Network [OSTI]

    Scaling control during membrane distillation of coal seam gas reverse osmosis brine Hung C. Duong during membrane distillation (MD) of brine from reverse osmosis (RO) treatment of coal seam gas (CSG. During CSG production, both gas and water are extracted to the surface. Gas is commonly separated from

  8. The Future of Coal in a Greenhouse Gas Constrained World Howard Herzog1

    E-Print Network [OSTI]

    1 The Future of Coal in a Greenhouse Gas Constrained World Howard Herzog1 , James Katzer1 1 M coal can make to the growing world energy demand during a period of increasing concern about global pursue in the short-term so that we can utilize coal in the longer-term and reduce its associated CO2

  9. Method for increasing the calorific value of gas produced by the in situ combustion of coal

    DOE Patents [OSTI]

    Shuck, Lowell Z. (Morgantown, WV)

    1978-01-01

    The present invention relates to the production of relatively high Btu gas by the in situ combustion of subterranean coal. The coal bed is penetrated with a horizontally-extending borehole and combustion is initiated in the coal bed contiguous to the borehole. The absolute pressure within the resulting combustion zone is then regulated at a desired value near the pore pressure within the coal bed so that selected quantities of water naturally present in the coal will flow into the combustion zone to effect a hydrogen and carbon monoxide-producing steam-carbon reaction with the hot carbon in the combustion zone for increasing the calorific value of the product gas.

  10. Water Extraction from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Bruce C. Folkedahl; Greg F. Weber; Michael E. Collings

    2006-06-30

    The overall objective of this program was to develop a liquid disiccant-based flue gas dehydration process technology to reduce water consumption in coal-fired power plants. The specific objective of the program was to generate sufficient subscale test data and conceptual commercial power plant evaluations to assess process feasibility and merits for commercialization. Currently, coal-fired power plants require access to water sources outside the power plant for several aspects of their operation in addition to steam cycle condensation and process cooling needs. At the present time, there is no practiced method of extracting the usually abundant water found in the power plant stack gas. This project demonstrated the feasibility and merits of a liquid desiccant-based process that can efficiently and economically remove water vapor from the flue gas of fossil fuel-fired power plants to be recycled for in-plant use or exported for clean water conservation. After an extensive literature review, a survey of the available physical and chemical property information on desiccants in conjunction with a weighting scheme developed for this application, three desiccants were selected and tested in a bench-scale system at the Energy and Environmental Research Center (EERC). System performance at the bench scale aided in determining which desiccant was best suited for further evaluation. The results of the bench-scale tests along with further review of the available property data for each of the desiccants resulted in the selection of calcium chloride as the desiccant for testing at the pilot-scale level. Two weeks of testing utilizing natural gas in Test Series I and coal in Test Series II for production of flue gas was conducted with the liquid desiccant dehumidification system (LDDS) designed and built for this study. In general, it was found that the LDDS operated well and could be placed in an automode in which the process would operate with no operator intervention or adjustment. Water produced from this process should require little processing for use, depending on the end application. Test Series II water quality was not as good as that obtained in Test Series I; however, this was believed to be due to a system upset that contaminated the product water system during Test Series II. The amount of water that can be recovered from flue gas with the LDDS is a function of several variables, including desiccant temperature, L/G in the absorber, flash drum pressure, liquid-gas contact method, and desiccant concentration. Corrosion will be an issue with the use of calcium chloride as expected but can be largely mitigated through proper material selection. Integration of the LDDS with either low-grade waste heat and or ground-source heating and cooling can affect the parasitic power draw the LDDS will have on a power plant. Depending on the amount of water to be removed from the flue gas, the system can be designed with no parasitic power draw on the power plant other than pumping loads. This can be accomplished in one scenario by taking advantage of the heat of absorption and the heat of vaporization to provide the necessary temperature changes in the desiccant with the flue gas and precipitates that may form and how to handle them. These questions must be addressed in subsequent testing before scale-up of the process can be confidently completed.

  11. Cornell's conversion of a coal fired heating plant to natural Gas -BACKGROUND: In December 2009, the Combined Heat and Power Plant

    E-Print Network [OSTI]

    Keinan, Alon

    Cornell's conversion of a coal fired heating plant to natural Gas University began operating with natural gas, instead of the coal-fired generators of the coal that had been stockpiled, the Plant is running completely on natural gas

  12. Fact #844: October 27, 2014 Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown – Dataset

    Broader source: Energy.gov [DOE]

    Excel file with dataset for Fact #844: Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown

  13. Process for the production of fuel gas from coal

    DOE Patents [OSTI]

    Patel, Jitendra G. (Bolingbrook, IL); Sandstrom, William A. (Chicago, IL); Tarman, Paul B. (Elmhurst, IL)

    1982-01-01

    An improved apparatus and process for the conversion of hydrocarbonaceous materials, such as coal, to more valuable gaseous products in a fluidized bed gasification reaction and efficient withdrawal of agglomerated ash from the fluidized bed is disclosed. The improvements are obtained by introducing an oxygen containing gas into the bottom of the fluidized bed through a separate conduit positioned within the center of a nozzle adapted to agglomerate and withdraw the ash from the bottom of the fluidized bed. The conduit extends above the constricted center portion of the nozzle and preferably terminates within and does not extend from the nozzle. In addition to improving ash agglomeration and withdrawal, the present invention prevents sintering and clinkering of the ash in the fluidized bed and permits the efficient recycle of fine material recovered from the product gases by contacting the fines in the fluidized bed with the oxygen as it emanates from the conduit positioned within the withdrawal nozzle. Finally, the present method of oxygen introduction permits the efficient recycle of a portion of the product gases to the reaction zone to increase the reducing properties of the hot product gas.

  14. Synthesis gas production with an adjustable H{sub 2}/CO ratio through the coal gasification process: effects of coal ranks and methane addition

    SciTech Connect (OSTI)

    Yan Cao; Zhengyang Gao; Jing Jin; Hongchang Zhou; Marten Cohron; Houying Zhao; Hongying Liu; Weiping Pan [Western Kentucky University (WKU), Bowling Green, KY (United States). Institute for Combustion Science and Environmental Technology (ICSET)

    2008-05-15

    Direct production of synthesis gas using coal as a cheap feedstock is attractive but challenging due to its low H{sub 2}/CO ratio of generated synthesis gas. Three typical U.S. coals of different ranks were tested in a 2.5 in. coal gasifier to investigate their gasification reactivity and adjustability on H{sub 2}/CO ratio of generated synthesis gas with or without the addition of methane. Tests indicated that lower-rank coals (lignite and sub-bituminous) have higher gasification reactivity than bituminous coals. The coal gasification reactivity is correlated to its synthesis-gas yield and the total percentage of H{sub 2} and CO in the synthesis gas, but not to the H{sub 2}/CO ratio. The H{sub 2}/CO ratio of coal gasification was found to be correlated to the rank of coals, especially the H/C ratio of coals. Methane addition into the dense phase of the pyrolysis and gasification zone of the cogasification reactor could make the best use of methane in adjusting the H{sub 2}/CO ratio of the generated synthesis gas. The maximum methane conversion efficiency, which was likely correlated to its gasification reactivity, could be achieved by 70% on average for all tested coals. The actual catalytic effect of generated coal chars on methane conversion seemed coal-dependent. The coal-gasification process benefits from methane addition and subsequent conversion on the adjustment of the H{sub 2}/CO ratio of synthesis gas. The methane conversion process benefits from the use of coal chars due to their catalytic effects. This implies that there were likely synergistic effects on both. 25 refs., 3 figs., 3

  15. Method and apparatus for enhancing the desulfurization of hot coal gas in a fluid-bed coal gasifier

    DOE Patents [OSTI]

    Grindley, T.

    1988-04-05

    A process and apparatus for providing additional desulfurization of the hot gas produced in a fluid-bed coal gasifier, within the gasifier is described. A fluid-bed of iron oxide is located inside the gasifier above the gasification bed in a fluid-bed coal gasifier in which in-bed desulfurization by lime/limestone takes place. The product gases leave the gasification bed typically at 1600 to 1800 F and are partially quenched with water to 1000 to 1200 F before entering the iron oxide bed. The iron oxide bed provides additional desulfurization beyond that provided by the lime /limestone. 1 fig.

  16. 168 Int. J. Oil, Gas and Coal Technology, Vol. 2, No. 2, 2009 Copyright 2009 Inderscience Enterprises Ltd.

    E-Print Network [OSTI]

    Ali, Mohammed

    168 Int. J. Oil, Gas and Coal Technology, Vol. 2, No. 2, 2009 Copyright © 2009 Inderscience.Y. (2009) `Geology and coal potential of Somaliland', Int. J. Oil, Gas and Coal Technology, Vol. 2, No. 2 of Africa. They are the oceanic spreading ridges of the Red Sea and the Gulf of Aden and the continental

  17. The competition between coal and natural gas : the importance of sunk costs

    E-Print Network [OSTI]

    Ellerman, A. Denny

    1996-01-01

    This paper explores the seeming paradox between the predominant choice of natural gas for capacity additions to generate electricity in the United States and the continuing large share of coal in meeting incremental ...

  18. Should we transport coal, gas, or electricity: cost, efficiency, and environmental implications

    SciTech Connect (OSTI)

    Joule A. Bergerson; Lester B. Lave

    2005-08-15

    The authors examine the life cycle costs, environmental discharges, and deaths of moving coal via rail, coal to synthetic natural gas via pipeline, and electricity via wire from the Powder River Basin (PRB) in Wyoming to Texas. Which method has least social cost depends on how much additional investment in rail line, transmission, or pipeline infrastructure is required, as well as how much and how far energy is transported. If the existing rail lines have unused capacity, coal by rail is the cheapest method (up to 200 miles of additional track could be added). If no infrastructure exists, greater distances and larger amounts of energy favor coal by rail and gasified coal by pipeline over electricity transmission. For 1,000 miles and 9 gigawatts of power, a gas pipeline is cheapest, has less environmental discharges, uses less land, and is least obtrusive. 28 refs., 4 figs., 3 tabs.

  19. Fact #844: October 27, 2014 Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown

    Broader source: Energy.gov [DOE]

    From 2002 to 2012, most states have reduced their reliance on coal for electricity generation. The figure below shows the percent change in electricity generated by coal and natural gas for each...

  20. Status of pulse combustion applications in (1) steam reforming of coal, (2) fluid bed combustion of coal, and (3) direct coal fired gas turbine

    SciTech Connect (OSTI)

    Durai-Swamy, K. [ThermoChem, Inc., Santa Fe Springs, CA (United States); Chandran, R.; Said, H.; Steedman, W.

    1994-12-31

    ThermoChem, Inc. has designed a 450 T/D wet coal gasification by indirect, pulse-combustor-heated, steam reforming process. The plant site is Gillette, Wyoming. Products from the demo project are: (1) High pressure steam for a K-Fuel coal upgrading plant and (2) Medium Btu syngas, which could be used for power generation or methanol production. The indirect heated steam reformer could also produce a char by-product (if desired) that could be used as a reductant in direct iron making (DRI) process. There has been interest for char production as well. ThermoChem is constructing a pulse assisted, atmospheric pressure fluid bed combustor unit (PAFBC) to produce 50,000 lb/hr of steam, at Clemson University in South Carolina. MTCI`s developing a pressurized pulse coal combustor coupled with bimodal ash agglomeration, sulfur capture and solids removal features, such that the hot flue gas can be directly expanded in a gas turbine to generate power. The status of these Clean Coal Technologies is presented in this paper.

  1. Combustion characteristics of pulverized coal and air/gas premixed flame in a double swirl combustor

    SciTech Connect (OSTI)

    Kamal, M.M.

    2009-07-01

    An experimental work was performed to investigate the co-firing of pulverized coal and premixed gas/air streams in a double swirl combustor. The results showed that the NOx emissions are affected by the relative rates of thermal NOx formation and destruction via the pyrolysis of the fuel-N species in high temperature fuel-rich zones. Various burner designs were tested in order to vary the temperature history and the residence time across both coal and gas flames inside the furnace. It was found that by injecting the coal with a gas/air mixture as a combined central jet surrounded by a swirled air stream, a double flame envelope develops with high temperature fuel-rich conditions in between the two reaction zones such that the pyrolysis reactions to N{sub 2} are accelerated. A further reduction in the minimum NOx emissions, as well as in the minimum CO concentrations, was reported for the case where the coal particles are fed with the gas/air mixture in the region between the two swirled air streams. On the other hand, allocating the gas/air mixture around the swirled air-coal combustion zone provides an earlier contact with air and retards the NOx reduction mechanism in such a way that the elevated temperatures around the coal particles allow higher overall NOx emissions. The downstream impingement of opposing air jets was found more efficient than the impinging of particle non-laden premixed flames for effective NOx reduction. In both cases, there is an upstream flow from the stagnation region to the coal primary combustion region, but with the case of air impingement, the hot fuel-rich zone develops earlier. The optimum configuration was found by impinging all jets of air and coal-gas/air mixtures that pronounced minimum NOx and CO concentrations of 310 and 480ppm, respectively.

  2. Int. J. Oil, Gas and Coal Technology, Vol. 7, No. 2, 2014 115 Copyright 2014 Inderscience Enterprises Ltd.

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Int. J. Oil, Gas and Coal Technology, Vol. 7, No. 2, 2014 115 Copyright © 2014 Inderscience fields in Saudi Arabia', Int. J. Oil, Gas and Coal Technology, Vol. 7, No. 2, pp.115­131. Biographical economic recovery of oil and gas from a reservoir. The purpose of reservoir management is to control

  3. Novel carbons from Illinois coal for natural gas storage. Technical report, March 1--May 31, 1995

    SciTech Connect (OSTI)

    Rostam-Abadi, M.; Sun, Jian; Lizzio, A.A.

    1995-12-31

    Goal is to develop a technology for producing microengineered adsorbent carbons from Illinois coal and to evaluate their potential application for storing natural gas for use in emerging low pressure, natural gas vehicles (NGVs). Focus is to design and engineer adsorbents that meet or exceed performance and cost targets established for low-pressure natural gas storage materials. Potentially, about two million tons adsorbent could be consumed in NGVs by year 2000. If successful, the results could lead to use of Illinois coal in a market that could exceed 6 million tons per year. Activated carbon samples were prepared from IBC-106 coal by controlling both the preoxidation temperature and time, and the devolatilization temperature in order to eliminate coal caking. A 4.6 cc pressurized vessel was constructed to measure the Vm/Vs methane adsorption capacity (volume of stored methane at STP per volume storage container). Several IBC-106 derived activated carbons showed methane adsorption capacities comparable to that of a 1000 m{sup 2}/g commercial activated carbon. Results indicated that surface area and micropore volume of activated carbons are important for natural gas storage. Work is in progress to synthesize samples from IBC-106 coal with optimum pore diameter for methane adsorption.

  4. Desulfurization of hot fuel gas produced from high-chlorine Illinois coals. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    O`Brien, W.S. [Southern Illinois Univ., Carbondale, IL (United States); Gupta, R.P. [Research Triangle Inst., Durham, NC (United States)

    1992-09-01

    There is a primary need to increase the utilization of Illinois coal resources by developing new methods of converting the coal into electricity by highly efficient and environmentally acceptable systems. New coal gasification processes are now being developed that can generate electricity with high thermal efficiency in either an integrated gasification combined cycle (IGCC) system or a molten carbonate fuel cell (MCFC). Both of-these new coal-to-electricity pathways require that the coal-derived fuel gas be at a high temperature and be free of potential pollutants, such as-sulfur compounds. Unfortunately, some high-sulfur Illinois coals also contain significant chlorine which converts into hydrogen chloride (HCI) in the coal gas. This project investigates the effect of HCI, in concentrations typical of a gasifier fed by high-chlorine Illinois coals, on zinc-titanate sorbents that are currently being developed for H{sub 2}S and COS removal from hot coal gas. This study is designed to identify any deleterious changes in the sorbent caused by HCI, both in adsorptive operation and in the regeneration cycle, and will pave the way to modify the sorbent formulation or the process operating procedure to remove HCl along with the H{sub 2}S and COS from hot coal gas. This will negate any harmful consequences Of utilizing high-chlorine Illinois coal in these processes.

  5. Sorbents for High Temperature Removal of Arsenic from Coal-Derived Synthesis Gas

    SciTech Connect (OSTI)

    Alptekin, G.O.; Copeland, R.; Dubovik, M.; Gershanovich, Y.

    2002-09-20

    Gasification technologies convert coal and other heavy feedstocks into synthesis gas feed streams that can be used in the production of a wide variety of chemicals, ranging from hydrogen through methanol, ammonia, acetic anhydride, dimethyl ether (DME), methyl tertiary butyl ether (MTBE), high molecular weight liquid hydrocarbons and waxes. Syngas can also be burned directly as a fuel in advanced power cycles to generate electricity with very high efficiency. However, the coal-derived synthesis gas contains a myriad of trace contaminants that may poison the catalysts that are used in the downstream manufacturing processes and may also be regulated in power plant emissions. Particularly, the catalysts used in the conversion of synthesis gas to methanol and other liquid fuels (Fischer-Tropsch liquids) have been found to be very sensitive to the low levels of poisons, especially arsenic, that are present in the synthesis gas from coal. TDA Research, Inc. (TDA) is developing an expendable high capacity, low-cost chemical absorbent to remove arsenic from coal-derived syngas. Unlike most of the commercially available sorbents that physically adsorb arsenic, TDA's sorbent operates at elevated temperatures and removes the arsenic through chemical reaction. The arsenic content in the coal gas stream is reduced to ppb levels with the sorbent by capturing and stabilizing the arsenic gas (As4) and arsenic hydrides (referred to as arsine, AsH3) in the solid state. To demonstrate the concept of high temperature arsenic removal from coal-derived syngas, we carried out bench-scale experiments to test the absorption capacity of a variety of sorbent formulations under representative conditions. Using on-line analysis techniques, we monitored the pre- and post-breakthrough arsine concentrations over different sorbent samples. Some of these samples exhibited pre-breakthrough arsine absorption capacity over 40% wt. (capacity is defined as lb of arsenic absorbed/lb of sorbent), while maintaining an arsine outlet concentration at less than 10 ppb.

  6. Hydrogen Resource Assessment: Hydrogen Potential from Coal, Natural Gas, Nuclear, and Hydro Power

    SciTech Connect (OSTI)

    Milbrandt, A.; Mann, M.

    2009-02-01

    This paper estimates the quantity of hydrogen that could be produced from coal, natural gas, nuclear, and hydro power by county in the United States. The study estimates that more than 72 million tonnes of hydrogen can be produced from coal, natural gas, nuclear, and hydro power per year in the country (considering only 30% of their total annual production). The United States consumed about 396 million tonnes of gasoline in 2007; therefore, the report suggests the amount of hydrogen from these sources could displace about 80% of this consumption.

  7. Study on systems based on coal and natural gas for producing dimethyl ether

    SciTech Connect (OSTI)

    Zhou, L.; Hu, S.Y.; Chen, D.J.; Li, Y.R.; Zhu, B.; Jin, Y.

    2009-04-15

    China is a coal-dependent country and will remain so for a long time. Dimethyl ether (DME), a potential substitute for liquid fuel, is a kind of clean diesel motor fuel. The production of DME from coal is meaningful and is studied in this article. Considering the C/H ratios of coal and natural gas (NG), the cofeed (coal and NG) system (CFS), which does not contain the water gas shift process, is studied. It can reduce CO{sub 2} emission and increase the conversion rate of carbon, producing more DME. The CFS is simulated and compared with the coal-based and NG-based systems with different recycling ratios. The part of the exhaust gas that is not recycled is burned, producing electricity. On the basis of the simulation results, the thermal efficiency, economic index, and CO{sub 2} emission ratio are calculated separately. The CFS with a 100% recycling ratio has the best comprehensive evaluation index, while the energy, economy, and environment were considered at the same time.

  8. 104 Int. J. Oil, Gas and Coal Technology, Vol. 4, No. 2, 2011 Copyright 2011 Inderscience Enterprises Ltd.

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    104 Int. J. Oil, Gas and Coal Technology, Vol. 4, No. 2, 2011 Copyright © 2011 Inderscience techniques used in the top-down modelling presented in this study include production decline analysis, type, Gas and Coal Technology, Vol. 4, No. 2, pp.104­133. Biographical notes: Amirmasoud Kalantari

  9. Advanced coal-fueled gas turbine systems, Volume 1: Annual technical progress report

    SciTech Connect (OSTI)

    Not Available

    1988-07-01

    This is the first annual technical progress report for The Advanced Coal-Fueled Gas Turbine Systems Program. Two semi-annual technical progress reports were previously issued. This program was initially by the Department of Energy as an R D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular three-stage slagging combustor concept. Fuel-rich conditions inhibit NO/sub x/ formation from fuel nitrogen in the first stage; coal ash and sulfur is subsequently removed from the combustion gases by an impact separator in the second stage. Final oxidation of the fuel-rich gases and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage. 27 figs., 15 tabs.

  10. Enabling Technology for Monitoring & Predicting Gas Turbine Health & Performance in COAL IGCC Powerplants

    SciTech Connect (OSTI)

    Kenneth A. Yackly

    2004-09-30

    The ''Enabling & Information Technology To Increase RAM for Advanced Powerplants'' program, by DOE request, has been re-directed, de-scoped to two tasks, shortened to a 2-year period of performance, and refocused to develop, validate and accelerate the commercial use of enabling materials technologies and sensors for Coal IGCC powerplants. The new program has been re-titled as ''Enabling Technology for Monitoring & Predicting Gas Turbine Health & Performance in IGCC Powerplants'' to better match the new scope. This technical progress report summarizes the work accomplished in the reporting period April 1, 2004 to August 31, 2004 on the revised Re-Directed and De-Scoped program activity. The program Tasks are: Task 1--IGCC Environmental Impact on high Temperature Materials: This first materials task has been refocused to address Coal IGCC environmental impacts on high temperature materials use in gas turbines and remains in the program. This task will screen material performance and quantify the effects of high temperature erosion and corrosion of hot gas path materials in Coal IGCC applications. The materials of interest will include those in current service as well as advanced, high-performance alloys and coatings. Task 2--Material In-Service Health Monitoring: This second task develops and demonstrates new sensor technologies to determine the in-service health of advanced technology Coal IGCC powerplants, and remains in the program with a reduced scope. Its focus is now on only two critical sensor need areas for advanced Coal IGCC gas turbines: (1) Fuel Quality Sensor for detection of fuel impurities that could lead to rapid component degradation, and a Fuel Heating Value Sensor to rapidly determine the fuel heating value for more precise control of the gas turbine, and (2) Infra-Red Pyrometer to continuously measure the temperature of gas turbine buckets, nozzles, and combustor hardware.

  11. Gas turbines for coal-fired turbocharged PFBC boiler power plants

    SciTech Connect (OSTI)

    Wenglarz, R.; Drenker, S.

    1984-11-01

    A coal-fired turbocharged boiler using fluidized bed combustion at high pressure would be more compact than a pulverized coal fired boiler. The smaller boiler size could permit the utility industry to adopt efficient modular construction methods now widely used in other industries. A commercial turbocharger of the capacity needed to run a 250 MW /SUB e/ power plant does not exist; commercial gas turbines of the correct capacity exist, but they are not matched to this cycle's gas temperature of less than 538/sup 0/C (1000/sup 0/F). In order to avoid impeding the development of the technology, it will probably be desirable to use existing machines to the maximum extent possible. This paper explores the advantages and disadvantages of applying either standard gas turbines or modified standard gas turbines to the turbocharged boiler.

  12. Permeability changes in coal resulting from gas desorption

    SciTech Connect (OSTI)

    Levine, J.R.; Tsay, F.

    1989-11-19

    Sampling Procedure: This project requires a carefully coordinated sample preparation procedure that will ensure that specimens of the proper size and physical characteristics are available for the various measurement methods used. Coherent blocks of coal will be collected in the field, with subsamples being removed in the lab by 1 inch-diameter core drill. At least 5 separate cores will be drilled from each block. Coal blocks sampled in the field will be approximately 10 inches (times) 10 inches {times} 6 inches. Distinctive compositional lithologies should be selected for sampling. For example, a section of the seam containing particularly thick vitrain or durain bands might be selected; or the block might include a mineral matter rich layer. If necessary, several blocks should be selected to represent a range in compositions. Sampling procedure must include a method for retaining moisture. The sample must not be allowed to dry out. Exposure to atmospheric oxygen should be limited as much as possible. The samples must carefully packed for shipment so as to preserve their integrity.

  13. System and method for producing substitute natural gas from coal

    DOE Patents [OSTI]

    Hobbs, Raymond (Avondale, AZ)

    2012-08-07

    The present invention provides a system and method for producing substitute natural gas and electricity, while mitigating production of any greenhouse gasses. The system includes a hydrogasification reactor, to form a gas stream including natural gas and a char stream, and an oxygen burner to combust the char material to form carbon oxides. The system also includes an algae farm to convert the carbon oxides to hydrocarbon material and oxygen.

  14. Advanced coal-fueled gas turbine systems: Subscale combustion testing. Topical report, Task 3.1

    SciTech Connect (OSTI)

    Not Available

    1993-05-01

    This is the final report on the Subscale Combustor Testing performed at Textron Defense Systems` (TDS) Haverhill Combustion Laboratories for the Advanced Coal-Fueled Gas Turbine System Program of the Westinghouse Electric Corp. This program was initiated by the Department of Energy in 1986 as an R&D effort to establish the technology base for the commercial application of direct coal-fired gas turbines. The combustion system under consideration incorporates a modular staged, rich-lean-quench, Toroidal Vortex Slogging Combustor (TVC) concept. Fuel-rich conditions in the first stage inhibit NO{sub x} formation from fuel-bound nitrogen; molten coal ash and sulfated sorbent are removed, tapped and quenched from the combustion gases by inertial separation in the second stage. Final oxidation of the fuel-rich gases, and dilution to achieve the desired turbine inlet conditions are accomplished in the third stage, which is maintained sufficiently lean so that here, too, NO{sub x} formation is inhibited. The primary objective of this work was to verify the feasibility of a direct coal-fueled combustion system for combustion turbine applications. This has been accomplished by the design, fabrication, testing and operation of a subscale development-type coal-fired combustor. Because this was a complete departure from present-day turbine combustors and fuels, it was considered necessary to make a thorough evaluation of this design, and its operation in subscale, before applying it in commercial combustion turbine power systems.

  15. Kinetics of Direct Oxidation of H2S in Coal Gas to Elemental Sulfur

    SciTech Connect (OSTI)

    K.C. Kwon

    2005-11-01

    Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced Vision 21 plants that produce electric power and clean transportation fuels with coal and natural gas. These Vision 21 plants will require highly clean coal gas with H{sub 2}S below 1 ppm and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation Vision 21 plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and 400 square cells/inch{sup 2}, {gamma}-Al{sub 2}O{sub 3}-wash-coated monolithic catalyst, and various reactors such as a micro packed-bed reactor, a micro bubble reactor, and a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam.

  16. Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal

    SciTech Connect (OSTI)

    Eric P. Robertson

    2007-09-01

    This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

  17. Coal pump

    DOE Patents [OSTI]

    Bonin, John H. (Sunnyvale, CA); Meyer, John W. (Palo Alto, CA); Daniel, Jr., Arnold D. (Alameda County, CA)

    1983-01-01

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

  18. Advanced coal-fueled industrial cogeneration gas turbine system particle removal system development

    SciTech Connect (OSTI)

    Stephenson, M.

    1994-03-01

    Solar Turbines developed a direct coal-fueled turbine system (DCFT) and tested each component in subscale facilities and the combustion system was tested at full-scale. The combustion system was comprised of a two-stage slagging combustor with an impact separator between the two combustors. Greater than 90 percent of the native ash in the coal was removed as liquid slag with this system. In the first combustor, coal water slurry mixture (CWM) was injected into a combustion chamber which was operated loan to suppress NO{sub x} formation. The slurry was introduced through four fuel injectors that created a toroidal vortex because of the combustor geometry and angle of orientation of the injectors. The liquid slag that was formed was directed downward toward an impaction plate made of a refractory material. Sixty to seventy percent of the coal-borne ash was collected in this fashion. An impact separator was used to remove additional slag that had escaped the primary combustor. The combined particulate collection efficiency from both combustors was above 95 percent. Unfortunately, a great deal of the original sulfur from the coal still remained in the gas stream and needed to be separated. To accomplish this, dolomite or hydrated lime were injected in the secondary combustor to react with the sulfur dioxide and form calcium sulfite and sulfates. This solution for the sulfur problem increased the dust concentrations to as much as 6000 ppmw. A downstream particulate control system was required, and one that could operate at 150 psia, 1850-1900{degrees}F and with low pressure drop. Solar designed and tested a particulate rejection system to remove essentially all particulate from the high temperature, high pressure gas stream. A thorough research and development program was aimed at identifying candidate technologies and testing them with Solar`s coal-fired system. This topical report summarizes these activities over a period beginning in 1987 and ending in 1992.

  19. Durable zinc oxide-containing sorbents for coal gas desulfurization

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV)

    1996-01-01

    Durable zinc-oxide containing sorbent pellets for removing hydrogen sulfide from a gas stream at an elevated temperature are made up to contain titania as a diluent, high-surface-area silica gel, and a binder. These materials are mixed, moistened, and formed into pellets, which are then dried and calcined. The resulting pellets undergo repeated cycles of sulfidation and regeneration without loss of reactivity and without mechanical degradation. Regeneration of the pellets is carried out by contacting the bed with an oxidizing gas mixture.

  20. Porosity of coal and shale: Insights from gas adsorption and SANS/USANS techniques

    SciTech Connect (OSTI)

    Mastalerz, Maria; He, Lilin; Melnichenko, Yuri B; Rupp, John A

    2012-01-01

    Two Pennsylvanian coal samples (Spr326 and Spr879-IN1) and two Upper Devonian-Mississippian shale samples (MM1 and MM3) from the Illinois Basin were studied with regard to their porosity and pore accessibility. Shale samples are early mature stage as indicated by vitrinite reflectance (R{sub o}) values of 0.55% for MM1 and 0.62% for MM3. The coal samples studied are of comparable maturity to the shale samples, having vitrinite reflectance of 0.52% (Spr326) and 0.62% (Spr879-IN1). Gas (N{sub 2} and CO{sub 2}) adsorption and small-angle and ultrasmall-angle neutron scattering techniques (SANS/USANS) were used to understand differences in the porosity characteristics of the samples. The results demonstrate that there is a major difference in mesopore (2-50 nm) size distribution between the coal and shale samples, while there was a close similarity in micropore (<2 nm) size distribution. Micropore and mesopore volumes correlate with organic matter content in the samples. Accessibility of pores in coal is pore-size specific and can vary significantly between coal samples; also, higher accessibility corresponds to higher adsorption capacity. Accessibility of pores in shale samples is low.

  1. High temperature alkali corrosion of ceramics in coal gas: Final report

    SciTech Connect (OSTI)

    Pickrell, G.R.; Sun, T.; Brown, J.J. Jr.

    1994-12-31

    There are several ceramic materials which are currently being considered for use as structural elements in coal combustion and coal conversion systems because of their thermal and mechanical properties. These include alumina (refractories, membranes, heat engines); silicon carbide and silicon nitride (turbine engines, internal combustion engines, heat exchangers, particulate filters); zirconia (internal combustion engines, turbine engines, refractories); and mullite and cordierite (particulate filters, refractories, heat exchangers). High temperature alkali corrosion has been known to cause premature failure of ceramic components used in advanced high temperature coal combustion systems such as coal gasification and clean-up, coal fired gas turbines, and high efficiency heat engines. The objective of this research is to systematically evaluate the alkali corrosion resistance of the most commonly used structural ceramics including silicon carbide, silicon nitride, cordierite, mullite, alumina, aluminum titanate, and zirconia. The study consists of identification of the alkali reaction products and determination of the kinetics of the alkali reactions as a function of temperature and time. 145 refs., 29 figs., 12 tabs.

  2. Novel carbons from Illinois coal for natural gas storage. Technical report, September 1--November 30, 1994

    SciTech Connect (OSTI)

    Rostam-Abadi, M.; Sun, J.; Lizzio, A.A. [Illinois State Geological Survey, Champaign, IL (United States); Fatemi, M. [Amoco Research Center, Naperville, IL (United States)

    1994-12-31

    The goal of this project is to develop a technology for producing microengineered adsorbent carbons from Illinois coal and to evaluate the potential application of these novel materials for storing natural gas for use in emerging low pressure, natural gas vehicles (NGV). Potentially, about two million tons of adsorbent could be consumed in natural gas vehicles by year 2000. If successful, the results obtained in this project could lead to the use of Illinois coal in a growing and profitable market that could exceed 6 million tons per year. During this reporting period, a pyrolysis-gasification reactor system was designed and assembled. Four carbon samples were produced from a {minus}20+100 mesh size fraction of an Illinois Basin Coal (IBC-106) using a three-step process. The three steps were: coal oxidation in air at 250 C, oxicoal (oxidized coal) devolatilization in nitrogen at 425 C and char gasification in 50% steam-50% nitrogen at 860 C. These initial tests were designed to evaluate the effects of pre-oxidation on the surface properties of carbon products, and to determine optimum reaction time and process conditions to produce an activated carbon with high surface area. Nitrogen-BET surface areas of the carbon products ranged from 700--800 m{sup 2}/g. Work is in progress to further optimize reaction conditions in order to produce carbons with higher surface areas. A few screening tests were made with a pressurized thermogravimetric (PTGA) to evaluate the suitability of this instrument for obtaining methane adsorption isotherms at ambient temperature and pressures ranging from one to 30 atmospheres. The preliminary results indicate that PTGA can be used for both the adsorption kinetic and equilibrium studies.

  3. Adsorptive removal of catalyst poisons from coal gas for methanol synthesis

    SciTech Connect (OSTI)

    Bhatt, B.L.; Golden, T.C.; Hsiung, T.H. (Air Products and Chemicals, Inc., Allentown, PA (United States))

    1991-12-01

    As an integral part of the liquid-phase methanol (LPMEOH) process development program, the present study evaluated adsorptive schemes to remove traces of catalyst poisons such as iron carbonyl, carbonyl sulfide, and hydrogen sulfide from coal gas on a pilot scale. Tests were conducted with coal gas from the Cool Water gasification plant at Daggett, California. Iron carbonyl, carbonyl sulfide, and hydrogen sulfide were effectively removed from the coal gas. The adsorption capacities of Linde H-Y zeolite and Calgon BPL carbon for Fe(CO){sub 5} compared well with previous bench-scale results at similar CO{sub 2} partial pressure. Adsorption of COS by Calgon FCA carbon appeared to be chemical and nonregenerable by thermal treatment in nitrogen. A Cu/Zn catalyst removed H{sub 2}S very effectively. With the adsorption system on-line, a methanol catalyst showed stable activity during 120 h operation, demonstrating the feasibility of adsorptive removal of trace catalyst poisons from the synthesis gas. Mass transfer coefficients were estimated for Fe(CO){sub 5} and COS removal which can be directly used for design and scale up.

  4. Bioconversion of coal-derived synthesis gas to liquid fuels. [Butyribacterium methylotrophicum

    SciTech Connect (OSTI)

    Jain, M.K.

    1991-01-01

    The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

  5. Cracking of simulated oil refinery off-gas over a coal char, petroleum coke, and quartz

    SciTech Connect (OSTI)

    Yuan Zhang; Jin-hu Wu; Dong-ke Zhang

    2008-03-15

    The cracking of oil refinery off-gas, simulated with a gas mixture containing methane (51%), ethylene (21.4%), ethane (21.1%), and propane (6.5%), over a coal char, petroleum coke, and quartz, respectively, has been studied in a fixed bed reactor. The experiments were performed at temperatures between 850 and 1000{sup o}C and at atmospheric pressure. The results show that the conversions of all species considered increased with increasing temperature. Ethane and propane completely decomposed over all three bed materials in the temperature range investigated. However, the higher initial conversion rates of methane and ethylene cracking at all temperatures were observed only over the coal char and not on the petroleum coke and quartz, indicating a significant catalytic effect of the coal char on methane and ethylene cracking. Methane and ethylene conversions decreased with reaction time due to deactivation of the coal char by carbon deposition on the char surface and, in the later stage of a cracking experiment, became negative, suggesting that methane and ethylene had been formed during the cracking of ethane and propane. 16 refs., 13 figs., 2 tabs.

  6. Digital Gas Joins Asian Waste-to-Energy Consortium: To Eliminate Coal as a Power Plant Fuel

    E-Print Network [OSTI]

    Columbia University

    Energy's patented technology produces a clean-burning by-product from the widest variety of processed-efficient technology represented by the coal-substitute technology. The same technology will be deployed by DIGGDigital Gas Joins Asian Waste-to-Energy Consortium: To Eliminate Coal as a Power Plant Fuel Digital

  7. DOE - Fossil Energy: The Cleanest Coal Technology - A Real Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding Low-Cost Ground8 GasDEVELOPMENTS E Natural

  8. Office of Oil, Gas, and Coal Supply Statistics

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2 Year-3 Year-4Barrels)(Dollars2.PDF Office3 Office

  9. Office of Oil, Gas, and Coal Supply Statistics

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2 Year-3 Year-4Barrels)(Dollars2.PDF Office3

  10. Co-firing of natural gas and coal. Final report, October 1988-March 1993

    SciTech Connect (OSTI)

    Bayless, D.J.; Daves, G.G.; Johnson, D.C.; Olsen, M.G.; Schroeder, A.R.

    1995-08-01

    The effects of co-firing natural gas on coal ignition, burning rate and sulfur emissions were investigated in a Drop Tube Furnace Facility (DTFF). The DTFF provides control over gas temperatures (1200 to 1700 K), residence times (5 msec to 2 sec), gas species concentrations (CH4, O2, CO2, etc.) and heating rates (up to 10(exp 4) K/sec). The DTFF includes a two-color pyrometer for particle temperature measurements, a digital camera and computer imaging analysis system for in situ particle size and morphology determination, and a sampling system for ash collection. Co-firing small amounts of natural gas reduced the ignition delay of low volatile particles to a value typical of high volatile coal due to increased heating of the particle from gas phase combustion. Co-firing increased sulfur capture because the natural gas flame promotes the conversion of SO2 to SO3, which is more reactive with sorbent materials in the ash.

  11. KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    K.C. Kwon

    2005-01-01

    The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and the hot-gas desulfurization using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process. The objective of this research is to support the near- and long-term process development efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and a micro bubble reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into liquid elemental sulfur were carried out for the space time range of 0.059-0.87 seconds at 125-155 C to evaluate effects of reaction temperature, H{sub 2}S concentration, reaction pressure, and catalyst loading on conversion of hydrogen sulfide into liquid elemental sulfur. Simulated coal gas mixtures consist of 62-78 v% hydrogen, 3,000-7,000-ppmv hydrogen sulfide, 1,500-3,500 ppmv sulfur dioxide, and 10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to a micro bubble reactor are 50 cm{sup 3}/min at room temperature and atmospheric pressure. The temperature of the reactor is controlled in an oven at 125-155 C. The pressure of the reactor is maintained at 40-170 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the bubble reactor is maintained at 2 for all the reaction experiment runs.

  12. KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    K.C. Kwon

    2004-01-01

    The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and the hot-gas desulfurization using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process. The objective of this research is to support the near- and long-term process development efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and a micro bubble reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into liquid elemental sulfur were carried out for the space time range of 1-6 milliseconds at 125-155 C to evaluate effects of reaction temperature, moisture concentration, reaction pressure on conversion of hydrogen sulfide into liquid elemental sulfur. Simulated coal gas mixtures consist of 70 v% hydrogen, 2,500-7,500-ppmv hydrogen sulfide, 1,250-3,750 ppmv sulfur dioxide, and 0-15 vol% moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to a micro bubble reactor are 100 cm{sup 3}/min at room temperature and atmospheric pressure. The temperature of the reactor is controlled in an oven at 125-155 C. The pressure of the reactor is maintained at 40-170 psia.

  13. Int. J. Oil, Gas and Coal Technology, Vol. 5, No. 1, 2012 1 Copyright 2012 Inderscience Enterprises Ltd.

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Int. J. Oil, Gas and Coal Technology, Vol. 5, No. 1, 2012 1 Copyright © 2012 Inderscience Enterprises Ltd. Top-Down, Intelligent Reservoir Modeling of Oil and Gas Producing Shale Reservoirs; Case.Bromhal@netl.doe.gov Abstract: Producing hydrocarbon (both oil and gas) from Shale plays has attracted much attention in recent

  14. Suggested Design Projects 2011-2012 1. Alkanes from Pennsylvania Coal and Marcellus Natural Gas by Hybrid Processing

    E-Print Network [OSTI]

    Discher, Dennis

    by Hybrid Processing (recommended by John A. Wismer, Arkema) The conversion of natural gas to liquid fuels "stranded natural gas" to easily transportable liquids. In fact, a previous design group used a variant of this technology to convert Alaskan natural gas to hydrocarbon liquids7 . The coal industry has also pursued

  15. Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation

    SciTech Connect (OSTI)

    Rue, David

    2013-09-30

    The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis found a number of modifications and adjustments that could provide higher efficiency and better use of available work. Conclusions from this analysis will help guide the analyses and CFD modeling in future process development. The MBB technology has the potential to be a disruptive technology that will enable coal combustion power plants to be built and operated in a cost effective way, cleanly with no carbon dioxide emissions. A large amount of work is needed to quantify and confirm the great promise of the MBB technology. A Phase 2 proposal was submitted to DOE and other sponsors to address the most critical MBB process technical gaps. The Phase 2 proposal was not accepted for current DOE support.

  16. Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds

    E-Print Network [OSTI]

    Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

    2008-01-01

    Coal-fired power generating plants contribute approximatelynumber of coal-fired generating plants (1-3). The mercury is

  17. Mercury Speciation in Coal-Fired Power Plant Flue Gas-Experimental Studies and Model Development

    SciTech Connect (OSTI)

    Radisav Vidic; Joseph Flora; Eric Borguet

    2008-12-31

    The overall goal of the project was to obtain a fundamental understanding of the catalytic reactions that are promoted by solid surfaces present in coal combustion systems and develop a mathematical model that described key phenomena responsible for the fate of mercury in coal-combustion systems. This objective was achieved by carefully combining laboratory studies under realistic process conditions using simulated flue gas with mathematical modeling efforts. Laboratory-scale studies were performed to understand the fundamental aspects of chemical reactions between flue gas constituents and solid surfaces present in the fly ash and their impact on mercury speciation. Process models were developed to account for heterogeneous reactions because of the presence of fly ash as well as the deliberate addition of particles to promote Hg oxidation and adsorption. Quantum modeling was used to obtain estimates of the kinetics of heterogeneous reactions. Based on the initial findings of this study, additional work was performed to ascertain the potential of using inexpensive inorganic sorbents to control mercury emissions from coal-fired power plants without adverse impact on the salability fly ash, which is one of the major drawbacks of current control technologies based on activated carbon.

  18. Life Cycle Greenhouse Gas Emissions of Coal-Fired Electricity Generation: Systematic Review and Harmonization

    SciTech Connect (OSTI)

    Whitaker, M.; Heath, G. A.; O'Donoughue, P.; Vorum, M.

    2012-04-01

    This systematic review and harmonization of life cycle assessments (LCAs) of utility-scale coal-fired electricity generation systems focuses on reducing variability and clarifying central tendencies in estimates of life cycle greenhouse gas (GHG) emissions. Screening 270 references for quality LCA methods, transparency, and completeness yielded 53 that reported 164 estimates of life cycle GHG emissions. These estimates for subcritical pulverized, integrated gasification combined cycle, fluidized bed, and supercritical pulverized coal combustion technologies vary from 675 to 1,689 grams CO{sub 2}-equivalent per kilowatt-hour (g CO{sub 2}-eq/kWh) (interquartile range [IQR]= 890-1,130 g CO{sub 2}-eq/kWh; median = 1,001) leading to confusion over reasonable estimates of life cycle GHG emissions from coal-fired electricity generation. By adjusting published estimates to common gross system boundaries and consistent values for key operational input parameters (most importantly, combustion carbon dioxide emission factor [CEF]), the meta-analytical process called harmonization clarifies the existing literature in ways useful for decision makers and analysts by significantly reducing the variability of estimates ({approx}53% in IQR magnitude) while maintaining a nearly constant central tendency ({approx}2.2% in median). Life cycle GHG emissions of a specific power plant depend on many factors and can differ from the generic estimates generated by the harmonization approach, but the tightness of distribution of harmonized estimates across several key coal combustion technologies implies, for some purposes, first-order estimates of life cycle GHG emissions could be based on knowledge of the technology type, coal mine emissions, thermal efficiency, and CEF alone without requiring full LCAs. Areas where new research is necessary to ensure accuracy are also discussed.

  19. Novel carbons from Illinois coal for natural gas storage. Quarterly report, 1 December 1994--28 February 1995

    SciTech Connect (OSTI)

    Rostam-Abadi, M.; Sun, Jian; Lizzio, A.A. [Illinois State Geological Survey, Urbana, IL (United States); Fatemi, M. [Sperry Univac, St. Paul, MN (United States)

    1995-12-31

    The goal of this project is to develop a technology for producing microengineered adsorbent carbons from Illinois coal and to evaluate the potential application of these novel materials for storing natural gas for use in emerging low pressure, natural gas vehicles (NGV). The focus of the project is to design and engineer adsorbents that meet or exceed the performance and cost targets established for low-pressure natural gas storage materials. Potentially, about two million tons of adsorbent could be consumed in natural gas vehicles by year 2000. If successful, the results obtained in this project could lead to the use of Illinois coal in a sowing and profitable market that could exceed 6 million tons per year. During this reporting period, a series of experiments were made to evaluate the effect of coal pre-oxidation, coal pyrolysis, and char activation on the surface area development and methane adsorption capacity of activated carbons/chars made from IBC-102. The optimum production conditions were determined to be: coal oxidation in air at 225C, oxicoal (oxidized coal); devolatilization in nitrogen at 400C; and char gasification in 50% steam in nitrogen at 850C. Nitrogen BET surface areas of the carbon products ranged from 800--1100 m{sup 2}/g. Methane adsorption capacity of several Illinois coal derived chars and a 883 m{sup 2}/g commercial activated carbon were measured using a pressurized thermogaravimetric analyzer at pressures up to 500 psig. Methane adsorption capacity (g/g) of the chars were comparable to that of the commercial activated carbon manufactured by Calgon Carbon. It was determined that the pre-oxidation is a key processing step for producing activated char/carbon with high surface area and high methane adsorption capacity. The results to date are encouraging and warrant further research and development in tailored activated char from Illinois coal for natural gas storage.

  20. Comparative life-cycle air emissions of coal, domestic natural gas, LNG, and SNG for electricity generation

    SciTech Connect (OSTI)

    Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews

    2007-09-15

    The U.S. Department of Energy (DOE) estimates that in the coming decades the United States' natural gas (NG) demand for electricity generation will increase. Estimates also suggest that NG supply will increasingly come from imported liquefied natural gas (LNG). Additional supplies of NG could come domestically from the production of synthetic natural gas (SNG) via coal gasification-methanation. The objective of this study is to compare greenhouse gas (GHG), SOx, and NOx life-cycle emissions of electricity generated with NG/LNG/SNG and coal. This life-cycle comparison of air emissions from different fuels can help us better understand the advantages and disadvantages of using coal versus globally sourced NG for electricity generation. Our estimates suggest that with the current fleet of power plants, a mix of domestic NG, LNG, and SNG would have lower GHG emissions than coal. If advanced technologies with carbon capture and sequestration (CCS) are used, however, coal and a mix of domestic NG, LNG, and SNG would have very similar life-cycle GHG emissions. For SOx and NOx we find there are significant emissions in the upstream stages of the NG/LNG life-cycles, which contribute to a larger range in SOx and NOx emissions for NG/LNG than for coal and SNG. 38 refs., 3 figs., 2 tabs.

  1. Tunable Diode Laser Sensors to Monitor Temperature and Gas Composition in High-Temperature Coal Gasifiers

    SciTech Connect (OSTI)

    Hanson, Ronald; Whitty, Kevin

    2014-12-01

    The integrated gasification combined cycle (IGCC) when combined with carbon capture and storage can be one of the cleanest methods of extracting energy from coal. Control of coal and biomass gasification processes to accommodate the changing character of input-fuel streams is required for practical implementation of integrated gasification combined-cycle (IGCC) technologies. Therefore a fast time-response sensor is needed for real-time monitoring of the composition and ideally the heating value of the synthesis gas (here called syngas) as it exits the gasifier. The goal of this project was the design, construction, and demonstration an in situ laserabsorption sensor to monitor multiple species in the syngas output from practical-scale coal gasifiers. This project investigated the hypothesis of using laser absorption sensing in particulateladen syngas. Absorption transitions were selected with design rules to optimize signal strength while minimizing interference from other species. Successful in situ measurements in the dusty, high-pressure syngas flow were enabled by Stanford’s normalized and scanned wavelength modulation strategy. A prototype sensor for CO, CH4, CO2, and H2O was refined with experiments conducted in the laboratory at Stanford University, a pilot-scale at the University of Utah, and an engineering-scale gasifier at DoE’s National Center for Carbon Capture with the demonstration of a prototype sensor with technical readiness level 6 in the 2014 measurement campaign.

  2. Advanced coal-fueled gas turbine systems. Annual report, July 1991--June 1992

    SciTech Connect (OSTI)

    Not Available

    1992-09-01

    Westinghouse`s Advanced Coal-Fueled Gas Turbine System Program (DE-AC2l-86MC23167) was originally split into two major phases - a Basic Program and an Option. The Basic Program also contained two phases. The development of a 6 atm, 7 lb/s, 12 MMBtu/hr slagging combustor with an extended period of testing of the subscale combustor, was the first part of the Basic Program. In the second phase of the Basic Program, the combustor was to be operated over a 3-month period with a stationary cascade to study the effect of deposition, erosion and corrosion on combustion turbine components. The testing of the concept, in subscale, has demonstrated its ability to handle high- and low-sulfur bituminous coals, and low-sulfur subbituminous coal. Feeding the fuel in the form of PC has proven to be superior to CWM type feed. The program objectives relative to combustion efficiency, combustor exit temperature, NO{sub x} emissions, carbon burnout, and slag rejection have been met. Objectives for alkali, particulate, and SO{sub x} levels leaving the combustor were not met by the conclusion of testing at Textron. It is planned to continue this testing, to achieve all desired emission levels, as part of the W/NSP program to commercialize the slagging combustor technology.

  3. Advanced Acid Gas Separation Technology for the Utilization of Low Rank Coals

    SciTech Connect (OSTI)

    Kloosterman, Jeff

    2012-12-31

    Air Products has developed a potentially ground-breaking technology – Sour Pressure Swing Adsorption (PSA) – to replace the solvent-based acid gas removal (AGR) systems currently employed to separate sulfur containing species, along with CO{sub 2} and other impurities, from gasifier syngas streams. The Sour PSA technology is based on adsorption processes that utilize pressure swing or temperature swing regeneration methods. Sour PSA technology has already been shown with higher rank coals to provide a significant reduction in the cost of CO{sub 2} capture for power generation, which should translate to a reduction in cost of electricity (COE), compared to baseline CO{sub 2} capture plant design. The objective of this project is to test the performance and capability of the adsorbents in handling tar and other impurities using a gaseous mixture generated from the gasification of lower rank, lignite coal. The results of this testing are used to generate a high-level pilot process design, and to prepare a techno-economic assessment evaluating the applicability of the technology to plants utilizing these coals.

  4. Sustainable Transportation Fuels from Natural Gas (H{sub 2}), Coal and Biomass

    SciTech Connect (OSTI)

    Huffman, Gerald

    2012-12-31

    This research program is focused primarily on the conversion of coal, natural gas (i.e., methane), and biomass to liquid fuels by Fischer-Tropsch synthesis (FTS), with minimum production of carbon dioxide. A complementary topic also under investigation is the development of novel processes for the production of hydrogen with very low to zero production of CO{sub 2}. This is in response to the nation?s urgent need for a secure and environmentally friendly domestic source of liquid fuels. The carbon neutrality of biomass is beneficial in meeting this goal. Several additional novel approaches to limiting carbon dioxide emissions are also being explored.

  5. Membrane Process to Capture CO{sub 2} from Coal-Fired Power Plant Flue Gas

    SciTech Connect (OSTI)

    Merkel, Tim; Wei, Xiaotong; Firat, Bilgen; He, Jenny; Amo, Karl; Pande, Saurabh; Baker, Richard; Wijmans, Hans; Bhown, Abhoyjit

    2012-03-31

    This final report describes work conducted for the U.S. Department of Energy National Energy Technology Laboratory (DOE NETL) on development of an efficient membrane process to capture carbon dioxide (CO{sub 2}) from power plant flue gas (award number DE-NT0005312). The primary goal of this research program was to demonstrate, in a field test, the ability of a membrane process to capture up to 90% of CO{sub 2} in coal-fired flue gas, and to evaluate the potential of a full-scale version of the process to perform this separation with less than a 35% increase in the levelized cost of electricity (LCOE). Membrane Technology and Research (MTR) conducted this project in collaboration with Arizona Public Services (APS), who hosted a membrane field test at their Cholla coal-fired power plant, and the Electric Power Research Institute (EPRI) and WorleyParsons (WP), who performed a comparative cost analysis of the proposed membrane CO{sub 2} capture process. The work conducted for this project included membrane and module development, slipstream testing of commercial-sized modules with natural gas and coal-fired flue gas, process design optimization, and a detailed systems and cost analysis of a membrane retrofit to a commercial power plant. The Polaris? membrane developed over a number of years by MTR represents a step-change improvement in CO{sub 2} permeance compared to previous commercial CO{sub 2}-selective membranes. During this project, membrane optimization work resulted in a further doubling of the CO{sub 2} permeance of Polaris membrane while maintaining the CO{sub 2}/N{sub 2} selectivity. This is an important accomplishment because increased CO{sub 2} permeance directly impacts the membrane skid cost and footprint: a doubling of CO{sub 2} permeance halves the skid cost and footprint. In addition to providing high CO{sub 2} permeance, flue gas CO{sub 2} capture membranes must be stable in the presence of contaminants including SO{sub 2}. Laboratory tests showed no degradation in Polaris membrane performance during two months of continuous operation in a simulated flue gas environment containing up to 1,000 ppm SO{sub 2}. A successful slipstream field test at the APS Cholla power plant was conducted with commercialsize Polaris modules during this project. This field test is the first demonstration of stable performance by commercial-sized membrane modules treating actual coal-fired power plant flue gas. Process design studies show that selective recycle of CO{sub 2} using a countercurrent membrane module with air as a sweep stream can double the concentration of CO{sub 2} in coal flue gas with little energy input. This pre-concentration of CO{sub 2} by the sweep membrane reduces the minimum energy of CO{sub 2} separation in the capture unit by up to 40% for coal flue gas. Variations of this design may be even more promising for CO{sub 2} capture from NGCC flue gas, in which the CO{sub 2} concentration can be increased from 4% to 20% by selective sweep recycle. EPRI and WP conducted a systems and cost analysis of a base case MTR membrane CO{sub 2} capture system retrofitted to the AEP Conesville Unit 5 boiler. Some of the key findings from this study and a sensitivity analysis performed by MTR include: The MTR membrane process can capture 90% of the CO{sub 2} in coal flue gas and produce high-purity CO{sub 2} (>99%) ready for sequestration. CO{sub 2} recycle to the boiler appears feasible with minimal impact on boiler performance; however, further study by a boiler OEM is recommended. For a membrane process built today using a combination of slight feed compression, permeate vacuum, and current compression equipment costs, the membrane capture process can be competitive with the base case MEA process at 90% CO{sub 2} capture from a coal-fired power plant. The incremental LCOE for the base case membrane process is about equal to that of a base case MEA process, within the uncertainty in the analysis. With advanced membranes (5,000 gpu for CO{sub 2} and 50 for CO{sub 2}/N{sub 2}), operating with no feed compression and l

  6. Impact of mine closure and access facilities on gas emissions from old mine workings to surface: examples of French iron and coal

    E-Print Network [OSTI]

    Boyer, Edmond

    : examples of French iron and coal Lorraine basins C. Lagny, R. Salmon, Z. Pokryszka and S. Lafortune (INERIS of mine shafts located in the iron Lorraine basin, in the Lorraine and in North-East coal basins are quite in mine workings but gas entrance and exit are allowed. Coal shafts are secured and can be equipped

  7. A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

    E-Print Network [OSTI]

    Pei, Y J; Dong, X; Feng, G Y; Fu, S; Gao, H; Hong, Y; Li, G; Li, Y X; Shang, L; Sheng, L S; Tian, Y C; Wang, X Q; Wang, Y; Wei, W; Zhang, Y W; Zhou, H J

    2001-01-01

    A Low Cost and High Efficient Facility for Removal of $\\SO_{2}$ and $\\NO_{x}$ in the Flue Gas from Coal Fire Power Plant

  8. Gas Permeability of Fractured Sandstone/Coal Samples under Variable Confining Pressure

    E-Print Network [OSTI]

    Liu, Weiqun; Li, Yushou; Wang, Bo

    2010-01-01

    of Fractured Sandstone/Coal Samples Smeulders, D.M.J. ,stress on permeability of coal. Int. J. Rock Mech. Min. Sci.of Fractured Sandstone/Coal Samples under Variable Con?ning

  9. Reversible Poisoning of the Nickel/Zirconia Solid Oxide Fuel Cell Anodes by Hydrogen Chloride in Coal Gas

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Thomsen, Edwin C.; Coyle, Christopher A.; Yoon, Kyung J.

    2010-10-15

    The performance of anode-supported solid oxide fuel cells (SOFC) was evaluated in synthetic coal gas containing HCl in the temperature range 650 to 850oC. Exposure to up to 800 ppm HCl resulted in reversible poisoning of the Ni/zirconia anode by chlorine species adsorption, the magnitude of which decreased with increased temperature. Performance losses increased with the concentration of HCl to ~100 ppm, above which losses were insensitive to HCl concentration. Cell voltage had no effect on poisoning. No evidence was found for long-term degradation that can be attributed to HCl exposure. Similarly, no evidence of microstructural changes or formation of new solid phases as a result of HCl exposure was found. From thermodynamic calculations, solid nickel chloride phase formation was shown to be highly unlikely in coal gas. Further, the presence of HCl at even the highest anticipated concentrations in coal gas would minimally increase the volatility of nickel.

  10. KINETICS OF DIRECT OXIDATION OF H2S IN COAL GAS TO ELEMENTAL SULFUR

    SciTech Connect (OSTI)

    K.C. Kwon

    2003-01-01

    The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objective of this research is to support the near- and long-term DOE efforts to commercialize this direct oxidation technology. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 60-{micro}m C-500-04 alumina catalyst particles and a PFA differential fixed-bed micro reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. To achieve the above-mentioned objectives, experiments on conversion of hydrogen sulfide into elemental sulfur were carried out for the space time range of 0.01-0.047 seconds at 125-155 C to evaluate effects of reaction temperatures, moisture concentrations, reaction pressures on conversion of hydrogen sulfide into elemental sulfur. Simulated coal gas mixtures consist of 61-89 v% hydrogen, 2,300-9,200-ppmv hydrogen sulfide, 1,600-4,900 ppmv sulfur dioxide, and 2.6-13.7 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 100-110 cm{sup 3}/min at room temperature and atmospheric pressure (SCCM). The temperature of the reactor is controlled in an oven at 125-155 C. The pressure of the reactor is maintained at 28-127 psia. The following results were obtained based on experimental data generated from the differential reactor system, and their interpretations, (1) Concentration of moisture and concentrations of both H{sub 2}S and SO{sub 2} appear to affect slightly reaction rates of H{sub 2}S with SO{sub 2} over the moisture range of 2.5-13.6 v% moisture at 140 C and 120-123 psia. (2) Concentrations of both H{sub 2}S and SO{sub 2} appear to affect slightly reaction rates of H{sub 2}S with SO{sub 2} over the temperature range of 135-145 C at 5-v% moisture and 112-123 psia. However, reaction rates of H{sub 2}S with SO{sub 2} appear to decrease slightly with increased reaction temperatures over the temperature range of 135-145 C at 5-v% moisture and 112-123 psia. (3) Concentrations of both H{sub 2}S and SO{sub 2} appear to affect slightly reaction rates of H{sub 2}S with SO{sub 2} over the pressure range of 28-123 psia at 5-v% moisture and 140 C. However, reaction rates of H{sub 2}S with SO{sub 2} increase significantly with increased reaction pressures over the pressure range of 28-123 psia at 5-v% moisture and 140 C.

  11. Enahancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual

    SciTech Connect (OSTI)

    1998-09-01

    The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved demonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit W, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. At each site where the techno!o@es were to be demonstrated, petiormance goals were set to achieve air emission reductions of 60 percent for NO. and 50 percent for SO2. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NOX emissions were reduced by 67.2% and S02 emissions by 52.6%. For the cyclone-fired unit, NOX emissions were reduced by 62.9% and SOZ emissions by 57.9%.

  12. Enhancing the Use of Coals by Gas Reburning - Sorbent Injection Volume 5 - Guideline Manual

    SciTech Connect (OSTI)

    1998-06-01

    The purpose of the Guideline Manual is to provide recommendations for the application of combined gas reburning-sorbent injection (GR-SI) technologies to pre-NSPS boilers. The manual includes design recommendations, performance predictions, economic projections and comparisons with competing technologies. The report also includes an assessment of boiler impacts. Two full-scale demonstrations of gas reburning-sorbent injection form the basis of the Guideline Manual. Under the U.S. Department of Energy's Clean Coal Technology Program (Round 1), a project was completed to demonstrate control of boiler emissions that comprise acid rain precursors, specifically oxides of nitrogen (NOX) and sulfur dioxide (S02). Other project sponsors were the Gas Research Institute and the Illinois State Department of Commerce and Community Affairs. The project involved d,emonstrating the combined use of Gas Reburning and Sorbent Injection (GR-SI) to assess the air emissions reduction potential of these technologies.. Three potential coal-fired utility boiler host sites were evaluated: Illinois Power's tangentially-fired 71 MWe (net) Hennepin Unit #1, City Water Light and Power's cyclone- fired 33 MWe (gross) Lakeside Unit #7, and Central Illinois Light Company's wall-fired 117 MWe (net) Edwards Unit #1. Commercial demonstrations were completed on the Hennepin and Lakeside Units. The Edwards Unit was removed from consideration for a site demonstration due to retrofit cost considerations. Gas Reburning (GR) controls air emissions of NOX. Natural gas is introduced into the furnace hot flue gas creating a reducing reburning zone to convert NOX to diatomic nitrogen (N,). Overfire air is injected into the furnace above the reburning zone to complete the combustion of the reducing (fuel) gases created in the reburning zone. Sorbent Injection (S1) consists of the injection of dry, calcium-based sorbents into furnace hot flue gas to achieve S02 capture. `At each site where the technologies were to be demonstrated, performance goals were set to achieve air emission reductions of 60 percent for NOX and 50 percent for S02. These performance goals were exceeded during long term demonstration testing. For the tangentially fired unit, NO, emissions were reduced by 67.2?40 and SOZ emissions by 52.6Y0. For the cyclone-fired unit, NO, emissions were reduced by 62.9% and SOZ emissions by 57.9Y0.

  13. Effect of steam partial pressure on gasification rate and gas composition of product gas from catalytic steam gasification of HyperCoal

    SciTech Connect (OSTI)

    Atul Sharma; Ikuo Saito; Toshimasa Takanohashi [National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan). Advanced Fuel Group

    2009-09-15

    HyperCoal was produced from coal by a solvent extraction method. The effect of the partial pressure of steam on the gasification rate and gas composition at temperatures of 600, 650, 700, and 750{sup o}C was examined. The gasification rate decreased with decreasing steam partial pressure. The reaction order with respect to steam partial pressure was between 0.2 and 0.5. The activation energy for the K{sub 2}CO{sub 3}-catalyzed HyperCoal gasification was independent of the steam partial pressure and was about 108 kJ/mol. The gas composition changed with steam partial pressure and H{sub 2} and CO{sub 2} decreased and CO increased with decreasing steam partial pressure. By changing the partial pressure of the steam, the H{sub 2}/CO ratio of the synthesis gas can be controlled. 18 refs., 7 figs., 2 tabs.

  14. Low-Btu coal-gasification-process design report for Combustion Engineering/Gulf States Utilities coal-gasification demonstration plant. [Natural gas or No. 2 fuel oil to natural gas or No. 2 fuel oil or low Btu gas

    SciTech Connect (OSTI)

    Andrus, H E; Rebula, E; Thibeault, P R; Koucky, R W

    1982-06-01

    This report describes a coal gasification demonstration plant that was designed to retrofit an existing steam boiler. The design uses Combustion Engineering's air blown, atmospheric pressure, entrained flow coal gasification process to produce low-Btu gas and steam for Gulf States Utilities Nelson No. 3 boiler which is rated at a nominal 150 MW of electrical power. Following the retrofit, the boiler, originally designed to fire natural gas or No. 2 oil, will be able to achieve full load power output on natural gas, No. 2 oil, or low-Btu gas. The gasifier and the boiler are integrated, in that the steam generated in the gasifier is combined with steam from the boiler to produce full load. The original contract called for a complete process and mechanical design of the gasification plant. However, the contract was curtailed after the process design was completed, but before the mechanical design was started. Based on the well defined process, but limited mechanical design, a preliminary cost estimate for the installation was completed.

  15. KINETICS OF Mn-BASED SORBENTS FOR HOT COAL GAS DESULFURIZATION

    SciTech Connect (OSTI)

    J.J. BERNS; K.A. SADECKI; M.T. HEPWORTH

    1997-09-15

    Mixed manganese oxide sorbents have been investigated for high-temperature removal of hydrogen sulfide (the primary sulfur bearing compound) from hot coal gases. The sorbents were screened by thermodynamic equilibrium considerations for sulfidation. Preliminary experimental work using thermogravimetric analysis (TGA) indicated titania to be a superior substrate than alumina. Four formulations showing superior reactivity in a TGA were then tested in an ambient pressure fixed-bed reactor to determine steady state H 2 S concentrations, breakthrough times and effectiveness of the sorbent when subjected to cyclic sulfidation and regeneration testing. Eight tests were conducted with each test consisting of five cycles of sulfidation and regeneration. Sulfidation occurred at 600 o C using a simulated coal gas at an empty-bed space velocity of approximately 12,000 per hour. Manganese-based sorbents with molar ratios > 1:1 Mn:Substrate were effective in reducing the H 2 S concentration in simulated coal gases to less than 100 ppmv over five cycles. Actual breakthrough time for formulation C6-2-1100 was as high as 73% of breakthrough time based on wt% Mn in sorbent at 600 o C. Regeneration tests determined that loaded pellets can be essentially completely regenerated in an air/steam mixture at 750 o C with minimal sulfate formation. The leading formulation (designated C6-2) from the fixed-bed tests was then further tested under varying sorbent induration temperature, sulfidation temperature and superficial gas velocity. Four tests were conducted with each test consisting of four cycles of sulfidation and regeneration. Results showed that the induration temperature of the sorbent and the reaction temperature greatly affected the H 2 S removal capacity of the sorbent while the superficial gas velocity between 1090 and 1635 cm/min had minimal affect on the sorbent's breakthrough capacity. Testing showed that the sorbent's strength was a strong function of the sorbent induration temperature. Sorbent also showed 30 to 53% loss of its strength over four cycles of sulfidation and regeneration. The former being sorbent indurated at 1115 o C and the prior being sorbent indurated at 1100 o C. A mathematical model was developed to describe the reaction of H 2 S with the mixed metal oxide in a fixed-bed reactor, where the individual pellets react according to the shrinking core model. The effective diffusivity within a single pellet was estimated by adjusting its value until a good match between the experimental and model H 2 S breakthrough curves was obtained. Predicted sorbent conversion at the conclusion of test FB3A compared well with experimental sulfur analysis.

  16. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    Natural Gas Coal 233 billion tonnes coal equivalent 97% total fossil fuel reserve base Reserves by location, quality,

  17. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems

    SciTech Connect (OSTI)

    Blough, E.; Russell, W.; Leach, J.W.

    1990-08-01

    Computer models have been developed for evaluating conceptual designs of integrated coal gasification combined cycle power plants. An overall system model was developed for performing thermodynamic cycle analyses, and detailed models were developed for predicting performance characteristics of fixed bed coal gasifiers and hot gas clean up subsystem components. The overall system model performs mass and energy balances and does chemical equilibrium analyses to determine the effects of changes in operating conditions, or to evaluate proposed design changes. An existing plug flow model for fixed bed gasifiers known as the Wen II model was revised and updated. Also, a spread sheet model of zinc ferrite sulfur sorbent regeneration subsystem was developed. Parametric analyses were performed to determine how performance depends on variables in the system design. The work was done to support CRS Sirrine Incorporated in their study of standardized air blown coal gasifier gas turbine concepts.

  18. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV)

    1997-01-01

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  19. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, R.V.

    1999-02-02

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  20. Durable regenerable sorbent pellets for removal of hydrogen sulfide coal gas

    DOE Patents [OSTI]

    Siriwardane, Ranjani V. (Morgantown, WV)

    1999-01-01

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form, usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  1. Durable regenerable sorbent pellets for removal of hydrogen sulfide from coal gas

    DOE Patents [OSTI]

    Siriwardane, R.V.

    1997-12-30

    Pellets for removing hydrogen sulfide from a coal gasification stream at an elevated temperature are prepared in durable form usable over repeated cycles of absorption and regeneration. The pellets include a material reactive with hydrogen sulfide, in particular zinc oxide, a binder, and an inert material, in particular calcium sulfate (drierite), having a particle size substantially larger than other components of the pellets. A second inert material and a promoter may also be included. Preparation of the pellets may be carried out by dry, solid-state mixing of components, moistening the mixture, and agglomerating it into pellets, followed by drying and calcining. Pellet size is selected, depending on the type of reaction bed for which the pellets are intended. The use of inert material with a large particle size provides a stable pellet structure with increased porosity, enabling effective gas contact and prolonged mechanical durability.

  2. Int. J. Oil, Gas and Coal Technology, Vol. 1, Nos. 1/2, 2008 65 Copyright 2008 Inderscience Enterprises Ltd.

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Int. J. Oil, Gas and Coal Technology, Vol. 1, Nos. 1/2, 2008 65 Copyright © 2008 Inderscience Enterprises Ltd. Building the foundation for Prudhoe Bay oil production optimisation using neural networks E-mail: siskd@Bp.com Abstract: Field data from the Prudhoe Bay oil field in Alaska was used

  3. 2 Int. J. Oil, Gas and Coal Technology, Vol. 2, No. 1, 2009 Copyright 2009 Inderscience Enterprises Ltd.

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    2 Int. J. Oil, Gas and Coal Technology, Vol. 2, No. 1, 2009 Copyright © 2009 Inderscience@yahoo.com Hafez Hafez ADCO-PDD, Abu Dhabi Company for Onshore Oil Operation (ADCO), P.O. Box 270, Abu Dhabi Dhabi Company for Onshore Oil Operation (ADCO), P.O. Box 270, Abu Dhabi, United Arab Emirates Email

  4. Evaluation of sorbents for the cleanup of coal-derived synthesis gas at elevated temperatures

    E-Print Network [OSTI]

    Couling, David Joseph

    2012-01-01

    Integrated Gasification Combined Cycle (IGCC) with carbon dioxide capture is a promising technology to produce electricity from coal at a higher efficiency than with traditional subcritical pulverized coal (PC) power plants. ...

  5. Using auxiliary gas power for CCS energy needs in retrofitted coal power plants

    E-Print Network [OSTI]

    Bashadi, Sarah (Sarah Omer)

    2010-01-01

    Post-combustion capture retrofits are expected to a near-term option for mitigating CO 2 emissions from existing coal-fired power plants. Much of the literature proposes using power from the existing coal plant and thermal ...

  6. Coal feed lock

    DOE Patents [OSTI]

    Pinkel, I. Irving (Fairview Park, OH)

    1978-01-01

    A coal feed lock is provided for dispensing coal to a high pressure gas producer with nominal loss of high pressure gas. The coal feed lock comprises a rotor member with a diametral bore therethrough. A hydraulically activated piston is slidably mounted in the bore. With the feed lock in a charging position, coal is delivered to the bore and then the rotor member is rotated to a discharging position so as to communicate with the gas producer. The piston pushes the coal into the gas producer. The rotor member is then rotated to the charging position to receive the next load of coal.

  7. Wyoming coal-conversion project. Final technical report, November 1980-February 1982. [Proposed WyCoalGas project, Converse County, Wyoming; contains list of appendices with title and identification

    SciTech Connect (OSTI)

    1982-01-01

    This final technical report describes what WyCoalGas, Inc. and its subcontractors accomplished in resolving issues related to the resource, technology, economic, environmental, socioeconomic, and governmental requirements affecting a project located near Douglas, Wyoming for producing 150 Billion Btu per day by gasifying sub-bituminous coal. The report summarizes the results of the work on each task and includes the deliverables that WyCoalGas, Inc. and the subcontractors prepared. The co-venturers withdrew from the project for two reasons: federal financial assistance to the project was seen to be highly uncertain; and funds were being expended at an unacceptably high rate.

  8. Enhancing the use of coals by gas reburning-sorbent injection: Volume 3 -- Gas reburning-sorbent injection at Edwards Unit 1, Central Illinois Light Company. Final report

    SciTech Connect (OSTI)

    NONE

    1996-03-01

    Design work has been completed for a Gas Reburning-Sorbent Injection (GR-SI) system to reduce emissions of NO{sub x} and SO{sub 2} from a wall fired unit at Central Illinois Light Company`s Edwards Station Unit 1, located in Bartonville, Illinois. The goal of the project was to reduce emissions of NO{sub x} by 60%, from the as found baseline of 0.98 lb/MBtu and to reduce emissions of SO{sub 2} by 50%. Since the unit currently fires a blend of high sulfur Illinois coal and low sulfur Kentucky coal to meet an SO{sub 2} limit of 1.8 lb/MBtu, the goal at this site was amended to meeting this limit while increasing the fraction of high sulfur coal to 57% from the current 15% level. GR-SI requires injection of natural gas into the furnace at the level of the top burner row, creating a fuel-rich zone in which NO{sub x} formed in the coal zone is reduced to N{sub 2}. Recycled flue gas is used to increase the reburning fuel jet momentum, resulting in enhanced mixing. Recycled flue gas is also used to cool the top row of burners which would not be in service during GR operation. Dry hydrated lime sorbent is injected into the upper furnace to react with SO{sub 2}, forming solid CaSO{sub 4} and CaSO{sub 3}, which are collected by the ESP. The system was designed to inject sorbent at a rate corresponding to a calcium (sorbent) to sulfur (coal) molar ratio of 2.0. The SI system design was optimized with respect to gas temperature, injection air flow rate, and sorbent dispersion. Sorbent injection air flow is equal to 3% of the combustion air. The design includes modifications of the ESP, sootblowing, and ash handling systems.

  9. DEVELOPMENT OF NOVEL CERAMIC NANOFILM-FIBER INTEGRATED OPTICAL SENSORS FOR RAPID DETECTION OF COAL DERIVED SYNTHESIS GAS

    SciTech Connect (OSTI)

    Junhang Dong; Hai Xiao; Xiling Tang; Hongmin Jiang; Kurtis Remmel; Amardeep Kaur

    2012-09-30

    The overall goal of this project is to conduct fundamental studies on advanced ceramic materials and fiber optic devices for developing new types of high temperature (>500{degree}C) fiber optic chemical sensors (FOCS) for monitoring fossil (mainly coal) and biomass derived gases in power plants. The primary technical objective is to investigate and demonstrate the nanocrystalline doped-ceramic thin film enabled FOCS that possess desired stability, sensitivity and selectivity for in-situ, rapid gas detection in the syngas streams from gasification and combustion flue gases. This report summarizes research works of two integrated parts: (1) development of metal oxide solid thin films as sensing materials for detection and measurement of important gas components relevant to the coal- and biomass-derived syngas and combustion gas streams at high temperatures; and (2) development of fiber optic devices that are potentially useful for constructing FOCS in combination with the solid oxide thin films identified in this program.

  10. Interaction of iron-copper mixed metal oxide oxygen carriers with simulated synthesis gas derived from steam gasification of coal

    SciTech Connect (OSTI)

    Siriwardane, Ranjani V. [U.S. DOE; Ksepko, Ewelina; Tian, Hanging [URS

    2013-01-01

    The objective of this work was to prepare supported bimetallic Fe–Cu oxygen carriers and to evaluate their performance for the chemical-looping combustion (CLC) process with simulated synthesis gas derived from steam gasification of coal/air. Ten-cycle CLC tests were conducted with Fe–Cu oxygen carriers in an atmospheric thermogravimetric analyzer utilizing simulated synthesis gas derived from the steam gasification of Polish Janina coal and Illinois #6 coal as fuel. The effect of temperature on reaction rates, chemical stability, and oxygen transport capacity were determined. Fractional reduction, fractional oxidation, and global rates of reactions were calculated from the thermogravimetric analysis (TGA) data. The supports greatly affected reaction performance. Data showed that reaction rates and oxygen capacities were stable during the 10-cycle TGA tests for most Fe–Cu/support oxygen carriers. Bimetallic Fe–Cu/support oxygen carriers showed higher reduction rates than Fe-support oxygen carriers. The carriers containing higher Cu content showed better stabilities and better reduction rates. An increase in temperature from 800 °C to 900 °C did not have a significant effect on either the oxygen capacity or the reduction rates with synthesis gas derived from Janina coal. Oxidation reaction was significantly faster than reduction reaction for all supported Fe–Cu oxygen carriers. Carriers with higher Cu content had lower oxidation rates. Ten-cycle TGA data indicated that these oxygen carriers had stable performances at 800–900 °C and might be successfully used up to 900 °C for coal CLC reaction in the presence of steam.

  11. Bioconversion of coal-derived synthesis gas to liquid fuels. Final technical report, September 1, 1990--August 31, 1991

    SciTech Connect (OSTI)

    Jain, M.K.

    1991-12-31

    The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

  12. Systems Study for Improving Gas Turbine Performance for Coal/IGCC Application

    SciTech Connect (OSTI)

    Ashok K. Anand

    2005-12-16

    This study identifies vital gas turbine (GT) parameters and quantifies their influence in meeting the DOE Turbine Program overall Integrated Gasification Combined Cycle (IGCC) plant goals of 50% net HHV efficiency, $1000/kW capital cost, and low emissions. The project analytically evaluates GE advanced F class air cooled technology level gas turbine conceptual cycle designs and determines their influence on IGCC plant level performance including impact of Carbon capture. This report summarizes the work accomplished in each of the following six Tasks. Task 1.0--Overall IGCC Plant Level Requirements Identification: Plant level requirements were identified, and compared with DOE's IGCC Goal of achieving 50% Net HHV Efficiency and $1000/KW by the Year 2008, through use of a Six Sigma Quality Functional Deployment (QFD) Tool. This analysis resulted in 7 GT System Level Parameters as the most significant. Task 2.0--Requirements Prioritization/Flow-Down to GT Subsystem Level: GT requirements were identified, analyzed and prioritized relative to achieving plant level goals, and compared with the flow down of power island goals through use of a Six Sigma QFD Tool. This analysis resulted in 11 GT Cycle Design Parameters being selected as the most significant. Task 3.0--IGCC Conceptual System Analysis: A Baseline IGCC Plant configuration was chosen, and an IGCC simulation analysis model was constructed, validated against published performance data and then optimized by including air extraction heat recovery and GE steam turbine model. Baseline IGCC based on GE 207FA+e gas turbine combined cycle has net HHV efficiency of 40.5% and net output nominally of 526 Megawatts at NOx emission level of 15 ppmvd{at}15% corrected O2. 18 advanced F technology GT cycle design options were developed to provide performance targets with increased output and/or efficiency with low NOx emissions. Task 4.0--Gas Turbine Cycle Options vs. Requirements Evaluation: Influence coefficients on 4 key IGCC plant level parameters (IGCC Net Efficiency, IGCC Net Output, GT Output, NOx Emissions) of 11 GT identified cycle parameters were determined. Results indicate that IGCC net efficiency HHV gains up to 2.8 pts (40.5% to 43.3%) and IGCC net output gains up to 35% are possible due to improvements in GT technology alone with single digit NOx emission levels. Task 5.0--Recommendations for GT Technical Improvements: A trade off analysis was conducted utilizing the performance results of 18 gas turbine (GT) conceptual designs, and three most promising GT candidates are recommended. A roadmap for turbine technology development is proposed for future coal based IGCC power plants. Task 6.0--Determine Carbon Capture Impact on IGCC Plant Level Performance: A gas turbine performance model for high Hydrogen fuel gas turbine was created and integrated to an IGCC system performance model, which also included newly created models for moisturized syngas, gas shift and CO2 removal subsystems. This performance model was analyzed for two gas turbine technology based subsystems each with two Carbon removal design options of 85% and 88% respectively. The results show larger IGCC performance penalty for gas turbine designs with higher firing temperature and higher Carbon removal.

  13. Integrated Warm Gas Multicontaminant Cleanup Technologies for Coal-Derived Syngas

    SciTech Connect (OSTI)

    Turk, Brian; Gupta, Raghubir; Sharma, Pradeepkumar; Albritton, Johnny; Jamal, Aqil

    2010-09-30

    One of the key obstacles for the introduction of commercial gasification technology for the production of power with Integrated Gasification Combined Cycle (IGCC) plants or the production of value added chemicals, transportation fuels, and hydrogen has been the cost of these systems. This situation is particularly challenging because the United States has ample coal resources available as raw materials and effective use of these raw materials could help us meet our energy and transportation fuel needs while significantly reducing our need to import oil. One component of the cost of these systems that faces strong challenges for continuous improvement is removing the undesirable components present in the syngas. The need to limit the increase in cost of electricity to < 35% for new coal-based power plants which include CO{sub 2} capture and sequestration addresses both the growing social concern for global climate change resulting from the emission of greenhouse gas and in particular CO{sub 2} and the need to control cost increases to power production necessary to meet this social objective. Similar improvements to technologies for trace contaminants are getting similar pressure to reduce environmental emissions and reduce production costs for the syngas to enable production of chemicals from coal that is cost competitive with oil and natural gas. RTI, with DOE/NETL support, has been developing sorbent technologies that enable capture of trace contaminants and CO{sub 2} at temperatures above 400 °F that achieve better capture performance, lower costs and higher thermal efficiency. This report describes the specific work of sorbent development for mercury (Hg), arsenic (As), selenium (Se), cadmium (Cd), and phosphorous (P) and CO{sub 2} removal. Because the typical concentrations of Hg, As, Se, Cd, and P are less than 10 ppmv, the focus has been on single-use sorbents with sufficient capacity to ensure replacement costs are cost effective. The research in this report describes the development efforts which expand this sorbent development effort to include Se, Cd, and P as well as Hg and As. Additional research has focused on improving removal performance with the goal of achieving effluent concentrations that are suitable for chemical production applications. By contrast, sorbent development for CO{sub 2} capture has focused on regenerable sorbents that capture the CO{sub 2} byproduct at higher CO{sub 2} pressures. Previous research on CO{sub 2} sorbents has demonstrated that the most challenging aspect of developing CO{sub 2} sorbents is regeneration. The research documented in this report investigates options to improve regeneration of the CO{sub 2} capture sorbents. This research includes effort on addressing existing regeneration limitations for sorbents previously developed and new approaches that focus initially on the regeneration performance of the sorbent.

  14. Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas

    SciTech Connect (OSTI)

    Carl Richardson; Katherine Dombrowski; Douglas Orr

    2006-12-31

    This project Final Report is submitted to the U.S. Department of Energy (DOE) as part of Cooperative Agreement DE-FC26-03NT41987, 'Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas.' Sorbent injection technology is targeted as the primary mercury control process on plants burning low/medium sulfur bituminous coals equipped with ESP and ESP/FGD systems. About 70% of the ESPs used in the utility industry have SCAs less than 300 ft2/1000 acfm. Prior to this test program, previous sorbent injection tests had focused on large-SCA ESPs. This DOE-NETL program was designed to generate data to evaluate the performance and economic feasibility of sorbent injection for mercury control at power plants that fire bituminous coal and are configured with small-sized electrostatic precipitators and/or an ESP-flue gas desulfurization (FGD) configuration. EPRI and Southern Company were co-funders for the test program. Southern Company and Reliant Energy provided host sites for testing and technical input to the project. URS Group was the prime contractor to NETL. ADA-ES and Apogee Scientific Inc. were sub-contractors to URS and was responsible for all aspects of the sorbent injection systems design, installation and operation at the different host sites. Full-scale sorbent injection for mercury control was evaluated at three sites: Georgia Power's Plant Yates Units 1 and 2 [Georgia Power is a subsidiary of the Southern Company] and Reliant Energy's Shawville Unit 3. Georgia Power's Plant Yates Unit 1 has an existing small-SCA cold-side ESP followed by a Chiyoda CT-121 wet scrubber. Yates Unit 2 is also equipped with a small-SCA ESP and a dual flue gas conditioning system. Unit 2 has no SO2 control system. Shawville Unit 3 is equipped with two small-SCA cold-side ESPs operated in series. All ESP systems tested in this program had SCAs less than 250 ft2/1000 acfm. Short-term parametric tests were conducted on Yates Units 1 and 2 to evaluate the performance of low-cost activated carbon sorbents for removing mercury. In addition, the effects of the dual flue gas conditioning system on mercury removal performance were evaluated as part of short-term parametric tests on Unit 2. Based on the parametric test results, a single sorbent (e.g., RWE Super HOK) was selected for a 30-day continuous injection test on Unit 1 to observe long-term performance of the sorbent as well as its effects on ESP and FGD system operations as well as combustion byproduct properties. A series of parametric tests were also performed on Shawville Unit 3 over a three-week period in which several activated carbon sorbents were injected into the flue gas duct just upstream of either of the two Unit 3 ESP units. Three different sorbents were evaluated in the parametric test program for the combined ESP 1/ESP 2 system in which sorbents were injected upstream of ESP 1: RWE Super HOK, Norit's DARCO Hg, and a 62:38 wt% hydrated lime/DARCO Hg premixed reagent. Five different sorbents were evaluated for the ESP 2 system in which activated carbons were injected upstream of ESP 2: RWE Super HOK and coarse-ground HOK, Norit's DARCO Hg and DARCO Hg-LH, and DARCO Hg with lime injection upstream of ESP 1. The hydrated lime tests were conducted to reduce SO3 levels in an attempt to enhance the mercury removal performance of the activated carbon sorbents. The Plant Yates and Shawville studies provided data required for assessing carbon performance and long-term operational impacts for flue gas mercury control across small-sized ESPs, as well as for estimating the costs of full-scale sorbent injection processes.

  15. Enhancing the use of coals by gas reburning-sorbent injection. Volume 3, Gas reburning-sorbent injection at Edwards Unit 1, Central Illinois Light Company

    SciTech Connect (OSTI)

    NONE

    1994-10-01

    Design work has been completed for a Gas Reburning-Sorbent Injection (GR-SI) system to reduce emissions of NO{sub x}, and SO{sub 2} from a wall fired unit. A GR-SI system was designed for Central Illinois Light Company`s Edwards Station Unit 1, located in Bartonville, Illinois. The unit is rated at 117 MW(e) (net) and is front wall fired with a pulverized bituminous coal blend. The goal of the project was to reduce emissions of NO{sub x} by 60%, from the ``as found`` baseline of 0.98 lb/MBtu (420 mg/MJ), and to reduce emissions of S0{sub 2} by 50%. Since the unit currently fires a blend of high sulfur Illinois coal and low sulfur Kentucky coal to meet an S0{sub 2} limit Of 1.8 lb/MBtu (770 mg/MJ), the goal at this site was amended to meeting this limit while increasing the fraction of high sulfur coal to 57% from the current 15% level. GR-SI requires injection of natural gas into the furnace at the level of the top burner row, creating a fuel-rich zone in which NO{sub x} formed in the coal zone is reduced to N{sub 2}. The design natural gas input corresponds to 18% of the total heat input. Burnout (overfire) air is injected at a higher elevation to burn out fuel combustible matter at a normal excess air level of 18%. Recycled flue gas is used to increase the reburning fuel jet momentum, resulting in enhanced mixing. Recycled flue gas is also used to cool the top row of burners which would not be in service during GR operation. Dry hydrated lime sorbent is injected into the upper furnace to react with S0{sub 2}, forming solid CaSO{sub 4} and CaSO{sub 3}, which are collected by the ESP. The SI system design was optimized with respect to gas temperature, injection air flow rate, and sorbent dispersion. Sorbent injection air flow is equal to 3% of the combustion air. The design includes modifications of the ESP, sootblowing, and ash handling systems.

  16. Hot coal gas desulfurization with manganese-based sorbents. Annual report, September 1992--September 1993

    SciTech Connect (OSTI)

    Hepworth, M.T.

    1993-12-01

    The focus of work being performed on Hot Coal Gas Desulfurization at the Morgantown Energy Technology Center is primarily in the use of zinc ferrite and zinc titanate sorbents; however, prior studies at the US Steel Fundamental Research Laboratories in Monroeville, PA, by E. T. Turkdogan indicated that an alternate sorbent, manganese dioxide-containing ore in mixture with alumina (75 wt % ore + 25 wt % Al{sub 2}O{sub 3}) may be a viable alternative to zinc-based sorbents. Manganese, for example, has a lower vapor pressure in the elemental state than zinc hence it is not as likely to undergo depletion from the sorbent surface upon loading and regeneration cycles. Also manganese oxide is less readily reduced to the elemental state than iron hence the range of reduction potentials for oxygen is somewhat greater than for zinc ferrite. In addition, thermodynamic analysis of the manganese-oxygen-sulfur system shows it to be less amenable to sulfation than zinc ferrite. Potential also exists for utilization of manganese at higher temperatures than zinc ferrite or zinc titanate. This Annual Topical Report documents progress in pelletizing and testing via thermo-gravimetric analysis of individual pellet formulations of manganese ore/ alumina combinations and also manganese carbonate/alumina with two binders, dextrin and bentonite. It includes the prior Quarterly Technical Reports which indicate that the manganese carbonate material, being of higher purity than the manganese ore, has a higher degree of sulfur capacity and more rapid absorption kinetics. A 2-inch fixed-bed reactor has been fabricated and is now ready for subjecting pellets to cyclic loading and regeneration.

  17. Pilot Scale Water Gas Shift - Membrane Device for Hydrogen from Coal

    SciTech Connect (OSTI)

    Barton, Tom

    2013-06-30

    The objectives of the project were to build pilot scale hydrogen separation systems for use in a gasification product stream. This device would demonstrate fabrication and manufacturing techniques for producing commercially ready facilities. The design was a 2 lb/day hydrogen device which included composite hydrogen separation membranes, a water gas shift monolith catalyst, and stainless steel structural components. Synkera Technologies was to prepare hydrogen separation membranes with metallic rims, and to adjust the alloy composition in their membranes to a palladium-gold composition which is sulfur resistant. Chart was to confirm their brazing technology for bonding the metallic rims of the composite membranes to their structural components and design and build the 2 lbs/day device incorporating membranes and catalysts. WRI prepared the catalysts and completed the testing of the membranes and devices on coal derived syngas. The reactor incorporated eighteen 2'' by 7'' composite palladium alloy membranes. These membranes were assembled with three stacks of three paired membranes. Initial vacuum testing and visual inspection indicated that some membranes were cracked, either in transportation or in testing. During replacement of the failed membranes, while pulling a vacuum on the back side of the membranes, folds were formed in the flexible composite membranes. In some instances these folds led to cracks, primarily at the interface between the alumina and the aluminum rim. The design of the 2 lb/day device was compromised by the lack of any membrane isolation. A leak in any membrane failed the entire device. A large number of tests were undertaken to bring the full 2 lb per day hydrogen capacity on line, but no single test lasted more than 48 hours. Subsequent tests to replace the mechanical seals with brazing have been promising, but the technology remains promising but not proven.

  18. Using auxiliary gas power for CCS energy needs in retrofitted coal power plants

    E-Print Network [OSTI]

    Bashadi, Sarah O.

    Adding post-combustion capture technology to existing coal-fired power plants is being considered as a near-term option for mitigating CO[subscript 2] emissions. To supply the thermal energy needed for CO[subscript 2] ...

  19. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    China Primary Energy Consumption, 1980-2007 Primary Energy Consumption (mtce) hydro & nuclear coal natural gas

  20. PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS

    SciTech Connect (OSTI)

    J. Douglas Way

    2001-07-31

    Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H2 separation. These membranes consist of a thin ({approx}1 mm) film of metal deposited on the inner surface of a porous metal or ceramic tube. Based on preliminary results, thin Pd{sub 60}Cu{sub 40} films are expected to exhibit hydrogen flux up to ten times larger than commercial polymer membranes for H2 separation, and resist poisoning by H{sub 2}S and other sulfur compounds typical of coal gas. Similar Pd-membranes have been operated at temperatures as high as 750 C. The overall objective of the proposed project is to demonstrate the feasibility of using sequential electroless plating to fabricate Pd{sub 60}Cu{sub 4}0 alloy membranes on porous supports for H{sub 2} separation. These following advantages of these membranes for processing of coal-derived gas will be demonstrated: High H{sub 2} flux; Sulfur tolerant, even at very high total sulfur levels (1000 ppm); Operation at temperatures well above 500 C; and Resistance to embrittlement and degradation by thermal cycling. The proposed research plan is designed to providing a fundamental understanding of: Factors important in membrane fabrication; Optimization of membrane structure and composition; Effect of temperature, pressure, and gas composition on H{sub 2} flux and membrane selectivity; and How this membrane technology can be integrated in coal gasification-fuel cell systems.

  1. JV Task 124 - Understanding Multi-Interactions of SO3, Mercury, Selenium, and Arsenic in Illinois Coal Flue Gas

    SciTech Connect (OSTI)

    Ye Zhuang; Christopher Martin; John Pavlish

    2009-03-31

    This project consisted of pilot-scale combustion testing with a representative Illinois basin coal to explore the multi-interactions of SO{sub 3}, mercury, selenium and arsenic. The parameters investigated for SO{sub 3} and mercury interactions included different flue gas conditions, i.e., temperature, moisture content, and particulate alkali content, both with and without activated carbon injection for mercury control. Measurements were also made to track the transformation of selenium and arsenic partitioning as a function of flue gas temperature through the system. The results from the mercury-SO{sub 3} testing support the concept that SO{sub 3} vapor is the predominant factor that impedes efficient mercury removal with activated carbon in an Illinois coal flue gas, while H{sub 2}SO{sub 4} aerosol has less impact on activated carbon injection performance. Injection of a suitably mobile and reactive additives such as sodium- or calcium-based sorbents was the most effective strategy tested to mitigate the effect of SO{sub 3}. Transformation measurements indicate a significant fraction of selenium was associated with the vapor phase at the electrostatic precipitator inlet temperature. Arsenic was primarily particulate-bound and should be captured effectively with existing particulate control technology.

  2. Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high temperature furnace (HITAF). Volume 1, Final report

    SciTech Connect (OSTI)

    NONE

    1996-02-01

    A major objective of the coal-fired high performance power systems (HIPPS) program is to achieve significant increases in the thermodynamic efficiency of coal use for electric power generation. Through increased efficiency, all airborne emissions can be decreased, including emissions of carbon dioxide. High Performance power systems as defined for this program are coal-fired, high efficiency systems where the combustion products from coal do not contact the gas turbine. Typically, this type of a system will involve some indirect heating of gas turbine inlet air and then topping combustion with a cleaner fuel. The topping combustion fuel can be natural gas or another relatively clean fuel. Fuel gas derived from coal is an acceptable fuel for the topping combustion. The ultimate goal for HIPPS is to, have a system that has 95 percent of its heat input from coal. Interim systems that have at least 65 percent heat input from coal are acceptable, but these systems are required to have a clear development path to a system that is 95 percent coal-fired. A three phase program has been planned for the development of HIPPS. Phase 1, reported herein, includes the development of a conceptual design for a commercial plant. Technical and economic feasibility have been analysed for this plant. Preliminary R&D on some aspects of the system were also done in Phase 1, and a Research, Development and Test plan was developed for Phase 2. Work in Phase 2 include s the testing and analysis that is required to develop the technology base for a prototype plant. This work includes pilot plant testing at a scale of around 50 MMBtu/hr heat input. The culmination of the Phase 2 effort will be a site-specific design and test plan for a prototype plant. Phase 3 is the construction and testing of this plant.

  3. Method for fluorinating coal

    DOE Patents [OSTI]

    Huston, John L. (Skokie, IL); Scott, Robert G. (Westmont, IL); Studier, Martin H. (Downers Grove, IL)

    1978-01-01

    Coal is fluorinated by contact with fluorine gas at low pressure. After pial fluorination, when the reaction rate has slowed, the pressure is slowly increased until fluorination is complete, forming a solid fluorinated coal of approximate composition CF.sub.1.55 H.sub.0.15. The fluorinated coal and a solid distillate resulting from vacuum pyrolysis of the fluorinated coal are useful as an internal standard for mass spectrometric unit mass assignments from about 100 to over 1500.

  4. Flue Gas Conditioning to Reduce Particulate Emissions in Industrial Coal-Fired Boilers 

    E-Print Network [OSTI]

    Miller, B.; Keon, E.

    1980-01-01

    create the EPA as a separate agency reporting dir ectly to the President, but it established schedules and a regulatory mechanism to treat air quality on a national basis. Although the initial reaction to this law by coal burners was the switch...

  5. Gas Permeability of Fractured Sandstone/Coal Samples under Variable Confining Pressure

    E-Print Network [OSTI]

    Liu, Weiqun; Li, Yushou; Wang, Bo

    2010-01-01

    argillite under con?nement: gas and water testing. Phys.Gascoyne, M. , Wuschke, D.M. : Gas migration through water-fractured rock: results of a gas injection test. J.

  6. Evaluation of BOC'S Lotox Process for the Oxidation of Elemental Mercury in Flue Gas from a Coal-Fired Boiler

    SciTech Connect (OSTI)

    Khalid Omar

    2008-04-30

    Linde's Low Temperature Oxidation (LoTOx{trademark}) process has been demonstrated successfully to remove more than 90% of the NOx emitted from coal-fired boilers. Preliminary findings have shown that the LoTOx{trademark} process can be as effective for mercury emissions control as well. In the LoTOx{trademark} system, ozone is injected into a reaction duct, where NO and NO{sub 2} in the flue gas are selectively oxidized at relatively low temperatures and converted to higher nitrogen oxides, which are highly water soluble. Elemental mercury in the flue gas also reacts with ozone to form oxidized mercury, which unlike elemental mercury is water-soluble. Nitrogen oxides and oxidized mercury in the reaction duct and residual ozone, if any, are effectively removed in a wet scrubber. Thus, LoTOx{trademark} appears to be a viable technology for multi-pollutant emission control. To prove the feasibility of mercury oxidation with ozone in support of marketing LoTOx{trademark} for multi-pollutant emission control, Linde has performed a series of bench-scale tests with simulated flue gas streams. However, in order to enable Linde to evaluate the performance of the process with a flue gas stream that is more representative of a coal-fired boiler; one of Linde's bench-scale LoTOx{trademark} units was installed at WRI's combustion test facility (CTF), where a slipstream of flue gas from the CTF was treated. The degree of mercury and NOx oxidation taking place in the LoTOx{trademark} unit was quantified as a function of ozone injection rates, reactor temperatures, residence time, and ranks of coals. The overall conclusions from these tests are: (1) over 80% reduction in elemental mercury and over 90% reduction of NOx can be achieved with an O{sub 3}/NO{sub X} molar ratio of less than two, (2) in most of the cases, a lower reactor temperature is preferred over a higher temperature due to ozone dissociation, however, the combination of both low residence time and high temperature proved to be effective in the oxidation of both NOx and elemental mercury, and (3) higher residence time, lower temperature, and higher molar ratio of O{sub 3}/NOx contributed to the highest elemental mercury and NOx reductions.

  7. Enhancing the use of coals by gas reburning-sorbent injection. Quarterly report No. 20, July 1--September 30, 1992

    SciTech Connect (OSTI)

    Not Available

    1992-10-15

    The objective of this project is to evaluate and demonstrate a cost effective emission control technology for acid rain precursors, oxides of nitrogen (NO{sub x}) and sulfur (SO{sub x}) on two coal fired utility boilers in Illinois. The units selected are representative of pre-NSPS design practices: tangential and cyclone fired. Work on a third unit, wall fired, has been stopped because of funding limitations. The specific objectives are to demonstrate reductions of 60 percent in NO{sub x} and 50 percent in SO{sub x} emissions, by a combination of two developed technologies, gas reburning (GR) and sorbent injection (SI). With GR, about 80--85 percent of the coal fuel is fired in the primary combustion zone. The balance of the fuel is added downstream as natural gas to create a slightly fuel rich environment in which NO{sub x} is converted to N{sub 2}. The combustion process is completed by overfire air addition. So{sub x} emissions are reduced by injecting dry sorbents (usually calcium based) into the upper furnace. The sorbents trap SO{sub x} as solid sulfates that are collected in the particulate control device. This project is conducted in three phases at each site: (1) Design and Permitting; (2) Construction and Startup; and, (3) Operation, Data Collection, Reporting and Disposition. Technology transfer to industry is accomplished through the formation of an industry panel.

  8. Electrochemical, Structural and Surface Characterization of Nickel/Zirconia Solid Oxide Fuel Cell Anodes in Coal Gas Containing Antimony

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Thomsen, Edwin C.; Nachimuthu, Ponnusamy; Edwards, Danny J.

    2011-02-27

    The interaction of antimony with the nickel-zirconia solid oxide fuel cell (SOFC) anode has been investigated. Tests with both anode-supported and electrolyte-supported button cells were performed at 700 and 800oC in synthetic coal gas containing 10 ppb to 9 ppm antimony. Minor performance loss was observed immediately after Sb introduction to coal gas resulting in ca. 5 % power output drop. While no further degradation was observed during the following several hundred hours of testing, cells abruptly and irreversibly failed after 800-1500 hours depending on Sb concentration and test temperature. Antimony was found to interact strongly with nickel and result in extensive alteration phase formation, consistent with expectations based on thermodynamic properties. Nickel antimonide phases, NiSb and Ni5Sb2, were partially coalesced into large grains and eventually affected electronic percolation through the anode support. Initial degradation was attributed to diffusion of antimony to the active anode/electrolyte interface to form an adsorption layer.

  9. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1993-02-01

    Through the mid-1980s, Air Products has brought the liquid phase approach to a number of other synthesis gas reactions where effective heat management is a key issue. In 1989, in response to DOE`s PRDA No. DE-RA22-88PC88805, Air Products proposed a research and development program entitled ``Synthesis of Dimethyl Ether and Alternative Fuels in the Liquid Phase from Coal Derived Syngas.`` The proposal aimed at extending the LPMEOH experience to convert coal-derived synthesis gas to other useful fuels and chemicals. The work proposed included development of a novel one-step synthesis of dimethyl ether (DME) from syngas, and exploration of other liquid phase synthesis of alternative fuel directly from syngas. The one-step DME process, conceived in 1986 at Air Products as a means of increasing syngas conversion to liquid products, envisioned the concept of converting product methanol in situ to DME in a single reactor. The slurry reactor based liquid phase technology is ideally suited for such an application, since the second reaction (methanol to DME) can be accomplished by adding a second catalyst with dehydration activity to the methanol producing reactor. An area of exploration for other alternative fuels directly from syngas was single-step slurry phase synthesis of hydrocarbons via methanol and DME as intermediates. Other possibilities included the direct synthesis of mixed alcohols and mixed ethers in a slurry reactor.

  10. MULTIPHASE REACTOR MODELING FOR ZINC CHLORIDE CATALYZED COAL LIQUEFACTION

    E-Print Network [OSTI]

    Joyce, Peter James

    2011-01-01

    labeled for hydrogen, coal, and liquid and gas phase water.is employed to deliver coal- derived liquids to the domesticMultiphase Flow of Gas-Liquid and Gas-Coal Slurry Mixtures

  11. Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals

    SciTech Connect (OSTI)

    Sun, Xiaolei; Rink, Nancy

    2011-04-30

    This report presents the results of the research and development conducted on an Advanced Hydrogasification Process (AHP) conceived and developed by Arizona Public Service Company (APS) under U.S. Department of Energy (DOE) contract: DE-FC26-06NT42759 for Substitute Natural Gas (SNG) production from western coal. A double-wall (i.e., a hydrogasification contained within a pressure shell) down-flow hydrogasification reactor was designed, engineered, constructed, commissioned and operated by APS, Phoenix, AZ. The reactor is ASME-certified under Section VIII with a rating of 1150 pounds per square inch gage (psig) maximum allowable working pressure at 1950 degrees Fahrenheit ({degrees}F). The reaction zone had a 1.75 inch inner diameter and 13 feet length. The initial testing of a sub-bituminous coal demonstrated ~ 50% carbon conversion and ~10% methane yield in the product gas under 1625{degrees}F, 1000 psig pressure, with a 11 seconds (s) residence time, and 0.4 hydrogen-to-coal mass ratio. Liquid by-products mainly contained Benzene, Toluene, Xylene (BTX) and tar. Char collected from the bottom of the reactor had 9000-British thermal units per pound (Btu/lb) heating value. A three-dimensional (3D) computational fluid dynamic model simulation of the hydrodynamics around the reactor head was utilized to design the nozzles for injecting the hydrogen into the gasifier to optimize gas-solid mixing to achieve improved carbon conversion. The report also presents the evaluation of using algae for carbon dioxide (CO{sub 2}) management and biofuel production. Nannochloropsis, Selenastrum and Scenedesmus were determined to be the best algae strains for the project purpose and were studied in an outdoor system which included a 6-meter (6M) radius cultivator with a total surface area of 113 square meters (m{sup 2}) and a total culture volume between 10,000 to 15,000 liters (L); a CO{sub 2} on-demand feeding system; an on-line data collection system for temperature, pH, Photosynthetically Activate Radiation (PAR) and dissolved oxygen (DO); and a ~2 gallons per minute (gpm) algae culture dewatering system. Among the three algae strains, Scenedesmus showed the most tolerance to temperature and irradiance conditions in Phoenix and the best self-settling characteristics. Experimental findings and operational strategies determined through these tests guided the operation of the algae cultivation system for the scale-up study. Effect of power plant flue gas, especially heavy metals, on algae growth and biomass adsorption were evaluated as well.

  12. PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS

    SciTech Connect (OSTI)

    J. Douglas Way

    2003-01-01

    For hydrogen from coal gasification to be used economically, processing approaches that produce a high purity gas must be developed. Palladium and its alloys, nickel, platinum and the metals in Groups 3 to 5 of the Periodic Table are all permeable to hydrogen. Hydrogen permeable metal membranes made of palladium and its alloys are the most widely studied due to their high hydrogen permeability, chemical compatibility with many hydrocarbon containing gas streams, and infinite hydrogen selectivity. Our Pd composite membranes have demonstrated stable operation at 450 C for over 70 days. Coal derived synthesis gas will contain up to 15000 ppm H{sub 2}S as well as CO, CO{sub 2}, N{sub 2} and other gases. Highly selectivity membranes are necessary to reduce the H{sub 2}S concentration to acceptable levels for solid oxide and other fuel cell systems. Pure Pd-membranes are poisoned by sulfur, and suffer from mechanical problems caused by thermal cycling and hydrogen embrittlement. Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H{sub 2} separation. These membranes consist of a thin ({le} 5 {micro}m) film of metal deposited on the inner surface of a porous metal or ceramic tube. With support from this DOE Grant, we have fabricated thin, high flux Pd-Cu alloy composite membranes using a sequential electroless plating approach. Thin, Pd{sub 60}Cu{sub 40} films exhibit a hydrogen flux more than ten times larger than commercial polymer membranes for H{sub 2} separation, resist poisoning by H{sub 2}S and other sulfur compounds typical of coal gas, and exceed the DOE Fossil Energy target hydrogen flux of 80 ml/cm{sup 2} {center_dot} min = 0.6 mol/m{sup 2} {center_dot} s for a feed pressure of 40 psig. Similar Pd-membranes have been operated at temperatures as high as 750 C. We have developed practical electroless plating procedures for fabrication of thin Pd-Cu composite membranes at any scale.

  13. Zevenhoven & Kilpinen CROSS EFFECTS, TOTAL SYSTEM LAY-OUT 13.6.2001 10-1 Figure 10.1 Typical pulverised coal combustion and gas clean-up system: dry scrubber +

    E-Print Network [OSTI]

    Zevenhoven, Ron

    pulverised coal combustion and gas clean-up system: dry scrubber + baghouse filter for SO2 and particulate the emissions regulations depend on process type and plant size. Some compounds such as alkali or chlorine may For a conventional pulverised coal-fired power plant a set-up is shown in Figure 10.1, with a gas clean-up system

  14. RCW 79.14 Mineral, Coal, Oil and Gas Leases | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/NevadaaTools < RAPID79.14 Mineral, Coal, Oil and

  15. Measurement of gas species, temperatures, coal burnout, and wall heat fluxes in a 200 MWe lignite-fired boiler with different overfire air damper openings

    SciTech Connect (OSTI)

    Jianping Jing; Zhengqi Li; Guangkui Liu; Zhichao Chen; Chunlong Liu

    2009-07-15

    Measurements were performed on a 200 MWe, wall-fired, lignite utility boiler. For different overfire air (OFA) damper openings, the gas temperature, gas species concentration, coal burnout, release rates of components (C, H, and N), furnace temperature, and heat flux and boiler efficiency were measured. Cold air experiments for a single burner were conducted in the laboratory. The double-swirl flow pulverized-coal burner has two ring recirculation zones starting in the secondary air region in the burner. As the secondary air flow increases, the axial velocity of air flow increases, the maxima of radial velocity, tangential velocity and turbulence intensity all increase, and the swirl intensity of air flow and the size of recirculation zones increase slightly. In the central region of the burner, as the OFA damper opening widens, the gas temperature and CO concentration increase, while the O{sub 2} concentration, NOx concentration, coal burnout, and release rates of components (C, H, and N) decrease, and coal particles ignite earlier. In the secondary air region of the burner, the O{sub 2} concentration, NOx concentration, coal burnout, and release rates of components (C, H, and N) decrease, and the gas temperature and CO concentration vary slightly. In the sidewall region, the gas temperature, O{sub 2} concentration, and NOx concentration decrease, while the CO concentration increases and the gas temperature varies slightly. The furnace temperature and heat flux in the main burning region decrease appreciably, but increase slightly in the burnout region. The NOx emission decreases from 1203.6 mg/m{sup 3} (6% O{sub 2}) for a damper opening of 0% to 511.7 mg/m{sup 3} (6% O{sub 2}) for a damper opening of 80% and the boiler efficiency decreases from 92.59 to 91.9%. 15 refs., 17 figs., 3 tabs.

  16. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    cycle gas turbine power plant carbon capture and storagewind hybrid combined cycle power plant natural gas combinedPower Plants study, Volume 1: Bituminous Coal and Natural Gas

  17. Optical fiber evanescent wave adsorption sensors for high-temperature gas sensing in advanced coal-fired power plants

    SciTech Connect (OSTI)

    Buric, M.; Ohodnicky, P.; Duy, J.

    2012-01-01

    Modern advanced energy systems such as coal-fired power plants, gasifiers, or similar infrastructure present some of the most challenging harsh environments for sensors. The power industry would benefit from new, ultra-high temperature devices capable of surviving in hot and corrosive environments for embedded sensing at the highest value locations. For these applications, we are currently exploring optical fiber evanescent wave absorption spectroscopy (EWAS) based sensors consisting of high temperature core materials integrated with novel high temperature gas sensitive cladding materials. Mathematical simulations can be used to assist in sensor development efforts, and we describe a simulation code that assumes a single thick cladding layer with gas sensitive optical constants. Recent work has demonstrated that Au nanoparticle-incorporated metal oxides show a potentially useful response for high temperature optical gas sensing applications through the sensitivity of the localized surface plasmon resonance absorption peak to ambient atmospheric conditions. Hence, the simulation code has been applied to understand how such a response can be exploited in an optical fiber based EWAS sensor configuration. We demonstrate that interrogation can be used to optimize the sensing response in such materials.

  18. ADVANCED FLUE GAS CONDITIONING AS A RETROFIT UPGRADE TO ENHANCE PM COLLECTION FROM COAL-FIRED ELECTRIC UTILITY BOILERS

    SciTech Connect (OSTI)

    Kenneth E. Baldrey

    2003-07-30

    The U.S. Department of Energy and ADA Environmental Solutions are engaged in a project to develop commercial flue gas conditioning additives. The objective is to develop conditioning agents that can help improve particulate control performance of smaller or under-sized electrostatic precipitators on utility coal-fired boilers. The new chemicals will be used to control both the electrical resistivity and the adhesion or cohesivity of the fly ash. There is a need to provide cost-effective and safer alternatives to traditional flue gas conditioning with SO{sub 3} and ammonia. This quarterly report summarizes project activity for the period April-June, 2003. In this period there was limited activity and no active field trials. Results of ash analysis from the AEP Conesville demonstration were received. In addition, a site visit was made to We Energies Presque Isle Power Plant and a proposal extended for a flue gas conditioning trial with the ADA-51 cohesivity additive. It is expected that this will be the final full-scale evaluation on the project.

  19. Comparing and assessing different measurement techniques for mercury in coal systhesis gas

    SciTech Connect (OSTI)

    Maxwell, D.P.; Richardson, C.F. [Radian Corporation, Austin, TX (United States)

    1995-11-01

    Three mercury measurement techniques were performed on synthesis gas streams before and after an amine-based sulfur removal system. The syngas was sampled using (1) gas impingers containing a nitric acid-hydrogen peroxide solution, (2) coconut-based charcoal sorbent, and (3) an on-line atomic absorption spectrophotometer equipped with a gold amalgamation trap and cold vapor cell. Various impinger solutions were applied upstream of the gold amalgamation trap to remove hydrogen sulfide and isolate oxidized and elemental species of mercury. The results from these three techniques are compared to provide an assessment of these measurement techniques in reducing gas atmospheres.

  20. Coal: the new black

    SciTech Connect (OSTI)

    Tullo, A.H.; Tremblay, J.-F.

    2008-03-15

    Long eclipsed by oil and natural gas as a raw material for high-volume chemicals, coal is making a comeback, with oil priced at more than $100 per barrel. It is relatively cheap feedstock for chemicals such as methanol and China is building plants to convert coal to polyolefins on a large scale and interest is spreading worldwide. Over the years several companies in the US and China have made fertilizers via the gasification of coal. Eastman in Tennessee gasifies coal to make methanol which is then converted to acetic acid, acetic anhydride and acetate fiber. The future vision is to convert methanol to olefins. UOP and Lurgi are the major vendors of this technology. These companies are the respective chemical engineering arms of Honeywell and Air Liquide. The article reports developments in China, USA and India on coal-to-chemicals via coal gasification or coal liquefaction. 2 figs., 2 photo.

  1. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal

    SciTech Connect (OSTI)

    Nick Degenstein; Minish Shah; Doughlas Louie

    2012-05-01

    The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

  2. Coal sector profile

    SciTech Connect (OSTI)

    Not Available

    1990-06-05

    Coal is our largest domestic energy resource with recoverable reserves estimated at 268 billion short tons or 5.896 quads Btu equivalent. This is approximately 95 percent of US fossil energy resources. It is relatively inexpensive to mine, and on a per Btu basis it is generally much less costly to produce than other energy sources. Its chief drawbacks are the environmental, health and safety concerns that must be addressed in its production and consumption. Historically, coal has played a major role in US energy markets. Coal fueled the railroads, heated the homes, powered the factories. and provided the raw materials for steel-making. In 1920, coal supplied over three times the amount of energy of oil, gas, and hydro combined. From 1920 until the mid 1970s, coal production remained fairly constant at 400 to 600 million short tons a year. Rapid increases in overall energy demands, which began during and after World War II were mostly met by oil and gas. By the mid 1940s, coal represented only half of total energy consumption in the US. In fact, post-war coal production, which had risen in support of the war effort and the postwar Marshall plan, decreased approximately 25 percent between 1945 and 1960. Coal demand in the post-war era up until the 1970s was characterized by increasing coal use by the electric utilities but decreasing coal use in many other markets (e.g., rail transportation). The oil price shocks of the 1970s, combined with natural gas shortages and problems with nuclear power, returned coal to a position of prominence. The greatly expanded use of coal was seen as a key building block in US energy strategies of the 1970s. Coal production increased from 613 million short tons per year in 1970 to 950 million short tons in 1988, up over 50 percent.

  3. Development of Superior Sorbents for Separation of CO2 from Flue Gas at a Wide Temperature range during Coal Combustion

    SciTech Connect (OSTI)

    Panagiotis Smirniotis

    2002-09-17

    A number basic sorbents based on CaO were synthesized, characterized with novel techniques and tested for sorption of CO{sub 2} and selected gas mixtures simulating flue gas from coal fired boilers. Our studies resulted in highly promising sorbents which demonstrated zero affinity for N{sub 2}, O{sub 2}, SO{sub 2}, and NO very low affinity for water, ultrahigh CO{sub 2} sorption capacities, and rapid sorption characteristics, CO{sub 2} sorption at a very wide temperature range, durability, and low synthesis cost. One of the 'key' characteristics of the proposed materials is the fact that we can control very accurately their basicity (optimum number of basic sites of the appropriate strength) which allows for the selective chemisorption of CO{sub 2} at a wide range of temperatures. These unique characteristics of this family of sorbents offer high promise for development of advanced industrial sorbents for the effective CO{sub 2} removal.

  4. A New Coal-Permeability Model: Internal Swelling Stress and Fracture–Matrix Interaction

    E-Print Network [OSTI]

    Liu, Hui-Hai; Rutqvist, Jonny

    2010-01-01

    L. : Adsorption-induced coal swelling and stress:acid gas sequestration into coal seams. J Geophys. Res. (fracturing on permeability of coal. Min. Sci. Technol. 3,

  5. A new coal-permeability model: Internal swelling stress and fracture-matrix interaction

    E-Print Network [OSTI]

    Liu, H.H.

    2010-01-01

    of carbon dioxide in coal with enhanced coalbed methaneL. Adsorption-induced coal swelling and stress: Implicationsand acid gas sequestration into coal seams. J Geophys Res. (

  6. Table 6. Electric power delivered fuel prices and quality for coal, petroleum, natural gas, 1990 - 2013

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price toStocksU.S. shale gas plays: natural gasPetroleum NetCrude oil

  7. Table 6. Electric power delivered fuel prices and quality for coal, petroleum, natural gas, 1990 - 2013

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Informationmonthly gasoline price toStocksU.S. shale gas plays: natural gasPetroleum NetCrude

  8. Determination of the Effect of Coal/Biomass-Derived Syngas Contaminants on the Performance of Fischer-Tropsch and Water-Gas-Shift Catalysts

    SciTech Connect (OSTI)

    Trembly, Jason; Cooper, Matthew; Farmer, Justin; Turk, Brian; Gupta, Raghubir

    2010-12-31

    Today, nearly all liquid fuels and commodity chemicals are produced from non-renewable resources such as crude oil and natural gas. Because of increasing scrutiny of carbon dioxide (CO{sub 2}) emissions produced using traditional fossil-fuel resources, the utilization of alternative feedstocks for the production of power, hydrogen, value-added chemicals, and high-quality hydrocarbon fuels such as diesel and substitute natural gas (SNG) is critical to meeting the rapidly growing energy needs of modern society. Coal and biomass are particularly attractive as alternative feedstocks because of the abundant reserves of these resources worldwide. The strategy of co-gasification of coal/biomass (CB) mixtures to produce syngas for synthesis of Fischer-Tropsch (FT) fuels offers distinct advantages over gasification of either coal or biomass alone. Co-feeding coal with biomass offers the opportunity to exploit economies of scale that are difficult to achieve in biomass gasification, while the addition of biomass to the coal gasifier feed leverages proven coal gasification technology and allows CO{sub 2} credit benefits. Syngas generated from CB mixtures will have a unique contaminant composition because coal and biomass possess different concentrations and types of contaminants, and the final syngas composition is also strongly influenced by the gasification technology used. Syngas cleanup for gasification of CB mixtures will need to address this unique contaminant composition to support downstream processing and equipment. To investigate the impact of CB gasification on the production of transportation fuels by FT synthesis, RTI International conducted thermodynamic studies to identify trace contaminants that will react with water-gas-shift and FT catalysts and built several automated microreactor systems to investigate the effect of single components and the synergistic effects of multiple contaminants on water-gas-shift and FT catalyst performance. The contaminants investigated were sodium chloride (NaCl), potassium chloride (KCl), hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), ammonia (NH{sub 3}), and combinations thereof. This report details the thermodynamic studies and the individual and multi-contaminant results from this testing program.

  9. Cooperative research on the combustion characteristics of cofired desulfurized Illinois coal and char with natural gas. Final technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    Buckius, R.O.; Wu, Cheng-Kang; Krier, H.; Peters, J.E. [Illinois Univ., Urbana-Champaign, IL (United States)

    1992-12-31

    The DTFF is extended to larger sample collecting capability and higher temperatures, resulting in the establishment of the Ash Characterization Facility and the High Temperature Drop Tube Furnace. The Ash Characterization Facility enables continuous coal injection and sampling under controlled conditions. Several hundred milligrams of char or ash can be collected in one-half hour. The High Temperature Drop Tube Furnace uses a plasma torch to preheat the gas to over 2000 K and inject it into a ceramic tube which enters a furnace designed for 1700{degrees}C (1973 K) operation, so that temperatures and heating rates encountered by pulverized coal particles in the flames of large boilers or in the advanced slagging cyclone combustors can be simulated. An aerodynamic coal feeder works well in supplying coal continuously to the drop tube. A watercooled, Helium-quench sampling probe collects the solid samples. A scanning electron microscope is used to study the morphology of ash and char particles. A sulfur determinator, a gas chromatograph provide analytical means in the laboratory, and the Illinois State Geological Survey performs other necessary analyses of the samples. Tests on cofiring coal with I to 4% methane show that sulfur retention in ash was related to temperature and residence time. The addition of methane caused changes in gas temperature profile in the tube and also changes in chemical composition of the gases. The overall effect on sulfur retention is seen to be a result of several complex interacting factors. Further detailed studies are necessary to clarify the contribution of each factor and to provide clues to the mechanism of the process.

  10. Robust Low-Cost Water-Gas Shift Membrane Reactor for High-Purity Hydrogen Production form Coal-Derived Syngas

    SciTech Connect (OSTI)

    James Torkelson; Neng Ye; Zhijiang Li; Decio Coutinho; Mark Fokema

    2008-05-31

    This report details work performed in an effort to develop a low-cost, robust water gas shift membrane reactor to convert coal-derived syngas into high purity hydrogen. A sulfur- and halide-tolerant water gas shift catalyst and a sulfur-tolerant dense metallic hydrogen-permeable membrane were developed. The materials were integrated into a water gas shift membrane reactor in order to demonstrate the production of >99.97% pure hydrogen from a simulated coal-derived syngas stream containing 2000 ppm hydrogen sulfide. The objectives of the program were to (1) develop a contaminant-tolerant water gas shift catalyst that is able to achieve equilibrium carbon monoxide conversion at high space velocity and low steam to carbon monoxide ratio, (2) develop a contaminant-tolerant hydrogen-permeable membrane with a higher permeability than palladium, (3) demonstrate 1 L/h purified hydrogen production from coal-derived syngas in an integrated catalytic membrane reactor, and (4) conduct a cost analysis of the developed technology.

  11. Partitioning of mercury, arsenic, selenium, boron, and chloride in a full-scale coal combustion process equipped with selective catalytic reduction, electrostatic precipitation, and flue gas desulfurization systems

    SciTech Connect (OSTI)

    Chin-Min Cheng; Pauline Hack; Paul Chu; Yung-Nan Chang; Ting-Yu Lin; Chih-Sheng Ko; Po-Han Chiang; Cheng-Chun He; Yuan-Min Lai; Wei-Ping Pan

    2009-09-15

    A full-scale field study was carried out at a 795 MWe coal-fired power plant equipped with selective catalytic reduction (SCR), an electrostatic precipitator (ESP), and wet flue gas desulfurization (FGD) systems to investigate the distribution of selected trace elements (i.e., mercury, arsenic, selenium, boron, and chloride) from coal, FGD reagent slurry, makeup water to flue gas, solid byproduct, and wastewater streams. Flue gases were collected from the SCR outlet, ESP inlet, FGD inlet, and stack. Concurrent with flue gas sampling, coal, bottom ash, economizer ash, and samples from the FGD process were also collected for elemental analysis. By combining plant operation parameters, the overall material balances of selected elements were established. The removal efficiencies of As, Se, Hg, and B by the ESP unit were 88, 56, 17, and 8%, respectively. Only about 2.5% of Cl was condensed and removed from flue gas by fly ash. The FGD process removed over 90% of Cl, 77% of B, 76% of Hg, 30% of Se, and 5% of As. About 90% and 99% of the FGD-removed Hg and Se were associated with gypsum. For B and Cl, over 99% were discharged from the coal combustion process with the wastewater. Mineral trona (trisodium hydrogendicarbonate dehydrate, Na{sub 3}H(CO{sub 3}){sub 2}.2H{sub 2}O) was injected before the ESP unit to control the emission of sulfur trioxide (SO{sub 3}). By comparing the trace elements compositions in the fly ash samples collected from the locations before and after the trona injection, the injection of trona did not show an observable effect on the partitioning behaviors of selenium and arsenic, but it significantly increased the adsorption of mercury onto fly ash. The stack emissions of mercury, boron, selenium, and chloride were for the most part in the gas phase. 47 refs., 3 figs., 11 tabs.

  12. Proceedings, twenty-fourth annual international Pittsburgh coal conference

    SciTech Connect (OSTI)

    2007-07-01

    Topics covered include: gasification technologies; coal production and preparation; combustion technologies; environmental control technologies; synthesis of liquid fuels, chemicals, materials and other non-fuel uses of coal; hydrogen from coal; advanced synthesis gas cleanup; coal chemistry, geosciences and resources; Fischer-Tropsch technology; coal and sustainability; global climate change; gasification (including underground gasification); materials, instrumentation and controls; and coal utilisation byproducts.

  13. Proceedings, twenty-five annual international Pittsburgh coal conference

    SciTech Connect (OSTI)

    NONE

    2008-07-01

    The conference theme was 'coal - energy, environment and sustainable development'. The topics covered energy and environmental issues, and technologies related to coal and its byproducts. These included: gasification, hydrogen from coal, combustion technologies, coal production and preparation, synthesis of liquid fuels, gas turbines and fuel cells for synthesis gas and hydrogen applications, coal chemistry and geosciences, global climate change, underground coal gasification, environmental control technologies, and coal utilization byproducts.

  14. Supersonic coal water slurry fuel atomizer

    DOE Patents [OSTI]

    Becker, Frederick E. (Reading, MA); Smolensky, Leo A. (Concord, MA); Balsavich, John (Foxborough, MA)

    1991-01-01

    A supersonic coal water slurry atomizer utilizing supersonic gas velocities to atomize coal water slurry is provided wherein atomization occurs externally of the atomizer. The atomizer has a central tube defining a coal water slurry passageway surrounded by an annular sleeve defining an annular passageway for gas. A converging/diverging section is provided for accelerating gas in the annular passageway to supersonic velocities.

  15. Preliminary draft industrial siting administration permit application: Socioeconomic factors technical report. Final technical report, November 1980-May 1982. [Proposed WyCoalGas project in Converse County, Wyoming

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    Under the with-project scenario, WyCoalGas is projected to make a difference in the long-range future of Converse County. Because of the size of the proposed construction and operations work forces, the projected changes in employment, income, labor force, and population will alter Converse County's economic role in the region. Specifically, as growth occurs, Converse County will begin to satisfy a larger portion of its own higher-ordered demands, those that are currently being satisfied by the economy of Casper. Business-serving and household-serving activities, currently absent, will find the larger income and population base forecast to occur with the WyCoalGas project desirable. Converse County's economy will begin to mature, moving away from strict dependence on extractive industries to a more sophisticated structure that could eventually appeal to national, and certainly, regional markets. The technical demand of the WyCoalGas plant will mean a significant influx of varying occupations and skills. The creation of basic manufacturing, advanced trade and service sectors, and concomitant finance and transportation firms will make Converse County more economically autonomous. The county will also begin to serve market center functions for the smaller counties of eastern Wyoming that currently rely on Casper, Cheyenne or other distant market centers. The projected conditions expected to exist in the absence of the WyCoalGas project, the socioeconomic conditions that would accompany the project, and the differences between the two scenarios are considered. The analysis is keyed to the linkages between Converse County and Natrona County.

  16. Metal-Organic Frameworks Capture CO2 From Coal Gasification Flue Gas |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeatMaRIEdioxide capture | Center for Gas

  17. Hydrogen Resource Assessment: Hydrogen Potential from Coal, Natural Gas, Nuclear, and Hydro Power

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (JournalvivoHighHussein Khalil HusseinH2FAST NationalGas

  18. Evaluation of gasification and gas cleanup processes for use in molten carbonate fuel cell power plants. Final report. [Contains lists and evaluations of coal gasification and fuel gas desulfurization processes

    SciTech Connect (OSTI)

    Jablonski, G.; Hamm, J.R.; Alvin, M.A.; Wenglarz, R.A.; Patel, P.

    1982-01-01

    This report satisfies the requirements for DOE Contract AC21-81MC16220 to: List coal gasifiers and gas cleanup systems suitable for supplying fuel to molten carbonate fuel cells (MCFC) in industrial and utility power plants; extensively characterize those coal gas cleanup systems rejected by DOE's MCFC contractors for their power plant systems by virtue of the resources required for those systems to be commercially developed; develop an analytical model to predict MCFC tolerance for particulates on the anode (fuel gas) side of the MCFC; develop an analytical model to predict MCFC anode side tolerance for chemical species, including sulfides, halogens, and trace heavy metals; choose from the candidate gasifier/cleanup systems those most suitable for MCFC-based power plants; choose a reference wet cleanup system; provide parametric analyses of the coal gasifiers and gas cleanup systems when integrated into a power plant incorporating MCFC units with suitable gas expansion turbines, steam turbines, heat exchangers, and heat recovery steam generators, using the Westinghouse proprietary AHEAD computer model; provide efficiency, investment, cost of electricity, operability, and environmental effect rankings of the system; and provide a final report incorporating the results of all of the above tasks. Section 7 of this final report provides general conclusions.

  19. Partial Oxidation Gas Turbine for Power and Hydrogen Co-Production from Coal-Derived Fuel in Industrial Applications

    SciTech Connect (OSTI)

    Joseph Rabovitser

    2009-06-30

    The report presents a feasibility study of a new type of gas turbine. A partial oxidation gas turbine (POGT) shows potential for really high efficiency power generation and ultra low emissions. There are two main features that distinguish a POGT from a conventional gas turbine. These are associated with the design arrangement and the thermodynamic processes used in operation. A primary design difference of the POGT is utilization of a non?catalytic partial oxidation reactor (POR) in place of a conventional combustor. Another important distinction is that a much smaller compressor is required, one that typically supplies less than half of the air flow required in a conventional gas turbine. From an operational and thermodynamic point of view a key distinguishing feature is that the working fluid, fuel gas provided by the OR, has a much higher specific heat than lean combustion products and more energy per unit mass of fluid can be extracted by the POGT expander than in the conventional systems. The POGT exhaust stream contains unreacted fuel that can be combusted in different bottoming ycle or used as syngas for hydrogen or other chemicals production. POGT studies include feasibility design for conversion a conventional turbine to POGT duty, and system analyses of POGT based units for production of power solely, and combined production of power and yngas/hydrogen for different applications. Retrofit design study was completed for three engines, SGT 800, SGT 400, and SGT 100, and includes: replacing the combustor with the POR, compressor downsizing for about 50% design flow rate, generator replacement with 60 90% ower output increase, and overall unit integration, and extensive testing. POGT performances for four turbines with power output up to 350 MW in POGT mode were calculated. With a POGT as the topping cycle for power generation systems, the power output from the POGT ould be increased up to 90% compared to conventional engine keeping hot section temperatures, pressures, and volumetric flows practically identical. In POGT mode, the turbine specific power (turbine net power per lb mass flow from expander exhaust) is twice the value of the onventional turbine. POGT based IGCC plant conceptual design was developed and major components have been identified. Fuel flexible fluid bed gasifier, and novel POGT unit are the key components of the 100 MW IGCC plant for co producing electricity, hydrogen and/or yngas. Plant performances were calculated for bituminous coal and oxygen blown versions. Various POGT based, natural gas fueled systems for production of electricity only, coproduction of electricity and hydrogen, and co production of electricity and syngas for gas to liquid and hemical processes were developed and evaluated. Performance calculations for several versions of these systems were conducted. 64.6 % LHV efficiency for fuel to electricity in combined cycle was achieved. Such a high efficiency arise from using of syngas from POGT exhaust s a fuel that can provide required temperature level for superheated steam generation in HRSG, as well as combustion air preheating. Studies of POGT materials and combustion instabilities in POR were conducted and results reported. Preliminary market assessment was performed, and recommendations for POGT systems applications in oil industry were defined. POGT technology is ready to proceed to the engineering prototype stage, which is recommended.

  20. Clean coal

    SciTech Connect (OSTI)

    Liang-Shih Fan; Fanxing Li [Ohio State University, OH (United States). Dept. of Chemical and Biomolecular Engineering

    2006-07-15

    The article describes the physics-based techniques that are helping in clean coal conversion processes. The major challenge is to find a cost- effective way to remove carbon dioxide from the flue gas of power plants. One industrially proven method is to dissolve CO{sub 2} in the solvent monoethanolamine (MEA) at a temperature of 38{sup o}C and then release it from the solvent in another unit when heated to 150{sup o}C. This produces CO{sub 2} ready for sequestration. Research is in progress with alternative solvents that require less energy. Another technique is to use enriched oxygen in place of air in the combustion process which produces CO{sub 2} ready for sequestration. A process that is more attractive from an energy management viewpoint is to gasify coal so that it is partially oxidized, producing a fuel while consuming significantly less oxygen. Several IGCC schemes are in operation which produce syngas for use as a feedstock, in addition to electricity and hydrogen. These schemes are costly as they require an air separation unit. Novel approaches to coal gasification based on 'membrane separation' or chemical looping could reduce the costs significantly while effectively capturing carbon dioxide. 1 ref., 2 figs., 1 photo.

  1. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    IGCC PC advanced coal-wind hybrid combined cycle power plantnatural gas combined cycle gas turbine power plant carboncrude gasification combined cycle power plant with carbon

  2. Fact #844: October 27, 2014 Electricity Generated from Coal has...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    4: October 27, 2014 Electricity Generated from Coal has Declined while Generation from Natural Gas has Grown Fact 844: October 27, 2014 Electricity Generated from Coal has...

  3. Biogeochemistry of Microbial Coal-Bed Methane

    E-Print Network [OSTI]

    Macalady, Jenn

    Biogeochemistry of Microbial Coal-Bed Methane Dariusz Strapo´c,1, Maria Mastalerz,2 Katherine, biodegradation Abstract Microbial methane accumulations have been discovered in multiple coal- bearing basins low-maturity coals with predominantly microbial methane gas or uplifted coals containing older

  4. Method of extracting coal from a coal refuse pile

    DOE Patents [OSTI]

    Yavorsky, Paul M. (Monongahela, PA)

    1991-01-01

    A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

  5. Coal-oil slurry preparation

    DOE Patents [OSTI]

    Tao, John C. (Perkiomenville, PA)

    1983-01-01

    A pumpable slurry of pulverized coal in a coal-derived hydrocarbon oil carrier which slurry is useful as a low-ash, low-sulfur clean fuel, is produced from a high sulfur-containing coal. The initial pulverized coal is separated by gravity differentiation into (1) a high density refuse fraction containing the major portion of non-coal mineral products and sulfur, (2) a lowest density fraction of low sulfur content and (3) a middlings fraction of intermediate sulfur and ash content. The refuse fraction (1) is gasified by partial combustion producing a crude gas product from which a hydrogen stream is separated for use in hydrogenative liquefaction of the middlings fraction (3). The lowest density fraction (2) is mixed with the liquefied coal product to provide the desired fuel slurry. Preferably there is also separately recovered from the coal liquefaction LPG and pipeline gas.

  6. A new coal-permeability model: Internal swelling stress and fracture-matrix interaction

    E-Print Network [OSTI]

    Liu, H.H.

    2010-01-01

    2005) Table 1. Properties of coal cores used in laboratorythe same values for coal mechanical properties and matrixeffect of coal’s elastic properties and gas sorption on the

  7. A New Coal-Permeability Model: Internal Swelling Stress and Fracture–Matrix Interaction

    E-Print Network [OSTI]

    Liu, Hui-Hai; Rutqvist, Jonny

    2010-01-01

    the same values for coal mechanical properties and matrixbined effect of coal’s elastic properties and gas sorptionPermeability Model Table 1 Properties of coal cores used in

  8. Impact of Contaminants Present in Coal-Biomass Derived Synthesis Gas on Water-gas Shift and Fischer-Tropsch Synthesis Catalysts

    SciTech Connect (OSTI)

    Gokhan Alptekin

    2012-09-30

    Co-gasification of biomass and coal in large-scale, Integrated Gasification Combined Cycle (IGCC) plants increases the efficiency and reduces the environmental impact of making synthesis gas ("syngas") that can be used in Coal-Biomass-to-Liquids (CBTL) processes for producing transportation fuels. However, the water-gas shift (WGS) and Fischer-Tropsch synthesis (FTS) catalysts used in these processes may be poisoned by multiple contaminants found in coal-biomass derived syngas; sulfur species, trace toxic metals, halides, nitrogen species, the vapors of alkali metals and their salts (e.g., KCl and NaCl), ammonia, and phosphorous. Thus, it is essential to develop a fundamental understanding of poisoning/inhibition mechanisms before investing in the development of any costly mitigation technologies. We therefore investigated the impact of potential contaminants (H{sub 2}S, NH{sub 3}, HCN, AsH{sub 3}, PH{sub 3}, HCl, NaCl, KCl, AS{sub 3}, NH{sub 4}NO{sub 3}, NH{sub 4}OH, KNO{sub 3}, HBr, HF, and HNO{sub 3}) on the performance and lifetime of commercially available and generic (prepared in-house) WGS and FT catalysts; ferrochrome-based high-temperature WGS catalyst (HT-WGS, Shiftmax 120�, Süd-Chemie), low-temperature Cu/ZnO-based WGS catalyst (LT-WGS, Shiftmax 230�, Süd-Chemie), and iron- and cobalt-based Fischer-Trospch synthesis catalysts (Fe-FT & Co-FT, UK-CAER). In this project, TDA Research, Inc. collaborated with a team at the University of Kentucky Center for Applied Energy Research (UK-CAER) led by Dr. Burt Davis. We first conducted a detailed thermodynamic analysis. The three primary mechanisms whereby the contaminants may deactivate the catalyst are condensation, deposition, and reaction. AsH{sub 3}, PH{sub 3}, H{sub 2}S, HCl, NH{sub 3} and HCN were found to have a major impact on the Fe-FT catalyst by producing reaction products, while NaCl, KCl and PH{sub 3} produce trace amounts of deposition products. The impact of the contaminants on the activity, selectivity, and deactivation rates (lifetime) of the catalysts was determined in bench-scale tests. Most of the contaminants appeared to adsorb onto (or react with) the HT- and LT-WGS catalysts were they were co-fed with the syngas: � 4.5 ppmv AsH{sub 3} or 1 ppmv PH{sub 3} in the syngas impacted the selectivity and CO conversion of both catalysts; � H{sub 2}S slowly degraded both WGS catalysts; - A binary mixture of H{sub 2}S (60 ppmv) and NH{sub 3} (38 ppmv) impacted the activity of the LT-WGS catalyst, but not the HT-WGS catalyst � Moderate levels of NH{sub 3} (100 ppmv) or HCN (10 ppmv) had no impact � NaCl or KCl had essentially no effect on the HT-WGS catalyst, but the activity of the LT-WGS catalyst decreased very slowly Long-term experiments on the Co-FT catalyst at 260 and 270 °C showed that all of the contaminants impacted it to some extent with the exception of NaCl and HF. Irrespective of its source (e.g., NH{sub 3}, KNO{sub 3}, or HNO{sub 3}), ammonia suppressed the activity of the Co-FT catalyst to a moderate degree. There was essentially no impact the Fe-FT catalyst when up to 100 ppmw halide compounds (NaCl and KCl), or up to 40 ppmw alkali bicarbonates (NaHCO{sub 3} and KHCO{sub 3}). After testing, BET analysis showed that the surface areas, and pore volumes and diameters of both WGS catalysts decreased during both single and binary H2S and NH3 tests, which was attributed to sintering and pore filling by the impurities. The HT-WGS catalyst was evaluated with XRD after testing in syngas that contained 1 ppmv PH{sub 3}, or 2 ppmv H{sub 2}S, or both H{sub 2}S (60 ppmv) and NH{sub 3} (38 ppmv). The peaks became sharper during testing, which was indicative of crystal growth and sintering, but no new phases were detected. After LT-WGS tests (3-33 ppmv NH{sub 3} and/or 0-88 ppmv H{sub 2}S) there were a few new phases that appeared, including sulfides. The fresh Fe-FT catalyst was nanocrystalline and amorphous. ICP-AA spectroscopy and other methods (e.g., chromatography) were used to analyze for

  9. Comprehensive report to Congress: Clean Coal Technology program: Evaluation of gas reburning and low-NO sub x burners on a wall-fired boiler

    SciTech Connect (OSTI)

    Not Available

    1990-09-01

    This report briefly describes the Gas Reburning and Low-NO{sub x} Burners technology which is a low-cost technology that can be applied in both retrofit and new applications. This demonstration will be conducted on a utility boiler in Colorado at Cherokee Station {number sign}3; however, the technology is applicable to industrial boilers and other combustion systems. Although this technology is primarily a NO{sub x} reduction technology, some reductions in other emissions will take place. Since 15--20% of the coal is replaced with natural gas, SO{sub 2} and particulate emissions are reduced commensurately. Also the lower carbon-to-hydrogen ratio of natural gas compared to coal reduces CO{sub 2} emissions. The formation of NO{sub x} is controlled by several factors: (1) the amount of nitrogen that is chemically bound in the fuel; (2) the flame temperature; (3) the residence time that combustion products remain at very high temperatures; and (4) the amount of excess oxygen available, especially at the hottest parts of the flame. Decreasing any of these parameters, tends to reduce NO{sub x} formation. 6 figs., 1 tab.

  10. Enhancing the use of coals by gas reburning-sorbent injection: Volume 4 -- Gas reburning-sorbent injection at Lakeside Unit 7, City Water, Light and Power, Springfield, Illinois. Final report

    SciTech Connect (OSTI)

    NONE

    1996-03-01

    A demonstration of Gas Reburning-Sorbent Injection (GR-SI) has been completed at a cyclone-fired utility boiler. The Energy and Environmental Research Corporation (EER) has designed, retrofitted and tested a GR-SI system at City Water Light and Power`s 33 MWe Lakeside Station Unit 7. The program goals of 60% NO{sub x} emissions reduction and 50% SO{sub 2} emissions reduction were exceeded over the long-term testing period; the NO{sub x} reduction averaged 63% and the SO{sub 2} reduction averaged 58%. These were achieved with an average gas heat input of 22% and a calcium (sorbent) to sulfur (coal) molar ratio of 1.8. GR-SI resulted in a reduction in thermal efficiency of approximately 1% at full load due to firing natural gas which forms more moisture in flue gas than coal and also results in a slight increase in air heater exit gas temperature. Minor impacts on other areas of unit performance were measured and are detailed in this report. The project at Lakeside was carried out in three phases, in which EER designed the GR-SI system (Phase 1), completed construction and start-up activities (Phase 2), and evaluated its performance with both short parametric tests and a long-term demonstration (Phase 3). This report contains design and technical performance data; the economics data for all sites are presented in Volume 5.

  11. MTCI advanced coal technologies

    SciTech Connect (OSTI)

    Mansour, M.N.; Chandran, R.R. [Manufacturing and Technology Conversion International, Inc., Columbia, MD (United States)

    1994-12-31

    MTCI is pursuing the development and commercialization of several advanced combustion and gasification systems based on pulse combustion technology. The systems include indirectly heated thermochemical reactor, atmospheric pressure pulse combustor, pulsed atmospheric fluidized bed combustor, direct coal-fired gas turbine pulse combustor island, and advanced concept second-generation pressurized fluidized bed combustor island. Although the systems in toto are capable of processing lignite, subbituminous, bituminous, and anthracite coals in an efficient, economical and environmentally acceptable manner, each system is considered ideal for certain coal types. Brief descriptions of the systems, applications, selected test results and technology status are presented.

  12. FIELD TEST PROGRAM FOR LONG-TERM OPERATION OF A COHPAC SYSTEM FOR REMOVING MERCURY FROM COAL-FIRED FLUE GAS

    SciTech Connect (OSTI)

    Jean Bustard; Charles Lindsey; Paul Brignac; Travis Starns; Sharon Sjostrom; Trent Taylor; Cindy Larson

    2003-10-31

    With the Nation's coal-burning utilities facing the possibility of tighter controls on mercury pollutants, the U.S. Department of Energy is funding projects that could offer power plant operators better ways to reduce these emissions at much lower costs. Sorbent injection technology represents one of the simplest and most mature approaches to controlling mercury emissions from coal-fired boilers. It involves injecting a solid material such as powdered activated carbon into the flue gas. The gas-phase mercury in the flue gas contacts the sorbent and attaches to its surface. The sorbent with the mercury attached is then collected by the existing particle control device along with the other solid material, primarily fly ash. During 2001, ADA Environmental Solutions (ADA-ES) conducted a full-scale demonstration of sorbent-based mercury control technology at the Alabama Power E.C. Gaston Station (Wilsonville, AL). This unit burns a low-sulfur bituminous coal and uses a hot-side electrostatic precipitator (ESP) in combination with a Compact Hybrid Particulate Collector (COHPAC{trademark}) baghouse to collect fly ash. The majority of the fly ash is collected in the ESP with the residual being collected in the COHPAC baghouse. Activated carbon was injected between the ESP and COHPAC units to collect the mercury. Short-term mercury removal levels in excess of 90% were achieved using the COHPAC unit. The test also showed that activated carbon was effective in removing both forms of mercury-elemental and oxidized. However, a great deal of additional testing is required to further characterize the capabilities and limitations of this technology relative to use with baghouse systems such as COHPAC. It is important to determine performance over an extended period of time to fully assess all operational parameters. The project described in this report focuses on fully demonstrating sorbent injection technology at a coal-fired power generating plant that is equipped with a COHPAC system. The overall objective is to evaluate the long-term effects of sorbent injection on mercury capture and COHPAC performance. The work is being done on one-half of the gas stream at Alabama Power Company's Plant Gaston Unit 3 (nominally 135 MW). Data from the testing will be used to determine: (1) If sorbent injection into a high air-to-cloth ratio baghouse is a viable, long-term approach for mercury control; and (2) Design criteria and costs for new baghouse/sorbent injection systems that will use a similar, polishing baghouse (TOXECON{trademark}) approach.

  13. Clean Coal Technology: Reduction of NO{sub x} and SO{sub 2} using gas reburning, sorbent injection, and integrated technologies. Topical report No. 3, Revision 1

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    The Clean Coal Technology Demonstration Program (also referred to as the CCT Program), is a unique government/industry cost-shared effort to develop these advanced coal-based technologies. The CCT Program provides numerous options for addressing a wide range of energy and environmental issues, including acid rain, global climate change, improved energy efficiency, energy security, and environmental qualitiy. It is intended to demonstrate a new generation of full-scale, ``showcase`` facilities built through the United States. Gas Reburning, Sorbent Injection and Integrated Technologies -- the subject of this Topical Report -- are one such set of promising innovative developments. In addition to discussing the technologies involved, this report will describe two specific projects, results to date, and the commercial promise of these processes. The objectives of Gas Reburning and Sorbent Injection were to have a 60% reduction in NO{sub x} emissions and a 50% reduction in SO{sub 2} emissions. These objectives have been achieved at the tangentially-fired boiler at the Hennepin site of Illinois Power and at the cyclone-fired boiler operated by City Water, Light and Power in Springfield, Illinois. The other project, Gas Reburning and Low NO{sub x} Burners had the goal of a 70% NO{sub x} reduction from the wall-fired boiler operated by Public Service of Colorado at Denver. In early preliminary testing, this goal was also achieved. Energy and Environmental Research (EER) is now ready to design and install Gas Rebunting and Sorbent Injection systems, and Gas Reburning-Low NO{sub x}, Burner systems for any utility or industrial application. These technologies are offered with performance and emission control guarantees.

  14. Development of a Hydrogasification Process for Co-Production of Substitute Natural Gas (SNG) and Electric Power from Western Coals-Phase I

    SciTech Connect (OSTI)

    Raymond Hobbs

    2007-05-31

    The Advanced Hydrogasification Process (AHP)--conversion of coal to methane--is being developed through NETL with a DOE Grant and has successfully completed its first phase of development. The results so far are encouraging and have led to commitment by DOE/NETL to begin a second phase--bench scale reactor vessel testing, expanded engineering analysis and economic perspective review. During the next decade new means of generating electricity, and other forms of energy, will be introduced. The members of the AHP Team envision a need for expanded sources of natural gas or substitutes for natural gas, to fuel power generating plants. The initial work the team has completed on a process to use hydrogen to convert coal to methane (pipeline ready gas) shows promising potential. The Team has intentionally slanted its efforts toward the needs of US electric utilities, particularly on fuels that can be used near urban centers where the greatest need for new electric generation is found. The process, as it has evolved, would produce methane from coal by adding hydrogen. The process appears to be efficient using western coals for conversion to a highly sought after fuel with significantly reduced CO{sub 2} emissions. Utilities have a natural interest in the preservation of their industry, which will require a dramatic reduction in stack emissions and an increase in sustainable technologies. Utilities tend to rank long-term stable supplies of fuel higher than most industries and are willing to trade some ratio of cost for stability. The need for sustainability, stability and environmentally compatible production are key drivers in the formation and progression of the AHP development. In Phase II, the team will add a focus on water conservation to determine how the basic gasification process can be best integrated with all the plant components to minimize water consumption during SNG production. The process allows for several CO{sub 2} reduction options including consumption of the CO{sub 2} in the original process as converted to methane. The process could under another option avoid emissions following the conversion to SNG through an adjunct algae conversion process. The algae would then be converted to fuels or other products. An additional application of the algae process at the end use natural gas fired plant could further reduce emissions. The APS team fully recognizes the competition facing the process from natural gas and imported liquid natural gas. While we expect those resources to set the price for methane in the near-term, the team's work to date indicates that the AHP process can be commercially competitive, with the added benefit of assuring long-term energy supplies from North American resources. Conversion of coal to a more readily transportable fuel that can be employed near load centers with an overall reduction of greenhouses gases is edging closer to reality.

  15. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01

    Costs for desulfurized coal, liquid fuels and gaseous fuelsSavings Using Liquid Solvent Refined Coal in New 500 Mwand natural gas liquids Notural gas Coal a. E c: c: :J

  16. Challenges, uncertainties and issues facing gas production from gas hydrate deposits

    E-Print Network [OSTI]

    Moridis, G.J.

    2011-01-01

    gas such as tight gas, shale gas, or coal bed methane gas tolocation. Development of shale oil and gas, tar sands, coalGas hydrates will undoubtedly also be present in shales,

  17. Coal: the cornerstone of America's energy future

    SciTech Connect (OSTI)

    Beck, R.A. [National Coal Council (United Kingdom)

    2006-06-15

    In April 2005, US Secretary of Energy Samuel W. Bodman asked the National Coal Council to develop a 'report identifying the challenges and opportunities of more fully exploring our domestic coal resources to meet the nation's future energy needs'. The Council has responded with eight specific recommendations for developing and implementing advanced coal processing and combustion technologies to satisfy our unquenchable thirst for energy. These are: Use coal-to-liquids technologies to produce 2.6 million barrels/day; Use coal-to-natural gas technologies to produce 4 trillion ft{sup 3}/yr; Build 100 GW of clean coal plants by 2025; Produce ethanol from coal; Develop coal-to-hydrogen technologies; Use CO{sub 2} to enhance recovery of oil and coal-bed methane; Increase the capacity of US coal mines and railroads; and Invest in technology development and implementation. 1 ref.; 4 figs.; 1 tab.

  18. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal

    SciTech Connect (OSTI)

    Monica Zanfir; Rahul Solunke; Minish Shah

    2012-06-01

    The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

  19. Formation and retention of methane in coal

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  20. Process for electrochemically gasifying coal

    DOE Patents [OSTI]

    Botts, T.E.; Powell, J.R.

    1985-10-25

    A process is claimed for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution. 7 figs.

  1. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems. Volume 2, Appendix A: Fixed bed gasifier and sulfur sorbent regeneration subsystem computer model development: Final report

    SciTech Connect (OSTI)

    Blough, E.; Russell, W.; Leach, J.W.

    1990-08-01

    Computer models have been developed for evaluating conceptual designs of integrated coal gasification combined cycle power plants. An overall system model was developed for performing thermodynamic cycle analyses, and detailed models were developed for predicting performance characteristics of fixed bed coal gasifiers and hot gas clean up subsystem components. The overall system model performs mass and energy balances and does chemical equilibrium analyses to determine the effects of changes in operating conditions, or to evaluate proposed design changes. An existing plug flow model for fixed bed gasifiers known as the Wen II model was revised and updated. Also, a spread sheet model of zinc ferrite sulfur sorbent regeneration subsystem was developed. Parametric analyses were performed to determine how performance depends on variables in the system design. The work was done to support CRS Sirrine Incorporated in their study of standardized air blown coal gasifier gas turbine concepts.

  2. Integrated coal cleaning, liquefaction, and gasification process

    DOE Patents [OSTI]

    Chervenak, Michael C. (Pennington, NJ)

    1980-01-01

    Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

  3. Photosynthetic pigment concentrations, gas exchange and vegetative growth for selected monocots and dicots treated with two contrasting coal fly ashes

    SciTech Connect (OSTI)

    Yunusa, I.A.M.; Burchett, M.D.; Manoharan, V.; DeSilva, D.L.; Eamus, D.; Skilbeck, C.G.

    2009-07-15

    There is uncertainty as to the rates of coal fly ash needed for optimum physiological processes and growth. In the current study we tested the hyothesis that photosynthetic pigments concentrations and CO{sub 2} assimilation (A) are more sensitive than dry weights in plants grown on media amended with coal fly ash. We applied the Terrestrial Plant Growth Test (Guideline 208) protocols of the Organization for Economic Cooperation and Development (OECD) to monocots (barley (Hordeum vulgare) and ryegrass (Secale cereale)) and dicots (canola (Brasica napus), radish (Raphanus sativus), field peas (Pisum sativum), and lucerne (Medicago sativa)) on media amended with fly ashes derived from semi-bituminous (gray ash) or lignite (red ash) coals at rates of 0, 2.5, 5.0, 10, or 20 Mg ha(-1). The red ash had higher elemental concentrations and salinity than the gray ash. Fly ash addition had no significant effect on germination by any of the six species. At moderate rates ({<=}10 Mg ha{sup -1}) both ashes increased (P < 0.05) growth rates and concentrations of chlorophylls a and b, but reduced carotenoid concentrations. Addition of either ash increased A in radish and transpiration in barley. Growth rates and final dry weights were reduced for all of the six test species when addition rates exceeded 10 Mg ha{sup -1} for gray ash and 5 Mg ha{sup -1} for red ash. We concluded that plant dry weights, rather than pigment concentrations and/or instantaneous rates of photosynthesis, are more consistent for assessing subsequent growth in plants supplied with fly ash.

  4. Iron catalyzed coal liquefaction process

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Givens, Edwin N. (Bethlehem, PA)

    1983-01-01

    A process is described for the solvent refining of coal into a gas product, a liquid product and a normally solid dissolved product. Particulate coal and a unique co-catalyst system are suspended in a coal solvent and processed in a coal liquefaction reactor, preferably an ebullated bed reactor. The co-catalyst system comprises a combination of a stoichiometric excess of iron oxide and pyrite which reduce predominantly to active iron sulfide catalysts in the reaction zone. This catalyst system results in increased catalytic activity with attendant improved coal conversion and enhanced oil product distribution as well as reduced sulfide effluent. Iron oxide is used in a stoichiometric excess of that required to react with sulfur indigenous to the feed coal and that produced during reduction of the pyrite catalyst to iron sulfide.

  5. Permeability changes in coal resulting from gas desorption. First quarterly report, August 16, 1989--November 15, 1989

    SciTech Connect (OSTI)

    Levine, J.R.; Tsay, F.

    1989-11-19

    Sampling Procedure: This project requires a carefully coordinated sample preparation procedure that will ensure that specimens of the proper size and physical characteristics are available for the various measurement methods used. Coherent blocks of coal will be collected in the field, with subsamples being removed in the lab by 1 inch-diameter core drill. At least 5 separate cores will be drilled from each block. Coal blocks sampled in the field will be approximately 10 inches (times) 10 inches {times} 6 inches. Distinctive compositional lithologies should be selected for sampling. For example, a section of the seam containing particularly thick vitrain or durain bands might be selected; or the block might include a mineral matter rich layer. If necessary, several blocks should be selected to represent a range in compositions. Sampling procedure must include a method for retaining moisture. The sample must not be allowed to dry out. Exposure to atmospheric oxygen should be limited as much as possible. The samples must carefully packed for shipment so as to preserve their integrity.

  6. Process for heating coal-oil slurries

    DOE Patents [OSTI]

    Braunlin, W.A.; Gorski, A.; Jaehnig, L.J.; Moskal, C.J.; Naylor, J.D.; Parimi, K.; Ward, J.V.

    1984-01-03

    Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec[sup [minus]1]. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72. 29 figs.

  7. Process for heating coal-oil slurries

    DOE Patents [OSTI]

    Braunlin, Walter A. (Spring, TX); Gorski, Alan (Lovington, NM); Jaehnig, Leo J. (New Orleans, LA); Moskal, Clifford J. (Oklahoma City, OK); Naylor, Joseph D. (Houston, TX); Parimi, Krishnia (Allison Park, PA); Ward, John V. (Arvada, CO)

    1984-01-03

    Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec.sup. -1. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72.

  8. Experimental research on emission and removal of dioxins in flue gas from a co-combustion of MSW and coal incinerator

    SciTech Connect (OSTI)

    Zhong Zhaoping [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)]. E-mail: zzhong@seu.edu.cn; Jin Baosheng [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Huang Yaji [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Zhou Hongcang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China); Lan Jixiang [Department of Power Engineering, Research Institute of Thermal Energy Engineering, Key Laboratory of Clean Coal Power Generation and Combustion Technology of Ministry of Education, Southeast University, Nanjing 210096 (China)

    2006-07-01

    This paper describes the experimental study of dioxins removal from flue gas from a co-combustion municipal solid waste and coal incinerator by means of a fluidized absorption tower and a fabric filter. A test rig has been set up. The flow rate of flue gas of the test rig is 150-2000 m{sup 3}/h. The system was composed of a humidification and cooling system, an absorption tower, a demister, a slurry make-up tank, a desilter, a fabric filter and a measurement system. The total height of the absorption tower was 6.5 m, and the diameter of the reactor pool was 1.2 m. When the absorbent was 1% limestone slurry, the recirculation ratio was 3, the jet rate was 5-15 m/s and the submerged depth of the bubbling pipe under the slurry was 0.14 m, the removal efficiency for dioxins was 99.35%. The concentration of dioxins in the treated flue gas was 0.1573 x 10{sup -13} kg/Nm{sup 3} and the concentration of oxygen was 11%. This concentration is comparable to the emission standards of other developed countries.

  9. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems

    SciTech Connect (OSTI)

    Sadowski, R.S.; Brown, M.J.; Hester, J.C.; Harriz, J.T.; Ritz, G.J.

    1991-02-01

    The objective of this study is to develop standardized air blown fixed bed gasification hot gas cleanup integrated gasifier combined cycle (IGCC) systems.

  10. Abstract-Coal and hydro will be the main sources of electric energy in Chile for the near future, given that natural gas

    E-Print Network [OSTI]

    Dixon, Juan

    Abstract- Coal and hydro will be the main sources of electric energy in Chile for the near future and the environmental dilemma faced by the country, where both coal and hydro produce some kind of impact. The role

  11. Modeling of Coal Drying before Pyrolysis Damintode Kolani1, a

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    in the coal without chemical decomposition and pyrolysis converts dry coal into gas and coke [1]. The final1 Modeling of Coal Drying before Pyrolysis Damintode Kolani1, a , Eric Blond1, b , Alain Gasser1 Forbach, France a damintode.kolani@univ-orleans.fr, b eric.blond@univ-orleans.fr Keywords: coal, drying

  12. Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases

    DOE Patents [OSTI]

    Ayala, Raul E. (Clifton Park, NY)

    1993-01-01

    This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

  13. Fired heater for coal liquefaction process

    DOE Patents [OSTI]

    Ying, David H. S. (Macungie, PA); McDermott, Wayne T. (Allentown, PA); Givens, Edwin N. (Bethlehem, PA)

    1985-01-01

    A fired heater for a coal liquefaction process is operated under conditions to maximize the slurry slug frequency and thereby improve the heat transfer efficiency. The operating conditions controlled are (1) the pipe diameter and pipe arrangement, (2) the minimum coal/solvent slurry velocity, (3) the maximum gas superficial velocity, and (4) the range of the volumetric flow velocity ratio of gas to coal/solvent slurry.

  14. Effects of HCl and SO{sub 2} concentration on mercury removal by activated carbon sorbents in coal-derived flue gas

    SciTech Connect (OSTI)

    Ryota Ochiai; M. Azhar Uddin; Eiji Sasaoka; Shengji Wu [Okayama University, Okayama (Japan). Faculty of Environmental Science and Technology

    2009-09-15

    The effect of the presence of HCl and SO{sub 2} in the simulated coal combustion flue gas on the Hg{sup 0} removal by a commercial activated carbon (coconut shell AC) was investigated in a laboratory-scale fixed-bed reactor in a temperature range of 80-200{sup o}C. The characteristics (thermal stability) of the mercury species formed on the sorbents under various adsorption conditions were investigated by the temperature-programmed decomposition desorption (TPDD) technique. It was found that the presence of HCl and SO{sub 2} in the flue gas affected the mercury removal efficiency of the sorbents as well as the characteristics of the mercury adsorption species. The mercury removal rate of AC increased with the HCl concentration in the flue gas. In the presence of HCl and the absence of SO{sub 2} during Hg{sup 0} adsorption by AC, a single Hg{sup 0} desorption peak at around 300{sup o}C was observed in the TPDD spectra and intensity of this peak increased with the HCl concentration during mercury adsorption. The peak at around 300{sup o}C may be derived from the decomposition and desorption of mercury chloride species. The presence of SO{sub 2} during mercury adsorption had an adverse effect on the mercury removal by AC in the presence of HCl. In the presence of both HCl and SO{sub 2} during Hg{sup 0} adsorption by AC, the major TPDD peak temperatures changed drastically depending upon the concentration of HCl and SO{sub 2} in flue gas during Hg{sup 0} adsorption. 16 refs., 7 figs.

  15. Assessment of environmental health and safety issues associated with the commercialization of unconventional gas recovery: methane from coal seams

    SciTech Connect (OSTI)

    Ethridge, L.J.; Cowan, C.E.; Riedel, E.F.

    1980-07-01

    Potential public health and safety problems and the potential environmental impacts from the recovery of gas from coalbeds are identified and examined. The technology of methane recovery is described and economic and legal barriers to production are discussed. (ACR)

  16. Transportation and Greenhouse Gas Mitigation

    E-Print Network [OSTI]

    Lutsey, Nicholas P.; Sperling, Dan

    2008-01-01

    natural gas and liquefied petroleum gas have continued to make small contributions to transportation,transportation actions include electric power sector actions, eg coal to natural gas

  17. Combined cycle power plant incorporating coal gasification

    DOE Patents [OSTI]

    Liljedahl, Gregory N. (Tariffville, CT); Moffat, Bruce K. (Simsbury, CT)

    1981-01-01

    A combined cycle power plant incorporating a coal gasifier as the energy source. The gases leaving the coal gasifier pass through a liquid couplant heat exchanger before being used to drive a gas turbine. The exhaust gases of the gas turbine are used to generate both high pressure and low pressure steam for driving a steam turbine, before being exhausted to the atmosphere.

  18. Pyrolysis of coal

    DOE Patents [OSTI]

    Babu, Suresh P. (Willow Springs, IL); Bair, Wilford G. (Morton Grove, IL)

    1992-01-01

    A method for mild gasification of crushed coal in a single vertical elongated reaction vessel providing a fluidized bed reaction zone, a freeboard reaction zone, and an entrained reaction zone within the single vessel. Feed coal and gas may be fed separately to each of these reaction zones to provide different reaction temperatures and conditions in each reaction zone. The reactor and process of this invention provides for the complete utilization of a coal supply for gasification including utilization of caking and non-caking or agglomerating feeds in the same reactor. The products may be adjusted to provide significantly greater product economic value, especially with respect to desired production of char having high surface area.

  19. Hydroliquefaction of coal

    DOE Patents [OSTI]

    Sze, Morgan C. (Upper Montclair, NJ); Schindler, Harvey D. (Fairlawn, NJ)

    1982-01-01

    Coal is catalytically hydroliquefied by passing coal dispersed in a liquefaction solvent and hydrogen upwardly through a plurality of parallel expanded catalyst beds, in a single reactor, in separate streams, each having a cross-sectional flow area of no greater than 255 inches square, with each of the streams through each of the catalyst beds having a length and a liquid and gas superficial velocity to maintain an expanded catalyst bed and provide a Peclet Number of at least 3. If recycle is employed, the ratio of recycle to total feed (coal and liquefaction solvent) is no greater than 2:1, based on volume. Such conditions provide for improved selectivity to liquid product to thereby reduce hydrogen consumption. The plurality of beds are formed by partitions in the reactor.

  20. Climate change: A crack in the natural-gas bridge

    E-Print Network [OSTI]

    Davis, SJ; Shearer, C

    2014-01-01

    fuels such as coal, gas and oil produces more than 80% ofsubstitution of gas for coal and oil can thus decarbonize

  1. A crack in the natural-gas bridge

    E-Print Network [OSTI]

    Davis, SJ; Shearer, C

    2014-01-01

    fuels such as coal, gas and oil produces more than 80% ofsubstitution of gas for coal and oil can thus decarbonize

  2. Chlorine in coal and boiler corrosion

    SciTech Connect (OSTI)

    Chou, M.I.M.; Lytle, J.M. [Illinois State Geological Survey, Champaign, IL (United States); Pan, W.P.; Liu, L. [Western Kentucky Univ., Bowling Green, KY (United States); Huggins, F.E.; Huffman, G.P. [Univ. of Kentucky, Lexington, KY (United States); Ho, K.K. [Illinois Clean Coal Inst., Carbondale, IL (United States)

    1994-12-31

    Corrosion of superheaters in the United Kingdom has been attributed to the high level of chlorine (Cl) in British coals. On the other hand, similar high-Cl Illinois coals have not caused boiler corrosion. This suggests that the extent of boiler corrosion due to Cl may not be directly related to the amount of Cl in the coal but to how the Cl occurs in the coal or to other factors. In this study, both destructive temperature-programmed Thermogravimetry with Fourier transform infrared (TGA-FTIR) and non-destructive X-ray absorption near-edge structure (XANES) techniques were used to examine the thermal evolution characteristics and the forms of Cl in four Illinois and four British coals. The TGA-FTIR results indicate that under oxidizing conditions, both British and Illinois coals release hydrogen chloride (HCl) gas. Maximum evolution of HCl gas from Illinois coals occurs near 425 C, whereas, the temperature of maximum HCl release from British coals occurs between 210 and 280 C. The XANES results indicate that Cl in coal exists in ionic forms including a solid salt form. The HCl evolution profiles of the Illinois and British coals suggests that the way in which Cl ions are associated in Illinois coals is of different from the way they are associated in British coals.

  3. Imminence of peak in US coal production and overestimation of reserves

    E-Print Network [OSTI]

    Khare, Sanjay V.

    be produced at the current rate of consumption. This assumption is based on the large reported coal reserves fuels, coal, oil, and natural gas, it is coal that is the most carbon intensive (W. Moomaw, 2011). Due

  4. Easing the natural gas crisis: Reducing natural gas prices through increased deployment of renewable energy and energy efficiency

    E-Print Network [OSTI]

    Wiser, Ryan; Bolinger, Mark; St. Clair, Matt

    2004-01-01

    gas-price forecasts of recent years suggest that coal mayprice forecasts (e.g. , UCS 2004a, 2004b), generally find less gas displacement (and greater coal

  5. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01

    OF COAL MODEL COMPOUNDS AND COAL LIQUIDS James Anthony AprilCOAL MODEL COMPOUNDS AND COAL LIQUIDS James Anthony Wrathalla promising agent in coal-liquid desulfurization, assuming

  6. Gasifier feed - Tailor-made from Illinois coals

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III (Illinois State Geological Survey, Champaign, IL (United States)); Lytle, J.; Frost, R.R.; Lizzio, A.; Kohlenberger, L.; Brewer, K. (Illinois State Geological Survey, Champaign, IL (United States) DESTEC Energy (United States) Williams Technology, (United States) Illinois Coal Association (United States))

    1992-01-01

    The main purpose of this project is to produce a feedstock from preparation plant fines from an illinois coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high sulfur content and high Btu value of Illinois coals are particularly advantageous in such a gasifier; preliminary calculations indicate that the increased cost of removing sulfur from the gas from a high sulfur coal is more than offset by the increased revenue from the sale of the elemental sulfur; additionally the high Btu Illinois coal concentrates more energy into the slurry of a given coal to water ratio. The Btu is higher not only because of the higher Btu value of the coal but also because Illinois coal requires less water to produce a pumpable slurry than western coal, i.e., as little as 30--35% water may be used for Illinois coal as compared to approximately 45% for most western coals.

  7. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas

    SciTech Connect (OSTI)

    Bhatt, B.L.

    1992-09-01

    As part of the DOE-sponsored contract for the Synthesis of Dimethyl Ether (DME) and Alternative Fuels in the Liquid Phase from Coal- Derived Syngas, the single-step, slurry phase DME synthesis process was developed. The development involved screening of catalyst systems, process variable studies, and catalyst life studies in two 300 ml stirred autoclaves. As a spin-off of the Liquid Phase Methanol (LPMEOH*) process, the new process significantly improves the syngas conversion efficiency of the LPMEOH process. This improvement can be achieved by replacing a portion of methanol catalyst with a dehydration catalyst in the reactor, resulting in the product methanol being converted to DME, thus avoiding the thermodynamic equilibrium constraint of the methanol reaction. Overall, this increases syngas conversion per-pass. The selectivity and productivity of DME and methanol are affected by the catalyst system employed as well as operating conditions. A preferred catalyst system, consisting of a physical mixture of a methanol catalyst and a gamma alumina, was identified. An improvement of about 50% in methanol equivalent productivity was achieved compared to the LPMEOH process. Results from the process variable study indicate that higher pressure and CO[sub 2] removal benefit the process significantly. Limited life studies performed on the preferred catalyst system suggest somewhat higher than expected deactivation rate for the methanol catalyst. Several DME/methanol mixtures were measured for their key properties as transportation fuels. With small amounts of DME added, significant improvements in both flash points and Reid Vapor Pressure (RVP) were observed over the corresponding values of methanol alone.

  8. Underground Coal Thermal Treatment

    SciTech Connect (OSTI)

    P. Smith; M. Deo; E. Eddings; A. Sarofim; K. Gueishen; M. Hradisky; K. Kelly; P. Mandalaparty; H. Zhang

    2011-10-30

    The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coalâ??s carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO{sub 2} sequestration. Efforts focused on: â?˘ Constructing a suite of three different coal pyrolysis reactors. These reactors offer the ability to gather heat transfer, mass transfer and kinetic data during coal pyrolysis under conditions that mimic in situ conditions (Subtask 6.1). â?˘ Studying the operational parameters for various underground thermal treatment processes for oil shale and coal and completing a design matrix analysis for the underground coal thermal treatment (UCTT). This analysis yielded recommendations for terms of targeted coal rank, well orientation, rubblization, presence of oxygen, temperature, pressure, and heating sources (Subtask 6.2). â?˘ Developing capabilities for simulating UCTT, including modifying the geometry as well as the solution algorithm to achieve long simulation times in a rubblized coal bed by resolving the convective channels occurring in the representative domain (Subtask 6.3). â?˘ Studying the reactive behavior of carbon dioxide (CO{sub 2}) with limestone, sandstone, arkose (a more complex sandstone) and peridotite, including mineralogical changes and brine chemistry for the different initial rock compositions (Subtask 6.4). Arkose exhibited the highest tendency of participating in mineral reactions, which can be attributed to the geochemical complexity of its initial mineral assemblage. In experiments with limestone, continuous dissolution was observed with the release of CO{sub 2} gas, indicated by the increasing pressure in the reactor (formation of a gas chamber). This occurred due to the lack of any source of alkali to buffer the solution. Arkose has the geochemical complexity for permanent sequestration of CO{sub 2} as carbonates and is also relatively abundant. The effect of including NH{sub 3} in the injected gas stream was also investigated in this study. Precipitation of calcite and trace amounts of ammonium zeolites was observed. A batch geochemical model was developed using Geochemists Workbench (GWB). Degassing effect in the experiments was corrected using the sliding fugacity model in GWB. Experimental and simulation results were compared and a reasonable agreement between the two was observed.

  9. Bioconversion of coal-derived synthesis gas to liquid fuels. Final report, September 29, 1992--December 27, 1994

    SciTech Connect (OSTI)

    Jain, M.K.; Worden, R.M.; Grethlein, H.E.

    1995-01-15

    The proposed research project consists of an integrated, two-stage fermentation and a highly energy-efficient product separation scheme. In the first fermentation, Butyribacterium methylotrophicum converts carbon monoxide (CO) into butyric acid and acetic acids which are then converted into butanol, ethanol, and a small amount of acetone in the second stage fermentation by Clostridium acetobutylicum. An advanced separation system process, based on pervaporation, removes the alcohols from the fermentation broth as they are formed, along with some of the hydrogen sulfide (H{sub 2}S), to minimize possible inhibition of the fermentations. This bioconversion process offers a critical advantage over conventional, catalytic processes for synthesis gas conversion: the microorganisms are several orders of magnitude more sulfur tolerant than metallic catalysts. The catalysts require sulfur removal to the parts per million level, while the microorganisms are unaffected by H{sub 2}S and carbonyl sulfide (COS) at one part per hundred--roughly the composition of sulfur in raw synthesis gas. During the two-year course of this project, the following major objectives have been accomplished: demonstrated long-term cell recycle of continuous fermentation of synthesis gas; demonstrated cell immobilization of Butyribacterium methylotrophicum; identified trickle-bed reactor as a viable alternative fermentation method; modulated metabolic pathways to increase C4 formation during synthesis gas fermentation; recovered carbon and electrons from H{sub 2} and CO{sub 2} with pathway modulation for increased C4 production; developed bacterial strains with improved selectivity for butyrate fermentation; demonstrated two-stage CO to alcohol fermentation; and concentrated alcohol from solventogenic fermentation by pervaporation.

  10. Optical Fiber Chemical Sensor with Sol-Gel Derived Refractive Material as Transducer for High Temperature Gas Sensing in Clean Coal Technology

    SciTech Connect (OSTI)

    Shiquan Tao

    2006-12-31

    The chemistry of sol-gel derived silica and refractive metal oxide has been systematically studied. Sol-gel processes have been developed for preparing porous silica and semiconductor metal oxide materials. Micelle/reversed micelle techniques have been developed for preparing nanometer sized semiconductor metal oxides and noble metal particles. Techniques for doping metal ions, metal oxides and nanosized metal particles into porous sol-gel material have also been developed. Optical properties of sol-gel derived materials in ambient and high temperature gases have been studied by using fiber optic spectroscopic techniques, such as fiber optic ultraviolet/visible absorption spectrometry, fiber optic near infrared absorption spectrometry and fiber optic fluorescence spectrometry. Fiber optic spectrometric techniques have been developed for investigating the optical properties of these sol-gel derived materials prepared as porous optical fibers or as coatings on the surface of silica optical fibers. Optical and electron microscopic techniques have been used to observe the microstructure, such as pore size, pore shape, sensing agent distribution, of sol-gel derived material, as well as the size and morphology of nanometer metal particle doped in sol-gel derived porous silica, the nature of coating of sol-gel derived materials on silica optical fiber surface. In addition, the chemical reactions of metal ion, nanostructured semiconductor metal oxides and nanometer sized metal particles with gas components at room temperature and high temperatures have also been investigated with fiber optic spectrometric methods. Three classes of fiber optic sensors have been developed based on the thorough investigation of sol-gel chemistry and sol-gel derived materials. The first group of fiber optic sensors uses porous silica optical fibers doped with metal ions or metal oxide as transducers for sensing trace NH{sub 3} and H{sub 2}S in high temperature gas samples. The second group of fiber optic sensors uses sol-gel derived porous silica materials doped with nanometer particles of noble metals in the form of fiber or coating for sensing trace H{sub 2}, NH{sub 3} and HCl in gas samples at for applications ambient temperature. The third classes of fiber optic sensors use sol-gel derived semiconductor metal oxide coating on the surface of silica optical fiber as transducers for selectively sensing H{sub 2}, CH{sub 4} and CO at high temperature. In addition, optical fiber temperature sensors use the fluorescence signal of rare-earth metal ions doped porous silica optical fiber or the optical absorption signal of thermochromic metal oxide materials coated on the surface of silica optical fibers have also been developed for monitoring gas temperature of corrosive gas. Based on the results obtained from this project, the principle of fiber optic sensor techniques for monitoring matrix gas components as well as trace components of coal gasification derived syngas has been established. Prototype sensors for sensing trace ammonia and hydrogen sulfide in gasification derived syngas have been built up in our laboratory and have been tested using gas samples with matrix gas composition similar to that of gasification derived fuel gas. Test results illustrated the feasibility of these sensors for applications in IGCC processes.

  11. Inclined fluidized bed system for drying fine coal

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO); Merriam, Norman W. (Laramie, WY); Boysen, John E. (Laramie, WY)

    1992-02-11

    Coal is processed in an inclined fluidized bed dryer operated in a plug-flow manner with zonal temperature and composition control, and an inert fluidizing gas, such as carbon dioxide or combustion gas. Recycled carbon dioxide, which is used for drying, pyrolysis, quenching, and cooling, is produced by partial decarboxylation of the coal. The coal is heated sufficiently to mobilize coal tar by further pyrolysis, which seals micropores upon quenching. Further cooling with carbon dioxide enhances stabilization.

  12. Assessment of fuel-cycle energy use and greenhouse gas emissions for Fischer-Tropsch diesel from coal and cellulosic biomass.

    SciTech Connect (OSTI)

    Xie, X.; Wang, M.; Han, J. (Energy Systems)

    2011-04-01

    This study expands and uses the GREET (Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation) model to assess the effects of carbon capture and storage (CCS) technology and cellulosic biomass and coal cofeeding in Fischer-Tropsch (FT) plants on energy use and greenhouse gas (GHG) emissions of FT diesel (FTD). To demonstrate the influence of the coproduct credit methods on FTD life-cycle analysis (LCA) results, two allocation methods based on the energy value and the market revenue of different products and a hybrid method are employed. With the energy-based allocation method, fossil energy use of FTD is less than that of petroleum diesel, and GHG emissions of FTD could be close to zero or even less than zero with CCS when forest residue accounts for 55% or more of the total dry mass input to FTD plants. Without CCS, GHG emissions are reduced to a level equivalent to that from petroleum diesel plants when forest residue accounts for 61% of the total dry mass input. Moreover, we show that coproduct method selection is crucial for LCA results of FTD when a large amount of coproducts is produced.

  13. X-ray Computed Tomography of coal: Final report

    SciTech Connect (OSTI)

    Maylotte, D.H.; Spiro, C.L.; Kosky, P.G.; Lamby, E.J.

    1986-12-01

    X-ray Computed Tomography (CT) is a method of mapping with x-rays the internal structures of coal. The technique normally produces 2-D images of the internal structures of an object. These images can be recast to create pseudo 3-D representations. CT of coal has been explored for a variety of different applications to coal and coal processing technology. In a comparison of CT data with conventional coal analyses and petrography, CT was found to offer a good indication of the total ash content of the coal. The spatial distribution of the coal mineral matter as seen with CT has been suggested as an indicator of coal washability. Studies of gas flow through coal using xenon gas as a tracer have shown the extremely complicated nature of the modes of penetration of gas through coal, with significant differences in the rates at which the gas can pass along and across the bedding planes of coal. In a special furnace designed to allow CT images to be taken while the coal was being heated, the pyrolysis and gasification of coal have been studied. Gasification rates with steam and CO/sub 2/ for a range of coal ranks have been obtained, and the location of the gasification reactions within the piece of coal can be seen. Coal drying and the progress of the pyrolysis wave into coal have been examined when the coal was subjected to the kind of sudden temperature jump that it might experience in fixed bed gasifier applications. CT has also been used to examine stable flow structures within model fluidized beds and the accessibility of lump coal to microbial desulfurization. 53 refs., 242 figs., 26 tabs.

  14. Conventional Energy (Oil, Gas, and Coal) Forum & Associated Vertical Business Development Best Practices in Indian Country

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p aDepartmentEnergy comparingDeep January 2012CONVENTIONAL ENERGY

  15. Infiltration from an impoundment for coal-bed natural gas, Powder River Basin, Wyoming: Evolution of water and sediment chemistry - article no. W06424

    SciTech Connect (OSTI)

    Healy, R.W.; Rice, C.A.; Bartos, T.T.; McKinley, M.P. [US Geological Survey, Lakewood, CO (United States). Denver Federal Center

    2008-06-15

    Development of coal-bed natural gas (CBNG) in the Powder River Basin, Wyoming, has increased substantially in recent years. Among environmental concerns associated with this development is the fate of groundwater removed with the gas. A preferred water-management option is storage in surface impoundments. A study was conducted on changes in water and sediment chemistry as water from an impoundment infiltrated the subsurface. Sediment cores were collected prior to operation of the impoundment and after its closure and reclamation. Suction lysimeters were used to collect water samples from beneath the impoundment. Large amounts of chloride (12,300 kg) and nitrate (13,500 kg as N), most of which accumulated naturally in the sediments over thousands of years, were released into groundwater by infiltrating water. Nitrate was more readily flushed from the sediments than chloride. If sediments at other impoundment locations contain similar amounts of chloride and nitrate, impoundments already permitted could release over 48 x 10{sup 6} kg of chloride and 52 x 10{sup 6} kg of nitrate into groundwater in the basin. A solute plume with total dissolved solid (TDS) concentrations at times exceeding 100,000 mg/L was created in the subsurface. TDS concentrations in the plume were substantially greater than those in the CBNG water (about 2300 mg/L) and in the ambient shallow groundwater (about 8000 mg/L). Sulfate, sodium, and magnesium are the dominant ions in the plume. The elevated concentrations are attributed to cation-exchange-enhanced gypsum dissolution. As gypsum dissolves, calcium goes into solution and is exchanged for sodium and magnesium on clays. Removal of calcium from solution allows further gypsum dissolution.

  16. Apparatus for fixed bed coal gasification

    DOE Patents [OSTI]

    Sadowski, Richard S. (Greenville, SC)

    1992-01-01

    An apparatus for fixed-bed coal gasification is described in which coal such as caking coal is continuously pyrolyzed with clump formation inhibited, by combining the coal with a combustible gas and an oxidant, and then continually feeding the pyrolyzed coal under pressure and elevated temperature into the gasification region of a pressure vessel. The materials in the pressure vessel are allowed to react with the gasifying agents in order to allow the carbon contents of the pyrolyzed coal to be completely oxidized. The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  17. Coal Distribution Database, 2006

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) Gas Wells (Million7 December 2008

  18. Coal Distribution Database, 2006

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) Gas Wells (Million7 December 2008

  19. Coal Distribution Database, 2006

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) Gas Wells (Million7 December

  20. Coal Distribution Database, 2008

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) Gas Wells (Million7 December3Q 2009

  1. Coal Distribution Database, 2008

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) Gas Wells (Million7 December3Q 20093Q

  2. Coal Distribution Database, 2008

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) Gas Wells (Million7 December3Q

  3. Coal Distribution Database, 2008

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4Cubic Feet) Gas Wells (Million7 December3Q4Q 2009

  4. EIA -Quarterly Coal Distribution

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1 Table272/SPipelineNatural Gas Energy MarketsCoal

  5. China's Coal: Demand, Constraints, and Externalities

    SciTech Connect (OSTI)

    Aden, Nathaniel; Fridley, David; Zheng, Nina

    2009-07-01

    This study analyzes China's coal industry by focusing on four related areas. First, data are reviewed to identify the major drivers of historical and future coal demand. Second, resource constraints and transport bottlenecks are analyzed to evaluate demand and growth scenarios. The third area assesses the physical requirements of substituting coal demand growth with other primary energy forms. Finally, the study examines the carbon- and environmental implications of China's past and future coal consumption. There are three sections that address these areas by identifying particular characteristics of China's coal industry, quantifying factors driving demand, and analyzing supply scenarios: (1) reviews the range of Chinese and international estimates of remaining coal reserves and resources as well as key characteristics of China's coal industry including historical production, resource requirements, and prices; (2) quantifies the largest drivers of coal usage to produce a bottom-up reference projection of 2025 coal demand; and (3) analyzes coal supply constraints, substitution options, and environmental externalities. Finally, the last section presents conclusions on the role of coal in China's ongoing energy and economic development. China has been, is, and will continue to be a coal-powered economy. In 2007 Chinese coal production contained more energy than total Middle Eastern oil production. The rapid growth of coal demand after 2001 created supply strains and bottlenecks that raise questions about sustainability. Urbanization, heavy industrial growth, and increasing per-capita income are the primary interrelated drivers of rising coal usage. In 2007, the power sector, iron and steel, and cement production accounted for 66% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units would save only 14% of projected 2025 coal demand for the power sector. A new wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. If coal to chemicals capacity reaches 70 million tonnes and coal-to-liquids capacity reaches 60 million tonnes, coal feedstock requirements would add an additional 450 million tonnes by 2025. Even with more efficient growth among these drivers, China's annual coal demand is expected to reach 3.9 to 4.3 billion tonnes by 2025. Central government support for nuclear and renewable energy has not reversed China's growing dependence on coal for primary energy. Substitution is a matter of scale: offsetting one year of recent coal demand growth of 200 million tonnes would require 107 billion cubic meters of natural gas (compared to 2007 growth of 13 BCM), 48 GW of nuclear (compared to 2007 growth of 2 GW), or 86 GW of hydropower capacity (compared to 2007 growth of 16 GW). Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on a high growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China has a low proportion of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport capacity. Furthermore, transporting coal to users has overloaded the train system and dramatically increased truck use, raising transportation oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 million tonnes by 2025, significantly impacting regional markets.

  6. Clean coal technology. Coal utilisation by-products

    SciTech Connect (OSTI)

    NONE

    2006-08-15

    The need to remove the bulk of ash contained in flue gas from coal-fired power plants coupled with increasingly strict environmental regulations in the USA result in increased generation of solid materials referred to as coal utilisation by-products, or CUBs. More than 40% of CUBs were sold or reused in the USA in 2004 compared to less than 25% in 1996. A goal of 50% utilization has been established for 2010. The American Coal Ash Association (ACCA) together with the US Department of Energy's Power Plant Improvement Initiative (PPPI) and Clean Coal Power Initiative (CCPI) sponsor a number of projects that promote CUB utilization. Several are mentioned in this report. Report sections are: Executive summary; Introduction; Where do CUBs come from?; Market analysis; DOE-sponsored CUB demonstrations; Examples of best-practice utilization of CUB materials; Factors limiting the use of CUBs; and Conclusions. 14 refs., 1 fig., 5 tabs., 14 photos.

  7. Formation and retention of methane in coal. Final report

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  8. Outlook and Challenges for Chinese Coal

    SciTech Connect (OSTI)

    Aden, Nathaniel T.; Fridley, David G.; Zheng, Nina

    2008-06-20

    China has been, is, and will continue to be a coal-powered economy. The rapid growth of coal demand since 2001 has created deepening strains and bottlenecks that raise questions about supply security. Although China's coal is 'plentiful,' published academic and policy analyses indicate that peak production will likely occur between 2016 and 2029. Given the current economic growth trajectory, domestic production constraints will lead to a coal gap that is not likely to be filled with imports. Urbanization, heavy industry growth, and increasing per-capita consumption are the primary drivers of rising coal usage. In 2006, the power sector, iron and steel, and cement accounted for 71% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units could save only 14% of projected 2025 coal demand. If China follows Japan, steel production would peak by 2015; cement is likely to follow a similar trajectory. A fourth wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. New demand from coal-to-liquids and coal-to-chemicals may add 450 million tonnes of coal demand by 2025. Efficient growth among these drivers indicates that China's annual coal demand will reach 4.2 to 4.7 billion tonnes by 2025. Central government support for nuclear and renewable energy has not been able to reduce China's growing dependence on coal for primary energy. Few substitution options exist: offsetting one year of recent coal demand growth would require over 107 billion cubic meters of natural gas, 48 GW of nuclear, or 86 GW of hydropower capacity. While these alternatives will continue to grow, the scale of development using existing technologies will be insufficient to substitute significant coal demand before 2025. The central role of heavy industry in GDP growth and the difficulty of substituting other fuels suggest that coal consumption is inextricably entwined with China's economy in its current mode of growth. Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on its current growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Broadening awareness of the environmental costs of coal mining, transport, and combustion is raising the pressure on Chinese policy makers to find alternative energy sources. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China is short of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport. Transporting coal to users has overloaded the train system and dramatically increased truck use, raising transport oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 mt by 2025, significantly impacting regional markets. The looming coal gap threatens to derail China's growth path, possibly undermining political, economic, and social stability. High coal prices and domestic shortages will have regional and global effects. Regarding China's role as a global manufacturing center, a domestic coal gap will increase prices and constrain growth. Within the Asia-Pacific region, China's coal gap is likely to bring about increased competition with other coal-importing countries including Japan, South Korea, Taiwan, and India. As with petroleum, China may respond with a government-supported 'going-out' strategy of resource acquisition and vertical integration. Given its population and growing resource constraints, China may favor energy security, competitiveness, and local environmental protection over global climate change mitigation. The possibility of a large coal gap suggests that Chinese and international policy makers should maximize institutional and financial support

  9. Clean Coal Diesel Demonstration Project

    SciTech Connect (OSTI)

    Robert Wilson

    2006-10-31

    A Clean Coal Diesel project was undertaken to demonstrate a new Clean Coal Technology that offers technical, economic and environmental advantages over conventional power generating methods. This innovative technology (developed to the prototype stage in an earlier DOE project completed in 1992) enables utilization of pre-processed clean coal fuel in large-bore, medium-speed, diesel engines. The diesel engines are conventional modern engines in many respects, except they are specially fitted with hardened parts to be compatible with the traces of abrasive ash in the coal-slurry fuel. Industrial and Municipal power generating applications in the 10 to 100 megawatt size range are the target applications. There are hundreds of such reciprocating engine power-plants operating throughout the world today on natural gas and/or heavy fuel oil.

  10. Electricity from coal and utilization of coal combustion by-products

    SciTech Connect (OSTI)

    Demirbas, A.

    2008-07-01

    Most electricity in the world is conventionally generated using coal, oil, natural gas, nuclear energy, or hydropower. Due to environmental concerns, there is a growing interest in alternative energy sources for heat and electricity production. The major by-products obtained from coal combustion are fly ash, bottom ash, boiler slag, and flue gas desulfurization (FGD) materials. The solid wastes produced in coal-fired power plants create problems for both power-generating industries and environmentalists. The coal fly ash and bottom ash samples may be used as cementitious materials.

  11. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01

    Pollutants Associated With Coal Combustion. • E.P.A.Control Guidelines for Coal-Derived Pollutants .Forms of Sulfur in Coal • . . . . Coal Desulfurization

  12. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    that own the scores of coal power plants whose coal ismillion tons in 2006. Coal power plants currently accountan electric generating coal power plant that would be built

  13. Review of China's Low-Carbon City Initiative and Developments in the Coal Industry

    E-Print Network [OSTI]

    Fridley, David

    2014-01-01

    technology roadmap and feasibility study was then conducted by Bechtel Corporation with a proposed coal-methanol-town gas

  14. Coal Bed Methane Primer

    SciTech Connect (OSTI)

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

  15. 1 | P a g e 2012 International Pittsburgh Coal Conference

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    1 | P a g e 2012 International Pittsburgh Coal Conference Pittsburgh, PA, USA October 15 - 18, 2012-mineable Coal Seam Qin He, Shahab D. Mohaghegh, Vida Gholami Department of Petroleum and Natural Gas Engineering, West Virginia University, Morgantown, WV26505, U.S.A. Abstract Studies have shown that, coal seam

  16. Process for converting coal into liquid fuel and metallurgical coke

    DOE Patents [OSTI]

    Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

    1994-01-01

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  17. Toward zero emissions from coal in China Robert H. Williams

    E-Print Network [OSTI]

    is oxygen-blown (O2­blown) gasification to generate synthesis gas from coal. This technology is used is a strong candidate for becoming the "third" clean energy carrier for China. Evolving a coal-based energyToward zero emissions from coal in China Robert H. Williams Princeton Environmental Institute, Room

  18. Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalystes to Poisons form High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures

    SciTech Connect (OSTI)

    Burton Davis; Gary Jacobs; Wenping Ma; Khalid Azzam; Janet ChakkamadathilMohandas; Wilson Shafer

    2009-09-30

    There has been a recent shift in interest in converting not only natural gas and coal derived syngas to Fischer-Tropsch synthesis products, but also converting biomass-derived syngas, as well as syngas derived from coal and biomass mixtures. As such, conventional catalysts based on iron and cobalt may not be suitable without proper development. This is because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using entrained-flow oxygen-blown gasifier gasification gasification) than solely from coal, other compounds may actually be increased. Of particular concern are compounds containing alkali chemicals like the chlorides of sodium and potassium. In the first year, University of Kentucky Center for Applied Energy Research (UK-CAER) researchers completed a number of tasks aimed at evaluating the sensitivity of cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts and a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to alkali halides. This included the preparation of large batches of 0.5%Pt-25%Co/Al{sub 2}O{sub 3} and 100Fe: 5.1Si: 3.0K: 2.0Cu (high alpha) catalysts that were split up among the four different entities participating in the overall project; the testing of the catalysts under clean FT and WGS conditions; the testing of the Fe-Cr WGS catalyst under conditions of co-feeding NaCl and KCl; and the construction and start-up of the continuously stirred tank reactors (CSTRs) for poisoning investigations.

  19. Process for electrochemically gasifying coal using electromagnetism

    DOE Patents [OSTI]

    Botts, Thomas E. (Markham, VA); Powell, James R. (Shoreham, NY)

    1987-01-01

    A process for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution.

  20. Method of operating a two-stage coal gasifier

    DOE Patents [OSTI]

    Tanca, Michael C. (Tariffville, CT)

    1982-01-01

    A method of operating an entrained flow coal gasifier (10) via a two-stage gasification process. A portion of the coal (18) to be gasified is combusted in a combustion zone (30) with near stoichiometric air to generate combustion products. The combustion products are conveyed from the combustion zone into a reduction zone (32) wherein additional coal is injected into the combustion products to react with the combustion products to form a combustible gas. The additional coal is injected into the reduction zone as a mixture (60) consisting of coal and steam, preferably with a coal-to-steam weight ratio of approximately ten to one.

  1. The Role of Oxygen in Coal Gasification 

    E-Print Network [OSTI]

    Klosek, J.; Smith, A. R.; Solomon, J.

    1986-01-01

    of capital and energy. This paper examines the major factors in oxygen purity selection for typical coal gasifiers. Examples demonstrating the effect of oxygen purity on several processes are presented: production of synthetic natural gas (SNG), integrated...

  2. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    US emission data are from the IEA World Energy Outlook,world conventional fossil fuel reserves were coal by energy content; 19% were oil, and 19% natural gas. Data

  3. Industrial Utilization of Coal-Oil Mixtures 

    E-Print Network [OSTI]

    Dunn, J. E.; Hawkins, G. T.

    1982-01-01

    Coal-oil mixtures (COM) are receiving increasing interest as economical alternatives to residual fuel oil and natural gas used in heavy industrial and utility applications. Four basic approaches are currently employed in the manufacture of COM...

  4. High-pressure gasification of Montana subbituminous coal

    SciTech Connect (OSTI)

    Goyal, A.; Bryan, B.; Rehmat, A.

    1991-01-01

    A data base for the fluidized-bed gasification of different coals at elevated pressures has been developed at the Institute of Gas Technology (IGT) with different ranks of coal at pressures up to 450 psig and at temperatures dictated by the individual coals. Adequate data have been obtained to characterize the effect of pressure on the gasification of Montana Rosebud subbituminous coal and North Dakota lignite. The results obtained with Montana Rosebud subbituminous coal are presented here. This program was funded by the Gas Research Institute. 9 refs., 10 figs., 3 tabs.

  5. Coal industry annual 1997

    SciTech Connect (OSTI)

    1998-12-01

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  6. Coal Industry Annual 1995

    SciTech Connect (OSTI)

    1996-10-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  7. Coal industry annual 1996

    SciTech Connect (OSTI)

    1997-11-01

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  8. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, G.W.; Lewis, S.N.

    1988-01-21

    The present invention relates to a cell-free preparation and process for the microbial solubilization of coal into solubilized coal products. More specifically, the present invention relates to bacterial solubilization of coal into solubilized coal products and a cell-free bacterial byproduct useful for solubilizing coal. 5 tabs.

  9. Coal conversion. 1979 technical report

    SciTech Connect (OSTI)

    None

    1980-09-01

    Individual reports are made on research programs which are being conducted by various organizations and institutions for the commercial development of processes for converting coal into products that substitute for these derived from oil and natural gas. Gasification, liquefaction, and demonstration processes and plants are covered. (DLC)

  10. Oxy-coal Combustion Studies

    SciTech Connect (OSTI)

    J. Wendt; E. Eddings; J. Lighty; T. Ring; P. Smith; J. Thornock; Y. Jia, W. Morris; J. Pedel; D. Rezeai; L. Wang; J. Zhang; K. Kelly

    2012-01-01

    The objective of this project is to move toward the development of a predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. This validation research brings together multi-scale experimental measurements and computer simulations. The combination of simulation development and validation experiments is designed to lead to predictive tools for the performance of existing air fired pulverized coal boilers that have been retrofitted to various oxy-firing configurations. In addition, this report also describes novel research results related to oxy-combustion in circulating fluidized beds. For pulverized coal combustion configurations, particular attention is focused on the effect of oxy-firing on ignition and coal-flame stability, and on the subsequent partitioning mechanisms of the ash aerosol. To these ends, the project has focused on the following: â?˘ The development of reliable Large Eddy Simulations (LES) of oxy-coal flames using the Direct Quadrature Method of Moments (DQMOM) (Subtask 3.1). The simulations were validated for both non-reacting particle-laden jets and oxy-coal flames. â?˘ The modifications of an existing oxy-coal combustor to allow operation with high levels of input oxygen to enable in-situ laser diagnostic measurements as well as the development of strategies for directed oxygen injection (Subtask 3.2). Flame stability was quantified for various burner configurations. One configuration that was explored was to inject all the oxygen as a pure gas within an annular oxygen lance, with burner aerodynamics controlling the subsequent mixing. â?˘ The development of Particle Image Velocimetry (PIV) for identification of velocity fields in turbulent oxy-coal flames in order to provide high-fidelity data for the validation of oxy-coal simulation models (Subtask 3.3). Initial efforts utilized a laboratory diffusion flame, first using gas-fuel and later a pulverized-coal flame to ensure the methodology was properly implemented and that all necessary data and image-processing techniques were fully developed. Success at this stage of development led to application of the diagnostics in a large-scale oxy-fuel combustor (OFC). â?˘ The impact of oxy-coal-fired vs. air-fired environments on SO{sub x} (SO{sub 2}, SO{sub 3}) emissions during coal combustion in a pilot-scale circulating fluidized-bed (CFB) (Subtask 3.4). Profiles of species concentration and temperature were obtained for both conditions, and profiles of temperature over a wide range of O{sub 2} concentration were studied for oxy-firing conditions. The effect of limestone addition on SO{sub 2} and SO{sub 3} emissions were also examined for both air- and oxy- firing conditions. â?˘ The investigation of O{sub 2}/CO{sub 2} and O{sub 2}/N{sub 2} environments on SO{sub 2 emissions during coal combustion in a bench-scale single-particle fluidized-bed reactor (Subtask 3.5). Moreover, the sulfation mechanisms of limestone in O{sub 2}/CO{sub 2} and O{sub 2}/N{sub 2} environments were studied, and a generalized gassolid and diffusion-reaction single-particle model was developed to study the effect of major operating variables. â?˘ The investigation of the effect of oxy-coal combustion on ash formation, particle size distributions (PSD), and size-segregated elemental composition in a drop-tube furnace and the 100 kW OFC (Subtask 3.6). In particular, the effect of coal type and flue gas recycle (FGR, OFC only) was investigated.

  11. Rail Coal Transportation Rates

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan FebCubicFracking,MichiganThousand47,959.15 KeroseneCoal Glossary

  12. Rail Coal Transportation Rates

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan FebCubicFracking,MichiganThousand47,959.15 KeroseneCoal

  13. Annual Coal Distribution Tables

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal Consumers4.32Elements)Grossc. Real73 Table

  14. Annual Coal Distribution Tables

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal Consumers4.32Elements)Grossc. Real73

  15. Annual Coal Distribution Tables

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal Consumers4.32Elements)Grossc. Real73and Foreign

  16. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear JanProfileDecadeJulyAnnual

  17. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear JanProfileDecadeJulyAnnual0

  18. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear JanProfileDecadeJulyAnnual00

  19. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear JanProfileDecadeJulyAnnual000

  20. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear JanProfileDecadeJulyAnnual0000

  1. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear

  2. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy Information

  3. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy Information1 U.S.

  4. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy Information1

  5. By Coal Destination State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy Information12

  6. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy

  7. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S. Energy

  8. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S. Energy0

  9. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S. Energy00

  10. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S. Energy000

  11. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S. Energy0001

  12. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S. Energy00011

  13. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S.

  14. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S.1 U.S.

  15. By Coal Origin State

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal4 Arizona - NaturalYear1 U.S. Energy0 U.S.1 U.S.2 U.S.

  16. Rail Coal Transportation Rates

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)Decade Year-0 Year-1 Year-2Feet)Thousand Cubic Feet)698 1.873 -Coal

  17. Coal combustion products (CCPs

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p aDepartment of Energyof the CleanClient education istheCoalFocuses

  18. Rail Coal Transportation Rates

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry NaturalPrices1Markets160Product:7a. Space Heatingreports Coal

  19. Fluidized bed injection assembly for coal gasification

    DOE Patents [OSTI]

    Cherish, Peter (Bethel Park, PA); Salvador, Louis A. (Hempfield Township, Westmoreland County, PA)

    1981-01-01

    A coaxial feed system for fluidized bed coal gasification processes including an inner tube for injecting particulate combustibles into a transport gas, an inner annulus about the inner tube for injecting an oxidizing gas, and an outer annulus about the inner annulus for transporting a fluidizing and cooling gas. The combustibles and oxidizing gas are discharged vertically upward directly into the combustion jet, and the fluidizing and cooling gas is discharged in a downward radial direction into the bed below the combustion jet.

  20. Coal liquefaction and hydrogenation

    DOE Patents [OSTI]

    Schindler, Harvey D. (Fair Lawn, NJ); Chen, James M. (Edison, NJ)

    1985-01-01

    Disclosed is a coal liquefaction process using two stages. The first stage liquefies the coal and maximizes the product while the second stage hydrocracks the remainder of the coal liquid to produce solvent.

  1. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01

    flow sheet of a K-T coal gasification complex for producingslag or bottom ash, coal gasification, or coal liquefactionCoal (Ref. 46). COAL PREPARATION GASIFICATION 3 K·T GASI FI

  2. Coal liquefaction

    DOE Patents [OSTI]

    Schindler, Harvey D. (Fairlawn, NJ)

    1985-01-01

    In a two-stage liquefaction wherein coal, hydrogen and liquefaction solvent are contacted in a first thermal liquefaction zone, followed by recovery of an essentially ash free liquid and a pumpable stream of insoluble material, which includes 850.degree. F.+ liquid, with the essentially ash free liquid then being further upgraded in a second liquefaction zone, the liquefaction solvent for the first stage includes the pumpable stream of insoluble material from the first liquefaction stage, and 850.degree. F.+ liquid from the second liquefaction stage.

  3. NETL: Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeatMaRIEdioxide capture CS Seminars Calendar HomeNETLCareersCoal

  4. Field Test Program for Long-Term Operation of a COHPAC System for Removing Mercury from Coal-Fired Flue Gas

    SciTech Connect (OSTI)

    C. Jean Bustard; Charles Lindsey; Paul Brignac

    2006-05-01

    This document provides a summary of the full-scale demonstration efforts involved in the project ''Field Test Program for Long-Term Operation of a COHPAC{reg_sign} System for Removing Mercury from Coal-Fired Flue Gas''. The project took place at Alabama Power's Plant Gaston Unit 3 and involved the injection of sorbent between an existing particulate collector (hot-side electrostatic precipitators) and a COHPAC{reg_sign} fabric filter (baghouse) downstream. Although the COHPAC{reg_sign} baghouse was designed originally for polishing the flue gas, when activated carbon injection was added, the test was actually evaluating the EPRI TOXECON{reg_sign} configuration. The results from the baseline tests with no carbon injection showed that the cleaning frequency in the COHPAC{reg_sign} unit was much higher than expected, and was above the target maximum cleaning frequency of 1.5 pulses/bag/hour (p/b/h), which was used during the Phase I test in 2001. There were times when the baghouse was cleaning continuously at 4.4 p/b/h. In the 2001 tests, there was virtually no mercury removal at baseline conditions. In this second round of tests, mercury removal varied between 0 and 90%, and was dependent on inlet mass loading. There was a much higher amount of ash exiting the electrostatic precipitators (ESP), creating an inlet loading greater than the design conditions for the COHPAC{reg_sign} baghouse. Tests were performed to try to determine the cause of the high ash loading. The LOI of the ash in the 2001 baseline tests was 11%, while the second baseline tests showed an LOI of 17.4%. The LOI is an indication of the carbon content in the ash, which can affect the native mercury uptake, and can also adversely affect the performance of ESPs, allowing more ash particles to escape the unit. To overcome this, an injection scheme was implemented that balanced the need to decrease carbon injection during times when inlet loading to the baghouse was high and increase carbon injection when inlet loading and mercury removal were low. The resulting mercury removal varied between 50 and 98%, with an overall average of 85.6%, showing that the process was successful at removing high percentages of vapor-phase mercury even with a widely varying mass loading. In an effort to improve baghouse performance, high-permeability bags were tested. The new bags made a significant difference in the cleaning frequency of the baghouse. Before changing the bags, the baghouse was often in a continuous clean of 4.4 p/b/h, but with the new bags the cleaning frequency was very low, at less than 1 p/b/h. Alternative sorbent tests were also performed using these high-permeability bags. The results of these tests showed that most standard, high-quality activated carbon performed similarly at this site; low-cost sorbent and ash-based sorbents were not very effective at removing mercury; and chemically enhanced sorbents did not appear to offer any benefits over standard activated carbons at this site.

  5. Wabash River Coal Gasification Repowering Project

    SciTech Connect (OSTI)

    Amick, P.; Mann, G.J.; Cook, J.J.; Fisackerly, R.; Spears, R.C.

    1992-01-01

    The Destec gasification process features an oxygen-blown, two stage entrained flow gasifier. PSI will procure coal for the Project consistent with the design specification ranges of Destec's coal gasification facility. Destec's plant will be designed to accept coal with a maximum sulfur content of 5.9% (dry basis) and a minimum energy content of 13,5000 BTU/pound (moisture and ash free basis). PSI and Destec will test at least two other coals for significant periods during the demonstration period. In the Destec process, coal is ground with water to form a slurry. It is then pumped into a gasification vessel where oxygen is added to form a hot raw gas through partial combustion. Most of the noncarbon material in the coal melts and flows out the bottom of the vessel forming slag -- a black, glassy, non-leaching, sand-like material. Particulates, sulfur and other impurities are removed from the gas before combustion to make it acceptable fuel for the gas turbine. The synthetic fuel gas (syngas) is piped to a General Electric MS 7001F high temperature combustion turbine generator. A heat recovery steam generator recovers gas turbine exhaust heat to produce high pressure steam. This steam and the steam generated in the gasification process supply an existing steam turbine-generator. The plant will be designed to outperform air emission standards established by the Clean Air Act Amendments for the year 2000.

  6. Wabash River Coal Gasification Repowering Project

    SciTech Connect (OSTI)

    Amick, P.; Mann, G.J.; Cook, J.J.; Fisackerly, R.; Spears, R.C.

    1992-11-01

    The Destec gasification process features an oxygen-blown, two stage entrained flow gasifier. PSI will procure coal for the Project consistent with the design specification ranges of Destec`s coal gasification facility. Destec`s plant will be designed to accept coal with a maximum sulfur content of 5.9% (dry basis) and a minimum energy content of 13,5000 BTU/pound (moisture and ash free basis). PSI and Destec will test at least two other coals for significant periods during the demonstration period. In the Destec process, coal is ground with water to form a slurry. It is then pumped into a gasification vessel where oxygen is added to form a hot raw gas through partial combustion. Most of the noncarbon material in the coal melts and flows out the bottom of the vessel forming slag -- a black, glassy, non-leaching, sand-like material. Particulates, sulfur and other impurities are removed from the gas before combustion to make it acceptable fuel for the gas turbine. The synthetic fuel gas (syngas) is piped to a General Electric MS 7001F high temperature combustion turbine generator. A heat recovery steam generator recovers gas turbine exhaust heat to produce high pressure steam. This steam and the steam generated in the gasification process supply an existing steam turbine-generator. The plant will be designed to outperform air emission standards established by the Clean Air Act Amendments for the year 2000.

  7. EIS-0105: Conversion to Coal, Baltimore Gas & Electric Company, Brandon Shores Generating Station Units 1 and 2, Anne Arundel County, Maryland

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy’s Economic Regulatory Administration Office of Fuels Program, Coal and Electricity Division prepared this statement to assess the potential environmental and socioeconomic impacts associated with prohibiting the use of petroleum products as a primary energy source for Units 1 and 2 of the Brandon Shores Generating Station, located in Anne Arundel County, Maryland.

  8. Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures

    SciTech Connect (OSTI)

    Burton Davis; Gary Jacobs; Wenping Ma; Dennis Sparks; Khalid Azzam; Janet Chakkamadathil Mohandas; Wilson Shafer; Venkat Ramana Rao Pendyala

    2011-09-30

    There has been a recent shift in interest in converting not only natural gas and coal derived syngas to Fischer-Tropsch synthesis products, but also converting biomass-derived syngas, as well as syngas derived from coal and biomass mixtures. As such, conventional catalysts based on iron and cobalt may not be suitable without proper development. This is because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using entrained-flow oxygen-blown gasifier gasification gasification) than solely from coal, other compounds may actually be increased. Of particular concern are compounds containing alkali chemicals like the chlorides of sodium and potassium. In the first year, University of Kentucky Center for Applied Energy Research (UK-CAER) researchers completed a number of tasks aimed at evaluating the sensitivity of cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts and a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to alkali halides. This included the preparation of large batches of 0.5%Pt-25%Co/Al{sub 2}O{sub 3} and 100Fe: 5.1Si: 3.0K: 2.0Cu (high alpha) catalysts that were split up among the four different entities participating in the overall project; the testing of the catalysts under clean FT and WGS conditions; the testing of the Fe-Cr WGS catalyst under conditions of co-feeding NaCl and KCl; and the construction and start-up of the continuously stirred tank reactors (CSTRs) for poisoning investigations. In the second and third years, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H{sub 2}S and NH{sub 3}. Cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts were also subjected to a number of the same compounds in order to evaluate their sensitivities at different concentration levels of added contaminant.

  9. Energy and Greenhouse Gas Emissions in China: Growth, Transition, and Institutional Change

    E-Print Network [OSTI]

    Kahrl, Fredrich James

    2011-01-01

    coal mining, petroleum extraction and refining, coking, andCoal Mining and Dressing Petroleum and Natural Gas Extraction Petroleum Processing, Coking andCoal Mining and Dressing Petroleum and Natural Gas Extraction Petroleum Processing, Coking and

  10. 47 Natural Gas Market Trends NATURAL GAS MARKET TRENDS

    E-Print Network [OSTI]

    of the chapter addresses the forecast of coal prices to specific coal-fired power plants in the northwest;Natural Gas Market Trends 48 percent was produced within the state. Another 17 percent came from Canada

  11. Division of Oil, Gas, and Mining Permitting

    E-Print Network [OSTI]

    Utah, University of

    " or "Gas" does not include any gaseous or liquid substance processed from coal, oil shale, or tar sands

  12. REMEDIAT1NG AT MANUFACTURED GAS

    E-Print Network [OSTI]

    Peters, Catherine A.

    , comhusti- hle gas manufactured Pfrom coke, coal, and oil 1 served as the major gas- eous fuel for urban for the three primary gas production meth- ods: coal carbonization, carbureted water gas production, and oil gas carbonization, from the resi- due of gasifying oils in oil gas pro- cesses, and from the cracking of en- riching

  13. Coal combustion by wet oxidation

    SciTech Connect (OSTI)

    Bettinger, J.A.; Lamparter, R.A.; McDowell, D.C.

    1980-11-15

    The combustion of coal by wet oxidation was studied by the Center for Waste Management Programs, of Michigan Technological University. In wet oxidation a combustible material, such as coal, is reacted with oxygen in the presence of liquid water. The reaction is typically carried out in the range of 204/sup 0/C (400/sup 0/F) to 353/sup 0/C (650/sup 0/F) with sufficient pressure to maintain the water present in the liquid state, and provide the partial pressure of oxygen in the gas phase necessary to carry out the reaction. Experimental studies to explore the key reaction parameters of temperature, time, oxidant, catalyst, coal type, and mesh size were conducted by running batch tests in a one-gallon stirred autoclave. The factors exhibiting the greatest effect on the extent of reaction were temperature and residence time. The effect of temperature was studied from 204/sup 0/C (400/sup 0/F) to 260/sup 0/C (500/sup 0/F) with a residence time from 600 to 3600 seconds. From this data, the reaction activation energy of 2.7 x 10/sup 4/ calories per mole was determined for a high-volatile-A-Bituminous type coal. The reaction rate constant may be determined at any temperature from the activation energy using the Arrhenius equation. Additional data were generated on the effect of mesh size and different coal types. A sample of peat was also tested. Two catalysts were evaluated, and their effects on reaction rate presented in the report. In addition to the high temperature combustion, low temperature desulfurization is discussed. Desulfurization can improve low grade coal to be used in conventional combustion methods. It was found that 90% of the sulfur can be removed from the coal by wet oxidation with the carbon untouched. Further desulfurization studies are indicated.

  14. Coal liquefaction process utilizing coal/CO.sub.2 slurry feedstream

    DOE Patents [OSTI]

    Comolli, Alfred G. (Yardley, PA); McLean, Joseph B. (S. Somerville, NJ)

    1989-01-01

    A coal hydrogenation and liquefaction process in which particulate coal feed is pressurized to an intermediate pressure of at least 500 psig and slurried with CO.sub.2 liquid to provide a flowable coal/CO.sub.2 slurry feedstream, which is further pressurized to at least 1000 psig and fed into a catalytic reactor. The coal particle size is 50-375 mesh (U.S. Sieve Series) and provides 50-80 W % coal in the coal/CO.sub.2 slurry feedstream. Catalytic reaction conditions are maintained at 650.degree.-850.degree. F. temperature, 1000-4000 psig hydrogen partial pressure and coal feed rate of 10-100 lb coal/hr ft.sup.3 reactor volume to produce hydrocarbon gas and liquid products. The hydrogen and CO.sub.2 are recovered from the reactor effluent gaseous fraction, hydrogen is recycled to the catalytic reactor, and CO.sub.2 is liquefied and recycled to the coal slurrying step. If desired, two catalytic reaction stages close coupled together in series relation can be used. The process advantageously minimizes the recycle and processing of excess hydrocarbon liquid previously needed for slurrying the coal feed to the reactor(s).

  15. Coal gasification 2006: roadmap to commercialization

    SciTech Connect (OSTI)

    NONE

    2006-05-15

    Surging oil and gas prices, combined with supply security and environmental concerns, are prompting power generators and industrial firms to further develop coal gasification technologies. Coal gasification, the process of breaking down coal into its constituent chemical components prior to combustion, will permit the US to more effectively utilize its enormous, low cost coal reserves. The process facilitates lower environmental impact power generation and is becoming an increasingly attractive alternative to traditional generation techniques. The study is designed to inform the reader as to this rapidly evolving technology, its market penetration prospects and likely development. Contents include: Clear explanations of different coal gasification technologies; Emissions and efficiency comparisons with other fuels and technologies; Examples of US and global gasification projects - successes and failures; Commercial development and forecast data; Gasification projects by syngas output; Recommendations for greater market penetration and commercialization; Current and projected gasification technology market shares; and Recent developments including proposals for underground gasification process. 1 app.

  16. Underground Coal Thermal Treatment Task 6 Topical Report, Utah Clean Coal Program

    SciTech Connect (OSTI)

    Smith, P.J.; Deo, M.; Edding, E.G.; Hradisky, M.; Kelly, K.E.; Krumm, R.; Sarofim, Adel; Wang, D.

    2014-08-15

    The long-term objective of this task is to develop a transformational energy production technology by in- situ thermal treatment of a coal seam for the production of substitute natural gas and/or liquid transportation fuels while leaving much of the coal’s carbon in the ground. This process converts coal to a high-efficiency, low-greenhouse gas (GHG) emitting fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This task focused on three areas: • Experimental. The Underground Coal Thermal Treatment (UCTT) team focused on experiments at two scales, bench-top and slightly larger, to develop data to understand the feasibility of a UCTT process as well as to develop validation/uncertainty quantification (V/UQ) data for the simulation team. • Simulation. The investigators completed development of High Performance Computing (HPC) simulations of UCTT. This built on our simulation developments over the course of the task and included the application of Computational Fluid Dynamics (CFD)- based tools to perform HPC simulations of a realistically sized domain representative of an actual coal field located in Utah. • CO2 storage. In order to help determine the amount of CO2 that can be sequestered in a coal formation that has undergone UCTT, adsorption isotherms were performed on coals treated to 325, 450, and 600°C with slow heating rates. Raw material was sourced from the Sufco (Utah), Carlinville (Illinois), and North Antelope (Wyoming) mines. The study indicated that adsorptive capacity for the coals increased with treatment temperature and that coals treated to 325°C showed less or similar capacity to the untreated coals.

  17. Coal Combustion Products | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal Combustion Products Coal Combustion Products Coal combustion products (CCPs) are solid materials produced when coal is burned to generate electricity. Since coal provides the...

  18. Method for reducing NOx during combustion of coal in a burner

    DOE Patents [OSTI]

    Zhou, Bing (Cranbury, NJ); Parasher, Sukesh (Lawrenceville, NJ); Hare, Jeffrey J. (Provo, UT); Harding, N. Stanley (North Salt Lake, UT); Black, Stephanie E. (Sandy, UT); Johnson, Kenneth R. (Highland, UT)

    2008-04-15

    An organically complexed nanocatalyst composition is applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This process leads to reduced NOx production during coal combustion. The nanocatalyst compositions include a nanoparticle catalyst that is made using a dispersing agent that can bond with the catalyst atoms. The dispersing agent forms stable, dispersed, nano-sized catalyst particles. The catalyst composition can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a coal material. The catalyst composition can be applied before or after pulverizing the coal material or it may be injected directly into the coal burner together with pulverized coal.

  19. Gasifier feed - Tailor-made from Illinois coals. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III [Illinois State Geological Survey, Champaign, IL (United States); Lytle, J.; Frost, R.R.; Lizzio, A.; Kohlenberger, L.; Brewer, K. [Illinois State Geological Survey, Champaign, IL (United States)]|[DESTEC Energy (United States)]|[Williams Technology, (United States)]|[Illinois Coal Association (United States)

    1992-08-01

    The main purpose of this project is to produce a feedstock from preparation plant fines from an illinois coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high sulfur content and high Btu value of Illinois coals are particularly advantageous in such a gasifier; preliminary calculations indicate that the increased cost of removing sulfur from the gas from a high sulfur coal is more than offset by the increased revenue from the sale of the elemental sulfur; additionally the high Btu Illinois coal concentrates more energy into the slurry of a given coal to water ratio. The Btu is higher not only because of the higher Btu value of the coal but also because Illinois coal requires less water to produce a pumpable slurry than western coal, i.e., as little as 30--35% water may be used for Illinois coal as compared to approximately 45% for most western coals.

  20. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    is produced via coal gasification, then, depending on thenot be amenable to coal gasification and, thus, Eastern coalto represent a coal-to- hydrogen gasification process that

  1. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    transportation component of coal price should also increase;investment. Coal costs and prices are functions of a numberTable 15: Coal Supply, Disposition, and Prices”, http://

  2. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    increase in rail coal transportation costs in the future? (Ythus, the cost of coal transportation via unit trains ischance of the cost of coal transportation increasing are

  3. The particulate and vapor phase components of airborne polyaromatic hydrocarbons (PAHs) in coal gasification pilot plants 

    E-Print Network [OSTI]

    Brink, Eric Jon

    1980-01-01

    gas, ammonia, and other chemicals from coal. For example, coal is being gasified today in Turkey, India, South Africa, Scotland, Morocco, Yugoslavia, and Korea, Coal conversion was a large scale operation in Germany in World War II and supplied 85... on the process, such as: process options, type of coal feedstock, gasifier operational mode, and purification processes. However, there are similarities that permit a discussion of the fundamental process steps. A block diagram of a generalized coal...

  4. Hydrogen from Coal Edward Schmetz

    E-Print Network [OSTI]

    Hydrogen from Coal Edward Schmetz Office of Sequestration, Hydrogen and Clean Coal Fuels U-based technology. (a) Based on equal quantities of coal used to produce hydrogen and electricity 4 #12;Why Hydrogen From Coal? Huge U.S. coal reserves Hydrogen can be produced cleanly from coal Coal can provide

  5. Coal data: A reference

    SciTech Connect (OSTI)

    Not Available

    1995-02-01

    This report, Coal Data: A Reference, summarizes basic information on the mining and use of coal, an important source of energy in the US. This report is written for a general audience. The goal is to cover basic material and strike a reasonable compromise between overly generalized statements and detailed analyses. The section ``Supplemental Figures and Tables`` contains statistics, graphs, maps, and other illustrations that show trends, patterns, geographic locations, and similar coal-related information. The section ``Coal Terminology and Related Information`` provides additional information about terms mentioned in the text and introduces some new terms. The last edition of Coal Data: A Reference was published in 1991. The present edition contains updated data as well as expanded reviews and additional information. Added to the text are discussions of coal quality, coal prices, unions, and strikes. The appendix has been expanded to provide statistics on a variety of additional topics, such as: trends in coal production and royalties from Federal and Indian coal leases, hours worked and earnings for coal mine employment, railroad coal shipments and revenues, waterborne coal traffic, coal export loading terminals, utility coal combustion byproducts, and trace elements in coal. The information in this report has been gleaned mainly from the sources in the bibliography. The reader interested in going beyond the scope of this report should consult these sources. The statistics are largely from reports published by the Energy Information Administration.

  6. CO2 SEQUESTRATION POTENTIAL OF TEXAS LOW-RANK COALS

    SciTech Connect (OSTI)

    Duane A. McVay; Walter B. Ayers, Jr.; Jerry L. Jensen

    2004-07-01

    The objectives of this project are to evaluate the feasibility of carbon dioxide (CO{sub 2}) sequestration in Texas low-rank coals and to determine the potential for enhanced coalbed methane (CBM) recovery as an added benefit of sequestration. The main tasks for this reporting period were to correlate well logs and refine coal property maps, evaluate methane content and gas composition of Wilcox Group coals, and initiate discussions concerning collection of additional, essential data with Anadarko. To assess the volume of CO{sub 2} that may be sequestered and volume of methane that can be produced in the vicinity of the proposed Sam Seymour sequestration site, we used approximately 200 additional wells logs from Anadarko Petroleum Corp. to correlate and map coal properties of the 3 coal-bearing intervals of Wilcox group. Among the maps we are making are maps of the number of coal beds, number of coal beds greater than 5 ft thick, and cumulative coal thickness for each coal interval. This stratigraphic analysis validates the presence of abundant coal for CO{sub 2} sequestration in the Wilcox Group in the vicinity of Sam Seymour power plant. A typical wellbore in this region may penetrate 20 to 40 coal beds with cumulative coal thickness between 80 and 110 ft. Gas desorption analyses of approximately 75 coal samples from the 3 Wilcox coal intervals indicate that average methane content of Wilcox coals in this area ranges between 216 and 276 scf/t, basinward of the freshwater boundary indicated on a regional hydrologic map. Vitrinite reflectance data indicate that Wilcox coals are thermally immature for gas generation in this area. Minor amounts of biogenic gas may be present, basinward of the freshwater line, but we infer that most of the Wilcox coalbed gas in the deep coal beds is migrated thermogenic gas. Analysis based on limited data suggest that sites for CO{sub 2} sequestration and enhanced coalbed gas recovery should be located basinward of the Wilcox freshwater contour, where methane content is high and the freshwater aquifer can be avoided.

  7. Apparatus and method for solar coal gasification

    DOE Patents [OSTI]

    Gregg, David W. (Moraga, CA)

    1980-01-01

    Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials. Incident solar radiation is focused from an array of heliostats onto a tower-mounted secondary mirror which redirects the focused solar radiation down through a window onto the surface of a vertically-moving bed of coal, or a fluidized bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called "synthesis gas", which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam at the rear surface of the secondary mirror.

  8. Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures

    SciTech Connect (OSTI)

    Burtron Davis; Gary Jacobs; Wenping Ma; Khalid Azzam; Dennis Sparks; Wilson Shafer

    2010-09-30

    The successful adaptation of conventional cobalt and iron-based Fischer-Tropsch synthesis catalysts for use in converting biomass-derived syngas hinges in part on understanding their susceptibility to byproducts produced during the biomass gasification process. With the possibility that oil production will peak in the near future, and due to concerns in maintaining energy security, the conversion of biomass-derived syngas and syngas derived from coal/biomass blends to Fischer-Tropsch synthesis products to liquid fuels may provide a sustainable path forward, especially considering if carbon sequestration can be successfully demonstrated. However, one current drawback is that it is unknown whether conventional catalysts based on iron and cobalt will be suitable without proper development because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using an entrained-flow oxygen-blown gasifier) than solely from coal, other byproducts may be present in higher concentrations. The current project examines the impact of a number of potential byproducts of concern from the gasification of biomass process, including compounds containing alkali chemicals like the chlorides of sodium and potassium. In the second year, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H{sub 2}S and NH{sub 3}. Cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts were also subjected to a number of the same compounds in order to evaluate their sensitivities.

  9. COAL DESULFURIZATION PRIOR TO COMBUSTION

    E-Print Network [OSTI]

    Wrathall, J.

    2013-01-01

    90e COAL DESULFURIZATION PRIOR TO COMBUSTION J. Wrathall, T.of coal during combustion. The process involves the additionCOAL DESULFURIZATION PRIOR TO COMBUSTION Lawrence Berkeley

  10. WABASH RIVER COAL GASIFICATION REPOWERING PROJECT

    SciTech Connect (OSTI)

    Unknown

    2000-09-01

    The close of 1999 marked the completion of the Demonstration Period of the Wabash River Coal Gasification Repowering Project. This Final Report summarizes the engineering and construction phases and details the learning experiences from the first four years of commercial operation that made up the Demonstration Period under Department of Energy (DOE) Cooperative Agreement DE-FC21-92MC29310. This 262 MWe project is a joint venture of Global Energy Inc. (Global acquired Destec Energy's gasification assets from Dynegy in 1999) and PSI Energy, a part of Cinergy Corp. The Joint Venture was formed to participate in the Department of Energy's Clean Coal Technology (CCT) program and to demonstrate coal gasification repowering of an existing generating unit impacted by the Clean Air Act Amendments. The participants jointly developed, separately designed, constructed, own, and are now operating an integrated coal gasification combined-cycle power plant, using Global Energy's E-Gas{trademark} technology (E-Gas{trademark} is the name given to the former Destec technology developed by Dow, Destec, and Dynegy). The E-Gas{trademark} process is integrated with a new General Electric 7FA combustion turbine generator and a heat recovery steam generator in the repowering of a 1950's-vintage Westinghouse steam turbine generator using some pre-existing coal handling facilities, interconnections, and other auxiliaries. The gasification facility utilizes local high sulfur coals (up to 5.9% sulfur) and produces synthetic gas (syngas), sulfur and slag by-products. The Project has the distinction of being the largest single train coal gasification combined-cycle plant in the Western Hemisphere and is the cleanest coal-fired plant of any type in the world. The Project was the first of the CCT integrated gasification combined-cycle (IGCC) projects to achieve commercial operation.

  11. Fuel supply system and method for coal-fired prime mover

    DOE Patents [OSTI]

    Smith, William C. (Morgantown, WV); Paulson, Leland E. (Morgantown, WV)

    1995-01-01

    A coal-fired gas turbine engine is provided with an on-site coal preparation and engine feeding arrangement. With this arrangement, relatively large dry particles of coal from an on-site coal supply are micro-pulverized and the resulting dry, micron-sized, coal particulates are conveyed by steam or air into the combustion chamber of the engine. Thermal energy introduced into the coal particulates during the micro-pulverizing step is substantially recovered since the so-heated coal particulates are fed directly from the micro-pulverizer into the combustion chamber.

  12. Coal Markets

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry Natural Gas ReservesAlabamaAboutTotalWhy I Chose EIA EIACoal Markets

  13. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01

    Coal Cleaning Costs Process Clean Coal Produced, * T/D (DryMM$ Net Operating Cost, $/T (Clean Coal Basis) Net OperatingCost, $/T (Clean Coal Bases) Case NA Hazen KVB Battelle

  14. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    Railroads”, Conference on the Future of Coal, U.S. SenateFuture Impacts of Coal Distribution Constraints on Coal Costone at that! -ii- Future Impacts of Coal Distribution

  15. Upgraded Coal Interest Group

    SciTech Connect (OSTI)

    Evan Hughes

    2009-01-08

    The Upgraded Coal Interest Group (UCIG) is an EPRI 'users group' that focuses on clean, low-cost options for coal-based power generation. The UCIG covers topics that involve (1) pre-combustion processes, (2) co-firing systems and fuels, and (3) reburn using coal-derived or biomass-derived fuels. The UCIG mission is to preserve and expand the economic use of coal for energy. By reducing the fuel costs and environmental impacts of coal-fired power generation, existing units become more cost effective and thus new units utilizing advanced combustion technologies are more likely to be coal-fired.

  16. Investigation of coal tar mobility at a former MGP site

    SciTech Connect (OSTI)

    Moo-Young, H.K.; Mo, X.H.; Waterman, R.; Coleman, A.; Saroff, S.

    2009-11-15

    The presence of coal tar in the subsurface of former manufactured gas plant sites poses an environmental hazard and a potential threat to public health. Coal tar can release various chemical compounds that are transported into the groundwater. Before any efforts can be made to remove coal tar from contaminated subsurface soils, it is recommended to characterize coal tar properties and composition and to delineate the residual saturation point between mobile and immobile coal tar. This paper presents a new innovative field device, the Res-SAT field tool, and laboratory procedures that can be used to determine the saturation-capillary pressure relationship for a soil-water coal-tar system and the critical pressure for coal tar mobility.

  17. Coal properties and system operating parameters for underground coal gasification

    SciTech Connect (OSTI)

    Yang, L. [China University of Mining & Technology, Xuzhou (China)

    2008-07-01

    Through the model experiment for underground coal gasification, the influence of the properties for gasification agent and gasification methods on underground coal gasifier performance were studied. The results showed that pulsating gasification, to some extent, could improve gas quality, whereas steam gasification led to the production of high heating value gas. Oxygen-enriched air and backflow gasification failed to improve the quality of the outlet gas remarkably, but they could heighten the temperature of the gasifier quickly. According to the experiment data, the longitudinal average gasification rate along the direction of the channel in the gasifying seams was 1.212 m/d, with transverse average gasification rate 0.069 m/d. Experiment indicated that, for the oxygen-enriched steam gasification, when the steam/oxygen ratio was 2:1, gas compositions remained stable, with H{sub 2} + CO content virtually standing between 60% and 70% and O{sub 2} content below 0.5%. The general regularities of the development of the temperature field within the underground gasifier and the reasons for the changes of gas quality were also analyzed. The 'autopneumatolysis' and methanization reaction existing in the underground gasification process were first proposed.

  18. Low-rank coal research. Quarterly report, January--March 1990

    SciTech Connect (OSTI)

    Not Available

    1990-08-01

    This document contains several quarterly progress reports for low-rank coal research that was performed from January-March 1990. Reports in Control Technology and Coal Preparation Research are in Flue Gas Cleanup, Waste Management, and Regional Energy Policy Program for the Northern Great Plains. Reports in Advanced Research and Technology Development are presented in Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Reports in Combustion Research cover Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Coal Fuels, Diesel Utilization of Low-Rank Coals, and Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications. Liquefaction Research is reported in Low-Rank Coal Direct Liquefaction. Gasification Research progress is discussed for Production of Hydrogen and By-Products from Coal and for Chemistry of Sulfur Removal in Mild Gas.

  19. Development of standardized air-blown coal gasifier/gas turbine concepts for future electric power systems. Volume 1, Final report

    SciTech Connect (OSTI)

    Sadowski, R.S.; Brown, M.J.; Hester, J.C.; Harriz, J.T.; Ritz, G.J.

    1991-02-01

    The objective of this study is to develop standardized air blown fixed bed gasification hot gas cleanup integrated gasifier combined cycle (IGCC) systems.

  20. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-01-26

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  1. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, Larry W. (Oswego, IL)

    1988-01-01

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover.

  2. Combustor for fine particulate coal

    DOE Patents [OSTI]

    Carlson, L.W.

    1988-11-08

    A particulate coal combustor with two combustion chambers is provided. The first combustion chamber is toroidal; air and fuel are injected, mixed, circulated and partially combusted. The air to fuel ratio is controlled to avoid production of soot or nitrogen oxides. The mixture is then moved to a second combustion chamber by injection of additional air where combustion is completed and ash removed. Temperature in the second chamber is controlled by cooling and gas mixing. The clean stream of hot gas is then delivered to a prime mover. 4 figs.

  3. Process for fixed bed coal gasification

    DOE Patents [OSTI]

    Sadowski, Richard S. (Greenville, SC)

    1992-01-01

    The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  4. Method of operating a coal predrying and heating plant in connection with a coking plant

    SciTech Connect (OSTI)

    Bocsanczy, J.; Knappstein, J.; Stalherm, D.

    1981-01-27

    A method of preparing and delivering coal to a coking plant comprises conveying the coal to the plant on a moving conveyor while an inert combustion gas is directed over the coal being conveyed. The combustion gas is generated by burning a fuel with air to produce a substantially inert combustion gas which is passed over the coal during its conveying and, thereafter, passed through a cooler for removing the moisture which has been picked up from the coal by the gas. The heating and predrying inert gases are advantageously generated by the direct combustion of air and fuel which are passed through flash dryer tubes and one or more separate separator systems and then delivered into a conveyor pipeline through which the coal is conveyed. A portion of the gases which are generated are also directed with a return gas to a filter for removal of any coal therefrom and to a cooler for removing the moisture picked up from the coal and then back into the stream for delivery to the conveyor for the coal. The inert gas may also be a gas which is circulated in heat exchange relationship with combustion gases which are generated by a combustion of the coal itself. In such a system, a portion of the combustion gases generated are also passed through a condenser or cooler and the cooled and dried waste gases are circulated over the coal being conveyed to the coking oven or its bunkers.

  5. Indonesian coal mining

    SciTech Connect (OSTI)

    NONE

    2008-11-15

    The article examines the opportunities and challenges facing the Indonesian coal mining industry and how the coal producers, government and wider Indonesian society are working to overcome them. 2 figs., 1 tab.

  6. Coal Production 1992

    SciTech Connect (OSTI)

    Not Available

    1993-10-29

    Coal Production 1992 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, productive capacity, and recoverable reserves to a wide audience including Congress, Federal and State agencies, the coal industry, and the general public. In 1992, there were 3,439 active coal mining operations made up of all mines, preparation plants, and refuse operations. The data in Table 1 cover the 2,746 mines that produced coal, regardless of the amount of production, except for bituminous refuse mines. Tables 2 through 33 include data from the 2,852 mining operations that produced, processed, or prepared 10 thousand or more short tons of coal during the period, except for bituminous refuse, and includes preparation plants with 5 thousand or more employee hours. These mining operations accounted for over 99 percent of total US coal production and represented 83 percent of all US coal mining operations in 1992.

  7. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, Gerald W. (Farragut, TN); Lewis, Susan N. (Knoxville, TN)

    1990-01-01

    This invention deals with the solubilization of coal using species of Streptomyces. Also disclosed is an extracellular component from a species of Streptomyces, said component being able to solubilize coal.

  8. Coal gasification. Quarterly report, April-June 1979

    SciTech Connect (OSTI)

    None

    1980-04-01

    In DOE's program for the conversion of coal to gaseous fuels both high-and low-Btu gasification processes are being developed. High-Btu gas can be distributed economically to consumers in the same pipeline systems now used to carry natural gas. Low-Btu gas, the cheapest of the gaseous fuels produced from coal, can be used economically only on site, either for electric power generation or by industrial and petrochemical plants. High-Btu natural gas has a heating value of 950 to 1000 Btu per standard cubic foot, is composed essentially of methane, and contains virtually no sulfur, carbon monoxide, or free hydrogen. The conversion of coal to High-Btu gas requires a chemical and physical transformation of solid coal. Coals have widely differing chemical and physical properties, depending on where they are mined, and are difficult to process. Therefore, to develop the most suitable techniques for gasifying coal, DOE, together with the American Gas Association (AGA), is sponsoring the development of several advanced conversion processes. Although the basic coal-gasification chemical reactions are the same for each process, each of the processes under development have unique characteristics. A number of the processes for converting coal to high-Btu gas have reached the pilot plant Low-Btu gas, with a heating value of up to 350 Btu per standard cubic foot, is an economical fuel for industrial use as well as for power generation in combined gas-steam turbine power cycles. Because different low-Btu gasification processes are optimum for converting different types of coal, and because of the need to provide commercially acceptable processes at the earliest possible date, DOE is sponsoring the concurrent development of several basic types of gasifiers (fixed-bed, fluidized-bed, and entrained-flow).

  9. International perspectives on coal preparation

    SciTech Connect (OSTI)

    1997-12-31

    The report consists of the vugraphs from the presentations which covered the following topics: Summaries of the US Department of Energy`s coal preparation research programs; Preparation trends in Russia; South African coal preparation developments; Trends in hard coal preparation in Germany; Application of coal preparation technology to oil sands extraction; Developments in coal preparation in China; and Coal preparation in Australia.

  10. Utilization ROLE OF COAL COMBUSTION

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    , materials left after combustion of coal in conventional and/ or advanced clean-coal technology combustors and advanced clean-coal technology combustors. This paper describes various coal combustion products produced (FGD) products from pulverized coal and advanced clean-coal technology combustors. Over 70% of the CCPs

  11. Identifying Options for Deep Reductions in Greenhouse Gas Emissions from California Transportation: Meeting an 80% Reduction Goal in 2050

    E-Print Network [OSTI]

    Yang, Christopher; McCollum, David L; McCarthy, Ryan; Leighty, Wayne

    2008-01-01

    Diesel (Coal-to- Liquids) Hydrogen (Natural Gas, pipeline)Hydrogen (Natural Gas, liquid H2 truck) Hydrogen (Coal,Natural Gas, on-site Natural Gas, liquid H2 truck, w/o or w/

  12. Coal gasification apparatus

    DOE Patents [OSTI]

    Nagy, Charles K. (Monaca, PA)

    1982-01-01

    Coal hydrogenation vessel has hydrogen heating passages extending vertically through its wall and opening into its interior.

  13. Energy and Greenhouse Gas Emissions in China: Growth, Transition, and Institutional Change

    E-Print Network [OSTI]

    Kahrl, Fredrich James

    2011-01-01

    Coal Natural Gas Petroleum Products Unit Energy Use Emissionis that some energy inputs, in particular “other petroleum4 The energy industry itself (coal mining, petroleum

  14. Coal production 1989

    SciTech Connect (OSTI)

    Not Available

    1990-11-29

    Coal Production 1989 provides comprehensive information about US coal production, the number of mines, prices, productivity, employment, reserves, and stocks to a wide audience including Congress, federal and state agencies, the coal industry, and the general public. 7 figs., 43 tabs.

  15. COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM

    E-Print Network [OSTI]

    Gandhi, Shamim Ahmed

    2013-01-01

    Additional products line gas, LPG, F, phenolsv and ammonia.Purified gas coal 4'JI,. LPG L_J" _ _, Sulfm Fractionatorcooled and separated into LPG and pipeline gas. The residue

  16. Coal: An energy bridge to the future

    SciTech Connect (OSTI)

    Bauer, Susan J.

    2006-09-29

    For years, coal drove the transportation business in this country and it may be poised for a comeback when it comes to moving people and things. A hundred years ago, steam engines burned tons of coal as they pulled trains across the country. Now researchers are looking at converting that coal to liquid fuel that would fill up our gas tanks and move our cars and trucks. The technology already exists to transform coal into a liquid fuel. In fact, Pacific Northwest National Laboratory scientists and engineers have researched forms of coal and hydrocarbon gasification on and off for more than 30 years. But oil has never sustained a high enough price to kick start a coal-to-liquid fuel industry. That may be changing now. In addition to high crude oil prices, experts agree worldwide petroleum resources won’t last forever, and hydrocarbon resources like coal may be the only resource available, at a large enough scale, to off-set oil consumption, in the near term.

  17. Fluidized bed selective pyrolysis of coal

    DOE Patents [OSTI]

    Shang, J.Y.; Cha, C.Y.; Merriam, N.W.

    1992-12-15

    The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyses the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step. 9 figs.

  18. Fluidized bed selective pyrolysis of coal

    DOE Patents [OSTI]

    Shang, Jer Y. (McLean, VA); Cha, Chang Y. (Golden, CO); Merriam, Norman W. (Laramie, WY)

    1992-01-01

    The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyzes the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step.

  19. Method for desulfurization of coal

    DOE Patents [OSTI]

    Kelland, D.R.

    1987-07-07

    A process and apparatus are disclosed for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS[sub 2] to a troilite FeS form or a pyrrhotite form Fe[sub 1[minus]x]S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H[sub 2]S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents. 2 figs.

  20. Method for desulfurization of coal

    DOE Patents [OSTI]

    Kelland, David R. (Lexington, MA)

    1987-01-01

    A process and apparatus for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS.sub.2 to a troilite FeS form or a pyrrhotite form Fe.sub.1-x S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H.sub.2 S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents.

  1. Apparatus for solar coal gasification

    DOE Patents [OSTI]

    Gregg, D.W.

    1980-08-04

    Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials is described. Incident solar radiation is focused from an array of heliostats through a window onto the surface of a moving bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called synthesis gas, which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam in one embodiment at the rear surface of a secondary mirror used to redirect the focused sunlight. Another novel feature of the invention is the location and arrangement of the array of mirrors on an inclined surface (e.g., a hillside) to provide for direct optical communication of said mirrors and the carbonaceous feed without a secondary redirecting mirror.

  2. Chemical coal cleaning process and costs refinement for coal-water slurry manufacture

    SciTech Connect (OSTI)

    Bhasin, A.K.; Berggren, M.H.; Ronzio, N.J.; Smit, F.J.

    1985-12-31

    This report describes the results of process and cost refinement studies for the manufacture of ultra-clean coal-slurry fuel for direct-fired gas turbines. The work was performed as an extension to an earlier contract in which AMAX R and D supplied METC with two lots of highly beneficiated coal slurry fuel for use in the Heat Engines program. A conceptual design study and cost estimate supplied to METC at that time indicated that a combined physical and chemical cleaning process could produce ultra-clean fuel at a competitive price. Laboratory and pilot plant studies performed for the contract extension further defined the process conditions and operating and capital costs to prepare coals containing from 0.2 to 1.0% ash as slurry fuels. A base-case fuel containing coal cleaned to 0.5% ash in a 1000 cp slurry containing 55% coal was $4.16 per million Btu when produced in quantities required to fuel a 500 MW gas-turbine generating station. Coal slurry fuel production costs as low as $3.66 per million Btu were projected for coals cleaned to 1.0% ash. 12 refs., 23 figs., 63 tabs.

  3. Coal recovery process

    DOE Patents [OSTI]

    Good, Robert J. (Grand Island, NY); Badgujar, Mohan (Williamsville, NY)

    1992-01-01

    A method for the beneficiation of coal by selective agglomeration and the beneficiated coal product thereof is disclosed wherein coal, comprising impurities, is comminuted to a particle size sufficient to allow impurities contained therein to disperse in water, an aqueous slurry is formed with the comminuted coal particles, treated with a compound, such as a polysaccharide and/or disaccharide, to increase the relative hydrophilicity of hydrophilic components, and thereafter the slurry is treated with sufficient liquid agglomerant to form a coagulum comprising reduced impurity coal.

  4. Sixth annual coal preparation, utilization, and environmental control contractors conference

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    A conference was held on coal preparation, utilization and environmental control. Topics included: combustion of fuel slurries; combustor performance; desulfurization chemically and by biodegradation; coal cleaning; pollution control of sulfur oxides and nitrogen oxides; particulate control; and flue gas desulfurization. Individual projects are processed separately for the databases. (CBS).

  5. Transforming coal for sustainability: a strategy for China

    E-Print Network [OSTI]

    energy, and ``modernized'' coal. By aggressively pursu- ing the advanced technology strategy now refers to the use of gasification technology to produce synthetic gas for power, clean fuelsTransforming coal for sustainability: a strategy for China Report by the Task Force on Energy

  6. NOVEL SLURRY PHASE DIESEL CATALYSTS FOR COAL-DERIVED SYNGAS

    SciTech Connect (OSTI)

    Dr. Dragomir B. Bukur; Dr. Ketil Hanssen; Alec Klinghoffer; Dr. Lech Nowicki; Patricia O'Dowd; Dr. Hien Pham; Jian Xu

    2001-01-07

    This report describes research conducted to support the DOE program in novel slurry phase catalysts for converting coal-derived synthesis gas to diesel fuels. The primary objective of this research program is to develop attrition resistant catalysts that exhibit high activities for conversion of coal-derived syngas.

  7. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, Charles L. (Tullahoma, TN); Foote, John P. (Tullahoma, TN)

    1995-01-01

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler, the converted boiler including a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones.

  8. Retrofitted coal-fired firetube boiler and method employed therewith

    DOE Patents [OSTI]

    Wagoner, C.L.; Foote, J.P.

    1995-07-04

    A coal-fired firetube boiler and a method for converting a gas-fired firetube boiler to a coal-fired firetube boiler are disclosed. The converted boiler includes a plurality of combustion zones within the firetube and controlled stoichiometry within the combustion zones. 19 figs.

  9. Preliminary assessment of coal-based industrial energy systems

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    This report presents the results of a study, performed by Mittelhauser Corp. and Resource Engineering, Inc. to identify the potential economic, environmental, and energy impacts of possible New Source Performance Standards for industrial steam generators on the use of coal and coal-derived fuels. A systems-level approach was used to take mine-mouth coal and produce a given quantity of heat input to a new boiler at an existing Chicago industrial-plant site. The technologies studied included post-combustion clean-up, atmospheric fluidized-bed combustion, solvent-refined coal liquids, substitute natural gas, and low-Btu gas. Capital and operating costs were prepared on a mid-1985 basis from a consistent set of economic guidelines. The cases studied were evaluated using three levels of air emission controls, two coals, two boiler sizes, and two operating factors. Only those combinations considered likely to make a significant impact on the 1985 boiler population were considered. The conclusions drawn in the report are that the most attractive applications of coal technology are atmospheric fluidized-bed combustion and post-combustion clean-up. Solvent-refined coal and probably substitute natural gas become competitive for the smaller boiler applications. Coal-derived low-Btu gas was found not to be a competitive boiler fuel at the sizes studied. It is recommended that more cases be studied to broaden the applicability of these results.

  10. CONCEPTUAL STUDIES OF A FUEL-FLEXIBLE LOW-SWIRL COMBUSTION SYSTEM FOR THE GAS TURBINE IN CLEAN COAL POWER PLANTS

    SciTech Connect (OSTI)

    Smith, K.O.; Littlejohn, David; Therkelsen, Peter; Cheng, Robert K.; Ali, S.

    2009-11-30

    This paper reports the results of preliminary analyses that show the feasibility of developing a fuel flexible (natural gas, syngas and high-hydrogen fuel) combustion system for IGCC gas turbines. Of particular interest is the use of Lawrence Berkeley National Laboratory's DLN low swirl combustion technology as the basis for the IGCC turbine combustor. Conceptual designs of the combustion system and the requirements for the fuel handling and delivery circuits are discussed. The analyses show the feasibility of a multi-fuel, utility-sized, LSI-based, gas turbine engine. A conceptual design of the fuel injection system shows that dual parallel fuel circuits can provide range of gas turbine operation in a configuration consistent with low pollutant emissions. Additionally, several issues and challenges associated with the development of such a system, such as flashback and auto-ignition of the high-hydrogen fuels, are outlined.

  11. Process for clean-burning fuel from low-rank coal

    DOE Patents [OSTI]

    Merriam, Norman W. (Laramie, WY); Sethi, Vijay (Laramie, WY); Brecher, Lee E. (Laramie, WY)

    1994-01-01

    A process for upgrading and stabilizing low-rank coal involving the sequential processing of the coal through three fluidized beds; first a dryer, then a pyrolyzer, and finally a cooler. The fluidizing gas for the cooler is the exit gas from the pyrolyzer with the addition of water for cooling. Overhead gas from pyrolyzing is likely burned to furnish the energy for the process. The product coal exits with a tar-like pitch sealant to enhance its safety during storage.

  12. Beluga Coal Gasification - ISER

    SciTech Connect (OSTI)

    Steve Colt

    2008-12-31

    ISER was requested to conduct an economic analysis of a possible 'Cook Inlet Syngas Pipeline'. The economic analysis was incorporated as section 7.4 of the larger report titled: 'Beluga Coal Gasification Feasibility Study, DOE/NETL-2006/1248, Phase 2 Final Report, October 2006, for Subtask 41817.333.01.01'. The pipeline would carry CO{sub 2} and N{sub 2}-H{sub 2} from a synthetic gas plant on the western side of Cook Inlet to Agrium's facility. The economic analysis determined that the net present value of the total capital and operating lifecycle costs for the pipeline ranges from $318 to $588 million. The greatest contributor to this spread is the cost of electricity, which ranges from $0.05 to $0.10/kWh in this analysis. The financial analysis shows that the delivery cost of gas may range from $0.33 to $0.55/Mcf in the first year depending primarily on the price for electricity.

  13. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    coal type mining. Production by coal type Since 1980, China maximizedthe production shares of coal types, the shares of different

  14. Clean and Secure Energy from Coal

    SciTech Connect (OSTI)

    Smith, Philip; Davies, Lincoln; Kelly, Kerry; Lighty, JoAnn; Reitze, Arnold; Silcox, Geoffrey; Uchitel, Kirsten; Wendt, Jost; Whitty, Kevin

    2014-08-31

    The University of Utah, through their Institute for Clean and Secure Energy (ICSE), performed research to utilize the vast energy stored in our domestic coal resources and to do so in a manner that will capture CO2 from combustion from stationary power generation. The research was organized around the theme of validation and uncertainty quantification (V/UQ) through tightly coupled simulation and experimental designs and through the integration of legal, environment, economics and policy issues. The project included the following tasks: • Oxy-Coal Combustion – To ultimately produce predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. • High-Pressure, Entrained-Flow Coal Gasification – To ultimately provide a simulation tool for industrial entrained-flow integrated gasification combined cycle (IGCC) gasifier with quantified uncertainty. • Chemical Looping Combustion (CLC) – To develop a new carbon-capture technology for coal through CLC and to transfer this technology to industry through a numerical simulation tool with quantified uncertainty bounds. • Underground Coal Thermal Treatment – To explore the potential for creating new in-situ technologies for production of synthetic natural gas (SNG) from deep coal deposits and to demonstrate this in a new laboratory-scale reactor. • Mercury Control – To understand the effect of oxy-firing on the fate of mercury. • Environmental, Legal, and Policy Issues – To address the legal and policy issues associated with carbon management strategies in order to assess the appropriate role of these technologies in our evolving national energy portfolio. • Validation/Uncertainty Quantification for Large Eddy Simulations of the Heat Flux in the Tangentially Fired Oxy-Coal Alstom Boiler Simulation Facility – To produce predictive capability with quantified uncertainty bounds for the heat flux in commercial-scale, tangentially fired, oxy-coal boilers.

  15. Chlorine in coal and its relationship with boiler corrosion. Technical report, 1 March--31 May 1994

    SciTech Connect (OSTI)

    Chou, M.I.M.; Lytle, J.M.; Ruch, R.R. [Illinois State Geological Survey, Champaign, IL (United States)] [and others

    1994-09-01

    Limited literature and use history data have suggested that some high-chlorine Illinois coals do not cause boiler corrosion while extensive data developed by the British correlate corrosion with chlorine content and other parameters related to the coal and boiler. The differences in corrosivity in coals may be due to the coal properties, to blending of coals, or to the boiler parameters in which they were burned. The goals of this study focus on coal properties. In this quarter, both destructive temperature-programmed Thermogravimetry with Fourier transform infrared (TGA-FTIR) and non-destructive X-ray absorption near-edge structure (XANES) techniques were used to examine the forms and the evolution characteristics of chlorine in coals. The TGA-FTIR results indicate that under oxidation condition, both British and Illinois coals release hydrogen chloride gas. Illinois coals release the gas at high temperature with maximum evolution temperature ranged between 210 and 280 C. The XANES results indicate that chlorine in coal exists in ionic forms including a solid salt form. The solid NaCl salt form, however, is observed only in some of the British coals and none of the Illinois coals. These results combined with TGA-FTIR results suggest that the chlorine ions in Illinois coals are different from the chlorine ions in British coals.

  16. The spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil Point, California

    E-Print Network [OSTI]

    Washburn, Libe

    The spatial scales, distribution, and intensity of natural marine hydrocarbon seeps near Coal Oil pollution sources. A field of strong hydrocarbon seepage offshore of Coal Oil Point near Santa Barbara in the Coal Oil Point field to measure directly the atmospheric gas flux from three seeps of varying size

  17. Solution for Coal Seam Deaasi ication Wel s =ducing Under Two-Phase Flow Conditkms

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    tested extensively using a wide range of coal properties including desorption charac- teristics, and were. `E 22673 7ype-Curve ., Solution for Coal Seam Deaasi ication Wel s =ducing Under Two-Phase Flow the presenceof water in the coal seam and its co- production with gas. The developed type curves are capable

  18. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01

    Plant - without coking (lb/hr) Feed Coal* Hydrogen YieldsCoking Summary Cost Estimates for Solvent Refining of Five U.S. CoalsCoal Handling and Preparation Preheaters and Dissolvers Mineral Separation (Filters) Solvent Recovery Gas Recovery Mineral Residue Processing and Storage Coking

  19. CORROSION OF Fe-10Al-Cr ALLOYS BY COAL CHAR

    E-Print Network [OSTI]

    Gordon, B.A.

    2011-01-01

    off-gas from a typical gasifier contains large percentagesIOAl-Cr alloys at coal-gasifier This FeS and CaS0 operating

  20. Investigation of plasma-aided bituminous coal gasification

    SciTech Connect (OSTI)

    Matveev, I.B.; Messerle, V.E.; Ustimenko, A.B. [Applied Plasma Technology, Mclean, VA (United States)

    2009-04-15

    This paper presents thermodynamic and kinetic modeling of plasma-aided bituminous coal gasification. Distributions of concentrations, temperatures, and velocities of the gasification products along the gasifier are calculated. Carbon gasification degree, specific power consumptions, and heat engineering characteristics of synthesis gas at the outlet of the gasifier are determined at plasma air/steam and oxygen/steam gasification of Powder River Basin bituminous coal. Numerical simulation showed that the plasma oxygen/steam gasification of coal is a more preferable process in comparison with the plasma air/steam coal gasification. On the numerical experiments, a plasma vortex fuel reformer is designed.

  1. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    power plant pulverized coal power plant v Advanced Coal WindMW coal gasification combined cycle power plant equippedMW coal gasification, combined cycle power plant equipped

  2. Gasifier feed - Tailor-made from Illinois coals

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III (Illinois State Geological Survey, Champaign, IL (United States)); Lytle, J.; Frost, R.R.; Lizzio, A.; Kohlenberger, L.; Brewer, K. (Illinois State Geological Survey, Champaign, IL (United States) DESTEC Energy (United States) Williams Technology (United States) Illinois Coal Association (United States))

    1992-01-01

    The main purpose of this project is to produce a feedstock from preparation plant fines from an Illinois coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high sulfur content and high Btu value of Illinois coals are particularly advantageous in such a gasifier; preliminary calculations indicate that the increased cost of removing sulfur from the gas from a high sulfur coal is more than offset by the increased revenue from the sale of the elemental sulfur; additionally the high Btu Illinois coal concentrates more energy into the slurry of a given coal to water ratio. This project will bring the expertise of four organizations together to perform the various tasks. The Illinois Coal Association will help direct the project to be the most beneficial to the Illinois coal industry. DESTEC Energy, a wholly-owned subsidiary of Dow Chemical Company, will provide guidelines and test compatibility of the slurries developed for gasification feedstock. Williams Technology will provide their expertise in long distance slurry pumping, and test selected products for viscosity, pumpability, and handlability. The Illinois State Geological Survey will study methods for producing clean coal/water slurries from preparation plant wastes including the concentration of pyritic sulfur into the coal slurry to increase the revenue from elemental sulfur produced during gasification operations, and decrease the pyritic sulfur content of the waste streams. ISGS will also test the gasification reactivity of the coals. As reported earlier, a variety of possible samples of coal have been analyzed and the gasification performance evaluation reported. Additionally, commercial sized samples of -28 mesh {times} 100 mesh coal -100 {times} 0 coal were subjected to pumpability testing. Neither the coarse product nor the fine product by themselves proved to be good candidates for trouble free pumping, but the mix of the two proved to be a very acceptable product

  3. JEDI II: Jobs and Economic Development Impacts from Coal, Naural...

    Wind Powering America (EERE)

    new coal, gas, or wind plant: * Year of installation * Size of the project * Location * Cost (kW) * Any other site-specific information The more information the user provides,...

  4. New Computer Codes Unlock the Secrets of Cleaner Burning Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - 250 megawatts of which are supplied to the electric grid. The plant's gas cleaning technology removes more than 98 percent of the sulfur in coal, converting it to a...

  5. Application of Multivariable Control to Oil and Coal Fired Boilers 

    E-Print Network [OSTI]

    Swanson, K.

    1981-01-01

    Increased visibility provided by advanced measurement and control techniques has shown that control of oil and coal fired boilers is a complex problem involving simultaneous determination of flue gas carbon monoxide, ...

  6. Pressurized pyrolysis and gasification of Chinese typical coal samples

    SciTech Connect (OSTI)

    Hanping Chen; Zhiwu Luo; Haiping Yang; Fudong Ju; Shihong Zhang [Huazhong University of Science and Technology, Wuhan (China). State Key Laboratory of Coal Combustion

    2008-03-15

    This paper aims to understand the pyrolysis and gasification behavior of different Chinese coal samples at different pressures. First, the pyrolysis of four typical Chinese coals samples (Xiaolongtan brown coal, Shenfu bituminous coal, Pingzhai anthracite coal, and Heshan lean coal) were carried out using a pressurized thermogravimetric analyzer at ambient pressure and 3 MPa, respectively. The surface structure and elemental component of the resultant char were measured with an automated gas adsorption apparatus and element analyzer. It was observed that higher pressure suppressed the primary pyrolysis, while the secondary pyrolysis of coal particles was promoted. With respect to the resultant solid char, the carbon content increased while H content decreased; however, the pore structure varied greatly with increasing pressure for different coal samples. For Xiaolongtan brown coal (XLT) char, it decreased greatly, while it increased obviously for the other three char types. Then, the isothermal gasification behavior of solid char particles was investigated using an ambient thermal analyzer with CO{sub 2} as the gasifying agent at 1000{sup o}C. The gasification reactivity of solid char was decreased greatly with increasing pyrolysis pressure. However, the extent of change displayed a vital relation with the characteristics of the original coal sample. 26 refs., 5 figs., 5 tabs.

  7. The Development of Warm Gas Cleanup Technologies for the Removal of Sulfur Containing Species from Steam Hydrogasification

    E-Print Network [OSTI]

    Luo, Qian

    2012-01-01

    sulfur was strongly dependent on coal type. Gryglewicz [19]coal) [9] and other factors such as heating rate, time, pressure and velocity of the carrying gas, type

  8. Generating power with drained coal mine methane

    SciTech Connect (OSTI)

    2005-09-01

    The article describes the three technologies most commonly used for generating electricity from coal mine methane: internal combustion engines, gas turbines, and microturbines. The most critical characteristics and features of these technologies, such as efficiency, output and size are highlighted. 5 refs.

  9. Comparative assessment of health and safety impacts of coal use

    SciTech Connect (OSTI)

    Not Available

    1980-03-01

    Increasing the use of coal to replace oil and gas consumption is considered beneficial for economic and political reasons. The evaluation of this report, however, is that the shift to coal can involve significant health, safety, and environmental impacts compared to those from oil and natural gas systems, which are considerably less adverse than those of any coal energy system in use today. An evaluation and comparison of the potential impacts from the various alternative coal technologies would be useful to both governmental and industrial policy planners and would provide them with information relevant to a decision on assistance, incentives, and prioritization among the energy technologies. It is, therefore, the main objective of this report to review the key health, safety, and environmental impacts of some promising coal energy technologies and to compare them.

  10. Comparative Life-Cycle Air Emissions of Coal, Domestic Natural

    E-Print Network [OSTI]

    Jaramillo, Paulina

    near projected levels, the average wellhead price of natural gas peaked at $11/Mcf in October 2005 (6Comparative Life-Cycle Air Emissions of Coal, Domestic Natural Gas, LNG, and SNG for Electricity States' natural gas (NG) demand for electricity generation will increase. Estimates also suggest that NG

  11. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    a particular type of coal, each of which is inherentlyThere are four classes of coal: bituminous, sub-bituminous,minerals Metallic ores Coal Crude petroleum Gasoline Fuel

  12. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    Council (NCC), 2006, “Coal: America’s Energy Future”, VolumeCan Coal Deliver? America’s Coal Potential & Limits”, Studycoal generating units currently in operation throughout North America (

  13. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    5 Figure 1: Map of U.S. coal plants and generating1: Map of U.S. coal plants and generating units (GED, 2006a)of an electric generating coal power plant that would be

  14. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    than those of other coal types, depending on the location oftrue that different coal types (in terms of heating values,= installed capacity of i-type coal plants [GW]; HR i = heat

  15. Pore-scale mechanisms of gas flow in tight sand reservoirs

    E-Print Network [OSTI]

    Silin, D.

    2011-01-01

    include tight gas sands, gas shales, and coal-bed methane.Figure 3. Although the gas-shale production grows at a

  16. Pulverized coal fuel injector

    DOE Patents [OSTI]

    Rini, Michael J. (Hebron, CT); Towle, David P. (Windsor, CT)

    1992-01-01

    A pulverized coal fuel injector contains an acceleration section to improve the uniformity of a coal-air mixture to be burned. An integral splitter is provided which divides the coal-air mixture into a number separate streams or jets, and a center body directs the streams at a controlled angle into the primary zone of a burner. The injector provides for flame shaping and the control of NO/NO.sub.2 formation.

  17. Pneumatic solids feeder for coal gasification reactor

    SciTech Connect (OSTI)

    Notestein, J.E.; Halow, J.S.

    1991-12-31

    This invention is comprised of a pneumatic feeder system for a coal gasification reactor which includes one or more feeder tubes entering the reactor above the level of the particle bed inside the reactor. The tubes are inclined downward at their outer ends so that coal particles introduced into the tubes through an aperture at the top of the tubes slides downward away from the reactor and does not fall directly into the reactor. Pressurized gas introduced into, or resulting from ignition of recycled combustible gas in a chamber adjacent to the tube ends, propels the coal from the tube into the reactor volume and onto the particle bed. Leveling of the top of the bed is carried out by a bladed rotor mounted on the reactor stirring shaft. Coal is introduced into the tubes from containers above the tubes by means of rotary valves placed across supply conduits. This system avoids placement of feeder hardware in the plenum above the particle bed and keeps the coal from being excessively heated prior to reaching the particle bed.

  18. Optimization of Oxygen Purity for Coal Conversion Energy Reduction 

    E-Print Network [OSTI]

    Baker, C. R.; Pike, R. A.

    1982-01-01

    or liquefaction. Gasification of coal is a partial oxidation process in which steam and oxygen are reacted with coal to produce a mixture of hydrogen and carbon monoxide plus a number of other components. This mixture has a heating value of about 300 Btu..., or hydrocarbon liquids. The synthesis gas mixture can also be converted by means of the water gas shift reaction to produce hydrogen Which, in turn, can be reacted with coal to form hydrocarbon liquids by direct liquefaction techniques. Oxygen is required...

  19. The Coal Transportation Rate Database

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYear Jan3 November18.5 385.5Dry Production (Million CubicThe Coal

  20. U.S. Coal Reserves

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979 1.988Prices,Flight.... 111.1Marcellus RegionProduct:Coal

  1. Weekly Coal Production Estimation Methodology

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal Consumers inYear JanSalesa.E.DRAFT0, 19977,

  2. Clean Coal Projects (Virginia)

    Broader source: Energy.gov [DOE]

    This legislation directs the Virginia Air Pollution Control Board to facilitate the construction and implementation of clean coal projects by expediting the permitting process for such projects.

  3. Balancing coal pipes

    SciTech Connect (OSTI)

    Earley, D.; Kirkenir, B.

    2009-11-15

    Balancing coal flow to the burners to optimise combustion by using real-time measurement systems (such as microwave mass measurement) is discussed. 3 figs.

  4. Coal | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    capture, utilization and sequestration. Featured Energy Secretary Moniz Visits Clean Coal Facility in Mississippi On Friday, Nov. 8, 2013, Secretary Moniz and international...

  5. Coal liquefaction quenching process

    DOE Patents [OSTI]

    Thorogood, Robert M. (Macungie, PA); Yeh, Chung-Liang (Bethlehem, PA); Donath, Ernest E. (St. Croix, VI)

    1983-01-01

    There is described an improved coal liquefaction quenching process which prevents the formation of coke with a minimum reduction of thermal efficiency of the coal liquefaction process. In the process, the rapid cooling of the liquid/solid products of the coal liquefaction reaction is performed without the cooling of the associated vapor stream to thereby prevent formation of coke and the occurrence of retrograde reactions. The rapid cooling is achieved by recycling a subcooled portion of the liquid/solid mixture to the lower section of a phase separator that separates the vapor from the liquid/solid products leaving the coal reactor.

  6. Rail Coal Transportation Rates

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Recurring Reserves Stocks All reports Browse by Tag Alphabetical Frequency Tag Cloud Data For: 2001 Next Release Date: October 2003 U. S. Coal-Producing Districts...

  7. Gas flux and carbonate occurrence at a shallow seep of thermogenic natural gas

    E-Print Network [OSTI]

    2010-01-01

    DL (2008) Disentangling oil weathering at a marine seepAbstract The Coal Oil Point seep field located offshorethe thermo- genic gas and oil seeps located near Coal Oil

  8. Shale Gas Application in Hydraulic Fracturing Market is likely...

    Open Energy Info (EERE)

    on unconventional reservoirs such as coal bed methane, tight gas, tight oil, shale gas, and shale oil. Over the period of time, hydraulic fracturing technique has found...

  9. Underground CO2 Storage, Natural Gas Recovery Targeted by Virginia...

    Energy Savers [EERE]

    to permanently store the greenhouse gas while simultaneously recovering natural gas. Organic-rich sedimentary rocks, such as shale and coal, consist of nondecayed organic...

  10. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    coal (PC) or integrated gasification combined cycle ( IGCC)coal (PC) or integrated gasification combined cycle (IGCC)will be integrated gasification combined cycle (IGCC) (Same

  11. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    minerals Metallic ores Coal Crude petroleum Gasoline FuelMetallic ores and concentrates Coal Crude Petroleum Gasoline and aviation turbine fuel

  12. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01

    Credit Extra Fuel Oil Coal to gasifier Na cost· Na processoiL Replace res. with coal as gasifier feed. 543 ton/day @$

  13. COAL DESULFURIZATION PRIOR TO COMBUSTION

    E-Print Network [OSTI]

    Wrathall, J.

    2013-01-01

    Corporation, 5-25~79. on Coal Liquefaction at ChevronHamersma, et a L, "Meyers Process for Coal Desulfurization,"in Wheelock, Coal Desulfurization, ACS Symp. Ser 64 (1977(.

  14. Catalyst for coal liquefaction process

    DOE Patents [OSTI]

    Huibers, Derk T. A. (Pennington, NJ); Kang, Chia-Chen C. (Princeton, NJ)

    1984-01-01

    An improved catalyst for a coal liquefaction process; e.g., the H-Coal Process, for converting coal into liquid fuels, and where the conversion is carried out in an ebullated-catalyst-bed reactor wherein the coal contacts catalyst particles and is converted, in addition to liquid fuels, to gas and residual oil which includes preasphaltenes and asphaltenes. The improvement comprises a catalyst selected from the group consisting of the oxides of nickel molybdenum, cobalt molybdenum, cobalt tungsten, and nickel tungsten on a carrier of alumina, silica, or a combination of alumina and silica. The catalyst has a total pore volume of about 0.500 to about 0.900 cc/g and the pore volume comprises micropores, intermediate pores and macropores, the surface of the intermediate pores being sufficiently large to convert the preasphaltenes to asphaltenes and lighter molecules. The conversion of the asphaltenes takes place on the surface of micropores. The macropores are for metal deposition and to prevent catalyst agglomeration. The micropores have diameters between about 50 and about 200 angstroms (.ANG.) and comprise from about 50 to about 80% of the pore volume, whereas the intermediate pores have diameters between about 200 and 2000 angstroms (.ANG.) and comprise from about 10 to about 25% of the pore volume, and the macropores have diameters between about 2000 and about 10,000 angstroms (.ANG.) and comprise from about 10 to about 25% of the pore volume. The catalysts are further improved where they contain promoters. Such promoters include the oxides of vanadium, tungsten, copper, iron and barium, tin chloride, tin fluoride and rare earth metals.

  15. A perspective on syngas from coal

    SciTech Connect (OSTI)

    Rath, L.K.; Longanbach, J.R. )

    1991-01-01

    Syngas, a mixture of hydrogen and carbon monoxide, has been produced from coal for more than 100 years. But today most syngas is produced from noncoal feedstocks, by catalytic steam reforming of natural gas and naphtha or partial oxidation of heavy hydrocarbons such as petroleum resid. Three types of syngas, characterized by their H{sub 2}/CO ratio, are needed. Low ratio, H{sub 2}/CO = 0.4-0.8, syngas can be used in recently developed processes such as the Liquid Phase Methanol synthesis and the Shell Fischer-Tropsch wax synthesis; moderate ratio, H{sub 2}/CO = 0.8-1.5, syngas is used in the Tennessee Eastman coal based synthesis of methanol and acetic anhydride; high ratio, H{sub 2}/CO = 1.8-2.5, syngas is used in traditional methanol synthesis and the Fischer-Tropsch synthesis at Sasol. Different types of gasifiers are available for the production of syngas. These include Lurgi fixed-bed dry bottom and slagging gasifiers, agglomerating fluidized-bed gasifiers, single and two-stage entrained slurry feed gasifiers, and single-stage entrained dry feed gasifiers. The cost of syngas from subbituminous coal is shown to be relatively insensitive to the H{sub 2}/CO ratio produced and may soon be competitive with natural gas-based syngas in some parts of the country due to the increasing demand for and cost of natural gas. Recent in this paper, DOE sponsored research on three topics on the production of syngas from coal, coal gasifiers for the direct production of high hydrogen content syngas, advanced methods to separate hydrogen from syngas at elevated temperatures and biological conversion of coal to syngas, are also discussed.

  16. Tracking new coal-fired power plants: coal's resurgence in electric power generation

    SciTech Connect (OSTI)

    NONE

    2007-05-01

    This information package is intended to provide an overview of 'Coal's resurgence in electric power generation' by examining proposed new coal-fired power plants that are under consideration in the USA. The results contained in this package are derived from information that is available from various tracking organizations and news groups. Although comprehensive, this information is not intended to represent every possible plant under consideration but is intended to illustrate the large potential that exists for new coal-fired power plants. It should be noted that many of the proposed plants are likely not to be built. For example, out of a total portfolio (gas, coal, etc.) of 500 GW of newly planned power plant capacity announced in 2001, 91 GW have been already been scrapped or delayed. 25 refs.

  17. Laboratory scale studies of Pd/{gamma}-Al{sub 2}O{sub 3} sorbents for the removal of trace contaminants from coal-derived fuel gas at elevated temperatures

    SciTech Connect (OSTI)

    Rupp, Erik C.; Granite, Evan J.; Stanko, Dennis C.

    2013-01-01

    The Integrated Gasification Combined Cycle (IGCC) is a promising technology for the use of coal in a clean and efficient manner. In order to maintain the overall efficiency of the IGCC process, it is necessary to clean the fuel gas of contaminants (sulfur, trace compounds) at warm (150–540 °C) to hot (>540 °C) temperatures. Current technologies for trace contaminant (such as mercury) removal, primarily activated carbon based sorbents, begin to lose effectiveness above 100 °C, creating the need to develop sorbents effective at elevated temperatures. As trace elements are of particular environmental concern, previous work by this group has focused on the development of a Pd/?-Al{sub 2}O{sub 3} sorbent for Hg removal. This paper extends the research to Se (as hydrogen selenide, H{sub 2}Se), As (as arsine, AsH{sub 3}), and P (as phosphine, PH{sub 3}) which thermodynamic studies indicate are present as gaseous species under gasification conditions. Experiments performed under ambient conditions in He on 20 wt.% Pd/?-Al{sub 2}O{sub 3} indicate the sorbent can remove the target contaminants. Further work is performed using a 5 wt.% Pd/?-Al{sub 2}O{sub 3} sorbent in a simulated fuel gas (H{sub 2}, CO, CO{sub 2}, N{sub 2} and H{sub 2}S) in both single and multiple contaminant atmospheres to gauge sorbent performance characteristics. The impact of H{sub 2}O, Hg and temperature on sorbent performance is explored.

  18. Plasma gasification of coal in different oxidants

    SciTech Connect (OSTI)

    Matveev, I.B.; Messerle, V.E.; Ustimenko, A.B. [Applied Plasma Technology, Mclean, VA (USA)

    2008-12-15

    Oxidant selection is the highest priority for advanced coal gasification-process development. This paper presents comparative analysis of the Powder River Basin bituminous-coal gasification processes for entrained-flow plasma gasifier. Several oxidants, which might be employed for perspective commercial applications, have been chosen, including air, steam/carbon-dioxide blend, carbon dioxide, steam, steam/air, steam/oxygen, and oxygen. Synthesis gas composition, carbon gasification degree, specific power consumptions, and power efficiency for these processes were determined. The influence of the selected oxidant composition on the gasification-process main characteristics have been investigated.

  19. Illinois Coal Development Program (Illinois)

    Broader source: Energy.gov [DOE]

    The Illinois Coal Development Program seeks to advance promising clean coal technologies beyond research and towards commercialization. The program provides a 50/50 match with private industry...

  20. COAL DESULFURIZATION PRIOR TO COMBUSTION

    E-Print Network [OSTI]

    Wrathall, J.

    2013-01-01

    10%. These two properties can be used to classify coals forsulfur in the coal to be burned. Other properties, such as

  1. Clean coal technologies market potential

    SciTech Connect (OSTI)

    Drazga, B. (ed.)

    2007-01-30

    Looking at the growing popularity of these technologies and of this industry, the report presents an in-depth analysis of all the various technologies involved in cleaning coal and protecting the environment. It analyzes upcoming and present day technologies such as gasification, combustion, and others. It looks at the various technological aspects, economic aspects, and the various programs involved in promoting these emerging green technologies. Contents: Industry background; What is coal?; Historical background of coal; Composition of coal; Types of coal; Environmental effects of coal; Managing wastes from coal; Introduction to clean coal; What is clean coal?; Byproducts of clean coal; Uses of clean coal; Support and opposition; Price of clean coal; Examining clean coal technologies; Coal washing; Advanced pollution control systems; Advanced power generating systems; Pulverized coal combustion (PCC); Carbon capture and storage; Capture and separation of carbon dioxide; Storage and sequestration of carbon dioxide; Economics and research and development; Industry initiatives; Clean Coal Power Initiative; Clean Coal Technology Program; Coal21; Outlook; Case Studies.

  2. Coal surface structure and thermodynamics. Final report

    SciTech Connect (OSTI)

    Larsen, J.W.; Wernett, P.C.; Glass, A.S.; Quay, D.; Roberts, J.

    1994-05-01

    Coals surfaces were studied using static surface adsorption measurements, low angle x-ray scattering (LAXS), inverse gas chromatography (IGC) and a new {sup 13}C NMR relaxation technique. A comparison of surface areas determined by hydrocarbon gas adsorption and LAXS led to the twin conclusions that the hydrocarbons had to diffuse through the solid to reach isolated pores and that the coal pores do not form interconnected networks, but are largely isolated. This conclusion was confirmed when IGC data for small hydrocarbons showed no discontinuities in their size dependence as usually observed with porous solids. IGC is capable of providing adsorption thermodynamics of gases on coal surfaces. The interactions of non-polar molecules and coal surfaces are directly proportioned to the gas molecular polarizability. For bases, the adsorption enthalpy is equal to the polarizability interaction plus the heat of hydrogen bond formation with phenol. Amphoteric molecules have more complex interactions. Mineral matter can have highly specific effects on surface interactions, but with most of the molecules studied is not an important factor.

  3. Method for coal liquefaction

    DOE Patents [OSTI]

    Wiser, Wendell H. (Kaysville, UT); Oblad, Alex G. (Salt Lake City, UT); Shabtai, Joseph S. (Salt Lake City, UT)

    1994-01-01

    A process is disclosed for coal liquefaction in which minute particles of coal in intimate contact with a hydrogenation catalyst and hydrogen arc reacted for a very short time at a temperature in excess of 400.degree. C. at a pressure of at least 1500 psi to yield over 50% liquids with a liquid to gaseous hydrocarbon ratio in excess of 8:1.

  4. Mechanochemical hydrogenation of coal

    DOE Patents [OSTI]

    Yang, Ralph T. (Tonawanda, NY); Smol, Robert (East Patchogue, NY); Farber, Gerald (Elmont, NY); Naphtali, Leonard M. (Washington, DC)

    1981-01-01

    Hydrogenation of coal is improved through the use of a mechanical force to reduce the size of the particulate coal simultaneously with the introduction of gaseous hydrogen, or other hydrogen donor composition. Such hydrogen in the presence of elemental tin during this one-step size reduction-hydrogenation further improves the yield of the liquid hydrocarbon product.

  5. Coal liquefaction process

    DOE Patents [OSTI]

    Carr, Norman L. (Allison Park, PA); Moon, William G. (Cheswick, PA); Prudich, Michael E. (Pittsburgh, PA)

    1983-01-01

    A C.sub.5 -900.degree. F. (C.sub.5 -482.degree. C.) liquid yield greater than 50 weight percent MAF feed coal is obtained in a coal liquefaction process wherein a selected combination of higher hydrogen partial pressure, longer slurry residence time and increased recycle ash content of the feed slurry are controlled within defined ranges.

  6. Coal. [Great Plains Project

    SciTech Connect (OSTI)

    Not Available

    1981-03-01

    The status of various research projects related to coal is considered: gasification (approximately 30 processes) and in-situ gasification. Methanol production, retrofitting internal combustion engines to stratified charge engines, methanation (Conoco), direct reduction of iron ores, water resources, etc. Approximately 200 specific projects related to coal are considered with respect to present status. (LTN)

  7. Cooperative research program in coal liquefaction

    SciTech Connect (OSTI)

    Huffman, G.P.

    1991-01-01

    This Quarterly Report on coal liquefaction research includes discussion in the areas of (1) Iron Based Catalysts for Coal Liquefaction; (2) Exploratory Research on Coal Conversion; (3) Novel Coal Liquefaction Concepts; (4) Novel Catalysts for Coal Liquefaction. (VC)

  8. Coal in China

    SciTech Connect (OSTI)

    Minchener, A.J. [IEA Clean Coal Centre, London (United Kingdom)

    2005-07-01

    The article gives an overview of the production and use of coal in China, for power generation and in other sectors. Coal use for power generation was 850 million tonnes in 2003 and 800 million tonnes in the non-power sector. The majority of power will continue to be produced from coal, with a trend towards new larger pulverised coal fired units and introduction of circulating fluidised bed combustors. Stricter regulations are forcing introduction of improved pollution control technologies. It seems likely that China will need international finance to supplement private and state investment to carry out a programme to develop and apply clean coal technologies. The author concludes that there is evidence of a market economy being established but there is a need to resolve inconsistencies with the planned aspects of the economy and that additional policies are needed in certain sectors to achieve sustainable development. 1 ref., 2 figs., 2 tabs.

  9. Sibley station low-sulfur coal conversion program

    SciTech Connect (OSTI)

    Rupinskas, R.L. [Sargent & Lundy LLC, Chicago, IL (United States); Rembold, D.F. [Missouri Public Service, Kansas City, MO (United States)

    1995-03-01

    After embarking on an upgrade project in 1986 that was designed to allow efficient and reliable operation of its coal-fired Sibley station through 2010, Missouri Public Service (MPS) faced the uncertainty of impending acid-rain legislation. To protect its investment in the Sibley Rebuild Program, the utility evaluated compliance options based on the emerging legislation and concluded that switching to low-sulfur coal offered the least-cost compliance approach. Compared to installing a scrubber, switching to a low-sulfur coal was also more straightforward, although not without challenges and complications. This paper reviews the Sibley low-sulfur coal conversion program. At Sibley, fuel switching was chosen only after numerous internal and external studies; it withstood late challenges from natural gas and allowance trading. Switching demanded additional equipment to blend Power River Basin coals and other coals, and demanded additional and upgraded protective equipment in the areas of fire protection, dust collection, and explosion prevention. In the year since the coal conversion project was completed the facility has operated reliably, the economic benefits of the lower cost Powder River Basin coals have been realized, and the station has also met the requirements of both phases of the acid rain legislation. Fuel switching at Sibley required a team approach and careful analysis. The coal conversion project also required attention and dedication by team members in order to minimize fuel costs while maintaining optimum plant efficiency and availability.

  10. State coal profiles, January 1994

    SciTech Connect (OSTI)

    Not Available

    1994-02-02

    The purpose of State Coal Profiles is to provide basic information about the deposits, production, and use of coal in each of the 27 States with coal production in 1992. Although considerable information on coal has been published on a national level, there is a lack of a uniform overview for the individual States. This report is intended to help fill that gap and also to serve as a framework for more detailed studies. While focusing on coal output, State Coal Profiles shows that the coal-producing States are major users of coal, together accounting for about three-fourths of total US coal consumption in 1992. Each coal-producing State is profiled with a description of its coal deposits and a discussion of the development of its coal industry. Estimates of coal reserves in 1992 are categorized by mining method and sulfur content. Trends, patterns, and other information concerning production, number of mines, miners, productivity, mine price of coal, disposition, and consumption of coal are detailed in statistical tables for selected years from 1980 through 1992. In addition, coal`s contribution to the State`s estimated total energy consumption is given for 1991, the latest year for which data are available. A US summary of all data is provided for comparing individual States with the Nation as a whole. Sources of information are given at the end of the tables.

  11. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01

    a conventional gas-fired power plant to produce electricity.primarily on gas- and oil-fired power plant data made byfrom Coal Burning Power Plant Flue Gases," ASME, Pub. 66-WA/

  12. Process and apparatus for coal hydrogenation

    DOE Patents [OSTI]

    Ruether, John A. (McMurray, PA)

    1988-01-01

    In a coal liquefaction process an aqueous slurry of coal is prepared containing a dissolved liquefaction catalyst. A small quantity of oil is added to the slurry and then coal-oil agglomerates are prepared by agitation of the slurry at atmospheric pressure. The resulting mixture of agglomerates, excess water, dissolved catalyst, and unagglomerated solids is pumped to reaction pressure and then passed through a drainage device where all but a small amount of surface water is removed from the agglomerates. Sufficient catalyst for the reaction is contained in surface water remaining on the agglomerates. The agglomerates fall into the liquefaction reactor countercurrently to a stream of hot gas which is utilized to dry and preheat the agglomerates as well as deposit catalyst on the agglomerates before they enter the reactor where they are converted to primarily liquid products under hydrogen pressure.

  13. Process for coal liquefaction in staged dissolvers

    DOE Patents [OSTI]

    Roberts, George W. (Emmaus, PA); Givens, Edwin N. (Bethlehem, PA); Skinner, Ronald W. (Allentown, PA)

    1983-01-01

    There is described an improved liquefaction process by which coal is converted to a low ash and low sulfur carbonaceous material that can be used as a fuel in an environmentally acceptable manner without costly gas scrubbing equipment. In the process, coal is slurried with a pasting oil, passed through a preheater and at least two dissolvers in series in the presence of hydrogen-rich gases at elevated temperatures and pressures. Solids, including mineral ash and unconverted coal macerals, are separated from the condensed reactor effluent. In accordance with the improved process, the first dissolver is operated at a higher temperature than the second dissolver. This temperature sequence produces improved product selectivity and permits the incorporation of sufficient hydrogen in the solvent for adequate recycle operations.

  14. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01

    coal are least expensive when produced from the Powder River Basin region, where cheaper surface mining

  15. Clean coal technology: The new coal era

    SciTech Connect (OSTI)

    Not Available

    1994-01-01

    The Clean Coal Technology Program is a government and industry cofunded effort to demonstrate a new generation of innovative coal processes in a series of full-scale showcase`` facilities built across the country. Begun in 1986 and expanded in 1987, the program is expected to finance more than $6.8 billion of projects. Nearly two-thirds of the funding will come from the private sector, well above the 50 percent industry co-funding expected when the program began. The original recommendation for a multi-billion dollar clean coal demonstration program came from the US and Canadian Special Envoys on Acid Rain. In January 1986, Special Envoys Lewis and Davis presented their recommendations. Included was the call for a 5-year, $5-billion program in the US to demonstrate, at commercial scale, innovative clean coal technologies that were beginning to emerge from research programs both in the US and elsewhere in the world. As the Envoys said: if the menu of control options was expanded, and if the new options were significantly cheaper, yet highly efficient, it would be easier to formulate an acid rain control plan that would have broader public appeal.

  16. EIA - Weekly U.S. Coal Production

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry Natural GasNatural Gas UsageDieselPresentations,Alabama TableCoal

  17. Coal-water mixture fuel burner

    DOE Patents [OSTI]

    Brown, T.D.; Reehl, D.P.; Walbert, G.F.

    1985-04-29

    The present invention represents an improvement over the prior art by providing a rotating cup burner arrangement for use with a coal-water mixture fuel which applies a thin, uniform sheet of fuel onto the inner surface of the rotating cup, inhibits the collection of unburned fuel on the inner surface of the cup, reduces the slurry to a collection of fine particles upon discharge from the rotating cup, and further atomizes the fuel as it enters the combustion chamber by subjecting it to the high shear force of a high velocity air flow. Accordingly, it is an object of the present invention to provide for improved combustion of a coal-water mixture fuel. It is another object of the present invention to provide an arrangement for introducing a coal-water mixture fuel into a combustion chamber in a manner which provides improved flame control and stability, more efficient combustion of the hydrocarbon fuel, and continuous, reliable burner operation. Yet another object of the present invention is to provide for the continuous, sustained combustion of a coal-water mixture fuel without the need for a secondary combustion source such as natural gas or a liquid hydrocarbon fuel. Still another object of the present invention is to provide a burner arrangement capable of accommodating a coal-water mixture fuel having a wide range of rheological and combustion characteristics in providing for its efficient combustion. 7 figs.

  18. Consensus Coal Production Forecast for

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Consensus Coal Production Forecast for West Virginia 2009-2030 Prepared for the West Virginia Summary 1 Recent Developments 2 Consensus Coal Production Forecast for West Virginia 10 Risks References 27 #12;W.Va. Consensus Coal Forecast Update 2009 iii List of Tables 1. W.Va. Coal Production

  19. Underground coal gasification field experiment in the high-dipping coal seams

    SciTech Connect (OSTI)

    Yang, L.H.; Liu, S.Q.; Yu, L.; Zhang, W. [China University of Mining & Technology, Xuzhou (China). College of Resources & Geoscience

    2009-07-01

    In this article the experimental conditions and process of the underground gasification in the Woniushan Mine, Xuzhou, Jiangsu Province are introduced, and the experimental results are analyzed. By adopting the new method of long-channel, big-section, and two-stage underground coal gasification, the daily gas production reaches about 36,000 m{sup 3}, with the maximum output of 103,700 m{sup 3}. The daily average heating value of air gas is 5.04 MJ/m{sup 3}, with 13.57 MJ/m{sup 3} for water gas. In combustible compositions of water gas, H{sub 2} contents stand at over 50%, with both CO and CH{sub 4} contents over 6%. Experimental results show that the counter gasification can form new temperature conditions and increase the gasification efficiency of coal seams.

  20. Aqueous coal slurry

    SciTech Connect (OSTI)

    Berggren, M.H.; Smit, F.J.; Swanson, W.W.

    1989-10-30

    A principal object of the invention is the provision of an aqueous coal slurry containing a dispersant, which is of low-cost and which contains very low or no levels of sodium, potassium, sulfur and other contaminants. In connection with the foregoing object, it is an object of the invention to provide an aqueous slurry containing coal and dextrin as a dispersant and to provide a method of preparing an aqueous coal slurry which includes the step of adding an effective amount of dextrin as a dispersant. The invention consists of certain novel features and a combination of parts hereinafter fully described, and particularly pointed out in the appended claims. 6 tabs.

  1. Coal liquefaction process

    DOE Patents [OSTI]

    Wright, Charles H. (Overland Park, KS)

    1986-01-01

    A process for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range.

  2. Clean coal today

    SciTech Connect (OSTI)

    none,

    1990-01-01

    This is the first issue of the Clean Coal Today publication. Each issue will provide project status reports, feature articles about certain projects and highlight key events concerning the US Clean Coal Technology Demonstration Program. Projects described in this publication include: Colorado-Ute Electric Association Circulating Fluidized Bed Combustor Project at Nucla, Colorado; Babcock and Wilcox coolside and limestone injection multistage burner process (dry sorbent injection); Coal Tech's Advanced Cyclone Combustor Project; and the TIDD pressurized fluidized bed combustor combined cycle facility in Brilliant, Ohio. The status of other projects is included.

  3. Coal liquefaction process

    DOE Patents [OSTI]

    Wright, C.H.

    1986-02-11

    A process is described for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range. 1 fig.

  4. Removal of mercury from coal via a microbial pretreatment process

    DOE Patents [OSTI]

    Borole, Abhijeet P. (Knoxville, TN); Hamilton, Choo Y. (Knoxville, TN)

    2011-08-16

    A process for the removal of mercury from coal prior to combustion is disclosed. The process is based on use of microorganisms to oxidize iron, sulfur and other species binding mercury within the coal, followed by volatilization of mercury by the microorganisms. The microorganisms are from a class of iron and/or sulfur oxidizing bacteria. The process involves contacting coal with the bacteria in a batch or continuous manner. The mercury is first solubilized from the coal, followed by microbial reduction to elemental mercury, which is stripped off by sparging gas and captured by a mercury recovery unit, giving mercury-free coal. The mercury can be recovered in pure form from the sorbents via additional processing.

  5. Method for gasification of deep, thin coal seams

    DOE Patents [OSTI]

    Gregg, David W. (Moraga, CA)

    1982-01-01

    A method of gasification of coal in deep, thin seams by using controlled bending subsidence to confine gas flow to a region close to the unconsumed coal face. The injection point is moved sequentially around the perimeter of a coal removal area from a production well to sweep out the area to cause the controlled bending subsidence. The injection holes are drilled vertically into the coal seam through the overburden or horizontally into the seam from an exposed coal face. The method is particularly applicable to deep, thin seams found in the eastern United States and at abandoned strip mines where thin seams were surface mined into a hillside or down a modest dip until the overburden became too thick for further mining.

  6. Method for gasification of deep, thin coal seams. [DOE patent

    DOE Patents [OSTI]

    Gregg, D.W.

    1980-08-29

    A method of gasification of coal in deep, thin seams by using controlled bending subsidence to confine gas flow to a region close to the unconsumed coal face is given. The injection point is moved sequentially around the perimeter of a coal removal area from a production well to sweep out the area to cause the controlled bending subsidence. The injection holes are drilled vertically into the coal seam through the overburden or horizontally into the seam from an exposed coal face. The method is particularly applicable to deep, thin seams found in the eastern United States and at abandoned strip mines where thin seams were surface mined into a hillside or down a modest dip until the overburden became too thick for further mining.

  7. Enhanced Combustion Low NOx Pulverized Coal Burner

    SciTech Connect (OSTI)

    David Towle; Richard Donais; Todd Hellewell; Robert Lewis; Robert Schrecengost

    2007-06-30

    For more than two decades, Alstom Power Inc. (Alstom) has developed a range of low cost, infurnace technologies for NOx emissions control for the domestic U.S. pulverized coal fired boiler market. This includes Alstom's internally developed TFS 2000{trademark} firing system, and various enhancements to it developed in concert with the U.S. Department of Energy. As of the date of this report, more than 270 units representing approximately 80,000 MWe of domestic coal fired capacity have been retrofit with Alstom low NOx technology. Best of class emissions range from 0.18 lb/MMBtu for bituminous coal to 0.10 lb/MMBtu for subbituminous coal, with typical levels at 0.24 lb/MMBtu and 0.13 lb/MMBtu, respectively. Despite these gains, NOx emissions limits in the U.S. continue to ratchet down for new and existing boiler equipment. On March 10, 2005, the Environmental Protection Agency (EPA) announced the Clean Air Interstate Rule (CAIR). CAIR requires 25 Eastern states to reduce NOx emissions from the power generation sector by 1.7 million tons in 2009 and 2.0 million tons by 2015. Low cost solutions to meet such regulations, and in particular those that can avoid the need for a costly selective catalytic reduction system (SCR), provide a strong incentive to continue to improve low NOx firing system technology to meet current and anticipated NOx control regulations. The overall objective of the work is to develop an enhanced combustion, low NOx pulverized coal burner, which, when integrated with Alstom's state-of-the-art, globally air staged low NOx firing systems will provide a means to achieve: Less than 0.15 lb/MMBtu NOx emissions when firing a high volatile Eastern or Western bituminous coal, Less than 0.10 lb/MMBtu NOx emissions when firing a subbituminous coal, NOx reduction costs at least 25% lower than the costs of an SCR, Validation of the NOx control technology developed through large (15 MWt) pilot scale demonstration, and Documentation required for economic evaluation and commercial application. During the project performance period, Alstom performed computational fluid dynamics (CFD) modeling and large pilot scale combustion testing in its Industrial Scale Burner Facility (ISBF) at its U.S. Power Plant Laboratories facility in Windsor, Connecticut in support of these objectives. The NOx reduction approach was to optimize near-field combustion to ensure that minimum NOx emissions are achieved with minimal impact on unburned carbon in ash, slagging and fouling, corrosion, and flame stability/turn-down. Several iterations of CFD and combustion testing on a Midwest coal led to an optimized design, which was extensively combustion tested on a range of coals. The data from these tests were then used to validate system costs and benefits versus SCR. Three coals were evaluated during the bench-scale and large pilot-scale testing tasks. The three coals ranged from a very reactive subbituminous coal to a moderately reactive Western bituminous coal to a much less reactive Midwest bituminous coal. Bench-scale testing was comprised of standard ASTM properties evaluation, plus more detailed characterization of fuel properties through drop tube furnace testing and thermogravimetric analysis. Bench-scale characterization of the three test coals showed that both NOx emissions and combustion performance are a strong function of coal properties. The more reactive coals evolved more of their fuel bound nitrogen in the substoichiometric main burner zone than less reactive coal, resulting in the potential for lower NOx emissions. From a combustion point of view, the more reactive coals also showed lower carbon in ash and CO values than the less reactive coal at any given main burner zone stoichiometry. According to bench-scale results, the subbituminous coal was found to be the most amenable to both low NOx, and acceptably low combustibles in the flue gas, in an air staged low NOx system. The Midwest bituminous coal, by contrast, was predicted to be the most challenging of the three coals, with the Western bituminous coal predicted to beh

  8. Recent advances in coal geochemistry

    SciTech Connect (OSTI)

    Chyi, L.L. (Dept. of Geology, Univ. of Akron, Akron, OH (US)); Chou, C.-L. (Illinois State Geological Survey, 615 E. Peabody Drive, Champaign, IL (US))

    1990-01-01

    Chapters in this collection reflect the recent emphasis both on basic research in coal geochemistry and on applied aspects related to coal utilization. Geochemical research on peat and coal generates compositional data that are required for the following reasons. First, many studies in coal geology require chemical data to aid in interpretation for better understanding of the origin and evolution of peat and coal. Second, coal quality assessment is based largely on composition data, and these data generate useful insights into the geologic factors that control the quality of coal. Third, compositional data are needed for effective utilization of coal resources and to reflect the recent emphasis on both basic research in coal geochemistry and environmental aspects related to coal utilization.

  9. High-pressure coal fuel processor development

    SciTech Connect (OSTI)

    Greenhalgh, M.L. (Caterpillar, Inc., Peoria, IL (United States))

    1992-12-01

    Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. Two overall conclusions resulted from Task 1. First direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risk associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept. The significant conclusions from Task 2 were: An engine concept, derived from a Caterpillar 3600 series engine, and a fuel processor concept, based on scaling up a removable-canister configuration from the test rig, appear feasible; and although the results of this concept study are encouraging, further, full-scale component research and development are required before attempting a full-scale integrated system demonstration effort.

  10. Cyclic flow underground coal gasification process

    DOE Patents [OSTI]

    Bissett, Larry A. (Morgantown, WV)

    1978-01-01

    The present invention is directed to a method of in situ coal gasification for providing the product gas with an enriched concentration of carbon monoxide. The method is practiced by establishing a pair of combustion zones in spaced-apart boreholes within a subterranean coal bed and then cyclically terminating the combustion in the first of the two zones to establish a forward burn in the coal bed so that while an exothermic reaction is occurring in the second combustion zone to provide CO.sub.2 -laden product gas, an endothermic CO-forming reaction is occurring in the first combustion zone between the CO.sub.2 -laden gas percolating thereinto and the hot carbon in the wall defining the first combustion zone to increase the concentration of CO in the product gas. When the endothermic reaction slows to a selected activity the roles of the combustion zones are reversed by re-establishing an exothermic combustion reaction in the first zone and terminating the combustion in the second zone.

  11. THE ECONOMICAL PRODUCTION OF ALCOHOL FUELS FROM COAL-DERIVED SYNTHESIS GAS. Includes quarterly technical progress report No.25 from 10/01/1997-12/31/1997, and quarterly technical progress report No.26 from 01/01/1998-03/31/1998

    SciTech Connect (OSTI)

    1999-03-01

    This project was divided into two parts. One part evaluated possible catalysts for producing higher-alcohols (C{sub 2} to C{sub 5+}) as fuel additives. The other part provided guidance by looking both at the economics of mixed-alcohol production from coal-derived syngas and the effect of higher alcohol addition on gasoline octane and engine performance. The catalysts studied for higher-alcohol synthesis were molybdenum sulfides promoted with potassium. The best catalysts produced alcohols at a rate of 200 g/kg of catalyst/h. Higher-alcohol selectivity was over 40%. The hydrocarbon by-product was less than 20%. These catalysts met established success criteria. The economics for mixed alcohols produced from coal were poor compared to mixed alcohols produced from natural gas. Syngas from natural gas was always less expensive than syngas from coal. Engine tests showed that mixed alcohols added to gasoline significantly improved fuel quality. Mixed-alcohols as produced by our catalysts enhanced gasoline octane and decreased engine emissions. Mixed-alcohol addition gave better results than adding individual alcohols as had been done in the 1980's when some refiners added methanol or ethanol to gasoline.

  12. PressurePressure Indiana Coal Characteristics

    E-Print Network [OSTI]

    Fernández-Juricic, Esteban

    TimeTime PressurePressure · Indiana Coal Characteristics · Indiana Coals for Coke · Coal Indiana Total Consumption Electricity 59,664 Coke 4,716 Industrial 3,493 Major Coal- red power plantsTransportation in Indiana · Coal Slurry Ponds Evaluation · Site Selection for Coal Gasification · Coal-To-Liquids Study, CTL

  13. Underground coal gasification using oxygen and steam

    SciTech Connect (OSTI)

    Yang, L.H.; Zhang, X.; Liu, S. [China University of Mining & Technology, Xuzhou (China)

    2009-07-01

    In this paper, through model experiment of the underground coal gasification, the effects of pure oxygen gasification, oxygen-steam gasification, and moving-point gasification methods on the underground gasification process and gas quality were studied. Experiments showed that H{sub 2} and CO volume fraction in product gas during the pure oxygen gasification was 23.63-30.24% and 35.22-46.32%, respectively, with the gas heating value exceeding 11.00 MJ/m{sup 3}; under the oxygen-steam gasification, when the steam/oxygen ratio stood at 2: 1, gas compositions remained virtually stable and CO + H{sub 2} was basically between 61.66 and 71.29%. Moving-point gasification could effectively improve the changes in the cavity in the coal seams or the effects of roof inbreak on gas quality; the ratio of gas flowing quantity to oxygen supplying quantity was between 3.1:1 and 3.5:1 and took on the linear changes; on the basis of the test data, the reasons for gas quality changes under different gasification conditions were analyzed.

  14. Aqueous coal slurry

    SciTech Connect (OSTI)

    Berggren, Mark H.; Smit, Francis J.; Swanson, Wilbur W.

    1993-04-06

    An aqueous slurry containing coal and dextrin as a dispersant. The slurry, in addition to containing dextrin, may contain a conventional dispersant or, alternatively, a pH controlling reagent.

  15. Aqueous coal slurry

    DOE Patents [OSTI]

    Berggren, Mark H. (Golden, CO); Smit, Francis J. (Arvada, CO); Swanson, Wilbur W. (Golden, CO)

    1993-01-01

    An aqueous slurry containing coal and dextrin as a dispersant. The slurry, in addition to containing dextrin, may contain a conventional dispersant or, alternatively, a pH controlling reagent.

  16. Clean Coal Technology (Indiana)

    Broader source: Energy.gov [DOE]

    A public utility may not use clean coal technology at a new or existing electric generating facility without first applying for and obtaining from the Utility Regulatory Commission a certificate...

  17. Quarterly coal report

    SciTech Connect (OSTI)

    Young, P.

    1996-05-01

    The Quarterly Coal Report (QCR) provides comprehensive information about U.S. coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for October through December 1995 and aggregated quarterly historical data for 1987 through the third quarter of 1995. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  18. Method for coal liquefaction

    DOE Patents [OSTI]

    Wiser, W.H.; Oblad, A.G.; Shabtai, J.S.

    1994-05-03

    A process is disclosed for coal liquefaction in which minute particles of coal in intimate contact with a hydrogenation catalyst and hydrogen arc reacted for a very short time at a temperature in excess of 400 C at a pressure of at least 1500 psi to yield over 50% liquids with a liquid to gaseous hydrocarbon ratio in excess of 8:1. 1 figures.

  19. Coal liquefaction process

    DOE Patents [OSTI]

    Skinner, Ronald W. (Allentown, PA); Tao, John C. (Perkiomenville, PA); Znaimer, Samuel (Vancouver, CA)

    1985-01-01

    This invention relates to an improved process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal. The claimed improved process includes the hydrocracking of the light SRC mixed with a suitable hydrocracker solvent. The recycle of the resulting hydrocracked product, after separation and distillation, is used to produce a solvent for the hydrocracking of the light solvent refined coal.

  20. Trace elements in coal by glow discharge mass spectrometry

    SciTech Connect (OSTI)

    Jacobs, M.L.; Wilson, C.R.; Pestovich, J. Jr.

    1995-08-01

    A need and a demand exist for determining trace elements in coal and coal related by-products, especially those elements which may potentially be a health hazard. The provisions of the 1990 clean air act require that the EPA evaluate the emissions of electric utilities for trace elements and other potentially hazardous organic compounds. The coal fired electric utility industry supplies roughly 60% of the total generating capacity of 2,882,525 million kilowatt hours (nearly 3 trillion kilowatt hours) generated in the U.S. This is accomplished by 414 power plants scattered across the country that burned 813,508,000 short tons of coal in 1993. The relative volatility of some inorganic constituents in coal makes them more prone to be emitted to the atmosphere following combustion. The production of analytical data for trace elements is known to be a difficult task in coal and by-products of coal combustion (fly ash, bottom ash, gas streams, etc.), in terms of both sample collection and analytical determinations. There are several common analytical methods available to the analyst to determine trace elements in coal and coal by-products. In general analytical germs, the material to be analyzed can be totally solubilized (or extracted), or the elements analytes can be determined in the material as a solid. A relatively new elemental technique, Glow Discharge Mass Spectrometry (GDMS) can be used with solids as well. This new analytical technique had never before been applied directly to coal. The radio frequency-glow discharge quadropole mass spectrometer was used to analyze coal directly for the first time ever by rf-GDMS. The rf-GDMS technique is described.

  1. Calderon coal gasification Process Development Unit design and test program

    SciTech Connect (OSTI)

    Calderon, A.; Madison, E.; Probert, P.

    1992-01-01

    The Process Development Unit (PDU) was designed and constructed to demonstrate the novel Calderon gasification/hot gas cleanup process. in the process, run-of-mine high sulfur coal is first pyrolyzed to recover a rich gas (medium Btu gas), after which the resulting char is subjected to airblown gasification to yield a lean gas (low Btu gas). The process incorporates a proprietary integrated system for the conversion of coal to gases and for the hot cleanup of the gases which removes both particulate and sulfur components of the gaseous products. The yields are: a syngas (CO and H[sub 2] mix) suitable for further conversion to liquid fuel (e.g. methanol/gasoline), and a lean gas suitable to fuel the combustion turbine of a combined cycle power generation plant with very low levels of NO[sub x] (15 ppmv). The fused slag (from the gasified char ash content) and the sulfur recovered during the hot gas cleanup will be sold as by-products. The small quantity of spent sorbent generated will be combined with the coal feed as a fluxing agent for the slag. The small quantity of wastewater from slag drainings and steam generation blowdown will be mixed with the coal feed for disposal. The Calderon gasification/hot gas cleanup, which is a completely closed system, operates at a pressure suitable for combined cycle power generation.

  2. Calderon coal gasification Process Development Unit design and test program

    SciTech Connect (OSTI)

    Calderon, A.; Madison, E.; Probert, P.

    1992-11-01

    The Process Development Unit (PDU) was designed and constructed to demonstrate the novel Calderon gasification/hot gas cleanup process. in the process, run-of-mine high sulfur coal is first pyrolyzed to recover a rich gas (medium Btu gas), after which the resulting char is subjected to airblown gasification to yield a lean gas (low Btu gas). The process incorporates a proprietary integrated system for the conversion of coal to gases and for the hot cleanup of the gases which removes both particulate and sulfur components of the gaseous products. The yields are: a syngas (CO and H{sub 2} mix) suitable for further conversion to liquid fuel (e.g. methanol/gasoline), and a lean gas suitable to fuel the combustion turbine of a combined cycle power generation plant with very low levels of NO{sub x} (15 ppmv). The fused slag (from the gasified char ash content) and the sulfur recovered during the hot gas cleanup will be sold as by-products. The small quantity of spent sorbent generated will be combined with the coal feed as a fluxing agent for the slag. The small quantity of wastewater from slag drainings and steam generation blowdown will be mixed with the coal feed for disposal. The Calderon gasification/hot gas cleanup, which is a completely closed system, operates at a pressure suitable for combined cycle power generation.

  3. Measurement of Oil and Gas Emissions from a Marine Seep

    E-Print Network [OSTI]

    Leifer, Ira; Boles, J R; Luyendyk, B P

    2007-01-01

    hydrocarbon seeps near Coal Oil Point, California, Marineet al. , 2007, Measurement of Oil and Gas Emissions from aand P.G. Mikolaj, Natural oil seepage at Coal Oil Point,

  4. Isolation and identification of fatty acid amides from Shengli coal

    SciTech Connect (OSTI)

    Ming-Jie Ding; Zhi-Min Zong; Ying Zong; Xiao-Dong Ou-Yang; Yao-Guo Huang; Lei Zhou; Feng Wang; Jiang-Pei Cao; Xian-Yong Wei

    2008-07-15

    Shengli coal, a Chinese brown coal, was extracted with carbon disulfide and the extract was gradiently eluted with n-hexane and ethyl acetate (EA)/n-hexane mixed solvents with different concentrations of EA in a silica gel-filled column. A series of fatty acid amides, including fourteen alkanamides (C{sub 15}-C{sub 28}) and three alkenamides (C{sub 18} and C{sub 22}), were isolated from the coal by this method and analyzed with a gas chromatography/mass spectrometry. 26 refs., 2 figs., 2 tabs.

  5. U.S. Energy Information Administration | Annual Coal Report 2013

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969 1.979Coal Consumers in the ManufacturingCoal Production andCoal

  6. WEAR RESISTANT ALLOYS FOR COAL HANDLING EQUIPMENT

    E-Print Network [OSTI]

    Bhat, M.S.

    2011-01-01

    Proceedings of the Conference on Coal Feeding Systems, HeldWear Resistant Alloys for Coal Handling Equipment", proposalWear Resistant Alloys for Coal Handling Equi pment". The

  7. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    mines in China lowers the coal recovery rate and increasesthat China’s average coal recovery rate is 30% nationallyimproved aggregate coal recovery rates and local- scale

  8. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    of deploying advanced coal power in the Chinese context,”12 2.6. International coal prices and12 III. Chinese Coal

  9. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    of Figures Figure ES-1. Advanced Coal Wind Hybrid: Basicviii Figure 1. Advanced-Coal Wind Hybrid: Basic29 Figure 9. Sensitivity to Coal

  10. Coal Gasification and Transportation Fuels Magazine

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal Gasification and Transportation Fuels Magazine Current Edition: Coal Gasification and Transportation Fuels Quarterly News, Vol.1, Issue 4 (July 2015) Archived Editions: Coal...

  11. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    19 3.4. Coking coal for iron & steels FOB export value for coking coal was relatively stables FOB export value for coking coal significantly increased

  12. Decaking of coal or oil shale during pyrolysis in the presence of iron oxides

    DOE Patents [OSTI]

    Khan, M. Rashid (Morgantown, WV)

    1989-01-01

    A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis.

  13. Decaking of coal or oil shale during pyrolysis in the presence of iron oxides

    DOE Patents [OSTI]

    Rashid Khan, M.

    1988-05-05

    A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere is described. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis. 4 figs., 8 tabs.

  14. REFINING AND END USE STUDY OF COAL LIQUIDS

    SciTech Connect (OSTI)

    Unknown

    2002-01-01

    This document summarizes all of the work conducted as part of the Refining and End Use Study of Coal Liquids. There were several distinct objectives set, as the study developed over time: (1) Demonstration of a Refinery Accepting Coal Liquids; (2) Emissions Screening of Indirect Diesel; (3) Biomass Gasification F-T Modeling; and (4) Updated Gas to Liquids (GTL) Baseline Design/Economic Study.

  15. Coal combustion products 2007 production and use report

    SciTech Connect (OSTI)

    2009-07-01

    The American Coal Ash Association's 2007 Annual Coal Combustion Products (CCP) are derived from data from more than 170 power plants. The amount of CCPs used was 40.55%, a decrease of 2.88% from 2006, attributed to reduced fuel burn and a decrease in demand in the building industry. Figures are given for the production of fly ash, flue gas desulfurization gypsum, bottom ash, FBC ash and boiler slag. The article summarises results of the survey. 1 ref., 1 tab.

  16. Process for thermal hydrocracking of coal

    SciTech Connect (OSTI)

    Yamashita, K.; Kimura, M.

    1983-11-01

    A process for liquefying and gasifying coal by thermal treatment in the presence of hydrogen gas for hydrocracking is disclosed. The process comprises a sequence of the following two steps: (1) coal fines are injected into a heated hydrogen gas stream at a pressure of from 35 to 250 kg/cm G such that they are rapidly heated to a temperature of from 750/sup 0/ to 1100/sup 0/ C. for thermal cracking thereof; and (2) the resulting liquid product is subjected to hydrocracking for a period of from 1.0 to 60 seconds at a temperature that is lower than the temperature used in the first step and which is in the range of from 570/sup 0/ to 850/sup 0/ C.

  17. Mercury emission control for coal fired power plants using coal and biomass 

    E-Print Network [OSTI]

    Arcot Vijayasarathy, Udayasarathy

    2009-05-15

    + Oxidized Mercury HgP Particulate Mercury HgCl2 Mercuric chloride HCl Hydrogen chloride Sep. Sol. Separated Solids HA High Ash PC Partially Composted DB Dairy Biomass TXL Texas Lignite Coal WYC Wyoming Subbituminous Coal HHV Higher Heating.... ? Oxidized mercury (Hg2+) ? normally exist in gas phase, and can be captured by wet FGD type of units, since they are highly soluble in water. ? Mercury in particulate form (HgP) ? exist in solid phase and can be easily captured at traditional particulate...

  18. Coal-Fired Fluidized Bed Combustion Cogeneration 

    E-Print Network [OSTI]

    Thunem, C.; Smith, N.

    1985-01-01

    BED COMBUSTION COGENERATION Cabot Thunem, P.E Norm Smith, P.E. Stanley Consultants, Inc. Muscatine, Iowa ABSTRACT The availability of an environmentally accep table multifuel technology, such as fluidized bed combustion, has encouraged many... steam producers/ users to investigate switching from oil or gas to coal. Changes in federal regulations encouraging cogeneration have further enhanced the economic incentives for primary fuel switching. However, this addition of cogeneration...

  19. Coal within a revised energy perspective

    SciTech Connect (OSTI)

    Darmstadter, J. [Resources for the Future (RFF), Washington, DC (United States)

    2006-07-15

    The author considers the use of coal within a revised energy perspective, focusing on the factors that will drive which fuels are used to generate electricity going forward. He looks at the world markets for fossil fuels and the difficulties of predicting oil and natural gas supply and prices, as demonstrated by the variability in projections from one year to another in the EIA's Annual Energy Outlook. 4 refs., 1 tab.

  20. Solvent extraction of bituminous coals using light cycle oil: characterization of diaromatic products in liquids

    SciTech Connect (OSTI)

    Josefa M. Griffith; Caroline E. Burgess Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States). EMS Energy Institute

    2009-09-15

    Many studies of the pyrolytic degradation of coal-derived and petroleum-derived aviation fuels have demonstrated that the coal-derived fuels show better thermal stability, both with respect to deposition of carbonaceous solids and cracking to gases. Much previous work at our institute has focused on the use of refined chemical oil (RCO), a distillate from the refining of coal tar, blended with light cycle oil (LCO) from catalytic cracking of vacuum gas oil. Hydroprocessing of this blend forms high concentrations of tetralin and decalin derivatives that confer particularly good thermal stability on the fuel. However, possible supply constraints for RCO make it important to consider alternative ways to produce an 'RCO-like' product from coal in an inexpensive process. This study shows the results of coal extraction using LCO as a solvent. At 350{sup o}C at a solvent-to-coal ratio of 10:1, the conversions were 30-50 wt % and extract yields 28-40 wt % when testing five different coals. When using lower LCO/coal ratios, conversions and extract yields were much smaller; lower LCO/coal ratios also caused mechanical issues. LCO is thought to behave similarly to a nonpolar, non-hydrogen donor solvent, which would facilitate heat-induced structural relaxation of the coal followed by solubilization. The main components contributed from the coal to the extract when using Pittsburgh coal are di- and triaromatic compounds. 41 refs., 3 figs., 12 tabs.

  1. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01

    of coal sulfur K-T gasification process SRC I process U. S.flow sheet of a K-T coal gasification complex for producingProduction via K-T Gasification" © CEP Aug. 78. Feed

  2. Successful so far, coal lobby's campaign may run out of steam

    SciTech Connect (OSTI)

    2009-05-15

    The anti-coal lobby has mounted a highly successful campaign that has brought the permitting, financing, and construction of new conventional coal-fired plants to a virtual halt. But the coal lobby is not yet ready to concede defeat. With powerful constituents in coal-mining and coal-burning states and influential utilities, mining companies, and railroads, it continues to fight for its survival using any and all gimmicks and scare tactics in the book. The battle is being waged in courtrooms, public forums, media campaigns, and especially in Congress. The problem with the coal lobby is that it refuses to admit that coal combustion to generate electricity is among the chief sources of U.S. greenhouse gas emissions; unless they address this issue honestly, effectively, and immediately, their efforts are going to win few converts in the courts of law or public opinion.

  3. Solvent refined coal (SRC) process. Annual technical progress report, January 1979-December 1979

    SciTech Connect (OSTI)

    Not Available

    1980-11-01

    This report discusses the effects on SRC yields of seven process variables (reactor temperature, SRT, hydrogen partial pressure, recycle ash and coal concentrations, gas velocity and coal type) predicted by second-order regression models developed from a data base containing pilot plant data with both Kentucky and Powhatan coals. The only effect of coal type in the model is a shift in each yield by a constant factor. Although some differences were found between the models developed from the Kentucky data base (1) (which we call Kentucky models) and the pooled coal models, the general conclusions of the previous report are confirmed by the new models and the assumption of similar behavior of the two coals appears to be justified. In some respects the dependence of the yields (MAF coal basis) on variables such as pressure and temperature are clearer than in the previous models. The principal trends which emerge are discussed.

  4. Hydrocracking catalysts from coals

    SciTech Connect (OSTI)

    Farcasiu, M.; Petrosius, S.C.; Pladner, E. [USDOE Pittsburgh Energy Technology Center, PA (United States); Derbyshire, F.; Jagtoyen, M. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    1994-12-31

    In previous work at PETC it was shown that carbon blacks and carbonized polymers could be active and selective catalysts in hydrocracking reactions of interest for fossil fuels processing. Work at CAER for the production of various activated carbons from coals have shown that the properties of the materials could be varied if they are produced under different conditions. The authors will report work to optimize the catalytic properties of some coal based carbon materials prepared at CAER. One of the most promising materials for this purpose is obtained from an Illinois bituminous coal. The procedure hydroxide solution with coal and reacting in two stages; (1) heat treatment of the solution at 75 C under nitrogen for one hour followed by drying and (2) heat treatment at 400--1,100 C followed by leaching to remove KOH. The product was extensively characterized and its catalytic activity was measured. The catalytic activity of some of the materials is comparable with other, more expensive carbon materials. The catalysts have potential use in upgrading petroleum heavy ends and coal liquefaction.

  5. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    2 Syngas (H2 + CO + CO2) Coal Gasifier coal Fuel Production/2 Syngas (H2 + CO + CO2) Coal Gasifier coal Fuel Production/this operational mode, the gasifiers and other parts of the

  6. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01

    pollution. With coal and liquid transport fuel deficits in26 3.6. Coal-to-liquids and coal-to-70 million tonnes and coal-to-liquids capacity reaches 60

  7. Carbon Emissions Primer Symposium on Greenhouse Gas andSymposium on Greenhouse Gas and

    E-Print Network [OSTI]

    feet (~26.2'x26.2'x26.2') 5 CO2 Content by Fuel Type (lbs of CO2 per Million Btu of Fuel) Coal Type (lbs of CO2 per Megawatt-hour of Power) Coal-fired generation Coal-fired generation Existing PNW Sectors, by Fuel Type Annual 2012Annual 2012 Millions of Metric Tons Fuel Type Coal 1,657 Natural Gas 1

  8. Coal Problems 1. Name two examples of clean coal technology and in what manner do they clean the coal?

    E-Print Network [OSTI]

    Bowen, James D.

    Coal Problems 1. Name two examples of clean coal technology and in what manner do they clean the coal? a. Coal Washing- Crushing coal then mixing it with a liquid to allow the impurities to settle. b burning coal altogether. With integrated gasification combined cycle (IGCC) systems, steam and hot

  9. Composition and properties of coals from the Yurty coal occurrence

    SciTech Connect (OSTI)

    N.G. Vyazova; L.N. Belonogova; V.P. Latyshev; E.A. Pisar'kova [Irkutsk State University, Irkutsk (Russia). Research Institute of Oil and Coal Chemistry and Synthesis

    2008-10-15

    Coals from the Yurty coal occurrence were studied. It was found that the samples were brown non-coking coals with low sulfur contents (to 1%) and high yields of volatile substances. The high heat value of coals was 20.6-27.7 MJ/kg. The humic acid content varied from 5.45 to 77.62%. The mineral matter mainly consisted of kaolinite, a-quartz, and microcline. The concentration of toxic elements did not reach hazardous values.

  10. Coal News and Markets - Energy Information Administration

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet)DecadeYearEnergy InformationSign upAnnual Energynatural gasInternshipsBrowserCoal

  11. Quarterly Coal Report - Energy Information Administration

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming Dry Natural Gas Reserves AdjustmentsDecadeSign063 2.028Year:PressCoal

  12. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01

    application of new clean coal technologies with near zeroapplication of new clean coal technologies with near zero

  13. Characterisation of an oxy-coal flame through digital imaging

    SciTech Connect (OSTI)

    Smart, John; Riley, Gerry [RWE npower plc, Windmill Hill Business Park, Whitehill Way, Swindon SN5 6PB (United Kingdom); Lu, Gang; Yan, Yong [Instrumentation, Control and Embedded Systems Research Group, School of Engineering and Digital Arts, University of Kent, Canterbury, Kent CT2 7NT (United Kingdom)

    2010-06-15

    This paper presents investigations into the impact of oxy-fuel combustion on flame characteristics through the application of digital imaging and image processing techniques. The characteristic parameters of the flame are derived from flame images that are captured using a vision-based flame monitoring system. Experiments were carried out on a 0.5 MW{sub th} coal combustion test facility. Different flue gas recycle ratios and furnace oxygen levels were created for two different coals. The characteristics of the flame and the correlation between the measured flame parameters and corresponding combustion conditions are described and discussed. The results show that the flame temperature decreases with the recycle ratio for both test coals, suggesting that the flame temperature is effectively controlled by the flue gas recycle ratio. The presence of high levels of CO{sub 2} at high flue gas recycle ratios may result in delayed combustion and thus has a detrimental effect on the flame stability. (author)

  14. Coal and Coal-Biomass to Liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAuditsCluster Compatibility Mode Cluster CompatibilityCoal Markets

  15. Particulate control for low rank coals

    SciTech Connect (OSTI)

    Touzel, R.McD.

    1993-12-31

    The power generating system in Victoria currently comprises a total capacity of 6650 MW. Eighty percent of this capacity consists of base load stations in the Latrobe Valley using brown coal. The Latrobe Valley brown coals have unique characteristics with high moisture content ranging from 58 percent to 70 percent and an ash content which is relatively low but very variable in nature. These and other factors associated with the coal have caused special problems in handling and combustion of the coal and the de-dusting of the boiler flue gases. In recent years, this has been the basis for the design parameters adopted for all the plants in the system. With respect to flue gas de-dusting, the SECV has carried out extensive laboratory studies to characterize the different ashes obtained from the Latrobe Valley brown coals, including precipitability and aerodynamic tests. It also carried out full-scale tests on operating plants and pilot tests have been conducted on inertial collectors, precipitators and bag filters. The Environmental Protection Authority of Victoria has established a particulate emission level of 0.150 grams/m{sup 3} n.t.p. dry for recent Latrobe Valley boilers. However, the mandated emission level takes into account wide variations in operating conditions, and the plants normally achieve much lower emission levels. The Latrobe Valley plants presently in operation include Yallourn W (2x350 MW + 2x375 MW), Morwell (170 MW total and briquette factory), Hazelwood (8x200 MW) and Loy Yang (4x500 MW). The Yalloum W boilers are supplied with coal from the Yalloum Open Cut, the Morwell and Hazelwood boilers from the Morwell Open Cut and Loy Yang boilers from the Loy Yang Open Cut. All boilers are pulverized coal fired (PCF) and incorporate special firing equipment to enable the as-mined wet coal to be fired directly into the furnaces. All boilers are fitted with electrostatic precipitators. The locations of the stations and open cuts are shown.

  16. Healy Clean Coal Project

    SciTech Connect (OSTI)

    None

    1997-12-31

    The Healy Clean Coal Project, selected by the U.S. Department of Energy under Round 111 of the Clean Coal Technology Program, has been constructed and is currently in the Phase 111 Demonstration Testing. The project is owned and financed by the Alaska Industrial Development and Export Authority (AIDEA), and is cofunded by the U.S. Department of Energy. Construction was 100% completed in mid-November of 1997, with coal firing trials starting in early 1998. Demonstration testing and reporting of the results will take place in 1998, followed by commercial operation of the facility. The emission levels of nitrogen oxides (NOx), sulfur dioxide (S02), and particulate from this 50-megawatt plant are expected to be significantly lower than current standards.

  17. Resinous binders for coal and chars

    SciTech Connect (OSTI)

    Olson, E.S.; Sharma, R.K.; Young, B.C.

    1995-12-31

    Binder development and application to the briquetting or pelleting of coal fines has been extensive. The search for low-cost, effective binders for making strong and durable briquettes or pellets continues unabated. Strong, durable compacts are required, not only for handling, transport, and storage of the product but also to withstand the rigors of application such as flue gas treatment sorbents and catalytic supports. Many kinds of binders, organic and inorganic, have been used to gain the desired strength. Synthetic polymers have been investigated because they promote good strength and water insolubility, but these features are generally outweighed by the polymer cost. Promising earlier developments of biomass-derived binders have received slow market acceptance, mainly because of the cost resulting from the high concentrations required. However, recent advances in processing lignocellulosic materials have generated potentially low-cost polymeric binding agents for making coal briquettes. Phenol novolaks were previously used with lignites to make activated carbons. Recently, binders were prepared from mixtures of phenol, lignin, and formaldehyde and used for wood flour molding and friction materials. The goal of our work was to investigate the characteristics of resinous binders from lignocellulosic as well as coal-derived materials when used with dried or beneficiated coals and chars.

  18. Coal based electric generation comparative technologies report

    SciTech Connect (OSTI)

    Not Available

    1989-10-26

    Ohio Clean Fuels, Inc., (OCF) has licensed technology that involves Co-Processing (Co-Pro) poor grade (high sulfur) coal and residual oil feedstocks to produce clean liquid fuels on a commercial scale. Stone Webster is requested to perform a comparative technologies report for grassroot plants utilizing coal as a base fuel. In the case of Co-Processing technology the plant considered is the nth plant in a series of applications. This report presents the results of an economic comparison of this technology with other power generation technologies that use coal. Technologies evaluated were:Co-Processing integrated with simple cycle combustion turbine generators, (CSC); Co-Processing integrated with combined cycle combustion turbine generators, (CCC); pulverized coal-fired boiler with flue gas desulfurization and steam turbine generator, (PC) and Circulating fluidized bed boiler and steam turbine generator, (CFB). Conceptual designs were developed. Designs were based on approximately equivalent net electrical output for each technology. A base case of 310 MWe net for each technology was established. Sensitivity analyses at other net electrical output sizes varying from 220 MWe's to 1770 MWe's were also performed. 4 figs., 9 tabs.

  19. Eastman, AP start on coal unit

    SciTech Connect (OSTI)

    1995-10-25

    Eastman Chemical and Air Products and Chemicals (AP) have started construction of a $214-million, coal-to-methanol demonstration unit at Eastmans site in Kingsport, TN. The project is part of the Department of Energy`s clean coal technology program and is receiving $93 million in federal support. The demonstration unit-which will have a methanol capacity of 260 tons/day-will use novel catalyst technology for converting coal-derived synthesis gas (syngas) to methanol. Unlike conventional technology that processes syngas through a fixed bed of dry catalyst particles, the liquid-phase methanol process converts the syngas in a single vessel containing catalysts suspended in mineral oil. The companies say the innovation allows the process to better able handle the gases from coal gasifiers and is more stable and reliable than existing processes. Eastman says it will use the methanol produced by the plant as a chemical feedstock. It currently uses methanol as an intermediate in making acetic anhydride and dimethyl terephthalate. In addition, the companies say the methanol will be evaluated as a feedstock in making methyl tert-butyl ether for reformulated fuels. Eastman also says it will evaluate coproducing dimethyl ether (DME) with the methanol. DME can be used as a fuel additive or blended with methanol for a chemical feedstock, according to Eastman.

  20. OVERLAY COATINGS FOR GAS TURBINE AIRFOILS

    E-Print Network [OSTI]

    Boone, Donald H.

    2013-01-01

    Materials Coating Techniques." OVERLAY COATINGS FOR GAS TURBINEGas Turbine Coatings for Minimally Processed Coal Derived Liquid Fuels," presented at the Conference on Advanced MaterialsCoating Technology and Processing Capabilities,'' proceedings 3rd Conference on Gas Turbine Materials

  1. Dry cleaning of Turkish coal

    SciTech Connect (OSTI)

    Cicek, T. [Dokuz Eylul University, Izmir (Turkey). Faculty of Engineering

    2008-07-01

    This study dealt with the upgrading of two different type of Turkish coal by a dry cleaning method using a modified air table. The industrial size air table used in this study is a device for removing stones from agricultural products. This study investigates the technical and economical feasibility of the dry cleaning method which has never been applied before on coals in Turkey. The application of a dry cleaning method on Turkish coals designated for power generation without generating environmental pollution and ensuring a stable coal quality are the main objectives of this study. The size fractions of 5-8, 3-5, and 1-3 mm of the investigated coals were used in the upgrading experiments. Satisfactory results were achieved with coal from the Soma region, whereas the upgrading results of Hsamlar coal were objectionable for the coarser size fractions. However, acceptable results were obtained for the size fraction 1-3 mm of Hsamlar coal.

  2. The world price of coal

    E-Print Network [OSTI]

    Ellerman, A. Denny

    1994-01-01

    A significant increase in the seaborne trade for coal over the past twenty years has unified formerly separate coal markets into a world market in which prices move in tandem. Due to its large domestic market, the United ...

  3. 2009 Coal Age Buyers Guide

    SciTech Connect (OSTI)

    2009-07-15

    The buyers guide lists more than 1200 companies mainly based in the USA, that provide equipment and services to US coal mines and coal preparation plants. The guide is subdivided by product categories.

  4. 2008 Coal Age buyers guide

    SciTech Connect (OSTI)

    2008-07-15

    The buyers guide lists more than 1200 companies mainly based in the USA, that provide equipment and services to US coal mines and coal preparation plants. The guide is subdivided by product categories.

  5. Low-rank coal research

    SciTech Connect (OSTI)

    Weber, G. F.; Laudal, D. L.

    1989-01-01

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  6. (Basic properties of coals and other solids)

    SciTech Connect (OSTI)

    Not Available

    1991-11-25

    This report discusses basic properties of bituminous, subbituminous, and lignite coals. Properties of coal liquids are also investigated. Heats of immersion in strong acids are found for Pittsburgh {number sign}8, Illinois {number sign}6, and Wyodak coals. Production of coal liquids by distillation is discussed. Heats of titration of coal liquids and coal slurries are reported. (VC)

  7. Underground coal gasification. Presentations

    SciTech Connect (OSTI)

    NONE

    2007-07-01

    The 8 presentations are: underground coal gasification (UCG) and the possibilities for carbon management (J. Friedmann); comparing the economics of UCG with surface gasification technologies (E. Redman); Eskom develops UCG technology project (C. Gross); development and future of UCG in the Asian region (L. Walker); economically developing vast deep Powder River Basin coals with UCG (S. Morzenti); effectively managing UCG environmental issues (E. Burton); demonstrating modelling complexity of environmental risk management; and UCG research at the University of Queensland, Australia (A.Y. Klimenko).

  8. Clean Coal Power Initiative

    SciTech Connect (OSTI)

    Doug Bartlett; Rob James; John McDermott; Neel Parikh; Sanjay Patnaik; Camilla Podowski

    2006-03-31

    This report is the fifth quarterly Technical Progress Report submitted by NeuCo, Incorporated, under Award Identification Number, DE-FC26-04NT41768. This award is part of the Clean Coal Power Initiative (''CCPI''), the ten-year, $2B initiative to demonstrate new clean coal technologies in the field. This report is one of the required reports listed in Attachment B Federal Assistance Reporting Checklist, part of the Cooperative Agreement. The report covers the award period January 1, 2006 - March 31, 2006 and NeuCo's efforts within design, development, and deployment of on-line optimization systems during that period.

  9. PNNL Coal Gasification Research

    SciTech Connect (OSTI)

    Reid, Douglas J.; Cabe, James E.; Bearden, Mark D.

    2010-07-28

    This report explains the goals of PNNL in relation to coal gasification research. The long-term intent of this effort is to produce a syngas product for use by internal Pacific Northwest National Laboratory (PNNL) researchers in materials, catalysts, and instrumentation development. Future work on the project will focus on improving the reliability and performance of the gasifier, with a goal of continuous operation for 4 hours using coal feedstock. In addition, system modifications to increase operational flexibility and reliability or accommodate other fuel sources that can be used for syngas production could be useful.

  10. Coal Research FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAuditsCluster Compatibility Mode Cluster CompatibilityCoal Markets ReleaseCoal

  11. CONSORTIUM FOR CLEAN COAL UTILIZATION

    E-Print Network [OSTI]

    Subramanian, Venkat

    1 CONSORTIUM FOR CLEAN COAL UTILIZATION Request for Proposals Date of Issue: February 16, 2015 The Consortium for Clean Coal Utilization (CCCU) at Washington University in St. Louis was established in January of 2009. The mission of the CCCU is to enable environmentally benign and sustainable use of coal, both

  12. CONSORTIUM FOR CLEAN COAL UTILIZATION

    E-Print Network [OSTI]

    Subramanian, Venkat

    CONSORTIUM FOR CLEAN COAL UTILIZATION Call for Proposals Date of Issue: July 29, 2013 The Consortium for Clean Coal Utilization (CCCU) at Washington University in St. Louis was established in January of Clean Coal Utilization. The format may be a conference or workshop, or a seminar given by a leading

  13. Coal Market Module - NEMS Documentation

    Reports and Publications (EIA)

    2014-01-01

    Documents the objectives and the conceptual and methodological approach used in the development of the National Energy Modeling System's (NEMS) Coal Market Module (CMM) used to develop the Annual Energy Outlook 2014 (AEO2014). This report catalogues and describes the assumptions, methodology, estimation techniques, and source code of CMM's two submodules. These are the Coal Production Submodule (CPS) and the Coal Distribution Submodule (CDS).

  14. Development of a pulse coal combustor for industrial applications

    SciTech Connect (OSTI)

    Not Available

    1990-10-31

    This report presents the results of the first phase of a program for the development of a retrofit pulse coal combustor for industrial applications. This phase was comprised of laboratory-scale (approximately 2 MMBtu/hr) combustor design optimization testing and the preparation of an integrated prototype combustor system design at approximately 3.5 to 5.0 MMBtu/hr scale for further development in Phase IA. The program objective was to develop an advanced pulse coal combustor system at the required scale that has high carbon utilization, high ash rejection, low flue gas emissions and low sensitivity to variations in fuels specifications. An optimized tandem advanced refractory chamber unit was designed and fabricate during October and November 1987. The unit logged approximately 100 hours of operation burning pulverized coals, micronized coals, coal-water slurries made of pulverized coal, and micronized coal. Sulfur capturing sorbents lime/limestone were injected into the combustor system to evaluate sulfur capturing efficiency. Staged air injections were also investigated. 42 figs., 16 tabs.

  15. Process for clean-burning fuel from low-rank coal

    DOE Patents [OSTI]

    Merriam, N.W.; Sethi, V.; Brecher, L.E.

    1994-06-21

    A process is described for upgrading and stabilizing low-rank coal involving the sequential processing of the coal through three fluidized beds; first a dryer, then a pyrolyzer, and finally a cooler. The fluidizing gas for the cooler is the exit gas from the pyrolyzer with the addition of water for cooling. Overhead gas from pyrolyzing is likely burned to furnish the energy for the process. The product coal exits with a tar-like pitch sealant to enhance its safety during storage. 1 fig.

  16. MOF stability and gas adsorption as a function of exposure to water, humid air, SO2, and NO2

    E-Print Network [OSTI]

    Nair, Sankar

    the burning of oil, coal, and natural gas [1]. Cur- rent technologies for capturing CO2 from these sources

  17. Formation of carbon deposits from coal in an arc plasma

    SciTech Connect (OSTI)

    Wang, B.; Tian, Y.; Zhang, Y.; Zhu, S.; Lu, Y.; Zhang, Y.; Xie, K.

    2007-07-01

    The issue of deposited carbon (DC) on a reactor wall during the production of acetylene by the coal/arc plasma process is a potential obstacle for the industrialization process. The formation mechanism of DC is very difficult to reveal because the high complexity of coal and the volatile matter. Combining with quenching technique, the methane, liquid petroleum gas and benzene were employed as the model materials to roughly act as the light gas, chain and aromatic subcomponents of volatile matter, and then the reasonable formation mechanism of DC was subtly speculated accordingly.

  18. Lignin-assisted coal depolymerization. Technical report, December 1, 1991--February 29, 1992

    SciTech Connect (OSTI)

    Lalvani, S.B.

    1992-08-01

    Previous research has shown that addition of lignin and lignin-derived liquids to coal stirred in tetralin under mild reaction conditions (375{degrees}C and 300--500 psig) results in a marked enhancement in the rate of coal depolymerization. In this quarterly report, overall mass balances on experiments conducted with tetralin, coal, lignin and coal-lignin mixture are reported. Overall mass recoveries of 95--99% of the total mass charged to the reactor were obtained. A number of experiments were conducted on coal, lignin and coal-lignin depolymerization. A careful statistical analysis of the data shows that coal depolymerization is enhanced by 10.4%, due to the lignin addition. The liquids obtained are being examined for their elemental composition, and molecular weight determination by size exclusion chromatography. The stability of the liquid products is being examined in various environments. The gaseous product analyses show that the major gases produced during the course of depolymerization are CO, CH{sub 4}, and CO{sub 2}. When coal and lignin are reacted together, the amount of CO and CH{sub 4}produced respectively 12% and 38% greater than the corresponding amount of gases calculated, based on the weighted average of values obtained for coal and lignin alone. The data obtained show that lignin addition to coal is synergistic in that not only is the extent of coal depolymerization increased, but the gas produced contains higher concentrations of more desirable gaseous products.

  19. Coal companies hope to receive carbon credits for methane reductions

    SciTech Connect (OSTI)

    2007-09-30

    Each year, underground coal mining in the USA liberates 2.4 million tonnes of coal mine methane (CMM), of which less than 30% is recovered and used. One barrier to CMM recovery is cost. Drainage, collection, and utilization systems are complex and expensive to install. Two coal mines have improved the cost equation, however, by signing on to earn money for CMM emissions they are keeping out of the atmosphere. Jim Walter Resources and PinnOak Resources have joined a voluntary greenhouse gas reduction trading program called the Chicago Climate Exchange (CCX) to turn their avoided emissions into carbon credits. The example they set may encourage other coal mining companies to follow suit, and may bring new projects on the line that would otherwise have not gone forward. 2 refs., 1 fig.

  20. Sixth clean coal technology conference: Proceedings. Volume 2: Technical papers

    SciTech Connect (OSTI)

    NONE

    1998-12-01

    The Sixth Clean Coal Technology Conference focused on the ability of clean coal technologies (CCTs) to meet increasingly demanding environmental requirements while simultaneously remaining competitive in both international and domestic markets. Conference speakers assessed environmental, economic, and technical issues and identified approaches that will help enable CCTs to be deployed in an era of competing, interrelated demands for energy, economic growth, and environmental protection. Recognition was given to the dynamic changes that will result from increasing competition in electricity and fuel markets and industry restructuring, both domestically and internationally. Volume 2 contains 28 papers related to fluidized-bed combustion, coal gasification for combined cycle power plants, the Liquid Phase Methanol Process, use of coal in iron making, air pollution control of nitrogen oxides, coke making, and hot gas cleanup.