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Sample records for gas sampling surface

  1. Surface Gas Sampling | Open Energy Information

    Open Energy Info (EERE)

    In The Past 20 Years- Geochemistry In Geothermal Exploration Resource Evaluation And Reservoir Management Surface Gas Sampling At Fenton Hill HDR Geothermal Area (Goff &...

  2. Category:Surface Gas Sampling | Open Energy Information

    Open Energy Info (EERE)

    Surface Gas Sampling Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Surface Gas Sampling page? For detailed information on Surface...

  3. Surface Gas Sampling At Lightning Dock Area (Norman, Et Al.,...

    Open Energy Info (EERE)

    Surface Gas Sampling At Lightning Dock Area (Norman, Et Al., 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Gas Sampling At...

  4. Surface Gas Sampling At Lightning Dock Area (Norman & Moore,...

    Open Energy Info (EERE)

    Surface Gas Sampling At Lightning Dock Area (Norman & Moore, 2004) (Redirected from Water-Gas Samples At Lightning Dock Area (Norman & Moore, 2004)) Jump to: navigation, search...

  5. Surface Gas Sampling At Lightning Dock Area (Norman, Et Al.,...

    Open Energy Info (EERE)

    Surface Gas Sampling At Lightning Dock Area (Norman, Et Al., 2002) (Redirected from Water-Gas Samples At Lightning Dock Area (Norman, Et Al., 2002)) Jump to: navigation, search...

  6. Surface Gas Sampling At Fenton Hill HDR Geothermal Area (Grigsby...

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Gas Sampling At Fenton Hill HDR Geothermal Area (Grigsby, Et Al., 1983) Exploration...

  7. Surface Gas Sampling At Lassen Volcanic National Park Area (Janik...

    Open Energy Info (EERE)

    Lassen Volcanic National Park Area (Janik & Mclaren, 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Gas Sampling At Lassen...

  8. Surface Gas Sampling At International Geothermal Area Mexico...

    Open Energy Info (EERE)

    International Geothermal Area Mexico (Norman, Et Al., 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Gas Sampling At International...

  9. Surface Gas Sampling At Valles Caldera - Sulphur Springs Area...

    Open Energy Info (EERE)

    Sulphur Springs Area (Goff & Janik, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Gas Sampling At Valles Caldera - Sulphur...

  10. Surface Gas Sampling At Fenton Hill HDR Geothermal Area (Goff...

    Open Energy Info (EERE)

    Goff & Janik, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Gas Sampling At Fenton Hill HDR Geothermal Area (Goff & Janik, 2002)...

  11. Surface Gas Sampling At Jemez Springs Area (Goff & Janik, 2002...

    Open Energy Info (EERE)

    Jemez Springs Area (Goff & Janik, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Gas Sampling At Jemez Springs Area (Goff & Janik,...

  12. Surface Gas Sampling At Yellowstone Region (Goff & Janik, 2002...

    Open Energy Info (EERE)

    Yellowstone Region (Goff & Janik, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Gas Sampling At Yellowstone Region (Goff & Janik,...

  13. Surface Gas Sampling At Valles Caldera - Redondo Area (Goff ...

    Open Energy Info (EERE)

    Redondo Area (Goff & Janik, 2002) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Gas Sampling At Valles Caldera - Redondo Area (Goff &...

  14. Surface Gas Sampling At Lightning Dock Area (Norman & Moore,...

    Open Energy Info (EERE)

    David I. Norman, Joseph Moore (2004) Gas Analysis Of Geothermal Fluid Inclusions- A New Technology For Geothermal Exploration Additional References Retrieved from "http:...

  15. Category:Gas Sampling | Open Energy Information

    Open Energy Info (EERE)

    Technique Subcategories This category has the following 3 subcategories, out of 3 total. G Gas Flux Sampling 1 pages S Soil Gas Sampling 1 pages Surface Gas...

  16. Gas Sampling | Open Energy Information

    Open Energy Info (EERE)

    of geothermometric calculations and geochemical modeling of the data. In the case of gas flux sampling, different measurement techniques and devices may disrupt or alter the...

  17. Water-Gas Sampling | Open Energy Information

    Open Energy Info (EERE)

    Water-Gas Sampling (Redirected from Water-Gas Samples) Redirect page Jump to: navigation, search REDIRECT Downhole Fluid Sampling Retrieved from "http:en.openei.orgw...

  18. Water-Gas Samples At Fenton Hill Hdr Geothermal Area (Goff &...

    Open Energy Info (EERE)

    Water-Gas Samples At Fenton Hill Hdr Geothermal Area (Goff & Janik, 2002) Redirect page Jump to: navigation, search REDIRECT Surface Gas Sampling At Fenton Hill Hdr Geothermal...

  19. Gas sampling system for reactive gas-solid mixtures

    DOE Patents [OSTI]

    Daum, Edward D.; Downs, William; Jankura, Bryan J.; McCoury, Jr., John M.

    1990-01-01

    An apparatus and method for sampling gas containing a reactive particulate solid phase flowing through a duct and for communicating a representative sample to a gas analyzer. A sample probe sheath 32 with an angular opening 34 extends vertically into a sample gas duct 30. The angular opening 34 is opposite the gas flow. A gas sampling probe 36 concentrically located within sheath 32 along with calibration probe 40 partly extends in the sheath 32. Calibration probe 40 extends further in the sheath 32 than gas sampling probe 36 for purging the probe sheath area with a calibration gas during calibration.

  20. Gas sampling system for reactive gas-solid mixtures

    DOE Patents [OSTI]

    Daum, Edward D.; Downs, William; Jankura, Bryan J.; McCoury, Jr., John M.

    1989-01-01

    An apparatus and method for sampling a gas containing a reactive particulate solid phase flowing through a duct and for communicating a representative sample to a gas analyzer. A sample probe sheath 32 with an angular opening 34 extends vertically into a sample gas duct 30. The angular opening 34 is opposite the gas flow. A gas sampling probe 36 concentrically located within sheath 32 along with calibration probe 40 partly extend in the sheath 32. Calibration probe 40 extends further in the sheath 32 than gas sampling probe 36 for purging the probe sheath area with a calibration gas during calibration.

  1. Shale Gas Development Challenges: Surface Impacts | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Surface Impacts Shale Gas Development Challenges: Surface Impacts Shale Gas Development Challenges: Surface Impacts (657.75 KB) More Documents & Publications Natural Gas from ...

  2. Gas sampling system for a mass spectrometer

    DOE Patents [OSTI]

    2003-12-30

    The present invention relates generally to a gas sampling system, and specifically to a gas sampling system for transporting a hazardous process gas to a remotely located mass spectrometer. The gas sampling system includes a capillary tube having a predetermined capillary length and capillary diameter in communication with the supply of process gas and the mass spectrometer, a flexible tube surrounding and coaxial with the capillary tube intermediate the supply of process gas and the mass spectrometer, a heat transfer tube surrounding and coaxial with the capillary tube, and a heating device in communication the heat transfer tube for substantially preventing condensation of the process gas within the capillary tube.

  3. Retained Gas Sampling Results for the Flammable Gas Program

    SciTech Connect (OSTI)

    J.M. Bates; L.A. Mahoney; M.E. Dahl; Z.I. Antoniak

    1999-11-18

    The key phenomena of the Flammable Gas Safety Issue are generation of the gas mixture, the modes of gas retention, and the mechanisms causing release of the gas. An understanding of the mechanisms of these processes is required for final resolution of the safety issue. Central to understanding is gathering information from such sources as historical records, tank sampling data, tank process data (temperatures, ventilation rates, etc.), and laboratory evaluations conducted on tank waste samples.

  4. Thermophoretic separation of aerosol particles from a sampled gas stream

    DOE Patents [OSTI]

    Postma, Arlin K.

    1986-01-01

    A method for separating gaseous samples from a contained atmosphere that includes aerosol particles uses the step of repelling particles from a gas permeable surface or membrane by heating the surface to a temperature greater than that of the surrounding atmosphere. The resulting thermophoretic forces maintain the gas permeable surface clear of aerosol particles. The disclosed apparatus utilizes a downwardly facing heated plate of gas permeable material to combine thermophoretic repulsion and gravity forces to prevent particles of any size from contacting the separating plate surfaces.

  5. Ball assisted device for analytical surface sampling

    SciTech Connect (OSTI)

    ElNaggar, Mariam S; Van Berkel, Gary J; Covey, Thomas R

    2015-11-03

    A system for sampling a surface includes a sampling probe having a housing and a socket, and a rolling sampling sphere within the socket. The housing has a sampling fluid supply conduit and a sampling fluid exhaust conduit. The sampling fluid supply conduit supplies sampling fluid to the sampling sphere. The sampling fluid exhaust conduit has an inlet opening for receiving sampling fluid carried from the surface by the sampling sphere. A surface sampling probe and a method for sampling a surface are also disclosed.

  6. Category:Soil Gas Sampling | Open Energy Information

    Open Energy Info (EERE)

    Soil Gas Sampling Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Soil Gas Sampling page? For detailed information on Soil Gas...

  7. Category:Gas Flux Sampling | Open Energy Information

    Open Energy Info (EERE)

    Gas Flux Sampling Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Gas Flux Sampling page? For detailed information on Gas Flux...

  8. Gas Flux Sampling | Open Energy Information

    Open Energy Info (EERE)

    the true flux of hydrothermal gases may affect the results of geochemical modeling of gas dispersion in the near-surface environment.3 References 1.0 1.1 Measuring...

  9. Gas Sampling At Wister Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gas Sampling At Wister Area (DOE GTP) (Redirected from Water-Gas Samples At Wister Area (DOE GTP)) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration...

  10. Gas Sampling At Wister Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gas Sampling At Wister Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Sampling At Wister Area (DOE GTP) Exploration Activity...

  11. Gas Sampling At Colrado Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gas Sampling At Colrado Area (DOE GTP) (Redirected from Water-Gas Samples At Colrado Area (DOE GTP)) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration...

  12. Gas Sampling At Colrado Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gas Sampling At Colrado Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Sampling At Colrado Area (DOE GTP) Exploration...

  13. Surface Water Sampling | Open Energy Information

    Open Energy Info (EERE)

    Surface Water Sampling Details Activities (3) Areas (2) Regions (0) NEPA(0) Exploration Technique Information Exploration Group: Field Techniques Exploration Sub Group: Field...

  14. Water-Gas Samples At Long Valley Caldera Area (Goff & Janik,...

    Open Energy Info (EERE)

    Area (Goff & Janik, 2002) Redirect page Jump to: navigation, search REDIRECT Surface Gas Sampling At Long Valley Caldera Area (Goff & Janik, 2002) Retrieved from "http:...

  15. Surface studies of plasma processed Nb samples

    SciTech Connect (OSTI)

    Tyagi, Puneet V; Doleans, Marc; Hannah, Brian S; Afanador, Ralph; Stewart, Stephen; Mammosser, John; Howell, Matthew P; Saunders, Jeffrey W; Degraff, Brian D; Kim, Sang-Ho

    2015-01-01

    Contaminants present at top surface of superconducting radio frequency (SRF) cavities can act as field emitters and restrict the cavity accelerating gradient. A room temperature in-situ plasma processing technology for SRF cavities aiming to clean hydrocarbons from inner surface of cavities has been recently developed at the Spallation Neutron Source (SNS). Surface studies of the plasma processed Nb samples by Secondary ion mass spectrometry (SIMS) and Scanning Kelvin Probe (SKP) showed that the NeO2 plasma processing is very effective to remove carbonaceous contaminants from top surface and improves the surface work function by 0.5 to 1.0 eV.

  16. Gas Flux Sampling (Evans, Et Al., 2001) | Open Energy Information

    Open Energy Info (EERE)

    show that gas samples collected by either sudden pre-evacuated container or gradual gas pump. Removal of tens of cm3 of gas through an access pipe appear to reflect steady-state...

  17. Gas Flux Sampling (Laney, 2005) | Open Energy Information

    Open Energy Info (EERE)

    in the near surface: Available technologies for monitoring CO2 in the near-surface environment include (1) the infrared gas analyzer (IRGA) for measurement of concentrations at...

  18. Gasbuggy, New Mexico, Hydrologic and Natural Gas Sampling and Analysis Results for 2009

    SciTech Connect (OSTI)

    2009-11-01

    The U.S. Department of Energy (DOE) Office of Legacy Management conducted hydrologic and natural gas sampling for the Gasbuggy, New Mexico, site on June 16, and 17, 2009. Hydrologic sampling consists of collecting water samples from water wells and surface water locations. Natural gas sampling consists of collecting both gas samples and samples of produced water from gas production wells. The water well samples were analyzed for gamma-emitting radionuclides and tritium. Surface water samples were analyzed for tritium. Water samples from gas production wells were analyzed for gamma-emitting radionuclides, gross alpha, gross beta, and tritium. Natural gas samples were analyzed for tritium and carbon-14. Water samples were analyzed by ALS Laboratory Group in Fort Collins, Colorado, and natural gas samples were analyzed by Isotech Laboratories in Champaign, Illinois. Concentrations of tritium and gamma-emitting radionuclides in water samples collected in the vicinity of the Gasbuggy site continue to demonstrate that the sample locations have not been impacted by detonation-related contaminants. Results from the sampling of natural gas from producing wells demonstrate that the gas wells nearest the Gasbuggy site are not currently impacted by detonation-related contaminants. Annual sampling of the gas production wells nearest the Gasbuggy site for gas and produced water will continue for the foreseeable future. The sampling frequency of water wells and surface water sources in the surrounding area will be reduced to once every 5 years. The next hydrologic sampling event at water wells, springs, and ponds will be in 2014.

  19. Rapid surface sampling and archival record system

    SciTech Connect (OSTI)

    Barren, E.; Penney, C.M.; Sheldon, R.B.

    1995-10-01

    A number of contamination sites exist in this country where the area and volume of material to be remediated is very large, approaching or exceeding 10{sup 6} m{sup 2} and 10{sup 6} m{sup 3}. Typically, only a small fraction of this material is actually contaminated. In such cases there is a strong economic motivation to test the material with a sufficient density of measurements to identify which portions are uncontaminated, so extensively they be left in place or be disposed of as uncontaminated waste. Unfortunately, since contamination often varies rapidly from position to position, this procedure can involve upwards of one million measurements per site. The situation is complicated further in many cases by the difficulties of sampling porous surfaces, such as concrete. This report describes a method for sampling concretes in which an immediate distinction can be made between contaminated and uncontaminated surfaces. Sample acquisition and analysis will be automated.

  20. Soil Gas Sampling | Open Energy Information

    Open Energy Info (EERE)

    "normal" background soil gas contents of a particular geothermal area. References Toxic Substances Hydrology Program 2.0 2.1 The Application of Soil-Gas Technique to...

  1. Surface sampling concentration and reaction probe

    DOE Patents [OSTI]

    Van Berkel, Gary J; Elnaggar, Mariam S

    2013-07-16

    A method of analyzing a chemical composition of a specimen is described. The method can include providing a probe comprising an outer capillary tube and an inner capillary tube disposed co-axially within the outer capillary tube, where the inner and outer capillary tubes define a solvent capillary and a sampling capillary in fluid communication with one another at a distal end of the probe; contacting a target site on a surface of a specimen with a solvent in fluid communication with the probe; maintaining a plug volume proximate a solvent-specimen interface, wherein the plug volume is in fluid communication with the probe; draining plug sampling fluid from the plug volume through the sampling capillary; and analyzing a chemical composition of the plug sampling fluid with an analytical instrument. A system for performing the method is also described.

  2. System and method for extracting a sample from a surface

    SciTech Connect (OSTI)

    Van Berkel, Gary; Covey, Thomas

    2015-06-23

    A system and method is disclosed for extracting a sample from a sample surface. A sample is provided and a sample surface receives the sample which is deposited on the sample surface. A hydrophobic material is applied to the sample surface, and one or more devices are configured to dispense a liquid on the sample, the liquid dissolving the sample to form a dissolved sample material, and the one or more devices are configured to extract the dissolved sample material from the sample surface.

  3. Category:Surface Water Sampling | Open Energy Information

    Open Energy Info (EERE)

    Surface Water Sampling Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Geothermalpower.jpg Looking for the Surface Water Sampling page? For detailed information on...

  4. Gas Flux Sampling At Steamboat Springs Area (Lechler And Coolbaugh...

    Open Energy Info (EERE)

    Steamboat Springs Area (Lechler And Coolbaugh, 2007) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Flux Sampling At Steamboat Springs Area...

  5. Gas Flux Sampling At Desert Peak Area (Lechler And Coolbaugh...

    Open Energy Info (EERE)

    Desert Peak Area (Lechler And Coolbaugh, 2007) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Flux Sampling At Desert Peak Area (Lechler And...

  6. Gas Flux Sampling At Lahaina-Kaanapali Area (Thomas, 1986) |...

    Open Energy Info (EERE)

    1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Flux Sampling At Lahaina-Kaanapali Area (Thomas, 1986) Exploration Activity Details...

  7. Gas Flux Sampling At Lualualei Valley Area (Thomas, 1986) | Open...

    Open Energy Info (EERE)

    1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Flux Sampling At Lualualei Valley Area (Thomas, 1986) Exploration Activity Details...

  8. Gas Flux Sampling At Kilauea East Rift Geothermal Area (Thomas...

    Open Energy Info (EERE)

    1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Flux Sampling At Kilauea East Rift Geothermal Area (Thomas, 1986) Exploration Activity...

  9. Gas Sampling At Maui Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Sampling At Maui Area (DOE GTP) Exploration Activity Details Location Maui Area...

  10. Gas Flux Sampling At Lightning Dock Area (Cunniff & Bowers, 2005...

    Open Energy Info (EERE)

    2005) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Flux Sampling At Lightning Dock Area (Cunniff & Bowers, 2005) Exploration Activity...

  11. Gas Flux Sampling At Mokapu Penninsula Area (Thomas, 1986) |...

    Open Energy Info (EERE)

    1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Flux Sampling At Mokapu Penninsula Area (Thomas, 1986) Exploration Activity Details...

  12. Soil Gas Sampling At Chena Geothermal Area (Kolker, 2008) | Open...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Soil Gas Sampling At Chena Geothermal Area (Kolker, 2008) Exploration Activity Details Location...

  13. Gas Flux Sampling At Hualalai Northwest Rift Area (Thomas, 1986...

    Open Energy Info (EERE)

    1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Flux Sampling At Hualalai Northwest Rift Area (Thomas, 1986) Exploration Activity...

  14. Gas Flux Sampling At Kawaihae Area (Thomas, 1986) | Open Energy...

    Open Energy Info (EERE)

    1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Flux Sampling At Kawaihae Area (Thomas, 1986) Exploration Activity Details Location...

  15. Water-Gas Samples At Valles Caldera - Redondo Geothermal Area...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water-Gas Samples At Valles Caldera - Redondo Geothermal Area (Janik & Goff, 2002)...

  16. NNSA implements nondestructive gas sampling technique for nuclear...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    implements ... NNSA implements nondestructive gas sampling technique for nuclear weapon components Posted: June 12, 2012 - 1:34pm The National Nuclear Security Administration...

  17. August 2015 Groundwater and Surface Water Sampling at the Tuba...

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Tuba City, Arizona, Disposal Site November 2015 LMSTUB.........7 Water Sampling Field Activities Verification ...

  18. February 2016 Groundwater and Surface Water Sampling at the Tuba...

    Office of Legacy Management (LM)

    6 Groundwater and Surface Water Sampling at the Tuba City, Arizona, Disposal Site April .........5 Water Sampling Field Activities Verification ...

  19. Neural net controlled tag gas sampling system for nuclear reactors

    DOE Patents [OSTI]

    Gross, Kenneth C.; Laug, Matthew T.; Lambert, John D. B.; Herzog, James P.

    1997-01-01

    A method and system for providing a tag gas identifier to a nuclear fuel rod and analyze escaped tag gas to identify a particular failed nuclear fuel rod. The method and system include disposing a unique tag gas composition into a plenum of a nuclear fuel rod, monitoring gamma ray activity, analyzing gamma ray signals to assess whether a nuclear fuel rod has failed and is emitting tag gas, activating a tag gas sampling and analysis system upon sensing tag gas emission from a failed nuclear rod and evaluating the escaped tag gas to identify the particular failed nuclear fuel rod.

  20. Neural net controlled tag gas sampling system for nuclear reactors

    DOE Patents [OSTI]

    Gross, K.C.; Laug, M.T.; Lambert, J.B.; Herzog, J.P.

    1997-02-11

    A method and system are disclosed for providing a tag gas identifier to a nuclear fuel rod and analyze escaped tag gas to identify a particular failed nuclear fuel rod. The method and system include disposing a unique tag gas composition into a plenum of a nuclear fuel rod, monitoring gamma ray activity, analyzing gamma ray signals to assess whether a nuclear fuel rod has failed and is emitting tag gas, activating a tag gas sampling and analysis system upon sensing tag gas emission from a failed nuclear rod and evaluating the escaped tag gas to identify the particular failed nuclear fuel rod. 12 figs.

  1. Apparatus and method for maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling

    DOE Patents [OSTI]

    Felix, Larry Gordon; Farthing, William Earl; Irvin, James Hodges; Snyder, Todd Robert

    2010-05-11

    A dilution apparatus for diluting a gas sample. The apparatus includes a sample gas conduit having a sample gas inlet end and a diluted sample gas outlet end, and a sample gas flow restricting orifice disposed proximate the sample gas inlet end connected with the sample gas conduit and providing fluid communication between the exterior and the interior of the sample gas conduit. A diluted sample gas conduit is provided within the sample gas conduit having a mixing end with a mixing space inlet opening disposed proximate the sample gas inlet end, thereby forming an annular space between the sample gas conduit and the diluted sample gas conduit. The mixing end of the diluted sample gas conduit is disposed at a distance from the sample gas flow restricting orifice. A dilution gas source connected with the sample gas inlet end of the sample gas conduit is provided for introducing a dilution gas into the annular space, and a filter is provided for filtering the sample gas. The apparatus is particularly suited for diluting heated sample gases containing one or more condensable components.

  2. Apparatus and process for collection of gas and vapor samples

    DOE Patents [OSTI]

    Jackson, Dennis G.; Peterson, Kurt D.; Riha, Brian D.

    2008-04-01

    A gas sampling apparatus and process is provided in which a standard crimping tool is modified by an attached collar. The collar permits operation of the crimping tool while also facilitating the introduction of a supply of gas to be introduced into a storage vial. The introduced gas supply is used to purge ambient air from a collection chamber and an interior of the sample vial. Upon completion of the purging operation, the vial is sealed using the crimping tool.

  3. Portable tester for determining gas content within a core sample

    DOE Patents [OSTI]

    Garcia, Jr., Fred; Schatzel, Steven J.

    1998-01-01

    A portable tester is provided for reading and displaying the pressure of a gas released from a rock core sample stored within a sealed container and for taking a sample of the released pressurized gas for chemical analysis thereof for subsequent use in a modified direct method test which determines the volume of gas and specific type of gas contained within the core sample. The portable tester includes a pair of low and high range electrical pressure transducers for detecting a gas pressure; a pair of low and high range display units for displaying the pressure of the detected gas- a selector valve connected to the low and high range pressure transducers, a selector knob for selecting gas flow to one of the flow paths; control valve having an inlet connection to the sealed container, and outlets connected to: a sample gas canister, a second outlet port connected to the selector valve means for reading the pressure of the gas from the sealed container to either the low range or high range pressure transducers, and a connection for venting gas contained within the sealed container to the atmosphere. A battery is electrically connected to and supplies the power for operating the unit. The pressure transducers, display units, selector and control valve means and the battery is mounted to and housed within a protective casing for portable transport and use.

  4. Portable tester for determining gas content within a core sample

    DOE Patents [OSTI]

    Garcia, F. Jr.; Schatzel, S.J.

    1998-04-21

    A portable tester is provided for reading and displaying the pressure of a gas released from a rock core sample stored within a sealed container and for taking a sample of the released pressurized gas for chemical analysis thereof for subsequent use in a modified direct method test which determines the volume of gas and specific type of gas contained within the core sample. The portable tester includes a pair of low and high range electrical pressure transducers for detecting a gas pressure; a pair of low and high range display units for displaying the pressure of the detected gas; a selector valve connected to the low and high range pressure transducers and a selector knob for selecting gas flow to one of the flow paths; control valve having an inlet connection to the sealed container; and outlets connected to: a sample gas canister, a second outlet port connected to the selector valve means for reading the pressure of the gas from the sealed container to either the low range or high range pressure transducers, and a connection for venting gas contained within the sealed container to the atmosphere. A battery is electrically connected to and supplies the power for operating the unit. The pressure transducers, display units, selector and control valve means and the battery is mounted to and housed within a protective casing for portable transport and use. 5 figs.

  5. Evaluation for the Frequency of Gas Sampling for the High Burnup...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The report provides a technically based gas sampling frequency strategy for the ... could change gas composition culminates in an adaptive gas sampling frequency strategy. ...

  6. ARM - Field Campaign - Precision Gas Sampling (PGS) Validation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Campaign : Precision Gas Sampling (PGS) Validation Field Campaign 2003.04.02 - 2003.09.02 Lead Scientist : Marc Fischer For data sets, see below. Abstract Ecosystem-atmosphere ...

  7. Sampling and analysis plan for canister liquid and gas sampling at 105 KW fuel storage basin

    SciTech Connect (OSTI)

    Trimble, D.J.

    1996-08-09

    This Sampling and Analysis Plan describes the equipment,procedures and techniques for obtaining gas and liquid samples from sealed K West fuel canisters. The analytical procedures and quality assurance requirements for the subsequent laboratory analysis of the samples are also discussed.

  8. GNS Castor V/21 Headspace Gas Sampling 2014

    SciTech Connect (OSTI)

    Winston, Philip Lon

    2016-01-01

    Prior to performing an internal visual inspection, samples of the headspace gas of the GNS Castor V/21 cask were taken on June 12, 2014. These samples were taken in support of the CREIPI/Japanese nuclear industry effort to validate fuel integrity without visual inspection by measuring the 85Kr content of the cask headspace

  9. FASTGAS: Fast Gas Sampling for palladium exchange tests

    SciTech Connect (OSTI)

    Malinowski, M.E.; Stewart, K.D.; VerBerkmoes, A.A.

    1991-06-01

    A mass spectrometric technique for measuring the composition of gas flows in rapid H/D exchange reactions in palladium compacts has been developed. This method, called FASTGAS (Fast Gas Sampling)'' has been used at atmospheric pressures and above with a time response of better than 100 ms. The current implementation of the FASTGAS technique is described in detail and examples of its application to palladium hydride exchange tests are given. 12 refs., 10 figs.

  10. Self-contained cryogenic gas sampling apparatus and method

    DOE Patents [OSTI]

    McManus, Gary J.; Motes, Billy G.; Bird, Susan K.; Kotter, Dale K.

    1996-01-01

    Apparatus for obtaining a whole gas sample, composed of: a sample vessel having an inlet for receiving a gas sample; a controllable valve mounted for controllably opening and closing the inlet; a valve control coupled to the valve for opening and closing the valve at selected times; a portable power source connected for supplying operating power to the valve control; and a cryogenic coolant in thermal communication with the vessel for cooling the interior of the vessel to cryogenic temperatures. A method of obtaining an air sample using the apparatus described above, by: placing the apparatus at a location at which the sample is to be obtained; operating the valve control to open the valve at a selected time and close the valve at a selected subsequent time; and between the selected times maintaining the vessel at a cryogenic temperature by heat exchange with the coolant.

  11. Self-contained cryogenic gas sampling apparatus and method

    DOE Patents [OSTI]

    McManus, G.J.; Motes, B.G.; Bird, S.K.; Kotter, D.K.

    1996-03-26

    Apparatus for obtaining a whole gas sample, is composed of: a sample vessel having an inlet for receiving a gas sample; a controllable valve mounted for controllably opening and closing the inlet; a valve control coupled to the valve for opening and closing the valve at selected times; a portable power source connected for supplying operating power to the valve control; and a cryogenic coolant in thermal communication with the vessel for cooling the interior of the vessel to cryogenic temperatures. A method is described for obtaining an air sample using the apparatus described above, by: placing the apparatus at a location at which the sample is to be obtained; operating the valve control to open the valve at a selected time and close the valve at a selected subsequent time; and between the selected times maintaining the vessel at a cryogenic temperature by heat exchange with the coolant. 3 figs.

  12. ARM - Field Campaign - Precision Gas Sampling (PGS) Validation Field

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Campaign govCampaignsPrecision Gas Sampling (PGS) Validation Field Campaign ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Precision Gas Sampling (PGS) Validation Field Campaign 2001.07.11 - 2001.07.25 Lead Scientist : Marc Fischer Data Availability Data are being processed for inclusion in ARM Archive. For data sets, see below. Summary July, 2001: Three systems were deployed in four fields during a

  13. ARM - Field Campaign - Precision Gas Sampling (PGS) Validation Field

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Campaign govCampaignsPrecision Gas Sampling (PGS) Validation Field Campaign ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Precision Gas Sampling (PGS) Validation Field Campaign 2004.04.15 - 2004.12.15 Lead Scientist : Marc Fischer For data sets, see below. Abstract Accurate prediction of the regional responses of CO2 flux to changing climate, land use, and management requires models that are

  14. ARM - Field Campaign - Precision Gas Sampling (PGS) Validation Field

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Campaign govCampaignsPrecision Gas Sampling (PGS) Validation Field Campaign ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Precision Gas Sampling (PGS) Validation Field Campaign 2005.03.01 - 2006.01.08 Lead Scientist : Marc Fischer For data sets, see below. Abstract Accurate prediction of the regional responses of CO2 flux to changing climate, land use, and management requires models that are

  15. ARM - Field Campaign - Precision Gas Sampling (PGS) Validation Field

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Campaign govCampaignsPrecision Gas Sampling (PGS) Validation Field Campaign ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Precision Gas Sampling (PGS) Validation Field Campaign 2007.01.01 - 2007.12.31 Lead Scientist : Marc Fischer For data sets, see below. Abstract Accurate prediction of the regional responses of CO2 flux to changing climate, land use, and management requires models that are

  16. ARM - Field Campaign - Precision Gas Sampling (PGS) Validation Field

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Campaign govCampaignsPrecision Gas Sampling (PGS) Validation Field Campaign ARM Data Discovery Browse Data Related Campaigns PGS Validation 2011-2013 2011.03.01, Fischer, SGP PGS Validatation 2010 2010.03.01, Fischer, SGP PGS Validatation 2009.03.01, Fischer, SGP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Precision Gas Sampling (PGS) Validation Field Campaign 2008.01.01 - 2008.12.31 Lead Scientist : Marc Fischer For data sets,

  17. Field Sampling | Open Energy Information

    Open Energy Info (EERE)

    Field Mapping Hand-held X-Ray Fluorescence (XRF) Macrophotography Portable X-Ray Diffraction (XRD) Field Sampling Gas Sampling Gas Flux Sampling Soil Gas Sampling Surface Gas...

  18. CHARACTERIZATION OF DWPF MELTER OFF-GAS QUENCHER SAMPLE

    SciTech Connect (OSTI)

    Newell, J.

    2011-11-14

    The Savannah River National Laboratory (SRNL) recently received a deposit sample from the Melter Primary Off Gas System (POG) of the Defense Waste Processing Facility (DWPF). This sample was composed of material that had been collected while the quencher was in operation January 27, 2011 through March 31, 2011. DWPF requested, through a technical assistance request, characterization of the melter off-gas deposits by x-ray diffraction (XRD), scanning electron microscopy (SEM), and chemical analysis. The purpose of the Melter Off-Gas System is to reduce the amount of radioactive particles and mercury in the gases vented to the atmosphere. Gases emitted from the melter pass through the primary film cooler, quencher, Off-Gas Condensate Tank (OGCT), Steam Atomized Scrubbers (SAS), a condenser, a high efficiency mist eliminator, and a high efficiency particulate air filter, before being vented to the Process Vessel Vent System. The film coolers cool the gases leaving the melter vapor space from {approx}750 C to {approx}375 C, by introducing air and steam to the flow. In the next step, the quencher cools the gas to about 60 C by bringing the condensate from the OGCT in contact with the effluent (Figure 1). Most of the steam in the effluent is then condensed and the melter vapor space pressure is reduced. The purpose of the OGCT is to collect and store the condensate formed during the melter operation. Condensate from the OGCT is circulated to the SAS and atomized with steam. This atomized condensate is mixed with the off-gas to wet and join the particulate which is then removed in the cyclone. The next stage incorporates a chilled water condenser which separates the vapors and elemental mercury from the off-gas steam. Primary off-gas deposit samples from the DWPF melter have previously been analyzed. In 2003, samples from just past the film cooler, from the inlet of the quencher and inside the quencher were analyzed at SRNL. It was determined that the samples were a

  19. Surface Water Sampling At Raft River Geothermal Area (1973) ...

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Water Sampling At Raft River Geothermal Area (1973) Exploration Activity Details Location...

  20. Surface Water Sampling At Chena Geothermal Area (Holdmann, Et...

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Surface Water Sampling At Chena Geothermal Area (Holdmann, Et Al., 2006) Exploration Activity...

  1. Gas Sampling At Gabbs Valley Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gas Sampling At Gabbs Valley Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Sampling At Gabbs Valley Area (DOE GTP)...

  2. Gas Sampling At Gabbs Valley Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gas Sampling At Gabbs Valley Area (DOE GTP) (Redirected from Water-Gas Samples At Gabbs Valley Area (DOE GTP)) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home...

  3. Gas Sampling At Glass Buttes Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gas Sampling At Glass Buttes Area (DOE GTP) (Redirected from Water-Gas Samples At Glass Buttes Area (DOE GTP)) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home...

  4. Gas Sampling At Glass Buttes Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gas Sampling At Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Sampling At Glass Buttes Area (DOE GTP)...

  5. Gasbuggy, New Mexico, Natural Gas and Produced Water Sampling and Analysis Results for 2011

    SciTech Connect (OSTI)

    2011-09-01

    The U.S. Department of Energy (DOE) Office of Legacy Management conducted natural gas sampling for the Gasbuggy, New Mexico, site on June 7 and 8, 2011. Natural gas sampling consists of collecting both gas samples and samples of produced water from gas production wells. Water samples from gas production wells were analyzed for gamma-emitting radionuclides, gross alpha, gross beta, and tritium. Natural gas samples were analyzed for tritium and carbon-14. ALS Laboratory Group in Fort Collins, Colorado, analyzed water samples. Isotech Laboratories in Champaign, Illinois, analyzed natural gas samples.

  6. Automated Surface Sampling Probe for Mass Spectrometry - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Advanced Materials Advanced Materials Find More Like This Return to Search Automated Surface Sampling Probe for Mass Spectrometry Mass Spectrometry Imaging for Drug Discovery and Pharmaceutical Research Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing Summary Dr. Gary Van Berkel and colleagues have developed a liquid microjunction surface sampling probe (LMJ?SSP). The LMJ?SSP provides mass spectrometry with a simple and efficient ambient surface

  7. Thermophoretic separation of aerosol particles from a sampled gas stream

    DOE Patents [OSTI]

    Postma, A.K.

    1984-09-07

    This disclosure relates to separation of aerosol particles from gas samples withdrawn from within a contained atmosphere, such as containment vessels for nuclear reactors or other process equipment where remote gaseous sampling is required. It is specifically directed to separation of dense aerosols including particles of any size and at high mass loadings and high corrosivity. The United States Government has rights in this invention pursuant to Contract DE-AC06-76FF02170 between the US Department of Energy and Westinghouse Electric Corporation.

  8. Gas impermeable glaze for sealing a porous ceramic surface

    DOE Patents [OSTI]

    Reed, Scott T.; Stone, Ronald G.; Nenoff, Tina M.; Trudell, Daniel E.; Thoma, Steven G.

    2004-04-06

    A process for fabricating a gas impermeable seal on a porous ceramic surface using a thin, glass-based, pinhole free glaze. The process can be used to fabricate gas impermeable end seals on porous alumina tubes used as filter media. The porous alumina tubes can have an inorganic microporous thin film separation membrane on the inner surface, which can be used for high temperature gas separation processes.

  9. Gasbuggy, New Mexico, Natural Gas and Produced Water Sampling Results for 2012

    SciTech Connect (OSTI)

    2012-12-01

    The U.S. Department of Energy (DOE) Office of Legacy Management conducted annual natural gas sampling for the Gasbuggy, New Mexico, Site on June 20 and 21, 2012. This long-term monitoring of natural gas includes samples of produced water from gas production wells that are located near the site. Water samples from gas production wells were analyzed for gamma-emitting radionuclides, gross alpha, gross beta, and tritium. Natural gas samples were analyzed for tritium and carbon-14. ALS Laboratory Group in Fort Collins, Colorado, analyzed water samples. Isotech Laboratories in Champaign, Illinois, analyzed natural gas samples.

  10. Gasbuggy, New Mexico, Hydrologic and Natural Gas Sampling and Analysis Results for 2010

    SciTech Connect (OSTI)

    None

    2010-12-01

    The U.S. Department of Energy (DOE) Office of Legacy Management conducted natural gas sampling for the Gasbuggy, New Mexico, site on July 6 and 7, 2010. Additionally, a water sample was obtained at one well known as the 29-6 Water Hole, several miles west of the Gasbuggy site. Natural gas sampling consists of collecting both gas samples and samples of produced water from gas production wells. Water samples from gas production wells were analyzed for gamma-emitting radionuclides, gross alpha, gross beta, and tritium. Natural gas samples were analyzed for tritium and carbon-14. The one water well sample was analyzed for gamma-emitting radionuclides and tritium. ALS Laboratory Group in Fort Collins, Colorado, analyzed water samples. Isotech Laboratories in Champaign, Illinois, analyzed natural gas samples.

  11. DUS II SOIL GAS SAMPLING AND AIR INJECTION TEST RESULTS (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: DUS II SOIL GAS SAMPLING AND AIR INJECTION TEST RESULTS Citation Details In-Document Search Title: DUS II SOIL GAS SAMPLING AND AIR INJECTION TEST RESULTS You ...

  12. Full-Column Greenhouse Gas Sampling 2012-2014 Final Campaign...

    Office of Scientific and Technical Information (OSTI)

    Full-Column Greenhouse Gas Sampling 2012-2014 Final Campaign Report Citation Details In-Document Search Title: Full-Column Greenhouse Gas Sampling 2012-2014 Final Campaign Report ...

  13. DUS II SOIL GAS SAMPLING AND AIR INJECTION TEST RESULTS (Technical...

    Office of Scientific and Technical Information (OSTI)

    DUS II SOIL GAS SAMPLING AND AIR INJECTION TEST RESULTS Citation Details In-Document Search Title: DUS II SOIL GAS SAMPLING AND AIR INJECTION TEST RESULTS Soil vapor extraction ...

  14. Sampling and Analysis Plan for canister liquid and gas sampling at 105-KW fuel storage basin

    SciTech Connect (OSTI)

    Harris, R.A.; Green, M.A.; Makenas, B.J.; Trimble, D.J.

    1995-03-01

    This Sampling and Analysis Plan (SAP) details the sampling and analyses to be performed on fuel canisters transferred to the Weasel Pit of the 105-KW fuel storage basin. The radionuclide content of the liquid and gas in the canisters must be evaluated to support the shipment of fuel elements to the 300 Area in support of the fuel characterization studies (Abrefah, et al. 1994, Trimble 1995). The following sections provide background information and a description of the facility under investigation, discuss the existing site conditions, present the constituents of concern, outline the purpose and scope of the investigation, outline the data quality objectives (DQO), provide analytical detection limit, precision, and accuracy requirements, and address other quality assurance (QA) issues.

  15. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........3 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Natural Gas Analysis Data ...

  16. Sampling for Beryllium Surface Contamination using Wet, Dry and Alcohol Wipe Sampling

    SciTech Connect (OSTI)

    Kerr, Kent

    2004-12-17

    This research project was conducted at the National Nuclear Security Administration's Kansas City Plant, operated by Honeywell Federal Manufacturing and Technologies, in conjunction with the Safety Sciences Department of Central Missouri State University, to compare relative removal efficiencies of three wipe sampling techniques currently used at Department of Energy facilities. Efficiencies of removal of beryllium contamination from typical painted surfaces were tested by wipe sampling with dry Whatman 42 filter paper, with water-moistened (Ghost Wipe) materials, and by methanol-moistened wipes. Test plates were prepared using 100 mm X 15 mm Pyrex Petri dishes with interior surfaces spray painted with a bond coat primer. To achieve uniform deposition over the test plate surface, 10 ml aliquots of solution containing 1 beryllium and 0.1 ml of metal working fluid were transferred to the test plates and subsequently evaporated. Metal working fluid was added to simulate the slight oiliness common on surfaces in metal working shops where fugitive oil mist accumulates over time. Sixteen test plates for each wipe method (dry, water, and methanol) were processed and sampled using a modification of wiping patterns recommended by OSHA Method 125G. Laboratory and statistical analysis showed that methanol-moistened wipe sampling removed significantly more (about twice as much) beryllium/oil-film surface contamination as water-moistened wipes (p< 0.001), which removed significantly more (about twice as much) residue as dry wipes (p <0.001). Evidence for beryllium sensitization via skin exposure argues in favor of wipe sampling with wetting agents that provide enhanced residue removal efficiency.

  17. Method and apparatus for measuring the gas permeability of a solid sample

    DOE Patents [OSTI]

    Carstens, D.H.W.

    1984-01-27

    The disclosure is directed to an apparatus and method for measuring the permeability of a gas in a sample. The gas is allowed to reach a steady flow rate through the sample. A measurable amount of the gas is collected during a given time period and then delivered to a sensitive quadrupole. The quadrupole signal, adjusted for background, is proportional to the amount of gas collected during the time period. The quadrupole can be calibrated with a standard helium leak. The gas can be deuterium and the sample can be polyvinyl alcohol.

  18. Gas Flux Sampling At Brady Hot Springs Area (Lechler And Coolbaugh...

    Open Energy Info (EERE)

    Brady Hot Springs Area (Lechler And Coolbaugh, 2007) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Flux Sampling At Brady Hot Springs Area...

  19. Gas Sampling At Rye Patch Area (DOE GTP, 2011) | Open Energy...

    Open Energy Info (EERE)

    2011) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Sampling At Rye Patch Area (DOE GTP, 2011) Exploration Activity Details Location Rye...

  20. Gas Flux Sampling At Olowalu-Ukumehame Canyon Area (Thomas, 1986...

    Open Energy Info (EERE)

    1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Flux Sampling At Olowalu-Ukumehame Canyon Area (Thomas, 1986) Exploration Activity...

  1. Gas Flux Sampling At Mccoy Geothermal Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Flux Sampling At Mccoy Geothermal Area (DOE GTP) Exploration Activity Details Location...

  2. Gas Sampling At Black Warrior Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Sampling At Black Warrior Area (DOE GTP) Exploration Activity Details Location Black...

  3. Gas Flux Sampling At Black Warrior Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Flux Sampling At Black Warrior Area (DOE GTP) Exploration Activity Details Location...

  4. Gas Flux Sampling At Maui Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Flux Sampling At Maui Area (DOE GTP) Exploration Activity Details Location Maui Area...

  5. Gas Flux Sampling At Mauna Loa Northeast Rift Area (Thomas, 1986...

    Open Energy Info (EERE)

    1986) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Flux Sampling At Mauna Loa Northeast Rift Area (Thomas, 1986) Exploration Activity...

  6. Systems acceptance and operability testing for rotary mode core sampling in flammable gas tanks

    SciTech Connect (OSTI)

    Corbett, J.E., Westinghouse Hanford

    1996-07-29

    This document provides instructions for the system acceptance and operability testing of the rotary mode core sampling system, modified for use in flammable gas tanks.

  7. Water-Gas Samples At Long Valley Caldera Geothermal Area (Farrar...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water-Gas Samples At Long Valley Caldera Geothermal Area (Farrar, Et Al., 2003) Exploration...

  8. Water-Gas Sampling At Fenton Hill HDR Geothermal Area (Janik...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water-Gas Sampling At Fenton Hill HDR Geothermal Area (Janik & Goff, 2002) Exploration...

  9. Sample Format Natural Gas Imports by Pipeline Monthly Sales and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are: Northeast, Midwest, South, West Send to: The Office of Fossil Energy, Natural Gas Regulatory Activities, U.S. Dept. of Energy, FE-34, P.O. Box 44375 Washington, D.C....

  10. Process and apparatus for obtaining samples of liquid and gas from soil

    DOE Patents [OSTI]

    Rossabi, Joseph; May, Christopher P.; Pemberton, Bradley E.; Shinn, Jim; Sprague, Keith

    1999-01-01

    An apparatus and process for obtaining samples of liquid and gas from subsurface soil is provided having filter zone adjacent an external expander ring. The expander ring creates a void within the soil substrate which encourages the accumulation of soil-borne fluids. The fluids migrate along a pressure gradient through a plurality of filters before entering a first chamber. A one-way valve regulates the flow of fluid into a second chamber in further communication with a collection tube through which samples are collected at the surface. A second one-way valve having a reverse flow provides additional communication between the chambers for the pressurized cleaning and back-flushing of the apparatus.

  11. Process and apparatus for obtaining samples of liquid and gas from soil

    DOE Patents [OSTI]

    Rossabi, J.; May, C.P.; Pemberton, B.E.; Shinn, J.; Sprague, K.

    1999-03-30

    An apparatus and process for obtaining samples of liquid and gas from subsurface soil is provided having filter zone adjacent an external expander ring. The expander ring creates a void within the soil substrate which encourages the accumulation of soil-borne fluids. The fluids migrate along a pressure gradient through a plurality of filters before entering a first chamber. A one-way valve regulates the flow of fluid into a second chamber in further communication with a collection tube through which samples are collected at the surface. A second one-way valve having a reverse flow provides additional communication between the chambers for the pressurized cleaning and back-flushing of the apparatus. 8 figs.

  12. Surface Gas Sampling (Klein, 2007) | Open Energy Information

    Open Energy Info (EERE)

    In The Past 20 Years- Geochemistry In Geothermal Exploration Resource Evaluation And Reservoir Management Additional References Retrieved from "http:en.openei.orgw...

  13. Gas Flux Sampling (Lewicki & Oldenburg) | Open Energy Information

    Open Energy Info (EERE)

    Activity Date Usefulness useful DOE-funding Unknown References Jennifer L. Lewicki, Curtis M. Oldenburg (Unknown) Near-Surface Co2 Monitoring And Analysis To Detect Hidden...

  14. Gas Flux Sampling (Lewicki & Oldenburg, 2004) | Open Energy Informatio...

    Open Energy Info (EERE)

    Activity Date Usefulness useful DOE-funding Unknown References Jennifer L. Lewicki, Curtis M. Oldenburg (2004) Strategies For Detecting Hidden Geothermal Systems By Near-Surface...

  15. ARM - Field Campaign - Full-column Greenhouse Gas Sampling 2012-2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govCampaignsFull-column Greenhouse Gas Sampling 2012-2014 Campaign Links Final Campaign Report ARM Data Discovery Browse Data Related Campaigns Full-column Greenhouse Gas Sampling 2015-2017 2015.03.01, Fischer, SGP Balloon-Borne Full-column Greenhouse Gas Profiling 2014.03.01, Fischer, SGP Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : Full-column Greenhouse Gas Sampling 2012-2014 2012.01.13 - 2014.02.28 Lead Scientist : Marc Fischer

  16. Draft evaluation of the frequency for gas sampling for the high burnup confirmatory data project

    SciTech Connect (OSTI)

    Stockman, Christine T.; Alsaed, Halim A.; Bryan, Charles R.

    2015-03-26

    This report fulfills the M3 milestone M3FT-15SN0802041, “Draft Evaluation of the Frequency for Gas Sampling for the High Burn-up Storage Demonstration Project” under Work Package FT-15SN080204, “ST Field Demonstration Support – SNL”. This report provides a technically based gas sampling frequency strategy for the High Burnup (HBU) Confirmatory Data Project. The evaluation of: 1) the types and magnitudes of gases that could be present in the project cask and, 2) the degradation mechanisms that could change gas compositions culminates in an adaptive gas sampling frequency strategy. This adaptive strategy is compared against the sampling frequency that has been developed based on operational considerations. Gas sampling will provide information on the presence of residual water (and byproducts associated with its reactions and decomposition) and breach of cladding, which could inform the decision of when to open the project cask.

  17. Modeled heating and surface erosion comparing motile (gas borne) and stationary (surface coating) inert particle additives

    SciTech Connect (OSTI)

    Buckingham, A.C.; Siekhaus, W.J.

    1982-09-27

    The unsteady, non-similar, chemically reactive, turbulent boundary layer equations are modified for gas plus dispersed solid particle mixtures, for gas phase turbulent combustion reactions and for heterogeneous gas-solid surface erosive reactions. The exterior (ballistic core) edge boundary conditions for the solutions are modified to include dispersed particle influences on core propellant combustion-generated turbulence levels, combustion reactants and products, and reaction-induced, non-isentropic mixture states. The wall surface (in this study it is always steel) is considered either bare or coated with a fixed particle coating which is conceptually non-reactive, insulative, and non-ablative. Two families of solutions are compared. These correspond to: (1) consideration of gas-borne, free-slip, almost spontaneously mobile (motile) solid particle additives which influence the turbulent heat transfer at the uncoated steel surface and, in contrast, (2) consideration of particle-free, gas phase turbulent heat transfer to the insulated surface coated by stationary particles. Significant differences in erosive heat transfer are found in comparing the two families of solutions over a substantial range of interior ballistic flow conditions. The most effective influences on reducing erosive heat transfer appear to favor mobile, gas-borne particle additives.

  18. Gas Flux Sampling At Haleakala Volcano Area (Thomas, 1986) |...

    Open Energy Info (EERE)

    deviations from expected ratios. One well was also found to have an abnormally high sulfate concentration. All three wells are located in the same general area and are sampling...

  19. ARM - Field Campaign - Precision Gas Sampling (PGS) Validation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sampling (PGS) Validation Field Campaign 2002.01.01 - 2002.07.31 Lead Scientist : Marc Fischer For data sets, see below. Abstract The PGS validation will continue measuring the...

  20. A new Stark decelerator based surface scattering instrument for studying energy transfer at the gas-surface interface

    SciTech Connect (OSTI)

    Engelhart, Daniel P.; Grätz, Fabian; Wagner, Roman J. V.; Wodtke, Alec M.; Schäfer, Tim; Haak, Henrik; Meijer, Gerard

    2015-04-15

    We report on the design and characterization of a new apparatus for performing quantum-state resolved surface scattering experiments. The apparatus combines optical state-specific molecule preparation with a compact hexapole and a Stark decelerator to prepare carrier gas-free pulses of quantum-state pure CO molecules with velocities controllable between 33 and 1000 m/s with extremely narrow velocity distributions. The ultrahigh vacuum surface scattering chamber includes homebuilt ion and electron detectors, a closed-cycle helium cooled single crystal sample mount capable of tuning surface temperature between 19 and 1337 K, a Kelvin probe for non-destructive work function measurements, a precision leak valve manifold for targeted adsorbate deposition, an inexpensive quadrupole mass spectrometer modified to perform high resolution temperature programmed desorption experiments and facilities to clean and characterize the surface.

  1. June 2011 Natural Gas and Produced Water Sampling at the Gasbuggy, New Mexico, Site

    SciTech Connect (OSTI)

    2011-10-01

    Annual natural gas and produced water monitoring was conducted for gas wells adjacent to Section 36, where the Gasbuggy test was conducted, in accordance with the draft Long-Term Surveillance and Maintenance Plan for the Gasbuggy Site, Rio Arriba County, New Mexico. Sampling and analysis were conducted as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PLN/S04351, continually updated). Natural gas samples were collected for tritium and carbon-14 analyses. Produced water samples were collected and analyzed for tritium, gamma-emitting radionuclides (by high-resolution gamma spectrometry), gross alpha, and gross beta. A duplicate produced water sample was collected from well 30-039-21743. Produced water samples were not collected at locations 30-039-30161 and 30-039-21744 because of the lack of water. Samples were not collected from location 30-039-29988 because the well was shut-in.

  2. July 2010 Natural Gas and Produced Water Sampling at the Gasbuggy, New Mexico, Site

    SciTech Connect (OSTI)

    2011-01-01

    Annual natural gas and produced water monitoring was conducted for gas wells adjacent to Section 36, where the Gasbuggy test was conducted, in accordance with the draft Long-Term Surveillance and Maintenance Plan for the Gasbuggy Site, Rio Arriba County, New Mexico. Sampling and analysis was conducted as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites. (LMS/PLN/S04351, continually updated). Natural gas samples were collected for tritium and carbon-14 analysis. Produced water samples were collected and analyzed for tritium, gamma-emitting radionuclides (by high-resolution gamma spectrometry), gross alpha, and gross beta. An additional water sample was collected from well 29-6 Water Hole for analysis of tritium and gamma-emitting radionuclides. A duplicate produced water sample was collected from well 30-039-21743.

  3. June 2015 Groundwater and Surface Water Sampling at the Green...

    Office of Legacy Management (LM)

    ... DVP-June 2015, Green River, Utah U.S. Department of Energy RIN 15067102 August 2015 Page 12 Inductively Coupled Plasma Interference Check Sample Analysis Interference check samples ...

  4. Evaluation for the Frequency of Gas Sampling for the High Burnup Confirmation Data Project

    Office of Energy Efficiency and Renewable Energy (EERE)

    The report provides a technically based gas sampling frequency strategy for the High-Burnup (HBU) Confirmatory Data Project.  The evaluation of 1) the types and magnitudes of gases that could be...

  5. High heating rate thermal desorption for molecular surface sampling

    DOE Patents [OSTI]

    Ovchinnikova, Olga S.; Van Berkel, Gary J.

    2016-03-29

    A method for analyzing a sample having at least one analyte includes the step of heating the sample at a rate of at least 10.sup.6 K/s to thermally desorb at least one analyte from the sample. The desorbed analyte is collected. The analyte can then be analyzed.

  6. Surface Water Sampling At Chena Geothermal Area (Waring, Et Al...

    Open Energy Info (EERE)

    calcium and magnesium concentrations were measured, with elevated levels of silica and sulfate. Surface fumarole gases were tested with a flame to indicate carbon dioxide...

  7. Bulk and surface controlled diffusion of fission gas atoms

    SciTech Connect (OSTI)

    Andersson, Anders D.

    2012-08-09

    {sub 2{+-}x}, which compare favorably to available experiments. This is an extension of previous work [13]. In particular, it applies improved chemistry models for the UO{sub 2{+-}x} nonstoichiometry and its impact on the fission gas activation energies. The derivation of these models follows the approach that used in our recent study of uranium vacancy diffusion in UO{sub 2} [14]. Also, based on the calculated DFT data we analyze vacancy enhanced diffusion mechanisms in the intermediate temperature regime. In addition to vacancy enhanced diffusion we investigate species transport on the (111) UO{sub 2} surface. This is motivated by the formation of small voids partially filled with fission gas atoms (bubbles) in UO{sub 2} under irradiation, for which surface diffusion could be the rate-limiting transport step. Diffusion of such bubbles constitutes an alternative mechanism for mass transport in these materials.

  8. Langasite Surface Acoustic Wave Gas Sensors: Modeling and Verification

    SciTech Connect (OSTI)

    Zheng, Peng; Greve, David W; Oppenheim, Irving J

    2013-01-01

    We report finite element simulations of the effect of conductive sensing layers on the surface wave velocity of langasite substrates. The simulations include both the mechanical and electrical influences of the conducting sensing layer. We show that three-dimensional simulations are necessary because of the out-of-plane displacements of the commonly used (0, 138.5, 26.7) Euler angle. Measurements of the transducer input admittance in reflective delay-line devices yield a value for the electromechanical coupling coefficient that is in good agreement with the three-dimensional simulations on bare langasite substrate. The input admittance measurements also show evidence of excitation of an additional wave mode and excess loss due to the finger resistance. The results of these simulations and measurements will be useful in the design of surface acoustic wave gas sensors.

  9. Design of pellet surface grooves for fission gas plenum

    SciTech Connect (OSTI)

    Carter, T.J.; Jones, L.R.; Macici, N.; Miller, G.C.

    1986-01-01

    In the Canada deuterium uranium pressurized heavy water reactor, short (50-cm) Zircaloy-4 clad bundles are fueled on-power. Although internal void volume within the fuel rods is adequate for the present once-through natural uranium cycle, the authors have investigated methods for increasing the internal gas storage volume needed in high-power, high-burnup, experimental ceramic fuels. This present work sought to prove the methodology for design of gas storage volume within the fuel pellets - specifically the use of grooves pressed or machined into the relatively cool pellet/cladding interface. Preanalysis and design of pellet groove shape and volume was accomplished using the TRUMP heat transfer code. Postirradiation examination (PIE) was used to check the initial design and heat transfer assumptions. Fission gas release was found to be higher for the grooved pellet rods than for the comparison rods with hollow or unmodified pellets. This had been expected from the initial TRUMP thermal analyses. The ELESIM fuel modeling code was used to check in-reactor performance, but some modifications were necessary to accommodate the loss of heat transfer surface to the grooves. It was concluded that for plenum design purposes, circumferential pellet grooves could be adequately modeled by the codes TRUMP and ELESIM.

  10. Waste drum gas generation sampling program at Rocky Flats during FY 1989

    SciTech Connect (OSTI)

    Roggenthen, D.K.; Nieweg, R.G.

    1990-10-01

    Rocky Flats Plant transuranic waste drums were sampled for gas composition. Glass, metal, graphite, and solidified inorganic sludge transuranic waste forms were sampled. A vacuum system was used to sample each layer of containment inside a waste drum, including individual waste bags. G values were calculated for the waste drums. G(H{sub 2}) was below 0.6 and G(Total) was below 1.3 for all waste forms discussed in this report. 5 refs., 3 figs., 3 tabs.

  11. DEVELOPMENT AND FIELD IMPLEMENTATION OF AN IMPROVED METHOD FOR HEADSPACE GAS SAMPLING OF TRANSURANIC WASTE DRUMS

    SciTech Connect (OSTI)

    Polley, M.; Ankrom, J.; Wickland, T.; Warren, J.

    2003-02-27

    A fast, safe, and cost-effective method for obtaining headspace gas samples has been developed and implemented at Los Alamos National Laboratory (LANL). A sample port is installed directly into a drum lid using a pneumatic driver, allowing sampling with a side-port needle. Testing has shown that the sample port can be installed with no release of radioactive material. Use of this system at LANL has significantly reduced the time required for sampling, and eliminates the need for many safety precautions previously used. The system has significantly improved productivity and lowered radiation exposure and cost.

  12. Characterization of trapped gas saturation and heterogeneity in core sampling using miscible-displacement experiments

    SciTech Connect (OSTI)

    Smith, D.H.; Jikich, S.A.

    1994-12-31

    Trapped gas saturation and permeability heterogeneity were evaluated in Berea cores at reservoir conditions, using standard miscible displacement experiments, with and without surfactants. Pressure and production history were influenced by core heterogeneity and foam lamellae formation when aqueous surfactant was present in the core. The objective of the dispersion-capacitance model was to estimate trapped gas saturations; however longitudinal dispersion and mass transfer also were examined. The results show that the dispersion-capacitance model accurately fits trapped gas saturation controlled by rock heterogeneities and foam lamellae for lamella generating mechanisms that allow a continuous gas phase (leave-behind lamellae). The practical applications resulting from this study can aid in core sample selection and scaling short laboratory corefloods to field dimensions for applications to foam stimulation and underground storage of natural gas.

  13. Critique of Hanford Waste Vitrification Plant off-gas sampling requirements

    SciTech Connect (OSTI)

    Goles, R.W.

    1996-03-01

    Off-gas sampling and monitoring activities needed to support operations safety, process control, waste form qualification, and environmental protection requirements of the Hanford Waste Vitrification Plant (HWVP) have been evaluated. The locations of necessary sampling sites have been identified on the basis of plant requirements, and the applicability of Defense Waste Processing Facility (DWPF) reference sampling equipment to these HWVP requirements has been assessed for all sampling sites. Equipment deficiencies, if present, have been described and the bases for modifications and/or alternative approaches have been developed.

  14. Mass spectrometric helium analysis of solid and gas samples from cold-fusion type experiments

    SciTech Connect (OSTI)

    Oliver, B.M.

    1995-12-01

    A custom mass spectrometer system, operating in static mode, has been used to measure helium in both solid and gas samples front cold-fusion type experiments. The mass spectrometer is a 2-in. Radius, 60{degrees}, permanent angle magnet instrument with a single electron-multiplier collecting. Depending on the absolute levels of helium expected, the analysis are conducted by isotope dilution or by measuring absolute collector values. Solid samples are vaporized to ensure complete helium release. Prior to analysis, the fraction of sample gas to be analyzed is exposed to a series of physical and chemical getters, including room temperature Zr-Al alloy (SAES type 101) and liquid-nitrogen cooled activated charcoal. This is done to remove active gases and hydrogen isotopes which could interfere with the helium determinations. Generally, the analysis protocol is to analyze an equal or greater number of {open_quotes}controls{close_quotes} along with the samples to accurately characterize system background and reproducibility. Absolute sensitivity for the system is approximately 1 x 10{sup 9} atoms. Absolute accuracy is 1% or better for helium levels > 10{sup 11} atoms. With few exceptions, helium analysis of solid samples front cold fusion type experiments have yielded no excess helium above usual system background. A few samples have shown helium levels in the low 10{sup 9} atom range, and some gas samples have shown {sup 4}He levels up to several hundred ppm.

  15. Atmospheric and soil-gas monitoring for surface leakage at the...

    Office of Scientific and Technical Information (OSTI)

    Atmospheric and soil-gas monitoring for surface leakage at the San Juan Basin COsub 2 pilot test site at Pump Canyon New Mexico, using perfluorocarbon tracers, COsub 2 soil-gas ...

  16. Tank 241-T-111 headspace gas and vapor characterization results for samples collected in January 1995

    SciTech Connect (OSTI)

    Huckaby, J.L.; Bratzel, D.R.

    1995-09-01

    Significant changes have been made to all of the original vapor characterization reports. This report documents specific headspace gas and vapor characterization results for all vapor sampling events to date. In addition, changes have been made to the original vapor reports to qualify the data based on quality assurance issues associated with the performing laboratories.

  17. Tank 241-U-111 headspace gas and vapor characterization results for samples collected in February 1995

    SciTech Connect (OSTI)

    Huckaby, J.L.; Bratzel, D.R.

    1995-09-01

    Significant changes have been made to all of the original vapor characterization reports. This report documents specific headspace gas and vapor characterization results for all vapor sampling events to date. In addition, changes have been made to the original vapor reports to qualify the data based on quality assurance issues associated with the performing laboratories.

  18. Tank 241-S-111 headspace gas and vapor characterization results for samples collected in March 1995

    SciTech Connect (OSTI)

    Huckaby, J.L.; Bratzel, D.R.

    1995-09-01

    Significant changes have been made to all of the original vapor characterization reports. This report documents specific headspace gas and vapor characterization results for all vapor sampling events to date. In addition, changes have been made to the original vapor reports to qualify the data based on quality assurance issues associated with the performing laboratories.

  19. Real-time quadrupole mass spectrometer analysis of gas in boreholefluid samples acquired using the U-Tube sampling methodology

    SciTech Connect (OSTI)

    Freifeld, Barry M.; Trautz, Robert C.

    2006-01-11

    Sampling of fluids in deep boreholes is challenging becauseof the necessity to minimize external contamination and maintain sampleintegrity during recovery. The U-tube sampling methodology was developedto collect large volume, multiphase samples at in situ pressures. As apermanent or semi-permanent installation, the U-tube can be used forrapidly acquiring multiple samples or it may be installed for long-termmonitoring applications. The U-tube was first deployed in Liberty County,TX to monitor crosswell CO2 injection as part of the Frio CO2sequestration experiment. Analysis of gases (dissolved or separate phase)was performed in the field using a quadrupole mass spectrometer, whichserved as the basis for determining the arrival of the CO2 plume. Thepresence of oxygen and argon in elevated concentrations, along withreduced methane concentration, indicate sample alteration caused by theintroduction of surface fluids during borehole completion. Despiteproducing the well to eliminate non-native fluids, measurementsdemonstrate that contamination persists until the immiscible CO2injection swept formation fluid into the observationwellbore.

  20. Analysis of volatile organic compounds in groundwater samples by gas chromatography-mass spectrometry

    SciTech Connect (OSTI)

    Bernhardt, J.

    1995-08-23

    The Savannah River Site contains approximately 1500 monitoring wells from which groundwater samples are collected. Many of these samples are sent off-site for various analyses, including the determination of trace volatile organic compounds (VOCs). This report describes accomplishments that have been made during the past year which will ultimately allow VOC analysis to be performed on-site using gas chromatography-mass spectrometry. Through the use of the on-site approach, it is expected that there will be a substantial cost savings. This approach will also provide split-sample analysis capability which can serve as a quality control measure for off-site analysis.

  1. Waste drum gas generation sampling program at Rocky Flats during FY 1988

    SciTech Connect (OSTI)

    Roggenthen, D.K.; McFeeters, T.L.; Nieweg, R.G.

    1991-02-11

    Rocky Flats Plant Transuranic Waste Drums were sampled for gas composition. Combustibles, plastics, Raschig rings, solidified organic sludge, and solidified inorganic sludge transuranic waste forms were sampled. Plastic bag material and waste samples were also taken from some solidified sludge waste drums. A vacuum system was used to sample each layer of containment inside a waste drum, including individual waste bags. G values (gas generation) were calculated for the waste drums. Analytical results indicate that very low concentrations of potentially flammable or corrosive gas mixtures will be found in vented drums. G(H{sub 2}) was usually below 1.6, while G(Total) was below 4.0. Hydrogen permeability tests on different types of plastic waste bags used at Rocky Flats were also conducted. Polyvinylchloride was slightly more permeable to hydrogen than polyethylene for new or creased material. Permeability of aged material to hydrogen was slightly higher than for new material. Solidified organic and inorganic sludges were sampled for volatile organics. The analytical results from two drums of solidified organic sludges showed concentrations were above detection limits for four of the 36 volatile organics analyzed. The analytical results for four of the five solidified inorganic sludges show that concentrations were below detection limits for all volatile organics analyzed. 3 refs., 5 figs., 2 tabs.

  2. September 2015 Groundwater and Surface Water Sampling at the Shiprock, New Mexico, Disposal Site

    Office of Legacy Management (LM)

    Groundwater and Surface Water Sampling at the Shiprock, New Mexico, Disposal Site February 2016 LMS/SHP/S00915 This page intentionally left blank U.S. Department of Energy DVP-September 2015, Shiprock, New Mexico February 2016 RINs 15097348 and 15097349 Page i Contents Sampling Event Summary ...............................................................................................................1 Planned Sampling Map Shiprock, New Mexico, Disposal Site

  3. January 2016 Groundwater and Surface Water Sampling at the Grand Junction, Colorado, Processing Site

    Office of Legacy Management (LM)

    6 Groundwater and Surface Water Sampling at the Grand Junction, Colorado, Processing Site March 2016 LMS/GJT/S00116 This page intentionally left blank U.S. Department of Energy DVP-January 2016, Grand Junction, Colorado March 2016 RIN 15127576 Page i Contents Sampling Event Summary ...............................................................................................................1 Grand Junction, Colorado, Processing Site, Sample Location Map

  4. November 2015 Groundwater and Surface Water Sampling at the Old and New Rifle, Colorado, Processing Sites

    Office of Legacy Management (LM)

    5 Groundwater and Surface Water Sampling at the Old and New Rifle, Colorado, Processing Sites February 2016 LMS/RFN/RFO/S01115 This page intentionally left blank U.S. Department of Energy DVP-November 2015, Rifle, Colorado February 2016 RINs 15107463 and 15107464 Page i Contents Sampling Event Summary ...............................................................................................................1 New Rifle, Colorado, Processing Site, Planned Sampling Map

  5. Adsorbed sulfur-gas methods for both near-surface exploration and downhole logging

    SciTech Connect (OSTI)

    Farwell, S.O.; Barinaga, C.J.; Dolenc, M.R.; Farwell, G.H.

    1986-08-01

    The use of sulfur-containing gases in petroleum exploration is supported by (1) the idea that sulfur may play a role in petroleum genesis, (2) the corresponding existence of sulfur-containing compounds in petroleum and the potential for vertical migration of the low-molecular-weight sulfur species from these reservoirs, (3) the production of H/sub 2/S by anaerobic microorganism populations that develop in the subsurface areas overlying petroleum reservoirs due to the concomitant supply of hydrocarbon nutrients, (4) the recent discovery of near-surface accumulations of pyrite and marcasite as the source of induction potential anomalies over certain fields, and (5) the strong adsorptive affinities of sulfur gases to solid surfaces, which enhance both the concentration and localization of such sulfur-expressed anomalies. During the past 3 years, numerous near-surface soil samples and well cuttings from the Utah-Wyoming Overthrust belt have been analyzed for adsorbed sulfur-gas content by two novel analytical techniques: thermal desorption/metal foil collection/flash desorption/sulfur-selective detection (TD/MFC/FD/SSD) and thermal desorption/cryogenic preconcentration/high-resolution-gas chromatography/optimized-flame photometry (TD/CP/HRGC/OFP).

  6. AFM fluid delivery/liquid extraction surface sampling/electrostatic spray cantilever probe

    SciTech Connect (OSTI)

    Van Berkel, Gary J.

    2015-06-23

    An electrospray system comprises a liquid extraction surface sampling probe. The probe comprises a probe body having a liquid inlet and a liquid outlet, and having a liquid extraction tip. A solvent delivery conduit is provided for receiving solvent liquid from the liquid inlet and delivering the solvent liquid to the liquid extraction tip. An open liquid extraction channel extends across an exterior surface of the probe body from the liquid extraction tip to the liquid outlet. An electrospray emitter tip is in liquid communication with the liquid outlet of the liquid extraction surface sampling probe. A system for analyzing samples, a liquid junction surface sampling system, and a method of analyzing samples are also disclosed.

  7. Radio Frequency Surface Impedance Characterization System for Superconducting Samples at 7.5 GHz

    SciTech Connect (OSTI)

    Binping Xiao, Charles Reece, Michael Kelley, Larry Phillips, Rongli Geng, Haipeng Wang, Frank Marhauser

    2011-05-01

    A radio frequency (RF) surface impedance characterization (SIC) system that uses a sapphire-loaded Nb cavity operating at 7.5 GHz has been fabricated to measure the RF surface impedance of flat superconducting samples. Currently, the SIC system can make direct calorimetric surface impedance measurements in the central 0.8 cm2 area of 5 cm diameter disk samples in a temperature range from 2 to 20 K, exposed to a magnetic flux density of up to 14 mT. As an application, we present the measurement results for a bulk Nb sample.

  8. Method and apparatus for transport, introduction, atomization and excitation of emission spectrum for quantitative analysis of high temperature gas sample streams containing vapor and particulates without degradation of sample stream temperature

    DOE Patents [OSTI]

    Eckels, David E.; Hass, William J.

    1989-05-30

    A sample transport, sample introduction, and flame excitation system for spectrometric analysis of high temperature gas streams which eliminates degradation of the sample stream by condensation losses.

  9. Refractory two-dimensional hole gas on hydrogenated diamond surface

    SciTech Connect (OSTI)

    Hiraiwa, Atsushi; Daicho, Akira; Kurihara, Shinichiro; Yokoyama, Yuki; Kawarada, Hiroshi

    2012-12-15

    Use of two-dimensional hole gas (2DHG), induced on a hydrogenated diamond surface, is a solution to overcoming one of demerits of diamond, i.e., deep energy levels of impurities. This 2DHG is affected by its environment and accordingly needs a passivation film to get a stable device operation especially at high temperature. In response to this requirement, we achieved the high-reliability passivation forming an Al{sub 2}O{sub 3} film on the diamond surface using an atomic-layer-deposition (ALD) method with an H{sub 2}O oxidant at 450 Degree-Sign C. The 2DHG thus protected survived air annealing at 550 Degree-Sign C for an hour, establishing a stable high-temperature operation of 2DHG devices in air. In part, this achievement is based on high stability of C-H bonds up to 870 Degree-Sign C in vacuum and above 450 Degree-Sign C in an H{sub 2}O-containing environment as in the ALD. Chemically, this stability is supported by the fact that both the thermal decomposition of C-H bonds and reaction between C-H bonds and H{sub 2}O are endothermic processes. It makes a stark contrast to the instability of Si-H bonds, which decompose even at room temperature being exposed to atomic hydrogen. In this respect, the diamond 2DHG devices are also promising as power devices expectedly being free from many instability phenomena, such as hot carrier effect and negative-bias temperature instability, associated with Si devices. As to adsorbate, which is the other prerequisite for 2DHG, it desorbed in vacuum below 250 Degree-Sign C, and accordingly some new adsorbates should have adsorbed during the ALD at 450 Degree-Sign C. As a clue to this question, we certainly confirmed that some adsorbates, other than those at room temperature, adsorbed in air above 100 Degree-Sign C and remained at least up to 290 Degree-Sign C. The identification of these adsorbates is open for further investigation.

  10. CHARACTERIZATION OF DWPF MELTER OFF-GAS QUENCHER AND STEAM ATOMIZED SCRUBBER DEPOSIT SAMPLES

    SciTech Connect (OSTI)

    Zeigler, K; Ned Bibler, N

    2007-06-06

    This report summarizes the results from the characterization of deposits from the inlets of the primary off-gas Quencher and Steam Atomized Scrubber (SAS) in the Defense Waste Processing Facility (DWPF), as requested by a technical assistance request. DWPF requested elemental analysis and compound identification to help determine the potential causes for the substance formation. This information will be fed into Savannah River National Laboratory modeling programs to determine if there is a way to decrease the formation of the deposits. The general approach to the characterization of these samples included x-ray diffraction (XRD), scanning electron microscopy (SEM), and chemical analysis. The following conclusions are drawn from the analytical results found in this report: (1) The deposits are not high level waste glass from the DWPF melt pool based on comparison of the compositions of deposits to the composition of a sample of glass taken from the pour stream of the melter during processing of Sludge Batch 3. (2) Chemical composition results suggest that the deposits are probably a combination of sludge and frit particles entrained in the off-gas. (3) Gamma emitters, such as Co-60, Cs-137, Eu-154, Am-241, and Am-243 were detected in both the Quencher and SAS samples with Cs-137 having the highest concentration of the gamma emitters. (4) No evidence existed for accumulation of fissile material (U-233, U-235, and Pu-239) relative to Fe in either deposit. (5) XRD results indicated both samples were primarily amorphorous and contained some crystals of the iron oxides, hematite and magnetite (Fe{sub 2}O{sub 3} and Fe(Fe{sub 2}O{sub 4})), along with sodium nitrate (NaNO{sub 3}). The other main crystalline compound in the SAS deposit was mercurous chloride. The main crystalline compound in the Quencher deposit was a uranium oxide compound. These are all sludge components. (6) SEM analysis of the Quencher deposit revealed crystalline uranium compounds within the sample

  11. Characterization of trapped gas saturation and heterogeneity in core samples using miscible-displacement experiments

    SciTech Connect (OSTI)

    Smith, D.H.; Jikich, S.A.

    1994-12-31

    Trapped gas saturation and permeability heterogeneity were evaluated in Berea cores at reservoir conditions, using standard miscible displacement experiments, with and without surfactants. Pressure and production history were influenced by core heterogeneity and foam lamellae formation when aqueous surfactant was present in the core. A simple dispersion model and a three-coefficient dispersion-capacitance model (Coates-Smith) were fit to the experimental data. The dispersion-capacitance model successfully matched the experiments in which foam lamella formed, while the simple dispersion model was used only for determining initial core flow heterogeneity. The objective of the dispersion-capacitance model was to estimate trapped gas saturations; however longitudinal dispersion and mass transfer also were examined. The results show that the dispersion-capacitance model accurately fits trapped gas saturation controlled by rock heterogeneities and foam lamellae for lamella generating mechanisms that allow a continuous gas phase (leave-behind lamellae). The practical applications resulting from this study can aid in core sample selection and scaling short laboratory corefloods to field dimensions for applications to foam stimulation and underground storage of natural gas.

  12. Vapor and gas sampling of Single-Shell Tank 241-A-101 using the Vapor Sampling System

    SciTech Connect (OSTI)

    Caprio, G.S.

    1995-11-01

    This document presents sampling data resulting from the June 8, 1995, sampling of SST 241-A-101 using the Vapor Sampling System.

  13. THE SMALL ISOLATED GAS-RICH IRREGULAR DWARF (SIGRID) GALAXY SAMPLE: DESCRIPTION AND FIRST RESULTS

    SciTech Connect (OSTI)

    Nicholls, David C.; Dopita, Michael A.; Jerjen, Helmut; Meurer, Gerhardt R.

    2011-09-15

    Using an optically unbiased selection process based on the HIPASS neutral hydrogen survey, we have selected a sample of 83 spatially isolated, gas-rich dwarf galaxies in the southern hemisphere with cz between 350 and 1650 km s{sup -1}, and with R-band luminosities and H I masses less than that of the Small Magellanic Cloud. The sample is an important population of dwarf galaxies in the local universe, all with ongoing star formation, and most of which have no existing spectroscopic data. We are measuring the chemical abundances of these galaxies, using the integral-field spectrograph on the Australian National University 2.3 m telescope, the Wide-Field Spectrograph. This paper describes our survey criteria and procedures, lists the survey sample, and reports on initial observations.

  14. December 2015 Groundwater and Surface Waater Sampling at the Grand Junction, Colorado, Site

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Grand Junction, Colorado, Site March 2016 LMS/GJO/S01215 This page intentionally left blank U.S. Department of Energy DVP-December 2015, Grand Junction, Colorado March 2016 RIN 15117528 Page i Contents Sampling Event Summary ...............................................................................................................1 Data Assessment Summary

  15. July 2015 Groundwater and Surface Water Sampling at the Naturita, Colorado, Processing Site

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Naturita, Colorado, Processing Site October 2015 LMS/NAP/S00715 This page intentionally left blank U.S. Department of Energy DVP-July 2015, Naturita, Colorado October 2015 RIN 15077222 Page i Contents Sampling Event Summary ...............................................................................................................1 Data Assessment Summary

  16. May 2013 Groundwater and Surface Water Sampling at the Rio Blanco, Colorado, Site (Data Validation Package)

    SciTech Connect (OSTI)

    2013-10-01

    Annual sampling was conducted at the Rio Blanco, Colorado, site for the Long-Term Hydrologic Monitoring Program May 14-16, 2013, to monitor groundwater and surface water for potential radionuclide contamination. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for the U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from location CER #1 Black Sulphur. Samples were analyzed for gamma-emitting radionuclides by high-resolution gamma spectrometry and for tritium using the conventional and enrichment methods.

  17. Operable Unit 3-13, Group 3, Other Surface Soils (Phase II) Field Sampling Plan

    SciTech Connect (OSTI)

    G. L. Schwendiman

    2006-07-27

    This Field Sampling Plan describes the Operable Unit 3-13, Group 3, Other Surface Soils, Phase II remediation field sampling activities to be performed at the Idaho Nuclear Technology and Engineering Center located within the Idaho National Laboratory Site. Sampling activities described in this plan support characterization sampling of new sites, real-time soil spectroscopy during excavation, and confirmation sampling that verifies that the remedial action objectives and remediation goals presented in the Final Record of Decision for Idaho Nuclear Technology and Engineering Center, Operable Unit 3-13 have been met.

  18. May 2011 Groundwater and Surface Water Sampling at the Rio Blanco, Colorado, Site (Data Validation Package)

    SciTech Connect (OSTI)

    2011-12-01

    Annual sampling was conducted at the Rio Blanco, Colorado, site for the Long-Term Hydrologic Monitoring Program May 16-17, 2011, to monitor groundwater and surface water for potential radionuclide contamination. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for the U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from location Johnson Artesian WL. Samples were analyzed by the U.S. Environmental Protection Agency (EPA) Radiation&Indoor Environments National Laboratory in Las Vegas, Nevada. Samples were analyzed for gamma-emitting radionuclides by high-resolution gamma spectrometry, and for tritium using the conventional method. Tritium was not measured using the enrichment method because the EPA laboratory no longer offers that service. Results of this monitoring at the Rio Blanco site demonstrate that groundwater and surface water outside the boundaries have not been affected by project-related contaminants.

  19. Surface plasmon sensing of gas phase contaminants using optical...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Country of Publication: United States Language: English Subject: 72 ... RESONANCE; SENSITIVITY; SIMULATION; TESTING Optical resonance.; Surface Plasmon ...

  20. May 2012 Groundwater and Surface Water Sampling at the Rio Blanco, Colorado, Site (Data Validation Package)

    SciTech Connect (OSTI)

    2012-12-01

    Annual sampling was conducted at the Rio Blanco, Colorado, site for the Long-Term Hydrologic Monitoring Program May 9-10, 2012, to monitor groundwater and surface water for potential radionuclide contamination. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for the U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from location Johnson Artesian WL. Samples were analyzed for gamma-emitting radionuclides by high-resolution gamma spectrometry and for tritium using the conventional and enrichment methods. Results of this monitoring at the Rio Blanco site demonstrate that groundwater and surface water outside the site boundaries have not been affected by project-related contaminants.

  1. Instantaneous and efficient surface wave excitation of a low pressure gas or gases

    DOE Patents [OSTI]

    Levy, Donald J.; Berman, Samuel M.

    1988-01-01

    A system for instantaneously ionizing and continuously delivering energy in the form of surface waves to a low pressure gas or mixture of low pressure gases, comprising a source of rf energy, a discharge container, (such as a fluorescent lamp discharge tube), an rf shield, and a coupling device responsive to rf energy from the source to couple rf energy directly and efficiently to the gas or mixture of gases to ionize at least a portion of the gas or gases and to provide energy to the gas or gases in the form of surface waves. The majority of the rf power is transferred to the gas or gases near the inner surface of the discharge container to efficiently transfer rf energy as excitation energy for at least one of the gases. The most important use of the invention is to provide more efficient fluorescent and/or ultraviolet lamps.

  2. Plasma channel created by ionization of gas by a surface wave

    SciTech Connect (OSTI)

    Konovalov, V. N.; Kuz’min, G. P.; Minaev, I. M. Rukhadze, A. A.; Tikhonevich, O. V.

    2015-09-15

    Conditions for gas ionization in the field of a slow surface wave excited by a microwave source are considered. The gas ionization rate and the plasma density distribution over the radius of the discharge tube were studied by the optical method. The experiments were conducted in a dielectric tube with a radius much smaller than the tube length, the gas pressure being ∼1–3 Torr. It is shown that the stationary distribution of the plasma density is determined by diffusion processes.

  3. Method and apparatus for maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling

    DOE Patents [OSTI]

    Farthing, William Earl [Pinson, AL; Felix, Larry Gordon [Pelham, AL; Snyder, Todd Robert [Birmingham, AL

    2008-02-12

    An apparatus and method for diluting and cooling that is extracted from high temperature and/or high pressure industrial processes. Through a feedback process, a specialized, CFD-modeled dilution cooler is employed along with real-time estimations of the point at which condensation will occur within the dilution cooler to define a level of dilution and diluted gas temperature that results in a gas that can be conveyed to standard gas analyzers that contains no condensed hydrocarbon compounds or condensed moisture.

  4. Method and apparatus maintaining multi-component sample gas constituents in vapor phase during sample extraction and cooling

    DOE Patents [OSTI]

    Farthing, William Earl; Felix, Larry Gordon; Snyder, Todd Robert

    2009-12-15

    An apparatus and method for diluting and cooling that is extracted from high temperature and/or high pressure industrial processes. Through a feedback process, a specialized, CFD-modeled dilution cooler is employed along with real-time estimations of the point at which condensation will occur within the dilution cooler to define a level of dilution and diluted gas temperature that results in a gas that can be conveyed to standard gas analyzers that contains no condensed hydrocarbon compounds or condensed moisture.

  5. Laboratory Studies on Surface Sampling of Bacillus anthracis Contamination: Summary, Gaps, and Recommendations

    SciTech Connect (OSTI)

    Piepel, Gregory F.; Amidan, Brett G.; Hu, Rebecca

    2011-11-28

    This report summarizes previous laboratory studies to characterize the performance of methods for collecting, storing/transporting, processing, and analyzing samples from surfaces contaminated by Bacillus anthracis or related surrogates. The focus is on plate culture and count estimates of surface contamination for swab, wipe, and vacuum samples of porous and nonporous surfaces. Summaries of the previous studies and their results were assessed to identify gaps in information needed as inputs to calculate key parameters critical to risk management in biothreat incidents. One key parameter is the number of samples needed to make characterization or clearance decisions with specified statistical confidence. Other key parameters include the ability to calculate, following contamination incidents, the (1) estimates of Bacillus anthracis contamination, as well as the bias and uncertainties in the estimates, and (2) confidence in characterization and clearance decisions for contaminated or decontaminated buildings. Gaps in knowledge and understanding identified during the summary of the studies are discussed and recommendations are given for future studies.

  6. Rapid Surface Sampling and Archival Record (RSSAR) system. Final report, October 1995--May 1997

    SciTech Connect (OSTI)

    NONE

    1998-12-31

    This report describes the results of Phase 2 efforts to develop a Rapid Surface Sampling and Archival Record (RSSAR) System for the detection of semivolatile organic contaminants on concrete, transite, and metal surfaces. The characterization of equipment and building surfaces for the presence of contaminants as part of building decontamination and decommissioning activities is an immensely large task of concern to both government and industry. Because of the high cost of hazardous waste disposal, old, contaminated buildings cannot simply be demolished and scrapped. Contaminated and clean materials must be clearly identified and segregated so that the clean material can be recycled or reused, if possible, or disposed of more cheaply as nonhazardous waste. DOE has a number of sites requiring surface characterization. These sites are large, contain very heterogeneous patterns of contamination (requiring high sampling density), and will thus necessitate an enormous number of samples to be taken and analyzed. Characterization of building and equipment surfaces will be needed during initial investigations, during cleanup operations, and during the final confirmation process, increasing the total number of samples well beyond that needed for initial characterization. This multiplicity of information places a premium on the ability to handle and track data as efficiently as possible.

  7. Strategies for Detecting Hidden Geothermal Systems by Near-Surface Gas Monitoring

    SciTech Connect (OSTI)

    Lewicki, Jennifer L.; Oldenburg, Curtis M.

    2004-12-15

    environment include (1) the infrared gas analyzer (IRGA) for measurement of concentrations at point locations, (2) the accumulation chamber (AC) method for measuring soil CO2 fluxes at point locations, (3) the eddy covariance (EC) method for measuring net CO2 flux over a given area, (4) hyperspectral imaging of vegetative stress resulting from elevated CO2 concentrations, and (5) light detection and ranging (LIDAR) that can measure CO2 concentrations over an integrated path. Technologies currently in developmental stages that have the potential to be used for CO2 monitoring include tunable lasers for long distance integrated concentration measurements and micro-electronic mechanical systems (MEMS) that can make widespread point measurements. To address the challenge of detecting potentially small-magnitude geothermal CO2 emissions within the natural background variability of CO2, we propose an approach that integrates available detection and monitoring methodologies with statistical analysis and modeling strategies. Within the area targeted for geothermal exploration, point measurements of soil CO2 fluxes and concentrations using the AC method and a portable IRGA, respectively, and measurements of net surface flux using EC should be made. Also, the natural spatial and temporal variability of surface CO2 fluxes and subsurface CO2 concentrations should be quantified within a background area with similar geologic, climatic, and ecosystem characteristics to the area targeted for geothermal exploration. Statistical analyses of data collected from both areas should be used to guide sampling strategy, discern spatial patterns that may be indicative of geothermal CO2 emissions, and assess the presence (or absence) of geothermal CO2 within the natural background variability with a desired confidence level. Once measured CO2 concentrations and fluxes have been determined to be of anomalous geothermal origin with high confidence, more expensive vertical subsurface gas sampling and

  8. Vapor and gas sampling of single-shell tank 241-S-103 using the in situ vapor sampling system

    SciTech Connect (OSTI)

    Lockrem, L.L.

    1997-08-05

    The Vapor Issue Resolution Program tasked the Vapor Team (VT) to collect representative headspace samples from Hanford Site single-shell tank (SST) 241-S-103. This document presents In Situ Vapor Sampling System (ISVS) data resulting from the June 12, 1996 sampling of SST 241-S-103. Analytical results will be presented in separate reports issued by the Pacific Northwest National Laboratory (PNNL) which supplied and analyzed the sample media.

  9. Vapor and gas sampling of the single-shell tank 241-S-101 using the in situ vapor sampling system

    SciTech Connect (OSTI)

    Lockrem, L.L.

    1997-08-05

    The Vapor Issue Resolution Program tasked the Vapor Team (VT) to collect representative headspace samples from Hanford Site single-shell tank (SST) 241-S-101. This document presents In Situ Vapor Sampling System (ISVS) data resulting from the June 6, 1996 sampling of SST 241-S-101. Analytical results will be presented in separate reports issued by the Pacific Northwest National Laboratory (PNNL) which supplied and analyzed the sample media.

  10. Surface analyses of electropolished niobium samples for superconducting radio frequency cavity

    SciTech Connect (OSTI)

    Tyagi, P. V.; Nishiwaki, M.; Saeki, T.; Sawabe, M.; Hayano, H.; Noguchi, T.; Kato, S.

    2010-07-15

    The performance of superconducting radio frequency niobium cavities is sometimes limited by contaminations present on the cavity surface. In the recent years extensive research has been done to enhance the cavity performance by applying improved surface treatments such as mechanical grinding, electropolishing (EP), chemical polishing, tumbling, etc., followed by various rinsing methods such as ultrasonic pure water rinse, alcoholic rinse, high pressure water rinse, hydrogen per oxide rinse, etc. Although good cavity performance has been obtained lately by various post-EP cleaning methods, the detailed nature about the surface contaminants is still not fully characterized. Further efforts in this area are desired. Prior x-ray photoelectron spectroscopy (XPS) analyses of EPed niobium samples treated with fresh EP acid, demonstrated that the surfaces were covered mainly with the niobium oxide (Nb{sub 2}O{sub 5}) along with carbon, in addition a small quantity of sulfur and fluorine were also found in secondary ion mass spectroscopy (SIMS) analysis. In this article, the authors present the analyses of surface contaminations for a series of EPed niobium samples located at various positions of a single cell niobium cavity followed by ultrapure water rinsing as well as our endeavor to understand the aging effect of EP acid solution in terms of contaminations presence at the inner surface of the cavity with the help of surface analytical tools such as XPS, SIMS, and scanning electron microscope at KEK.

  11. Measurement of Fission Gas Release from Irradiated U-Mo Monolithic Fuel Samples

    SciTech Connect (OSTI)

    Burkes, Douglas; Casella, Amanda J.; Casella, Andrew M.; Luscher, Walter G.; Rice, Francine; Pool, Karl N.

    2015-06-01

    The uranium-molybdenum (U-Mo) alloy in a monolithic form has been proposed as one fuel design capable of converting some of the world’s highest power research reactors from the use of high enriched uranium (HEU) to low enriched uranium (LEU). One aspect of the fuel development and qualification process is to demonstrate appropriate understanding of the extent of fission product release from the fuel under anticipated service environments. An apparatus capable of annealing post-irradiated small-scale samples cut from larger fuel segments according to specified thermal profiles under a controlled atmosphere has been installed into a hot cell. Results show that optimized experimental parameters to investigate fission product release from small samples have been established. Initial measurements conducted on aluminum alloy clad uranium-molybdenum monolithic fuel samples reveal three clear fission gas release events over the temperature range of 30-1050 C. The mechanisms responsible for these events are discussed, and the results have been compared with available information in literature.

  12. Measurement of fission gas release from irradiated U–Mo monolithic fuel samples

    SciTech Connect (OSTI)

    Burkes, Douglas E.; Casella, Amanda J.; Casella, Andrew M.; Luscher, Walter G.; Rice, Francine J.; Pool, Karl N.

    2015-06-01

    The uranium–molybdenum (U-Mo) alloy in a monolithic form has been proposed as one fuel design capable of converting some of the world’s highest power research reactors from the use of high enriched uranium (HEU) to low enriched uranium (LEU). One aspect of the fuel development and qualification process is to demonstrate appropriate understanding of the extent of fission product release from the fuel under anticipated service environments. An apparatus capable of heating post-irradiated small-scale samples cut from larger fuel segments according to specified thermal profiles under a controlled atmosphere has been installed into a hot cell. Results show that optimized experimental parameters to investigate fission product release from small samples have been established. Initial measurements conducted on aluminum alloy clad uranium–molybdenum monolithic fuel samples reveal three clear fission gas release events over the temperature range of 30-1000 °C. The mechanisms responsible for these events are discussed, and the results have been compared with available information in the literature.

  13. CORRELATION BETWEEN ENVIRONMENT AND GAS METALLICITY FOR STAR-FORMING GALAXIES IN THE MAIN GALAXY SAMPLE OF SDSS DR7

    SciTech Connect (OSTI)

    Deng Xinfa

    2011-05-15

    Using two volume-limited samples of the Main Galaxy sample of the Sloan Digital Sky Survey Data Release 7 with luminosities of -20.5 {<=} M{sub r} {<=} -18.5 and -22.5 {<=} M{sub r} {<=} -20.5, respectively, I explore the correlation between environment and gas metallicity for star-forming galaxies. Overall, results indicate that galaxies in the lowest density regime preferentially have lower gas metallicity than galaxies in the densest regimes, and that the correlation between environment and gas metallicity is fundamental.

  14. Control of the positional relationship between a sample collection instrument and a surface to be analyzed during a sampling procedure with image analysis

    DOE Patents [OSTI]

    Van Berkel, Gary J.; Kertesz, Vilmos

    2011-08-09

    A system and method utilizes an image analysis approach for controlling the collection instrument-to-surface distance in a sampling system for use, for example, with mass spectrometric detection. Such an approach involves the capturing of an image of the collection instrument or the shadow thereof cast across the surface and the utilization of line average brightness (LAB) techniques to determine the actual distance between the collection instrument and the surface. The actual distance is subsequently compared to a target distance for re-optimization, as necessary, of the collection instrument-to-surface during an automated surface sampling operation.

  15. Detailed Surface Analysis Of Incremental Centrifugal Barrel Polishing (CBP) Of Single-Crystal Niobium Samples

    SciTech Connect (OSTI)

    Palczewski, Ari D.; Hui Tian; Trofimova, Olga; Reece, Charles E.

    2011-07-01

    We performed Centrifugal Barrel Polishing (CBP) on single crystal niobium samples/coupons housed in a stainless steel sample holder following the polishing recipe developed at Fermi Lab (FNAL) in 2011 \\cite{C. A. Cooper 2011}. Post CBP, the sample coupons were analyzed for surface roughness, crystal composition and structure, and particle contamination. Following the initial analysis each coupon was high pressure rinsed (HRP) and analyzed for the effectiveness of contamination removal. We were able to obtain the mirror like surface finish after the final stage of tumbling, although some defects and embedded particles remained. In addition, standard HPR appears to have little effect on removing embedded particles which remain after each tumbling step, although final polishing media removal was partially affected by standard/extended HPR.

  16. Application of a dry-gas meter for measuring air sample volumes in an ambient air monitoring network

    SciTech Connect (OSTI)

    Fritz, Brad G.

    2009-05-24

    Ambient air monitoring for non-research applications (e.g. compliance) occurs at locations throughout the world. Often, the air sampling systems employed for these purposes employee simple yet robust equipment capable of handling the rigors of demanding sampling schedules. At the Hanford Site (near Richland, Washington) concentrations of radionuclides in ambient air are monitored continuously at 44 locations. In 2004, mechanical dry-gas meters were incorporated into the Hanford Site ambient air sample collection system to allow the direct measurement of sample volumes. These meters replaced a portable airflow measurement system that required two manual flow measurements and a sample duration measurement to determine sample volume. A six-month evaluation of the dry-gas meters compared sample volumes calculated using the original flow rate method to the direct sample volume measurement (new method). The results of the evaluation indicate that use of the dry-gas meters result in accurate sample volume measurements and provide greater confidence in the measured sample volumes. In several years of in-network use, the meters have proven to be reliable and have resulted in an improved sampling system.

  17. Wang-Landau sampling of the interplay between surface adsorption and folding of HP lattice proteins

    SciTech Connect (OSTI)

    Li, Ying Wai [ORNL] [ORNL; Wuest, Thomas [Swiss Federal Research Institute, Switzerland] [Swiss Federal Research Institute, Switzerland; Landau, David P [University of Georgia, Athens, GA] [University of Georgia, Athens, GA

    2014-01-01

    Generic features associated with the adsorption of proteins on solid surfaces are reviewed within the framework of the hydrophobic-polar (HP) lattice protein model. The thermodynamic behavior and structural properties of various HP protein sequences interacting with attractive surfaces have been studied using extensive Wang-Landau sampling with different types of surfaces, each of which attracts either: all monomers, only hydrophobic (H) monomers, or only polar (P) monomers, respectively. Consequently, different types of folding behavior occur for varied surface strengths. Analysis of the combined patterns of various structural observables, e.g., the derivatives of the numbers of interaction contacts, together with the specific heat, leads to the identification of fundamental categories of folding and transition hierarchies. We also inferred a connection between the transition categories and the relative surface strengths, i.e., the ratios of the surface attractive strengths to the intra-chain attraction among H monomers. We thus believe that the folding hierarchies and identification scheme are generic for different HP sequences interacting with attractive surfaces, regardless of the chain length, sequence, or surface attraction.

  18. A Gas-Cooled Reactor Surface Power System

    SciTech Connect (OSTI)

    Harms, G.A.; Lenard, R.X.; Lipinski, R.J.; Wright, S.A.

    1998-11-09

    A human outpost on Mars requires plentiful power to assure survival of the astronauts. Anywhere from 50 to 500 kW of electric power (kWe) will be needed, depending on the number of astronauts, level of scientific activity, and life- cycle closure desired. This paper describes a 250-kWe power system based on a gas-cooled nuclear reactor with a recuperated closed Brayton cycle conversion system. The design draws upon the extensive data and engineering experience developed under the various high-temperature gas cooled reactor programs and under the SP-100 program. The reactor core is similar in power and size to the research reactors found on numerous university campuses. The fuel is uranium nitide clad in Nb 1 %Zr, which has been extensively tested under the SP-I 00 program The fiel rods are arranged in a hexagonal array within a BeO block. The BeO softens the spectrum, allowing better use of the fbel and stabilizing the geometty against deformation during impact or other loadings. The system has a negative temperature feedback coefficient so that the power level will automatically follow a variable load without the need for continuous adjustment of control elements. Waste heat is removed by an air-cooled heat exchanger using cold Martian air. The amount of radioactivity in the reactor at launch is very small (less than a Curie, and about equal to a truckload of uranium ore). The system will need to be engineered so that criticality cannot occur for any launch accident. This system is also adaptable for electric propulsion or life-support during transit to and from Mars.

  19. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Groundwater, Surface Water, Produced Water, and Natural Gas Sampling at the Gasbuggy, New Mexico, Site October 2014 LMSGSBS00614 Available for sale to the public from: U.S. ...

  20. TRITIUM UNCERTAINTY ANALYSIS FOR SURFACE WATER SAMPLES AT THE SAVANNAH RIVER SITE

    SciTech Connect (OSTI)

    Atkinson, R.

    2012-07-31

    Radiochemical analyses of surface water samples, in the framework of Environmental Monitoring, have associated uncertainties for the radioisotopic results reported. These uncertainty analyses pertain to the tritium results from surface water samples collected at five locations on the Savannah River near the U.S. Department of Energy's Savannah River Site (SRS). Uncertainties can result from the field-sampling routine, can be incurred during transport due to the physical properties of the sample, from equipment limitations, and from the measurement instrumentation used. The uncertainty reported by the SRS in their Annual Site Environmental Report currently considers only the counting uncertainty in the measurements, which is the standard reporting protocol for radioanalytical chemistry results. The focus of this work is to provide an overview of all uncertainty components associated with SRS tritium measurements, estimate the total uncertainty according to ISO 17025, and to propose additional experiments to verify some of the estimated uncertainties. The main uncertainty components discovered and investigated in this paper are tritium absorption or desorption in the sample container, HTO/H{sub 2}O isotopic effect during distillation, pipette volume, and tritium standard uncertainty. The goal is to quantify these uncertainties and to establish a combined uncertainty in order to increase the scientific depth of the SRS Annual Site Environmental Report.

  1. Geochemical Analyses of Surface and Shallow Gas Flux and Composition Over a Proposed Carbon Sequestration Site in Eastern Kentucky

    SciTech Connect (OSTI)

    Thomas Parris; Michael Solis; Kathryn Takacs

    2009-12-31

    Using soil gas chemistry to detect leakage from underground reservoirs (i.e. microseepage) requires that the natural range of soil gas flux and chemistry be fully characterized. To meet this need, soil gas flux (CO{sub 2}, CH{sub 4}) and the bulk (CO{sub 2}, CH{sub 4}) and isotopic chemistry ({delta}{sup 13}C-CO2) of shallow soil gases (<1 m, 3.3 ft) were measured at 25 locations distributed among two active oil and gas fields, an active strip mine, and a relatively undisturbed research forest in eastern Kentucky. The measurements apportion the biologic, atmospheric, and geologic influences on soil gas composition under varying degrees of human surface disturbance. The measurements also highlight potential challenges in using soil gas chemistry as a monitoring tool where the surface cover consists of reclaimed mine land or is underlain by shallow coals. For example, enrichment of ({delta}{sup 13}C-CO2) and high CH{sub 4} concentrations in soils have been historically used as indicators of microseepage, but in the reclaimed mine lands similar soil chemistry characteristics likely result from dissolution of carbonate cement in siliciclastic clasts having {delta}{sup 13}C values close to 0{per_thousand} and degassing of coal fragments. The gases accumulate in the reclaimed mine land soils because intense compaction reduces soil permeability, thereby impeding equilibration with the atmosphere. Consequently, the reclaimed mine lands provide a false microseepage anomaly. Further potential challenges arise from low permeability zones associated with compacted soils in reclaimed mine lands and shallow coals in undisturbed areas that might impede upward gas migration. To investigate the effect of these materials on gas migration and composition, four 10 m (33 ft) deep monitoring wells were drilled in reclaimed mine material and in undisturbed soils with and without coals. The wells, configured with sampling zones at discrete intervals, show the persistence of some of the

  2. Removing a sheet from the surface of a melt using gas jets

    DOE Patents [OSTI]

    Kellerman, Peter L; Thronson, Gregory D; Sun, Dawei

    2014-04-01

    In one embodiment, a sheet production apparatus comprises a vessel configured to hold a melt of a material. A cooling plate is disposed proximate the melt and is configured to form a sheet of the material on the melt. A first gas jet is configured to direct a gas toward an edge of the vessel. A sheet of a material is translated horizontally on a surface of the melt and the sheet is removed from the melt. The first gas jet may be directed at the meniscus and may stabilize this meniscus or increase local pressure within the meniscus.

  3. Analysis of Cloud Variability and Sampling Errors in Surface and Satellite Mesurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Analysis of Cloud Variability and Sampling Errors in Surface and Satellite Measurements Z. Li, M. C. Cribb, and F.-L. Chang Earth System Science Interdisciplinary Center University of Maryland College Park, Maryland A. P. Trishchenko and Y. Luo Canada Centre for Remote Sensing Ottawa, Ontario, Canada Introduction Radiation measurements have been widely employed for evaluating cloud parameterization schemes and model simulation results. As the most comprehensive program aiming to improve cloud

  4. Laboratory studies on surface sampling of Bacillus anthracis contamination: summary, gaps, and recommendations

    SciTech Connect (OSTI)

    Piepel, Gregory F.; Amidan, Brett G.; Hu, Rebecca

    2012-12-01

    This article summarizes previous laboratory studies to characterize the performance of methods for collecting, storing/transporting, processing, and analyzing samples from surfaces contaminated by Bacillus anthracis or related surrogates. The focus is on plate culture and count estimates of surface contamination for swab, wipe, and vacuum samples of porous and nonporous surfaces. Summaries of the previous studies and their results were assessed to identify gaps in information needed as inputs to calculate key parameters critical to risk management in biothreat incidents. One key parameter is the number of samples needed to make characterization or clearance decisions with specified statistical confidence. Other key parameters include the ability to calculate, following contamination incidents, the 1) estimates of Bacillus anthracis contamination, as well as the bias and uncertainties in the estimates, and 2) confidence in characterization and clearance decisions for contaminated or decontaminated buildings. Gaps in knowledge and understanding identified during the summary of the studies are discussed. Recommendations are given for future evaluations of data from existing studies and possible new studies.

  5. Sampling and Analysis of the Headspace Gas in 3013 Type Plutonium Storage Containers at Los Alamos National Laboratory

    SciTech Connect (OSTI)

    Jackson, Jay M.; Berg, John M.; Hill, Dallas D.; Worl, Laura A.; Veirs, Douglas K.

    2012-07-11

    Department of Energy (DOE) sites have packaged approximately 5200 3013 containers to date. One of the requirements specified in DOESTD-3013, which specifies requirements for packaging plutonium bearing materials, is that the material be no greater than 0.5 weight percent moisture. The containers are robust, nested, welded vessels. A shelf life surveillance program was established to monitor these cans over their 50 year design life. In the event pressurization is detected by radiography, it will be necessary to obtain a head space gas sample from the pressurized container. This technique is also useful to study the head space gas in cans selected for random destructive evaluation. The atmosphere is sampled and the hydrogen to oxygen ratio is measured to determine the effects of radiolysis on the moisture in the container. A system capable of penetrating all layers of a 3013 container assembly and obtaining a viable sample of the enclosed gas and an estimate of internal pressure was designed.

  6. May and June 2015 Groundwater and Surface Water Sampling at the...

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma Interference Check Sample Analysis Interference check samples ... Inductively Coupled Plasma Interference Check Sample Analysis Interference check samples ...

  7. Application of finite element, global polynomial, and kriging response surfaces in Progressive Lattice Sampling designs

    SciTech Connect (OSTI)

    ROMERO,VICENTE J.; SWILER,LAURA PAINTON; GIUNTA,ANTHONY A.

    2000-04-25

    This paper examines the modeling accuracy of finite element interpolation, kriging, and polynomial regression used in conjunction with the Progressive Lattice Sampling (PLS) incremental design-of-experiments approach. PLS is a paradigm for sampling a deterministic hypercubic parameter space by placing and incrementally adding samples in a manner intended to maximally reduce lack of knowledge in the parameter space. When combined with suitable interpolation methods, PLS is a formulation for progressive construction of response surface approximations (RSA) in which the RSA are efficiently upgradable, and upon upgrading, offer convergence information essential in estimating error introduced by the use of RSA in the problem. The three interpolation methods tried here are examined for performance in replicating an analytic test function as measured by several different indicators. The process described here provides a framework for future studies using other interpolation schemes, test functions, and measures of approximation quality.

  8. Materials processing issues for non-destructive laser gas sampling (NDLGS)

    SciTech Connect (OSTI)

    Lienert, Thomas J [Los Alamos National Laboratory

    2010-12-09

    The Non-Destructive Laser Gas Sampling (NDLGS) process essentially involves three steps: (1) laser drilling through the top of a crimped tube made of 304L stainles steel (Hammar and Svennson Cr{sub eq}/Ni{sub eq} = 1.55, produced in 1985); (2) gas sampling; and (3) laser re-welding of the crimp. All three steps are performed in a sealed chamber with a fused silica window under controlled vacuum conditions. Quality requirements for successful processing call for a hermetic re-weld with no cracks or other defects in the fusion zone or HAZ. It has been well established that austenitic stainless steels ({gamma}-SS), such as 304L, can suffer from solidification cracking if their Cr{sub eq}/Ni{sub eq} is below a critical value that causes solidification to occur as austenite (fcc structure) and their combined impurity level (%P+%S) is above {approx}0.02%. Conversely, for Cr{sub eq}/Ni{sub eq} values above the critical level, solidification occurs as ferrite (bcc structure), and cracking propensity is greatly reduced at all combined impurity levels. The consensus of results from studies of several researchers starting in the late 1970's indicates that the critical Cr{sub eq}/Ni{sub eq} value is {approx}1.5 for arc welds. However, more recent studies by the author and others show that the critical Cr{sub eq}/Ni{sub eq} value increases to {approx}1 .6 for weld processes with very rapid thermal cycles, such as the pulsed Nd:YAG laser beam welding (LBW) process used here. Initial attempts at NDLGS using pulsed LBW resulted in considerable solidification cracking, consistent with the results of work discussed above. After a brief introduction to the welding metallurgy of {gamma}-SS, this presentation will review the results of a study aimed at developing a production-ready process that eliminates cracking. The solution to the cracking issue, developed at LANL, involved locally augmenting the Cr content by applying either Cr or a Cr-rich stainless steel (ER 312) to the top of

  9. A Principle Component Analysis of Galaxy Properties from a Large, Gas-Selected Sample

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chang, Yu-Yen; Chao, Rikon; Wang, Wei-Hao; Chen, Pisin

    2012-01-01

    Disney emore » t al. (2008) have found a striking correlation among global parameters of H i -selected galaxies and concluded that this is in conflict with the CDM model. Considering the importance of the issue, we reinvestigate the problem using the principal component analysis on a fivefold larger sample and additional near-infrared data. We use databases from the Arecibo Legacy Fast Arecibo L -band Feed Array Survey for the gas properties, the Sloan Digital Sky Survey for the optical properties, and the Two Micron All Sky Survey for the near-infrared properties. We confirm that the parameters are indeed correlated where a single physical parameter can explain 83% of the variations. When color ( g - i ) is included, the first component still dominates but it develops a second principal component. In addition, the near-infrared color ( i - J ) shows an obvious second principal component that might provide evidence of the complex old star formation. Based on our data, we suggest that it is premature to pronounce the failure of the CDM model and it motivates more theoretical work.« less

  10. Electrochemical machining process for forming surface roughness elements on a gas turbine shroud

    DOE Patents [OSTI]

    Lee, Ching-Pang; Johnson, Robert Alan; Wei, Bin; Wang, Hsin-Pang

    2002-01-01

    The back side recessed cooling surface of a shroud defining in part the hot gas path of a turbine is electrochemically machined to provide surface roughness elements and spaces therebetween to increase the heat transfer coefficient. To accomplish this, an electrode with insulating dielectric portions and non-insulating portions is disposed in opposition to the cooling surface. By passing an electrolyte between the cooling surface and electrode and applying an electrical current between the electrode and a shroud, roughness elements and spaces therebetween are formed in the cooling surface in opposition to the insulating and non-insulating portions of the electrode, hence increasing the surface area and heat transfer coefficient of the shroud.

  11. Control of the positional relationship between a sample collection instrument and a surface to be analyzed during a sampling procedure using a laser sensor

    DOE Patents [OSTI]

    Van Berkel, Gary J.; Kertesz, Vilmos

    2012-02-21

    A system and method utilizes distance-measuring equipment including a laser sensor for controlling the collection instrument-to-surface distance during a sample collection process for use, for example, with mass spectrometric detection. The laser sensor is arranged in a fixed positional relationship with the collection instrument, and a signal is generated by way of the laser sensor which corresponds to the actual distance between the laser sensor and the surface. The actual distance between the laser sensor and the surface is compared to a target distance between the laser sensor and the surface when the collection instrument is arranged at a desired distance from the surface for sample collecting purposes, and adjustments are made, if necessary, so that the actual distance approaches the target distance.

  12. Tank 241-BY-111 headspace gas and vapor characterization results for samples collected in May 1994 and November 1994

    SciTech Connect (OSTI)

    Huckaby, J.L.; Bratzel, D.R.

    1995-09-28

    Significant changes have been made to all of the original vapor characterization reports. This report documents specific headspace gas and vapor characterization results for all vapor sampling events to date. In addition, changes have been made to the original vapor reports to qualify the data based on quality assurance issues associated with the performing laboratories

  13. Tank 241-C-111 headspace gas and vapor characterization results for samples collected in August 1993 and September 1994

    SciTech Connect (OSTI)

    Huckaby, J.L.; Bratzel, D.R.

    1995-09-01

    Significant changes have been made to all of the original vapor characterization reports. This report documents specific headspace gas and vapor characterization results for all vapor sampling events to date. In addition, changes have been made to the original vapor reports to qualify the data based on quality assurance issues associated with the performing laboratories.

  14. Tank 241-BY-106 headspace gas and vapor characterization results for samples collected in May 1994 and July 1994

    SciTech Connect (OSTI)

    Huckaby, J.L.; Bratzel, D.R.

    1995-09-01

    Significant changes have been made to all of the original vapor characterization reports. This report documents specific headspace gas and vapor characterization results for all vapor sampling events to date. In addition, changes have been made to the original vapor reports to qualify the data based on quality assurance issues associated with the performing laboratories.

  15. Surface water and atmospheric carbon dioxide and nitrous oxide observations by shipboard automated gas chromatography: Results from expeditions between 1977 and 1990

    SciTech Connect (OSTI)

    Weiss, R.F.; Van Woy, F.A.; Salameh, P.K.; Sepanski, R.J.

    1992-12-01

    This document presents the results of surface water and atmospheric carbon dioxide (CO{sub 2}) and nitrous oxide (N{sub 2}O) measurements carried out by shipboard gas chromatography over the period 1977--1990. These data include results from 11 different oceanic surveys for a total of 41 expedition legs. Collectively, they represent a globally distributed sampling that includes locations in the Atlantic, Pacific, Indian, and Southern Oceans, as well as the Mediterranean and Red Seas. The measurements were made by an automated high-precision shipboard gas chromatographic system developed during the late 1970s and used extensively over the intervening years. This instrument measures CO{sub 2} by flame ionization after quantitative reaction to methane in a stream of hydrogen. Nitrous oxide is measured by a separate electron capture detector. The chromatographic system measures 196 dry-gas samples a day, divided equally among the atmosphere, gas equilibrated with surface water, a low-range gas standard, and a high-range gas standard.

  16. Surface water and atmospheric carbon dioxide and nitrous oxide observations by shipboard automated gas chromatography: Results from expeditions between 1977 and 1990

    SciTech Connect (OSTI)

    Weiss, R.F.; Van Woy, F.A.; Salameh, P.K. ); Sepanski, R.J. . Energy, Environment and Resources Center)

    1992-12-01

    This document presents the results of surface water and atmospheric carbon dioxide (CO[sub 2]) and nitrous oxide (N[sub 2]O) measurements carried out by shipboard gas chromatography over the period 1977--1990. These data include results from 11 different oceanic surveys for a total of 41 expedition legs. Collectively, they represent a globally distributed sampling that includes locations in the Atlantic, Pacific, Indian, and Southern Oceans, as well as the Mediterranean and Red Seas. The measurements were made by an automated high-precision shipboard gas chromatographic system developed during the late 1970s and used extensively over the intervening years. This instrument measures CO[sub 2] by flame ionization after quantitative reaction to methane in a stream of hydrogen. Nitrous oxide is measured by a separate electron capture detector. The chromatographic system measures 196 dry-gas samples a day, divided equally among the atmosphere, gas equilibrated with surface water, a low-range gas standard, and a high-range gas standard.

  17. Analysis of core samples from the BPXA-DOE-USGS Mount Elbert gas hydrate stratigraphic test well: Insights into core disturbance and handling

    SciTech Connect (OSTI)

    Kneafsey, Timothy J.; Lu, Hailong; Winters, William; Boswell, Ray; Hunter, Robert; Collett, Timothy S.

    2009-09-01

    Collecting and preserving undamaged core samples containing gas hydrates from depth is difficult because of the pressure and temperature changes encountered upon retrieval. Hydrate-bearing core samples were collected at the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well in February 2007. Coring was performed while using a custom oil-based drilling mud, and the cores were retrieved by a wireline. The samples were characterized and subsampled at the surface under ambient winter arctic conditions. Samples thought to be hydrate bearing were preserved either by immersion in liquid nitrogen (LN), or by storage under methane pressure at ambient arctic conditions, and later depressurized and immersed in LN. Eleven core samples from hydrate-bearing zones were scanned using x-ray computed tomography to examine core structure and homogeneity. Features observed include radial fractures, spalling-type fractures, and reduced density near the periphery. These features were induced during sample collection, handling, and preservation. Isotopic analysis of the methane from hydrate in an initially LN-preserved core and a pressure-preserved core indicate that secondary hydrate formation occurred throughout the pressurized core, whereas none occurred in the LN-preserved core, however no hydrate was found near the periphery of the LN-preserved core. To replicate some aspects of the preservation methods, natural and laboratory-made saturated porous media samples were frozen in a variety of ways, with radial fractures observed in some LN-frozen sands, and needle-like ice crystals forming in slowly frozen clay-rich sediments. Suggestions for hydrate-bearing core preservation are presented.

  18. Examination of core samples from the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope: Effects of retrieval and preservation

    SciTech Connect (OSTI)

    Kneafsey, T.J.; Liu, T.J. H.; Winters, W.; Boswell, R.; Hunter, R.; Collett, T.S.

    2011-06-01

    Collecting and preserving undamaged core samples containing gas hydrates from depth is difficult because of the pressure and temperature changes encountered upon retrieval. Hydrate-bearing core samples were collected at the BPXA-DOE-USGS Mount Elbert Gas Hydrate Stratigraphic Test Well in February 2007. Coring was performed while using a custom oil-based drilling mud, and the cores were retrieved by a wireline. The samples were characterized and subsampled at the surface under ambient winter arctic conditions. Samples thought to be hydrate bearing were preserved either by immersion in liquid nitrogen (LN), or by storage under methane pressure at ambient arctic conditions, and later depressurized and immersed in LN. Eleven core samples from hydrate-bearing zones were scanned using x-ray computed tomography to examine core structure and homogeneity. Features observed include radial fractures, spalling-type fractures, and reduced density near the periphery. These features were induced during sample collection, handling, and preservation. Isotopic analysis of the methane from hydrate in an initially LN-preserved core and a pressure-preserved core indicate that secondary hydrate formation occurred throughout the pressurized core, whereas none occurred in the LN-preserved core, however no hydrate was found near the periphery of the LN-preserved core. To replicate some aspects of the preservation methods, natural and laboratory-made saturated porous media samples were frozen in a variety of ways, with radial fractures observed in some LN-frozen sands, and needle-like ice crystals forming in slowly frozen clay-rich sediments. Suggestions for hydrate-bearing core preservation are presented.

  19. Surface Cleaning Techniques: Ultra-Trace ICP-MS Sample Preparation and Assay of HDPE

    SciTech Connect (OSTI)

    Overman, Nicole R.; Hoppe, Eric W.; Addleman, Raymond S.

    2013-06-01

    The world’s most sensitive radiation detection and assay systems depend upon ultra-low background (ULB) materials to reduce unwanted radiological backgrounds. Herein, we evaluate methods to clean HDPE, a material of interest to ULB systems and the means to provide rapid assay of surface and bulk contamination. ULB level material and ultra-trace level detection of actinide elements is difficult to attain, due to the introduction of contamination from sample preparation equipment such as pipette tips, sample vials, forceps, etc. and airborne particulate. To date, literature available on the cleaning of such polymeric materials and equipment for ULB applications and ultra-trace analyses is limited. For these reasons, a study has been performed to identify an effective way to remove surface contamination from polymers in an effort to provide improved instrumental detection limits. Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) was utilized to assess the effectiveness of a variety of leachate solutions for removal of inorganic uranium and thorium surface contamination from polymers, specifically high density polyethylene (HDPE). HDPE leaching procedures were tested to optimize contaminant removal of thorium and uranium. Calibration curves for thorium and uranium ranged from 15 ppq (fg/mL) to 1 ppt (pg/mL). Detection limits were calculated at 6 ppq for uranium and 7 ppq for thorium. Results showed the most effective leaching reagent to be clean 6 M nitric acid for 72 hour exposures. Contamination levels for uranium and thorium found in the leachate solutions were significant for ultralow level radiation detection applications.

  20. Enhanced convective and film boiling heat transfer by surface gas injection

    SciTech Connect (OSTI)

    Duignan, M.R.; Greene, G.A. ); Irvine, T.F., Jr. . Dept. of Mechanical Engineering)

    1992-04-01

    Heat transfer measurements were made for stable film boiling of water over a horizontal, flat stainless steel plate from the minimum film boiling point temperature, T{sub SURFACE} {approximately}500K, to T{sub SURFACE} {approximately}950K. The pressure at the plate was approximately 1 atmosphere and the temperature of the water pool was maintained at saturation. The data were compared to the Berenson film-boiling model, which was developed for minimum film-boiling-point conditions. The model accurately represented the data near the minimum film-boiling point and at the highest temperatures measured, as long it was corrected for the heat transferred by radiation. On the average, the experimental data lay within {plus minus}7% of the model. Measurements of heat transfer were made without film boiling for nitrogen jetting into an overlying pool of water from nine 1-mm- diameter holes, drilled in the heat transfer plate. The heat flux was maintained constant at approximately 26.4 kW/m{sup 2}. For water-pool heights of less than 6cm the heat transfer coefficient deceased linearly with a decrease in heights. Above 6cm the heat transfer coefficient was unaffected. For the entire range of gas velocities measured (0 to 8.5 cm/s), the magnitude of the magnitude of the heat transfer coefficient only changed by approximately 20%. The heat transfer data bound the Konsetov model for turbulent pool heat transfer which was developed for vertical heat transfer surfaces. This agreement suggests that surface orientation may not be important when the gas jets do not locally affect the surface heat transfer. Finally, a database was developed for heat transfer from the plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface. 60 refs.

  1. Enhanced convective and film boiling heat transfer by surface gas injection

    SciTech Connect (OSTI)

    Duignan, M.R.; Greene, G.A.; Irvine, T.F., Jr.

    1992-04-01

    Heat transfer measurements were made for stable film boiling of water over a horizontal, flat stainless steel plate from the minimum film boiling point temperature, T{sub SURFACE} {approximately}500K, to T{sub SURFACE} {approximately}950K. The pressure at the plate was approximately 1 atmosphere and the temperature of the water pool was maintained at saturation. The data were compared to the Berenson film-boiling model, which was developed for minimum film-boiling-point conditions. The model accurately represented the data near the minimum film-boiling point and at the highest temperatures measured, as long it was corrected for the heat transferred by radiation. On the average, the experimental data lay within {plus_minus}7% of the model. Measurements of heat transfer were made without film boiling for nitrogen jetting into an overlying pool of water from nine 1-mm- diameter holes, drilled in the heat transfer plate. The heat flux was maintained constant at approximately 26.4 kW/m{sup 2}. For water-pool heights of less than 6cm the heat transfer coefficient deceased linearly with a decrease in heights. Above 6cm the heat transfer coefficient was unaffected. For the entire range of gas velocities measured [0 to 8.5 cm/s], the magnitude of the magnitude of the heat transfer coefficient only changed by approximately 20%. The heat transfer data bound the Konsetov model for turbulent pool heat transfer which was developed for vertical heat transfer surfaces. This agreement suggests that surface orientation may not be important when the gas jets do not locally affect the surface heat transfer. Finally, a database was developed for heat transfer from the plate with both film boiling and gas jetting occurring simultaneously, in a pool of water maintained at its saturation temperature. The effect of passing nitrogen through established film boiling is to increase the heat transfer from that surface. 60 refs.

  2. Performances of a bent-crystal spectrometer adapted to resonant x-ray emission measurements on gas-phase samples

    SciTech Connect (OSTI)

    Journel, Loiec; El Khoury, Lara; Marin, Thierry; Guillemin, Renaud; Carniato, Stephane; Avila, Antoine; Delaunay, Renaud; Hague, Coryn F.; Simon, Marc

    2009-09-15

    We describe a bent-crystal spectrometer adapted to measure x-ray emission resulting from core-level excitation of gas-phase molecules in the 0.8-8 keV energy range. The spectrometer is based on the Johann principle, and uses a microfocused photon beam to provide high-resolution (resolving power of {approx}7500). A gas cell was designed to hold a high-pressure (300 mbar) sample of gas while maintaining a high vacuum (10{sup -9} mbar) in the chamber. The cell was designed to optimize the counting rate (2000 cts/s at the maximum of the Cl K{alpha} emission line), while minimizing self-absorption. Example of the K{alpha} emission lines of CH{sub 3}Cl molecules is presented to illustrate the capabilities of this new instrument.

  3. A CORRELATION BETWEEN SURFACE DENSITIES OF YOUNG STELLAR OBJECTS AND GAS IN EIGHT NEARBY MOLECULAR CLOUDS

    SciTech Connect (OSTI)

    Gutermuth, R. A.; Pipher, J. L.; Megeath, S. T.; Allen, T. S.; Myers, P. C.; Allen, L. E.

    2011-10-01

    We report the discovery and characterization of a power-law correlation between the local surface densities of Spitzer-identified, dusty young stellar objects (YSOs) and the column density of gas (as traced by near-IR extinction) in eight molecular clouds within 1 kpc and with 100 or more known YSOs. This correlation, which appears in data smoothed over size scales of {approx}1 pc, varies in quality from cloud to cloud; those clouds with tight correlations, MonR2 and Ophiuchus, are fit with power laws of slope 2.67 and 1.87, respectively. The spread in the correlation is attributed primarily to local gas disruption by stars that formed there or to the presence of very young subregions at the onset of star formation. We explore the ratio of the number of Class II to Class I sources, a proxy for the star formation age of a region, as a function of gas column density; this analysis reveals a declining Class II to Class I ratio with increasing column density. We show that the observed star-gas correlation is consistent with a star formation law where the star formation rate per area varies with the gas column density squared. We also propose a simple picture of thermal fragmentation of dense gas in an isothermal, self-gravitating layer as an explanation for the power law. Finally, we briefly compare the star-gas correlation and its implied star formation law with other recent proposed of star formation laws at similar and larger size scales from nearby star-forming regions.

  4. Accelerating ab initio path integral molecular dynamics with multilevel sampling of potential surface

    SciTech Connect (OSTI)

    Geng, Hua Y.

    2015-02-15

    A multilevel approach to sample the potential energy surface in a path integral formalism is proposed. The purpose is to reduce the required number of ab initio evaluations of energy and forces in ab initio path integral molecular dynamics (AI-PIMD) simulation, without compromising the overall accuracy. To validate the method, the internal energy and free energy of an Einstein crystal are calculated and compared with the analytical solutions. As a preliminary application, we assess the performance of the method in a realistic model—the FCC phase of dense atomic hydrogen, in which the calculated result shows that the acceleration rate is about 3 to 4-fold for a two-level implementation, and can be increased up to 10 times if extrapolation is used. With only 16 beads used for the ab initio potential sampling, this method gives a well converged internal energy. The residual error in pressure is just about 3 GPa, whereas it is about 20 GPa for a plain AI-PIMD calculation with the same number of beads. The vibrational free energy of the FCC phase of dense hydrogen at 300 K is also calculated with an AI-PIMD thermodynamic integration method, which gives a result of about 0.51 eV/proton at a density of r{sub s}=0.912.

  5. False negative rate and other performance measures of a sponge-wipe surface sampling method for low contaminant concentrations.

    SciTech Connect (OSTI)

    Einfeld, Wayne; Krauter, Paula A.; Boucher, Raymond M.; Tezak, Mathew; Amidan, Brett G.; Piepel, Greg F.

    2011-05-01

    Recovery of spores from environmental surfaces is known to vary due to sampling methodology, techniques, spore size and characteristics, surface materials, and environmental conditions. A series of tests were performed to evaluate a new, validated sponge-wipe method. Specific factors evaluated were the effects of contaminant concentrations and surface materials on recovery efficiency (RE), false negative rate (FNR), limit of detection (LOD) - and the uncertainties of these quantities. Ceramic tile and stainless steel had the highest mean RE values (48.9 and 48.1%, respectively). Faux leather, vinyl tile, and painted wood had mean RE values of 30.3, 25.6, and 25.5, respectively, while plastic had the lowest mean RE (9.8%). Results show a roughly linear dependence of surface roughness on RE, where the smoothest surfaces have the highest mean RE values. REs were not influenced by the low spore concentrations tested (3 x 10{sup -3} to 1.86 CFU/cm{sup 2}). The FNR data were consistent with RE data, showing a trend of smoother surfaces resulting in higher REs and lower FNRs. Stainless steel generally had the lowest mean FNR (0.123) and plastic had the highest mean FNR (0.479). The LOD{sub 90} varied with surface material, from 0.015 CFU/cm{sup 2} on stainless steel up to 0.039 on plastic. Selecting sampling locations on the basis of surface roughness and using roughness to interpret spore recovery data can improve sampling. Further, FNR values, calculated as a function of concentration and surface material, can be used pre-sampling to calculate the numbers of samples for statistical sampling plans with desired performance, and post-sampling to calculate the confidence in characterization and clearance decisions.

  6. A safety assessment of rotary mode core sampling in flammable gas single shell tanks: Hanford Site, Richland, Washington

    SciTech Connect (OSTI)

    Raymond, R.E.

    1996-04-15

    This safety assessment (SA) addresses each of the required elements associated with the installation, operation, and removal of a rotary-mode core sampling (RMCS) device in flammable-gas single-shell tanks (SSTs). The RMCS operations are needed in order to retrieve waste samples from SSTs with hard layers of waste for which push-mode sampling is not adequate for sampling. In this SA, potential hazards associated with the proposed action were identified and evaluated systematically. Several potential accident cases that could result in radiological or toxicological gas releases were identified and analyzed and their consequences assessed. Administrative controls, procedures and design changes required to eliminate or reduce the potential of hazards were identified. The accidents were analyzed under nine categories, four of which were burn scenarios. In SSTS, burn accidents result in unacceptable consequences because of a potential dome collapse. The accidents in which an aboveground burn propagates into the dome space were shown to be in the ``beyond extremely unlikely`` frequency category. Given the unknown nature of the gas-release behavior in the SSTS, a number of design changes and administrative controls were implemented to achieve these low frequencies. Likewise, drill string fires and dome space fires were shown to be very low frequency accidents by taking credit for the design changes, controls, and available experimental and analytical data. However, a number of Bureau of Mines (BOM) tests must be completed before some of the burn accidents can be dismissed with high confidence. Under the category of waste fires, the possibility of igniting the entrapped gases and the waste itself were analyzed. Experiments are being conducted at the BOM to demonstrate that the drill bit is not capable of igniting the trapped gas in the waste. Laboratory testing and thermal analysis demonstrated that, under normal operating conditions, the drill bit will not create high

  7. Gas Generation and Release in Near-Surface Repository at Armenian NPP - 13372

    SciTech Connect (OSTI)

    Grigoryan, G.; Amirjanyan, A.; Hovhannisyan, A.; Gondakyan, Y.

    2013-07-01

    The potential nuclear waste repository at Armenian Nuclear Power Plant (ANPP) can store Low and Intermediate Level Radioactive waste (LL/ILW). In this kind of near-surface repository for radioactive waste, significant quantities of gases may be generated as a result of microbial degradation and corrosion. A discussion is presented of the microbial and chemical degradation of cellulose. For the release of gas, it is assumed that the complete conversion of cellulosic wastes to gases by the action of microbes, is, in principle, permitted. Released radioactive gases such as {sup 14}CO{sub 2} and {sup 14}CH{sub 4} could have a direct pathway to the atmosphere. The potential impact of gas generation, accumulation and migration on the long-term of repository, should therefore be assessed properly. We present here safety assessment result of gas producing radioactive waste disposal by the inhalation dose to a maximally exposed individual above ground, based on some conservative assumptions about release from waste as well as gas generation calculations. (authors)

  8. Calculation of the dose rate emanating from gamma radiation of a gas jet propagating through the surface layer of the atmosphere

    SciTech Connect (OSTI)

    Zakharov, O.V.; Kovalenko, V.V.; Kolobashkin, V.M.

    1982-09-01

    The problem of calculating the dose rate on the Earth's surface which emanates from a gas jet is examined.

  9. Analysis of tank 7 surface supernatant sample (FTF-7-15-26) in support of corrosion control program

    SciTech Connect (OSTI)

    Oji, L. N

    2015-10-01

    This report provides the results of analyses on Savannah River Site Tank 7 surface supernatant liquid sample in support of the Corrosion Control Program (CCP). The measured nitrate, nitrite and free-hydroxide concentrations for the Tank 7 surface sample averaged, 3.74E-01 ± 1.88E-03, 4.17E-01 ± 9.01E-03 and 0.602 ± 0.005 M, respectively. The Tank 7 surface cesium-137, sodium and silicon concentrations were, respectively, 3.99E+08, ± 3.25E+06 dpm/mL, 2.78 M and <3.10 mg/L. The measured aluminum concentration in the Tank 7 surface sample averaged 0.11 M.

  10. Entropic description of gas hydrate ice/liquid equilibrium via enhanced sampling of coexisting phases

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Malolepsza, Edyta; Kim, Jaegil; Keyes, Tom

    2015-04-28

    Metastable β ice holds small guest molecules in stable gas hydrates, so its solid/liquid equilibrium is of interest. However, aqueous crystal/liquid transitions are very difficult to simulate. A new MD algorithm generates trajectories in a generalized NPT ensemble and equilibrates states of coexisting phases with a selectable enthalpy. Furthermore, with replicas spanning the range between β ice and liquid water we find the statistical temperature from the enthalpy histograms and characterize the transition by the entropy, introducing a general computational procedure for first-order transitions.

  11. Development testing of the chemical analysis automation polychlorinated biphenyl standard analysis method during surface soils sampling at the David Witherspoon 1630 site

    SciTech Connect (OSTI)

    Hunt, M.A.; Klatt, L.N.; Thompson, D.H.

    1998-02-01

    The Chemical Analysis Automation (CAA) project is developing standardized, software-driven, site-deployable robotic laboratory systems with the objective of lowering the per-sample analysis cost, decreasing sample turnaround time, and minimizing human exposure to hazardous and radioactive materials associated with DOE remediation projects. The first integrated system developed by the CAA project is designed to determine polychlorinated biphenyls (PCB) content in soil matrices. A demonstration and development testing of this system was conducted in conjuction with surface soil characterization activities at the David Witherspoon 1630 Site in Knoxville, Tennessee. The PCB system consists of five hardware standard laboratory modules (SLMs), one software SLM, the task sequence controller (TSC), and the human-computer interface (HCI). Four of the hardware SLMs included a four-channel Soxhlet extractor, a high-volume concentrator, a column cleanup, and a gas chromatograph. These SLMs performed the sample preparation and measurement steps within the total analysis protocol. The fifth hardware module was a robot that transports samples between the SLMs and the required consumable supplies to the SLMs. The software SLM is an automated data interpretation module that receives raw data from the gas chromatograph SLM and analyzes the data to yield the analyte information. The TSC is a software system that provides the scheduling, management of system resources, and the coordination of all SLM activities. The HCI is a graphical user interface that presents the automated laboratory to the analyst in terms of the analytical procedures and methods. Human control of the automated laboratory is accomplished via the HCI. Sample information required for processing by the automated laboratory is entered through the HCI. Information related to the sample and the system status is presented to the analyst via graphical icons.

  12. A safety equipment list for rotary mode core sampling systems operation in single shell flammable gas tanks

    SciTech Connect (OSTI)

    SMALLEY, J.L.

    1999-05-18

    This document identifies all interim safety equipment to be used for rotary mode core sampling of single-shell flammable gas tanks utilizing Rotary Mode Core Sampling systems (RMCS). This document provides the safety equipment for RMCS trucks HO-68K-4600, HO-68K-4647, trucks three and four respectively, and associated equipment. It is not intended to replace or supersede WHC-SD-WM-SEL-023, (Kelly 1991), or WHC-SD-WM-SEL-032, (Corbett 1994), which classifies 80-68K-4344 and HO-68K-4345 respectively. The term ''safety equipment'' refers to safety class (SC) and safety significant (SS) equipment, where equipment refers to structures, systems and components (SSC's). The identification of safety equipment in this document is based on the credited design safety features and analysis contained in the Authorization Basis (AB) for rotary mode core sampling operations in single-shell flammable gas tanks. This is an interim safety classification since the AB is interim. This document will be updated to reflect the final RMCS equipment safety classification designations upon completion of a final AB which will be implemented with the release of the Final Safety Analysis Report (FSAR).

  13. April 2012 Groundwater and Surface Water Sampling at the Salmon, Mississippi, Site (Data Validation Package)

    SciTech Connect (OSTI)

    2012-10-12

    Sampling and analysis were conducted on April 16-19, 2012, as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office Of Legacy Management Sites (LMS/PLN/S04351, continually updated). Duplicate samples were collected from locations SA1-1-H, HMH-5R, SA3-4-H, SA1-2-H, Pond W of GZ, and SA5-4-4. One trip blank was collected during this sampling event.

  14. Surface Characterization of Nb Samples Electro-polished Together With Real Superconducting Radio-frequency Accelerator Cavities

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xin Zhao; Geng, Rongli; Tyagi, P. V.; Hayano, Hitoshi; Kato, Shigeki; Nishiwaki, Michiru; Saeki, Takayuki; Sawabe, Motoaki

    2010-12-01

    We report the results of surface characterizations of niobium (Nb) samples electropolished together with a single cell superconducting radio-frequency accelerator cavity. These witness samples were located in three regions of the cavity, namely at the equator, the iris and the beam-pipe. Auger electron spectroscopy (AES) was utilized to probe the chemical composition of the topmost four atomic layers. Scanning electron microscopy with energy dispersive X-ray for elemental analysis (SEM/EDX) was used to observe the surface topography and chemical composition at the micrometer scale. A few atomic layers of sulfur (S) were found covering the samples non-uniformly. Niobium oxide granules withmore » a sharp geometry were observed on every sample. Some Nb-O granules appeared to also contain sulfur.« less

  15. Precision Gas Sampling (PGS) Validation2011-2014 Final Campaign Report

    SciTech Connect (OSTI)

    Tom, M. S.; Fischer, M. L.; Biraud, S. C.; Billesbach, D.

    2016-01-01

    In this field campaign, we used eddy covariance towers to quantify carbon, water, and energy fluxes from a pasture and a wheat field that were converted to switchgrass. The U.S. Department of Energy is investing in switchgrass as a cellulosic bioenergy crop, but there is little data available that could be used to develop or test land surface model representations of the crop. This campaign was a collaboration between Lawrence Berkeley National Laboratory and the U.S. Department of Agriculture Agricultural Research Service. Unfortunately, in 2011, Oklahoma had one of the most severe droughts on record, and the crop in one of the switchgrass fields experienced almost complete die-off. The crop was replanted, but subsequent drought conditions prevented its establishment. Then, in April 2012, a large tornado demolished the instruments at our site in Woodward, Oklahoma. These two events meant that we have some interesting data on land response to extreme weather; however, we were not able to collect continuous data for annual sums as originally intended. We did observe that, because of the drought, the net ecosystem exchange of CO2 was much lower in 2011 than in 2010. Concomitantly, sensible heat fluxes increased and latent heat fluxes decreased. These conditions would have large consequences for land surface forcing of convection. Data from all years were submitted to the Atmospheric Radiation Measurement Climate Research Facility Data Archive, and the sites were registered in AmeriFlux.

  16. June-July 2015 Groundwater and Surface Water Sampling at the Old and New Rifle, Colorado, Processing Sites

    Office of Legacy Management (LM)

    June-July 2015 Groundwater and Surface Water Sampling at the Old and New Rifle, Colorado, Processing Sites November 2015 LMS/RFL/S00615 This page intentionally left blank U.S. Department of Energy DVP-June and July 2015, Old and New Rifle, Colorado November 2015 RINs 15067100, 15067101, and 15077206 Page i Contents Sampling Event Summary ...............................................................................................................1 New Rifle, Colorado, Processing Site, Planned

  17. Full-Column Greenhouse Gas Sampling 2012-2014 Final Campaign Report

    SciTech Connect (OSTI)

    Fischer, M. L.; Sweeney, C.

    2016-01-01

    The vertical distributions of CO2, CH4, and other gases provide important constraints when determining terrestrial and ocean sources and sinks of carbon and other biogeochemical processes in the Earth system. The U.S. Department of Energy's (DOE) Office of Biological and Environmental Research and the National Oceanic and Atmospheric Administration's Earth System Research Laboratory to quantify the vertically resolved distribution of atmospheric carbon-cycle gases(CO2, CH4 ) within approximately 99% of the atmospheric column at the DOE ’s Atmospheric Radiation Measurement Southern Great Plains (SGP) site in Oklahoma . During the 2012 to 2014 campaign period, 12 successful Air C ore flights were conducted from the SGP site . In addition to providing critical data for evaluating remote sensing and earth system models, valuable lessons were learned that motivate improvements to the sampling and recovery systems and campaign logistics . With the launch of the Orbiting Carbon Observatory - 2 (OCO - 2) and Greenhouse gases Observing Satellite ( GOSAT ) satellites, we look forward to proposing additional sampling and analysis efforts at the SGP site and at other sites to characterize the vertical distribution of CO2, CH4 over time and space.

  18. Optimization of an enclosed gas analyzer sampling system for measuring eddy covariance fluxes of H2O and CO2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Metzger, Stefan; Burba, George; Burns, Sean P.; Blanken, Peter D.; Li, Jiahong; Luo, Hongyan; Zulueta, Rommel C.

    2016-03-31

    Several initiatives are currently emerging to observe the exchange of energy and matter between the earth's surface and atmosphere standardized over larger space and time domains. For example, the National Ecological Observatory Network (NEON) and the Integrated Carbon Observing System (ICOS) are set to provide the ability of unbiased ecological inference across ecoclimatic zones and decades by deploying highly scalable and robust instruments and data processing. In the construction of these observatories, enclosed infrared gas analyzers are widely employed for eddy covariance applications. While these sensors represent a substantial improvement compared to their open- and closed-path predecessors, remaining high-frequency attenuation variesmore » with site properties and gas sampling systems, and requires correction. Here, we show that components of the gas sampling system can substantially contribute to such high-frequency attenuation, but their effects can be significantly reduced by careful system design. From laboratory tests we determine the frequency at which signal attenuation reaches 50 % for individual parts of the gas sampling system. For different models of rain caps and particulate filters, this frequency falls into ranges of 2.5–16.5 Hz for CO2, 2.4–14.3 Hz for H2O, and 8.3–21.8 Hz for CO2, 1.4–19.9 Hz for H2O, respectively. A short and thin stainless steel intake tube was found to not limit frequency response, with 50 % attenuation occurring at frequencies well above 10 Hz for both H2O and CO2. From field tests we found that heating the intake tube and particulate filter continuously with 4 W was effective, and reduced the occurrence of problematic relative humidity levels (RH > 60 %) by 50 % in the infrared gas analyzer cell. No further improvement of H2O frequency response was found for heating in excess of 4 W. These laboratory and field tests were reconciled using resistor–capacitor theory, and NEON's final gas sampling system was

  19. On eddy accumulation with limited conditional sampling to measure air-surface exchange

    SciTech Connect (OSTI)

    Wesely, M.L.; Hart, R.L.

    1994-01-01

    An analysis of turbulence data collected at a height of 12.3 m above grasslands was carried out to illustrate some of the limitations and possible improvements in methods to compute vertical fluxes of trace substances by the eddy accumulation technique with conditional sampling. The empirical coefficient used in the technique has a slight dependence on atmospheric stability, which can be minimized by using a threshold vertical velocity equal to approximately 0.75{sigma}{sub w}, below which chemical sampling is suspended. This protocol results in a smaller chemical sample but increases the differences in concentrations by approximately 70%. For effective conditional sampling when mass is being accumulated in a trap or reservoir, the time of sampling during updrafts versus downdrafts should be measured and used to adjust estimates of the mean concentrations.

  20. Detection of high molecular weight organic tracers in vegetation smoke samples by high-temperature gas chromatography-mass spectrometry

    SciTech Connect (OSTI)

    Elias, V.O.; Simoneit, B.R.T. ); Pereira, A.S.; Cardoso, J.N. ); Cabral, J.A. )

    1999-07-15

    High-temperature high-resolution gas chromatography (HTGC) is an established technique for the separation of complex mixtures of high molecular weight (HMW) compounds which do not elute when analyzed on conventional GC columns. The combination of this technique with mass spectrometry is not so common and application to aerosols is novel. The HTGC and HTGC-MS analyses of smoke samples taken by particle filtration from combustion of different species of plants provided the characterization of various classes of HMW compounds reported to occur for the first time in emissions from biomass burning. Among these components are a series of wax esters with up to 58 carbon numbers, aliphatic hydrocarbons, triglycerides, long chain methyl ketones, alkanols and a series of triterpenyl fatty acid esters which have been characterized as novel natural products. Long chain fatty acids with more than 32 carbon numbers are not present in the smoke samples analyzed. The HMW compounds in smoke samples from the burning of plants from Amazonia indicate the input of directly volatilized natural products in the original plants during their combustion. However, the major organic compounds extracted from smoke consist of a series of lower molecular weight polar components, which are not natural products but the result of the thermal breakdown of cellulose and lignin. In contrast, the HMW natural products may be suitable tracers for specific sources of vegetation combustion because they are emitted as particles without thermal alternation in the smoke and can thus be related directly to the original plant material.

  1. Tuning the Electron Gas at an Oxide Heterointerface via Free Surface Charges

    SciTech Connect (OSTI)

    Bell, Christopher

    2011-08-11

    Oxide heterointerfaces are emerging as one of the most exciting materials systems in condensed matter science. One remarkable example is the LaAlO{sub 3}/SrTiO{sub 3} (LAO/STO) interface, a model system in which a highly mobile electron gas forms between two band insulators, exhibiting two dimensional superconductivity and unusual magnetotransport properties. An ideal tool to tune such an electron gas is the electrostatic field effect. In principle, the electrostatic field can be generated by bound charges due to polarization (as in the normal and ferroelectric field effects) or by adding excess free charge. In previous studies, a large modulation of the carrier density and mobility of the LAO/STO interface has been achieved using the normal field effect. However, little attention has been paid to the field effect generated by free charges. This issue is scarcely addressed, even in conventional semiconductor devices, since the free charges are typically not stable. Here, we demonstrate an unambiguous tuning of the LAO/STO interface conductivity via free surface charges written using conducting atomic force microscopy (AFM). The modulation of the carrier density was found to be reversible, nonvolatile and surprisingly large, {approx}3 x 10{sup 13} cm{sup -2}, comparable to the maximum modulation by the normal field effect. Our finding reveal the efficiency of free charges in controlling the conductivity of this oxide interface, and suggest that this technique may be extended more generally to other oxide systems.

  2. Results of Hg speciation testing on tanks 30, 32, and 37 surface samples

    SciTech Connect (OSTI)

    Bannochie, C. J.

    2015-11-11

    The Savannah River National Laboratory (SRNL) was tasked with preparing and shipping samples for Hg speciation by Eurofins Frontier Global Sciences, Inc. in Seattle, WA on behalf of the Savannah River Remediation (SRR) Mercury Task Team.

  3. COMPARISON OF RESULTS FOR QUARTER 5 SURFACE WATER SPLIT SAMPLES COLLECTED AT THE NUCLEAR FUEL SERVICES SITE ERWIN TENNESSEE

    SciTech Connect (OSTI)

    2013-09-23

    Oak Ridge Associated Universities (ORAU), under the Oak Ridge Institute for Science and Education (ORISE) contract, collected split surface water samples with Nuclear Fuel Services (NFS) representatives on August 21, 2013. Representatives from the U.S. Nuclear Regulatory Commission (NRC) and the Tennessee Department of Environment and Conservation were also in attendance. Samples were collected at four surface water stations, as required in the approved Request for Technical Assistance number 11-018. These stations included Nolichucky River upstream (NRU), Nolichucky River downstream (NRD), Martin Creek upstream (MCU), and Martin Creek downstream (MCD). Both ORAU and NFS performed gross alpha and gross beta analyses, and the comparison of results using the duplicate error ratio (DER), also known as the normalized absolute difference, are tabulated. All DER values were less than 3 and results are consistent with low (e.g., background) concentrations.

  4. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Natural Gas and Produced Water Sampling at the Rulison, Colorado, Site November 2014 LMS.........3 Water Sampling Field Activities Verification ...

  5. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Natural Gas and Produced Water Sampling at the Gasbuggy, New Mexico, Site December 2013 .........5 Water Sampling Field Activities Verification ...

  6. COMPARISON OF RESULTS FOR QUARTER 2 SURFACE WATER SPLIT SAMPLES COLLECTED AT THE NUCLEAR FUEL SERVICES SITE, ERWIN, TENNESSEE

    SciTech Connect (OSTI)

    2013-01-21

    Oak Ridge Associated Universities (ORAU), under the Oak Ridge Institute for Science and Education (ORISE) contract, collected split surface water samples with Nuclear Fuel Services (NFS) representatives on November 15, 2012. Representatives from the U.S. Nuclear Regulatory Commission and Tennessee Department of Environment and Conservation were also in attendance. Samples were collected at four surface water stations, as required in the approved Request for Technical Assistance number 11-018. These stations included Nolichucky River upstream (NRU), Nolichucky River downstream (NRD), Martin Creek upstream (MCU), and Martin Creek downstream (MCD). Both ORAU and NFS performed gross alpha and gross beta analyses, and the results are compared using the duplicate error ratio (DER), also known as the normalized absolute difference. A DER {<=} 3 indicates that, at a 99% confidence interval, split sample results do not differ significantly when compared to their respective one standard deviation (sigma) uncertainty (ANSI N42.22). The NFS split sample report does not specify the confidence level of reported uncertainties (NFS 2012). Therefore, standard two sigma reporting is assumed and uncertainty values were divided by 1.96. In conclusion, all DER values were less than 3 and results are consistent with low (e.g., background) concentrations.

  7. COMPARISON OF RESULTS FOR QUARTER 4 SURFACE WATER SPLIT SAMPLES COLLECTED AT THE NUCLEAR FUELS SERVICES SITE, ERWIN, TN

    SciTech Connect (OSTI)

    none,

    2013-08-15

    Oak Ridge Associated Universities (ORAU), under the Oak Ridge Institute for Science and Education (ORISE) contract, collected split surface water samples with Nuclear Fuel Services (NFS) representatives on June 12, 2013. Representatives from the U.S. Nuclear Regulatory Commission (NRC) and the Tennessee Department of Environment and Conservation were also in attendance. Samples were collected at four surface water stations, as required in the approved Request for Technical Assistance number 11-018. These stations included Nolichucky River upstream (NRU), Nolichucky River downstream (NRD), Martin Creek upstream (MCU), and Martin Creek downstream (MCD). Both ORAU and NFS performed gross alpha and gross beta analyses, and Table 1 presents the comparison of results using the duplicate error ratio (DER), also known as the normalized absolute difference. A DER ≤ 3 indicates at a 99% confidence interval that split sample results do not differ significantly when compared to their respective one standard deviation (sigma) uncertainty (ANSI N42.22). The NFS split sample report specifies 95% confidence level of reported uncertainties (NFS 2013). Therefore, standard two sigma reporting values were divided by 1.96. In conclusion, most DER values were less than 3 and results are consistent with low (e.g., background) concentrations. The gross beta result for sample 5198W0014 was the exception. The ORAU gross beta result of 6.30 ± 0.65 pCi/L from location NRD is well above NFS's non-detected result of 1.56 ± 0.59 pCi/L. NFS's data package includes no detected result for any radionuclide at location NRD. At NRC's request, ORAU performed gamma spectroscopic analysis of sample 5198W0014 to identify analytes contributing to the relatively elevated gross beta results. This analysis identified detected amounts of naturally-occurring constituents, most notably Ac-228 from the thorium decay series, and does not suggest the presence of site-related contamination.

  8. Cryodeposition of nitrogen gas on a surface cooled by helium II

    SciTech Connect (OSTI)

    Dhuley, R. C.; Bosque, E. S.; Van Sciver, S. W.

    2014-01-29

    Catastrophic loss of beam tube vacuum in a superconducting particle accelerator can be simulated by sudden venting of a long high vacuum channel cooled on its outer surface by He II. The rapid rush of atmospheric air in such an event shows an interesting propagation effect, which is much slower than the shock wave that occurs with vacuum loss at ambient conditions. This is due to flash frosting/deposition of air on the cold walls of the channel. Hence to characterize the propagation as well as the associated heat transfer, it is first necessary to understand the deposition process. Here we attempt to model the growth of nitrogen frost layer on a cold plate in order to estimate its thickness with time. The deposition process can be divided into two regimes- free molecular and continuum. It is shown that in free molecular regime, the frost growth can be modeled reasonably well using cryopump theory and general heat transfer relations. The continuum regime is more complex to model, given the higher rate of gas incident on cryosurface causing a large heat load on helium bath and changing cryosurface temperature. Results from the continuum regime are discussed in the context of recent experiments performed in our laboratory.

  9. Groundwater Sampling and Soil Gas Data Analysis, Distler Brickyard Superfund Site, Hardin County, Kentucky -- June - August 2000

    SciTech Connect (OSTI)

    Martin, Jennifer Pauline; Peterson, Lance Nutting; Taylor, C. J.

    2000-11-01

    This report describes the results of groundwater and soil gas sampling conducted at the Distler Brickyard Site, Hardin County, Kentucky, June-August, 2000. The purpose of the sampling activities was to address remaining data gaps regarding the feasibility of monitored natural attenuation (MNA) for remediation of chloroethene/ane contamination. Specifically, data gaps fall into four categories: 1) effect of seasonal recharge on contaminant concentrations, 2) geochemical conditions in the Fine Grained Alluvium (FGA), 3) conditions along the flowpath between Wells GW-11 and MW-3, and 4) the extent of aerobic degradation in the Coarse Grained Alluvium (CGA). A data collection strategy composed of both groundwater sampling and passive soil vapor sampling devices (Gore-Sorbers?) was used. The Gore-Sorber? technology was used to collect data from the FGA, which because of its low hydraulic conductivity and variable saturation makes collection of groundwater samples problematic. Gore-Sorbers were deployed in 15 wells, most of them being in the FGA, and groundwater samples were collected in 17 wells, which were mostly in the CGA. Both sampling methods were utilized in a subset of wells (7) in order to determine the general comparability of results obtained from each method. Results indicate that water levels in both the FGA and CGA were higher in June-August 2000 than in October 1999, likely due to increased infiltration of precipitation through the FGA during the wetter months. Redox conditions in the FGA and downgradient CGA were iron-reducing, less reducing than in October-1999. In general, concentrations of chloroethenes/anes were higher in June-August 2000 than October 1999. Trichloroethene (TCE) was present at concentrations as high as 65 µg/L in the FGA and 19 µg/L in the CGA. This is substantially higher than the maximum concentration in October 1999 of 11 µg/L. The following conclusions were drawn from these data collection activities: 1) two potential

  10. Direct Sampling and Analysis from Solid Phase Extraction Cards using an Automated Liquid Extraction Surface Analysis Nanoelectrospray Mass Spectrometry System

    SciTech Connect (OSTI)

    Walworth, Matthew J; ElNaggar, Mariam S; Stankovich, Joseph J; WitkowskiII, Charles E.; Norris, Jeremy L; Van Berkel, Gary J

    2011-01-01

    Direct liquid extraction based surface sampling, a technique previously demonstrated with continuous flow and autonomous pipette liquid microjunction surface sampling probes, has recently been implemented as the Liquid Extraction Surface Analysis (LESA) mode on the commercially available Advion NanoMate chip-based infusion nanoelectrospray ionization system. In the present paper, the LESA mode was applied to the analysis of 96-well format custom solid phase extraction (SPE) cards, with each well consisting of either a 1 or 2 mm diameter monolithic hydrophobic stationary phase. These substrate wells were conditioned, loaded with either single or multi-component aqueous mixtures, and read out using the LESA mode of a TriVersa NanoMate or a Nanomate 100 coupled to an ABI/Sciex 4000QTRAPTM hybrid triple quadrupole/linear ion trap mass spectrometer and a Thermo LTQ XL linear ion trap mass spectrometer. Extraction conditions, including extraction/nanoESI solvent composition, volume, and dwell times, were optimized in the analysis of targeted compounds. Limit of detection and quantitation as well as analysis reproducibility figures of merit were measured. Calibration data was obtained for propranolol using a deuterated internal standard which demonstrated linearity and reproducibility. A 10x increase in signal and cleanup of micromolar Angiotensin II from a concentrated salt solution was demonstrated. Additionally, a multicomponent herbicide mixture at ppb concentration levels was analyzed using MS3 spectra for compound identification in the presence of isobaric interferences.

  11. Molecular Beam Epitaxy on Gas Cluster Ion Beam Prepared GaSb Substrates: Towards Improved Surfaces and Interfaces

    SciTech Connect (OSTI)

    Krishnaswami, Kannan; Vangala, Shivashankar R.; Dauplaise, Helen; Allen, Lisa; Dallas, Gordon; Bakken, Daniel; Bliss, David; Goodhue, William

    2008-04-01

    A key problem in producing mid-infrared optoelectronic and low-power electronic devices in the GaSb material system is the lack of substrates with appropriate surfaces for epitaxial growth. Chemical mechanical polishing (CMP) of GaSb results in surface damage accompanied by tenacious oxides that do not easily desorb. To overcome this, we have developed a process using gas cluster ion beams (GCIB) to remove surface damage and produce engineered surface oxides. In this paper, we present surface modification results on GaSb substrates using O2-, CF4/O2-, and HBr-GCIB processes. X-ray photoelectron spectroscopy of GCIB produced surface layers showed the presence of mixed Ga- and Sb-oxides, with mostly Ga-oxides at the interface, desorbing at temperatures ranging 530°C to 560°C. Cross-sectional transmission electron microscopy of molecular beam epitaxy grown GaSb/AlGaSb layers showed that GCIB surfaces yielded smooth defect free substrate to epi transitions as compared to CMP surfaces. Furthermore, HBr-GCIB surfaces exhibited neither dislocation layers nor discernable interfaces, indicating complete oxide desorbtion prior to epigrowth on a clean single crystal template. Atomic force microscopy of GCIB epilayers exhibited smooth surfaces with characteristic step-terrace formations comprising monatomic steps and wide terraces. The HBr-GCIB process can be easily adapted to a large scale manufacturing process for epi-ready GaSb.

  12. Mechanism of surface modification of the Ti-6Al-4V alloy using a gas tungsten arc heat source

    SciTech Connect (OSTI)

    Labudovic, M.; Kovacevic, R.; Kmecko, I.; Khan, T.I.; Blecic, D.; Blecic, Z.

    1999-06-01

    The surface modification of a Ti-6Al-4V alloy using a gas tungsten arc, as a heat source, was studied. The experimental results show that the titanium alloy surface can be melted and nitrided using pure nitrogen or a nitrogen/argon mixture shielding atmosphere. The resolidified surfaces are 0.9 to 1.2-mm thick and contain titanium nitride dendrites, {alpha}-titanium, and {alpha}{double_prime}-titanium (martensite). The average dendrite arm spacing is influenced by the electrode speed. Small titanium nitride dendrites are homogeneously distributed in the resolidified surfaces. The microstructure and phase constitution in the resolidified surfaces were determined and analyzed, and the mechanism of the formation of titanium nitrides is discussed. The results show that the nitriding kinetics obey parabolic laws and are, therefore, controlled by nitrogen diffusion. The nitrogen-concentration depth profiles, calculated using Fick`s second law of diffusion, are compared to experimental nitrogen depth profiles, showing satisfactory agreement.

  13. Surface radiation survey and soil sampling of the 300-FF-1 operable unit, Hanford Site, southeastern Washington: A case study

    SciTech Connect (OSTI)

    Teel, S.S.; Olsen, K.B.

    1990-10-01

    The methods used for conducting a radiological characterization of the soil surface for the Phase I Remedial Investigation of a Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) site is presented via a case study. The study site is an operable unit (300-FF-1) located in and adjacent to the 300 Area of the US Department of Energy's Hanford Site in southeastern Washington State. The operable unit contains liquid and solid waste disposal facilities associated with nuclear fuels fabrication. Continuous surface radiation surveying and soil sampling of selected locations were conducted. Contamination was found in several locations within the operable unit including areas near the liquid and solid waste disposal facilities. Instruments used during surveying included portable beta/gamma (P-11) detectors, and the Ultrasonic Ranging and Data System using an NaI (Tl) detector. Laboratory analyses results indicate that above-background radiation levels were primarily due to the presence of uranium. Both types of field instruments used in the study were effective in detecting surface contamination from radionuclides; however, each had specific advantages. Guidelines are presented for the optimum use of these instruments when performing a radiological characterization of the soil surface. 4 refs., 3 figs., 3 tabs.

  14. SURFACE CHEMKIN-III: A Fortran package for analyzing heterogeneous chemical kinetics at a solid-surface - gas-phase interface

    SciTech Connect (OSTI)

    Coltrin, M.E.; Kee, R.J.; Rupley, F.M.; Meeks, E.

    1996-05-01

    This document is the user`s manual for the SURFACE CHEMKIN-III package. Together with CHEMKIN-III, this software facilitates the formation, solution, and interpretation of problems involving elementary heterogeneous and gas-phase chemical kinetics in the presence of a solid surface. The package consists of two major software components: an Interpreter and a Surface Subroutine Library. The Interpreter is a program that reads a symbolic description of a user-specified chemical reaction mechanism. One output from the Interpreter is a data file that forms a link to the Surface Subroutine Library, which is a collection of about seventy modular Fortran subroutines that may be called from a user`s application code to return information on chemical production rates and thermodynamic properties. This version of SURFACE CHEMKIN-III includes many modifications to allow treatment of multi-fluid plasma systems, for example modeling the reactions of highly energetic ionic species with a surface. Optional rate expressions allow reaction rates to depend upon ion energy rather than a single thermodynamic temperature. In addition, subroutines treat temperature as an array, allowing an application code to define a different temperature for each species. This version of SURFACE CHEMKIN-III allows use of real (non-integer) stoichiometric coefficients; the reaction order with respect to species concentrations can also be specified independent of the reaction`s stoichiometric coefficients. Several different reaction mechanisms can be specified in the Interpreter input file through the new construct of multiple materials.

  15. COMPARISON OF RESULTS FOR QUARTER 3 SURFACE WATER SPLIT SAMPLES COLLECTED AT THE NUCLEAR FUEL SERVICES SITE, ERWIN, TENNESSEE

    SciTech Connect (OSTI)

    none,

    2013-05-28

    Oak Ridge Associated Universities (ORAU), under the Oak Ridge Institute for Science and Education (ORISE) contract, collected split surface water samples with Nuclear Fuel Services (NFS) representatives on March 20, 2013. Representatives from the U.S. Nuclear Regulatory Commission and the Tennessee Department of Environment and Conservation were also in attendance. Samples were collected at four surface water stations, as required in the approved Request for Technical Assistance number 11-018. These stations included Nolichucky River upstream (NRU), Nolichucky River downstream (NRD), Martin Creek upstream (MCU), and Martin Creek downstream (MCD). Both ORAU and NFS performed gross alpha and gross beta analyses, and Table 1 presents the comparison of results using the duplicate error ratio (DER), also known as the normalized absolute difference. A DER {<=} 3 indicates that at a 99% confidence interval, split sample results do not differ significantly when compared to their respective one standard deviation (sigma) uncertainty (ANSI N42.22). The NFS split sample report does not specify the confidence level of reported uncertainties (NFS 2013). Therefore, standard two sigma reporting is assumed and uncertainty values were divided by 1.96. In conclusion, most DER values were less than 3 and results are consistent with low (e.g., background) concentrations. The gross beta result for sample 5198W0012 was the exception. The ORAU result of 9.23 ± 0.73 pCi/L from location MCD is well above NFS's result of -0.567 ± 0.63 pCi/L (non-detected). NFS's data package included a detected result for U-233/234, but no other uranium or plutonium detection, and nothing that would suggest the presence of beta-emitting radionuclides. The ORAU laboratory reanalyzed sample 5198W0012 using the remaining portion of the sample volume and a result of 11.3 ± 1.1 pCi/L was determined. As directed, the laboratory also counted the filtrate using gamma spectrometry analysis and

  16. A versatile elevated-pressure reactor combined with an ultrahigh vacuum surface setup for efficient testing of model and powder catalysts under clean gas-phase conditions

    SciTech Connect (OSTI)

    Morfin, Franck; Piccolo, Laurent

    2013-09-15

    A small-volume reaction cell for catalytic or photocatalytic testing of solid materials at pressures up to 1000 Torr has been coupled to a surface-science setup used for standard sample preparation and characterization under ultrahigh vacuum (UHV). The reactor and sample holder designs allow easy sample transfer from/to the UHV chamber, and investigation of both planar and small amounts of powder catalysts under the same conditions. The sample is heated with an infrared laser beam and its temperature is measured with a compact pyrometer. Combined in a regulation loop, this system ensures fast and accurate temperature control as well as clean heating. The reaction products are automatically sampled and analyzed by mass spectrometry and/or gas chromatography (GC). Unlike previous systems, our GC apparatus does not use a recirculation loop and allows working in clean conditions at pressures as low as 1 Torr while detecting partial pressures smaller than 10{sup ?4} Torr. The efficiency and versatility of the reactor are demonstrated in the study of two catalytic systems: butadiene hydrogenation on Pd(100) and CO oxidation over an AuRh/TiO{sub 2} powder catalyst.

  17. Apparatus for focusing flowing gas streams

    DOE Patents [OSTI]

    Nogar, N.S.; Keller, R.A.

    1985-05-20

    Apparatus for focusing gas streams. The principle of hydrodynamic focusing is applied to flowing gas streams in order to provide sample concentration for improved photon and sample utilization in resonance ionization mass spectrometric analysis. In a concentric nozzle system, gas samples introduced from the inner nozzle into the converging section of the outer nozzle are focused to streams 50-250-..mu..m in diameter. In some cases diameters of approximately 100-..mu..m are maintained over distances of several centimeters downstream from the exit orifice of the outer nozzle. The sheath gas employed has been observed to further provide a protective covering around the flowing gas sample, thereby isolating the flowing gas sample from possible unwanted reactions with nearby surfaces. A single nozzle variation of the apparatus for achieving hydrodynamic focusing of gas samples is also described.

  18. Gas chromatography/matrix-isolation apparatus

    DOE Patents [OSTI]

    Reedy, Gerald T.

    1986-01-01

    A gas-sample collection device provides matrix isolation of individual gas bands from a gas chromatographic separation and for the spectroscopic analysis of the individual sample bands. The device includes a vacuum chamber containing a rotatably supported, specular carousel having at least one reflecting surface for holding a sample deposited thereon. A gas inlet is provided for depositing a mixture of sample and matrix material on the reflecting surface which is maintained at a sufficiently low temperature to cause solidification. A first parabolic mirror directs an incident beam of electromagnetic radiation, such as in the infrared (IR) spectrum, from a source onto the sample/matrix mixture while a second parabolic mirror directs a second beam of electromagnetic radiation reflected by the specular surface to an IR spectrometer for determining the absorption spectra of the sample material deposited on the reflecting surface. The pair of off-axis parabolic mirrors having a common focal point are positioned outside of the vacuum chamber and may be displaced in combination for improved beam positioning and alignment. The carousel is provided with an aperture for each reflecting surface to facilitate accurate positioning of the incident beam relative to the gas-samples under analysis. Improved gas-sample deposition is insured by the use of a long focal length stereomicroscope positioned outside of the vacuum chamber for monitoring sample formation through a window, while the sample collector is positioned outside of the zone bounded by the incident and reflected electromagnetic beams for improved sample access and monitoring.

  19. Selecting a surface-controlled subsurface safety valve for deep, hot, high-pressure, sour gas offshore completions

    SciTech Connect (OSTI)

    Nystrom, K.O.

    1983-10-01

    From a safety aspect, a surface-controlled subsurface safety valve (SCSSV) is installed to perform but one function - that is, in an emergency, shut in the well to prevent a catastrophic blowout. As such, producers must be assured that the safety valve installed will: close, remain locked in position, and seal off pressure in an emergency, and maintain its mechanical reliability in the producing environment. To gain this assurance, Exxon Company USA conducted an extensive program to select and test a surface-controlled subsurface safety valve for a 15,000 psi working pressure (WP), hot, sour, corrosive gas completion in the Gulf of Mexico.

  20. AURORA: A FORTRAN program for modeling well stirred plasma and thermal reactors with gas and surface reactions

    SciTech Connect (OSTI)

    Meeks, E.; Grcar, J.F.; Kee, R.J.; Moffat, H.K.

    1996-02-01

    The AURORA Software is a FORTRAN computer program that predicts the steady-state or time-averaged properties of a well mixed or perfectly stirred reactor for plasma or thermal chemistry systems. The software was based on the previously released software, SURFACE PSR which was written for application to thermal CVD reactor systems. AURORA allows modeling of non-thermal, plasma reactors with the determination of ion and electron concentrations and the electron temperature, in addition to the neutral radical species concentrations. Well stirred reactors are characterized by a reactor volume, residence time or mass flow rate, heat loss or gas temperature, surface area, surface temperature, the incoming temperature and mixture composition, as well as the power deposited into the plasma for non-thermal systems. The model described here accounts for finite-rate elementary chemical reactions both in the gas phase and on the surface. The governing equations are a system of nonlinear algebraic relations. The program solves these equations using a hybrid Newton/time-integration method embodied by the software package TWOPNT. The program runs in conjunction with the new CHEMKIN-III and SURFACE CHEMKIN-III packages, which handle the chemical reaction mechanisms for thermal and non-thermal systems. CHEMKIN-III allows for specification of electron-impact reactions, excitation losses, and elastic-collision losses for electrons.

  1. THEORETICAL STUDY ON THE INTERACTION BETWEEN XENON AND POSITIVE SILVER CLUSTERS IN GAS PHASE AND ON THE (001) CHABAZITE SURFACE

    SciTech Connect (OSTI)

    Hunter, D.

    2009-03-16

    A systematic study on the adsorption of xenon on silver clusters in the gas phase and on the (001) surface of silver-exchanged chabazite is reported. Density functional theory at the B3LYP level with the cluster model was employed. The results indicate that the dominant part of the binding is the {sigma} donation, which is the charge transfer from the 5p orbital of Xe to the 5s orbital of Ag and is not the previously suggested d{sub {pi}}-d{sub {pi}} back-donation. A correlation between the binding energy and the degree of {sigma} donation is found. Xenon was found to bind strongly to silver cluster cations and not to neutral ones. The binding strength decreases as the cluster size increases for both cases, clusters in the gas-phase and on the chabazite surface. The Ag{sup +} cation is the strongest binding site for xenon both in gas phase and on the chabazite surface with the binding energies of 73.9 and 14.5 kJ/mol, respectively. The results also suggest that the smaller silver clusters contribute to the negative chemical shifts observed in the {sup 129}Xe NMR spectra in experiments.

  2. Y-12 Groundwater Protection Program Groundwater And Surface Water Sampling And Analysis Plan For Calendar Year 2012

    SciTech Connect (OSTI)

    Elvado Environmental, LLC

    2011-09-01

    This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2012 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring performed by the GWPP during CY 2012 is in accordance with the following goals: (1) to protect the worker, the public, and the environment; (2) to maintain surveillance of existing and potential groundwater contamination sources; (3) to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; (4) to identify and characterize long-term trends in groundwater quality at Y-12; and (5) to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring will be performed in three hydrogeologic regimes at Y-12: the Bear Creek Hydrogeologic Regime (Bear Creek Regime), the Upper East Fork Poplar Creek Hydrogeologic Regime (East Fork Regime), and the Chestnut Ridge Hydrogeologic Regime (Chestnut Ridge Regime). The Bear Creek and East Fork regimes are located in Bear Creek Valley and the Chestnut Ridge Regime is located south of Y-12 (Figure A.1). Additional surface water monitoring will be performed north of Pine Ridge along the boundary of the Oak Ridge Reservation. Modifications to the CY 2012 monitoring program may be necessary during implementation. Changes in programmatic requirements may alter the analytes specified for selected monitoring wells or may add or remove wells from the planned monitoring network. Each modification to the monitoring program will be approved by the Y-12 GWPP manager and documented as an addendum to this sampling and analysis plan. The following sections of this report provide details regarding

  3. Bar coded air sample tracking and bar coded loose surface contamination sample tracking: How it can assist in compliance with the DOE`s new 10 CFR 835 and the NRC`s new 10 CFR 20 regulations

    SciTech Connect (OSTI)

    Bailey, W.H.

    1994-12-31

    The paper describes advance sample tracking and processing techniques which utilize bar code technology for field data collection and count room analysis. Techniques described by the paper include bar coded area air sampling, bar coded portable breathing zone air sampling, and bar coded loose surface contamination sampling. Bar coded sample tracking is explored to demonstrate how it can assist in compliance with new DOE 10 CFR 835 and NRC 10 CFR 20 requirements. Operation of portable bar code readers is explored to provide insight to the advantages of bar coded sample tracking and corresponding sample trending analyses. Case studies involving bar coded sample tracking systems which are in use at NRC facilities, DOE sites, and decommission projects are discussed.

  4. An enhanced droplet-based liquid microjunction surface sampling system coupled with HPLC-ESI-MS/MS for spatially resolved analysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Van Berkel, Gary J.; Weiskittel, Taylor M.; Kertesz, Vilmos

    2014-11-07

    Droplet-based liquid microjunction surface sampling coupled with high-performance liquid chromatography (HPLC)-electrospray ionization (ESI)-tandem mass spectrometry (MS/MS) for spatially resolved analysis provides the possibility of effective analysis of complex matrix samples and can provide a greater degree of chemical information from a single spot sample than is typically possible with a direct analysis of an extract. Described here is the setup and enhanced capabilities of a discrete droplet liquid microjunction surface sampling system employing a commercially available CTC PAL autosampler. The system enhancements include incorporation of a laser distance sensor enabling unattended analysis of samples and sample locations of dramatically disparatemore » height as well as reliably dispensing just 0.5 μL of extraction solvent to make the liquid junction to the surface, wherein the extraction spot size was confined to an area about 0.7 mm in diameter; software modifications improving the spatial resolution of sampling spot selection from 1.0 to 0.1 mm; use of an open bed tray system to accommodate samples as large as whole-body rat thin tissue sections; and custom sample/solvent holders that shorten sampling time to approximately 1 min per sample. Lastly, the merit of these new features was demonstrated by spatially resolved sampling, HPLC separation, and mass spectral detection of pharmaceuticals and metabolites from whole-body rat thin tissue sections and razor blade (“crude”) cut mouse tissue.« less

  5. Method and apparatus utilizing ionizing and microwave radiation for saturation determination of water, oil and a gas in a core sample

    DOE Patents [OSTI]

    Maerefat, N.L.; Parmeswar, R.; Brinkmeyer, A.D.; Honarpour, M.

    1994-08-23

    A system is described for determining the relative permeabilities of gas, water and oil in a core sample has a microwave emitter/detector subsystem and an X-ray emitter/detector subsystem. A core holder positions the core sample between microwave absorbers which prevent diffracted microwaves from reaching a microwave detector where they would reduce the signal-to-noise ratio of the microwave measurements. The microwave emitter/detector subsystem and the X-ray emitter/detector subsystem each have linear calibration characteristics, allowing one subsystem to be calibrated with respect to the other subsystem. The dynamic range of microwave measurements is extended through the use of adjustable attenuators. This also facilitates the use of core samples with wide diameters. The stratification characteristics of the fluids may be observed with a windowed cell separator at the outlet of the core sample. The condensation of heavy hydrocarbon gas and the dynamic characteristics of the fluids are observed with a sight glass at the outlet of the core sample. 11 figs.

  6. Method and apparatus utilizing ionizing and microwave radiation for saturation determination of water, oil and a gas in a core sample

    DOE Patents [OSTI]

    Maerefat, Nicida L.; Parmeswar, Ravi; Brinkmeyer, Alan D.; Honarpour, Mehdi

    1994-01-01

    A system for determining the relative permeabilities of gas, water and oil in a core sample has a microwave emitter/detector subsystem and an X-ray emitter/detector subsystem. A core holder positions the core sample between microwave absorbers which prevent diffracted microwaves from reaching a microwave detector where they would reduce the signal-to-noise ratio of the microwave measurements. The microwave emitter/detector subsystem and the X-ray emitter/detector subsystem each have linear calibration characteristics, allowing one subsystem to be calibrated with respect to the other subsystem. The dynamic range of microwave measurements is extended through the use of adjustable attenuators. This also facilitates the use of core samples with wide diameters. The stratification characteristics of the fluids may be observed with a windowed cell separator at the outlet of the core sample. The condensation of heavy hydrocarbon gas and the dynamic characteristics of the fluids are observed with a sight glass at the outlet of the core sample.

  7. Analysis of tank 39H (HTF-39-15-61, 62) surface and subsurface supernatant samples in support of corrosion control program

    SciTech Connect (OSTI)

    Oji, L. N.

    2015-08-01

    This report provides the results of analyses on Tanks 39H surface and subsurface supernatant liquid samples in support of the Corrosion Control Program. Analyses included warm acid strike preparation followed by analysis for silicon, aluminum, and sodium and water dilution preparation followed by analysis for anions. Other reported analytical results include analyses results for uranium, Pu-241 and Pu-239. The measured sodium concentration averaged, respectively, 4.28E+00 ± 9.30E-02 M and 4.32E+00 ± 1.076E-01 M in the Tank 39H surface sample and Tank 39H subsurface sample. In general, the nitrate, nitrite, free-OH and specific gravity of the Tank 39H surface and subsurface samples were all about the same in magnitude, respectively, averaging 1.98 M, 0.314 M, 1.26 M and 1.24. The measured silicon concentration for the Tank 39H surface and subsurface samples were, respectively, 3.84E+01± 5.51E+00 and 4.14E+01± 1.17E+00 mg/L. Based on the uranium, Pu-241 and Pu-239 concentrations, the calculated U-235 equivalent is 21.41 wt% for the surface sample and 21.32 wt% for the subsurface sample.

  8. Surface acoustic wave sensors/gas chromatography; and Low quality natural gas sulfur removal and recovery CNG Claus sulfur recovery process

    SciTech Connect (OSTI)

    Klint, B.W.; Dale, P.R.; Stephenson, C.

    1997-12-01

    This topical report consists of the two titled projects. Surface Acoustic Wave/Gas Chromatography (SAW/GC) provides a cost-effective system for collecting real-time field screening data for characterization of vapor streams contaminated with volatile organic compounds (VOCs). The Model 4100 can be used in a field screening mode to produce chromatograms in 10 seconds. This capability will allow a project manager to make immediate decisions and to avoid the long delays and high costs associated with analysis by off-site analytical laboratories. The Model 4100 is currently under evaluation by the California Environmental Protection Agency Technology Certification Program. Initial certification focuses upon the following organics: cis-dichloroethylene, chloroform, carbon tetrachloride, trichlorethylene, tetrachloroethylene, tetrachloroethane, benzene, ethylbenzene, toluene, and o-xylene. In the second study the CNG Claus process is being evaluated for conversion and recovery of elemental sulfur from hydrogen sulfide, especially found in low quality natural gas. This report describes the design, construction and operation of a pilot scale plant built to demonstrate the technical feasibility of the integrated CNG Claus process.

  9. Site characterization summary report for dry weather surface water sampling upper East Fork Poplar Creek characterization area Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    1996-08-01

    This report describes activities associated with conducting dry weather surface water sampling of Upper East Fork Poplar Creek (UEFPC) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee. This activity is a portion of the work to be performed at UEFPC Operable Unit (OU) 1 [now known as the UEFPC Characterization Area (CA)], as described in the RCRA Facility Investigation Plan for Group 4 at the Oak- Ridge Y-12 Plant, Oak Ridge, Tennessee and in the Response to Comments and Recommendations on RCRA Facility Investigation Plan for Group 4 at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee, Volume 1, Operable Unit 1. Because these documents contained sensitive information, they were labeled as unclassified controlled nuclear information and as such are not readily available for public review. To address this issue the U.S. Department of Energy (DOE) published an unclassified, nonsensitive version of the initial plan, text and appendixes, of this Resource Conservation and Recovery Act (RCRA) Facility Investigation (RFI) Plan in early 1994. These documents describe a program for collecting four rounds of wet weather and dry weather surface water samples and one round of sediment samples from UEFPC. They provide the strategy for the overall sample collection program including dry weather sampling, wet weather sampling, and sediment sampling. Figure 1.1 is a schematic flowchart of the overall sampling strategy and other associated activities. A Quality Assurance Project Plan (QAPJP) was prepared to specifically address four rounds of dry weather surface water sampling and one round of sediment sampling. For a variety of reasons, sediment sampling has not been conducted and has been deferred to the UEFPC CA Remedial Investigation (RI), as has wet weather sampling.

  10. September 2004 Water Sampling

    Office of Legacy Management (LM)

    4 Groundwater and Surface Water Sampling at the Slick Rock, Colorado, Processing Sites .........7 Water Sampling Field Activities Verification ...

  11. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Green River, Utah, Disposal Site August 2014 LMSGRN.........7 Water Sampling Field Activities Verification ...

  12. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and May 2014 Groundwater and Surface Water Sampling at the Shiprock, New Mexico, Disposal .........9 Water Sampling Field Activities Verification ...

  13. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Rio Blanco, Colorado, Site October 2014 LMSRBLS00514 .........5 Water Sampling Field Activities Verification ...

  14. September 2004 Water Sampling

    Office of Legacy Management (LM)

    5 Groundwater and Surface Water Sampling at the Rulison, Colorado, Site October 2015 LMS.........5 Water Sampling Field Activities Verification ...

  15. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Monticello, Utah, Processing Site July 2015 LMSMNT.........7 Water Sampling Field Activities Verification ...

  16. September 2004 Water Sampling

    Office of Legacy Management (LM)

    2015 Groundwater and Surface Water Sampling at the Shiprock, New Mexico, Disposal Site .........9 Water Sampling Field Activities Verification ...

  17. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Rio Blanco, Colorado, Site October 2015 LMSRBLS00515 .........5 Water Sampling Field Activities Verification ...

  18. September 2004 Water Sampling

    Office of Legacy Management (LM)

    3 Groundwater and Surface Water Sampling at the Monument Valley, Arizona, Processing Site .........7 Water Sampling Field Activities Verification ...

  19. September 2004 Water Sampling

    Office of Legacy Management (LM)

    July 2015 Groundwater and Surface Water Sampling at the Gunnison, Colorado, Processing .........5 Water Sampling Field Activities Verification ...

  20. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Monticello, Utah, Processing Site July 2014 LMSMNT.........7 Water Sampling Field Activities Verification ...

  1. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Naturita, Colorado Processing Site October 2013 LMSNAP.........5 Water Sampling Field Activities Verification ...

  2. September 2004 Water Sampling

    Office of Legacy Management (LM)

    4 Groundwater and Surface Water Sampling at the Gunnison, Colorado, Processing Site .........5 Water Sampling Field Activities Verification ...

  3. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Tuba City, Arizona, Disposal Site November 2013 LMSTUB.........9 Water Sampling Field Activities Verification ...

  4. September 2004 Water Sampling

    Office of Legacy Management (LM)

    5 Groundwater and Surface Water Sampling at the Monticello, Utah, Processing Site January .........7 Water Sampling Field Activities Verification ...

  5. Analysis of the structural parameters that influence gas production from the Devonian shale. Annual progress report, 1979-1980. Volume II. Data repository and reports published during fiscal year 1979-1980: regional structure, surface structure, surface fractures, hydrology

    SciTech Connect (OSTI)

    Negus-De Wys, J.; Dixon, J. M.; Evans, M. A.; Lee, K. D.; Ruotsala, J. E.; Wilson, T. H.; Williams, R. T.

    1980-10-01

    This volume comprises appendices giving regional structure data, surface structure data, surface fracture data, and hydrology data. The fracture data covers oriented Devonian shale cores from West Virginia, Ohio, Virginia, Pennsylvania, and Kentucky. The subsurface structure of the Eastern Kentucky gas field is also covered. (DLC)

  6. A high surface area Zr(IV)-based metal–organic framework showing stepwise gas adsorption and selective dye uptake

    SciTech Connect (OSTI)

    Lv, Xiu-Liang; Tong, Minman; Huang, Hongliang; Wang, Bin; Gan, Lei; Yang, Qingyuan; Zhong, Chongli; Li, Jian-Rong

    2015-03-15

    Exploitation of new metal–organic framework (MOF) materials with high surface areas has been attracting great attention in related research communities due to their broad potential applications. In this work, a new Zr(IV)-based MOF, [Zr{sub 6}O{sub 4}(OH){sub 4}(eddb){sub 6}] (BUT-30, H{sub 2}eddb=4,4′-(ethyne-1,2-diyl)dibenzoic acid) has been solvothermally synthesized, characterized, and explored for gases and dyes adsorptions. Single-crystal X-ray diffraction analysis demonstrates a three-dimensional cubic framework structure of this MOF, in which each Zr{sub 6}O{sub 4}(OH){sub 4} building unit is linked by 12 linear eddb ligands. BUT-30 has been found stable up to 400 °C and has a Brunauer–Emmett–Teller (BET) surface area as high as 3940.6 m{sup 2} g{sup −1} (based on the N{sub 2} adsorption at 77 K) and total pore volume of 1.55 cm{sup 3} g{sup −1}. It is more interesting that this MOF exhibits stepwise adsorption behaviors for Ar, N{sub 2}, and CO{sub 2} at low temperatures, and selective uptakes towards different ionic dyes. - Graphical abstract: A new Zr(IV)-based MOF with high surface area has been synthesized and structurally characterized, which shows stepwise gas adsorption at low temperature and selective dye uptake from solution. - Highlights: • A new Zr-based MOF was synthesized and structurally characterized. • This MOF shows a higher surface area compared with its analogous UiO-67 and 68. • This MOF shows a rare stepwise adsorption towards light gases at low temperature. • This MOF performs selective uptakes towards cationic dyes over anionic ones. • Using triple-bond spacer is confirmed feasible in enhancing MOF surface areas.

  7. Realistic multisite lattice-gas modeling and KMC simulation of catalytic surface reactions: Kinetics and multiscale spatial behavior for CO-oxidation on metal (100) surfaces

    SciTech Connect (OSTI)

    Liu, Dajiang [Ames Laboratory; Evans, James W. [Ames Laboratory

    2013-12-01

    A realistic molecular-level description of catalytic reactions on single-crystal metal surfaces can be provided by stochastic multisite lattice-gas (msLG) models. This approach has general applicability, although in this report, we will focus on the example of CO-oxidation on the unreconstructed fcc metal (100) or M(100) surfaces of common catalyst metals M = Pd, Rh, Pt and Ir (i.e., avoiding regimes where Pt and Ir reconstruct). These models can capture the thermodynamics and kinetics of adsorbed layers for the individual reactants species, such as CO/M(100) and O/M(100), as well as the interaction and reaction between different reactant species in mixed adlayers, such as (CO + O)/M(100). The msLG models allow population of any of hollow, bridge, and top sites. This enables a more flexible and realistic description of adsorption and adlayer ordering, as well as of reaction configurations and configuration-dependent barriers. Adspecies adsorption and interaction energies, as well as barriers for various processes, constitute key model input. The choice of these energies is guided by experimental observations, as well as by extensive Density Functional Theory analysis. Model behavior is assessed via Kinetic Monte Carlo (KMC) simulation. We also address the simulation challenges and theoretical ramifications associated with very rapid diffusion and local equilibration of reactant adspecies such as CO. These msLG models are applied to describe adsorption, ordering, and temperature programmed desorption (TPD) for individual CO/M(100) and O/M(100) reactant adlayers. In addition, they are also applied to predict mixed (CO + O)/M(100) adlayer structure on the nanoscale, the complete bifurcation diagram for reactive steady-states under continuous flow conditions, temperature programmed reaction (TPR) spectra, and titration reactions for the CO-oxidation reaction. Extensive and reasonably successful comparison of model predictions is made with experimental data. Furthermore

  8. Analysis of tank 4 (FTF-4-15-22, 23) surface and subsurface supernatant samples in support of enrichment control, corrosion control and evaporator feed qualification programs

    SciTech Connect (OSTI)

    Oji, L. N.

    2015-09-09

    This report provides the results of analyses on Savannah River Site Tank 4 surface and subsurface supernatant liquid samples in support of the Enrichment Control Program (ECP), the Corrosion Control Program (CCP) and the Evaporator Feed Qualification (EFQ) Program. The purpose of the ECP sample taken from Tank 4 in August 2015 was to determine if the supernatant liquid would be “acceptable feed” to the 2H and 3H evaporator systems.

  9. Surface water sampling and analysis plan for environmental monitoring in Waste Area Grouping 6 at Oak Ridge National Laboratory, Oak Ridge, Tennessee. Environmental Restoration Program

    SciTech Connect (OSTI)

    Not Available

    1994-06-01

    This Sampling and Analysis Plan addresses surface water monitoring, sampling, and analysis activities that will be conducted in support of the Environmental Monitoring Plan for Waste Area Grouping (WAG) 6. WAG 6 is a shallow-burial land disposal facility for low-level radioactive waste at the Oak Ridge National Laboratory, a research facility owned by the US Department of Energy and managed by Martin Marietta Energy Systems, Inc. Surface water monitoring will be conducted at nine sites within WAG 6. Activities to be conducted will include the installation, inspection, and maintenance of automatic flow-monitoring and sampling equipment and manual collection of various water and sediment samples. The samples will be analyzed for various organic, inorganic, and radiological parameters. The information derived from the surface water monitoring, sampling, and analysis will aid in evaluating risk associated with contaminants migrating off-WAG, and will be used in calculations to establish relationships between contaminant concentration (C) and flow (Q). The C-Q relationship will be used in calculating the cumulative risk associated with the off-WAG migration of contaminants.

  10. Advanced Natural Gas Reciprocating Engine: Parasitic Loss Control through Surface Modification

    SciTech Connect (OSTI)

    Farshid Sadeghi; Chin-Pei Wang

    2008-12-31

    This report presents results of our investigation on parasitic loss control through surface modification in reciprocating engine. In order to achieve the objectives several experimental and corresponding analytical models were designed and developed to corroborate our results. Four different test rigs were designed and developed to simulate the contact between the piston ring and cylinder liner (PRCL) contact. The Reciprocating Piston Test Rig (RPTR) is a novel suspended liner test apparatus which can be used to accurately measure the friction force and side load at the piston-cylinder interface. A mixed lubrication model for the complete ring-pack and piston skirt was developed to correlate with the experimental measurements. Comparisons between the experimental and analytical results showed good agreement. The results revealed that in the reciprocating engines higher friction occur near TDC and BDC of the stroke due to the extremely low piston speed resulting in boundary lubrication. A Small Engine Dynamometer Test Rig was also designed and developed to enable testing of cylinder liner under motored and fired conditions. Results of this study provide a baseline from which to measure the effect of surface modifications. The Pin on Disk Test Rig (POD) was used in a flat-on-flat configuration to study the friction effect of CNC machining circular pockets and laser micro-dimples. The results show that large and shallow circular pockets resulted in significant friction reduction. Deep circular pockets did not provide much load support. The Reciprocating Liner Test Rig (RLTR) was designed to simplifying the contact at the PRCL interface. Accurate measurement of friction was obtained using 3-axis piezoelectric force transducer. Two fiber optic sensors were used to measure the film thickness precisely. The results show that the friction force is reduced through the use of modified surfaces. The Shear Driven Test Rig (SDTR) was designed to simulate the mechanism of the

  11. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Equipment Blank Data ...

  12. Analysis of tank 39H (HTF-39-15-61, 62) surface and subsurface supernatant samples in support of corrosion control program

    SciTech Connect (OSTI)

    Oji, L. N.

    2015-08-19

    This report provides the results of analyses on Tanks 39H surface and subsurface supernatant liquid samples in support of the Corrosion Control Program. Analyses included warm acid strike preparation followed by analysis for silicon, aluminum, and sodium and water dilution preparation followed by analysis for anions. Other reported analytical results include analyses results for uranium, Pu-241 and Pu-239.

  13. Highly Effective Pt-Based Water-Gas Shift Catalysts by Surface Modification with Alkali Hydroxide Salts

    SciTech Connect (OSTI)

    Kusche, Matthias; Bustillo, Karen; Agel, Friederike; Wasserscheid, Peter

    2015-01-29

    Here, we describe an economical and convenient method to improve the performance of Pt/alumina catalysts for the water–gas shift reaction through surface modification of the catalysts with alkali hydroxides according to the solid catalyst with ionic liquid layer approach. The results are in agreement with our findings reported earlier for methanol steam reforming. This report indicates that alkali doping of the catalyst plays an important role in the observed catalyst activation. In addition, the basic and hygroscopic nature of the salt coating contributes to a significant improvement in the performance of the catalyst. During the reaction, a partly liquid film of alkali hydroxide forms on the alumina surface, which increases the availability of H2O at the catalytically active sites. Kinetic studies reveal a negligible effect of the KOH coating on the rate dependence of CO and H2O partial pressures. In conclusion, TEM studies indicate an agglomeration of the active Pt clusters during catalyst preparation; restructuring of Pt nanoparticles occurs under reaction conditions, which leads to a highly active and stable system over 240h time on stream. Excessive pore fillings with KOH introduce a mass transfer barrier as indicated in a volcano-shaped curve of activity versus salt loading. The optimum KOH loading was found to be 7.5wt%.

  14. Highly Effective Pt-Based Water-Gas Shift Catalysts by Surface Modification with Alkali Hydroxide Salts

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kusche, Matthias; Bustillo, Karen; Agel, Friederike; Wasserscheid, Peter

    2015-01-29

    Here, we describe an economical and convenient method to improve the performance of Pt/alumina catalysts for the water–gas shift reaction through surface modification of the catalysts with alkali hydroxides according to the solid catalyst with ionic liquid layer approach. The results are in agreement with our findings reported earlier for methanol steam reforming. This report indicates that alkali doping of the catalyst plays an important role in the observed catalyst activation. In addition, the basic and hygroscopic nature of the salt coating contributes to a significant improvement in the performance of the catalyst. During the reaction, a partly liquid filmmore » of alkali hydroxide forms on the alumina surface, which increases the availability of H2O at the catalytically active sites. Kinetic studies reveal a negligible effect of the KOH coating on the rate dependence of CO and H2O partial pressures. In conclusion, TEM studies indicate an agglomeration of the active Pt clusters during catalyst preparation; restructuring of Pt nanoparticles occurs under reaction conditions, which leads to a highly active and stable system over 240h time on stream. Excessive pore fillings with KOH introduce a mass transfer barrier as indicated in a volcano-shaped curve of activity versus salt loading. The optimum KOH loading was found to be 7.5wt%.« less

  15. CARMA SURVEY TOWARD INFRARED-BRIGHT NEARBY GALAXIES (STING). III. THE DEPENDENCE OF ATOMIC AND MOLECULAR GAS SURFACE DENSITIES ON GALAXY PROPERTIES

    SciTech Connect (OSTI)

    Wong, Tony; Xue, Rui; Bolatto, Alberto D.; Fisher, David B.; Vogel, Stuart N.; Leroy, Adam K.; Blitz, Leo; Rosolowsky, Erik; Bigiel, Frank; Ott, Jrgen; Rahman, Nurur; Walter, Fabian

    2013-11-01

    We investigate the correlation between CO and H I emission in 18 nearby galaxies from the CARMA Survey Toward IR-Bright Nearby Galaxies (STING) at sub-kpc and kpc scales. Our sample, spanning a wide range in stellar mass and metallicity, reveals evidence for a metallicity dependence of the H I column density measured in regions exhibiting CO emission. Such a dependence is predicted by the equilibrium model of McKee and Krumholz, which balances H{sub 2} formation and dissociation. The observed H I column density is often smaller than predicted by the model, an effect we attribute to unresolved clumping, although values close to the model prediction are also seen. We do not observe H I column densities much larger than predicted, as might be expected were there a diffuse H I component that did not contribute to H{sub 2} shielding. We also find that the H{sub 2} column density inferred from CO correlates strongly with the stellar surface density, suggesting that the local supply of molecular gas is tightly regulated by the stellar disk.

  16. Gas chromatography/matrix-isolation apparatus

    DOE Patents [OSTI]

    Reedy, G.T.

    1986-06-10

    A gas-sample collection device provides matrix isolation of individual gas bands from a gas chromatographic separation and for the spectroscopic analysis of the individual sample bands. The device includes a vacuum chamber containing a rotatably supported, specular carousel having at least one reflecting surface for holding a sample deposited thereon. A gas inlet is provided for depositing a mixture of sample and matrix material on the reflecting surface which is maintained at a sufficiently low temperature to cause solidification. A first parabolic mirror directs an incident beam of electromagnetic radiation, such as in the infrared (IR) spectrum, from a source onto the sample/matrix mixture while a second parabolic mirror directs a second beam of electromagnetic radiation reflected by the specular surface to an IR spectrometer for determining the absorption spectra of the sample material deposited on the reflecting surface. The pair of off-axis parabolic mirrors having a common focal point are positioned outside of the vacuum chamber and may be displaced in combination for improved beam positioning and alignment. The carousel is provided with an aperture for each reflecting surface to facilitate accurate positioning of the incident beam relative to the gas-samples under analysis. Improved gas-sample deposition is insured by the use of a long focal length stereomicroscope positioned outside of the vacuum chamber for monitoring sample formation through a window, while the sample collector is positioned outside of the zone bounded by the incident and reflected electromagnetic beams for improved sample access and monitoring. 10 figs.

  17. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye

    1988-01-01

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  18. Gas separating

    DOE Patents [OSTI]

    Gollan, Arye Z. [Newton, MA

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing.

  19. Y-12 Groundwater Protection Program Groundwater And Surface Water Sampling And Analysis Plan For Calendar Year 2014

    SciTech Connect (OSTI)

    2013-09-01

    This plan provides a description of the groundwater and surface water quality monitoring activities planned for calendar year (CY) 2014 at the U.S. Department of Energy (DOE) Y-12 National Security Complex (Y-12) that will be managed by the Y-12 Groundwater Protection Program (GWPP). Groundwater and surface water monitoring is performed by the GWPP during CY 2014 to achieve the following goals: 􀁸 to protect the worker, the public, and the environment; 􀁸 to maintain surveillance of existing and potential groundwater contamination sources; 􀁸 to provide for the early detection of groundwater contamination and determine the quality of groundwater and surface water where contaminants are most likely to migrate beyond the Oak Ridge Reservation property line; 􀁸 to identify and characterize long-term trends in groundwater quality at Y-12; and 􀁸 to provide data to support decisions concerning the management and protection of groundwater resources. Groundwater and surface water monitoring will be performed in three hydrogeologic regimes at Y-12.

  20. Surface carbonation of synthetic C-S-H samples: A comparison between fresh and aged C-S-H using X-ray photoelectron spectroscopy

    SciTech Connect (OSTI)

    Black, Leon Garbev, Krassimir; Gee, Ian

    2008-06-15

    This paper presents a continuation of studies into silicate anion structure using X-ray photoelectron spectroscopy (XPS). A series of C-S-H samples have been prepared mechanochemically, and then stored under ambient conditions for six months. Storage led to surface carbonation, the extent of which was dependent upon the calcium/silicon ratio of the fresh sample. Carbonation arose through decalcification of the C-S-H, leading to increased silicate polymerisation. The surfaces of the most calcium-rich phases (C/S = 1.33 and 1.50) underwent complete decalcification to yield silica (possibly containing some silanol groups) and calcium carbonate. Carbonation, and hence changes in silicate anion structure, was minimal for the C-S-H phases with C/S = 0.67 and 0.75.

  1. Geophysical investigation at Mustard Gas Burial Ground, Naval Surface Warfare Center, Crane Division, Crane, Indiana. Final report

    SciTech Connect (OSTI)

    Llopis, J.L.; Sjostrom, K.J.; Murphy, W.L.

    1997-06-01

    A geophysical investigation was conducted at the Mustard Gas Burial Ground (MGBG) at the Naval Surface Warfare Center, Crane Division, Crane, IN. The MGBG, an approximately 2-acre area, is a former Solid Waste Management Unit. The objective of the investigation was to detect and delineate anomalies indicating the locations of buried structures, objects, or disturbed zones associated with past hazardous waste burial at the MGBG. The locations of these objects are needed so they can be excavated for removal to a permanent treatment or disposal site. Frequency and time domain electromagnetic (EM) along with magnetic survey methods were used at the MGBG. All the surveys performed at the MGBG indicated an anomalous area approximately 10 ft in diameter centered on Station 255 on Line 130. The estimated depth of the anomaly, based on results of the transient EM surveys, is 1 to 2 ft. The anomaly is presumed to be ferrous in nature since it was detected by the magnetometer. An additional, 2- to 3-ft diameter anomaly, caused by a small metallic object was detected by the transient EM surveys.

  2. Natural Gas Weekly Update

    Gasoline and Diesel Fuel Update (EIA)

    Weekly Underground Natural Gas Storage Report. The sample change occurred over a transition period that began with the release of the Weekly Natural Gas Storage Report (WNGSR)...

  3. Recovery Efficiency, False Negative Rate, and Limit of Detection Performance of a Validated Macrofoam-Swab Sampling Method with Low Surface Concentrations of Two Bacillus anthracis Surrogates

    SciTech Connect (OSTI)

    Piepel, Gregory F.; Hutchison, Janine R.; Deatherage Kaiser, Brooke L; Amidan, Brett G.; Sydor, Michael A.; Barrett, Christopher A.

    2015-03-31

    The performance of a macrofoam-swab sampling method was evaluated using Bacillus anthracis Sterne (BAS) and Bacillus atrophaeus Nakamura (BG) spores applied at nine low target amounts (2-500 spores) to positive-control plates and test coupons (2 in. × 2 in.) of four surface materials (glass, stainless steel, vinyl tile, and plastic). Test results from cultured samples were used to evaluate the effects of surrogate, surface concentration, and surface material on recovery efficiency (RE), false negative rate (FNR), and limit of detection. For RE, surrogate and surface material had statistically significant effects, but concentration did not. Mean REs were the lowest for vinyl tile (50.8% with BAS, 40.2% with BG) and the highest for glass (92.8% with BAS, 71.4% with BG). FNR values ranged from 0 to 0.833 for BAS and 0 to 0.806 for BG, with values increasing as concentration decreased in the range tested (0.078 to 19.375 CFU/cm2, where CFU denotes ‘colony forming units’). Surface material also had a statistically significant effect. A FNR-concentration curve was fit for each combination of surrogate and surface material. For both surrogates, the FNR curves tended to be the lowest for glass and highest for vinyl title. The FNR curves for BG tended to be higher than for BAS at lower concentrations, especially for glass. Results using a modified Rapid Viability-Polymerase Chain Reaction (mRV-PCR) analysis method were also obtained. The mRV-PCR results and comparisons to the culture results will be discussed in a subsequent report.

  4. Investigation of Cathode Electrocatalytic Activity using Surface Engineered Thin Film Samples and High Temperature Physical Property Measurements

    SciTech Connect (OSTI)

    Salvador, Paul

    2014-02-23

    In this Final Technical Report, a summary of the technical output from the award DE-NT0004105 is given. First, the major goals and observations from the project are reviewed and then specific example results are presented as highlights. The surprising importance of microstructure on the surface chemical exchange coefficient in La0.7Sr0.3MnO3 (LSM) was uncovered in this work and is re-emphasized in this report. Significant orientation and thickness dependencies of the surface exchange coefficient are correlated with microstructural effects, especially to the nature of the strain, dislocation content, and grain boundary population. We also illustrate similar microstructural effects are present in other SOFC cathode systems, including LSCF (La1-xSrxCo1-yFeyO3) and La2NiO4 (LNO). Throughout the report, the relation to SOFC cathode performance is discussed.

  5. September 2004 Water Sampling

    Office of Legacy Management (LM)

    5 Groundwater and Surface Water Sampling at the Tuba City, Arizona Disposal Site June 2015 .........7 Water Sampling Field Activities Verification ...

  6. Externally pressurized porous cylinder for multiple surface aerosol generation and method of generation

    DOE Patents [OSTI]

    Apel, Charles T.; Layman, Lawrence R.; Gallimore, David L.

    1988-01-01

    A nebulizer for generating aerosol having small droplet sizes and high efficiency at low sample introduction rates. The nebulizer has a cylindrical gas permeable active surface. A sleeve is disposed around the cylinder and gas is provided from the sleeve to the interior of the cylinder formed by the active surface. In operation, a liquid is provided to the inside of the gas permeable surface. The gas contacts the wetted surface and forms small bubbles which burst to form an aerosol. Those bubbles which are large are carried by momentum to another part of the cylinder where they are renebulized. This process continues until the entire sample is nebulized into aerosol sized droplets.

  7. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........9 Water Sampling Field Activities Verification ... Data Durango Processing Site Surface Water Quality Data Equipment Blank Data Static ...

  8. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Time-Concentration Graph ...

  9. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........9 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Static Water Level Data ...

  10. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........3 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Time-Concentration Graphs ...

  11. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........7 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Equipment Blank Data Static ...

  12. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Groundwater Quality Data Surface Water Quality Data Equipment Blank Data Static ...

  13. CONTINUOUS GAS ANALYZER

    DOE Patents [OSTI]

    Katz, S.; Weber, C.W.

    1960-02-16

    A reagent gas and a sample gas are chemically combined on a continuous basis in a reaction zone maintained at a selected temperature. The reagent gas and the sample gas are introduced to the reaction zone at preselected. constant molar rates of flow. The reagent gas and the selected gas in the sample mixture combine in the reaction zone to form a product gas having a different number of moles from the sum of the moles of the reactants. The difference in the total molar rates of flow into and out of the reaction zone is measured and indicated to determine the concentration of the selected gas.

  14. Device for collecting and analyzing matrix-isolated samples

    DOE Patents [OSTI]

    Reedy, Gerald T.

    1979-01-01

    A gas-sample collection device is disclosed for matrix isolation of individual gas bands from a gas chromatographic separation and for presenting these distinct samples for spectrometric examination. The device includes a vacuum chamber containing a rotatably supported, specular carrousel having a number of external, reflecting surfaces around its axis of rotation for holding samples. A gas inlet is provided for depositing sample and matrix material on the individual reflecting surfaces maintained at a sufficiently low temperature to cause solidification. Two optical windows or lenses are installed in the vacuum chamber walls for transmitting a beam of electromagnetic radiation, for instance infrared light, through a selected sample. Positioned within the chamber are two concave mirrors, the first aligned to receive the light beam from one of the lenses and focus it to the sample on one of the reflecting surfaces of the carrousel. The second mirror is aligned to receive reflected light from that carrousel surface and to focus it outwardly through the second lens. The light beam transmitted from the sample is received by a spectrometer for determining absorption spectra.

  15. Sampling apparatus

    DOE Patents [OSTI]

    Gordon, Norman R.; King, Lloyd L.; Jackson, Peter O.; Zulich, Alan W.

    1989-01-01

    A sampling apparatus is provided for sampling substances from solid surfaces. The apparatus includes first and second elongated tubular bodies which telescopically and sealingly join relative to one another. An absorbent pad is mounted to the end of a rod which is slidably received through a passageway in the end of one of the joined bodies. The rod is preferably slidably and rotatably received through the passageway, yet provides a selective fluid tight seal relative thereto. A recess is formed in the rod. When the recess and passageway are positioned to be coincident, fluid is permitted to flow through the passageway and around the rod. The pad is preferably laterally orientable relative to the rod and foldably retractable to within one of the bodies. A solvent is provided for wetting of the pad and solubilizing or suspending the material being sampled from a particular surface.

  16. Sampling apparatus

    DOE Patents [OSTI]

    Gordon, N.R.; King, L.L.; Jackson, P.O.; Zulich, A.W.

    1989-07-18

    A sampling apparatus is provided for sampling substances from solid surfaces. The apparatus includes first and second elongated tubular bodies which telescopically and sealingly join relative to one another. An absorbent pad is mounted to the end of a rod which is slidably received through a passageway in the end of one of the joined bodies. The rod is preferably slidably and rotatably received through the passageway, yet provides a selective fluid tight seal relative thereto. A recess is formed in the rod. When the recess and passageway are positioned to be coincident, fluid is permitted to flow through the passageway and around the rod. The pad is preferably laterally orientable relative to the rod and foldably retractable to within one of the bodies. A solvent is provided for wetting of the pad and solubilizing or suspending the material being sampled from a particular surface. 15 figs.

  17. Gas separating

    DOE Patents [OSTI]

    Gollan, A.

    1988-03-29

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  18. Gas separating

    DOE Patents [OSTI]

    Gollan, A.Z.

    1990-12-25

    Feed gas is directed tangentially along the non-skin surface of gas separation membrane modules comprising a cylindrical bundle of parallel contiguous hollow fibers supported to allow feed gas to flow from an inlet at one end of a cylindrical housing through the bores of the bundled fibers to an outlet at the other end while a component of the feed gas permeates through the fibers, each having the skin side on the outside, through a permeate outlet in the cylindrical casing. 3 figs.

  19. Friction surfaced Stellite6 coatings

    SciTech Connect (OSTI)

    Rao, K. Prasad; Damodaram, R.; Rafi, H. Khalid; Ram, G.D. Janaki; Reddy, G. Madhusudhan; Nagalakshmi, R.

    2012-08-15

    Solid state Stellite6 coatings were deposited on steel substrate by friction surfacing and compared with Stellite6 cast rod and coatings deposited by gas tungsten arc and plasma transferred arc welding processes. Friction surfaced coatings exhibited finer and uniformly distributed carbides and were characterized by the absence of solidification structure and compositional homogeneity compared to cast rod, gas tungsten arc and plasma transferred coatings. Friction surfaced coating showed relatively higher hardness. X-ray diffraction of samples showed only face centered cubic Co peaks while cold worked coating showed hexagonally close packed Co also. - Highlights: Black-Right-Pointing-Pointer Stellite6 used as coating material for friction surfacing. Black-Right-Pointing-Pointer Friction surfaced (FS) coatings compared with casting, GTA and PTA processes. Black-Right-Pointing-Pointer Finer and uniformly distributed carbides in friction surfaced coatings. Black-Right-Pointing-Pointer Absence of melting results compositional homogeneity in FS Stellite6 coatings.

  20. Radionuclides, Metals, and Hydrocarbons in Oil and Gas Operational Discharges and Environmental Samples Associated with Offshore Production Facilities on the Texas/Louisiana Continental Shelf with an Environmental Assessment of Metals and Hydrocarbons

    SciTech Connect (OSTI)

    Continental Shelf Associates, Inc.

    1999-08-16

    This report presents concentrations of radionuclides, metals, and hydrocarbons in samples of produced water and produced sand from oil and gas production platforms located offshore Texas and Louisiana. Concentrations in produced water discharge plume/receiving water, ambient seawater, sediment, interstitial water, and marine animal tissue samples collected in the vicinity of discharging platforms and reference sites distant from discharges are also reported and discussed. An environmental risk assessment is made on the basis of the concentrations of metals and hydrocarbons determined in the samples.

  1. Radionuclides, Metals, and Hydrocarbons in Oil and Gas Operational Discharges and Environmental Samples Associated with Offshore Production Facilities on the Texas/Louisiana Continental Shelf with an Environmental Assessment of Metals and Hydrocarbons.

    SciTech Connect (OSTI)

    1997-06-01

    This report presents concentrations of radionuclides, metals, and hydrocarbons in samples of produced water and produced sand from oil and gas production platforms located offshore Texas and Louisiana. concentrations in produced water discharge plume / receiving water, ambient seawater, sediment, interstitial water, and marine animal tissue samples collected in the vicinity of discharging platforms and reference sites distant from discharges are also reported and discussed. An environmental risk assessment is made on the basis of the concentration of metals and hydrocarbons determined in the samples.

  2. ARTIFACT FORMATION DURING NEUTRALIZATION OF TANK 50 SAMPLES

    SciTech Connect (OSTI)

    Crump, S.; Young, J.

    2014-08-01

    Degradation products have been identified in the extracts of Tank 50 samples analyzed by semivolatile organic compound analysis (SVOA) using gas chromatography/mass spectrometry (GC/MS). These materials, identified as short chain alkyl alcohols, were formed by acidification during sample preparation. A number of questions were raised about the formation of these and other materials reported in Tank 50 surface samples, and this report serves to address these questions.

  3. False Negative Rates of a Macrofoam-Swab Sampling Method with Low Surface Concentrations of Two Bacillus anthracis Surrogates via Real-Time PCR

    SciTech Connect (OSTI)

    Hutchison, Janine R.; Piepel, Gregory F.; Amidan, Brett G.; Sydor, Michael A.; Deatherage Kaiser, Brooke L

    2015-05-01

    Surface sampling for Bacillus anthracis spores has traditionally relied on detection via bacterial cultivation methods. Although effective, this approach does not provide the level of organism specificity that can be gained through molecular techniques. False negative rates (FNR) and limits of detection (LOD) were determined for two B. anthracis surrogates with modified rapid viability-polymerase chain reaction (mRV-PCR) following macrofoam-swab sampling. This study was conducted in parallel with a previously reported study that analyzed spores using a plate-culture method. B. anthracis Sterne (BAS) or B. atrophaeus Nakamura (BG) spores were deposited onto four surface materials (glass, stainless steel, vinyl tile, and plastic) at nine target concentrations (2 to 500 spores/coupon; 0.078 to 19.375 colony-forming units [CFU] per cm²). Mean FNR values for mRV-PCR analysis ranged from 0 to 0.917 for BAS and 0 to 0.875 for BG and increased as spore concentration decreased (over the concentrations investigated) for each surface material. FNRs based on mRV-PCR data were not statistically different for BAS and BG, but were significantly lower for glass than for vinyl tile. FNRs also tended to be lower for the mRV-PCR method compared to the culture method. The mRV-PCR LOD₉₅ was lowest for glass (0.429 CFU/cm² with BAS and 0.341 CFU/cm² with BG) and highest for vinyl tile (0.919 CFU/cm² with BAS and 0.917 CFU/cm² with BG). These mRV-PCR LOD₉₅ values were lower than the culture values (BAS: 0.678 to 1.023 CFU/cm² and BG: 0.820 to 1.489 CFU/cm²). The FNR and LOD₉₅ values reported in this work provide guidance for environmental sampling of Bacillus spores at low concentrations.

  4. Surface characterizatin of palladium-alumina sorbents for high-temperature capture of mercury and arsenic from fuel gas

    SciTech Connect (OSTI)

    Baltrus, J.P.; Granite, E.J.; Pennline, H.W.; Stanko, D.; Hamilton, H.; Rowsell, L.; Poulston, S.; Smith, A.; Chu, W.

    2010-01-01

    Coal gasification with subsequent cleanup of the resulting fuel gas is a way to reduce the impact of mercury and arsenic in the environment during power generation and on downstream catalytic processes in chemical production, The interactions of mercury and arsenic with PdlAl2D3 model thin film sorbents and PdlAh03 powders have been studied to determine the relative affinities of palladium for mercury and arsenic, and how they are affected by temperature and the presence of hydrogen sulfide in the fuel gas. The implications of the results on strategies for capturing the toxic metals using a sorbent bed are discussed.

  5. Liquid sampling system

    DOE Patents [OSTI]

    Larson, L.L.

    1984-09-17

    A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed. 5 figs.

  6. Liquid sampling system

    DOE Patents [OSTI]

    Larson, Loren L.

    1987-01-01

    A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed.

  7. Analysis of Tank 38H (HTF-38-15-47, 49) and Tank 43H (HTF-43-15-51, 53) surface and subsurface supernatant samples in support of enrichment and corrosion control programs

    SciTech Connect (OSTI)

    Oji, L. N.

    2015-06-30

    This report provides the results of analyses on Tanks 38H and 43H surface and subsurface supernatant liquid samples in support of the Enrichment Control Program (ECP) and the Corrosion Control Program (CCP).

  8. Matrix isolation apparatus with extended sample collection capability

    DOE Patents [OSTI]

    Reedy, Gerald T.

    1987-01-01

    A gas-sample collection device provides for the matrix isolation of increased amounts of a sample material for spectrographic analysis from a gas chromatographic separation. The device includes an evacuated sample collection chamber containing a disc-like specular carousel having a generally circular lateral surface upon which the sample is deposited in an inert gas matrix for infrared (IR) spectral analysis. The evacuated sample chamber is mounted in a fixed manner and is coupled to and supports a rotating cryostatic coupler which, in turn, supports the specular carousel within the collection chamber. A rotational drive system connected to the cryostatic coupler provides for its rotational displacement as well as that of the sample collecting carousel. In addition, rotation of the cryostatic coupler effects vertical displacement of the carousel to permit the collection of an extended sample band in a helical configuration on the entire lateral surface of the carousel. The various components of the carousel's angular/linear displacement drive system are located exterior to the cryostatic coupler for easy access and improved operation. The cryostatic coupler includes a 360.degree. rotary union assembly for permitting the delivery of a high pressure working fluid to the cryostatic coupler in a continuous flow manner for maintaining the specular carousel at a low temperature, e.g., 10.degree.-20.degree. K., for improved uninterrupted gas sample collection and analysis.

  9. Smoothing single-crystalline SiC surfaces by reactive ion etching using pure NF{sub 3} and NF{sub 3}/Ar mixture gas plasmas

    SciTech Connect (OSTI)

    Tasaka, Akimasa; Kotaka, Yuki; Oda, Atsushi; Saito, Morihiro; Tojo, Tetsuro; Inaba, Minoru

    2014-09-01

    In pure NF{sub 3} plasma, the etching rates of four kinds of single-crystalline SiC wafer etched at NF{sub 3} pressure of 2 Pa were the highest and it decreased with an increase in NF{sub 3} pressure. On the other hand, they increased with an increase in radio frequency (RF) power and were the highest at RF power of 200 W. A smooth surface was obtained on the single-crystalline 4H-SiC after reactive ion etching at NF{sub 3}/Ar gas pressure of 2 Pa and addition of Ar to NF{sub 3} plasma increased the smoothness of SiC surface. Scanning electron microscopy observation revealed that the number of pillars decreased with an increase in the Ar-concentration in the NF{sub 3}/Ar mixture gas. The roughness factor (R{sub a}) values were decreased from 51.5 nm to 25.5 nm for the As-cut SiC, from 0.25 nm to 0.20 nm for the Epi-SiC, from 5.0 nm to 0.7 nm for the Si-face mirror-polished SiC, and from 0.20 nm to 0.16 nm for the C-face mirror-polished SiC by adding 60% Ar to the NF{sub 3} gas. Both the R{sub a} values of the Epi- and the C-face mirror-polished wafer surfaces etched using the NF{sub 3}/Ar (40:60) plasma were similar to that treated with mirror polishing, so-called the Catalyst-Referred Etching (CARE) method, with which the lowest roughness of surface was obtained among the chemical mirror polishing methods. Etching duration for smoothing the single-crystalline SiC surface using its treatment was one third of that with the CARE method.

  10. Polyport atmospheric gas sampler

    DOE Patents [OSTI]

    Guggenheim, S. Frederic

    1995-01-01

    An atmospheric gas sampler with a multi-port valve which allows for multi, sequential sampling of air through a plurality of gas sampling tubes mounted in corresponding gas inlet ports. The gas sampler comprises a flow-through housing which defines a sampling chamber and includes a gas outlet port to accommodate a flow of gases through the housing. An apertured sample support plate defining the inlet ports extends across and encloses the sampling chamber and supports gas sampling tubes which depend into the sampling chamber and are secured across each of the inlet ports of the sample support plate in a flow-through relation to the flow of gases through the housing during sampling operations. A normally closed stopper means mounted on the sample support plate and operatively associated with each of the inlet ports blocks the flow of gases through the respective gas sampling tubes. A camming mechanism mounted on the sample support plate is adapted to rotate under and selectively lift open the stopper spring to accommodate a predetermined flow of gas through the respective gas sampling tubes when air is drawn from the housing through the outlet port.

  11. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Groundwater, Surface Water, and Alternate Water Supply System Sampling at the Riverton, Wyoming, Processing Site December 2013 LMSRVTS00913 This page intentionally left blank ...

  12. Electrochemical, Structural and Surface Characterization of Nickel/Zirconia Solid Oxide Fuel Cell Anodes in Coal Gas Containing Antimony

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.; Coyle, Christopher A.; Thomsen, Edwin C.; Nachimuthu, Ponnusamy; Edwards, Danny J.

    2011-02-27

    The interaction of antimony with the nickel-zirconia solid oxide fuel cell (SOFC) anode has been investigated. Tests with both anode-supported and electrolyte-supported button cells were performed at 700 and 800oC in synthetic coal gas containing 10 ppb to 9 ppm antimony. Minor performance loss was observed immediately after Sb introduction to coal gas resulting in ca. 5 % power output drop. While no further degradation was observed during the following several hundred hours of testing, cells abruptly and irreversibly failed after 800-1500 hours depending on Sb concentration and test temperature. Antimony was found to interact strongly with nickel and result in extensive alteration phase formation, consistent with expectations based on thermodynamic properties. Nickel antimonide phases, NiSb and Ni5Sb2, were partially coalesced into large grains and eventually affected electronic percolation through the anode support. Initial degradation was attributed to diffusion of antimony to the active anode/electrolyte interface to form an adsorption layer.

  13. Surface Soil

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface Soil Surface Soil We compare local soil samples with samples collected from northern New Mexico locations that are beyond the range of potential influence from normal Laboratory operations. April 12, 2012 Farm soil sampling Two LANL environmental field team members take soil samples from a farm. Contact Environmental Communication & Public Involvement P.O. Box 1663 MS M996 Los Alamos, NM 87545 (505) 667-0216 Email Measurements are compared to samples from the regional sites and

  14. Packed-Bed Reactor Study of NETL Sample 196c for the Removal of Carbon Dioxide from Simulated Flue Gas Mixture

    SciTech Connect (OSTI)

    Hoffman, James S.; Hammache, Sonia; Gray, McMahan L.; Fauth Daniel J.; Pennline, Henry W.

    2012-04-24

    An amine-based solid sorbent process to remove CO2 from flue gas has been investigated. The sorbent consists of polyethylenimine (PEI) immobilized onto silica (SiO2) support. Experiments were conducted in a packed-bed reactor and exit gas composition was monitored using mass spectrometry. The effects of feed gas composition (CO2 and H2O), temperature, and simulated steam regeneration were examined for both the silica support as well as the PEI-based sorbent. The artifact of the empty reactor was also quantified. Sorbent CO2 capacity loading was compared to thermogravimetric (TGA) results to further characterize adsorption isotherms and better define CO2 working capacity. Sorbent stability was monitored by periodically repeating baseline conditions throughout the parametric testing and replacing with fresh sorbent as needed. The concept of the Basic Immobilized Amine Sorbent (BIAS) Process using this sorbent within a system where sorbent continuously flows between the absorber and regenerator was introduced. The basic tenet is to manipulate or control the level of moisture on the sorbent as it travels around the sorbent circulation path between absorption and regeneration stages to minimize its effect on regeneration heat duty.

  15. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    on Thursday, May 9, 2002. A sample of EIA's report can be seen at: Weekly Gas Storage Test Page. The Natural Gas Weekly Market Update report will convert to the new data series...

  16. Category:Field Sampling | Open Energy Information

    Open Energy Info (EERE)

    Technique Subcategories This category has the following 2 subcategories, out of 2 total. G + Gas Sampling (3 categories) 4 pages W + Water Sampling (2 categories) 3...

  17. Microminiature gas chromatograph

    DOE Patents [OSTI]

    Yu, C.M.

    1996-12-10

    A microminiature gas chromatograph ({mu}GC) comprising a least one silicon wafer, a gas injector, a column, and a detector. The gas injector has a normally closed valve for introducing a mobile phase including a sample gas in a carrier gas. The valve is fully disposed in the silicon wafer(s). The column is a microcapillary in silicon crystal with a stationary phase and is mechanically connected to receive the mobile phase from the gas injector for the molecular separation of compounds in the sample gas. The detector is mechanically connected to the column for the analysis of the separated compounds of sample gas with electronic means, e.g., ion cell, field emitter and PIN diode. 7 figs.

  18. Microminiature gas chromatograph

    DOE Patents [OSTI]

    Yu, Conrad M.

    1996-01-01

    A microminiature gas chromatograph (.mu.GC) comprising a least one silicon wafer, a gas injector, a column, and a detector. The gas injector has a normally closed valve for introducing a mobile phase including a sample gas in a carrier gas. The valve is fully disposed in the silicon wafer(s). The column is a microcapillary in silicon crystal with a stationary phase and is mechanically connected to receive the mobile phase from the gas injector for the molecular separation of compounds in the sample gas. The detector is mechanically connected to the column for the analysis of the separated compounds of sample gas with electronic means, e.g., ion cell, field emitter and PIN diode.

  19. Chalcogels : porous metal-chalcogenide networks from main-group metal ions. Effect of surface polarizability on selectivity in gas separation.

    SciTech Connect (OSTI)

    Bag, S.; Kanatzidis, M. G.; Materials Science Division; Northwestern Univ.

    2010-10-06

    We report the synthesis of metal-chalcogenide gels and aerogels from anionic chalcogenide clusters and linking metal ions. Metal ions such as Sb{sup 3+} and Sn{sup 2+}, respectively chelated with tartrate and acetate ligands, react in solution with the chalcogenide clusters to form extended polymeric networks that exhibit gelation phenomena. Chalcogenide cluster anions with different charge densities, such as [Sn{sub 2}S{sub 6}]{sup 4-} and [SnS{sub 4}]{sup 4-}, were employed. In situ rheological measurements during gelation showed that a higher charge density on the chalcogenide cluster favors formation of a rigid gel network. Aerogels obtained from the gels after supercritical drying have BET surface areas from 114 to 368 m{sup 2}/g. Electron microscopy images coupled with nitrogen adsorption measurements showed the pores are micro (below 2 nm), meso (2-50 nm), and macro (above 50 nm) regions. These chalcogels possess band gaps in the range of 1.00-2.00 eV and selectively adsorb polarizable gases. A 2-fold increase in selectivity toward CO{sub 2}/C{sub 2}H{sub 6} over H{sub 2} was observed for the Pt/Sb/Ge{sub 4}Se{sub 10}-containing aerogel compared to aerogel containing Pt{sub 2}Ge{sub 4}S{sub 10}. The experimental results suggest that high selectivity in gas adsorption is achievable with high-surface-area chalcogenide materials containing heavy polarizable elements.

  20. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and Surface Water Sampling at the Monument Valley, Arizona, Processing Site February 2015 LMS/MON/S01214 This page intentionally left blank U.S. Department of Energy DVP-December 2014, Monument Valley, Arizona February 2015 RIN 14126645 Page i Contents Sampling Event Summary ...............................................................................................................1 Monument Valley, Arizona, Disposal Site Sample Location Map ..................................................5

  1. September 2004 Water Sampling

    Office of Legacy Management (LM)

    February 2015 Groundwater and Surface Water Sampling at the Grand Junction, Colorado, Site April 2015 LMS/GJO/S00215 This page intentionally left blank U.S. Department of Energy DVP-February 2015, Grand Junction, Colorado, Site April 2015 RIN 15026795 Page i Contents Sampling Event Summary ...............................................................................................................1 Grand Junction, Colorado, Site Sample Location Map

  2. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Groundwater and Surface Water Sampling at the Slick Rock East and West, Colorado, Processing Sites November 2013 LMS/SRE/SRW/S0913 This page intentionally left blank U.S. Department of Energy DVP-September 2013, Slick Rock, Colorado November 2013 RIN 13095593 Page i Contents Sampling Event Summary ...............................................................................................................1 Slick Rock East and West, Colorado, Processing Sites, Sample Location Map

  3. Morphology of the surface of technically pure titanium VT1-0 after electroexplosive carbonization with a weighed zirconium oxide powder sample and electron beam treatment

    SciTech Connect (OSTI)

    Sosnin, Kirill V.; Raykov, Sergey V.; Vaschuk, Ekaterina S.; Budovskikh, Evgenie A. Gromov, Victor E.; Ivanov, Yuri F.

    2014-11-14

    Titanium is carbonized by the electroexplosive method. Formation of a surface alloyed layer and a coating on the treated surface is established by the methods of transmission electron microscopy. The morphology and elemental composition of the alloyed layer are analyzed. A dependence of the structure of the modified layer subjected to electron gun treatment on the absorbed power density is revealed.

  4. Atmospheric and soil-gas monitoring for surface leakage at the San Juan Basin CO{sub 2} pilot test site at Pump Canyon New Mexico, using perfluorocarbon tracers, CO{sub 2} soil-gas flux and soil-gas hydrocarbons

    SciTech Connect (OSTI)

    Wells, Arthur W.; Diehl, J. Rodney; Strazisar, Brian R.; Wilson, Thomas; H Stanko, Dennis C.

    2012-05-01

    Near-surface monitoring and subsurface characterization activities were undertaken in collaboration with the Southwest Regional Carbon Sequestration Partnership on their San Juan Basin coal-bed methane pilot test site near Navajo City, New Mexico. Nearly 18,407 short tons (1.670 107 kg) of CO{sub 2} were injected into 3 seams of the Fruitland coal between July 2008 and April 2009. Between September 18 and October 30, 2008, two additions of approximately 20 L each of perfluorocarbon (PFC) tracers were mixed with the CO{sub 2} at the injection wellhead. PFC tracers in soil-gas and in the atmosphere were monitored over a period of 2 years using a rectangular array of permanent installations. Additional monitors were placed near existing well bores and at other locations of potential leakage identified during the pre-injection site survey. Monitoring was conducted using sorbent containing tubes to collect any released PFC tracer from soil-gas or the atmosphere. Near-surface monitoring activities also included CO{sub 2} surface flux and carbon isotopes, soil-gas hydrocarbon levels, and electrical conductivity in the soil. The value of the PFC tracers was demonstrated when a significant leakage event was detected near an offset production well. Subsurface characterization activities, including 3D seismic interpretation and attribute analysis, were conducted to evaluate reservoir integrity and the potential that leakage of injected CO{sub 2} might occur. Leakage from the injection reservoir was not detected. PFC tracers made breakthroughs at 2 of 3 offset wells which were not otherwise directly observable in produced gases containing 2030% CO{sub 2}. These results have aided reservoir geophysical and simulation investigations to track the underground movement of CO{sub 2}. 3D seismic analysis provided a possible interpretation for the order of appearance of tracers at production wells.

  5. The galactic census of high- and medium-mass protostars. II. Luminosities and evolutionary states of a complete sample of dense gas clumps

    SciTech Connect (OSTI)

    Ma, Bo; Tan, Jonathan C.; Barnes, Peter J.

    2013-12-10

    The Census of High- and Medium-mass Protostars (CHaMP) is the first large-scale (280° < l < 300°, –4° < b < 2°), unbiased, subparsec resolution survey of Galactic molecular clumps and their embedded stars. Barnes et al. presented the source catalog of ∼300 clumps based on HCO{sup +}(1-0) emission, used to estimate masses M. Here we use archival midinfrared-to-millimeter continuum data to construct spectral energy distributions. Fitting two-temperature gray-body models, we derive bolometric luminosities, L. We find that the clumps have 10 ≲ L/L {sub ☉} ≲ 10{sup 6.5} and 0.1 ≲ L/M/[L {sub ☉}/M {sub ☉}] ≲ 10{sup 3}, consistent with a clump population spanning a range of instantaneous star-formation efficiencies from 0 to ∼50%. We thus expect L/M to be a useful, strongly varying indicator of clump evolution during the star cluster formation process. We find correlations of the ratio of warm-to-cold component fluxes and of cold component temperature with L/M. We also find a near-linear relation between L/M and Spitzer-IRAC specific intensity (surface brightness); thus, this relation may also be useful as a star-formation efficiency indicator. The lower bound of the clump L/M distribution suggests that the star-formation efficiency per free-fall time is ε{sub ff} < 0.2. We do not find strong correlations of L/M with mass surface density, velocity dispersion, or virial parameter. We find a linear relation between L and L{sub HCO{sup +}(1--0)}, although with large scatter for any given individual clump. Fitting together with extragalactic systems, the linear relation still holds, extending over 10 orders of magnitude in luminosity. The complete nature of the CHaMP survey over a several kiloparsec-scale region allows us to derive a measurement at an intermediate scale, bridging those of individual clumps and whole galaxies.

  6. Gas phase chemical detection with an integrated chemical analysis system

    SciTech Connect (OSTI)

    CASALNUOVO,STEPHEN A.; FRYE-MASON,GREGORY CHARLES; KOTTENSTETTE,RICHARD; HELLER,EDWIN J.; MATZKE,CAROLYN M.; LEWIS,PATRICK R.; MANGINELL,RONALD P.; BACA,ALBERT G.; HIETALA,VINCENT M.

    2000-04-12

    Microfabrication technology has been applied to the development of a miniature, multi-channel gas phase chemical laboratory that provides fast response, small size, and enhanced versatility and chemical discrimination. Each analysis channel includes a sample preconcentrator followed by a gas chromatographic separator and a chemically selective surface acoustic wave detector array to achieve high sensitivity and selectivity. The performance of the components, individually and collectively, is described.

  7. Water–gas shift reaction over gold nanoparticles dispersed on nanostructured CeOx–TiO2(110) surfaces: Effects of high ceria coverage

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Grinter, D. C.; Park, J. B.; Agnoli, S.; Evans, J.; Hrbek, J.; Stacchiola, D. J.; Senanayake, S. D.; Rodriguez, J. A.

    2016-08-01

    We used scanning tunnelling microscopy to study the morphology of an overlayer of ceria in contact with a TiO2(110) substrate. Two types of domains were observed after ceria deposition. An ordered ceria film covered half of the surface and high-resolution imaging suggested a near-c(6 × 2) relationship to the underlying TiO2(110)-(1 × 1). For the other half of the surface, it comprised CeOx nanoparticles and reconstructed TiOx supported on TiO2(110)-(1 × 1). Exposure to a small amount of gold resulted in the formation of isolated gold atoms and small clusters on the ordered ceria film and TiO2(110)-(1 × 1) areas,more » which exhibited significant sintering at 500 K and showed strong interaction between the sintered gold clusters and the domain boundaries of the ceria film. The Au/CeOx/TiO2(110) model system proved to be a good catalyst for the water–gas shift (WGS) exhibiting much higher turnover frequencies (TOFs) than Cu(111) and Pt(111) benchmarks, or the individual Au/TiO2(110) and Au/CeO2(111) systems. Finally, for Au/CeOx/TiO2(110) catalysts, there was a decrease in catalytic activity with increasing ceria coverage that correlates with a reduction in the concentration of Ce3 + formed during WGS reaction conditions.« less

  8. Residual gas analysis device

    DOE Patents [OSTI]

    Thornberg, Steven M.

    2012-07-31

    A system is provided for testing the hermeticity of a package, such as a microelectromechanical systems package containing a sealed gas volume, with a sampling device that has the capability to isolate the package and breach the gas seal connected to a pulse valve that can controllably transmit small volumes down to 2 nanoliters to a gas chamber for analysis using gas chromatography/mass spectroscopy diagnostics.

  9. Quantitation of repaglinide and metabolites in mouse whole-body thin tissue sections using droplet-based liquid microjunction surface sampling-high-performance liquid chromatography-electrospray ionization tandem mass spectrometry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Weiqi; Wang, Lifei; Van Berkel, Gary J.; Gan, Jinping; Kertesz, Vilmos

    2015-11-03

    Herein, quantitation aspects of a fully automated autosampler/HPLC-MS/MS system applied for unattended droplet-based surface sampling of repaglinide dosed thin tissue sections with subsequent HPLC separation and mass spectrometric analysis of parent drug and various drug metabolites was studied. Major organs (brain, lung, liver, kidney, muscle) from whole-body thin tissue sections and corresponding organ homogenates prepared from repaglinide dosed mice were sampled by surface sampling and by bulk extraction, respectively, and analyzed by HPLC-MS/MS. A semi-quantitative agreement between data obtained by surface sampling and that by employing organ homogenate extraction was observed. Drug concentrations obtained by the two methods followed themore » same patterns for post-dose time points (0.25, 0.5, 1 and 2 h). Drug amounts determined in the specific tissues was typically higher when analyzing extracts from the organ homogenates. Furthermore, relative comparison of the levels of individual metabolites between the two analytical methods also revealed good semi-quantitative agreement.« less

  10. Quantitation of repaglinide and metabolites in mouse whole-body thin tissue sections using droplet-based liquid microjunction surface sampling-high-performance liquid chromatography-electrospray ionization tandem mass spectrometry

    SciTech Connect (OSTI)

    Chen, Weiqi; Wang, Lifei; Van Berkel, Gary J.; Gan, Jinping; Kertesz, Vilmos

    2015-11-03

    Herein, quantitation aspects of a fully automated autosampler/HPLC-MS/MS system applied for unattended droplet-based surface sampling of repaglinide dosed thin tissue sections with subsequent HPLC separation and mass spectrometric analysis of parent drug and various drug metabolites was studied. Major organs (brain, lung, liver, kidney, muscle) from whole-body thin tissue sections and corresponding organ homogenates prepared from repaglinide dosed mice were sampled by surface sampling and by bulk extraction, respectively, and analyzed by HPLC-MS/MS. A semi-quantitative agreement between data obtained by surface sampling and that by employing organ homogenate extraction was observed. Drug concentrations obtained by the two methods followed the same patterns for post-dose time points (0.25, 0.5, 1 and 2 h). Drug amounts determined in the specific tissues was typically higher when analyzing extracts from the organ homogenates. Furthermore, relative comparison of the levels of individual metabolites between the two analytical methods also revealed good semi-quantitative agreement.

  11. Profiling of Adrenocorticotropic Hormone and Arginine Vasopressin in Human Pituitary Gland and Tumor Thin Tissue Sections using Droplet-Based Liquid Microjunction Surface Sampling-HPLC-ESI-MS/MS

    SciTech Connect (OSTI)

    Kertesz, Vilmos; Van Berkel, Gary J; Calligaris, David; Feldman, Daniel R; Changelian, Armen; Laws, Edward R; Santagata, Sandro; Agar, Nathalie YR

    2015-01-01

    Described here are the results from the profiling of the proteins arginine vasopressin (AVP) and adrenocorticotropic hormone (ACTH) from normal human pituitary gland and pituitary adenoma tissue sections using a fully automated droplet-based liquid microjunction surface sampling-HPLC-ESI-MS/MS system for spatially resolved sampling, HPLC separation, and mass spectral detection. Excellent correlation was found between the protein distribution data obtained with this droplet-based liquid microjunction surface sampling-HPLC-ESI-MS/MS system and those data obtained with matrix assisted laser desorption ionization (MALDI) chemical imaging analyses of serial sections of the same tissue. The protein distributions correlated with the visible anatomic pattern of the pituitary gland. AVP was most abundant in the posterior pituitary gland region (neurohypophysis) and ATCH was dominant in the anterior pituitary gland region (adenohypophysis). The relative amounts of AVP and ACTH sampled from a series of ACTH secreting and non-secreting pituitary adenomas correlated with histopathological evaluation. ACTH was readily detected at significantly higher levels in regions of ACTH secreting adenomas and in normal anterior adenohypophysis compared to non-secreting adenoma and neurohypophysis. AVP was mostly detected in normal neurohypophysis as anticipated. This work demonstrates that a fully automated droplet-based liquid microjunction surface sampling system coupled to HPLC-ESI-MS/MS can be readily used for spatially resolved sampling, separation, detection, and semi-quantitation of physiologically-relevant peptide and protein hormones, such as AVP and ACTH, directly from human tissue. In addition, the relative simplicity, rapidity and specificity of the current methodology support the potential of this basic technology with further advancement for assisting surgical decision-making.

  12. Profiling of adrenocorticotropic hormone and arginine vasopressin in human pituitary gland and tumor thin tissue sections using droplet-based liquid-microjunction surface-sampling-HPLC–ESI-MS–MS

    SciTech Connect (OSTI)

    Kertesz, Vilmos; Calligaris, David; Feldman, Daniel R.; Changelian, Armen; Laws, Edward R.; Santagata, Sandro; Agar, Nathalie Y. R.; Van Berkel, Gary J.

    2015-06-18

    Described here are the results from the profiling of the proteins arginine vasopressin (AVP) and adrenocorticotropic hormone (ACTH) from normal human pituitary gland and pituitary adenoma tissue sections using a fully automated droplet-based liquid microjunction surface sampling-HPLC-ESI-MS/MS system for spatially resolved sampling, HPLC separation, and mass spectral detection. Excellent correlation was found between the protein distribution data obtained with this droplet-based liquid microjunction surface sampling-HPLC-ESI-MS/MS system and those data obtained with matrix assisted laser desorption ionization (MALDI) chemical imaging analyses of serial sections of the same tissue. The protein distributions correlated with the visible anatomic pattern of the pituitary gland. AVP was most abundant in the posterior pituitary gland region (neurohypophysis) and ATCH was dominant in the anterior pituitary gland region (adenohypophysis). The relative amounts of AVP and ACTH sampled from a series of ACTH secreting and non-secreting pituitary adenomas correlated with histopathological evaluation. ACTH was readily detected at significantly higher levels in regions of ACTH secreting adenomas and in normal anterior adenohypophysis compared to non-secreting adenoma and neurohypophysis. AVP was mostly detected in normal neurohypophysis as anticipated. This work demonstrates that a fully automated droplet-based liquid microjunction surface sampling system coupled to HPLC-ESI-MS/MS can be readily used for spatially resolved sampling, separation, detection, and semi-quantitation of physiologically-relevant peptide and protein hormones, such as AVP and ACTH, directly from human tissue. In addition, the relative simplicity, rapidity and specificity of the current methodology support the potential of this basic technology with further advancement for assisting surgical decision-making.

  13. Profiling of adrenocorticotropic hormone and arginine vasopressin in human pituitary gland and tumor thin tissue sections using droplet-based liquid-microjunction surface-sampling-HPLC–ESI-MS–MS

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kertesz, Vilmos; Calligaris, David; Feldman, Daniel R.; Changelian, Armen; Laws, Edward R.; Santagata, Sandro; Agar, Nathalie Y. R.; Van Berkel, Gary J.

    2015-06-18

    Described here are the results from the profiling of the proteins arginine vasopressin (AVP) and adrenocorticotropic hormone (ACTH) from normal human pituitary gland and pituitary adenoma tissue sections using a fully automated droplet-based liquid microjunction surface sampling-HPLC-ESI-MS/MS system for spatially resolved sampling, HPLC separation, and mass spectral detection. Excellent correlation was found between the protein distribution data obtained with this droplet-based liquid microjunction surface sampling-HPLC-ESI-MS/MS system and those data obtained with matrix assisted laser desorption ionization (MALDI) chemical imaging analyses of serial sections of the same tissue. The protein distributions correlated with the visible anatomic pattern of the pituitary gland.more » AVP was most abundant in the posterior pituitary gland region (neurohypophysis) and ATCH was dominant in the anterior pituitary gland region (adenohypophysis). The relative amounts of AVP and ACTH sampled from a series of ACTH secreting and non-secreting pituitary adenomas correlated with histopathological evaluation. ACTH was readily detected at significantly higher levels in regions of ACTH secreting adenomas and in normal anterior adenohypophysis compared to non-secreting adenoma and neurohypophysis. AVP was mostly detected in normal neurohypophysis as anticipated. This work demonstrates that a fully automated droplet-based liquid microjunction surface sampling system coupled to HPLC-ESI-MS/MS can be readily used for spatially resolved sampling, separation, detection, and semi-quantitation of physiologically-relevant peptide and protein hormones, such as AVP and ACTH, directly from human tissue. In addition, the relative simplicity, rapidity and specificity of the current methodology support the potential of this basic technology with further advancement for assisting surgical decision-making.« less

  14. Numerical simulation of the environmental impact of hydraulic fracturing of tight/shale gas reservoirs on near-surface groundwater: Background, base cases, shallow reservoirs, short-term gas, and water transport

    SciTech Connect (OSTI)

    Reagan, Matthew T.; Moridis, George J.; Keen, Noel D.; Johnson, Jeffrey N.

    2015-04-18

    Hydrocarbon production from unconventional resources and the use of reservoir stimulation techniques, such as hydraulic fracturing, has grown explosively over the last decade. However, concerns have arisen that reservoir stimulation creates significant environmental threats through the creation of permeable pathways connecting the stimulated reservoir with shallower freshwater aquifers, thus resulting in the contamination of potable groundwater by escaping hydrocarbons or other reservoir fluids. This study investigates, by numerical simulation, gas and water transport between a shallow tight-gas reservoir and a shallower overlying freshwater aquifer following hydraulic fracturing operations, if such a connecting pathway has been created. We focus on two general failure scenarios: (1) communication between the reservoir and aquifer via a connecting fracture or fault and (2) communication via a deteriorated, preexisting nearby well. We conclude that the key factors driving short-term transport of gas include high permeability for the connecting pathway and the overall volume of the connecting feature. Production from the reservoir is likely to mitigate release through reduction of available free gas and lowering of reservoir pressure, and not producing may increase the potential for release. We also find that hydrostatic tight-gas reservoirs are unlikely to act as a continuing source of migrating gas, as gas contained within the newly formed hydraulic fracture is the primary source for potential contamination. Such incidents of gas escape are likely to be limited in duration and scope for hydrostatic reservoirs. Reliable field and laboratory data must be acquired to constrain the factors and determine the likelihood of these outcomes.

  15. Setup for in situ investigation of gases and gas/solid interfaces by soft x-ray emission and absorption spectroscopy

    SciTech Connect (OSTI)

    Benkert, A. E-mail: l.weinhardt@kit.edu; Blum, M.; Advanced Light Source, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 ; Meyer, F.; Wilks, R. G.; Yang, W.; Bär, M.; Solar Energy Research, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin; Insitut für Physik und Chemie, Brandenburgische Technische Universität Cottbus-Senftenberg, Konrad-Wachsmann-Allee 1, 03046 Cottbus ; and others

    2014-01-15

    We present a novel gas cell designed to study the electronic structure of gases and gas/solid interfaces using soft x-ray emission and absorption spectroscopies. In this cell, the sample gas is separated from the vacuum of the analysis chamber by a thin window membrane, allowing in situ measurements under atmospheric pressure. The temperature of the gas can be regulated from room temperature up to approximately 600 °C. To avoid beam damage, a constant mass flow can be maintained to continuously refresh the gaseous sample. Furthermore, the gas cell provides space for solid-state samples, allowing to study the gas/solid interface for surface catalytic reactions at elevated temperatures. To demonstrate the capabilities of the cell, we have investigated a TiO{sub 2} sample behind a mixture of N{sub 2} and He gas at atmospheric pressure.

  16. September 2004 Water Sampling

    Office of Legacy Management (LM)

    and September 2013 Groundwater and Surface Water Sampling at the Durango, Colorado, Disposal and Processing Sites March 2014 LMS/DUD/DUP/S00613 This page intentionally left blank U.S. Department of Energy DVP-June and September 2013, Durango, Colorado March 2014 RIN 13055370 and 13085577 Page i Contents Sampling Event Summary ...............................................................................................................1 Durango, Colorado, Disposal Site Sample Location Map-June

  17. Protections: Sampling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Protections: Sampling Protections: Sampling Protection #3: Sampling for known and unexpected contaminants August 1, 2013 Monitoring stormwater in Los Alamos Canyon Monitoring stormwater in Los Alamos Canyon The Environmental Sampling Board, a key piece of the Strategy, ensures that LANL collects relevant and appropriate data to answer questions about the protection of human and environmental health, and to satisfy regulatory requirements. LANL must demonstrate the data are technically justified

  18. Externally pressurized porous cylinder for multiple surface aerosol generation and method of generation

    DOE Patents [OSTI]

    Apel, C.T.; Layman, L.R.; Gallimore, D.L.

    1988-05-10

    A nebulizer is described for generating aerosol having small droplet sizes and high efficiency at low sample introduction rates. The nebulizer has a cylindrical gas permeable active surface. A sleeve is disposed around the cylinder and gas is provided from the sleeve to the interior of the cylinder formed by the active surface. In operation, a liquid is provided to the inside of the gas permeable surface. The gas contacts the wetted surface and forms small bubbles which burst to form an aerosol. Those bubbles which are large are carried by momentum to another part of the cylinder where they are renebulized. This process continues until the entire sample is nebulized into aerosol sized droplets. 2 figs.

  19. Numerical simulation of the environmental impact of hydraulic fracturing of tight/shale gas reservoirs on near-surface groundwater: Background, base cases, shallow reservoirs, short-term gas, and water transport

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Reagan, Matthew T.; Moridis, George J.; Keen, Noel D.; Johnson, Jeffrey N.

    2015-04-18

    Hydrocarbon production from unconventional resources and the use of reservoir stimulation techniques, such as hydraulic fracturing, has grown explosively over the last decade. However, concerns have arisen that reservoir stimulation creates significant environmental threats through the creation of permeable pathways connecting the stimulated reservoir with shallower freshwater aquifers, thus resulting in the contamination of potable groundwater by escaping hydrocarbons or other reservoir fluids. This study investigates, by numerical simulation, gas and water transport between a shallow tight-gas reservoir and a shallower overlying freshwater aquifer following hydraulic fracturing operations, if such a connecting pathway has been created. We focus on twomore » general failure scenarios: (1) communication between the reservoir and aquifer via a connecting fracture or fault and (2) communication via a deteriorated, preexisting nearby well. We conclude that the key factors driving short-term transport of gas include high permeability for the connecting pathway and the overall volume of the connecting feature. Production from the reservoir is likely to mitigate release through reduction of available free gas and lowering of reservoir pressure, and not producing may increase the potential for release. We also find that hydrostatic tight-gas reservoirs are unlikely to act as a continuing source of migrating gas, as gas contained within the newly formed hydraulic fracture is the primary source for potential contamination. Such incidents of gas escape are likely to be limited in duration and scope for hydrostatic reservoirs. Reliable field and laboratory data must be acquired to constrain the factors and determine the likelihood of these outcomes.« less

  20. WAFER TEST CAVITY -Linking Surface Microstructure to RF Performance: a ‘Short-­Sample Test Facility’ for characterizing superconducting materials for SRF cavities.

    SciTech Connect (OSTI)

    Pogue, Nathaniel; Comeaux, Justin; McIntyre, Peter

    2014-05-30

    The Wafer Test cavity was designed to create a short sample test system to determine the properties of the superconducting materials and S-I-S hetero-structures. The project, funded by ARRA, was successful in accomplishing several goals to achieving a high gradient test system for SRF research and development. The project led to the design and construction of the two unique cavities that each severed unique purposes: the Wafer test Cavity and the Sapphire Test cavity. The Sapphire Cavity was constructed first to determine the properties of large single crystal sapphires in an SRF environment. The data obtained from the cavity greatly altered the design of the Wafer Cavity and provided the necessary information to ascertain the Wafer Test cavity’s performance.

  1. Enhanced membrane gas separations

    SciTech Connect (OSTI)

    Prasad, R.

    1993-07-13

    An improved membrane gas separation process is described comprising: (a) passing a feed gas stream to the non-permeate side of a membrane system adapted for the passage of purge gas on the permeate side thereof, and for the passage of the feed gas stream in a counter current flow pattern relative to the flow of purge gas on the permeate side thereof, said membrane system being capable of selectively permeating a fast permeating component from said feed gas, at a feed gas pressure at or above atmospheric pressure; (b) passing purge gas to the permeate side of the membrane system in counter current flow to the flow of said feed gas stream in order to facilitate carrying away of said fast permeating component from the surface of the membrane and maintaining the driving force for removal of the fast permeating component through the membrane from the feed gas stream, said permeate side of the membrane being maintained at a subatmospheric pressure within the range of from about 0.1 to about 5 psia by vacuum pump means; (c) recovering a product gas stream from the non-permeate side of the membrane; and (d) discharging purge gas and the fast permeating component that has permeated the membrane from the permeate side of the membrane, whereby the vacuum conditions maintained on the permeate side of the membrane by said vacuum pump means enhance the efficiency of the gas separation operation, thereby reducing the overall energy requirements thereof.

  2. Sample introducing apparatus and sample modules for mass spectrometer

    DOE Patents [OSTI]

    Thompson, Cyril V.; Wise, Marcus B.

    1993-01-01

    An apparatus for introducing gaseous samples from a wide range of environmental matrices into a mass spectrometer for analysis of the samples is described. Several sample preparing modules including a real-time air monitoring module, a soil/liquid purge module, and a thermal desorption module are individually and rapidly attachable to the sample introducing apparatus for supplying gaseous samples to the mass spectrometer. The sample-introducing apparatus uses a capillary column for conveying the gaseous samples into the mass spectrometer and is provided with an open/split interface in communication with the capillary and a sample archiving port through which at least about 90 percent of the gaseous sample in a mixture with an inert gas that was introduced into the sample introducing apparatus is separated from a minor portion of the mixture entering the capillary discharged from the sample introducing apparatus.

  3. Sample introducing apparatus and sample modules for mass spectrometer

    DOE Patents [OSTI]

    Thompson, C.V.; Wise, M.B.

    1993-12-21

    An apparatus for introducing gaseous samples from a wide range of environmental matrices into a mass spectrometer for analysis of the samples is described. Several sample preparing modules including a real-time air monitoring module, a soil/liquid purge module, and a thermal desorption module are individually and rapidly attachable to the sample introducing apparatus for supplying gaseous samples to the mass spectrometer. The sample-introducing apparatus uses a capillary column for conveying the gaseous samples into the mass spectrometer and is provided with an open/split interface in communication with the capillary and a sample archiving port through which at least about 90 percent of the gaseous sample in a mixture with an inert gas that was introduced into the sample introducing apparatus is separated from a minor portion of the mixture entering the capillary discharged from the sample introducing apparatus. 5 figures.

  4. Protections: Sampling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Protection 3: Sampling for known and unexpected contaminants August 1, 2013 Monitoring stormwater in Los Alamos Canyon Monitoring stormwater in Los Alamos Canyon The Environmental ...

  5. Protections: Sampling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and unexpected contaminants August 1, 2013 Monitoring stormwater in Los Alamos Canyon Monitoring stormwater in Los Alamos Canyon The Environmental Sampling Board, a key piece...

  6. Fission gas detection system

    DOE Patents [OSTI]

    Colburn, Richard P. (Pasco, WA)

    1985-01-01

    A device for collecting fission gas released by a failed fuel rod which device uses a filter to pass coolant but which filter blocks fission gas bubbles which cannot pass through the filter due to the surface tension of the bubble.

  7. Sulfur gas emissions from stored flue gas desulfurization solids. Final report

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1981-10-01

    The emissions of volatile, sulfur-containing compounds from the surfaces of 13 flue gas desulfurization (FGD) solids field storage sites have been characterized. The sulfur gas emissions from these storage surfaces were determined by measuring the sulfur gas enhancement of sulfur-free sweep air passing through a dynamic emission flux chamber placed over selected sampling areas. Samples of the enclosure sweep air were cryogenically concentrated in surface-deactivated Pyrex U traps. Analyses were conducted by wall-coated, open-tubular, capillary column, cryogenic, temperature-programmed gas chromatography using a sulfur-selective flame photometric detector. Several major variables associated with FGD sludge production processes were examined in relation to the measured range and variations in sulfur fluxes including: the sulfur dioxide scrubbing reagent used, sludge sulfite oxidation, unfixed or stabilized (fixed) FGD solids, and ponding or landfill storage. The composition and concentration of the measured sulfur gas emissions were found to vary with the type of solids, the effectiveness of rainwater drainage from the landfill surface, the method of impoundment, and the sulfate/sulfite ratio of the solids. The FGD solids emissions may contain hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide in varying concentrations and ratios. In addition, up to four unidentified organo-sulfur compounds were found in the emissions from four different FGD solids. The measured, total sulfur emissions ranged from less than 0.01 to nearly 0.3 kg of sulfur per day for an equivalent 40.5 hectare (100 acre) FGD solids impoundment surface.

  8. Fluid Inclusion Gas Analysis

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Dilley, Lorie

    Fluid inclusion gas analysis for wells in various geothermal areas. Analyses used in developing fluid inclusion stratigraphy for wells and defining fluids across the geothermal fields. Each sample has mass spectrum counts for 180 chemical species.

  9. Fluid Inclusion Gas Analysis

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Dilley, Lorie

    2013-01-01

    Fluid inclusion gas analysis for wells in various geothermal areas. Analyses used in developing fluid inclusion stratigraphy for wells and defining fluids across the geothermal fields. Each sample has mass spectrum counts for 180 chemical species.

  10. Analysis of Tank 38H (HTF-38-15-119, 127) Surface, Subsurface and Tank 43H (HTF-43-15-116, 117 and 118) Surface, Feed Pump Suction and Jet Suction Subsurface Supernatant Samples in Support of Enrichment, Corrosion Control and Salt Batch Planning Programs

    SciTech Connect (OSTI)

    Oji, L.

    2015-12-17

    Compositional feed limits have been established to ensure that a nuclear criticality event for the 2H and 3H Evaporators is not possible. The Enrichment Control Program (ECP) requires feed sampling to determine the equivalent enriched uranium content prior to transfer of waste other than recycle transfers (requires sampling to determine the equivalent enriched uranium at two locations in Tanks 38H and 43H every 26 weeks) The Corrosion Control Program (CCP) establishes concentration and temperature limits for key constituents and periodic sampling and analysis to confirm that waste supernate is within these limits. This report provides the results of analyses on Tanks 38H and 43H surface and subsurface supernatant liquid samples in support of the ECP, the CCP, and the Salt Batch 10 Planning Program.

  11. SAMPLING SYSTEM

    DOE Patents [OSTI]

    Hannaford, B.A.; Rosenberg, R.; Segaser, C.L.; Terry, C.L.

    1961-01-17

    An apparatus is given for the batch sampling of radioactive liquids such as slurries from a system by remote control, while providing shielding for protection of operating personnel from the harmful effects of radiation.

  12. Sampling box

    DOE Patents [OSTI]

    Phillips, Terrance D.; Johnson, Craig

    2000-01-01

    An air sampling box that uses a slidable filter tray and a removable filter cartridge to allow for the easy replacement of a filter which catches radioactive particles is disclosed.

  13. Non-planar microfabricated gas chromatography column

    DOE Patents [OSTI]

    Lewis, Patrick R.; Wheeler, David R.

    2007-09-25

    A non-planar microfabricated gas chromatography column comprises a planar substrate having a plurality of through holes, a top lid and a bottom lid bonded to opposite surfaces of the planar substrate, and inlet and outlet ports for injection of a sample gas and elution of separated analytes. A plurality of such planar substrates can be aligned and stacked to provide a longer column length having a small footprint. Furthermore, two or more separate channels can enable multi-channel or multi-dimensional gas chromatography. The through holes preferably have a circular cross section and can be coated with a stationary phase material or packed with a porous packing material. Importantly, uniform stationary phase coatings can be obtained and band broadening can be minimized with the circular channels. A heating or cooling element can be disposed on at least one of the lids to enable temperature programming of the column.

  14. Gas-recovery system

    DOE Patents [OSTI]

    Heckman, R.A.

    1971-12-14

    Nuclear explosions have been proposed as a means for recovering gas from underground gas-bearing rock formations. In present practice, the nuclear device is positioned at the end of a long pipe which is subsequently filled with grout or concrete. After the device is exploded, the grout is drilled through to provide a flow path for the released gas to the ground surface. As settled grout is brittle, often the compressive shock of the explosion fractures the grout and deforms the pipe so that it may not be removed nor reused. In addition, the pipe is sometimes pinched off completely and the gas flow is totally obstructed. (2 claims)

  15. Gas-Recovery System

    DOE Patents [OSTI]

    Heckman, R. A.

    1971-12-14

    Nuclear explosions have been proposed as a means for recovering gas from underground gas-bearing rock formations. In present practice, the nuclear device is positioned at the end of a long pipe which is subsequently filled with grout or concrete. After the device is exploded, the grout is drilled through to provide a flow path for the released gas to the ground surface. As settled grout is brittle, often the compressive shock of the explosion fractures the grout and deforms the pipe so that it may not be removed nor reused. In addition, the pipe is sometimes pinched off completely and the gas flow is totally obstructed. (2 claims)

  16. Situ soil sampling probe system with heated transfer line

    DOE Patents [OSTI]

    Robbat, Jr., Albert

    2002-01-01

    The present invention is directed both to an improved in situ penetrometer probe and to a heated, flexible transfer line. The line and probe may be implemented together in a penetrometer system in which the transfer line is used to connect the probe to a collector/analyzer at the surface. The probe comprises a heater that controls a temperature of a geologic medium surrounding the probe. At least one carrier gas port and vapor collection port are located on an external side wall of the probe. The carrier gas port provides a carrier gas into the geologic medium, and the collection port captures vapors from the geologic medium for analysis. In the transfer line, a flexible collection line that conveys a collected fluid, i.e., vapor, sample to a collector/analyzer. A flexible carrier gas line conveys a carrier gas to facilitate the collection of the sample. A system heating the collection line is also provided. Preferably the collection line is electrically conductive so that an electrical power source can generate a current through it so that the internal resistance generates heat.

  17. Measuring Complementary Electronic Structure Properties of both Deposited and Gas Phase Clusters using STM, UPS, and PES: Size-Selected Clusters on Surfaces

    SciTech Connect (OSTI)

    Bowen, Kit H.

    2014-03-05

    In this project, we studied size-selected cluster interactions with surfaces, with other clusters on surfaces, and with external stimuli. These studies focused on mobility as a function of cluster size, surface morphologies as a function of composition and coverage, ion-induced modification and reactivity of clusters as a function of composition, the structural evolution of cluster cuboids culminating in the characterization of theoretically-predicted baby crystal clusters, and unusual fractal pattern formation due to deposition.

  18. Geologic interrelations relative to gas hydrates within the North Slope of Alaska: Task No. 6, Final report

    SciTech Connect (OSTI)

    Collett, T.S.; Bird, K.J.; Kvenvolden, K.A.; Magoon, L.B.

    1988-01-01

    The five primary objectives of the US Geological Survey North Slope Gas Hydrate Project were to: (1) Determine possible geologic controls on the occurrence of gas hydrate; (2) locate and evaluate possible gas-hydrate-bearing reservoirs; (3) estimate the volume of gas within the hydrates; (4) develop a model for gas-hydrate formation; and (5) select a coring site for gas-hydrate sampling and analysis. Our studies of the North Slope of Alaska suggest that the zone in which gas hydrates are stable is controlled primarily by subsurface temperatures and gas chemistry. Other factors, such as pore-pressure variations, pore-fluid salinity, and reservior-rock grain size, appear to have little effect on gas hydrate stability on the North Slope. Data necessary to determine the limits of gas hydrate stability field are difficult to obtain. On the basis of mud-log gas chromatography, core data, and cuttings data, methane is the dominant species of gas in the near-surface (0--1500 m) sediment. Gas hydrates were identified in 34 wells utilizing well-log responses calibrated to the response of an interval in one well where gas hydrates were actually recovered in a core by an oil company. A possible scenario describing the origin of the interred gas hydrates on the North Slope involves the migration of thermogenic solution- and free-gas from deeper reservoirs upward along faults into the overlying sedimentary rocks. We have identified two (dedicated) core-hole sites, the Eileen and the South-End core-holes, at which there is a high probability of recovering a sample of gas hydrate. At the Eileen core-hole site, at least three stratigraphic units may contain gas hydrate. The South-End core-hole site provides an opportunity to study one specific rock unit that appears to contain both gas hydrate and oil. 100 refs., 72 figs., 24 tabs.

  19. THE 0.8-14.5 {mu}m SPECTRA OF MID-L TO MID-T DWARFS: DIAGNOSTICS OF EFFECTIVE TEMPERATURE, GRAIN SEDIMENTATION, GAS TRANSPORT, AND SURFACE GRAVITY

    SciTech Connect (OSTI)

    Stephens, D. C.; Leggett, S. K.; Geballe, T. R.; Cushing, Michael C.; Marley, Mark S.; Saumon, D.; Golimowski, David A.; Noll, K. S.; Fan Xiaohui

    2009-09-01

    We present new 5.2-14.5 {mu}m low-resolution spectra of 14 mid-L to mid-T dwarfs. We also present new 3.0-4.1 {mu}m spectra for five of these dwarfs. These data are supplemented by existing red and near-infrared spectra ({approx}0.6-2.5 {mu}m), as well as red through mid-infrared spectroscopy of seven other L and T dwarfs presented by Cushing et al. We compare these spectra to those generated from the model atmospheres of Saumon and Marley. The models reproduce the observed spectra well, except in the case of one very red L3.5 dwarf, 2MASS J22244381-0158521. The broad wavelength coverage allows us to constrain almost independently the four parameters used to describe these photospheres in our models: effective temperature (T {sub eff}), surface gravity, grain sedimentation efficiency (f{sub sed}), and vertical gas transport efficiency (K{sub zz} ). The CH{sub 4} bands centered at 2.2, 3.3, and 7.65 {mu}m and the CO band at 2.3 {mu}m are sensitive to K{sub zz} , and indicates that chemical mixing is important in all L and T dwarf atmospheres. The sample of L3.5 to T5.5 dwarfs spans the range 1800 K{approx}> T{sub eff} {approx}>1000 K, with an L-T transition (spectral types L7 to T4) that lies between 1400 and 1100 K for dwarfs with typical near-infrared colors; bluer and redder dwarfs can be 100 K warmer or cooler, respectively, when using infrared spectral types. When using optical spectral types, the bluer dwarfs have more typical T {sub eff} values as they tend to have earlier optical spectral types. In this model analysis, f {sub sed} increases rapidly between types T0 and T4, indicating that increased sedimentation can explain the rapid disappearance of clouds at this stage of brown dwarf evolution. There is a suggestion that the transition to dust-free atmospheres happens at lower temperatures for lower gravity dwarfs.

  20. SAMPLING OSCILLOSCOPE

    DOE Patents [OSTI]

    Sugarman, R.M.

    1960-08-30

    An oscilloscope is designed for displaying transient signal waveforms having random time and amplitude distributions. The oscilloscopc is a sampling device that selects for display a portion of only those waveforms having a particular range of amplitudes. For this purpose a pulse-height analyzer is provided to screen the pulses. A variable voltage-level shifter and a time-scale rampvoltage generator take the pulse height relative to the start of the waveform. The variable voltage shifter produces a voltage level raised one step for each sequential signal waveform to be sampled and this results in an unsmeared record of input signal waveforms. Appropriate delay devices permit each sample waveform to pass its peak amplitude before the circuit selects it for display.

  1. Viscous sludge sample collector

    DOE Patents [OSTI]

    Beitel, George A [Richland, WA

    1983-01-01

    A vertical core sample collection system for viscous sludge. A sample tube's upper end has a flange and is attached to a piston. The tube and piston are located in the upper end of a bore in a housing. The bore's lower end leads outside the housing and has an inwardly extending rim. Compressed gas, from a storage cylinder, is quickly introduced into the bore's upper end to rapidly accelerate the piston and tube down the bore. The lower end of the tube has a high sludge entering velocity to obtain a full-length sludge sample without disturbing strata detail. The tube's downward motion is stopped when its upper end flange impacts against the bore's lower end inwardly extending rim.

  2. Flue gas desulfurization

    DOE Patents [OSTI]

    Im, K.H.; Ahluwalia, R.K.

    1984-05-01

    The invention involves a combustion process in which combustion gas containing sulfur oxide is directed past a series of heat exchangers to a stack and in which a sodium compound is added to the combustion gas in a temparature zone of above about 1400 K to form Na/sub 2/SO/sub 4/. Preferably, the temperature is above about 1800 K and the sodium compound is present as a vapor to provide a gas-gas reaction to form Na/sub 2/SO/sub 4/ as a liquid. Since liquid Na/sub 2/SO/sub 4/ may cause fouling of heat exchanger surfaces downstream from the combustion zone, the process advantageously includes the step of injecting a cooling gas downstream of the injection of the sodium compound yet upstream of one or more heat exchangers to cool the combustion gas to below about 1150 K and form solid Na/sub 2/SO/sub 4/. The cooling gas is preferably a portion of the combustion gas downstream which may be recycled for cooling. It is further advantageous to utilize an electrostatic precipitator downstream of the heat exchangers to recover the Na/sub 2/SO/sub 4/. It is also advantageous in the process to remove a portion of the combustion gas cleaned in the electrostatic precipitator and recycle that portion upstream to use as the cooling gas. 3 figures.

  3. Sulfur gas emissions from stored flue-gas-desulfurization sludges

    SciTech Connect (OSTI)

    Adams, D.F.; Farwell, S.O.

    1980-01-01

    In field studies conducted for the Electric Power Research Institute by the University of Washington (1978) and the University of Idaho (1979), 13 gas samples from sludge storage sites at coal-burning power plants were analyzed by wall-coated open-tube cryogenic capillary-column gas chromatography with a sulfur-selective flame-photometric detector. Hydrogen sulfide, carbonyl sulfide, dimethyl sulfide, carbon disulfide, and dimethyl disulfide were identified in varying concentrations and ratios in the emissions from both operating sludge ponds and landfills and from FGD sludge surfaces that had been stored in the open for 3-32 mo or longer. Other sulfur compounds, probably propanethiols, were found in emissions from some sludges. Chemical ''stabilization/fixation'' sulfate-sulfite ratio, sludge water content, and temperature were the most significant variables controlling sulfur gas production. The average sulfur emissions from each of the 13 FGD storage sites ranged from 0.01 to 0.26 g/sq m/yr sulfur.

  4. The retention of iodine in stainless steel sample lines

    SciTech Connect (OSTI)

    Evans, G.J.; Deir, C.; Ball, J.M.

    1995-02-01

    Following an accident in a multi-unit CANDU nuclear generating station, decontamination of air vented from containment would play a critical role in minimizing the release of iodine to the environment. The concentration of gas phase iodine in containment air would be measured using the post accident radiation monitoring system, requiring that air samples be passed through a considerable length of tubing to a remote location where the desired measurements could safely be made. A significant loss of iodine, due to adsorption on the sample line surfaces, could greatly distort the measurement. In this study, the retention of I{sub 2}(g) on stainless steel was evaluated in bench scale experiments in order to evaluate, and if possible minimise, the extent of any such line losses. Experiments at the University of Toronto were performed using 6 inch lengths of 1/4 inch stainless steel tubing. Air, containing I-131 labelled I{sub 2}(g), ranging in concentration from 10{sup {minus}10} to 10{sup {minus}6} mol/dm{sup 3} and relative humidity (:RH) from 20 to 90 %, was passed through tubing samples maintained at temperatures ranging from 25 to 90{degrees}C. Adsorption at low gas phase iodine concentrations differed substantially from that at higher concentrations. The rate of deposition was proportional to the gas phase concentration, giving support to the concept of a first order deposition velocity. The surface loading increased with increasing relative humidity, particularly at low RH values, while the deposition rate decreased with increasing temperature. Surface water on the steel may play an important role in the deposition process. The chemisorbed iodine was located primarily in areas of corrosion. Furthermore, water used to wash the steel contained Fe, Mn and iodine in the form of iodide, suggesting that I{sub 2} reacted to form metal iodides. The deposition of I{sub 2} was also found to depend on the initial surface condition.

  5. Gas Hydrate Storage of Natural Gas

    SciTech Connect (OSTI)

    Rudy Rogers; John Etheridge

    2006-03-31

    Environmental and economic benefits could accrue from a safe, above-ground, natural-gas storage process allowing electric power plants to utilize natural gas for peak load demands; numerous other applications of a gas storage process exist. A laboratory study conducted in 1999 to determine the feasibility of a gas-hydrates storage process looked promising. The subsequent scale-up of the process was designed to preserve important features of the laboratory apparatus: (1) symmetry of hydrate accumulation, (2) favorable surface area to volume ratio, (3) heat exchanger surfaces serving as hydrate adsorption surfaces, (4) refrigeration system to remove heat liberated from bulk hydrate formation, (5) rapid hydrate formation in a non-stirred system, (6) hydrate self-packing, and (7) heat-exchanger/adsorption plates serving dual purposes to add or extract energy for hydrate formation or decomposition. The hydrate formation/storage/decomposition Proof-of-Concept (POC) pressure vessel and supporting equipment were designed, constructed, and tested. This final report details the design of the scaled POC gas-hydrate storage process, some comments on its fabrication and installation, checkout of the equipment, procedures for conducting the experimental tests, and the test results. The design, construction, and installation of the equipment were on budget target, as was the tests that were subsequently conducted. The budget proposed was met. The primary goal of storing 5000-scf of natural gas in the gas hydrates was exceeded in the final test, as 5289-scf of gas storage was achieved in 54.33 hours. After this 54.33-hour period, as pressure in the formation vessel declined, additional gas went into the hydrates until equilibrium pressure/temperature was reached, so that ultimately more than the 5289-scf storage was achieved. The time required to store the 5000-scf (48.1 hours of operating time) was longer than designed. The lower gas hydrate formation rate is attributed to a

  6. Apparatus for gas sorption measurement with integrated gas composition measurement device and gas mixing

    DOE Patents [OSTI]

    Micklash. II, Kenneth James; Dutton, Justin James; Kaye, Steven

    2014-06-03

    An apparatus for testing of multiple material samples includes a gas delivery control system operatively connectable to the multiple material samples and configured to provide gas to the multiple material samples. Both a gas composition measurement device and pressure measurement devices are included in the apparatus. The apparatus includes multiple selectively openable and closable valves and a series of conduits configured to selectively connect the multiple material samples individually to the gas composition device and the pressure measurement devices by operation of the valves. A mixing system is selectively connectable to the series of conduits and is operable to cause forced mixing of the gas within the series of conduits to achieve a predetermined uniformity of gas composition within the series of conduits and passages.

  7. Fuel leak detection apparatus for gas cooled nuclear reactors

    DOE Patents [OSTI]

    Burnette, Richard D.

    1977-01-01

    Apparatus is disclosed for detecting nuclear fuel leaks within nuclear power system reactors, such as high temperature gas cooled reactors. The apparatus includes a probe assembly that is inserted into the high temperature reactor coolant gaseous stream. The probe has an aperture adapted to communicate gaseous fluid between its inside and outside surfaces and also contains an inner tube for sampling gaseous fluid present near the aperture. A high pressure supply of noncontaminated gas is provided to selectively balance the pressure of the stream being sampled to prevent gas from entering the probe through the aperture. The apparatus includes valves that are operable to cause various directional flows and pressures, which valves are located outside of the reactor walls to permit maintenance work and the like to be performed without shutting down the reactor.

  8. Stack sampling apparatus

    DOE Patents [OSTI]

    Lind, Randall F; Lloyd, Peter D; Love, Lonnie J; Noakes, Mark W; Pin, Francois G; Richardson, Bradley S; Rowe, John C

    2014-09-16

    An apparatus for obtaining samples from a structure includes a support member, at least one stabilizing member, and at least one moveable member. The stabilizing member has a first portion coupled to the support member and a second portion configured to engage with the structure to restrict relative movement between the support member and the structure. The stabilizing member is radially expandable from a first configuration where the second portion does not engage with a surface of the structure to a second configuration where the second portion engages with the surface of the structure.

  9. Raman spectroscopy of solutions and interfaces containing nitrogen dioxide, water, and 1,4 dioxane: Evidence for repulsion of surface water by NO{sub 2} gas

    SciTech Connect (OSTI)

    Murdachaew, Garold; Varner, Mychel E.; Veer, Wytze E. van der; Gerber, R. Benny; Phillips, Leon F.

    2014-05-14

    The interaction of water, 1,4 dioxane, and gaseous nitrogen dioxide, has been studied as a function of distance measured through the liquid-vapour interface by Raman spectroscopy with a narrow (<0.1 mm) laser beam directed parallel to the interface. The Raman spectra show that water is present at the surface of a dioxane-water mixture when gaseous NO{sub 2} is absent, but is virtually absent from the surface of a dioxane-water mixture when gaseous NO{sub 2} is present. This is consistent with recent theoretical calculations that show NO{sub 2} to be mildly hydrophobic.

  10. Gas venting

    DOE Patents [OSTI]

    Johnson, Edwin F.

    1976-01-01

    Improved gas venting from radioactive-material containers which utilizes the passageways between interbonded impervious laminae.

  11. Monitoring Results Natural Gas Wells Near Project Rulison

    Office of Legacy Management (LM)

    Natural Gas Wells Near Project Rulison Third Quarter 2013 U.S. Department of Energy Office of Legacy Management Grand Junction, Colorado Date Sampled: June 12, 2013 Background: Project Rulison was the second Plowshare Program test to stimulate natural-gas recovery from deep and low permeability formations. On September 10, 1969, a 40-kiloton-yield nuclear device was detonated 8,426 feet (1.6 miles) below the ground surface in the Williams Fork Formation at what is now the Rulison, Colorado,

  12. Gas Phase Chemical Detection with an Integrated Chemical Analysis System

    SciTech Connect (OSTI)

    Baca, Albert G.; Casalnuovo, Stephen A.; Frye-Mason, Gregory C.; Heller, Edwin J.; Hietala, Susan L.; Hietala, Vincent M.; Kottenstette, Richard J.; Lewis, Patrick R.; Manginell, Ronald P.; Matzke, Carloyn M.; Reno, John L.; Sasaki, Darryl Y.; Schubert, W. Kent

    1999-07-08

    Microfabrication technology has been applied to the development of a miniature, multi-channel gas phase chemical laboratory that provides fast response, small size, and enhanced versatility and chemical discrimination. Each analysis channel includes a sample concentrator followed by a gas chromatographic separator and a chemically selective surface acoustic wave detector array to achieve high sensitivity and selectivity. The performance of the components, individually and collectively, is described. The design and performance of novel micromachined acoustic wave devices, with the potential for improved chemical sensitivity, are also described.

  13. Natural Gas Weekly Update, Printer-Friendly Version

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Weekly Underground Natural Gas Storage Report. The sample change occurred over a transition period that began with the release of the Weekly Natural Gas Storage Report (WNGSR)...

  14. Noble Gas Geochemistry In Thermal Springs | Open Energy Information

    Open Energy Info (EERE)

    Noble Gas Geochemistry In Thermal Springs Abstract The composition of noble gases in both gas and water samples collected from Horseshoe Spring, Yellowstone National Park, was...

  15. HIGH PRESSURE GAS REGULATOR

    DOE Patents [OSTI]

    Ramage, R.W.

    1962-05-01

    A gas regulator operating on the piston and feedback principle is described. The device is particularly suitable for the delicate regulation of high pressure, i.e., 10,000 psi and above, gas sources, as well as being perfectly adaptable for use on gas supplies as low as 50 psi. The piston is adjustably connected to a needle valve and the movement of the piston regulates the flow of gas from the needle valve. The gas output is obtained from the needle valve. Output pressure is sampled by a piston feedback means which, in turn, regulates the movement of the main piston. When the output is other than the desired value, the feedback system initiates movement of the main piston to allow the output pressure to be corrected or to remain constant. (AEC)

  16. Pulse studies to decipher the role of surface morphology in CuO/CeO₂ nanocatalysts for the water gas shift reaction

    SciTech Connect (OSTI)

    Rodriguez, Jose A.; Zhao, Fuzhen; Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Si, Rui; Johnston-Peck, Aaron C.; Martinez-Arias, Arturo; Hanson, Jonathan C.; Senanayake, Sanjaya D.

    2015-01-23

    The water-gas shift reaction (WGS, CO + H₂O → CO₂) was studied over CuO/CeO₂ catalysts with two different ceria particle morphohologies, in the form of nanospheres (ns) and nanocubes (nc). To understand the strong dependence of the WGS reaction activity on the ceria nanoshapes, pulses of CO (without and with water vapor) were employed during in situ X-ray diffraction (XRD) and X-ray absoprtion near edge structure (XANES) measurements done to characterize the catalysts. The results showed that CuO/CeO₂ (ns) exhibited a substantially better activity than CuO/CeO₂ (nc). The higher activity was associated with the unique properties of CuO/CeO₂ (ns), such as the easier reduction of highly dispersed CuO to metallic Cu, the stability of metallic Cu and a larger concentration Ce³⁺ in CeO₂ (ns).

  17. Pulse studies to decipher the role of surface morphology in CuO/CeO₂ nanocatalysts for the water gas shift reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A.; Zhao, Fuzhen; Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Si, Rui; Johnston-Peck, Aaron C.; Martinez-Arias, Arturo; Hanson, Jonathan C.; Senanayake, Sanjaya D.

    2015-01-23

    The water-gas shift reaction (WGS, CO + H₂O → CO₂) was studied over CuO/CeO₂ catalysts with two different ceria particle morphohologies, in the form of nanospheres (ns) and nanocubes (nc). To understand the strong dependence of the WGS reaction activity on the ceria nanoshapes, pulses of CO (without and with water vapor) were employed during in situ X-ray diffraction (XRD) and X-ray absoprtion near edge structure (XANES) measurements done to characterize the catalysts. The results showed that CuO/CeO₂ (ns) exhibited a substantially better activity than CuO/CeO₂ (nc). The higher activity was associated with the unique properties of CuO/CeO₂ (ns), suchmore » as the easier reduction of highly dispersed CuO to metallic Cu, the stability of metallic Cu and a larger concentration Ce³⁺ in CeO₂ (ns).« less

  18. GAS ANALYSES FROM HEADSPACE OF PLUTONIUM-BEARING MATERIALS CONTAINERS

    SciTech Connect (OSTI)

    Almond, P.; Livingston, R.; Traver, L.; Arnold, M.; Bridges, N.; Kessinger, G.; Duffey, J.

    2010-02-01

    The Savannah River National Laboratory (SRNL) 3013 destructive examination program performs surveillances on 3013 containers originating from multiple sites across the DOE complex. The bases for the packaging, storage, and surveillance activities are derived from the Department of Energy's 3013 Standard (DOE-STD-3013-2004). During destructive examination, headspace gas samples are obtained from the 3013 inner container and the annulus between the outer and inner containers. To characterize gas species, the samples are analyzed by gas chromatography (GC), direct-inlet mass spectrometry (DIMS), and Fourier-transform infrared spectroscopy (FTIR). The GC results, as well as other parameters, are utilized as input into the gas evaluation software tool (GEST) program for computation of pre-puncture gas compositions and pressures. Over 30 containers from the Hanford Site and the Rocky Flats Environmental Technology Site (RFETS) have been examined in the first three years of the surveillance program. Several containers were shown to have appreciable hydrogen content (some greater than 30 mol %), yet little or no oxygen was detected in any of the containers, including those exhibiting high hydrogen concentrations. Characteristics including moisture content, surface area, and material composition, along with the headspace gas composition, are utilized in an attempt to explain the chemical behavior of the packaged materials.

  19. Field-deployable, nano-sensing approach for real-time detection of free mercury, speciation and quantification in surface stream waters and groundwater samples at the U.S. Department of Energy contaminated sites

    SciTech Connect (OSTI)

    Campiglia, Andres D.; Hernandez, Florencio E.

    2014-08-28

    The detrimental effects on human health caused by long-term exposure to trace contamination of toxic metals have been documented in numerous epidemiological and toxicological studies. The fact that metals are non-biodegradable and accumulate in the food chain poses a severe threat to the environment and human health. Their monitoring in drinking water, aquatic ecosystems, food and biological fluids samples is then essential for global sustainability. While research efforts employing established methodology continue to advance conceptual/computational models of contaminant behavior, the increasing awareness and public concern with environmental and occupational exposure to toxic metals calls for sensing devices capable to handle on-site elemental analysis in short analysis time. Field analysis with potable methodology prevents unnecessary scrutiny of un-contaminated samples via laboratory-bound methods, reduces analysis cost and expedites turnaround time for decision making and remediation purposes. Of particular toxicological interest are mercury and its species. Mercury is recognized as a major environmental pollution issue. The field-portable sensor developed in this project provides a unique and valuable tool for the on-site, real-time determination of inorganic mercury in surface waters. The ability to perform on-site analysis of mercury should prove useful in remote locations with difficult accessibility. It should facilitate data collection from statistically meaningful population sizes for a better understanding of the dose-effect role and the water-soil-plant-animal-human transfer mechanisms. The acquired knowledge should benefit the development of efficient environmental remediation processes, which is extremely relevant for a globally sustainable environment.

  20. Weapons assessment efficiencies through use of nondestructive laser gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sampling Weapons assessment efficiencies through use of nondestructive laser gas sampling Weapons assessment efficiencies through use of nondestructive laser gas sampling Nondestructive laser welding process far less expensive, no underground testing. June 8, 2012 Nondestructive Laser Gas Sampling Nondestructive Laser Gas Sampling is expected to save several million dollars per year and requires no underground testing. "We're continually innovating and working to improve the way we do

  1. Fundamentals of gas measurement II

    SciTech Connect (OSTI)

    Smith, J.P.

    1995-12-01

    A knowledge of the Fundamentals of Gas Measurement is essential for all technicians and engineers that are called upon to perform gas volume calculations. These same people must have at least a working knowledge of the fundamentals to perform their everyday jobs including equipment calibrations, specific gravity tests, collecting gas samples, etc. To understand the fundamentals, one must be familiar with the definitions of the terms that are used in day-to- day gas measurement operations. They also must know how to convert some values from one quantity as measured to another quantity that is called for in the gas purchase or sales contracts or transportation agreements.

  2. Materials Characterization Capabilities at the HTML: Surface...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HTML: SurfaceSub-surface dislocation density analysis of forming samples using advanced characterization techniques Materials Characterization Capabilities at the HTML: Surface...

  3. Visual Sample Plan

    Energy Science and Technology Software Center (OSTI)

    2007-10-25

    VSP selects the appropriate number and location of environmental samples to ensure that the results of statistical tests performed to provide input to risk decisions have the required confidence and performance. VSP Version 5.0 provides sample-size equations or algorithms needed by specific statistical tests appropriate for specific environmental sampling objectives. It also provides data quality assessment and statistical analysis functions to support evaluation of the data and determine whether the data support decisions regarding sitesmore » suspected of contamination. The easy-to-use program is highly visual and graphic. VSP runs on personal computers with Microsoft Windows operating systems (98, NT, 2000, Millennium Edition, CE, and XP) Designed primarily for project managers and users without expertise in statistics, VSP is applicable to two- and three-dimensional populations to be sampled (e.g., rooms and buildings, surface soil, a defined layer of subsurface soil, water bodies, and other similar applications) for studies of environmental quality. VSP is also applicable for designing sampling plans for assessing chem./rad/bio threat and hazard identification within rooms and buildings, and for designing geophysical surveys for UXO identification.« less

  4. Handling and characterization of glow-discharge polymer samples...

    Office of Scientific and Technical Information (OSTI)

    for the light gas gun Citation Details In-Document Search Title: Handling and characterization of glow-discharge polymer samples for the light gas gun Authors: Akin, M C ; ...

  5. Water-Stable Zirconium-Based Metal-Organic Framework Material with High-Surface Area and Gas-Storage Capacities

    SciTech Connect (OSTI)

    Gutov, OV; Bury, W; Gomez-Gualdron, DA; Krungleviciute, V; Fairen-Jimenez, D; Mondloch, JE; Sarjeant, AA; Al-Juaid, SS; Snurr, RQ; Hupp, JT; Yildirim, T; Farha, OK

    2014-08-14

    We designed, synthesized, and characterized a new Zr-based metal-organic framework material, NU-1100, with a pore volume of 1.53 ccg(-1) and Brunauer-Emmett-Teller (BET) surface area of 4020 m(2)g(-1); to our knowledge, currently the highest published for Zr-based MOFs. CH4/CO2/H-2 adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65 bar and 77 K is 0.092 gg(-1), which corresponds to 43 gL(-1). The volumetric and gravimetric methane-storage capacities at 65 bar and 298 K are approximately 180 v(STP)/v and 0.27 gg(-1), respectively.

  6. Gas Shale Plays? The Global Transition

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    wells, and install the extensive surface infrastructure needed to transport product to market. Industry is cautious regarding China's likely pace of shale gas development. Even...

  7. Virginia Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) Virginia Natural Gas Number of Gas and Gas Condensate Wells (Number of Elements) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 ...

  8. Pulsed field sample neutralization

    DOE Patents [OSTI]

    Appelhans, Anthony D.; Dahl, David A.; Delmore, James E.

    1990-01-01

    An apparatus and method for alternating voltage and for varying the rate of extraction during the extraction of secondary particles, resulting in periods when either positive ions, or negative ions and electrons are extracted at varying rates. Using voltage with alternating charge during successive periods to extract particles from materials which accumulate charge opposite that being extracted causes accumulation of surface charge of opposite sign. Charge accumulation can then be adjusted to a ratio which maintains a balance of positive and negative charge emission, thus maintaining the charge neutrality of the sample.

  9. Gas magnetometer

    DOE Patents [OSTI]

    Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

    2016-05-03

    Measurement of a precessional rate of a gas, such as an alkali gas, in a magnetic field is made by promoting a non-uniform precession of the gas in which substantially no net magnetic field affects the gas during a majority of the precession cycle. This allows sensitive gases that would be subject to spin-exchange collision de-phasing to be effectively used for extremely sensitive measurements in the presence of an environmental magnetic field such as the Earth's magnetic field.

  10. Natural Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, ... Grid Integration & Advanced Inverters Materials & Fabrication Microsystems Enabled ...

  11. Radon exhalation rates from some soil samples of Kharar, Punjab

    SciTech Connect (OSTI)

    Mehta, Vimal; Singh, Tejinder Pal; Chauhan, R. P.; Mudahar, G. S.

    2015-08-28

    Radon and its progeny are major contributors in the radiation dose received by general population of the world. Because radon is a noble gas, a large portion of it is free to migrate away from radium. The primary sources of radon in the houses are soils and rocks source emanations, emanation from building materials, and entry of radon into a structure from outdoor air. Keeping this in mind the study of radon exhalation rate from some soil samples of the Kharar, Punjab has been carried out using Can Technique. The equilibrium radon concentration in various soil samples of Kharar area of district Mohali varied from 12.7 Bqm{sup −3} to 82.9 Bqm{sup −3} with an average of 37.5 ± 27.0 Bqm{sup −3}. The radon mass exhalation rates from the soil samples varied from 0.45 to 2.9 mBq/kg/h with an average of 1.4 ± 0.9 mBq/kg/h and radon surface exhalation rates varied from 10.4 to 67.2 mBq/m{sup 2}/h with an average of 30.6 ± 21.8 mBq/m{sup 2}/h. The radon mass and surface exhalation rates of the soil samples of Kharar, Punjab were lower than that of the world wide average.

  12. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Salmon, Mississippi, Site, Water Sampling Location Map .........5 Water Sampling Field Activities Verification ...

  13. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........1 Water Sampling Locations at the Rulison, .........3 Water Sampling Field Activities Verification ...

  14. Determination of landfill gas composition and pollutant emission rates at fresh kills landfill. Volume 1. Project report. Final report

    SciTech Connect (OSTI)

    1995-12-07

    Air emissions of landfill gas pollutants at Fresh Kills Landfill, located in Staten Island, NY, were estimated based on three weeks of sampling of flow, concentration, and flux at passive vents, gas extraction wells, gas collection plant headers, and the landfill surface conducted by Radian Corporation in 1995. Emission rates were estimated for 202 pollutants, including hydrogen sulfide, mercury vapor, speciated volatile organic compounds, methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane recovery plant. Emission factors based on the results are presented.

  15. Systems and methods for sample analysis

    DOE Patents [OSTI]

    Cooks, Robert Graham; Li, Guangtao; Li, Xin; Ouyang, Zheng

    2015-01-13

    The invention generally relates to systems and methods for sample analysis. In certain embodiments, the invention provides a system for analyzing a sample that includes a probe including a material connected to a high voltage source, a device for generating a heated gas, and a mass analyzer.

  16. Systems and methods for sample analysis

    SciTech Connect (OSTI)

    Cooks, Robert Graham; Li, Guangtao; Li, Xin; Ouyang, Zheng

    2015-10-20

    The invention generally relates to systems and methods for sample analysis. In certain embodiments, the invention provides a system for analyzing a sample that includes a probe including a material connected to a high voltage source, a device for generating a heated gas, and a mass analyzer.

  17. Depth-discrete sampling port

    DOE Patents [OSTI]

    Pemberton, Bradley E.; May, Christopher P.; Rossabi, Joseph; Riha, Brian D.; Nichols, Ralph L.

    1999-01-01

    A sampling port is provided which has threaded ends for incorporating the port into a length of subsurface pipe. The port defines an internal receptacle which is in communication with subsurface fluids through a series of fine filtering slits. The receptacle is in further communication through a bore with a fitting carrying a length of tubing there which samples are transported to the surface. Each port further defines an additional bore through which tubing, cables, or similar components of adjacent ports may pass.

  18. Depth-discrete sampling port

    DOE Patents [OSTI]

    Pemberton, Bradley E.; May, Christopher P.; Rossabi, Joseph; Riha, Brian D.; Nichols, Ralph L.

    1998-07-07

    A sampling port is provided which has threaded ends for incorporating the port into a length of subsurface pipe. The port defines an internal receptacle which is in communication with subsurface fluids through a series of fine filtering slits. The receptacle is in further communication through a bore with a fitting carrying a length of tubing there which samples are transported to the surface. Each port further defines an additional bore through which tubing, cables, or similar components of adjacent ports may pass.

  19. Background canceling surface alpha detector

    DOE Patents [OSTI]

    MacArthur, D.W.; Allander, K.S.; Bounds, J.A.

    1996-06-11

    A background canceling long range alpha detector which is capable of providing output proportional to both the alpha radiation emitted from a surface and to radioactive gas emanating from the surface. The detector operates by using an electrical field between first and second signal planes, an enclosure and the surface or substance to be monitored for alpha radiation. The first and second signal planes are maintained at the same voltage with respect to the electrically conductive enclosure, reducing leakage currents. In the presence of alpha radiation and radioactive gas decay, the signal from the first signal plane is proportional to both the surface alpha radiation and to the airborne radioactive gas, while the signal from the second signal plane is proportional only to the airborne radioactive gas. The difference between these two signals is proportional to the surface alpha radiation alone. 5 figs.

  20. Background canceling surface alpha detector

    DOE Patents [OSTI]

    MacArthur, Duncan W.; Allander, Krag S.; Bounds, John A.

    1996-01-01

    A background canceling long range alpha detector which is capable of providing output proportional to both the alpha radiation emitted from a surface and to radioactive gas emanating from the surface. The detector operates by using an electrical field between first and second signal planes, an enclosure and the surface or substance to be monitored for alpha radiation. The first and second signal planes are maintained at the same voltage with respect to the electrically conductive enclosure, reducing leakage currents. In the presence of alpha radiation and radioactive gas decay, the signal from the first signal plane is proportional to both the surface alpha radiation and to the airborne radioactive gas, while the signal from the second signal plane is proportional only to the airborne radioactive gas. The difference between these two signals is proportional to the surface alpha radiation alone.

  1. Handling and characterization of glow-discharge polymer samples...

    Office of Scientific and Technical Information (OSTI)

    of glow-discharge polymer samples for the light gas gun Citation Details In-Document Search Title: Handling and characterization of glow-discharge polymer samples for the light ...

  2. Explosives screening on a vehicle surface

    DOE Patents [OSTI]

    Parmeter, John E.; Brusseau, Charles A.; Davis, Jerry D.; Linker, Kevin L.; Hannum, David W.

    2005-02-01

    A system for detecting particles on the outer surface of a vehicle has a housing capable of being placed in a test position adjacent to, but not in contact with, a portion of the outer surface of the vehicle. An elongate sealing member is fastened to the housing along a perimeter surrounding the wall, and the elongate sealing member has a contact surface facing away from the wall to contact the outer surface of the vehicle to define a test volume when the wall is in the test position. A gas flow system has at least one gas inlet extending through the wall for providing a gas stream against the surface of the vehicle within the test volume. This gas stream, which preferably is air, dislodges particles from the surface of the vehicle covered by the housing. The gas stream exits the test volume through a gas outlet and particles in the stream are detected.

  3. GAS COOLED NUCLEAR REACTORS

    DOE Patents [OSTI]

    Long, E.; Rodwell, W.

    1958-06-10

    A gas-cooled nuclear reactor consisting of a graphite reacting core and reflector structure supported in a containing vessel is described. A gas sealing means is included for sealing between the walls of the graphite structure and containing vessel to prevent the gas coolant by-passing the reacting core. The reacting core is a multi-sided right prismatic structure having a pair of parallel slots around its periphery. The containing vessel is cylindrical and has a rib on its internal surface which supports two continuous ring shaped flexible web members with their radially innermost ends in sealing engagement within the radially outermost portion of the slots. The core structure is supported on ball bearings. This design permits thermal expansion of the core stracture and vessel while maintainirg a peripheral seal between the tvo elements.

  4. Environmental surveillance master sampling schedule

    SciTech Connect (OSTI)

    Bisping, L.E.

    1995-02-01

    Environmental surveillance of the Hanford Site and surrounding areas is conducted by the Pacific Northwest Laboratory (PNL) for the U.S. Department of Energy (DOE). This document contains the planned 1994 schedules for routine collection of samples for the Surface Environmental Surveillance Project (SESP), Drinking Water Project, and Ground-Water Surveillance Project. Samples are routinely collected for the SESP and analyzed to determine the quality of air, surface water, soil, sediment, wildlife, vegetation, foodstuffs, and farm products at Hanford Site and surrounding communities. The responsibility for monitoring onsite drinking water falls outside the scope of the SESP. PNL conducts the drinking water monitoring project concurrent with the SESP to promote efficiency and consistency, utilize expertise developed over the years, and reduce costs associated with management, procedure development, data management, quality control, and reporting. The ground-water sampling schedule identifies ground-water sampling .events used by PNL for environmental surveillance of the Hanford Site. Sampling is indicated as annual, semi-annual, quarterly, or monthly in the sampling schedule. Some samples are collected and analyzed as part of ground-water monitoring and characterization programs at Hanford (e.g. Resources Conservation and Recovery Act (RCRA), Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), or Operational). The number of samples planned by other programs are identified in the sampling schedule by a number in the analysis column and a project designation in the Cosample column. Well sampling events may be merged to avoid redundancy in cases where sampling is planned by both-environmental surveillance and another program.

  5. Spark gap switch with spiral gas flow

    DOE Patents [OSTI]

    Brucker, John P.

    1989-01-01

    A spark gap switch having a contaminate removal system using an injected gas. An annular plate concentric with an electrode of the switch defines flow paths for the injected gas which form a strong spiral flow of the gas in the housing which is effective to remove contaminates from the switch surfaces. The gas along with the contaminates is exhausted from the housing through one of the ends of the switch.

  6. Gas filled panel insulation

    DOE Patents [OSTI]

    Griffith, B.T.; Arasteh, D.K.; Selkowitz, S.E.

    1993-12-14

    A structural or flexible highly insulative panel which may be translucent, is formed from multi-layer polymeric material in the form of an envelope surrounding a baffle. The baffle is designed so as to minimize heat transfer across the panel, by using material which forms substantially closed spaces to suppress convection of the low conductivity gas fill. At least a portion of the baffle carries a low emissivity surface for suppression of infrared radiation. 18 figures.

  7. Gas filled panel insulation

    DOE Patents [OSTI]

    Griffith, Brent T.; Arasteh, Dariush K.; Selkowitz, Stephen E.

    1993-01-01

    A structural or flexible highly insulative panel which may be translucent, is formed from multi-layer polymeric material in the form of an envelope surrounding a baffle. The baffle is designed so as to minimize heat transfer across the panel, by using material which forms substantially closed spaces to suppress convection of the low conductivity gas fill. At least a portion of the baffle carries a low emissivity surface for suppression of infrared radiation.

  8. Fluid sampling system for a nuclear reactor

    DOE Patents [OSTI]

    Lau, L.K.; Alper, N.I.

    1994-11-22

    A system of extracting fluid samples, either liquid or gas, from the interior of a nuclear reactor containment utilizes a jet pump. To extract the sample fluid, a nonradioactive motive fluid is forced through the inlet and discharge ports of a jet pump located outside the containment, creating a suction that draws the sample fluid from the containment through a sample conduit connected to the pump suction port. The mixture of motive fluid and sample fluid is discharged through a return conduit to the interior of the containment. The jet pump and means for removing a portion of the sample fluid from the sample conduit can be located in a shielded sample grab station located next to the containment. A non-nuclear grade active pump can be located outside the grab sampling station and the containment to pump the nonradioactive motive fluid through the jet pump. 1 fig.

  9. Fluid sampling system for a nuclear reactor

    DOE Patents [OSTI]

    Lau, Louis K.; Alper, Naum I.

    1994-01-01

    A system of extracting fluid samples, either liquid or gas, from the interior of a nuclear reactor containment utilizes a jet pump. To extract the sample fluid, a nonradioactive motive fluid is forced through the inlet and discharge ports of a jet pump located outside the containment, creating a suction that draws the sample fluid from the containment through a sample conduit connected to the pump suction port. The mixture of motive fluid and sample fluid is discharged through a return conduit to the interior of the containment. The jet pump and means for removing a portion of the sample fluid from the sample conduit can be located in a shielded sample grab station located next to the containment. A non-nuclear grade active pump can be located outside the grab sampling station and the containment to pump the nonradioactive motive fluid through the jet pump.

  10. Effect of morphology of hydrophobic surfaces on cavitation kinetics

    SciTech Connect (OSTI)

    LUZAR,ALENKA; LEUNG,KEVIN

    2000-04-24

    Cavitation has been suggested to be a possible source of long range interactions between mesoscopic hydrophobic surfaces. While evaporation is predicted by thermodynamics, little is known about its kinetics. Glauber dynamics Monte Carlo simulations of a lattice gas close to liquid-gas coexistence and confined between partially drying surfaces are used to model the effect of water confinement on the dynamics of surface-induced phase transition. Specifically, they examine how kinetics of induced evaporation change as the texture of hydrophobic surfaces is varied. Evaporation rates are considerably slowed with relatively small amount of hydrophilic coverage. However, the distribution of hydrophilic patches is found to be crucial, with the homogeneous one being much more effective in slowing the formation of vapor tubes which triggers the evaporation process. They estimate the free energy barrier of vapor tube formation via transition state theory, using a constrained forward-backward umbrella sampling technique applied to the metastable, confined liquid. Furthermore, to relate simulation rates to experimental ones, they perform simulations using the mass-conserving Kawasaki algorithm. They predict evaporation time scales that range from hundreds of picoseconds in the case of mesoscopic surfaces {approximately} 10{sup 4} nm{sup 2} to tens of nanoseconds for smaller surfaces {approximately} 40 nm{sup 2}, when the two surfaces are {approximately} 10 solvent layers apart. The present study demonstrates that cavitation is kinetically viable in real systems and should be considered in studies of processes at confined geometry.

  11. Viscous-sludge sample collector

    DOE Patents [OSTI]

    Not Available

    1979-01-01

    A vertical core sample collection system for viscous sludge is disclosed. A sample tube's upper end has a flange and is attached to a piston. The tube and piston are located in the upper end of a bore in a housing. The bore's lower end leads outside the housing and has an inwardly extending rim. Compressed gas, from a storage cylinder, is quickly introduced into the bore's upper end to rapidly accelerate the piston and tube down the bore. The lower end of the tube has a high sludge entering velocity to obtain a full-length sludge sample without disturbing strata detail. The tube's downward motion is stopped when its upper end flange impacts against the bore's lower end inwardly extending rim.

  12. Automated soil gas monitoring chamber

    DOE Patents [OSTI]

    Edwards, Nelson T.; Riggs, Jeffery S.

    2003-07-29

    A chamber for trapping soil gases as they evolve from the soil without disturbance to the soil and to the natural microclimate within the chamber has been invented. The chamber opens between measurements and therefore does not alter the metabolic processes that influence soil gas efflux rates. A multiple chamber system provides for repetitive multi-point sampling, undisturbed metabolic soil processes between sampling, and an essentially airtight sampling chamber operating at ambient pressure.

  13. September 2004 Water Sampling

    Office of Legacy Management (LM)

    5 Produced Water Sampling at the Rulison, Colorado, Site May 2015 LMSRULS00115 Available .........3 Water Sampling Field Activities Verification ...

  14. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Produced Water Sampling at the Rulison, Colorado, Site January 2016 LMSRULS00915 .........3 Water Sampling Field Activities Verification ...

  15. September 2004 Water Sampling

    Office of Legacy Management (LM)

    3 Water Sampling at the Monticello, Utah, Processing Site January 2014 LMSMNTS01013 This .........7 Water Sampling Field Activities Verification ...

  16. Where is shale gas found in the United States? | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Where is shale gas found in the United States? Where is shale gas found in the United States? Where is shale gas found in the United States? (2.7 MB) More Documents & Publications Natural Gas from Shale: Questions and Answers Shale Gas Development Challenges: Surface Impacts Shale Gas Glossary

  17. Passive gas separator and accumulator device

    DOE Patents [OSTI]

    Choe, H.; Fallas, T.T.

    1994-08-02

    A separation device employing a gas separation filter and swirler vanes for separating gas from a gas-liquid mixture is provided. The cylindrical filter utilizes the principle that surface tension in the pores of the filter prevents gas bubbles from passing through. As a result, the gas collects in the interior region of the filter and coalesces to form larger bubbles in the center of the device. The device is particularly suited for use in microgravity conditions since the swirlers induce a centrifugal force which causes liquid to move from the inner region of the filter, pass the pores, and flow through the outlet of the device while the entrained gas is trapped by the filter. The device includes a cylindrical gas storage screen which is enclosed by the cylindrical gas separation filter. The screen has pores that are larger than those of the filters. The screen prevents larger bubbles that have been formed from reaching and interfering with the pores of the gas separation filter. The device is initially filled with a gas other than that which is to be separated. This technique results in separation of the gas even before gas bubbles are present in the mixture. Initially filling the device with the dissimilar gas and preventing the gas from escaping before operation can be accomplished by sealing the dissimilar gas in the inner region of the separation device with a ruptured disc which can be ruptured when the device is activated for use. 3 figs.

  18. Analysis of K west basin canister gas

    SciTech Connect (OSTI)

    Trimble, D.J., Fluor Daniel Hanford

    1997-03-06

    Gas and Liquid samples have been collected from a selection of the approximately 3,820 spent fuel storage canisters in the K West Basin. The samples were taken to characterize the contents of the gas and water in the canisters providing source term information for two subprojects of the Spent Nuclear Fuel Project (SNFP) (Fulton 1994): the K Basins Integrated Water Treatment System Subproject (Ball 1996) and the K Basins Fuel Retrieval System Subproject (Waymire 1996). The barrels of ten canisters were sampled for gas and liquid in 1995, and 50 canisters were sampled in a second campaign in 1996. The analysis results from the first campaign have been reported (Trimble 1995a, 1995b, 1996a, 1996b). The analysis results from the second campaign liquid samples have been documented (Trimble and Welsh 1997; Trimble 1997). This report documents the results for the gas samples from the second campaign and evaluates all gas data in terms of expected releases when opening the canisters for SNFP activities. The fuel storage canisters consist of two closed and sealed barrels, each with a gas trap. The barrels are attached at a trunion to make a canister, but are otherwise independent (Figure 1). Each barrel contains up to seven N Reactor fuel element assemblies. A gas space of nitrogen was established in the top 2.2 to 2.5 inches (5.6 to 6.4 cm) of each barrel. Many of the fuel elements were damaged allowing the metallic uranium fuel to be corroded by the canister water. The corrosion releases fission products and generates hydrogen gas. The released gas mixes with the gas-space gas and excess gas passes through the gas trap into the basin water. The canister design does not allow canister water to be exchanged with basin water.

  19. Mass spectrometer having a derivatized sample presentation apparatus

    DOE Patents [OSTI]

    Nelson, Randall W.

    2000-07-25

    A mass spectrometer having a derivatized sample presentation apparatus is provided. The sample presentation apparatus has a complex bound to the surface of the sample presentation apparatus. This complex includes a molecule which may chemically modify a biomolecule.

  20. Radiolytic gas generation from cement-based waste hosts for DOE low-level radioactive wastes

    SciTech Connect (OSTI)

    Dole, L.R.; Friedman, H.A.

    1986-01-01

    Using cement-based immobilization binders with simulated radioactive waste containing sulfate, nitrate, nitrite, phosphate, and fluoride anions, the gamma- and alpha-radiolytic gas generation factors (G/sub t/, molecules/100 eV) and gas compositions were measured on specimens of cured grouts. These tests studied the effects of; (1) waste composition; (2) the sample surface-to-volume ratio; (3) the waste slurry particle size; and (4) the water content of the waste host formula. The radiolysis test vessels were designed to minimize the ''dead'' volume and to simulate the configuration of waste packages.

  1. Microsoft Word - 4Q2012_Gas PW_Samp_Results.docx

    Office of Legacy Management (LM)

    Monitoring Results for Natural Gas Wells near Project Rulison Fourth Quarter 2012 and First Quarter 2013 U.S. Department of Energy Office of Legacy Management Grand Junction, Colorado Date Sampled: January 10, 2013 Background: Project Rulison was the second Plowshare Program test to stimulate natural-gas recovery from deep and low-permeability formations. On September 10, 1969, a 40-kiloton-yield nuclear device was detonated 8,426 feet (1.6 miles) below the ground surface in the Williams Fork

  2. Method and apparatus for selective capture of gas phase analytes using metal .beta.-diketonate polymers

    DOE Patents [OSTI]

    Harvey, Scott D [Kennewick, WA

    2011-06-21

    A process and sensor device are disclosed that employ metal .beta.-diketonate polymers to selectively capture gas-phase explosives and weaponized chemical agents in a sampling area or volume. The metal .beta.-diketonate polymers can be applied to surfaces in various analytical formats for detection of: improvised explosive devices, unexploded ordinance, munitions hidden in cargo holds, explosives, and chemical weapons in public areas.

  3. Brine Sampling and Evaluation Program, 1991 report

    SciTech Connect (OSTI)

    Deal, D.E.; Abitz, R.J.; Myers, J.; Martin, M.L.; Milligan, D.J.; Sobocinski, R.W.; Lipponer, P.P.J.; Belski, D.S.

    1993-09-01

    The data presented in this report are the result of Brine Sampling and Evaluation Program (BSEP) activities at the Waste Isolation Pilot Plan (WIPP) during 1991. These BSEP activities document and investigate the origins, hydraulic characteristics, extent, and composition of brine occurrences in the Permian Salado Formation and seepage of that brine into the excavations at the WIPP. When excavations began at the WIPP in 1982, small brine seepages (weeps) were observed on the walls. Brine studies began as part of the Site Validation Program and were formalized as a program in its own right in 1985. During nine years of observations (1982--1991), evidence has mounted that the amount of brine seeping into the WIPP excavations is limited, local, and only a small fraction of that required to produce hydrogen gas by corroding the metal in the waste drums and waste inventory. The data through 1990 is discussed in detail and summarized by Deal and others (1991). The data presented in this report describes progress made during the calendar year 1991 and focuses on four major areas: (1) quantification of the amount of brine seeping across vertical surfaces in the WIPP excavations (brine ``weeps); (2) monitoring of brine inflow, e.g., measuring brines recovered from holes drilled downward from the underground drifts (downholes), upward from the underground drifts (upholes), and from subhorizontal holes; (3) further characterization of brine geochemistry; and (4) preliminary quantification of the amount of brine that might be released by squeezing the underconsolidated clays present in the Salado Formation.

  4. Apparatus and method for monitoring of gas having stable isotopes

    SciTech Connect (OSTI)

    Clegg, Samuel M; Fessenden-Rahn, Julianna E

    2013-03-05

    Gas having stable isotopes is monitored continuously by using a system that sends a modulated laser beam to the gas and collects and transmits the light not absorbed by the gas to a detector. Gas from geological storage, or from the atmosphere can be monitored continuously without collecting samples and transporting them to a lab.

  5. September 2004 Water Sampling

    Office of Legacy Management (LM)

    ... levels at the site to natural thorium in the uranium ore. ... screened for radium-226 by gas flow proportional counting. ... Chromatography Peak Integration The integration of analyte ...

  6. WRAP Module 1 sampling strategy and waste characterization alternatives study

    SciTech Connect (OSTI)

    Bergeson, C.L.

    1994-09-30

    The Waste Receiving and Processing Module 1 Facility is designed to examine, process, certify, and ship drums and boxes of solid wastes that have a surface dose equivalent of less than 200 mrem/h. These wastes will include low-level and transuranic wastes that are retrievably stored in the 200 Area burial grounds and facilities in addition to newly generated wastes. Certification of retrievably stored wastes processing in WRAP 1 is required to meet the waste acceptance criteria for onsite treatment and disposal of low-level waste and mixed low-level waste and the Waste Isolation Pilot Plant Waste Acceptance Criteria for the disposal of TRU waste. In addition, these wastes will need to be certified for packaging in TRUPACT-II shipping containers. Characterization of the retrievably stored waste is needed to support the certification process. Characterization data will be obtained from historical records, process knowledge, nondestructive examination nondestructive assay, visual inspection of the waste, head-gas sampling, and analysis of samples taken from the waste containers. Sample characterization refers to the method or methods that are used to test waste samples for specific analytes. The focus of this study is the sample characterization needed to accurately identify the hazardous and radioactive constituents present in the retrieved wastes that will be processed in WRAP 1. In addition, some sampling and characterization will be required to support NDA calculations and to provide an over-check for the characterization of newly generated wastes. This study results in the baseline definition of WRAP 1 sampling and analysis requirements and identifies alternative methods to meet these requirements in an efficient and economical manner.

  7. LCLS Sample Preparation Laboratory | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LCLS Sample Preparation Laboratory Kayla Zimmerman | (650) 926-6281 Lisa Hammon, LCLS Lab Coordinator Welcome to the LCLS Sample Preparation Laboratory. This small general use wet lab is located in Rm 109 of the Far Experimental Hall near the MEC, CXI, and XCS hutches. It conveniently serves all LCLS hutches and is available for final stage sample preparation. Due to space limitations, certain types of activities may be restricted and all access must be scheduled in advance. User lab bench

  8. Passive gas separator and accumulator device

    DOE Patents [OSTI]

    Choe, Hwang; Fallas, Thomas T.

    1994-01-01

    A separation device employing a gas separation filter and swirler vanes for separating gas from a gasliquid mixture is provided. The cylindrical filter utilizes the principle that surface tension in the pores of the filter prevents gas bubbles from passing through. As a result, the gas collects in the interior region of the filter and coalesces to form larger bubbles in the center of the device. The device is particularly suited for use in microgravity conditions since the swirlers induce a centrifugal force which causes liquid to move from the inner region of the filter, pass the pores, and flow through the outlet of the device while the entrained gas is trapped by the filter. The device includes a cylindrical gas storage screen which is enclosed by the cylindrical gas separation filter. The screen has pores that are larger than those of the filters. The screen prevents larger bubbles that have been formed from reaching and interfering with the pores of the gas separation filter. The device is initially filled with a gas other than that which is to be separated. This technique results in separation of the gas even before gas bubbles are present in the mixture. Initially filling the device with the dissimilar gas and preventing the gas from escaping before operation can be accomplished by sealing the dissimilar gas in the inner region of the separation device with a ruptured disc which can be ruptured when the device is activated for use.

  9. Development of unconventional oil and gas (UOG) must be done...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    unconventional oil and gas (UOG) must be done in responsible ways to minimize surface ... Office of Oil and Natural Gas Goals * To reduce the amount of land and time needed for oil ...

  10. Sample introduction system for a flow cytometer

    DOE Patents [OSTI]

    Van den Engh, Ger

    1997-01-01

    A sample introduction system for a flow cytometer allows easy change of sample containers such as test tubes and facilitates use in high pressure environments. The sample container includes a cap having a pressure supply chamber and a sample container attachment cavity. A sample container may be automatically positioned into the attachment cavity so as to sealably engage the end of the sample container as its outer surface. This positioning may be accomplished through some sample introduction mechanism. To facilitate cleaning, HPLC tubing and fittings may be used in a manner which facilitates removing of the entire tubing from both the nozzle container and other sample container cap to permit its replacement to avoid contamination. The sample container support may include horizontal stops which loosely limit the movement of the sample container and thus avoid further stresses upon it.

  11. Sample introduction apparatus for a flow cytometer

    DOE Patents [OSTI]

    Van den Engh, Ger

    1998-01-01

    A sample introduction system for a flow cytometer allows easy change of sample containers such as test tubes and facilitates use in high pressure environments. The sample container includes a cap having a pressure supply chamber and a sample container attachment cavity. A sample container may be automatically positioned into the attachment cavity so as to sealably engage the end of the sample container as its outer surface. This positioning may be accomplished through some sample introduction mechanism. To facilitate cleaning HPLC tubing and fittings may be used in a manner which facilitates removable of the entire tubing from both the nozzle container and other sample container cap to permit its replacement to avoid contamination. The sample container support may include horizontal stops which loosely limit the movement of the sample container and thus avoid further stresses upon it.

  12. Sample introduction apparatus for a flow cytometer

    DOE Patents [OSTI]

    Van den Engh, G.

    1998-03-10

    A sample introduction system for a flow cytometer allows easy change of sample containers such as test tubes and facilitates use in high pressure environments. The sample container includes a cap having a pressure supply chamber and a sample container attachment cavity. A sample container may be automatically positioned into the attachment cavity so as to sealably engage the end of the sample container as its outer surface. This positioning may be accomplished through some sample introduction mechanism. To facilitate cleaning HPLC tubing and fittings may be used in a manner which facilitates removable of the entire tubing from both the nozzle container and other sample container cap to permit its replacement to avoid contamination. The sample container support may include horizontal stops which loosely limit the movement of the sample container and thus avoid further stresses upon it. 3 figs.

  13. Sample introduction system for a flow cytometer

    DOE Patents [OSTI]

    Engh, G. van den

    1997-02-11

    A sample introduction system for a flow cytometer allows easy change of sample containers such as test tubes and facilitates use in high pressure environments. The sample container includes a cap having a pressure supply chamber and a sample container attachment cavity. A sample container may be automatically positioned into the attachment cavity so as to sealably engage the end of the sample container as its outer surface. This positioning may be accomplished through some sample introduction mechanism. To facilitate cleaning, HPLC tubing and fittings may be used in a manner which facilitates removing of the entire tubing from both the nozzle container and other sample container cap to permit its replacement to avoid contamination. The sample container support may include horizontal stops which loosely limit the movement of the sample container and thus avoid further stresses upon it. 3 figs.

  14. Gas sensor

    DOE Patents [OSTI]

    Schmid, Andreas K.; Mascaraque, Arantzazu; Santos, Benito; de la Figuera, Juan

    2014-09-09

    A gas sensor is described which incorporates a sensor stack comprising a first film layer of a ferromagnetic material, a spacer layer, and a second film layer of the ferromagnetic material. The first film layer is fabricated so that it exhibits a dependence of its magnetic anisotropy direction on the presence of a gas, That is, the orientation of the easy axis of magnetization will flip from out-of-plane to in-plane when the gas to be detected is present in sufficient concentration. By monitoring the change in resistance of the sensor stack when the orientation of the first layer's magnetization changes, and correlating that change with temperature one can determine both the identity and relative concentration of the detected gas. In one embodiment the stack sensor comprises a top ferromagnetic layer two mono layers thick of cobalt deposited upon a spacer layer of ruthenium, which in turn has a second layer of cobalt disposed on its other side, this second cobalt layer in contact with a programmable heater chip.

  15. Rotary mode core sampling approved checklist: 241-TX-113

    SciTech Connect (OSTI)

    Fowler, K.D.

    1998-08-03

    The safety assessment for rotary mode core sampling was developed using certain bounding assumptions, however, those assumptions were not verified for each of the existing or potential flammable gas tanks. Therefore, a Flammable Gas/Rotary Mode Core Sampling Approved Checklist has been completed for tank 241-TX-113 prior to sampling operations. This transmittal documents the dispositions of the checklist items from the safety assessment.

  16. Rotary mode core sampling approved checklist: 241-TX-116

    SciTech Connect (OSTI)

    FOWLER, K.D.

    1999-02-24

    The safety assessment for rotary mode core sampling was developed using certain bounding assumptions, however, those assumptions were not verified for each of the existing or potential flammable gas tanks. Therefore, a Flammable Gas/Rotary Mode Core Sampling Approved Checklist has been completed for tank 241-TX-116 prior to sampling operations. This transmittal documents the dispositions of the checklist items from the safety assessment.

  17. Determination of landfill gas composition and pollutant emission rates at fresh kills landfill. Volume 2. Appendices to project report. Final report

    SciTech Connect (OSTI)

    1995-12-07

    Air emissions of landfill gas pollutants at Fresh Kills Landfill, located in Staten Island, NY, were estimated based on three weeks of sampling of flow, concentration, and flux at passive vents, gas extraction wells, gas collection plant headers, and the landfill surface conducted by Radian Corporation in 1995. Emission rates were estimated for 202 pollutants, including hydrogen sulfide, mercury vapor, speciated volatile organic compounds, methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane, and carbon dioxide. Results indicate that large amounts of mercury enter the methane recovery plant. Emission factors based on the results are presented.

  18. Environmental surveillance master sampling schedule

    SciTech Connect (OSTI)

    Bisping, L.E.

    1991-01-01

    Environmental surveillance of the Hanford Site and surrounding areas is conducted by the Pacific Northwest Laboratory (PNL) for the US Department of Energy (DOE). This document contains the planned schedule for routine sample collection for the Surface Environmental Surveillance Project (SESP) and Ground-Water Monitoring Project. The routine sampling plan for the SESP has been revised this year to reflect changing site operations and priorities. Some sampling previously performed at least annually has been reduced in frequency, and some new sampling to be performed at a less than annual frequency has been added. Therefore, the SESP schedule reflects sampling to be conducted in calendar year 1991 as well as future years. The ground-water sampling schedule is for 1991. This schedule is subject to modification during the year in response to changes in Site operation, program requirements, and the nature of the observed results. Operational limitations such as weather, mechanical failures, sample availability, etc., may also require schedule modifications. Changes will be documented in the respective project files, but this plan will not be reissued. The purpose of these monitoring projects is to evaluate levels of radioactive and nonradioactive pollutants in the Hanford evirons.

  19. September 2004 Water Sampling

    Office of Legacy Management (LM)

    ... Inductively Coupled Plasma (ICP) Interference Check Sample (ICS) Analysis ICP interference check samples ICSA and ICSAB were analyzed at the required frequency to verify the ...

  20. Visual Sample Plan Flyer

    Office of Energy Efficiency and Renewable Energy (EERE)

    This flyer better explains that VSP is a free, easy-to-use software tool that supports development of optimal sampling plans based on statistical sampling theory.

  1. Plasma processing of large curved surfaces for superconducting rf cavity modification

    SciTech Connect (OSTI)

    Upadhyay, J; Im, Do; Popovi??, S; Valente-Feliciano, A -M; Phillips, L; Vuskovic, L

    2014-12-01

    Plasma based surface modification of niobium is a promising alternative to wet etching of superconducting radio frequency (SRF) cavities. The development of the technology based on Cl2/Ar plasma etching has to address several crucial parameters which influence the etching rate and surface roughness, and eventually, determine cavity performance. This includes dependence of the process on the frequency of the RF generator, gas pressure, power level, the driven (inner) electrode configuration, and the chlorine concentration in the gas mixture during plasma processing. To demonstrate surface layer removal in the asymmetric non-planar geometry, we are using a simple cylindrical cavity with 8 ports symmetrically distributed over the cylinder. The ports are used for diagnosing the plasma parameters and as holders for the samples to be etched. The etching rate is highly correlated with the shape of the inner electrode, radio-frequency (RF) circuit elements, chlorine concentration in the Cl2/Ar gas mixtures, residence time of reactive species and temperature of the cavity. Using cylindrical electrodes with variable radius, large-surface ring-shaped samples and d.c. bias implementation in the external circuit we have demonstrated substantial average etching rates and outlined the possibility to optimize plasma properties with respect to maximum surface processing effect.

  2. UMTRA project water sampling and analysis plan, Riverton, Wyoming

    SciTech Connect (OSTI)

    Not Available

    1994-03-01

    Surface remediation was completed at the former uranium mill site in Riverton, Wyoming, in 1990. Residual radioactive materials (contaminated soil and debris) were removed and disposed of at Union Carbide Corporation`s (Umetco) nearby Gas Hills Title 2 facility. Ground water in the surficial and semiconfined aquifers (known collectively as the `uppermost aquifer`) below the former mill and tailings site has been contaminated. No contamination has been detected in the deeper, confined sandstone aquifer. The contaminant plume extends off site to the south and east. The plume is constrained by surface wetlands and small streams to the east and west of the site and by the Little Wind River to the south. Fifteen monitor wells installed in 1993 were sampled to better define the contaminant plume and to provide additional water quality data for the baseline risk assessment. Samples also were collected from domestic wells in response to a request by the Wyoming Department of Environmental Quality in January 1994. No contamination attributable to the former uranium milling operations have ever been detected in any of the domestic wells used for potable supplies.

  3. Natural Gas Applications

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Gas Applications. If you need assistance viewing this page, please call (202) 586-8800. Energy Information Administration Home Page Home > Natural Gas > Natural Gas Applications...

  4. Natural Gas Weekly Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    natural gas demand, thereby contributing to larger net injections of natural gas into storage. Other Market Trends: EIA Releases The Natural Gas Annual 2006: The Energy...

  5. Handsfree Surface Analysis

    Energy Science and Technology Software Center (OSTI)

    2006-11-01

    The HANDSFREE SURFACE ANALYSIS software code enables unattended analysis of surfaces by desorption electrospray (DESI) and liquid-junction surface sampling probe (SSP) mass spectrometry. The software allows automated lane scanning, imaging (e.g. lane rastering), spot and array sampling, and array scanning methods by controlling the movement of the sample attached to a computer-controlled stage. The software is able to collect, visualize and analyze mass spectrometry data real-time for surface analysis purposes by interacting with mass spectrometrymore » instrumentation software. The software also enables data post processing for imaging and other analytical purposes. The software also contains image analysis approaches to control the sampling capillary-to-surface distance when used with DESI, and for automated formation and real-time reoptimization of the sampling probe-to-surface liquid microjunction when used with SSP. Control of these distances is essential to automated, hands-free operation of a DESI or SSP mass spectrometry system.« less

  6. Graph facilitates tracking water and gas influx

    SciTech Connect (OSTI)

    Gruy, H.J. )

    1990-03-26

    Graphing the vertical distribution of reservoir volume is an easy method for estimating the acre-ft remaining to be exploited in reservoirs with water or gas encroachment. To evaluate reservoir performance and estimate oil and gas reserves in water-drive reservoirs or oil reservoirs with a gas cap, it is necessary to determine the magnitude of the movement of oil-water and gas-oil contact surfaces. In reviewing reserve estimates and reservoir studies done by others, the authors have found that very few reservoir engineers or geologists have an easy method for tracking the movement of these surfaces and estimating the volumes of oil displaced water encroachment, gas cap expansion, or the volumes of oil lost by wetting the gas cap. The following method evolved from the author's studies of the East Texas field starting in 1942, and it took this form in the early 1950s.

  7. GAS SEAL

    DOE Patents [OSTI]

    Monson, H.; Hutter, E.

    1961-07-11

    A seal is described for a cover closing an opening in the top of a pressure vessel that may house a nuclear reactor. The seal comprises a U-shaped trough formed on the pressure vessel around the opening therein, a mass of metal in the trough, and an edge flange on the cover extending loosely into the trough and dipping into the metal mass. The lower portion of the metal mass is kept melted, and the upper portion, solid. The solid pontion of the metal mass prevents pressure surges in the vessel from expelling the liquid portion of the metal mass from the trough; the liquld portion, thus held in place by the solid portion, does not allow gas to go through, and so gas cannot escape through shrinkage holes in the solid portion.

  8. Gas sensitive materials for gas detection and methods of making

    DOE Patents [OSTI]

    Trakhtenberg, Leonid Israilevich; Gerasimov, Genrikh Nikolaevich; Gromov, Vladimir Fedorovich; Rozenberg, Valeriya Isaakovna

    2014-07-15

    A gas sensitive material comprising SnO.sub.2 nanocrystals doped with In.sub.2O.sub.3 and an oxide of a platinum group metal, and a method of making the same. The platinum group metal is preferably Pd, but also may include Pt, Ru, Ir, and combinations thereof. The SnO.sub.2 nanocrystals have a specific surface of 7 or greater, preferably about 20 m2/g, and a mean particle size of between about 10 nm and about 100 nm, preferably about 40 nm. A gas detection device made from the gas sensitive material deposited on a substrate, the gas sensitive material configured as a part of a current measuring circuit in communication with a heat source.

  9. Gas sensitive materials for gas detection and method of making

    DOE Patents [OSTI]

    Trakhtenberg, Leonid Israilevich; Gerasimov, Genrikh Nikolaevich; Gromov, Vladimir Fedorovich; Rozenberg, Valeriya Isaakovna

    2012-12-25

    A gas sensitive material comprising SnO2 nanocrystals doped with In2O3 and an oxide of a platinum group metal, and a method of making the same. The platinum group metal is preferably Pd, but also may include Pt, Ru, Ir, and combinations thereof. The SnO2 nanocrystals have a specific surface of 7 or greater, preferably about 20 m2/g, and a mean particle size of between about 10 nm and about 100 nm, preferably about 40 nm. A gas detection device made from the gas sensitive material deposited on a substrate, the gas sensitive material configured as a part of a current measuring circuit in communication with a heat source.

  10. Fluid sampling tool

    DOE Patents [OSTI]

    Garcia, Anthony R.; Johnston, Roger G.; Martinez, Ronald K.

    2000-01-01

    A fluid-sampling tool for obtaining a fluid sample from a container. When used in combination with a rotatable drill, the tool bores a hole into a container wall, withdraws a fluid sample from the container, and seals the borehole. The tool collects fluid sample without exposing the operator or the environment to the fluid or to wall shavings from the container.

  11. New Mexico Natural Gas in Underground Storage (Base Gas) (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Base Gas) (Million Cubic Feet) New Mexico Natural Gas in Underground Storage (Base Gas) ... Underground Base Natural Gas in Storage - All Operators New Mexico Underground Natural Gas ...

  12. New York Natural Gas in Underground Storage (Base Gas) (Million...

    U.S. Energy Information Administration (EIA) Indexed Site

    Base Gas) (Million Cubic Feet) New York Natural Gas in Underground Storage (Base Gas) ... Underground Base Natural Gas in Storage - All Operators New York Underground Natural Gas ...

  13. The Sample Preparation Laboratories | Sample Preparation Laboratories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cynthia Patty 1 Sam Webb 2 John Bargar 3 Arizona 4 Chemicals 5 Team Work 6 Bottles 7 Glass 8 Plan Ahead! See the tabs above for Laboratory Access and forms you'll need to complete. Equipment and Chemicals tabs detail resources already available on site. Avoid delays! Hazardous materials use may require a written Standard Operating Procedure (SOP) before you work. Check the Chemicals tab for more information. The Sample Preparation Laboratories The Sample Preparation Laboratories provide wet lab

  14. Thermionic gas switch

    DOE Patents [OSTI]

    Hatch, G.L.; Brummond, W.A.; Barrus, D.M.

    1984-04-05

    The present invention is directed to an improved temperature responsive thermionic gas switch utilizing a hollow cathode and a folded emitter surface area. The folded emitter surface area of the thermionic switch substantially increases the on/off ratio by changing the conduction surface area involved in the two modes thereof. The improved switch of this invention provides an on/off ratio of 450:1 compared to the 10:1 ratio of the prior known thermionic switch, while providing for adjusting the on current. In the improved switch of this invention the conduction area is made small in the off mode, while in the on mode the conduction area is made large. This is achieved by utilizing a folded hollow cathode configuration and utilizing a folded emitter surface area, and by making the dimensions of the folds small enough so that a space charge will develop in the convolutions of the folds and suppress unignited current, thus limiting the current carrying surface in the off mode.

  15. ,"Natural Gas Consumption",,,"Natural Gas Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    Census Division, 1999" ,"Natural Gas Consumption",,,"Natural Gas Expenditures" ,"per Building (thousand cubic feet)","per Square Foot (cubic feet)","per Worker (thousand cubic...

  16. Shale gas is natural gas trapped inside

    Broader source: Energy.gov (indexed) [DOE]

    Shale gas is natural gas trapped inside formations of shale - fine grained sedimentary ... Fossil Energy Research Benefits FE's early investments in shale research in the 1970s ...

  17. Radionuclide gas transport through nuclear explosion-generated fracture networks

    SciTech Connect (OSTI)

    Jordan, Amy B.; Stauffer, Philip H.; Knight, Earl E.; Rougier, Esteban; Anderson, Dale N.

    2015-12-17

    Underground nuclear weapon testing produces radionuclide gases which may seep to the surface. Barometric pumping of gas through explosion-fractured rock is investigated using a new sequentially-coupled hydrodynamic rock damage/gas transport model. Fracture networks are produced for two rock types (granite and tuff) and three depths of burial. The fracture networks are integrated into a flow and transport numerical model driven by surface pressure signals of differing amplitude and variability. There are major differences between predictions using a realistic fracture network and prior results that used a simplified geometry. Matrix porosity and maximum fracture aperture have the greatest impact on gas breakthrough time and window of opportunity for detection, with different effects between granite and tuff simulations highlighting the importance of accurately simulating the fracture network. In particular, maximum fracture aperture has an opposite effect on tuff and granite, due to different damage patterns and their effect on the barometric pumping process. From stochastic simulations using randomly generated hydrogeologic parameters, normalized detection curves are presented to show differences in optimal sampling time for granite and tuff simulations. In conclusion, seasonal and location-based effects on breakthrough, which occur due to differences in barometric forcing, are stronger where the barometric signal is highly variable.

  18. NNSA implements nondestructive gas sampling technique for nuclear weapon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Security Site | National Nuclear Security Administration | (NNSA) hosts international CTBT on-site inspection experts at Nevada National Security Site Thursday, May 26, 2016 - 2:26pm CTBT surrogate inspectors and other inspection experts visited the Nevada National Security Site, a former nuclear explosive test site. Here they are pictured on the edge of the Sedan Crater. This month, NNSA hosted a Comprehensive Nuclear-Test-Ban Treaty (CTBT) on-site inspection activity at the Nevada National

  19. Gas Flux Sampling (Klein, 2007) | Open Energy Information

    Open Energy Info (EERE)

    In The Past 20 Years- Geochemistry In Geothermal Exploration Resource Evaluation And Reservoir Management Additional References Retrieved from "http:en.openei.orgw...

  20. Gas Sampling At Valles Caldera - Sulphur Springs Geothermal Area...

    Open Energy Info (EERE)

    to other geothermal systems hosted within sedimentary rocks, suggesting that organic carbon and nitrogen in Paleozoic and Miocene strata were depleted during 13 million years...

  1. Soil Gas Sampling At Kilauea East Rift Geothermal Area (Cox,...

    Open Energy Info (EERE)

    the ground in the Lower East Rift Zone were measured using alpha particle sensitive cellulose nitrate films. The survey was successful in defining an area of geothermal...

  2. ARM - Field Campaign - Precision Gas Sampling (PGS) Validation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in an example of grazed land of the Southern Great Plains. In collaboration with Dr. Herman Mayeux, of the USDA Grazing Lands Research Laboratory (GRL), we conducted a...

  3. Gas Flux Sampling At Long Valley Caldera Geothermal Area (Bergfeld...

    Open Energy Info (EERE)

    from locations west and east of the plant revealed the presence of isobutane related to plant operations. The 13C values of diffuse CO2 range from - 5.7 to - 3.4, similar...

  4. Precision Gas Sampling (PGS) Validation2011-2014 Final Campaign...

    Office of Scientific and Technical Information (OSTI)

    We did observe that, because of the drought, the net ecosystem exchange of CO2 was much lower in 2011 than in 2010. Concomitantly, sensible heat fluxes increased and latent heat ...

  5. Gas Flux Sampling At Long Valley Caldera Geothermal Area (Lewicki...

    Open Energy Info (EERE)

    between chamber CO2 fluxes and the atmospheric parameters over a comparable time period. Energy balance closure was assessed by statistical regression of EC energy fluxes...

  6. Sample Format In-Transit Natural Gas (Pipeline) Monthly Sales...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (7) (8) (9) Origin & Final Destination Country (one country) Transit Country Initial Border Crossing Point Foreign Transporter at Initial Border Crossing U.S. Transporter at...

  7. Sample Format Natural Gas Exports by Pipeline Monthly Sales and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (4) (5) (6) (7) (8) Destination Country Point of EXIT from U.S. Volume (Mcf at U.S. Border) Avg. Price at U.S. Border (U.S.MMBtu) Supplier(s) Foreign Transporter U.S....

  8. Sample Format Natural Gas Imports by Pipeline Monthly Sales and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (4) (5) (6) (7) (8) (9) Country of Origin Point of ENTRY into U.S. Volume (Mcf at U.S. Border) Avg. Price at U.S. Border (U.S.MMBtu) Supplier(s) Foreign Transporter U.S....

  9. Gas Flux Sampling At Dixie Valley Geothermal Area (Iovenitti...

    Open Energy Info (EERE)

    H. Ibser, Jennifer Lewicki, B. Mack. Kennedy, Michael Swyer (2013) Egs Exploration Methodology Project Using the Dixie Valley Geothermal System, Nevada, Status Update Additional...

  10. Gas Flux Sampling (Lewicki & Oldenburg, 2005) | Open Energy Informatio...

    Open Energy Info (EERE)

    Activity Date Usefulness useful DOE-funding Unknown References Jennifer L. Lewicki, Curtis M. Oldenburg (2005) Strategies To Detect Hidden Geothermal Systems Based On Monitoring...

  11. Natural Gas Basics

    SciTech Connect (OSTI)

    NREL Clean Cities

    2010-04-01

    Fact sheet answers questions about natural gas production and use in transportation. Natural gas vehicles are also described.

  12. Microsoft Word - 4Q2011_Gas_samp.doc

    Office of Legacy Management (LM)

    Fourth Quarter 2011 U.S. Department of Energy Office of Legacy Management Grand Junction, Colorado Date Sampled: 6 December 2011 Purpose: The purpose of this environmental sample collection is to monitor natural gas and production water from natural gas wells drilled near the Project Rulison test site. As part of the Department of Energy's (DOE's) directive to protect human health and the environment, samples are collected from producing gas wells and analyzed to ensure no Rulison related

  13. Rain sampling device

    DOE Patents [OSTI]

    Nelson, D.A.; Tomich, S.D.; Glover, D.W.; Allen, E.V.; Hales, J.M.; Dana, M.T.

    1991-05-14

    The present invention constitutes a rain sampling device adapted for independent operation at locations remote from the user which allows rainfall to be sampled in accordance with any schedule desired by the user. The rain sampling device includes a mechanism for directing wet precipitation into a chamber, a chamber for temporarily holding the precipitation during the process of collection, a valve mechanism for controllably releasing samples of the precipitation from the chamber, a means for distributing the samples released from the holding chamber into vessels adapted for permanently retaining these samples, and an electrical mechanism for regulating the operation of the device. 11 figures.

  14. Rain sampling device

    DOE Patents [OSTI]

    Nelson, Danny A.; Tomich, Stanley D.; Glover, Donald W.; Allen, Errol V.; Hales, Jeremy M.; Dana, Marshall T.

    1991-01-01

    The present invention constitutes a rain sampling device adapted for independent operation at locations remote from the user which allows rainfall to be sampled in accordance with any schedule desired by the user. The rain sampling device includes a mechanism for directing wet precipitation into a chamber, a chamber for temporarily holding the precipitation during the process of collection, a valve mechanism for controllably releasing samples of said precipitation from said chamber, a means for distributing the samples released from the holding chamber into vessels adapted for permanently retaining these samples, and an electrical mechanism for regulating the operation of the device.

  15. Study of the effect of the acid-base surface properties of ZnO, Fe{sub 2}O{sub 3} and ZnFe{sub 2}O{sub 4} oxides on their gas sensitivity to ethanol vapor

    SciTech Connect (OSTI)

    Karpova, S. S. Moshnikov, V. A.; Maksimov, A. I.; Mjakin, S. V.; Kazantseva, N. E.

    2013-08-15

    Binary (ZnO, Fe{sub 2}O{sub 3}) and ternary (ZnFe{sub 2}O{sub 4}) gas-sensitive oxide materials are synthesized, and the correlation between their sensitivity to ethanol vapor and the functional chemical composition of the surface is studied by X-ray photoelectron spectroscopy and by the technique of the adsorption of acid-base indicators. It is found that the sensitivity to ethanol increases with increasing content of Broensted acid sites with the acidity index pK{sub a} Almost-Equal-To 2.5 and with increasing percentage of surface oxygen involved in OH/CO{sub 3}/C-O groups. This interrelation is attributed to the specific features of interaction between ethanol molecules and hydroxyl groups on the surface of the oxides.

  16. Differences Between Monthly and Weekly Working Gas In Storage

    Weekly Natural Gas Storage Report (EIA)

    levels. These are estimated from volume data provided by a sample of operators that report on Form EIA-912, "Weekly Underground Natural Gas Storage Report." The EIA first...

  17. Water and Sediment Sampling

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MDC Blank 7222014 Below MDC Below MDC Water Sampling Results Location Sample Date WIPP ... Tut Tank 3132014 Below MDC Below MDC Fresh Water Tank 3122014 Below MDC Below MDC Hill ...

  18. September 2004 Water Sampling

    Office of Legacy Management (LM)

    ... 100, 17B, 1A, 72, and 81 were classified as Category II. The sample results were qualified with a "Q" flag, indicating the data are qualitative because of the sampling technique. ...

  19. September 2004 Water Sampling

    Office of Legacy Management (LM)

    ... the applicable MDL. Inductively Coupled Plasma Interference Check Sample Analysis ... and background correction factors for all inductively coupled plasma instruments. ...

  20. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........7 Water Sampling Field Activities Verification ... Groundwater Quality Data Static Water Level Data Time-Concentration Graphs ...

  1. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Groundwater Quality Data Static Water Level Data Hydrographs Time-Concentration ...

  2. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Groundwater Quality Data Static Water Level Data Hydrograph Time-Concentration ...

  3. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Quality Data Equipment Blank Data Static Water Level Data Time-Concentration Graphs ...

  4. September 2004 Water Sampling

    Office of Legacy Management (LM)

    .........5 Water Sampling Field Activities Verification ... Groundwater Quality Data Static Water Level Data Time-Concentration Graphs ...

  5. Method and apparatus for recovering a gas from a gas hydrate located on the ocean floor

    DOE Patents [OSTI]

    Wyatt, Douglas E.

    2001-01-01

    A method and apparatus for recovering a gas from a gas hydrate on the ocean floor includes a flexible cover, a plurality of steerable base members secured to the cover, and a steerable mining module. A suitable source for inflating the cover over the gas hydrate deposit is provided. The mining module, positioned on the gas hydrate deposit, is preferably connected to the cover by a control cable. A gas retrieval conduit or hose extends upwardly from the cover to be connected to a support ship on the ocean surface.

  6. Gas/liquid sampler for closed canisters in KW Basin - test report

    SciTech Connect (OSTI)

    Pitkoff, C.C.

    1995-01-23

    Test report for the gas/liquid sampler designed and developed for sampling closed canisters in the KW Basin.

  7. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Water Sampling at the Ambrosia Lake, New Mexico, Disposal Site February 2015 LMS/AMB/S01114 This page intentionally left blank U.S. Department of Energy DVP-November 2014, Ambrosia Lake, New Mexico February 2015 RIN 14116607 Page i Contents Sampling Event Summary ...............................................................................................................1 Ambrosia Lake, NM, Disposal Site Planned Sampling Map...........................................................3 Data

  8. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Sampling at the Ambrosia Lake, New Mexico, Disposal Site March 2016 LMS/AMB/S01215 This page intentionally left blank U.S. Department of Energy DVP-December 2015, Ambrosia Lake, New Mexico March 2016 RIN 15117494 Page i Contents Sampling Event Summary ...............................................................................................................1 Ambrosia Lake, NM, Disposal Site Planned Sampling Map...........................................................3 Data Assessment

  9. September 2004 Water Sampling

    Office of Legacy Management (LM)

    October 2013 Groundwater Sampling at the Bluewater, New Mexico, Disposal Site December 2013 LMS/BLU/S00813 This page intentionally left blank U.S. Department of Energy DVP-August and October 2013, Bluewater, New Mexico December 2013 RIN 13085537 and 13095651 Page i Contents Sampling Event Summary ...............................................................................................................1 Private Wells Sampled August 2013 and October 2013, Bluewater, NM, Disposal Site

  10. September 2004 Water Sampling

    Office of Legacy Management (LM)

    4 Alternate Water Supply System Sampling at the Riverton, Wyoming, Processing Site May 2014 LMS/RVT/S00314 This page intentionally left blank U.S. Department of Energy DVP-March 2014, Riverton, Wyoming May 2014 RIN 14035986 Page i Contents Sampling Event Summary ...............................................................................................................1 Riverton, WY, Processing Site, Sample Location Map ...................................................................3 Data

  11. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Sampling at the Grand Junction, Colorado, Disposal Site November 2013 LMS/GRJ/S00813 This page intentionally left blank U.S. Department of Energy DVP-August 2013, Grand Junction, Colorado November 2013 RIN 13075515 Page i Contents Sampling Event Summary ...............................................................................................................1 Grand Junction, Colorado, Disposal Site Sample Location Map ....................................................3 Data Assessment

  12. September 2004 Water Sampling

    Office of Legacy Management (LM)

    Old and New Rifle, Colorado, Processing Sites August 2013 LMS/RFN/RFO/S00613 This page intentionally left blank U.S. Department of Energy DVP-June 2013, Rifle, Colorado August 2013 RIN 13065380 Page i Contents Sampling Event Summary ...............................................................................................................1 Sample Location Map, New Rifle, Colorado, Processing Site ........................................................5 Sample Location Map, Old Rifle,

  13. New York Natural Gas Number of Gas and Gas Condensate Wells ...

    U.S. Energy Information Administration (EIA) Indexed Site

    Gas and Gas Condensate Wells (Number of Elements) New York Natural Gas Number of Gas and ... Number of Producing Gas Wells Number of Producing Gas Wells (Summary) New York Natural Gas ...

  14. Proceedings of the wellbore sampling workshop Traeger, R.K. ...

    Office of Scientific and Technical Information (OSTI)

    Harding, B.W. 58 GEOSCIENCES; 15 GEOTHERMAL ENERGY; 02 PETROLEUM; 03 NATURAL GAS; 04 OIL SHALES AND TAR SANDS; 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; BOREHOLES; SAMPLING;...

  15. Aerosol sampling system

    DOE Patents [OSTI]

    Masquelier, Donald A.

    2004-02-10

    A system for sampling air and collecting particulate of a predetermined particle size range. A low pass section has an opening of a preselected size for gathering the air but excluding particles larger than the sample particles. An impactor section is connected to the low pass section and separates the air flow into a bypass air flow that does not contain the sample particles and a product air flow that does contain the sample particles. A wetted-wall cyclone collector, connected to the impactor section, receives the product air flow and traps the sample particles in a liquid.

  16. Rapid estimate of solid volume in large tuff cores using a gas pycnometer

    SciTech Connect (OSTI)

    Thies, C.; Geddis, A.M.; Guzman, A.G.

    1996-09-01

    A thermally insulated, rigid-volume gas pycnometer system has been developed. The pycnometer chambers have been machined from solid PVC cylinders. Two chambers confine dry high-purity helium at different pressures. A thick-walled design ensures minimal heat exchange with the surrounding environment and a constant volume system, while expansion takes place between the chambers. The internal energy of the gas is assumed constant over the expansion. The ideal gas law is used to estimate the volume of solid material sealed in one of the chambers. Temperature is monitored continuously and incorporated into the calculation of solid volume. Temperature variation between measurements is less than 0.1{degrees}C. The data are used to compute grain density for oven-dried Apache Leap tuff core samples. The measured volume of solid and the sample bulk volume are used to estimate porosity and bulk density. Intrinsic permeability was estimated from the porosity and measured pore surface area and is compared to in-situ measurements by the air permeability method. The gas pycnometer accommodates large core samples (0.25 m length x 0.11 m diameter) and can measure solid volume greater than 2.20 cm{sup 3} with less than 1% error.

  17. Sample Proficiency Test exercise

    SciTech Connect (OSTI)

    Alcaraz, A; Gregg, H; Koester, C

    2006-02-05

    The current format of the OPCW proficiency tests has multiple sets of 2 samples sent to an analysis laboratory. In each sample set, one is identified as a sample, the other as a blank. This method of conducting proficiency tests differs from how an OPCW designated laboratory would receive authentic samples (a set of three containers, each not identified, consisting of the authentic sample, a control sample, and a blank sample). This exercise was designed to test the reporting if the proficiency tests were to be conducted. As such, this is not an official OPCW proficiency test, and the attached report is one method by which LLNL might report their analyses under a more realistic testing scheme. Therefore, the title on the report ''Report of the Umpteenth Official OPCW Proficiency Test'' is meaningless, and provides a bit of whimsy for the analyses and readers of the report.

  18. Automated sample collection and processing for radionuclide effluent monitoring

    SciTech Connect (OSTI)

    Beals, D.M.; Crandall, B.S.; Fledderman, P.D.

    1998-12-31

    In the United States, all nuclear facilities must provide for environmental monitoring of effluent points for radionuclides that have the potential for release to the environment. For the US Department of Energy (DOE) this means thousands of surface water analyses are performed each year at a cost of millions of dollars per year. Analytical costs for radiochemical analyses are often high due to the lengthy chemical separations required prior to counting for the selected analyte. At the Savannah River Site, a DOE facility located in South Carolina, a new technique has been demonstrated whereby samples are collected and processed in the field, at the time of collection, for selected radionuclides. The technique makes use of ion selective solid-phase extraction (SPE) disks being placed in a portable automatic aqueous sampler. Water from a surface stream or effluent sampling point is collected via an ISCO, Inc., 3710 SPX portable sampler. Weekly or biweekly (depending on the sampling requirements), the SPE disks are collected and returned to the laboratory for activity determination. The analytes that are currently being monitored by the new method are {sup 99}Tc, {sup 80}Sr, {sup 137}Cs, {sup 58}Co, and {sup 60}Co. The RAD SPE disks have been shown to be effective for the extraction of technetium, strontium, and cesium and cobalt from aqueous systems. The {sup 99}Tc and {sup 90}Sr activities are determined by direct counting of the SPE disk by gas flow beta proportional techniques; the {sup 137}Cs and radiocobalt activities are determined by direct counting of the SPE disk by gamma spectrometry. Because of the specificity of the SPE disks, there is no additional chemical separation required prior to counting the SPE disks for the selected activity determination.

  19. Hot gas filter and system assembly

    DOE Patents [OSTI]

    Lippert, Thomas Edwin; Palmer, Kathryn Miles; Bruck, Gerald Joseph; Alvin, Mary Anne; Smeltzer, Eugene E.; Bachovchin, Dennis Michael

    1999-01-01

    A filter element for separating fine dirty particles from a hot gas. The filter element comprises a first porous wall and a second porous wall. Each porous wall has an outer surface and an inner surface. The first and second porous walls being coupled together thereby forming a substantially closed figure and open at one end. The open end is formed to be coupled to a hot gas clean up system support structure. The first and second porous walls define a channel beginning at the open end and terminate at the closed end through which a filtered clean gas can flow through and out into the clean gas side of a hot gas clean up system.

  20. Hot gas filter and system assembly

    DOE Patents [OSTI]

    Lippert, T.E.; Palmer, K.M.; Bruck, G.J.; Alvin, M.A.; Smeltzer, E.E.; Bachovchin, D.M.

    1999-08-31

    A filter element is described for separating fine dirty particles from a hot gas. The filter element comprises a first porous wall and a second porous wall. Each porous wall has an outer surface and an inner surface. The first and second porous walls being coupled together thereby forming a substantially closed figure and open at one end. The open end is formed to be coupled to a hot gas clean up system support structure. The first and second porous walls define a channel beginning at the open end and terminate at the closed end through which a filtered clean gas can flow through and out into the clean gas side of a hot gas clean up system. 8 figs.